air-water co2 fluxes: Topics by Science.gov

Sample records for air-water co2 fluxes

Air-water CO2 Fluxes In Seasonal Hypoxia-influenced Green Bay, Lake Michigan

NASA Astrophysics Data System (ADS)

Lin, P.; Klump, J. V.; Guo, L.

2016-02-01

Increasing anthropogenic nutrient enrichment has led to seasonal hypoxia in Green Bay, the largest freshwater estuary in the Laurentian Great Lakes, but change in carbon dynamics associated with the development of hypoxia remains poorly understood. Variations in alkalinity, abundance of carbon species, and air-water CO2 fluxes were quantified under contrasting hypoxic conditions during summer 2014. Green Bay was characterized with high pH (average 8.62 ± 0.16 in August), high DIC concentrations (2113 - 3213 µmol/kg) and high pCO2 in the water column. pCO2 was mostly >700 µatm in June, resulting in a net CO2 source to the air, while pCO2 was mostly <650 µatm in August when hypoxic conditions occurred in Green Bay. In central Green Bay, pCO2 was the highest during both sampling months, accompanying by low dissolved oxygen (DO) and lower pH in the water column. In August, pCO2 was inversely correlated with DOC concentration and increased with DOC/DOP ratio, suggesting a control by organic matter on air-water CO2 dynamics and consumption of DO in Green Bay. Positive CO2 fluxes to the atmosphere during August were only observed in northern bay but a CO2 sink was found in southern Green Bay ( 40% of study area) with high biological production and terrestrial DOM. Daily CO2 flux ranged from 10.9 to 48.5 mmol-C m-2 d-1 in June with an average of 18.29 ± 7.44 mmol-C m-2 d-1, whereas it varied from 1.82 ± 1.18 mmol m-2 d-1 in the north to -2.05 ± 1.89 mmol m-2 d-1 in the south of Green Bay in August. Even though strong biological production reduced the CO2 emission, daily CO2 fluxes from Green Bay to the air were as high as 7.4 × 107 mole-C in June and 4.6 × 106 mole-C in August, suggesting a significant role of high-DIC lakes in global CO2 budget and cycling.
Air-water gas exchange and CO2 flux in a mangrove-dominated estuary

USGS Publications Warehouse

Ho, David T.; Ferrón, Sara; Engel, Victor C.; Larsen, Laurel G.; Barr, Jordan G.

2014-01-01

Mangrove forests are highly productive ecosystems, but the fate of mangrove-derived carbon remains uncertain. Part of that uncertainty stems from the fact that gas transfer velocities in mangrove-surrounded waters are not well determined, leading to uncertainty in air-water CO2 fluxes. Two SF6 tracer release experiments were conducted to determine gas transfer velocities (k(600) = 8.3 ± 0.4 and 8.1 ± 0.6 cm h−1), along with simultaneous measurements of pCO2 to determine the air-water CO2 fluxes from Shark River, Florida (232.11 ± 23.69 and 171.13 ± 20.28 mmol C m−2 d−1), an estuary within the largest contiguous mangrove forest in North America. The gas transfer velocity results are consistent with turbulent kinetic energy dissipation measurements, indicating a higher rate of turbulence and gas exchange than predicted by commonly used wind speed/gas exchange parameterizations. The results have important implications for carbon fluxes in mangrove ecosystems.
Air-sea CO2 flux pattern along the southern Bay of Bengal waters

NASA Astrophysics Data System (ADS)

Shanthi, R.; Poornima, D.; Naveen, M.; Thangaradjou, T.; Choudhury, S. B.; Rao, K. H.; Dadhwal, V. K.

2016-12-01

Physico-chemical observations made from January 2013 to March 2015 in coastal waters of the southwest Bay of Bengal show pronounced seasonal variation in physico-chemical parameters including total alkalinity (TA: 1927.390-4088.642 μmol kg-1), chlorophyll (0.13-19.41 μg l-1) and also calculated dissolved inorganic carbon (DIC: 1574.219-3790.954 μmol kg-1), partial pressure of carbon dioxide (pCO2: 155.520-1488.607 μatm) and air-sea CO2 flux (FCO2: -4.808 to 11.255 mmol Cm-2 d-1). Most of the physical parameters are at their maximum during summer due to the increased solar radiation at cloud free conditions, less or no riverine inputs, and lack of vertical mixing of water column which leads to the lowest nutrients concentration, dissolved oxygen (DO), biological production, pCO2 and negative flux of CO2 to the atmosphere. Chlorophyll and DO concentrations enhanced due to increased nutrients during premonsoon and monsoon season due to the vertical mixing of water column driven by the strong winds and external inputs at respective seasons. The constant positive loading of nutrients, TA, DIC, chlorophyll, pCO2 and FCO2 against atmospheric temperature (AT), lux, sea surface temperature (SST), pH and salinity observed in principal component analysis (PCA) suggested that physical and biological parameters play vital role in the seasonal distribution of pCO2 along the southwest Bay of Bengal. The annual variability of CO2 flux clearly depicted that the southwest Bay of Bengal switch from sink (2013) to source status in the recent years (2014 and 2015) and it act as significant source of CO2 to the atmosphere with a mean flux of 0.204 ± 1.449 mmol Cm-2 d-1.
Effect of Sampling Depth on Air-Sea CO2 Flux Estimates in River-Stratified Arctic Coastal Waters

NASA Astrophysics Data System (ADS)

Miller, L. A.; Papakyriakou, T. N.

2015-12-01

In summer-time Arctic coastal waters that are strongly influenced by river run-off, extreme stratification severely limits wind mixing, making it difficult to effectively sample the surface 'mixed layer', which can be as shallow as 1 m, from a ship. During two expeditions in southwestern Hudson Bay, off the Nelson, Hayes, and Churchill River estuaries, we confirmed that sampling depth has a strong impact on estimates of 'surface' pCO2 and calculated air-sea CO2 fluxes. We determined pCO2 in samples collected from 5 m, using a typical underway system on the ship's seawater supply; from the 'surface' rosette bottle, which was generally between 1 and 3 m; and using a niskin bottle deployed at 1 m and just below the surface from a small boat away from the ship. Our samples confirmed that the error in pCO2 derived from typical ship-board versus small-boat sampling at a single station could be nearly 90 μatm, leading to errors in the calculated air-sea CO2 flux of more than 0.1 mmol/(m2s). Attempting to extrapolate such fluxes over the 6,000,000 km2 area of the Arctic shelves would generate an error approaching a gigamol CO2/s. Averaging the station data over a cruise still resulted in an error of nearly 50% in the total flux estimate. Our results have implications not only for the design and execution of expedition-based sampling, but also for placement of in-situ sensors. Particularly in polar waters, sensors are usually deployed on moorings, well below the surface, to avoid damage and destruction from drifting ice. However, to obtain accurate information on air-sea fluxes in these areas, it is necessary to deploy sensors on ice-capable buoys that can position the sensors in true 'surface' waters.
Air-ice CO2 fluxes and pCO2 dynamics in the Arctic coastal area (Amundsen Gulf, Canada)

NASA Astrophysics Data System (ADS)

Geilfus, Nicolas-Xavier; Tison, Jean Louis; Carnat, Gauthier; Else, Brent; Borges, Alberto V.; Thomas, Helmuth; Shadwick, Elizabeth; Delille, Bruno

2010-05-01

driven by the air-ice pCO2 gradient. Hence, while the temperature is a leading factor in controlling magnitude of air-ice CO2 fluxes, pCO2 of the ice controls both magnitude and direction of fluxes. However, pCO2 in Arctic is significantly higher than in Antarctica. This difference could be due to a higher level of organic matter in Arctic. The degradation of this organic matter fuel CO2 efflux from the ice to the atmosphere in early spring. We observed evidence of CaCO3 precipitation, but only at the top of the ice. Implications in term of air-ice CO2 transfer of such CaCO3 precipitation will be discussed. In addition, salt-rich snow appears to strongly affect air-ice CO2 fluxes in the arctic. Borges, A. V., et al. (2006), Carbon dioxide in European coastal waters, Estuar. Coast. Shelf Sci., 70(3), 375-387.
Effects of sea-ice and biogeochemical processes and storms on under-ice water fCO2 during the winter-spring transition in the high Arctic Ocean: Implications for sea-air CO2 fluxes

NASA Astrophysics Data System (ADS)

Fransson, Agneta; Chierici, Melissa; Skjelvan, Ingunn; Olsen, Are; Assmy, Philipp; Peterson, Algot K.; Spreen, Gunnar; Ward, Brian

2017-07-01

We performed measurements of carbon dioxide fugacity (fCO2) in the surface water under Arctic sea ice from January to June 2015 during the Norwegian young sea ICE (N-ICE2015) expedition. Over this period, the ship drifted with four different ice floes and covered the deep Nansen Basin, the slopes north of Svalbard, and the Yermak Plateau. This unique winter-to-spring data set includes the first winter-time under-ice water fCO2 observations in this region. The observed under-ice fCO2 ranged between 315 µatm in winter and 153 µatm in spring, hence was undersaturated relative to the atmospheric fCO2. Although the sea ice partly prevented direct CO2 exchange between ocean and atmosphere, frequently occurring leads and breakup of the ice sheet promoted sea-air CO2 fluxes. The CO2 sink varied between 0.3 and 86 mmol C m-2 d-1, depending strongly on the open-water fractions (OW) and storm events. The maximum sea-air CO2 fluxes occurred during storm events in February and June. In winter, the main drivers of the change in under-ice water fCO2 were dissolution of CaCO3 (ikaite) and vertical mixing. In June, in addition to these processes, primary production and sea-air CO2 fluxes were important. The cumulative loss due to CaCO3 dissolution of 0.7 mol C m-2 in the upper 10 m played a major role in sustaining the undersaturation of fCO2 during the entire study. The relative effects of the total fCO2 change due to CaCO3 dissolution was 38%, primary production 26%, vertical mixing 16%, sea-air CO2 fluxes 16%, and temperature and salinity insignificant.
A flux-gradient system for simultaneous measurement of the CH4, CO2, and H2O fluxes at a lake-air interface.

PubMed

Xiao, Wei; Liu, Shoudong; Li, Hanchao; Xiao, Qitao; Wang, Wei; Hu, Zhenghua; Hu, Cheng; Gao, Yunqiu; Shen, Jing; Zhao, Xiaoyan; Zhang, Mi; Lee, Xuhui

2014-12-16

Inland lakes play important roles in water and greenhouse gas cycling in the environment. This study aims to test the performance of a flux-gradient system for simultaneous measurement of the fluxes of water vapor, CO2, and CH4 at a lake-air interface. The concentration gradients over the water surface were measured with an analyzer based on the wavelength-scanned cavity ring-down spectroscopy technology, and the eddy diffusivity was measured with a sonic anemometer. Results of a zero-gradient test indicate a flux measurement precision of 4.8 W m(-2) for water vapor, 0.010 mg m(-2) s(-1) for CO2, and 0.029 μg m(-2) s(-1) for CH4. During the 620 day measurement period, 97%, 69%, and 67% of H2O, CO2, and CH4 hourly fluxes were higher in magnitude than the measurement precision, which confirms that the flux-gradient system had adequate precision for the measurement of the lake-air exchanges. This study illustrates four strengths of the flux-gradient method: (1) the ability to simultaneously measure the flux of H2O, CO2, and CH4; (2) negligibly small density corrections; (3) the ability to resolve small CH4 gradient and flux; and (4) continuous and noninvasive operation. The annual mean CH4 flux (1.8 g CH4 m(-2) year(-1)) at this hypereutrophic lake was close to the median value for inland lakes in the world (1.6 g CH4 m(-2) year(-1)). The system has adequate precision for CH4 flux for broad applications but requires further improvement to resolve small CO2 flux in many lakes.
Surface Water pCO2 Variations and Sea-Air CO2 Fluxes During Summer in the Eastern Canadian Arctic

NASA Astrophysics Data System (ADS)

Burgers, T. M.; Miller, L. A.; Thomas, H.; Else, B. G. T.; Gosselin, M.; Papakyriakou, T.

2017-12-01

Based on a 2 year data set, the eastern Canadian Arctic Archipelago and Baffin Bay appear to be a modest summertime sink of atmospheric CO2. We measured surface water CO2 partial pressure (pCO2), salinity, and temperature throughout northern Baffin Bay, Nares Strait, and Lancaster Sound from the CCGS Amundsen during its 2013 and 2014 summer cruises. Surface water pCO2 displayed considerable variability (144-364 μatm) but never exceeded atmospheric concentrations, and average calculated CO2 fluxes in 2013 and 2014 were -12 and -3 mmol C m-2 d-1 (into the ocean), respectively. Ancillary measurements of chlorophyll a reveal low summertime productivity in surface waters. Based on total alkalinity and stable oxygen isotopes (δ18O) data, a strong riverine signal in northern Nares Strait coincided with relatively high surface pCO2, whereas areas of sea-ice melt occur with low surface pCO2. Further assessments, extending the seasonal observation period, are needed to properly constrain both seasonal and annual CO2 fluxes in this region.
The Effect of Breaking Waves on CO_2 Air-Sea Fluxes in the Coastal Zone

NASA Astrophysics Data System (ADS)

Gutiérrez-Loza, Lucía; Ocampo-Torres, Francisco J.; García-Nava, Héctor

2018-03-01

The influence of wave-associated parameters controlling turbulent CO_2 fluxes through the air-sea interface is investigated in a coastal region. A full year of high-quality data of direct estimates of air-sea CO_2 fluxes based on eddy-covariance measurements is presented. The study area located in Todos Santos Bay, Baja California, Mexico, is a net sink of CO_2 with a mean flux of -1.3 μmol m^{-2}s^{-1} (-41.6 mol m^{-2}yr^{-1} ). The results of a quantile-regression analysis computed between the CO_2 flux and, (1) wind speed, (2) significant wave height, (3) wave steepness, and (4) water temperature, suggest that the significant wave height is the most correlated parameter with the magnitude of the flux but the behaviour of the relation varies along the probability distribution function, with the slopes of the regression lines presenting both positive and negative values. These results imply that the presence of surface waves in coastal areas is the key factor that promotes the increase of the flux from and into the ocean. Further analysis suggests that the local characteristics of the aqueous and atmospheric layers might determine the direction of the flux.
Climatological mean and decadal change in surface ocean pCO 2, and net sea-air CO 2 flux over the global oceans

NASA Astrophysics Data System (ADS)

Takahashi, Taro; Sutherland, Stewart C.; Wanninkhof, Rik; Sweeney, Colm; Feely, Richard A.; Chipman, David W.; Hales, Burke; Friederich, Gernot; Chavez, Francisco; Sabine, Christopher; Watson, Andrew; Bakker, Dorothee C. E.; Schuster, Ute; Metzl, Nicolas; Yoshikawa-Inoue, Hisayuki; Ishii, Masao; Midorikawa, Takashi; Nojiri, Yukihiro; Körtzinger, Arne; Steinhoff, Tobias; Hoppema, Mario; Olafsson, Jon; Arnarson, Thorarinn S.; Tilbrook, Bronte; Johannessen, Truls; Olsen, Are; Bellerby, Richard; Wong, C. S.; Delille, Bruno; Bates, N. R.; de Baar, Hein J. W.

2009-04-01

A climatological mean distribution for the surface water pCO 2 over the global oceans in non-El Niño conditions has been constructed with spatial resolution of 4° (latitude) ×5° (longitude) for a reference year 2000 based upon about 3 million measurements of surface water pCO 2 obtained from 1970 to 2007. The database used for this study is about 3 times larger than the 0.94 million used for our earlier paper [Takahashi et al., 2002. Global sea-air CO 2 flux based on climatological surface ocean pCO 2, and seasonal biological and temperature effects. Deep-Sea Res. II, 49, 1601-1622]. A time-trend analysis using deseasonalized surface water pCO 2 data in portions of the North Atlantic, North and South Pacific and Southern Oceans (which cover about 27% of the global ocean areas) indicates that the surface water pCO 2 over these oceanic areas has increased on average at a mean rate of 1.5 μatm y -1 with basin-specific rates varying between 1.2±0.5 and 2.1±0.4 μatm y -1. A global ocean database for a single reference year 2000 is assembled using this mean rate for correcting observations made in different years to the reference year. The observations made during El Niño periods in the equatorial Pacific and those made in coastal zones are excluded from the database. Seasonal changes in the surface water pCO 2 and the sea-air pCO 2 difference over four climatic zones in the Atlantic, Pacific, Indian and Southern Oceans are presented. Over the Southern Ocean seasonal ice zone, the seasonality is complex. Although it cannot be thoroughly documented due to the limited extent of observations, seasonal changes in pCO 2 are approximated by using the data for under-ice waters during austral winter and those for the marginal ice and ice-free zones. The net air-sea CO 2 flux is estimated using the sea-air pCO 2 difference and the air-sea gas transfer rate that is parameterized as a function of (wind speed) 2 with a scaling factor of 0.26. This is estimated by inverting
Net sea-air CO2 fluxes and modelled pCO2 in the southwestern subtropical Atlantic continental shelf during spring 2010 and summer 2011

NASA Astrophysics Data System (ADS)

Ito, Rosane Gonçalves; Garcia, Carlos Alberto Eiras; Tavano, Virginia Maria

2016-05-01

Sea-air CO2 fluxes over continental shelves vary substantially in time on both seasonal and sub-seasonal scales, driven primarily by variations in surface pCO2 due to several oceanic mechanisms. Furthermore, coastal zones have not been appropriately considered in global estimates of sea-air CO2 fluxes, despite their importance to ecology and to productivity. In this work, we aimed to improve our understanding of the role played by shelf waters in controlling sea-air CO2 fluxes by investigating the southwestern Atlantic Ocean (21-35°S) region, where physical, chemical and biological measurements were made on board the Brazilian R. V. Cruzeiro do Sul during late spring 2010 and early summer 2011. Features such as discharge from the La Plata River, intrusions of tropical waters on the outer shelf due to meandering and flow instabilities of the Brazil Current, and coastal upwelling in the Santa Marta Grande Cape and São Tomé Cape were detected by both in situ measurements and ocean colour and thermal satellite imagery. Overall, shelf waters in the study area were a source of CO2 to the atmosphere, with an average of 1.2 mmol CO2 m-2 day-1 for the late spring and 11.2 mmol CO2 m-2 day-1 for the early summer cruises. The spatial variability in ocean pCO2 was associated with surface ocean properties (temperature, salinity and chlorophyll-a concentration) in both the slope and shelf waters. Empirical algorithms for predicting temperature-normalized surface ocean pCO2 as a function of surface ocean properties were shown to perform well in both shelf and slope waters, except (a) within cyclonic eddies produced by baroclinic instability of the Brazil Current as detected by satellite SST imagery and (b) in coastal upwelling regions. In these regions, surface ocean pCO2 values were higher as a result of upwelled CO2-enriched subsurface waters. Finally, a pCO2 algorithm based on both sea surface temperature and surface chlorophyll-a was developed that enabled the spatial
Comparison of two closed-path cavity-based spectrometers for measuring air-water CO2 and CH4 fluxes by eddy covariance

NASA Astrophysics Data System (ADS)

Yang, Mingxi; Prytherch, John; Kozlova, Elena; Yelland, Margaret J.; Parenkat Mony, Deepulal; Bell, Thomas G.

2016-11-01

In recent years several commercialised closed-path cavity-based spectroscopic instruments designed for eddy covariance flux measurements of carbon dioxide (CO2), methane (CH4), and water vapour (H2O) have become available. Here we compare the performance of two leading models - the Picarro G2311-f and the Los Gatos Research (LGR) Fast Greenhouse Gas Analyzer (FGGA) at a coastal site. Both instruments can compute dry mixing ratios of CO2 and CH4 based on concurrently measured H2O, temperature, and pressure. Additionally, we used a high throughput Nafion dryer to physically remove H2O from the Picarro airstream. Observed air-sea CO2 and CH4 fluxes from these two analysers, averaging about 12 and 0.12 mmol m-2 day-1 respectively, agree within the measurement uncertainties. For the purpose of quantifying dry CO2 and CH4 fluxes downstream of a long inlet, the numerical H2O corrections appear to be reasonably effective and lead to results that are comparable to physical removal of H2O with a Nafion dryer in the mean. We estimate the high-frequency attenuation of fluxes in our closed-path set-up, which was relatively small ( ≤ 10 %) for CO2 and CH4 but very large for the more polar H2O. The Picarro showed significantly lower noise and flux detection limits than the LGR. The hourly flux detection limit for the Picarro was about 2 mmol m-2 day-1 for CO2 and 0.02 mmol m-2 day-1 for CH4. For the LGR these detection limits were about 8 and 0.05 mmol m-2 day-1. Using global maps of monthly mean air-sea CO2 flux as reference, we estimate that the Picarro and LGR can resolve hourly CO2 fluxes from roughly 40 and 4 % of the world's oceans respectively. Averaging over longer timescales would be required in regions with smaller fluxes. Hourly flux detection limits of CH4 from both instruments are generally higher than the expected emissions from the open ocean, though the signal to noise of this measurement may improve closer to the coast.
[Partial pressure of CO2 and CO2 degassing fluxes of Huayuankou and Xiaolangdi Station affected by Xiaolangdi Reservoir].

PubMed

Zhang, Yong-ling; Yang, Xiao-lin; Zhang, Dong

2015-01-01

According to periodic sampling analysis per month in Xiaolangdi station and Huayuankou station from November 2011 to October 2012, combined with continuous sampling analysis of Xiaolangdi Reservoir during runoff and sediment control period in 2012, partial pressure of CO2 (pCO2) in surface water were calculated based on Henry's Law, pCO2 features and air-water CO2 degassing fluxes of Huayuankou station and Xiaolangdi station affected by Xiaolangdi Reservoir were studied. The results were listed as follows, when Xiaolangdi Reservoir operated normally, pCO2 in surface water of Xiaolangdi station and Huayuankou station varied from 82 to 195 Pa and from 99 to 228 Pa, moreover, pCO2 in surface water from July to September were distinctly higher than those in other months; meanwhile, pCO, in surface water from Huayuankou station were higher than that from Xiaolangdi station. During runoff and sediment control period of Xiaolangdi Reservoir, two hydrological stations commonly indicated that pCO2 in surface water during water draining were obviously lower than those during sediment releasing. Whether in the period of normal operation or runoff and sediment control, pCO2 in surface water had positive relations to DIC content in two hydrological stations. Since the EpCO,/AOU value was higher than the theoretical value of 0. 62, the biological aerobic respiration effect had distinct contribution to pCO2. Throughout the whole year, air-water CO2 degassing fluxes from Xiaolangdi station and Huayuankou station were 0.486 p.mol (m2 s) -l and 0.588 pmol (m2 x s)(-1) respectively; When Xiaolangdi Reservoir operated normally, air-water CO, degassing fluxes in Huayuankou station were higher than that in Xiaolangdi station; during runoff and sediment control from Xiaolangdi Reservoir, two hydrological stations had one observation result in common, namely, air-water CO2 degassing fluxes in the period of water draining were obviously lower than that in the period of sediment releasing.
Effect of hydroperiod on CO2 fluxes at the air-water interface in the Mediterranean coastal wetlands of Doñana

NASA Astrophysics Data System (ADS)

Huertas, I. Emma; Flecha, Susana; Figuerola, Jordi; Costas, Eduardo; Morris, Edward P.

2017-07-01

Wetlands are productive ecosystems that play an important role in the Earth's carbon cycle and thus global carbon budgets. Climate variability affects amount of material entering and the metabolic balance of wetlands, thereby modifying carbon dynamics. This study presents spatiotemporal changes in air-water CO2 exchange in the vast wetlands of Doñana (Spain) in relation to different hydrological cycles. Water sources feeding Doñana, including groundwater and streams, ultimately depend on the fluctuating balance between annual precipitation and evapotranspiration. Hence, in order to examine the contribution of the rainfall pattern to the emission/capture of CO2 by a range of aquatic habitats in Doñana, we took monthly measurements during severely wet, dry, and normal hydrological years (2010-2013). During wet hydrological cycles, CO2 outgassing from flooded marshes markedly decreased in comparison to that observed during subsequent dry-normal cycles, with mean values of 25.84 ± 19 and 5.2 ± 8 mmol m-2 d-1, respectively. Under drier meteorological conditions, air-water CO2 fluxes also diminished in permanent floodplains and ponds, which even behaved as mild sinks for atmospheric CO2 during certain periods. Increased inputs of dissolved CO2 from the underground aquifer and the stream following periods of high rainfall are believed to be behind this pattern. Large lagoons with a managed water supply from an adjacent estuary took up atmospheric CO2 nearly permanently. Regional air-water carbon transport was 15.2 GgC yr-1 under wet and 1.24 GgC yr-1 under dry meteorological conditions, well below the estimated net primary production for Doñana wetlands, indicating that the ecosystem acts as a large CO2 sink.
Deriving a sea surface climatology of CO2 fugacity in support of air-sea gas flux studies

NASA Astrophysics Data System (ADS)

Goddijn-Murphy, L. M.; Woolf, D. K.; Land, P. E.; Shutler, J. D.; Donlon, C.

2014-07-01

Climatologies, or long-term averages, of essential climate variables are useful for evaluating models and providing a baseline for studying anomalies. The Surface Ocean Carbon Dioxide (CO2) Atlas (SOCAT) has made millions of global underway sea surface measurements of CO2 publicly available, all in a uniform format and presented as fugacity, fCO2. fCO2 is highly sensitive to temperature and the measurements are only valid for the instantaneous sea surface temperature (SST) that is measured concurrent with the in-water CO2 measurement. To create a climatology of fCO2 data suitable for calculating air-sea CO2 fluxes it is therefore desirable to calculate fCO2 valid for climate quality SST. This paper presents a method for creating such a climatology. We recomputed SOCAT's fCO2 values for their respective measurement month and year using climate quality SST data from satellite Earth observation and then extrapolated the resulting fCO2 values to reference year 2010. The data were then spatially interpolated onto a 1° × 1° grid of the global oceans to produce 12 monthly fCO2 distributions for 2010. The partial pressure of CO2 (pCO2) is also provided for those who prefer to use pCO2. The CO2 concentration difference between ocean and atmosphere is the thermodynamic driving force of the air-sea CO2 flux, and hence the presented fCO2 distributions can be used in air-sea gas flux calculations together with climatologies of other climate variables.
Surface Ocean pCO2 Seasonality and Sea-Air CO2 Flux Estimates for the North American East Coast

NASA Technical Reports Server (NTRS)

Signorini, Sergio; Mannino, Antonio; Najjar, Raymond G., Jr.; Friedrichs, Marjorie A. M.; Cai, Wei-Jun; Salisbury, Joe; Wang, Zhaohui Aleck; Thomas, Helmuth; Shadwick, Elizabeth

2013-01-01

Underway and in situ observations of surface ocean pCO2, combined with satellite data, were used to develop pCO2 regional algorithms to analyze the seasonal and interannual variability of surface ocean pCO2 and sea-air CO2 flux for five physically and biologically distinct regions of the eastern North American continental shelf: the South Atlantic Bight (SAB), the Mid-Atlantic Bight (MAB), the Gulf of Maine (GoM), Nantucket Shoals and Georges Bank (NS+GB), and the Scotian Shelf (SS). Temperature and dissolved inorganic carbon variability are the most influential factors driving the seasonality of pCO2. Estimates of the sea-air CO2 flux were derived from the available pCO2 data, as well as from the pCO2 reconstructed by the algorithm. Two different gas exchange parameterizations were used. The SS, GB+NS, MAB, and SAB regions are net sinks of atmospheric CO2 while the GoM is a weak source. The estimates vary depending on the use of surface ocean pCO2 from the data or algorithm, as well as with the use of the two different gas exchange parameterizations. Most of the regional estimates are in general agreement with previous studies when the range of uncertainty and interannual variability are taken into account. According to the algorithm, the average annual uptake of atmospheric CO2 by eastern North American continental shelf waters is found to be between 3.4 and 5.4 Tg C/yr (areal average of 0.7 to 1.0 mol CO2 /sq m/yr) over the period 2003-2010.
Global sea-air CO 2 flux based on climatological surface ocean pCO 2, and seasonal biological and temperature effects

NASA Astrophysics Data System (ADS)

Takahashi, Taro; Sutherland, Stewart C.; Sweeney, Colm; Poisson, Alain; Metzl, Nicolas; Tilbrook, Bronte; Bates, Nicolas; Wanninkhof, Rik; Feely, Richard A.; Sabine, Christopher; Olafsson, Jon; Nojiri, Yukihiro

Based on about 940,000 measurements of surface-water pCO 2 obtained since the International Geophysical Year of 1956-59, the climatological, monthly distribution of pCO 2 in the global surface waters representing mean non-El Niño conditions has been obtained with a spatial resolution of 4°×5° for a reference year 1995. The monthly and annual net sea-air CO 2 flux has been computed using the NCEP/NCAR 41-year mean monthly wind speeds. An annual net uptake flux of CO 2 by the global oceans has been estimated to be 2.2 (+22% or -19%) Pg C yr -1 using the (wind speed) 2 dependence of the CO 2 gas transfer velocity of Wanninkhof (J. Geophys. Res. 97 (1992) 7373). The errors associated with the wind-speed variation have been estimated using one standard deviation (about±2 m s -1) from the mean monthly wind speed observed over each 4°×5° pixel area of the global oceans. The new global uptake flux obtained with the Wanninkhof (wind speed) 2 dependence is compared with those obtained previously using a smaller number of measurements, about 250,000 and 550,000, respectively, and are found to be consistent within±0.2 Pg C yr -1. This estimate for the global ocean uptake flux is consistent with the values of 2.0±0.6 Pg C yr -1 estimated on the basis of the observed changes in the atmospheric CO 2 and oxygen concentrations during the 1990s (Nature 381 (1996) 218; Science 287 (2000) 2467). However, if the (wind speed) 3 dependence of Wanninkhof and McGillis (Res. Lett. 26 (1999) 1889) is used instead, the annual ocean uptake as well as the sensitivity to wind-speed variability is increased by about 70%. A zone between 40° and 60° latitudes in both the northern and southern hemispheres is found to be a major sink for atmospheric CO 2. In these areas, poleward-flowing warm waters meet and mix with the cold subpolar waters rich in nutrients. The pCO 2 in the surface water is decreased by the cooling effect on warm waters and by the biological drawdown of pCO 2 in
Spatio-temporal visualization of air-sea CO2 flux and carbon budget using volume rendering

NASA Astrophysics Data System (ADS)

Du, Zhenhong; Fang, Lei; Bai, Yan; Zhang, Feng; Liu, Renyi

2015-04-01

This paper presents a novel visualization method to show the spatio-temporal dynamics of carbon sinks and sources, and carbon fluxes in the ocean carbon cycle. The air-sea carbon budget and its process of accumulation are demonstrated in the spatial dimension, while the distribution pattern and variation of CO2 flux are expressed by color changes. In this way, we unite spatial and temporal characteristics of satellite data through visualization. A GPU-based direct volume rendering technique using half-angle slicing is adopted to dynamically visualize the released or absorbed CO2 gas with shadow effects. A data model is designed to generate four-dimensional (4D) data from satellite-derived air-sea CO2 flux products, and an out-of-core scheduling strategy is also proposed for on-the-fly rendering of time series of satellite data. The presented 4D visualization method is implemented on graphics cards with vertex, geometry and fragment shaders. It provides a visually realistic simulation and user interaction for real-time rendering. This approach has been integrated into the Information System of Ocean Satellite Monitoring for Air-sea CO2 Flux (IssCO2) for the research and assessment of air-sea CO2 flux in the China Seas.
Seasonal and spatial variations in surface pCO2 and air-sea CO2 flux in the Chesapeake Bay

NASA Astrophysics Data System (ADS)

Cai, W. J.; Chen, B.

2017-12-01

Bay-wide observations of surface water partial pressure of carbon dioxide (pCO2) were conducted in May, June, August, and October 2016 to study the spatial and seasonal variations in surface pCO2 and to estimate air-sea CO2 flux in the Chesapeake Bay. Overall, high surface pCO2 in the upper-bay decreased downstream rapidly below the atmospheric value near the bay bridge in the mid-bay and then increased slightly to the lower-bay where pCO2 approached the atmospheric level. Over the course of a year, pCO2 was higher than 1000 µatm in the upper bay and the highest pCO2 (2500 µatm) was observed in August. Significant biologically-induced pCO2 undersaturation was observed at the upper part of the mid-bay in August with pCO2 as low as 50 µatm and oversaturated DO% of 200%. In addition to biological control, vertical mixing and upwelling controlled by wind direction and tidal stage played an important role in controlling surface pCO2 in the mid-bay as is evidenced by co-occurrence of high pCO2 with low temperature and low oxygen or high salinity from the subsurface. These physical processes occurred regularly and in short time scale of hours, suggesting they must be considered in the assessment of annual air-sea CO2 flux. Seasonally, the upper-bay acted as a source for atmospheric CO2 over the course of a year. The boundary of upper and mid bay transited from a CO2 source to a sink from May to August and was a source again in October due to strong biological production in summer. In contrast, the mid-bay represented as a CO2 source with large temporal variation due to dynamic hydrographic settings. The lower-bay transited from a weak sink in May to equilibrated with the atmosphere from June to August, while became a source again in October. Moreover, the CO2 flux could be reversed very quickly under episodic severe weather events. Thus further research, including the influence of severe weather and subsequent bloom, is needed to get better understanding of the carbon
In situ evaluation of air-sea CO2 gas transfer velocity in an inner estuary using eddy covariance - with a special focus on the importance of using reliable CO2-fluxes

NASA Astrophysics Data System (ADS)

Jørgensen, E. T.; Sørensen, L. L.; Jensen, B.; Sejr, M. K.

2012-04-01

The air-sea exchange of CO2 or CO2 flux is driven by the difference in the partial pressure of CO2 in the water and the atmosphere (ΔpCO2), the solubility of CO2 (K0) and the gas transfer velocity (k) (Wanninkhof et al., 2009;Weiss, 1974) . ΔpCO2 and K0 are determined with relatively high precision and it is estimated that the biggest uncertainty when modelling the air-sea flux is the parameterization of k. As an example; the estimated global air-sea flux increases by 70 % when using the parameterization by Wanninkhof and McGillis (1999) instead of Wanninkhof (1992) (Rutgersson et al., 2008). In coastal areas the uncertainty is even higher and only few studies have focused on determining transfer velocity for the coastal waters and even fewer on estuaries (Borges et al., 2004;Rutgersson et al., 2008). The transfer velocity (k600) of CO2 in the inner estuary of Roskilde Fjord, Denmark was investigated using eddy covariance CO2 fluxes (ECM) and directly measured ΔpCO2 during May and June 2010. The data was strictly sorted to heighten the certainty of the results and the outcome was; DS1; using only ECM, and DS2; including the inertial dissipation method (IDM). The inner part of Roskilde Fjord showed to be a very biological active CO2 sink and preliminary results showed that the average k600 was more than 10 times higher than transfer velocities from similar studies of other coastal areas. The much higher transfer velocities were estimated to be caused by the greater fetch and shallower water in Roskilde Fjord, which indicated that turbulence in both air and water influence k600. The wind speed parameterization of k600 using DS1 showed some scatter but when including IDM the r2 of DS2 reached 0.93 with an exponential parameterization, where U10 was based on the Businger-Dyer relationships using friction velocity and atmospheric stability. This indicates that some of the uncertainties coupled with CO2 fluxes calculated by the ECM are removed when including the IDM.

The OceanFlux Greenhouse Gases methodology for deriving a sea surface climatology of CO2 fugacity in support of air-sea gas flux studies

NASA Astrophysics Data System (ADS)

Goddijn-Murphy, L. M.; Woolf, D. K.; Land, P. E.; Shutler, J. D.; Donlon, C.

2015-07-01

Climatologies, or long-term averages, of essential climate variables are useful for evaluating models and providing a baseline for studying anomalies. The Surface Ocean CO2 Atlas (SOCAT) has made millions of global underway sea surface measurements of CO2 publicly available, all in a uniform format and presented as fugacity, fCO2. As fCO2 is highly sensitive to temperature, the measurements are only valid for the instantaneous sea surface temperature (SST) that is measured concurrently with the in-water CO2 measurement. To create a climatology of fCO2 data suitable for calculating air-sea CO2 fluxes, it is therefore desirable to calculate fCO2 valid for a more consistent and averaged SST. This paper presents the OceanFlux Greenhouse Gases methodology for creating such a climatology. We recomputed SOCAT's fCO2 values for their respective measurement month and year using monthly composite SST data on a 1° × 1° grid from satellite Earth observation and then extrapolated the resulting fCO2 values to reference year 2010. The data were then spatially interpolated onto a 1° × 1° grid of the global oceans to produce 12 monthly fCO2 distributions for 2010, including the prediction errors of fCO2 produced by the spatial interpolation technique. The partial pressure of CO2 (pCO2) is also provided for those who prefer to use pCO2. The CO2 concentration difference between ocean and atmosphere is the thermodynamic driving force of the air-sea CO2 flux, and hence the presented fCO2 distributions can be used in air-sea gas flux calculations together with climatologies of other climate variables.
A comparison of CO2 dynamics and air-water fluxes in a river-dominated estuary and a mangrove-dominated marine estuary

NASA Astrophysics Data System (ADS)

Akhand, Anirban; Chanda, Abhra; Manna, Sudip; Das, Sourav; Hazra, Sugata; Roy, Rajdeep; Choudhury, S. B.; Rao, K. H.; Dadhwal, V. K.; Chakraborty, Kunal; Mostofa, K. M. G.; Tokoro, T.; Kuwae, Tomohiro; Wanninkhof, Rik

2016-11-01

The fugacity of CO2 (fCO2 (water)) and air-water CO2 flux were compared between a river-dominated anthropogenically disturbed open estuary, the Hugli, and a comparatively pristine mangrove-dominated semiclosed marine estuary, the Matla, on the east coast of India. Annual mean salinity of the Hugli Estuary (≈7.1) was much less compared to the Matla Estuary (≈20.0). All the stations of the Hugli Estuary were highly supersaturated with CO2 (annual mean 2200 µatm), whereas the Matla was marginally oversaturated (annual mean 530 µatm). During the postmonsoon season, the outer station of the Matla Estuary was under saturated with respect to CO2 and acted as a sink. The annual mean CO2 emission from the Hugli Estuary (32.4 mol C m-2 yr-1) was 14 times higher than the Matla Estuary (2.3 mol C m-2 yr-1). CO2 efflux rate from the Hugli Estuary has increased drastically in the last decade, which is attributed to increased runoff from the river-dominated estuary.
Arctic Ocean CO2 uptake: an improved multiyear estimate of the air-sea CO2 flux incorporating chlorophyll a concentrations

NASA Astrophysics Data System (ADS)

Yasunaka, Sayaka; Siswanto, Eko; Olsen, Are; Hoppema, Mario; Watanabe, Eiji; Fransson, Agneta; Chierici, Melissa; Murata, Akihiko; Lauvset, Siv K.; Wanninkhof, Rik; Takahashi, Taro; Kosugi, Naohiro; Omar, Abdirahman M.; van Heuven, Steven; Mathis, Jeremy T.

2018-03-01

We estimated monthly air-sea CO2 fluxes in the Arctic Ocean and its adjacent seas north of 60° N from 1997 to 2014. This was done by mapping partial pressure of CO2 in the surface water (pCO2w) using a self-organizing map (SOM) technique incorporating chlorophyll a concentration (Chl a), sea surface temperature, sea surface salinity, sea ice concentration, atmospheric CO2 mixing ratio, and geographical position. We applied new algorithms for extracting Chl a from satellite remote sensing reflectance with close examination of uncertainty of the obtained Chl a values. The overall relationship between pCO2w and Chl a was negative, whereas the relationship varied among seasons and regions. The addition of Chl a as a parameter in the SOM process enabled us to improve the estimate of pCO2w, particularly via better representation of its decline in spring, which resulted from biologically mediated pCO2w reduction. As a result of the inclusion of Chl a, the uncertainty in the CO2 flux estimate was reduced, with a net annual Arctic Ocean CO2 uptake of 180 ± 130 Tg C yr-1. Seasonal to interannual variation in the CO2 influx was also calculated.
Gas exchange and CO2 flux in the tropical Atlantic Ocean determined from Rn-222 and pCO2 measurements

NASA Technical Reports Server (NTRS)

Smethie, W. M., Jr.; Takahashi, T.; Chipman, D. W.; Ledwell, J. R.

1985-01-01

The piston velocity for the tropical Atlantic Ocean has been determined from 29 radon profiles measured during the TTO Tropical Atlantic Study. By combining these data with the pCO2 data measured in the surface water and air samples, the net flux of CO2 across the sea-air interface has been calculated for the tropical Atlantic. The dependence of the piston velocity on wind speed is discussed, and possible causes for the high sea-to-air CO2 flux observed in the equatorial zone are examined.
Carbon Dioxide and Water Vapor Fluxes at Reduced and Elevated CO2 Concentrations in Southern California Chaparral

NASA Astrophysics Data System (ADS)

Cheng, Y.; Oechel, W. C.; Hastings, S. J.; Bryant, P. J.; Qian, Y.

2003-12-01

This research took two different approaches to measuring carbon and water vapor fluxes at the plot level (2 x 2 meter and 1 x 1 meter plots) to help understand and predict ecosystem responses to elevated CO2 concentrations and concomitant environmental changes. The first measurement approach utilized a CO2-controlled, ambient lit, temperature controlled (CO2LT) null-balance chamber system run in a chaparral ecosystem in southern California, with six different CO2 concentrations ranging from 250 to 750 ppm CO2 concentrations with 100 ppm difference between treatments. The second measurement approach used a free air CO2 enrichment (FACE) system operated at 550 ppm CO2 concentration. These manipulations allowed the study of responses of naturally-growing chaparral to varying levels of CO2, under both chamber and open air conditions. There was a statistically significant CO2 effect on annual NEE (net ecosystem exchange) during the period of this study, 1997 to 2000. The effects of elevated CO2 on CO2 and water vapor flux showed strong seasonal patterns. Elevated CO2 delayed the development of water stress, enhanced leaf-level photosynthesis, and decreased transpiration and conductance rates. These effects were observed regardless of water availability. Ecosystem CO2 sink strength and plant water status were significantly enhanced by elevated CO2 when water availability was restricted. Comparing the FACE treatment and the FACE control, the ecosystem was either a stronger sink or a weaker source to the atmosphere throughout the dry seasons, but there was no statistically significant difference during the wet seasons. Annual average leaf transpiration decreased with the increasing of the atmospheric CO2 concentration. Although leaf level water-use efficiency (WUE) increased with the growth CO2 concentration increase, annual evapotranspiration (ET) during these four years also increased with the increase of the atmospheric CO2 concentrations. These results indicate that
Quantifying the drivers of ocean-atmosphere CO2 fluxes

NASA Astrophysics Data System (ADS)

Lauderdale, Jonathan M.; Dutkiewicz, Stephanie; Williams, Richard G.; Follows, Michael J.

2016-07-01

A mechanistic framework for quantitatively mapping the regional drivers of air-sea CO2 fluxes at a global scale is developed. The framework evaluates the interplay between (1) surface heat and freshwater fluxes that influence the potential saturated carbon concentration, which depends on changes in sea surface temperature, salinity and alkalinity, (2) a residual, disequilibrium flux influenced by upwelling and entrainment of remineralized carbon- and nutrient-rich waters from the ocean interior, as well as rapid subduction of surface waters, (3) carbon uptake and export by biological activity as both soft tissue and carbonate, and (4) the effect on surface carbon concentrations due to freshwater precipitation or evaporation. In a steady state simulation of a coarse-resolution ocean circulation and biogeochemistry model, the sum of the individually determined components is close to the known total flux of the simulation. The leading order balance, identified in different dynamical regimes, is between the CO2 fluxes driven by surface heat fluxes and a combination of biologically driven carbon uptake and disequilibrium-driven carbon outgassing. The framework is still able to reconstruct simulated fluxes when evaluated using monthly averaged data and takes a form that can be applied consistently in models of different complexity and observations of the ocean. In this way, the framework may reveal differences in the balance of drivers acting across an ensemble of climate model simulations or be applied to an analysis and interpretation of the observed, real-world air-sea flux of CO2.
Influence of leaf water potential on diurnal changes in CO2 and water vapour fluxes

NASA Astrophysics Data System (ADS)

Yu, Qiang; Xu, Shouhua; Wang, Jing; Lee, Xuhui

2007-08-01

Mass and energy fluxes between the atmosphere and vegetation are driven by meteorological variables, and controlled by plant water status, which may change more markedly diurnally than soil water. We tested the hypothesis that integration of dynamic changes in leaf water potential may improve the simulation of CO2 and water fluxes over a wheat canopy. Simulation of leaf water potential was integrated into a comprehensive model (the ChinaAgrosys) of heat, water and CO2 fluxes and crop growth. Photosynthesis from individual leaves was integrated to the canopy by taking into consideration the attenuation of radiation when penetrating the canopy. Transpiration was calculated with the Shuttleworth-Wallace model in which canopy resistance was taken as a link between energy balance and physiological regulation. A revised version of the Ball-Woodrow-Berry stomatal model was applied to produce a new canopy resistance model, which was validated against measured CO2 and water vapour fluxes over winter wheat fields in Yucheng (36°57' N, 116°36' E, 28 m above sea level) in the North China Plain during 1997, 2001 and 2004. Leaf water potential played an important role in causing stomatal conductance to fall at midday, which caused diurnal changes in photosynthesis and transpiration. Changes in soil water potential were less important. Inclusion of the dynamics of leaf water potential can improve the precision of the simulation of CO2 and water vapour fluxes, especially in the afternoon under water stress conditions.
Comparison of Sea-Air CO2 Flux Estimates Using Satellite-Based Versus Mooring Wind Speed Data

NASA Astrophysics Data System (ADS)

Sutton, A. J.; Sabine, C. L.; Feely, R. A.; Wanninkhof, R. H.

2016-12-01

The global ocean is a major sink of anthropogenic CO2, absorbing approximately 27% of CO2 emissions since the beginning of the industrial revolution. Any variation or change in the ocean CO2 sink has implications for future climate. Observations of sea-air CO2 flux have relied primarily on ship-based underway measurements of partial pressure of CO2 (pCO2) combined with satellite, model, or multi-platform wind products. Direct measurements of ΔpCO2 (seawater - air pCO2) and wind speed from moored platforms now allow for high-resolution CO2 flux time series. Here we present a comparison of CO2 flux calculated from moored ΔpCO2 measured on four moorings in different biomes of the Pacific Ocean in combination with: 1) Cross-Calibrated Multi-Platform (CCMP) winds or 2) wind speed measurements made on ocean reference moorings excluded from the CCMP dataset. Preliminary results show using CCMP winds overestimates CO2 flux on average by 5% at the Kuroshio Extension Observatory, Ocean Station Papa, WHOI Hawaii Ocean Timeseries Station, and Stratus. In general, CO2 flux seasonality follows patterns of seawater pCO2 and SST with periods of CO2 outgassing during summer and CO2 uptake during winter at these locations. Any offsets or seasonal biases in CCMP winds could impact global ocean sink estimates using this data product. Here we present patterns and trends between the two CO2 flux estimates and discuss the potential implications for tracking variability and change in global ocean CO2 uptake.
The impact of changing wind speeds on gas transfer and its effect on global air-sea CO2 fluxes

NASA Astrophysics Data System (ADS)

Wanninkhof, R.; Triñanes, J.

2017-06-01

An increase in global wind speeds over time is affecting the global uptake of CO2 by the ocean. We determine the impact of changing winds on gas transfer and CO2 uptake by using the recently updated, global high-resolution, cross-calibrated multiplatform wind product (CCMP-V2) and a fixed monthly pCO2 climatology. In particular, we assess global changes in the context of regional wind speed changes that are attributed to large-scale climate reorganizations. The impact of wind on global CO2 gas fluxes as determined by the bulk formula is dependent on several factors, including the functionality of the gas exchange-wind speed relationship and the regional and seasonal differences in the air-water partial pressure of CO2 gradient (ΔpCO2). The latter also controls the direction of the flux. Fluxes out of the ocean are influenced more by changes in the low-to-intermediate wind speed range, while ingassing is impacted more by changes in higher winds because of the regional correlations between wind and ΔpCO2. Gas exchange-wind speed parameterizations with a quadratic and third-order polynomial dependency on wind, each of which meets global constraints, are compared. The changes in air-sea CO2 fluxes resulting from wind speed trends are greatest in the equatorial Pacific and cause a 0.03-0.04 Pg C decade-1 increase in outgassing over the 27 year time span. This leads to a small overall decrease of 0.00 to 0.02 Pg C decade-1 in global net CO2 uptake, contrary to expectations that increasing winds increase net CO2 uptake.Plain Language SummaryThe effects of changing winds are isolated from the total change in trends in global air-sea CO2 fluxes over the last 27 years. The overall effect of increasing winds over time has a smaller impact than expected as the impact in regions of outgassing is greater than for the regions acting as a CO2 sink. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018CSR...162...27C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018CSR...162...27C">Diurnal variability of CO2 flux at coastal zone of Taiwan based on eddy covariance observation</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Chien, Hwa; Zhong, Yao-Zhao; Yang, Kang-Hung; Cheng, Hao-Yuan 2018-06-01 In this study, we employed shore-based eddy covariance systems for a continuous measurement of the coastal CO2 flux near the northwestern coast of Taiwan from 2011 to 2015. To ensure the validity of the analysis, the data was selected and filtered with a footprint model and an empirical mode decomposition method. The results indicate that the nearshore air-sea and air-land CO2 fluxes exhibited a significant diurnal variability and a substantial day-night difference. The net air-sea CO2 flux was -1.75 ± 0.98 μmol-C m-2 s-1, whereas the net air-land CO2 flux was 0.54 ± 7.35 μmol-C m-2 s-1, which indicated that in northwestern Taiwan, the coastal water acts as a sink of atmospheric CO2 but the coastal land acts as a source. The Random Forest Method was applied to hierarchize the influence of Chl-a, SST, DO, pH and U10 on air-sea CO2 fluxes. The result suggests that the strength of the diurnal air-sea CO2 flux is strongly influenced by the local wind speed. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.B41B0407B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.B41B0407B">Field evaluation of open and closed-path CO2 flux systems over asphalt surface</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Bogoev, I.; Santos, E. 2016-12-01 Eddy covariance (EC) is a widely used method for quantifying surface fluxes of heat, water vapor and carbon dioxide between ecosystems and the atmosphere. A typical EC system consists of an ultrasonic anemometer measuring the 3D wind vector and a fast-response infrared gas analyzer for sensing the water vapor and CO2 density in the air. When using an open-path analyzer that detects the constituent's density in situ a correction for concurrent air temperature and humidity fluctuations must be applied, Webb et al. (1980). In environments with small magnitudes of CO2 flux (<5µmol m-2 s-1) and in the presence of high sensible heat flux, like wintertime over boreal forest, open-path flux measurements have been challenging since the magnitude of the density corrections are as large as the uncorrected CO2 flux itself. A new technology merging the sensing paths of the gas analyzer and the sonic anemometer has been recently developed. This new integrated instrument allows a direct measurement of CO2 mixing ratio in the open air and has the potential to improve the quality of the temperature related density corrections by synchronously measuring the sensible heat flux in the optical path of the gas analyzer. We evaluate the performance and the accuracy of this new sensor over a large parking lot with an asphalt surface where the CO2 fluxes are considered low and the interfering sensible heat fluxes are above 200 Wm-2. A co-located closed-path EC system is used as a reference measurement to examine any systematic biases and apparent CO2 uptake observed with open-path sensors under high sensible heat flux regimes. Half-hour mean and variance of CO2 and water vapor concentrations are evaluated. The relative spectral responses, covariances and corrected turbulent fluxes using a common sonic anemometer are analyzed. The influence of sensor separation and frequency response attenuation on the density corrections is discussed. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016PolSc..10..323Y','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016PolSc..10..323Y">Mapping of the air-sea CO2 flux in the Arctic Ocean and its adjacent seas: Basin-wide distribution and seasonal to interannual variability</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Yasunaka, Sayaka; Murata, Akihiko; Watanabe, Eiji; Chierici, Melissa; Fransson, Agneta; van Heuven, Steven; Hoppema, Mario; Ishii, Masao; Johannessen, Truls; Kosugi, Naohiro; Lauvset, Siv K.; Mathis, Jeremy T.; Nishino, Shigeto; Omar, Abdirahman M.; Olsen, Are; Sasano, Daisuke; Takahashi, Taro; Wanninkhof, Rik 2016-09-01 We produced 204 monthly maps of the air-sea CO2 flux in the Arctic north of 60°N, including the Arctic Ocean and its adjacent seas, from January 1997 to December 2013 by using a self-organizing map technique. The partial pressure of CO2 (pCO2) in surface water data were obtained by shipboard underway measurements or calculated from alkalinity and total inorganic carbon of surface water samples. Subsequently, we investigated the basin-wide distribution and seasonal to interannual variability of the CO2 fluxes. The 17-year annual mean CO2 flux shows that all areas of the Arctic Ocean and its adjacent seas were net CO2 sinks. The estimated annual CO2 uptake by the Arctic Ocean was 180 TgC yr-1. The CO2 influx was strongest in winter in the Greenland/Norwegian Seas (>15 mmol m-2 day-1) and the Barents Sea (>12 mmol m-2 day-1) because of strong winds, and strongest in summer in the Chukchi Sea (∼10 mmol m-2 day-1) because of the sea-ice retreat. In recent years, the CO2 uptake has increased in the Greenland/Norwegian Sea and decreased in the southern Barents Sea, owing to increased and decreased air-sea pCO2 differences, respectively. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013EGUGA..1514237M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013EGUGA..1514237M">Soil CO2 flux in alley-cropping systems composed of black locust and poplar trees, Germany</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Medinski, Tetiana; Freese, Dirk; Boehm, Christian 2013-04-01 The understanding of soil carbon dynamics after establishment of alley-cropping systems is crucial for mitigation of greenhouse CO2 gas. This study investigates soil CO2 fluxes in alley-cropping systems composed of strips of black locust (Robinia pseudoacacia L.) and poplar (Max 1) trees and adjacent to them crop strips (Lupinus). Soil CO2 flux was measured monthly over a period from March to November 2012, using a LI-COR LI-8100A automated device. Concurrently with CO2 flux measurements, soil and air temperature and soil moisture were recorded within 10 cm of each collar. Soil samples were collected nearby each soil collar for microbial C and hot water-extractable C analyses. At each study plot, root biomass was measured to a depth of 15 cm. In all vegetation types, soil CO2 flux increased from May to August, showing a significant positive correlation with air and soil temperature, which can be a reflection of increase in photosynthesis over the warm summer months. CO2 flux was the highest in poplar followed by black locust and lupines. The relationships between CO2 flux, microbial biomass and hot water-extractable carbon were not straightforward. Among the measured parameters, root density was found to be the main factor to explain the higher CO2 flux in tree strips. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMOS24A..02V','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMOS24A..02V">Watershed-scale drivers of air-water CO2 exchanges in two lagoonal, North Carolina (USA) estuaries</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Van Dam, B.; Crosswell, J.; Anderson, I. C.; Paerl, H. W. 2017-12-01 Riverine loading of nutrients and organic matter act in concert to modulate CO2 fluxes in estuaries, yet quantitative relationships between these factors remain poorly defined. This study explored watershed-scale mechanisms responsible for the relatively low CO2 fluxes observed in two microtidal, lagoonal estuaries. Air-water CO2 fluxes were quantified with 74 high-resolution spatial surveys in the neighboring New River Estuary (NewRE) and Neuse River Estuary (NeuseRE), North Carolina, which experience a common climatology, but differ in marine versus riverine influence. Annually, both estuaries were relatively small sources of CO2 to the atmosphere, 12.5 and 16.3 mmol C m2 d-1 in the NeuseRE and NewRE, respectively. Variations in riverine alkalinity and inorganic carbon loading caused zones of minimum buffering capacity to occur at different locations in each estuary, enhancing the sensitivity of estuarine inorganic C chemistry to acidification. Large-scale pCO2 variations were driven by changes in freshwater age (akin to residence time), which modulate nutrient and organic carbon supply and phytoplankton flushing. Greatest pCO2 under-saturation was observed at intermediate freshwater ages, between 2-3 weeks. Biological controls on CO2 fluxes were obscured by variable inputs of river-borne CO2, which drove CO2 degassing in the river-dominated NeuseRE. Internally produced CO2 exceeded river-borne CO2 in the marine-dominated NewRE, suggesting that net ecosystem heterotrophy, rather than riverine inputs, drove CO2 fluxes in this system. Although annual CO2 fluxes were similar between systems, watershed-specific hydrologic factors led to disparate controls on internal carbonate chemistry, which can influence overall ecosystem health and response to future perturbation. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018JGRG..123..271V','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018JGRG..123..271V">Watershed-Scale Drivers of Air-Water CO2 Exchanges in Two Lagoonal North Carolina (USA) Estuaries</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Van Dam, Bryce R.; Crosswell, Joseph R.; Anderson, Iris C.; Paerl, Hans W. 2018-01-01 Riverine loading of nutrients and organic matter act in concert to modulate CO2 fluxes in estuaries, yet quantitative relationships between these factors remain poorly defined. This study explored watershed-scale mechanisms responsible for the relatively low CO2 fluxes observed in two microtidal, lagoonal estuaries. Air-water CO2 fluxes were quantified with 74 high-resolution spatial surveys in the neighboring New River Estuary (NewRE) and Neuse River Estuary (NeuseRE), North Carolina, which experience a common climatology but differ in marine versus riverine influence. Annually, both estuaries were relatively small sources of CO2 to the atmosphere, 12.5 and 16.3 mmol C m-2 d-1 in the NeuseRE and NewRE, respectively. Large-scale pCO2 variations were driven by changes in freshwater age, which modulates nutrient and organic carbon supply and phytoplankton flushing. Greatest pCO2 undersaturation was observed at intermediate freshwater ages, between 2 and 3 weeks. Biological controls on CO2 fluxes were obscured by variable inputs of river-borne CO2, which drove CO2 degassing in the river-dominated NeuseRE. Internally produced CO2 exceeded river-borne CO2 in the marine-dominated NewRE, suggesting that net ecosystem heterotrophy, rather than riverine inputs, drove CO2 fluxes in this system. Variations in riverine alkalinity and inorganic carbon loading caused zones of minimum buffering capacity to occur at different locations in each estuary, enhancing the sensitivity of estuarine inorganic C chemistry to acidification. Although annual CO2 fluxes were similar between systems, watershed-specific hydrologic factors led to disparate controls on internal carbonate chemistry, which can influence ecosystem biogeochemical cycling, trophic state, and response to future perturbations. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013BGeo...10.8109L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013BGeo...10.8109L">Climate change impacts on sea-air fluxes of CO2 in three Arctic seas: a sensitivity study using Earth observation</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Land, P. E.; Shutler, J. D.; Cowling, R. D.; Woolf, D. K.; Walker, P.; Findlay, H. S.; Upstill-Goddard, R. C.; Donlon, C. J. 2013-12-01 We applied coincident Earth observation data collected during 2008 and 2009 from multiple sensors (RA2, AATSR and MERIS, mounted on the European Space Agency satellite Envisat) to characterise environmental conditions and integrated sea-air fluxes of CO2 in three Arctic seas (Greenland, Barents, Kara). We assessed net CO2 sink sensitivity due to changes in temperature, salinity and sea ice duration arising from future climate scenarios. During the study period the Greenland and Barents seas were net sinks for atmospheric CO2, with integrated sea-air fluxes of -36 ± 14 and -11 ± 5 Tg C yr-1, respectively, and the Kara Sea was a weak net CO2 source with an integrated sea-air flux of +2.2 ± 1.4 Tg C yr-1. The combined integrated CO2 sea-air flux from all three was -45 ± 18 Tg C yr-1. In a sensitivity analysis we varied temperature, salinity and sea ice duration. Variations in temperature and salinity led to modification of the transfer velocity, solubility and partial pressure of CO2 taking into account the resultant variations in alkalinity and dissolved organic carbon (DOC). Our results showed that warming had a strong positive effect on the annual integrated sea-air flux of CO2 (i.e. reducing the sink), freshening had a strong negative effect and reduced sea ice duration had a small but measurable positive effect. In the climate change scenario examined, the effects of warming in just over a decade of climate change up to 2020 outweighed the combined effects of freshening and reduced sea ice duration. Collectively these effects gave an integrated sea-air flux change of +4.0 Tg C in the Greenland Sea, +6.0 Tg C in the Barents Sea and +1.7 Tg C in the Kara Sea, reducing the Greenland and Barents sinks by 11% and 53%, respectively, and increasing the weak Kara Sea source by 81%. Overall, the regional integrated flux changed by +11.7 Tg C, which is a 26% reduction in the regional sink. In terms of CO2 sink strength, we conclude that the Barents Sea is the most </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/26910987','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/26910987">[Summer Greenhouse Gases Exchange Flux Across Water-air Interface in Three Water Reservoirs Located in Different Geologic Setting in Guangxi, China].</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Li, Jian-hong; Pu, Jun-bing; Sun, Ping-an; Yuan, Dao-xian; Liu, Wen; Zhang, Tao; Mo, Xue 2015-11-01 Due to special hydrogeochemical characteristics of calcium-rich, alkaline and DIC-rich ( dissolved inorganic carbon) environment controlled by the weathering products from carbonate rock, the exchange characteristics, processes and controlling factors of greenhouse gas (CO2 and CH4) across water-air interface in karst water reservoir show obvious differences from those of non-karst water reservoir. Three water reservoirs (Dalongdong reservoir-karst reservoir, Wulixia reservoir--semi karst reservoir, Si'anjiang reservoir-non-karst reservoir) located in different geologic setting in Guangxi Zhuang Autonomous Region, China were chosen to reveal characteristics and controlling factors of greenhouse gas exchange flux across water-air interface. Two common approaches, floating chamber (FC) and thin boundary layer models (TBL), were employed to research and contrast greenhouse gas exchange flux across water-air interface from three reservoirs. The results showed that: (1) surface-layer water in reservoir area and discharging water under dam in Dalongdong water reservoir were the source of atmospheric CO2 and CH4. Surface-layer water in reservoir area in Wulixia water reservoir was the sink of atmospheric CO2 and the source of atmospheric CH4, while discharging water under dam was the source of atmospheric CO2 and CH4. Surface-layer water in Si'anjiang water reservoir was the sink of atmospheric CO2 and source of atmospheric CH4. (2) CO2 and CH4 effluxes in discharging water under dam were much more than those in surface-layer water in reservoir area regardless of karst reservoir or non karst reservoir. Accordingly, more attention should be paid to the CO2 and CH4 emission from discharging water under dam. (3) In the absence of submerged soil organic matters and plants, the difference of CH4 effluxes between karst groundwater-fed reservoir ( Dalongdong water reservoir) and non-karst area ( Wulixia water reservoir and Si'anjiang water reservoir) was less. However, CO2 </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017OcSci..13..997P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017OcSci..13..997P">The spatial and interannual dynamics of the surface water carbonate system and air-sea CO2 fluxes in the outer shelf and slope of the Eurasian Arctic Ocean</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Pipko, Irina I.; Pugach, Svetlana P.; Semiletov, Igor P.; Anderson, Leif G.; Shakhova, Natalia E.; Gustafsson, Örjan; Repina, Irina A.; Spivak, Eduard A.; Charkin, Alexander N.; Salyuk, Anatoly N.; Shcherbakova, Kseniia P.; Panova, Elena V.; Dudarev, Oleg V. 2017-11-01 The Arctic is undergoing dramatic changes which cover the entire range of natural processes, from extreme increases in the temperatures of air, soil, and water, to changes in the cryosphere, the biodiversity of Arctic waters, and land vegetation. Small changes in the largest marine carbon pool, the dissolved inorganic carbon pool, can have a profound impact on the carbon dioxide (CO2) flux between the ocean and the atmosphere, and the feedback of this flux to climate. Knowledge of relevant processes in the Arctic seas improves the evaluation and projection of carbon cycle dynamics under current conditions of rapid climate change. Investigation of the CO2 system in the outer shelf and continental slope waters of the Eurasian Arctic seas (the Barents, Kara, Laptev, and East Siberian seas) during 2006, 2007, and 2009 revealed a general trend in the surface water partial pressure of CO2 (pCO2) distribution, which manifested as an increase in pCO2 values eastward. The existence of this trend was defined by different oceanographic and biogeochemical regimes in the western and eastern parts of the study area; the trend is likely increasing due to a combination of factors determined by contemporary change in the Arctic climate, each change in turn evoking a series of synergistic effects. A high-resolution in situ investigation of the carbonate system parameters of the four Arctic seas was carried out in the warm season of 2007; this year was characterized by the next-to-lowest historic sea-ice extent in the Arctic Ocean, on satellite record, to that date. The study showed the different responses of the seawater carbonate system to the environment changes in the western vs. the eastern Eurasian Arctic seas. The large, open, highly productive water area in the northern Barents Sea enhances atmospheric CO2 uptake. In contrast, the uptake of CO2 was strongly weakened in the outer shelf and slope waters of the East Siberian Arctic seas under the 2007 environmental conditions </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018AtmEn.172..102H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018AtmEn.172..102H">Characteristics of GHG flux from water-air interface along a reclaimed water intake area of the Chaobai River in Shunyi, Beijing</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> He, Baonan; He, Jiangtao; Wang, Jian; Li, Jie; Wang, Fei 2018-01-01 To understand greenhouse gas (GHG) flux in reclaimed water intake area impact on urban climate, 'static chamber' method was used to investigate the spatio-diurnal variations and the influence factors of GHG fluxes at water-air interface from Jian River to Chaobai River. Results showed that the average fluxes of CO2 from the Jian River and the Chaobai River were 73.46 mg(m2·h)-1 and -64.75 mg(m2·h)-1, respectively. CO2 was emitted the most in the Jian River, but it was absorbed from the atmosphere in the Chaobai River. Unary linear regression analyses demonstrated that Chlorophyll a (Chl a) and pH variation controlled the carbon source and sink from the Jian River to the Chaobai River. The diurnal variation of CO2 fluxes was higher at night than in the daytime in the Jian River, and it was the inverse in the Chaobai River, which highly correlated with dissociative CO2 and HCO3- transformation to CO32-. The average fluxes of CH4 from the Jian River and Chaobai River were 0.973 mg(m2·h)-1 and 5.556 mg(m2·h)-1, respectively, which increased along the water flow direction. Unary and multiple linear regression analyses demonstrated that Chl a and total organic carbon (TOC) controlled the increase of CH4 along the flow direction. The diurnal variation of CH4 fluxes was slightly higher in the daytime than at night due to the effect of water temperature. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016ECSS..176....1M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016ECSS..176....1M">Temporal variability of air-sea CO2 exchange in a low-emission estuary</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Mørk, Eva Thorborg; Sejr, Mikael Kristian; Stæhr, Peter Anton; Sørensen, Lise Lotte 2016-07-01 There is the need for further study of whether global estimates of air-sea CO2 exchange in estuarine systems capture the relevant temporal variability and, as such, the temporal variability of bulk parameterized and directly measured CO2 fluxes was investigated in the Danish estuary, Roskilde Fjord. The air-sea CO2 fluxes showed large temporal variability across seasons and between days and that more than 30% of the net CO2 emission in 2013 was a result of two large fall and winter storms. The diurnal variability of ΔpCO2 was up to 400 during summer changing the estuary from a source to a sink of CO2 within the day. Across seasons the system was suggested to change from a sink of atmospheric CO2 during spring to near neutral during summer and later to a source of atmospheric CO2 during fall. Results indicated that Roskilde Fjord was an annual low-emission estuary, with an estimated bulk parameterized release of 3.9 ± 8.7 mol CO2 m-2 y-1 during 2012-2013. It was suggested that the production-respiration balance leading to the low annual emission in Roskilde Fjord, was caused by the shallow depth, long residence time and high water quality in the estuary. In the data analysis the eddy covariance CO2 flux samples were filtered according to the H2Osbnd CO2 cross-sensitivity assessment suggested by Landwehr et al. (2014). This filtering reduced episodes of contradicting directions between measured and bulk parameterized air-sea CO2 exchanges and changed the net air-sea CO2 exchange from an uptake to a release. The CO2 gas transfer velocity was calculated from directly measured CO2 fluxes and ΔpCO2 and agreed to previous observations and parameterizations. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_1");'>1</a></li> <li class="active">2</li> <li><a href="#" onclick='return showDiv("page_3");'>3</a></li> <li><a href="#" onclick='return showDiv("page_4");'>4</a></li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_3" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_1");'>1</a></li> <li><a href="#" onclick='return showDiv("page_2");'>2</a></li> <li class="active">3</li> <li><a href="#" onclick='return showDiv("page_4");'>4</a></li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="41"> <li> <a target="_blank" onclick="trackOutboundLink('http://hdl.handle.net/2060/20020044134','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20020044134">Sensitivity of Global Sea-Air CO2 Flux to Gas Transfer Algorithms, Climatological Wind Speeds, and Variability of Sea Surface Temperature and Salinity</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> McClain, Charles R.; Signorini, Sergio 2002-01-01 Sensitivity analyses of sea-air CO2 flux to gas transfer algorithms, climatological wind speeds, sea surface temperatures (SST) and salinity (SSS) were conducted for the global oceans and selected regional domains. Large uncertainties in the global sea-air flux estimates are identified due to different gas transfer algorithms, global climatological wind speeds, and seasonal SST and SSS data. The global sea-air flux ranges from -0.57 to -2.27 Gt/yr, depending on the combination of gas transfer algorithms and global climatological wind speeds used. Different combinations of SST and SSS global fields resulted in changes as large as 35% on the oceans global sea-air flux. An error as small as plus or minus 0.2 in SSS translates into a plus or minus 43% deviation on the mean global CO2 flux. This result emphasizes the need for highly accurate satellite SSS observations for the development of remote sensing sea-air flux algorithms. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5038955','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5038955">A Sensitivity Analysis of the Impact of Rain on Regional and Global Sea-Air Fluxes of CO2</a> <a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Shutler, J. D.; Land, P. E.; Woolf, D. K.; Quartly, G. D. 2016-01-01 The global oceans are considered a major sink of atmospheric carbon dioxide (CO2). Rain is known to alter the physical and chemical conditions at the sea surface, and thus influence the transfer of CO2 between the ocean and atmosphere. It can influence gas exchange through enhanced gas transfer velocity, the direct export of carbon from the atmosphere to the ocean, by altering the sea skin temperature, and through surface layer dilution. However, to date, very few studies quantifying these effects on global net sea-air fluxes exist. Here, we include terms for the enhanced gas transfer velocity and the direct export of carbon in calculations of the global net sea-air fluxes, using a 7-year time series of monthly global climate quality satellite remote sensing observations, model and in-situ data. The use of a non-linear relationship between the effects of rain and wind significantly reduces the estimated impact of rain-induced surface turbulence on the rate of sea-air gas transfer, when compared to a linear relationship. Nevertheless, globally, the rain enhanced gas transfer and rain induced direct export increase the estimated annual oceanic integrated net sink of CO2 by up to 6%. Regionally, the variations can be larger, with rain increasing the estimated annual net sink in the Pacific Ocean by up to 15% and altering monthly net flux by > ± 50%. Based on these analyses, the impacts of rain should be included in the uncertainty analysis of studies that estimate net sea-air fluxes of CO2 as the rain can have a considerable impact, dependent upon the region and timescale. PMID:27673683 </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1351785','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1351785">Nonlinear CO 2 flux response to 7 years of experimentally induced permafrost thaw</a> <a target="_blank" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Mauritz, Marguerite; Bracho, Rosvel; Celis, Gerardo Rapid Arctic warming is expected to increase global greenhouse gas concentrations as permafrost thaw exposes immense stores of frozen carbon (C) to microbial decomposition. Permafrost thaw also stimulates plant growth, which could offset C loss. Using data from 7 years of experimental Air and Soil warming in moist acidic tundra, we show that Soil warming had a much stronger effect on CO 2 flux than Air warming. Soil warming caused rapid permafrost thaw and increased ecosystem respiration (R eco), gross primary productivity (GPP), and net summer CO 2 storage (NEE). Over 7 years R eco, GPP, and NEE also increasedmore » in Control (i.e., ambient plots), but this change could be explained by slow thaw in Control areas. In the initial stages of thaw, R eco, GPP, and NEE increased linearly with thaw across all treatments, despite different rates of thaw. As thaw in Soil warming continued to increase linearly, ground surface subsidence created saturated microsites and suppressed R eco, GPP, and NEE. However R eco and GPP remained high in areas with large Eriophorum vaginatum biomass. In general NEE increased with thaw, but was more strongly correlated with plant biomass than thaw, indicating that higher R eco in deeply thawed areas during summer months was balanced by GPP. Summer CO 2 flux across treatments fit a single quadratic relationship that captured the functional response of CO 2 flux to thaw, water table depth, and plant biomass. These results demonstrate the importance of indirect thaw effects on CO 2 flux: plant growth and water table dynamics. Nonsummer R eco models estimated that the area was an annual CO 2 source during all years of observation. As a result, nonsummer CO 2 loss in warmer, more deeply thawed soils exceeded the increases in summer GPP, and thawed tundra was a net annual CO 2 source.« less </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1351785-nonlinear-co2-flux-response-nbsp-years-experimentally-induced-permafrost-thaw','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1351785-nonlinear-co2-flux-response-nbsp-years-experimentally-induced-permafrost-thaw">Nonlinear CO 2 flux response to 7 years of experimentally induced permafrost thaw</a> <a target="_blank" href="http://www.osti.gov/pages">DOE PAGES</a> Mauritz, Marguerite; Bracho, Rosvel; Celis, Gerardo; ... 2017-02-16 Rapid Arctic warming is expected to increase global greenhouse gas concentrations as permafrost thaw exposes immense stores of frozen carbon (C) to microbial decomposition. Permafrost thaw also stimulates plant growth, which could offset C loss. Using data from 7 years of experimental Air and Soil warming in moist acidic tundra, we show that Soil warming had a much stronger effect on CO 2 flux than Air warming. Soil warming caused rapid permafrost thaw and increased ecosystem respiration (R eco), gross primary productivity (GPP), and net summer CO 2 storage (NEE). Over 7 years R eco, GPP, and NEE also increasedmore » in Control (i.e., ambient plots), but this change could be explained by slow thaw in Control areas. In the initial stages of thaw, R eco, GPP, and NEE increased linearly with thaw across all treatments, despite different rates of thaw. As thaw in Soil warming continued to increase linearly, ground surface subsidence created saturated microsites and suppressed R eco, GPP, and NEE. However R eco and GPP remained high in areas with large Eriophorum vaginatum biomass. In general NEE increased with thaw, but was more strongly correlated with plant biomass than thaw, indicating that higher R eco in deeply thawed areas during summer months was balanced by GPP. Summer CO 2 flux across treatments fit a single quadratic relationship that captured the functional response of CO 2 flux to thaw, water table depth, and plant biomass. These results demonstrate the importance of indirect thaw effects on CO 2 flux: plant growth and water table dynamics. Nonsummer R eco models estimated that the area was an annual CO 2 source during all years of observation. As a result, nonsummer CO 2 loss in warmer, more deeply thawed soils exceeded the increases in summer GPP, and thawed tundra was a net annual CO 2 source.« less </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28208232','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28208232">Nonlinear CO2 flux response to 7 years of experimentally induced permafrost thaw.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Mauritz, Marguerite; Bracho, Rosvel; Celis, Gerardo; Hutchings, Jack; Natali, Susan M; Pegoraro, Elaine; Salmon, Verity G; Schädel, Christina; Webb, Elizabeth E; Schuur, Edward A G 2017-09-01 Rapid Arctic warming is expected to increase global greenhouse gas concentrations as permafrost thaw exposes immense stores of frozen carbon (C) to microbial decomposition. Permafrost thaw also stimulates plant growth, which could offset C loss. Using data from 7 years of experimental Air and Soil warming in moist acidic tundra, we show that Soil warming had a much stronger effect on CO 2 flux than Air warming. Soil warming caused rapid permafrost thaw and increased ecosystem respiration (R eco ), gross primary productivity (GPP), and net summer CO 2 storage (NEE). Over 7 years R eco , GPP, and NEE also increased in Control (i.e., ambient plots), but this change could be explained by slow thaw in Control areas. In the initial stages of thaw, R eco , GPP, and NEE increased linearly with thaw across all treatments, despite different rates of thaw. As thaw in Soil warming continued to increase linearly, ground surface subsidence created saturated microsites and suppressed R eco , GPP, and NEE. However R eco and GPP remained high in areas with large Eriophorum vaginatum biomass. In general NEE increased with thaw, but was more strongly correlated with plant biomass than thaw, indicating that higher R eco in deeply thawed areas during summer months was balanced by GPP. Summer CO 2 flux across treatments fit a single quadratic relationship that captured the functional response of CO 2 flux to thaw, water table depth, and plant biomass. These results demonstrate the importance of indirect thaw effects on CO 2 flux: plant growth and water table dynamics. Nonsummer R eco models estimated that the area was an annual CO 2 source during all years of observation. Nonsummer CO 2 loss in warmer, more deeply thawed soils exceeded the increases in summer GPP, and thawed tundra was a net annual CO 2 source. © 2017 John Wiley & Sons Ltd. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016EGUGA..18.2264C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016EGUGA..18.2264C">METEOPOLE-FLUX: an observatory of terrestrial water, energy, and CO2 fluxes in Toulouse</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Calvet, Jean-Christophe; Roujean, Jean-Louis; Zhang, Sibo; Maurel, William; Piguet, Bruno; Barrié, Joël; Bouhours, Gilles; Couzinier, Jacques; Garrouste, Olivier; Girres, Sandrine; Suquia, David; Tzanos, Diane 2016-04-01 The METEOPOLE-FLUX project (http://www.cnrm.meteo.fr/spip.php?article874&lang=en) aims at monitoring a large suburban set-aside field in the city of Toulouse (43.572898 N, 1.374384 E). Since June 2012, these data contribute to the international effort to monitor terrestrial ecosystems (grasslands in particular), to the validation of land surface models, and to the near real time quality monitoring of operational weather forecast models. Various variables are monitored at a subhourly rate: wind speed, air temperature, air humidity, atmospheric pressure, precipitation, turbulent fluxes (H, LE, CO2), downwelling and upwelling solar and infrared radiation, downwelling and upwelling PAR, fraction of diffuse incoming PAR, presence of water intercepted by vegetation (rain, dew), soil moisture profile, soil temperature profile, surface albedo, transmissivity of PAR in vegetation canopy. Moreover, local observations are performed using remote sensing techniques: infrared radiometry, GNSS reflectometry, and multi-band surface reflectometry using an aerosol photometer from the AERONET network. Destructive measurements of LAI, green/brown above-ground biomass, and necromass are performed twice a year. This site is characterized by a large fraction of gravels and stones in the soil, ranging from 17% to 35% in the top soil layer (down to 0.6 m), and peaking at 81% at 0.7 m. The impact of gravels and stones on thermal and moisture fluxes in the soil has not been much addressed in the past and is not represented in most land surface models. Their impact on the available water content for plant transpiration and plant growth is not much documented so far. The long term monitoring of this site will therefore improve the knowledge on land processes. The data will be used together with urban meteorological data to characterize the urban heat island. Finally, this site will be used for the CAL/VAL of various satellite products in conjunction with the SMOSMANIA soil moisture network </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017JMS...173...70C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017JMS...173...70C">Air-sea CO2 fluxes for the Brazilian northeast continental shelf in a climatic transition region</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Carvalho, A. C. O.; Marins, R. V.; Dias, F. J. S.; Rezende, C. E.; Lefèvre, N.; Cavalcante, M. S.; Eschrique, S. A. 2017-09-01 Oceanographic cruises were carried out in October 2012 (3°S-5°S and 38,5°W-35,5°W) and in September 2014 (1°S-4°S and 43°W-37°W), measuring atmospheric and sea surface CO2 fugacity (fCO2) underway in the northeast coast of Brazil. Sea surface water samples were also collected for chlorophyll a, nutrients and DOC analysis. During the second cruise, the sampling area covered a transition between semi-arid to more humid areas of the coast, with different hydrologic and rainfall regimes. The seawater fCO2sw, in October 2012, was in average 400.9 ± 7.3μatm and 391.1 ± 6.3 μatm in September 2014. For the atmosphere, the fCO2air in October 2012 was 375.8 ± 2.0 μatm and in September 2014, 368.9 ± 2.2 μatm. The super-saturation of the seawater in relation to the atmosphere indicates a source of CO2 to the atmosphere. The entire study area presents oligotrophic conditions. Despite the low concentrations, Chl a and nutrients presented significant influence on fCO2sw, particularly in the westernmost and more humid part of the northeast coast, where river fluxes are three orders of magnitude larger than eastern rivers and rainfall events are more intense and constant. fCO2sw spatial distribution presented homogeneity along the same transect and longitudinal heterogeneity, between east and west, reinforcing the hypothesis of transition between two regions of different behaviour. The fCO2sw at the eastern portion was controlled by parameters such as temperature and salinity. At the western portion, fCO2sw was influenced by nutrient and Chl a. Calculated instantaneous CO2 flux ranged from + 1.66 to + 7.24 mmol m- 2 d- 1 in the first cruise and + 0.89 to + 14.62 mmol m- 2 d- 1 in the second cruise. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014ACPD...1422587Z','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014ACPD...1422587Z">Constraining terrestrial ecosystem CO2 fluxes by integrating models of biogeochemistry and atmospheric transport and data of surface carbon fluxes and atmospheric CO2 concentrations</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Zhu, Q.; Zhuang, Q.; Henze, D.; Bowman, K.; Chen, M.; Liu, Y.; He, Y.; Matsueda, H.; Machida, T.; Sawa, Y.; Oechel, W. 2014-09-01 Regional net carbon fluxes of terrestrial ecosystems could be estimated with either biogeochemistry models by assimilating surface carbon flux measurements or atmospheric CO2 inversions by assimilating observations of atmospheric CO2 concentrations. Here we combine the ecosystem biogeochemistry modeling and atmospheric CO2 inverse modeling to investigate the magnitude and spatial distribution of the terrestrial ecosystem CO2 sources and sinks. First, we constrain a terrestrial ecosystem model (TEM) at site level by assimilating the observed net ecosystem production (NEP) for various plant functional types. We find that the uncertainties of model parameters are reduced up to 90% and model predictability is greatly improved for all the plant functional types (coefficients of determination are enhanced up to 0.73). We then extrapolate the model to a global scale at a 0.5° × 0.5° resolution to estimate the large-scale terrestrial ecosystem CO2 fluxes, which serve as prior for atmospheric CO2 inversion. Second, we constrain the large-scale terrestrial CO2 fluxes by assimilating the GLOBALVIEW-CO2 and mid-tropospheric CO2 retrievals from the Atmospheric Infrared Sounder (AIRS) into an atmospheric transport model (GEOS-Chem). The transport inversion estimates that: (1) the annual terrestrial ecosystem carbon sink in 2003 is -2.47 Pg C yr-1, which agrees reasonably well with the most recent inter-comparison studies of CO2 inversions (-2.82 Pg C yr-1); (2) North America temperate, Europe and Eurasia temperate regions act as major terrestrial carbon sinks; and (3) The posterior transport model is able to reasonably reproduce the atmospheric CO2 concentrations, which are validated against Comprehensive Observation Network for TRace gases by AIrLiner (CONTRAIL) CO2 concentration data. This study indicates that biogeochemistry modeling or atmospheric transport and inverse modeling alone might not be able to well quantify regional terrestrial carbon fluxes. However, combining </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2006AGUSM.U32A..01G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2006AGUSM.U32A..01G">Measurement of Urban fluxes of CO2 and water</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Grimmond, S.; Crawford, B.; Offerle, B.; Hom, J. 2006-05-01 Measurements of surface-atmosphere fluxes of carbon dioxide (FCO2) and latent heat in urban environments are rare even though cities are a major source of atmospheric CO2 and users of water. In this paper, an overview of urban FCO2 measurements will be presented to illustrate how and where such measurements are being conducted and emerging results to date. Most of these studies have been conducted over short periods of time; few studies have considered annual sources/sinks. More investigations have been conducted, and are planned, in European cities than elsewhere, most commonly in areas of medium density urban development. The most dense urban sites are significant net sources of carbon. However, in areas where there is large amounts of vegetation present, there is a net sink of carbon during the summertime. In the second part of the presentation, more detailed attention will be directed to an ongoing measurement program in Baltimore, MD (part of the Baltimore Ecosystem Study). Eddy covariance instrumentation mounted on a tall-tower at 41.2 m has continuously measured local-scale fluxes of carbon dioxide from a suburban environment since 2001. Several features make this particular study unique: 1) for an urban area, the study site is extensively vegetated, 2) the period of record (2001-2005) is among the longest available for urban FCO2 measurements, 3) both closed-path and open-path infrared gas analyzers are used for observations, and 4) several unique data quality control and gap-filling methods have been developed for use in an urban environment. Additionally, detailed surface datasets and GIS software are used to perform flux source area analysis. Results from Baltimore indicate that FCO2 is very dependent on source area land-cover characteristics, particularly the proportion of vegetated and built surfaces. Over the course of a year, the urban surface is a strong net source of CO2, though there is considerable inter-annual variability depending on </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/23778238','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/23778238">An inorganic CO2 diffusion and dissolution process explains negative CO2 fluxes in saline/alkaline soils.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Ma, Jie; Wang, Zhong-Yuan; Stevenson, Bryan A; Zheng, Xin-Jun; Li, Yan 2013-01-01 An 'anomalous' negative flux, in which carbon dioxide (CO2) enters rather than is released from the ground, was studied in a saline/alkaline soil. Soil sterilization disclosed an inorganic process of CO2 dissolution into (during the night) and out of (during the day) the soil solution, driven by variation in soil temperature. Experimental and modeling analysis revealed that pH and soil moisture were the most important determinants of the magnitude of this inorganic CO2 flux. In the extreme cases of air-dried saline/alkaline soils, this inorganic process was predominant. While the diurnal flux measured was zero sum, leaching of the dissolved inorganic carbon in the soil solution could potentially effect net carbon ecosystem exchange. This finding implies that an inorganic module should be incorporated when dealing with the CO2 flux of saline/alkaline land. Neglecting this inorganic flux may induce erroneous or misleading conclusions in interpreting CO2 fluxes of these ecosystems. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3685845','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3685845">An inorganic CO2 diffusion and dissolution process explains negative CO2 fluxes in saline/alkaline soils</a> <a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Ma, Jie; Wang, Zhong-Yuan; Stevenson, Bryan A.; Zheng, Xin-Jun; Li, Yan 2013-01-01 An ‘anomalous' negative flux, in which carbon dioxide (CO2) enters rather than is released from the ground, was studied in a saline/alkaline soil. Soil sterilization disclosed an inorganic process of CO2 dissolution into (during the night) and out of (during the day) the soil solution, driven by variation in soil temperature. Experimental and modeling analysis revealed that pH and soil moisture were the most important determinants of the magnitude of this inorganic CO2 flux. In the extreme cases of air-dried saline/alkaline soils, this inorganic process was predominant. While the diurnal flux measured was zero sum, leaching of the dissolved inorganic carbon in the soil solution could potentially effect net carbon ecosystem exchange. This finding implies that an inorganic module should be incorporated when dealing with the CO2 flux of saline/alkaline land. Neglecting this inorganic flux may induce erroneous or misleading conclusions in interpreting CO2 fluxes of these ecosystems. PMID:23778238 </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014EGUGA..1613217Q','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014EGUGA..1613217Q">Temporal changes in soil water repellency linked to the soil respiration and CH4 and CO2 fluxes</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Qassem, Khalid; Urbanek, Emilia; van Keulen, Geertje 2014-05-01 Soil water repellency (SWR) is known to be a spatially and temporally variable phenomenon. The seasonal changes in soil moisture lead to development of soil water repellency, which in consequence may affect the microbial activity and in consequence alter the CO2 and CH4 fluxes from soils. Soil microbial activity is strongly linked to the temperature and moisture status of the soil. In terms of CO2 flux intermediate moisture contents are most favourable for the optimal microbial activity and highest CO2 fluxes. Methanogenesis occurs primarily in anaerobic water-logged habitats while methanotrophy is a strictly aerobic process. In the study we hypothesise that the changes in CO2 and CH4 fluxes are closely linked to critical moisture thresholds for soil water repellency. This research project aims to adopt a multi-disciplinary approach to comprehensively determine the effect of SWR on CO2 and CH4 fluxes. Research is conducted in situ at four sites exhibiting SWR in the southern UK. Flux measurements are carried out concomitant with meteorological and SWR observations Field observations are supported by laboratory measurements carried out on intact soil samples collected at the above identified field sites. The laboratory analyses are conducted under constant temperatures with controlled changes of soil moisture content. Methanogenic and Methanotrophic microbial populations are being analysed at different SWR and moisture contents using the latest metagenomic and metatranscriptomic approaches. Currently available data show that greenhouse gas flux are closely linked with soil moisture thresholds for SWR development. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=19830046452&hterms=water+gas+exchange&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D20%26Ntt%3Dwater%2Bgas%2Bexchange','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=19830046452&hterms=water+gas+exchange&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D20%26Ntt%3Dwater%2Bgas%2Bexchange">Methane flux across the air-water interface - Air velocity effects</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Sebacher, D. I.; Harriss, R. C.; Bartlett, K. B. 1983-01-01 Methane loss to the atmosphere from flooded wetlands is influenced by the degree of supersaturation and wind stress at the water surface. Measurements in freshwater ponds in the St. Marks Wildlife Refuge, Florida, demonstrated that for the combined variability of CH4 concentrations in surface water and air velocity over the water surface, CH4 flux varied from 0.01 to 1.22 g/sq m/day. The liquid exchange coefficient for a two-layer model of the gas-liquid interface was calculated as 1.7 cm/h for CH4 at air velocity of zero and as 1.1 + 1.2 v to the 1.96th power cm/h for air velocities from 1.4 to 3.5 m/s and water temperatures of 20 C. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015ECSS..166...13L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015ECSS..166...13L">Net ecosystem production, calcification and CO2 fluxes on a reef flat in Northeastern Brazil</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Longhini, Cybelle M.; Souza, Marcelo F. L.; Silva, Ananda M. 2015-12-01 The carbon cycle in coral reefs is usually dominated by the organic carbon metabolism and precipitation-dissolution of CaCO3, processes that control the CO2 partial pressure (pCO2) in seawater and the CO2 fluxes through the air-sea interface. In order to characterize these processes and the carbonate system, four sampling surveys were conducted at the reef flat of Coroa Vermelha during low tide (exposed flat). Net ecosystem production (NEP), net precipitation-dissolution of CaCO3 (G) and CO2 fluxes across the air-water interface were calculated. The reef presented net autotrophy and calcification at daytime low tide. The NEP ranged from -8.7 to 31.6 mmol C m-2 h-1 and calcification from -13.1 to 26.0 mmol C m-2 h-1. The highest calcification rates occurred in August 2007, coinciding with the greater NEP rates. The daytime CO2 fluxes varied from -9.7 to 22.6 μmol CO2 m-2 h-1, but reached up to 13,900 μmol CO2 m-2 h-1 during nighttime. Carbon dioxide influx to seawater was predominant in the reef flat during low tide. The regions adjacent to the reef showed a supersaturation of CO2, acting as a source of CO2 to the atmosphere (from -22.8 to -2.6 mol CO2 m-2 h-1) in the reef flat during ebbing tide. Nighttime gas release to the atmosphere indicates a net CO2 release from the Coroa Vermelha reef flat within 24 h, and that these fluxes can be important to carbon budget in coral reefs. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://hdl.handle.net/2060/20140005809','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20140005809">CO2 Flux Estimation Errors Associated with Moist Atmospheric Processes</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Parazoo, N. C.; Denning, A. S.; Kawa, S. R.; Pawson, S.; Lokupitiya, R. 2012-01-01 Vertical transport by moist sub-grid scale processes such as deep convection is a well-known source of uncertainty in CO2 source/sink inversion. However, a dynamical link between vertical transport, satellite based retrievals of column mole fractions of CO2, and source/sink inversion has not yet been established. By using the same offline transport model with meteorological fields from slightly different data assimilation systems, we examine sensitivity of frontal CO2 transport and retrieved fluxes to different parameterizations of sub-grid vertical transport. We find that frontal transport feeds off background vertical CO2 gradients, which are modulated by sub-grid vertical transport. The implication for source/sink estimation is two-fold. First, CO2 variations contained in moist poleward moving air masses are systematically different from variations in dry equatorward moving air. Moist poleward transport is hidden from orbital sensors on satellites, causing a sampling bias, which leads directly to small but systematic flux retrieval errors in northern mid-latitudes. Second, differences in the representation of moist sub-grid vertical transport in GEOS-4 and GEOS-5 meteorological fields cause differences in vertical gradients of CO2, which leads to systematic differences in moist poleward and dry equatorward CO2 transport and therefore the fraction of CO2 variations hidden in moist air from satellites. As a result, sampling biases are amplified and regional scale flux errors enhanced, most notably in Europe (0.43+/-0.35 PgC /yr). These results, cast from the perspective of moist frontal transport processes, support previous arguments that the vertical gradient of CO2 is a major source of uncertainty in source/sink inversion. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1167255','SCIGOV-DOEDE'); return false;" href="https://www.osti.gov/servlets/purl/1167255">CO2 CH4 flux Air temperature Soil temperature and Soil moisture, Barrow, Alaska 2013 ver. 1</a> <a target="_blank" href="http://www.osti.gov/dataexplorer">DOE Data Explorer</a> Margaret Torn 2015-01-14 This dataset consists of field measurements of CO2 and CH4 flux, as well as soil properties made during 2013 in Areas A-D of Intensive Site 1 at the Next-Generation Ecosystem Experiments (NGEE) Arctic site near Barrow, Alaska. Included are i) measurements of CO2 and CH4 flux made from June to September (ii) Calculation of corresponding Gross Primary Productivity (GPP) and CH4 exchange (transparent minus opaque) between atmosphere and the ecosystem (ii) Measurements of Los Gatos Research (LGR) chamber air temperature made from June to September (ii) measurements of surface layer depth, type of surface layer, soil temperature and soil moisture from June to September. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/biblio/467708-measurements-co-sub-fluxes-bubbles-from-tower-during-asgasex','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/467708-measurements-co-sub-fluxes-bubbles-from-tower-during-asgasex">Measurements of CO{sub 2} fluxes and bubbles from a tower during ASGASEX</a> <a target="_blank" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Leeuw, G. de; Kunz, G.J.; Larsen, S.E. 1994-12-31 The Air-Sea Gas Exchange experiment ASGASEX was conducted from August 30 until October 1st from the Meetpost Noordwijk (MPN), a research tower in the North Sea at 9 km from the Dutch coast. The objective of ASGASEX was a study of parameters affecting the air-sea exchange of gases, and a comparison of experimental methods to derive the exchange coefficient for CO{sub 2}. A detailed description of the ASGASEX experiment is presented in Oost. The authors` contribution to ASGASEX was a micro-meteorological package to measure the fluxes of CO{sub 2}, momentum, heat and water vapor, and an instrument to measure themore » size distribution of bubbles just below the sea surface. In this contribution the authors report preliminary results from the CO{sub 2} flux measurements and the bubble measurements. The latter was made as part of a larger study on the influence of bubbles on gas exchange in cooperation with the University of Southampton and the University of Galway.« less </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/26785557','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/26785557">[Effects of brackish water irrigation on soil enzyme activity, soil CO2 flux and organic matter decomposition].</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Zhang, Qian-qian; Wang, Fei; Liu, Tao; Chu, Gui-xin 2015-09-01 Brackish water irrigation utilization is an important way to alleviate water resource shortage in arid region. A field-plot experiment was set up to study the impact of the salinity level (0.31, 3.0 or 5.0 g · L(-1) NaCl) of irrigated water on activities of soil catalase, invertase, β-glucosidase, cellulase and polyphenoloxidase in drip irrigation condition, and the responses of soil CO2 flux and organic matter decomposition were also determined by soil carbon dioxide flux instrument (LI-8100) and nylon net bag method. The results showed that in contrast with fresh water irrigation treatment (CK), the activities of invertase, β-glucosidase and cellulase in the brackish water (3.0 g · L(-1)) irrigation treatment declined by 31.7%-32.4%, 29.7%-31.6%, 20.8%-24.3%, respectively, while soil polyphenoloxidase activity was obviously enhanced with increasing the salinity level of irrigated water. Compared to CK, polyphenoloxidase activity increased by 2.4% and 20.5%, respectively, in the brackish water and saline water irrigation treatments. Both soil microbial biomass carbon and microbial quotient decreased with increasing the salinity level, whereas, microbial metabolic quotient showed an increasing tendency with increasing the salinity level. Soil CO2 fluxes in the different treatments were in the order of CK (0.31 g · L(-1)) > brackish water irrigation (3.0 g · L(-1)) ≥ saline water irrigation (5.0 g · L(-1)). Moreover, CO2 flux from plastic film mulched soil was always much higher than that from no plastic film mulched soil, regardless the salinity of irrigated water. Compared with CK, soil CO2 fluxes in the saline water and brackish water treatments decreased by 29.8% and 28.2% respectively in the boll opening period. The decomposition of either cotton straw or alfalfa straw in the different treatments was in the sequence of CK (0.31 g · L(-1)) > brackish water irrigation (3.0 g · L(-1)) > saline water treatment (5.0 g · L(-1)). The organic matter </li> <li> <a target="_blank" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=19860037918&hterms=water+cycle&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D80%26Ntt%3Dwater%2Bcycle','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=19860037918&hterms=water+cycle&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D80%26Ntt%3Dwater%2Bcycle">The Martian hydrologic cycle - Effects of CO2 mass flux on global water distribution</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> James, P. B. 1985-01-01 The Martian CO2 cycle, which includes the seasonal condensation and subsequent sublimation of up to 30 percent of the planet's atmosphere, produces meridional winds due to the consequent mass flux of CO2. These winds currently display strong seasonal and hemispheric asymmetries due to the large asymmetries in the distribution of insolation on Mars. It is proposed that asymmetric meridional advection of water vapor on the planet due to these CO2 condensation winds is capable of explaining the observed dessication of Mars' south polar region at the current time. A simple model for water vapor transport is used to verify this hypothesis and to speculate on the effects of changes in orbital parameters on the seasonal water cycle. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.A41E2327D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.A41E2327D">Controlling factors of evaporation and CO2 flux over an open water lake in southeastern margin of Tibetan Plateau</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Du, Q.; Liu, H.; Liu, Y.; Wang, L.; Xu, L. 2017-12-01 Erhai lake is located in the southeastern margin of Tibetan Plateau. Based on the 4 years measurement over Erhai lake with eddy covariance technique (EC) from 2012 to 2015, the diurnal and seasonal variations of latent and sensible heat and CO2 fluxes, and their controlling factors over different time scales were analyzed. The diurnal average LE ranged from 31 to 171 Wm-2, while Hs ranged from -31 to 21 Wm-2. Bowen ratio was larger during January and May and smaller during June and October. The lake continued storing heat during January and June, and releasing heat since July. The diurnal average CO2 fluxes during nighttime were higher than the daytime, and carbon uptake was almost observed during the midday time of the day for the whole study period. The annual carbon budget fluctuated from 117.5 to 161.7 g C m-2 a-1, while annual total evaporation (ET) from 1120.8 to 1228.5 mm for the four-years period. The Erhai Lake behaved as a net carbon source over the whole period but carbon uptake was observed during the middle time of each year. The difference between water surface and air temperature (DeltaT) and the product of DeltaT and wind speed were the main controlling factors for Hs from halfhourly to monthly scale. There was significant relationship between wind speed, the product of wind speed and vapor pressure deficit (VPD) and LE on halfhourly and daily scales. The total cloud amount and net radiation (Rn) had a large effect on monthly variation of LE. Photosynthetic active radiation (PAR) and wind speed was mainly responsible for the variation of halfhourly and daily CO2 fluxes, respectively. The total cloud amount was the most important factors controlling for annual total ET. The annual rainfall, water surface temperature was observed to be negatively related with annual CO2 fluxes. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_1");'>1</a></li> <li><a href="#" onclick='return showDiv("page_2");'>2</a></li> <li class="active">3</li> <li><a href="#" onclick='return showDiv("page_4");'>4</a></li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_4" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_2");'>2</a></li> <li><a href="#" onclick='return showDiv("page_3");'>3</a></li> <li class="active">4</li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li><a href="#" onclick='return showDiv("page_6");'>6</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="61"> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011AGUFM.A43H..07F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011AGUFM.A43H..07F">Evaluation of NASA's Carbon Monitoring System (CMS) Flux Pilot: Terrestrial CO2 Fluxes</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Fisher, J. B.; Polhamus, A.; Bowman, K. W.; Collatz, G. J.; Potter, C. S.; Lee, M.; Liu, J.; Jung, M.; Reichstein, M. 2011-12-01 NASA's Carbon Monitoring System (CMS) flux pilot project combines NASA's Earth System models in land, ocean and atmosphere to track surface CO2 fluxes. The system is constrained by atmospheric measurements of XCO2 from the Japanese GOSAT satellite, giving a "big picture" view of total CO2 in Earth's atmosphere. Combining two land models (CASA-Ames and CASA-GFED), two ocean models (ECCO2 and NOBM) and two atmospheric chemistry and inversion models (GEOS-5 and GEOS-Chem), the system brings together the stand-alone component models of the Earth System, all of which are run diagnostically constrained by a multitude of other remotely sensed data. Here, we evaluate the biospheric land surface CO2 fluxes (i.e., net ecosystem exchange, NEE) as estimated from the atmospheric flux inversion. We compare against the prior bottom-up estimates (e.g., the CASA models) as well. Our evaluation dataset is the independently derived global wall-to-wall MPI-BGC product, which uses a machine learning algorithm and model tree ensemble to "scale-up" a network of in situ CO2 flux measurements from 253 globally-distributed sites in the FLUXNET network. The measurements are based on the eddy covariance method, which uses observations of co-varying fluxes of CO2 (and water and energy) from instruments on towers extending above ecosystem canopies; the towers integrate fluxes over large spatial areas (~1 km2). We present global maps of CO2 fluxes and differences between products, summaries of fluxes by TRANSCOM region, country, latitude, and biome type, and assess the time series, including timing of minimum and maximum fluxes. This evaluation shows both where the CMS is performing well, and where improvements should be directed in further work. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://hdl.handle.net/2060/20010022991','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20010022991">BOREAS TF-3 Automated Chamber CO2 Flux Data from the NSA-OBS</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Goulden, Michael L.; Crill, Patrick M.; Hall, Forrest G. (Editor); Conrad, Sara (Editor) 2000-01-01 The BOReal Ecosystem Atmosphere Study Tower Flux (BOREAS TF-3) and Trace Gas Biogeochemistry (TGB-1) teams collected automated CO2 chamber flux data in their efforts to fully describe the CO2 flux at the Northern Study Area-Old Black Spruce (NSA-OBS) site. This data set contains fluxes of CO2 at the NSA-OBS site measured using automated chambers. In addition to reporting the CO2 flux, it reports chamber air temperature, moss temperature, and light levels during each measurement. The data set covers the period from 23-Sep-1995 through 26-Oct-1995 and from 28-May-1996 through 21-Oct-1996. The data are stored in tabular ASCII files. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013BGeo...10.2699S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013BGeo...10.2699S">Coccolithophore surface distributions in the North Atlantic and their modulation of the air-sea flux of CO2 from 10 years of satellite Earth observation data</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Shutler, J. D.; Land, P. E.; Brown, C. W.; Findlay, H. S.; Donlon, C. J.; Medland, M.; Snooke, R.; Blackford, J. C. 2013-04-01 Coccolithophores are the primary oceanic phytoplankton responsible for the production of calcium carbonate (CaCO3). These climatically important plankton play a key role in the oceanic carbon cycle as a major contributor of carbon to the open ocean carbonate pump (~50%) and their calcification can affect the atmosphere-to-ocean (air-sea) uptake of carbon dioxide (CO2) through increasing the seawater partial pressure of CO2 (pCO2). Here we document variations in the areal extent of surface blooms of the globally important coccolithophore, Emiliania huxleyi, in the North Atlantic over a 10-year period (1998-2007), using Earth observation data from the Sea-viewing Wide Field-of-view Sensor (SeaWiFS). We calculate the annual mean sea surface areal coverage of E. huxleyi in the North Atlantic to be 474 000 ± 104 000 km2, which results in a net CaCO3 carbon (CaCO3-C) production of 0.14-1.71 Tg CaCO3-C per year. However, this surface coverage (and, thus, net production) can fluctuate inter-annually by -54/+8% about the mean value and is strongly correlated with the El Niño/Southern Oscillation (ENSO) climate oscillation index (r=0.75, p<0.02). Our analysis evaluates the spatial extent over which the E. huxleyi blooms in the North Atlantic can increase the pCO2 and, thus, decrease the localised air-sea flux of atmospheric CO2. In regions where the blooms are prevalent, the average reduction in the monthly air-sea CO2 flux can reach 55%. The maximum reduction of the monthly air-sea CO2 flux in the time series is 155%. This work suggests that the high variability, frequency and distribution of these calcifying plankton and their impact on pCO2 should be considered if we are to fully understand the variability of the North Atlantic air-to-sea flux of CO2. We estimate that these blooms can reduce the annual N. Atlantic net sink atmospheric CO2 by between 3-28%. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://hdl.handle.net/2060/20010022990','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20010022990">BOREAS TF-4 CO2 and CH4 Chamber Flux Data from the SSA</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Anderson, Dean; Striegl, Robert; Wickland, Kimberly; Hall, Forrest G. (Editor); Conrad, Sara (Editor) 2000-01-01 The BOREAS TF-4 team measured fluxes of CO2 and CH4 across the soil-air interface in four ages of jack pine forest at the BOREAS SSA during August 1993 to March 1995. Gross and net flux of CO2 and flux of CH4 between soil and air are presented for 24 chamber sites in mature jack pine forest, 20-year-old, 4-year-old, and clear cut areas. The data are stored in tabular ASCII files. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013EGUGA..15.8634D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013EGUGA..15.8634D">Interannual variability of primary production and air-sea CO2 flux in the Atlantic and Indian sectors of the Southern Ocean.</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Dufour, Carolina; Merlivat, Liliane; Le Sommer, Julien; Boutin, Jacqueline; Antoine, David 2013-04-01 As one of the major oceanic sinks of anthropogenic CO2, the Southern Ocean plays a critical role in the climate system. However, due to the scarcity of observations, little is known about physical and biological processes that control air-sea CO2 fluxes and how these processes might respond to climate change. It is well established that primary production is one of the major drivers of air-sea CO2 fluxes, consuming surface Dissolved Inorganic Carbon (DIC) during Summer. Southern Ocean primary production is though constrained by several limiting factors such as iron and light availability, which are both sensitive to mixed layer depth. Mixed layer depth is known to be affected by current changes in wind stress or freshwater fluxes over the Southern Ocean. But we still don't know how primary production may respond to anomalous mixed layer depth neither how physical processes may balance this response to set the seasonal cycle of air-sea CO2 fluxes. In this study, we investigate the impact of anomalous mixed layer depth on surface DIC in the Atlantic and Indian sectors of the Subantarctic zone of the Southern Ocean (60W-60E, 38S-55S) with a combination of in situ data, satellite data and model experiment. We use both a regional eddy permitting ocean biogeochemical model simulation based on NEMO-PISCES and data-based reconstruction of biogeochemical fields based on CARIOCA buoys and SeaWiFS data. A decomposition of the physical and biological processes driving the seasonal variability of surface DIC is performed with both the model data and observations. A good agreement is found between the model and the data for the amplitude of biological and air-sea flux contributions. The model data are further used to investigate the impact of winter and summer anomalies in mixed layer depth on surface DIC over the period 1990-2004. The relative changes of each physical and biological process contribution are quantified and discussed. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013BGD....1015641F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013BGD....1015641F">Synoptic evaluation of carbon cycling in Beaufort Sea during summer: contrasting river inputs, ecosystem metabolism and air-sea CO2 fluxes</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Forest, A.; Coupel, P.; Else, B.; Nahavandian, S.; Lansard, B.; Raimbault, P.; Papakyriakou, T.; Gratton, Y.; Fortier, L.; Tremblay, J.-É.; Babin, M. 2013-10-01 The accelerated decline in Arctic sea ice combined with an ongoing trend toward a more dynamic atmosphere is modifying carbon cycling in the Arctic Ocean. A critical issue is to understand how net community production (NCP; the balance between gross primary production and community respiration) responds to changes and modulates air-sea CO2 fluxes. Using data collected as part of the ArcticNet-Malina 2009 expedition in southeastern Beaufort Sea (Arctic Ocean), we synthesize information on sea ice, wind, river, water column properties, metabolism of the planktonic food web, organic carbon fluxes and pools, as well as air-sea CO2 exchange, with the aim of identifying indices of ecosystem response to environmental changes. Data were analyzed to develop a non-steady-state carbon budget and an assessment of NCP against air-sea CO2 fluxes. The mean atmospheric forcing was a mild upwelling-favorable wind (~5 km h-1) blowing from the N-E and a decaying ice cover (<80% concentration) was observed beyond the shelf, the latter being fully exposed to the atmosphere. We detected some areas where the surface mixed layer was net autotrophic owing to high rates of primary production (PP), but the ecosystem was overall net heterotrophic. The region acted nonetheless as a sink for atmospheric CO2 with a mean uptake rate of -2.0 ± 3.3 mmol C m-2d-1. We attribute this discrepancy to: (1) elevated PP rates (>600 mg C m-2d-1) over the shelf prior to our survey, (2) freshwater dilution by river runoff and ice melt, and (3) the presence of cold surface waters offshore. Only the Mackenzie River delta and localized shelf areas directly affected by upwelling were identified as substantial sources of CO2 to the atmosphere (>10mmol C m-2d-1). Although generally <100 mg C m-2d-1, daily PP rates cumulated to a total PP of ~437.6 × 103 t C, which was roughly twice higher than the organic carbon delivery by river inputs (~241.2 × 103 t C). Subsurface PP represented 37.4% of total PP for the </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMOS33A1443Y','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMOS33A1443Y">Diagnosing CO2 fluxes and seasonality in the Arabian Sea as an Ocean-Dominated Margin</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Yang, W.; Dai, M. 2017-12-01 The Arabian Sea is a large marginal sea of the Indian Ocean characterized by highly predictable annual circulation cycle driven by Asian monsoon. The Arabian Sea is generally sources to atmospheric CO2. In this study, we applied the physical-biogeochemical coupled approach previously adopted for diagnosis of CO2 fluxes in Ocean-dominated margin (OceMar) to assesses the CO2 fluxes and their seasonality in Arabian Sea using data collected during five US JGOFS Arabian Sea Process Study cruises (ttn-043, ttn-045, ttn-049, ttn-053, ttn-054) conducted from September 1994 to December 1995. The pCO2 estimated during the 5 cruises was 396±5μatm, 359±7 μatm, 373±7 μatm, 379±9 μatm and 387±12 μatm, respectively, which agreed well with the pCO2 observed during the cruises of 389±8 μatm, 361±6 μatm, 366±6 μatm, 371±8 μatm and 367±11 μatm from underway measurements. This strongly suggests that our semi-analytical diagnostic approach in the OceMar framework can evaluate the pCO2 in Arabian Sea. Our coupled diagnostic approach assumes that water mass mixing, biological response and air-sea exchange under steady state over a similar time scale. This assumption should be justified at the region with intensified upwelling where decoupling between upwelling and biological response may occur, where only water mass mixing and air-sea CO2 exchange should be accounted for. This presentation will also examine the seasonality of the CO2 dynamics and its controls. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014JMS...140...26M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014JMS...140...26M">Spatio-temporal dynamics of biogeochemical processes and air-sea CO2 fluxes in the Western English Channel based on two years of FerryBox deployment</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Marrec, P.; Cariou, T.; Latimier, M.; Macé, E.; Morin, P.; Vernet, M.; Bozec, Y. 2014-12-01 From January 2011 to January 2013, a FerryBox system was installed on a Voluntary Observing Ship (VOS), which crossed the Western English Channel (WEC) between Roscoff (France) and Plymouth (UK) up to 3 times a day. The FerryBox continuously measured sea surface temperature (SST), sea surface salinity (SSS), dissolved oxygen (DO), fluorescence and partial pressure of CO2 (from April 2012) along the ferry track. Sensors were calibrated based on 714 bimonthly surface samplings with precisions of 0.016 for SSS, 3.3 μM for DO, 0.40 μg L- 1 for Chlorophyll-a (Chl-a) (based on fluorescence measurements) and 5.2 μatm for pCO2. Over the 2 years of deployment (900 crossings), we reported 9% of data lost due to technical issues and quality checked data was obtained to allow investigation of the dynamics of biogeochemical processes related to air-sea CO2 fluxes in the WEC. Based on this unprecedented high-frequency dataset, the physical structure of the WEC was assessed using SST anomalies and the presence of a thermal front was observed around the latitude 49.5°N, which divided the WEC in two main provinces: the seasonally stratified northern WEC (nWEC) and the all-year well-mixed southern WEC (sWEC). These hydrographical properties strongly influenced the spatial and inter-annual distributions of phytoplankton blooms, which were mainly limited by nutrients and light availability in the nWEC and the sWEC, respectively. Air-sea CO2 fluxes were also highly related to hydrographical properties of the WEC between late April and early September 2012, with the sWEC a weak source of CO2 to the atmosphere of 0.9 mmol m- 2 d- 1, whereas the nWEC acted as a sink for atmospheric CO2 of 6.9 mmol m- 2 d- 1. The study of short time-scale dynamics of air-sea CO2 fluxes revealed that an intense and short (less than 10 days) summer bloom in the nWEC contributed to 29% of the CO2 sink during the productive period, highlighting the necessity for high frequency observations in coastal </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2004AGUSM.B13A..01J','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2004AGUSM.B13A..01J">Modelling the Response of Energy, Water and CO2 Fluxes Over Forests to Climate Variability</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Ju, W.; Chen, J.; Liu, J.; Chen, B. 2004-05-01 Understanding the response of energy, water and CO2 fluxes of terrestrial ecosystems to climate variability at various temporal scales is of interest to climate change research. To simulate carbon (C) and water dynamics and their interactions at the continental scale with high temporal and spatial resolutions, the remote sensing driven BEPS (Boreal Ecosystem Productivity Simulator) model was updated to couple with the soil model of CENTURY and a newly developed biophysical model. This coupled model separates the whole canopy into two layers. For the top layer, the leaf-level conductance is scaled up to canopy level using a sunlit and shaded leaf separation approach. Fluxes of water, and CO{2} are simulated as the sums of those from sunlit and shaded leaves separately. This new approach allows for close coupling in modeling these fluxes. The whole profile of soil under a seasonal snowpack is split into four layers for estimating soil moisture and temperature. Long-term means of the vegetation productivity and climate are employed to initialize the carbon pools for the computation of heterotrophic respiration. Validated against tower data at four forested sites, this model is able to describe these fluxes and their response to climate variability. The model captures over 55% of year-round half/one hourly variances of these fluxes. The highest agreement of model results with tower data was achieved for CO2 flux at Southern Old Aspen (SOA) (R2>0.85 and RMSE<2.37 μ mol C m-2 s-1, N=17520). However, the model slightly overestimates the diurnal amplitude of sensible heat flux in winter and sometimes underestimates that of CO2 flux in the growing season. Model simulations suggest that C uptakes of forests are controlled by climate variability and the response of C cycle to climate depends on forest type. For SOA, the annual NPP (Net Primary Productivity) is more sensitive to temperature than to precipitation. This forest usually has higher NPP in warm years than in cool </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014BGeo...11.2827F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014BGeo...11.2827F">Synoptic evaluation of carbon cycling in the Beaufort Sea during summer: contrasting river inputs, ecosystem metabolism and air-sea CO2 fluxes</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Forest, A.; Coupel, P.; Else, B.; Nahavandian, S.; Lansard, B.; Raimbault, P.; Papakyriakou, T.; Gratton, Y.; Fortier, L.; Tremblay, J.-É.; Babin, M. 2014-05-01 The accelerated decline in Arctic sea ice and an ongoing trend toward more energetic atmospheric and oceanic forcings are modifying carbon cycling in the Arctic Ocean. A critical issue is to understand how net community production (NCP; the balance between gross primary production and community respiration) responds to changes and modulates air-sea CO2 fluxes. Using data collected as part of the ArcticNet-Malina 2009 expedition in the southeastern Beaufort Sea (Arctic Ocean), we synthesize information on sea ice, wind, river, water column properties, metabolism of the planktonic food web, organic carbon fluxes and pools, as well as air-sea CO2 exchange, with the aim of documenting the ecosystem response to environmental changes. Data were analyzed to develop a non-steady-state carbon budget and an assessment of NCP against air-sea CO2 fluxes. During the field campaign, the mean wind field was a mild upwelling-favorable wind (~ 5 km h-1) from the NE. A decaying ice cover (< 80% concentration) was observed beyond the shelf, the latter being fully exposed to the atmosphere. We detected some areas where the surface mixed layer was net autotrophic owing to high rates of primary production (PP), but the ecosystem was overall net heterotrophic. The region acted nonetheless as a sink for atmospheric CO2, with an uptake rate of -2.0 ± 3.3 mmol C m-2 d-1 (mean ± standard deviation associated with spatial variability). We attribute this discrepancy to (1) elevated PP rates (> 600 mg C m-2 d-1) over the shelf prior to our survey, (2) freshwater dilution by river runoff and ice melt, and (3) the presence of cold surface waters offshore. Only the Mackenzie River delta and localized shelf areas directly affected by upwelling were identified as substantial sources of CO2 to the atmosphere (> 10 mmol C m-2 d-1). Daily PP rates were generally < 100 mg C m-2 d-1 and cumulated to a total PP of ~ 437.6 × 103 t C for the region over a 35-day period. This amount was about twice the </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28073055','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28073055">CO2 emissions from German drinking water reservoirs.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Saidi, Helmi; Koschorreck, Matthias 2017-03-01 Globally, reservoirs are a significant source of atmospheric CO 2 . However, precise quantification of greenhouse gas emissions from drinking water reservoirs on the regional or national scale is still challenging. We calculated CO 2 fluxes for 39 German drinking water reservoirs during a period of 22years (1991-2013) using routine monitoring data in order to quantify total emission of CO 2 from drinking water reservoirs in Germany and to identify major drivers. All reservoirs were a net CO 2 source with a median flux of 167gCm -2 y -1 , which makes gaseous emissions a relevant process for the carbon budget of each reservoir. Fluxes varied seasonally with median fluxes of 13, 48, and 201gCm -2 y -1 in spring, summer, and autumn respectively. Differences between reservoirs appeared to be primarily caused by the concentration of CO 2 in the surface water rather than by the physical gas transfer coefficient. Consideration of short term fluctuations of the gas transfer coefficient due to varying wind speed had only a minor effect on the annual budgets. High CO 2 emissions only occurred in reservoirs with pH<7 and total alkalinity <0.2mEql -1 . Annual CO 2 emissions correlated exponentially with pH but not with dissolved organic carbon (DOC). There was significant correlation between land use in the catchment and CO 2 emissions. In total, German drinking water reservoirs emit 44000t of CO 2 annually, which makes them a negligible CO 2 source (<0.005% of national CO 2 emissions) in Germany. Copyright © 2017 Elsevier B.V. All rights reserved. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5031984','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5031984">A new frontier in CO2 flux measurements using a highly portable DIAL laser system</a> <a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Queiβer, Manuel; Granieri, Domenico; Burton, Mike 2016-01-01 Volcanic CO2 emissions play a key role in the geological carbon cycle, and monitoring of volcanic CO2 fluxes helps to forecast eruptions. The quantification of CO2 fluxes is challenging due to rapid dilution of magmatic CO2 in CO2-rich ambient air and the diffuse nature of many emissions, leading to large uncertainties in the global magmatic CO2 flux inventory. Here, we report measurements using a new DIAL laser remote sensing system for volcanic CO2 (CO2DIAL). Two sites in the volcanic zone of Campi Flegrei (Italy) were scanned, yielding CO2 path-amount profiles used to compute fluxes. Our results reveal a relatively high CO2 flux from Campi Flegrei, consistent with an increasing trend. Unlike previous methods, the CO2DIAL is able to measure integrated CO2 path-amounts at distances up to 2000 m using virtually any solid surface as a reflector, whilst also being highly portable. This opens a new frontier in quantification of geological and anthropogenic CO2 fluxes. PMID:27652775 </li> <li> <a target="_blank" onclick="trackOutboundLink('http://hdl.handle.net/2060/20150002122','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20150002122">Natural Air-Sea Flux of CO2 in Simulations of the NASA-GISS Climate Model: Sensitivity to the Physical Ocean Model Formulation</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Romanou, A.; Gregg, Watson W.; Romanski, J.; Kelley, M.; Bleck, R.; Healy, R.; Nazarenko, L.; Russell, G.; Schmidt, G. A.; Sun, S.; <a style="text-decoration: none; " href="javascript:void(0); " onClick="displayelement('author_20150002122'); toggleEditAbsImage('author_20150002122_show'); toggleEditAbsImage('author_20150002122_hide'); "> <img style="display:inline; width:12px; height:12px; " src="images/arrow-up.gif" width="12" height="12" border="0" alt="hide" id="author_20150002122_show"> <img style="width:12px; height:12px; display:none; " src="images/arrow-down.gif" width="12" height="12" border="0" alt="hide" id="author_20150002122_hide"> 2013-01-01 Results from twin control simulations of the preindustrial CO2 gas exchange (natural flux of CO2) between the ocean and the atmosphere are presented here using the NASA-GISS climate model, in which the same atmospheric component (modelE2) is coupled to two different ocean models, the Russell ocean model and HYCOM. Both incarnations of the GISS climate model are also coupled to the same ocean biogeochemistry module (NOBM) which estimates prognostic distributions for biotic and abiotic fields that influence the air-sea flux of CO2. Model intercomparison is carried out at equilibrium conditions and model differences are contrasted with biases from present day climatologies. Although the models agree on the spatial patterns of the air-sea flux of CO2, they disagree on the strength of the North Atlantic and Southern Ocean sinks mainly because of kinematic (winds) and chemistry (pCO2) differences rather than thermodynamic (SST) ones. Biology/chemistry dissimilarities in the models stem from the different parameterizations of advective and diffusive processes, such as overturning, mixing and horizontal tracer advection and to a lesser degree from parameterizations of biogeochemical processes such as gravitational settling and sinking. The global meridional overturning circulation illustrates much of the different behavior of the biological pump in the two models, together with differences in mixed layer depth which are responsible for different SST, DIC and nutrient distributions in the two models and consequently different atmospheric feedbacks (in the wind, net heat and freshwater fluxes into the ocean). </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016JGRC..121.1229W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016JGRC..121.1229W">On the calculation of air-sea fluxes of CO2 in the presence of temperature and salinity gradients</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Woolf, D. K.; Land, P. E.; Shutler, J. D.; Goddijn-Murphy, L. M.; Donlon, C. J. 2016-02-01 The presence of vertical temperature and salinity gradients in the upper ocean and the occurrence of variations in temperature and salinity on time scales from hours to many years complicate the calculation of the flux of carbon dioxide (CO2) across the sea surface. Temperature and salinity affect the interfacial concentration of aqueous CO2 primarily through their effect on solubility with lesser effects related to saturated vapor pressure and the relationship between fugacity and partial pressure. The effects of temperature and salinity profiles in the water column and changes in the aqueous concentration act primarily through the partitioning of the carbonate system. Climatological calculations of flux require attention to variability in the upper ocean and to the limited validity of assuming "constant chemistry" in transforming measurements to climatological values. Contrary to some recent analysis, it is shown that the effect on CO2 fluxes of a cool skin on the sea surface is large and ubiquitous. An opposing effect on calculated fluxes is related to the occurrence of warm layers near the surface; this effect can be locally large but will usually coincide with periods of low exchange. A salty skin and salinity anomalies in the upper ocean also affect CO2 flux calculations, though these haline effects are generally weaker than the thermal effects. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70021683','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70021683">Estimating lake-atmosphere CO2 exchange</a> <a target="_blank" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Anderson, D.E.; Striegl, Robert G.; Stannard, D.I.; Michmerhuizen, C.M.; McConnaughey, T.A.; LaBaugh, J.W. 1999-01-01 Lake-atmosphere CO2 flux was directly measured above a small, woodland lake using the eddy covariance technique and compared with fluxes deduced from changes in measured lake-water CO2 storage and with flux predictions from boundary-layer and surface-renewal models. Over a 3-yr period, lake-atmosphere exchanges of CO2 were measured over 5 weeks in spring, summer, and fall. Observed springtime CO2 efflux was large (2.3-2.7 ??mol m-2 s-1) immediately after lake-thaw. That efflux decreased exponentially with time to less than 0.2 ??mol m-2 s-1 within 2 weeks. Substantial interannual variability was found in the magnitudes of springtime efflux, surface water CO2 concentrations, lake CO2 storage, and meteorological conditions. Summertime measurements show a weak diurnal trend with a small average downward flux (-0.17 ??mol m-2 s-1) to the lake's surface, while late fall flux was trendless and smaller (-0.0021 ??mol m-2 s-1). Large springtime efflux afforded an opportunity to make direct measurement of lake-atmosphere fluxes well above the detection limits of eddy covariance instruments, facilitating the testing of different gas flux methodologies and air-water gas-transfer models. Although there was an overall agreement in fluxes determined by eddy covariance and those calculated from lake-water storage change in CO2, agreement was inconsistent between eddy covariance flux measurements and fluxes predicted by boundary-layer and surface-renewal models. Comparison of measured and modeled transfer velocities for CO2, along with measured and modeled cumulative CO2 flux, indicates that in most instances the surface-renewal model underpredicts actual flux. Greater underestimates were found with comparisons involving homogeneous boundary-layer models. No physical mechanism responsible for the inconsistencies was identified by analyzing coincidentally measured environmental variables. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4914144','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4914144">Lateral transport of soil carbon and land−atmosphere CO2 flux induced by water erosion in China</a> <a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Yue, Yao; Ni, Jinren; Ciais, Philippe; Piao, Shilong; Wang, Tao; Huang, Mengtian; Borthwick, Alistair G. L.; Li, Tianhong; Wang, Yichu; Chappell, Adrian; Van Oost, Kristof 2016-01-01 Soil erosion by water impacts soil organic carbon stocks and alters CO2 fluxes exchanged with the atmosphere. The role of erosion as a net sink or source of atmospheric CO2 remains highly debated, and little information is available at scales larger than small catchments or regions. This study attempts to quantify the lateral transport of soil carbon and consequent land−atmosphere CO2 fluxes at the scale of China, where severe erosion has occurred for several decades. Based on the distribution of soil erosion rates derived from detailed national surveys and soil carbon inventories, here we show that water erosion in China displaced 180 ± 80 Mt C⋅y−1 of soil organic carbon during the last two decades, and this resulted a net land sink for atmospheric CO2 of 45 ± 25 Mt C⋅y−1, equivalent to 8–37% of the terrestrial carbon sink previously assessed in China. Interestingly, the “hotspots,” largely distributed in mountainous regions in the most intensive sink areas (>40 g C⋅m−2⋅y−1), occupy only 1.5% of the total area suffering water erosion, but contribute 19.3% to the national erosion-induced CO2 sink. The erosion-induced CO2 sink underwent a remarkable reduction of about 16% from the middle 1990s to the early 2010s, due to diminishing erosion after the implementation of large-scale soil conservation programs. These findings demonstrate the necessity of including erosion-induced CO2 in the terrestrial budget, hence reducing the level of uncertainty. PMID:27247397 </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016PNAS..113.6617Y','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016PNAS..113.6617Y">Lateral transport of soil carbon and land-atmosphere CO2 flux induced by water erosion in China</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Yue, Yao; Ni, Jinren; Ciais, Philippe; Piao, Shilong; Wang, Tao; Huang, Mengtian; Borthwick, Alistair G. L.; Li, Tianhong; Wang, Yichu; Chappell, Adrian; Van Oost, Kristof 2016-06-01 Soil erosion by water impacts soil organic carbon stocks and alters CO2 fluxes exchanged with the atmosphere. The role of erosion as a net sink or source of atmospheric CO2 remains highly debated, and little information is available at scales larger than small catchments or regions. This study attempts to quantify the lateral transport of soil carbon and consequent land-atmosphere CO2 fluxes at the scale of China, where severe erosion has occurred for several decades. Based on the distribution of soil erosion rates derived from detailed national surveys and soil carbon inventories, here we show that water erosion in China displaced 180 ± 80 Mt Cṡy-1 of soil organic carbon during the last two decades, and this resulted a net land sink for atmospheric CO2 of 45 ± 25 Mt Cṡy-1, equivalent to 8-37% of the terrestrial carbon sink previously assessed in China. Interestingly, the “hotspots,” largely distributed in mountainous regions in the most intensive sink areas (>40 g Cṡm-2ṡy-1), occupy only 1.5% of the total area suffering water erosion, but contribute 19.3% to the national erosion-induced CO2 sink. The erosion-induced CO2 sink underwent a remarkable reduction of about 16% from the middle 1990s to the early 2010s, due to diminishing erosion after the implementation of large-scale soil conservation programs. These findings demonstrate the necessity of including erosion-induced CO2 in the terrestrial budget, hence reducing the level of uncertainty. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014EGUGA..16..583M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014EGUGA..16..583M">Dynamics of air-sea CO2 fluxes based on FerryBox measurements and satellite-based prediction of pCO2 in the Western English Channel</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Marrec, Pierre; Thierry, Cariou; Eric, Mace; Pascal, Morin; Marc, Vernet; Yann, Bozec 2014-05-01 Since April 2012, we installed an autonomous FerryBox system on a Voluntary Observing Ship (VOS), which crosses the Western English Channel (WEC) between Roscoff and Plymouth on a daily basis. High-frequency data of sea surface temperature (SST), salinity (SSS), fluorescence, dissolved oxygen (DO) and partial pressure of CO2 (pCO2) were recorded for two years across the all-year mixed southern WEC (sWEC) and the seasonally stratified northern WEC (nWEC). These contrasting hydrographical provinces strongly influenced the spatio-temporal distributions of pCO2 and air-sea CO2 fluxes. During the productive period (from May to September), the nWEC acted as a sink for atmospheric CO2 of -5.6 mmolC m-2 d-1 and -4.6 mmolC m-2 d-1, in 2012 and 2013, respectively. During the same period, the sWEC showed significant inter-annual variability degassing CO2 to the atmosphere in 2012 (1.4 mmolC m-2 d-1) and absorbing atmospheric CO2 in 2013 (-1.6 mmolC m-2 d-1). In 2012, high-frequency data revealed that an intense and short (less than 10 days) summer phytoplankton bloom in the nWEC contributed to 31% of the total CO2 drawdown during the productive period, highlighting the necessity of pCO2 high-frequency measurements in coastal ecosystems. Based on this multi-annual dataset, we developed pCO2 algorithms using multiple linear regression (MLR) based on SST, SSS, chlorophyll-a (Chl-a) concentration, time, latitude and mixed layer depth to predict pCO2 in the two hydrographical provinces of the WEC. MLR were performed based on more than 200,000 underway observations spanning the range from 150 to 480 µatm. The root mean square errors (RMSE) of the MLR fit to the data were 17.2 µatm and 21.5 µatm for the s WEC and the nWEC with correlation coefficient (r²) of 0.71 and 0.79, respectively. We applied these algorithms to satellite SST and Chl-a products and to modeled SSS estimates in the entire WEC. Based on these high-frequency and satellite approaches, we will discuss the main </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/biblio/351688-sensing-flux-volatile-chemicals-through-air-water-interface','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/351688-sensing-flux-volatile-chemicals-through-air-water-interface">Sensing the flux of volatile chemicals through the air-water interface</a> <a target="_blank" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Mackay, D.; Schroeder, W.H.; Ooijen, H. von 1997-12-31 There are several situations in which there is a need to assess the direction and magnitude of the flux across the air-water interface. Contaminants may be evaporating or absorbing in wastewater treatment systems in natural lake, river, estuarine and marine systems, and any attempt to compile a mass balance must include this process. In this study the authors review the theory underlying air-water exchange, then describe and discuss a sparging approach by which the direction and magnitude of the flux can be ascertained. The principle of the method is that a known flow rate of air is bubbled through themore » sparger and allowed to equilibrate with the water. The gas exiting the water surface is passed through a sorbent trap and later analyzed. The concentration, and hence the fugacity, of the contaminant in the sparged air can be deduced. In parallel, a similar flow of air from the atmosphere above the water is drawn through another sparger at a similar flow rate for a similar time and the trapped chemical analyzed giving the concentration and fugacity in the air. These data show the direction of air-water exchange (i.e. from high to low fugacity) and with information on the mass transfer coefficients and area, the flux. Successful tests were conducted of the system in a laboratory tank, in Lake Ontario and in Hamilton Harbour. Analyses of the traps showed a large number of peaks on the chromatogram many of which are believed to be of petroleum origin from fuels and vessel exhaust. The system will perform best under conditions where concentrations of specific contaminants are large, as occurs in waste water treatment systems. The approach has the potential to contribute to more accurate assessment of air-water fluxes. It avoids the problems of different analytical methodologies and the effect of sorption in the water column.« less </li> <li> <a target="_blank" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20140002146&hterms=climate+change+ocean&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D70%26Ntt%3Dclimate%2Bchange%2Bocean','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20140002146&hterms=climate+change+ocean&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D70%26Ntt%3Dclimate%2Bchange%2Bocean">Monitoring Ocean CO2 Fluxes from Space: GOSAT and OCO-2</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Crisp, David 2012-01-01 The ocean is a major component of the global carbon cycle, emitting over 330 billion tons of carbon dioxide (CO2) into the atmosphere each year, or about 10 times that emitted fossil fuel combustion and all other human activities [1, 2]. The ocean reabsorbs a comparable amount of CO2 each year, along with 25% of the CO2 emitted by these human activities. The nature and geographic distribution of the processes controlling these ocean CO2 fluxes are still poorly constrained by observations. A better understanding of these processes is essential to predict how this important CO2 sink may evolve as the climate changes.While in situ measurements of ocean CO2 fluxes can be very precise, the sampling density is far too sparse to quantify ocean CO2 sources and sinks over much of the globe. One way to improve the spatial resolution, coverage, and sampling frequency is to make observations of the column averaged CO2 dry air mole fraction, XCO2, from space [4, 5, 6]. Such measurements could provide global coverage at high resolution (< 100 km) on monthly time scales. High precision (< 1 part per million, ppm) is essential to resolve the small, near-surface CO2 variations associated with ocean fluxes and to better constrain the CO2 transport over the ocean. The Japanese Greenhouse gases Observing Satellite (GOSAT) and the NASA Orbiting Carbon Observatory (OCO) were first two space based sensors designed specifically for this task. GOSAT was successfully launched on January 23, 2009, and has been returning measurements of XCO2 since April 2009. The OCO mission was lost in February 2009, when its launch vehicle malfunctioned and failed to reach orbit. In early 2010, NASA authorized a re-flight of OCO, called OCO-2, which is currently under development. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_2");'>2</a></li> <li><a href="#" onclick='return showDiv("page_3");'>3</a></li> <li class="active">4</li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li><a href="#" onclick='return showDiv("page_6");'>6</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_5" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_3");'>3</a></li> <li><a href="#" onclick='return showDiv("page_4");'>4</a></li> <li class="active">5</li> <li><a href="#" onclick='return showDiv("page_6");'>6</a></li> <li><a href="#" onclick='return showDiv("page_7");'>7</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="81"> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/25181008','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/25181008">External CO2 and water supplies for enhancing electrical power generation of air-cathode microbial fuel cells.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Ishizaki, So; Fujiki, Itto; Sano, Daisuke; Okabe, Satoshi 2014-10-07 Alkalization on the cathode electrode limits the electrical power generation of air-cathode microbial fuel cells (MFCs), and thus external proton supply to the cathode electrode is essential to enhance the electrical power generation. In this study, the effects of external CO2 and water supplies to the cathode electrode on the electrical power generation were investigated, and then the relative contributions of CO2 and water supplies to the total proton consumption were experimentally evaluated. The CO2 supply decreased the cathode pH and consequently increased the power generation. Carbonate dissolution was the main proton source under ambient air conditions, which provides about 67% of total protons consumed for the cathode reaction. It is also critical to adequately control the water content on the cathode electrode of air-cathode MFCs because the carbonate dissolution was highly dependent on water content. On the basis of these experimental results, the power density was increased by 400% (143.0 ± 3.5 mW/m(2) to 575.0 ± 36.0 mW/m(2)) by supplying a humid gas containing 50% CO2 to the cathode chamber. This study demonstrates that the simultaneous CO2 and water supplies to the cathode electrode were effective to increase the electrical power generation of air-cathode MFCs for the first time. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1431413','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1431413">Sniffle: a step forward to measure in situ CO 2 fluxes with the floating chamber technique</a> <a target="_blank" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Ribas-Ribas, Mariana; Kilcher, Levi F.; Wurl, Oliver Understanding how the ocean absorbs anthropogenic CO 2 is critical for predicting climate change. We designed Sniffle, a new autonomous drifting buoy with a floating chamber, to measure gas transfer velocities and air-sea CO 2 fluxes with high spatiotemporal resolution. Currently, insufficient in situ data exist to verify gas transfer parameterizations at low wind speeds (<4 m s -1), which leads to underestimation of gas transfer velocities and, therefore, of air-sea CO 2 fluxes. The Sniffle is equipped with a sensor to consecutively measure aqueous and atmospheric pCO 2 and to monitor increases or decreases of CO 2 inside themore » chamber. During autonomous operation, a complete cycle lasts 40 minutes, with a new cycle initiated after flushing the chamber. The Sniffle can be deployed for up to 15 hours at wind speeds up to 10 m s -1. Floating chambers often overestimate fluxes because they create additional turbulence at the water surface. We correct fluxes by measuring turbulence with two acoustic Doppler velocimeters, one positioned directly under the floating chamber and the other positioned sideways, to compare artificial disturbance caused by the chamber and natural turbulence. The first results of deployment in the North Sea during the summer of 2016 demonstrate that the new drifting buoy is a useful tool that can improve our understanding of gas transfer velocity with in situ measurements. At low and moderate wind speeds and different conditions, the results obtained indicate that the observed tidal basin was acting as a source of atmospheric CO 2. Wind speed and turbulence alone could not fully explain the variance in gas transfer velocity. We suggest therefore, that other factors like surfactants, rain or tidal current will have an impact on gas transfer parameterizations.« less </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1431413-sniffle-step-forward-measure-situ-co2-fluxes-floating-chamber-technique','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1431413-sniffle-step-forward-measure-situ-co2-fluxes-floating-chamber-technique">Sniffle: a step forward to measure in situ CO 2 fluxes with the floating chamber technique</a> <a target="_blank" href="http://www.osti.gov/pages">DOE PAGES</a> Ribas-Ribas, Mariana; Kilcher, Levi F.; Wurl, Oliver 2018-01-09 Understanding how the ocean absorbs anthropogenic CO 2 is critical for predicting climate change. We designed Sniffle, a new autonomous drifting buoy with a floating chamber, to measure gas transfer velocities and air-sea CO 2 fluxes with high spatiotemporal resolution. Currently, insufficient in situ data exist to verify gas transfer parameterizations at low wind speeds (<4 m s -1), which leads to underestimation of gas transfer velocities and, therefore, of air-sea CO 2 fluxes. The Sniffle is equipped with a sensor to consecutively measure aqueous and atmospheric pCO 2 and to monitor increases or decreases of CO 2 inside themore » chamber. During autonomous operation, a complete cycle lasts 40 minutes, with a new cycle initiated after flushing the chamber. The Sniffle can be deployed for up to 15 hours at wind speeds up to 10 m s -1. Floating chambers often overestimate fluxes because they create additional turbulence at the water surface. We correct fluxes by measuring turbulence with two acoustic Doppler velocimeters, one positioned directly under the floating chamber and the other positioned sideways, to compare artificial disturbance caused by the chamber and natural turbulence. The first results of deployment in the North Sea during the summer of 2016 demonstrate that the new drifting buoy is a useful tool that can improve our understanding of gas transfer velocity with in situ measurements. At low and moderate wind speeds and different conditions, the results obtained indicate that the observed tidal basin was acting as a source of atmospheric CO 2. Wind speed and turbulence alone could not fully explain the variance in gas transfer velocity. We suggest therefore, that other factors like surfactants, rain or tidal current will have an impact on gas transfer parameterizations.« less </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5400058','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5400058">Revisiting the choice of the driving temperature for eddy covariance CO2 flux partitioning</a> <a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Wohlfahrt, Georg; Galvagno, Marta 2017-01-01 So-called CO2 flux partitioning algorithms are widely used to partition the net ecosystem CO2 exchange into the two component fluxes, gross primary productivity and ecosystem respiration. Common CO2 flux partitioning algorithms conceptualize ecosystem respiration to originate from a single source, requiring the choice of a corresponding driving temperature. Using a conceptual dual-source respiration model, consisting of an above- and a below-ground respiration source each driven by a corresponding temperature, we demonstrate that the typical phase shift between air and soil temperature gives rise to a hysteresis relationship between ecosystem respiration and temperature. The hysteresis proceeds in a clockwise fashion if soil temperature is used to drive ecosystem respiration, while a counter-clockwise response is observed when ecosystem respiration is related to air temperature. As a consequence, nighttime ecosystem respiration is smaller than daytime ecosystem respiration when referenced to soil temperature, while the reverse is true for air temperature. We confirm these qualitative modelling results using measurements of day and night ecosystem respiration made with opaque chambers in a short-statured mountain grassland. Inferring daytime from nighttime ecosystem respiration or vice versa, as attempted by CO2 flux partitioning algorithms, using a single-source respiration model is thus an oversimplification resulting in biased estimates of ecosystem respiration. We discuss the likely magnitude of the bias, options for minimizing it and conclude by emphasizing that the systematic uncertainty of gross primary productivity and ecosystem respiration inferred through CO2 flux partitioning needs to be better quantified and reported. PMID:28439145 </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.B33C0620I','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.B33C0620I">Analysis of uncertainties in GOSAT-inferred regional CO2 fluxes</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Ishizawa, M.; Shirai, T.; Maksyutov, S. S.; Yoshida, Y.; Morino, I.; Inoue, M.; Nakatsuru, T.; Uchino, O.; Mabuchi, K. 2016-12-01 Satellite-based CO2 measurements have potential for improving our understanding global carbon cycle because of more spatiotemporal coverage than those from ground-based observations. Since the Greenhouse gases Observing Satellite (GOSAT) was launched in January 2009, it has been measuring the column-average dry air-mole function of CO2 (XCO2) from the space. To utilize the GOSAT XCO2 for better CO2 flux estimates, several challenges should be overcome. Systematic errors (biases) in XCO2 retrievals are a major factor which leads to large differences among inverted CO2 fluxes. Temporally variable data coverage and density are also taken into account when interpreting the estimated surface fluxes. In this study, we employ an atmospheric inverse model to investigate the impacts of retrievals biases and temporally varying global distribution of GOSAT XCO2 on surface CO2 flux estimates. Inversions are performed for 2009-2013, with several subsets of the 5-year record of GOSAT XCO2 (v2.21) and its bias-corrected XCO2. GOSAT XCO2 data consist of three types: H-gain for vegetated lands, M-gain for bright surfaces (desert areas), and sun-glint for ocean surface. The results show that the global spatial distributions of estimated CO2 fluxes depend on the subset of XCO2 used. M-gain XCO2 results in unrealistically high CO2 emissions in and around the Middle East, including the neighboring ocean regions. On the other hand, M-gain XCO2 causes compensating unrealistic uptakes far beyond M-gain regions in low latitudes, also partially contributing on the summer uptake in Europe. The joint inversions with both surface measurements and GOSAT XCO2 data obtain larger flux gradient between the northern extra-tropics and the tropics than the inversion with surface measurements only for the first 2 years. Recently, these North-South gradients seem to be gradually reducing as the tropics become a weaker source or turn into a sink, while the net emission strength in East Asia is increasing </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.A43C2468M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.A43C2468M">Constraints on Southern Ocean CO2 Fluxes and Seasonality from Atmospheric Vertical Gradients Observed on Multiple Airborne Campaigns</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> McKain, K.; Sweeney, C.; Stephens, B. B.; Long, M. C.; Jacobson, A. R.; Basu, S.; Chatterjee, A.; Weir, B.; Wofsy, S. C.; Atlas, E. L.; Blake, D. R.; Montzka, S. A.; Stern, R. 2017-12-01 The Southern Ocean plays an important role in the global carbon cycle and climate system, but net CO2 flux into the Southern Ocean is difficult to measure and model because it results from large opposing and seasonally-varying fluxes due to thermal forcing, biological uptake, and deep-water mixing. We present an analysis to constrain the seasonal cycle of net CO2 exchange with the Southern Ocean, and the magnitude of summer uptake, using the vertical gradients in atmospheric CO2 observed during three aircraft campaigns in the southern polar region. The O2/N2 Ratio and CO2 Airborne Southern Ocean Study (ORCAS) was an airborne campaign that intensively sampled the atmosphere at 0-13 km altitude and 45-75 degrees south latitude in the austral summer (January-February) of 2016. The global airborne campaigns, the HIAPER Pole-to-Pole Observations (HIPPO) study and the Atmospheric Tomography Mission (ATom), provide additional measurements over the Southern Ocean from other seasons and multiple years (2009-2011, 2016-2017). Derivation of fluxes from measured vertical gradients requires robust estimates of the residence time of air in the polar tropospheric domain, and of the contribution of long-range transport from northern latitudes outside the domain to the CO2 gradient. We use diverse independent approaches to estimate both terms, including simulations using multiple transport and flux models, and observed gradients of shorter-lived tracers with specific sources regions and well-known loss processes. This study demonstrates the utility of aircraft profile measurements for constraining large-scale air-sea fluxes for the Southern Ocean, in contrast to those derived from the extrapolation of sparse ocean and atmospheric measurements and uncertain flux parameterizations. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28944134','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28944134">CO2 flux from Javanese mud volcanism.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Queißer, M; Burton, M R; Arzilli, F; Chiarugi, A; Marliyani, G I; Anggara, F; Harijoko, A 2017-06-01 Studying the quantity and origin of CO 2 emitted by back-arc mud volcanoes is critical to correctly model fluid-dynamical, thermodynamical, and geochemical processes that drive their activity and to constrain their role in the global geochemical carbon cycle. We measured CO 2 fluxes of the Bledug Kuwu mud volcano on the Kendeng Fold and thrust belt in the back arc of Central Java, Indonesia, using scanning remote sensing absorption spectroscopy. The data show that the expelled gas is rich in CO 2 with a volume fraction of at least 16 vol %. A lower limit CO 2 flux of 1.4 kg s -1 (117 t d -1 ) was determined, in line with the CO 2 flux from the Javanese mud volcano LUSI. Extrapolating these results to mud volcanism from the whole of Java suggests an order of magnitude total CO 2 flux of 3 kt d -1 , comparable with the expected back-arc efflux of magmatic CO 2 . After discussing geochemical, geological, and geophysical evidence we conclude that the source of CO 2 observed at Bledug Kuwu is likely a mixture of thermogenic, biogenic, and magmatic CO 2 , with faulting controlling potential pathways for magmatic fluids. This study further demonstrates the merit of man-portable active remote sensing instruments for probing natural gas releases, enabling bottom-up quantification of CO 2 fluxes. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017JGRB..122.4191Q','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017JGRB..122.4191Q">CO2 flux from Javanese mud volcanism</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Queißer, M.; Burton, M. R.; Arzilli, F.; Chiarugi, A.; Marliyani, G. I.; Anggara, F.; Harijoko, A. 2017-06-01 Studying the quantity and origin of CO2 emitted by back-arc mud volcanoes is critical to correctly model fluid-dynamical, thermodynamical, and geochemical processes that drive their activity and to constrain their role in the global geochemical carbon cycle. We measured CO2 fluxes of the Bledug Kuwu mud volcano on the Kendeng Fold and thrust belt in the back arc of Central Java, Indonesia, using scanning remote sensing absorption spectroscopy. The data show that the expelled gas is rich in CO2 with a volume fraction of at least 16 vol %. A lower limit CO2 flux of 1.4 kg s-1 (117 t d-1) was determined, in line with the CO2 flux from the Javanese mud volcano LUSI. Extrapolating these results to mud volcanism from the whole of Java suggests an order of magnitude total CO2 flux of 3 kt d-1, comparable with the expected back-arc efflux of magmatic CO2. After discussing geochemical, geological, and geophysical evidence we conclude that the source of CO2 observed at Bledug Kuwu is likely a mixture of thermogenic, biogenic, and magmatic CO2, with faulting controlling potential pathways for magmatic fluids. This study further demonstrates the merit of man-portable active remote sensing instruments for probing natural gas releases, enabling bottom-up quantification of CO2 fluxes. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.A51A2037B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.A51A2037B">Observational analysis of air-sea fluxes and sea water temperature offshore South China Sea</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Bi, X.; Huang, J.; Gao, Z.; Liu, Y. 2017-12-01 This paper investigates the air-sea fluxes (momentum flux, sensible heat flux and latent heat flux) from eddy covariance method based on data collected at an offshore observation tower in the South China Sea from January 2009 to December 2016 and sea water temperature (SWT) on six different levels based on data collected from November 2011 to June 2013. The depth of water at the tower over the sea averages about 15 m. This study presents the in-situ measurements of continuous air-sea fluxes and SWT at different depths. Seasonal and diurnal variations in air-sea fluxes and SWT on different depths are examined. Results show that air-sea fluxes and all SWT changed seasonally; sea-land breeze circulation appears all the year round. Unlike winters where SWT on different depths are fairly consistent, the difference between sea surface temperature (SST) and sea temperature at 10 m water depth fluctuates dramatically and the maximum value reaches 7 °C during summer. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..19.6688K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..19.6688K">Comparison of Source Partitioning Methods for CO2 and H2O Fluxes Based on High Frequency Eddy Covariance Data</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Klosterhalfen, Anne; Moene, Arnold; Schmidt, Marius; Ney, Patrizia; Graf, Alexander 2017-04-01 Source partitioning of eddy covariance (EC) measurements of CO2 into respiration and photosynthesis is routinely used for a better understanding of the exchange of greenhouse gases, especially between terrestrial ecosystems and the atmosphere. The most frequently used methods are usually based either on relations of fluxes to environmental drivers or on chamber measurements. However, they often depend strongly on assumptions or invasive measurements and do usually not offer partitioning estimates for latent heat fluxes into evaporation and transpiration. SCANLON and SAHU (2008) and SCANLON and KUSTAS (2010) proposed an promising method to estimate the contributions of transpiration and evaporation using measured high frequency time series of CO2 and H2O fluxes - no extra instrumentation necessary. This method (SK10 in the following) is based on the spatial separation and relative strength of sources and sinks of CO2 and water vapor among the sub-canopy and canopy. Assuming that air from those sources and sinks is not yet perfectly mixed before reaching EC sensors, partitioning is estimated based on the separate application of the flux-variance similarity theory to the stomatal and non-stomatal components of the regarded fluxes, as well as on additional assumptions on stomatal water use efficiency (WUE). The CO2 partitioning method after THOMAS et al. (2008) (TH08 in the following) also follows the argument that the dissimilarities of sources and sinks in and below a canopy affect the relation between H2O and CO2 fluctuations. Instead of involving assumptions on WUE, TH08 directly screens their scattergram for signals of joint respiration and evaporation events and applies a conditional sampling methodology. In spite of their different main targets (H2O vs. CO2), both methods can yield partitioning estimates on both fluxes. We therefore compare various sub-methods of SK10 and TH08 including own modifications (e.g., cluster analysis) to each other, to established </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5586201','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5586201">CO2 flux from Javanese mud volcanism</a> <a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Burton, M. R.; Arzilli, F.; Chiarugi, A.; Marliyani, G. I.; Anggara, F.; Harijoko, A. 2017-01-01 Abstract Studying the quantity and origin of CO2 emitted by back‐arc mud volcanoes is critical to correctly model fluid‐dynamical, thermodynamical, and geochemical processes that drive their activity and to constrain their role in the global geochemical carbon cycle. We measured CO2 fluxes of the Bledug Kuwu mud volcano on the Kendeng Fold and thrust belt in the back arc of Central Java, Indonesia, using scanning remote sensing absorption spectroscopy. The data show that the expelled gas is rich in CO2 with a volume fraction of at least 16 vol %. A lower limit CO2 flux of 1.4 kg s−1 (117 t d−1) was determined, in line with the CO2 flux from the Javanese mud volcano LUSI. Extrapolating these results to mud volcanism from the whole of Java suggests an order of magnitude total CO2 flux of 3 kt d−1, comparable with the expected back‐arc efflux of magmatic CO2. After discussing geochemical, geological, and geophysical evidence we conclude that the source of CO2 observed at Bledug Kuwu is likely a mixture of thermogenic, biogenic, and magmatic CO2, with faulting controlling potential pathways for magmatic fluids. This study further demonstrates the merit of man‐portable active remote sensing instruments for probing natural gas releases, enabling bottom‐up quantification of CO2 fluxes. PMID:28944134 </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMOS33A1448Z','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMOS33A1448Z">Seasonal variation of air-sea CO2 fluxes in the Terra Nova Bay of the Ross Sea, Antarctica, based on year-round pCO2 observations</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Zappa, C. J.; Rhee, T. S.; Kwon, Y. S.; Choi, T.; Yang, E. J.; Kim, J. 2017-12-01 The polar oceans are rapidly changing in response to climate variability. In particular, augmented inflow of glacial melt water and shrinking sea-ice extent impacts the polar coastal oceans, which may in turn shift the biogeochemistry into an unprecedented paradigm not experienced previously. Nonetheless, most research in the polar oceans is limited to the summer season. Here, we present the first direct observations of ocean and atmospheric pCO2 measured near the coast of Terra Nova Bay in the Ross Sea, Antarctica, ongoing since February, 2015 at Jang Bogo Station. The coastal area is covered by landfast sea-ice from spring to fall while continually exposed to the atmosphere during summer season only. The pCO2 in seawater swung from 120 matm in February to 425 matm in early October. Although sea-ice still covers the coastal area, pCO2 already started decreasing after reaching the peak in October. In November, the pCO2 suddenly dropped as much as 100 matm in a week. This decrease of pCO2 continued until late February when the sea-ice concentration was minimal. With growing sea ice, the pCO2 increased logarithmically reaching the atmospheric concentration in June/July, depending on the year, and continued to increase until October. Daily mean air-sea CO2 flux in the coastal area widely varied from -70 mmol m-2 d-1 to 20 mmol m-2 d-1. Based on these observations of pCO2 in Terra Nova Bay, the annual uptake of CO2 is 8 g C m-2, estimated using the fraction of sea-ice concentration estimated from AMSR2 microwave emission imagery. Extrapolating to all polynyas surrounding Antarctica, we expect the annual uptake of 8 Tg C in the atmosphere. This is comparable to the amount of CO2 degassed into the atmosphere south of the Antarctic Polar Front (62°S). </li> <li> <a target="_blank" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70188140','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70188140">Historical patterns of acidification and increasing CO2 flux associated with Florida springs</a> <a target="_blank" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Barrera, Kira E.; Robbins, Lisa L. 2017-01-01 Florida has one of the highest concentrations of springs in the world, with many discharging into rivers and predominantly into eastern Gulf of Mexico coast, and they likely influence the hydrochemistry of these adjacent waters; however, temporal and spatial trends have not been well studied. We present over 20 yr of hydrochemical, seasonally sampled data to identify temporal and spatial trends of pH, alkalinity, partial pressure of carbon dioxide (pCO2), and CO2flux from five first-order-magnitude (springs that discharge greater than 2.83 m3 s−1) coastal spring groups fed by the Floridan Aquifer System that ultimately discharge into the Gulf of Mexico. All spring groups had pCO2 levels (averages 3174.3–6773.2 μatm) that were much higher than atmospheric levels of CO2 and demonstrated statistically significant temporal decreases in pH and increases in CO2 flux, pCO2, and alkalinity. Total carbon flux emissions increased from each of the spring groups by between 3.48 × 107 and 2.856 × 108 kg C yr−1 over the time period. By 2013 the Springs Groups in total emitted more than 1.1739 × 109 kg C yr−1. Increases in alkalinity and pCO2 varied from 90.9 to 347.6 μmol kg−1 and 1262.3 to 2666.7 μatm, respectively. Coastal data show higher CO2 evasion than the open Gulf of Mexico, which suggests spring water influences nearshore waters. The results of this study have important implications for spring water quality, dissolution of the Florida carbonate platform, and identification of the effect and partitioning of carbon fluxes to and within coastal and marine ecosystems. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28262984','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28262984">Diffusive flux of PAHs across sediment-water and water-air interfaces at urban superfund sites.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Minick, D James; Anderson, Kim A 2017-09-01 Superfund sites may be a source of polycyclic aromatic hydrocarbons (PAHs) to the surrounding environment. These sites can also act as PAH sinks from present-day anthropogenic activities, especially in urban locations. Understanding PAH transport across environmental compartments helps to define the relative contributions of these sources and is therefore important for informing remedial and management decisions. In the present study, paired passive samplers were co-deployed at sediment-water and water-air interfaces within the Portland Harbor Superfund Site and the McCormick and Baxter Superfund Site. These sites, located along the Willamette River (Portland, OR, USA), have PAH contamination from both legacy and modern sources. Diffusive flux calculations indicate that the Willamette River acts predominantly as a sink for low molecular weight PAHs from both the sediment and the air. The sediment was also predominantly a source of 4- and 5-ring PAHs to the river, and the river was a source of these same PAHs to the air, indicating that legacy pollution may be contributing to PAH exposure for residents of the Portland urban center. At the remediated McCormick and Baxter Superfund Site, flux measurements highlight locations within the sand and rock sediment cap where contaminant breakthrough is occurring. Environ Toxicol Chem 2017;36:2281-2289. © 2017 SETAC. © 2017 SETAC. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014AGUFM.A53L3379W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014AGUFM.A53L3379W">CO2 Fluxes and Concentrations in a Residential Area in the Southern Hemisphere</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Weissert, L. F.; Salmond, J. A.; Turnbull, J. C.; Schwendenmann, L. 2014-12-01 While cities are generally major sources of anthropogenic carbon dioxide (CO2) emissions, recent research has shown that parts of urban areas may also act as CO2 sinks due to CO2 uptake by vegetation. However, currently available results are related to a large degree of uncertainty due to the limitations of the applied methods and the limited number of studies available from urban areas, particularly from the southern hemisphere. In this study, we explore the potential of eddy covariance and tracer measurements (13C and 14C isotopes of CO2) to quantify and partition CO2 fluxes and concentrations in a residential urban area in Auckland, New Zealand. Based on preliminary results from autumn and winter (March to July 2014) the residential area is a small source of CO2 (0.11 mol CO2 m-2 day-1). CO2 fluxes and concentrations follow a distinct diurnal cycle with a morning peak between 7:00 and 9:00 (max: 0.25 mol CO2 m-2 day-1/412 ppm) and midday low with negative CO2 fluxes (min: -0.17 mol CO2 m-2 day-1/392 ppm) between 10:00 and 15:00 local time, likely due to photosynthetic CO2 uptake by local vegetation. Soil CO2 efflux may explain that CO2 concentrations increase and remain high (401 ppm) throughout the night. Mean diurnal winter δ13C values are in anti-phase with CO2 concentrations and vary between -9.0 - -9.7‰. The depletion of δ13C compared to clean atmospheric air (-8.2‰) is likely a result of local CO2 sources dominated by gasoline combustion (appr. 60%) during daytime. A sector analysis (based on prevailing wind) of CO2 fluxes and concentrations indicates lower CO2 fluxes and concentrations from the vegetation-dominated sector, further demonstrating the influence of vegetation on local CO2 concentrations. These results provide an insight into the temporal and spatial variability CO2 fluxes/concentrations and potential CO2 sinks and sources from a city in the southern hemisphere and add valuable information to the global database of urban CO2 fluxes. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013ACPD...1326529C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013ACPD...1326529C">Atmospheric inversion of the surface CO2 flux with 13CO2 constraint</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Chen, J. M.; Mo, G.; Deng, F. 2013-10-01 Observations of 13CO2 at 73 sites compiled in the GLOBALVIEW database are used for an additional constraint in a global atmospheric inversion of the surface CO2 flux using CO2 observations at 210 sites for the 2002-2004 period for 39 land regions and 11 ocean regions. This constraint is implemented using the 13CO2/CO2 flux ratio modeled with a terrestrial ecosystem model and an ocean model. These models simulate 13CO2 discrimination rates of terrestrial photosynthesis and respiration and ocean-atmosphere diffusion processes. In both models, the 13CO2 disequilibrium between fluxes to and from the atmosphere is considered due to the historical change in atmospheric 13CO2 concentration. For the 2002-2004 period, the 13CO2 constraint on the inversion increases the total land carbon sink from 3.40 to 3.70 Pg C yr-1 and decreases the total oceanic carbon sink from 1.48 to 1.12 Pg C yr-1. The largest changes occur in tropical areas: a considerable decrease in the carbon source in the Amazon forest, and this decrease is mostly compensated by increases in the ocean region immediately west of the Amazon and the southeast Asian land region. Our further investigation through different treatments of the 13CO2/CO2 flux ratio used in the inversion suggests that variable spatial distributions of the 13CO2 isotopic discrimination rate simulated by the models over land and ocean have considerable impacts on the spatial distribution of the inverted CO2 flux over land and the inversion results are not sensitive to errors in the estimated disequilibria over land and ocean. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.B21E1987B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.B21E1987B">Carbon Dioxide and Water Vapor Concentrations, Co-spectra and Fluxes from Latest Standardized Automated CO2/H2O Flux Systems versus Established Analyzer Models</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Burba, G. G.; Kathilankal, J. C.; Begashaw, I.; Franzen, D.; Welles, J.; McDermitt, D. K. 2017-12-01 Spatial and temporal flux data coverage have improved significantly in recent years, due to standardization, automation and management of data collection, and better handling of the generated data. With more stations and networks, larger data streams from each station, and smaller operating budgets, modern tools are required to effectively and efficiently handle the entire process.These tools should produce standardized verifiable datasets, and provide a way to cross-share the standardized data with external collaborators to leverage available funding, and promote data analyses and publications. In 2015, new open-path and enclosed flux measurement systems1 were developed, based on established gas analyzer models2,3, with the goal of improving stability in the presence of contamination, refining temperature control and compensation, and providing more accurate gas concentration measurements. In 2017, the new open-path system was further refined to simplify hardware configuration, and to reduce power consumption and cost. Additionally, all new systems incorporate complete automated on-site flux calculations using EddyPro® Software4 run by a weatherized remotely-accessible microcomputer to provide standardized traceable data sets for fluxes and supporting variables. This presentation will describe details and results from the field tests of the new flux systems, in comparison to older models and reference instruments. References:1 Burba G., W. Miller, I. Begashaw, G. Fratini, F. Griessbaum, J. Kathilankal, L. Xu, D. Franz, E. Joseph, E. Larmanou, S. Miller, D. Papale, S. Sabbatini, T. Sachs, R. Sakai, D. McDermitt, 2017. Comparison of CO2 Concentrations, Co-spectra and Flux Measurements between Latest Standardized Automated CO2/H2O Flux Systems and Older Gas Analysers. 10th ICDC Conference, Switzerland: 21-25/08 2 Metzger, S., G. Burba, S. Burns, P. Blanken, J. Li, H. Luo, R. Zulueta, 2016. Optimization of an enclosed gas analyzer sampling system for measuring eddy </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011JVGR..207..130C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011JVGR..207..130C">Diffuse CO 2 soil degassing and CO 2 and H 2S concentrations in air and related hazards at Vulcano Island (Aeolian arc, Italy)</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Carapezza, M. L.; Barberi, F.; Ranaldi, M.; Ricci, T.; Tarchini, L.; Barrancos, J.; Fischer, C.; Perez, N.; Weber, K.; Di Piazza, A.; Gattuso, A. 2011-10-01 La Fossa crater on Vulcano Island is quiescent since 1890. Periodically it undergoes "crises" characterized by marked increase of temperature (T), gas output and concentration of magmatic components in the crater fumaroles (T may exceed 600 °C). During these crises, which so far did not lead to any eruptive reactivation, the diffuse CO 2 soil degassing also increases and in December 2005 an anomalous CO 2 flux of 1350 tons/day was estimated by 1588 measurements over a surface of 1.66 km 2 extending from La Fossa crater to the inhabited zone of Vulcano Porto. The crater area and two other anomalously degassing sites (Levante Beach and Palizzi) have been periodically investigated from December 2004 to August 2010 for diffuse CO 2 soil flux. They show a marked variation with time of the degassing rate, with synchronous maxima in December 2005. Carbon dioxide soil flux and environmental parameters have been also continuously monitored for over one year by an automatic station at Vulcano Porto. In order to assess the hazard of the endogenous gas emissions, CO 2 and H 2S air concentrations have been measured by Tunable Diode Laser profiles near the fumaroles of the crater rim and of the Levante Beach area, where also the viscous gas flux has been estimated. In addition, CO 2 air concentration has been measured both indoor and outdoor in an inhabited sector of Vulcano Porto. Results show that in some sites usually frequented by tourists there is a dangerous H 2S air concentration and CO 2 exceeds the hazardous thresholds in some Vulcano houses. These zones should be immediately monitored for gas hazard should a new crisis arise. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.V31E..03C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.V31E..03C">CO2 fluxes from diffuse degassing in Italy</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Cardellini, C.; Chiodini, G.; Frondini, F.; Caliro, S. 2016-12-01 Central and southern Italy are affected by an intense process of CO2 Earth degassing from both active volcanoes, and tectonically active areas. Regional scale studies, based on C mass balance of groundwater of regional aquifers in not volcanically active areas, highlighted the presence of two large CO2 degassing structures that, for magnitude and the geochemical-isotopic features, were related to a regional process of mantle degassing. Quantitative estimates provided a CO2 flux of 9 Mt/y for the region (62000 km2). Besides the magnitude of the process, a strong link between the deep CO2 degassing and the seismicity of the region and a strict correlation between migration of deep CO2-rich fluids and the heat flux have been highlighted. In addition, the region is also characterised by the presence of many cold gas emissions where deeply derived CO2 is released by vents and soil diffuse degassing areas. Both direct CO2 expulsion at the surface and C-rich groundwater are different manifestations of the same process, in fact, the deeply produced gas can be dissolved by groundwater or emitted directly to the atmosphere depending on the gas flux rate, and the geological-structural and hydrogeological settings. Quantitative estimations of the CO2 fluxes are available only for a limited number ( 30) of the about 270 catalogued gas manifestations allowing an estimations of a CO2 flux of 1.4 Mt/y. Summing the two estimates the non-volcanic CO2 flux from the region results globally relevant, being from 2 to 10% of the estimated present-day global CO2 discharge from subaerial volcanoes. Large amounts of CO2 is also discharged by soil diffuse degassing in volcanic-hydrothermal systems. Specific surveys at Solfatara of Pozzuoli (Campi Flegrei Caldera) pointed out the relevance of this process. CO2 diffuse degassing at Solfatara, measured since 1998 shows a persistent CO2 flux of 1300 t/d (± 390 t/d), a flux comparable to an erupting volcano. The quantification of diffuse CO2 </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28863371','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28863371">Modelling CO2 emissions from water surface of a boreal hydroelectric reservoir.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Wang, Weifeng; Roulet, Nigel T; Kim, Youngil; Strachan, Ian B; Del Giorgio, Paul; Prairie, Yves T; Tremblay, Alain 2018-01-15 To quantify CO 2 emissions from water surface of a reservoir that was shaped by flooding the boreal landscape, we developed a daily time-step reservoir biogeochemistry model. We calibrated the model using the measured concentrations of dissolved organic and inorganic carbon (C) in a young boreal hydroelectric reservoir, Eastmain-1 (EM-1), in northern Quebec, Canada. We validated the model against observed CO 2 fluxes from an eddy covariance tower in the middle of EM-1. The model predicted the variability of CO 2 emissions reasonably well compared to the observations (root mean square error: 0.4-1.3gCm -2 day -1 , revised Willmott index: 0.16-0.55). In particular, we demonstrated that the annual reservoir surface effluxes were initially high, steeply declined in the first three years, and then steadily decreased to ~115gCm -2 yr -1 with increasing reservoir age over the estimated "engineering" reservoir lifetime (i.e., 100years). Sensitivity analyses revealed that increasing air temperature stimulated CO 2 emissions by enhancing CO 2 production in the water column and sediment, and extending the duration of open water period over which emissions occur. Increasing the amount of terrestrial organic C flooded can enhance benthic CO 2 fluxes and CO 2 emissions from the reservoir water surface, but the effects were not significant over the simulation period. The model is useful for the understanding of the mechanism of C dynamics in reservoirs and could be used to assist the hydro-power industry and others interested in the role of boreal hydroelectric reservoirs as sources of greenhouse gas emissions. Copyright © 2017 Elsevier B.V. All rights reserved. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_3");'>3</a></li> <li><a href="#" onclick='return showDiv("page_4");'>4</a></li> <li class="active">5</li> <li><a href="#" onclick='return showDiv("page_6");'>6</a></li> <li><a href="#" onclick='return showDiv("page_7");'>7</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_6" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_4");'>4</a></li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li class="active">6</li> <li><a href="#" onclick='return showDiv("page_7");'>7</a></li> <li><a href="#" onclick='return showDiv("page_8");'>8</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="101"> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017SolE....8.1017Q','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017SolE....8.1017Q">Increasing CO2 flux at Pisciarelli, Campi Flegrei, Italy</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Queißer, Manuel; Granieri, Domenico; Burton, Mike; Arzilli, Fabio; Avino, Rosario; Carandente, Antonio 2017-09-01 The Campi Flegrei caldera is located in the metropolitan area of Naples (Italy) and has been undergoing different stages of unrest since 1950, evidenced by episodes of significant ground uplift followed by minor subsidence, increasing and fluctuating emission strengths of water vapor and CO2 from fumaroles, and periodic seismic crises. We deployed a scanning laser remote-sensing spectrometer (LARSS) that measured path-integrated CO2 concentrations in the Pisciarelli area in May 2017. The resulting mean CO2 flux is 578 ± 246 t d-1. Our data suggest a significant increase in CO2 flux at this site since 2015. Together with recent geophysical observations, this suggests a greater contribution of the magmatic source to the degassing and/or an increase in permeability at shallow levels. Thanks to the integrated path soundings, LARSS may help to give representative measurements from large regions containing different CO2 sources, including fumaroles, low-temperature vents, and degassing soils, helping to constrain the contribution of deep gases and their migration mechanisms towards the surface. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016EGUGA..18.1180C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016EGUGA..18.1180C">On which timescales do gas transfer velocities control North Atlantic CO2 flux variability?</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Couldrey, Matthew; Oliver, Kevin; Yool, Andrew; Halloran, Paul; Achterberg, Eric 2016-04-01 The North Atlantic is an important basin for the global ocean's uptake of anthropogenic and natural carbon dioxide (CO2), but the mechanisms controlling this carbon flux are not fully understood. The air-sea flux of CO2, F, is the product of a gas transfer velocity, k, the air-sea CO2concentration gradient, ΔpCO2, and the temperature and salinity-dependent solubility coefficient, α. k is difficult to constrain, representing the dominant uncertainty in F on short (instantaneous to interannual) timescales. Previous work shows that in the North Atlantic, ΔpCO2and k both contribute significantly to interannual F variability, but that k is unimportant for multidecadal variability. On some timescale between interannual and multidecadal, gas transfer velocity variability and its associated uncertainty become negligible. Here, we quantify this critical timescale for the first time. Using an ocean model, we determine the importance of k, ΔpCO2and α on a range of timescales. On interannual and shorter timescales, both ΔpCO2and k are important controls on F. In contrast, pentadal to multidecadal North Atlantic flux variability is driven almost entirely by ΔpCO2; k contributes less than 25%. Finally, we explore how accurately one can estimate North Atlantic F without a knowledge of non-seasonal k variability, finding it possible for interannual and longer timescales. These findings suggest that continued efforts to better constrain gas transfer velocities are necessary to quantify interannual variability in the North Atlantic carbon sink. However, uncertainty in k variability is unlikely to limit the accuracy of estimates of longer term flux variability. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016GBioC..30..787C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016GBioC..30..787C">On which timescales do gas transfer velocities control North Atlantic CO2 flux variability?</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Couldrey, Matthew P.; Oliver, Kevin I. C.; Yool, Andrew; Halloran, Paul R.; Achterberg, Eric P. 2016-05-01 The North Atlantic is an important basin for the global ocean's uptake of anthropogenic and natural carbon dioxide (CO2), but the mechanisms controlling this carbon flux are not fully understood. The air-sea flux of CO2, F, is the product of a gas transfer velocity, k, the air-sea CO2 concentration gradient, ΔpCO2, and the temperature- and salinity-dependent solubility coefficient, α. k is difficult to constrain, representing the dominant uncertainty in F on short (instantaneous to interannual) timescales. Previous work shows that in the North Atlantic, ΔpCO2 and k both contribute significantly to interannual F variability but that k is unimportant for multidecadal variability. On some timescale between interannual and multidecadal, gas transfer velocity variability and its associated uncertainty become negligible. Here we quantify this critical timescale for the first time. Using an ocean model, we determine the importance of k, ΔpCO2, and α on a range of timescales. On interannual and shorter timescales, both ΔpCO2 and k are important controls on F. In contrast, pentadal to multidecadal North Atlantic flux variability is driven almost entirely by ΔpCO2; k contributes less than 25%. Finally, we explore how accurately one can estimate North Atlantic F without a knowledge of nonseasonal k variability, finding it possible for interannual and longer timescales. These findings suggest that continued efforts to better constrain gas transfer velocities are necessary to quantify interannual variability in the North Atlantic carbon sink. However, uncertainty in k variability is unlikely to limit the accuracy of estimates of longer-term flux variability. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOSAH23A..06C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOSAH23A..06C">On which timescales do gas transfer velocities control North Atlantic CO2 flux variability?</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Couldrey, M.; Oliver, K. I. C.; Yool, A.; Halloran, P. R.; Achterberg, E. P. 2016-02-01 The North Atlantic is an important basin for the global ocean's uptake of anthropogenic and natural carbon dioxide (CO2), but the mechanisms controlling this carbon flux are not fully understood. The air-sea flux of CO2, F, is the product of a gas transfer velocity, k, the air-sea CO2 concentration gradient, ΔpCO2, and the temperature and salinity-dependent solubility coefficient, α. k is difficult to constrain, representing the dominant uncertainty in F on short (instantaneous to interannual) timescales. Previous work shows that in the North Atlantic, ΔpCO2 and k both contribute significantly to interannual F variability, but that k is unimportant for multidecadal variability. On some timescale between interannual and multidecadal, gas transfer velocity variability and its associated uncertainty become negligible. Here, we quantify this critical timescale for the first time. Using an ocean model, we determine the importance of k, ΔpCO2 and α on a range of timescales. On interannual and shorter timescales, both ΔpCO2 and k are important controls on F. In contrast, pentadal to multidecadal North Atlantic flux variability is driven almost entirely by ΔpCO2; k contributes less than 25%. Finally, we explore how accurately one can estimate North Atlantic F without a knowledge of non-seasonal k variability, finding it possible for interannual and longer timescales. These findings suggest that continued efforts to better constrain gas transfer velocities are necessary to quantify interannual variability in the North Atlantic carbon sink. However, uncertainty in k variability is unlikely to limit the accuracy of estimates of longer term flux variability. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016GBioC..30.1509B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016GBioC..30.1509B">The role of metabolism in modulating CO2 fluxes in boreal lakes</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Bogard, Matthew J.; del Giorgio, Paul A. 2016-10-01 Lake CO2 emissions are increasingly recognized as an important component of the global CO2 cycle, yet the origin of these emissions is not clear, as specific contributions from metabolism and in-lake cycling, versus external inputs, are not well defined. To assess the coupling of lake metabolism with CO2 concentrations and fluxes, we estimated steady state ratios of gross primary production to respiration (GPP:R) and rates of net ecosystem production (NEP = GPP-R) from surface water O2 dynamics (concentration and stable isotopes) in 187 boreal lakes spanning long environmental gradients. Our findings suggest that internal metabolism plays a dominant role in regulating CO2 fluxes in most lakes, but this pattern only emerges when examined at a resolution that accounts for the vastly differing relationships between lake metabolism and CO2 fluxes. Fluxes of CO2 exceeded those from NEP in over half the lakes, but unexpectedly, these effects were most common and typically largest in a subset ( 30% of total) of net autotrophic lakes that nevertheless emitted CO2. Equally surprising, we found no environmental characteristics that distinguished this category from the more common net heterotrophic, CO2 outgassing lakes. Excess CO2 fluxes relative to NEP were best predicted by catchment structure and hydrologic properties, and we infer from a combination of methods that both catchment inputs and internal anaerobic processes may have contributed this excess CO2. Together, our findings show that the link between lake metabolism and CO2 fluxes is often strong but can vary widely across the boreal biome, having important implications for catchment-wide C budgets. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1255257-co2-fluxing-collapses-metal-mobility-magmatic-vapour','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1255257-co2-fluxing-collapses-metal-mobility-magmatic-vapour">CO 2-fluxing collapses metal mobility in magmatic vapour</a> <a target="_blank" href="http://www.osti.gov/pages">DOE PAGES</a> van Hinsberg, V. J.; Berlo, K.; Migdisov, A. A.; ... 2016-05-18 Magmatic systems host many types of ore deposits, including world-class deposits of copper and gold. Magmas are commonly an important source of metals and ore-forming fluids in these systems. In many magmatic-hydrothermal systems, low-density aqueous fluids, or vapours, are significant metal carriers. Such vapours are water-dominated shallowly, but fluxing of CO 2-rich vapour exsolved from deeper magma is now recognised as ubiquitous during open-system magma degassing. Furthermore, we show that such CO 2-fluxing leads to a sharp drop in element solubility, up to a factor of 10,000 for Cu, and thereby provides a highly efficient, but as yet unrecognised mechanismmore » for metal deposition.« less </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOS.A43A..03B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOS.A43A..03B">Seasonal Oxygen Supersaturation and Air-Sea Fluxes from Profiling Floats in the Pacific</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Bushinsky, S. M.; Emerson, S. R. 2016-02-01 The Pacific Ocean is a heterogeneous basin that includes regions of strong CO2 fluxes to and from the atmosphere. The Kuroshio Extension (KE) is a current associated with the largest CO2 flux into the Pacific Ocean, which extends across the Pacific basin between the subarctic and subtropical regions. The relative importance of the biological and physical processes controlling this sink is uncertain. The stoichiometric relationship between O2 and dissolved inorganic carbon during photosynthesis and respiration may allow in situ O2 measurements to help determine the processes driving this large CO2 flux. In this study, we used Argo profiling floats with modified oxygen sensors to estimate O2 fluxes in several areas of the Pacific. In situ air calibrations of these sensors allowed us to accurately measure air-sea O2 differences, which largely control the flux of O2 to and from the atmosphere. In this way, we determine air-sea O2 fluxes from profiling floats, which previously did not measure O2 accurately enough to make these calculations. To characterize different areas within the KE, we separated O2 measurements from floats into 3 regions based on geographical position and temperature-salinity relationships: North KE, Central KE, and South KE. We then used these regions and floats in the Alaska Gyre and subtropical South Pacific gyre to develop seasonal climatologies of ΔO2 and air-sea flux. Mean annual air-sea oxygen fluxes (positive fluxes represent addition of O2 to the ocean) were calculated for the Alaska Gyre of -0.3 mol m-2 yr-1 (2012-2015), for the northern KE, central KE, and southern KE (2013-2015) of 6.8, 10.5, and 0.5 mol m-2 yr-1, respectively, and for the south subtropical Pacific (2014-2015) of 0.6 mol m-2 yr-1. The air-sea flux due to bubbles was greater than 50% of the total flux for winter months and essential for determining the magnitude and, in some cases, direction of the cumulative mean annual flux. Increases in solubility due to wintertime </li> <li> <a target="_blank" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20080015856&hterms=Fuel+co2&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D20%26Ntt%3DFuel%2Bco2','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20080015856&hterms=Fuel+co2&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D20%26Ntt%3DFuel%2Bco2">Using CO2:CO Correlations to Improve Inverse Analyses of Carbon Fluxes</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Palmer, Paul I.; Suntharalingam, Parvadha; Jones, Dylan B. A.; Jacob, Daniel J.; Streets, David G.; Fu, Qingyan; Vay, Stephanie A.; Sachse, Glen W. 2006-01-01 Observed correlations between atmospheric concentrations of CO2 and CO represent potentially powerful information for improving CO2 surface flux estimates through coupled CO2-CO inverse analyses. We explore the value of these correlations in improving estimates of regional CO2 fluxes in east Asia by using aircraft observations of CO2 and CO from the TRACE-P campaign over the NW Pacific in March 2001. Our inverse model uses regional CO2 and CO surface fluxes as the state vector, separating biospheric and combustion contributions to CO2. CO2-CO error correlation coefficients are included in the inversion as off-diagonal entries in the a priori and observation error covariance matrices. We derive error correlations in a priori combustion source estimates of CO2 and CO by propagating error estimates of fuel consumption rates and emission factors. However, we find that these correlations are weak because CO source uncertainties are mostly determined by emission factors. Observed correlations between atmospheric CO2 and CO concentrations imply corresponding error correlations in the chemical transport model used as the forward model for the inversion. These error correlations in excess of 0.7, as derived from the TRACE-P data, enable a coupled CO2-CO inversion to achieve significant improvement over a CO2-only inversion for quantifying regional fluxes of CO2. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014AGUFM.B41E0110R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014AGUFM.B41E0110R">CO2 Flux From Antarctic Dry Valley Soils: Determining the Source and Environmental Controls</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Risk, D. A.; Macintyre, C. M.; Shanhun, F.; Almond, P. C.; Lee, C.; Cary, C. 2014-12-01 Soils within the McMurdo Dry Valleys are known to respire carbon dioxide (CO2), but considerable debate surrounds the contributing sources and mechanisms that drive temporal variability. While some of the CO2 is of biological origin, other known contributors to variability include geochemical sources within, or beneath, the soil column. The relative contribution from each of these sources will depend on seasonal and environmental drivers such as temperature and wind that exert influence on temporal dynamics. To supplement a long term CO2 surface flux monitoring station that has now recorded fluxes over three full annual cycles, in January 2014 an automated flux and depth concentration monitoring system was installed in the Spaulding Pond area of Taylor Valley, along with standard meteorological sensors, to assist in defining source contributions through time. During two weeks of data we observed marked diel variability in CO2 concentrations within the profile (~100 ppm CO2 above or below atmospheric), and of CO2 moving across the soil surface. The pattern at many depths suggested an alternating diel-scale transition from source to sink that seemed clearly correlated with temperature-driven changes in the solubility of CO2 in water films. This CO2 solution storage flux was very highly coupled to soil temperature. A small depth source of unknown origin also appeared to be present. A controlled laboratory soil experiment was conducted to confirm the magnitude of fluxes into and out of soil water films, and confirmed the field results and temperature dependence. Ultimately, this solution storage flux needs to be well understood if the small biological fluxes from these soils are to be properly quantified and monitored for change. Here, we present results from the 2013/2014 field season and these supplementary experiments, placed in the context of 3 year long term continuous measurement of soil CO2 flux within the Dry Valleys. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012AGUFM.A42F..07L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012AGUFM.A42F..07L">Simultaneous assimilation of AIRS and GOSAT CO2 observations with Ensemble Kalman filter</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Liu, J.; Kalnay, E.; Fung, I.; Kang, J. 2012-12-01 Lack of CO2 vertical information could lead to bias in the surface CO2 flux estimation (Stephens et al., 2007). Liu et al. (2012) showed that assimilating AIRS CO2 observations, which are sensitive to middle to upper troposphere CO2, improves CO2 concentration, especially in the middle to upper troposphere. GOSAT is sensitive to CO2 over the whole column, but the spatial coverage is sparser than AIRS. In this study, we assimilate AIRS and GOSAT CO2 observations simultaneously along with surface flask CO2 observations and meteorology observations with Ensemble Kalman filter (EnKF) to constrain CO2 vertical profiles simulated by NCAR carbon-climate model. We will show the impact of assimilating AIRS and GOSAT CO2 on the CO2 vertical gradient, seasonal cycle and spatial gradient by assimilating only GOSAT or AIRS and comparing to the control experiment. The quality of CO2 analysis will be examined by validating against independent CO2 aircraft observations, and analyzing the relationship between CO2 analysis fields and major circulation, such as Madden Julian Oscillation. We will also discuss the deficiencies of the observation network in understanding the carbon cycle. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28434669','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28434669">Diurnal variation of CO2, CH4, and N2O emission fluxes continuously monitored in-situ in three environmental habitats in a subtropical estuarine wetland.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Yang, Wen-Bin; Yuan, Chung-Shin; Tong, Chuan; Yang, Pin; Yang, Lei; Huang, Bang-Qin 2017-06-15 Wetlands play a crucial role in modulating atmospheric concentrations of greenhouse gases (GHGs) such as carbon dioxide (CO 2 ), methane (CH 4 ), and nitrous oxide (N 2 O). The key factors controlling GHG emission from subtropical estuarine wetlands were investigated in this study, which continuously monitored the uptake/emission of GHGs (CO 2 , CH 4 , and N 2 O) by/from a subtropical estuarine wetland located in the Minjiang estuary in the coastal region of southeastern China. A self-designed floating chamber was used to collect air samples on-site at three environmental habitats (Phragmites australis marsh, mudflats, and river water). The CO 2 , CH 4 , and N 2 O concentrations were then measured using an automated nondispersive infrared analyzer. The magnitudes of the CO 2 and N 2 O emission fluxes at the three habitats were ordered as river water>P. australis>mudflats. P. australis emitted GHGs through photosynthesis and respiration processes. Emissions of CH 4 from P. australis and the mudflats were revealed to be slightly higher than those from the river water. The total GHG emission fluxes at the three environmental habitats were quite similar (4.68-4.78gm -2 h -1 ). However, when the total carbon dioxide equivalent fluxes (CO 2 -e) were considered, the river water was discovered to emit the most CO 2 -e compared with P. australis and the mudflats. Based on its potential to increase global warming, N 2 O was the main contributor to the total GHG emission, with that emitted from the river water being the most considerable. Tidal water carried onto the marsh had its own GHG content and thus has acted as a source or sink of GHGs. However, water quality had a large effect on GHG emissions from the river water whereas the tidal water height did not. Both high salinity and large amounts of sulfates in the wetlands explicitly inhibited the activity of CH 4 -producing bacteria, particularly at nighttime. Copyright © 2017 Elsevier Ltd. All rights reserved. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013AGUFM.A53E0229L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013AGUFM.A53E0229L">A Synthesized Model-Observation Approach to Constraining Gross Urban CO2 Fluxes Using 14CO2 and carbonyl sulfide</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> LaFranchi, B. W.; Campbell, J. E.; Cameron-Smith, P. J.; Bambha, R.; Michelsen, H. A. 2013-12-01 Urbanized regions are responsible for a disproportionately large percentage (30-40%) of global anthropogenic greenhouse gas (GHG) emissions, despite covering only 2% of the Earth's surface area [Satterthwaite, 2008]. As a result, policies enacted at the local level in these urban areas can, in aggregate, have a large global impact, both positive and negative. In order to address the scientific questions that are required to drive these policy decisions, methods are needed that resolve gross CO2 flux components from the net flux. Recent work suggests that the critical knowledge gaps in CO2 surface fluxes could be addressed through the combined analysis of atmospheric carbonyl sulfide (COS) and radiocarbon in atmospheric CO2 (14CO2) [e.g. Campbell et al., 2008; Graven et al., 2009]. The 14CO2 approach relies on mass balance assumptions about atmospheric CO2 and the large differences in 14CO2 abundance between fossil and natural sources of CO2 [Levin et al., 2003]. COS, meanwhile, is a potentially transformative tracer of photosynthesis because its variability in the atmosphere has been found to be influenced primarily by vegetative uptake, scaling linearly will gross primary production (GPP) [Kettle et al., 20027]. Taken together, these two observations provide constraints on two of the three main components of the CO2 budget at the urban scale: photosynthesis and fossil fuel emissions. The third component, respiration, can then be determined by difference if the net flux is known. Here we present a general overview of our synthesized model-observation approach for improving surface flux estimates of CO2 for the upwind fetch of a ~30m tower located in Livermore, CA, USA, a suburb (pop. ~80,000) at the eastern edge of the San Francisco Bay Area. Additionally, we will present initial results from a one week observational intensive, which includes continuous CO2, CH4, CO, SO2, NOx, and O3 observations in addition to measurements of 14CO2 and COS from air samples </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012AGUFM.B43H0528Y','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012AGUFM.B43H0528Y">Effects of a holiday week on urban soil CO2 flux: an intensive study in Xiamen, southeastern China</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Ye, H.; Wang, K.; Chen, F. 2012-12-01 To study the effects of a holiday period on urban soil CO2 flux, CO2 efflux from grassland soil in a traditional park in the city of Xiamen was measured hourly from 28th Sep to 11th Oct, a period that included China's National Day holiday week in 2009. The results of this study revealed that: a) The urban soil CO2 emissions were higher before and after the holiday week and lower during the National Day holiday reflecting changes in the traffic cycles; b) A diurnal cycle where the soil CO2 flux decreased from early morning to noon was associated with CO2 uptake by vegetation which strongly offset vehicle CO2 emissions. The soil CO2 flux increased from night to early morning, associated with reduced CO2 uptake by vegetation; c) During the National Day holiday week in 2009, lower rates of soil respiration were measured after Mid-Autumn Day than earlier in the week, and this was related to a reduced level of human activities and vehicle traffic, reducing the CO2 concentration in the air. Urban holidays have a clear effect on soil CO2 flux through the interactions between vehicle, visitor and vegetation CO2 emissions which indirectly control the use of carbon by plant roots, the rhizosphere and soil microorganisms. Consequently, appropriate traffic controls and tourism travel plans can have positive effects on the soil carbon store and may improve local air quality. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2006ThApC..84..117V','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2006ThApC..84..117V">Temporal dynamics of CO2 fluxes and profiles over a Central European city</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Vogt, R.; Christen, A.; Rotach, M. W.; Roth, M.; Satyanarayana, A. N. V. 2006-02-01 In Summer 2002 eddy covariance flux measurements of CO2 were performed over a dense urban surface. The month-long measurements were carried out in the framework of the Basel Urban Boundary Layer Experiment (BUBBLE). Two Li7500 open path analysers were installed at z/z H = 1.0 and 2.2 above a street canyon with z H the average building height of 14.6 m and z the height above street level. Additionally, profiles of CO2 concentration were sampled at 10 heights from street level up to 2 z H . The minimum and maximum of the average diurnal course of CO2 concentration at 2 z H were 362 and 423 ppmv in late afternoon and early morning, respectively. Daytime CO2 concentrations were not correlated to local sources, e.g. the minimum occurred together with the maximum in traffic load. During night-time CO2 is in general accumulated, except when inversion development is suppressed by frontal passages. CO2 concentrations were always decreasing with height and correspondingly, the fluxes on average always directed upward. At z/z H = 2.2 low values of about 3 µmol m-2 s-1 were measured during the second half of the night. During daytime average values reached up to 14 µmol m-2 s-1. The CO2 fluxes are well correlated with the traffic load, with their maxima occurring together in late afternoon. Daytime minimum CO2 concentrations fell below regional background values. Besides vertical mixing and entrainment, it is suggested that this is also due to advection of rural air with reduced CO2 concentration. Comparison with other urban observations shows a large range of differences among urban sites in terms of both CO2 fluxes and concentrations. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28153403','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28153403">Effect of water table management and elevated CO2 on radish productivity and on CH4 and CO2 fluxes from peatlands converted to agriculture.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Musarika, S; Atherton, C E; Gomersall, T; Wells, M J; Kaduk, J; Cumming, A M J; Page, S E; Oechel, W C; Zona, D 2017-04-15 Anthropogenic activity is affecting the global climate through the release of greenhouse gases (GHGs) e.g. CO 2 and CH 4 . About a third of anthropogenic GHGs are produced from agriculture, including livestock farming and horticulture. A large proportion of the UK's horticultural farming takes place on drained lowland peatlands, which are a source of significant amounts of CO 2 into the atmosphere. This study set out to establish whether raising the water table from the currently used -50cm to -30cm could reduce GHGs emissions from agricultural peatlands, while simultaneously maintaining the current levels of horticultural productivity. A factorial design experiment used agricultural peat soil collected from the Norfolk Fens (among the largest of the UK's lowland peatlands under intensive cultivation) to assess the effects of water table levels, elevated CO 2 , and agricultural production on GHG fluxes and crop productivity of radish, one of the most economically important fenland crops. The results of this study show that a water table of -30cm can increase the productivity of the radish crop while also reducing soil CO 2 emissions but without a resultant loss of CH 4 to the atmosphere, under both ambient and elevated CO 2 concentrations. Elevated CO 2 increased dry shoot biomass, but not bulb biomass nor root biomass, suggesting no immediate advantage of future CO 2 levels to horticultural farming on peat soils. Overall, increasing the water table could make an important contribution to global warming mitigation while not having a detrimental impact on crop yield. Copyright © 2017 The Authors. Published by Elsevier B.V. All rights reserved. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..19.8085Q','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..19.8085Q">A practical CO2 flux remote sensing technique</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Queisser, Manuel; Burton, Mike 2017-04-01 An accurate quantification of CO2 flux from both natural and anthropogenic sources is of great interest in various areas of the Earth, environmental and atmospheric sciences. As emitted excess CO2 quickly dilutes into the 400 ppm ambient CO2 concentration and degassing often occurs diffusively, measuring CO2 fluxes is challenging. Therefore, fluxes are usually derived from grids of in-situ measurements, which are labour intensive measurements. Other than a safe measurement distance, remote sensing offers quick, spatially integrated and thus a more thorough measurement of gas fluxes. Active remote sensing combines these merits with operation independent of sunlight or clear sky conditions. Due to their weight and size, active remote sensing platforms for CO2, such as LIDAR, cannot easily be applied in the field or transported overseas. Moreover, their complexity requires a rather lengthy setup procedure to be undertaken by skilled personal. To meet the need for a rugged, practical CO2 remote sensing technique to scan volcanic plumes, we have developed the CO2 LIDAR. It measures 1-D column densities of CO2 with sufficient sensitivity to reveal the contribution of magmatic CO2. The CO2 LIDAR has been mounted inside a small aircraft and used to measure atmospheric column CO2 concentrations between the aircraft and the ground. It was further employed on the ground, measuring CO2 emissions from mud volcanism. During the measurement campaign the CO2 LIDAR demonstrated reliability, portability, quick set-up time (10 to 15 min) and platform independence. This new technique opens the possibility of rapid, comprehensive surveys of point source, open-vent CO2 emissions, as well as emissions from more diffuse sources such as lakes and fumarole fields. Currently, within the proof-of-concept ERC project CarbSens, a further reduction in size, weight and operational complexity is underway with the goal to commercialize the platform. Areas of potential applications include fugitive </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018ThApC.131..547W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018ThApC.131..547W">Water and CO2 fluxes over semiarid alpine steppe and humid alpine meadow ecosystems on the Tibetan Plateau</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Wang, Lei; Liu, Huizhi; Shao, Yaping; Liu, Yang; Sun, Jihua 2018-01-01 Based on eddy covariance flux data from July 15, 2014, to December 31, 2015, the water and CO2 fluxes were compared over a semiarid alpine steppe (Bange, Tibetan Plateau) and a humid alpine meadow (Lijiang, Yunnan) on the Tibetan Plateau and its surrounding region. During the wet season, the evaporative fraction (EF) was strongly and linearly correlated with the soil water content (SWC) at Bange because of its sparse green grass cover. In contrast, the correlation between the EF at Lijiang and the SWC and the normalized difference vegetation index (NDVI) was very low because the atmosphere was close to saturation and the EF was relatively constant. In the dry season, the EF at both sites decreased with the SWC. The net ecosystem exchange (NEE) at Bange was largely depressed at noon, while this phenomenon did not occur at Lijiang. The saturated NEE at Bange was 24% of that at Lijiang. The temperature sensitivity coefficient of ecosystem respiration at Bange (1.7) was also much lower than that at Lijiang (3.4). The annual total NEE in 2015 was 21.8 and -230.0 g C m-2 yr-1 at Bange and Lijiang, respectively, and the NEE was tightly controlled by the NDVI at the two sites. The distinct differences in the water and CO2 fluxes at Bange and Lijiang are attributed to the large SWC difference and its effect on vegetation growth. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMGC51G..03J','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMGC51G..03J">Impact of climate, CO2 and land use on terrestrial carbon and water fluxes in China based on a multi-model analysis</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Jia, B.; Xie, Z. 2017-12-01 Climate change and anthropogenic activities have been exerting profound influences on ecosystem function and processes, including tightly coupled terrestrial carbon and water cycles. However, their relative contributions of the key controlling factors, e.g., climate, CO2 fertilization, land use and land cover change (LULCC), on spatial-temporal patterns of terrestrial carbon and water fluxes in China are still not well understood due to the lack of ecosystem-level flux observations and uncertainties in single terrestrial biosphere model (TBM). In the present study, we quantified the effect of climate, CO2, and LULCC on terrestrial carbon and water fluxes in China using multi-model simulations for their inter-annual variability (IAV), seasonal cycle amplitude (SCA) and long-term trend during the past five decades (1961-2010). In addition, their relative contributions to the temporal variations of gross primary productivity (GPP), net ecosystem productivity (NEP) and evapotranspiration (ET) were investigated through factorial experiments. Finally, the discussions about the inter-model differences and model uncertainties were presented. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1364062','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1364062">Radiocarbon in Ecosystem Respiration and Soil Pore-Space CO2 with Surface Gas Flux, Air Temperature, and Soil Temperature and Moisture, Barrow, Alaska, 2012-2014</a> <a target="_blank" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Lydia Vaughn; Margaret Torn; Rachel Porras Dataset includes Delta14C measurements made from CO2 that was collected and purified in 2012-2014 from surface soil chambers, soil pore space, and background atmosphere. In addition to 14CO2 data, dataset includes co-located measurements of CO2 and CH4 flux, soil and air temperature, and soil moisture. Measurements and field samples were taken from intensive study site 1 areas A, B, and C, and the site 0 and AB transects, from specified positions in high-centered, flat-centered, and low centered polygons. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..19.9319M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..19.9319M">CO2 and heat fluxes in a recently clear-cut spruce forest in European Russia: experimental and modeling studies</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Mamkin, Vadim; Kurbatova, Julia; Avilov, Vitaly; Mukhartova, Yulia; Krupenko, Alexander; Ivanov, Dmitry; Levashova, Natalia; Olchev, Alexander 2017-04-01 Ecosystem carbon dioxide, energy, and water fluxes were measured using eddy covariance and portable chambers in a fresh clear-cut surrounded by a mixed spruce-birch-aspen forest in the boreal zone of European Russia. Measurements were initiated in spring 2016 following timber harvest and continued for seven months until the end of October. The influence of surrounding forest on air flow and turbulent fluxes within the clear-cut were examined using a process-based two-dimensional (2D) hydrodynamic turbulent exchange model. Clear-cut was a permanent source of CO2 to the atmosphere. During the period the mean daily latent (LE) and sensible (H) heat fluxes were very similar and the Bowen ratio (β=H/LE) averaged about 1.0. During the late spring and summer months the net ecosystem exchange of CO2 (NEE) remained slightly positive following onset of vegetation growth, while β was changing in the range from 0.6 to 4.0. There was strong diurnal variability in NEE, LE and H over the measurement period that was governed by solar radiation and temperature as well as the leaf area index (LAI) of regrown vegetation. Modeled vertical CO2 and H2O fluxes along a transect that crossed the clear-cut and coincided with the dominate wind direction showed that the clear-cut strongly influenced turbulent fluxes within the atmospheric surface layer. Furthermore, modeled atmospheric dynamics suggested that the clear-cut had a large influence on turbulent fluxes in the downwind forest, but little impact on the upwind side. An aggregated approach including field measurements and process-based models can be used to estimate energy, water and carbon dioxide fluxes in non-uniform forest landscapes. This study was supported by a grant from the Russian Science Foundation (14-14-00956). </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_4");'>4</a></li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li class="active">6</li> <li><a href="#" onclick='return showDiv("page_7");'>7</a></li> <li><a href="#" onclick='return showDiv("page_8");'>8</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_7" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li><a href="#" onclick='return showDiv("page_6");'>6</a></li> <li class="active">7</li> <li><a href="#" onclick='return showDiv("page_8");'>8</a></li> <li><a href="#" onclick='return showDiv("page_9");'>9</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="121"> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/1981Icar...47..112H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/1981Icar...47..112H">Liquid water on Mars - an energy balance climate model for CO2/H2O atmospheres</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Hoffert, M. I.; Callegari, A. J.; Hsieh, T.; Ziegler, W. 1981-07-01 A simple climatic model is developed for a Mars atmosphere containing CO2 and sufficient liquid water to account for the observed hydrologic surface features by the existence of a CO2/H2O greenhouse effect. A latitude-resolved climate model originally devised for terrestrial climate studies is applied to Martian conditions, with the difference between absorbed solar flux and emitted long-wave flux to space per unit area attributed to the divergence of the meridional heat flux and the poleward heat flux assumed to equal the atmospheric eddy heat flux. The global mean energy balance is calculated as a function of atmospheric pressure to assess the CO2/H2O greenhouse liquid water hypothesis, and some latitude-resolved cases are examined in detail in order to clarify the role of atmospheric transport and temperature-albedo feedback. It is shown that the combined CO2/H2O greenhouse at plausible early surface pressures may account for climates hot enough to support a hydrological cycle and running water at present-day insolation and visible albedo levels. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=19820029400&hterms=CO2+H2O&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D10%26Ntt%3DCO2%2BH2O','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=19820029400&hterms=CO2+H2O&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D10%26Ntt%3DCO2%2BH2O">Liquid water on Mars - An energy balance climate model for CO2/H2O atmospheres</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Hoffert, M. I.; Callegari, A. J.; Hsieh, C. T.; Ziegler, W. 1981-01-01 A simple climatic model is developed for a Mars atmosphere containing CO2 and sufficient liquid water to account for the observed hydrologic surface features by the existence of a CO2/H2O greenhouse effect. A latitude-resolved climate model originally devised for terrestrial climate studies is applied to Martian conditions, with the difference between absorbed solar flux and emitted long-wave flux to space per unit area attributed to the divergence of the meridional heat flux and the poleward heat flux assumed to equal the atmospheric eddy heat flux. The global mean energy balance is calculated as a function of atmospheric pressure to assess the CO2/H2O greenhouse liquid water hypothesis, and some latitude-resolved cases are examined in detail in order to clarify the role of atmospheric transport and temperature-albedo feedback. It is shown that the combined CO2/H2O greenhouse at plausible early surface pressures may account for climates hot enough to support a hydrological cycle and running water at present-day insolation and visible albedo levels. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2009BGD.....6.3481Z','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2009BGD.....6.3481Z">Conditional CO2 flux analysis of a managed grassland with the aid of stable isotopes</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Zeeman, M. J.; Tuzson, B.; Emmenegger, L.; Knohl, A.; Buchmann, N.; Eugster, W. 2009-04-01 Short statured managed ecosystems, such as agricultural grasslands, exhibit high temporal changes in carbon dioxide assimilation and respiration fluxes for which measurements of the net CO2 flux, e.g. by using the eddy covariance (EC) method, give only limited insight. We have therefore adopted a recently proposed concept for conditional EC flux analysis of forest to grasslands, in order to identify and quantify daytime sub-canopy respiration fluxes. To validate the concept, high frequency (≈5 Hz) stable carbon isotope analyis of CO2 was used. We made eddy covariance measurements of CO2 and its isotopologues during four days in August 2007, using a novel quantum cascade laser absorption spectrometer, capable of high time resolution stable isotope analysis. The effects of a grass cut during the measurement period could be detected and resulted in a sub-canopy source conditional flux classification, for which the isotope composition of the CO2 could be confirmed to be of a respiration source. However, the conditional flux method did not work for an undisturbed grassland canopy. We attribute this to the flux measurement height that was chosen well above the roughness sublayer, where the natural isotopic tracer (δ13C) of respiration was too well mixed with background air. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://hdl.handle.net/2060/20150001279','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20150001279">Quantifying the Observability of CO2 Flux Uncertainty in Atmospheric CO2 Records Using Products from Nasa's Carbon Monitoring Flux Pilot Project</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Ott, Lesley; Pawson, Steven; Collatz, Jim; Watson, Gregg; Menemenlis, Dimitris; Brix, Holger; Rousseaux, Cecile; Bowman, Kevin; Bowman, Kevin; Liu, Junjie; <a style="text-decoration: none; " href="javascript:void(0); " onClick="displayelement('author_20150001279'); toggleEditAbsImage('author_20150001279_show'); toggleEditAbsImage('author_20150001279_hide'); "> <img style="display:inline; width:12px; height:12px; " src="images/arrow-up.gif" width="12" height="12" border="0" alt="hide" id="author_20150001279_show"> <img style="width:12px; height:12px; display:none; " src="images/arrow-down.gif" width="12" height="12" border="0" alt="hide" id="author_20150001279_hide"> 2014-01-01 NASAs Carbon Monitoring System (CMS) Flux Pilot Project (FPP) was designed to better understand contemporary carbon fluxes by bringing together state-of-the art models with remote sensing datasets. Here we report on simulations using NASAs Goddard Earth Observing System Model, version 5 (GEOS-5) which was used to evaluate the consistency of two different sets of observationally constrained land and ocean fluxes with atmospheric CO2 records. Despite the strong data constraint, the average difference in annual terrestrial biosphere flux between the two land (NASA Ames CASA and CASA-GFED) models is 1.7 Pg C for 2009-2010. Ocean models (NOBM and ECCO2-Darwin) differ by 35 in their global estimates of carbon flux with particularly strong disagreement in high latitudes. Based upon combinations of terrestrial and ocean fluxes, GEOS-5 reasonably simulated the seasonal cycle observed at northern hemisphere surface sites and by the Greenhouse gases Observing SATellite (GOSAT) while the model struggled to simulate the seasonal cycle at southern hemisphere surface locations. Though GEOS-5 was able to reasonably reproduce the patterns of XCO2 observed by GOSAT, it struggled to reproduce these aspects of AIRS observations. Despite large differences between land and ocean flux estimates, resulting differences in atmospheric mixing ratio were small, typically less than 5 ppmv at the surface and 3 ppmv in the XCO2 column. A statistical analysis based on the variability of observations shows that flux differences of these magnitudes are difficult to distinguish from natural variability, regardless of measurement platform. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014ACP....1413281T','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014ACP....1413281T">A joint data assimilation system (Tan-Tracker) to simultaneously estimate surface CO2 fluxes and 3-D atmospheric CO2 concentrations from observations</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Tian, X.; Xie, Z.; Liu, Y.; Cai, Z.; Fu, Y.; Zhang, H.; Feng, L. 2014-12-01 precision for both CO2 concentrations and CO2 fluxes, mainly due to the simultaneous estimation of CO2 concentrations and CFs in our Tan-Tracker data assimilation system. A experiment for assimilating the real dry-air column CO2 retrievals (XCO2) from the Japanese Greenhouse Gases Observation Satellite (GOSAT) further demonstrates its potential wide applications. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015EGUGA..17.2834Z','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015EGUGA..17.2834Z">Impact of elevated CO2, water table, and temperature changes on CO2 and CH4 fluxes from arctic tundra soils</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Zona, Donatella; Haynes, Katherine; Deutschman, Douglas; Bryant, Emma; McEwing, Katherine; Davidson, Scott; Oechel, Walter 2015-04-01 Large uncertainties still exist on the response of tundra C emissions to future climate due, in part, to the lack of understanding of the interactive effects of potentially controlling variables on C emissions from Arctic ecosystems. In this study we subjected 48 soil cores (without active vegetation) from dominant arctic wetland vegetation types, to a laboratory manipulation of elevated atmospheric CO2, elevated temperature, and altered water table, representing current and future conditions in the Arctic for two growing seasons. To our knowledge this experiment comprised the most extensively replicated manipulation of intact soil cores in the Arctic. The hydrological status of the soil was the most dominant control on both soil CO2 and CH4 emissions. Despite higher soil CO2 emission occurring in the drier plots, substantial CO2 respiration occurred under flooded conditions, suggesting significant anaerobic respirations in these arctic tundra ecosystems. Importantly, a critical control on soil CO2 and CH4 fluxes was the original vascular plant cover. The dissolved organic carbon (DOC) concentration was correlated with cumulative CH4 emissions but not with cumulative CO2 suggesting C quality influenced CH4 production but not soil CO2 emissions. An interactive effect between increased temperature and elevated CO2 on soil CO2 emissions suggested a potential shift of the soils microbial community towards more efficient soil organic matter degraders with warming and elevated CO2. Methane emissions did not decrease over the course of the experiment, even with no input from vegetation. This result indicated that CH4 emissions are not carbon limited in these C rich soils. Overall CH4 emissions represented about 49% of the sum of total C (C-CO2 + C-CH4) emission in the wet treatments, and 15% in the dry treatments, representing a dominant component of the overall C balance from arctic soils. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.fs.usda.gov/treesearch/pubs/38924','TREESEARCH'); return false;" href="https://www.fs.usda.gov/treesearch/pubs/38924">Effects of experimental water table and temperature manipulations on ecosystem CO2 fluxes in an Alaskan rich fen</a> <a target="_blank" href="http://www.fs.usda.gov/treesearch/">Treesearch</a> M.R. Chivers; M.R. Turetsky; J.M. Waddington; J.W. Harden; A.D. McGuire 2009-01-01 Peatlands store 30% of the world's terrestrial soil carbon (C) and those located at northern latitudes are expected to experience rapid climate warming. We monitored growing season carbon dioxide (CO2) fluxes across a factorial design of in situ water table (control, drought, and flooded plots) and soil warming (control vs. warming via open... </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/22445955','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/22445955">Responses of CH(4), CO(2) and N(2)O fluxes to increasing nitrogen deposition in alpine grassland of the Tianshan Mountains.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Li, Kaihui; Gong, Yanming; Song, Wei; He, Guixiang; Hu, Yukun; Tian, Changyan; Liu, Xuejun 2012-06-01 To assess the effects of nitrogen (N) deposition on greenhouse gas (GHG) fluxes in alpine grassland of the Tianshan Mountains in central Asia, CH(4), CO(2) and N(2)O fluxes were measured from June 2010 to May 2011. Nitrogen deposition tended to significantly increase CH(4) uptake, CO(2) and N(2)O emissions at sites receiving N addition compared with those at site without N addition during the growing season, but no significant differences were found for all sites outside the growing season. Air temperature, soil temperature and water content were the important factors that influence CO(2) and N(2)O emissions at year-round scale, indicating that increased temperature and precipitation in the future will exert greater impacts on CO(2) and N(2)O emissions in the alpine grassland. In addition, plant coverage in July was also positively correlated with CO(2) and N(2)O emissions under elevated N deposition rates. The present study will deepen our understanding of N deposition impacts on GHG balance in the alpine grassland ecosystem, and help us assess the global N effects, parameterize Earth System models and inform decision makers. Copyright © 2012 Elsevier Ltd. All rights reserved. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/26463894','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/26463894">Rice grain yield and quality responses to free-air CO2 enrichment combined with soil and water warming.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Usui, Yasuhiro; Sakai, Hidemitsu; Tokida, Takeshi; Nakamura, Hirofumi; Nakagawa, Hiroshi; Hasegawa, Toshihiro 2016-03-01 Rising air temperatures are projected to reduce rice yield and quality, whereas increasing atmospheric CO2 concentrations ([CO2 ]) can increase grain yield. For irrigated rice, ponded water is an important temperature environment, but few open-field evaluations are available on the combined effects of temperature and [CO2 ], which limits our ability to predict future rice production. We conducted free-air CO2 enrichment and soil and water warming experiments, for three growing seasons to determine the yield and quality response to elevated [CO2 ] (+200 μmol mol(-1) , E-[CO2 ]) and soil and water temperatures (+2 °C, E-T). E-[CO2 ] significantly increased biomass and grain yield by approximately 14% averaged over 3 years, mainly because of increased panicle and spikelet density. E-T significantly increased biomass but had no significant effect on the grain yield. E-T decreased days from transplanting to heading by approximately 1%, but days to the maximum tiller number (MTN) stage were reduced by approximately 8%, which limited the panicle density and therefore sink capacity. On the other hand, E-[CO2 ] increased days to the MTN stage by approximately 4%, leading to a greater number of tillers. Grain appearance quality was decreased by both treatments, but E-[CO2 ] showed a much larger effect than did E-T. The significant decrease in undamaged grains (UDG) by E-[CO2 ] was mainly the result of an increased percentage of white-base grains (WBSG), which were negatively correlated with grain protein content. A significant decrease in grain protein content by E-[CO2 ] accounted in part for the increased WBSG. The dependence of WBSG on grain protein content, however, was different among years; the slope and intercept of the relationship were positively correlated with a heat dose above 26 °C. Year-to-year variation in the response of grain appearance quality demonstrated that E-[CO2 ] and rising air temperatures synergistically reduce grain appearance quality of </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2007JGRD..11210301G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2007JGRD..11210301G">Retrieval of average CO2 fluxes by combining in situ CO2 measurements and backscatter lidar information</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Gibert, Fabien; Schmidt, Martina; Cuesta, Juan; Ciais, Philippe; Ramonet, Michel; Xueref, IrèNe; Larmanou, Eric; Flamant, Pierre Henri 2007-05-01 The present paper deals with a boundary layer budgeting method which makes use of observations from various in situ and remote sensing instruments to infer regional average net ecosystem exchange (NEE) of CO2. Measurements of CO2 within and above the atmospheric boundary layer (ABL) by in situ sensors, in conjunction with a precise knowledge of the change in ABL height by lidar and radiosoundings, enable to infer diurnal and seasonal NEE variations. Near-ground in situ CO measurements are used to discriminate natural and anthropogenic contributions of CO2 diurnal variations in the ABL. The method yields mean NEE that amounts to 5 μmol m-2 s-1 during the night and -20 μmol m-2 s-1 in the middle of the day between May and July. A good agreement is found with the expected NEE accounting for a mixed wheat field and forest area during winter season, representative of the mesoscale ecosystems in the Paris area according to the trajectory of an air column crossing the landscape. Daytime NEE is seen to follow the vegetation growth and the change in the ratio diffuse/direct radiation. The CO2 vertical mixing flux during the rise of the atmospheric boundary layer is also estimated and seems to be the main cause of the large decrease of CO2 mixing ratio in the morning. The outcomes on CO2 flux estimate are compared to eddy-covariance measurements on a barley field. The importance of various sources of error and uncertainty on the retrieval is discussed. These errors are estimated to be less than 15%; the main error resulted from anthropogenic emissions. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://www.ars.usda.gov/research/publications/publication/?seqNo115=314066','TEKTRAN'); return false;" href="http://www.ars.usda.gov/research/publications/publication/?seqNo115=314066">Seasonal variation in measured H2O and CO2 flux of irrigated rice in the Mid-South</a> <a target="_blank" href="https://www.ars.usda.gov/research/publications/find-a-publication/">USDA-ARS?s Scientific Manuscript database</a> Rice production in the Lower Mississippi River Basin constitutes over half of US rice production, but little research has been done on water and carbon flux in this region at the field scale. Eddy covariance measurements of water and CO2 flux allow for an integrated field measurement of the interac... </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/biblio/6085685-co-sub-fluxes-tropical-atlantic-during-focal-cruises','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/6085685-co-sub-fluxes-tropical-atlantic-during-focal-cruises">CO/sub 2/ fluxes in the tropical Atlantic during FOCAL cruises</a> <a target="_blank" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Andrie, C.; Oudot, C.; Genthon, C. 1986-10-15 CO/sub 2/ partial pressures in the atmosphere and in surface seawater have been measured in the equatorial Atlantic Ocean during Programme Francais Ocean-Climat en Atlantique Equatorial cruises extending from July 1982 to August 1984 along the 4/degree/W, 22/degree/W, and 35/degree/W meridians. Gas transfer coefficients based on recently reported field data combined with information deduced from wind tunnel experiments are used to compute the CO/sub 2/ fluxes. The global mean net flux between 5/degree/N and 5/degree/S is equal to 1.05 mmol m/sup /minus/2/ d/sup /minus/1/ and is from the ocean to the atmosphere. The escape of CO/sub 2/ increases strongly frommore » the east to the west and is always lower in the north than in the south. The importance of wind speed, pCO/sub 2/ in atmosphere, PCO/sub 2/ in surface seawater, and temperature on the flux variability is discussed. The relative influence of the equatorial upwelling on one hand and of the advection and warming of surface waters on the other hand is studied in order to explain high partial pressure in seawater. 59 refs., 15 figs., 5 tabs.« less </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3594177','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3594177">Responses of Soil CO2 Fluxes to Short-Term Experimental Warming in Alpine Steppe Ecosystem, Northern Tibet</a> <a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Lu, Xuyang; Fan, Jihui; Yan, Yan; Wang, Xiaodan 2013-01-01 Soil carbon dioxide (CO2) emission is one of the largest fluxes in the global carbon cycle. Therefore small changes in the size of this flux can have a large effect on atmospheric CO2 concentrations and potentially constitute a powerful positive feedback to the climate system. Soil CO2 fluxes in the alpine steppe ecosystem of Northern Tibet and their responses to short-term experimental warming were investigated during the growing season in 2011. The results showed that the total soil CO2 emission fluxes during the entire growing season were 55.82 and 104.31 g C m-2 for the control and warming plots, respectively. Thus, the soil CO2 emission fluxes increased 86.86% with the air temperature increasing 3.74°C. Moreover, the temperature sensitivity coefficient (Q 10) of the control and warming plots were 2.10 and 1.41, respectively. The soil temperature and soil moisture could partially explain the temporal variations of soil CO2 fluxes. The relationship between the temporal variation of soil CO2 fluxes and the soil temperature can be described by exponential equation. These results suggest that warming significantly promoted soil CO2 emission in the alpine steppe ecosystem of Northern Tibet and indicate that this alpine ecosystem is very vulnerable to climate change. In addition, soil temperature and soil moisture are the key factors that controls soil organic matter decomposition and soil CO2 emission, but temperature sensitivity significantly decreases due to the rise in temperature. PMID:23536854 </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/23536854','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/23536854">Responses of soil CO2 fluxes to short-term experimental warming in alpine steppe ecosystem, Northern Tibet.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Lu, Xuyang; Fan, Jihui; Yan, Yan; Wang, Xiaodan 2013-01-01 Soil carbon dioxide (CO2) emission is one of the largest fluxes in the global carbon cycle. Therefore small changes in the size of this flux can have a large effect on atmospheric CO2 concentrations and potentially constitute a powerful positive feedback to the climate system. Soil CO2 fluxes in the alpine steppe ecosystem of Northern Tibet and their responses to short-term experimental warming were investigated during the growing season in 2011. The results showed that the total soil CO2 emission fluxes during the entire growing season were 55.82 and 104.31 g C m(-2) for the control and warming plots, respectively. Thus, the soil CO2 emission fluxes increased 86.86% with the air temperature increasing 3.74°C. Moreover, the temperature sensitivity coefficient (Q 10) of the control and warming plots were 2.10 and 1.41, respectively. The soil temperature and soil moisture could partially explain the temporal variations of soil CO2 fluxes. The relationship between the temporal variation of soil CO2 fluxes and the soil temperature can be described by exponential equation. These results suggest that warming significantly promoted soil CO2 emission in the alpine steppe ecosystem of Northern Tibet and indicate that this alpine ecosystem is very vulnerable to climate change. In addition, soil temperature and soil moisture are the key factors that controls soil organic matter decomposition and soil CO2 emission, but temperature sensitivity significantly decreases due to the rise in temperature. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/23798102','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/23798102">[Diurnal changes in greenhouse gases at water-air interface of Xiangxi River in autumn and their influencing factors].</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Huang, Wen-Min; Zhu, Kong-Xian; Zhao, Wei; Yu, Bo-Shi; Yuan, Xi-Gong; Feng, Rui-Jie; Bi, Yong-Hong; Hu, Zheng-Yu 2013-04-01 With the closed chamber and gas chromatography method, a 24-hour continuous monitoring was carried out to understand the greenhouse gases fluxes across the water-air interface of the Xiangxi River Bay, the Three-Gorges Reservoir in Autumn. Results indicated that the fluxes of CO2, CH4 and N2O across the water-air interface showed an obvious diurnal variation. The absorption and emission process of CH4 showed strong diurnal variation during the experimental period, reaching the highest emission at 1 am, whereas CO2 and N2O were emitted all day. The fluxes of CO2 ranged from 20.1-97.5 mg x (m2 x h)(-1) at day and 32.7-42.5 mg x (m2 x h)(-1) at night, the fluxes of N2O ranged from 18.4-133.7 microg x (m2 x h)(-1) at day and 42.1-102.6 microg x (m2 x h)(-1) at night. The fluxes of CO2 had positive correlation with wind speed and negative correlation with pH. The fluxes of N2O had positive correlation with pH. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/12898382','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/12898382">Elevated CO2 reduces sap flux in mature deciduous forest trees.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Cech, Patrick G; Pepin, Steeve; Körner, Christian 2003-10-01 We enriched in CO2 the canopy of 14 broad-leaved trees in a species-rich, ca. 30-m-tall forest in NW Switzerland to test whether elevated CO2 reduces water use in mature forest trees. Measurements of sap flux density (JS) were made prior to CO2 enrichment (summer 2000) and throughout the first whole growing season of CO2 exposure (2001) using the constant heat-flow technique. The short-term responses of sap flux to brief (1.5-3 h) interruptions of CO2 enrichment were also examined. There were no significant a priori differences in morphological and physiological traits between trees which were later exposed to elevated CO2 (n=14) and trees later used as controls (n=19). Over the entire growing season, CO2 enrichment resulted in an average 10.7% reduction in mean daily JS across all species compared to control trees. Responses were most pronounced in Carpinus, Acer, Prunus and Tilia, smaller in Quercus and close to zero in Fagus trees. The JS of treated trees significantly increased by 7% upon transient exposure to ambient CO2 concentrations at noon. Hence, responses of the different species were, in the short term, similar in magnitude to those observed over the whole season (though opposite because of the reversed treatment). The reductions in mean JS of CO2-enriched trees were high (22%) under conditions of low evaporative demand (vapour pressure deficit, VPD <5 hPa) and small (2%) when mean daily VPD was greater than 10 hPa. During a relatively dry period, the effect of elevated CO2 on JS even appeared to be reversed. These results suggest that daily water savings by CO2-enriched trees may have accumulated to a significantly improved water status by the time when control trees were short of soil moisture. Our data indicate that the magnitude of CO2 effects on stand transpiration will depend on rainfall regimes and the relative abundance of the different species, being more pronounced under humid conditions and in stands dominated by species such as Carpinus and </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2007AGUFM.A53G..02G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2007AGUFM.A53G..02G">A Portable FTIR Analyser for Field Measurements of Trace Gases and their Isotopologues: CO2, CH4, N2O, CO, del13C in CO2 and delD in water vapour</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Griffith, D. W.; Bryant, G. R.; Deutscher, N. M.; Wilson, S. R.; Kettlewell, G.; Riggenbach, M. 2007-12-01 We describe a portable Fourier Transform InfraRed (FTIR) analyser capable of simultaneous high precision analysis of CO2, CH4, N2O and CO in air, as well as δ13C in CO2 and δD in water vapour. The instrument is based on a commercial 1 cm-1 resolution FTIR spectrometer fitted with a mid-IR globar source, 26 m multipass White cell and thermoelectrically-cooled MCT detector operating between 2000 and 7500 cm-1. Air is passed through the cell and analysed in real time without any pre-treatment except for (optional) drying. An inlet selection manifold allows automated sequential analysis of samples from one or more inlet lines, with typical measurement times of 1-10 minutes per sample. The spectrometer, inlet sampling sequence, real-time quantitative spectrum analysis, data logging and display are all under the control of a single program running on a laptop PC, and can be left unattended for continuous measurements over periods of weeks to months. Selected spectral regions of typically 100-200 cm-1 width are analysed by a least squares fitting technique to retrieve concentrations of trace gases, 13CO2 and HDO. Typical precision is better than 0.1% without the need for calibration gases. Accuracy is similar if measurements are referenced to calibration standard gases. δ13C precision is typically around 0.1‰, and for δD it is 1‰. Applications of the analyser include clean and polluted air monitoring, tower-based flux measurements such as flux gradient or integrated horizontal flux measurements, automated soil chambers, and field-based measurements of isotopic fractionation in soil-plant-atmosphere systems. The simultaneous multi-component advantages can be exploited in tracer-type emission measurements, for example of CH4 from livestock using a co-released tracer gas and downwind measurement. We have also developed an open path variant especially suited to tracer release studies and measurements of NH3 emissions from agricultural sources. An illustrative </li> <li> <a target="_blank" onclick="trackOutboundLink('https://pubs.usgs.gov/sir/2009/5061/','USGSPUBS'); return false;" href="https://pubs.usgs.gov/sir/2009/5061/">Soil CO2 Flux in the Amargosa Desert, Nevada, during El Nino 1998 and La Nina 1999</a> <a target="_blank" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Riggs, Alan C.; Stannard, David I.; Maestas, Florentino B.; Karlinger, Michael R.; Striegl, Robert G. 2009-01-01 Mean annual soil CO2 fluxes from normally bare mineral soil in the Amargosa Desert in southern Nevada, United States, measured with clear and opaque soil CO2-flux chambers (autochambers) were small - <5 millimoles per square meter per day - during both El Nino 1998 and La Nina 1999. The 1998 opaque-chamber flux exceeded 1999 opaque-chamber flux by an order of magnitude, whereas the 1998 clear-chamber flux exceeded 1999 clear-chamber flux by less than a factor of two. These data suggest that above-normal soil moisture stimulated increased metabolic activity, but that much of the extra CO2 produced was recaptured by plants. Fluxes from warm moist soil were the largest sustained fluxes measured, and their hourly pattern is consistent with enhanced soil metabolic activity at some depth in the soil and photosynthetic uptake of a substantial portion of the CO2 released. Flux from cool moist soil was smaller than flux from warm moist soil. Flux from hot dry soil was intermediate between warm-moist and cool-moist fluxes, and clear-chamber flux was more than double the opaque-chamber flux, apparently due to a chamber artifact stemming from a thermally controlled CO2 reservoir near the soil surface. There was no demonstrable metabolic contribution to the very small flux from cool dry soil, which was dominated by diffusive up-flux of CO2 from the water table and temperature-controlled CO2-reservoir up- and down-fluxes. These flux patterns suggest that transfer of CO2 across the land surface is a complex process that is difficult to accurately measure. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMOS24A..04D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMOS24A..04D">Diagnosis of CO2 Fluxes in the Coastal Ocean</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Dai, M.; Cao, Z.; Yang, W.; Guo, X.; Yin, Z.; Zhao, Y. 2017-12-01 Coastal ocean carbon is an important component of the global carbon cycle. However, its mechanistic-based conceptualization, a prerequisite of coastal carbon modeling and its inclusion in the Earth System Model, remains difficult due to the highest variability in both time and space. Here we show that the inter-seasonal change of the global coastal pCO2 is more determined by non-temperature factors such as biological drawdown and water mass mixing, the latter of which features the dynamic boundary processes of the coastal ocean at both land-margin and margin-open ocean interfaces. Considering these unique features, we resolve the coastal CO2 fluxes using a semi-analytical approach coupling physics-biogeochemistry and carbon-nutrients and conceptualize the coastal carbon cycle into Ocean-dominated Margins (OceMar) and River-dominated Ocean Margins (RiOMar). The diagnostic result of CO2 fluxes in the South China Sea basin and the Arabian Sea as OceMars and in the Pearl River Plume as a RioMar is consistent with field observations. Our mechanistic-based diagnostic approach therefore helps better understand and model coastal carbon cycle yet the stoichiometry of carbon-nutrients coupling needs scrutiny when applying our approach. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://hdl.handle.net/2060/20080023465','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20080023465">A Preliminary Study of CO2 Flux Measurements by Lidar</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Gibert, Fabien; Koch, Grady J.; Beyon, Jeffrey Y.; Hilton, T.; Davis, Kenneth J.; Andrews, Arlyn; Ismail, Syed; Singh, Upendra N. 2008-01-01 A mechanistic understanding of the global carbon cycle requires quantification of terrestrial ecosystem CO2 fluxes at regional scales. In this paper, we analyze the potential of a Doppler DIAL system to make flux measurements of atmospheric CO2 using the eddy-covariance and boundary layer budget methods and present results from a ground based experiment. The goal of this study is to put CO2 flux point measurements in a mesoscale context. In June 2007, a field experiment combining a 2-m Doppler Heterodyne Differential Absorption Lidar (HDIAL) and in-situ sensors of a 447-m tall tower (WLEF) took place in Wisconsin. The HDIAL measures simultaneously: 1) CO2 mixing ratio, 2) atmosphere structure via aerosol backscatter and 3) radial velocity. We demonstrate how to synthesize these data into regional flux estimates. Lidar-inferred fluxes are compared with eddy-covariance fluxes obtained in-situ at 396m AGL from the tower. In cases where the lidar was not yet able to measure the fluxes with acceptable precision, we discuss possible modifications to improve system performance. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li><a href="#" onclick='return showDiv("page_6");'>6</a></li> <li class="active">7</li> <li><a href="#" onclick='return showDiv("page_8");'>8</a></li> <li><a href="#" onclick='return showDiv("page_9");'>9</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_8" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_6");'>6</a></li> <li><a href="#" onclick='return showDiv("page_7");'>7</a></li> <li class="active">8</li> <li><a href="#" onclick='return showDiv("page_9");'>9</a></li> <li><a href="#" onclick='return showDiv("page_10");'>10</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="141"> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017GSL.....4....9S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017GSL.....4....9S">Implications of overestimated anthropogenic CO2 emissions on East Asian and global land CO2 flux inversion</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Saeki, Tazu; Patra, Prabir K. 2017-12-01 Measurement and modelling of regional or country-level carbon dioxide (CO2) fluxes are becoming critical for verification of the greenhouse gases emission control. One of the commonly adopted approaches is inverse modelling, where CO2 fluxes (emission: positive flux, sink: negative flux) from the terrestrial ecosystems are estimated by combining atmospheric CO2 measurements with atmospheric transport models. The inverse models assume anthropogenic emissions are known, and thus the uncertainties in the emissions introduce systematic bias in estimation of the terrestrial (residual) fluxes by inverse modelling. Here we show that the CO2 sink increase, estimated by the inverse model, over East Asia (China, Japan, Korea and Mongolia), by about 0.26 PgC year-1 (1 Pg = 1012 g) during 2001-2010, is likely to be an artifact of the anthropogenic CO2 emissions increasing too quickly in China by 1.41 PgC year-1. Independent results from methane (CH4) inversion suggested about 41% lower rate of East Asian CH4 emission increase during 2002-2012. We apply a scaling factor of 0.59, based on CH4 inversion, to the rate of anthropogenic CO2 emission increase since the anthropogenic emissions of both CO2 and CH4 increase linearly in the emission inventory. We find no systematic increase in land CO2 uptake over East Asia during 1993-2010 or 2000-2009 when scaled anthropogenic CO2 emissions are used, and that there is a need of higher emission increase rate for 2010-2012 compared to those calculated by the inventory methods. High bias in anthropogenic CO2 emissions leads to stronger land sinks in global land-ocean flux partitioning in our inverse model. The corrected anthropogenic CO2 emissions also produce measurable reductions in the rate of global land CO2 sink increase post-2002, leading to a better agreement with the terrestrial biospheric model simulations that include CO2-fertilization and climate effects. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012AGUFM.B53C0683C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012AGUFM.B53C0683C">Coupling of N2O and CO2 fluxes from agriculture in Michigan</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Cui, M.; Tang, J.; Hastings, M. G.; Gelfand, I.; Tao, L.; Sun, K. 2012-12-01 CO2 has been known to cause global warming, and N2O is the largest contributor to the greenhouse gas burden of cropping systems in the United States due to application of fertilizer. In our study, fluxes of N2O and CO2 were measured at two maize fields and one reference grassland from Kellogg Biological Station in Southwest Michigan. Here we compared two measuring systems, traditional GC method and LGR/Li-Cor system. Our initial results show that the two measuring systems are consistent (N2O slope=0.96, R2=0.96; and CO2 slope= 1.03, R2=0.86 measuring from the same chamber). Measurements done in pairs of chambers suggest great spatial variations, despite that the chambers were only 0.5 meter apart. The two systems are still comparable by averaging 8 pairs of chambers distributed within one site. Increase of CO2 fluxes were observed the second day after fertilization, but no significant change of N2O fluxes was shown. After artificial rainfall, boosting N2O fluxes and further increase in CO2 fluxes were demonstrated. Our result indicates that precipitation is necessary before a prominent N2O peak. In our LGR/Li-Cor system, CO was also measured from chambers. Interesting CO fluxes were shown in our experiment. Soil, which is usually considered as a CO sink, emits CO in some chambers during our measurement, which is probably related to the nationwide forest fires and lack of precipitation during the period. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016EGUGA..18.2190Q','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016EGUGA..18.2190Q">Development of a laser remote sensing instrument to measure sub-aerial volcanic CO2 fluxes</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Queisser, Manuel; Burton, Mike 2016-04-01 A thorough quantification of volcanic CO2 fluxes would lead to an enhanced understanding of the role of volcanoes in the geological carbon cycle. This would enable a more subtle understanding of human impact on that cycle. Furthermore, variations in volcanic CO2 emissions are a key to understanding volcanic processes such as eruption phenomenology. However, measuring fluxes of volcanic CO2 is challenging as volcanic CO2 concentrations are modest compared with the ambient CO2 concentration (~400 ppm) . Volcanic CO2 quickly dilutes with the background air. For Mt. Etna (Italy), for instance, 1000 m downwind from the crater, dispersion modelling yields a signal of ~4 ppm only. It is for this reason that many magmatic CO2 concentration measurements focus on in situ techniques, such as direct sampling Giggenbach bottles, chemical sensors, IR absorption spectrometers or mass spectrometers. However, emission rates are highly variable in time and space. Point measurements fail to account for this variability. Inferring 1-D or 2-D gas concentration profiles, necessary to estimate gas fluxes, from point measurements may thus lead to erroneous flux estimations. Moreover, in situ probing is time consuming and, since many volcanoes emit toxic gases and are dangerous as mountains, may raise safety concerns. In addition, degassing is often diffuse and spatially extended, which makes a measurement approach with spatial coverage desirable. There are techniques that allow to indirectly retrieve CO2 fluxes from correlated SO2 concentrations and fluxes. However, they still rely on point measurements of CO2 and are prone to errors of SO2 fluxes due to light dilution and depend on blue sky conditions. Here, we present a new remote sensing instrument, developed with the ERC project CO2Volc, which measures 1-D column amounts of CO2 in the atmosphere with sufficient sensitivity to reveal the contribution of magmatic CO2. Based on differential absorption LIDAR (DIAL) the instrument measures </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMIN12C..01H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMIN12C..01H">Evaluation of Deep Learning Models for Predicting CO2 Flux</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Halem, M.; Nguyen, P.; Frankel, D. 2017-12-01 Artificial neural networks have been employed to calculate surface flux measurements from station data because they are able to fit highly nonlinear relations between input and output variables without knowing the detail relationships between the variables. However, the accuracy in performing neural net estimates of CO2 flux from observations of CO2 and other atmospheric variables is influenced by the architecture of the neural model, the availability, and complexity of interactions between physical variables such as wind, temperature, and indirect variables like latent heat, and sensible heat, etc. We evaluate two deep learning models, feed forward and recurrent neural network models to learn how they each respond to the physical measurements, time dependency of the measurements of CO2 concentration, humidity, pressure, temperature, wind speed etc. for predicting the CO2 flux. In this paper, we focus on a) building neural network models for estimating CO2 flux based on DOE data from tower Atmospheric Radiation Measurement data; b) evaluating the impact of choosing the surface variables and model hyper-parameters on the accuracy and predictions of surface flux; c) assessing the applicability of the neural network models on estimate CO2 flux by using OCO-2 satellite data; d) studying the efficiency of using GPU-acceleration for neural network performance using IBM Power AI deep learning software and packages on IBM Minsky system. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018BGeo...15.3331N','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018BGeo...15.3331N">CO2 flux over young and snow-covered Arctic pack ice in winter and spring</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Nomura, Daiki; Granskog, Mats A.; Fransson, Agneta; Chierici, Melissa; Silyakova, Anna; Ohshima, Kay I.; Cohen, Lana; Delille, Bruno; Hudson, Stephen R.; Dieckmann, Gerhard S. 2018-06-01 Rare CO2 flux measurements from Arctic pack ice show that two types of ice contribute to the release of CO2 from the ice to the atmosphere during winter and spring: young, thin ice with a thin layer of snow and older (several weeks), thicker ice with thick snow cover. Young, thin sea ice is characterized by high salinity and high porosity, and snow-covered thick ice remains relatively warm ( > -7.5 °C) due to the insulating snow cover despite air temperatures as low as -40 °C. Therefore, brine volume fractions of these two ice types are high enough to provide favorable conditions for gas exchange between sea ice and the atmosphere even in mid-winter. Although the potential CO2 flux from sea ice decreased due to the presence of the snow, the snow surface is still a CO2 source to the atmosphere for low snow density and thin snow conditions. We found that young sea ice that is formed in leads without snow cover produces CO2 fluxes an order of magnitude higher than those in snow-covered older ice (+1.0 ± 0.6 mmol C m-2 day-1 for young ice and +0.2 ± 0.2 mmol C m-2 day-1 for older ice). </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..1917180Q','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..1917180Q">Land use and rainfall effect on soil CO2 fluxes in a Mediterranean agroforestry system</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Quijano, Laura; Álvaro-Fuentes, Jorge; Lizaga, Iván; Navas, Ana 2017-04-01 Soils are the largest C reservoir of terrestrial ecosystems and play an important role in regulating the concentration of CO2 in the atmosphere. The exchange of CO2 between the atmosphere and soil controls the balance of C in soils. The CO2 fluxes may be influenced by climate conditions and land use and cover change especially in the upper soil organic layer. Understanding C dynamics is important for maintaining C stocks to sustain and improve soil quality and to enhance sink C capacity of soils. This study focuses on the response of the CO2 emitted to rainfall events from different land uses (i.e. forest, abandoned cultivated soils and winter cereal cultivated soils) in a representative Mediterranean agroforestry ecosystem in the central part of the Ebro basin, NE Spain (30T 4698723N 646424E). A total of 30 measurement points with the same soil type (classified as Calcisols) were selected. Soil CO2 flux was measured in situ using a portable EGM-4 CO2 analyzer PPSystems connected to a dynamic chamber system (model CFX-1, PPSystems) weekly during autumn 2016. Eleven different rainfall events were measured at least 24 hours before (n=7) and after the rainfall event (n=4). Soil water content and temperature were measured at each sampling point within the first 5 cm. Soil samples were taken at the beginning of the experiment to determine soil organic carbon (SOC) content using a LECO RC-612. The mean SOC for forest, abandoned and cultivated soils were 2.5, 2.7 and 0.6 %, respectively. The results indicated differences in soil CO2 fluxes between land uses. The field measurements of CO2 flux show that before cereal sowing the highest values were recorded in the abandoned soils varying from 56.1 to 171.9 mg CO2-C m-2 h-1 whereas after cereal sowing the highest values were recorded in cultivated soils ranged between 37.8 and 116.2 mg CO2-C m-2 h-1 indicating the agricultural impact on CO2 fluxes. In cultivated soils, lower mean CO2 fluxes were measured after direct seeding </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.B22A..03W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.B22A..03W">Annual dynamics of N2O, CH4 and CO2 fluxes from the agricultural irrigation watersheds in southeast China</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Wu, S.; Zou, J.; Liu, S.; Chen, J.; Kong, D.; Geng, Y. 2017-12-01 Agricultural irrigation watershed covers a large area in southeast of China and is a potentially important source of carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O). However, the flux magnitudes contribution to the overall catchment greenhouse gas (GHGs) fluxes and their drivers of seasonal variability are limited in agricultural irrigation watersheds. An in-situ observation was performed to measure annual CO2, CH4 and N2O fluxes from an agricultural irrigation watershed in southeast of China from September 2014 to September 2016. GHGs fluxes were measured using floating chambers and a gas exchange model was also used to predict CH4 and N2O fluxes. All GHGs showed varied seasonally with highest fluxes in early summer (July) and lowest in winter. Estimated seasonal CH4-C fluxes (11.5-97.6 mg m-2 hr-1) and N2O-N fluxes (2.8-80.8μg m-2 hr-1) were in relative agreement with measured CH4-C fluxes (0.05-74.9mg m-2 hr-1) and N2O-N fluxes (3.9-68.7μg m-2 hr-1) fluxes using floating chambers. Both CH4 and N2O fluxes were positively related to water temperature. The CH4 fluxes were negatively related to water dissolved oxygen (DO) concentration but positively related to sediment dissolved organic carbon (DOC). The N2O fluxes were positively related to water NH4+ and NO3-. The calculated EF5-r value in this study (mean = 0.0016; range = 0.0013-0.0018) was below the current IPCC (2006) default value of 0.0025. This implied that IPCC methodology may over estimates of N2O emissions associated with nitrogen leaching and runoff from agriculture. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2009AGUFM.B51A0302O','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2009AGUFM.B51A0302O">Soil CO2 Fluxes Following Wetting Events: Field Observations and Modeling</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> O'Donnell, F. C.; Caylor, K. K. 2009-12-01 Carbon exchange data from eddy flux towers in drylands suggest that the Birch Effect, a pulse of soil CO2 efflux triggered by the first rain following a dry period, may contribute significantly to the annual carbon budget of these ecosystems. Laboratory experiments on dryland soils have shown that microbes adapted to live in arid ecosystems may be able to remain dormant in dry soil for much longer than expected and an osmotic shock response to sudden increases in soil water potential may play a role in the Birch Effect. However, little has been done to understand how a dry soil profile responds to a rainfall event. We measured soil CO2 production during experimental wetting events in treatment plots at a site on the Botswana portion of the Kalahari Transect (KT). We buried small, solid-state sensors that continuously measure CO2 concentration in the soil air space at four depths and the soil surface and applied wetting treatments intended to simulate typical rainfall for the region to the plots, including single 10 mm wettings (the mean storm depth for the KT), single 20 mm wettings, and repeated 10 mm wettings. We solved a finite difference approximation of the governing equation for CO2 in the soil airspace to determine the source rate of CO2 during and after the wetting treatments, using Richard’s equation to approximate the change in air-filled porosity due to infiltrating water. The wetting treatments induced a rapid spike in the source rate of CO2 in the soil, the timing and magnitude of which were consistent with laboratory experiments that observed a microbial osmotic shock response. The source rate averaged over the first three hours after wetting showed that a 20 mm wetting produced a larger response than the 10 mm wettings. It also showed that a second wetting event produced a smaller response than the first and though it was not significant, an upward trend in response was apparent through the two month period. These results suggest that there may be </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012AGUFM.A34B..03F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012AGUFM.A34B..03F">Estimating regional CO2 and CH4 fluxes using GOSAT XCO2 and XCH4 observations</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Fraser, A. C.; Palmer, P. I.; Feng, L.; Parker, R.; Boesch, H.; Cogan, A. J. 2012-12-01 We infer regional monthly surface flux estimates for CO2 and CH4, June 2009-December 2010, from proxy dry-air column-averaged mole fractions of CO2 and CH4 from the Greenhouse gases Observing SATellite (GOSAT) using an ensemble Kalman Filter combined with the GEOS-Chem chemistry transport model. We compare these flux estimates with estimates inferred from in situ surface mole fraction measurements and from combining in situ and GOSAT measurements in order to quantify the added value of GOSAT data above the conventional surface measurement network. We find that the error reduction, a measure of how much the posterior fluxes are being informed by the assimilated data, at least doubles when GOSAT measurements are used versus the surface only inversions, with the exception of regions that are well covered by the surface network at the spatial and temporal resolution of our flux estimation calculation. We have incorporated a new online bias correction scheme to account for GOSAT biases. We report global and regional flux estimates inferred from GOSAT and/or in situ measurements. While the global posterior fluxes from GOSAT and in situ measurements agree, we find significant differences in the regional fluxes, particularly over the tropics. We evaluate the posterior fluxes by comparing them against independent surface mole fraction, column, and aircraft measurements using the GEOS-Chem model as an intermediary. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017BGeo...14.5595B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017BGeo...14.5595B">Continuous measurement of air-water gas exchange by underwater eddy covariance</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Berg, Peter; Pace, Michael L. 2017-12-01 Exchange of gases, such as O2, CO2, and CH4, over the air-water interface is an important component in aquatic ecosystem studies, but exchange rates are typically measured or estimated with substantial uncertainties. This diminishes the precision of common ecosystem assessments associated with gas exchanges such as primary production, respiration, and greenhouse gas emission. Here, we used the aquatic eddy covariance technique - originally developed for benthic O2 flux measurements - right below the air-water interface (˜ 4 cm) to determine gas exchange rates and coefficients. Using an acoustic Doppler velocimeter and a fast-responding dual O2-temperature sensor mounted on a floating platform the 3-D water velocity, O2 concentration, and temperature were measured at high-speed (64 Hz). By combining these data, concurrent vertical fluxes of O2 and heat across the air-water interface were derived, and gas exchange coefficients were calculated from the former. Proof-of-concept deployments at different river sites gave standard gas exchange coefficients (k600) in the range of published values. A 40 h long deployment revealed a distinct diurnal pattern in air-water exchange of O2 that was controlled largely by physical processes (e.g., diurnal variations in air temperature and associated air-water heat fluxes) and not by biological activity (primary production and respiration). This physical control of gas exchange can be prevalent in lotic systems and adds uncertainty to assessments of biological activity that are based on measured water column O2 concentration changes. For example, in the 40 h deployment, there was near-constant river flow and insignificant winds - two main drivers of lotic gas exchange - but we found gas exchange coefficients that varied by several fold. This was presumably caused by the formation and erosion of vertical temperature-density gradients in the surface water driven by the heat flux into or out of the river that affected the turbulent </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2007BGD.....4.2279K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2007BGD.....4.2279K">CO2 flux determination by closed-chamber methods can be seriously biased by inappropriate application of linear regression</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Kutzbach, L.; Schneider, J.; Sachs, T.; Giebels, M.; Nykänen, H.; Shurpali, N. J.; Martikainen, P. J.; Alm, J.; Wilmking, M. 2007-07-01 Closed (non-steady state) chambers are widely used for quantifying carbon dioxide (CO2) fluxes between soils or low-stature canopies and the atmosphere. It is well recognised that covering a soil or vegetation by a closed chamber inherently disturbs the natural CO2 fluxes by altering the concentration gradients between the soil, the vegetation and the overlying air. Thus, the driving factors of CO2 fluxes are not constant during the closed chamber experiment, and no linear increase or decrease of CO2 concentration over time within the chamber headspace can be expected. Nevertheless, linear regression has been applied for calculating CO2 fluxes in many recent, partly influential, studies. This approach was justified by keeping the closure time short and assuming the concentration change over time to be in the linear range. Here, we test if the application of linear regression is really appropriate for estimating CO2 fluxes using closed chambers over short closure times and if the application of nonlinear regression is necessary. We developed a nonlinear exponential regression model from diffusion and photosynthesis theory. This exponential model was tested with four different datasets of CO2 flux measurements (total number: 1764) conducted at three peatland sites in Finland and a tundra site in Siberia. The flux measurements were performed using transparent chambers on vegetated surfaces and opaque chambers on bare peat surfaces. Thorough analyses of residuals demonstrated that linear regression was frequently not appropriate for the determination of CO2 fluxes by closed-chamber methods, even if closure times were kept short. The developed exponential model was well suited for nonlinear regression of the concentration over time c(t) evolution in the chamber headspace and estimation of the initial CO2 fluxes at closure time for the majority of experiments. CO2 flux estimates by linear regression can be as low as 40% of the flux estimates of exponential regression for </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.B24C..08M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.B24C..08M">Methane and Carbon Dioxide Concentrations and Fluxes in Amazon Floodplains</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Melack, J. M.; MacIntyre, S.; Forsberg, B.; Barbosa, P.; Amaral, J. H. 2016-12-01 Field studies on the central Amazon floodplain in representative aquatic habitats (open water, flooded forests, floating macrophytes) combine measurements of methane and carbon dioxide concentrations and fluxes to the atmosphere over diel and seasonal times with deployment of meteorological sensors and high-resolution thermistors and dissolved oxygen sondes. A cavity ringdown spectrometer is used to determine gas concentrations, and floating chambers and bubble collectors are used to measure fluxes. To further understand fluxes, we measured turbulence as rate of dissipation of turbulent kinetic energy based on microstructure profiling. These results allow calculations of vertical mixing within the water column and of air-water exchanges using surface renewal models. Methane and carbon dioxide fluxes varied as a function of season, habitat and water depth. High CO2 fluxes at high water are related to high pCO2; low pCO2 levels at low water result from increased phytoplankton uptake. CO2 fluxes are highest at turbulent open water sites, and pCO2 is highest in macrophyte beds. Fluxes and pCH4 are high in macrophyte beds. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..19.4632A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..19.4632A">Diffuse CO2 fluxes from Santiago and Congro volcanic lakes (São Miguel, Azores archipelago)</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Andrade, César; Cruz, José; Viveiros, Fátima; Branco, Rafael 2017-04-01 Diffuse CO2 degassing occurring in Santiago and Congro lakes, both located in depressions associated to maars from São Miguel Island (Azores, Portugal), was studied through detailed flux measurements. Four sampling campaigns were developed between 2013 and 2016 in each water body, split by the cold and wet seasons. São Miguel has an area of 744.6 km2, being the largest island of the archipelago. The geology of the island is dominated by three quiescent central volcanoes (Sete Cidades, Fogo and Furnas), linked by volcanic fissural zones (Picos and Congro Fissural Volcanic systems). The oldest volcanic systems of the island are located in its eastern part (Povoação-Nordeste). Santiago lake, with a surface area of 0.26 km2 and a depth of 30.5 m, is located inside a maar crater in the Sete Cidades volcano at an altitude of 355 m. The watershed of the lake has an area of 0.97 km2 and a surface flow estimated as 1.54x10 m3/a. A total of 1612 CO2 flux measurements using the accumulation chamber method were made at Santiago lake, 253 in the first campaign (November 2013), and 462, 475 and 422 in the three other campaigns, respectively, in April 2014, September 2016 and December 2016. The total CO2 flux estimated for this lake varies between 0.4 t d-1 and 0.59 t d-1, for the surveys performed, respectively, in November 2013 and September 2016; higher CO2 outputs of 1.57 and 5.87 t d-1 were calculated for the surveys carried out in April 2014 and December 2016. These higher CO2 emissions were associated with a period without water column stratification. Similarly to Santiago lake, Congro lake is located inside a maar, in the Congro Fissural Volcanic system, and has a surface area of 0.04 km2 with 18.5 m depth and a storage of about 2.4x105 m3/a. The lake, located at an altitude of 420 m, is fed by a watershed with an area of 0.33 km2 and a runoff estimated as about 8x104 m3/a. In Congro lake a total of 713 CO2 flux measurements were performed during four surveys from </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AGUFM.B41C0458G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AGUFM.B41C0458G">Effects of experimental warming and elevated CO2 on surface methane and CO2 fluxes from a boreal black spruce peatland</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Gill, A. L.; Finzi, A.; Giasson, M. A. 2015-12-01 High latitude peatlands represent a major terrestrial carbon store sensitive to climate change, as well as a globally significant methane source. While elevated atmospheric carbon dioxide concentrations and warming temperatures may increase peat respiration and C losses to the atmosphere, reductions in peatland water tables associated with increased growing season evapotranspiration may alter the nature of trace gas emission and increase peat C losses as CO2 relative to methane (CH4). As CH4 is a greenhouse gas with twenty times the warming potential of CO2, it is critical to understand how surface fluxes of CO2 and CH4 will be influenced by factors associated with global climate change. We used automated soil respiration chambers to assess the influence of elevated atmospheric CO2 and whole ecosystem warming on peatland CH4 and CO2 fluxes at the SPRUCE (Spruce and Peatland Responses Under Climatic and Environmental Change) Experiment in northern Minnesota. Belowground warming treatments were initiated in July 2014 and whole ecosystem warming and elevated CO2 treatments began in August 2015. Here we report soil iCO2 and iCH4 flux responses to the first year of belowground warming and the first two months of whole ecosystem manipulation. We also leverage the spatial and temporal density of measurements across the twenty autochambers to assess how physical (i.e., plant species composition, microtopography) and environmental (i.e., peat temperature, water table position, oxygen availability) factors influence observed rates of CH4 and CO2 loss. We find that methane fluxes increased significantly across warming treatments following the first year of belowground warming, while belowground warming alone had little influence on soil CO2 fluxes. Peat microtopography strongly influenced trace gas emission rates, with higher CH4 fluxes in hollow locations and higher CO2 fluxes in hummock locations. While there was no difference in the isotopic composition of the methane </li> <li> <a target="_blank" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70035657','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70035657">Effects of experimental water table and temperature manipulations on ecosystem CO2 fluxes in an Alaskan rich fen</a> <a target="_blank" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Chivers, M.R.; Turetsky, M.R.; Waddington, J.M.; Harden, J.W.; McGuire, A.D. 2009-01-01 Peatlands store 30% of the world's terrestrial soil carbon (C) and those located at northern latitudes are expected to experience rapid climate warming. We monitored growing season carbon dioxide (CO2) fluxes across a factorial design of in situ water table (control, drought, and flooded plots) and soil warming (control vs. warming via open top chambers) treatments for 2 years in a rich fen located just outside the Bonanza Creek Experimental Forest in interior Alaska. The drought (lowered water table position) treatment was a weak sink or small source of atmospheric CO2 compared to the moderate atmospheric CO2 sink at our control. This change in net ecosystem exchange was due to lower gross primary production and light-saturated photosynthesis rather than increased ecosystem respiration. The flooded (raised water table position) treatment was a greater CO2 sink in 2006 due largely to increased early season gross primary production and higher light-saturated photosynthesis. Although flooding did not have substantial effects on rates of ecosystem respiration, this water table treatment had lower maximum respiration rates and a higher temperature sensitivity of ecosystem respiration than the control plot. Surface soil warming increased both ecosystem respiration and gross primary production by approximately 16% compared to control (ambient temperature) plots, with no net effect on net ecosystem exchange. Results from this rich fen manipulation suggest that fast responses to drought will include reduced ecosystem C storage driven by plant stress, whereas inundation will increase ecosystem C storage by stimulating plant growth. ?? 2009 Springer Science+Business Media, LLC. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012AGUFM.B51B0521F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012AGUFM.B51B0521F">Carbon dioxide and water vapor fluxes over Erhai Lake using eddy covariance technique</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Feng, J.; Liu, H.; Sun, J. 2012-12-01 The lakes have significant impacts on the local or even regional weather and climate. However, the effect of lakes is poorly parameterized in numerical weather prediction and climate models until now. In this background, an eddy covariance measurement site was built to directly measure long-term turbulent fluxes of water vapor and CO2 over Erhai Lake (area 250 km2, maximum depth 21.5 m) in the Southwest part of China. This study aimed at getting better understands on the air-lake interaction that in turn may benefit the parameterization schemes in the models. The observations also included radiation, wind speed, direction, and water temperature profile measurements. Using a whole year data in 2011, the diurnal variation patterns of sensible heat, latent heat and CO2 fluxes were investigated. The sensible heat flux peaked in early morning (about 25 W m-2) and reached its minimum in the afternoon (about -15 W m-2), and was strongly controlled by the air-water temperature difference. The latent had an opposite diurnal course with a maximum in the afternoon (about 150 W m-2) and minimum in the morning (about 5 W m-2), which was correlated with water pressure deficit and wind speed. The CO2 fluxes were positive at night (about 2.1 μmol m-2 s-1), and weakly negative (about -1.0 μmol m-2 s-1) in the afternoon (14:00-16:00). In the seasonal time scale, the lake was a weak CO2 sink in the summer, but a CO2 source in the other time of the year. In order to analyze energy balance, heat storage of water was estimated using water temperature profile data. The result showed that the average energy balance closure was about 85% in the summer, and about 78% in the other time of the year. The minimum values of albedo were observed to be about 0.05 at midday, indicating a large part of solar radiation was absorbed by the water. The aerodynamic roughness length (z0) and bulk transfer coefficients (Cd, Ch and Cq) were also estimated using eddy covariance data. The average value of z </li> <li> <a target="_blank" onclick="trackOutboundLink('http://hdl.handle.net/2060/20110005616','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20110005616">Comparing Global Atmospheric CO2 Flux and Transport Models with Remote Sensing (and Other) Observations</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Kawa, S. R.; Collatz, G. J.; Pawson, S.; Wennberg, P. O.; Wofsy, S. C.; Andrews, A. E. 2010-01-01 We report recent progress derived from comparison of global CO2 flux and transport models with new remote sensing and other sources of CO2 data including those from satellite. The overall objective of this activity is to improve the process models that represent our understanding of the workings of the atmospheric carbon cycle. Model estimates of CO2 surface flux and atmospheric transport processes are required for initial constraints on inverse analyses, to connect atmospheric observations to the location of surface sources and sinks, to provide the basic framework for carbon data assimilation, and ultimately for future projections of carbon-climate interactions. Models can also be used to test consistency within and between CO2 data sets under varying geophysical states. Here we focus on simulated CO2 fluxes from terrestrial vegetation and atmospheric transport mutually constrained by analyzed meteorological fields from the Goddard Modeling and Assimilation Office for the period 2000 through 2009. Use of assimilated meteorological data enables direct model comparison to observations across a wide range of scales of variability. The biospheric fluxes are produced by the CASA model at 1x1 degrees on a monthly mean basis, modulated hourly with analyzed temperature and sunlight. Both physiological and biomass burning fluxes are derived using satellite observations of vegetation, burned area (as in GFED-3), and analyzed meteorology. For the purposes of comparison to CO2 data, fossil fuel and ocean fluxes are also included in the transport simulations. In this presentation we evaluate the model's ability to simulate CO2 flux and mixing ratio variability in comparison to remote sensing observations from TCCON, GOSAT, and AIRS as well as relevant in situ observations. Examples of the influence of key process representations are shown from both forward and inverse model comparisons. We find that the model can resolve much of the synoptic, seasonal, and interannual </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/18044541','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/18044541">Energy and material balance of CO2 capture from ambient air.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Zeman, Frank 2007-11-01 Current Carbon Capture and Storage (CCS) technologies focus on large, stationary sources that produce approximately 50% of global CO2 emissions. We propose an industrial technology that captures CO2 directly from ambient air to target the remaining emissions. First, a wet scrubbing technique absorbs CO2 into a sodium hydroxide solution. The resultant carbonate is transferred from sodium ions to calcium ions via causticization. The captured CO2 is released from the calcium carbonate through thermal calcination in a modified kiln. The energy consumption is calculated as 350 kJ/mol of CO2 captured. It is dominated by the thermal energy demand of the kiln and the mechanical power required for air movement. The low concentration of CO2 in air requires a throughput of 3 million cubic meters of air per ton of CO2 removed, which could result in significant water losses. Electricity consumption in the process results in CO2 emissions and the use of coal power would significantly reduce to net amount captured. The thermodynamic efficiency of this process is low but comparable to other "end of pipe" capture technologies. As another carbon mitigation technology, air capture could allow for the continued use of liquid hydrocarbon fuels in the transportation sector. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2003EAEJA....11433I','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2003EAEJA....11433I">Short-term effects of rainfall on CO2 fluxes above rangelands dominated by Artemisia, Bromus tectorum, and Agropyron</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Ivans, S.; Saliendra, N. Z.; Johnson, D. A. 2003-04-01 The short-term effects of rainfall on carbon dioxide (CO_2) fluxes have not been well documented in rangelands of the Intermountain Region of the western USA. We used the Bowen ratio-energy balance technique to continuously measure CO_2 fluxes above three rangeland sites in Idaho and Utah dominated by: 1) Artemisia (sagebrush) near Malta, Idaho; 2) Bromus tectorum (cheatgrass) near Malta, Idaho; and 3) Agropyron (crested wheatgrass) in Rush Valley, Utah. We examined CO_2 fluxes immediately before and after rainfall during periods of 10--19 July 2001 (Summer), 8--17 October 2001 (Autumn), and 16--30 May 2002 (Spring). On sunny days before rainfall during Spring, all three sites were sinks for CO_2. After rainfall in Spring, all three sites became sources of CO_2 for about two days and after that became CO_2 sinks again. During Summer and Autumn when water was limiting, sites were small sources of CO_2 and became larger sources for one day after rainfall. In all three seasons, daytime CO_2 fluxes decreased and nighttime CO_2 fluxes increased after rainfall, suggesting that rainfall stimulated belowground respiration at all three sites. Results from this study indicated that CO_2 fluxes above rangeland sites in the Intermountain West changed markedly after rainfall, especially during Spring when fluxes were highest. KEY WORDS: Bowen ratio-energy balance, Intermountain West, rangelands, sagebrush, cheatgrass, crested wheatgrass </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1287223-large-co2-effluxes-night-during-synoptic-weather-events-significantly-contribute-co2-emissions-from-reservoir','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1287223-large-co2-effluxes-night-during-synoptic-weather-events-significantly-contribute-co2-emissions-from-reservoir">Large CO 2 effluxes at night and during synoptic weather events significantly contribute to CO 2 emissions from a reservoir</a> <a target="_blank" href="http://www.osti.gov/pages">DOE PAGES</a> Liu, Heping; Zhang, Qianyu; Katul, Gabriel G.; ... 2016-05-24 CO 2 emissions from inland waters are commonly determined by indirect methods that are based on the product of a gas transfer coefficient and the concentration gradient at the air water interface (e.g., wind-based gas transfer models). The measurements of concentration gradient are typically collected during the day in fair weather throughout the course of a year. Direct measurements of eddy covariance CO 2 fluxes from a large inland water body (Ross Barnett reservoir, Mississippi, USA) show that CO 2 effluxes at night are approximately 70% greater than those during the day. At longer time scales, frequent synoptic weather eventsmore » associated with extratropical cyclones induce CO 2 flux pulses, resulting in further increase in annual CO 2 effluxes by 16%. Therefore, CO 2 emission rates from this reservoir, if these diel and synoptic processes are under-sampled, are likely to be underestimated by approximately 40%. Our results also indicate that the CO 2 emission rates from global inland waters reported in the literature, when based on indirect methods, are likely underestimated. Field samplings and indirect modeling frameworks that estimate CO 2 emissions should account for both daytime-nighttime efflux difference and enhanced emissions during synoptic weather events. Furthermore, the analysis here can guide carbon emission sampling to improve regional carbon estimates.« less </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_6");'>6</a></li> <li><a href="#" onclick='return showDiv("page_7");'>7</a></li> <li class="active">8</li> <li><a href="#" onclick='return showDiv("page_9");'>9</a></li> <li><a href="#" onclick='return showDiv("page_10");'>10</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_9" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_7");'>7</a></li> <li><a href="#" onclick='return showDiv("page_8");'>8</a></li> <li class="active">9</li> <li><a href="#" onclick='return showDiv("page_10");'>10</a></li> <li><a href="#" onclick='return showDiv("page_11");'>11</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="161"> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1287223','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1287223">Large CO 2 effluxes at night and during synoptic weather events significantly contribute to CO 2 emissions from a reservoir</a> <a target="_blank" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Liu, Heping; Zhang, Qianyu; Katul, Gabriel G. CO 2 emissions from inland waters are commonly determined by indirect methods that are based on the product of a gas transfer coefficient and the concentration gradient at the air water interface (e.g., wind-based gas transfer models). The measurements of concentration gradient are typically collected during the day in fair weather throughout the course of a year. Direct measurements of eddy covariance CO 2 fluxes from a large inland water body (Ross Barnett reservoir, Mississippi, USA) show that CO 2 effluxes at night are approximately 70% greater than those during the day. At longer time scales, frequent synoptic weather eventsmore » associated with extratropical cyclones induce CO 2 flux pulses, resulting in further increase in annual CO 2 effluxes by 16%. Therefore, CO 2 emission rates from this reservoir, if these diel and synoptic processes are under-sampled, are likely to be underestimated by approximately 40%. Our results also indicate that the CO 2 emission rates from global inland waters reported in the literature, when based on indirect methods, are likely underestimated. Field samplings and indirect modeling frameworks that estimate CO 2 emissions should account for both daytime-nighttime efflux difference and enhanced emissions during synoptic weather events. Furthermore, the analysis here can guide carbon emission sampling to improve regional carbon estimates.« less </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..19.3646S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..19.3646S">CO2 response to rewetting of hydrophobic soils - Can soil water repellency inhibit the 'Birch effect'?</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Sanchez-Garcia, Carmen; Urbanek, Emilia; Doerr, Stefan 2017-04-01 Rewetting of dry soils is known to cause a short-term CO2 pulse commonly known as the 'Birch effect'. The displacement of CO2 with water during the process of wetting has been recognised as one of the sources of this pulse. The 'Birch effect' has been extensively observed in many soils, but some studies report a lack of such phenomenon, suggesting soil water repellency (SWR) as a potential cause. Water infiltration in water repellent soils can be severely restricted, causing overland flow or increased preferential flow, resulting in only a small proportion of soil pores being filled with water and therefore small gas-water replacement during wetting. Despite the suggestions of a different response of CO2 fluxes to wetting under hydrophobic conditions, this theory has never been tested. The aim of this study is to test the hypothesis that CO2 pulse does not occur during rewetting of water repellent soils. Dry homogeneous soils at water-repellent and wettable status have been rewetted with different amounts of water. CO2 flux as a response to wetting has been continuously measured with the CO2 flux analyser. Delays in infiltration and non-uniform heterogeneous water flow were observed in water repellent soils, causing an altered response in the CO2 pulse in comparison to typically observed 'Birch effect' in wettable systems. The main conclusion from the study is that water repellency not only affects water relations in soil, but has also an impact on greenhouse gas production and transport and therefore should be included as an important parameter during the sites monitoring and modelling of gas fluxes. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70020545','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70020545">Winter fluxes of CO2 and CH4 from subalpine soils in Rocky Mountain National Park, Colorado</a> <a target="_blank" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Mast, M. Alisa; Wickland, Kimberly P.; Striegl, Robert G.; Clow, David W. 1998-01-01 Fluxes of CO2 and CH4 through a seasonal snowpack were measured in and adjacent to a subalpine wetland in Rocky Mountain National Park, Colorado. Gas diffusion through the snow was controlled by gas production or consumption in the soil and by physical snowpack properties. The snowpack insulated soils from cold midwinter air temperatures allowing microbial activity to continue through the winter. All soil types studied were net sources of CO2 to the atmosphere through the winter, whereas saturated soils in the wetland center were net emitters of CH4 and soils adjacent to the wetland were net CH4 consumers. Most sites showed similar temporal patterns in winter gas fluxes; the lowest fluxes occurred in early winter, and maximum fluxes occurred at the onset of snowmelt. Temporal changes in fluxes probably were related to changes in soil-moisture conditions and hydrology because soil temperatures were relatively constant under the snowpack. Average winter CO2 fluxes were 42.3, 31.2, and 14.6 mmol m−2 d−1 over dry, moist, and saturated soils, respectively, which accounted for 8 to 23% of the gross annual CO2emissions from these soils. Average winter CH4 fluxes were −0.016, 0.274, and 2.87 mmol m−2 d−1over dry, moist, and saturated soils, respectively. Microbial activity under snow cover accounted for 12% of the annual CH4 consumption in dry soils and 58 and 12% of the annual CH4 emitted from moist and saturated soils, respectively. The observed ranges in CO2 and CH4 flux through snow indicated that winter fluxes are an important part of the annual carbon budget in seasonally snow-covered terrains. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.fs.usda.gov/treesearch/pubs/4575','TREESEARCH'); return false;" href="https://www.fs.usda.gov/treesearch/pubs/4575">Quantitative comparison of in situ soil CO2 flux measurement methods</a> <a target="_blank" href="http://www.fs.usda.gov/treesearch/">Treesearch</a> Jennifer D. Knoepp; James M. Vose 2002-01-01 Development of reliable regional or global carbon budgets requires accurate measurement of soil CO2 flux. We conducted laboratory and field studies to determine the accuracy and comparability of methods commonly used to measure in situ soil CO2 fluxes. Methods compared included CO2... </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011AGUFM.A43H..02B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011AGUFM.A43H..02B">Optimization of CO2 Surface Flux using GOSAT Total Column CO2: First Results for 2009-2010</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Basu, S.; Houweling, S. 2011-12-01 Constraining surface flux estimates of CO2 using satellite measurements has been one of the long-standing goals of the atmospheric inverse modeling community. We present the first results of inverting GOSAT total column CO2 measurements for obtaining global monthly CO2 flux maps over one year (June 2009 to May 2010). We use the SRON RemoTeC retrieval of CO2 for our inversions. The SRON retrieval has been shown to have no bias when compared to TCCON total column measurements, and latitudinal gradients of the retrieved CO2 are consistent with gradients deduced from the surface flask network [Butz et al, 2011]. This makes this retrieval an ideal candidate for atmospheric inversions, which are highly sensitive to spurious gradients. Our inversion system is analogous to the CarbonTracker (CT) data assimilation system; it is initialized with the prior CO2 fluxes of CT, and uses the same atmospheric transport model, i.e., TM5. The two major differences are (a) we add GOSAT CO2 data to the inversion in addition to flask data, and (b) we use a 4DVAR optimization system instead of a Kalman filter. We compare inversions using (a) only GOSAT total column CO2 measurements, (b) only surface flask CO2 measurements, and (c) the joint data set of GOSAT and surface flask measurements. We validate GOSAT-only inversions against the NOAA surface flask network and joint inversions against CONTRAIL and other aircraft campaigns. We see that inverted fluxes from a GOSAT-only inversion are consistent with fluxes from a stations-only inversion, reaffirming the low biases in SRON retrievals. From the joint inversion, we estimate the amount of added constraints upon adding GOSAT total column measurements to existing surface layer measurements. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013AGUFM.B31E0447B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013AGUFM.B31E0447B">Assessing the impact of urban land cover composition on CO2 flux</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Becker, K.; Hinkle, C. 2013-12-01 Urbanization is an ever increasing trend in global land use change, and has been identified as a key driver of CO2 emissions. Therefore, understanding how urbanization affects CO2 flux across a range of climatic zones and development patterns is critical to projecting the impact of future land use on CO2 flux dynamics. A growing number of studies are applying the eddy covariance method to urban areas to quantify the CO2 flux dynamics of these systems. However, interpretation of eddy covariance data in these urban systems presents a challenge, particularly in areas with high heterogeneity due to a mixing of built and green space. Here we present a study aimed at establishing a relationship between land cover composition and CO2 flux for a heterogeneous urban area of Orlando, FL. CO2 flux has been measured at this site for > 4 years using an open path eddy covariance system. Land cover at this site was classified into built and green space, and relative weight of both land covers were calculated for each 30 min CO2 flux measurement using the Schuepp model and a source area based on +/- one standard deviation of wind direction. The results of this analysis established a relationship between built land cover and CO2 flux within the measured footprint of this urban area. These results, in combination with future projected land use data, will be a valuable resource for providing insight into the impact of future urbanization on CO2 flux dynamics in this region. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018GMD....11..497Q','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018GMD....11..497Q">ORCHIDEE-PEAT (revision 4596), a model for northern peatland CO2, water, and energy fluxes on daily to annual scales</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Qiu, Chunjing; Zhu, Dan; Ciais, Philippe; Guenet, Bertrand; Krinner, Gerhard; Peng, Shushi; Aurela, Mika; Bernhofer, Christian; Brümmer, Christian; Bret-Harte, Syndonia; Chu, Housen; Chen, Jiquan; Desai, Ankur R.; Dušek, Jiří; Euskirchen, Eugénie S.; Fortuniak, Krzysztof; Flanagan, Lawrence B.; Friborg, Thomas; Grygoruk, Mateusz; Gogo, Sébastien; Grünwald, Thomas; Hansen, Birger U.; Holl, David; Humphreys, Elyn; Hurkuck, Miriam; Kiely, Gerard; Klatt, Janina; Kutzbach, Lars; Largeron, Chloé; Laggoun-Défarge, Fatima; Lund, Magnus; Lafleur, Peter M.; Li, Xuefei; Mammarella, Ivan; Merbold, Lutz; Nilsson, Mats B.; Olejnik, Janusz; Ottosson-Löfvenius, Mikaell; Oechel, Walter; Parmentier, Frans-Jan W.; Peichl, Matthias; Pirk, Norbert; Peltola, Olli; Pawlak, Włodzimierz; Rasse, Daniel; Rinne, Janne; Shaver, Gaius; Schmid, Hans Peter; Sottocornola, Matteo; Steinbrecher, Rainer; Sachs, Torsten; Urbaniak, Marek; Zona, Donatella; Ziemblinska, Klaudia 2018-02-01 Peatlands store substantial amounts of carbon and are vulnerable to climate change. We present a modified version of the Organising Carbon and Hydrology In Dynamic Ecosystems (ORCHIDEE) land surface model for simulating the hydrology, surface energy, and CO2 fluxes of peatlands on daily to annual timescales. The model includes a separate soil tile in each 0.5° grid cell, defined from a global peatland map and identified with peat-specific soil hydraulic properties. Runoff from non-peat vegetation within a grid cell containing a fraction of peat is routed to this peat soil tile, which maintains shallow water tables. The water table position separates oxic from anoxic decomposition. The model was evaluated against eddy-covariance (EC) observations from 30 northern peatland sites, with the maximum rate of carboxylation (Vcmax) being optimized at each site. Regarding short-term day-to-day variations, the model performance was good for gross primary production (GPP) (r2 = 0.76; Nash-Sutcliffe modeling efficiency, MEF = 0.76) and ecosystem respiration (ER, r2 = 0.78, MEF = 0.75), with lesser accuracy for latent heat fluxes (LE, r2 = 0.42, MEF = 0.14) and and net ecosystem CO2 exchange (NEE, r2 = 0.38, MEF = 0.26). Seasonal variations in GPP, ER, NEE, and energy fluxes on monthly scales showed moderate to high r2 values (0.57-0.86). For spatial across-site gradients of annual mean GPP, ER, NEE, and LE, r2 values of 0.93, 0.89, 0.27, and 0.71 were achieved, respectively. Water table (WT) variation was not well predicted (r2 < 0.1), likely due to the uncertain water input to the peat from surrounding areas. However, the poor performance of WT simulation did not greatly affect predictions of ER and NEE. We found a significant relationship between optimized Vcmax and latitude (temperature), which better reflects the spatial gradients of annual NEE than using an average Vcmax value. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/27126229','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/27126229">Temporal and spatial patterns of internal and external stem CO2 fluxes in a sub-Mediterranean oak.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Salomón, Roberto L; Valbuena-Carabaña, María; Gil, Luis; McGuire, Mary Anne; Teskey, Robert O; Aubrey, Doug P; González-Doncel, Inés; Rodríguez-Calcerrada, Jesús 2016-11-01 To accurately estimate stem respiration (R S ), measurements of both carbon dioxide (CO 2 ) efflux to the atmosphere (E A ) and internal CO 2 flux through xylem (F T ) are needed because xylem sap transports respired CO 2 upward. However, reports of seasonal dynamics of F T and E A are scarce and no studies exist in Mediterranean species under drought stress conditions. Internal and external CO 2 fluxes at three stem heights, together with radial stem growth, temperature, sap flow and shoot water potential, were measured in Quercus pyrenaica Willd. in four measurement campaigns during one growing season. Substantial daytime depressions in temperature-normalized E A were observed throughout the experiment, including prior to budburst, indicating that diel hysteresis between stem temperature and E A cannot be uniquely ascribed to diversion of CO 2 in the transpiration stream. Low internal [CO 2 ] (<0.5%) resulted in low contributions of F T to R S throughout the growing season, and R S was mainly explained by E A (>90%). Internal [CO 2 ] was found to vary vertically along the stems. Seasonality in resistance to radial CO 2 diffusion was related to shoot water potential. The low internal [CO 2 ] and F T observed in our study may result from the downregulation of xylem respiration in response to a legacy of coppicing as well as high radial diffusion of CO 2 through cambium, phloem and bark tissues, which was related to low water content of stems. Long-term studies analyzing temporal and spatial variation in internal and external CO 2 fluxes and their interactions are needed to mechanistically understand and model respiration of woody tissues. © The Author 2016. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2007BGeo....4.1005K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2007BGeo....4.1005K">CO2 flux determination by closed-chamber methods can be seriously biased by inappropriate application of linear regression</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Kutzbach, L.; Schneider, J.; Sachs, T.; Giebels, M.; Nykänen, H.; Shurpali, N. J.; Martikainen, P. J.; Alm, J.; Wilmking, M. 2007-11-01 Closed (non-steady state) chambers are widely used for quantifying carbon dioxide (CO2) fluxes between soils or low-stature canopies and the atmosphere. It is well recognised that covering a soil or vegetation by a closed chamber inherently disturbs the natural CO2 fluxes by altering the concentration gradients between the soil, the vegetation and the overlying air. Thus, the driving factors of CO2 fluxes are not constant during the closed chamber experiment, and no linear increase or decrease of CO2 concentration over time within the chamber headspace can be expected. Nevertheless, linear regression has been applied for calculating CO2 fluxes in many recent, partly influential, studies. This approach has been justified by keeping the closure time short and assuming the concentration change over time to be in the linear range. Here, we test if the application of linear regression is really appropriate for estimating CO2 fluxes using closed chambers over short closure times and if the application of nonlinear regression is necessary. We developed a nonlinear exponential regression model from diffusion and photosynthesis theory. This exponential model was tested with four different datasets of CO2 flux measurements (total number: 1764) conducted at three peatlands sites in Finland and a tundra site in Siberia. Thorough analyses of residuals demonstrated that linear regression was frequently not appropriate for the determination of CO2 fluxes by closed-chamber methods, even if closure times were kept short. The developed exponential model was well suited for nonlinear regression of the concentration over time c(t) evolution in the chamber headspace and estimation of the initial CO2 fluxes at closure time for the majority of experiments. However, a rather large percentage of the exponential regression functions showed curvatures not consistent with the theoretical model which is considered to be caused by violations of the underlying model assumptions. Especially the </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011AGUFM.V14A..04B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011AGUFM.V14A..04B">Measuring water adsorption on mineral surfaces in air, CO2, and supercritical CO2 with a quartz-crystal microbalance</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Bryan, C. R.; Wells, R. K.; Burton, P. D.; Heath, J. E.; Dewers, T. A.; Wang, Y. 2011-12-01 Carbon sequestration via underground storage in geologic formations is a proposed approach for reducing industrial CO2 emissions. However, current models for carbon injection and long-term storage of supercritical CO2 (scCO2) do not consider the development and stability of adsorbed water films at the scCO2-hydrophilic mineral interface. The thickness and properties of the water films control the surface tension and wettability of the mineral surface, and on the core scale, affect rock permeability, saturation, and capillary properties. The film thickness is strongly dependent upon the activity of water in the supercritical fluid, which will change as initially anhydrous scCO2 absorbs water from formation brine. As described in a companion paper by the coauthors, the thickness of the adsorbed water layer is controlled by the disjoining pressure; structural and van der Waals components dominate at low water activity, while electrostatic forces become more important with increasing film thickness (higher water activities). As scCO2 water activity and water layer thickness increase, concomitant changes in mineral surface properties and reservoir/caprock hydrologic properties will affect the mobility of the aqueous phase and of scCO2. Moreover, the development of a water layer may be critical to mineral dissolution reactions in scCO2. Here, we describe the use of a quartz-crystal microbalance (QCM) to monitor adsorption of water by mineral surfaces. QCMs utilize a piezoelectrically-stimulated quartz wafer to measure adsorbed or deposited mass via changes in vibrational frequency. When used to measure the mass of adsorbed liquid films, the frequency response of the crystal must be corrected for the viscoelastic, rather than elastic, response of the adsorbed layer. Results are presented for adsorption to silica in N2 and CO2 at one bar, and in scCO2. Additional data are presented for water uptake by clays deposited on a QCM wafer. In this case, water uptake occurs by the </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/21332508','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/21332508">The water-water cycle in leaves is not a major alternative electron sink for dissipation of excess excitation energy when CO(2) assimilation is restricted.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Driever, Steven M; Baker, Neil R 2011-05-01 Electron flux from water via photosystem II (PSII) and PSI to oxygen (water-water cycle) may provide a mechanism for dissipation of excess excitation energy in leaves when CO(2) assimilation is restricted. Mass spectrometry was used to measure O(2) uptake and evolution together with CO(2) uptake in leaves of French bean and maize at CO(2) concentrations saturating for photosynthesis and the CO(2) compensation point. In French bean at high CO(2) and low O(2) concentrations no significant water-water cycle activity was observed. At the CO(2) compensation point and 3% O(2) a low rate of water-water cycle activity was observed, which accounted for 30% of the linear electron flux from water. In maize leaves negligible water-water cycle activity was detected at the compensation point. During induction of photosynthesis in maize linear electron flux was considerably greater than CO(2) assimilation, but no significant water-water cycle activity was detected. Miscanthus × giganteus grown at chilling temperature also exhibited rates of linear electron transport considerably in excess of CO(2) assimilation; however, no significant water-water cycle activity was detected. Clearly the water-water cycle can operate in leaves under some conditions, but it does not act as a major sink for excess excitation energy when CO(2) assimilation is restricted. © 2011 Blackwell Publishing Ltd. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28975183','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28975183">The catalytic effect of H2O on the hydrolysis of CO32- in hydrated clusters and its implication in the humidity driven CO2 air capture.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Xiao, Hang; Shi, Xiaoyang; Zhang, Yayun; Liao, Xiangbiao; Hao, Feng; Lackner, Klaus S; Chen, Xi 2017-10-18 The hydration of ions in nanoscale hydrated clusters is ubiquitous and essential in many physical and chemical processes. Here we show that the hydrolysis reaction is strongly affected by relative humidity. The hydrolysis of CO 3 2- with n = 1-8 water molecules is investigated using an ab initio method. For n = 1-5 water molecules, all the reactants follow a stepwise pathway to the transition state. For n = 6-8 water molecules, all the reactants undergo a direct proton transfer to the transition state with overall lower activation free energy. The activation free energy of the reaction is dramatically reduced from 10.4 to 2.4 kcal mol -1 as the number of water molecules increases from 1 to 6. Meanwhile, the degree of hydrolysis of CO 3 2- is significantly increased compared to the bulk water solution scenario. Incomplete hydration shells facilitate the hydrolysis of CO 3 2- with few water molecules to be not only thermodynamically favorable but also kinetically favorable. We showed that the chemical kinetics is not likely to constrain the speed of CO 2 air capture driven by the humidity-swing. Instead, the pore-diffusion of ions is expected to be the time-limiting step in the humidity driven CO 2 air capture. The effect of humidity on the speed of CO 2 air capture was studied by conducting a CO 2 absorption experiment using IER with a high ratio of CO 3 2- to H 2 O molecules. Our result is able to provide valuable insights into designing efficient CO 2 air-capture sorbents. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..1918319L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..1918319L">Modification of land-atmosphere interactions by CO2 effects</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Lemordant, Leo; Gentine, Pierre 2017-04-01 Plant stomata couple the energy, water and carbon cycles. Increased CO2 modifies the seasonality of the water cycle through stomatal regulation and increased leaf area. As a result, the water saved during the growing season through higher water use efficiency mitigates summer dryness and the impact of potential heat waves. Land-atmosphere interactions and CO2 fertilization together synergistically contribute to increased summer transpiration. This, in turn, alters the surface energy budget and decreases sensible heat flux, mitigating air temperature rise. Accurate representation of the response to higher CO2 levels, and of the coupling between the carbon and water cycles are therefore critical to forecasting seasonal climate, water cycle dynamics and to enhance the accuracy of extreme event prediction under future climate. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017GeoRL..44.5627S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017GeoRL..44.5627S">Variability and trends in surface seawater pCO2 and CO2 flux in the Pacific Ocean</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Sutton, A. J.; Wanninkhof, R.; Sabine, C. L.; Feely, R. A.; Cronin, M. F.; Weller, R. A. 2017-06-01 Variability and change in the ocean sink of anthropogenic carbon dioxide (CO2) have implications for future climate and ocean acidification. Measurements of surface seawater CO2 partial pressure (pCO2) and wind speed from moored platforms are used to calculate high-resolution CO2 flux time series. Here we use the moored CO2 fluxes to examine variability and its drivers over a range of time scales at four locations in the Pacific Ocean. There are significant surface seawater pCO2, salinity, and wind speed trends in the North Pacific subtropical gyre, especially during winter and spring, which reduce CO2 uptake over the 10 year record of this study. Starting in late 2013, elevated seawater pCO2 values driven by warm anomalies cause this region to be a net annual CO2 source for the first time in the observational record, demonstrating how climate forcing can influence the timing of an ocean region shift from CO2 sink to source. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013EGUGA..15.1470D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013EGUGA..15.1470D">The effects of ecological restoration on CO2 fluxes from a climatically marginal upland blanket bog</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Dixon, Simon; Qassim, Suzane; Rowson, James; Worrall, Fred; Evans, Martin 2013-04-01 A legacy of gully incision, deposition of industrially-derived aerial pollutants, inappropriate management and wildfire has left large expanses of the topographic Bleaklow Plateau (Peak District National Park, England, UK) bare of vegetation and susceptible to massive erosion of the peat soils. The consequence of such degradation has been to decrease the capacity of the peatland on the plateau to provide important ecosystem services including; loss of net C sink function, discolouration of surface waters, mobilisation to surface waters of stored heavy metals and infilling of upland reservoirs with peat-derived sediment. In response to on-going and worsening degradation a programme of ecological restoration has been undertaken. Restoration methods include: seeding with a lawn grass mix; liming; fertilisation; slope stabilisation; and gully blocking. This talk will present data from a five-year, observational-study of CO2 fluxes from eight sites, with four sites sampling different restoration treatments and four sampling bare and least disturbed areas. The results of the analysis reveal that sites with revegetation alongside slope stabilisation were most productive and were the largest net (daylight hours) sinks of CO2. Unrestored, bare sites, while having relatively low gross fluxes of CO2 were the largest net sources of CO2. Revegetation without slope stabilisation took longer (~18 months) to show an impact on CO2 flux in comparison to the sites with slope stabilisation. Binary logistic regression indicated that a ten centimetre increase in water table depth decreases the odds of observing a net CO2 sink, on a given site, by up to 30%. Sites with slope stabilisation were between 5-8x more likely to be net CO2 sinks than the bare sites. Sites without slope stabilisation were only 2-2.3x more likely to be net CO2 sinks compared to the bare sites. The most important conclusion of this research is that revegetation appears to be effective at increasing the likelihood </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018AtmEn.173..248W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018AtmEn.173..248W">Subsurface watering resulted in reduced soil N2O and CO2 emissions and their global warming potentials than surface watering</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Wei, Qi; Xu, Junzeng; Yang, Shihong; Liao, Linxian; Jin, Guangqiu; Li, Yawei; Hameed, Fazli 2018-01-01 Water management is an important practice with significant effect on greenhouse gases (GHG) emission from soils. Nitrous oxide (N2O) and carbon dioxide (CO2) emissions and their global warming potentials (GWPs) from subsurface watering soil (SUW) were investigated, with surface watering (SW) as a control. Results indicated that the N2O and CO2 emissions from SUW soils were somewhat different to those from SW soil, with the peak N2O and CO2 fluxes from SUW soil reduced by 28.9% and 19.4%, and appeared 72 h and 168 h later compared with SW. The fluxes of N2O and CO2 from SUW soils were lower than those from SW soil in both pulse and post-pulse periods, and the reduction was significantly (p<0.05) in pulse period. Compare to SW, the cumulative N2O and CO2 emissions and its integrative GWPs from SUW soil decreased by 21.0% (p<0.05), 15.9% and 18.0%, respectively. The contributions of N2O to GWPs were lower than those of CO2 during most of time, except in pulse emission periods, and the proportion of N2O from SUW soil was 1.4% (p>0.1) lower that from SW soil. Moreover, N2O and CO2 fluxes from both watering treatments increased exponentially with increase of soil water-filled pore space (WFPS) and temperature. Our results suggest that watering soil from subsurface could significantly reduce the integrative greenhouse effect caused by N2O and CO2 and is a promising strategy for soil greenhouse gases (GHGs) mitigation. And the pulse period, contributed most to the reduction in emissions of N2O and CO2 from soils between SW and SUW, should be a key period for mitigating GHGs emissions. Response of N2O and CO2 emissions to soil WFPS and temperature illustrated that moisture was the dominant parameters that triggering GHG pulse emissions (especially for N2O), and temperature had a greater effect on the soil microorganism activity than moisture in drier soil. Avoiding moisture and temperature are appropriate for GHG emission at the same time is essential for GHGs mitigation </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018DokES.479..507Z','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018DokES.479..507Z">Daily Course of CO2 Fluxes in the Atmosphere-Water System and Variable Fluorescence of Phytoplankton during the Open-Water Period for Lake Baikal according to Long-Term Measurements</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Zavoruev, V. V.; Domysheva, V. M.; Pestunov, D. A.; Sakirko, M. V.; Panchenko, M. V. 2018-04-01 The process of gas exchange of CO2 in the atmosphere-water system and its relation to the daily course of variable fluorescence of phytoplankton is studied on the basis of long-term (2004-2014) measurements during the open water period for Lake Baikal. It is found that the decrease in photosynthetic activity of plankton is almost synchronous to the increase in the CO2 flux from atmosphere to water. It follows from comparison of the spring and summer data with December measurements that the daily decrease in variable fluorescence of phytoplankton is caused by the internal daily rhythm of the photosynthetic activity of plankton. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2003JGRD..108.8224W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2003JGRD..108.8224W">Soil surface CO2 flux in a boreal black spruce fire chronosequence</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Wang, Chuankuan; Bond-Lamberty, Ben; Gower, Stith T. 2003-02-01 Understanding the effects of wildfire on the carbon (C) cycle of boreal forests is essential to quantifying the role of boreal forests in the global carbon cycle. Soil surface CO2 flux (Rs), the second largest C flux in boreal forests, is directly and indirectly affected by fire and is hypothesized to change during forest succession following fire. The overall objective of this study was to measure and model Rs for a black spruce (Picea mariana [Mill.] BSP) postfire chronosequence in northern Manitoba, Canada. The experiment design was a nested factorial that included two soil drainage classes (well and poorly drained) × seven postfire aged stands. Specific objectives were (1) to quantify the relationship between Rs and soil temperature for different aged boreal black spruce forests in well-drained and poorly drained soil conditions, (2) to examine Rs dynamics along postfire successional stands, and (3) to estimate annual soil surface CO2 flux for these ecosystems. Soil surface CO2 flux was significantly affected by soil drainage class (p = 0.014) and stand age (p = 0.006). Soil surface CO2 flux was positively correlated to soil temperature (R2 = 0.78, p < 0.001), but different models were required for each drainage class × aged stand combination. Soil surface CO2 flux was significantly greater at the well-drained than the poorly drained stands (p = 0.007) during growing season. Annual soil surface CO2 flux for the 1998, 1995, 1989, 1981, 1964, 1930, and 1870 burned stands averaged 226, 412, 357, 413, 350, 274, and 244 g C m-2 yr-1 in the well-drained stands and 146, 380, 300, 303, 256, 233, and 264 g C m-2 yr-1 in the poorly drained stands. Soil surface CO2 flux during the winter (from 1 November to 30 April) comprised from 5 to 19% of the total annual Rs. We speculate that the smaller soil surface CO2 flux in the recently burned than the older stands is mainly caused by decreased root respiration. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2002JGRD..107.8224W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2002JGRD..107.8224W">Soil surface CO2 flux in a boreal black spruce fire chronosequence</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Wang, Chuankuan; Bond-Lamberty, Ben; Gower, Stith T. 2002-02-01 Understanding the effects of wildfire on the carbon (C) cycle of boreal forests is essential to quantifying the role of boreal forests in the global carbon cycle. Soil surface CO2 flux (Rs), the second largest C flux in boreal forests, is directly and indirectly affected by fire and is hypothesized to change during forest succession following fire. The overall objective of this study was to measure and model Rs for a black spruce (Picea mariana [Mill.] BSP) postfire chronosequence in northern Manitoba, Canada. The experiment design was a nested factorial that included two soil drainage classes (well and poorly drained) × seven postfire aged stands. Specific objectives were (1) to quantify the relationship between Rs and soil temperature for different aged boreal black spruce forests in well-drained and poorly drained soil conditions, (2) to examine Rs dynamics along postfire successional stands, and (3) to estimate annual soil surface CO2 flux for these ecosystems. Soil surface CO2 flux was significantly affected by soil drainage class (p = 0.014) and stand age (p = 0.006). Soil surface CO2 flux was positively correlated to soil temperature (R2 = 0.78, p < 0.001), but different models were required for each drainage class × aged stand combination. Soil surface CO2 flux was significantly greater at the well-drained than the poorly drained stands (p = 0.007) during growing season. Annual soil surface CO2 flux for the 1998, 1995, 1989, 1981, 1964, 1930, and 1870 burned stands averaged 226, 412, 357, 413, 350, 274, and 244 g C m-2 yr-1 in the well-drained stands and 146, 380, 300, 303, 256, 233, and 264 g C m-2 yr-1 in the poorly drained stands. Soil surface CO2 flux during the winter (from 1 November to 30 April) comprised from 5 to 19% of the total annual Rs. We speculate that the smaller soil surface CO2 flux in the recently burned than the older stands is mainly caused by decreased root respiration. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AGUFM.V21C3048H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AGUFM.V21C3048H">Controls on the fore-arc CO2 flux along the Central America margin</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Hilton, D. R.; Barry, P. H.; Ramirez, C. J.; Kulongoski, J. T.; Patel, B. S.; Virrueta, C.; Blackmon, K. 2015-12-01 The subduction of carbon to the deep mantle via subduction zones is interrupted by outputs via the fore-arc, volcanic front, and back-arc regions. Whereas output fluxes for arc and back-arc locales are well constrained for the Central America Volcanic Arc (CAVA) [1-2], the fore-arc flux via cold seeps and ground waters is poorly known. We present new He and CO2 data (isotopes and relative abundances) for the volcanic front and inner fore-arc of western Panama to complement on-going studies of fore-arc C-fluxes in Costa Rica [3-4] and to determine tectonic controls on the fore-arc C-outgassing fluxes. Helium isotope (3He/4He) values at Baru, La Yeguada, and El Valle volcanoes are high (5-8RA), consistent with results for other Central America volcanoes. However, CO2/3He values are variable (from > 1012 to < 108). Baru has an arc-like δ13C of - 4‰, whereas the other volcanoes have δ13C < -10 ‰. Cold seeps collected in the coastal fore-arc of Panama show a trend of decreasing He-isotopes from west (~6RA) to east (~1RA). This trend is mirrored by δ13C (-5‰ to <-20‰) values. CO2/3He values of the seeps are also variable and fall between 106 and 1012. Using CO2/3He-δ13C mixing plots with conventional endmember values for Limestone, Organic Sediment and Mantle CO2, we show that several Panama samples have been extensively modified by crustal processes. Nevertheless, there are clear west-to east trends (both volcanoes and coastal seeps), whereby L dominates the CO2 inventory in the west, similar to Costa Rica, and S-derived CO2 increases eastward towards central Panama. Previously [4], we limited the Costa Rica subaerial fore-arc flux to ~ 6 × 107 gCkm-1yr-1, or ~ 4% of the total incoming sedimentary C-load. This flux diminishes to zero within ~400 km to the east of Baru volcano. The transition from orthogonal subduction of the Cocos Plate to oblique subduction of the Nazca Plate, relative to the common over-riding Caribbean Plate, is the major impediment to </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_7");'>7</a></li> <li><a href="#" onclick='return showDiv("page_8");'>8</a></li> <li class="active">9</li> <li><a href="#" onclick='return showDiv("page_10");'>10</a></li> <li><a href="#" onclick='return showDiv("page_11");'>11</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_10" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_8");'>8</a></li> <li><a href="#" onclick='return showDiv("page_9");'>9</a></li> <li class="active">10</li> <li><a href="#" onclick='return showDiv("page_11");'>11</a></li> <li><a href="#" onclick='return showDiv("page_12");'>12</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="181"> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..1915319D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..1915319D">Quantifying the magnitude and spatiotemporal variation of aquatic CO2 fluxes in a sub-tropical karst catchment, Southwest China</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Ding, Hu; Waldron, Susan; Newton, Jason; Garnett, Mark H. 2017-04-01 The role played by rivers in regional and global C budgets is receiving increasing attention. A large portion of the carbon transported via inland waters is returned to the atmosphere by carbon dioxide evasion from rivers and lakes. Karst landscapes represent an important C store on land, and are also considered to play an important role in climate regulation by consuming atmospheric CO2 during chemical weathering. However, we cannot be certain how effective this sink is if we do not know how efficiently the rivers draining karst landscapes remobilise weathered C to the atmosphere as CO2. pCO2 in karst waters is generally greater than atmospheric equilibrium, indicating that there can be a net CO2 efflux to the atmosphere. However, measurement confirming this and quantifying flux rates has been rarely conducted. Using a floating chamber method, in 2016 we directly measured CO2 fluxes from spatially distributed freshwaters (springs, sinkholes, streams and reservoirs/ponds) in the Houzhai Catchment, a karst region in SW China. Fluxes ranged from -0.5 to +267.4 μmol CO2 m-2s-1, and most sites showed seasonal variations with higher CO2 efflux rates in the wet (April - September) than dry season (October - March). There was a significant positive relationship between CO2 efflux and flow velocity, indicating that hydraulic controls on CO2 efflux from flowing water are important, while for water with little movement (sinkholes and reservoirs/ponds), pCO2 appears a more important control on efflux rates. Conditions similar to this study area may exist in many sub-tropical rivers that drain karst landscapes in South China. These waters are rich in DIC which can be an order of magnitude greater than some non-karst catchments. The large DIC pool has the potential to be a considerable source of free CO2 to the atmosphere. Considering that carbonate lithology covers a significant part of the Earth's surface, CO2 evasion in fluvial water from these regions is expected to </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/26324399','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/26324399">New ground-based lidar enables volcanic CO2 flux measurements.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Aiuppa, Alessandro; Fiorani, Luca; Santoro, Simone; Parracino, Stefano; Nuvoli, Marcello; Chiodini, Giovanni; Minopoli, Carmine; Tamburello, Giancarlo 2015-09-01 There have been substantial advances in the ability to monitor the activity of hazardous volcanoes in recent decades. However, obtaining early warning of eruptions remains challenging, because the patterns and consequences of volcanic unrests are both complex and nonlinear. Measuring volcanic gases has long been a key aspect of volcano monitoring since these mobile fluids should reach the surface long before the magma. There has been considerable progress in methods for remote and in-situ gas sensing, but measuring the flux of volcanic CO2-the most reliable gas precursor to an eruption-has remained a challenge. Here we report on the first direct quantitative measurements of the volcanic CO2 flux using a newly designed differential absorption lidar (DIAL), which were performed at the restless Campi Flegrei volcano. We show that DIAL makes it possible to remotely obtain volcanic CO2 flux time series with a high temporal resolution (tens of minutes) and accuracy (<30%). The ability of this lidar to remotely sense volcanic CO2 represents a major step forward in volcano monitoring, and will contribute improved volcanic CO2 flux inventories. Our results also demonstrate the unusually strong degassing behavior of Campi Flegrei fumaroles in the current ongoing state of unrest. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..19.4204Z','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..19.4204Z">Global CO2 flux inversions from remote-sensing data with systematic errors using hierarchical statistical models</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Zammit-Mangion, Andrew; Stavert, Ann; Rigby, Matthew; Ganesan, Anita; Rayner, Peter; Cressie, Noel 2017-04-01 The Orbiting Carbon Observatory-2 (OCO-2) satellite was launched on 2 July 2014, and it has been a source of atmospheric CO2 data since September 2014. The OCO-2 dataset contains a number of variables, but the one of most interest for flux inversion has been the column-averaged dry-air mole fraction (in units of ppm). These global level-2 data offer the possibility of inferring CO2 fluxes at Earth's surface and tracking those fluxes over time. However, as well as having a component of random error, the OCO-2 data have a component of systematic error that is dependent on the instrument's mode, namely land nadir, land glint, and ocean glint. Our statistical approach to CO2-flux inversion starts with constructing a statistical model for the random and systematic errors with parameters that can be estimated from the OCO-2 data and possibly in situ sources from flasks, towers, and the Total Column Carbon Observing Network (TCCON). Dimension reduction of the flux field is achieved through the use of physical basis functions, while temporal evolution of the flux is captured by modelling the basis-function coefficients as a vector autoregressive process. For computational efficiency, flux inversion uses only three months of sensitivities of mole fraction to changes in flux, computed using MOZART; any residual variation is captured through the modelling of a stochastic process that varies smoothly as a function of latitude. The second stage of our statistical approach is to simulate from the posterior distribution of the basis-function coefficients and all unknown parameters given the data using a fully Bayesian Markov chain Monte Carlo (MCMC) algorithm. Estimates and posterior variances of the flux field can then be obtained straightforwardly from this distribution. Our statistical approach is different than others, as it simultaneously makes inference (and quantifies uncertainty) on both the error components' parameters and the CO2 fluxes. We compare it to more classical </li> <li> <a target="_blank" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70023234','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70023234">High CO2 emissions through porous media: Transport mechanisms and implications for flux measurement and fractionation</a> <a target="_blank" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Evans, William C.; Sorey, M.L.; Kennedy, B.M.; Stonestrom, David A.; Rogie, J.D.; Shuster, D.L. 2001-01-01 Diffuse emissions of CO2 are known to be large around some volcanoes and hydrothermal areas. Accumulation-chamber measurements of CO2 flux are increasingly used to estimate the total magmatic or metamorphic CO2 released from such areas. To assess the performance of accumulation chamber systems at fluxes one to three orders of magnitude higher than normally encountered in soil respiration studies, a test system was constructed in the laboratory where known fluxes could be maintained through dry sand. Steady-state gas concentration profiles and fractionation effects observed in the 30-cm sand column nearly match those predicted by the Stefan-Maxwell equations, indicating that the test system was functioning successfully as a uniform porous medium. Eight groups of investigators tested their accumulation chamber equipment, all configured with continuous infrared gas analyzers (IRGA), in this system. Over a flux range of ~ 200-12,000 g m-2 day-1, 90% of their 203 flux measurements were 0-25% lower than the imposed flux with a mean difference of - 12.5%. Although this difference would seem to be within the range of acceptability for many geologic investigations, some potential sources for larger errors were discovered. A steady-state pressure gradient of -20 Pa/m was measured in the sand column at a flux of 11,200 g m-2 day-1. The derived permeability (50 darcies) was used in the dusty-gas model (DGM) of transport to quantify various diffusive and viscous flux components. These calculations were used to demonstrate that accumulation chambers, in addition to reducing the underlying diffusive gradient, severely disrupt the steady-state pressure gradient. The resultant diversion of the net gas flow is probably responsible for the systematically low flux measurements. It was also shown that the fractionating effects of a viscous CO2 efflux against a diffusive influx of air will have a major impact on some important geochemical indicators, such as N2/Ar, ??15N-N2, and 4He/22 </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.A14G..06A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.A14G..06A">Studying emissions of CO2 in the Baltimore/Washington area using airborne measurements: source attribution, flux quantification, and model comparison</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Ahn, D.; Hansford, J. R.; Salawitch, R. J.; Ren, X.; Cohen, M.; Karion, A.; Whetstone, J. R.; Salmon, O. E.; Shepson, P. B.; Gurney, K. R.; Osterman, G. B.; Dickerson, R. R. 2017-12-01 We study emissions of CO2 in the Baltimore-Washington area using airborne in-situ measurements, obtained during the February 2015 Fluxes of Greenhouse Gases in Maryland (FLAGG-MD) campaign. In this study, we attributed enhanced signals of CO2 to several power plants and two urban areas (Baltimore City and Washington, DC), using the NOAA HYSPLIT air parcel trajectory model as well as the analysis of chemical ratios to quantify the source/receptor relationship. Then, the fluxes of attributed CO2 are estimated using a mass balance approach. The uncertainty in the aircraft-based mass balance approach is estimated by conducting a detailed sensitivity analysis of CO2 fluxes, considering factors such as the background mixing ratio of CO2, wind direction and speed, PBL heights, the horizontal boundary, and vertical interpolation methods. Estimated fluxes of CO2 with estimated uncertainty ranges are then compared to output from various emissions data and models, such as CEMS, CarbonTracker, FFDAS, and ODIAC. Finally, column CO2 data over the Baltimore-Washington region observed by the OCO-2 satellite instrument are statistically compared to aircraft in-situ observations, to assess how well OCO-2 is able to quantify geographic and synoptic-scale variability. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015EGUGA..17.8639K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015EGUGA..17.8639K">Net drainage effects on CO2 fluxes of a permafrost ecosystem through eddy-covariance measurements</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Kittler, Fanny; Burjack, Ina; Zimov, Nikita; Zimov, Sergey; Heimann, Martin; Göckede, Mathias 2015-04-01 Permafrost landscapes in the Northern high latitudes with their massive organic carbon stocks are critically important for the global carbon cycle, yet feedback processes with the atmosphere under future climate conditions are uncertain. To improve the understanding of mechanisms and drivers dominating permafrost carbon cycling, we established a continuous observation program in moist tussock tundra ecosystem near Cherskiy in North-eastern Siberia (68.75°N, 161.33°E). The experiment has been designed to monitor carbon cycle fluxes at different scales with different approaches, including e.g. the eddy-covariance technique, and their environmental drivers. Recent observations started mid July 2013 and are still ongoing, while 'historic' measurements are available for the period 2002-2005. Since 2004 part of the observation area has been disturbed by a drainage ditch ring, altering the soil water conditions in the surrounding area in a way that is expected for degrading ice-rich permafrost under a warming climate. With parallel observations over the disturbed (drained) area and a reference area nearby, respectively, we aim to evaluate the disturbance effect on the carbon cycle budgets and the dominating biogeochemical mechanisms. Here, findings based on over 1.5 years of continuous eddy-covariance CO2 flux measurements (July 2013 - March 2015) for both observation areas are presented. Results show systematic shifts in the tundra ecosystem as a result of 10 years of disturbance in the drained area, with significant effects on biotic and abiotic site conditions as well as on the carbon cycle dynamics. Comparing the net budget fluxes between both observations areas indicates a reduction of the net sink strength for CO2 of the drained ecosystem during the summer season in comparison to natural conditions, mostly caused by reduced CO2 uptake with low water levels in late summer. Regarding the long-term CO2 uptake dynamics of the disturbance regime (2005 vs. 2013/14) the </li> <li> <a target="_blank" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20110011454&hterms=Koch&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D30%26Ntt%3DKoch','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20110011454&hterms=Koch&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D30%26Ntt%3DKoch">Can CO2 Turbulent Flux Be Measured by Lidar? A Preliminary Study</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Gilbert, Fabien; Koch, Grady; Beyon, Jeffrey Y.; Hilton, Timothy W.; Davis, Kenneth J.; Andrews, Arlyn; Flamant, Pierre H.; Singh, Upendra N. 2011-01-01 The vertical profiling ofCO2 turbulent fluxes in the atmospheric boundary layer (ABL) is investigated using a coherent differential absorption lidar (CDIAL) operated nearby a tall tower in Wisconsin during June 2007. A CDIAL can perform simultaneous range-resolved CO2 DIAL and velocity measurements. The lidar eddy covariance technique is presented. The aims of the study are (i) an assessment of performance and current limitation of available CDIAL for CO2 turbulent fluxes and (ii) the derivation of instrument specifications to build a future CDIAL to perform accurate range-resolved CO2 fluxes. Experimental lidar CO2 mixing ratio and vertical velocity profiles are successfully compared with in situ sensors measurements. Time and space integral scales of turbulence in the ABL are addressed that result in limitation for time averaging and range accumulation. A first attempt to infer CO2 fluxes using an eddy covariance technique with currently available 2-mm CDIAL dataset is reported. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.fs.usda.gov/treesearch/pubs/42020','TREESEARCH'); return false;" href="https://www.fs.usda.gov/treesearch/pubs/42020">Seasonal soil CO2 flux under big sagebrush (Artemisia tridentata Nutt.)</a> <a target="_blank" href="http://www.fs.usda.gov/treesearch/">Treesearch</a> Michael C. Amacher; Cheryl L. Mackowiak 2011-01-01 Soil respiration is a major contributor to atmospheric CO2, but accurate landscape-scale estimates of soil CO2 flux for many ecosystems including shrublands have yet to be established. We began a project to measure, with high spatial and temporal resolution, soil CO2 flux in a stand (11 x 25 m area) of big sagebrush (Artemisia tridentata Nutt.) at the Logan, Utah,... </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011AGUFM.A41B0088V','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011AGUFM.A41B0088V">CO2 fluxes from a tropical neighborhood: sources and sinks</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Velasco, E.; Roth, M.; Tan, S.; Quak, M.; Britter, R.; Norford, L. 2011-12-01 Cities are the main contributors to the CO2 rise in the atmosphere. The CO2 released from the various emission sources is typically quantified by a bottom-up aggregation process that accounts for emission factors and fossil fuel consumption data. This approach does not consider the heterogeneity and variability of the urban emission sources, and error propagation can result in large uncertainties. In this context, direct measurements of CO2 fluxes that include all major and minor anthropogenic and natural sources and sinks from a specific district can be used to evaluate emission inventories. This study reports and compares CO2 fluxes measured directly using the eddy covariance method with emissions estimated by emissions factors and activity data for a residential neighborhood of Singapore, a highly populated and urbanized tropical city. The flux measurements were conducted during one year. No seasonal variability was found as a consequence of the constant climate conditions of tropical places; but a clear diurnal pattern with morning and late afternoon peaks in phase with the rush-hour traffic was observed. The magnitude of the fluxes throughout daylight hours is modulated by the urban vegetation, which is abundant in terms of biomass but not of land-cover (15%). Even though the carbon uptake by vegetation is significant, it does not exceed the anthropogenic emissions and the monitored district is a net CO2 source of 20.3 ton km-2 day-1 on average. The carbon uptake by vegetation is investigated as the difference between the estimated emissions and the measured fluxes during daytime. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013AGUFM.B51D0296M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013AGUFM.B51D0296M">Microbial imprint on soil-atmosphere H2, COS, and CO2 fluxes</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Meredith, L. K.; Commane, R.; Munger, J. W.; Wofsy, S. C.; Prinn, R. G. 2013-12-01 Microorganisms drive large trace gas fluxes between soil and atmosphere, but the signal can be difficult to detect and quantify in the presence of stronger exchange processes in an ecosystem. Partitioning methods are often needed to estimate trace gas budgets and to develop process-based models to explore the sensitivity of microbe-mediated fluxes. In this study, we test the performance of trace gases with predominantly microbe-mediated soil fluxes as a metric of the soil microbial uptake activity of other trace gases. Using simultaneous, collocated measurements at Harvard Forest, we consider three trace gases with microbe-mediated soil fluxes of various importance relative to their other (mainly plant-mediated) ecosystem fluxes: molecular hydrogen (H2), carbonyl sulfide (COS), and carbon dioxide (CO2). These gases probe different aspects of the soil trace-gas microbiology. Soil H2 uptake is a redox reaction driving the energy metabolism of a portion of the microbial community, while soil CO2 respiration is a partial proxy for the overall soil microbial metabolism. In comparison, very little is understood about the microbiological and environmental drivers of soil COS uptake and emissions. In this study, we find that H2, COS, and CO2 soil uptake rates are often correlated, but the relative soil uptake between gases is not constant, and is influenced by seasonality and local environmental conditions. We also consider how differences in the microbial communities and pathways involved in the soil fluxes may explain differences in the observations. Our results are important for informing previous studies using tracer approaches. For example, H2 has been used to estimate COS soil uptake, which must be accounted for to use COS as a carbon cycle tracer. Furthermore, the global distribution of H2 deposition velocity has been inferred from net primary productivity (CO2). Given that insufficient measurement frequency and spatial distribution exists to partition global net </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018PhyB..528...24L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018PhyB..528...24L">Effect of fluxing treatment on the properties of Fe66Co15Mo1P7.5C5.5B2Si3 bulk metallic glass by water quenching</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Li, Jin-Feng; Wang, Xin; Liu, Xue; Zhao, Shao-Fan; Yao, Ke-Fu 2018-01-01 The effect of fluxing treatment on the properties of Fe66Co15Mo1P7.5C5.5B2Si3bulk amorphous alloy (BAA) has been investigated. Prepared by a combination method of flux treatment and water quenching, the Fe66Co15Mo1P7.5C5.5B2Si3 BAA exhibits better glass-forming ability, thermal stability, soft magnetic properties and ductility than those of the one prepared by direct water quenching. This indicates that fluxing treatment can play a potential role in improving the properties of Fe-based BAA due to the effective elimination of the impurities within the alloy. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/biblio/1355087-measuring-co-mass-transfer-gap-co-capture-solvents-varied-water-loadings','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/1355087-measuring-co-mass-transfer-gap-co-capture-solvents-varied-water-loadings">Measuring CO 2 and N 2 O Mass Transfer into GAP-1 CO 2 –Capture Solvents at Varied Water Loadings</a> <a target="_blank" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Whyatt, Greg A.; Zwoster, Andy; Zheng, Feng This paper investigates the CO 2 and N 2 O absorption behavior in the water-lean gamma amino propyl (GAP)-1/TEG solvent system using a wetted-wall contactor. Testing was performed on a blend of GAP-1 aminosilicone in triethylene glycol at varied water loadings in the solvent. Measurements were made with CO 2 and N 2 O at representative lean (0.04 mol CO 2/mol alkalinity), middle (0.13 mol CO 2 /mol alkalinity) and rich (0.46 mol CO 2 /mol alkalinity) solvent loadings at 0, 5, 10 and 15 wt% water loadings at 40, 60 and 80C° and N 2 O at (0.08-0.09 molmore » CO 2 /mol alkalinity) at 5 wt% water at 40, 60 and 80C°. CO 2 flux was found to be non-linear with respect to log mean pressure driving force (LMPD). Liquid-film mass transfer coefficients (k'g) were calculated by subtracting the gas film resistance (determined from a correlation from literature) from the overall mass transfer measurement. The resulting k'g values for CO 2 and N 2 O in GAP-1/TEG mixtures were found to be higher than that of 5M aqueous monoethanolamine under comparable driving force albeit at higher solvent viscosities. The k'g values for CO 2 were also found to decrease with increasing solvent water content and increase with a decrease in temperature. These observations indicate that mass transfer of CO 2 in GAP-1/TEG is linked to the physical solubility of CO 2 , which is higher in organic solvents compared to water. This paper expands on the understanding of the unique mass transfer behavior and kinetics of CO 2 capture in water-lean solvents.« less </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.B44D..06G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.B44D..06G">Effects of experimental warming and elevated CO2 on surface methane and CO2 fluxes from a boreal black spruce peatland</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Gill, A. L.; Finzi, A.; Hsieh, I. F.; Giasson, M. A. 2016-12-01 High latitude peatlands represent a major terrestrial carbon store sensitive to climate change, as well as a globally significant methane source. While elevated atmospheric carbon dioxide concentrations and warming temperatures may increase peat respiration and C losses to the atmosphere, reductions in peatland water tables associated with increased growing season evapotranspiration may alter the nature of trace gas emission and increase peat C losses as CO2 relative to methane (CH4). As CH4 is a greenhouse gas with twenty times the warming potential of CO2, it is critical to understand how surface fluxes of CO2 and CH4 will be influenced by factors associated with global climate change. We used automated soil respiration chambers to assess the influence of elevated atmospheric CO2 and whole ecosystem warming on peatland CH4 and CO2 fluxes at the SPRUCE (Spruce and Peatland Responses Under Climatic and Environmental Change) Experiment in northern Minnesota. Here we report soil iCO2 and iCH4 flux responses to the first year of belowground warming and the first season of whole ecosystem warming and elevated CO2 treatments. We find that peat methane fluxes are more sensitive to warming treatments than peat CO2 fluxes, particularly in hollow peat microforms. Surface CO2:CH4 flux ratios decreased across warming treatments, suggesting that the temperature sensitivity of methane production overshadows the effect of peat drying and surface aeration in the short term. δ13C of the emitted methane was more depleted in the early and late growing season, indicating a transition from hydrogenotrophic to acetoclastic methanogenesis during periods of high photosynthetic input. The measurement record demonstrates that belowground warming has measureable impacts on the nature of peat greenhouse gas emission within one year of treatment. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017JGRG..122.3238C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017JGRG..122.3238C">Grain Yield Observations Constrain Cropland CO2 Fluxes Over Europe</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Combe, M.; de Wit, A. J. W.; Vilà-Guerau de Arellano, J.; van der Molen, M. K.; Magliulo, V.; Peters, W. 2017-12-01 Carbon exchange over croplands plays an important role in the European carbon cycle over daily to seasonal time scales. A better description of this exchange in terrestrial biosphere models—most of which currently treat crops as unmanaged grasslands—is needed to improve atmospheric CO2 simulations. In the framework we present here, we model gross European cropland CO2 fluxes with a crop growth model constrained by grain yield observations. Our approach follows a two-step procedure. In the first step, we calculate day-to-day crop carbon fluxes and pools with the WOrld FOod STudies (WOFOST) model. A scaling factor of crop growth is optimized regionally by minimizing the final grain carbon pool difference to crop yield observations from the Statistical Office of the European Union. In a second step, we re-run our WOFOST model for the full European 25 × 25 km gridded domain using the optimized scaling factors. We combine our optimized crop CO2 fluxes with a simple soil respiration model to obtain the net cropland CO2 exchange. We assess our model's ability to represent cropland CO2 exchange using 40 years of observations at seven European FluxNet sites and compare it with carbon fluxes produced by a typical terrestrial biosphere model. We conclude that our new model framework provides a more realistic and strongly observation-driven estimate of carbon exchange over European croplands. Its products will be made available to the scientific community through the ICOS Carbon Portal and serve as a new cropland component in the CarbonTracker Europe inverse model. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/biblio/6151749','DOE-PATENT-XML'); return false;" href="https://www.osti.gov/biblio/6151749">Process for analyzing CO[sub 2] in air and in water</a> <a target="_blank" href="http://www.osti.gov/doepatents">DOEpatents</a> Atwater, J.E.; Akse, J.R.; DeHart, J. 1999-06-08 The process of this invention comprises providing a membrane for separating CO[sub 2] into a first CO[sub 2] sample phase and a second CO[sub 2] analyte phase. CO[sub 2] is then transported through the membrane thereby separating the CO[sub 2] with the membrane into a first CO[sub 2] sample phase and a second CO[sub 2] analyte liquid phase including an ionized, conductive, dissociated CO[sub 2] species. Next, the concentration of the ionized, conductive, dissociated CO[sub 2] species in the second CO[sub 2] analyte liquid phase is chemically amplified using a water-soluble chemical reagent which reversibly reacts with undissociated CO[sub 2] to produce conductivity changes therein corresponding to fluctuations in the partial pressure of CO[sub 2] in the first CO[sub 2] sample phase. Finally, the chemically amplified, ionized, conductive, dissociated CO[sub 2] species is introduced to a conductivity measuring instrument. Conductivity changes in the chemically amplified, ionized, conductive, dissociated CO[sub 2] species are detected using the conductivity measuring instrument. 43 figs. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/872321','DOE-PATENT-XML'); return false;" href="https://www.osti.gov/servlets/purl/872321">Process for analyzing CO.sub.2 in air and in water</a> <a target="_blank" href="http://www.osti.gov/doepatents">DOEpatents</a> Atwater, James E.; Akse, James R.; DeHart, Jeffrey 1999-01-01 The process of this invention comprises providing a membrane for separating CO.sub.2 into a first CO.sub.2 sample phase and a second CO.sub.2 analyte phase. CO.sub.2 is then transported through the membrane thereby separating the CO.sub.2 with the membrane into a first CO.sub.2 sample phase and a second CO.sub.2 analyte liquid phase including an ionized, conductive, dissociated CO.sub.2 species. Next, the concentration of the ionized, conductive, dissociated CO.sub.2 species in the second CO.sub.2 analyte liquid phase is chemically amplified using a water-soluble chemical reagent which reversibly reacts with undissociated CO.sub.2 to produce conductivity changes therein corresponding to fluctuations in the partial pressure of CO.sub.2 in the first CO.sub.2 sample phase. Finally, the chemically amplified, ionized, conductive, dissociated CO.sub.2 species is introduced to a conductivity measuring instrument. Conductivity changes in the chemically amplified, ionized, conductive, dissociated CO.sub.2 species are detected using the conductivity measuring instrument. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011BGeo....8..505M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011BGeo....8..505M">Changes in ocean circulation and carbon storage are decoupled from air-sea CO2 fluxes</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Marinov, I.; Gnanadesikan, A. 2011-02-01 The spatial distribution of the air-sea flux of carbon dioxide is a poor indicator of the underlying ocean circulation and of ocean carbon storage. The weak dependence on circulation arises because mixing-driven changes in solubility-driven and biologically-driven air-sea fluxes largely cancel out. This cancellation occurs because mixing driven increases in the poleward residual mean circulation result in more transport of both remineralized nutrients and heat from low to high latitudes. By contrast, increasing vertical mixing decreases the storage associated with both the biological and solubility pumps, as it decreases remineralized carbon storage in the deep ocean and warms the ocean as a whole. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2010BGD.....7.7985M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2010BGD.....7.7985M">Changes in ocean circulation and carbon storage are decoupled from air-sea CO2 fluxes</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Marinov, I.; Gnanadesikan, A. 2010-11-01 The spatial distribution of the air-sea flux of carbon dioxide is a poor indicator of the underlying ocean circulation and of ocean carbon storage. The weak dependence on circulation arises because mixing-driven changes in solubility-driven and biologically-driven air-sea fluxes largely cancel out. This cancellation occurs because mixing driven increases in the poleward residual mean circulation results in more transport of both remineralized nutrients and heat from low to high latitudes. By contrast, increasing vertical mixing decreases the storage associated with both the biological and solubility pumps, as it decreases remineralized carbon storage in the deep ocean and warms the ocean as a whole. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/23712111','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/23712111">Dynamics of CO2 fluxes and environmental responses in the rain-fed winter wheat ecosystem of the Loess Plateau, China.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Wang, Wen; Liao, Yuncheng; Wen, Xiaoxia; Guo, Qiang 2013-09-01 Chinese Loess Plateau plays an important role in carbon balance of terrestrial ecosystems. Continuous measurement of CO2 fluxes in cropland ecosystem is of great significance to accurately evaluate the carbon sequestration potential and to better explain the carbon cycle process in this region. By using the eddy covariance system we conducted a long-term (from Sep 2009 to Jun 2010) CO2 fluxes measurement in the rain-fed winter wheat field of the Chinese Loess Plateau and elaborated the responses of CO2 fluxes to environmental factors. The results show that the winter wheat ecosystem has distinct seasonal dynamics of CO2 fluxes. The total net ecosystem CO2 exchange (NEE) of -218.9±11.5 gC m(-2) in the growing season, however, after considering the harvested grain, the agro-ecosystem turned into a weak carbon sink (-36.2 gC m(-2)). On the other hand, the responses of CO2 fluxes to environmental factors depended on different growth stages of winter wheat and different ranges of environmental variables, suggesting that the variations in CO2 exchange were sensitive to the changes in controlling factors. Particularly, we found the pulse response of ecosystem respiration (Reco) to a large rainfall event, and the strong fluctuations of CO2 fluxes usually appeared after effective rainfall events (daily precipitation > 5 mm) during middle growing season. Such phenomenon also occurred in the case of the drastic changes in air temperature and within 5 days after field management (e.g. tillage and plough). Copyright © 2013 The Authors. Published by Elsevier B.V. All rights reserved. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://hdl.handle.net/2060/20180002067','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20180002067">The Impact of Prior Biosphere Models in the Inversion of Global Terrestrial CO2 Fluxes by Assimilating OCO-2 Retrievals</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Philip, Sajeev; Johnson, Matthew S. 2018-01-01 Atmospheric mixing ratios of carbon dioxide (CO2) are largely controlled by anthropogenic emissions and biospheric fluxes. The processes controlling terrestrial biosphere-atmosphere carbon exchange are currently not fully understood, resulting in terrestrial biospheric models having significant differences in the quantification of biospheric CO2 fluxes. Atmospheric transport models assimilating measured (in situ or space-borne) CO2 concentrations to estimate "top-down" fluxes, generally use these biospheric CO2 fluxes as a priori information. Most of the flux inversion estimates result in substantially different spatio-temporal posteriori estimates of regional and global biospheric CO2 fluxes. The Orbiting Carbon Observatory 2 (OCO-2) satellite mission dedicated to accurately measure column CO2 (XCO2) allows for an improved understanding of global biospheric CO2 fluxes. OCO-2 provides much-needed CO2 observations in data-limited regions facilitating better global and regional estimates of "top-down" CO2 fluxes through inversion model simulations. The specific objectives of our research are to: 1) conduct GEOS-Chem 4D-Var assimilation of OCO-2 observations, using several state-of-the-science biospheric CO2 flux models as a priori information, to better constrain terrestrial CO2 fluxes, and 2) quantify the impact of different biospheric model prior fluxes on OCO-2-assimilated a posteriori CO2 flux estimates. Here we present our assessment of the importance of these a priori fluxes by conducting Observing System Simulation Experiments (OSSE) using simulated OCO-2 observations with known "true" fluxes. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_8");'>8</a></li> <li><a href="#" onclick='return showDiv("page_9");'>9</a></li> <li class="active">10</li> <li><a href="#" onclick='return showDiv("page_11");'>11</a></li> <li><a href="#" onclick='return showDiv("page_12");'>12</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_11" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_9");'>9</a></li> <li><a href="#" onclick='return showDiv("page_10");'>10</a></li> <li class="active">11</li> <li><a href="#" onclick='return showDiv("page_12");'>12</a></li> <li><a href="#" onclick='return showDiv("page_13");'>13</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="201"> <li> <a target="_blank" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20120003648&hterms=budget&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D50%26Ntt%3Dbudget','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20120003648&hterms=budget&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D50%26Ntt%3Dbudget">Sensitivity of Terrestrial Water and Energy Budgets to CO2-Physiological Forcing: An Investigation Using an Offline Land Model</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Gopalakrishnan, Ranjith; Bala, Govindsamy; Jayaraman, Mathangi; Cao, Long; Nemani, Ramakrishna; Ravindranath, N. H. 2011-01-01 Increasing concentrations of atmospheric carbon dioxide (CO2) influence climate by suppressing canopy transpiration in addition to its well-known greenhouse gas effect. The decrease in plant transpiration is due to changes in plant physiology (reduced opening of plant stomata). Here, we quantify such changes in water flux for various levels of CO2 concentrations using the National Center for Atmospheric Research s (NCAR) Community Land Model. We find that photosynthesis saturates after 800 ppmv (parts per million, by volume) in this model. However, unlike photosynthesis, canopy transpiration continues to decline at about 5.1% per 100 ppmv increase in CO2 levels. We also find that the associated reduction in latent heat flux is primarily compensated by increased sensible heat flux. The continued decline in canopy transpiration and subsequent increase in sensible heat flux at elevated CO2 levels implies that incremental warming associated with the physiological effect of CO2 will not abate at higher CO2 concentrations, indicating important consequences for the global water and carbon cycles from anthropogenic CO2 emissions. Keywords: CO2-physiological effect, CO2-fertilization, canopy transpiration, water cycle, runoff, climate change 1. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.A43C2466P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.A43C2466P">Assessing the Importance of Prior Biospheric Fluxes on Inverse Model Estimates of CO2</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Philip, S.; Johnson, M. S.; Potter, C. S.; Genovese, V. B. 2017-12-01 Atmospheric mixing ratios of carbon dioxide (CO2) are largely controlled by anthropogenic emissions and biospheric sources/sinks. The processes controlling terrestrial biosphere-atmosphere carbon exchange are currently not fully understood, resulting in models having significant differences in the quantification of biospheric CO2 fluxes. Currently, atmospheric chemical transport models (CTM) and global climate models (GCM) use multiple different biospheric CO2 flux models resulting in large differences in simulating the global carbon cycle. The Orbiting Carbon Observatory 2 (OCO-2) satellite mission was designed to allow for the improved understanding of the processes involved in the exchange of carbon between terrestrial ecosystems and the atmosphere, and therefore allowing for more accurate assessment of the seasonal/inter-annual variability of CO2. OCO-2 provides much-needed CO2 observations in data-limited regions allowing for the evaluation of model simulations of greenhouse gases (GHG) and facilitating global/regional estimates of "top-down" CO2 fluxes. We conduct a 4-D Variation (4D-Var) data assimilation with the GEOS-Chem (Goddard Earth Observation System-Chemistry) CTM using 1) OCO-2 land nadir and land glint retrievals and 2) global in situ surface flask observations to constrain biospheric CO2 fluxes. We apply different state-of-the-science year-specific CO2 flux models (e.g., NASA-CASA (NASA-Carnegie Ames Stanford Approach), CASA-GFED (Global Fire Emissions Database), Simple Biosphere Model version 4 (SiB-4), and LPJ (Lund-Postdam-Jena)) to assess the impact of "a priori" flux predictions to "a posteriori" estimates. We will present the "top-down" CO2 flux estimates for the year 2015 using OCO-2 and in situ observations, and a complete indirect evaluation of the a priori and a posteriori flux estimates using independent in situ observations. We will also present our assessment of the variability of "top-down" CO2 flux estimates when using different </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AGUFM.B22E..06O','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AGUFM.B22E..06O">Progress Toward Measuring CO2 Isotopologue Fluxes in situ with the LLNL Miniature, Laser-based CO2 Sensor</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Osuna, J. L.; Bora, M.; Bond, T. 2015-12-01 One method to constrain photosynthesis and respiration independently at the ecosystem scale is to measure the fluxes of CO2 isotopologues. Instrumentation is currently available to makes these measurements but they are generally costly, large, bench-top instruments. Here, we present progress toward developing a laser-based sensor that can be deployed directly to a canopy to passively measure CO2 isotopologue fluxes. In this study, we perform initial proof-of-concept and sensor characterization tests in the laboratory and in the field to demonstrate performance of the Lawrence Livermore National Laboratory (LLNL) tunable diode laser flux sensor. The results shown herein demonstrate measurement of bulk CO2 as a first step toward achieving flux measurements of CO2 isotopologues. The sensor uses a Vertical Cavity Surface Emitting Laser (VCSEL) in the 2012 nm range. The laser is mounted in a multi-pass White Cell. In order to amplify the absorption signal of CO2 in this range we employ wave modulation spectroscopy, introducing an alternating current (AC) bias component where f is the frequency of modulation on the laser drive current in addition to the direct current (DC) emission scanning component. We observed a strong linear relationship (r2 = 0.998 and r2 = 0.978 at all and low CO2 concentrations, respectively) between the 2f signal and the CO2 concentration in the cell across the range of CO2 concentrations relevant for flux measurements. We use this calibration to interpret CO2 concentration of a gas flowing through the White cell in the laboratory and deployed over a grassy field. We will discuss sensor performance in the lab and in situ as well as address steps toward achieving canopy-deployed, passive measurements of CO2 isotopologue fluxes. This work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. LLNL-ABS-675788 </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2003EAEJA....11892I','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2003EAEJA....11892I">CO2 flux response to precipitation events in Juniperus osteosperma and Artemisia tridentata ecosystems using eddy covariance measurements</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Ivans, S.; Hipps, L. E. 2003-04-01 Eddy covariance measurements were used to determine the seasonal changes of net CO_2 flux, and the response to intermittent precipitation events in juniper (Juniperus osteosperma) and sagebrush (Artemisia tridentata) plant communities in a semi-arid region in the Great Basin of the United States over the entire growing seasons of 2001 and 2002. The net CO_2 fluxes were negative or downward in each community during the spring when soil water availability was largest. During this time, rain events resulted in large increases of net CO_2 uptake in juniper within 24 hours after the rain. The relative increases were larger in the dry spring of 2001 compared to the wetter conditions of 2002. Response of sage to rain events in the spring was smaller in magnitude. During the dry periods of summer and early fall net CO_2 flux was upward at each site in both years. In these periods the respiration of soil and vegetation apparently exceeded any assimilation by the plants. During these dry periods increases in CO_2 efflux were observed at both sites following rain events, presumably as a result of increases in soil respiration. The response of CO_2 fluxes to these events lasted generally 2 to 3 days. During late fall and early winter, no significant changes in CO_2 fluxes were observed at either site in response to rainfall because of significantly lower temperatures and plant dormancy in the year 2001. However in 2002, because of warmer weather, rainfall events triggered a temporary change in the flux direction at both sites from CO_2 efflux to CO_2 uptake, suggesting that the plants were actively photosynthesizing. Energy balance closure values for both sites ranged from 0.75--0.80 in the moist conditions of spring, and increased to 0.80--0.85 in the dry conditions of summer and fall. It is not yet clear why energy balance closure is dependent upon the relative sizes of sensible and latent heat fluxes. The issue of whether or not to force closure by adding to the fluxes </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28526196','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28526196">Use of a numerical simulation approach to improve the estimation of air-water exchange fluxes of polycyclic aromatic hydrocarbons in a coastal zone.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Lai, I-Chien; Lee, Chon-Lin; Ko, Fung-Chi; Lin, Ju-Chieh; Huang, Hu-Ching; Shiu, Ruei-Feng 2017-07-15 The air-water exchange is important for determining the transport, fate, and chemical loading of polycyclic aromatic hydrocarbons (PAHs) in the atmosphere and in aquatic systems. Investigations of PAH air-water exchange are mostly based on observational data obtained using complicated field sampling processes. This study proposes a new approach to improve the estimation of long-term PAH air-water exchange fluxes by using a multivariate regression model to simulate hourly gaseous PAH concentrations. Model performance analysis and the benefits from this approach indicate its effectiveness at improving the flux estimations and at decreasing the field sampling difficulty. The proposed GIS mapping approach is useful for box model establishment and is tested for visualization of the spatiotemporal variations of air-water exchange fluxes in a coastal zone. The air-water exchange fluxes illustrated by contour maps suggest that the atmospheric PAHs might have greater impacts on offshore sites than on the coastal area in this study. Copyright © 2017 Elsevier Ltd. All rights reserved. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011AGUFM.H51K1361Z','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011AGUFM.H51K1361Z">Effects of cold front passage on turbulent fluxes over a large inland water</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Zhang, Q.; Liu, H. 2011-12-01 Turbulent fluxes of sensible and latent heat over a large inland water in southern USA were measured using the eddy covariance method through the year of 2008. In addition, net radiation, air temperatures and relative humidity, and water temperature in different depths were also measured. The specific objective of this study is to examine effects of a cold front passage on the surface energy fluxes. For the typical cold front event selected from April 11 to 14, air temperature decreased by 16°C, while surface temperature only dropped 6°C. Atmospheric vapor pressure decreased by 1.6 kPa, while that in the water-air interface dropped 0.7 kPa. The behavior difference in the water-air interface was caused by the passage of cold, dry air masses immediately behind the cold front. During the cold front event, sensible heat and latent heat flux increased by 171 W m-2 and 284 W m-2, respectively. Linear aggression analysis showed that the sensible heat flux was proportional to the product of wind speed and the temperature gradient of water-air interface, with a correlation coefficient of 0.95. Latent heat flux was proportional to the product of wind speed and vapor pressure difference between the water surface and overlaying atmosphere, with a correlation coefficient of 0.81. Also, the correlations between both fluxes and the wind speed were weak. This result indicated that the strong wind associated with the cold front event contributed to the turbulent mixing, which indirectly enhanced surface energy exchange between the water surface and the atmosphere. The relationship between the water heat storage energy and turbulent fluxes was also examined. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2010AGUFM.B23A0388H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2010AGUFM.B23A0388H">Solution for Minimizing Surface Heating Effect for Fast Open-Path CO2 Flux Measurements in Cold Environments</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Hupp, J. R.; Burba, G. G.; McDermitt, D. K.; Anderson, D. J.; Eckles, R. D. 2010-12-01 Open-path design of the high speed gas analyzers is a well-established configuration widely used for measurements of CO2 fluxes and concentrations. This configuration has advantages and deficiencies. Advantages include excellent frequency response, long-term stability, low sensitivity to window contamination, low-power pump-free operation, and infrequent calibration requirements. Deficiencies include susceptibility to precipitation and icing, and a potential need for instrument surface heating correction in extremely cold environments. In spite of the deficiencies, open-path measurements often provide data coverage that would not have been possible using traditional closed-path approach. Data loss from precipitation and icing may not always be prevented for the open-path instruments, while heating effect does not pose a problem for CO2 flux in warm environments. Even in cold environments, the impact of heating on CO2 flux is much smaller than other well-known effects, such as Webb-Pearman-Leuning terms, or frequency response corrections for closed-path analyzers. Nonetheless, instrument surface heating effect in cold environments could be addressed scientifically, via developing the theoretical corrections, and instrumentally, via measuring fast integrated air temperature in the optical path, or via enclosing the open-path instrument into a low-power short-intake design. Here we provide an alternative way to minimize or eliminate open-path heating effect, achieved by minimizing or eliminating the temperature gradient between the instrument surface and ambient air. Open-path low temperature controlled design is discussed in comparison with two other approaches (e.g., traditional open-path design and closed-path design) in terms of their field performance for Eddy Covariance flux measurements in the cold. This study presents field data from a new open-path CO2/H2O gas analyzer, LI-7500A, based on the LI-7500 model modified to produce substantially less heat during </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2005TellB..57....1M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2005TellB..57....1M">Soil CO2 flux from three ecosystems in tropical peatland of Sarawak, Malaysia</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Melling, Lulie; Hatano, Ryusuke; Goh, Kah Joo 2005-02-01 Soil CO2 flux was measured monthly over a year from tropical peatland of Sarawak, Malaysia using a closed-chamber technique. The soil CO2 flux ranged from 100 to 533 mg C m<img src="/entityImage/script/2212.gif" alt="-" border="0" style="font-weight: bold"></img>2 h<img src="/entityImage/script/2212.gif" alt="-" border="0" style="font-weight: bold"></img>1 for the forest ecosystem, 63 to 245 mg C m<img src="/entityImage/script/2212.gif" alt="-" border="0" style="font-weight: bold"></img>2 h<img src="/entityImage/script/2212.gif" alt="-" border="0" style="font-weight: bold"></img>1 for the sago and 46 to 335 mg C m<img src="/entityImage/script/2212.gif" alt="-" border="0" style="font-weight: bold"></img>2 h<img src="/entityImage/script/2212.gif" alt="-" border="0" style="font-weight: bold"></img>1 for the oil palm. Based on principal component analysis (PCA), the environmental variables over all sites could be classified into three components, namely, climate, soil moisture and soil bulk density, which accounted for 86% of the seasonal variability. A regression tree approach showed that CO2 flux in each ecosystem was related to different underlying environmental factors. They were relative humidity for forest, soil temperature at 5 cm for sago and water-filled pore space for oil palm. On an annual basis, the soil CO2 flux was highest in the forest ecosystem with an estimated production of 2.1 kg C m<img src="/entityImage/script/2212.gif" alt="-" border="0" style="font-weight: bold"></img>2 yr<img src="/entityImage/script/2212.gif" alt="-" border="0" style="font-weight: bold"></img>1 followed by oil palm at 1.5 kg C m<img src="/entityImage/script/2212.gif" alt="-" border="0" style="font-weight: bold"></img>2 yr<img src="/entityImage/script/2212.gif" alt="-" border="0" style="font-weight: bold"></img>1 and sago at 1.1 kg C m<img src="/entityImage/script/2212.gif" alt="-" border="0" style="font-weight: bold"></img>2 yr<img src="/entityImage/script/2212.gif" alt </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014EGUGA..16...26P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014EGUGA..16...26P">Volcanic CO2 mapping and flux measurements at Campi Flegrei by Tunable Diode Laser absorption Spectroscopy</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Pedone, Maria; Aiuppa, Alessandro; Giudice, Gaetano; Grassa, Fausto; Chiodini, Giovanni; Valenza, Mariano 2014-05-01 Near-infrared room-temperature Tunable Diode Lasers (TDL) have recently found increased usage in atmospheric chemistry and air monitoring research, but applications in Volcanology are still limited to a few examples. Here, we explored the potentiality of a commercial infrared laser unit (GasFinder 2.0 from Boreal Laser Ltd) to measurement of volcanic CO2 flux emissions. Our field tests were conducted at Campi Flegrei (near Pozzuoli, Southern Italy), where the GasFinder was used (during three campaigns in October 2012, January 2013 and May 2013) to repeatedly measure the path-integrated concentrations of CO2 along cross-sections of the atmospheric plumes of the two main fumarolic fields in the area (Solfatara and Pisciarelli). By using ad-hoc designed field-set-up and a tomographic post-processing routine, we resolved, for each of the 2 manifestations, the contour maps of CO2 concentrations in their atmospheric plumes, from the integration of which (and after multiplication by the plumes' transport speeds) the CO2 fluxes were finally obtained [1]. The so-calculated fluxes average of 490 tons/day, which agrees well with independent evaluations of Aiuppa et al. (2013) [2] (460 tons/day on average), and support a significant contribution of fumaroles to the total CO2 budget. The cumulative (fumarole [this study] +soil [2]) CO2 output from Campi Flegrei is finally evaluated at 1600 tons/day. The application of lasers to volcanic gas studies is still an emerging (though intriguing) research field, and requires more testing and validation experiments. We conclude that TDL technique may valuably assist CO2 flux quantification at a number of volcanic targets worldwide. [1] Pedone M. et al. (2013) Gold2013:abs:5563, Goldschmidt Conference, session 11a. [2] Aiuppa A. et al. (2013) Geochemistry Geophysics Geosystems. doi: 10.1002/ggge.20261. [3] Chiodini G. et al. (2010) Journal of Geophysical Research, Volume 115, B03205. doi:10.1029/2008JB006258. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=85598&Lab=NERL&keyword=control+AND+group+AND+experimental&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=85598&Lab=NERL&keyword=control+AND+group+AND+experimental&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">SOIL FLUXES OF CO2, CO, NO AND N2O FROM AN OLD-PASTURE AND FROM NATIVE SAVANNA IN BRAZIL</a> <a target="_blank" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> We compared fluxes of CO2, CO, NO and N2O, soil microbial biomass, and N-mineralization rates in a 20-year old Brachiaria pasture and a native cerrado area (savanna in Central Brazil). In order to assess the spatial variability of CO2 fluxes, we tested the relation between elect... </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014JVGR..284..122P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014JVGR..284..122P">Fluid geochemistry and soil gas fluxes (CO2-CH4-H2S) at a promissory Hot Dry Rock Geothermal System: The Acoculco caldera, Mexico</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Peiffer, L.; Bernard-Romero, R.; Mazot, A.; Taran, Y. A.; Guevara, M.; Santoyo, E. 2014-09-01 The Acoculco caldera has been recognized by the Mexican Federal Electricity Company (CFE) as a Hot Dry Rock Geothermal System (HDR) and could be a potential candidate for developing an Enhanced Geothermal System (EGS). Apart from hydrothermally altered rocks, geothermal manifestations within the Acoculco caldera are scarce. Close to ambient temperature bubbling springs and soil degassing are reported inside the caldera while a few springs discharge warm water on the periphery of the caldera. In this study, we infer the origin of fluids and we characterize for the first time the soil degassing dynamic. Chemical and isotopic (δ18O-δD) analyses of spring waters indicate a meteoric origin and the dissolution of CO2 and H2S gases, while gas chemical and isotopic compositions (N2/He, 3He/4He, 13C, 15N) reveal a magmatic contribution with both MORB- and arc-type signatures which could be explained by an extension regime created by local and regional fault systems. Gas geothermometry results are in agreement with temperature measured during well drilling (260 °C-300 °C). Absence of well-developed water reservoir at depth impedes re-equilibration of gases upon surface. A multi-gas flux survey including CO2, CH4 and H2S measurements was performed within the caldera. Using the graphical statistical analysis (GSA) approach, CO2 flux measurements were classified in two populations. Population A, representing 95% of measured fluxes is characterized by low values (mean: 18 g m- 2 day- 1) while the remaining 5% fluxes belonging to Population B are much higher (mean: 5543 g m- 2 day- 1). This low degassing rate probably reflects the low permeability of the system, a consequence of the intense hydrothermal alteration observed in the upper 800 m of volcanic rocks. An attempt to interpret the origin and transport mechanism of these fluxes is proposed by means of flux ratios as well as by numerical modeling. Measurements with CO2/CH4 and CO2/H2S flux ratios similar to mass ratios </li> <li> <a target="_blank" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20150005617&hterms=infrared+temperature+sensor&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D20%26Ntt%3Dinfrared%2Btemperature%2Bsensor','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20150005617&hterms=infrared+temperature+sensor&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D20%26Ntt%3Dinfrared%2Btemperature%2Bsensor">Sensitivity Analysis for Atmospheric Infrared Sounder (AIRS) CO2 Retrieval</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Gat, Ilana 2012-01-01 The Atmospheric Infrared Sounder (AIRS) is a thermal infrared sensor able to retrieve the daily atmospheric state globally for clear as well as partially cloudy field-of-views. The AIRS spectrometer has 2378 channels sensing from 15.4 micrometers to 3.7 micrometers, of which a small subset in the 15 micrometers region has been selected, to date, for CO2 retrieval. To improve upon the current retrieval method, we extended the retrieval calculations to include a prior estimate component and developed a channel ranking system to optimize the channels and number of channels used. The channel ranking system uses a mathematical formalism to rapidly process and assess the retrieval potential of large numbers of channels. Implementing this system, we identifed a larger optimized subset of AIRS channels that can decrease retrieval errors and minimize the overall sensitivity to other iridescent contributors, such as water vapor, ozone, and atmospheric temperature. This methodology selects channels globally by accounting for the latitudinal, longitudinal, and seasonal dependencies of the subset. The new methodology increases accuracy in AIRS CO2 as well as other retrievals and enables the extension of retrieved CO2 vertical profiles to altitudes ranging from the lower troposphere to upper stratosphere. The extended retrieval method for CO2 vertical profile estimation using a maximum-likelihood estimation method. We use model data to demonstrate the beneficial impact of the extended retrieval method using the new channel ranking system on CO2 retrieval. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/27363345','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/27363345">Grazing effects on ecosystem CO2 fluxes differ among temperate steppe types in Eurasia.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Hou, Longyu; Liu, Yan; Du, Jiancai; Wang, Mingya; Wang, Hui; Mao, Peisheng 2016-07-01 Grassland ecosystems play a critical role in regulating CO2 fluxes into and out of the Earth's surface. Whereas previous studies have often addressed single fluxes of CO2 separately, few have addressed the relation among and controls of multiple CO2 sub-fluxes simultaneously. In this study, we examined the relation among and controls of individual CO2 fluxes (i.e., GEP, NEP, SR, ER, CR) in three contrasting temperate steppes of north China, as affected by livestock grazing. Our findings show that climatic controls of the seasonal patterns in CO2 fluxes were both individual flux- and steppe type-specific, with significant grazing impacts observed for canopy respiration only. In contrast, climatic controls of the annual patterns were only individual flux-specific, with minor grazing impacts on the individual fluxes. Grazing significantly reduced the mean annual soil respiration rate in the typical and desert steppes, but significantly enhanced both soil and canopy respiration in the meadow steppe. Our study suggests that a reassessment of the role of livestock grazing in regulating GHG exchanges is imperative in future studies. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013AGUFM.B31H..08S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013AGUFM.B31H..08S">CO2, CH4, and DOC Flux During Long Term Thaw of High Arctic Tundra</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Stackhouse, B. T.; Vishnivetskaya, T. A.; Layton, A.; Bennett, P.; Mykytczuk, N.; Lau, C. M.; Whyte, L.; Onstott, T. C. 2013-12-01 Arctic regions are expected to experience temperature increases of >4° C by the end of this century. This warming is projected to cause a drastic reduction in the extent of permafrost at high northern latitudes, affecting an estimated 1000 Pg of SOC in the top 3 m. Determining the effects of this temperature change on CO2 and CH4 emissions is critical for defining source constraints to global climate models. To investigate this problem, 18 cores of 1 m length were collected in late spring 2011 before the thawing of the seasonal active layer from an ice-wedge polygon near the McGill Arctic Research Station (MARS) on Axel Heiberg Island, Nunavut, Canada (N79°24, W90°45). Cores were collected from acidic soil (pH 5.5) with low SOC (~1%), summertime active layer depth between 40-70 cm (2010-2013), and sparse vegetation consisting primarily of small shrubs and sedges. Cores were progressively thawed from the surface over the course of 14 weeks to a final temperature of 4.5° C and held at that temperature for 15 months under the following conditions: in situ water saturation conditions versus fully water saturated conditions using artificial rain fall, surface light versus no surface light, cores from the polygon edge, and control cores with a permafrost table maintained at 70 cm depth. Core headspaces were measured weekly for CO2, CH4, H2, CO, and O2 flux during the 18 month thaw experiment. After ~20 weeks of thawing maximum, CO2 flux for the polygon edge and dark treatment cores were 3.0×0.7 and 1.7×0.4 mmol CO2 m-2 hr-1, respectively. The CO2 flux for the control, saturated, and in situ saturation cores reached maximums of 0.6×0.2, 0.9×0.5, and 0.9×0.1 mmol CO2 m-2 hr-1, respectively. Field measurements of CO2 flux from an adjacent polygon during the mid-summer of 2011 to 2013 ranged from 0.3 to 3.7 mmol CO2 m-2 hr-1. Cores from all treatments except water saturated were found to consistently oxidize CH4 at ~atmospheric concentrations (2 ppmv) with a maximum </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29136323','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29136323">Increasing canopy photosynthesis in rice can be achieved without a large increase in water use-A model based on free-air CO2 enrichment.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Ikawa, Hiroki; Chen, Charles P; Sikma, Martin; Yoshimoto, Mayumi; Sakai, Hidemitsu; Tokida, Takeshi; Usui, Yasuhiro; Nakamura, Hirofumi; Ono, Keisuke; Maruyama, Atsushi; Watanabe, Tsutomu; Kuwagata, Tsuneo; Hasegawa, Toshihiro 2018-03-01 Achieving higher canopy photosynthesis rates is one of the keys to increasing future crop production; however, this typically requires additional water inputs because of increased water loss through the stomata. Lowland rice canopies presently consume a large amount of water, and any further increase in water usage may significantly impact local water resources. This situation is further complicated by changing the environmental conditions such as rising atmospheric CO 2 concentration ([CO 2 ]). Here, we modeled and compared evapotranspiration of fully developed rice canopies of a high-yielding rice cultivar (Oryza sativa L. cv. Takanari) with a common cultivar (cv. Koshihikari) under ambient and elevated [CO 2 ] (A-CO 2 and E-CO 2 , respectively) via leaf ecophysiological parameters derived from a free-air CO 2 enrichment (FACE) experiment. Takanari had 4%-5% higher evapotranspiration than Koshihikari under both A-CO 2 and E-CO 2 , and E-CO 2 decreased evapotranspiration of both varieties by 4%-6%. Therefore, if Takanari was cultivated under future [CO 2 ] conditions, the cost for water could be maintained at the same level as for cultivating Koshihikari at current [CO 2 ] with an increase in canopy photosynthesis by 36%. Sensitivity analyses determined that stomatal conductance was a significant physiological factor responsible for the greater canopy photosynthesis in Takanari over Koshihikari. Takanari had 30%-40% higher stomatal conductance than Koshihikari; however, the presence of high aerodynamic resistance in the natural field and lower canopy temperature of Takanari than Koshihikari resulted in the small difference in evapotranspiration. Despite the small difference in evapotranspiration between varieties, the model simulations showed that Takanari clearly decreased canopy and air temperatures within the planetary boundary layer compared to Koshihikari. Our results indicate that lowland rice varieties characterized by high-stomatal conductance can play a </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013EGUGA..15.7939Z','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013EGUGA..15.7939Z">Application of Relaxed Eddy Accumulation (REA) method to estimate CO2 and CH4 surface fluxes in the city of Krakow, southern Poland.</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Zimnoch, Miroslaw; Gorczyca, Zbigniew; Pieniazek, Katarzyna; Jasek, Alina; Chmura, Lukasz; Rozanski, Kazimierz 2013-04-01 There is a growing interest in the recent years in studies aimed at quantifying carbon cycling in urban centres. Worldwide migration of human population from rural to urban areas and corresponding growth of extensive urban agglomerations and megacities leads to intensification of anthropogenic emissions of carbon and strong disruption of natural carbon cycle on these areas. Therefore, a deeper understanding of the carbon "metabolism" of such regions is required. Apart of better quantification of surface carbon fluxes, also a thorough understanding of the functioning of biosphere under strong anthropogenic influence is needed. Nowadays, covariance methods are widely applied for studying gas exchange between the atmosphere and the Earth's surface. Relaxed Eddy Accumulation method (REA), combined with the CO2 and CH4 CRDS analyser allows simultaneous measurements of surface fluxes of carbon dioxide and methane within the chosen footprint of the detection system, thus making possible thorough characterisation of the overall exchange of those gases between the atmosphere and the urban surface across diverse spatial and temporal scales. Here we present preliminary results of the study aimed at quantifying surface fluxes of CO2 and CH4 in Krakow, southern Poland. The REA system for CO2 and CH4 flux measurements has been installed on top of a 20m high tower mounted on the roof of the faculty building, close to the city centre of Krakow. The sensors were installed ca 42 m above the local ground. Gill Windmaster-Pro sonic anemometer was coupled with self-made system, designed by the Poznan University of Life Sciences, Poland, for collecting air samples in two pairs of 10-liter Tedlar bags, and with Picarro G2101-i CRDS analyser. The air was collected in 30-min intervals. The CO2 and CH4 mixing ratios in these cumulative downdraft and updraft air samples were determined by the CRDS analyser after each sampling interval. Based on the measured mixing ratios difference and the </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4237463','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4237463">Net uptake of atmospheric CO2 by coastal submerged aquatic vegetation</a> <a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Tokoro, Tatsuki; Hosokawa, Shinya; Miyoshi, Eiichi; Tada, Kazufumi; Watanabe, Kenta; Montani, Shigeru; Kayanne, Hajime; Kuwae, Tomohiro 2014-01-01 ‘Blue Carbon’, which is carbon captured by marine living organisms, has recently been highlighted as a new option for climate change mitigation initiatives. In particular, coastal ecosystems have been recognized as significant carbon stocks because of their high burial rates and long-term sequestration of carbon. However, the direct contribution of Blue Carbon to the uptake of atmospheric CO2 through air-sea gas exchange remains unclear. We performed in situ measurements of carbon flows, including air-sea CO2 fluxes, dissolved inorganic carbon changes, net ecosystem production, and carbon burial rates in the boreal (Furen), temperate (Kurihama), and subtropical (Fukido) seagrass meadows of Japan from 2010 to 2013. In particular, the air-sea CO2 flux was measured using three methods: the bulk formula method, the floating chamber method, and the eddy covariance method. Our empirical results show that submerged autotrophic vegetation in shallow coastal waters can be functionally a sink for atmospheric CO2. This finding is contrary to the conventional perception that most near-shore ecosystems are sources of atmospheric CO2. The key factor determining whether or not coastal ecosystems directly decrease the concentration of atmospheric CO2 may be net ecosystem production. This study thus identifies a new ecosystem function of coastal vegetated systems; they are direct sinks of atmospheric CO2. PMID:24623530 </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014AGUFM.B31C0032K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014AGUFM.B31C0032K">Water, energy and CO2 exchange over a seasonally flooded forest in the Sahel.</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Kergoat, L.; Le Dantec, V.; Timouk, F.; Hiernaux, P.; Mougin, E.; Manuela, G.; Diawara, M. 2014-12-01 In semi-arid areas like the Sahel, perennial water bodies and temporary-flooded lowlands are critical for a number of activities. In some cases, their existence is simply a necessary condition for human societies to establish. They also play an important role in the water and carbon cycle and have strong ecological values. As a result of the strong multi-decadal drought that impacted the Sahel in the 70' to 90', a paradoxical increase of ponds and surface runoff has been observed ("Less rain, more water in the ponds", Gardelle 2010). In spite of this, there are excessively few data documenting the consequence of such a paradox on the water and carbon cycle. Here we present 2 years of eddy covariance data collected over the Kelma flooded Acacia forest in the Sahel (15.50 °N), in the frame of the AMMA project. The flooded forest is compared to the other major component of this Sahelian landscape: a grassland and a rocky outcrop sites. All sites are involved in the ALMIP2 data/LSM model comparison. The seasonal cycle of the flooded forest strongly departs from the surroundings grassland and bare soil sites. Before the rain season, the forest displays the strongest net radiation and sensible heat flux. Air temperature within the canopy reaches extremely high values. During the flood, it turns to the lowest sensible heat flux. In fact, due to an oasis effect, this flux is negative during the late flood. Water fluxes turn from almost zero in the dry season to strong evaporation during the flood, since it uses additional energy provided by negative sensible heat flux. The eddy covariance fluxes are consistent with sap flow data, showing that the flood greatly increases the length of the growing season. CO2 fluxes over the forest were twice as large as over the grassland, and the growing season was also longer, giving a much larger annual photosynthesis. In view of these data and data over surroundings grasslands and bare soil, as well as data from a long-term ecological </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2009AGUFM.H21E0900W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2009AGUFM.H21E0900W">LASER ABSORPTION SPECTROSCOPY METHODS FOR SUBSURFACE MONITORING OF CO2 IN WATER AND AIR PHASES AT SEQUESTRATION SITES</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Wu, S.; Romanak, K.; Yang, C. 2009-12-01 We report the development of two methods for subsurface monitoring of CO2 in both air and water phases at sequestration sites. The first method is based on line-of-sight (LOS) tunable laser spectroscopy. Funded by DOE, we demonstrated the Phase Insensitive Two Tone Frquency Modulation spectroscopy (PITTFM). FM reduces low frequency noise in the beam path due to scintillations; while the PI design gives the ease of installation. We demonstrated measurement over 1 mile distance with an accuracy of 3ppm of CO2 in normal air. Built-in switches shoot the laser beam into multi-directions, thus forming a cellular monitoring network covering 10 km^2. The system cost is under $100K, and COTS telecom components guarantee the reliability in the field over decades. Software will log the data and translate the 2D CO2 profile. When coupled with other parameters, it will be able to locate the point and rate of leakages. Field tests at SECARB sequestration site are proposed. The system also monitors other green house gases (GHG), e.g. CH4, which is also needed where EOR is pursued along with CO2 sequestration. Figures 1 through 2 give the results of this method. The second method is based on the latest technology advances in quantum cascade lasers (QCLs). The current state of the art technology to measure Total/Dissolved Inorganic Carbon (TIC/DIC) in water is menometer. Menometer is both time consuming and costly, and could not be used underground, i.e. high pressure and temperature. We propose to use high brightness QC lasers to extend the current Mid-IR optical path from 30 microns to over 500microns, thus providing the possibility to measure CO2 dissoveled (Aqueous phase) with an accuracy of 0.2mg/Liter. Preliminary results will be presented. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014AGUFM.B41D0082M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014AGUFM.B41D0082M">Annual Greenhouse Gas (CO2, CH4, and N2O) Fluxes Via Ebullition from a Temperate Emergent Wetland</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Mcnicol, G.; Sturtevant, C. S.; Knox, S. H.; Baldocchi, D. D.; Silver, W. L. 2014-12-01 Quantifying wetland greenhouse gas exchange is necessary to evaluate their potential for mitigating climate change via carbon sequestration. However measuring greenhouse gas fluxes of carbon dioxide (CO2), methane (CH4), and nitrous oxide (N2O) in wetlands is difficult due to high spatial and temporal variability, and multiple transport pathways of emission. Transport of biogenic soil gas via highly sporadic ebullition (bubbling) events is often ignored or quantified poorly in wetland greenhouse gas budgets, but can rapidly release large volumes of gas to the atmosphere. To quantify a robust annual ebullition flux we measured rates continuously for a year (2013-2014) using custom-built chambers deployed in a restored emergent wetland located in the Sacramento-San Joaquin Delta, CA. We combined ebullition flux rates with observations of gas concentrations to estimate annual ebullition emissions of CO2, CH4, and N2O and compare flux rates to whole-ecosystem exchange of CO2 and CH4 measured simultaneously by eddy covariance.Mean ebullition flux rates were 18.3 ± 5.6 L m-2 yr-1. Ebullition CH4 concentrations were very high and ranged from 23-76 % with a mean of 47 ± 2.9 %; CO2 concentrations were lower and ranged from 0.7-6.6 % with a mean of 2.8 ± 0.3 %; N2O concentrations were below atmospheric concentrations and ranged from 130-389 ppb(v) with a mean of 257 ± 13 ppb(v). We calculated well-constrained annual ebullition fluxes of: 6.2 ± 1.9 g CH4 m-2 yr-1, 1.0 ± 0.3 g CO2 m-2 yr-1 and 9.3 ± 2.8 mg N2O m-2 yr-1. Methane emissions via ebullition were very large, representing 15-25 % of total wetland CH4 emissions measured at this site, whereas ebullition released only relatively small quantities of CO2 and N2O. Our results demonstrate that large releases of CH4 via ebullition from open water surfaces can be a significant component of restored wetland greenhouse gas budgets. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_9");'>9</a></li> <li><a href="#" onclick='return showDiv("page_10");'>10</a></li> <li class="active">11</li> <li><a href="#" onclick='return showDiv("page_12");'>12</a></li> <li><a href="#" onclick='return showDiv("page_13");'>13</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_12" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_10");'>10</a></li> <li><a href="#" onclick='return showDiv("page_11");'>11</a></li> <li class="active">12</li> <li><a href="#" onclick='return showDiv("page_13");'>13</a></li> <li><a href="#" onclick='return showDiv("page_14");'>14</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="221"> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1020274','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1020274">Eddy Correlation Flux Measurement System (ECOR) Handbook</a> <a target="_blank" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Cook, DR 2011-01-31 The eddy correlation (ECOR) flux measurement system provides in situ, half-hour measurements of the surface turbulent fluxes of momentum, sensible heat, latent heat, and carbon dioxide (CO2) (and methane at one Southern Great Plains extended facility (SGP EF) and the North Slope of Alaska Central Facility (NSA CF). The fluxes are obtained with the eddy covariance technique, which involves correlation of the vertical wind component with the horizontal wind component, the air temperature, the water vapor density, and the CO2 concentration. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2008AGUFM.H23D1006B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2008AGUFM.H23D1006B">Multi-channel Auto-dilution System for Remote Continuous Monitoring of High Soil-CO2 Fluxes</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Barr, J. L.; Amonette, J. E. 2008-12-01 We describe a novel field instrument that takes input from up to 27 soil flux chambers and measures flux using the steady-state method. CO2 concentrations are determined with an infrared gas analyzer (IRGA, 0- 3000 ppmv range) with corrections for temperature, barometric pressure, and moisture content. The concentrations are monitored during data collection and, if they exceed the range of the IRGA, a stepped dilution program is automatically implemented that allows up to 50-fold dilution of the incoming gas stream with N2 supplied by boil-off from a large dewar. The upper concentration limit of the system with dilution is extended to at least 150,000 ppmv CO2. The data are stored on a datalogger having a cellular modem connection that allows remote control of the system as well as transmittal of data. The system is designed to operate for six weeks with no on-site maintenance required. Longer periods are possible with modifications to allow on-site generation of N2 from air. Example data from a recent CO2 test injection at the Zero- Emission Research and Technology (ZERT) field site in Bozeman, MT are presented. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013CorRe..32..239W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013CorRe..32..239W">Spatiotemporal variations in CO2 flux in a fringing reef simulated using a novel carbonate system dynamics model</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Watanabe, A.; Yamamoto, T.; Nadaoka, K.; Maeda, Y.; Miyajima, T.; Tanaka, Y.; Blanco, A. C. 2013-03-01 A carbonate system dynamics (CSD) model was developed in a fringing reef on the east coast of Ishigaki Island, southwest Japan, by incorporating organic and inorganic carbon fluxes (photosynthesis and calcification), air-sea gas exchanges, and benthic cover of coral and seagrass into a three-dimensional hydrodynamic model. The CSD model could reproduce temporal variations in dissolved inorganic carbon (DIC) and total alkalinity in coral zones, but not in seagrass meadows. The poor reproduction in seagrass meadows can be attributed to significant contributions of submarine groundwater discharge as well as misclassification of remotely sensed megabenthos in this area. In comparison with offshore areas, the reef acted as a CO2 sink during the observation period when it was averaged over 24 h. The CSD model also indicated large spatiotemporal differences in the carbon dioxide (CO2) sink/source, possibly related to hydrodynamic features such as effective offshore seawater exchange and neap/spring tidal variation. This suggests that the data obtained from a single point observation may lead to misinterpretation of the overall trend and thus should be carefully considered. The model analysis also showed that the advective flux of DIC from neighboring grids is several times greater than local biological flux of DIC and is three orders of magnitude greater than the air-sea gas flux at the coral zone. Sensitivity tests in which coral or seagrass covers were altered revealed that the CO2 sink potential was much more sensitive to changes in coral cover than seagrass cover. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.B33C0609S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.B33C0609S">Decadal trends in regional CO2 fluxes estimated from atmospheric inversions</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Saeki, T.; Patra, P. K. 2016-12-01 Top-down approach (or atmospheric inversion) using atmospheric transport models and CO2 observations are an effective way to optimize surface fluxes at subcontinental scales and monthly time intervals. We used the CCSR/NIES/FRCGC AGCM-based Chemistry Transport Model (JAMSTEC's ACTM) and atmospheric CO2 concentrations at NOAA, CSIRO, JMA, NIES, NIES-MRI sites from Obspack GLOBALVIEW-CO2 data product (2013) for estimating CO2 fluxes for the period of 1990-2011. Carbon fluxes were estimated for 84 partitions (54 lands + 30 oceans) of the globe by using a Bayesian synthesis inversion framework. A priori fluxes are (1) atmosphere-ocean exchange from Takahashi et al. (2009), (2) 3-hourly terrestrial biosphere fluxes (annually balanced) from CASA model, and (3) fossil fuel fluxes from CDIAC global totals and EDGAR4.2 spatial distributions. Four inversion cases have been tested with 1) 21 sites (sites which have real data fraction of 90 % or more for 1989-2012), 2) 21 sites + CONTRAIL data, 3) 66 sites (over 70 % coverage), and 4) 157 sites. As a result of time-dependent inversions, mean total flux (excluding fossil fuel) for the period 1990-2011 is estimated to be -3.09 ±0.16 PgC/yr (mean and standard deviation of the four cases), where land (incl. biomass burning and land use change) and ocean absorb an average rate of -1.80 ±0.18 and -1.29 ±0.08 PgC/yr, respectively. The average global total sink from 1991-2000 to 2001-2010 increases by about 0.5 PgC/yr, mainly due to the increase in northern and tropical land sinks (Africa, Boreal Eurasia, East Asia and Europe), while ocean sinks show no clear trend. Inversion with CONTRAIL data estimates large positive flux anomalies in late 1997 associated with the 1997/98 El-Nino, while inversion without CONTARIL data between Japan and Australia fails to estimate such large anomalies. Acknowledgements. This work is supported by the Environment Research and Technology Development Fund (2-1401) of the Ministry of the Environment </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018JOUC...17..320W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018JOUC...17..320W">Distributions and Relationships of CO2, O2, and Dimethylsulfide in the Changjiang (Yangtze) Estuary and Its Adjacent Waters in Summer</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Wu, Xi; Tan, Tingting; Liu, Chunying; Li, Tie; Liu, Xiaoshou; Yang, Guipeng 2018-04-01 The distributions and relationships of O2, CO2, and dimethylsulfide (DMS) in the Changjiang (Yangtze) Estuary and its adjacent waters were investigated in June 2014. In surface water, mean O2 saturation level, partial pressure of CO2 (pCO2), and DMS concentrations (and ranges) were 110% (89%-167%), 374 μatm (91-640 μatm), and 8.53 nmol L-1 (1.10-27.50 nmol L-1), respectively. The sea-to-air fluxes (and ranges) of DMS and CO2 were 8.24 μmol m-2 d-1 (0.26-62.77 μmol m-2 d-1), and -4.7 mmol m-2 d-1 (-110.8-31.7 mmol m-2 d-1), respectively. Dissolved O2 was oversaturated, DMS concentrations were relatively high, and this region served as a sink of atmospheric CO2. The pCO2 was significantly and negatively correlated with the O2 saturation level, while the DMS concentration showed different positive relationships with the O2 saturation level in different water masses. In vertical profiles, a hypoxic zone existed below 20 m at a longitude of 123°E. The stratification of temperature and salinity caused by the Taiwan Warm Current suppressed seawater exchange between upper and lower layers, resulting in the formation of a hypoxic zone. Oxidative decomposition of organic detritus carried by the Changjiang River Diluted Water (CRDW) consumed abundant O2 and produced additional CO2. The DMS concentrations decreased because of low phytoplankton biomass in the hypoxic zone. Strong correlations appeared between the O2 saturation level, pCO2 and DMS concentrations in vertical profiles. Our results strongly suggested that CRDW played an important role in the distributions and relationships of O2, CO2, and DMS. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014BGD....1117543L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014BGD....1117543L">Rapid establishment of the CO2 sink associated with Kerguelen's bloom observed during the KEOPS2/OISO20 cruise</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Lo Monaco, C.; Metzl, N.; D'Ovidio, F.; Llort, J.; Ridame, C. 2014-12-01 Iron and light are the main factors limiting the biological pump of CO2 in the Southern Ocean. Iron fertilization experiments have demonstrated the potential for increased uptake of atmospheric CO2, but little is known about the evolution of fertilized environnements. This paper presents observations collected in one of the largest phytoplankton bloom of the Southern Ocean sustained by iron originating from the Kerguelen Plateau. We first complement previous studies by investigating the mechanisms that control air-sea CO2 fluxes over and downstream of the Kerguelen Plateau at the onset of the bloom based on measurements obtained in October-November 2011. These new observations show the rapid establishment of a strong CO2 sink in waters fertilized with iron as soon as vertical mixing is reduced. The magnitude of the CO2 sink was closely related to chlorophyll a and iron concentrations. Because iron concentration strongly depends on the distance from the iron source and the mode of delivery, we identified lateral advection as the main mechanism controlling air-sea CO2 fluxes downtream the Kerguelen Plateau during the growing season. In the southern part of the bloom, situated over the Plateau (iron source), the CO2 sink was stronger and spatially more homogeneous than in the plume offshore. However, we also witnessed a substantial reduction in the uptake of atmospheric CO2 over the Plateau following a strong winds event. Next, we used all the data available in this region in order to draw the seasonal evolution of air-sea CO2 fluxes. The CO2 sink is rapidly reduced during the course of the growing season, which we attribute to iron and silicic acid depletion. South of the Polar Front, where nutrients depletion is delayed, we suggest that the amplitude and duration of the CO2 sink is mainly controlled by vertical mixing. The impact of iron fertilization on air-sea CO2 fluxes is revealed by comparing the uptake of CO2 integrated over the productive season in the bloom </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018ACP....18.7189B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018ACP....18.7189B">The impact of transport model differences on CO2 surface flux estimates from OCO-2 retrievals of column average CO2</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Basu, Sourish; Baker, David F.; Chevallier, Frédéric; Patra, Prabir K.; Liu, Junjie; Miller, John B. 2018-05-01 We estimate the uncertainty of CO2 flux estimates in atmospheric inversions stemming from differences between different global transport models. Using a set of observing system simulation experiments (OSSEs), we estimate this uncertainty as represented by the spread between five different state-of-the-art global transport models (ACTM, LMDZ, GEOS-Chem, PCTM and TM5), for both traditional in situ CO2 inversions and inversions of XCO2 estimates from the Orbiting Carbon Observatory 2 (OCO-2). We find that, in the absence of relative biases between in situ CO2 and OCO-2 XCO2, OCO-2 estimates of terrestrial flux for TRANSCOM-scale land regions can be more robust to transport model differences than corresponding in situ CO2 inversions. This is due to a combination of the increased spatial coverage of OCO-2 samples and the total column nature of OCO-2 estimates. We separate the two effects by constructing hypothetical in situ networks with the coverage of OCO-2 but with only near-surface samples. We also find that the transport-driven uncertainty in fluxes is comparable between well-sampled northern temperate regions and poorly sampled tropical regions. Furthermore, we find that spatiotemporal differences in sampling, such as between OCO-2 land and ocean soundings, coupled with imperfect transport, can produce differences in flux estimates that are larger than flux uncertainties due to transport model differences. This highlights the need for sampling with as complete a spatial and temporal coverage as possible (e.g., using both land and ocean retrievals together for OCO-2) to minimize the impact of selective sampling. Finally, our annual and monthly estimates of transport-driven uncertainties can be used to evaluate the robustness of conclusions drawn from real OCO-2 and in situ CO2 inversions. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29751299','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29751299">Net ecosystem exchange of CO2 and H2O fluxes from irrigated grain sorghum and maize in the Texas High Plains.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Wagle, Pradeep; Gowda, Prasanna H; Moorhead, Jerry E; Marek, Gary W; Brauer, David K 2018-05-08 Net ecosystem exchange (NEE) of carbon dioxide (CO 2 ) and water vapor (H 2 O) fluxes from irrigated grain sorghum (Sorghum bicolor L. Moench) and maize (Zea mays L.) fields in the Texas High Plains were quantified using the eddy covariance (EC) technique during 2014-2016 growing seasons and examined in terms of relevant controlling climatic variables. Eddy covariance measured evapotranspiration (ET EC ) was also compared against lysimeter measured ET (ET Lys ). Daily peak (7-day averages) NEE reached approximately -12 g C m -2 for sorghum and -14.78 g C m -2 for maize. Daily peak (7-day averages) ET EC reached approximately 6.5 mm for sorghum and 7.3 mm for maize. Higher leaf area index (5.7 vs 4-4.5 m 2  m -2 ) and grain yield (14 vs 8-9 t ha -1 ) of maize compared to sorghum caused larger magnitudes of NEE and ET EC in maize. Comparisons of ET EC and ET Lys showed a strong agreement (R 2  = 0.93-0.96), while the EC system underestimated ET by 15-24% as compared to lysimeter without any corrections or energy balance adjustments. Both NEE and ET EC were not inhibited by climatic variables during peak photosynthetic period even though diurnal peak values (~2-weeks average) of photosynthetic photon flux density (PPFD), air temperature (T a ), and vapor pressure deficit (VPD) had reached over 2000 μmol m -2  s -1 , 30 °C, and 2.5 kPa, respectively, indicating well adaptation of both C 4 crops in the Texas High Plains under irrigation. However, more sensitivity of NEE and H 2 O fluxes beyond threshold T a and VPD for maize than for sorghum indicated higher adaptability of sorghum for the region. These findings provide baseline information on CO 2 fluxes and ET for a minimally studied grain sorghum and offer a robust geographic comparison for maize outside the United States Corn Belt. However, longer-term measurements are required for assessing carbon and water dynamics of these globally important agro-ecosystems. Copyright � </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2010EGUGA..12.3916I','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2010EGUGA..12.3916I">Regional variability of grassland CO2 fluxes in Tyrol/Austria</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Irschick, Christoph; Hammerle, Albin; Haslwanter, Alois; Wohlfahrt, Georg 2010-05-01 ecosystem respiration (RECO), (ii) GPP depended mainly on the amount of incident photosynthetically active radiation and the amount of green plant matter, the scale of influence of these two factors varying fourfold between the sites, and not so much on the available water, (iii) RECO was mainly affected by the soil temperature, but some evidence for priming effects was also found, (iv) the NEE was mainly influenced by GPP and to a lower extent by RECO. Taken together our results indicate that even within the same ecosystem type exposed to similar climate and land use, site selection may strongly affect the resulting NEE estimates. References: [1] D.D. Baldocchi, "Breathing of the terrestrial biosphere: lessons learned from a global network of carbon dioxide flux measurement systems", Australian Journal of Botany vol.56 (2008) pp. 1-26. [2] A. Hammerle, A. Haslwanter, U. Tappeiner, A. Cernusca, G. Wohlfahrt, "Leaf area controls on energy partitioning of a temperate mountain grassland", Biogeosciences vol.5 (2008) pp. 421 431. [3] G. Wohlfahrt, A. Hammerle, A. Haslwanter, M. Bahn, U. Tappeiner, A. Cernusca, "Seasonal and inter-annual variability of the net ecosystem CO2 exchange of a temperate mountain grassland: effects of weather and management", Journal of Geophysical Research 113 (2008) D08110, doi:10.1029/2007JD009286. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/25482824','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/25482824">Response of wheat growth, grain yield and water use to elevated CO2 under a Free-Air CO2 Enrichment (FACE) experiment and modelling in a semi-arid environment.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> O'Leary, Garry J; Christy, Brendan; Nuttall, James; Huth, Neil; Cammarano, Davide; Stöckle, Claudio; Basso, Bruno; Shcherbak, Iurii; Fitzgerald, Glenn; Luo, Qunying; Farre-Codina, Immaculada; Palta, Jairo; Asseng, Senthold 2014-12-05 The response of wheat crops to elevated CO 2 (eCO 2 ) was measured and modelled with the Australian Grains Free-Air CO 2 Enrichment experiment, located at Horsham, Australia. Treatments included CO 2 by water, N and temperature. The location represents a semi-arid environment with a seasonal VPD of around 0.5 kPa. Over 3 years, the observed mean biomass at anthesis and grain yield ranged from 4200 to 10 200 kg ha -1 and 1600 to 3900 kg ha -1 , respectively, over various sowing times and irrigation regimes. The mean observed response to daytime eCO 2 (from 365 to 550 μmol mol -1 CO 2 ) was relatively consistent for biomass at stem elongation and at anthesis and LAI at anthesis and grain yield with 21%, 23%, 21% and 26%, respectively. Seasonal water use was decreased from 320 to 301 mm (P = 0.10) by eCO 2 , increasing water use efficiency for biomass and yield, 36% and 31%, respectively. The performance of six models (APSIM-Wheat, APSIM-Nwheat, CAT-Wheat, CROPSYST, OLEARY-CONNOR and SALUS) in simulating crop responses to eCO 2 was similar and within or close to the experimental error for accumulated biomass, yield and water use response, despite some variations in early growth and LAI. The primary mechanism of biomass accumulation via radiation use efficiency (RUE) or transpiration efficiency (TE) was not critical to define the overall response to eCO 2 . However, under irrigation, the effect of late sowing on response to eCO 2 to biomass accumulation at DC65 was substantial in the observed data (~40%), but the simulated response was smaller, ranging from 17% to 28%. Simulated response from all six models under no water or nitrogen stress showed similar response to eCO 2 under irrigation, but the differences compared to the dryland treatment were small. Further experimental work on the interactive effects of eCO 2 , water and temperature is required to resolve these model discrepancies. © 2014 John Wiley & Sons Ltd. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/27400026','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/27400026">Contrasting ecosystem CO2 fluxes of inland and coastal wetlands: a meta-analysis of eddy covariance data.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Lu, Weizhi; Xiao, Jingfeng; Liu, Fang; Zhang, Yue; Liu, Chang'an; Lin, Guanghui 2017-03-01 Wetlands play an important role in regulating the atmospheric carbon dioxide (CO 2 ) concentrations and thus affecting the climate. However, there is still lack of quantitative evaluation of such a role across different wetland types, especially at the global scale. Here, we conducted a meta-analysis to compare ecosystem CO 2 fluxes among various types of wetlands using a global database compiled from the literature. This database consists of 143 site-years of eddy covariance data from 22 inland wetland and 21 coastal wetland sites across the globe. Coastal wetlands had higher annual gross primary productivity (GPP), ecosystem respiration (R e ), and net ecosystem productivity (NEP) than inland wetlands. On a per unit area basis, coastal wetlands provided large CO 2 sinks, while inland wetlands provided small CO 2 sinks or were nearly CO 2 neutral. The annual CO 2 sink strength was 93.15 and 208.37 g C m -2 for inland and coastal wetlands, respectively. Annual CO 2 fluxes were mainly regulated by mean annual temperature (MAT) and mean annual precipitation (MAP). For coastal and inland wetlands combined, MAT and MAP explained 71%, 54%, and 57% of the variations in GPP, R e , and NEP, respectively. The CO 2 fluxes of wetlands were also related to leaf area index (LAI). The CO 2 fluxes also varied with water table depth (WTD), although the effects of WTD were not statistically significant. NEP was jointly determined by GPP and R e for both inland and coastal wetlands. However, the NEP/R e and NEP/GPP ratios exhibited little variability for inland wetlands and decreased for coastal wetlands with increasing latitude. The contrasting of CO 2 fluxes between inland and coastal wetlands globally can improve our understanding of the roles of wetlands in the global C cycle. Our results also have implications for informing wetland management and climate change policymaking, for example, the efforts being made by international organizations and enterprises to restore coastal </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013EGUGA..1511498F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013EGUGA..1511498F">Aircraft observations of the urban CO2 dome in London and calculated daytime CO2 fluxes at the urban-regional scale</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Font, Anna; Morgui, Josep Anton; Grimmond, Sue; Barratt, Benjamin 2013-04-01 Traffic, industry and energy production and consumption within urban boundaries emit great amounts of CO2 into the atmosphere, creating an urban increment of CO2 mixing ratios compared to the surrounding rural atmosphere. Monitoring CO2 within these 'urban domes' has been proposed as a means to evaluate the effectiveness of policies aiming to mitigate and reduce CO2 urban emissions (CMEGGE, 2010). London is the biggest urban conurbation in Western Europe with more than 8 million inhabitants, and it emitted roughly 45000 ktn CO2 in 2010 (DECC, 2012). In order to develop and implement observational strategies to measure the contribution of urban areas into the global carbon cycle, two airborne surveys were deployed using the Natural and Environment Research Council - Airborne Research and Survey Facility (NERC-ARSF). High frequency measurements of atmospheric CO2, O3, particles and meteorological variables were taken over London in October 2011 and July 2012. CO2 mixing ratios were measured by a Non-Dispersive IR instrument developed by AOS. In July 2012, a Cavity Ring-Down Spectroscopy (CDRS) instrument developed by PICARRO was deployed measuring CO2, CH4 and water vapour at 1Hz resolution. The objectives of the campaigns were to measure the CO2 dome over London and to calculate CO2 emissions at the urban-regional-scale. London was crossed by two transects (SW-NE and SSE-NNW) at an altitude of 360 m and vertical profiles up to 2000 m were carried out to characterize the structure of the atmosphere. Aircraft measurements allowed observation on how CO2 domes were shaped by meteorological conditions. In October 2011, the mean CO2 mixing ratio measured in London was on average 2 ppmv higher than the suburban measurements within the boundary layer. However, under low wind speeds, the CO2 mixing ratio in the urban mixing ratio peaked in central London (>10 ppmv) and decreased towards the city boundaries. Under windy conditions, the structure of the urban dome was </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017GeCoA.217..112B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017GeCoA.217..112B">Constraining the subsoil carbon source to cave-air CO2 and speleothem calcite in central Texas</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Bergel, Shelly J.; Carlson, Peter E.; Larson, Toti E.; Wood, Chris T.; Johnson, Kathleen R.; Banner, Jay L.; Breecker, Daniel O. 2017-11-01 Canonical models for speleothem formation and the subsurface carbon cycle invoke soil respiration as the dominant carbon source. However, evidence from some karst regions suggests that belowground CO2 originates from a deeper, older source. We therefore investigated the carbon sources to central Texas caves. Drip-water chemistry of two caves in central Texas implies equilibration with calcite at CO2 concentrations (PCO2_sat) higher than the maximum CO2 concentrations observed in overlying soils. This observation suggests that CO2 is added to waters after they percolate through the soils, which requires a subsoil carbon source. We directly evaluate the carbon isotope composition of the subsoil carbon source using δ13C measurements on cave-air CO2, which we independently demonstrate has little to no contribution from host rock carbon. We do so using the oxidative ratio, OR, defined as the number of moles of O2 consumed per mole of CO2 produced during respiration. However, additional belowground processes that affect O2 and CO2 concentrations, such as gas-water exchange and/or diffusion, may also influence the measured oxidative ratio, yielding an apparent OR (ORapparent). Cave air in Natural Bridge South Cavern has ORapparent values (1.09 ± 0.06) indistinguishable from those expected for respiration alone (1.08 ± 0.06). Pore space gases from soils above the cave have lower values (ORapparent = 0.67 ± 0.05) consistent with respiration and gas transport by diffusion. The simplest explanation for these observations is that cave air in NB South is influenced by respiration in open-system bedrock fractures such that neither diffusion nor exchange with water influence the composition of the cave air. The radiocarbon activities of NB South cave-air CO2 suggest the subsoil carbon source is hundreds of years old. The calculated δ13C values of the subsoil carbon source are consistent with tree-sourced carbon (perhaps decomposing root matter), the δ13C values of which </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011AGUFM.V21A2484W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011AGUFM.V21A2484W">Gas composition and soil CO2 flux at Changbaishan intra-plate volcano, NE China</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> wen, H.; Yang, T. F.; Guo, Z.; Fu, C.; Zhang, M. 2011-12-01 Changbaishan, located on the border of China and North Korea, is one of the most active volcanoes in China. This volcano violently erupted 1000 years ago and produced massive magma and widespread volcanic ash, resulting in one of the largest explosive eruptions during the last 2000 years. Recent gas emissions and seismic events in the Tianchi area suggested potential increasing volcanic activities. If that is so, then 1 million residents living on the crater flank shall be endangered by enormous volcanic hazards, including the threat of 2 billion tons of water in the crater lake . In order to better understand current status of Changbaishan, we investigated gas geochemistry in samples from the Tianchi crater lake and surrounding areas. Bubbling gas from hot springs were collected and analyzed. The results show that CO2 is the major component gas for most samples. The maximum value of helium isotopic ratio 5.8 RA (where RA = 3He/4He in air) implies more than 60% of helium is contributed by mantle component, while carbon isotope values fall in the range of -5.8 to -2.0% (vs. PDB), indicating magmatic source signatures as well. Nitrogen dominated samples, 18Dawgo, have helium isotopic ratio 0.7 RA and carbon isotope value -11.4% implying the gas source might be associated with regional crustal components in 18Dawgo. The first-time systematic soil CO2 flux measurements indicate the flux is 22.8 g m-2 day-1 at the western flank of Changbaishan, which is at the same level as the background value in the Tatun Volcano Group (24.6 g m-2 day-1), implying that it may not be as active as TVG. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011AGUFM.A44A..06N','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011AGUFM.A44A..06N">Imposing strong constraints on tropical terrestrial CO2 fluxes using passenger aircraft based measurements</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Niwa, Y.; Machida, T.; Sawa, Y.; Matsueda, H.; Schuck, T. J.; Brenninkmeijer, C. A.; Imasu, R.; Satoh, M. 2011-12-01 Better understanding of the global and regional carbon budget is needed to perform a reliable prediction of future climate with an earth system model. However, the reliability of CO2 source/sink estimation by inverse modeling, which is one of the promising methods to estimate regional carbon budget, is limited because of sparse observational data coverage. Very few observational data are available in tropics. Therefore, especially the reconstruction of tropical terrestrial fluxes has considerable uncertainties. In this study, regional CO2 fluxes for 2006-2008 are estimated by inverse modeling using the Comprehensive Observation Network for Trace gases by Airliner (CONTRAIL) in addition to the surface measurement dataset of GLOBALVIEW-CO2. CONTRAIL is a recently established CO2 measurement network using in-situ measurement instruments on board commercial aircraft. Five CONTRAIL aircraft travel back and forth between Japan and many areas: Europe, North America, Southeast Asia, South Asia, and Australia. The Bayesian synthesis approach is used to estimate monthly fluxes for 42 regions using NICAM-TM simulations with existing CO2 flux datasets and monthly mean observational data. It is demonstrated that the aircraft data have great impact on estimated tropical terrestrial fluxes. By adding the aircraft data to the surface data, the analyzed uncertainty of tropical fluxes has been reduced by 15 % and more than 30 % uncertainty reduction rate is found in Southeast and South Asia. Specifically, for annual net CO2 fluxes, nearly neutral fluxes of Indonesia, which is estimated using the surface dataset alone, turn to positive fluxes, i.e. carbon sources. In Indonesia, a remarkable carbon release during the severe drought period of October-December in 2006 is estimated, which suggests that biosphere respiration or biomass burning was larger than the prior fluxes. Comparison of the optimized atmospheric CO2 with independent aircraft measurements of CARIBIC tends to validate </li> <li> <a target="_blank" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=19950031260&hterms=biodegradation&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D70%26Ntt%3Dbiodegradation','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=19950031260&hterms=biodegradation&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D70%26Ntt%3Dbiodegradation">Flux to the atmosphere of CH4 and CO2 from wetland ponds on the Hudson Bay lowlands (HBLs)</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Hamilton, J. David; Kelly, Carol A.; Rudd, John W. M.; Hesslein, Raymond H.; Roulet, Nigel T. 1994-01-01 Ponds on peatlands of the Hudson Bay lowlands (HBLs) are complex ecosystems in which the fluxes to the atmosphere of CH4 and CO2 were controlled by interacting physical and biological factors. This resulted in strong diel variations of both dissolved gas concentrations and gas fluxes to the atmosphere, necessitating frequent sampling on a 24-hour schedule to enable accurate estimates of daily fluxes. Ponds at three sites on the HBL were constant net sources of CH4 and CO2 to the atmosphere at mean rates of 110-180 mg CH4 m(exp -2)/d and 3700-11,000 mg CO2 m(exp -2)/d. Rates peaked in August and September. For CH4 the pond fluxes were 3-30 times higher than adjacent vegetated surfaces. For CO2 the net pond fluxes were similar in magnitude to the vegetated fluxes but the direction of the flux was opposite, toward atmosphere. Even though ponds cover only 8-12% of the HBL area, they accounted for 30% of its total CH4 flux to the atmosphere. There is some circumstantial evidence that the ponds are being formed by decomposition of the underlying peat and that this decomposition is being stimulated by the activity of N2 fixing cyanobacteria that grow in mats at the peat-water interface. The fact that the gas fluxes from the ponds were so different from the surrounding vegetated surfaces means that any change in the ratio of pond to vegetated area, as may occur in response to climate change, would affect the total HBL fluxes. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.B14B..05W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.B14B..05W">Reconciling Eddy Flux and Tree Ring Estimates of Forest Water-Use Efficiency</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Wehr, R. A.; Belmecheri, S.; Commane, R.; Munger, J. W.; Wofsy, S. C.; Saleska, S. R. 2016-12-01 Eddy flux measurements of ecosystem-atmosphere CO2 and water vapor exchange suggest that rising atmospheric CO2 levels have caused plant endogenous water-use efficiency (WUE) to increase strongly over the last 20 years at sites including the Harvard Forest.1 On the other hand, tree ring 13C isotope measurements at the Harvard Forest seem to suggest that endogenous WUE has not increased.2 Several potential reasons for this discrepancy have been proposed,2,3 including: (1) the definitional difference between the "inherent WUE" calculated from eddy fluxes and the "intrinsic WUE" calculated from tree rings, (2) neglect of factors that affect the isotopic composition of tree ring carbon (e.g. mesophyll conductance, photorespiration, post-photosynthetic fractionation), and (3) temporal mismatch between the instantaneous CO2 flux and seasonally-integrated tree ring carbon. Here we test those proposed explanations by combining tree-ring 13C measurements, 13CO2 eddy flux measurements, and recently developed estimates of transpiration, photosynthesis, and canopy stomatal conductance. We first compute both inherent and intrinsic WUE from eddy flux data and show that their definitional difference does not explain the discrepancy between eddy flux and tree ring estimates of WUE. We further investigate the impact of mesophyll conductance, photorespiration, and mitochondrial respiration on the seasonal isotopic composition of assimilated carbon to elucidate the mismatch between eddy flux- and tree ring-derived water use efficiencies. 1. Keenan, T. F. et al. Increase in forest water-use efficiency as atmospheric carbon dioxide concentrations rise. Nature 499, 324-327 (2013). 2. Belmecheri, S. et al. Tree-ring δ13C tracks flux tower ecosystem productivity estimates in a NE temperate forest. Environ. Res. Lett. 9, 074011 (2014). 3. Seibt, U. et al. Carbon isotopes and water use efficiency: sense and sensitivity. Oecologia 155, 441-454 (2008). </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.B53G0599C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.B53G0599C">Year-round Regional CO2 Fluxes from Boreal and Tundra Ecosystems in Alaska</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Commane, R.; Lindaas, J.; Benmergui, J. S.; Luus, K. A.; Chang, R. Y. W.; Daube, B. C.; Euskirchen, E. S.; Henderson, J.; Karion, A.; Miller, J. B.; Miller, S. M.; Parazoo, N.; Randerson, J. T.; Sweeney, C.; Tans, P. P.; Thoning, K. W.; Veraverbeke, S.; Miller, C. E.; Wofsy, S. C. 2016-12-01 High-latitude ecosystems could release large amounts of carbon dioxide (CO2) to the atmosphere in a warmer climate. We derive temporally and spatially resolved year-round CO2 fluxes in Alaska from a synthesis of airborne and tower CO2 observations in 2012-2014. We find that tundra ecosystems were net sources of atmospheric CO2. We discuss these flux estimates in the context of long-term CO2 measurements at Barrow, AK, to asses the long term trend in carbon fluxes in the Arctic. Many Earth System Models incorrectly simulate net carbon uptake in Alaska presently. Our results imply that annual net emission of CO2 to the atmosphere may have increased markedly in this region of the Arctic in response to warming climate, supporting the view that climate-carbon feedback is strongly positive in the high Arctic. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/biblio/7266116-long-term-direct-measurements-co-sub-water-vapor-exchange-over-deciduous-forest-canopy','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/7266116-long-term-direct-measurements-co-sub-water-vapor-exchange-over-deciduous-forest-canopy">Long-term and direct measurements of CO[sub 2] and water vapor exchange over a deciduous forest canopy</a> <a target="_blank" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Greco, S.; Baldocchi, D.D. 1994-06-01 Long-term monitoring of CO[sub 2] and water vapor exchange is needed to determine components of the carbon and hydrologic cycles and to provide data for parameterizing and testing assessment models. Responding to this need we initiated a continous field measurement campaign in April 1993 in a deciduous forest growing near Oak Ridge, TN. The micrometerological eddy correlation method was used to measure flux densities of CO[sub 2] and water vapor over the canopy. Periodic measurements were made of stomatal resistence and pre-dawn water potential to characterize the photosynthetic capacity of the canopy. Three factors accounted for a disproportionate amount ofmore » seasonal variance in CO[sub 2] flux densities: photon flux densities, leaf area and the occurrence of drought. Positive and increasing magnitudes of carbon gain were observed between April and June as leaves expanded, the canopy closed and daily insolation increased. At midsummer a drought and heat spell were experienced. This period caused CO[sub 2] flux densities to decline. By late summer adequate precipitation and replenishment of soil water resurrected carbon uptake rates until autumnal leaf senescence and leaf fall.« less </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AGUFM.B51H0526M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AGUFM.B51H0526M">Estimating CO2 Fluxes Pre and Post Drought Using Remote Sensing Data in the Sierra Nevada Range</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Mazzi, J. R.; Grigsby, S.; Goulden, M.; Ustin, S. 2015-12-01 The recent California drought presents an opportunity to study CO2 flux changes over time due to insufficient water uptake by plant life using remote sensing data. Three flux towers were used to create linear regressions between AVIRIS derived Net Ecosystem Exchange (NEE = PRI * NDVI * PAR) and tower measured CO2 flux in the San Joaquin Experimental Range. To estimate CO2 from NEE, two linear regressions were used based on time of day and season, with R2 values of 0.85 and 0.87 respectively. Per-pixel CO2 flux was estimated for AVIRIS flights flown in June 2013, 2014, and 2015, as well as September 2011 and October 2014. There was a significant decrease in post drought photosynthetic CO2 uptake over the 6,700 km2 studied, totaling 2,977 grams per minute less (15.9% decrease) from June 2013 to June 2014. Data from the 2015 HyspIRI flights suggest a continuation of this trend for June 2015. Pre-drought conditions over a 33 km2 area show that the photosynthetic CO2 uptake dropped from 74 mg per minute on September 24, 2011, to 35 mg per minute on October 6, 2014 (a 53% decrease). HyspIRI flight lines also include 434 km2 of the Rim Fire, an area that saw a decrease in CO2 uptake of 413 grams per minute (71.7% decrease from June 2013 to June 2014) from the burn alone. It is estimated that the entire Rim Fire (1,041 km2) has caused a total decrease in photosynthetic CO2 uptake totaling 988 grams less per minute from 2013 to 2014, with some recovery evident in 2015. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_10");'>10</a></li> <li><a href="#" onclick='return showDiv("page_11");'>11</a></li> <li class="active">12</li> <li><a href="#" onclick='return showDiv("page_13");'>13</a></li> <li><a href="#" onclick='return showDiv("page_14");'>14</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_13" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_11");'>11</a></li> <li><a href="#" onclick='return showDiv("page_12");'>12</a></li> <li class="active">13</li> <li><a href="#" onclick='return showDiv("page_14");'>14</a></li> <li><a href="#" onclick='return showDiv("page_15");'>15</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="241"> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013BVol...75..757M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013BVol...75..757M">Soil CO2 flux baseline in an urban monogenetic volcanic field: the Auckland Volcanic Field, New Zealand</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Mazot, Agnès; Smid, Elaine R.; Schwendenmann, Luitgard; Delgado-Granados, Hugo; Lindsay, Jan 2013-11-01 The Auckland Volcanic Field (AVF) is a dormant monogenetic basaltic field located in Auckland, New Zealand. Though soil gas CO2 fluxes are routinely used to monitor volcanic regions, there have been no published studies of soil CO2 flux or soil gas CO2 concentrations in the AVF to date or many other monogenetic fields worldwide. We measured soil gas CO2 fluxes and soil gas CO2 concentrations in 2010 and 2012 in varying settings, seasons, and times of day to establish a baseline soil CO2 flux and to determine the major sources of and controlling influences on Auckland's soil CO2 flux. Soil CO2 flux measurements varied from 0 to 203 g m-2 day-1, with an average of 27.1 g m-2 day-1. Higher fluxes were attributed to varying land use properties (e.g., landfill). Using a graphical statistical approach, two populations of CO2 fluxes were identified. Isotope analyses of δ13CO2 confirmed that the source of CO2 in the AVF is biogenic with no volcanic component. These data may be used to assist with eruption forecasting in the event of precursory activity in the AVF, and highlight the importance of knowing land use history when assessing soil gas CO2 fluxes in urban environments. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/18186331','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/18186331">Variability of the gaseous elemental mercury sea-air flux of the Baltic Sea.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Kuss, Joachim; Schneider, Bernd 2007-12-01 The importance of the sea as a sink for atmospheric mercury has been established quantitatively through models based on wet and dry deposition data, but little is known about the release of mercury from sea areas. The concentration of elemental mercury (Hg0) in sea surface water and in the marine atmosphere of the Baltic Sea was measured at high spatial resolution in February, April, July, and November 2006. Wind-speed records and the gas-exchange transfer velocity were then used to calculate Hg0 sea-air fluxes on the basis of Hg0 sea-air concentration differences. Our results show that the spatial resolution of the surface water Hg0 data can be significantly improved by continuous measurements of Hg0 in air equilibrated with water instead of quantitative extraction of Hg0 from seawater samples. A spatial and highly seasonal variability of the Hg0 sea-air flux was thus determined. In winter, the flux was low and changed in direction. In summer, a strong emission flux of up to 150 ng m(-2) day(-1) in the central Baltic Sea was recorded. The total emission of Hg0 from the studied area (235000 km2) was 4300 +/- 1600 kg in 2006 and exceeded deposition estimates. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.B11K..03K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.B11K..03K">Assessing the effect of marginal water use efficiency on water use of loblolly pine and sweetgum in ambient and elevated CO2 conditions</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Kim, D.; Medvigy, D.; Xu, X.; Oren, R.; Ward, E. J. 2017-12-01 Stomata are the common pathways through which diffusion of CO2 and water vapor take place in a plant. Therefore, the responses of stomatal conductance to environmental conditions are important to quantify carbon assimilation and water use of plants. In stomatal optimality theory, plants may adjust the stomatal conductance to maximize carbon assimilation for a given water availability. The carbon cost for unit water loss, marginal water use efficiency (λ), depends on changes in atmospheric CO2 concentration and pre-dawn leaf water potential. The relationship can be described by λ with no water stress (λ0) and the sensitivity of λ to pre-dawn leaf water potential (β0), which may vary by plant functional type. Assessment of sensitivity of tree and canopy water use to those parameters and the estimation of the parameters for individual plant functional type or species are needed. We modeled tree water use of loblolly pine (Pinus taeda) and sweetgum (Liquidambar styraciflua) in ambient and elevated CO2 (+200 µmol mol-1) at the Duke Forest free-air CO2 enrichment (FACE) site with Ecosystem Demography model 2 (ED2), a demographic terrestrial biosphere model that scales up individual-level competition for light, water and nutrients to the ecosystem-level. Simulated sap flux density for different tree size classes and species was compared to observations. The sensitivity analysis with respect to the model's hydraulic parameters was performed. The initial results showed that the impacts of λ on tree water use were greater than other hydraulic traits in the model, such as vertical hydraulic conductivity and leaf and stem capacitance. With 10% increase in λ, modeled water flow from root to leaf decreased by 2.5 and 1.6% for P. taeda and by 7.9 and 5.1% for L. styraciflua in ambient and elevated CO2 conditions, respectively. Values of hydraulic traits (λ0 and β0) for P. taeda and L. styraciflua in ambient an elevated CO2 conditions were also suggested. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://hdl.handle.net/2060/19910021296','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/19910021296">Analysis of field measurements of carbon dioxide and water vapor fluxes</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Verma, Shashi B. 1991-01-01 Analysis of the field measurements of carbon dioxide and water vapor fluxes is discussed. These data were examined in conjunction with reflectance obtained from helicopter mounted Modular Multiband Radiometer. These measurements are representative of the canopy scale (10 to 100 m)(exp 2) and provide a good basis for investigating the hypotheses/relationship potentially useful in remote sensing applications. All the micrometeorological data collected during FIFE-89 were processed and fluxes of CO2, water vapor, and sensible heat were calculated. Soil CO2 fluxes were also estimated. Employing these soil CO2 flux values, in conjunction with micrometeorological measurements, canopy photosynthesis is being estimated. A biochemical model of leaf photosynthesis was adapted to the prairie vegetation. The modeled leaf photosynthesis rates were scaled up to the canopy level. This model and a multiplicative stomatal conductance model are also used to calculate canopy conductance. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.fs.usda.gov/treesearch/pubs/53877','TREESEARCH'); return false;" href="https://www.fs.usda.gov/treesearch/pubs/53877">Plant water relations and the effects of elevated CO2: a review and suggestions for future research</a> <a target="_blank" href="http://www.fs.usda.gov/treesearch/">Treesearch</a> Melvin T. Tyree; John D. Alexander 1993-01-01 Increased ambient carbon dioxide (CO2) has been found to ameliorate water stress in the majority of species studied. The results of many studies indicate that lower evaporative flux density is associated with high CO2-induced stomatal closure. As a result of decreases in evaporative flux density and increases in net... </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFMGC33F..07P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFMGC33F..07P">Competing Air Quality and Water Conservation Co-benefits from Power Sector Decarbonization</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Peng, W.; Wagner, F.; Mauzerall, D. L.; Ramana, M. V.; Zhai, H.; Small, M.; Zhang, X.; Dalin, C. 2016-12-01 Decarbonizing the power sector can reduce fossil-based generation and associated air pollution and water use. However, power sector configurations that prioritize air quality benefits can be different from those that maximize water conservation benefits. Despite extensive work to optimize the generation mix under an air pollution or water constraint, little research has examined electricity transmission networks and the choice of which fossil fuel units to displace in order to achieve both environmental objectives simultaneously. When air pollution and water stress occur in different regions, the optimal transmission and displacement decisions still depend on priorities placed on air quality and water conservation benefits even if low-carbon generation planning is fixed. Here we use China as a test case, and develop a new optimization framework to study transmission and displacement decisions and the resulting air quality and water use impacts for six power sector decarbonization scenarios in 2030 ( 50% of national generation is low carbon). We fix low-carbon generation in each scenario (e.g. type, location, quantity) and vary technology choices and deployment patterns across scenarios. The objective is to minimize the total physical costs (transmission costs and coal power generation costs) and the estimated environmental costs. Environmental costs are estimated by multiplying effective air pollutant emissions (EMeff, emissions weighted by population density) and effective water use (Weff, water use weighted by a local water stress index) by their unit economic values, Vem and Vw. We are hence able to examine the effect of varying policy priorities by imposing different combinations of Vem and Vw. In all six scenarios, we find that increasing the priority on air quality co-benefits (higher Vem) reduces air pollution impacts (lower EMeff) at the expense of lower water conservation (higher Weff); and vice versa. Such results can largely be explained by differences </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017ESD.....8.1093P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017ESD.....8.1093P">The potential of using remote sensing data to estimate air-sea CO2 exchange in the Baltic Sea</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Parard, Gaëlle; Rutgersson, Anna; Parampil, Sindu Raj; Alexandre Charantonis, Anastase 2017-12-01 In this article, we present the first climatological map of air-sea CO2 flux over the Baltic Sea based on remote sensing data: estimates of pCO2 derived from satellite imaging using self-organizing map classifications along with class-specific linear regressions (SOMLO methodology) and remotely sensed wind estimates. The estimates have a spatial resolution of 4 km both in latitude and longitude and a monthly temporal resolution from 1998 to 2011. The CO2 fluxes are estimated using two types of wind products, i.e. reanalysis winds and satellite wind products, the higher-resolution wind product generally leading to higher-amplitude flux estimations. Furthermore, the CO2 fluxes were also estimated using two methods: the method of Wanninkhof et al. (2013) and the method of Rutgersson and Smedman (2009). The seasonal variation in fluxes reflects the seasonal variation in pCO2 unvaryingly over the whole Baltic Sea, with high winter CO2 emissions and high pCO2 uptakes. All basins act as a source for the atmosphere, with a higher degree of emission in the southern regions (mean source of 1.6 mmol m-2 d-1 for the South Basin and 0.9 for the Central Basin) than in the northern regions (mean source of 0.1 mmol m-2 d-1) and the coastal areas act as a larger sink (annual uptake of -4.2 mmol m-2 d-1) than does the open sea (-4 mmol m-2 d-1). In its entirety, the Baltic Sea acts as a small source of 1.2 mmol m-2 d-1 on average and this annual uptake has increased from 1998 to 2012. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.A32F..08C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.A32F..08C">Constraining the Stratosphere-Troposphere Exchange of Radiocarbon using AirCore 14CO2 Measurements</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Chen, H. 2016-12-01 Radiocarbon (14C) plays an important role in the carbon cycle studies to understand both natural and anthropogenic carbon fluxes, but also in atmospheric chemistry to constrain hydroxyl radical (OH) concentrations in the atmosphere. Apart from the enormous 14C emissions from nuclear bomb testing in the 1950s and 1960s, radiocarbon is primarily produced in the upper atmosphere due to reactions of nitrogen nuclei with thermal neutrons that are induced by cosmic rays. 14C is quickly oxidized to 14CO, which is then further oxidized to 14CO2 by OH. To this end, better understanding the radiocarbon source is very useful to advance the use of radiocarbon for these applications. However, upper atmospheric 14C observations have been very sparse to constrain the magnitude and the location of the 14C production as well as the transport of radiocarbon from the stratosphere to the troposphere. Recently we have successfully made stratospheric 14CO2 measurements using AirCore samples from Sodankylä, Northern Finland, along with regular AirCore profiles of CO2, CH4, and CO since 2013. In this study, we calculate the stratosphere-troposphere exchange of 14C using the correlation between 14CO2 and N2O, and the estimated N2O loss rate. Besides this, we assess the impact of the mean age of air on 14CO2 profiles. Furthermore, we will evaluate the influence of different cosmogenic 14C production scenarios and the uncertainties in the OH field on the seasonal cycles of radiocarbon and on the stratosphere-troposphere exchange. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..19.7685S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..19.7685S">Concurrent CO2 and COS fluxes across major biomes in Europe</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Spielmann, Felix M.; Kitz, Florian; Hammerle, Albin; Gerdel, Katharina; Ibrom, Andreas; Kolle, Olaf; Migliavacca, Mirco; Moreno, Gerardo; Noe, Steffen M.; Wohlfahrt, Georg 2017-04-01 The trace gas carbonyl sulfide (COS) has been proposed as a tracer for canopy gross primary production (GPP), canopy transpiration and stomatal conductance of plant canopies in the last few years. COS enters the plant leaf through the stomata and diffuses through the intercellular space, the cell wall, the plasma membrane and the cytosol like carbon dioxide (CO2). It is then catalyzed by the enzyme carbonic anhydrase in a one-way reaction to hydrogen sulfide and CO2. This one-way flux into the leaf makes COS a promising tracer for the GPP. However, this approach assumes that the ratio of the deposition velocities between COS and CO2 is constant, which must be determined in field experiments covering a wide variety of ecosystems. The overarching objective of this study was to quantify the relationship between the ecosystem-scale exchange of COS and CO2 and thus, to test for the potential of COS to be used as a universal tracer for the plant canopy CO2 exchange. Between spring 2015 and summer 2016 we set up our quantum cascade laser at different field sites across Europe. These sites included a managed temperate mountain grassland (AUT), a savanna (ESP), a temperate beech forest (DEN) and a hemiboreal forest (EST). On each of these sites, we conducted ecosystem scale eddy covariance and soil chamber measurements. Since the soil COS flux contribution, especially in grass dominated ecosystems, could not be neglected, we had to derive the actual canopy COS fluxes for all the measurement sites. Using these fluxes we compared the ecosystem relative uptake (ERU) of the sites and searched for factors affecting its variability. We then used the influential factors to scale the ERU to be comparable under different field sites and conditions. Furthermore we also calculated the GPP using conventional CO2 flux partitioning and compared the results with the approach of using the leaf relative uptake. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/20103140','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/20103140">CO2 volume fluxes outgassing from champagne glasses: the impact of champagne ageing.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Liger-Belair, Gérard; Villaume, Sandra; Cilindre, Clara; Jeandet, Philippe 2010-02-15 It was demonstrated that CO(2) volume fluxes outgassing from a flute poured with a young champagne (elaborated in 2007) are much higher than those outgassing from the same flute poured with an older champagne (elaborated in the early 1990s). The difference in dissolved-CO(2) concentrations between the two types of champagne samples was found to be a crucial parameter responsible for differences in CO(2) volume fluxes outgassing from one champagne to another. Nevertheless, it was shown that, for a given identical dissolved-CO(2) concentration in both champagne types, the CO(2) volume flux outgassing from the flute poured with the old champagne is, in average, significantly lower than that outgassing from the flute poured with the young one. Therefore, CO(2) seems to "escape" more easily from the young champagne than from the older one. The diffusion coefficient of CO(2) in both champagne types was pointed as a key parameter to thoroughly determine in the future, in order to unravel our experimental observation. Copyright 2009 Elsevier B.V. All rights reserved. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.A31O..02S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.A31O..02S">Interpreting OCO-2 Constrained CO2 Surface Flux Estimates Through the Lens of Atmospheric Transport Uncertainty.</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Schuh, A. E.; Jacobson, A. R.; Basu, S.; Weir, B.; Baker, D. F.; Bowman, K. W.; Chevallier, F.; Crowell, S.; Deng, F.; Denning, S.; Feng, L.; Liu, J. 2017-12-01 The orbiting carbon observatory (OCO-2) was launched in July 2014 and has collected three years of column mean CO2 (XCO2) data. The OCO-2 model inter-comparison project (MIP) was formed to provide a means of analysis of results from many different atmospheric inversion modeling systems. Certain facets of the inversion systems, such as observations and fossil fuel CO2 fluxes were standardized to remove first order sources of difference between the systems. Nevertheless, large variations amongst the flux results from the systems still exist. In this presentation, we explore one dimension of this uncertainty, the impact of different atmospheric transport fields, i.e. wind speeds and directions. Early results illustrate a large systematic difference between two classes of atmospheric transport, arising from winds in the parent GEOS-DAS (NASA-GMAO) and ERA-Interim (ECMWF) data assimilation models. We explore these differences and their effect on inversion-based estimates of surface CO2 flux by using a combination of simplified inversion techniques as well as the full OCO-2 MIP suite of CO2 flux estimates. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/20527160','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/20527160">[Characteristics of CO2 flux before and in the heating period at urban complex underlying surface area].</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Jia, Qing-yu; Zhou, Guang-sheng; Wang, Yu; Liu, Xiao-mei 2010-04-01 Urban areas were significant contributors to global carbon dioxide emissions. The eddy covariance (EC) was used to measure carbon dioxide (CO2) concentration and flux data at urban area in Shenyang. This research analyzed the characteristics of atmospheric CO2 concentration and flux in October 2008 to November 2008 period before and in the heating period. The results showed that the daily variation of CO2 concentration was two-peak curve. The first peak time appeared as same as sunrise time, while the second peak time impacted by vehicles and heating. The result of CO2 flux showed that urban atmospheric CO2 was net emissions, vegetation photosynthesis absorbed CO2 of traffic, the CO2 flux peak appeared at 17:15-18:15 in the heating period, CO2 emission increased 29.37 g x (m2 x d)(-1) in the heating period than that before the heating period; there was corresponding relationship between CO2 flux and the time when temperature peak and sensible heating flux (Hc) turn positive. The results also indicated that atmospheric CO2 concentration and its flux were affected seriously by both wind direction and carbon sources. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018E%26PSL.489..123S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018E%26PSL.489..123S">Infiltration-driven metamorphism, New England, USA: Regional CO2 fluxes and implications for Devonian climate and extinctions</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Stewart, E. M.; Ague, Jay J. 2018-05-01 We undertake thermodynamic pseudosection modeling of metacarbonate rocks in the Wepawaug Schist, Connecticut, USA, and examine the implications for CO2 outgassing from collisional orogenic belts. Two broad types of pseudosections are calculated: (1) a fully closed-system model with no fluid infiltration and (2) a fluid-buffered model including an H2O-CO2 fluid of a fixed composition. This fluid-buffered model is used to approximate a system open to infiltration by a water-bearing fluid. In all cases the fully closed-system model fails to reproduce the observed major mineral zones, mineral compositions, reaction temperatures, and fluid compositions. The fluid-infiltrated models, on the other hand, successfully reproduce these observations when the XCO2 of the fluid is in the range ∼0.05 to ∼0.15. Fluid-infiltrated models predict significant progressive CO2 loss, peaking at ∼50% decarbonation at amphibolite facies. The closed-system models dramatically underestimate the degree of decarbonation, predicting only ∼15% CO2 loss at peak conditions, and, remarkably, <1% CO2 loss below ∼600 °C. We propagate the results of fluid-infiltrated pseudosections to determine an areal CO2 flux for the Wepawaug Schist. This yields ∼1012 mol CO2 km-2 Myr-1, consistent with multiple independent estimates of the metamorphic CO2 flux, and comparable in magnitude to fluxes from mid-ocean ridges and volcanic arcs. Extrapolating to the area of the Acadian orogenic belt, we suggest that metamorphic CO2 degassing is a plausible driver of global warming, sea level rise, and, perhaps, extinction in the mid- to late-Devonian. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015EGUGA..17.2333B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015EGUGA..17.2333B">On the importance of high-frequency air-temperature fluctuations for spectroscopic corrections of open-path carbon dioxide flux measurements</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Bogoev, Ivan; Helbig, Manuel; Sonnentag, Oliver 2015-04-01 A growing number of studies report systematic differences in CO2 flux estimates obtained with the two main types of gas analyzers: compared to eddy-covariance systems based on closed-path (CP) gas analyzers, systems with open-path (OP) gas analyzers systematically overestimate CO2 uptake during daytime periods with high positive sensible heat fluxes, while patterns for differences in nighttime CO2 exchange are less obvious. These biases have been shown to correlate with the sign and the magnitude of the sensible heat flux and to introduce large uncertainties when calculating annual CO2 budgets. In general, CP and OP gas analyzers commonly used to measure the CO2 density in the atmosphere operate on the principle of infrared light absorption approximated by Beer-Lambert's law. Non-dispersive interference-based optical filter elements are used to select spectral bands with strong attenuation of light transmission, characteristic to the gas of interest. The intensity of the light passing through the optical sensing path depends primarily on the amount of absorber gas in the measurement volume. Besides the density of the gas, barometric pressure and air temperature are additional factors affecting the strength and the half-width of the absorption lines. These so-called spectroscopic effects are accounted for by measuring barometric pressure and air temperature in the sensing path and scaling the light-intensity measurements before applying the calibration equation. This approach works well for CP gas analyzers with an intake tube that acts as a low-pass filter on fast air-temperature fluctuations. Low-frequency response temperature sensors in the measurement cell are therefore sufficient to account for spectroscopic temperature effects. In contrast, OP gas analyzers are exposed to high-frequency air-temperature fluctuations associated with the atmospheric surface-layer turbulent heat exchange. If not corrected adequately, these fast air-temperature variations can cause </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012JGRD..11711303N','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012JGRD..11711303N">Imposing strong constraints on tropical terrestrial CO2 fluxes using passenger aircraft based measurements</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Niwa, Yosuke; Machida, Toshinobu; Sawa, Yousuke; Matsueda, Hidekazu; Schuck, Tanja J.; Brenninkmeijer, Carl A. M.; Imasu, Ryoichi; Satoh, Masaki 2012-06-01 Because very few measurements of atmospheric carbon dioxide (CO2) are available in the tropics, estimates of surface CO2 fluxes in tropical regions are beset with considerable uncertainties. To improve estimates of tropical terrestrial fluxes, atmospheric CO2 inversion was performed using passenger aircraft based measurements of the Comprehensive Observation Network for Trace gases by Airliner (CONTRAIL) project in addition to the surface measurement data set of GLOBALVIEW-CO2. Regional monthly fluxes at the earth's surface were estimated using the Bayesian synthesis approach focusing on the period 2006-2008 using the Nonhydrostatic Icosahedral Atmospheric Model-based Transport Model (NICAM-TM). By adding the aircraft to the surface data, the posterior flux errors were greatly reduced; specifically, error reductions of up to 64% were found for tropical Asia regions. This strong impact is closely related to efficient vertical transport in the tropics. The optimized surface fluxes using the CONTRAIL data were evaluated by comparing the simulated atmospheric CO2 distributions with independent aircraft measurements of the Civil Aircraft for the Regular Investigation of the atmosphere Based on an Instrument Container (CARIBIC) project. The inversion with the CONTRAIL data yields the global carbon sequestration rates of 2.22 ± 0.28 Pg C yr-1 for the terrestrial biosphere and 2.24 ± 0.27 Pg C yr-1 for the oceans (the both are adjusted by riverine input of CO2). For the first time the CONTRAIL CO2 measurements were used in an inversion system to identify the areas of greatest impact in terms of reducing flux uncertainties. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016EGUGA..1815385G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016EGUGA..1815385G">Diurnal variations in CO2 flux from peatland floodplains: Implications for models of ecosystem respiration</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Goulsbra, Claire; Rickards, Nathan; Brown, Sarah; Evans, Martin; Boult, Stephen; Alderson, Danielle 2016-04-01 Peatlands are important terrestrial carbon stores, and within these environments, floodplains have been identified as hotspots of carbon processing, potentially releasing substantial amounts of CO2 into the atmosphere. Previous monitoring campaigns have shown that such CO2 release from ecosystem respiration is linked not only to soil temperature and water table depth, but also to CO2 sequestration via primary productivity, thought to be because the root exudates produced during photosynthesis stimulate microbial activity. This suggests that extrapolation models that are parameterised on data collected during day light hours, when vegetation is photosynthesising, may overestimate ecosystem respiration rates at night, which has important implications for estimates of annual CO2 flux and carbon budgeting. To investigate this hypothesis, monitoring data is collected on the CO2 flux from UK peatland floodplains over the full diurnal cycle. This is done via ex-situ manual data collection from mesocosms using an infra-red gas analyser, and the in-situ automated collection of CO2 concentration data from boreholes within the peat using GasClams®. Preliminary data collected during the summer months suggest that night time respiration is suppressed compared to that during the day, and that the significant predictors of respiration are different when examining day and night time data. This highlights the importance of incorporating diurnal variations into models of ecosystem respiration. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/22823525','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/22823525">Concurrent separation of CO2 and H2O from air by a temperature-vacuum swing adsorption/desorption cycle.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Wurzbacher, Jan Andre; Gebald, Christoph; Piatkowski, Nicolas; Steinfeld, Aldo 2012-08-21 A temperature-vacuum swing (TVS) cyclic process is applied to an amine-functionalized nanofibrilated cellulose sorbent to concurrently extract CO(2) and water vapor from ambient air. The promoting effect of the relative humidity on the CO(2) capture capacity and on the amount of coadsorbed water is quantified. The measured specific CO(2) capacities range from 0.32 to 0.65 mmol/g, and the corresponding specific H(2)O capacities range from 0.87 to 4.76 mmol/g for adsorption temperatures varying between 10 and 30 °C and relative humidities varying between 20 and 80%. Desorption of CO(2) is achieved at 95 °C and 50 mbar(abs) without dilution by a purge gas, yielding a purity exceeding 94.4%. Sorbent stability and a closed mass balance for both H(2)O and CO(2) are demonstrated for ten consecutive adsorption-desorption cycles. The specific energy requirements of the TVS process based on the measured H(2)O and CO(2) capacities are estimated to be 12.5 kJ/mol(CO2) of mechanical (pumping) work and between 493 and 640 kJ/mol(CO2) of heat at below 100 °C, depending on the air relative humidity. For a targeted CO(2) capacity of 2 mmol/g, the heat requirement would be reduced to between 272 and 530 kJ/mol(CO2), depending strongly on the amount of coadsorbed water. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1355135-how-can-mountaintop-co2-observations-used-constrain-regional-carbon-fluxes','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1355135-how-can-mountaintop-co2-observations-used-constrain-regional-carbon-fluxes">How can mountaintop CO 2 observations be used to constrain regional carbon fluxes?</a> <a target="_blank" href="http://www.osti.gov/pages">DOE PAGES</a> Lin, John C.; Mallia, Derek V.; Wu, Dien; ... 2017-05-03 Despite the need for researchers to understand terrestrial biospheric carbon fluxes to account for carbon cycle feedbacks and predict future CO 2 concentrations, knowledge of these fluxes at the regional scale remains poor. This is particularly true in mountainous areas, where complex meteorology and lack of observations lead to large uncertainties in carbon fluxes. Yet mountainous regions are often where significant forest cover and biomass are found – i.e., areas that have the potential to serve as carbon sinks. As CO 2 observations are carried out in mountainous areas, it is imperative that they are properly interpreted to yield informationmore » about carbon fluxes. In this paper, we present CO 2 observations at three sites in the mountains of the western US, along with atmospheric simulations that attempt to extract information about biospheric carbon fluxes from the CO 2 observations, with emphasis on the observed and simulated diurnal cycles of CO 2. We show that atmospheric models can systematically simulate the wrong diurnal cycle and significantly misinterpret the CO 2 observations, due to erroneous atmospheric flows as a result of terrain that is misrepresented in the model. This problem depends on the selected vertical level in the model and is exacerbated as the spatial resolution is degraded, and our results indicate that a fine grid spacing of ~4 km or less may be needed to simulate a realistic diurnal cycle of CO 2 for sites on top of the steep mountains examined here in the American Rockies. In conclusion, in the absence of higher resolution models, we recommend coarse-scale models to focus on assimilating afternoon CO 2 observations on mountaintop sites over the continent to avoid misrepresentations of nocturnal transport and influence.« less </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017ACP....17.5561L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017ACP....17.5561L">How can mountaintop CO2 observations be used to constrain regional carbon fluxes?</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Lin, John C.; Mallia, Derek V.; Wu, Dien; Stephens, Britton B. 2017-05-01 Despite the need for researchers to understand terrestrial biospheric carbon fluxes to account for carbon cycle feedbacks and predict future CO2 concentrations, knowledge of these fluxes at the regional scale remains poor. This is particularly true in mountainous areas, where complex meteorology and lack of observations lead to large uncertainties in carbon fluxes. Yet mountainous regions are often where significant forest cover and biomass are found - i.e., areas that have the potential to serve as carbon sinks. As CO2 observations are carried out in mountainous areas, it is imperative that they are properly interpreted to yield information about carbon fluxes. In this paper, we present CO2 observations at three sites in the mountains of the western US, along with atmospheric simulations that attempt to extract information about biospheric carbon fluxes from the CO2 observations, with emphasis on the observed and simulated diurnal cycles of CO2. We show that atmospheric models can systematically simulate the wrong diurnal cycle and significantly misinterpret the CO2 observations, due to erroneous atmospheric flows as a result of terrain that is misrepresented in the model. This problem depends on the selected vertical level in the model and is exacerbated as the spatial resolution is degraded, and our results indicate that a fine grid spacing of ˜ 4 km or less may be needed to simulate a realistic diurnal cycle of CO2 for sites on top of the steep mountains examined here in the American Rockies. In the absence of higher resolution models, we recommend coarse-scale models to focus on assimilating afternoon CO2 observations on mountaintop sites over the continent to avoid misrepresentations of nocturnal transport and influence. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.fs.usda.gov/treesearch/pubs/5413','TREESEARCH'); return false;" href="https://www.fs.usda.gov/treesearch/pubs/5413">Forest Floor CO2 Flux From Two Contrasting Ecosystems in the Southern Appalachians</a> <a target="_blank" href="http://www.fs.usda.gov/treesearch/">Treesearch</a> James M. Vose; Barton D. Clinton; Verl Emrick 1995-01-01 We measured forest floor CO2 flux in two contrasting ecosystems (white pine plantation and northern hardwood ecosystems at low and high elevations, respectively) in May and September 1993 to quantify differences and determine factors regulating CO2 fluxes. An automated IRGA based, flow through system was used with chambers... </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_11");'>11</a></li> <li><a href="#" onclick='return showDiv("page_12");'>12</a></li> <li class="active">13</li> <li><a href="#" onclick='return showDiv("page_14");'>14</a></li> <li><a href="#" onclick='return showDiv("page_15");'>15</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_14" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_12");'>12</a></li> <li><a href="#" onclick='return showDiv("page_13");'>13</a></li> <li class="active">14</li> <li><a href="#" onclick='return showDiv("page_15");'>15</a></li> <li><a href="#" onclick='return showDiv("page_16");'>16</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="261"> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013EGUGA..15..856N','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013EGUGA..15..856N">Human Effects and Soil Surface CO2 fluxes in Tropical Urban Green Areas, Singapore</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Ng, Bernard; Gandois, Laure; Kai, Fuu Ming; Chua, Amy; Cobb, Alex; Harvey, Charles; Hutyra, Lucy 2013-04-01 Urban green spaces are appreciated for their amenity value, with increasing interest in the ecosystem services they could provide (e.g. climate amelioration and increasingly as possible sites for carbon sequestration). In Singapore, turfgrass occupies approximately 20% of the total land area and is readily found on both planned and residual spaces. This project aims at understanding carbon fluxes in tropical urban green areas, including controls of soil environmental factors and the effect of urban management techniques. Given the large pool of potentially labile carbon, management regimes are recognised to have an influence on soil environmental factors (temperature and moisture), this would affect soil respiration and feedbacks to the greenhouse effect. A modified closed dynamic chamber method was employed to measure total soil respiration fluxes. In addition to soil respiration rates, environmental factors such as soil moisture and temperature, and ambient air temperature were monitored for the site in an attempt to evaluate their control on the observed fluxes. Measurements of soil-atmosphere CO2 exchanges are reported for four experimental plots within the Singtel-Kranji Radio Transmission Station (103o43'49E, 1o25'53N), an area dominated by Axonopus compressus. Different treatments such as the removal of turf, and application of clippings were effected as a means to determine the fluxes from the various components (respiration of soil and turf, and decomposition of clippings), and to explore the effects of human intervention on observed effluxes. The soil surface CO2 fluxes observed during the daylight hours ranges from 2.835 + 0.772 umol m-2 s-1 for the bare plot as compared to 6.654 + 1.134 umol m-2 s-1 for the turfed plot; this could be attributed to both autotrophic and heterotrophic respiration. Strong controls of both soil temperature and soil moisture are observed on measured soil fluxes. On the base soils, fluxes were positively correlated to soil </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2010AGUFM.A51C0127L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2010AGUFM.A51C0127L">Modeling Global Atmospheric CO2 Fluxes and Transport Using NASA MERRA Reanalysis Data</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Liu, Y.; Kawa, S. R.; Collatz, G. J. 2010-12-01 We present our first results of CO2 surface biosphere fluxes and global atmospheric CO2 transport using NASA’s new MERRA reanalysis data. MERRA is the Modern Era Retrospective-Analysis For Research And Applications based on the Goddard Global Modeling and Assimilation Office GEOS-5 data assimilation system. After some application testing and analysis, we have generated biospheric CO2 fluxes at 3-hourly temporal resolution from an updated version of the CASA carbon cycle model using the 1x1.25-degree reanalysis data. The experiment covers a period of 9 years from 2000 -2008. The affects of US midwest crop (largely corn and soy) carbon uptake and removal by harvest are explicitly included in this version of CASA. Across the agricultural regions of the Midwest US, USDA crop yield data are used to scale vegetation fluxes producing a strong sink in the growing season and a comparatively weaker source from respiration after harvest. Comparisons of the new fluxes to previous ones generated using GEOS-4 data are provided. The Parameterized Chemistry/Transport Model (PCTM) is then used with the analyzed meteorology in offline CO2 transport. In the simulation of CO2 transport, we have a higher vertical resolution from MERRA (the lowest 56 of 72 levels are used in our simulation). A preliminary analysis of the CO2 simulation results is carried out, including diurnal, seasonal and latitudinal variability. We make comparisons of our simulation to continuous CO2 analyzer sites, especially those in agricultural regions. The results show that the model captures reasonably well the observed synoptic variability due to transport changes and biospheric fluxes. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016ACP....16.5665B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016ACP....16.5665B">Separation of biospheric and fossil fuel fluxes of CO2 by atmospheric inversion of CO2 and 14CO2 measurements: Observation System Simulations</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Basu, Sourish; Bharat Miller, John; Lehman, Scott 2016-05-01 National annual total CO2 emissions from combustion of fossil fuels are likely known to within 5-10 % for most developed countries. However, uncertainties are inevitably larger (by unknown amounts) for emission estimates at regional and monthly scales, or for developing countries. Given recent international efforts to establish emission reduction targets, independent determination and verification of regional and national scale fossil fuel CO2 emissions are likely to become increasingly important. Here, we take advantage of the fact that precise measurements of 14C in CO2 provide a largely unbiased tracer for recently added fossil-fuel-derived CO2 in the atmosphere and present an atmospheric inversion technique to jointly assimilate observations of CO2 and 14CO2 in order to simultaneously estimate fossil fuel emissions and biospheric exchange fluxes of CO2. Using this method in a set of Observation System Simulation Experiments (OSSEs), we show that given the coverage of 14CO2 measurements available in 2010 (969 over North America, 1063 globally), we can recover the US national total fossil fuel emission to better than 1 % for the year and to within 5 % for most months. Increasing the number of 14CO2 observations to ˜ 5000 per year over North America, as recently recommended by the National Academy of Science (NAS) (Pacala et al., 2010), we recover monthly emissions to within 5 % for all months for the US as a whole and also for smaller, highly emissive regions over which the specified data coverage is relatively dense, such as for the New England states or the NY-NJ-PA tri-state area. This result suggests that, given continued improvement in state-of-the art transport models, a measurement program similar in scale to that recommended by the NAS can provide for independent verification of bottom-up inventories of fossil fuel CO2 at the regional and national scale. In addition, we show that the dual tracer inversion framework can detect and minimize biases in </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2005GeoRL..32.8606C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2005GeoRL..32.8606C">Control of air-sea CO2 disequilibria in the subtropical NE Atlantic by planktonic metabolism under the ocean skin</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Calleja, María Ll.; Duarte, Carlos M.; Navarro, Nuria; Agustí, Susana 2005-04-01 The air-sea CO2 gradient at the subtropical NE Atlantic was strongly dependent on the metabolism of the planktonic community within the top cms, but independent of that of the communities deeper in the water column. Gross primary production (GPP) and community respiration (R) of the planktonic community within the top cms exceeded those of the communities deeper in the water column by >10-fold and >7 fold, respectively. Net autotrophic metabolism (GPP > R) at the top cms of the water column in some stations drove CO2 uptake by creating a CO2 deficit at the ocean surface, while net heterotrophic metabolism (GPP < R) at the top cms of the water column in other stations resulted in strong CO2 supersaturation, driving CO2 emissions. These results suggest a strong control of the air-sea pCO2 anomaly by intense biological processes. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.B33E2118G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.B33E2118G">Understanding the Temporal Variation of CO2 and CH4 Fluxes in a Subtropical Seasonal Wetland</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Gomez-Casanovas, N.; DeLucia, N.; DeLucia, E. H.; Boughton, E.; Bernacchi, C. 2017-12-01 The magnitude of the net greenhouse gas (GHG) sink strength of wetlands and mechanisms driving C fluxes remain uncertain, particularly for subtropical and tropical wetlands that are responsible for the majority of wetland CH4 emissions globally. We determined the exchange of CO2 and CH4 fluxes between a subtropical wetland and the atmosphere, and investigated how changes in water table (WT), soil temperature (ST), and Gross Primary Productivity (GPP) alter CH4 fluxes. Measurements were made using the eddy covariance technique from June, 2013 to December, 2015. As GPP was greater than ecosystem respiration, wetland was consistently a net sink of CO2 from the atmosphere (-480 gC m-2 in 2013, -275 gC m-2 in 2014 and -258 gC m-2 in 2015). Though variable among years, wetland was a net source of CH4 to the atmosphere (24.5 gC m-2 in 2013, 26.1 gC m-2 in 2014, 32.7 gC m-2 in 2015). WT and ST were strong drivers of net CH4 fluxes. Fluxes of CH4 exponentially increased with WT near the soil surface, and they were maximal and sustained after 3 days or more of preceding flooding suggesting that flooding duration and intensity drives CH4 emissions in this system. GPP also exerted a strong control on these fluxes, particularly when water was near the soil surface. The system emitted an average of 2 g more C-CH4 m-2 during the wet seasons of 2013 and 2015 than the wet season of 2014 due to higher WT, and increases in flooding days and cumulative GPP for days with water at near-surface (GPPWT). Although WT was higher during the dry season of 2015 than the wet season of 2014, CH4 fluxes were similar likely because of increased ST and GPPWT in the wet season of 2014. The contribution of CH4 fluxes during the dry season to annual fluxes was 41% in 2014 and 48% in 2015. Wetland was a strong sink of C, and it was a net sink of GHGs in 2014 and a net source in 2015 mainly attributable to increases in net CH4 emissions. Climate models predict that subtropical and tropical regions will </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013ACPD...13.7267V','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013ACPD...13.7267V">The role of vegetation in the CO2 flux from a tropical urban neighbourhood</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Velasco, E.; Roth, M.; Tan, S. H.; Quak, M.; Nabarro, S. D. A.; Norford, L. 2013-03-01 Urban surfaces are usually net sources of CO2. Vegetation can potentially have an important role in reducing the CO2 emitted by anthropogenic activities in cities, particularly when vegetation is extensive and/or evergreen. Negative daytime CO2 fluxes, for example have been observed during the growing season at suburban sites characterized by abundant vegetation and low population density. A direct and accurate estimation of carbon uptake by urban vegetation is difficult due to the particular characteristics of the urban ecosystem and high variability in tree distribution and species. Here, we investigate the role of urban vegetation in the CO2 flux from a residential neighbourhood in Singapore using two different approaches. CO2 fluxes measured directly by eddy covariance are compared with emissions estimated from emissions factors and activity data. The latter includes contributions from vehicular traffic, household combustion, soil respiration and human breathing. The difference between estimated emissions and measured fluxes should approximate the biogenic flux. In addition, a tree survey was conducted to estimate the annual CO2 sequestration using allometric equations and an alternative model of the metabolic theory of ecology for tropical forests. Palm trees, banana plants and turfgrass were also included in the survey with their annual CO2 uptake obtained from published growth rates. Both approaches agree within 2% and suggest that vegetation captures 8% of the total emitted CO2 in the residential neighbourhood studied. A net uptake of 1.4 ton km-2 day-1 (510 ton km-2 yr-1 ) was estimated from the difference between the daily CO2 uptake by photosynthesis (3.95 ton km-2 ) and release by respiration (2.55 ton km-2). The study shows the importance of urban vegetation at the local scale for climate change mitigation in the tropics. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28484018','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28484018">Enhanced CO2 uptake at a shallow Arctic Ocean seep field overwhelms the positive warming potential of emitted methane.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Pohlman, John W; Greinert, Jens; Ruppel, Carolyn; Silyakova, Anna; Vielstädte, Lisa; Casso, Michael; Mienert, Jürgen; Bünz, Stefan 2017-05-23 Continued warming of the Arctic Ocean in coming decades is projected to trigger the release of teragrams (1 Tg = 10 6 tons) of methane from thawing subsea permafrost on shallow continental shelves and dissociation of methane hydrate on upper continental slopes. On the shallow shelves (<100 m water depth), methane released from the seafloor may reach the atmosphere and potentially amplify global warming. On the other hand, biological uptake of carbon dioxide (CO 2 ) has the potential to offset the positive warming potential of emitted methane, a process that has not received detailed consideration for these settings. Continuous sea-air gas flux data collected over a shallow ebullitive methane seep field on the Svalbard margin reveal atmospheric CO 2 uptake rates (-33,300 ± 7,900 μmol m -2 ⋅d -1 ) twice that of surrounding waters and ∼1,900 times greater than the diffusive sea-air methane efflux (17.3 ± 4.8 μmol m -2 ⋅d -1 ). The negative radiative forcing expected from this CO 2 uptake is up to 231 times greater than the positive radiative forcing from the methane emissions. Surface water characteristics (e.g., high dissolved oxygen, high pH, and enrichment of 13 C in CO 2 ) indicate that upwelling of cold, nutrient-rich water from near the seafloor accompanies methane emissions and stimulates CO 2 consumption by photosynthesizing phytoplankton. These findings challenge the widely held perception that areas characterized by shallow-water methane seeps and/or strongly elevated sea-air methane flux always increase the global atmospheric greenhouse gas burden. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5448205','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5448205">Enhanced CO2 uptake at a shallow Arctic Ocean seep field overwhelms the positive warming potential of emitted methane</a> <a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Greinert, Jens; Silyakova, Anna; Vielstädte, Lisa; Casso, Michael; Mienert, Jürgen; Bünz, Stefan 2017-01-01 Continued warming of the Arctic Ocean in coming decades is projected to trigger the release of teragrams (1 Tg = 106 tons) of methane from thawing subsea permafrost on shallow continental shelves and dissociation of methane hydrate on upper continental slopes. On the shallow shelves (<100 m water depth), methane released from the seafloor may reach the atmosphere and potentially amplify global warming. On the other hand, biological uptake of carbon dioxide (CO2) has the potential to offset the positive warming potential of emitted methane, a process that has not received detailed consideration for these settings. Continuous sea−air gas flux data collected over a shallow ebullitive methane seep field on the Svalbard margin reveal atmospheric CO2 uptake rates (−33,300 ± 7,900 μmol m−2⋅d−1) twice that of surrounding waters and ∼1,900 times greater than the diffusive sea−air methane efflux (17.3 ± 4.8 μmol m−2⋅d−1). The negative radiative forcing expected from this CO2 uptake is up to 231 times greater than the positive radiative forcing from the methane emissions. Surface water characteristics (e.g., high dissolved oxygen, high pH, and enrichment of 13C in CO2) indicate that upwelling of cold, nutrient-rich water from near the seafloor accompanies methane emissions and stimulates CO2 consumption by photosynthesizing phytoplankton. These findings challenge the widely held perception that areas characterized by shallow-water methane seeps and/or strongly elevated sea−air methane flux always increase the global atmospheric greenhouse gas burden. PMID:28484018 </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..1918160M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..1918160M">Application of a two-dimensional hydrodynamic model for calculating the CO_{2} and H_{2}O fluxes over complex terrain</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Mukhartova, Yulia; Krupenko, Alexandr; Levashova, Natalia; Olchev, Alexandr 2017-04-01 Within the framework of the study a two dimensional hydrodynamic model of turbulent transfer of greenhouse gases was developed and applied for calculating the CO2 and H2O turbulent fluxes within the atmospheric surface layer over the heterogeneous land surface with mosaic vegetation and complex topography. The vegetation cover in the model is represented as the two-phase medium containing the elements of vegetation and the air. The model is based on solving the system of averaged Navier-Stokes and continuity equations for the wind velocity components (⃗V = {V1,V2}), using the 1.5-order closure scheme (Wilcox 1998, Wyngaard 2010). The system of the main equations includes also the diffusion and advection equations for turbulent transfer of sensible heat, CO2 concentration (Cs) and specific humidity (q) at soil - vegetation -atmosphere interface (Sogachev, Panferov 2006, Mukhartova et al. 2015, Mamkin et al. 2016): ( ) { ( )} ∂Vi+ ⃗V,∇ V = -1ṡ-∂-δP -∂- 2δ ¯e- K ṡ ∂Vi-+ ∂Vj- +gṡδTv+F , i,j = 1,2, ∂t i ρ0 ∂xi ∂xj 3 ij ∂xj ∂xi T0 i div⃗V = 0, ∂T ( ) Tv γa ∂T 1 ( ) H ∂t-+ ⃗V ,∇ T+ γaṡT-ṡV2 = div (KT ṡ∇T )+ T-ṡKT ṡ∂x-+ρ-c- ⃗V,∇ δP -ρ-c-, 0 0 2 0 p 0 p ∂Cs- (⃗ ) ∂q- (⃗ ) E- ∂t + V ,∇ Cs = div(KC ṡ∇Cs )+FC, ∂t+ V ,∇ q = div(Kv ṡ∇q )+ ρ , where x1,x2 - horizontal and vertical coordinates respectively, ρ0 - the density of dry air, δP - the deviation of mean air pressure from the hydrostatic distribution, ¯e - the turbulent kinetic energy, T - the temperature of the air, δTv = T ṡ(1+ 0.61q) -T0 - the deviation of virtual temperature from the adiabatic temperature T0(x2) for dry air, Fi - the components of the viscous drag forces induced by the presence of vegetation, K,KT,KC,Kv - turbulent exchange coefficients for momentum, sensible heat, CO2and H2O respectively, γa = g/ cp, cp - the specific heat of the air at constant atmospheric pressure, FC - the sources/sinks of CO2in </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/biblio/1332937-transient-load-following-control-analysis-advanced-co2-power-conversion-dry-air-cooling','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/1332937-transient-load-following-control-analysis-advanced-co2-power-conversion-dry-air-cooling">Transient Load Following and Control Analysis of Advanced S-CO2 Power Conversion with Dry Air Cooling</a> <a target="_blank" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Moisseytsev, Anton; Sienicki, James J. 2016-01-01 Supercritical carbon dioxide (S-CO2) Brayton cycles are under development as advanced energy converters for advanced nuclear reactors, especially the Sodium-Cooled Fast Reactor (SFR). The use of dry air cooling for direct heat rejection to the atmosphere ultimate heat sink is increasingly becoming a requirement in many regions due to restrictions on water use. The transient load following and control behavior of an SFR with an S-CO2 cycle power converter utilizing dry air cooling have been investigated. With extension and adjustment of the previously existing control strategy for direct water cooling, S-CO2 cycle power converters can also be used for loadmore » following operation in regions where dry air cooling is a requirement« less </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4948307','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4948307">Detecting regional patterns of changing CO2 flux in Alaska</a> <a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Parazoo, Nicholas C.; Wofsy, Steven C.; Koven, Charles D.; Sweeney, Colm; Lawrence, David M.; Lindaas, Jakob; Chang, Rachel Y.-W.; Miller, Charles E. 2016-01-01 With rapid changes in climate and the seasonal amplitude of carbon dioxide (CO2) in the Arctic, it is critical that we detect and quantify the underlying processes controlling the changing amplitude of CO2 to better predict carbon cycle feedbacks in the Arctic climate system. We use satellite and airborne observations of atmospheric CO2 with climatically forced CO2 flux simulations to assess the detectability of Alaskan carbon cycle signals as future warming evolves. We find that current satellite remote sensing technologies can detect changing uptake accurately during the growing season but lack sufficient cold season coverage and near-surface sensitivity to constrain annual carbon balance changes at regional scale. Airborne strategies that target regular vertical profile measurements within continental interiors are more sensitive to regional flux deeper into the cold season but currently lack sufficient spatial coverage throughout the entire cold season. Thus, the current CO2 observing network is unlikely to detect potentially large CO2 sources associated with deep permafrost thaw and cold season respiration expected over the next 50 y. Although continuity of current observations is vital, strategies and technologies focused on cold season measurements (active remote sensing, aircraft, and tall towers) and systematic sampling of vertical profiles across continental interiors over the full annual cycle are required to detect the onset of carbon release from thawing permafrost. PMID:27354511 </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1259729-detecting-regional-patterns-changing-co2-flux-alaska','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1259729-detecting-regional-patterns-changing-co2-flux-alaska">Detecting regional patterns of changing CO 2 flux in Alaska</a> <a target="_blank" href="http://www.osti.gov/pages">DOE PAGES</a> Parazoo, Nicholas C.; Commane, Roisin; Wofsy, Steven C.; ... 2016-06-27 With rapid changes in climate and the seasonal amplitude of carbon dioxide (CO 2) in the Arctic, it is critical that we detect and quantify the underlying processes controlling the changing amplitude of CO 2 to better predict carbon cycle feedbacks in the Arctic climate system. We use satellite and airborne observations of atmospheric CO 2 with climatically forced CO 2 flux simulations to assess the detectability of Alaskan carbon cycle signals as future warming evolves. We find that current satellite remote sensing technologies can detect changing uptake accurately during the growing season but lack sufficient cold season coverage andmore » near-surface sensitivity to constrain annual carbon balance changes at regional scale. Airborne strategies that target regular vertical profile measurements within continental interiors are more sensitive to regional flux deeper into the cold season but currently lack sufficient spatial coverage throughout the entire cold season. Thus, the current CO 2 observing network is unlikely to detect potentially large CO 2 sources associated with deep permafrost thaw and cold season respiration expected over the next 50 y. In conclusion, although continuity of current observations is vital, strategies and technologies focused on cold season measurements (active remote sensing, aircraft, and tall towers) and systematic sampling of vertical profiles across continental interiors over the full annual cycle are required to detect the onset of carbon release from thawing permafrost.« less </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013GGG....14.3600B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013GGG....14.3600B">Chemical weathering on the North Island of New Zealand: CO2 consumption and fluxes of Sr and Os</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Blazina, Tim; Sharma, Mukul 2013-09-01 We present Os and Sr isotope ratios and Os, Sr and major/trace element concentrations for river waters, spring waters and rains on the North Island of New Zealand. The Os and Sr data are used to examine whether the NINZ is a significant contributor of unradiogenic Os and Sr to the oceans. Major element chemistry is used to quantify weathering and CO2 consumption rates on the island to investigate relationships between these processes and Os and Sr behavior. Chemical erosion rates and CO2 consumption rates across the island range from 44 to 555 km-2 yr-1 and 95 to 1900 × 103 mol CO2 km-2 yr-1, respectively. Strontium flux for the island range from 177 to 16,100 mol km-2 yr-1 and the rivers have an average flux normalized 87Sr/86Sr ratio of 0.7075. In agreement with the previous studies these findings provide further evidence that weathering of arc terrains contributes a disproportionally large amount of Sr to the oceans and consumes very large amounts of CO2 annually compared to their areal extent. However, the 87Sr/86Sr from the NINZ is not particularly unradiogenic and it is likely not contributing significant amounts of unradiogenic Sr to the oceans. Repeated Os analyses and bottle leaching experiments revealed extensive and variable sample contamination by Os leaching from rigorously precleaned LDPE bottles. An upper bound on the flux of Os from NINZ can nevertheless be assessed and indicates that island arcs cannot provide significant amounts of unradiogenic Os to the oceans. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013AtmEn..74...60L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013AtmEn..74...60L">Variability of CO2 concentrations and fluxes in and above an urban street canyon</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Lietzke, Björn; Vogt, Roland 2013-08-01 The variability of CO2 concentrations and fluxes in dense urban environments is high due to the inherent heterogeneity of these complex areas and their spatio-temporally variable anthropogenic sources. With a focus on micro- to local-scale CO2-exchange processes, measurements were conducted in a street canyon in the city of Basel, Switzerland in 2010. CO2 fluxes were sampled at the top of the canyon (19 m) and at 39 m while vertical CO2 concentration profiles were measured in the center and at a wall of the canyon. CO2 concentration distributions in the street canyon and exchange processes with the layers above show, apart from expected general diurnal patterns due mixing layer heights, a strong dependence on wind direction relative to the canyon. As a consequence of the resulting corkscrew-like canyon vortex, accumulation of CO2 inside the canyon is modulated with distinct distribution patterns. The evaluation of diurnal traffic data provides good explanations for the vertical and horizontal differences in CO2-distribution inside the canyon. Diurnal flux characteristics at the top of the canyon can almost solely be explained with traffic density expressed by the strong linear dependence. Even the diurnal course of the flux at 39 m shows a remarkable relationship to traffic density for east wind conditions while, for west wind situations, a change toward source areas with lower emissions leads to a reduced flux. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013EGUGA..15.1398B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013EGUGA..15.1398B">Top-down estimate of surface flux in the Los Angeles Basin using a mesoscale inverse modeling technique: assessing anthropogenic emissions of CO, NOx and CO2 and their impacts</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Brioude, Jerome; Angevine, Wayne; Ahmadov, Ravan; Kim, Si Wan; Evan, Stephanie; McKeen, Stuart; Hsie, Eirh Yu; Frost, Greg; Neuman, Andy; Pollack, Ilana; Peischl, Jeff; Ryerson, Tom; Holloway, John; Brown, Steeve; Nowak, John; Roberts, Jim; Wofsy, Steeve; Santoni, Greg; Trainer, Michael 2013-04-01 We present top-down estimates of anthropogenic CO, NOx and CO2 surface fluxes at mesoscale using a Lagrangian model in combination with three different WRF model configurations, driven by data from aircraft flights during the CALNEX campaign in southern California in May-June 2010. The US EPA National Emission Inventory 2005 (NEI 2005) was the prior in the CO and NOx inversion calculations. The flux ratio inversion method, based on linear relationships between chemical species, was used to calculate the CO2 inventory without prior knowledge of CO2 surface fluxes. The inversion was applied to each flight to estimate the variability of single-flight-based flux estimates. In Los Angeles (LA) County, the uncertainties on CO and NOx fluxes were 10% and 15%, respectively. Compared with NEI 2005, the CO posterior emissions were lower by 43% ± 6% in LA County and by 37% ± 10% in the South Coast Air Basin (SoCAB). NOx posterior emissions were lower by 32% ± 10% in LA County and by 27% ± 15% in the SoCAB. NOx posterior emissions were 40% lower on weekends relative to weekdays. The CO2 posterior estimates were 183 ± 18 Tg yr-1 in SoCAB. A flight during ITCT in 2002 was used to estimate emissions in the LA Basin in 2002. From 2002 to 2010, the CO and NOx posterior emissions decreased by 41% and 37%, respectively, in agreement with previous studies. Over the same time period, CO2 emissions increased by 10% ± 14% in LA County but decreased by 4% ± 10% in the SoCAB, a statistically insignificant change. Overall, the posterior estimates were in good agreement with the California Air Resources Board (CARB) inventory, with differences of 15% or less. However, the posterior spatial distribution in the basin was significantly different from CARB for NOx emissions. WRF-Chem mesoscale chemical-transport model simulations allowed an evaluation of differences in chemistry using different inventory assumptions, including NEI 2005, CARB 2010 and the posterior inventories derived in </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013ACP....13.3661B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013ACP....13.3661B">Top-down estimate of surface flux in the Los Angeles Basin using a mesoscale inverse modeling technique: assessing anthropogenic emissions of CO, NOx and CO2 and their impacts</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Brioude, J.; Angevine, W. M.; Ahmadov, R.; Kim, S.-W.; Evan, S.; McKeen, S. A.; Hsie, E.-Y.; Frost, G. J.; Neuman, J. A.; Pollack, I. B.; Peischl, J.; Ryerson, T. B.; Holloway, J.; Brown, S. S.; Nowak, J. B.; Roberts, J. M.; Wofsy, S. C.; Santoni, G. W.; Oda, T.; Trainer, M. 2013-04-01 We present top-down estimates of anthropogenic CO, NOx and CO2 surface fluxes at mesoscale using a Lagrangian model in combination with three different WRF model configurations, driven by data from aircraft flights during the CALNEX campaign in southern California in May-June 2010. The US EPA National Emission Inventory 2005 (NEI 2005) was the prior in the CO and NOx inversion calculations. The flux ratio inversion method, based on linear relationships between chemical species, was used to calculate the CO2 inventory without prior knowledge of CO2 surface fluxes. The inversion was applied to each flight to estimate the variability of single-flight-based flux estimates. In Los Angeles (LA) County, the uncertainties on CO and NOx fluxes were 10% and 15%, respectively. Compared with NEI 2005, the CO posterior emissions were lower by 43% in LA County and by 37% in the South Coast Air Basin (SoCAB). NOx posterior emissions were lower by 32% in LA County and by 27% in the SoCAB. NOx posterior emissions were 40% lower on weekends relative to weekdays. The CO2 posterior estimates were 183 Tg yr-1 in SoCAB. A flight during ITCT (Intercontinental Transport and Chemical Transformation) in 2002 was used to estimate emissions in the LA Basin in 2002. From 2002 to 2010, the CO and NOx posterior emissions decreased by 41% and 37%, respectively, in agreement with previous studies. Over the same time period, CO2 emissions increased by 10% in LA County but decreased by 4% in the SoCAB, a statistically insignificant change. Overall, the posterior estimates were in good agreement with the California Air Resources Board (CARB) inventory, with differences of 15% or less. However, the posterior spatial distribution in the basin was significantly different from CARB for NOx emissions. WRF-Chem mesoscale chemical-transport model simulations allowed an evaluation of differences in chemistry using different inventory assumptions, including NEI 2005, a gridded CARB inventory and the posterior </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012ACPD...1231439B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012ACPD...1231439B">Top-down estimate of surface flux in the Los Angeles Basin using a mesoscale inverse modeling technique: assessing anthropogenic emissions of CO, NOx and CO2 and their impacts</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Brioude, J.; Angevine, W. M.; Ahmadov, R.; Kim, S.-W.; Evan, S.; McKeen, S. A.; Hsie, E.-Y.; Frost, G. J.; Neuman, J. A.; Pollack, I. B.; Peischl, J.; Ryerson, T. B.; Holloway, J.; Brown, S. S.; Nowak, J. B.; Roberts, J. M.; Wofsy, S. C.; Santoni, G. W.; Trainer, M. 2012-12-01 We present top-down estimates of anthropogenic CO, NOx and CO2 surface fluxes at mesoscale using a Lagrangian model in combination with three different WRF model configurations, driven by data from aircraft flights during the CALNEX campaign in southern California in May-June 2010. The US EPA National Emission Inventory 2005 (NEI 2005) was the prior in the CO and NOx inversion calculations. The flux ratio inversion method, based on linear relationships between chemical species, was used to calculate the CO2 inventory without prior knowledge of CO2 surface fluxes. The inversion was applied to each flight to estimate the variability of single-flight-based flux estimates. In Los Angeles (LA) County, the uncertainties on CO and NOx fluxes were 10% and 15%, respectively. Compared with NEI 2005, the CO posterior emissions were lower by 43% ± 6% in LA County and by 37% ± 10% in the South Coast Air Basin (SoCAB). NOx posterior emissions were lower by 32% ± 10% in LA County and by 27% ± 15% in the SoCAB. NOx posterior emissions were 40% lower on weekends relative to weekdays. The CO2 posterior estimates were 183 ± 18 Tg yr-1 in SoCAB. A flight during ITCT in 2002 was used to estimate emissions in the LA Basin in 2002. From 2002 to 2010, the CO and NOx posterior emissions decreased by 41% and 37%, respectively, in agreement with previous studies. Over the same time period, CO2 emissions increased by 10% ± 14% in LA County but decreased by 4% ± 10% in the SoCAB, a statistically insignificant change. Overall, the posterior estimates were in good agreement with the California Air Resources Board (CARB) inventory, with differences of 15% or less. However, the posterior spatial distribution in the basin was significantly different from CARB for NOx emissions. WRF-Chem mesoscale chemical-transport model simulations allowed an evaluation of differences in chemistry using different inventory assumptions, including NEI 2005, CARB 2010 and the posterior inventories derived in </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016QuRes..85...87C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016QuRes..85...87C">Variability of 14C reservoir age and air-sea flux of CO2 in the Peru-Chile upwelling region during the past 12,000 years</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Carré, Matthieu; Jackson, Donald; Maldonado, Antonio; Chase, Brian M.; Sachs, Julian P. 2016-01-01 The variability of radiocarbon marine reservoir age through time and space limits the accuracy of chronologies in marine paleo-environmental archives. We report here new radiocarbon reservoir ages (ΔR) from the central coast of Chile ( 32°S) for the Holocene period and compare these values to existing reservoir age reconstructions from southern Peru and northern Chile. Late Holocene ΔR values show little variability from central Chile to Peru. Prior to 6000 cal yr BP, however, ΔR values were markedly increased in southern Peru and northern Chile, while similar or slightly lower-than-modern ΔR values were observed in central Chile. This extended dataset suggests that the early Holocene was characterized by a substantial increase in the latitudinal gradient of marine reservoir age between central and northern Chile. This change in the marine reservoir ages indicates that the early Holocene air-sea flux of CO2 could have been up to five times more intense than in the late Holocene in the Peruvian upwelling, while slightly reduced in central Chile. Our results show that oceanic circulation changes in the Humboldt system during the Holocene have substantially modified the air-sea carbon flux in this region. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://hdl.handle.net/2060/19970021275','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/19970021275">Low pCO2 Air-Polarized CO2 Concentrator Development</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Schubert, Franz H. 1997-01-01 Life Systems completed a Ground-based Space Station Experiment Development Study Program which verifies through testing the performance and applicability of the electrochemical Air-Polarized Carbon Dioxide Concentrator (APC) process technology for space missions requiring low (i.e., less than 3 mm Hg) CO2 partial pressure (pCO2) in the cabin atmosphere. Required test hardware was developed and testing was accomplished at an approximate one-person capacity CO2 removal level. Initially, two five-cell electrochemical modules using flight-like 0.5 sq ft cell hardware were tested individually, following by their testing at the integrated APC system level. Testing verified previously projected performance and established a database for sizing of APC systems. A four person capacity APC system was sized and compared with four candidate CO2 removal systems. At its weight of 252 lb, a volume of 7 cu ft and a power consumption of 566 W while operating at 2.2 mm Hg pCO2, the APC was surpassed only by an Electrochemical Depolarized CO2 Concentrator (EDC) (operating with H2), when compared on a total equivalent basis. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://www.ars.usda.gov/research/publications/publication/?seqNo115=276808','TEKTRAN'); return false;" href="http://www.ars.usda.gov/research/publications/publication/?seqNo115=276808">Calculating CO2 and H2O eddy covariance fluxes from an enclosed gas analyzer using an instantaneous mixing ratio 2159</a> <a target="_blank" href="https://www.ars.usda.gov/research/publications/find-a-publication/">USDA-ARS?s Scientific Manuscript database</a> Eddy covariance flux research has relied on open- or closed-path gas analyzers for producing estimates of net ecosystem exchange of carbon dioxide (CO2) and water vapor (H2O). The two instruments have had different challenges that have led to development of an enclosed design that is intended to max... </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_12");'>12</a></li> <li><a href="#" onclick='return showDiv("page_13");'>13</a></li> <li class="active">14</li> <li><a href="#" onclick='return showDiv("page_15");'>15</a></li> <li><a href="#" onclick='return showDiv("page_16");'>16</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_15" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_13");'>13</a></li> <li><a href="#" onclick='return showDiv("page_14");'>14</a></li> <li class="active">15</li> <li><a href="#" onclick='return showDiv("page_16");'>16</a></li> <li><a href="#" onclick='return showDiv("page_17");'>17</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="281"> <li> <a target="_blank" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4849023','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4849023">Changes in Air CO2 Concentration Differentially Alter Transcript Levels of NtAQP1 and NtPIP2;1 Aquaporin Genes in Tobacco Leaves</a> <a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Secchi, Francesca; Schubert, Andrea; Lovisolo, Claudio 2016-01-01 The aquaporin specific control on water versus carbon pathways in leaves is pivotal in controlling gas exchange and leaf hydraulics. We investigated whether Nicotiana tabacum aquaporin 1 (NtAQP1) and Nicotiana tabacum plasma membrane intrinsic protein 2;1 (NtPIP2;1) gene expression varies in tobacco leaves subjected to treatments with different CO2 concentrations (ranging from 0 to 800 ppm), inducing changes in photosynthesis, stomatal regulation and water evaporation from the leaf. Changes in air CO2 concentration ([CO2]) affected net photosynthesis (Pn) and leaf substomatal [CO2] (Ci). Pn was slightly negative at 0 ppm air CO2; it was one-third that of ambient controls at 200 ppm, and not different from controls at 800 ppm. Leaves fed with 800 ppm [CO2] showed one-third reduced stomatal conductance (gs) and transpiration (E), and their gs was in turn slightly lower than in 200 ppm– and in 0 ppm–treated leaves. The 800 ppm air [CO2] strongly impaired both NtAQP1 and NtPIP2;1 gene expression, whereas 0 ppm air [CO2], a concentration below any in vivo possible conditions and specifically chosen to maximize the gene expression alteration, increased only the NtAQP1 transcript level. We propose that NtAQP1 expression, an aquaporin devoted to CO2 transport, positively responds to CO2 scarcity in the air in the whole range 0–800 ppm. On the contrary, expression of NtPIP2;1, an aquaporin not devoted to CO2 transport, is related to water balance in the leaf, and changes in parallel with gs. These observations fit in a model where upregulation of leaf aquaporins is activated at low Ci, while downregulation occurs when high Ci saturates photosynthesis and causes stomatal closure. PMID:27089333 </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.fs.usda.gov/treesearch/pubs/48404','TREESEARCH'); return false;" href="https://www.fs.usda.gov/treesearch/pubs/48404">Diffusional flux of CO2 through snow: Spatial and temporal variability among alpine-subalpine sites</a> <a target="_blank" href="http://www.fs.usda.gov/treesearch/">Treesearch</a> Richard A. Sommerfeld; William J. Massman; Robert C. Musselman 1996-01-01 Three alpine and three subalpine sites were monitored for up to 4 years to acquire data on the temporal and spatial variability of CO2 flux through snowpacks. We conclude that the snow formed a passive cap which controlled the concentration of CO2 at the snow-soil interface, while the flux of CO2 into the atmosphere was controlled by CO2 production in the soil.... </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015EGUGA..1715084M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015EGUGA..1715084M">Agricultural crops and soil treatment impacts on the daily and seasonal dynamics of CO2 fluxes in the field agroecosystems at the Central region of Russia</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Mazirov, Ilya; Vasenev, Ivan; Meshalkina, Joulia; Yaroslavtsev, Alexis; Berezovskiy, Egor; Djancharov, Turmusbek 2015-04-01 The problem of greenhouse gases' concentrations increasing becomes more and more important due to global changes issues. The main component of greenhouse gases is carbon dioxide. The researches focused on its fluxes in natural and anthropogenic modified landscapes can help in this problem solution. Our research has been done with support of the RF Government grants # 11.G34.31.0079 and # 14.120.14.4266 and of FP7 Grant # 603542 LUC4C in the representative for Central Region of Russia field agroecosystems at the Precision Farming Experimental Field of Russian Timiryazev State Agrarian University with cultivated sod podzoluvisols, barley and oats - vetch grass mix (Moscow station of the RusFluxNet). The daily and seasonal dynamics of the carbon dioxide have been studied at the ecosystem level by the Eddy covariance method (2 stations) and at the soil level by the exposition chamber method (40 chambers) with mobile infra red gas analyzer (Li-Cor 820). The primary Eddy covariance monitoring data on CO2 fluxes and water vapor have been processed by EddyPro software developed by LI-COR Biosciences. According to the two-year monitoring data the daily CO2 sink during the vegetation season is usually approximately two times higher than its emission at night. Seasonal CO2 fluxes comparative stabilization has been fixed in case the plants height around 10-12 cm and it usually persist until the wax ripeness phase. There is strong dependence between the soil CO2 emission and the air temperature with the correlation coefficient 0.86 in average (due to strong input of the soil thin top functional subhorizon), but it drops essentially at the end of the season - till 0.38. The soil moisture impact on CO2 fluxes dynamics was less, with negative correlation at the end of the season. High daily dynamics of CO2 fluxes determines the protocol requirements for seasonal soil monitoring investigation with less limitation at the end of the season. The accumulated monitoring data will be </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.B53I..03W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.B53I..03W">Warming trumps CO2: future climate conditions suppress carbon fluxes in two dominant boreal tree species</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Way, D.; Dusenge, M. E.; Madhavji, S. 2017-12-01 Increases in CO2 are expected to raise air temperatures in northern latitudes by up to 8 °C by the end of the century. Boreal forests in these regions play a large role in the global carbon cycle, and the responses of boreal tree species to climate drivers will thus have considerable impacts on the trajectory of future CO2 increases. We grew two dominant North American boreal tree species at a range of future climate conditions to assess how carbon fluxes were altered by high CO2 and warming. Black spruce (Picea mariana) and tamarack (Larix laricina) were grown from seed under either ambient (400 ppm) or elevated CO2 concentrations (750 ppm) and either ambient temperatures, moderate warming (ambient +4 °C), or extreme warming (ambient +8 °C) for six months. We measured temperature responses of net photosynthesis, maximum rates of Rubisco carboxylation (Vcmax) and electron transport (Jmax) and dark respiration to determine acclimation to the climate treatments. Overall, growth temperature had a strong effect on carbon fluxes, while there were no significant effects of growth CO2. In both species, the photosynthetic thermal optimum increased and maximum photosynthetic rates were reduced in warm-grown seedlings, but the strength of these changes varied between species. Vcmax and Jmax were also reduced in warm-grown seedlings, and this correlated with reductions in leaf N concentrations. Warming increased the activation energy for Vcmax and the thermal optimum for Jmax in both species. Respiration acclimated to elevated growth temperatures, but there were no treatment effects on the Q10 of respiration (the increase in respiration for a 10 °C increase in leaf temperature). Our results show that climate warming is likely to reduce carbon fluxes in these boreal conifers, and that photosynthetic parameters used to model photosynthesis in dynamic global vegetation models acclimate to increased temperatures, but show little response to elevated CO2. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.A53I..07B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.A53I..07B">Eddy-Covariance Observations and Large-Eddy-Simulations of Near-Shore Fluxes from Water Bodies</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Bohrer, G.; Rey Sanchez, C.; Kenny, W.; Morin, T. H. 2017-12-01 Eddy covariance (EC) measurement techniques are increasingly used in the study of lakes and coastal ecosystems. The sharp water-shore transitions in energy forcing and surface roughness are challenging the validity of the EC approach at these sites. We discuss the results of two seasonal campaigns to measure CO2 and water-vapor fluxes in coastal environments - a small lake in Michigan, and the water over a coral reef in the Red, Sea, Israel. We show that in both environments, horizontal advection of CO2 and water vapor is responsible to a non-negligible component of the total flux to/from the water. We used a two-tower approach to measure fluxes from the water and from the shore and calculate the advection and flux divergence between the two. An empirical footprint model was used to filter the observations and keep only the times when interference from the shore-line transition is minimal. Observations of both vertical turbulent fluxes and advection were gapfilled with a neural-network model, based on their observed relationships with environmental forcing. Gap-filled observations were used to determine the seasonal net fluxes for the tow ecosystems. We used Large-Eddy Simulations (LES) to conduct a case study of airflow patterns associated with a small inland lake surrounded by forest (i.e. radius of lake only ten times the height of the forest). We combined LES outputs with scalar dispersion simulations to model potential biases in EC flux measurements due to the heterogeneity of surface fluxes and vertical advection. Our simulations show that the lake-to-forest transition can induce a non-zero vertical wind component, which will strongly affect the interpretation of wind and flux measurements. Furthermore, significant horizontal gradients of CO2 are generated by the forest carbon sink and lake carbon source, which are further transported by local roughness-induced circulation. We simulated six hypothetical flux tower locations along a downwind gradient at </li> <li> <a target="_blank" onclick="trackOutboundLink('http://hdl.handle.net/2060/20090025444','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20090025444">Turbulent CO2 Flux Measurements by Lidar: Length Scales, Results and Comparison with In-Situ Sensors</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Gilbert, Fabien; Koch, Grady J.; Beyon, Jeffrey Y.; Hilton, Timothy W.; Davis, Kenneth J.; Andrews, Arlyn; Ismail, Syed; Singh, Upendra N. 2009-01-01 The vertical CO2 flux in the atmospheric boundary layer (ABL) is investigated with a Doppler differential absorption lidar (DIAL). The instrument was operated next to the WLEF instrumented tall tower in Park Falls, Wisconsin during three days and nights in June 2007. Profiles of turbulent CO2 mixing ratio and vertical velocity fluctuations are measured by in-situ sensors and Doppler DIAL. Time and space scales of turbulence are precisely defined in the ABL. The eddy-covariance method is applied to calculate turbulent CO2 flux both by lidar and in-situ sensors. We show preliminary mean lidar CO2 flux measurements in the ABL with a time and space resolution of 6 h and 1500 m respectively. The flux instrumental errors decrease linearly with the standard deviation of the CO2 data, as expected. Although turbulent fluctuations of CO2 are negligible with respect to the mean (0.1 %), we show that the eddy-covariance method can provide 2-h, 150-m range resolved CO2 flux estimates as long as the CO2 mixing ratio instrumental error is no greater than 10 ppm and the vertical velocity error is lower than the natural fluctuations over a time resolution of 10 s. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014EGUGA..1616784M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014EGUGA..1616784M">CO2 Fluxes Monitoring at the Level of Field Agroecosystem in Moscow Region of Russia</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Meshalkina, Joulia; Mazirov, Ilya; Samardzic, Miljan; Yaroslavtsev, Alexis; Valentini, Riccardo; Vasenev, Ivan 2014-05-01 The Central Russia is still one of the less GHG-investigated European areas especially in case of agroecosystem-level carbon dioxide fluxes monitoring by eddy covariance method. The eddy covariance technique is a statistical method to measure and calculate vertical turbulent fluxes within atmospheric boundary layers. The major assumption of the metod is that measurements at a point can represent an entire upwind area. Eddy covariance researches, which could be considered as repeated for the same area, are very rare. The research has been carried out on the Precision Farming Experimental Field of the Russian Timiryazev State Agricultural University (Moscow, Russia) in 2013 under the support of RF Government grant No. 11.G34.31.0079. Arable derno-podzoluvisls have around 1 The results have shown high daily and seasonal dynamic of agroecosystem CO2 emission. Sowing activates soil microbiological activity and the average soil CO2 emission and adsorption are rising at the same time. CO2 streams are intensified after crop emerging from values of 3 to 7 μmol/s-m2 for emission, and from values of 5 to 20 μmol/s-m2 for adsorption. Stabilization of the flow has come at achieving plants height of 10-12 cm. The vegetation period is characterized by high average soil CO2 emission and adsorption at the same time, but the adsorption is significantly higher. The resulted CO2 absorption during the day is approximately 2-5 times higher than emissions at night. For example, in mid-June, the absorption value was about 0.45 mol/m2 during the day-time, and the emission value was about 0.1 mol/m2 at night. After harvesting CO2 emission is becoming essentially higher than adsorption. Autumn and winter data are fluctuate around zero, but for some periods a small predominance of CO2 emissions over the absorption may be observed. The daily dynamics of CO2 emissions depends on the air temperature with the correlation coefficient changes between 0.4 and 0.8. Crop stage, agrotechnological </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/23552893','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/23552893">Terrestrial water fluxes dominated by transpiration.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Jasechko, Scott; Sharp, Zachary D; Gibson, John J; Birks, S Jean; Yi, Yi; Fawcett, Peter J 2013-04-18 Renewable fresh water over continents has input from precipitation and losses to the atmosphere through evaporation and transpiration. Global-scale estimates of transpiration from climate models are poorly constrained owing to large uncertainties in stomatal conductance and the lack of catchment-scale measurements required for model calibration, resulting in a range of predictions spanning 20 to 65 per cent of total terrestrial evapotranspiration (14,000 to 41,000 km(3) per year) (refs 1, 2, 3, 4, 5). Here we use the distinct isotope effects of transpiration and evaporation to show that transpiration is by far the largest water flux from Earth's continents, representing 80 to 90 per cent of terrestrial evapotranspiration. On the basis of our analysis of a global data set of large lakes and rivers, we conclude that transpiration recycles 62,000 ± 8,000 km(3) of water per year to the atmosphere, using half of all solar energy absorbed by land surfaces in the process. We also calculate CO2 uptake by terrestrial vegetation by connecting transpiration losses to carbon assimilation using water-use efficiency ratios of plants, and show the global gross primary productivity to be 129 ± 32 gigatonnes of carbon per year, which agrees, within the uncertainty, with previous estimates. The dominance of transpiration water fluxes in continental evapotranspiration suggests that, from the point of view of water resource forecasting, climate model development should prioritize improvements in simulations of biological fluxes rather than physical (evaporation) fluxes. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012AMT.....5.2689N','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012AMT.....5.2689N">Effect of air composition (N2, O2, Ar, and H2O) on CO2 and CH4 measurement by wavelength-scanned cavity ring-down spectroscopy: calibration and measurement strategy</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Nara, H.; Tanimoto, H.; Tohjima, Y.; Mukai, H.; Nojiri, Y.; Katsumata, K.; Rella, C. W. 2012-11-01 We examined potential interferences from water vapor and atmospheric background gases (N2, O2, and Ar), and biases by isotopologues of target species, on accurate measurement of atmospheric CO2 and CH4 by means of wavelength-scanned cavity ring-down spectroscopy (WS-CRDS). Changes of the background gas mole fractions in the sample air substantially impacted the CO2 and CH4 measurements: variation of CO2 and CH4 due to relative increase of each background gas increased as Ar < O2 < N2, suggesting similar relation for the pressure-broadening effects (PBEs) among the background gas. The pressure-broadening coefficients due to variations in O2 and Ar for CO2 and CH4 are empirically determined from these experimental results. Calculated PBEs using the pressure-broadening coefficients are linearly correlated with the differences between the mole fractions of O2 and Ar and their ambient abundances. Although the PBEs calculation showed that impact of natural variation of O2 is negligible on the CO2 and CH4 measurements, significant bias was inferred for the measurement of synthetic standard gases. For gas standards balanced with purified air, the PBEs were estimated to be marginal (up to 0.05 ppm for CO2 and 0.01 ppb for CH4) although the PBEs were substantial (up to 0.87 ppm for CO2 and 1.4 ppb for CH4) for standards balanced with synthetic air. For isotopic biases on CO2 measurements, we compared experimental results and theoretical calculations, which showed excellent agreement within their uncertainty. We derived instrument-specific water correction functions empirically for three WS-CRDS instruments (Picarro EnviroSense 3000i, G-1301, and G-2301), and evaluated the transferability of the water correction function from G-1301 among these instruments. Although the transferability was not proven, no significant difference was found in the water vapor correction function for the investigated WS-CRDS instruments as well as the instruments reported in the past studies </li> <li> <a target="_blank" onclick="trackOutboundLink('http://www.ars.usda.gov/research/publications/publication/?seqNo115=345752','TEKTRAN'); return false;" href="http://www.ars.usda.gov/research/publications/publication/?seqNo115=345752">Net ecosystem exchange of CO2 and H2O fluxes from irrigated grain sorghum and maize in the Texas High Plains</a> <a target="_blank" href="https://www.ars.usda.gov/research/publications/find-a-publication/">USDA-ARS?s Scientific Manuscript database</a> Net ecosystem exchange (NEE) of carbon dioxide (CO2) and water vapor (H2O) fluxes from irrigated grain sorghum (Sorghum bicolor L. Moench) and maize (Zea mays L.) fields in the Texas High Plains were quantified using the eddy covariance (EC) technique during 2014-2016 growing seasons and examined in... </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1302506-intermediate-scale-community-level-flux-co2-ch4-minnesota-peatland-putting-spruce-project-global-context','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1302506-intermediate-scale-community-level-flux-co2-ch4-minnesota-peatland-putting-spruce-project-global-context">Intermediate-scale community-level flux of CO 2 and CH 4 in a Minnesota peatland: Putting the SPRUCE project in a global context</a> <a target="_blank" href="http://www.osti.gov/pages">DOE PAGES</a> Hanson, Paul J.; Gill, Allison; Xu, Xiaofeng; ... 2016-08-20 Peatland measurements of CO 2 and CH 4 flux were obtained at scales appropriate to the in situ biological community below the tree layer to demonstrate representativeness of the spruce and peatland responses under climatic and environmental change (SPRUCE) experiment. Surface flux measurements were made using dual open-path analyzers over an area of 1.13 m 2 in daylight and dark conditions along with associated peat temperatures, water table height, hummock moisture, atmospheric pressure and incident radiation data. Observations from August 2011 through December 2014 demonstrated seasonal trends correlated with temperature as the dominant apparent driving variable. The S1-Bog for themore » SPRUCE study was found to be representative of temperate peatlands in terms of CO 2 and CH 4 flux. Maximum net CO 2 flux in midsummer showed similar rates of C uptake and loss: daytime surface uptake was -5 to -6 µmol m -2 s -1 and dark period loss rates were 4–5 µmol m -2 s -1 (positive values are carbon lost to the atmosphere). Maximum midsummer CH4-C flux ranged from 0.4 to 0.5 µmol m -2 s -1 and was a factor of 10 lower than dark CO 2–C efflux rates. Midwinter conditions produced near-zero flux for both CO 2 and CH 4 with frozen surfaces. Integrating temperature-dependent models across annual periods showed dark CO 2–C and CH 4–C flux to be 894 ± 34 and 16 ± 2 gC m -2 y -1, respectively. Net ecosystem exchange of carbon from the shrub-forb-Sphagnum-microbial community (excluding tree contributions) ranged from -3.1 gCO2–C m -2 y -1 in 2013, to C losses from 21 to 65 gCO 2–C m -2 y -1 for the other years.« less </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015EGUGA..1710530G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015EGUGA..1710530G">Potentials and challenges associated with automated closed dynamic chamber measurements of soil CO2 fluxes</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Görres, Carolyn-Monika; Kammann, Claudia; Ceulemans, Reinhart 2015-04-01 Soil respiration fluxes are influenced by natural factors such as climate and soil type, but also by anthropogenic activities in managed ecosystems. As a result, soil CO2 fluxes show a large intra- and interannual as well as intra- and intersite variability. Most of the available soil CO2 flux data giving insights into this variability have been measured with manually closed static chambers, but technological advances in the past 15 years have also led to an increased use of automated closed chamber systems. The great advantage of automated chambers in comparison to manually operated chambers is the higher temporal resolution of the flux data. This is especially important if we want to better understand the effects of short-term events, e.g. fertilization or heavy rainfall, on soil CO2 flux variability. However, the chamber method is an invasive measurement method which can potentially alter soil CO2 fluxes and lead to biased measurement results. In the peer-reviewed literature, many papers compare the field performance and results of different closed static chamber designs, or compare manual chambers with automated chamber systems, to identify potential biases in CO2 flux measurements, and thus help to reduce uncertainties in the flux data. However, inter-comparisons of different automated closed dynamic chamber systems are still lacking. Here we are going to present a field comparison of the most-cited automated chamber system, the LI-8100A Automated Soil Flux System, with the also commercially available Greenhouse Gas Monitoring System AGPS. Both measurement systems were installed side by side at a recently harvested poplar bioenergy plantation (POPFULL, http://uahost.uantwerpen.be/popfull/) from April 2014 until August 2014. The plantation provided optimal comparison conditions with a bare field situation after the harvest and a regrowing canopy resulting in a broad variety of microclimates. Furthermore, the plantation was planted in a double-row system with </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29182300','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29182300">CO2-Switchable Membranes Prepared by Immobilization of CO2-Breathing Microgels.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Zhang, Qi; Wang, Zhenwu; Lei, Lei; Tang, Jun; Wang, Jianli; Zhu, Shiping 2017-12-20 Herein, we report the development of a novel CO 2 -responsive membrane system through immobilization of CO 2 -responsive microgels into commercially available microfiltration membranes using a method of dynamic adsorption. The microgels, prepared from soap-free emulsion polymerization of CO 2 -responsive monomer 2-(diethylamino)ethyl methacrylate (DEA), can be reversibly expanded and shrunken upon CO 2 /N 2 alternation. When incorporated into the membranes, this switching behavior was preserved and further led to transformation between microfiltration and ultrafiltration membranes, as indicated from the dramatic changes on water flux and BSA rejection results. This CO 2 -regulated performance switching of membranes was caused by the changes of water transportation channel, as revealed from the dynamic water contact angle tests and SEM observation. This work represents a simple yet versatile strategy for making CO 2 -responsive membranes. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014BGD....11.9249M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014BGD....11.9249M">CO2 fluxes and ecosystem dynamics at five European treeless peatlands - merging data and process oriented modelling</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Metzger, C.; Jansson, P.-E.; Lohila, A.; Aurela, M.; Eickenscheidt, T.; Belelli-Marchesini, L.; Dinsmore, K. J.; Drewer, J.; van Huissteden, J.; Drösler, M. 2014-06-01 The carbon dioxide (CO2) exchange of five different peatland systems across Europe with a wide gradient in landuse intensity, water table depth, soil fertility and climate was simulated with the process oriented CoupModel. The aim of the study was to find out to what extent CO2 fluxes measured at different sites, can be explained by common processes and parameters implemented in the model. The CoupModel was calibrated to fit measured CO2 fluxes, soil temperature, snow depth and leaf area index (LAI) and resulting differences in model parameters were analysed. Finding site independent model parameters would mean that differences in the measured fluxes could be explained solely by model input data: water table, meteorological data, management and soil inventory data. The model, utilizing a site independent configuration for most of the parameters, captured seasonal variability in the major fluxes well. Parameters that differed between sites included the rate of soil organic decomposition, photosynthetic efficiency, and regulation of the mobile carbon (C) pool from senescence to shooting in the next year. The largest difference between sites was the rate coefficient for heterotrophic respiration. Setting it to a common value would lead to underestimation of mean total respiration by a factor of 2.8 up to an overestimation by a factor of 4. Despite testing a wide range of different responses to soil water and temperature, heterotrophic respiration rates were consistently lowest on formerly drained sites and highest on the managed sites. Substrate decomposability, pH and vegetation characteristics are possible explanations for the differences in decomposition rates. Applying common parameter values for the timing of plant shooting and senescence, and a minimum temperature for photosynthesis, had only a minor effect on model performance, even though the gradient in site latitude ranged from 48° N (South-Germany) to 68° N (northern Finland). This was also true for </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3690887','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3690887">Direct electrolytic dissolution of silicate minerals for air CO2 mitigation and carbon-negative H2 production</a> <a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Rau, Greg H.; Carroll, Susan A.; Bourcier, William L.; Singleton, Michael J.; Smith, Megan M.; Aines, Roger D. 2013-01-01 We experimentally demonstrate the direct coupling of silicate mineral dissolution with saline water electrolysis and H2 production to effect significant air CO2 absorption, chemical conversion, and storage in solution. In particular, we observed as much as a 105-fold increase in OH− concentration (pH increase of up to 5.3 units) relative to experimental controls following the electrolysis of 0.25 M Na2SO4 solutions when the anode was encased in powdered silicate mineral, either wollastonite or an ultramafic mineral. After electrolysis, full equilibration of the alkalized solution with air led to a significant pH reduction and as much as a 45-fold increase in dissolved inorganic carbon concentration. This demonstrated significant spontaneous air CO2 capture, chemical conversion, and storage as a bicarbonate, predominantly as NaHCO3. The excess OH− initially formed in these experiments apparently resulted via neutralization of the anolyte acid, H2SO4, by reaction with the base mineral silicate at the anode, producing mineral sulfate and silica. This allowed the NaOH, normally generated at the cathode, to go unneutralized and to accumulate in the bulk electrolyte, ultimately reacting with atmospheric CO2 to form dissolved bicarbonate. Using nongrid or nonpeak renewable electricity, optimized systems at large scale might allow relatively high-capacity, energy-efficient (<300 kJ/mol of CO2 captured), and inexpensive (<$100 per tonne of CO2 mitigated) removal of excess air CO2 with production of carbon-negative H2. Furthermore, when added to the ocean, the produced hydroxide and/or (bi)carbonate could be useful in reducing sea-to-air CO2 emissions and in neutralizing or offsetting the effects of ongoing ocean acidification. PMID:23729814 </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/11746880','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/11746880">Extraction of CO2 from air samples for isotopic analysis and limits to ultra high precision delta18O determination in CO2 gas.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Werner, R A; Rothe, M; Brand, W A 2001-01-01 The determination of delta18O values in CO2 at a precision level of +/-0.02 per thousand (delta-notation) has always been a challenging, if not impossible, analytical task. Here, we demonstrate that beyond the usually assumed major cause of uncertainty - water contamination - there are other, hitherto underestimated sources of contamination and processes which can alter the oxygen isotope composition of CO2. Active surfaces in the preparation line with which CO2 comes into contact, as well as traces of air in the sample, can alter the apparent delta18O value both temporarily and permanently. We investigated the effects of different surface materials including electropolished stainless steel, Duran glass, gold and quartz, the latter both untreated and silanized. CO2 frozen with liquid nitrogen showed a transient alteration of the 18O/16O ratio on all surfaces tested. The time to recover from the alteration as well as the size of the alteration varied with surface type. Quartz that had been ultrasonically cleaned for several hours with high purity water (0.05 microS) exhibited the smallest effect on the measured oxygen isotopic composition of CO2 before and after freezing. However, quartz proved to be mechanically unstable with time when subjected to repeated large temperature changes during operation. After several days of operation the gas released from the freezing step contained progressively increasing trace amounts of O2 probably originating from inclusions within the quartz, which precludes the use of quartz for cryogenically trapping CO2. Stainless steel or gold proved to be suitable materials after proper pre-treatment. To ensure a high trapping efficiency of CO2 from a flow of gas, a cold trap design was chosen comprising a thin wall 1/4" outer tube and a 1/8" inner tube, made respectively from electropolished stainless steel and gold. Due to a considerable 18O specific isotope effect during the release of CO2 from the cold surface, the thawing time had to </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28640914','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28640914">Kinetic analysis of an anion exchange absorbent for CO2 capture from ambient air.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Shi, Xiaoyang; Li, Qibin; Wang, Tao; Lackner, Klaus S 2017-01-01 This study reports a preparation method of a new moisture swing sorbent for CO2 capture from air. The new sorbent components include ion exchange resin (IER) and polyvinyl chloride (PVC) as a binder. The IER can absorb CO2 when surrounding is dry and release CO2 when surrounding is wet. The manuscript presents the studies of membrane structure, kinetic model of absorption process, performance of desorption process and the diffusivity of water molecules in the CO2 absorbent. It has been proved that the kinetic performance of CO2 absorption/desorption can be improved by using thin binder and hot water treatment. The fast kinetics of P-100-90C absorbent is due to the thin PVC binder, and high diffusion rate of H2O molecules in the sample. The impressive is this new CO2 absorbent has the fastest CO2 absorption rate among all absorbents which have been reported by other up-to-date literatures. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5480984','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5480984">Kinetic analysis of an anion exchange absorbent for CO2 capture from ambient air</a> <a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Shi, Xiaoyang; Li, Qibin; Lackner, Klaus S. 2017-01-01 This study reports a preparation method of a new moisture swing sorbent for CO2 capture from air. The new sorbent components include ion exchange resin (IER) and polyvinyl chloride (PVC) as a binder. The IER can absorb CO2 when surrounding is dry and release CO2 when surrounding is wet. The manuscript presents the studies of membrane structure, kinetic model of absorption process, performance of desorption process and the diffusivity of water molecules in the CO2 absorbent. It has been proved that the kinetic performance of CO2 absorption/desorption can be improved by using thin binder and hot water treatment. The fast kinetics of P-100-90C absorbent is due to the thin PVC binder, and high diffusion rate of H2O molecules in the sample. The impressive is this new CO2 absorbent has the fastest CO2 absorption rate among all absorbents which have been reported by other up-to-date literatures. PMID:28640914 </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.A51M..01A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.A51M..01A">North American CO2 fluxes for 2007-2015 from NOAA's CarbonTracker-Lagrange Regional Inverse Modeling Framework</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Andrews, A. E.; Hu, L.; Thoning, K. W.; Nehrkorn, T.; Mountain, M. E.; Jacobson, A. R.; Michalak, A.; Dlugokencky, E. J.; Sweeney, C.; Worthy, D. E. J.; Miller, J. B.; Fischer, M. L.; Biraud, S.; van der Velde, I. R.; Basu, S.; Tans, P. P. 2017-12-01 CarbonTracker-Lagrange (CT-L) is a new high-resolution regional inverse modeling system for improved estimation of North American CO2 fluxes. CT-L uses footprints from the Stochastic Time-Inverted Lagrangian Transport (STILT) model driven by high-resolution (10 to 30 km) meteorological fields from the Weather Research and Forecasting (WRF) model. We performed a suite of synthetic-data experiments to evaluate a variety of inversion configurations, including (1) solving for scaling factors to an a priori flux versus additive corrections, (2) solving for fluxes at 3-hrly resolution versus at coarser temporal resolution, (3) solving for fluxes at 1o × 1o resolution versus at large eco-regional scales. Our framework explicitly and objectively solves for the optimal solution with a full error covariance matrix with maximum likelihood estimation, thereby enabling rigorous uncertainty estimates for the derived fluxes. In the synthetic-data inversions, we find that solving for weekly scaling factors of a priori Net Ecosystem Exchange (NEE) at 1o × 1o resolution with optimization of diurnal cycles of CO2 fluxes yields faithful retrieval of the specified "true" fluxes as those solved at 3-hrly resolution. In contrast, a scheme that does not allow for optimization of diurnal cycles of CO2 fluxes suffered from larger aggregation errors. We then applied the optimal inversion setup to estimate North American fluxes for 2007-2015 using real atmospheric CO2 observations, multiple prior estimates of NEE, and multiple boundary values estimated from the NOAA's global Eulerian CarbonTracker (CarbonTracker) and from an empirical approach. Our derived North American land CO2 fluxes show larger seasonal amplitude than those estimated from the CarbonTracker, removing seasonal biases in the CarbonTracker's simulated CO2 mole fractions. Independent evaluations using in-situ CO2 eddy covariance flux measurements and independent aircraft profiles also suggest an improved estimation on North </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1076541','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1076541">EGS rock reactions with Supercritical CO2 saturated with water and water saturated with Supercritical CO2</a> <a target="_blank" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Earl D. Mattson; Travis L. McLing; William Smith 2013-02-01 EGS using CO2 as a working fluid will likely involve hydro-shearing low-permeability hot rock reservoirs with a water solution. After that process, the fractures will be flushed with CO2 that is maintained under supercritical conditions (> 70 bars). Much of the injected water in the main fracture will be flushed out with the initial CO2 injection; however side fractures, micro fractures, and the lower portion of the fracture will contain connate water that will interact with the rock and the injected CO2. Dissolution/precipitation reactions in the resulting scCO2/brine/rock systems have the potential to significantly alter reservoir permeability, so it ismore » important to understand where these precipitates form and how are they related to the evolving ‘free’ connate water in the system. To examine dissolution / precipitation behavior in such systems over time, we have conducted non-stirred batch experiments in the laboratory with pure minerals, sandstone, and basalt coupons with brine solution spiked with MnCl2 and scCO2. The coupons are exposed to liquid water saturated with scCO2 and extend above the water surface allowing the upper portion of the coupons to be exposed to scCO2 saturated with water. The coupons were subsequently analyzed using SEM to determine the location of reactions in both in and out of the liquid water. Results of these will be summarized with regard to significance for EGS with CO2 as a working fluid.« less </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_13");'>13</a></li> <li><a href="#" onclick='return showDiv("page_14");'>14</a></li> <li class="active">15</li> <li><a href="#" onclick='return showDiv("page_16");'>16</a></li> <li><a href="#" onclick='return showDiv("page_17");'>17</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_16" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_14");'>14</a></li> <li><a href="#" onclick='return showDiv("page_15");'>15</a></li> <li class="active">16</li> <li><a href="#" onclick='return showDiv("page_17");'>17</a></li> <li><a href="#" onclick='return showDiv("page_18");'>18</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="301"> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2006TellB..58...73W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2006TellB..58...73W">The role of Southern Ocean mixing and upwelling in glacial-interglacial atmospheric CO2 change</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Watson, Andrew J.; Naveira Garabato, Alberto C. 2006-02-01 Decreased ventilation of the Southern Ocean in glacial time is implicated in most explanations of lower glacial atmospheric CO2. Today, the deep (>2000 m) ocean south of the Polar Front is rapidly ventilated from below, with the interaction of deep currents with topography driving high mixing rates well up into the water column. We show from a buoyancy budget that mixing rates are high in all the deep waters of the Southern Ocean. Between the surface and ~2000 m depth, water is upwelled by a residual meridional overturning that is directly linked to buoyancy fluxes through the ocean surface. Combined with the rapid deep mixing, this upwelling serves to return deep water to the surface on a short time scale. We propose two new mechanisms by which, in glacial time, the deep Southern Ocean may have been more isolated from the surface. Firstly, the deep ocean appears to have been more stratified because of denser bottom water resulting from intense sea ice formation near Antarctica. The greater stratification would have slowed the deep mixing. Secondly, subzero atmospheric temperatures may have meant that the present-day buoyancy flux from the atmosphere to the ocean surface was reduced or reversed. This in turn would have reduced or eliminated the upwelling (contrary to a common assumption, upwelling is not solely a function of the wind stress but is coupled to the air-sea buoyancy flux too). The observed very close link between Antarctic temperatures and atmospheric CO2 could then be explained as a natural consequence of the connection between the air-sea buoyancy flux and upwelling in the Southern Ocean, if slower ventilation of the Southern Ocean led to lower atmospheric CO2. Here we use a box model, similar to those of previous authors, to show that weaker mixing and reduced upwelling in the Southern Ocean can explain the low glacial atmospheric CO2 in such a formulation. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018CSR...152...14Z','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018CSR...152...14Z">Air-sea heat flux control on the Yellow Sea Cold Water Mass intensity and implications for its prediction</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Zhu, Junying; Shi, Jie; Guo, Xinyu; Gao, Huiwang; Yao, Xiaohong 2018-01-01 The Yellow Sea Cold Water Mass (YSCWM), which occurs during summer in the central Yellow Sea, plays an important role in the hydrodynamic field, nutrient cycle and biological species. Based on water temperature observations during the summer from 1978 to 1998 in the western Yellow Sea, five specific YSCWM years were identified, including two strong years (1984 and 1985), two weak years (1989 and 1995) and one normal year (1992). Using a three-dimensional hydrodynamic model, the YSCWM formation processes in these five years were simulated and compared with observations. In general, the YSCWM began forming in spring, matured in summer and gradually disappeared in autumn of every year. The 8 °C isotherm was used to indicate the YSCWM boundary. The modelled YSCWM areas in the two strong years were approximately two times larger than those in the two weak years. Based on the simulations in the weak year of 1995, ten numerical experiments were performed to quantify the key factors influencing the YSCWM intensity by changing the initial water condition in the previous autumn, air-sea heat flux, wind, evaporation, precipitation and sea level pressure to those in the strong year of 1984, respectively. The results showed that the air-sea heat flux was the dominant factor influencing the YSCWM intensity, which contributed about 80% of the differences of the YSCWM average water temperature at a depth of 50 m. In addition, the air-sea heat flux in the previous winter had a determining effect, contributing more than 50% of the differences between the strong and weak YSCWM years. Finally, a simple formula for predicting the YSCWM intensity was established by using the key influencing factors, i.e., the sea surface temperature before the cooling season and the air-sea heat flux during the cooling season from the previous December to the current February. With this formula, instead of a complicated numerical model, we were able to roughly predict the YSCWM intensity for the </li> <li> <a target="_blank" onclick="trackOutboundLink('http://hdl.handle.net/2060/20010023281','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20010023281">BOREAS TF-11 CO2 and CH4 Flux Data from the SSA-Fen</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Valentine, David W.; Hall, Forrest G. (Editor); Conrad, Sara (Editor) 2000-01-01 The BOREAS TF-11 team collected several data sets in its efforts to fully describe the flux and site characteristics at the SSA-Fen site. This data set contains fluxes of methane and carbon dioxide at the SSA-Fen site measured using static chambers. The measurements were conducted as part of a 2 x 2 factorial experiment in which we added carbon (300 g/sq m as wheat straw) and nitrogen (6 g/sq m as urea) to four replicate locations in the vicinity of the TF-11 tower. In addition to siting and treatment variables, it reports air temperature and water table height relative to the average peat surface during each measurement. The data set covers the period from the first week of June 1994 through the second week of September 1994. The data are stored in tabular ASCII files. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.fs.usda.gov/treesearch/pubs/13467','TREESEARCH'); return false;" href="https://www.fs.usda.gov/treesearch/pubs/13467">Temporal and spatial trends of fluxes and concentrations of CO2 above and within the canopy at Howland, Maine: preliminary results</a> <a target="_blank" href="http://www.fs.usda.gov/treesearch/">Treesearch</a> S. M. Goltz 1996-01-01 In order to develop and evaluate models of net carbon exchange, we have collected profiles of CO2 through and above the canopy for extended periods over three years as well as collected short-term trial data of diurnal CO2, water vapor, and sensible heat fluxes above the canopy as measured by eddy correlation. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=340834&Lab=NHEERL&keyword=Change+AND+climate&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=340834&Lab=NHEERL&keyword=Change+AND+climate&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">Nitrous oxide flux under changing temperature and CO2</a> <a target="_blank" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> We are investigating nitrous oxide flux seasonal trends and response to temperature and CO2 increases in a boreal peatland. Peatlands located in boreal regions make up a third of global wetland area and are expected to have the highest temperature increases in response to climat... </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/biblio/1306691-direct-capture-co2-from-ambient-air','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/1306691-direct-capture-co2-from-ambient-air">Direct capture of CO 2 from ambient air</a> <a target="_blank" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Sanz-Perez, Eloy S.; Murdock, Christopher R.; Didas, Stephanie A. The increase in the global atmospheric CO 2 concentration resulting from over a century of combustion of fossil fuels has been associated with significant global climate change. With the global population increase driving continued increases in fossil fuel use, humanity’s primary reliance on fossil energy for the next several decades is assured. Traditional modes of carbon capture such as precombustion and postcombustion CO 2 capture from large point sources can help slow the rate of increase of the atmospheric CO 2 concentration, but only the direct removal of CO 2 from the air, or “direct air capture” (DAC), can actuallymore » reduce the global atmospheric CO 2 concentration. The past decade has seen a steep rise in the use of chemical sorbents that are cycled through sorption and desorption cycles for CO 2 removal from ultradilute gases such as air. This Review provides a historical overview of the field of DAC, along with an exhaustive description of the use of chemical sorbents targeted at this application. Solvents and solid sorbents that interact strongly with CO 2 are described, including basic solvents, supported amine and ammonium materials, and metal-organic frameworks (MOFs), as the primary classes of chemical sorbents. Hypothetical processes for the deployment of such sorbents are discussed, as well as the limited array of technoeconomic analyses published on DAC. Overall, it is concluded that there are many new materials that could play a role in emerging DAC technologies. Furthermore, these materials need to be further investigated and developed with a practical sorbent-air contacting process in mind if society is to make rapid progress in deploying DAC as a means of mitigating climate change.« less </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1306691-direct-capture-co2-from-ambient-air','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1306691-direct-capture-co2-from-ambient-air">Direct capture of CO 2 from ambient air</a> <a target="_blank" href="http://www.osti.gov/pages">DOE PAGES</a> Sanz-Perez, Eloy S.; Murdock, Christopher R.; Didas, Stephanie A.; ... 2016-08-25 The increase in the global atmospheric CO 2 concentration resulting from over a century of combustion of fossil fuels has been associated with significant global climate change. With the global population increase driving continued increases in fossil fuel use, humanity’s primary reliance on fossil energy for the next several decades is assured. Traditional modes of carbon capture such as precombustion and postcombustion CO 2 capture from large point sources can help slow the rate of increase of the atmospheric CO 2 concentration, but only the direct removal of CO 2 from the air, or “direct air capture” (DAC), can actuallymore » reduce the global atmospheric CO 2 concentration. The past decade has seen a steep rise in the use of chemical sorbents that are cycled through sorption and desorption cycles for CO 2 removal from ultradilute gases such as air. This Review provides a historical overview of the field of DAC, along with an exhaustive description of the use of chemical sorbents targeted at this application. Solvents and solid sorbents that interact strongly with CO 2 are described, including basic solvents, supported amine and ammonium materials, and metal-organic frameworks (MOFs), as the primary classes of chemical sorbents. Hypothetical processes for the deployment of such sorbents are discussed, as well as the limited array of technoeconomic analyses published on DAC. Overall, it is concluded that there are many new materials that could play a role in emerging DAC technologies. Furthermore, these materials need to be further investigated and developed with a practical sorbent-air contacting process in mind if society is to make rapid progress in deploying DAC as a means of mitigating climate change.« less </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.fs.usda.gov/treesearch/pubs/43522','TREESEARCH'); return false;" href="https://www.fs.usda.gov/treesearch/pubs/43522">High-frequency pressure variations in the vicinity of a surface CO2 flux chamber</a> <a target="_blank" href="http://www.fs.usda.gov/treesearch/">Treesearch</a> Eugene S. Takle; James R. Brandle; R. A. Schmidt; Rick Garcia; Irina V. Litvina; William J. Massman; Xinhua Zhou; Geoffrey Doyle; Charles W. Rice 2003-01-01 We report measurements of 2Hz pressure fluctuations at and below the soil surface in the vicinity of a surface-based CO2 flux chamber. These measurements were part of a field experiment to examine the possible role of pressure pumping due to atmospheric pressure fluctuations on measurements of surface fluxes of CO2. Under the moderate wind speeds, warm temperatures,... </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..1915402S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..1915402S">Results from twelve years of continuous monitoring of the soil CO2 flux at the Ketzin CO2 storage pilot site, Germany</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Szizybalski, Alexandra; Zimmer, Martin; Pilz, Peter; Liebscher, Axel 2017-04-01 Under the coordination of the GFZ German Research Centre for Geosciences the complete life-cycle of a geological storage site for CO2 has been investigated and studied in detail over the past 12 years at Ketzin near Berlin, Germany. The test site is located at the southern flank of an anticlinal structure. Beginning with an exploration phase in 2004, drilling of the first three wells took place in 2007. From June 2008 to August 2013 about 67 kt of CO2 were injected into Upper Triassic sandstones at a depth of 630 to 650 m overlain by more than 165 m of shaley cap rocks. A comprehensive operational and scientific monitoring program forms the central part of the Ketzin project targeting at the reservoir itself, its overburden or above-zone and the surface. The surface monitoring is done by continuous soil CO2 flux measurements. These already started in 2005, more than three years prior to the injection phase using a survey chamber from LI-COR Inc. Twenty sampling locations were selected in the area of the anticline covering about 3 x 3 km. In order to obtain information on seasonal trends, measurements are performed at least once a month. The data set obtained prior to the injection serves as a basis for comparison with all further measurements during the injection and storage operations [Zimmer et al., 2010]. To refine the monitoring network, eight automatic, permanent soil CO2 flux stations were additionally installed in 2011 in the direct vicinity of the boreholes. Using this system, the CO2 soil flux is measured on an hourly basis. Over the whole monitoring time, soil temperature and moisture are recorded simultaneously and soil samples down to 70 cm depth were studied for their structure, carbon and nitrogen content. ver the whole monitoring time. Both, diurnal and seasonal flux variations can be detected and hence, provide a basis for interpretation of the measured data. Detailed analysis of the long-term monitoring at each station clearly reveals the influence </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=1080961','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=1080961">Relationships between the Efficiencies of Photosystems I and II and Stromal Redox State in CO2-Free Air 1</a> <a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Harbinson, Jeremy; Foyer, Christine H. 1991-01-01 The responses of the efficiencies of photosystems I and II, stromal redox state (as indicated by NADP-malate dehydrogenase activation state), and activation of the Benson-Calvin cycle enzymes ribulose 1,5-bisphosphate carboxylase and fructose 1,6-bisphosphatase to varying irradiance were measured in pea (Pisum sativum L.) leaves operating close to the CO2 compensation point. A comparison of the relationships among these parameters obtained from leaves in air was made with those obtained when the leaves were maintained in air from which the CO2 had been removed. P700 was more oxidized at any measured irradiance in CO2-free air than in air. The relationship between the quantum efficiencies of the photosystems in CO2-free air was distinctly curvilinear in contrast to the predominantly linear relationship obtained with leaves in air. This nonlinearity may be consistent with the operation of cyclic electron flow around photosystem I because the quantum efficiency of photosystem II was much more restricted than the quantum efficiency of photosystem I. In CO2-free air, measured NADP-malate dehydrogenase activities varied considerably at low irradiances. However, at high irradiance the activity of the enzyme was low, implying that the stroma was oxidized. In contrast, fructose-1,6-bisphosphatase activities tended to increase with increasing electron flux through the photosystems. Ribulose-1,5-bisphosphate carboxylase activity remained relatively constant with respect to irradiance in CO2-free air, with an activation state 50% of maximum. We conclude that, at the CO2 compensation point and high irradiance, low redox states are favored and that cyclic electron flow may be substantial. These two features may be the requirements necessary to trigger and maintain the dissipative processes in the thylakoid membrane. PMID:16668401 </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3251141','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3251141">Economic and energetic analysis of capturing CO2 from ambient air</a> <a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> House, Kurt Zenz; Baclig, Antonio C.; Ranjan, Manya; van Nierop, Ernst A.; Wilcox, Jennifer; Herzog, Howard J. 2011-01-01 Capturing carbon dioxide from the atmosphere (“air capture”) in an industrial process has been proposed as an option for stabilizing global CO2 concentrations. Published analyses suggest these air capture systems may cost a few hundred dollars per tonne of CO2, making it cost competitive with mainstream CO2 mitigation options like renewable energy, nuclear power, and carbon dioxide capture and storage from large CO2 emitting point sources. We investigate the thermodynamic efficiencies of commercial separation systems as well as trace gas removal systems to better understand and constrain the energy requirements and costs of these air capture systems. Our empirical analyses of operating commercial processes suggest that the energetic and financial costs of capturing CO2 from the air are likely to have been underestimated. Specifically, our analysis of existing gas separation systems suggests that, unless air capture significantly outperforms these systems, it is likely to require more than 400 kJ of work per mole of CO2, requiring it to be powered by CO2-neutral power sources in order to be CO2 negative. We estimate that total system costs of an air capture system will be on the order of $1,000 per tonne of CO2, based on experience with as-built large-scale trace gas removal systems. PMID:22143760 </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013ACP....13.7607C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013ACP....13.7607C">Improved simulation of regional CO2 surface concentrations using GEOS-Chem and fluxes from VEGAS</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Chen, Z. H.; Zhu, J.; Zeng, N. 2013-08-01 CO2 measurements have been combined with simulated CO2 distributions from a transport model in order to produce the optimal estimates of CO2 surface fluxes in inverse modeling. However, one persistent problem in using model-observation comparisons for this goal relates to the issue of compatibility. Observations at a single station reflect all underlying processes of various scales. These processes usually cannot be fully resolved by model simulations at the grid points nearest the station due to lack of spatial or temporal resolution or missing processes in the model. In this study the stations in one region were grouped based on the amplitude and phase of the seasonal cycle at each station. The regionally averaged CO2 at all stations in one region represents the regional CO2 concentration of this region. The regional CO2 concentrations from model simulations and observations were used to evaluate the regional model results. The difference of the regional CO2 concentration between observation and modeled results reflects the uncertainty of the large-scale flux in the region where the grouped stations are. We compared the regional CO2 concentrations between model results with biospheric fluxes from the Carnegie-Ames-Stanford Approach (CASA) and VEgetation-Global-Atmosphere-Soil (VEGAS) models, and used observations from GLOBALVIEW-CO2 to evaluate the regional model results. The results show the largest difference of the regionally averaged values between simulations with fluxes from VEGAS and observations is less than 5 ppm for North American boreal, North American temperate, Eurasian boreal, Eurasian temperate and Europe, which is smaller than the largest difference between CASA simulations and observations (more than 5 ppm). There is still a large difference between two model results and observations for the regional CO2 concentration in the North Atlantic, Indian Ocean, and South Pacific tropics. The regionally averaged CO2 concentrations will be helpful for </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2009AGUFM.C43B0498M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2009AGUFM.C43B0498M">CO2 flux monitoring using Continuous Timeseries-Forced Diffusion (CT-FD): Development, Validation</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> McArthur, G. S.; Risk, D. A.; Nickerson, N. R.; Creelman, C. A.; Beltrami, H. 2009-12-01 Land-based CO2 flux measurements are a key indicator of the biological, chemical and physical processes occurring in the soil. While highly dense temporal flux measurements can be acquired using Eddy Covariance towers, or flux chambers, the challenge of gathering data that is rich both temporally and spatially persists. Over the past two years we have developed a new technique for measuring soil CO2 fluxes, called continuous timeseries-forced diffusion (CT-FD) attempts to satisfy the need for spatially and temporally rich data. The CT-FD probe consists of a Vaisala CO2 sensor, embodied in a PVC casing, with tear/UV resistant Tyvek membranes at both the inlet and outlet. The probe delivers continuous flux data and can be inexpensively replicated across the landscape.The CT-FD technique works by forcing a known diffusive regime between the soil and the atmosphere, allowing the calculation of fluxes across the soil/atmosphere boundary to be made from; the internal concentration of a CT-FD probe placed at the soil surface; and a common reference probe designed to capture the atmospheric CO2. For every concentration measurement, the difference between the probe and the reference concentration is indicative of a unique flux value. Here we examine properties of the instrument and method, as documented by a long series of developmental studies involving numerical gas transport modeling, laboratory and field experiments. A suite of 1D and 3D modeling experiments were needed to optimize embodiment and geometries of the probe. These show that the probe should have a relatively long collar, with relatively high diffusivity made possible by having large, highly diffusive membranes, both of which help to induce 1D movement of gases into the probe and reduce the lateral diffusion around the probe. Modeling also shows that correction for lateral diffusion is feasible. As for error, sensor error transfers linearly to errors in the flux, and that the sensor can be used in non free </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/1996AnGeo..14..342S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/1996AnGeo..14..342S">Seasonal change in CO2 and H2O exchange between grassland and atmosphere</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Saigusa, N.; Liu, S.; Oikawa, T.; Watanabe, T. 1996-03-01 The seasonal change in CO2 flux over an artificial grassland was analyzed from the ecological and meteorological point of view. This grassland contains C3 and C4 plants; the three dominant species belonging to the Gramineae; Festuca elatior (C3) dominated in early spring, and Imperata cylindrica (C4) and Andropogon virginicus (C4) grew during early summer and became dominant in mid-summer. CO2 flux was measured by the gradient method, and the routinely observed data for the surface-heat budget were used to analyze the CO2 and H2O exchange between the grassland and atmosphere. From August to October in 1993, CO2 flux was reduced to around half under the same solar-radiation conditions, while H2O flux decreased 20% during the same period. The monthly values of water use efficiency, i.e., ratio of CO2 flux to H2O flux decreased from 5.8 to 3.3 mg CO2/g H2O from August to October, the Bowen ratio increased from 0.20 to 0.30, and the ratio of the bulk latent heat transfer coefficient CE to the sensible heat transfer coefficient CH was maintained around 0.40-0.50. The increase in the Bowen ratio was explained by the decrease in air temperature from 22.3 °C in August to 16.6 °C in October without considering biological effects such as stomatal closure on the individual leaves. The nearly constant CE/CH ratios suggested that the contribution ratio of canopy resistance to aerodynamic resistance did not change markedly, although the meteorological conditions changed seasonally. The decrease in the water use efficiency, however, suggested that the photosynthetic rate decreased for individual leaves from August to October under the same radiation conditions. Diurnal variations of CO2 exchange were simulated by the multi-layer canopy model taking into account the differences in the stomatal conductance and photosynthetic pathway between C3 and C4 plants. The results suggested that C4 plants played a major role in the CO2 exchange in August, the contribution of C4 plants </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/22066218','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/22066218">Forest soil CO2 fluxes as a function of understory removal and N-fixing species addition.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Li, Haifang; Fu, Shenglei; Zhao, Hongting; Xia, Hanping 2011-01-01 We report on the effects of forest management practices of understory removal and N-fixing species (Cassia alata) addition on soil CO2 fluxes in an Eucalyptus urophylla plantation (EUp), Acacia crassicarpa plantation (ACp), 10-species-mixed plantation (Tp), and 30-species-mixed plantation (THp) using the static chamber method in southern China. Four forest management treatments, including (1) understory removal (UR); (2) C. alata addition (CA); (3) understory removal and replacement with C. alata (UR+CA); and (4) control without any disturbances (CK), were applied in the above four forest plantations with three replications for each treatment. The results showed that soil CO2 fluxes rates remained at a high level during the rainy season (from April to September), followed by a rapid decrease after October reaching a minimum in February. Soil CO2 fluxes were significantly higher (P < 0.01) in EUp (132.6 mg/(m2 x hr)) and ACp (139.8 mg/(m2 x hr)) than in Tp (94.0 mg/(m2 x hr)) and THp (102.9 mg/(m2 x hr)). Soil CO2 fluxes in UR and CA were significantly higher (P < 0.01) among the four treatments, with values of 105.7, 120.4, 133.6 and 112.2 mg/(m2 x hr) for UR+CA, UR, CA and CK, respectively. Soil CO2 fluxes were positively correlated with soil temperature (P < 0.01), soil moisture (P < 0.01), NO3(-)-N (P < 0.05), and litterfall (P < 0.01), indicating that all these factors might be important controlling variables for soil CO2 fluxes. This study sheds some light on our understanding of soil CO2 flux dynamics in forest plantations under various management practices. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/1998WRR....34.3245B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/1998WRR....34.3245B">Air sparging: Air-water mass transfer coefficients</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Braida, Washington J.; Ong, Say Kee 1998-12-01 Experiments investigating the mass transfer of several dissolved volatile organic compounds (VOCs) across the air-water interface were conducted using a single-air- channel air-sparging system. Three different porous media were used in the study. Air velocities ranged from 0.2 cm s-1 to 2.5 cm s-1. The tortuosity factor for each porous medium and the air-water mass transfer coefficients were estimated by fitting experimental data to a one-dimensional diffusion model. The estimated mass transfer coefficients KG ranged from 1.79 × 10-3 cm min-1 to 3.85 × 10-2 cm min-1. The estimated lumped gas phase mass transfer coefficients KGa were found to be directly related to the air diffusivity of the VOC, air velocity, and particle size, and inversely related to the Henry's law constant of the VOCs. Of the four parameters investigated, the parameter that controlled or had a dominant effect on the lumped gas phase mass transfer coefficient was the air diffusivity of the VOC. Two empirical models were developed by correlating the Damkohler and the modified air phase Sherwood numbers with the air phase Peclet number, Henry's law constant, and the reduced mean particle size of porous media. The correlation developed in this study may be used to obtain better predictions of mass transfer fluxes for field conditions. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=1080410','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=1080410">Growth Kinetics, Carbohydrate, and Leaf Phosphate Content of Clover (Trifolium subterraneum L.) after Transfer to a High CO2 Atmosphere or to High Light and Ambient Air 1</a> <a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Morin, Francoise; André, Marcel; Betsche, Thomas 1992-01-01 Intact air-grown (photosynthetic photon flux density, 400 microeinsteins per square meter per second) clover plants (Trifolium subterraneum L.) were transfered to high CO2 (4000 microliters CO2 per liter; photosynthetic photon flux density, 400 microeinsteins per square meter per second) or to high light (340 microliters CO2 per liter; photosynthetic photon flux density, 800 microeinsteins per square meter per second) to similarly stimulate photosynthetic net CO2 uptake. The daily increment of net CO2 uptake declined transiently in high CO2, but not in high light, below the values in air/standard light. After about 3 days in high CO2, the daily increment of net CO2 uptake increased but did not reach the high light values. Nightly CO2 release increased immediately in high light, whereas there was a 3-day lag phase in high CO2. During this time, starch accumulated to a high level, and leaf deterioration was observed only in high CO2. After 12 days, starch was two- to threefold higher in high CO2 than in high light, whereas sucrose was similar. Leaf carbohydrates were determined during the first and fourth day in high CO2. Starch increased rapidly throughout the day. Early in the day, sucrose was low and similar in high CO2 and ambient air (same light). Later, sucrose increased considerably in high CO2. The findings that (a) much more photosynthetic carbon was partitioned into the leaf starch pool in high CO2 than in high light, although net CO2 uptake was similar, and that (b) rapid starch formation occurred in high CO2 even when leaf sucrose was only slightly elevated suggest that low sink capacity was not the main constraint in high CO2. It is proposed that carbon partitioning between starch (chloroplast) and sucrose (cytosol) was perturbed by high CO2 because of the lack of photorespiration. Total phosphate pools were determined in leaves. Concentrations based on fresh weight of orthophosphate, soluble esterified phosphate, and total phosphate markedly declined </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AtmRe.164..328D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AtmRe.164..328D">Fog chemical composition and its feedback to fog water fluxes, water vapor fluxes, and microphysical evolution of two events near Paris</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Degefie, D. T.; El-Madany, T.-S.; Held, M.; Hejkal, J.; Hammer, E.; Dupont, J.-C.; Haeffelin, M.; Fleischer, E.; Klemm, O. 2015-10-01 The chemical composition of collected fog water and its temporal evolution was studied during the PARISFOG campaign in winter 2012/2013 at the SIRTA (Site Instrumental de Recherche par Télédétection Atmosphéric) atmospheric observatory outside Paris, France. A further development of the caltech active fog collector was applied, in which the collected fog water gets into contact with Teflon and polyether ether ketone (PEEK) material exclusively. The collector was operational whenever the visibility was below 1000 m. In addition, the turbulent and gravitational fluxes of fog water and water vapor flux were used to examine in detail the temporal evolution the chemical composition of two fogs. The technique was applied to two fog events, one representing a radiation fog and the other one representing a stratus lowering fog. The result revealed that the dominant inorganic species in the fog water were NH4+, NO3-, Ca2 + and SO42 -, which accounted for more than 85% of the ion balance. The pH ranged from 3.7 to 6.2. In the evolution the two fog events, the interaction among the turbulent fog water flux, gravitational fog water flux and water vapor flux controlled the major ion loads (amount of ions, dissolved in fog droplets per volume of air) and ion concentrations (amount dissolved per volume of liquid water) of the fog water. In the radiation fog event, an increase of ion loads and ion concentrations occurred when the direction of water vapor flux towards to the place where the condensation process occurred. A decrease of ion loads and ion concentrations mainly happened by gravitational fog water flux with a minor contribution from turbulent fog water flux. However, when the turbulent water vapor flux was oriented downward, it turned the turbulent fog water flux upward and offset the removal of ions in the fog. In the stratus lowering fog event, the turbulent fog water flux and the gravitational water flux together mainly contributed to the fog water deposition and </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..19.9924L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..19.9924L">Soil methane and CO2 fluxes in rainforest and rubber plantations</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Lang, Rong; Blagodatsky, Sergey; Goldberg, Stefanie; Xu, Jianchu 2017-04-01 Expansion of rubber plantations in South-East Asia has been a land use transformation trend leading to losses of natural forest cover in the region. Besides impact on ecosystem carbon stocks, this conversion influences the dynamics of greenhouse gas fluxes from soil driven by microbial activity, which has been insufficiently studied. Aimed to understand how land use change affects the soil CO2 and CH4 fluxes, we measured surface gas fluxes, gas concentration gradient, and 13C signature in CH4 and soil organic matter in profiles in a transect in Xishuangbanna, including a rainforest site and three rubber plantation sites with age gradient. Gas fluxes were measured by static chamber method and open chamber respiration system. Soil gases were sampled from installed gas samplers at 5, 10, 30, and 75cm depth at representative time in dry and rainy season. The soil CO2 flux was comparable in rainforest and old rubber plantations, while young rubber plantation had the lowest rate. Total carbon content in the surface soil well explained the difference of soil CO2 flux between sites. All sites were CH4 sinks in dry season and uptake decreased in the order of rainforest, old rubber plantations and young rubber plantation. From dry season to rainy season, CH4 consumption decreased with increasing CH4 concentration in the soil profile at all depths. The enrichment of methane by 13CH4 shifted towards to lowerδ13C, being the evidence of enhanced CH4 production process while net surface methane flux reflected the consumption in wet condition. Increment of CH4 concentration in the profile from dry to rainy season was higher in old rubber plantation compared to rainforest, while the shifting of δ13CH4 was larger in rainforest than rubber sites. Turnover rates of soil CO2 and CH4 suggested that the 0-5 cm surface soil was the most active layer for gaseous carbon exchange. δ13C in soil organic matter and soil moisture increased from rainforest, young rubber plantation to old </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017BGeo...14.4781U','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017BGeo...14.4781U">CO2 efflux from soils with seasonal water repellency</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Urbanek, Emilia; Doerr, Stefan H. 2017-10-01 Soil carbon dioxide (CO2) emissions are strongly dependent on pore water distribution, which in turn can be modified by reduced wettability. Many soils around the world are affected by soil water repellency (SWR), which reduces infiltration and results in diverse moisture distribution. SWR is temporally variable and soils can change from wettable to water-repellent and vice versa throughout the year. Effects of SWR on soil carbon (C) dynamics, and specifically on CO2 efflux, have only been studied in a few laboratory experiments and hence remain poorly understood. Existing studies suggest soil respiration is reduced with increasing severity of SWR, but the responses of soil CO2 efflux to varying water distribution created by SWR are not yet known.Here we report on the first field-based study that tests whether SWR indeed reduces soil CO2 efflux, based on in situ measurements carried out over three consecutive years at a grassland and pine forest sites under the humid temperate climate of the UK.Soil CO2 efflux was indeed very low on occasions when soil exhibited consistently high SWR and low soil moisture following long dry spells. Low CO2 efflux was also observed when SWR was absent, in spring and late autumn when soil temperatures were low, but also in summer when SWR was reduced by frequent rainfall events. The highest CO2 efflux occurred not when soil was wettable, but when SWR, and thus soil moisture, was spatially patchy, a pattern observed for the majority of the measurement period. Patchiness of SWR is likely to have created zones with two different characteristics related to CO2 production and transport. Zones with wettable soil or low persistence of SWR with higher proportion of water-filled pores are expected to provide water with high nutrient concentration resulting in higher microbial activity and CO2 production. Soil zones with high SWR persistence, on the other hand, are dominated by air-filled pores with low microbial activity, but facilitating O2 </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_14");'>14</a></li> <li><a href="#" onclick='return showDiv("page_15");'>15</a></li> <li class="active">16</li> <li><a href="#" onclick='return showDiv("page_17");'>17</a></li> <li><a href="#" onclick='return showDiv("page_18");'>18</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_17" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_15");'>15</a></li> <li><a href="#" onclick='return showDiv("page_16");'>16</a></li> <li class="active">17</li> <li><a href="#" onclick='return showDiv("page_18");'>18</a></li> <li><a href="#" onclick='return showDiv("page_19");'>19</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="321"> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.A33G2447M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.A33G2447M">High-resolution CO2 and CH4 flux inverse modeling combining GOSAT, OCO-2 and ground-based observations</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Maksyutov, S. S.; Oda, T.; Saito, M.; Ito, A.; Janardanan Achari, R.; Sasakawa, M.; Machida, T.; Kaiser, J. W.; Belikov, D.; Valsala, V.; O'Dell, C.; Yoshida, Y.; Matsunaga, T. 2017-12-01 We develop a high-resolution CO2 and CH4 flux inversion system that is based on the Lagrangian-Eulerian coupled tracer transport model, and is designed to estimate surface fluxes from atmospheric CO2 and CH4 data observed by the GOSAT and OCO-2 satellites and by global in-situ networks, including observation in Siberia. We use the Lagrangian particle dispersion model (LPDM) FLEXPART to estimate the surface flux footprints for each observation at 0.1-degree spatial resolution for three days of transport. The LPDM is coupled to a global atmospheric tracer transport model (NIES-TM). The adjoint of the coupled transport model is used in an iterative optimization procedure based on either quasi-Newtonian algorithm or singular value decomposition. Combining surface and satellite data for use in inversion requires correcting for biases present in satellite observation data, that is done in a two-step procedure. As a first step, bi-weekly corrections to prior flux fields are estimated for the period of 2009 to 2015 from in-situ CO2 and CH4 data from global observation network, included in Obspack-GVP (for CO2), WDCGG (CH4) and JR-STATION datasets. High-resolution prior fluxes were prepared for anthropogenic emissions (ODIAC and EDGAR), biomass burning (GFAS), and the terrestrial biosphere. The terrestrial biosphere flux was constructed using a vegetation mosaic map and separate simulations of CO2 fluxes by the VISIT model for each vegetation type present in a grid. The prior flux uncertainty for land is scaled proportionally to monthly mean GPP by the MODIS product for CO2 and EDGAR emissions for CH4. Use of the high-resolution transport leads to improved representation of the anthropogenic plumes, often observed at continental continuous observation sites. OCO-2 observations are aggregated to 1 second averages, to match the 0.1 degree resolution of the transport model. Before including satellite observations in the inversion, the monthly varying latitude-dependent bias is </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/biblio/96050-influence-water-table-carbon-dioxide-carbon-monoxide-methane-fluxes-from-taiga-bog-microcosms','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/96050-influence-water-table-carbon-dioxide-carbon-monoxide-methane-fluxes-from-taiga-bog-microcosms">Influence of water table on carbon dioxide, carbon monoxide, and methane fluxes from taiga bog microcosms</a> <a target="_blank" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Funk, D.W.; Pullmann, E.R.; Peterson, K.M. 1994-09-01 Hydrological changes, particularly alterations in water table level, may largely overshadow the more direct effects of global temperature increase upon carbon cycling in arctic and subarctic wetlands. Frozen cores (n=40) of intact soils and vegetation were collected from a bog near Fairbanks, Alaska, and fluxes of CO{sub 2}, CH{sub 4}, and Co in response to water table variation were studied under controlled conditions in the Duke University phytotron. Core microcosms thawed to a 20-cm depth over 30 days under a 20 hour photoperiod with a day/night temperature regime of 20/10{degrees}C. After 30 days the water table in 20 microcosms wasmore » decreased from the soil surface to -15 cm and maintained at the soil surface in 20 control cores. Outward fluxes of CO{sub 2} (9-16 g m{sup -2}d{sup -1}) and CO (3-4 mg m{sup -2}d{sup -1}) were greatest during early thaw and decreased to near zero for both gases before the water table treatment started. Lower water table tripled CO{sub 2} flux to the atmosphere when compared with control cores. Carbon monoxide was emitted at low rates from high water table cores and consumed by low water table cores. Methane fluxes were low (<1 mg m{sup -2}d{sup -1}) in all cores during thaw. High water table cores increased CH{sub 4} flux to 8-9 mg m{sup -2}d{sup -1} over 70 days and remained high relative to the low water table cores (<0.74 mg m{sup -2}d{sup -1}). Although drying of wetland taiga soils may decrease CH{sub 4} emissions to the atmosphere, the associated increase in CO{sub 2} due to aerobic respiration will likely increase the global warming potential of gas emissions from these soils. 43 refs., 4 figs.« less </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.fs.usda.gov/treesearch/pubs/39384','TREESEARCH'); return false;" href="https://www.fs.usda.gov/treesearch/pubs/39384">Do plant species influence soil CO2 and N2O fluxes in a diverse tropical forest?</a> <a target="_blank" href="http://www.fs.usda.gov/treesearch/">Treesearch</a> J.L.M. van Haren; R.C. de Oliveira; N. Restrepo-Coupe; L. Hutyra; P. B. de Camargo; Michael Keller; S.R. Saleska 2010-01-01 [1] To test whether plant species influence greenhouse gas production in diverse ecosystems, we measured wet season soil CO2 and N2O fluxes close to 300 large (>35 cm in diameter at breast height (DBH)) trees of 15 species at three clayârich forest sites in central Amazonia. We found that soil CO2 fluxes were 38% higher near large trees than at control sites >10... </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012EGUGA..14.4933P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012EGUGA..14.4933P">Growth strategy of Norway spruce under air elevated [CO2</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Pokorny, R.; Urban, O.; Holisova, P.; Sprtova, M.; Sigut, L.; Slipkova, R. 2012-04-01 Plants will respond to globally increasing atmospheric CO2 concentration ([CO2]) by acclimation or adaptation at physiological and morphological levels. Considering the temporal onset, physiological responses may be categorized as short-term and morphological ones as long-term responses. The degree of plant growth responses, including cell division and cell expansion, is highly variable. It depends mainly on the specie's genetic predisposition, environment, mineral nutrition status, duration of CO2 enrichment, and/or synergetic effects of other stresses. Elevated [CO2] causes changes in tissue anatomy, quantity, size, shape and spatial orientation and can result in altered sink strength. Since, there are many experimental facilities for the investigation of elevated [CO2] effects on trees: i) closed systems or open top chambers (OTCs), ii) semi-open systems (for example glass domes with adjustable lamella windows - DAWs), and iii) free-air [CO2] enrichments (FACE); the results are still unsatisfactory due to: i) relatively short-term duration of experiments, ii) cultivation of young plants with different growth strategy comparing to old ones, iii) plant cultivation under artificial soil and weather conditions, and iv) in non-representative stand structure. In this contribution we are discussing the physiological and morphological responses of Norway spruce trees cultivated in DAWs during eight consecutive growing seasons in the context with other results from Norway spruce cultivation under air-elevated [CO2] conditions. On the level of physiological responses, we discuss the changes in the rate of CO2 assimilation, assimilation capacity, photorespiration, dark respiration, stomatal conductance, water potential and transpiration, and the sensitivity of these physiological processes to temperature. On the level of morphological responses, we discuss the changes in bud and growth phenology, needle and shoot morphology, architecture of crown and root system, wood </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AGUFM.B51D0457D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AGUFM.B51D0457D">Comparing Amazon Basin CO2 fluxes from an atmospheric inversion with TRENDY biosphere models</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Diffenbaugh, N. S.; Alden, C. B.; Harper, A. B.; Ahlström, A.; Touma, D. E.; Miller, J. B.; Gatti, L. V.; Gloor, M. 2015-12-01 Net exchange of carbon dioxide (CO2) between the atmosphere and the terrestrial biosphere is sensitive to environmental conditions, including extreme heat and drought. Of particular importance for local and global carbon balance and climate are the expansive tracts of tropical rainforest located in the Amazon Basin. Because of the Basin's size and ecological heterogeneity, net biosphere CO2 exchange with the atmosphere remains largely un-constrained. In particular, the response of net CO2 exchange to changes in environmental conditions such as temperature and precipitation are not yet well known. However, proper representation of these relationships in biosphere models is a necessary constraint for accurately modeling future climate and climate-carbon cycle feedbacks. In an effort to compare biosphere response to climate across different biosphere models, the TRENDY model intercomparison project coordinated the simulation of CO2 fluxes between the biosphere and atmosphere, in response to historical climate forcing, by 9 different Dynamic Global Vegetation Models. We examine the TRENDY model results in the Amazon Basin, and compare this "bottom-up" method with fluxes derived from a "top-down" approach to estimating net CO2 fluxes, obtained through atmospheric inverse modeling using CO2 measurements sampled by aircraft above the basin. We compare the "bottom-up" and "top-down" fluxes in 5 sub-regions of the Amazon basin on a monthly basis for 2010-2012. Our results show important periods of agreement between some models in the TRENDY suite and atmospheric inverse model results, notably the simulation of increased biosphere CO2 loss during wet season heat in the Central Amazon. During the dry season, however, model ability to simulate observed response of net CO2 exchange to drought was varied, with few models able to reproduce the "top-down" inversion flux signals. Our results highlight the value of atmospheric trace gas observations for helping to narrow the </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/23873747','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/23873747">Environmental controls of temporal and spatial variability in CO2 and CH4 fluxes in a neotropical peatland.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Wright, Emma L; Black, Colin R; Turner, Benjamin L; Sjögersten, Sofie 2013-12-01 Tropical peatlands play an important role in the global storage and cycling of carbon (C) but information on carbon dioxide (CO2) and methane (CH4) fluxes from these systems is sparse, particularly in the Neotropics. We quantified short and long-term temporal and small scale spatial variation in CO2 and CH4 fluxes from three contrasting vegetation communities in a domed ombrotrophic peatland in Panama. There was significant variation in CO2 fluxes among vegetation communities in the order Campnosperma panamensis > Raphia taedigera > Cyperus. There was no consistent variation among sites and no discernible seasonal pattern of CH4 flux despite the considerable range of values recorded (e.g. -1.0 to 12.6 mg m(-2) h(-1) in 2007). CO2 fluxes varied seasonally in 2007, being greatest in drier periods (300-400 mg m(-2) h(-1)) and lowest during the wet period (60-132 mg m(-2) h(-1)) while very high emissions were found during the 2009 wet period, suggesting that peak CO2 fluxes may occur following both low and high rainfall. In contrast, only weak relationships between CH4 flux and rainfall (positive at the C. panamensis site) and solar radiation (negative at the C. panamensis and Cyperus sites) was found. CO2 fluxes showed a diurnal pattern across sites and at the Cyperus sp. site CO2 and CH4 fluxes were positively correlated. The amount of dissolved carbon and nutrients were strong predictors of small scale within-site variability in gas release but the effect was site-specific. We conclude that (i) temporal variability in CO2 was greater than variation among vegetation communities; (ii) rainfall may be a good predictor of CO2 emissions from tropical peatlands but temporal variation in CH4 does not follow seasonal rainfall patterns; and (iii) diurnal variation in CO2 fluxes across different vegetation communities can be described by a Fourier model. © 2013 John Wiley & Sons Ltd. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2001AGUSM...B41A03D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2001AGUSM...B41A03D">Multiple Flux Footprints, Flux Divergences and Boundary Layer Mixing Ratios: Studies of Ecosystem-Atmosphere CO2 Exchange Using the WLEF Tall Tower.</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Davis, K. J.; Bakwin, P. S.; Yi, C.; Cook, B. D.; Wang, W.; Denning, A. S.; Teclaw, R.; Isebrands, J. G. 2001-05-01 Long-term, tower-based measurements using the eddy-covariance method have revealed a wealth of detail about the temporal dynamics of netecosystem-atmosphere exchange (NEE) of CO2. The data also provide a measure of the annual net CO2 exchange. The area represented by these flux measurements, however, is limited, and doubts remain about possible systematic errors that may bias the annual net exchange measurements. Flux and mixing ratio measurements conducted at the WLEF tall tower as part of the Chequamegon Ecosystem-Atmosphere Study (ChEAS) allow for unique assessment of the uncertainties in NEE of CO2. The synergy between flux and mixing ratio observations shows the potential for comparing inverse and eddy-covariance methods of estimating NEE of CO2. Such comparisons may strengthen confidence in both results and begin to bridge the huge gap in spatial scales (at least 3 orders of magnitude) between continental or hemispheric scale inverse studies and kilometer-scale eddy covariance flux measurements. Data from WLEF and Willow Creek, another ChEAS tower, are used to estimate random and systematic errors in NEE of CO2. Random uncertainty in seasonal exchange rates and the annual integrated NEE, including both turbulent sampling errors and variability in enviromental conditions, is small. Systematic errors are identified by examining changes in flux as a function of atmospheric stability and wind direction, and by comparing the multiple level flux measurements on the WLEF tower. Nighttime drainage is modest but evident. Systematic horizontal advection occurs during the morning turbulence transition. The potential total systematic error appears to be larger than random uncertainty, but still modest. The total systematic error, however, is difficult to assess. It appears that the WLEF region ecosystems were a small net sink of CO2 in 1997. It is clear that the summer uptake rate at WLEF is much smaller than that at most deciduous forest sites, including the nearby </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.B43D2148B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.B43D2148B">Assessing Near-surface Heat, Water Vapor and Carbon Dioxide Exchange Over a Coastal Salt-marsh</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Bogoev, I.; O'Halloran, T. L.; LeMoine, J. 2017-12-01 Coastal ecosystems play an important role in mitigating the effects of climate change by storing significant quantities of carbon. A growing number of studies suggest that vegetated estuarine habitats, specifically salt marshes, have high long-term rates of carbon sequestration, perhaps even higher than mature tropical and temperate forests. Large amounts of carbon, accumulated over thousands of years, are stored in the plant materials and sediment. Improved understanding of the factors that control energy and carbon exchange is needed to better guide restoration and conservation management practices. To that end, we recently established an observation system to study marsh-atmosphere interactions within the North Inlet-Winyah Bay National Estuarine Research Reserve. Near-surface fluxes of heat, water vapor (H2O) and carbon dioxide (CO2) were measured by an eddy-covariance system consisting of an aerodynamic open-path H2O / CO2 gas analyzer with a spatially integrated 3D sonic anemometer/thermometer (IRGASON). The IRGASON instrument provides co-located and highly synchronized, fast response H2O, CO2 and air- temperature measurements, which eliminates the need for spectral corrections associated with the separation between the sonic anemometer and the gas analyzer. This facilitates calculating the instantaneous CO2 molar mixing ratio relative to dry air. Fluxes computed from CO2 and H2O mixing ratios, which are conserved quantities, do not require post-processing corrections for air-density changes associated with temperature and water vapor fluctuations. These corrections are particularly important for CO2, because they could be even larger than the measured flux. Here we present the normalized frequency spectra of air temperature, water vapor and CO2, as well as their co-spectra with the co-located vertical wind. We also show mean daily cycles of sensible, latent and CO2 fluxes and analyze correlations with air/water temperature, wind speed and light availability. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29548413','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29548413">Effect of drainage on CO2, CH4, and N2O fluxes from aquaculture ponds during winter in a subtropical estuary of China.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Yang, Ping; Lai, Derrick Y F; Huang, Jia F; Tong, Chuan 2018-03-01 Aquaculture ponds are dominant features of the landscape in the coastal zone of China. Generally, aquaculture ponds are drained during the non-culture period in winter. However, the effects of such drainage on the production and flux of greenhouse gases (GHGs) from aquaculture ponds are largely unknown. In the present study, field-based research was performed to compare the GHG fluxes between one drained pond (DP, with a water depth of 0.05m) and one undrained pond (UDP, with a water depth of 1.16m) during one winter in the Min River estuary of southeast China. Over the entire study period, the mean CO 2 flux in the DP was (0.75±0.12) mmol/(m 2 ·hr), which was significantly higher than that in the UDP of (-0.49±0.09) mmol/(m 2 ·hr) (p<0.01). This indicates that drainage drastically transforms aquaculture ponds from a net sink to a net source of CO 2 in winter. Mean CH 4 and N 2 O emissions were significantly higher in the DP compared to those in the UDP (CH 4 =(0.66±0.31) vs. (0.07±0.06) mmol/(m 2 ·hr) and N 2 O=(19.54±2.08) vs. (0.01±0.04) µmol/(m 2 ·hr)) (p<0.01), suggesting that drainage would also significantly enhance CH 4 and N 2 O emissions. Changes in environmental variables (including sediment temperature, pH, salinity, redox status, and water depth) contributed significantly to the enhanced GHG emissions following pond drainage. Furthermore, analysis of the sustained-flux global warming and cooling potentials indicated that the combined global warming potentials of the GHG fluxes were significantly higher in the DP than in the UDP (p<0.01), with values of 739.18 and 26.46mgCO 2 -eq/(m 2 ·hr), respectively. Our findings suggested that drainage of aquaculture ponds can increase the emissions of potent GHGs from the coastal zone of China to the atmosphere during winter, further aggravating the problem of global warming. Copyright © 2017. Published by Elsevier B.V. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.A43C2464G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.A43C2464G">The use of fair-weather cases from the ACT-America Summer 2016 field campaign to better constrain regional biogenic CO2 surface fluxes</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Gaudet, B. J.; Davis, K. J.; DiGangi, J. P.; Feng, S.; Hoffman, K.; Jacobson, A. R.; Lauvaux, T.; McGill, M. J.; Miles, N.; Pal, S.; Pauly, R.; Richardson, S. 2017-12-01 The Atmospheric Carbon and Transport - America (ACT-America) study is a multi-year NASA-funded project designed to increase our understanding of regional-scale greenhouse gas (GHG) fluxes over North America through aircraft, satellite, and tower-based observations. This is being accomplished through a series of field campaigns that cover three focus regions (Mid-Atlantic, Gulf Coast, and Midwest), and all four seasons (summer, winter, fall, and spring), as well as a variety of meteorological conditions. While constraints on GHG fluxes can be derived on the global scale (through remote-site concentration measurements and global flux inversion models) and the local scale (through eddy-covariance flux tower measurements), observational constraints on the intermediate scales are not as readily available. Biogenic CO2 fluxes are particularly challenging because of their strong seasonal and diurnal cycles and large spatial variability. During the summer 2016 ACT field campaign, fair weather days were targeted for special flight patterns designed to estimate surface fluxes at scales on the order of 105 km2 using a modified mass-balance approach. For some onshore flow cases in the Gulf Coast, atmospheric boundary layer (ABL) flight transects were performed both inland and offshore when it could be reasonably inferred that the homogeneous Gulf air provided the background GHG field for the inland transect. On other days, two-day flight sequences were performed, where the second-day location of the flight patterns was designed to encompass the air mass that was sampled on the first day. With these flight patterns, the average regional flux can be estimated from the ABL CO2 concentration change. Direct measurements of ABL depth from both aircraft profiles and high-resolution airborne lidar will be used, while winds and free-tropospheric CO2 can be determined from model output and in situ aircraft observations. Here we will present examples of this flux estimation for both Gulf </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017GBioC..31..591W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017GBioC..31..591W">Calculating surface ocean pCO2 from biogeochemical Argo floats equipped with pH: An uncertainty analysis</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Williams, N. L.; Juranek, L. W.; Feely, R. A.; Johnson, K. S.; Sarmiento, J. L.; Talley, L. D.; Dickson, A. G.; Gray, A. R.; Wanninkhof, R.; Russell, J. L.; Riser, S. C.; Takeshita, Y. 2017-03-01 More than 74 biogeochemical profiling floats that measure water column pH, oxygen, nitrate, fluorescence, and backscattering at 10 day intervals have been deployed throughout the Southern Ocean. Calculating the surface ocean partial pressure of carbon dioxide (pCO2sw) from float pH has uncertainty contributions from the pH sensor, the alkalinity estimate, and carbonate system equilibrium constants, resulting in a relative standard uncertainty in pCO2sw of 2.7% (or 11 µatm at pCO2sw of 400 µatm). The calculated pCO2sw from several floats spanning a range of oceanographic regimes are compared to existing climatologies. In some locations, such as the subantarctic zone, the float data closely match the climatologies, but in the polar Antarctic zone significantly higher pCO2sw are calculated in the wintertime implying a greater air-sea CO2 efflux estimate. Our results based on four representative floats suggest that despite their uncertainty relative to direct measurements, the float data can be used to improve estimates for air-sea carbon flux, as well as to increase knowledge of spatial, seasonal, and interannual variability in this flux. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2010AGUFM.C43E0586E','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2010AGUFM.C43E0586E">Carbon Dioxide Transfer Through Sea Ice: Modelling Flux in Brine Channels</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Edwards, L.; Mitchelson-Jacob, G.; Hardman-Mountford, N. 2010-12-01 For many years sea ice was thought to act as a barrier to the flux of CO2 between the ocean and atmosphere. However, laboratory-based and in-situ observations suggest that while sea ice may in some circumstances reduce or prevent transfer (e.g. in regions of thick, superimposed multi-year ice), it may also be highly permeable (e.g. thin, first year ice) with some studies observing significant fluxes of CO2. Sea ice covered regions have been observed to act both as a sink and a source of atmospheric CO2 with the permeability of sea ice and direction of flux related to sea ice temperature and the presence of brine channels in the ice, as well as seasonal processes such as whether the ice is freezing or thawing. Brine channels concentrate dissolved inorganic carbon (DIC) as well as salinity and as these dense waters descend through both the sea ice and the surface ocean waters, they create a sink for CO2. Calcium carbonate (ikaite) precipitation in the sea ice is thought to enhance this process. Micro-organisms present within the sea ice will also contribute to the CO2 flux dynamics. Recent evidence of decreasing sea ice extent and the associated change from a multi-year ice to first-year ice dominated system suggest the potential for increased CO2 flux through regions of thinner, more porous sea ice. A full understanding of the processes and feedbacks controlling the flux in these regions is needed to determine their possible contribution to global CO2 levels in a future warming climate scenario. Despite the significance of these regions, the air-sea CO2 flux in sea ice covered regions is not currently included in global climate models. Incorporating this carbon flux system into Earth System models requires the development of a well-parameterised sea ice-air flux model. In our work we use the Los Alamos sea ice model, CICE, with a modification to incorporate the movement of CO2 through brine channels including the addition of DIC processes and ice algae production to </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/19215133','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/19215133">Kinetics of CO(2) fluxes outgassing from champagne glasses in tasting conditions: the role of temperature.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Liger-Belair, Gérard; Villaume, Sandra; Cilindre, Clara; Jeandet, Philippe 2009-03-11 Measurements of CO(2) fluxes outgassing from a flute poured with a standard Champagne wine initially holding about 11 g L(-1) of dissolved CO(2) were presented, in tasting conditions, all along the first 10 min following the pouring process. Experiments were performed at three sets of temperature, namely, 4 degrees C, 12 degrees C, and 20 degrees C, respectively. It was demonstrated that the lower the champagne temperature, the lower CO(2) volume fluxes outgassing from the flute. Therefore, the lower the champagne temperature, the lower its progressive loss of dissolved CO(2) concentration with time, which constitutes the first analytical proof that low champagne temperatures prolong the drink's chill and helps retains its effervescence. A correlation was also proposed between CO(2) volume fluxes outgassing from the flute poured with champagne and its continuously decreasing dissolved CO(2) concentration. Finally, the contribution of effervescence to the global kinetics of CO(2) release was discussed and modeled by the use of results developed over recent years. The temperature dependence of the champagne viscosity was found to play a major role in the kinetics of CO(2) outgassing from a flute. On the basis of this bubbling model, the theoretical influence of champagne temperature on CO(2) volume fluxes outgassing from a flute was discussed and found to be in quite good accordance with our experimental results. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012AGUFMGC51G..04D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012AGUFMGC51G..04D">Retrieval of Paris CO2 and CO emissions using a boundary layer budget method in the framework of the CO2-MEGAPARIS project</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Dieudonné, E.; Gibert, F.; Xueref-remy, I. C.; Lopez, M.; Schmidt, M.; Ravetta, F. 2012-12-01 . These anthropogenic fluxes are compared to the CITEPA and IER emission inventories using the air mass footprint from a Lagrangian Particle Dispersion Model in backward mode. Results from a case study in March 2012 are presented to assess the propagation of Paris CO2 and CO plume, the precision of the method and its ability to provide an independent verification of urban emission inventories. References: [a] Xueref-Remy et al., Abstract n°A13F-0277, AGU Fall Meeting 2010, San Francisco, USA [b] http://co2-megaparis.lsce.ipsl.fr/ [c] Gibert et al., J. Geophys. Research, 112, D10301 (2007) [d] http://www.icos-infrastructure.eu/ </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.B21F0488S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.B21F0488S">Temporally-resolved Study of Atmosphere-lake Net CO2 Exchange at Lochaber Lake, Nova Scotia, Canada</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Spafford, L. A.; Risk, D. A. 2016-12-01 Lakes are carbon gateways with immense processing capacity, acting as either sinks or sources for CO2. As climate change exacerbates weather extremes, carbon stored within permafrost and soils is liberated to water systems, altering aquatic carbon budgets and light availability for photosynthesis. The functional response of lakes to climate change is uncertain, and continuous data of lake respiration and its drivers are lacking. This study used high-frequency measurements of CO2 exchange during a growing season by a novel technique to quantify the net flux of carbon at a small deep oligotrophic lake in eastern Nova Scotia, Canada, and to examine the influence of environmental forcings. We installed 3 floating Forced Diffusion dynamic membrane chambers on the lake, coupled to a valving multiplexer and a single Vaisala GMP 343 CO2 analyzer. This low-power system sampled lake-atmosphere CO2 exchange at several points from shore every hour for over 100 days in the growing season. At the same frequency we also collected automated measurements of wind velocity, photosynthetically active radiation (PAR), dissolved CO2, air and water temperature. Manual measurement campaigns measured chlorophyll `a', DOC, surface methane (CH4), and CO2 flux by manual static floating chamber to confirm the automated measurements. The lake was a net source for carbon, on average emitting 0.038 µmol CO2/m2/s or 4.967 g CO2/s over the entire lake, but we did observe significant temporal variation across diel cycles, and along with changing weather. Approximately 48 hours after every rain event, we observed an increase in littoral CO2 release by the lake. Wind speed, air temperature, and distance from shore were also drivers of variation, as the littoral zone tended to release less CO2 during the course of our study. This work shows the variable influence of environmental drivers of lake carbon flux, as well as the utility of low-power automated chambers for observing aquatic net CO2 exchange. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://eric.ed.gov/?q=chemical+AND+engineering+AND+reactions&pg=5&id=EJ945561','ERIC'); return false;" href="https://eric.ed.gov/?q=chemical+AND+engineering+AND+reactions&pg=5&id=EJ945561">Combining Experiments and Simulation of Gas Absorption for Teaching Mass Transfer Fundamentals: Removing CO2 from Air Using Water and NaOH</a> <a target="_blank" href="http://www.eric.ed.gov/ERICWebPortal/search/extended.jsp?_pageLabel=advanced">ERIC Educational Resources Information Center</a> Clark, William M.; Jackson, Yaminah Z.; Morin, Michael T.; Ferraro, Giacomo P. 2011-01-01 Laboratory experiments and computer models for studying the mass transfer process of removing CO2 from air using water or dilute NaOH solution as absorbent are presented. Models tie experiment to theory and give a visual representation of concentration profiles and also illustrate the two-film theory and the relative importance of various… </li> <li> <a target="_blank" onclick="trackOutboundLink('http://www.ars.usda.gov/research/publications/publication/?seqNo115=333940','TEKTRAN'); return false;" href="http://www.ars.usda.gov/research/publications/publication/?seqNo115=333940">Data from the Arizona FACE (Free-Air CO2 Enrichment) experiments on wheat at ample and limiting levels of water and nitrogen</a> <a target="_blank" href="https://www.ars.usda.gov/research/publications/find-a-publication/">USDA-ARS?s Scientific Manuscript database</a> Four free-air CO2 enrichment (FACE) experiments were conducted on wheat (Triticum aestivum L. cv. Yecora Rojo) at Maricopa, Arizona, U.S.A. from December, 1992 through May, 1997. The first two were conducted at ample and limited (50% of ample) supplies of water, and second two at ample (350 kg N ha-... </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/25627372','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/25627372">Diurnal sampling reveals significant variation in CO2 emission from a tropical productive lake.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Reis, P C J; Barbosa, F A R 2014-08-01 It is well accepted in the literature that lakes are generally net heterotrophic and supersaturated with CO2 because they receive allochthonous carbon inputs. However, autotrophy and CO2 undersaturation may happen for at least part of the time, especially in productive lakes. Since diurnal scale is particularly important to tropical lakes dynamics, we evaluated diurnal changes in pCO2 and CO2 flux across the air-water interface in a tropical productive lake in southeastern Brazil (Lake Carioca) over two consecutive days. Both pCO2 and CO2 flux were significantly different between day (9:00 to 17:00) and night (21:00 to 5:00) confirming the importance of this scale for CO2 dynamics in tropical lakes. Net heterotrophy and CO2 outgassing from the lake were registered only at night, while significant CO2 emission did not happen during the day. Dissolved oxygen concentration and temperature trends over the diurnal cycle indicated the dependence of CO2 dynamics on lake metabolism (respiration and photosynthesis). This study indicates the importance of considering the diurnal scale when examining CO2 emissions from tropical lakes. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018APJAS..54....1K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018APJAS..54....1K">Effect of Data Assimilation Parameters on The Optimized Surface CO2 Flux in Asia</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Kim, Hyunjung; Kim, Hyun Mee; Kim, Jinwoong; Cho, Chun-Ho 2018-02-01 In this study, CarbonTracker, an inverse modeling system based on the ensemble Kalman filter, was used to evaluate the effects of data assimilation parameters (assimilation window length and ensemble size) on the estimation of surface CO2 fluxes in Asia. Several experiments with different parameters were conducted, and the results were verified using CO2 concentration observations. The assimilation window lengths tested were 3, 5, 7, and 10 weeks, and the ensemble sizes were 100, 150, and 300. Therefore, a total of 12 experiments using combinations of these parameters were conducted. The experimental period was from January 2006 to December 2009. Differences between the optimized surface CO2 fluxes of the experiments were largest in the Eurasian Boreal (EB) area, followed by Eurasian Temperate (ET) and Tropical Asia (TA), and were larger in boreal summer than in boreal winter. The effect of ensemble size on the optimized biosphere flux is larger than the effect of the assimilation window length in Asia, but the importance of them varies in specific regions in Asia. The optimized biosphere flux was more sensitive to the assimilation window length in EB, whereas it was sensitive to the ensemble size as well as the assimilation window length in ET. The larger the ensemble size and the shorter the assimilation window length, the larger the uncertainty (i.e., spread of ensemble) of optimized surface CO2 fluxes. The 10-week assimilation window and 300 ensemble size were the optimal configuration for CarbonTracker in the Asian region based on several verifications using CO2 concentration measurements. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/1995TellB..47..447I','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/1995TellB..47..447I">Air-sea exchange of CO2 in the central and western equatorial Pacific in 1990</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Ishii, Masao; Yoshikawa Inoue, Hisayuki 1995-09-01 Measurements of CO2 in marine boundary air and in surface seawater of the central and western Pacific west of 150°W were made during the period from September to December 1990. The meridional section along 150°W showed pCO2(sea) maximum over 410 µatm between the equator and 3°S due to strong equatorial upwelling. In the equatorial Pacific between 150°W and 179°E, pCO2(sea) decreased gradually toward the west as a result of biological CO2 uptake and surface sea temperature increase. Between 179°E and 170°E, the pCO2(sea) decreased steeply from 400 µatm to 350 µatm along with a decrease of salinity. West of 170°E, where the salinity is low owing to the heavy rainfall, pCO2(sea) was nearly equal to pCO2(air). The distribution of the atmospheric CO2 concentration showed a considerable variability (±3ppm) in the area north of the Intertropical Convergence Zone due to the regional net source-sink strength of the terrestrial biosphere. The net CO2 flux from the sea to the atmosphere in the equatorial region of the central and western Pacific (15°S-10°N, 140°E-150°W) was evaluated from the ΔpCO2 distribution and the several gas transfer coefficients reported so far. It ranged from 0.13 GtC year<img src="/entityImage/script/2212.gif" alt="-" border="0" style="font-weight: bold"></img>1-0.29 GtC year<img src="/entityImage/script/2212.gif" alt="-" border="0" style="font-weight: bold"></img>1. This CO2 outflux is thought to almost disappear during the period of an El Niño event. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_15");'>15</a></li> <li><a href="#" onclick='return showDiv("page_16");'>16</a></li> <li class="active">17</li> <li><a href="#" onclick='return showDiv("page_18");'>18</a></li> <li><a href="#" onclick='return showDiv("page_19");'>19</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_18" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_16");'>16</a></li> <li><a href="#" onclick='return showDiv("page_17");'>17</a></li> <li class="active">18</li> <li><a href="#" onclick='return showDiv("page_19");'>19</a></li> <li><a href="#" onclick='return showDiv("page_20");'>20</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="341"> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2002AGUSMGC32A..05K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2002AGUSMGC32A..05K">CO2 Capture from the Air: Technology Assessment and Implications for Climate Policy</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Keith, D. W. 2002-05-01 It is physically possible to capture CO2 directly from the air and immobilize it in geological structures. Today, there are no large-scale technologies that achieve air capture at reasonable cost. Yet, strong arguments suggest that it will comparatively easy to develop practical air capture technologies on the timescales relevant to climate policy [1]. This paper first analyzes the cost of air capture and then assesses the implications for climate policy. We first analyze the lower bound on the cost needed for air capture, describing the thermodynamic and physical limits to the use of energy and land. We then compare the costs of air capture to the cost of capture from combustion exhaust streams. While the intrinsic minimum energy requirement is larger for air capture, we argue that air capture has important structural advantages, such as the reduction of transport costs and the larger potential for economies of scale. These advantages suggest that, in the long-run air capture be competitive with other methods of achieving deep emissions reductions. We provide a preliminary engineering-economic analysis of an air capture system based on CaO to CaCO3 chemical looping [1]. We analyze the possibility of doing the calcination in a modified pressurized fluidized bed combustor (PFBC) burning coal in a CO2 rich atmosphere with oxygen supplied by an air separation unit. The CaCO3-to-coal ratio would be ~2:1 and the system would be nearly thermally neutral. PFBC systems have been demonstrated at capacities of over 100 MW. Such systems already include CaCO3 injection for sulfur control, and operate at suitable temperatures and pressures for calcination. We assess the potential to recover heat from the dissolution of CaO in order to reduce the overall energy requirements. We analyze the possibility of adapting existing large water/air heat exchangers for use as contacting systems to capture CO2 from the air using the calcium hydroxide solution. The implications of air capture </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..1910783S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..1910783S">Estimation of the CO2 fluxes between the ocean and atmosphere for the hurricane wind forces using remote sensing data.</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Sergeev, Daniil; Soustova, Irina; Balandina, Galina 2017-04-01 CO2 transfer between the hydrosphere and atmosphere in the boundary layer is an important part of the global cycle of the main greenhouse gas. Gas flux is determined by the difference of the partial pressures of the gas between the atmosphere and hydrosphere, near the border, as well as to a large extent processes involving turbulent boundary layer. The last is usually characterized by power dependence on the equivalent wind speed (10-m height). Hurricane-force winds lead to intensive wave breaking, with formation of spray in the air, and bubbles in the water. Such multiphase turbulent processes at the interface strongly intensify gas transfer. Currently, data characterizing the dependence of the gas exchange of the wind speed for the hurricane conditions demonstrate a strong variation. On the other hand there is an obvious problem of obtaining reliable data on the wind speed. Widely used reanalysis data typically underestimate wind speed, due to the low spatial and temporal resolution One of the most promising ways to measure near water wind speed is the use of the data of remote sensing. The present study used technique to obtain near water wind speed based on the processing of remote sensing of the ocean surface data obtained with C-band scattermeter of RADARSAT using geophysical model function, developed in a laboratory conditions for a wide range of wind speeds, including hurricanes (see [1]). This function binds wind speed with effective radar cross-section in cross-polarized mode. We used two different parameterizations of gas transfer velocity of the wind speed. Widely used in [2], and obtained by processing results of recent experiment in modeling winds up to hurricane on wind-wave facility [3]. The new method of calculating was tested by the example of hurricane Earl image (09.2010). Estimates showed 13-18 times excess CO2 fluxes rates in comparison with monitoring data NOAA (see. [4]). 1. Troitskaya Yu., Abramov V., Ermoshkin A., Zuikova E., Kazakov V </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2010AGUFM.A21A0020B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2010AGUFM.A21A0020B">Urban Evapotranspiration and Carbon Dioxide Flux in Miami - Dade, Florida</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Bernier, T.; Hopper, W. 2010-12-01 Atmospheric Carbon Dioxide (CO2) concentrations are leading indicators of secular climate change. With increasing awareness of the consequences of climate change, methods for monitoring this change are becoming more important daily. Of particular interest is the carbon dioxide exchange between natural and urban landscapes and the correlation of atmospheric CO2 concentrations. Monitoring Evapotranspiration (ET) is important for assessments of water availability for growing populations. ET is surprisingly understudied in the hydrologic cycle considering ET removes as much as 80 to over 100% of precipitation back into the atmosphere as water vapor. Lack of understanding in spatial and temporal ET estimates can limit the credibility of hydrologic water budgets designed to promote sustainable water use and resolve water-use conflicts. Eddy covariance (EC) methods are commonly used to estimate ET and CO2 fluxes. The EC platform consist of a (CSAT) 3-D Sonic Anemometer and a Li-Cor Open Path CO2/ H2O Analyzer. Measurements collected at 10 Hz create a very large data sets. A EC flux tower located in the Snapper Creek Well Field as part of a study to estimate ET for the Miami Dade County Water and Sewer project. Data has been collected from December 17, 2009 to August 30, 2010. QA/QC is performed with the EdiRe data processing software according to Ameri-flux protocols. ET estimates along with other data--latent-heat flux, sensible-heat flux, rainfall, air temperature, wind speed and direction, solar irradiance, net radiation, soil-heat flux and relative humidity--can be used to aid in the development of water management policies and regulations. Currently, many financial institutions have adopted an understanding about baseline environmental monitoring. The “Equator Principle” is an example of a voluntary standard for managing social and environmental risk in project financing and has changed the way in which projects are financed. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70044410','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70044410">Resolving hyporheic and groundwater components of streambed water flux</a> <a target="_blank" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Bhaskar, Aditi S.; Harvey, Judson W.; Henry, Eric J. 2012-01-01 Hyporheic and groundwater fluxes typically occur together in permeable sediments beneath flowing stream water. However, streambed water fluxes quantified using the thermal method are usually interpreted as representing either groundwater or hyporheic fluxes. Our purpose was to improve understanding of co-occurring groundwater and hyporheic fluxes using streambed temperature measurements and analysis of one-dimensional heat transport in shallow streambeds. First, we examined how changes in hyporheic and groundwater fluxes affect their relative magnitudes by reevaluating previously published simulations. These indicated that flux magnitudes are largely independent until a threshold is crossed, past which hyporheic fluxes are diminished by much larger (1000-fold) groundwater fluxes. We tested accurate quantification of co-occurring fluxes using one-dimensional approaches that are appropriate for analyzing streambed temperature data collected at field sites. The thermal analytical method, which uses an analytical solution to the one-dimensional heat transport equation, was used to analyze results from a numerical heat transport model, in which hyporheic flow was represented as increased thermal dispersion at shallow depths. We found that co-occurring groundwater and hyporheic fluxes can be quantified in streambeds, although not always accurately. For example, using a temperature time series collected in a sandy streambed, we found that hyporheic and groundwater flow could both be detected when thermal dispersion due to hyporheic flow was significant compared to thermal conduction. We provide guidance for when thermal data can be used to quantify both hyporheic and groundwater fluxes, and we show that neglecting thermal dispersion may affect accuracy and interpretation of estimated streambed water fluxes. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.B21F2004M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.B21F2004M">The effect to the water stress to soil CO2 efflux in the Siberian boreal forest</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Makhnykina, A. V.; Prokishkin, A. S.; Verkhovets, S. V.; Koshurnikova, N. N. 2017-12-01 The boreal forests in Siberia covered more than 70% area of this region. Due to the climate change this ecosystems represent a very sensitive and significant source of carbon. In forests, total ecosystem respiration tends to be dominated by soil respiration, which accounts for approximately 69% of this large flux (Janssens et al., 2001). Dynamic global vegetation models predict that soil respiration will increase more than total net primary productivity in response to warmer temperatures and increase in precipitation, the terrestrial carbon sink is expected to decline significantly (Bonan et al., 2003). The aim of the present study was to identify the response of the soil CO2 efflux to the different amount of water input for two highly differentiated years by the precipitation conditions in the middle taiga forests in Central Siberia. The study was conducted in the pine forests in Central Siberia (60°N, 90°E), Russia. We used the automated soil CO2 flux system LI-8100 for measuring the soil efflux. Soil temperature was measured with Soil Temperature Probe Type E in three depths 5, 10, 15 cm. Volumetric soil moisture was measured with Theta Probe Model ML2. We constructed the field experiment based on the addition of different amount of water (0%, 25%, 50% and 100% sites) after each rain event during the growing season. We found that the amount of precipitation have a huge impact to the value of soil CO2 efflux. For the more precipitated year (2015) the fluxes were almost twice higher compared to less precipitated year (2016). The max fluxes during the season in 2015 observed at the site without any water input there and the min one - for the 100% precipitation site (natural rain conditions). In 2016 we identified the opposite response: the max soil efflux demonstrated the site with 100% precipitation conditions (Fig. 1). We also detected the high dependence between the soil temperature and soil CO2 efflux for the site with 0% additional water input in more </li> <li> <a target="_blank" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20130000016&hterms=Administration+Global&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D10%26Ntt%3DAdministration%2BGlobal','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20130000016&hterms=Administration+Global&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D10%26Ntt%3DAdministration%2BGlobal">Global and Regional Seasonal Variability of Mid-Tropospheric CO2 as Measured by the Atmospheric Infrared Sounder (AIRS)</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Pagano, Thomas S.; Olsen, Edward T.; Nguyen, Hai 2012-01-01 The Atmospheric Infrared Sounder (AIRS) is a hyperspectral infrared instrument on the Earth Observing System (EOS) Aqua Spacecraft, launched on May 4, 2002 into a near polar sun-synchronous orbit. AIRS has 2378 infrared channels ranging from 3.7 ?m to 15.4 ?m and a 13.5 km footprint at nadir. AIRS, in conjunction with the Advanced Microwave Sounding Unit (AMSU), produces temperature profiles with 1K/km accuracy on a global scale, as well as water vapor profiles and trace gas amounts for CO2, CO, SO2, O3 and CH4. AIRS CO2 climatologies have been shown to be useful for identifying anomalies associated with geophysical events such as El Nino-Southern Oscillation or Madden-Julian oscillation. In this study, monthly representations of mid-tropospheric CO2 are constructed from 10 years of AIRS Version 5 monthly Level 3 data. We compare the AIRS mid-tropospheric CO2 representations to ground-based measurements from the Scripps and National Oceanic and Atmospheric Administration Climate Modeling and Diagnostics Laboratory (NOAA CMDL) ground networks to better understand the phase lag of the CO2 seasonal cycle between the surface and middle troposphere. Results show only a small phase lag in the tropics that grows to approximately two months in the northern latitudes. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.H34H..05P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.H34H..05P">Urban Land Cover Type Influences CO2 Fluxes within Phoenix, Arizona</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Perez-Ruiz, E. R.; Vivoni, E. R.; Templeton, N. P. 2017-12-01 Urbanization is accompanied by the modification of land surface characteristics that should have an impact on local energy, water and carbon cycles. For instance, despite their relative small land area, cities are responsible for more than 70% of the global anthropogenic CO2 emissions. Nevertheless, relatively little is known on the dynamics of urban carbon fluxes or net ecosystem exchange (NEE), in particular over the multitude of land cover patches present within cities. In this study, we present a comparison of NEE measurements in four urban patches in the Phoenix metropolitan area. A mobile eddy covariance (EC) tower was deployed at a xeric landscaping, a parking lot and a mesic landscaping during consecutive, short-term ( 40 days) sampling periods and compared to a reference site (REF) in a suburban neighborhood over a longer deployment ( 9 months). Based on the datasets, we analyze the diurnal cycle and the daily and seasonal variations of NEE in the context of the measured meteorological conditions, including the surface energy budget. EC observations were then related to vegetation conditions through a satellite-based Normalized Difference Vegetation Index (NDVI) and to anthropogenic activities through local traffic counts. All deployment sites showed important differences in NEE with respect to the REF location due to the influence of the urban patch area sampled within the EC footprint. Daily NEE values at all sites exhibited differences among days of the week that were linked to traffic conditions, with higher values during weekdays and lower values during weekends. The diurnal behavior of NEE showed different trends depending on the amount of vegetation and the proximity to nearby roads. Minimum midday (around noon) values of NEE were noted where urban plants absorbed CO2, while maximum peaks of NEE occurred during rush hours (around 8 am and 6 pm) where the traffic influence was high. Overall, three of the four sites with low to moderate vegetation </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/biblio/6295083-use-free-air-co-sub-enrichment-face-study-effects-co-sub-cotton-preliminary-summary-report','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/6295083-use-free-air-co-sub-enrichment-face-study-effects-co-sub-cotton-preliminary-summary-report">Use of Free Air CO/sub 2/ Enrichment (FACE) to study effects of CO/sub 2/ on cotton: Preliminary summary report -- 1988</a> <a target="_blank" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Biswas, P.K.; Hileman, D.R.; Bhattacharya, N.C. 1988-01-01 In the summer of 1988, Tuskegee University, along with Brookhaven National Laboratory, Manhattan College, and USDA laboratories in Tallahassee, FL and Phoenix, AZ, participated in joint program to evaluate the feasibility of using a Free Air CO/sub 2/ Enrichment (FACE) system to conduct experiments on the effects of elevated CO/sub 2/ on cotton. The experiments were conducted in Yazoo City, MS, under the direction of the US Department of Energy, Carbon Dioxide Research Division. Tuskegee University's role in the project included the following objectives: (1)Soil moisture and nutrient analysis before planting and at harvest. (2) Photosynthesis and stomatal conductance measurementsmore » at ambient and enriched CO/sub 2/ atmosphere. (3) Leaf water potential measurements. (4) CO/sub 2/ distribution patterns in the FACE array. 12 figs., 14 tabs.« less </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013NatGe...6..457Z','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013NatGe...6..457Z">Millennial-scale changes in atmospheric CO2 levels linked to the Southern Ocean carbon isotope gradient and dust flux</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Ziegler, Martin; Diz, Paula; Hall, Ian R.; Zahn, Rainer 2013-06-01 The rise in atmospheric CO2 concentrations observed at the end of glacial periods has, at least in part, been attributed to the upwelling of carbon-rich deep water in the Southern Ocean. The magnitude of outgassing of dissolved CO2, however, is influenced by the biological fixation of upwelled inorganic carbon and its transfer back to the deep sea as organic carbon. The efficiency of this biological pump is controlled by the extent of nutrient utilization, which can be stimulated by the delivery of iron by atmospheric dust particles. Changes in nutrient utilization should be reflected in the δ13C gradient between intermediate and deep waters. Here we use the δ13C values of intermediate- and bottom-dwelling foraminifera to reconstruct the carbon isotope gradient between thermocline and abyssal water in the subantarctic zone of the South Atlantic Ocean over the past 360,000 years. We find millennial-scale oscillations of the carbon isotope gradient that correspond to changes in dust flux and atmospheric CO2 concentrations as reported from Antarctic ice cores. We interpret this correlation as a relationship between the efficiency of the biological pump and fertilization by dust-borne iron. As the correlation is exponential, we suggest that the sensitivity of the biological pump to dust-borne iron fertilization may be increased when the background dust flux is low. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/26470015','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/26470015">Multivariate regulation of soil CO2 and N2 O pulse emissions from agricultural soils.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Liang, Liyin L; Grantz, David A; Jenerette, G Darrel 2016-03-01 Climate and land-use models project increasing occurrence of high temperature and water deficit in both agricultural production systems and terrestrial ecosystems. Episodic soil wetting and subsequent drying may increase the occurrence and magnitude of pulsed biogeochemical activity, affecting carbon (C) and nitrogen (N) cycles and influencing greenhouse gas (GHG) emissions. In this study, we provide the first data to explore the responses of carbon dioxide (CO2 ) and nitrous oxide (N2 O) fluxes to (i) temperature, (ii) soil water content as percent water holding capacity (%WHC), (iii) substrate availability throughout, and (iv) multiple soil drying and rewetting (DW) events. Each of these factors and their interactions exerted effects on GHG emissions over a range of four (CO2 ) and six (N2 O) orders of magnitude. Maximal CO2 and N2 O fluxes were observed in environments combining intermediate %WHC, elevated temperature, and sufficient substrate availability. Amendments of C and N and their interactions significantly affected CO2 and N2 O fluxes and altered their temperature sensitivities (Q10 ) over successive DW cycles. C amendments significantly enhanced CO2 flux, reduced N2 O flux, and decreased the Q10 of both. N amendments had no effect on CO2 flux and increased N2 O flux, while significantly depressing the Q10 for CO2 , and having no effect on the Q10 for N2 O. The dynamics across DW cycles could be attributed to changes in soil microbial communities as the different responses to wetting events in specific group of microorganisms, to the altered substrate availabilities, or to both. The complex interactions among parameters influencing trace gas fluxes should be incorporated into next generation earth system models to improve estimation of GHG emissions. © 2015 John Wiley & Sons Ltd. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20070023316&hterms=casa&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D40%26Ntt%3Dcasa','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20070023316&hterms=casa&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D40%26Ntt%3Dcasa">Progress in Modeling Global Atmospheric CO2 Fluxes and Transport: Results from Simulations with Diurnal Fluxes</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Collatz, G. James; Kawa, R. 2007-01-01 Progress in better determining CO2 sources and sinks will almost certainly rely on utilization of more extensive and intensive CO2 and related observations including those from satellite remote sensing. Use of advanced data requires improved modeling and analysis capability. Under NASA Carbon Cycle Science support we seek to develop and integrate improved formulations for 1) atmospheric transport, 2) terrestrial uptake and release, 3) biomass and 4) fossil fuel burning, and 5) observational data analysis including inverse calculations. The transport modeling is based on meteorological data assimilation analysis from the Goddard Modeling and Assimilation Office. Use of assimilated met data enables model comparison to CO2 and other observations across a wide range of scales of variability. In this presentation we focus on the short end of the temporal variability spectrum: hourly to synoptic to seasonal. Using CO2 fluxes at varying temporal resolution from the SIB 2 and CASA biosphere models, we examine the model's ability to simulate CO2 variability in comparison to observations at different times, locations, and altitudes. We find that the model can resolve much of the variability in the observations, although there are limits imposed by vertical resolution of boundary layer processes. The influence of key process representations is inferred. The high degree of fidelity in these simulations leads us to anticipate incorporation of realtime, highly resolved observations into a multiscale carbon cycle analysis system that will begin to bridge the gap between top-down and bottom-up flux estimation, which is a primary focus of NACP. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016PrOce.144...15W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016PrOce.144...15W">Biofilm-like properties of the sea surface and predicted effects on air-sea CO2 exchange</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Wurl, Oliver; Stolle, Christian; Van Thuoc, Chu; The Thu, Pham; Mari, Xavier 2016-05-01 Because the sea surface controls various interactions between the ocean and the atmosphere, it has a profound function for marine biogeochemistry and climate regulation. The sea surface is the gateway for the exchange of climate-relevant gases, heat and particles. Thus, in order to determine how the ocean and the atmosphere interact and respond to environmental changes on a global scale, the characterization and understanding of the sea surface are essential. The uppermost part of the water column is defined as the sea-surface microlayer and experiences strong spatial and temporal dynamics, mainly due to meteorological forcing. Wave-damped areas at the sea surface are caused by the accumulation of surface-active organic material and are defined as slicks. Natural slicks are observed frequently but their biogeochemical properties are poorly understood. In the present study, we found up to 40 times more transparent exopolymer particles (TEP), the foundation of any biofilm, in slicks compared to the underlying bulk water at multiple stations in the North Pacific, South China Sea, and Baltic Sea. We found a significant lower enrichment of TEP (up to 6) in non-slick sea surfaces compared to its underlying bulk water. Moreover, slicks were characterized by a large microbial biomass, another shared feature with conventional biofilms on solid surfaces. Compared to non-slick samples (avg. pairwise similarity of 70%), the community composition of bacteria in slicks was increasingly (avg. pairwise similarity of 45%) different from bulk water communities, indicating that the TEP-matrix creates specific environments for its inhabitants. We, therefore, conclude that slicks can feature biofilm-like properties with the excessive accumulation of particles and microbes. We also assessed the potential distribution and frequency of slick-formation in coastal and oceanic regions, and their effect on air-sea CO2 exchange based on literature data. We estimate that slicks can reduce CO2 </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.A43F2533S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.A43F2533S">Measurement of NOx and CO Fluxes from a Tall Tower in Beijing.</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Squires, F. A.; Drysdale, W. S.; Hamilton, J.; Lee, J. D.; Vaughan, A. R.; Wild, O.; Mullinger, N.; Nemitz, E.; Metzger, S.; Zhang, Q. 2017-12-01 China's air quality problems are well publicised; in 2010, 1.2 million premature deaths were attributed to outdoor air pollution in China. One of the major air quality issues is high concentrations of nitrogen oxides (NOx). China is the largest NOx emitter, contributing an estimated 18 % to global NOx emissions. Beijing itself is reported to have NO2 concentrations 42 % higher than the annual national standard. Given the high levels of pollution, increased focus has been placed on improving emissions estimates which are typically developed using a `bottom-up' approach where emissions are predicted from their sources. Emission inventories in China have large uncertainties and are rapidly changing with time in response to economic development, environmental regulation and new technologies. In fact, China is the largest contributor to the uncertainty in the source and the magnitude of air pollutants in air quality models. Recent studies have shown a discrepancy between NOx inventories and measured NOx emissions for UK cities, highlighting the limitations of bottom-up emissions inventories and the importance of accurate measurement data to improve the estimates. 5 Hz measurements of NOx and CO concentration were made as part of the Air Pollutants in Beijing (AIRPOLL-Beijing) project during two field campaigns in Nov-Dec 2016 and May-June 2017. Sampling took place from an inlet co-located with a sonic anemometer at 102 m on a meteorological tower in central Beijing. Analysis of the covariance between vertical wind speed and concentration enabled the calculation of emission flux, with an estimated footprint of between 2 - 5 km from the tower (which typically included some major ring roads and expressways). Fluxes were quantified using the continuous wavelet transformation (CWT) method, which enabled one minute resolved fluxes to be calculated. These data were compared to existing emissions estimates from the Multi-resolution Emission Inventory for China (MEIC). It is </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29554758','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29554758">Influence of plankton metabolism and mixing depth on CO2 dynamics in an Amazon floodplain lake.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Amaral, João Henrique F; Borges, Alberto V; Melack, John M; Sarmento, Hugo; Barbosa, Pedro M; Kasper, Daniele; de Melo, Michaela L; De Fex-Wolf, Daniela; da Silva, Jonismar S; Forsberg, Bruce R 2018-07-15 We investigated plankton metabolism and its influence on carbon dioxide (CO 2 ) dynamics in a central Amazon floodplain lake (Janauacá, 3°23' S, 60°18' W) from September 2015 to May 2016, including a period with exceptional drought. We made diel measurements of CO 2 emissions to the atmosphere with floating chambers and depth profiles of temperature and CO 2 partial pressure (pCO 2 ) at two sites with differing wind exposure and proximity to vegetated habitats. Dissolved oxygen (DO) concentrations were monitored continuously during day and night in clear and dark chambers with autonomous optical sensors to evaluate plankton metabolism. Overnight community respiration (CR), and gross primary production (GPP) rates were higher in clear chambers and positively correlated with chlorophyll-a (Chl-a). CO 2 air-water fluxes varied over 24-h periods with changes in thermal structure and metabolism. Most net daily CO 2 fluxes during low water and mid-rising water at the wind exposed site were into the lake as a result of high rates of photosynthesis. All other measurements indicated net daily release to the atmosphere. Average GPP rates (6.8gCm -2 d -1 ) were high compared with other studies in Amazon floodplain lakes. The growth of herbaceous plants on exposed sediment during an exceptional drought led to large carbon inputs when these areas were flooded, enhancing CR, pCO 2 , and CO 2 fluxes. During the period when the submerged herbaceous vegetation decayed phytoplankton abundance increased and photosynthetic uptake of CO 2 occurred. While planktonic metabolism was often autotrophic (GPP:CR>1), CO 2 out-gassing occurred during most periods investigated indicating other inputs of carbon such as sediments or soils and wetland plants. Copyright © 2018 Elsevier B.V. All rights reserved. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1340454-co2-capture-from-ambient-air-crystallization-guanidine-sorbent','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1340454-co2-capture-from-ambient-air-crystallization-guanidine-sorbent">CO 2 Capture from Ambient Air by Crystallization with a Guanidine Sorbent</a> <a target="_blank" href="http://www.osti.gov/pages">DOE PAGES</a> Seipp, Charles A.; Univ. of Texas, Austin, TX; Williams, Neil J.; ... 2016-12-21 Carbon capture and storage is an important strategy for stabilizing the increasing concentration of atmospheric CO 2 and the global temperature. A possible approach toward reversing this trend and decreasing the atmospheric CO 2 concentration is to remove the CO 2 directly from air (direct air capture). In this paper, we report a simple aqueous guanidine sorbent that captures CO 2 from ambient air and binds it as a crystalline carbonate salt by guanidinium hydrogen bonding. The resulting solid has very low aqueous solubility (K sp=1.0(4)×10 -8), which facilitates its separation from solution by filtration. The bound CO 2 canmore » be released by relatively mild heating of the crystals at 80–120 °C, which regenerates the guanidine sorbent quantitatively. Finally and thus, this crystallization-based approach to CO 2 separation from air requires minimal energy and chemical input, and offers the prospect for low-cost direct air capture technologies.« less </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/24406632','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/24406632">Soil and water warming accelerates phenology and down-regulation of leaf photosynthesis of rice plants grown under free-air CO2 enrichment (FACE).</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Adachi, Minaco; Hasegawa, Toshihiro; Fukayama, Hiroshi; Tokida, Takeshi; Sakai, Hidemitsu; Matsunami, Toshinori; Nakamura, Hirofumi; Sameshima, Ryoji; Okada, Masumi 2014-02-01 To enable prediction of future rice production in a changing climate, we need to understand the interactive effects of temperature and elevated [CO2] (E[CO2]). We therefore examined if the effect of E[CO2] on the light-saturated leaf photosynthetic rate (Asat) was affected by soil and water temperature (NT, normal; ET, elevated) under open-field conditions at the rice free-air CO2 enrichment (FACE) facility in Shizukuishi, Japan, in 2007 and 2008. Season-long E[CO2] (+200 µmol mol(-1)) increased Asat by 26%, when averaged over two years, temperature regimes and growth stages. The effect of ET (+2°C) on Asat was not significant at active tillering and heading, but became negative and significant at mid-grain filling; Asat in E[CO2]-ET was higher than in ambient [CO2] (A[CO2])-NT by only 4%. Photosynthetic down-regulation at E[CO2] also became apparent at mid-grain filling; Asat compared at the same [CO2] in the leaf cuvette was significantly lower in plants grown in E[CO2] than in those grown in A[CO2]. The additive effects of E[CO2] and ET decreased Asat by 23% compared with that of A[CO2]-NT plants. Although total crop nitrogen (N) uptake was increased by ET, N allocation to the leaves and to Rubisco was reduced under ET and E[CO2] at mid-grain filling, which resulted in a significant decrease (32%) in the maximum rate of ribulose-1,5-bisphosphate carboxylation on a leaf area basis. Because the change in N allocation was associated with the accelerated phenology in E[CO2]-ET plants, we conclude that soil and water warming accelerates photosynthetic down-regulation at E[CO2]. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015EGUGA..1713074S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015EGUGA..1713074S">Air-sea fluxes and satellite-based estimation of water masses formation</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Sabia, Roberto; Klockmann, Marlene; Fernandez-Prieto, Diego; Donlon, Craig 2015-04-01 Recent work linking satellite-based measurements of sea surface salinity (SSS) and sea surface temperature (SST) with traditional physical oceanography has demonstrated the capability of generating routinely satellite-derived surface T-S diagrams [1] and analyze the distribution/dynamics of SSS and its relative surface density with respect to in-situ measurements. Even more recently [2,3], this framework has been extended by exploiting these T-S diagrams as a diagnostic tool to derive water masses formation rates and areas. A water mass describes a water body with physical properties distinct from the surrounding water, formed at the ocean surface under specific conditions which determine its temperature and salinity. The SST and SSS (and thus also density) at the ocean surface are largely determined by fluxes of heat and freshwater. The surface density flux is a function of the latter two and describes the change of the density of seawater at the surface. To obtain observations of water mass formation is of great interest, since they serve as indirect observations of the thermo-haline circulation. The SSS data which has become available through the SMOS [4] and Aquarius [5] satellite missions will provide the possibility of studying also the effect of temporally-varying SSS fields on water mass formation. In the present study, the formation of water masses as a function of SST and SSS is derived from the surface density flux by integrating the latter over a specific area and time period in bins of SST and SSS and then taking the derivative of the total density flux with respect to density. This study presents a test case using SMOS SSS, OSTIA SST, as well as Argo ISAS SST and SSS for comparison, heat fluxes from the NOCS Surface Flux Data Set v2.0, OAFlux evaporation and CMORPH precipitation. The study area, initially referred to the North Atlantic, is extended over two additional ocean basins and the study period covers the 2011-2012 timeframe. Yearly, seasonal </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1224019-amineoxide-hybrid-materials-co-capture-from-ambient-air','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1224019-amineoxide-hybrid-materials-co-capture-from-ambient-air">Amine–Oxide Hybrid Materials for CO 2 Capture from Ambient Air</a> <a target="_blank" href="http://www.osti.gov/pages">DOE PAGES</a> Didas, Stephanie A.; Choi, Sunho; Chaikittisilp, Watcharop; ... 2015-09-10 CONSPECTUS: Oxide supports functionalized with amine moieties have been used for decades as catalysts and chromatographic media. Owing to the recognized impact of atmospheric CO2 on global climate change, the study of the use of amine-oxide hybrid materials as CO2 sorbents has exploded in the past decade. While the majority of the work has concerned separation of CO2 from dilute mixtures such as flue gas from coal-fired power plants, it has been recognized by us and others that such supported amine materials are also perhaps uniquely suited to extract CO2 from ultradilute gas mixtures, such as ambient air. As unique,more » low temperature chemisorbents, they can operate under ambient conditions, spontaneously extracting CO2 from ambient air, while being regenerated under mild conditions using heat or the combination of heat and vacuum. This Account describes the evolution of our activities on the design of amine-functionalized silica materials for catalysis to the design, characterization, and utilization of these materials in CO2 separations. New materials developed in our laboratory, such as hyperbranched aminosilica materials, and previously known amine-oxide hybrid compositions, have been extensively studied for CO2 extraction from simulated ambient air (400 ppm of CO2). The role of amine type and structure (molecular, polymeric), support type and structure, the stability of the various compositions under simulated operating conditions, and the nature of the adsorbed CO2 have been investigated in detail. The requirements for an effective, practical air capture process have been outlined and the ability of amine−oxide hybrid materials to meet these needs has been discussed. Ultimately, the practicality of such a “direct air capture” process is predicated not only on the physicochemical properties of the sorbent, but also how the sorbent operates in a practical process that offers a scalable gas−solid contacting strategy. In this regard, the utility of </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1224019-amineoxide-hybrid-materials-co2-capture-from-ambient-air','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1224019-amineoxide-hybrid-materials-co2-capture-from-ambient-air">Amine–Oxide Hybrid Materials for CO 2 Capture from Ambient Air</a> <a target="_blank" href="http://www.osti.gov/pages">DOE PAGES</a> Didas, Stephanie A.; Choi, Sunho; Chaikittisilp, Watcharop; ... 2015-09-10 Oxide supports functionalized with amine moieties have been used for decades as catalysts and chromatographic media. Owing to the recognized impact of atmospheric CO 2 on global climate change, the study of the use of amine-oxide hybrid materials as CO 2 sorbents has exploded in the past decade. While the majority of the work has concerned separation of CO 2 from dilute mixtures such as flue gas from coal-fired power plants, it has been recognized by us and others that such supported amine materials are also perhaps uniquely suited to extract CO 2 from ultradilute gas mixtures, such as ambientmore » air. As unique, low temperature chemisorbents, they can operate under ambient conditions, spontaneously extracting CO 2 from ambient air, while being regenerated under mild conditions using heat or the combination of heat and vacuum. This Account describes the evolution of our activities on the design of amine-functionalized silica materials for catalysis to the design, characterization, and utilization of these materials in CO 2 separations. New materials developed in our laboratory, such as hyperbranched aminosilica materials, and previously known amine-oxide hybrid compositions, have been extensively studied for CO 2 extraction from simulated ambient air (400 ppm of CO 2). The role of amine type and structure (molecular, polymeric), support type and structure, the stability of the various compositions under simulated operating conditions, and the nature of the adsorbed CO 2 have been investigated in detail. The requirements for an effective, practical air capture process have been outlined and the ability of amine-oxide hybrid materials to meet these needs has been discussed. Ultimately, the practicality of such a “direct air capture” process is predicated not only on the physicochemical properties of the sorbent, but also how the sorbent operates in a practical process that offers a scalable gas-solid contacting strategy. In conclusion, the utility of low </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.fs.usda.gov/treesearch/pubs/43512','TREESEARCH'); return false;" href="https://www.fs.usda.gov/treesearch/pubs/43512">Consequences of incomplete surface energy balance closure for CO2 fluxes from open-path CO2/H2O infrared gas analyzers</a> <a target="_blank" href="http://www.fs.usda.gov/treesearch/">Treesearch</a> Heping Liu; James T. Randerson; Jamie Lindfors; William J. Massman; Thomas Foken 2006-01-01 We present an approach for assessing the impact of systematic biases in measured energy fluxes on CO2 flux estimates obtained from open-path eddy-covariance systems. In our analysis, we present equations to analyse the propagation of errors through the Webb, Pearman, and Leuning (WPL) algorithm [Quart. J. Roy. Meteorol. Soc. 106, 85Â100, 1980] that is widely used to... </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_16");'>16</a></li> <li><a href="#" onclick='return showDiv("page_17");'>17</a></li> <li class="active">18</li> <li><a href="#" onclick='return showDiv("page_19");'>19</a></li> <li><a href="#" onclick='return showDiv("page_20");'>20</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_19" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_17");'>17</a></li> <li><a href="#" onclick='return showDiv("page_18");'>18</a></li> <li class="active">19</li> <li><a href="#" onclick='return showDiv("page_20");'>20</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="361"> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.B11C0480J','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.B11C0480J">Factors Controlling Diffusive CO2 Transport and Production in the Cedarburg Bog, Saukville, Wisconsin</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Joynt, E.; Grundl, T.; Han, W. S.; Gulbranson, E. L. 2016-12-01 Wetlands are vital components of the carbon cycle containing an estimated 20-30% of the global soil carbon store. The Cedarburg Bog of southeastern Wisconsin contains multiple wetland types, including the southernmost string bog found in North America. Carbon dioxide (CO2) behavior in wetland systems respond to multiple interdependent variables that are collectively not well understood. Modeling CO2 behavior in wetland environments requires a detailed representation of these variables. In 2014 a LI-COR 8100A automated soil gas flux system was installed in the string bog, measuring CO2 concentration and flux. Groundwater data, soil temperature, and weather data (temperature, pressure, precipitation, etc.) were included to reveal correlations between soil CO2 flux/concentration and external forces. In 2015 field data were complemented with soil moisture data and depth profiles of pore water chemistry and stable carbon isotopes from peat and soil gas to discern source and evolution of CO2 at depth. Initial gaseous δ13C(CO2) average -18‰ and deplete overnight suggesting increasing microbial metabolic efficiency. δ13C soil microbial biomass measure roughly -21‰ to -22‰. LI-COR data show diurnal and seasonal trends; CO2 concentration builds overnight while flux increases during the day. CO2 flux magnitude and CO2 concentration range peak in mid-summer, but frequency of increased CO2 flux events varies seasonally each year. Flux averages 7.55 mgCO2/min-m2 during the day but reaches 530 mgCO2/min-m2. Increased atmospheric and soil temperatures and decreasing atmospheric pressure prelude increasing CO2 flux intensity, though correlation strengths vary. Water level may influence CO2 flux, but observations suggest a mobile peat surface with the water table. 2016 imagery from trail cameras will determine extent of peat/well casing movement with water level changes. Further interpretation of data trends will utilize HYDRUS-1D to quantify relationships under changing </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2009AGUFM.B51B0309S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2009AGUFM.B51B0309S">An analytical model for the distribution of CO2 sources and sinks, fluxes, and mean concentration within the roughness sub-layer</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Siqueira, M. B.; Katul, G. G. 2009-12-01 A one-dimensional analytical model that predicts foliage CO2 uptake rates, turbulent fluxes, and mean concentration throughout the roughness sub-layer (RSL), a layer that extends from the ground surface up to 5 times the canopy height (h), is proposed. The model combines the mean continuity equation for CO2 with first-order closure principles for turbulent fluxes and simplified physiological and radiative transfer schemes for foliage uptake. This combination results in a second-order ordinary differential equation in which it is imposed soil respiration (RE) as lower and CO2 concentration well above the RSL as upper boundary conditions. An inverse version of the model was tested against data sets from two contrasting ecosystems: a tropical forest (TF, h=40 m) and a managed irrigated rice canopy (RC, h=0.7 m) - with good agreement noted between modeled and measured mean CO2 concentration profiles within the entire RSL (see figure). Sensitivity analysis on the model parameters revealed a plausible scaling regime between them and a dimensionless parameter defined by the ratio between external (RE) and internal (stomatal conductance) characteristics controlling the CO2 exchange process. The model can be used to infer the thickness of the RSL for CO2 exchange, the inequality in zero-plane displacement between CO2 and momentum, and its consequences on modeled CO2 fluxes. A simplified version of the solution is well suited for being incorporated into large-scale climate models. Furthermore, the model framework here can be used to a priori estimate relative contributions from the soil surface and the atmosphere to canopy-air CO2 concentration thereby making it synergetic to stable isotopes studies. Panels a) and c): Profiles of normalized measured leaf area density distribution (a) for TF and RC, respectively. Continuous lines are the constant a used in the model and dashed lines represent data-derived profiles. Panels b) and d) are modeled and ensemble-averaged measured </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016GeoRL..4310240L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016GeoRL..4310240L">Modification of land-atmosphere interactions by CO2 effects: Implications for summer dryness and heat wave amplitude</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Lemordant, Léo.; Gentine, Pierre; Stéfanon, Marc; Drobinski, Philippe; Fatichi, Simone 2016-10-01 Plant stomata couple the energy, water, and carbon cycles. We use the framework of Regional Climate Modeling to simulate the 2003 European heat wave and assess how higher levels of surface CO2 may affect such an extreme event through land-atmosphere interactions. Increased CO2 modifies the seasonality of the water cycle through stomatal regulation and increased leaf area. As a result, the water saved during the growing season through higher water use efficiency mitigates summer dryness and the heat wave impact. Land-atmosphere interactions and CO2 fertilization together synergistically contribute to increased summer transpiration. This, in turn, alters the surface energy budget and decreases sensible heat flux, mitigating air temperature rise. Accurate representation of the response to higher CO2 levels and of the coupling between the carbon and water cycles is therefore critical to forecasting seasonal climate, water cycle dynamics, and to enhance the accuracy of extreme event prediction under future climate. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFMED41A0839B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFMED41A0839B">Effect of Wildfire on Sequoiadendron giganteum Growth and CO2 Flux</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Barwegen, S. 2016-12-01 Due to global warming, parts of the United States are becoming drier than ever before. In 2015, we surpassed 9 million acres burned by wildfires nationally (Rice 2015). Wildfires are most common in the Western United States due to drought, and the fact that the summer months are drier than other areas such as the East Coast, so there is a higher risk for wildland fires (Donegan 2016). These high-growth forests that are more frequently burned by wildfires each year are located near mountain ranges on the west side of the United States. They are important to tourism, contain many endangered species, and need to maintain the natural cycle of fire and regrowth for the continued success of the native plant life. This project investigated the effect of burnt soil on Sequoiadendron giganteum trees. Three were grown in burnt potting soil that had been roasted over a grill for 45 minutes (which is the average destructive fire time), and the other three were the control group in unburned potting soil. We assessed growth by measuring height, color, photosynthetically active radiation (PAR), and CO2 flux to evaluate the health of the trees in the two soil conditions. We noted that after two weeks the trunks of the trees growing in burnt soil began to brown in color, and they lost leaves. Over the course of the experiment, the trees growing in burnt soil had reduced levels of photosynthesis as compared to the unburned soil (as measured by the net change in CO2 concentration in a sealed chamber over the course of fifteen minutes intervals). On average, the trees growing in burnt soil had flux rates that were 19.59 ppm CO2 /min. more than those growing in unburned soil. In the dark reactions, the burnt soil flux was 54.5 ppm CO2/min., while the unburned soil averaged 40.5 ppm CO2/min. Our results help quantify the impact of fire on delicate ecosystems that are experiencing an increase in fire activity caused by global warming. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1245979','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1245979">Eddy Correlation Flux Measurement System Handbook</a> <a target="_blank" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Cook, D. R. 2016-01-01 The eddy correlation (ECOR) flux measurement system provides in situ, half-hour measurements of the surface turbulent fluxes of momentum, sensible heat, latent heat, and carbon dioxide (CO2) (and methane at one Southern Great Plains extended facility (SGP EF) and the North Slope of Alaska Central Facility (NSA CF). The fluxes are obtained with the eddy covariance technique, which involves correlation of the vertical wind component with the horizontal wind component, the air temperature, the water vapor density, and the CO2 concentration. The instruments used are: • a fast-response, three-dimensional (3D) wind sensor (sonic anemometer) to obtain the orthogonal wind componentsmore » and the speed of sound (SOS) (used to derive the air temperature) • an open-path infrared gas analyzer (IRGA) to obtain the water vapor density and the CO2 concentration, and • an open-path infrared gas analyzer (IRGA) to obtain methane density and methane flux at one SGP EF and at the NSA CF. The ECOR systems are deployed at the locations where other methods for surface flux measurements (e.g., energy balance Bowen ratio [EBBR] systems) are difficult to employ, primarily at the north edge of a field of crops. A Surface Energy Balance System (SEBS) has been installed collocated with each deployed ECOR system in SGP, NSA, Tropical Western Pacific (TWP), ARM Mobile Facility 1 (AMF1), and ARM Mobile Facility 2 (AMF2). The surface energy balance system consists of upwelling and downwelling solar and infrared radiometers within one net radiometer, a wetness sensor, and soil measurements. The SEBS measurements allow the comparison of ECOR sensible and latent heat fluxes with the energy balance determined from the SEBS and provide information on wetting of the sensors for data quality purposes. The SEBS at one SGP and one NSA site also support upwelling and downwelling PAR measurements to qualify those two locations as Ameriflux sites.« less </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.fs.usda.gov/treesearch/pubs/35420','TREESEARCH'); return false;" href="https://www.fs.usda.gov/treesearch/pubs/35420">LBA-ECO TG-07 Soil CO2 Flux by Automated Chamber, Para, Brazil: 2001-2003</a> <a target="_blank" href="http://www.fs.usda.gov/treesearch/">Treesearch</a> R.K. Varner; M.M. Keller 2009-01-01 Measurements of the soil-atmosphere flux of CO2 were made at the km 67 flux tower site in the Tapajos National Forest, Santarem, Para, Brazil. Eight chambers were set up to measure trace gas exchange between the soil and atmosphere about 5 times a day (during daylight and night) at this undisturbed forest site from April 2001 to April 2003. CO2 soil efflux data are... </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/12557686','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/12557686">[Responses of agricultural crops of free-air CO2 enrichment].</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Kimball, B A; Zhu, Jianguo; Cheng, Lei; Kobayashi, K; Bindi, M 2002-10-01 Over the past decade, free-air CO2 enrichment (FACE) experiments have been conducted on several agricultural crops: wheat(Triticum aestivum L.), perennial ryegrass (Lolium perenne), and rice(Oryza sativa L.) which are C3 grasses; sorghum (Sorghum bicolor (L.) Möench), a C4 grass; white clover (Trifolium repens), a C3 legume; potato (Solanum tuberosum L.), a C3 forb with tuber storage; and cotton (Gossypium hirsutum L.) and grape (Vitis vinifera L.) which are C3 woody perennials. Using reports from these experiments, the relative responses of these crops was discussed with regard to photosynthesis, stomatal conductance, canopy temperature, water use, water potential, leaf area index, shoot and root biomass accumulation, agricultural yield, radiation use efficiency, specific leaf area, tissue nitrogen concentration, nitrogen yield, carbohydrate concentration, phenology, soil microbiology, soil respiration, trace gas emissions, and soil carbon sequestration. Generally, the magnitude of these responses varied with the functional type of plant and with the soil nitrogen and water status. As expected, the elevated CO2 increased photosynthesis and biomass production and yield substantially in C3 species, but little in C4, and it decreased stomatal conductance and transpiration in both C3 and C4 species and greatly improved water-use efficiency in all the crops. Growth stimulations were as large or larger under water-stress compared to well-watered conditions. Growth stimulations of non-legumes were reduced at low soil nitrogen, whereas elevated CO2 strongly stimulated the growth of the clover legume both at ample and under low N conditions. Roots were generally stimulated more than shoots. Woody perennials had larger growth responses to elevated CO2, while at the same time, their reductions in stomatal conductance were smaller. Tissue nitrogen concentrations went down while carbohydrate and some other carbon-based compounds went up due to elevated CO2, with leaves and </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013AGUFM.B11F0421L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013AGUFM.B11F0421L">Carbon dioxide(CO2) and nitrous oxide (N2O) fluxes in an agro-ecosystems under changing physical and biological conditions</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Liang, L.; Eberwein, J.; Oikawa, P.; Jenerette, D.; Grantz, D. A. 2013-12-01 Liyin Liang1, Jennifer Eberwein1, Patty Oikawa1, Darrel Jenerette1, David Grantz1 1Department of Botany and Plant Sciences, University of California, Riverside, CA 92521, USA Carbon dioxide (CO2) and nitrous oxide (N2O) are the major greenhouse gases and together produce a strong positive radiative forcing in the atmosphere. The fluxes of CO2 and N2O from soil to atmosphere vary with physical and biological factors, e.g., temperature, soil moisture, pH value, soil organic carbon contents, microorganism communities and so on. Understanding the interactions among these factors is critical to estimation of CO2 and N2O emissions. We investigate these fluxes in an extreme production environment with very high maximum temperatures, at the agricultural experiment station of University of California-Desert Research Center in the Imperial Valley of southern California. In this research, we measured the CO2 and N2O fluxes from soil incubation under controlled laboratory conditions, in surface chambers under field conditions and by eddy covariance. We explore the variation of CO2 and N2O fluxes and relationship between them in this extreme biofuel production environment. The discrete chamber measurements showed that the N2O flux in our field sites is 2.39×0.70 μg N m-2 hr-1, with a 95% confidence interval (CI) from 0.86 to 3.92 μg N m-2 hr-1. Compared to the previous reported value (0.45~26.26 μg N m-2 hr-1) of N2O flux in California, the N2O flux from biofuel crop land is in the lower level, although more observations should be took to confirm it. The N2O flux also shows very high variability within a field of biomass Sorghum, ranging from 0.40 to 8.19 μg N m-2 hr-1 across 11 sites owning to the high variability of physical and biological factors. Soil incubation measurements will be conducted to identify the sources of this variability. The eddy covariance measurements will allow calculation of the CO2 and N2O emissions at the ecosystem level as a step in quantifying </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/25207956','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/25207956">Reducing the cost of Ca-based direct air capture of CO2.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Zeman, Frank 2014-10-07 Direct air capture, the chemical removal of CO2 directly from the atmosphere, may play a role in mitigating future climate risk or form the basis of a sustainable transportation infrastructure. The current discussion is centered on the estimated cost of the technology and its link to "overshoot" trajectories, where atmospheric CO2 levels are actively reduced later in the century. The American Physical Society (APS) published a report, later updated, estimating the cost of a one million tonne CO2 per year air capture facility constructed today that highlights several fundamental concepts of chemical air capture. These fundamentals are viewed through the lens of a chemical process that cycles between removing CO2 from the air and releasing the absorbed CO2 in concentrated form. This work builds on the APS report to investigate the effect of modifications to the air capture system based on suggestions in the report and subsequent publications. The work shows that reduced carbon electricity and plastic packing materials (for the contactor) may have significant effects on the overall price, reducing the APS estimate from $610 to $309/tCO2 avoided. Such a reduction does not challenge postcombustion capture from point sources, estimated at $80/tCO2, but does make air capture a feasible alternative for the transportation sector and a potential negative emissions technology. Furthermore, air capture represents atmospheric reductions rather than simply avoided emissions. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/26386629','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/26386629">The effects of grazing and watering on ecosystem CO2 fluxes vary by community phenology.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Han, Juanjuan; Li, Linghao; Chu, Housen; Miao, Yuan; Chen, Shiping; Chen, Jiquan 2016-01-01 Grazing profoundly influences vegetation and the subsequent carbon fluxes in various ecosystems. However, little effort has been made to explore the underlying mechanisms for phenological changes and their consequences on carbon fluxes at ecosystem level, especially under the coupled influences of human disturbances and climate change. Here, a manipulative experiment (2012-2013) was conducted to examine both the independent and interactive effects of grazing and watering on carbon fluxes across phenological phases in a desert steppe. Grazing advanced or delayed phenological timing, leading to a shortened green-up phase (GrP: 23.60 days) in 2013 and browning phase (BrP: 12.48 days) in 2012 from high grazing, and insignificant effects on the reproductive phase (ReP) in either year. High grazing significantly enhance carbon uptake, while light grazing reduce carbon uptake in ReP. Watering only delayed the browning time by 5.01 days in 2013, producing no significant effects on any phenophase. Watering promoted the net ecosystem exchange (NEE), ecosystem respiration (ER), and gross ecosystem productivity (GEP) only in the GrP. When calculating the yearly differences in phenophases and the corresponding carbon fluxes, we found that an extended GrP greatly enhanced NEE, but a prolonged ReP distinctly reduced it. The extended GrP also significantly promote GEP. Increases in growing season length appeared promoting ER, regardless of any phenophase. Additionally, the shifts in NEE appeared dependent of the variations in leaf area index (LAI). Copyright © 2015 Elsevier Inc. All rights reserved. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2007AGUFM.B23B1265S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2007AGUFM.B23B1265S">Carbonate Mineral Weathering Contributions to the HCO3- Flux from Headwater Mid-latitude Streams in the Face of Increasing Atmospheric CO2</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Szramek, K.; Ogrinc, N.; Walter, L. M. 2007-12-01 As anthropogenic liberated CO2 increases in the atmosphere, landscape level responses of the carbon cycle to perturbations associated with global warming are likely to be observed in carbonate bearing regions. Within physically open weathering environments, carbonate (calcite and dolomite) mineral solubility is proportional to pCO2 and inversely proportional to temperature, with the solubility of dolomite progressively greater than calcite below 25°C. Changes in weathering zone CO2 occur as CO2 drawdown is increased due to CO2 fertilization effects on plant growth, to warmer mean annual temperatures, or to land use changes. The rise in weathering zone CO2 will significantly augment the open system solubility of carbonate minerals and increase the DIC content of surface waters (unconfined groundwaters and rivers). The thermodynamic relationships between calcite and dolomite indicate the further need to examine the role of dolomite on the global riverine DIC budget. On a continental scale, the global weathering budget indicates the importance of northern hemisphere landmasses to riverine fluxes of Ca2+, Mg2+ and DIC as HCO3-. The results of a hydrogeochemical study of carbonate mineral equilibria and weathering fluxes for headwater streams within the Danube, the James and the St. Lawrence River Basins is presented. Available long-term geochemical and discharge data along with detailed catchment geochemical views of surface water and soil weathering zones were determined to examine the historical and current contribution of carbonate weathering to the geochemical fluctuations of the these headwater regions and the ability of these watersheds to maintain current conditions in the facing of increasing CO2. In order to gauge how these streams with variable climates, land use practices, lithologies, and weathering zone thicknesses compare to each other, river runoff and HCO3- concentrations are normalized to catchment area. The resulting carbonate weathering intensity on </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013ACPD...13.2243C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013ACPD...13.2243C">Improved simulation of group averaged CO2 surface concentrations using GEOS-Chem and fluxes from VEGAS</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Chen, Z. H.; Zhu, J.; Zeng, N. 2013-01-01 CO2 measurements have been combined with simulated CO2 distributions from a transport model in order to produce the optimal estimates of CO2 surface fluxes in inverse modeling. However one persistent problem in using model-observation comparisons for this goal relates to the issue of compatibility. Observations at a single site reflect all underlying processes of various scales that usually cannot be fully resolved by model simulations at the grid points nearest the site due to lack of spatial or temporal resolution or missing processes in models. In this article we group site observations of multiple stations according to atmospheric mixing regimes and surface characteristics. The group averaged values of CO2 concentration from model simulations and observations are used to evaluate the regional model results. Using the group averaged measurements of CO2 reduces the noise of individual stations. The difference of group averaged values between observation and modeled results reflects the uncertainties of the large scale flux in the region where the grouped stations are. We compared the group averaged values between model results with two biospheric fluxes from the model Carnegie-Ames-Stanford-Approach (CASA) and VEgetation-Global-Atmosphere-Soil (VEGAS) and observations to evaluate the regional model results. Results show that the modeling group averaged values of CO2 concentrations in all regions with fluxes from VEGAS have significant improvements for most regions. There is still large difference between two model results and observations for grouped average values in North Atlantic, Indian Ocean, and South Pacific Tropics. This implies possible large uncertainties in the fluxes there. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.B42C..03H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.B42C..03H">Response of surface CH4 and CO2 fluxes to whole ecosystem warming and elevated CO2 in a boreal black spruce peatland, northern Minnesota</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Hsieh, I. F.; Gill, A. L.; Finzi, A. 2017-12-01 Potential increase in peatland C losses by environmental change has been presented by impacting the balance of CO2 and CH4 sequestration and release. While temperature warming may accelerate the temperature-sensitive processes and release CO2 and CH4 from peat C stores, factors associated with warming and that associated with elevated CO2 concentration may alter the intrinsic characteristics of CO2 and CH4 emission from peatland. By leveraging Spruce and Peatland Responses Under Changing Environments (SPRUCE) experiment, we measured peat surface CO2 and CH4 fluxes and their i13C signatures across a gradient of warming temperatures in a boreal black spruce peat bog in 2015 and 2016 growing seasons. Elevated CO2 (eCO2) treatment was added to the warming experiment in June, 2016. Our results show both CH4 and CO2 flux increased with warming temperature in the two-year measurement period. Total emission for both gases were higher in 2016 with whole ecosystem warming than that in 2015 with deep peat heat warming. The 2016 increase in CO2 emission was significantly larger in the hummock microtopographic position compared to hollows. The opposite was true for CH4 fluxes, where the increase was strongest in the hollows. In fact, CH4 flux from hummocks declined in 2016 compared to 2015, suggesting lower overall rates of CH4 production and/or greater rates of methanotrophy. The increase (less depleted) in i13C -CH4 signatures suggest acetoclastic methanogensis increased its contribution to total CH4 production across the growing season and in response to experimental warming, while hydrogenotrophic methanogenesis dominated total CH4 production. On the contrary, results of i13C-CO2 show no significant change in the contribution of different sources to total CO2 emission through time or across warming temperature. On the other hand, i13C-CO2 signatures under CO2 fumigation in 2016 was significantly depleted since the eCO2 initiation, indicating a rapid increase in plant </li> <li> <a target="_blank" onclick="trackOutboundLink('http://hdl.handle.net/2060/20010022518','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20010022518">BOREAS TGB-5 CO2, CH4 and CO Chamber Flux Data Over the NSA</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Burke, Roger; Hall, Forrest G. (Editor); Conrad, Sara K. (Editor); Zepp, Richard 2000-01-01 The BOReal Ecosystem-Atmosphere Study Trace Gas Biogeochemistry (BOREAS TGB-5) team collected a variety of trace gas concentration and flux measurements at several NSA sites. This data set contains carbon dioxide (CO2), methane (CH4), and carbon monoxide (CO) chamber flux measurements conducted in 1994 at upland forest sites that experienced stand-replacement fires. These measurements were acquired to understand the impact of fires on soil biogeochemistry and related changes in trace gas exchange in boreal forest soils. Relevant ancillary data, including data concerning the soil temperature, solar irradiance, and information from nearby un-burned control sites, are included to provide a basis for modeling the regional impacts of fire and climate changes on trace gas biogeochemistry. The data are provided in tabular ASCII files. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29110454','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29110454">Metal-Organic Framework-Stabilized CO2/Water Interfacial Route for Photocatalytic CO2 Conversion.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Luo, Tian; Zhang, Jianling; Li, Wei; He, Zhenhong; Sun, Xiaofu; Shi, Jinbiao; Shao, Dan; Zhang, Bingxing; Tan, Xiuniang; Han, Buxing 2017-11-29 Here, we propose a CO 2 /water interfacial route for photocatalytic CO 2 conversion by utilizing a metal-organic framework (MOF) as both an emulsifier and a catalyst. The CO 2 reduction occurring at the CO 2 /water interface produces formate with remarkably enhanced efficiency as compared with that in conventional solvent. The route is efficient, facile, adjustable, and environmentally benign, which is applicable for the CO 2 transformation photocatalyzed by different kinds of MOFs. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://hdl.handle.net/2060/20110014594','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20110014594">Ocean Winds and Turbulent Air-Sea Fluxes Inferred From Remote Sensing</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Bourassa, Mark A.; Gille, Sarah T.; Jackson, Daren L.; Roberts, J. Brent; Wick, Gary A. 2010-01-01 Air-sea turbulent fluxes determine the exchange of momentum, heat, freshwater, and gas between the atmosphere and ocean. These exchange processes are critical to a broad range of research questions spanning length scales from meters to thousands of kilometers and time scales from hours to decades. Examples are discussed (section 2). The estimation of surface turbulent fluxes from satellite is challenging and fraught with considerable errors (section 3); however, recent developments in retrievals (section 3) will greatly reduce these errors. Goals for the future observing system are summarized in section 4. Surface fluxes are defined as the rate per unit area at which something (e.g., momentum, energy, moisture, or CO Z ) is transferred across the air/sea interface. Wind- and buoyancy-driven surface fluxes are called surface turbulent fluxes because the mixing and transport are due to turbulence. Examples of nonturbulent processes are radiative fluxes (e.g., solar radiation) and precipitation (Schmitt et al., 2010). Turbulent fluxes are strongly dependent on wind speed; therefore, observations of wind speed are critical for the calculation of all turbulent surface fluxes. Wind stress, the vertical transport of horizontal momentum, also depends on wind direction. Stress is very important for many ocean processes, including upper ocean currents (Dohan and Maximenko, 2010) and deep ocean currents (Lee et al., 2010). On short time scales, this horizontal transport is usually small compared to surface fluxes. For long-term processes, transport can be very important but again is usually small compared to surface fluxes. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2010AGUFM.U23B..06V','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2010AGUFM.U23B..06V">H2O and CO2 devolatilization in subduction zones: implications for the global water and carbon cycles (Invited)</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> van Keken, P. E.; Hacker, B. R.; Syracuse, E. M.; Abers, G. A. 2010-12-01 Subduction of sediments and altered oceanic crust functions as a major carbon sink. Upon subduction the carbon may be released by progressive metamorphic reactions, which can be strongly enhanced by free fluids. Quantification of the CO2 release from subducting slabs is important to determine the provenance of CO2 that is released by the volcanic arc and to constrain the flux of carbon to the deeper mantle. In recent work we used a global set of high resolution thermal models of subduction zones to predict the flux of H2O from the subducting slab (van Keken, Hacker, Syracuse, Abers, Subduction factory 4: Depth-dependent flux of H2O from subducting slabs worldwide, J. Geophys. Res., under review) which provides a new estimate of the dehydration efficiency of the global subducting system. It was found that mineralogically bound water can pass efficiently through old and fast subduction zones (such as in the western Pacific) but that warm subduction zones (such as Cascadia) see nearly complete dehydration of the subducting slab. The top of the slab is sufficiently hot in all subduction zones that the upper crust dehydrates significantly. The degree and depth of dehydration is highly diverse and strongly depends on (p,T) and bulk rock composition. On average about one third of subducted H2O reaches 240 km depth, carried principally and roughly equally in the gabbro and peridotite sections. The present-day global flux of H2O to the deep mantle translates to an addition of about one ocean mass over the age of the Earth. We extend the slab devolatilization work to carbon by providing an update to Gorman et al. (Geochem. Geophys. Geosyst, 2006), who quantified the effects of free fluids on CO2 release. The thermal conditions were based on three end-member subduction zones with linear interpolation to provide a global CO2 flux. We use the new high resolution and global set of models to provide higher resolution predictions for the provenance and pathways of CO2 release to </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017JMetR..31..363C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017JMetR..31..363C">Effects of optimized root water uptake parameterization schemes on water and heat flux simulation in a maize agroecosystem</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Cai, Fu; Ming, Huiqing; Mi, Na; Xie, Yanbing; Zhang, Yushu; Li, Rongping 2017-04-01 As root water uptake (RWU) is an important link in the water and heat exchange between plants and ambient air, improving its parameterization is key to enhancing the performance of land surface model simulations. Although different types of RWU functions have been adopted in land surface models, there is no evidence as to which scheme most applicable to maize farmland ecosystems. Based on the 2007-09 data collected at the farmland ecosystem field station in Jinzhou, the RWU function in the Common Land Model (CoLM) was optimized with scheme options in light of factors determining whether roots absorb water from a certain soil layer ( W x ) and whether the baseline cumulative root efficiency required for maximum plant transpiration ( W c ) is reached. The sensibility of the parameters of the optimization scheme was investigated, and then the effects of the optimized RWU function on water and heat flux simulation were evaluated. The results indicate that the model simulation was not sensitive to W x but was significantly impacted by W c . With the original model, soil humidity was somewhat underestimated for precipitation-free days; soil temperature was simulated with obvious interannual and seasonal differences and remarkable underestimations for the maize late-growth stage; and sensible and latent heat fluxes were overestimated and underestimated, respectively, for years with relatively less precipitation, and both were simulated with high accuracy for years with relatively more precipitation. The optimized RWU process resulted in a significant improvement of CoLM's performance in simulating soil humidity, temperature, sensible heat, and latent heat, for dry years. In conclusion, the optimized RWU scheme available for the CoLM model is applicable to the simulation of water and heat flux for maize farmland ecosystems in arid areas. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013PhDT.......178W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013PhDT.......178W">Aqueous turbulence structure immediately adjacent to the air - water interface and interfacial gas exchange</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Wang, Binbin Air-sea interaction and the interfacial exchange of gas across the air-water interface are of great importance in coupled atmospheric-oceanic environmental systems. Aqueous turbulence structure immediately adjacent to the air-water interface is the combined result of wind, surface waves, currents and other environmental forces and plays a key role in energy budgets, gas fluxes and hence the global climate system. However, the quantification of turbulence structure sufficiently close to the air-water interface is extremely difficult. The physical relationship between interfacial gas exchange and near surface turbulence remains insufficiently investigated. This dissertation aims to measure turbulence in situ in a complex environmental forcing system on Lake Michigan and to reveal the relationship between turbulent statistics and the CO2 flux across the air-water interface. The major objective of this dissertation is to investigate the physical control of the interfacial gas exchange and to provide a universal parameterization of gas transfer velocity from environmental factors, as well as to propose a mechanistic model for the global CO2 flux that can be applied in three dimensional climate-ocean models. Firstly, this dissertation presents an advanced measurement instrument, an in situ free floating Particle Image Velocimetry (FPIV) system, designed and developed to investigate the small scale turbulence structure immediately below the air-water interface. Description of hardware components, design of the system, measurement theory, data analysis procedure and estimation of measurement error were provided. Secondly, with the FPIV system, statistics of small scale turbulence immediately below the air-water interface were investigated under a variety of environmental conditions. One dimensional wave-number spectrum and structure function sufficiently close to the water surface were examined. The vertical profiles of turbulent dissipation rate were intensively studied </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29445143','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29445143">Dry habitats sustain high CO2 emissions from temporary ponds across seasons.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Obrador, Biel; von Schiller, Daniel; Marcé, Rafael; Gómez-Gener, Lluís; Koschorreck, Matthias; Borrego, Carles; Catalán, Núria 2018-02-14 Despite the increasing understanding of the magnitude and drivers of carbon gas emissions from inland waters, the relevance of water fluctuation and associated drying on their dynamics is rarely addressed. Here, we quantified CO 2 and CH 4 fluxes from a set of temporary ponds across seasons. The ponds were in all occasion net CO 2 emitters irrespective of the presence or absence of water. While the CO 2 fluxes were in the upper range of emissions for freshwater lentic systems, CH 4 fluxes were mostly undetectable. Dry habitats substantially contributed to these emissions and were always a source of CO 2 , whereas inundated habitats acted either as a source or a sink of atmospheric CO 2 along the year. Higher concentrations of coloured and humic organic matter in water and sediment were linked to higher CO 2 emissions. Composition of the sediment microbial community was related both to dissolved organic matter concentration and composition, but we did not find a direct link with CO 2 fluxes. The presence of methanogenic archaea in most ponds suggested the potential for episodic CH 4 production and emission. Our results highlight the need for spatially and temporally inclusive approaches that consider the dry phases and habitats to characterize carbon cycling in temporary systems. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_17");'>17</a></li> <li><a href="#" onclick='return showDiv("page_18");'>18</a></li> <li class="active">19</li> <li><a href="#" onclick='return showDiv("page_20");'>20</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_20" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_18");'>18</a></li> <li><a href="#" onclick='return showDiv("page_19");'>19</a></li> <li class="active">20</li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="381"> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFMOS42A..08S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFMOS42A..08S">Southern Ocean Carbon Dioxide and Oxygen Fluxes Detected by SOCCOM Biogeochemical Profiling Floats</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Sarmiento, J. L.; Bushinksy, S.; Gray, A. R. 2016-12-01 The Southern Ocean is known to play an important role in the global carbon cycle, yet historically our measurements of this remote region have been sparse and heavily biased towards summer. Here we present new estimates of air-sea fluxes of carbon dioxide and oxygen calculated with measurements from autonomous biogeochemical profiling floats. At high latitudes in and southward of the Antarctic Circumpolar Current, we find a significant flux of CO2 from the ocean to the atmosphere during 2014-2016, which is particularly enhanced during winter months. These results suggest that previous estimates may be biased towards stronger Southern Ocean CO2 uptake due to undersampling in winter. We examine various implications of having a source of CO2 that is higher than previous estimates. We also find that CO2:O2 flux ratios north of the Subtropical Front are positive, consistent with the fluxes being driven by changes in solubility, while south of the Polar Front biological processes and upwelling of deep water combine to produce a negative CO2:O2 flux ratio. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2008AGUFMOS22B..07M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2008AGUFMOS22B..07M">Wintertime Air-Sea Gas Transfer Rates and Air Injection Fluxes at Station Papa in the NE Pacific</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> McNeil, C.; Steiner, N.; Vagle, S. 2008-12-01 In recent studies of air-sea fluxes of N2 and O2 in hurricanes, McNeil and D'Asaro (2007) used a simplified model formulation of air-sea gas flux to estimate simultaneous values of gas transfer rate, KT, and air injection flux, VT. The model assumes air-sea gas fluxes at high to extreme wind speeds can be explained by a combination of two processes: 1) air injection, by complete dissolution of small bubbles drawn down into the ocean boundary layer by turbulent currents, and 2) near-surface equilibration processes, such as occurs within whitecaps. This analysis technique relies on air-sea gas flux estimates for two gases, N2 and O2, to solve for the two model parameters, KT and VT. We present preliminary results of similar analysis of time series data collected during winter storms at Station Papa in the NE Pacific during 2003/2004. The data show a clear increase in KT and VT with increasing NCEP derived wind speeds and acoustically measured bubble penetration depth. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29872104','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29872104">Soil water content effects on net ecosystem CO2 exchange and actual evapotranspiration in a Mediterranean semiarid savanna of Central Chile.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Meza, Francisco J; Montes, Carlo; Bravo-Martínez, Felipe; Serrano-Ortiz, Penélope; Kowalski, Andrew S 2018-06-05 Biosphere-atmosphere water and carbon fluxes depend on ecosystem structure, and their magnitudes and seasonal behavior are driven by environmental and biological factors. We studied the seasonal behavior of net ecosystem CO 2 exchange (NEE), Gross Primary Productivity (GPP), Ecosystem Respiration (RE), and actual evapotranspiration (ETa) obtained by eddy covariance measurements during two years in a Mediterranean Acacia savanna ecosystem (Acacia caven) in Central Chile. The annual carbon balance was -53 g C m -2 in 2011 and -111 g C m -2 in 2012, showing that the ecosystem acts as a net sink of CO 2 , notwithstanding water limitations on photosynthesis observed in this particularly dry period. Total annual ETa was of 128 mm in 2011 and 139 mm in 2012. Both NEE and ETa exhibited strong seasonality with peak values recorded in the winter season (July to September), as a result of ecosystem phenology, soil water content and rainfall occurrence. Consequently, the maximum carbon assimilation rate occurred in wintertime. Results show that soil water content is a major driver of GPP and RE, defining their seasonal patterns and the annual carbon assimilation capacity of the ecosystem, and also modulating the effect that solar radiation and air temperature have on NEE components at shorter time scales. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.B43E2180T','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.B43E2180T">CO2 and CH4 fluxes in a Spartina salt marsh and brackish Phragmites marsh in Massachusetts</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Tang, J.; Wang, F.; Kroeger, K. D.; Gonneea, M. E. 2017-12-01 Coastal salt marshes play an important role in global and regional carbon cycling. Tidally restricted marshes reduce salinity and provide a habitat suitable for Phragmites invasion. We measured greenhouse gas (GHG) emissions (CO2 and CH4) continuously with the eddy covariance method and biweekly with the static chamber method in a Spartina salt marsh and a Phragmites marsh on Cape Cod, Massachusetts, USA. We did not find significant difference in CO2 fluxes between the two sites, but the CH4 fluxes were much higher in the Phragmites site than the Spartina marsh. Temporally, tidal cycles influence the CO2 and CH4 fluxes in both sites. We found that the salt marsh was a significant carbon sink when CO2 and CH4 fluxes were combined. Restoring tidally restricted marshes will significantly reduce CH4 emissions and provide a strong ecosystem carbon service. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2006JCrGr.289..605W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2006JCrGr.289..605W">Flux growth of high-quality CoFe 2O 4 single crystals and their characterization</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Wang, W. H.; Ren, X. 2006-04-01 We report the growth of high-quality CoFe 2O 4 single crystals using a borax flux method. The crystals were characterized by powder X-ray diffraction, electron probe microanalysis and Raman spectroscopy. We found the crystals are flux-free and highly homogeneous in composition. X-ray rocking curves of the CoFe 2O 4 single crystals showed a full-width at half-maximum of 0.15°. The saturation magnetization of the CoFe 2O 4 single crystals was measured to be 90 emu/g or equivalently 3.65 μ B/f.u. at 5 K. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.B51I1941B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.B51I1941B">A Spatial-Temporal Comparison of Lake Mendota CO2 Fluxes and Collection Methods</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Baldocchi, A. K.; Reed, D. E.; Desai, A. R.; Loken, L. C.; Schramm, P.; Stanley, E. H. 2017-12-01 Monitoring of carbon fluxes at the lake/atmosphere interface can help us determine baselines from which to understand responses in both space and time that may result from our warming climate or increasing nutrient inputs. Since recent research has shown lakes to be hotspots of global carbon cycling, it is important to quantify carbon sink and source dynamics as well as to verify observations between multiple methods in the context of long-term data collection efforts. Here we evaluate a new method for measuring space and time variation in CO2 fluxes based on novel speedboat-based collection method of aquatic greenhouse gas concentrations and a flux computation and interpolation algorithm. Two-hundred and forty-nine consecutive days of spatial flux maps over the 2016 open ice period were compared to ongoing eddy covariance tower flux measurements on the shore of Lake Mendota, Wisconsin US using a flux footprint analysis. Spatial and temporal alignments of the fluxes from these two observational datasets revealed both similar trends from daily to seasonal timescales as well as biases between methods. For example, throughout the Spring carbon fluxes showed strong correlation although off by an order of magnitude. Isolating physical patterns of agreement between the two methods of the lake/atmosphere CO2 fluxes allows us to pinpoint where biology and physical drivers contribute to the global carbon cycle and help improve modelling of lakes and utilize lakes as leading indicators of climate change. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/20675550','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/20675550">Hypercarbic cardiorespiratory reflexes in the facultative air-breathing fish jeju (Hoplerythrinus unitaeniatus): the role of branchial CO2 chemoreceptors.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> de Lima Boijink, Cheila; Florindo, Luiz Henrique; Leite, Cleo A Costa; Kalinin, Ana Lúcia; Milsom, William K; Rantin, Francisco Tadeu 2010-08-15 The aim of the present study was to determine the roles that externally versus internally oriented CO(2)/H(+)-sensitive chemoreceptors might play in promoting cardiorespiratory responses to environmental hypercarbia in the air-breathing fish, Hoplerythrinus unitaeniatus (jeju). Fish were exposed to graded hypercarbia (1, 2.5, 5, 10 and 20% CO(2)) and also to graded levels of environmental acidosis (pH approximately 7.0, 6.0, 5.8, 5.6, 5.3 and 4.7) equal to the pH levels of the hypercarbic water to distinguish the relative roles of CO(2) versus H(+). We also injected boluses of CO(2)-equilibrated solutions (5, 10 and 20% CO(2)) and acid solutions equilibrated to the same pH as the CO(2) boluses into the caudal vein (internal) and buccal cavity (external) to distinguish between internal and external stimuli. The putative location of the chemoreceptors was determined by bilateral denervation of branches of cranial nerves IX (glossopharyngeal) and X (vagus) to the gills. The data indicate that the chemoreceptors eliciting bradycardia, hypertension and gill ventilatory responses (increased frequency and amplitude) to hypercarbia are exclusively branchial, externally oriented and respond specifically to changes in CO(2) and not H(+). Those involved in producing the cardiovascular responses appeared to be distributed across all gill arches while those involved in the gill ventilatory responses were located primarily on the first gill arch. Higher levels of aquatic CO(2) depressed gill ventilation and stimulated air breathing. The chemoreceptors involved in producing air breathing in response to hypercarbia also appeared to be branchial, distributed across all gill arches and responded specifically to changes in aquatic CO(2). This would suggest that chemoreceptor groups with different orientations (blood versus water) are involved in eliciting air-breathing responses to hypercarbia in jeju. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70176205','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70176205">Experimental warming in a dryland community reduced plant photosynthesis and soil CO2 efflux although the relationship between the fluxes remained unchanged</a> <a target="_blank" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Wertin, Timothy M.; Belnap, Jayne; Reed, Sasha C. 2016-01-01 1. Drylands represent our planet's largest terrestrial biome and, due to their extensive area, maintain large stocks of carbon (C). Accordingly, understanding how dryland C cycling will respond to climate change is imperative for accurately forecasting global C cycling and future climate. However, it remains difficult to predict how increased temperature will affect dryland C cycling, as substantial uncertainties surround the potential responses of the two main C fluxes: plant photosynthesis and soil CO2 efflux. In addition to a need for an improved understanding of climate effects on individual dryland C fluxes, there is also notable uncertainty regarding how climate change may influence the relationship between these fluxes.2. To address this important knowledge gap, we measured a growing season's in situphotosynthesis, plant biomass accumulation, and soil CO2 efflux of mature Achnatherum hymenoides (a common and ecologically important C3 bunchgrass growing throughout western North America) exposed to ambient or elevated temperature (+2°C above ambient, warmed via infrared lamps) for three years.3. The 2°C increase in temperature caused a significant reduction in photosynthesis, plant growth, and soil CO2 efflux. Of important note, photosynthesis and soil respiration appeared tightly coupled and the relationship between these fluxes was not altered by the elevated temperature treatment, suggesting C fixation's strong control of both above-ground and below-ground dryland C cycling. Leaf water use efficiency was substantially increased in the elevated temperature treatment compared to the control treatment.4. Taken together, our results suggest notable declines in photosynthesis with relatively subtle warming, reveal strong coupling between above- and below-ground C fluxes in this dryland, and highlight temperature's strong effect on fundamental components of dryland C and water cycles. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://www.ars.usda.gov/research/publications/publication/?seqNo115=309452','TEKTRAN'); return false;" href="http://www.ars.usda.gov/research/publications/publication/?seqNo115=309452">Changes in fluxes of heat, H2O, CO2 caused by a large wind farm</a> <a target="_blank" href="https://www.ars.usda.gov/research/publications/find-a-publication/">USDA-ARS?s Scientific Manuscript database</a> The Crop Wind Energy Experiment (CWEX) provides a platform to investigate the effect of wind turbines and large wind farms on surface fluxes of momentum, heat, moisture and carbon dioxide (CO2). In 2010 and 2011, eddy covariance flux stations were installed between two lines of turbines at the south... </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMIN13B0074H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMIN13B0074H">Comparisons of a Quantum Annealing and Classical Computer Neural Net Approach for Inferring Global Annual CO2 Fluxes over Land</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Halem, M.; Radov, A.; Singh, D. 2017-12-01 Investigations of mid to high latitude atmospheric CO2 show growing amplitudes in seasonal variations over the past several decades. Recent high-resolution satellite measurements of CO2 concentration are now available for three years from the Orbiting Carbon Observatory-2. The Atmospheric Radiation Measurement (ARM) program of DOE has been making long-term CO2-flux measurements (in addition to CO2 concentration and an array of other meteorological quantities) at several towers and mobile sites located around the globe at half-hour frequencies. Recent papers have shown CO2 fluxes inferred by assimilating CO2 observations into ecosystem models are largely inconsistent with station observations. An investigation of how the biosphere has reacted to changes in atmospheric CO2 is essential to our understanding of potential climate-vegetation feedbacks. Thus, new approaches for calculating CO2-flux for assimilation into land surface models are necessary for improving the prediction of annual carbon uptake. In this study, we calculate and compare the predicted CO2 fluxes results employing a Feed Forward Backward Propagation Neural Network model on two architectures, (i) an IBM Minsky Computer node and (ii) a hybrid version of the ARC D-Wave quantum annealing computer. We compare the neural net results of predictions of CO2 flux from ARM station data for three different DOE ecosystem sites; an arid plains near Oklahoma City, a northern arctic site at Barrows AL, and a tropical rainforest site in the Amazon. Training times and predictive results for the calculating annual CO2 flux for the two architectures for each of the three sites are presented. Comparative results of predictions as measured by RMSE and MAE are discussed. Plots and correlations of observed vs predicted CO2 flux are also presented for all three sites. We show the estimated training times for quantum and classical calculations when extended to calculating global annual Carbon Uptake over land. We also </li> <li> <a target="_blank" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70029353','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70029353">CO2 dynamics in the Amargosa Desert: Fluxes and isotopic speciation in a deep unsaturated zone</a> <a target="_blank" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Walvoord, Michelle Ann; Striegl, Robert G.; Prudic, David E.; Stonestrom, David A. 2005-01-01 Natural unsaturated-zone gas profiles at the U.S. Geological Survey's Amargosa Desert Research Site, near Beatty, Nevada, reveal the presence of two physically and isotopically distinct CO2 sources, one shallow and one deep. The shallow source derives from seasonally variable autotrophic and heterotrophic respiration in the root zone. Scanning electron micrograph results indicate that at least part of the deep CO2 source is associated with calcite precipitation at the 110-m-deep water table. We use a geochemical gas-diffusion model to explore processes of CO2 production and behavior in the unsaturated zone. The individual isotopic species 12CO2, 13CO2, and 14CO2 are treated as separate chemical components that diffuse and react independently. Steady state model solutions, constrained by the measured δ13C (in CO2), and δ14C (in CO2) profiles, indicate that the shallow CO2 source from root and microbial respiration composes ∼97% of the annual average total CO2 production at this arid site. Despite the small contribution from deep CO2 production amounting to ∼0.1 mol m−2 yr−1, upward diffusion from depth strongly influences the distribution of CO2 and carbon isotopes in the deep unsaturated zone. In addition to diffusion from deep CO2 production, 14C exchange with a sorbed CO2 phase is indicated by the modeled δ14C profiles, confirming previous work. The new model of carbon-isotopic profiles provides a quantitative approach for evaluating fluxes of carbon under natural conditions in deep unsaturated zones. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/15825257','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/15825257">Effects of air velocity on photosynthesis of plant canopies under elevated CO2 levels in a plant culture system.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Kitaya, Y; Shibuya, T; Yoshida, M; Kiyota, M 2004-01-01 To obtain basic data for adequate air circulation for promoting plant growth in closed plant production modules in bioregenerative life support systems in space, effects of air velocities ranging from 0.1 to 0.8 m s-1 on photosynthesis in tomato seedlings canopies were investigated under atmospheric CO2 concentrations of 0.4 and 0.8 mmol mol-1. The canopy of tomato seedlings on a plug tray (0.4 x 0.4 m2) was set in a wind-tunnel-type chamber (0.6 x 0.4 x 0.3 m3) installed in a semi-closed-type assimilation chamber (0.9 x 0.5 x 0.4 m3). The net photosynthetic rate in the plant canopy was determined with the differences in CO2 concentrations between the inlet and outlet of the assimilation chamber multiplied by the volumetric air exchange rate of the chamber. Photosynthetic photon flux (PPF) on the plant canopy was kept at 0.25 mmol m-2 s-1, air temperature at 23 degrees C and relative humidity at 55%. The leaf area indices (LAIs) of the plant canopies were 0.6-2.5 and plant heights were 0.05-0.2 m. The net photosynthetic rate of the plant canopy increased with increasing air velocities inside plant canopies and saturated at 0.2 m s-1. The net photosynthetic rate at the air velocity of 0.4 m s-1 was 1.3 times that at 0.1 m s-1 under CO2 concentrations of 0.4 and 0.8 mmol mol-1. The net photosynthetic rate under CO2 concentrations of 0.8 mmol mol-1 was 1.2 times that under 0.4 mmol mol-1 at the air velocity ranging from 0.1 to 0.8 m s-1. The results confirmed the importance of controlling air movement for enhancing the canopy photosynthesis under an elevated CO2 level as well as under a normal CO2 level in the closed plant production modules. c2004 COSPAR. Published by Elsevier Ltd. All rights reserved. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2005AGUFM.B33E1085H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2005AGUFM.B33E1085H">Simultaneous Micrometeorological Flux Observations of CO2 and CH4 at a Sub-Arctic Black-Spruce Forest in Alaska</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Harazono, Y.; Ueyama, M.; Miyata, A. 2005-12-01 Carbon dioxide (CO2) and methane (CH4) fluxes were measured at a black spruce forest over discontinuous permafrost in central Alaska since November 2002. CO2 flux was measured by open-path eddy correlation system and CH4 flux was measured by gradient method continuously. CO2 uptake was observed during daytime after DOY 60 when the forest floor was snow-covered with low temperature (<-10 °C). At the moment, CH4 flux was negative (uptake) during daytime and nearing to zero at night, which varied with surface temperature. During snow melt and following permafrost thawing periods (around DOY 110-140, 2003), nocturnal CO2 efflux was larger than daytime uptake resulted in a daily CO2 source, and CH4 flux became small positive in daytime and nearing zero at night resulted in a weak daily CH4 source. After DOY 140 in 2003, CO2 flux was strong uptake and the maximum level was 1.0 g m-2 h-1 in late July around 10:30h when 3 hr earlier than solar noon. During mid summer (DOY 180-230, 2003), daytime CH4 uptake was weak and was near zero at night resulted in a weak daily CH4 sink. 2004 was low snow fall and draught summer, the seasonal patterns of CO2 and CH4 fluxes shifted more than 3-weeks earlier than that in 2003, resulted in high CO2 and CH4 emissions in early summer. Daily amount of CH4 flux in mid summer 2003 and 2004 were 1.2 and 0.5 mg CH4 m-2 d-1, respectively. Sum of observed NEE and CO2 storage term within the canopy, NEP were -482 and -366.6 gCO2 m-2 y-1 in 2003 and 2004. However, application of u* filtering correction made NEP reduce to the ranges between -434.8 and -315.9 gCO2 m-2 y-1 (under u<0.05 ms-1 and u<0.2 ms-1) in 2003 and to -282.5 and -215.9 gCO2 m-2 y-1 in 2004. The low NEP in 2004 was caused by high temperature and low precipitation during growing season. CH4 emission was also higher in 2004. CO2 and CH4 exchanges at sub-arctic forest were quite sensitive to draught and summer temperature. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28841262','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28841262">Measuring 13 C-enriched CO2 in air with a cavity ring-down spectroscopy gas analyser: Evaluation and calibration.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Dickinson, Dane; Bodé, Samuel; Boeckx, Pascal 2017-11-30 Cavity ring-down spectroscopy (CRDS) is becoming increasingly popular for δ 13 C-CO 2 analysis of air. However, little is known about the effect of high 13 C abundances on the performance of CRDS. Overlap between 12 CO 2 and 13 CO 2 spectral lines may adversely affect isotopic-CO 2 CRDS measurements of 13 C-enriched samples. Resolving this issue is important so that CRDS analysers can be used in CO 2 flux studies involving 13 C-labelled tracers. We tested a Picarro G2131-i CRDS isotopic-CO 2 gas analyser with specialty gravimetric standards of widely varying 13 C abundance (from natural to 20.1 atom%) and CO 2 mole fraction (xCO 2 : <0.1 to 2116 ppm) in synthetic air. The presence of spectroscopic interference between 12 CO 2 and 13 CO 2 bands was assessed by analysing errors in measurements of the standards. A multi-component calibration strategy was adopted, incorporating isotope ratio and mole fraction data to ensure accuracy and consistency in corrected values of δ 13 C-CO 2 , x 12 CO 2 , and x 13 CO 2 . CRDS measurements of x 13 CO 2 were found to be accurate throughout the tested range (<0.005 to 100 ppm). On the other hand, spectral cross-talk in x 12 CO 2 measurements of standards containing elevated levels of 13 CO 2 led to inaccuracy in x 12 CO 2 , total-xCO 2 (x 12 CO 2 + x 13 CO 2 ), and δ 13 C-CO 2 data. An empirical relationship for x 12 CO 2 measurements that incorporated the 13 C/ 12 C isotope ratio (i.e. 13 CO 2 / 12 CO 2 , RCO2) as a secondary (non-linear) variable was found to compensate for the perturbations, and enabled accurate instrument calibration for all CO 2 compositions covered by our standard gases. 13 C-enrichement in CO 2 leads to minor errors in CRDS measurements of x 12 CO 2 . We propose an empirical correction for measurements of 13 C-enriched CO 2 in air by CRDS instruments such as the Picarro G2131-i. Copyright © 2017 John Wiley & Sons, Ltd. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1156852','SCIGOV-DOEDE'); return false;" href="https://www.osti.gov/servlets/purl/1156852">CO2 and CH4 Fluxes across Polygon Geomorphic Types, Barrow, Alaska, 2006-2010</a> <a target="_blank" href="http://www.osti.gov/dataexplorer">DOE Data Explorer</a> Tweedie,Craig; Lara, Mark 2014-09-17 Carbon flux data are reported as Net Ecosystem Exchange (NEE), Gross Ecosystem Exchange (GEE), Ecosystem Respiration (ER), and Methane (CH4) flux. Measurements were made at 82 plots across various polygon geomorphic classes at research sites on the Barrow Environmental Observatory (BEO), the Biocomplexity Experiment site on the BEO, and the International Biological Program (IBP) site a little west of the BEO. This product is a compilation of data from 27 plots as presented in Lara et al. (2012), data from six plots presented in Olivas et al. (2010); and from 49 plots described in (Lara et al. 2014). Measurements were made during the peak of the growing seasons during 2006 to 2010. At each of the measurement plots (except Olivas et al., 2010) four different thicknesses of shade cloth were used to generate CO2 light response curves. Light response curves were used to normalize photosynthetically active radiation that is diurnally variable to a peak growing season average ~400 umolm-2sec-1. At the Olivas et al. (2010) plots, diurnal patterns were characterized by repeated sampling. CO2 measurements were made using a closed-chamber photosynthesis system and CH4 measurements were made using a photo-acoustic multi-gas analyzer. In addition, plot-level measurements for thaw depth (TD), water table depth (WTD), leaf area index (LAI), and normalized difference vegetation index (NDVI) are summarized by geomorphic polygon type. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AtmEn.143..164W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AtmEn.143..164W">Temporal variability in the sources and fluxes of CO2 in a residential area in an evergreen subtropical city</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Weissert, L. F.; Salmond, J. A.; Turnbull, J. C.; Schwendenmann, L. 2016-10-01 Measurements of CO2 fluxes in temperate climates have shown that urban areas are a net source of CO2 and that photosynthetic CO2 uptake is generally not sufficient to offset local CO2 emissions. However, little is known about the role of vegetation in cities where biogenic CO2 uptake is not limited to a 2-8 months growing season. This study used the eddy covariance technique to quantify the atmospheric CO2 fluxes over a period of 12 months in a residential area in subtropical Auckland, New Zealand, where the vegetation cover (surface cover fraction: 47%) is dominated by evergreen vegetation. Radiocarbon isotope measurements of CO2 were conducted at three different times of the day (06:00-09:00, 12:00-15:00, 01:00-04:00) for four consecutive weekdays in summer and winter to differentiate anthropogenic sources of CO2 (fossil fuel combustion) from biogenic sources (ecosystem respiration, combustion of biofuel/biomass). The results reveal previously unreported patterns for CO2 fluxes, with no seasonal variability and negative (net uptake) CO2 midday fluxes throughout the year, demonstrating photosynthetic uptake by the evergreen vegetation all year-round. The winter radiocarbon measurements showed that 85% of the CO2 during the morning rush hour was attributed to fossil fuel emissions, when wind was from residential areas. However, for all other time periods radiocarbon measurements showed that fossil fuel combustion was not a large source of CO2, suggesting that biogenic processes likely dominate CO2 fluxes at this residential site. Overall, our findings highlight the importance of vegetation in residential areas to mitigate local CO2 emissions, particularly in cities with a climate that allows evergreen vegetation to maintain high photosynthetic rates over winter. As urban areas grow, urban planners need to consider the role of urban greenspace to mitigate urban CO2 emissions. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.fs.usda.gov/treesearch/pubs/23725','TREESEARCH'); return false;" href="https://www.fs.usda.gov/treesearch/pubs/23725">Seasonal patterns in soil surface CO2 flux under snow cover in 50 and 300 year old subalpine forests</a> <a target="_blank" href="http://www.fs.usda.gov/treesearch/">Treesearch</a> Robert M. Hubbard; Michael G. Ryan; Kelly Elder; Charles C. Rhoades 2005-01-01 Soil CO2 flux can contribute as much as 60-80% of total ecosystem respiration in forests. Although considerable research has focused on quantifying this flux during the growing season, comparatively little effort has focused on non-growing season fluxes. We measured soil CO2 efflux through snow in 50 and 300 year old subalpine forest stands near Fraser CO. Our... </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AGUFM.B33G..07M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AGUFM.B33G..07M">Soil carbon content and CO2 flux along a hydrologic gradient in a High-Arctic tundra lake basin, Northwest Greenland</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> McKnight, J.; Klein, E. S.; Welker, J. M.; Schaeffer, S. M.; Franklin, M. 2015-12-01 High Arctic landscapes are composed of watershed basins that vary in size and ecohydrology, but typically have a plant community complex that ranges from dry tundra to moist tundra to wet sedge systems along water body shorelines. The spatial extent of these plant communities reflects mean annual soil moisture and temperature, and is vulnerable to changes in climate conditions. Soil moisture and temperature significantly influence organic matter microbial activity and decomposition, and can affect the fate of soil carbon in tundra soils. Consequently, due to the unique soil carbon differences between tundra plant communities, shifts in their spatial extent may drive future High Arctic biosphere-atmosphere interactions. Understanding this terrestrial-atmosphere trace gas feedback, however, requires quantification of the rates and patterns of CO2 exchange along soil moisture gradients and the associated soil properties. In summer of 2015, soil CO2 flux rate, soil moisture and temperature were measured along a soil moisture gradient spanning three vegetation zones (dry tundra, wet tundra, and wet grassland) in a snow melt-fed lake basin near Thule Greenland. Mean soil temperature during the 2015 growing season was greater in dry tundra than in wet tundra and wet grassland (13.0 ± 1.2, 7.8 ± 0.8, and 5.5 ± 0.9°C, respectively). Mean volumetric soil moisture differed among all three vegetation zones where the soil moisture gradient ranged from 9 % (dry tundra) to 34 % (wet tundra) to 51 % (wet grassland). Mean soil CO2 flux was significantly greater in the wet grassland (1.7 ± 0.1 μmol m-2 s-1) compared to wet tundra (0.9 ± 0.2 μmol m-2 s-1) and dry tundra (1.2 ± 0.2 μmol m-2 s-1). Soil CO2 flux increased and decreased with seasonal warming and cooling of soil temperature. Although soil temperature was an important seasonal driver of soil CO2 flux rates, differences in mean seasonal soil CO2 flux rates among vegetation zones appeared to be a function of the </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017GBioC..31.1192G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017GBioC..31.1192G">Global evaluation of particulate organic carbon flux parameterizations and implications for atmospheric pCO2</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Gloege, Lucas; McKinley, Galen A.; Mouw, Colleen B.; Ciochetto, Audrey B. 2017-07-01 The shunt of photosynthetically derived particulate organic carbon (POC) from the euphotic zone and deep remineralization comprises the basic mechanism of the "biological carbon pump." POC raining through the "twilight zone" (euphotic depth to 1 km) and "midnight zone" (1 km to 4 km) is remineralized back to inorganic form through respiration. Accurately modeling POC flux is critical for understanding the "biological pump" and its impacts on air-sea CO2 exchange and, ultimately, long-term ocean carbon sequestration. Yet commonly used parameterizations have not been tested quantitatively against global data sets using identical modeling frameworks. Here we use a single one-dimensional physical-biogeochemical modeling framework to assess three common POC flux parameterizations in capturing POC flux observations from moored sediment traps and thorium-234 depletion. The exponential decay, Martin curve, and ballast model are compared to data from 11 biogeochemical provinces distributed across the globe. In each province, the model captures satellite-based estimates of surface primary production within uncertainties. Goodness of fit is measured by how well the simulation captures the observations, quantified by bias and the root-mean-square error and displayed using "target diagrams." Comparisons are presented separately for the twilight zone and midnight zone. We find that the ballast hypothesis shows no improvement over a globally or regionally parameterized Martin curve. For all provinces taken together, Martin's b that best fits the data is [0.70, 0.98]; this finding reduces by at least a factor of 3 previous estimates of potential impacts on atmospheric pCO2 of uncertainty in POC export to a more modest range [-16 ppm, +12 ppm]. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2002EGSGA..27.3717S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2002EGSGA..27.3717S">The Coca-campaign: An Attempt To Derive The Carbon Exchange of A Forested Region Using Airborne Co2 and Co Observations</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Schmitgen, S.; Ciais, P.; Geiß, H.; Kley, D.; Neininger, B.; Baeumle, M.; Fuchs, W.; Brunet, Y. As part of the project COCA an attempt was made to measure the daytime biogenic CO2 fluxes over a forest area (about 15 by 30 km). This campaign took place around the CARBOEUROFLUX site "Le Bray" (Pinus pinaster) close to Bordeaux in France end of June 2001. Based on continuous airborne CO2, H2O and CO flux and concen- tration measurements a Lagrangian budgeting approach was chosen for the determi- nation of the regional CO2 fluxes. The objective is to determine the CO2 uptake of the extended forest area from the CO2/CO gradients up- and downwind of the ecosystem, using CO as air mass tracer and such eliminating the influence of anthropogenic CO2 advected into the area. First results will be shown of a flight on June 23rd, where fair wind speeds (about 5 m/s) and a low CBL height led to the observation of a clear decrease in CO2 at the downwind flight stacks with basically constant CO concentrations. For other flights with very low wind speeds, local effects dominate the observa- tions leading to a larger variability in the observations. Both, correlations and anti- correlations of CO2 with the anthropogenic tracer CO have been observed. Positive correlations indicate fresh plumes of anthropogenic CO2. Negative correlations are indicative of entrainment of free tropospheric air, that was marked by relatively higher CO2 and lower CO concentrations than the average CBL concentrations. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_18");'>18</a></li> <li><a href="#" onclick='return showDiv("page_19");'>19</a></li> <li class="active">20</li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_21" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_19");'>19</a></li> <li><a href="#" onclick='return showDiv("page_20");'>20</a></li> <li class="active">21</li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li><a href="#" onclick='return showDiv("page_23");'>23</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="401"> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017ACP....17.4781F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017ACP....17.4781F">Consistent regional fluxes of CH4 and CO2 inferred from GOSAT proxy XCH4 : XCO2 retrievals, 2010-2014</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Feng, Liang; Palmer, Paul I.; Bösch, Hartmut; Parker, Robert J.; Webb, Alex J.; Correia, Caio S. C.; Deutscher, Nicholas M.; Domingues, Lucas G.; Feist, Dietrich G.; Gatti, Luciana V.; Gloor, Emanuel; Hase, Frank; Kivi, Rigel; Liu, Yi; Miller, John B.; Morino, Isamu; Sussmann, Ralf; Strong, Kimberly; Uchino, Osamu; Wang, Jing; Zahn, Andreas 2017-04-01 We use the GEOS-Chem global 3-D model of atmospheric chemistry and transport and an ensemble Kalman filter to simultaneously infer regional fluxes of methane (CH4) and carbon dioxide (CO2) directly from GOSAT retrievals of XCH4 : XCO2, using sparse ground-based CH4 and CO2 mole fraction data to anchor the ratio. This work builds on the previously reported theory that takes into account that (1) these ratios are less prone to systematic error than either the full-physics data products or the proxy CH4 data products; and (2) the resulting CH4 and CO2 fluxes are self-consistent. We show that a posteriori fluxes inferred from the GOSAT data generally outperform the fluxes inferred only from in situ data, as expected. GOSAT CH4 and CO2 fluxes are consistent with global growth rates for CO2 and CH4 reported by NOAA and have a range of independent data including new profile measurements (0-7 km) over the Amazon Basin that were collected specifically to help validate GOSAT over this geographical region. We find that large-scale multi-year annual a posteriori CO2 fluxes inferred from GOSAT data are similar to those inferred from the in situ surface data but with smaller uncertainties, particularly over the tropics. GOSAT data are consistent with smaller peak-to-peak seasonal amplitudes of CO2 than either the a priori or in situ inversion, particularly over the tropics and the southern extratropics. Over the northern extratropics, GOSAT data show larger uptake than the a priori but less than the in situ inversion, resulting in small net emissions over the year. We also find evidence that the carbon balance of tropical South America was perturbed following the droughts of 2010 and 2012 with net annual fluxes not returning to an approximate annual balance until 2013. In contrast, GOSAT data significantly changed the a priori spatial distribution of CH4 emission with a 40 % increase over tropical South America and tropical Asia and a smaller decrease over Eurasia and temperate </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012AGUFM.B51B0539D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012AGUFM.B51B0539D">Constraining Gas Diffusivity-Soil Water Content Relationships in Forest Soils Using Surface Chamber Fluxes and Depth Profiles of Multiple Trace Gases</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Dore, J. E.; Kaiser, K.; Seybold, E. C.; McGlynn, B. L. 2012-12-01 Forest soils are sources of carbon dioxide (CO2) to the atmosphere and can act as either sources or sinks of methane (CH4) and nitrous oxide (N2O), depending on redox conditions and other factors. Soil moisture is an important control on microbial activity, redox conditions and gas diffusivity. Direct chamber measurements of soil-air CO2 fluxes are facilitated by the availability of sensitive, portable infrared sensors; however, corresponding CH4 and N2O fluxes typically require the collection of time-course physical samples from the chamber with subsequent analyses by gas chromatography (GC). Vertical profiles of soil gas concentrations may also be used to derive CH4 and N2O fluxes by the gradient method; this method requires much less time and many fewer GC samples than the direct chamber method, but requires that effective soil gas diffusivities are known. In practice, soil gas diffusivity is often difficult to accurately estimate using a modeling approach. In our study, we apply both the chamber and gradient methods to estimate soil trace gas fluxes across a complex Rocky Mountain forested watershed in central Montana. We combine chamber flux measurements of CO2 (by infrared sensor) and CH4 and N2O (by GC) with co-located soil gas profiles to determine effective diffusivity in soil for each gas simultaneously, over-determining the diffusion equations and providing constraints on both the chamber and gradient methodologies. We then relate these soil gas diffusivities to soil type and volumetric water content in an effort to arrive at empirical parameterizations that may be used to estimate gas diffusivities across the watershed, thereby facilitating more accurate, frequent and widespread gradient-based measurements of trace gas fluxes across our study system. Our empirical approach to constraining soil gas diffusivity is well suited for trace gas flux studies over complex landscapes in general. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2007AGUFM.B43D1587W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2007AGUFM.B43D1587W">Examining the Influence of Teleconnection Patterns on CO2 Fluxes at an Old-Growth Forest Scaling from Stand to Region Using MODIS</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Wharton, S.; Chasmer, L.; Falk, M.; Paw U, K. 2007-12-01 In this study, year-to-year variability in three of the major Pacific teleconnection patterns were examined to determine if CO2 and H2O fluxes at an old-growth forest in the Pacific Northwest were affected by climatic changes associated with these patterns. The three cycles examined are the Pacific Decadal Oscillation, Pacific/North American Oscillation and El Niño-Southern Oscillation. We centered our study on the Wind River Canopy Crane, an AmeriFlux tower located in a 500 year old conifer forest in southern Washington State. CO2 and H2O fluxes have been measured continuously for six years using the eddy covariance method. The objectives of this study are to: 1. determine to what extent teleconnection patterns influence measured CO2 and H2O fluxes through mechanistic anomalies; 2. ascertain if climatic shifts affect annual vegetation canopy characteristics; and 3. make comparisons at the local and regional scales using MODIS. The ecosystem was a significant sink of carbon (-207 gC m-2 year-1) in 1999 but turned into a large carbon source (+ 100 gC m-2 year-1) in 2003. NEE significantly (above the 95th CI) lags the PNA, ENSO and PDO indicating that these patterns affect the forest carbon budget across overlapping time scales. To ascertain the influence of atmospheric patterns on fluxes, we categorized the flux measurement years based on in-phase climate events (1999 = La Niña/cool PDO, 2003 = El Niño/warm PDO, 2000-2002, 2004 = neutral ENSO years). The results of this analysis indicate that the Pacific Ocean/atmospheric oscillation anomalies explain much of variance in annual NEE (R2 = 0.78 between NEE and the PDO, R2 = 0.87 for the PNA, and R2 = 0.56 for ENSO). Teleconnection patterns are found to be associated mostly with air temperature, precipitation, and incoming light radiation (cloudy vs. sunny conditions). Important meteorological driving mechanisms of fluxes include: water- use efficiency (WUE), light-use efficiency (LUE) and canopy structure </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015BGD....1210389M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015BGD....1210389M">Lateral carbon fluxes and CO2 outgassing from a tropical peat-draining river</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Müller, D.; Warneke, T.; Rixen, T.; Müller, M.; Jamahari, S.; Denis, N.; Mujahid, A.; Notholt, J. 2015-07-01 Tropical peatlands play an important role in the global carbon cycle due to their immense carbon storage capacity. However, pristine peat swamp forests are vanishing due to deforestation and peatland degradation, especially in Southeast Asia. CO2 emissions associated with this land use change might not only come from the peat soil directly, but also from peat-draining rivers. So far, though, this has been mere speculation, since there was no data from undisturbed reference sites. We present the first combined assessment of lateral organic carbon fluxes and CO2 outgassing from an undisturbed tropical peat-draining river. Two sampling campaigns were undertaken on the Maludam river in Sarawak, Malaysia. The river catchment is covered by protected peat swamp forest, offering a unique opportunity to study a peat-draining river in its natural state, without any influence from tributaries with different characteristics. The two campaigns yielded consistent results. Dissolved organic carbon (DOC) concentrations ranged between 3222 and 6218 μmol L-1 and accounted for more than 99 % of the total organic carbon (TOC). Radiocarbon dating revealed that the riverine DOC was of recent origin, suggesting that it derives from the top soil layers and surface runoff. We observed strong oxygen depletion, implying high rates of organic matter decomposition and consequently CO2 production. The measured median pCO2 was 7795 and 8400 μatm during the two campaigns, respectively. Overall, we found that only 26 ± 15 % of the carbon was exported by CO2 evasion, while the rest was exported by discharge. CO2 outgassing seemed to be moderated by the short water residence time. Since most Southeast Asian peatlands are located at the coast, this is probably an important limiting factor for CO2 outgassing from most of its peat-draining rivers. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015BGeo...12.5967M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015BGeo...12.5967M">Lateral carbon fluxes and CO2 outgassing from a tropical peat-draining river</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Müller, D.; Warneke, T.; Rixen, T.; Müller, M.; Jamahari, S.; Denis, N.; Mujahid, A.; Notholt, J. 2015-10-01 Tropical peatlands play an important role in the global carbon cycle due to their immense carbon storage capacity. However, pristine peat swamp forests are vanishing due to deforestation and peatland degradation, especially in Southeast Asia. CO2 emissions associated with this land use change might not only come from the peat soil directly but also from peat-draining rivers. So far, though, this has been mere speculation, since there has been no data from undisturbed reference sites. We present the first combined assessment of lateral organic carbon fluxes and CO2 outgassing from an undisturbed tropical peat-draining river. Two sampling campaigns were undertaken on the Maludam River in Sarawak, Malaysia. The river catchment is covered by protected peat swamp forest, offering a unique opportunity to study a peat-draining river in its natural state, without any influence from tributaries with different characteristics. The two campaigns yielded consistent results. Dissolved organic carbon (DOC) concentrations ranged between 3222 and 6218 μmol L-1 and accounted for more than 99 % of the total organic carbon (TOC). Radiocarbon dating revealed that the riverine DOC was of recent origin, suggesting that it derives from the top soil layers and surface runoff. We observed strong oxygen depletion, implying high rates of organic matter decomposition and consequently CO2 production. The measured median pCO2 was 7795 and 8400 μatm during the first and second campaign, respectively. Overall, we found that only 32 ± 19 % of the carbon was exported by CO2 evasion, while the rest was exported by discharge. CO2 outgassing seemed to be moderated by the short water residence time. Since most Southeast Asian peatlands are located at the coast, this is probably an important limiting factor for CO2 outgassing from most of its peat-draining rivers. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://www.ars.usda.gov/research/publications/publication/?seqNo115=321468','TEKTRAN'); return false;" href="http://www.ars.usda.gov/research/publications/publication/?seqNo115=321468">Comparing CO2 flux data from eddy covariance methods with bowen ratio energy balance methods from contrasting soil management</a> <a target="_blank" href="https://www.ars.usda.gov/research/publications/find-a-publication/">USDA-ARS?s Scientific Manuscript database</a> Measuring CO2 fluxes from contrasting soil management practices is important for understanding the role of agriculture in source-sink relationship with CO2 flux. There are several micrometeorological methods for measuring CO2 emissions, however all are expensive and thus do not easily lend themselve... </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28672186','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28672186">Effect of pretreatment and membrane orientation on fluxes for concentration of whey with high foulants by using NH3/CO2 in forward osmosis.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Seker, M; Buyuksari, E; Topcu, S; Babaoglu, D S; Celebi, D; Keskinler, B; Aydiner, C 2017-11-01 Usage of forward osmosis membrane in FO mode, in which active and support layers of the membrane were in contact with the feed and the draw solutions respectively, provided higher initial water flux (12L/m 2 h) than the usage of membrane in PRO mode (6L/m 2 h) having opposite orientation but fluxes approached to each other after 4h during concentration of whey with NH 3 /CO 2 as draw salt. High organic and inorganic foulants of whey was considered as reason for observed result in addition to lower solute resistivity. Initial water flux (8,5L/m 2 h) was lower when pre-treatment was applied before forward osmosis process but final flux (4L/m 2 h) was equal flux of non pre-treatment. Reduction of solute resistivity or absence of hydraulic pressure can be reasons for lower initial flux. Detection of organic carbon but absence of lactose in draw solution showed passage of molecules being different than lactose into draw solution. Copyright © 2017 Elsevier Ltd. All rights reserved. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/24066532','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/24066532">[Temperature sensitivity of CO2 fluxes from rhizosphere soil mineralization and root decomposition in Pinus massoniana and Castanopsis sclerophylla forests].</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Liu, Yu; Hu, Xiao-Fei; Chen, Fu-Sheng; Yuan, Ping-Cheng 2013-06-01 Rhizospheric and non-rhizospheric soils and the absorption, transition, and storage roots were sampled from the mid-subtropical Pinus massoniana and Castanopsis sclerophylla forests to study the CO2 fluxes from soil mineralization and root decomposition in the forests. The samples were incubated in closed jars at 15 degrees C, 25 degrees C, 35 degrees C, and 45 degrees C, respectively, and alkali absorption method was applied to measure the CO2 fluxes during 53 days incubation. For the two forests, the rhizospheric effect (ratio of rhizospheric to non-rhizospheric soil) on the CO2 flux from soil mineralization across all incubation temperature ranged from 1.12 to 3.09, with a decreasing trend along incubation days. There was no significant difference in the CO2 flux from soil mineralization between the two forests at 15 degrees C, but the CO2 flux was significantly higher in P. massoniana forest than in C. sclerophylla forest at 25 degrees C and 35 degrees C, and in an opposite pattern at 45 degrees C. At all incubation temperature, the CO2 release from the absorption root decomposition was higher than that from the transition and storage roots decomposition, and was smaller in P. massoniana than in C. sclerophylla forest for all the root functional types. The Q10 values of the CO2 fluxes from the two forests were higher for soils (1.21-1.83) than for roots (0.96-1.36). No significant differences were observed in the Q10 values of the CO2 flux from soil mineralization between the two forests, but the Q10 value of the CO2 flux from root decomposition was significantly higher in P. massoniana than in C. sclerophylla forest. It was suggested that the increment of CO2 flux from soil mineralization under global warming was far higher than that from root decomposition, and for P. massoniana than for C. sclerophylla forest. In subtropics of China, the adaptability of zonal climax community to global warming would be stronger than that of pioneer community. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..1918076S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..1918076S">True eddy accumulation and eddy covariance methods and instruments intercomparison for fluxes of CO2, CH4 and H2O above the Hainich Forest</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Siebicke, Lukas 2017-04-01 The eddy covariance (EC) method is state-of-the-art in directly measuring vegetation-atmosphere exchange of CO2 and H2O at ecosystem scale. However, the EC method is currently limited to a small number of atmospheric tracers by the lack of suitable fast-response analyzers or poor signal-to-noise ratios. High resource and power demands may further restrict the number of spatial sampling points. True eddy accumulation (TEA) is an alternative method for direct and continuous flux observations. Key advantages are the applicability to a wider range of air constituents such as greenhouse gases, isotopes, volatile organic compounds and aerosols using slow-response analyzers. In contrast to relaxed eddy accumulation (REA), true eddy accumulation (Desjardins, 1977) has the advantage of being a direct method which does not require proxies. True Eddy Accumulation has the potential to overcome above mentioned limitations of eddy covariance but has hardly ever been successfully demonstrated in practice in the past. This study presents flux measurements using an innovative approach to true eddy accumulation by directly, continuously and automatically measuring trace gas fluxes using a flow-through system. We merge high-frequency flux contributions from TEA with low-frequency covariances from the same sensors. We show flux measurements of CO2, CH4 and H2O by TEA and EC above an old-growth forest at the ICOS flux tower site "Hainich" (DE-Hai). We compare and evaluate the performance of the two direct turbulent flux measurement methods eddy covariance and true eddy accumulation using side-by-side trace gas flux observations. We further compare performance of seven instrument complexes, i.e. combinations of sonic anemometers and trace gas analyzers. We compare gas analyzers types of open-path, enclosed-path and closed-path design. We further differentiate data from two gas analysis technologies: infrared gas analysis (IRGA) and laser spectrometry (open path and CRDS closed </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28152339','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28152339">Autonomous mobile platform for monitoring air emissions from industrial and municipal wastewater ponds.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Fu, Long; Huda, Quamrul; Yang, Zheng; Zhang, Lucas; Hashisho, Zaher 2017-11-01 Significant amounts of volatile organic compounds and greenhouse gases are generated from wastewater lagoons and tailings ponds in Alberta, Canada. Accurate measurements of these air pollutants and greenhouse gases are needed to support management and regulatory decisions. A mobile platform was developed to measure air emissions from tailings pond in the oil sands region of Alberta. The mobile platform was tested in 2015 in a municipal wastewater treatment lagoon. With a flux chamber and a CO 2 /CH 4 sensor on board, the mobile platform was able to measure CO 2 and CH 4 emissions over two days at two different locations in the pond. Flux emission rates of CO 2 and CH 4 that were measured over the study period suggest the presence of aerobic and anaerobic zones in the wastewater treatment lagoon. The study demonstrated the capabilities of the mobile platform in measuring fugitive air emissions and identified the potential for the applications in air and water quality monitoring programs. The Mobile Platform demonstrated in this study has the ability to measure greenhouse gas (GHG) emissions from fugitive sources such as municipal wastewater lagoons. This technology can be used to measure emission fluxes from tailings ponds with better detection of spatial and temporal variations of fugitive emissions. Additional air and water sampling equipment could be added to the mobile platform for a broad range of air and water quality studies in the oil sands region of Alberta. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013AGUFM.B21A0449H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013AGUFM.B21A0449H">The Dynamics of Energy and CO2 Transport above a Subtropical Rice Paddy</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Hsieh, C.; Huang, C.; Cheng, S. 2013-12-01 An eddy-covariance system was established to understand the dynamics of turbulent transport of sensible heat, water vapor, and CO2 above a subtropical rice paddy in north Taiwan (24°48'07.958'N, 121°47'58.665'E). The results showed that, during crop season, about 25% of net radiation was used for latent heat flux, 10% for sensible heat flux, and the rest (65%) was absorbed by the water and soil in the rice paddy. However, during fallow period, where there was no rice in the paddy, both water vapor and sensible heat fluxes occupied about 18% of the net radiation. Also, Penman-Monteith equation was found to reproduce the water vapor flux well with surface resistance close to 190 s m-1. We also found that, under small Bowen ratio (< 0.2) conditions, water vapor and CO2 were transported more efficiently than heat. However, when Bowen ration was large (> 0.5), sensible heat was transported about 10% more efficiently than both water vapor and CO2. During crop season the maximum CO2 uptake was about 22 micro mol m-2 s-1. In fallow period, the maximum CO2 emission rate from the soil-water surface was around 5 micro mol m-2 s-1, which was about the same as the growing season. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3722186','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3722186">Controls of Evapotranspiration and CO2 Fluxes from Scots Pine by Surface Conductance and Abiotic Factors</a> <a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Zha, Tianshan; Li, Chunyi; Kellomäki, Seppo; Peltola, Heli; Wang, Kai-Yun; Zhang, Yuqing 2013-01-01 Evapotranspiration (E) and CO2 flux (Fc) in the growing season of an unusual dry year were measured continuously over a Scots pine forest in eastern Finland, by eddy covariance techniques. The aims were to gain an understanding of their biological and environmental control processes. As a result, there were obvious diurnal and seasonal changes in E, Fc, surface conductance (gc), and decoupling coefficient (Ω), showing similar trends to those in radiation (PAR) and vapour pressure deficit (δ). The maximum mean daily values (24-h average) for E, Fc, gc, and Ω were 1.78 mmol m−2 s−1, −11.18 µmol m−2 s−1, 6.27 mm s−1, and 0.31, respectively, with seasonal averages of 0.71 mmol m−2 s−1, −4.61 µmol m−2 s−1, 3.3 mm s−1, and 0.16. E and Fc were controlled by combined biological and environmental variables. There was curvilinear dependence of E on gc and Fc on gc. Among the environmental variables, PAR was the most important factor having a positive linear relationship to E and curvilinear relationship to Fc, while vapour pressure deficit was the most important environmental factor affecting gc. Water use efficiency was slightly higher in the dry season, with mean monthly values ranging from 6.67 to 7.48 μmol CO2 (mmol H2O)−1 and a seasonal average of 7.06 μmol CO2 (μmol H2O)−1. Low Ω and its close positive relationship with gc indicate that evapotranspiration was sensitive to surface conductance. Mid summer drought reduced surface conductance and decoupling coefficient, suggesting a more biotic control of evapotranspiration and a physiological acclimation to dry air. Surface conductance remained low and constant under dry condition, supporting that a constant value of surface constant can be used for modelling transpiration under drought condition. PMID:23894401 </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/23894401','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/23894401">Controls of evapotranspiration and CO2 fluxes from scots pine by surface conductance and abiotic factors.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Zha, Tianshan; Li, Chunyi; Kellomäki, Seppo; Peltola, Heli; Wang, Kai-Yun; Zhang, Yuqing 2013-01-01 Evapotranspiration (E) and CO2 flux (Fc ) in the growing season of an unusual dry year were measured continuously over a Scots pine forest in eastern Finland, by eddy covariance techniques. The aims were to gain an understanding of their biological and environmental control processes. As a result, there were obvious diurnal and seasonal changes in E, Fc , surface conductance (gc ), and decoupling coefficient (Ω), showing similar trends to those in radiation (PAR) and vapour pressure deficit (δ). The maximum mean daily values (24-h average) for E, Fc , gc , and Ω were 1.78 mmol m(-2) s(-1), -11.18 µmol m(-2) s(-1), 6.27 mm s(-1), and 0.31, respectively, with seasonal averages of 0.71 mmol m(-2) s(-1), -4.61 µmol m(-2) s(-1), 3.3 mm s(-1), and 0.16. E and Fc were controlled by combined biological and environmental variables. There was curvilinear dependence of E on gc and Fc on gc . Among the environmental variables, PAR was the most important factor having a positive linear relationship to E and curvilinear relationship to Fc , while vapour pressure deficit was the most important environmental factor affecting gc . Water use efficiency was slightly higher in the dry season, with mean monthly values ranging from 6.67 to 7.48 μmol CO2 (mmol H2O)(-1) and a seasonal average of 7.06 μmol CO2 (μmol H2O)(-1). Low Ω and its close positive relationship with gc indicate that evapotranspiration was sensitive to surface conductance. Mid summer drought reduced surface conductance and decoupling coefficient, suggesting a more biotic control of evapotranspiration and a physiological acclimation to dry air. Surface conductance remained low and constant under dry condition, supporting that a constant value of surface constant can be used for modelling transpiration under drought condition. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..19.3932B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..19.3932B">An anomalous CO2 uptake measured over asphalt surface by open-path eddy-covariance system</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Bogoev, Ivan; Santos, Eduardo 2017-04-01 Measurements of net ecosystem exchange of CO2 in desert environments made by Wohlfahrt et al. (2008) and Ma (2014) indicate strong CO2 sink. The results of these studies have been challenged by Schlesinger (2016) because the rates of the CO2 uptake are incongruent with the increase of biomass in the vegetation and accumulation of organic and inorganic carbon in the soil. Consequently, the accuracy of the open-path eddy-covariance systems in arid and semi-arid ecosystems has been questioned. A new technology merging the sensing paths of the gas analyzer and the sonic anemometer has recently been developed. This integrated open-path system allows a direct measurement of CO2 mixing ratio in the open air and has the potential to improve the quality of the temperature related density and spectroscopic corrections by synchronously measuring the sensible heat flux in the optical path of the gas analyzer. We evaluate the performance and the accuracy of this new sensor over a large parking lot with an asphalt surface where the water vapor and CO2 fluxes are expected to be low and the interfering sensible heat fluxes are above 200 Wm-2. For independent CO2 flux reference measurements, we use a co-located closed-path analyzer with a short intake tube and a standalone sonic anemometer. We compare energy and carbon dioxide fluxes between the open- and the closed-path systems. During periods with sensible heat flux above 100 W m-2, the open-path system reports an apparent CO2 uptake of 0.02 mg m-2 s-1, while the closed-path system consistently measures a more acceptable upward flux of 0.015 mg m-2 s-1. We attribute this systematic bias to inadequate fast-response temperature compensation of absorption-line broadening effects. We demonstrate that this bias can be eliminated by using the humidity-corrected fast-response sonic temperature to compensate for the abovementioned spectroscopic effects in the open-path analyzer. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018ACP....18.4297L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018ACP....18.4297L">Using eddy covariance to measure the dependence of air-sea CO2 exchange rate on friction velocity</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Landwehr, Sebastian; Miller, Scott D.; Smith, Murray J.; Bell, Thomas G.; Saltzman, Eric S.; Ward, Brian 2018-03-01 Parameterisation of the air-sea gas transfer velocity of CO2 and other trace gases under open-ocean conditions has been a focus of air-sea interaction research and is required for accurately determining ocean carbon uptake. Ships are the most widely used platform for air-sea flux measurements but the quality of the data can be compromised by airflow distortion and sensor cross-sensitivity effects. Recent improvements in the understanding of these effects have led to enhanced corrections to the shipboard eddy covariance (EC) measurements.Here, we present a revised analysis of eddy covariance measurements of air-sea CO2 and momentum fluxes from the Southern Ocean Surface Ocean Aerosol Production (SOAP) study. We show that it is possible to significantly reduce the scatter in the EC data and achieve consistency between measurements taken on station and with the ship underway. The gas transfer velocities from the EC measurements correlate better with the EC friction velocity (u*) than with mean wind speeds derived from shipboard measurements corrected with an airflow distortion model. For the observed range of wind speeds (u10 N = 3-23 m s-1), the transfer velocities can be parameterised with a linear fit to u*. The SOAP data are compared to previous gas transfer parameterisations using u10 N computed from the EC friction velocity with the drag coefficient from the Coupled Ocean-Atmosphere Response Experiment (COARE) model version 3.5. The SOAP results are consistent with previous gas transfer studies, but at high wind speeds they do not support the sharp increase in gas transfer associated with bubble-mediated transfer predicted by physically based models. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/25412353','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/25412353">Polycyclic aromatic hydrocarbon (PAH) and oxygenated PAH (OPAH) air-water exchange during the deepwater horizon oil spill.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Tidwell, Lane G; Allan, Sarah E; O'Connell, Steven G; Hobbie, Kevin A; Smith, Brian W; Anderson, Kim A 2015-01-06 Passive sampling devices were used to measure air vapor and water dissolved phase concentrations of 33 polycyclic aromatic hydrocarbons (PAHs) and 22 oxygenated PAHs (OPAHs) at four Gulf of Mexico coastal sites prior to, during, and after shoreline oiling from the Deepwater Horizon oil spill (DWH). Measurements were taken at each site over a 13 month period, and flux across the water-air boundary was determined. This is the first report of vapor phase and flux of both PAHs and OPAHs during the DWH. Vapor phase sum PAH and OPAH concentrations ranged between 1 and 24 ng/m(3) and 0.3 and 27 ng/m(3), respectively. PAH and OPAH concentrations in air exhibited different spatial and temporal trends than in water, and air-water flux of 13 individual PAHs were strongly associated with the DWH incident. The largest PAH volatilizations occurred at the sites in Alabama and Mississippi in the summer, each nominally 10,000 ng/m(2)/day. Acenaphthene was the PAH with the highest observed volatilization rate of 6800 ng/m(2)/day in September 2010. This work represents additional evidence of the DWH incident contributing to air contamination, and provides one of the first quantitative air-water chemical flux determinations with passive sampling technology. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012AGUFM.A51F..06C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012AGUFM.A51F..06C">Comparing inversion techniques for constraining CO2 fluxes in the Brazilian Amazon Basin with aircraft observations</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Chow, V. Y.; Gerbig, C.; Longo, M.; Koch, F.; Nehrkorn, T.; Eluszkiewicz, J.; Ceballos, J. C.; Longo, K.; Wofsy, S. C. 2012-12-01 The Balanço Atmosférico Regional de Carbono na Amazônia (BARCA) aircraft program spanned the dry to wet and wet to dry transition seasons in November 2008 & May 2009 respectively. It resulted in ~150 vertical profiles covering the Brazilian Amazon Basin (BAB). With the data we attempt to estimate a carbon budget for the BAB, to determine if regional aircraft experiments can provide strong constraints for a budget, and to compare inversion frameworks when optimizing flux estimates. We use a LPDM to integrate satellite-, aircraft-, & surface-data with mesoscale meteorological fields to link bottom-up and top-down models to provide constraints and error bounds for regional fluxes. The Stochastic Time-Inverted Lagrangian Transport (STILT) model driven by meteorological fields from BRAMS, ECMWF, and WRF are coupled to a biosphere model, the Vegetation Photosynthesis Respiration Model (VPRM), to determine regional CO2 fluxes for the BAB. The VPRM is a prognostic biosphere model driven by MODIS 8-day EVI and LSWI indices along with shortwave radiation and temperature from tower measurements and mesoscale meteorological data. VPRM parameters are tuned using eddy flux tower data from the Large-Scale Biosphere Atmosphere experiment. VPRM computes hourly CO2 fluxes by calculating Gross Ecosystem Exchange (GEE) and Respiration (R) for 8 different vegetation types. The VPRM fluxes are scaled up to the BAB by using time-averaged drivers (shortwave radiation & temperature) from high-temporal resolution runs of BRAMS, ECMWF, and WRF and vegetation maps from SYNMAP and IGBP2007. Shortwave radiation from each mesoscale model is validated using surface data and output from GL 1.2, a global radiation model based on GOES 8 visible imagery. The vegetation maps are updated to 2008 and 2009 using landuse scenarios modeled by Sim Amazonia 2 and Sim Brazil. A priori fluxes modeled by STILT-VPRM are optimized using data from BARCA, eddy covariance sites, and flask measurements. The </li> <li> <a target="_blank" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20020054331&hterms=Organic+fertilizers&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D10%26Ntt%3DOrganic%2Bfertilizers','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20020054331&hterms=Organic+fertilizers&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D10%26Ntt%3DOrganic%2Bfertilizers">Interannual Variability in Soil Trace Gas (CO2, N2O, NO) Fluxes and Analysis of Controllers</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Potter, C.; Klooster, S.; Peterson, David L. (Technical Monitor) 1997-01-01 Interannual variability in flux rates of biogenic trace gases must be quantified in order to understand the differences between short-term trends and actual long-term change in biosphere-atmosphere interactions. We simulated interannual patterns (1983-1988) of global trace gas fluxes from soils using the NASA Ames model version of CASA (Carnegie-Ames-Stanford Approach) in a transient simulation mode. This ecosystem model has been recalibrated for simulations driven by satellite vegetation index data from the NOAA Advanced Very High Resolution Radiometer (AVHRR) over the mid-1980s. The predicted interannual pattern of soil heterotropic CO2 emissions indicates that relatively large increases in global carbon flux from soils occurred about three years following the strong El Nino Southern Oscillation (ENSO) event of 1983. Results for the years 1986 and 1987 showed an annual increment of +1 Pg (1015 g) C-CO2 emitted from soils, which tended to dampen the estimated global increase in net ecosystem production with about a two year lag period relative to plant carbon fixation. Zonal discrimination of model results implies that 80-90 percent of the yearly positive increments in soil CO2 emission during 1986-87 were attributable to soil organic matter decomposition in the low-latitudes (between 30 N and 30 S). Soils of the northern middle-latitude zone (between 30 N and 60 N) accounted for the residual of these annual increments. Total annual emissions of nitrogen trace gases (N2O and NO) from soils were estimated to vary from 2-4 percent over the time period modeled, a level of variability which is consistent with predicted interannual fluctuations in global soil CO2 fluxes. Interannual variability of precipitation in tropical and subtropical zones (30 N to 20 S appeared to drive the dynamic inverse relationship between higher annual emissions of NO versus emissions of N2O. Global mean emission rates from natural (heterotrophic) soil sources over the period modeled (1983 </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014AGUFM.B41C0071S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014AGUFM.B41C0071S">Sampling Soil CO2 for Isotopic Flux Partitioning: Non Steady State Effects and Methodological Biases</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Snell, H. S. K.; Robinson, D.; Midwood, A. J. 2014-12-01 Measurements of δ13C of soil CO2 are used to partition the surface flux into autotrophic and heterotrophic components. Models predict that the δ13CO2 of the soil efflux is perturbed by non-steady state (NSS) diffusive conditions. These could be large enough to render δ13CO2 unsuitable for accurate flux partitioning. Field studies sometimes find correlations between efflux δ13CO2 and flux or temperature, or that efflux δ13CO2 is not correlated as expected with biological drivers. We tested whether NSS effects in semi-natural soil were comparable with those predicted. We compared chamber designs and their sensitivity to changes in efflux δ13CO2. In a natural soil mesocosm, we controlled temperature to generate NSS conditions of CO2 production. We measured the δ13C of soil CO2 using in situ probes to sample the subsurface, and dynamic and forced-diffusion chambers to sample the surface efflux. Over eight hours we raised soil temperature by 4.5 OC to increase microbial respiration. Subsurface CO2 concentration doubled, surface efflux became 13C-depleted by 1 ‰ and subsurface CO2 became 13C-enriched by around 2 ‰. Opposite changes occurred when temperature was lowered and CO2 production was decreasing. Different chamber designs had inherent biases but all detected similar changes in efflux δ13CO2, which were comparable to those predicted. Measurements using dynamic chambers were more 13C-enriched than expected, probably due to advection of CO2 into the chamber. In the mesocosm soil, δ13CO2 of both efflux and subsurface was determined by physical processes of CO2 production and diffusion. Steady state conditions are unlikely to prevail in the field, so spot measurements of δ13CO2 and assumptions based on the theoretical 4.4 ‰ diffusive fractionation will not be accurate for estimating source δ13CO2. Continuous measurements could be integrated over a period suitable to reduce the influence of transient NSS conditions. It will be difficult to disentangle </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012AGUFM.B51B0544R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012AGUFM.B51B0544R">Year-round record of Dry Valley soil CO2 flux provides insights into Antarctic soil dynamics</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Risk, D. A.; Lee, C.; Macintyre, C. M.; Cary, C. 2012-12-01 The McMurdo Dry Valleys of Antarctica host extreme soil microbial communities that have been extensively studied within the past decade. Activity of microbial communities is routinely measured via soil CO2 flux, and some useful Antarctic measurements have been made during short Austral summers. These studies are mostly spatial in nature, but temporal patterns are also valuable and may provide insights into critical thresholds and the interplay between various mechanisms that drive CO2 flux and its variation. New membrane-based Forced Diffusion (FD) soil efflux techniques offer promise for this application. The purpose of this study was to use a specially designed FD instrument in Hidden Valley of the Antarctic Dry Valleys to evaluate hardware performance in year-round deployments, and to identify features of interest with respect to soil CO2 flux variation. Overall, the deployment was successful. Small but sustained positive fluxes were present only twice during the year. The first such event was small but consistent and of long duration, occurring in the Austral winter. The second was more volatile and likely of microbial origin, and appeared for roughly a month at the end of the calendar year within the Austral summer. The observed patterns suggest that Hidden Valley soil CO2 fluxes are not solely biological in nature, but likely modulated by a combination of biological, geological, and physical processes, which will be discussed in this presentation. In future studies, additional measurement locations, and simultaneous subsurface and lower atmospheric gradient concentration measurements (power-permitting) would be extremely valuable for interpreting measured fluxes, to help identify advective depletion events, the depth source of fluxes, and changes in soil and atmospheric diffusivities. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_19");'>19</a></li> <li><a href="#" onclick='return showDiv("page_20");'>20</a></li> <li class="active">21</li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li><a href="#" onclick='return showDiv("page_23");'>23</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_22" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_20");'>20</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li class="active">22</li> <li><a href="#" onclick='return showDiv("page_23");'>23</a></li> <li><a href="#" onclick='return showDiv("page_24");'>24</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="421"> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012AGUFM.B52B..06Z','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012AGUFM.B52B..06Z">Greenhouse gas fluxes (CO2, CH4, N2O) of a short-rotation poplar plantation after conversion from agriculture</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Zona, D.; Janssens, I.; Aubinet, M.; Ceulemans, R. 2012-12-01 The increasing demand for renewable energy may lead to the conversion of millions of hectares into bioenergy plantations with a possible substantial transitory carbon (C) loss. Here we report on the greenhouse gas fluxes (CO2, CH4, and N2O) measured using eddy covariance of a short-rotation bioenergy poplar plantation converted from agricultural fields. The first six months after the establishment of the plantation (June-Dec 2010) presented substantial CO2, CH4, and N2O emissions (a total of 5.36 ± 0.52 Mg CO2eq ha-1 in terms of CO2 equivalents). Nitrous oxide loss mostly occurred during a week-long peak emission after an unusually large rainfall. This week-long N2O emission represented 52% of the entire N2O loss during one and an half years of measurements. As most of the N2O loss occurred in just this week-long period, accurately capturing these emission events are critical to accurate estimates of the GHG balance of bioenergy. While initial establishment (Jun-Dec 2010) of the plantation resulted in a net CO2 loss into the atmosphere (2.76 ± 0.16 Mg CO2eq ha-1), in the second year (2011) the plantation presented a substantial net CO2 uptake (-4.82 ± 0.47 Mg CO2eq ha-1). During the entire measurement period, CH4 was a source to the atmosphere (0.63 ± 0.05 Mg CO2eq ha-1 in 2010, and 0.49 ± 0.05 Mg CO2eq ha-1 in 2011), and was controlled by water table depth. Importantly, over the entire measurement period, the sum of the CH4 and N2O losses was almost double (3.51 ± 0.52 Mg CO2eq ha-1) than the magnitude of net CO2 uptake (-2.06 ± 0.50 Mg CO2eq ha-1). As water availability was an important control on the GHG emission of the plantation, expected climate change and altered rainfall pattern could increase the negative environmental impacts of bioenergy. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AGUFM.A33F0242W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AGUFM.A33F0242W">An Inversion Analysis of Recent Variability in Natural CO2 Fluxes Using GOSAT and In Situ Observations</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Wang, J. S.; Kawa, S. R.; Baker, D. F.; Collatz, G. J.; Ott, L. E. 2015-12-01 About one-half of the global CO2 emissions from fossil fuel combustion and deforestation accumulates in the atmosphere, where it contributes to global warming. The rest is taken up by vegetation and the ocean. The precise contribution of the two sinks, and their location and year-to-year variability are, however, not well understood. We use two different approaches, batch Bayesian synthesis inversion and variational data assimilation, to deduce the global spatiotemporal distributions of CO2 fluxes during 2009-2010. One of our objectives is to assess different sources of uncertainties in inferred fluxes, including uncertainties in prior flux estimates and observations, and differences in inversion techniques. For prior constraints, we utilize fluxes and uncertainties from the CASA-GFED model of the terrestrial biosphere and biomass burning driven by satellite observations and interannually varying meteorology. We also use measurement-based ocean flux estimates and two sets of fixed fossil CO2 emissions. Here, our inversions incorporate column CO2 measurements from the GOSAT satellite (ACOS retrieval, filtered and bias-corrected) and in situ observations (individual flask and afternoon-average continuous observations) to estimate fluxes in 108 regions over 8-day intervals for the batch inversion and at 3° x 3.75° weekly for the variational system. Relationships between fluxes and atmospheric concentrations are derived consistently for the two inversion systems using the PCTM atmospheric transport model driven by meteorology from the MERRA reanalysis. We compare the posterior fluxes and uncertainties derived using different data sets and the two inversion approaches, and evaluate the posterior atmospheric concentrations against independent data including aircraft measurements. The optimized fluxes generally resemble those from other studies. For example, the results indicate that the terrestrial biosphere is a net CO2 sink, and a GOSAT-only inversion suggests a </li> <li> <a target="_blank" onclick="trackOutboundLink('http://hdl.handle.net/2060/20160000370','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20160000370">An Inversion Analysis of Recent Variability in Natural CO2 Fluxes Using GOSAT and In Situ Observations</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Wang, James S.; Kawa, S. Randolph; Collatz, G. James; Baker, David F.; Ott, Lesley 2015-01-01 About one-half of the global CO2 emissions from fossil fuel combustion and deforestation accumulates in the atmosphere, where it contributes to global warming. The rest is taken up by vegetation and the ocean. The precise contribution of the two sinks, and their location and year-to-year variability are, however, not well understood. We use two different approaches, batch Bayesian synthesis inversion and variational data assimilation, to deduce the global spatiotemporal distributions of CO2 fluxes during 2009-2010. One of our objectives is to assess different sources of uncertainties in inferred fluxes, including uncertainties in prior flux estimates and observations, and differences in inversion techniques. For prior constraints, we utilize fluxes and uncertainties from the CASA-GFED model of the terrestrial biosphere and biomass burning driven by satellite observations and interannually varying meteorology. We also use measurement-based ocean flux estimates and two sets of fixed fossil CO2 emissions. Here, our inversions incorporate column CO2 measurements from the GOSAT satellite (ACOS retrieval, filtered and bias-corrected) and in situ observations (individual flask and afternoon-average continuous observations) to estimate fluxes in 108 regions over 8-day intervals for the batch inversion and at 3 x 3.75 weekly for the variational system. Relationships between fluxes and atmospheric concentrations are derived consistently for the two inversion systems using the PCTM atmospheric transport model driven by meteorology from the MERRA reanalysis. We compare the posterior fluxes and uncertainties derived using different data sets and the two inversion approaches, and evaluate the posterior atmospheric concentrations against independent data including aircraft measurements. The optimized fluxes generally resemble those from other studies. For example, the results indicate that the terrestrial biosphere is a net CO2 sink, and a GOSAT-only inversion suggests a shift in </li> <li> <a target="_blank" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20080030789&hterms=erickson&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D40%26Ntt%3Derickson','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20080030789&hterms=erickson&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D40%26Ntt%3Derickson">Evaluating the Capacity of Global CO2 Flux and Atmospheric Transport Models to Incorporate New Satellite Observations</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Kawa, S. R.; Collatz, G. J.; Erickson, D. J.; Denning, A. S.; Wofsy, S. C.; Andrews, A. E. 2007-01-01 As we enter the new era of satellite remote sensing for CO2 and other carbon cyclerelated quantities, advanced modeling and analysis capabilities are required to fully capitalize on the new observations. Model estimates of CO2 surface flux and atmospheric transport are required for initial constraints on inverse analyses, to connect atmospheric observations to the location of surface sources and sinks, and ultimately for future projections of carbon-climate interactions. For application to current, planned, and future remotely sensed CO2 data, it is desirable that these models are accurate and unbiased at time scales from less than daily to multi-annual and at spatial scales from several kilometers or finer to global. Here we focus on simulated CO2 fluxes from terrestrial vegetation and atmospheric transport mutually constrained by analyzed meteorological fields from the Goddard Modeling and Assimilation Office for the period 1998 through 2006. Use of assimilated meteorological data enables direct model comparison to observations across a wide range of scales of variability. The biospheric fluxes are produced by the CASA model at lxi degrees on a monthly mean basis, modulated hourly with analyzed temperature and sunlight. Both physiological and biomass burning fluxes are derived using satellite observations of vegetation, burned area (as in GFED-2), and analyzed meteorology. For the purposes of comparison to CO2 data, fossil fuel and ocean fluxes are also included in the transport simulations. In this presentation we evaluate the model's ability to simulate CO2 flux and mixing ratio variability in comparison to in situ observations at sites in Northern mid latitudes and the continental tropics. The influence of key process representations is inferred. We find that the model can resolve much of the hourly to synoptic variability in the observations, although there are limits imposed by vertical resolution of boundary layer processes. The seasonal cycle and its </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.B21F2017D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.B21F2017D">Characterization And Partitioning Of CH4 And CO2 Eddy Flux Data Measured at NGEE-Arctic Sites</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Dengel, S.; Chafe, O.; Curtis, J. B.; Biraud, S.; Torn, M. S.; Wullschleger, S. D. 2017-12-01 The high latitudes are experiencing rapid warming with permafrost ecosystems being highly vulnerable to this change. Since the advancement in Eddy Covariance (EC) measurements, the number of high latitude sites measuring greenhouse gases and energy (CO2, CH4 and H2O) fluxes is steadily increasing, with new sites being established each year. Data from these sites are not only valuable for annual carbon budget calculations, but also vital to the modeling community for improving their predictions of emission rates and trends. CH4 flux measurements are not as straightforward as CO2 fluxes. They tend to be less predictable or as easily interpretable as CO2 fluxes. Understanding CH4 emission patterns are often challenging. Moreover, gas flux fluctuations are spatially and temporally diverse, and in many cases event-based. An improvement in understanding would also contribute to improvements in the fidelity of model predictions. These rely on having high quality data, and thus will entail developing new QA/QC and gap-filling methods for Arctic systems, in particularly for CH4. Contributing to these challenges is the limited number of ancillary measurements carried out at many sites and the lack of standardized data processing, QA/QC, and gap-filling procedures, in particular for CH4. CO2, CH4, and energy flux measurements are ongoing at, both NGEE-Arctic/AmeriFlux, US-NGB (Arctic coastal plain), and US-NGC (subarctic tussock tundra) sites. The sites, with underlying continuous permafrost, show a high degree of inter-annual and seasonal variability in CH4 fluxes. In order to interpret this variability, we apply a variety of models, such as footprint characterization, generalized additive models, as well as artificial neural networks, in an attempt to decipher these diverse fluxes, patterns and events. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5544137','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5544137">Simultaneously reducing CO2 and particulate exposures via fractional recirculation of vehicle cabin air</a> <a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Jung, Heejung S.; Grady, Michael L.; Victoroff, Tristan; Miller, Arthur L. 2017-01-01 Prior studies demonstrate that air recirculation can reduce exposure to nanoparticles in vehicle cabins. However when people occupy confined spaces, air recirculation can lead to carbon dioxide (CO2) accumulation which can potentially lead to deleterious effects on cognitive function. This study proposes a fractional air recirculation system for reducing nanoparticle concentration while simultaneously suppressing CO2 levels in the cabin. Several recirculation scenarios were tested using a custom-programmed HVAC (heat, ventilation, air conditioning) unit that varied the recirculation door angle in the test vehicle. Operating the recirculation system with a standard cabin filter reduced particle concentrations to 1000 particles/cm3, although CO2 levels rose to 3000 ppm. When as little as 25% fresh air was introduced (75% recirculation), CO2 levels dropped to 1000 ppm, while particle concentrations remained below 5000 particles/cm3. We found that nanoparticles were removed selectively during recirculation and demonstrated the trade-off between cabin CO2 concentration and cabin particle concentration using fractional air recirculation. Data showed significant increases in CO2 levels during 100% recirculation. For various fan speeds, recirculation fractions of 50–75% maintained lower CO2 levels in the cabin, while still reducing particulate levels. We recommend fractional recirculation as a simple method to reduce occupants’ exposures to particulate matter and CO2 in vehicles. A design with several fractional recirculation settings could allow air exchange adequate for reducing both particulate and CO2 exposures. Developing this technology could lead to reductions in airborne nanoparticle exposure, while also mitigating safety risks from CO2 accumulation. PMID:28781568 </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28781568','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28781568">Simultaneously reducing CO2 and particulate exposures via fractional recirculation of vehicle cabin air.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Jung, Heejung S; Grady, Michael L; Victoroff, Tristan; Miller, Arthur L 2017-07-01 Prior studies demonstrate that air recirculation can reduce exposure to nanoparticles in vehicle cabins. However when people occupy confined spaces, air recirculation can lead to carbon dioxide (CO 2 ) accumulation which can potentially lead to deleterious effects on cognitive function. This study proposes a fractional air recirculation system for reducing nanoparticle concentration while simultaneously suppressing CO 2 levels in the cabin. Several recirculation scenarios were tested using a custom-programmed HVAC (heat, ventilation, air conditioning) unit that varied the recirculation door angle in the test vehicle. Operating the recirculation system with a standard cabin filter reduced particle concentrations to 1000 particles/cm 3 , although CO 2 levels rose to 3000 ppm. When as little as 25% fresh air was introduced (75% recirculation), CO 2 levels dropped to 1000 ppm, while particle concentrations remained below 5000 particles/cm 3 . We found that nanoparticles were removed selectively during recirculation and demonstrated the trade-off between cabin CO 2 concentration and cabin particle concentration using fractional air recirculation. Data showed significant increases in CO 2 levels during 100% recirculation. For various fan speeds, recirculation fractions of 50-75% maintained lower CO 2 levels in the cabin, while still reducing particulate levels. We recommend fractional recirculation as a simple method to reduce occupants' exposures to particulate matter and CO 2 in vehicles. A design with several fractional recirculation settings could allow air exchange adequate for reducing both particulate and CO 2 exposures. Developing this technology could lead to reductions in airborne nanoparticle exposure, while also mitigating safety risks from CO 2 accumulation. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AtmEn.160...77J','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AtmEn.160...77J">Simultaneously reducing CO2 and particulate exposures via fractional recirculation of vehicle cabin air</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Jung, Heejung S.; Grady, Michael L.; Victoroff, Tristan; Miller, Arthur L. 2017-07-01 Prior studies demonstrate that air recirculation can reduce exposure to nanoparticles in vehicle cabins. However when people occupy confined spaces, air recirculation can lead to carbon dioxide (CO2) accumulation which can potentially lead to deleterious effects on cognitive function. This study proposes a fractional air recirculation system for reducing nanoparticle concentration while simultaneously suppressing CO2 levels in the cabin. Several recirculation scenarios were tested using a custom-programmed HVAC (heat, ventilation, air conditioning) unit that varied the recirculation door angle in the test vehicle. Operating the recirculation system with a standard cabin filter reduced particle concentrations to 1000 particles/cm3, although CO2 levels rose to 3000 ppm. When as little as 25% fresh air was introduced (75% recirculation), CO2 levels dropped to 1000 ppm, while particle concentrations remained below 5000 particles/cm3. We found that nanoparticles were removed selectively during recirculation and demonstrated the trade-off between cabin CO2 concentration and cabin particle concentration using fractional air recirculation. Data showed significant increases in CO2 levels during 100% recirculation. For various fan speeds, recirculation fractions of 50-75% maintained lower CO2 levels in the cabin, while still reducing particulate levels. We recommend fractional recirculation as a simple method to reduce occupants' exposures to particulate matter and CO2 in vehicles. A design with several fractional recirculation settings could allow air exchange adequate for reducing both particulate and CO2 exposures. Developing this technology could lead to reductions in airborne nanoparticle exposure, while also mitigating safety risks from CO2 accumulation. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016BGeo...13.6107V','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016BGeo...13.6107V">The role of Phragmites in the CH4 and CO2 fluxes in a minerotrophic peatland in southwest Germany</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> van den Berg, Merit; Ingwersen, Joachim; Lamers, Marc; Streck, Thilo 2016-11-01 Peatlands are interesting as a carbon storage option, but are also natural emitters of the greenhouse gas methane (CH4). Phragmites peatlands are particularly interesting due to the global abundance of this wetland plant (Phragmites australis) and the highly efficient internal gas transport mechanism, which is called humidity-induced convection (HIC). The research aims were to (1) clarify how this plant-mediated gas transport influences the CH4 fluxes, (2) which other environmental variables influence the CO2 and CH4 fluxes, and (3) whether Phragmites peatlands are a net source or sink of greenhouse gases. CO2 and CH4 fluxes were measured with the eddy covariance technique within a Phragmites-dominated fen in southwest Germany. One year of flux data (March 2013-February 2014) shows very clear diurnal and seasonal patterns for both CO2 and CH4. The diurnal pattern of CH4 fluxes was only visible when living, green reed was present. In August the diurnal cycle of CH4 was the most distinct, with 11 times higher midday fluxes (15.7 mg CH4 m-2 h-1) than night fluxes (1.41 mg CH4 m-2 h-1). This diurnal cycle has the highest correlation with global radiation, which suggests a high influence of the plants on the CH4 flux. But if the cause were the HIC, it would be expected that relative humidity would correlate stronger with CH4 flux. Therefore, we conclude that in addition to HIC, at least one additional mechanism must be involved in the creation of the convective flow within the Phragmites plants. Overall, the fen was a sink for carbon and greenhouse gases in the measured year, with a total carbon uptake of 221 g C m-2 yr-1 (26 % of the total assimilated carbon). The net uptake of greenhouse gases was 52 g CO2 eq. m-2 yr-1, which is obtained from an uptake of CO2 of 894 g CO2 eq. m-2 yr-1 and a release of CH4 of 842 g CO2 eq. m-2 yr-1. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014AGUFMGC11B0561K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014AGUFMGC11B0561K">Effect of Thaw Depth on Fluxes of CO2 and CH4 in Manipulated Arctic Coastal Tundra of Barrow, Alaska</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Kim, Y. 2014-12-01 Changes in CO2 and CH4 emissions represent one of the most significant consequences of drastic climate change in the Arctic, by way of thawing permafrost, a deepened active layer, and decline of thermokarst lakes in the Arctic. This study conducted flux-measurements of CO2 and CH4, as well as environmental factors such as temperature, moisture, and thaw depth, as part of a water table manipulation experiment in the Arctic coastal plain tundra of Barrow, Alaska during autumn. The manipulation treatment consisted of draining, controlling, and flooding treated sections by adjusting standing water. Inundation increased CH4 emission by a factor of 4.3 compared to non-flooded sections. This may be due to the decomposition of organic matter under a limited oxygen environment by saturated standing water. On the other hand, CO2 emission in the dry section was 3.9-fold higher than in others. CH4 emission tends to increase with deeper thaw depth, which strongly depends on the water table; however, CO2 emission is not related to thaw depth. Quotients of global warming potential (GWPCO2) (dry/control) and GWPCH4 (wet/control) increased by 464 and 148 %, respectively, and GWPCH4 (dry/control) declined by 66 %. This suggests that CO2 emission in a drained section is enhanced by soil and ecosystem respiration, and CH4 emission in a flooded area is likely stimulated under an anoxic environment by inundated standing water. The findings of this manipulation experiment during the autumn period demonstrate the different production processes of CO2 and CH4, as well as different global warming potentials, coupled with change in thaw depth. Thus the outcomes imply that the expansion of tundra lakes leads the enhancement of CH4 release, and the disappearance of the lakes causes the stimulated CO2 production in response to the Arctic climate change. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014AtmEn..99..546A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014AtmEn..99..546A">Quantifying the air quality-CO2 tradeoff potential for airports</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Ashok, Akshay; Dedoussi, Irene C.; Yim, Steve H. L.; Balakrishnan, Hamsa; Barrett, Steven R. H. 2014-12-01 Aircraft movements on the airport surface are responsible for CO2 emissions that contribute to climate change and other emissions that affect air quality and human health. While the potential for optimizing aircraft surface movements to minimize CO2 emissions has been assessed, the implications of CO2 emissions minimization for air quality have not been quantified. In this paper, we identify conditions in which there is a tradeoff between CO2 emissions and population exposure to O3 and secondary PM2.5 - i.e. where decreasing fuel burn (which is directly proportional to CO2 emissions) results in increased exposure. Fuel burn and emissions are estimated as a function of thrust setting for five common gas turbine engines at 34 US airports. Regional air quality impacts, which are dominated by ozone and secondary PM2.5, are computed as a function of airport location and time using the adjoint of the GEOS-Chem chemistry-transport model. Tradeoffs between CO2 emissions and population exposure to PM2.5 and O3 occur between 2-18% and 5-60% of the year, respectively, depending on airport location, engine type, and thrust setting. The total duration of tradeoff conditions is 5-12 times longer at maximum thrust operations (typical for takeoff) relative to 4% thrust operations (typical for taxiing). Per kilogram of additional fuel burn at constant thrust setting during tradeoff conditions, reductions in population exposure to PM2.5 and O3 are 6-13% and 32-1060% of the annual average (positive) population exposure per kilogram fuel burn, where the ranges encompass the medians over the 34 airports. For fuel burn increases due to thrust increases (i.e. for constant operating time), reductions in both PM2.5 and O3 exposure are 1.5-6.4 times larger in magnitude than those due to increasing fuel burn at constant thrust (i.e. increasing operating time). Airports with relatively high population exposure reduction potentials - which occur due to a combination of high duration and </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017JMS...173...49L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017JMS...173...49L">Controlling mechanisms of surface partial pressure of CO2 in Jiaozhou Bay during summer and the influence of heavy rain</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Li, Yunxiao; Yang, Xufeng; Han, Ping; Xue, Liang; Zhang, Longjun 2017-09-01 Due to the combined effects of natural processes and human activities, carbon source/sink processes and mechanisms in the coastal ocean are becoming more and more important in current ocean carbon cycle research. Based on differences in the ratio of total alkalinity (TA) to dissolved inorganic carbon (DIC) associated with terrestrial input, biological process (production and respiration), calcium carbonate (CaCO3) process (precipitation and dissolution) and CO2 evasion/invasion, we discuss the mechanisms controlling the surface partial pressure of CO2 (pCO2) in Jiaozhou Bay (JZB) during summer and the influence of heavy rain, via three cruises performed in mid-June, early July and late July of 2014. In mid-June and in early July, without heavy rain or obvious river input, sea surface pCO2 ranged from 521 to 1080 μatm and from 547 to 998 μatm, respectively. The direct input of DIC from sewage and the intense respiration produced large DIC additions and the highest pCO2 values in the northeast of the bay near the downtown of Qingdao. However, in the west of the bay, significant CaCO3 precipitation led to DIC removal but no obvious increase in pCO2, which was just close to that in the central area. Due to the shallow depth and longer water residence time in this region, this pattern may be related to the sustained release of CO2 into the atmosphere. In late July, heavy rain promoted river input in the western and eastern portions of JZB. Strong primary production led to a significant decrease in pCO2 in the western area, with the lowest pCO2 value of 252 μatm. However, in the northeastern area, the intense respiration remained, and the highest pCO2 value was 1149 μatm. The average air-sea CO2 flux in mid-June and early July was 20.23 mmol m- 2 d- 1 and 23.56 mmol m- 2 d- 1, respectively. In contrast, in late July, sources became sinks for atmospheric CO2 in the western and central areas of the bay, halving the average air-sea CO2 flux to a value of 10.58 mmol m- 2 </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014AGUFM.B24D..03H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014AGUFM.B24D..03H">High-resolution mapping of biogenic carbon fluxes to improve urban CO2 monitoring, reporting, and verification</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Hardiman, B. S.; Hutyra, L.; Gately, C.; Raciti, S. M. 2014-12-01 Urban areas are home to 80% of the US population and 70% of energy related fossil fuel emissions originate from urban areas. Efforts to accurately monitor, report, and verify anthropogenic CO2 missions using atmospheric measurements require reliable partitioning of anthropogenic and biogenic sources. Anthropogenic emissions peak during the daytime, coincident with biogenic drawdown of CO2. In contrast, biogenic respiration emissions peak at night when anthropogenic emissions are lower. This temporal aliasing of fluxes requires careful modeling of both biogenic and anthropogenic fluxes for accurate source attribution through inverse modeling. Biogenic fluxes in urban regions can be a significant component of the urban carbon cycle. However, vegetation in urban areas is subject to longer growing seasons, reduced competition, higher rates of nitrogen deposition, and altered patterns of biomass inputs, all interacting to elevate C turnover rates relative to analogous non-urban ecosystems. These conditions suggest that models that ignore urban vegetation or base biogenic flux estimates on non-urban forests are likely to produce inaccurate estimates of anthropogenic CO2 emissions. Biosphere models often omit biogenic fluxes in urban areas despite potentially extensive vegetation coverage. For example, in Massachusetts, models mask out as much as 40% of land area, effectively assuming they have no biological flux. This results in a ~32% underestimate of aboveground biomass (AGB) across the state as compared to higher resolution vegetation maps. Our analysis suggests that some common biomass maps may underestimate forest biomass by ~520 Tg C within the state of Massachusetts. Moreover, omitted portions of the state have the highest population density, indicating that we know least about regions where most people live. We combine remote sensing imagery of urban vegetation cover with ground surveys of tree growth and mortality to improve estimates of aboveground biomass and </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013AMT.....6..817W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013AMT.....6..817W">Jena Reference Air Set (JRAS): a multi-point scale anchor for isotope measurements of CO2 in air</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Wendeberg, M.; Richter, J. M.; Rothe, M.; Brand, W. A. 2013-03-01 The need for a unifying scale anchor for isotopes of CO2 in air was brought to light at the 11th WMO/IAEA Meeting of Experts on Carbon Dioxide in Tokyo 2001. During discussions about persistent discrepancies in isotope measurements between the worlds leading laboratories, it was concluded that a unifying scale anchor for Vienna Pee Dee Belemnite (VPDB) of CO2 in air was desperately needed. Ten years later, at the 2011 Meeting of Experts on Carbon Dioxide in Wellington, it was recommended that the Jena Reference Air Set (JRAS) become the official scale anchor for isotope measurements of CO2 in air (Brailsford, 2012). The source of CO2 used for JRAS is two calcites. After releasing CO2 by reaction with phosphoric acid, the gases are mixed into CO2-free air. This procedure ensures both isotopic stability and longevity of the CO2. That the reference CO2 is generated from calcites and supplied as an air mixture is unique to JRAS. This is made to ensure that any measurement bias arising from the extraction procedure is eliminated. As every laboratory has its own procedure for extracting the CO2, this is of paramount importance if the local scales are to be unified with a common anchor. For a period of four years, JRAS has been evaluated through the IMECC1 program, which made it possible to distribute sets of JRAS gases to 13 laboratories worldwide. A summary of data from the six laboratories that have reported the full set of results is given here along with a description of the production and maintenance of the JRAS scale anchors. 1 IMECC refers to the EU project "Infrastructure for Measurements of the European Carbon Cycle" (<a href="http://imecc.ipsl.jussieu.fr/"target="_blank">http://imecc.ipsl.jussieu.fr/</a>). </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017CSR...145...95R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017CSR...145...95R">Time series pCO2 at a coastal mooring: Internal consistency, seasonal cycles, and interannual variability</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Reimer, Janet J.; Cai, Wei-Jun; Xue, Liang; Vargas, Rodrigo; Noakes, Scott; Hu, Xinping; Signorini, Sergio R.; Mathis, Jeremy T.; Feely, Richard A.; Sutton, Adrienne J.; Sabine, Christopher; Musielewicz, Sylvia; Chen, Baoshan; Wanninkhof, Rik 2017-08-01 Marine carbonate system monitoring programs often consist of multiple observational methods that include underway cruise data, moored autonomous time series, and discrete water bottle samples. Monitored parameters include all, or some of the following: partial pressure of CO2 of the water (pCO2w) and air, dissolved inorganic carbon (DIC), total alkalinity (TA), and pH. Any combination of at least two of the aforementioned parameters can be used to calculate the others. In this study at the Gray's Reef (GR) mooring in the South Atlantic Bight (SAB) we: examine the internal consistency of pCO2w from underway cruise, moored autonomous time series, and calculated from bottle samples (DIC-TA pairing); describe the seasonal to interannual pCO2w time series variability and air-sea flux (FCO2), as well as describe the potential sources of pCO2w variability; and determine the source/sink for atmospheric pCO2. Over the 8.5 years of GR mooring time series, mooring-underway and mooring-bottle calculated-pCO2w strongly correlate with r-values > 0.90. pCO2w and FCO2 time series follow seasonal thermal patterns; however, seasonal non-thermal processes, such as terrestrial export, net biological production, and air-sea exchange also influence variability. The linear slope of time series pCO2w increases by 5.2 ± 1.4 μatm y-1 with FCO2 increasing 51-70 mmol m-2 y-1. The net FCO2 sign can switch interannually with the magnitude varying greatly. Non-thermal pCO2w is also increasing over the time series, likely indicating that terrestrial export and net biological processes drive the long term pCO2w increase. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017JGRD..122.7664L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017JGRD..122.7664L">Atmospheric deposition and air-sea gas exchange fluxes of DDT and HCH in the Yangtze River Estuary, East China Sea</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Li, Zhongxia; Lin, Tian; Li, Yuanyuan; Jiang, Yuqing; Guo, Zhigang 2017-07-01 The Yangtze River Estuary (YRE) is strongly influenced by the Yangtze River and lies on the pathway of the East Asian Monsoon. This study examined atmospheric deposition and air-sea gas exchange fluxes of dichlorodiphenyltrichloroethane (DDT) and hexachlorocyclohexane (HCH) to determine whether the YRE is a sink or source of selected pesticides at the air-water interface under the influences of river input and atmospheric transport. The air-sea gas exchange of DDT was characterized by net volatilization with a marked difference in its fluxes between summer (140 ng/m2/d) and the other three seasons (12 ng/m2/d), possibly due to the high surface seawater temperatures and larger riverine input in summer. However, there was no obvious seasonal variation in the atmospheric HCH deposition, and the air-sea gas exchange reached equilibrium because of low HCH levels in the air and seawater after the long-term banning of HCH and the degradation. The gas exchange flux of HCH was comparable to the dry and wet deposition fluxes at the air-water interface. This suggests that the influences from the Yangtze River input and East Asian continental outflow on the fate of HCH in the YRE were limited. The gas exchange flux of DDT was about fivefold higher than the total dry and wet deposition fluxes. DDT residues in agricultural soil transported by enhanced riverine runoff were responsible for sustaining such a high net volatilization in summer. Moreover, our results indicated that there were fresh sources of DDT from the local environment to sustain net volatilization throughout the year. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2009AGUFM.B23A0357G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2009AGUFM.B23A0357G">Positive feedback between increasing atmospheric CO2 and ecosystem productivity</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Gelfand, I.; Hamilton, S. K.; Robertson, G. P. 2009-12-01 Increasing atmospheric CO2 will likely affect both the hydrologic cycle and ecosystem productivity. Current assumptions that increasing CO2 will lead to increased ecosystem productivity and plant water use efficiency (WUE) are driving optimistic predictions of higher crop yields as well as greater availability of freshwater resources due to a decrease in evapotranspiration. The plant physiological response that drives these effects is believed to be an increase in carbon uptake either by (a) stronger CO2 gradient between the stomata and the atmosphere, or by (b) reduced CO2 limitation of enzymatic carboxylation within the leaf. The (a) scenario will lead to increased water use efficiency (WUE) in plants. However, evidence for increased WUE is mostly based on modeling studies, and experiments producing a short duration or step-wise increase in CO2 concentration (e.g. free-air CO2 enrichment). We hypothesize that the increase in atmospheric CO2 concentration is having a positive effect on ecosystem productivity and WUE. To investigate this hypothesis, we analyzed meteorological, ANPP, and soil CO2 flux datasets together with carbon isotopic ratio (13C/12C) of archived plant samples from the long term ecological research (LTER) program at Kellogg Biological Station. The datasets were collected between 1989 and 2007 (corresponding to an increase in atmospheric CO2 concentration of ~33 ppmv at Mauna Loa). Wheat (Triticum aestivum) samples taken from 1989 and 2007 show a significant decrease in the C isotope discrimination factor (Δ) over time. Stomatal conductance is directly related to Δ, and thus Δ is inversely related to plant intrinsic WUE (iWUE). Historical changes in the 13C/12C ratio (δ13C) in samples of a perennial forb, Canada goldenrod (Solidago canadensis), taken from adjacent successional fields, indicate changes in Δ upon uptake of CO2 as well. These temporal trends in Δ suggest a positive feedback between the increasing CO2 concentration in the </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AGUFM.B21H0573M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AGUFM.B21H0573M">Beyond the Methanogenic Black-Box: Greenhouse Gas Fluxes (CO2, CH4, N2O) as Evidence for Wetlands as Dynamic Redox Systems</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Mcnicol, G.; Knox, S. H.; Sturtevant, C. S.; Baldocchi, D. D.; Silver, W. L. 2015-12-01 Seminal wetland research in the 1990s demonstrated that annual methane (CH4) fluxes scaled positively with ecosystem production across distinctive wetlands globally. This relationship implies a model of flooded wetland ecosystems as 'methanogenic black-boxes'; poised at a low redox state, and tending to release a fixed fraction of incoming annual productivity as CH4. In contrast, recent studies have reported high ratios of carbon dioxide (CO2) to CH4 emissions, and are adding to a body of evidence suggesting wetlands can vary more widely in their redox state. To explore this apparent incongruence we used principles of redox thermodynamics and laboratory experiments to develop predictions of wetland greenhouse gas (GHG) fluxes under different redox regimes. We then used a field study to test the hypothesis that ecosystem seasonality in gross primary productivity (GPP) and temperature would drive changes in GHG emissions, mediated by a dynamic - as opposed to static - redox regime. We estimated wetland GHG emissions from an emergent marsh in the Sacramento Delta, CA from March 2014-2015. We measured CO2, CH4 and N2O emissions via diffusion and ebullition with manual sampling, and whole-ecosystem fluxes of CO2 and CH4 using eddy-covariance. Ebullition and diffusive CH4 fluxes were strongly seasonal, with minimum rates (0.86 and 0.35 mg C-CH4 m-2 yr-1, respectively) during winter, and maximum rates (1.3 and 1.8 g C-CH4 m-2 yr-1, respectively) during the summer growing season. In contrast, winter diffusive CO2 fluxes (494 g C-CO2 m-2 yr-1) and fall bubble CO2 concentrations (1.49%) were highest, despite being seasons of lower GPP, temperature, and CH4 flux. Further, diffusive and ebullition fluxes of N2O showed zero net flux only during spring and summer months, whereas the wetland was a significant source of N2O during winter (81.2 ± 24.4 mg N-N2O m-2 yr-1). These seasonal flux dynamics contradict a 'methanogenic black box' model of wetland redox, which </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016EGUGA..18.9131O','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016EGUGA..18.9131O">Preliminary results on yield and CO2 fluxes when using alternate wetting and drying on different varieties of European rice</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Oliver, Viktoria; Monaco, Stefano; Volante, Andrea; Cochrane, Nicole; Gennaro, Massimo; Orasen, Gabriele; Valè, Giampiero; Price, Adam; Arn Teh, Yit 2016-04-01 In Europe, rice is grown (467 000 ha) under permanently flooded conditions (PF) using irrigation waters of major rivers. Climate change, which has led to a greater fluctuation in river flows, is a major challenge to rice production systems, which depend on large and consistent water supplies. This challenge will become more acute in the future, with more frequent extreme weather (e.g. drought) predicted under climate change and increased demands for rice. Alternate wetting and drying (AWD) is a system in where irrigation is applied to obtain 2-5 cm of field water depth, after which the soil is allowed to drain naturally to typically 15 cm below the surface before re-wetting once more. Preliminary studies suggest that AWD can reduce water use by up 30 %, with no net loss in yield but significantly reducing CH4 emissions. However, uncertainties still remain as to the impacts of AWD on CO2 exchange, N2O fluxes, and plant acclimation responses to a fluctuating water regime. For example, CO2 emissions could potentially increase in AWD due to higher rates of soil organic matter decomposition when the fields are drained. The work presented here evaluated the impacts of AWD on the productivity and yield of twelve varieties of European rice, whilst simultaneously measuring CO2 exchange, N2O fluxes, and plant biomass allocation patterns under different treatment regimes. Field experiments were conducted in the Piedmont region (northern Italy Po river plain) in a loamy soil during the growing season of 2015 in a 2-factor paired plot design, with water treatment (AWD, PF) and variety (12 European varieties) as factors (n=4 per variety per treatment). The varieties chosen were commercially important cultivars from across the rice growing regions of Europe (6 Italian, 3 French, 3 Spanish). Light and dark CO2 fluxes were measured six times over the growing season, using an infra-red gas analyzer. Environmental variables (soil moisture, temperature, water table depth, water </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/27836385','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/27836385">Behavior of CO2/water flow in porous media for CO2 geological storage.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Jiang, Lanlan; Yu, Minghao; Liu, Yu; Yang, Mingjun; Zhang, Yi; Xue, Ziqiu; Suekane, Tetsuya; Song, Yongchen 2017-04-01 A clear understanding of two-phase fluid flow properties in porous media is of importance to CO 2 geological storage. The study visually measured the immiscible and miscible displacement of water by CO 2 using MRI (magnetic resonance imaging), and investigated the factor influencing the displacement process in porous media which were filled with quartz glass beads. For immiscible displacement at slow flow rates, the MR signal intensity of images increased because of CO 2 dissolution; before the dissolution phenomenon became inconspicuous at flow rate of 0.8mLmin -1 . For miscible displacement, the MR signal intensity decreased gradually independent of flow rates, because supercritical CO 2 and water became miscible in the beginning of CO 2 injection. CO 2 channeling or fingering phenomena were more obviously observed with lower permeable porous media. Capillary force decreases with increasing particle size, which would increase permeability and allow CO 2 and water to invade into small pore spaces more easily. The study also showed CO 2 flow patterns were dominated by dimensionless capillary number, changing from capillary finger to stable flow. The relative permeability curve was calculated using Brooks-Corey model, while the results showed the relative permeability of CO 2 slightly decreases with the increase of capillary number. Copyright Â© 2016 Elsevier Inc. All rights reserved. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_20");'>20</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li class="active">22</li> <li><a href="#" onclick='return showDiv("page_23");'>23</a></li> <li><a href="#" onclick='return showDiv("page_24");'>24</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_23" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li class="active">23</li> <li><a href="#" onclick='return showDiv("page_24");'>24</a></li> <li><a href="#" onclick='return showDiv("page_25");'>25</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="441"> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/21096927','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/21096927">Tactile communication using a CO(2) flux stimulation for blind or deafblind people.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> da Cunha, Jose Carlos; Bordignon, Luiz Alberto; Nohama, Percy 2010-01-01 This paper describes a tactile stimulation system for producing nonvisual image patterns to blind or deafblind people. The stimulator yields a CO(2) pulsatile flux directed to the user's skin throughout a needle that is coupled to a 2-D tactile plotter. The fluxtactile plotter operates with two step motor mounted on a wood structure, controlled by a program developed to produce alphanumerical characters and geometric figures of different size and speed, which will be used to investigate the psychophysical properties of this kind of tactile communication. CO(2) is provided by a cylinder that delivers a stable flux, which is converted to a pulsatile mode through a high frequency solenoid valve that can chop it up to 1 kHz. Also, system temperature is controlled by a Peltier based device. Tests on the prototype indicate that the system is a valuable tool to investigate the psychophysical properties of the skin in response to stimulation by CO(2) jet, allowing a quantitative and qualitative analysis as a function of stimulation parameters. With the system developed, it was possible to plot the geometric figures proposed: triangles, rectangles and octagons, in different sizes and speeds, and verify the control of the frequency of CO(2) jet stimuli. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.A33A2334Z','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.A33A2334Z">Constraining biosphere CO2 flux at regional scale with WRF-CO2 4DVar assimilation system</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Zheng, T. 2017-12-01 The WRF-CO2 4DVar assimilation system is updated to include (1) operators for tower based observations (2) chemistry initial and boundary condition in the state vector (3) mechanism for aggregation from simulation model grid to state vector space. The update system is first tested with synthetic data to ensure its accuracy. The system is then used to test regional scale CO2 inversion at MCI (Midcontinental intensive) sites where CO2 mole fraction data were collected at multiple high towers during 2007-2008. The model domain is set to center on Iowa and include 8 towers within its boundary, and it is of 12x12km horizontal grid spacing. First, the relative impacts of the initial and boundary condition are assessed by the system's adjoint model. This is done with 24, 48, 72 hour time span. Second, we assessed the impacts of the transport error, including the misrepresentation of the boundary layer and cumulus activities. Third, we evaluated the different aggregation approach from the native model grid to the control variables (including scaling factors for flux, initial and boundary conditions). Four, we assessed the inversion performance using CO2 observation with different time-interval, and from different tower levels. We also examined the appropriate treatment of the background and observation error covariance in relation with these varying observation data sets. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.fs.usda.gov/treesearch/pubs/34913','TREESEARCH'); return false;" href="https://www.fs.usda.gov/treesearch/pubs/34913">Re-assessment of plant carbon dynamics at the Duke free-air CO2 enrichment site: interactions of atmospheric [CO2] with nitrogen and water availability over stand development</a> <a target="_blank" href="http://www.fs.usda.gov/treesearch/">Treesearch</a> Heather R. McCarthy; Ram Oren; Kurt H Johnsen; Anne Gallet-Budynek; Seth G. Pritchard; Charles W Cook; Shannon L. LaDeau; Robert B. Jackson; Adrien C. Finzi 2010-01-01 The potential for elevated [CO2]-induced changes to plant carbon (C) storage, through modifications in plant production and allocation of C among plant pools, is an important source of uncertainty when predicting future forest function. Utilizing 10 yr of data from the Duke free-air CO2 enrichment site, we evaluated the... </li> <li> <a target="_blank" onclick="trackOutboundLink('http://hdl.handle.net/2060/20000116508','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20000116508">BOREAS AFM-2 Wyoming King Air 1994 Aircraft Sounding Data</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Kelly, Robert D.; Hall, Forrest G. (Editor); Knapp, David E. (Editor); Smith, David E. (Technical Monitor) 2000-01-01 The BOREAS AFM-2 team used the University of Wyoming King Air aircraft during IFCs 1, 2, and 3 in 1994 to collected pass-by-pass fluxes (and many other statistics) for the large number of level (constant altitude), straight-line passes used in a variety of flight patterns over the SSA and NSA and areas along the transect between these study areas. The data described here form a second set, namely soundings that were incorporated into nearly every research flight by the King Air in 1994. These soundings generally went from near the surface to above the inversion layer. Most were flown immediately after takeoff or immediately after finishing the last flux pattern of that particular day's flights. The parameters that were measured include wind direction, wind speed, west wind component (u), south wind component (v), static pressure, air dry bulb temperature, potential temperature, dewpoint, temperature, water vapor mixing ratio, and CO2 concentration. Data on the aircraft's location, attitude, and altitude during data collection are also provided. These data are stored in tabular ASCH files. The data files are available on a CD-ROM (see document number 20010000884) or from the Oak Ridge National Laboratory (ORNL) Distributed Active Archive Center (DAAC). </li> <li> <a target="_blank" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70159437','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70159437">Component-specific dynamics of riverine mangrove CO2 efflux in the Florida coastal Everglades</a> <a target="_blank" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Troxler, Tiffany G.; Barr, Jordan G.; Fuentes, Jose D.; Engel, Victor C.; Anderson, Gordon H.; Sanchez, Christopher; Lagomosino, David; Price, Rene; Davis, Stephen E. 2015-01-01 Carbon cycling in mangrove forests represents a significant portion of the coastal wetland carbon (C) budget across the latitudes of the tropics and subtropics. Previous research suggests fluctuations in tidal inundation, temperature and salinity can influence forest metabolism and C cycling. Carbon dioxide (CO2) from respiration that occurs from below the canopy is contributed from different components. In this study, we investigated variation in CO2 flux among different below-canopy components (soil, leaf litter, course woody debris, soil including pneumatophores, prop roots, and surface water) in a riverine mangrove forest of Shark River Slough estuary, Everglades National Park (Florida, USA). The range in CO2 flux from different components exceeded that measured among sites along the oligohaline-saline gradient. Black mangrove (Avicennia germinans) pneumatophores contributed the largest average CO2 flux. Over a narrow range of estuarine salinity (25–35 practical salinity units (PSU)), increased salinity resulted in lower CO2 flux to the atmosphere. Tidal inundation reduced soil CO2 flux overall but increased the partial pressure of CO2 (pCO2) observed in the overlying surface water upon flooding. Higher pCO2 in surface water is then subject to tidally driven export, largely as HCO3. Integration and scaling of CO2 flux rates to forest scale allowed for improved understanding of the relative contribution of different below-canopy components to mangrove forest ecosystem respiration (ER). Summing component CO2fluxes suggests a more significant contribution of below-canopy respiration to ER than previously considered. An understanding of below-canopy CO2 component fluxes and their contributions to ER can help to elucidate how C cycling will change with discrete disturbance events (e.g., hurricanes) and long-term change, including sea-level rise, and potential impact mangrove forests. As such, key controls on below-canopy ER must be taken into consideration when </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AGUFM.V13C3147T','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AGUFM.V13C3147T">The CO2 Flux and the Chemistry of the Crater lake in 2013-2015 Evidence for the Enhanced Activity of El Chichon volcano, Mexico.</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Taran, Y.; Jácome Paz, M. P.; Inguaggiato, S.; Collard, N. 2015-12-01 During 2013-2015, four CO2 flux surveys were performed in the El Chichon crater both, from the lake surface and from the soil of the crater. The chemistry of the lake water, as well as its physical parameters (surface area, depth, temperature) were also determined. The CO2 flux in 2014-2015 compared to the 2007-2008 data (Mazot et al., 2011, BV, 73: 423-441) increased almost one order of magnitude (from ~ 140 ton d-1 in 2008 to ~ 840 ton d-1 in 2014). During the last two years the lake became the largest for the whole time of observations with the maximum surface area more than 18 ha covering completely the NE fumarolic field and all thermal springs feeding the lake with mineralized water. Despite the maximum volume of the lake it was characterized in 2015 by the highest since 2007 chloride content (~2500 ppm) and temperature (34°C). A large degassing spot in the middle of the lake for the first time was observed in April 2015 with more than 10,000 g m-2 d-1 of the CO2 flux. These observations evidence that the volcano-hydrothermal system of El Chichon volcano came into a new stage of activity associated most probably with changes in the magmatic activity at depth. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2003AGUFM.B41A..07P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2003AGUFM.B41A..07P">Land-use change effects on fluxes and isotopic composition of CO2 and CH4 in Panama, and possible insights into the atmospheric H2 cycle</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Pendall, E.; Schwendenmann, L.; Potvin, C. 2003-12-01 Land-use changes in tropical regions are believed to release a quantity of C to the atmosphere which is similar in magnitude to the entire "missing" sink for anthropogenic CO2. Our research attempts to evaluate carbon cycling in three land-cover systems in central Panama: cow pasture, native tree plantation, and undisturbed moist forest. In this ongoing project, we are collecting samples of air from profiles in the stable, nocturnal boundary layer, which is dominated by ecosystem respiration. Samples are analyzed for CO2 and its isotopes, CH4 and its C isotopic composition, N2O, H2, CO, and SF6. We use a flux-gradient method to estimate ecosystem-scale fluxes of trace gases from soil to the atmosphere. Keeling plot intercepts reflect the respiratory contribution of C3 and C4 biomass under contrasting land cover systems, and how this varies with pronounced wet-dry seasonal cycles. C isotopes of methane and gradients of molecular hydrogen provide insight into the source of methane production from pasture and plantation soils. Rainforest soils, in contrast, are sinks for both atmospheric methane and hydrogen. The process oriented nature of this field experiment will contribute to parameterization of carbon cycle models at a variety of spatial scales. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5292819','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5292819">Effect of Leaf Water Potential on Internal Humidity and CO2 Dissolution: Reverse Transpiration and Improved Water Use Efficiency under Negative Pressure</a> <a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Vesala, Timo; Sevanto, Sanna; Grönholm, Tiia; Salmon, Yann; Nikinmaa, Eero; Hari, Pertti; Hölttä, Teemu 2017-01-01 The pull of water from the soil to the leaves causes water in the transpiration stream to be under negative pressure decreasing the water potential below zero. The osmotic concentration also contributes to the decrease in leaf water potential but with much lesser extent. Thus, the surface tension force is approximately balanced by a force induced by negative water potential resulting in concavely curved water-air interfaces in leaves. The lowered water potential causes a reduction in the equilibrium water vapor pressure in internal (sub-stomatal/intercellular) cavities in relation to that over water with the potential of zero, i.e., over the flat surface. The curved surface causes a reduction also in the equilibrium vapor pressure of dissolved CO2, thus enhancing its physical solubility to water. Although the water vapor reduction is acknowledged by plant physiologists its consequences for water vapor exchange at low water potential values have received very little attention. Consequences of the enhanced CO2 solubility to a leaf water-carbon budget have not been considered at all before this study. We use theoretical calculations and modeling to show how the reduction in the vapor pressures affects transpiration and carbon assimilation rates. Our results indicate that the reduction in vapor pressures of water and CO2 could enhance plant water use efficiency up to about 10% at a leaf water potential of −2 MPa, and much more when water potential decreases further. The low water potential allows for a direct stomatal water vapor uptake from the ambient air even at sub-100% relative humidity values. This alone could explain the observed rates of foliar water uptake by e.g., the coastal redwood in the fog belt region of coastal California provided the stomata are sufficiently open. The omission of the reduction in the water vapor pressure causes a bias in the estimates of the stomatal conductance and leaf internal CO2 concentration based on leaf gas exchange </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28220128','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28220128">Effect of Leaf Water Potential on Internal Humidity and CO2 Dissolution: Reverse Transpiration and Improved Water Use Efficiency under Negative Pressure.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Vesala, Timo; Sevanto, Sanna; Grönholm, Tiia; Salmon, Yann; Nikinmaa, Eero; Hari, Pertti; Hölttä, Teemu 2017-01-01 The pull of water from the soil to the leaves causes water in the transpiration stream to be under negative pressure decreasing the water potential below zero. The osmotic concentration also contributes to the decrease in leaf water potential but with much lesser extent. Thus, the surface tension force is approximately balanced by a force induced by negative water potential resulting in concavely curved water-air interfaces in leaves. The lowered water potential causes a reduction in the equilibrium water vapor pressure in internal (sub-stomatal/intercellular) cavities in relation to that over water with the potential of zero, i.e., over the flat surface. The curved surface causes a reduction also in the equilibrium vapor pressure of dissolved CO 2 , thus enhancing its physical solubility to water. Although the water vapor reduction is acknowledged by plant physiologists its consequences for water vapor exchange at low water potential values have received very little attention. Consequences of the enhanced CO 2 solubility to a leaf water-carbon budget have not been considered at all before this study. We use theoretical calculations and modeling to show how the reduction in the vapor pressures affects transpiration and carbon assimilation rates. Our results indicate that the reduction in vapor pressures of water and CO 2 could enhance plant water use efficiency up to about 10% at a leaf water potential of -2 MPa, and much more when water potential decreases further. The low water potential allows for a direct stomatal water vapor uptake from the ambient air even at sub-100% relative humidity values. This alone could explain the observed rates of foliar water uptake by e.g., the coastal redwood in the fog belt region of coastal California provided the stomata are sufficiently open. The omission of the reduction in the water vapor pressure causes a bias in the estimates of the stomatal conductance and leaf internal CO 2 concentration based on leaf gas exchange </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015ACPD...15.1915M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015ACPD...15.1915M">On the ability of a global atmospheric inversion to constrain variations of CO2 fluxes over Amazonia</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Molina, L.; Broquet, G.; Imbach, P.; Chevallier, F.; Poulter, B.; Bonal, D.; Burban, B.; Ramonet, M.; Gatti, L. V.; Wofsy, S. C.; Munger, J. W.; Dlugokencky, E.; Ciais, P. 2015-01-01 The exchanges of carbon, water, and energy between the atmosphere and the Amazon Basin have global implications for current and future climate. Here, the global atmospheric inversion system of the Monitoring of Atmospheric Composition and Climate service (MACC) was used to further study the seasonal and interannual variations of biogenic CO2 fluxes in Amazonia. The system assimilated surface measurements of atmospheric CO2 mole fractions made over more than 100 sites over the globe into an atmospheric transport model. This study added four surface stations located in tropical South America, a region poorly covered by CO2 observations. The estimates of net ecosystem exchange (NEE) optimized by the inversion were compared to independent estimates of NEE upscaled from eddy-covariance flux measurements in Amazonia, and against reports on the seasonal and interannual variations of the land sink in South America from the scientific literature. We focused on the impact of the interannual variation of the strong droughts in 2005 and 2010 (due to severe and longer-than-usual dry seasons), and of the extreme rainfall conditions registered in 2009. The spatial variations of the seasonal and interannual variability of optimized NEE were also investigated. While the inversion supported the assumption of strong spatial heterogeneity of these variations, the results revealed critical limitations that prevent global inversion frameworks from capturing the data-driven seasonal patterns of fluxes across Amazonia. In particular, it highlighted issues due to the configuration of the observation network in South America and the lack of continuity of the measurements. However, some robust patterns from the inversion seemed consistent with the abnormal moisture conditions in 2009. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016JVGR..327..208R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016JVGR..327..208R">Diffuse degassing at Longonot volcano, Kenya: Implications for CO2 flux in continental rifts</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Robertson, Elspeth; Biggs, Juliet; Edmonds, Marie; Clor, Laura; Fischer, Tobias P.; Vye-Brown, Charlotte; Kianji, Gladys; Koros, Wesley; Kandie, Risper 2016-11-01 Magma movement, fault structures and hydrothermal systems influence volatile emissions at rift volcanoes. Longonot is a Quaternary caldera volcano located in the southern Kenyan Rift, where regional extension controls recent shallow magma ascent. Here we report the results of a soil carbon dioxide (CO2) survey in the vicinity of Longonot volcano, as well as fumarolic gas compositions and carbon isotope data. The total non-biogenic CO2 degassing is estimated at < 300 kg d- 1, and is largely controlled by crater faults and fractures close to the summit. Thus, recent volcanic structures, rather than regional tectonics, control fluid pathways and degassing. Fumarolic gases are characterised by a narrow range in carbon isotope ratios (δ13C), from - 4.7‰ to - 6.4‰ (vs. PDB) suggesting a magmatic origin with minor contributions from biogenic CO2. Comparison with other degassing measurements in the East African Rift shows that records of historical eruptions or unrest do not correspond directly to the magnitude of CO2 flux from volcanic centres, which may instead reflect the current size and characteristics of the subsurface magma reservoir. Interestingly, the integrated CO2 flux from faulted rift basins is reported to be an order of magnitude higher than that from any of the volcanic centres for which CO2 surveys have so far been reported. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014ChJOL..32..358Z','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014ChJOL..32..358Z">Pyropia yezoensis can utilize CO2 in the air during moderate dehydration</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Zhou, Wei; He, Linwen; Yang, Fang; Lin, Apeng; Zhang, Baoyu; Niu, Jianfeng; Wang, Guangce 2014-03-01 Pyropia yezoensis, an intertidal seaweed, experiences regular dehydration and rehydration with the tides. In this study, the responses of P. yezoensis to dehydration and rehydration under high and low CO2 concentrations ((600-700)×10-6 and (40-80)×10-6, named Group I and Group II respectively) were investigated. The thalli of Group I had a significantly higher effective photosystem II quantum yield than the thalli of Group II at 71% absolute water content (AWC). There was little difference between thalli morphology, total Rubisco activity and total protein content at 100% and 71% AWC, which might be the basis for the normal performance of photosynthesis during moderate dehydration. A higher effective photosystem I quantum yield was observed in the thalli subjected to a low CO2 concentration during moderate dehydration, which might be caused by the enhancement of cyclic electron flow. These results suggested that P. yezoensis can directly utilize CO2 in ambient air during moderate dehydration. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.A41F0091W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.A41F0091W">An Inversion Analysis of Recent Variability in CO2 Fluxes Using GOSAT and In Situ Observations</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Wang, J. S.; Kawa, S. R.; Baker, D. F.; Collatz, G. J. 2016-12-01 About one-half of the global CO2 emissions from fossil fuel combustion and deforestation accumulates in the atmosphere, where it contributes to global warming. The rest is taken up by vegetation and the ocean. The precise contribution of the two sinks and their location and year-to-year variability are not well understood. We use two different approaches, batch Bayesian synthesis inversion and variational data assimilation, to deduce the global spatiotemporal distributions of CO2 fluxes during 2009-2010. One of our objectives is to assess different sources of uncertainties in inferred fluxes, including uncertainties in prior flux estimates and observations, and differences in inversion techniques. For prior constraints, we utilize fluxes and uncertainties from the CASA-GFED model of the terrestrial biosphere and biomass burning driven by satellite observations. We also use measurement-based ocean flux estimates and fixed fossil CO2 emissions. Our inversions incorporate column CO2 measurements from the GOSAT satellite (ACOS retrieval, bias-corrected) and in situ observations (individual flask and afternoon-average continuous observations) to estimate fluxes in 108 regions over 8-day intervals for the batch inversion and at 3° x 3.75° weekly for the variational system. Relationships between fluxes and atmospheric concentrations are derived consistently for the two inversion systems using the PCTM transport model with MERRA meteorology. We compare the posterior fluxes and uncertainties derived using different data sets and the two inversion approaches, and evaluate the posterior atmospheric concentrations against independent data including aircraft measurements. The optimized fluxes generally resemble each other and those from other studies. For example, a GOSAT-only inversion suggests a shift in the global sink from the tropics/south to the north relative to the prior and to an in-situ-only inversion. The posterior fluxes of the GOSAT inversion are better </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.B43J..06P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.B43J..06P">Responses of CO2 Fluxes to Arctic Browning Events in a Range of High Latitude, Shrub-Dominated Ecosystems</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Phoenix, G. K.; Treharne, R.; Emberson, L.; Tømmervik, H. A.; Bjerke, J. W. 2017-12-01 Climatic and biotic extreme events can result in considerable damage to arctic vegetation, often at landscape and larger scale. These acute events therefore contribute to the browning observed in some arctic regions. It is of considerable concern, therefore, that such extreme events are increasing in frequency as part of climate change. However, despite the increasing importance of browning events, and the considerable impact they can have on ecosystems, to date there is little understanding of their impacts on ecosystem carbon fluxes. To address this, the impacts of a number of different, commonly occurring, extreme events and their subsequent browning (vegetation damage) on key ecosystem CO2 fluxes were assessed during the growing season at a range of event damaged sites of shrub dominated vegetation. Sites were located from the boreal to High Arctic (64˚N-79˚N) and had been previously been damaged by events of frost-drought, extreme winter warming, ground icing and caterpillar (Epirrita autumnata) outbreaks. Plot-level CO2 fluxes of Ecosystem Exchange (NEE), Gross Primary Productivity (GPP) and Ecosystem Respiration (Reco) were assessed using vegetation chambers. At a sub-set of sites, NDVI (greenness) in flux plots was also assessed by hand-held proximal sensor, allowing the relationship between NDVI of damage plots to CO2 flux to be calculated. Despite the contrasting sites and drivers, damage had consistent, major impacts on all fluxes. All sites showed reductions in GPP and NEE with increasing damage, despite efflux from Reco also declining with damage. When scaled to site-level, reductions of up to 81% of NEE, 51% of GPP and 37% of Reco were observed. In the plot-level NDVI-flux relationship, NDVI was shown to explain up to 91% of variation in GPP, and therefore supports the use of NDVI for estimating changes in ecosystem CO2 flux at larger scales in regions where browning has been driven by extreme events. This work is the first attempt to quantify the </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2007AGUFM.B13B1201K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2007AGUFM.B13B1201K">Discovering the Importance of Bi-directional Water Fluxes in Leaves</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Kayler, Z. E.; Saurer, M.; Siegwolf, R. 2007-12-01 The stable isotope ratio 18O/16O is used for constraining climate change models, partitioning ecosystem water fluxes and for studies of plant ecophysiology. Leaf water enrichment is an essential starting point for each of these applications. In order to obtain a complete picture of the role leaf water plays, not only the 18O values from leaf water but also the signature of transpired water must be accurately predicted for plants under varying environmental conditions. We used a novel chamber approach using highly depleted water (-330 ‰) as a vapor source to leaves of the velvet bean (Mucuna pruriens). We used a Walz gas exchange system consisting of a chamber that is controlled for humidity, light, and temperature. Water and carbon dioxide fluxes were measured by an infrared gas analyzer and chamber vapor was collected in cold traps chilled to - 60°C. Three leaves were collected after 2 hours to insure isotopic steady-state followed by leaf water extraction and isotope analysis. From this experiment we were able to measure the outward flux of soil source water and the inward flux of ambient vapor over a range of environments that varied in relative humidity (80%, 45%, 20%), light (50, 1000 μmolm-2s-1) and CO2 (50, 800 ppm). Leaf water isotopic values were below the source water values reflecting the influx of the labeled vapor. The degree to which leaf water values were depleted was strongly related to the relative humidity. The Craig-Gordon model overestimated depletion of leaf water under high relative humidity and predictions were improved with the Péclet correction. However, our initial analysis indicates that these models may not fully account for stomatal conductance in predicting leaf water isotopic values. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.epa.gov/radnet/radnet-air-data-denver-co','PESTICIDES'); return false;" href="https://www.epa.gov/radnet/radnet-air-data-denver-co">RadNet Air Data From Denver, CO</a> <a target="_blank" href="http://www.epa.gov/pesticides/search.htm">EPA Pesticide Factsheets</a> This page presents radiation air monitoring and air filter analysis data for Denver, CO from EPA's RadNet system. RadNet is a nationwide network of monitoring stations that measure radiation in air, drinking water and precipitation. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/26256597','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/26256597">Simultaneous Online Measurement of H2O and CO2 in the Humid CO2 Adsorption/Desorption Process.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Yu, Qingni; Ye, Sha; Zhu, Jingke; Lei, Lecheng; Yang, Bin 2015-01-01 A dew point meter (DP) and an infrared (IR) CO2 analyzer were assembled in a humid CO2 adsorption/desorption system in series for simultaneous online measurements of H2O and CO2, respectively. The humidifier, by using surface-flushing on a saturated brine solution was self-made for the generation of humid air flow. It was found that by this method it became relatively easy to obtain a low H2O content in air flow and that its fluctuation could be reduced compared to the bubbling method. Water calibration for the DP-IR detector is necessary to be conducted for minimizing the measurement error of H2O. It demonstrated that the relative error (RA) for simultaneous online measurements H2O and CO2 in the desorption process is lower than 0.1%. The high RA in the adsorption of H2O is attributed to H2O adsorption on the transfer pipe and amplification of the measurement error. The high accuracy of simultaneous online measurements of H2O and CO2 is promising for investigating their co-adsorption/desorption behaviors, especially for direct CO2 capture from ambient air. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/1996PCE....21..409I','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/1996PCE....21..409I">Eddy-correlation measurements of fluxes of CO 2 and H 2O above a spruce stand</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Ibrom, A.; Schütz, C.; Tworek, T.; Morgenstern, K.; Oltchev, A.; Falk, M.; Constantin, J.; Gravenhorst, G. 1996-12-01 Atmospheric fluxes of CO 2 and H 2O above a mature spruce stand ( Picea abies (L.) Karst.) have been investigated using the eddy- correlation technique. A closed path sensor adapted to the special requirements of long-term studies has been developed and tested. Field measurements have been performed since April 1995. Estimates of fetch showed a very narrow source area dimension under instable stratification (≤ 200 m). Fetch requirements at night are not met in some directions. Energy balance closure was influenced systematically by the wind direction indicating a substantial attenuation of the vertical wind motion by the tower (up to 40 %). Even for optimal flow directions, energy balance closure was about 88%. Intercomparison of the used ultra sonic anemometer (USAT-3) with a GILL - anemometer showed systematically lower values of vertical wind speed fluctuations (13 %). Average CO 2-fluxes ranged between -13 at noon to 3 μ mol m-2, s-1 at night in summer. In November and December the stand released CO 2 on a daily basis. A preliminary estimate of the cumulative net carbon balance over the observed period of 9 months is 4-5 t, Cha-1. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014EGUGA..1615273S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014EGUGA..1615273S">Micrometeorological flux measurements at a coastal site</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Song, Guozheng; Meixner, Franz X.; Bruse, Michael; Mamtimin, Buhalqem 2014-05-01 The eddy covariance (EC) technique is the only direct measurement of the momentum, heat, and trace gas (e.g. water vapor, CO2 and ozone) fluxes. The measurements are expected to be most accurate over flat terrain where there is an extended homogenous surface upwind from the tower, and when the environmental conditions are steady. Additionally, the one dimensional approach assumes that vertical turbulent exchange is the dominant flux, whereas advective influences should be negligible. The application of EC method under non-ideal conditions, for example in complex terrain, has yet to be fully explored. To explore the possibilities and limitations of EC technique under non-ideal conditions, an EC system was set up at Selles beach, Crete, Greece (35.33°N, 25.71°E) in the beginning of July 2012. The dominant wind direction was west, parallel to the coast. The EC system consisted of a sonic anemometer (CSAT3 Campbell Scientific), an infrared open-path CO2/H2O gas analyzer (LI-7500, Li-COR Biosciences) and a fast chemiluminescence ozone analyzer (enviscope GmbH). All the signals of these fast response instruments were sampled at 10 Hz and the measurement height was 3 m. Besides, another gradient system was setup. Air temperature, relative humidity (HYGROMER MP 103 A), and wind speed (WMT700 Vaisala) were measured every 10 seconds at 3 heights (0.7, 1.45, 3 m). Air intakes were set up at 0.7m and 3m. A pump drew the air through a flow system and a telflon valve alternately switched between the two heights every 30 seconds. H2O, CO2 (LI-840A, Li-COR Biosciences) and ozone mixing ratio s (model 205, 2BTechnologies) were measured every 10 seconds. Momentum, heat, CO2 and ozone fluxes were evaluated by both EC and gradient technique. For the calculation of turbulent fluxes, TK3 algorithm (Department of Micrometeorology, University Bayreuth, Germany) was applied. We will present the measured fluxes of the two systems and assess the data quality under such non-ideal condition. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014EGUGA..1611798J','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014EGUGA..1611798J">Chambers versus Relaxed Eddy Accumulation: an intercomparison study of two methods for short-term measurements of biogenic CO2 fluxes</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Jasek, Alina; Zimnoch, Miroslaw; Gorczyca, Zbigniew; Chmura, Lukasz; Necki, Jaroslaw 2014-05-01 The presented work is a part of comprehensive study aimed at thorough characterization of carbon cycle in the urban environment of Krakow, southern Poland. In the framework of this study two independent methods were employed to quantify biogenic CO2 flux in the city: (i) closed chambers, and (ii) Relaxed Eddy Accumulation (REA). The results of a three-day intensive intercomparison campaign performed in July 2013 and utilizing both measurement methods are reported here. The chamber method is a widely used approach for measurements of gas exchange between the soil and the atmosphere. The system implemented in this study consisted of a single chamber operating in a closed-dynamic mode, combined with Vaisala CarboCAP infrared CO2 sensor in a mobile setup. An alternative flux measurement method, covering larger area is represented by REA, which is a modification of the eddy covariance method. It consists of a 3D anemometer (Gill Windmaster Pro) and the system collecting updraft and downdraft samples to 5-litre Tedlar bags. The CO2 mixing ratios in the collected samples are measured by Picarro G2101i analyzer. The setup consists of two sets of bags so that the sampling can be performed continuously with 15-min temporal resolution. A 48-hectares open meadow located close the city center was chosen as a test site for comparison of the two methods of CO2 flux measurements outlined above. In the middle of the meadow a 3-metre high tripod was installed with the anemometer and REA inlet system. For a period of 46 hours the system was measuring net CO2 flux from the surrounding area. A meteorological conditions and intensity of photosynthetically active radiation (PAR) were also recorded. In the same time, CO2 flux from several points around the REA inlet was measured with the chamber system, resulting in 93 values for both respiration and net CO2 flux. Chamber results show rather homogenous distribution of the soil CO2 flux (the mean value equal to 40.9 ± 2.2 mmol/m2h), with </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li class="active">23</li> <li><a href="#" onclick='return showDiv("page_24");'>24</a></li> <li><a href="#" onclick='return showDiv("page_25");'>25</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_24" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li><a href="#" onclick='return showDiv("page_23");'>23</a></li> <li class="active">24</li> <li><a href="#" onclick='return showDiv("page_25");'>25</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="461"> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2008AGUFM.B33A0392D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2008AGUFM.B33A0392D">Global Monthly CO2 Flux Inversion Based on Results of Terrestrial Ecosystem Modeling</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Deng, F.; Chen, J.; Peters, W.; Krol, M. 2008-12-01 Most of our understanding of the sources and sinks of atmospheric CO2 has come from inverse studies of atmospheric CO2 concentration measurements. However, the number of currently available observation stations and our ability to simulate the diurnal planetary boundary layer evolution over continental regions essentially limit the number of regions that can be reliably inverted globally, especially over continental areas. In order to overcome these restrictions, a nested inverse modeling system was developed based on the Bayesian principle for estimating carbon fluxes of 30 regions in North America and 20 regions for the rest of the globe. Inverse modeling was conducted in monthly steps using CO2 concentration measurements of 5 years (2000 - 2005) with the following two models: (a) An atmospheric transport model (TM5) is used to generate the transport matrix where the diurnal variation n of atmospheric CO2 concentration is considered to enhance the use of the afternoon-hour average CO2 concentration measurements over the continental sites. (b) A process-based terrestrial ecosystem model (BEPS) is used to produce hourly step carbon fluxes, which could minimize the limitation due to our inability to solve the inverse problem in a high resolution, as the background of our inversion. We will present our recent results achieved through a combination of the bottom-up modeling with BEPS and the top-down modeling based on TM5 driven by offline meteorological fields generated by the European Centre for Medium Range Weather Forecast (ECMFW). </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AGUFM.A52C..03K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AGUFM.A52C..03K">Evaluation of Diagnostic CO2 Flux and Transport Modeling in NU-WRF and GEOS-5</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Kawa, S. R.; Collatz, G. J.; Tao, Z.; Wang, J. S.; Ott, L. E.; Liu, Y.; Andrews, A. E.; Sweeney, C. 2015-12-01 We report on recent diagnostic (constrained by observations) model simulations of atmospheric CO2 flux and transport using a newly developed facility in the NASA Unified-Weather Research and Forecast (NU-WRF) model. The results are compared to CO2 data (ground-based, airborne, and GOSAT) and to corresponding simulations from a global model that uses meteorology from the NASA GEOS-5 Modern Era Retrospective analysis for Research and Applications (MERRA). The objective of these intercomparisons is to assess the relative strengths and weaknesses of the respective models in pursuit of an overall carbon process improvement at both regional and global scales. Our guiding hypothesis is that the finer resolution and improved land surface representation in NU-WRF will lead to better comparisons with CO2 data than those using global MERRA, which will, in turn, inform process model development in global prognostic models. Initial intercomparison results, however, have generally been mixed: NU-WRF is better at some sites and times but not uniformly. We are examining the model transport processes in detail to diagnose differences in the CO2 behavior. These comparisons are done in the context of a long history of simulations from the Parameterized Chemistry and Transport Model, based on GEOS-5 meteorology and Carnegie Ames-Stanford Approach-Global Fire Emissions Database (CASA-GFED) fluxes, that capture much of the CO2 variation from synoptic to seasonal to global scales. We have run the NU-WRF model using unconstrained, internally generated meteorology within the North American domain, and with meteorological 'nudging' from Global Forecast System and North American Regional Reanalysis (NARR) in an effort to optimize the CO2 simulations. Output results constrained by NARR show the best comparisons to data. Discrepancies, of course, may arise either from flux or transport errors and compensating errors are possible. Resolving their interplay is also important to using the data in </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/16668401','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/16668401">Relationships between the Efficiencies of Photosystems I and II and Stromal Redox State in CO(2)-Free Air : Evidence for Cyclic Electron Flow in Vivo.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Harbinson, J; Foyer, C H 1991-09-01 The responses of the efficiencies of photosystems I and II, stromal redox state (as indicated by NADP-malate dehydrogenase activation state), and activation of the Benson-Calvin cycle enzymes ribulose 1,5-bisphosphate carboxylase and fructose 1,6-bisphosphatase to varying irradiance were measured in pea (Pisum sativum L.) leaves operating close to the CO(2) compensation point. A comparison of the relationships among these parameters obtained from leaves in air was made with those obtained when the leaves were maintained in air from which the CO(2) had been removed. P700 was more oxidized at any measured irradiance in CO(2)-free air than in air. The relationship between the quantum efficiencies of the photosystems in CO(2)-free air was distinctly curvilinear in contrast to the predominantly linear relationship obtained with leaves in air. This nonlinearity may be consistent with the operation of cyclic electron flow around photosystem I because the quantum efficiency of photosystem II was much more restricted than the quantum efficiency of photosystem I. In CO(2)-free air, measured NADP-malate dehydrogenase activities varied considerably at low irradiances. However, at high irradiance the activity of the enzyme was low, implying that the stroma was oxidized. In contrast, fructose-1,6-bisphosphatase activities tended to increase with increasing electron flux through the photosystems. Ribulose-1,5-bisphosphate carboxylase activity remained relatively constant with respect to irradiance in CO(2)-free air, with an activation state 50% of maximum. We conclude that, at the CO(2) compensation point and high irradiance, low redox states are favored and that cyclic electron flow may be substantial. These two features may be the requirements necessary to trigger and maintain the dissipative processes in the thylakoid membrane. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..19.6835B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..19.6835B">Soil management practice in Croatian vineyard affect CO2 fluxes and soil degradation in trafficking zones. First results</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Bogunovic, Igor; Bilandzija, Darija; Andabaka, Zeljko; Stupic, Domagoj; Cacic, Marija; Brezinscak, Luka; Maletic, Edi; Pereira, Paulo; Kisic, Ivica 2017-04-01 Vineyards represent one of the most degradation prone types of intensively managed land on Earth. Steep slopes encourage grape producers to adopt environmental friendly soil management like mulching or continuous no-tillage. In this context, producers have concerns about efficient fertilisation practices and water competitions between vine and grasses in continuous no-tillage inter rows. Vineyards in semi-humid areas like Continental Croatia mostly not suffer from water deficit during growth. Nevertheless, lack of research of different soil management practices open dilemma about soil compaction concerns in intensively trafficked soils in vineyard of semi-humid areas. Soil compaction, determined by bulk density (BD), soil water content (SWC) and CO2 fluxes from trafficked inter row positions were recorded in 2016 in an experiment in which four different soil management systems were compared in a vineyard raised on a silty clay loam soil, near Zagreb, Croatia: No-tillage (NT) system, continuous tillage (CT) and yearly inversed grass covered (INV-GC) and tillage managed (INV-T) inter rows are subjected to intensive traffic. Grape yield and must quality of grape variety Chardonnay was also monitored. Tractor traffic increased the soil BD at 0-10 and 10-20 cm, but especially at the 0-10 cm depth. CT treatment record lowest compaction at 0-10 cm because of tillage. Soil water content showed better conservation possibilities of INV-GC in drier period. In wet period SWC possibilities are similar between treatments. The results of soil compaction under different management indicate that vineyard soil differently response to traffic intensity and impact on microfauna activity and CO2 emissions. INV-GC and NT managed soils record lower CO2 fluxes from vineyard soil compared to CT and INV-T treatments. Management treatments did not statistically influenced on grape yields. Several years of investigation is needed to confirm the overall impact of different management </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4011700','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4011700">Soil Organic Carbon Redistribution by Water Erosion – The Role of CO2 Emissions for the Carbon Budget</a> <a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Wang, Xiang; Cammeraat, Erik L. H.; Romeijn, Paul; Kalbitz, Karsten 2014-01-01 A better process understanding of how water erosion influences the redistribution of soil organic carbon (SOC) is sorely needed to unravel the role of soil erosion for the carbon (C) budget from local to global scales. The main objective of this study was to determine SOC redistribution and the complete C budget of a loess soil affected by water erosion. We measured fluxes of SOC, dissolved organic C (DOC) and CO2 in a pseudo-replicated rainfall-simulation experiment. We characterized different C fractions in soils and redistributed sediments using density fractionation and determined C enrichment ratios (CER) in the transported sediments. Erosion, transport and subsequent deposition resulted in significantly higher CER of the sediments exported ranging between 1.3 and 4.0. In the exported sediments, C contents (mg per g soil) of particulate organic C (POC, C not bound to soil minerals) and mineral-associated organic C (MOC) were both significantly higher than those of non-eroded soils indicating that water erosion resulted in losses of C-enriched material both in forms of POC and MOC. The averaged SOC fluxes as particles (4.7 g C m−2 yr−1) were 18 times larger than DOC fluxes. Cumulative emission of soil CO2 slightly decreased at the erosion zone while increased by 56% and 27% at the transport and depositional zone, respectively, in comparison to non-eroded soil. Overall, CO2 emission is the predominant form of C loss contributing to about 90.5% of total erosion-induced C losses in our 4-month experiment, which were equal to 18 g C m−2. Nevertheless, only 1.5% of the total redistributed C was mineralized to CO2 indicating a large stabilization after deposition. Our study also underlines the importance of C losses by particles and as DOC for understanding the effects of water erosion on the C balance at the interface of terrestrial and aquatic ecosystems. PMID:24802350 </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.B41B0409L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.B41B0409L">A gap-filling model for eddy covariance CO2 flux: Estimating carbon assimilated by a subtropical evergreen broad-leaved forest at the Lien-Hua-Chih flux observation site</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Lan, C. Y.; Li, M. H.; Chen, Y. Y. 2016-12-01 Appropriate estimations of gaps appeared in eddy covariance (EC) flux observations are critical to the reliability of long-term EC applications. In this study we present a semi-parametric multivariate gap-filling model for tower-based measurement of CO2 flux. The raw EC data passing QC/QA was separated into two groups, clear sky, having net radiation greater than 50 W/m2, and nighttime/cloudy. For the clear sky conditions, the principle component analysis (PCA) was used to resolve the multicollinearity relationships among various environmental variables, including net radiation, wind speed, vapor pressure deficit, soil moisture deficit, leaf area index, and soil temperature, in association with CO2 assimilated by forest. After the principal domains were determined by the PCA, the relationships between CO2 fluxes and selected PCs (key factors) were built up by nonlinear interpolations to estimate the gap-filled CO2 flux. In view of limited photosynthesis at nighttime/cloudy conditions, respiration rate of the forest ecosystem was estimated by the Lloyd-Tylor equation. Artificial gaps were randomly selected to exam the applicability of our PCA approach. Based on tower-based measurement of CO2 flux at the Lien-Hua-Chih site, a total of 5.8 ton-C/ha/yr was assimilated in 2012. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2002EGSGA..27.6028L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2002EGSGA..27.6028L">Using New Remotely-sensed Biomass To Estimate Co2 Fluxes Over Siberia</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Lafont, S.; Kergoat, L.; Dedieu, G.; Le Toan, T. Two european programs recently focused on Siberia. The first one, Eurosiberian Car- bonflux was a faisability study for an observation system of the regional CO2 fluxes. The second one, SIBERIA was a big effort to develop and validate a biomass map on Siberia using radar data from satelltes (J-ERS, ERS). Here, we extend the simula- tion of NPP performed for the first program by using the biomass data of the second program. The TURC model, used here, is a global NPP model, based on light use efficiency, where photosynthetic assimilation is driven by satellite vegetation index, and au- totrophic respiration is driven by biomass. In this study, we will present a n´ zoom z on siberian region. The TURC model was run with a fine resolution (few kilometers) and a daily time step. We will discuss the impact of a new biomass dataset description on Net Primary Pro- ductivity (NPP) and CO2 fluxes estimation. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.osti.gov/biblio/6207452-monitoring-seasonal-state-mapping-species-alaskan-taiga-using-imaging-radar-input-co-sub-flux-models','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/6207452-monitoring-seasonal-state-mapping-species-alaskan-taiga-using-imaging-radar-input-co-sub-flux-models">Monitoring seasonal state and mapping species in Alaskan taiga using imaging radar as input to CO[sub 2] flux models</a> <a target="_blank" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Way, J.B.; Rignot, E.; McDonald, K. 1993-06-01 Changes in the seasonal CO[sub 2] flux of the boreal forests may result from increased atmospheric CO[sub 2] concentrations and associated atmospheric warming. To monitor this potential change, a combination of remote sensing information and ecophysiological models are required. In this paper we address the use of synthetic aperture radar (SAR) data to provide some of the input to the ecophysiological models: forest type, freeze/thaw state which limits the growing season for conifers, and leaf on/off state which limits the growing season for deciduous species. AIRSAR data collected in March 1988 during an early thaw event and May 1991 duringmore » spring breakup are used to generate species maps and to determine the sensitivity of SAR to canopy freeze/thaw transitions. These data are also used to validate a microwave scattering model which is then used to determine the sensitivity of SAR to leaf on/off and soil freeze/thaw transitions. Finally, a CO[sub 2] flux algorithm which utilizes SAR data and an ecophysiological model to estimate CO[sub 2] flux is presented. CO[sub 2] flux maps are generated from which areal estimates of CO[sub 2] flux are derived. This work was carried out at the Jet Propulsion Laboratory under contract to the NASA.« less </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016ApJ...816L..28F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016ApJ...816L..28F">N2 and CO Desorption Energies from Water Ice</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Fayolle, Edith C.; Balfe, Jodi; Loomis, Ryan; Bergner, Jennifer; Graninger, Dawn; Rajappan, Mahesh; Öberg, Karin I. 2016-01-01 The relative desorption energies of CO and N2 are key to interpretations of observed interstellar CO and N2 abundance patterns, including the well-documented CO and N2H+ anti-correlations in disks, protostars, and molecular cloud cores. Based on laboratory experiments on pure CO and N2 ice desorption, the difference between CO and N2 desorption energies is small; the N2-to-CO desorption energy ratio is 0.93 ± 0.03. Interstellar ices are not pure, however, and in this study we explore the effect of water ice on the desorption energy ratio of the two molecules. We present temperature programmed desorption experiments of different coverages of 13CO and 15N2 on porous and compact amorphous water ices and, for reference, of pure ices. In all experiments, 15N2 desorption begins a few degrees before the onset of 13CO desorption. The 15N2 and 13CO energy barriers are 770 and 866 K for the pure ices, 1034-1143 K and 1155-1298 K for different submonolayer coverages on compact water ice, and 1435 and 1575 K for ˜1 ML of ice on top of porous water ice. For all equivalent experiments, the N2-to-CO desorption energy ratio is consistently 0.9. Whenever CO and N2 ice reside in similar ice environments (e.g., experience a similar degree of interaction with water ice) their desorption temperatures should thus be within a few degrees of one another. A smaller N2-to-CO desorption energy ratio may be present in interstellar and circumstellar environments if the average CO ice molecules interacts more with water ice compared to the average N2 molecules. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMPP23D..02M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMPP23D..02M">Millennial Variability of Eastern Equatorial Bottom Water Oxygenation and Atmospheric CO2 over the past 100 kyr</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Marcantonio, F.; Loveley, M.; Wisler, M.; Hostak, R.; Hertzberg, J. E.; Schmidt, M. W.; Lyle, M. W. 2017-12-01 Storage of respired carbon in the deep ocean may play a significant role in lowering atmospheric CO2 concentrations by about 80 ppm during the last glacial maximum compared to pre-industrial times. The cause of this sequestration and the subsequent release of the deep respired carbon pool at the last termination remains elusive. Within the last glacial period, on millennial timescales, the relationship between the CO2 cycle and any waxing and waning of a deep respired pool also remains unclear. To further our understanding of the millennial variability in the storage of a deep-ocean respired carbon pool during the last glacial, we measure authigenic uranium and 230Th-derived non-lithogenic barium fluxes (xsBa flux) in two high-sedimentation-rate cores from the Panama Basin of the Eastern Equatorial Pacific (EEP) (8JC, 6° 14.0' N, 86° 02.6' W; 1993 m water depth; 17JC 00° 10.8' S, 85° 52.0' W; 2846 m water depth). Sediment authigenic U concentrations are controlled by the redox state of sediments which, in turn, is a function of the rain of organic material from the surface ocean and the oxygen content of bottom waters. At both 8JC and 17JC, the mismatch between xsBa fluxes, a proxy for the reconstruction of oceanic productivity, and authigenic uranium concentrations suggests that the primary control of the latter values is changes in bottom water oxygenation. Peak authigenic uranium concentrations occur during glacial periods MIS 2, 3, and 4, respectively, and are two to three times higher than those during interglacial periods, MIS 1 and 5. EEP bottom waters were likely suboxic during times of the last glacial period when atmospheric CO2 concentrations were at their lowest concentrations. In addition, the pattern of increased deep-water oxygenation during times of higher CO2 during the last glacial is similar to that reported in a study of authigenic U in sediments from the Antarctic Zone of the Southern Ocean (Jaccard et al., 2016). We suggest that a respired </li> <li> <a target="_blank" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20100032897&hterms=nz&qs=N%3D0%26Ntk%3DAll%26Ntx%3Dmode%2Bmatchall%26Ntt%3Dnz','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20100032897&hterms=nz&qs=N%3D0%26Ntk%3DAll%26Ntx%3Dmode%2Bmatchall%26Ntt%3Dnz">Validation of AIRS Retrievals of CO2 via Comparison to In Situ Measurements</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Olsen, Edward T.; Chahine, Moustafa T.; Chen, Luke L.; Jiang, Xun; Pagano, Thomas S.; Yung, Yuk L. 2008-01-01 Topics include AIRS on Aqua, 2002-present with discussion about continued operation to 2011 and beyond and background, including spectrum, weighting functions, and initialization; comparison with aircraft and FTIR measurements in Masueda (CONTRAIL) JAL flask measurements, Park Falls, WI FTIR, Bremen, GDF, and Spitsbergen, Norway; AIRS retrievals over addition FTIR sites in Darwin, AU and Lauder, NZ; and mid-tropospheric carbon dioxide weather and contribution from major surface sources. Slide titles include typical AIRS infrared spectrum, AIRS sensitivity for retrieving CO2 profiles, independence of CO2 solution with respect to the initial guess, available in situ measurements for validation and comparison, comparison of collocated V1.5x AIRS CO2 (N_coll greater than or equal to 9) with INTEX-NA and SPURT; </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015BGD....12.4405O','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015BGD....12.4405O">Response of CO2 and H2O fluxes of a mountainous tropical rain forest in equatorial Indonesia to El Niño events</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Olchev, A.; Ibrom, A.; Panferov, O.; Gushchina, D.; Propastin, P.; Kreilein, H.; June, T.; Rauf, A.; Gravenhorst, G.; Knohl, A. 2015-03-01 The possible impact of El Niño-Southern Oscillation (ENSO) events on the main components of CO2 and H2O fluxes in a pristine mountainous tropical rainforest growing in Central Sulawesi in Indonesia is described. The fluxes were continuously measured using the eddy covariance method for the period from January 2004 to June 2008. During this period, two episodes of El Niño and one episode of La Niña were observed. All these ENSO episodes had moderate intensity and were of Central Pacific type. The temporal variability analysis of the main meteorological parameters and components of CO2 and H2O exchange showed a very high sensitivity of Evapotranspiration (ET) and Gross Primary Production (GPP) of the tropical rain forest to meteorological variations caused by both El Niño and La Niña episodes. Incoming solar radiation is the main governing factor that is responsible for ET and GPP variability. Ecosystem Respiration (RE) dynamics depend mainly on the air temperature changes and are almost insensitive to ENSO. Changes of precipitation due to moderate ENSO events did not cause any notable effect on ET and GPP, mainly because of sufficient soil moisture conditions even in periods of anomalous reduction of precipitation in the region. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013AGUFM.B51E0337M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013AGUFM.B51E0337M">Expanding Spatial and Temporal Coverage of Arctic CH4 and CO2 Fluxes</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Murphy, P.; Oechel, W. C.; Moreaux, V.; Losacco, S.; Zona, D. 2013-12-01 Carbon storage and exchange in Arctic ecosystems is the subject of intensive study focused on determining rates, controls, and mechanisms of CH4 and CO2 fluxes. The Arctic contains more than 1 Gt of Carbon in the upper meter of soil, both in the active layer and permafrost (Schuur et al., 2008; Tarnocai et al., 2009). However, the annual pattern and controls on the release of CH4 is inadequately understood in Arctic tundra ecosystems. Annual methane budgets are poorly understood, and very few studies measure fluxes through the freeze-up cycle during autumn months (Mastepanov et al., 2008; Mastepanov et al., 2010; Sturtevant et al., 2012). There is no known, relatively continuous, CH4 flux record for the Arctic. Clearly, the datasets that currently exist for budget calculations and model parameterization and verification are inadequate. This is likely due to the difficult nature of flux measurements in the Arctic. In September 2012, we initiated a research project towards continuous methane flux measurements along a latitudinal transect in Northern Alaska. The eddy-covariance (EC) technique is challenging in such extreme weather conditions due to the effects of ice formation and precipitation on instrumentation, including gas analyzers and sonic anemometers. The challenge is greater in remote areas of the Arctic, when low power availability and limited communication can lead to delays in data retrieval or data loss. For these reasons, a combination of open- and closed-path gas analyzers, and several sonic anemometers (including one with heating), have been installed on EC towers to allow for cross-comparison and cross-referencing of calculated fluxes. Newer instruments for fast CH4 flux determination include: the Los Gatos Research Fast Greenhouse Gas Analyzer and the Li-Cor LI-7700. We also included the self-heated Metek Class-A uSonic-3 Anemometer as a new instrument. Previously existing instruments used for comparison include the Li-Cor LI-7500; Li-Cor LI-7200 </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016EGUGA..1814864M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016EGUGA..1814864M">Fluxes of CO2, CH4 and N2O at two European beech forests: linking soil gas production profiles with soil and stem fluxes</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Maier, Martin; Machacova, Katerina; Halaburt, Ellen; Haddad, Sally; Urban, Otmar; Lang, Friederike 2016-04-01 consumption sites of soil gases in the adjacent soil. Soils at both sites took up CH4 and N2O and emitted CO2. Soil gas profiles at the Black Forest showed only CH4 and N2O consumption. CH4 uptake was much larger by the well aerated Black Forest soil than by the loamy-clay soil in the White Carpathians. Here, it was possible to stratify the apparently homogenous site into two plots, one having redoximorphic features in the soil profiles, the other plot without. It seemed that CH4 and N2O were mainly produced in the deeper soil at the plot with temporarily reducing conditions. Beech stems mostly took up N2O from the atmosphere at both sites, whereas CH4 was emitted. The stem CH4 flux was higher for the White Carpathians than for the Black Forest site. Thus, the tree and soil flux of CH4 seems to be affected by soil structure, soil water content and the redox potential in the rooting space. We conclude from our results that trees might provide preferential pathways for greenhouse gases produced in the subsoil thereby enhancing the release of greenhouse gases. Acknowledgement This research was financially supported by the Czech Academy of Sciences and the German Academic Exchange Service within the project "Methane (CH4) and nitrous oxide (N2O) emissions from Fagus sylvatica trees" (DAAD-15-03), National Programme for Sustainability I (LO1415) and project DFG (MA 5826/2-1). We would like to thank Marek Jakubik for technical support and Sinikka Paulus for help by field measurements. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011AGUFM.H23B1252C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011AGUFM.H23B1252C">Non-Volcanic release of CO2 in Italy: quantification, conceptual models and gas hazard</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Chiodini, G.; Cardellini, C.; Caliro, S.; Avino, R. 2011-12-01 Central and South Italy are characterized by the presence of many reservoirs naturally recharged by CO2 of deep provenance. In the western sector, the reservoirs feed hundreds of gas emissions at the surface. Many studies in the last years were devoted to (i) elaborating a map of CO2 Earth degassing of the region; (ii) to asses the gas hazard; (iii) to develop methods suitable for the measurement of the gas fluxes from different types of emissions; (iv) to elaborate the conceptual model of Earth degassing and its relation with the seismic activity of the region and (v) to develop physical numerical models of CO2 air dispersion. The main results obtained are: 1) A general, regional map of CO2 Earth degassing in Central Italy has been elaborated. The total flux of CO2 in the area has been estimated in ~ 10 Mt/a which are released to the atmosphere trough numerous dangerous gas emissions or by degassing spring waters (~ 10 % of the CO2 globally estimated to be released by the Earth trough volcanic activity). 2) An on line, open access, georeferenced database of the main CO2 emissions (~ 250) was settled up (http://googas.ov.ingv.it). CO2 flux > 100 t/d characterise 14% of the degassing sites while CO2 fluxes from 100 t/d to 10 t/d have been estimated for about 35% of the gas emissions. 3) The sites of the gas emissions are not suitable for life: the gas causes many accidents to animals and people. In order to mitigate the gas hazard a specific model of CO2 air dispersion has been developed and applied to the main degassing sites. A relevant application regarded Mefite d'Ansanto, southern Apennines, which is the largest natural emission of low temperature CO2 rich gases, from non-volcanic environment, ever measured in the Earth (˜2000 t/d). Under low wind conditions, the gas flows along a narrow natural channel producing a persistent gas river which has killed over a period of time many people and animals. The application of the physical numerical model allowed us to </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOS.B34A0337O','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOS.B34A0337O">Are changes in the phytoplankton community structure altering the flux of CO2 in regions of the North Atlantic?</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Ostle, C.; Landschutzer, P.; Johnson, M.; Schuster, U.; Watson, A. J.; Edwards, M.; Robinson, C. 2016-02-01 The North Atlantic Ocean is a globally important sink of carbon dioxide (CO2). However, the strength of the sink varies temporally and regionally. This study uses a neural network method to map the surface ocean pCO2 (partial pressure of CO2) and flux of CO2from the atmosphere to the ocean alongside measurements of plankton abundance collected from the Continuous Plankton Recorder (CPR) survey to determine the relationship between regional changes in phytoplankton community structure and regional differences in carbon flux. Despite increasing sea surface temperatures, the Grand Banks of Newfoundland show a decrease in sea surface pCO2 of -2 µatm yr-1 from 1993 to 2011. The carbon flux in the North Sea is variable over the same period. This is in contrast to most of the open ocean within the North Atlantic, where increases in sea surface pCO2 follow the trend of increasing CO2 in the atmosphere, i.e. the flux or sink remains constant. The increasing CO2 sink in the Grand Banks of Newfoundland and the variable sink in the North Sea correlate with changes in phytoplankton community composition. This study investigates the biogeochemical and oceanographic mechanisms potentially linking increasing sea surface temperature, changes in phytoplankton community structure and the changing carbon sink in these two important regions of the Atlantic Ocean. The use of volunteer ships to concurrently collect these datasets demonstrates the potential to investigate relationships between plankton community structure and carbon flux in a cost-effective way. These results not only have implications for plankton-dynamic biogeochemical models, but also likely influence carbon export, as different phytoplankton communities have different carbon export efficiencies. Extending and maintaining such datasets is critical to improving our understanding of and monitoring carbon cycling in the surface ocean and improving climate model accuracy. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015EGUGA..1715214B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015EGUGA..1715214B">Eddy Covariance measurements of stable CO2 and H2O isotopologues</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Braden-Behrens, Jelka; Knohl, Alexander 2015-04-01 The analysis of the stable isotope composition of CO2 and H2O fluxes (such as 13C, 18O and 2H in H2O and CO2) has provided valuable insights into ecosystem gas exchange. The approach builds on differences in the isotope signature of different ecosystem components that are primarily caused by the preference for or the discrimination against respective isotope species by important processes within the ecosystem (e.g. photosynthesis or leaf water diffusion). With the ongoing development of laser spectrometric methods, fast and precise measurements of isotopologue mixing ratios became possible, hence also enabling Eddy Covariance (EC) based approaches to directly measure the isotopic composition of CO2 and H2Ov net fluxes on ecosystem scale. During an eight month long measurement campaign in 2015, we plan to simultaneously measure CO2 and H2Ov isotopologue fluxes using an EC approach in a managed beech forest in Thuringia, Germany. For this purpose, we will use two different laser spectrometers for high frequency measurements of isotopic compositions: For H2Ov measurements, we will use an off axis cavity output water vapour isotope analyser (WVIA, Los Gatos Research Inc.) with 5 Hz response; and for CO2 measurements, we will use a quantum cascade laser-based system (QCLAS, Aerodyne Research Inc.) with thermoelectrically cooled detectors and up to 10 Hz measurement capability. The resulting continuous isotopologue flux measurements will be accompanied by intensive sampling campaigns on the leaf scale: Water from leaf, twig, soil and precipitation samples will be analysed in the lab using isotope ratio mass spectrometry. During data analysis we will put a focus on (i) the influence of carbon and oxygen discrimination on the isotopic signature of respective net ecosystem exchange, (ii) on the relationship between evapotranspiration and leaf water enrichment, and (iii) on the 18O exchange between carbon dioxide and water. At present, we already carried out extensive </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017BGeo...14.5189J','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017BGeo...14.5189J">Year-round CH4 and CO2 flux dynamics in two contrasting freshwater ecosystems of the subarctic</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Jammet, Mathilde; Dengel, Sigrid; Kettner, Ernesto; Parmentier, Frans-Jan W.; Wik, Martin; Crill, Patrick; Friborg, Thomas 2017-11-01 Lakes and wetlands, common ecosystems of the high northern latitudes, exchange large amounts of the climate-forcing gases methane (CH4) and carbon dioxide (CO2) with the atmosphere. The magnitudes of these fluxes and the processes driving them are still uncertain, particularly for subarctic and Arctic lakes where direct measurements of CH4 and CO2 emissions are often of low temporal resolution and are rarely sustained throughout the entire year. Using the eddy covariance method, we measured surface-atmosphere exchange of CH4 and CO2 during 2.5 years in a thawed fen and a shallow lake of a subarctic peatland complex. Gas exchange at the fen exhibited the expected seasonality of a subarctic wetland with maximum CH4 emissions and CO2 uptake in summer, as well as low but continuous emissions of CH4 and CO2 throughout the snow-covered winter. The seasonality of lake fluxes differed, with maximum CO2 and CH4 flux rates recorded at spring thaw. During the ice-free seasons, we could identify surface CH4 emissions as mostly ebullition events with a seasonal trend in the magnitude of the release, while a net CO2 flux indicated photosynthetic activity. We found correlations between surface CH4 emissions and surface sediment temperature, as well as between diel CO2 uptake and diel solar input. During spring, the breakdown of thermal stratification following ice thaw triggered the degassing of both CH4 and CO2. This spring burst was observed in 2 consecutive years for both gases, with a large inter-annual variability in the magnitude of the CH4 degassing. On the annual scale, spring emissions converted the lake from a small CO2 sink to a CO2 source: 80 % of total annual carbon emissions from the lake were emitted as CO2. The annual total carbon exchange per unit area was highest at the fen, which was an annual sink of carbon with respect to the atmosphere. Continuous respiration during the winter partly counteracted the fen summer sink by accounting for, as both CH4 and CO2, 33 </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29714795','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29714795">Humidity-swing mechanism for CO2 capture from ambient air.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Yang, Hao; Singh, Manmilan; Schaefer, Jacob 2018-05-10 A humidity-swing polymeric sorbent captures CO2 from ambient air at room temperature simply by changing the humidity level. To date there has been no direct experimental evidence to characterize the chemical mechanism for this process. In this report we describe the use of solid-state NMR to study the humidity-swing CO2 absorption/desorption cycle directly. We find that at low humidity levels CO2 is absorbed as HCO3-. At high humidity levels, HCO3- is replaced by hydrated OH- and the absorbed CO2 is released. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016EGUGA..1815671H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016EGUGA..1815671H">Effect of photosynthesis on the abundance of 18O13C16O in atmospheric CO2</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Hofmann, Magdalena E. G.; Pons, Thijs L.; Ziegler, Martin; Lourens, Lucas J.; Röckmann, Thomas 2016-04-01 The abundance of the isotopologue 18O13C16O (Δ47) in atmospheric air is a promising new tracer for the atmospheric carbon cycle (Eiler and Schauble, 2004; Affek and Eiler, 2006; Affek et al., 2007). The large gross fluxes in CO2 between the atmosphere and biosphere are supposed to play a major role in controlling its abundance. Eiler and Schauble (2004) set up a box model describing the effect of air-leaf interaction on the abundance of 18O13C16O in atmospheric air. The main assumption is that the exchange between CO2 and water within the mesophyll cells will imprint a Δ47 value on the back-diffusing CO2 that reflects the leaf temperature. Additionally, kinetic effects due to CO2 diffusion into and out of the stomata are thought to play a role. We investigated the effect of photosynthesis on the residual CO2 under controlled conditions using a leaf chamber set-up to quantitatively test the model assumptions suggested by Eiler and Schauble (2004). We studied the effect of photosynthesis on the residual CO2 using two C3 and one C4 plant species: (i) sunflower (Helianthus annuus), a C3 species with a high leaf conductance for CO2 diffusion, (ii) ivy (Hedera hibernica), a C3 species with a low conductance, and (iii), maize (Zea mays), a species with the C4 photosynthetic pathway. We also investigated the effect of different light intensities (photosynthetic photon flux density of 200, 700 and 1800 μmol m2s-1), and thus, photosynthetic rate in sunflower and maize. A leaf was mounted in a cuvette with a transparent window and an adjustable light source. The air inside was thoroughly mixed, making the composition of the outgoing air equal to the air inside. A gas-mixing unit was attached at the entrance of the cuvette that mixed air with a high concentration of scrambled CO2 with a Δ47 value of 0 to 0.1‰ with CO2 free air to set the CO2 concentration of ingoing air at 500 ppm. The flow rate through the cuvette was adjusted to the photosynthetic activity of the leaf </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li><a href="#" onclick='return showDiv("page_23");'>23</a></li> <li class="active">24</li> <li><a href="#" onclick='return showDiv("page_25");'>25</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_25" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li><a href="#" onclick='return showDiv("page_23");'>23</a></li> <li><a href="#" onclick='return showDiv("page_24");'>24</a></li> <li class="active">25</li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="481"> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017JGRC..122.8661B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017JGRC..122.8661B">Oxygen in the Southern Ocean From Argo Floats: Determination of Processes Driving Air-Sea Fluxes</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Bushinsky, Seth M.; Gray, Alison R.; Johnson, Kenneth S.; Sarmiento, Jorge L. 2017-11-01 The Southern Ocean is of outsized significance to the global oxygen and carbon cycles with relatively poor measurement coverage due to harsh winters and seasonal ice cover. In this study, we use recent advances in the parameterization of air-sea oxygen fluxes to analyze 9 years of oxygen data from a recalibrated Argo oxygen data set and from air-calibrated oxygen floats deployed as part of the Southern Ocean Carbon and Climate Observations and Modeling (SOCCOM) project. From this combined data set of 150 floats, we find a total Southern Ocean oxygen sink of -183 ± 80 Tmol yr-1 (positive to the atmosphere), greater than prior estimates. The uptake occurs primarily in the Polar-Frontal Antarctic Zone (PAZ, -94 ± 30 Tmol O2 yr-1) and Seasonal Ice Zone (SIZ, -111 ± 9.3 Tmol O2 yr-1). This flux is driven by wintertime ventilation, with a large portion of the flux in the SIZ passing through regions with fractional sea ice. The Subtropical Zone (STZ) is seasonally driven by thermal fluxes and exhibits a net outgassing of 47 ± 29 Tmol O2 yr-1 that is likely driven by biological production. The Subantarctic Zone (SAZ) uptake is -25 ± 12 Tmol O2 yr-1. Total oxygen fluxes were separated into a thermal and nonthermal component. The nonthermal flux is correlated with net primary production and mixed layer depth in the STZ, SAZ, and PAZ, but not in the SIZ where seasonal sea ice slows the air-sea gas flux response to the entrainment of deep, low-oxygen waters. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014AGUFM.B54C..04S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014AGUFM.B54C..04S">Nitrate loading and CH4 and N2O Flux from headwater streams</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Sousa, C. H. R. D.; Hilker, T.; Hall, F. G.; Moura, Y. M.; McAdam, E. 2014-12-01 Freshwater ecosystems transport and process significant amounts of terrestrial carbon and can be considerable sources of CO2, CH4, and N2O. A great deal of uncertainty, however, remains in both global estimates and our understanding of drivers of freshwater greenhouse gas emissions. Furthermore, small headwater streams have received insufficient attention to date and may contribute disproportionately to global GHG flux. Our objective was to quantify GHG flux and assess the impact of changes in DOC and NO3 concentrations in surface and subsurface water on flux rates in three streams in the Lamprey River watershed in New Hampshire, USA, that contrast in surface water DOC:NO3. We measured DOC, NO3 and dissolved gas concentrations in surface waters of each stream monthly from May 2011 to April 2012. Empirical measurements of reaeration coefficients were used to convert dissolved gas concentrations to fluxes. We found higher GHG concentrations and fluxes in the two streams with high DOC concentrations, particularly gases produced by anaerobic metabolism (CH4, N2O from methanogenesis and denitrification, respectively). The stream with high DOC and high NO3 showed high N2O and low CH4 flux, while the high DOC, low NO3 stream showed high CH4 and low N2O flux. Our results are consistent with a model in which C inputs drive total GHG production, while NO3 input regulates the relative importance of CH4 and N2O by suppressing methanogenesis and stimulating denitrification. The magnitude of GHG fluxes suggests that streams in this region are likely to be small sources of CO2, but potentially important sources of CH4 and N2O. Since CH4 and N2O are many times more powerful than CO2 at trapping heat in the atmosphere, freshwater emissions of these gases have the potential to offset a significant proportion of the climate benefits of the terrestrial carbon sink, a possibility that has not been sufficiently incorporated into climate models. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AGUFM.B54C..04S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AGUFM.B54C..04S">Nitrate loading and CH4 and N2O Flux from headwater streams</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Schade, J. D.; Bailio, J.; McDowell, W. H. 2015-12-01 Freshwater ecosystems transport and process significant amounts of terrestrial carbon and can be considerable sources of CO2, CH4, and N2O. A great deal of uncertainty, however, remains in both global estimates and our understanding of drivers of freshwater greenhouse gas emissions. Furthermore, small headwater streams have received insufficient attention to date and may contribute disproportionately to global GHG flux. Our objective was to quantify GHG flux and assess the impact of changes in DOC and NO3 concentrations in surface and subsurface water on flux rates in three streams in the Lamprey River watershed in New Hampshire, USA, that contrast in surface water DOC:NO3. We measured DOC, NO3 and dissolved gas concentrations in surface waters of each stream monthly from May 2011 to April 2012. Empirical measurements of reaeration coefficients were used to convert dissolved gas concentrations to fluxes. We found higher GHG concentrations and fluxes in the two streams with high DOC concentrations, particularly gases produced by anaerobic metabolism (CH4, N2O from methanogenesis and denitrification, respectively). The stream with high DOC and high NO3 showed high N2O and low CH4 flux, while the high DOC, low NO3 stream showed high CH4 and low N2O flux. Our results are consistent with a model in which C inputs drive total GHG production, while NO3 input regulates the relative importance of CH4 and N2O by suppressing methanogenesis and stimulating denitrification. The magnitude of GHG fluxes suggests that streams in this region are likely to be small sources of CO2, but potentially important sources of CH4 and N2O. Since CH4 and N2O are many times more powerful than CO2 at trapping heat in the atmosphere, freshwater emissions of these gases have the potential to offset a significant proportion of the climate benefits of the terrestrial carbon sink, a possibility that has not been sufficiently incorporated into climate models. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012AGUFM.A31H..02T','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012AGUFM.A31H..02T">Quantification of fossil fuel CO2 emissions at the urban scale: Results from the Indianapolis Flux Project (INFLUX)</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Turnbull, J. C.; Cambaliza, M. L.; Sweeney, C.; Karion, A.; Newberger, T.; Tans, P. P.; Lehman, S.; Davis, K. J.; Miles, N. L.; Richardson, S.; Lauvaux, T.; Shepson, P.; Gurney, K. R.; Song, Y.; Razlivanov, I. N. 2012-12-01 Emissions of fossil fuel CO2 (CO2ff) from anthropogenic sources are the primary driver of observed increases in the atmospheric CO2 burden, and hence global warming. Quantification of the magnitude of fossil fuel CO2 emissions is vital to improving our understanding of the global and regional carbon cycle, and independent evaluation of reported emissions is essential to the success of any emission reduction efforts. The urban scale is of particular interest, because ~75% CO2ff is emitted from urban regions, and cities are leading the way in attempts to reduce emissions. Measurements of 14CO2 can be used to determine CO2ff, yet existing 14C measurement techniques require laborious laboratory analysis and measurements are often insufficient for inferring an urban emission flux. This presentation will focus on how 14CO2 measurements can be combined with those of more easily measured ancillary tracers to obtain high resolution CO2ff mixing ratio estimates and then infer the emission flux. A pilot study over Sacramento, California showed strong correlations between CO2ff and carbon monoxide (CO) and demonstrated an ability to quantify the urban flux, albeit with large uncertainties. The Indianapolis Flux Project (INFLUX) aims to develop and assess methods to quantify urban greenhouse gas emissions. Indianapolis was chosen as an ideal test case because it has relatively straightforward meteorology; a contained, isolated, urban region; and substantial and well-known fossil fuel CO2 emissions. INFLUX incorporates atmospheric measurements of a suite of gases and isotopes including 14C from light aircraft and from a network of existing tall towers surrounding the Indianapolis urban area. The recently added CO2ff content is calculated from measurements of 14C in CO2, and then convolved with atmospheric transport models and ancillary data to estimate the urban CO2ff emission flux. Significant innovations in sample collection include: collection of hourly averaged samples to </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016JSSCh.233....8K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016JSSCh.233....8K">Structure and magnetic properties of flux grown single crystals of Co3-xFexSn2S2 shandites</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Kassem, Mohamed A.; Tabata, Yoshikazu; Waki, Takeshi; Nakamura, Hiroyuki 2016-01-01 We report a successful single crystal growth of the shandite-type half-metallic ferromagnet Co3Sn2S2, and its Fe-substituted compounds, Co3-xFexSn2S2, by employing the flux method. Although Fe3Sn2S2 is unstable phase, we found that using the self Sn flux enables us to obtain single phase crystals up to x=0.53. The chemical composition of the grown plate-shaped single crystals was examined using wavelength-dispersive X-ray spectroscopy. The shandite structure with R 3 ̅m symmetry was confirmed by powder X-ray diffraction and the crystal structure parameters were refined using the Rietveld method. Magnetization measurements show suppression of the ferromagnetic order upon Fe-substitution , as well as in other substituted systems such as In- and Ni-substituted Co3Sn2S2. The almost identical magnetic phase diagrams of the Fe- and In-substituted compounds indicate that the electron number is dominantly significant to the magnetism in the Co-based shandite. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20060038619&hterms=taiga&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D10%26Ntt%3Dtaiga','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20060038619&hterms=taiga&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D10%26Ntt%3Dtaiga">(abstract) Monitoring Seasonal State and Mapping Species in Alaskan Taiga Using Imaging Radar as Input to CO(sub 2) Flux Models</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Way, J. B.; Rignot, E.; McDonald, K.; Adams, P.; Viereck, L. 1993-01-01 Changes in the seasonal CO(sub 2) flux of the boreal forests may result from increased atmospheric CO(sub 2) concentrations and associated atmospheric warming. To monitor this potential change, a combination of remote sensing information and ecophysiological models are required. In this paper we address the use of synthetic aperture radar (SAR) data to provide some of the input to the ecophysiological models: forest type, freeze/thaw state which limits the growing season for conifers, and leaf on/off state which limits the growing season for deciduous species. AIRSAR data collected in March 1988 during an early thaw event and May 1991 during spring breakup are used to generate species maps and to determine the sensitivity of SAR to canopy freeze/thaw transitions. These data are also used to validate a microwave scattering model which is then used to determine the sensitivity of SAR to leaf on/off and soil freeze/thaw transitions. Finally, a CO(sub 2) flux algorithm which utilizes SAR data and an ecophysiological model to estimate CO(sub 2) flux is presented. CO(sub 2) flux maps are generated from which areal estimates of CO(sub 2) flux are derived. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018ACP....18.4765N','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018ACP....18.4765N">Estimates of CO2 fluxes over the city of Cape Town, South Africa, through Bayesian inverse modelling</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Nickless, Alecia; Rayner, Peter J.; Engelbrecht, Francois; Brunke, Ernst-Günther; Erni, Birgit; Scholes, Robert J. 2018-04-01 We present a city-scale inversion over Cape Town, South Africa. Measurement sites for atmospheric CO2 concentrations were installed at Robben Island and Hangklip lighthouses, located downwind and upwind of the metropolis. Prior estimates of the fossil fuel fluxes were obtained from a bespoke inventory analysis where emissions were spatially and temporally disaggregated and uncertainty estimates determined by means of error propagation techniques. Net ecosystem exchange (NEE) fluxes from biogenic processes were obtained from the land atmosphere exchange model CABLE (Community Atmosphere Biosphere Land Exchange). Uncertainty estimates were based on the estimates of net primary productivity. CABLE was dynamically coupled to the regional climate model CCAM (Conformal Cubic Atmospheric Model), which provided the climate inputs required to drive the Lagrangian particle dispersion model. The Bayesian inversion framework included a control vector where fossil fuel and NEE fluxes were solved for separately.Due to the large prior uncertainty prescribed to the NEE fluxes, the current inversion framework was unable to adequately distinguish between the fossil fuel and NEE fluxes, but the inversion was able to obtain improved estimates of the total fluxes within pixels and across the domain. The median of the uncertainty reductions of the total weekly flux estimates for the inversion domain of Cape Town was 28 %, but reach as high as 50 %. At the pixel level, uncertainty reductions of the total weekly flux reached up to 98 %, but these large uncertainty reductions were for NEE-dominated pixels. Improved corrections to the fossil fuel fluxes would be possible if the uncertainty around the prior NEE fluxes could be reduced. In order for this inversion framework to be operationalised for monitoring, reporting, and verification (MRV) of emissions from Cape Town, the NEE component of the CO2 budget needs to be better understood. Additional measurements of Δ14C and δ13C isotope </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2007GBioC..21.2015S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2007GBioC..21.2015S">Constraining global air-sea gas exchange for CO2 with recent bomb 14C measurements</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Sweeney, Colm; Gloor, Emanuel; Jacobson, Andrew R.; Key, Robert M.; McKinley, Galen; Sarmiento, Jorge L.; Wanninkhof, Rik 2007-06-01 The 14CO2 released into the stratosphere during bomb testing in the early 1960s provides a global constraint on air-sea gas exchange of soluble atmospheric gases like CO2. Using the most complete database of dissolved inorganic radiocarbon, DI14C, available to date and a suite of ocean general circulation models in an inverse mode we recalculate the ocean inventory of bomb-produced DI14C in the global ocean and confirm that there is a 25% decrease from previous estimates using older DI14C data sets. Additionally, we find a 33% lower globally averaged gas transfer velocity for CO2 compared to previous estimates (Wanninkhof, 1992) using the NCEP/NCAR Reanalysis 1 1954-2000 where the global mean winds are 6.9 m s-1. Unlike some earlier ocean radiocarbon studies, the implied gas transfer velocity finally closes the gap between small-scale deliberate tracer studies and global-scale estimates. Additionally, the total inventory of bomb-produced radiocarbon in the ocean is now in agreement with global budgets based on radiocarbon measurements made in the stratosphere and troposphere. Using the implied relationship between wind speed and gas transfer velocity ks = 0.27<u102>(Sc/660)-0.5 and standard partial pressure difference climatology of CO2 we obtain an net air-sea flux estimate of 1.3 ± 0.5 PgCyr-1 for 1995. After accounting for the carbon transferred from rivers to the deep ocean, our estimate of oceanic uptake (1.8 ± 0.5 PgCyr-1) compares well with estimates based on ocean inventories, ocean transport inversions using ocean concentration data, and model simulations. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/23564676','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/23564676">Lower responsiveness of canopy evapotranspiration rate than of leaf stomatal conductance to open-air CO2 elevation in rice.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Shimono, Hiroyuki; Nakamura, Hirofumi; Hasegawa, Toshihiro; Okada, Masumi 2013-08-01 An elevated atmospheric CO2 concentration ([CO2 ]) can reduce stomatal conductance of leaves for most plant species, including rice (Oryza sativa L.). However, few studies have quantified seasonal changes in the effects of elevated [CO2 ] on canopy evapotranspiration, which integrates the response of stomatal conductance of individual leaves with other responses, such as leaf area expansion, changes in leaf surface temperature, and changes in developmental stages, in field conditions. We conducted a field experiment to measure seasonal changes in stomatal conductance of the uppermost leaves and in the evapotranspiration, transpiration, and evaporation rates using a lysimeter method. The study was conducted for flooded rice under open-air CO2 elevation. Stomatal conductance decreased by 27% under elevated [CO2 ], averaged throughout the growing season, and evapotranspiration decreased by an average of 5% during the same period. The decrease in daily evapotranspiration caused by elevated [CO2 ] was more significantly correlated with air temperature and leaf area index (LAI) rather than with other parameters of solar radiation, days after transplanting, vapor-pressure deficit and FAO reference evapotranspiration. This indicates that higher air temperatures, within the range from 16 to 27 °C, and a larger LAI, within the range from 0 to 4 m(2) m(-2) , can increase the magnitude of the decrease in evapotranspiration rate caused by elevated [CO2 ]. The crop coefficient (i.e. the evapotranspiration rate divided by the FAO reference evapotranspiration rate) was 1.24 at ambient [CO2 ] and 1.17 at elevated [CO2 ]. This study provides the first direct measurement of the effects of elevated [CO2 ] on rice canopy evapotranspiration under open-air conditions using the lysimeter method, and the results will improve future predictions of water use in rice fields. © 2013 John Wiley & Sons Ltd. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016JGRG..121..249W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016JGRG..121..249W">Increased wintertime CO2 loss as a result of sustained tundra warming</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Webb, Elizabeth E.; Schuur, Edward A. G.; Natali, Susan M.; Oken, Kiva L.; Bracho, Rosvel; Krapek, John P.; Risk, David; Nickerson, Nick R. 2016-02-01 Permafrost soils currently store approximately 1672 Pg of carbon (C), but as high latitudes warm, this temperature-protected C reservoir will become vulnerable to higher rates of decomposition. In recent decades, air temperatures in the high latitudes have warmed more than any other region globally, particularly during the winter. Over the coming century, the arctic winter is also expected to experience the most warming of any region or season, yet it is notably understudied. Here we present nonsummer season (NSS) CO2 flux data from the Carbon in Permafrost Experimental Heating Research project, an ecosystem warming experiment of moist acidic tussock tundra in interior Alaska. Our goals were to quantify the relationship between environmental variables and winter CO2 production, account for subnivean photosynthesis and late fall plant C uptake in our estimate of NSS CO2 exchange, constrain NSS CO2 loss estimates using multiple methods of measuring winter CO2 flux, and quantify the effect of winter soil warming on total NSS CO2 balance. We measured CO2 flux using four methods: two chamber techniques (the snow pit method and one where a chamber is left under the snow for the entire season), eddy covariance, and soda lime adsorption, and found that NSS CO2 loss varied up to fourfold, depending on the method used. CO2 production was dependent on soil temperature and day of season but atmospheric pressure and air temperature were also important in explaining CO2 diffusion out of the soil. Warming stimulated both ecosystem respiration and productivity during the NSS and increased overall CO2 loss during this period by 14% (this effect varied by year, ranging from 7 to 24%). When combined with the summertime CO2 fluxes from the same site, our results suggest that this subarctic tundra ecosystem is shifting away from its historical function as a C sink to a C source. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29525712','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29525712">Tidal variability of CO2 and CH4 emissions from the water column within a Rhizophora mangrove forest (New Caledonia).</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Jacotot, Adrien; Marchand, Cyril; Allenbach, Michel 2018-08-01 We performed a preliminary study to quantify CO 2 and CH 4 emissions from the water column within a Rhizophora spp. mangrove forest. Mean CO 2 and CH 4 emissions during the studied period were 3.35±3.62mmolCm -2 h -1 and 18.30±27.72μmolCm -2 h -1 , respectively. CO 2 and CH 4 emissions were highly variable and mainly driven by tides (flow/ebb, water column thickness, neap/spring). Indeed, an inverse relationship between the magnitude of the emissions and the thickness of the water column above the mangrove soil was observed. δ 13 CO 2 values ranged from -26.88‰ to -8.6‰, suggesting a mixing between CO 2 -enriched pore waters and lagoon incoming waters. In addition, CO 2 and CH 4 emissions were significantly higher during ebb tides, mainly due to the progressive enrichment of the water column by diffusive fluxes as its residence time over the forest floor increased. Eventually, we observed higher CO 2 and CH 4 emissions during spring tides than during neap tides, combined to depleted δ 13 CO 2 values, suggesting a higher contribution of soil-produced gases to the emissions. These higher emissions may result from higher renewable of the electron acceptor and enhanced exchange surface between the soil and the water column. This study shows that CO 2 and CH 4 emissions from the water column were not negligible and must be considered in future carbon budgets in mangroves. Copyright © 2018 Elsevier B.V. All rights reserved. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011PhDT.......456K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011PhDT.......456K">A quantitative determination of air-water heat fluxes in Hermit Lake, New Hampshire under varying meteorological conditions, time of day, and time of year</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Kyper, Nicholas D. An extensive heat flux study is performed at Hermit Lake, New Hampshire from May 26, 2010 till November 7, 2010 to determine the effects of the five individual heat fluxes on Hermit Lake and the surrounding amphibian community. Hermit Lake was chosen due to the relatively long meteorological observations record within the White Mountains of New Hampshire, a new lakeside meteorological station, and ongoing phenology studies of the surrounding eco-system. Utilizing meteorological data from the lakeside weather station and moored water temperature sensors, the incident (Qi), blackbody ( Qbnet ), latent (Qe), sensible (Q s), and net (Qn) heat fluxes are calculated. The incident heat flux is the dominate term in the net flux, accounting for 93% of the variance found in Qn and producing a heat gain of ˜ 19x108 J m-2 throughout the period of study. This large gain produces a net gain of heat in the lake until October 1, 2010, where gains by Qi are offset by the large combined losses of Qbnet , Qs, and Qe thereby producing a gradual decline of heat within the lake. The latent and blackbody heat fluxes produce the largest losses of heat in the net heat flux with a total losses of ˜ -8x108 J m-2 and ˜ -7x108 J m-2, respectively. The sensible heat flux is negligible, producing a total minimal loss of ˜ -1x108 J m-2. Overall the net heat produces a net gain of heat of 2x108 J m-2 throughout the study period. Frog calls indicative of breeding are recorded from May 26, 2010 until August 16, 2010. The spring peeper, American toad, and green frog each produced enough actively calling days to be compared to air temperature, surface water temperature, and wind speed data, as well as data from the five heat fluxes. Linear regression analysis reveals that certain water temperature thresholds affect the calling activities of the spring peeper and green frog, while higher wind speeds have a dramatic effect on the calling activities of both the green frog and American toad. All three </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28378907','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28378907">Advanced buffer materials for indoor air CO2 control in commercial buildings.</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Rajan, P E; Krishnamurthy, A; Morrison, G; Rezaei, F 2017-11-01 In this study, we evaluated solid sorbents for their ability to passively control indoor CO 2 concentration in buildings or rooms with cyclic occupancy (eg, offices, bedrooms). Silica supported amines were identified as suitable candidates and systematically evaluated in the removal of CO 2 from indoor air by equilibrium and dynamic techniques. In particular, sorbents with various amine loadings were synthesized using tetraethylenepentamine (TEPA), poly(ethyleneimine) (PEI) and a silane coupling agent 3-aminopropyltriethoxysilane (APS). TGA analysis indicates that TEPA impregnated silica not only displays a relatively high adsorption capacity when exposed to ppm level CO 2 concentrations, but also is capable of desorbing the majority of CO 2 by air flow (eg, by concentration gradient). In 10 L flow-through chamber experiments, TEPA-based sorbents reduced outlet CO 2 by up to 5% at 50% RH and up to 93% of CO 2 adsorbed over 8 hours was desorbed within 16 hours. In 8 m 3 flow-through chamber experiments, 18 g of the sorbent powder spread over a 2 m 2 area removed approximately 8% of CO 2 injected. By extrapolating these results to real buildings, we estimate that meaningful reductions in the CO 2 can be achieved, which may help reduce energy requirements for ventilation and/or improve air quality. © 2017 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015ACP....15.8423M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015ACP....15.8423M">On the ability of a global atmospheric inversion to constrain variations of CO2 fluxes over Amazonia</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Molina, L.; Broquet, G.; Imbach, P.; Chevallier, F.; Poulter, B.; Bonal, D.; Burban, B.; Ramonet, M.; Gatti, L. V.; Wofsy, S. C.; Munger, J. W.; Dlugokencky, E.; Ciais, P. 2015-07-01 The exchanges of carbon, water and energy between the atmosphere and the Amazon basin have global implications for the current and future climate. Here, the global atmospheric inversion system of the Monitoring of Atmospheric Composition and Climate (MACC) service is used to study the seasonal and interannual variations of biogenic CO2 fluxes in Amazonia during the period 2002-2010. The system assimilated surface measurements of atmospheric CO2 mole fractions made at more than 100 sites over the globe into an atmospheric transport model. The present study adds measurements from four surface stations located in tropical South America, a region poorly covered by CO2 observations. The estimates of net ecosystem exchange (NEE) optimized by the inversion are compared to an independent estimate of NEE upscaled from eddy-covariance flux measurements in Amazonia. They are also qualitatively evaluated against reports on the seasonal and interannual variations of the land sink in South America from the scientific literature. We attempt at assessing the impact on NEE of the strong droughts in 2005 and 2010 (due to severe and longer-than-usual dry seasons) and the extreme rainfall conditions registered in 2009. The spatial variations of the seasonal and interannual variability of optimized NEE are also investigated. While the inversion supports the assumption of strong spatial heterogeneity of these variations, the results reveal critical limitations of the coarse-resolution transport model, the surface observation network in South America during the recent years and the present knowledge of modelling uncertainties in South America that prevent our inversion from capturing the seasonal patterns of fluxes across Amazonia. However, some patterns from the inversion seem consistent with the anomaly of moisture conditions in 2009. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/23087696','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/23087696">Experimental vs. modeled water use in mature Norway spruce (Picea abies) exposed to elevated CO(2).</a> <a target="_blank" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Leuzinger, Sebastian; Bader, Martin K-F 2012-01-01 Rising levels of atmospheric CO(2) have often been reported to reduce plant water use. Such behavior is also predicted by standard equations relating photosynthesis, stomatal conductance, and atmospheric CO(2) concentration, which form the core of dynamic global vegetation models (DGVMs). Here, we provide first results from a free air CO(2) enrichment (FACE) experiment with naturally growing, mature (35 m) Picea abies (L.) (Norway spruce) and compare them to simulations by the DGVM LPJ-GUESS. We monitored sap flow, stem water deficit, stomatal conductance, leaf water potential, and soil moisture in five 35-40 m tall CO(2)-treated (550 ppm) trees over two seasons. Using LPJ-GUESS, we simulated this experiment using climate data from a nearby weather station. While the model predicted a stable reduction of transpiration of between 9% and 18% (at concentrations of 550-700 ppm atmospheric CO(2)), the combined evidence from various methods characterizing water use in our experimental trees suggest no changes in response to future CO(2) concentrations. The discrepancy between the modeled and the experimental results may be a scaling issue: while dynamic vegetation models correctly predict leaf-level responses, they may not sufficiently account for the processes involved at the canopy and ecosystem scale, which could offset the first-order stomatal response. </li> <li> <a target="_blank" onclick="trackOutboundLink('http://hdl.handle.net/2060/20120013671','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20120013671">Does Terrestrial Drought Explain Global CO2 Flux Anomalies Induced by El Nino?</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Schwalm. C. R.; Williams, C. A.; Schaefer, K.; Baker, I.; Collatz, G. J.; Roedenbeck, C. 2011-01-01 The El Nino Southern Oscillation is the dominant year-to-year mode of global climate variability. El Nino effects on terrestrial carbon cycling are mediated by associated climate anomalies, primarily drought, influencing fire emissions and biotic net ecosystem exchange (NEE). Here we evaluate whether El Nino produces a consistent response from the global carbon cycle. We apply a novel bottom-up approach to estimating global NEE anomalies based on FLUXNET data using land cover maps and weather reanalysis. We analyze 13 years (1997-2009) of globally gridded observational NEE anomalies derived from eddy covariance flux data, remotely-sensed fire emissions at the monthly time step, and NEE estimated from an atmospheric transport inversion. We evaluate the overall consistency of biospheric response to El Nino and, more generally, the link between global CO2 flux anomalies and El Nino-induced drought. Our findings, which are robust relative to uncertainty in both methods and time-lags in response, indicate that each event has a different spatial signature with only limited spatial coherence in Amazonia, Australia and southern Africa. For most regions, the sign of response changed across El Nino events. Biotic NEE anomalies, across 5 El Nino events, ranged from -1.34 to +0.98 Pg Cyr(exp -1, whereas fire emissions anomalies were generally smaller in magnitude (ranging from -0.49 to +0.53 Pg C yr(exp -1). Overall drought does not appear to impose consistent terrestrial CO2 flux anomalies during El Ninos, finding large variation in globally integrated responses from 11.15 to +0.49 Pg Cyr(exp -1). Despite the significant correlation between the CO2 flux and El Nino indices, we find that El Nino events have, when globally integrated, both enhanced and weakened terrestrial sink strength, with no consistent response across events </li> <li> <a target="_blank" onclick="trackOutboundLink('http://www.ars.usda.gov/research/publications/publication/?seqNo115=335224','TEKTRAN'); return false;" href="http://www.ars.usda.gov/research/publications/publication/?seqNo115=335224">How accurately do maize crop models simulate the interactions of atmospheric CO2 concentration levels with limited water supply on water use and yield?</a> <a target="_blank" href="https://www.ars.usda.gov/research/publications/find-a-publication/">USDA-ARS?s Scientific Manuscript database</a> This study assesses the ability of 21 crop models to capture the impact of elevated CO2 concentration ([CO218 ]) on maize yield and water use as measured in a 2-year Free Air Carbon dioxide Enrichment experiment conducted at the Thünen Institute in Braunschweig, Germany (Manderscheid et al. 2014). D... </li> <li> <a target="_blank" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20040046904&hterms=CO2+H2O&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D90%26Ntt%3DCO2%2BH2O','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20040046904&hterms=CO2+H2O&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D90%26Ntt%3DCO2%2BH2O">[CO2 Budget and Atmospheric Rectification (COBRA) Over North America</a> <a target="_blank" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> 2004-01-01 The purpose of the CO2 Budget and Rectification Airborne (COBRA) study was to assess terrestrial sources and sinks of carbon dioxide using an air-borne study. The study was designed to address the measurement gap between plot-scale direct flux measurements and background hemispheric-scale constraints and to refine techniques for measuring terrestrial fluxes at regional to continental scales. The initial funded effort (reported on here) was to involve two air-borne campaigns over North America, one in summer and one in winter. Measurements for COBRA (given the acronym C02BAR in the initial proposal) were conducted from the University of North Dakota Citation 11, a twin-engine jet aircraft capable of profiling from the surface to 12 km and cruising for up to 4 hours and 175m/s. Onboard instrumentation measured concentrations of CO2, CO, and H2O, and meteorological parameters at high rates. In addition, two separate flask sampling systems collected discrete samples for laboratory analysis of CO2,CO, CH4, N2O, SF6, H2, 13CO2, C18O16O,O2/N2, and Ar/N2. The project involved a collaboration between a number of institutions, including (but not limited to) Harvard, NOAA-CMDL, the University of North Dakota, and Scripps. </li> <li> <a target="_blank" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70037743','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70037743">Hurricane disturbance and recovery of energy balance, CO2 fluxes and canopy structure in a mangrove forest of the Florida Everglades</a> <a target="_blank" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Barr, Jordan G.; Engel, Vic; Smith, Thomas J.; Fuentes, Jose D. 2012-01-01 Eddy covariance (EC) estimates of carbon dioxide (CO2) fluxes and energy balance are examined to investigate the functional responses of a mature mangrove forest to a disturbance generated by Hurricane Wilma on October 24, 2005 in the Florida Everglades. At the EC site, high winds from the hurricane caused nearly 100% defoliation in the upper canopy and widespread tree mortality. Soil temperatures down to -50 cm increased, and air temperature lapse rates within the forest canopy switched from statically stable to statically unstable conditions following the disturbance. Unstable conditions allowed more efficient transport of water vapor and CO2 from the surface up to the upper canopy layer. Significant increases in latent heat fluxes (LE) and nighttime net ecosystem exchange (NEE) were also observed and sensible heat fluxes (H) as a proportion of net radiation decreased significantly in response to the disturbance. Many of these impacts persisted through much of the study period through 2009. However, local albedo and MODIS (Moderate Resolution Imaging Spectro-radiometer) data (the Enhanced Vegetation Index) indicated a substantial proportion of active leaf area recovered before the EC measurements began 1 year after the storm. Observed changes in the vertical distribution and the degree of clumping in newly emerged leaves may have affected the energy balance. Direct comparisons of daytime NEE values from before the storm and after our measurements resumed did not show substantial or consistent differences that could be attributed to the disturbance. Regression analyses on seasonal time scales were required to differentiate the storm's impact on monthly average daytime NEE from the changes caused by interannual variability in other environmental drivers. The effects of the storm were apparent on annual time scales, and CO2 uptake remained approximately 250 g C m-2 yr-1 lower in 2009 compared to the average annual values measured in 2004–2005. Dry season CO2 </li> <li> <a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016EGUGA..18.7862S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016EGUGA..18.7862S">Tree species influence soil-atmosphere fluxes of the greenhouse gases CO2, CH4 and N2O</a> <a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Steffens, Christina; Vesterdal, Lars; Pfeiffer, Eva-Maria 2016-04-01 In the temperate zone, forests are the greatest terrestrial sink for atmospheric CO2, and tree species affect soil C stocks and soil CO2 emissions. When considering the total greenhouse gas (GHG) balance of the forest soil, the relevant GHGs CH4 and N2O should also be considered as they have a higher global warming potential than CO2. The presented data are first results from a field study in a common garden site in Denmark where tree species with ectomycorrhizal colonization (beech - Fagus sylvatica, oak - Quercus robur) and with arbuscular mycorrhizal colonization (maple - Acer pseudoplatanus, ash - Fraxinus excelsior) have been planted in monocultures in adjacent blocks of about 0.25 ha in the year 1973 on former arable land. The soil-atmosphere fluxes of all three gases were measured every second week since August 2015. The hypothesis is that the total GHG efflux from forest soil would differ between species, and that these differences could be related to the type of mycorrhizal association and leaf litter quality. Preliminary results (August to December 2015) indicate that tree species influence the fluxes (converted to CO2-eq) of the three GHGs. Total soil CO2 efflux was in the low end of the range reported for temperate broadleaved forests but similar to the measurements at the same site approximately ten years ago. It was highest under oak (9.6±2.4 g CO2 m-2 d-1) and lowest under maple (5.2±1.6 g CO2 m-2 d-1). In contrast, soil under oak was a small but significant sink for CH4(-0.005±0.003 g CO2-eq m-2 d-1), while there were almost no detectable CH4 fluxes in maple. Emissions of N2O were highest under beech (0.6±0.6 g CO2-eq m-2 d-1) and oak (0.2±0.09 g CO2-eq m-2 d-1) and lowest under ash (0.03±0.04 g CO2-eq m-2 d-1). In the total GHG balance, soil CH4 uptake was negligible (≤0.1% of total emissions). Emissions of N2O (converted to CO2-eq) contributed <1% (ash) to 8% (beech) to total GHG emissions. Summing up all GHG emissions, the tree species </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li><a href="#" onclick='return showDiv("page_23");'>23</a></li> <li><a href="#" onclick='return showDiv("page_24");'>24</a></li> <li class="active">25</li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div class="footer-extlink text-muted" style="margin-bottom:1rem; text-align:center;">Some links on this page may take you to non-federal websites. 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