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Sample records for airs atmospheric infrared

  1. AIRS - the Atmospheric Infrared Sounder

    NASA Technical Reports Server (NTRS)

    Lambrigsten, Bjorn H.; Fetzer, Eric; Fishbein, Evan; Lee, Sung-Yung; Paganao, Thomas

    2004-01-01

    The Atmospheric Infrared Sounder (AIRS) was launched in 2002, along with two companion microwave sounders. This AIRS sounding suite is the most advanced atmospheric sounding system to date, with measurement accuracies far surpassing those of current weather satellites. From its sun synchronous polar orbit, the AIRS system provides more than 90% of the globe every 24 hours. Much of the post-launch period has been devoted to optimizing the 'retrieval' system used to derive atmospheric and other parameters from the observations and to validate those parameters. The geophysical parameters have been produced since the beginning of 2003 - the first data were released to the public in mid-2003, and future improved versions will be released periodically. The ongoing calibration/validation effort has confirmed that the system is very accurate and stable. There are a number of applications for the AIRS products, ranging from numerical weather prediction - where positive impact on forecast accuracy has already been demonstrated, to atmospheric research - where the AIRS water vapor products near the surface and in the mid and upper troposphere as well as in the stratosphere promise to make it possible to characterize and model phenomena that are key for short-term atmospheric processes, from weather patterns to long-term processes, such as interannual variability and climate change.

  2. Application of Atmospheric Infrared Sounder (AIRS) Data to Climate Research

    NASA Technical Reports Server (NTRS)

    Aumann, Hartmut H.; Gregorich, David; Gaiser, Steve; Chahine, Moustafa T.

    2004-01-01

    The application of hyper spectral radiometric data to climate research requires very high absolute radiometric accuracy and stability. We use cloud-free tropical ocean data from the Atmospheric InfraRed Sounder (AIR) Calibration Data Subset (ADCS) to show that the radiometric precision and stability required climate applications has been achieved. The sea surface skin temperatures derived from the AIRS 2616cm-1 super window channel are stable relative to the RTG.SST at the better than 8 mK/year level, and the spectral calibration is stable at the 1 ppm/year level. The excellent stability and accuracy are the result of the implementation of AIRS as a grating array spectrometer, which is cooled and stabilized within 10 mK at 155 K. Analysis of daily measurements of the temperature gradient between the surface and 7 km altitude show that the AIRS Calibration Data Subset has applications which extend its original intent for calibration support to climate research. The Atmospheric Infrared Sounder (AIRS) on the EOS Aqua satellite was launched into polar orbit in May 2002. AIRS covers the spectral region from 640 to 2700 cm-1 with 2378 independent channels and represents the first of a new generation of hyper spectral resolution sounders in support of global sounding data for weather forecasting and climate research.

  3. Sensitivity Analysis for Atmospheric Infrared Sounder (AIRS) CO2 Retrieval

    NASA Technical Reports Server (NTRS)

    Gat, Ilana

    2012-01-01

    The Atmospheric Infrared Sounder (AIRS) is a thermal infrared sensor able to retrieve the daily atmospheric state globally for clear as well as partially cloudy field-of-views. The AIRS spectrometer has 2378 channels sensing from 15.4 micrometers to 3.7 micrometers, of which a small subset in the 15 micrometers region has been selected, to date, for CO2 retrieval. To improve upon the current retrieval method, we extended the retrieval calculations to include a prior estimate component and developed a channel ranking system to optimize the channels and number of channels used. The channel ranking system uses a mathematical formalism to rapidly process and assess the retrieval potential of large numbers of channels. Implementing this system, we identifed a larger optimized subset of AIRS channels that can decrease retrieval errors and minimize the overall sensitivity to other iridescent contributors, such as water vapor, ozone, and atmospheric temperature. This methodology selects channels globally by accounting for the latitudinal, longitudinal, and seasonal dependencies of the subset. The new methodology increases accuracy in AIRS CO2 as well as other retrievals and enables the extension of retrieved CO2 vertical profiles to altitudes ranging from the lower troposphere to upper stratosphere. The extended retrieval method for CO2 vertical profile estimation using a maximum-likelihood estimation method. We use model data to demonstrate the beneficial impact of the extended retrieval method using the new channel ranking system on CO2 retrieval.

  4. Regional Assimilation of NASA Atmospheric Infrared Sounder (AIRS) Data

    NASA Technical Reports Server (NTRS)

    Chou, Shih-Hung; Lapenta, William; Jediovec, Gary J.; McCarty, William; Mecikalski, John R.

    2004-01-01

    The NASA Short-term Prediction Research and Transition (SPORT) Center seeks to accelerate the infusion of NASA Earth Science Enterprise (ESE) observations, data assimilation and modeling research into NW S forecast operations and decision-making. The Atmospheric Infrared Sounder (AIRS), is expected to advance climate research and weather prediction into the 21 st century. It is one of six instruments onboard Aqua, a satellite that is part of NASA s Earth Observing System. AIRS, along with two partner microwave sounding instruments, represents the most advanced atmospheric sounding system ever deployed in space. The system is capable of measuring the atmospheric temperature in the troposphere with radiosonde accuracies of 1 K over 1 km-thick layers under both clear and cloudy conditions, while the accuracy of the derived moisture profiles will exceed that obtained by radiosondes. It is imperative that the scientific community is prepared to take full advantage of next-generation satellite data that will become available within the next decade. The purpose of this paper is to describe a procedure designed to optimally assimilate AIRS data at high spatial resolution over both land and ocean. The assimilation system used in this study is the Local Analysis and Prediction System (LAPS) developed at the Forecast System Laboratory used extensively around the globe. Results will focus on quality control issues associated with AIRS, optimal assimilation strategies, and the impact of the AIRS data on subsequent numerical forecasts at 12 km produced by the next generation Weather Research and Forecast (WRF) model.

  5. Development of Level 3 (gridded) products for the Atmospheric Infrared Sounder (AIRS)

    NASA Technical Reports Server (NTRS)

    Granger, Stephanie L.; Leroy, Stephen S.; Manning, Evan M.; Fetzer, Eric J.; Oliphant, Robert B.; Braverman, Amy; Lee, Sung-Yung; Lambrigtsen, Bjom H.

    2004-01-01

    The Atmospheric Infrared Sounder (AIRS) sounding system is a suite of infrared and microwave instruments flown as part of NASA's Earth Observing System (EOS) onboard the Aqua platform. The AIRS dataset provides a daily, global view of Earth processes at a finer vertical resolution than ever before. However, analysis of the AIRS data is a daunting task given the sheer volume and complexity of the data. The volume of data produced by the EOS project is unprecedented; the AIRS project alone will produce many terabytes of data over the lifetime of the mission. This paper describes development of AIRS Level 3 data products that will help to alleviate problems of access and usability.

  6. Tropical Storm Beryl as Observed by NASA's Spaceborne Atmospheric Infrared Sounder (AIRS)

    NASA Technical Reports Server (NTRS)

    2006-01-01

    [figure removed for brevity, see original site] Figure 1: AIRS Microwave Image

    This is an infrared image of Tropical Storm Beryl in the western Atlantic, from the Atmospheric Infrared Sounder (AIRS) on NASA's Aqua satellite on July 20, 2006, 1:30 am local time. This AIRS image shows the temperature of the cloud tops or the surface of the Earth in cloud-free regions. The lowest temperatures (in purple) are associated with high, cold cloud tops that make up the top of the hurricane. The infrared signal does not penetrate through clouds. Where there are no clouds the AIRS instrument reads the infrared signal from the surface of the Earth, revealing warmer temperatures (red). This infrared image shows three large regions of strong convection surrounding the core of the storm. The largest, on the northern edge of the core, also appears in the companion microwave image to contain intense precipitation.

    The image in figure 1 is created from microwave radiation emitted by Earth's atmosphere and received by the instrument. It shows where the heaviest rainfall is taking place (in blue) in the storm. Blue areas outside of the tropical storm, where there are either some clouds or no clouds indicate where the sea surface shines through.

    The Atmospheric Infrared Sounder Experiment, with its visible, infrared, and microwave detectors, provides a three-dimensional look at Earth's weather. Working in tandem, the three instruments can make simultaneous observations all the way down to the Earth's surface, even in the presence of heavy clouds. With more than 2,000 channels sensing different regions of the atmosphere, the system creates a global, 3-D map of atmospheric temperature and humidity and provides information on clouds, greenhouse gases, and many other atmospheric phenomena. The AIRS Infrared Sounder Experiment flies onboard NASA's Aqua spacecraft and is managed by NASA's Jet Propulsion Laboratory, Pasadena, Calif., under contract to NASA. JPL is a

  7. Improved Products for Assimilation and Model Validation from the Atmospheric Infrared Sounder (AIRS) on Aqua

    NASA Technical Reports Server (NTRS)

    Pagano, Thomas S.

    2008-01-01

    The Atmospheric Infrared Sounder (AIRS) on the EOS Aqua Spacecraft was launched on May 4, 2002. AIRS acquires hyperspectral infrared radiances in the 3.7-15.4 micrometer spectral region with spectral resolution of better than 1200. Key channels from the AIRS Level 1B calibrated radiance product are currently assimilated into operational weather forecasts at NCEP and other international agencies. Additional Level 2 products for assimilation include the AIRS cloud cleared radiances and the geophysical retrieved temperature and water vapor profiles. The AIRS products are also used to validate climate model vertical and horizontal biases and transport of water vapor and key trace gases including Carbon Dioxide and Ozone. The wide variety of products available from the AIRS make it well suited to study processes affecting the interaction of these products.

  8. Science Highlights and Lessons Learned from the Atmospheric Infrared Sounder (AIRS)

    NASA Technical Reports Server (NTRS)

    Pagano, Thomas S.; Fetzer, Eric J.; Suda, Jarrod; Licata, Steve

    2011-01-01

    The Atmospheric Infrared Sounder (AIRS) and companion instrument, the Advanced Microwave Sounding Unit (AMSU) on the NASA Earth Observing System Aqua spacecraft are facility instruments designed to support measurements of atmospheric temperature, water vapor and a wide range of atmospheric constituents in support of weather forecasting and scientific research in climate and atmospheric chemistry. This paper is an update to the science highlights from a paper by the authors released last year and also looks back at the lessons learned and future needs of the scientific community. These lessons not only include requirements on the measurements, but scientific shortfalls as well. Results from the NASA Science Community Workshop in IR and MW Sounders relating to AIRS and AMSU requirements and concerns are covered and reflect much of what has been learned and what is needed for future atmospheric sounding from Low Earth Orbit.

  9. Demonstrating the Operational Value of Atmospheric Infrared Sounder (AIRS) Profiles in the Pre-Convective Environment

    NASA Technical Reports Server (NTRS)

    Kozlowski, Danielle; Zavodsky, Bradley; Stano, Geoffrey; Jedlovec, Gary

    2011-01-01

    The Short-term Prediction Research and Transition (SPoRT) is a project to transition those NASA observations and research capabilities to the weather forecasting community to improve the short-term regional forecasts. This poster reviews the work to demonstrate the value to these forecasts of profiles from the Atmospheric Infrared Sounder (AIRS) instrument on board the Aqua satellite with particular assistance in predicting thunderstorm forecasts by the profiles of the pre-convective environment.

  10. Hurricane Katrina as Observed by NASA's Spaceborne Atmospheric Infrared Sounder (AIRS)

    NASA Technical Reports Server (NTRS)

    2005-01-01

    [figure removed for brevity, see original site] Figure 1: click on image for larger AIRS microwave image

    At 1:30 a.m. local time this morning, the remnants of (now Tropical Depression) Katrina were centered on the Mississippi-Tennessee border. This microwave image from the Atmospheric Infrared Sounder instrument on NASA's Aqua spacecrat shows that the area of most intense precipitation was concentrated to the north of the center of activity.

    The infrared image shows how the storms look through an AIRS Infrared window channel. Window channels measure the temperature of the cloud tops or the surface of the Earth in cloud-free regions. The lowest temperatures are associated with high, cold cloud tops that make up the top of the hurricane. The infrared signal does not penetrate through clouds, so the purple color indicates the cool cloud tops of the storm. In cloud-free areas, the infrared signal is retrieved at the Earth's surface, revealing warmer temperatures. Cooler areas are pushing to purple and warmer areas are pushing to red.

    The microwave image (figure 1) reveals where the heaviest precipitation in the hurricane is taking place. The blue areas within the storm show the location of this heavy precipitation. Blue areas outside of the storm where there are moderate or no clouds are where the cold (in the microwave sense) sea surface shines through.

    The Atmospheric Infrared Sounder Experiment, with its visible, infrared, and microwave detectors, provides a three-dimensional look at Earth's weather. Working in tandem, the three instruments can make simultaneous observations all the way down to the Earth's surface, even in the presence of heavy clouds. With more than 2,000 channels sensing different regions of the atmosphere, the system creates a global, 3-D map of atmospheric temperature and humidity and provides information on clouds, greenhouse gases, and many other atmospheric phenomena. The AIRS Infrared Sounder Experiment flies onboard

  11. Hurricane Frances as Observed by NASA's Spaceborne Atmospheric Infrared Sounder (AIRS) and SeaWinds

    NASA Technical Reports Server (NTRS)

    2004-01-01

    This image shows Hurricane Frances as captured by instruments onboard two different satellites: the AIRS infrared instrument onboard Aqua, and the SeaWinds scatterometer onboard QuikSCAT. Both are JPL-managed instruments. AIRS data are used to create global three-dimensional maps of temperature, humidity and clouds, while scatterometers measure surface wind speed and direction over the ocean.

    The red vectors in the image show Frances' surface winds as measured by SeaWinds on QuikSCAT. The background colors show the temperature of clouds and surface as viewed in the infrared by AIRS, with cooler areas pushing to purple and warmer areas are pushing to red. The color scale on the right gives the temperatures in degrees Kelvin. (The top of the scale, 320 degrees Kelvin, corresponds to 117 degrees Fahrenheit, and the bottom, 180 degrees K is -135 degrees F.) The powerful circulation of this storm is evident from the combined data as well as the development of a clearly-defined central 'eye'. The infrared signal does not penetrate through clouds, so the light blue areas reveal the cold clouds tops associated with strong thunderstorms embedded within the storm. In cloud-free areas the infrared signal comes from Earth's surface, revealing warmer temperatures.

    The power of the SeaWinds scatterometer data set lies in its ability to generate global maps of wind speed and direction, giving us a snapshot of how the atmosphere is circulating. Weather prediction centers, including the Tropical Prediction Center - a branch of NOAA that monitors the creation of ocean-born storms, use scatterometer data to help it 'see' where these storms are brewing so that warnings can be issued and the storms, with often erratic motions, can be tracked.

    While the SeaWinds instrument isn't designed to gather hurricane data, having difficulty seeing the surface in heavy rain, it's data can be used in combination with other data sets to give us an insight into these storms. In

  12. Hurricane Alex as Observed by NASA's Spaceborne Atmospheric Infrared Sounder (AIRS)

    NASA Technical Reports Server (NTRS)

    2004-01-01

    [figure removed for brevity, see original site] Click on the image for August 3, 2004 movie, slicing down the atmosphere with the AIRS infrared sensor

    These images of hurricane Alex were captured on August 3, 2004 at 1:30pm EDT. Located in the Atlantic Ocean located about 80 miles south-southeast of Charleston, South Carolina, Alex is now a category 2 hurricane with maximum sustained winds were near 100 mph (161 kph). Alex's center was about 65 miles (104 kilometers) northeast of Cape Hatteras and moving away from the U.S. coast.

    The major contribution to radiation (infrared light) that AIRS infrared channels sense comes from different levels in the atmosphere, depending upon the channel wavelength. To create the movies, a set of AIRS infrared channels were selected which probe the atmosphere at progressively deeper levels. If there were no clouds, the color in each frame would be nearly uniform until the Earth's surface is encountered. The tropospheric air temperature warms at a rate of 6 K (about 11 F) for each kilometer of descent toward the surface. Thus the colors would gradually change from cold to warm as the movie progresses.

    Clouds block the infrared radiation. Thus wherever there are clouds we can penetrate no deeper in infrared. The color remains fixed as the movie progresses, for that area of the image is 'stuck' to the cloud top temperature. The coldest temperatures around 220 K (about -65 F) come from altitudes of about 10 miles.

    We therefore see in a 'surface channel' at the end of the movie, signals from clouds as cold as 220 K and from Earth's surface at 310 K (about 100 F). The very coldest clouds are seen in deep convection thunderstorms over land. Images [figure removed for brevity, see original site] August 2, 2004, 1:30am ET Frame from August 2 movie, slicing down the atmosphere with the AIRS infrared sensor. Alex a tropical storm, sustained winds at 60 mph. The storm is 115 miles southeast of Charleston, South

  13. Improving Regional Forecast by Assimilating Atmospheric InfraRed Sounder (AIRS) Profiles into WRF Model

    NASA Technical Reports Server (NTRS)

    Chou, Shih-Hung; Zavodsky, Brad; Jedlovec, Gary J.

    2009-01-01

    In data sparse regions, remotely-sensed observations can be used to improve analyses and produce improved forecasts. One such source comes from the Atmospheric InfraRed Sounder (AIRS), which together with the Advanced Microwave Sounding Unit (AMSU), represents one of the most advanced space-based atmospheric sounding systems. The purpose of this paper is to describe a procedure to optimally assimilate high resolution AIRS profile data into a regional configuration of the Advanced Research WRF (ARW) version 2.2 using WRF-Var. The paper focuses on development of background error covariances for the regional domain and background type, and an optimal methodology for ingesting AIRS temperature and moisture profiles as separate overland and overwater retrievals with different error characteristics. The AIRS thermodynamic profiles are derived from the version 5.0 Earth Observing System (EOS) science team retrieval algorithm and contain information about the quality of each temperature layer. The quality indicators were used to select the highest quality temperature and moisture data for each profile location and pressure level. The analyses were then used to conduct a month-long series of regional forecasts over the continental U.S. The long-term impacts of AIRS profiles on forecast were assessed against verifying NAM analyses and stage IV precipitation data.

  14. Improved Impact of Atmospheric Infrared Sounder (AIRS) Radiance Assimilation in Numerical Weather Prediction

    NASA Technical Reports Server (NTRS)

    Zavodsky, Bradley; Chou, Shih-Hung; Jedlovec, Gary

    2012-01-01

    Improvements to global and regional numerical weather prediction (NWP) have been demonstrated through assimilation of data from NASA s Atmospheric Infrared Sounder (AIRS). Current operational data assimilation systems use AIRS radiances, but impact on regional forecasts has been much smaller than for global forecasts. Retrieved profiles from AIRS contain much of the information that is contained in the radiances and may be able to reveal reasons for this reduced impact. Assimilating AIRS retrieved profiles in an identical analysis configuration to the radiances, tracking the quantity and quality of the assimilated data in each technique, and examining analysis increments and forecast impact from each data type can yield clues as to the reasons for the reduced impact. By doing this with regional scale models individual synoptic features (and the impact of AIRS on these features) can be more easily tracked. This project examines the assimilation of hyperspectral sounder data used in operational numerical weather prediction by comparing operational techniques used for AIRS radiances and research techniques used for AIRS retrieved profiles. Parallel versions of a configuration of the Weather Research and Forecasting (WRF) model with Gridpoint Statistical Interpolation (GSI) that mimics the analysis methodology, domain, and observational datasets for the regional North American Mesoscale (NAM) model run at the National Centers for Environmental Prediction (NCEP)/Environmental Modeling Center (EMC) are run to examine the impact of each type of AIRS data set. The first configuration will assimilate the AIRS radiance data along with other conventional and satellite data using techniques implemented within the operational system; the second configuration will assimilate AIRS retrieved profiles instead of AIRS radiances in the same manner. Preliminary results of this study will be presented and focus on the analysis impact of the radiances and profiles for selected cases.

  15. The Impact of Atmospheric InfraRed Sounder (AIRS) Profiles on Short-term Weather Forecasts

    NASA Technical Reports Server (NTRS)

    Chou, Shih-Hung; Zavodsky, Brad; Jedlovec, Gary J.; Lapenta, William

    2007-01-01

    The Atmospheric Infrared Sounder (AIRS), together with the Advanced Microwave Sounding Unit (AMSU), represents one of the most advanced spacebased atmospheric sounding systems. The combined AlRS/AMSU system provides radiance measurements used to retrieve temperature profiles with an accuracy of 1 K over 1 km layers under both clear and partly cloudy conditions, while the accuracy of the derived humidity profiles is 15% in 2 km layers. Critical to the successful use of AIRS profiles for weather and climate studies is the use of profile quality indicators and error estimates provided with each profile Aside form monitoring changes in Earth's climate, one of the objectives of AIRS is to provide sounding information of sufficient accuracy such that the assimilation of the new observations, especially in data sparse region, will lead to an improvement in weather forecasts. The purpose of this paper is to describe a procedure to optimally assimilate highresolution AIRS profile data in a regional analysis/forecast model. The paper will focus on the impact of AIRS profiles on a rapidly developing east coast storm and will also discuss preliminary results for a 30-day forecast period, simulating a quasi-operation environment. Temperature and moisture profiles were obtained from the prototype version 5.0 EOS science team retrieval algorithm which includes explicit error information for each profile. The error profile information was used to select the highest quality temperature and moisture data for every profile location and pressure level for assimilation into the ARPS Data Analysis System (ADAS). The AIRS-enhanced analyses were used as initial fields for the Weather Research and Forecast (WRF) system used by the SPORT project for regional weather forecast studies. The ADASWRF system will be run on CONUS domain with an emphasis on the east coast. The preliminary assessment of the impact of the AIRS profiles will focus on quality control issues associated with AIRS

  16. Observation of the water cycle from space with the Atmospheric Infrared Sounder (AIRS)

    NASA Astrophysics Data System (ADS)

    Chahine, M. T.; Waliser, D. E.; Fetzer, E. J.; Olsen, E. T.

    2007-12-01

    AIRS is one of six instruments on board the Aqua satellite, part of NASA's Earth Observing System launched in a sun synchronous near polar orbit on May 4, 2002. AIRS and its partner microwave instrument, AMSU A, provide high quality data facilitating studies of the global water and energy cycles, climate variation and trends, and the response of the climate system to increased greenhouse gases. The exceptional stability of the AIRS instrument provides a climate record of thermal infrared radiance spectra spanning the 3.74 15.4 mm spectral band with 2378 channels at a nominal resolution of 1/1200. (Chahine et al, in BAMS, July 2006) Accurate knowledge of the vertical distribution of water vapor in the atmosphere is critically important to the determination of the warming the Earth will experience as a result of anthropogenic forcing. Comparison of the AIRS specific humidity product to state of the art climate models has shown most models exhibit a pattern of drier than observed (by 10 25%) in the tropics below 800 hPa and moister than observed (by 25 100%) between 300 and 600 hPa in the extra tropics (Pierce et al, GRL 2006). The AIRS water vapor measurements also reveal tropospheric moisture perturbations that are much larger than those depicted in previous NCAR/NCEP reanalysis and ECMWF analysis datasets, both of which have been widely used as observations to validate models. This suggests that the impact of convection induced downdrafts on the atmospheric boundary layer is significantly underestimated in both ECMWF and NCEP reanalysis (Fu et al., GRL 2006). AIRS data have led to the discovery of significant differences in the lower troposphere moisture and temperature fields during the spatial temporal evolution of the Madden Julian Oscillation (MJO). The anomalous lower troposphere temperature structure is observed in detail by AIRS for the Indian and western Pacific Oceans, while it remains much less well defined in the NCEP temperature fields (Tian et al

  17. Validation of the Atmospheric Infrared Sounder (AIRS) over the Antarctic Plateau: Low Radiance, Low Humidity, and Thin Clouds

    NASA Technical Reports Server (NTRS)

    Tobin, David C.

    2005-01-01

    The main goal of the project has been to use specialized measurements collected at the Antarctic Plateau to provide validation of the Atmospheric InfraRed Sounder (AIRS) spectral radiances and some AIRS Level 2 products. As proposed, efforts conducted at the University of Wisconsin are focused on providing technical information, data, and software in support of the validation studies.

  18. Carbon Monoxide Distribution over Peninsular Malaysia from the Atmospheric Infrared Sounder (AIRS)

    NASA Astrophysics Data System (ADS)

    Rajab, Jaso M.; MatJafri, M. Z.; Lim, H. S.; Abdullah, K.

    2009-07-01

    The Atmospheric Infrared Sounder (AIRS) onboard NASA's Aqua satellite. It daily coverage of ˜70% of the planet represents a significant evolutionary advance in satellite traces gas remote sensing. AIRS, the part of a large international investment to upgrade the operational meteorological satellite systems, is first of the new generation of meteorological advanced sounders for operational and research use, Providing New Insights into Weather and Climate for the 21st Century. Carbon monoxide (CO) is a ubiquitous, an indoor and outdoor air pollutant, is not a significant greenhouse gas as it absorbs little infrared radiation from the Earth. However, it does have an influence on oxidization in the atmosphere through interaction with hydroxyl radicals (OH), which also react with methane, halocarbons and tropospheric ozone. It produced by the incomplete combustion of fossil fuels and biomass burning, and that it has a role as a smog. The aim of this investigation is to study the (CO) carbon monoxide distribution over Peninsular Malaysia. The land use map of the Peninsular Malaysia was conducted by using CO total column amount, obtained from AIRS data, the map & data was processed and analyzed by using Photoshop & SigmaPlot 11.0 programs and compared for timing of various (day time) (28 August 2005 & 29 August 2007) for both direct comparison and the comparison using the same a priori profile, the CO concentrations in 28/8/2005 higher. The CO maps were generated using Kriging Interpolation technique. This interpolation technique produced high correlation coefficient, R2 and low root mean square error, RMS for CO. This study provided useful information for influence change of CO concentration on varies temperature.

  19. Data Assimilation and Regional Forecasts Using Atmospheric InfraRed Sounder (AIRS) Profiles

    NASA Technical Reports Server (NTRS)

    Chou, Shih-Hung; Zavodsky, Bradley; Jedlovec, Gary

    2009-01-01

    In data sparse regions, remotely-sensed observations can be used to improve analyses, which in turn should lead to better forecasts. One such source comes from the Atmospheric Infrared Sounder (AIRS), which together with the Advanced Microwave Sounding Unit (AMSU), provides temperature and moisture profiles with an accuracy comparable to that of radiosondes. The purpose of this paper is to describe a procedure to optimally assimilate AIRS thermodynamic profiles--obtained from the version 5.0 Earth Observing System (EOS) science team retrieval algorithm-into a regional configuration of the Weather Research and Forecasting (WRF) model using WRF-Var. The paper focuses on development of background error covariances for the regional domain and background field type, a methodology for ingesting AIRS profiles as separate over-land and over-water retrievals with different error characteristics, and utilization of level-by-level quality indicators to select only the highest quality data. The assessment of the impact of the AIRS profiles on WRF-Var analyses will focus on intelligent use of the quality indicators, optimized tuning of the WRF-Var, and comparison of analysis soundings to radiosondes. The analyses will be used to conduct a month-long series of regional forecasts over the continental U.S. The long-tern1 impact of AIRS profiles on forecast will be assessed against verifying radiosonde and stage IV precipitation data.

  20. Data Assimilation and Regional Forecasts using Atmospheric InfraRed Sounder (AIRS) Profiles

    NASA Technical Reports Server (NTRS)

    Zabodsky, Brad; Chou, Shih-Hung; Jedlovec, Gary J.

    2009-01-01

    In data sparse regions, remotely-sensed observations can be used to improve analyses, which in turn should lead to better forecasts. One such source comes from the Atmospheric Infrared Sounder (AIRS), which, together with the Advanced Microwave Sounding Unit (AMSU), provides temperature and moisture profiles with an accuracy comparable to that of radionsondes. The purpose of this poster is to describe a procedure to optimally assimilate AIRS thermodynamic profiles, obtained from the version 5.0 Earth Observing System (EOS) science team retrieval algorithm, into a regional configuration of the Weather Research and Forecasting (WRF) model using WRF-Var. The poster focuses on development of background error covariances for the regional domain and background field type, a methodology for ingesting AIRS profiles as separate over-land and over-water retrievals with different error characteristics, and utilization of level-by-level quality indicators to select only the highest quality data. The assessment of the impact of the AIRS profiles on WRF-Var analyses will focus on intelligent use of the quality indicators, optimized tuning of the WRF-Var, and comparison of analysis soundings to radiosondes. The analyses are used to conduct a month-long series of regional forecasts over the continental U.S. The long-term impact of AIRS profiles on forecast will be assessed against NAM analyses and stage IV precipitation data.

  1. Impact of Atmospheric Infrared Sounder (AIRS) Thermodynamic Profiles on Regional Weather Forecasting

    NASA Technical Reports Server (NTRS)

    Chou, Shih-Hung; Zavodsky, Bradley T.; Jedlovee, Gary J.

    2010-01-01

    In data sparse regions, remotely-sensed observations can be used to improve analyses and lead to better forecasts. One such source comes from the Atmospheric Infrared Sounder (AIRS), which together with the Advanced Microwave Sounding Unit (AMSU), provides temperature and moisture profiles with accuracy comparable to that of radiosondes. The purpose of this paper is to describe a procedure to assimilate AIRS thermodynamic profile data into a regional configuration of the Advanced Research Weather Research and Forecasting (WRF-ARW) model using its three-dimension variational (3DVAR) analysis component (WRF-Var). Quality indicators are used to select only the highest quality temperature and moisture profiles for assimilation in both clear and partly cloudy regions. Separate error characteristics for land and water profiles are also used in the assimilation process. Assimilation results indicate that AIRS profiles produce an analysis closer to in situ observations than the background field. Forecasts from a 37-day case study period in the winter of 2007 show that AIRS profile data can lead to improvements in 6-h cumulative precipitation forecasts due to instability added in the forecast soundings by the AIRS profiles. Additionally, in a convective heavy rainfall event from February 2007, assimilation of AIRS profiles produces a more unstable boundary layer resulting in enhanced updrafts in the model. These updrafts produce a squall line and precipitation totals that more closely reflect ground-based observations than a no AIRS control forecast. The location of available high-quality AIRS profiles ahead of approaching storm systems is found to be of paramount importance to the amount of impact the observations will have on the resulting forecasts.

  2. Hurricane Frances as Observed by NASA's Spaceborne Atmospheric Infrared Sounder (AIRS) - Total Water

    NASA Technical Reports Server (NTRS)

    2004-01-01

    Born in the Atlantic, Hurricane Frances became a category 4 hurricane on August 31, 2004. Expectations are the hurricane will hit the Space Coast of Florida in Brevard County early Sunday morning.

    This movie is a time-series of maps that show AIRS observations of the total amount of water vapor present in the atmospheric column above each point of the Earth's surface. If all the water vapor in the column were forced to fall as rain, the depth of the resulting puddle on the surface at that point is equal to the value shown on the map. Fifty millimeters (mm) is about 2 inches. The large band of maximum water vapor in the neighborhood of the equator is the Intertropical Convergence Zone (ITCZ), a region of strong convection and powerful thunderstorms.

    This movie shows the total precipitable water vapor from August 23 through September 2, 2004. You can see Hurricane Frances as it moves through the Caribbean toward Florida, and the changes in intensity are visible. The eye has been marked with a red spot. The water vapor encompassed by the hurricane is also the result of the very strong convection which is an integral part of the formation and intensification of tropical storms. If you look at the last frame of the movie in the lower right corner, you can see the emergence of a new tropical storm. Ivan makes its debut in the Atlantic.

    The Atmospheric Infrared Sounder Experiment, with its visible, infrared, and microwave detectors, provides a three-dimensional look at Earth's weather. Working in tandem, the three instruments can make simultaneous observations all the way down to the Earth's surface, even in the presence of heavy clouds. With more than 2,000 channels sensing different regions of the atmosphere, the system creates a global, 3-D map of atmospheric temperature and humidity and provides information on clouds, greenhouse gases, and many other atmospheric phenomena. The AIRS Infrared Sounder Experiment flies onboard NASA's Aqua spacecraft

  3. Impact of Atmospheric Infrared Sounder (AIRS) Thermodynamic Profiles on Regional Precipitation Forecasting

    NASA Technical Reports Server (NTRS)

    Chou, S.-H.; Zavodsky, B. T.; Jedloved, G. J.

    2010-01-01

    In data sparse regions, remotely-sensed observations can be used to improve analyses and lead to better forecasts. One such source comes from the Atmospheric Infrared Sounder (AIRS), which together with the Advanced Microwave Sounding Unit (AMSU), provides temperature and moisture profiles in clear and cloudy regions with accuracy which approaches that of radiosondes. The purpose of this paper is to describe an approach to assimilate AIRS thermodynamic profile data into a regional configuration of the Advanced Research WRF (ARW) model using WRF-Var. Quality indicators are used to select only the highest quality temperature and moisture profiles for assimilation in clear and partly cloudy regions, and uncontaminated portions of retrievals above clouds in overcast regions. Separate error characteristics for land and water profiles are also used in the assimilation process. Assimilation results indicate that AIRS profiles produce an analysis closer to in situ observations than the background field. Forecasts from a 37-day case study period in the winter of 2007 show that AIRS profile data can lead to improvements in 6-h cumulative precipitation forecasts resulting from improved thermodynamic fields. Additionally, in a convective heavy rainfall event from February 2007, assimilation of AIRS profiles produces a more unstable boundary layer resulting in enhanced updrafts in the model. These updrafts produce a squall line and precipitation totals that more closely reflect ground-based observations than a no AIRS control forecast. The location of available high-quality AIRS profiles ahead of approaching storm systems is found to be of paramount importance to the amount of impact the observations will have on the resulting forecasts.

  4. Hurricane Ivan as Observed by NASA's Spaceborne Atmospheric Infrared Sounder (AIRS)

    NASA Technical Reports Server (NTRS)

    2004-01-01

    visible, infrared, and microwave detectors, provides a three-dimensional look at Earth's weather. Working in tandem, the three instruments can make simultaneous observations all the way down to the Earth's surface, even in the presence of heavy clouds. With more than 2,000 channels sensing different regions of the atmosphere, the system creates a global, 3-D map of atmospheric temperature and humidity and provides information on clouds, greenhouse gases, and many other atmospheric phenomena. The AIRS Infrared Sounder Experiment flies onboard NASA's Aqua spacecraft and is managed by NASA's Jet Propulsion Laboratory, Pasadena, Calif., under contract to NASA. JPL is a division of the California Institute of Technology in Pasadena.

  5. Regional Precipitation Forecast with Atmospheric InfraRed Sounder (AIRS) Profile Assimilation

    NASA Technical Reports Server (NTRS)

    Chou, S.-H.; Zavodsky, B. T.; Jedloved, G. J.

    2010-01-01

    Advanced technology in hyperspectral sensors such as the Atmospheric InfraRed Sounder (AIRS; Aumann et al. 2003) on NASA's polar orbiting Aqua satellite retrieve higher vertical resolution thermodynamic profiles than their predecessors due to increased spectral resolution. Although these capabilities do not replace the robust vertical resolution provided by radiosondes, they can serve as a complement to radiosondes in both space and time. These retrieved soundings can have a significant impact on weather forecasts if properly assimilated into prediction models. Several recent studies have evaluated the performance of specific operational weather forecast models when AIRS data are included in the assimilation process. LeMarshall et al. (2006) concluded that AIRS radiances significantly improved 500 hPa anomaly correlations in medium-range forecasts of the Global Forecast System (GFS) model. McCarty et al. (2009) demonstrated similar forecast improvement in 0-48 hour forecasts in an offline version of the operational North American Mesoscale (NAM) model when AIRS radiances were assimilated at the regional scale. Reale et al. (2008) showed improvements to Northern Hemisphere 500 hPa height anomaly correlations in NASA's Goddard Earth Observing System Model, Version 5 (GEOS-5) global system with the inclusion of partly cloudy AIRS temperature profiles. Singh et al. (2008) assimilated AIRS temperature and moisture profiles into a regional modeling system for a study of a heavy rainfall event during the summer monsoon season in Mumbai, India. This paper describes an approach to assimilate AIRS temperature and moisture profiles into a regional configuration of the Advanced Research Weather Research and Forecasting (WRF-ARW) model using its three-dimensional variational (3DVAR) assimilation system (WRF-Var; Barker et al. 2004). Section 2 describes the AIRS instrument and how the quality indicators are used to intelligently select the highest-quality data for assimilation

  6. Assimilation of Atmospheric InfraRed Sounder (AIRS) Profiles using WRF-Var

    NASA Technical Reports Server (NTRS)

    Zavodsky, Brad; Jedlovec, Gary J.; Lapenta, William

    2008-01-01

    The Weather Research and Forecasting (WRF) model contains a three-dimensional variational (3DVAR) assimilation system (WRF-Var), which allows a user to join data from multiple sources into one coherent analysis. WRF-Var combines observations with a background field traditionally generated using a previous model forecast through minimization of a cost function. In data sparse regions, remotely-sensed observations may be able to improve analyses and produce improved forecasts. One such source comes from the Atmospheric Infrared Sounder (AIRS), which together with the Advanced Microwave Sounding Unit (AMSU), represents one of the most advanced space-based atmospheric sounding systems. The combined AIRS/AMSU system provides radiance measurements used as input to a sophisticated retrieval scheme which has been shown to produce temperature profiles with an accuracy of 1 K over 1 km layers and humidity profiles with accuracy of 15% in 2 km layers in both clear and partly cloudy conditions. The retrieval algorithm also provides estimates of the accuracy of the retrieved values at each pressure level, allowing the user to select profiles based on the required error tolerances of the application. The purpose of this paper is to describe a procedure to optimally assimilate high-resolution AIRS profile data into a regional configuration of the Advanced Research WRF (ARW) version 2.2 using WRF-Var. The paper focuses on development of background error covariances for the regional domain and background field type using gen_be and an optimal methodology for ingesting AIRS temperature and moisture profiles as separate overland and overwater retrievals with different error characteristics in the WRF-Var. The AIRS thermodynamic profiles are obtained from the version 5.0 Earth Observing System (EOS) science team retrieval algorithm and contain information about the quality of each temperature layer. The quality indicators are used to select the highest quality temperature and moisture

  7. Evaluating the Impact of Atmospheric Infrared Sounder (AIRS) Data On Convective Forecasts

    NASA Technical Reports Server (NTRS)

    Kozlowski, Danielle; Zavodsky, Bradley

    2011-01-01

    The Short-term Prediction Research and Transition Center (SPoRT) is a collaborative partnership between NASA and operational forecasting partners, including a number of National Weather Service (NWS) offices. SPoRT provides real-time NASA products and capabilities to its partners to address specific operational forecast challenges. The mission of SPoRT is to transition observations and research capabilities into operations to help improve short-term weather forecasts on a regional scale. Two areas of focus are data assimilation and modeling, which can to help accomplish SPoRT's programmatic goals of transitioning NASA data to operational users. Forecasting convective weather is one challenge that faces operational forecasters. Current numerical weather prediction (NWP) models that operational forecasters use struggle to properly forecast location, timing, intensity and/or mode of convection. Given the proper atmospheric conditions, convection can lead to severe weather. SPoRT's partners in the National Oceanic and Atmospheric Administration (NOAA) have a mission to protect the life and property of American citizens. This mission has been tested as recently as this 2011 severe weather season, which has seen more than 300 fatalities and injuries and total damages exceeding $10 billion. In fact, during the three day period from 25-27 April, 1,265 storms reports (362 tornado reports) were collected making this three day period one of most active in American history. To address the forecast challenge of convective weather, SPoRT produces a real-time NWP model called the SPoRT Weather Research and Forecasting (SPoRT-WRF), which incorporates unique NASA data sets. One of the NASA assets used in this unique model configuration is retrieved profiles from the Atmospheric Infrared Sounder (AIRS).The goal of this project is to determine the impact that these AIRS profiles have on the SPoRT-WRF forecasts by comparing to a current operational model and a control SPoRT-WRF model

  8. The Atmospheric Infrared Sounder (AIRS) on the NASA Aqua Spacecraft: A General Remote Sensing Tool for Understanding Atmospheric Structure, Dynamics and Composition

    NASA Technical Reports Server (NTRS)

    Pagano, Thomas S.; Chahine, Moustafa T.; Fetzer, Eric J.

    2010-01-01

    The Atmospheric Infrared Sounder (AIRS) on the EOS Aqua Spacecraft was launched on May 4, 2002. Early in the mission, the AIRS instrument demonstrated its value to the weather forecasting community with better than 6 hours of improvement on the 5 day forecast. Now with over eight years of consistent and stable data from AIRS, scientists are able to examine processes governing weather and climate and look at seasonal and interannual trends from the AIRSdata with high statistical confidence. Naturally, long-term climate trends require a longer data set, but indications are that the Aqua spacecraft and the AIRS instrument should last beyond 2018. This paper briefly describes the AIRS data products and presents some of the most significant findings involving the use of AIRS data in the areas of weather forecast improvement, climate processes and model validation, cloud and polar processes, and atmospheric composition (chemistry and dust).

  9. Atmospheric infrared sounder

    NASA Technical Reports Server (NTRS)

    Rosenkranz, Philip, W.; Staelin, David, H.

    1995-01-01

    This report summarizes the activities of two Atmospheric Infrared Sounder (AIRS) team members during the first half of 1995. Changes to the microwave first-guess algorithm have separated processing of Advanced Microwave Sounding Unit A (AMSU-A) from AMSU-B data so that the different spatial resolutions of the two instruments may eventually be considered. Two-layer cloud simulation data was processed with this algorithm. The retrieved water vapor column densities and liquid water are compared. The information content of AIRS data was applied to AMSU temperature profile retrievals in clear and cloudy atmospheres. The significance of this study for AIRS/AMSU processing lies in the improvement attributable to spatial averaging and in the good results obtained with a very simple algorithm when all of the channels are used. Uncertainty about the availability of either a Microwave Humidity Sensor (MHS) or AMSU-B for EOS has motivated consideration of possible low-cost alternative designs for a microwave humidity sensor. One possible configuration would have two local oscillators (compared to three for MHS) at 118.75 and 183.31 GHz. Retrieval performances of the two instruments were compared in a memorandum titled 'Comparative Analysis of Alternative MHS Configurations', which is attached.

  10. Evaluation of the Impact of Atmospheric Infrared Sounder (AIRS) Radiance and Profile Data Assimilation in Partly Cloudy Regions

    NASA Technical Reports Server (NTRS)

    Zavodsky, Bradley; Srikishen, Jayanthi; Jedlovec, Gary

    2013-01-01

    Improvements to global and regional numerical weather prediction have been demonstrated through assimilation of data from NASA s Atmospheric Infrared Sounder (AIRS). Current operational data assimilation systems use AIRS radiances, but impact on regional forecasts has been much smaller than for global forecasts. Retrieved profiles from AIRS contain much of the information that is contained in the radiances and may be able to reveal reasons for this reduced impact. Assimilating AIRS retrieved profiles in an identical analysis configuration to the radiances, tracking the quantity and quality of the assimilated data in each technique, and examining analysis increments and forecast impact from each data type can yield clues as to the reasons for the reduced impact. By doing this with regional scale models individual synoptic features (and the impact of AIRS on these features) can be more easily tracked. This project examines the assimilation of hyperspectral sounder data used in operational numerical weather prediction by comparing operational techniques used for AIRS radiances and research techniques used for AIRS retrieved profiles. Parallel versions of a configuration of the Weather Research and Forecasting (WRF) model with Gridpoint Statistical Interpolation (GSI) are run to examine the impact AIRS radiances and retrieved profiles. Statistical evaluation of 6 weeks of forecast runs will be compared along with preliminary results of in-depth investigations for select case comparing the analysis increments in partly cloudy regions and short-term forecast impacts.

  11. /Air Atmospheres

    NASA Astrophysics Data System (ADS)

    Emami, Samar; Sohn, Hong Yong; Kim, Hang Goo

    2014-08-01

    Molten magnesium oxidizes rapidly when exposed to air causing melt loss and handling difficulties. The use of certain additive gases such as SF6, SO2, and CO2 to form a protective MgO layer over a magnesium melt has been proposed. The oxidation behavior of molten magnesium in air containing various concentrations of SF6 was investigated. Measurements of the kinetics of the oxide layer growth at various SF6 concentrations in air and temperatures were made. Experiments were performed using a thermogravimetric analysis unit in the temperature range of 943 K to 1043 K (670 °C to 770 °C). Results showed that a thin, coherent, and protective MgF2 layer was formed under SF6/Air mixtures, with a thickness ranging from 300 nm to 3 μm depending on SF6 concentration, temperature, and exposure time. Rate parameters were calculated and a model for the process was developed. The morphology and composition of the surface films were studied using scanning electron microscope and energy-dispersive spectroscope.

  12. Analysis of Co-located Ground- and Space-based Infrared Atmospheric Measurements: AERI, AIRS, CERES, MODIS

    NASA Astrophysics Data System (ADS)

    Lewis, P. E.; Anderson, G. P.; Chetwynd, J.; Roman, M.; Schaaf, C. B.; Turner, D. D.; Rutan, D. A.; Berk, A.; Shen, S. S.; Miller, D. P.; Kroutil, R.

    2008-12-01

    Sets of clear-sky, co-located, down-looking infrared data, from the NASA AQUA space-based Atmospheric Infrared Sounder (AIRS) and the Clouds and the Earth's Radiant Energy System (CERES), have been paired with the DOE Southern Great Plains (SGP) ground-based, up-looking Atmospheric Emitted Radiance Interferometer (AERI). Only 26 cases are included in this study, the 8% of the available 2005 AIRS acquisitions at SGP that were defined as cloud free. These data sets have then been simulated using the MODTRAN® 5 (MOD5) radiative transfer code with auxiliary 'truth' data as input. Since MOD5 is unaffiliated with any of the instruments, its use as a transfer agent among the instrument suites provides important algorithm validation. Of particular interest is the impact, if any, of the Ground Sampling Distance (GSD) of AIRS, CERES and MODIS (13, 26 and 0.5 km, respectively) vs. the soda-straw up-looking mode of AERI. The sensitivity of the larger GSDs on measurements of outgoing long wave radiation (OLR) is an important question for next-stage climate monitoring. In addition to the coincident SGP 'ground truth' data (vertical profile sondes and AERONET measurements) and MODIS products, the AURA Ozone Monitoring Instrument (OMI) has also augmented the available 'truth' input parameters. Initial calculations with MOD5 have replicated both the AERI and AIRS measurements to within 1% RMS. Preliminary calculations of the CERES long wave radiances suggest that differences will fall well within 3%. While these results are not sufficiently precise for specific instrument algorithms, they suggest some confidence in the generic use of MODTRAN® 5 as an integration tool for Climate Change studies.

  13. Demonstrating the Operational Value of Atmospheric Infrared Sounder (AIRS) Retrieved Profiles in the Pre-Convective Environment

    NASA Technical Reports Server (NTRS)

    Kozlowski, Danielle M.; Zavodsky, T.; Jedloved, Gary J.

    2011-01-01

    The Short-term Prediction Research and Transition Center (SPoRT) is a collaborative partnership between NASA and operational forecasting partners, including a number of National Weather Service offices. SPoRT provides real-time NASA products and capabilities to its partners to address specific operational forecast challenges. One operational forecast challenge is forecasting convective weather in data-void regions such as large bodies of water (e.g. Gulf of Mexico). To address this forecast challenge, SPoRT produces a twice-daily three-dimensional analysis that blends a model first-guess from the Advanced Research Weather Research and Forecasting (WRF-ARW) model with retrieved profiles from the Atmospheric Infrared Sounder (AIRS) -- a hyperspectral sounding instrument aboard NASA's Aqua satellite that provides temperature and moisture profiles of the atmosphere. AIRS profiles are unique in that they give a three dimensional view of the atmosphere that is not available through the current rawinsonde network. AIRS has two overpass swaths across North America each day, one valid in the 0700-0900 UTC timeframe and the other in the 1900-2100 UTC timeframe. This is helpful because the rawinsonde network only has data from 0000 UTC and 1200 UTC at specific land-based locations. Comparing the AIRS analysis product with control analyses that include no AIRS data demonstrates the value of the retrieved profiles to situational awareness for the pre-convective (and convective) environment. In an attempt to verify that the AIRS analysis was a good representation of the vertical structure of the atmosphere, both the AIRS and control analyses are compared to a Rapid Update Cycle (RUC) analysis used by operational forecasters. Using guidance from operational forecasters, convective available potential energy (CAPE) was determined to be a vital variable in making convective forecasts and is used herein to demonstrate the utility of the AIRS profiles in changing the vertical

  14. A radiance-based method for estimating uncertainties in the Atmospheric Infrared Sounder (AIRS) land surface temperature product

    NASA Astrophysics Data System (ADS)

    Hulley, Glynn C.; Hook, Simon J.

    2012-10-01

    Land Surface Temperature (LST) has been identified by NASA and other international organizations as an important Earth System Data Record (ESDR). An ESDR is defined as a long-term, well calibrated and validated data set. Identifying uncertainties in LST products with coarse spatial resolutions (>10 km) such as those from hyperspectral infrared sounders is notoriously difficult due to the challenges of making reliable in situ measurements representative of the spatial scales of the output products. In this study we utilize a Radiance-based (R-based) LST method for estimating uncertainties in the Atmospheric Infrared Sounder (AIRS) v5 LST product. The R-based method provides estimates of the true LST using a radiative closure simulation without the need for in situ measurements, and requires input air temperature, relative humidity profiles and emissivity data. The R-based method was employed at three validation sites over the Namib Desert, Gran Desierto, and Redwood National Park for all AIRS observations from 2002 to 2010. Results showed daytime LST root-mean square errors (RMSE) of 2-3 K at the Namib and Desierto sites, and 1.5 K at the Redwood site. Nighttime LST RMSEs at the two desert sites were a factor of two less when compared to daytime results. Positive daytime LST biases were found at each site due to an underestimation of the daytime AIRS v5 longwave spectral emissivity, while the reverse occurred at nighttime. In the AIRS v6 product (release 2012), LST biases and RMSEs will be reduced significantly due to improved methodologies for the surface retrieval and emissivity first guess.

  15. Investigations of the spatial and temporal resolution of retrievals of atmospheric carbon dioxide from the Atmospheric InfraRed Sounder (AIRS).

    NASA Astrophysics Data System (ADS)

    Maddy, Eric Sean

    As the dominant anthropogenic greenhouse gas, carbon dioxide (CO 2), represents an important component of climate change (IPCC 2007). Owing to burning of fossil fuels and deforestation, atmospheric CO2 concentrations have increased over 110 parts-per-million by volume (ppmv) from 270 ppmv to 380 ppmv since the dawn of the Industrial Revolution. Understanding of the spatial distribution of the sources and sinks of atmospheric CO 2 is necessary not only to predict the future atmospheric abundances but also their effect on future climate. Although designed for deriving high precision temperature and moisture profiles, NASA's Atmospheric InfraRed Sounder (AIRS) IR measurements include broad vertical sensitivity (between 3 and 10 km) to atmospheric CO2 variations. Coupled with AIRS' broad swath pattern and a technique referred to as "cloud-clearing" these measurements enable daily global spatial coverage. Nevertheless, AIRS' ability to determine the spatial distribution of carbon dioxide (CO2) is strongly dependent on its ability to separate the radiative effects of CO2 from temperature not to mention measurement uncertainties due to clouds and other geophysical variables such as moisture and ozone. This research presents a thorough investigation into the temporal and spatial scales that the AIRS can separate temperature (and other geophysical variables) from CO2. Through our detailed understanding of the way satellites view the Earth's atmosphere, we have developed an algorithm capable of retrieving global middle-to-upper tropospheric CO2 concentrations in all-weather conditions with total uncertainties ranging between 1 to 2 ppmv. From a radiative perspective, roughly equivalent to 30 mK to 60 mK, 1 to 2 ppmv, is an awesome feat for a space-borne sensor. Necessary for the remarkable performance of this algorithm, we developed methodologies capable of separating the radiative effect of CO2 variability from temperature, improved the fast rapid transmittance algorithm

  16. P.88 Regional Precipitation Forecast with Atmospheric Infrared Sounder (AIRS) Profiles

    NASA Technical Reports Server (NTRS)

    Chou, Shih-Hung; Zavodsky, Bradley; Jedlovec, Gary

    2010-01-01

    Prudent assimulation of AIRS thermodynamic profiles and quality indicators can improve initial conditions for regional weather models. In general, AIRS-enhanced analysis more closely resembles radiosondes than the CNTL; forecasts with AIRS profiles are generally closer to NAM analyses than CNTL for sensible weather parameters (not shown here). Assimilation of AIRS leads to an overall QPF improvement in 6-h accumulated precipitation forecases. Including AIRS profiles in assimilation process enhances the low-level instability and produces stronger updrafts and a better precipitation forecast than the CNTL run.

  17. P161 Improved Impact of Atmospheric Infrared Sounder (AIRS) Radiance Assimilation in Numerical Weather Prediction

    NASA Technical Reports Server (NTRS)

    Zavodsky, Bradley T.; Chou, Shih-Hung; Jedlovec, Gary J.

    2012-01-01

    For over 6 years, AIRS radiances have been assimilated operationally into National (e.g. Environmental Modeling Center (EMC)) and International (e.g. European Centre for Medium-Range Weather Forecasts (ECMWF)), operational centers; assimilated in the North American Mesoscale (NAM) since 2008. Due partly to data latency and operational constraints, hyperspectral radiance assimilation has had less impact on the Gridpoint Statistical Interpolation (GSI) system used in the NAM and GFS. Objective of this project is to use AIRS retrieved profiles as a proxy for the AIRS radiances in situations where AIRS radiances are unable to be assimilated in the current operational system by evaluating location and magnitude of analysis increments.

  18. Spaceborne Infrared Atmospheric Sounder

    NASA Technical Reports Server (NTRS)

    Pagano, Thomas; Macenka, Steven; Kampe, Thomas

    2004-01-01

    A report describes the development of the spaceborne infrared atmospheric sounder (SIRAS) - a spectral imaging instrument, suitable for observing the atmosphere of the Earth from a spacecraft, that utilizes four spectrometers to cover the wavelength range of 12 to 15.4 m with a spectral resolution that ranges between 1 part per 900 and 1 part per 1,200 in wavelength. The spectrometers are operated in low orders to minimize filtering requirements. Focal planes receive the dispersed energy and provide a spectrum of the scene. The design of the SIRAS combines advanced, wide-field refractive optics with high-dispersion gratings in a solid-state (no moving parts), diffraction-limited optical system that is the smallest such system that can be constructed for the specified wavelength range and resolution. The primary structure of the SIRAS has dimensions of 10 by 10 by 14 cm and has a mass of only 2.03 kg

  19. Operational readiness for the Atmospheric Infrared Sounder (AIRS) on the earth observing system aqua spacecraft

    NASA Technical Reports Server (NTRS)

    Pagano, T.; Aumann, H.; Chahine, M.; Karnik, A.; Goodson, G.; Schindler, R.; Elliot, D. A.; Hofstadter, M.

    2001-01-01

    This paper describes the AIRS science objectives, the instrument design and operation, the in-flight operational scenario, and the calibration plan. All aspects of the program are addressed here to demonstrate that the AIRS program is ready to transition to the flight segment of the program.

  20. Large Scale Variability of Mid-Tropospheric Carbon Dioxide as Observed by the Atmospheric Infrared Sounder (AIRS) on the NASA EOS Aqua Platform

    NASA Technical Reports Server (NTRS)

    Pagano, Thomas S.; Olsen, Edward T.

    2012-01-01

    The Atmospheric Infrared Sounder (AIRS) is a hyperspectral infrared instrument on the EOS Aqua Spacecraft, launched on May 4, 2002. AIRS has 2378 infrared channels ranging from 3.7 microns to 15.4 microns and a 13.5 km footprint. AIRS, in conjunction with the Advanced Microwave Sounding Unit (AMSU), produces temperature profiles with 1K/km accuracy, water vapor profiles (20%/2km), infrared cloud height and fraction, and trace gas amounts for CO2, CO, SO2, O3 and CH4 in the mid to upper troposphere. AIRS wide swath(cedilla) +/-49.5 deg , enables daily global daily coverage for over 95% of the Earth's surface. AIRS data are used for weather forecasting, validating climate model distribution and processes, and observing long-range transport of greenhouse gases. In this study, we examine the large scale and regional horizontal variability in the AIRS Mid-tropospheric Carbon Dioxide product as a function of season and associate the observed variability with known atmospheric transport processes, and sources and sinks of CO2.

  1. The Atmospheric Infrared Sounder (AIRS) on Aqua: instrument stability and data products for climate observations

    NASA Technical Reports Server (NTRS)

    Pagano, Thomas S.; Chahine, M.; Aumann, H.; Strow, L.; Broberg, S.; Gaiser, S.

    2003-01-01

    30th International Symposium on Remote Sensing of the Environment (ISRSE) NASA Honolulu, Hawaii, USAThis paper discusses the stability of the AIRS instrument as measured pre-flight and in-orbit. In order differentiate instrument related changes with true changes in climate observations, the instrument stability must be demonstrated.

  2. Global Daily Atmospheric State Profiles from the Atmospheric Infrared Sounder

    NASA Technical Reports Server (NTRS)

    Pagano, Thomas S.; Aumann, Hartmut H.; Fetzer, Eric J.; Lambrigtsen, Bjorn H.; Chahine, Moustafa T.

    2008-01-01

    The Atmospheric Infrared Sounder (AIRS) is a hyperspectral infrared instrument on the EOS Aqua Spacecraft, launched on May 4, 2002. AIRS has 2378 infrared channels ranging from 3.7 (micro)m to 15.4 (micro)m and a 13.5 km footprint. AIRS, in conjunction with the Advanced Microwave Sounding Unit (AMSU), produces temperature profiles with 1K/km accuracy on a global scale, as well as water vapor profiles, clouds, dust and trace gas amounts for CO2, CO, SO2, O3 and CH4.[1] AIRS data are used for weather forecasting and studies of global climate change. The AIRS is a 'facility' instrument developed by NASA as an experimental demonstration of advanced technology for remote sensing and the benefits of high resolution infrared spectra to science investigations.

  3. Infrared Atmospheric Emission. I.

    DTIC Science & Technology

    1982-03-01

    contract. They are (i) "The 5g Levels of Atomic Nitrogen" AO)YA ii Edward S. Chang and Hajime Sakai J. Phys. B 14, L391 (1981) (ii) "Infrared Emission...At. Idol. Phys. 14 (1981) L391 -L395. printed in Great Bjritain LETTER TO THE EDITOR INC 5g levels of atomic nitrogent Edward S Chang and Hajime Sakai...81/120391 +05$01.30 C) 1981 The Institute of Physics L391 The U.S. Qovermnt is authoried to repoduce and sem tns report. Parmb@a- or ur Uther

  4. MODTRAN5 analysis of clear-sky, co-located space- and ground-based infrared atmospheric measurements: AERI, AIRS, CERES, MODIS

    NASA Astrophysics Data System (ADS)

    Lewis, Paul E.; Anderson, Gail P.; Shen, Sylvia S.; Chetwynd, James; Roman, Miguel, III; Schaaf, Crystal; Turner, David D.; Rutan, David A.; Berk, Alexander; Miller, David P.; Kroutil, Robert

    2009-05-01

    A set of 26 clear-sky, co-located, infrared data from NASA's space-based, downward looking Atmospheric Infrared Sounder (AIRS)1 and its Clouds and the Earth's Radiant Energy System (CERES)2 have been paired with the DOE's Southern Great Plains (SGP)3 ground-based, upward looking Atmospheric Emitted Radiance Interferometer (AERI)4. These data sets have then been simulated using the MODTRAN®55 (MOD5) radiative transfer code with standard auxiliary 'truth' data as input. Of particular interest is the impact, if any, of the large Ground Sampling Distance (GSD) of AIRS and CERES (minimum radii of approximately 13 and 26 km, respectively) vs. the soda-straw up-looking mode of AERI. The smaller Moderate Resolution Imaging Spectroradiometer (MODIS)6 GSD (<1 km) provides estimated distributions of land-type and albedo within the larger footprints. The SGP's coincident vertical profile sondes and Aeronet7 retrievals, along with other satellite data [Ozone Monitoring Instrument (OMI)8] constrain the surface type, column ozone and aerosol optical depth that existed during the measurement events. Initial MOD5 calculations, using these ancillary data as input, have replicated the AERI and AIRS measurements to within an average difference of ~1% over their entire spectral range. Using MODIS visible albedo9 retrievals to extend the albedo into the long wave (LW) only slightly improved the statistical comparison between the CERES and MOD5 broadband LW radiances agreement, from 3% to ~1.5%, while increasing the variance. While these results are not sufficient for specific instrument inversion algorithms, they suggest some confidence in the generic use of MODTRAN®5 to help integrate and spectrally extend assorted data sets for sensitivity studies of Climate Change, where the estimated required sensitivity is <1%.

  5. Infrared Measurements of Atmospheric Constituents

    NASA Technical Reports Server (NTRS)

    Murcray, Frank J.

    1998-01-01

    This research program studies atmospheric trace gas concentrations and altitude distributions, particularly for those gases that are important in stratospheric chemistry and radiative balance. Measurements are made with infrared remote sensing instruments, either ground based or balloon-borne. Most of the ground based instruments are part of the Network for Detection of Stratospheric Change (NDSC), including a very high spectral resolution solar absorption spectrometer at Mauna Loa Observatory and similar system at McMurdo Station, Antarctica (operated in collaboration with the New Zealand NIWA). Additionally, we are deriving stratospheric constituent data from the spectra obtained at the DOE Atmospheric Radiation Measurements (ARM) program's site in north-central Oklahoma. We have an atmospheric emission spectrometer system at the South Pole (with additional support from NSF), and an identical NSF support instrument at Eureka, NWT, Canada. Our balloon-borne instruments include a very high resolution solar absorption spectrometer system, a smaller, slightly lower resolution solar spectrometer system, a high resolution atmospheric emission spectrometer, and several medium resolution emission spectrometers (CAESRs) that are usually flown piggyback. During the past year, we participated in the MANTRA balloon flight from Saskatoon, Saskatchewan, with the high resolution solar spectrometer system. Several of our instruments were extensively compared to (UARS) Upper Atmosphere Research Satellite observations, and so provide a data set with known connections to UARS. In the longer term, the data can be used to relate UARS data to (EOS) Earth Observing System and (ADEOS) Advanced Airborne Earth Observing System.

  6. Models for infrared atmospheric radiation

    NASA Technical Reports Server (NTRS)

    Tiwari, S. N.

    1976-01-01

    Line and band models for infrared spectral absorption are discussed. Radiative transmittance and integrated absorptance of Lorentz, Doppler, and voigt line profiles were compared for a range of parameters. It was found that, for the intermediate path lengths, the combined Lorentz-Doppler (Voigt) profile is essential in calculating the atmospheric transmittance. Narrow band model relations for absorptance were used to develop exact formulations for total absorption by four wide band models. Several continuous correlations for the absorption of a wide band model were compared with the numerical solutions of the wide band models. By employing the line-by-line and quasi-random band model formulations, computational procedures were developed for evaluating transmittance and upwelling atmospheric radiance. Homogeneous path transmittances were calculated for selected bands of CO, CO2, and N2O and compared with experimental measurements. The upwelling radiance and signal change in the wave number interval of the CO fundamental band were also calculated.

  7. Four Years of Absolutely Calibrated Hyperspectral Data from the Atmospheric Infrared Sounder (AIRS) on the Eos Aqua

    NASA Technical Reports Server (NTRS)

    Aumann, Hartmut H.; Broberg, Steve; Elliott, Denis; Gregorich, Dave

    2006-01-01

    This viewgraph presentation reviews four years of absolute calibration of hyperspectral data from the AIRS instrument located on the EOS AQUA spacecraft. The following topics are discussed: 1) A quick overview of AIRS; 2) What absolute calibration accuracy and stability are required for climate applications?; 3) Validating of radiance accuracy and stability: Results from four years of AIRS data; and 4) Conclusions.

  8. Infrared band absorptance correlations and applications to nongray radiation. [mathematical models of absorption spectra for nongray atmospheres in order to study air pollution

    NASA Technical Reports Server (NTRS)

    Tiwari, S. N.; Manian, S. V. S.

    1976-01-01

    Various mathematical models for infrared radiation absorption spectra for atmospheric gases are reviewed, and continuous correlations for the total absorptance of a wide band are presented. Different band absorptance correlations were employed in two physically realistic problems (radiative transfer in gases with internal heat source, and heat transfer in laminar flow of absorbing-emitting gases between parallel plates) to study their influence on final radiative transfer results. This information will be applied to the study of atmospheric pollutants by infrared radiation measurement.

  9. Infrared Signature Masking by Air Plasma Radiation

    NASA Technical Reports Server (NTRS)

    Kruger, Charles H.; Laux, C. O.

    2001-01-01

    This report summarizes the results obtained during a research program on the infrared radiation of air plasmas conducted in the High Temperature Gasdynamics Laboratory at Stanford University under the direction of Professor Charles H. Kruger, with Dr. Christophe O. Laux as Associate Investigator. The goal of this research was to investigate the masking of infrared signatures by the air plasma formed behind the bow shock of high velocity missiles. To this end, spectral measurements and modeling were made of the radiation emitted between 2.4 and 5.5 micrometers by an atmospheric pressure air plasma in chemical and thermal equilibrium at a temperature of approximately 3000 K. The objective was to examine the spectral emission of air species including nitric oxide, atomic oxygen and nitrogen lines, molecular and atomic continua, as well as secondary species such as water vapor or carbon dioxide. The cold air stream injected in the plasma torch contained approximately 330 parts per million of CO2, which is the natural CO2 concentration in atmospheric air at room temperatures, and a small amount of water vapor with an estimated mole fraction of 3.8x10(exp -4).

  10. On Cirrus Cloud Fields Measured by the Atmospheric Infrared Sounder

    NASA Technical Reports Server (NTRS)

    Kahn, Brian H.; Eldering, Annmarie; Liou, Kuo Nan

    2006-01-01

    A viewgraph presentation showing trends in clouds measured by the Atmospheric Infrared Sounder (AIRS) is given. The topics include: 1) Trends in clouds measured by AIRS: Are they reasonable? 2) Single and multilayered cloud trends; 3) Retrievals of thin cirrus D(sub e) and tau: Single-layered cloud only; 4) Relationships between ECF, D(sub e), tau, and T(sub CLD); and 5) MODIS vs. AIRS retrievals.

  11. Infrared Signature Masking by Air Plasma Radiation

    NASA Technical Reports Server (NTRS)

    Kruger, C. H.; Laux, C. O.

    1998-01-01

    This report describes progress during the second year of our research program on Infrared Signature Masking by Air Plasmas at Stanford University. This program is intended to investigate the masking of infrared signatures by the air plasma formed behind the bow shock of high velocity missiles. Our previous annual report described spectral measurements and modeling of the radiation emitted between 3.2 and 5.5 microns by an atmospheric pressure air plasma in chemical and thermal equilibrium at a temperature of approximately 3100 K. One of our goals was to examine the spectral emission of secondary species such as water vapor or carbon dioxide. The cold air stream injected in the plasma torch contained approximately 330 parts per million Of CO2, which is the natural CO2 concentration in atmospheric air at room temperature, and a small amount of water vapor with an estimated mole fraction of 3.8 x 10(exp -4). As can be seen from Figure 1, it was found that the measured spectrum exhibited intense spectral features due to the fundamental rovibrational bands of NO at 4.9 - 5.5 microns and the V(3) band of CO2 (antisymmetric stretch) at 4.2-4.8 microns. These observations confirmed the well-known fact that infrared signatures between 4.15 - 5.5 microns can be masked by radiative emission in the interceptor's bow-shock. Figure I also suggested that the range 3.2 - 4.15 microns did not contain any significant emission features (lines or continuum) that could mask IR signatures. However, the signal-to-noise level, close to one in that range, precluded definite conclusions. Thus, in an effort to further investigate the spectral emission in the range of interest to signature masking problem, new measurements were made with a higher signal-to-noise ratio and an extended wavelength range.

  12. Infrared measurements of atmospheric constituents

    NASA Technical Reports Server (NTRS)

    Murcray, David G.; Murcray, Frank J.; Goldman, Aaron; Rinsland, Curtis P.; Camy-Peyret, C.; Flaud, J. M.

    1990-01-01

    The objective of this program is to obtain data concerning the concentration versus altitude of various constituents of interest in the photochemistry of the stratospheric ozone layer. Data pertinent to this objective are obtained using balloon-borne instruments to measure the atmospheric transmission and emission in the mid infrared. In addition to obtaining constituent profile information, the spectral data obtained are also used to identify absorption or emission features which may interfere with the retrieval of constituent data from satellite instruments using lower spectral resolution. The spectral resolution obtained with the solar spectral system is 0.0025 cm(exp -1) and represents about a factor of 5 greater resolution than any solar spectra previously obtained in this spectral region. As a result of the increase in spectral resolution, a large number of features are observed in these spectra which were not observed in previous studies. Identification and analysis of these features is in progress. The results of this analysis to date shows a number of HNO3 features which have not been observed before, and these occur where they will interfere with the retrieval of other constituents. An example of the interference is the occurrence of features in the 780.2 cm(exp -1) region which overlap the ClONO2 feature which will be used for retrieval of ClONO2 by the CLAES instrument on UARS. A number of features due to COF2 were also identified in the 1250 cm(exp -1) region which may interfere with retrieval of N2O5.

  13. Advanced microwave sounding unit study for atmospheric infrared sounder

    NASA Technical Reports Server (NTRS)

    Rosenkranz, Philip W.; Staelin, David H.

    1992-01-01

    The Atmospheric Infrared Sounder (AIRS), the Advanced Microwave Sounding Unit (AMSU-A), and the Microwave Humidity Sounder (MHS, formerly AMSU-B) together constitute the advanced sounding system facility for the Earth Observing System (EOS). A summary of the EOS phase B activities are presented.

  14. Infrared laboratory studies of synthetic planetary atmospheres

    NASA Technical Reports Server (NTRS)

    Williams, D.

    1973-01-01

    Previous research dealing with telluric gases is briefly reviewed. Current research concerning absorption-line broadening, and particulate constituents of planetary atmospheres are discussed. Two articles are included: optical constants of liquid ammonia in the infrared, and broadening of infrared absorption lines at reduced temperatures for nitrous oxide.

  15. Atmospheric Chemistry and Air Pollution

    DOE PAGES

    Gaffney, Jeffrey S.; Marley, Nancy A.

    2003-01-01

    Atmospheric chemistry is an important discipline for understanding air pollution and its impacts. This mini-review gives a brief history of air pollution and presents an overview of some of the basic photochemistry involved in the production of ozone and other oxidants in the atmosphere. Urban air quality issues are reviewed with a specific focus on ozone and other oxidants, primary and secondary aerosols, alternative fuels, and the potential for chlorine releases to amplify oxidant chemistry in industrial areas. Regional air pollution issues such as acid rain, long-range transport of aerosols and visibility loss, and the connections of aerosols to ozonemore » and peroxyacetyl nitrate chemistry are examined. Finally, the potential impacts of air pollutants on the global-scale radiative balances of gases and aerosols are discussed briefly.« less

  16. Atmospheric chemistry and air pollution.

    PubMed

    Gaffney, Jeffrey S; Marley, Nancy A

    2003-04-07

    Atmospheric chemistry is an important discipline for understanding air pollution and its impacts. This mini-review gives a brief history of air pollution and presents an overview of some of the basic photochemistry involved in the production of ozone and other oxidants in the atmosphere. Urban air quality issues are reviewed with a specific focus on ozone and other oxidants, primary and secondary aerosols, alternative fuels, and the potential for chlorine releases to amplify oxidant chemistry in industrial areas. Regional air pollution issues such as acid rain, long-range transport of aerosols and visibility loss, and the connections of aerosols to ozone and peroxyacetyl nitrate chemistry are examined. Finally, the potential impacts of air pollutants on the global-scale radiative balances of gases and aerosols are discussed briefly.

  17. Atmospheric monitoring with an infrared radiometer

    NASA Astrophysics Data System (ADS)

    Daniel, M. K.; Chadwick, P. M.

    2015-03-01

    The molecular atmosphere has a number of windows where it is effectively transparent to electromagnetic radiation, one of these being in the infrared 8-14 micron region. The presence of clouds and aerosols, which are more effective emitters of infrared radiation, in the atmosphere show up as an increase in the effective brightness temperature compared to the clear sky. This talk will cover the results from operating a scanning radiometer at the H.E.S.S. site in Namibia in determining atmospheric conditions.

  18. Airborne laser systems for atmospheric sounding in the near infrared

    NASA Astrophysics Data System (ADS)

    Sabatini, Roberto; Richardson, Mark A.; Jia, Huamin; Zammit-Mangion, David

    2012-06-01

    This paper presents new techniques for atmospheric sounding using Near Infrared (NIR) laser sources, direct detection electro-optics and passive infrared imaging systems. These techniques allow a direct determination of atmospheric extinction and, through the adoption of suitable inversion algorithms, the indirect measurement of some important natural and man-made atmospheric constituents, including Carbon Dioxide (CO2). The proposed techniques are suitable for remote sensing missions performed by using aircraft, satellites, Unmanned Aerial Vehicles (UAV), parachute/gliding vehicles, Roving Surface Vehicles (RSV), or Permanent Surface Installations (PSI). The various techniques proposed offer relative advantages in different scenarios. All are based on measurements of the laser energy/power incident on target surfaces of known geometric and reflective characteristics, by means of infrared detectors and/or infrared cameras calibrated for radiance. Experimental results are presented relative to ground and flight trials performed with laser systems operating in the near infrared (NIR) at λ = 1064 nm and λ = 1550 nm. This includes ground tests performed with 10 Hz and 20 KHz PRF NIR laser systems in a variety of atmospheric conditions, and flight trials performed with a 10 Hz airborne NIR laser system installed on a TORNADO aircraft, flying up to altitudes of 22,000 ft above ground level. Future activities are planned to validate the atmospheric retrieval algorithms developed for CO2 column density measurements, with emphasis on aircraft related emissions at airports and other high air-traffic density environments.

  19. Clean Air Slots Amid Atmospheric Pollution

    NASA Technical Reports Server (NTRS)

    Hobbs, Peter V.

    2002-01-01

    This article investigates the mechanism for those layers in the atmosphere that are free of air borne pollution even though the air above and below them carry pollutants. Atmospheric subsidence is posed as a mechanism for this phenomenon.

  20. A Simple Drought Product and Indicator Derived from Temperature and Relative Humidity Observed by the Atmospheric InfraRed Sounder (AIRS)

    NASA Astrophysics Data System (ADS)

    Granger, S. L.; Behrangi, A.

    2015-12-01

    In the United States, drought results in agricultural losses, impacts to industry, power and energy production, natural resources, municipal water supplies and human health making it one of the costliest natural hazards in the nation. Monitoring drought is therefore critical to help local governments, resource managers, and other groups make effective decisions, yet there is no single definition of drought, and because of the complex nature of drought there is no universal best drought indicator. Remote sensing applications in drought monitoring are advantageous due to the large spatial and temporal frequency of observations, leading to a better understanding of the spatial extent of drought and its duration, and in detecting the onset of drought and its intensity. NASA Earth Observing System (EOS)-era data have potential for monitoring and assessing drought and many are already used either directly or indirectly for drought monitoring. Land Surface Temperature (LST) and Normalized Difference Vegetation Index (NDVI) observations from the Moderate Resolution Imaging Spectro-radiometer (MODIS) sensor are widely used for agricultural and environmental plant-stress monitoring via the USDM, the VegDRI project and FEWSNet. However there remain underutilized sources of information from NASA satellite observations that may have promise for characterizing and understanding meteorological drought. Once such sensor is NASA's Advanced Infra-Red Sounder (AIRS) aboard the Aqua satellite. AIRS and it's sister sensor the Advanced Microwave Sounding Unit (AMSU) that together provide meteorological information of high relevance to meteorological drought, e.g., profiles of water vapor, surface air temperature, and precipitation. Recent work undertaken to develop simple indicators of drought based on temperature and relative humidity from the AIRS suite of instruments is promising. Although there are more sophisticated indicators developed through the application of a variety of

  1. Infrared radiation models for atmospheric methane

    NASA Technical Reports Server (NTRS)

    Cess, R. D.; Kratz, D. P.; Caldwell, J.; Kim, S. J.

    1986-01-01

    Mutually consistent line-by-line, narrow-band and broad-band infrared radiation models are presented for methane, a potentially important anthropogenic trace gas within the atmosphere. Comparisons of the modeled band absorptances with existing laboratory data produce the best agreement when, within the band models, spurious band intensities are used which are consistent with the respective laboratory data sets, but which are not consistent with current knowledge concerning the intensity of the infrared fundamental band of methane. This emphasizes the need for improved laboratory band absorptance measurements. Since, when applied to atmospheric radiation calculations, the line-by-line model does not require the use of scaling approximations, the mutual consistency of the band models provides a means of appraising the accuracy of scaling procedures. It is shown that Curtis-Godson narrow-band and Chan-Tien broad-band scaling provide accurate means of accounting for atmospheric temperature and pressure variations.

  2. The research on the effect of atmospheric transmittance for the measuring accuracy of infrared thermal imager

    NASA Astrophysics Data System (ADS)

    Zhang, Yu-cun; Chen, Yi-ming; Fu, Xian-bin; Luo, Cheng

    2016-07-01

    The effect of atmospheric transmittance on infrared thermal imager temperature measuring accuracy cannot be ignored when the object is far from infrared thermal imager. In this paper, a method of reducing the influence of atmospheric transmittance is proposed for the infrared thermal imager. Firstly, the temperature measuring formula of infrared thermal imager and the effect of atmospheric transmittance on temperature measuring accuracy is analyzed. According to the composition of the atmosphere, the main factors influencing the atmosphere transmittance are determined. Secondly, the temperature measuring model of infrared thermal imager in sea level is established according to the absorption of water vapor and carbon dioxide, the scattering of air molecules and aerosol particulate, and the attenuation effects of weather conditions such as rain and snow. Finally, the correctness and feasibility of the proposed model is verified by the comparison experiments of four different environmental conditions. According to the experiments, the temperature measuring accuracy of the infrared thermal imager is improved.

  3. Infrared Laser System for Extended Area Monitoring of Air Pollution

    NASA Technical Reports Server (NTRS)

    Snowman, L. R.; Gillmeister, R. J.

    1971-01-01

    An atmospheric pollution monitoring system using a spectrally scanning laser has been developed by the General Electric Company. This paper will report on an evaluation of a breadboard model, and will discuss applications of the concept to various ambient air monitoring situations. The system is adaptable to other tunable lasers. Operating in the middle infrared region, the system uses retroreflectors to measure average concentrations over long paths at low, safe power levels. The concept shows promise of meeting operational needs in ambient air monitoring and providing new data for atmospheric research.

  4. Retrievals with the Infrared Atmospheric Sounding Interferometer

    NASA Technical Reports Server (NTRS)

    Zhou, Daniel K.; Liu, Xu; Larar, Allen M.; Smith, William L.; Taylor, Jonathan P.; Schlussel, Peter; Strow, L. Larrabee; Calbet, Xavier; Mango, Stephen A.

    2007-01-01

    The Infrared Atmospheric Sounding Interferometer (IASI) on the MetOp satellite was launched on October 19, 2006. The Joint Airborne IASI Validation Experiment (JAIVEx) was conducted during April 2007 mainly for validation of the IASI on the MetOp satellite. IASI possesses an ultra-spectral resolution of 0.25/cm and a spectral coverage from 645 to 2760/cm. Ultraspectral resolution infrared spectral radiance obtained from near nadir observations provide atmospheric, surface, and cloud property information. An advanced retrieval algorithm with a fast radiative transfer model, including cloud effects, is used for atmospheric profile and cloud parameter retrieval. Preliminary retrievals of atmospheric soundings, surface properties, and cloud optical/microphysical properties with the IASI observations during the JAIVEx are obtained and presented. These retrievals are further inter-compared with those obtained from airborne FTS system, such as the NPOESS Airborne Sounder Testbed Interferometer (NAST-I), dedicated dropsondes, radiosondes, and ground based Raman Lidar. The capabilities of satellite ultra-spectral sounder such as the IASI are investigated.

  5. The Atmospheric Infrared Sounder Version 6 Cloud Products

    NASA Technical Reports Server (NTRS)

    Kahn, B. H.; Irion, F. W.; Dang, V. T.; Manning, E. M.; Nasiri, S. L.; Naud, C. M.; Blaisdell, J. M.; Schreier, M. M..; Yue, Q.; Bowman, K. W.; Fetzer, E. J.; Hulley, G. C.; Liou, K. N.; Lubin, D.; Ou, S. C.; Susskind, J.; Takano, Y.; Tian, B.; Worden, J. R.

    2014-01-01

    The version 6 cloud products of the Atmospheric Infrared Sounder (AIRS) and Advanced Microwave Sounding Unit (AMSU) instrument suite are described. The cloud top temperature, pressure, and height and effective cloud fraction are now reported at the AIRS field-of-view (FOV) resolution. Significant improvements in cloud height assignment over version 5 are shown with FOV-scale comparisons to cloud vertical structure observed by the CloudSat 94 GHz radar and the Cloud-Aerosol LIdar with Orthogonal Polarization (CALIOP). Cloud thermodynamic phase (ice, liquid, and unknown phase), ice cloud effective diameter D(sub e), and ice cloud optical thickness (t) are derived using an optimal estimation methodology for AIRS FOVs, and global distributions for 2007 are presented. The largest values of tau are found in the storm tracks and near convection in the tropics, while D(sub e) is largest on the equatorial side of the midlatitude storm tracks in both hemispheres, and lowest in tropical thin cirrus and the winter polar atmosphere. Over the Maritime Continent the diurnal variability of tau is significantly larger than for the total cloud fraction, ice cloud frequency, and D(sub e), and is anchored to the island archipelago morphology. Important differences are described between northern and southern hemispheric midlatitude cyclones using storm center composites. The infrared-based cloud retrievals of AIRS provide unique, decadal-scale and global observations of clouds over portions of the diurnal and annual cycles, and capture variability within the mesoscale and synoptic scales at all latitudes.

  6. Thermal Band Atmospheric Correction Using Atmospheric Profiles Derived from Global Positioning System Radio Occultation and the Atmospheric Infrared Sounder

    NASA Technical Reports Server (NTRS)

    Pagnutti, Mary; Holekamp, Kara; Stewart, Randy; Vaughan, Ronald D.

    2006-01-01

    This Rapid Prototyping Capability study explores the potential to use atmospheric profiles derived from GPS (Global Positioning System) radio occultation measurements and by AIRS (Atmospheric Infrared Sounder) onboard the Aqua satellite to improve surface temperature retrieval from remotely sensed thermal imagery. This study demonstrates an example of a cross-cutting decision support technology whereby NASA data or models are shown to improve a wide number of observation systems or models. The ability to use one data source to improve others will be critical to the GEOSS (Global Earth Observation System of Systems) where a large number of potentially useful systems will require auxiliary datasets as input for decision support. Atmospheric correction of thermal imagery decouples TOA radiance and separates surface emission from atmospheric emission and absorption. Surface temperature can then be estimated from the surface emission with knowledge of its emissivity. Traditionally, radiosonde sounders or atmospheric models based on radiosonde sounders, such as the NOAA (National Oceanic & Atmospheric Administration) ARL (Air Resources Laboratory) READY (Real-time Environmental Application and Display sYstem), provide the atmospheric profiles required to perform atmospheric correction. Unfortunately, these types of data are too spatially sparse and too infrequently taken. The advent of high accuracy, global coverage, atmospheric data using GPS radio occultation and AIRS may provide a new avenue for filling data input gaps. In this study, AIRS and GPS radio occultation derived atmospheric profiles from the German Aerospace Center CHAMP (CHAllenging Minisatellite Payload), the Argentinean Commission on Space Activities SAC-C (Satellite de Aplicaciones Cientificas-C), and the pair of NASA GRACE (Gravity Recovery and Climate Experiment) satellites are used as input data in atmospheric radiative transport modeling based on the MODTRAN (MODerate resolution atmospheric

  7. Infrared radiation models for atmospheric ozone

    NASA Technical Reports Server (NTRS)

    Kratz, David P.; Ces, Robert D.

    1988-01-01

    A hierarchy of line-by-line, narrow-band, and broadband infrared radiation models are discussed for ozone, a radiatively important atmospheric trace gas. It is shown that the narrow-band (Malkmus) model is in near-precise agreement with the line-by-line model, thus providing a means of testing narrow-band Curtis-Godson scaling, and it is found that this scaling procedure leads to errors in atmospheric fluxes of up to 10 percent. Moreover, this is a direct consequence of the altitude dependence of the ozone mixing ratio. Somewhat greater flux errors arise with use of the broadband model, due to both a lesser accuracy of the broadband scaling procedure and to inherent errors within the broadband model, despite the fact that this model has been tuned to the line-by-line model.

  8. Channel alignment and radiometry in hyperspectral atmospheric infrared sounders

    NASA Technical Reports Server (NTRS)

    Elliott, Denis A.; Aumanna, H. H.; Pagano, Thomas S.; Overoye, Kenneth R.; Schindler, Rudolf A.

    2005-01-01

    The Atmospheric Infrared Sounder (AIRS) is a hyper-spectral infrared sounder which covers the 3.7 to 15,4 micron region with 2378 spectral channels. The AIRS instrument specification called for spatial co-registration of all channels to better than 2% of the field of view. Pre-launch testing confirmed that this requirement was met, since the standard deviations in the centroids was about 1% of the 13.5 km IFOV in scan and 3% in track. Detailed analysis of global AIRS data show that the typical scene gradient in 10 micron window channels is about I .3K/km rms. The way these gradients, which are predominantly caused by clouds, manifest themselves in the data depends on the details of the instrument design and the way the spectral channels are used in the data analysis, AIRS temperature and moisture retrievals use 328 of the 2378 channels from 17 independent arrays. As a result, the effect of the boresight misalignment averages to zero mean. Any increase in the effective noise is less than 0.2K. Also, there is no discernable performance degradation of products at the 45 km spatial resolution in the presence of partially cloudy scenes with up to 80% cloudiness. Single pixel radiometric differences between channels with boresight alignment differences can be appreciable and can affect scientific investigations on a single 15km footprint scale, particularly near coastlines, thunderstorms and surface emissivity inhomogeneities.

  9. Results from A Simple Infrared Atmospheric Radiometer

    NASA Astrophysics Data System (ADS)

    Maghrabi, Abdullrahman; Clay, Rpger

    2015-04-01

    Longwave radiation (wavelength 4.0-100 μm) is a key term in the surface energy budget and is vitally important for meteorology, climatology, remote sensing, and the study of radiative cooling of buildings, solar energy collection, and vegetation. Detailed data of this radiation is of great importance but it requires costly equipments. We have developed a single pixel infrared (IR) detector based on commercial IR thermopile sensors. The detectors are developed with different fields of view (FOV) and have a spectral response which extends from 5.5 μm to above 20 μm. These detectors were used for different atmospheric applications and studies. This paper aims to give a detailed description of these detectors, and the methodology followed to construct and calibrate them. Results from observations with these detectors will be given.

  10. Infrared imaging-spectroscopic observations of Venus atmosphere

    NASA Astrophysics Data System (ADS)

    Ohtsuki, Shoko; Sagawa, Hideo; Ueno, Munetaka

    2005-01-01

    We present a report on our recent observations of Venus atmosphere which we have performed in infrared wavelength at Okayama Astrophysical Observatory. The data show important results on the CO distribution and on O2 IRA (0,0) 1.27μm airglow in the atmosphere. The infrared windows of the Venusian atmosphere are rather developing areas and will give us important information on the dynamics of Venus atmosphere.

  11. Causality arguments behind closed-form description of air dispersion in the mid-infrared

    NASA Astrophysics Data System (ADS)

    Zheltikov, A. M.

    2017-04-01

    We show that a closed-form Sellmeier-equation description of the refractive index of atmospheric air can be extended to the mid- and long-wavelength infrared spectral ranges, where the optical response of air is dominated by molecular rovibrational modes. When written in the form of a Sellmeier-type equation, the formula of air refractivity is shown to be instrumental for the analysis of group-velocity dispersion of atmospheric air, helping identify the regions of broadband anomalous dispersion, where long-distance transmission and soliton pulse compression of high-power mid- and long-wavelength infrared field waveforms are possible.

  12. Thermal Infrared Radiative Forcing By Atmospheric Aerosol

    NASA Astrophysics Data System (ADS)

    Adhikari, Narayan

    The work mainly focuses on the study of thermal infrared (IR) properties of atmospheric greenhouse gases and aerosols, and the estimation of the aerosol-induced direct longwave (LW) radiative forcing in the spectral region 5-20 mum at the Earth's surface (BOA; bottom of the atmosphere) and the top of the atmosphere (TOA) in cloud-free atmospheric conditions. These objectives were accomplished by conducting case studies on clear sky, smoky, and dusty conditions that took place in the Great Basin of the USA in 2013. Both the solar and thermal IR measurements and a state-of-the-science radiative transfer model, the LBLDIS, a combination of the Line-By-Line Radiative Transfer Model and the Discrete Ordinate Radiative Transfer (DISORT) solver were employed for the study. The LW aerosol forcing is often not included in climate models because the aerosol effect on the LW is often assumed to be negligible. We lack knowledge of aerosol characteristics in the LW region, and aerosol properties exhibit high variability. We have found that the LW TOA radiative forcing due to fine mode aerosols, mainly associated with small biomass burning smoke particles, is + 0.4 W/m2 which seems to be small, but it is similar to the LW radiative forcing due to increase in CO2 concentration in the Earth's atmosphere since the preindustrial era of 1750 (+ 1.6 W/m 2). The LW radiative forcing due to coarse mode aerosols, associated with large airborne mineral dust particles, was found to be as much as + 5.02 W/m2 at the surface and + 1.71 W/m2 at the TOA. All of these significant positive values of the aerosol radiative forcing both at the BOA and TOA indicate that the aerosols have a heating effect in the LW range, which contributes to counterbalancing the cooling effect associated with the aerosol radiative forcing in the shortwave (SW) spectral region. In the meantime, we have found that LW radiative forcing by aerosols is highly sensitive to particle size and complex refractive indices of

  13. Propagation of infrared radiation in a naturally obscured atmosphere

    NASA Astrophysics Data System (ADS)

    Winchester, L. W., Jr.; Gimmestad, G. G.; Lee, S. M.; Wilburn, D. K.

    1981-07-01

    An integrated model of target vehicle signatures must include a description of the effect of transmission of electromagnetic radiation through the atmosphere between the target and the threat sensor devices. A number of models published by various investigators are in use to describe this transmission phenomenon. These models predict fairly accurately the attenuation of light as it propagates through clear air, indicating that they account for the molecular absorption reasonably well. They are not as accurate when the atmosphere contains small particles such as those in rain, fog, snow, etc. In adverse atmospheric conditions, the scattering process becomes comparatively more important and must also be considered. In this report, a detailed investigation is presented for the scattering of infrared radiation by atmospheric aerosols. The theoretical analysis is compared to the measured data obtained at the Keweenaw Research Center (KRC). The analysis and the results are compared to the prediction of other available models. In addition, the implication of the present work on the ongoing TACOM/KRC modeling effort of target signature is discussed.

  14. Air Activation Following an Atmospheric Explosion

    SciTech Connect

    Lowrey, Justin D.; McIntyre, Justin I.; Prichard, Andrew W.; Gesh, Christopher J.

    2013-03-13

    In addition to thermal radiation and fission products, nuclear explosions result in a very high flux of unfissioned neutrons. Within an atmospheric nuclear explosion, these neutrons can activate the various elemental components of natural air, potentially adding to the radioactive signature of the event as a whole. The goal of this work is to make an order-of-magnitude estimate of the total amount of air activation products that can result from an atmospheric nuclear explosion.

  15. How Well Can Infrared Sounders Observe the Atmosphere and Surface Through Clouds?

    NASA Technical Reports Server (NTRS)

    Zhou, Daniel K.; Larar, Allen M.; Liu, Xu; Smith, William L.; Strow, L. Larrabee; Yang, Ping

    2010-01-01

    Infrared sounders, such as the Atmospheric Infrared Sounder (AIRS), the Infrared Atmospheric Sounding Interferometer (IASI), and the Cross-track Infrared sounder (CrIS), have a cloud-impenetrable disadvantage in observing the atmosphere and surface under opaque cloudy conditions. However, recent studies indicate that hyperspectral, infrared sounders have the ability to detect cloud effective-optical and microphysical properties and to penetrate optically thin clouds in observing the atmosphere and surface to a certain degree. We have developed a retrieval scheme dealing with atmospheric conditions with cloud presence. This scheme can be used to analyze the retrieval accuracy of atmospheric and surface parameters under clear and cloudy conditions. In this paper, we present the surface emissivity results derived from IASI global measurements under both clear and cloudy conditions. The accuracy of surface emissivity derived under cloudy conditions is statistically estimated in comparison with those derived under clear sky conditions. The retrieval error caused by the clouds is shown as a function of cloud optical depth, which helps us to understand how well infrared sounders can observe the atmosphere and surface through clouds.

  16. Infrared measurements of atmospheric CH3CN

    NASA Technical Reports Server (NTRS)

    Kleinbohl, Armin; Toon, Geoffrey C.; Bhaswar, Sen; Blavier, Jean--Francois; Weisenstein, Debra K.; Wennberg, Paul O.

    2005-01-01

    For the first time CH3CN has been measured in the Earth's atmosphere by means of infrared remote sensing. Vertical profiles of volume mixing ratio were retrieved from 12 solar occultation measurements by the balloon-borne JPL MkIV interferometer between 1993 and 2004. Profile retrieval is possible in an altitude range between 12 and 30 km with a precision of _20 ppt in the Arctic and _30 ppt at mid-latitudes. The retrieved CH3CN profiles show mixing ratios of 100-150 ppt a few kilometers above the tropopause that decrease to values below 40 ppt at altitudes between 22 and 30 km. The CH3CN mixing ratios show a reasonably compact correlation with the stratospheric tracers CH3Cl and CH4. The CH3CN altitude profiles and tracer correlations are well reproduced by a 2-dimensional model, suggesting that CH3CN is long-lived in the lower stratosphere and that previously-proposed ion-molecule reactions do not play a major role as loss processes of CH3CN.

  17. Impact assessment of additional predictors to the retrieval of atmospheric profiles from infrared radiances

    NASA Astrophysics Data System (ADS)

    Jiang, Deming; Dong, Chaohua; Huo, Ruili; Cai, Ronghui

    2008-12-01

    Impacts of additional predictors on inverting atmospheric infrared radiance for temperature and humidity profiles are investigated using Atmospheric Infrared Sounder (AIRS) real measurements and empirical orthogonal function expansion method (EOF). These predictors are microwave channels, latitude, topography, surface altitude, surface temperature, and surface air pressure. The results suggest that microwave channels can remarkably help the improvement of the accuracy of retrieved profiles at lower troposphere (below 800hPa) and have little effect on that above 800hPa. With dataset classified by latitude, better retrievals are obtained. The root mean square errors (RMSE) of retrieved temperature at complicated terrain are significantly greater than that at plat area. For humidity retrievals it was found that RMSE exhibit weak sensitivity to topography. By combined use of infrared measurements and additional predictors, great improvements have achieved in the retrieval of atmospheric temperature and humidity profiles at lower troposphere.

  18. Clean Air Slots Amid Atmospheric Pollution

    NASA Technical Reports Server (NTRS)

    Hobbs, Peter V.

    2002-01-01

    Layering in the Earth's atmosphere is most commonly seen where parts of the atmosphere resist the incursion of air parcels from above and below - for example, when there is an increase in temperature with height over a particular altitude range. Pollutants tend to accumulate underneath the resulting stable layers. which is why visibility often increases markedly above certain altitudes. Here we describe the occurrence of an opposite effect, in which stable layers generate a layer of remarkably clean air (we refer to these layers as clean-air 'slots') sandwiched between layers of polluted air. We have observed clean-air slots in various locations around the world, but they are particularly well defined and prevalent in southern Africa during the dry season August-September). This is because at this time in this region, stable layers are common and pollution from biomass burning is widespread.

  19. Jupiter's atmospheric composition from the Cassini thermal infrared spectroscopy experiment

    NASA Technical Reports Server (NTRS)

    Kunde, V. G.; Flasar, F. M.; Jennings, D. E.; Bezard, B.; Strobel, D. F.; Conrath, B. J.; Nixon, C. A.; Bjoraker, G. L.; Romani, P. N.; Achterberg, R. K.; Simon-Miller, A. A.; Irwin, P.; Brasunas, J. C.; Pearl, J. C.; Smith, M. D.; Orton, G. S.; Gierasch, P. J.; Spilker, L. J.; Carlson, R. C.; Mamoutkine, A. A.; Calcutt, S. B.; Read, P. L.; Taylor, F. W.; Fouchet, T.; Parrish, P.

    2004-01-01

    The Composite Infrared Spectrometer observed Jupiter in the thermal infrared during the swing-by of the Cassini spacecraft. Results include the detection of two new stratospheric species, the methyl radical and diacetylene, gaseous species present in the north and south auroral infrared hot spots; determination of the variations with latitude of acetylene and ethane, the latter a tracer of atmospheric motion; observations of unexpected spatial distributions of carbon dioxide and hydrogen cyanide, both considered to be products of comet Shoemaker-Levy 9 impacts; characterization of the morphology of the auroral infrared hot spot acetylene emission; and a new evaluation of the energetics of the northern auroral infrared hot spot.

  20. Infrared experiments for spaceborne planetary atmospheres research. Full report

    NASA Technical Reports Server (NTRS)

    1981-01-01

    The role of infrared sensing in atmospheric science is discussed and existing infrared measurement techniques are reviewed. Proposed techniques for measuring planetary atmospheres are criticized and recommended instrument developments for spaceborne investigations are summarized for the following phenomena: global and local radiative budget; radiative flux profiles; winds; temperature; pressure; transient and marginal atmospheres; planetary rotation and global atmospheric activity; abundances of stable constituents; vertical, lateral, and temporal distribution of abundances; composition of clouds and aerosols; radiative properties of clouds and aerosols; cloud microstructure; cloud macrostructure; and non-LTE phenomena.

  1. Infrared differential absorption for atmospheric pollutant detection

    NASA Technical Reports Server (NTRS)

    Byer, R. L.

    1974-01-01

    Progress made in the generation of tunable infrared radiation and its application to remote pollutant detection by the differential absorption method are summarized. It is recognized that future remote pollutant measurements depended critically on the availability of high energy tunable transmitters. Futhermore, due to eye safety requirements, the transmitted frequency must lie in the 1.4 micron to 13 micron infrared spectral range.

  2. Investigation of infra-red and nonequilibrium air radiation

    NASA Technical Reports Server (NTRS)

    Kruger, Charles H.

    1995-01-01

    This report describes progress on the first year of a research program on the infrared radiation of air plasmas conducted in the High Temperature Gasdynamics Laboratory at Stanford University. This program is intended to investigate the masking of infrared signatures by the air plasma formed behind the bow shock of high velocity missiles. To this date, the radiative emission of air plasmas in the infrared has been the object of few experimental investigations, and although several infrared systems are already modeled in radiation codes such as NEQAIR, measurements are required to validate numerical predictions and indicate whether all transitions of importance are accounted for. The present program is motivated by the fact that 9 excited states (A, B, C, D, B', F, H, and H') of NO radiate in the infrared, especially between 1 and 1.5 microns where at least 9 transitions involving can be observed. Because these IR transitions are relatively well separated from each other, excited NO states concentrations can be easily measured, thus providing essential information on excited-state chemistry for use in optical diagnostics or in electronic excitation model validation. Developing accurate collisional-radiative models for these excited NO states is of importance as the UV-VUV transitions of NO (beta, gamma, epsilon, beta prime, gamma prime) produce a major, if not dominant, fraction of the radiation emitted by air plasmas. During the first year of the program, research has focused on the spectral range 1.0 to 1.5 microns, as detailed in Section 2 of this report. The measurements, conducted in a 50 kW radio-frequency inductively coupled plasma torch operating on air at atmospheric pressure, extend previous shock tube investigations by Wray to a wider spectral range (1.0 to 1.5 microns vs 0.9 to 1.2 microns) and higher temperatures (7600 K in the plasma torch versus 6700 K in the shock-tube). These higher temperatures in the present experiment have made it possible to

  3. Spectral measurements of the atmospheric thermal infrared emission in Antarctica

    NASA Astrophysics Data System (ADS)

    Palchetti, L.; Bianchini, G.; Del Guasta, M.; Baglioni, A.

    2012-12-01

    A better understanding of radiative effects of water vapor and clouds could be achieved through better spectrally-resolved measurements of the atmospheric thermal emission, particularly in the far infrared (FIR) region below 650 cm-1. To explore this relatively unknown region, an experiment, named Radiative Properties of Water Vapor and Clouds in Antarctica (PRANA, "Proprieta' Radiative del vapore Acqueo e delle Nubi in Antartide"), is under way at Concordia station in Antarctica since December 2011. This experiment exploits the high altitude and extremely dry air conditions found on the Antarctic Plateau to extend the ground-based infrared sounding capabilities to the water vapor pure rotational band. The experiment includes a spectroradiometer for the spectral characterization of the downwelling longwave radiance in the 100-1400 cm-1 spectral region and a LIDAR to characterize a possible cloud coverage. Measurements will be carried on for two years, thus covering systematically different sky conditions. Moreover, routine integrated measurements of downwelling and upwelling shortwave and longwave radiation components (performed within the Baseline Surface Radiation Network - BSRN) and daily radiosoundings of water vapor and temperature vertical profiles are performed from the base, providing an independent knowledge of the state of the observed atmosphere. Detailed specifications of the complete set of instruments are shown along with a preliminary analysis of spectroscopic data. The analysis shows that a spectrally-resolved measurement has the capability to identify and to quantify the effect of the different atmospheric components on the radiation budget, and at the same time it shows that it is necessary to improve the spectroscopic characterization of the water vapor rotational band to be used in radiative transfer models in order to perform this task at best. The spectral signature of thin ice clouds is also identified in the measurements and characterized in

  4. Mid-infrared laser filaments in the atmosphere.

    PubMed

    Mitrofanov, A V; Voronin, A A; Sidorov-Biryukov, D A; Pugžlys, A; Stepanov, E A; Andriukaitis, G; Flöry, T; Ališauskas, S; Fedotov, A B; Baltuška, A; Zheltikov, A M

    2015-02-17

    Filamentation of ultrashort laser pulses in the atmosphere offers unique opportunities for long-range transmission of high-power laser radiation and standoff detection. With the critical power of self-focusing scaling as the laser wavelength squared, the quest for longer-wavelength drivers, which would radically increase the peak power and, hence, the laser energy in a single filament, has been ongoing over two decades, during which time the available laser sources limited filamentation experiments in the atmosphere to the near-infrared and visible ranges. Here, we demonstrate filamentation of ultrashort mid-infrared pulses in the atmosphere for the first time. We show that, with the spectrum of a femtosecond laser driver centered at 3.9 μm, right at the edge of the atmospheric transmission window, radiation energies above 20 mJ and peak powers in excess of 200 GW can be transmitted through the atmosphere in a single filament. Our studies reveal unique properties of mid-infrared filaments, where the generation of powerful mid-infrared supercontinuum is accompanied by unusual scenarios of optical harmonic generation, giving rise to remarkably broad radiation spectra, stretching from the visible to the mid-infrared.

  5. Mid-infrared laser filaments in the atmosphere

    PubMed Central

    Mitrofanov, A. V.; Voronin, A. A.; Sidorov-Biryukov, D. A.; Pugžlys, A.; Stepanov, E. A.; Andriukaitis, G.; Flöry, T.; Ališauskas, S.; Fedotov, A. B.; Baltuška, A.; Zheltikov, A. M.

    2015-01-01

    Filamentation of ultrashort laser pulses in the atmosphere offers unique opportunities for long-range transmission of high-power laser radiation and standoff detection. With the critical power of self-focusing scaling as the laser wavelength squared, the quest for longer-wavelength drivers, which would radically increase the peak power and, hence, the laser energy in a single filament, has been ongoing over two decades, during which time the available laser sources limited filamentation experiments in the atmosphere to the near-infrared and visible ranges. Here, we demonstrate filamentation of ultrashort mid-infrared pulses in the atmosphere for the first time. We show that, with the spectrum of a femtosecond laser driver centered at 3.9 μm, right at the edge of the atmospheric transmission window, radiation energies above 20 mJ and peak powers in excess of 200 GW can be transmitted through the atmosphere in a single filament. Our studies reveal unique properties of mid-infrared filaments, where the generation of powerful mid-infrared supercontinuum is accompanied by unusual scenarios of optical harmonic generation, giving rise to remarkably broad radiation spectra, stretching from the visible to the mid-infrared. PMID:25687621

  6. Infrared Signature Masking by Air Plasma Radiation

    NASA Technical Reports Server (NTRS)

    Kruger, C. H.; Laux, C. O.

    1998-01-01

    Detailed measurements and modeling of the spectral emission of an atmospheric pressure air plasma at temperatures up to -3400 K have been made. The cold gas injected in the plasma torch contained an estimated mole fraction of water vapor of approximately 4.5 x 10(exp -3) and an estimated carbon dioxide mole fraction of approximately 3.3 x 10(exp -4). Under these conditions, the minimum level of air plasma emission is found to be between 3.9 and 4.15 microns. Outside this narrow region, significant spectral emission is detected that can be attributed to the fundamental and overtone bands of NO and OH, and to the v(sub 3) and the (v(sub 1)+v(sub 3)) bands Of CO2. Special attention was paid to the effects of ambient air absorption in the optical path between the plasma and the detector. Excellent quantitative agreement is obtained between the measured and simulated spectra, which are both on absolute intensity scales, thus lending confidence in the radiation models incorporated into NEQAIR2-IR over the course of this research program.

  7. Validation of the Radiometric Stability of the Atmospheric Infrared Sounder

    NASA Technical Reports Server (NTRS)

    Aumann, H. H.; Elliott, D.; Strow, L. L.

    2012-01-01

    It has been widely accepted that an infrared sounder in low polar orbit is capable of producing climate quality data, if the spectral brightness temperatures have instrumental trends of less than 10 mK/yr. Achieving measurement stability at this level is not only very demanding of the design of the instrument, it is also pushes the state of art of measuring on orbit what stability is actually achieved. We discuss this using Atmospheric Infrared Sounder (AIRS) L1B data collected between 2002 and 2011. We compare the L1B brightness temperature observed in cloud filtered night tropical ocean spectra (obs) to the brightness temperature calculated based on the known surface emissivity, temperature and water vapor profiles from the ECMWF ReAnalysis (ERA) and the growth rates of CO2, N2O and Ozone. The trend in (obs-calc) is a powerful tool for the evaluation of the stability of the 2378 AIRS channels. We divided the channels into seven classes: All channels which sound in the stratosphere (at pressure levels below 150 hPa), 14 micron CO2 sounding, 4 micron CO2 P-branch sounding, 4 micron CO2 R-branch sounding, water vapor sounding, shortwave surface sounding and longwave surface sounding. The peak in the weighting function at 1050 hPa separates sounding and surface channels. The boundary between shortwave and longwave is 5 microns. Except for the stratosphere sounding channels, the remaining six groups have (obs-calc) trends of less than 20 mK/yr. The longwave surface channels have trends of 2 mK/yr, significantly less than the 8 mK/yr trend seem in the shortwave window channels. Based on the design of the instrument, trends within a group of channels should be the same. While the longwave and shortwave trends are less than the canonical 10 mK/yr, the larger trend in the shortwave channels could be an artifact of using the pre-launch determined calibration coefficients. This is currently under evaluation. The trend in (obs-calc) for the non-surface sounding channels, in

  8. Biases in Total Precipitable Water Vapor Climatologies from Atmospheric Infrared Sounder and Advanced Microwave Scanning Radiometer

    NASA Technical Reports Server (NTRS)

    Fetzer, Eric J.; Lambrigtsen, Bjorn H.; Eldering, Annmarie; Aumann, Hartmut H.; Chahine, Moustafa T.

    2006-01-01

    We examine differences in total precipitable water vapor (PWV) from the Atmospheric Infrared Sounder (AIRS) and the Advanced Microwave Scanning Radiometer (AMSR-E) experiments sharing the Aqua spacecraft platform. Both systems provide estimates of PWV over water surfaces. We compare AIRS and AMSR-E PWV to constrain AIRS retrieval uncertainties as functions of AIRS retrieved infrared cloud fraction. PWV differences between the two instruments vary only weakly with infrared cloud fraction up to about 70%. Maps of AIRS-AMSR-E PWV differences vary with location and season. Observational biases, when both instruments observe identical scenes, are generally less than 5%. Exceptions are in cold air outbreaks where AIRS is biased moist by 10-20% or 10-60% (depending on retrieval processing) and at high latitudes in winter where AIRS is dry by 5-10%. Sampling biases, from different sampling characteristics of AIRS and AMSR-E, vary in sign and magnitude. AIRS sampling is dry by up to 30% in most high-latitude regions but moist by 5-15% in subtropical stratus cloud belts. Over the northwest Pacific, AIRS samples conditions more moist than AMSR-E by a much as 60%. We hypothesize that both wet and dry sampling biases are due to the effects of clouds on the AIRS retrieval methodology. The sign and magnitude of these biases depend upon the types of cloud present and on the relationship between clouds and PWV. These results for PWV imply that climatologies of height-resolved water vapor from AIRS must take into consideration local meteorological processes affecting AIRS sampling.

  9. Calibrated infrared ground/air radiometric spectrometer

    NASA Astrophysics Data System (ADS)

    Silk, J. K.; Schildkraut, Elliot Robert; Bauldree, Russell S.; Goodrich, Shawn M.

    1996-06-01

    The calibrated infrared ground/air radiometric spectrometer (CIGARS) is a new high performance, multi-purpose, multi- platform Fourier transform spectrometer (FPS) sensor. It covers the waveband from 0.2 to 12 micrometer, has spectral resolution as fine as 0.3 cm-1, and records over 100 spectra per second. Two CIGARS units are being used for observations of target signatures in the air or on the ground from fixed or moving platforms, including high performance jet aircraft. In this paper we describe the characteristics and capabilities of the CIGARS sensor, which uses four interchangeable detector modules (Si, InGaAs, InSb, and HgCdTe) and two optics modules, with internal calibration. The data recording electronics support observations of transient events, even without precise information on the timing of the event. We present test and calibration data on the sensitivity, spectral resolution, stability, and spectral rate of CIGARS, and examples of in- flight observations of real targets. We also discuss plans for adapting CIGARS for imaging spectroscopy observations, with simultaneous spectral and spatial data, by replacing the existing detectors with a focal plane array (FPA).

  10. Effect of tropospheric aerosols upon atmospheric infrared cooling rates

    NASA Technical Reports Server (NTRS)

    Harshvardhan, MR.; Cess, R. D.

    1978-01-01

    The effect of tropospheric aerosols on atmospheric infrared cooling rates is investigated by the use of recent models of infrared gaseous absorption. A radiative model of the atmosphere that incorporates dust as an absorber and scatterer of infrared radiation is constructed by employing the exponential kernel approximation to the radiative transfer equation. Scattering effects are represented in terms of a single scattering albedo and an asymmetry factor. The model is applied to estimate the effect of an aerosol layer made of spherical quartz particles on the infrared cooling rate. Calculations performed for a reference wavelength of 0.55 microns show an increased greenhouse effect, where the net upward flux at the surface is reduced by 10% owing to the strongly enhanced downward emission. There is a substantial increase in the cooling rate near the surface, but the mean cooling rate throughout the lower troposphere was only 10%.

  11. Simulations of infrared atmospheric transmittance based on measured data

    NASA Astrophysics Data System (ADS)

    Song, Fu-yin; Lu, Yuan; Qiao, Ya; Tao, Hui-feng; Tang, Cong; Ling, Yong-shun

    2016-10-01

    There are two regular methods to calculate infrared atmospheric transmittance, including empirical formula and professional software. However, it has large deviations to use empirical formula. It is complicated to use professional software and difficult to apply in other infrared simulative system. Therefore, based on measured atmospheric data in some area for many years, article used the method of molecular single absorption to calculate absorption coefficients of water vapor and carbon dioxide in different temperature. Temperatures, pressures, and consequent scattering coefficients which distributed in different high were fitted with analysis formula according to different months. Then, it built simulative calculation model of atmospheric transmittance of infrared radiation. The simulative results are very close to accuracy results calculated by user-defined model of MODTRAN. The method is easy and convenient to use and has certain referent value in the project application.

  12. Global mapping of minor atmospheric constituents with AIRS on EOS

    NASA Technical Reports Server (NTRS)

    Aumann, H. H.; Haskins, R. D.

    1990-01-01

    The Atmospheric Infrared Sounder (AIRS) is a grating-array spectrometer on EOS. It covers the region from 650 to 3000/cm with spectral resolution of 1200. The prime objective of AIRS is the global retrieval of temperature and water vapor profiles and of surface temperatures. The wide spectral coverage of AIRS permits the measurement of a number of additional atmospheric and surface parameters. Of particular interest is the potential to produce daily global maps of the spatial distribution of the more abundant of the minor gases, e.g. ozone, CO, CH4, and N2O. This potential capability for CH4 and N2O is strongly affected by cloud residual. Using the CH4 band at 1306/cm as example, spatial averaging of AIRS data is required to measure a 10 percent change in the nominal CH4 column abundance. At 1300/cm, this requires cloud clearing at the 0.3 percent level. The mapping capability for ozone and CO in terms of rural/urban abundance patterns is not likely to be impacted with cloud-clearing residuals as high as 5 percent.

  13. Development of Atmospheric Infrared Emission Models

    DTIC Science & Technology

    2007-11-02

    spectral radiance may be calculated for an arbitrary line -of-sight (LOS) passing through up to seven profiles . Interpolation is used to... Spectral Line with the Voigt Profile ," J. Quant. Spectrosc. Radiat. Transfer, 14, 319 (1974). 34. "U. S. Standard Atmosphere 1976," National Oceanic... Spectral Radiance Model 7 2.4.1 Calculation for a Single Line 7 2.4.2 Illustrative Calculations 9 2.5 Data Comparisons 11 3. DEVELOPMENT OF

  14. Infrared Spectroscopy of Halogenated Species for Atmospheric Remote Sensing

    NASA Astrophysics Data System (ADS)

    Harrison, Jeremy J.

    2014-06-01

    Fluorine- and chlorine-containing molecules in the atmosphere are very strong greenhouse gases, meaning that even small amounts of these gases contribute significantly to the radiative forcing of climate. Chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs) are regulated by the 1987 Montreal Protocol because they deplete the ozone layer. Hydrofluorocarbons (HFCs), which do not deplete the ozone layer and are not regulated by the Montreal Protocol, have been introduced as replacements for CFCs and HCFCs. HFCs have global-warming potentials many times greater than carbon dioxide, and are increasing in the atmosphere at a very fast rate. Various satellite instruments monitor many of these molecules by detecting infrared radiation that has passed through the Earth's atmosphere. However, the quantification of their atmospheric abundances crucially requires accurate quantitative infrared spectroscopy. This talk will focus on new and improved laboratory spectroscopic measurements for a number of important halogenated species.

  15. Daily global maps of carbon monoxide from NASA's Atmospheric Infrared Sounder

    NASA Astrophysics Data System (ADS)

    McMillan, W. W.; Barnet, C.; Strow, L.; Chahine, M. T.; McCourt, M. L.; Warner, J. X.; Novelli, P. C.; Korontzi, S.; Maddy, E. S.; Datta, S.

    2005-06-01

    We present the first observations of tropospheric carbon monoxide (CO) by the Atmospheric Infrared Sounder (AIRS) onboard NASA's Aqua satellite. AIRS daily coverage of ~70% of the planet represents a significant evolutionary advance in satellite trace gas remote sensing. Tropospheric CO abundances are retrieved from AIRS 4.55 μm spectral region using the full AIRS retrieval algorithm run in a research mode. The presented AIRS daily global CO maps from 22-29 September 2002 show large-scale, long-range transport of CO from anthropogenic and natural sources, most notably from biomass burning. The sequence of daily maps reveal CO advection from Brazil to the South Atlantic in qualitative agreement with previous observations. Forward trajectory analysis confirms this scenario and indicates much longer range transport into the southern Indian Ocean. Preliminary comparisons to in situ aircraft profiles indicate AIRS CO retrievals are approaching the 15% accuracy target set by pre-launch simulations.

  16. Seven Years of Observations of Mid-Tropospheric CO2 from the Atmospheric Infrared Sounder

    NASA Technical Reports Server (NTRS)

    Pagano, Thomas S.; Chahine, Moustafa T.; Olsen, Edward T.

    2010-01-01

    The Atmospheric Infrared Sounder (AIRS) on the EOS Aqua Spacecraft was launched on May 4, 2002. AIRS acquires hyperspectral infrared radiances in the 3.7-15.4 um spectral region with spectral resolution of better than 1200. The AIRS was designed to measure temperature and water vapor profiles and cloud properties for improvement in weather forecast and improved parameterization of climate processes. Currently the AIRS Level 1B Radiance Products are assimilated by NWP centers and have shown considerable forecast improvement. Scientists have also demonstrated accurate retrievals of minor gases from AIRS including Carbon Monoxide, Methane, and Ozone. The excellent sensitivity and stability of the AIRS instrument has recently allowed the AIRS team to successfully retrieve Carbon Dioxide (CO2) concentrations in the mid-troposphere (8-10 km) with a horizontal resolution of 100 km and accuracy of 1-2 ppm. The AIRS retrieves over 15,000 measurements per day and can achieve full global coverage in 30 days. The AIRS CO2 accuracy has been validated against a variety of aircraft measurements in the mid-troposphere and upward looking interferometers. Findings from the AIRS data include higher than expected variability in the mid-troposphere, the presence of a belt of CO2 in the southern hemisphere, and numerous observations of atmospheric circulation including the effects of El Nino/La Nina on the CO2 concentrations in the mid-troposphere. The full mid-tropospheric AIRS CO2 data set is now available at the NASA GES/DISC for almost eight years since AIRS has been operational.

  17. Seven years of observations of mid-tropospheric CO 2 from the Atmospheric Infrared Sounder

    NASA Astrophysics Data System (ADS)

    Pagano, Thomas S.; Chahine, Moustafa T.; Olsen, Edward T.

    2011-09-01

    The Atmospheric Infrared Sounder (AIRS) on the EOS Aqua Spacecraft was launched on May 4, 2002. AIRS acquires hyperspectral infrared radiances in the 3.7-15.4 μm spectral region with spectral resolving power of better than 1200. The AIRS was designed to measure temperature and water vapor profiles and cloud properties for improvement in weather forecast and improved parameterization of climate processes. Currently a subset of AIRS Level 1B Radiance Products is assimilated by NWP centers, resulting in significant forecast improvement. Scientists have also demonstrated accurate retrievals of minor gases from AIRS including carbon monoxide, methane, and ozone. The excellent sensitivity and stability of the AIRS instrument has recently allowed the AIRS team to successfully retrieve carbon dioxide (CO 2) concentrations in the mid-troposphere (8-10 km) with a horizontal resolution of 100 km and accuracy better than 2 ppm. The AIRS mid-tropospheric CO 2 yield is 15,000 measurements per 24-h period over land and ocean, day and night for clear and cloudy scenes. The AIRS CO 2 accuracy has been validated against a variety of mid-tropospheric aircraft measurements as well as upward looking interferometers. Findings from the AIRS data include higher than expected variability in the mid-troposphere, the presence of a seasonally variable belt of enhanced CO 2 in the southern hemisphere, and observations of impact of atmospheric dynamics on the CO 2 concentrations in the mid-troposphere including the effects of El Nino/La Nina and the Arctic polar vortex. The full mid-tropospheric AIRS CO 2 data set is now available at the NASA GES/DISC for the 8 year time span since AIRS became operational.

  18. Infrared lidars for atmospheric remote sensing

    NASA Technical Reports Server (NTRS)

    Menzies, Robert T.

    1991-01-01

    Lidars using pulsed TEA-CO2 transmitters and coherent receivers have been developed at JPL and used to measure atmospheric backscatter and extinction at wavelengths in the 9-11 micron region. The global winds measurement application of coherent Doppler lidar requires intensive study of the global climatology of aerosol and cloud backscatter and extinction. An airborne lidar was recently flown on the NASA DC-8 research aircraft for operation during two Pacific circumnavigation missions. The instrument characteristics, as well as representative measurement results, are discussed.

  19. Infrared laboratory studies of synthetic planetary atmospheres

    NASA Technical Reports Server (NTRS)

    Williams, D.

    1972-01-01

    The initial stages of the research were involved with a test of Burch's law of multiplicative transmittance for mixed absorbing gases when their lines are broadened by H2 and He, which are constituents of the atmospheres of the major planets. The broadening of individual lines in the CO fundamental by various gases was investigated. Line strength and half-width for individual CO lines were studied as a function of temperature. Measurements of total band absorptance as a function of absorber thickness and total effective pressure were made at various temperatures for bands of CO and N2O. Attempts were made to develop a phenomenological theory of line broadening that would account for the phenomena observed for the CO fundamental and those reported for more highly polar gases. Laboratory measurements of nitric acid vapor absorptance were compared with balloon measurements in arriving at an estimate of the quantity of nitric acid vapor present in the earth's atmosphere in the region of the ozone layer.

  20. An empirical model for estimating the atmospheric transmittance of upward infrared radiation at different altitudes

    NASA Astrophysics Data System (ADS)

    Dai, Qiumin; Fang, Xiande; Zhao, Yingjie; Xing, Daoming

    2016-12-01

    The upward infrared (IR) radiation is one of the most important factors that affect the thermal characteristics of light-than-air (LTA) vehicles. Therefore, it is necessary to propose an accurate model to evaluate the upward atmospheric transmittance. The upward IR atmospheric transmittances of 6 different atmospheric models at the altitude from sea level to 30 km are obtained from the MODTRAN atmospheric radiative transfer code. Based on the data, a new upward IR atmospheric transmittance correlation related to pressure and vertical water column is proposed by regression analysis. It has excellent prediction accuracy with the coefficient of determination of 0.928, the root mean square error of 0.028, and the mean absolute percentage error of 2.68% for the database. Based on the new correlation, the thermal characteristics of a stratospheric airship located in tropics in midsummer are numerical studied and discussed.

  1. Spectrally resolved infrared radiances from AIRS observation and GCM simulation

    NASA Astrophysics Data System (ADS)

    Huang, Y.; Ramaswamy, V.

    2007-12-01

    Global multi-year spectrally resolved infrared radiances observed by the Atmospheric Infrared Sound (AIRS) satellite instrument and simulated from the General Circulation Models (GCMs) of the Geophysical Fluid Dynamics Lab (GFDL) are processed to obtain long-term global and regional means as well as the associated spatial and temporal variability. The accumulated radiance data comprise a host of phenomena that are still largely unrecognized but reveal important physical processes. For instance, the correlation between the radiances and the Sea Surface Temperatures (SSTs) discloses the roles of water vapor in both upper (via its v2 band) and lower (via the continuum in the window region) troposphere, and that of clouds regarding the so called "super greenhouse effect" in Tropics. A comparison between observed and simulated radiances demonstrates that radiance affords a stricter and more insightful metric than the broadband flux. A seemingly good agreement of OLR flux may arise from cancellation of errors of opposite signs in different spectral regions; radiance biases are indicative of physical causes because the radiances at each frequency are sensitive to factor(s) at different levels. Model validation at the radiance level thus provides a complementary and integrative perspective to that obtained using meteorological variables. It is demonstrated that the radiance discrepancies between the GFDL model and the observation are consistent with the model biases in temperature, water vapor and clouds.

  2. Filamentation in Air with Ultrashort Mid-Infrared Pulses

    DTIC Science & Technology

    2011-05-09

    Filamentation in air with ultrashort mid-infrared pulses Bonggu Shim,1,2 Samuel E. Schrauth,1 and Alexander L. Gaeta1,3 1School of Applied and...filamentation of ultrashort laser pulses in air in the mid-infrared regime under conditions in which the group-velocity dispersion (GVD) is anomalous. When a...and propagates several times its diffraction length. Compared with temporal self-compression in gases due to plasma formation and pulse splitting in the

  3. Infrared Photography as an Air Pollution Surveillance Instrument

    ERIC Educational Resources Information Center

    Casalinuovo, Anthony F.; Sawan, Alan

    1976-01-01

    The purpose of this study was to determine the practicality of infrared photographic analysis to air pollution agencies, by the detection of plant damage from pollutants before they are visually identifiable. Results showed that photomicrographic imaging using infrared radiation should be considered a viable surveillance tool in similiar…

  4. Titan's Atmospheric Composition from Observations by the Cassini Infrared Spectrometer

    NASA Technical Reports Server (NTRS)

    Abbas, M. M.; LeClair, A.; Flasar, F. M.; Kunde, V. G.; Conrath, B. J.; Coustenis, A.; Jennings, D. J.; Nixon, C. A.; Brasunas, J.; Achterberg, R. K.

    2006-01-01

    The Composite Infrared Spectrometer (CIRS) aboard the Cassini spacecraft has been making observations during the fly-bys of Titan since the Saturn-Orbit-Insertion in July 2004. The observations provide infrared them1 emission spectra of Titan s atmosphere in three spectral channels covering the 10/cm to 1400/cm spectral region, with variable spectral resolutions of 0.53/cm and 2.8/cm. The uniquely observed spectra exhibit rotational and vibrational-rotational spectral lines of the molecular constituents of Titan s atmosphere that may be analyzed to retrieve information about the composition, thermal structure, and physical and dynamical processes in the remotely sensed atmosphere. We present an analysis of Titan's infrared spectra observed during July 2004 (TO), December 2004 (Tb) and February 2005 (T3), for retrieval of the stratospheric thermal structure, distribution of the hydrocarbons, nitriles, and oxygen bearing constituents, such as C2H2, C2H4, C2H6, C3H8, HCN, HC3N, CO, and CO2 . Preliminary results on the distribution and opacity of haze in Titan s atmosphere are discussed.

  5. Infrared Opacities in Dense Atmospheres of Cool White Dwarf Stars

    NASA Astrophysics Data System (ADS)

    Kowalski, P. M.; Blouin, S.; Dufour, P.

    2017-03-01

    Dense, He-rich atmospheres of cool white dwarfs represent a challenge to the modeling. This is because these atmospheres are constituted of a dense fluid in which strong multi-atomic interactions determine their physics and chemistry. Therefore, the ideal-gas-based description of absorption is no longer adequate, which makes the opacities of these atmospheres difficult to model. This is illustrated with severe problems in fitting the spectra of cool, He-rich stars. Good description of the infrared (IR) opacity is essential for proper assignment of the atmospheric parameters of these stars. Using methods of computational quantum chemistry we simulate the IR absorption of dense He/H media. We found a significant IR absorption from He atoms (He-He-He CIA opacity) and a strong pressure distortion of the H2-He collision-induced absorption (CIA). We discuss the implication of these results for the interpretation of the spectra of cool stars.

  6. The Transition of Atmospheric Infrared Sounder Total Ozone Products to Operations

    NASA Technical Reports Server (NTRS)

    Berndt, E. B.; Zavodsky, B. T.; Jedlovec, G. J.

    2014-01-01

    The National Aeronautics and Space Administration Short-term Prediction Research and Transition Center (NASA SPoRT) has transitioned a total column ozone product from the Atmospheric Infrared Sounder (AIRS) retrievals to the Weather Prediction Center and Ocean Prediction Center. The total column ozone product is used to diagnose regions of warm, dry, ozone-rich, stratospheric air capable of descending to the surface to create high-impact non-convective winds. Over the past year, forecasters have analyzed the Red, Green, Blue (RGB) Air Mass imagery in conjunction with the AIRS total column ozone to aid high wind forecasts. One of the limitations of the total ozone product is that it is difficult for forecasters to determine whether elevated ozone concentrations are related to stratospheric air or climatologically high values of ozone in certain regions. During the summer of 2013, SPoRT created an AIRS ozone anomaly product which calculates the percent of normal ozone based on a global stratospheric ozone mean climatology. With the knowledge that ozone values 125 percent of normal and greater typically represent stratospheric air; the anomaly product can be used with the total column ozone product to confirm regions of stratospheric air. This paper describes the generation of these products along with forecaster feedback concerning the use of the AIRS ozone products in conjunction with the RGB Air Mass product to access the utility and transition of the products.

  7. Infrared Observations of SO emission from Io's Atmosphere during Eclipse

    NASA Astrophysics Data System (ADS)

    de Kleer, K.; De Pater, I.; Adamkovics, M.

    2013-12-01

    Io, the volcanic moon of Jupiter, hosts an atmosphere dominated by SO2 and SO, but the question of the direct source of these molecules is still debated. Many different approaches have been taken to establish a link between volcanic activity on Io and atmospheric effects, to distinguish whether the atmosphere is supplied by volcanic outgassing or ice sublimation. In the infrared, atmospheric emission lines are lost in reflected sunlight; observing Io in eclipse provides a unique opportunity to study infrared lines, during a time when most of Io's atmosphere may be frozen out in Jupiter's shadow. In 1999 the a1Δ → Χ3Σ- transition of SO at 1.707 μm was discovered by de Pater et al. (2002); Laver et al. (2007) made additional observations, which they fit with equilibrium models to infer a likely volcanic origin for the SO. Here we present additional high spectral resolution observations of the 1.707 μm SO line while Io is in eclipse. We model these observations with equilibrium and non-LTE models, and address implications for the origin of SO on Io.

  8. On-line infrared process signature measurements through combustion atmospheres

    NASA Astrophysics Data System (ADS)

    Zweibaum, F. M.; Kozlowski, A. T.; Surette, W. E., Jr.

    1980-01-01

    A number of on-line infrared process signature measurements have been made through combustion atmospheres, including those in jet engines, piston engines, and coal gasification reactors. The difficulties involved include operation in the presence of pressure as high as 1800 psi, temperatures as high as 3200 F, and explosive, corrosive and dust-laden atmospheres. Calibration problems have resulted from the use of purge gases to clear the viewing tubes, and the obscuration of the view ports by combustion products. A review of the solutions employed to counteract the problems is presented, and areas in which better solutions are required are suggested.

  9. A Comparison of the Red Green Blue Air Mass Imagery and Hyperspectral Infrared Retrieved Profiles

    NASA Technical Reports Server (NTRS)

    Berndt, E. B.; Folmer, Michael; Dunion, Jason

    2014-01-01

    The Red Green Blue (RGB) Air Mass imagery is derived from multiple channels or paired channel differences. Multiple channel products typically provide additional information than a single channel can provide alone. The RGB Air Mass imagery simplifies the interpretation of temperature and moisture characteristics of air masses surrounding synoptic and mesoscale features. Despite the ease of interpretation of multiple channel products, the combination of channels and channel differences means the resulting product does not represent a quantity or physical parameter such as brightness temperature in conventional single channel satellite imagery. Without a specific quantity to reference, forecasters are often confused as to what RGB products represent. Hyperspectral infrared retrieved profiles of temperature, moisture, and ozone can provide insight about the air mass represented on the RGB Air Mass product and provide confidence in the product and representation of air masses despite the lack of a quantity to reference for interpretation. This study focuses on RGB Air Mass analysis of Hurricane Sandy as it moved north along the U.S. East Coast, while transitioning to a hybrid extratropical storm. Soundings and total column ozone retrievals were analyzed using data from the Cross-track Infrared and Advanced Technology Microwave Sounder Suite (CrIMSS) on the Suomi National Polar Orbiting Partnership satellite and the Atmospheric Infrared Sounder (AIRS) on the National Aeronautics and Space Administration Aqua satellite along with dropsondes that were collected from National Oceanic and Atmospheric Administration and Air Force research aircraft. By comparing these datasets to the RGB Air Mass, it is possible to capture quantitative information that could help in analyzing the synoptic environment enough to diagnose the onset of extratropical transition. This was done by identifying any stratospheric air intrusions (SAIs) that existed in the vicinity of Sandy as the wind

  10. CANOES II; Dynamics of Atmospheric Infrared Thermochemical Excitation. Volume 2

    DTIC Science & Technology

    1989-03-01

    4 8 which carried at least 6.5 eV internal energy, in their studies on the excitation of mercuric halides by N2 (A). The energy of the companion...as auroral precursors of infrared radiation ., 20. DISTRIBUTION /AVAILABILITY OF ABSTRACT 21 ABSTRACT SECURITY CLASSIFICATION MUNCLASSIFIED/tINLIMITED...investigate chemiluminescent reactions of atmospherically important radiators which could significantly contribute to emissions in several important

  11. Atmospheric Sounder Spectrometer for Infrared Spectral Technology (ASSIST) Instrument Handbook

    SciTech Connect

    Flynn, Connor J.

    2016-03-01

    The Atmospheric Sounder Spectrometer for Infrared Spectral Technology (ASSIST) measures the absolute infrared (IR) spectral radiance (watts per square meter per steradian per wavenumber) of the sky directly above the instrument. More information about the instrument can be found through the manufacturer’s website. The spectral measurement range of the instrument is 3300 to 520 wavenumbers (cm-1) or 3-19.2 microns for the normal-range instruments and 3300 to 400 cm-1 or 3-25 microns, for the extended-range polar instruments. Spectral resolution is 1.0 cm-1. Instrument field-of-view is 1.3 degrees. Calibrated sky radiance spectra are produced on cycle of about 141 seconds with a group of 6 radiance spectra zenith having dwell times of about 14 seconds each interspersed with 55 seconds of calibration and mirror motion. The ASSIST data is comparable to the Atmospheric Emitted Radiance Interferometer (AERI) data and can be used for 1) evaluating line-by-line radiative transport codes, 2) detecting/quantifying cloud effects on ground-based measurements of infrared spectral radiance (and hence is valuable for cloud property retrievals), and 3) calculating vertical atmospheric profiles of temperature and water vapor and the detection of trace gases.

  12. Hurricane Isabel, Amount of Atmospheric Water Vapor Observed By AIRS

    NASA Technical Reports Server (NTRS)

    2003-01-01

    Atmospheric Infrared Sounder Experiment, with its visible, infrared, and microwave detectors, provides a three-dimensional look at Earth's weather. Working in tandem, the three instruments can make simultaneous observations all the way down to the Earth's surface, even in the presence of heavy clouds. With more than 2,000 channels sensing different regions of the atmosphere, the system creates a global, 3-D map of atmospheric temperature and humidity and provides information on clouds, greenhouse gases, and many other atmospheric phenomena. The AIRS Infrared Sounder Experiment flies onboard NASA's Aqua spacecraft and is managed by NASA's Jet Propulsion Laboratory, Pasadena, Calif., under contract to NASA. JPL is a division of the California Institute of Technology in Pasadena.

  13. Retrieval with Infrared Atmospheric Sounding Interferometer and Validation during JAIVEx

    NASA Technical Reports Server (NTRS)

    Zhou, Daniel K.; Liu, Xu; Larar, Allen M.; Smith, William L.; Taylor, Jonathan P.; Schluessel, Peter; Strow, L. Larrabee; Mango, Stephen A.

    2008-01-01

    A state-of-the-art IR-only retrieval algorithm has been developed with an all-season-global EOF Physical Regression and followed by 1-D Var. Physical Iterative Retrieval for IASI, AIRS, and NAST-I. The benefits of this retrieval are to produce atmospheric structure with a single FOV horizontal resolution (approx. 15 km for IASI and AIRS), accurate profiles above the cloud (at least) or down to the surface, surface parameters, and/or cloud microphysical parameters. Initial case study and validation indicates that surface, cloud, and atmospheric structure (include TBL) are well captured by IASI and AIRS measurements. Coincident dropsondes during the IASI and AIRS overpasses are used to validate atmospheric conditions, and accurate retrievals are obtained with an expected vertical resolution. JAIVEx has provided the data needed to validate the retrieval algorithm and its products which allows us to assess the instrument ability and/or performance. Retrievals with global coverage are under investigation for detailed retrieval assessment. It is greatly desired that these products be used for testing the impact on Atmospheric Data Assimilation and/or Numerical Weather Prediction.

  14. DESCRIPTION OF ATMOSPHERIC TRANSPORT PROCESSES IN EULERIAN AIR QUALITY MODELS

    EPA Science Inventory

    Key differences among many types of air quality models are the way atmospheric advection and turbulent diffusion processes are treated. Gaussian models use analytical solutions of the advection-diffusion equations. Lagrangian models use a hypothetical air parcel concept effecti...

  15. Monthly Representations of Mid-Tropospheric Carbon Dioxide from the Atmospheric Infrared Sounder

    NASA Technical Reports Server (NTRS)

    Pagano, Thomas S.; Olsen, Edward T.; Chahine, Moustafa T.; Ruzmaikin, Alexander; Nguyen, Hai; Jiang, Xun

    2011-01-01

    The Atmospheric Infrared Sounder (AIRS) on NASA's Earth Observing System Aqua spacecraft was launched in May of 2002 and acquires hyperspectral infrared spectra used to generate a wide range of atmospheric products including temperature, water vapor, and trace gas species including carbon dioxide. Here we present monthly representations of global concentrations of mid-tropospheric carbon dioxide produced from 8 years of data obtained by AIRS between the years of 2003 and 2010. We define them as "representations" rather than "climatologies" to reflect that the files are produced over a relatively short time period and represent summaries of the Level 3 data. Finally, they have not yet been independently validated. The representations have a horizontal resolution of 2.0 deg x 2.5 deg (Latitude x Longitude) and faithfully reproduce the original 8 years of monthly L3 CO2 concentrations with a standard deviation of 1.48 ppm and less than 2% outliers. The representations are intended for use in studies of the global general circulation of CO2 and identification of anomalies in CO2 typically associated with atmospheric transport. The seasonal variability and trend found in the AIRS CO2 data are discussed.

  16. AIRES: An Airborne Infra-Red Echelle Spectrometer for SOFIA

    NASA Technical Reports Server (NTRS)

    Dotson, Jessie J.; Erickson, Edwin F.; Haas, Michael R.; Colgan, Sean W. J.; Simpson, Janet P.; Telesco, Charles M.; Pina, Robert K.; Wolf, Juergen; Young, Erick T.

    1999-01-01

    SOFIA will enable astronomical observations with unprecedented angular resolution at infrared wavelengths obscured from the ground. To help open this new chapter in the exploration of the infrared universe, we are building AIRES, an Airborne Infra-Red Echelle Spectrometer. AIRES will be operated as a first generation, general purpose facility instrument by USRA, NASA's prime contractor for SOFIA. AIRES is a long slit spectrograph operating from 17 - 210 microns. In high resolution mode the spectral resolving power is approx. 10(exp 6) microns/A or approx. 10(exp 4) at 100 microns. Unfortunately, since the conference, a low resolution mode with resolving power about 100 times lower has been deleted due to budgetary constraints. AIRES includes a slit viewing camera which operates in broad bands at 18 and 25 microns.

  17. Overview of Atmospheric Ionizing Radiation (AIR)

    NASA Technical Reports Server (NTRS)

    Wilson, J. W.; Maiden, D. L.; Goldhagen, P.; Tai, H.; Shinn, J. L.

    2003-01-01

    The SuperSonic Transport (SST) development program within the US was based at the Langley Research Center as was the Apollo radiation testing facility (Space Radiation Effects Laboratory) with associated radiation research groups. It was natural for the issues of the SST to be first recognized by this unique combination of research programs. With a re-examination of the technologies for commercial supersonic flight and the possible development of a High Speed Civil Transport (HSCT), the remaining issues of the SST required resolution. It was the progress of SST radiation exposure research program founded by T. Foelsche at the Langley Research Center and the identified remaining issues after that project over twenty-five years ago which became the launch point of the current atmospheric ionizing radiation (AIR) research project. Added emphasis to the need for reassessment of atmospheric radiation resulted from the major lowering of the recommended occupational exposure limits, the inclusion of aircrew as radiation workers, and the recognition of civil aircrew as a major source of occupational exposures. Furthermore, the work of Ferenc Hajnal of the Environmental Measurements Laboratory brought greater focus to the uncertainties in the neutron flux at high altitudes. A re-examination of the issues involved was committed at the Langley Research Center and by the National Council on Radiation Protection (NCRP). As a result of the NCRP review, a new flight package was assembled and flown during solar minimum at which time the galactic cosmic radiation is at a maximum (June 1997). The present workshop is the initial analysis of the new data from that flight. The present paper is an overview of the status of knowledge of atmospheric ionizing radiations. We will re-examine the exposures of the world population and examine the context of aircrew exposures with implications for the results of the present research. A condensed version of this report was given at the 1998

  18. Near-infrared Characterization of the Atmospheres of Alien Worlds

    NASA Astrophysics Data System (ADS)

    Croll, Bryce

    In this thesis I present near-infrared detections of the thermal emission of a number of hot Jupiters and likely transit depth differences from different wavelength observations of a super-Earth. I have pioneered "Staring Mode" using the Wide-field Infrared Camera on the Canada-France-Hawaii Telescope to achieve the most accurate photometry to-date in the near- infrared from the ground. I also discuss avenues that should allow one to achieve even more accurate photometry in the future. Using WIRCam on CFHT my collaborators and I have detected the thermal emission of the following hot Jupiters: TrES-2b and TrES-3b in Ks-band, WASP-12b in the J, H & Ks-bands, and WASP-3b in the Ks-band on two occasions. Near- infrared detections of the thermal emission of hot Jupiters are important, because the majority of these planets' blackbodies peak in this wavelength range; near-infrared detections allow us to obtain the most model-independent constraints on these planets' atmospheric characteristics, their temperature-pressure profiles with depth and an estimate of their bolometric luminosities. With these detections we are able to answer such questions as: how efficiently these planets redistribute heat to their nightsides, if they're being inflated by tidal heating, whether there's any evidence that one of these planets is precessing, and whether another experiences extreme weather and violent storms? My collaborators and I have also observed several transits of the super-Earth GJ 1214b. We find a deeper transit depth in one of our near-infrared bands than the other. This is likely indicative of a spectral absorption feature. For the differences in the transit depth to be as large as we observed, the atmosphere of GJ 1214b must have a large scale height, low mean molecular weight and thus have a hydrogen/helium dominated atmosphere. Given that other researchers have not found similar transit depth differences, we also discuss the most likely atmospheric makeup for this

  19. Memory efficient atmospheric effects modeling for infrared scene generators

    NASA Astrophysics Data System (ADS)

    Kavak, Çaǧlar; Özsaraç, Seçkin

    2015-05-01

    The infrared (IR) energy radiated from any source passes through the atmosphere before reaching the sensor. As a result, the total signature captured by the IR sensor is significantly modified by the atmospheric effects. The dominant physical quantities that constitute the mentioned atmospheric effects are the atmospheric transmittance and the atmospheric path radiance. The incoming IR radiation is attenuated by the transmittance and path radiance is added on top of the attenuated radiation. In IR scene simulations OpenGL is widely used for rendering purposes. In the literature there are studies, which model the atmospheric effects in an IR band using OpenGLs exponential fog model as suggested by Beers law. In the standard pipeline of OpenGL, the related fog model needs single equivalent OpenGL variables for the transmittance and path radiance, which actually depend on both the distance between the source and the sensor and also on the wavelength of interest. However, in the conditions where the range dependency cannot be modeled as an exponential function, it is not accurate to replace the atmospheric quantities with a single parameter. The introduction of OpenGL Shading Language (GLSL) has enabled the developers to use the GPU more flexible. In this paper, a novel method is proposed for the atmospheric effects modeling using the least squares estimation with polynomial fitting by programmable OpenGL shader programs built with GLSL. In this context, a radiative transfer model code is used to obtain the transmittance and path radiance data. Then, polynomial fits are computed for the range dependency of these variables. Hence, the atmospheric effects model data that will be uploaded in the GPU memory is significantly reduced. Moreover, the error because of fitting is negligible as long as narrow IR bands are used.

  20. Quantitative infrared absorption cross sections of isoprene for atmospheric measurements

    DOE PAGES

    Brauer, C. S.; Blake, T. A.; Guenther, A. B.; ...

    2014-11-19

    Isoprene (C5H8, 2-methyl-1,3-butadiene) is a volatile organic compound (VOC) and is one of the primary contributors to annual global VOC emissions. Isoprene is produced primarily by vegetation as well as anthropogenic sources, and its OH- and O3-initiated oxidations are a major source of atmospheric oxygenated organics. Few quantitative infrared studies have been reported for isoprene, limiting the ability to quantify isoprene emissions via remote or in situ infrared detection. We thus report absorption cross sections and integrated band intensities for isoprene in the 600–6500 cm-1 region. The pressure-broadened (1 atmosphere N2) spectra were recorded at 278, 298, and 323 Kmore » in a 19.94 cm path-length cell at 0.112 cm-1 resolution, using a Bruker IFS 66v/S Fourier transform infrared (FTIR) spectrometer. Composite spectra are derived from a minimum of seven isoprene sample pressures, each at one of three temperatures, and the number densities are normalized to 296 K and 1 atm.« less

  1. ARIEL - Atmospheric Remote-Sensing Infrared Exoplanet Large-survey

    NASA Astrophysics Data System (ADS)

    Tinetti, Giovanna; Drossart, Pierre; Eccleston, Paul; Hartogh, Paul; Leconte, Jérémy; Micela, Giusi; Ollivier, Marc; Pilbratt, Göran; Puig, Ludovic; Turrini, Diego; Vandenbussche, Bart; Wolkenberg, Paulina; ARIEL Consortium, ARIEL ESA Study Team

    2016-10-01

    The Atmospheric Remote-Sensing Infrared Exoplanet Large-survey (ARIEL) is one of the three candidate missions selected by the European Space Agency (ESA) for its next medium-class science mission due for launch in 2026. The goal of the ARIEL mission is to investigate the atmospheres of several hundreds planets orbiting distant stars in order to address the fundamental questions on how planetary systems form and evolve.During its four (with a potential extension to six) years mission ARIEL will observe 500+ exoplanets in the visible and the infrared with its meter-class telescope in L2. ARIEL targets will include Jupiter- and Neptune-size down to super-Earth and Earth-size around different types of stars. The main focus of the mission will be on hot and warm planets orbiting very close to their star, as they represent a natural laboratory in which to study the chemistry and formation of exoplanets. In cooler planets, different gases separate out through condensation and sinking into distinct cloud layers. The scorching heat experienced by hot exoplanets overrides these processes and keeps all molecular species circulating throughout the atmosphere.The ARIEL mission concept has been developed by a consortium of more than 50 institutes from 12 countries, which include UK, France, Italy, Germany, the Netherlands, Poland, Spain, Belgium, Austria, Denmark, Ireland and Portugal. The analysis of ARIEL spectra and photometric data will allow to extract the chemical fingerprints of gases and condensates in the planets' atmospheres, including the elemental composition for the most favorable targets. It will also enable the study of thermal and scattering properties of the atmosphere as the planet orbit around the star.ARIEL will have an open data policy, enabling rapid access by the general community to the high-quality exoplanet spectra that the core survey will deliver.

  2. Algorithmic vs. finite difference Jacobians for infrared atmospheric radiative transfer

    NASA Astrophysics Data System (ADS)

    Schreier, Franz; Gimeno García, Sebastián; Vasquez, Mayte; Xu, Jian

    2015-10-01

    Jacobians, i.e. partial derivatives of the radiance and transmission spectrum with respect to the atmospheric state parameters to be retrieved from remote sensing observations, are important for the iterative solution of the nonlinear inverse problem. Finite difference Jacobians are easy to implement, but computationally expensive and possibly of dubious quality; on the other hand, analytical Jacobians are accurate and efficient, but the implementation can be quite demanding. GARLIC, our "Generic Atmospheric Radiation Line-by-line Infrared Code", utilizes algorithmic differentiation (AD) techniques to implement derivatives w.r.t. atmospheric temperature and molecular concentrations. In this paper, we describe our approach for differentiation of the high resolution infrared and microwave spectra and provide an in-depth assessment of finite difference approximations using "exact" AD Jacobians as a reference. The results indicate that the "standard" two-point finite differences with 1 K and 1% perturbation for temperature and volume mixing ratio, respectively, can exhibit substantial errors, and central differences are significantly better. However, these deviations do not transfer into the truncated singular value decomposition solution of a least squares problem. Nevertheless, AD Jacobians are clearly recommended because of the superior speed and accuracy.

  3. Effect of tropospheric aerosols upon atmospheric infrared cooling rates

    NASA Technical Reports Server (NTRS)

    Harshvardhan, MR.; Cess, R. D.

    1978-01-01

    An investigation has been made of the impact of wind-blown dust particles upon local climate of arid regions. The case of Northwest India is specifically considered, where a dense layer of dust persists for several months during the summer. In order to examine the effect of this dust layer on the infrared radiative flux and cooling rates, a method is presented for calculating the IR flux within a dusty atmosphere which allows the use of gaseous band models and is applicable in the limit of small single scattering albedo and pronounced forward scattering. The participating components of the atmosphere are assumed to be water vapor and spherical quartz particles only. The atmospheric window is partially filled by including the water vapor continuum bands for which empirically obtained transmission functions have been used. It is shown that radically different conclusions may be drawn on dust effects if the continuum absorption is not considered. The radiative transfer model, when applied to a dusty atmosphere, indicates that there is a moderate enhancement in the atmospheric greenhouse and a 10% increase in the mean IR radiative cooling rate, relative to the dust free case, within the lower troposphere. These results have been compared with previous work by other authors in the context of the possibility of dust layers inhibiting local precipitation.

  4. Cloud identification in atmospheric trace molecule spectroscopy infrared occultation measurements.

    PubMed

    Kahn, Brian H; Eldering, Annmarie; Irion, Fredrick W; Mills, Franklin P; Sen, Bhaswar; Gunson, Michael R

    2002-05-20

    High-resolution infrared nongas absorption spectra derived from the Atmospheric Trace Molecule Spectroscopy (ATMOS) experiment are analyzed for evidence of the presence of cirrus clouds. Several nonspherical ice extinction models based on realistic size distributions and crystal habits along with a stratospheric sulfate aerosol model are fit to the spectra, and comparisons are made with different model combinations. Nonspherical ice models often fit observed transmission spectra better than a spherical Mie ice model, and some discrimination among nonspherical models is noted. The ATMOS lines of sight for eight occultations are superimposed on coincident geostationary satellite infrared imagery, and brightness temperatures along the lines of sight are compared with retrieved vertical temperature profiles. With these comparisons, studies of two cases of clear sky, three cases of opaque cirrus, and three cases of patchy cirrus are discussed.

  5. Vehicle/Atmosphere Interaction Glows: Far Ultraviolet, Visible, and Infrared

    NASA Technical Reports Server (NTRS)

    Swenson, G.

    1999-01-01

    Spacecraft glow information has been gathered from a number of spacecraft including Atmospheric and Dynamic satellites, and Space Shuttles (numerous flights) with dedicated pallet flow observations on STS-39 (DOD) and STS-62 (NASA). In addition, a larger number of laboratory experiments with low energy oxygen beam studies have made important contributions to glow understanding. The following report provides information on three engineering models developed for spacecraft glow including the far ultraviolet to ultraviolet (1400-4000 A), and infrared (0.9-40 microns) spectral regions. The models include effects resulting from atmospheric density/altitude, spacecraft temperature, spacecraft material, and ram angle. Glow brightness would be predicted as a function of distance from surfaces for all wavelengths.

  6. Tunable Infrared Laser Instruments for Airborne Atmospheric Studies

    NASA Technical Reports Server (NTRS)

    Fried, A.; Diskin, G.; Weibring, P.; Richter, D.; Walega, J. G.; Sachse, G.; Slate, T.; Rana, M.; Podolske, J.

    2008-01-01

    Tunable infrared laser-based instruments on airborne platforms have provided invaluable contributions to atmospheric studies over the past several decades. This paper presents an overview of some recent studies and developments using this approach that were presented at the 2007 Field Laser Applications in Industry and Research (FLAIR, http://www.inoa.it/flair/) conference in Florence, Italy. The present overview only covers select in situ absorption-based instruments that were presented in the airborne session at this conference. In no case are comprehensive details presented. These details can be found in the numerous references given. Additional approaches based upon cavity-enhanced and photoacoustic measurements, which are also making invaluable contributions in airborne atmospheric studies, are not discussed in this brief overview.

  7. Voyager infrared observations of Uranus' atmosphere - Thermal structure and dynamics

    NASA Astrophysics Data System (ADS)

    Flasar, F. M.; Conrath, B. J.; Pirraglia, J. A.; Gierasch, P. J.

    1987-12-01

    Temperatures in the Uranus atmosphere are derived from infrared spectrometer (IRIS) observations for a layer between 60 and 200 mbar, which includes the tropopause, where the vertical profile of temperature has a minimum. The variation with latitude of these temperatures and the implied thermal winds are in the same sense as those previously reported at the lower altitude range. The authors discuss the implications of this for dynamical models of the atmospheric thermal and wind structure. Finally, they use a linear, zonally symmetric model with radiative damping and frictional drag to estimate the magnitude of the frictional damping that is needed to account for the tropopause temperatures derived from IRIS observations and the zonal winds inferred from Voyager imaging data.

  8. Lower atmospheric composition of Jupiter from Voyager infrared measurements

    NASA Technical Reports Server (NTRS)

    Abbas, M. M.

    1984-01-01

    The observed spectrum of Jovian atmosphere exhibits spectral features of H2, CH4, C2H6, NH3, H2O, GeH4 and CH3D. Analytical programs were developed for radiative transfer calculations and for retrieval of lower atmospheric composition of Jupiter from the observed infrared spectrum. The program models developed are based line by line transmittance calculations with appropriate convolution of the instrument function. The constituent inversion programs were evaluated for accuracy by analyzing synthetic data for retrievals of NH3 profiles. The inversion programs were employed for retrieval of NH3 profiles from the Voyager infared data with results generally in agreement with the accepted values.

  9. ACE infrared spectral atlases of the Earth's atmosphere

    NASA Astrophysics Data System (ADS)

    Hughes, Ryan; Bernath, Peter; Boone, Chris

    2014-11-01

    Five infrared atmospheric atlases are presented using solar occultation spectra from the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) in low earth orbit. The spectral atlases were created for Arctic summer, Arctic winter, mid-latitude summer, mid-latitude winter and the tropics. Each covers the spectral range from 700 to 4400 cm-1 and consists of 31 spectra that span an altitude range of 6-126 km in 4-km altitude intervals. To improve the signal-to-noise ratio, each spectrum in the atlas is an average of at least several hundred individual ACE-FTS limb transmission spectra. Representative plots in pdf format at 10 km (troposphere), 30 km (stratosphere), 70 km (mesosphere), and 110 km (lower thermosphere) are also available.

  10. Atmospheric Remote Sensing via Infrared-Submillimeter Double Resonance

    NASA Astrophysics Data System (ADS)

    Srikantaiah, Sree; Holt, Jennifer; Neese, Christopher F.; Phillips, Dane; Everitt, Henry O.; De Lucia, Frank C.

    2016-06-01

    Specificity and sensitivity in atmospheric pressure remote sensing have always been big challenges. This is especially true for approaches that involve the submillimeter/terahertz (smm/THz) spectral region because atmospheric pressure broadening precludes taking advantage of the small Doppler broadening in the region. The Infrared-submillimeter (IR-smm) double resonance spectroscopic technique allows us to obtain a more specific two-dimensional signature as well as a means of modulating the molecular signal to enhance its separation from background and system variation. Applying this technique at atmospheric pressure presents a unique bandwidth requirement on the IR pump laser, and the smm/THz receiver. We will discuss the pump system comprising of a CO2 TEA laser, plasma switch and a free induction decay hot cell designed to produce fast IR pulses on the time scale of atmospheric pressure relaxation and a high bandwidth fast pulse smm/THz receiver. System diagnostics will also be discussed. Results as a function of pressure and pump pulse width will be presented.

  11. Infrared heterodyne radiometer for airborne atmospheric transmittance measurements

    NASA Technical Reports Server (NTRS)

    Wolczok, J. M.; Lange, R. A.; Dinardo, A. J.

    1980-01-01

    An infrared heterodyne radiometer (IHR) was used to measure atmospheric transmittance at selected hydrogen fluoride (2.7 micrometer) and deuterium fluoride (3.8 micrometer) laser transitions. The IHR was installed aboard a KC-135 aircraft for an airborne atmospheric measurements program that used the sun as a backlighting source for the transmission measurements. The critical components are: a wideband indium antimonide (1nSb) photomixer, a CW HF/DF laser L0, a radiometric processor, and a 1900 K blackbody reference source. The measured heterodyne receiver sensitivity (NEP) is 1.3 x 10 to the -19th power W/Hz, which yields a calculated IHR temperature resolution accuracy of delta I sub S/-3 sub S = 0.005 for a source temperature of 1000 K and a total transmittance of 0.5. Measured atmospheric transmittance at several wavelengths and aircraft altitudes from 9.14 km (30,000 ft) to 13.72 km (45,000 ft) were obtained during the measurements program and have been compared with values predicted by the AFGL Atmospheric Line Parameter Compilation.

  12. Range estimation of passive infrared targets through the atmosphere

    NASA Astrophysics Data System (ADS)

    Cho, Hoonkyung; Chun, Joohwan; Seo, Doochun; Choi, Seokweon

    2013-04-01

    Target range estimation is traditionally based on radar and active sonar systems in modern combat systems. However, jamming signals tremendously degrade the performance of such active sensor devices. We introduce a simple target range estimation method and the fundamental limits of the proposed method based on the atmosphere propagation model. Since passive infrared (IR) sensors measure IR signals radiating from objects in different wavelengths, this method has robustness against electromagnetic jamming. The measured target radiance of each wavelength at the IR sensor depends on the emissive properties of target material and various attenuation factors (i.e., the distance between sensor and target and atmosphere environment parameters). MODTRAN is a tool that models atmospheric propagation of electromagnetic radiation. Based on the results from MODTRAN and atmosphere propagation-based modeling, the target range can be estimated. To analyze the proposed method's performance statistically, we use maximum likelihood estimation (MLE) and evaluate the Cramer-Rao lower bound (CRLB) via the probability density function of measured radiance. We also compare CRLB and the variance of MLE using Monte-Carlo simulation.

  13. Investigation of Infra-red and Nonequilibrium Air Radiation

    NASA Technical Reports Server (NTRS)

    Kruger, Charles H.; Laux, Christophe O.

    1994-01-01

    This report summarizes the results obtained during a research program on the infrared radiation of air plasmas conducted in the High Temperature Gasdynamics Laboratory at Stanford University. This program was intended to investigate the masking of infrared signatures by the air plasma formed behind the bow shock of high velocity missiles. Prior to this work, the radiative emission of air plasmas in the infrared had been the object of few experimental investigations, and although several infrared systems were already modeled in radiation codes such as NEQAIR, measurements were required to validate numerical predictions and indicate whether all transitions of importance were accounted for in the model. The program was further motivated by the fact that 9 excited states (A, B, C, D, B', F, H, and H') of NO radiate in the infrared, especially between 1 and 1.5 microns where at least 9 transitions involving can be observed. Because these IR transitions are relatively well separated from each other, excited NO states concentrations can be easily measured, thus providing essential information on excited-state chemistry for use in optical diagnostics or in electronic excitation model validation. Detailed comparisons between measured and simulated spectra are presented.

  14. Non-LTE diagnositics of infrared radiation of Titan's atmosphere

    NASA Astrophysics Data System (ADS)

    Feofilov, Artem; Rezac, Ladislav; Kutepov, Alexander; Vinatier, Sandrine; Rey, Michael; Nikitin, Andrew; Tyuterev, Vladimir

    2016-06-01

    Yelle (1991) and Garcia-Comas et al, (2011) demonstrated the importance of accounting for the local thermodynamic equilibrium (LTE) breakdown in the middle and upper atmosphere of Titan for the interpretation of infrared radiances measured at these heights. In this work, we make further advance in this field by: • updating the non-LTE model of CH4 emissions in Titan's atmosphere and including a new extended database of CH4 spectroscopic parameters • studying the non-LTE CH4 vibrational level populations and the impact of non-LTE on limb infrared emissions of various CH4 ro-vibrational bands including those at 7.6 and 3.3 µm • implementing our non-LTE model into the LTE-based retrieval algorithm applied by Vinatier et al., (2015) for processing the Cassini/CIRS spectra. We demonstrate that accounting for non-LTE leads to an increase in temperatures retrieved from CIRS 7.6 µm limb emissions spectra (˜10 K at 600 km altitude) and estimate how this affects the trace gas density retrieval. Finally, we discuss the effects of including a large number of weak one-quantum and combinational bands on the calculated daytime limb 3.3 µm emissions and the impact they may have on the CH4 density retrievals from the Cassini VIMS 3.3 µm limb emission observations.

  15. Infrared polarization spectroscopy of CO 2 at atmospheric pressure

    NASA Astrophysics Data System (ADS)

    Alwahabi, Z. T.; Li, Z. S.; Zetterberg, J.; Aldén, M.

    2004-04-01

    Polarisation spectroscopy (PS) was used to probe CO 2 gas concentration in a CO 2/N 2 binary mixture at atmospheric pressure and ambient temperature. The CO 2 molecules were probed by a direct laser excitation to an overtone and combination vibrational state. The tuneable narrow linewidth infrared laser radiation at 2 μm was obtained by Raman shifting of the output from a single-longitudinal-mode pulsed alexandrite laser-system to the second Stokes component in a H 2 gas cell. Infrared polarisation spectroscopy (IRPS) and time-resolved infrared laser-induced fluorescence (IRLIF) spectra were collected. A linear dependence of the IRPS signal on the CO 2 mole fraction has been found. This indicates that the IRPS signal is only weakly affected by the molecular collisions and that the inter- and intra- molecular energy transfer processes do not strongly influence the molecular alignment at the time scale of the measurements. Thus IRPS holds great potential for quantitative instantaneous gas concentration diagnostics in general. This is especially important for molecules which do not posses an accessible optical transition such as CO, CO 2 and N 2O. In addition, an accurate experimental method to measure the extinction ratio of the IR polarisers employed in this study has been developed and applied. With its obvious merits as simplicity, easy alignment and high accuracy, the method can be generalized to all spectral regions, different polarisers and high extinction ratios.

  16. Atmospheric pressure molecular imaging by infrared MALDI mass spectrometry.

    PubMed

    Li, Yue; Shrestha, Bindesh; Vertes, Akos

    2007-01-15

    An atmospheric pressure (AP) MALDI imaging interface was developed for an orthogonal acceleration time-of-flight mass spectrometer and utilized to analyze peptides, carbohydrates, and other small biomolecules using infrared laser excitation. In molecular imaging experiments, the spatial distribution of mock peptide patterns was recovered with a detection limit of approximately 1 fmol/pixel from a variety of MALDI matrixes. With the use of oversampling for the image acquisition, a spatial resolution of 40 microm, 5 times smaller than the laser spot size, was achieved. This approach, however, required that the analyte was largely removed at the point of analysis before the next point was interrogated. Native water in plant tissue was demonstrated to be an efficient natural matrix for AP infrared laser desorption ionization. In soft fruit tissues from bananas, grapes, and strawberries, potassiated ions of the most abundant metabolites, small carbohydrates, and their clusters produced the strongest peaks in the spectra. Molecular imaging of a strawberry skin sample revealed the distribution of the sucrose, glucose/fructose, and citric acid species around the embedded seeds. Infrared AP MALDI mass spectrometric imaging without the addition of an artificial matrix enables the in vivo investigation of small biomolecules and biological processes (e.g., metabolomics) in their natural environment.

  17. High Vertically Resolved Atmospheric and Surface/Cloud Parameters Retrieved with Infrared Atmospheric Sounding Interferometer (IASI)

    NASA Technical Reports Server (NTRS)

    Zhou, Daniel K.; Liu, Xu; Larar, Allen M.; Smith, WIlliam L.; Taylor, Jonathan P.; Schluessel, Peter; Strow, L. Larrabee; Mango, Stephen A.

    2008-01-01

    The Joint Airborne IASI Validation Experiment (JAIVEx) was conducted during April 2007 mainly for validation of the IASI on the MetOp satellite. IASI possesses an ultra-spectral resolution of 0.25/cm and a spectral coverage from 645 to 2760/cm. Ultra-spectral resolution infrared spectral radiance obtained from near nadir observations provide atmospheric, surface, and cloud property information. An advanced retrieval algorithm with a fast radiative transfer model, including cloud effects, is used for atmospheric profile and cloud parameter retrieval. This physical inversion scheme has been developed, dealing with cloudy as well as cloud-free radiance observed with ultraspectral infrared sounders, to simultaneously retrieve surface, atmospheric thermodynamic, and cloud microphysical parameters. A fast radiative transfer model, which applies to the cloud-free and/or clouded atmosphere, is used for atmospheric profile and cloud parameter retrieval. A one-dimensional (1-d) variational multi-variable inversion solution is used to improve an iterative background state defined by an eigenvector-regression-retrieval. The solution is iterated in order to account for non-linearity in the 1-d variational solution. It is shown that relatively accurate temperature and moisture retrievals are achieved below optically thin clouds. For optically thick clouds, accurate temperature and moisture profiles down to cloud top level are obtained. For both optically thin and thick cloud situations, the cloud top height can be retrieved with relatively high accuracy (i.e., error < 1 km). Preliminary retrievals of atmospheric soundings, surface properties, and cloud optical/microphysical properties with the IASI observations are obtained and presented. These retrievals will be further inter-compared with those obtained from airborne FTS system, such as the NPOESS Airborne Sounder Testbed - Interferometer (NAST-I), dedicated dropsondes, radiosondes, and ground based Raman Lidar. The

  18. Near- and mid-Infrared Resolved Imaging of Titan's Atmosphere

    NASA Astrophysics Data System (ADS)

    Roe, H. G.; de Pater, I.; Gibbard, S. G.; Macintosh, B.; Max, C. E.; McKay, C. P.

    2000-10-01

    We present spatially resolved images of Titan in the near-infrared (1-2.5 μ m) with the W.M. Keck Observatory Adaptive Optics (AO) system and in the mid-infrared (8-13 μ m) with the Keck Long Wave Spectometer (LWS). On 30 October 1999 (UT) we observed a bright cloud band at 70° S latitude in two narrowband filters (each ~1% bandwidth centered on 1.158 μ m and 1.702 μ m) chosen such that they selectively probe the atmosphere above the tropopause. The feature was spatially unresolved in latitude and extended over all visible longitudes. From measurements of a star, the AO system achieved a spatial resolution at 1.158 μ m of 0.032'', or 190 km on Titan. Further, we observed a broad haze band extending over approximately 60o of latitude centered slightly south of Titan's equator. This feature is apparent in near-infrared AO images from October 1999. Mid-infrared LWS images from September and November 1999 with a resolution of ~0.2'' show structure across the disk of Titan, and we compare these with models of haze thermal emission in order to determine the haze distribution. HGR is funded by a NASA-GSRP fellowship. This research was supported in part by the STC Program of the National Science Foundation under Agreement No. AST-9876783, and in part under the auspices of the US Department of Energy at Lawrence Livermore National Laboratory, Univ. of Calif. under contract No. W-7405-Eng-48.

  19. Motion in Jupiter's Atmospheric Vortices (Near-infrared filters)

    NASA Technical Reports Server (NTRS)

    1997-01-01

    Two frame 'movie' of a pair of vortices in Jupiter's southern hemisphere. The two frames are separated by ten hours. The right oval is rotating counterclockwise, like other anticyclonic bright vortices in Jupiter's atmosphere. The left vortex is a cyclonic (clockwise) vortex. The differences between them (their brightness, their symmetry, and their behavior) are clues to how Jupiter's atmosphere works. The frames span about fifteen degrees in latitude and longitude and are centered at 141 degrees west longitude and 36 degrees south planetocentric latitude. Both vortices are about 3500 kilometers in diameter in the north-south direction.

    The images were taken in near infrared light at 756 nanometers and show clouds that are at a pressure level of about 1 bar in Jupiter's atmosphere. North is at the top. The smallest resolved features are tens of kilometers in size. These images were taken on May 7, 1997, at a range of 1.5 million kilometers by the Solid State Imaging system on NASA's Galileo spacecraft.

    The Jet Propulsion Laboratory, Pasadena, CA manages the Galileo mission for NASA's Office of Space Science, Washington, DC. JPL is an operating division of California Institute of Technology (Caltech).

    This image and other images and data received from Galileo are posted on the World Wide Web, on the Galileo mission home page at URL http://galileo.jpl.nasa.gov. Background information and educational context for the images can be found at URL http://www.jpl.nasa.gov/galileo/sepo

  20. Validation of the Atmospheric Infrared Sounder Water Vapor Retrievals Using Global Positioning System: Case Study in South Korea

    NASA Astrophysics Data System (ADS)

    Won, Jihye; Park, Kwan-Dong; Kim, Dusik; Ha, Jihyun

    2011-12-01

    The atmospheric infrared sounder (AIRS) sensor loaded on the Aqua satellite observes the global vertical structure of atmosphere and enables verification of the water vapor distribution over the entire area of South Korea. In this study, we performed a comparative analysis of the accuracy of the total precipitable water (TPW) provided as the AIRS level 2 standard retrieval product by Jet Propulsion Laboratory (JPL) over the South Korean area using the global positioning system (GPS) TPW data. The analysis TPW for the period of one year in 2008 showed that the accuracy of the data produced by the combination of the Advanced Microwave Sounding Unit sensor with the AIRS sensor to correct the effect of clouds (AIRS-X) was higher than that of the AIRS IR-only data (AIRS-I). The annual means of the root mean square error with reference to the GPS data were 5.2 kg/m2 and 4.3 kg/m2 for AIRS-I and AIRS-X, respectively. The accuracy of AIRS-X was higher in summer than in winter while measurement values of AIRS-I and AIRS-X were lower than those of GPS TPW to some extent.

  1. Design And Implementation Of A Broadband Infrared Atmospheric Transmissometer

    NASA Astrophysics Data System (ADS)

    Gruenzel, Ronald R.; Martin, William C.; Schuwerk, M. James

    1981-07-01

    For the past several years the Air Force has been involv..ed with the attempt to measure narrowband atmospheric transmission over horizontal paths (up to 8km) in three spectral regions--visible, 3-5 micrometers and 8-12 micrometers. The data is required for use in LOWTRAN model verification, itself a prime tool for predicting imaging sensor performance as it relates to meteorological conditions. Problems associated with the use of commercially available equipment purchased by the Air Force are briefly described, as well as the design of a new transmissometer receiver intended to operate over the full 8km range. Measurements taken with this new receiver are presented along with their LOWTRAN predictions. Preliminary data indicates that the accuracy attainable with this instrument far exceeds that of the original equipment and will serve as a great help in LOWTRAN validation efforts currently underway.

  2. In-Scene Atmospheric Characterization and Compensation in Hyperspectral Thermal Infrared Images

    NASA Technical Reports Server (NTRS)

    Gillespie, A.; Alley, R.; Kahle, A.; Cothern, S.

    1998-01-01

    Compensation of thermal infrared radiometric measurements for atmospheric absorption and emission is one of the main factors limiting the accurate estimation of land surface temperatures and emissivities today.

  3. Near-infrared conical emission from 800 nm filament in air

    NASA Astrophysics Data System (ADS)

    Shipilo, D. E.; Pushkarev, D. V.; Panov, N. A.; Uryupina, D. S.; Andreeva, V. A.; Volkov, R. V.; Balakin, A. V.; Shkurinov, A. P.; Babushkin, I.; Morgner, U.; Kosareva, O. G.; Savel’ev, A. B.

    2017-03-01

    We used a single shot imaging technique to register frequency-angular distribution at different positions along the filament of 55 fs 800 nm pulse focused with the numerical aperture of about 1/600 into air. We have revealed that the phenomena accompanying filamentation develop successively in the propagation direction. The conical emission in the visible comes first. Later in the propagation the conical emission in the infrared appears and develops down to 900 nm at least. Multiple robust light bullets become the secondary sources of the conical waves on the infrared side of the spectrum. The overall scenario of the nonlinear phenomena successive appearance in air is for the first time unified in one experiment in atmospheric gases and simulated with the carrier wave resolved in agreement with the experiment.

  4. Atmospheric and Spectroscopic Research in the Far Infrared

    NASA Technical Reports Server (NTRS)

    Park, Kwangjai

    1998-01-01

    The spectroscopic measurements of molecular parameters constitute one of the major areas of our research program. This part of our program has been conducted in close collaboration with Smithsonian Astrophysical Observatory (SAO) and National Institute of Standards and Technology (NIST). The references on HO2, OH, and O2 that appear on the publication list are examples of this type of work completed during the grant period. These pressure-broadening studies have provided the kind of improvements needed in the database for retrieving atmospheric profiles from far infrared limb sensing data. One example of this linkage between the pressure broadening studies and the improvements in data retrieval is described in the paper on HBr (paper #4, publication list). The retrieval of the concentration profile of this important species from the IBEX data was facilitated by a number of performance improvement factors, not the least of which was the database improvements.

  5. Infrared Absorption by Atmospheric Aerosols in Mexico City during MILAGRO.

    NASA Astrophysics Data System (ADS)

    Kelley, K. L.; Mangu, A.; Gaffney, J. S.; Marley, N. A.

    2007-12-01

    found as colloidal materials in surface and groundwaters (4). Examples of the IR spectra obtained and variance as a function of time at the two sites will be presented. The spectra are taken in Kubelka - Munk format, which also allows the infrared absorption strengths to be evaluated as function of wavelength. The wavelength dependence of the aerosol complex refractive index (m = n + ik) in the infrared spectral region is determined by application of the Kramers Kronig function. The importance of the aerosol absorption in the infrared spectral region to radiative forcing will be discussed. 1. N.A. Marley, J.S. Gaffney, and M.M. Cunningham,Environ. Sci. Technol. 27 2864-2869 (1993). 2. N.A. Marley, J.S. Gaffney, and M.M. Cunningham, Spectroscopy 7 44-53 (1992). 3. J.S. Gaffney and N.A. Marley, Atmospheric Environment, New Directions contribution, 32, 2873-2874 (1998). 4. N.A. Marley, J.S. Gaffney, and K.A. Orlandini, Chapter 7 in Humic/Fulvic Acids and Organic Colloidal Materials in the Environment, ACS Symposium Series 651, American Chemical Society, Washington, D.C., pp. 96-107, 1996. This work was performed as part of the Department of Energy's Megacity Aerosol Experiment - Mexico City (MAX- Mex) under the support of the Atmospheric Science Program. This research was supported by the Office of Science (BER), U.S. Department of Energy, Grant No. DE-FG02-07ER64328.

  6. Smartphone Air Quality and Atmospheric Aerosol Characterization for Public Health Applications

    NASA Astrophysics Data System (ADS)

    Strong, S. B.; Brown, D. M.; Brown, A.

    2014-12-01

    Air quality is a major global concern. Tracking and monitoring air quality provides individuals with the knowledge to make personal decisions about their health and investigate the environment in which they live. Satellite remote sensing and ground-based observations (e.g. Environmental Protection Agency, NASA Aerosol Robotic Network) of air quality is spatially and temporarlly limited and often neglects to provide individuals with the freedom to understand their own personal environment using their personal observations. Given the ubiquitous nature of smartphones, individuals have access to powerful processing and sensing capabilities. When coupled with the appropriate sensor parameters, filters, and algorithms, smartphones can be used both for 'citizen science' air quality applications and 'professional' scientific atmospheric investigations, alike, simplifying data analysis, processing, and improving deployment efficiency. We evaluate the validity of smartphone technology for air quality investigations using standard Cimel CE 318 sun photometry and Fourier Transform Infrared Spectroradiometer (FTIR) observations at specific locations.

  7. THE ATMOSPHERIC MODEL EVALUATION TOOL (AMET); AIR QUALITY MODULE

    EPA Science Inventory

    This presentation reviews the development of the Atmospheric Model Evaluation Tool (AMET) air quality module. The AMET tool is being developed to aid in the model evaluation. This presentation focuses on the air quality evaluation portion of AMET. Presented are examples of the...

  8. Degradation of near infrared and shortwave infrared imager performance due to atmospheric scattering of diffuse night illumination.

    PubMed

    Vollmerhausen, Richard

    2013-07-20

    On moonless nights, airglow is the primary source of natural ground illumination in the near infrared and shortwave infrared spectral bands. Therefore, night vision imagers operating in these spectral bands view targets that are diffusely illuminated. Aerosol scattering of diffuse airglow illumination causes atmospheric path radiance and that radiance causes increased imager noise. These phenomena and their quantification are described in this paper.

  9. Improving the Air Force Infrared Stellar Calibration Network with High Spectral Resolution Data from the Infrared Space Observatory

    NASA Astrophysics Data System (ADS)

    Kraemer, K. E.; Engelke, C. W.; Price, S. D.

    2004-12-01

    We present preliminary results of a project to improve the spectral resolution of the Air Force Infrared Stellar Calibration Network by incorporating data from the Infrared Space Observatory (ISO). This network and its deriviatives were created by Cohen and colleagues to support infrared calibration for government and civilian ground- and space-based observatories, such as the Infrared Telescope Facility, Gemini, and the Maui Optical Site. The reduced 2.4 to 45 μ m spectra from the ISO Short Wavelength Spectrometer (SWS) are up to 100 times higher spectral resolution than the current network data. Appropriately substituting these spectra for the standard stars will improve the accuracy of the calibration network, particularly in spectral regions where the atmosphere limits ground-based data, and permit more accurate calibration of very narrow spectral bandpasses. The initial effort has photometrically calibrated the SWS spectra for the 9 stellar or secondary standards with composites. The model atmosphere spectrum for α Cen has been replaced by SWS data; the model spectra for α CMa and α Lyr have been retained in order to preserve the common calibration pedigree with the original Cohen et al. network (although see Price et al. 2004, AJ, 128, 889). Where available, high quality photometry from the Midcourse Space Experiment (MSX) are used, supplemented by photometry from the Diffuse Infrared Background Experment (DIRBE) and the photometry used by Cohen et al. used to create the original composite. The next steps are to 1) replace the 10-15 tertiary standard stars with template spectra with measured spectra for the cases in which the SWS observations have sufficiently high signal-to-noise ratios (this will double the number of secondary standards); 2) develop a set of high spectral resolution infrared templates based on the SWS observations for each MK spectral class of the secondary standards with which to upgrade the entire network; 3) create new templates for

  10. Infrared photometry and spectrophotometry of Titan. [for atmospheric brightness temperature model

    NASA Technical Reports Server (NTRS)

    Morrison, D.

    1974-01-01

    The wide variation in infrared brightness temperature of Titan is explained in terms of a greenhouse effect. Radiometric observations in the infrared and microwave frequencies indicate an alternate hot atmospheric model. Methane, ammonia, hydrogen atoms, and nitrogen atoms are suggested as main constituents for the Titan atmosphere.

  11. Studies of Arctic Middle Atmosphere Chemistry using Infrared Absorption Spectroscopy

    NASA Astrophysics Data System (ADS)

    Lindenmaier, Rodica

    The objective of this Ph.D. project is to investigate Arctic middle atmosphere chemistry using solar infrared absorption spectroscopy. These measurements were made at the Polar Environment Atmospheric Research Laboratory (PEARL) at Eureka, Nunavut, which is operated by the Canadian Network for the Detection of Atmospheric Change (CANDAC). This research is part of the CANDAC/PEARL Arctic Middle Atmosphere Chemistry theme and aims to improve our understanding of the processes controlling the stratospheric ozone budget using measurements of the concentrations of stratospheric constituents. The instrument, a Bruker IFS 125HR Fourier transform infrared (FTIR) spectrometer, has been specifically designed for high-resolution measurements over a broad spectral range and has been used to measure reactive species, source gases, reservoirs, and dynamical tracers at PEARL since August 2006. The first part of this research focuses on the optimization of ozone retrievals, for which 22 microwindows were studied and compared. The spectral region from 1000 to 1005 cm-1 was found to be the most sensitive in both the stratosphere and troposphere, giving the highest number of independent pieces of information and the smallest total error for retrievals at Eureka. Similar studies were performed in coordination with the Network for the Detection of Atmospheric Composition Change for nine other species, with the goal of improving and harmonizing the retrieval parameters among all Infrared Working Group sites. Previous satellite validation exercises have identified the highly variable polar conditions of the spring period to be a challenge. In this work, comparisons between the 125HR and ACE-FTS (Atmospheric Chemistry Experiment-Fourier transform spectrometer) from 2007 to 2010 have been used to develop strict criteria that allow the ground and satellite-based instruments to be confidently compared. After applying these criteria, the differences between the two instruments were generally

  12. Detection of Ice Polar Stratospheric Clouds from Assimilation of Atmospheric Infrared Sounder Data

    NASA Technical Reports Server (NTRS)

    Stajner, Ivanka; Benson, Craig; Liu, Hui-Chun; Pawson, Steven; Chang, Ping; Riishojgaard, Lars Peter

    2006-01-01

    A novel technique is presented for detection of ice polar stratospheric clouds (PSCs) that form at extremely low temperatures in the lower polar stratosphere during winter. Temperature is a major factor in determining abundance of PSCs, which in turn provide surfaces for heterogeneous chemical reactions leading to ozone loss and radiative cooling. The technique infers the presence of ice PSCs using radiances from the Atmospheric Infrared Sounder (AIRS) in the Goddard Earth Observing System version 5 (GEOS-5) data assimilation system. Brightness temperatures are computed from short-term GEOS-5 forecasts for several hundred AIRS channels, using a radiation transfer module. The differences between collocated AIRS observations and these computed values are the observed-minus-forecast (O-F) residuals in the assimilation system. Because the radiation model assumes clear-sky conditions, we hypothesize that these O-F residuals contain quantitative information about PSCs. This is confirmed using sparse data from the Polar Ozone and Aerosol Measurement (POAM) III occultation instrument. The analysis focuses on 0-F residuals for the 6.79pm AIRS moisture channel. At coincident locations, when POAM III detects ice clouds, the AIRS O-F residuals for this channel are lower than -2K. When no ice PSCs are evident in POAM III data, the AIRS 0-F residuals are larger. Given this relationship, the high spatial density of AIRS data is used to construct maps of regions where 0-F residuals are lower than -2K, as a proxy for ice PSCs. The spatial scales and spatio-temporal variations of these PSCs in the Antarctic and Arctic are discussed on the basis of these maps.

  13. The Radiative Consistency of Atmospheric Infrared Sounder and Moderate Resolution Imaging Spectroradiometer Cloud Retrievals

    NASA Technical Reports Server (NTRS)

    Kahn, Brian H.; Fishbein, Evan; Nasiri, Shaima L.; Eldering, Annmarie; Fetzer, Eric J.; Garay, Michael J.; Lee, Sung-Yung

    2007-01-01

    The consistency of cloud top temperature (Tc) and effective cloud fraction (f) retrieved by the Atmospheric Infrared Sounder (AIRS)/Advanced Microwave Sounding Unit (AMSU) observation suite and the Moderate Resolution Imaging Spectroradiometer (MODIS) on the EOS-Aqua platform are investigated. Collocated AIRS and MODIS TC and f are compared via an 'effective scene brightness temperature' (Tb,e). Tb,e is calculated with partial field of view (FOV) contributions from TC and surface temperature (TS), weighted by f and 1-f, respectively. AIRS reports up to two cloud layers while MODIS reports up to one. However, MODIS reports TC, TS, and f at a higher spatial resolution than AIRS. As a result, pixel-scale comparisons of TC and f are difficult to interpret, demonstrating the need for alternatives such as Tb,e. AIRS-MODIS Tb,e differences ((Delta)Tb,e) for identical observing scenes are useful as a diagnostic for cloud quantity comparisons. The smallest values of DTb,e are for high and opaque clouds, with increasing scatter in (Delta)Tb,e for clouds of smaller opacity and lower altitude. A persistent positive bias in DTb,e is observed in warmer and low-latitude scenes, characterized by a mixture of MODIS CO2 slicing and 11-mm window retrievals. These scenes contain heterogeneous cloud cover, including mixtures of multilayered cloudiness and misplaced MODIS cloud top pressure. The spatial patterns of (Delta)Tb,e are systematic and do not correlate well with collocated AIRS-MODIS radiance differences, which are more random in nature and smaller in magnitude than (Delta)Tb,e. This suggests that the observed inconsistencies in AIRS and MODIS cloud fields are dominated by retrieval algorithm differences, instead of differences in the observed radiances. The results presented here have implications for the validation of cloudy satellite retrieval algorithms, and use of cloud products in quantitative analyses.

  14. Flight tests of a clear-air turbulence alerting system. [infrared radiometers

    NASA Technical Reports Server (NTRS)

    Kurkowski, R. L.; Kuhn, P. M.; Stearns, L. P.

    1981-01-01

    The detection of clear-air turbulence (CAT) ahead of an aircraft in real-time by an infrared (IR) radiometer is discussed. It is noted that the alter time and reliability depend on the band-pass of the IR filter used and on the altitude of the aircraft. Results of flights tests indicate that a bandpass of 20 to 40 microns appears optimal for altering the aircraft crew to CAT at times before encounter of 2 to 9 min. Alert time increases with altitude, as the atmospheric absorption determining the horizontal weighting is reduced.

  15. Nighttime Cirrus Detection using Atmospheric Infrared Sounder Window Channels and Total Column Water Vapor

    NASA Technical Reports Server (NTRS)

    Kahn, Brian H.; Liou, Kuo Nan; Lee, Sung-Yung; Fishbein, Evan F.; DeSouza-Machado, Sergio; Eldering, Annmarie; Fetzer, Eric J.; Hannon, Scott E.; Strow, L. Larrabee

    2005-01-01

    A method of cirrus detection at nighttime is presented that utilizes 3.8 and 10.4 (micro)m infrared (IR) window brightness temperature differences (dBT) and total column precipitable water (PW) measurements. This technique is applied to the Atmospheric Infrared Sounder (AIRS) and Advanced Microwave Sounding Unit A (AMSU-A) instrument suite on board EOS-Aqua, where dBT is determined from sets of carefully selected AIRS window channels, while PW is derived from the synergistic AIRS and AMSU-A water vapor retrievals. Simulated and observed dBT for a particular value of PW are not constant; several physical factors impact dBT, including the variability in temperature and relative humidity profiles, surface emissivity, instrument noise, and skin/ near-surface air temperature differences. We simulate clear-sky dBT over a realistic range of PWs using 8350 radiosondes that have varying temperature and relative humidity profiles. Thresholds between cloudy and uncertain sky conditions are derived once the scatter in the clear-sky dBT is determined. Simulations of optically thin cirrus indicate that this technique is most sensitive to cirrus optical depth in the 10 (micro)m window of 0.1-0.15 or greater over the tropical and subtropical oceans, where surface emissivity and skin/near-surface air temperature impacts on the IR radiances are minimal. The method at present is generally valid over oceanic regions only, specifically, the tropics and subtropics. The detection of thin cirrus, and other cloud types, is validated using observations at the Atmospheric Radiation Measurement (ARM) program site located at Manus Island in the tropical western Pacific for 89 coincident EOS-Aqua overpasses. Even though the emphasis of this work is on the detection of thin cirrus at nighttime, this technique is sensitive to a broad cloud morphology. The cloud detection technique agrees with ARM-detected clouds 82-84% of the time, which include thin cirrus, as well as other cloud types. Most of

  16. A Thermal Infrared Radiation Parameterization for Atmospheric Studies

    NASA Technical Reports Server (NTRS)

    Chou, Ming-Dah; Suarez, Max J.; Liang, Xin-Zhong; Yan, Michael M.-H.; Cote, Charles (Technical Monitor)

    2001-01-01

    This technical memorandum documents the longwave radiation parameterization developed at the Climate and Radiation Branch, NASA Goddard Space Flight Center, for a wide variety of weather and climate applications. Based on the 1996-version of the Air Force Geophysical Laboratory HITRAN data, the parameterization includes the absorption due to major gaseous absorption (water vapor, CO2, O3) and most of the minor trace gases (N2O, CH4, CFCs), as well as clouds and aerosols. The thermal infrared spectrum is divided into nine bands. To achieve a high degree of accuracy and speed, various approaches of computing the transmission function are applied to different spectral bands and gases. The gaseous transmission function is computed either using the k-distribution method or the table look-up method. To include the effect of scattering due to clouds and aerosols, the optical thickness is scaled by the single-scattering albedo and asymmetry factor. The parameterization can accurately compute fluxes to within 1% of the high spectral-resolution line-by-line calculations. The cooling rate can be accurately computed in the region extending from the surface to the 0.01-hPa level.

  17. Study on the characteristics of different infrared transmission in atmospheric turbulence

    NASA Astrophysics Data System (ADS)

    Wang, Zhe; Wang, Jing-yuan; Xu, Zhi-yong; Chang, Shuai; Zhao, Ji-yong; Chen, Yi-wang; Wang, Rong; Wei, Yi-mei

    2015-10-01

    It is known theoretically that the long wavelength infrared has better performance when transmitting in atmospheric turbulence. In order to evaluate the influence of the atmospheric turbulence quantificationally, the characteristics of different infrareds transmission in atmospheric turbulence are simulated and studied. A series of time relevant phase screens of atmospheric turbulence are simulated based on Fourier transform method proposed by McGlamery. Wind speed and direction are introduced in the meantime. Wavefront distortion, image spot dancing and spreading, receive loss of different wavelengths (0.85μm, 3.6μm, 10.6μm) are simulated respectively and compared to each other. The results show that the performances of long wavelength infrared (10.6μm) are the best, mid wavelength infrared (3.6μm) takes the second place and short wavelength infrared (0.85μm) is the worst.

  18. Infrared Aerosol Radiative Forcing at the Surface and the Top of the Atmosphere

    NASA Technical Reports Server (NTRS)

    Markowicz, Krzysztof M.; Flatau, Piotr J.; Vogelmann, Andrew M.; Quinn, Patricia K.; Welton, Ellsworth J.

    2003-01-01

    We study the clear-sky aerosol radiative forcing at infrared wavelengths using data from the Aerosol Characterization Experiment (ACE-Asia) cruise of the NOAA R/V Ronald H. Brown. Limited number of data points is analyzed mostly from ship and collocated satellite values. An optical model is derived from chemical measurements, lidar profiles, and visible extinction measurements which is used to and estimate the infrared aerosol optical thickness and the single scattering albedo. The IR model results are compared to detailed Fourier Transform Interferometer based infrared aerosol forcing estimates, pyrgeometer based infrared downward fluxes, and against the direct solar forcing observations. This combined approach attests for the self-consistency of the optical model and allows to derive quantities such as the infrared forcing at the top of the atmosphere or the infrared optical thickness. The mean infrared aerosol optical thickness at 10 microns is 0.08 and the single scattering albedo is 0.55. The modeled infrared aerosol forcing reaches 10 W/sq m during the cruise, which is a significant contribution to the total direct aerosol forcing. The surface infrared aerosol radiative forcing is between 10 to 25% of the shortwave aerosol forcing. The infrared aerosol forcing at the top of the atmosphere can go up to 19% of the solar aerosol forcing. We show good agreement between satellite (CERES instrument) retrievals and model results at the top of the atmosphere. Over the Sea of Japan, the average infrared radiative forcing is 4.6 W/sq m in the window region at the surface and it is 1.5 W/sq m at top of the atmosphere. The top of the atmosphere IR forcing efficiency is a strong function of aerosol temperature while the surface IR forcing efficiency varies between 37 and 55 W/sq m (per infrared optical depth unit). and changes between 10 to 18 W/sq m (per infrared optical depth unit).

  19. Developing of a New Atmospheric Ionizing Radiation (AIR) Model

    NASA Technical Reports Server (NTRS)

    Clem, John M.; deAngelis, Giovanni; Goldhagen, Paul; Wilson, John W.

    2003-01-01

    As a result of the research leading to the 1998 AIR workshop and the subsequent analysis, the neutron issues posed by Foelsche et al. and further analyzed by Hajnal have been adequately resolved. We are now engaged in developing a new atmospheric ionizing radiation (AIR) model for use in epidemiological studies and air transportation safety assessment. A team was formed to examine a promising code using the basic FLUKA software but with modifications to allow multiple charged ion breakup effects. A limited dataset of the ER-2 measurements and other cosmic ray data will be used to evaluate the use of this code.

  20. The Atmospheric Remote-sensing Infrared Exoplanets Large-survey (ARIEL) payload electronic subsystems

    NASA Astrophysics Data System (ADS)

    Focardi, M.; Pace, E.; Colomé, J.; Ribas, I.; Rataj, M.; Ottensamer, R.; Farina, M.; Di Giorgio, A. M.; Wawer, P.; Pancrazzi, M.; Noce, V.; Pezzuto, S.; Morgante, G.; Artigues, B.; Sierra-Roig, C.; Gesa, L.; Eccleston, P.; Crook, M.; Micela, G.

    2016-07-01

    The ARIEL mission has been proposed to ESA by an European Consortium as the first space mission to extensively perform remote sensing on the atmospheres of a well defined set of warm and hot transiting gas giant exoplanets, whose temperature range between ~600 K and 3000 K. ARIEL will observe a large number (~500) of warm and hot transiting gas giants, Neptunes and super-Earths around a range of host star types using transit spectroscopy in the ~2-8 μm spectral range and broad-band photometry in the NIR and optical. ARIEL will target planets hotter than 600 K to take advantage of their well-mixed atmospheres, which should show minimal condensation and sequestration of high-Z materials and thus reveal their bulk and elemental composition. One of the major motivations for exoplanet characterisation is to understand the probability of occurrence of habitable worlds, i.e. suitable for surface liquid water. While ARIEL will not study habitable planets, its major contribution to this topic will results from its capability to detect the presence of atmospheres on many terrestrial planets outside the habitable zone and, in many cases, characterise them. This represents a fundamental breakthrough in understanding the physical and chemical processes of a large sample of exoplanets atmospheres as well as their bulk properties and to probe in-space technology. The ARIEL infrared spectrometer (AIRS) provides data on the atmospheric composition; these data are acquired and processed by an On-Board Data Handling (OBDH) system including the Cold Front End Electronics (CFEE) and the Instrument Control Unit (ICU). The Telescope Control Unit (TCU) is also included inside the ICU. The latter is directly connected to the Control and Data Management Unit (CDMU) on board the Service Module (SVM). The general hardware architecture and the application software of the ICU are described. The Fine Guidance Sensor (FGS) electronics and the Cooler Control Electronics are also presented.

  1. Gas carburizing of steel with furnace atmospheres formed in situ from methane and air and from butane and air

    NASA Astrophysics Data System (ADS)

    Stickels, C. A.; Mack, C. M.; Pieprzak, J. A.

    1992-01-01

    Carburizing experiments were conducted at 927 °C (1700 °F) and 843 °C (1550 °F) using furnace atmospheres formed from methane and air and from butane and air introduced directly into the carburizing furnace. Gas flow rates were low to promote equilibration of the reaction products within the furnace. The air flow rate was held constant while the methane or butane flow was automatically regulated to maintain a constant oxygen potential, as measured by a zirconia oxygen sensor, within the furnace. In comparing the results of these experiments with earlier results obtained using propane and air, several differences were noted: (a) The methane content of the furnace atmosphere, measured by infrared analysis, was about twice as great when methane was the feed gas rather than propane or butane. This was true despite the fact that the mean residence time of the gas within the furnace was greater in the methane experiments. Methane appears to be less effective than propane or butane in reducing the CO2 and H2O contents to the levels required for carburizing. (b) There was a greater tendency for the CO content of the furnace atmosphere to decrease at high carbon potentials when methane is used instead of propane or butane. The decrease in CO content is due to hydrogen dilution caused by sooting in the furnace vestibule. These differences in behavior make propane or butane better suited than methane for in situ generation of carburizing atmospheres. However, there is no difference in the amount of carburizing occurring at a specified carbon potential when methane, propane, or butane are used as the feed gas in this process.

  2. Atmospheric effects on infrared measurements at ground level: Application to monitoring of transport infrastructures

    NASA Astrophysics Data System (ADS)

    Boucher, Vincent; Dumoulin, Jean

    2014-05-01

    and the water. These changes in refractive indexes lead to the evolution of extinction coefficient Kext according to relative humidity. Using such models in very low visibility conditions leads to the following question: Up to which optical depth (i.e. tau=Kext.d) can we use a simple scattering model as Mie Theory? To show the effect of multiple scattering on previous transmission estimation, Monte-Carlo calculations have been performed. Calculations used a software dedicated to photometrical rendering of fog (PROF [5]). Up to an optical depth tau=1, simple and multiple scatterings differ of less than 2%. For tau >1 the simple scattering model is no more available to keep the error less than 10%. Finally, study of fog effect is proposed. Results obtained by numerical simulations but also by experiments carried out in a dedicated fog tunnel are presented and discussed. Perspectives about possible implementation on on site measurement systems are evocated. REFERENCES [1]Proto M. et al., , 2010. Transport infrastructure surveillance and monitoring by electromagnetic sensing: the ISTIMES project. Sensors, 10,10620-10639, doi: 10.3390/s101210620. [2]J. Dumoulin, A. Crinière, R. Averty ," Detection and thermal characterization of the inner structure of the "Musmeci" bridge deck by infrared thermography monitoring ",Journal of Geophysics and Engineering, Volume 10, Number 2, November 2013, IOP Science, doi:10.1088/1742-2132/10/6/064003. [3]Shettle. P. and Fenn R. W., "Models for the aerosols of the lower atmosphere and the effects of humidity variations on their optical properties", Air Force Geophysics Laboratory 79-0214, (1979). [4]30. Hänel, Gottfried, "The properties of atmospheric aerosol particles as functions of the relarive humidity at thermodynamic equilibrium with the surrounding moist air, in Advances in Geophysics, 73-188. Edited by H.E. Landsberg, and J. Van Mieghem, Academic Press, New York, 1976. [5]31. Dumont E., "Semi-Monte Carlo light tracing applied to

  3. Atmospheric Ionizing Radiation (AIR) ER-2 Preflight Analysis

    NASA Technical Reports Server (NTRS)

    Tai, Hsiang; Wilson, John W.; Maiden, D. L.

    1998-01-01

    Atmospheric ionizing radiation (AIR) produces chemically active radicals in biological tissues that alter the cell function or result in cell death. The AIR ER-2 flight measurements will enable scientists to study the radiation risk associated with the high-altitude operation of a commercial supersonic transport. The ER-2 radiation measurement flights will follow predetermined, carefully chosen courses to provide an appropriate database matrix which will enable the evaluation of predictive modeling techniques. Explicit scientific results such as dose rate, dose equivalent rate, magnetic cutoff, neutron flux, and air ionization rate associated with those flights are predicted by using the AIR model. Through these flight experiments, we will further increase our knowledge and understanding of the AIR environment and our ability to assess the risk from the associated hazard.

  4. AIRS FPA applied to the MIRIADS: powerful infrared systems applications

    NASA Astrophysics Data System (ADS)

    Caulfield, John T.; McCarley, Paul L.; Baxter, Christopher R.; Massie, Mark A.

    2001-10-01

    Raytheon's Infrared Operations (RIO) has invented and developed a new type of focal plane array with 'Image Processing on-the-chip' named the Adaptive IR Sensor (AIRS). The AIRS FPA is based upon the human retina in that it performs signal processing near the photoreceptors. The AIRS FPA has been reduced to practice and adaptively removes detector and optic temperature drift and 1/f induced fixed pattern noise. This 3rd-generation multi-mode IRFPA, also called a Smart FPA, is a 256 X 256-array format capable of operation in four modes: (1) Direct Injection (DI), (2) Adaptive Non-uniformity Correction (NUC), (3) Motion/Edge Detection, and (4) Subframe Averaging. Nova Research has developed a Modular IR Application Development System (MIRIADS) which is a compact single board camera system that is highly integrated with the dewar assembly. The MIRIADS system coupled with the AIRS Smart FPA results in a very high performance wide field of view IR Sensor and processing system with integrated in one of the smallest packages to date.

  5. Thermal decomposition of dolomite under CO2-air atmosphere

    NASA Astrophysics Data System (ADS)

    Subagjo, Wulandari, Winny; Adinata, Pratitis Mega; Fajrin, Anita

    2017-01-01

    This paper reports a study on thermal decomposition of dolomite under CO2-air. Calcination was carried out non-isothermally by using thermogravimetry analysis-differential scanning calorimetry (TGA-DSC) with a heating rate of 10°C/minute in an air atmosphere as well as 10 vol% CO2 and 90 vol% air atmosphere from 25 to 950°C. In addition, a thermodynamic modeling was also carried out to simulate dolomite calcination in different level of CO2-air atmosphere by using FactSage® 7.0. The the main constituents of typical dolomite from Gresik, East Java include MgCO3 (magnesite), CaCO3 (calcite), Ca(OH)2, CaO, MgO, and less than 1% of metal impurities. Based on the kinetics analysis from TGA results, it is found that non-isothermal dolomite calcination in 10 vol% CO2 atmosphere is occurred in a two-stage reaction; the first stage is the decomposition of magnesite at 650-740 °C with activation energy of 161.23 kJ/mol, and the second stage is the decomposition of calcite at 775-820 °C with activation energy of 162.46 kJ/mol. The magnesite decomposition is found to follow nucleation reaction mechanism of Avrami Eroveyef (A3), while calcite decomposition follows second order chemical reaction equation. Thermodynamic modeling supports these kinetic analyses. The results of this research give insight to the kinetics of dolomite decomposition in CO2-air atmosphere.

  6. Atmospheric Soundings from AIRS/AMSU in Partial Cloud Cover

    NASA Technical Reports Server (NTRS)

    Susskind, Joel; Atlas, Robert

    2005-01-01

    Simultaneous use of AIRS/AMSU-A observations allow for the determination of accurate atmospheric soundings under partial cloud cover conditions. The methodology involves the determination of the radiances AIRS would have seen if the AIRS fields of view were clear, called clear column radiances, and use of these radiances to infer the atmospheric and surface conditions giving rise to these clear column radiances. Susskind et al. demonstrate via simulation that accurate temperature soundings and clear column radiances can be derived from AIRS/AMSU-A observations in cases of up to 80% partial cloud cover, with only a small degradation in accuracy compared to that obtained in clear scenes. Susskind and Atlas show that these findings hold for real AIRS/AMSU-A soundings as well. For data assimilation purposes, this small degradation in accuracy is more than offset by a significant increase in spatial coverage (roughly 50% of global cases were accepted, compared to 3.6% of the global cases being diagnosed as clear), and assimilation of AIRS temperature soundings in partially cloudy conditions resulted in a larger improvement in forecast skill than when AIRS soundings were assimilated only under clear conditions. Alternatively, derived AIRS clear column radiances under partial cloud cover could also be used for data assimilation purposes. Further improvements in AIRS sounding methodology have been made since the results shown in Susskind and Atlas . A new version of the AIRS/AMSU-A retrieval algorithm, Version 4.0, was delivered to the Goddard DAAC in February 2005 for production of AIRS derived products, including clear column radiances. The major improvement in the Version 4.0 retrieval algorithm is with regard to a more flexible, parameter dependent, quality control. Results are shown of the accuracy and spatial distribution of temperature-moisture profiles and clear column radiances derived from AIRS/AMSU-A as a function of fractional cloud cover using the Version 4

  7. The Arctic is becoming warmer and wetter as revealed by the Atmospheric Infrared Sounder

    NASA Astrophysics Data System (ADS)

    Boisvert, L. N.; Stroeve, J. C.

    2015-06-01

    Over the past decade, the Arctic has seen unprecedented declines in the summer sea ice area, leading to larger and longer exposed open water areas. The Atmospheric Infrared Sounder is a useful yet underutilized tool to study corresponding atmospheric changes and their feedbacks between 2003 and 2013. Most pronounced warming occurs between November and April, with skin and air temperatures increasing on average 2.5 K and 1.5 K over the Arctic Ocean. In response to sea ice loss, evaporation rates (i.e., moisture flux) increased between August and October by 1.5 × 10-3 g m-2 s-1 (3.8 W m-2 latent heat flux energy), increasing the water vapor feedback and cloud cover. Although most trends are positive over the Arctic Ocean, there is considerable interannual variability. Increasing specific humidity in May and corresponding downward moisture fluxes cause earlier melt onset; warming skin temperatures and radiative responses to increased water vapor and cloud cover in autumn delay freeze-up.

  8. Atmospheric transport and deposition of acidic air pollutants

    SciTech Connect

    Murphy, C.E. Jr.

    1981-01-01

    Although general principles which govern atmospheric chemistry of sulfur are understood, a purely theoretical estimation of the magnitude of the processes is not likely to be useful. Furthermore, the data base necessary to make empirical estimates does not yet exist. The sulfur budget of the atmosphere appears to be dominated by man-associated sulfur. The important processes in deposition of man-associated sulfur are wet deposition of sulfate and dry deposition of SO/sub 2/. The relative importance of sulfate and SO/sub 2/ to sulfur deposition (input to watersheds) depends on the air concentrations, and either compound may be the greater contributor depending on conditions. (PSB)

  9. Extreme atmospheric electron densities created by extensive air showers

    NASA Astrophysics Data System (ADS)

    Rutjes, Casper; Camporeale, Enrico; Ebert, Ute; Buitink, Stijn; Scholten, Olaf; Trinh, Gia

    2016-04-01

    A sufficient density of free electrons and strong electric fields are the basic requirements to start any electrical discharge. In the context of thunderstorm discharges it has become clear that in addition droplets and or ice particles are required to enhance the electric field to values above breakdown. In our recent study [1] we have shown that these three ingredients have to interplay to allow for lightning inception, triggered by an extensive air shower event. The extensive air showers are a very stochastic natural phenomenon, creating highly coherent bursts of extreme electron density in our atmosphere. Predicting these electron density bursts accurately one has to take the uncertainty of the input variables into account. To this end we use uncertainty quantification methods, like in [2], to post-process our detailed Monte Carlo extensive air shower simulations, done with the CORSIKA [3] software package, which provides an efficient and elegant way to determine the distribution of the atmospheric electron density enhancements. We will present the latest results. [1] Dubinova, A., Rutjes, C., Ebert, E., Buitink, S., Scholten, O., and Trinh, G. T. N. "Prediction of Lightning Inception by Large Ice Particles and Extensive Air Showers." PRL 115 015002 (2015) [2] G.J.A. Loeven, J.A.S. Witteveen, H. Bijl, Probabilistic collocation: an efficient nonintrusive approach for arbitrarily distributed parametric uncertainties, 45th AIAA Aerospace Sciences Meeting, Reno, Nevada, 2007, AIAA-2007-317 [3] Heck, Dieter, et al. CORSIKA: A Monte Carlo code to simulate extensive air showers. No. FZKA-6019. 1998.

  10. Generation of subnanosecond electron beams in air at atmospheric pressure

    NASA Astrophysics Data System (ADS)

    Kostyrya, I. D.; Tarasenko, V. F.; Baksht, E. Kh.; Burachenko, A. G.; Lomaev, M. I.; Rybka, D. V.

    2009-11-01

    Optimum conditions for the generation of runaway electron beams with maximum current amplitudes and densities in nanosecond pulsed discharges in air at atmospheric pressure are determined. A supershort avalanche electron beam (SAEB) with a current amplitude of ˜30 A, a current density of ˜20 A/cm2, and a pulse full width at half maximum (FWHM) of ˜100 ps has been observed behind the output foil of an air-filled diode. It is shown that the position of the SAEB current maximum relative to the voltage pulse front exhibits a time shift that varies when the small-size collector is moved over the foil surface.

  11. Atmospheric and surface properties of Mars obtained by infrared spectroscopy on Mariner 9

    NASA Technical Reports Server (NTRS)

    Conrath, B.; Curran, R.; Hanel, R.; Kunde, V.; Maguire, W.; Pearl, J.; Pirraglia, J.; Welker, J.; Burke, T.

    1973-01-01

    The infrared spectroscopy experiment on Mariner 9 obtained data over much of Mars. Interpretation of the thermal emission of Mars in terms of atmospheric temperatures, wind fields and dynamics, surface temperatures, surface pressure and topography, mineral composition, and minor atmospheric constituents including isotopic ratios, as well as a search for unexpected phenomena are reported.

  12. Saturn's Atmospheric Composition from Observations by the Cassini/Composite Infrared Spectrometer

    NASA Technical Reports Server (NTRS)

    Abbas, M. M.; Young, M.; LeClair, A. C.; Achterberg, R. K.; Flasar, F. M.; Kunde, V. G.

    2010-01-01

    Thermal emission infrared observation of Saturn s atmosphere are being made by the Composite Infrared Spectrometer (CIRS) aboard the Cassini spacecraft since its insertion in Saturn s orbit on July 2nd, 2004. The measurements made in both limb and nadir modes of observations consist of infrared spectra in the 10-1400/cm region with a variable spectral resolution of 0.53/cm and 2.8/cm, and exhibit rotational and vibrational spectral features that may be analyzed for retrieval of the thermal structure and constituent distribution of Saturn s atmosphere. In this paper, we present a comprehensive analysis of the CIRS infrared observed spectra for retrieval of Saturn s atmospheric composition focusing on the distributions of some selected hydrocarbons, phosphine, ammonia, and possible determination of the isotopic ratios of some species with sufficiently strong isolated spectral features. A comparison of the retrieved constituent distributions with the available data in the literature will be made.

  13. Improved Determination of Surface and Atmospheric Temperatures Using Only Shortwave AIRS Channels: The AIRS Version 6 Retrieval Algorithm

    NASA Technical Reports Server (NTRS)

    Susskind, Joel; Blaisdell, John; Iredell, Lena

    2010-01-01

    AIRS was launched on EOS Aqua on May 4, 2002 together with ASMU-A and HSB to form a next generation polar orbiting infrared and microwave atmosphere sounding system (Pagano et al 2003). The theoretical approach used to analyze AIRS/AMSU/HSB data in the presence of clouds in the AIRS Science Team Version 3 at-launch algorithm, and that used in the Version 4 post-launch algorithm, have been published previously. Significant theoretical and practical improvements have been made in the analysis of AIRS/AMSU data since the Version 4 algorithm. Most of these have already been incorporated in the AIRS Science Team Version 5 algorithm (Susskind et al 2010), now being used operationally at the Goddard DISC. The AIRS Version 5 retrieval algorithm contains three significant improvements over Version 4. Improved physics in Version 5 allowed for use of AIRS clear column radiances (R(sub i)) in the entire 4.3 micron CO2 absorption band in the retrieval of temperature profiles T(p) during both day and night. Tropospheric sounding 15 micron CO2 observations were used primarily in the generation of clear column radiances (R(sub i)) for all channels. This new approach allowed for the generation of accurate Quality Controlled values of R(sub i) and T(p) under more stressing cloud conditions. Secondly, Version 5 contained a new methodology to provide accurate case-by-case error estimates for retrieved geophysical parameters and for channel-by-channel clear column radiances. Thresholds of these error estimates are used in a new approach for Quality Control. Finally, Version 5 contained for the first time an approach to provide AIRS soundings in partially cloudy conditions that does not require use of any microwave data. This new AIRS Only sounding methodology was developed as a backup to AIRS Version 5 should the AMSU-A instrument fail. Susskind et al 2010 shows that Version 5 AIRS Only sounding are only slightly degraded from the AIRS/AMSU soundings, even at large fractional cloud

  14. Fire Influences on Atmospheric Composition, Air Quality, and Climate

    NASA Technical Reports Server (NTRS)

    Voulgarakis, Apostolos; Field, Robert D.

    2015-01-01

    Fires impact atmospheric composition through their emissions, which range from long-lived gases to short-lived gases and aerosols. Effects are typically larger in the tropics and boreal regions but can also be substantial in highly populated areas in the northern mid-latitudes. In all regions, fire can impact air quality and health. Similarly, its effect on large-scale atmospheric processes, including regional and global atmospheric chemistry and climate forcing, can be substantial, but this remains largely unexplored. The impacts are primarily realised in the boundary layer and lower free troposphere but can also be noticeable in upper troposphere/lower stratosphere (UT/LS) region, for the most intense fires. In this review, we summarise the recent literature on findings related to fire impact on atmospheric composition, air quality and climate. We explore both observational and modelling approaches and present information on key regions and on the globe as a whole. We also discuss the current and future directions in this area of research, focusing on the major advances in emission estimates, the emerging efforts to include fire as a component in Earth system modelling and the use of modelling to assess health impacts of fire emissions.

  15. Improved Determination of Surface and Atmospheric Temperatures Using Only Shortwave AIRS Channels

    NASA Technical Reports Server (NTRS)

    Susskind,Joel

    2009-01-01

    AIRS was launched on EOS Aqua on May 4, 2002, together with AMSU-A and HSB, to form a next generation polar orbiting infrared and microwave atmospheric sounding system. AIRS is a grating spectrometer with a number of linear arrays of detectors with each detector sensitive to outgoing radiation in a characteristic frequency v(sub i) with a spectral band pass delta v(sub i) of roughly v(sub i) /1200. AIRS contains 2378 spectral channels covering portions of the spectral region 650 cm(exp -1) (15.38 gm) - 2665 cm(exp -1)' (3.752 micrometers). These spectral regions contain significant absorption features from two CO2 absorption bands, the 15 micrometer (longwave) CO2 band, and the 4.3 micrometer (shortwave) CO, absorption band. There are also two atmospheric window regions, the 12 micrometerm - 8 micrometer (longwave) window, and the 4.17 micrometer - 3.75 micrometer (shortwave) window. Historically, determination of surface and atmospheric temperatures from satellite observations was performed using primarily observations in the longwave window and CO2 absorption regions. One reason for this was concerns about the effects, during the day, of reflected sunlight and non-Local Thermodynamic Equilibrium (non-LTE) on the observed radiances in the shortwave portion of the spectrum. According to cloud clearing theory, more accurate soundings of both surface skin and atmospheric temperatures can be obtained under partial cloud cover conditions if one uses the longwave channels to determine cloud cleared radiances R(sub i) for all channels, and uses R(sub i) only from shortwave channels in the determination of surface and atmospheric temperatures. This procedure is now being used by the AIRS Science Team in preparation for the AIRS Version 6 Retrieval Algorithm. This paper describes how the effects on the radiances of solar radiation reflected by clouds and the Earth's surface, and also of non-LTE, are accounted for in the analysis of the data. Results are presented for both

  16. Laboratory infrared studies of molecules of atmospheric and astrophysical interest

    NASA Technical Reports Server (NTRS)

    Rao, N. N.

    1982-01-01

    Nineteen reprints on the molecular species are compiled. Much of the work was done by using the Doppler-limited resolution provided by diode lasers. The diode laser was used as a source to a grating spectrometer which has been used earlier for high resolution studies. This technique provided many advantages. Wherever possible, the studies have been directed to intensity determinations of infrared bands.

  17. Natural sources of atmospheric aerosols influencing air quality across Europe.

    PubMed

    Viana, M; Pey, J; Querol, X; Alastuey, A; de Leeuw, F; Lükewille, Anke

    2014-02-15

    Atmospheric aerosols are emitted by natural and anthropogenic sources. Contributions from natural sources to ambient aerosols vary widely with time (inter-annual and seasonal variability) and as a function of the distance to source regions. This work aims to identify the main natural sources of atmospheric aerosols affecting air quality across Europe. The origin, frequency, magnitude, and spatial and temporal variability of natural events were assessed for the years 2008 and 2009. The main natural sources of atmospheric aerosols identified were African dust, sea spray and wildfires. Primary biological particles were not included in the present work. Volcanic eruptions did not affect air quality significantly in Europe during the study period. The impact of natural episodes on air quality was significant in Southern and Western Europe (Cyprus, Spain, France, UK, Greece, Malta, Italy and Portugal), where they contributed to surpass the PM10 daily and annual limit values. In Central and Northern Europe (Germany, Austria and Latvia) the impact of these events was lower, as it resulted in the exceedance of PM daily but not annual limit values. Contributions from natural sources to mean annual PM10 levels in 2008 and 2009 ranged between 1 and 2 μg/m(3) in Italy, France and Portugal, between 1 and 4 μg/m(3) in Spain (10 μg/m(3) when including the Canary Islands), 5 μg/m(3) in UK, between 3 and 8 μg/m(3) in Greece, and reached up to 13 μg/m(3) in Cyprus. The evaluation of the number of monitoring stations per country reporting natural exceedances of the daily limit value (DLV) is suggested as a potential tool for air quality monitoring networks to detect outliers in the assessment of natural contributions. It is strongly suggested that a reference methodology for the identification and quantification of African dust contributions should be adopted across Europe.

  18. Cloud thermodynamic phase, cirrus cloud optical thickness and effective diameter in the Version 6 Atmospheric Infrared Sounder data release

    NASA Astrophysics Data System (ADS)

    Kahn, B. H.; Irion, F. W.; Manning, E. M.; Oliphant, R.; Schreier, M. M.; Yue, Q.; Fetzer, E.; Jin, H.; Nasiri, S. L.; Baum, B. A.; Ou, S. S.; Takano, Y.; Liou, K.

    2011-12-01

    The development of a new set of cloud products produced in the upcoming Version 6 release of the Atmospheric Infrared Sounder (AIRS) algorithm is described and initial results are presented. The three new cloud retrieval products include (1) cloud thermodynamic phase, (2) cirrus cloud optical thickness, and (3) cirrus cloud effective diameter. The retrieval methodology of the cirrus cloud parameters is based on an optimal estimation approach that uses Level 1B observed radiances and Level 2 cloud clearing-derived atmospheric profiles that define the atmospheric state, surface temperature and emissivity, and cloud top temperature. The Stand Alone AIRS Radiative Transfer Algorithm (SARTA) is coupled to a delta-4-stream (D4S) approximation (SARTA+D4S) to simulate single-layered cloudy spectra. The same ice scattering models used in the Moderate Resolution Imaging Spectroradiometer (MODIS) Collection 5 release are also used in the SARTA+D4S model. The error characterization and averaging kernels associated with the retrieved fields, and various challenges to operational implementation, will be highlighted. Statistical comparisons are made to pixel-scale collocated Aqua MODIS retrievals, with similarities and differences quantified in the AIRS products that are sorted into distinct cloud regimes.

  19. Analysis of Atmospheric Composition and Tropospheric Variability With Integrated Open- Path and Ground-Based Solar Infrared Absorption Spectroscopy

    NASA Astrophysics Data System (ADS)

    Steill, J. D.; Compton, R. N.; Hager, J. S.

    2006-12-01

    Ground-based solar infrared absorption spectroscopy coupled with open-path spectroscopy provides a means for analysis of the highly variable contribution of the boundary layer to problems of radiative transfer and atmospheric chemistry. This is of particular importance in geographic regions of significant local anthropogenic influence and large tropospheric fluctuations in general. A Bomem DA8 FT-IR integrated with a sun-tracking and open-path system (~0.5 km) is located at The University of Tennessee, in downtown Knoxville and near The Great Smoky Mountains National Park, an area known for problematic air quality. From atmospheric absorption spectra, boundary layer concentrations as well as total column abundances and vertical concentration profiles are derived. A record of more than 1000 solar-sourced atmospheric spectra covering a period greater than three years in duration is under analysis to characterize the limit of precision in total column abundance determinations for many gases such as O3, CO, CH4, N2O, HF and CO2. Initial efforts using atmospheric O2 as a calibration indicate the solar-sourced spectra may not meet the precision required for the highly accurate atmospheric CO2 quantification by such global efforts as the OCO and NDSC. However, the determined variability of CO2 and other gas concentrations is statistically significant and is indicative of local concentration fluxes pertinent to the regional atmospheric chemistry. This is therefore an important data record in the southeastern United States, a somewhat under- sampled geographic region. In addition to providing a means to improve the analysis of solar spectra, the open-path data is useful for elucidation of seasonal and diurnal trends in the trace gas concentrations. This provides an urban air quality monitor in addition to improving the description of the total atmospheric composition, as the open-path system is stable and permanent.

  20. Planetary Probe Entry Atmosphere Estimation Using Synthetic Air Data System

    NASA Technical Reports Server (NTRS)

    Karlgaard, Chris; Schoenenberger, Mark

    2017-01-01

    This paper develops an atmospheric state estimator based on inertial acceleration and angular rate measurements combined with an assumed vehicle aerodynamic model. The approach utilizes the full navigation state of the vehicle (position, velocity, and attitude) to recast the vehicle aerodynamic model to be a function solely of the atmospheric state (density, pressure, and winds). Force and moment measurements are based on vehicle sensed accelerations and angular rates. These measurements are combined with an aerodynamic model and a Kalman-Schmidt filter to estimate the atmospheric conditions. The new method is applied to data from the Mars Science Laboratory mission, which landed the Curiosity rover on the surface of Mars in August 2012. The results of the new estimation algorithm are compared with results from a Flush Air Data Sensing algorithm based on onboard pressure measurements on the vehicle forebody. The comparison indicates that the new proposed estimation method provides estimates consistent with the air data measurements, without the use of pressure measurements. Implications for future missions such as the Mars 2020 entry capsule are described.

  1. Evaluation of upwelling infrared radiance from earth's atmosphere

    NASA Technical Reports Server (NTRS)

    Gupta, S. K.; Tiwari, S. N.

    1975-01-01

    Basic equations for calculating the upwelling atmospheric radiation are presented which account for various sources of radiation coming out at the top of the atmosphere. The theoretical formulation of the transmittance models (line-by-line and quasi-random band model) and the computational procedures used for the evaluation of the transmittance and radiance are discussed in detail. By employing the Lorentz line-by-line and quasi-random computer programs, model calculations were made to determine the upwelling radiance and signal change in the wave number interval of CO fundamental band. These results are useful in determining the effects of different interfering molecules, water vapor profiles, ground temperatures, and ground emittances on the upwelling radiance and signal change. This information is of vital importance in establishing the feasibility of measuring the concentrations of pollutants in the atmosphere from a gas filter correlation instrument flown on an aircraft or mounted on a satellite.

  2. An efficient routine for infrared radiative transfer in a cloudy atmosphere

    NASA Technical Reports Server (NTRS)

    Chou, M. D.; Kouvaris, L.

    1981-01-01

    A FORTRAN program that calculates the atmospheric cooling rate and infrared fluxes for partly cloudy atmospheres is documented. The IR fluxes in the water bands and the 9.6 and 15 micron bands are calculated at 15 levels ranging from 1.39 mb to the surface. The program is generalized to accept any arbitrary atmospheric temperature and humidity profiles and clouds as input and return the cooling rate and fluxes as output. Sample calculations for various atmospheric profiles and cloud situations are demonstrated.

  3. The portable atmospheric research interferometric spectrometer for the infrared, PARIS-IR

    NASA Astrophysics Data System (ADS)

    Fu, Dejian; Walker, Kaley A.; Sung, Keeyoon; Boone, Chris D.; Soucy, Marc-Andre; Bernath, Peter F.

    2007-01-01

    A new compact, portable Fourier transform spectrometer, called the Portable Atmospheric Research Interferometric Spectrometer for the Infrared (PARIS-IR), has been built for atmospheric remote sensing. The first comprehensive description of the configuration and performance of this instrument for ground-based and balloon-borne operation is provided. Sample atmospheric absorption spectra and representative results observed at the Waterloo Atmospheric Observatory (WAO) are given. The good agreement between PARIS IR, Brewer spectrophotometer, and ozonesonde measurements of the column density of ozone at mid-latitudes demonstrate the performance and the reliability of the instrument.

  4. Space-borne observation of methane from atmospheric infrared sounder version 6: validation and implications for data analysis

    NASA Astrophysics Data System (ADS)

    Xiong, X.; Weng, F.; Liu, Q.; Olsen, E.

    2015-08-01

    Atmospheric Methane (CH4) is generated as a standard product in recent version of the hyperspectral Atmospheric Infrared Sounder (AIRS-V6) aboard NASA's Aqua satellite at the NASA Goddard Earth Sciences Data and Information Services Center (NASA/GES/DISC). Significant improvements in AIRS-V6 was expected but without a thorough validation. This paper first introduced the improvements of CH4 retrieval in AIRS-V6 and some characterizations, then presented the results of validation using ~ 1000 aircraft profiles from several campaigns spread over a couple of years and in different regions. It was found the mean biases of AIRS CH4 at layers 343-441 and 441-575 hPa are -0.76 and -0.05 % and the RMS errors are 1.56 and 1.16 %, respectively. Further analysis demonstrates that the errors in the spring and in the high northern latitudes are larger than in other seasons or regions. The error is correlated with Degree of Freedoms (DOFs), particularly in the tropics or in the summer, and cloud amount, suggesting that the "observed" spatiotemporal variation of CH4 by AIRS is imbedded with some artificial impact from the retrieval sensitivity in addition to its variation in reality, so the variation of information content in the retrievals needs to be taken into account in data analysis of the retrieval products. Some additional filtering (i.e. rejection of profiles with obvious oscillation as well as those deviating greatly from the norm) for quality control is recommended for the users to better utilize AIRS-V6 CH4, and their implementation in the future versions of the AIRS retrieval algorithm is under consideration.

  5. Retrieval of atmospheric CH4 profiles from Fourier transform infrared data using dimension reduction and MCMC

    NASA Astrophysics Data System (ADS)

    Tukiainen, S.; Railo, J.; Laine, M.; Hakkarainen, J.; Kivi, R.; Heikkinen, P.; Chen, H.; Tamminen, J.

    2016-09-01

    We introduce an inversion method that uses dimension reduction for the retrieval of atmospheric methane (CH4) profiles. Uncertainty analysis is performed using the Markov chain Monte Carlo (MCMC) statistical estimation. These techniques are used to retrieve CH4 profiles from the ground-based spectral measurements by the Fourier Transform Spectrometer (FTS) instrument at Sodankylä (67.4°N, 26.6°E), Northern Finland. The Sodankylä FTS is part of the Total Carbon Column Observing Network (TCCON), a global network that observes solar spectra in near-infrared wavelengths. The high spectral resolution of the data provides approximately 3 degrees of freedom about the vertical structure of CH4 between around 0 and 40 km. We reduce the dimension of the inverse problem by using principal component analysis. Smooth and realistic profiles are sought by estimating three parameters for the profile shape. We use Bayesian framework with adaptive MCMC to better characterize the full posterior distribution of the solution and uncertainties related to the retrieval. The retrieved profiles are validated against in situ AirCore soundings which provide an accurate reference up to 20-30 km. The method is presented in a general form, so that it can easily be adapted for other applications, such as different trace gases or satellite-borne measurements where more accurate profile information and better analysis of the uncertainties would be highly valuable.

  6. Remote sensing of trace constituents from atmospheric infrared emission and absorption spectra

    NASA Technical Reports Server (NTRS)

    Barker, D. B.; Brooks, J. N.; Goldman, A.; Kosters, J. J.; Murcray, D. G.; Murcray, F. H.; Van Allen, J.; Williams, W. J.

    1976-01-01

    Atmospheric infrared emission and absorption spectra obtained from aircraft and balloon-borne spectrometers are presented. From such spectra, mixing ratio vs altitude profiles are derived for several minor constituents. Recent results for HNO3, CF2Cl2, CFCl3, and HF are presented. In addition, the feasibility of infrared detection of other trace constituents, such as HCl, HF, NH3, NO and SO2, against the rest of the atmospheric background is studied. From this study, made on a line-by-line basis for 'state of the art' airborne spectrometers, potential spectral features for detection of the trace constituents are isolated.

  7. An Instrument Concept for Atmospheric Infrared Sounding from Medium Earth Orbit

    NASA Technical Reports Server (NTRS)

    Pagano, Thomas S.; Baron, Richard l.

    2004-01-01

    Medium Earth Orbit (MEO) offers a unique vantage point for atmospheric infrared sounding. The orbit allows the entire globe to be covered each day with one satellite. The orbit is slow enough to allow multiple views of a single target to be made on each pass. this paper discusses the advantages in coverage and revisit rate from MEO for a particular concept for a Medium Earth Orbit Infrared Atmospheric Sounder (MIRIS). The requirements for this instrument in terms of spectral range, spatial resolution, field of view, and calibration are presented as well as the radiometric performance expectations.

  8. Impact of AIRS Thermodynamic Profiles on Precipitation Forecasts for Atmospheric River Cases Affecting the Western United States

    NASA Technical Reports Server (NTRS)

    Zavodsky, Bradley T.; Jedlovec, Gary J.; Blakenship, Clay B.; Wick, Gary A.; Neiman, Paul J.

    2013-01-01

    This project is a collaborative activity between the NASA Short-term Prediction Research and Transition (SPoRT) Center and the NOAA Hydrometeorology Testbed (HMT) to evaluate a SPoRT Advanced Infrared Sounding Radiometer (AIRS: Aumann et al. 2003) enhanced moisture analysis product. We test the impact of assimilating AIRS temperature and humidity profiles above clouds and in partly cloudy regions, using the three-dimensional variational Gridpoint Statistical Interpolation (GSI) data assimilation (DA) system (Developmental Testbed Center 2012) to produce a new analysis. Forecasts of the Weather Research and Forecasting (WRF) model initialized from the new analysis are compared to control forecasts without the additional AIRS data. We focus on some cases where atmospheric rivers caused heavy precipitation on the US West Coast. We verify the forecasts by comparison with dropsondes and the Cooperative Institute for Research in the Atmosphere (CIRA) Blended Total Precipitable Water product.

  9. [Atmospheric air pollution: a risk factor for COPD?].

    PubMed

    Allain, Y-M; Roche, N; Huchon, G

    2010-04-01

    Tobacco smoking is the leading cause of COPD worldwide but other risk factors have been recognized. Air pollution is one of them, but its exact role in the development of COPD is hard to demonstrate. Its physiological effects on lung function have only been studied since the nineties by long and tedious cohort studies. Difficulties arise from the heterogeneity of air pollution (gas and particles); thus, its respiratory effects have to be examined for every component separately, and in different populations. It is also necessary to analyse the effects of atmospheric pollution in the short and the long term, considering both its physiological, clinical and toxicological effects, from childhood to adulthood. These factors make it difficult to obtain statistically significant results. Nevertheless, most studies seem to point to a role of air pollution in the development of COPD via oxydative stress but further studies are needed to confirm the exact effect of each component of air pollution on the respiratory tract. These studies could lead to improved public health policies and results are awaited that would identify at-risk populations, decide appropriate preventive measures and propose documented thresholds in pollution exposure... thereby limiting the spread of COPD.

  10. Urban air pollution and atmospheric diffusion research in China

    NASA Astrophysics Data System (ADS)

    Ning, Datong; Whitney, Joseph B.; Yap, David

    1987-11-01

    Air pollution has become a serious problem in China as a result of that country's efforts in the last 30 years to become a great industrial power. The burning of coal, which currently provides over 70% of all China's energy needs, is a major source of air pollution. Because Chinese coal is high in sulfur and ash content and because most combustion devices in China have low efficiencies, SO2 and particulate emissions are a serious problem and are comparable to or exceed those found in many countries that are much more industrialized. Although most coal is burned in North China, acid precipitation is most severe in South China because of the lack of buffering loess dust found in the former region. The Chinese government has already taken major steps to mitigate air pollution, such as relocating polluting industries, supplying coal with lower sulfur content, using gas instead of coal for residential heating, and levying fines on industries that exceed pollution standards. Atmospheric environmental impact assessment (AEIA) is also required for all major new projects. This article describes three types of mathematical diffusion models and field and wind-tunnel experiments that are used in such assessments. The Chinese authorities believe that a range of technological, managerial, locational, and behavioral changes must be effected before the air of Chinese cities can be significantly improved.

  11. Quantitative infrared absorption cross sections of isoprene for atmospheric measurements

    SciTech Connect

    Brauer, Carolyn S.; Blake, Thomas A.; Guenther, Alex B.; Sharpe, Steven W.; Sams, Robert L.; Johnson, Timothy J.

    2014-11-19

    The OH- and O3- initiated oxidations of isoprene, which is one of the primary volatile organic compounds produced by vegetation, are a major source of atmospheric formaldehyde and other oxygenated organics, yet little quantitative IR data exists for isoprene. We thus report absorption coefficients and integrated band intensities for isoprene in the 600 - 6500 cm-1 region. The pressure-broadened (1 atmosphere N2) spectra were recorded at 278, 298 and 323 K in a 19.96 cm path length cell at 0.112 cm-1 resolution, using a Bruker 66V FTIR. Composite spectra are derived from a minimum of seven pressures at each temperature.

  12. The balance model of oxygen enrichment of atmospheric air

    NASA Astrophysics Data System (ADS)

    Popov, Alexander

    2013-04-01

    The study of turnover of carbon and oxygen is an important line of scientific investigation. This line takes on special significance in conditions of soil degradation, which leads to the excess content of carbon dioxide and, as result, decrease of oxygen in the atmosphere. The aim of this article is a statement the balance model of oxygen enrichment of atmospheric air (ratio O/C) depending on consumption and assimilation by plants of dissolved organic matter (DOM) and the value of the oxidation-reduction potential (Eh). Basis of model was the following: green vascular plants are facultative heterotrophic organisms with symbiotic digestion and nutrition. According to the trophology viewpoint, the plant consumption of organic compounds broadens greatly a notion about the plant nutrition and ways of its regulation. In particular, beside the main known cycle of carbon: plant - litter - humus - carbon dioxide - plant, there is the second carbon cycle (turnover of organic compounds): plant - litter - humus - DOM - plant. The biogeochemical meaning of consumption of organic compounds by plants is that plants build the structural and functional blocks of biological macromolecules in their bodies. It provides receiving of a certain "energy payoff" by plants, which leads to increase of plant biomass by both an inclusion of allochthonous organic molecules in plant tissues, and positive effect of organic compounds on plant metabolic processes. One more of powerful ecological consequence of a heterotrophic nutrition of green plants is oxygen enrichment of atmospheric air. As the organic molecules in the second biological cycle of carbon are built in plants without considerable chemical change, the atmospheric air is enriched on that amount of oxygen, which would be required on oxidation of the organic molecules absorbed by plants, in result. It was accepted that: plant-soil system was climax, the plant community was grassy, initial contents of carbon in phytomass was accepted

  13. An automated baseline correction protocol for infrared spectra of atmospheric aerosols collected on polytetrafluoroethylene (Teflon) filters

    NASA Astrophysics Data System (ADS)

    Kuzmiakova, Adele; Dillner, Ann M.; Takahama, Satoshi

    2016-06-01

    A growing body of research on statistical applications for characterization of atmospheric aerosol Fourier transform infrared (FT-IR) samples collected on polytetrafluoroethylene (PTFE) filters (e.g., Russell et al., 2011; Ruthenburg et al., 2014) and a rising interest in analyzing FT-IR samples collected by air quality monitoring networks call for an automated PTFE baseline correction solution. The existing polynomial technique (Takahama et al., 2013) is not scalable to a project with a large number of aerosol samples because it contains many parameters and requires expert intervention. Therefore, the question of how to develop an automated method for baseline correcting hundreds to thousands of ambient aerosol spectra given the variability in both environmental mixture composition and PTFE baselines remains. This study approaches the question by detailing the statistical protocol, which allows for the precise definition of analyte and background subregions, applies nonparametric smoothing splines to reproduce sample-specific PTFE variations, and integrates performance metrics from atmospheric aerosol and blank samples alike in the smoothing parameter selection. Referencing 794 atmospheric aerosol samples from seven Interagency Monitoring of PROtected Visual Environment (IMPROVE) sites collected during 2011, we start by identifying key FT-IR signal characteristics, such as non-negative absorbance or analyte segment transformation, to capture sample-specific transitions between background and analyte. While referring to qualitative properties of PTFE background, the goal of smoothing splines interpolation is to learn the baseline structure in the background region to predict the baseline structure in the analyte region. We then validate the model by comparing smoothing splines baseline-corrected spectra with uncorrected and polynomial baseline (PB)-corrected equivalents via three statistical applications: (1) clustering analysis, (2) functional group quantification

  14. Performance Expectations for Future Moderate Resolution Visible and Infrared Space Instruments Based on AIRS and MODIS In-Flight Experience

    NASA Technical Reports Server (NTRS)

    Pagano, Thomas S.; Broberg, Steven E.; Aumann, Hartmut H.; Baron, Richard L.

    2004-01-01

    Lessons learned from the Atmospheric Infrared Sounder (AIRS) and the Moderate Resolution Imaging Spectroradiometer (MODIS) projects highlight areas where further technology development is needed to address future land, ocean and atmospheric measurement needs. Although not established as requirements at this time, it is anticipated that scientists will expect improvements in the areas of spatial, spectral, radiometric, polarimetric, temporal and calibration performance for future sensors. This paper addresses each of these performance areas and provides lessons learned from MODIS and AIRS. We also present expectations in performance of the system based on information from NASA Instrument Incubator Program and industry reports. Tradeoffs are presented vs orbit altitude (LEO, ME0 and GEO) and provide a 'systems' perspective to future measurement concepts.

  15. Search for minor molecular compounds in Titan's atmosphere using infrared spectroscopy

    NASA Astrophysics Data System (ADS)

    Jolly, Antoine

    2016-06-01

    The Composite Infrared Spectrometer (CIRS) on-board Cassini has recorded spectra in the far and mid-infrared since 2004 with a spectral resolution of up to 0.5 cm-1. Improvement in the spectroscopic parameters has led to the detection of 13C isotopologues of HC3N (Jennings 2008) and C4H2 (Jolly 2010). The study on C2N2 opens the way to the detection of 15N isotopologues whose abundances could give some clues to understand the origin and the evolution of Titan's atmosphere (Fayt 2012). The higher accuracy of spectroscopic data used to model CIRS spectra enables the search for longer carbon chains on Titan such as HC5N, C6H2 and C4N2. Intensity measurements and a careful analysis of high resolution data has led to the first line lists for C4N2. No detection of this molecule was possible but a precise abundance upper limit of C4N2 in the gas phase in Titan's atmosphere could be determined (Jolly 2015). Photochemical models of Titan's atmosphere predict significant amount of allene (CH2CCH2) and butane (C4H10). Allene reacts chemically very similarly to its isomer propyne (CH3CCH) which is easily detected in the infrared. Butane is supposed to be almost as abundant as propane (C3H8) which has a large number of infrared signatures in the CIRS spectra of Titan's atmosphere. And yet, both hydrocarbons have not been detected on Titan so far. Low temperature spectra down to 150 K have been recorded in the mid and far infrared at the AILEs beamline of the SOLEIL synchrotron facility. Line lists or pseudo line lists have been compiled to search for the infrared signature of those molecules in the CIRS spectra of Titan's atmosphere.

  16. Cine: Line excitation by infrared fluorescence in cometary atmospheres

    NASA Astrophysics Data System (ADS)

    de Val-Borro, Miguel; Cordiner, Martin A.; Milam, Stefanie N.; Charnley, Steven B.

    2017-03-01

    CINE is a Python module for calculating infrared pumping efficiencies that can be applied to the most common molecules found in cometary comae such as water, hydrogen cyanide or methanol. Excitation by solar radiation of vibrational bands followed by radiative decay to the ground vibrational state is one of the main mechanisms for molecular excitation in comets. This code calculates the effective pumping rates for rotational levels in the ground vibrational state scaled by the heliocentric distance of the comet. Line transitions are queried from the latest version of the HITRAN spectroscopic repository using the astroquery affiliated package of astropy. Molecular data are obtained from the LAMDA database. These coefficients are useful for modeling rotational emission lines observed in cometary spectra at sub-millimeter wavelengths. Combined with computational methods to solve the radiative transfer equations based, e.g., on the Monte Carlo algorithm, this model can retrieve production rates and rotational temperatures from the observed emission spectrum.

  17. The One Atmosphere Glow Discharge in Air: Phenomenology and Applications

    NASA Astrophysics Data System (ADS)

    Ben Gadri, Rami; Sherman, Daniel M.; Chen, Zhiyu; Karakaya, Fuat; Reece Roth, J.

    1999-10-01

    The existence of an atmospheric pressure RF glow plasma with the characteristics of a classical low pressure DC glow discharge has been experimentally and theoretically demonstrated [1, 2]. At the UTK Plasma Sciences Laboratory, the One Atmosphere Uniform Glow Discharge Plasma (OAUGDP) in air has been applied to a wide range of plasma processing applications. The technology is simple, technically attractive, and suitable for online treatment of webs and 3-dimensional workpieces. A parallel plate reactor and a Remote Exposure Reactor (RER) have been developed for direct plasma immersion and remote exposure, respectively. The RER is based on generating active species capable of sterilization and surface treatment in a uniform surface layer of the OAUGDP on planar panels [3], and convecting the active species to a remote chamber where the workpiece is located. A related surface plasma has been developed for indoor air filtration systems. In addition, the surface plasma on flat panels modified the boundary layer in wind tunnel tests to produce electrohydrodynamic (EHD) flow effects that can be used to increase or decrease aerodynamic drag [3]. [1] Massines et al., J. Appl. Phys., Vol. 83, N 6, pp 2950-2957, Mar. 1998. [2] J. R. Roth, "Industrial Plasma Engineering" Vol. I: Principles. Inst. Phys. Pub., Bristol and philadelphia, ISBN 0-7503-0318-2, 1995. [3] Roth et al., AIAA Paper 98-0328, 36th AIAA Meeting, Reno NV, 1998, Jan. 12-15.

  18. Air Enquirer's multi-sensor boxes as a tool for High School Education and Atmospheric Research

    NASA Astrophysics Data System (ADS)

    Morguí, Josep-Anton; Font, Anna; Cañas, Lidia; Vázquez-García, Eusebi; Gini, Andrea; Corominas, Ariadna; Àgueda, Alba; Lobo, Agustin; Ferraz, Carlos; Nofuentes, Manel; Ulldemolins, Delmir; Roca, Alex; Kamnang, Armand; Grossi, Claudia; Curcoll, Roger; Batet, Oscar; Borràs, Silvia; Occhipinti, Paola; Rodó, Xavier

    2016-04-01

    An educational tool was designed with the aim of making more comprehensive the research done on Greenhouse Gases (GHGs) in the ClimaDat Spanish network of atmospheric observation stations (www.climadat.es). This tool is called Air Enquirer and it consist of a multi-sensor box. It is envisaged to build more than two hundred boxes to yield them to the Spanish High Schools through the Education department (www.educaixa.com) of the "Obra Social 'La Caixa'", who funds this research. The starting point for the development of the Air Enquirers was the experience at IC3 (www.ic3.cat) in the CarboSchools+ FP7 project (www.carboschools.cat, www.carboschools.eu). The Air Enquirer's multi-sensor box is based in Arduino's architecture and contains sensors for CO2, temperature, relative humidity, pressure, and both infrared and visible luminance. The Air Enquirer is designed for taking continuous measurements. Every Air Enquirer ensemble of measurements is used to convert values to standard units (water content in ppmv, and CO2 in ppmv_dry). These values are referred to a calibration made with Cavity Ring Down Spectrometry (Picarro®) under different temperature, pressure, humidity and CO2 concentrations. Multiple sets of Air Enquirers are intercalibrated for its use in parallel during the experiments. The different experiments proposed to the students will be outdoor (observational) or indoor (experimental, in the lab) focusing on understanding the biogeochemistry of GHGs in the ecosystems (mainly CO2), the exchange (flux) of gases, the organic matter production, respiration and decomposition processes, the influence of the anthropogenic activities on the gases (and particles) exchanges, and their interaction with the structure and composition of the atmosphere (temperature, water content, cooling and warming processes, radiative forcing, vertical gradients and horizontal patterns). In order to ensure Air Enquirers a high-profile research performance the experimental designs

  19. Inter-Comparison of Suomi NPP CrIS Radiances with AIRS and IASI toward Infrared Hyperspectral Benchmark Radiance Measurements

    NASA Astrophysics Data System (ADS)

    Wang, L.; Han, Y.; Chen, Y.; Jin, X.; Tremblay, D. A.

    2013-12-01

    The Cross-track Infrared Sounder (CrIS) on the newly-launched Suomi National Polar-orbiting Partnership (SNPP) and future Joint Polar Satellite System (JPSS) is a Fourier transform spectrometer that provides soundings of the atmosphere with 1305 spectral channels, over 3 wavelength ranges: LWIR (9.14 - 15.38 μm); MWIR (5.71 - 8.26 μm); and SWIR (3.92 - 4.64 μm). The SNPP CrIS, combined with the existed Atmospheric Infrared Sounder (AIRS) on NASA Aqua and Infrared Atmospheric Sounding Interferometer (IASI) on Metop-A and -B, will accumulate decades of hyperspectral spectral infrared measurements with high accuracy, which have potentials for climate monitoring and model assessments. In this presentation, we will 1) evaluate radiance consistency among AIRS, IASI, and CrIS, and 2) thus demonstrate that the CrIS SDR data from SNPP and JPSS can serve as a long-term reference benchmark for inter-calibration and climate-related study just like AIRS and IASI. In the first part of presentation, we will brief major postlaunch calibration and validation activities for SNPP CrIS performed by the NOAA STAR CrIS sensor data record (SDR) team, including the calibration parameter updates, instrument stability monitoring, and data processing quality assurance. Comprehensive assessments of the radiometric, spectral, geometric calibration of CrIS SDR will be presented. In addition, the preparation of CrIS SDR re-processing toward consistent Climate Data Records (CDRs) will be discussed. The purpose of this part is to provide a comprehensive overview of CrIS SDR data quality to the user community. In the second part, we will compare CrIS hyperspectral radiance measurements with the AIRS and IASI on Metop-A and -B to examine spectral and radiometric consistence and differences among three hyperspectral IR sounders. The SNPP CrIS, combined with AIRS and IASI, provide the first-ever inter-calibration opportunity because three hyperspectral IR sounders can observe the Earth and

  20. 20-micron transparency and atmospheric water vapor at the Wyoming Infrared Observatory

    NASA Technical Reports Server (NTRS)

    Grasdalen, G. L.; Gehrz, R. D.; Hackwell, J. A.; Freedman, R.

    1985-01-01

    The atmospheric transparency at 19.5 and 23 microns from the Wyoming Infrared Observatory over the past six years has been examined. It is found that the transparency is largely controlled by the season. Four months: June, July, August, and September have very poor 20-micron transparency. During the rest of the year the transparency is usually quite good at 19.5 microns and moderately good at 23 microns. Using rawinsonde data and theoretical calculations for the expected infrared transparency, the measures of 20-micron transparency were calibrated in terms of atmospheric water-vapor content. The water vapor over the Wyoming Infrared Observatory is found to compare favorably with that above other proposed or developed sites: Mauna Kea, Mount Graham, and Wheeler Peak.

  1. Measurements of trace constituents from atmospheric infrared emission and absorption spectra, a feasibility study

    NASA Technical Reports Server (NTRS)

    Goldman, A.; Williams, W. J.; Murcray, D. G.

    1974-01-01

    The feasibility of detecting eight trace constituents (CH4, HCl, HF, HNO3, NH3, NO, NO2 and SO2) against the rest of the atmospheric background at various altitudes from infrared emission and absorption atmospheric spectra was studied. Line-by-line calculations and observational data were used to establish features that can be observed in the atmospheric spectrum due to each trace constituent. Model calculations were made for experimental conditions which approximately represent state of the art emission and absorption spectrometers.

  2. Voigt line infrared atmospheric transmittance calculations by Fourier transform

    NASA Astrophysics Data System (ADS)

    Neuendorffer, A. C.

    1980-04-01

    The absorption coefficient space of an IR atmospheric path contains the linear superposition of many Voigt spectral lines. This paper discusses the practical application of Karp's method to the simulation of satellite transmittance and radiance observations by using fast Fourier transforms on the recursively generated Voigt transforms. Although the procedure is physically straightforward, it is nonetheless computationally demanding and suited primarily to narrow isolated Q-branch regions. Performing the calculation on a 2.4/cm wide 15-micron CO2 Q-branch region demonstrates that 4% of the total absorption takes place above 0.1 mb. This absorption is in the cold mesopause and results in a 1-2% radiation deficit with its inclusion in a satellite radiation calculation.

  3. An infrared radiation routine for use in numerical atmospheric models

    NASA Technical Reports Server (NTRS)

    Chow, M.-D.; Arking, A.

    1978-01-01

    Previous methods for calculating radiative fluxes due to water vapor and CO2 absorption bands are extended to take into consideration the entire water vapor and CO2 bands, including e-type absorption in the window region and the overlapping of different absorptions. Cooling rate profiles in the water vapor bands for a tropical atmosphere were computed by a detailed line-by-line method and by a far-wing approximation method, and the error of both methods is less than 0.2 C/day. Cooling rate profiles in the 15 micron band including overlapping of CO2 absorption with water vapor were calculated by a method in which flux transmittance is computed by means of a linear expansion and the multiplication rule, and maximum errors of 0.3 C/day were found in comparison with the exact line-by-line method.

  4. Effect of chlorofluoromethane infrared radiation on zonal atmospheric temperatures

    NASA Technical Reports Server (NTRS)

    Dickinson, R. E.; Donahue, T. M.; Liu, S. C.

    1978-01-01

    Estimates are made of changes in the atmospheric climate due to the radiative effects of 10 ppb of chlorofluoromethanes (CFM's). The estimates are derived on the basis of a 12-layer stratospheric general circulation model with a specified change of ocean temperature. Two tropical maxima in zonal average temperature change were observed: one in the upper troposphere and one centered at the tropopause. The temperature change exceeds the surface temperature change by a factor of at least two. If the 1975 CFM emission rate were to continue indefinitely, stratospheric water-vapor concentrations would increase by up to 60% due to CFM radiative effects. This would reduce ozone concentrations by an additional 4% of the natural ozone column.

  5. The important role of stellar atmosphere spectra for a consistent spectrophotometric calibration from the optical to the infrared wavelengths

    NASA Astrophysics Data System (ADS)

    Decin, L.

    2008-12-01

    We discuss the role of stellar atmosphere models in the spectrophotometric calibration pedigree. It is shown that stellar atmosphere spectra form an essential ingredient for spectrophotometric calibration. Compared with other (infrared) calibration networks currently available, the marcs grid is shown to provide the calibration community with spectral reference energy distributions of higher accuracy improving the spectrophotometric calibration of infrared spectrometers by more than 3%.

  6. Comparison of Methane Data Products from the TES and AIRS Infrared Sounders

    NASA Astrophysics Data System (ADS)

    Pagano, T. J.; Pagano, T. S.; Worden, J. R.

    2015-12-01

    Methane is the second most powerful greenhouse gas with a highly positive radiative forcing of 0.48 W/m2 (IPCC 2013). Global concentrations of methane have been steadily increasing since 2007 (Bruhwiler 2014), raising concerns about methane's impact on the future global climate. For about the last decade, the Tropospheric Emission Spectrometer (TES) on the Earth Observing System (EOS) Aura spacecraft has been detecting several trace gas species in the troposphere including methane. The goal of this study is to compare TES methane retrievals to that of the Atmospheric Infrared Sounder (AIRS) on the EOS Aqua spacecraft so that scientific investigations may be transferred from TES to AIRS. The two instruments fly in the afternoon constellation (A-Train), providing numerous coincident measurements for comparison. In addition, they also have a similar spectral range, (3.3 to 15.4 µm) for TES (Beer, 2006) and (3.7 to 15.4 µm) for AIRS (Chahine, 2006), making both instruments sensitive to the mid and upper troposphere. This makes them ideal candidates to compare methane data products. However, because AIRS spectral resolution is lower than that of the TES, there may be a difference in vertical sensitivity. In addition, the retrieval techniques and error characteristics are different for the two data sets. The current state of validation for these data products will be presented. To identify conditions in which the data sets agree and dis agree, we present global maps of methane concentrations from monthly level 3 (L3) data products. We also investigate the temporal stability between the two datasets by comparing global zonal averages derived from L3 over the last decade. Finally, we compare L2 retrieval profiles from representative granules in the tropical, mid-latitude and northern latitudes.

  7. FT-IR remote sensing of atmospheric species: Application to global change and air pollution

    SciTech Connect

    Vazquez, G.J.

    1995-12-31

    In this contribution, the author describes two applications of Fourier Transform Infrared Spectroscopy to the monitoring of atmospheric compounds. Firstly, the author reports FTIR solar spectroscopy measurements carried out at ground level at NCAR and on airplanes employing a spectrometer of 0.06 cm{sup -1} resolution. Sample atmospheric spectra and fitting examples are presented for key species relevant to stratospheric chemistry and global change: ozone (O{sub 3}), a chlorofluorocarbon (CF{sub 2}Cl{sub 2}), a greenhouse gas (N{sub 2}O), HCl, NO and HNO{sub 3}. Secondly, the author briefly describes urban air pollution measurements at an intersection with heavy traffic in Tucson, AZ. Two FTIR spectrometers of 1 cm{sup -1} resolution were employed to carry out long-path open-path measurements of the CO/CO{sub 2} ratio and SF{sub 6}. Two FEAT and two LPUV instruments were employed for ancillary measurements of CO, CO{sub 2}, NO, and aromatic hydrocarbons. Measurements of CO at two heights and a comparison of CO/CO{sub 2} ratios obtained by FEAT exhaust emission and FTIR ambient air measurements are reported.

  8. [Mid-infrared atmosphere radiation transfer analytic model and remote sensing images simulation].

    PubMed

    Yang, Gui-Jun; Liu, Qin-Huo; Liu, Qiang; Xiao, Qing; Gu, Xing-Fa; Huang, Wen-Jiang

    2009-03-01

    In order to establish a complete set of simulation system for high-resolution mid-infrared remote sensing and provide a powerful reference for spacecraft design and related works, the importance of atmospheric radiative transfer simulation in this system was considered, and a reasonable and high precision imaging numerical simulation method was expected. Taking into account the characteristics of MIR, including scattering and thermal emission, terms of atmospheric radiative transfer were decomposed based on radiative transfer principle, and images of top of atmosphere (TOA) were simulated according to MODTRAN4 and look-up table method. Besides, adjacency effect caused by atmospheric scattering of neighboring pixels radiation was considered, and an extended point spread function in mid-infrared was coupled with analytical model of atmospheric radiative transfer to simulate TOA images. Finally, a preliminary test and simulation results show that the simulation model has better accuracy. If parameters of observation geometry and atmosphere were given and the land surface temperature/emissivity was determined, the calculation of pixel-level atmospheric radiative transfer was to be achieved.

  9. Determination of atmospheric temperature, water vapor, and heating rates from mid- and far- infrared hyperspectral measurements

    NASA Astrophysics Data System (ADS)

    Feldman, D.; Liou, K.; Yung, Y.; Johnson, D.; Mlynczak, M.

    2007-12-01

    Comprehensive satellite-borne far-infrared (15-100 μm) hyperspectral measurements of the earth have not been implemented since the short-lived Infrared Interferometer Sounder-D (IRIS-D) instrument on the Nimbus-4 satellite ceased operation in 1971 due primarily to instrumentation limitations and mission cost considerations. Recently, the development of the Far Infrared Spectroscopy of the Troposphere (FIRST) instrument [Mlynczak et al, 2006], a balloon-borne FTS which records spectra from 5 to 200 μm, provides a test-bed for the development of space-based far-infrared measurements for climate change monitoring. A comparison of the retrieval capabilities of a notional space-based instrument of comparable performance to FIRST and the currently-operational mid-infrared instrument AIRS is presented. Temperature and water vapor retrievals are compared (in an orbital simulation framework) along with the relative ability of the retrievals from these two instruments to constrain the heating rate profile. Also, the skill with which the AIRS measurements can be used to extrapolate the cloud radiative effect into the far-infrared is explored. Finally, FIRST test flight spectra are presented in the framework of other A-Train measurements such as MODIS and CALIPSO, followed by a discussion of climate applications.

  10. Comprehensive analysis of Shuttle Orbiter leeside surface infrared imagery obtained during atmospheric entry

    NASA Technical Reports Server (NTRS)

    Myrick, D. L.; Throckmorton, D. A.

    1986-01-01

    The thermographic analysis techniques developed for processing of data from the Shuttle Infrared Leeside Temperature Sensing (SILTS) experiment are discussed. The SILTS experiment will obtain high-spatial-resolution infrared images of the leeside of the Space Shuttle Orbiter during atmospheric entry by means of a scanning infrared radiometer located atop the orbiter's vertical stabilizer. Comprehensive analysis of the SILTS thermography requires accurate consideration of all those factors (such as geometry of the observed surfaces, local surface emissivity, solar radiation, and other potential sources of image degradation) which may potentially affect the output of the infrared radiometer. An overview of the entire data processing procedure and brief descriptions of the data processing algorithms are presented.

  11. High resolution infrared spectroscopy: Some new approaches and applications to planetary atmospheres

    NASA Technical Reports Server (NTRS)

    Mumma, M. J.

    1978-01-01

    The principles of spectral line formation and of techniques for retrieval of atmospheric temperature and constituent profiles are discussed. Applications to the atmospheres of Earth, Mars, Venus, and Jupiter are illustrated by results obtained with Fourier transform and infrared heterodyne spectrometers at resolving powers (lambda/delta hyperon lambda of approximately 10,000 and approximately 10 to the seventh power), respectively, showing the high complementarity of spectroscopy at these two widely different resolving powers. The principles of heterodyne spectroscopy are presented and its applications to atmospheric probing and to laboratory spectroscopy are discussed. Direct absorption spectroscopy with tuneable semiconductor lasers is discussed in terms of precision frequency-and line strength-measurements, showing substantial advances in laboratory infrared spectroscopy.

  12. Infrared /IR/ spectroscopy in support of atmospheric measurements

    NASA Technical Reports Server (NTRS)

    Toth, R. A.

    1981-01-01

    In general, the data required for the more abundant species are: (1) linewidths as a function of temperature; (2) line strength measurements obtained at various temperatures when since quantum assignments for the lines are unknown the lower state energy levels are unknown; and (3) line strength measurements of the 'hot' bands and bands of the isotopic species. It is pointed out that an extensive list of line center frequencies and line strengths from 2400 to 3200 per cm of (CH4)4 has recently been added to the Air Force Geophysics Laboratory compilation. Since many of the lines in the list could not be assigned, the laboratory research required measurements of samples at various temperatures in order to experimentally determine the temperature dependence on the line strengths. The 'hot' band here refers to transitions arising from vibrational states other than the ground state. 'Hot' bands are usually near the parent band (arising from the ground state). Very few 'hot' bands are without parent bands.

  13. Optical Emission Studies of Copper Plasma Induced Using Infrared Transversely Excited Atmospheric (IR TEA) Carbon Dioxide Laser Pulses.

    PubMed

    Momcilovic, Milos; Kuzmanovic, Miroslav; Rankovic, Dragan; Ciganovic, Jovan; Stoiljkovic, Milovan; Savovic, Jelena; Trtica, Milan

    2015-04-01

    Spatially resolved, time-integrated optical emission spectroscopy was applied for investigation of copper plasma produced by a nanosecond infrared (IR) transversely excited atmospheric (TEA) CO2 laser, operating at 10.6 μm. The effect of surrounding air pressure, in the pressure range 0.1 to 1013 mbar, on plasma formation and its characteristics was investigated. A linear dependence of intensity threshold for plasma formation on logarithm of air pressure was found. Lowering of the air pressure reduces the extent of gas breakdown, enabling better laser-target coupling and thus increases ablation. Optimum air pressure for target plasma formation was 0.1 mbar. Under that pressure, the induced plasma consisted of two clearly distinguished and spatially separated regions. The maximum intensity of emission, with sharp and well-resolved spectral lines and negligibly low background emission, was obtained from a plasma zone 8 mm from the target surface. The estimated excitation temperature in this zone was around 7000 K. The favorable signal to background ratio obtained in this plasma region indicates possible analytical application of TEA CO2 laser produced copper plasma. Detection limits of trace elements present in the Cu sample were on the order of 10 ppm (parts per million). Time-resolved measurements of spatially selected plasma zones were used to find a correlation between the observed spatial position and time delay.

  14. ARIEL: Atmospheric Remote-Sensing Infrared Exoplanet Large-survey

    NASA Astrophysics Data System (ADS)

    Tinetti, Giovanna

    2015-11-01

    More than 1,000 extrasolar systems have been discovered, hosting nearly 2,000 exoplanets. Ongoing and planned ESA and NASA missions from space such as GAIA, Cheops, PLATO, K2 and TESS will increase the number of known systems to tens of thousands.Of all these exoplanets we know very little, i.e. their orbital data and, for some of these, their physical parameters such as their size and mass. In the past decade, pioneering results have been obtained using transit spectroscopy with Hubble, Spitzer and ground-based facilities, enabling the detection of a few of the most abundant ionic, atomic and molecular species and to constrain the planet’s thermal structure. Future general purpose facilities with large collecting areas will allow the acquisition of better exoplanet spectra, compared to the currently available, especially from fainter targets. A few tens of planets will be observed with JWST and E-ELT in great detail.A breakthrough in our understanding of planet formation and evolution mechanisms will only happen through the observation of the planetary bulk and atmospheric composition of a statistically large sample of planets. This requires conducting spectroscopic observations covering simultaneously a broad spectral region from the visible to the mid-IR. It also requires a dedicated space mission with the necessary photometric stability to perform these challenging measurements and sufficient agility to observe multiple times ~500 exoplanets over mission life-time.The ESA-M4 mission candidate ARIEL is designed to accomplish this goal and will provide a complete, statistically significant sample of gas-giants, Neptunes and super-Earths with temperatures hotter than 600K, as these types of planets will allow direct observation of their bulk properties, enabling us to constrain models of planet formation and evolution.The ARIEL consortium currently includes academic institutes and industry from eleven countries in Europe; the consortium is open and invites new

  15. Atmospheric Effects on Cosmic Ray Air Showers Observed with HAWC

    NASA Astrophysics Data System (ADS)

    Young, Steven

    2014-01-01

    The High Altitude Water Cherenkov Gamma Ray detector (HAWC), currently under construction on the Sierra Negra volcano near Puebla, Mexico, can be used to study solar physics with its scaler data acquisition system. Increases in the scaler rates are used to observe GeV cosmic rays from solar flares while decreases in the rates show the heliospheric disturbances associated with coronal mass ejections. However, weather conditions and height-dependent state variables such as pressure and temperature affect the production of extensive particle air showers that can be detected by the scaler system. To see if these atmospheric effects can be removed, we obtained local weather data from the Global Data Assimilation System (GDAS) and the local weather station at HAWC. The scaler pulse rates were then correlated to the pressure and temperature. We present data from a Forbush decrease observed by HAWC following a significant coronal mass ejection in April 2013, and describe our efforts to remove atmospheric variations from the scaler counts. This work was partially supported by the National Science Foundation’s REU program through NSF Award AST-1004881 to the University of Wisconsin-Madison.

  16. Atmospheric, Cloud, and Surface Parameters Retrieved from Satellite Ultra-spectral Infrared Sounder Measurements

    NASA Technical Reports Server (NTRS)

    Zhou, Daniel K.; Liu, Xu; Larar, Allen M.; Smith, William L.; Yang, Ping; Schluessel, Peter; Strow, Larrabee

    2007-01-01

    An advanced retrieval algorithm with a fast radiative transfer model, including cloud effects, is used for atmospheric profile and cloud parameter retrieval. This physical inversion scheme has been developed, dealing with cloudy as well as cloud-free radiance observed with ultraspectral infrared sounders, to simultaneously retrieve surface, atmospheric thermodynamic, and cloud microphysical parameters. A fast radiative transfer model, which applies to the clouded atmosphere, is used for atmospheric profile and cloud parameter retrieval. A one-dimensional (1-d) variational multivariable inversion solution is used to improve an iterative background state defined by an eigenvector-regression-retrieval. The solution is iterated in order to account for non-linearity in the 1-d variational solution. This retrieval algorithm is applied to the MetOp satellite Infrared Atmospheric Sounding Interferometer (IASI) launched on October 19, 2006. IASI possesses an ultra-spectral resolution of 0.25 cm(exp -1) and a spectral coverage from 645 to 2760 cm(exp -1). Preliminary retrievals of atmospheric soundings, surface properties, and cloud optical/microphysical properties with the IASI measurements are obtained and presented.

  17. Ground Based Observation of Isotopic Oxygen in the Martian Atmosphere Using Infrared Heterodyne Spectroscopy

    NASA Technical Reports Server (NTRS)

    Smith, R. L.; Kostiuk, T.; Livengood, T. A.; Fast, K. E.; Hewagama, T.; Delgado, J. D.; Sonnabend, G.

    2010-01-01

    Infrared heterodyne spectra of isotopic CO2 in the Martian atmosphere were obtained using the Goddard Heterodyne Instrument for Planetary Wind and Composition, HIPWAC, which was interfaced with the 3-meter telescope at the NASA Infrared Telescope Facility- Spectra were colle cted at a resolution of lambda/delta lambda=10(exp 7). Absorption fea tures of the CO2 isotopologues have been identified from which isotop ic ratios of oxygen have been determined. The isotopic ratios O-17/O -16 and O-18/O-16 in the Martian atmosphere can be related to Martian atmospheric evolution and can be compared to isotopic ratios of oxyg en in the Earth's atmosphere. Isotopic carbon and oxygen are importa nt constraints on any theory for the erosion of the Martian primordia l atmosphere and the interaction between the atmosphere and surface o r subsurface chemical reservoirs. This investigation explored the pr esent abundance of the stable isotopes of oxygen in Mars' atmospheric carbon dioxide by measuring rovibrational line absorption in isotop ic species of CO2 using groundbased infrared heterodyne spectroscopy in the vicinity of the 9.6 micron and 10.6 micron CO2 lasing bands. T he target transitions during this observation were O-18 C-12 O-16 as well as O-178 C-12 O-16 and O-16 C-113 O-16 at higher resolving power of lambda/delta lambda=10(exp 7) and with high signal-to-noise ratio (longer integration time) in order to fully characterize the absorpt ion line profiles. The fully-resolved lineshape of both the strong n ormal-isotope and the weak isotopic CO2 lines were measured simultane ously in a single spectrum.

  18. Radio Emission in Atmospheric Air Showers Measured by LOPES-30

    SciTech Connect

    Isar, P. G.

    2008-01-24

    When Ultra High Energy Cosmic Rays (UHECR) interact with particles in the Earth's atmosphere, they produce a shower of secondary particles propagating towards the ground. These relativistic particles emit synchrotron radiation in the radio frequency range when passing the Earth's magnetic field. The LOPES (LOFAR Prototype Station) experiment investigates the radio emission from these showers in detail and will pave the way to use this detection technique for large scale applications like in LOFAR (Low Frequency Array) and the Pierre Auger Observatory. The LOPES experiment is co-located and measures in coincidence with the air shower experiment KASCADE-Grande at Forschungszentrum Karlsruhe, Germany. LOPES has an absolute amplitude calibration array of 30 dipole antennas (LOPES-30). After one year of measurements of the single East-West polarization by all 30 antennas, recently, the LOPES-30 set-up was configured to perform dual-polarization measurements. Half of the antennas have been configured for measurements of the North-South polarization. Only by measuring at the same time both, the E-W and N-S polarization components of the radio emission, the geo-synchrotron effect as the dominant emission mechanism in air showers can be verified. The status of the measurements, including the absolute calibration procedure of the dual-polarized antennas as well as analysis of dual-polarized event examples are reported.

  19. Operational testing and applications of the AIRS FPA with infrared fisheye optics

    NASA Astrophysics Data System (ADS)

    Baxter, Christopher R.; Massie, Mark A.; Bartolac, Thomas J.

    2003-01-01

    Nova's development of the "Modular Infrared Imaging Applications Development System" (MIRIADS) produced a longwave infrared (LWIR) camera system that operated the "Adaptive Infrared Sensor" (AIRS) focal plane device produced by the Raytheon Infrared Operations (RIO) organization. A novel system architecture permitted the integration of an infrared fisheye lens system produced by Optics 1, Inc., which permitted a complete hemispherical field of view to be imaged onto the AIRS FPA. This paper will describe applications for this system as an extremely wide field-of-view IR sensor (early warning detection, fire detection, etc.), and will present test imagery collected with the system. This technology advancement has been the result of the coordinated effort of a variety of companies and government agencies. This presentation will highlight significant contributions of individuals and will indicate the effectiveness of the Small Business Innovative Research (SBIR) program in helping to advance this nation's technology base.

  20. Measurements of C02 Distribution in Saturn's Atmosphere by Cassini-Infrared Observations

    NASA Technical Reports Server (NTRS)

    Abbas, M. M.; LeClair, A.; Woodard, E.; Young, M.; Stanbro, M.; Flasar, M.

    2013-01-01

    The Fourier transform infrared spectrometer aboard the Cassini spacecraft, inserted in Saturn s orbit in July 2004, has been providing high resolution/high sensitivity infrared (IR) spectra of the Saturnian system. The measurements cover the spectral range of 10-1400/cm with variable spectral resolutions of 0.53 to 15/cm, exhibiting spectral features of a series of trace gases including CO2 and H2O. The observed spectra may be analyzed for retrieval of global P/T and gas density profiles of Saturn. The infrared measurements of Saturn by ISO(SWS) have indicated unexpected large abundances of CO2 in Saturn's atmosphere. The rigorous photochemical models of Saturn's atmosphere that have been developed indicate exogenic oxygen influx of icy dust grains that lead to the production of CO2. The distribution of CO2 in Saturn's atmosphere needs to be confirmed, and the nature of exogenic sources remains to be investigated. This paper presents comprehensive measurements of the CO2 distribution in Saturn's atmosphere by Cassini IR observations.

  1. Single band atmospheric correction tool for thermal infrared data: application to Landsat 7 ETM+

    NASA Astrophysics Data System (ADS)

    Galve, Joan Miquel; Coll, César; Sánchez, Juan Manuel; Valor, Enric; Niclòs, Raquel; Pérez-Planells, Lluís.; Doña, Carolina; Caselles, Vicente

    2016-10-01

    Atmospheric correction of Thermal Infrared (TIR) remote sensing data is a key process in order to obtain accurate land surface temperatures (LST). Single band atmospheric correction methods are used for sensors provided with a single TIR band. Which employs a radiative transfer model using atmospheric profiles over the study area as inputs to estimate the atmospheric transmittances and emitted radiances. Currently, TIR data from Landsat 5-TM, Landsat 7-ETM+ and Landsat 8-TIRS can be atmospherically corrected using the on-line Atmospheric Correction Parameter Calculator (ACPC, http://atmcorr.gsfc.nasa.gov). For specific geographical coordinates and observation time, the ACPC provides the atmospheric transmittance, and both upwelling and downwelling radiances, which are calculated from MODTRAN4 radiative transfer simulations with NCEP atmospheric profiles as inputs. Since the ACPC provides the atmospheric parameters for a single location, it does not account for their eventual variability within the full Landsat scene. The new Single Band Atmospheric Correction (SBAC) tool provides the geolocated atmospheric parameters for every pixel taking into account their altitude. SBAC defines a three-dimensional grid with 1°×1° latitude/longitude spatial resolution, corresponding to the location of NCEP profiles, and 13 altitudes from sea level to 5000 meters. These profiles are entered in MODTRAN5 to calculate the atmospheric parameters corresponding to a given pixel are obtained by weighted spatial interpolation in the horizontal dimensions and linear interpolation in the vertical dimension. In order to compare both SBAC and ACPC tools, we have compared with ground measurements the Landsat-7/ETM+ LST obtained using both tools over the Valencia ground validation site.

  2. Infrared image enhancement based on atmospheric scattering model and histogram equalization

    NASA Astrophysics Data System (ADS)

    Li, Yi; Zhang, Yunfeng; Geng, Aihui; Cao, Lihua; Chen, Juan

    2016-09-01

    Infrared images are fuzzy due to the special imaging technology of infrared sensor. In order to achieve contrast enhancement and gain clear edge details from a fuzzy infrared image, we propose an efficient enhancement method based on atmospheric scattering model and histogram equalization. The novel algorithm optimizes and improves the visual image haze remove method which combines the characteristics of the fuzzy infrared images. Firstly, an average filtering operation is presented to get the estimation of coarse transmission rate. Then we get the fuzzy free image through self-adaptive transmission rate calculated with the statistics information of original infrared image. Finally, to deal with low lighting problem of fuzzy free image, we propose a sectional plateau histogram equalization method which is capable of background suppression. Experimental results show that the performance and efficiency of the proposed algorithm are pleased, compared to four other algorithms in both subjective observation and objective quantitative evaluation. In addition, the proposed algorithm is competent to enhance infrared image for different applications under different circumstances.

  3. Determination of atmospheric moisture structure and infrared cooling rates from high resolution MAMS radiance data

    NASA Technical Reports Server (NTRS)

    Menzel, W. Paul; Moeller, Christopher C.; Smith, William L.

    1991-01-01

    This program has applied Multispectral Atmospheric Mapping Sensor (MAMS) high resolution data to the problem of monitoring atmospheric quantities of moisture and radiative flux at small spatial scales. MAMS, with 100-m horizontal resolution in its four infrared channels, was developed to study small scale atmospheric moisture and surface thermal variability, especially as related to the development of clouds, precipitation, and severe storms. High-resolution Interferometer Sounder (HIS) data has been used to develop a high spectral resolution retrieval algorithm for producing vertical profiles of atmospheric temperature and moisture. The results of this program are summarized and a list of publications resulting from this contract is presented. Selected publications are attached as an appendix.

  4. Finding Atmospheres of Extra-Solar Planets in High-Dispersion Near-Infrared Spectra

    NASA Astrophysics Data System (ADS)

    Käufl, Hans Ulrich

    In the wavelength regime of 950-5500nm CRIRES, ESO's Cryogenic Infrared Echelle Spectrograph will offer a spectral resolution λ/Δλ ≈ 10^5 in combination with a spatial resolution of 0.2^''. This makes it well suited to search for spectral signatures of atmospheres of extra-solar planets. Sensitivity estimates for the detection of the non-thermal OH glow in oxygen-bearing atmospheres are given. With the VLT such a search is still sensitivity limited, but a dedicated spectrograph at the projected ESO 100m OWL telescope could detect Earth-like planets at a distance of ≈ 5 parsec.

  5. Distribution of CO2 in Saturn's Atmosphere from Cassini/cirs Infrared Observations

    NASA Astrophysics Data System (ADS)

    Abbas, M. M.; LeClair, A.; Woodard, E.; Young, M.; Stanbro, M.; Flasar, F. M.; Kunde, V. G.; Achterberg, R. K.; Bjoraker, G.; Brasunas, J.; Jennings, D. E.; the Cassini/CIRS Team

    2013-10-01

    This paper focuses on the CO2 distribution in Saturn's atmosphere based on analysis of infrared spectral observations of Saturn made by the Composite Infrared Spectrometer aboard the Cassini spacecraft. The Cassini spacecraft was launched in 1997 October, inserted in Saturn's orbit in 2004 July, and has been successfully making infrared observations of Saturn, its rings, Titan, and other icy satellites during well-planned orbital tours. The infrared observations, made with a dual Fourier transform spectrometer in both nadir- and limb-viewing modes, cover spectral regions of 10-1400 cm-1, with the option of variable apodized spectral resolutions from 0.53 to 15 cm-1. An analysis of the observed spectra with well-developed radiative transfer models and spectral inversion techniques has the potential to provide knowledge of Saturn's thermal structure and composition with global distributions of a series of gases. In this paper, we present an analysis of a large observational data set for retrieval of Saturn's CO2 distribution utilizing spectral features of CO2 in the Q-branch of the ν2 band, and discuss its possible relationship to the influx of interstellar dust grains. With limited spectral regions available for analysis, due to low densities of CO2 and interference from other gases, the retrieved CO2 profile is obtained as a function of a model photochemical profile, with the retrieved values at atmospheric pressures in the region of ~1-10 mbar levels. The retrieved CO2 profile is found to be in good agreement with the model profile based on Infrared Space Observatory measurements with mixing ratios of ~4.9 × 10-10 at atmospheric pressures of ~1 mbar.

  6. DISTRIBUTION OF CO{sub 2} IN SATURN'S ATMOSPHERE FROM CASSINI/CIRS INFRARED OBSERVATIONS

    SciTech Connect

    Abbas, M. M.; LeClair, A.; Woodard, E.; Young, M.; Stanbro, M.; Flasar, F. M.; Achterberg, R. K.; Bjoraker, G.; Brasunas, J.; Jennings, D. E.; Kunde, V. G. E-mail: Andre.C.LeClair@nasa.gov E-mail: mcs0001@uah.edu E-mail: f.m.flasar@nasa.gov; Collaboration: and the Cassini /CIRS team

    2013-10-20

    This paper focuses on the CO{sub 2} distribution in Saturn's atmosphere based on analysis of infrared spectral observations of Saturn made by the Composite Infrared Spectrometer aboard the Cassini spacecraft. The Cassini spacecraft was launched in 1997 October, inserted in Saturn's orbit in 2004 July, and has been successfully making infrared observations of Saturn, its rings, Titan, and other icy satellites during well-planned orbital tours. The infrared observations, made with a dual Fourier transform spectrometer in both nadir- and limb-viewing modes, cover spectral regions of 10-1400 cm{sup –1}, with the option of variable apodized spectral resolutions from 0.53 to 15 cm{sup –1}. An analysis of the observed spectra with well-developed radiative transfer models and spectral inversion techniques has the potential to provide knowledge of Saturn's thermal structure and composition with global distributions of a series of gases. In this paper, we present an analysis of a large observational data set for retrieval of Saturn's CO{sub 2} distribution utilizing spectral features of CO{sub 2} in the Q-branch of the ν{sub 2} band, and discuss its possible relationship to the influx of interstellar dust grains. With limited spectral regions available for analysis, due to low densities of CO{sub 2} and interference from other gases, the retrieved CO{sub 2} profile is obtained as a function of a model photochemical profile, with the retrieved values at atmospheric pressures in the region of ∼1-10 mbar levels. The retrieved CO{sub 2} profile is found to be in good agreement with the model profile based on Infrared Space Observatory measurements with mixing ratios of ∼4.9 × 10{sup –10} at atmospheric pressures of ∼1 mbar.

  7. Measurement approach and design of the CubeSat Infrared Atmospheric Sounder (CIRAS)

    NASA Astrophysics Data System (ADS)

    Pagano, Thomas S.; Rider, David; Rud, Mayer; Ting, David; Yee, Karl

    2016-09-01

    The CubeSat Infrared Atmospheric Sounder (CIRAS) will measure upwelling infrared radiation of the Earth in the MWIR region of the spectrum from space on a CubeSat. The observed radiances have information of potential value to weather forecasting agencies and can be used to retrieve lower tropospheric temperature and water vapor globally for weather and climate science investigations. Multiple units can be flown to improve temporal coverage or in formation to provide new data products including 3D atmospheric motion vector winds. CIRAS incorporates key new instrument technologies including a 2D array of High Operating Temperature Barrier Infrared Detector (HOT-BIRD) material, selected for its high uniformity, low cost, low noise and higher operating temperatures than traditional materials. The detectors are hybridized to a commercial ROIC and commercial camera electronics. The second key technology is an MWIR Grating Spectrometer (MGS) designed to provide imaging spectroscopy for atmospheric sounding in a CubeSat volume. The MGS has no moving parts and includes an immersion grating to reduce the volume and reduce distortion. The third key technology is an infrared blackbody fabricated with black silicon to have very high emissivity in a flat plate construction. JPL will also develop the mechanical, electronic and thermal subsystems for CIRAS, while the spacecraft will be a commercially available CubeSat. The integrated system will be a complete 6U CubeSat capable of measuring temperature and water vapor profiles with good lower tropospheric sensitivity. The CIRAS is the first step towards the development of an Earth Observation Nanosatellite Infrared (EON-IR) capable of operational readiness to mitigate a potential loss of CrIS on JPSS or complement the current observing system with different orbit crossing times.

  8. Design of a Far-Infrared Spectrometer for Atmospheric Thermal Emission Measurements

    NASA Technical Reports Server (NTRS)

    Johnson, David G.

    2004-01-01

    Global measurements of far infrared emission from the upper troposphere are required to test models of cloud radiative forcing, water vapor continuum emission, and cooling rates. Spectra with adequate resolution can also be used for retrieving atmospheric temperature and humidity profiles, and yet there are few spectrally resolved measurements of outgoing longwave flux at wavelengths longer than 16 m. It has been difficult to make measurements in the far infrared due to the need for liquid-helium cooled detectors and large optics to achieve adequate sensitivity and bandwidth. We review design considerations for infrared Fourier transform spectrometers, including the dependence of system performance on basic system parameters, and discuss the prospects for achieving useful sensitivity from a satellite platform with a lightweight spectrometer using uncooled detectors.

  9. A new software tool for computing Earth's atmospheric transmission of near- and far-infrared radiation

    NASA Technical Reports Server (NTRS)

    Lord, Steven D.

    1992-01-01

    This report describes a new software tool, ATRAN, which computes the transmittance of Earth's atmosphere at near- and far-infrared wavelengths. We compare the capabilities of this program with others currently available and demonstrate its utility for observational data calibration and reduction. The program employs current water-vapor and ozone models to produce fast and accurate transmittance spectra for wavelengths ranging from 0.8 microns to 10 mm.

  10. High spectral resolution observations of Martian atmosphere in infrared - submillimeter range from ground-based instruments.

    NASA Astrophysics Data System (ADS)

    Nakagawa, Hiromu; Kasaba, Yasumasa; Aoki, Shohei; Murata, Isao; Maezawa, Hiroyuki; Okano, Shoichi; Sagawa, Hideo; Kasai, Yasuko

    2010-05-01

    With increased knowledge on our "neighbor" planets Mars and Venus, based on recent aggressive explorations by the US and Europe, our image on them is changing significantly. In particular, Mars is called ‘a frozen water planet'. It is almost certain that Mars once had duration with warm and wet climate [Head et al., 1999; Donahue, 1995; Parker et al., 1993]. It still conserves a large amount of water ice under the surface [Boynton et al., 2002; Mitrofanov et al., 2002; Feldman et al., 2002]. The question "Why and when did they diverge?" is essential for their environments which potentially could create and keep the life or not. Many molecules in planetary atmospheres show transitions in the mid infrared - submillimeter region. Thus, high-resolution spectroscopy in this region is significantly indispensable to study planetary atmospheres. We searched sulfur oxide (SO2 and SO) in the Martian atmosphere by the Atacama Submillimeter Telescope Experiment (ASTE). Sulfur oxide is one of the most evident species in terrestrial volcanic gases. Although it has not yet been detected at Mars, this detection can constraint the Martian crustal and volcanic activities. We observed northern winter of Mars on 26/Dec./2007 (Ls=8.1) in 346 GHz range with ~ 1h integration, and got the upper limit of the SO2 mixing ratio, 2 ppb. We concluded that the crustal or volcanic gas produced into the atmosphere is tenuous in northern winter [Nakagawa et al., 2009]. Infrared heterodyne spectroscopy has proven to be a powerful tool for astrophysical studies. To achieve highest spectral resolution and sensitivity as well as compact instrumentation heterodyne systems are advantageous over direct-detection methods. Our group in Tohoku University has developed own heterodyne system for infrared spectrometer for Earth's atmosphere over the past 20 years. The failure of earlier attempts to build tunable systems using tunable diode lasers was due mostly to insufficient laser power. Recently, quantum

  11. Study of short atmospheric pressure dc glow microdischarge in air

    NASA Astrophysics Data System (ADS)

    Kudryavtsev, Anatoly; Bogdanov, Eugene; Chirtsov, Alexander; Emelin, Sergey

    2011-10-01

    The results of experiments and simulations of short (without positive column) atmospheric pressure dc glow discharge in air are presented. We used metal steel electrodes with a gap of 5-100 microns. The experimental voltage-current characteristic's (VAC) have a constant or slightly increasing form at low gap. The most stable microdischarges were burning with a flat cathode and rounded anode, when the length of the discharge is automatically established near the minimum of the Paschen curve by changing their binding on the anode. In this case microdischarge was stable and it had growing VAC. For simulations we used 2D fluid model with kinetic description of electrons. We solved the balance equations for the vibrationally- and the electronically-excited states of a nitrogen and oxygen molecules; nitrogen and oxygen atoms; ozone molecule; and different nitrogen and oxygen ions with different plasmochemical reactions between them. Simulations predicted the main regions of the dc glow discharges including cathode and anode sheath and plasma of negative glow, Faraday dark space and transition region. Gas heating plays an important role in shaping the discharge profiles. The results of experiments and simulations of short (without positive column) atmospheric pressure dc glow discharge in air are presented. We used metal steel electrodes with a gap of 5-100 microns. The experimental voltage-current characteristic's (VAC) have a constant or slightly increasing form at low gap. The most stable microdischarges were burning with a flat cathode and rounded anode, when the length of the discharge is automatically established near the minimum of the Paschen curve by changing their binding on the anode. In this case microdischarge was stable and it had growing VAC. For simulations we used 2D fluid model with kinetic description of electrons. We solved the balance equations for the vibrationally- and the electronically-excited states of a nitrogen and oxygen molecules; nitrogen

  12. Estimation of absolute water surface temperature based on atmospherically corrected thermal infrared multispectral scanner digital data

    NASA Technical Reports Server (NTRS)

    Anderson, James E.

    1986-01-01

    Airborne remote sensing systems, as well as those on board Earth orbiting satellites, sample electromagnetic energy in discrete wavelength regions and convert the total energy sampled into data suitable for processing by digital computers. In general, however, the total amount of energy reaching a sensor system located at some distance from the target is composed not only of target related energy, but, in addition, contains a contribution originating from the atmosphere itself. Thus, some method must be devised for removing or at least minimizing the effects of the atmosphere. The LOWTRAN-6 Program was designed to estimate atmospheric transmittance and radiance for a given atmospheric path at moderate spectral resolution over an operational wavelength region from 0.25 to 28.5 microns. In order to compute the Thermal Infrared Multispectral Scanner (TIMS) digital values which were recorded in the absence of the atmosphere, the parameters derived from LOWTRAN-6 are used in a correction equation. The TIMS data were collected at 1:00 a.m. local time on November 21, 1983, over a recirculating cooling pond for a power plant in southeastern Mississippi. The TIMS data were analyzed before and after atmospheric corrections were applied using a band ratioing model to compute the absolute surface temperature of various points on the power plant cooling pond. The summarized results clearly demonstrate the desirability of applying atmospheric corrections.

  13. Atmospheric Visual and Infrared Transmission Deduced from Surface Weather Observations: Weather and Warplanes. V1

    DTIC Science & Technology

    1976-10-01

    continental dust, forest fire smoke, industrial effluents, etc.), such as different "dry" size distributions, different growth rates with relative humidity...Airborne Measure- ments of Optica Atmospheric Properties in Southern Illinois, Visibility Laboratory, UCSD, San Diego (AFCRL-TR-73-0422, Air Force

  14. Urban Climate Effects on Air Pollution and Atmospheric Chemistry

    NASA Astrophysics Data System (ADS)

    Rasoul, Tara; Bloss, William; Pope, Francis

    2016-04-01

    Tropospheric ozone, adversely affects the environment and human health. The presence of chlorine nitrate (ClNO2) in the troposphere can enhance ozone (O3) formation as it undergoes photolysis, releasing chlorine reactive atoms (Cl) and nitrogen dioxide (NO2), both of which enhance tropospheric ozone formation. The importance of new sources of tropospheric ClNO2 via heterogeneous processes has recently been highlighted. This study employed a box model, using the Master Chemical Mechanism (MCM version 3.2) to assess the effect of ClNO2 on air quality in urban areas within the UK. The model updated to include ClNO2 production, photolysis, a comprehensive parameterisation of dinitrogen pentoxide (N2O5) uptake, and ClNO2 production calculated from bulk aerosol composition. The model simulation revealed the presence of ClNO2 enhances the formation of NO2, organic peroxy radical (CH3O2), O3, and hydroxyl radicals (OH) when compared with simulations excluding ClNO2. In addition, the study examined the effect of temperature variation upon ClNO2 formation. The response of ClNO2 to temperature was analysed to identify the underlying drivers, of particular importance when assessing the response of atmospheric chemistry processes under potential future climates.

  15. Thermogravimetric analysis of rice husks in an air atmosphere

    SciTech Connect

    Mansaray, K.G.; Ghaly, A.E.

    1998-08-01

    In rice-producing countries, large amounts of rice husks are generated as waste material for which there is no ready use and in some cases may have a negative value because of the cost of disposal. Most of these countries depend on fossil fuels for their energy uses, and rice husk can be used to supplement such energy sources using thermochemical conversion processes. However, efficient operation of thermochemical conversion systems requires a thorough understanding of the influence of the influence of the composition and thermal properties of rice husks on their behavior during the conversion process. In this study, the thermal behavior of four rice husk varieties (Lemont, ROK 14, CP 4, and Pa Potho) was examined at three heating rates (10, 20, and 50 C/min) in stationary air atmosphere. The thermal degradation rate in active and passive pyrolysis zones, the initial degradation temperature, and the residual weight at 600 C were determined. Increasing the heating rate increased both the thermal degradation rate and the residual weight and decreased the initial degradation temperature. The higher the cellulosic content of the rice husk, the higher the thermal degradation rate and the initial degradation temperature. Also, higher ash content in the rice husk resulted in higher residual weight at 600 C.

  16. Atmospheric water mapping with the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS), Mountain Pass, California

    NASA Technical Reports Server (NTRS)

    Conel, James E.; Green, Robert O.; Carrere, Veronique; Margolis, Jack S.; Alley, Ronald E.; Vane, Gregg; Bruegge, Carol J.; Gary, Bruce L.

    1988-01-01

    Observations are given of the spatial variation of atmospheric precipitable water using the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) over a desert area in eastern California, derived using a band ratio method and the 940 nm atmospheric water band and 870 nm continuum radiances. The ratios yield total path water from curves of growth supplied by the LOWTRAN 7 atmospheric model. An independent validation of the AVIRIS-derived column abundance at a point is supplied by a spectral hygrometer calibrated with respect to radiosonde observations. Water values conform to topography and fall off with surface elevation. The edge of the water vapor boundary layer defined by topography is thought to have been recovered. The ratio method yields column abundance estimates of good precision and high spatial resolution.

  17. In situ sensing of the middle atmosphere with balloonborne near-infrared laser diodes.

    PubMed

    Durry, G; Amarouche, N; Zéninari, V; Parvitte, B; Lebarbu, T; Ovarlez, J

    2004-12-01

    Since 1997, two near-infrared laser diode sensors have been developed with the support of the CNES, the French space agency, to provide in situ data of H(2)O, CH(4) and CO(2) in the middle atmosphere. The realized instruments were flown from stratospheric balloons within the framework of European campaigns for the study of stratospheric ozone and water vapor and were involved in the validation of the ODIN and ENVISAT satellites. In this paper, we describe the developed laser probing technique, we report atmospheric measurements and finally we discuss future perspectives, particularly the in situ laser sensing of the lower atmosphere of Mars and the implication of the laser hygrometers in balloon campaigns at mid-latitudes and tropical regions to investigate the sources and sinks of stratospheric H(2)O.

  18. Analysis of the radiative budget of Venus atmosphere based on infrared Net Exchange Rate formalism

    NASA Astrophysics Data System (ADS)

    Lebonnois, S.; Eymet, V.; Lee, C.; Vatant d'Ollone, J.

    2015-10-01

    The thick cloud cover present in the atmosphere of Venus between roughly 47 and 70 km of altitude plays a crucial role in the radiative balance of this system,by reflecting more than 75 % of the incoming solar flux back to space, absorbing half of the remaining flux, and being also optically thick over most of the infrared spectral range. The temperature profile of the atmosphere of Venus is characterized by a very hot troposphere from the surface (˜735 K) to roughly 60 km altitude, in the middle clouds. The strong greenhouse effect is provided by the 92 bars of CO2 that is the main constituent of the atmosphere and by the thick cloud layer.

  19. Impact of background and atmospheric variability on infrared hyperspectral chemical detection sensitivity

    SciTech Connect

    Sheen, David M.; Gallagher, Neal B.; Sharpe, Steven W.; Anderson, Kevin K.; Schultz, John F.; Shen, Sylvia S.; Lewis, Paul E.

    2003-04-15

    Chemical detection using infrared (IR) hyperspectral imaging systems is often limited by the effects of variability of the scene background emissivity spectra and temperature. Additionally, the atmospheric up-welling and down-welling radiance and transmittance are difficult to estimate from the hyperspectral image data, and may vary across the image. In combination, these background variability effects are referred to as''clutter.'' A study has been undertaken at Pacific Northwest National Laboratory (PNNL) to determine the relative impact of atmospheric variability and background variability on the detection of trace chemical vapors. This study has analyzed Atmospheric Emitted Radiance Interferometer (AERI) data to estimate fluctuations in atmospheric constituents. To allow separation of the effects of background and atmospheric variability, hyperspectral data was synthesized using large sets of simulated atmospheric spectra, measured background emissivity spectra, and measured high-resolution gas absorbance spectra. The atmosphere was simulated using FASCODE in which the constituent gas concentrations and temperatures were varied. These spectral sets were combined synthetically using a physics model to realize a statistical synthetic scene with a plume present in a portion of the image. Noise was added to the image with the level determined by a numerical model of the hyperspectral imaging instrument. The chemical detection performance was determined by applying a matched-filter estimator to both the on-plume and off-plume regions. The detected levels in the off-plume region were then used to determine the noise equivalent concentration pathlength (NECL), which is a measure of the chemical detection sensitivity. The NECL was estimated for numerous gases and for a variety of background and atmospheric conditions to determine the relative impact of instrument noise, background variability, and atmospheric variability.

  20. Determination of nitrogen dioxide in ambient air employing diffuse reflectance Fourier transform infrared spectroscopy

    NASA Astrophysics Data System (ADS)

    Verma, Santosh Kumar; Deb, Manas Kanti; Verma, Devsharan

    2008-10-01

    This paper presents the development of a simple and precise analytical method for the determination of nitrogen dioxide in ambient air. In this method nitrogen dioxide is determined in the form of nitrite. The determination of nitrogen dioxide needs no reagents except for a solution of sodium hydroxide mixed with sodium arsenite (NaOH-Na 2As 2O 3) which is used as an absorbing reagent for trapping the nitrogen dioxide from the atmosphere in the form of nitrite, i.e., a prior analysis step. The determination of submicrogram levels of nitrogen dioxide is based on the selection of a strong and sharp quantitative analytical peak at 1380 cm - 1 using diffuse reflectance infrared spectroscopy (DRS-FTIR). The limit of detection (LOD) and the limit of quantification of the method are found to be 0.008 μg g - 1 NO 2- and 0.05 μg g - 1 NO 2-, respectively. The precision in terms of standard deviation and relative standard deviation value at a level of 2 μg NO 2- / 0.1 g KBr for n = 10 is found to be 0.036 μg NO 2- and 1.8%, respectively. The relative standard deviation ( n = 10) for the determination of nitrogen dioxide in ambient air was observed to be in the range 2.6-3.8%. The method proposed is time-saving and eliminates the slow and cumbersome steps of pH maintenance of the reaction mixture and color formation of the EPA recommended spectrophotometric and other methods for quantitative determination of nitrogen dioxide.

  1. bdGas carburizing of steel with furnace atmospheres formed in situ from methane and air and from butane and air

    NASA Astrophysics Data System (ADS)

    Stickels, C. A.; Mack, C. M.; Pieprzak, J. A.

    1982-12-01

    Carburizing experiments were conducted at 927°C (1700°F) and 843°C (1550°F) using furnace atmospheres formed from methane and air and from butane and air introduced directly into the carburizing furnace. Gas flow rates were low to promote equilibration of the reaction products within the furnace. The air flow rate was held constant while the methane or butane flow was automatically regulated to maintain a constant oxygen potential, as measured by a zirconia oxygen sensor, within the furnace. In comparing the results of these experiments with earlier results obtained using propane and air, several differences were noted: (a) The methane content of the furnace atmosphere, measured by infrared analysis, was about twice as great when methane was the feed gas rather than propane or butane. This was true despite the fact that the mean residence time of the gas within the furnace was greater in the methane experiments. Methane appears to be less effective than propane or butane in reducing the CO2 and H2O contents to the levels required for carburizing. (b) There was a greater tendency for the CO content of the furnace atmosphere to decrease at high carbon potentials when methane is used instead of propane or butane. The decrease in CO content is due to hydrogen dilution caused by sooting in the furnace vestibule. These differences in behavior make propane or butane better suited than methane for in situ generation of carburizing atmospheres. However, there is no difference in the amount of carburizing occurring at a specified carbon potential when methane, propane, or butane are used as the feed gas in this process.

  2. Analysis of the radiative budget of the Venusian atmosphere based on infrared Net Exchange Rate formalism

    NASA Astrophysics Data System (ADS)

    Lebonnois, Sébastien; Eymet, Vincent; Lee, Christopher; Vatant d'Ollone, Jan

    2015-06-01

    A detailed one-dimensional analysis of the energy balance in Venus atmosphere is proposed in this work, based on the Net Exchange Rate formalism that allows the identification in each altitude region of the dominant energy exchanges controlling the temperature. Well-known parameters that control the temperature profile are the solar flux deposition and the cloud particle distribution. Balance between solar heating and infrared energy exchanges is analyzed for each region: upper atmosphere (from cloud top to 100 km), upper cloud, middle cloud, cloud base, and deep atmosphere (cloud base to surface). The energy accumulated below the clouds is transferred to the cloud base through infrared windows, mostly at 3-4 μm and 5-7 μm. The continuum opacity in these spectral regions is not well known for the hot temperatures and large pressures of Venus's deep atmosphere but strongly affects the temperature profile from cloud base to surface. From cloud base, upward transport of energy goes through convection and short-range radiative exchanges up to the middle cloud where the atmosphere is thin enough in the 20-30 μm window to cool directly to space. Total opacity in this spectral window between the 15 μm CO2 band and the CO2 collision-induced absorption has a strong impact on the temperature in the cloud convective layer. Improving our knowledge of the gas opacities in these different windows through new laboratory measurements or ab initio computations, as well as improving the constraints on cloud opacities would help to separate gas and cloud contributions and secure a better understanding of Venus's atmosphere energy balance.

  3. The Impact of Physical Atmosphere on Air Quality and the Utility of Satellite Observations in Air Quality Models

    NASA Astrophysics Data System (ADS)

    Pour Biazar, A.; McNider, R. T.; Park, Y. H.; Doty, K.; Khan, M. N.; Dornblaser, B.

    2012-12-01

    Physical atmosphere significantly impacts air quality as it regulates production, accumulation, and transport of atmospheric pollutants. Consequently, air quality simulations are greatly influenced by the uncertainties that emanates from the simulation of physical atmosphere. Since air quality model predictions are increasingly being used in health studies, regulatory applications, and policy making, reducing such uncertainties in model simulations is of outmost importance. This paper describes some of the critical aspects of physical atmosphere affecting air quality models that can be improved by utilizing satellite observations. Retrievals of skin temperature, surface albedo, surface insolation, cloud top temperature and cloud reflectance obtained from the Geostationary Operational Environmental Satellite (GOES) by NASA/MSFC GOES Product Generation System (GPGS) have been utilized to improve the air quality simulations used in the State Implementation Plan (SIP) attainment demonstrations. Satellite observations of ground temperature are used to recover surface moisture and heat capacity and thereby improving model simulation of air temperature. Observations of clouds are utilized to improve the photochemical reaction rates within the photochemical model and also to assimilate clouds in the meteorological model. These techniques have been implemented and tested in some of the widely used air quality decision modeling systems such as MM5/WRF/CMAQ/CAMx. The results from these activities show significant improvements in air quality simulations.

  4. Atmospheric ultraviolet and red-infrared flashes from Universitetsky-Tatiana-2 satellite data

    NASA Astrophysics Data System (ADS)

    Vedenkin, N. N.; Garipov, G. K.; Klimov, P. A.; Klimenko, V. V.; Mareev, E. A.; Martinez, O.; Morozenko, V. S.; Park, I.; Panasyuk, M. I.; Ponce, E.; Salazar, H.; Tulupov, V. I.; Khrenov, B. A.; Yashin, I. V.

    2011-11-01

    Millisecond ultraviolet (240-400 nm) and red-infrared (610-800 nm) flashes were detected in the nighttime atmosphere with the scientific payload installed onboard the Universitetsky-Tatiana-2 micro-satellite. Flashes with various numbers of photons, from 1020 to 1026, were detected within the atmospheric area 300 km in diameter observed by the detector. The flashes differ in duration and temporal profile: from single short flashes ˜1 ms in duration to flashes with a complex profile more than 100 ms in duration. Different global geographic distributions are observed for flashes with different numbers of photons. Flashes with fewer than 1022 photons are distributed uniformly over the Earth's map. Flashes with more than 1022 photons are concentrated near the equator and above the continents. Series of flashes were observed in one turn of the satellite when flying not only over thunderstorm regions but also over cloudless ones. The flash number distribution has been derived from the ratio of the numbers of red-infrared and ultraviolet photons. As applied to discharges in the upper atmosphere, whose glow is dominated by the emission in the first and second positive systems of molecular nitrogen bands (1PN2 and 2PN2), this distribution is equivalent to the flash altitude distribution in the atmosphere. The observed ratio of the numbers of photons in red-infrared and ultraviolet flashes agrees with the calculated one for electric discharges at altitudes higher than 50 km. In-orbit measurements of the charged particle flux (with a threshold energy for electrons of 1 MeV) provide no evidence for a synchronous occurrence of an ultraviolet flash and a burst in the particle flux in the orbit.

  5. Atmospheric ultraviolet and red-infrared flashes from Universitetsky-Tatiana-2 satellite data

    SciTech Connect

    Vedenkin, N. N.; Garipov, G. K.; Klimov, P. A.; Klimenko, V. V.; Mareev, E. A.; Martinez, O.; Morozenko, V. S.; Park, I.; Panasyuk, M. I.; Ponce, E.; Salazar, H.; Tulupov, V. I.; Khrenov, B. A.; Yashin, I. V.

    2011-11-15

    Millisecond ultraviolet (240-400 nm) and red-infrared (610-800 nm) flashes were detected in the nighttime atmosphere with the scientific payload installed onboard the Universitetsky-Tatiana-2 micro-satellite. Flashes with various numbers of photons, from 10{sup 20} to 10{sup 26}, were detected within the atmospheric area 300 km in diameter observed by the detector. The flashes differ in duration and temporal profile: from single short flashes {approx}1 ms in duration to flashes with a complex profile more than 100 ms in duration. Different global geographic distributions are observed for flashes with different numbers of photons. Flashes with fewer than 10{sup 22} photons are distributed uniformly over the Earth's map. Flashes with more than 10{sup 22} photons are concentrated near the equator and above the continents. Series of flashes were observed in one turn of the satellite when flying not only over thunderstorm regions but also over cloudless ones. The flash number distribution has been derived from the ratio of the numbers of red-infrared and ultraviolet photons. As applied to discharges in the upper atmosphere, whose glow is dominated by the emission in the first and second positive systems of molecular nitrogen bands (1PN{sub 2} and 2PN{sub 2}), this distribution is equivalent to the flash altitude distribution in the atmosphere. The observed ratio of the numbers of photons in red-infrared and ultraviolet flashes agrees with the calculated one for electric discharges at altitudes higher than 50 km. In-orbit measurements of the charged particle flux (with a threshold energy for electrons of 1 MeV) provide no evidence for a synchronous occurrence of an ultraviolet flash and a burst in the particle flux in the orbit.

  6. A synthetic data set of high-spectral-resolution infrared spectra for the Arctic atmosphere

    NASA Astrophysics Data System (ADS)

    Cox, Christopher J.; Rowe, Penny M.; Neshyba, Steven P.; Walden, Von P.

    2016-05-01

    Cloud microphysical and macrophysical properties are critical for understanding the role of clouds in climate. These properties are commonly retrieved from ground-based and satellite-based infrared remote sensing instruments. However, retrieval uncertainties are difficult to quantify without a standard for comparison. This is particularly true over the polar regions, where surface-based data for a cloud climatology are sparse, yet clouds represent a major source of uncertainty in weather and climate models. We describe a synthetic high-spectral-resolution infrared data set that is designed to facilitate validation and development of cloud retrieval algorithms for surface- and satellite-based remote sensing instruments. Since the data set is calculated using pre-defined cloudy atmospheres, the properties of the cloud and atmospheric state are known a priori. The atmospheric state used for the simulations is drawn from radiosonde measurements made at the North Slope of Alaska (NSA) Atmospheric Radiation Measurement (ARM) site at Barrow, Alaska (71.325° N, 156.615° W), a location that is generally representative of the western Arctic. The cloud properties for each simulation are selected from statistical distributions derived from past field measurements. Upwelling (at 60 km) and downwelling (at the surface) infrared spectra are simulated for 260 cloudy cases from 50 to 3000 cm-1 (3.3 to 200 µm) at monochromatic (line-by-line) resolution at a spacing of ˜ 0.01 cm-1 using the Line-by-line Radiative Transfer Model (LBLRTM) and the discrete-ordinate-method radiative transfer code (DISORT). These spectra are freely available for interested researchers from the NSF Arctic Data Center data repository (doi:10.5065/D61J97TT).

  7. Performance of greenhouse gas profiling by infrared-laser and microwave occultation in cloudy air

    NASA Astrophysics Data System (ADS)

    Proschek, V.; Kirchengast, G.; Emde, C.; Schweitzer, S.

    2012-12-01

    ACCURATE is a proposed future satellite mission enabling simultaneous measurements of greenhouse gases (GHGs), wind and thermodynamic variables from Low Earth Orbit (LEO). The measurement principle is a combination of LEO-LEO infrared-laser occultation (LIO) and microwave occultation (LMO), the LMIO method, where the LIO signals are very sensitive to clouds. The GHG retrieval will therefore be strongly influenced by clouds in parts of the troposphere. The IR-laser signals, at wavelengths within 2--2.5μ m, are chosen to measure six GHGs (H2O, CO2, CH4, N2O, O3, CO; incl.~key isotopes 13CO2, C18OO, HDO). The LMO signals enable to co-measure the thermodynamic variables. In this presentation we introduce the algorithm to retrieve GHG profiles under cloudy-air conditions by using quasi-realistic forward simulations, including also influence of Rayleigh scattering, scintillations and aerosols. Data from CALIPSO--Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations--with highest vertical resolution of about 60 m and horizontal resolution of about 330 m were used for simulation of clouds. The IR-laser signals consist for each GHG of a GHG-sensitive and a close-by reference signal. The key process, ``differencing'' of these two signals, removes the atmospheric ``broadband'' effects, resulting in a pure GHG transmission profile. Very thin ice clouds, like sub-visible cirrus, are fairly transparent to the IR-laser signals, thicker and liquid water clouds block the signals. The reference signal is used to produce a cloud layering profile from zero to blocking clouds and is smoothed in a preprocess to suppress scintillations. Sufficiently small gaps, of width <2 km in the cloud layering profile, are found to enable a decent retrieval of entire GHG profiles over the UTLS under broken cloudiness and are therefore bridged by interpolation. Otherwise in case of essentially continuous cloudiness the profiles are found to terminate at cloud top level. The accuracy of

  8. Herbig stars' near-infrared excess: An origin in the protostellar disk's magnetically supported atmosphere

    SciTech Connect

    Turner, N. J.; Benisty, M.; Dullemond, C. P.; Hirose, S.

    2014-01-01

    Young stars with masses 2-8 times solar, the Herbig Ae and Be stars, often show a near-infrared excess too large to explain with a hydrostatically supported circumstellar disk of gas and dust. At the same time, the accretion flow carrying the circumstellar gas to the star is thought to be driven by magnetorotational turbulence, which, according to numerical MHD modeling, yields an extended low-density atmosphere supported by the magnetic fields. We demonstrate that the base of the atmosphere can be optically thick to the starlight and that the parts lying near 1 AU are tall enough to double the fraction of the stellar luminosity reprocessed into the near-infrared. We generate synthetic spectral energy distributions (SEDs) using Monte Carlo radiative transfer calculations with opacities for submicron silicate and carbonaceous grains. The synthetic SEDs closely follow the median Herbig SED constructed recently by Mulders and Dominik and, in particular, match the large near-infrared flux, provided the grains have a mass fraction close to interstellar near the disk's inner rim.

  9. The impact of AIRS atmospheric temperature and moisture profiles on hurricane forecasts: Ike (2008) and Irene (2011)

    NASA Astrophysics Data System (ADS)

    Zheng, Jing; Li, Jun; Schmit, Timothy J.; Li, Jinlong; Liu, Zhiquan

    2015-03-01

    Atmospheric InfraRed Sounder (AIRS) measurements are a valuable supplement to current observational data, especially over the oceans where conventional data are sparse. In this study, two types of AIRS-retrieved temperature and moisture profiles, the AIRS Science Team product (SciSup) and the single field-of-view (SFOV) research product, were evaluated with European Centre for Medium-Range Weather Forecasts (ECMWF) analysis data over the Atlantic Ocean during Hurricane Ike (2008) and Hurricane Irene (2011). The evaluation results showed that both types of AIRS profiles agreed well with the ECMWF analysis, especially between 200 hPa and 700 hPa. The average standard deviation of both temperature profiles was approximately 1 K under 200 hPa, where the mean AIRS temperature profile from the AIRS SciSup retrievals was slightly colder than that from the AIRS SFOV retrievals. The mean SciSup moisture profile was slightly drier than that from the SFOV in the mid troposphere. A series of data assimilation and forecast experiments was then conducted with the Advanced Research version of the Weather Research and Forecasting (WRF) model and its three-dimensional variational (3DVAR) data assimilation system for hurricanes Ike and Irene. The results showed an improvement in the hurricane track due to the assimilation of AIRS clear-sky temperature profiles in the hurricane environment. In terms of total precipitable water and rainfall forecasts, the hurricane moisture environment was found to be affected by the AIRS sounding assimilation. Meanwhile, improving hurricane intensity forecasts through assimilating AIRS profiles remains a challenge for further study.

  10. Data Assimilation of AIRS Water Vapor Profiles: Impact on Precipitation Forecasts for Atmospheric River Cases Affecting the Western of the United States

    NASA Technical Reports Server (NTRS)

    Blankenship, Clay; Zavodsky, Bradley; Jedlovec, Gary; Wick, Gary; Neiman, Paul

    2013-01-01

    Atmospheric rivers are transient, narrow regions in the atmosphere responsible for the transport of large amounts of water vapor. These phenomena can have a large impact on precipitation. In particular, they can be responsible for intense rain events on the western coast of North America during the winter season. This paper focuses on attempts to improve forecasts of heavy precipitation events in the Western US due to atmospheric rivers. Profiles of water vapor derived from from Atmospheric Infrared Sounder (AIRS) observations are combined with GFS forecasts by a three-dimensional variational data assimilation in the Gridpoint Statistical Interpolation (GSI). Weather Research and Forecasting (WRF) forecasts initialized from the combined field are compared to forecasts initialized from the GFS forecast only for 3 test cases in the winter of 2011. Results will be presented showing the impact of the AIRS profile data on water vapor and temperature fields, and on the resultant precipitation forecasts.

  11. History of Space-Based Infrared Astronomy and the Air Force Infrared Celestial Backgrounds Program

    DTIC Science & Technology

    2008-04-18

    this collection of information is estimated to average 1 hour per response, including the time for reviewing instructions, searching existing data...Infrared Surveys ........................................................................................ 253 9.5. The Search for Near-Earth...www.dtic.mil/dtic/ search /tr/index.html) or the National Technical Information Service (NTIS – http://ntis.gov); I provide the unique nine character

  12. Air Sampling Instruments for Evaluation of Atmospheric Contaminants. Fourth Edition.

    ERIC Educational Resources Information Center

    American Conference of Governmental Industrial Hygienists, Cincinnati, OH.

    This text, a revision and extension of the first three editions, consists of papers discussing the basic considerations in sampling air for specific purposes, sampler calibration, systems components, sample collectors, and descriptions of air-sampling instruments. (BT)

  13. Fourier transform infrared absorption spectroscopy characterization of gaseous atmospheric pressure plasmas with 2 mm spatial resolution

    SciTech Connect

    Laroche, G.; Vallade, J.; Bazinette, R.; Hernandez, E.; Hernandez, G.; Massines, F.; Nijnatten, P. van

    2012-10-15

    This paper describes an optical setup built to record Fourier transform infrared (FTIR) absorption spectra in an atmospheric pressure plasma with a spatial resolution of 2 mm. The overall system consisted of three basic parts: (1) optical components located within the FTIR sample compartment, making it possible to define the size of the infrared beam (2 mm Multiplication-Sign 2 mm over a path length of 50 mm) imaged at the site of the plasma by (2) an optical interface positioned between the spectrometer and the plasma reactor. Once through the plasma region, (3) a retro-reflector module, located behind the plasma reactor, redirected the infrared beam coincident to the incident path up to a 45 Degree-Sign beamsplitter to reflect the beam toward a narrow-band mercury-cadmium-telluride detector. The antireflective plasma-coating experiments performed with ammonia and silane demonstrated that it was possible to quantify 42 and 2 ppm of these species in argon, respectively. In the case of ammonia, this was approximately three times less than this gas concentration typically used in plasma coating experiments while the silane limit of quantification was 35 times lower. Moreover, 70% of the incoming infrared radiation was focused within a 2 mm width at the site of the plasma, in reasonable agreement with the expected spatial resolution. The possibility of reaching this spatial resolution thus enabled us to measure the gaseous precursor consumption as a function of their residence time in the plasma.

  14. Fourier transform infrared absorption spectroscopy characterization of gaseous atmospheric pressure plasmas with 2 mm spatial resolution.

    PubMed

    Laroche, G; Vallade, J; Bazinette, R; van Nijnatten, P; Hernandez, E; Hernandez, G; Massines, F

    2012-10-01

    This paper describes an optical setup built to record Fourier transform infrared (FTIR) absorption spectra in an atmospheric pressure plasma with a spatial resolution of 2 mm. The overall system consisted of three basic parts: (1) optical components located within the FTIR sample compartment, making it possible to define the size of the infrared beam (2 mm × 2 mm over a path length of 50 mm) imaged at the site of the plasma by (2) an optical interface positioned between the spectrometer and the plasma reactor. Once through the plasma region, (3) a retro-reflector module, located behind the plasma reactor, redirected the infrared beam coincident to the incident path up to a 45° beamsplitter to reflect the beam toward a narrow-band mercury-cadmium-telluride detector. The antireflective plasma-coating experiments performed with ammonia and silane demonstrated that it was possible to quantify 42 and 2 ppm of these species in argon, respectively. In the case of ammonia, this was approximately three times less than this gas concentration typically used in plasma coating experiments while the silane limit of quantification was 35 times lower. Moreover, 70% of the incoming infrared radiation was focused within a 2 mm width at the site of the plasma, in reasonable agreement with the expected spatial resolution. The possibility of reaching this spatial resolution thus enabled us to measure the gaseous precursor consumption as a function of their residence time in the plasma.

  15. Evaluation of Shortwave Infrared Atmospheric Correction for Ocean Color Remote Sensing of Chesapeake Bay

    NASA Technical Reports Server (NTRS)

    Werdell, P. Jeremy; Franz, Bryan A.; Bailey, Sean W.

    2010-01-01

    The NASA Moderate Resolution Imaging Spectroradiometer onboard the Aqua platform (MODIS-Aqua) provides a viable data stream for operational water quality monitoring of Chesapeake Bay. Marine geophysical products from MODIS-Aqua depend on the efficacy of the atmospheric correction process, which can be problematic in coastal environments. The operational atmospheric correction algorithm for MODIS-Aqua requires an assumption of negligible near-infrared water-leaving radiance, nL(sub w)(NIR). This assumption progressively degrades with increasing turbidity and, as such, methods exist to account for non-negligible nL(sub w)(NIR) within the atmospheric correction process or to use alternate radiometric bands where the assumption is satisfied, such as those positioned within shortwave infrared (SWIR) region of the spectrum. We evaluated a decade-long time-series of nL(sub w)(lambda) from MODIS-Aqua in Chesapeake Bay derived using NIR and SWIR bands for atmospheric correction. Low signal-to-noise ratios (SNR) for the SWIR bands of MODIS-Aqua added noise errors to the derived radiances, which produced broad, flat frequency distributions of nL(sub w)(lambda) relative to those produced using the NIR bands. The SWIR approach produced an increased number of negative nL(sub w)(lambda) and decreased sample size relative to the NIR approach. Revised vicarious calibration and regional tuning of the scheme to switch between the NIR and SWIR approaches may improve retrievals in Chesapeake Bay, however, poor SNR values for the MODIS-Aqua SWIR bands remain the primary deficiency of the SWIR-based atmospheric correction approach.

  16. Quantitative infrared absorption cross-sections of isoprene for atmospheric measurements

    DOE PAGES

    Brauer, C. S.; Blake, T. A.; Guenther, A. B.; ...

    2014-04-25

    Isoprene (C5H8, 2-methyl-1,3-butadiene) is a volatile organic compound (VOC) that is one of the primary contributors to annual global VOC emissions. Produced by vegetation as well as anthropogenic sources, the OH- and O3-initiated oxidations of isoprene are a major source of atmospheric oxygenated organics. Few quantitative infrared studies have been reported for isoprene, however, limiting the ability to quantify isoprene emissions via stand-off infrared or in situ detection. We thus report absorption coefficients and integrated band intensities for isoprene in the 600–6500 cm−1 region. The pressure-broadened (1 atmosphere N2) spectra were recorded at 278, 298 and 323 K in amore » 19.94 cm path length cell at 0.112 cm−1 resolution, using a Bruker 66v FTIR. Composite spectra are derived from a minimum of seven isoprene sample pressures at each temperature and the number densities are normalized to 296 K and 1 atmosphere.« less

  17. Development of a Fast Forward Model for the Infrared Atmospheric Sounding Interferometer

    NASA Astrophysics Data System (ADS)

    Liu, X.; Schluessel, P.; Zhou, D.; Larar, A.; Smith, W.; Mango, S.

    The Infrared Atmospheric Sounding Interferometer IASI is a modern satellite sensor with 8461 channels and a spectral resolution of 0 25 wavenumber It provides a wealth of information on atmospheric and surface properties Due to the high spectral resolution a large number of Radiative Transfer RT calculations through the inhomogeneous atmosphere are needed Usually only subsets of channels are used to perform physical inversions for atmospheric profiles This paper presents a novel radiative transfer model based on principal component analysis The Principal Component-based Radiative Transfer Model PCRTM predicts PC scores and associated derivatives with respect to various atmospheric and surface properties in PC space directly Usually less than 200 PCs are needed to regenerate the original radiance spectrum with accuracy better than instrument noise level Therefore the dimension of the spectrum is reduced by an order of magnitude for hyper spectral sensors with thousands of channels The reduction in dimension and the fast RTM make the physical inversion algorithm very fast and efficient Due to its significant savings in computational time the approach uses information from all measured channels There is no need to use only subset of channels The parameterization of the PCRTM model is derived from properties of PC scores and instrument line shape functions It is physical and accurate

  18. Evaluation of transmittance of selected infrared bands. [of air pollutants

    NASA Technical Reports Server (NTRS)

    Gupta, S. K.; Tiwari, S. N.

    1976-01-01

    Computer programs were developed for evaluating homogeneous path transmittance with line-by-line and quasi-random band model formulations. Spectral transmittances for some selected bands of different gases (CO, N2O, CO2, H2O) were obtained using these programs. Results of theoretical computations are compared with available experimental measurements. Significant errors are observed in the results obtained from a quasi-random band model formulation, indicating that it is inadequate to meet the accuracy requirements for atmospheric work.

  19. Infrared measurements of column abundances of several trace gases in the Antarctic atmosphere

    NASA Technical Reports Server (NTRS)

    Murcray, F. J.; Murcray, F. H.; Murcray, D. G.

    1988-01-01

    Atmospheric emission measurements were made in 1978 from an LC 130 aircraft from Point Mugu, CA, to McMurdo Station, Antarctica, and from McMurdo over the Antarctic continent on several different flights. These included a number of flights over the South Pole. In December 1980, infrared solar spectra were obtained from the ground at South Pole Station. Infrared solar spectra were also obtained from South Pole during late November and early December of 1986. These latter measurements were extended to cover additional spectral regions to obtain column densities of a number of additional constituents. The results obtained from these measurement series are reviewed and, where measurements were made during both periods, compared. Spectral absorption or emission features due to HNO3, NO, NO2, HCl, (H-16)2O, (H-18)2O, HDO, CH4, and N2O were used to obtain data on the total column abundances for these compounds.

  20. Low-temperature and low atmospheric pressure infrared reflectance spectroscopy of Mars soil analog materials

    NASA Technical Reports Server (NTRS)

    Bishop, Janice L.; Pieters, Carle M.

    1995-01-01

    Infrared reflectance spectra of carefully selected Mars soil analog materials have been measured under low atmospheric pressures and temperatures. Chemically altered montmorillonites containing ferrihydrite and hydrated ferric sulfate complexes are examined, as well as synthetic ferrihydrite and a palagonitic soil from Haleakala, Maui. Reflectance spectra of these analog materials exhibit subtle visible to near-infrared features, which are indicative of nanophase ferric oxides or oxyhydroxides and are similar to features observed in the spectra of the bright regions of Mars. Infrared reflectance spectra of these analogs include hydration features due to structural OH, bound H2O, and adsorbed H2O. The spectral character of these hydration features is highly dependent on the sample environment and on the nature of the H2O/OH in the analogs. The behavior of the hydration features near 1.9 micron, 2.2 micron, 2.7 micron, 3 micron, and 6 microns are reported here in spectra measured under a Marslike atmospheric environment. In spectra of these analogs measured under dry Earth atmospheric conditions the 1.9-micron band depth is 8-17%; this band is much stronger under moist conditions. Under Marslike atmospheric conditions the 1.9-micron feature is broad and barely discernible (1-3% band depth) in spectra of the ferrihydrite and palagonitic soil samples. In comparable spectra of the ferric sulfate-bearing montmorillonite the 1.9-micron feature is also broad, but stronger (6% band depth). In the low atmospheric pressure and temperature spectra of the ferrihydrite-bearing montmorillonite this feature is sharper than the other analogs and relatively stronger (6% band depth). Although the intensity of the 3-micron band is weaker in spectra of each of the analogs when measured under Marslike conditions, the 3-micron band remains a dominant feature and is especially broad in spectra of the ferrihydrite and palagonitic soil. The structural OH features observed in these materials

  1. Low-temperature and low atmospheric pressure infrared reflectance spectroscopy of Mars soil analog materials

    NASA Technical Reports Server (NTRS)

    Bishop, Janice L.; Pieters, Carle M.

    1995-01-01

    Infrared reflectance spectra of carefully selected Mars soil analog materials have been measured under low atmospheric pressures and temperatures. Chemically altered montmorillonites containing ferrihydrite and hydrated ferric sulfate complexes are examined, as well as synthetic ferrihydrate and a palagonitic soil from Haleakala, Maui. Reflectance spectra of these analog materials exhibit subtle visible to near-infrared features, which are indicative of nanophase ferric oxides or oxyhydroxides and are similar to features observed in the spectra of the bright regions of Mars. Infrared reflectance spectra of these analogs include hydration features due to structural OH, bound H2O and adsorbed H2O. The spectal character of these hydration features is highly dependent on the sample environment and on the nature of the H2O/OH in the analogs. The behavior of the hydration features near 1.9 micrometers, 2.2 micrometers, 2.7 micrometers, 3 micrometers, and 6 micrometers are reported here in spetra measured under Marslike atmospheric environment. In spectra of these analogs measured under dry Earth atmospheric conditions the 1.9-micrometer band depth is 8-17%; this band is much stonger under moist conditions. Under Marslike atmospheric conditions the 1.9-micrometer feature is broad and barely discernible (1-3% band depth) in spectra of the ferrihydrite and palagonitic soil samples. In comparable spectra of the ferric sulfate-bearing montmorillonite the 1.9-micrometer feature is also broad, but stronger (6% band depth). In the low atmospheric pressure and temperature spectra of the ferrihydrite-bearing montmorillonite this feature is sharper than the other analogs and relatively stronger (6% band depth). Although the intensity of the 3- micrometer band is weaker in spectra of each of the analogs when measured under Marslike conditions, the 3-micromter band remains a dominant feature and is especially broad in spectra of the ferrihydrite and palagonitic soil. The structural

  2. A Useful Tool for Atmospheric Correction and Surface Temperature Estimation of Landsat Infrared Thermal Data

    NASA Astrophysics Data System (ADS)

    Rivalland, Vincent; Tardy, Benjamin; Huc, Mireille; Hagolle, Olivier; Marcq, Sébastien; Boulet, Gilles

    2016-04-01

    Land Surface temperature (LST) is a critical variable for studying the energy and water budgets at the Earth surface, and is a key component of many aspects of climate research and services. The Landsat program jointly carried out by NASA and USGS has been providing thermal infrared data for 40 years, but no associated LST product has been yet routinely proposed to community. To derive LST values, radiances measured at sensor-level need to be corrected for the atmospheric absorption, the atmospheric emission and the surface emissivity effect. Until now, existing LST products have been generated with multi channel methods such as the Temperature/Emissivity Separation (TES) adapted to ASTER data or the generalized split-window algorithm adapted to MODIS multispectral data. Those approaches are ill-adapted to the Landsat mono-window data specificity. The atmospheric correction methodology usually used for Landsat data requires detailed information about the state of the atmosphere. This information may be obtained from radio-sounding or model atmospheric reanalysis and is supplied to a radiative transfer model in order to estimate atmospheric parameters for a given coordinate. In this work, we present a new automatic tool dedicated to Landsat thermal data correction which improves the common atmospheric correction methodology by introducing the spatial dimension in the process. The python tool developed during this study, named LANDARTs for LANDsat Automatic Retrieval of surface Temperature, is fully automatic and provides atmospheric corrections for a whole Landsat tile. Vertical atmospheric conditions are downloaded from the ERA Interim dataset from ECMWF meteorological organization which provides them at 0.125 degrees resolution, at a global scale and with a 6-hour-time step. The atmospheric correction parameters are estimated on the atmospheric grid using the commercial software MODTRAN, then interpolated to 30m resolution. We detail the processing steps

  3. Atmospheric transmission and thermal background emission in the mid-infrared at Mauna Kea

    NASA Astrophysics Data System (ADS)

    Otárola, A.; Richter, M.; Packham, C.; Chun, M.

    2015-04-01

    We present results of a preliminary study intended to quantitatively estimate the atmospheric transmission and thermal background emission in the mid-infrared (MIR), 7 μm - 26 μm, at the 13N TMT site in Mauna Kea. This is in the interest of supporting the planning of MIR instrumentation for the posible second-generation of astronomical instruments for the Thirty Meter Telescope (TMT) project. Mauna Kea, located at high altitude (4,050 m above sea level), enjoys natural conditions that make it an outstanding location for astronomical observations in the mid-infrared. The goal of this work is to produce a dataset and model that shows the atmospheric transmission and thermal emission for two cases of precipitable water vapor (PWV), a low value of 0.3 mm, and at 1.5 mm which represent near median conditions at the site. Besides, and driven by the interest of the MIR community to exploit the daily twilight times, we look at the specific atmospheric conditions around twilight as a function of season. The best conditions are found for cold and dry winter days, and in particular the morning twilight offers the best conditions. The analysis of PWV data, shows the median value for the site (all year conditions between 6:00 PM and 7:30AM) is 1.8 mm and that periods of water vapor lower than 1.0 mm are common, these supports the opportunity and discovery potential of the TMT project in the mid-infrared bands.

  4. Identification of acetylene (C2H2) in infrared atmospheric absorption spectra

    NASA Astrophysics Data System (ADS)

    Goldman, A.; Murcray, F. J.; Blatherwick, R. D.; Gillis, J. R.; Bonomo, F. S.; Murcray, F. H.; Murcray, D. G.; Cicerone, R. J.

    1981-12-01

    Infrared atmospheric absorption spectra at ˜0.02 cm-1 resolution obtained during a balloon flight made on March 23, 1981, show absorption features attributable to C2H2. These features are used to derive a preliminary mixing ratio of ˜25 pptv near 9 km. This mixing ratio falls into the range of values we calculate for upper tropospheric C2H2 in a photochemical/transport model but well below values measured previously in samples collected by other researchers.

  5. Identification of acetylene /C2H2/ in infrared atmospheric absorption spectra

    NASA Technical Reports Server (NTRS)

    Goldman, A.; Murcray, F. J.; Blatherwick, R. D.; Gillis, J. R.; Bonomo, F. S.; Murcray, F. H.; Murcray, D. G.; Cicerone, R. J.

    1981-01-01

    Infrared atmospheric absorption spectra at 0.02/cm resolution were obtained during a balloon flight on March 23, 1981 from the Holloman AFB, New Mexico. The absorption features, attributed to C2H2, were used to derive a preliminary mixing ratio of about 25 pptv near 9 km, accurate to + or - 40%. This mixing ratio falls into the range of values calculated for the upper troposphere C2H2 in a photochemical/transport model. However, previous measurements from aircraft grab sampling (Cronn and Robinson, 1979) show four to twelve times this C2H2 concentration 1.5 km below the tropopause.

  6. Four-laser airborne infrared spectrometer for atmospheric trace gas measurements.

    PubMed

    Roths, J; Zenker, T; Parchatka, U; Wienhold, F G; Harris, G W

    1996-12-20

    We describe the four-laser airborne infrared (FLAIR) instrument, a tunable diode laser absorption spectrometer designed for simultaneous high-sensitivity in situ measurements of four atmospheric trace gases in the troposphere. The FLAIR spectrometer was employed during the large-scale airborne research campaign on tropospheric ozone (TROPOZ II) in 1991 and was used to measure CO, H(2) O(2), HCHO, and NO(2) in the free troposphere where detection limits below 100 parts in 10(12) by volume were achieved.

  7. Novel Infrared Phototransistors for Atmospheric CO2 Profiling at 2 Micron Wavelength

    NASA Technical Reports Server (NTRS)

    Refaat, Tamer F.; Abedin, M. Nurul; Sulima, Oleg V.; Singh, Upendra N.; Ismail, Syed

    2004-01-01

    Two-micron detectors are critical for atmospheric carbon dioxide profiling using the lidar technique. The characterization results of a novel infrared AlGaAsSb/ InGaAsSb phototransistor are reported. Emitter dark current variation with the collector-emitter voltage at different temperatures is acquired to examine the gain mechanism. Spectral response measurements resulted in responsivity as high as 2650 A/W at 2.05 m wavelength. Bias voltage and temperature effects on the device responsivity are presented. The detectivity of this device is compared to InGaAs and HgCdTe devices.

  8. Novel Infrared Phototransistors for Atmospheric CO2 Profiling at 2 microns Wavelength

    NASA Technical Reports Server (NTRS)

    Refaat, Tamer F.; Abedin, M. Nurul; Sulima, Oleg V.; Singh, Upendra N.; Ismail, Syed

    2004-01-01

    Two-micron detectors are critical for atmospheric carbon dioxide profiling using the lidar technique. The characterization results of a novel infrared AlGaAsSb/ InGaAsSb phototransistor are reported. Emitter dark current variation with the collector-emitter voltage at different temperatures is acquired to examine the gain mechanism. Spectral response measurements resulted in responsivity as high as 2650 A/W at 2.05 microns wavelength. Bias voltage and temperature effects on the device responsivity are presented. The detectivity of this device is compared to InGaAs and HgCdTe devices.

  9. Atmospheric chemistry of HFE-7300 and HFE-7500: Temperature dependent kinetics, atmospheric lifetimes, infrared spectra and global warming potentials

    NASA Astrophysics Data System (ADS)

    Rodríguez, Ana; Rodríguez, Diana; Moraleda, Araceli; Bravo, Iván; Moreno, Elena; Notario, Alberto

    2014-10-01

    The atmospheric degradation of two hydrofluoroethers, HFE-7300 [n-C2F5CF(OCH3)CF(CF3)2] and HFE-7500 [n-C3F7CF(OC2H5)CF(CF3)2] used in industrial applications has been studied. The kinetics and reaction products were determined at atmospheric pressure as a function of temperature in a reaction chamber using GC/FID and GC/MS techniques for the analysis. The following Arrhenius expressions were obtained (in units of cm3 molecule-1 s-1): kHFE-7300 + OH = (5.6 ± 2.0) × 10-13 exp(-(1186 ± 111)/T); kHFE-7300 + Cl = (3.8 ± 1.3) × 10-12 exp(-(968 ± 101)/T); and kHFE-7500 + OH = (7.6 ± 6.0) × 10-12 exp(-(1163 ± 385)/T) (temperature range 271-333 K). The atmospheric lifetimes calculated from kinetic data for HFE-7300 and HFE-7500 were 5.24 and 0.30 years, respectively. In the oxidation of HFE-7300 with OH and Cl radicals, the only detected product was CF3CF2CF(OCHO)CF(CF3)2, whereas in the oxidation of HFE-7500 by OH radicals the detected products were: C3F7CF(OC(O)CH3)CF(CF3)2 and C3F7CF(OC(O)H)CF(CF3)2. Infrared spectra of the studied HFEs have also been measured and radiative forcing efficiencies were determined. Combining these results with the kinetic data, we estimated 100-year time horizon global warming potentials of 440 and 12 for HFE-7300 and HFE-7500, respectively.

  10. Neutral gas laser: a tool for sensing atmospheric species by infrared absorption

    NASA Astrophysics Data System (ADS)

    Wormhoudt, Joda C.; Kebabian, Paul L.

    1994-07-01

    In the spectroscopic analysis of atmospheric composition, there is a continuing need for stable and reproducible mid-infrared light sources. The neutral rare gas lasers offer several important benefits, in the many cases where one of their lines coincides with an absorption line of an atmospheric species to be observed. As atomic spectral lines, they are not subject to the drift and aging effects seen in diode lasers. Furthermore, the Zeeman effect provides up to a few tenths of a wavenumber of tunability, which can be an advantage over molecular lasers (such as CO2) which can only be tuned by line selection. We present observations in applications of neutral rare gas lasers to measurements of CO, N2O and CH4, and discuss possible applications to a variety of other species, including formaldehyde, methanol, hydrazine, water vapor, and the methyl radical.

  11. A radiation model for calculating atmospheric corrections to remotely sensed infrared measurements, version 2

    NASA Technical Reports Server (NTRS)

    Boudreau, R. D.

    1973-01-01

    A numerical model is developed which calculates the atmospheric corrections to infrared radiometric measurements due to absorption and emission by water vapor, carbon dioxide, and ozone. The corrections due to aerosols are not accounted for. The transmissions functions for water vapor, carbon dioxide, and water are given. The model requires as input the vertical distribution of temperature and water vapor as determined by a standard radiosonde. The vertical distribution of carbon dioxide is assumed to be constant. The vertical distribution of ozone is an average of observed values. The model also requires as input the spectral response function of the radiometer and the nadir angle at which the measurements were made. A listing of the FORTRAN program is given with details for its use and examples of input and output listings. Calculations for four model atmospheres are presented.

  12. Remote Sensing of Methane in the Martian Atmosphere using Infrared Laser Heterodyne Radiometry

    NASA Astrophysics Data System (ADS)

    Passmore, R. L.; Bowles, N. E.; Weidmann, D.; Smith, K.

    2011-12-01

    In the last few years, several research teams have reported the detection of methane in the atmosphere of Mars, measuring 10 ppb on average [1][2][3]. The source of the methane is still unknown, but its identification is important as its presence could imply a biological origin. However, the detection limits of current instruments lie below the requirements for an unambiguous determination of concentration mapping and distribution. We investigate the viability of detecting methane in the Martian atmosphere via a high sensitivity remote sensing technique known as passive mid-infrared laser heterodyne radiometry. Although heterodyne spectroscopy is not a new idea, recent advancements in local oscillator technology [4] offer the possibility of significant instrument miniaturisation relevant to space deployment. We present our current work on a laser heterodyne radiometer (LHR) which involves adapting an existing 10 μm laser breadboard design, which was used with much success to study stratospheric ozone [5], to operate at 7.7 μm in order to target the ν4 fundamental band of methane. The core of the LHR consists of a distributed-feedback quantum cascade laser (QCL) operating in continuous-wave mode, which acts as the local oscillator. QCLs are ideal local oscillators for this type of instrument as they emit with high spectral purity and the necessary optical power in the mid-infrared region where characteristic spectral lines of interest lie. Atmospheric modelling of the Martian atmosphere and instrument sensitivity studies enabled simulated methane spectral features to be studied in detail, which subsequently determined the focus for experimental efforts in the laboratory. Testing of the LHR was initially carried out on small gas cells containing pure methane gas, but in order to test the instrument more rigorously for atmospheric studies a larger gas cell was constructed that approximates the Martian atmosphere in the laboratory. Trace quantities of methane were

  13. A chemometrics approach applied to Fourier transform infrared spectroscopy (FTIR) for monitoring the spoilage of fresh salmon (Salmo salar) stored under modified atmospheres.

    PubMed

    Saraiva, C; Vasconcelos, H; de Almeida, José M M M

    2017-01-16

    The aim of this work was to investigate the potential of Fourier transform infrared spectroscopy (FTIR) to detect and predict the bacterial load of salmon fillets (Salmo salar) stored at 3, 8 and 30°C under three packaging conditions: air packaging (AP) and two modified atmospheres constituted by a mixture of 50%N2/40%CO2/10%O2 with lemon juice (MAPL) and without lemon juice (MAP). Fresh salmon samples were periodically examined for total viable counts (TVC), specific spoilage organisms (SSO) counts, pH, FTIR and sensory assessment of freshness. Principal components analysis (PCA) allowed identification of the wavenumbers potentially correlated with the spoilage process. Linear discriminant analysis (LDA) of infrared spectral data was performed to support sensory data and to accurately identify samples freshness. The effect of the packaging atmospheres was assessed by microbial enumeration and LDA was used to determine sample packaging from the measured infrared spectra. It was verified that modified atmospheres can decrease significantly the bacterial load of fresh salmon. Lemon juice combined with MAP showed a more pronounced delay in the growth of Brochothrix thermosphacta, Photobacterium phosphoreum, psychrotrophs and H2S producers. Partial least squares regression (PLS-R) allowed estimates of TVC and psychrotrophs, lactic acid bacteria, molds and yeasts, Brochothrix thermosphacta, Enterobacteriaceae, Pseudomonas spp. and H2S producer counts from the infrared spectral data. For TVC, the root mean square error of prediction (RMSEP) value was 0.78logcfug(-1) for an external set of samples. According to the results, FTIR can be used as a reliable, accurate and fast method for real time freshness evaluation of salmon fillets stored under different temperatures and packaging atmospheres.

  14. Spectral Irradiance Calibration in the Infrared. Part 7; New Composite Spectra, Comparison with Model Atmospheres, and Far-Infrared Extrapolations

    NASA Technical Reports Server (NTRS)

    Cohen, Martin; Witteborn, Fred C.; Carbon, Duane F.; Davies, John K.; Wooden, Diane H.; Bregman, Jesse D.

    1996-01-01

    We present five new absolutely calibrated continuous stellar spectra constructed as far as possible from spectral fragments observed from the ground, the Kuiper Airborne Observatory (KAO), and the IRAS Low Resolution Spectrometer. These stars-alpha Boo, gamma Dra, alpha Cet, gamma Cru, and mu UMa-augment our six, published, absolutely calibrated spectra of K and early-M giants. All spectra have a common calibration pedigree. A revised composite for alpha Boo has been constructed from higher quality spectral fragments than our previously published one. The spectrum of gamma Dra was created in direct response to the needs of instruments aboard the Infrared Space Observatory (ISO); this star's location near the north ecliptic pole renders it highly visible throughout the mission. We compare all our low-resolution composite spectra with Kurucz model atmospheres and find good agreement in shape, with the obvious exception of the SiO fundamental, still lacking in current grids of model atmospheres. The CO fundamental seems slightly too deep in these models, but this could reflect our use of generic models with solar metal abundances rather than models specific to the metallicities of the individual stars. Angular diameters derived from these spectra and models are in excellent agreement with the best observed diameters. The ratio of our adopted Sirius and Vega models is vindicated by spectral observations. We compare IRAS fluxes predicted from our cool stellar spectra with those observed and conclude that, at 12 and 25 microns, flux densities measured by IRAS should be revised downwards by about 4.1% and 5.7%, respectively, for consistency with our absolute calibration. We have provided extrapolated continuum versions of these spectra to 300 microns, in direct support of ISO (PHT and LWS instruments). These spectra are consistent with IRAS flux densities at 60 and 100 microns.

  15. The science of ARIEL (Atmospheric Remote-sensing Infrared Exoplanet Large-survey)

    NASA Astrophysics Data System (ADS)

    Tinetti, G.; Drossart, P.; Eccleston, P.; Hartogh, P.; Heske, A.; Leconte, J.; Micela, G.; Ollivier, M.; Pilbratt, G.; Puig, L.; Turrini, D.; Vandenbussche, B.; Wolkenberg, P.; Pascale, E.; Beaulieu, J.-P.; Güdel, M.; Min, M.; Rataj, M.; Ray, T.; Ribas, I.; Barstow, J.; Bowles, N.; Coustenis, A.; Coudé du Foresto, V.; Decin, L.; Encrenaz, T.; Forget, F.; Friswell, M.; Griffin, M.; Lagage, P. O.; Malaguti, P.; Moneti, A.; Morales, J. C.; Pace, E.; Rocchetto, M.; Sarkar, S.; Selsis, F.; Taylor, W.; Tennyson, J.; Venot, O.; Waldmann, I. P.; Wright, G.; Zingales, T.; Zapatero-Osorio, M. R.

    2016-07-01

    The Atmospheric Remote-Sensing Infrared Exoplanet Large-survey (ARIEL) is one of the three candidate missions selected by the European Space Agency (ESA) for its next medium-class science mission due for launch in 2026. The goal of the ARIEL mission is to investigate the atmospheres of several hundred planets orbiting distant stars in order to address the fundamental questions on how planetary systems form and evolve. During its four (with a potential extension to six) years mission ARIEL will observe 500+ exoplanets in the visible and the infrared with its meter-class telescope in L2. ARIEL targets will include gaseous and rocky planets down to the Earth-size around different types of stars. The main focus of the mission will be on hot and warm planets orbiting close to their star, as they represent a natural laboratory in which to study the chemistry and formation of exoplanets. The ARIEL mission concept has been developed by a consortium of more than 50 institutes from 12 countries, which include UK, France, Italy, Germany, the Netherlands, Poland, Spain, Belgium, Austria, Denmark, Ireland and Portugal. The analysis of the ARIEL spectra and photometric data in the 0.5-7.8 micron range will allow to extract the chemical fingerprints of gases and condensates in the planets' atmospheres, including the elemental composition for the most favorable targets. It will also enable the study of thermal and scattering properties of the atmosphere as the planet orbit around the star. ARIEL will have an open data policy, enabling rapid access by the general community to the high-quality exoplanet spectra that the core survey will deliver.

  16. Atmospheric science: Ancient air caught by shooting stars

    NASA Astrophysics Data System (ADS)

    Zahnle, Kevin; Buick, Roger

    2016-05-01

    Ashes of ancient meteors recovered from a 2.7-billion-year-old lake bed imply that the upper atmosphere was rich in oxygen at a time when all other evidence implies that the atmosphere was oxygen-free. See Letter p.235

  17. Atmospheric Boundary Layer Modeling for Combined Meteorology and Air Quality Systems

    EPA Science Inventory

    Atmospheric Eulerian grid models for mesoscale and larger applications require sub-grid models for turbulent vertical exchange processes, particularly within the Planetary Boundary Layer (PSL). In combined meteorology and air quality modeling systems consistent PSL modeling of wi...

  18. Mitigating atmospheric effects in high-resolution infra-red surveillance imagery with bispectral speckle imaging

    SciTech Connect

    Carrano, C J

    2006-05-30

    Obtaining a high-resolution image of an object or scene from a long distance away can be very problematic, even with the best optical system. This is because atmospheric blurring and distortion will limit the resolution and contrast of high-resolution imaging systems with substantial sized apertures over horizontal and slant paths. Much of the horizontal and slant-path surveillance imagery we have previously collected and successfully enhanced has been collected at visible wavelengths where atmospheric effects are the strongest. Imaging at longer wavelengths has the benefit of seeing through obscurants or even at night, but even though the atmospheric effects are noticeably reduced, they are nevertheless present, especially near the ground. This paper will describe our recent work on enhanced infrared (IR) surveillance using bispectral speckle imaging. Bispectral speckle imaging in this context is an image postprocessing algorithm that aims to solve the atmospheric blurring and distortion problem of imaging through horizontal or slant path turbulence. A review of the algorithm as well as descriptions of the IR camera and optical systems used in our data collections will be given. Examples of horizontal and slant-path imagery before and after speckle processing will also be presented to demonstrate the resolution improvement gained by the processing. Comparisons of IR imagery to visible wavelength imagery of the same target under the same conditions will be shown to demonstrate the tradeoffs of going to longer wavelengths.

  19. Probing Atmospheric Electric Fields in Thunderstorms through Radio Emission from Cosmic-Ray-Induced Air Showers.

    PubMed

    Schellart, P; Trinh, T N G; Buitink, S; Corstanje, A; Enriquez, J E; Falcke, H; Hörandel, J R; Nelles, A; Rachen, J P; Rossetto, L; Scholten, O; Ter Veen, S; Thoudam, S; Ebert, U; Koehn, C; Rutjes, C; Alexov, A; Anderson, J M; Avruch, I M; Bentum, M J; Bernardi, G; Best, P; Bonafede, A; Breitling, F; Broderick, J W; Brüggen, M; Butcher, H R; Ciardi, B; de Geus, E; de Vos, M; Duscha, S; Eislöffel, J; Fallows, R A; Frieswijk, W; Garrett, M A; Grießmeier, J; Gunst, A W; Heald, G; Hessels, J W T; Hoeft, M; Holties, H A; Juette, E; Kondratiev, V I; Kuniyoshi, M; Kuper, G; Mann, G; McFadden, R; McKay-Bukowski, D; McKean, J P; Mevius, M; Moldon, J; Norden, M J; Orru, E; Paas, H; Pandey-Pommier, M; Pizzo, R; Polatidis, A G; Reich, W; Röttgering, H; Scaife, A M M; Schwarz, D J; Serylak, M; Smirnov, O; Steinmetz, M; Swinbank, J; Tagger, M; Tasse, C; Toribio, M C; van Weeren, R J; Vermeulen, R; Vocks, C; Wise, M W; Wucknitz, O; Zarka, P

    2015-04-24

    We present measurements of radio emission from cosmic ray air showers that took place during thunderstorms. The intensity and polarization patterns of these air showers are radically different from those measured during fair-weather conditions. With the use of a simple two-layer model for the atmospheric electric field, these patterns can be well reproduced by state-of-the-art simulation codes. This in turn provides a novel way to study atmospheric electric fields.

  20. FAST TRACK COMMUNICATION: Contrasting characteristics of sub-microsecond pulsed atmospheric air and atmospheric pressure helium-oxygen glow discharges

    NASA Astrophysics Data System (ADS)

    Walsh, J. L.; Liu, D. X.; Iza, F.; Rong, M. Z.; Kong, M. G.

    2010-01-01

    Glow discharges in air are often considered to be the ultimate low-temperature atmospheric pressure plasmas for numerous chamber-free applications. This is due to the ubiquitous presence of air and the perceived abundance of reactive oxygen and nitrogen species in air plasmas. In this paper, sub-microsecond pulsed atmospheric air plasmas are shown to produce a low concentration of excited oxygen atoms but an abundance of excited nitrogen species, UV photons and ozone molecules. This contrasts sharply with the efficient production of excited oxygen atoms in comparable helium-oxygen discharges. Relevant reaction chemistry analysed with a global model suggests that collisional excitation of O2 by helium metastables is significantly more efficient than electron dissociative excitation of O2, electron excitation of O and ion-ion recombination. These results suggest different practical uses of the two oxygen-containing atmospheric discharges, with air plasmas being well suited for nitrogen and UV based chemistry and He-O2 plasmas for excited atomic oxygen based chemistry.

  1. Terminal air-to-ground missile guidance by infrared seeker

    NASA Astrophysics Data System (ADS)

    Christy, Stephane; Mazar, Bruno; Horaud, Radu

    1997-06-01

    In this paper, we describe a new method for terminal air-to- ground missile guidance based on IR seeker. The aim is to hit a building which has been previously selected in a 3D model of the scene. The proposed algorithm is divided in two steps: acquisition and tracking steps. Acquisition consists in estimating the location of the target in the first image and to reestimate the missile position. The second step is the tracking of the target along the sequence of images by predicting the target location in each image from the previous one. A supervisor module is in charge of verifying the correctness of the tracking, by doing some reacquisitions in background and ensure the coherence between reacquisitions in background and ensure the coherence between reacquisitions and tracking. All computations are real-time compatible.

  2. Modelling an infrared Man Portable Air Defence System

    NASA Astrophysics Data System (ADS)

    Birchenall, Richard P.; Richardson, Mark A.; Brian, Butters; Roy, Walmsley

    2010-09-01

    The global proliferation of shoulder launched IR Man Portable Air Defence Systems (ManPADS) has resulted in the existence of a serious threat to both civilian and military aircraft from terrorist attack. Some of the older generations of ManPADS can be defeated with modern countermeasures but even the most sophisticated protection still has vulnerabilities to the latest family of ManPADS. This paper describes the work undertaken by the authors to model a second generation ManPAD, based on the Russian SA-14, and assess the vulnerabilities of aircraft both with and without flare countermeasures from these systems. The conclusions are the results of over 11,000 simulated firings against targets of varying aspects, velocities and altitudes.

  3. Development of Mid-Infrared Lasers for the Measurement of Trace Atmospheric Gases

    NASA Astrophysics Data System (ADS)

    Hannun, R. A.; Witinski, M. F.; Forouhar, S.; Anderson, J.

    2012-12-01

    In order to thoroughly characterize atmospheric composition at all altitudes, an unprecedented scientific and technical effort is needed. Essential to the advancement of both satellite and in situ science are improvements in continuous wave (CW) and high-power pulsed laser systems in the infrared spectral region integrated with miniaturized electronic and optical components, allowing for the deployment of single mode light sources aboard satellite and UAV platforms. Sources in the the spectral region from 2.8 μm to 3.5 μm are crucial to the sensitive and precise quantification of several atmospherically relevant species, including: OH, H2O, H218O, HDO, CH4, 13CH4, CO2, CH2O, and C2H6, all of which present strong fundamental vibrational absorptions in this mid-infrared range. Currently, however, a massive technology gap exists in both CW and pulsed laser systems within this spectral window. Recent developments include the advancement of CW tunable diode technology using new solid state materials to improve electron hole localization, and the initial integration of these lasers into miniaturized optoelectronic systems ideal for in situ deployment. In addition, high-power pulsed light sources have been produced using optical parametric generation (OPG). A single-frequency Nd:YAG pumps a nonlinear crystal, injection seeded with a diode laser to enhance efficiency and reduce the bandwidth of the output radiation, creating a light source ideal for LIDAR and other remote sensing applications.

  4. Atmospheric CO2 measurement using dispersive infrared spectroscopy with a scanning Fabry-Pérot interferometer sensor

    NASA Astrophysics Data System (ADS)

    Chan, Ka Lok; Ning, Zhi; Westerdahl, Dane; Wong, Ka Chun; Sun, You Wen; Hartl, Andreas; Wenig, Mark

    2014-05-01

    A novel infrared absorption spectroscopic based measurement technique was developed for atmospheric CO2 measurement by using a new scanning Febry-Pérot interferometer sensor. The sensor measures the optical spectra in the mid infrared (3900nm to 5220nm) wavelength range with full width half maximum (FWHM) spectral resolution of 78.8 nm at the CO2 absorption band (~4280 nm) and sampling resolution of 20 nm. The CO2 concentration is determined from the measured optical absorption spectra by fitting it to the CO2 reference spectrum. Interference from other major absorbers in the same wavelength range, e.g., carbon monoxide (CO) and water vapor (H2O), was taken out by including their reference spectra in the fit as well. An iterative algorithm to account for the non-linear response of the fit function to the absorption cross sections due to the broad instrument function was developed and tested. The detailed descriptions of the instrumental setup, the retrieval procedure, a modeling study for error analysis as well as laboratory validation using standard gas concentrations are presented. A modeling study of the retrieval algorithm showed that errors due to instrument noise can be considerably reduced by using the dispersive spectral information in the retrieval. The mean measurement error of the prototype DIRS CO2 measurement for 1 minute averaged data is about ± 2.5 ppmv, and down to ± 0.8 ppmv for 10 minute averaged data. A field test of atmospheric CO2 measurements were carried out in an urban site in Hong Kong for a month and compared to a commercial non-dispersive infrared (NDIR) CO2 analyzer. 10 minute averaged data shows good agreement between the DIRS and NDIR measurements with Pearson correlation coefficient (R) of 0.99. A CO2 episode observed during the measurement period was analysis by the Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model. Result shows the air mass was recirculated in the region which indicates that the CO2 episode

  5. Infrared

    NASA Astrophysics Data System (ADS)

    Vollmer, M.

    2013-11-01

    techniques such as attenuated total reflectance [6]. The two final papers deal with what seem to be wholly different scientific fields [7, 8]. One paper describes SOFIA, an aeroplane-based astronomical observatory covering the whole IR range [7], while the other represents a small review of the quite new topic of terahertz physics at the upper end of the IR spectral range, from around 30 µm to 3 mm wavelength, and its many applications in science and industry [8]. Although artificially separated, all these fields use similar kinds of detectors, similar kinds of IR sources and similar technologies, while the instruments use the same physical principles. We are convinced that the field of infrared physics will develop over the next decade in the same dynamic way as during the last, and this special issue may serve as starting point for regular submissions on the topic. At any rate, it shines a light on this fascinating and many-faceted subject, which started more than 200 years ago. References [1] Mangold K, Shaw J A and Vollmer M 2013 The physics of near-infrared photography Eur. J. Phys. 34 S51-71 [2] Vollmer M and Möllmann K-P 2013 Characterization of IR cameras in student labs Eur. J. Phys. 34 S73-90 [3] Ibarra-Castanedo C, Tarpani J R and Maldague X P V 2013 Nondestructive testing with thermography Eur. J. Phys. 34 S91-109 [4] Shaw J A and Nugent P W 2013 Physics principles in radiometric infrared imaging of clouds in the atmosphere Eur. J. Phys. 34 S111-21 [5] Möllmann K-P and Vollmer M 2013 Fourier transform infrared spectroscopy in physics laboratory courses Eur. J. Phys. 34 S123-37 [6] Heise H M, Fritzsche J, Tkatsch H, Waag F, Karch K, Henze K, Delbeck S and Budde J 2013 Recent advances in mid- and near-infrared spectroscopy with applications for research and teaching, focusing on petrochemistry and biotechnology relevant products Eur. J. Phys. 34 S139-59 [7] Krabbe A, Mehlert D, Röser H-P and Scorza C 2013 SOFIA, an airborne observatory for infrared astronomy

  6. Retrieval of atmospheric parameters and radiative properties using Far-Infrared remote sensing measurements

    NASA Astrophysics Data System (ADS)

    Jamali, Maryam; Milz, Mathias; Martín-Torres, Javier; Palchetti, Luca

    2016-04-01

    The far-infrared (FIR) spectral region, covering wavelengths between 15 μm (667 cm-1) and about 1 μm (10,000 cm-1) plays a critical role in the climate system. A good knowledge of the radiation processes in this spectral region is of high interest for observations and understanding of heating and cooling rates, and global energy balance. Even though approximately 50% of terrestrial radiation occurs in the FIR and despite the critical FIR contribution to the Earth's energy balance, this spectral region has been only studied by a few number of instruments. Also the full FIR spectral region has not ever been directly observed from space. High spectral resolution observations in this region can help to enlighten its role for the global energy budget and atmospheric radiation processes. Among others, the reasons for this lack of measurements are: (i) the decreasing intensity of the radiation towards longer wavelengths; and, then (ii) the high sensitivity and cooling of the detectors requirements. These requirements are now overcome and future space missions will have the capability to measure the full FIR and then open fully one-half of the Earth's spectrum, and accordingly improve our ability to model and assess climate processes. The aim of the study is to assess the use of FIR remote sensing instruments for retrievals of atmospheric parameters and radiative properties such as heating and cooling rates. Case studies with simulated spectra, together with ground based measurements in the FIR at Dome C over the Antarctic Plateau at 3,230 m a.s.l. (above sea level) in clear-sky conditions, which been observed almost continuously since 2012, are used to assess the potential of remote sensing instruments in the far-infrared region. Appropriate selection of spectral channels to directly measure the far-infrared spectra as needed for future space missions and recommended.

  7. Infrared and Passive Microwave Radiometric Sea Surface Temperatures and Their Relationships to Atmospheric Forcing

    NASA Technical Reports Server (NTRS)

    Castro, Sandra L.

    2004-01-01

    The current generation of infrared (IR) and passive microwave (MW) satellite sensors provides highly complementary information for monitoring sea surface temperature (SST). On the one hand, infrared sensors provide high resolution and high accuracy but are obscured by clouds. Microwave sensors on the other hand, provide coverage through non-precipitating clouds but have coarser resolution and generally poorer accuracy. Assuming that the satellite SST measurements do not have spatially variable biases, they can be blended combining the merits of both SST products. These factors have motivated recent work in blending the MW and IR data in an attempt to produce high-accuracy SST products with improved coverage in regions with persistent clouds. The primary sources of retrieval uncertainty are, however, different for the two sensors. The main uncertainty in the MW retrievals lies in the effects of wind-induced surface roughness and foam on emissivity, whereas the IR retrievals are more sensitive to the atmospheric water vapor and aerosol content. Average nighttime differences between the products for the month periods of January 1999 and June 2000 are shown. These maps show complex spatial and temporal differences as indicated by the strong spatially coherent features in the product differences and the changes between seasons. Clearly such differences need to be understood and accounted for if the products are to be combined. The overall goals of this project are threefold: (1) To understand the sources of uncertainty in the IR and MW SST retrievals and to characterize the errors affecting the two types of retrieval as a fiction of atmospheric forcing; (2) To demonstrate how representative the temperature difference between the two satellite products is of Delta T; (3) To apply bias adjustments and to device a comprehensive treatment of the behavior of the temperature difference across the oceanic skin layer to determine the best method for blending thermal infrared

  8. Behavior of self-confined spherical layer of light radiation in the air atmosphere

    NASA Astrophysics Data System (ADS)

    Torchigin, V. P.; Torchigin, A. V.

    2004-07-01

    Behavior of thin spherical layer of intensive light in an inhomogeneous atmosphere is considered. It is shown that the behavior is similar to puzzling and mysterious behavior of ball lightnings. Under assumption that ball lightning moves along the gradient of atmosphere air density process of ball lightning penetration in a salon of a flying airplane is analyzed.

  9. Remote Sensing of Arctic Environmental Conditions and Critical Infrastructure using Infra-Red (IR) Cameras and Unmanned Air Vehicles (UAVs)

    NASA Astrophysics Data System (ADS)

    Hatfield, M. C.; Webley, P.; Saiet, E., II

    2014-12-01

    Remote Sensing of Arctic Environmental Conditions and Critical Infrastructure using Infra-Red (IR) Cameras and Unmanned Air Vehicles (UAVs) Numerous scientific and logistical applications exist in Alaska and other arctic regions requiring analysis of expansive, remote areas in the near infrared (NIR) and thermal infrared (TIR) bands. These include characterization of wild land fire plumes and volcanic ejecta, detailed mapping of lava flows, and inspection of lengthy segments of critical infrastructure, such as the Alaska pipeline and railroad system. Obtaining timely, repeatable, calibrated measurements of these extensive features and infrastructure networks requires localized, taskable assets such as UAVs. The Alaska Center for Unmanned Aircraft Systems Integration (ACUASI) provides practical solutions to these problem sets by pairing various IR sensors with a combination of fixed-wing and multi-rotor air vehicles. Fixed-wing assets, such as the Insitu ScanEagle, offer long reach and extended duration capabilities to quickly access remote locations and provide enduring surveillance of the target of interest. Rotary-wing assets, such as the Aeryon Scout or the ACUASI-built Ptarmigan hexcopter, provide a precision capability for detailed horizontal mapping or vertical stratification of atmospheric phenomena. When included with other ground capabilities, we will show how they can assist in decision support and hazard assessment as well as giving those in emergency management a new ability to increase knowledge of the event at hand while reducing the risk to all involved. Here, in this presentation, we illustrate how UAV's can provide the ideal tool to map and analyze the hazardous events and critical infrastructure under extreme environmental conditions.

  10. [Quantitative analysis of nitrate in atmospheric particulates PM2.5 with Fourier transform infrared spectroscopy].

    PubMed

    Liu, Na; Wei, Xiu-li; Gao, Min-guang; Xu, Liang; Jiao, Yang; Li, Sheng; Tong, Jing-jing; Cheng, Si-yang

    2013-09-01

    Airborne fine particulate matter PM2.5 as one of composite core pollutants of air pollution is concerned and NO as one of the main components of water-soluble ions has an important impact on precipitation and human health, so searching a method of rapid and reliable detection is an important work. According to advantages of the Fourier transform infrared spectroscopy technology, the infrared spectrum of NO3- in NH4NO3 was compared with PM2.5 by a sampling method of making film. The result shows that their spectra are consistent with each other. A range of infrared spectra of different masses of NO3- were measured and the absorbance was fitted with mass, correlation and mass range of which are 0.994 8 and 7.82-73.78 microg, respectively. According to the corresponding relationship of mass between solution and sample film, the FTIR of the sample film was measured directly and mass concentrations of NO3- in a month (between 2012-03-20 and 2012-04-20) of Hefei area are listed and the average is 4.1713 microg x m(-3).

  11. Clean Air Slots Amid Dense Atmospheric Pollution in Southern Africa

    NASA Technical Reports Server (NTRS)

    Hobbs, Peter V.

    2003-01-01

    During the flights of the University of Washington's Convair-580 in the Southern African Regional Science Initiative (SAFARI 2000) in southern Africa, a phenomenon was observed that has not been reported previously. This was the occurrence of thin layers of remarkably clean air, sandwiched between heavily polluted air, which persisted for many hours during the day. Photographs are shown of these clean air slots (CAS), and particle concentrations and light scattering coefficients in and around such slot are presented. An explanation is proposed for the propensity of CAS to form in southern Africa during the dry season.

  12. Experimental Determination of the Mass of Air Molecules from the Law of Atmospheres.

    ERIC Educational Resources Information Center

    Hayn, Carl H.; Galvin, Vincent, Jr.

    1979-01-01

    A gas pressure gauge has been constructed for use in a student experiment involving the law of atmospheres. From pressure data obtained at selected elevations the average mass of air molecules is determined and compared to that calculated from the molecular weights and percentages of constituents to the air. (Author/BB)

  13. Sea surface velocities from visible and infrared multispectral atmospheric mapping sensor imagery

    NASA Technical Reports Server (NTRS)

    Pope, P. A.; Emery, W. J.; Radebaugh, M.

    1992-01-01

    High resolution (100 m), sequential Multispectral Atmospheric Mapping Sensor (MAMS) images were used in a study to calculate advective surface velocities using the Maximum Cross Correlation (MCC) technique. Radiance and brightness temperature gradient magnitude images were formed from visible (0.48 microns) and infrared (11.12 microns) image pairs, respectively, of Chandeleur Sound, which is a shallow body of water northeast of the Mississippi delta, at 145546 GMT and 170701 GMT on 30 Mar. 1989. The gradient magnitude images enhanced the surface water feature boundaries, and a lower cutoff on the gradient magnitudes calculated allowed the undesirable sunglare and backscatter gradients in the visible images, and the water vapor absorption gradients in the infrared images, to be reduced in strength. Requiring high (greater than 0.4) maximum cross correlation coefficients and spatial coherence of the vector field aided in the selection of an optimal template size of 10 x 10 pixels (first image) and search limit of 20 pixels (second image) to use in the MCC technique. Use of these optimum input parameters to the MCC algorithm, and high correlation and spatial coherence filtering of the resulting velocity field from the MCC calculation yielded a clustered velocity distribution over the visible and infrared gradient images. The velocity field calculated from the visible gradient image pair agreed well with a subjective analysis of the motion, but the velocity field from the infrared gradient image pair did not. This was attributed to the changing shapes of the gradient features, their nonuniqueness, and large displacements relative to the mean distance between them. These problems implied a lower repeat time for the imagery was needed in order to improve the velocity field derived from gradient imagery. Suggestions are given for optimizing the repeat time of sequential imagery when using the MCC method for motion studies. Applying the MCC method to the infrared

  14. TIME-DEPENDENT INFRARED STUDIES.

    DTIC Science & Technology

    INFRARED RESEARCH, TIME , INFRARED PHENOMENA, INFRARED RADIATION, INFRARED SPECTROSCOPY, HIGH ALTITUDE, SOLAR ATMOSPHERE, TRANSMISSIONS(MECHANICAL), VIBRATION, QUANTUM THEORY, CALIBRATION, INFRARED SCANNING.

  15. Synergy between middle infrared and millimeter-wave limb sounding of atmospheric temperature and minor constituents

    NASA Astrophysics Data System (ADS)

    Cortesi, Ugo; Del Bianco, Samuele; Ceccherini, Simone; Gai, Marco; Dinelli, Bianca Maria; Castelli, Elisa; Oelhaf, Hermann; Woiwode, Wolfgang; Höpfner, Michael; Gerber, Daniel

    2016-05-01

    Synergistic exploitation of redundant and complementary information from independent observations of the same target remains a major issue in atmospheric remote sounding and increasing attention is devoted to investigate optimized or innovative methods for the combination of two or more measured data sets. This paper focuses on the synergy between middle infrared and millimeter-wave limb sounding measurements of atmospheric composition and temperature and reports the results of a study conducted as part of the preparatory activities of the PREMIER (Process Exploration through Measurements of Infrared and millimeter-wave Emitted Radiation) mission candidate to the Core Missions of the European Space Agency (ESA) Earth Explorer 7. The activity was based on data acquired by the MIPAS-STR (Michelson Interferometer for Passive Atmospheric Sounding - STRatospheric aircraft) and MARSCHALS (Millimetre-wave Airborne Receivers for Spectroscopic CHaracterisation in Atmospheric Limb Sounding) instruments on-board the high-altitude research aircraft M-55 Geophysica during the flight of the PremierEx (PREMIER Experiment) campaign on 10 March 2010 from Kiruna, Sweden, for observation of the Arctic upper troposphere and lower stratosphere. The cloud coverage observed along the flight provided representative test cases to evaluate the synergy in three different scenarios: low clouds in the first part, no clouds in the central part and high tropospheric clouds at the end. The calculation of synergistic profiles of four atmospheric targets (i.e., O3, HNO3, H2O and temperature) was performed using a posteriori combination of individual retrieved profiles, i.e., Level 2 (L2) data rather than simultaneous inversion of observed radiances, i.e., Level 1 (L1) data. An innovative method of data fusion, based on the Measurement Space Solution (MSS) was applied along with the standard approach of inversion of MARSCHALS spectral radiances using MIPAS-STR retrieval products as a priori

  16. Synergy between middle infrared and millimetre-wave limb sounding of atmospheric temperature and minor constituents

    NASA Astrophysics Data System (ADS)

    Cortesi, U.; Del Bianco, S.; Ceccherini, S.; Gai, M.; Dinelli, B. M.; Castelli, E.; Oelhaf, H.; Woiwode, W.; Höpfner, M.; Gerber, D.

    2015-11-01

    Synergistic exploitation of redundant and complementary information from independent observations of the same target remains a major issue in atmospheric remote-sounding and increasing attention is devoted to investigate optimised or innovative methods for the combination of two or more measured data sets. This paper is focusing on the synergy between middle infrared and millimetre-wave limb sounding measurements of atmospheric composition and temperature and reports the results of a study conducted as part of the preparatory activities of the PREMIER (Process Exploration through Measurements of Infrared and millimetre wave Emitted Radiation) mission candidate to the Core Missions of ESA Earth Explorer 7. The activity was based on data acquired by the MIPAS-STR (Michelson Interferometer for Passive Atmospheric Sounding - STRatospheric aircraft) and MARSCHALS (Millimetre-wave Airborne Receivers for Spectroscopic CHaracterisation in Atmospheric Limb Sounding) instruments onboard the high altitude research aircraft M-55 Geophysica during the flight of the PremierEx (PREMIER Experiment) campaign on 10 March 2010 from Kiruna, Sweden for observation of the Arctic upper troposphere and lower stratosphere. The cloud coverage observed along the flight provided representative test cases to evaluate the synergy in three different scenarios: low clouds in the first part, no clouds in the central part and high tropospheric clouds at the end. The calculation of synergistic profiles of four atmospheric targets (i.e., O2, HNO3, H2O and temperature) was performed using a posteriori combination of individual retrieved profiles, i.e., Level 2 (L2) data rather than simultaneous inverse processing of observed radiances, i.e., Level 1 (L1) data. An innovative method of data fusion, based on the Measurement Space Solution (MSS) was applied along with the standard approach of inverse processing of MARSCHALS spectral radiances using MIPAS-STR retrieval products as a priori information (L1

  17. Atmospheric effects on extensive air showers observed with the surface detector of the Pierre Auger observatory

    NASA Astrophysics Data System (ADS)

    Pierre Auger Collaboration; Abraham, J.; Abreu, P.; Aglietta, M.; Aguirre, C.; Ahn, E. J.; Allard, D.; Allekotte, I.; Allen, J.; Allison, P.; Alvarez-Muñiz, J.; Ambrosio, M.; Anchordoqui, L.; Andringa, S.; Anzalone, A.; Aramo, C.; Arganda, E.; Argirò, S.; Arisaka, K.; Arneodo, F.; Arqueros, F.; Asch, T.; Asorey, H.; Assis, P.; Aublin, J.; Ave, M.; Avila, G.; Bäcker, T.; Badagnani, D.; Barber, K. B.; Barbosa, A. F.; Barroso, S. L. C.; Baughman, B.; Bauleo, P.; Beatty, J. J.; Beau, T.; Becker, B. R.; Becker, K. H.; Bellétoile, A.; Bellido, J. A.; Benzvi, S.; Berat, C.; Bernardini, P.; Bertou, X.; Biermann, P. L.; Billoir, P.; Blanch-Bigas, O.; Blanco, F.; Bleve, C.; Blümer, H.; Boháčová, M.; Bonifazi, C.; Bonino, R.; Borodai, N.; Brack, J.; Brogueira, P.; Brown, W. C.; Bruijn, R.; Buchholz, P.; Bueno, A.; Burton, R. E.; Busca, N. G.; Caballero-Mora, K. S.; Caramete, L.; Caruso, R.; Carvalho, W.; Castellina, A.; Catalano, O.; Cazon, L.; Cester, R.; Chauvin, J.; Chiavassa, A.; Chinellato, J. A.; Chou, A.; Chudoba, J.; Chye, J.; Clay, R. W.; Colombo, E.; Conceição, R.; Connolly, B.; Contreras, F.; Coppens, J.; Cordier, A.; Cotti, U.; Coutu, S.; Covault, C. E.; Creusot, A.; Criss, A.; Cronin, J.; Curutiu, A.; Dagoret-Campagne, S.; Dallier, R.; Daumiller, K.; Dawson, B. R.; de Almeida, R. M.; de Domenico, M.; de Donato, C.; de Jong, S. J.; de La Vega, G.; de Mello, W. J. M.; de Mello Neto, J. R. T.; de Mitri, I.; de Souza, V.; de Vries, K. D.; Decerprit, G.; Del Peral, L.; Deligny, O.; Della Selva, A.; Delle Fratte, C.; Dembinski, H.; di Giulio, C.; Diaz, J. C.; Diep, P. N.; Dobrigkeit, C.; D'Olivo, J. C.; Dong, P. N.; Dornic, D.; Dorofeev, A.; Dos Anjos, J. C.; Dova, M. T.; D'Urso, D.; Dutan, I.; Duvernois, M. A.; Engel, R.; Erdmann, M.; Escobar, C. O.; Etchegoyen, A.; Facal San Luis, P.; Falcke, H.; Farrar, G.; Fauth, A. C.; Fazzini, N.; Ferrer, F.; Ferrero, A.; Fick, B.; Filevich, A.; Filipčič, A.; Fleck, I.; Fliescher, S.; Fracchiolla, C. E.; Fraenkel, E. D.; Fulgione, W.; Gamarra, R. F.; Gambetta, S.; García, B.; García Gámez, D.; Garcia-Pinto, D.; Garrido, X.; Gelmini, G.; Gemmeke, H.; Ghia, P. L.; Giaccari, U.; Giller, M.; Glass, H.; Goggin, L. M.; Gold, M. S.; Golup, G.; Gomez Albarracin, F.; Gómez Berisso, M.; Gonçalves, P.; Gonçalves Do Amaral, M.; Gonzalez, D.; Gonzalez, J. G.; Góra, D.; Gorgi, A.; Gouffon, P.; Grashorn, E.; Grebe, S.; Grigat, M.; Grillo, A. F.; Guardincerri, Y.; Guarino, F.; Guedes, G. P.; Gutiérrez, J.; Hague, J. D.; Halenka, V.; Hansen, P.; Harari, D.; Harmsma, S.; Harton, J. L.; Haungs, A.; Healy, M. D.; Hebbeker, T.; Hebrero, G.; Heck, D.; Hojvat, C.; Holmes, V. C.; Homola, P.; Hörandel, J. R.; Horneffer, A.; Hrabovský, M.; Huege, T.; Hussain, M.; Iarlori, M.; Insolia, A.; Ionita, F.; Italiano, A.; Jiraskova, S.; Kaducak, M.; Kampert, K. H.; Karova, T.; Kasper, P.; Kégl, B.; Keilhauer, B.; Kemp, E.; Kieckhafer, R. M.; Klages, H. O.; Kleifges, M.; Kleinfeller, J.; Knapik, R.; Knapp, J.; Koang, D.-H.; Krieger, A.; Krömer, O.; Kruppke-Hansen, D.; Kuempel, D.; Kunka, N.; Kusenko, A.; La Rosa, G.; Lachaud, C.; Lago, B. L.; Lautridou, P.; Leão, M. S. A. B.; Lebrun, D.; Lebrun, P.; Lee, J.; Leigui de Oliveira, M. A.; Lemiere, A.; Letessier-Selvon, A.; Leuthold, M.; Lhenry-Yvon, I.; López, R.; Lopez Agüera, A.; Louedec, K.; Lozano Bahilo, J.; Lucero, A.; Luna García, R.; Lyberis, H.; Maccarone, M. C.; Macolino, C.; Maldera, S.; Mandat, D.; Mantsch, P.; Mariazzi, A. G.; Maris, I. C.; Marquez Falcon, H. R.; Martello, D.; Martínez, J.; Martínez Bravo, O.; Mathes, H. J.; Matthews, J.; Matthews, J. A. J.; Matthiae, G.; Maurizio, D.; Mazur, P. O.; McEwen, M.; McNeil, R. R.; Medina-Tanco, G.; Melissas, M.; Melo, D.; Menichetti, E.; Menshikov, A.; Meyhandan, R.; Micheletti, M. I.; Miele, G.; Miller, W.; Miramonti, L.; Mollerach, S.; Monasor, M.; Monnier Ragaigne, D.; Montanet, F.; Morales, B.; Morello, C.; Moreno, J. C.; Morris, C.; Mostafá, M.; Moura, C. A.; Mueller, S.; Muller, M. A.; Mussa, R.; Navarra, G.; Navarro, J. L.; Navas, S.; Necesal, P.; Nellen, L.; Newman-Holmes, C.; Newton, D.; Nhung, P. T.; Nierstenhoefer, N.; Nitz, D.; Nosek, D.; Nožka, L.; Nyklicek, M.; Oehlschläger, J.; Olinto, A.; Oliva, P.; Olmos-Gilbaja, V. M.; Ortiz, M.; Ortolani, F.; Pacheco, N.; Pakk Selmi-Dei, D.; Palatka, M.; Pallotta, J.; Parente, G.; Parizot, E.; Parlati, S.; Pastor, S.; Patel, M.; Paul, T.; Pavlidou, V.; Payet, K.; Pech, M.; PeĶala, J.; Pelayo, R.; Pepe, I. M.; Perrone, L.; Pesce, R.; Petermann, E.; Petrera, S.; Petrinca, P.; Petrolini, A.; Petrov, Y.; Petrovic, J.; Pfendner, C.; Piegaia, R.; Pierog, T.; Pimenta, M.; Pinto, T.; Pirronello, V.; Pisanti, O.; Platino, M.; Pochon, J.; Ponce, V. H.; Pontz, M.; Privitera, P.; Prouza, M.; Quel, E. J.; Rautenberg, J.; Ravel, O.; Ravignani, D.; Redondo, A.; Reucroft, S.; Revenu, B.; Rezende, F. A. S.; Ridky, J.; Riggi, S.; Risse, M.; Rivière, C.; Rizi, V.; Robledo, C.; Rodriguez, G.; Rodriguez Martino, J.; Rodriguez Rojo, J.; Rodriguez-Cabo, I.; Rodríguez-Frías, M. D.; Ros, G.; Rosado, J.; Rossler, T.; Roth, M.; Rouillé-D'Orfeuil, A.; Roulet, E.; Rovero, A. C.; Salamida, F.; Salazar, H.; Salina, G.; Sánchez, F.; Santander, M.; Santo, C. E.; Santos, E. M.; Sarazin, F.; Sarkar, S.; Sato, R.; Scharf, N.; Scherini, V.; Schieler, H.; Schiffer, P.; Schmidt, A.; Schmidt, F.; Schmidt, T.; Scholten, O.; Schoorlemmer, H.; Schovancova, J.; Schovánek, P.; Schroeder, F.; Schulte, S.; Schüssler, F.; Schuster, D.; Sciutto, S. J.; Scuderi, M.; Segreto, A.; Semikoz, D.; Settimo, M.; Shellard, R. C.; Sidelnik, I.; Siffert, B. B.; Smiałkowski, A.; Šmída, R.; Smith, B. E.; Snow, G. R.; Sommers, P.; Sorokin, J.; Spinka, H.; Squartini, R.; Strazzeri, E.; Stutz, A.; Suarez, F.; Suomijärvi, T.; Supanitsky, A. D.; Sutherland, M. S.; Swain, J.; Szadkowski, Z.; Tamashiro, A.; Tamburro, A.; Tarutina, T.; Taşcău, O.; Tcaciuc, R.; Tcherniakhovski, D.; Thao, N. T.; Thomas, D.; Ticona, R.; Tiffenberg, J.; Timmermans, C.; Tkaczyk, W.; Todero Peixoto, C. J.; Tomé, B.; Tonachini, A.; Torres, I.; Travnicek, P.; Tridapalli, D. B.; Tristram, G.; Trovato, E.; Tuci, V.; Tueros, M.; Ulrich, R.; Unger, M.; Urban, M.; Valdés Galicia, J. F.; Valiño, I.; Valore, L.; van den Berg, A. M.; Vázquez, J. R.; Vázquez, R. A.; Veberič, D.; Velarde, A.; Venters, T.; Verzi, V.; Videla, M.; Villaseñor, L.; Vorobiov, S.; Voyvodic, L.; Wahlberg, H.; Wahrlich, P.; Wainberg, O.; Warner, D.; Watson, A. A.; Westerhoff, S.; Whelan, B. J.; Wieczorek, G.; Wiencke, L.; Wilczyńska, B.; Wilczyński, H.; Wileman, C.; Winnick, M. G.; Wu, H.; Wundheiler, B.; Yamamoto, T.; Younk, P.; Yuan, G.; Zas, E.; Zavrtanik, D.; Zavrtanik, M.; Zaw, I.; Zepeda, A.; Ziolkowski, M.

    2009-09-01

    Atmospheric parameters, such as pressure (P), temperature (T) and density (ρ∝P/T), affect the development of extensive air showers initiated by energetic cosmic rays. We have studied the impact of atmospheric variations on extensive air showers by means of the surface detector of the Pierre Auger Observatory. The rate of events shows a ˜10% seasonal modulation and ˜2% diurnal one. We find that the observed behaviour is explained by a model including the effects associated with the variations of P and ρ. The former affects the longitudinal development of air showers while the latter influences the Molière radius and hence the lateral distribution of the shower particles. The model is validated with full simulations of extensive air showers using atmospheric profiles measured at the site of the Pierre Auger Observatory.

  18. Dispersive infrared spectroscopy measurements of atmospheric CO₂ using a Fabry-Pérot interferometer sensor.

    PubMed

    Chan, K L; Ning, Z; Westerdahl, D; Wong, K C; Sun, Y W; Hartl, A; Wenig, M O

    2014-02-15

    In this paper, we present the first dispersive infrared spectroscopic (DIRS) measurement of atmospheric carbon dioxide (CO2) using a new scanning Fabry-Pérot interferometer (FPI) sensor. The sensor measures the optical spectra in the mid infrared (3,900 nm to 5,220 nm) wavelength range with full width half maximum (FWHM) spectral resolution of 78.8 nm at the CO2 absorption band (~4,280 nm) and sampling resolution of 20 nm. The CO2 concentration is determined from the measured optical absorption spectra by fitting it to the CO2 reference spectrum. Interference from other major absorbers in the same wavelength range, e.g., carbon monoxide (CO) and water vapor (H2O), was taken out by including their reference spectra in the fit as well. The detailed descriptions of the instrumental setup, the retrieval procedure, a modeling study for error analysis as well as laboratory validation using standard gas concentrations are presented. An iterative algorithm to account for the non-linear response of the fit function to the absorption cross sections due to the broad instrument function was developed and tested. A modeling study of the retrieval algorithm showed that errors due to instrument noise can be considerably reduced by using the dispersive spectral information in the retrieval. The mean measurement error of the prototype DIRS CO2 measurement for 1 minute averaged data is about ±2.5 ppmv, and down to ± 0.8ppmv for 10 minute averaged data. A field test of atmospheric CO2 measurements were carried out in an urban site in Hong Kong for a month and compared to a commercial non-dispersive infrared (NDIR) CO2 analyzer. 10 minute averaged data shows good agreement between the DIRS and NDIR measurements with Pearson correlation coefficient (R) of 0.99. This new method offers an alternative approach of atmospheric CO2 measurement featuring high accuracy, correction of non-linear absorption and interference of water vapor.

  19. Mid-Infrared OPO for High Resolution Measurements of Trace Gases in the Mars Atmosphere

    NASA Technical Reports Server (NTRS)

    Yu, Anthony W.; Numata,Kenji; Riris, haris; Abshire, James B.; Allan, Graham; Sun, Xiaoli; Krainak, Michael A.

    2008-01-01

    The Martian atmosphere is composed primarily (>95%) of CO2 and N2 gas, with CO, O2, CH4, and inert gases such as argon comprising most of the remainder. It is surprisingly dynamic with various processes driving changes in the distribution of CO2, dust, haze, clouds and water vapor on global scales in the meteorology of Mars atmosphere [I]. The trace gases and isotopic ratios in the atmosphere offer important but subtle clues as to the origins of the planet's atmosphere, hydrology, geology, and potential for biology. In the search for life on Mars, an important process is the ability of bacteria to metabolize inorganic substrates (H2, CO2 and rock) to derive energy and produce methane as a by-product of anaerobic metabolism. Trace gases have been measured in the Mars atmosphere from Earth, Mars orbit, and from the Mars surface. The concentration of water vapor and various carbon-based trace gases are observed in variable concentrations. Within the past decade multiple groups have reported detection of CH4, with concentrations in the 10's of ppb, using spectroscopic observations from Earth [2]. Passive spectrometers in the mid-infrared (MIR) are restricted to the sunlit side of the planet, generally in the mid latitudes, and have limited spectral and spatial resolution. To accurately map the global distribution and to locate areas of possibly higher concentrations of these gases such as plumes or vents requires an instrument with high sensitivity and fine spatial resolution that also has global coverage and can measure during both day and night. Our development goal is a new MIR lidar capable of measuring, on global scales, with sensitivity, resolution and precision needed to characterize the trace gases and isotopic ratios of the Martian atmosphere. An optical parametric oscillator operating in the MIR is well suited for this instrument. The sufficient wavelength tuning range of the OPO can extend the measurements to other organic molecules, CO2, atmospheric water

  20. Atmospheric profiles at the southern Pierre Auger Observatory and their relevance to air shower measurement

    SciTech Connect

    Keilhauer, B.; Bluemer, J.; Engel, R.; Gora, D.; Homola, P.; Klages, H.; Pekala, J.; Risse, M.; Unger, M.; Wilczynska, B.; Wilczynski, H.

    2005-07-01

    The dependence of atmospheric conditions on altitude and time have to be known at the site of an air shower experiment for accurate reconstruction of extensive air showers and their simulations. The height-profile of atmospheric depth is of particular interest as it enters directly into the reconstruction of longitudinal shower development and of the primary energy and mass of cosmic rays. For the southern part of the Auger Observatory, the atmosphere has been investigated in a number of campaigns with meteorological radio soundings and with continuous measurements of ground-based weather stations. Focusing on atmospheric depth and temperature profiles, temporal variations are described and monthly profiles are developed. Uncertainties of the monthly atmospheres that are currently applied in the Auger reconstruction are discussed.

  1. Atmospheric measurements of volcanic eruptions with the infrared sounder IASI (Arne Richter Award for Outstanding Young Scientists Lecture)

    NASA Astrophysics Data System (ADS)

    Clarisse, L.

    2012-04-01

    Due to their spatial coverage, satellite sounders are ideal for measuring volcanic emissions. They are able to monitor (dormant) volcanoes in remote parts of the world and measure large plumes from explosive eruptions. Currently over a dozen instruments (operating in the IR and UV spectral ranges) are capable of detecting volcanic ash and/or sulphur dioxide. Satellite measurements are highly relevant for hazard mitigation, locally but also on large scales for air traffic avoidance of volcanic clouds. Their coverage enables to establish an accurate time-record of global volcanic emissions. This is useful from a volcanology perspective, but also for assessing the global climate impact of volcanic emissions. In this talk we give an overview of four years of measurements of large eruptive plumes from the high resolution infrared atmospheric sounding interferometer (IASI). The focus is on the detection and measurement of volcanic aerosol (volcanic ash, ice and sulphuric acid). In the second part of this talk, we discuss sulphur dioxide measurements and the recent first observations of hydrogen sulphide. We conclude with a discussion of open problems and challenges which lie ahead for the remote sensing of volcanic products.

  2. Simulation of the infrared signature of transient luminous events in the middle atmosphere for a limb line of sight

    NASA Astrophysics Data System (ADS)

    Romand, Frédéric; Croizé, Laurence; Payan, Sébastien; Huret, Nathalie

    2016-04-01

    Transient Luminous Events (TLE) are electrical and optical events which occurs above thunderstorms. Visual signatures are reported since the beginning of the 20th century but the first picture is accidentally recorded from a television camera in 1989. Their occurrence is closely linked with the lightning activity below thunderstorms. TLEs are observed from the base of the stratosphere to the thermosphere (15 - 110 km). They are a very brief phenomenon which lasts from 1 to 300 milliseconds. At a worldwide scale, four TLEs occur each minute. The energy deposition, about some tenth of megajoules, is able to ionize, dissociate and excite the molecules of the atmosphere. Atmospheric discharges in the troposphere are important sources of NO and NO2. TLEs might have the same effects at higher altitudes, in the stratosphere. NOx then can affect the concentration of O3 and OH. Consequently, TLEs could be locally important contributors to the chemical budget of the middle atmosphere. The perturbation of the atmospheric chemistry induced by TLEs has the consequence to locally modify the radiations in the infrared during the minutes following the event. The interest of studying the infrared signature of a TLE is twofold. For the atmospheric sciences it allows to link the perturbed composition to the resulting infrared spectrum. Then, some Defense systems like detection and guiding devices are equipped with airborne infrared sensors so that the TLE infrared signature might disturb them. We want to obtain a quantitative and kinetic evaluation of the infrared signature of the atmosphere locally perturbed by a TLE. In order to do so we must model three phenomena. 1) The plasma/chemistry coupling, which describes how the different energetic levels of atmospheric molecules are populated by the energetic deposition of the TLE. This step lasts the time of the lightning itself. 2) The chemical kinetics which describes how these populations will evolve in the following minutes. 3) The

  3. Theoretical model atmosphere spectra used for the calibration of infrared instruments

    NASA Astrophysics Data System (ADS)

    Decin, L.; Eriksson, K.

    2007-09-01

    Context: One of the key ingredients in establishing the relation between input signal and output flux from a spectrometer is accurate determination of the spectrophotometric calibration. In the case of spectrometers onboard satellites, the accuracy of this part of the calibration pedigree is ultimately linked to the accuracy of the set of reference spectral energy distributions (SEDs) that the spectrophotometric calibration is built on. Aims: In this paper, we deal with the spectrophotometric calibration of infrared (IR) spectrometers onboard satellites in the 2 to 200 μm wavelength range. We aim at comparing the different reference SEDs used for the IR spectrophotometric calibration. The emphasis is on the reference SEDs of stellar standards with spectral type later than A0, with special focus on the theoretical model atmosphere spectra. Methods: Using the MARCS model atmosphere code, spectral reference SEDs were constructed for a set of IR stellar standards (A dwarfs, solar analogs, G9-M0 giants). A detailed error analysis was performed to estimate proper uncertainties on the predicted flux values. Results: It is shown that the uncertainty on the predicted fluxes can be as high as 10%, but in case high-resolution observational optical or near-IR data are available, and IR excess can be excluded, the uncertainty on medium-resolution SEDs can be reduced to 1-2% in the near-IR, to ~3% in the mid-IR, and to ~5% in the far-IR. Moreover, it is argued that theoretical stellar atmosphere spectra are at the moment the best representations for the IR fluxes of cool stellar standards. Conclusions: When aiming at a determination of the spectrophotometric calibration of IR spectrometers better than 3%, effort should be put into constructing an appropriate set of stellar reference SEDs based on theoretical atmosphere spectra for some 15 standard stars with spectral types between A0 V and M0 III.

  4. Measurements of vertical air currents in the atmosphere

    NASA Technical Reports Server (NTRS)

    Lange, K O

    1931-01-01

    To summarize, the experiments with balloons, sailplanes and light airplanes conducted thus far, reveal the vertical velocities of the air to be primarily dependent on the vertical temperature distribution. Stable stratifications result in up-and-down currents forced by the contour of the ground, which are readily recognized in flight and, if need be, may be avoided.

  5. Technology Needs Assessment of an Atmospheric Observation System for Multidisciplinary Air Quality/Meteorology Missions, Part 2

    NASA Technical Reports Server (NTRS)

    Alvarado, U. R.; Bortner, M. H.; Grenda, R. N.; Brehm, W. F.; Frippel, G. G.; Alyea, F.; Kraiman, H.; Folder, P.; Krowitz, L.

    1982-01-01

    The technology advancements that will be necessary to implement the atmospheric observation systems are considered. Upper and lower atmospheric air quality and meteorological parameters necessary to support the air quality investigations were included. The technology needs were found predominantly in areas related to sensors and measurements of air quality and meteorological measurements.

  6. Retrievals of atmospheric variables on the gas giants from ground-based mid-infrared imaging

    NASA Astrophysics Data System (ADS)

    Fletcher, L. N.; Orton, G. S.; Yanamandra-Fisher, P.; Fisher, B. M.; Parrish, P. D.; Irwin, P. G. J.

    2009-03-01

    Thermal-infrared imaging of Jupiter and Saturn using the NASA/IRTF and Subaru observatories are quantitatively analyzed to assess the capabilities for reproducing and extending the zonal mean atmospheric results of the Cassini/CIRS experiment. We describe the development of a robust, systematic and reproducible approach to the acquisition and reduction of planetary images in the mid-infrared (7-25 μm), and perform an adaptation and validation of the optimal estimation, correlated- k retrieval algorithm described by Irwin et al. [Irwin, P., Teanby, N., de Kok, R., Fletcher, L., Howett, C., Tsang, C., Wilson, C., Calcutt, S., Nixon, C., Parrish, P., 2008. J. Quant. Spectrosc. Radiat. Trans. 109 (6), 1136-1150] for channel-integrated radiances. Synthetic spectral analyses and a comparison to Cassini results are used to verify our abilities to retrieve temperatures, haze opacities and gaseous abundances from filtered imaging. We find that ground-based imaging with a sufficiently high spatial resolution is able to reproduce the three-dimensional temperature and para-H 2 fields measured by spacecraft visiting Jupiter and Saturn, allowing us to investigate vertical wind shear, pressure and, with measured cloud-top winds, Ertel potential vorticity on potential temperature surfaces. Furthermore, by scaling vertical profiles of NH 3, PH 3, haze opacity and hydrocarbons as free parameters during thermal retrievals, we can produce meridional results comparable with CIRS spectroscopic investigations. This paper demonstrates that mid-IR imaging instruments operating at ground-based observatories have access to several dynamical and chemical diagnostics of the atmospheric state of the gas giants, offering the prospect for quantitative studies over much longer baselines and often covering much wider areas than is possible from spaceborne platforms.

  7. Contribution of ultraviolet and shortwave infrared observations to atmospheric correction of PACE ocean-color imagery

    NASA Astrophysics Data System (ADS)

    Frouin, Robert J.; Gross-Colzy, Lydwine S.

    2016-05-01

    The Pre-Aerosol, Cloud, and ocean Ecosystem (PACE) mission will carry into space a spectrometer measuring at 5 nm resolution in the ultraviolet (UV) to near infrared (NIR) and at lower resolution in spectral bands in the NIR and shortwave infrared (SWIR). These observations have great potential for improving estimates of marine reflectance in the post-EOS era. In view of this, we evaluate, using simulations with a coupled radiation transfer code, the gain in marine reflectance accuracy expected by including observations in the UV and SWIR compared with just using observations in the visible to NIR. The study is performed for the PACE threshold aggregate bands with respect to the standard set of bands used to generate ocean color products. The top-of-atmosphere (TOA) signal measured by the PACE spectrometer is simulated for a variety of realistic atmospheric and oceanic conditions. The TOA reflectance and the marine reflectance of the simulated ensemble are decomposed into principal components, and the components of the TOA reflectance sensitive to the ocean signal identified. Inverse models are constructed to retrieve the principal components of the marine reflectance, allowing a reconstruction, therefore an estimation of the marine reflectance. Theoretical performance is quantified as a function of angular geometry, aerosol properties, and water type, showing a significant improvement in retrieval accuracy when using the extended spectral range. On average over all the situations considered (including sun glint), the RMS error is reduced from 0.0037 to 0.0024 at 412 nm, from 0.0013 to 0.0007 at 665 nm, and from 0.0010 to 0.0004 at 865 nm (Case 2 waters are better handled). The performance is degraded at large zenith angles and aerosol optical thickness, is better at scattering angles around 120-130 degrees, and exhibits little dependence on aerosol single scattering albedo and aerosol scale height.

  8. Correcting infrared satellite estimates of sea surface temperature for atmospheric water vapor attenuation

    NASA Technical Reports Server (NTRS)

    Emery, William J.; Yu, Yunyue; Wick, Gary A.; Schluessel, Peter; Reynolds, Richard W.

    1994-01-01

    A new satellite sea surface temperature (SST) algorithm is developed that uses nearly coincident measurements from the microwave special sensor microwave imager (SSM/I) to correct for atmospheric moisture attenuation of the infrared signal from the advanced very high resolution radiometer (AVHRR). This new SST algorithm is applied to AVHRR imagery from the South Pacific and Norwegian seas, which are then compared with simultaneous in situ (ship based) measurements of both skin and bulk SST. In addition, an SST algorithm using a quadratic product of the difference between the two AVHRR thermal infrared channels is compared with the in situ measurements. While the quadratic formulation provides a considerable improvement over the older cross product (CPSST) and multichannel (MCSST) algorithms, the SSM/I corrected SST (called the water vapor or WVSST) shows overall smaller errors when compared to both the skin and bulk in situ SST observations. Applied to individual AVHRR images, the WVSST reveals an SST difference pattern (CPSST-WVSST) similar in shape to the water vapor structure while the CPSST-quadratic SST difference appears unrelated in pattern to the nearly coincident water vapor pattern. An application of the WVSST to week-long composites of global area coverage (GAC) AVHRR data demonstrates again the manner in which the WVSST corrects the AVHRR for atmospheric moisture attenuation. By comparison the quadratic SST method underestimates the SST corrections in the lower latitudes and overestimates the SST in th e higher latitudes. Correlations between the AVHRR thermal channel differences and the SSM/I water vapor demonstrate the inability of the channel difference to represent water vapor in the midlatitude and high latitudes during summer. Compared against drifting buoy data the WVSST and the quadratic SST both exhibit the same general behavior with the relatively small differences with the buoy temperatures.

  9. Infrared radiation in the mesosphere and lower thermosphere: energetic effects and coupling with lower atmosphere

    NASA Astrophysics Data System (ADS)

    Feofilov, Artem; Kutepov, Alexander; Rezac, Ladislav

    2013-04-01

    The translational degrees of freedom of atmospheric molecular and atomic gaseous compounds represent the heat reservoir. This reservoir obtains or loses energy due to a number of sources and sinks, among them heating and cooling related to various types of mass motions, redistribution of energy released in the course of various photochemical reactions (the translational energy, the chemical energy and the nascent electronic, vibration and rotational energy of the reaction products), and absorption and emission of the infrared (IR) radiation. In the latter case, one deals with interaction between matter and the IR radiative field, which, for the case of the mesosphere/lower thermosphere (MLT), includes the atmospheric radiation formed in these layers, the upwelling radiation from the ground and lower atmosphere, and, during daytime, the IR solar radiation. In this talk, we address the energetic effects of IR radiation in the MLT and its radiative coupling with lower atmosphere by analyzing the interaction between IR radiation and matter. In the MLT, this interaction is strongly affected by the situation when vibrational (and in its upper part also rotational) excitation of the molecules does not obey Boltzmann's law with the local kinetic temperature. As a result, the IR radiation emitted in these layers does not reflect the thermal state of matter. This situation is referred to as the breakdown of local thermodynamic equilibrium (LTE) for the vibrational (or rotational-vibrational) degrees of freedom. Detailed treatment of non-LTE plays a crucial role for estimating thermal effects of the IR radiation as well as for the diagnostics of space-based IR observations. We discuss the peculiarities of the non-LTE radiation formation in the IR bands of CO2, O3, and H2O molecules, estimate radiative cooling/heating rates for typical atmospheric scenarios, and analyze sensitivity of the MLT radiative energy balance to various mechanisms of populating/depopulating molecular

  10. An integrated payload design for the Atmospheric Remote-sensing Infrared Exoplanet Large-survey (ARIEL)

    NASA Astrophysics Data System (ADS)

    Eccleston, Paul; Tinetti, Giovanna; Beaulieu, Jean-Philippe; Güdel, Manuel; Hartogh, Paul; Micela, Giuseppina; Min, Michiel; Rataj, Miroslaw; Ray, Tom; Ribas, Ignasi; Vandenbussche, Bart; Auguères, Jean-Louis; Bishop, Georgia; Da Deppo, Vania; Focardi, Mauro; Hunt, Thomas; Malaguti, Giuseppe; Middleton, Kevin; Morgante, Gianluca; Ollivier, Marc; Pace, Emanuele; Pascale, Enzo; Taylor, William

    2016-07-01

    ARIEL (the Atmospheric Remote-sensing Infrared Exoplanet Large-survey) is one of the three candidates for the next ESA medium-class science mission (M4) expected to be launched in 2026. This mission will be devoted to observing spectroscopically in the infrared a large population of warm and hot transiting exoplanets (temperatures from ~500 K to ~3000 K) in our nearby Galactic neighborhood, opening a new discovery space in the field of extrasolar planets and enabling the understanding of the physics and chemistry of these far away worlds. The three candidate missions for M4 are now in a Phase A study which will run until mid-2017 at which point one mission will be selected for implementation. ARIEL is based on a 1-m class telescope feeding both a moderate resolution spectrometer covering the wavelengths from 1.95 to 7.8 microns, and a four channel photometer (which also acts as a Fine Guidance Sensor) with bands between 0.55 and 1.65 microns. During its 3.5 years of operation from an L2 orbit, ARIEL will continuously observe exoplanets transiting their host star.

  11. A Southern Hemisphere atmospheric history of carbon monoxide from South Pole firn air

    NASA Astrophysics Data System (ADS)

    Verhulst, K. R.; Aydin, M.; Novelli, P. C.; Holmes, C. D.; Prather, M. J.; Saltzman, E. S.

    2013-12-01

    Carbon monoxide (CO) is a reactive trace gas and is important to tropospheric photochemistry as a major sink of hydroxyl radicals (OH). Major sources of CO are fossil fuel combustion, linked mostly to automotive emissions, biomass burning, and oxidation of atmospheric methane. Understanding changes in carbon monoxide over the past century will improve our understanding of man's influence on the reactivity of the atmosphere. Little observational information is available about CO levels and emissions prior to the 1990s, particularly for the Southern Hemisphere. The NOAA global flask network provides the most complete instrumental record of CO, extending back to 1988. Annually averaged surface flask measurements suggest atmospheric CO levels at South Pole were relatively stable from 2004-2009 at about 51 nmol mol-1 [Novelli and Masarie, 2013]. In this study, a 20th century atmospheric history of CO is reconstructed from South Pole firn air measurements, using a 1-D firn air diffusion model. Firn air samples were collected in glass flasks from two adjacent holes drilled from the surface to 118 m at South Pole, Antarctica during the 2008/2009 field season and CO analysis was carried out by NOAA/CCG. Carbon monoxide levels increase from about 45 nmol mol-1 in the deepest firn sample at 116 m to 52 nmol mol-1 at 107 m, and remain constant at about 51-52 nmol mol-1 at shallower depths. Atmospheric histories based on the firn air reconstructions suggest that CO levels over Antarctica increased by roughly 40% (from about 36 to 50 nmol mol-1) between 1930-1990, at a rate of about 0.18 nmol mol-1 yr-1. Firn air and surface air results suggest the rate of CO increase at South Pole slowed considerably after 1990. The firn air-based atmospheric history is used to infer changes in Southern Hemisphere CO emissions over the 20th century.

  12. Drying and decontamination of raw pistachios with sequential infrared drying, tempering and hot air drying.

    PubMed

    Venkitasamy, Chandrasekar; Brandl, Maria T; Wang, Bini; McHugh, Tara H; Zhang, Ruihong; Pan, Zhongli

    2017-04-04

    Pistachio nuts have been associated with outbreaks of foodborne disease and the industry has been impacted by numerous product recalls due to contamination with Salmonella enterica. The current hot air drying of pistachios has low energy efficiency and drying rates, and also does not guarantee the microbial safety of products. In the study described herein, dehulled and water-sorted pistachios with a moisture content (MC) of 38.14% (wet basis) were dried in a sequential infrared and hot air (SIRHA) drier to <9% MC. The decontamination efficacy was assessed by inoculating pistachios with Enterococcus faecium, a surrogate of Salmonella enterica used for quality control in the almond industry. Drying with IR alone saved 105min (34.4%) of drying time compared with hot air drying. SIRHA drying of pistachios for 2h with infrared (IR) heat followed by tempering at a product temperature of 70°C for 2h and then by hot air drying shortened the drying time by 40min (9.1%) compared with drying by hot air only. This SIRHA method also reduced the E. faecium cell population by 6.1-logCFU/g kernel and 5.41-logCFU/g shell of pistachios. The free fatty acid contents of SIRHA dried pistachios were on par with that of hot air dried samples. Despite significant differences in peroxide values (PV) of pistachio kernels dried with the SIRHA method compared with hot air drying at 70°C, the PV were within the permissible limit of 5Meq/kg for edible oils. Our findings demonstrate the efficacy of SIRHA drying in achieving simultaneous drying and decontamination of pistachios.

  13. An objective definition of air mass types affecting Athens, Greece; the corresponding atmospheric pressure patterns and air pollution levels.

    PubMed

    Sindosi, O A; Katsoulis, B D; Bartzokas, A

    2003-08-01

    This work aims at defining characteristic air mass types that dominate in the region of Athens, Greece during the cold (November-March) and the warm (May-September) period of the year and also at evaluating the corresponding concentration levels of the main air pollutants. For each air mass type, the mean atmospheric pressure distribution (composite maps) over Europe and the Mediterranean is estimated in order to reveal the association of atmospheric circulation with air pollution levels in Athens. The data basis for this work consists of daily values of thirteen meteorological and six pollutant parameters covering the period 1993-97. The definition of the characteristic air mass types is attempted objectively by using the methods of Factor Analysis and Cluster Analysis. The results show that during the cold period of the year there are six prevailing air mass types (at least 3% of the total number of days) and six infrequent ones. The examination of the corresponding air pollution concentration levels shows that the primary air pollutants appear with increased concentrations when light or southerly winds prevail. This is usually the case when a high pressure system is located over the central Mediterranean or a low pressure system lays over south Italy, respectively. Low levels of the primary pollutants are recorded under northeasterly winds, mainly caused by a high pressure system over Ukraine. During the warm period of the year, the southwestern Asia thermal low and the subtropical anticyclone of the Atlantic Ocean affect Greece. Though these synoptic systems cause almost stagnant conditions, four main air mass types are dominant and ten others, associated with extreme weather, are infrequent. Despite the large amounts of total solar radiation characterizing this period, ozone concentrations remain at low levels in central Athens because of its destruction by nitric oxide.

  14. Flush Air Data Sensing System for Trans-Atmospheric Vehicles

    NASA Astrophysics Data System (ADS)

    Ellsworth, Joel

    2006-10-01

    With the emergence of multiple companies attempting to tap the space tourism market, as well as NASA's return to the moon initiative, an inexpensive but reliable means of determining wind relative vehicle attitude is becoming a necessity. The traditional means of obtaining air data (altitude, Mach number, angles of attack and sideslip) using fixed pitot probes and directional flow vanes is not viable for collecting data on high supersonic and hypersonic vehicles, due to the high temperatures and dynamic pressures. The solution is to use a matrix of flush mounted pressure ports on the vehicle nose or on an outboard wing leading edge. Since the ports will be located behind a detached shock wave at supersonic velocities, the temperatures will remain substantially lower. A Flush Air Data Sensing (FADS) system can also be used for subsonic conditions, although it must be calibrated for the effects of the vehicle geometry. The physics of air behavior and the mathematics of the solution algorithm will be presented. Several relevant examples of planned vehicles will be presented.

  15. Infrared Radiative Forcing and Atmospheric Lifetimes of Trace Species Based on Observations from UARS

    NASA Technical Reports Server (NTRS)

    Minschwaner, K.; Carver, R. W.; Briegleb, B. P.

    1997-01-01

    Observations from instruments on the Upper Atmosphere Research Satellite (UARS) have been used to constrain calculations of infrared radiative forcing by CH4, CCl2F2 and N2O, and to determine lifetimes Of CCl2F2 and N2O- Radiative forcing is calculated as a change in net infrared flux at the tropopause that results from an increase in trace gas amount from pre-industrial (1750) to contemporary (1992) times. Latitudinal and seasonal variations are considered explicitly, using distributions of trace gases and temperature in the stratosphere from UARS measurements and seasonally averaged cloud statistics from the International Satellite Cloud Climatology Project. Top-of-atmosphere fluxes calculated for the contemporary period are in good agreement with satellite measurements from the Earth Radiation Budget Experiment. Globally averaged values of the radiative forcing are 0.536, 0.125, and 0.108 W m-2 for CH4, CCl2F2, and N2O, respectively. The largest forcing occurs near subtropical latitudes during summer, predominantly as a result of the combination of cloud-free skies and a high, cold tropopause. Clouds are found to play a significant role in regulating infrared forcing, reducing the magnitude of the forcing by 30-40% compared to the case of clear skies. The vertical profile of CCl2F2 is important in determining its radiative forcing; use of a height-independent mixing ratio in the stratosphere leads to an over prediction of the forcing by 10%. The impact of stratospheric profiles on radiative forcing by CH4 and N2O is less than 2%. UARS-based distributions of CCl2F2 and N2O are used also to determine global destruction rates and instantaneous lifetimes of these gases. Rates of photolytic destruction in the stratosphere are calculated using solar ultraviolet irradiances measured on UARS and a line-by-line model of absorption in the oxygen Schumann-Runge bands. Lifetimes are 114 +/- 22 and 118 +/- 25 years for CCl2F2 and N2O, respectively.

  16. Organics in the atmosphere: From air pollution to biogeochemical cycles and climate (Vilhelm Bjerknes Medal)

    NASA Astrophysics Data System (ADS)

    Kanakidou, Maria

    2016-04-01

    Organics are key players in the biosphere-atmosphere-climate interactions. They have also a significant anthropogenic component due to primary emissions or interactions with pollution. The organic pool in the atmosphere is a complex mixture of compounds of variable reactivity and properties, variable content in C, H, O, N and other elements depending on their origin and their history in the atmosphere. Multiphase atmospheric chemistry is known to produce organic acids with high oxygen content, like oxalic acid. This water soluble organic bi-acid is used as indicator for cloud processing and can form complexes with atmospheric Iron, affecting Iron solubility. Organics are also carriers of other nutrients like nitrogen and phosphorus. They also interact with solar radiation and with atmospheric water impacting on climate. In line with this vision for the role of organics in the atmosphere, we present results from a global 3-dimensional chemistry-transport model on the role of gaseous and particulate organics in atmospheric chemistry, accounting for multiphase chemistry and aerosol ageing in the atmosphere as well as nutrients emissions, atmospheric transport and deposition. Historical simulations and projections highlight the human impact on air quality and atmospheric deposition to the oceans. The results are put in the context of climate change. Uncertainties and implications of our findings for biogeochemical and climate modeling are discussed.

  17. Visible and infrared extinction of atmospheric aerosol in the marine and coastal environment.

    PubMed

    Kaloshin, Gennady A

    2011-05-10

    The microphysical model Marine Aerosol Extinction Profiles (MaexPro) for surface layer marine and coastal atmospheric aerosols, which is based on long-term observations of size distributions for 0.01-100 μm particles, is presented. The fundamental feature of the model is a parameterization of amplitudes and widths for aerosol modes of the aerosol size distribution function (ASDF) as functions of fetch and wind speed. The shape of the ASDF and its dependence on meteorological parameters, altitudes above the sea level (H), fetch (X), wind speed (U), and relative humidity is investigated. The model is primarily to characterize aerosols for the near-surface layer (within 25 m). The model is also applicable to higher altitudes within the atmospheric boundary layer, where the change in the vertical profile of aerosol is not very large. In this case, it is only valid for "clean" marine environments, in the absence of air pollution or any other major sources of continental aerosols, such desert dust or smoke from biomass burning. The spectral profiles of the aerosol extinction coefficients calculated by MaexPro are in good agreement with observational data and the numerical results obtained by the well-known Navy Aerosol Model and Advanced Navy Aerosol Model codes. Moreover, MaexPro was found to be an accurate and reliable instrument for investigation of the optical properties of atmospheric aerosols.

  18. Pyroelectricity Assisted Infrared-Laser Desorption Ionization (PAI-LDI) for Atmospheric Pressure Mass Spectrometry

    NASA Astrophysics Data System (ADS)

    Li, Yanyan; Ma, Xiaoxiao; Wei, Zhenwei; Gong, Xiaoyun; Yang, Chengdui; Zhang, Sichun; Zhang, Xinrong

    2015-08-01

    A new atmospheric pressure ionization method termed pyroelectricity-assisted infrared laser desorption ionization (PAI-LDI) was developed in this study. The pyroelectric material served as both sample target plate and enhancing ionization substrate, and an IR laser with wavelength of 1064 nm was employed to realize direct desorption and ionization of the analytes. The mass spectra of various compounds obtained on pyroelectric material were compared with those of other substrates. For the five standard substances tested in this work, LiNbO3 substrate produced the highest ion yield and the signal intensity was about 10 times higher than that when copper was used as substrate. For 1-adamantylamine, as low as 20 pg (132.2 fmol) was successfully detected. The active ingredient in (Compound Paracetamol and 1-Adamantylamine Hydrochloride Capsules), 1-adamantylamine, can be sensitively detected at an amount as low as 150 pg, when the medicine stock solution was diluted with urine. Monosaccharide and oligosaccharides in Allium Cepa L. juice was also successfully identified with PAI-LDI. The method did not require matrix-assisted external high voltage or other extra facility-assisted set-ups for desorption/ionization. This study suggested exciting application prospect of pyroelectric materials in matrix- and electricity-free atmospheric pressure mass spectrometry research.

  19. Infrared spectra of van de Waals complexes of importance in planetary atmospheres

    NASA Technical Reports Server (NTRS)

    Fraser, G. T.; Pine, A. S.; Lafferty, W. J.

    1990-01-01

    It has been suggested that (CO2)2 and Ar-CO2 are important constituents of the planetary atmospheres of Venus and Mars. Recent results on the laboratory spectroscopy of CO2 containing van der Waals complexes which may be of use in the modeling of the spectra of planetary atmospheres are presented. Sub-Doppler infrared spectra were obtained for (CO2)2, (CO2)3, and rare-gas-CO2 complexes in the vicinity of the CO2 Fermi diad at 2.7 micrometers using a color-center-laser optothermal spectrometer. From the spectroscopic constants the geometries of the complexes have been determined and van der Waals vibrational frequencies have been estimated. The equilibrium configurations are C2h, C3h, and C2v, for (CO2)2, (CO2)3, and the rare-gas-CO2 complexes, respectively. Most of the homogeneous linewidths for the revibrational transitions range from 0.5 to 22 MHz, indicating that predissociation is as much as four orders of magnitude faster than radiative processes for vibrational relaxation in these complexes.

  20. Infrared characterisation of acetonitrile and propionitrile aerosols under Titan's atmospheric conditions.

    PubMed

    Ennis, C; Auchettl, R; Ruzi, M; Robertson, E G

    2017-01-25

    Pure, crystalline acetonitrile (CH3CN) and propionitrile (CH3CH2CN) particles were formed in a collisional cooling cell allowing for infrared (IR) signatures to be compiled from 50 to 5000 cm(-1). The cell temperature and pressure conditions were controlled to simulate Titan's lower atmosphere (80-130 K and 1-100 mbar), allowing for the comparison of laboratory data to the spectra obtained from the Cassini-Huygens mission. The far-IR features confirmed the morphology of CH3CN aerosols as the metastable β-phase (monoclinic) ice, however, a specific crystalline phase for CH3CH2CN could not be verified. Mie theory and the literature complex refractive indices enabled of the experimental spectra to be modelled. The procedure yielded size distributions for CH3CN (55-140 nm) and CH3CH2CN (140-160 nm) particles. Effective kinetic profiles, tracing the evolution of aerosol band intensities, showed that condensation of CH3CH2CN proceeded at twice the rate of CH3CN aerosols. In addition, the rate of CH3CH2CN aerosol depletion via lateral diffusion of the particles from the interrogation volume was approximately 50% faster than that of CH3CN. The far-IR spectra recorded for both nitrile aerosols did not display absorption profiles that could be attributed to the unassigned 220 cm(-1) feature, which has been observed to fluctuate seasonally in the spectra obtained from Titan's atmosphere.

  1. A lightweight near-infrared spectrometer for the detection of trace atmospheric species.

    PubMed

    Gardiner, T; Mead, M I; Garcelon, S; Robinson, R; Swann, N; Hansford, G M; Woods, P T; Jones, R L

    2010-08-01

    This paper describes the development and deployment of a lightweight in situ near-infrared tunable diode laser absorption spectrometer (TDLAS) for balloon-borne measurements of trace species such as methane in the upper troposphere and stratosphere. The key feature of the instrument design is its ability to provide high sensitivity measurements with better than 1 part in 10(6) Hz(-1/2) optical sensitivity in a lightweight package weighing as little as 6 kg, and maintaining this level of performance over the wide range of conditions experienced during field measurements. The absolute accuracy for methane measurements is approximately 10% limited by uncertainties in determining the gas temperature in the measurement volume. The high sensitivity and high temporal resolution (2.3 s measurement period) enables details of the fine-scale structure in the atmosphere to be measured. The TDLAS instrument has been used on a number of major international measurement campaigns. Intercomparison with other instruments during these campaigns have confirmed the comparability of the results from this instrument with measurements made by a range of other techniques, and demonstrated the instruments suitability for studies of atmospheric dynamics, transport, and mixing processes.

  2. Air pollution forecasting in Ankara, Turkey using air pollution index and its relation to assimilative capacity of the atmosphere.

    PubMed

    Genc, D Deniz; Yesilyurt, Canan; Tuncel, Gurdal

    2010-07-01

    Spatial and temporal variations in concentrations of CO, NO, NO(2), SO(2), and PM(10), measured between 1999 and 2000, at traffic-impacted and residential stations in Ankara were investigated. Air quality in residential areas was found to be influenced by traffic activities in the city. Pollutant ratios were proven to be reliable tracers to differentiate between different sources. Air pollution index (API) of the whole city was calculated to evaluate the level of air quality in Ankara. Multiple linear regression model was developed for forecasting API in Ankara. The correlation coefficients were found to be 0.79 and 0.63 for different time periods. The assimilative capacity of Ankara atmosphere was calculated in terms of ventilation coefficient (VC). The relation between API and VC was investigated and found that the air quality in Ankara was determined by meteorology rather than emissions.

  3. The temperature fields measurement of air in the car cabin by infrared camera

    NASA Astrophysics Data System (ADS)

    Pešek, M.

    2013-04-01

    The article deals with the temperature fields measurement of air using the Jenoptic Variocam infrared camera inside the car Škoda Octavia Combi II. The temperature fields with the use of auxiliary material with a high emissivity value were visualized. The measurements through the viewing window with a high transmissivity value were performed. The viewing windows on the side car door were placed. In the rear car area, the temperature fields of air on the spacious sheet of auxiliary material were visualized which is a suitable method for 2D airstreams. In the front car area, the temperature fields in the air were measured with the use of the measuring net which is suitable for 3D airstreams measuring.

  4. First Light from Jupiter: Initial Atmospheric and Satellite Results from the Near Infrared Mapping Spectrometer.

    NASA Astrophysics Data System (ADS)

    Carlson, R. W.; Galileo NIMS Team

    1996-09-01

    During late June 1996, the Galileo spacecraft obtained its first remote-sensing measurements within the Jovian system, and the Near Infrared Mapping Spectrometer (NIMS) performed spectroscopic and spectral mapping measurements of Jupiter's atmosphere and the surfaces of Ganymede and Callisto. The NIMS instrument represents a marriage of spectroscopic and imaging capabilities, the combination of which provides a powerful remote-sensing tool. A large number of molecules and minerals exhibit diagnostic spectral signatures in the NIMS range, thereby providing unique information for studying diverse phenomena and targets, including both atmospheres and solid surfaces. Our atmospheric measurements concentrated on two features: a 5 mu m hot spot and the Great Red Spot. Hot spots, within which one can probe the deep troposphere (down to the 8 bar region) and determine abundances of trace species (e.g. H2O, NH3, GeH4, PH3), have long been of interest in NIMS investigations, and this interest is heightened by the entry of the Galileo probe into such a region. Our preliminary analyses indicate less ammonia absorption within the observed hot spot, and water abundances consistent with the Probe measurements. For the Great Red Spot, we used the vertical sounding capability of absorption bands of differing strengths to determine the altitude structure of the clouds and the corresponding motions. Our satellite measurements consist of global spectral maps of Ganymede (100 km spatial resolution) and Callisto (650 km), and higher-spatial-resolution spectral images of selected targets on Ganymede. Derived compositional maps will be useful for studying the evolution and history of the satellite surfaces. Both Ganymede and Callisto show the presence of water and hydrated minerals in varying concentrations over their surfaces. A new absorption feature was found at 4.25 mu m, which is stronger in Callisto's spectrum. Candidate materials producing this feature include hydrates, hydroxides

  5. Using Infrared Laser Heterodyne Radiometry to Search for Methane in the Atmosphere of Mars

    NASA Astrophysics Data System (ADS)

    Passmore, Richard; Bowles, Neil; Weidmann, Damien; Smith, Kevin

    2010-05-01

    Introduction Methane has been detected in the atmosphere of Mars by several research teams in the last few years. Ground-based observations [1][2] and space-based instruments (e.g. the Planetary Fourier Transform spectrometer on Mars Express [3]) have reported low levels of methane gas (approximately 10 ppb) in the Martian atmosphere. Methane detection is important as its presence could imply a biological origin, and Martian methane sources are still unknown. However, current methane concentration measurements are at instruments' lower limits of detection. The viability of remote sensing using infrared laser heterodyne radiometry (LHR) to detect methane in the Martian atmosphere is investigated. The LHR technique allows high spectral resolution (greater than 0.001 cm-1) measurements over a narrow spectral range (~10 cm-1) when a distributed feedback quantum cascade laser (QCL) is used as local oscillator. The advantages of such an instrument, including its compact lightweight design, over current remote sensing spectral instruments are reviewed. The Laser Heterodyne Radiometer Laser heterodyne radiometers have been used extensively, and with much success, for atmospheric studies such as work on stratospheric ozone [4], mainly because the ultrahigh spectral resolution of the instrument allows fully resolved narrow molecular absorption line-shapes, which contain information on vertical concentration profiles. It has been shown that a carefully selected specific high resolution micro-window provides as much vertical profile information as a medium resolution radiometer covering a broad spectral range [5]. In addition to the high spectral resolution, the LHR is also extremely compact and robust and so has a significant advantage when targeting specific trace species over larger instruments such as high-resolution Fourier Transform spectrometers. Quantum Cascade Laser as Local Oscillator At the heart of the current generation infrared LHR is the use of a Quantum Cascade

  6. Carbon dioxide capture from atmospheric air using sodium hydroxide spray.

    PubMed

    Stolaroff, Joshuah K; Keith, David W; Lowry, Gregory V

    2008-04-15

    In contrast to conventional carbon capture systems for power plants and other large point sources, the system described in this paper captures CO2 directly from ambient air. This has the advantages that emissions from diffuse sources and past emissions may be captured. The objective of this research is to determine the feasibility of a NaOH spray-based contactor for use in an air capture system by estimating the cost and energy requirements per unit CO2 captured. A prototype system is constructed and tested to measure CO2 absorption, energy use, and evaporative water loss and compared with theoretical predictions. A numerical model of drop collision and coalescence is used to estimate operating parameters for a full-scale system, and the cost of operating the system per unit CO2 captured is estimated. The analysis indicates that CO2 capture from air for climate change mitigation is technically feasible using off-the-shelf technology. Drop coalescence significantly decreases the CO2 absorption efficiency; however, fan and pump energy requirements are manageable. Water loss is significant (20 mol H2O/mol CO2 at 15 degrees C and 65% RH) but can be lowered by appropriately designing and operating the system. The cost of CO2 capture using NaOH spray (excluding solution recovery and CO2 sequestration, which may be comparable) in the full-scale system is 96 $/ton-CO2 in the base case, and ranges from 53 to 127 $/ton-CO2 under alternate operating parameters and assumptions regarding capital costs and mass transfer rate. The low end of the cost range is reached by a spray with 50 microm mean drop diameter, which is achievable with commercially available spray nozzles.

  7. Modification of various metals by volume discharge in air atmosphere

    NASA Astrophysics Data System (ADS)

    Shulepov, Mikhail A.; Erofeev, Mikhail V.; Oskomov, Konstantin V.; Tarasenko, Victor F.

    2015-12-01

    The results of the modification of stainless steel, niobium and titanium by volume discharge induced by a beam of runaway electrons in air under normal pressure are presented. Changes in the chemical composition of the surface layers of metal by the action of the discharge, structural changes and changes of hardness were studied. It has been found that the concentration of oxygen and carbon in the surface layers of the samples depend on the number of discharge pulses. The aim of this work is to find possible application of this type of discharge in science and industrial production.

  8. Means of atmospheric air pollution reduction during drilling wells

    NASA Astrophysics Data System (ADS)

    Shkitsa, L.; Yatsyshyn, T.; Lyakh, M.; Sydorenko, O.

    2016-08-01

    The process of drilling oil and gas wells is the source of air pollution through drilling mud evaporation containing hazardous chemical substances. The constructive solution for cleaning device of downhole tool that contains elements covering tube and clean the surface from the mud in the process of rising from the well is offered. Inside the device is filled with magnetic fluid containing the substance neutralizing hazardous substances. The use of the equipment proposed will make it possible to avoid penetration of harmful substances into the environment and to escape the harmful effects of aggressive substances for staff health and increase rig's fire safety.

  9. A handheld low temperature atmospheric pressure air plasma gun for nanomaterial synthesis in liquid phase

    SciTech Connect

    Yu, Shuang; Wang, Kaile; Zuo, Shasha; Liu, Jiahui; Zhang, Jue Fang, Jing

    2015-10-15

    A handheld low temperature atmospheric pressure air plasma gun based on a dielectric barrier structure with hollow electrodes was proposed. The portable plasma gun with an embedded mini air pump was driven by a 12 V direct voltage battery. The air plasma jet generated from the gun could be touched without a common shock hazard. Besides working in air, the plasma gun can also work in water. The diagnostic result of optical emission spectroscopy showed the difference in reactive species of air plasma jet between in air and in water. The plasma gun was excited in 20 ml chloroauric acid aqueous solution with a concentration of 1.214 mM. A significant amount of gold nanoparticles were synthesized after 2 min continuous discharge. The plasma gun with these unique features is applicable in plasma medicine, etching, and s-nthesis of nanomaterials.

  10. A handheld low temperature atmospheric pressure air plasma gun for nanomaterial synthesis in liquid phase

    NASA Astrophysics Data System (ADS)

    Yu, Shuang; Wang, Kaile; Zuo, Shasha; Liu, Jiahui; Zhang, Jue; Fang, Jing

    2015-10-01

    A handheld low temperature atmospheric pressure air plasma gun based on a dielectric barrier structure with hollow electrodes was proposed. The portable plasma gun with an embedded mini air pump was driven by a 12 V direct voltage battery. The air plasma jet generated from the gun could be touched without a common shock hazard. Besides working in air, the plasma gun can also work in water. The diagnostic result of optical emission spectroscopy showed the difference in reactive species of air plasma jet between in air and in water. The plasma gun was excited in 20 ml chloroauric acid aqueous solution with a concentration of 1.214 mM. A significant amount of gold nanoparticles were synthesized after 2 min continuous discharge. The plasma gun with these unique features is applicable in plasma medicine, etching, and s-nthesis of nanomaterials.

  11. Influence of large-scale atmospheric circulation on marine air intrusion toward the East Antarctic coast

    NASA Astrophysics Data System (ADS)

    Kurita, Naoyuki; Hirasawa, Naohiko; Koga, Seizi; Matsushita, Junji; Steen-Larsen, Hans Christian; Masson-Delmotte, Valérie; Fujiyoshi, Yasushi

    2016-09-01

    Marine air intrusions into Antarctica play a key role in high-precipitation events. Here we use shipboard observations of water vapor isotopologues between Australia and Syowa on the East Antarctic coast to elucidate the mechanism by which large-scale circulation influences marine air intrusions. The temporal isotopic variations at Syowa reflect the meridional movement of a marine air front. They are also associated with atmospheric circulation anomalies that enhance the southward movement of cyclones over the Southern Ocean. The relationship between large-scale circulation and the movement of the front is explained by northerly winds which, in association with cyclones, move toward the Antarctic coast and push marine air with isotopically enriched moisture into the inland covered by glacial air with depleted isotopic values. Future changes in large-scale circulation may have a significant impact on the frequency and intensity of marine air intrusion into Antarctica.

  12. Atmospheric-pressure air microplasma jets in aqueous media for the inactivation of Pseudomonas fluorescens cells

    SciTech Connect

    Zhang, Xianhui; Yang, Si-ze; Liu, Dongping; Song, Ying; Sun, Yue

    2013-05-15

    The hollow fiber-based cold air microplasma jet array running at atmospheric pressure has been designed to inactivate Pseudomonas fluorescens (P. fluorescens) cells in vitro in aqueous media. The influences of electrode configurations, air flow rate, and applied voltage on the discharge characteristics of the single microplasma jet operating in aqueous media are presented, and the bactericidal efficiency of the hollow fibers-based and large-volume microplasma jet array is reported. Optical emission spectroscopy is utilized to identify excited species during the antibacterial testing of plasma in solutions. These well-aligned and rather stable air microplasma jets containing a variety of short-lived species, such as OH and O radicals and charged particles, are in direct contact with aqueous media and are very effective in killing P. fluorescens cells in aqueous media. This design shows its potential application for atmospheric pressure air plasma inactivation of bacteria cells in aqueous media.

  13. Internal gravity wave-atmospheric wind interaction - A cause of clear air turbulence.

    NASA Technical Reports Server (NTRS)

    Bekofske, K.; Liu, V. C.

    1972-01-01

    The interaction between an internal gravity wave (IGW) and a vertical wind shear is discussed as a possible cause in the production of clear air turbulence in the free atmosphere. It is shown that under certain typical condition the interaction of an IGW with a background wind shear near a critical level provides a mechanism for depositing sufficient momentum in certain regions of the atmosphere to significantly increase the local mean wind shear and to lead to the production of turbulence.

  14. Prediction of asthma exacerbations among children through integrating air pollution, upper atmosphere, and school health surveillances.

    PubMed

    Jayawardene, Wasantha Parakrama; Youssefagha, Ahmed Hassan; Lohrmann, David Kurt; El Afandi, Gamal Salah

    2013-01-01

    Climatic factors and air pollution are important in predicting asthma exacerbations among children. This study was designed to determine if a relationship exists between asthma exacerbations among elementary school children and the combined effect of daily upper atmosphere observations (temperature, relative humidity, dew point, and mixing ratio) and daily air pollution (particulate matter, sulfur dioxide, nitrogen dioxide, carbon monoxide, and ozone) and, if so, to predict asthma exacerbations among children using a mathematical model. Using an ecological study design, school health records of 168,825 students in elementary schools enrolled in "Health eTools for Schools" within 49 Pennsylvania counties were analyzed. Data representing asthma exacerbations were originally recorded by school nurses as the type of treatment given to a student during a clinic visit on a particular day. Daily upper atmosphere measurements from ground level to the 850-mb pressure level and air pollution measurements were obtained. A generalized estimating equation model was used to predict the occurrence of >48 asthma exacerbations, the daily mean for 2008-2010. The greatest occurrence of asthma among school children was in the fall, followed by summer, spring, and winter. Upper atmosphere temperature, dew point, mixing ratio, and six air pollutants as well as their interactions predicted the probability of asthma exacerbations occurring among children. Monitoring of upper atmosphere observation data and air pollutants over time can be a reliable means for predicting increases of asthma exacerbations among elementary school children. Such predictions could help parents and school officials implement effective precautionary measures.

  15. Static Hot Air and Infrared Rays Roasting are Efficient Methods for Aflatoxin Decontamination on Hazelnuts

    PubMed Central

    Siciliano, Ilenia; Dal Bello, Barbara; Zeppa, Giuseppe; Spadaro, Davide; Gullino, Maria Lodovica

    2017-01-01

    Aflatoxins are a group of secondary metabolites produced by members of Aspergillus Section Flavi that are dangerous to humans and animals. Nuts can be potentially contaminated with aflatoxins, often over the legal threshold. Food processes, including roasting, may have different effects on mycotoxins, and high temperatures have proven to be very effective in the reduction of mycotoxins. In this work, two different roasting methods—traditional static hot air roasting and infra-red rays roasting—were applied and compared for the detoxification of hazelnuts from Italy and Turkey. At the temperature of 140 °C for 40 min of exposure, detoxification was effective for both roasting techniques. Residual aflatoxins after infra-red rays treatments were lower compared to static hot air roasting. On Italian hazelnuts, residual aflatoxins were lower than 5%, while for Turkish hazelnuts they were lower than 15% after 40 min of exposure to an infra-red rays roaster. After roasting, the perisperm was detached from the nuts and analyzed for aflatoxin contents. Residual aflatoxins in the perisperm ranged from 80% up to 100%. After roasting, the lipid profile and the nutritional quality of hazelnuts were not affected. Fatty acid methyl esters analyses showed a similar composition for Italian and Turkish hazelnuts. PMID:28230792

  16. Static Hot Air and Infrared Rays Roasting are Efficient Methods for Aflatoxin Decontamination on Hazelnuts.

    PubMed

    Siciliano, Ilenia; Dal Bello, Barbara; Zeppa, Giuseppe; Spadaro, Davide; Gullino, Maria Lodovica

    2017-02-21

    Aflatoxins are a group of secondary metabolites produced by members of Aspergillus Section Flavi that are dangerous to humans and animals. Nuts can be potentially contaminated with aflatoxins, often over the legal threshold. Food processes, including roasting, may have different effects on mycotoxins, and high temperatures have proven to be very effective in the reduction of mycotoxins. In this work, two different roasting methods-traditional static hot air roasting and infra-red rays roasting-were applied and compared for the detoxification of hazelnuts from Italy and Turkey. At the temperature of 140 °C for 40 min of exposure, detoxification was effective for both roasting techniques. Residual aflatoxins after infra-red rays treatments were lower compared to static hot air roasting. On Italian hazelnuts, residual aflatoxins were lower than 5%, while for Turkish hazelnuts they were lower than 15% after 40 min of exposure to an infra-red rays roaster. After roasting, the perisperm was detached from the nuts and analyzed for aflatoxin contents. Residual aflatoxins in the perisperm ranged from 80% up to 100%. After roasting, the lipid profile and the nutritional quality of hazelnuts were not affected. Fatty acid methyl esters analyses showed a similar composition for Italian and Turkish hazelnuts.

  17. Air exchange rates from atmospheric CO2 daily cycle.

    PubMed

    Carrilho, João Dias; Mateus, Mário; Batterman, Stuart; da Silva, Manuel Gameiro

    2015-04-01

    We propose a new approach for measuring ventilation air exchange rates (AERs). The method belongs to the class of tracer gas techniques, but is formulated in the light of systems theory and signal processing. Unlike conventional CO2 based methods that assume the outdoor ambient CO2 concentration is constant, the proposed method recognizes that photosynthesis and respiration cycle of plants and processes associated with fuel combustion produce daily, quasi-periodic, variations in the ambient CO2 concentrations. These daily variations, which are within the detection range of existing monitoring equipment, are utilized for estimating ventilation rates without the need of a source of CO2 in the building. Using a naturally-ventilated residential apartment, AERs obtained using the new method compared favorably (within 10%) to those obtained using the conventional CO2 decay fitting technique. The new method has the advantages that no tracer gas injection is needed, and high time resolution results are obtained.

  18. Air exchange rates from atmospheric CO2 daily cycle

    PubMed Central

    Carrilho, João Dias; Mateus, Mário; Batterman, Stuart; da Silva, Manuel Gameiro

    2015-01-01

    We propose a new approach for measuring ventilation air exchange rates (AERs). The method belongs to the class of tracer gas techniques, but is formulated in the light of systems theory and signal processing. Unlike conventional CO2 based methods that assume the outdoor ambient CO2 concentration is constant, the proposed method recognizes that photosynthesis and respiration cycle of plants and processes associated with fuel combustion produce daily, quasi-periodic, variations in the ambient CO2 concentrations. These daily variations, which are within the detection range of existing monitoring equipment, are utilized for estimating ventilation rates without the need of a source of CO2 in the building. Using a naturally-ventilated residential apartment, AERs obtained using the new method compared favorably (within 10%) to those obtained using the conventional CO2 decay fitting technique. The new method has the advantages that no tracer gas injection is needed, and high time resolution results are obtained. PMID:26236090

  19. Overview of atmospheric ionizing radiation (AIR) Research: SST-present

    NASA Astrophysics Data System (ADS)

    Wilson, J. W.; Goldhagen, P.; Rafnsson, V.; Clem, J. M.; De Angelis, G.; Friedberg, W.

    The Supersonic Transport (SST) program proposed in 1961, first raised concern for the exposure of pregnant occupants by solar energetic particles (SEP), and neutrons were suspected to have a main role in particle propagation deep into the atmosphere. An eight-year flight program confirmed the role of SEP as a significant hazard and of the neutrons as contributing over half of the galactic cosmic ray exposures, with the largest contribution from neutrons above 10 MeV. The FAA Advisory Committee on the Radiobiological Aspects of the SST provided operational requirements. The more recent lowering of ICRP-recommended exposure limits 1990 with the classification of aircrew as "radiation workers" renewed interest in GCR background exposures at commercial flight altitudes and stimulated epidemiological studies in Europe, Japan, Canada and the USA. The proposed development of a High Speed Civil Transport (HSCT) required validation of the role of high-energy neutrons, and this resulted in ER-2 flights at solar minimum June 1997 and studies on effects of aircraft materials on interior exposures. Recent evaluation of health outcomes of DOE nuclear workers resulted in legislation for health compensation in year 2000 and recent European aircrew epidemiological studies of health outcomes bring renewed interest in aircraft radiation exposures. As improved radiation models become available, it is imperative that a corresponding epidemiological program of US aircrew be implemented.

  20. Overview of Atmospheric Ionizing Radiation (AIR) research: SST-present

    NASA Astrophysics Data System (ADS)

    Wilson, J.; Goldhagen, P.; Rafnson, V.; Clem, J.; Deangelis, G.

    The Super Sonic Transport (SST) program, proposed in 1961, first raised concern for the exposure of pregnant passengers and crew by solar energetic particles (SEP), and neutrons were suspected to have a main role in effects due to particle propagation deep into the atmosphere. An eight-year flight program confirmed the role of SEP as a significant hazard and of the neutrons as contributing over half of the galactic cosmic ray exposures, with the largest contribution from neutrons above 10 MeV. The FAA Standing Committee provided recommendations on SST radiobiological issues and operational requirements. The lowering of ICRP-recommended exposure limits (1990) with the classification of aircrew as "radiation workers" renewed interest in GCR background exposures at commercial flight altitudes and stimulated epidemiological studies in Europe, Japan, Canada and the USA. The proposed development of a High Speed Civil Transport (HSCT) required validation of the role of high-energy neutrons, and this resulted in ER-2 flights at solar minimum (June 1997) and studies of effects of aircraft materials on interior exposures. Recent evaluation of health outcomes of DOE nuclear workers resulted in legislation for health compensation in 2000 and more recent European aircrew epidemiological studies of health outcomes brings renewed interest in aircraft radiation exposures. As improved radiation models become available, it is imperative that a corresponding epidemiological program of US aircrew be implemented.

  1. Overview of Atmospheric Ionizing Radiation (AIR) Research: SST - Present

    NASA Technical Reports Server (NTRS)

    Wilson, J. W.; Goldhagen, P.; Rafnsson, V.; Clem, J. M.; DeAngelis, G.; Friedberg, W.

    2002-01-01

    The Supersonic Transport (SST) program, proposed in 1961, first raised concern for the exposure of pregnant occupants by solar energetic particles (SEP), and neutrons were suspected to have a main role in particle propagation deep into the atmosphere. An eight-year flight program confirmed the role of SEP as a significant hazard and of the neutrons as contributing over half of the galactic cosmic ray (GCR) exposures, with the largest contribution from neutrons above 10 MeV. The FAA Advisory Committee on the Radiobiological Aspects of the SST provided operational requirements. The more recent (1990) lowering of recommended exposure limits by the International Commission on Radiological Protection with the classification of aircrew as "radiation workers" renewed interest in GCR background exposures at commercial flight altitudes and stimulated epidemiological studies in Europe, Japan, Canada and the USA. The proposed development of a High Speed Civil Transport (HSCT) required validation of the role of high-energy neutrons, and this resulted in ER-2 flights at solar minimum (June 1997) and studies on effects of aircraft materials on interior exposures. Recent evaluation of health outcomes of DOE nuclear workers resulted in legislation for health compensation in year 2000 and recent European aircrew epidemiological studies of health outcomes bring renewed interest in aircraft radiation exposures. As improved radiation models become available, it is imperative that a corresponding epidemiological program of US aircrew be implemented.

  2. Summary of Atmospheric Ionizing AIR Research: SST-Present

    NASA Technical Reports Server (NTRS)

    Wilson, J. W.; Goldhagen, P.; Rafnsson, V.; deAngelis, G.; Friedberg, W.; Clem, J. M.

    2003-01-01

    The Supersonic Transport (SST) program, proposed in 1961, first raised concern for the exposure of pregnant occupants by solar energetic particles (SEP), and neutrons were suspected to have a main role in particle propagation deep into the atmosphere. An eight-year flight program confirmed the role of SEP as a significant hazard and of the neutrons as contributing over half of the galactic cosmic ray (GCR) exposures, with the largest contribution from neutrons above 10 MeV. The FAA Advisory Committee on the Radiobiological Aspects of the SST provided operational requirements. The more recent lowering of the radiation exposure limits by the International Commission on Radiological Protection with the classification of aircrew as radiation workers renewed interest in GCR background exposures at commercial flight altitudes and stimulated epidemiological studies in Europe, Japan, Canada and the USA. The proposed development of a High Speed Civil Transport (HSCT) required validation of the role of high-energy neutrons, and this resulted in ER-2 flights at solar minimum (June 1997) and studies on effects of aircraft materials on interior exposures. Recent evaluation of health outcomes of DOE nuclear workers resulted in legislation for health compensation in year 2000 and recent European aircrew epidemiological studies of health outcomes bring renewed interest in aircraft radiation exposures. As improved radiation models become available, it is imperative that a corresponding epidemiological program of US aircrew be implemented.

  3. Overview of atmospheric ionizing radiation (AIR) research: SST-present

    NASA Technical Reports Server (NTRS)

    Wilson, J. W.; Goldhagen, P.; Rafnsson, V.; Clem, J. M.; De Angelis, G.; Friedberg, W.

    2003-01-01

    The Supersonic Transport (SST) program, proposed in 1961, first raised concern for the exposure of pregnant occupants by solar energetic particles (SEP), and neutrons were suspected to have a main role in particle propagation deep into the atmosphere. An eight-year flight program confirmed the role of SEP as a significant hazard and of the neutrons as contributing over half of the galactic cosmic ray exposures, with the largest contribution from neutrons above 10 MeV. The FAA Advisory Committee on the Radiobiological Aspects of the SST provided operational requirements. The more recent lowering of ICRP-recommended exposure limits (1990) with the classification of aircrew as "radiation workers" renewed interest in GCR background exposures at commercial flight altitudes and stimulated epidemiological studies in Europe, Japan, Canada and the USA. The proposed development of a High Speed Civil Transport (HSCT) required validation of the role of high-energy neutrons, and this resulted in ER-2 flights at solar minimum (June 1997) and studies on effects of aircraft materials on interior exposures. Recent evaluation of health outcomes of DOE nuclear workers resulted in legislation for health compensation in year 2000 and recent European aircrew epidemiological studies of health outcomes bring renewed interest in aircraft radiation exposures. As improved radiation models become available, it is imperative that a corresponding epidemiological program of US aircrew be implemented. Published by Elsevier Ltd on behalf of COSPAR.

  4. Overview of atmospheric ionizing radiation (AIR) research: SST-present.

    PubMed

    Wilson, J W; Goldhagen, P; Rafnsson, V; Clem, J M; De Angelis, G; Friedberg, W

    2003-01-01

    The Supersonic Transport (SST) program, proposed in 1961, first raised concern for the exposure of pregnant occupants by solar energetic particles (SEP), and neutrons were suspected to have a main role in particle propagation deep into the atmosphere. An eight-year flight program confirmed the role of SEP as a significant hazard and of the neutrons as contributing over half of the galactic cosmic ray exposures, with the largest contribution from neutrons above 10 MeV. The FAA Advisory Committee on the Radiobiological Aspects of the SST provided operational requirements. The more recent lowering of ICRP-recommended exposure limits (1990) with the classification of aircrew as "radiation workers" renewed interest in GCR background exposures at commercial flight altitudes and stimulated epidemiological studies in Europe, Japan, Canada and the USA. The proposed development of a High Speed Civil Transport (HSCT) required validation of the role of high-energy neutrons, and this resulted in ER-2 flights at solar minimum (June 1997) and studies on effects of aircraft materials on interior exposures. Recent evaluation of health outcomes of DOE nuclear workers resulted in legislation for health compensation in year 2000 and recent European aircrew epidemiological studies of health outcomes bring renewed interest in aircraft radiation exposures. As improved radiation models become available, it is imperative that a corresponding epidemiological program of US aircrew be implemented.

  5. Using Unmanned Air Systems to Monitor Methane in the Atmosphere

    NASA Technical Reports Server (NTRS)

    Clow, Jacqueline; Smith, Jeremy Christopher

    2016-01-01

    Methane is likely to be an important contributor to global warming, and our current knowledge of its sources, distributions, and transport is insufficient. It is estimated that there could be from 7.5 to 400 billion tons carbon-equivalent of methane in the arctic region, a broad range that is indicative of the uncertainty within the Earth Science community. Unmanned Air Systems (UASs) are often used for combat or surveillance by the military, but they also have been used for Earth Science field missions. In this study, we will analyze the utility of the NASA Global Hawk and the Aurora Flight Sciences Orion UASs compared to the manned DC-8 aircraft for conducting a methane monitoring mission. The mission will focus on the measurement of methane along the boundaries of Arctic permafrost thaw and melting glaciers. The use of Long Endurance UAS brings a new range of possibilities including the ability to obtain long- term and persistent observations and to significantly augment methane measurements/retrievals collected by satellite. Furthermore, we discuss the future of long endurance UAS and their potential for science applications in the next twenty to twenty-five years.

  6. Effect of Atmospheric Pollutants on the Air Quality in Tunisia

    PubMed Central

    Bouchlaghem, Karim; Nsom, Blaise

    2012-01-01

    This paper presents the evolution of Saharan dust advection when the PM10 (particles with an aerodynamic diameter below 10 μm) concentration exceeds standard limits in different Tunisian sites. Meteorological and concentration data (from 2004 to 2010) obtained from several monitoring stations and in situ measurements were used to identify African dust change in seasonal occurrence, their source origin, and their impact on surface PM10 concentrations. We pointed out that the Saharan dust contribution caused frequently the surpassing of the maximum number of days in excess of EU standard limits as well as of the maximum yearly average in the Mediterranean Tunisian coasts. The maximum daily concentration reaches 439 μg/m3 during the Saharan events. The decrease in particulate levels recorded at the end of each event is due to the injection of European air masses and rainfalls. Primary pollutants peaks were much higher in winter than in summer which can be explained on the basis of the lower ventilation and mixing. PMID:22654641

  7. Experimental study of the heat transfer process of air around atmospheric arc plasma

    NASA Astrophysics Data System (ADS)

    Salimi Meidanshahi, F.; Madanipour, Kh.; Shokri, Babak

    2011-05-01

    The experimental investigation of thermodynamic properties such heat and mass transfer of plasmas has many applications in different industries. Laboratory atmospheric arc plasma is studied in this work. The refractive index of the air around the plasma is changed because of convection phenomena. When the convection creates the air flowing around the plasma, the density and consequently, the refractive index of air are distributed symmetrically. Moiré deflectometry is a technique of wave front analysis which in both Talbot effect and moiré technique is applied for measuring phase objects. Deflection of light beam passing through the inhomogeneous medium is utilized to obtain the refractive index distribution. In experimental set-up, an expanded collimated He-Ne laser propagate through the arc plasma and the around air. The temperature distribution is obtained by use of thermo-optic coefficient of air. To calculate the thermo- optic coefficient and the refractive index of air for a given wavelength of light and given atmospheric conditions (air temperature, pressure, and humidity), the Edlén equation is used. The convective heat transfer coefficient is obtained by calculating the temperature gradient on the plasma border. This method is not expensive, complicated and sensitive to environmental vibrations.

  8. Mitigating the Effects of Atmospheric Turbulence: Towards More Useful Micro Air Vehicles

    DTIC Science & Technology

    2010-07-18

    outdoor turbulent environment. 25 REFERENCES AND BIBLIOGRAPHY Abdulrahim M., Watkins S., Segal R . and Sheridan J., “Dynamic Sensitivity to...Shortis M., Loxton B., Segal R . and Bil C., “Turbulence in the Atmospheric Wind: A Limiting Factor in MAV Operations”, 24th Bristol Unmanned Air

  9. Compact 180-kV Marx generator triggered in atmospheric air by femtosecond laser filaments

    NASA Astrophysics Data System (ADS)

    Arantchouk, L.; Point, G.; Brelet, Y.; Larour, J.; Carbonnel, J.; André, Y.-B.; Mysyrowicz, A.; Houard, A.

    2014-03-01

    We developed a compact Marx generator triggered in atmospheric air by a single femtosecond laser beam undergoing filamentation. Voltage pulses of 180 kV could be generated with a subnanosecond jitter. The same laser beam was also used to initiate simultaneously guided discharges up to 21 cm long at the output of the generator.

  10. Critical Evaluation of Air-Liquid Interface Exposure Devices for In Vitro Assessment of Atmospheric Pollutants

    EPA Science Inventory

    Exposure of cells to atmospheric pollutants at the air-liquid interface (ALI) is a more realistic approach than exposures of attached cells submerged in liquid medium. However, there is still limited understanding of the ideal ALI device design features that permit reproducible a...

  11. Compact 180-kV Marx generator triggered in atmospheric air by femtosecond laser filaments

    SciTech Connect

    Arantchouk, L. Larour, J.; Point, G.; Brelet, Y.; Carbonnel, J.; André, Y.-B.; Mysyrowicz, A.; Houard, A.

    2014-03-10

    We developed a compact Marx generator triggered in atmospheric air by a single femtosecond laser beam undergoing filamentation. Voltage pulses of 180 kV could be generated with a subnanosecond jitter. The same laser beam was also used to initiate simultaneously guided discharges up to 21 cm long at the output of the generator.

  12. Optical Alignment and Diffraction Analysis for AIRES: An Airborne Infrared Echelle Spectrometer

    NASA Technical Reports Server (NTRS)

    Haas, Michael R.; Fonda, Mark (Technical Monitor)

    2002-01-01

    The optical design is presented for a long-slit grating spectrometer known as AIRES (Airborne InfraRed Echelle Spectrometer). The instrument employs two gratings in series: a small order sorter and a large steeply blazed echelle. The optical path includes four pupil and four field stops, including two narrow slits. A detailed diffraction analysis is performed using GLAD by Applied Optics Research to evaluate critical trade-offs between optical throughput, spectral resolution, and system weight and volume. The effects of slit width, slit length, oversizing the second slit relative to the first, on- vs off-axis throughput, and clipping at the pupil stops and other optical elements are discussed.

  13. Air Force electronic warfare evaluation simulator (AFEWES) infrared test and evaluation capabilities

    NASA Astrophysics Data System (ADS)

    Shepherd, Seth D.

    2003-09-01

    The Air Force Electronic Warfare Evaluation Simulator (AFEWES) Infrared Countermeasures (IRCM) test facility currently has the ability to simulate a complete IRCM test environment, including IR missiles in flight, aircraft in flight, and various IR countermeasures including maneuvers, point-source flares and lamp- and LASER-based jammer systems. The simulations of IR missiles in flight include missile seeker hardware mounted on a six degree-of-freedom flight simulation table. This paper will focus on recent developments and upgrades to the AFEWES IR capability.

  14. Thermal infrared laser heterodyne spectroradiometry for solar occultation atmospheric CO2 measurements

    NASA Astrophysics Data System (ADS)

    Hoffmann, Alex; Macleod, Neil A.; Huebner, Marko; Weidmann, Damien

    2016-12-01

    This technology demonstration paper reports on the development, demonstration, performance assessment, and initial data analysis of a benchtop prototype quantum cascade laser heterodyne spectroradiometer, operating within a narrow spectral window of ˜ 1 cm-1 around 953.1 cm-1 in transmission mode and coupled to a passive Sun tracker. The instrument has been specifically designed for accurate dry air total column, and potentially vertical profile, measurements of CO2. Data from over 8 months of operation in 2015 near Didcot, UK, confirm that atmospheric measurements with noise levels down to 4 times the shot noise limit can be achieved with the current instrument. Over the 8-month period, spectra with spectral resolutions of 60 MHz (0.002 cm-1) and 600 MHz (0.02 cm-1) have been acquired with median signal-to-noise ratios of 113 and 257, respectively, and a wavenumber calibration uncertainty of 0.0024 cm-1.Using the optimal estimation method and RFM as the radiative transfer forward model, prior analysis and theoretical benchmark modelling had been performed with an observation system simulator (OSS) to target an optimized spectral region of interest. The selected narrow spectral window includes both CO2 and H2O ro-vibrational transition lines to enable the measurement of dry air CO2 column from a single spectrum. The OSS and preliminary retrieval results yield roughly 8 degrees of freedom for signal (over the entire state vector) for an arbitrarily chosen a priori state with relatively high uncertainty ( ˜ 4 for CO2). Preliminary total column mixing ratios obtained are consistent with GOSAT monthly data. At a spectral resolution of 60 MHz with an acquisition time of 90 s, instrumental noise propagation yields an error of around 1.5 ppm on the dry air total column of CO2, exclusive of biases and geophysical parameters errors at this stage.

  15. Thermal infrared properties of the Martian atmosphere. I - Global behavior at 7, 9, 11, and 20 microns

    NASA Technical Reports Server (NTRS)

    Martin, T. Z.; Peterfreund, A. R.; Miner, E. D.; Kieffer, H. H.; Hunt, G. E.

    1979-01-01

    Infrared observations of Mars by the Viking infrared thermal mapper (IRTM) are presented for conditions of both a relatively clear and a dust-laden atmosphere. The 7-, 9-, 11-, and 20-micron bands of the IRTM respond differently to radiation emitted through and by a dusty atmosphere, permitting characterization of the global atmospheric state, monitoring of secular changes, and derivation of optical depth information. Surface temperature behavior is found to be greatly modified by the diminution of insolation and thermal blanketing resulting from global dust storms. Brightness temperature at 7 microns is employed to estimate surface temperatures in the presence of dust absorption. The difference (T7) is indicative of airborne dust when thermal contrast exists between the surface and atmosphere. The diurnal behavior of T7-T9 reveals changes in the contrast; the sign of the differential reverses as the surface, warmer than the atmosphere in daytime, becomes cooler than the atmosphere at night. IRTM observations of local areas at varying emission angle yield optical depths indicative of global trends. Two global dust storms in 1977 produced large optical depth changes: at 9 microns the optical depth became as large as 2.0.

  16. Contribution of Atmospheric Diffusion Conditions to the Recent Improvement in Air Quality in China

    PubMed Central

    Wang, Xiaoyan; Wang, Kaicun; Su, Liangyuan

    2016-01-01

    This study analyzed hourly mass concentration observations of PM2.5 (particulate matters with diameter less than 2.5 μm) at 512 stations in China from December 2013 to May 2015. We found that the mean concentrations of PM2.5 during the winter and spring of 2015 Dec. 2014 to Feb. 2015 and Mar. 2015 to May 2015) decreased by 20% and 14% compared to the previous year, respectively. Hazardous air-quality days decreased by 11% in 2015 winter, with more frequent good to unhealthy days; and the good and moderate air-quality days in 2015 spring increased by 9% corresponding to the less occurrence of unhealthy conditions. We compared the atmospheric diffusion conditions during these two years and quantified its contribution to the improvement of air quality during the first half of 2015 over China. Our results show that during the 2015 winter and spring, 70% and 57% of the 512 stations experienced more favorable atmospheric diffusion conditions compared to those of previous year. Over central and northern China, approximately 40% of the total decrease in PM2.5 during the 2015 winter can be attributed to the favorable atmospheric diffusion conditions. The atmospheric diffusion conditions during the spring of 2015 were not as favorable as in winter; and the average contributions of the atmospheric conditions were slight. PMID:27805030

  17. Contribution of Atmospheric Diffusion Conditions to the Recent Improvement in Air Quality in China

    NASA Astrophysics Data System (ADS)

    Wang, Xiaoyan; Wang, Kaicun; Su, Liangyuan

    2016-11-01

    This study analyzed hourly mass concentration observations of PM2.5 (particulate matters with diameter less than 2.5 μm) at 512 stations in China from December 2013 to May 2015. We found that the mean concentrations of PM2.5 during the winter and spring of 2015 Dec. 2014 to Feb. 2015 and Mar. 2015 to May 2015) decreased by 20% and 14% compared to the previous year, respectively. Hazardous air-quality days decreased by 11% in 2015 winter, with more frequent good to unhealthy days; and the good and moderate air-quality days in 2015 spring increased by 9% corresponding to the less occurrence of unhealthy conditions. We compared the atmospheric diffusion conditions during these two years and quantified its contribution to the improvement of air quality during the first half of 2015 over China. Our results show that during the 2015 winter and spring, 70% and 57% of the 512 stations experienced more favorable atmospheric diffusion conditions compared to those of previous year. Over central and northern China, approximately 40% of the total decrease in PM2.5 during the 2015 winter can be attributed to the favorable atmospheric diffusion conditions. The atmospheric diffusion conditions during the spring of 2015 were not as favorable as in winter; and the average contributions of the atmospheric conditions were slight.

  18. Fourier Transform Infrared (FT-IR) Spectroscopy of Atmospheric Trace Gases HCl, NO and SO2

    NASA Technical Reports Server (NTRS)

    Haridass, C.; Aw-Musse, A.; Dowdye, E.; Bandyopadhyay, C.; Misra, P.; Okabe, H.

    1998-01-01

    Fourier Transform Infrared (FT-IR) spectral data have been recorded in the spectral region 400-4000/cm of hydrogen chloride and sulfur dioxide with I/cm resolution and of nitric oxide with 0.25 cm-i resolution, under quasi-static conditions, when the sample gas was passed through tubings of aluminum, copper, stainless steel and teflon. The absorbance was measured for the rotational lines of the fundamental bands of (1)H(35)Cl and (1)H(37)Cl for pressures in the range 100-1000 Torr and for the (14)N(16)O molecule in the range 100-300 Torr. The absorbance was also measured for individual rotational lines corresponding to the three modes of vibrations (upsilon(sub 1) - symmetric stretch, upsilon(sub 2) - symmetric bend, upsilon(sub 3) - anti-symmetric stretch) of the SO2 molecule in the pressure range 25-150 Torr. A graph of absorbance versus pressure was plotted for the observed rotational transitions of the three atmospherically significant molecules, and it was found that the absorbance was linearly proportional to the pressure range chosen, thereby validating Beer's law. The absorption cross-sections were determined from the graphical slopes for each rotational transition recorded for the HCl, NO and SO2 species. Qualitative and quantitative spectral changes in the FT-IR data will be discussed to identify and characterize various tubing materials with respect to their absorption features.

  19. Near infrared cavity enhanced absorption spectra of atmospherically relevant ether-1, 4-Dioxane

    NASA Astrophysics Data System (ADS)

    Chandran, Satheesh; Varma, Ravi

    2016-01-01

    1, 4-Dioxane (DX) is a commonly found ether in industrially polluted atmosphere. The near infrared absorption spectra of this compound has been recorded in the region 5900-8230 cm- 1 with a resolution of 0.08 cm- 1 using a novel Fourier transform incoherent broadband cavity-enhanced absorption spectrometer (FT-IBBCEAS). All recorded spectra were found to contain regions that are only weakly perturbed. The possible combinations of fundamental modes and their overtone bands corresponding to selected regions in the measured spectra are tabulated. Two interesting spectral regions were identified as 5900-6400 cm- 1 and 8100-8230 cm- 1. No significant spectral interference due to presence of water vapor was observed suggesting the suitability of these spectral signatures for spectroscopic in situ detection of DX. The technique employed here is much more sensitive than standard Fourier transform spectrometer measurements on account of long effective path length achieved. Hence significant enhancement of weaker absorption lines above the noise level was observed as demonstrated by comparison with an available measurement from database.

  20. An outline for the RTNEPH infrared atmospheric water vapor attenuation study

    NASA Astrophysics Data System (ADS)

    Dentremont, Robert P.; Moncet, John-Luc; Miller, Todd R.; Griffin, Michael K.; Thomason, Larry W.; Bunting, James T.; Schaaf, Crystal Barker

    1989-12-01

    The Real-Time Nephanalysis (RTNEPH) generates real-time global analysis of cloud extent, base, height, and type. The RTNEPH makes extensive use of satellite data that are measured in the 10 to 12 micron infrared (IR) window for thermal mapping of clouds and the earth's surface both day and night. Water vapor absorption effects are significant in such data, especially for high viewing angles and tropical atmospheres where water vapor concentrations are generally high. Water vapor attenuates the emitted ground radiance, reducing its magnitude and with it the apparent temperature of the surface being viewed. Currently, the RTNEPH takes into account such attenuation losses using lookup tables that are functions of viewing geometry, time of day, type of background, and the like. However, these corrections have limited value and leave room for significant improvement. This report outlines and presents two new techniques that are expected to enhance the attenuation correction capabilities of the RTNEPH, multivariate polynomial regression (the Weinreb technique) and the correlated K method.

  1. Infrared pulse characterization using four-wave mixing inside a few cycle pulse filament in air

    SciTech Connect

    Marceau, Claude Thomas, Steven; Kassimi, Yacine; Gingras, Guillaume; Witzel, Bernd

    2014-02-03

    We demonstrate a four-wave mixing (FWM) technique to measure near- and mid-infrared (IR) laser pulse shapes in time domain. Few cycle 800 nm laser pulses were synchronized with the IR pulse and focused colinearly to generate a plasma filament in air. Second harmonic radiation around 400 nm was generated through FWM, with a yield proportional to the IR pulse intensity. Excellent signal to noise ratio was observed from 2.1 μm to 18 μm. With proper phase stabilization of the IR beam, this technique is a promising step toward direct electric field sensing of near-IR pulses in air.

  2. Development of an atmospheric infrared radiation model with high clouds for target detection

    NASA Astrophysics Data System (ADS)

    Bellisario, Christophe; Malherbe, Claire; Schweitzer, Caroline; Stein, Karin

    2016-10-01

    In the field of target detection, the simulation of the camera FOV (field of view) background is a significant issue. The presence of heterogeneous clouds might have a strong impact on a target detection algorithm. In order to address this issue, we present here the construction of the CERAMIC package (Cloudy Environment for RAdiance and MIcrophysics Computation) that combines cloud microphysical computation and 3D radiance computation to produce a 3D atmospheric infrared radiance in attendance of clouds. The input of CERAMIC starts with an observer with a spatial position and a defined FOV (by the mean of a zenithal angle and an azimuthal angle). We introduce a 3D cloud generator provided by the French LaMP for statistical and simplified physics. The cloud generator is implemented with atmospheric profiles including heterogeneity factor for 3D fluctuations. CERAMIC also includes a cloud database from the French CNRM for a physical approach. We present here some statistics developed about the spatial and time evolution of the clouds. Molecular optical properties are provided by the model MATISSE (Modélisation Avancée de la Terre pour l'Imagerie et la Simulation des Scènes et de leur Environnement). The 3D radiance is computed with the model LUCI (for LUminance de CIrrus). It takes into account 3D microphysics with a resolution of 5 cm-1 over a SWIR bandwidth. In order to have a fast computation time, most of the radiance contributors are calculated with analytical expressions. The multiple scattering phenomena are more difficult to model. Here a discrete ordinate method with correlated-K precision to compute the average radiance is used. We add a 3D fluctuations model (based on a behavioral model) taking into account microphysics variations. In fine, the following parameters are calculated: transmission, thermal radiance, single scattering radiance, radiance observed through the cloud and multiple scattering radiance. Spatial images are produced, with a

  3. Air Purification Effect of Positively and Negatively Charged Ions Generated by Discharge Plasma at Atmospheric Pressure

    NASA Astrophysics Data System (ADS)

    Nishikawa, Kazuo; Nojima, Hideo

    2001-08-01

    In this paper, the air purification effect of positively and negatively charged ions generated by discharge plasma at atmospheric pressure is reported. We have developed a novel ion generation device which consists of a cylindrical glass tube and attached inner and outer mesh electrodes. With the application of AC voltage between the electrodes, positively charged ions and negatively charged ions have been generated at atmospheric pressure. The ion densities of 3.0× 104--7.0× 104 counts/cm3 have been obtained with the AC voltage of 1.8-2.3 kV (effective value). We have examined the air purification properties of this device. By the operation of this device, the initial oxygen nitride (NO) density of 10 ppm in 1 m3 (in cigarette smoke) was decreased to 1 ppm after 30 min. The number of suspended germs in air has been significantly reduced by the use of this type of ion generation device.

  4. [Detection of potentially carcinogenic compounds persisting in atmospheric air and having high priority for hygienic regulation].

    PubMed

    Ingel', F I; Legostaeva, T B; Antipanova, N A; Krivtsova, E K; Iurtseva, N A

    2012-01-01

    The algorithm for the choice of potentially carcinogenic compounds (PCS) among emitted into air and results of the study, undertaken for realization of this algorithm are presented. The investigation was carried out in Magnitogorsk - Russian town of black metallurgy - in frames of the other study, aimed to evaluation of the influence of atmospheric pollution on children's health and genomic instability. The 11 PCS for further profound study of biological activity were selected out of more than 300 PCS, persisting in the air. The carcinogenic activity for 6 compounds out of these 11 ones was already have been found out before, that testifies correctness of the created approach and its adequacy for detection PCS in atmospheric air.

  5. Ground-based Infrared Observations of Water Vapor and Hydrogen Peroxide in the Atmosphere of Mars

    NASA Astrophysics Data System (ADS)

    Encrenaz, T.; Greathouse, T. K.; Bitner, M.; Kruger, A.; Richter, M. J.; Lacy, J. H.; Bézard, B.; Fouchet, T.; Lefevre, F.; Forget, F.; Atreya, S. K.

    2008-11-01

    Ground-based observations of water vapor and hydrogen peroxide have been obtained in the thermal infrared range, using the TEXES instrument at the NASA Infrared Telescope Facility, for different times of the seasonal cycle.

  6. Infrared Measurements of Atmospheric Gases Above Mauna Loa, Hawaii, in February 1987

    NASA Technical Reports Server (NTRS)

    Rinsland, C. P.; Goldman, A.; Murcray, F. J.; Murcray, F. H.; Blatherwick, R. D.; Murcray, D. G.

    1988-01-01

    Infrared solar absorption spectra recorded at 0.02/ cm resolution from the National Oceanic and Atmospheric Administration (NOAA) Geophysical Monitoring for Climate Change (GMCC) program station at Mauna Loa, Hawaii (latitude 19.5 deg N, longitude 155.6 deg W, elevation 3.40 km), in February 1997 have been analyzed to determine simultaneous total vertical column amounts for 13 atmospheric gases. Average tropospheric concentrations of CO2, N2O, CH4, and CHCIF2 and the daytime diurnal variations or the total columns of NO and NO2 have also been inferred. The retrieved total columns (in molecules /sq cm) of the nondiurnally varying gases are 1.6 +/- 0.2 x 10(exp 15) for HCl, 5.9 +/- 1.2 x 10(exp 15) for HNO3, 2.0 +/- 0.2 x 10(exp 21) for H2O16, 4.4 +/- 0.7 x 10(exp 18) for H2O18, 2.7 +/- 0.1 x 10(exp 17) for HDO, 2.3 +/- 0.2 x 10(exp 19) for CH4, 5.0 +/- 0.5 x 10(exp 21) for CO2, 6.7 +/- 0.8 x 10(exp 18) for O3, 4.3 +/- 0.4 x 10(exp 18) for N2O, 1.0 +/- 0.2 x 10(exp 16) for C2H6, and 9.7 +/- 2.5 x 10(exp 14) for CHClF2. We compare the total column measurements of HCl and HNO3 with previously reported ground-based, aircraft, and satellite measurements. The results for HCl are or particular interest because of the expected temporal increase in the concentration of this gas in the stratosphere. However, systematic differences among stratospheric HCl total column measurements from 1978 to 1980 and the absence of observations of free tropospheric HCl above Mauna Loa make it impossible to obtain a reliable estimate of the trend in the total burden of HCl. The measured HNO3 total column is consistent with aircraft measurements from approx. 12 km altitude. The O3 total column deduced from the IR spectra agrees with correlative Mauna Loa Umkehr measurements within the estimated error limits. The column-averaged D/H ratio of water vapor is (68 +/- 9) x- 10(exp -6), which is 0.44 +/- 0.06 times the reference value of 155.76 x 10(exp -6) for standard mean ocean water (SMOW). This

  7. Gas chromatograph analysis on closed air and nitrogen oxide storage atmospheres of recalcitrant seeds of Quercus Alba

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Storage of recalcitrant seeds remains an unsolved problem. This study investigated the quantitative gas analysis of nitrous oxide (N2O) and air atmospheres on the recalcitrant seeds of Quercus alba by using gas chromatograph. Ten seeds were placed in each sealed atmospheric system of air and 98/2% N...

  8. Instrumentation for Infrared Astronomy in the Collections of the National Air and Space Museum, Smithsonian Institution

    NASA Astrophysics Data System (ADS)

    DeVorkin, David H.

    2017-01-01

    The National Air and Space Museum of the Smithsonian Institution is responsible for preserving the material heritage of modern astronomical history. We place emphasis on American accomplishments, on both airborne and spaceborne instrumentation, and on ground based instrumentation that stimulated and supported spaceborne efforts. At present the astronomical collection includes over 600 objects, of which approximately 40 relate to the history of infrared astronomy. This poster will provide a simple listing of our holdings in infrared and far-infrared astronomy, and will highlight particularly significant early objects, like Cashman and Ektron cells, Leighton and Neugebauer's Caltech 2.2 micron survey telescope, Low's Lear Jet Bolometer, Harwit's first Aerobee IR payload and Fazio's balloon-borne observatory. Elements from more recent missions will also be included, such as instruments from KAO, an IRAS focal plane instrument, FIRAS from COBE, the payload from Boomerang and Woody and Richards' balloonsonde payload. The poster author will invite AAS members to comment on these holdings, provide short stories of their experiences building and using them, and suggest candidates for possible collection.

  9. The effect of the atmospheric condition on the extensive air shower analysis at the Telescope Array experiment

    SciTech Connect

    Kobayashi, Y.; Tsunesada, Y.; Tokuno, H.; Kakimoto, F.; Tomida, T.

    2011-09-22

    The accuracies in determination of air shower parameters such as longitudinal profiles or primary energies with the fluorescence detection technique are strongly dependent on atmospheric conditions of the molecular and aerosol components. Moreover, air fluorescence photon yield depends on the atmospheric density, and the transparency of the air for fluorescence photons depends on the atmospheric conditions from EAS to FDs. In this paper, we describe the atmospheric monitoring system in the Telescope Array (TA experiment), and the impact of the atmospheric conditions in air shower reconstructions. The systematic uncertainties of the determination of the primary cosmic ray energies and of the measurement of depth of maximum development (X{sub max}) of EASs due to atmospheric variance are evaluated by Monte Carlo simulation.

  10. Hot, cold, and annual reference atmospheres for Edwards Air Force Base, California (1975 version)

    NASA Technical Reports Server (NTRS)

    Johnson, D. L.

    1975-01-01

    Reference atmospheres pertaining to summer (hot), winter (cold), and mean annual conditions for Edwards Air Force Base, California, are presented from surface to 90 km altitude (700 km for the annual model). Computed values of pressure, kinetic temperature, virtual temperature, and density and relative differences percentage departure from the Edwards reference atmospheres, 1975 (ERA-75) of the atmospheric parameters versus altitude are tabulated in 250 m increments. Hydrostatic and gas law equations were used in conjunction with radiosonde and rocketsonde thermodynamic data in determining the vertical structure of these atmospheric models. The thermodynamic parameters were all subjected to a fifth degree least-squares curve-fit procedure, and the resulting coefficients were incorporated into Univac 1108 computer subroutines so that any quantity may be recomputed at any desired altitude using these subroutines.

  11. Coupled Inertial Navigation and Flush Air Data Sensing Algorithm for Atmosphere Estimation

    NASA Technical Reports Server (NTRS)

    Karlgaard, Christopher D.; Kutty, Prasad; Schoenenberger, Mark

    2015-01-01

    This paper describes an algorithm for atmospheric state estimation that is based on a coupling between inertial navigation and flush air data sensing pressure measurements. In this approach, the full navigation state is used in the atmospheric estimation algorithm along with the pressure measurements and a model of the surface pressure distribution to directly estimate atmospheric winds and density using a nonlinear weighted least-squares algorithm. The approach uses a high fidelity model of atmosphere stored in table-look-up form, along with simplified models of that are propagated along the trajectory within the algorithm to provide prior estimates and covariances to aid the air data state solution. Thus, the method is essentially a reduced-order Kalman filter in which the inertial states are taken from the navigation solution and atmospheric states are estimated in the filter. The algorithm is applied to data from the Mars Science Laboratory entry, descent, and landing from August 2012. Reasonable estimates of the atmosphere and winds are produced by the algorithm. The observability of winds along the trajectory are examined using an index based on the discrete-time observability Gramian and the pressure measurement sensitivity matrix. The results indicate that bank reversals are responsible for adding information content to the system. The algorithm is then applied to the design of the pressure measurement system for the Mars 2020 mission. The pressure port layout is optimized to maximize the observability of atmospheric states along the trajectory. Linear covariance analysis is performed to assess estimator performance for a given pressure measurement uncertainty. The results indicate that the new tightly-coupled estimator can produce enhanced estimates of atmospheric states when compared with existing algorithms.

  12. Simulation and Theory of Ions at Atmospherically Relevant Aqueous Liquid-Air Interfaces

    SciTech Connect

    Tobias, Douglas J.; Stern, Abraham C.; Baer, Marcel D.; Levin, Yan; Mundy, Christopher J.

    2013-04-01

    Chemistry occurring at or near the surfaces of aqueous droplets and thin films in the atmosphere influences air quality and climate. Molecular dynamics simulations are becoming increasingly useful for gaining atomic-scale insight into the structure and reactivity of aqueous interfaces in the atmosphere. Here we review simulation studies of atmospherically relevant aqueous liquid-air interfaces, with an emphasis on ions that play important roles in the chemistry of atmospheric aerosols. In addition to surveying results from simulation studies, we discuss challenges to the refinement and experimental validation of the methodology for simulating ion adsorption to the air-water interface, and recent advances in elucidating the driving forces for adsorption. We also review the recent development of a dielectric continuum theory that is capable of reproducing simulation and experimental data on ion behavior at aqueous interfaces. MDB and CJM acknowledge support from the US Department of Energy's Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences. Pacific Northwest National Laboratory (PNNL) is operated for the Department of Energy by Battelle. MDB is supported by the Linus Pauling Distinguished Postdoctoral Fellowship Program at PNNL.

  13. Wind tunnel experiments: cold-air pooling and atmospheric decoupling above a melting snow patch

    NASA Astrophysics Data System (ADS)

    Mott, R.; Paterna, E.; Horender, S.; Crivelli, P.; Lehning, M.

    2015-10-01

    The longevity of perennial snow fields is not fully understood but it is known that strong atmospheric stability and thus boundary layer decoupling limits the amount of (sensible and latent) heat that can be transmitted to the snow surface. The strong stability is typically caused by two factors, (i) the temperature difference between the (melting) snow surface and the near-surface atmosphere and (ii) cold-air pooling in topographic depressions. These factors are almost always a prerequisite for perennial snow fields to exist. For the first time, this contribution investigates the relative importance of the two factors in a controlled wind tunnel environment. Vertical profiles of sensible heat fluxes are measured using two-component hot wire and one-component cold-wire anemometry directly over the melting snow patch. The comparison between a flat snow surface and one that has a depression shows that atmospheric decoupling is strongly increased in the case of topographic sheltering but only for low to moderate wind speeds. For those conditions, the near-surface suppression of turbulent mixing was observed to be strongest and drainage flows were decoupled from the surface enhancing atmospheric stability and promoting the cold-air pooling over the single snow patch. Further work is required to systematically and quantitatively describe the flux distribution for varying terrain geometry, wind speeds and air temperatures.

  14. Development of Atmospheric Air 85Kr Monitoring Methodology on the Territory of the USSR

    NASA Astrophysics Data System (ADS)

    Pakhomov, Sergei; Dubasov, Yury

    2014-05-01

    Highly sensitive, low-background and high-performance method of beta-radioactivity measurements of the gas samples was developed in mid-eighties at Khlopin Radium institute. This method was based on the use of the serial automated installation for liquid scintillation measurements and special scintillating cells. Cells were equipped with the gas valve, and their internal surface were covered by a thin layer of organic scintillator. This method found was successfully was applied for 85Kr activity measurements in atmospheric krypton samples and for 85Kr concentration measurements in atmospheric air. For the first time, method developed for 85Kr activity measurements, was practically tested in May - June, 1986, while studying radioactive pollution characteristics in the air basin of Russia and Ukraine after the Chernobyl NPP accident. Thus for sampling of atmospheric krypton the industrial krypton-xenon mix manufactured at air-separating plants, located in the cities of Cherepovets, Lipetsk, Krivoi Rog and Enakiyevo was used. In the end of April and in the first half of May it was determined that 1,5-fold excess concentrations of 85Kr in atmospheric air were observed in atmospheric air of considerable part of the European territory of Russia and Ukraine During the period from 1987 to 1991 this method was used for monitoring of 85Kr on the territory of the former USSR in the air basin of Russia, Ukraine and Kazakhstan. Industrial krypton-xenon mix manufactured at 14 large air-separating plants was also used for sampling. Six of them were situated in Russia (Novomoskovsk, Lipetsk, Cherepovets, Chelyabinsk, Nizhni Tagil, Orsk). Seven - in Ukraine (Enakiyevo, Kommunarsk, Krivoi Rog, Makeyevka, Mariupol, Severodonetsk, Dneprodzerzhinsk). One plant was situated in Temirtau, in Kazakhstan. The analysis indicated that in Krivoi Rog; Dneprozhzerzhinsk; Severodonetsk; Makeyevka; Mariupol; Enakiyevo; Kommunarsk; Novomoskovsk and Cherepovets the average 85Kr concentration in

  15. Hydrogen Isotopic Composition of Arctic and Atmospheric CH4 Determined by a Portable Near-Infrared Cavity Ring-Down Spectrometer with a Cryogenic Pre-Concentrator

    NASA Astrophysics Data System (ADS)

    Chen, Y.; Lehmann, Kevin K.; Peng, Y.; Pratt, L. M.; White, J. R.; Cadieux, S. B.; Sherwood Lollar, B.; Lacrampe-Couloume, G.; Onstott, T. C.

    2016-10-01

    In this study, near-infrared continuous wave cavity ring-down spectroscopy was applied to the measurement of the δ2H of methane (CH4). The cavity ring-down spectrometer (CRDS) system consisted of multiple DFB laser diodes to optimize selection of spectral line pairs. By rapidly switching measurements between spectral line peaks and the baseline regions, the long-term instrumental drift was minimized, substantially increasing measurement precision. The CRDS system coupled with a cryogenic pre-concentrator measured the δ2H of terrestrial atmospheric CH4 from 3 standard liters of air with a precision of ±1.7‰. The rapidity with which both C and H isotopic measurements of CH4 can be made with the CRDS will enable hourly monitoring of diurnal variations in terrestrial atmospheric CH4 signatures that can be used to increase the resolution of global climate models for the CH4 cycle. Although the current instrument is not capable of measuring the δ2H of 10 ppbv of martian CH4, current technology does exist that could make this feasible for future spaceflight missions. As biological and abiotic CH4 sources have overlapping carbon isotope signatures, dual-element (C and H) analysis is key to reliable differentiation of these sources. Such an instrument package would therefore offer improved ability to determine whether or not the CH4 recently detected in the martian atmosphere is biogenic in origin.

  16. Long-term air temperature variation in the Karkonosze mountains according to atmospheric circulation

    NASA Astrophysics Data System (ADS)

    Migała, Krzysztof; Urban, Grzegorz; Tomczyński, Karol

    2016-07-01

    The results of meteorological measurements carried out continuously on Mt Śnieżka in Karkonosze mountains since 1880 well document the warming observed on a global scale. Data analysis indicates warming expressed by an increase in the mean annual air temperature of 0.8 °C/100 years. A much higher temperature increase was recorded in the last two decades at the turn of the twenty-first century. Mean decade air temperatures increased from -0.1 to 1.5 °C. It has been shown that there are relationships between air temperature at Mt Śnieżka and global mechanisms of atmospheric and oceanic circulation. Thermal conditions of the Karkonosze (Mt Śnieżka) accurately reflect global climate trends and impact of the North Atlantic Oscillation (NAO) index, macrotypes of atmospheric circulation in Europe (GWL) and Atlantic Multidecadal Oscillation (AMO). The increase in air temperature during the 1989-2012 solar magnetic cycle may reveal a synergy effect to which astrophysical effects and atmospheric and oceanic circulation effects contribute, modified by constantly increasing anthropogenic factors.

  17. On the evaluation of air mass factors for atmospheric near-ultraviolet and visible absorption spectroscopy

    NASA Technical Reports Server (NTRS)

    Perliski, Lori M.; Solomon, Susan

    1993-01-01

    The interpretation of UV-visible twilight absorption measurements of atmospheric chemical constituents is dependent on how well the optical path, or air mass factor, of light collected by the spectrometer is understood. A simple single scattering model and a Monte Carlo radiative transfer scheme have been developed to study the effects of multiple scattering, aerosol scattering, surface albedo and refraction on air mass factors for scattered light observations. At fairly short visible wavelengths (less than about 450 nm), stratospheric air mass factors are found to be relatively insensitive to multiple scattering, surface albedo and refraction, as well as aerosol scattering by background aerosols. Longer wavelengths display greater sensitivity to refraction and aerosol scattering. Tropospheric air mass factors are found to be highly dependent on aerosol scattering, surface albedo and, at long visible wavelengths (about 650 nm), refraction. Absorption measurements of NO2 and O4 are shown to support these conclusions.

  18. Time evolution of nanosecond runaway discharges in air and helium at atmospheric pressure

    SciTech Connect

    Yatom, S.; Vekselman, V.; Krasik, Ya. E.

    2012-12-15

    Time- and space-resolved fast framing photography was employed to study the discharge initiated by runaway electrons in air and He gas at atmospheric pressure. Whereas in the both cases, the discharge occurs in a nanosecond time scale and its front propagates with a similar velocity along the cathode-anode gap, the later stages of the discharge differ significantly. In air, the main discharge channels develop and remain in the locations with the strongest field enhancement. In He gas, the first, diode 'gap bridging' stage, is similar to that obtained in air; however, the development of the discharge that follows is dictated by an explosive electron emission from micro-protrusions on the edge of the cathode. These results allow us to draw conclusions regarding the different conductivity of the plasma produced in He and air discharges.

  19. Sources of Atmospheric Pollutants Impacting Air and Water Quality in the Lake Tahoe Basin

    NASA Astrophysics Data System (ADS)

    Gertler, A. W.; Cahill, T. A.; Gillies, J.; Kuhns, H.

    2008-12-01

    Starting in the second half of the 20th century, decline in Lake Tahoe's water clarity and degradation in the basin's air quality have become major concerns due to its unique scenic features. Gaseous and particulate nitrogen (N) and particulate phosphorus (P) loading via direct atmospheric deposition and sediment transport to the lake have also been implicated as responsible for its eutrophication and decline in water clarity. Estimates suggest that atmospheric N deposition contributes 55% of the total N loading to the lake, while atmospheric P deposition contributes 15% of the total P loading. In order to improve both air quality and, as a consequence, water quality, it is necessary to develop an understanding of the sources of the atmospheric pollutants. Once this is accomplished, it is possible to implement cost-effective strategies to reduce this impact. This paper summarizes the findings of a series of studies performed to determine the levels and sources of ambient air pollutants in the basin. Projects have included the development of a Tahoe-specific emissions inventory, long-term measurements of road dust resuspension, modeling to determine the fraction of pollutants coming from in-basin vs. out-of-basin sources, particulate source apportionment, and estimates of nitric acid deposition. These studies found that the pollutants most closely connected to the decline in water quality come largely from within basin sources, as opposed to those coming from the Central Valley and upwind urban areas of California. These results indicate regulators need to control pollutant emissions within the Tahoe basin in order to reduce the impact of atmospheric pollutants on both air and water quality.

  20. Infrared atmospheric pressure MALDI ion trap mass spectrometry of frozen samples using a Peltier-cooled sample stage.

    PubMed

    Von Seggern, Christopher E; Gardner, Ben D; Cotter, Robert J

    2004-10-01

    Infrared atmospheric pressure matrix-assisted laser desorption/ionization on an ion trap mass spectrometer is used to analyze frozen samples generated using a Peltier-cooled sample stage. This allows for the analysis of samples in water without the addition of matrix, in near-native conditions, and with minimal loss of water due to evaporation. Analysis of frozen samples is extended to study peptides, carbohydrates, and glycolipids.

  1. Coupled Inertial Navigation and Flush Air Data Sensing Algorithm for Atmosphere Estimation

    NASA Technical Reports Server (NTRS)

    Karlgaard, Christopher D.; Kutty, Prasad; Schoenenberger, Mark

    2016-01-01

    This paper describes an algorithm for atmospheric state estimation based on a coupling between inertial navigation and flush air data-sensing pressure measurements. The navigation state is used in the atmospheric estimation algorithm along with the pressure measurements and a model of the surface pressure distribution to estimate the atmosphere using a nonlinear weighted least-squares algorithm. The approach uses a high-fidelity model of atmosphere stored in table-lookup form, along with simplified models propagated along the trajectory within the algorithm to aid the solution. Thus, the method is a reduced-order Kalman filter in which the inertial states are taken from the navigation solution and atmospheric states are estimated in the filter. The algorithm is applied to data from the Mars Science Laboratory entry, descent, and landing from August 2012. Reasonable estimates of the atmosphere are produced by the algorithm. The observability of winds along the trajectory are examined using an index based on the observability Gramian and the pressure measurement sensitivity matrix. The results indicate that bank reversals are responsible for adding information content. The algorithm is applied to the design of the pressure measurement system for the Mars 2020 mission. A linear covariance analysis is performed to assess estimator performance. The results indicate that the new estimator produces more precise estimates of atmospheric states than existing algorithms.

  2. Performance assessment of future thermal infrared geostationary instruments to monitor air quality

    NASA Astrophysics Data System (ADS)

    Sellitto, P.; Dauphin, P.; Dufour, G.; Eremenko, M.; Cuesta, J.; Coman, A.; Forêt, G.; Beekmann, M.; Gaubert, B.; Flaud, J.-M.

    2012-04-01

    Air quality (AQ) has a recognized onerous impact on human health and the environment, and then on society. It is more and more clear that constantly and efficiently monitoring AQ from space is a valuable step forward towards a more thorough comprehension of pollution processes that can have a relevant impact on the biosphere. In recent years, important progresses in this field have been made, e.g., reliable observations of several pollutants have been obtained, proving the feasibility of monitoring atmospheric composition from space. In this sense, low Earth orbit (LEO) thermal infrared (TIR) space-borne instruments are widely regarded as a useful tool to observe targeted AQ parameters like tropospheric ozone concentrations [1]. However, limitations remain with the current observation systems in particular to observe ozone in the lowermost troposphere (LmT) with a spatial and temporal resolution relevant for monitoring pollution processes at the regional scale. Indeed, LEO instruments are not well adapted to monitor small scale and short term phenomena, owing to their unsatisfactory revisit time. From this point of view, a more satisfactory concept might be based on geostationary (GEO) platforms. Current and planned GEO missions are mainly tailored on meteorological parameters retrieval and do not have sufficient spectral resolutions and signal to noise ratios (SNR) to infer information on trace gases in the LmT. New satellite missions are currently proposed that can partly overcome these limitations. Here we present a group of simulation exercises and sensitivity analyses to set-up future TIR GEO missions adapted to monitor and forecast AQ over Europe, and to evaluate their technical requirements. At this aim, we have developed a general simulator to produce pseudo-observations for different platform/instrument configurations. The core of this simulator is the KOPRA radiative transfer model, including the KOPRAfit inversion module [2]. Note that to assess the

  3. Study of wind retrieval from space-borne infrared coherent lidar in cloudy atmosphere.

    NASA Astrophysics Data System (ADS)

    Baron, Philippe; Ishii, Shoken; Mizutani, Kohei; Okamoto, Kozo; Ochiai, Satoshi

    2015-04-01

    Future spaceborne tropospheric wind missions using infrared coherent lidar are currently being studied in Japan and in the United States [1,2]. The line-of-sight wind velocity is retrieved from the Doppler shift frequency of the signal returned by aerosol particles. However a large percentage (70-80%) of the measured single-shot intensity profiles are expected to be contaminated by clouds [3]. A large number of cloud contaminated profiles (>40%) will be characterized by a cloud-top signal intensity stronger than the aerosol signal by a factor of one order of magnitude, and by a strong attenuation of the signal backscattered from below the clouds. Profiles including more than one cloud layer are also expected. This work is a simulation study dealing with the impacts of clouds on wind retrieval. We focus on the three following points: 1) definition of an algorithm for optimizing the wind retrieval from the cloud-top signal, 2) assessment of the clouds impact on the measurement performance and, 3) definition of a method for averaging the measurements before the retrieval. The retrieval simulations are conducted considering the instrumental characteristics selected for the Japanese study: wavelength at 2 µm, PRF of 30 Hz, pulse power of 0.125 mJ and platform altitude between 200-400 km. Liquid and ice clouds are considered. The analysis uses data from atmospheric models and statistics of cloud effects derived from CALIPSO measurements such as in [3]. A special focus is put on the average method of the measurements before retrieval. Good retrievals in the mid-upper troposphere implie the average of measured single-range power spectra over large horizontal (100 km) and vertical (1 km) ranges. Large differences of signal intensities due to the presence of clouds and the clouds non-uniform distribution have to be taken into account when averaging the data to optimize the measurement performances. References: [1] S. Ishii, T. Iwasaki, M. Sato, R. Oki, K. Okamoto, T

  4. Project 1640 Observations of Brown Dwarf GJ 758 B: Near-infrared Spectrum and Atmospheric Modeling

    NASA Astrophysics Data System (ADS)

    Nilsson, R.; Veicht, A.; Giorla Godfrey, P. A.; Rice, E. L.; Aguilar, J.; Pueyo, L.; Roberts, L. C., Jr.; Oppenheimer, R.; Brenner, D.; Luszcz-Cook, S. H.; Bacchus, E.; Beichman, C.; Burruss, R.; Cady, E.; Dekany, R.; Fergus, R.; Hillenbrand, L.; Hinkley, S.; King, D.; Lockhart, T.; Parry, I. R.; Sivaramakrishnan, A.; Soummer, R.; Vasisht, G.; Zhai, C.; Zimmerman, N. T.

    2017-03-01

    The nearby Sun-like star GJ 758 hosts a cold substellar companion, GJ 758 B, at a projected separation of ≲30 au, previously detected in high-contrast multi-band photometric observations. In order to better constrain the companion’s physical characteristics, we acquired the first low-resolution (R ∼ 50) near-infrared spectrum of it using the high-contrast hyperspectral imaging instrument Project 1640 on Palomar Observatory’s 5 m Hale telescope. We obtained simultaneous images in 32 wavelength channels covering the Y, J, and H bands (∼952–1770 nm), and used data processing techniques based on principal component analysis to efficiently subtract chromatic background speckle-noise. GJ 758 B was detected in four epochs during 2013 and 2014. Basic astrometric measurements confirm its apparent northwest trajectory relative to the primary star, with no clear signs of orbital curvature. Spectra of SpeX/IRTF observed T dwarfs were compared to the combined spectrum of GJ 758 B, with χ 2 minimization suggesting a best fit for spectral type T7.0 ± 1.0, but with a shallow minimum over T5–T8. Fitting of synthetic spectra from the BT-Settl13 model atmospheres gives an effective temperature T eff = 741 ± 25 K and surface gravity {log}g=4.3+/- 0.5 dex (cgs). Our derived best-fit spectral type and effective temperature from modeling of the low-resolution spectrum suggest a slightly earlier and hotter companion than previous findings from photometric data, but do not rule out current results, and confirm GJ 758 B as one of the coolest sub-stellar companions to a Sun-like star to date.

  5. Statistical model for atmospheric limb radiance structure: application to airborne infrared surveillance systems

    NASA Astrophysics Data System (ADS)

    Quang, Carine; Dalaudier, Francis; Roblin, Antoine; Rialland, Valérie; Chervet, Patrick

    2008-10-01

    Infrared (IR) detectors can be used as airborne limb-viewing surveillance systems for missile detection. These systems' performances are impacted by the atmospheric inhomogeneous background. In fact, the probability of target detection can be heavily affected. Consequently, the knowledge of these radiance small-scale fluctuations and their statistical properties is required to assess these systems' detection capability. A model of two-dimensional radiance spatial fluctuations autocorrelation function (ACF) is developed. This model is dedicated to airborne limb-viewing conditions in the thermal IR. In the stratosphere and in clear-sky conditions, the structured background is mainly due to internal-gravity-wave-induced temperature and density spatial fluctuations. Moreover, in the particular case of water vapour absorption bands, the mass fraction fluctuations play a non negligible role on the radiative field. Thereby, considering the temperature field and the water vapour field as stochastic processes, the radiance ACF can be expressed as a function of the temperature ACF and the water vapor mass fraction ACF. A local thermodynamic equilibrium model is sufficient for stratospheric conditions and sunlight scattering is neglected in the thermal IR. In addition, determination of the radiance fluctuations ACF requires the knowledge of the absorption coefficient and its first derivatives with respect to the temperature and water vapour mass fraction. Thus, a line-by-line model specific to water vapor absorption bands has been developed. This model is used to precalculate the absorption coefficients and their derivatives. This look-up table method allows circumventing the computational cost of a line-by-line calculation. A detailed description of the radiance fluctuations ACF model is presented and first results are discussed.

  6. Atmospheric organochlorine pollutants and air-sea exchange of hexachlorocyclohexane in the Bering and Chukchi Seas

    USGS Publications Warehouse

    Hinckley, D.A.; Bidleman, T.F.; Rice, C.P.

    1991-01-01

    Organochlorine pesticides have been found in Arctic fish, marine mammals, birds, and plankton for some time. The lack of local sources and remoteness of the region imply long-range transport and deposition of contaminants into the Arctic from sources to the south. While on the third Soviet-American Joint Ecological Expedition to the Bering and Chukchi Seas (August 1988), high-volume air samples were taken and analyzed for organochlorine pesticides. Hexachlorocyclohexane (HCH), hexachlorobenzene, polychlorinated camphenes, and chlordane (listed in order of abundance, highest to lowest) were quantified. The air-sea gas exchange of HCH was estimated at 18 stations during the cruise. Average alpha-HCH concentrations in concurrent atmosphere and surface water samples were 250 pg m-3 and 2.4 ng L-1, respectively, and average gamma-HCH concentrations were 68 pg m-3 in the atmosphere and 0.6 ng L-1 in surface water. Calculations based on experimentally derived Henry's law constants showed that the surface water was undersaturated with respect to the atmosphere at most stations (alpha-HCH, average 79% saturation; gamma-HCH, average 28% saturation). The flux for alpha-HCH ranged from -47 ng m-2 day-1 (sea to air) to 122 ng m-2 d-1 (air to sea) and averaged 25 ng m-2 d-1 air to sea. All fluxes of gamma-HCH were from air to sea, ranged from 17 to 54 ng m-2 d-1, and averaged 31 ng m-2 d-1.

  7. Atmospheric organochlorine pollutants and air-sea exchange of hexachlorocyclohexane in the Bering and Chukchi Seas

    SciTech Connect

    Hinckley, D.A.; Bidleman, T.F. ); Rice, C.P. )

    1991-04-15

    Organochlorine pesticides have been found in Arctic fish, marine mammals, birds, and plankton for some time. The lack of local sources and remoteness of the region imply long-range transport and deposition of contaminants into the Arctic from sources to the south. While on the third Soviet-American Joint Ecological Expedition to the Bering and Chukchi Seas (August 1988), high-volume air samples were taken and analyzed for organochlorine pesticides. Hexachlorocyclohexane (HCH), hexachlorobenzene, polychlorinated camphenes, and chlordane (listed in order of abundance, highest to lowest) were quantified. The air-sea gas exchange of HCH was estimated at 18 stations during the cruise. Average {alpha}-HCH concentrations in concurrent atmosphere and surface water samples were 250 pg/m{sup 3} and 2.4 ng/l, respectively, and average {gamma}-HCH concentrations were 68 pg/m{sup 3} in the atmosphere and 0.6 ng/l in surface water. Calculations based on experimentally derived Henry's law constants showed that the surface water was undersaturated with respect to the atmosphere at most stations ({alpha}-HCH, average 79% saturation; {gamma}-HCH, average 28% saturation). The flux for {alpha}-HCH ranged from {minus}47 ng/m{sup 2} day (sea to air) to 122 ng/m{sup 2} day (air to sea) and averaged 25 ng/m{sup 2} day air to sea. All fluxes of {gamma}-HCH were from air to sea, ranged from 17 to 54 ng/m{sup 2} day, and averaged 31 ng/m{sup 2} day.

  8. Study of the atmospheric conditions affecting infrared astronomical measurements at White Mountain, California

    NASA Technical Reports Server (NTRS)

    Field, G. B.

    1974-01-01

    Measurements are described of atmospheric conditions affecting astronomical observations at White Mountain, California. Measurements were made at more than 1400 times spaced over more than 170 days at the Summit Laboratory and a small number of days at the Barcroft Laboratory. The recorded quantities were ten micron sky noise and precipitable water vapor, plus wet and dry bulb temperatures, wind speed and direction, brightness of the sky near the sun, fisheye lens photographs of the sky, description of cloud cover and other observable parameters, color photographs of air pollution astronomical seeing, and occasional determinations of the visible light brightness of the night sky. Measurements of some of these parameters have been made for over twenty years at the Barcroft and Crooked Creek Laboratories, and statistical analyses were made of them. These results and interpretations are given. The bulk of the collected data are statistically analyzed, and disposition of the detailed data is described. Most of the data are available in machine readable form. A detailed discussion of the techniques proposed for operation at White Mountain is given, showing how to cope with the mountain and climatic problems.

  9. Atmospheric correction using near-infrared bands for satellite ocean color data processing in the turbid western Pacific region.

    PubMed

    Wang, Menghua; Shi, Wei; Jiang, Lide

    2012-01-16

    A regional near-infrared (NIR) ocean normalized water-leaving radiance (nL(w)(λ)) model is proposed for atmospheric correction for ocean color data processing in the western Pacific region, including the Bohai Sea, Yellow Sea, and East China Sea. Our motivation for this work is to derive ocean color products in the highly turbid western Pacific region using the Geostationary Ocean Color Imager (GOCI) onboard South Korean Communication, Ocean, and Meteorological Satellite (COMS). GOCI has eight spectral bands from 412 to 865 nm but does not have shortwave infrared (SWIR) bands that are needed for satellite ocean color remote sensing in the turbid ocean region. Based on a regional empirical relationship between the NIR nL(w)(λ) and diffuse attenuation coefficient at 490 nm (K(d)(490)), which is derived from the long-term measurements with the Moderate-resolution Imaging Spectroradiometer (MODIS) on the Aqua satellite, an iterative scheme with the NIR-based atmospheric correction algorithm has been developed. Results from MODIS-Aqua measurements show that ocean color products in the region derived from the new proposed NIR-corrected atmospheric correction algorithm match well with those from the SWIR atmospheric correction algorithm. Thus, the proposed new atmospheric correction method provides an alternative for ocean color data processing for GOCI (and other ocean color satellite sensors without SWIR bands) in the turbid ocean regions of the Bohai Sea, Yellow Sea, and East China Sea, although the SWIR-based atmospheric correction approach is still much preferred. The proposed atmospheric correction methodology can also be applied to other turbid coastal regions.

  10. The Zugspitze radiative closure experiment: quantification of the near-infrared water vapor continuum from atmospheric measurements

    NASA Astrophysics Data System (ADS)

    Reichert, Andreas; Sussmann, Ralf; Rettinger, Markus

    2016-04-01

    Inaccuracies in the description of atmospheric radiative processes are among the major shortcomings of current climate models. Especially the contribution by water vapor, the primary greenhouse gas in the Earth's atmosphere, currently still lacks sufficiently accurate quantification. The main focus of our study is on the so-called water vapor continuum absorption in the near-infrared spectral range, which is of crucial importance for atmospheric radiative processes. To date, the quantification of this contribution originates exclusively from laboratory experiments which show contradictory results and whose findings are not unambiguously transferable to atmospheric conditions. The aim of the Zugspitze radiative closure study is therefore to obtain, to our knowledge for the first time, an exact characterization of the near-infrared water vapor continuum absorption using atmospheric measurements. This enables validation and, if necessary, improvements of the radiative transfer codes used in current climate models. The closure experiment comprises near-infrared spectral radiance measurements using a solar absorption FTIR spectrometer. These measurements are then compared to synthetic radiance spectra computed by means of a high-resolution radiative transfer model. The spectral residuals, i.e. the difference between measured and calculated spectral radiances can then be used to quantify errors in the description of water vapor absorption. Due to the extensive permanent instrumentation available at the Zugspitze observatory, the atmospheric state used as an input to the model calculations can be constrained with high accuracy. Additionally, we employ a novel radiometric calibration strategy for the solar FTIR spectral radiance measurements based on a combination of the Langley method and measurements of a medium-temperature blackbody source. These prerequisites enable accurate quantification of the water vapor continuum in the near-infrared spectral region, where

  11. Thermal Characteristics of Air in the Problem of Hypersonic Motion of Bodies in the Earth's Atmosphere

    NASA Astrophysics Data System (ADS)

    Alhussan, K.; Morozov, D. O.; Stankevich, Yu. A.; Stanchits, L. K.; Stepanov, K. L.

    2014-07-01

    The thermal properties of hot air needed for describing the hypersonic motion of bodies in the Earth's atmosphere have been considered. Such motion, as is known, is accompanied by the propagation of strong shock waves analogous to waves generated by powerful explosions. Calculations have been made and data banks have been created for the equations of state and thermal characteristics of air in the temperature and density ranges corresponding to velocities of motion of bodies of up to 10 km/s at altitudes of 0-100 km. The formulation of the problem of hypersonic motion in the absence of thermodynamic equilibrium is discussed.

  12. Dust Event of April 23-24, 2014 in the Northwest China and Changes in Air Quality, Atmospheric and Meteorological Parameters

    NASA Astrophysics Data System (ADS)

    Zheng, S.; Cao, C.; Singh, R. P.

    2014-12-01

    Dust season is prevalent every year during spring season (March-May) affecting the Northern parts of China. A strong cold air from the Western Siberia started affecting the Northern parts of China on April 22, 2014. On April 23-24, 2014, a massive dust storm blanketed the Northwest China including Xinjiang, Gansu, Qinghai, Ningxia, and Shanxi provinces. The Moderate Resolution Imaging Spectroradiometer (MODIS) Terra images clearly show the long range transport of dust storms. Higher concentrations of atmospheric (satellite aerosol optical depth - AOD) and air quality (PM10 and PM2.5) were observed after the dust event. The Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model was used to produce forward dispersion patterns of pollutants from the source locations. It is found that the dust disperse from west to east in the Northwest region of China. We have considered three locations along dust flow (Urumchi in Xinjiang, Jiayuguan in Gansu, and Yinchuan in Ningxia provinces). Using Atmospheric Infrared Sounder (AIRS) and ground data, we have analyzed changes in carbon monoxide (CO), water vapor, and relative humidity (RH) at different pressure levels with the dust storms. The results show distinct differences in these meteorological parameters during dusty days at the three locations. Our analysis shows changes in total column CO, ground and upper layer CO concentrations, water vapor mass mixing ratio and relative humidity. The changes in atmospheric and meteorological parameters and their impacts on the regional weather and climate will be discussed.

  13. Air-stable few-layer black phosphorus phototransistor for near-infrared detection

    NASA Astrophysics Data System (ADS)

    Na, Junhong; Park, Kichul; Kim, Jin Tae; Choi, Won Kook; Song, Yong-Won

    2017-02-01

    We have demonstrated a few-layer black phosphorus (BP) phototransistor of stable operation in ambient air environment and at near-infrared light (λ = 1550 nm). The air-stable electronic and optoelectronic properties of the few-layer BP phototransistor have been achieved by a proper Al2O3 passivation. The optical identification method and qualitative and quantitative electrical characterizations of the few-layer BP phototransistor in dark state confirmed that the device performance was robust in ambient air, to further chemical treatments, and storage of more than six months. In addition, the low-frequency noise characterizations had revealed that the noise spectral density related to the sensitivity of phototransistor was reduced. Owing to the suppression of interaction between few-layer BP and adsorbates arising from the Al2O3 passivation, a fast rise time of the few-layer BP phototransistor, less than 100 μs, had been observed, demonstrating the intrinsic photoresponse properties of few-layer BP. The low dark current of ˜4 nA at the operation bias and the reasonable responsivity of ˜6 mA W-1 were obtained under the condition lacking adsorbates interactions. Internally, the dark current and responsivity level was tunable by changing the operation bias. Our results are close to the intrinsic properties of the few-layer BP phototransistor, implying that it can be a building block of functioned few-layer BP photodetectors.

  14. The influence of scales of atmospheric motion on air pollution over Portugal

    NASA Astrophysics Data System (ADS)

    Russo, Ana; Trigo, Ricardo; Mendes, Manuel; Jerez, Sonia; Gouveia, Célia Marina

    2014-05-01

    Air pollution is determined by the combination of different factors, namely, emissions, physical constrains, meteorology and chemical processes [1,2,3]. The relative importance of such factors is influenced by their interaction on diverse scales of atmospheric motion. Each scale depicts different meteorological conditions, which, when combined with the different air pollution sources and photochemistry, result in varying ambient concentrations [2]. Identifying the dominant scales of atmospheric motion over a given airshed can be of great importance for many applications such as air pollution and pollen dispersion or wind energy management [2]. Portugal has been affected by numerous air pollution episodes during the last decade. These episodes are often related to peak emissions from local industry or transport, but can also be associated to regional transport from other urban areas or to exceptional emission events, such as forest fires. This research aims to identify the scales of atmospheric motion which contribute to an increase of air pollution. A method is proposed for differentiating between the scales of atmospheric motion that can be applied on a daily basis from data collected at several wind-measuring sites in a given airshed and to reanalysis datasets. The method is based on the daily mean wind recirculation and the mean and standard deviation between sites. The determination of the thresholds between scales is performed empirically following the approach of Levy et al. [2] and also through a automatic statistical approach computed taking into account the tails of the distributions (e.g. 95% and 99% percentile) of the different wind samples. A comparison is made with two objective approaches: 1) daily synoptic classification for the same period over the region [4] and 2) a 3-D backward trajectory approach [5,6] for specific episodes. Furthermore, the outcomes are expected to support the Portuguese authorities on the implementation of strategies for a

  15. Parameters of a supershort avalanche electron beam generated in atmospheric-pressure air

    SciTech Connect

    Tarasenko, V. F.

    2011-05-15

    Conditions under which the number of runaway electrons in atmospheric-pressure air reaches {approx}5 Multiplication-Sign 10{sup 10} are determined. Recommendations for creating runaway electron accelerators are given. Methods for measuring the parameters of a supershort avalanche electron beam and X-ray pulses from gas-filled diodes, as well as the discharge current and gap voltage, are described. A technique for determining the instant of runaway electron generation with respect to the voltage pulse is proposed. It is shown that the reduction in the gap voltage and the decrease in the beam current coincide in time. The mechanism of intense electron beam generation in gas-filled diodes is analyzed. It is confirmed experimentally that, in optimal regimes, the number of electrons generated in atmospheric-pressure air with energies T > eU{sub m}, where U{sub m} is the maximum gap voltage, is relatively small.

  16. Airborne mass spectrometers: four decades of atmospheric and space research at the Air Force research laboratory.

    PubMed

    Viggiano, A A; Hunton, D E

    1999-11-01

    Mass spectrometry is a versatile research tool that has proved to be extremely useful for exploring the fundamental nature of the earth's atmosphere and ionosphere and in helping to solve operational problems facing the Air Force and the Department of Defense. In the past 40 years, our research group at the Air Force Research Laboratory has flown quadrupole mass spectrometers of many designs on nearly 100 sounding rockets, nine satellites, three Space Shuttles and many missions of high-altitude research aircraft and balloons. We have also used our instruments in ground-based investigations of rocket and jet engine exhaust, combustion chemistry and microwave breakdown chemistry. This paper is a review of the instrumentation and techniques needed for space research, a summary of the results from many of the experiments, and an introduction to the broad field of atmospheric and space mass spectrometry in general.

  17. Parameters of a supershort avalanche electron beam generated in atmospheric-pressure air

    NASA Astrophysics Data System (ADS)

    Tarasenko, V. F.

    2011-05-01

    Conditions under which the number of runaway electrons in atmospheric-pressure air reaches ˜5 × 1010 are determined. Recommendations for creating runaway electron accelerators are given. Methods for measuring the parameters of a supershort avalanche electron beam and X-ray pulses from gas-filled diodes, as well as the discharge current and gap voltage, are described. A technique for determining the instant of runaway electron generation with respect to the voltage pulse is proposed. It is shown that the reduction in the gap voltage and the decrease in the beam current coincide in time. The mechanism of intense electron beam generation in gas-filled diodes is analyzed. It is confirmed experimentally that, in optimal regimes, the number of electrons generated in atmospheric-pressure air with energies T > eU m , where U m is the maximum gap voltage, is relatively small.

  18. GARLIC - A general purpose atmospheric radiative transfer line-by-line infrared-microwave code: Implementation and evaluation

    NASA Astrophysics Data System (ADS)

    Schreier, Franz; Gimeno García, Sebastián; Hedelt, Pascal; Hess, Michael; Mendrok, Jana; Vasquez, Mayte; Xu, Jian

    2014-04-01

    A suite of programs for high resolution infrared-microwave atmospheric radiative transfer modeling has been developed with emphasis on efficient and reliable numerical algorithms and a modular approach appropriate for simulation and/or retrieval in a variety of applications. The Generic Atmospheric Radiation Line-by-line Infrared Code - GARLIC - is suitable for arbitrary observation geometry, instrumental field-of-view, and line shape. The core of GARLIC's subroutines constitutes the basis of forward models used to implement inversion codes to retrieve atmospheric state parameters from limb and nadir sounding instruments. This paper briefly introduces the physical and mathematical basics of GARLIC and its descendants and continues with an in-depth presentation of various implementation aspects: An optimized Voigt function algorithm combined with a two-grid approach is used to accelerate the line-by-line modeling of molecular cross sections; various quadrature methods are implemented to evaluate the Schwarzschild and Beer integrals; and Jacobians, i.e. derivatives with respect to the unknowns of the atmospheric inverse problem, are implemented by means of automatic differentiation. For an assessment of GARLIC's performance, a comparison of the quadrature methods for solution of the path integral is provided. Verification and validation are demonstrated using intercomparisons with other line-by-line codes and comparisons of synthetic spectra with spectra observed on Earth and from Venus.

  19. Atmospheric Parameter Climatologies from AIRS: Monitoring Short-, and Longer-Term Climate Variabilities and 'Trends'

    NASA Technical Reports Server (NTRS)

    Molnar, Gyula; Susskind, Joel

    2008-01-01

    The AIRS instrument is currently the best space-based tool to simultaneously monitor the vertical distribution of key climatically important atmospheric parameters as well as surface properties, and has provided high quality data for more than 5 years. AIRS analysis results produced at the GODDARD/DAAC, based on Versions 4 & 5 of the AIRS retrieval algorithm, are currently available for public use. Here, first we present an assessment of interrelationships of anomalies (proxies of climate variability based on 5 full years, since Sept. 2002) of various climate parameters at different spatial scales. We also present AIRS-retrievals-based global, regional and 1x1 degree grid-scale "trend"-analyses of important atmospheric parameters for this 5-year period. Note that here "trend" simply means the linear fit to the anomaly (relative the mean seasonal cycle) time series of various parameters at the above-mentioned spatial scales, and we present these to illustrate the usefulness of continuing AIRS-based climate observations. Preliminary validation efforts, in terms of intercomparisons of interannual variabilities with other available satellite data analysis results, will also be addressed. For example, we show that the outgoing longwave radiation (OLR) interannual spatial variabilities from the available state-of-the-art CERES measurements and from the AIRS computations are in remarkably good agreement. Version 6 of the AIRS retrieval scheme (currently under development) promises to further improve bias agreements for the absolute values by implementing a more accurate radiative transfer model for the OLR computations and by improving surface emissivity retrievals.

  20. Characterization of an atmospheric pressure air plasma source for polymer surface modification

    NASA Astrophysics Data System (ADS)

    Yang, Shujun; Tang, Jiansheng

    2013-10-01

    An atmospheric pressure air plasma source was generated through dielectric barrier discharge (DBD). It was used to modify polyethyleneterephthalate (PET) surfaces with very high throughput. An equivalent circuit model was used to calculate the peak average electron density. The emission spectrum from the plasma was taken and the main peaks in the spectrum were identified. The ozone density in the down plasma region was estimated by Absorption Spectroscopy. NSF and ARC-ODU

  1. Collaborative Study for Analysis of High Resolution Infrared Atmospheric Spectra Between NASA Langley Research Center and the University of Denver

    NASA Technical Reports Server (NTRS)

    Goldman, A.

    2002-01-01

    The Langley-D.U. collaboration on the analysis of high resolultion infrared atmospheric spectra covered a number of important studies of trace gases identification and quantification from field spectra, and spectral line parameters analysis. The collaborative work included: 1) Quantification and monitoring of trace gases from ground-based spectra available from various locations and seasons and from balloon flights; 2) Identification and preliminary quantification of several isotopic species, including oxygen and Sulfur isotopes; 3) Search for new species on the available spectra, including the use of selective coadding of ground-based spectra for high signal to noise; 4) Update of spectroscopic line parameters, by combining laboratory and atmospheric spectra with theoretical spectroscopy methods; 5) Study of trends and correlations of atmosphere trace constituents; and 6) Algorithms developments, retrievals intercomparisons and automatization of the analysis of NDSC spectra, for both column amounts and vertical profiles.

  2. Collaborative Study of Analysis of High Resolution Infrared Atmospheric Spectra Between NASA Langley Research Center and the University of Denver

    NASA Technical Reports Server (NTRS)

    Goldman, Aaron

    1999-01-01

    The Langley-D.U. collaboration on the analysis of high resolution infrared atmospheric spectra covered a number of important studies of trace gases identification and quantification from field spectra, and spectral line parameters analysis. The collaborative work included: Quantification and monitoring of trace gases from ground-based spectra available from various locations and seasons and from balloon flights. Studies toward identification and quantification of isotopic species, mostly oxygen and Sulfur isotopes. Search for new species on the available spectra. Update of spectroscopic line parameters, by combining laboratory and atmospheric spectra with theoretical spectroscopy methods. Study of trends of atmosphere trace constituents. Algorithms developments, retrievals intercomparisons and automatization of the analysis of NDSC spectra, for both column amounts and vertical profiles.

  3. Air exposure of coral is a significant source of dimethylsulfide (DMS) to the atmosphere

    NASA Astrophysics Data System (ADS)

    Hopkins, Frances E.; Bell, Thomas G.; Yang, Mingxi; Suggett, David J.; Steinke, Michael

    2016-10-01

    Corals are prolific producers of dimethylsulfoniopropionate (DMSP). High atmospheric concentrations of the DMSP breakdown product dimethylsulfide (DMS) have been linked to coral reefs during low tides. DMS is a potentially key sulfur source to the tropical atmosphere, but DMS emission from corals during tidal exposure is not well quantified. Here we show that gas phase DMS concentrations (DMSgas) increased by an order of magnitude when three Indo-Pacific corals were exposed to air in laboratory experiments. Upon re-submersion, an additional rapid rise in DMSgas was observed, reflecting increased production by the coral and/or dissolution of DMS-rich mucus formed by the coral during air exposure. Depletion in DMS following re-submersion was likely due to biologically-driven conversion of DMS to dimethylsulfoxide (DMSO). Fast Repetition Rate fluorometry showed downregulated photosynthesis during air exposure but rapid recovery upon re-submersion, suggesting that DMS enhances coral tolerance to oxidative stress during a process that can induce photoinhibition. We estimate that DMS emission from exposed coral reefs may be comparable in magnitude to emissions from other marine DMS hotspots. Coral DMS emission likely comprises a regular and significant source of sulfur to the tropical marine atmosphere, which is currently unrecognised in global DMS emission estimates and Earth System Models.

  4. Variable air temperature response of gas-phase atmospheric polychlorinated biphenyls near a former manufacturing facility.

    PubMed

    Hermanson, Mark H; Scholten, Cheryl A; Compher, Kevin

    2003-09-15

    Many investigations of gas-phase atmospheric PCB show a strong relationship between concentration and air temperature, especially near PCB sources. Comparative gas-phase atmospheric PCB trends during an annual temperature regime at two sites near a former PCB manufacturing plant and nearby PCB landfills in Anniston, AL, indicate a departure from this trend. The Mars Hill sampling site, located closest to the plant and landfills, shows an annual average sigmaPCB concentration of 27 ng m(-3) (ranging from 8.7 to 82 ng m(-3)) three times the average at Carter, 1.5 km away (9 ng m(-3), ranging from 1.1 to 39). However, total PCB and congener concentrations vary more with air temperature at Carter where PCB are evaporating from surfaces during warmer weather. The slopes of the Clausius-Clapeyron plots of 18 of the most concentrated congeners representing dichloro- through heptachlorobiphenyl homologues are significantly higher at the Carter site. While some of the atmospheric PCB at Mars Hill is derived from ground surface evaporation, the source of much of it apparently is the material buried in the landfills, which has different thermal properties than surface materials and is not in equilibrium with air temperature.

  5. Air exposure of coral is a significant source of dimethylsulfide (DMS) to the atmosphere

    PubMed Central

    Hopkins, Frances E.; Bell, Thomas G.; Yang, Mingxi; Suggett, David J.; Steinke, Michael

    2016-01-01

    Corals are prolific producers of dimethylsulfoniopropionate (DMSP). High atmospheric concentrations of the DMSP breakdown product dimethylsulfide (DMS) have been linked to coral reefs during low tides. DMS is a potentially key sulfur source to the tropical atmosphere, but DMS emission from corals during tidal exposure is not well quantified. Here we show that gas phase DMS concentrations (DMSgas) increased by an order of magnitude when three Indo-Pacific corals were exposed to air in laboratory experiments. Upon re-submersion, an additional rapid rise in DMSgas was observed, reflecting increased production by the coral and/or dissolution of DMS-rich mucus formed by the coral during air exposure. Depletion in DMS following re-submersion was likely due to biologically-driven conversion of DMS to dimethylsulfoxide (DMSO). Fast Repetition Rate fluorometry showed downregulated photosynthesis during air exposure but rapid recovery upon re-submersion, suggesting that DMS enhances coral tolerance to oxidative stress during a process that can induce photoinhibition. We estimate that DMS emission from exposed coral reefs may be comparable in magnitude to emissions from other marine DMS hotspots. Coral DMS emission likely comprises a regular and significant source of sulfur to the tropical marine atmosphere, which is currently unrecognised in global DMS emission estimates and Earth System Models. PMID:27796323

  6. Formation of thermal flow fields and chemical transport in air and water by atmospheric plasma

    NASA Astrophysics Data System (ADS)

    Shimizu, Tetsuji; Iwafuchi, Yutaka; Morfill, Gregor E.; Sato, Takehiko

    2011-05-01

    Cold atmospheric plasma is a potential tool for medical purposes, e.g. disinfection/sterilization. In order for it to be effective and functional, it is crucial to understand the transport mechanism of chemically reactive species in air as well as in liquid. An atmospheric plasma discharge was produced between a platinum pin electrode and the surface of water. The thermal flow field of a cold atmospheric plasma as well as its chemical components was measured. A gas flow with a velocity of around 15 m s-1 to the water's surface was shown to be induced by the discharge. This air flow induced a circulating flow in the water from the discharge point at the water's surface because of friction. It was also demonstrated that the chemical components generated in air dissolved in water and the properties of the water changed. The reactive species were believed to be distributed mainly by convective transport in water, because the variation in the pH profile indicated by a methyl red solution resembled the induced flow pattern.

  7. Reconstructing Atmospheric Histories of Halogenated Compounds to Preindustrial Times Using Antarctic Firn Air

    NASA Astrophysics Data System (ADS)

    Shields, J. E.; Mühle, J.; Severinghaus, J. P.; Weiss, R. F.

    2007-12-01

    Atmospheric histories of many halogenated trace gases remain poorly known, hampering understanding of lifetimes and anthropogenic impacts. A profile of air samples dating back to the late 19th century was collected from the firn at the Megadunes site in central Antarctica (80.78° S, 124.5° E) in January 2004. A number of anthropogenic halogenated compounds were measured in these samples using the AGAGE Medusa gas chromatograph-mass spectrometer instrumentation (B. R. Miller et al., in preparation). A firn gas-diffusion forward model based on the work of Schwander et al. (1993) was tuned to CO2 and 15N observations from the same Megadunes site. The age distribution of CO2 in diffusively mixed air samples collected at each depth was approximated by running short pulses through the forward model. The atmospheric histories of a number of halogenated compounds were then reconstructed using the iterative dating technique developed by Trudinger et al. (2002). The modeled age spread at this site is relatively broad, but interstitial air at the close-off zone is comparatively old with a mean age of about 100 years. Reconstructed histories show good agreement with direct measurements, although rapid changes are not well resolved. The mixing ratios of the deepest layer are within the range of preindustrial estimates, most notably for tetrafluoromethane. Schwander, J., J. M. Barnola, C. Andrie, M. Leuenberger, A. Ludin, D. Raynaud, B. Stauffer (1993). The Age of the Air in the Firn and the Ice at Summit, Greenland. J. Geophys. Res. 98(D2): 2831-2838. Trudinger, C. M., D. M. Etheridge, G. A. Sturrock, P. J. Fraser, P. B. Krummel, and A. McCulloch (2004). Atmospheric histories of halocarbons from analysis of Antarctic firn air: Methyl bromide, methyl chloride, chloroform, and dichloromethane. J. Geophys. Res. 109(D22310): doi:10.1029/2004JD004932.

  8. [Near infrared spectroscopy (NIRS) in a neurocritical patient with an air embolisism and pneumocephalus].

    PubMed

    Rodríguez Díaz-Regañón, I; Benatar-Haserfaty, J; Perez, J C

    2015-02-01

    The pneumocephalus is commonly encountered after neurosurgical procedures. The collections are usually small with benign behavior, and they respond to a conservative therapy. However, there is a high percentage of cases that may behave like a space-occupying lesion. A high index of suspicion is necessary to make the diagnosis and prompt treatment of these cases. Monitoring Near infra-red spectrometry (NIRS) monitoring could help to complete the diagnosis and treatment in these cases. A venous air embolism is a common complication in neurosurgical procedures that are performed in a sitting position, where this monitoring has also been shown to be useful. In the case presented, NIRS monitoring, along with clinical and analytical data, was used for the diagnosis of the two complications.

  9. Air Force Electronic Warfare Evaluation Simulator (AFEWES) infrared test and evaluation capabilities

    NASA Astrophysics Data System (ADS)

    Jackson, Hank D., II; Shepherd, Seth D.

    2004-08-01

    The Air Force Electronic Warfare Evaluation Simulator (AFEWES) Infrared Countermeasures (IRCM) test facility currently has the ability to simulate a complete IRCM test environment, including IR missiles in flight, aircraft in flight, and various IR countermeasures including maneuvers, point-source flares and lamp- and LASER-based jammer systems. The simulations of IR missiles in flight include missile seeker hardware mounted on a six degree-of-freedom flight simulation table. This paper will focus on recent developments and upgrades to the AFEWES IR capability. In particular, current developments in IR scene generation/projection and efforts to optically combining the IR image produced by a resistive array with existing foreground lamp sources.

  10. Air Force electronic warfare evaluation simulator (AFEWES) infrared test and evaluation capabilities

    NASA Astrophysics Data System (ADS)

    Jackson, Hank D., II; Blair, Tommy L.; Ensor, Bruce A.; Deyo, Charles R.; Longbottom, Jeff A.; White, Jason C.

    2005-05-01

    The Air Force Electronic Warfare Evaluation Simulator (AFEWES) Infrared Countermeasures (IRCM) test facility currently has the ability to simulate a complete IRCM test environment, including IR missiles in flight, aircraft in flight, and various IR countermeasures including maneuvers, point-source flares, and lamp- and LASER-based jammer systems. The simulations of IR missiles in flight include missile seeker hardware mounted on a six degree-of-freedom flight simulation table. This paper will focus on recent developments and upgrades to the AFEWES IR capability. In particular, current developments in IR scene generation/projection and efforts to optically combining the IR image produced by a resistive array with existing foreground lamp sources.

  11. Air Force Electronic Warfare Evaluation Simulator (AFEWES) infrared test and evaluation capabilities

    NASA Astrophysics Data System (ADS)

    Jackson, Hank D., II; Blair, Tommy L.; Ensor, Bruce A.

    2007-04-01

    The Air Force Electronic Warfare Evaluation Simulator (AFEWES) Infrared Countermeasures (IRCM) test facility currently has the ability to simulate a complete IRCM test environment, including IR missiles in flight, aircraft in flight, and various IR countermeasures including maneuvers, point-source flares and lamp- and LASER-based jammer systems. The simulations of IR missiles in flight include missile seeker hardware mounted on a six degree-of-freedom flight simulation table. This paper will focus on recent developments and upgrades to the AFEWES IR capability. In particular, current developments in IR scene generation/projection and efforts to optically combining the IR image produced by a resistive array with existing foreground lamp sources.

  12. Air Force electronic warfare evaluation simulator (AFEWES) infrared test and evaluation capabilities

    NASA Astrophysics Data System (ADS)

    Shepherd, Seth D.

    2001-08-01

    The Air Force Electronic Warfare Evaluation Simulator Infrared Countermeasures (IRCM) lab currently has the ability to simulate a complete IRCM test environment, including IR missiles in flight, aircraft in flight, and various IR countermeasures including maneuvers, LASERs, flares, and lamp-based jammer systems. The simulations of IR missiles in flight include real missile seeker hardware mounted in a six degree-of-freedom flight simulation table. The simulations of aircraft signatures and IR countermeasures are accomplished by using eight xenon arc lamps, located in 9' X 3' cylindrical housings, in the presentation foreground. A mirror system keeps the high intensity IR sources in the missile field of view. Range closure is simulated in the background by zooming in on the scene and in the foreground by separating and controlling the irises of the arc lamp sources for proper spatial and intensity characteristics. All relative motion and range closure is controlled by missile flyout software and aircraft flight-profile software models.

  13. Air Force electronic warfare evaluation simulator (AFEWES) infrared test and evaluation capabilities

    NASA Astrophysics Data System (ADS)

    Jackson, Hank D., II; Grauvogel, Nathanael L.; Blair, Tommy L.; Ensor, Bruce A.

    2006-05-01

    The Air Force Electronic Warfare Evaluation Simulator (AFEWES) infrared countermeasures (IRCM) test facility currently has the ability to simulate a complete IRCM test environment, including IR missiles in flight, aircraft in flight, and various IR countermeasures including maneuvers, point-source flares, and lamp- and LASER-based jammer systems. The simulations of IR missiles in flight include missile seeker hardware mounted on a six degree-of-freedom flight simulation table. This paper will focus on recent developments and upgrades to the AFEWES IR capability. In particular, current developments in IR scene generation/projection and efforts to optically combine the IR image produced by a resistive array with existing foreground lamp sources.

  14. [Investigation on remote measurement of air pollution by a method of infrared passive scanning imaging].

    PubMed

    Jiao, Yang; Xu, Liang; Gao, Min-Guang; Feng, Ming-Chun; Jin, Ling; Tong, Jing-Jing; Li, Sheng

    2012-07-01

    Passive remote sensing by Fourier-transform infrared (FTIR) spectrometry allows detection of air pollution. However, for the localization of a leak and a complete assessment of the situation in the case of the release of a hazardous cloud, information about the position and the distribution of a cloud is essential. Therefore, an imaging passive remote sensing system comprising an interferometer, a data acquisition and processing software, scan system, a video system, and a personal computer has been developed. The remote sensing of SF6 was done. The column densities of all directions in which a target compound has been identified may be retrieved by a nonlinear least squares fitting algorithm and algorithm of radiation transfer, and a false color image is displayed. The results were visualized by a video image, overlaid by false color concentration distribution image. The system has a high selectivity, and allows visualization and quantification of pollutant clouds.

  15. A new method for infrared imaging of air currents in and around critical hazard fume hoods

    SciTech Connect

    Mulac, W.A.; McCreary, J.R. ); Schmalz, H. Thermal Surveys, Inc., Rockford, IL )

    1992-01-01

    A real time method of measuring and recording the efficacy of vapor containment in and around critical hazard fume hoods is being developed. An infrared camera whose response is restricted to a spectral range that overlaps a strong absorption band in a non-toxic gas is used to render real-time video images of the presence and flow of the gas. The gas, nitrous oxide, is ejected in a continuous stream in and around fume hoods that are to be certified capable of containing hazardous fumes. The principle advantage is that various scenarios of air flow displacement in and outside the hood can be easily investigated; the principle limitation is the necessity of high tracer gas concentration to obtain strong visualizations. We hope that this technique can be found to be an effective and safe method to test hoods in locations that were built before present regulations were promulgated.

  16. A new method for infrared imaging of air currents in and around critical hazard fume hoods

    SciTech Connect

    Mulac, W.A.; McCreary, J.R.; Schmalz, H. |

    1992-11-01

    A real time method of measuring and recording the efficacy of vapor containment in and around critical hazard fume hoods is being developed. An infrared camera whose response is restricted to a spectral range that overlaps a strong absorption band in a non-toxic gas is used to render real-time video images of the presence and flow of the gas. The gas, nitrous oxide, is ejected in a continuous stream in and around fume hoods that are to be certified capable of containing hazardous fumes. The principle advantage is that various scenarios of air flow displacement in and outside the hood can be easily investigated; the principle limitation is the necessity of high tracer gas concentration to obtain strong visualizations. We hope that this technique can be found to be an effective and safe method to test hoods in locations that were built before present regulations were promulgated.

  17. A new method for infrared imaging of air currents in and around critical hazard fume hoods

    SciTech Connect

    Mulac, W.A.; McCreary, J.R.; Schmalz, H.

    1994-03-01

    Active, safe real-time method of measuring and recording the efficacy of vapor containment in and around critical hazard fume hoods has been developed. An infrared camera whose response is restricted to a spectral range that overlaps a strong absorption band in a nontoxic gas is used to render real-time video images of the presence and flow of the gas. The gas, nitrous oxide, is ejected in a continuous stream in and around fume hoods that are to be certified capable of containing hazardous fumes. The principal advantage is that various scenarios of air flow displacement in and outside the hood can be easily investigated; the principal limitation is the necessity of high tracer gas concentration to obtain strong visualizations.

  18. Measurements of the CO_2 15 μm Band System Broadened by Air, N_2 and CO_2 at Terrestrial Atmospheric Temperatures

    NASA Astrophysics Data System (ADS)

    Smith, M. A. H.; Devi, V. Malathy; Benner, D. Chris; Blake, T. A.; Sams, R. L.

    2009-06-01

    In earth remote sensing, retrievals of atmospheric temperature profiles are often based on observed radiances in infrared spectral regions where emission from atmospheric CO_2 predominates. To achieve improved retrieval accuracy, systematic errors in the forward model must be reduced, especially those associated with errors in the spectroscopic line calculation. We have recorded more than 110 new high-resolution infrared spectra of the 15-μm band system of CO_2 to accurately determine line intensities, self-, air- and N_2-broadened widths and pressure-induced line shifts, along with their temperature dependences. The spectra were recorded with the Bruker IFS 120 HR Fourier transform spectrometer at Pacific Northwest National Laboratory (PNNL) and temperature-controlled sample cells. Sample temperatures were between 206K and 298K. Maximum total pressures were 15 Torr for self-broadening and 613 Torr for air- and N_2-broadening. Analysis is done using a multispectrum fitting technique to retrieve the spectroscopic parameters. Line mixing and other non-Lorentz, non-Voigt line shapes are also assessed. The resulting line parameters are compared with the HITRAN database and with other measurements. D. Chris Benner, C.P. Rinsland, V. Malathy Devi, M.A.H. Smith, and D. Atkins, J. Quant. Spectrosc. Radiat. Transfer 53, 705-721 (1995) L.S. Rothman et al., J. Quant. Spectrosc. Radiat. Transfer 96, 139-204 (2005) L.S. Rothman et al., J. Quant. Spectrosc. Radiat. Transfer, in press (2009)

  19. Responses of atmospheric electric field and air-earth current to variations of conductivity profiles

    NASA Astrophysics Data System (ADS)

    Makino, M.; Ogawa, T.

    1984-05-01

    A global circuit model is constructed to study responses of air-earth current and electric field to a variation of atmospheric electrical conductivity profile. The model includes the orography and the global distribution of thunderstorm generators. The conductivity varies with latitude and exponentially with altitude. The thunderstorm cloud is assumed to be a current generator with a positive source at the top and a negative one at the bottom. The UT diurnal variations of the global current and the ionospheric potential are evaluated considering the local-time dependence of thunderstorm activity. The global distribution of the electric field and the air-earth current are affected by the orography and latitudinal effects. Assuming a variation of conductivity profile, responses of atmospheric electrical parameters are investigated. The nonuniform decrement of the conductivity with altitude increases both the electric field and the air-earth current. The result suggests a possibility that the increment of the electric field and the air-earth current after a solar flare may be caused by this scheme, due to Forbush decrease.

  20. Atmospheric emissions and air quality impacts from natural gas production and use.

    PubMed

    Allen, David T

    2014-01-01

    The US Energy Information Administration projects that hydraulic fracturing of shale formations will become a dominant source of domestic natural gas supply over the next several decades, transforming the energy landscape in the United States. However, the environmental impacts associated with fracking for shale gas have made it controversial. This review examines emissions and impacts of air pollutants associated with shale gas production and use. Emissions and impacts of greenhouse gases, photochemically active air pollutants, and toxic air pollutants are described. In addition to the direct atmospheric impacts of expanded natural gas production, indirect effects are also described. Widespread availability of shale gas can drive down natural gas prices, which, in turn, can impact the use patterns for natural gas. Natural gas production and use in electricity generation are used as a case study for examining these indirect consequences of expanded natural gas availability.

  1. Upward excursion limits from air saturation at 5 ATA (Atmospheres Absolute)

    NASA Astrophysics Data System (ADS)

    Parker, James W.

    1989-01-01

    Present USN submarine rescue capability makes a prolonged exposure of the submarine crew to hyperbaric air a distinct possibility. The exposure may be to pressures as great as 5 atmospheres absolute (ATA), and for periods of time of up to 72 hours. A series of experimental dives were conducted to establish the safe, upward excursion from 5 ATA (132 FSWG); that is, the maximum, immediate reduction in pressure which these individuals can safely tolerate. This specifies the required pressure in the compartment of a mother submarine to which the rescued personnel would be transferred. In order to minimize the effects of pulmonary oxygen toxicity, the limits first were established using a nitrox equivalent of air at 5 ATA. The upward limit from 4.36 ATA (111 FSWG) was found to be 2.97 ATA (65 FSWG). Once this limit had been set, a series of dives were conducted to test this up limit from standard air at 5 ATA.

  2. Atmospheric lifetimes, infrared spectra and degradation products of a series of hydrofluoroethers

    NASA Astrophysics Data System (ADS)

    Cavalli, F.; Glasius, M.; Hjorth, J.; Rindone, B.; Jensen, N. R.

    The rate constants of the reactions between the OH radical and a series of hydrofluoroethers (HFE) have been measured. The reaction of OH with CHF 2OCF 2OCHF 2 (1), CHF 2OCF 2CF 2OCHF 2 (2), CHF 2OCF 2CF 2OCF 2OCHF 2 (3) and CH 3OC 4F 9 (4) were investigated at 295±3 K and 740±5 Torr total pressure. The following values of the rate constants were determined for the reaction with the OH radical: k1=(2.4±0.7)×10 -15 cm 3 molecule -1 s -1, k2=(4.7±1.6)×10 -15 cm 3 molecule -1 s -1, k3=(4.6±1.6)×10 -15 cm 3 molecule -1 s -1 and k4=(7.2±1.6)×10 -15 cm 3 molecule -1 s -1. (All values are given with 2 σ uncertainties). Infrared spectra were obtained for all four HFEs in the range from 600 to 4000 cm -1 (3 to 17 μm), with the following IBI-values (integrated band intensities): IBI 1= (5.19±0.23)×10 -16 cm molecule -1 for the 978-1584 cm -1 band, IBI 2=(6.04±0.13)×10 -16 cm molecule -1 for the 930-1501 cm -1 band, IBI 3=(8.49±0.34)×10 -16 cm molecule -1 from the 963-1587 cm -1 band and IBI 4=(4.23±0.14)×10 -16 cm molecule -1 for the 845-1428 cm -1 band. Carbonyl fluoride, CF 2O, was the only fluorine-containing degradation product that was found from the Cl atom-initiated reactions of both CHF 2OCF 2OCF 2CF 2OCHF 2 and CH 3OC 4F 9, with measured product yields of 60-97% and 20-40% (based on carbon atoms), respectively. Due to the high uptake parameter of CF 2O to liquid water, its lifetime in the atmosphere is very short (with an upper limit between 15 and 30 d). It is rapidly incorporated into raindrops/aerosols, where it eventually degrades to HF and CO 2. The GWP of CF 2O is therefore negligible compared to those of CFC-11 and CFC-12.

  3. A comparison of minor trace gas retrievals from the Tropospheric Emission Spectrometer (TES) and the Infrared Atmospheric Sounding Interferometer (IASI)

    NASA Astrophysics Data System (ADS)

    Cady-Pereira, K. E.; Shephard, M. W.; Henze, D. K.; Millet, D. B.; Gombos, D.; Van Damme, M.; Clarisse, L.; Coheur, P. F.; Pommier, M.; Clerbaux, C.

    2014-12-01

    The advent of hyperspectral infrared instruments orbiting the Earth has allowed for detecting and measuring numerous trace gas species that play important roles in atmospheric chemistry and impact air quality, but for which there is a dearth of information on their distribution and temporal variability. Here we will present global and regional comparisons of measurements from the NASA TES and the European MetOp IASI instruments of three of these gases: ammonia (NH3), formic acid (HCOOH) and methanol (CH3OH). Ammonia is highly reactive and thus very variable in space and time, while the sources and sinks of methanol and formic acid are poorly quantified: thus space-based measurements have the potential of significantly increasing our knowledge of the emissions and distributions of these gases. IASI and TES have many similarities but some significant differences. TES has significantly higher spectral resolution (0.06 cm-1), and its equator crossing times are ~1:30 am and 1:30 pm, local time, while IASI has lower resolution (0.5 cm-1) and an earlier equator crossing time (9:30 am and 9:30 pm), which leads to lower thermal contrast; however IASI provides much greater temporal and spatial coverage due to its cross-track scanning. Added to the instrumental differences are the differences in retrieval algorithms. The IASI team uses simple but efficient methods to estimate total column amounts of the species above, while the TES team performs full optimal estimation retrievals. We will compare IASI and TES total column measurements averaged on a 2.5x2.5 degree global grid for each month in 2009, and we will examine the seasonal cycle in some regions of interest, such as South America, eastern China, and the Midwest and the Central Valley in the US. In regions where both datasets are in agreement this analysis will provide confidence that the results are robust and reliable. In regions where there is disagreement we will look for the causes of the discrepancies, which will

  4. Hydrogen Isotopic Composition of Arctic and Atmospheric CH4 Determined by a Portable Near-Infrared Cavity Ring-Down Spectrometer with a Cryogenic Pre-Concentrator.

    PubMed

    Chen, Y; Lehmann, Kevin K; Peng, Y; Pratt, L M; White, J R; Cadieux, S B; Sherwood Lollar, B; Lacrampe-Couloume, G; Onstott, T C

    2016-10-01

    In this study, near-infrared continuous wave cavity ring-down spectroscopy was applied to the measurement of the δ(2)H of methane (CH4). The cavity ring-down spectrometer (CRDS) system consisted of multiple DFB laser diodes to optimize selection of spectral line pairs. By rapidly switching measurements between spectral line peaks and the baseline regions, the long-term instrumental drift was minimized, substantially increasing measurement precision. The CRDS system coupled with a cryogenic pre-concentrator measured the δ(2)H of terrestrial atmospheric CH4 from 3 standard liters of air with a precision of ±1.7‰. The rapidity with which both C and H isotopic measurements of CH4 can be made with the CRDS will enable hourly monitoring of diurnal variations in terrestrial atmospheric CH4 signatures that can be used to increase the resolution of global climate models for the CH4 cycle. Although the current instrument is not capable of measuring the δ(2)H of 10 ppbv of martian CH4, current technology does exist that could make this feasible for future spaceflight missions. As biological and abiotic CH4 sources have overlapping carbon isotope signatures, dual-element (C and H) analysis is key to reliable differentiation of these sources. Such an instrument package would therefore offer improved ability to determine whether or not the CH4 recently detected in the martian atmosphere is biogenic in origin. Key Words: Arctic-Hydrogen isotopes-Atmospheric CH4-CRDS-Laser. Astrobiology 16, 787-797.

  5. Conditions for the use of infrared camera diagnostics in energy auditing of the objects exposed to open air space at isothermal sky

    NASA Astrophysics Data System (ADS)

    Kruczek, Tadeusz

    2015-03-01

    Convective and radiation heat transfer take place between various objects placed in open air space and their surroundings. These phenomena bring about heat losses from pipelines, building walls, roofs and other objects. One of the main tasks in energy auditing is the reduction of excessive heat losses. In the case of a low sky temperature, the radiation heat exchange is very intensive and the temperature of the top part of the horizontal pipelines or walls is lower than the temperature of their bottom parts. Quite often this temperature is also lower than the temperature of the surrounding atmospheric air. In the case of overhead heat pipelines placed in open air space, it is the ground and sky that constitute the surroundings. The aforementioned elements of surroundings usually have different values of temperature. Thus, these circumstances bring about difficulties during infrared inspections because only one ambient temperature which represents radiation of all surrounding elements must be known during the thermovision measurements. This work is aimed at the development of a method for determination of an equivalent ambient temperature representing the thermal radiation of the surrounding elements of the object under consideration placed in open air space, which could be applied at a fairly uniform temperature of the sky during the thermovision measurements as well as for the calculation of radiative heat losses.

  6. The persistence of pesticides in atmospheric particulate phase: An emerging air quality issue

    NASA Astrophysics Data System (ADS)

    Socorro, Joanna; Durand, Amandine; Temime-Roussel, Brice; Gligorovski, Sasho; Wortham, Henri; Quivet, Etienne

    2016-09-01

    The persistent organic pollutants (POPs) due to their physicochemical properties can be widely spread all over the globe; as such they represent a serious threat to both humans and wildlife. According to Stockholm convention out of 24 officially recognized POPs, 16 are pesticides. The atmospheric life times of pesticides, up to now were estimated based on their gas-phase reactivity. It has been only speculated that sorption to aerosol particles may increase significantly the half-lives of pesticides in the atmosphere. The results presented here challenge the current view of the half-lives of pesticides in the lower boundary layer of the atmosphere and their impact on air quality and human health. We demonstrate that semivolatile pesticides which are mostly adsorbed on atmospheric aerosol particles are very persistent with respect to the highly reactive hydroxyl radicals (OH) that is the self-cleaning agent of the atmosphere. The half-lives in particulate phase of difenoconazole, tetraconazole, fipronil, oxadiazon, deltamethrin, cyprodinil, permethrin, and pendimethalin are in order of several days and even higher than one month, implying that these pesticides can be transported over long distances, reaching the remote regions all over the world; hence these pesticides shall be further evaluated prior to be confirmed as POPs.

  7. Wind tunnel experiments: cold-air pooling and atmospheric decoupling above a melting snow patch

    NASA Astrophysics Data System (ADS)

    Mott, Rebecca; Paterna, Enrico; Horender, Stefan; Crivelli, Philip; Lehning, Michael

    2016-02-01

    The longevity of perennial snowfields is not fully understood, but it is known that strong atmospheric stability and thus boundary-layer decoupling limit the amount of (sensible and latent) heat that can be transmitted from the atmosphere to the snow surface. The strong stability is typically caused by two factors, (i) the temperature difference between the (melting) snow surface and the near-surface atmosphere and (ii) cold-air pooling in topographic depressions. These factors are almost always a prerequisite for perennial snowfields to exist. For the first time, this contribution investigates the relative importance of the two factors in a controlled wind tunnel environment. Vertical profiles of sensible heat and momentum fluxes are measured using two-component hot-wire and one-component cold-wire anemometry directly over the melting snow patch. The comparison between a flat snow surface and one that has a depression shows that atmospheric decoupling is strongly increased in the case of topographic sheltering but only for low to moderate wind speeds. For those conditions, the near-surface suppression of turbulent mixing was observed to be strongest, and the ambient flow was decoupled from the surface, enhancing near-surface atmospheric stability over the single snow patch.

  8. The persistence of pesticides in atmospheric particulate phase: An emerging air quality issue

    PubMed Central

    Socorro, Joanna; Durand, Amandine; Temime-Roussel, Brice; Gligorovski, Sasho; Wortham, Henri; Quivet, Etienne

    2016-01-01

    The persistent organic pollutants (POPs) due to their physicochemical properties can be widely spread all over the globe; as such they represent a serious threat to both humans and wildlife. According to Stockholm convention out of 24 officially recognized POPs, 16 are pesticides. The atmospheric life times of pesticides, up to now were estimated based on their gas-phase reactivity. It has been only speculated that sorption to aerosol particles may increase significantly the half‐lives of pesticides in the atmosphere. The results presented here challenge the current view of the half-lives of pesticides in the lower boundary layer of the atmosphere and their impact on air quality and human health. We demonstrate that semivolatile pesticides which are mostly adsorbed on atmospheric aerosol particles are very persistent with respect to the highly reactive hydroxyl radicals (OH) that is the self-cleaning agent of the atmosphere. The half-lives in particulate phase of difenoconazole, tetraconazole, fipronil, oxadiazon, deltamethrin, cyprodinil, permethrin, and pendimethalin are in order of several days and even higher than one month, implying that these pesticides can be transported over long distances, reaching the remote regions all over the world; hence these pesticides shall be further evaluated prior to be confirmed as POPs. PMID:27628441

  9. Exhaled air analysis using wideband wave number tuning range infrared laser photoacoustic spectroscopy

    NASA Astrophysics Data System (ADS)

    Kistenev, Yury V.; Borisov, Alexey V.; Kuzmin, Dmitry A.; Penkova, Olga V.; Kostyukova, Nadezhda Y.; Karapuzikov, Alexey A.

    2017-01-01

    The infrared laser photoacoustic spectroscopy (LPAS) and the pattern-recognition-based approach for noninvasive express diagnostics of pulmonary diseases on the basis of absorption spectra analysis of the patient's exhaled air are presented. The study involved lung cancer patients (N=9), patients with chronic obstructive pulmonary disease (N=12), and a control group of healthy, nonsmoking volunteers (N=11). The analysis of the measured absorption spectra was based at first on reduction of the dimension of the feature space using principal component analysis; thereafter, the dichotomous classification was carried out using the support vector machine. The gas chromatography-mass spectrometry method (GC-MS) was used as the reference. The estimated mean value of the sensitivity of exhaled air sample analysis by the LPAS in dichotomous classification was not less than 90% and specificity was not less than 69%; the analogous results of analysis by GC-MS were 68% and 60%, respectively. Also, the approach to differential diagnostics based on the set of SVM classifiers usage is presented.

  10. Nitrogen Isotopic Ratio in Jupiter's Atmosphere from Observations by Composite Infrared Spectrometer (CIRS) on the Cassini Spacecraft

    NASA Technical Reports Server (NTRS)

    Abbas, M. M.; LeClair, A.; Owen, T.; Conrath, B. J.; Flasar, F. M.; Kunde, V. G.; Nixon, C. A..; Achterberg, R. K.; Bjoraker, G.; Jennings, D. J.

    2003-01-01

    The Composite Infrared Spectrometer (CIRS) on the Cassini spacecraft made infrared observations of Jupiter's atmosphere during the flyby in December 2000 to January 2001. The unique database in the 600-1400/cm region with 0.53 and 2.8/cm spectral resolutions obtained from the observations permits retrieval of global maps of the thermal structure and composition of Jupiter's atmosphere including the distributions of (14)NH3 and (15)NH3. Analysis of Jupiter's ammonia distributions from three isolated (15)NH3 spectral lines in eight latitudes is presented for evaluation of the nitrogen isotopic ratio. The nitrogen isotopic ratio (14)N/(15)N (or (15)N/(14)N) in Jupiter's atmosphere in this analysis is calculated to be: 448 +/- 62 ((2.23 +/- 0.31) x 10(exp -3)). This value of the ratio determined from CIRS data is found to be in very close agreement with the value previously obtained from the measurements by the Galileo Probe Mass Spectrometer. Some possible mechanisms to account for the variation of Jupiter's observed isotopic ratio relative to various astrophysical environments are discussed.

  11. Atmospheric carbon dioxide at Mauna Loa Observatory 1. NOAA global monitoring for climatic change measurements with a nondispersive infrared analyzer, 1974--1985

    SciTech Connect

    Komhyr, W. D.; Harris, T. B.; Waterman, L. S.; Chin, J. F. S.; Thoning, K. W.

    1989-06-20

    Atmospheric CO/sub 2/ measurements made with a nondispersive infrared analyzer during 1974--1985 at Mauna Lao Observatory, Hawaii, are described, with emphasis on the measurement methodology, calibrations, and data accuracy. Monthly mean CO/sub 2/ data, representative of global background conditions, are presented for the period of record. The monthly means were derived from an all-data base of CO/sub 2/ hourly averged archived at the National Oceanic and Atmospheric Administration (NOAA) Geophysical Monitoring for Climatic Change (GMCC) facility in Boulder, Colorado; at the Carbon Dioxide Information Analysis Center (CDIAC) in Oak Ridge, Tennessee; and in the microfiche version of this paper. Flags in the all-data base identify CO/sub 2/ hourly averages that have been deemed unreliable because of sampling and analysis problems or that are unrepresentative of clean background air because of influences of the local environment, for example, CO/sub 2/ uptake by nearby vegetation or contamination and pollution effects. The select NOAA GMCC monthly mean data are compared with similar data obtained independently at Mauna Loa Observatory by the Scripps Institution of Oceanography. The averge difference of corresponding monthly mean CO/sub 2/ values for the two data sets is 0.15/plus minus/0.18 ppm, where the indicated variability is the standard deviation. Careful scrutiny of the NOAA GMCC measurement, calibration, and data processing procedures that might have caused the small bias in the data has revealed no unusual errors. /copyright/ American Geophysical Union 1989

  12. Use of near-infrared reflectance spectroscopy for shelf-life discrimination of green asparagus stored in a cool room under controlled atmosphere.

    PubMed

    Sánchez, María-Teresa; Pérez-Marín, Dolores; Flores-Rojas, Katherine; Guerrero, José-Emilio; Garrido-Varo, Ana

    2009-04-30

    This study sought to evaluate the ability of near-infrared reflectance spectroscopy (NIRS) to classify intact green asparagus, in refrigerated storage under controlled atmosphere, by storage time and post-harvest treatments applied. A total of 468 green asparagus (Asparagus officinalis, L., cultivar UC-157) were sampled after 7, 14, 21 and 28 days of refrigerated storage (2 degrees C, 95% R.H.) under three controlled atmosphere (CA) treatments: air (21 kPa O(2)+0.3 kPa CO(2)), CA(1) (5 kPa O(2)+5 kPa CO(2)) and CA(2) (10 kPa O(2)+10kPa CO(2)). Two commercially available spectrophotometers were evaluated for this purpose: a scanning monochromator (SM) of 400-2500 nm and a combination of diode array and scanning monochromator (DASM) of 350-2500 nm. Models developed using partial least squares 2-discriminant analysis (PLS2-DA) correctly classified between 81-100% of samples by post-harvest storage time, depending on the instrument used. Using similar models, the DASM instrument correctly classified 85% of samples by post-harvest treatment, compared with 72% using the SM. These results confirmed that NIR spectroscopy, coupled with the use of chemometric techniques, provides a reliable, accurate method of predicting the shelf-life of asparagus under different storage conditions and as a function of post-harvest treatment applied; the method can be readily applied at industrial level.

  13. Air-Sea Exchange and Atmospheric Cycling of Mercury in South China Sea

    NASA Astrophysics Data System (ADS)

    Tseng, C. M.; Liu, C. S.; Lamborg, C. H.

    2014-12-01

    Limited knowledge exists concerning the role of the low-latitude marginal seas in mercury (Hg) emissions on a global scale, especially tropical-subtropical and monsoon-dominated marginal seas in East Asia. To assess this potential mobilization of Hg through air-sea gas exchange, we have determined the dissolved elemental Hg (DEM) and gaseous elemental Hg (GEM) concentrations in surface seawater and atmosphere, respectively, during seasonal oceanographic cruises to the SouthEast Asian Time-series Study (SEATS) station (18 oN, 116 oE) from 2003 to 2007. The sampling and analysis of GEM and DEM were performed on board ship by using an on-line mercury analyzer (GEMA). Over the SCS, the GEM concentrations are elevated 2-3 times above global background values, with higher enhancements in the winter when the northeast monsoon draws air from China. The impact of long-range transport, as controlled by seasonal monsoons, has on the Hg atmospheric distribution and cycling in the SCS. The DEM concentration varied seasonally, with a high in summer and a low in winter and showed a positive correlation with sea surface temperature (SST). The elevated DEM concentration in summer appears mainly abiologically driven. In winter, the SCS acts as a sink of atmosphere Hg0 as a result of low SST and high wind of the year, enhanced vertical mixing and elevated atmospheric gaseous elemental mercury. Annually, the SCS serves as a source of Hg0 to the atmosphere of 300±50 pmol m-2 d-1 (390±60 kmol Hg y-1, ~2.6% of global emission in ~1% of global ocean area), suggesting high regional Hg pollution impacts from the surrounding Mainland (mostly China).

  14. Py4CAtS - Python tools for line-by-line modelling of infrared atmospheric radiative transfer

    NASA Astrophysics Data System (ADS)

    Schreier, Franz; García, Sebastián Gimeno

    2013-05-01

    Py4CAtS — Python scripts for Computational ATmospheric Spectroscopy is a Python re-implementation of the Fortran infrared radiative transfer code GARLIC, where compute-intensive code sections utilize the Numeric/Scientific Python modules for highly optimized array-processing. The individual steps of an infrared or microwave radiative transfer computation are implemented in separate scripts to extract lines of relevant molecules in the spectral range of interest, to compute line-by-line cross sections for given pressure(s) and temperature(s), to combine cross sections to absorption coefficients and optical depths, and to integrate along the line-of-sight to transmission and radiance/intensity. The basic design of the package, numerical and computational aspects relevant for optimization, and a sketch of the typical workflow are presented.

  15. Ground-based atmospheric infrared and visible emission measurements. Report for 15 July 1983-14 June 1985

    SciTech Connect

    Baker, D.J.; Steed, A.J.; Ware, G.A.; Offermann, D.; Lange, G.

    1985-01-01

    This reprint describes Ground-based measurements of night-sky near-infrared and visible emissions made at the Andenes, Norway, and Kiruna, Sweden, rocket launch sites during the Energy Budget Campaign of 1980. Optical measurements were made using visible and infrared photometers, a Michelson interferometer and a grating spectrometer. The specific aim of the experiments reported in the present paper was to investigate the relationships between the optical emissions from upper atmospheric hydroxyl (OH) and molecular oxygen (O2)and the magnetic activity in the auroral zone. Other airglow emissions, including the O and N2(+) species, wee monitored photometrically for diagnostic purposes. Furthermore, the ground-based optical instruments were used to support rocket-borne experiments launched in salvoes during the campaign. Observations were provided before and after the launches of the rocket payloads. Comparisons between upper atomospheric temperatures derived from airglow emissions and those obtained from in situ rocket probes were sought.

  16. Infrared emissions of H3(+) in the atmosphere of Jupiter in the 2. 1 and 4. 0 micron region

    SciTech Connect

    Miller, S.; Tennyson, J.; Joseph, R.D. Hawaii Univ., Honolulu )

    1990-09-01

    Infrared spectra of the Jovian atmosphere around 2.1 and 4.0 microns, measured using the NASA Infrared Telescope Facility at Mauna Kea, Hawaii, are presented. The observations were made between February 6 and 8, 1990. In both spectral regions, features attributable to H3(+) were visible. The intensity ratio of lines in the 2 and 4 microns regions measured from the northern auroral hot spot during the same night leads to a rovibrational temperature of 1100 + or - 100 K for this molecular ion, close to a previous measurement of the rotational temperature of 1099 + or - 100 K. This indicates that the upper energy levels are being populated by purely thermal processes, rather than by resonant energy exchange. The para-H3(+) fractional abundance of 0.58 determined by previous workers is found to be consistent with this study. The time dependency of the H3(+) emission phenomena is confirmed. 9 refs.

  17. The effects of atmospheric pressure on infrared reflectance spectra of Martian analogs

    NASA Technical Reports Server (NTRS)

    Bishop, Janice L.; Pieters, Carle M.; Pratt, Stephen F.; Patterson, William

    1993-01-01

    The use of terrestrial samples as analogs of Mars soils are complicated by the Martian atmosphere. Spectral features due to the Martian atmosphere can be removed from telescopic spectra of Mars and ISM spectra of Mars, but this does not account for any spectral differences resulting from atmospheric pressure or any interactions between the atmosphere and the surface. We are examining the effects of atmospheric pressure on reflectance spectra of powdered samples in the laboratory. Contrary to a previous experiment with granite, no significant changes in albedo or the Christiansen feature were observed from 1 bar pressure down to a pressure of 8 micrometers Hg. However, reducing the atmospheric pressure does have a pronounced affect on the hydration features, even for samples retained in a dry environment for years.

  18. Study of martian atmospheres by mid-infrared and submillimeter high-spectral resolution measurements: A search for SO2 in the martin atmosphere, and a development of the tuneable heterodyne infrared spectrometer

    NASA Astrophysics Data System (ADS)

    Nakagawa, H.; Kasaba, Y.; Hashimoto, A.; Murata, I.; Okano, S.; Maezawa, H.

    2009-04-01

    With increased knowledge on our "neighbor" planets, based on recent aggressive explorations, our image on them is changing significantly. It is almost certain that Mars once had a duration warm and wet climate and that it still conserves a large amount of water (ice) under the surface. Mars is now called a "frozen water planet". Evolution of Mars is important for understanding the process to form the planetary environment for life. Japan launched NOZOMI in 1998 by the insertion to Mars orbit turned out to be unsuccessful. Recently, groups of enthusiastic people got together, to challenge the Mars exploration again. Mid-infrared and submillimeter range has a plenty of both main components and minor constituents of the planetary atmosphere (CO2,H2O,CH4,SO2,NH3,CO,H2O2), which is very important for understanding the atmospheric dynamics and variations. The common necessity is " a high spectral-resolution" (e.g., resolution power : 107 = a few m/s in the velocity field). Following recent report on ground-based observations by Krasnopolsky [2005] suggesting that currently there is no active volcanism on Mars and restricts the delivery of sulfur and other gasses into the atmosphere, we tried to verify them on the different season (Ls = 8.1) based on the ASTE submillimeter observations with a higher-spectral resolution than that in previous studies. The ASTE is located at an elevation of 4800m on the Atacama desert in the northern Chile, and consists of a 10--m diameter telescope. Our observations on 25 and 26 December from 0:00 to 5:00 UT employed the 345 Superconductor-Insulator Superconductor (SIS) Sideband Separating receivers, operating 330 - 360 GHz to observe the SO2 at a frequency of 346.5285 GHz, SO at a frequency of 346.5239 GHz, 12CO J = 3-2 at 345.7960 GHz, and 13CO J = 3-2 at 330.5880 GHz rotation transitions. A sensitive spectrum puts an upper limit on SO2 of 1 ppb. The evidence for seepage could not be found even in the season which more CH4 was detected

  19. Optical parametric oscillators in lidar sounding of trace atmospheric gases in the mid infrared region

    NASA Astrophysics Data System (ADS)

    Romanovskii, O. A.; Sadovnikov, S. A.; Kharchenko, O. V.; Shumskii, V. K.; Yakovlev, S. V.

    2015-12-01

    Applicability of a KTA crystal-based laser system with optical parametric generation to lidar sounding of the atmosphere in the spectral range 3-4 μm is studied in this work. A technique developed for lidar sounding of trace atmospheric gases is based on differential absorption (DIAL) technique and differential optical absorption spectroscopy (DOAS). The DIAL-DOAS technique is tested to estimate its efficiency for lidar sounding of atmospheric trace gases.

  20. Nanosecond Enhancements of the Atmospheric Electron Density by Extensive Air Showers

    NASA Astrophysics Data System (ADS)

    Rutjes, C.; Camporeale, E.; Ebert, U.; Buitink, S.; Scholten, O.; Trinh, G. T. N.; Witteveen, J.

    2015-12-01

    As is well known a sufficient density of free electrons and strong electric fields are the basic requirements to start any electrical discharge. In the context of thunderstorm discharges it has become clear that in addition droplets and or ice particles are required to enhance the electric field to values above breakdown. In our recent study [1] we have shown that these three ingredients have to interplay to allow for lightning inception, triggered by an extensive air shower event. The extensive air showers are a very stochastic natural phenomenon, creating highly coherent sub-nanosecond enhancements of the atmospheric electron density. Predicting these electron density enhancements accurately one has to take the uncertainty of the input variables into account. For this study we use the initial energy, inclination and altitude of first interaction, which will influence the evolution of the shower significantly. To this end, we use the stochastic collocation method, [2] to post-process our detailed Monte Carlo extensive air shower simulations, done with the CORSIKA [3] software package, which provides an efficient and elegant way to determine the distribution of the atmospheric electron density enhancements. [1] Dubinova, A., Rutjes, C., Ebert, E., Buitink, S., Scholten, O., and Trinh, G. T. N. "Prediction of Lightning Inception by Large Ice Particles and Extensive Air Showers." PRL 115 015002 (2015)[2] G.J.A. Loeven, J.A.S. Witteveen, H. Bijl, Probabilistic collocation: an efficient nonintrusive approach for arbitrarily distributed parametric uncertainties, 45th AIAA Aerospace Sciences Meeting, Reno, Nevada, 2007, AIAA-2007-317[3] Heck, Dieter, et al. CORSIKA: A Monte Carlo code to simulate extensive air showers. No. FZKA-6019. 1998.

  1. On the origin and destination of atmospheric moisture and air mass over the Tibetan Plateau

    NASA Astrophysics Data System (ADS)

    Chen, Bin; Xu, Xiang-De; Yang, Shuai; Zhang, Wei

    2012-12-01

    The Tibet Plateau (TP) is a key region that imposes profound impacts on the atmospheric water cycle and energy budget of Asia, even the global climate. In this work, we develop a climatology of origin (destination) of air mass and moisture transported to (from) the TP using a Lagrangian moisture diagnosis combined with the forward and backward atmospheric tracking schemes. The climatology is derived from 6-h particle positions based on 5-year (2005-2009) seasonal summer trajectory dataset from the Lagrangian particle dispersion model FLEXPART using NCEP/GFS data as input, where the regional model atmosphere was globally filled with particles. The results show that (1) the dominant origin of the moisture supplied to the TP is a narrow tropical-subtropical band in the extended Arabian Sea covering a long distance from the Indian subcontinent to the Southern Hemisphere. Two additional moisture sources are located in the northwestern part of TP and the Bay of Bengal and play a secondary role. This result indicates that the moisture transporting to the TP more depends on the Indian summer monsoon controlled by large-scale circulation. (2) The moisture departing from the TP can be transported rapidly to East Asia, including East China, Korea, Japan, and even East Pacific. The qualitative similarity between the regions of diagnosed moisture loss and the pattern of the observed precipitation highlights the robustness of the role of the TP on precipitation over East Asia. (3) In contrast to the moisture origin confined in the low level, the origin and fate of whole column air mass over the TP is largely controlled by a strong high-level Asian anticyclone. The results show that the TP is a crossroad of air mass where air enters mainly from the northwest and northeast and continues in two separate streams: one goes southwestwards over the Indian Ocean and the other southeastwards through western North Pacific. Both of them partly enter the trade wind zone, which manifests the

  2. The atmospheric footprint of preindustrial, anthropogenic, and contemporary air-sea fluxes of CO2 estimated from an ocean inversion

    NASA Astrophysics Data System (ADS)

    Mikaloff Fletcher, S. E.; Gruber, N. P.; Sarmiento, J. L.; Jacobson, A. R.

    2006-12-01

    Air-sea exchange is a primary determinant of the spatial pattern of atmospheric carbon dioxide, yet there are substantial gaps in our understanding of the impact of the oceans on these gradients. Recent inverse modeling studies have used ocean interior observations of dissolved inorganic carbon (DIC) and other tracers and Ocean General Circulation Models (OGCMs) to estimate separately the natural air-sea flux that already existed in preindustrial times and the component of the air-sea flux that is due to the anthropogenic perturbation of atmospheric CO2. The sum of these components is the contemporary air-sea flux. Furthermore, the results from the ocean inversion have been combined with an analogous atmospheric inversion using surface observations of atmospheric carbon dioxide concentrations and atmospheric transport models to estimate air- sea and air-land fluxes. This work suggested that there might be an unexpectedly large source of carbon dioxide to the atmosphere from tropical land regions. We use the air-sea fluxes estimated from this ocean inversion together with estimates of the seasonal cycle of these fluxes from ΔpCO2 observations and bulk parameterizations as boundary conditions for the Model for Ozone And Related chemical Tracers (MOZART). The effects of preindustrial, anthropogenic, and contemporary air-sea fluxes on the spatial pattern of atmospheric CO2 are analyzed and the implications for ocean interior transport are discussed. In addition, we use atmospheric observations of 13C/12C isotopic ratios in carbon dioxide to independently test the finding of a large terrestrial source in the tropics, since the terrestrial biosphere discriminates against 13C much more strongly than the oceans.

  3. Vertical profile of tritium concentration in air during a chronic atmospheric HT release.

    PubMed

    Noguchi, Hiroshi; Yokoyama, Sumi

    2003-03-01

    The vertical profiles of tritium gas and tritiated water concentrations in air, which would have an influence on the assessment of tritium doses as well as on the environmental monitoring of tritium, were measured in a chronic tritium gas release experiment performed in Canada in 1994. While both of the profiles were rather uniform during the day because of atmospheric mixing, large gradients of the profiles were observed at night. The gradient coefficients of the profiles were derived from the measurements. Correlations were analyzed between the gradient coefficients and meteorological conditions: solar radiation, wind speed, and turbulent diffusivity. It was found that the solar radiation was highly correlated with the gradient coefficients of tritium gas and tritiated water profiles and that the wind speed and turbulent diffusivity showed weaker correlations with those of tritiated water profiles. A one-dimensional tritium transport model was developed to analyze the vertical diffusion of tritiated water re-emitted from the ground into the atmosphere. The model consists of processes of tritium gas deposition to soil including oxidation into tritiated water, reemission of tritiated water, dilution of tritiated water in soil by rain, and vertical diffusion of tritiated water in the atmosphere. The model accurately represents the accumulation of tritiated water in soil water and the time variations and vertical profiles of tritiated water concentrations in air.

  4. Mixture model-based atmospheric air mass classification: a probabilistic view of thermodynamic profiles

    NASA Astrophysics Data System (ADS)

    Pernin, Jérôme; Vrac, Mathieu; Crevoisier, Cyril; Chédin, Alain

    2016-10-01

    Air mass classification has become an important area in synoptic climatology, simplifying the complexity of the atmosphere by dividing the atmosphere into discrete similar thermodynamic patterns. However, the constant growth of atmospheric databases in both size and complexity implies the need to develop new adaptive classifications. Here, we propose a robust unsupervised and supervised classification methodology of a large thermodynamic dataset, on a global scale and over several years, into discrete air mass groups homogeneous in both temperature and humidity that also provides underlying probability laws. Temperature and humidity at different pressure levels are aggregated into a set of cumulative distribution function (CDF) values instead of classical ones. The method is based on a Gaussian mixture model and uses the expectation-maximization (EM) algorithm to estimate the parameters of the mixture. Spatially gridded thermodynamic profiles come from ECMWF reanalyses spanning the period 2000-2009. Different aspects are investigated, such as the sensitivity of the classification process to both temporal and spatial samplings of the training dataset. Comparisons of the classifications made either by the EM algorithm or by the widely used k-means algorithm show that the former can be viewed as a generalization of the latter. Moreover, the EM algorithm delivers, for each observation, the probabilities of belonging to each class, as well as the associated uncertainty. Finally, a decision tree is proposed as a tool for interpreting the different classes, highlighting the relative importance of temperature and humidity in the classification process.

  5. The relationship between ozone formation and air temperature in the atmospheric surface layer

    NASA Astrophysics Data System (ADS)

    Belan, Boris D.; Savkin, Denis; Tolmachev, Gennadii

    2016-04-01

    Studying the formation and dynamics of ozone in the atmosphere is important due to several reasons. First, the contribution of tropospheric ozone to the global greenhouse effect is only slightly less than that of water vapor, carbon dioxide, and methane. Second, tropospheric ozone acts as a strong poison that has negative effects on human health, animals, and vegetation. Third, being a potent oxidizer, ozone destroys almost all materials, including platinum group metals and compounds. Fourthly, ozone is formed in situ from precursors as a result of photochemical processes, but not emitted into the atmosphere by any industrial enterprises directly. In this work, we present some results of the study aimed at the revealing relationship between ozone formation rate and surface air temperature in the background atmosphere. It has been found that this relationship is nonlinear. Analysis of the possible reasons showed that the nonlinear character of this relationship may be due to a nonlinear increase in the reaction constants versus air temperature and a quadratic increase in the concentration of hydrocarbons with increasing temperature. This work was supported by the Ministry of Education and Science contract no.14.613.21.0013 (ID: RFMEFI61314X0013).

  6. Airglow in the Visible and Infrared Spectral Ranges of the Disturbed Upper Atmosphere under Conditions of High-Velocity Plasma Jet Injection: I. Experimental data

    NASA Astrophysics Data System (ADS)

    Zetzer, J. I.; Kozlov, S. I.; Rybakov, V. A.; Ponomarenko, A. V.; Smirnova, N. V.; Romanovsky, Yu. A.; Meng, C.-I.; Erlandson, R.; Stoyanov, B.

    2002-05-01

    The measurements of infrared emission from an artificial structure, which was generated during the Fluxus experiment with plasma jet injection into the atmosphere, are obtained and discussed for the first time. Additional experimental data on the airglow in the visible spectral band of the disturbed region of the atmosphere are presented. A generalized analysis of the data is given.

  7. Materials performance in the atmospheric fluidized-bed cogeneration air heater experiment

    SciTech Connect

    Natesan, K.; Podolski, W.; Wang, D.Y.; Teats, F.G. ); Gerritsen, W.; Stewart, A.; Robinson, K. )

    1991-02-01

    The Atmospheric Fluidized-Bed Cogeneration Air Heater Experiment (ACAHE) sponsored by the US Department of Energy (DOE) was initiated to assess the performance of various heat-exchanger materials to be used in fluidized-bed combustion air heater systems. Westinghouse Electric Corporation, through subcontracts with Babcock Wilcox, Foster Wheeler, and ABB Combustion Engineering Systems, prepared specifications and hardware for the ACAHE tests. Argonne National Laboratory contracted with Rockwell International to conduct tests in the DOE atmospheric fluidized-bed combustion facility. This report presents an overview of the project, a description of the facility and the test hardware, the test operating conditions, a summary of the operation, and the results of analyzing specimens from several uncooled and cooled probes exposed in the facility. Extensive microstructural analyses of the base alloys, claddings, coatings, and weldments were performed on specimens exposed in several probes for different lengths of time. Alloy penetration data were determined for several of the materials as a function of specimen orientation and the exposure location in the combustor. Finally, the data were compared with earlier laboratory test data, and the long-term performance of candidate materials for air-heater applications was assessed.

  8. A VHF driven coaxial atmospheric air plasma: electrical and optical characterization

    NASA Astrophysics Data System (ADS)

    Byrns, Brandon; Wooten, Daniel; Lindsay, Alexander; Shannon, Steven

    2012-05-01

    A coaxially driven VHF plasma source for atmospheric air plasmas has been built and characterized. Electrical and optical characterization of this source present a unique operating regime when compared to state of the art atmospheric systems such as dielectric barrier discharge, pulsed dc, microwave, or ac blown arc discharges. The discharge does not appear to produce streamers or arcs, but instead remains as a steady-state glow located at the end of the inner coaxial power feed. Plasma impedance was determined by comparing the loaded and unloaded impedance of the coaxial source RF input; this termination impedance was combined with a simple high-frequency global model to estimate an electron density of approximately 1011 cm-3 at 400 W delivered power in air. Optical emission characterization of the source shows a monotonic increase in emission with respect with power; the relative intensity of the peaks from excited species, however, remains constant over a power range from 300 to 600 W. This unique source geometry presents a possible pathway for high gas throughput, large area, high power density processes such as surface modification, air purification, media removal and chemical surface treatment.

  9. Characteristics of atmospheric visibility and its relationship with air pollution in Korea.

    PubMed

    Lee, Jeong-Young; Jo, Wan-Kuen; Chun, Ho-Hwan

    2014-09-01

    Although analysis of long-term data is necessary to obtain reliable information on characteristics of atmospheric visibility and its relationship with air pollution, it has rarely been performed. Therefore, a long-term evaluation of atmospheric visibility in characteristically different Korean cities, as well as a remote island, during 2001 to 2009, was performed in this study. In general, visibility decreased in the studied areas during the 9-yr study period. In addition, all areas displayed a distinct seasonal trend, with high visibility in the cold season relative to the warm season. Weekday visibility, however, did not significantly differ from weekend visibility. Similarly, the number of days per year for both low (<10 km) and high visibility (>19 km) fluctuated during the study period. Busan (a coastal city) exhibited the highest visibility, with an overall average of 17.6 km, followed by Daegu (a basin city), Ulsan (with concentrated petrochemical industries), Ullungdo (a remote island), and Seoul (the capital of Korea). Visibility was found to be significantly correlated with target air pollutants, except for ozone, for all metropolitan cities, whereas it was significantly correlated only with particulate matter with an aerodynamic diameter <10 μm (PM10) and ozone on the remote island (Ullungdo). Among the metropolitan cities, Seoul exhibited the lowest visibility for both the PM10 standard exceedance and non-exceedance days, followed by Ulsan, Daegu, and Busan. The results of this study can be used to establish effective strategies for improving urban visibility and air quality.

  10. Potential for atmospheric-driven lead paint degradation in the South Coast Air Basin of California.

    PubMed

    Cohan, Alexander J; Edwards, Rufus D; Kleinman, Michael T; Dabdub, Donald

    2009-12-01

    Exposure to lead in paint or lead residues in house dust and soil is one of the leading environmental risks to the health of children in the United States. Components of photochemical smog can increase the degradation of binders in lead paint, leading to increased release of lead pigment granules to hands in surface contact or for deposition in house dust and soil. This study uses photochemical air quality modeling to map areas susceptible to increased lead paint degradation as a result of photochemical atmospheric pollutants to prioritize areas of concern. Typical air quality episodes in the South Coast Air Basin of California (SoCAB) are modeled for the 1970s, 1980s, and 1990s. Results indicate that large areas of the SoCAB were susceptible to atmospheric-driven accelerated lead paint degradation. Inner city urban areas from central Los Angeles to Azusa and most of Orange County had the highest susceptibility to accelerated lead paint degradation, followed by inland locations near the San Bernardino Mountains. This study identifies photochemical oxidant gases as contributors to greater lead release from indoor painted surfaces in urban areas.

  11. Materials performance in the atmospheric fluidized-bed cogeneration air heater experiment

    SciTech Connect

    Natesan, K.; Podolski, W.; Wang, D.Y.; Teats, F.G.; Gerritsen, W.; Stewart, A.; Robinson, K.

    1991-02-01

    The Atmospheric Fluidized-Bed Cogeneration Air Heater Experiment (ACAHE) sponsored by the US Department of Energy (DOE) was initiated to assess the performance of various heat-exchanger materials to be used in fluidized-bed combustion air heater systems. Westinghouse Electric Corporation, through subcontracts with Babcock & Wilcox, Foster Wheeler, and ABB Combustion Engineering Systems, prepared specifications and hardware for the ACAHE tests. Argonne National Laboratory contracted with Rockwell International to conduct tests in the DOE atmospheric fluidized-bed combustion facility. This report presents an overview of the project, a description of the facility and the test hardware, the test operating conditions, a summary of the operation, and the results of analyzing specimens from several uncooled and cooled probes exposed in the facility. Extensive microstructural analyses of the base alloys, claddings, coatings, and weldments were performed on specimens exposed in several probes for different lengths of time. Alloy penetration data were determined for several of the materials as a function of specimen orientation and the exposure location in the combustor. Finally, the data were compared with earlier laboratory test data, and the long-term performance of candidate materials for air-heater applications was assessed.

  12. Comparison of toluene removal in air at atmospheric conditions by different corona discharges.

    PubMed

    Schiorlin, Milko; Marotta, Ester; Rea, Massimo; Paradisi, Cristina

    2009-12-15

    Different types of corona discharges, produced by DC of either polarity (+/-DC) and positive pulsed (+pulsed) high voltages, were applied to the removal of toluene via oxidation in air at room temperature and atmospheric pressure. Mechanistic insight was obtained through comparison of the three different corona regimes with regard to process efficiency, products, response to the presence of humidity and, for DC coronas, current/voltage characteristics coupled with ion analysis. Process efficiency increases in the order +DC < -DC < +pulsed, with pulsed processing being remarkably efficient compared to recently reported data for related systems. With -DC, high toluene conversion and product selectivity were achieved, CO(2) and CO accounting for about 90% of all reacted carbon. Ion analysis, performed by APCI-MS (Atmospheric Pressure Chemical Ionization-Mass Spectrometry), provides a powerful rationale for interpreting current/voltage characteristics of DC coronas. All experimental findings are consistent with the proposal that in the case of +DC corona toluene oxidation is initiated by reactions with ions (O(2)(+*), H(3)O(+) and their hydrates, NO(+)) both in dry as well as in humid air. In contrast, with -DC no evidence is found for any significant reaction of toluene with negative ions. It is also concluded that in humid air OH radicals are involved in the initial stage of toluene oxidation induced both by -DC and +pulsed corona.

  13. Sterilization of soybean powder with plasma treatment in atmospheric humid air

    NASA Astrophysics Data System (ADS)

    Iwami, R.; Kikuchi, Y.; Fukumoto, N.; Nagata, M.; Nakayama, A.; Nakagawa, K.

    2013-10-01

    Sterilization of foods has been performed by conventional methods such as heat, steam and chemical solutions. However, these sterilization techniques could cause damages to the food material. It is considered that plasma sterilization at atmospheric pressure is one of the promising alternative methods because of the low temperature process. In our previous study, the inactivation of Bacillus atrophaeusspores by a dielectric barrier discharge (DBD) plasma produced in atmospheric humid air was investigated in order to develop low-temperature, low-cost and high-speed plasma sterilization technique. The results showed that the inactivation of Bacillus atrophaeusspores was found to be dependent strongly on the humidity. In the present study, the plasma treatment technique in humid air is applied to sterilization of soybean powder. Effects of plasma sterilization were successfully confirmed by a colony counting method. It was found that the sterilization efficiency was increased by using the humid air as the discharge gas. In the conference, an improvement of the plasma treatment system to enhance the sterilization efficiency will be shown.

  14. Conceptual design and structural analysis of the spectroscopy of the atmosphere using far infrared emission (SAFIRE) instrument

    NASA Technical Reports Server (NTRS)

    Moses, Robert W.; Averill, Robert D.

    1992-01-01

    The conceptual design and structural analysis for the Spectroscopy of the Atmosphere using Far Infrared Emission (SAFIRE) Instrument are provided. SAFIRE, which is an international effort, is proposed for the Earth Observing Systems (EOS) program for atmospheric ozone studies. A concept was developed which meets mission requirements and is the product of numerous parametric studies and design/analysis iterations. Stiffness, thermal stability, and weight constraints led to a graphite/epoxy composite design for the optical bench and supporting struts. The structural configuration was determined by considering various mounting arrangements of the optical, cryo, and electronic components. Quasi-static, thermal, modal, and dynamic response analyses were performed, and the results are presented for the selected configuration.

  15. Laboratory studies at high resolution of the infrared absorption spectra of a number of gases found in planetary atmospheres

    NASA Technical Reports Server (NTRS)

    Hunt, R. H.

    1983-01-01

    The infrared absorption spectra of a number of gases found in planetary atmospheres were studied at high resolution. Absorption line measurements which can be of value for the interpretation of planetary spectra in terms of molecular abundances and conditions in the planetary atmospheres were provided. The high resolution spectra have yielded measurements of individual vibration rotation line parameters including positions, strengths, pressure broadened widths and, where assignments were unknown, the temperature sensitivity of the strengths. Such information allows the determinations of the absorption of a given molecular gas under planetary conditions of temperature and pressure and at the same time it provides the data necessary if the spectra are to be understood in terms of basic molecular theory. Thus this work has included spectral analysis in the form of line assignments as well as fitting of the data to Hamiltonian models. Such fitting is very useful in that it helps to confirm and extend the assignments.

  16. The Atmospheres of Saturn and Titan in the Near-Infrared: First Results of Cassini/VIMS

    NASA Technical Reports Server (NTRS)

    Baines, K. H.; Drossart, P.; Momary, T. W.; Formisano, V.; Griffith, C.; Bellucci, G.; Bibring, J. P.; Brown, R. H.; Buratti, B. J.; Capaccioni, F.; Cerroni, P.; Clark, R. N.; Coradini, A.; Combes, M.; Cruikshank, D. P.; Jaumann, R.; Langevin, Y.; Matson, D. L.; McCord, T. B.; Mennella, V.; Nelson, R. M.; Nicholson, P. D.; Sicardy, B.; Sotin, C.

    2005-01-01

    The wide spectral coverage and extensive spatial, temporal, and phase-angle mapping capabilities of the Visual Infrared Mapping Spectrometer (VIMS) onboard the Cassini-Huygens Orbiter are producing fundamental new insights into the nature of the atmospheres of Saturn and Titan. For both bodies, VIMS maps over time and solar phase angles provide information for a multitude of atmospheric constituents and aerosol layers, providing new insights into atmospheric structure and dynamical and chemical processes. For Saturn, salient early results include evidence for phosphine depletion in relatively dark and less cloudy belts at temperate and mid-latitudes compared to the relatively bright and cloudier Equatorial Region, consistent with traditional theories of belts being regions of relative downwelling. Additional Saturn results include (1) the mapping of enhanced trace gas absorptions at the south pole, and (2) the first high phase-angle, high-spatial-resolution imagery of CH4 fluorescence. An additional fundamental new result is the first nighttime near-infrared mapping of Saturn, clearly showing discrete meteorological features relatively deep in the atmosphere beneath the planet's sunlit haze and cloud layers, thus revealing a new dynamical regime at depth where vertical dynamics is relatively more important than zonal dynamics in determining cloud morphology. Zonal wind measurements at deeper levels than previously available are achieved by tracking these features over multiple days, thereby providing measurements of zonal wind shears within Saturn's troposphere when compared to cloudtop movements measured in reflected sunlight. For Titan, initial results include (1) the first detection and mapping of thermal emission spectra of CO, CO2, and CH3D on Titan's nightside limb, (2) the mapping of CH4 fluorescence over the dayside bright limb, extending to approximately 750 km altitude, (3) wind measurements of approximately 0.5 ms(exp -1), favoring prograde, from the

  17. The atmospheres of Saturn and Titan in the near-infrared: First results of Cassini/Vims

    USGS Publications Warehouse

    Baines, K.H.; Momary, T.W.; Buratti, B.J.; Matson, D.L.; Nelson, R.M.; Drossart, P.; Sicardy, B.; Formisano, V.; Bellucci, G.; Coradini, A.; Griffith, C.; Brown, R.H.; Bibring, J.-P.; Langevin, Y.; Capaccioni, F.; Cerroni, P.; Clark, R.N.; Combes, M.; Cruikshank, D.P.; Jaumann, R.; McCordt, T.B.; Mennella, V.; Nicholson, P.D.; Sotin, C.

    2006-01-01

    The wide spectral coverage and extensive spatial, temporal, and phase-angle mapping capabilities of the Visual Infrared Mapping Spectrometer (VIMS) onboard the Cassini-Huygens Orbiter are producing fundamental new insights into the nature of the atmospheres of Saturn and Titan. For both bodies, VIMS maps over time and solar phase angles provide information for a multitude of atmospheric constituents and aerosol layers, providing new insights into atmospheric structure and dynamical and chemical processes. For Saturn, salient early results include evidence for phosphine depletion in relatively dark and less cloudy belts at temperate and mid-latitudes compared to the relatively bright and cloudier Equatorial Region, consistent with traditional theories of belts being regions of relative downwelling. Additional Saturn results include (1) the mapping of enhanced trace gas absorptions at the south pole, and (2) the first high phase-angle, high-spatial-resolution imagery of CH4 fluorescence. An additional fundamental new result is the first nighttime near-infrared mapping of Saturn, clearly showing discrete meteorological features relatively deep in the atmosphere beneath the planet's sunlit haze and cloud layers, thus revealing a new dynamical regime at depth where vertical dynamics is relatively more important than zonal dynamics in determining cloud morphology. Zonal wind measurements at deeper levels than previously available are achieved by tracking these features over multiple days, thereby providing measurements of zonal wind shears within Saturn's troposphere when compared to cloudtop movements measured in reflected sunlight. For Titan, initial results include (1) the first detection and mapping of thermal emission spectra of CO, CO2, and CH3D on Titan's nightside limb, (2) the mapping of CH4 fluorescence over the dayside bright limb, extending to ??? 750 km altitude, (3) wind measurements of ???0.5 ms-1, favoring prograde, from the movement of a persistent

  18. Monitoring of atmospheric aerosol emissions using a remotely piloted air vehicle (RPV)-Borne Sensor Suite

    SciTech Connect

    1996-05-01

    We have developed a small sensor system, the micro-atmospheric measurement system ({mu}-AMS), to monitor and track aerosol emissions. The system was developed to fly aboard a remotely piloted air vehicle, or other mobile platform, to provide real-time particle measurements in effluent plumes and to collect particles for chemical analysis. The {mu}-AMS instrument measures atmospheric parameters including particle mass concentration and size distribution, temperature, humidity, and airspeed, altitude and position (by GPS receiver) each second. The sensor data are stored onboard and are also down linked to a ground station in real time. The {mu}-AMS is battery powered, small (8 in. dia x 36 in.), and lightweight (15 pounds). Aerosol concentrations and size distributions from above ground explosive tests, airbone urban pollution, and traffic-produced particulates are presented.

  19. Atmospheric air pollutants: CO in Nitrogen, 5 μmol/mol

    NASA Astrophysics Data System (ADS)

    Konopelko, L. A.; Pankratov, V. V.; Pankov, A. A.; Ivahnenko, B. V.; Efremova, O. V.; Bakovec, N. V.; Mironchik, A. M.; Aleksandrov, V. V.

    2017-01-01

    This article presents the report on the COOMET supplementary comparison "Atmospheric air pollutants: CO in Nitrogen, 5 μmol/mol". Carbon monoxide (CO) is present in atmosphere due to different natural and anthropogenic sources. CO is a toxic gas and in concentrations higher than (3-5) μmol/mol it is hazardous to human health. Main text To reach the main text of this paper, click on Final Report. Note that this text is that which appears in Appendix B of the BIPM key comparison database kcdb.bipm.org/. The final report has been peer-reviewed and approved for publication by the CCQM, according to the provisions of the CIPM Mutual Recognition Arrangement (CIPM MRA).

  20. Revisiting Atmospheric Lead in NYC - Comparison of Archived Air Filters to Urban Park Sediments and Soils

    NASA Astrophysics Data System (ADS)

    Chillrud, S. N.; Ross, J. M.; Yan, B.; Bopp, R.

    2015-12-01

    Urban lake sediments have the potential to be used for reconstructing history of aerosols, providing data before the start of urban air quality monitoring. In a previous study, the similarity between radionuclide and excess Pb inventories (57 g/m^2) in Central Park Lake (CPL) sediments and those same parameters in Central Park soils (CPS) was interpreted to indicate that urban lake sediment cores from CPL represent deposition of atmospheric aerosols over the history of the park, which was constructed in the 1860s. Furthermore, metal ratios and metal chronologies indicated that incineration was the major source of Pb to the NYC atmosphere over the 20th century. In this report, we compare the lake chronologies for metals to a set of archived air filters collected by the Department of Energy's Environmental Measurement Lab (EML). These weekly filters of total suspended particulates (TSP) were collected by a high volume sampler located in lower Manhattan for radionuclides as part of the program focused on documenting radioactive fallout from nuclear weapons testing. Metal concentrations measured in subsamples of the EML filters collected between the 1970s to 1990s showed Pb decreasing more slowly than the records of Pb added to gasoline. Metal ratios in the filters were similar to the ratios measured in CPL sediments; the Pb to Sn ratios were roughly 20:1 and the Pb to Zn ratios were in close to 1. The similarity of the ratios provides additional solid support that the CP Lake sediment cores reflect atmospheric inputs. The enrichment of Pb in the large aerosol particle fraction (TSP), relative to fine PM2.5 fraction, demonstrates that the resuspended NYC soils and their historical contaminant burden, are the primary, current source of Pb to NYC air.

  1. Sterilization effect of atmospheric pressure non-thermal air plasma on dental instruments

    PubMed Central

    Sung, Su-Jin; Huh, Jung-Bo; Yun, Mi-Jung; Chang, Brian Myung W.; Jeong, Chang-Mo

    2013-01-01

    PURPOSE Autoclaves and UV sterilizers have been commonly used to prevent cross-infections between dental patients and dental instruments or materials contaminated by saliva and blood. To develop a dental sterilizer which can sterilize most materials, such as metals, rubbers, and plastics, the sterilization effect of an atmospheric pressure non-thermal air plasma device was evaluated. MATERIALS AND METHODS After inoculating E. coli and B. subtilis the diamond burs and polyvinyl siloxane materials were sterilized by exposing them to the plasma for different lengths of time (30, 60, 90, 120, 180 and, 240 seconds). The diamond burs and polyvinyl siloxane materials were immersed in PBS solutions, cultured on agar plates and quantified by counting the colony forming units. The data were analyzed using one-way ANOVA and significance was assessed by the LSD post hoc test (α=0.05). RESULTS The device was effective in killing E. coli contained in the plasma device compared with the UV sterilizer. The atmospheric pressure non-thermal air plasma device contributed greatly to the sterilization of diamond burs and polyvinyl siloxane materials inoculated with E. coli and B. subtilis. Diamond burs and polyvinyl siloxane materials inoculated with E. coli was effective after 60 and 90 seconds. The diamond burs and polyvinyl siloxane materials inoculated with B. subtilis was effective after 120 and 180 seconds. CONCLUSION The atmospheric pressure non-thermal air plasma device was effective in killing both E. coli and B. subtilis, and was more effective in killing E. coli than the UV sterilizer. PMID:23508991

  2. Comparison of halocarbon measurements in an atmospheric dry whole air sample

    PubMed Central

    Hall, Bradley D.; Harth, Christina M.; Kim, Jin Seog; Lee, Jeongsoon; Montzka, Stephen A.; Mühle, Jens; Reimann, Stefan; Vollmer, Martin K.; Weiss, Ray F.

    2015-01-01

    The growing awareness of climate change/global warming, and continuing concerns regarding stratospheric ozone depletion, will require continued measurements and standards for many compounds, in particular halocarbons that are linked to these issues. In order to track atmospheric mole fractions and assess the impact of policy on emission rates, it is necessary to demonstrate measurement equivalence at the highest levels of accuracy for assigned values of standards. Precise measurements of these species aid in determining small changes in their atmospheric abundance. A common source of standards/scales and/or well-documented agreement of different scales used to calibrate the measurement instrumentation are key to understanding many sets of data reported by researchers. This report describes the results of a comparison study among National Metrology Institutes and atmospheric research laboratories for the chlorofluorocarbons (CFCs) dichlorodifluoromethane (CFC-12), trichlorofluoromethane (CFC-11), and 1,1,2-trichlorotrifluoroethane (CFC-113); the hydrochlorofluorocarbons (HCFCs) chlorodifluoromethane (HCFC-22) and 1-chloro-1,1-difluoroethane (HCFC-142b); and the hydrofluorocarbon (HFC) 1,1,1,2-tetrafluoroethane (HFC-134a), all in a dried whole air sample. The objective of this study is to compare calibration standards/scales and the measurement capabilities of the participants for these halocarbons at trace atmospheric levels. The results of this study show agreement among four independent calibration scales to better than 2.5% in almost all cases, with many of the reported agreements being better than 1.0%. PMID:26753167

  3. Long-period humidity variability in the Arctic atmosphere from upper-air observations

    NASA Astrophysics Data System (ADS)

    Agurenko, A.; Khokhlova, A.

    2014-12-01

    Under climate change, atmospheric water content also tends to change. This gives rise to changes in the amount of moisture transferred, clouds and precipitation, as well as in hydrological regime. This work analyzes seasonal climatic characteristics of precipitated water in the Arctic atmosphere, by using 1972-2011 data from 55 upper-air stations located north of 60°N. Regions of maximum and minimum mean values and variability trends are determined. In the summer, water amount is shown to increase in nearly the whole of the latitudinal zone. The comparison with the similar characteristics of reanalysis obtained by the other authors shows a good agreement. Time variation in the atmosphere moisture transport crossing 70°N, which is calculated from observation data, is presented and compared with model results. The work is supported by the joint EC ERA.Net RUS and Russian Fundamental Research Fund Project "Arctic Climate Processes Linked Through the Circulation of the Atmosphere" (ACPCA) (project 12-05-91656-ЭРА_а).

  4. Decline of hexachlorocyclohexane in the Arctic atmosphere and reversal of air-sea gas exchange

    NASA Astrophysics Data System (ADS)

    Bidleman, T. F.; Jantunen, L. M.; Falconer, R. L.; Barrie, L. A.; Fellin, P.

    1995-02-01

    Hexachlorocyclohexanes (HCHs) are the most abundant organochlorine pesticides in the arctic atmosphere and ocean surface water. A compilation of measurements made between 1979-93 from stations in the Canadian and Norwegian Arctic and from cruises in the Bering and Chukchi seas indicates that atmospheric concentrations of α-HCH have declined significantly (p < 0.01), with a time for 50% decrease of about 4 y in summer-fall and 6 y in winter-spring. The 1992-93 levels of about 100 pg m-3 are 2-4 fold lower than values in the mid-1980s. The trend in γ-HCH is less pronounced, but a decrease is also suggested from measurements in the Canadian Arctic and the Bering-Chukchi seas. HCHs in ocean surface water have remained relatively constant since the early 1980s. The decline in atmospheric α-HCH has reversed the net direction of air-sea gas exchange to the point where some northern waters are now sources of the pesticide to the atmosphere instead of sinks.

  5. Thermal monitoring of transport infrastructures by infrared thermography coupled with inline local atmospheric conditions survey

    NASA Astrophysics Data System (ADS)

    Dumoulin, J.

    2013-09-01

    An infrared system architecture (software and hardware) has been studied and developed to allow long term monitoring of transport infrastructures in a standalone configuration. It is based on the implementation of low cost infrared thermal cameras (equipped with uncooled microbolometer focal plane array) available on the market coupled with other measurement systems. All data collected feed simplified radiative models running on GPU available on small PC to produce corrected thermal map of the surveyed structure at selected time step. Furthermore, added Web-enabled capabilities of this new infrared measurement system are also presented and discussed. A prototype of this system was tested and evaluated on real infrastructure opened to traffic. Results obtained by image and signal processing are presented. Finally, conclusions and perspectives for new implementation and new functionalities are presented and discussed.

  6. A study of the glow discharge characteristics of contact electrodes at atmospheric pressure in air

    SciTech Connect

    Liu, Wenzheng Sun, Guangliang Li, Chuanhui; Zhang, Rongrong

    2014-04-15

    Electric field distributions and discharge properties of rod-rod contact electrodes were studied under the condition of DBD for the steady generation of atmospheric pressure glow discharge plasma (APGD) in air. We found that under the effect of the initial electrons generated in a nanometer-scale gap, the rod-rod cross-contact electrodes yielded APGD plasma in air. Regarding the rod-rod cross-contact electrodes, increasing the working voltage expanded the strong electric field area of the gas gap so that both discharge area and discharge power increased, and the increase in the number of contact points kept the initial discharge voltage unchanged a