Conductive heat exchange with a gel-coated circulating water mattress.

PubMed

Bräuer, Anselm; Pacholik, Larissa; Perl, Thorsten; English, Michael John Murray; Weyland, Wolfgang; Braun, Ulrich

2004-12-01

The use of forced-air warming is associated with costs for the disposable blankets. As an alternative method, we studied heat transfer with a reusable gel-coated circulating water mattress placed under the back in eight healthy volunteers. Heat flux was measured with six calibrated heat flux transducers. Additionally, mattress temperature, skin temperature, and core temperature were measured. Water temperature was set to 25 degrees C, 30 degrees C, 35 degrees C, and 41 degrees C. Heat transfer was calculated by multiplying heat flux by contact area. Mattress temperature, skin temperature, and heat flux were used to determine the heat exchange coefficient for conduction. Heat flux and water temperature were related by the following equation: heat flux = 10.3 x water temperature - 374 (r(2) = 0.98). The heat exchange coefficient for conduction was 121 W . m(-2) . degrees C(-1). The maximal heat transfer with the gel-coated circulating water mattress was 18.4 +/- 3.3 W. Because of the small effect on the heat balance of the body, a gel-coated circulating water mattress placed only on the back cannot replace a forced-air warming system.

Fluidized bed heat exchanger with water cooled air distributor and dust hopper

DOEpatents

Jukkola, Walfred W.; Leon, Albert M.; Van Dyk, Jr., Garritt C.; McCoy, Daniel E.; Fisher, Barry L.; Saiers, Timothy L.; Karstetter, Marlin E.

1981-11-24

A fluidized bed heat exchanger is provided in which air is passed through a bed of particulate material containing fuel. A steam-water natural circulation system is provided for heat exchange and the housing of the heat exchanger has a water-wall type construction. Vertical in-bed heat exchange tubes are provided and the air distributor is water-cooled. A water-cooled dust hopper is provided in the housing to collect particulates from the combustion gases and separate the combustion zone from a volume within said housing in which convection heat exchange tubes are provided to extract heat from the exiting combustion gases.

Observational analysis of air-sea fluxes and sea water temperature offshore South China Sea

NASA Astrophysics Data System (ADS)

Bi, X.; Huang, J.; Gao, Z.; Liu, Y.

2017-12-01

This paper investigates the air-sea fluxes (momentum flux, sensible heat flux and latent heat flux) from eddy covariance method based on data collected at an offshore observation tower in the South China Sea from January 2009 to December 2016 and sea water temperature (SWT) on six different levels based on data collected from November 2011 to June 2013. The depth of water at the tower over the sea averages about 15 m. This study presents the in-situ measurements of continuous air-sea fluxes and SWT at different depths. Seasonal and diurnal variations in air-sea fluxes and SWT on different depths are examined. Results show that air-sea fluxes and all SWT changed seasonally; sea-land breeze circulation appears all the year round. Unlike winters where SWT on different depths are fairly consistent, the difference between sea surface temperature (SST) and sea temperature at 10 m water depth fluctuates dramatically and the maximum value reaches 7 °C during summer.

Spatial Distribution and Air-Water Exchange of Organic Flame Retardants in the Lower Great Lakes.

PubMed

McDonough, Carrie A; Puggioni, Gavino; Helm, Paul A; Muir, Derek; Lohmann, Rainer

2016-09-06

Organic flame retardants (OFRs) such as polybrominated diphenyl ethers (PBDEs) and novel halogenated flame retardants (NHFRs) are ubiquitous, persistent, and bioaccumulative contaminants that have been used in consumer goods to slow combustion. In this study, polyethylene passive samplers (PEs) were deployed throughout the lower Great Lakes (Lake Erie and Lake Ontario) to measure OFRs in air and water, calculate air-water exchange fluxes, and investigate spatial trends. Dissolved Σ12BDE was greatest in Lake Ontario near Toronto (18 pg/L), whereas gaseous Σ12BDE was greatest on the southern shoreline of Lake Erie (11 pg/m(3)). NHFRs were generally below detection limits. Air-water exchange was dominated by absorption of BDEs 47 and 99, ranging from -964 pg/m(2)/day to -30 pg/m(2)/day. Σ12BDE in air and water was significantly correlated with surrounding population density, suggesting that phased-out PBDEs continued to be emitted from population centers along the Great Lakes shoreline in 2012. Correlation with dissolved Σ12BDE was strongest when considering population within 25 km while correlation with gaseous Σ12BDE was strongest when using population within 3 km to the south of each site. Bayesian kriging was used to predict dissolved Σ12BDE over the lakes, illustrating the utility of relatively highly spatially resolved measurements in identifying potential hot spots for future study.

A Water Balance Model for Hill reservoir - Aquifer Exchange Water Flux Quantification and Uncertainty Analysis - Application to the Kamech catchment, Tunisia

NASA Astrophysics Data System (ADS)

Bouteffeha, Maroua; Dagès, Cécile; Bouhlila, Rachida; Raclot, Damien; Molénat, Jérôme

2013-04-01

In Mediterranean regions, food and water demand increase with population growth leading to considerable changes of the land use and agricultural practices. In North Africa, particularly in the Mediterranean zones, hill reservoirs are water harvesting infrastructures that have been increasingly adopted to mobilize runoff and create alternative water resource that can be used to develop agriculture. Hill reservoirs are also used to prevent from silting of downstream dams. Management of water resources collected in these infrastructures requires a good knowledge of their hydrological functioning. In particular, the rate of water exchanges between the reservoir and the underlying aquifer, called surface-subsurface exchange hereafter, is still an open question. The main purpose of the study is to better know the hydrological functioning of hill reservoirs in quantifying at the annual and intra-annual time scales the flux of surface-subsurface exchange and the uncertainty associated to the flux. The approach is based on the hydrological water balance of the hill reservoir. It was applied to the hill reservoir of the 2.6 km² Kamech catchment (Tunisia), which belongs to the long term Mediterranean hydrological observatory OMERE (Voltz and Albergel, 2002). The dense monitoring of the observation catchment allowed quantifying the fluxes of all hydrological processes governing the reservoir hydrology, and their associated uncertainties. The water balance was established by considering water inputs (direct rainfall, waddy and hillslope runoff, surface-subsurface exchange), water outputs (evaporation, spillway discharge) and hill reservoir water volume changes. The surface-subsurface exchange component was deduced as the default closure term in the water balance. The results first demonstrate the ability of the proposed approach to estimate the net surface-subsurface exchange flux and its uncertainty at various time scales. Its application on the Kamech catchment for two

Quantifying Surface Water, Porewater, and Groundwater Interactions Using Tracers: Tracer Fluxes, Water Fluxes, and End-member Concentrations

NASA Astrophysics Data System (ADS)

Cook, Peter G.; Rodellas, Valentí; Stieglitz, Thomas C.

2018-03-01

Tracer approaches to estimate both porewater exchange (the cycling of water between surface water and sediments, with zero net water flux) and groundwater inflow (the net flow of terrestrially derived groundwater into surface water) are commonly based on solute mass balances. However, this requires appropriate characterization of tracer end-member concentrations in exchanging or discharging water. Where either porewater exchange or groundwater inflow to surface water occur in isolation, then the water flux is easily estimated from the net tracer flux if the end-member is appropriately chosen. However, in most natural systems porewater exchange and groundwater inflow will occur concurrently. Our analysis shows that if groundwater inflow (Qg) and porewater exchange (Qp) mix completely before discharging to surface water, then the combined water flux (Qg + Qp) can be approximated by dividing the combined tracer flux by the difference between the porewater and surface water concentrations, (cp - c). If Qg and Qp do not mix prior to discharge, then (Qg + Qp) can only be constrained by minimum and maximum values. The minimum value is obtained by dividing the net tracer flux by the groundwater concentration, and the maximum is obtained by dividing by (cp - c). Dividing by the groundwater concentration gives a maximum value for Qg. If porewater exchange and groundwater outflow occur concurrently, then dividing the net tracer flux by (cp - c) will provide a minimum value for Qp. Use of multiple tracers, and spatial and temporal replication should provide a more complete picture of exchange processes and the extent of subsurface mixing.

Turbulence and wave breaking effects on air-water gas exchange

PubMed

Boettcher; Fineberg; Lathrop

2000-08-28

We present an experimental characterization of the effects of turbulence and breaking gravity waves on air-water gas exchange in standing waves. We identify two regimes that govern aeration rates: turbulent transport when no wave breaking occurs and bubble dominated transport when wave breaking occurs. In both regimes, we correlate the qualitative changes in the aeration rate with corresponding changes in the wave dynamics. In the latter regime, the strongly enhanced aeration rate is correlated with measured acoustic emissions, indicating that bubble creation and dynamics dominate air-water exchange.

Wind driven vertical transport in a vegetated, wetland water column with air-water gas exchange

NASA Astrophysics Data System (ADS)

Poindexter, C.; Variano, E. A.

2010-12-01

gas transfer coefficient, k, for both a vegetated condition and a control condition (no cylinders). The presence of cylinders in the tank substantially increased the rate of the gas transfer. For the highest wind speed, the gas transfer coefficient was several times higher when cylinders were present compared to when they were not. The gas transfer coefficient for the vegetated condition also proved sensitive to wind speed, increasing markedly with increasing mean wind speeds. Profiles of dissolved oxygen revealed well-mixed conditions in the bulk water column following prolonged air-flow above the water surface, suggesting application of the thin-film model is appropriate. The enhanced gas exchange observed might be explained by increased turbulent kinetic energy within the water column and the anisotropy of the cylinder array, which constrains horizontal motions more than vertical motions. Improved understanding of gas exchange in vegetated water columns may be of particularly use to investigations of carbon fluxes and soil accretion in wetlands. Reference: Nepf, H. (1999), Drag, turbulence, and diffusion in flow through emergent vegetation, Water Resour. Res., 35(2), 479-489.

Why and how terrestrial plants exchange gases with air.

PubMed

Cieslik, S; Omasa, K; Paoletti, E

2009-11-01

This work is intended as a review of gas exchange processes between the atmosphere and the terrestrial vegetation, which have been known for more than two centuries since the discovery of photosynthesis. The physical and biological mechanisms of exchange of carbon dioxide, water vapour, volatile organic compounds emitted by plants and air pollutants taken up by them, is critically reviewed. The role of stomatal physiology is emphasised, as it controls most of these processes. The techniques used for measurement of gas exchange fluxes between the atmosphere and vegetation are outlined.

Coupling of phytoplankton uptake and air-water exchange of persistent organic pollutants

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dachs, J.; Eisenreich, S.J.; Baker, J.E.

1999-10-15

A dynamic model that couples air-water exchange and phytoplankton uptake of persistent organic pollutants has been developed and then applied to PCB data from a small experimental lake. A sensitivity analysis of the model, taking into account the influence of physical environmental conditions such as temperature, wind speed, and mixing depth as well as plankton-related parameters such as biomass and growth rate was carried out for a number of PCBs with different physical-chemical properties. The results indicate that air-water exchange dynamics are influenced not only by physical parameters but also by phytoplankton biomass and growth rate. New phytoplankton production resultsmore » in substantially longer times to reach equilibrium. Phytoplankton uptake-induced depletion of the dissolved phase concentration maintains air and water phases out of equilibrium. Furthermore, PCBs in phytoplankton also take longer times to reach equilibrium with the dissolved water phase when the latter is supported by diffusive air-water exchange. However, both model analysis and model application to the Experimental Lakes Area of northwestern Ontario (Canada) suggest that the gas phase supports the concentrations of persistent organic pollutants, such as PCBs, in atmospherically driven aquatic environments.« less

Effects of cold front passage on turbulent fluxes over a large inland water

NASA Astrophysics Data System (ADS)

Zhang, Q.; Liu, H.

2011-12-01

Turbulent fluxes of sensible and latent heat over a large inland water in southern USA were measured using the eddy covariance method through the year of 2008. In addition, net radiation, air temperatures and relative humidity, and water temperature in different depths were also measured. The specific objective of this study is to examine effects of a cold front passage on the surface energy fluxes. For the typical cold front event selected from April 11 to 14, air temperature decreased by 16°C, while surface temperature only dropped 6°C. Atmospheric vapor pressure decreased by 1.6 kPa, while that in the water-air interface dropped 0.7 kPa. The behavior difference in the water-air interface was caused by the passage of cold, dry air masses immediately behind the cold front. During the cold front event, sensible heat and latent heat flux increased by 171 W m-2 and 284 W m-2, respectively. Linear aggression analysis showed that the sensible heat flux was proportional to the product of wind speed and the temperature gradient of water-air interface, with a correlation coefficient of 0.95. Latent heat flux was proportional to the product of wind speed and vapor pressure difference between the water surface and overlaying atmosphere, with a correlation coefficient of 0.81. Also, the correlations between both fluxes and the wind speed were weak. This result indicated that the strong wind associated with the cold front event contributed to the turbulent mixing, which indirectly enhanced surface energy exchange between the water surface and the atmosphere. The relationship between the water heat storage energy and turbulent fluxes was also examined.

Variability of the gaseous elemental mercury sea-air flux of the Baltic Sea.

PubMed

Kuss, Joachim; Schneider, Bernd

2007-12-01

The importance of the sea as a sink for atmospheric mercury has been established quantitatively through models based on wet and dry deposition data, but little is known about the release of mercury from sea areas. The concentration of elemental mercury (Hg0) in sea surface water and in the marine atmosphere of the Baltic Sea was measured at high spatial resolution in February, April, July, and November 2006. Wind-speed records and the gas-exchange transfer velocity were then used to calculate Hg0 sea-air fluxes on the basis of Hg0 sea-air concentration differences. Our results show that the spatial resolution of the surface water Hg0 data can be significantly improved by continuous measurements of Hg0 in air equilibrated with water instead of quantitative extraction of Hg0 from seawater samples. A spatial and highly seasonal variability of the Hg0 sea-air flux was thus determined. In winter, the flux was low and changed in direction. In summer, a strong emission flux of up to 150 ng m(-2) day(-1) in the central Baltic Sea was recorded. The total emission of Hg0 from the studied area (235000 km2) was 4300 +/- 1600 kg in 2006 and exceeded deposition estimates.

Air-Seawater Exchange of Organochlorine Pesticides along the Sediment Plume of a Large Contaminated River.

PubMed

Lin, Tian; Guo, Zhigang; Li, Yuanyuan; Nizzetto, Luca; Ma, Chuanliang; Chen, Yingjun

2015-05-05

Gaseous exchange fluxes of organochlorine pesticides (OCPs) across the air-water interface of the coastal East China Sea were determined in order to assess whether the contaminated plume of the Yangtze River could be an important regional source of OCPs to the atmosphere. Hexachlorocyclohexanes (HCHs), chlordane compounds (CHLs), and dichlorodiphenyltrichloroethanes (DDTs) were the most frequently detected OCPs in air and water. Air-water exchange was mainly characterized by net volatilization for all measured OCPs. The net gaseous exchange flux ranged 10-240 ng/(m2·day) for γ-HCH, 60-370 ng/(m2·day) for trans-CHL, 97-410 ng/(m2·day) for cis-CHL, and ∼0 (e.g., equilibrium) to 490 ng/(m2·day) for p,p'-DDE. We found that the plume of the large contaminated river can serve as a significant regional secondary atmospheric source of legacy contaminants released in the catchment. In particular, the sediment plume represented the relevant source of DDT compounds (especially p,p'-DDE) sustaining net degassing when clean air masses from the open ocean reached the plume area. In contrast, a mass balance showed that, for HCHs, contaminated river discharge (water and sediment) plumes were capable of sustaining volatilization throughout the year. These results demonstrate the inconsistencies in the fate of HCHs and DDTs in this large estuarine system with declining primary sources.

Air-Water Exchange of Legacy and Emerging Organic Pollutants across the Great Lakes

NASA Astrophysics Data System (ADS)

Lohmann, R.; Ruge, Z.; Khairy, M.; Muir, D.; Helm, P.

2014-12-01

Organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) are transported to great water bodies via long-range atmospheric transport and released from the surface water as air concentrations continue to diminish. As the largest fresh water bodies in North America, the Great Lakes have both the potential to accumulate and serve as a secondary source of persistent bioaccumulative toxins. OCP and PCB concentrations were sampled at 30+ sites across Lake Superior, Ontario and Erie in the summer of 2011. Polyethylene passive samplers (PEs) were simultaneously deployed in surface water and near surface atmosphere to determine air-water gaseous exchange of OCPs and PCBs. In Lake Superior, surface water and atmospheric concentrations were dominated by α-HCH (average 250 pg/L and 4.2 pg/m3, respectively), followed by HCB (average 17 pg/L and 89 pg/m3, respectively). Air-water exchange varied greatly between sites and individual OCPs, however α-endosulfan was consistently deposited into the surface water (average 19 pg/m2/day). PCBs in the air and water were characterized by penta- and hexachlorobiphenyls with distribution along the coast correlated with proximity to developed areas. Air-water exchange gradients generally yielded net volatilization of PCBs out of Lake Superior. Gaseous concentrations of hexachlorobenzene, dieldrin and chlordanes were significantly higher (p < 0.05) at Lake Erie than Lake Ontario. A multiple linear regression that incorporated meteorological, landuse and population data was used to explain variability in the atmospheric concentrations. Results indicated that landuse (urban and/or cropland) greatly explained the variability in the data. Freely dissolved concentrations of OCPs (water quality guidelines for the protection of human health from the consumption of fish. Spatial distributions of

Atmospheric partitioning and the air-water exchange of polycyclic aromatic hydrocarbons in a large shallow Chinese lake (Lake Chaohu).

PubMed

Qin, Ning; He, Wei; Kong, Xiang-Zhen; Liu, Wen-Xiu; He, Qi-Shuang; Yang, Bin; Ouyang, Hui-Ling; Wang, Qing-Mei; Xu, Fu-Liu

2013-11-01

The residual levels of polycyclic aromatic hydrocarbons (PAHs) in the atmosphere and in dissolved phase from Lake Chaohu were measured by (GC-MS). The composition and seasonal variation were investigated. The diffusive air-water exchange flux was estimated by a two-film model, and the uncertainty in the flux calculations and the sensitivity of the parameters were evaluated. The following results were obtained: (1) the average residual levels of all PAHs (PAH16) in the atmosphere from Lake Chaohu were 60.85±46.17 ng m(-3) in the gaseous phase and 14.32±23.82 ng m(-3) in the particulate phase. The dissolved PAH16 level was 173.46±132.89 ng L(-1). (2) The seasonal variation of average PAH16 contents ranged from 43.09±33.20 ng m(-3) (summer) to 137.47±41.69 ng m(-3) (winter) in gaseous phase, from 6.62±2.72 ng m(-3) (summer) to 56.13±22.99 ng m(-3) (winter) in particulate phase, and 142.68±74.68 ng L(-1) (winter) to 360.00±176.60 ng L(-1) (summer) in water samples. Obvious seasonal trends of PAH16 concentrations were found in the atmosphere and water. The values of PAH16 for both the atmosphere and the water were significantly correlated with temperature. (3) The monthly diffusive air-water exchange flux of total PAH16 ranged from -1.77×10(4) ng m(-2) d(-1) to 1.11×10(5) ng m(-2) d(-1), with an average value of 3.45×10(4) ng m(-2) d(-1). (4) The results of a Monte Carlo simulation showed that the monthly average PAH fluxes ranged from -3.4×10(3) ng m(-2) d(-1) to 1.6×10(4) ng m(-2) d(-1) throughout the year, and the uncertainties for individual PAHs were compared. (5) According to the sensitivity analysis, the concentrations of dissolved and gaseous phase PAHs were the two most important factors affecting the results of the flux calculations. Copyright © 2013 Elsevier Ltd. All rights reserved.

Air-water exchange of PAHs and OPAHs at a superfund mega-site.

PubMed

Tidwell, Lane G; Blair Paulik, L; Anderson, Kim A

2017-12-15

Chemical fate is a concern at environmentally contaminated sites, but characterizing that fate can be difficult. Identifying and quantifying the movement of chemicals at the air-water interface are important steps in characterizing chemical fate. Superfund sites are often suspected sources of air pollution due to legacy sediment and water contamination. A quantitative assessment of polycyclic aromatic hydrocarbons (PAHs) and oxygenated PAH (OPAHs) diffusive flux in a river system that contains a Superfund Mega-site, and passes through residential, urban and agricultural land, has not been reported before. Here, passive sampling devices (PSDs) were used to measure 60 polycyclic aromatic hydrocarbons (PAHs) and 22 oxygenated PAH (OPAHs) in air and water. From these concentrations the magnitude and direction of contaminant flux between these two compartments was calculated. The magnitude of PAH flux was greater at sites near or within the Superfund Mega-site than outside of the Superfund Mega-site. The largest net individual PAH deposition at a single site was naphthalene at a rate of -14,200 (±5780) (ng/m 2 )/day. The estimated one-year total flux of phenanthrene was -7.9×10 5 (ng/m 2 )/year. Human health risk associated with inhalation of vapor phase PAHs and dermal exposure to PAHs in water were assessed by calculating benzo[a]pyrene equivalent concentrations. Excess lifetime cancer risk estimates show potential increased risk associated with exposure to PAHs at sites within and in close proximity to the Superfund Mega-site. Specifically, estimated excess lifetime cancer risk associated with dermal exposure and inhalation of PAHs was above 1 in 1 million within the Superfund Mega-site. The predominant depositional flux profile observed in this study suggests that the river water in this Superfund site is largely a sink for airborne PAHs, rather than a source. Copyright © 2017 Elsevier B.V. All rights reserved.

A CRITICAL ASSESSMENT OF ELEMENTAL MERCURY AIR/WATER EXCHANGE PARTNERS

EPA Science Inventory

Although evasion of elemental mercury from aquatic systems can significantly deplete net mercury accumulation resulting from atmospheric deposition, the current ability to model elemental mercury air/water exchange is limited by uncertainties in our understanding of all gaseous a...

THE EFFECT OF SALINITY ON RATES OF ELEMENTAL MERCURY AIR/WATER EXCHANGE

EPA Science Inventory

The U.S. EPA laboratory in Athens, Georgia i spursuing the goal of developing a model for describing toxicant vapor phase air/water exchange under all relevant environmental conditions. To date, the two-layer exchange model (suitable for low wind speed conditions) has been modif...

Nitrous oxide and methane in Atlantic and Mediterranean waters in the Strait of Gibraltar: Air-sea fluxes and inter-basin exchange

NASA Astrophysics Data System (ADS)

de la Paz, M.; Huertas, I. E.; Flecha, S.; Ríos, A. F.; Pérez, F. F.

2015-11-01

The global ocean plays an important role in the overall budget of nitrous oxide (N2O) and methane (CH4), as both gases are produced within the ocean and released to the atmosphere. However, for large parts of the open and coastal oceans there is little or no spatial data coverage for N2O and CH4. Hence, a better assessment of marine emissions estimates is necessary. As a contribution to remedying the scarcity of data on marine regions, N2O and CH4 concentrations have been determined in the Strait of Gibraltar at the ocean Fixed Time series (GIFT). During six cruises performed between July 2011 and November 2014 samples were collected at the surface and various depths in the water column, and subsequently measured using gas chromatography. From this we were able to quantify the temporal variability of the gas air-sea exchange in the area and examine the vertical distribution of N2O and CH4 in Atlantic and Mediterranean waters. Results show that surface Atlantic waters are nearly in equilibrium with the atmosphere whereas deeper Mediterranean waters are oversaturated in N2O, and a gradient that gradually increases with depth was detected in the water column. Temperature was found to be the main factor responsible for the seasonal variability of N2O in the surface layer. Furthermore, although CH4 levels did not reveal any feature clearly associated with the circulation of water masses, vertical distributions showed that higher concentrations are generally observed in the Atlantic layer, and that the deeper Mediterranean waters are considerably undersaturated (by up to 50%). Even though surface waters act as a source of atmospheric N2O during certain periods, on an annual basis the net N2O flux in the Strait of Gibraltar is only 0.35 ± 0.27 μmol m-2 d-1, meaning that these waters are almost in a neutral status with respect to the atmosphere. Seasonally, the region behaves as a slight sink for atmospheric CH4 in winter and as a source in spring and fall. Approximating

Polycyclic aromatic hydrocarbon (PAH) and oxygenated PAH (OPAH) air-water exchange during the deepwater horizon oil spill.

PubMed

Tidwell, Lane G; Allan, Sarah E; O'Connell, Steven G; Hobbie, Kevin A; Smith, Brian W; Anderson, Kim A

2015-01-06

Passive sampling devices were used to measure air vapor and water dissolved phase concentrations of 33 polycyclic aromatic hydrocarbons (PAHs) and 22 oxygenated PAHs (OPAHs) at four Gulf of Mexico coastal sites prior to, during, and after shoreline oiling from the Deepwater Horizon oil spill (DWH). Measurements were taken at each site over a 13 month period, and flux across the water-air boundary was determined. This is the first report of vapor phase and flux of both PAHs and OPAHs during the DWH. Vapor phase sum PAH and OPAH concentrations ranged between 1 and 24 ng/m(3) and 0.3 and 27 ng/m(3), respectively. PAH and OPAH concentrations in air exhibited different spatial and temporal trends than in water, and air-water flux of 13 individual PAHs were strongly associated with the DWH incident. The largest PAH volatilizations occurred at the sites in Alabama and Mississippi in the summer, each nominally 10,000 ng/m(2)/day. Acenaphthene was the PAH with the highest observed volatilization rate of 6800 ng/m(2)/day in September 2010. This work represents additional evidence of the DWH incident contributing to air contamination, and provides one of the first quantitative air-water chemical flux determinations with passive sampling technology.

Air--sea gaseous exchange of PCB at the Venice lagoon (Italy).

PubMed

Manodori, L; Gambaro, A; Moret, I; Capodaglio, G; Cescon, P

2007-10-01

Water bodies are important storage media for persistent organic pollutants (POPs) such as polychlorinated biphenyls (PCBs) and this function is increased in coastal regions because their inputs are higher than those to the open sea. The air-water interface is extensively involved with the global cycling of PCBs because it is the place where they accumulate due to depositional processes and where they may be emitted by gaseous exchange. In this work the parallel collection of air, microlayer and sub-superficial water samples was performed in July 2005 at a site in the Venice lagoon to evaluate the summer gaseous flux of PCBs. The total concentration of PCBs (sum of 118 congeners) in air varies from 87 to 273 pg m(-3), whereas in the operationally defined dissolved phase of microlayer and sub-superficial water samples it varies from 159 to 391 pg L(-1). No significant enrichment of dissolved PCB into the microlayer has been observed, although a preferential accumulation of most hydrophobic congeners occurs. Due to this behaviour, we believe that the modified two-layer model was the most suitable approach for the evaluation of the flux at the air-sea interface, because it takes into account the influence of the microlayer. From its application it appears that PCB volatilize from the lagoon waters with a net flux varying from 58 to 195 ng m(-2)d(-1) (uncertainty: +/-50-64%) due to the strong influence of wind speed. This flux is greater than those reported in the literature for the atmospheric deposition and rivers input and reveals that PCB are actively emitted from the Venice lagoon in summer months.

ISSUES IN SIMULATING ELEMENTAL MERCURY AIR/WATER EXCHANGE AND AQUEOUS MONOMETHYLMERCURY SPECIATION

EPA Science Inventory

This presentation focuses on two areas relevant to assessing the global fate and bioavailability of mercury: elemental mercury air/water exchange and aqueous environmental monomethylmercury speciation.

[Characteristics of mercury exchange flux between soil and atmosphere under the snow retention and snow melting control].

PubMed

Zhang, Gang; Wang, Ning; Ai, Jian-Chao; Zhang, Lei; Yang, Jing; Liu, Zi-Qi

2013-02-01

Jiapigou gold mine, located in the upper Songhua River, was once the largest mine in China due to gold output, where gold extraction with algamation was widely applied to extract gold resulting in severe mercury pollution to ambient environmental medium. In order to study the characteristics of mercury exchange flux between soil (snow) and atmosphere under the snow retention and snow melting control, sampling sites were selected in equal distances along the slope which is situated in the typical hill-valley terrain unit. Mercury exchange flux between soil (snow) and atmosphere was determined with the method of dynamic flux chamber and in all sampling sites the atmosphere concentration from 0 to 150 cm near to the earth in the vertical direction was measured. Furthermore, the impact factors including synchronous meteorology, the surface characteristics under the snow retention and snow melting control and the mercury concentration in vertical direction were also investigated. The results are as follows: During the period of snow retention and melting the air mercury tends to gather towards valley bottom along the slope and an obvious deposit tendency process was found from air to the earth's surface under the control of thermal inversion due to the underlying surface of cold source (snow surface). However, during the period of snow melting, mercury exchange flux between the soil and atmosphere on the surface of the earth with the snow being melted demonstrates alternative deposit and release processes. As for the earth with snow covered, the deposit level of mercury exchange flux between soil and atmosphere is lower than that during the period of snow retention. The relationship between mercury exchange flux and impact factors shows that in snow retention there is a remarkable negative linear correlation between mercury exchange flux and air mercury concentration as well as between the former and the air temperature. In addition, in snow melting mercury exchange

Atmospheric concentrations and air-sea exchanges of nonylphenol, tertiary octylphenol and nonylphenol monoethoxylate in the North Sea.

PubMed

Xie, Zhiyong; Lakaschus, Soenke; Ebinghaus, Ralf; Caba, Armando; Ruck, Wolfgang

2006-07-01

Concentrations of nonylphenol isomers (NP), tertiary octylphenol (t-OP) and nonylphenol monoethoxylate isomers (NP1EO) have been simultaneously determined in the sea water and atmosphere of the North Sea. A decreasing concentration profile appeared following the distance increasing from the coast to the central part of the North Sea. Air-sea exchanges of t-OP and NP were estimated using the two-film resistance model based upon relative air-water concentrations and experimentally derived Henry's law constant. The average of air-sea exchange fluxes was -12+/-6 ng m(-2)day(-1) for t-OP and -39+/-19 ng m(-2)day(-1) for NP, which indicates a net deposition is occurring. These results suggest that the air-sea vapour exchange is an important process that intervenes in the mass balance of alkylphenols in the North Sea.

20 Years of Air-Water Gas Exchange Observations for Pesticides in the Western Arctic Ocean.

PubMed

Jantunen, Liisa M; Wong, Fiona; Gawor, Anya; Kylin, Henrik; Helm, Paul A; Stern, Gary A; Strachan, William M J; Burniston, Deborah A; Bidleman, Terry F

2015-12-01

The Arctic has been contaminated by legacy organochlorine pesticides (OCPs) and currently used pesticides (CUPs) through atmospheric transport and oceanic currents. Here we report the time trends and air-water exchange of OCPs and CUPs from research expeditions conducted between 1993 and 2013. Compounds determined in both air and water were trans- and cis-chlordanes (TC, CC), trans- and cis-nonachlors (TN, CN), heptachlor exo-epoxide (HEPX), dieldrin (DIEL), chlorobornanes (ΣCHBs and toxaphene), dacthal (DAC), endosulfans and metabolite endosulfan sulfate (ENDO-I, ENDO-II, and ENDO SUL), chlorothalonil (CHT), chlorpyrifos (CPF), and trifluralin (TFN). Pentachloronitrobenzene (PCNB and quintozene) and its soil metabolite pentachlorothianisole (PCTA) were also found in air. Concentrations of most OCPs declined in surface water, whereas some CUPs increased (ENDO-I, CHT, and TFN) or showed no significant change (CPF and DAC), and most compounds declined in air. Chlordane compound fractions TC/(TC + CC) and TC/(TC + CC + TN) decreased in water and air, while CC/(TC + CC + TN) increased. TN/(TC + CC + TN) also increased in air and slightly, but not significantly, in water. These changes suggest selective removal of more labile TC and/or a shift in chlordane sources. Water-air fugacity ratios indicated net volatilization (FR > 1.0) or near equilibrium (FR not significantly different from 1.0) for most OCPs but net deposition (FR < 1.0) for ΣCHBs. Net deposition was shown for ENDO-I on all expeditions, while the net exchange direction of other CUPs varied. Understanding the processes and current state of air-surface exchange helps to interpret environmental exposure and evaluate the effectiveness of international protocols and provides insights for the environmental fate of new and emerging chemicals.

Surfactant control of air-sea gas exchange across contrasting biogeochemical regimes

NASA Astrophysics Data System (ADS)

Pereira, Ryan; Schneider-Zapp, Klaus; Upstill-Goddard, Robert

2014-05-01

Air-sea gas exchange is important to the global partitioning of CO2.Exchange fluxes are products of an air-sea gas concentration difference, ΔC, and a gas transfer velocity, kw. The latter is controlled by the rate of turbulent diffusion at the air-sea interface but it cannot be directly measured and has a high uncertainty that is now considered one of the greatest challenges to quantifying net global air-sea CO2 exchange ...(Takahashi et al., 2009). One important control on kw is exerted by sea surface surfactants that arise both naturally from biological processes and through anthropogenic activity. They influence gas exchange in two fundamental ways: as a monolayer physical barrier and through modifying sea surface hydrodynamics and hence turbulent energy transfer. These effects have been demonstrated in the laboratory with artificial surfactants ...(Bock et al., 1999; Goldman et al., 1988) and through purposeful surfactant releases in coastal waters .(.).........().(Brockmann et al., 1982) and in the open ocean (Salter et al., 2011). Suppression of kwin these field experiments was ~5-55%. While changes in both total surfactant concentration and the composition of the natural surfactant pool might be expected to impact kw, the required in-situ studies are lacking. New data collected from the coastal North Sea in 2012-2013 shows significant spatio-temporal variability in the surfactant activity of organic matter within the sea surface microlayer that ranges from 0.07-0.94 mg/L T-X-100 (AC voltammetry). The surfactant activities show a strong winter/summer seasonal bias and general decrease in concentration with increasing distance from the coastline possibly associated with changing terrestrial vs. phytoplankton sources. Gas exchange experiments of this seawater using a novel laboratory tank and gas tracers (CH4 and SF6) demonstrate a 12-45% reduction in kw compared to surfactant-free water. Seasonally there is higher gas exchange suppression in the summer

Turbulent water vapor exchanges and two source energy balance model estimated fluxes of heterogeneous vineyard canopies

NASA Astrophysics Data System (ADS)

Los, S.; Hipps, L.; Alfieri, J. G.; Prueger, J. H.; Kustas, W. P.

2017-12-01

Agriculture in semi-arid regions is globally facing increasing stress on water resources. Hence, knowledge of water used in irrigated crops is essential for water resource management. However, quantifying spatial and temporal distribution of evapotranspiration (ET) has proven difficult because of the inherent complexities involved. Understanding of the complex biophysical relationships that govern ET is incomplete, particularly for heterogeneous vegetation. The USDA-ARS is developing a remotely-sensed ET modeling system that utilizes a two-source energy balance (TSEB) model capable of simulating turbulent water and energy exchange from measurements of radiometric land surface temperature. The modeling system has been tested over a number of vegetated surfaces and is currently being validated for vineyard sites in the Central Valley of California through the Grape Remote sensing Atmospheric Profiling & Evapotranspiration eXperiment (GRAPEX). The highly variable, elevated canopy structure and semi-arid climatic conditions of these sites give the opportunity to gain knowledge of both turbulent exchange processes and the TSEB model's ability to simulate turbulent fluxes for heterogeneous vegetation. Analyzed are fast-response (20 Hz) 3-D velocity, temperature, and humidity measurements gathered over 4 years at two vineyard sites. These data were collected at a height of 5 m, within the surface layer but above the canopy, and at 1.5 m, below the canopy top. Power spectra and cross-spectra are used to study behavior of turbulent water vapor exchanges and coupling between the canopy layer and surface layer under various atmospheric conditions. Frequent light winds and unstable daytime conditions, combined with the complicated canopy structure, often induce intermittent and episodic turbulence transport. This resulted in a modal behavior alternating between periods of more continuous canopy venting and periods where water vapor fluxes are dominated by transient, low

Using Riverboat-Mounted Eddy Covariance for Direct Measurements of Air-water Gas Exchange in Amazonia

NASA Astrophysics Data System (ADS)

Miller, S. D.; Freitas, H.; Read, E.; Goulden, M. L.; Rocha, H.

2007-12-01

Gas evasion from Amazonian rivers and lakes to the atmosphere has been estimated to play an important role in the regional budget of carbon dioxide (Richey et al., 2002) and the global budget of methane (Melack et al., 2004). These flux estimates were calculated by combining remote sensing estimates of inundation area with water-side concentration gradients and gas transfer rates (piston velocities) estimated primarily from floating chamber measurements (footprint ~1 m2). The uncertainty in these fluxes was large, attributed primarily to uncertainty in the gas exchange parameterization. Direct measurements of the gas exchange coefficient are needed to improve the parameterizations in these environments, and therefore reduce the uncertainty in fluxes. The micrometeorological technique of eddy covariance is attractive since it is a direct measurement of gas exchange that samples over a much larger area than floating chambers, and is amenable to use from a moving platform. We present eddy covariance carbon dioxide exchange measurements made using a small riverboat in rivers and lakes in the central Amazon near Santarem, Para, Brazil. Water-side carbon dioxide concentration was measured in situ, and the gas exchange coefficient was calculated. We found the piston velocity at a site on the Amazon River to be similar to existing ocean-based parameterizations, whereas the piston velocity at a site on the Tapajos River was roughly a factor 5 higher. We hypothesize that the enhanced gas exchange at the Tapajos site was due to a shallow upwind fetch. Our results demonstrate the feasibility of boat-based eddy covariance on these rivers, and also the utility of a mobile platform to investigate spatial variability of gas exchange.

Air-water CO2 Fluxes In Seasonal Hypoxia-influenced Green Bay, Lake Michigan

NASA Astrophysics Data System (ADS)

Lin, P.; Klump, J. V.; Guo, L.

2016-02-01

Increasing anthropogenic nutrient enrichment has led to seasonal hypoxia in Green Bay, the largest freshwater estuary in the Laurentian Great Lakes, but change in carbon dynamics associated with the development of hypoxia remains poorly understood. Variations in alkalinity, abundance of carbon species, and air-water CO2 fluxes were quantified under contrasting hypoxic conditions during summer 2014. Green Bay was characterized with high pH (average 8.62 ± 0.16 in August), high DIC concentrations (2113 - 3213 µmol/kg) and high pCO2 in the water column. pCO2 was mostly >700 µatm in June, resulting in a net CO2 source to the air, while pCO2 was mostly <650 µatm in August when hypoxic conditions occurred in Green Bay. In central Green Bay, pCO2 was the highest during both sampling months, accompanying by low dissolved oxygen (DO) and lower pH in the water column. In August, pCO2 was inversely correlated with DOC concentration and increased with DOC/DOP ratio, suggesting a control by organic matter on air-water CO2 dynamics and consumption of DO in Green Bay. Positive CO2 fluxes to the atmosphere during August were only observed in northern bay but a CO2 sink was found in southern Green Bay ( 40% of study area) with high biological production and terrestrial DOM. Daily CO2 flux ranged from 10.9 to 48.5 mmol-C m-2 d-1 in June with an average of 18.29 ± 7.44 mmol-C m-2 d-1, whereas it varied from 1.82 ± 1.18 mmol m-2 d-1 in the north to -2.05 ± 1.89 mmol m-2 d-1 in the south of Green Bay in August. Even though strong biological production reduced the CO2 emission, daily CO2 fluxes from Green Bay to the air were as high as 7.4 × 107 mole-C in June and 4.6 × 106 mole-C in August, suggesting a significant role of high-DIC lakes in global CO2 budget and cycling.

Temporal variability of air-sea CO2 exchange in a low-emission estuary

NASA Astrophysics Data System (ADS)

Mørk, Eva Thorborg; Sejr, Mikael Kristian; Stæhr, Peter Anton; Sørensen, Lise Lotte

2016-07-01

There is the need for further study of whether global estimates of air-sea CO2 exchange in estuarine systems capture the relevant temporal variability and, as such, the temporal variability of bulk parameterized and directly measured CO2 fluxes was investigated in the Danish estuary, Roskilde Fjord. The air-sea CO2 fluxes showed large temporal variability across seasons and between days and that more than 30% of the net CO2 emission in 2013 was a result of two large fall and winter storms. The diurnal variability of ΔpCO2 was up to 400 during summer changing the estuary from a source to a sink of CO2 within the day. Across seasons the system was suggested to change from a sink of atmospheric CO2 during spring to near neutral during summer and later to a source of atmospheric CO2 during fall. Results indicated that Roskilde Fjord was an annual low-emission estuary, with an estimated bulk parameterized release of 3.9 ± 8.7 mol CO2 m-2 y-1 during 2012-2013. It was suggested that the production-respiration balance leading to the low annual emission in Roskilde Fjord, was caused by the shallow depth, long residence time and high water quality in the estuary. In the data analysis the eddy covariance CO2 flux samples were filtered according to the H2Osbnd CO2 cross-sensitivity assessment suggested by Landwehr et al. (2014). This filtering reduced episodes of contradicting directions between measured and bulk parameterized air-sea CO2 exchanges and changed the net air-sea CO2 exchange from an uptake to a release. The CO2 gas transfer velocity was calculated from directly measured CO2 fluxes and ΔpCO2 and agreed to previous observations and parameterizations.

A flux-gradient system for simultaneous measurement of the CH4, CO2, and H2O fluxes at a lake-air interface.

PubMed

Xiao, Wei; Liu, Shoudong; Li, Hanchao; Xiao, Qitao; Wang, Wei; Hu, Zhenghua; Hu, Cheng; Gao, Yunqiu; Shen, Jing; Zhao, Xiaoyan; Zhang, Mi; Lee, Xuhui

2014-12-16

Inland lakes play important roles in water and greenhouse gas cycling in the environment. This study aims to test the performance of a flux-gradient system for simultaneous measurement of the fluxes of water vapor, CO2, and CH4 at a lake-air interface. The concentration gradients over the water surface were measured with an analyzer based on the wavelength-scanned cavity ring-down spectroscopy technology, and the eddy diffusivity was measured with a sonic anemometer. Results of a zero-gradient test indicate a flux measurement precision of 4.8 W m(-2) for water vapor, 0.010 mg m(-2) s(-1) for CO2, and 0.029 μg m(-2) s(-1) for CH4. During the 620 day measurement period, 97%, 69%, and 67% of H2O, CO2, and CH4 hourly fluxes were higher in magnitude than the measurement precision, which confirms that the flux-gradient system had adequate precision for the measurement of the lake-air exchanges. This study illustrates four strengths of the flux-gradient method: (1) the ability to simultaneously measure the flux of H2O, CO2, and CH4; (2) negligibly small density corrections; (3) the ability to resolve small CH4 gradient and flux; and (4) continuous and noninvasive operation. The annual mean CH4 flux (1.8 g CH4 m(-2) year(-1)) at this hypereutrophic lake was close to the median value for inland lakes in the world (1.6 g CH4 m(-2) year(-1)). The system has adequate precision for CH4 flux for broad applications but requires further improvement to resolve small CO2 flux in many lakes.

Impacts of Soil-aquifer Heat and Water Fluxes on Simulated Global Climate

NASA Technical Reports Server (NTRS)

Krakauer, N.Y.; Puma, Michael J.; Cook, B. I.

2013-01-01

Climate models have traditionally only represented heat and water fluxes within relatively shallow soil layers, but there is increasing interest in the possible role of heat and water exchanges with the deeper subsurface. Here, we integrate an idealized 50m deep aquifer into the land surface module of the GISS ModelE general circulation model to test the influence of aquifer-soil moisture and heat exchanges on climate variables. We evaluate the impact on the modeled climate of aquifer-soil heat and water fluxes separately, as well as in combination. The addition of the aquifer to ModelE has limited impact on annual-mean climate, with little change in global mean land temperature, precipitation, or evaporation. The seasonal amplitude of deep soil temperature is strongly damped by the soil-aquifer heat flux. This not only improves the model representation of permafrost area but propagates to the surface, resulting in an increase in the seasonal amplitude of surface air temperature of >1K in the Arctic. The soil-aquifer water and heat fluxes both slightly decrease interannual variability in soil moisture and in landsurface temperature, and decrease the soil moisture memory of the land surface on seasonal to annual timescales. The results of this experiment suggest that deepening the modeled land surface, compared to modeling only a shallower soil column with a no-flux bottom boundary condition, has limited impact on mean climate but does affect seasonality and interannual persistence.

Advances in quantifying air-sea gas exchange and environmental forcing.

PubMed

Wanninkhof, Rik; Asher, William E; Ho, David T; Sweeney, Colm; McGillis, Wade R

2009-01-01

The past decade has seen a substantial amount of research on air-sea gas exchange and its environmental controls. These studies have significantly advanced the understanding of processes that control gas transfer, led to higher quality field measurements, and improved estimates of the flux of climate-relevant gases between the ocean and atmosphere. This review discusses the fundamental principles of air-sea gas transfer and recent developments in gas transfer theory, parameterizations, and measurement techniques in the context of the exchange of carbon dioxide. However, much of this discussion is applicable to any sparingly soluble, non-reactive gas. We show how the use of global variables of environmental forcing that have recently become available and gas exchange relationships that incorporate the main forcing factors will lead to improved estimates of global and regional air-sea gas fluxes based on better fundamental physical, chemical, and biological foundations.

[Comparison of air/soil mercury exchange between warm and cold season in Hongfeng Reservoir region].

PubMed

Wang, Shao-feng; Feng, Xin-bin; Qiu, Guang-le; Fu, Xue-wu

2004-01-01

In July 2002 and March 2003, the mercury exchange flux between soil and air was measured using dynamic flux chamber method in Hongfeng Reservoir region. Mercury exchange flux is (27.4 +/- 40.1) ng x (m2 x h)(-1) (n = 255) and (5.6 +/- 19.4) ng x (m2 x h)(-1) (n = 192) in summer and winter respectively. The correlation coefficient between mercury flux and solar radiation, air temperature, soil temperature is 0.74, 0.83 and 0.80 in summer, and 0.88, 0.56 and 0.59 in winter. From the data, it was found that the mercury emission is stronger in summer than that in winter, and compared to winter, mercury exchange between soil and air depends more on meteorological conditions in summer.

THE ROLE OF AQUEOUS THIN FILM EVAPORATIVE COOLING ON RATES OF ELEMENTAL MERCURY AIR-WATER EXCHANGE UNDER TEMPERATURE DISEQUILIBRIUM CONDITIONS

EPA Science Inventory

The technical conununity has only recently addressed the role of atmospheric temperature variations on rates of air-water vapor phase toxicant exchange. The technical literature has documented that: 1) day time rates of elemental mercury vapor phase air-water exchange can exceed ...

Diffusive flux of PAHs across sediment-water and water-air interfaces at urban superfund sites.

PubMed

Minick, D James; Anderson, Kim A

2017-09-01

Superfund sites may be a source of polycyclic aromatic hydrocarbons (PAHs) to the surrounding environment. These sites can also act as PAH sinks from present-day anthropogenic activities, especially in urban locations. Understanding PAH transport across environmental compartments helps to define the relative contributions of these sources and is therefore important for informing remedial and management decisions. In the present study, paired passive samplers were co-deployed at sediment-water and water-air interfaces within the Portland Harbor Superfund Site and the McCormick and Baxter Superfund Site. These sites, located along the Willamette River (Portland, OR, USA), have PAH contamination from both legacy and modern sources. Diffusive flux calculations indicate that the Willamette River acts predominantly as a sink for low molecular weight PAHs from both the sediment and the air. The sediment was also predominantly a source of 4- and 5-ring PAHs to the river, and the river was a source of these same PAHs to the air, indicating that legacy pollution may be contributing to PAH exposure for residents of the Portland urban center. At the remediated McCormick and Baxter Superfund Site, flux measurements highlight locations within the sand and rock sediment cap where contaminant breakthrough is occurring. Environ Toxicol Chem 2017;36:2281-2289. © 2017 SETAC. © 2017 SETAC.

Observational Studies of Parameters Influencing Air-sea Gas Exchange

NASA Astrophysics Data System (ADS)

Schimpf, U.; Frew, N. M.; Bock, E. J.; Hara, T.; Garbe, C. S.; Jaehne, B.

A physically-based modeling of the air-sea gas transfer that can be used to predict the gas transfer rates with sufficient accuracy as a function of micrometeorological parameters is still lacking. State of the art are still simple gas transfer rate/wind speed relationships. Previous measurements from Coastal Ocean Experiment in the Atlantic revealed positive correlations between mean square slope, near surface turbulent dis- sipation, and wind stress. It also demonstrated a strong negative correlation between mean square slope and the fluorescence of surface-enriched colored dissolved organic matter. Using heat as a proxy tracer for gases the exchange process at the air/water interface and the micro turbulence at the water surface can be investigated. The anal- ysis of infrared image sequences allow the determination of the net heat flux at the ocean surface, the temperature gradient across the air/sea interface and thus the heat transfer velocity and gas transfer velocity respectively. Laboratory studies were carried out in the new Heidelberg wind-wave facility AELOTRON. Direct measurements of the Schmidt number exponent were done in conjunction with classical mass balance methods to estimate the transfer velocity. The laboratory results allowed to validate the basic assumptions of the so called controlled flux technique by applying differ- ent tracers for the gas exchange in a large Schmidt number regime. Thus a modeling of the Schmidt number exponent is able to fill the gap between laboratory and field measurements field. Both, the results from the laboratory and the field measurements should be able to give a further understanding of the mechanisms controlling the trans- port processes across the aqueous boundary layer and to relate the forcing functions to parameters measured by remote sensing.

Heat flux exchange estimation by using ATSR SST data in TOGA area

NASA Astrophysics Data System (ADS)

Xue, Yong; Lawrence, Sean P.; Llewellyn-Jones, David T.

1995-12-01

The study of phenomena such as ENSO requires consideration of the dynamics and thermodynamics of the coupled ocean-atmosphere system. The dynamic and thermal properties of the atmosphere and ocean are directly affected by air-sea transfers of fluxes of momentum, heat and moisture. In this paper, we present results of turbulent heat fluxes calculated by using two years (1992 and 1993) monthly average TOGA data and ATSR SST data in TOGA area. A comparison with published results indicates good qualitative agreement. Also, we compared the results of heat flux exchange by using ATSR SST data and by using the TOGA bucket SST data. The ATSR SST data set has been shown to be useful in helping to estimate the large space scale heat flux exchange.

Air-water Gas Exchange Rates on a Large Impounded River Measured Using Floating Domes (Poster)

EPA Science Inventory

Mass balance models of dissolved gases in rivers typically serve as the basis for whole-system estimates of greenhouse gas emission rates. An important component of these models is the exchange of dissolved gases between air and water. Controls on gas exchange rates (K) have be...

Determination of temperature dependent Henry's law constants of polychlorinated naphthalenes: Application to air-sea exchange in Izmir Bay, Turkey

NASA Astrophysics Data System (ADS)

Odabasi, Mustafa; Adali, Mutlu

2016-12-01

The Henry's law constant (H) is a crucial variable to investigate the air-water exchange of persistent organic pollutants. H values for 32 polychlorinated naphthalene (PCN) congeners were measured using an inert gas-stripping technique at five temperatures ranging between 5 and 35 °C. H values in deionized water (at 25 °C) varied between 0.28 ± 0.08 Pa m3 mol-1 (PCN-73) and 18.01 ± 0.69 Pa m3 mol-1 (PCN-42). The agreement between the measured and estimated H values from the octanol-water and octanol-air partition coefficients was good (measured/estimated ratio = 1.00 ± 0.41, average ± SD). The calculated phase change enthalpies (ΔHH) were within the interval previously determined for other several semivolatile organic compounds (42.0-106.4 kJ mol-1). Measured H values, paired atmospheric and aqueous concentrations and meteorological variables were also used to reveal the level and direction of air-sea exchange fluxes of PCNs at the coast of Izmir Bay, Turkey. The net PCN air-sea exchange flux varied from -0.55 (volatilization, PCN-24/14) to 2.05 (deposition, PCN-23) ng m-2 day-1. PCN-19, PCN-24/14, PCN-42, and PCN-33/34/37 were mainly volatilized from seawater while the remaining congeners were mainly deposited. The overall number of the cases showing deposition was higher (67.9%) compared to volatilization (21.4%) and near equilibrium (10.7%).

Exchange across the sediment-water interface quantified from porewater radon profiles

NASA Astrophysics Data System (ADS)

Cook, Peter G.; Rodellas, Valentí; Andrisoa, Aladin; Stieglitz, Thomas C.

2018-04-01

Water recirculation through permeable sediments induced by wave action, tidal pumping and currents enhances the exchange of solutes and fine particles between sediments and overlying waters, and can be an important hydro-biogeochemical process. In shallow water, most of the recirculation is likely to be driven by the interaction of wave-driven oscillatory flows with bottom topography which can induce pressure fluctuations at the sediment-water interface on very short timescales. Tracer-based methods provide the most reliable means for characterizing this short-timescale exchange. However, the commonly applied approaches only provide a direct measure of the tracer flux. Estimating water fluxes requires characterizing the tracer concentration in discharging porewater; this implies collecting porewater samples at shallow depths (usually a few mm, depending on the hydrodynamic dispersivity), which is very difficult with commonly used techniques. In this study, we simulate observed vertical profiles of radon concentration beneath shallow coastal lagoons using a simple water recirculation model that allows us to estimate water exchange fluxes as a function of depth below the sediment-water interface. Estimated water fluxes at the sediment water interface at our site were 0.18-0.25 m/day, with fluxes decreasing exponentially with depth. Uncertainty in dispersivity is the greatest source of error in exchange flux, and results in an uncertainty of approximately a factor-of-five.

Spume Drops: Their Potential Role in Air-Sea Gas Exchange

NASA Astrophysics Data System (ADS)

Monahan, Edward C.; Staniec, Allison; Vlahos, Penny

2017-12-01

After summarizing the time scales defining the change of the physical properties of spume and other droplets cast up from the sea surface, the time scales governing drop-atmosphere gas exchange are compared. Following a broad review of the spume drop production functions described in the literature, a subset of these functions is selected via objective criteria, to represent typical, upper bound, and lower bound production functions. Three complementary mechanisms driving spume-atmosphere gas exchange are described, and one is then used to estimate the relative importance, over a broad range of wind speeds, of this spume drop mechanism compared to the conventional, diffusional, sea surface mechanism in air-sea gas exchange. While remaining uncertainties in the wind dependence of the spume drop production flux, and in the immediate sea surface gas flux, preclude a definitive conclusion, the findings of this study strongly suggest that, at high wind speeds (>20 m s-1 for dimethyl sulfide and >30 m s-1 for gases such a carbon dioxide), spume drops do make a significant contribution to air-sea gas exchange.