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Sample records for aircraft nox emissions

  1. Impact of Aircraft Emissions on NO(x) in the Lowermost Stratosphere at Northern Midlatitudes

    NASA Technical Reports Server (NTRS)

    Kondo, Y.; Koike, M.; Ikeda, H.; Anderson, B. E.; Brunke, K. E.; Zhao, Y.; Kita, K.; Sugita, T.; Singh, H. B.; Liu, S. C.

    1999-01-01

    Airborne measurements of NO(x) total reactive nitrogen (NO(y)), O3 and condensation nuclei (CN) were made within air traffic corridors over the U.S. and North Atlantic regions (35-60 deg N) in the fall of 1997. NO(x) and NO(y) data obtained in the lowermost stratosphere (LS) were examined using the calculated increase in NO(y) ((delta)NO(y)) along five-day back trajectories as a parameter to identify possible effects of aircraft on reactive nitrogen. It is very likely that aircraft emissions had a significant impact on the NO(x) levels in the LS inasmuch as the NO(s), mixing ratios at 8.5-12 km were significantly correlated with the independent parameters of aircraft emissions, i.e., (delta)NO(y) levels and CN values. In order to estimate quantitatively the impact of aircraft emissions on NO(x), and CN, the background levels of CN and NO(x) at O3 = 100-200 ppbv were derived from the correlations of these quantities with (delta)NO(y)). On average, the aircraft emissions are estimated to have increased the NO(x) and CN values by 130 pptv and 400 STP,cc, respectively, which corresponds to 70 -/+ 30 % and 30 -/+ 20 % of the observed median values.

  2. CO2, NOx, and particle emissions from aircraft and support activities at a regional airport.

    PubMed

    Klapmeyer, Michael E; Marr, Linsey C

    2012-10-16

    The goal of this research was to quantify emissions of carbon dioxide (CO(2)), nitrogen oxides (NO(x)), particle number, and black carbon (BC) from in-use aircraft and related activity at a regional airport. Pollutant concentrations were measured adjacent to the airfield and passenger terminal at the Roanoke Regional Airport in Virginia. Observed NO(x) emission indices (EIs) for jet-powered, commuter aircraft were generally lower than those contained in the International Civil Aviation Organization databank for both taxi (same as idle) and takeoff engine settings. NO(x) EIs ranged from 1.9 to 3.7 g (kg fuel)(-1) across five types of aircraft during taxiing, whereas EIs were consistently higher, 8.8-20.6 g (kg fuel)(-1), during takeoff. Particle number EIs ranged from 1.4 × 10(16) to 7.1 × 10(16) (kg fuel)(-1) and were slightly higher in taxi mode than in takeoff mode for four of the five types of aircraft. Diurnal patterns in CO(2) and NO(x) concentrations were influenced mainly by atmospheric conditions, while patterns in particle number concentrations were attributable mainly to patterns in aircraft activity. CO(2) and NO(x) fluxes measured by eddy covariance were higher at the terminal than at the airfield and were lower than found in urban areas.

  3. Parameterization of plume chemistry into large-scale atmospheric models: Application to aircraft NOx emissions

    NASA Astrophysics Data System (ADS)

    Cariolle, D.; Caro, D.; Paoli, R.; Hauglustaine, D. A.; CuéNot, B.; Cozic, A.; Paugam, R.

    2009-10-01

    A method is presented to parameterize the impact of the nonlinear chemical reactions occurring in the plume generated by concentrated NOx sources into large-scale models. The resulting plume parameterization is implemented into global models and used to evaluate the impact of aircraft emissions on the atmospheric chemistry. Compared to previous approaches that rely on corrected emissions or corrective factors to account for the nonlinear chemical effects, the present parameterization is based on the representation of the plume effects via a fuel tracer and a characteristic lifetime during which the nonlinear interactions between species are important and operate via rates of conversion for the NOx species and an effective reaction rates for O3. The implementation of this parameterization insures mass conservation and allows the transport of emissions at high concentrations in plume form by the model dynamics. Results from the model simulations of the impact on atmospheric ozone of aircraft NOx emissions are in rather good agreement with previous work. It is found that ozone production is decreased by 10 to 25% in the Northern Hemisphere with the largest effects in the north Atlantic flight corridor when the plume effects on the global-scale chemistry are taken into account. These figures are consistent with evaluations made with corrected emissions, but regional differences are noticeable owing to the possibility offered by this parameterization to transport emitted species in plume form prior to their dilution at large scale. This method could be further improved to make the parameters used by the parameterization function of the local temperature, humidity and turbulence properties diagnosed by the large-scale model. Further extensions of the method can also be considered to account for multistep dilution regimes during the plume dissipation. Furthermore, the present parameterization can be adapted to other types of point-source NOx emissions that have to be

  4. Emissions of NOx, particle mass and particle numbers from aircraft main engines, APU's and handling equipment at Copenhagen Airport

    NASA Astrophysics Data System (ADS)

    Winther, Morten; Kousgaard, Uffe; Ellermann, Thomas; Massling, Andreas; Nøjgaard, Jacob Klenø; Ketzel, Matthias

    2015-01-01

    This paper presents a detailed emission inventory for NOx, particle mass (PM) and particle numbers (PN) for aircraft main engines, APU's and handling equipment at Copenhagen Airport (CPH) based on time specific activity data and representative emission factors for the airport. The inventory has a high spatial resolution of 5 m × 5 m in order to be suited for further air quality dispersion calculations. Results are shown for the entire airport and for a section of the airport apron area ("inner apron") in focus. The methodology presented in this paper can be used to quantify the emissions from aircraft main engines, APU and handling equipment in other airports. For the entire airport, aircraft main engines is the largest source of fuel consumption (93%), NOx, (87%), PM (61%) and PN (95%). The calculated fuel consumption [NOx, PM, PN] shares for APU's and handling equipment are 5% [4%, 8%, 5%] and 2% [9%, 31%, 0%], respectively. At the inner apron area for handling equipment the share of fuel consumption [NOx, PM, PN] are 24% [63%, 75%, 2%], whereas APU and main engines shares are 43% [25%, 19%, 54%], and 33% [11%, 6%, 43%], respectively. The inner apron NOx and PM emission levels are high for handling equipment due to high emission factors for the diesel fuelled handling equipment and small for aircraft main engines due to small idle-power emission factors. Handling equipment is however a small PN source due to the low number based emission factors. Jet fuel sulphur-PM sensitivity calculations made in this study with the ICAO FOA3.0 method suggest that more than half of the PM emissions from aircraft main engines at CPH originate from the sulphur content of the fuel used at the airport. Aircraft main engine PN emissions are very sensitive to the underlying assumptions. Replacing this study's literature based average emission factors with "high" and "low" emission factors from the literature, the aircraft main engine PN emissions were estimated to change with a

  5. Evaluating BC and NOx emission inventories for the Paris region from MEGAPOLI aircraft measurements

    NASA Astrophysics Data System (ADS)

    Petetin, H.; Beekmann, M.; Colomb, A.; Denier van der Gon, H. A. C.; Dupont, J.-C.; Honoré, C.; Michoud, V.; Morille, Y.; Perrussel, O.; Schwarzenboeck, A.; Sciare, J.; Wiedensohler, A.; Zhang, Q. J.

    2015-09-01

    High uncertainties affect black carbon (BC) emissions, and, despite its important impact on air pollution and climate, very few BC emissions evaluations are found in the literature. This paper presents a novel approach, based on airborne measurements across the Paris, France, plume, developed in order to evaluate BC and NOx emissions at the scale of a whole agglomeration. The methodology consists in integrating, for each transect, across the plume observed and simulated concentrations above background. This allows for several error sources (e.g., representativeness, chemistry, plume lateral dispersion) to be minimized in the model used. The procedure is applied with the CHIMERE chemistry-transport model to three inventories - the EMEP inventory and the so-called TNO and TNO-MP inventories - over the month of July 2009. Various systematic uncertainty sources both in the model (e.g., boundary layer height, vertical mixing, deposition) and in observations (e.g., BC nature) are discussed and quantified, notably through sensitivity tests. Large uncertainty values are determined in our results, which limits the usefulness of the method to rather strongly erroneous emission inventories. A statistically significant (but moderate) overestimation is obtained for the TNO BC emissions and the EMEP and TNO-MP NOx emissions, as well as for the BC / NOx emission ratio in TNO-MP. The benefit of the airborne approach is discussed through a comparison with the BC / NOx ratio at a ground site in Paris, which additionally suggests a spatially heterogeneous error in BC emissions over the agglomeration.

  6. Aircraft NO/x/ emissions and stratospheric ozone reductions - Another look

    NASA Technical Reports Server (NTRS)

    Turco, R. P.; Whitten, R. C.; Toon, O. B.; Inn, E. C. Y.; Hamill, P.

    1981-01-01

    New estimates for stratospheric ozone perturbations attributable to supersonic transport (SST) emissions are presented. First, a review is given of recent data pointing to lower OH concentrations below 30 km, as compared to the values predicted by photochemical models. The evidence for lower OH comes from a wide range of laboratory and atmospheric studies. The sensitivity of theoretical estimates of ozone change to OH abundances, and the coupling mechanisms between the O(x)-NO(x)-HO(x)-Cl(x) families which are responsible for the sensitivity, are discussed. Updated calculations for SST-induced ozone alterations are compared with older predictions. For example, assuming continuous aircraft injection of NO2 at 20 km at a rate of 1 x 10 to the 9th kg per year (globally), a 4% ozone decrease, is now calculated where earlier a 3% ozone increase was found. This large variance from previous forecasts suggests that new assessments of certain other polluting agents, particularly nitrogen fertilizers, are needed.

  7. Seasonal Chemical and Dynamical Responses in a Chemistry-Climate model to Aircraft NOx Emissions: Simulations with the GEOS CCM and Comparisons with GMI

    NASA Astrophysics Data System (ADS)

    Selkirk, H. B.; Rodriguez, J. M.; Oman, L.; Liang, Q.; Douglass, A. R.; Pawson, S.; Manyin, M.; Ott, L. E.; Damoah, R.

    2011-12-01

    We have run multi-year ensembles of one-year simulations with GEOS CCM to study both annual average and seasonal effects of NOx emissions by aviation. GEOS CCM is an atmospheric GCM with interactive stratospheric and tropospheric chemistry. Hourly aircraft NOx emissions over the globe for the year 2006 were provided by courtesy of the US Department of Transportation. All simulations were forced by historical SSTs and sea ice with constant greenhouse gases for 2005, and climatological lightning NOx, aerosols and dust were prescribed in monthly fields. On average, the perturbation response in NOx is positive and predominantly in the upper troposphere and lower stratosphere of the Northern Hemisphere where the bulk of the emissions lie, reaching values over 50 pptv at ~10 km on an annual average basis. The concomitant ozone response extends over a deeper layer in the troposphere with statistically significant mid-tropospheric increases of more than 5% and 8% in mid-latitudes and at the northern polar regions. Seasonal differences in the responses are striking, with the largest perturbations of NOx during January at the tropopause near the core of the emissions at 40°N, while in July perturbations over 50 pptv spread throughout the Arctic. These differences are reflected in ozone, which shows perturbations of 50 ppbv and greater in July at the summer polar tropopause while in January the tropospheric response throughout the middle and polar latitudes is limited to ~10 ppbv. We compare these seasonal variations in response to aviation NOx emissions in GEOS CCM with those from GMI, a chemical transport model that shares the COMBO chemistry scheme with GEOS CCM . Finally, we examine the radiative impacts of these seasonal perturbations in ozone and methane.

  8. Combining active and passive remote sensing from research aircraft with atmospheric models to evaluate NOx emission fluxes and O3 formation in the Los Angeles Megacity

    NASA Astrophysics Data System (ADS)

    Baidar, Sunil; Oetjen, Hilke; Senff, Christoph; Alvarez, Raul, II; Hardesty, Michael; Langford, Andrew; Kim, Si-Wan; Trainer, Michael; Volkamer, Rainer

    2013-04-01

    Ozone (O3) and nitrogen dioxide (NO2) are two important components of air pollution. We have measured vertical column amounts of NO2, and vertical profiles of O3 and wind speed by means of measurements of solar stray light by CU Airborne MAX-DOAS, and active remote sensing using the NOAA TOPAZ lidar, and the University of Leeds Doppler lidar aboard the NOAA Twin Otter research aircraft. A total of 52 flights (up to 4 hours each) were carried out between May 19 and July 19 2010 during the CalNex and CARES field campaigns. These flights cover most of California. The boundary layer height was measured by TOPAZ lidar, and trace gas concentrations of NO2 and O3 were integrated over boundary layer height. These column integrated quantities are then combined with direct wind speed measurements to quantify directly the pollutant flux across the boundary, as defined by the flight track. By tracking the pollution fluxes during transects that are flown upwind and in various distances downwind of a NOx emission source, the NOx emission rate, and the ozone formation rate are quantified. These pollutant fluxes are calculated here for the first time exclusively based on measurements (i.e., without need to infer wind speed from a model). These fluxes provide constraints to quantify localized NOx emissions, and are being compared with WRF-Chem model simulations.

  9. Commercial Aircraft Emission Scenario for 2020: Database Development and Analysis

    NASA Technical Reports Server (NTRS)

    Sutkus, Donald J., Jr.; Baughcum, Steven L.; DuBois, Douglas P.; Wey, Chowen C. (Technical Monitor)

    2003-01-01

    This report describes the development of a three-dimensional database of aircraft fuel use and emissions (NO(x), CO, and hydrocarbons) for the commercial aircraft fleet projected to 2020. Global totals of emissions and fuel burn for 2020 are compared to global totals from previous aircraft emission scenario calculations.

  10. Aircraft Engine Emissions. [conference

    NASA Technical Reports Server (NTRS)

    1977-01-01

    A conference on a aircraft engine emissions was held to present the results of recent and current work. Such diverse areas as components, controls, energy efficient engine designs, and noise and pollution reduction are discussed.

  11. Advanced Low NOx Combustors for Aircraft Gas Turbines

    NASA Technical Reports Server (NTRS)

    Roberts, P. B.; White, D. J.; Shekleton, J. R.; Butze, H. F.

    1976-01-01

    A test rig program was conducted with the objective of evaluating and minimizing the exhaust emissions, in particular NOx, of two advanced aircraft combustor concepts at a simulated high-altitude cruise condition. The two pre-mixed, lean-reaction designs are known as the Jet Induced Circulation (JIC) combustor and the Vortex Air Blast (VAB) combustor and were rig tested in the form of reverse flow can combustors in the 0.13 ni (5.0 in. ) size range. Various configuration modifications were applied to the JIC and VAB combustor designs in an effort to reduce the emissions levels. The VAB combustor demonstrated a NOx level of 1.11 gm NO2/kg fuel with essentially 100 percent combustion efficiency at the simulated cruise combustor condition of 507 kPa (5 atm), 833 K (1500 R), inlet pressure and temperature respectively, and 1778 K (3200 R) outlet temperature on Jet-Al fuel. These configuration screening tests were carried out on essentially reaction zones only, in order to simplify the construction and modification of the combustors and to uncouple any possible effects on the emissions produced by the dilution flow. Tests were also conducted however at typical engine idle conditions on both combustors equipped with dilution ports in order to better define the problem areas involved in the operation of such concepts over a complete engine operational envelope. Versions of variable-geometry, JIC and VAB annular combustors are proposed.

  12. NASA Glenn High Pressure Low NOx Emissions Research

    NASA Technical Reports Server (NTRS)

    Tacina, Kathleen M.; Wey, Changlie

    2008-01-01

    In collaboration with U.S. aircraft engine companies, NASA Glenn Research Center has contributed to the advancement of low emissions combustion systems. For the High Speed Research Program (HSR), a 90% reduction in nitrogen oxides (NOx) emissions (relative to the then-current state of the art) has been demonstrated in sector rig testing at General Electric Aircraft Engines (GEAE). For the Advanced Subsonic Technology Program (AST), a 50% reduction in NOx emissions relative to the 1996 International Civil Aviation Organization (ICAO) standards has been demonstrated in sector rigs at both GEAE and Pratt & Whitney (P&W). During the Ultra Efficient Engine Technology Program (UEET), a 70% reduction in NOx emissions, relative to the 1996 ICAO standards, was achieved in sector rig testing at Glenn in the world class Advanced Subsonic Combustion Rig (ASCR) and at contractor facilities. Low NOx combustor development continues under the Fundamental Aeronautics Program. To achieve these reductions, experimental and analytical research has been conducted to advance the understanding of emissions formation in combustion processes. Lean direct injection (LDI) concept development uses advanced laser-based non-intrusive diagnostics and analytical work to complement the emissions measurements and to provide guidance for concept improvement. This paper describes emissions results from flametube tests of a 9-injection-point LDI fuel/air mixer tested at inlet pressures up to 5500 kPa. Sample results from CFD and laser diagnostics are also discussed.

  13. Controlling NOx emission from industrial sources

    SciTech Connect

    Srivastava, R.K.; Nueffer, W.; Grano, D.; Khan, S.; Staudt, J.E.; Jozewicz, W.

    2005-07-01

    A number of regulatory actions focused on reducing NOx emissions from stationary combustion sources have been taken in the United States in the last decade. These actions include the Acid Rain NOx regulations, the Ozone Transport Commission's NOx Budget Program, and the NOx SIP Call rulemakings. In addition to these regulations, the recent Interstate Air Quality Rulemaking proposal and other bills in the Congress are focusing on additional reductions of NOx. Industrial combustion sources accounted for about 18016 of NOx emissions in the United States in 2000 and constituted the second largest emitting source category within stationary sources, only behind electric utility sources. Based on these data, reduction of NOx emissions from industrial combustion sources is an important consideration in efforts undertaken to address the environmental concerns associated with NOx. This paper discusses primary and secondary NOx control technologies applicable to various major categories of industrial sources. The sources considered in this paper include large boilers, furnaces and fired heaters, combustion turbines, large IC engines, and cement kilns. For each source category considered in this paper, primary NOx controls are discussed first, followed by a discussion of secondary NOx controls.

  14. Variation of radiative forcings and global warming potentials from regional aviation NOx emissions

    NASA Astrophysics Data System (ADS)

    Skowron, Agnieszka; Lee, David S.; De León, Ruben R.

    2015-03-01

    The response to hemispherical and regional aircraft NOx emissions is explored by using two climate metrics: radiative forcing (RF) and Global Warming Potential (GWP). The global chemistry transport model, MOZART-3 CTM, is applied in this study for a series of incremental aircraft NOx emission integrations to different regions. It was found that the sensitivity of chemical responses per unit emission rate from regional aircraft NOx emissions varies with size of aircraft NOx emission rate and that climate metric values decrease with increasing aircraft NOx emission rates, except for Southeast Asia. Previous work has recognized that aircraft NOx GWPs may vary regionally. However, the way in which these regional GWPs are calculated are critical. Previous studies have added a fixed amount of NOx to different regions. This approach can heavily bias the results of a regional GWP because of the well-established sensitivity of O3 production to background NOx whereby the Ozone Production Efficiency (OPE) is greater at small background NOx. Thus, even a small addition of NOx in a clean-air area can produce a large O3 response. Using this 'fixed addition' method of 0.035 Tg(N) yr-1, results in the greatest effect observed for North Atlantic and Brazil, ∼10.0 mW m-2/Tg(N) yr-1. An alternative 'proportional approach' is also taken that preserves the subtle balance of local NOx-O3-CH4 systems with the existing emission patterns of aircraft and background NOx, whereby a proportional amount of aircraft NOx, 5% (N) yr-1, is added to each region in order to determine the response. This results in the greatest effect observed for North Pacific that with its net NOx RF of 23.7 mW m-2/Tg(N) yr-1 is in contrast with the 'fixed addition' method. For determining regional NOx GWPs, it is argued that the 'proportional' approach gives more representative results. However, a constraint of both approaches is that the regional GWP determined is dependent on the relative global emission pattern

  15. Global mortality attributable to aircraft cruise emissions.

    PubMed

    Barrett, Steven R H; Britter, Rex E; Waitz, Ian A

    2010-10-01

    Aircraft emissions impact human health though degradation of air quality. The majority of previous analyses of air quality impacts from aviation have considered only landing and takeoff emissions. We show that aircraft cruise emissions impact human health over a hemispheric scale and provide the first estimate of premature mortalities attributable to aircraft emissions globally. We estimate ∼8000 premature mortalities per year are attributable to aircraft cruise emissions. This represents ∼80% of the total impact of aviation (where the total includes the effects of landing and takeoff emissions), and ∼1% of air quality-related premature mortalities from all sources. However, we note that the impact of landing and takeoff emissions is likely to be under-resolved. Secondary H(2)SO(4)-HNO(3)-NH(3) aerosols are found to dominate mortality impacts. Due to the altitude and region of the atmosphere at which aircraft emissions are deposited, the extent of transboundary air pollution is particularly strong. For example, we describe how strong zonal westerly winds aloft, the mean meridional circulation around 30-60°N, interaction of aircraft-attributable aerosol precursors with background ammonia, and high population densities in combination give rise to an estimated ∼3500 premature mortalities per year in China and India combined, despite their relatively small current share of aircraft emissions. Subsidence of aviation-attributable aerosol and aerosol precursors occurs predominantly around the dry subtropical ridge, which results in reduced wet removal of aviation-attributable aerosol. It is also found that aircraft NO(x) emissions serve to increase oxidation of nonaviation SO(2), thereby further increasing the air quality impacts of aviation. We recommend that cruise emissions be explicitly considered in the development of policies, technologies and operational procedures designed to mitigate the air quality impacts of air transportation.

  16. Correlating Engine NOx Emission with Biodiesel Composition

    NASA Astrophysics Data System (ADS)

    Jeyaseelan, Thangaraja; Mehta, Pramod Shankar

    2016-06-01

    Biodiesel composition comprising of saturated and unsaturated fatty acid methyl esters has a significant influence on its properties and hence the engine performance and emission characteristics. This paper proposes a comprehensive approach for composition-property-NOx emission analysis for biodiesel fuels and highlights the pathways responsible for such a relationship. Finally, a procedure and a predictor equation are developed for the assessment of biodiesel NOx emission from its composition details.

  17. LOW-CONCENTRATION NOX EMISSIONS MEASUREMENT

    EPA Science Inventory

    The paper gives results of a recent series of low-concentration nitrogen oxides (NOx) emission measurements, made by Midwest Research Institute (MRI) during U.S. EPA-sponsored Environmental Technology Verification (ETV) test of a NOx control system called Xonon (TM) Cool Combust...

  18. Modelling NOx emissions of single droplet combustion

    NASA Astrophysics Data System (ADS)

    Moesl, Klaus G.; Schwing, Joachim E.; Sattelmayer, Thomas

    2012-02-01

    An approach for modelling and simulation of the generation of nitrogen oxide (NOx) in the gas phase surrounding single burning droplets is presented. Assuming spherical symmetry (no gravity, no forced convection), the governing equations are derived first. Then simplifications are introduced and it is proven that they are appropriate. The influences of the initial droplet diameter, the ambient conditions, and the droplet pre-vapourisation on NOx are investigated. The fuel of choice is n-decane (C10H22) as it resembles kerosene and diesel fuel best, and the complexity of the reaction mechanism is manageable. Combinations of C10H22 mechanisms and well-established NOx kinetics are evaluated in detail and validated for their applicability in the context of this work. The conducted simulations of droplet combustion in an atmosphere of hot exhaust gas show that NOx formation (by mass of fuel) increases linearly with the droplet diameter. There is a trade-off between available oxygen and ambient temperature. Increasing the equivalence ratio of the exhaust gas leads to higher NOx emissions in the very lean regime, but to lower emissions if the equivalence ratio exceeds 0.85. Pre-vapourisation of fuel at ambient conditions becomes beneficial with respect to NOx emissions only if the degree of vapourisation is above a minimum limit. If less fuel is vapourised before ignition, the NOx emissions remain almost unaffected.

  19. The impact of global aviation NOx emissions on tropospheric composition changes from 2005 to 2011

    NASA Astrophysics Data System (ADS)

    Wasiuk, D. K.; Khan, M. A. H.; Shallcross, D. E.; Lowenberg, M. H.

    2016-09-01

    The impact of aviation NOx emissions from 2005 to 2011 on the chemical composition of the atmosphere has been investigated on the basis of integrations of the 3-D global chemical and transport model, STOCHEM-CRI with the novel CRIv2-R5 chemistry scheme. A base case simulation without aircraft NOx emissions and integrations with NOx emissions from aircraft are inter-compared. The sensitivity of the global atmosphere to varying the quantity and the geographical distribution of the global annual aviation NOx emissions is assessed by performing, for the first time, a series of integrations based on changing the total mass and distribution of aircraft NOx emissions derived from air traffic movements recorded between 2005 and 2011. The emissions of NOx from the global fleet based on actual records of air traffic movements between 2005 and 2011 increased the global tropospheric annual mean burden of O3 by 1.0 Tg and decreased the global tropospheric annual mean burden of CH4 by 2.5 Tg. The net NOy and O3 production increases by 0.5% and 1%, respectively between 2005 and 2011 in total. At cruise altitude, the absolute increase in the modelled O3 mixing ratios is found to be up to 0.7 ppb between 2005 and 2011 at 25°N-50°N.

  20. NOx Emission Reduction by Oscillating Combustion

    SciTech Connect

    2005-09-01

    This project focuses on a new technology that reduces NOx emissions while increasing furnace efficiency for both air- and oxygen-fired furnaces. Oscillating combustion is a retrofit technology that involves the forced oscillation of the fuel flow rate to a furnace. These oscillations create successive, fuel-rich and fuel-lean zones within the furnace.

  1. Year 2015 Aircraft Emission Scenario for Scheduled Air Traffic

    NASA Technical Reports Server (NTRS)

    Baughcum, Steven L.; Sutkus, Donald J.; Henderson, Stephen C.

    1998-01-01

    This report describes the development of a three-dimensional scenario of aircraft fuel burn and emissions (fuel burned, NOx, CO, and hydrocarbons)for projected year 2015 scheduled air traffic. These emission inventories are available for use by atmospheric scientists conducting the Atmospheric Effects of Aviation Project (AEAP) modeling studies. Fuel burned and emissions of nitrogen oxides (NOx as NO2), carbon monoxides, and hydrocarbons have been calculated on a 1 degree latitude x 1 degree longitude x 1 kilometer altitude grid and delivered to NASA as electronic files.

  2. NOx emissions from a Central California dairy

    NASA Astrophysics Data System (ADS)

    Hasson, Alam S.; Ogunjemiyo, Segun O.; Trabue, Steven; Ashkan, Shawn; Scoggin, Kenwood; Steele, Julie; Olea, Catalina; Middala, Srikar; Vu, Kennedy; Scruggs, Austen; Addala, Laxmi R.; Nana, Lucien

    2013-05-01

    Concentrations of NOx (NO + NO2) were monitored downwind from a Central California dairy facility during 2011 and 2012. NOx concentrations at the dairy were significantly higher than the background levels during August 2011 primarily due to the presence of elevated NO, but were indistinguishable from background concentrations during January and April 2012. A Gaussian plume model (AERMOD) and a Lagrangian back trajectory model (Wind Trax) were used to estimate the flux of NO from the dairy during August 2011 with the assumption that emissions were primarily from animal feed. NO emissions from silage were also directly measured from feed to provide additional insight into the sources. Isolation flux chamber measurements imply an NO flux from the feed of about 1.3 × 10-3 g m-2 h-1, but these relatively low fluxes are inconsistent with the elevated NO concentrations observed during August 2011. This implies that either the flux chamber method grossly underestimates the true NO emissions from feed, or that most of the ambient NO measured at the dairy is from other sources. Emissions from farm machinery may account for the NO concentrations observed. Animal feed thus appears to be a small contributor to NOx emissions within Central California.

  3. Wide range operation of advanced low NOx aircraft gas turbine combustors

    NASA Technical Reports Server (NTRS)

    Roberts, P. B.; Fiorito, R. J.; Butze, H. F.

    1978-01-01

    The paper summarizes the results of an experimental test rig program designed to define and demonstrates techniques which would allow the jet-induced circulation and vortex air blast combustors to operate stably with acceptable emissions at simulated engine idle without compromise to the low NOx emissions under the high-altitude supersonic cruise condition. The discussion focuses on the test results of the key combustor modifications for both the simulated engine idle and cruise conditions. Several range-augmentation techniques are demonstrated that allow the lean-reaction premixed aircraft gas turbine combustor to operate with low NOx emissons at engine cruise and acceptable CO and UHC levels at engine idle. These techniques involve several combinations, including variable geometry and fuel switching designs.

  4. NOx emissions in China: historical trends and future perspectives

    NASA Astrophysics Data System (ADS)

    Zhao, B.; Wang, S. X.; Xu, J. Y.; Fu, K.; Klimont, Z.; Hao, J. M.; He, K. B.; Cofala, J.; Amann, M.

    2013-06-01

    Nitrogen oxides (NOx) are key pollutants for the improvement of ambient air quality. Within this study we estimated the historical NOx emissions in China for the period 1995-2010, and calculated future NOx emissions every five years until 2030 under six emission scenarios. Driven by the fast growth of energy consumption, we estimate the NOx emissions in China increased rapidly from 11.0 Mt in 1995 to 26.1 Mt in 2010. Power plants, industry and transportation were major sources of NOx emissions, accounting for 28.4, 34.0, and 25.4% of the total NOx emissions in 2010, respectively. Two energy scenarios, a business as usual scenario (BAU) and an alternative policy scenario (PC), were developed to project future energy consumption. In 2030, total energy consumption is projected to increase by 64 and 27% from 2010 level respectively. Three sets of end-of-pipe pollution control measures, including baseline, progressive, and stringent control case, were developed for each energy scenario, thereby constituting six emission scenarios. By 2030, the total NOx emissions are projected to increase (compared to 2010) by 36% in the baseline while policy cases result in reduction up to 61% in the most ambitious case with stringent control measures. More than a third of the reduction achieved by 2030 between least and most ambitious scenario comes from power sector and more than half is distributed equally between industry and transportation sectors. Selective Catalytic Reduction dominates the NOx emission reductions in power plants, while life style changes, control measures for industrial boilers and cement production are major contributors to reductions in industry. Timely enforcement of legislation on heavy duty vehicles would contribute significantly to NOx emission reductions. About 30% of the NOx emission reduction in 2020, and 40% of the NOx emission reduction in 2030 could be treated as the ancillary benefit of energy conservation. Sensitivity analysis was conducted to

  5. NOx emissions in China: historical trends and future perspectives

    NASA Astrophysics Data System (ADS)

    Zhao, B.; Wang, S. X.; Liu, H.; Xu, J. Y.; Fu, K.; Klimont, Z.; Hao, J. M.; He, K. B.; Cofala, J.; Amann, M.

    2013-10-01

    Nitrogen oxides (NOx) are key pollutants for the improvement of ambient air quality. Within this study we estimated the historical NOx emissions in China for the period 1995-2010, and calculated future NOx emissions every five years until 2030 under six emission scenarios. Driven by the fast growth of energy consumption, we estimate the NOx emissions in China increased rapidly from 11.0 Mt in 1995 to 26.1 Mt in 2010. Power plants, industry and transportation were major sources of NOx emissions, accounting for 28.4%, 34.0%, and 25.4% of the total NOx emissions in 2010, respectively. Two energy scenarios, a business as usual scenario (BAU) and an alternative policy scenario (PC), were developed to project future energy consumption. In 2030, total energy consumption is projected to increase by 64% and 27% from 2010 level respectively. Three sets of end-of-pipe pollution control measures, including baseline, progressive, and stringent control case, were developed for each energy scenario, thereby constituting six emission scenarios. By 2030, the total NOx emissions are projected to increase (compared to 2010) by 36% in the baseline while policy cases result in reduction up to 61% in the most ambitious case with stringent control measures. More than a third of the reduction achieved by 2030 between least and most ambitious scenario comes from power sector, and more than half is distributed equally between industry and transportation sectors. Selective catalytic reduction dominates the NOx emission reductions in power plants, while life style changes, control measures for industrial boilers and cement production are major contributors to reductions in industry. Timely enforcement of legislation on heavy-duty vehicles would contribute significantly to NOx emission reductions. About 30% of the NOx emission reduction in 2020 and 40% of the NOx emission reduction in 2030 could be treated as the ancillary benefit of energy conservation. Sensitivity analysis was conducted to

  6. Verification of NOx emission inventories over North Korea.

    PubMed

    Kim, Na Kyung; Kim, Yong Pyo; Morino, Yu; Kurokawa, Jun-ichi; Ohara, Toshimasa

    2014-12-01

    In this study, the top-down NOx emissions estimated from satellite observations of NO2 vertical column densities over North Korea from 1996 to 2009 were analyzed. Also, a bottom-up NOx emission inventory from REAS 1.1 from 1980 to 2005 was analyzed with several statistics. REAS 1.1 was in good agreement with the top-down approach for both trend and amount. The characteristics of NOx emissions in North Korea were quite different from other developed countries including South Korea. In North Korea, emissions from industry sector was the highest followed by transportation sector in the 1980s. However, after 1990, the NOx emissions from other sector, mainly agriculture, became the 2nd highest. Also, no emission centers such as urban areas or industrial areas were distinctively observed. Finally, the monthly NOx emissions were high during the warm season.

  7. High Pressure Low NOx Emissions Research: Recent Progress at NASA Glenn Research Center

    NASA Technical Reports Server (NTRS)

    Chi-Ming, Lee; Tacina, Kathleen M.; Wey, Changlie

    2007-01-01

    In collaboration with U.S. aircraft engine companies, NASA Glenn Research Center has contributed to the advancement of low emissions combustion systems. For the High Speed Research Program (HSR), a 90% reduction in nitrogen oxides (NOx) emissions (relative to the then-current state of the art) has been demonstrated in sector rig testing at General Electric Aircraft Engines (GEAE). For the Advanced Subsonic Technology Program (AST), a 50% reduction in NOx emissions relative to the 1996 International Civil Aviation Organization (ICAO) standards has been at demonstrated in sector rigs at both GEAE and Pratt & Whitney (P&W). During the Ultra Efficient Engine Technology Program (UEET), a 70% reduction in NOx emissions, relative to the 1996 ICAO standards, was achieved in sector rig testing at Glenn in the world class Advanced Subsonic Combustion Rig (ASCR) and at contractor facilities. Low NOx combustor development continues under the Fundamental Aeronautics Program. To achieve these reductions, experimental and analytical research has been conducted to advance the understanding of emissions formation in combustion processes. Lean direct injection (LDI) concept development uses advanced laser-based non-intrusive diagnostics and analytical work to complement the emissions measurements and to provide guidance for concept improvement. This paper describes emissions results from flametube tests of a 9- injection-point LDI fuel/air mixer tested at inlet pressures up to 5500 kPa. Sample results from CFD and laser diagnostics are also discussed.

  8. Water Misting and Injection of Commercial Aircraft Engines to Reduce Airport NOx

    NASA Technical Reports Server (NTRS)

    Daggett, David L.; Hendricks, Robert C. (Technical Monitor)

    2004-01-01

    This report provides the first high level look at system design, airplane performance, maintenance, and cost implications of using water misting and water injection technology in aircraft engines for takeoff and climb-out NOx emissions reduction. With an engine compressor inlet water misting rate of 2.2 percent water-to-air ratio, a 47 percent NOx reduction was calculated. Combustor water injection could achieve greater reductions of about 85 percent, but with some performance penalties. For the water misting system on days above 59 F, a fuel efficiency benefit of about 3.5 percent would be experienced. Reductions of up to 436 F in turbine inlet temperature were also estimated, which could lead to increased hot section life. A 0.61 db noise reduction will occur. A nominal airplane weight penalty of less than 360 lb (no water) was estimated for a 305 passenger airplane. The airplane system cost is initially estimated at $40.92 per takeoff giving an attractive NOx emissions reduction cost/benefit ratio of about $1,663/ton.

  9. Alternative control techniques document. NOx emissions from stationary gas turbines

    SciTech Connect

    Snyder, R.B.

    1993-01-01

    The Alternative Control Techniques document describes available control technologies for reducing NOx emissions levels from stationary combustion gas turbines. Information on the formation of NOx and uncontrolled NOx emissions from gas turbines is included. Water injection, steam injection, and low-NOx combustors, used independently or in combination with selective catalytic reduction (SCR), are discussed. Achievable controlled NOx emissions levels, costs and cost effectiveness, and environmental impacts are presented and applicability to new equipment as well as retrofit applications is discussed. The application of these technologies to gas turbines operating in offshore platform applications is included. Information on the use of alternate fuels, catalytic combustion, and selective noncatalytic reduction (SNCR) to reduce NOx emissions is also briefly presented.

  10. Catalytic effects of minerals on NOx emission from coal combustion

    SciTech Connect

    Yao, M.Y.; Che, D.F.

    2007-07-01

    The catalytic effects of inherent mineral matters on NOx emissions from coal combustion have been investigated by a thermo-gravimetric analyzer (TGA) equipped with a gas analyzer. The effect of demineralization and the individual effect of Na, K, Ca, Mg, and Fe on the formation of NOx are studied as well as the combined catalytic effects of Ca + Na and Ca + Ti. Demineralization causes more Fuel-N to retain in the char, and reduction of NOx mostly. But the mechanistic effect on NOx formation varies from coal to coal. Ca and Mg promote NOx emission. Na, K, Fe suppress NOx formation to different extents. The effect of transition element Fe is the most obvious. The combination of Ca + Na and Ca + Ti can realize the simultaneous control of sulfur dioxide and nitrogen oxides emissions.

  11. Aircraft NO(x) had no Unique Fingerprint on Sonex; Lightning Dominated Fresh NO(x) Sources

    NASA Technical Reports Server (NTRS)

    Thompson, A.; Sparling, L.; Kondo, Y.; Anderson, B.; Gregory, G.; Sachse, G.

    1999-01-01

    Key questions to which SONEX was directed were the following: Can aircraft corridors be detected? Is there a unique tracer for aircraft NO(x)? Can a "background" NO(x) (or NO(y) be defined? What fraction of NO(x) measured during SONEX was from aircraft? How representative was SONEX of the North Atlantic in 1997 and how typical of other years? We attempt to answer these questions through species-species correlations, probability distribution functions (PDFs), and meteorological history. There is not a unique aircraft tracer, largely due to the high variability of air mass origins and tracer ratios, which render "average" quantities meaningless. The greatest NO and NO(y) signals were associated with lightning and convective NO sources. Well-defined background CO, NO(y) and NO(y)/ozone ratio appear in subsets of two cross-track flights with subtropical origins and five flights with predominantly mid-latitude air. Forty percent of the observations on these 7 flights showed NO(y)/ozone to be above background, evidently due to unreacted NO(x). This NO(x) is a combination of aircraft, lightning and surface pollution injected by convection. The strongly subtropical signatures in SONEX observations, confirmed by pv (potential vorticity) values along flight tracks, argues for most of the unreacted NO(x) originating from lightning. Potential vorticity statistics along SONEX flight tracks in 1992-1998, and for the North Atlantic as a whole, show the SONEX meteorological environment to be representative of the North Atlantic flight corridor in the October-November period.

  12. Scheduled civil aircraft emission inventories for 1992: Database development and analysis

    NASA Technical Reports Server (NTRS)

    Baughcum, Steven L.; Tritz, Terrance G.; Henderson, Stephen C.; Pickett, David C.

    1996-01-01

    This report describes the development of a three-dimensional database of aircraft fuel burn and emissions (fuel burned, NOx, CO, and hydrocarbons) from scheduled commercial aircraft for each month of 1992. The seasonal variation in aircraft emissions was calculated for selected regions (global, North America, Europe, North Atlantic, and North Pacific). A series of parametric calculations were done to quantify the possible errors introduced from making approximations necessary to calculate the global emission inventory. The effects of wind, temperature, load factor, payload, and fuel tankering on fuel burn were evaluated to identify how they might affect the accuracy of aircraft emission inventories. These emissions inventories are available for use by atmospheric scientists conducting the Atmospheric Effects of Aviation Project (AEAP) modeling studies. Fuel burned and emissions of nitrogen oxides (NOx as N02), carbon monoxide, and hydrocarbons have been calculated on a 1 degree latitude x 1 degree longitude x 1 kilometer altitude grid and delivered to NASA as electronic files.

  13. Spatially Resolved Emissions of NOx and VOCs and Comparison to Inventories.

    NASA Astrophysics Data System (ADS)

    Vaughan, A. R.; Lee, J. D.; Lewis, A. C.; Shaw, M.; Purvis, R.; Carslaw, D.; Hewitt, C. N.; Misztal, P. K.; Metzger, S.; Beevers, S.; Goldstein, A. H.; Karl, T.; Davison, B.

    2015-12-01

    Recent trends in ambient concentrations of NOx in the UK (and other European countries) have shown a general decrease over the period 1990 to 2002, followed by largely static concentrations from 2004 - present. This is not in line with the decreases predicted based on bottom up emission inventories and has lead to widespread non-compliance with EU Air Quality Directives. We present a method to quantify the geographic variability of emission of NOx and selected VOCs at a city scale (London) using an aircraft platform. High frequency observations of NOx and VOCs (10 Hz and 2 Hz, respectively) were made using low altitude flights across London and combined with 20 Hz micro-meteorological data to provide an emission flux using the aircraft eddy covariance technique. A continuous wavelet transformation was used to produce instantaneous fluxes along the flight transect and a parameterisation of a backward Lagrangian model used to calculate the flux footprint, attributing emission rates to specific areas in Greater London (see figure). The observed flux was compared to the UK National Atmospheric Emission Inventory (NAEI), which takes a "bottom up" approach to calculating emissions, involving estimates from different source sectors to produce yearly emission estimates. These were then modified using factors specific to each source to reflect the actual month, day and time of the flight, to provide a more meaningful comparison to the observation. A significant underestimation in the inventory NOx was observed ranging from 150-200% in outer London, to 300% in the central area. Potential reasons for this are discussed, including the poor treatment of real world emissions of NOx from diesel vehicles in the inventory. We also compare measurements to the London Atmospheric Emissions Inventory (LAEI), which provides a more explicit treatment of the traffic emissions specific to London and which shows better agreement with the measurements.

  14. Measurement of In-Flight Aircraft Emissions

    NASA Technical Reports Server (NTRS)

    Sokoloski, M.; Arnold, C.; Rider, D.; Beer, R.; Worden, H.; Glavich, T.

    1995-01-01

    Aircraft engine emission and their chemical and physical evolution can be measured in flight using high resolution infrared spectroscopy. The Airborne Emission Spectrometer (AES), designed for remote measure- ments of atmosphere emissions from an airborne platform, is an ideal tool for the evaluation of aircraft emissions and their evolution. Capabilities of AES will be discussed. Ground data will be given.

  15. Advanced low NO/x/ combustors for supersonic high-altitude aircraft gas turbines

    NASA Technical Reports Server (NTRS)

    Roberts, P. B.; Shekleton, J. R.; White, D. J.; Butze, H. F.

    1976-01-01

    A test rig program was conducted with the objective of evaluating and minimizing the exhaust emissions, in particular NO(x), of two advanced aircraft combustor concepts at a simulated, high-altitude cruise condition. The two combustor designs, both members of the lean-reaction, pre-mixed family, are known as the Jet Induced Circulation (JIC) combustor and the Vortex Air Blast (VAB) combustor and were rig tested in the form of reverse flow can combustors in the 0.127-m size range. Various configuration modifications were applied to each of the initial JIC and VAB combustor model designs in an effort to reduce the emissions levels. The VAB combustor demonstrated a NO(x) level of 1.1 gm NO2/kg fuel with essentially 100 percent combustion efficiency at the simulated cruise combustor condition of 507 kPa, 833 K inlet pressure and temperature, respectively and 1778 K outlet temperature on Jet-A1 fuel. In addition, emissions data were obtained at low combustor inlet pressure and temperatures that indicate the potential performance at engine off-design conditions.

  16. Technology for controlling emissions of oxides of nitrogen from supersonic cruise aircraft

    NASA Technical Reports Server (NTRS)

    Reck, G. M.; Rudey, R. A.

    1976-01-01

    Various experiments are sponsored and conducted by NASA to explore the potential of advanced combustion techniques for controlling aircraft engine emissions into the upper atmosphere. Of particular concern are the oxide of nitrogen (NOx) emissions into the stratosphere. The experiments utilize a wide variety of approaches varying from advanced combustor concepts to fundamental flame tube experiments. Results are presented which indicate that substantial reductions in cruise NOx emissions should be achievable in future aircraft engines. A major NASA program is described which focuses the many fundamental experiments into a planned evolution and demonstration of the prevaporized-premixed combustion technique in a full-scale engine.

  17. Avco Lycoming/NASA contract status. [on reduction of emissions from aircraft piston engines

    NASA Technical Reports Server (NTRS)

    Duke, L. C.

    1976-01-01

    The standards promulgated by the Environmental Protection Agency (EPA) for carbon monoxide (CO), unburned hydrocarbon (HC), and oxides-of-nitrogen (NOx) emissions were the basis in a study of ways to reduce emissions from aircraft piston engines. A variable valve timing system, ultrasonic fuel atomization, and ignition system changes were postulated.

  18. 40 CFR 97.154 - Compliance with CAIR NOX emissions limitation.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 22 2013-07-01 2013-07-01 false Compliance with CAIR NOX emissions... PROGRAMS (CONTINUED) FEDERAL NOX BUDGET TRADING PROGRAM AND CAIR NOX AND SO2 TRADING PROGRAMS CAIR NOX Allowance Tracking System § 97.154 Compliance with CAIR NOX emissions limitation. (a) Allowance...

  19. 40 CFR 96.154 - Compliance with CAIR NOX emissions limitation.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 21 2011-07-01 2011-07-01 false Compliance with CAIR NOX emissions... PROGRAMS (CONTINUED) NOX BUDGET TRADING PROGRAM AND CAIR NOX AND SO2 TRADING PROGRAMS FOR STATE IMPLEMENTATION PLANS CAIR NOX Allowance Tracking System § 96.154 Compliance with CAIR NOX emissions...

  20. 40 CFR 97.354 - Compliance with CAIR NOX emissions limitation.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 21 2011-07-01 2011-07-01 false Compliance with CAIR NOX emissions... PROGRAMS (CONTINUED) FEDERAL NOX BUDGET TRADING PROGRAM AND CAIR NOX AND SO2 TRADING PROGRAMS CAIR NOX Ozone Season Allowance Tracking System § 97.354 Compliance with CAIR NOX emissions limitation....

  1. 40 CFR 97.154 - Compliance with CAIR NOX emissions limitation.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 21 2011-07-01 2011-07-01 false Compliance with CAIR NOX emissions... PROGRAMS (CONTINUED) FEDERAL NOX BUDGET TRADING PROGRAM AND CAIR NOX AND SO2 TRADING PROGRAMS CAIR NOX Allowance Tracking System § 97.154 Compliance with CAIR NOX emissions limitation. (a) Allowance...

  2. 40 CFR 97.354 - Compliance with CAIR NOX emissions limitation.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 22 2013-07-01 2013-07-01 false Compliance with CAIR NOX emissions... PROGRAMS (CONTINUED) FEDERAL NOX BUDGET TRADING PROGRAM AND CAIR NOX AND SO2 TRADING PROGRAMS CAIR NOX Ozone Season Allowance Tracking System § 97.354 Compliance with CAIR NOX emissions limitation....

  3. 40 CFR 97.154 - Compliance with CAIR NOX emissions limitation.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 22 2012-07-01 2012-07-01 false Compliance with CAIR NOX emissions... PROGRAMS (CONTINUED) FEDERAL NOX BUDGET TRADING PROGRAM AND CAIR NOX AND SO2 TRADING PROGRAMS CAIR NOX Allowance Tracking System § 97.154 Compliance with CAIR NOX emissions limitation. (a) Allowance...

  4. 40 CFR 97.354 - Compliance with CAIR NOX emissions limitation.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 22 2012-07-01 2012-07-01 false Compliance with CAIR NOX emissions... PROGRAMS (CONTINUED) FEDERAL NOX BUDGET TRADING PROGRAM AND CAIR NOX AND SO2 TRADING PROGRAMS CAIR NOX Ozone Season Allowance Tracking System § 97.354 Compliance with CAIR NOX emissions limitation....

  5. 40 CFR 96.154 - Compliance with CAIR NOX emissions limitation.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 22 2012-07-01 2012-07-01 false Compliance with CAIR NOX emissions... PROGRAMS (CONTINUED) NOX BUDGET TRADING PROGRAM AND CAIR NOX AND SO2 TRADING PROGRAMS FOR STATE IMPLEMENTATION PLANS CAIR NOX Allowance Tracking System § 96.154 Compliance with CAIR NOX emissions...

  6. Spatially resolved flux measurements of NOx from London suggest significantly higher emissions than predicted by inventories.

    PubMed

    Vaughan, Adam R; Lee, James D; Misztal, Pawel K; Metzger, Stefan; Shaw, Marvin D; Lewis, Alastair C; Purvis, Ruth M; Carslaw, David C; Goldstein, Allen H; Hewitt, C Nicholas; Davison, Brian; Beevers, Sean D; Karl, Thomas G

    2016-07-18

    To date, direct validation of city-wide emissions inventories for air pollutants has been difficult or impossible. However, recent technological innovations now allow direct measurement of pollutant fluxes from cities, for comparison with emissions inventories, which are themselves commonly used for prediction of current and future air quality and to help guide abatement strategies. Fluxes of NOx were measured using the eddy-covariance technique from an aircraft flying at low altitude over London. The highest fluxes were observed over central London, with lower fluxes measured in suburban areas. A footprint model was used to estimate the spatial area from which the measured emissions occurred. This allowed comparison of the flux measurements to the UK's National Atmospheric Emissions Inventory (NAEI) for NOx, with scaling factors used to account for the actual time of day, day of week and month of year of the measurement. The comparison suggests significant underestimation of NOx emissions in London by the NAEI, mainly due to its under-representation of real world road traffic emissions. A comparison was also carried out with an enhanced version of the inventory using real world driving emission factors and road measurement data taken from the London Atmospheric Emissions Inventory (LAEI). The measurement to inventory agreement was substantially improved using the enhanced version, showing the importance of fully accounting for road traffic, which is the dominant NOx emission source in London. In central London there was still an underestimation by the inventory of 30-40% compared with flux measurements, suggesting significant improvements are still required in the NOx emissions inventory.

  7. Spatially resolved flux measurements of NOx from London suggest significantly higher emissions than predicted by inventories.

    PubMed

    Vaughan, Adam R; Lee, James D; Misztal, Pawel K; Metzger, Stefan; Shaw, Marvin D; Lewis, Alastair C; Purvis, Ruth M; Carslaw, David C; Goldstein, Allen H; Hewitt, C Nicholas; Davison, Brian; Beevers, Sean D; Karl, Thomas G

    2016-07-18

    To date, direct validation of city-wide emissions inventories for air pollutants has been difficult or impossible. However, recent technological innovations now allow direct measurement of pollutant fluxes from cities, for comparison with emissions inventories, which are themselves commonly used for prediction of current and future air quality and to help guide abatement strategies. Fluxes of NOx were measured using the eddy-covariance technique from an aircraft flying at low altitude over London. The highest fluxes were observed over central London, with lower fluxes measured in suburban areas. A footprint model was used to estimate the spatial area from which the measured emissions occurred. This allowed comparison of the flux measurements to the UK's National Atmospheric Emissions Inventory (NAEI) for NOx, with scaling factors used to account for the actual time of day, day of week and month of year of the measurement. The comparison suggests significant underestimation of NOx emissions in London by the NAEI, mainly due to its under-representation of real world road traffic emissions. A comparison was also carried out with an enhanced version of the inventory using real world driving emission factors and road measurement data taken from the London Atmospheric Emissions Inventory (LAEI). The measurement to inventory agreement was substantially improved using the enhanced version, showing the importance of fully accounting for road traffic, which is the dominant NOx emission source in London. In central London there was still an underestimation by the inventory of 30-40% compared with flux measurements, suggesting significant improvements are still required in the NOx emissions inventory. PMID:27098421

  8. NOx Emissions from Diesel Passenger Cars Worsen with Age.

    PubMed

    Chen, Yuche; Borken-Kleefeld, Jens

    2016-04-01

    Commonly, the NOx emissions rates of diesel vehicles have been assumed to remain stable over the vehicle's lifetime. However, there have been hardly any representative long-term emission measurements. Here we present real-driving emissions of diesel cars and light commercial vehicles sampled on-road over 15 years in Zurich/Switzerland. Results suggest deterioration of NOx unit emissions for Euro 2 and Euro 3 diesel technologies, while Euro 1 and Euro 4 technologies seem to be stable. We can exclude a significant influence of high-emitting vehicles. NOx emissions from all cars and light commercial vehicles in European emission inventories increase by 5-10% accounting for the observed deterioration, depending on the country and its share of diesel cars. We suggest monitoring the stability of emission controls particularly for high-mileage light commercial as well as heavy-duty vehicles.

  9. NOx Emissions from Diesel Passenger Cars Worsen with Age.

    PubMed

    Chen, Yuche; Borken-Kleefeld, Jens

    2016-04-01

    Commonly, the NOx emissions rates of diesel vehicles have been assumed to remain stable over the vehicle's lifetime. However, there have been hardly any representative long-term emission measurements. Here we present real-driving emissions of diesel cars and light commercial vehicles sampled on-road over 15 years in Zurich/Switzerland. Results suggest deterioration of NOx unit emissions for Euro 2 and Euro 3 diesel technologies, while Euro 1 and Euro 4 technologies seem to be stable. We can exclude a significant influence of high-emitting vehicles. NOx emissions from all cars and light commercial vehicles in European emission inventories increase by 5-10% accounting for the observed deterioration, depending on the country and its share of diesel cars. We suggest monitoring the stability of emission controls particularly for high-mileage light commercial as well as heavy-duty vehicles. PMID:26886254

  10. Characterization of NOx, SO2, ethene, and propene from industrial emission sources in Houston, Texas

    NASA Astrophysics Data System (ADS)

    Washenfelder, R. A.; Trainer, M.; Frost, G. J.; Ryerson, T. B.; Atlas, E. L.; de Gouw, J. A.; Flocke, F. M.; Fried, A.; Holloway, J. S.; Parrish, D. D.; Peischl, J.; Richter, D.; Schauffler, S. M.; Walega, J. G.; Warneke, C.; Weibring, P.; Zheng, W.

    2010-08-01

    The Houston-Galveston-Brazoria urban area contains industrial petrochemical sources that emit volatile organic compounds and nitrogen oxides, resulting in rapid and efficient ozone production downwind. During September to October 2006, the NOAA WP-3D aircraft conducted research flights as part of the second Texas Air Quality Study (TexAQS II). We use measurements of NOx, SO2, and speciated hydrocarbons from industrial sources in Houston to derive source emission ratios and compare these to emission inventories and the first Texas Air Quality Study (TexAQS) in 2000. Between 2000 and 2006, NOx/CO2 emission ratios changed by an average of -29% ± 20%, while a significant trend in SO2/CO2 emission ratios was not observed. We find that high hydrocarbon emissions are routine for the isolated petrochemical facilities. Ethene (C2H4) and propene (C3H6) are the major contributors to ozone formation based on calculations of OH reactivity for organic species including C2-C10 alkanes, C2-C5 alkenes, ethyne, and C2-C5 aldehydes and ketones. Measured ratios of C2H4/NOx and C3H6/NOx exceed emission inventory values by factors of 1.4-20 and 1-24, respectively. We examine trends in C2H4/NOx and C3H6/NOx ratios between 2000 and 2006 for the isolated petrochemical sources and estimate a change of -30% ± 30%, with significant day-to-day and within-plume variability. Median ambient mixing ratios of ethene and propene in Houston show decreases of -52% and -48%, respectively, between 2000 and 2006. The formaldehyde, acetaldehyde, and peroxyacetyl nitrate products produced by alkene oxidation are observed downwind, and their time evolution is consistent with the rapid photochemistry that also produces ozone.

  11. Environmental protection agency aircraft emissions standards

    NASA Technical Reports Server (NTRS)

    Kittredge, G. D.

    1977-01-01

    Emissions of air pollutants from aircraft were investigated in order to determine: (1) the extent to which such emissions affect air quality in air quality control regions throughout the United States; and (2) the technological feasibility of controlling such emissions. The basic information supporting the need for aircraft emissions standards is summarized. The EPA ambient air quality standards are presented. Only the primary (health related) standards are shown. Of the six pollutants, only the first three, carbon monoxide (CO), hydrocarbons (HC), and nitrogen oxides, are influenced significantly by aircraft.

  12. Aircraft Emission Scenarios Projected in Year 2015 for the NASA Technology Concept Aircraft (TCA) High Speed Civil Transport

    NASA Technical Reports Server (NTRS)

    Baughcum, Steven L.; Henderson, Stephen C.

    1998-01-01

    This report describes the development of a three-dimensional database of aircraft fuel burn and emissions (fuel burned, NOx, CO, and hydrocarbons) from projected fleets of high speed civil transports (HSCTs) on a universal airline network. Inventories for 500 and 1000 HSCT fleets, as well as the concurrent subsonic fleets, were calculated. The HSCT scenarios are calculated using the NASA technology concept airplane (TCA) and update an earlier report. These emissions inventories are available for use by atmospheric scientists conducting the Atmospheric Effects of Stratospheric Aircraft (AESA) modeling studies. Fuel burned and emissions of nitrogen oxides (NOx as NO2), carbon monoxide, and hydrocarbons have been calculated on a 1 degree latitude x 1 degree longitude x 1 kilometer pressure altitude grid and delivered to NASA as electronic files.

  13. ULTRA LOW NOx INTEGRATED SYSTEM FOR NOx EMISSION CONTROL FROM COAL-FIRED BOILERS

    SciTech Connect

    Galen H. Richards; Charles Q. Maney; Richard W. Borio; Robert D. Lewis

    2002-12-30

    ALSTOM Power Inc.'s Power Plant Laboratories, working in concert with ALSTOM Power's Performance Projects Group, has teamed with the U.S. Department of Energy's National Energy Technology Laboratory (DOE NETL) to conduct a comprehensive study to develop/evaluate low-cost, efficient NOx control technologies for retrofit to pulverized coal fired utility boilers. The objective of this project was to develop retrofit NOx control technology to achieve less than 0.15 lb/MMBtu NOx (for bituminous coals) and 0.10 lb/MMBtu NOx (for subbituminous coals) from existing pulverized coal fired utility boilers at a cost which is at least 25% less than SCR technology. Efficient control of NOx is seen as an important, enabling step in keeping coal as a viable part of the national energy mix in this century, and beyond. Presently 57% of U.S. electrical generation is coal based, and the Energy Information Agency projects that coal will maintain a lead in U.S. power generation over all other fuel sources for decades (EIA 1998 Energy Forecast). Yet, coal-based power is being strongly challenged by society's ever-increasing desire for an improved environment and the resultant improvement in health and safety. The needs of the electric-utility industry are to improve environmental performance, while simultaneously improving overall plant economics. This means that emissions control technology is needed with very low capital and operating costs. This project has responded to the industry's need for low NOx emissions by evaluating ideas that can be adapted to present pulverized coal fired systems, be they conventional or low NOx firing systems. The TFS 2000{trademark} firing system has been the ALSTOM Power Inc. commercial offering producing the lowest NOx emission levels. In this project, the TFS 2000{trademark} firing system served as a basis for comparison to other low NOx systems evaluated and was the foundation upon which refinements were made to further improve NOx emissions and

  14. 40 CFR 96.354 - Compliance with CAIR NOX emissions limitation.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 22 2012-07-01 2012-07-01 false Compliance with CAIR NOX emissions... PROGRAMS (CONTINUED) NOX BUDGET TRADING PROGRAM AND CAIR NOX AND SO2 TRADING PROGRAMS FOR STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Tracking System § 96.354 Compliance with CAIR NOX...

  15. 40 CFR 97.424 - Compliance with TR NOX Annual emissions limitation.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 22 2012-07-01 2012-07-01 false Compliance with TR NOX Annual... (CONTINUED) AIR PROGRAMS (CONTINUED) FEDERAL NOX BUDGET TRADING PROGRAM AND CAIR NOX AND SO2 TRADING PROGRAMS TR NOX Annual Trading Program § 97.424 Compliance with TR NOX Annual emissions limitation....

  16. Scheduled Civil Aircraft Emission Inventories for 1976 and 1984: Database Development and Analysis

    NASA Technical Reports Server (NTRS)

    Baughcum, Steven L.; Henderson, Stephen C.; Tritz, Terrance G.

    1996-01-01

    This report describes the development of a three-dimensional database of aircraft fuel burn and emissions (fuel burned, NOx, CO, and hydrocarbons) from scheduled commercial aircraft for four months (February, May, August, and November) of 1976 and 1984. Combining this data with earlier published data for 1990 and 1992, trend analyses for fuel burned, NOx, carbon monoxide, and hydrocarbons were calculated for selected regions (global, North America, Europe, North Atlantic, and North Pacific). These emissions inventories are available for use by atmospheric scientists conducting the Atmospheric Effects of Aviation Project (AEAP) modeling studies. Fuel burned and emissions of nitrogen oxides (NOx as NO2), carbon monoxide, and hydrocarbons have been calculated on a 1 degree latitude x 1 degree longitude x 1 kilometer altitude grid and delivered to NASA as electronic files.

  17. Nox Emission Reduction in Commercial Jets Through Water Injection

    NASA Technical Reports Server (NTRS)

    Balepin, Vladimir; Ossello, Chris; Snyder, Chris

    2002-01-01

    This paper discusses a method of the nitrogen oxides (NOx) emission reduction through the injection of water in commercial turbofan engines during the takeoff and climbout cycles. In addition to emission reduction, this method can significantly reduce turbine temperature during the most demanding operational modes (takeoff and climbout) and increase engine reliability and life.

  18. NOx Sensor for Direct Injection Emission Control

    SciTech Connect

    Betteridge, William J

    2006-02-28

    The Electricore/Delphi team continues to leverage the electrochemical planar sensor technology that has produced stoichiometric planar and wide range oxygen sensors as the basis for development of a NOx sensor. Zirconia cell technology with an integrated heater will provide the foundation for the sensor structure. Proven materials and packaging technology will help to ensure a cost-effective approach to the manufacture of this sensor. The electronics technique and interface is considered to be an area where new strategies need to be employed to produce higher S/N ratios of the NOx signal with emphasis on signal stability over time for robustness and durability Both continuous mode and pulse mode control techniques are being evaluated. Packaging the electronics requires careful design and circuit partitioning so that only the necessary signal conditioning electronics are coupled directly in the wiring harness, while the remainder is situated within the ECM for durability and costs reasons. This task continues to be on hold due to the limitation that the definition of the interface electronics was unavailable until very late in the project. The sense element is based on the amperometric method utilizing integrated alumina and zirconia ceramics. Precious metal electrodes are used to form the integrated heater, the cell electrodes and leads. Inside the actual sense cell structure, it is first necessary to separate NOx from the remaining oxygen constituents of the exhaust, without reducing the NOx. Once separated, the NOx will be measured using a measurement cell. Development or test coupons have been used to facilitate material selection and refinement, cell, diffusion barrier, and chamber development. The sense element currently requires elaborate interconnections. To facilitate a robust durable connection, mechanical and metallurgical connections are under investigation. Materials and process refinements continue to play an important role in the development of the

  19. Electrochemical NOx Sensor for Monitoring Diesel Emissions

    SciTech Connect

    Woo, L Y; Glass, R S

    2008-11-14

    % NO, balance NO{sub 2}. Since automotive exhaust sensors will probably be required to operate at temperatures > 600 C, NO is the dominant component in thermodynamic equilibrium and the target NOx species. Also, the use of upstream catalysts could further promote the conversion of NO{sub x} species to NO. Therefore, the focus of current work is to investigate the response to NO. Nevertheless, minimizing the sensitivity to a variety of competing species is important in order to obtain the accuracy necessary for achieving the emission limits. Mitigating the effect of interfering gases (e.g., O{sub 2}, water vapor, HCs, etc.) is an area of current study. For impedance metric NO{sub x} sensors, our previous work has demonstrated that the cross-sensitivity to O{sub 2} may be accounted for by comparing measurements at multiple frequencies. Other strategies for compensation are also being explored, including calibration using data from existing sensors located nearby. Our current work has made significant advances in terms of developing prototype sensors more suitable for commercialization. Also, dynamometer testing has provided real-world sensor performance data that will be useful in approaching potential suppliers to whom we can transfer the technology for commercialization. The advances are a direct result of understanding the sensing mechanisms responsible for impedance-based NO{sub x} sensing and the effect of materials choice and sensor design/geometry.

  20. Estimating Lightning NOx Emissions for Regional Air Quality Modeling

    NASA Astrophysics Data System (ADS)

    Holloway, T.; Scotty, E.; Harkey, M.

    2014-12-01

    Lightning emissions have long been recognized as an important source of nitrogen oxides (NOx) on a global scale, and an essential emission component for global atmospheric chemistry models. However, only in recent years have regional air quality models incorporated lightning NOx emissions into simulations. The growth in regional modeling of lightning emissions has been driven in part by comparisons with satellite-derived estimates of column NO2, especially from the Ozone Monitoring Instrument (OMI) aboard the Aura satellite. We present and evaluate a lightning inventory for the EPA Community Multiscale Air Quality (CMAQ) model. Our approach follows Koo et al. [2010] in the approach to spatially and temporally allocating a given total value based on cloud-top height and convective precipitation. However, we consider alternate total NOx emission values (which translate into alternate lightning emission factors) based on a review of the literature and performance evaluation against OMI NO2 for July 2007 conditions over the U.S. and parts of Canada and Mexico. The vertical distribution of lightning emissions follow a bimodal distribution from Allen et al. [2012] calculated over 27 vertical model layers. Total lightning NO emissions for July 2007 show the highest above-land emissions in Florida, southeastern Texas and southern Louisiana. Although agreement with OMI NO2 across the domain varied significantly depending on lightning NOx assumptions, agreement among the simulations at ground-based NO2 monitors from the EPA Air Quality System database showed no meaningful sensitivity to lightning NOx. Emissions are compared with prior studies, which find similar distribution patterns, but a wide range of calculated magnitudes.

  1. 40 CFR 96.354 - Compliance with CAIR NOX emissions limitation.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Tracking System § 96.354 Compliance with CAIR NOX emissions limitation. (a) Allowance transfer deadline. The CAIR NOX Ozone Season allowances are available to be deducted for compliance with a source's CAIR NOX Ozone Season emissions limitation for a control period...

  2. 40 CFR 96.354 - Compliance with CAIR NOX emissions limitation.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Tracking System § 96.354 Compliance with CAIR NOX emissions limitation. (a) Allowance transfer deadline. The CAIR NOX Ozone Season allowances are available to be deducted for compliance with a source's CAIR NOX Ozone Season emissions limitation for a control period...

  3. Particle and gaseous emissions from commercial aircraft at each stage of the landing and takeoff cycle.

    PubMed

    Mazaheri, M; Johnson, G R; Morawska, L

    2009-01-15

    A novel technique was used to measure emission factors for commonly used commercial aircraft including a range of Boeing and Airbus airframes under real world conditions. Engine exhaust emission factors for particles in terms of particle number and mass (PM2.5), along with those for CO2 and NOx, were measured for over 280 individual aircraft during the various modes of landing/takeoff (LTO) cycle. Results from this study show that particle number, and NOx emission factors are dependent on aircraft engine thrust level. Minimum and maximum emissions factors for particle number, PM2.5, and NOx emissions were found to be in the range of 4.16 x 10(15)-5.42 x 10(16) kg(-1), 0.03-0.72 g.kg(-1), and 3.25-37.94 g.kg(-1), respectively, for all measured airframes and LTO cycle modes. Number size distributions of emitted particles for the naturally diluted aircraft plumes in each mode of LTO cycle showed that particles were predominantly in the range of 4-100 nm in diameter in all cases. In general, size distributions exhibit similar modality during all phases of the LTO cycle. A very distinct nucleation mode was observed in all particle size distributions, except for taxiing and landing of A320 aircraft. Accumulation modes were also observed in all particle size distributions. Analysis of aircraft engine emissions during LTO cycle showed that aircraft thrust level is considerably higher during taxiing than idling suggesting that International Civil Aviation Organization (ICAO) standards need to be modified as the thrust levels for taxi and idle are considered to be the same (7% of total thrust) (Environmental Protection, Annex 16, Vol. II, Aircraft Engine Emissions, 2nd ed.; ICAO--International Civil Aviation Organization: Montreal, 1993).

  4. Development of Low-NOx Emission DME (Dimethyl Ether) Combustor

    NASA Astrophysics Data System (ADS)

    Matsumoto, Ryosuke; Ishihara, Isao; Ozawa, Mamoru; Imahori, Keizo

    This study focuses on fundamental characteristics of DME (Dimethyl Ether) combustion, aiming at the development of low-NOx combustion. DME is one of the most promising new alternative fuels owing to its cleanness of the exhaust gas and wide applications. Combustion experiments using a diffusion burner were conducted for characterizing DME through the comparison with the results of LPG and 13A-city gas. Experimental results demonstrated a high potential of DME for a boiler and a gas-turbine fuel. DME has a wide stable-combustion range compared with those of the other fuels. In this study, the concept of the low-NOx combustion, referred to as the tube-nested combustion, was applied to the DME combustion. This tube-nested combustor consists of tube banks to cool the burning flame leading to NOx reduction. Then, the NOx emission of the DME combustion was successfully reduced to a level suitable for practical applications.

  5. Aircraft Piston Engine Exhaust Emission Symposium

    NASA Technical Reports Server (NTRS)

    1976-01-01

    A 2-day symposium on the reduction of exhaust emissions from aircraft piston engines was held on September 14 and 15, 1976, at the Lewis Research Center in Cleveland, Ohio. Papers were presented by both government organizations and the general aviation industry on the status of government contracts, emission measurement problems, data reduction procedures, flight testing, and emission reduction techniques.

  6. The effect of incomplete fuel-air mixing on the lean blowout limit, lean stability limit and NO(x) emissions in lean premixed gas turbine combustors

    NASA Technical Reports Server (NTRS)

    Shih, W.-P.; Lee, J. G.; Santavicca, D. A.

    1994-01-01

    Gas turbine engines for both land-based and aircraft propulsion applications are facing regulations on NOx emissions which cannot be met with current combustor technology. A number of alternative combustor strategies are being investigated which have the potential capability of achieving ultra-low NOx emissions, including lean premixed combustors, direct injection combustors, rich burn-quick quench-lean burn combustors and catalytic combustors. The research reported in this paper addresses the effect of incomplete fuel-air mixing on the lean limit performance and the NOx emissions characteristics of lean premixed combustors.

  7. NOx Emissions from Oil and Gas Production in the North Sea

    NASA Astrophysics Data System (ADS)

    Lee, J. D.; Foulds, A.; Purvis, R.; Vaughan, A. R.; Carslaw, D.; Lewis, A. C.

    2015-12-01

    North Sea oil is a mixture of hydrocarbons, comprising liquid petroleum and natural gas, produced from petroleum reservoirs beneath the North Sea. As of January 2015, the North Sea is the world's most active offshore drilling region with 173 rigs drilling. During the summer of 2015, a series of survey flights took place on the UKs FAAM BAe 146 research aircraft with the primary aim to assess background methane (and other hydrocarbons) levels in the drilling areas of the North Sea. Also measured were Nitrogen Oxides (NO and NO2), which are emitted from almost all combustion processes and are a key air pollutant, both directly and as a precursor to ozone (O3). The oil and gas platforms in the North Sea are often manned and require significant power generation and support vessels for their continued operation, processes that potentially emit significant amounts of NOx into an otherwise relative clean environment. During these flights we were able to measure the NO­­­x (and any subsequently produced O3) emitted from specific rigs, as well as the NOx levels in the wider North Sea oil and gas production region (see figure for example). NOx mixing ratios of <10 ppbv were frequently observed in plumes, with significant perturbation to the wider North Sea background levels. NOx emissions from the rigs are point sources within the UKs National Atmospheric Emission Inventory (NAEI) and the measurements taken in plumes from individual rigs are used to assess the accuracy of these estimates.

  8. An Evaluation of Aircraft Emissions Inventory Methodology by Comparisons with Reported Airline Data

    NASA Technical Reports Server (NTRS)

    Daggett, D. L.; Sutkus, D. J.; DuBois, D. P.; Baughcum, S. L.

    1999-01-01

    This report provides results of work done to evaluate the calculation methodology used in generating aircraft emissions inventories. Results from the inventory calculation methodology are compared to actual fuel consumption data. Results are also presented that show the sensitivity of calculated emissions to aircraft payload factors. Comparisons of departures made, ground track miles flown and total fuel consumed by selected air carriers were made between U.S. Dept. of Transportation (DOT) Form 41 data reported for 1992 and results of simplified aircraft emissions inventory calculations. These comparisons provide an indication of the magnitude of error that may be present in aircraft emissions inventories. To determine some of the factors responsible for the errors quantified in the DOT Form 41 analysis, a comparative study of in-flight fuel flow data for a specific operator's 747-400 fleet was conducted. Fuel consumption differences between the studied aircraft and the inventory calculation results may be attributable to several factors. Among these are longer flight times, greater actual aircraft weight and performance deterioration effects for the in-service aircraft. Results of a parametric study on the variation in fuel use and NOx emissions as a function of aircraft payload for different aircraft types are also presented.

  9. Aircraft emissions, plume chemistry, and alternative fuels: results from the APEX, AAFEX, and MDW-2009 campaigns

    NASA Astrophysics Data System (ADS)

    Wood, E. C.; Herndon, S. C.; Timko, M.; Yu, Z.; Miake-Lye, R. C.; Lee, B. H.; Santoni, G.; Munger, J. W.; Wofsy, S.; Anderson, B.; Knighton, W. B.

    2009-12-01

    We describe observations of aircraft emissions from the APEX, JETS-APEX2, APEX3, MDW-2009 and AAFEX campaigns. Direct emissions of HOx precursors are important for understanding exhaust plume chemistry due to their role in determining HOx concentrations. Nitrous acid (HONO) and formaldehyde are crucial HOx precursors and thus drivers of plume chemistry. At idle power, aircraft engine exhaust is unique among fossil fuel combustion sources due to the speciation of both NOx and VOCs. The impacts of emissions of HOx precursors on plume chemistry at low power are demonstrated with empirical observations of rapid NO to NO2 conversion, indicative of rapid HOx chemistry. The impacts of alternative fuels (derived from biomass, coal, and natural gas) on emissions of NOx, CO, and speciated VOCs are discussed.

  10. 40 CFR 97.524 - Compliance with TR NOX Ozone Season emissions limitation.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 22 2013-07-01 2013-07-01 false Compliance with TR NOX Ozone Season... TR NOX Ozone Season Trading Program § 97.524 Compliance with TR NOX Ozone Season emissions limitation. (a) Availability for deduction for compliance. TR NOX Ozone Season allowances are available to...

  11. 40 CFR 97.524 - Compliance with TR NOX Ozone Season emissions limitation.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 22 2012-07-01 2012-07-01 false Compliance with TR NOX Ozone Season... TR NOX Ozone Season Trading Program § 97.524 Compliance with TR NOX Ozone Season emissions limitation. (a) Availability for deduction for compliance. TR NOX Ozone Season allowances are available to...

  12. 40 CFR 97.524 - Compliance with TR NOX Ozone Season emissions limitation.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 21 2014-07-01 2014-07-01 false Compliance with TR NOX Ozone Season... TR NOX Ozone Season Trading Program § 97.524 Compliance with TR NOX Ozone Season emissions limitation. (a) Availability for deduction for compliance. TR NOX Ozone Season allowances are available to...

  13. 40 CFR 96.154 - Compliance with CAIR NOX emissions limitation.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... IMPLEMENTATION PLANS CAIR NOX Allowance Tracking System § 96.154 Compliance with CAIR NOX emissions limitation... affect the liability of the owners and operators of the CAIR NOX source or the CAIR NOX units at the... submissions. (1) The Administrator may review and conduct independent audits concerning any submission...

  14. 40 CFR 96.154 - Compliance with CAIR NOX emissions limitation.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... IMPLEMENTATION PLANS CAIR NOX Allowance Tracking System § 96.154 Compliance with CAIR NOX emissions limitation... affect the liability of the owners and operators of the CAIR NOX source or the CAIR NOX units at the... submissions. (1) The Administrator may review and conduct independent audits concerning any submission...

  15. MENU OF NOX EMISSION CONTROL OPTIONS FOR COAL-FIRED ELECTRIC UTILITY BOILERS

    EPA Science Inventory

    The paper reviews NOx control options for coal-fired electric utility boilers. (NOTE: Acid Rain NOx regulations, the Ozone Transport Commission's NOx Budget Program, revision of the New Source Performance Standards (NSPS) for NOx emissions from utility sources, and Ozone Transpor...

  16. NOX EMISSION CONTROL OPTIONS FOR COAL-FIRED ELECTRIC UTILITY BOILERS

    EPA Science Inventory

    The paper reviews NOx control options for coal-fired electric utility boilers. (NOTE: Acid Rain NOx regulations, the Ozone Transport Commission's NOx Budget Program, revision of the New Source Performance Standards (NSPS) for NOx emissions from utility sources, and Ozone Transpor...

  17. Characteristics of NOx emission from Chinese coal-fired power plants equipped with new technologies

    NASA Astrophysics Data System (ADS)

    Ma, Zizhen; Deng, Jianguo; Li, Zhen; Li, Qing; Zhao, Ping; Wang, Liguo; Sun, Yezhu; Zheng, Hongxian; Pan, Li; Zhao, Shun; Jiang, Jingkun; Wang, Shuxiao; Duan, Lei

    2016-04-01

    Coal combustion in coal-fired power plants is one of the important anthropogenic NOx sources, especially in China. Many policies and methods aiming at reducing pollutants, such as increasing installed capacity and installing air pollution control devices (APCDs), especially selective catalytic reduction (SCR) units, could alter NOx emission characteristics (NOx concentration, NO2/NOx ratio, and NOx emission factor). This study reported the NOx characteristics of eight new coal-fired power-generating units with different boiler patterns, installed capacities, operating loads, and coal types. The results showed that larger units produced less NOx, and anthracite combustion generated more NOx than bitumite and lignite combustion. During formation, the NOx emission factors varied from 1.81 to 6.14 g/kg, much lower than those of older units at similar scales. This implies that NOx emissions of current and future units could be overestimated if they are based on outdated emission factors. In addition, APCDs, especially SCR, greatly decreased NOx emissions, but increased NO2/NOx ratios. Regardless, the NO2/NOx ratios were lower than 5%, in accordance with the guidelines and supporting the current method for calculating NOx emissions from coal-fired power plants that ignore NO2.

  18. 40 CFR 51.125 - Emissions reporting requirements for SIP revisions relating to budgets for SO2 and NOX emissions.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... SIP revisions relating to budgets for SO2 and NOX emissions. 51.125 Section 51.125 Protection of... SIP revisions relating to budgets for SO2 and NOX emissions. (a) For its transport SIP revision under § 51.123 and/or 51.124, each State must submit to EPA SO2 and/or NOX emissions data as described...

  19. 40 CFR 51.125 - Emissions reporting requirements for SIP revisions relating to budgets for SO2 and NOX emissions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... SIP revisions relating to budgets for SO2 and NOX emissions. 51.125 Section 51.125 Protection of... SIP revisions relating to budgets for SO2 and NOX emissions. (a) For its transport SIP revision under § 51.123 and/or 51.124, each State must submit to EPA SO2 and/or NOX emissions data as described...

  20. Optimization of NOx emissions in Yangtze Delta Region using in-situ observations

    NASA Astrophysics Data System (ADS)

    Wang, Hengmao; Jiang, Fei; Jiang, Ziqiang; Liu, Jane; Chen, Jing Ming; Ju, Weimin

    2016-04-01

    Well quantified NOx emissions are essential for air quality forecasting and air pollution mitigation. The traditional "bottom-up" estimates of NOx emissions, using activity data and emission factors, are subject to large uncertainties, especially in China. Inverse modelling, often referred to as "top-down" approach, using atmospheric observations made from satellites and ground stations, provides an effective means to optimize bottom-up NOx emission inventory. The rapid expansion of air quality monitoring network in China offers an opportunity to constrain NOx emissions using in-situ ground measurements. We explore the potential of using NO2 observations from the air quality monitoring network to improve NOx emissions estimates in China. The four dimensional variational data assimilation (4DVAR) scheme in the Community Multi-scale Air Quality (CMAQ) adjoint model is implemented to infer NOx emissions in Yangtze Delta Region at 12 km resolution. The optimized NOx emissions are presented. The uncertainly reduction of estimates is analyzed and discussed.

  1. Implications of diesel emissions control failures to emission factors and road transport NOx evolution

    NASA Astrophysics Data System (ADS)

    Ntziachristos, Leonidas; Papadimitriou, Giannis; Ligterink, Norbert; Hausberger, Stefan

    2016-09-01

    Diesel NOx emissions have been at the forefront of research and regulation scrutiny as a result of failures of late vehicle technologies to deliver on-road emissions reductions. The current study aims at identifying the actual emissions levels of late light duty vehicle technologies, including Euro 5 and Euro 6 ones. Mean NOx emission factor levels used in the most popular EU vehicle emission models (COPERT, HBEFA and VERSIT+) are compared with latest emission information collected in the laboratory over real-world driving cycles and on the road using portable emissions measurement systems (PEMS). The comparison shows that Euro 5 passenger car (PC) emission factors well reflect on road levels and that recently revealed emissions control failures do not call for any significant corrections. However Euro 5 light commercial vehicles (LCVs) and Euro 6 PCs in the 2014-2016 period exhibit on road emission levels twice as high as used in current models. Moreover, measured levels vary a lot for Euro 6 vehicles. Scenarios for future evolution of Euro 6 emission factors, reflecting different degree of effectiveness of emissions control regulations, show that total NOx emissions from diesel Euro 6 PC and LCV may correspond from 49% up to 83% of total road transport emissions in 2050. Unless upcoming and long term regulations make sure that light duty diesel NOx emissions are effectively addressed, this will have significant implications in meeting future air quality and national emissions ceilings targets.

  2. NOx Emissions from a Lobed Fuel Injector/Burner

    NASA Technical Reports Server (NTRS)

    Mitchell, M. G.; Smith, L. L.; Karagozian, A. R.; Smith, O. I.

    1996-01-01

    The present experimental study examines the performance of a novel fuel injector/burner configuration with respect to reduction in nitrogen oxide NOx emissions. The lobed injector/burner is a device in which very rapid initial mixing of reactants can occur through strong streamwise vorticity generation, producing high fluid mechanical strain rates which can delay ignition and thus prevent the formation of stoichiometric diffusion flames. Further downstream of the rapid mixing region. this flowfield produces a reduced effective strain rate, thus allowing ignition to occur in a premixed mode, where it is possible for combustion to take place under locally lean conditions. potentially reducing NOx emissions from the burner. The present experiments compare NO/NO2/NOx emissions from a lobed fuel injector configuration with emissions from a straight fuel injector to determine the net effect of streamwise vorticity generation. Preliminary results show that the lobed injector geometry can produce lean premixed flame structures. while for comparable flow conditions, a straight fuel injector geometry produces much longer. sooting diffusion flames or slightly rich pre-mixed flames. NO measurements show that emissions from a lobed fuel injector/burner can be made significantly lower than from a straight fuel injector under comparable flow conditions.

  3. On-Road Measurements of NO2 /NOx and NOx / CO Vehicle Emission Ratios in Colorado Summer Traffic

    NASA Astrophysics Data System (ADS)

    Wild, R. J.; Peischl, J.; Ryerson, T. B.; Neuman, J. A.; Dube, W. P.; Brown, S. S.

    2014-12-01

    Emissions of nitrogen oxides (NO and NO2) from vehicles are important precursors to ozone (O3) formation, and thus contribute to environmental and health issues. Both carbon dioxide (CO2) and carbon monoxide (CO) are large emissions from combustion, with the former a marker for total fuel consumption and the latter a commonly used combustion tracer. Thus, measurements of NOx to CO and CO2 emission ratios form an important part of characterizing total vehicle NOx emissions. Vehicle NOx emissions are primarily in the form of NO, although the NO2 content of these emissions may be changing as a result of control technology implementation, particularly for Diesel engines. Characterization of direct NO2 emission factors (i.e., NO2 to NOx ratio) is important because NO2 produces ozone upon its photolysis, while NO emission titrates ozone near sources. NO + O3 → NO2 + O2NO2 + hν (+ O2) → NO + O3Higher NO2 to NO emission ratios will likely result in higher ozone levels per unit NOx emitted. Higher NO2 emission ratios also lead to ozone production in closer proximity to the emission sources. There is a substantial lack of top-down measurements to assess emission inventories. Here we present an analysis of on-road measurements of vehicular emissions. We simultaneously measured NO, NO2 and O3 with a shared inlet at 20 pptv/s precision using a custom-built cavity ring-down measurement system in an instrumented van, together with high time resolution measurements of CO and CO2. Measurements were performed while driving throughout the Colorado Front Range urban area. We present a statistical analysis of vehicle plumes and their corresponding emissions ratios that can be used to constrain the direct emission ratio of NO2 in NOx, and NOx emission factors relative to CO and CO2.

  4. Scheduled Civil Aircraft Emission Inventories for 1999: Database Development and Analysis

    NASA Technical Reports Server (NTRS)

    Sutkus, Donald J., Jr.; Baughcum, Steven L.; DuBois, Douglas P.

    2001-01-01

    This report describes the development of a three-dimensional database of aircraft fuel burn and emissions (NO(x), CO, and hydrocarbons) for the scheduled commercial aircraft fleet for each month of 1999. Global totals of emissions and fuel burn for 1999 are compared to global totals from 1992 and 2015 databases. 1999 fuel burn, departure and distance totals for selected airlines are compared to data reported on DOT Form 41 to evaluate the accuracy of the calculations. DOT Form T-100 data were used to determine typical payloads for freighter aircraft and this information was used to model freighter aircraft more accurately by using more realistic payloads. Differences in the calculation methodology used to create the 1999 fuel burn and emissions database from the methodology used in previous work are described and evaluated.

  5. 40 CFR 75.12 - Specific provisions for monitoring NOX emission rate.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 17 2014-07-01 2014-07-01 false Specific provisions for monitoring NOX... provisions for monitoring NOX emission rate. (a) Coal-fired units, gas-fired nonpeaking units or oil-fired... for a NOX continuous emission monitoring system (CEMS) for each affected coal-fired unit,...

  6. 40 CFR 75.12 - Specific provisions for monitoring NOX emission rate.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 17 2013-07-01 2013-07-01 false Specific provisions for monitoring NOX... provisions for monitoring NOX emission rate. (a) Coal-fired units, gas-fired nonpeaking units or oil-fired... for a NOX continuous emission monitoring system (CEMS) for each affected coal-fired unit,...

  7. 40 CFR 75.12 - Specific provisions for monitoring NOX emission rate.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 17 2012-07-01 2012-07-01 false Specific provisions for monitoring NOX... provisions for monitoring NOX emission rate. (a) Coal-fired units, gas-fired nonpeaking units or oil-fired... for a NOX continuous emission monitoring system (CEMS) for each affected coal-fired unit,...

  8. 40 CFR 60.4380 - How are excess emissions and monitor downtime defined for NOX?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... downtime defined for NOX? 60.4380 Section 60.4380 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... downtime defined for NOX? For the purpose of reports required under § 60.7(c), periods of excess emissions... NOX control will also be considered an excess emission. (2) A period of monitor downtime is any...

  9. 40 CFR 60.4320 - What emission limits must I meet for nitrogen oxides (NOX)?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 7 2014-07-01 2014-07-01 false What emission limits must I meet for nitrogen oxides (NOX)? 60.4320 Section 60.4320 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... nitrogen oxides (NOX)? (a) You must meet the emission limits for NOX specified in Table 1 to this...

  10. 40 CFR 60.4320 - What emission limits must I meet for nitrogen oxides (NOX)?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false What emission limits must I meet for nitrogen oxides (NOX)? 60.4320 Section 60.4320 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... nitrogen oxides (NOX)? (a) You must meet the emission limits for NOX specified in Table 1 to this...

  11. 40 CFR 60.4320 - What emission limits must I meet for nitrogen oxides (NOX)?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 7 2012-07-01 2012-07-01 false What emission limits must I meet for nitrogen oxides (NOX)? 60.4320 Section 60.4320 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... nitrogen oxides (NOX)? (a) You must meet the emission limits for NOX specified in Table 1 to this...

  12. 40 CFR 60.4320 - What emission limits must I meet for nitrogen oxides (NOX)?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false What emission limits must I meet for nitrogen oxides (NOX)? 60.4320 Section 60.4320 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... nitrogen oxides (NOX)? (a) You must meet the emission limits for NOX specified in Table 1 to this...

  13. 40 CFR 60.4320 - What emission limits must I meet for nitrogen oxides (NOX)?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false What emission limits must I meet for nitrogen oxides (NOX)? 60.4320 Section 60.4320 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... nitrogen oxides (NOX)? (a) You must meet the emission limits for NOX specified in Table 1 to this...

  14. Inverse modeling of Texas NOx emissions using space-based and ground-based NO2 observations

    NASA Astrophysics Data System (ADS)

    Tang, W.; Cohan, D. S.; Lamsal, L. N.; Xiao, X.; Zhou, W.

    2013-11-01

    Inverse modeling of nitrogen oxide (NOx) emissions using satellite-based NO2 observations has become more prevalent in recent years, but has rarely been applied to regulatory modeling at regional scales. In this study, OMI satellite observations of NO2 column densities are used to conduct inverse modeling of NOx emission inventories for two Texas State Implementation Plan (SIP) modeling episodes. Addition of lightning, aircraft, and soil NOx emissions to the regulatory inventory narrowed but did not close the gap between modeled and satellite-observed NO2 over rural regions. Satellite-based top-down emission inventories are created with the regional Comprehensive Air Quality Model with extensions (CAMx) using two techniques: the direct scaling method and discrete Kalman filter (DKF) with decoupled direct method (DDM) sensitivity analysis. The simulations with satellite-inverted inventories are compared to the modeling results using the a priori inventory as well as an inventory created by a ground-level NO2-based DKF inversion. The DKF inversions yield conflicting results: the satellite-based inversion scales up the a priori NOx emissions in most regions by factors of 1.02 to 1.84, leading to 3-55% increase in modeled NO2 column densities and 1-7 ppb increase in ground 8 h ozone concentrations, while the ground-based inversion indicates the a priori NOx emissions should be scaled by factors of 0.34 to 0.57 in each region. However, none of the inversions improve the model performance in simulating aircraft-observed NO2 or ground-level ozone (O3) concentrations.

  15. Inverse modeling of Texas NOx emissions using space-based and ground-based NO2 observations

    NASA Astrophysics Data System (ADS)

    Tang, W.; Cohan, D.; Lamsal, L. N.; Xiao, X.; Zhou, W.

    2013-07-01

    Inverse modeling of nitrogen oxide (NOx) emissions using satellite-based NO2 observations has become more prevalent in recent years, but has rarely been applied to regulatory modeling at regional scales. In this study, OMI satellite observations of NO2 column densities are used to conduct inverse modeling of NOx emission inventories for two Texas State Implementation Plan (SIP) modeling episodes. Addition of lightning, aircraft, and soil NOx emissions to the regulatory inventory narrowed but did not close the gap between modeled and satellite observed NO2 over rural regions. Satellite-based top-down emission inventories are created with the regional Comprehensive Air Quality Model with extensions (CAMx) using two techniques: the direct scaling method and discrete Kalman filter (DKF) with Decoupled Direct Method (DDM) sensitivity analysis. The simulations with satellite-inverted inventories are compared to the modeling results using the a priori inventory as well as an inventory created by a ground-level NO2 based DKF inversion. The DKF inversions yield conflicting results: the satellite-based inversion scales up the a priori NOx emissions in most regions by factors of 1.02 to 1.84, leading to 3-55% increase in modeled NO2 column densities and 1-7 ppb increase in ground 8 h ozone concentrations, while the ground-based inversion indicates the a priori NOx emissions should be scaled by factors of 0.34 to 0.57 in each region. However, none of the inversions improve the model performance in simulating aircraft-observed NO2 or ground-level ozone (O3) concentrations.

  16. Inverse Modeling of Texas NOx Emissions Using Space-Based and Ground-Based NO2 Observations

    NASA Technical Reports Server (NTRS)

    Tang, Wei; Cohan, D.; Lamsal, L. N.; Xiao, X.; Zhou, W.

    2013-01-01

    Inverse modeling of nitrogen oxide (NOx) emissions using satellite-based NO2 observations has become more prevalent in recent years, but has rarely been applied to regulatory modeling at regional scales. In this study, OMI satellite observations of NO2 column densities are used to conduct inverse modeling of NOx emission inventories for two Texas State Implementation Plan (SIP) modeling episodes. Addition of lightning, aircraft, and soil NOx emissions to the regulatory inventory narrowed but did not close the gap between modeled and satellite observed NO2 over rural regions. Satellitebased top-down emission inventories are created with the regional Comprehensive Air Quality Model with extensions (CAMx) using two techniques: the direct scaling method and discrete Kalman filter (DKF) with Decoupled Direct Method (DDM) sensitivity analysis. The simulations with satellite-inverted inventories are compared to the modeling results using the a priori inventory as well as an inventory created by a ground-level NO2 based DKF inversion. The DKF inversions yield conflicting results: the satellite based inversion scales up the a priori NOx emissions in most regions by factors of 1.02 to 1.84, leading to 3-55% increase in modeled NO2 column densities and 1-7 ppb increase in ground 8 h ozone concentrations, while the ground-based inversion indicates the a priori NOx emissions should be scaled by factors of 0.34 to 0.57 in each region. However, none of the inversions improve the model performance in simulating aircraft-observed NO2 or ground-level ozone (O3) concentrations.

  17. CONTROLLING NOX EMISSION FROM INDUSTRIAL SOURCES

    EPA Science Inventory

    A number of regulatory actions focused on reducing NOx emissions from stationary combustion sources have been taken in the United States in the last decade. These actions include the Acid Rain NOx regulations, the Ozone Transport Commission's NOx ...

  18. Methodology for Airborne Quantification of NOx fluxes over Central London and Comparison to Emission Inventories

    NASA Astrophysics Data System (ADS)

    Vaughan, A. R.; Lee, J. D.; Lewis, A. C.; Purvis, R.; Carslaw, D.; Misztal, P. K.; Metzger, S.; Beevers, S.; Goldstein, A. H.; Hewitt, C. N.; Shaw, M.; Karl, T.; Davison, B.

    2015-12-01

    The emission of pollutants is a major problem in today's cities. Emission inventories are a key tool for air quality management, with the United Kingdom's National and London Atmospheric Emission Inventories (NAEI & LAEI) being good examples. Assessing the validity of such inventoried is important. Here we report on the technical methodology of matching flux measurements of NOx over a city to inventory estimates. We used an eddy covariance technique to directly measure NOx fluxes from central London on an aircraft flown at low altitude. NOx mixing ratios were measured at 10 Hz time resolution using chemiluminescence (to measure NO) and highly specific photolytic conversion of NO2 to NO (to measure NO2). Wavelet transformation was used to calculate instantaneous fluxes along the flight track for each flight leg. The transformation allows for both frequency and time information to be extracted from a signal, where we quantify the covariance between the de-trended vertical wind and concentration to derive a flux. Comparison between the calculated fluxes and emission inventory data was achieved using a footprint model, which accounts for contributing source. Using both a backwards lagrangian model and cross-wind dispersion function, we find the footprint extent ranges from 5 to 11 Km in distance from the sample point. We then calculate a relative weighting matrix for each emission inventory within the calculated footprint. The inventories are split into their contributing source sectors with each scaled using up to date emission factors, giving a month; day and hourly scaled estimate which is then compared to the measurement.

  19. 40 CFR 1037.102 - Exhaust emission standards for NOX, HC, PM, and CO.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... (CONTINUED) AIR POLLUTION CONTROLS CONTROL OF EMISSIONS FROM NEW HEAVY-DUTY MOTOR VEHICLES Emission Standards and Related Requirements § 1037.102 Exhaust emission standards for NOX, HC, PM, and CO. See 40 CFR... 40 Protection of Environment 33 2014-07-01 2014-07-01 false Exhaust emission standards for NOX,...

  20. 40 CFR 1037.102 - Exhaust emission standards for NOX, HC, PM, and CO.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... (CONTINUED) AIR POLLUTION CONTROLS CONTROL OF EMISSIONS FROM NEW HEAVY-DUTY MOTOR VEHICLES Emission Standards and Related Requirements § 1037.102 Exhaust emission standards for NOX, HC, PM, and CO. See 40 CFR... 40 Protection of Environment 34 2012-07-01 2012-07-01 false Exhaust emission standards for NOX,...

  1. 40 CFR 1037.102 - Exhaust emission standards for NOX, HC, PM, and CO.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... (CONTINUED) AIR POLLUTION CONTROLS CONTROL OF EMISSIONS FROM NEW HEAVY-DUTY MOTOR VEHICLES Emission Standards and Related Requirements § 1037.102 Exhaust emission standards for NOX, HC, PM, and CO. See 40 CFR... 40 Protection of Environment 34 2013-07-01 2013-07-01 false Exhaust emission standards for NOX,...

  2. High-speed Civil Transport Aircraft Emissions

    NASA Technical Reports Server (NTRS)

    Miake-Lye, Richard C.; Matulaitis, J. A.; Krause, F. H.; Dodds, Willard J.; Albers, Martin; Hourmouziadis, J.; Hasel, K. L.; Lohmann, R. P.; Stander, C.; Gerstle, John H.

    1992-01-01

    Estimates are given for the emissions from a proposed high speed civil transport (HSCT). This advanced technology supersonic aircraft would fly in the lower stratosphere at a speed of roughly Mach 1.6 to 3.2 (470 to 950 m/sec or 920 to 1850 knots). Because it would fly in the stratosphere at an altitude in the range of 15 to 23 km commensurate with its design speed, its exhaust effluents could perturb the chemical balance in the upper atmosphere. The first step in determining the nature and magnitude of any chemical changes in the atmosphere resulting from these proposed aircraft is to identify and quantify the chemically important species they emit. Relevant earlier work is summarized, dating back to the Climatic Impact Assessment Program of the early 1970s and current propulsion research efforts. Estimates are provided of the chemical composition of an HSCT's exhaust, and these emission indices are presented. Other aircraft emissions that are not due to combustion processes are also summarized; these emissions are found to be much smaller than the exhaust emissions. Future advances in propulsion technology, in experimental measurement techniques, and in understanding upper atmospheric chemistry may affect these estimates of the amounts of trace exhaust species or their relative importance.

  3. Aircraft Particle Emissions eXperiment (APEX)

    NASA Technical Reports Server (NTRS)

    Wey, C. C.; Anderson, B. E.; Hudgins, C.; Wey, C.; Li-Jones, X.; Winstead, E.; Thornhill, L. K.; Lobo, P.; Hagen, D.; Whitefield, P.

    2006-01-01

    APEX systematically investigated the gas-phase and particle emissions from a CFM56-2C1 engine on NASA's DC-8 aircraft as functions of engine power, fuel composition, and exhaust plumage. Emissions parameters were measured at 11 engine power, settings, ranging from idle to maximum thrust, in samples collected at 1, 10, and 30 m downstream of the exhaust plane as the aircraft burned three fuels to stress relevant chemistry. Gas-phase emission indices measured at 1 m were in good agreement with the ICAO data and predictions provided by GEAE empirical modeling tools. Soot particles emitted by the engine exhibited a log-normal size distribution peaked between 15 and 40 nm, depending on engine power. Samples collected 30 m downstream of the engine exhaust plane exhibited a prominent nucleation mode.

  4. Aircraft gas turbine low-power emissions reduction technology program

    NASA Technical Reports Server (NTRS)

    Dodds, W. J.; Gleason, C. C.; Bahr, D. W.

    1978-01-01

    Advanced aircraft turbine engine combustor technology was used to reduce low-power emissions of carbon monoxide and unburned hydrocarbons to levels significantly lower than those which were achieved with current technology. Three combustor design concepts, which were designated as the hot-wall liner concept, the recuperative-cooled liner concept, and the catalyst converter concept, were evaluated in a series of CF6-50 engine size 40 degree-sector combustor rig tests. Twenty-one configurations were tested at operating conditions spanning the design condition which was an inlet temperature and pressure of 422 K and 304 kPa, a reference velocity of 23 m/s and a fuel-air-ration of 10.5 g/kg. At the design condition typical of aircraft turbine engine ground idle operation, the best configurations of all three concepts met the stringent emission goals which were 10, 1, and 4 g/kg for CO, HC, and Nox, respectively.

  5. NOx Emission Reduction by Oscillating combustion

    SciTech Connect

    Institute of Gas Technology

    2004-01-30

    High-temperature, natural gas-fired furnaces, especially those fired with preheated air, produce large quantities of NO{sub x} per ton of material processed. Regulations on emissions from industrial furnaces are becoming increasingly more stringent. In addition, competition is forcing operators to make their furnaces more productive and/or efficient. Switching from preheated air to industrial oxygen can increase efficiency and reduce NO{sub x}, but oxygen is significantly more costly than air and may not be compatible with the material being heated. What was needed, and what was developed during this project, is a technology that reduces NO{sub x} emissions while increasing furnace efficiency for both air- and oxy-fired furnaces. Oscillating combustion is a retrofit technology that involves the forced oscillation of the fuel flow rate to a furnace. These oscillations create successive, fuel-rich and fuel-lean zones within the furnace. Heat transfer from the flame to the load increases due to the more luminous fuel-rich zones, a longer overall flame length, and the breakup of the thermal boundary layer. The increased heat transfer shortens heat up times, thereby increasing furnace productivity, and reduces the heat going up the stack, thereby increasing efficiency. The fuel-rich and fuel-lean zones also produce substantially less NO{sub x} than firing at a constant excess air level. The longer flames and higher heat transfer rate reduces overall peak flame temperature and thus reduces additional NO{sub x} formation from the eventual mixing of the zones and burnout of combustibles from the rich zones. This project involved the development of hardware to implement oscillating combustion on an industrial scale, the laboratory testing of oscillating combustion on various types of industrial burners, and the field testing of oscillating combustion on several types of industrial furnace. Before laboratory testing began, a market study was conducted, based on the

  6. NOx Emission Reduction by Oscillating Combustion

    SciTech Connect

    John C. Wagner

    2004-03-31

    High-temperature, natural gas-fired furnaces, especially those fired with preheated air, produce large quantities of NO{sub x} per ton of material processed. Regulations on emissions from industrial furnaces are becoming increasingly more stringent. In addition, competition is forcing operators to make their furnaces more productive and/or efficient. Switching from preheated air to industrial oxygen can increase efficiency and reduce NO{sub x}, but oxygen is significantly more costly than air and may not be compatible with the material being heated. What was needed, and what was developed during this project, is a technology that reduces NO{sub x} emissions while increasing furnace efficiency for both air- and oxy-fired furnaces. Oscillating combustion is a retrofit technology that involves the forced oscillation of the fuel flow rate to a furnace. These oscillations create successive, fuel-rich and fuel-lean zones within the furnace. Heat transfer from the flame to the load increases due to the more luminous fuel-rich zones, a longer overall flame length, and the breakup of the thermal boundary layer. The increased heat transfer shortens heat up times, thereby increasing furnace productivity, and reduces the heat going up the stack, thereby increasing efficiency. The fuel-rich and fuel-lean zones also produce substantially less NO{sub x} than firing at a constant excess air level. The longer flames and higher heat transfer rate reduces overall peak flame temperature and thus reduces additional NO{sub x} formation from the eventual mixing of the zones and burnout of combustibles from the rich zones. This project involved the development of hardware to implement oscillating combustion on an industrial scale, the laboratory testing of oscillating combustion on various types of industrial burners, and the field testing of oscillating combustion on several types of industrial furnace. Before laboratory testing began, a market study was conducted, based on the

  7. 40 CFR 75.19 - Optional SO2, NOX, and CO2 emissions calculation for low mass emissions (LME) units.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... emission test data that is representative of operation at normal load or historical data from a CEMS... historical emission test data that is representative of operation at normal load. The NOX emission limit... rate by conducting a four load NOX emission rate test procedure as specified in section 2.1 of...

  8. LOW NOx EMISSIONS IN A FUEL FLEXIBLE GAS TURBINE

    SciTech Connect

    Raymond Drnevich; James Meagher; Vasilis Papavassiliou; Troy Raybold; Peter Stuttaford; Leonard Switzer; Lee Rosen

    2004-08-01

    In alignment with Vision 21 goals, a study is presented here on the technical and economic potential for developing a gas turbine combustor that is capable of generating less that 2 ppm NOx emissions, firing on either coal synthesis gas or natural gas, and being implemented on new and existing systems. The proposed solution involves controlling the quantity of H2 contained in the fuel. The presence of H2 leads to increased flame stability such that the combustor can be operated at lower temperatures and produce less thermal NOx. Coal gas composition would be modified using a water gas shift converter, and natural gas units would implement a catalytic partial oxidation (CPOX) reactor to convert part of the natural gas feed to a syngas before fed back into the combustor. While both systems demonstrated technical merit, the economics involved in implementing such a system are marginal at best. Therefore, Praxair has decided not to pursue the technology any further at this time.

  9. High NO2/NOx emissions downstream of the catalytic diesel particulate filter: An influencing factor study.

    PubMed

    He, Chao; Li, Jiaqiang; Ma, Zhilei; Tan, Jianwei; Zhao, Longqing

    2015-09-01

    Diesel vehicles are responsible for most of the traffic-related nitrogen oxide (NOx) emissions, including nitric oxide (NO) and nitrogen dioxide (NO2). The use of after-treatment devices increases the risk of high NO2/NOx emissions from diesel engines. In order to investigate the factors influencing NO2/NOx emissions, an emission experiment was carried out on a high pressure common-rail, turbocharged diesel engine with a catalytic diesel particulate filter (CDPF). NO2 was measured by a non-dispersive ultraviolet analyzer with raw exhaust sampling. The experimental results show that the NO2/NOx ratios downstream of the CDPF range around 20%-83%, which are significantly higher than those upstream of the CDPF. The exhaust temperature is a decisive factor influencing the NO2/NOx emissions. The maximum NO2/NOx emission appears at the exhaust temperature of 350°C. The space velocity, engine-out PM/NOx ratio (mass based) and CO conversion ratio are secondary factors. At a constant exhaust temperature, the NO2/NOx emissions decreased with increasing space velocity and engine-out PM/NOx ratio. When the CO conversion ratios range from 80% to 90%, the NO2/NOx emissions remain at a high level.

  10. High NO2/NOx emissions downstream of the catalytic diesel particulate filter: An influencing factor study.

    PubMed

    He, Chao; Li, Jiaqiang; Ma, Zhilei; Tan, Jianwei; Zhao, Longqing

    2015-09-01

    Diesel vehicles are responsible for most of the traffic-related nitrogen oxide (NOx) emissions, including nitric oxide (NO) and nitrogen dioxide (NO2). The use of after-treatment devices increases the risk of high NO2/NOx emissions from diesel engines. In order to investigate the factors influencing NO2/NOx emissions, an emission experiment was carried out on a high pressure common-rail, turbocharged diesel engine with a catalytic diesel particulate filter (CDPF). NO2 was measured by a non-dispersive ultraviolet analyzer with raw exhaust sampling. The experimental results show that the NO2/NOx ratios downstream of the CDPF range around 20%-83%, which are significantly higher than those upstream of the CDPF. The exhaust temperature is a decisive factor influencing the NO2/NOx emissions. The maximum NO2/NOx emission appears at the exhaust temperature of 350°C. The space velocity, engine-out PM/NOx ratio (mass based) and CO conversion ratio are secondary factors. At a constant exhaust temperature, the NO2/NOx emissions decreased with increasing space velocity and engine-out PM/NOx ratio. When the CO conversion ratios range from 80% to 90%, the NO2/NOx emissions remain at a high level. PMID:26354692

  11. 40 CFR 96.354 - Compliance with CAIR NOX emissions limitation.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Tracking System § 96.354 Compliance with CAIR NOX emissions... under paragraph (d)(1) of this section shall not affect the liability of the owners and operators of the... Administrator may review and conduct independent audits concerning any submission under the CAIR NOX...

  12. CONTROL OF NOX EMISSIONS FROM U.S. COAL-FIRED ELECTRIC UTILITY BOILERS

    EPA Science Inventory

    The paper discusses the control of nitrogen oxide (NOx) emissions from U.S. coal-fired electric utility boilers. (NOTE: In general, NOx control technologies are categorized as being either primary or secondary control technologies. Primary technologies reduce the amount of NOx pr...

  13. Jet aircraft emissions during cruise: Present and future

    NASA Technical Reports Server (NTRS)

    Grobman, J. S.

    1975-01-01

    Forecasts of engine exhaust emissions that may be practicably achievable for future commercial aircraft operating at high altitude cruise conditions are compared to cruise emission for present day aircraft. The forecasts are based on: (1) knowledge of emission characteristics of combustors and augmentors; (2) combustion research in emission reduction technology, and (3) trends in projected engine designs for advanced subsonic or supersonic commercial aircraft. Recent progress that was made in the evolution of emissions reduction technology is discussed.

  14. 40 CFR 76.6 - NOX emission limitations for Group 2 boilers.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.6 NOX emission limitations..., the date on which the unit is required to meet Acid Rain emission reduction requirements for SO2,...

  15. 40 CFR 76.6 - NOX emission limitations for Group 2 boilers.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.6 NOX emission limitations..., the date on which the unit is required to meet Acid Rain emission reduction requirements for SO2,...

  16. 40 CFR 76.6 - NOX emission limitations for Group 2 boilers.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.6 NOX emission limitations..., the date on which the unit is required to meet Acid Rain emission reduction requirements for SO2,...

  17. 40 CFR 76.6 - NOX emission limitations for Group 2 boilers.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.6 NOX emission limitations..., the date on which the unit is required to meet Acid Rain emission reduction requirements for SO2,...

  18. 40 CFR 76.6 - NOX emission limitations for Group 2 boilers.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.6 NOX emission limitations..., the date on which the unit is required to meet Acid Rain emission reduction requirements for SO2,...

  19. Aircraft hydrocarbon emissions at Oakland International Airport.

    PubMed

    Herndon, Scott C; Wood, Ezra C; Northway, Megan J; Miake-Lye, Richard; Thornhill, Lee; Beyersdorf, Andreas; Anderson, Bruce E; Dowlin, Renee; Dodds, Willard; Knighton, W Berk

    2009-03-15

    To help airports improve emission inventory data, speciated hydrocarbon emission indices have been measured from in-use commercial, airfreight, and general aviation aircraft at Oakland International Airport. The compounds reported here include formaldehyde, acetaldehyde, ethene, propene, and benzene. At idle, the magnitude of hydrocarbon emission indices was variable and reflected differences in engine technology, actual throttle setting, and ambient temperature. Scaling the measured emission indices to the simultaneously measured formaldehyde (HCHO) emission index eliminated most of the observed variability. This result supports a uniform hydrocarbon emissions profile across engine types when the engine is operating near idle, which can greatly simplify how speciated hydrocarbons are handled in emission inventories. The magnitude of the measured hydrocarbon emission index observed in these measurements (ambient temperature range 12-22 degrees C) is a factor of 1.5-2.2 times larger than the certification benchmarks. Using estimates of operational fuel flow rates at idle, this analysis suggests that current emission inventories at the temperatures encountered at this airport underestimate hydrocarbon emissions from the idle phase of operation by 16-45%.

  20. A plume capture technique for the remote characterization of aircraft engine emissions.

    PubMed

    Johnson, G R; Mazaheri, M; Ristovski, Z D; Morawska, L

    2008-07-01

    A technique for capturing and analyzing plumes from unmodified aircraft or other combustion sources under real world conditions is described and applied to the task of characterizing plumes from commercial aircraft during the taxiing phase of the Landing/Take-Off (LTO) cycle. The method utilizes a Plume Capture and Analysis System (PCAS) mounted in a four-wheel drive vehicle which is positioned in the airfield 60 to 180 m downwind of aircraft operations. The approach offers low test turnaround times with the ability to complete careful measurements of particle and gaseous emission factors and sequentially scanned particle size distributions without distortion due to plume concentration fluctuations. These measurements can be performed for individual aircraft movements at five minute intervals. A Plume Capture Device (PCD) collected samples of the naturally diluted plume in a 200 L conductive membrane conforming to a defined shape. Samples from over 60 aircraft movements were collected and analyzed in situ for particulate and gaseous concentrations and for particle size distribution using a Scanning Particle Mobility Sizer (SMPS). Emission factors are derived for particle number, NO(x), and PM2.5 for a widely used commercial aircraft type, Boeing 737 airframes with predominantly CFM56 class engines, during taxiing. The practical advantages of the PCAS include the capacity to perform well targeted and controlled emission factor and size distribution measurements using instrumentation with varying response times within an airport facility, in close proximity to aircraft during their normal operations.

  1. Wide range operation of advanced low NOx combustors for supersonic high-altitude aircraft gas turbines

    NASA Technical Reports Server (NTRS)

    Roberts, P. B.; Fiorito, R. J.

    1977-01-01

    An initial rig program tested the Jet Induced Circulation (JIC) and Vortex Air Blast (VAB) systems in small can combustor configurations for NOx emissions at a simulated high altitude, supersonic cruise condition. The VAB combustor demonstrated the capability of meeting the NOx goal of 1.0 g NO2/kg fuel at the cruise condition. In addition, the program served to demonstrate the limited low-emissions range available from the lean, premixed combustor. A follow-on effort was concerned with the problem of operating these lean, premixed combustors with acceptable emissions at simulated engine idle conditions. Various techniques have been demonstrated that allow satisfactory operation on both the JIC and VAB combustors at idle with CO emissions below 20 g/kg fuel. The VAB combustor was limited by flashback/autoignition phenomena at the cruise conditions to a pressure of 8 atmospheres. The JIC combustor was operated up to the full design cruise pressure of 14 atmospheres without encountering an autoignition limitation although the NOx levels, in the 2-3 g NO2/kg fuel range, exceeded the program goal.

  2. Impact of Aircraft Emissions on Reactive Nitrogen over the North Atlantic Flight Corridor Region

    NASA Technical Reports Server (NTRS)

    Koike, M.; Kondo, Y.; Ikeda, H.; Gregory, G. L.; Anderson, B. E.; Sachse, G. W.; Blake, D.; Liu, S. C.; Singh, H. B.; Thompson, A.

    1999-01-01

    The impact of aircraft emissions on reactive nitrogen in the upper troposphere (UT) and lowermost stratosphere (LS) was estimated using the NO(y)-O3 correlation obtained during the SASS Ozone and NO(x) Experiment (SONEX) carried out over the US continent and North Atlantic Flight Corridor (NAFC) region in October and November 1997. To evaluate the large scale impact, we made a reference NO(y)-O3 relationship in air masses, upon which aircraft emissions were considered to have little impact. For this purpose, the integrated input of NO(x) from aircraft into an air mass along a 10-d back trajectory (DELTA-NO(y)) was calculated based on the ANCAT/EC2 emission inventory. The excess NO(y) (dNO(y)) was calculated from the observed NO(y) and the reference NO(y)-O3 relationship. As a result, a weak positive correlation was found between the dNO(y) and DELTA-NO(y), and dNO(y) and NO(x)/NO(y) values, while no positive correlation between the dNO(y) and CO values was found, suggesting that dNO(y) values can be used as a measure of the NO(x) input from aircraft emissions. The excess NO(y) values calculated from another NO(y)-O3 reference relationship made using in-situ CN data also agreed with these dNO(y) values, within the uncertainties. At the NAFC region (45 N - 60 N), the median value of dNO(y) in the troposphere increased with altitude above 9 km and reached 70 pptv (20% of NO(y)) at 11 km. The excess NO(x) was estimated to be about half of the dNO(y) values, corresponding to 30% of the observed NO(x) level. Higher dNO(y) values were generally found in air masses where O3 = 75 - 125 ppbv, suggesting a more pronounced effect around the tropopause. The median value of dNO(y) in the stratosphere at the NAFC region at 8.5 - 11.5 km was about 120 pptv. The higher dNO(y) values in the LS were probably due to the accumulated effect of aircraft emissions, given the long residence time of affected air in the LS. Similar dNO(y) values were also obtained in air masses sampled over

  3. Three-Dimensional Composite Nanostructures for Lean NOx Emission Control

    SciTech Connect

    Gao, Pu-Xian

    2013-07-31

    This final report to the Department of Energy (DOE) and National Energy Technology Laboratory (NETL) for DE-EE0000210 covers the period from October 1, 2009 to July 31, 2013. Under this project, DOE awarded UConn about $1,248,242 to conduct the research and development on a new class of 3D composite nanostructure based catalysts for lean NOx emission control. Much of the material presented here has already been submitted to DOE/NETL in quarterly technical reports. In this project, through a scalable solution process, we have successfully fabricated a new class of catalytic reactors, i.e., the composite nanostructure array (nano-array) based catalytic converters. These nanocatalysts, distinct from traditional powder washcoat based catalytic converters, directly integrate monolithic substrates together with nanostructures with well-defined size and shape during the scalable hydrothermal process. The new monolithic nanocatalysts are demonstrated to be able to save raw materials including Pt-group metals and support metal oxides by an order of magnitude, while perform well at various oxidation (e.g., CO oxidation and NO oxidation) and reduction reactions (H{sub 2} reduction of NOx) involved in the lean NOx emissions. The size, shape and arrangement of the composite nanostructures within the monolithic substrates are found to be the key in enabling the drastically reduced materials usage while maintaining the good catalytic reactivity in the enabled devices. The further understanding of the reaction kinetics associated with the unique mass transport and surface chemistry behind is needed for further optimizing the design and fabrication of good nanostructure array based catalytic converters. On the other hand, the high temperature stability, hydrothermal aging stability, as well as S-poisoning resistance have been investigated in this project on the nanocatalysts, which revealed promising results toward good chemical and mechanical robustness, as well as S

  4. Evaluations of NOx and highly reactive VOC emission inventories in Texas and their implications for ozone plume simulations during the Texas Air Quality Study 2006

    NASA Astrophysics Data System (ADS)

    Kim, S.-W.; McKeen, S. A.; Frost, G. J.; Lee, S.-H.; Trainer, M.; Richter, A.; Angevine, W. M.; Atlas, E.; Bianco, L.; Boersma, F. K.; Brioude, J.; Burrows, J. P.; de Gouw, J.; Fried, A.; Gleason, J.; Hilboll, A.; Mellqvist, J.; Peischl, J.; Richter, D.; Rivera, C.; Ryerson, T.; Te Lintel Hekkert, S.; Walega, J.; Warneke, C.; Weibring, P.; Williams, E.

    2011-07-01

    Satellite and aircraft observations made during the 2006 Texas Air Quality Study (TexAQS) detected strong urban, industrial and power plant plumes in Texas. We simulated these plumes using the Weather Research and Forecasting - Chemistry (WRF-Chem) model with input from the US EPA's 2005 National Emission Inventory (NEI-2005), in order to evaluate emissions of nitrogen oxides (NOx = NO + NO2) and volatile organic compounds (VOCs) in the cities of Houston and Dallas-Fort Worth. We compared the model results with satellite retrievals of tropospheric nitrogen dioxide (NO2) columns and airborne in-situ observations of several trace gases including NOx and a number of VOCs. The model and satellite NO2 columns agree well for regions with large power plants and for urban areas that are dominated by mobile sources, such as Dallas. However, in Houston, where significant mobile, industrial, and in-port marine vessel sources contribute to NOx emissions, the model NO2 columns are approximately 50 %-70 % higher than the satellite columns. Similar conclusions are drawn from comparisons of the model results with the TexAQS 2006 aircraft observations in Dallas and Houston. For Dallas plumes, the model-simulated NO2 showed good agreement with the aircraft observations. In contrast, the model-simulated NO2 is ~60 % higher than the aircraft observations in the Houston plumes. Further analysis indicates that the NEI-2005 NOx emissions over the Houston Ship Channel area are overestimated while the urban Houston NOx emissions are reasonably represented. The comparisons of model and aircraft observations confirm that highly reactive VOC emissions originating from industrial sources in Houston are underestimated in NEI-2005. The update of VOC emissions based on Solar Occultation Flux measurements during the field campaign leads to improved model simulations of ethylene, propylene, and formaldehyde. Reducing NOx emissions in the Houston Ship Channel and increasing highly reactive VOC

  5. Evaluations of NOx and highly reactive VOC emission inventories in Texas and their implications for ozone plume simulations during the Texas Air Quality Study 2006

    NASA Astrophysics Data System (ADS)

    Kim, S.-W.; McKeen, S. A.; Frost, G. J.; Lee, S.-H.; Trainer, M.; Richter, A.; Angevine, W. M.; Atlas, E.; Bianco, L.; Boersma, K. F.; Brioude, J.; Burrows, J. P.; de Gouw, J.; Fried, A.; Gleason, J.; Hilboll, A.; Mellqvist, J.; Peischl, J.; Richter, D.; Rivera, C.; Ryerson, T.; Te Lintel Hekkert, S.; Walega, J.; Warneke, C.; Weibring, P.; Williams, E.

    2011-11-01

    Satellite and aircraft observations made during the 2006 Texas Air Quality Study (TexAQS) detected strong urban, industrial and power plant plumes in Texas. We simulated these plumes using the Weather Research and Forecasting-Chemistry (WRF-Chem) model with input from the US EPA's 2005 National Emission Inventory (NEI-2005), in order to evaluate emissions of nitrogen oxides (NOx = NO + NO2) and volatile organic compounds (VOCs) in the cities of Houston and Dallas-Fort Worth. We compared the model results with satellite retrievals of tropospheric nitrogen dioxide (NO2) columns and airborne in-situ observations of several trace gases including NOx and a number of VOCs. The model and satellite NO2 columns agree well for regions with large power plants and for urban areas that are dominated by mobile sources, such as Dallas. However, in Houston, where significant mobile, industrial, and in-port marine vessel sources contribute to NOx emissions, the model NO2 columns are approximately 50%-70% higher than the satellite columns. Similar conclusions are drawn from comparisons of the model results with the TexAQS 2006 aircraft observations in Dallas and Houston. For Dallas plumes, the model-simulated NO2 showed good agreement with the aircraft observations. In contrast, the model-simulated NO2 is ~60% higher than the aircraft observations in the Houston plumes. Further analysis indicates that the NEI-2005 NOx emissions over the Houston Ship Channel area are overestimated while the urban Houston NOx emissions are reasonably represented. The comparisons of model and aircraft observations confirm that highly reactive VOC emissions originating from industrial sources in Houston are underestimated in NEI-2005. The update of VOC emissions based on Solar Occultation Flux measurements during the field campaign leads to improved model simulations of ethylene, propylene, and formaldehyde. Reducing NOx emissions in the Houston Ship Channel and increasing highly reactive VOC emissions

  6. 40 CFR 75.72 - Determination of NOX mass emissions for common stack and multiple stack configurations.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 17 2014-07-01 2014-07-01 false Determination of NOX mass emissions... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING NOX Mass Emissions Provisions § 75.72 Determination of NOX mass emissions for common stack and multiple...

  7. 40 CFR 75.72 - Determination of NOX mass emissions for common stack and multiple stack configurations.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 17 2013-07-01 2013-07-01 false Determination of NOX mass emissions... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING NOX Mass Emissions Provisions § 75.72 Determination of NOX mass emissions for common stack and multiple...

  8. 40 CFR 75.72 - Determination of NOX mass emissions for common stack and multiple stack configurations.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 16 2011-07-01 2011-07-01 false Determination of NOX mass emissions... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING NOX Mass Emissions Provisions § 75.72 Determination of NOX mass emissions for common stack and multiple...

  9. Spatio-temporal variability in isotopic signatures of atmospheric NOx emissions from vehicles

    NASA Astrophysics Data System (ADS)

    Miller, D. J.; Wojtal, P.; O'Connor, M.; Clark, S.; Hastings, M. G.

    2015-12-01

    Atmospheric nitrogen oxides (NOx = NO + NO2) play key roles in atmospheric chemistry and radiative forcing. Their oxidation products, nitric acid or nitrate, have significant contributions to nitrogen (N) deposition, with implications for ecosystem health. On-road vehicle NOx sources currently dominate U.S. anthropogenic emission budgets, yet vehicle NOx emissions contributions to local and regional N deposition patterns are highly uncertain. NOx isotopic signatures offer a potentially valuable observational tool to trace source contributions to N deposition. We characterize the spatio-temporal variability of vehicle NOx emission isotopic signatures with a field and laboratory-verified technique for actively capturing NOx in solution to quantify the nitrogen isotopic composition (δ15N-NOx) to within ±1.5‰ (1σ) precision. We present a novel combination of on-road mobile and stationary urban δ15N-NOx measurements at minutes to hourly resolution along with NOx and CO2 concentration measurements. We evaluate spatial gradients of δ15N-NOx on U.S. Northeast and Midwest highways, including six urban metropolitan areas and rural interstate highways during summer and autumn. We also assess on-road diurnal δ15N-NOx variations over ~800 km driving distance in Providence, RI by targeting the upwind footprint of urban background measurements to distinguish background and source NOx. We observe on-road δ15N-NOx signatures range from -3 to -10‰ under different traffic conditions in the U.S. Northeast and Midwest. On-road δ15N-NOx daytime variations from -3 to -6‰ agree well with simultaneous urban background sampling in Providence, RI, suggesting that vehicles dominate NOx emissions in this region. We use these datasets to estimate the range of representative δ15N-NOx source signatures for U.S. vehicle fleet-integrated emission plumes. Our novel approach suggests that previously reported isotopic signatures for vehicle NOx are not necessarily representative. These

  10. Origin of Ozone NO(x) in the Tropical Troposphere: A Photochemical Analysis of Aircraft Observations Over the South Atlantic Basin

    NASA Technical Reports Server (NTRS)

    Jacob, D. J.; Heikes, B. G.; Fan, S.-M.; Logan, J. A.; Mauzerall, D. L.; Bradshaw, J. D.; Singh, H. B.; Gregory, G. L.; Talbot, R. W.; Blake, D. R.; Sachse, G. W.

    1996-01-01

    The photochemistry of the troposphere over the South Atlantic basin is examined by modeling of aircraft observations up to 12-km altitude taken during the TRACE A expedition in September-October 1992. A close balance is found in the 0 to 12-km column between photochemical production and loss Of O3, with net production at high altitudes compensating for weak net loss at low altitudes. This balance implies that O3 concentrations in the 0-12 km column can be explained solely by in situ photochemistry; influx from the stratosphere is negligible. Simulation of H2O2, CH3OOH, and CH2O concentrations measured aboard the aircraft lends confidence in the computations of O3 production and loss rates, although there appears to be a major gap in current understanding of CH2O chemistry in the marine boundary layer. The primary sources of NO(x) over the South Atlantic Basin appear to be continental (biomass burning, lightning, soils). There is evidence that NO(x) throughout the 0 to 12-km column is recycled from its oxidation products rather than directly transported from its primary sources. There is also evidence for rapid conversion of HNO3 to NO(x) in the upper troposphere by a mechanism not included in current models. A general representation of the O3 budget in the tropical troposphere is proposed that couples the large scale Walker circulation and in situ photochemistry. Deep convection in the rising branches of the Walker circulation injects NO(x) from combustion, soils, and lightning to the upper troposphere, leading to O3 production; eventually, the air subsides and net O3 loss takes place in the lower troposphere, closing the O3 cycle. This scheme implies a great sensitivity of the oxidizing power of the atmosphere to NO(x) emissions in the tropics.

  11. 40 CFR 51.122 - Emissions reporting requirements for SIP revisions relating to budgets for NOX emissions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... reporting requirements of 40 CFR part 75, then the state need not provide an every-year cycle report to EPA... SIP revisions relating to budgets for NOX emissions. 51.122 Section 51.122 Protection of Environment... relating to budgets for NOX emissions. (a) As used in this section, words and terms shall have the...

  12. 40 CFR 75.19 - Optional SO2, NOX, and CO2 emissions calculation for low mass emissions (LME) units.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... for units equipped with SCR or SNCR), or, consistent with paragraph (c)(1)(iv)(C)(4) of this section, for a unit that uses SCR or SNCR to control NOX emissions, an estimated default NOX emission rate of 0... units that use selective catalytic reduction (SCR) or selective non-catalytic reduction (SNCR)...

  13. NOx Emissions Performance and Correlation Equations for a Multipoint LDI Injector

    NASA Technical Reports Server (NTRS)

    He, Zhuohui J.; Chang, Clarence T.; Follen, Caitlin E.

    2014-01-01

    Lean Direct Injection (LDI) is a combustor concept that reduces nitrogen oxides (NOx) emissions. This paper looks at a 3-zone multipoint LDI concept developed by Parker Hannifin Corporation. The concept was tested in a flame-tube test facility at NASA Glenn Research Center. Due to test facility limitations, such as inlet air temperature and pressure, the flame-tube test was not able to cover the full set of engine operation conditions. Three NOx correlation equations were developed based on assessing NOx emissions dependencies on inlet air pressure (P3), inlet air temperature (T3), and fuel air equivalence ratio (?) to estimate the NOx emissions at the unreachable high engine power conditions. As the results, the NOx emissions are found to be a strong function of combustion inlet air temperature and fuel air equivalence ratio but a weaker function of inlet air pressure. With these three equations, the NOx emissions performance of this injector concept is calculated as a 66 percent reduction relative to the ICAO CAEP-6 standard using a 55:1 pressure-ratio engine cycle. Uncertainty in the NOx emissions estimation increases as the extrapolation range departs from the experimental conditions. Since maximum inlet air pressure tested was less than 50 percent of the full power engine inlet air pressure, a future experiment at higher inlet air pressure conditions is needed to confirm the NOx emissions dependency on inlet air pressure.

  14. NOx Emissions Performance and Correlation Equations for a Multipoint LDI Injector

    NASA Technical Reports Server (NTRS)

    He, Zhuohui J.; Chang, Clarence T.; Follen, Caitlin E.

    2014-01-01

    Lean Direct Injection (LDI) is a combustor concept that reduces nitrogen oxides (NOx) emissions. This paper looks at a 3-zone multipoint LDI concept developed by Parker Hannifin Corporation. The concept was tested in a flame-tube test facility at NASA Glenn Research Center. Due to test facility limitations, such as inlet air temperature and pressure, the flame-tube test was not able to cover the full set of engine operation conditions. Three NOx correlation equations were developed based on assessing NOx emissions dependencies on inlet air pressure (P3), inlet air temperature (T3), and fuel air equivalence ratio (phi) to estimate the NOx emissions at the unreachable high engine power conditions. As the results, the NOx emissions are found to be a strong function of combustion inlet air temperature and fuel air equivalence ratio but a weaker function of inlet air pressure. With these three equations, the NOx emissions performance of this injector concept is calculated as a 66 percent reduction relative to the ICAO CAEP-6 standard using a 55:1 pressure-ratio engine cycle. Uncertainty in the NOx emissions estimation increases as the extrapolation range departs from the experimental conditions. Since maximum inlet air pressure tested was less than 50 percent of the full power engine inlet air pressure, a future experiment at higher inlet air pressure conditions is needed to confirm the NOx emissions dependency on inlet air pressure.

  15. NOx Emissions Performance and Correlation Equations for a Multipoint LDI Injector

    NASA Technical Reports Server (NTRS)

    He, Zhuohui Joe; Chang, Clarence T.; Follen, Caitlin E.

    2015-01-01

    Lean Direct Injection (LDI) is a combustor concept that reduces nitrogen oxides (NOx) emissions.This paper looks at a 3-zone multipoint LDI concept developed by Parker Hannifin Corporation. The concept was tested in a flame-tube test facility at NASA Glenn Research Center. Due to test facility limitations, such as inlet air temperature and pressure, the flame-tube test was not able to cover the full set of engine operation conditions. Three NOx correlation equations were developed based on assessing NOx emissions dependencies on inlet air pressure (P3), inlet air temperature (T3), and fuel air equivalence ratio(theta) to estimate the NOx emissions at the unreachable high engine power conditions. As the results, the NOx emissions are found to be a strong function of combustion inlet air temperature and fuel air equivalence ratio but a weaker function of inlet air pressure. With these three equations, the NOx emissions performance of this injector concept is calculated as a 66 reduction relative to the ICAO CAEP-6 standard using a 55:1 pressure-ratio engine cycle. Uncertainty in the NOx emissions estimation increases as the extrapolation range departs from the experimental conditions. Since maximum inlet air pressure tested was less than 50 of the full power engine inlet air pressure, a future experiment at higher inlet air pressure conditions is needed to confirm the NOx emissions dependency on inlet air pressure.

  16. NOx Emissions Performance and Correlation Equations for a Multipoint LDI Injector

    NASA Technical Reports Server (NTRS)

    He, Zhuohui J.; Chang, Clarence T.; Follen, Caitlin E.

    2015-01-01

    Lean Direct Injection (LDI) is a combustor concept that reduces nitrogen oxides (NOx) emissions. This paper looks at a 3-zone multipoint LDI concept developed by Parker Hannifin Corporation. The concept was tested in a flame-tube test facility at NASA Glenn Research Center. Due to test facility limitations, such as inlet air temperature and pressure, the flame-tube test was not able to cover the full set of engine operation conditions. Three NOx correlation equations were developed based on assessing NOx emissions dependencies on inlet air pressure (P3), inlet air temperature (T3), and fuel air equivalence ratio (?) to estimate the NOx emissions at the unreachable high engine power conditions. As the results, the NOx emissions are found to be a strong function of combustion inlet air temperature and fuel air equivalence ratio but a weaker function of inlet air pressure. With these three equations, the NOx emissions performance of this injector concept is calculated as a 66% reduction relative to the ICAO CAEP-6 standard using a 55:1 pressure-ratio engine cycle. Uncertainty in the NOx emissions estimation increases as the extrapolation range departs from the experimental conditions. Since maximum inlet air pressure tested was less than 50% of the full power engine inlet air pressure, a future experiment at higher inlet air pressure conditions is needed to confirm the NOx emissions dependency on inlet air pressure.

  17. Probing Emissions of Military Cargo Aircraft: Description of a Joint Field Measurement Program

    SciTech Connect

    Cheng, Mengdawn; Corporan, E.; DeWitt, M.; Spicer, C.; Holdren, M.; Cowen, K.; Harris, B.; Shores, R.; Hashmonay, R.; Kaganan, R.

    2008-01-01

    Direct emissions of NOx, volatile organic compounds, and particulate matter (PM) by aircraft contribute to the pollutant levels found in the atmosphere. Aircraft emissions can be injected at the ground level or directly at the high altitude in flight. Conversion of the precursor gases into secondary PM is one of the pathways for the increased atmospheric PM. Atmospheric PM interacts with solar radiation altering atmospheric radiation balance and potentially contributing to global and regional climate changes. Also, direct emissions of air toxics, ozone precursors and PM from aircraft in and around civilian airports and military air bases can worsen local air quality in non-attainment and/or maintenance areas. These emissions need to be quantified. However, the current EPA methods for particle emission measurements from such sources, modified Method 5 and Conditional Test Method 039, are gravimetric-based, and it is anticipated that these methods will not be suitable for current and future generations of aircraft turbine engines, whose particle mass emissions are low. To evaluate measurement approaches for military aircraft emissions, two complementary projects were initiated in 2005. A joint field campaign between these two programs was executed during the first week of October 2005 at the Kentucky Air National Guard (KYANG) base in Louisville, KY. This campaign represented the first in a series of field studies for each program funded by the DoD Strategic Environmental Research and Development Program (SERDP) and provided the basis for cross-comparison of the sampling approaches and measurement techniques employed by the respective program teams. This paper describes the overall programmatic of the multi-year SERDP aircraft emissions research and presents a summary of the results from the joint field campaign.

  18. Aircraft Emission Inventories Projected in Year 2015 for a High Speed Civil Transport (HSCT) Universal Airline Network. Final report

    SciTech Connect

    Baughcum, S.L.; Henderson, S.C.

    1995-07-01

    This report describes the development of a three-dimensional database of aircraft fuel burn and emissions (fuel burned, NOx, CO, and hydrocarbons) from projected fleets of high speed civil transports (HSCT`s) on a universal airline network. Inventories for 500 and 1000 HSCT fleets, as well as the concurrent subsonic fleets, were calculated. The objective of this work was to evaluate the changes in geographical distribution of the HSCT emissions as the fleet size grew from 500 to 1000 HSCT`s. For this work, a new expanded HSCT network was used and flights projected using a market penetration analysis rather than assuming equal penetration as was done in the earlier studies. Emission inventories on this network were calculated for both Mach 2.0 and Mach 2.4 HSCT fleets with NOx cruise emission indices of approximately 5 and 15 grams NOx/kg fuel. These emissions inventories are available for use by atmospheric scientists conducting the Atmospheric Effects of Stratospheric Aircraft (AESA) modeling studies. Fuel burned and emissions of nitrogen oxides (NOx as NO2), carbon monoxide, and hydrocarbons have been calculated on a 1 degree latitude x 1 degree longitude x 1 kilometer attitude grid and delivered to NASA as electronic files.

  19. Aircraft Emission Inventories Projected in Year 2015 for a High Speed Civil Transport (HSCT) Universal Airline Network

    NASA Technical Reports Server (NTRS)

    Baughcum, Steven L.; Henderson, Stephen C.

    1995-01-01

    This report describes the development of a three-dimensional database of aircraft fuel burn and emissions (fuel burned, NOx, CO, and hydrocarbons) from projected fleets of high speed civil transports (HSCT's) on a universal airline network.Inventories for 500 and 1000 HSCT fleets, as well as the concurrent subsonic fleets, were calculated. The objective of this work was to evaluate the changes in geographical distribution of the HSCT emissions as the fleet size grew from 500 to 1000 HSCT's. For this work, a new expanded HSCT network was used and flights projected using a market penetration analysis rather than assuming equal penetration as was done in the earlier studies. Emission inventories on this network were calculated for both Mach 2.0 and Mach 2.4 HSCT fleets with NOx cruise emission indices of approximately 5 and 15 grams NOx/kg fuel. These emissions inventories are available for use by atmospheric scientists conducting the Atmospheric Effects of Stratospheric Aircraft (AESA) modeling studies. Fuel burned and emissions of nitrogen oxides (NOx as NO2), carbon monoxide, and hydrocarbons have been calculated on a 1 degree latitude x 1 degree longitude x 1 kilometer attitude grid and delivered to NASA as electronic files.

  20. Control of NOx Emissions from Stationary Combustion Sources

    EPA Science Inventory

    In general, NOx control technologies are categorized as being either primary control technologies or secondary control technologies. Primary control technologies reduce the formation of NOx in the primary combustion zone. In contrast, secondary control technologies destroy the NO...

  1. Continuous reduction of cyclic adsorbed and desorbed NO(x) in diesel emission using nonthermal plasma.

    PubMed

    Kuwahara, Takuya; Nakaguchi, Harunobu; Kuroki, Tomoyuki; Okubo, Masaaki

    2016-05-01

    Considering the recent stringent regulations governing diesel NO(x) emission, an aftertreatment system for the reduction of NO(x) in the exhaust gas has been proposed and studied. The proposed system is a hybrid method combining nonthermal plasma and NOx adsorbent. The system does not require precious metal catalysts or harmful chemicals such as urea and ammonia. In the present system, NO(x) in diesel emission is treated by adsorption and desorption by adsorbent as well as nonthermal plasma reduction. In addition, the remaining NO(x) in the adsorbent is desorbed again in the supplied air by residual heat. The desorbed NO(x) in air recirculates into the intake of the engine, and this process, i.e., exhaust gas components' recirculation (EGCR) achieves NO(x) reduction. Alternate utilization of two adsorption chambers in the system can achieve high-efficiency NO(x) removal continuously. An experiment with a stationary diesel engine for electric power generation demonstrates an energy efficiency of 154 g(NO2)/kWh for NO(x) removal and continuous NO(x) reduction of 70.3%. Considering the regulation against diesel emission in Japan, i.e., the new regulation to be imposed on vehicles of 3.5-7.5 ton since 2016, the present aftertreatment system fulfills the requirement with only 1.0% of engine power.

  2. Continuous reduction of cyclic adsorbed and desorbed NO(x) in diesel emission using nonthermal plasma.

    PubMed

    Kuwahara, Takuya; Nakaguchi, Harunobu; Kuroki, Tomoyuki; Okubo, Masaaki

    2016-05-01

    Considering the recent stringent regulations governing diesel NO(x) emission, an aftertreatment system for the reduction of NO(x) in the exhaust gas has been proposed and studied. The proposed system is a hybrid method combining nonthermal plasma and NOx adsorbent. The system does not require precious metal catalysts or harmful chemicals such as urea and ammonia. In the present system, NO(x) in diesel emission is treated by adsorption and desorption by adsorbent as well as nonthermal plasma reduction. In addition, the remaining NO(x) in the adsorbent is desorbed again in the supplied air by residual heat. The desorbed NO(x) in air recirculates into the intake of the engine, and this process, i.e., exhaust gas components' recirculation (EGCR) achieves NO(x) reduction. Alternate utilization of two adsorption chambers in the system can achieve high-efficiency NO(x) removal continuously. An experiment with a stationary diesel engine for electric power generation demonstrates an energy efficiency of 154 g(NO2)/kWh for NO(x) removal and continuous NO(x) reduction of 70.3%. Considering the regulation against diesel emission in Japan, i.e., the new regulation to be imposed on vehicles of 3.5-7.5 ton since 2016, the present aftertreatment system fulfills the requirement with only 1.0% of engine power. PMID:26844402

  3. REDUCTION OF NOx EMISSION FROM COAL COMBUSTION THROUGH OXYGEN ENRICHMENT

    SciTech Connect

    Western Research Institute

    2006-07-01

    BOC Process Gas Solutions and Western Research Institute (WRI) conducted a pilot-scale test program to evaluate the impact of oxygen enrichment on the emissions characteristics of pulverized coal. The combustion test facility (CTF) at WRI was used to assess the viability of the technique and determine the quantities of oxygen required for NOx reduction from coal fired boiler. In addition to the experimental work, a series of Computational Fluid Dynamics (CFD) simulations were made of the CTF under comparable conditions. A series of oxygen enrichment test was performed using the CTF. In these tests, oxygen was injected into one of the following streams: (1) the primary air (PA), (2) the secondary air (SA), and (3) the combined primary and secondary air. Emission data were collected from all tests, and compared with the corresponding data from the baseline cases. A key test parameter was the burner stoichiometry ratio. A series of CFD simulation models were devised to mimic the initial experiments in which secondary air was enriched with oxygen. The results from these models were compared against the experimental data. Experimental evidence indicated that oxygen enrichment does appear to be able to reduce NOx levels from coal combustion, especially when operated at low over fire air (OFA) levels. The reductions observed however are significantly smaller than that reported by others (7-8% vs. 25-50%), questioning the economic viability of the technique. This technique may find favor with fuels that are difficult to burn or stabilize at high OFA and produce excessive LOI. While CFD simulation appears to predict NO amounts in the correct order of magnitude and the correct trend with staging, it is sensitive to thermal conditions and an accurate thermal prediction is essential. Furthermore, without development, Fluent's fuel-NO model cannot account for a solution sensitive fuel-N distribution between volatiles and char and thus cannot predict the trends seen in the

  4. Emission inventories of NOx from commercial energy consumption in China, 1995-1998.

    PubMed

    Hao, Jiming; Tian, Hezhong; Lu, Yongqi

    2002-02-15

    Emissions of nitrogen oxides (NOx) in China are of great concern because of their impact on local air pollution as well as on regional environmental risks such as acid rain, eutrophication, tropospheric ozone, fine particulate matter, and loss of biodiversity. In this paper, total anthropogenic emissions of NOx in China during the past two decades are estimated on the basis of commercial energy consumption and NOx emission factors of different sectors and fuel types. Specifically, emission inventories of NOx from 31 provinces, 7 economic sectors, and 11 fuel types from 1995 to 1998 are evaluated and analyzed in detail, and the distribution of provincial-based average NOx emission intensity in 1998 is presented. It can be seen that the calculated national total emissions of NOx have rapidly increased from 4.76 Mt in 1980 to a peak value of about 12.03 Mt in 1996, with an average annual growth rate of 6%. However, instead of increasing, NOx emissions in 1997 and 1998 decreased by 0.37 Mt and 0.85 Mt, respectively, as compared to the peak in 1996. In short, NOx emissions caused by energy use are mainly concentrated in the more populated and industrialized areas of China, i.e., the Eastern Central and Southeastern areas. These results imply that China's NOx emissions in the future may not become as high as previously expected which will be helpful for policy making to control local NOx pollution as well as to reduce acid rain and tropospheric ozone in East Asia.

  5. 40 CFR 75.17 - Specific provisions for monitoring emissions from common, bypass, and multiple stacks for NOX...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... emissions from common, bypass, and multiple stacks for NOX emission rate. 75.17 Section 75.17 Protection of..., and multiple stacks for NOX emission rate. Notwithstanding the provisions of paragraphs (a), (b), (c... this part to meet the monitoring and reporting requirements of a State or federal NOX mass...

  6. [NOx and SO2 formation in the sintering process and influence of sintering material composition on NOx emissions].

    PubMed

    Ren, Zhong-Pei; Zhu, Tian-Le; Zhu, Ting-Yu; Lü, Dong

    2014-10-01

    NOx and SO2 formation in the sintering process and the influence of coke powder content, moisture content and adding additives on NO emissions were investigated by the sintering pot experimental method. The results showed that the combustion zone moved downward along the sintering pot after the sintering started. The NOx concentrations of all monitoring points below the combustion zone were basically the same. SO2 generated in the combustion zone was adsorbed and accumulated in the sintering materials below the zone. Then, SO2 was released by pyrolysis, and finally discharged from the outlet of sintering pot. So the significant SO2 couldn't be detected before the burning through point, and the relationship between the SO2 concentration and the sintering time displayed an inverted "V" curve. NOx produced from the sintering process was mainly thermal-NOx, and most of it was NO, the NO2 concentration was very low. Reducing the coke powder and moisture contents, or adding sintering additives could effectively reduce NOx emissions.

  7. NOx EMISSIONS PRODUCED WITH COMBUSTION OF POWDER RIVER BASIN COAL IN A UTILITY BOILER

    SciTech Connect

    John S. Nordin; Norman W. Merriam

    1997-04-01

    The objective of this report is to estimate the NOx emissions produced when Powder River Basin (PRB) coal is combusted in a utility boiler. The Clean Air Act regulations specify NOx limits of 0.45 lb/mm Btu (Phase I) and 0.40 lb/mm Btu (Phase II) for tangentially fired boilers, and 0.50 lb/mm 13tu (Phase II) and 0.46 lb/mm Btu (Phase II) for dry-bottom wall-fired boilers. The Clean Air Act regulations also specify other limits for other boiler types. Compliance for Phase I has been in effect since January 1, 1996. Compliance for Phase II goes into effect on January 1, 2000. Emission limits are expressed as equivalent NO{sub 2} even though NO (and sometimes N{sub 2}O) is the NOx species emitted during combustion. Regulatory agencies usually set even lower NOx emission limits in ozone nonattainment areas. In preparing this report, Western Research Institute (WRI) used published test results from utilities burning various coals, including PRB coal, using state-of-the art control technology for minimizing NOx emissions. Many utilities can meet Clean Air Act NOx emission limits using a combination of tight combustion control and low-NOx burners and by keeping furnaces clean (i.e., no slag buildup). In meeting these limits, some utilities also report problems such as increased carbon in their fly ash and excessive furnace tube corrosion. This report discusses utility experience. The theory of NOx emission formation during coal combustion as related to coal structure and how the coal is combusted is also discussed. From this understanding, projections are made for NOx emissions when processed PRB coal is combusted in a test similar to that done with other coals. As will be shown, there are a lot of conditions for achieving low NOx emissions, such as tight combustion control and frequent waterlancing of the furnace to avoid buildup of deposits.

  8. Modeling the Effects of Aircraft Emissions on Atmospheric Photochemistry Using Layered Plume Dynamics

    NASA Astrophysics Data System (ADS)

    Cameron, M. A.; Jacobson, M. Z.; Naiman, A. D.; Lele, S. K.

    2012-12-01

    Aviation is an expanding industry, experiencing continued growth and playing an increasingly noticed role in upper tropospheric/lower stratospheric composition. Nitrogen oxides and other gas-phase emissions from aircraft react to affect ozone photochemistry. This research investigates the effects of treating aircraft gas-phase chemistry within an expanding layered plume versus at the grid scale. SMVGEAR II, a sparse-matrix, vectorized Gear-type solver for ordinary differential equations, is used to solve chemical equations at both the grid scale and subgrid scale. A Subgrid Plume Model (SPM) is used to advance the expanding plume, accounting for wind shear and diffusion. Simulations suggest that using a layered plume approach results in noticeably different final NOx concentrations, demonstrating the importance of these plume dynamics in predicting the effects of aircraft on ozone concentrations. Results showing the effects of a layered plume, single plume, and no plume on ozone after several hours will be presented.

  9. Sensitivity of NOx over the Indian Ocean to emissions from the surrounding continents and nonlinearities in atmospheric chemistry responses

    NASA Astrophysics Data System (ADS)

    Kunhikrishnan, T.; Lawrence, M. G.

    2004-08-01

    The sensitivity of the Indian Ocean atmospheric chemistry to continental NOx emissions is examined using a global chemistry-transport model (MATCH-MPIC). NOx responds nonlinearly to changes in emissions, since O3 and OH, which depend on NOx, influence its lifetime. Due to this feedback and the contribution from other NOx sources (e.g., lightning), much of the Indian Ocean lower troposphere (LT) is only weakly sensitive to continental NOx emissions. In contrast to INDOEX (Indian Ocean Experiment) results for aerosols, CO, etc., during the winter monsoon the central Indian Ocean (CIO) is weakly sensitivity to Indian NOx emissions. However, the Bay of Bengal LT is very sensitive to NOx emissions from India (summer) and SE Asia and China (winter). Higher up, NOx over the CIO is most sensitive to African and SE Asian emissions, while the northern regions are influenced by the summer monsoon plume from India, SE Asia and China.

  10. The challenge to NOx emission control for heavy-duty diesel vehicles in China

    NASA Astrophysics Data System (ADS)

    Wu, Y.; Zhang, S. J.; Li, M. L.; Ge, Y. S.; Shu, J. W.; Zhou, Y.; Xu, Y. Y.; Hu, J. N.; Liu, H.; Fu, L. X.; He, K. B.; Hao, J. M.

    2012-10-01

    China's new "Twelfth Five-Year Plan" set a target for total NOx emission reduction of 10% for the period of 2011-2015. Heavy-duty diesel vehicles (HDDVs) have been considered a major contributor to NOx emissions in China. Beijing initiated a comprehensive vehicle test program in 2008. This program included a sub-task for measuring on-road emission profiles of hundreds of HDDVs using portable emission measurement systems (PEMS). The major finding is that neither the on-road distance-specific (g km-1) nor brake-specific (g kWh-1) NOx emission factors for diesel buses and heavy-duty diesel trucks improved in most cases as emission standards became more stringent. For example, the average NOx emission factors for Euro II, Euro III and Euro IV buses are 11.3 ± 3.3 g km-1, 12.5 ± 1.3 g km-1, and 11.8 ± 2.0 g km-1, respectively. No statistically significant difference in NOx emission factors was observed between Euro II and III buses. Even for Euro IV buses equipped with SCR systems, the NOx emission factors are similar to Euro III buses. The data regarding real-time engine performance of Euro IV buses suggest the engine certification cycles did not reflect their real-world operating conditions. These new on-road test results indicate that previous estimates of total NOx emissions for HDDV fleet may be significantly underestimated. The new estimate in total NOx emissions for the Beijing HDDV fleet in 2009 is 37.0 Gg, an increase of 45% compared to the previous study. Further, we estimate that the total NOx emissions for the national HDDV fleet in 2009 are approximately 4.0 Tg, higher by 1.0 Tg (equivalent to 18% of total NOx emissions for vehicle fleet in 2009) than that estimated in the official report. This would also result in 4% increase in estimation of national anthropogenic NOx emissions. More effective control measures (such as promotion of CNG buses and a new in-use compliance testing program) are urged to secure the goal of total NOx mitigation for the HDDV

  11. Direct carbon dioxide emissions from civil aircraft

    NASA Astrophysics Data System (ADS)

    Grote, Matt; Williams, Ian; Preston, John

    2014-10-01

    Global airlines consume over 5 million barrels of oil per day, and the resulting carbon dioxide (CO2) emitted by aircraft engines is of concern. This article provides a contemporary review of the literature associated with the measures available to the civil aviation industry for mitigating CO2 emissions from aircraft. The measures are addressed under two categories - policy and legal-related measures, and technological and operational measures. Results of the review are used to develop several insights into the challenges faced. The analysis shows that forecasts for strong growth in air-traffic will result in civil aviation becoming an increasingly significant contributor to anthropogenic CO2 emissions. Some mitigation-measures can be left to market-forces as the key-driver for implementation because they directly reduce airlines' fuel consumption, and their impact on reducing fuel-costs will be welcomed by the industry. Other mitigation-measures cannot be left to market-forces. Speed of implementation and stringency of these measures will not be satisfactorily resolved unattended, and the current global regulatory-framework does not provide the necessary strength of stewardship. A global regulator with ‘teeth' needs to be established, but investing such a body with the appropriate level of authority requires securing an international agreement which history would suggest is going to be very difficult. If all mitigation-measures are successfully implemented, it is still likely that traffic growth-rates will continue to out-pace emissions reduction-rates. Therefore, to achieve an overall reduction in CO2 emissions, behaviour change will be necessary to reduce demand for air-travel. However, reducing demand will be strongly resisted by all stakeholders in the industry; and the ticket price-increases necessary to induce the required reduction in traffic growth-rates place a monetary-value on CO2 emissions of approximately 7-100 times greater than other common

  12. Commercial aircraft engine emissions characterization of in-use aircraft at Hartsfield-Jackson Atlanta International Airport.

    PubMed

    Herndon, Scott C; Jayne, John T; Lobo, Prem; Onasch, Timothy B; Fleming, Gregg; Hagen, Donald E; Whitefield, Philip D; Miake-Lye, Richard C

    2008-03-15

    The emissions from in-use commercial aircraft engines have been analyzed for selected gas-phase species and particulate characteristics using continuous extractive sampling 1-2 min downwind from operational taxi- and runways at Hartsfield-Jackson Atlanta International Airport. Using the aircraft tail numbers, 376 plumes were associated with specific engine models. In general, for takeoff plumes, the measured NOx emission index is lower (approximately 18%) than that predicted by engine certification data corrected for ambient conditions. These results are an in-service observation of the practice of "reduced thrust takeoff". The CO emission index observed in ground idle plumes was greater (up to 100%) than predicted by engine certification data for the 7% thrust condition. Significant differences are observed in the emissions of black carbon and particle number among different engine models/technologies. The presence of a mode at approximately 65 nm (mobility diameter) associated with takeoff plumes and a smaller mode at approximately 25 nm associated with idle plumes has been observed. An anticorrelation between particle mass loading and particle number concentration is observed.

  13. 40 CFR 97.424 - Compliance with TR NOX Annual emissions limitation.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 21 2014-07-01 2014-07-01 false Compliance with TR NOX Annual emissions limitation. 97.424 Section 97.424 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... accounting basis in the following order: (i) Any TR NOX Annual allowances that were allocated to the units...

  14. 40 CFR 97.354 - Compliance with CAIR NOX emissions limitation.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 21 2014-07-01 2014-07-01 false Compliance with CAIR NOX emissions limitation. 97.354 Section 97.354 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... section, on a first-in, first-out (FIFO) accounting basis in the following order: (i) Any CAIR NOX...

  15. 40 CFR 96.354 - Compliance with CAIR NOX emissions limitation.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 21 2014-07-01 2014-07-01 false Compliance with CAIR NOX emissions limitation. 96.354 Section 96.354 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... section, on a first-in, first-out (FIFO) accounting basis in the following order: (i) Any CAIR NOX...

  16. 40 CFR 97.424 - Compliance with TR NOX Annual emissions limitation.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 22 2013-07-01 2013-07-01 false Compliance with TR NOX Annual emissions limitation. 97.424 Section 97.424 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... accounting basis in the following order: (i) Any TR NOX Annual allowances that were allocated to the units...

  17. 40 CFR 97.154 - Compliance with CAIR NOX emissions limitation.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 21 2014-07-01 2014-07-01 false Compliance with CAIR NOX emissions limitation. 97.154 Section 97.154 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR...) accounting basis in the following order: (i) Any CAIR NOX allowances that were allocated to the units at...

  18. 40 CFR 97.354 - Compliance with CAIR NOX emissions limitation.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Ozone Season Allowance Tracking System § 97.354 Compliance with CAIR NOX emissions limitation. (a... under paragraph (d)(1) of this section shall not affect the liability of the owners and operators of the... Administrator may review and conduct independent audits concerning any submission under the CAIR NOX...

  19. 40 CFR 97.154 - Compliance with CAIR NOX emissions limitation.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Allowance Tracking System § 97.154 Compliance with CAIR NOX emissions limitation. (a) Allowance transfer... required under paragraph (d)(1) of this section shall not affect the liability of the owners and operators... conduct independent audits concerning any submission under the CAIR NOX Annual Trading Program and...

  20. Effects of Coaxial Air on Nitrogen-Diluted Hydrogen Jet Diffusion Flame Length and NOx Emission

    SciTech Connect

    Weiland, N.T.; Chen, R.-H.; Strakey, P.A.

    2007-10-01

    Turbulent nitrogen-diluted hydrogen jet diffusion flames with high velocity coaxial air flows are investigated for their NOx emission levels. This study is motivated by the DOE turbine program’s goal of achieving 2 ppm dry low NOx from turbine combustors running on nitrogen-diluted high-hydrogen fuels. In this study, effects of coaxial air velocity and momentum are varied while maintaining low overall equivalence ratios to eliminate the effects of recirculation of combustion products on flame lengths, flame temperatures, and resulting NOx emission levels. The nature of flame length and NOx emission scaling relationships are found to vary, depending on whether the combined fuel and coaxial air jet is fuel-rich or fuel-lean. In the absence of differential diffusion effects, flame lengths agree well with predicted trends, and NOx emissions levels are shown to decrease with increasing coaxial air velocity, as expected. Normalizing the NOx emission index with a flame residence time reveals some interesting trends, and indicates that a global flame strain based on the difference between the fuel and coaxial air velocities, as is traditionally used, is not a viable parameter for scaling the normalized NOx emissions of coaxial air jet diffusion flames.

  1. The challenge to NOx emission control for heavy-duty diesel vehicles in China

    NASA Astrophysics Data System (ADS)

    Wu, Y.; Zhang, S. J.; Li, M. L.; Ge, Y. S.; Shu, J. W.; Zhou, Y.; Xu, Y. Y.; Hu, J. N.; Liu, H.; Fu, L. X.; He, K. B.; Hao, J. M.

    2012-07-01

    China's new "Twelfth Five-Year Plan" set a target for total NOx emission reduction of 10% for the period of 2011-2015. Heavy-duty diesel vehicles (HDDVs) have been considered a major contributor to NOx emissions in China. Beijing initiated a comprehensive vehicle test program in 2008. This program included a sub-task for measuring on-road emission profiles of hundreds of HDDVs using portable emission measurement systems (PEMS). The major finding is that neither the on-road distance-specific (g km -1) nor brake-specific (g kW h-1) NOx emission factors for diesel buses and heavy-duty diesel trucks improved in most cases as emission standards became more stringent. For example, the average NOx emission factors for Euro II, Euro III and Euro IV buses are 11.3±3.3 g km-1, 12.5± 1.3 g km-1, and 11.8±2.0 g km-1, respectively. No statistically significant difference in NOx emission factors was observed between Euro II and III buses. Even for Euro IV buses equipped with SCR systems, the NOx emission factors are similar to Euro III buses. The data regarding real-time engine performance of Euro IV buses suggest the engine certification cycles did not reflect their real-world operating conditions. These new on-road test results indicate that previous estimates of total NOx emissions for HDDV fleet may be significantly underestimated. The new estimate in total NOx emissions for the Beijing HDDV fleet in 2009 is 37.0 Gg, an increase of 45% compared to the previous study. Further, we estimate that the total NOx emissions for the national HDDV fleet in 2009 are approximately 4.0 Tg, higher by 1.0 Tg (equivalent to 18% of total NOx emissions for vehicle fleet in 2009) than that estimated in the official report. This would also result in 4% increase in estimation of national anthropogenic NOx emissions. More effective control measures (such as promotion of CNG buses and a new in-use compliance testing program) are urged to secure the goal of total NOxmitigation for the HDDV fleet

  2. Characterization of emissions from commercial aircraft engines during the Aircraft Particle Emissions eXperiment (APEX) 1 to 3

    EPA Science Inventory

    The fine particulate matter emissions from aircraft operations at large airports located in areas of the U. S. designated as non-attainment for the National Ambient Air Quality Standard for PM-2.5 are of major environmental concern. PM emissions data for commercial aircraft engin...

  3. 40 CFR 76.5 - NOX emission limitations for Group 1 boilers.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.5 NOX emission limitations..., the date on which the unit is required to meet Acid Rain emission reduction requirements for SO2, the... subject to section 404(d) of the Act, the date the unit is required to meet Acid Rain emissions...

  4. 40 CFR 76.5 - NOX emission limitations for Group 1 boilers.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.5 NOX emission limitations..., the date on which the unit is required to meet Acid Rain emission reduction requirements for SO2, the... 404(d) of the Act, the date the unit is required to meet Acid Rain emissions reduction...

  5. 40 CFR 76.5 - NOX emission limitations for Group 1 boilers.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.5 NOX emission limitations..., the date on which the unit is required to meet Acid Rain emission reduction requirements for SO2, the... 404(d) of the Act, the date the unit is required to meet Acid Rain emissions reduction...

  6. 40 CFR 76.5 - NOX emission limitations for Group 1 boilers.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.5 NOX emission limitations..., the date on which the unit is required to meet Acid Rain emission reduction requirements for SO2, the... 404(d) of the Act, the date the unit is required to meet Acid Rain emissions reduction...

  7. 40 CFR 76.5 - NOX emission limitations for Group 1 boilers.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.5 NOX emission limitations..., the date on which the unit is required to meet Acid Rain emission reduction requirements for SO2, the... 404(d) of the Act, the date the unit is required to meet Acid Rain emissions reduction...

  8. Nitrogen isotopic composition of coal-fired power plant NOx: influence of emission controls and implications for global emission inventories.

    PubMed

    Felix, J David; Elliott, Emily M; Shaw, Stephanie L

    2012-03-20

    Despite the potential use of δ(15)N as a tracer of NO(x) source contributions, prior documentation of δ(15)N of various NO(x) emission sources is exceedingly limited. This manuscript presents the first measurements of the nitrogen isotopic composition of NO(x) (δ(15)N-NO(x)) emitted from coal-fired power plants in the U.S. at typical operating conditions with and without the presence of selective catalytic reduction (SCR) and selective noncatalytic reduction (SNCR) technology. To accomplish this, a novel method for collection and isotopic analysis of coal-fired stack NO(x) emission samples was developed based on modifications of a historic U.S. EPA stack sampling method. At the power plants included in this study, large differences exist in the isotopic composition of NO(x) emitted with and without SCRs and SNCRs; further the isotopic composition of power plant NO(x) is higher than that of other measured NO(x) emission sources confirming its use as an environmental tracer. These findings indicate that gradual implementation of SCRs at power plants will result in an industry-wide increase in δ(15)N values of NO(x) and NO(y) oxidation products from this emission source.

  9. Collection of NO and NO2 for isotopic analysis of NO(x) emissions.

    PubMed

    Fibiger, Dorothy L; Hastings, Meredith G; Lew, Audrey F; Peltier, Richard E

    2014-12-16

    There have been several measurements made of the nitrogen isotopic composition of gaseous NOx (NOx = NO + NO2) from various emission sources, utilizing a wide variety of methods to collect the NOx in solution as nitrate or nitrite. However, previous collection techniques have not been verified for complete or efficient capture of NOx such that the isotopic composition of NOx remains unaltered during collection. Here, we present a method of collecting NOx (NO + NO2) in solution as nitrate to evaluate the nitrogen isotopic composition of the NOx (δ(15)N-NOx). Using a 0.25 M KMnO4 and 0.5 M NaOH solution, quantitative NOx collection was achieved under a variety of conditions in laboratory and field settings, allowing for isotopic analysis without correcting for fractionations. The uncertainty across the entire analytic procedure is ±1.5‰ (1σ). With this method, a more robust inventory of NOx source isotopic composition is possible, which has implications for studies of air quality and acid deposition. PMID:25415365

  10. Simultaneous reduction of particulate matter and NO(x) emissions using 4-way catalyzed filtration systems.

    PubMed

    Swanson, Jacob J; Watts, Winthrop F; Newman, Robert A; Ziebarth, Robin R; Kittelson, David B

    2013-05-01

    The next generation of diesel emission control devices includes 4-way catalyzed filtration systems (4WCFS) consisting of both NOx and diesel particulate matter (DPM) control. A methodology was developed to simultaneously evaluate the NOx and DPM control performance of miniature 4WCFS made from acicular mullite, an advanced ceramic material (ACM), that were challenged with diesel exhaust. The impact of catalyst loading and substrate porosity on catalytic performance of the NOx trap was evaluated. Simultaneously with NOx measurements, the real-time solid particle filtration performance of catalyst-coated standard and high porosity filters was determined for steady-state and regenerative conditions. The use of high porosity ACM 4-way catalyzed filtration systems reduced NOx by 99% and solid and total particulate matter by 95% when averaged over 10 regeneration cycles. A "regeneration cycle" refers to an oxidizing ("lean") exhaust condition followed by a reducing ("rich") exhaust condition resulting in NOx storage and NOx reduction (i.e., trap "regeneration"), respectively. Standard porosity ACM 4-way catalyzed filtration systems reduced NOx by 60-75% and exhibited 99.9% filtration efficiency. The rich/lean cycling used to regenerate the filter had almost no impact on solid particle filtration efficiency but impacted NOx control. Cycling resulted in the formation of very low concentrations of semivolatile nucleation mode particles for some 4WCFS formulations. Overall, 4WCFS show promise for significantly reducing diesel emissions into the atmosphere in a single control device.

  11. Characterization of NOx emission in the suburbs of Tokyo based on simultaneous and real-time observations of atmospheric Ox and NOx

    NASA Astrophysics Data System (ADS)

    Matsumoto, J.

    2013-12-01

    Nitrogen oxides, NOx (NO, NO2), and volatile organic compounds, VOCs, are important as precursors of photochemical oxidants (tropospheric ozone, O3). To predict and control photochemical oxidants, NOx emission should be captured precisely. In addition, the ratio of NO2/NOx in the exhaust gas is also important as the initial balance between NO and NO2 in the atmosphere. Monitoring the NO2/NOx ratio in the exhaust gases is essential. Especially, the influence of the NOx emission on the real atmosphere should be explored. However, conversion reactions among NO, NO2 and O3 are typically in the time scale of minutes. The NO2/NOx ratio can change rapidly just after emission. Real-time observations of these compounds in the second time scale are essential. In view of photochemical oxidant, near emission sources of NO, ozone concentration can be easily perturbed by reaction with locally emitted NO. As an index of oxidant, the sum of O3 and NO2 (Ox = O3 + NO2) is useful. In this study, a simultaneous and real-time analyzer of atmospheric Ox and NOx has been developed utilizing the dual NO2 detectors based on laser-induced fluorescence technique (LIF), and characterization of NOx emission was explored through the observations of Ox and NOx in the suburbs of Tokyo. The dual LIF detectors consisted of one laser head, two LIF cells, and one common vacuum pump. As the Ox monitor, the excess NO was added to the sample and O3 was converted to NO2, and then the sum of O3 and NO2 in the sample was quantified at the 1st LIF cell. As the NOx monitor, the excess O3 was added to the sample and NO was converted to NO2, and then the sum of NO and NO2 in the sample was quantified at the 2nd LIF cell. Both the ';Ox' and ';NOx' channels in the dual LIF analyzer were simultaneously monitoring Ox and NOx in the sample air, respectively. The temporal resolution of observed data was 1 s. Typical conversion efficiencies of O3 and NO to NO2 were more than 0.98. The lower detection limits were 0

  12. 40 CFR 51.10 - How does my state report emissions that are required by the NOX SIP Call?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... are required by the NOX SIP Call? 51.10 Section 51.10 Protection of Environment ENVIRONMENTAL... does my state report emissions that are required by the NOX SIP Call? The District of Columbia and states that are subject to the NOX SIP Call § 51.121) are subject to the emissions reporting...

  13. 40 CFR 51.10 - How does my state report emissions that are required by the NOX SIP Call?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... are required by the NOX SIP Call? 51.10 Section 51.10 Protection of Environment ENVIRONMENTAL... does my state report emissions that are required by the NOX SIP Call? The District of Columbia and states that are subject to the NOX SIP Call § 51.121) are subject to the emissions reporting...

  14. 40 CFR 51.10 - How does my state report emissions that are required by the NOX SIP Call?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... are required by the NOX SIP Call? 51.10 Section 51.10 Protection of Environment ENVIRONMENTAL... does my state report emissions that are required by the NOX SIP Call? The District of Columbia and states that are subject to the NOX SIP Call § 51.121) are subject to the emissions reporting...

  15. Reduction of NOx emissions on oil firing at Bowline Point Unit No. 2

    SciTech Connect

    Conti, A.V.; Lucente, J.; O`Sullivan, R.C.; Schmidt, D.W.

    1995-12-31

    Improved combustion technology, based upon optimization of oil atomizer and flame stabilizer design, has been retrofitted to oil and oil/gas fired boilers to reduce NOx emissions, particulate matter emissions, opacity, and to provide operational and performance benefits. This technology, known as REACH, can be applied to wall and tangential-fired boilers at a fraction of the cost of installing new burners. The technology is also compatible with conventional NOx controls such as overfire air, flue gas recirculation, low-NOx burners, and can be combined with these controls to further reduce NOx Emissions. This paper describes the results achieved when this technology was applied to Orange and Rockland Utilities` Bowline Point Unit No. 2 to meet NYSDEC part 227 regulations for the emissions of nitrogen oxides (0.25 lbs/MBtu). Bowline Point No. 2 is a 600 MW opposed-wall fired boiler with overfire air and flue gas recirculation capability.

  16. Calculation of odour emissions from aircraft engines at Copenhagen Airport.

    PubMed

    Winther, Morten; Kousgaard, Uffe; Oxbøl, Arne

    2006-07-31

    In a new approach the odour emissions from aircraft engines at Copenhagen Airport are calculated using actual fuel flow and emission measurements (one main engine and one APU: Auxiliary Power Unit), odour panel results, engine specific data and aircraft operational data for seven busy days. The calculation principle assumes a linear relation between odour and HC emissions. Using a digitalisation of the aircraft movements in the airport area, the results are depicted on grid maps, clearly reflecting aircraft operational statistics as single flights or total activity during a whole day. The results clearly reflect the short-term temporal fluctuations of the emissions of odour (and exhaust gases). Aircraft operating at low engine thrust (taxiing, queuing and landing) have a total odour emission share of almost 98%, whereas the shares for the take off/climb out phases (2%) and APU usage (0.5%) are only marginal. In most hours of the day, the largest odour emissions occur, when the total amount of fuel burned during idle is high. However, significantly higher HC emissions for one specific engine cause considerable amounts of odour emissions during limited time periods. The experimentally derived odour emission factor of 57 OU/mg HC is within the range of 23 and 110 OU/mg HC used in other airport odour studies. The distribution of odour emission results between aircraft operational phases also correspond very well with the results for these other studies. The present study uses measurement data for a representative engine. However, the uncertainties become large when the experimental data is used to estimate the odour emissions for all aircraft engines. More experimental data is needed to increase inventory accuracy, and in terms of completeness it is recommended to make odour emission estimates also for engine start and the fuelling of aircraft at Copenhagen Airport in the future.

  17. Calculation of odour emissions from aircraft engines at Copenhagen Airport.

    PubMed

    Winther, Morten; Kousgaard, Uffe; Oxbøl, Arne

    2006-07-31

    In a new approach the odour emissions from aircraft engines at Copenhagen Airport are calculated using actual fuel flow and emission measurements (one main engine and one APU: Auxiliary Power Unit), odour panel results, engine specific data and aircraft operational data for seven busy days. The calculation principle assumes a linear relation between odour and HC emissions. Using a digitalisation of the aircraft movements in the airport area, the results are depicted on grid maps, clearly reflecting aircraft operational statistics as single flights or total activity during a whole day. The results clearly reflect the short-term temporal fluctuations of the emissions of odour (and exhaust gases). Aircraft operating at low engine thrust (taxiing, queuing and landing) have a total odour emission share of almost 98%, whereas the shares for the take off/climb out phases (2%) and APU usage (0.5%) are only marginal. In most hours of the day, the largest odour emissions occur, when the total amount of fuel burned during idle is high. However, significantly higher HC emissions for one specific engine cause considerable amounts of odour emissions during limited time periods. The experimentally derived odour emission factor of 57 OU/mg HC is within the range of 23 and 110 OU/mg HC used in other airport odour studies. The distribution of odour emission results between aircraft operational phases also correspond very well with the results for these other studies. The present study uses measurement data for a representative engine. However, the uncertainties become large when the experimental data is used to estimate the odour emissions for all aircraft engines. More experimental data is needed to increase inventory accuracy, and in terms of completeness it is recommended to make odour emission estimates also for engine start and the fuelling of aircraft at Copenhagen Airport in the future. PMID:16194561

  18. Investigating the impacts of aviation NOX, SO2 and black carbon emissions on ozone, aerosol and climate.

    NASA Astrophysics Data System (ADS)

    Kapadia, Zarashpe; Borman, Duncan; Spracklen, Dominick; Arnold, Stephen; Mann, Graham; Williams, Paul

    2013-04-01

    Aviation is currently responsible for 3% of global anthropogenic CO2 emissions, but 2-14% of anthropogenic induced warming due to the co-emission of NOX, SO2 and black carbon and formation of contrails. The impact of aviation emissions on ozone and aerosol is uncertain with recent research demonstrating the need to include atmospheric nitrate chemistry. The inclusion of nitrate chemistry may lead to a 20% reduction in aviation induced ozone forcing estimates due to the competition for atmospheric oxidants such as OH . Compounding this, uncertainties relating to the effects of NOx on ozone and methane illustrate the need for refining the understanding of aviation induced impacts. Furthermore the role of aerosol microphysics in controlling the climate impacts of aviation has not yet been explored. Here we use the TOMCAT 3-D chemical transport model coupled to the GLOMAP-mode aerosol microphysics model to quantify the impacts of aviation NOX, SO2 and BC emissions on ozone, aerosol and climate. GLOMAP-mode treats size resolved aerosol using a two-moment modal approach. We evaluate the effects of nitrate processing on the diagnosed impacts of aviation emissions on atmospheric composition including the first assessment of the impact on the global concentrations of cloud condensation nuclei. We investigate interactions between gas-phase oxidant photochemistry and aerosol microphysics in regions influenced by aircraft emissions, using fully-coupled tropospheric chemistry and multi-component aerosol treatment (BC, sulphate, nitrate). Finally, we use a 3-D radiative transfer model to quantify the ozone and aerosol direct and indirect radiative effects of aviation emissions. The work presented here is part of a wider research project which will be the first study to combine aviation NOX, SO2 and black carbon emission in a global size-resolved model which considers atmospheric nitrate chemistry, which will aim to add to the science surrounding present day aviation impacts by

  19. Emissions of greenhouse gases and air pollutants from commercial aircraft at international airports in Korea

    NASA Astrophysics Data System (ADS)

    Song, Sang-Keun; Shon, Zang-Ho

    2012-12-01

    The emissions of greenhouse gases (GHGs) and air pollutants from aircraft in the boundary layer at four major international airports in Korea over a two-year period (2009-2010) were estimated using the Emissions and Dispersion Modeling System (EDMS) (i.e. activity-based (Landing/Take-Off (LTO) cycle) methodology). Both domestic and international LTOs and ground support equipment at the airports were considered. The average annual emissions of GHGs (CO2, N2O, CH4 and H2O) at all four airports during the study period were 1.11 × 103, 1.76 × 10-2, -1.85 × 10-3 and 3.84 × 108 kt yr-1, respectively. The emissions of air pollutants (NOx, CO, VOCs and particulate matter) were 5.20, 4.12, 7.46 × 10-1 and 3.37 × 10-2 kt yr-1, respectively. The negative CH4 emission indicates the consumption of atmospheric CH4 in the engine. The monthly and daily emissions of GHGs and air pollutants showed no significant variations at all airports examined. The emissions of GHGs and air pollutants for each aircraft operational mode differed considerably, with the largest emission observed in taxi-out mode.

  20. Decreasing emissions of NOx relative to CO2 in East Asia inferred from satellite observations

    NASA Astrophysics Data System (ADS)

    Reuter, M.; Buchwitz, M.; Hilboll, A.; Richter, A.; Schneising, O.; Hilker, M.; Heymann, J.; Bovensmann, H.; Burrows, J. P.

    2014-11-01

    At present, global CO2 emission inventories are mainly based on bottom-up estimates that rely, for example, on reported fossil fuel consumptions and fuel types. The associated uncertainties propagate into the CO2-to-NOx emission ratios that are used in pollution prediction and monitoring, as well as into biospheric carbon fluxes derived by inverse models. Here we analyse simultaneous and co-located satellite retrievals from SCIAMACHY (ref. ; SCanning Imaging Absorption SpectroMeter for Atmospheric CHartographY) of the column-average dry-air mole fraction of CO2 (refs , ) and NO2 (refs , , ) for the years 2003-2011 to provide a top-down estimate of trends in emissions and in the ratio between CO2 and NOx emissions. Our analysis shows that the CO2-to-NOx emission ratio has increased by 4.2 +/- 1.7% yr-1 in East Asia. In this region, we find a large positive trend of CO2 emissions (9.8 +/- 1.7% yr-1), which we largely attribute to the growing Chinese economy. This trend exceeds the positive trend of NOx emissions (5.8 +/- 0.9% yr-1). Our findings suggest that the recently installed and renewed technology in East Asia, such as power plants, transportation and so on, is cleaner in terms of NOx emissions than the old infrastructure, and roughly matches relative emission levels in North America and Europe.

  1. Evaluating Texas NOx emissions using satellite-based observations and model simulations

    NASA Astrophysics Data System (ADS)

    Frost, G. J.; Kim, S.; McKeen, S.; Cooper, O.; Hsie, E.; Trainer, M.; Heckel, A.; Richter, A.; Burrows, J.; Gleason, J.

    2008-12-01

    Anthropogenic NOx is produced primarily from fossil fuel combustion by motor vehicles, power generation, and industrial processes. Satellite-based measurements have been used to assess NOx emission trends on regional to global spatial scales and daily to annual temporal scales. The small horizontal footprints of current satellite-borne instruments, including SCIAMACHY and OMI, can be used to detect NO2 resulting from NOx emitted by isolated point sources and metropolitan areas in the western US. In this study we examine NOx emissions in the state of Texas by comparing NO2 vertical columns retrieved from these satellite instruments to those predicted by a regional chemical-transport model. Comparisons of satellite-derived and model- calculated NO2 columns over US power plants, where in-stack emission monitoring is carried out, enables a critical evaluation of the key parameters leading to uncertainties in the satellite and model data products. By using the satellite retrieval algorithms and model configurations that produce the best agreement in NO2 columns over power plants in northeastern Texas and elsewhere in the western US, satellite-model comparisons of NO2 columns over Texas cities in turn allow urban NOx emission inventories to be assessed. This work focuses on two large Texas metropolitan areas: Dallas/Fort Worth, where NOx is emitted predominantly by mobile and area-wide sources; and Houston, which, like Dallas, has typical urban sources, but also contains large industrial point sources emitting significant amounts of NOx. Year-to-year and day-of- week changes in the satellite data are used to infer NOx emission trends from point and mobile sources and to evaluate the effectiveness of NOx controls on some of these sources.

  2. 78 FR 65554 - Exhaust Emission Standards for New Aircraft Turbine Engines and Identification Plate for Aircraft...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-11-01

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF TRANSPORTATION Federal Aviation Administration 14 CFR Parts 34 and 45 RIN 2120-AK15 Exhaust Emission Standards for New Aircraft Turbine Engines and Identification Plate for Aircraft Engines Correction In rule document 2013-24712, appearing on pages 63015-63017...

  3. CHARACTERIZATION OF ROTATING-WING AIRCRAFT EMISSIONS

    SciTech Connect

    Cheng, Mengdawn; Corporan, E.; Mahurin, Shannon Mark; DeWitt, M.

    2007-01-01

    Rotating-wing aircraft or helicopters are heavily used by the US military to transport cargo, troops and personnel, and perform combat missions. Similar helicopter engines (those from the Chinook helicopter, for example) are being used by civilian companies to lift and transport heavy loads. Emissions data for this type of engines are limited but are important for development and design of air quality control strategy for military installations and bases in the country that are surrounded by cities and metropolitan areas. Major gaseous, selected air toxics, and particulate emissions data from helicopters were measured for T700-GE-700 and T700-GE-701C running JP-8 and Fischer-Tropsch fuels in separate engine exhaust tests. Each engine-fuel combination test was run at three engine power levels from idle to maximum in sequence in each test in June 2007 at Hunter Army Airfield (HAAF) in Savannah, GA. The emissions from these engines were smaller than those (T33 and T56) tested earlier in terms of gas concentrations and particulate mass/number concentration. The mode diameter of a particle size distribution obtained from a test run throughout the whole campaign was smaller than 100 nm by a research-grade fast scanning mobility particle sizer, which was confirmed by a commercial scanning mobility particle sizer taking sample from a collocated position right at the engine exhaust exit plane. Use of FT fuel led to reduced particulate and gaseous emissions as compared to the use of JP-8 fuel on the same engine. Production of nanoparticles (with mobility diameter smaller than 20 nm) by the engine running on JP-8 fuel was clearly observed using a nano-DMA equipped scanning mobility particle sizer a few meters downstream from the engine exhaust plane. The production was proportional to the engine power setting, and likely to be caused by the sulfur content in the JP-8 fuel. Sulfate/sulfur data measured at the engine exhaust and the same downstream location supports such a

  4. Assimilated inversion of NOx emissions over east Asia using OMI NO2 column measurements

    NASA Astrophysics Data System (ADS)

    Zhao, Chun; Wang, Yuhang

    2009-03-01

    Assimilated inversion on a daily basis using OMI tropospheric NO2 columns is developed and applied in a regional chemical transport model (REAM) to constrain fossil fuel (FF) NOx emissions over east Asia in 2007. The iterative nature of the assimilated inversion improves upon the widely used monthly-mean inversion by accounting for the chemical feedbacks of changed NOx emissions and reducing the dependence of the a priori emissions. The assimilated a posteriori emissions from FF combustion over east Asia are 9.5 Tg N/yr comparable to 10.9 Tg N/yr of the a priori. Significant changes in the spatial distribution of FF NOx emissions are found in the assimilated inversion from the a priori or monthly-mean inversion. The assimilated inversion shows that the a priori FF NOx emission inventory tends to overestimate the emissions over the economically developed areas and underestimate over the underdeveloped areas in East China, which may reflect in part FF NOx emission reductions resulting from the urban-centric air quality controls in China.

  5. Improving NO(x) cap-and-trade system with adjoint-based emission exchange rates.

    PubMed

    Mesbah, S Morteza; Hakami, Amir; Schott, Stephan

    2012-11-01

    Cap-and-trade programs have proven to be effective instruments for achieving environmental goals while incurring minimum cost. The nature of the pollutant, however, affects the design of these programs. NO(x), an ozone precursor, is a nonuniformly mixed pollutant with a short atmospheric lifetime. NO(x) cap-and-trade programs in the U.S. are successful in reducing total NO(x) emissions but may result in suboptimal environmental performance because location-specific ozone formation potentials are neglected. In this paper, the current NO(x) cap-and-trade system is contrasted to a hypothetical NO(x) trading policy with sensitivity-based exchange rates. Location-specific exchange rates, calculated through adjoint sensitivity analysis, are combined with constrained optimization for prediction of NO(x) emissions trading behavior and post-trade ozone concentrations. The current and proposed policies are examined in a case study for 218 coal-fired power plants that participated in the NO(x) Budget Trading Program in 2007. We find that better environmental performance at negligibly higher system-wide abatement cost can be achieved through inclusion of emission exchange rates. Exposure-based exchange rates result in better environmental performance than those based on concentrations. PMID:23050674

  6. Evaluating NOx emission inventories for regulatory air quality modeling using satellite and air quality model data

    NASA Astrophysics Data System (ADS)

    Kemball-Cook, Susan; Yarwood, Greg; Johnson, Jeremiah; Dornblaser, Bright; Estes, Mark

    2015-09-01

    The purpose of this study was to assess the accuracy of NOx emissions in the Texas Commission on Environmental Quality's (TCEQ) State Implementation Plan (SIP) modeling inventories of the southeastern U.S. We used retrieved satellite tropospheric NO2 columns from the Ozone Monitoring Instrument (OMI) together with NO2 columns from the Comprehensive Air Quality Model with Extensions (CAMx) to make top-down NOx emissions estimates using the mass balance method. Two different top-down NOx emissions estimates were developed using the KNMI DOMINO v2.0 and NASA SP2 retrievals of OMI NO2 columns. Differences in the top-down NOx emissions estimates made with these two operational products derived from the same OMI radiance data were sufficiently large that they could not be used to constrain the TCEQ NOx emissions in the southeast. The fact that the two available operational NO2 column retrievals give such different top-down NOx emissions results is important because these retrievals are increasingly being used to diagnose air quality problems and to inform efforts to solve them. These results reflect the fact that NO2 column retrievals are a blend of measurements and modeled data and should be used with caution in analyses that will inform policy development. This study illustrates both benefits and challenges of using satellite NO2 data for air quality management applications. Comparison with OMI NO2 columns pointed the way toward improvements in the CAMx simulation of the upper troposphere, but further refinement of both regional air quality models and the NO2 column retrievals is needed before the mass balance and other emission inversion methods can be used to successfully constrain NOx emission inventories used in U.S. regulatory modeling.

  7. Esimating the emission of photopollutants from the city of Lagos from aircraft observations

    NASA Astrophysics Data System (ADS)

    Evans, M. J.; Hopkins, J.; Lee, J.; Lewis, A.; Marsham, J.; Parker, D.; Stewart, D.; Capes, G.; Williams, P.; Crosier, J.

    2007-12-01

    The city of Lagos, Nigeria is the second most populated city in Africa and by 2020 is likely to be the most populated. During the AMMA campaign in 2006 the UK BAe146 aircraft flew an orbit around the city observing the concentration of key photo-pollutants. This allowed the fluxes and thus emissions from the city to be calculated. We calculate CO, NOx and VOC emissions to be on the order of 1 Tg (CO) yr-1, 0.01 Tg (N) yr-1, 0.2 Tg (VOC) yr-1 respectively. Based upon a principal components analysis of the observations we split the emissions due to evaporative, low temperature combustion and high temperature combustion.

  8. Reconciling NOx emissions reductions and ozone trends in the U.S., 2002-2006

    NASA Astrophysics Data System (ADS)

    Zhou, Wei; Cohan, Daniel S.; Napelenok, Sergey L.

    2013-05-01

    Dynamic evaluation seeks to assess the ability of photochemical models to replicate changes in air quality as emissions and other conditions change. When a model fails to replicate an observed change, a key challenge is to discern whether the discrepancy is caused by errors in meteorological simulations, errors in emission magnitudes and changes, or inaccurate responses of simulated pollutant concentrations to emission changes. In this study, the Community Multiscale Air Quality (CMAQ) model is applied to simulate the ozone (O3) change after the NOx SIP Call and mobile emission controls substantially reduced nitrogen oxides (NOx) emissions in the eastern U.S. from 2002 to 2006. For both modeled and observed O3, changes in episode average daily maximal 8-h O3 were highly correlated (R2 = 0.89) with changes in the 95th percentile, although the magnitudes of reductions increased nonlinearly at high percentile O3 concentrations. Observed downward changes in mean NOx (-11.6 to -2.5 ppb) and 8-h O3 (-10.4 to -4.7 ppb) concentrations in metropolitan areas in the NOx SIP Call region were under-predicted by 31%-64% and 26%-66%, respectively. The under-predicted O3 improvements in the NOx SIP Call region could not be explained by adjusting for temperature biases in the meteorological input, or by considering uncertainties in the chemical reaction rate constants. However, the under-prediction in O3 improvements could be alleviated by 5%-31% by constraining NOx emissions in each year based on observed NOx concentrations. This demonstrates the crucial need to accurately characterize changes in precursor emissions when dynamically evaluating a model's ability to simulate O3 responses to those changes.

  9. NOx Emissions from Large Point Sources: Variability in Ozone Production, Resulting Health Damages and Economic Costs

    NASA Astrophysics Data System (ADS)

    Mauzerall, D. L.; Sultan, B.; Kim, N.; Bradford, D.

    2004-12-01

    We present a proof-of-concept analysis of the measurement of the health damage of ozone (O3) produced from nitrogen oxides (NOx = NO + NO2) emitted by individual large point sources in the eastern United States. We use a regional atmospheric model of the eastern United States, the Comprehensive Air Quality Model with Extensions (CAMx), to quantify the variable impact that a fixed quantity of NOx emitted from individual sources can have on the downwind concentration of surface O3, depending on temperature and local biogenic hydrocarbon emissions. We also examine the dependence of resulting ozone-related health damages on the size of the exposed population. The investigation is relevant to the increasingly widely used "cap and trade" approach to NOx regulation, which presumes that shifts of emissions over time and space, holding the total fixed over the course of the summer O3 season, will have minimal effect on the environmental outcome. By contrast, we show that a shift of a unit of NOx emissions from one place or time to another could result in large changes in the health effects due to ozone formation and exposure. We indicate how the type of modeling carried out here might be used to attach externality-correcting prices to emissions. Charging emitters fees that are commensurate with the damage caused by their NOx emissions would create an incentive for emitters to reduce emissions at times and in locations where they cause the largest damage.

  10. A simplified reaction mechanism for prediction of NO(x) emissions in the combustion of hydrocarbons

    NASA Technical Reports Server (NTRS)

    Kundu, K. P.; Deur, J. M.

    1992-01-01

    A simplified reaction mechanism is developed for the prediction of NO(x) in hydrocarbon combustion. The mechanism uses fewer reacting species and reaction steps than the detailed mechanisms available in the literature and therefore takes less computer time when used in CFD calculations. The mechanism has been used to calculate NO(x) emissions in the combustion of propane. With slight modifications, the same mechanism can be used to calculate NO(x) in the combustion of other hydrocarbons. Results obtained with the simplified reaction are compared with experimental results and results obtained with a detailed kinetic mechanism.

  11. Influence of satellite-derived photolysis rates and NOx emissions on Texas ozone modeling

    NASA Astrophysics Data System (ADS)

    Tang, W.; Cohan, D. S.; Pour-Biazar, A.; Lamsal, L. N.; White, A. T.; Xiao, X.; Zhou, W.; Henderson, B. H.; Lash, B. F.

    2015-02-01

    Uncertain photolysis rates and emission inventory impair the accuracy of state-level ozone (O3) regulatory modeling. Past studies have separately used satellite-observed clouds to correct the model-predicted photolysis rates, or satellite-constrained top-down NOx emissions to identify and reduce uncertainties in bottom-up NOx emissions. However, the joint application of multiple satellite-derived model inputs to improve O3 state implementation plan (SIP) modeling has rarely been explored. In this study, Geostationary Operational Environmental Satellite (GOES) observations of clouds are applied to derive the photolysis rates, replacing those used in Texas SIP modeling. This changes modeled O3 concentrations by up to 80 ppb and improves O3 simulations by reducing modeled normalized mean bias (NMB) and normalized mean error (NME) by up to 0.1. A sector-based discrete Kalman filter (DKF) inversion approach is incorporated with the Comprehensive Air Quality Model with extensions (CAMx)-decoupled direct method (DDM) model to adjust Texas NOx emissions using a high-resolution Ozone Monitoring Instrument (OMI) NO2 product. The discrepancy between OMI and CAMx NO2 vertical column densities (VCDs) is further reduced by increasing modeled NOx lifetime and adding an artificial amount of NO2 in the upper troposphere. The region-based DKF inversion suggests increasing NOx emissions by 10-50% in most regions, deteriorating the model performance in predicting ground NO2 and O3, while the sector-based DKF inversion tends to scale down area and nonroad NOx emissions by 50%, leading to a 2-5 ppb decrease in ground 8 h O3 predictions. Model performance in simulating ground NO2 and O3 are improved using sector-based inversion-constrained NOx emissions, with 0.25 and 0.04 reductions in NMBs and 0.13 and 0.04 reductions in NMEs, respectively. Using both GOES-derived photolysis rates and OMI-constrained NOx emissions together reduces modeled NMB and NME by 0.05, increases the model

  12. The effect of functional forms of nitrogen on fuel-NOx emissions.

    PubMed

    Zhang, Linghui; Su, Dagen; Zhong, Mingfeng

    2015-01-01

    This work explores the effects of different nitrogen functional forms on fuel-NOx emissions at 900 °C. The majority of tests are performed with an excess air coefficient of 1.4. Fuel-NOx is detected by measuring N-(1-naphthyl) ethylenediamine dihydrochloride (C₁₂H₁₆Cl₂N₂) via spectrophotometry. The different functional forms of nitrogen in the raw materials are identified by using X-ray photoelectron spectroscopy (XPS). A reliable density functional theory (DFT) method at the B3LYP/6-311++G** level is employed to investigate the reaction pathways of all functional forms of nitrogen during combustion. The results indicate that the functional forms of nitrogen influence the formation of nitrogen oxides. While under the same experimental conditions, fuel-NOx emissions increase by using less activation energy and nitrogen-containing groups with poor thermal stability. It is determined that fuel-NOx emissions vary in the following order: glycine > pyrrole > pyridine > methylenedi-p-phenylene diisocyanate (MDI). Glycine is the chain structure of amino acids in waste-leather and has low activation energy and poor thermal stability. With these properties, it is noted that glycine produces the most fuel-NOx in all of the raw materials studied. More pyrrole than pyridine in coal lead to high yields of fuel-NOx. The lowest yields of fuel-NO x are obtained using polyurethanes in waste-PU.

  13. Simulation of NOx emission in circulating fluidized beds burning low-grade fuels

    SciTech Connect

    Afsin Gungor

    2009-05-15

    Nitrogen oxides are a major environmental pollutant resulting from combustion. This paper presents a modeling study of pollutant NOx emission resulting from low-grade fuel combustion in a circulating fluidized bed. The simulation model accounts for the axial and radial distribution of NOx emission in a circulating fluidized bed (CFB). The model results are compared with and validated against experimental data both for small-size and industrial-size CFBs that use different types of low-grade fuels given in the literature. The present study proves that CFB combustion demonstrated by both experimental data and model predictions produces low and acceptable levels of NOx emissions resulting from the combustion of low-grade fuels. Developed model can also investigate the effects of different operational parameters on overall NOx emission. As a result of this investigation, both experimental data and model predictions show that NOx emission increases with the bed temperature but decreases with excess air if other parameters are kept unchanged. 37 refs., 5 figs., 5 tabs.

  14. 40 CFR 76.7 - Revised NOX emission limitations for Group 1, Phase II boilers.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 17 2012-07-01 2012-07-01 false Revised NOX emission limitations for Group 1, Phase II boilers. 76.7 Section 76.7 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.7 Revised...

  15. 40 CFR 76.7 - Revised NOX emission limitations for Group 1, Phase II boilers.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Revised NOX emission limitations for Group 1, Phase II boilers. 76.7 Section 76.7 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.7 Revised...

  16. 40 CFR 76.7 - Revised NOX emission limitations for Group 1, Phase II boilers.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 16 2011-07-01 2011-07-01 false Revised NOX emission limitations for Group 1, Phase II boilers. 76.7 Section 76.7 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.7 Revised...

  17. 40 CFR 76.7 - Revised NOX emission limitations for Group 1, Phase II boilers.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 17 2014-07-01 2014-07-01 false Revised NOX emission limitations for Group 1, Phase II boilers. 76.7 Section 76.7 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.7 Revised...

  18. 40 CFR 76.7 - Revised NOX emission limitations for Group 1, Phase II boilers.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 17 2013-07-01 2013-07-01 false Revised NOX emission limitations for Group 1, Phase II boilers. 76.7 Section 76.7 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.7 Revised...

  19. The Impact of Buoyancy and Flame Structure on Soot, Radiation and NOx Emissions from a Turbulent Diffusion Flame

    NASA Technical Reports Server (NTRS)

    Kennedy, I. M.; Kollman, W.; VanderWal, R. L.

    1999-01-01

    It is hypothesized that the spatial structure of a turbulent diffusion flame plays an important role in determining the emissions of radiative energy, soot and NO, from a combustor. This structure, manifested in the two point statistics, is influenced by buoyancy. Radiation, soot and NOx emissions are the cumulative result of processes that occur throughout a flame. For example, radiation fluxes along a line of sight can be found from summing up the contributions from sources in individual pockets of hot soot that emit, and from sinks in cold soot that absorb. Soot and NOx are both the results of slow chemistry and are not equilibrium products. The time that is available for production and burnout is crucial in determining the eventual emissions of these pollutants. Turbulence models generally rely on a single point closure of the appropriate time averaged equations. Hence, spatial information is lost and needs to be modeled using solution variables such as turbulence kinetic energy and dissipation rate, often with the assumption of isotropy. However, buoyancy can affect the physical structure of turbulent flames and can change the spatial extent of soot bearing regions. Theoretical comparisons with models are best done in the limit of infinite Froude number because the inclusion of buoyancy in flow models introduces significant uncertainties. Hence, LII measurements of soot, measurements of radiation fluxes from soot, Particle Imaging Velocimetry (PIV) of the flow field and measurements of post flame NOX will be carried out on the NASA Lewis 2.2 sec drop tower and eventually on the parabolic flight aircraft. The drop rig will be a modified version of a unit that has been successfully used at Lewis in the past.

  20. Differences in satellite-derived NOx emission factors between Eurasian and North American boreal forest fires

    NASA Astrophysics Data System (ADS)

    Schreier, S. F.; Richter, A.; Schepaschenko, D.; Shvidenko, A.; Hilboll, A.; Burrows, J. P.

    2015-11-01

    Current fire emission inventories apply universal emission factors (EFs) for the calculation of NOx emissions over large biomes such as boreal forest. However, recent satellite-based studies over tropical and subtropical regions have indicated spatio-temporal variations in EFs within specific biomes. In this study, satellite measurements of tropospheric NO2 vertical columns (TVC NO2) from the GOME-2 instrument and fire radiative power (FRP) from MODIS are used for the estimation of fire emission rates (FERs) of NOx over Eurasian and North American boreal forests. The retrieval of TVC NO2 is based on a stratospheric correction using simulated stratospheric NO2 instead of applying the reference sector method, which was used in a previous study. The model approach is more suitable for boreal latitudes. TVC NO2 and FRP are spatially aggregated to a 1° × 1° horizontal resolution and temporally averaged to monthly values. The conversion of the satellite-derived tropospheric NO2 columns into production rates of NOx from fire (Pf) is based on the NO2/NOx ratio as obtained from the MACC reanalysis data set and an assumed lifetime of NOx. A global land cover map is used to define boreal forests across these two regions in order to evaluate the FERs of NOx for this biome. The FERs of NOx, which are derived from the gradients of the linear relationship between Pf and FRP, are more than 30% lower for North American than for Eurasian boreal forest fires. We speculate that these discrepancies are mainly related to the variable nitrogen content in plant tissues, which is higher in deciduous forests dominating large parts in Eurasia. In order to compare the obtained values with EFs found in the literature, the FERs are converted into EFs. The satellite-based EFs of NOx are estimated at 0.83 and 0.61 g kg-1 for Eurasian and North American boreal forests, respectively, which is in good agreement with the value found in a recent emission factor compilation. However, recent fire

  1. Waste Coal Fines Reburn for NOx and Mercury Emission Reduction

    SciTech Connect

    Stephen Johnson; Chetan Chothani; Bernard Breen

    2008-04-30

    Injection of coal-water slurries (CWS) made with both waste coal and bituminous coal was tested for enhanced reduction of NO{sub x} and Hg emissions at the AES Beaver Valley plant near Monaca, PA. Under this project, Breen Energy Solutions (BES) conducted field experiments on the these emission reduction technologies by mixing coal fines and/or pulverized coal, urea and water to form slurry, then injecting the slurry in the upper furnace region of a coal-fired boiler. The main focus of this project was use of waste coal fines as the carbon source; however, testing was also conducted using pulverized coal in conjunction with or instead of waste coal fines for conversion efficiency and economic comparisons. The host site for this research and development project was Unit No.2 at AES Beaver Valley cogeneration station. Unit No.2 is a 35 MW Babcock & Wilcox (B&W) front-wall fired boiler that burns eastern bituminous coal. It has low NO{sub x} burners, overfire air ports and a urea-based selective non-catalytic reduction (SNCR) system for NO{sub x} control. The back-end clean-up system includes a rotating mechanical ash particulate removal and electrostatic precipitator (ESP) and wet flue gas desulfurization (FGD) scrubber. Coal slurry injection was expected to help reduce NOx emissions in two ways: (1) Via fuel-lean reburning when the slurry is injected above the combustion zone. (2) Via enhanced SNCR reduction when urea is incorporated into the slurry. The mercury control process under research uses carbon/water slurry injection to produce reactive carbon in-situ in the upper furnace, promoting the oxidation of elemental mercury in flue gas from coal-fired power boilers. By controlling the water content of the slurry below the stoichiometric requirement for complete gasification, water activated carbon (WAC) can be generated in-situ in the upper furnace. As little as 1-2% coal/water slurry (heat input basis) can be injected and generate sufficient WAC for mercury

  2. 40 CFR 51.122 - Emissions reporting requirements for SIP revisions relating to budgets for NOX emissions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... reporting requirements of 40 CFR part 75, then the state need not provide an every-year cycle report to EPA... SIP revisions relating to budgets for NOX emissions. 51.122 Section 51.122 Protection of Environment... OF IMPLEMENTATION PLANS Control Strategy § 51.122 Emissions reporting requirements for SIP...

  3. 40 CFR 51.122 - Emissions reporting requirements for SIP revisions relating to budgets for NOX emissions.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... reporting requirements of 40 CFR part 75, then the state need not provide an every-year cycle report to EPA... SIP revisions relating to budgets for NOX emissions. 51.122 Section 51.122 Protection of Environment... OF IMPLEMENTATION PLANS Control Strategy § 51.122 Emissions reporting requirements for SIP...

  4. 40 CFR 75.19 - Optional SO2, NOX, and CO2 emissions calculation for low mass emissions (LME) units.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... rates in Table LM-2 of this section are inappropriately high for the unit, the owner or operator may use... interval, the owner or operator shall either report the appropriate default NOX emission rate from Table LM... example, use the default emission rates in Tables LM-1, LM-2, and LM-3 of this section or use the...

  5. NOx emission estimates during the 2014 Youth Olympic Games in Nanjing

    NASA Astrophysics Data System (ADS)

    Ding, J.; van der A, R. J.; Mijling, B.; Levelt, P. F.; Hao, N.

    2015-08-01

    The Nanjing Government applied temporary environmental regulations to guarantee good air quality during the Youth Olympic Games (YOG) in 2014. We study the effect of those regulations by applying the emission estimate algorithm DECSO (Daily Emission estimates Constrained by Satellite Observations) to measurements of the Ozone Monitoring Instrument (OMI). We improved DECSO by updating the chemical transport model CHIMERE from v2006 to v2013 and by adding an Observation minus Forecast (OmF) criterion to filter outlying satellite retrievals due to high aerosol concentrations. The comparison of model results with both ground and satellite observations indicates that CHIMERE v2013 is better performing than CHIMERE v2006. After filtering the satellite observations with high aerosol loads that were leading to large OmF values, unrealistic jumps in the emission estimates are removed. Despite the cloudy conditions during the YOG we could still see a decrease of tropospheric NO2 column concentrations of about 32 % in the OMI observations when compared to the average NO2 columns from 2005 to 2012. The results of the improved DECSO algorithm for NOx emissions show a reduction of at least 25 % during the YOG period and afterwards. This indicates that air quality regulations taken by the local government have an effect in reducing NOx emissions. The algorithm is also able to detect an emission reduction of 10 % during the Chinese Spring Festival. This study demonstrates the capacity of the DECSO algorithm to capture the change of NOx emissions on a monthly scale. We also show that the observed NO2 columns and the derived emissions show different patterns that provide complimentary information. For example, the Nanjing smog episode in December 2013 led to a strong increase in NO2 concentrations without an increase in NOx emissions. Furthermore, DECSO gives us important information on the non-trivial seasonal relation between NOx emissions and NO2 concentrations on a local scale.

  6. Lagrangian Hotspots of In-Use NOX Emissions from Transit Buses.

    PubMed

    Kotz, Andrew J; Kittelson, David B; Northrop, William F

    2016-06-01

    In-use, spatiotemporal NOX emissions were measured from a conventional powertrain transit bus and a series electric hybrid bus over gradients of route kinetic intensity and ambient temperature. This paper introduces a new method for identifying NOX emissions hotspots along a bus route using high fidelity Lagrangian vehicle data to explore spatial interactions that may influence emissions production. Our study shows that the studied transit buses emit higher than regulated emissions because on-route operation does not accurately represent the range of engine operation tested according to regulatory standards. Using the Lagrangian hotspot detection, we demonstrate that NOX hotspots occurred at bus stops, during cold starts, on inclines, and for accelerations. On the selected routes, bus stops resulted in 3.3 times the route averaged emissions factor in grams/km without significant dependence on bus type or climate. The buses also emitted 2.3 times the route averaged NOX emissions factor at the beginning of each route due to cold selective catalytic reduction aftertreatment temperature. The Lagrangian hotspot detection technique demonstrated here could be employed in future connected vehicles empowered by advances in computational power, data storage capability, and improved sensor technology to optimize emissions as a function of spatial location.

  7. Lagrangian Hotspots of In-Use NOX Emissions from Transit Buses.

    PubMed

    Kotz, Andrew J; Kittelson, David B; Northrop, William F

    2016-06-01

    In-use, spatiotemporal NOX emissions were measured from a conventional powertrain transit bus and a series electric hybrid bus over gradients of route kinetic intensity and ambient temperature. This paper introduces a new method for identifying NOX emissions hotspots along a bus route using high fidelity Lagrangian vehicle data to explore spatial interactions that may influence emissions production. Our study shows that the studied transit buses emit higher than regulated emissions because on-route operation does not accurately represent the range of engine operation tested according to regulatory standards. Using the Lagrangian hotspot detection, we demonstrate that NOX hotspots occurred at bus stops, during cold starts, on inclines, and for accelerations. On the selected routes, bus stops resulted in 3.3 times the route averaged emissions factor in grams/km without significant dependence on bus type or climate. The buses also emitted 2.3 times the route averaged NOX emissions factor at the beginning of each route due to cold selective catalytic reduction aftertreatment temperature. The Lagrangian hotspot detection technique demonstrated here could be employed in future connected vehicles empowered by advances in computational power, data storage capability, and improved sensor technology to optimize emissions as a function of spatial location. PMID:27135811

  8. Assessing the Impact of Aircraft Emissions on the Stratosphere

    NASA Technical Reports Server (NTRS)

    Kawa, S. R.; Anderson, D. E.

    1999-01-01

    For the past decade, the NASA Atmospheric Effects of Aviation Project (AEAP) has been the U.S. focal point for research on aircraft effects. In conjunction with U.S. basic research programs, AEAP and concurrent European research programs have driven remarkable progress reports released in 1999 [IPCC, 1999; Kawa et al., 1999]. The former report primarily focuses on aircraft effects in the upper troposphere, with some discussion on stratospheric impacts. The latter report focuses entirely on the stratosphere. The current status of research regarding aviation effects on stratospheric ozone and climate, as embodied by the findings of these reports, is reviewed. The following topics are addressed: Aircraft Emissions, Pollution Transport, Atmospheric Chemistry, Polar Processes, Climate Impacts of Supersonic Aircraft, Subsonic Aircraft Effect on the Stratosphere, Calculations of the Supersonic Impact on Ozone and Sensitivity to Input Conditions.

  9. Emissions of an AVCO Lycoming 0-320-DIAD air cooled light aircraft engine as a function of fuel-air ratio, timing, and air temperature and humidity

    NASA Technical Reports Server (NTRS)

    Meng, P. R.; Skorobatckyi, M.; Cosgrove, D. V.; Kempke, E. E., Jr.

    1976-01-01

    A carbureted aircraft engine was operated over a range of test conditions to establish the exhaust levels over the EPA seven-mode emissions cycle. Baseline (full rich production limit) exhaust emissions at an induction air temperature of 59 F and near zero relative humidity were 90 percent of the EPA standard for HC, 35 percent for NOx, and 161 percent for CO. Changes in ignition timing around the standard 25 deg BTDC from 30 deg BTDC to 20 deg BTDC had little effect on the exhaust emissions. Retarding the timing to 15 deg BTDC increased both the HC and CO emissions and decreased NOx emissions. HC and CO emissions decreased as the carburetor was leaned out, while NOx emissions increased. The EPA emission standards were marginally achieved at two leanout conditions. Variations in the quantity of cooling air flow over the engine had no effect on exhaust emissions. Temperature-humidity effects at the higher values of air temperature and relative humidity tested indicated that the HC and CO emissions increased significantly, while the NOx emissions decreased.

  10. Heavy-Duty Emissions Control: Plasma-Facilitated vs Reformer-Assisted Lean NOx Catalysis

    SciTech Connect

    Aardahl, C; Rozmiarek, R; Rappe, K; Mendoza, D Park, P

    2003-08-24

    Progress has been made in the control of combustion processes to limit the formation of environmentally harmful species, but lean burn vehicles, such as those powered by diesel engines used for the majority of commercial trucking and off-road applications, remain a major source of nitrogen oxides (NOx) and particulate matter (PM) emissions. Tighter control of the combustion process coupled with exhaust gas recirculation has brought emissions in line with 2004 targets worldwide. Additional modifications to the engine control system, somewhat limited NOx control, and PM filters will likely allow the 2007 limits to be met for the on-highway regulations for heavy-duty engines in the United States. Concern arises when the NOx emission limit of 0.2 g/bhphr set for the year 2010 is considered.

  11. A Portable Emissions Measurement System (PEMS) study of NOx and primary NO2 emissions from Euro 6 diesel passenger cars and comparison with COPERT emission factors

    NASA Astrophysics Data System (ADS)

    O'Driscoll, Rosalind; ApSimon, Helen M.; Oxley, Tim; Molden, Nick; Stettler, Marc E. J.; Thiyagarajah, Aravinth

    2016-11-01

    Real world emissions of oxides of nitrogen (NOx) often greatly exceed those achieved in the laboratory based type approval process. In this paper the real world emissions from a substantial sample of the latest Euro 6 diesel passenger cars are presented with a focus on NOx and primary NO2. Portable Emissions Measurement System (PEMS) data is analysed from 39 Euro 6 diesel passenger cars over a test route comprised of urban and motorway sections. The sample includes vehicles installed with exhaust gas recirculation (EGR), lean NOx traps (LNT), or selective catalytic reduction (SCR). The results show wide variability in NOx emissions from 1 to 22 times the type approval limit. The average NOx emission, 0.36 (sd. 0.36) g km-1, is 4.5 times the Euro 6 limit. The average fraction primary NO2 (fNO2) is 44 (sd. 20) %. Higher emissions during the urban section of the route are attributed to an increased number of acceleration events. Comparisons between PEMS measurements and COPERT speed dependent emissions factors show PEMS measurements to be on average 1.6 times higher than COPERT estimates for NOx and 2.5 times for NO2. However, by removing the 5 most polluting vehicles average emissions were reduced considerably.

  12. Experimental Assessment of NOx Emissions from 73 Euro 6 Diesel Passenger Cars.

    PubMed

    Yang, Liuhanzi; Franco, Vicente; Mock, Peter; Kolke, Reinhard; Zhang, Shaojun; Wu, Ye; German, John

    2015-12-15

    Controlling nitrogen oxides (NOx) emissions from diesel passenger cars during real-world driving is one of the major technical challenges facing diesel auto manufacturers. Three main technologies are available for this purpose: exhaust gas recirculation (EGR), lean-burn NOx traps (LNT), and selective catalytic reduction (SCR). Seventy-three Euro 6 diesel passenger cars (8 EGR only, 40 LNT, and 25 SCR) were tested on a chassis dynamometer over both the European type-approval cycle (NEDC, cold engine start) and the more realistic Worldwide harmonized light-duty test cycle (WLTC version 2.0, hot start) between 2012 and 2015. Most vehicles met the legislative limit of 0.08 g/km of NOx over NEDC (average emission factors by technology: EGR-only 0.07 g/km, LNT 0.04 g/km, and SCR 0.05 g/km), but the average emission factors rose dramatically over WLTC (EGR-only 0.17 g/km, LNT 0.21 g/km, and SCR 0.13 g/km). Five LNT-equipped vehicles exhibited very poor performance over the WLTC, emitting 7-15 times the regulated limit. These results illustrate how diesel NOx emissions are not properly controlled under the current, NEDC-based homologation framework. The upcoming real-driving emissions (RDE) regulation, which mandates an additional on-road emissions test for EU type approvals, could be a step in the right direction to address this problem.

  13. The impact of satellite-adjusted NOx emissions on simulated NOx and O3 discrepancies in the urban and outflow areas of the Pacific and Lower Middle US

    NASA Astrophysics Data System (ADS)

    Choi, Y.

    2013-08-01

    We analyze the simulation results from a CMAQ model and GOME-2 NO2 retrievals over the United States for August~2009 to estimate the model-simulated biases of NOx concentrations over six geological regions (Pacific Coast = PC, Rocky Mountains = RM, Lower Middle = LM, Upper Middle = UM, Southeast = SE, Northeast = NE). By comparing GOME-2 NO2 columns to corresponding CMAQ NO2 columns, we produced satellite-adjusted NOx emission ("GOME2009") and compared baseline emission ("BASE2009") CMAQ simulations with GOME2009 CMAQ runs. We found that the latter exhibited decreases of -5.6%, -12.3%, -21.3%, and -15.9% over the PC, RM, LM, and SE regions, respectively, and increases of +2.3% and +10.0% over the UM and NE regions. In addition, we found that changes in NOx emissions generally mitigate discrepancies between the surface NOx concentrations of baseline CMAQ and those of AQS at EPA AQS stations (mean bias of +19.8% to -13.7% over PC, -13.8% to -36.7% over RM, +149.7% to -1.8% over LM, +22.5% to -7.8% over UM, +31.3% to -7.9% over SE, and +11.6% to +0.7% over NE). The relatively high simulated NOx biases from baseline CMAQ over LM (+149.7%) are likely the results of over-predictions of simulated NOx emissions, which could shed light on those from global/regional Chemical Transport Models. We also perform more detailed investigations on surface NOx and O3 concentrations in two urban and outflow areas, PC (e.g., Los Angeles, South Pasadena, Anaheim, La Habra and Riverside) and LM (e.g., Houston, Beaumont and Sulphur). From two case studies, we found that the GOME2009 emissions decreased surface NOx concentrations significantly in the urban areas of PC (up to 30 ppbv) and in those of LM (up to 10 ppbv) during the daytime and that simulated NOx concentrations from CMAQ with GOME2009 compare well to those of in-situ AQS observations. A significant reduction in NOx concentrations resulted in a comparable increase in surface O3 concentrations in the urban areas of PC (up to 30

  14. The impact of satellite-adjusted NOx emissions on simulated NOx and O3 discrepancies in the urban and outflow areas of the Pacific and Lower Middle US

    NASA Astrophysics Data System (ADS)

    Choi, Y.

    2014-01-01

    We analyze the simulation results from a CMAQ model and GOME-2 NO2 retrievals over the United States for August 2009 to estimate the model-simulated biases of NOx concentrations over six geological regions (Pacific Coast = PC, Rocky Mountains = RM, Lower Middle = LM, Upper Middle = UM, Southeast = SE, Northeast = NE). By comparing GOME-2 NO2 columns to corresponding CMAQ NO2 columns, we produced satellite-adjusted NOx emission ("GOME2009") and compared baseline emission ("BASE2009") CMAQ simulations with GOME2009 CMAQ runs. We found that the latter exhibited decreases of -5.6%, -12.3%, -21.3%, and -15.9 % over the PC, RM, LM, and SE regions, respectively, and increases of +2.3% and +10.0% over the UM and NE regions. In addition, we found that changes in NOx emissions generally mitigate discrepancies between the surface NOx concentrations of baseline CMAQ and those of AQS at EPA AQS stations (mean bias of +19.8% to -13.7% over PC, -13.8% to -36.7% over RM, +149.7% to -1.8% over LM, +22.5% to -7.8% over UM, +31.3% to -7.9% over SE, and +11.6% to +0.7% over NE). The relatively high simulated NOx biases from baseline CMAQ over LM (+149.7%) are likely the results of over-predictions of simulated NOx emissions, which could shed light on those from global/regional Chemical Transport Models. We also perform more detailed investigations on surface NOx and O3 concentrations in two urban and outflow areas, PC (e.g., Los Angeles, South Pasadena, Anaheim, La Habra and Riverside) and LM (e.g., Houston, Beaumont and Sulphur). From two case studies, we found that the GOME2009 emissions decreased surface NOx concentrations significantly in the urban areas of PC (up to 30 ppbv) and in those of LM (up to 10 ppbv) during the daytime and that simulated NOx concentrations from CMAQ with GOME2009 compare well to those of in-situ AQS observations. A significant reduction in NOx concentrations resulted in a comparable increase in surface O3 concentrations in the urban areas of PC (up to 30

  15. 40 CFR 75.17 - Specific provisions for monitoring emissions from common, bypass, and multiple stacks for NOX...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... reduction program must also meet the provisions for monitoring NOX emission rate in §§ 75.71 and 75.72. (a... operating properly, as described in the quality assurance/quality control program for the unit, required by... record parametric data to verify the proper operation of the NOX add-on emission controls as described...

  16. 40 CFR 75.17 - Specific provisions for monitoring emissions from common, bypass, and multiple stacks for NOX...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... reduction program must also meet the provisions for monitoring NOX emission rate in §§ 75.71 and 75.72. (a... operating properly, as described in the quality assurance/quality control program for the unit, required by... record parametric data to verify the proper operation of the NOX add-on emission controls as described...

  17. Propulsion Investigation for Zero and Near-Zero Emissions Aircraft

    NASA Technical Reports Server (NTRS)

    Snyder, Christopher A.; Berton, Jeffrey J.; Brown, Gerald v.; Dolce, James L.; Dravid, Marayan V.; Eichenberg, Dennis J.; Freeh, Joshua E.; Gallo, Christopher A.; Jones, Scott M.; Kundu, Krishna P.; Marek, Cecil J.; Millis, Marc G.; Murthy, Pappu L.; Roach, Timothy M.; Smith, Timothy D.; Stefko, George L.; Sullivan, Roy M.; Tornabene, Robert T.; Geiselhat, Karl A.; Kascak, Albert F.

    2009-01-01

    As world emissions are further scrutinized to identify areas for improvement, aviation s contribution to the problem can no longer be ignored. Previous studies for zero or near-zero emissions aircraft suggest aircraft and propulsion system sizes that would perform propulsion system and subsystems layout and propellant tankage analyses to verify the weight-scaling relationships. These efforts could be used to identify and guide subsequent work on systems and subsystems to achieve viable aircraft system emissions goals. Previous work quickly focused these efforts on propulsion systems for 70- and 100-passenger aircraft. Propulsion systems modeled included hydrogen-fueled gas turbines and fuel cells; some preliminary estimates combined these two systems. Hydrogen gas-turbine engines, with advanced combustor technology, could realize significant reductions in nitrogen emissions. Hydrogen fuel cell propulsion systems were further laid out, and more detailed analysis identified systems needed and weight goals for a viable overall system weight. Results show significant, necessary reductions in overall weight, predominantly on the fuel cell stack, and power management and distribution subsystems to achieve reasonable overall aircraft sizes and weights. Preliminary conceptual analyses for a combination of gas-turbine and fuel cell systems were also performed, and further studies were recommended. Using gas-turbine engines combined with fuel cell systems can reduce the fuel cell propulsion system weight, but at higher fuel usage than using the fuel cell only.

  18. Effects of reducing SO2 and NOx emission from ships on air quality in Alaska

    NASA Astrophysics Data System (ADS)

    Tran, T. T.; Mölders, N.

    2011-12-01

    We performed simulations with the Alaska-adapted WRF/Chem using the same meteorological conditions of January 2000, but alternatively applying the emissions of 2000 (REF), emissions of 2000 with the ship-emission reductions for the planned North American Emission Contral Area (ECA) for SO2 only (ECA1) and SO2 and NOx (ECA2) that have been proposed by the International Maritime Organization for 2015. The analysis focused on the air quality along the international shipping lanes (ISL), in the ECA and over Alaska (AK). Our goal is to examine how the decreases in ship emissions in the ISL and ECA affect to air quality in Alaska. Our model results show that reducing SO2 and NOx ship-emissions reduces the concentration of sulfur and nitrogen compounds over Alaska despite of no changes in Alaska emissions. The reductions of pollutants over the ISL, ECA and AK stemming from concurrent SO2-NOx ship emission reductions are an order of magnitude of those stemming from SO2 reduction in ship emissions only. Reductions in sulfur compounds reach up to 14km while reductions of nitrogen compounds reach to only about 7km. Reductions of sulfate and nitrate in clouds are highest at the top of the boundary layer. Among the three regions of interest, strongest reductions occur over the ECA and ISL for sulfur and nitrogen compounds, respectively, since the ECA (ISL) has highest reductions of SO2 (NOx). The PM2.5 speciation partitioning over all three regions marginally changes when the ship emissions change. Sulfate is the major component of PM2.5 in all regions. Closer to the land, organic carbon (OC) partitioning is higher indicating the enhancing impacts of inland anthropogenic emissions to total PM2.5 concentrations over land.

  19. NOx lifetimes and emissions of cities and power plants in polluted background estimated by satellite observations

    NASA Astrophysics Data System (ADS)

    Liu, Fei; Beirle, Steffen; Zhang, Qiang; Dörner, Steffen; He, Kebin; Wagner, Thomas

    2016-04-01

    We present a new method to quantify NOx emissions and corresponding atmospheric lifetimes from OMI NO2 observations together with ECMWF wind fields without further model input for sources located in a polluted background. NO2 patterns under calm wind conditions are used as proxy for the spatial patterns of NOx emissions, and the effective atmospheric NOx lifetime is determined from the change of spatial patterns measured at larger wind speeds. Emissions are subsequently derived from the NO2 mass above the background, integrated around the source of interest. Lifetimes and emissions are estimated for 17 power plants and 53 cities located in non-mountainous regions across China and the USA. The derived lifetimes for the ozone season (May-September) are 3.8 ± 1.0 h (mean ± standard deviation) with a range of 1.8 to 7.5 h. The derived NOx emissions show generally good agreement with bottom-up inventories for power plants and cities. Regional inventory shows better agreement with top-down estimates for Chinese cities compared to global inventory, most likely due to different downscaling approaches adopted in the two inventories.

  20. The climate impact of ship NOx emissions: an improved estimate accounting for plume chemistry

    NASA Astrophysics Data System (ADS)

    Holmes, C. D.; Prather, M. J.; Vinken, G. C. M.

    2014-07-01

    Nitrogen oxide (NOx) emissions from maritime shipping produce ozone (O3) and hydroxyl radicals (OH), which in turn destroy methane (CH4). The balance between this warming (due to O3) and cooling (due to CH4) determines the net effect of ship NOx on climate. Previous estimates of the chemical impact and radiative forcing (RF) of ship NOx have generally assumed that plumes of ship exhaust are instantly diluted into model grid cells spanning hundreds of kilometers, even though this is known to produce biased results. Here we improve the parametric representation of exhaust-gas chemistry developed in the GEOS-Chem chemical transport model (CTM) to provide the first estimate of RF from shipping that accounts for sub-grid-scale ship plume chemistry. The CTM now calculates O3 production and CH4 loss both within and outside the exhaust plumes and also accounts for the effect of wind speed. With the improved modeling of plumes, ship NOx perturbations are smaller than suggested by the ensemble of past global modeling studies, but if we assume instant dilution of ship NOx on the grid scale, the CTM reproduces previous model results. Our best estimates of the RF components from increasing ship NOx emissions by 1 Tg(N) yr-1 are smaller than that given in the past literature: + 3.4 ± 0.85 mW m-2 (1σ confidence interval) from the short-lived ozone increase, -5.7 ± 1.3 mW m-2 from the CH4 decrease, and -1.7 ± 0.7 mW m-2 from the long-lived O3 decrease that accompanies the CH4 change. The resulting net RF is -4.0 ± 2.0 mW m-2 for emissions of 1 Tg(N) yr-1. Due to non-linearity in O3 production as a function of background NOx, RF from large changes in ship NOx emissions, such as the increase since preindustrial times, is about 20% larger than this RF value for small marginal emission changes. Using sensitivity tests in one CTM, we quantify sources of uncertainty in the RF components and causes of the ±30% spread in past model results; the main source of uncertainty is the

  1. NO and NO2 emission ratios measured from in-use commercial aircraft during taxi and takeoff.

    PubMed

    Herndon, Scott C; Shorter, Joanne H; Zahniser, Mark S; Nelson, David D; Jayne, John; Brown, Robert C; Miake-Lye, Richard C; Waitz, Ian; Silva, Phillip; Lanni, Thomas; Demerjian, Ken; Kolb, Charles E

    2004-11-15

    In August 2001, the Aerodyne Mobile Laboratory simultaneously measured NO, NO2, and CO2 within 350 m of a taxiway and 550 m of a runway at John F. Kennedy Airport. The meteorological conditions were such that taxi and takeoff plumes from individual aircraft were clearly resolved against background levels. NO and NO2 concentrations were measured with 1 s time resolution using a dual tunable infrared laser differential absorption spectroscopy instrument, utilizing an astigmatic multipass Herriott cell. The CO2 measurements were also obtained at 1 s time resolution using a commercial non-dispersive infrared absorption instrument. Plumes were measured from over 30 individual planes, ranging from turbo props to jumbo jets. NOx emission indices were determined by examining the correlation between NOx (NO + NO2) and CO2 during the plume measurements. Several aircraft tail numbers were unambiguously identified, allowing those specific airframe/engine combinations to be determined. The resulting NOx emission indices from positively identified in-service operating airplanes are compared with the published International Civil Aviation Organization engine certification test database collected on new engines in certification test cells.

  2. Evaluation of the impacts of biodiesel and second generation biofuels on NO(x) emissions for CARB diesel fuels.

    PubMed

    Hajbabaei, Maryam; Johnson, Kent C; Okamoto, Robert A; Mitchell, Alexander; Pullman, Marcie; Durbin, Thomas D

    2012-08-21

    The impact of biodiesel and second generation biofuels on nitrogen oxides (NO(x)) emissions from heavy-duty engines was investigated using a California Air Resources Board (CARB) certified diesel fuel. Two heavy-duty engines, a 2006 engine with no exhaust aftertreatment, and a 2007 engine with a diesel particle filter (DPF), were tested on an engine dynamometer over four different test cycles. Emissions from soy- and animal-based biodiesels, a hydrotreated renewable diesel, and a gas to liquid (GTL) fuel were evaluated at blend levels from 5 to 100%. NO(x) emissions consistently increased with increasing biodiesel blend level, while increasing renewable diesel and GTL blends showed NO(x) emissions reductions with blend level. NO(x) increases ranged from 1.5% to 6.9% for B20, 6.4% to 18.2% for B50, and 14.1% to 47.1% for B100. The soy-biodiesel showed higher NO(x) emissions increases compared to the animal-biodiesel. NO(x) emissions neutrality with the CARB diesel was achieved by blending GTL or renewable diesel fuels with various levels of biodiesel or by using di-tert-butyl peroxide (DTBP). It appears that the impact of biodiesel on NO(x) emissions might be a more important consideration when blended with CARB diesel or similar fuels, and that some form of NO(x) mitigation might be needed for biodiesel blends with such fuels.

  3. Constraining NOx emissions using satellite NO2 measurements during 2013 DISCOVER-AQ Texas campaign

    NASA Astrophysics Data System (ADS)

    Souri, Amir Hossein; Choi, Yunsoo; Jeon, Wonbae; Li, Xiangshang; Pan, Shuai; Diao, Lijun; Westenbarger, David A.

    2016-04-01

    Reliable emission inventories are key to precisely model air pollutant concentrations. The relatively large reduction in NOx emissions that is well corroborated by satellite and in-situ observations over southeast Texas has resulted in discrepancies between observations and regional model simulations based on the National Emission Inventory (NEI) provided every three years in U.S. In this study, a Bayesian inversion of OMI tropospheric NO2 is conducted to update anthropogenic sources of NEI-2011 and soil-biogenic sources from BEIS3 (Biogenic Emission Inventory System version 3) over southeast Texas and west Louisiana during the 2013 DISCOVER-AQ Texas campaign. Results reveal that influences of the a priori profile used in OMI NO2 retrieval play a significant role in inconsistencies between model and satellite observations, which should be mitigated. A posteriori emissions are produced using the regional Community Multiscale Air Quality (CMAQ) model associated with Decoupled Direct Method (DDM) sensitivity analysis. The inverse estimate suggests a reduction in area (44%), mobile (30%), and point sources (60%) in high NOx areas (ENOx> 0.2 mol/s), and an increase in soil (∼52%) and area emissions (37%) in low NOx regions (ENOx< 0.02 mol/s). The reductions in anthropogenic sources in high NOx regions are attributed to both uncertainty of the priori and emissions policies, while increases in area and soil-biogenic emissions more likely resulted from under-estimation of ships emissions, and the Yienger- Levy scheme used in BEIS respectively. In order to validate the accuracy of updated NOx emissions, CMAQ simulation was performed and results were evaluated with independent surface NO2 measurements. Comparing to surface monitoring sites, we find improvements (before and after inverse modeling) for MB (1.95, -0.30 ppbv), MAB (3.65, 2.60 ppbv), RMSE (6.13, 4.37 ppbv), correlation (0.68, 0.69), and IOA (0.76, 0.82). The largest improvement is seen for morning time surface

  4. Fuel-Air Mixing Effect on Nox Emissions for a Lean Premixed-Prevaporized Combustion System

    NASA Technical Reports Server (NTRS)

    Lee, Chi-Ming; Chun, Kue S.; Locke, Randy J.

    1995-01-01

    The lean premixed-prevaporized (LPP) concept effectively meets low nitrogen oxides (NOx) emission requirements for combustors with the high inlet temperature and pressure typical of the High-Speed Civil Transport (HSCT). For the LPP system fuel-air mixture uniformity is probably the most important factor for low NOx emissions. Previous studies have suggested that the fuel-air mixture uniformity can be severely affected by changing the number and configuration of fuel injection points. Therefore, an experimental study was performed to determine how the number of fuel injection points and their arrangement affect NOx emissions from an LPP system. The NOx emissions were measured by a gas-sampling probe in a flame-tube rig at the following conditions: inlet temperature of 810 K (1000 F), rig pressure of 10 atm, reference velocity of 150 ft/s, and residence time near 0.005 s. Additionally, a focused Schlieren diagnostic technique coupled with a high speed camera was used to provide a qualitative description of the spatial flow field.

  5. Ozone Trends Across the United States over a Period of Decreasing NOx and VOC Emissions

    EPA Science Inventory

    In this work, we evaluate ambient ozone trends at urban, suburban, and rural monitoring sites across the United States over a period of decreasing NOx and VOC emissions (1998–2013). We find that decreasing ozone trends generally occur in the summer, in less urbanized areas,...

  6. PHOTOCHEMICAL EFFECTS ON NOX AND CO EMISSIONS IN A BRAZILIAN SAVANNA

    EPA Science Inventory

    Land clearing and burning in the tropics often results in increased solar irradiation of soil and surface organic matter. This increased light exposure may impact the emissions of nitrogen oxides (NOx) and carbon monoxide (CO), trace gases that play an important role in troposph...

  7. NOX AND CO EMISSIONS FROM SOIL AND SURFACE LITTER IN A BRAZILIAN SAVANNA

    EPA Science Inventory

    Land clearing and burning in the tropics often results in increased solar irradiation of soil and surface organic matter. This increased light exposure and surface heating may impact the emissions of nitrogen oxides (NOx) and carbon monoxide (CO), trace gases that play an importa...

  8. 40 CFR 96.154 - Compliance with CAIR NOX emissions limitation.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 21 2014-07-01 2014-07-01 false Compliance with CAIR NOX emissions limitation. 96.154 Section 96.154 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... section, on a first-in, first-out (FIFO) accounting basis in the following order: (i) Any CAIR...

  9. INVESTIGATION OF SELECTIVE CATALYTIC REDUCTION IMPACT ON MERCURY SPECIATION UNDER SIMULATED NOX EMISSION CONTROL CONDITIONS

    EPA Science Inventory

    Selective catalytic reduction (SCR) technology is being increasingly applied for controlling emissions of nitrogen oxides (NOx) from coal-fired boilers. Some recent field and pilot studies suggest that the operation of SCR could affect the chemical form of mercury in the coal com...

  10. Worldwide biogenic soil NOx emission estimates from OMI NO2 observations and the GEOS-Chem model

    NASA Astrophysics Data System (ADS)

    Vinken, Geert; Boersma, Folkert; Maasakkers, Bram; Martin, Randall

    2014-05-01

    Bacteria in soils are an important source of biogenic nitrogen oxides (NOx = NO + NO2), which are important precursors for ozone (O3) formation. Furthermore NOx emissions contribute to increased nitrogen deposition and particulate matter formation. Bottom-up estimates of global soil NOx emissions range from 4 to 27 Tg N / yr, reflecting our incomplete knowledge of emission factors and processes driving these emissions. In this study we used, for the first time, OMI NO2 columns on all continents to reduce the uncertainty in soil NOx emissions. Regions and months dominated by soil NOx emissions were identified using a filtering scheme in the GEOS-Chem chemistry transport model. Consequently, we compared OMI observed NO2 observed columns to GEOS-Chem simulated columns and provide constraints for these months in 11 regions. This allows us to provide a top-down emission inventory for 2005 for soil NOx emissions from all continents. Our total global soil NOx emission inventory amounts to 10 Tg N / yr. Our estimate is 4% higher than the GEOS-Chem a priori (Hudman et al., 2012), but substantial regional differences exist (e.g. +20% for Sahel and India; and -40% for mid-USA). We furthermore observed a stronger seasonal cycle in the Sahel region, indicating directions for possible future improvements to the parameterization currently used in GEOS-Chem. We validated NO2 concentrations simulated with this new top-down inventory against surface NO2 measurements from monitoring stations in Africa, the USA and Europe. On the whole, we conclude that simulations with our new top-down inventory better agree with measurements. Our work shows that satellite retrieved NO2 columns can improve estimates of soil NOx emissions over sparsely monitored remote rural areas. We show that the range in previous estimates of soil NOx emissions is too large, and global emissions are most likely around 10 Tg N/yr, in agreement with the most recent parameterizations.

  11. NOx Emission Reduction and its Effects on Ozone during the 2008 Olympic Games

    SciTech Connect

    Yang, Qing; Wang, Yuhang; Zhao, Chun; Liu, Zhen; Gustafson, William I.; Shao, Min

    2011-07-15

    We applied a daily-assimilated inversion method to estimate NOx (NO+NO2) emissions for June-September 2007 and 2008 on the basis of the Aura Ozone Monitoring Instrument (OMI) observations of nitrogen dioxide (NO2) and model simulations using the Regional chEmistry and trAnsport Model (REAM). Over urban Beijing, rural Beijing, and the Huabei Plain, OMI column NO2 reductions are approximately 45%, 33%, and 14%, respectively, while the corresponding anthropogenic NOx emission reductions are only 28%, 24%, and 6%, during the full emission control period (July 20 – Sep 20, 2008). The emission reduction began in early July and was in full force by July 20, corresponding to the scheduled implementation of emission controls over Beijing. The emissions did not appear to recover after the emission control period. Meteorological change from summer 2007 to 2008 is the main factor contributing to the column NO2 decreases not accounted for by the emission reduction. Model simulations suggest that the effect of emission reduction on ozone concentrations over Beijing is relatively minor using a standard VOC emission inventory in China. With an adjustment of the model emissions to reflect in situ observations of VOCs in Beijing, the model simulation suggests a larger effect of the emission reduction.

  12. 40 CFR 75.70 - NOX mass emissions provisions.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... affected unit that is subject to an Acid Rain emissions limitation shall comply with the initial... unit that is not subject to an Acid Rain emissions limitation shall comply with the initial... that is subject to an Acid Rain emissions limitation shall comply with the initial certification...

  13. 40 CFR 75.70 - NOX mass emissions provisions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... affected unit that is subject to an Acid Rain emissions limitation shall comply with the initial... unit that is not subject to an Acid Rain emissions limitation shall comply with the initial... that is subject to an Acid Rain emissions limitation shall comply with the initial certification...

  14. 40 CFR 75.70 - NOX mass emissions provisions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... affected unit that is subject to an Acid Rain emissions limitation shall comply with the initial... unit that is not subject to an Acid Rain emissions limitation shall comply with the initial... that is subject to an Acid Rain emissions limitation shall comply with the initial certification...

  15. 40 CFR 75.70 - NOX mass emissions provisions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... affected unit that is subject to an Acid Rain emissions limitation shall comply with the initial... unit that is not subject to an Acid Rain emissions limitation shall comply with the initial... that is subject to an Acid Rain emissions limitation shall comply with the initial certification...

  16. 40 CFR 75.70 - NOX mass emissions provisions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... affected unit that is subject to an Acid Rain emissions limitation shall comply with the initial... unit that is not subject to an Acid Rain emissions limitation shall comply with the initial... that is subject to an Acid Rain emissions limitation shall comply with the initial certification...

  17. A Low NO(x) Lean-Direct Injection, Multipoint Integrated Module Combuster Concept for Advanced Aircraft Gas Turbines

    NASA Technical Reports Server (NTRS)

    Tacina, Robert; Wey, Changlie; Laing, Peter; Mansour, Adel

    2002-01-01

    A low NO(x) emissions combustor has been demonstrated in flame-tube tests. A multipoint, lean-direct injection concept was used. Configurations were tested that had 25- and 36- fuel injectors in the size of a conventional single fuel injector. An integrated-module approach was used for the construction where chemically etched laminates, diffusion bonded together, combine the fuel injectors, air swirlers and fuel manifold into a single element. Test conditions were inlet temperatures up to 810 K, inlet pressures up to 2760 kPa, and flame temperatures up to 2100 K. A correlation was developed relating the NO(x) emissions with the inlet temperature, inlet pressure, fuel-air ratio and pressure drop. Assuming that 10 percent of the combustion air would be used for liner cooling and using a hypothetical engine cycle, the NO(x) emissions using the correlation from flame-tube tests were estimated to be less than 20 percent of the 1996 ICAO standard.

  18. TCM aircraft piston engine emission reduction program

    NASA Technical Reports Server (NTRS)

    Rezy, B. J.

    1976-01-01

    The technology necessary to safely reduce general aviation piston engine exhaust emissions to meet the EPA 1980 Emission Standards with minimum adverse effects on cost, weight, fuel economy, and performance was demonstrated. A screening and assessment of promising emission reduction concepts was provided, and the preliminary design and development of those concepts was established. A system analysis study and a decision making procedure were used by TCM to evaluate, trade off, and rank the candidate concepts from a list of 14 alternatives. Cost, emissions, and 13 other design criteria considerations were defined and traded off against each candidate concept to establish its merit and emission reduction usefulness. A computer program was used to aid the evaluators in making the final choice of three concepts.

  19. Mixing and NO(x) Emission Calculations of Confined Reacting Jet Flows in a Cylindrical Duct

    NASA Technical Reports Server (NTRS)

    Holdeman, James D. (Technical Monitor); Oechsle, Victor L.

    2003-01-01

    Rapid mixing of cold lateral jets with hot cross-stream flows in confined configurations is of practical interest in gas turbine combustors as it strongly affects combustor exit temperature quality, and gaseous emissions in for example rich-lean combustion. It is therefore important to further improve our fundamental understanding of the important processes of dilution jet mixing especially when the injected jet mass flow rate exceeds that of the cross-stream. The results reported in this report describe some of the main flow characteristics which develop in the mixing process in a cylindrical duct. A 3-dimensional tool has been used to predict the mixing flow field characteristics and NOx emission in a quench section of an RQL combustor, Eighteen configurations have been analyzed in a circular geometry in a fully reacting environment simulating the operating condition of an actual RQL gas turbine combustion liner. The evaluation matrix was constructed by varying three parameters: 1) jet-to-mainstream momentum-flux ratio (J), 2) orifice shape or orifice aspect ratio, and 3) slot slant angle. The results indicate that the mixing flow field significantly varies with the value of the jet penetration and subsequently, slanting elongated slots generally improve the mixing uniformity at high J conditions. Round orifices produce more uniform mixing and low NO(x) emissions at low J due to the strong and adequate jet penetration. No significant correlation was found between the NO(x) production rates and the mixing deviation parameters, however, strong correlation was found between NO(x) formation and jet penetration. In the computational results, most of the NO(x) formation occurred behind the orifice starting at the orifice wake region. Additional NO(x) is formed upstream of the orifice in certain configurations with high J conditions due to the upstream recirculation.

  20. Quantification of NOx emissions from NO2 hotspots over China: A satellite perspective

    NASA Astrophysics Data System (ADS)

    Liu, Fei; Beirle, Steffen; Zhang, Qiang; Wagner, Thomas; He, Kebin

    2014-05-01

    China is the primary contributor of global anthropogenic NOx emissions, owing to its massive energy demand driven by strong economic growth. Most of the emissions are emitted by power plants or/and from urban areas, from which have been placed considerable emphasis on promoting emission reduction by Chinese government. Better knowledge of their emissions could help to assess the achieved emission reductions and provide perspectives as to the future effectiveness, which is also a valuable aid for taking regulatory steps. Thus we have developed an unit-based emission inventory of China's coal-fired power plants with high spatial and temporal resolution for the period 1990-2010 in our previous work (Liu et al., in preparation), but developing an emission inventory for each city at the same resolution and accuracy is much more challenging. Strong power plants and large cities can be identified as NO2 "hotspots" using satellite-based instruments. It has been demonstrated in previous studies (Beirle et al., Science, 2011) that OMI products can be applied for the determination of megacity NOx emissions and their lifetime by analyzing the downwind decay of the NO2 plume. In addition, from the analysis of the OMI time-series, the construction of new, large power plants in China can clearly be identified (Zhang et al, GRL, 2009). We are working on determining Chinese hotspots emissions and lifetimes of NOx simultaneously from the observed downwind plume evolution and ECMWF wind fields using the latest OMI product (DOMINO V2.0). However, the method applied to isolated megacities like Riyadh needs to be modified in order to take interferences of several strong NOx sources within small distances into account.We will present and discuss different approaches to deal with this challenge. The derived power plant emission will be compared to the bottom-up unit-based emission inventory. The found relation between bottom-up and top-down emissions will be used for the evaluation of top

  1. 40 CFR 51.122 - Emissions reporting requirements for SIP revisions relating to budgets for NOX emissions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... NOX emissions data as described in this section. (c) Each revision must provide for periodic reporting... reporting requirements of 40 CFR part 75, then the state need not provide an every-year cycle report to EPA...) of this section. (3) Through 2011, reports are to be submitted according to the schedule in Table...

  2. 40 CFR 51.122 - Emissions reporting requirements for SIP revisions relating to budgets for NOX emissions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... NOX emissions data as described in this section. (c) Each revision must provide for periodic reporting... reporting requirements of 40 CFR part 75, then the state need not provide an every-year cycle report to EPA...) of this section. (3) Through 2011, reports are to be submitted according to the schedule in Table...

  3. Considerations of high altitude emissions. [from supersonic cruise aircraft

    NASA Technical Reports Server (NTRS)

    Broderick, A. J.; Krull, N. P.

    1976-01-01

    The status of the Federal Aviation Administration's High Altitude Pollution Program is described which was instituted to develop the detailed quantitative information needed to judge whether or not regulatory action to limit such exhaust emissions would be necessary. The complexities of this question and the nature and magnitude of uncertainties still present in our scientific understanding of the potential interactions between aircraft exhaust emissions and stratospheric ozone and climate are reviewed. The direction and scope of future Federal and international activities are described.

  4. Impacts of biogenic emissions of VOC and NOx on tropospheric ozone during summertime in eastern China.

    PubMed

    Wang, Qin'geng; Han, Zhiwei; Wang, Tijian; Zhang, Renjian

    2008-05-20

    This study is intended to understand and quantify the impacts of biogenic emissions of volatile organic compounds (VOC) and nitrogen oxides (NO(x)) on the formation of tropospheric ozone during summertime in eastern China. The model system consists of the non-hydrostatic mesoscale meteorological model (MM5) and a tropospheric chemical and transport model (TCTM) with the updated carbon-bond chemical reaction mechanism (CBM-IV). The spatial resolution of the system domain is 30 km x 30 km. The impacts of biogenic emissions are investigated by performing simulations (36 h) with and without biogenic emissions, while anthropogenic emissions are constant. The results indicate that biogenic emissions have remarkable impacts on surface ozone in eastern China. In big cities and their surrounding areas, surface ozone formation tends to be VOC-limited. The increase in ozone concentration by biogenic VOC is generally 5 ppbv or less, but could be more than 10 ppbv or even 30 ppbv in some local places. The impacts of biogenic NO(x) are different or even contrary in different regions, depending on the relative availability of NO(x) and VOC. The surface ozone concentrations reduced or increased by the biogenic NO(x) could be as much as 10 ppbv or 20 ppbv, respectively. The impacts of biogenic emissions on ozone aloft are generally restricted to the boundary layer and generally more obvious during the daytime than during the nighttime. This study is useful for understanding the role of biogenic emissions and for planning strategies for surface ozone abatement in eastern China. Due to limitations of the emission inventories used and the highly non-linear nature of zone formation, however, some uncertainties remain in the results.

  5. Flame Tube NOx Emissions Using a Lean-Direct-Wall-Injection Combustor Concept

    NASA Technical Reports Server (NTRS)

    Tacina, Robert R.; Wey, Changlie; Choi, Kyung J.

    2001-01-01

    A low-NOx emissions combustor concept has been demonstrated in flame tube tests. A lean-direct injection concept was used where the fuel is injected directly into the flame zone and the overall fuel-air mixture is lean. In this concept the air is swirled upstream of a venturi section and the fuel is injected radially inward into the air stream from the throat section using a plain-orifice injector. Configurations have two-, four-, or six-wall fuel injectors and in some cases fuel is also injected from an axially located simplex pressure atomizer. Various orifice sizes of the plain-orifice injector were evaluated for the effect on NOx. Test conditions were inlet temperatures up to 8 1 OK, inlet pressures up to 2760 kPa, and flame temperatures up to 2100 K. A correlation is developed relating the NOx emissions to inlet temperature, inlet pressure, fuel-air ratio and pressure drop. Assuming that 15 percent of the combustion air would be used for liner cooling and using an advanced engine cycle, for the best configuration, the NOx emissions using the correlation is estimated to be <75 percent of the 1996 ICAO standard.

  6. Constraints on ship NOx emissions in Europe using OMI NO2 observations

    NASA Astrophysics Data System (ADS)

    Vinken, G. C. M.; Boersma, K. F.

    2012-04-01

    About 90% of world trade is transported by oceangoing ships, and seaborne trade has been shown to have increased by about 5% per year in the past decade. Global ship traffic is currently not regulated under international treaties (e.g. Kyoto protocol) and ships are still allowed to burn low-grade bunker fuel. As a result, ships emit large quantities of nitrogen oxides (NOx = NO + NO2), important precursors for ozone (O3) and particulate matter formation. Previous studies indicated that the global NOx emissions from shipping are in the range 3.0-10.4 Tg N per year (15-30% of total global NOx emissions). Because most ships sail within 400 km of the coast, it is important to understand the contribution of ship emissions to atmospheric composition in the densely populated coastal regions. Chemistry Transport Models (CTMs), in combination with emission inventories, are used to simulate atmospheric concentrations of air pollutants to assess the impact of ship emissions. However, these bottom-up inventories, based on extrapolation of a few engine measurements and strong assumptions, suffer from large uncertainties. In this study we provide top-down constraints on ship NOx emissions in Europe using satellite observations of NO2 columns. We use the nested version of the GEOS-Chem model (0.5°-0.667°) to simulate tropospheric NO2 columns over Europe for the years 2005-2006, using our plume-in-grid treatment of ship NOx emissions. We improve the NO2 retrievals from the Ozone Monitoring Instrument (OMI v2.0) by replacing the coarse a priori (TM4) vertical NO2 profiles (2°-3°) with the high-resolution GEOS-Chem profiles. This ensures consistency between the retrievals and model simulations. GEOS-Chem simulations of tropospheric NO2 columns show remarkable quantitative agreement with the observed OMI columns over Europe (R2=0.89, RMS difference < 0.2-1015 molec. cm-2), providing confidence in the ability of the model to simulate NO2 pollution over the European mainland. We

  7. A model investigation of the impact of increases in anthropogenic NOx emissions between 1967 and 1980 on tropospheric ozone

    NASA Technical Reports Server (NTRS)

    Dignon, J.; Hameed, S.

    1985-01-01

    The impact of anthropogenic NOx emission on tropospheric ozone has been investigated. Two statistical models were used for estimating annual global emissions of NOx and for driving the trend in the emission for the years 1966-1980. Both models show a steady increase in the NOx emission, except for two brief periods of leveling off: after 1973 and after 1978. The impact was estimated by calculating the rates of emissions as functions of latitude, longitude, and year, with a one-dimensional (latitudinal) model, which included coupled tropospheric photochemistry and diffusive meridional transport. Steady-state photochemical calculations with prescribed NOx emissions appropriate for 1966 and 1980 indicate an ozone increase of 8-11 percent in the Northern Hemisphere, a result compatible with the rise in ozone suggested by the observations.

  8. Field test of available methods to measure remotely SOx and NOx emissions from ships

    NASA Astrophysics Data System (ADS)

    Balzani Lööv, J. M.; Alfoldy, B.; Gast, L. F. L.; Hjorth, J.; Lagler, F.; Mellqvist, J.; Beecken, J.; Berg, N.; Duyzer, J.; Westrate, H.; Swart, D. P. J.; Berkhout, A. J. C.; Jalkanen, J.-P.; Prata, A. J.; van der Hoff, G. R.; Borowiak, A.

    2014-08-01

    Methods for the determination of ship fuel sulphur content and NOx emission factors based on remote measurements have been compared in the harbour of Rotterdam and compared to direct stack emission measurements on the ferry Stena Hollandica. The methods were selected based on a review of the available literature on ship emission measurements. They were either optical (LIDAR, Differential Optical Absorption Spectroscopy (DOAS), UV camera), combined with model-based estimates of fuel consumption, or based on the so called "sniffer" principle, where SO2 or NOx emission factors are determined from simultaneous measurement of the increase of CO2 and SO2 or NOx concentrations in the plume of the ship compared to the background. The measurements were performed from stations at land, from a boat and from a helicopter. Mobile measurement platforms were found to have important advantages compared to the land-based ones because they allow optimizing the sampling conditions and sampling from ships on the open sea. Although optical methods can provide reliable results it was found that at the state of the art level, the "sniffer" approach is the most convenient technique for determining both SO2 and NOx emission factors remotely. The average random error on the determination of SO2 emission factors comparing two identical instrumental set-ups was 6%. However, it was found that apparently minor differences in the instrumental characteristics, such as response time, could cause significant differences between the emission factors determined. Direct stack measurements showed that about 14% of the fuel sulphur content was not emitted as SO2. This was supported by the remote measurements and is in agreement with the results of other field studies.

  9. Field test of available methods to measure remotely SO2 and NOx emissions from ships

    NASA Astrophysics Data System (ADS)

    Balzani Lööv, J. M.; Alfoldy, B.; Beecken, J.; Berg, N.; Berkhout, A. J. C.; Duyzer, J.; Gast, L. F. L.; Hjorth, J.; Jalkanen, J.-P.; Lagler, F.; Mellqvist, J.; Prata, F.; van der Hoff, G. R.; Westrate, H.; Swart, D. P. J.; Borowiak, A.

    2013-11-01

    Methods for the determination of ship fuel sulphur content and NOx emission factors from remote measurements have been compared in the harbour of Rotterdam and compared to direct stack emission measurements on the ferry Stena Hollandica. The methods were selected based on a review of the available literature on ship emission measurements. They were either optical (LIDAR, DOAS, UV camera), combined with model based estimates of fuel consumption, or based on the so called "sniffer" principle, where SO2 or NOx emission factors are determined from simultaneous measurement of the increase of CO2 and SO2 or NOx concentrations in the plume of the ship compared to the background. The measurements were performed from stations at land, from a boat, and from a helicopter. Mobile measurement platforms were found to have important advantages compared to the landbased ones because they allow to optimize the sampling conditions and to sample from ships on the open sea. Although optical methods can provide reliable results, it was found that at the state of the art, the "sniffer" approach is the most convenient technique for determining both SO2 and NOx emission factors remotely. The average random error on the determination of SO2 emission factors comparing two identical instrumental set-ups was 6%. However, it was found that apparently minor differences in the instrumental characteristics, such as response time, could cause significant differences between the emission factors determined. Direct stack measurements showed that about 14% of the fuel sulphur content was not emitted as SO2. This was supported by the remote measurements and is in agreement with the results of other field studies.

  10. SELECTIVE CATALYTIC REDUCTION OF DIESEL ENGINE NOX EMISSIONS USING ETHANOL AS A REDUCTANT

    SciTech Connect

    Kass, M; Thomas, J; Lewis, S; Storey, J; Domingo, N; Graves, R Panov, A

    2003-08-24

    NOx emissions from a heavy-duty diesel engine were reduced by more than 90% and 80% utilizing a full-scale ethanol-SCR system for space velocities of 21000/h and 57000/h respectively. These results were achieved for catalyst temperatures between 360 and 400 C and for C1:NOx ratios of 4-6. The SCR process appears to rapidly convert ethanol to acetaldehyde, which subsequently slipped past the catalyst at appreciable levels at a space velocity of 57000/h. Ammonia and N2O were produced during conversion; the concentrations of each were higher for the low space velocity condition. However, the concentration of N2O did not exceed 10 ppm. In contrast to other catalyst technologies, NOx reduction appeared to be enhanced by initial catalyst aging, with the presumed mechanism being sulfate accumulation within the catalyst. A concept for utilizing ethanol (distilled from an E-diesel fuel) as the SCR reductant was demonstrated.

  11. Emission of atmospheric pollutants out of Africa - Analysis of CARIBIC aircraft air samples

    NASA Astrophysics Data System (ADS)

    Thorenz, Ute R.; Baker, Angela K.; Schuck, Tanja; van Velthoven, Peter F. J.; Ziereis, Helmut; Brenninkmeijer, Carl A. M.

    2014-05-01

    Africa is the single largest continental source of biomass burning (BB) emissions. The burning African savannas and tropical forests are a source for a wide range of chemical species, which are important for global atmospheric chemistry, especially for the pristine Southern Hemisphere. Emitted compounds include carbon monoxide (CO), nitrogen oxides (NOx), hydrocarbons, oxygenated hydrocarbons and particles. Deep convection over Central Africa transports boundary layer emissions to the free troposphere making aircraft-based observations useful for investigation of surface emissions and examination of transport and chemistry processes over Africa The CARIBIC project (Civil Aircraft for the Regular Investigation of the Atmosphere Based on an Instrument Container, www.caribic-atmosphere.com part of IAGOS www.iagos.org) is a long term atmospheric measurement program using an instrument container deployed aboard a Lufthansa Airbus A340-600 for a monthly sequence of long-distance passenger flights. Besides the online measurements mixing ratios of greenhouse gases and a suite of C2-C8 non methane hydrocarbons (NMHCs) are measured from flask samples collected at cruise altitude. During northern hemispheric winter 2010/2011 CARIBIC flights took place from Frankfurt to Cape Town and Johannesburg in South Africa. Several BB tracers like methane, CO and various NMHCs were found to be elevated over tropical Africa. Using tracer-CO- and tracer-NOy-correlations emissions were characterized. The NMHC-CO correlations show monthly changing slopes, indicating a change in burned biomass, major fire stage, source region and/or other factors influencing NMHC emissions. To expand our analysis of emission sources a source region data filter was used, based on backward trajectories calculated along the flight tracks. Taking all CARIBIC samples into account having backward trajectories to the African boundary layer the dataset was enlarged from 77 to 168 samples. For both datasets tracer

  12. Quantification of variability and uncertainty in lawn and garden equipment NOx and total hydrocarbon emission factors.

    PubMed

    Frey, H Christopher; Bammi, Sachin

    2002-04-01

    Variability refers to real differences in emissions among multiple emission sources at any given time or over time for any individual emission source. Variability in emissions can be attributed to variation in fuel or feedstock composition, ambient temperature, design, maintenance, or operation. Uncertainty refers to lack of knowledge regarding the true value of emissions. Sources of uncertainty include small sample sizes, bias or imprecision in measurements, nonrepresentativeness, or lack of data. Quantitative methods for characterizing both variability and uncertainty are demonstrated and applied to case studies of emission factors for lawn and garden (L&G) equipment engines. Variability was quantified using empirical and parametric distributions. Bootstrap simulation was used to characterize confidence intervals for the fitted distributions. The 95% confidence intervals for the mean grams per brake horsepower/hour (g/hp-hr) emission factors for two-stroke engine total hydrocarbon (THC) and NOx emissions were from -30 to +41% and from -45 to +75%, respectively. The confidence intervals for four-stroke engines were from -33 to +46% for THCs and from -27 to +35% for NOx. These quantitative measures of uncertainty convey information regarding the quality of the emission factors and serve as a basis for calculation of uncertainty in emission inventories (EIs).

  13. Model Calculations of the Impact of NO(x) from Air Traffic, Lightning and Surface Emissions, Compared with Measurements

    NASA Technical Reports Server (NTRS)

    Meijer, E. W.; vanVelthoven, P. F. J.; Thompson, A. M.; Pfister, L.; Schlager, H.; Schulte, P.; Kelder, H.

    1999-01-01

    The impact of NO(x) from aircraft emissions, lightning and surface contributions on atmospheric nitrogen oxides and ozone has been investigated with the three-dimensional global chemistry transport model TM3 by partitioning the nitrogen oxides and ozone according to source category. The results have been compared with POLINAT II and SONEX airborne measurements in the North Atlantic flight corridor in 1997. Various cases have been investigated: measurements during a stagnant anti-cyclone and an almost cut-off low, both with expected high aircraft contributions, a southward bound flight with an expected strong flight corridor gradient and lightning contributions in the South, and a transatlantic flight with expected boundary layer pollution near the U.S. coast. The agreement between modeled results and measurements is reasonably good for NO and ozone. Also, the calculated impact of the three defined sources were consistent with the estimated exposure of the sampled air to these sources, obtained by specialized back-trajectory model products.

  14. Impact of Ship Emissions on Marine Boundary Layer NO(x) and SO2 Distributions over the Pacific Basin

    NASA Technical Reports Server (NTRS)

    Davis, D. D.; Grodzinsky, G.; Kasibhatla, P.; Crawford, J.; Chen, G.; Liu, S.; Bandy, A.; Thornton, D.; Guan, H.; Sandholm, S.

    2001-01-01

    The impact of ship emissions on marine boundary layer (MBL) NO(x) and SO2 levels over the Pacific Ocean has been explored by comparing predictions (with and without ships) from a global chemical transport model (GCTM) against compiled airborne observations of MBL NO(x) and SO2. For latitudes above 15 N, which define that part of the Pacific having the heaviest shipping, this analysis revealed significant model over prediction for NOx and a modest under prediction for SO2 when ship emissions were considered. Possible reasons for the difference in NO(x) and SO2 were explored using a full-chemistry box model. These results revealed that for an actual plume setting the NO(x) lifetime could be greatly shortened by chemical processes promoted by ship plume emissions themselves. Similar chemical behavior was not found for SO2.

  15. Experimental Assessment of NOx Emissions from 73 Euro 6 Diesel Passenger Cars.

    PubMed

    Yang, Liuhanzi; Franco, Vicente; Mock, Peter; Kolke, Reinhard; Zhang, Shaojun; Wu, Ye; German, John

    2015-12-15

    Controlling nitrogen oxides (NOx) emissions from diesel passenger cars during real-world driving is one of the major technical challenges facing diesel auto manufacturers. Three main technologies are available for this purpose: exhaust gas recirculation (EGR), lean-burn NOx traps (LNT), and selective catalytic reduction (SCR). Seventy-three Euro 6 diesel passenger cars (8 EGR only, 40 LNT, and 25 SCR) were tested on a chassis dynamometer over both the European type-approval cycle (NEDC, cold engine start) and the more realistic Worldwide harmonized light-duty test cycle (WLTC version 2.0, hot start) between 2012 and 2015. Most vehicles met the legislative limit of 0.08 g/km of NOx over NEDC (average emission factors by technology: EGR-only 0.07 g/km, LNT 0.04 g/km, and SCR 0.05 g/km), but the average emission factors rose dramatically over WLTC (EGR-only 0.17 g/km, LNT 0.21 g/km, and SCR 0.13 g/km). Five LNT-equipped vehicles exhibited very poor performance over the WLTC, emitting 7-15 times the regulated limit. These results illustrate how diesel NOx emissions are not properly controlled under the current, NEDC-based homologation framework. The upcoming real-driving emissions (RDE) regulation, which mandates an additional on-road emissions test for EU type approvals, could be a step in the right direction to address this problem. PMID:26580818

  16. Review of measurement and testing problems. [of aircraft emissions

    NASA Technical Reports Server (NTRS)

    1976-01-01

    Good instrumentation was required to obtain reliable and repeatable baseline data. Problems that were encountered in developing such a total system were: (1) accurate airflow measurement, (2) precise fuel flow measurement, and (3) the instrumentation used for pollutant measurement was susceptible to frequent malfunctions. Span gas quality had a significant effect on emissions test results. The Spindt method was used in the piston aircraft emissions program. The Spindt method provided a comparative computational procedure for fuel/air ratio based on measured emissions concentrations.

  17. Aircraft measurements of microwave emission from Arctic Sea ice

    USGS Publications Warehouse

    Wilheit, T.; Nordberg, W.; Blinn, J.; Campbell, W.; Edgerton, A.

    1971-01-01

    Measurements of the microwave emission from Arctic Sea ice were made with aircraft at 8 wavelengths ranging from 0.510 to 2.81 cm. The expected contrast in emissivities between ice and water was observed at all wavelengths. Distributions of sea ice and open water were mapped from altitudes up to 11 km in the presence of dense cloud cover. Different forms of ice also exhibited strong contrasts in emissivity. Emissivity differences of up to 0.2 were observed between two types of ice at the 0.811-cm wavelength. The higher emissivity ice type is tentatively identified as having been formed more recently than the lower emissivity ice. ?? 1971.

  18. Satellite-observed US power plant NOx emission reductions and their impact on air quality - article no. L22812

    SciTech Connect

    Kim, S.W.; Heckel, A.; McKeen, S.A.; Frost, G.J.; Hsie, E.Y.; Trainer, M.K.; Richter, A.; Burrows, J.P.; Peckham, S.E.; Grell, G.A.

    2006-11-29

    Nitrogen oxide (NOx) emissions resulting from fossil fuel combustion lead to unhealthy levels of near-surface ozone (O{sub 3}). One of the largest U.S. sources, electric power generation, represented about 25% of the U.S. anthropogenic NOx emissions in 1999. Here we show that space-based instruments observed declining regional NOx levels between 1999 and 2005 in response to the recent implementation of pollution controls by utility companies in the eastern U.S. Satellite-retrieved summertime nitrogen dioxide (NO{sub 2}) columns and bottom-up emission estimates show larger decreases in the Ohio River Valley, where power plants dominate NOx emissions, than in the northeast U.S. urban corridor. Model simulations predict lower O{sub 3} across much of the eastern U.S. in response to these emission reductions.

  19. 40 CFR 87.23 - Exhaust emission standards for Tier 6 and Tier 8 engines.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... standard, as described in § 87.60. The tier of standards identified for an engine relates to NOX emissions... the NOX emission standards. (a) New turboprop aircraft engines with rated output at or above 1,000... excepted without request from the otherwise applicable Tier 6 NOX emission standard. To be eligible...

  20. High ozone concentrations on hot days: The role of electric power demand and NOx emissions

    NASA Astrophysics Data System (ADS)

    He, Hao; Hembeck, Linda; Hosley, Kyle M.; Canty, Timothy P.; Salawitch, Ross J.; Dickerson, Russell R.

    2013-10-01

    ambient temperatures intensify photochemical production of tropospheric ozone, leading to concerns that global warming may exacerbate smog episodes. This widely observed phenomenon has been termed the climate penalty factor (CPF). A variety of meteorological and photochemical processes have been suggested to explain why surface ozone increases on hot days. Here, we quantify an anthropogenic factor previously overlooked: the rise of ozone precursor emissions on hot summer days due to high electricity demand. Between 1997 and 2011, power plant emissions of NOx in the eastern U.S. increased by ~2.5-4.0%/°C, raising surface NOx concentrations by 0.10-0.25 ppb/°C. Given an ozone production efficiency (OPE) of ~8 mol/mol based on the 2011 NASA DISCOVER-AQ campaign, at least one third of the CPF observed in the eastern U.S. can be attributed to the temperature dependence of NOx emissions. This finding suggests that controlling emissions associated with electricity generation on hot summer days can mitigate the CPF.

  1. Effects of Aircraft Wake Dynamics on Measured and Simulated NO(x) and HO(x) Wake Chemistry. Appendix B

    NASA Technical Reports Server (NTRS)

    Lewellen, D. C.; Lewellen, W. S.

    2001-01-01

    High-resolution numerical large-eddy simulations of the near wake of a B757 including simplified NOx and HOx chemistry were performed to explore the effects of dynamics on chemistry in wakes of ages from a few seconds to several minutes. Dilution plays an important basic role in the NOx-O3 chemistry in the wake, while a more interesting interaction between the chemistry and dynamics occurs for the HOx species. These simulation results are compared with published measurements of OH and HO2 within a B757 wake under cruise conditions in the upper troposphere taken during the Subsonic Aircraft Contrail and Cloud Effects Special Study (SUCCESS) mission in May 1996. The simulation provides a much finer grained representation of the chemistry and dynamics of the early wake than is possible from the 1 s data samples taken in situ. The comparison suggests that the previously reported discrepancy of up to a factor of 20 - 50 between the SUCCESS measurements of the [HO2]/[OH] ratio and that predicted by simplified theoretical computations is due to the combined effects of large mixing rates around the wake plume edges and averaging over volumes containing large species fluctuations. The results demonstrate the feasibility of using three-dimensional unsteady large-eddy simulations with coupled chemistry to study such phenomena.

  2. Will Euro 6 reduce the NOx emissions of new diesel cars? - Insights from on-road tests with Portable Emissions Measurement Systems (PEMS)

    NASA Astrophysics Data System (ADS)

    Weiss, Martin; Bonnel, Pierre; Kühlwein, Jörg; Provenza, Alessio; Lambrecht, Udo; Alessandrini, Stefano; Carriero, Massimo; Colombo, Rinaldo; Forni, Fausto; Lanappe, Gaston; Le Lijour, Philippe; Manfredi, Urbano; Montigny, Francois; Sculati, Mirco

    2012-12-01

    The nitrogen dioxide (NO2) pollution in urban areas of Europe can be partially attributed to the increasing market penetration of diesel cars that show higher distance-specific nitrogen oxides (NOx) emissions than gasoline cars. The on-road NOx emissions of diesel cars, furthermore, appear to exceed substantially applicable emissions standards. This observation raises concerns that the introduction of more stringent Euro 6 emissions standards in 2014 may not adequately reduce the distance-specific on-road NOx emissions of new diesel cars. We address the existing concerns by analyzing the gaseous emissions of one novel Euro 6 diesel car and six Euro 4-5 diesel cars with Portable Emissions Measurement Systems (PEMS). We find that the average on-road NOx emissions of the Euro 6 car (0.21 ± 0.09 g per kilometer [g km-1]) are considerably lower than those of the Euro 4 cars (0.76 ± 0.12 g km-1) and the Euro 5 cars (0.71 ± 0.30 g km-1). The selective catalytic reduction (SCR) system of the Euro 6 diesel car is suitable to limit NOx emissions during real-world on-road driving. Still, all tested cars, including the Euro 6 diesel car, exceed their NOx emissions standards on the road by 260 ± 130%. This finding suggests that the current type-approval procedure does not adequately capture the on-road NOx emissions of diesel cars. By introducing a complementary emissions test procedure that covers a wide range of normal operating conditions, the European legislative authorities can address this problem and ensure that Euro 6 will indeed deliver an adequate reduction in the NOx emissions of new diesel cars.

  3. Increased Use of Natural Gas for Power Generation in the U.S. and the Resulting Reductions in Emissions of CO2, NOx and SO2

    NASA Astrophysics Data System (ADS)

    De Gouw, J. A.; Parrish, D. D.; Trainer, M.

    2013-12-01

    Over the past decades, natural gas has increasingly replaced coal as a fuel for electrical power generation in the U.S. As a result, there have been significant reductions in the emissions of carbon dioxide (CO2), nitrogen oxides (NOx) and sulfur dioxide (SO2). Power plant emissions are continuously measured at the stack using continuous emissions monitoring systems (CEMS) required by the EPA. Previous studies using airborne measurements have shown these CEMS measurements to be accurate. Here, we use annual emissions since 1995 from all point sources included in the CEMS database to quantify the changes in CO2, NOx and SO2 emissions that have resulted from the changing use of fuels and technologies for power generation. In 1997, 83% of electrical power in the CEMS database was generated from coal-fired power plants. In 2012, the contribution from coal had decreased to 59%, and natural gas contributed 34% of the electrical power. Natural gas-fired power plants, in particular those equipped with combined cycle technology, emit less than 50% of CO2 per kWh produced compared to coal-fired plants. As a result of the increased use of natural gas, total CO2 emissions from U.S. power plants have decreased since 2008. In addition, natural gas-fired power plants emit less NOx and far less SO2 per kWh produced than coal-fired power plants. The increased use of natural gas has therefore led to significant emissions reductions of NOx and SO2 in addition to those obtained from the implementation of emissions control systems on coal-fired power plants. The increased use of natural gas for power generation has led to significant reductions in CO2 emissions as well as improvements in U.S. air quality. We will illustrate these points with examples from airborne measurements made using the NOAA WP-3D aircraft in the Southeastern U.S. in 2013 as part of the NOAA Southeast Nexus (SENEX) study. The emissions reductions from U.S. power plants due to the increased use of natural gas will

  4. NOx emissions from Euro IV busses with SCR systems associated with urban, suburban and freeway driving patterns.

    PubMed

    Fu, Mingliang; Ge, Yunshan; Wang, Xin; Tan, Jianwei; Yu, Linxiao; Liang, Bin

    2013-05-01

    NOx and particulate matter (PM) emissions from heavy-duty diesel vehicles (HDVs) have become the most important sources of pollutants affecting urban air quality in China. In recent years, a series of emission control strategies and diesel engine polices have been introduced that require advanced emission control technology. China and Europe mostly have used Selective Catalytic Reduction (SCR) with urea to meet the Euro IV diesel engine emission standard. In this study, two Euro IV busses with SCR were tested by using potable emission measurement system (PEMS) to assess NOx emissions associated with urban, suburban and freeway driving patterns. The results indicated that with the SCR system, the urea injection time for the entire driving period increased with higher vehicle speed. For freeway driving, the urea injection time covered 71%-83% of the driving period; the NOx emission factors from freeway driving were lower than those associated with urban and suburban driving. Unfortunately, the NOx emission factors were 2.6-2.8-, 2.3-2.7- and 2.2-2.3-fold higher than the Euro IV standard limits for urban, suburban and freeway driving, respectively; NOx emission factors (in g/km and g/(kW·h)) from the original vehicles (without SCR) were higher than their corresponding vehicles with SCR for suburban and freeway driving. Compared with the IVE model results, the measured NOx emission factors were 1.60-1.16-, 1.77-1.27-, 2.49-2.44-fold higher than the NOx predicted by the IVE model for urban and suburban driving, respectively. Thus, an adjustment of emission factors is needed to improve the estimation of Euro IV vehicle emissions in China.

  5. SUMMARY REPORT CONTROL OF NOX EMISSIONS BY REBURNING

    EPA Science Inventory

    This report covers NOx control employing reburning technology: A new, effective method of controlling NOx emissions from a wide range of stationary combustion sources including large, coal-fired, utility boilers. Although reburning potentially is applicable ...

  6. Attempts to Reduce NOx Exhaust Emissions by Using Reformulated Biodiesel

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Two routes were investigated for reformulating soy-based biodiesel in an effort to reduce its nitrogen oxide emissions. In the first approach, methyl soyate was modified by converting a proportion of the cis-bonds in the fatty acid chains of its methyl esters to their trans isomers. In the second ...

  7. Emission reduction of NOx, PM, PM-carbon, and PAHs from a generator fuelled by biodieselhols.

    PubMed

    Tsai, Jen-Hsiung; Chen, Shui-Jen; Huang, Kuo-Lin; Lin, Wen-Yinn; Lee, Wen-Jhy; Chao, How-Ran; Lin, Chih-Chung; Hsieh, Lien-Te

    2014-06-15

    This investigation examines the particulate matter (PM), particulate carbon, polycyclic aromatic hydrocarbons (PAHs), and nitrogen oxides (NOx) emitted from a generator fueled by petroleum diesel blended with waste-edible-oil-biodiesel and water-containing acetone. Experimental results show that using biodieselhols with water-containing (or pure) acetone as the fuel of generator, in comparison to using petroleum diesel, significantly reduces PM emission; roughly, this reduction increased as percentage of water-containing acetone increased. When the percentages of waste-edible-oil-biodiesel were ≤ 5 vol%, adding pure or water-containing acetone (1-3 vol%) to biodieselhols generated emission reductions of NOx, PM, particle-bound organic carbon (OC), total-PAHs, and total-BaPeq. Consequently, using water-containing acetone biodieselhols as an alternative generator fuel is feasible and helps recycle and reuse waste solvents containing water-containing acetone.

  8. Method for reducing CO2, CO, NOX, and SOx emissions

    DOEpatents

    Lee, James Weifu; Li, Rongfu

    2002-01-01

    Industrial combustion facilities are integrated with greenhouse gas-solidifying fertilizer production reactions so that CO.sub.2, CO, NO.sub.x, and SO.sub.x emissions can be converted prior to emission into carbonate-containing fertilizers, mainly NH.sub.4 HCO.sub.3 and/or (NH.sub.2).sub.2 CO, plus a small fraction of NH.sub.4 NO.sub.3 and (NH.sub.4).sub.2 SO.sub.4. The invention enhances sequestration of CO.sub.2 into soil and the earth subsurface, reduces N0.sub.3.sup.- contamination of surface and groundwater, and stimulates photosynthetic fixation of CO.sub.2 from the atmosphere. The method for converting CO.sub.2, CO, NO.sub.x, and SO.sub.x emissions into fertilizers includes the step of collecting these materials from the emissions of industrial combustion facilities such as fossil fuel-powered energy sources and transporting the emissions to a reactor. In the reactor, the CO.sub.2, CO, N.sub.2, SO.sub.x, and/or NO.sub.x are converted into carbonate-containing fertilizers using H.sub.2, CH.sub.4, or NH.sub.3. The carbonate-containing fertilizers are then applied to soil and green plants to (1) sequester inorganic carbon into soil and subsoil earth layers by enhanced carbonation of groundwater and the earth minerals, (2) reduce the environmental problem of NO.sub.3.sup.- runoff by substituting for ammonium nitrate fertilizer, and (3) stimulate photosynthetic fixation of CO.sub.2 from the atmosphere by the fertilization effect of the carbonate-containing fertilizers.

  9. The contribution of soil biogenic NO and HONO emissions from a managed hyperarid ecosystem to the regional NOx emissions during growing season

    NASA Astrophysics Data System (ADS)

    Mamtimin, Buhalqem; Meixner, Franz X.; Behrendt, Thomas; Badawy, Moawad; Wagner, Thomas

    2016-08-01

    A study was carried out to understand the contributions of soil biogenic NO emissions from managed (fertilized and irrigated) hyperarid ecosystems in NW China to the regional NOx emissions during the growing season. Soil biogenic net potential NO fluxes were quantified by laboratory incubation of soil samples from the three dominating ecosystems (desert, cotton, and grape fields). Regional biogenic NO emissions were calculated bottom-up hourly for the entire growing season (April-September 2010) by considering corresponding land use, hourly data of soil temperature, gravimetric soil moisture, and fertilizer enhancement factors. The regional HONO emissions were estimated using the ratio of the optimum condition ((FN,opt(HONO) to FN,opt (NO)). Regional anthropogenic NOx emissions were calculated bottom-up from annual statistical data provided by regional and local government bureaus which have been downscaled to monthly value. Regional top-down emission estimates of NOx were derived on the monthly basis from satellite observations (OMI) of tropospheric vertical NO2 column densities and prescribed values of the tropospheric NOx lifetime. In order to compare the top-down and bottom-up emission estimates, all emission estimates were expressed in terms of mass of atomic nitrogen. Consequently, monthly top-down NOx emissions (total) were compared with monthly bottom-up NOx emissions (biogenic + anthropogenic) for the time of the satellite overpass (around 13:00 LT) with the consideration of the diurnal cycle of bottom-up estimates. Annual variation in total Tohsun Oasis NOx emissions is characterized by a strong peak in winter (December-February) and a secondary peak in summer (June-August). During summer, soil biogenic emissions were from equal to double that of related anthropogenic emissions, and grape soils were the main contributor to soil biogenic emissions, followed by cotton soils, while emissions from the desert were negligible. The top-down and bottom

  10. Exhaust emissions reduction for intermittent combustion aircraft engines

    NASA Technical Reports Server (NTRS)

    Rezy, B. J.; Stuckas, K. J.; Tucker, J. R.; Meyers, J. E.

    1982-01-01

    Three concepts which, to an aircraft piston engine, provide reductions in exhaust emissions of hydrocarbons and carbon monoxide while simultaneously improving fuel economy. The three chosen concepts, (1) an improved fuel injection system, (2) an improved cooling cylinder head, and (3) exhaust air injection, when combined, show a synergistic relationship in achieving these goals. In addition, the benefits of variable ignition timing were explored and both dynamometer and flight testing of the final engine configuration were accomplished.

  11. Reductions of NOx emissions from the Bowline Point generating station

    SciTech Connect

    O`Sullivan, R.C.; Conti, A.V.; Hersh, S.

    1996-12-31

    Improved combustion hardware, based upon the simultaneous optimization of oil atomizer and flame stabilizer technologies, has been retrofitted to oil and gas fired boilers to reduce NO{sub x} emissions, particulate matter emissions, and opacity, and to provide operational and performance benefits. This technology, known as REACH, can be applied to wall and tangential-fired boilers at a fraction of the cost of installing new burners. In combination with conventional NO{sub x} controls such as overfire air, flue gas recirculation, and low-NO{sub x} burners, REACH technology can provide an additional increment in NO{sub x} reduction; often valuable for meeting and maintaining regulatory compliance. This paper describes the results achieved when this technology was applied to the boilers at Orange and Rockland Utilities` Bowline Point Station to meet NYSDEC part 227 regulations for the emissions of nitrogen oxides (NO{sub x}). Bowline Point Unit 1 is a 600 MWe tangentially fired boiler with no installed NO{sub x} control systems. Bowline Point No. 2 is a 600 MW opposed-wall fired boiler with overfire air and windbox flue gas recirculation capability.

  12. Cold-Start Emissions Control in Hybrid Vehicles Equipped with a Passive Hydrocarbon and NOx Adsorber

    SciTech Connect

    Gao, Zhiming; Kim, Miyoung; Choi, Jae-Soon; Daw, C Stuart; Parks, II, James E; Smith, David E

    2012-01-01

    We presents a study of the potential for using low-cost sorbent materials (i.e. Ag-Beta-zeolite and Fe-Mn-Zr transition metal oxides) to temporally trap hydrocarbons (HCs) and nitrogen oxides (NOx) emissions during cold-start periods in HEVs and PHEVs over transient driving cycles. The adsorption behavior of the candidate sorbent materials was characterized in our laboratory flow reactor experiments. The parameters were then used to develop a one-dimensional, transient device model which has been implemented in the Powertrain Systems Analysis Toolkit (PSAT) to simulate a passive HC and NOx absorber device. The results show that such an absorber can substantially reduce HC and NOx emissions by storing them when the 3-way catalyst is too cool to function and re-releasing them when the exhaust temperature rises. These improved emission controls do not involve any penalty in fuel consumption or require any change in engine operation. The cost of these sorbent materials is also much less than conventional 3-way catalysts.

  13. Improved NOx emissions and combustion characteristics for a retrofitted down-fired 300-MWe utility boiler.

    PubMed

    Li, Zhengqi; Ren, Feng; Chen, Zhichao; Liu, Guangkui; Xu, Zhenxing

    2010-05-15

    A new technique combining high boiler efficiency and low-NO(x) emissions was employed in a 300MWe down-fired boiler as an economical means to reduce NO(x) emissions in down-fired boilers burning low-volatile coals. Experiments were conducted on this boiler after the retrofit with measurements taken of gas temperature distributions along the primary air and coal mixture flows and in the furnace, furnace temperatures along the main axis and gas concentrations such as O(2), CO and NO(x) in the near-wall region. Data were compared with those obtained before the retrofit and verified that by applying the combined technique, gas temperature distributions in the furnace become more reasonable. Peak temperatures were lowered from the upper furnace to the lower furnace and flame stability was improved. Despite burning low-volatile coals, NO(x) emissions can be lowered by as much as 50% without increasing the levels of unburnt carbon in fly ash and reducing boiler thermal efficiency.

  14. Selective catalytic reduction operation with heavy fuel oil: NOx, NH3, and particle emissions.

    PubMed

    Lehtoranta, Kati; Vesala, Hannu; Koponen, Päivi; Korhonen, Satu

    2015-04-01

    To meet stringent NOx emission limits, selective catalytic reduction (SCR) is increasingly utilized in ships, likely also in combination with low-priced higher sulfur level fuels. In this study, the performance of SCR was studied by utilizing NOx, NH3, and particle measurements. Urea decomposition was studied with ammonia and isocyanic acid measurements and was found to be more effective with heavy fuel oil (HFO) than with light fuel oil. This is suggested to be explained by the metals found in HFO contributing to metal oxide particles catalyzing the hydrolysis reaction prior to SCR. At the exhaust temperature of 340 °C NOx reduction was 85-90%, while at lower temperatures the efficiency decreased. By increasing the catalyst loading, the low temperature behavior of the SCR was enhanced. The drawback of this, however, was the tendency of particle emissions (sulfate) to increase at higher temperatures with higher loaded catalysts. The particle size distribution results showed high amounts of nanoparticles (in 25-30 nm size), the formation of which SCR either increased or decreased. The findings of this work provide a better understanding of the usage of SCR in combination with a higher sulfur level fuel and also of ship particle emissions, which are a growing concern.

  15. Exhaust emission reduction for intermittent combustion aircraft engines

    NASA Technical Reports Server (NTRS)

    Moffett, R. N.

    1979-01-01

    Three concepts for optimizing the performance, increasing the fuel economy, and reducing exhaust emission of the piston aircraft engine were investigated. High energy-multiple spark discharge and spark plug tip penetration, ultrasonic fuel vaporization, and variable valve timing were evaluated individually. Ultrasonic fuel vaporization did not demonstrate sufficient improvement in distribution to offset the performance loss caused by the additional manifold restriction. High energy ignition and revised spark plug tip location provided no change in performance or emissions. Variable valve timing provided some performance benefit; however, even greater performance improvement was obtained through induction system tuning which could be accomplished with far less complexity.

  16. Bridge-based sensing of NOx and SO2 emissions from ocean-going ships

    NASA Astrophysics Data System (ADS)

    Burgard, Daniel A.; Bria, Carmen R. M.

    2016-07-01

    As emissions from nonroad mobile sources face increased regulatory scrutiny, a surprisingly few number of real-world, in-use measurements exist for these sources. This paper reports the first use of an open-path Remote Sensing Device (RSD) to measure emissions from ocean-going ships, including cruise ships. This noninvasive technique measured NOx and SO2 emission factors from 16 individually identified ocean-going ships as they passed under the Lions Gate Bridge in Vancouver, B.C. and their exhaust plumes passed through the sensing beam of the RSD on a bridge directly above. Ship NOx emissions generally agreed with previous studies showing no emissions trends across vessel type. Ship SO2 emissions were reasonable based on expected Environmental Control Area fuel sulfur requirements and corresponded to 0.4-2.4% sulfur in the fuels. This method's specificity of individual vessel SO2 measurements suggests that this technique could be used as a tool to detect high sulfur fuel use in vessels.

  17. Combining support vector regression and ant colony optimization to reduce NOx emissions in coal-fired utility boilers

    SciTech Connect

    Ligang Zheng; Hao Zhou; Chunlin Wang; Kefa Cen

    2008-03-15

    Combustion optimization has recently demonstrated its potential to reduce NOx emissions in high capacity coal-fired utility boilers. In the present study, support vector regression (SVR), as well as artificial neural networks (ANN), was proposed to model the relationship between NOx emissions and operating parameters of a 300 MW coal-fired utility boiler. The predicted NOx emissions from the SVR model, by comparing with that of the ANN-based model, showed better agreement with the values obtained in the experimental tests on this boiler operated at different loads and various other operating parameters. The mean modeling error and the correlation factor were 1.58% and 0.94, respectively. Then, the combination of the SVR model with ant colony optimization (ACO) to reduce NOx emissions was presented in detail. The experimental results showed that the proposed approach can effectively reduce NOx emissions from the coal-fired utility boiler by about 18.69% (65 ppm). A time period of less than 6 min was required for NOx emissions modeling, and 2 min was required for a run of optimization under a PC system. The computing times are suitable for the online application of the proposed method to actual power plants. 37 refs., 8 figs., 3 tabs.

  18. Influence of population density and temporal variations in emissions on the air duality benefits of NOx emission trading.

    PubMed

    Nobel, Carolyn E; McDonald-Buller, Elena C; Kimura, Yosuke; Lumbley, Katherine E; Allen, David T

    2002-08-15

    Ozone formation is a complex function of local hydrocarbon and nitrogen oxide emissions. Therefore, trading of NOx emissions among geographically distributed facilities can lead to more or less ozone formation than across-the-board reductions. Monte Carlo simulations of trading scenarios involving 51 large NOx point sources in eastern Texas were used in a previous study by the authors to assess the effects of trading on air quality benefits, as measured by changes in ozone concentrations. The results indicated that 12% of trading scenarios would lead to greater than a 25% variation from conventional across-the-board reductions when air quality benefits are based only on changes in ozone concentration. The current study found that when benefits are based on a metric related to population exposure to ozone, two-thirds of the trading scenarios lead to changes in air quality benefits of approximately 25%. Variability in air quality benefits is not as strongly dependent on the temporal distribution of NOx emissions.

  19. Air-sampling inlet contamination by aircraft emissions on the NASA CV-990 aircraft

    NASA Technical Reports Server (NTRS)

    Condon, E. P.; Vedder, J. F.

    1984-01-01

    Results of an experimental investigation of the contamination of air sampling inlets by aircraft emissions from the NASA CV-990 research aircraft are presented. This four-engine jet aircraft is a NASA facility used for many different atmospheric and meteorological experiments, as well as for developing spacecraft instrumentation for remote measurements. Our investigations were performed to provide information on which to base the selection of sampling locations for a series of multi-instrument missions for measuring tropospheric trace gases. The major source of contamination is the exhaust from the jet engines, which generate many of the same gases that are of interest in atmospheric chemistry, as well as other gases that may interfere with sampling measurements. The engine exhaust contains these gases in mixing ratios many orders of magnitude greater than those that occur in the clean atmosphere which the missions seek to quantify. Pressurized samples of air were collected simultaneously from a scoop located forward of the engines to represent clean air and from other multiport scoops at various aft positions on the aircraft. The air samples were analyzed in the laboratory by gas chromatography for carbon monoxide, an abundant combustion by-product. Data are presented for various scoop locations under various flight conditions.

  20. Comparison of Anthropogenic CO2, NOx, and CO Emissions: Exploiting a Synergy Between Air Quality and Carbon Cycle Studies

    NASA Astrophysics Data System (ADS)

    Fischer, M. L.; Gurney, K. R.; Gregg, J. S.; Murtishaw, S.; Knox, S.; Andres, R. J.; Sieb, B.

    2005-05-01

    Studies of biospheric CO2 exchange at the regional to continental scale would be facilitated by spatiotemporally resolved estimates of CO2 emissions from fossil fuel combustion and other human activities. However, current estimates of fossil CO2 emissions do not provide sufficient temporal or spatial resolution for regional-scale investigations. The US-EPA National Emission Inventory (NEI) for criteria pollutants (e.g., NOx and CO) was developed for control of regional air quality and currently provides high resolution emissions estimates that are based, in part on, estimates of fuel consumption. Here we investigate the applicability of estimating CO2 emissions from either 1) NEI estimates of NOx or CO emissions, or 2) underlying information on fuel use contained within NEI. First, we calculate monthly sums of NOx and CO emissions separately for mobile, distributed area, and point sources for the 48 continental United States. We compare the aggregate NOx and CO emissions with monthly sums of each states CO2 emissions computed from sales of petroleum, natural gas, and coal as reported by the US Energy Information Agency (EIA). We then compute linear regressions to estimate CO:CO2 and NOx:CO2 emissions ratios and quantify the fraction of variance in CO2 captured by NOx and CO. Although the categories in the two data sets do not overlap perfectly, we find that in the cases where a close correspondence between fuel type and use is expected (e.g., petroleum and mobile sources), variations in NOx and CO explain approximately 80% of the variation in CO2 emissions. Second, we employ the Consolidated Community Emissions Processing Tool (CONCEPT) framework to extract estimates of fuel use or other proxy variables and estimate CO2 directly from the information contained in the NEI, and compare with the EIA estimates of CO2 emissions, and with NEI estimates of NOx and CO emissions as above. Finally, we discuss these results with consideration of previous atmospheric

  1. Comparison of Anthropogenic CO2, NOx, and CO Emissions: Exploiting a Synergy Between Air Quality and Carbon Cycle Studies

    NASA Astrophysics Data System (ADS)

    Fischer, M. L.; Gurney, K. R.; Gregg, J. S.; Murtishaw, S.; Knox, S.; Andres, R. J.; Sieb, B.

    2006-12-01

    Studies of biospheric CO2 exchange at the regional to continental scale would be facilitated by spatiotemporally resolved estimates of CO2 emissions from fossil fuel combustion and other human activities. However, current estimates of fossil CO2 emissions do not provide sufficient temporal or spatial resolution for regional-scale investigations. The US-EPA National Emission Inventory (NEI) for criteria pollutants (e.g., NOx and CO) was developed for control of regional air quality and currently provides high resolution emissions estimates that are based, in part on, estimates of fuel consumption. Here we investigate the applicability of estimating CO2 emissions from either 1) NEI estimates of NOx or CO emissions, or 2) underlying information on fuel use contained within NEI. First, we calculate monthly sums of NOx and CO emissions separately for mobile, distributed area, and point sources for the 48 continental United States. We compare the aggregate NOx and CO emissions with monthly sums of each states CO2 emissions computed from sales of petroleum, natural gas, and coal as reported by the US Energy Information Agency (EIA). We then compute linear regressions to estimate CO:CO2 and NOx:CO2 emissions ratios and quantify the fraction of variance in CO2 captured by NOx and CO. Although the categories in the two data sets do not overlap perfectly, we find that in the cases where a close correspondence between fuel type and use is expected (e.g., petroleum and mobile sources), variations in NOx and CO explain approximately 80% of the variation in CO2 emissions. Second, we employ the Consolidated Community Emissions Processing Tool (CONCEPT) framework to extract estimates of fuel use or other proxy variables and estimate CO2 directly from the information contained in the NEI, and compare with the EIA estimates of CO2 emissions, and with NEI estimates of NOx and CO emissions as above. Finally, we discuss these results with consideration of previous atmospheric

  2. Global Partitioning of NOx Sources Using Satellite Observations: Relative Roles of Fossil Fuel Combustion, Biomass Burning and Soil Emissions

    NASA Technical Reports Server (NTRS)

    Jaegle, Lyatt; Steinberger, Linda; Martin, Randall V.; Chance, Kelly

    2005-01-01

    This document contains the following abstract for the paper "Global partitioning of NOx sources using satellite observations: Relative roles of fossil fuel combustion, biomass burning and soil emissions." Satellite observations have been used to provide important new information about emissions of nitrogen oxides. Nitrogen oxides (NOx) are significant in atmospheric chemistry, having a role in ozone air pollution, acid deposition and climate change. We know that human activities have led to a three- to six-fold increase in NOx emissions since pre-industrial times, and that there are three main surface sources of NOx: fuel combustion, large-scale fires, and microbial soil processes. How each of these sources contributes to the total NOx emissions is subject to some doubt, however. The problem is that current NOx emission inventories rely on bottom-up approaches, compiling large quantities of statistical information from diverse sources such as fuel and land use, agricultural data, and estimates of burned areas. This results in inherently large uncertainties. To overcome this, Lyatt Jaegle and colleagues from the University of Washington, USA, used new satellite observations from the Global Ozone Monitoring Experiment (GOME) instrument. As the spatial and seasonal distribution of each of the sources of NOx can be clearly mapped from space, the team could provide independent topdown constraints on the individual strengths of NOx sources, and thus help resolve discrepancies in existing inventories. Jaegle's analysis of the satellite observations, presented at the recent Faraday Discussion on "Atmospheric Chemistry", shows that fuel combustion dominates emissions at northern mid-latitudes, while fires are a significant source in the Tropics. Additionally, she discovered a larger than expected role for soil emissions, especially over agricultural regions with heavy fertilizer use. Additional information is included in the original extended abstract.

  3. Experimental study on combustion characteristics and NOX emissions of pulverized anthracite preheated by circulating fluidized bed

    NASA Astrophysics Data System (ADS)

    Wang, Jun; Zhu, Jian-Guo; Lu, Qing-Gang

    2011-08-01

    A 30 kW bench-scale rig of pulverized anthracite combustion preheated by a circulating fluidized bed (CFB) was developed. The CFB riser has a diameter of 90 mm and a height of 1,500 mm. The down-fired combustion chamber (DFCC) has a diameter of 260 mm and a height of 3,000 mm. Combustion experiments were carried out using pulverized anthracite with 6.74% volatile content. This low volatile coal is difficult to ignite and burn out. Therefore, it requires longer burnout time and higher combustion temperature, which results in larger NOX emissions. In the current study, important factors that influence the combustion characteristics and NOX emissions were investigated such as excess air ratio, air ratio in the reducing zone, and fuel residence time in the reducing zone. Pulverized anthracite can be quickly preheated up to 800°C in CFB when the primary air is 24% of theoretical air for combustion, and the temperature profile is uniform in DFCC. The combustion efficiency is 94.2%, which is competitive with other anthracite combustion technologies. When the excess air ratio ranges from 1.26 to 1.67, the coal-N conversion ratio is less than 32% and the NOX emission concentration is less than 371 mg/m3 (@6% O2). When the air ratio in the reducing zone is 0.12, the NOX concentration is 221 mg/m3 (@6% O2), and the coal-N conversion ratio is 21%, which is much lower than that of other boilers.

  4. Physical characterization of the fine particle emissions from commercial aircraft engines during the Aircraft Particle Emissions Experiment (APEX) 1 to 3

    EPA Science Inventory

    The f1me particulate matter (PM) emissions from nine commercial aircraft engine models were determined by plume sampling during the three field campaigns of the Aircraft Particle Emissions Experiment (APEX). Ground-based measurements were made primarily at 30 m behind the engine ...

  5. Variability in operation-based NO(x) emission factors with different test routes, and its effects on the real-driving emissions of light diesel vehicles.

    PubMed

    Lee, Taewoo; Park, Junhong; Kwon, Sangil; Lee, Jongtae; Kim, Jeongsoo

    2013-09-01

    The objective of this study is to quantify the differences in NO(x) emissions between standard and non-standard driving and vehicle operating conditions, and to estimate by how much NO(x) emissions exceed the legislative emission limits under typical Korean road traffic conditions. Twelve Euro 3-5 light-duty diesel vehicles (LDDVs) manufactured in Korea were driven on a chassis dynamometer over the standard New European Driving Cycle (NEDC) and a representative Korean on-road driving cycle (KDC). NO(x) emissions, average speeds and accelerations were calculated for each 1-km trip segment, so called averaging windows. The results suggest that the NO(x) emissions of the tested vehicles are more susceptible to variations in the driving cycles than to those in the operating conditions. Even under comparable operating conditions, the NO(x) control capabilities of vehicles differ from each other, i.e., NO(x) control is weaker for the KDC than for the NEDC. The NO(x) emissions over the KDC for given vehicle operating conditions exceed those over the NEDC by more than a factor of 8. Consequently, on-road NO(x) emission factors are estimated here to exceed the Euro 5 emission limit by up to a factor of 8, 4 and 3 for typical Korean urban, rural, and motorway road traffic conditions, respectively. Our findings support the development of technical regulations for supplementary real-world emission tests for emission certification and the corresponding research actions taken by automotive industries. PMID:23747552

  6. 40 CFR 75.17 - Specific provisions for monitoring emissions from common, bypass, and multiple stacks for NOX...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... emissions from common, bypass, and multiple stacks for NOX emission rate. 75.17 Section 75.17 Protection of... MONITORING Monitoring Provisions § 75.17 Specific provisions for monitoring emissions from common, bypass... § 75.17(d) for units with bypass stacks. Further, this option shall not be used unless the...

  7. Aircraft HO sub x and NO sub x emission effects on stratospheric ozone and temperature

    NASA Technical Reports Server (NTRS)

    Glatt, L.; Widhopf, G. F.

    1978-01-01

    A simplified two-dimensional steady-state photochemical model of the atmosphere was developed. The model was used to study the effect on the thermal and chemical structure of the atmosphere of two types of pollution cases: (1) injection of NOx and HOx from a hypothetical fleet of supersonic and subsonic aircraft and (2) injection of HOx from a hypothetical fleet of liquid-fueled hydrogen aircraft. The results are discussed with regard to stratospheric perturbations in ozone, water vapor and temperature.

  8. Analysis of long-term observations of NOx and CO in megacities and application to constraining emissions inventories

    NASA Astrophysics Data System (ADS)

    Hassler, Birgit; McDonald, Brian C.; Frost, Gregory J.; Borbon, Agnes; Carslaw, David C.; Civerolo, Kevin; Granier, Claire; Monks, Paul S.; Monks, Sarah; Parrish, David D.; Pollack, Ilana B.; Rosenlof, Karen H.; Ryerson, Thomas B.; Schneidemesser, Erika; Trainer, Michael

    2016-09-01

    Long-term atmospheric NOx/CO enhancement ratios in megacities provide evaluations of emission inventories. A fuel-based emission inventory approach that diverges from conventional bottom-up inventory methods explains 1970-2015 trends in NOx/CO enhancement ratios in Los Angeles. Combining this comparison with similar measurements in other U.S. cities demonstrates that motor vehicle emissions controls were largely responsible for U.S. urban NOx/CO trends in the past half century. Differing NOx/CO enhancement ratio trends in U.S. and European cities over the past 25 years highlights alternative strategies for mitigating transportation emissions, reflecting Europe's increased use of light-duty diesel vehicles and correspondingly slower decreases in NOx emissions compared to the U.S. A global inventory widely used by global chemistry models fails to capture these long-term trends and regional differences in U.S. and Europe megacity NOx/CO enhancement ratios, possibly contributing to these models' inability to accurately reproduce observed long-term changes in tropospheric ozone.

  9. Neural network boiler optimization of efficiency, emission, and reliability with TVA Kingston Unit 3 low NOx optimization test results

    SciTech Connect

    Chang, P.S.; Poston, J.M.; Schroech, K.A.; Hou, H.S.

    1995-12-31

    Boiler performance optimization includes the preservation of efficiency, emission, capacity, and reliability. Competitive pressures require cost reduction and environmental compliance. It is a challenge for utility personnel to balance these requirements often demand tradeoffs. The Clean Air Act Amendment requires utilities to reduce NOx emission. NOx emission reduction has often been accomplished by installation of new low NOx burners. Boiler tuning for NOx control can be used as an alternative to low NOx burner installation. Specifically in tangentially-fired boilers, boiler tuning can be very effective in NOx reduction. A PC-based computer software program was developed to assist the tuning process. This software, System Optimization Analysis Program (SOAP), is a neural network based code which uses the self-adaptation learning process, with an adaptive filter added for data noise control. SOAP can use historical data as the knowledge base and provides a fast optimal solution to adaptive control problems. SOAP was tested at TVA`s Kingston Unit 3 tangentially coal-fired furnace for NOx reduction. With a well-organized test plan, the optimized solution was reached with 16 tests at each test series load level. SOAP will be used for other plant equipment or system optimization, such as pulverizer performance, combustion system optimization, compared thermal performance design, and boiler tube leak detection and allocation.

  10. Alkali- and Sulfur-Resistant Tungsten-Based Catalysts for NOx Emissions Control.

    PubMed

    Huang, Zhiwei; Li, Hao; Gao, Jiayi; Gu, Xiao; Zheng, Li; Hu, Pingping; Xin, Ying; Chen, Junxiao; Chen, Yaxin; Zhang, Zhaoliang; Chen, Jianmin; Tang, Xingfu

    2015-12-15

    The development of catalysts with simultaneous resistance to alkalis and sulfur poisoning is of great importance for efficiently controlling NOx emissions using the selective catalytic reduction of NOx with NH3 (SCR), because the conventional V2O5/WO3-TiO2 catalysts often suffer severe deactivation by alkalis. Here, we support V2O5 on a hexagonal WO3 (HWO) to develop a V2O5/HWO catalyst, which has exceptional resistance to alkali and sulfur poisoning in the SCR reactions. A 350 μmol g(-1) K(+) loading and the presence of 1,300 mg m(-3) SO2 do not almost influence the SCR activity of the V2O5/HWO catalyst, and under the same conditions, the conventional V2O5/WO3-TiO2 catalysts completely lost the SCR activity within 4 h. The strong resistance to alkali and sulfur poisoning of the V2O5/HWO catalysts mainly originates from the hexagonal structure of the HWO. The HWO allows the V2O5 to be highly dispersed on the external surfaces for catalyzing the SCR reactions and has the relatively smooth surfaces and the size-suitable tunnels specifically for alkalis' diffusion and trapping. This work provides a useful strategy to develop SCR catalysts with exceptional resistance to alkali and sulfur poisoning for controlling NOx emissions from the stationary source and the mobile source.

  11. 77 FR 65823 - Control of Air Pollution From Aircraft and Aircraft Engines; Emission Standards and Test Procedures

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-10-31

    ... From the Federal Register Online via the Government Publishing Office ENVIRONMENTAL PROTECTION AGENCY 40 CFR Parts 87 RIN 2060-AO70 Control of Air Pollution From Aircraft and Aircraft Engines; Emission Standards and Test Procedures Correction In rule document 2012-13828 appearing on pages...

  12. Experimental investigation on NOx emission characteristics of a new solid fuel made from sewage sludge mixed with coal in combustion.

    PubMed

    Zhai, Yunbo; Zhu, Lu; Chen, Hongmei; Xu, Bibo; Li, Caiting; Zeng, Guangming

    2015-02-01

    In this article, a new briquette fuel (SC), which was produced by the mixture of coal fines (25.9%), sewage sludge (60.6%), lignin (4.5%), tannic acid (4.5%) and elemental silicon (4.5%), was provided. Then, in a high temperature electric resistance tubular furnace, the total emissions of NO2 and NO, effects of combustion temperature, air flow rate and heating rate on NOx (NO, NO2) emissions of SC were studied during the combustion of SC; furthermore, effects of additives on hardness were also analysed, and the X-ray photoelectron spectroscopy was applied to investigate the reduced NOx emission mechanism. The research results showed that, compared with the characteristics of briquette fuel (SC0) produced only by the mixture of coal and sewage sludge (the ratio of coal to sewage sludge was the same as that of SC), the Meyer hardness of SC was 12.6% higher than that of SC0 and the emissions of NOx were 27.83% less than that of SC0 under the same combustion conditions. The NOx emissions of SC decreased with the adding of heating rate and increased with the rise of air flow rate. When the temperature was below 1000 °C, the emissions of NOx increased with the elevated temperature, however, further temperature extension will result in a decreasing in emissions of NOx. Furthermore, the X-ray photoelectron spectroscopy results proposed that the possible mechanism for the reduction of NOx emissions was nitrogen and silicon in SC to form the compounds of silicon and nitrogen at high temperatures.

  13. UTILIZING WATER EMULSIFICATION TO REDUCE NOX AND PARTICULATE EMISSIONS ASSOCIATED WITH BIODIESEL

    SciTech Connect

    Kass, Michael D; Lewis Sr, Samuel Arthur; Lee, Doh-Won; Huff, Shean P; Storey, John Morse; Swartz, Matthew M; Wagner, Robert M

    2009-01-01

    A key barrier limiting extended utilization of biodiesel is higher NOx emissions compared to petrodiesel fuels. The reason for this effect is unclear, but various researchers have attributed this phenomena to the higher liquid bulk modulus associated with biodiesel and the additional heat released during the breaking of C-C double bonds in the methyl ester groups. In this study water was incorporated into neat biodiesel (B100) as an emulsion in an attempt to lower NOx and particulate matter (PM) emissions. A biodiesel emulsion containing 10wt% water was formulated and evaluated against an ultra-low sulfur petroleum diesel (ULSD) and neat biodiesel (B100) in a light-duty diesel engine operated at 1500RPM and at loads of 68Nm (50ft-lbs) and 102Nm (75ft-lbs). The influence of exhaust gas recirculation (EGR) was also examined. The incorporation of water was found to significantly lower the NOx emissions of B100, while maintaining fuel efficiency when operating at 0 and 27% EGR. The soot fraction of the particulates (as determined using an opacity meter) was much lower for the B100 and B100-water emulsion compared ULSD. In contrast, total PM mass (for the three fuel types) was unchanged for the 0% EGR condition but was significantly lower for the B100 and B100-emulsion during the 27% EGR condition compared to the ULSD fuel. Analysis of the emissions and heat release data indicate that water enhances air-fuel premixing to maintain fuel economy and lower soot formation. The exhaust chemistry of the biodiesel base fuels (B100 and water-emulsified B100) was found to be unique in that they contained measurable levels of methyl alkenoates, which were not found for the ULSD. These compounds were formed by the partial cracking of the methyl ester groups during combustion.

  14. Reductions in particulate and NO(x) emissions by diesel engine parameter adjustments with HVO fuel.

    PubMed

    Happonen, Matti; Heikkilä, Juha; Murtonen, Timo; Lehto, Kalle; Sarjovaara, Teemu; Larmi, Martti; Keskinen, Jorma; Virtanen, Annele

    2012-06-01

    Hydrotreated vegetable oil (HVO) diesel fuel is a promising biofuel candidate that can complement or substitute traditional diesel fuel in engines. It has been already reported that by changing the fuel from conventional EN590 diesel to HVO decreases exhaust emissions. However, as the fuels have certain chemical and physical differences, it is clear that the full advantage of HVO cannot be realized unless the engine is optimized for the new fuel. In this article, we studied how much exhaust emissions can be reduced by adjusting engine parameters for HVO. The results indicate that, with all the studied loads (50%, 75%, and 100%), particulate mass and NO(x) can both be reduced over 25% by engine parameter adjustments. Further, the emission reduction was even higher when the target for adjusting engine parameters was to exclusively reduce either particulates or NO(x). In addition to particulate mass, different indicators of particulate emissions were also compared. These indicators included filter smoke number (FSN), total particle number, total particle surface area, and geometric mean diameter of the emitted particle size distribution. As a result of this comparison, a linear correlation between FSN and total particulate surface area at low FSN region was found.

  15. Estimates of ozone response to various combinations of NO(x) and VOC emission reductions in the eastern United States

    NASA Technical Reports Server (NTRS)

    Roselle, Shawn J.; Schere, Kenneth L.; Chu, Shao-Hang

    1994-01-01

    There is increasing recognition that controls on NO(x) emissions may be necessary, in addition to existing and future Volatile Organic Compounds (VOC) controls, for the abatement of ozone (O3) over portions of the United States. This study compares various combinations of anthropogenic NO(x) and VOC emission reductions through a series of model simulations. A total of 6 simulations were performed with the Regional Oxidant Model (ROM) for a 9-day period in July 1988. Each simulation reduced anthropogenic NO(x) and VOC emissions across-the-board by different amounts. Maximum O3 concentrations for the period were compared between the simulations. Comparison of the simulations suggests that: (1) NO(x) controls may be more effective than VOC controls in reducing peak O3 over most of the eastern United States; (2) VOC controls are most effective in urban areas having large sources of emissions; (3) NO(x) controls may increase O3 near large point sources; and (4) the benefit gained from increasing the amount of VOC controls may lessen as the amount of NO(x) control is increased. This paper has been reviewed in accordance with the U.S. Environmental Protection Agency's peer and administrative review policies and approved for presentation and publication. Mention of trade names or commercial products does not constitute endorsement or recommendation for use.

  16. Reduction of aircraft gas turbine engine pollutant emissions

    NASA Technical Reports Server (NTRS)

    Diehl, L. A.

    1978-01-01

    To accomplish simultaneous reduction of unburned hydrocarbons, carbon monoxide, and oxides of nitrogen, required major modifications to the combustor. The modification most commonly used was a staged combustion technique. While these designs are more complicated than production combustors, no insurmountable operational difficulties were encountered in either high pressure rig or engine tests which could not be resolved with additional normal development. The emission reduction results indicate that reductions in unburned hydrocarbons were sufficient to satisfy both near and far-termed EPA requirements. Although substantial reductions were observed, the success in achieving the CO and NOx standards was mixed and depended heavily on the engine/engine cycle on which it was employed. Technology for near term CO reduction was satisfactory or marginally satisfactory. Considerable doubt exists if this technology will satisfy all far-term requirements.

  17. Latest results on reducing NOx emissions at American Electric Power's coal fired utility boilers with DB Riley's CCV burner technologies

    SciTech Connect

    Patel, R.; Penterson, C.; Weinshiemer, J.

    2000-07-01

    American Electric Power Service Corporation (AEP) and DB Riley, Inc., under an alliance arrangement, have retrofitted eight coal fired utility boilers with DB Riley's Controlled Combustion Venturi (CCV{reg_sign}) burners for reducing NOx emissions prior to SCR and/or SNCR installations on some of these units. These units all burn eastern bituminous coal and range in size from 260 to 1,300 MWn. The larger utility boilers are equipped with cell fired burners while the smaller units utilize more traditional single circular coal burners. The low NOx CCV{reg_sign} burner technology installed consisted of a variety of different designs including CCV{reg_sign} single register and CCV{reg_sign} cell burners. All burners were designed to be a ``plug into the existing waterwall openings'' type to preclude pressure part modifications. The most unique retrofit involved the installation of low NOx burners on all four-furnace walls of a 450 MWn utility boiler. Pre-retrofit baseline NOx levels on these eight (8) utility boilers ranged from 0.9 to 1.6 lb/mmbtu while post-retrofit NOx emission levels ranged from 0.42 to 0.70 lb/mmbtu. This represents about 50--60% reduction in NOx from uncontrolled levels using the burners only technology. This paper describes the latest results from this major low NOx burner retrofit project.

  18. Optical remote sensing of aircraft emissions with the K300

    SciTech Connect

    Bittner, H.; Klein, V.; Eisenmann, T.; Engler, F.; Resch, M.; Mosebach, H.; Erhard, M.; Rippel, H. )

    1993-01-01

    The K300 Double Pendulum Interferometer is a compact high resolution Fourier Transform spectrometer designed for outdoor optical remote sensing in the infrared spectral region. Apart from the known atmospheric pollution monitoring by long-path measurements and smoke stack remote sensing at power plants, the remote diagnostic of hot aircraft engine emissions is a very interesting application of the infrared spectroscopy. First results of such measurements performed with the Kayser-Threde Double Pendulum Interferometer K300 at the DLR airport, Oberpfaffenhofen on January 15, 1992 are presented and discussed.

  19. Trajectory modeling of emissions from lower stratospheric aircraft

    NASA Astrophysics Data System (ADS)

    Sparling, Lynn C.; Schoeberl, Mark R.; Douglass, Anne R.; Weaver, Clark J.; Newman, Paul A.; Lait, Leslie R.

    1995-01-01

    A series of isentropic trajectory calculations has been performed for emissions by stratospheric aircraft moving across the northern midlatitude oceanic flight corridors. Emission of exhaust is simulated by the daily initialization of air parcels along a flight path on the 500 K isentropic surface. Parcels are tracked during the first three weeks of each January from 1980 to 1994 in order to determine the interannual variability in the spatial distribution of the exhaust and the likelihood of exposure to cold temperatures. Few parcels emitted along these flight paths at this time of year were found to have experienced nitric acid trihydrate (NAT) formation temperatures, except for the particularly cold Januarys 1986, 1987, and 1992. We also find that large zonal fluctuations in the distribution of the emissions are typical for this time of year and are strongly dependent on flight path. An extended 6-month (January-June) run in which parcels were released daily along the New York-London route shows that emissions in the flight corridor increase at a time-averaged rate which is nearly twice the rate at which the zonal average increases. In addition, local fluctuations of pollutant density can be several times higher than the zonal average and can persist for several weeks. A study of seasonal variability also shows a rapid buildup of emissions during the summer months. These elevated emission levels must be considered in the interpretation of environmental impact assessments based on two-dimensional transport models.

  20. Trajectory modeling of emissions from lower stratospheric aircraft

    SciTech Connect

    Sparling, L.C.; Lait, L.R.; Weaver, C.J.

    1995-01-20

    A series of isentropic trajectory calculations has been performed for emissions by stratospheric aircraft moving across the northern midlatitude oceanic flight corridors. Emission of exhaust is simulated by the daily initialization of air parcels along a flight path on the 500 K isentropic surface. Parcels are tracked during the first three weeks of each January from 1980 to 1994 in order to determine the interannual variability in the spatial distribution of the exhaust and the liklihood of exposure to cold temperatures. Few parcels emitted along these flights paths at this time of year were found to have experienced nitric acid trihydrate (NAT) formation temperatures, except for the particularly cold Januarys 1986, 1987, and 1992. The authors also find that large zonal fluctuations in the distribution of the emissions are typical for this time of year and are strongly dependent on flight path. An extended 6-month (January-June) run in which parcels were released daily along the New York-London route shows that emissions in the flight corridor increase at a time-averaged rate which is nearly twice the rate at which the zonal average increases. In addition, local fluctuations of pollutant density can be several times higher than the zonal average and can persist for several weeks. A study of seasonal variability also shows a rapid buildup of emissions during the summer months. These elevated emission levels must be considered in the interpretation of environmental impact assessments based on two-dimensional transport models. 31 refs., 16 figs.

  1. Military Aircraft Emissions Research - Case of Hercules Cargo Plane (C-130H) Emissions

    SciTech Connect

    Cheng, Mengdawn; Corporan, E.; DeWitt, M.; Harris, B.; Hashmonay, R.; Holdren, M.; Kaganan, R.; Spicer, C.

    2007-01-01

    Tactical airlifter like C-130H has been in use for more than 50 years, and is expected to serve for many years to come. However, the emission characteristics data of the aircraft are scarce. To increase our understanding of turboprop engine emissions, emissions from a military C-130H cargo aircraft were characterized in field conditions in the fall of 2005. Particulate and gaseous pollutants were measured by conventional and advanced instrumentation platforms that were built with in-situ extractive or remote optical sensing technologies. The measurements performed at the C-130H engine exhaust exit showed increased levels of emissions as the engine power setting increased. In contrast, there was no such a relationship found for the C-130H emitted particulate matter (as a function of engine power setting) measured at about 15-m downstream of the engine exhaust plane. The emitted gaseous species measured at both locations were, however, proportional to the engine power setting and comparable (at both locations) when corrected for ambient dilution indicating the lack of particulate emission-power setting relationship at the far field is unique. The result clearly indicates that the aircraft emission factor or index for particulate matter cannot be experimentally determined at a downstream location away from the exhaust exit and has to be determined right at the engine exhaust plane. Emission indices that are needed for air quality modeling will be presented.

  2. Study of air emissions related to aircraft deicing

    SciTech Connect

    Zarubiak, D.C.Z.; DeToro, J.A.; Menon, R.P.

    1997-12-31

    This paper outlines the results of a study that was conducted by Trinity Consultants Incorporated (Trinity) to estimate the airborne emissions of glycol from Type 1 Deicer fluid and potential exposure of ground personnel during routine deicing of aircraft. The study involved the experimental measurement of Type 1 Deicer fluid vapor emissions by Southern Research Institute (SRI, Research Triangle Park, NC). An open path Fourier Transform Infrared (FTIR) spectroscopic technique developed by SRI was used during a simulated airplane deicing event. The emissions measurement data are analyzed to obtain appropriate emission rates for an atmospheric dispersion modeling analysis. The modeled gaseous Type 1 Deicer fluid concentrations are determined from calculated emission rates and selected meteorological conditions. A propylene glycol (PG)-based Type 1 Deicer fluid was used. In order to examine the effects of the assumptions that are made for the development of the emission quantification and dispersion modeling methodologies, various scenarios are evaluated. A parametric analysis evaluates the effect of variations in the following parameters on the results of the study: glycol concentrations in deicing fluids, error limits of emission measurements, emission source heights, evaporation rate for various wind speeds, wind directions over typical physical layouts, and background (ambient) Type 1 Deicer fluid concentrations. The emissions for an EG based Type 1 Deicing fluid are expected to be between 80 and 85% of the reported data. In general, the model shows the region of maximum concentrations is located between 20 and 50 meters downwind from the trailing edge of the wing. This range is consistent with experimental findings. Depending on the specific modeled scenarios, maximum glycol concentrations are found to generally range between 50 and 500 milligrams per cubic meter.

  3. Analysis of UK and European NOx and VOC emission scenarios in the Defra model intercomparison exercise

    NASA Astrophysics Data System (ADS)

    Derwent, Richard; Beevers, Sean; Chemel, Charles; Cooke, Sally; Francis, Xavier; Fraser, Andrea; Heal, Mathew R.; Kitwiroon, Nutthida; Lingard, Justin; Redington, Alison; Sokhi, Ranjeet; Vieno, Massimo

    2014-09-01

    Simple emission scenarios have been implemented in eight United Kingdom air quality models with the aim of assessing how these models compared when addressing whether photochemical ozone formation in southern England was NOx- or VOC-sensitive and whether ozone precursor sources in the UK or in the Rest of Europe (RoE) were the most important during July 2006. The suite of models included three Eulerian-grid models (three implementations of one of these models), a Lagrangian atmospheric dispersion model and two moving box air parcel models. The assignments as to NOx- or VOC-sensitive and to UK- versus RoE-dominant, turned out to be highly variable and often contradictory between the individual models. However, when the assignments were filtered by model performance on each day, many of the contradictions could be eliminated. Nevertheless, no one model was found to be the 'best' model on all days, indicating that no single air quality model could currently be relied upon to inform policymakers robustly in terms of NOx- versus VOC-sensitivity and UK- versus RoE-dominance on each day. It is important to maintain a diversity in model approaches.

  4. Closed loop engine control for regulating NOx emissions, using a two-dimensional fuel-air curve

    DOEpatents

    Bourn, Gary D.; Smith, Jack A.; Gingrich, Jess W.

    2007-01-30

    An engine control strategy that ensures that NOx emissions from the engine will be maintained at an acceptable level. The control strategy is based on a two-dimensional fuel-air curve, in which air manifold pressure (AMP) is a function of fuel header pressure and engine speed. The control strategy provides for closed loop NOx adjustment to a base AMP value derived from the fuel-air curve.

  5. Analysis of aircraft exhausts with Fourier-transform infrared emission spectroscopy.

    PubMed

    Heland, J; Schäfer, K

    1997-07-20

    Because of the worldwide growth in air traffic and its increasing effects on the atmospheric environment, it is necessary to quantify the direct aircraft emissions at all altitudes. In this study Fourier-transform infrared emission spectroscopy as a remote-sensing multi-component-analyzing technique for aircraft exhausts was investigated at ground level with a double pendulum interferometer and a line-by-line computer algorithm that was applied to a multilayer radiative transfer problem. Initial measurements were made to specify the spectral windows for traceable compounds, to test the sensitivity of the system, and to develop calibration and continuum handling procedures. To obtain information about the radial temperature and concentration profiles, we developed an algorithm for the analysis of an axial-symmetric multilayered plume by use of the CO(2) hot band at approximately 2400 cm(-1). Measurements were made with several in-service engines. Effects that were due to engine aging were detected but have to be analyzed systematically in the near future. Validation measurements were carried out with a conventional propane gas burner to compare the results with those obtained with standard measurement equipment. These measurements showed good agreement to within +/-20% for the CO and NO(x) results. The overall accuracy of the system was found to be +/-30%. The detection limits of the system for a typical engine plume (380 degrees C, ? = 50 cm) are below 0.1% for CO(2), ~0.7% for H(2)O, ~20 ppmv (parts per million by volume) for CO, and ~90 ppmv for NO.

  6. Analysis of aircraft exhausts with Fourier-transform infrared emission spectroscopy.

    PubMed

    Heland, J; Schäfer, K

    1997-07-20

    Because of the worldwide growth in air traffic and its increasing effects on the atmospheric environment, it is necessary to quantify the direct aircraft emissions at all altitudes. In this study Fourier-transform infrared emission spectroscopy as a remote-sensing multi-component-analyzing technique for aircraft exhausts was investigated at ground level with a double pendulum interferometer and a line-by-line computer algorithm that was applied to a multilayer radiative transfer problem. Initial measurements were made to specify the spectral windows for traceable compounds, to test the sensitivity of the system, and to develop calibration and continuum handling procedures. To obtain information about the radial temperature and concentration profiles, we developed an algorithm for the analysis of an axial-symmetric multilayered plume by use of the CO(2) hot band at approximately 2400 cm(-1). Measurements were made with several in-service engines. Effects that were due to engine aging were detected but have to be analyzed systematically in the near future. Validation measurements were carried out with a conventional propane gas burner to compare the results with those obtained with standard measurement equipment. These measurements showed good agreement to within +/-20% for the CO and NO(x) results. The overall accuracy of the system was found to be +/-30%. The detection limits of the system for a typical engine plume (380 degrees C, ? = 50 cm) are below 0.1% for CO(2), ~0.7% for H(2)O, ~20 ppmv (parts per million by volume) for CO, and ~90 ppmv for NO. PMID:18259296

  7. 40 CFR Appendix E to Part 75 - Optional NOX Emissions Estimation Protocol for Gas-Fired Peaking Units and Oil-Fired Peaking Units

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ....1Initial Performance Testing Use the following procedures for: measuring NOX emission rates at heat input rate levels corresponding to different load levels; measuring heat input rate; and plotting the correlation between heat input rate and NOX emission rate, in order to determine the emission rate of the...

  8. Airborne Observations of Aerosol Emissions from F-16 Aircraft

    NASA Technical Reports Server (NTRS)

    Anderson, B. E.; Cofer, W. R.; McDougal, D. S.

    1999-01-01

    We presented results from the SASS Near-Field Interactions Flight (SNIF-III) Experiment which was conducted during May and June 1997 in collaboration with the Vermont and New Jersey Air National Guard Units. The project objectives were to quantify the fraction of fuel sulfur converted to S(VI) species by jet engines and to gain a better understanding of particle formation and growth processes within aircraft wakes. Size and volatility segregated aerosol measurements along with sulfur species measurements were recorded in the exhaust of F-16 aircraft equipped with F-100 engines burning fuels with a range of fuel S concentrations at different altitudes and engine power settings. A total of 10 missions were flown in which F-16 exhaust plumes were sampled by an instrumented T-39 Sabreliner aircraft. On six of the flights, measurements were obtained behind the same two aircraft, one burning standard JP-8 fuel and the other either approximately 28 ppm or 1100 ppm S fuel or an equal mixture of the two (approximately 560 ppm S). A pair of flights was conducted for each fuel mixture, one at 30,000 ft altitude and the other starting at 35,000 ft and climbing to higher altitudes if contrail conditions were not encountered at the initial flight level. In each flight, the F-16s were operated at two power settings, approx. 80% and full military power. Exhaust emissions were sampled behind both aircraft at each flight level, power setting, and fuel S concentration at an initial aircraft separation of 30 m, gradually widening to about 3 km. Analyses of the aerosol data in the cases where fuel S was varied suggest results were consistent with observations from project SUCCESS, i.e., a significant fraction of the fuel S was oxidized to form S(VI) species and volatile particle emission indices (EIs) in comparably aged plumes exhibited a nonlinear dependence upon the fuel S concentration. For the high sulfur fuel, volatile particle EIs in 10-second-old-plumes were 2 to 3 x 10 (exp 17

  9. Damages and Expected Deaths Due to Excess NOx Emissions from 2009 to 2015 Volkswagen Diesel Vehicles.

    PubMed

    Holland, Stephen P; Mansur, Erin T; Muller, Nicholas Z; Yates, Andrew J

    2016-02-01

    We estimate the damages and expected deaths in the United States due to excess emissions of NOx from 2009 to 2015 Volkswagen diesel vehicles. Using data on vehicle registrations and a model of pollution transport and valuation, we estimate excess damages of $430 million and 46 excess expected deaths. Accounting for uncertainty about emissions gives a range for damages from $350 million to $500 million, and a range for excess expected deaths from 40 to 52. Our estimates incorporate significant local heterogeneity: for example, Minneapolis has the highest damages despite having fewer noncompliant vehicles than 13 other cities. Our estimated damages greatly exceed possible benefits from reduced CO2 emissions due to increased fuel economy. PMID:26720281

  10. Damages and Expected Deaths Due to Excess NOx Emissions from 2009 to 2015 Volkswagen Diesel Vehicles.

    PubMed

    Holland, Stephen P; Mansur, Erin T; Muller, Nicholas Z; Yates, Andrew J

    2016-02-01

    We estimate the damages and expected deaths in the United States due to excess emissions of NOx from 2009 to 2015 Volkswagen diesel vehicles. Using data on vehicle registrations and a model of pollution transport and valuation, we estimate excess damages of $430 million and 46 excess expected deaths. Accounting for uncertainty about emissions gives a range for damages from $350 million to $500 million, and a range for excess expected deaths from 40 to 52. Our estimates incorporate significant local heterogeneity: for example, Minneapolis has the highest damages despite having fewer noncompliant vehicles than 13 other cities. Our estimated damages greatly exceed possible benefits from reduced CO2 emissions due to increased fuel economy.

  11. Mixing and NOx Emission Calculations of Confined Reacting Jet Flows in Cylindrical and Annular Ducts

    NASA Technical Reports Server (NTRS)

    Oechsle, Victor L.; Connor, Christopher H.; Holdeman, James D. (Technical Monitor)

    2000-01-01

    Rapid mixing of cold lateral jets with hot cross-stream flows in confined configurations is of practical interest in gas turbine combustors as it strongly affects combustor exit temperature quality, and gaseous emissions in for example rich-lean combustion. It is therefore important to further improve our fundamental understanding of the important processes of dilution jet mixing especially when the injected jet mass flow rate exceeds that of the cross-stream. The results reported in this report describe some of the main flow characteristics which develop in the mixing process in a cylindrical duct. A three-dimensional computational fluid dynamics (CFD) code has been used to predict the mixing flow field characteristics and NOx emission in a quench section of a rich-burn/quick-mix/lean-burn (RQL) combustor. Sixty configurations have been analyzed in both circular and annular geometries in a fully reacting environment simulating the operating condition of an actual RQL gas turbine combustion liner. The evaluation matrix was constructed by varying the number of orifices per row and orifice shape. Other parameters such as J (momentum-flux ratio), MR (mass flowrate ratio), DR (density ratio), and mixer sector orifice ACd (effective orifice area) were maintained constant throughout the entire study. The results indicate that the mixing flow field can be correlated with the NOx production if they are referenced with the stoichiometric equivalence ratio value and not the equilibrium value. The mixing flowfields in both circular and annular mixers are different. The penetration of equal jets in both annular and circular geometries is vastly different which significantly affects the performance of the mixing section. In the computational results with the circular mixer, most of the NOx formation occurred behind the orifice starting at the orifice wake region. General trends have been observed in the NOx production as the number of orifices is changed and this appears to be

  12. Estimations of primary nitrogen dioxide exhaust emissions from chemiluminescence NOx measurements in a UK road tunnel.

    PubMed

    Simmons, W A; Seakins, P W

    2012-11-01

    NO and NO(2) measurements have been made using the chemiluminescence method from 115 weekdays during the period 4th Jan-10th Sep 2010 in a well characterised, unventilated tunnel on the Leeds Inner Ring Road. Measurements are made at two points in the tunnel and the difference in NO and NO(2) was attributed to emissions from vehicles in the tunnel. These data have been used to determine the fraction of NOx (NO+NO(2)) as primary NO(2) (f-NO(2)) from vehicles using the tunnel. The average value of f-NO(2) from 7 am to 7 pm was 0.17 (-0.03)(+0.01) in agreement with estimations from the UK National Atmospheric Emissions Inventory (NAEI). However, during the day there was a reproducible increase in f-NO(2) from approximately 0.10 at 7 am to 0.21 at 7 pm which is not reproduced with the current UK vehicle fleet emissions inventories. The increase in f-NO(2) can be qualitatively linked to a decrease in the fraction of NOx arising from heavy goods vehicles and buses. PMID:23000714

  13. Using satellite observations to quantify biomass burning emissions of NOx, and hydrocarbons in the Tropics

    NASA Technical Reports Server (NTRS)

    Jaegle, Lyatt

    2005-01-01

    This is the final report for "Using satellite observations to quantify biomass burning emissions of NOx and hydrocarbons in the Tropics", funded through the New Investigator Program between March 2001 and March 2005. This period includes a 1-year no-cost extension of the original award. This report summarizes our accomplishments during the duration of the grant. Section 2 focuses on the research component of this work, while section 3 describes the education component. The personnel supported under this project is given in section 4. Section 5 lists publications resulting from NASA support and section 6 provides a list of conferences and seminars where the results were presented.

  14. Anthropogenic emissions of NOx over China: Reconciling the difference of inverse modeling results using GOME-2 and OMI measurements

    SciTech Connect

    Gu, Dasa; Wang, Yuhang; Smeltzer, Charles; Boersma, K. Folkert

    2014-06-27

    Inverse modeling using satellite observations of nitrogen dioxide (NO2) columns has been extensively used to estimate nitrogen oxides (NOx) emissions in China. Recently, the Global Ozone Monitoring Experiment-2 (GOME-2) and Ozone Monitoring Instrument (OMI) provide independent global NO2 column measurements on a nearly daily basis at around 9:30 and 13:30 local time across the equator, respectively. Anthropogenic NOx emission estimates by applying previously developed monthly inversion (MI) or daily inversion (DI) methods to these two sets of measurements show substantial differences. We improve the DI method by conducting model simulation, satellite retrieval, and inverse modeling sequentially on a daily basis. After each inversion, we update anthropogenic NOx emissions in the model simulation with the newly obtained a posteriori results. Consequently, the inversion-optimized emissions are used to compute the a priori NO2 profiles for satellite retrievals. As such, the a priori profiles used in satellite retrievals are now coupled to inverse modeling results. The improved procedure was applied to GOME-2 and OMI NO2 measurements in 2011. The new daily retrieval-inversion (DRI) method estimates an average NOx emission of 6.9 Tg N/yr over China, and the difference between using GOME-2 and OMI measurements is 0.4 Tg N/yr, which is significantly smaller than the difference of 1.3 Tg N/yr using the previous DI method. Using the more consistent DRI inversion results, we find that anthropogenic NOx emissions tend to be higher in winter and summer than spring (and possibly fall) and the weekday-to-weekend emission ratio tends to increase with NOx emission in China.

  15. Design and testing of an independently controlled urea SCR retrofit system for the reduction of NOx emissions from marine diesels.

    PubMed

    Johnson, Derek R; Bedick, Clinton R; Clark, Nigel N; McKain, David L

    2009-05-15

    Diesel engine emissions for on-road, stationary and marine applications are regulated in the United States via standards set by the Environmental Protection Agency (EPA). A major component of diesel exhaust that is difficult to reduce is nitrogen oxides (NOx). Selective catalytic reduction (SCR) has been in use for many years for stationary applications, including external combustion boilers, and is promising for NOx abatement as a retrofit for mobile applications where diesel compression ignition engines are used. The research presented in this paper is the first phase of a program focused on the reduction of NOx by use of a stand-alone urea injection system, applicable to marine diesel engines typical of work boats (e.g., tugs). Most current urea SCR systems communicate with engine controls to predict NOx emissions based on signals such as torque and engine speed, however many marine engines in use still employ mechanical injection technology and lack electronic communication abilities. The system developed and discussed in this paper controls NOx emissions independentof engine operating parameters and measures NOx and exhaust flow using the following exhaust sensor inputs: absolute pressure, differential pressure, temperature, and NOx concentration. These sensor inputs were integrated into an independent controller and open loop architecture to estimate the necessary amount of urea needed, and the controller uses pulse width modulation (PWM) to power an automotive fuel injector for airless urea delivery. The system was tested in a transient test cell on a 350 hp engine certified at 4 g/bhp-hr of NOx, with a goal of reducing the engine out NOx levels by 50%. NOx reduction capabilities of 41-67% were shown on the non road transient cycle (NRTC) and ICOMIA E5 steady state cycles with system optimization during testing to minimize the dilute ammonia slip to cycle averages of 5-7 ppm. The goal of 50% reduction of NOx can be achieved dependent upon cycle. Further

  16. Analysis of Strategies for Multiple Emissions from Electric Power SO2, NOX, CO2, Mercury and RPS

    EIA Publications

    2001-01-01

    At the request of the Subcommittee, the Energy Information Administration prepared an initial report that focused on the impacts of reducing power sector NOx, SO2, and CO2 emissions. The current report extends the earlier analysis to add the impacts of reducing power sector mercury emissions and introducing renewable portfolio standard (RPS) requirements.

  17. Costs of mitigating CO2 emissions from passenger aircraft

    NASA Astrophysics Data System (ADS)

    Schäfer, Andreas W.; Evans, Antony D.; Reynolds, Tom G.; Dray, Lynnette

    2016-04-01

    In response to strong growth in air transportation CO2 emissions, governments and industry began to explore and implement mitigation measures and targets in the early 2000s. However, in the absence of rigorous analyses assessing the costs for mitigating CO2 emissions, these policies could be economically wasteful. Here we identify the cost-effectiveness of CO2 emission reductions from narrow-body aircraft, the workhorse of passenger air transportation. We find that in the US, a combination of fuel burn reduction strategies could reduce the 2012 level of life cycle CO2 emissions per passenger kilometre by around 2% per year to mid-century. These intensity reductions would occur at zero marginal costs for oil prices between US$50-100 per barrel. Even larger reductions are possible, but could impose extra costs and require the adoption of biomass-based synthetic fuels. The extent to which these intensity reductions will translate into absolute emissions reductions will depend on fleet growth.

  18. Exhaust particle and NOx emission performance of an SCR heavy duty truck operating in real-world conditions

    NASA Astrophysics Data System (ADS)

    Saari, Sampo; Karjalainen, Panu; Ntziachristos, Leonidas; Pirjola, Liisa; Matilainen, Pekka; Keskinen, Jorma; Rönkkö, Topi

    2016-02-01

    Particle and NOx emissions of an SCR equipped HDD truck were studied in real-world driving conditions using the "Sniffer" mobile laboratory. Real-time CO2 measurement enables emission factor calculation for NOx and particles. In this study, we compared three different emission factor calculation methods and characterised their suitability for real-world chasing experiments. The particle number emission was bimodal and dominated by the nucleation mode particles (diameter below 23 nm) having emission factor up to 1 × 1015 #/kgfuel whereas emission factor for soot (diameter above 23 nm that is consistent with the PMP standard) was typically 1 × 1014 #/kgfuel. The effect of thermodenuder on the exhaust particles indicated that the nucleation particles consisted mainly of volatile compounds, but sometimes there also existed a non-volatile core. The nucleation mode particles are not controlled by current regulations in Europe. However, these particles consistently form under atmospheric dilution in the plume of the truck and constitute a health risk for the human population that is exposed to those. Average NOx emission was 3.55 g/kWh during the test, whereas the Euro IV emission limit over transient testing is 3.5 g NOx/kWh. The on-road emission performance of the vehicle was very close to the expected levels, confirming the successful operation of the SCR system of the tested vehicle. Heavy driving conditions such as uphill driving increased both the NOx and particle number emission factors whereas the emission factor for soot particle number remains rather constant.

  19. Top-down estimate of surface flux in the Los Angeles Basin using a mesoscale inverse modeling technique: assessing anthropogenic emissions of CO, NOx and CO2 and their impacts

    NASA Astrophysics Data System (ADS)

    Brioude, J.; Angevine, W. M.; Ahmadov, R.; Kim, S.-W.; Evan, S.; McKeen, S. A.; Hsie, E.-Y.; Frost, G. J.; Neuman, J. A.; Pollack, I. B.; Peischl, J.; Ryerson, T. B.; Holloway, J.; Brown, S. S.; Nowak, J. B.; Roberts, J. M.; Wofsy, S. C.; Santoni, G. W.; Trainer, M.

    2012-12-01

    We present top-down estimates of anthropogenic CO, NOx and CO2 surface fluxes at mesoscale using a Lagrangian model in combination with three different WRF model configurations, driven by data from aircraft flights during the CALNEX campaign in southern California in May-June 2010. The US EPA National Emission Inventory 2005 (NEI 2005) was the prior in the CO and NOx inversion calculations. The flux ratio inversion method, based on linear relationships between chemical species, was used to calculate the CO2 inventory without prior knowledge of CO2 surface fluxes. The inversion was applied to each flight to estimate the variability of single-flight-based flux estimates. In Los Angeles (LA) County, the uncertainties on CO and NOx fluxes were 10% and 15%, respectively. Compared with NEI 2005, the CO posterior emissions were lower by 43% ± 6% in LA County and by 37% ± 10% in the South Coast Air Basin (SoCAB). NOx posterior emissions were lower by 32% ± 10% in LA County and by 27% ± 15% in the SoCAB. NOx posterior emissions were 40% lower on weekends relative to weekdays. The CO2 posterior estimates were 183 ± 18 Tg yr-1 in SoCAB. A flight during ITCT in 2002 was used to estimate emissions in the LA Basin in 2002. From 2002 to 2010, the CO and NOx posterior emissions decreased by 41% and 37%, respectively, in agreement with previous studies. Over the same time period, CO2 emissions increased by 10% ± 14% in LA County but decreased by 4% ± 10% in the SoCAB, a statistically insignificant change. Overall, the posterior estimates were in good agreement with the California Air Resources Board (CARB) inventory, with differences of 15% or less. However, the posterior spatial distribution in the basin was significantly different from CARB for NOx emissions. WRF-Chem mesoscale chemical-transport model simulations allowed an evaluation of differences in chemistry using different inventory assumptions, including NEI 2005, CARB 2010 and the posterior inventories derived in

  20. Top-down estimate of surface flux in the Los Angeles Basin using a mesoscale inverse modeling technique: assessing anthropogenic emissions of CO, NOx and CO2 and their impacts

    NASA Astrophysics Data System (ADS)

    Brioude, Jerome; Angevine, Wayne; Ahmadov, Ravan; Kim, Si Wan; Evan, Stephanie; McKeen, Stuart; Hsie, Eirh Yu; Frost, Greg; Neuman, Andy; Pollack, Ilana; Peischl, Jeff; Ryerson, Tom; Holloway, John; Brown, Steeve; Nowak, John; Roberts, Jim; Wofsy, Steeve; Santoni, Greg; Trainer, Michael

    2013-04-01

    We present top-down estimates of anthropogenic CO, NOx and CO2 surface fluxes at mesoscale using a Lagrangian model in combination with three different WRF model configurations, driven by data from aircraft flights during the CALNEX campaign in southern California in May-June 2010. The US EPA National Emission Inventory 2005 (NEI 2005) was the prior in the CO and NOx inversion calculations. The flux ratio inversion method, based on linear relationships between chemical species, was used to calculate the CO2 inventory without prior knowledge of CO2 surface fluxes. The inversion was applied to each flight to estimate the variability of single-flight-based flux estimates. In Los Angeles (LA) County, the uncertainties on CO and NOx fluxes were 10% and 15%, respectively. Compared with NEI 2005, the CO posterior emissions were lower by 43% ± 6% in LA County and by 37% ± 10% in the South Coast Air Basin (SoCAB). NOx posterior emissions were lower by 32% ± 10% in LA County and by 27% ± 15% in the SoCAB. NOx posterior emissions were 40% lower on weekends relative to weekdays. The CO2 posterior estimates were 183 ± 18 Tg yr-1 in SoCAB. A flight during ITCT in 2002 was used to estimate emissions in the LA Basin in 2002. From 2002 to 2010, the CO and NOx posterior emissions decreased by 41% and 37%, respectively, in agreement with previous studies. Over the same time period, CO2 emissions increased by 10% ± 14% in LA County but decreased by 4% ± 10% in the SoCAB, a statistically insignificant change. Overall, the posterior estimates were in good agreement with the California Air Resources Board (CARB) inventory, with differences of 15% or less. However, the posterior spatial distribution in the basin was significantly different from CARB for NOx emissions. WRF-Chem mesoscale chemical-transport model simulations allowed an evaluation of differences in chemistry using different inventory assumptions, including NEI 2005, CARB 2010 and the posterior inventories derived in

  1. Top-down estimate of surface flux in the Los Angeles Basin using a mesoscale inverse modeling technique: assessing anthropogenic emissions of CO, NOx and CO2 and their impacts

    NASA Astrophysics Data System (ADS)

    Brioude, J.; Angevine, W. M.; Ahmadov, R.; Kim, S.-W.; Evan, S.; McKeen, S. A.; Hsie, E.-Y.; Frost, G. J.; Neuman, J. A.; Pollack, I. B.; Peischl, J.; Ryerson, T. B.; Holloway, J.; Brown, S. S.; Nowak, J. B.; Roberts, J. M.; Wofsy, S. C.; Santoni, G. W.; Oda, T.; Trainer, M.

    2013-04-01

    We present top-down estimates of anthropogenic CO, NOx and CO2 surface fluxes at mesoscale using a Lagrangian model in combination with three different WRF model configurations, driven by data from aircraft flights during the CALNEX campaign in southern California in May-June 2010. The US EPA National Emission Inventory 2005 (NEI 2005) was the prior in the CO and NOx inversion calculations. The flux ratio inversion method, based on linear relationships between chemical species, was used to calculate the CO2 inventory without prior knowledge of CO2 surface fluxes. The inversion was applied to each flight to estimate the variability of single-flight-based flux estimates. In Los Angeles (LA) County, the uncertainties on CO and NOx fluxes were 10% and 15%, respectively. Compared with NEI 2005, the CO posterior emissions were lower by 43% in LA County and by 37% in the South Coast Air Basin (SoCAB). NOx posterior emissions were lower by 32% in LA County and by 27% in the SoCAB. NOx posterior emissions were 40% lower on weekends relative to weekdays. The CO2 posterior estimates were 183 Tg yr-1 in SoCAB. A flight during ITCT (Intercontinental Transport and Chemical Transformation) in 2002 was used to estimate emissions in the LA Basin in 2002. From 2002 to 2010, the CO and NOx posterior emissions decreased by 41% and 37%, respectively, in agreement with previous studies. Over the same time period, CO2 emissions increased by 10% in LA County but decreased by 4% in the SoCAB, a statistically insignificant change. Overall, the posterior estimates were in good agreement with the California Air Resources Board (CARB) inventory, with differences of 15% or less. However, the posterior spatial distribution in the basin was significantly different from CARB for NOx emissions. WRF-Chem mesoscale chemical-transport model simulations allowed an evaluation of differences in chemistry using different inventory assumptions, including NEI 2005, a gridded CARB inventory and the posterior

  2. Aircraft measurements of SO2, NOx, CO, and O3 over the coastal and offshore area of Yellow Sea of China.

    PubMed

    Yang, Xiaoyang; Wang, Xinhua; Yang, Wen; Xu, Jun; Ren, Lihong; He, Youjiang; Liu, Bing; Bai, Zhipeng; Meng, Fan; Hu, Min

    2016-09-01

    In order to investigate long-range transport of the air pollution in the East Asia, air pollutants, including SO2, NOx, CO, and O3, were observed by aircraft measurement over the coastal and offshore area of Yellow Sea of China in April 2011. NOx and SO2 seemed to become moderate in recent years, and the concentrations during the whole observations ranged from 0.49 to 9.57 ppb and from 0.10 to 16.02 ppb, respectively. The high concentrations of CO were measured with an average value of 0.98 ppm. The measured O3 average concentration was 76.25 ppb, which showed a higher level comparing with the results from some previous studies. Most of the results for the concentration values generally followed the typical characteristic of vertical and spatial distribution, which were "low altitude > high altitude" and "land/coastal > sea," respectively. Transport of polluted air mass from the continent to the aircraft measurement area was confirmed in some days during the observation by the meteorological analysis, while the measurement results supposed to represent the background level of the pollutants in rest days. Additionally, some small-scale air pollution plumes were observed. Significant positive correlations between NOx and SO2 indicated that these two species originated from the same region. On the other hand, good positive correlations between NOx and O3 found during 2-day flight suggested that the O3 formation was probably under "NOx-limited" regime in these days.

  3. Aircraft measurements of SO2, NOx, CO, and O3 over the coastal and offshore area of Yellow Sea of China.

    PubMed

    Yang, Xiaoyang; Wang, Xinhua; Yang, Wen; Xu, Jun; Ren, Lihong; He, Youjiang; Liu, Bing; Bai, Zhipeng; Meng, Fan; Hu, Min

    2016-09-01

    In order to investigate long-range transport of the air pollution in the East Asia, air pollutants, including SO2, NOx, CO, and O3, were observed by aircraft measurement over the coastal and offshore area of Yellow Sea of China in April 2011. NOx and SO2 seemed to become moderate in recent years, and the concentrations during the whole observations ranged from 0.49 to 9.57 ppb and from 0.10 to 16.02 ppb, respectively. The high concentrations of CO were measured with an average value of 0.98 ppm. The measured O3 average concentration was 76.25 ppb, which showed a higher level comparing with the results from some previous studies. Most of the results for the concentration values generally followed the typical characteristic of vertical and spatial distribution, which were "low altitude > high altitude" and "land/coastal > sea," respectively. Transport of polluted air mass from the continent to the aircraft measurement area was confirmed in some days during the observation by the meteorological analysis, while the measurement results supposed to represent the background level of the pollutants in rest days. Additionally, some small-scale air pollution plumes were observed. Significant positive correlations between NOx and SO2 indicated that these two species originated from the same region. On the other hand, good positive correlations between NOx and O3 found during 2-day flight suggested that the O3 formation was probably under "NOx-limited" regime in these days. PMID:27544762

  4. Control of diesel soot and NOx emissions with a particulate trap and EGR.

    PubMed

    Liu, Rui-xiang; Gao, Xi-yan; Yang, De-sheng; Xu, Xiao-guang

    2005-01-01

    The exhaust gas recirculation (EGR), coupled with a high-collection efficiency particulate trap to simultaneously control smoke and NOx emissions from diesel engines were studied. This ceramic trap developed previously provided the soot cleaning efficiency of 99%, the regeneration efficiency reaches 80% and the ratio of success reaches 97%, which make EGR used in diesel possible. At the presence of EGR, opening of the regeneration control valve of the trap was over again optimized to compensate for the decrease of the oxygen concentration in the exhaust gas resulted from EGR. The results indicated the cleaning efficiency and regeneration performance of the trap were maintained at the same level except that the back pressure increased faster. A new EGR system was developed, which is based on a wide range oxygen (UEGO) sensor. Experiments were carried out under steady state conditions while maintaining the engine speed at 1600 r/min, setting the engine loads at 0%, 25%, 50%, 75% and 100% respectively. Throughout each test the EGR rate was kept at nine different settings and data were taken with the gas analyzer and UEGO sensor. Then, the EGR rate and engine load maps, which showed the tendencies of NOx, CO and HC emissions from diesel engine, were made using the measured data. Using the maps, the author set up the EGR regulation, the relationship between the optimal amounts of EGR flow and the equivalence ratio, sigma, where sigma = 14.5/AFR.

  5. Fluidized combustion of coal. [to limit SO2 and NOx emissions

    NASA Technical Reports Server (NTRS)

    Pope, M.

    1978-01-01

    A combustion technology that permits the burning of low quality coal, and other fuels, while maintaining stack emissions within State and Federal EPA limits is discussed. Low quality fuels can be burned directly in fluidized beds while taking advantage of low furnace temperatures and chemical activity within the bed to limit SO2 and NOx emissions. The excellent heat transfer characteristics of the fluidized beds also result in a reduction of total heat transfer surface requirements. Tests on beds operating at pressures of one to ten atmospheres, at temperatures as high as 1600 F, and with gas velocities in the vicinity of four to twelve feet per second, have proven the concept. The progress that has been made in the development of fluidized bed combustion technology and work currently underway are discussed.

  6. [Aviation fuels and aircraft emissions. A risk characterization for airport neighbors using Hamburg Airport as an example].

    PubMed

    Tesseraux, I; Mach, B; Koss, G

    1998-06-01

    Aviation fuels are well characterised regarding their physical and chemical properties. Health effects of fuel vapours and of liquid fuel are described after occupational exposure and in animal studies. Exposure of the general population (airport visitors and people living in the vicinity of airports) may occur during fuel supply particularly in warm summers (odour). Aircraft emissions vary with the engine type and the kind of fuel. Combustion of aviation fuel results in CO2, H2O, CO, C, NOx and a great number of organic compounds. Among the emitted polyaromatic hydrocarbons (PAH) no compound characteristic for jet engines (tracer) could be detected so far. Hardly any data exist on the toxicology of jet engine emissions. According to analyses of their chemical composition, however, they contain various toxicologically relevant compounds including carcinogenic substances. Measurements in ambient air around the Hamburg Airport show no elevated pollutant levels. However, no such data exist on aldehydes, black smoke or fine particles. Annoying odours have been stated in some areas around the airport, which were mainly attributed to the aircraft engine emissions rather than to fuel vapours.

  7. [Aviation fuels and aircraft emissions. A risk characterization for airport neighbors using Hamburg Airport as an example].

    PubMed

    Tesseraux, I; Mach, B; Koss, G

    1998-06-01

    Aviation fuels are well characterised regarding their physical and chemical properties. Health effects of fuel vapours and of liquid fuel are described after occupational exposure and in animal studies. Exposure of the general population (airport visitors and people living in the vicinity of airports) may occur during fuel supply particularly in warm summers (odour). Aircraft emissions vary with the engine type and the kind of fuel. Combustion of aviation fuel results in CO2, H2O, CO, C, NOx and a great number of organic compounds. Among the emitted polyaromatic hydrocarbons (PAH) no compound characteristic for jet engines (tracer) could be detected so far. Hardly any data exist on the toxicology of jet engine emissions. According to analyses of their chemical composition, however, they contain various toxicologically relevant compounds including carcinogenic substances. Measurements in ambient air around the Hamburg Airport show no elevated pollutant levels. However, no such data exist on aldehydes, black smoke or fine particles. Annoying odours have been stated in some areas around the airport, which were mainly attributed to the aircraft engine emissions rather than to fuel vapours. PMID:9686444

  8. Overall evaluation of combustion and NO(x) emissions for a down-fired 600 MW(e) supercritical boiler with multiple injection and multiple staging.

    PubMed

    Kuang, Min; Li, Zhengqi; Liu, Chunlong; Zhu, Qunyi

    2013-05-01

    To achieve significant reductions in NOx emissions and to eliminate strongly asymmetric combustion found in down-fired boilers, a deep-air-staging combustion technology was trialed in a down-fired 600 MWe supercritical utility boiler. By performing industrial-sized measurements taken of gas temperatures and species concentrations in the near wing-wall region, carbon in fly ash and NOx emissions at various settings, effects of overfire air (OFA) and staged-air damper openings on combustion characteristics, and NOx emissions within the furnace were experimentally determined. With increasing the OFA damper opening, both fluctuations in NOx emissions and carbon in fly ash were initially slightly over OFA damper openings of 0-40% but then lengthened dramatically in openings of 40-70% (i.e., NOx emissions reduced sharply accompanied by an apparent increase in carbon in fly ash). Decreasing the staged-air declination angle clearly increased the combustible loss but slightly influenced NOx emissions. In comparison with OFA, the staged-air influence on combustion and NOx emissions was clearly weaker. Only at a high OFA damper opening of 50%, the staged-air effect was relatively clear, i.e., enlarging the staged-air damper opening decreased carbon in fly ash and slightly raised NOx emissions. By sharply opening the OFA damper to deepen the air-staging conditions, although NOx emissions could finally reduce to 503 mg/m(3) at 6% O2 (i.e., an ultralow NOx level for down-fired furnaces), carbon in fly ash jumped sharply to 15.10%. For economical and environment-friendly boiler operations, an optimal damper opening combination (i.e., 60%, 50%, and 50% for secondary air, staged-air, and OFA damper openings, respectively) was recommended for the furnace, at which carbon in fly ash and NOx emissions attained levels of about 10% and 850 mg/m(3) at 6% O2, respectively.

  9. RFID Transponders' RF Emissions in Aircraft Communication and Navigation Radio Bands

    NASA Technical Reports Server (NTRS)

    Nguyen, Truong X.; Ely, Jay J.; Koppen Sandra V.; Fersch, Mariatheresa S.

    2008-01-01

    Radiated emission data in aircraft communication and navigation bands are presented for several active radio frequency identification (RFID) tags. The individual tags are different in design, operation and transmitting frequencies. The process for measuring the tags emissions in a reverberation chamber is discussed. Measurement issues dealing with tag interrogation, low level measurement in the presence of strong transmissions, and tags low duty factors are discussed. The results show strong emissions, far exceeding aircraft emission limits and can be of potential interference risks.

  10. Impact of aircraft NO x emission on NO x and ozone over China

    NASA Astrophysics Data System (ADS)

    Liu, Yu; Isaksen, I. S. A.; Sundet, J. K.; Zhou, Xiuji; Ma, Jianzhong

    2003-07-01

    A three-dimensional global chemistry transport model (OSLO CTM2) is used to investigate the impact of subsonic aircraft NO x emission on NO x and ozone over China in terms of a year 2000 scenario of subsonic aircraft NO x emission. The results show that subsonic aircraft NO x emission significantly affects northern China, which makes NO x at 250 hPa increase by about 50 pptv with the highest percentage of 60% in January, and leading to an ozone increase of 8 ppbv with 5% relative change in April. The NO x increase is mainly attributed to the transport process, but ozone increase is produced by the chemical process. The NO x increases by less than 10 pptv by virtue of subsonic aircraft NO x emission over China, and ozone changes less than 0.4 ppbv. When subsonic aircraft NO x emission over China is doubled, its influence is still relatively small.

  11. Characterization of lubrication oil emissions from aircraft engines.

    PubMed

    Yu, Zhenhong; Liscinsky, David S; Winstead, Edward L; True, Bruce S; Timko, Michael T; Bhargava, Anuj; Herndon, Scott C; Miake-Lye, Richard C; Anderson, Bruce E

    2010-12-15

    In this first ever study, particulate matter (PM) emitted from the lubrication system overboard breather vent for two different models of aircraft engines has been systematically characterized. Lubrication oil was confirmed as the predominant component of the emitted particulate matter based upon the characteristic mass spectrum of the pure oil. Total particulate mass and size distributions of the emitted oil are also investigated by several high-sensitivity aerosol characterization instruments. The emission index (EI) of lubrication oil at engine idle is in the range of 2-12 mg kg(-1) and increases with engine power. The chemical composition of the oil droplets is essentially independent of engine thrust, suggesting that engine oil does not undergo thermally driven chemical transformations during the ∼4 h test window. Volumetric mean diameter is around 250-350 nm for all engine power conditions with a slight power dependence.

  12. 40 CFR Appendix E to Part 75 - Optional NOX Emissions Estimation Protocol for Gas-Fired Peaking Units and Oil-Fired Peaking Units

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 17 2014-07-01 2014-07-01 false Optional NOX Emissions Estimation... MONITORING Pt. 75, App. E Appendix E to Part 75—Optional NOX Emissions Estimation Protocol for Gas-Fired Peaking Units and Oil-Fired Peaking Units 1. Applicability 1.1 Unit Operation Requirements This...

  13. 40 CFR 60.4325 - What emission limits must I meet for NOX if my turbine burns both natural gas and distillate oil...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... NOX if my turbine burns both natural gas and distillate oil (or some other combination of fuels)? 60... Combustion Turbines Emission Limits § 60.4325 What emission limits must I meet for NOX if my turbine burns... burning that fuel. Similarly, when your total heat input is greater than 50 percent distillate oil...

  14. Modeling the Effects of VOC and NOx Emission Sources on Ozone Formation in Houston during the TexAQS 2000 Field Campaign

    SciTech Connect

    Jiang, Guangfeng; Fast, Jerome D.

    2004-09-01

    A meteorological and chemical modeling system is used to determine the effect of ethene and propene point source emission rates on the magnitude and distribution of ozone in the vicinity of Houston. The model performance is evaluated using surface and airborne meteorological and chemical measurements made as part of the 2000 Texas Air Quality Study. A simulation that employed the reported mobile, area, biogenic, and point source emissions produced ozone mixing ratios as high as 120 ppb and distributions of nitrogen oxides that were similar to measurements at most locations, but the model underestimated ozone mixing ratios greater than 140 ppb that were located just downwind of petrochemical facilities. When the point source emission rates of ethene and propene were increased by a factor of 10, the simulated peak ozone levels were in better agreement with surface, aircraft, and lidar observations. The magnitude of the simulated ethene and olefin concentrations were in better agreement with canister samples aloft as well; however, there was still a large amount of scatter in the results. While the highest ozone mixing ratios were produced just downwind of large point source emissions of VOCs, sensitivity simulations also showed that reductions in anthropogenic emissions of NOx would be needed to reduce ozone mixing ratios over a larger area.

  15. A Comprehensive Program for Measurement of Military Aircraft Emissions

    SciTech Connect

    Cheng, Mengdawn

    2009-11-01

    Emissions of gases and particulate matter by military aircraft were characterized inplume by 'extractive' and 'optical remote-sensing (ORS)' technologies. Non-volatile particle size distribution, number and mass concentrations were measured with good precision and reproducibly. Time-integrated particulate filter samples were collected and analyzed for smoke number, elemental composition, carbon contents, and sulfate. Observed at EEP the geometric mean diameter (as measured by the mobility diameter) generally increased as the engine power setting increased, which is consistent with downstream observations. The modal diameters at the downstream locations are larger than that at EEP at the same engine power level. The results indicate that engine particles were processed by condensation, for example, leading to particle growth in-plume. Elemental analysis indicated little metals were present in the exhaust, while most of the exhaust materials in the particulate phase were carbon and sulfate (in the JP-8 fuel). CO, CO{sub 2}, NO, NO{sub 2}, SO{sub 2}, HCHO, ethylene, acetylene, propylene, and alkanes were measured. The last five species were most noticeable under engine idle condition. The levels of hydrocarbons emitted at high engine power level were generally below the detection limits. ORS techniques yielded real-time gaseous measurement, but the same techniques could not be extended directly to ultrafine particles found in all engine exhausts. The results validated sampling methodology and measurement techniques used for non-volatile particulate aircraft emissions, which also highlighted the needs for further research on sampling and measurement for volatile particulate matter and semi-volatile species in the engine exhaust especially at the low engine power setting.

  16. Gas Emissions Acquired during the Aircraft Particle Emission Experiment (APEX) Series

    NASA Technical Reports Server (NTRS)

    Changlie, Wey; Chowen, Chou Wey

    2007-01-01

    NASA, in collaboration with other US federal agencies, engine/airframe manufacturers, airlines, and airport authorities, recently sponsored a series of 3 ground-based field investigations to examine the particle and gas emissions from a variety of in-use commercial aircraft. Emissions parameters were measured at multiple engine power settings, ranging from idle to maximum thrust, in samples collected at 3 different down stream locations of the exhaust. Sampling rakes at nominally 1 meter down stream contained multiple probes to facilitate a study of the spatial variation of emissions across the engine exhaust plane. Emission indices measured at 1 m were in good agreement with the engine certification data as well as predictions provided by the engine company. However at low power settings, trace species emissions were observed to be highly dependent on ambient conditions and engine temperature.

  17. Modeling the effects of VOC/NOx emissions on ozone synthesis in the cascadia airshed of the Pacific Northwest.

    PubMed

    Barna, M; Lamb, B; Westberg, H

    2001-07-01

    A modeling system consisting of MM5, Calmet, and Calgrid was used to investigate the sensitivity of anthropogenic volatile organic compound (VOC) and oxides of nitrogen (NOx) reductions on ozone formation within the Cascadia airshed of the Pacific Northwest. An ozone episode that occurred on July 11-14, 1996, was evaluated. During this event, high ozone levels were recorded at monitors downwind of Seattle, WA, and Portland, OR, with one monitor exceeding the 1 hr/120 ppb National Ambient Air Quality Standard (at 148 ppb), and six monitors above the proposed 8 hr/80 ppb standard (at 82-130 ppb). For this particular case, significant emissions reductions, between 25 and 75%, would be required to decrease peak ozone concentrations to desired levels. Reductions in VOC emissions alone, or a combination of reduced VOC and NOx emissions, were generally found to be most effective; reducing NOx emissions alone resulted in increased ozone in the Seattle area. When only VOC emissions were curtailed, ozone reductions occurred in the immediate vicinity of densely populated areas, while NOx reductions resulted in more widespread ozone reductions. PMID:15658221

  18. Measurements of real-world vehicle CO and NOx fleet average emissions in urban tunnels of two cities in China

    NASA Astrophysics Data System (ADS)

    Deng, Yiwen; Chen, Chao; Li, Qiong; Hu, Qinqiang; Yuan, Haoting; Li, Junmei; Li, Yan

    2015-12-01

    Urban tunnels located in the city center areas, can alleviate traffic pressure and provide more convenient traffic for people. Vehicles emit pollutants that are significant contributors to air pollution inside and at the outlet of tunnels. Ventilation is the most widely used method to dilute pollutants in tunnels. To calculate the design required air volume flow accurately, vehicle emissions should be exactly determined. Emission factors are important parameters to estimate vehicle emissions. To characterize carbon monoxide (CO) and nitrogen oxides (NOX) emission factors for a mixed vehicle fleet under real-world driving conditions of urban China, we measured CO and NOX concentrations in Shanghai East Yan'an Road tunnel and Changsha Yingpan Road tunnel in 2012 and 2013. In-use fleet average CO and NOX emission factors were calculated according to tunnel pollutants mass balance models. The results showed that the maximum CO concentration in August was 86 ppm, while in October it was 45 ppm in Shanghai East Yan'an Road tunnel. The maximum concentrations of CO and NOX were 33 ppm and 2 ppm in Changsha Yingpan Road tunnel, respectively. In-use fleet average CO emission factors of East Yan'an Road tunnel, with gradient of -3% ∼ 3%, were 1.266 (±0.889) ∼ 3.974 (±2.189) g km-1 vehicle-1. In-use fleet average CO and NOX emission factors of Yingpan Road tunnel with gradient of -6% ∼ 6% amounted to 0.754 (±0.561) ∼ 6.050 (±5.940) g km-1 vehicle-1 and 0.121 (±0.022) ∼ 0.818 (±0.755) g km-1 vehicle-1, respectively. The dependences of CO and NOX emission on roadway gradient and vehicle speed were found. The average CO and NOX emission factors increased with the ascending of roadway gradient as well as reverse with vehicle speed. These findings provide meaningful reference for ventilation design and environmental assessment of urban tunnels, and further help provide basic data to formulate relevant standards and norms.

  19. Method for control of NOx emission from combustors using fuel dilution

    SciTech Connect

    Schefer, Robert W.; Keller, Jay O

    2007-01-16

    A method of controlling NOx emission from combustors. The method involves the controlled addition of a diluent such as nitrogen or water vapor, to a base fuel to reduce the flame temperature, thereby reducing NOx production. At the same time, a gas capable of enhancing flame stability and improving low temperature combustion characteristics, such as hydrogen, is added to the fuel mixture. The base fuel can be natural gas for use in industrial and power generation gas turbines and other burners. However, the method described herein is equally applicable to other common fuels such as coal gas, biomass-derived fuels and other common hydrocarbon fuels. The unique combustion characteristics associated with the use of hydrogen, particularly faster flame speed, higher reaction rates, and increased resistance to fluid-mechanical strain, alter the burner combustion characteristics sufficiently to allow operation at the desired lower temperature conditions resulting from diluent addition, without the onset of unstable combustion that can arise at lower combustor operating temperatures.

  20. Aircraft measurements of ozone, NOx, CO, and aerosol concentrations in biomass burning smoke over Indonesia and Australia in October 1997: Depleted ozone layer at low altitude over Indonesia

    NASA Astrophysics Data System (ADS)

    Tsutsumi, Yukitomo; Sawa, Yousuke; Makino, Yukio; Jensen, Jørgen B.; Gras, John L.; Ryan, Brian F.; Diharto, Sri; Harjanto, Hery

    The 1997 El Niño unfolded as one of the most sever El Niño Southern Oscillation (ENSO) events in this century and it coincided with massive biomass burning in the equatorial western Pacific region. To assess the influence on the atmosphere, aircraft observations of trace gases and aerosol were conducted over Kalimantan in Indonesia and Australia. Over Kalimantan in Indonesia, high concentrations of O3, NOx, CO, and aerosols were observed during the flight. Although the aerosol and NOx decreased with altitude, the O3 had the maximum concentration (80.5 ppbv) in the middle layer of the smoke haze and recorded very low concentrations (˜20 ppbv) in the lower smoke layer. This feature was not observed in the Australian smoke. We proposed several hypotheses for the low O3 concentration at low levels over Kalimantan. The most likely are lack of solar radiation and losses at the surface of aerosol particles.

  1. Extrapolating Ground-Based Aircraft Engine Exhaust Emissions to Cruise Conditions: Lessons From the 2013 ACCESS Chase Plane Experiment

    NASA Astrophysics Data System (ADS)

    Moore, R.; Shook, M.; Thornhill, K. L.; Winstead, E.; Anderson, B. E.

    2011-12-01

    Aircraft engine emissions constitute a tiny fraction of the global black carbon mass, but can have a disproportionate climatic impact because they are emitted high in the troposphere and in remote regions with otherwise low aerosol concentrations. Consequently, these particles are likely to strongly influence cirrus and contrail formation by acting as ice nuclei (IN). However, the ice nucleating properties of aircraft exhaust at relevant atmospheric conditions are not well known, and thus, the overall impact of aviation on cloud formation remains very uncertain. While a number of aircraft engine emissions studies have previously been conducted at sea level temperature and pressure (e.g., APEX, AAFEX-1 and 2), it unclear the extent to which exhaust emissions on the ground translate to emissions at cruise conditions with much lower inlet gas temperatures and pressures. To address this need, the NASA Alternative Fuel Effects on Contrails and Cruise Emissions (ACCESS) was conducted in February-April, 2013 to examine the aerosol and gas emissions from the NASA DC-8 under a variety of different fuel types, engine power, and altitude/meteorological conditions. Two different fuel types were studied: a traditional JP-8 fuel and a 50:50 blend of JP-8 and a camelina-based hydro-treated renewable jet (HRJ) fuel. Emissions were sampled using a comprehensive suite of gas- and aerosol-phase instrumentation integrated on an HU-25 Falcon jet that was positioned in the DC-8 exhaust plume at approximately 100-500m distance behind the engines. In addition, a four-hour ground test was carried out with sample probes positioned at 30 m behind each of the inboard engines. Measurements of aerosol concentration, size distribution, soot mass, and hygroscopicity were carried out along with trace gas measurements of CO2, NO, NO2, O3, and water vapor. NOx emissions were reconciled by employing the well-established Boeing method for normalizing engine fuel flow rates to STP; however, comparison

  2. Extrapolating Ground-Based Aircraft Engine Exhaust Emissions to Cruise Conditions: Lessons From the 2013 ACCESS Chase Plane Experiment

    NASA Astrophysics Data System (ADS)

    Moore, R.; Shook, M.; Thornhill, K. L.; Winstead, E.; Anderson, B. E.

    2013-12-01

    Aircraft engine emissions constitute a tiny fraction of the global black carbon mass, but can have a disproportionate climatic impact because they are emitted high in the troposphere and in remote regions with otherwise low aerosol concentrations. Consequently, these particles are likely to strongly influence cirrus and contrail formation by acting as ice nuclei (IN). However, the ice nucleating properties of aircraft exhaust at relevant atmospheric conditions are not well known, and thus, the overall impact of aviation on cloud formation remains very uncertain. While a number of aircraft engine emissions studies have previously been conducted at sea level temperature and pressure (e.g., APEX, AAFEX-1 and 2), it unclear the extent to which exhaust emissions on the ground translate to emissions at cruise conditions with much lower inlet gas temperatures and pressures. To address this need, the NASA Alternative Fuel Effects on Contrails and Cruise Emissions (ACCESS) was conducted in February-April, 2013 to examine the aerosol and gas emissions from the NASA DC-8 under a variety of different fuel types, engine power, and altitude/meteorological conditions. Two different fuel types were studied: a traditional JP-8 fuel and a 50:50 blend of JP-8 and a camelina-based hydro-treated renewable jet (HRJ) fuel. Emissions were sampled using a comprehensive suite of gas- and aerosol-phase instrumentation integrated on an HU-25 Falcon jet that was positioned in the DC-8 exhaust plume at approximately 100-500m distance behind the engines. In addition, a four-hour ground test was carried out with sample probes positioned at 30 m behind each of the inboard engines. Measurements of aerosol concentration, size distribution, soot mass, and hygroscopicity were carried out along with trace gas measurements of CO2, NO, NO2, O3, and water vapor. NOx emissions were reconciled by employing the well-established Boeing method for normalizing engine fuel flow rates to STP; however, comparison

  3. Spatial representation of a current NOx emission inventory over China: A satellite perspective

    NASA Astrophysics Data System (ADS)

    Geng, G.; Zhang, Q.; Wang, S.; He, K.; Martin, R. V.; Lamsal, L. N.; Zheng, B.

    2012-12-01

    The top-down approach provides valuable constraints to bottom-up emission inventories. In this work, we evaluated the spatial representation of a current NOx emission inventory over China using NO2 retrievals from the Ozone Monitoring Instrument (OMI) and the nested-grid GEOS-Chem model. Comparison between model simulations and satellite observations showed that modeled NO2 columns were underestimated in most medium-sized cities, while good agreement was found in megacities such as Beijing, Shanghai. Large discrepancies between model simulations and satellite retrievals were found in grids with high Gross domestic product (GDP) value across different regions of China. We also found that the growth rates of NO2 columns have slowed in Chinese megacities over recent years, in contrast with medium-sized cities where the NO2 columns were soaring. Sensitivity simulations using emissions allocated by different spatial surrogates (e.g. population density, location, nighttime light, industrial GDP, road networks) indicated that the uncertainties in spatial representation of the current emission inventory might be caused by inappropriate spatial proxies.

  4. Impact of aircraft emissions on air quality in the vicinity of airports. Volume II. An updated model assessment of aircraft generated air pollution at LAX, JFK, and ORD. Final report Jan 1978-Jul 1980

    SciTech Connect

    Yamartino, R.J.; Smith, D.G.; Bremer, S.A.; Heinold, D.; Lamich, D.

    1980-07-01

    This report documents the results of the Federal Aviation Administration (FAA)/Environmental Protection Agency (EPA) air quality study which has been conducted to assess the impact of aircraft emissions of carbon monoxide (CO), hydrocarbons (HC), and oxides of nitrogen (NOx) in the vicinity of airports. This assessment includes the results of recent modeling and monitoring efforts at Washington National (DCA), Los Angeles International (LAX), Dulles International (IAD), and Lakeland, Florida airports and an updated modeling of aircraft generated pollution at LAX, John F. Kennedy (JFK) and Chicago O'Hare (ORD) airports. The Airport Vicinity Air Pollution (AVAP) model which was designed for use at civil airports was used in this assessment. In addition the results of the application of the military version of the AVAP model the Air Quality Assessment Model (AQAM), are summarized. Both the results of the pollution monitoring analyses in Volume I and the modeling studies in Volume II suggest that: maximum hourly average CO concentrations from aircraft are unlikely to exceed 5 parts per million (ppm) in areas of public exposure and are thus small in comparison to the National Ambient Air Quality Standard of 35 ppm; maximum hourly HC concentrations from aircraft can exceed 0.25 ppm over an area several times the size of the airport; and annual average NO2 concentrations from aircraft are estimated to contribute only 10 to 20 percent of the NAAQS limit level.

  5. Effect of air temperature and relative humidity at various fuel-air ratios on exhaust emissions on a per-mode basis of an Avco Lycoming 0-320 DIAD light aircraft engine. Volume 2: Individual data points

    NASA Technical Reports Server (NTRS)

    Skorobatckyi, M.; Cosgrove, D. V.; Meng, P. R.; Kempke, E. R.

    1976-01-01

    A carbureted four cylinder air cooled 0-320 DIAD Lycoming aircraft engine was tested to establish the effects of air temperature and humidity at various fuel-air ratios on the exhaust emissions on a per-mode basis. The test conditions included carburetor lean-out at air temperatures of 50, 59, 80, and 100 F at relative humidities of 0, 30, 60, and 80 percent. Temperature-humidity effects at the higher values of air temperature and relative humidity tested indicated that the HC and CO emissions increased significantly, while the NOx emissions decreased. Even at a fixed fuel-air ratio, the HC emissions increase and the NOx emissions decrease at the higher values of air temperature and humidity. Volume II contains the data taken at each of the individual test points.

  6. Effect of Air Temperature and Relative Humidity at Various Fuel-Air Ratios on Exhaust Emissions on a Per-Mode Basis of an AVCO Lycoming 0-320 Diad Light Aircraft Engine: Volume 1: Results and Plotted Data

    NASA Technical Reports Server (NTRS)

    Skorobatckyi, M.; Cosgrove, D. V.; Meng, P. R.; Kempe, E. E., Jr.

    1978-01-01

    A carbureted four cylinder air cooled 0-320 DIAD Lycoming aircraft engine was tested to establish the effects of air temperature and humidity at various fuel-air ratios on the exhaust emissions on a per-mode basis. The test conditions include carburetor lean out at air temperatures of 50, 59, 80, and 100 F at relative humidities of 0, 30, 60, and 80 percent. Temperature humidity effects at the higher values of air temperature and relative humidity tested indicated that the HC and CO emissions increased significantly, while the NOx emissions decreased. Even at a fixed fuel air ratio, the HC emissions increase and the NOx emissions decrease at the higher values of air temperature and humidity.

  7. Shifting primary energy source and NOx emission location with plug-in hybrid vehicles

    NASA Astrophysics Data System (ADS)

    Karman, Deniz

    2011-06-01

    Plug-in hybrid vehicles (PHEVs) present an interesting technological opportunity for using non-fossil primary energy in light duty passenger vehicles, with the associated potential for reducing air pollutant and greenhouse gas emissions, to the extent that the electric power grid is fed by non-fossil sources. This perspective, accompanying the article by Thompson et al (2011) in this issue, will touch on two other studies that are directly related: the Argonne study (Elgowainy et al 2010) and a PhD thesis from Utrecht (van Vliet 2010). Thompson et al (2011) have examined air quality effects in a case where the grid is predominantly fossil fed. They estimate a reduction of 7.42 tons/day of NOx from motor vehicles as a result of substituting electric VMTs for 20% of the light duty gasoline vehicle miles traveled. To estimate the impact of this reduction on air quality they also consider the increases in NOx emissions due to the increased load on electricity generating units. The NOx emission increases are estimated as 4.0, 5.5 and 6.3 tons for the Convenience, Battery and Night charging scenarios respectively. The net reductions are thus in the 1.1-3.4 tons/day range. The air quality modelling results presented show that the air quality impact from a ground-level ozone perspective is favorable overall, and while the effect is stronger in some localities, the difference between the three scenarios is small. This is quite significant and suggests that localization of the NOx emissions to point sources has a more pronounced effect than the absolute reductions achieved. Furthermore it demonstrates that localization of NOx emissions to electricity generating units by using PHEVs in vehicle traffic has beneficial effects for air quality not only by minimizing direct human exposure to motor vehicle emissions, but also due to reduced exposure to secondary pollutants (i.e. ozone). In an electric power grid with a smaller share of fossil fired generating units, the beneficial

  8. Intake fraction of PM2.5 and NOX from vehicle emissions in Beijing based on personal exposure data

    NASA Astrophysics Data System (ADS)

    Du, Xuan; Wu, Ye; Fu, Lixin; Wang, Shuxiao; Zhang, Shaojun; Hao, Jiming

    2012-09-01

    The intake fraction (iF) is the portion of attributable population intake of a source emissions, and is used to link pollutant emissions and population exposure. This study is the first work that reported individual intake fraction of PM2.5 and NOX from vehicle emissions based on personal exposure data in China. We employed PM2.5 and NOX measurement data from 24-h personal exposure sampling and concentration monitoring in traffic environments in the urban area of Beijing to estimate the individual intake fraction (iFi). iFi distributions are presented in microenvironments (traffic, work, home) for adults and children. The individual results are used to calculate the intake fraction for the children group and the adults group in the urban area of Beijing. The iF of PM2.5 for the whole population of these two groups in Beijing is 153 per million, which is significantly higher than those estimates in the United States (1-50 per million) and Mexico (23-120 per million). The iF of NOX is 70 per million, among which the intake in the traffic micro-environment ranks first compared to the iF in the home and office due to a high accumulation of NOX concentration in vehicles. PM2.5 and NOX intake fraction values from vehicle emissions in this study are from at least several times to one order of magnitude higher than those from other industry sources in China. This strongly suggests the health risk from vehicle emissions is significantly higher. Therefore, to protect human health, especially for the large number of people living in the cities of China, controlling vehicle emissions should be the highest priority.

  9. 40 CFR 86.1861-17 - How do the NMOG+NOX and evaporative emission credit programs work?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ...) in model year 2017. (c) The credit-deficit provisions 40 CFR 1037.745 apply to the NMOG+NOX and... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES General Compliance Provisions for Control of Air Pollution From New and In-Use...

  10. 40 CFR 75.72 - Determination of NOX mass emissions for common stack and multiple stack configurations.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... lbs) by multiplying the hourly NOX emission rate (in lbs/mmBtu) by the hourly heat input rate (in mm... determining the hourly unit heat input rates, either: (i) Apportion the common stack heat input rate to the... this part, (A) Use the procedures in appendix D to this part to determine heat input rate for that...

  11. Performance of High Temperature Air Combustion Boiler with Low NOx Emission

    NASA Astrophysics Data System (ADS)

    Kobayashi, Hiromichi; Ito, Yoshihito; Tsuruta, Naoki; Yoshikawa, Kunio

    Thermal performance in the experiments and three-dimensional numerical simulations for a high temperature air combustion boiler where fuel can be efficiently combusted by high temperature preheated air (800°C-1000°C) is examined. The boiler can burn not only natural gas but also low calorific gas (e. g. full gasification gas obtained from coal or wastes). In the boiler, four regenerative burners are installed. This boiler has new features that not only air but also gasification gas is heated up to 900°C, and combination of burners is switched every 15 seconds where two burners are used as inlets of fuel and air and the other two burners are used as outlets of exhaust gas. Natural gas and syngas obtained from coal are burned. The NOx emission for each fuel is less than 50ppm. The heat transfer of three-dimensional calculation is predicted higher than that of experiment.

  12. Vortex combustor for low NOX emissions when burning lean premixed high hydrogen content fuel

    DOEpatents

    Steele, Robert C; Edmonds, Ryan G; Williams, Joseph T; Baldwin, Stephen P

    2012-11-20

    A trapped vortex combustor. The trapped vortex combustor is configured for receiving a lean premixed gaseous fuel and oxidant stream, where the fuel includes hydrogen gas. The trapped vortex combustor is configured to receive the lean premixed fuel and oxidant stream at a velocity which significantly exceeds combustion flame speed in a selected lean premixed fuel and oxidant mixture. The combustor is configured to operate at relatively high bulk fluid velocities while maintaining stable combustion, and low NOx emissions. The combustor is useful in gas turbines in a process of burning synfuels, as it offers the opportunity to avoid use of diluent gas to reduce combustion temperatures. The combustor also offers the possibility of avoiding the use of selected catalytic reaction units for removal of oxides of nitrogen from combustion gases exiting a gas turbine.

  13. Vortex combustor for low NOx emissions when burning lean premixed high hydrogen content fuel

    DOEpatents

    Steele, Robert C.; Edmonds, Ryan G.; Williams, Joseph T.; Baldwin, Stephen P.

    2009-10-20

    A trapped vortex combustor. The trapped vortex combustor is configured for receiving a lean premixed gaseous fuel and oxidant stream, where the fuel includes hydrogen gas. The trapped vortex combustor is configured to receive the lean premixed fuel and oxidant stream at a velocity which significantly exceeds combustion flame speed in a selected lean premixed fuel and oxidant mixture. The combustor is configured to operate at relatively high bulk fluid velocities while maintaining stable combustion, and low NOx emissions. The combustor is useful in gas turbines in a process of burning synfuels, as it offers the opportunity to avoid use of diluent gas to reduce combustion temperatures. The combustor also offers the possibility of avoiding the use of selected catalytic reaction units for removal of oxides of nitrogen from combustion gases exiting a gas turbine.

  14. Procedure for generating global atmospheric engine emissions data from future supersonic transport aircraft. The 1990 high speed civil transport studies

    NASA Technical Reports Server (NTRS)

    Sohn, R. A.; Stroup, J. W.

    1990-01-01

    The input for global atmospheric chemistry models was generated for baseline High Speed Civil Transport (HSCT) configurations at Mach 1.6, 2.2, and 3.2. The input is supplied in the form of number of molecules of specific exhaust constituents injected into the atmosphere per year by latitude and by altitude (for 2-D codes). Seven exhaust constituents are currently supplied: NO, NO2, CO, CO2, H2O, SO2, and THC (Trace Hydrocarbons). An eighth input is also supplied, NO(x), the sum of NO and NO2. The number of molecules of a given constituent emitted per year is a function of the total fuel burned by a supersonic fleet and the emission index (EI) of the aircraft engine for the constituent in question. The EIs for an engine are supplied directly by the engine manufacturers. The annual fuel burn of a supersonic fleet is calculated from aircraft performance and economic criteria, both of which are strongly dependent on basic design parameters such as speed and range. The altitude and latitude distribution of the emission is determined based on 10 Intern. Air Transport Assoc. (IATA) regions chosen to define the worldwide route structure for future HSCT operations and the mission flight profiles.

  15. Jet aircraft engine exhaust emissions database development: Year 1990 and 2015 scenarios

    NASA Technical Reports Server (NTRS)

    Landau, Z. Harry; Metwally, Munir; Vanalstyne, Richard; Ward, Clay A.

    1994-01-01

    Studies relating to environmental emissions associated with the High Speed Civil Transport (HSCT) military jet and charter jet aircraft were conducted by McDonnell Douglas Aerospace Transport Aircraft. The report includes engine emission results for baseline 1990 charter and military scenario and the projected jet engine emissions results for a 2015 scenario for a Mach 1.6 HSCT charter and military fleet. Discussions of the methodology used in formulating these databases are provided.

  16. Method for the control of NOx emissions in long-range space travel.

    PubMed

    Xu, X H; Shi, Y; Liu, S H; Wang, H P; Chang, S G; Fisher, J W; Pisharody, S; Moran, M; Wignarajah, K

    2003-01-01

    The wheat straw, an inedible biomass that can be continuously produced in a space vehicle has been used to produce activated carbon for effective control of NOx emissions from the incineration of wastes. The optimal carbonization temperature of wheat straw was found to be around 600 degrees C when a burnoff of 67% was observed. The BET surface area of the activated carbon produced from the wheat straw reached as high as 300 m2/g. The presence of oxygen in flue gas is essential for effective adsorption of NO by activated carbon. On the contrary, water vapor inhibits the adsorption efficiency of NO. Consequently, water vapor in flue gas should be removed by drying agents before adsorption to ensure high NO adsorption efficiency. All of the NO in the flue gas was removed for more than 2 h by the activated carbons when 10% oxygen was present and the ratio of carbon weight to the flue gas flow rate (W/F) was 30 g min/L, with a contact time of 10.2 s. All of NO was reduced to N2 by the activated carbon at 450 degrees C with a W/F ratio of 15 g min/L and a contact time of 5.1 s. Reduction of the adsorbed NO also regenerated the activated carbon, and the regenerated activated carbon exhibited an improved NO adsorption efficiency. However, the reduction of the adsorbed NO resulted in a loss of carbon which was determined to be about 0.99% of the activated carbon per cycle of regeneration. The sufficiency of the amount of wheat straw in providing the activated carbon based on a six-person crew, such as the mission planned for Mars, has been determined. This novel approach for the control of NOx emissions is sustainable in a closed system such as the case in space travel. It is simple to operate and is functional under microgravity environment.

  17. Method for the control of NOx emissions in long-range space travel.

    PubMed

    Xu, X H; Shi, Y; Liu, S H; Wang, H P; Chang, S G; Fisher, J W; Pisharody, S; Moran, M; Wignarajah, K

    2003-01-01

    The wheat straw, an inedible biomass that can be continuously produced in a space vehicle has been used to produce activated carbon for effective control of NOx emissions from the incineration of wastes. The optimal carbonization temperature of wheat straw was found to be around 600 degrees C when a burnoff of 67% was observed. The BET surface area of the activated carbon produced from the wheat straw reached as high as 300 m2/g. The presence of oxygen in flue gas is essential for effective adsorption of NO by activated carbon. On the contrary, water vapor inhibits the adsorption efficiency of NO. Consequently, water vapor in flue gas should be removed by drying agents before adsorption to ensure high NO adsorption efficiency. All of the NO in the flue gas was removed for more than 2 h by the activated carbons when 10% oxygen was present and the ratio of carbon weight to the flue gas flow rate (W/F) was 30 g min/L, with a contact time of 10.2 s. All of NO was reduced to N2 by the activated carbon at 450 degrees C with a W/F ratio of 15 g min/L and a contact time of 5.1 s. Reduction of the adsorbed NO also regenerated the activated carbon, and the regenerated activated carbon exhibited an improved NO adsorption efficiency. However, the reduction of the adsorbed NO resulted in a loss of carbon which was determined to be about 0.99% of the activated carbon per cycle of regeneration. The sufficiency of the amount of wheat straw in providing the activated carbon based on a six-person crew, such as the mission planned for Mars, has been determined. This novel approach for the control of NOx emissions is sustainable in a closed system such as the case in space travel. It is simple to operate and is functional under microgravity environment. PMID:14672086

  18. Method for the control of NOx emissions in long-range space travel

    NASA Technical Reports Server (NTRS)

    Xu, X. H.; Shi, Y.; Liu, S. H.; Wang, H. P.; Chang, S. G.; Fisher, J. W.; Pisharody, S.; Moran, M.; Wignarajah, K.

    2003-01-01

    The wheat straw, an inedible biomass that can be continuously produced in a space vehicle has been used to produce activated carbon for effective control of NOx emissions from the incineration of wastes. The optimal carbonization temperature of wheat straw was found to be around 600 degrees C when a burnoff of 67% was observed. The BET surface area of the activated carbon produced from the wheat straw reached as high as 300 m2/g. The presence of oxygen in flue gas is essential for effective adsorption of NO by activated carbon. On the contrary, water vapor inhibits the adsorption efficiency of NO. Consequently, water vapor in flue gas should be removed by drying agents before adsorption to ensure high NO adsorption efficiency. All of the NO in the flue gas was removed for more than 2 h by the activated carbons when 10% oxygen was present and the ratio of carbon weight to the flue gas flow rate (W/F) was 30 g min/L, with a contact time of 10.2 s. All of NO was reduced to N2 by the activated carbon at 450 degrees C with a W/F ratio of 15 g min/L and a contact time of 5.1 s. Reduction of the adsorbed NO also regenerated the activated carbon, and the regenerated activated carbon exhibited an improved NO adsorption efficiency. However, the reduction of the adsorbed NO resulted in a loss of carbon which was determined to be about 0.99% of the activated carbon per cycle of regeneration. The sufficiency of the amount of wheat straw in providing the activated carbon based on a six-person crew, such as the mission planned for Mars, has been determined. This novel approach for the control of NOx emissions is sustainable in a closed system such as the case in space travel. It is simple to operate and is functional under microgravity environment.

  19. Injection of lightning-produced NOx, water vapor, wildfire emissions, and stratospheric air to the UT/LS as observed from DC3 measurements

    NASA Astrophysics Data System (ADS)

    Huntrieser, H.; Lichtenstern, M.; Scheibe, M.; Aufmhoff, H.; Schlager, H.; Pucik, T.; Minikin, A.; Weinzierl, B.; Heimerl, K.; Pollack, I. B.; Peischl, J.; Ryerson, T. B.; Weinheimer, A. J.; Honomichl, S.; Ridley, B. A.; Biggerstaff, M. I.; Betten, D. P.; Hair, J. W.; Butler, C. F.; Schwartz, M. J.; Barth, M. C.

    2016-06-01

    During the Deep Convective Clouds and Chemistry (DC3) experiment in summer 2012, airborne measurements were performed in the anvil inflow/outflow of thunderstorms over the Central U.S. by three research aircraft. A general overview of Deutsches Zentrum für Luft- und Raumfahrt (DLR)-Falcon in situ measurements (CO, O3, SO2, CH4, NO, NOx, and black carbon) is presented. In addition, a joint flight on 29 May 2012 in a convective line of isolated supercell storms over Oklahoma is described based on Falcon, National Science Foundation/National Center for Atmospheric Research Gulfstream-V (NSF/NCAR-GV), and NASA-DC8 trace species in situ and lidar measurements. During DC3 some of the largest and most destructive wildfires in New Mexico and Colorado state's history were burning, which strongly influenced air quality in the DC3 thunderstorm inflow and outflow region. Lofted biomass burning (BB) plumes were frequently observed in the mid- and upper troposphere (UT) in the vicinity of deep convection. The impact of lightning-produced NOx (LNOx) and BB emissions was analyzed on the basis of mean vertical profiles and tracer-tracer correlations (CO-NOx and O3-NO). On a regular basis DC3 thunderstorms penetrated the tropopause and injected large amounts of LNOx into the lower stratosphere (LS). Inside convection, low O3 air (~80 nmol mol-1) from the lower troposphere was rapidly transported to the UT/LS region. Simultaneously, O3-rich stratospheric air masses (~100-200 nmol mol-1) were present around and below the thunderstorm outflow and enhanced UT-O3 mixing ratios significantly. A 10 year global climatology of H2O data from the Aura Microwave Limb Sounder confirmed that the Central U.S. is a preferred region for convective injection into the LS.

  20. Multi-satellite sensor study on precipitation-induced emission pulses of NOx from soils in semi-arid ecosystems

    NASA Astrophysics Data System (ADS)

    Zörner, Jan; Penning de Vries, Marloes; Beirle, Steffen; Sihler, Holger; Veres, Patrick R.; Williams, Jonathan; Wagner, Thomas

    2016-07-01

    We present a top-down approach to infer and quantify rain-induced emission pulses of NOx ( ≡ NO + NO2), stemming from biotic emissions of NO from soils, from satellite-borne measurements of NO2. This is achieved by synchronizing time series at single grid pixels according to the first day of rain after a dry spell of prescribed duration. The full track of the temporal evolution several weeks before and after a rain pulse is retained with daily resolution. These are needed for a sophisticated background correction, which accounts for seasonal variations in the time series and allows for improved quantification of rain-induced soil emissions. The method is applied globally and provides constraints on pulsed soil emissions of NOx in regions where the NOx budget is seasonally dominated by soil emissions. We find strong peaks of enhanced NO2 vertical column densities (VCDs) induced by the first intense precipitation after prolonged droughts in many semi-arid regions of the world, in particular in the Sahel. Detailed investigations show that the rain-induced NO2 pulse detected by the OMI (Ozone Monitoring Instrument), GOME-2 and SCIAMACHY satellite instruments could not be explained by other sources, such as biomass burning or lightning, or by retrieval artefacts (e.g. due to clouds). For the Sahel region, absolute enhancements of the NO2 VCDs on the first day of rain based on OMI measurements 2007-2010 are on average 4 × 1014  molec cm-2 and exceed 1 × 1015  molec cm-2 for individual grid cells. Assuming a NOx lifetime of 4 h, this corresponds to soil NOx emissions in the range of 6 up to 65 ng N m-2 s-1, which is in good agreement with literature values. Apart from the clear first-day peak, NO2 VCDs are moderately enhanced (2 × 1014  molec cm-2) compared to the background over the following 2 weeks, suggesting potential further emissions during that period of about 3.3 ng N m-2 s-1

  1. A new approach for estimation of the effect of NOx emission reduction on roadside NO2 concentration in Tokyo

    NASA Astrophysics Data System (ADS)

    Takekawa, Hideto; Chatani, Satoru; Ito, Akiyoshi

    2013-04-01

    The mean NO2/NOx ratios of vehicle emission, the mean duration time of NO reaction with O3 and background concentrations at the five most polluted roadside stations in Tokyo are estimated statistically using monitoring data at both roadside sites and urban background sites. These statistics are then used to categorize roadside NO2 into three components; NO2 emission from vehicles (primary NO2), oxidation of NO by O3 (secondary NO2) and background NO2 (BG NO2). Secondary NO2 and BG NO2 make a greater contribution to the high NO2 concentrations in spring and summer. On the other hand, BG NO2 contributes the dominant portion to high NO2 concentrations in winter. The effects of vehicle NOx emission reduction on the concentration of primary, secondary and BG NO2 are evaluated using an NO2 emission reduction scenario, an oxidation model proposed in this study and an air quality simulation, respectively. It is predicted that the shift to vehicles meeting the stringent emission regulation beginning in 2009 will lower the roadside NO2 concentration due mainly to the large decrease in secondary NO2. On the other hand, the reduction of NOx in vehicle emissions results in a smaller decrease in roadside NO2 in winter.

  2. An enhanced rate-based emission trading program for NOX: the Dutch model.

    PubMed

    Sholtz, A M; Van Amburg, B; Wochnick, V K

    2001-12-01

    Since 1997 government and industry in The Netherlands have been engaged in intensive policy discussions on how to design an emission trading program that would satisfy the Government's policy objectives within the national and international regulatory framework and accommodate industry's need for a flexible and cost-effective approach. Early on in the discussion the most promising solution was a rate-based approach, which dynamically allocated saleable emission credits based on a performance standard rate and actual energy used by facilities. All industrial facilities above a threshold of 20 MWth would be judged on their ability to meet this performance rate. Those "cleaner" than the standard can sell excess credits to others with an allocation that is less than their actual NOX emission. With some changes in law, such a design could be made to fit well into the national and EU legislative framework while at the same time uniquely meeting industry's requirement of flexibility toward economic growth and facility expansion. (An analysis of the legislative changes required will be given in a separate paper by Chris Dekkers.) However, the environmental outcome of such a system is not as certain as under an absolute emission cap. At the request of the Netherlands Ministry of Housing, Spatial Planning and the Environment (VROM), Automated Credit Exchange (ACE), in close cooperation with the working group of government and industry representatives introduced a number of features into the Dutch NOX program allowing full exploitation of market mechanisms while allowing intermediate adjustments in the performance standard rates. The design is geared toward meeting environmental targets without jeopardizing the trading market the program intends to create. The paper discusses the genesis of the two-tier credit system ACE helped to design, explains the differences between primary (fixed) and secondary (variable) credits, and outlines how the Dutch system is expected to

  3. An enhanced rate-based emission trading program for NOX: the Dutch model.

    PubMed

    Sholtz, A M; Van Amburg, B; Wochnick, V K

    2001-12-01

    Since 1997 government and industry in The Netherlands have been engaged in intensive policy discussions on how to design an emission trading program that would satisfy the Government's policy objectives within the national and international regulatory framework and accommodate industry's need for a flexible and cost-effective approach. Early on in the discussion the most promising solution was a rate-based approach, which dynamically allocated saleable emission credits based on a performance standard rate and actual energy used by facilities. All industrial facilities above a threshold of 20 MWth would be judged on their ability to meet this performance rate. Those "cleaner" than the standard can sell excess credits to others with an allocation that is less than their actual NOX emission. With some changes in law, such a design could be made to fit well into the national and EU legislative framework while at the same time uniquely meeting industry's requirement of flexibility toward economic growth and facility expansion. (An analysis of the legislative changes required will be given in a separate paper by Chris Dekkers.) However, the environmental outcome of such a system is not as certain as under an absolute emission cap. At the request of the Netherlands Ministry of Housing, Spatial Planning and the Environment (VROM), Automated Credit Exchange (ACE), in close cooperation with the working group of government and industry representatives introduced a number of features into the Dutch NOX program allowing full exploitation of market mechanisms while allowing intermediate adjustments in the performance standard rates. The design is geared toward meeting environmental targets without jeopardizing the trading market the program intends to create. The paper discusses the genesis of the two-tier credit system ACE helped to design, explains the differences between primary (fixed) and secondary (variable) credits, and outlines how the Dutch system is expected to

  4. Effects of co-processing sewage sludge in cement kiln on NOx, NH3 and PAHs emissions.

    PubMed

    Lv, Dong; Zhu, Tianle; Liu, Runwei; Lv, Qingzhi; Sun, Ye; Wang, Hongmei; Liu, Yu; Zhang, Fan

    2016-09-01

    The effects of co-processing sewage sludge in cement kiln on NOx, NH3 and PAHs emissions were systematically investigated in a cement production line in Beijing. The results show that co-processing the sewage sludge was helpful to reduce NOx emission, which primarily depends on the NH3 amount released from the sewage sludge. Meanwhile, NOx and NH3 concentrations in the flue gas have a negative correlation, and the contribution of feeding the sewage sludge to NOx removal decreased with the increase of injection amount of ammonia water in the SNCR system. Therefore, it is suggested that the injection amount of ammonia water in SNCR system may reduce to cut down the operating costs during co-processing the sewage sludge in cement kiln. In addition, the emission of total PAHs seems to increase with the increased amount of the sewage sludge feeding to the cement kiln. However, the distributions of PAHs were barely changed, and lower molecular weight PAHs were mainly distributed in gaseous phase, accounted for the major portion of PAHs when co-processing sewage sludge in cement kiln.

  5. Effects of co-processing sewage sludge in cement kiln on NOx, NH3 and PAHs emissions.

    PubMed

    Lv, Dong; Zhu, Tianle; Liu, Runwei; Lv, Qingzhi; Sun, Ye; Wang, Hongmei; Liu, Yu; Zhang, Fan

    2016-09-01

    The effects of co-processing sewage sludge in cement kiln on NOx, NH3 and PAHs emissions were systematically investigated in a cement production line in Beijing. The results show that co-processing the sewage sludge was helpful to reduce NOx emission, which primarily depends on the NH3 amount released from the sewage sludge. Meanwhile, NOx and NH3 concentrations in the flue gas have a negative correlation, and the contribution of feeding the sewage sludge to NOx removal decreased with the increase of injection amount of ammonia water in the SNCR system. Therefore, it is suggested that the injection amount of ammonia water in SNCR system may reduce to cut down the operating costs during co-processing the sewage sludge in cement kiln. In addition, the emission of total PAHs seems to increase with the increased amount of the sewage sludge feeding to the cement kiln. However, the distributions of PAHs were barely changed, and lower molecular weight PAHs were mainly distributed in gaseous phase, accounted for the major portion of PAHs when co-processing sewage sludge in cement kiln. PMID:27343866

  6. Relationship between VOC and NOx emissions and chemical production of tropospheric ozone in the Aburrá Valley (Colombia).

    PubMed

    Toro, María Victoria; Cremades, Lázaro V; Calbó, Josep

    2006-10-01

    Relationship between volatile organic compounds (VOC) and nitrogen oxides (NOx) emissions and the chemical production of tropospheric ozone is studied through mathematical simulation. The study is applied to the Aburrá Valley, in the Colombian Andes, which is a practically unknown area from the point of view of ozone formation. The model used for this application is the European modelling of atmospheric constituents (EUMAC) zooming model (EZM) which consists of a mesoscale prognostic model (MEMO, mesoscale meteorological model) and a chemical reaction model (MUSE, multiscale for the atmospheric dispersion of reactive species), coupled to the chemical mechanism EMEP (European monitoring and evaluation program). The analysis is performed for a real episode that was characterized by high ozone production and that happened during the 23rd and 24th December, 1999 in Medellín (Colombia). From this real scenario, a sensitivity analysis has been carried out in order to assess the influence of VOC and NOx amounts on ozone production and to extract some conclusions for future ozone abatement policies in Andean regions. As far as ozone air quality is concerned, it is shown that in order to keep current levels the emphasis must be put to avoid increasing NOx emissions, or alternatively, to augment VOC emissions in order to have a high VOC/NOx ratio. PMID:16631888

  7. Measurement of ethylene emission from Japanese red pine (Pinus densiflora) under field conditions in NOx-polluted areas.

    PubMed

    Kume, A; Tsuboi, N; Nakatani, N; Nakane, K; Sakurai, N; Nakagawa, N; Sakugawa, H

    2001-01-01

    Emission of ethylene from the needles of Japanese red pine, Pinus densiflora, was measured in air-polluted areas in Hiroshima, Japan. We applied a suitable protocol to determine the rate of ethylene emission from the excised needles. The influence of excision of needles on ethylene emission was not detected during the first 4 h of incubation at 20 degrees C. Ethylene emissions were low in the unpolluted (clean) areas regardless of the altitude or season. The emission of stress ethylene increased with the atmospheric NO2 concentration, suggesting that atmospheric NOx or related substances induced the higher ethylene emission in the polluted areas (near urban and industrial areas). In all cases, 1-year-old needles emitted significantly larger amounts of ethylene than the current needles. Ethylene emission did not increase evenly in the polluted areas, but the frequency of trees emitting high ethylene increased. Therefore, threshold rates for the baseline ethylene emission were proposed.

  8. Shifting primary energy source and NOx emission location with plug-in hybrid vehicles

    NASA Astrophysics Data System (ADS)

    Karman, Deniz

    2011-06-01

    Plug-in hybrid vehicles (PHEVs) present an interesting technological opportunity for using non-fossil primary energy in light duty passenger vehicles, with the associated potential for reducing air pollutant and greenhouse gas emissions, to the extent that the electric power grid is fed by non-fossil sources. This perspective, accompanying the article by Thompson et al (2011) in this issue, will touch on two other studies that are directly related: the Argonne study (Elgowainy et al 2010) and a PhD thesis from Utrecht (van Vliet 2010). Thompson et al (2011) have examined air quality effects in a case where the grid is predominantly fossil fed. They estimate a reduction of 7.42 tons/day of NOx from motor vehicles as a result of substituting electric VMTs for 20% of the light duty gasoline vehicle miles traveled. To estimate the impact of this reduction on air quality they also consider the increases in NOx emissions due to the increased load on electricity generating units. The NOx emission increases are estimated as 4.0, 5.5 and 6.3 tons for the Convenience, Battery and Night charging scenarios respectively. The net reductions are thus in the 1.1-3.4 tons/day range. The air quality modelling results presented show that the air quality impact from a ground-level ozone perspective is favorable overall, and while the effect is stronger in some localities, the difference between the three scenarios is small. This is quite significant and suggests that localization of the NOx emissions to point sources has a more pronounced effect than the absolute reductions achieved. Furthermore it demonstrates that localization of NOx emissions to electricity generating units by using PHEVs in vehicle traffic has beneficial effects for air quality not only by minimizing direct human exposure to motor vehicle emissions, but also due to reduced exposure to secondary pollutants (i.e. ozone). In an electric power grid with a smaller share of fossil fired generating units, the beneficial

  9. Jet engine exhaust emissions of high altitude commercial aircraft projected to 1990

    NASA Technical Reports Server (NTRS)

    Grobman, J.; Ingebo, R. D.

    1974-01-01

    Projected minimum levels of engine exhaust emissions that may be practicably achievable for future commercial aircraft operating at high-altitude cruise conditions are presented. The forecasts are based on:(1) current knowledge of emission characteristics of combustors and augmentors; (2) the status of combustion research in emission reduction technology; and (3) predictable trends in combustion systems and operating conditions as required for projected engine designs that are candidates for advanced subsonic or supersonic commercial aircraft fueled by either JP fuel, liquefied natural gas, or hydrogen. Results are presented for cruise conditions in terms of both an emission index (g constituent/kg fuel) and an emission rate (g constituent/hr).

  10. Comparison of Weekly Cycle of NO2 Satellite Retrievals and NO(x) Emission Inventories for the Continental United States

    NASA Technical Reports Server (NTRS)

    Kaynak, B.; Hu, Y.; Martin, R. V.; Sioris, C. E.; Russell, A. G.

    2009-01-01

    Spatially resolved weekly NO2 variations are obtained from 2003 to 2005 Scanning Imaging Absorption Spectrometer for Atmospheric Cartography (SCIAMACHY) tropospheric NO2 columns for three different types of regions: urban, rural, and rural-point (rural with significant electricity generation unit (EGU) emissions). Regions are compared for magnitudes and weekly profiles. Rural regions do not show any weekly pattern, whereas urban areas show a distinct decrease on the weekends. Rural regions with EGUs show a slight decrease on Sundays. When compared with estimated mobile and stationary nitrogen oxides (NO(x)) emissions from the year 2004 for seven cities, the satellite data have greater variation during weekdays (Monday-Friday). Overall comparisons show that SCIAMACHY derived NO2 correlate well with estimated NO(x) emissions for urban and rural but less for rural-point regions.

  11. Estimates of the changes in tropospheric chemistry which result from human activity and their dependence on NO(x) emissions and model resolution

    NASA Technical Reports Server (NTRS)

    Kanakidou, Maria; Crutzen, Paul J.; Zimmermann, Peter H.

    1994-01-01

    As a consequence of the non-linear behavior of the chemistry of the atmosphere and because of the short lifetime of nitrogen oxides (NO(x)), two-dimensional models do not give an adequate description of the production and destruction rates of NO(x) and their effects on the distributions of the concentration of ozone and hydroxyl radical. In this study, we use a three-dimensional model to evaluate the contribution of increasing NO(x) emissions from industrial activity and biomass burning to changes in the chemical composition of the troposphere. By comparing results obtained from longitudinally-uniform and longitudinally-varying emissions of NO(x), we demonstrate that the geographical representation of the NO(x) emissions is crucial in simulating tropospheric chemistry.

  12. Status of Technological Advancements for Reducing Aircraft Gas Turbine Engine Pollutant Emissions

    NASA Technical Reports Server (NTRS)

    Rudey, R. A.

    1975-01-01

    Combustor test rig results indicate that substantial reductions from current emission levels of carbon monoxide (CO), total unburned hydrocarbons (THC), oxides of nitrogen (NOx), and smoke are achievable by employing varying degrees of technological advancements in combustion systems. Minor to moderate modifications to existing conventional combustors produced significant reductions in CO and THC emissions at engine low power (idle/taxi) operating conditions but did not effectively reduce NOx at engine full power (takeoff) operating conditions. Staged combusiton techniques were needed to simultaneously reduce the levels of all the emissions over the entire engine operating range (from idle to takeoff). Emission levels that approached or were below the requirements of the 1979 EPA standards were achieved with the staged combustion systems and in some cases with the minor to moderate modifications to existing conventional combustion systems. Results from research programs indicate that an entire new generation of combustor technology with extremely low emission levels may be possible in the future.

  13. Emission factors of air pollutants from CNG-gasoline bi-fuel vehicles: Part II. CO, HC and NOx.

    PubMed

    Huang, Xiaoyan; Wang, Yang; Xing, Zhenyu; Du, Ke

    2016-09-15

    The estimation of emission factors (EFs) is the basis of accurate emission inventory. However, the EFs of air pollutants for motor vehicles vary under different operating conditions, which will cause uncertainty in developing emission inventory. Natural gas (NG), considered as a "cleaner" fuel than gasoline, is increasingly being used to reduce combustion emissions. However, information is scarce about how much emission reduction can be achieved by motor vehicles burning NG (NGVs) under real road driving conditions, which is necessary for evaluating the environmental benefits for NGVs. Here, online, in situ measurements of the emissions from nine bi-fuel vehicles were conducted under different operating conditions on the real road. A comparative study was performed for the EFs of black carbon (BC), carbon monoxide (CO), hydrocarbons (HCs) and nitrogen oxides (NOx) for each operating condition when the vehicles using gasoline and compressed NG (CNG) as fuel. BC EFs were reported in part I. The part II in this paper series reports the influence of operating conditions and fuel types on the EFs of CO, HC and NOx. Fuel-based EFs of CO showed good correlations with speed when burning CNG and gasoline. The correlation between fuel-based HC EFs and speed was relatively weak whether burning CNG or gasoline. The fuel-based NOx EFs moderately correlated with speed when burning CNG, but weakly correlated with gasoline. As for HC, the mileage-based EFs of gasoline vehicles are 2.39-12.59 times higher than those of CNG vehicles. The mileage-based NOx EFs of CNG vehicles are slightly higher than those of gasoline vehicles. These results would facilitate a detailed analysis of the environmental benefits for replacing gasoline with CNG in light duty vehicles.

  14. Emission factors of air pollutants from CNG-gasoline bi-fuel vehicles: Part II. CO, HC and NOx.

    PubMed

    Huang, Xiaoyan; Wang, Yang; Xing, Zhenyu; Du, Ke

    2016-09-15

    The estimation of emission factors (EFs) is the basis of accurate emission inventory. However, the EFs of air pollutants for motor vehicles vary under different operating conditions, which will cause uncertainty in developing emission inventory. Natural gas (NG), considered as a "cleaner" fuel than gasoline, is increasingly being used to reduce combustion emissions. However, information is scarce about how much emission reduction can be achieved by motor vehicles burning NG (NGVs) under real road driving conditions, which is necessary for evaluating the environmental benefits for NGVs. Here, online, in situ measurements of the emissions from nine bi-fuel vehicles were conducted under different operating conditions on the real road. A comparative study was performed for the EFs of black carbon (BC), carbon monoxide (CO), hydrocarbons (HCs) and nitrogen oxides (NOx) for each operating condition when the vehicles using gasoline and compressed NG (CNG) as fuel. BC EFs were reported in part I. The part II in this paper series reports the influence of operating conditions and fuel types on the EFs of CO, HC and NOx. Fuel-based EFs of CO showed good correlations with speed when burning CNG and gasoline. The correlation between fuel-based HC EFs and speed was relatively weak whether burning CNG or gasoline. The fuel-based NOx EFs moderately correlated with speed when burning CNG, but weakly correlated with gasoline. As for HC, the mileage-based EFs of gasoline vehicles are 2.39-12.59 times higher than those of CNG vehicles. The mileage-based NOx EFs of CNG vehicles are slightly higher than those of gasoline vehicles. These results would facilitate a detailed analysis of the environmental benefits for replacing gasoline with CNG in light duty vehicles. PMID:27219504

  15. Comparison of methodologies estimating emissions of aircraft pollutants, environmental impact assessment around airports

    SciTech Connect

    Kurniawan, Jermanto S. Khardi, S.

    2011-04-15

    Air transportation growth has increased continuously over the years. The rise in air transport activity has been accompanied by an increase in the amount of energy used to provide air transportation services. It is also assumed to increase environmental impacts, in particular pollutant emissions. Traditionally, the environmental impacts of atmospheric emissions from aircraft have been addressed in two separate ways; aircraft pollutant emissions occurring during the landing and take-off (LTO) phase (local pollutant emissions) which is the focus of this study, and the non-LTO phase (global/regional pollutant emissions). Aircraft pollutant emissions are an important source of pollution and directly or indirectly harmfully affect human health, ecosystems and cultural heritage. There are many methods to asses pollutant emissions used by various countries. However, using different and separate methodology will cause a variation in results, some lack of information and the use of certain methods will require justification and reliability that must be demonstrated and proven. In relation to this issue, this paper presents identification, comparison and reviews of some of the methodologies of aircraft pollutant assessment from the past, present and future expectations of some studies and projects focusing on emissions factors, fuel consumption, and uncertainty. This paper also provides reliable information on the impacts of aircraft pollutant emissions in short term and long term predictions.

  16. Simulations of NOx Emissions from Low Emissions Discrete Jet Injector Combustor Tests

    NASA Technical Reports Server (NTRS)

    Ajmani, Kumud; Breisacher, Kevin

    2014-01-01

    An experimental and computational study was conducted to evaluate the performance and emissions characteristics of a candidate Lean Direct Injection (LDI) combustor configuration with a mix of simplex and airblast injectors. The National Combustion Code (NCC) was used to predict the experimentally measured EINOx emissions for test conditions representing low power, medium power, and high-power engine cycle conditions. Of the six cases modeled with the NCC using a reduced-kinetics finite-rate mechanism and lagrangian spray modeling, reasonable predictions of combustor exit temperature and EINOx were obtained at two high-power cycle conditions.

  17. Results and status of the NASA aircraft engine emission reduction technology programs

    NASA Technical Reports Server (NTRS)

    Jones, R. E.; Diehl, L. A.; Petrash, D. A.; Grobman, J.

    1978-01-01

    The results of an aircraft engine emission reduction study are reviewed in detail. The capability of combustor concepts to produce significantly lower levels of exhaust emissions than present production combustors was evaluated. The development status of each combustor concept is discussed relative to its potential for implementation in aircraft engines. Also, the ability of these combustor concepts to achieve proposed NME and NCE EPA standards is discussed.

  18. Status review of NASA programs for reducing aircraft gas turbine engine emissions

    NASA Technical Reports Server (NTRS)

    Rudey, R. A.

    1976-01-01

    Programs initiated by NASA to develop and demonstrate low emission advanced technology combustors for reducing aircraft gas turbine engine pollution are reviewed. Program goals are consistent with urban emission level requirements as specified by the U. S. Environmental Protection Agency and with upper atmosphere cruise emission levels as recommended by the U. S. Climatic Impact Assessment Program and National Research Council. Preliminary tests of advanced technology combustors indicate that significant reductions in all major pollutant emissions should be attainable in present generation aircraft gas turbine engines without adverse effects on fuel consumption. Preliminary test results from fundamental studies indicate that extremely low emission combustion systems may be possible for future generation jet aircraft. The emission reduction techniques currently being evaluated in these programs are described along with the results and a qualitative assessment of development difficulty.

  19. Attributing changes in atmospheric methane 1850-2000 to changes in CH4, NOx, CO, and NMVOC emissions (Invited)

    NASA Astrophysics Data System (ADS)

    Stevenson, D. S.

    2013-12-01

    Global atmospheric methane concentrations rose from 791 ppb in 1850 to 1751 ppb in 2000, with an associated radiative forcing (RF) of 427 mW m-2. This growth can be attributed to several factors - here we focus on changes in anthropogenic emissions of methane itself, but also on emissions of nitrogen oxides (NOx), carbon monoxide (CO) and non-methane hydrocarbons (NMVOC). Within the Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP), six models conducted sensitivity experiments and found that CH4 emissions alone produced a CH4 RF of 533 mW m-2; other contributions (mW m-2) were: NOx, -312; CO, 58; and NMVOC, 35. These four numbers sum to 300, not 427, indicating that the RFs cannot be simply added, and that important interactions between emitted species have occurred. A further suite of sensitivity experiments were carried out with one of the ACCMIP models (STOC-HadAM3), changing combinations of emissions, to investigate these interactions in more detail. The largest sources of non-linearity are from interactions between emitted NOx and the other emitted species. These results indicate that a simple, individual species attribution of CH4 RF to emitted species is only approximately correct, and hides important interactions. These interactions will probably depend on individual model's chemical schemes, and they present a further difficulty in communicating robust results on short-lived climate forcing agents to policymakers.

  20. Eco-friendly selection of ship emissions reduction strategies with emphasis on SOx and NOx emissions

    NASA Astrophysics Data System (ADS)

    Seddiek, Ibrahim S.; Elgohary, Mohamed M.

    2014-09-01

    Increasing amounts of ships exhaust gases emitted worldwide forced the International Maritime Organization to issue some restricted maritime legislation for reducing the adverse environmental impacts arising from such emissions. Consequently, ships emission reduction became one of the technical and economical challenges that facing the ships, operators. The present paper addresses the different strategies that can be used to reduce those emissions, especially nitrogen oxides and sulfur oxides. The strategies included: applying reduction technologies onboard, using of alternative fuels, and follows one of fuel saving strategies. Using of selective catalytic reduction and sea water scrubbing appeared as the best reduction technologies onboard ships. Moreover, among the various proposed alternative fuels, natural gas, in its liquid state; has the priority to be used instead of conventional fuels. Applying one of those strategies is the matter of ship type and working area. As a numerical example, the proposed methods were investigated at a high-speed craft operating in the Red Sea area between Egypt and the Kingdom of Saudi Arabia. The results obtained are very satisfactory from the point of view of environment and economic issues, and reflected the importance of applying those strategies

  1. The impact of emission standards on the design of aircraft gas turbine engine combustors

    NASA Technical Reports Server (NTRS)

    Rudey, R. A.

    1976-01-01

    The advent of environmental standards for controlling aircraft gas turbine engine emissions has led to a reevaluation of combustor design techniques. Effective emission control techniques have been identified and a wide spectrum of potential applications for these techniques to existing and advanced engines are being considered. Results from advanced combustor concept evaluations and from fundamental experiments are presented and discussed and comparisons are made with existing EPA emission standards and recommended levels for high altitude cruise. The impact that the advanced low emission concepts may impose on future aircraft engine combustor designs and related engine components is discussed.

  2. Experimental Assessment of the Emissions Control Potential of a Rich/Quench/ Lean Combustor for High Speed Civil Transport Aircraft Engines

    NASA Technical Reports Server (NTRS)

    Tacina, Robert R. (Technical Monitor); Rosfjord, T. J.; Padget, F. C.

    2001-01-01

    In support of Pratt & Whitney efforts to define the Rich burn/Quick mix/Lean burn (RQL) combustor for the High Speed Civil Transport (HSCT) aircraft engine, UTRC conducted a flametube-scale study of the RQL concept. Extensive combustor testing was performed at the Supersonic Cruise (SSC) condition of an HSCT engine cycle. Data obtained from probe traverses near the exit of the mixing section confirmed that the mixing section was the critical component in controlling combustor emissions. Circular-hole configurations, which produced rapidly-, highly-penetrating jets, were most effective in limiting NO(x). The spatial profiles of NO(x) and CO at the mixer exit were not directly interpretable using a simple flow model based on jet penetration, and a greater understanding of the flow and chemical processes in this section are required to optimize it. Neither the rich-combustor equivalence ratio nor its residence time was a direct contributor to the exit NO(x). Based on this study, it was also concluded that: (1) While NO(x) formation in both the mixing section and the lean combustor contribute to the overall emission, the NOx formation in the mixing section dominates. The gas composition exiting the rich combustor can be reasonably represented by the equilibrium composition corresponding to the rich combustor operating condition. Negligible NO(x) exits the rich combustor. (2) At the SSC condition, the oxidation processes occurring in the mixing section consume 99 percent of the CO exiting the rich combustor. Soot formed in the rich combustor is also highly oxidized, with combustor exit SAE Smoke Number <3. (3) Mixing section configurations which demonstrated enhanced emissions control at SSC also performed better at part-power conditions. Data from mixer exit traverses reflected the expected mixing behavior for off-design jet to crossflow momentum-flux ratios. (4) Low power operating conditions require that the RQL combustor operate as a lean-lean combustor to achieve

  3. Experimental Assessment of the Emissions Control Potential of a Rich/Quench/Lean Combustor for High Speed Civil Transport Aircraft Engines

    NASA Technical Reports Server (NTRS)

    Rosfjord, T. J.; Padget, F. C.; Tacina, Robert R. (Technical Monitor)

    2001-01-01

    In support of Pratt & Whitney efforts to define the Rich burn/Quick mix/Lean burn (RQL) combustor for the High Speed Civil Transport (HSCT) aircraft engine, UTRC conducted a flametube-scale study of the RQL concept. Extensive combustor testing was performed at the Supersonic Cruise (SSC) condition of a HSCT engine cycle, Data obtained from probe traverses near the exit of the mixing section confirmed that the mixing section was the critical component in controlling combustor emissions. Circular-hole configurations, which produced rapidly-, highly-penetrating jets, were most effective in limiting NOx. The spatial profiles of NOx and CO at the mixer exit were not directly interpretable using a simple flow model based on jet penetration, and a greater understanding of the flow and chemical processes in this section are required to optimize it. Neither the rich-combustor equivalence ratio nor its residence time was a direct contributor to the exit NOx. Based on this study, it was also concluded that (1) While NOx formation in both the mixing section and the lean combustor contribute to the overall emission, the NOx formation in the mixing section dominates. The gas composition exiting the rich combustor can be reasonably represented by the equilibrium composition corresponding to the rich combustor operating condition. Negligible NOx exits the rich combustor. (2) At the SSC condition, the oxidation processes occurring in the mixing section consume 99 percent of the CO exiting the rich combustor. Soot formed in the rich combustor is also highly oxidized, with combustor exit SAE Smoke Number <3. (3) Mixing section configurations which demonstrated enhanced emissions control at SSC also performed better at part-power conditions. Data from mixer exit traverses reflected the expected mixing behavior for off-design jet to crossflow momentum-flux ratios. (4) Low power operating conditions require that the RQL combustor operate as a lean-lean combustor to achieve low CO and

  4. Anthropogenic NOx emissions alter the intrinsic water-use efficiency (WUEi) for Quercus cerris stands under Mediterranean climate conditions.

    PubMed

    Guerrieri, Rossella; Siegwolf, Rolf; Saurer, Matthias; Ripullone, Francesco; Mencuccini, Maurizio; Borghetti, Marco

    2010-09-01

    We investigated the effect of N deposition (Ndep) on intrinsic water-use efficiency (WUEi), the ratio of photosynthesis (A) to stomatal conductance (gs), for two Quercus cerris stands at different distances to an oil refinery in Southern Italy. We used delta13C in tree rings for assessing changes in WUEi; while the influence of climate and NOx emission was explored through delta18O and delta15N, respectively. Differences in WUEi between the two sites were significant, with trees exposed to different degrees of NOx emissions showing an abrupt increase with the onset of pollution. Assuming similar gs at the two sites, as inferred through delta18O, the higher N availability at the polluted site caused the shift of the A/gs ratio in favour of A. Overall, our result suggests that an increase of Ndep may enhance tree WUE under a scenario of reduction of precipitation predicted for Mediterranean area.

  5. RFID Transponders' Radio Frequency Emissions in Aircraft Communication and Navigation Radio Bands

    NASA Technical Reports Server (NTRS)

    Nguyen, Truong X.; Ely, Jay J.; Williams, Reuben A.; Koppen, Sandra V.; Salud, Maria Theresa P.

    2006-01-01

    Radiated emissions in aircraft communication and navigation bands are measured from several active radio frequency identification (RFID) tags. The individual tags are different in design and operations. They may also operate in different frequency bands. The process for measuring the emissions is discussed, and includes tag interrogation, reverberation chamber testing, and instrument settings selection. The measurement results are described and compared against aircraft emission limits. In addition, interference path loss for the cargo bays of passenger aircraft is measured. Cargo bay path loss is more appropriate for RFID tags than passenger cabin path loss. The path loss data are reported for several aircraft radio systems on a Boeing 747 and an Airbus A320.

  6. Chemical characterization of the fine particle emissions from commercial aircraft engines during the Aircraft Particle Emissions eXperiment (APEX) 1 to 3

    EPA Science Inventory

    This paper addresses the need for detailed chemical information on the fine particulate matter (PM2.5) generated by commercial aviation engines. The exhaust plumes of nine engine models were sampled during the three test campaigns of the Aircraft Particle Emissions eXperiment (AP...

  7. The use of rice hulls for sustainable control of NOx emissions in deep space missions

    SciTech Connect

    Xu, X.H.; Shi, Y.; Chang, S.G.; Fisher, J.W.; Pisharody, S.; Moran, M.J.; Wignarajah, K.

    2001-12-21

    The use of the activated carbon produced from rice hulls to control NOx emissions for the future deep space missions has been demonstrated. The optimal carbonization temperature range was found to be between 600 C and 750 C. The burnoff of 61.8% was found at 700 C in pyrolysis and 750 C in activation. The BET surface area of the activated carbon from rice hulls was determined to be 172 m{sup 2}/g when prepared at 700 C. The presence of oxygen in flue gas is essential for effective adsorption of NO by the activated carbon. On the contrary, water vapor inhibits the adsorption efficiency of NO. Consequently, water vapor in flue gas should be removed by drying agents before adsorption to ensure high NO adsorption efficiency. All of NO in the flue gas was removed for more than one and a half hours when 10% oxygen was present and using a ratio of the carbon weight to the flue gas flow rate (W/F) of 15.4 g-min/L. The reduction of the adsorbed NO to form N{sub 2} can be effectively accomplished under anaerobic conditions at 550 C. For NO saturated activated carbon, the loss of carbon mass was determined to be about 0.16% of the activated carbon per cycle of regeneration. The reduction of the adsorbed NO also regenerates the activated carbon. The regenerated activated carbon exhibits improved NO adsorption efficiency.

  8. Apparatus and method for burning a lean, premixed fuel/air mixture with low NOx emission

    DOEpatents

    Kostiuk, Larry W.; Cheng, Robert K.

    1996-01-01

    An apparatus for enabling a burner to stably burn a lean fuel/air mixture. The burner directs the lean fuel/air mixture in a stream. The apparatus comprises an annular flame stabilizer; and a device for mounting the flame stabilizer in the fuel/air mixture stream. The burner may include a body having an internal bore, in which case, the annular flame stabilizer is shaped to conform to the cross-sectional shape of the bore, is spaced from the bore by a distance greater than about 0.5 mm, and the mounting device mounts the flame stabilizer in the bore. An apparatus for burning a gaseous fuel with low NOx emissions comprises a device for premixing air with the fuel to provide a lean fuel/air mixture; a nozzle having an internal bore through which the lean fuel/air mixture passes in a stream; and a flame stabilizer mounted in the stream of the lean fuel/air mixture. The flame stabilizer may be mounted in the internal bore, in which case, it is shaped and is spaced from the bore as just described. In a method of burning a lean fuel/air mixture, a lean fuel/air mixture is provided, and is directed in a stream; an annular eddy is created in the stream of the lean fuel/air mixture; and the lean fuel/air mixture is ignited at the eddy.

  9. Near-field commercial aircraft contribution to nitrogen oxides by engine, aircraft type, and airline by individual plume sampling.

    PubMed

    Carslaw, David C; Ropkins, Karl; Laxen, Duncan; Moorcroft, Stephen; Marner, Ben; Williams, Martin L

    2008-03-15

    Nitrogen oxides (NOx) concentrations were measured in individual plumes from aircraft departing on the northern runway at Heathrow Airport in west London. Over a period of four weeks 5618 individual plumes were sampled by a chemiluminescence monitor located 180 m from the runway. Results were processed and matched with detailed aircraft movement and aircraft engine data using chromatographic techniques. Peak concentrations associated with 29 commonly used engines were calculated and found to have a good relationship with N0x emissions taken from the International Civil Aviation Organization (ICAO) databank. However, it is found that engines with higher reported NOx emissions result in proportionately lower NOx concentrations than engines with lower emissions. We show that it is likely that aircraft operational factors such as takeoff weight and aircraftthrust setting have a measurable and important effect on concentrations of N0x. For example, NOx concentrations can differ by up to 41% for aircraft using the same airframe and engine type, while those due to the same engine type in different airframes can differ by 28%. These differences are as great as, if not greater than, the reported differences in NOx emissions between different engine manufacturers for engines used on the same airframe.

  10. Near-field commercial aircraft contribution to nitrogen oxides by engine, aircraft type, and airline by individual plume sampling.

    PubMed

    Carslaw, David C; Ropkins, Karl; Laxen, Duncan; Moorcroft, Stephen; Marner, Ben; Williams, Martin L

    2008-03-15

    Nitrogen oxides (NOx) concentrations were measured in individual plumes from aircraft departing on the northern runway at Heathrow Airport in west London. Over a period of four weeks 5618 individual plumes were sampled by a chemiluminescence monitor located 180 m from the runway. Results were processed and matched with detailed aircraft movement and aircraft engine data using chromatographic techniques. Peak concentrations associated with 29 commonly used engines were calculated and found to have a good relationship with N0x emissions taken from the International Civil Aviation Organization (ICAO) databank. However, it is found that engines with higher reported NOx emissions result in proportionately lower NOx concentrations than engines with lower emissions. We show that it is likely that aircraft operational factors such as takeoff weight and aircraftthrust setting have a measurable and important effect on concentrations of N0x. For example, NOx concentrations can differ by up to 41% for aircraft using the same airframe and engine type, while those due to the same engine type in different airframes can differ by 28%. These differences are as great as, if not greater than, the reported differences in NOx emissions between different engine manufacturers for engines used on the same airframe. PMID:18409606

  11. Dust emissions created by low-level rotary-winged aircraft flight over desert surfaces

    NASA Astrophysics Data System (ADS)

    Gillies, J. A.; Etyemezian, V.; Kuhns, H.; McAlpine, J. D.; King, J.; Uppapalli, S.; Nikolich, G.; Engelbrecht, J.

    2010-03-01

    There is a dearth of information on dust emissions from sources that are unique to U.S. Department of Defense testing and training activities. Dust emissions of PM 10 and PM 2.5 from low-level rotary-winged aircraft travelling (rotor-blade ≈7 m above ground level) over two types of desert surfaces (i.e., relatively undisturbed desert pavement and disturbed desert soil surface) were characterized at the Yuma Proving Ground (Yuma, AZ) in May 2007. Fugitive emissions are created by the shear stress of the outflow of high speed air created by the rotor-blade. The strength of the emissions was observed to scale primarily as a function of forward travel speed of the aircraft. Speed affects dust emissions in two ways: 1) as speed increases, peak shear stress at the soil surface was observed to decline proportionally, and 2) as the helicopter's forward speed increases its residence time over any location on the surface diminishes, so the time the downward rotor-generated flow is acting upon that surface must also decrease. The state of the surface over which the travel occurs also affects the scale of the emissions. The disturbed desert test surface produced approximately an order of magnitude greater emission than the undisturbed surface. Based on the measured emission rates for the test aircraft and the established scaling relationships, a rotary-winged aircraft similar to the test aircraft traveling 30 km h -1 over the disturbed surface would need to travel 4 km to produce emissions equivalent to one kilometer of travel by a light wheeled military vehicle also traveling at 30 km h -1 on an unpaved road. As rotary-winged aircraft activity is substantially less than that of off-road vehicle military testing and training activities it is likely that this source is small compared to emissions created by ground-based vehicle movements.

  12. Evaluation of on-road vehicle CO and NOx National Emission Inventories using an urban-scale source-oriented air quality model

    NASA Astrophysics Data System (ADS)

    Kota, Sri Harsha; Zhang, Hongliang; Chen, Gang; Schade, Gunnar W.; Ying, Qi

    2014-03-01

    The MOBILE6.2 model was replaced by the Motor Vehicle Emission Simulator (MOVES) in 2012 as an official tool recommended by the United States Environmental Protection Agency (US EPA) to predict vehicular pollutant emission factors. In this study, on-road vehicle emission inventories of CO and NOx for Southeast Texas generated by MOVES and MOBILE6.2 in two versions of the 2005 National Emission Inventory (NEI) were studied by comparing predicted CO and NOx using the EPA's Community Multiscale Air Quality (CMAQ) Model incorporated with a source-oriented gas phase chemical mechanism with measurements made at six urban and industrial sites in Southeast Texas. The source tracing technique allows direct determination of contributions of on-road vehicles to overall CO and NOx concentrations and identification of ambient concentration measurements which are mostly impacted by vehicle emissions. By grouping the fractional bias (FB) values of the hourly predictions based on vehicle contributions to total CO or NOx concentrations, clear trends in the FB were observed, indicating systematic biases in the emission inventory for these species. Data points dominated by vehicle emissions suggest that surface CO concentrations due to vehicle exhaust are significantly over-estimated by a factor of 2 using either MOVES or MOBILE6.2. NOx concentrations are overestimated by approximately 20-35% and 70% by using the MOBILE6.2 and MOVES emissions, respectively. Emission scaling runs show that a domain-wide reduction of MOBILE6.2 CO emissions by 60% and NOx emissions by 15-25% leads to better model performance of exhaust CO and NOx concentrations in the current study.

  13. Emissions of NOx, SO2, CO, and HCHO from commercial marine shipping during Texas Air Quality Study (TexAQS) 2006

    NASA Astrophysics Data System (ADS)

    Williams, E. J.; Lerner, B. M.; Murphy, P. C.; Herndon, S. C.; Zahniser, M. S.

    2009-11-01

    We report measurements of NOx, SO2, CO, and HCHO mass-based emission factors from more than 200 commercial vessel encounters in the Gulf of Mexico and the Houston-Galveston region of Texas during August and September, 2006. For underway ships, bulk freight carriers have the highest average NOx emissions at ˜87 g NOx (kg fuel)-1, followed by tanker ships at ˜79 g NOx (kg fuel)-1, while container carriers, passenger ships, and tugs all emit an average of about ˜60 g NOx (kg fuel)-1. Emission of NOx from stationary vessels was lower, except for container ships and tugs, and likely reflects use of medium-speed diesel engines. Overall, our mean NOx emission factors are 10-15% lower than published data. Average emission of SO2 was lower for passenger ships and tugs and tows (6-7 g SO2 (kg fuel)-1) than for larger cargo vessels (20-30 g SO2 (kg fuel)-1). Our data for large cargo ships in this region indicate an average residual fuel sulfur content of ˜1.4% which is a factor of two lower than the global average of 2.7%. Emission of CO was low for all categories (7-16 g CO (kg fuel)-1), although our mean overall CO emission factor is about 10% higher than published data. Emission of HCHO was less than 5% that of CO. Despite considerable variability, no functional relationships, such as emissions changes with engine speed or load, could be discerned. Comparison of emission factors from ships to those from other sources suggests ship emissions in this region cannot be ignored.

  14. Impact of passenger car NOx emissions and NO2 fractions on urban NO2 pollution - Scenario analysis for the city of Antwerp, Belgium

    NASA Astrophysics Data System (ADS)

    Degraeuwe, Bart; Thunis, Philippe; Clappier, Alain; Weiss, Martin; Lefebvre, Wouter; Janssen, Stijn; Vranckx, Stijn

    2016-02-01

    The annual NO2 concentrations in many European cities exceed the established air quality standard. This situation is mainly caused by Diesel cars whose NOx emissions are higher on the road than during type approval in the laboratory. Moreover, the fraction of NO2 in the NOx emissions of modern diesel cars appears to have increased as compared to previous models. In this paper, we assess 1) to which level the distance-specific NOx emissions of Diesel cars should be reduced to meet established air quality standards and 2) if it would be useful to introduce a complementary NO2 emissions limit. We develop a NO2 pollution model that accounts in an analysis of 9 emission scenarios for changes in both, the urban background NO2 concentrations and the local NO2 emissions at street level. We apply this model to the city of Antwerp, Belgium. The results suggest that a reduction in NOx emissions decreases the regional and urban NO2 background concentration; high NO2 fractions increase the ambient NO2 concentrations only in close spatial proximity to the emission source. In a busy access road to the city centre, the average NO2 concentration can be reduced by 23% if Diesel cars emitted 0.35 g NOx/km instead of the current 0.62 g NOx/km. Reductions of 45% are possible if the NOX emissions of Diesel cars decreased to the level of gasoline cars (0.03 g NOx/km). Our findings suggest that the Real-Driving Emissions (RDE) test procedure can solve the problem of NO2 exceedances in cities if it reduced the on-road NOx emissions of diesel cars to the permissible limit of 0.08 g/km. The implementation of a complementary NO2 emissions limit may then become superfluous. If Diesel cars continue to exceed by several factors their NOx emissions limit on the road, a shift of the vehicle fleet to gasoline cars may be necessary to solve persisting air quality problems.

  15. Effect of B20 and Low Aromatic Diesel on Transit Bus NOx Emissions Over Driving Cycles with a Range of Kinetic Intensity

    SciTech Connect

    Lammert, M. P.; McCormick, R. L.; Sindler, P.; Williams, A.

    2012-10-01

    Oxides of nitrogen (NOx) emissions for transit buses for up to five different fuels and three standard transit duty cycles were compared to establish whether there is a real-world biodiesel NOx increase for transit bus duty cycles and engine calibrations. Six buses representing the majority of the current national transit fleet and including hybrid and selective catalyst reduction systems were tested on a heavy-duty chassis dynamometer with certification diesel, certification B20 blend, low aromatic (California Air Resources Board) diesel, low aromatic B20 blend, and B100 fuels over the Manhattan, Orange County and UDDS test cycles. Engine emissions certification level had the dominant effect on NOx; kinetic intensity was the secondary driving factor. The biodiesel effect on NOx emissions was not statistically significant for most buses and duty cycles for blends with certification diesel, except for a 2008 model year bus. CARB fuel had many more instances of a statistically significant effect of reducing NOx. SCR systems proved effective at reducing NOx to near the detection limit on all duty cycles and fuels, including B100. While offering a fuel economy benefit, a hybrid system significantly increased NOx emissions over a same year bus with a conventional drivetrain and the same engine.

  16. Estimation of NOx emissions from vegetation fires based on the empirical relationship between satellite-derived tropospheric NO2 and fire radiative power

    NASA Astrophysics Data System (ADS)

    Schreier, S. F.; Richter, A.; Kaiser, J. W.; Burrows, J. P.

    2013-12-01

    Vegetation fires release large quantities of nitrogen oxides (NOx) into the atmosphere. These relatively short-lived reactive gases play key roles in atmospheric chemistry, air pollution, and climate. The traditional estimation of global NOx emissions from vegetation fires is based on the bottom-up approach by aggregating various local statistics. These statistics are based on parameters such as burned area, available fuel load, combustion completeness, and emission factors, which are derived from satellite measurements, laboratory experiments, and biogeochemical models. However, despite the progress achieved in deriving these parameters, there still exist large uncertainties for each parameter. The top-down estimation of NOx emissions from satellite measurements has the advantage of having a much higher spatio-temporal resolution. On the other hand, the conversion of the column number density into production rates of NOx and the partitioning between different NOx sources still remains challenging. In this study, we present a simple statistical approach for the estimation of production rates of NOx from fire by using the empirical relationship between satellite-derived tropospheric NO2 columns (from the GOME-2 instrument on board MetOp-A) and fire radiative power (from the MODIS instrument on board Terra). We show that the conversion of the column number density into production rates of NOx from fire is in good agreement with existing emission inventories. Therefore, we argue that this method allows for the adequate partitioning between biomass burning and other sources of NOx. The computation of Fire Emission Rates (FERs) of NOx for different land cover types indicates considerable differences among both the selected biomes and regions. The obtained FERs of NOx in combination with quantitative information about the diurnal cycle of the fire intensity are then applied for the estimation of NOx emissions from vegetation fires. A comparison of the achieved results

  17. Simulating the Contributions from Aircraft Emissions to Organic Aerosols Using the Volatility Basis Set

    NASA Astrophysics Data System (ADS)

    Woody, M. C.; Arunachalam, S.; Binkowski, F.; West, J.; Jathar, S.; Robinson, A. L.

    2012-12-01

    Regional air quality studies aimed at quantifying the impacts of aviation emissions to PM2.5 have generally predicted relatively low contributions from organic aerosols. However, recent sampling and smog chamber experiments have suggested that organic aerosols comprise a significant fraction of total PM2.5 formed from aircraft emissions. In this study, the results of aircraft-specific sampling and smog chamber experiments are incorporated into a regional chemical transport model with the volatility basis set and used to predict organic aerosol contributions from aircraft emissions. Contributions of aircraft emissions to primary organic aerosols (POA), secondary organic aerosols (SOA) formed from traditional precursors (e.g. aromatics and long-chain alkanes), and non-traditional SOA formed from unidentified precursors previously unaccounted for in air quality models are modeled using the volatility basis set approach in CMAQ v4.7.1. The model includes oxidation reactions of traditional SOA (both biogenic and anthropogenic) and non-traditional SOA precursors (specific to aircraft emissions) with OH to produce products of lower volatility. Non-traditional SOA yields and precursor emission estimates for idle and non-idle aircraft activities are based on sampling and smog chamber experiments. This model predicts the organic aerosol and total PM2.5 concentrations formed from aircraft emissions due to landing and takeoff activities at the Hartsfield-Jackson International Airport in Atlanta during January and July, 2002. Overall model results are compared against monitoring data in the region to determine the impacts of using the volatility basis set on CMAQ model performance.

  18. Estimates of global biomass burning emissions for reactive greenhouse gases (CO, NMHCs, and NOx) and CO2

    NASA Astrophysics Data System (ADS)

    Jain, Atul K.; Tao, Zhining; Yang, Xiaojuan; Gillespie, Conor

    2006-03-01

    Open fire biomass burning and domestic biofuel burning (e.g., cooking, heating, and charcoal making) algorithms have been incorporated into a terrestrial ecosystem model to estimate CO2 and key reactive GHGs (CO, NOx, and NMHCs) emissions for the year 2000. The emissions are calculated over the globe at a 0.5° × 0.5° spatial resolution using tree density imagery, and two separate sets of data each for global area burned and land clearing for croplands, along with biofuel consumption rate data. The estimated global and annual total dry matter (DM) burned due to open fire biomass burning ranges between 5221 and 7346 Tg DM/yr, whereas the resultant emissions ranges are 6564-9093 Tg CO2/yr, 438-568 Tg CO/yr, 11-16 Tg NOx/yr (as NO), and 29-40 Tg NMHCs/yr. The results indicate that land use changes for cropland is one of the major sources of biomass burning, which amounts to 25-27% (CO2), 25 -28% (CO), 20-23% (NO), and 28-30% (NMHCs) of the total open fire biomass burning emissions of these gases. Estimated DM burned associated with domestic biofuel burning is 3,114 Tg DM/yr, and resultant emissions are 4825 Tg CO2/yr, 243 Tg CO/yr, 3 Tg NOx/yr, and 23 Tg NMHCs/yr. Total emissions from biomass burning are highest in tropical regions (Asia, America, and Africa), where we identify important contributions from primary forest cutting for croplands and domestic biofuel burning.

  19. 77 FR 76842 - Exhaust Emissions Standards for New Aircraft Gas Turbine Engines and Identification Plate for...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-12-31

    ... action revises the standards for oxides of nitrogen and test procedures for exhaust emissions based on... Environmental Protection Agency (EPA) proposed new aircraft engine emission standards for oxides of nitrogen (NO... turbojet engines with rated thrusts greater than 26.7 kilonewtons (kN) (76 FR 45012, July 27, 2011)....

  20. Jet aircraft engine emissions database development: 1992 military, charter, and nonscheduled traffic

    NASA Technical Reports Server (NTRS)

    Metwally, Munir

    1995-01-01

    Studies relating to environmental emissions database for the military, charter, and non-scheduled traffic for the year 1992 were conducted by McDonnell Douglas Aerospace Transport Aircraft. The report also includes a comparison with a previous emission database for year 1990. Discussions of the methodology used in formulating these databases are provided.

  1. Towards the Tracing of NOx Sources by Isotopic Signature

    NASA Astrophysics Data System (ADS)

    Fibiger, D. L.; Hastings, M. G.

    2012-12-01

    Atmospheric NOx (NO and NO2) plays a significant role in both air quality (through the production of tropospheric ozone) and reactive N deposition (through production and deposition of nitric acid). NOx is released by both anthropogenic (fossil fuel combustion, biomass burning, aircraft emissions) and natural (lightning, biogenic production in soils, natural fires) sources. Global concentrations of NOx are rising because of increased anthropogenic emissions, while natural source emissions also contribute significantly to the global NOx burden. The contributions of both natural and anthropogenic sources and their considerable variability in space and time make it difficult to attribute local NOx concentrations and deposited nitric acid to a particular source or sources. Further, global atmospheric models typically use comparisons with nitric acid deposition to verify simulations that include assumptions about source magnitude and variability, chemistry, and transport. Several recent studies suggest that variability in the nitrogen isotopic composition (δ15N) of nitric acid is related to variability in the isotopic signatures of NOx emission sources. Nevertheless, considerable uncertainty remains regarding the isotopic composition of most NOx sources. We have refined a method in the laboratory that efficiently collects NOx from air, which is important for isotopic analysis, as incomplete capture can fractionate the sample NOx. The method (modeled after Margeson et al., 1984) uses a 0.5M NaOH/0.25M KMnO4 solution in a gas-washing bottle to scrub NOx from the air stream. Efficiency verification was conducted using a tank of known concentration under various conditions, including varying total flow rate, NOx concentration (by mixing with N2), solution volume and NaOH concentration. Efficient collection was achieved under a wide range of conditions. In addition to discussion of methodological details, strengths and weaknesses, our presentation will include measurements

  2. Aircraft

    DOEpatents

    Hibbs, B.D.; Lissaman, P.B.S.; Morgan, W.R.; Radkey, R.L.

    1998-09-22

    This disclosure provides a solar rechargeable aircraft that is inexpensive to produce, is steerable, and can remain airborne almost indefinitely. The preferred aircraft is a span-loaded flying wing, having no fuselage or rudder. Travelling at relatively slow speeds, and having a two-hundred foot wingspan that mounts photovoltaic cells on most all of the wing`s top surface, the aircraft uses only differential thrust of its eight propellers to turn. Each of five sections of the wing has one or more engines and photovoltaic arrays, and produces its own lift independent of the other sections, to avoid loading them. Five two-sided photovoltaic arrays, in all, are mounted on the wing, and receive photovoltaic energy both incident on top of the wing, and which is incident also from below, through a bottom, transparent surface. The aircraft is capable of a top speed of about ninety miles per hour, which enables the aircraft to attain and can continuously maintain altitudes of up to sixty-five thousand feet. Regenerative fuel cells in the wing store excess electricity for use at night, such that the aircraft can sustain its elevation indefinitely. A main spar of the wing doubles as a pressure vessel that houses hydrogen and oxygen gases for use in the regenerative fuel cell. The aircraft has a wide variety of applications, which include weather monitoring and atmospheric testing, communications, surveillance, and other applications as well. 31 figs.

  3. Aircraft

    DOEpatents

    Hibbs, Bart D.; Lissaman, Peter B. S.; Morgan, Walter R.; Radkey, Robert L.

    1998-01-01

    This disclosure provides a solar rechargeable aircraft that is inexpensive to produce, is steerable, and can remain airborne almost indefinitely. The preferred aircraft is a span-loaded flying wing, having no fuselage or rudder. Travelling at relatively slow speeds, and having a two-hundred foot wingspan that mounts photovoltaic cells on most all of the wing's top surface, the aircraft uses only differential thrust of its eight propellers to turn. Each of five sections of the wing has one or more engines and photovoltaic arrays, and produces its own lift independent of the other sections, to avoid loading them. Five two-sided photovoltaic arrays, in all, are mounted on the wing, and receive photovoltaic energy both incident on top of the wing, and which is incident also from below, through a bottom, transparent surface. The aircraft is capable of a top speed of about ninety miles per hour, which enables the aircraft to attain and can continuously maintain altitudes of up to sixty-five thousand feet. Regenerative fuel cells in the wing store excess electricity for use at night, such that the aircraft can sustain its elevation indefinitely. A main spar of the wing doubles as a pressure vessel that houses hydrogen and oxygen gasses for use in the regenerative fuel cell. The aircraft has a wide variety of applications, which include weather monitoring and atmospheric testing, communications, surveillance, and other applications as well.

  4. Development of EPA aircraft piston engine emission standards. [for air quality

    NASA Technical Reports Server (NTRS)

    Houtman, W.

    1976-01-01

    Piston engine light aircraft are significant sources of carbon monoxide in the vicinity of high activity general aviation airports. Substantial reductions in carbon monoxide were achieved by fuel mixture leaning using improved fuel management systems. The air quality impact of the hydrocarbon and oxides of nitrogen emissions from piston engine light aircraft were insufficient to justify the design constraints being confronted in present control system developments.

  5. The use of rice hulls for sustainable control of NOx emissions in deep space missions

    NASA Technical Reports Server (NTRS)

    Xu, X. H.; Shi, Y.; Kwak, D.; Chang, S. G.; Fisher, J. W.; Pisharody, S.; Moran, M. J.; Wignarajah, K.

    2003-01-01

    The use of the activated carbon produced from rice hulls to control NOx emissions for future deep space missions has been demonstrated. The optimal carbonization temperature range was found to be between 600 and 750 degrees C. A burnoff of 61.8% was found at 700 degrees C in pyrolysis and 750 degrees C in activation. The BET surface area of the activated carbon from rice hulls was determined to be 172 m2/g when prepared at 700 degrees C. The presence of oxygen in flue gas is essential for effective adsorption of NO by activated carbon. On the contrary, water vapor inhibits the adsorption efficiency of NO. Consequently, water vapor in flue gas should be removed by drying agents before adsorption to ensure high NO adsorption efficiency. All of the NO in the flue gas was removed for more than 1.5 h when 10% oxygen was present and the ratio of the carbon weight to the flue gas flow rate (W/F) was 15.4 g min/L. Reduction of the adsorbed NO to form N2 could be effectively accomplished under anaerobic conditions at 550 degrees C. The adsorption capacity of NO on the activated carbon was found to be 5.02 mg of NO/g of carbon. The loss of carbon mass was determined to be about 0.16% of the activated carbon per cycle of regeneration if the regeneration occurred when the NO in the flue gas after the carbon bed reached 4.8 ppm, the space maximum allowable concentration. The reduction of the adsorbed NO also regenerated the activated carbon, and the regenerated activated carbon exhibited an improved NO adsorption efficiency.

  6. Determination and Applications of Environmental Costs at Different Sized Airports: Aircraft Noise and Engine Emissions

    NASA Technical Reports Server (NTRS)

    Lu, Cherie; Lierens, Abigail

    2003-01-01

    With the increasing trend of charging for externalities and the aim of encouraging the sustainable development of the air transport industry, there is a need to evaluate the social costs of these undesirable side effects, mainly aircraft noise and engine emissions, for different airports. The aircraft noise and engine emissions social costs are calculated in monetary terms for five different airports, ranging from hub airports to small regional airports. The number of residences within different levels of airport noise contours and the aircraft noise classifications are the main determinants for accessing aircraft noise social costs. Whist, based on the damages of different engine pollutants on the human health, vegetation, materials, aquatic ecosystem and climate, the aircraft engine emissions social costs vary from engine types to aircraft categories. The results indicate that the relationship appears to be curvilinear between environmental costs and the traffic volume of an airport. The results and methodology of environmental cost calculation could input for to the proposed European wide harmonized noise charges as well as the social cost benefit analysis of airports.

  7. Ships going slow in reducing their NOx emissions: changes in 2005-2012 ship exhaust inferred from satellite measurements over Europe

    NASA Astrophysics Data System (ADS)

    Folkert Boersma, K.; Vinken, Geert C. M.; Tournadre, Jean

    2015-07-01

    We address the lack of temporal information on ship emissions, and report on rapid short-term variations of satellite-derived ship NOx emissions between 2005 and 2012 over European seas. Our inversion is based on OMI observed tropospheric NO2 columns and GEOS-Chem simulations. Average European ship NOx emissions increased by ˜15% from 2005 to 2008. This increase was followed by a reduction of ˜12% in 2009, a direct result of the global economic downturn in 2008-2009, and steady emissions from 2009 to 2012. Observations of ship passages through the Suez Canal and satellite altimeter derived ship densities suggests that ships in the Mediterranean Sea have reduced their speed by more than 30% since 2008. This reduction in ship speed is accompanied by a persistent 45% reduction of average, per ship NOx emission factors. Our results indicate that the practice of ‘slow steaming’, i.e. the lowering of vessel speed to reduce fuel consumption, has indeed been implemented since 2008, and can be detected from space. In spite of the implementation of slow steaming, one in seven of all NOx molecules emitted in Europe in 2012 originated from the shipping sector, up from one in nine in 2005. The growing share of the shipping contributions to the overall European NOx emissions suggests a need for the shipping sector to implement additional measures to reduce pollutant emissions at rates that are achieved by the road transport and energy producing sectors in Europe.

  8. Aircraft-Based Measurements of Point Source Methane Emissions in the Barnett Shale Basin.

    PubMed

    Lavoie, Tegan N; Shepson, Paul B; Cambaliza, Maria O L; Stirm, Brian H; Karion, Anna; Sweeney, Colm; Yacovitch, Tara I; Herndon, Scott C; Lan, Xin; Lyon, David

    2015-07-01

    We report measurements of methane (CH4) emission rates observed at eight different high-emitting point sources in the Barnett Shale, Texas, using aircraft-based methods performed as part of the Barnett Coordinated Campaign. We quantified CH4 emission rates from four gas processing plants, one compressor station, and three landfills during five flights conducted in October 2013. Results are compared to other aircraft- and surface-based measurements of the same facilities, and to estimates based on a national study of gathering and processing facilities emissions and 2013 annual average emissions reported to the U.S. EPA Greenhouse Gas Reporting Program (GHGRP). For the eight sources, CH4 emission measurements from the aircraft-based mass balance approach were a factor of 3.2-5.8 greater than the GHGRP-based estimates. Summed emissions totaled 7022 ± 2000 kg hr(-1), roughly 9% of the entire basin-wide CH4 emissions estimated from regional mass balance flights during the campaign. Emission measurements from five natural gas management facilities were 1.2-4.6 times larger than emissions based on the national study. Results from this study were used to represent "super-emitters" in a newly formulated Barnett Shale Inventory, demonstrating the importance of targeted sampling of "super-emitters" that may be missed by random sampling of a subset of the total.

  9. Recent advances in automotive catalysis for NOx emission control by small-pore microporous materials.

    PubMed

    Beale, A M; Gao, F; Lezcano-Gonzalez, I; Peden, C H F; Szanyi, J

    2015-10-21

    The ever increasing demand to develop highly fuel efficient engines coincides with the need to minimize air pollution originating from the exhaust gases of internal combustion engines. Dramatically improved fuel efficiency can be achieved at air-to-fuel ratios much higher than stoichiometric. In the presence of oxygen in large excess, however, traditional three-way catalysts are unable to reduce NOx. Among the number of lean-NOx reduction technologies, selective catalytic reduction (SCR) of NOx by NH3 over Cu- and Fe-ion exchanged zeolite catalysts has been extensively studied over the past 30+ years. Despite the significant advances in developing a viable practical zeolite-based catalyst for lean NOx reduction, the insufficient hydrothermal stabilities of the zeolite structures considered cast doubts about their real-world applicability. During the past decade renewed interest in zeolite-based lean NOx reduction was spurred by the discovery of the very high activity of Cu-SSZ-13 (and the isostructural Cu-SAPO-34) in the NH3-SCR of NOx. These new, small-pore zeolite-based catalysts not only exhibited very high NOx conversion and N2 selectivity, but also exhibited exceptionally high hydrothermal stability at high temperatures. In this review we summarize the key discoveries of the past ∼5 years that led to the introduction of these catalysts into practical applications. This review first briefly discusses the structure and preparation of the CHA structure-based zeolite catalysts, and then summarizes the key learnings of the rather extensive (but not complete) characterisation work. Then we summarize the key findings of reaction kinetic studies, and provide some mechanistic details emerging from these investigations. At the end of the review we highlight some of the issues that still need to be addressed in automotive exhaust control catalysis.

  10. Recent advances in automotive catalysis for NOx emission control by small-pore microporous materials.

    PubMed

    Beale, A M; Gao, F; Lezcano-Gonzalez, I; Peden, C H F; Szanyi, J

    2015-10-21

    The ever increasing demand to develop highly fuel efficient engines coincides with the need to minimize air pollution originating from the exhaust gases of internal combustion engines. Dramatically improved fuel efficiency can be achieved at air-to-fuel ratios much higher than stoichiometric. In the presence of oxygen in large excess, however, traditional three-way catalysts are unable to reduce NOx. Among the number of lean-NOx reduction technologies, selective catalytic reduction (SCR) of NOx by NH3 over Cu- and Fe-ion exchanged zeolite catalysts has been extensively studied over the past 30+ years. Despite the significant advances in developing a viable practical zeolite-based catalyst for lean NOx reduction, the insufficient hydrothermal stabilities of the zeolite structures considered cast doubts about their real-world applicability. During the past decade renewed interest in zeolite-based lean NOx reduction was spurred by the discovery of the very high activity of Cu-SSZ-13 (and the isostructural Cu-SAPO-34) in the NH3-SCR of NOx. These new, small-pore zeolite-based catalysts not only exhibited very high NOx conversion and N2 selectivity, but also exhibited exceptionally high hydrothermal stability at high temperatures. In this review we summarize the key discoveries of the past ∼5 years that led to the introduction of these catalysts into practical applications. This review first briefly discusses the structure and preparation of the CHA structure-based zeolite catalysts, and then summarizes the key learnings of the rather extensive (but not complete) characterisation work. Then we summarize the key findings of reaction kinetic studies, and provide some mechanistic details emerging from these investigations. At the end of the review we highlight some of the issues that still need to be addressed in automotive exhaust control catalysis. PMID:25913215

  11. Constraints on Anthropogenic NOx Emissions from Geostationary Satellite Observations in a Regional Chemical Data Assimilation System: Evaluation Using Observing System Simulation Experiments

    NASA Astrophysics Data System (ADS)

    Liu, X.; Mizzi, A. P.; Anderson, J. L.; Fung, I. Y.; Cohen, R. C.

    2015-12-01

    Nitrogen oxides (NOx=NO+NO2) control the tropospheric ozone (O3) budget, the abundance of the hydroxyl radical (OH), the formation of organic and inorganic nitrate aerosol, and therefore affect air quality and climate. There remain significant uncertainties in the processes responsible for NOx emissions and subsequent mixing and chemical removal. NOx has a short lifetime and its emissions show high spatiotemporal variability at urban scale. Future geostationary satellite instruments including TEMPO, GEMS and Sentinel-4 will provide hourly time resolution and high spatial resolution observations providing maps of NO2 on diurnal and local scales. Here we determine the extent to which a TEMPO like instrument can quantify urban-scale NOx emissions using a regional data assimilation (DA) system comprising of a chemical transport model, WRF-Chem, a TEMPO simulator and the DART Ensemble Adjustment Kalman Filter. We generate synthetic TEMPO observations by sampling from a nature run on an urban scale domain. We consider the effect of albedo, surface pressure, solar and viewing angles and a priori NO2 profiles on the TEMPO NO2 averaging kernel to achieve scene-dependent instrument sensitivity. We estimate NOx emissions using DART in a state augmentation approach by including NOx emissions in the state vector being analyzed. The ensemble-based statistical estimation of error correlations between concentrations and emissions are critical as they determine the impact of assimilated observations. We describe observing system simulation experiments to explore the optimal approach in the ensemble-based DA system to estimate hourly-resolved NOx emissions from TEMPO NO2 observations. Several case studies will be presented examining the role of covariance localization length and chemical perturbations on the success of the approach.

  12. The observed response of ozone production to the policy-driven decrease of NOx and CO emissions in the Baltimore/Washington area

    NASA Astrophysics Data System (ADS)

    Roberts, S. J.; Hosley, K.; Ren, X.; Wolfe, G.; Dickerson, R. R.; Salawitch, R. J.

    2015-12-01

    The nonlinearity of ozone production has important policy implications as cities continue to decrease NOx, CO, and other important ozone precursors. Observations in the Baltimore/Washington area from 1970 through 2014 demonstrate reductions in NOx and CO emissions due to policy implementation leading to dramatic improvement in air quality. We will analyze the response of the reactivity of ozone, NOx, and VOC to these emission reductions in the Baltimore/Washington area using the University of Washington Chemical Model (UWCMv2.2). This model allows us to evaluate this response using multiple gas-phase chemical mechanisms. With this model, we will also compare and contrast the response of modeled ozone to reduced NOx and CO concentrations across multiple chemical mechanisms.

  13. Forecast of jet engine exhaust emissions for future high altitude commercial aircraft

    NASA Technical Reports Server (NTRS)

    Grobman, J.; Ingebo, R. D.

    1974-01-01

    Projected minimum levels of engine exhaust emissions that may be practicably achievable for future commercial aircraft operating at high altitude cruise conditions are presented. The forecasts are based on: (1) current knowledge of emission characteristics of combustors and augmentors; (2) the current status of combustion research in emission reduction technology; (3) predictable trends in combustion systems and operating conditions as required for projected engine designs that are candidates for advanced subsonic or supersonic commercial aircraft. Results are presented for cruise conditions in terms of an emission index, g pollutant/kg fuel. Two sets of engine exhaust emission predictions are presented: the first, based on an independent NASA study and the second, based on the consensus of an ad hoc committee composed of industry, university, and government representatives. The consensus forecasts are in general agreement with the NASA forecasts.

  14. Reduction on NOx emissions on urban areas by changing specific vehicle fleets: effects on NO2 and O3 concentration

    NASA Astrophysics Data System (ADS)

    Goncalves, M.; Jimenez, P.; Baldasano, J.

    2007-12-01

    The largest amount of NOx emissions in urban areas comes from on-road traffic, which is the largest contributor to urban air pollution (Colvile et al., 2001). Currently different strategies are being tested in order to reduce its effects; many of them oriented to the reduction of the unitary vehicles emissions, by alternative fuels use (such as biofuels, natural gas or hydrogen) or introduction of new technologies (such as hybrid electric vehicles or fuel cells). Atmospheric modelling permits to predict their consequences on tropospheric chemistry (Vautard et al., 2007). Hence, this work assesses the changes on NO2 and O3 concentrations when substituting a 10 per cent of the urban private cars fleets by petrol hybrid electric cars (HEC) or by natural gas cars (NGC) in Madrid and Barcelona urban areas (Spain). These two cities are selected in order to highlight the different patterns of pollutants transport (inland vs. coastal city) and the different responses to emissions reductions. The results focus on a typical summertime episode of air pollution, by means of the Eulerian air quality model ARW- WRF/HERMES/CMAQ, applied with high resolution (1-hr, 1km2) since of the complexity of both areas under study. The detailed emissions scenarios are implemented in the HERMES traffic emissions module, based on the Copert III-EEA/EMEP-CORINAIR (Nztiachristos and Samaras, 2000) methodology. The HEC introduction reduces NOx emissions from on-road traffic in a 10.8 per cent and 8.2 per cent; and the NGC introduction in a 10.3 per cent and 7.8 per cent, for Madrid and Barcelona areas, respectively. The scenarios also affect the NMVOCs reduction (ranging from -3.1 to -6.9 per cent), influencing the tropospheric photochemistry through the NOx/NMVOCs ratio. The abatement of the NO photooxidation but also to the reduction on primary NO2 involves a decrease on NO2 levels centred on urban areas. For example, the NO2 24-hr average concentration in downtown areas reduces up to 8 per

  15. NOx, FINE PARTICLE AND TOXIC METAL EMISSIONS FROM THE COMBUSTION OF SEWAGE SLUDGE/COAL MIXTURES: A SYSTEMATIC ASSESSMENT

    SciTech Connect

    Jost O.L. Wendt

    2003-01-31

    This research project focuses on pollutants from the combustion of mixtures of dried municipal sewage sludge (MSS) and coal. The objective is to determine the relationship between (1) fraction sludge in the sludge/coal mixture, and (2) combustion conditions on (a) NOx concentrations in the exhaust, (b) the size segregated fine and ultra-fine particle composition in the exhaust, and (c) the partitioning of toxic metals between vapor and condenses phases, within the process. The proposed study will be conducted in concert with an existing ongoing research on toxic metal partitioning mechanisms for very well characterized pulverized coals alone. Both high NOx and low NOx combustion conditions will be investigated (unstaged and staged combustion). Tradeoffs between CO{sub 2} control, NO{sub x} control, and inorganic fine particle and toxic metal emissions will be determined. Previous research results have demonstrated that the inhalation of coal/MSS ash particles cause an increase in lung permeability than coal ash particles alone. Elemental analysis of the coal/MSS ash particles showed that Zn was more abundant in these ash particles than the ash particles of coal ash alone.

  16. NOx, FINE PARTICLE AND TOXIC METAL EMISSIONS FROM THE COMBUSTION OF SEWAGE SLUDGE/COAL MIXTURES: A SYSTEMATIC ASSESSMENT

    SciTech Connect

    Jost O.L. Wendt

    2001-08-01

    This research project focuses on pollutants from the combustion of mixtures of dried municipal sewage sludge (MSS) and coal. The objective is to determine the relationship between (1) fraction sludge in the sludge/coal mixture, and (2) combustion conditions on (a) NOx concentrations in the exhaust, (b) the size segregated fine and ultra-fine particle composition in the exhaust, and (c) the partitioning of toxic metals between vapor and condenses phases, within the process. To this end work is progress using an existing 17kW downflow laboratory combustor, available with coal and sludge feed capabilities. The proposed study will be conducted in concert with an existing ongoing research on toxic metal partitioning mechanisms for very well characterized pulverized coals alone. Both high NOx and low NOx combustion conditions will be investigated (unstaged and staged combustion). The proposed work uses existing analytical and experimental facilities and draws on 20 years of research on NO{sub x} and fine particles that has been funded by DOE in this laboratory. Four barrels of dried sewage sludge are currently in the laboratory. Insofar as possible pertinent mechanisms will be elucidated. Tradeoffs between CO{sub 2} control, NO{sub x} control, and inorganic fine particle and toxic metal emissions will be determined. For the Third Quarter of this project we present our data on trace metal partitioning obtained from combustion of MSS and Gas, MSS and Coal and Coal and Gas alone.

  17. Limitations of ozone data assimilation with adjustment of NOx emissions: mixed effects on NO2 forecast over Beijing and surrounding areas

    NASA Astrophysics Data System (ADS)

    Tang, X.; Zhu, J.; Wang, Z. F.; Gbaguidi, A.; Lin, C. Y.; Xin, J. Y.; Song, T.; Hu, B.

    2015-12-01

    This study investigates a cross-variable ozone data assimilation (DA) method based on an ensemble Kalman filter (EnKF) that has been validated as an efficient approach for improving ozone forecasts. The main purpose is to delve into the impacts of the cross-variable adjustment of nitrogen oxides (NOx) emissions on the nitrogen dioxide (NO2) forecasts over Beijing and surrounding regions during the 2008 Beijing Olympic Games. A mixed effect on the NO2 forecasts was observed during the application of the cross-variable assimilation approach in real-data assimilation (RDA) experiments. The method improved the NO2 forecast over almost half of the urban sites with reductions of the root mean square errors (RMSEs) by 15-36 % in contrast to big increases of the RMSEs over other urban stations by 56-239 %. Over the urban stations with negative DA impacts, improvement of the NO2 forecasts with 7 % reduction of the RMSEs was noticed during the night and the morning vs. significant deterioration of the forecasts during daytime with 190 % increase of the RMSEs, suggesting the negative DA impacts mainly occurred during daytime. Ideal data assimilation (IDA) experiments with a box model and the same cross-variable assimilation method, as a further investigation, confirmed the mixed effects found in the RDA experiments. An improvement of the NOx emission estimation was obtained from the cross-variable assimilation under relatively small errors in the prior estimation of NOx emissions during daytime, while deterioration of the NOx emission estimation was found under large biases in the prior estimation of NOx emissions during daytime. However, the cross-variable assimilation improved the NOx emission estimations during the night and the morning even with large biases in the prior estimations. The mixed effects observed in the cross-variable assimilation, i.e., positive DA impacts on NO2 forecast over some urban sites, negative DA impacts over the other urban sites and weak DA

  18. NOx, FINE PARTICLE AND TOXIC METAL EMISSIONS FROM THE COMBUSTION OF SEWAGE SLUDGE/COAL MIXTURES: A SYSTEMATIC ASSESSMENT

    SciTech Connect

    Jost O.L. Wendt

    2002-08-15

    This research project focuses on pollutants from the combustion of mixtures of dried municipal sewage sludge (MSS) and coal. The objective is to determine the relationship between (1) fraction sludge in the sludge/coal mixture, and (2) combustion conditions on (a) NOx concentrations in the exhaust, (b) the size segregated fine and ultra-fine particle composition in the exhaust, and (c) the partitioning of toxic metals between vapor and condenses phases, within the process. The proposed study will be conducted in concert with an existing ongoing research on toxic metal partitioning mechanisms for very well characterized pulverized coals alone. Both high NOx and low NOx combustion conditions will be investigated (unstaged and staged combustion). Tradeoffs between CO2 control, NOx control, and inorganic fine particle and toxic metal emissions will be determined. Previous research has yielded data on trace metal partitioning for MSS by itself, with natural gas assist, for coal plus MSS combustion together, and for coal alone. We have re-evaluated the inhalation health effects of ash aerosol from combustion of MSS both by itself and also together with coal. We have concluded that ash from the co-combustion of MSS and coal is very much worse from an inhalation health point of view, than ash from either MSS by itself or coal by itself. The reason is that ZnO is not the ''bad actor'' as had been suspected before, but the culprit is, rather, sulfated Zn. The MSS supplies the Zn and the coal supplies the sulfur, and so it is the combination of coal and MSS that makes that process environmentally bad. If MSS is to be burned, it should be burned without coal, in the absence of sulfur.

  19. Energy and emissions saving potential of additive manufacturing: the case of lightweight aircraft components

    SciTech Connect

    Huang, Runze; Riddle, Matthew; Graziano, Diane; Warren, Joshua; Das, Sujit; Nimbalkar, Sachin; Cresko, Joe; Masanet, Eric

    2015-05-08

    Additive manufacturing (AM) holds great potential for improving materials efficiency, reducing life-cycle impacts, and enabling greater engineering functionality compared to conventional manufacturing (CM) processes. For these reasons, AM has been adopted by a growing number of aircraft component manufacturers to achieve more lightweight, cost-effective designs. This study estimates the net changes in life-cycle primary energy and greenhouse gas emissions associated with AM technologies for lightweight metallic aircraft components through the year 2050, to shed light on the environmental benefits of a shift from CM to AM processes in the U.S. aircraft industry. A systems modeling framework is presented, with integrates engineering criteria, life-cycle environmental data, and aircraft fleet stock and fuel use models under different AM adoption scenarios. Estimated fleetwide life-cycle primary energy savings in a rapid adoption scenario reach 70-174 million GJ/year in 2050, with cumulative savings of 1.2-2.8 billion GJ. Associated cumulative emission reduction potentials of CO2e were estimated at 92.8-217.4 million metric tons. About 95% of the savings is attributed to airplane fuel consumption reductions due to lightweighting. In addition, about 4050 tons aluminum, 7600 tons titanium and 8100 tons of nickel alloys could be saved per year in 2050. The results indicate a significant role of AM technologies in helping society meet its long-term energy use and GHG emissions reduction goals, and highlight barriers and opportunities for AM adoption for the aircraft industry.

  20. NO(x) Concentrations in the Upper Troposphere as a Result of Lightning

    NASA Technical Reports Server (NTRS)

    Penner, Joyce E.

    1998-01-01

    Upper tropospheric NO(x) controls, in part, the distribution of ozone in this greenhouse-sensitive region of the atmosphere. Many factors control NO(x) in this region. As a result it is difficult to assess uncertainties in anthropogenic perturbations to NO from aircraft, for example, without understanding the role of the other major NO(x) sources in the upper troposphere. These include in situ sources (lightning, aircraft), convection from the surface (biomass burning, fossil fuels, soils), stratospheric intrusions, and photochemical recycling from HNO3. This work examines the separate contribution to upper tropospheric "primary" NO(x) from each source category and uses two different chemical transport models (CTMS) to represent a range of possible atmospheric transport. Because aircraft emissions are tied to particular pressure altitudes, it is important to understand whether those emissions are placed in the model stratosphere or troposphere and to assess whether the models can adequately differentiate stratospheric air from tropospheric air. We examine these issues by defining a point-by-point "tracer tropopause" in order to differentiate stratosphere from troposphere in terms of NO(x) perturbations. Both models predict similar zonal average peak enhancements of primary NO(x) due to aircraft (approx. = 10-20 parts per trillion by volume (pptv) in both January and July); however, the placement of this peak is primarily in a region of large stratospheric influence in one model and centered near the level evaluated as the tracer tropopause in the second. Below the tracer tropopause, both models show negligible NO(x) derived directly from the stratospheric source. Also, they predict a typically low background of 1 - 20 pptv NO(x) when tropospheric HNO3 is constrained to be 100 pptv of HNO3. The two models calculate large differences in the total background NO(x) (defined as the source of NO(x) from lightning + stratosphere + surface + HNO3) when using identical loss

  1. Characterization of particulate matter and gaseous emissions of a C-130H aircraft.

    PubMed

    Corporan, Edwin; Quick, Adam; DeWitt, Matthew J

    2008-04-01

    The gaseous and nonvolatile particulate matter (PM) emissions of two T56-A-15 turboprop engines of a C-130H aircraft stationed at the 123rd Airlift Wing in the Kentucky Air National Guard were characterized. The emissions campaign supports the Strategic Environmental Research and Development Program (SERDP) project WP-1401 to determine emissions factors from military aircraft. The purpose of the project is to develop a comprehensive emissions measurement program using both conventional and advanced techniques to determine emissions factors of pollutants, and to investigate the spatial and temporal evolutions of the exhaust plumes from fixed and rotating wing military aircraft. Standard practices for the measurement of gaseous emissions from aircraft have been well established; however, there is no certified methodology for the measurement of aircraft PM emissions. In this study, several conventional instruments were used to physically characterize and quantify the PM emissions from the two turboprop engines. Emissions samples were extracted from the engine exit plane and transported to the analytical instrumentation via heated lines. Multiple sampling probes were used to assess the spatial variation and obtain a representative average of the engine emissions. Particle concentrations, size distributions, and mass emissions were measured using commercially available aerosol instruments. Engine smoke numbers were determined using established Society of Automotive Engineers (SAE) practices, and gaseous species were quantified via a Fourier-transform infrared-based gas analyzer. The engines were tested at five power settings, from idle to take-off power, to cover a wide range of operating conditions. Average corrected particle numbers (PNs) of (6.4-14.3) x 10(7) particles per cm3 and PN emission indices (EI) from 3.5 x 10(15) to 10.0 x 10(15) particles per kg-fuel were observed. The highest PN EI were observed for the idle power conditions. The mean particle diameter

  2. Comparative study of automotive, aircraft and biogenic emissions of aldehydes and aromatic compounds.

    PubMed

    Guimarães, C S; Custodio, D; de Oliveira, R C S; Varandas, L S; Arbilla, G

    2010-02-01

    Air samples were collected in three well characterized locations in the city of Rio de Janeiro, Brazil: downtown, the idle and taxi way areas of the national airport and an urban forest, where the main emissions are from vehicular, aircraft and biogenic sources, respectively. Aldehydes and BTEX concentrations show a characteristic profile which may be attributed to the emission sources. Formaldehyde/acetaldehyde ratios, in the early morning, were 1.39, 0.62 and 2.22 in downtown, airport and forest, respectively. Toluene/benzene ratios, for downtown, airport and forest areas, were 1.11, 1.82 and 1.06, respectively. The results show that the impact of the urban emissions on the forest is negligible as well as the impact of aircraft emissions over the urban area.

  3. Recent advances in automotive catalysis for NOx emission control by small-pore microporous materials

    SciTech Connect

    Beale, Andrew M.; Gao, Feng; Lezcano-Gonzalez, Ines; Peden, Charles HF; Szanyi, Janos

    2015-10-05

    The ever increasing demand to develop highly fuel efficient engines coincides with the need to minimize air pollution originating from the exhaust gases of internal combustion engines. Dramatically improved fuel efficiency can be achieved at air-to-fuel ratios much higher than stoichiometric. In the presence of oxygen in large excess, however, traditional three-way catalysts are unable to reduce NOx. Among the number of lean-NOx reduction technologies, selective catalytic reduction (SCR) of NOx by NH3 over Cu- and Fe-ion exchanged zeolite catalysts has been extensively studied over the past 30+ years. Despite the significant advances in developing a viable practical zeolite-based catalyst for lean NOx reduction, the insufficient hydrothermal stabilities of the zeolite structures considered cast doubts about their real-world applicability. During the past decade a renewed interest in zeolite-based lean NOx reduction was spurred by the discovery of the very high activity of Cu-SSZ-13 (and the isostructural Cu-SAPO-34) in the NH3 SCR of NOx. These new, small-pore zeolite-based catalysts not only exhibited very high NOx conversion and N2 selectivity, but also exhibited exceptional high hydrothermal stability at high temperatures. In this review we summarize the key discoveries of the past ~5 years that lead to the introduction of these catalysts into practical application. The review first briefly discusses the structure and preparation of the CHA structure-based zeolite catalysts, and then summarizes the key learnings of the rather extensive (but not complete) characterisation work. Then we summarize the key findings of reaction kinetics studies, and provide some mechanistic details emerging from these investigations. At the end of the review we highlight some of the issues that are still need to be addressed in automotive exhaust control catalysis. Funding A.M.B. and I.L.G. would like to thank EPSRC for funding. F.G., C.H.F.P. and J.Sz. gratefully acknowledge

  4. Evaluation of Methods for the Determination of Black Carbon Emissions from an Aircraft Gas Turbine Engine

    EPA Science Inventory

    The emissions from aircraft gas turbine engines consist of nanometer size black carbon (BC) particles plus gas-phase sulfur and organic compounds which undergo gas-to-particle conversion downstream of the engine as the plume cools and dilutes. In this study, four BC measurement ...

  5. Emission analysis of large number of various passenger electronic devices in aircraft

    NASA Astrophysics Data System (ADS)

    Schüür, Jens; Oppermann, Lukas; Enders, Achim; Nunes, Rafael R.; Oertel, Carl-Henrik

    2016-09-01

    The ever increasing use of PEDs (passenger or portable electronic devices) has put pressure on the aircraft industry as well as operators and administrations to reevaluate established restrictions in PED-use on airplanes in the last years. Any electronic device could cause electromagnetic interference to the electronics of the airplane, especially interference at receiving antennas of sensitive wireless navigation and communication (NAV/COM) systems. This paper presents a measurement campaign in an Airbus A320. 69 test passengers were asked to actively use a combination of about 150 electronic devices including many attached cables, preferentially with a high data load on their buses, to provoke maximal emissions. These emissions were analysed within the cabin as well as at the inputs of aircraft receiving antennas outside of the fuselage. The emissions of the electronic devices as well as the background noise are time-variant, so just comparing only one reference and one transmission measurement is not sufficient. Repeated measurements of both cases lead to a more reliable first analysis. Additional measurements of the absolute received power at the antennas of the airplane allow a good estimation of the real interference potential to aircraft NAV/COM systems. Although there were many measured emissions within the cabin, there were no disturbance signals detectable at the aircraft antennas.

  6. Experimental study on NOx emission and unburnt carbon of a radial biased swirl burner for coal combustion

    SciTech Connect

    Shan Xue; Shi'en Hui; Qulan Zhou; Tongmo Xu

    2009-07-15

    Pilot tests were carried out on a 1 MW thermal pulverized coal fired testing furnace. Symmetrical combustion was implemented by use of two whirl burners with dual air adjustment. The burnout air device was installed in various places at the top of the main burner, which consists of a primary air pipe with a varying cross-section and an impact ring. In the primary air pipe, the air pulverized coal (PC) stream was separated into a whirling stream that was thick inside and thin outside, thus realizing the thin-thick distribution at the burner nozzle in the radial direction. From the comparative combustion tests of three coals with relatively great characteristic differences, Shaanbei Shenhua high rank bituminous coal (SH coal), Shanxi Hejin low rank bituminous coal (HJ coal), and Shanxi Changzhi meager coal (CZ coal), were obtained such test results as the primary air ratio, inner secondary air ratio, outer secondary air ratio, impact of the change of outer secondary air, change of the relative position for the layout of burnout air, change of the swirling intensity of the primary air and secondary air, etc., on the NOx emission, and unburnt carbon content in fly ash (CFA). At the same time, the relationship between the NOx emission and burnout ratio and affecting factors of the corresponding test items on the combustion stability and economic results were also acquired. The results may provide a vital guiding significance to engineering designs and practical applications. According to the experimental results, the influence of each individual parameter on NOx formation and unburned carbon in fly ash agrees well with the existing literature. In this study, the influences of various combinations of these parameters are also examined, thus providing some reference for the design of the radial biased swirl burner, the configuration of the furnace, and the distribution of the air. 23 refs., 14 figs., 2 tabs.

  7. The empirical relationship between satellite-derived tropospheric NO2 and fire radiative power and possible implications for fire emission rates of NOx

    NASA Astrophysics Data System (ADS)

    Schreier, S. F.; Richter, A.; Kaiser, J. W.; Burrows, J. P.

    2014-03-01

    Nitrogen oxides (NOx) play key roles in atmospheric chemistry, air pollution, and climate. While the largest fraction of these reactive gases is released by anthropogenic emission sources, a significant amount can be attributed to vegetation fires. In this study, NO2 from GOME-2 on board EUMETSAT's MetOp-A and OMI on board NASA's Aura as well as fire radiative power (FRP) from the measurements of MODIS on board NASA's Terra and Aqua satellites are used to derive fire emission rates (FERs) of NOx for different types of vegetation using a simple statistical approach. Monthly means of tropospheric NO2 vertical columns (TVC NO2) have been analyzed for their temporal correlation with the monthly means of FRP for five consecutive years from 2007 to 2011 on a horizontal 1° × 1° grid. The strongest correlation is found to be largely confined to tropical and subtropical regions, which account for more than 80% of yearly burned area, on average, globally. In these regions, the seasonal variation of fire intensity, expressed by the FRP data, is similar to the pattern of TVC NO2. As chemical models typically require values for the amount of NOx being released as a function of time, we have converted the retrieved TVC NO2 into production rates of NOx from fire (Pf) by assuming a constant lifetime of NOx. The comparison between Pf and NOx emissions from the Global Fire Emissions Database (GFEDv3.1) over 5 characteristic biomass burning regions in the tropics and subtropics shows good agreement. By separating the monthly means of Pf and FRP according to land cover type, FERs of NOx could be derived for different biomes. The estimated FERs for the dominating types of vegetation burned are lowest for open shrublands and savannas (0.28-1.03 g NOx s-1 MW-1) and highest for croplands and woody savannas (0.82-1.56 g NOx s-1 MW-1). This analysis demonstrates that the strong empirical relationship between TVC NO2 and FRP and the following simplified assumptions are a useful tool for

  8. Simultaneous NOx and hydrocarbon emissions control for lean-burn engines using low-temperature solid oxide fuel cell at open circuit.

    PubMed

    Huang, Ta-Jen; Hsu, Sheng-Hsiang; Wu, Chung-Ying

    2012-02-21

    The high fuel efficiency of lean-burn engines is associated with high temperature and excess oxygen during combustion and thus is associated with high-concentration NO(x) emission. This work reveals that very high concentration of NO(x) in the exhaust can be reduced and hydrocarbons (HCs) can be simultaneously oxidized using a low-temperature solid oxide fuel cell (SOFC). An SOFC unit is constructed with Ni-YSZ as the anode, YSZ as the electrolyte, and La(0.6)Sr(0.4)CoO(3) (LSC)-Ce(0.9)Gd(0.1)O(1.95) as the cathode, with or without adding vanadium to LSC. SOFC operation at 450 °C and open circuit can effectively treat NO(x) over the cathode at a very high concentration in the simulated exhaust. Higher NO(x) concentration up to 5000 ppm can result in a larger NO(x) to N(2) rate. Moreover, a higher oxygen concentration promotes NO conversion. Complete oxidation of HCs can be achieved by adding silver to the LSC current collecting layer. The SOFC-based emissions control system can treat NO(x) and HCs simultaneously, and can be operated without consuming the anode fuel (a reductant) at near the engine exhaust temperature to eliminate the need for reductant refilling and extra heating.

  9. Towards Ideal NOx and CO2 Emission Control Technology for Bio-Oils Combustion Energy System Using a Plasma-Chemical Hybrid Process

    NASA Astrophysics Data System (ADS)

    Okubo, M.; Fujishima, H.; Yamato, Y.; Kuroki, T.; Tanaka, A.; Otsuka, K.

    2013-03-01

    A pilot-scale low-emission boiler system consisting of a bio-fuel boiler and plasma-chemical hybrid NOx removal system is investigated. This system can achieve carbon neutrality because the bio-fuel boiler uses waste vegetable oil as one of the fuels. The plasma-chemical hybrid NOx removal system has two processes: NO oxidation by ozone produced from plasma ozonizers and NO2 removal using a Na2SO3 chemical scrubber. Test demonstrations of the system are carried out for mixed oils (mixture of A-heavy oil and waste vegetable oil). Stable combustion is achieved for the mixed oil (20 - 50% waste vegetable oil). Properties of flue gas—e.g., O2, CO2 and NOx—when firing mixed oils are nearly the same as those when firing heavy oil for an average flue gas flow rate of 1000 Nm3/h. NOx concentrations at the boiler outlet are 90 - 95 ppm. Furthermore, during a 300-min continuous operation when firing 20% mixed oil, NOx removal efficiency of more than 90% (less than 10 ppm NOx emission) is confirmed. In addition, the CO2 reduction when heavy oil is replaced with waste vegetable oil is estimated. The system comparison is described between the plasma-chemical hybrid NOx removal and the conventional technology.

  10. Structure, Stability and Emissions of Lean Direct Injection Combustion, including a Novel Multi-Point LDI System for NOx Reduction

    NASA Astrophysics Data System (ADS)

    Villalva Gomez, Rodrigo

    Experimental research on Lean Direct Injection (LDI) combustors for gas turbine applications is presented. LDI combustion is an alternative to lean premixed combustion which has the potential of equivalent reduction of oxides of nitrogen (NOx) emissions and of peak combustor exit temperatures, but without some drawbacks of premixed combustors, such as flashback and autoignition. Simultaneous observations of the velocity field and reaction zone of an LDI swirl-stabilized combustor with a mixing tube at atmospheric conditions, with the goal of studying the flame stabilization mechanism, are shown. The flame was consistently anchored at the shear layer formed by the high-speed reactants exiting the mixing tube and the low speed recirculation region. Individual image analysis of the location of the tip of the recirculation zone and tip of the reaction region confirmed previously observed trends, but showed that calculation of the distance between these two points for corresponding image pairs yields results no different than when calculated from random image pairs. This most likely indicates a lag in the anchoring of the flame to changes in the recirculation zone, coupled with significant stochastic variation. An alternate LDI approach, multi-point LDI (MLDI), is also tested experimentally. A single large fuel nozzle is replaced by multiple small fuel nozzles to improve atomization and reduce the total volume of the high-temperature, low velocity recirculation zones, reducing NOx formation. The combustor researched employs a novel staged approach to allow good performance across a wide range of conditions by using a combination of nozzle types optimized to various power settings. The combustor has three independent fuel circuits referenced as pilot, intermediate, and outer. Emissions measurements, OH* chemiluminescence imaging, and thermoacoustic instability studies were run in a pressurized combustion facility at pressures from 2.0 to 5.3 bar. Combustor performance

  11. The Evolution of Hono Emissions In An Aircraft Engine Turbine

    NASA Astrophysics Data System (ADS)

    Miake-Lye, R. C.; Yam, C. K.; Han, S.; Lukachko, S. P.; Waitz, I. A.; Wormhoudt, J.; Brown, R. C.; Zhang, J.; Clague, A. R.; Brundish, K. D.

    Measurements and chemical kinetic modeling of NOy species have been performed for exhaust species passing through an aircraft engine turbine. The measurements of NO, NO2, and HONO were made at the exit of a combustor in a sector test rig and at the engine exit of the DERA (QinetiQ) TRACE engine using the same combustor technology. Simulations of the fluid flow and chemistry through the post combustor sections of the engine were made using the CNEWT code. Significant increases in HONO concentrations are observed in the measurements and are corroborated by the numerical simulations, with the latter indicating that OH driven oxidation of NO is the primary HONO chemical production mechanism. Reasonable quantitative agreement between the measurements and model at the combustor exit was achieved, despite significant uncertainties in model initialization of radical species.

  12. Impact of the 2008 Global Recession on air quality over the United States: Implications for surface ozone levels from changes in NOx emissions

    NASA Astrophysics Data System (ADS)

    Tong, Daniel; Pan, Li; Chen, Weiwei; Lamsal, Lok; Lee, Pius; Tang, Youhua; Kim, Hyuncheol; Kondragunta, Shobha; Stajner, Ivanka

    2016-09-01

    Satellite and ground observations detected large variability in nitrogen oxides (NOx) during the 2008 economic recession, but the impact of the recession on air quality has not been quantified. This study combines observed NOx trends and a regional chemical transport model to quantify the impact of the recession on surface ozone (O3) levels over the continental United States. The impact is quantified by simulating O3 concentrations under two emission scenarios: business-as-usual (BAU) and recession. In the BAU case, the emission projection from the Cross-State Air Pollution Rule is used to estimate the "would-be" NOx emission level in 2011. In the recession case, the actual NO2 trends observed from Air Quality System ground monitors and the Ozone Monitoring Instrument on the Aura satellite are used to obtain "realistic" changes in NOx emissions. The model prediction with the recession effect agrees better with ground O3 observations over time and space than the prediction with the BAU emission. The results show that the recession caused a 1-2 ppbv decrease in surface O3 concentration over the eastern United States, a slight increase (0.5-1 ppbv) over the Rocky Mountain region, and mixed changes in the Pacific West. The gain in air quality benefits during the recession, however, could be quickly offset by the much slower emission reduction rate during the post-recession period.

  13. Status review of NASA programs for reducing aircraft gas turbine engine emissions

    NASA Technical Reports Server (NTRS)

    Rudey, R. A.

    1976-01-01

    The paper describes and discusses the results from some of the research and development programs for reducing aircraft gas turbine engine emissions. Although the paper concentrates on NASA programs only, work supported by other U.S. government agencies and industry has provided considerable data on low emission advanced technology for aircraft gas turbine engine combustors. The results from the two major NASA technology development programs, the ECCP (Experimental Clean Combustor Program) and the PRTP (Pollution Reduction Technology Program), are presented and compared with the requirements of the 1979 U.S. EPA standards. Emission reduction techniques currently being evaluated in these programs are described along with the results and a qualitative assessment of development difficulty.

  14. Soot in the stratosphere: The impact of current and HSCT aircraft emissions

    SciTech Connect

    Hansen, A.D.A. ); Pueschel, R.F.; Snetsinger, K.G. . Ames Research Center)

    1991-08-01

    One of the trace components of emissions from aircraft engines and other combustion sources are soot particles. These particles are strongly absorbing in the visible and IR spectra, may act as condensation nuclei, and may provide a large surface area for the catalytic promotion of gas-phase chemical reactions. Soot if found throughout the troposphere, even at remote locations, and also in the stratosphere. Present techniques do not allow an unambiguous identification of the sources. This paper discusses the emission of soot from existing and proposed aircraft and the contribution of this soot to concentrations observed in the troposphere and stratosphere. We consider the implications of these emissions for issues in stratospheric physics and chemistry. 11 refs.

  15. Performance, emissions, and physical characteristics of a rotating combustion aircraft engine

    NASA Technical Reports Server (NTRS)

    Berkowitz, M.; Hermes, W. L.; Mount, R. E.; Myers, D.

    1976-01-01

    The RC2-75, a liquid cooled two chamber rotary combustion engine (Wankel type), designed for aircraft use, was tested and representative baseline (212 KW, 285 BHP) performance and emissions characteristics established. The testing included running fuel/air mixture control curves and varied ignition timing to permit selection of desirable and practical settings for running wide open throttle curves, propeller load curves, variable manifold pressure curves covering cruise conditions, and EPA cycle operating points. Performance and emissions data were recorded for all of the points run. In addition to the test data, information required to characterize the engine and evaluate its performance in aircraft use is provided over a range from one half to twice its present power. The exhaust emissions results are compared to the 1980 EPA requirements. Standard day take-off brake specific fuel consumption is 356 g/KW-HR (.585 lb/BHP-HR) for the configuration tested.

  16. Multi-satellite sensor study on precipitation-induced emission pulses of NOx from soils in semi-arid ecosystems

    NASA Astrophysics Data System (ADS)

    Zörner, Jan; Penning de Vries, Marloes; Beirle, Steffen; Veres, Patrick; Williams, Jonathan; Wagner, Thomas

    2016-04-01

    Soil emissions of NOx (≡ NO + NO2), stemming from biotic emissions of NO, represent a considerable fraction of total NOx emissions, and may even dominate in agricultural and remote areas. Rain-induced spikes in NOx have been observed by in-situ measurements and also satellite observations. However, the estimation of soil emissions over broad geographic regions and on short time scales remains uncertain. This study presents a top-down approach to estimate pulsed soil emissions of trace gases on a global scale using tropospheric NO2 column densities (as a proxy for NOx) as observed by OMI, GOME-2 and SCIAMACHY. We introduce an optimized algorithm that synchronizes and averages multiple time series of atmospheric variables either from one location only, or also from different grid pixels, by aligning them on a relative scale to each other. This method allows investigating changes in the evolution of NO2 VCDs around the first day of rainfall after a prolonged dry period with a temporal resolution of one day and a spatial resolution of 0.25° . We find enhancements in NO2 VCDs on the day of first rainfall in many semi-arid regions in the world which are highly dependent on the season and land cover type. Strongest and most clustered enhancements are found in the distinct band of the Sahel region during the onset of the wet season in April-May-June. Absolute enhancements averaged over the Sahel region for four seasons from 2007 to 2010 range from 0.3*1015molec cm-2 for OMI to 0.4*1015molec cm-2 for GOME-2 and SCIAMACHY on the first day of rainfall. A thorough analysis of other influences on the retrieved signal as well as sensitivity studies are conducted which help to better characterize these short term enhancements. Translating the observed enhancements in NO2 VCDs to emission rates, leads to estimates between 5 and 65 ng N m-2 s-1 for the first day of rainfall which is in line with previous literature. We find that the enhancement in NO2 VCDs already starts to

  17. Long-term NOx trends over large cities in the United States during the great recession: Comparison of satellite retrievals, ground observations, and emission inventories

    NASA Astrophysics Data System (ADS)

    Tong, Daniel Q.; Lamsal, Lok; Pan, Li; Ding, Charles; Kim, Hyuncheol; Lee, Pius; Chai, Tianfeng; Pickering, Kenneth E.; Stajner, Ivanka

    2015-04-01

    National emission inventories (NEIs) take years to assemble, but they can become outdated quickly, especially for time-sensitive applications such as air quality forecasting. This study compares multi-year NOx trends derived from satellite and ground observations and uses these data to evaluate the updates of NOx emission data by the US National Air Quality Forecast Capability (NAQFC) for next-day ozone prediction during the 2008 Global Economic Recession. Over the eight large US cities examined here, both the Ozone Monitoring Instrument (OMI) and the Air Quality System (AQS) detect substantial downward trends from 2005 to 2012, with a seven-year total of -35% according to OMI and -38% according to AQS. The NOx emission projection adopted by NAQFC tends to be in the right direction, but at a slower reduction rate (-25% from 2005 to 2012), due likely to the unaccounted effects of the 2008 economic recession. Both OMI and AQS datasets display distinct emission reduction rates before, during, and after the 2008 global recession in some cities, but the detailed changing rates are not consistent across the OMI and AQS data. Our findings demonstrate the feasibility of using space and ground observations to evaluate major updates of emission inventories objectively. The combination of satellite, ground observations, and in-situ measurements (such as emission monitoring in power plants) is likely to provide more reliable estimates of NOx emission and its trend, which is an issue of increasing importance as many urban areas in the US are transitioning to NOx-sensitive chemical regimes by continuous emission reductions.

  18. Impact of biogenic emissions on ozone and fine particles over Europe: Assessing the effect of temperature increase and the role of anthropogenic NOx emissions reduction

    NASA Astrophysics Data System (ADS)

    Tagaris, Efthimios; Sotiropoulou, Rafaella-Eleni P.; Gounaris, Nikos; Andronopoulos, Spyros; Vlachogiannis, Diamando

    2014-05-01

    The role of biogenic emissions on ozone and PM2.5 levels over Europe is assessed for July 2006 using the CMAQ modeling system. Biogenic emissions are simulated to increase the daily maximum 8 hour ozone (Max8hrO3) mixing ratios and to decrease PM2.5 average concentrations over Europe. Since climate change will lead to higher temperatures increasing subsequently biogenic emissions, sensitivity analysis to temperature is performed. Higher temperatures suggest an average increase in Max8hrO3 mixing ratios over Europe by about 3% and an average decrease in PM2.5 concentrations by about 6%, related to a temperature increase by 3 K degrees. Temperature increases are simulated, also, to increase the organic part of PM2.5 and to decrease the inorganic one on average over Europe. In order to examine if abatement measures for anthropogenic emissions could offset ozone increases in a warmer environment and their effect on PM2.5 concentrations, simulation with a domain wide reduction of anthropogenic NOx emissions by 10% is performed. This is estimated to reduce Max8hrO3 mixing ratios on average over Europe, however, in VOCs limited areas there is an increase. The reduction in anthropogenic NOx emissions is simulated to reduce PM2.5 concentrations on average over Europe enhancing the reduction simulated in a warmer environment but further modifying PM2.5 component concentrations. This work was supported by the National Strategic Reference Framework (NSRF) 2007-2013 grand No 09SYN-31-667.

  19. The empirical relationship between satellite-derived tropospheric NO2 and fire radiative power and possible implications for fire emission rates of NOx

    NASA Astrophysics Data System (ADS)

    Schreier, Stefan F.; Richter, Andreas; Kaiser, Johannes W.; Schepaschenko, Dmitry; Shvidenko, Anatoly; Hilboll, Andreas; Burrows, John P.

    2014-05-01

    Vegetation fires across the globe have various impacts on Earth systems such as the atmosphere and biosphere. Every year, large quantities of biomass in different ecosystems are burned, either started by lightning strikes or caused by humans. Consequently, a considerable amount of trace gases (e.g. NOx) and aerosols is released into the atmosphere. As nitrogen oxides (NOx) affect atmospheric chemistry, air quality, and climate, a quantification of the total emissions is needed. Although several approaches have been developed for the estimation of NOx emissions from fires, they still suffer from large uncertainties. We present a simple statistical approach to estimate fire emission rates (FERs) of NOx based on the linear relationship between satellite-observed tropospheric NO2 vertical columns (TVC NO2) and fire radiative power (FRP). While the great advantage of the method is the spatial coverage of FERs and the application to various biomes and regions, the uncertainties in the two retrieved parameters can lead to uncertainties in the FERs. In general, the approach performs well for the tropical and subtropical regions where both the number and the spatial extent of vegetation fires are rather large throughout the fire season. However, due to the smaller number of fires and the patchy spatial occurrence, the estimation of FERs is more complicated in the boreal regions. Nevertheless, it is possible to derive FERs for some characteristic regions in the North American and Eurasian part of the boreal forest biome. The estimated FERs of NOx for the dominating types of vegetation burned are lowest for open shrublands, savannas, and boreal forest (0.28-1.03 g NOx s-1 MW-1) and highest for croplands and woody savannas (0.82-1.56 g NOx s-1 MW-1). Interestingly, there are large regional discrepancies of up to 40 % observed for evergreen broadleaf forest and boreal forest. Possible explanations for these regional discrepancies are discussed.

  20. NOx, FINE PARTICLE AND TOXIC METAL EMISSIONS FROM THE COMBUSTION OF SEWAGE SLUDGE/COAL MIXTURES: A SYSTEMATIC ASSESSMENT

    SciTech Connect

    Jost O.L. Wendt

    2001-01-31

    This research project focuses on pollutants from the combustion of mixtures of dried municipal sewage sludge (MSS) and coal. The objective is to determine the relationship between (1) fraction sludge in the sludge/coal mixture, and (2) combustion conditions on (a) NOx concentrations in the exhaust, (b) the size segregated fine and ultra-fine particle composition in the exhaust, and (c) the partitioning of toxic metals between vapor and condenses phases, within the process. To this end we shall use an existing 17kW downflow laboratory combustor, available with coal and sludge feed capabilities. The proposed study will be conducted in concert with an existing ongoing research on toxic metal partitioning mechanisms for very well characterized pulverized coals alone. Both high NOx and low NOx combustion conditions will be investigated (unstaged and staged combustion). The proposed work uses existing analytical and experimental facilities and draws on 20 years of research on NO{sub x} and fine particles that has been funded by DOE in this laboratory. Four barrels of dried sewage sludge are currently in the laboratory. Insofar as possible pertinent mechanisms will be elucidated. Tradeoffs between CO{sub 2} control, NO{sub x} control, and inorganic fine particle and toxic metal emissions will be determined. For the First Quarter of this three year project work has centered around recruiting a graduate student to take responsibility for execution of portions of the research, and modifying the furnace and supporting equipment to allow the combustion of coal/MMS mixtures. We have readied the analytical panel for measuring NO{sub x} and other gaseous pollutants. We expect initial experiments for data gathering for coal/MSS mixtures to commence in the next Quarter.

  1. Injection of Lightning-Produced NOx, Water Vapor, Wildfire Emissions, and Stratospheric Air to the UT/LS as Observed from DC3 Measurements

    NASA Astrophysics Data System (ADS)

    Huntrieser, H.; Lichtenstern, M.; Scheibe, M.; Aufmhoff, H.; Schlager, H.; Minikin, A.; Weinzierl, B.; Pollack, I. B.; Peischl, J.; Ryerson, T. B.; Weinheimer, A. J.; Honomichl, S.; Ridley, B. A.; Hair, J. W.; Schwartz, M. J.; Rappenglück, B.; Pickering, K. E.; Cummings, K.; Biggerstaff, M. I.; Heimerl, K.; Pucik, T.; Fütterer, D.; Ackermann, L.; Betten, D.; Butler, C. F.; Barth, M. C.

    2014-12-01

    In summer 2012 the Deep Convective Clouds and Chemistry Project (DC3) field campaign investigated a number of severe thunderstorms over the Central U.S. and their impact on the upper tropospheric (UT) - lower stratospheric (LS) composition and chemistry. In addition, during DC3 some of the largest and most destructive wildfires in New Mexico and Colorado state history were burning, influencing the air quality in the DC3 thunderstorm inflow and outflow region. Besides three instrumented aircraft platforms measuring a variety of trace species in-situ and remotely (e.g. CO, O3, SO2, NOx, VOC, CN, and black carbon), dense networks of ground-based instruments (e.g. radar and lightning) complemented the airborne measurements. Satellite measurements (e.g. GOES, MODIS, and GOME-2) and model forecasts (e.g. WRF-Chem and FLEXPART) were used to monitor the rapid development of the thunderstorms (which frequently developed huge anvils with overshooting tops) and the spread of smoke plumes in the vicinity of the storms. In-situ probing of fresh and aged (12-24 h) anvil outflows showed injection of lightning-produced NOx and wildfire emissions into the UTLS. Vertical cross sections of lidar and Doppler radar measurements supported these observations and gave detailed information on dynamical processes within and in the vicinity of the storms. Besides very strong updrafts in the storm core, surrounding downdrafts caused a direct in-mixing of O3-rich LS air masses into the boundaries of the anvil outflow. The wrapping of O3-rich LS air masses around and below the anvil outflow was also a prominent feature in several storms. The in-situ probing of the aged anvil outflow showed a pronounced influence on the UT composition and chemistry with average O3 enhancements in the range of 20-50 nmol mol-1 and evidence of new particle formation. A 10-year global climatology of H2O data from Aura-MLS confirms that the Central U.S. is a preferred region for convective injection into the LS.

  2. Injection of Lightning-Produced NOx, Water Vapor, Wildfire Emissions, and Stratospheric Air to the UT/LS as Observed from DC3 Measurements

    NASA Astrophysics Data System (ADS)

    Huntrieser, H.; Lichtenstern, M.; Scheibe, M.; Aufmhoff, H.; Schlager, H.; Minikin, A.; Weinzierl, B.; Pollack, I. B.; Peischl, J.; Ryerson, T. B.; Weinheimer, A. J.; Honomichl, S.; Ridley, B. A.; Hair, J. W.; Schwartz, M. J.; Rappenglück, B.; Pickering, K. E.; Cummings, K.; Biggerstaff, M. I.; Heimerl, K.; Pucik, T.; Fütterer, D.; Ackermann, L.; Betten, D.; Butler, C. F.; Barth, M. C.

    2015-12-01

    In summer 2012 the Deep Convective Clouds and Chemistry Project (DC3) field campaign investigated a number of severe thunderstorms over the Central U.S. and their impact on the upper tropospheric (UT) - lower stratospheric (LS) composition and chemistry. In addition, during DC3 some of the largest and most destructive wildfires in New Mexico and Colorado state history were burning, influencing the air quality in the DC3 thunderstorm inflow and outflow region. Besides three instrumented aircraft platforms measuring a variety of trace species in-situ and remotely (e.g. CO, O3, SO2, NOx, VOC, CN, and black carbon), dense networks of ground-based instruments (e.g. radar and lightning) complemented the airborne measurements. Satellite measurements (e.g. GOES, MODIS, and GOME-2) and model forecasts (e.g. WRF-Chem and FLEXPART) were used to monitor the rapid development of the thunderstorms (which frequently developed huge anvils with overshooting tops) and the spread of smoke plumes in the vicinity of the storms. In-situ probing of fresh and aged (12-24 h) anvil outflows showed injection of lightning-produced NOx and wildfire emissions into the UTLS. Vertical cross sections of lidar and Doppler radar measurements supported these observations and gave detailed information on dynamical processes within and in the vicinity of the storms. Besides very strong updrafts in the storm core, surrounding downdrafts caused a direct in-mixing of O3-rich LS air masses into the boundaries of the anvil outflow. The wrapping of O3-rich LS air masses around and below the anvil outflow was also a prominent feature in several storms. The in-situ probing of the aged anvil outflow showed a pronounced influence on the UT composition and chemistry with average O3 enhancements in the range of 20-50 nmol mol-1 and evidence of new particle formation. A 10-year global climatology of H2O data from Aura-MLS confirms that the Central U.S. is a preferred region for convective injection into the LS.

  3. Combustion Dynamics and Control for Ultra Low Emissions in Aircraft Gas-Turbine Engines

    NASA Technical Reports Server (NTRS)

    DeLaat, John C.

    2011-01-01

    Future aircraft engines must provide ultra-low emissions and high efficiency at low cost while maintaining the reliability and operability of present day engines. The demands for increased performance and decreased emissions have resulted in advanced combustor designs that are critically dependent on efficient fuel/air mixing and lean operation. However, all combustors, but most notably lean-burning low-emissions combustors, are susceptible to combustion instabilities. These instabilities are typically caused by the interaction of the fluctuating heat release of the combustion process with naturally occurring acoustic resonances. These interactions can produce large pressure oscillations within the combustor and can reduce component life and potentially lead to premature mechanical failures. Active Combustion Control which consists of feedback-based control of the fuel-air mixing process can provide an approach to achieving acceptable combustor dynamic behavior while minimizing emissions, and thus can provide flexibility during the combustor design process. The NASA Glenn Active Combustion Control Technology activity aims to demonstrate active control in a realistic environment relevant to aircraft engines by providing experiments tied to aircraft gas turbine combustors. The intent is to allow the technology maturity of active combustion control to advance to eventual demonstration in an engine environment. Work at NASA Glenn has shown that active combustion control, utilizing advanced algorithms working through high frequency fuel actuation, can effectively suppress instabilities in a combustor which emulates the instabilities found in an aircraft gas turbine engine. Current efforts are aimed at extending these active control technologies to advanced ultra-low-emissions combustors such as those employing multi-point lean direct injection.

  4. Aircraft engine exhaust emissions and other airport-related contributions to ambient air pollution: A review

    NASA Astrophysics Data System (ADS)

    Masiol, Mauro; Harrison, Roy M.

    2014-10-01

    Civil aviation is fast-growing (about +5% every year), mainly driven by the developing economies and globalisation. Its impact on the environment is heavily debated, particularly in relation to climate forcing attributed to emissions at cruising altitudes and the noise and the deterioration of air quality at ground-level due to airport operations. This latter environmental issue is of particular interest to the scientific community and policymakers, especially in relation to the breach of limit and target values for many air pollutants, mainly nitrogen oxides and particulate matter, near the busiest airports and the resulting consequences for public health. Despite the increased attention given to aircraft emissions at ground-level and air pollution in the vicinity of airports, many research gaps remain. Sources relevant to air quality include not only engine exhaust and non-exhaust emissions from aircraft, but also emissions from the units providing power to the aircraft on the ground, the traffic due to the airport ground service, maintenance work, heating facilities, fugitive vapours from refuelling operations, kitchens and restaurants for passengers and operators, intermodal transportation systems, and road traffic for transporting people and goods in and out to the airport. Many of these sources have received inadequate attention, despite their high potential for impact on air quality. This review aims to summarise the state-of-the-art research on aircraft and airport emissions and attempts to synthesise the results of studies that have addressed this issue. It also aims to describe the key characteristics of pollution, the impacts upon global and local air quality and to address the future potential of research by highlighting research needs.

  5. Estimates of non-traditional secondary organic aerosols from aircraft SVOC and IVOC emissions using CMAQ

    NASA Astrophysics Data System (ADS)

    Woody, M. C.; West, J. J.; Jathar, S. H.; Robinson, A. L.; Arunachalam, S.

    2014-12-01

    Utilizing an aircraft-specific parameterization based on smog chamber data in the Community Multiscale Air Quality (CMAQ) model with the Volatility Basis Set (VBS), we estimated contributions of non-traditional secondary organic aerosols (NTSOA) for aircraft emissions during landing and takeoff (LTO) activities at the Hartsfield-Jackson Atlanta International Airport. NTSOA, formed from the oxidation of semi-volatile and intermediate volatility organic compounds (S/IVOCs), is a heretofore unaccounted component of fine particulate matter (PM2.5) in most air quality models. We expanded a prerelease version of CMAQ with VBS implemented for the Carbon Bond 2005 (CB05) chemical mechanism to use the Statewide Air Pollution Research Center 2007 (SAPRC-07) chemical mechanism, and added species representing aircraft S/IVOCs and corresponding NTSOA oxidation products. Results indicated the maximum monthly average NTSOA contributions occurred at the airport, and ranged from 2.4 ng m-3 (34% from idle and 66% from non-idle aircraft activities) in January to 9.1 ng m-3 (33 and 67%) in July. This represents 1.7% (of 140 ng m-3) in January and 7.4% in July (of 122 ng m-3) of aircraft-attributable PM2.5, compared to 41.0-42.0% from elemental carbon and 42.8-58.0% from inorganic aerosols. As a percentage of PM2.5, impacts were higher downwind of the airport, where NTSOA averaged 4.6-17.9% of aircraft-attributable PM2.5 and, considering alternative aging schemes, was high as 24.0% - thus indicating the increased contribution of aircraft-attributable SOA, as a component of PM2.5. However, NTSOA contributions were generally low compared to smog chamber results, particularly at idle, due to the considerably lower ambient organic aerosol concentrations in CMAQ, vs. those in the smog chamber experiments.

  6. Estimates of non-traditional secondary organic aerosols from aircraft SVOC and IVOC emissions using CMAQ

    NASA Astrophysics Data System (ADS)

    Woody, M. C.; West, J. J.; Jathar, S. H.; Robinson, A. L.; Arunachalam, S.

    2015-06-01

    Utilizing an aircraft-specific parameterization based on smog chamber data in the Community Multiscale Air Quality (CMAQ) model with the volatility basis set (VBS), we estimated contributions of non-traditional secondary organic aerosols (NTSOA) for aircraft emissions during landing and takeoff (LTO) activities at the Hartsfield-Jackson Atlanta International Airport. NTSOA, formed from the oxidation of semi-volatile and intermediate volatility organic compounds (S/IVOCs), is a heretofore unaccounted component of fine particulate matter (PM2.5) in most air quality models. We expanded a prerelease version of CMAQ with VBS implemented for the Carbon Bond 2005 (CB05) chemical mechanism to use the Statewide Air Pollution Research Center 2007 (SAPRC-07) chemical mechanism and added species representing aircraft S/IVOCs and corresponding NTSOA oxidation products. Results indicated that the maximum monthly average NTSOA contributions occurred at the airport and ranged from 2.4 ng m-3 (34 % from idle and 66 % from non-idle aircraft activities) in January to 9.1 ng m-3 (33 and 67 %) in July. This represents 1.7 % (of 140 ng m-3) in January and 7.4 % in July (of 122 ng m-3) of aircraft-attributable PM2.5 compared to 41.0-42.0 % from elemental carbon and 42.8-58.0 % from inorganic aerosols. As a percentage of PM2.5, impacts were higher downwind of the airport, where NTSOA averaged 4.6-17.9 % of aircraft-attributable PM2.5 and, considering alternative aging schemes, was as high as 24.0 % - thus indicating the increased contribution of aircraft-attributable SOA as a component of PM2.5. However, NTSOA contributions were generally low compared to smog chamber results, particularly at idle, due to the considerably lower ambient organic aerosol concentrations in CMAQ compared to those in the smog chamber experiments.

  7. Evaluation of an Aircraft Concept With Over-Wing, Hydrogen-Fueled Engines for Reduced Noise and Emissions

    NASA Technical Reports Server (NTRS)

    Guynn, Mark D.; Olson, Erik D.

    2002-01-01

    This report describes the analytical modeling and evaluation of an unconventional commercial transport aircraft concept designed to address aircraft noise and emission issues. A strut-braced wing configuration with overwing, ultra-high bypass ratio, hydrogen fueled turbofan engines is considered. Estimated noise and emission characteristics are compared to a conventional configuration designed for the same mission and significant benefits are identified. The design challenges and technology issues which would have to be addressed to make the concept a viable alternative to current aircraft designs are discussed. This concept is one of the "Quiet Green Transport" aircraft concepts studied as part of NASA's Revolutionary Aerospace Systems Concepts (RASC) Program. The RASC Program seeks to develop revolutionary concepts that address strategic objectives of the NASA Enterprises, such as reducing aircraft noise and emissions, and to identify enabling advanced technology requirements for the concepts.

  8. Evaluation of a Hydrogen Fuel Cell Powered Blended-Wing-Body Aircraft Concept for Reduced Noise and Emissions

    NASA Technical Reports Server (NTRS)

    Guynn, Mark D.; Freh, Joshua E.; Olson, Erik D.

    2004-01-01

    This report describes the analytical modeling and evaluation of an unconventional commercial transport aircraft concept designed to address aircraft noise and emission issues. A blended-wing-body configuration with advanced technology hydrogen fuel cell electric propulsion is considered. Predicted noise and emission characteristics are compared to a current technology conventional configuration designed for the same mission. The significant technology issues which have to be addressed to make this concept a viable alternative to current aircraft designs are discussed. This concept is one of the "Quiet Green Transport" aircraft concepts studied as part of NASA's Revolutionary Aerospace Systems Concepts (RASC) Program. The RASC Program was initiated to develop revolutionary concepts that address strategic objectives of the NASA Enterprises, such as reducing aircraft noise and emissions, and to identify advanced technology requirements for the concepts.

  9. ICOARE: Impacts on Climate and Ozone from Aircraft and Rocket Emissions

    NASA Astrophysics Data System (ADS)

    Toohey, D. W.; Ross, M.

    2009-12-01

    This presentation will provide an overview of an Earth Venture proposal for a series of in situ measurements in the exhaust plumes of aircraft and rockets with the following objectives: to obtain information that is critical for reducing the uncertainties in assessments (e.g., WMO and IPCC) of the impacts of aviation and aerospace activities on regional and global climate; to assess the viability of a climate engineering scheme that employs injection of reflective particles into the lower stratosphere; and to initiate the development of an operational modeling tool that can be used by the aviation and aerospace industries to guide design of new transporation systems that minimize the impact on Earth’s climate. The ICOARE mission will deploy instruments to measure water vapor, ice water content, tracers, reactive species, particles, and radiation fields on a high-altitude aircraft to characterize the variability of water vapor in aircraft and rocket contrails, determine accurate emission indices for initialization of plume-wake and regional scale models, investigate the microphysical properties of cirrus particles in and out of aircraft corridors, and examine the light scattering properties of contrail ice crystals and small alumina particles. Focused campaigns will be timed to occur around the launch schedules of a variety of rocket types in order to characterize the range of emissions from the current launch suite. There will be special emphasis on characterizing the emissions from rockets employing new propellants, in particular those that may produce soot and nitrogen oxides. Observations in aircraft exhaust, and examinations of cirrus cloud properties and persistent contrails, will occur on flights that are not dedicated to studies of rockets (e.g., test, transit, and rocket-scrub flights). ICOARE will offer a unique opportunities for training students and postdoctorates, especially those from underrepresented groups, in areas of project management, logistics

  10. Energy and emissions saving potential of additive manufacturing: the case of lightweight aircraft components

    DOE PAGES

    Huang, Runze; Riddle, Matthew; Graziano, Diane; Warren, Joshua; Das, Sujit; Nimbalkar, Sachin; Cresko, Joe; Masanet, Eric

    2015-05-08

    Additive manufacturing (AM) holds great potential for improving materials efficiency, reducing life-cycle impacts, and enabling greater engineering functionality compared to conventional manufacturing (CM) processes. For these reasons, AM has been adopted by a growing number of aircraft component manufacturers to achieve more lightweight, cost-effective designs. This study estimates the net changes in life-cycle primary energy and greenhouse gas emissions associated with AM technologies for lightweight metallic aircraft components through the year 2050, to shed light on the environmental benefits of a shift from CM to AM processes in the U.S. aircraft industry. A systems modeling framework is presented, with integratesmore » engineering criteria, life-cycle environmental data, and aircraft fleet stock and fuel use models under different AM adoption scenarios. Estimated fleetwide life-cycle primary energy savings in a rapid adoption scenario reach 70-174 million GJ/year in 2050, with cumulative savings of 1.2-2.8 billion GJ. Associated cumulative emission reduction potentials of CO2e were estimated at 92.8-217.4 million metric tons. About 95% of the savings is attributed to airplane fuel consumption reductions due to lightweighting. In addition, about 4050 tons aluminum, 7600 tons titanium and 8100 tons of nickel alloys could be saved per year in 2050. The results indicate a significant role of AM technologies in helping society meet its long-term energy use and GHG emissions reduction goals, and highlight barriers and opportunities for AM adoption for the aircraft industry.« less

  11. Assessing the environmental impacts of aircraft noise and emissions

    NASA Astrophysics Data System (ADS)

    Mahashabde, Anuja; Wolfe, Philip; Ashok, Akshay; Dorbian, Christopher; He, Qinxian; Fan, Alice; Lukachko, Stephen; Mozdzanowska, Aleksandra; Wollersheim, Christoph; Barrett, Steven R. H.; Locke, Maryalice; Waitz, Ian A.

    2011-01-01

    With the projected growth in demand for commercial aviation, many anticipate increased environmental impacts associated with noise, air quality, and climate change. Therefore, decision-makers and stakeholders are seeking policies, technologies, and operational procedures that balance environmental and economic interests. The main objective of this paper is to address shortcomings in current decision-making practices for aviation environmental policies. We review knowledge of the noise, air quality, and climate impacts of aviation, and demonstrate how including environmental impact assessment and quantifying uncertainties can enable a more comprehensive evaluation of aviation environmental policies. A comparison is presented between the cost-effectiveness analysis currently used for aviation environmental policy decision-making and an illustrative cost-benefit analysis. We focus on assessing a subset of the engine NO X emissions certification stringency options considered at the eighth meeting of the International Civil Aviation Organization’s Committee on Aviation Environmental Protection. The FAA Aviation environmental Portfolio Management Tool (APMT) is employed to conduct the policy assessments. We show that different conclusions may be drawn about the same policy options depending on whether benefits and interdependencies are estimated in terms of health and welfare impacts versus changes in NO X emissions inventories as is the typical practice. We also show that these conclusions are sensitive to a variety of modeling uncertainties. While our more comprehensive analysis makes the best policy option less clear, it represents a more accurate characterization of the scientific and economic uncertainties underlying impacts and the policy choices.

  12. Hydrocarbon emissions from in-use commercial aircraft during airport operations.

    PubMed

    Herndon, Scott C; Rogers, Todd; Dunlea, Edward J; Jayne, John T; Miake-Lye, Richard; Knighton, Berk

    2006-07-15

    The emissions of selected hydrocarbons from in-use commercial aircraft at a major airport in the United States were characterized using proton-transfer reaction mass spectrometry (PTR-MS) and tunable infrared differential absorption spectroscopy (TILDAS) to probe the composition of diluted exhaust plumes downwind. The emission indices for formaldehyde, acetaldehyde, benzene, and toluene, as well as other hydrocarbon species, were determined through analysis of 45 intercepted plumes identified as being associated with specific aircraft. As would have been predicted for high bypass turbine engines, the hydrocarbon emission index was greater in idle and taxiway acceleration plumes relative to approach and takeoff plumes. The opposite was seen in total NOy emission index, which increased from idle to takeoff. Within the idle plumes sampled in this study, the median emission index for formaldehyde was 1.1 g of HCHO per kg of fuel. For the subset of hydrocarbons measured in this work, the idle emissions levels relative to formaldehyde agree well with those of previous studies. The projected total unburned hydrocarbons (UHC) deduced from the range of in-use idle plumes analyzed in this work is greater than a plausible range of engine types using the defined idle condition (7% of rated engine thrust) in the International Civil Aviation Organization (ICAO) databank reference.

  13. Eastern Asian Emissions of Anthropogenic Halocarbons Deduced from Aircraft Concentration Data

    NASA Technical Reports Server (NTRS)

    Palmer, Paul I.; Jacob, Daniel J.; Mickle, Loretta, J.; Blake, Donald R.; Sachse, Glen W.; Fuelberg, Henry E.; Kiley, Christopher M.

    2003-01-01

    The Montreal Protocol restricts production of ozone-depleting halocarbons worldwide. Enforcement of the protocol has relied mainly on annual government statistics of production and consumption of these compounds (bottom-up approach). We show here that aircraft observations of ha1ocarbon:CO enhancement ratios on regional to continental scales can be used to infer halocarbon emissions, providing independent verification of the bottom-up approach. We apply this topdown approach to aircraft observations of Asian outflow &om the TRACE-P mission over the western Pacific (March-April 2001) and derive emissions from eastern Asia (China, Japan, and Korea). We derive an eastern Asian carbon tetrachloride (CCl4) source of 21.5 Gg yr(sup -1), several-fold larger than previous estimates and amounting to -30% of the global budget for this gas. Our emission estimate for CFC-11 from eastern Asia is 50% higher than inventories derived from manufacturing records. Our emission estimates for methyl chloroform (CH3CC13) and CFC-12 are in agreement with existing inventories. For halon 1211 we find only a strong local source originating from the Shanghai area. Our emission estimates for the above gases result in a approximately equal to 40% increase in the ozone depletion potential (ODP) of Asian emissions relative to previous estimates, corresponding to a approximately equal to 10% global increase in ODP.

  14. Near-Field Characterization of Methane Emission Variability from a Compressor Station Using a Model Aircraft.

    PubMed

    Nathan, Brian J; Golston, Levi M; O'Brien, Anthony S; Ross, Kevin; Harrison, William A; Tao, Lei; Lary, David J; Johnson, Derek R; Covington, April N; Clark, Nigel N; Zondlo, Mark A

    2015-07-01

    A model aircraft equipped with a custom laser-based, open-path methane sensor was deployed around a natural gas compressor station to quantify the methane leak rate and its variability at a compressor station in the Barnett Shale. The open-path, laser-based sensor provides fast (10 Hz) and precise (0.1 ppmv) measurements of methane in a compact package while the remote control aircraft provides nimble and safe operation around a local source. Emission rates were measured from 22 flights over a one-week period. Mean emission rates of 14 ± 8 g CH4 s(-1) (7.4 ± 4.2 g CH4 s(-1) median) from the station were observed or approximately 0.02% of the station throughput. Significant variability in emission rates (0.3-73 g CH4 s(-1) range) was observed on time scales of hours to days, and plumes showed high spatial variability in the horizontal and vertical dimensions. Given the high spatiotemporal variability of emissions, individual measurements taken over short durations and from ground-based platforms should be used with caution when examining compressor station emissions. More generally, our results demonstrate the unique advantages and challenges of platforms like small unmanned aerial vehicles for quantifying local emission sources to the atmosphere.

  15. Reducing NOx Emissions for a 600 MWe Down-Fired Pulverized-Coal Utility Boiler by Applying a Novel Combustion System.

    PubMed

    Ma, Lun; Fang, Qingyan; Lv, Dangzhen; Zhang, Cheng; Chen, Yiping; Chen, Gang; Duan, Xuenong; Wang, Xihuan

    2015-11-01

    A novel combustion system was applied to a 600 MWe Foster Wheeler (FW) down-fired pulverized-coal utility boiler to solve high NOx emissions, without causing an obvious increase in the carbon content of fly ash. The unit included moving fuel-lean nozzles from the arches to the front/rear walls and rearranging staged air as well as introducing separated overfire air (SOFA). Numerical simulations were carried out under the original and novel combustion systems to evaluate the performance of combustion and NOx emissions in the furnace. The simulated results were found to be in good agreement with the in situ measurements. The novel combustion system enlarged the recirculation zones below the arches, thereby strengthening the combustion stability considerably. The coal/air downward penetration depth was markedly extended, and the pulverized-coal travel path in the lower furnace significantly increased, which contributed to the burnout degree. The introduction of SOFA resulted in a low-oxygen and strong-reducing atmosphere in the lower furnace region to reduce NOx emissions evidently. The industrial measurements showed that NOx emissions at full load decreased significantly by 50%, from 1501 mg/m3 (O2 at 6%) to 751 mg/m3 (O2 at 6%). The carbon content in the fly ash increased only slightly, from 4.13 to 4.30%. PMID:26452156

  16. 40 CFR Appendix E to Part 75 - Optional NOX Emissions Estimation Protocol for Gas-Fired Peaking Units and Oil-Fired Peaking Units

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 17 2013-07-01 2013-07-01 false Optional NOX Emissions Estimation Protocol for Gas-Fired Peaking Units and Oil-Fired Peaking Units E Appendix E to Part 75 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CONTINUOUS...

  17. Reducing NOx Emissions for a 600 MWe Down-Fired Pulverized-Coal Utility Boiler by Applying a Novel Combustion System.

    PubMed

    Ma, Lun; Fang, Qingyan; Lv, Dangzhen; Zhang, Cheng; Chen, Yiping; Chen, Gang; Duan, Xuenong; Wang, Xihuan

    2015-11-01

    A novel combustion system was applied to a 600 MWe Foster Wheeler (FW) down-fired pulverized-coal utility boiler to solve high NOx emissions, without causing an obvious increase in the carbon content of fly ash. The unit included moving fuel-lean nozzles from the arches to the front/rear walls and rearranging staged air as well as introducing separated overfire air (SOFA). Numerical simulations were carried out under the original and novel combustion systems to evaluate the performance of combustion and NOx emissions in the furnace. The simulated results were found to be in good agreement with the in situ measurements. The novel combustion system enlarged the recirculation zones below the arches, thereby strengthening the combustion stability considerably. The coal/air downward penetration depth was markedly extended, and the pulverized-coal travel path in the lower furnace significantly increased, which contributed to the burnout degree. The introduction of SOFA resulted in a low-oxygen and strong-reducing atmosphere in the lower furnace region to reduce NOx emissions evidently. The industrial measurements showed that NOx emissions at full load decreased significantly by 50%, from 1501 mg/m3 (O2 at 6%) to 751 mg/m3 (O2 at 6%). The carbon content in the fly ash increased only slightly, from 4.13 to 4.30%.

  18. 40 CFR Table 1 to Subpart Jjjj of... - NOX, CO, and VOC Emission Standards for Stationary Non-Emergency SI Engines ≥100 HP (Except...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Combustion Engines Pt. 60, Subpt. JJJJ, Table 1 Table 1 to Subpart JJJJ of Part 60—NOX, CO, and VOC Emission... Stationary Non-Emergency SI Engines â¥100 HP (Except Gasoline and Rich Burn LPG), Stationary SI Landfill/Digester Gas Engines, and Stationary Emergency Engines >25 HP 1 Table 1 to Subpart JJJJ of Part...

  19. 40 CFR Table 1 to Subpart Jjjj of... - NOX, CO, and VOC Emission Standards for Stationary Non-Emergency SI Engines ≥100 HP (Except...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Combustion Engines Pt. 60, Subpt. JJJJ, Table 1 Table 1 to Subpart JJJJ of Part 60—NOX, CO, and VOC Emission... Stationary Non-Emergency SI Engines â¥100 HP (Except Gasoline and Rich Burn LPG), Stationary SI Landfill/Digester Gas Engines, and Stationary Emergency Engines >25 HP 1 Table 1 to Subpart JJJJ of Part...

  20. 40 CFR Table 1 to Subpart Jjjj of... - NOX, CO, and VOC Emission Standards for Stationary Non-Emergency SI Engines ≥100 HP (Except...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Combustion Engines Pt. 60, Subpt. JJJJ, Table 1 Table 1 to Subpart JJJJ of Part 60—NOX, CO, and VOC Emission... Stationary Non-Emergency SI Engines â¥100 HP (Except Gasoline and Rich Burn LPG), Stationary SI Landfill/Digester Gas Engines, and Stationary Emergency Engines >25 HP 1 Table 1 to Subpart JJJJ of Part...

  1. 40 CFR Table 1 to Subpart Jjjj of... - NOX, CO, and VOC Emission Standards for Stationary Non-Emergency SI Engines ≥100 HP (Except...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Combustion Engines Pt. 60, Subpt. JJJJ, Table 1 Table 1 to Subpart JJJJ of Part 60—NOX, CO, and VOC Emission... Stationary Non-Emergency SI Engines â¥100 HP (Except Gasoline and Rich Burn LPG), Stationary SI Landfill/Digester Gas Engines, and Stationary Emergency Engines >25 HP 1 Table 1 to Subpart JJJJ of Part...

  2. 40 CFR Table 1 to Subpart Jjjj of... - NOX, CO, and VOC Emission Standards for Stationary Non-Emergency SI Engines ≥100 HP (Except...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Combustion Engines Pt. 60, Subpt. JJJJ, Table 1 Table 1 to Subpart JJJJ of Part 60—NOX, CO, and VOC Emission... Stationary Non-Emergency SI Engines â¥100 HP (Except Gasoline and Rich Burn LPG), Stationary SI Landfill/Digester Gas Engines, and Stationary Emergency Engines >25 HP 1 Table 1 to Subpart JJJJ of Part...

  3. AISI/DOE Technology Roadmap Program: Development of an O2-Enriched Furnace System for Reduced CO2 and NOx Emissions For the Steel Industry

    SciTech Connect

    Edward W. Grandmaison; David J. Poirier; Eric Boyd

    2003-01-20

    An oxygen-enriched furnace system for reduced CO2 and NOx emission has been developed. The furnace geometry, with a sidewall-mounted burner, was similar to configurations commonly encountered in a steel reheat furnace. The effect of stack oxygen concentration, oxygen enrichment level and air infiltration on fuel savings/CO2 reduction, NOx emissions and scale formation were investigated. The firing rate required to maintain the furnace temperature at 1100 C decreased linearly with increasing oxygen enrichment. At full oxygen enrichment a reduction of 40-45% in the firing rate was required to maintain furnace temperature. NOx emissions were relatively constant at oxygen enrichment levels below 60% and decreased concentration at all oxygen enrichment levels. Air infiltration also had an effect on NOx levels leading to emissions similar to those observed with no air infiltration but with similar stack oxygen concentrations. At high oxygen enrichment levels, there was a larger variation in the refractory surface-temperature on the roof and blind sidewall of the furnace. Scale habit, intactness, adhesion and oxidation rates were examined for five grades of steel over a range of stack oxygen concentrations and oxygen enrichment levels at 1100 degree C. The steel grade had the largest effect on scaling properties examined in this work. The stack oxygen concentration and the oxygen enrichment level had much smaller effects on the scaling properties.

  4. 40 CFR 60.4325 - What emission limits must I meet for NOX if my turbine burns both natural gas and distillate oil...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... NOX if my turbine burns both natural gas and distillate oil (or some other combination of fuels)? 60... both natural gas and distillate oil (or some other combination of fuels)? You must meet the emission... percent natural gas, you must meet the corresponding limit for a natural gas-fired turbine when you...

  5. 40 CFR 60.4325 - What emission limits must I meet for NOX if my turbine burns both natural gas and distillate oil...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... NOX if my turbine burns both natural gas and distillate oil (or some other combination of fuels)? 60... both natural gas and distillate oil (or some other combination of fuels)? You must meet the emission... percent natural gas, you must meet the corresponding limit for a natural gas-fired turbine when you...

  6. 40 CFR 60.4325 - What emission limits must I meet for NOX if my turbine burns both natural gas and distillate oil...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... NOX if my turbine burns both natural gas and distillate oil (or some other combination of fuels)? 60... both natural gas and distillate oil (or some other combination of fuels)? You must meet the emission... percent natural gas, you must meet the corresponding limit for a natural gas-fired turbine when you...

  7. 40 CFR 60.4325 - What emission limits must I meet for NOX if my turbine burns both natural gas and distillate oil...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... NOX if my turbine burns both natural gas and distillate oil (or some other combination of fuels)? 60... both natural gas and distillate oil (or some other combination of fuels)? You must meet the emission... percent natural gas, you must meet the corresponding limit for a natural gas-fired turbine when you...

  8. 40 CFR Appendix E to Part 75 - Optional NOX Emissions Estimation Protocol for Gas-Fired Peaking Units and Oil-Fired Peaking Units

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... following procedures. 2.1.6.1Plot the heat input rate (mmBtu/hr) as the independent (or x) variable and the NOX emission rates (lb/mmBtu) as the dependent (or y) variable for each load point. Construct...

  9. EMISSIONS AND COST ESTIMATES FOR GLOBALLY SIGNIFICANT ANTHROPOGENIC COMBUSTION SOURCES OF NOX, N2O, CH4, CO AND CO2

    EPA Science Inventory

    The report discusses the development of emission factors for CO2, CO, CH4, NOx, and N2O for about 80 globally significant combustion sources in seven source categories: utility, industrial, fuel production, transportation, residential, commercial, and kilns/ovens/dryers. ecause o...

  10. Aerosol emissions from prescribed fires in the United States: A synthesis of laboratory and aircraft measurements

    NASA Astrophysics Data System (ADS)

    May, A. A.; McMeeking, G. R.; Lee, T.; Taylor, J. W.; Craven, J. S.; Burling, I.; Sullivan, A. P.; Akagi, S.; Collett, J. L.; Flynn, M.; Coe, H.; Urbanski, S. P.; Seinfeld, J. H.; Yokelson, R. J.; Kreidenweis, S. M.

    2014-10-01

    Aerosol emissions from prescribed fires can affect air quality on regional scales. Accurate representation of these emissions in models requires information regarding the amount and composition of the emitted species. We measured a suite of submicron particulate matter species in young plumes emitted from prescribed fires (chaparral and montane ecosystems in California; coastal plain ecosystem in South Carolina) and from open burning of over 15 individual plant species in the laboratory. We report emission ratios and emission factors for refractory black carbon (rBC) and submicron nonrefractory aerosol and compare field and laboratory measurements to assess the representativeness of our laboratory-measured emissions. Laboratory measurements of organic aerosol (OA) emission factors for some fires were an order of magnitude higher than those derived from any of our aircraft observations; these are likely due to higher-fuel moisture contents, lower modified combustion efficiencies, and less dilution compared to field studies. Nonrefractory inorganic aerosol emissions depended more strongly on fuel type and fuel composition than on combustion conditions. Laboratory and field measurements for rBC were in good agreement when differences in modified combustion efficiency were considered; however, rBC emission factors measured both from aircraft and in the laboratory during the present study using the Single Particle Soot Photometer were generally higher than values previously reported in the literature, which have been based largely on filter measurements. Although natural variability may account for some of these differences, an increase in the BC emission factors incorporated within emission inventories may be required, pending additional field measurements for a wider variety of fires.

  11. Biofuel Blending Impacts on Aircraft Engine Particle Emissions at Cruise Conditions

    NASA Astrophysics Data System (ADS)

    Moore, R.

    2015-12-01

    We present measurements of aerosol emissions indices and microphysical properties measured in-situ behind the CFM56-2-C1 engines of the NASA DC-8 aircraft during the 2014 Alternative Fuel Effects on Contrails and Cruise Emissions (ACCESS) project. Aircraft engine emissions can have a disproportionately large climatic impact since they are emitted high in the troposphere and in remote regions with otherwise low aerosol concentrations. This has motivated numerous past ground-based studies focused on quantifying the emissions indices of non-volatile and semi-volatile aerosol species, however, it is unclear the extent to which emissions on the ground translate to emissions at cruise conditions. In addition, the ability of engine-emitted aerosols to nucleate ice crystals and form linear contrails or contrail cirrus clouds remains poorly understood. To better understand these effects, two chase plane experiments were carried out in 2013 and 2014. Three different fuel types are discussed: a low-sulfur JP-8 fuel, a 50:50 blend of JP-8 and a camelina-based HEFA fuel, and the JP-8 fuel doped with sulfur. Emissions were sampled using a large number of aerosol and gas instruments integrated on HU-25 and Falcon 20 jets that were positioned in the DC-8 exhaust plume at approximately 50-500 m distance behind the engines. It was found that the biojet fuel blend substantially decreases the aerosol number and mass emissions indices, while the gas phase emission indices were similar across fuels. The magnitude of the effects of these fuel-induced changes of aerosol emissions and implications for future aviation biofuel blending impacts will be discussed.

  12. Environmental investigation on co-combustion of sewage sludge and coal gangue: SO2, NOx and trace elements emissions.

    PubMed

    Yang, Zhenzhou; Zhang, Yingyi; Liu, Lili; Wang, Xidong; Zhang, Zuotai

    2016-04-01

    To promote the utilization of waste material as alternative fuel, the mono- and co-combustion characteristics of sewage sludge (SS) and coal gangue (CG) were systematically investigated, with emphasis on environmental influences. The emission of SO2, NOx as well as the trace elements during combustion of SS and CG were studied with regard to the effects of their chemistries, structures and interactions. Results showed that co-combustion can be beneficial for ignition performance. A synergic effect on both desulfurization and denitrification can be expected at ca. 800°C. Further, an enhanced retention of trace elements during co-combustion was also observed, especially for Pb and Zn. On the basis of the results, it can be expected that, with proper operation, co-combustion of SS and CG can be a promising method for the disposal of these two wastes.

  13. NOx Emission Reduction by the Optimization of the Primary Air Distribution in the 235Mwe CFB Boiler

    NASA Astrophysics Data System (ADS)

    Mirek, P.; Czakiert, T.; Nowak, W.

    The article presents the results of experimental studies conducted on a large-scale 235 MWe CFB (Circulating Fluidized Bed) boiler, in which the primary air distribution system was modified. The modification was connected with the change of internal geometry of primary air channels as well as internal space of plenum chamber. The obtained results have shown, that the optimization of primary air flow has a great influence on the intensity of the combustion process and the temperature distribution along the height of combustion chamber. As a result, the NOx emission has been reduced by up to ten percent and the temperature profile in the combustion chamber has been revealed to be more uniform.

  14. DEVELOPMENT OF A VALIDATED MODEL FOR USE IN MINIMIZING NOx EMISSIONS AND MAXIMIZING CARBON UTILIZATION WHEN COFIRING BIOMASS WITH COAL

    SciTech Connect

    Larry G. Felix; P. Vann Bush; Stephen Niksa

    2001-01-24

    This is the first Quarterly Technical Report for DOE Cooperative Agreement No. DE-FC26-00NT40895. A statement of the project objectives is included in the Introduction of this report. The project goals and detailed plans were presented in two project kickoff meetings; one at NETL in Pittsburgh and one in Birmingham, AL at Southern Research Institute. Progress has been made in developing a modeling approach to synthesize the reaction time and temperature distributions that will be produced by computational fluid dynamic models of the pilot-scale combustion furnace and the char burnout and chemical reaction kinetics that will predict NOx emissions and unburned carbon levels in the furnace exhaust. Preparations are under way for the initial pilot-scale combustion experiments.

  15. Reduced emissions of CO2, NOx, and SO2 from U.S. power plants owing to switch from coal to natural gas with combined cycle technology

    NASA Astrophysics Data System (ADS)

    de Gouw, J. A.; Parrish, D. D.; Frost, G. J.; Trainer, M.

    2014-02-01

    Since 1997, an increasing fraction of electric power has been generated from natural gas in the United States. Here we use data from continuous emission monitoring systems (CEMS), which measure emissions at the stack of most U.S. electric power generation units, to investigate how this switch affected the emissions of CO2, NOx, and SO2. Per unit of energy produced, natural gas power plants equipped with combined cycle technology emit on an average 44% of the CO2 compared with coal power plants. As a result of the increased use of natural gas, CO2 emissions from U.S. fossil-fuel power plants were 23% lower in 2012 than they would have been if coal had continued to provide the same fraction of electric power as in 1997. In addition, natural gas power plants with combined cycle technology emit less NOx and far less SO2 per unit of energy produced than coal power plants. Therefore, the increased use of natural gas has led to emission reductions of NOx (40%) and SO2 (44%), in addition to those obtained from the implementation of emission control systems on coal power plants. These benefits to air quality and climate should be weighed against the increase in emissions of methane, volatile organic compounds, and other trace gases that are associated with the production, processing, storage, and transport of natural gas.

  16. Fire emission rates of NOx based on the empirical relationship between satellite-derived tropospheric NO2 and fire radiative power

    NASA Astrophysics Data System (ADS)

    Schreier, S. F.; Richter, A.; Kaiser, J. W.; Burrows, J. P.

    2013-11-01

    Nitrogen oxides (NOx) play key roles in atmospheric chemistry, air pollution, and climate. While the largest fraction of these reactive gases is released by anthropogenic emission sources, a significant amount can be attributed to vegetation fires. In this study, NO2 from GOME-2 on board EUMETSAT's MetOp-A and OMI on board NASA's Aura as well as fire radiative power (FRP) from the measurements of MODIS on board NASA's Terra and Aqua are used to derive fire emission rates (FERs) of NOx for different types of vegetation using a simple statistical approach. Monthly means of tropospheric NO2 vertical columns (TVC NO2) have been analyzed for their temporal correlation with the monthly means of FRP for five consecutive years from 2007 to 2011 on a horizontal 1° × 1° grid. The strongest correlation is found to be largely confined to tropical and subtropical regions, which account for more than 80% of yearly burned area on average globally. In these regions, the seasonal variation of fire intensity, expressed by the FRP data, is similar to the pattern of TVC NO2. As chemical models typically require values for the amount of NOx being released as a function of time, we have converted the retrieved TVC NO2 into production rates of NOx from fire (Pf) by assuming a constant lifetime of NOx. The comparison between Pf and NOx emissions from GFEDv3.1 over 5 characteristic biomass burning regions in the tropics and subtropics indicated good agreement. By separating the monthly means of Pf and FRP according to land cover type, FERs of NOx could be derived for different biomes. The estimated FERs for the dominating types of vegetation burned are lowest for open shrublands and savannas (0.28-1.03 g NOx s-1 MW-1) and highest for croplands and woody savannas (0.82-1.56 g NOx s-1 MW-1). This analysis demonstrates clearly that there are biome-specific, diurnal, and regional differences in FERs for the dominating types of vegetation burned in the tropics and subtropics. Possible

  17. Estimation of NOx emissions from the Megacity of Lahore, Pakistan using car MAX-DOAS observations and comparison with OMI satellite data

    NASA Astrophysics Data System (ADS)

    Razi, Maria; Shaiganfar, Reza; Fahim Khokhar, Muhammad; Dörner, Steffen; Ahmad, Noor; Donner, Sebastian; Beirle, Steffen; Wagner, Thomas

    2016-04-01

    Lahore is a metropolitan city of Pakistan with about more than 10 million inhabitants and thus a strong emission source of atmospheric pollutants. The quantification of these emission sources is usually accomplished by so-called bottom-up inventories, based on the summation of the emissions of individual emission sources for all relevant emission categories. Such inventories are subject to large errors because of uncertainties in the emission estimates for individual sources as well as their numbers and characteristics. Here we present results of a top-down emission inventory for Lahore based on car multi-axis differential optical absorption spectroscopy (car-MAX-DOAS) observations. We performed such measurements around the city on Lahore on six days in December 2015. From the measured spectra we derive the vertically integrated concentration of NO2 along the driving route (the so called tropospheric vertical column density, VCD). By combining these observations with wind data we estimate the total NO2 emissions from the city of Lahore. Since from the measured spectra only NO2 (but not NO) can be retrieved, we convert the NO2 emissions to total NOx (NO2 plus NO) emissions. We also apply corrections for the decay of NOx on the way between the emission source and the location of the measurements. We compare the derived NOx emissions to existing emission inventories. We also compare the spatial distributions of the tropospheric NO2 VCDs observed by car MAX-DOAS with collocated results from satellite observations of the Ozone Monitoring Instrument (OMI).

  18. Analysis of the CO2, NOx emission and fuel consumption from a heavy-duty vehicle designed for carriage of timber

    NASA Astrophysics Data System (ADS)

    Fuc, P.; Lijewski, P.; Ziolkowski, A.

    2016-09-01

    The paper presents the results of measurements of the CO2 and NOx emission and fuel consumption recorded under actual operating conditions of a heavy-duty vehicle designed for loading and carriage of timber. The tests were performed on a specially designed test route that reflected the arrival of the vehicle to the felling site in the forest, the loading process and return to the lumberyard. The route ran through paved (asphalt) and unpaved (forest) portions. Its total length was 8.6 km. An advanced PEMS (Portable Emission Measurement System) device was used for the measurement of the exhaust emissions - SEMTECH DS by Sensors Inc. The paper analyses the CO2 and NOx emission and fuel consumption on all portions of the test route and presents a comparison between the forest and asphalt roads.

  19. The Observed Response of Ozone Monitoring Instrument (OMI) NO2 Columns to NOx Emission Controls on Power Plants in the United States: 2005-2011

    NASA Technical Reports Server (NTRS)

    Duncan, Bryan N.; Yoshida, Yasuko; deFoy, Benjamin; Lamsal, Lok N.; Streets, David G.; Lu, Zifeng; Pickering, Kenneth E.; Krotkov, Nickolay A.

    2013-01-01

    We show that Aura Ozone Monitoring Instrument (OMI) nitrogen dioxide (NO2) tropospheric column data may be used to assess changes of the emissions of nitrogen oxides (NOx) from power plants in the United States, though careful interpretation of the data is necessary. There is a clear response for OMI NO2 data to NOx emission reductions from power plants associated with the implementation of mandated emission control devices (ECDs) over the OMI record (2005e2011). This response is scalar for all intents and purposes, whether the reduction is rapid or incremental over several years. However, it is variable among the power plants, even for those with the greatest absolute decrease in emissions. We document the primary causes of this variability, presenting case examples for specific power plants.

  20. Extractive sampling and optical remote sensing of F100 aircraft engine emissions.

    PubMed

    Cowen, Kenneth; Goodwin, Bradley; Joseph, Darrell; Tefend, Matthew; Satola, Jan; Kagann, Robert; Hashmonay, Ram; Spicer, Chester; Holdren, Michael; Mayfield, Howard

    2009-05-01

    The Strategic Environmental Research and Development Program (SERDP) has initiated several programs to develop and evaluate techniques to characterize emissions from military aircraft to meet increasingly stringent regulatory requirements. This paper describes the results of a recent field study using extractive and optical remote sensing (ORS) techniques to measure emissions from six F-15 fighter aircraft. Testing was performed between November 14 and 16, 2006 on the trim-pad facility at Tyndall Air Force Base in Panama City, FL. Measurements were made on eight different F100 engines, and the engines were tested on-wing of in-use aircraft. A total of 39 test runs were performed at engine power levels that ranged from idle to military power. The approach adopted for these tests involved extractive sampling with collocated ORS measurements at a distance of approximately 20-25 nozzle diameters downstream of the engine exit plane. The emission indices calculated for carbon dioxide, carbon monoxide, nitric oxide, and several volatile organic compounds showed very good agreement when comparing the extractive and ORS sampling methods.

  1. Composition and morphology of particle emissions from in-use aircraft during takeoff and landing.

    PubMed

    Mazaheri, Mandana; Bostrom, Thor E; Johnson, Graham R; Morawska, Lidia

    2013-05-21

    In order to provide realistic data for air pollution inventories and source apportionment at airports, the morphology and composition of ultrafine particles (UFP) in aircraft engine exhaust were measured and characterized. For this purpose, two independent measurement techniques were employed to collect emissions during normal takeoff and landing operations at Brisbane Airport, Australia. PM1 emissions in the airfield were collected on filters and analyzed using the particle-induced X-ray emission (PIXE) technique. Morphological and compositional analyses of individual ultrafine particles in aircraft plumes were performed on silicon nitride membrane grids using transmission electron microscopy (TEM) combined with energy-dispersive X-ray microanalysis (EDX). TEM results showed that the deposited particles were in the range of 5-100 nm in diameter, had semisolid spherical shapes and were dominant in the nucleation mode (18-20 nm). The EDX analysis showed the main elements in the nucleation particles were C, O, S, and Cl. The PIXE analysis of the airfield samples was generally in agreement with the EDX in detecting S, Cl, K, Fe, and Si in the particles. The results of this study provide important scientific information on the toxicity of aircraft exhaust and their impact on local air quality.

  2. Accurate Measurements of Aircraft Engine Soot Emissions Using a CAPS PMssa Monitor

    NASA Astrophysics Data System (ADS)

    Onasch, Timothy; Thompson, Kevin; Renbaum-Wolff, Lindsay; Smallwood, Greg; Make-Lye, Richard; Freedman, Andrew

    2016-04-01

    We present results of aircraft engine soot emissions measurements during the VARIAnT2 campaign using CAPS PMssa monitors. VARIAnT2, an aircraft engine non-volatile particulate matter (nvPM) emissions field campaign, was focused on understanding the variability in nvPM mass measurements using different measurement techniques and accounting for possible nvPM sampling system losses. The CAPS PMssa monitor accurately measures both the optical extinction and scattering (and thus single scattering albedo and absorption) of an extracted sample using the same sample volume for both measurements with a time resolution of 1 second and sensitivity of better than 1 Mm-1. Absorption is obtained by subtracting the scattering signal from the total extinction. Given that the single scattering albedo of the particulates emitted from the aircraft engine measured at both 630 and 660 nm was on the order of 0.1, any inaccuracy in the scattering measurement has little impact on the accuracy of the ddetermined absorption coefficient. The absorption is converted into nvPM mass using a documented Mass Absorption Coefficient (MAC). Results of soot emission indices (mass soot emitted per mass of fuel consumed) for a turbojet engine as a function of engine power will be presented and compared to results obtained using an EC/OC monitor.

  3. Impact of aircraft emissions on air quality in the vicinity of airports. Volume I. Recent airport measurement programs, data analyses, and sub-model development. Final report Jan78-Jul 80

    SciTech Connect

    Yamartino, R.J.; Smith, D.G.; Bremer, S.A.; Heinold, D.; Lamich, D.

    1980-07-01

    This report documents the results of the Federal Aviation Administration (FAA)/Environmental Protection Agency (EPA) air quality study which has been conducted to assess the impact of aircraft emissions of carbon monoxide (CO), hydrocarbons (HC), and oxides of nitrogen (NOx) in the vicinity of airports. This assessment includes the results of recent modeling and monitoring efforts at Washington National (DCA), Los Angeles International (LAX), Dulles International (IAD), and Lakeland, Florida airports and an updated modeling of aircraft generated pollution at LAX, John F. Kennedy (JFK) and Chicago O'Hare (ORD) airports. The Airport Vicinity Air Pollution (AVAP) model which was designed for use at civil airports was used in this assessment. In addition the results of the application of the military version of the AVAP model the Air Quality Assessment Model (AQAM), are summarized.

  4. Nonintrusive optical measurements of aircraft engine exhaust emissions and comparison with standard intrusive techniques.

    PubMed

    Schäfer, K; Heland, J; Lister, D H; Wilson, C W; Howes, R J; Falk, R S; Lindermeir, E; Birk, M; Wagner, G; Haschberger, P; Bernard, M; Legras, O; Wiesen, P; Kurtenbach, R; Brockmann, K J; Kriesche, V; Hilton, M; Bishop, G; Clarke, R; Workman, J; Caola, M; Geatches, R; Burrows, R; Black, J D; Hervé, P; Vally, J

    2000-01-20

    Nonintrusive systems for the measurement on test rigs of aeroengine exhaust emissions required for engine certification (CO, NO(x), total unburned hydrocarbon, and smoke), together with CO(2) and temperature have been developed. These results have been compared with current certified intrusive measurements on an engine test. A spectroscopic database and data-analysis software has been developed to enable Fourier-transform Infrared measurement of concentrations of molecular species. CO(2), CO, and NO data showed agreement with intrusive techniques of approximately ?30%. A narrow-band spectroscopic device was used to measure CO(2) (with deviations of less than ?10% from the intrusive measurement), whereas laser-induced incandescence was used to measure particles. Future improvements to allow for the commercial use of the nonintrusive systems have been identified and the methods are applicable to any measurement of combustion emissions.

  5. Methodology to estimate particulate matter emissions from certified commercial aircraft engines.

    PubMed

    Wayson, Roger L; Fleming, Gregg G; Lovinelli, Ralph

    2009-01-01

    Today, about one-fourth of U.S. commercial service airports, including 41 of the busiest 50, are either in nonattainment or maintenance areas per the National Ambient Air Quality Standards. U.S. aviation activity is forecasted to triple by 2025, while at the same time, the U.S. Environmental Protection Agency (EPA) is evaluating stricter particulate matter (PM) standards on the basis of documented human health and welfare impacts. Stricter federal standards are expected to impede capacity and limit aviation growth if regulatory mandated emission reductions occur as for other non-aviation sources (i.e., automobiles, power plants, etc.). In addition, strong interest exists as to the role aviation emissions play in air quality and climate change issues. These reasons underpin the need to quantify and understand PM emissions from certified commercial aircraft engines, which has led to the need for a methodology to predict these emissions. Standardized sampling techniques to measure volatile and nonvolatile PM emissions from aircraft engines do not exist. As such, a first-order approximation (FOA) was derived to fill this need based on available information. FOA1.0 only allowed prediction of nonvolatile PM. FOA2.0 was a change to include volatile PM emissions on the basis of the ratio of nonvolatile to volatile emissions. Recent collaborative efforts by industry (manufacturers and airlines), research establishments, and regulators have begun to provide further insight into the estimation of the PM emissions. The resultant PM measurement datasets are being analyzed to refine sampling techniques and progress towards standardized PM measurements. These preliminary measurement datasets also support the continued refinement of the FOA methodology. FOA3.0 disaggregated the prediction techniques to allow for independent prediction of nonvolatile and volatile emissions on a more theoretical basis. The Committee for Aviation Environmental Protection of the International Civil

  6. Speciation and chemical evolution of nitrogen oxides in aircraft exhaust near airports.

    PubMed

    Wood, Ezra C; Herndon, Scott C; Timko, Michael T; Yelvington, Paul E; Miake-Lye, Richard C

    2008-03-15

    Measurements of nitrogen oxides from a variety of commercial aircraft engines as part of the JETS-APEX2 and APEX3 campaigns show that NOx (NOx [triple bond] NO + NO2) is emitted primarily in the form of NO2 at idle thrust and NO at high thrust. A chemical kinetics combustion model reproduces the observed NO2 and NOx trends with engine power and sheds light on the relevant chemical mechanisms. Experimental evidence is presented of rapid conversion of NO to NO2 in the exhaust plume from engines at low thrust. The rapid conversion and the high NO2/NOx emission ratios observed are unrelated to ozone chemistry. NO2 emissions from a CFM56-3B1 engine account for approximately 25% of the NOx emitted below 3000 feet (916 m) and 50% of NOx emitted below 500 feet (153 m) during a standard ICAO (International Civil Aviation Organization) landing-takeoff cycle. Nitrous acid (HONO) accounts for 0.5% to 7% of NOy emissions from aircraft exhaust depending on thrust and engine type. Implications for photochemistry near airports resulting from aircraft emissions are discussed.

  7. Evaluation of mass balance, 4D-Var, and hybrid approaches to constraining NOx emissions using OMI NO2 remote sensing measurements.

    NASA Astrophysics Data System (ADS)

    Qu, Z.

    2015-12-01

    Nitrogen oxides (NOx) contribute to photochemical smog, tropospheric ozone and aerosol, and human health problems. Remote sensing observations provide a valuable means of constraining emissions of NOx, and thus improving our ability to use air quality models for further understanding these issues. Traditional top-down estimates have provided important constraints for NOx emission inventories in China, but are either time-consuming (e.g., 4D-Var) or only crudely represent the influence of atmospheric transport and chemistry (e.g., mass balance). Here, we combine mass balance and 4D-Var approaches, and investigate the improvements in simulated NOx column density over China. Scaling factors derived from the mass balance approach with OMI observations are first applied to NOx emissions. In this process, a smoothing kernel is used to account for emissions from adjacent grid cells, and optimized NOx emissions are derived using maximum likelihood estimation, which weigh top-down and bottom up estimates by their relative errors. This is followed by subsequent inversion using an adjoint-based 4D-Var approach with GEOS-Chem at the 0.5x0.667 degree resolution. We consider the correlations between errors in neighboring grid cells by using off-diagonal terms in scaling factors' error covariance matrix. An optimal value of the regularization parameter is selected using an L-curve and minimization of total error. We compare the solutions obtained using this hybrid approach with that obtained from standard 4D-Var, as well as to the direct solution from the mass balance approach itself. Differences between these methods in specific grid cells are investigated. We demonstrate the effect of transport and chemistry on the performance of mass balance and 4D-Var, identifying cases where the smoothing kernel and weighting errors in mass balance can cause the scaling factor to be in a direction that occasionally increases residual error. This study shows potential to facilitate decadal

  8. Nitrogen oxides from high-altitude aircraft - An update of potential effects on ozone

    NASA Technical Reports Server (NTRS)

    Johnston, Harold S.; Kinnison, Douglas E.; Wuebbles, Donald J.

    1989-01-01

    In the study of fuel consumption rate by stratospheric aircraft, the range of nitric oxide injection is interpreted as an eightfold range of emission index (5-40) with both the one- and the two-dimensional models. Possible effects of future aircraft NO(x) emissions on stratospheric ozone are considered for a broad range in magnitude, altitude, and latitude of the assumed NO(x) emissions. Results of the sensitivity studies using both models are discussed. Large ozone reductions are found to be outside the expected range of validity of these models and are to be anticipated if there should be a large fleet of stratospheric aircraft with NO(x) emission characteristics of current commercial aircraft. Under the test conditions, a global ozone reduction of about 9 percent is estimated for a jet engine emission index of 15 in both models. If engines are redesigned to reduce the emission index to the NASA goal of 5, global average ozone reductions are between 2 and 3 percent, and those of the Northern Hemisphere are about 4 percent. The effects of stratospheric aircraft on ozone could be further reduced through operation at lower altitudes, reduction of aircraft, and efficient fuel consumption.

  9. Using hydroponic biomass to regulate NOx emissions in long range space travel

    SciTech Connect

    Xu, X.H.; Shi, Y.; Chang, S.G.; Fisher, J.; Pisharody, S.; Moran, M.; Wignarajah, K.

    2002-02-01

    The incineration of wastes is one of the most promising reclamation technologies being developed for life support in long range space travel. However, incineration in a closed environment will build up hazardous NOx if not regulated. A technology that can remove NOx under microgravity conditions without the need of expendables is required. Activated carbon prepared from inedible wheat straw and sweet potato stalk that were grown under hydroponic conditions has been demonstrated to be able to adsorb NO and reduce it to N{sub 2}. The high mineral content in the activated carbon prepared from hydroponic biomass prohibits high surface area production and results in inferior NO adsorption capacity. The removal of mineral from the carbon circumvents the aforementioned negative effect. The optimal production conditions to obtain maximum yield and surface area for the activated carbon have been determined. A parametric study on the NO removal efficiency by the activated carbon has been done. The presence of oxygen in flue gas is essential for effective adsorption of NO by the activated carbon. On the contrary, water vapor inhibits the adsorption efficiency of NO. The NO adsorption capacity and the duration before it exceeds the Space Maximum Allowable Concentration were determined. After the adsorption of NO, the activated carbon can be regenerated for reuse by heating the carbon bed under anaerobic conditions to above 500 C, when the adsorbed NO is reduced to N{sub 2}. The regenerated activated carbon exhibits improved NO adsorption efficiency. However, regeneration had burned off a small percentage of the activated carbon.

  10. Improving combustion characteristics and NO(x) emissions of a down-fired 350 MW(e) utility boiler with multiple injection and multiple staging.

    PubMed

    Kuang, Min; Li, Zhengqi; Xu, Shantian; Zhu, Qunyi

    2011-04-15

    Within a Mitsui Babcock Energy Limited down-fired pulverized-coal 350 MW(e) utility boiler, in situ experiments were performed, with measurements taken of gas temperatures in the burner and near the right-wall regions, and of gas concentrations (O(2) and NO) from the near-wall region. Large combustion differences between zones near the front and rear walls and particularly high NO(x) emissions were found in the boiler. With focus on minimizing these problems, a new technology based on multiple-injection and multiple-staging has been developed. Combustion improvements and NO(x) reductions were validated by investigating three aspects. First, numerical simulations of the pulverized-coal combustion process and NO(x) emissions were compared in both the original and new technologies. Good agreement was found between simulations and in situ measurements with the original technology. Second, with the new technology, gas temperature and concentration distributions were found to be symmetric near the front and rear walls. A relatively low-temperature and high-oxygen-concentration zone formed in the near-wall region that helps mitigate slagging in the lower furnace. Third, NO(x) emissions were found to have decreased by as much as 50%, yielding a slight decrease in the levels of unburnt carbon in the fly ash.

  11. Influence of the overfire air ratio on the NO(x) emission and combustion characteristics of a down-fired 300-MW(e) utility boiler.

    PubMed

    Ren, Feng; Li, Zhengqi; Chen, Zhichao; Fan, Subo; Liu, Guangkui

    2010-08-15

    Down-fired boilers used to burn low-volatile coals have high NO(x) emissions. To find a way of solving this problem, an overfire air (OFA) system was introduced on a 300 MW(e) down-fired boiler. Full-scale experiments were performed on this retrofitted boiler to explore the influence of the OFA ratio (the mass flux ratio of OFA to the total combustion air) on the combustion and NO(x) emission characteristics in the furnace. Measurements were taken of gas temperature distributions along the primary air and coal mixture flows, average gas temperatures along the furnace height, concentrations of gases such as O(2), CO, and NO(x) in the near-wall region and carbon content in the fly ash. Data were compared for five different OFA ratios. The results show that as the OFA ratio increases from 12% to 35%, the NO(x) emission decreases from 1308 to 966 mg/Nm(3) (at 6% O(2) dry) and the carbon content in the fly ash increases from 6.53% to 15.86%. Considering both the environmental and economic effect, 25% was chosen as the optimized OFA ratio.

  12. Effects of a combined Diesel particle filter-DeNOx system (DPN) on reactive nitrogen compounds emissions: a parameter study.

    PubMed

    Heeb, Norbert V; Haag, Regula; Seiler, Cornelia; Schmid, Peter; Zennegg, Markus; Wichser, Adrian; Ulrich, Andrea; Honegger, Peter; Zeyer, Kerstin; Emmenegger, Lukas; Zimmerli, Yan; Czerwinski, Jan; Kasper, Markus; Mayer, Andreas

    2012-12-18

    The impact of a combined diesel particle filter-deNO(x) system (DPN) on emissions of reactive nitrogen compounds (RNCs) was studied varying the urea feed factor (α), temperature, and residence time, which are key parameters of the deNO(x) process. The DPN consisted of a platinum-coated cordierite filter and a vanadia-based deNO(x) catalyst supporting selective catalytic reduction (SCR) chemistry. Ammonia (NH₃) is produced in situ from thermolysis of urea and hydrolysis of isocyanic acid (HNCO). HNCO and NH₃ are both toxic and highly reactive intermediates. The deNO(x) system was only part-time active in the ISO8178/4 C1cycle. Urea injection was stopped and restarted twice. Mean NO and NO₂ conversion efficiencies were 80%, 95%, 97% and 43%, 87%, 99%, respectively, for α = 0.8, 1.0, and 1.2. HNCO emissions increased from 0.028 g/h engine-out to 0.18, 0.25, and 0.26 g/h at α = 0.8, 1.0, and 1.2, whereas NH₃ emissions increased from <0.045 to 0.12, 1.82, and 12.8 g/h with maxima at highest temperatures and shortest residence times. Most HNCO is released at intermediate residence times (0.2-0.3 s) and temperatures (300-400 °C). Total RNC efficiencies are highest at α = 1.0, when comparable amounts of reduced and oxidized compounds are released. The DPN represents the most advanced system studied so far under the VERT protocol achieving high conversion efficiencies for particles, NO, NO₂, CO, and hydrocarbons. However, we observed a trade-off between deNO(x) efficiency and secondary emissions. Therefore, it is important to adopt such DPN technology to specific application conditions to take advantage of reduced NO(x) and particle emissions while avoiding NH₃ and HNCO slip.

  13. Aircraft mass budgeting to measure CO2 emissions of Rome, Italy.

    PubMed

    Gioli, Beniamino; Carfora, Maria F; Magliulo, Vincenzo; Metallo, Maria C; Poli, Attilio A; Toscano, Piero; Miglietta, Franco

    2014-04-01

    Aircraft measurements were used to estimate the CO2 emission rates of the city of Rome, assessed against high-resolution inventorial data. Three experimental flights were made, composed of vertical soundings to measure Planetary Boundary Layer (PBL) properties, and circular horizontal transects at various altitudes around the city area. City level emissions and associated uncertainties were computed by means of mass budgeting techniques, obtaining a positive net CO2 flux of 14.7 ± 4.5, 2.5 ± 1.2, and 10.3 ± 1.2 μmol m(-2) s(-1) for the three flights. Inventorial CO2 fluxes at the time of flights were computed by means of spatial and temporal disaggregation of the gross emission inventory, at 10.9 ± 2.5, 9.6 ± 1.3, and 17.4 ± 9.6 μmol m(-2) s(-1). The largest differences between the two dataset are associated with a greater variability of wind speed and direction in the boundary layer during measurements. Uncertainty partitioned into components related to horizontal boundary flows and top surface flow, revealed that the latter dominates total uncertainty in the presence of a wide variability of CO2 concentration in the free troposphere (up to 7 ppm), while it is a minor term with uniform tropospheric concentrations in the study area (within 2 ppm). Overall, we demonstrate how small aircraft may provide city level emission measurements that may integrate and validate emission inventories. Optimal atmospheric conditions and measurement strategies for the deployment of aircraft experimental flights are finally discussed.

  14. NO2 columns in the western United States observed from space and simulated by a regional chemistry model and their implications for NOx emissions

    NASA Astrophysics Data System (ADS)

    Kim, S.-W.; Heckel, A.; Frost, G. J.; Richter, A.; Gleason, J.; Burrows, J. P.; McKeen, S.; Hsie, E.-Y.; Granier, C.; Trainer, M.

    2009-06-01

    There are many isolated sources of NOx emissions across the western United States, including electrical power generation plants and urban areas. In this manuscript, two satellite instruments measuring NO2 vertical columns over these sources and an atmospheric chemical-transport model are used to evaluate bottom-up NOx emission inventories, model assumptions, and satellite retrieval algorithms. We carried out simulations with the Weather Research and Forecasting-Chemistry (WRF-Chem) model for the western U.S. domain during the summer of 2005 using measured power plant NOx emissions. Model NO2 vertical columns are compared with a retrieval of the Scanning Imaging Absorption Spectrometer for Atmospheric Chartography (SCIAMACHY) satellite instrument data by the University of Bremen and retrievals of the Ozone Monitoring Instrument (OMI) data by the U.S. National Aeronautics and Space Administration (NASA) and a modified version of the NASA OMI retrieval produced by the University of Bremen. For areas dominated by power plant NOx emissions, the model NO2 columns serve as a comparison standard for satellite retrievals because emissions are continuously monitored at all large U.S. power plants. An extensive series of sensitivity tests of the assumptions in both the satellite retrievals and the model are carried out over the Four Corners and San Juan power plants, two adjacent facilities in the northwest corner of New Mexico that together represent the largest NOx point source in the United States. Overall, the SCIAMACHY and OMI NO2 columns over western U.S. power plants agree well with model NO2 columns, with differences between the two being within the variability of the model and satellite. In contrast to regions dominated by power plant emissions, model NO2 columns over large urban areas along the U.S. west coast are approximately twice as large as satellite NO2 columns from SCIAMACHY and OMI retrievals. The discrepancies in urban areas are beyond the sensitivity

  15. Systematic Field Study of NO(x) Emission Control Methods for Utility Boilers.

    ERIC Educational Resources Information Center

    Bartok, William; And Others

    A utility boiler field test program was conducted. The objectives were to determine new or improved NO (x) emission factors by fossil fuel type and boiler design, and to assess the scope of applicability of combustion modification techniques for controlling NO (x) emissions from such installations. A statistically designed test program was…

  16. 40 CFR 60.4380 - How are excess emissions and monitor downtime defined for NOX?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false How are excess emissions and monitor... (CONTINUED) AIR PROGRAMS (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Stationary Combustion Turbines Reporting § 60.4380 How are excess emissions and...

  17. Chemical characterization of the fine particle emissions from commercial aircraft engines during the Aircraft Particle Emissions eXperiment (APEX) 1 to 3.

    PubMed

    Kinsey, J S; Hays, M D; Dong, Y; Williams, D C; Logan, R

    2011-04-15

    This paper addresses the need for detailed chemical information on the fine particulate matter (PM) generated by commercial aviation engines. The exhaust plumes of seven turbofan engine models were sampled as part of the three test campaigns of the Aircraft Particle Emissions eXperiment (APEX). In these experiments, continuous measurements of black carbon (BC) and particle surface-bound polycyclic aromatic compounds (PAHs) were conducted. In addition, time-integrated sampling was performed for bulk elemental composition, water-soluble ions, organic and elemental carbon (OC and EC), and trace semivolatile organic compounds (SVOCs). The continuous BC and PAH monitoring showed a characteristic U-shaped curve of the emission index (EI or mass of pollutant/mass of fuel burned) vs fuel flow for the turbofan engines tested. The time-integrated EIs for both elemental composition and water-soluble ions were heavily dominated by sulfur and SO(4)(2-), respectively, with a ∼2.4% median conversion of fuel S(IV) to particle S(VI). The corrected OC and EC emission indices obtained in this study ranged from 37 to 83 mg/kg and 21 to 275 mg/kg, respectively, with the EC/OC ratio ranging from ∼0.3 to 7 depending on engine type and test conditions. Finally, the particle SVOC EIs varied by as much as 2 orders of magnitude with distinct variations in chemical composition observed for different engine types and operating conditions.

  18. Chemical characterization of the fine particle emissions from commercial aircraft engines during the Aircraft Particle Emissions eXperiment (APEX) 1 to 3.

    PubMed

    Kinsey, J S; Hays, M D; Dong, Y; Williams, D C; Logan, R

    2011-04-15

    This paper addresses the need for detailed chemical information on the fine particulate matter (PM) generated by commercial aviation engines. The exhaust plumes of seven turbofan engine models were sampled as part of the three test campaigns of the Aircraft Particle Emissions eXperiment (APEX). In these experiments, continuous measurements of black carbon (BC) and particle surface-bound polycyclic aromatic compounds (PAHs) were conducted. In addition, time-integrated sampling was performed for bulk elemental composition, water-soluble ions, organic and elemental carbon (OC and EC), and trace semivolatile organic compounds (SVOCs). The continuous BC and PAH monitoring showed a characteristic U-shaped curve of the emission index (EI or mass of pollutant/mass of fuel burned) vs fuel flow for the turbofan engines tested. The time-integrated EIs for both elemental composition and water-soluble ions were heavily dominated by sulfur and SO(4)(2-), respectively, with a ∼2.4% median conversion of fuel S(IV) to particle S(VI). The corrected OC and EC emission indices obtained in this study ranged from 37 to 83 mg/kg and 21 to 275 mg/kg, respectively, with the EC/OC ratio ranging from ∼0.3 to 7 depending on engine type and test conditions. Finally, the particle SVOC EIs varied by as much as 2 orders of magnitude with distinct variations in chemical composition observed for different engine types and operating conditions. PMID:21428391

  19. Measurements of nitrous acid in commercial