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Sample records for aisi304 stainless steel

  1. Chemical composition of passive films on AISI 304 stainless steel

    SciTech Connect

    Lorang, G.; Da Cunha Belo, M. ); Simoes, A.M.P.; Ferreira, M.G.S. . Dept. de Engenharia Quimica)

    1994-12-01

    Chemical characterization of passive films formed on AISI 304 austenitic stainless steel, in a borate/boric acid solution at pH 9.2, under various conditions of potential, temperature, and polarizations time, was made by Auger electron spectroscopy combined with ion sputtering, and x-ray photoelectron spectroscopy (XPS). The depth chemical composition, thickness, and duplex character of the passive layers were determined after processing AES sputter profiles by their quantitative approach based on the sequential layer sputtering model. Moreover, separated contributions of elements in their oxidized and unoxidized state could be disclosed from part to part of the oxide-alloy interface. The XPS study specified the chemical bondings which take placed inside the film, between Fe and oxygen (and water).

  2. Abnormal grain growth in AISI 304L stainless steel

    SciTech Connect

    Shirdel, M.; Mirzadeh, H.; Parsa, M.H.

    2014-11-15

    The microstructural evolution during abnormal grain growth (secondary recrystallization) in 304L stainless steel was studied in a wide range of annealing temperatures and times. At relatively low temperatures, the grain growth mode was identified as normal. However, at homologous temperatures between 0.65 (850 °C) and 0.7 (900 °C), the observed transition in grain growth mode from normal to abnormal, which was also evident from the bimodality in grain size distribution histograms, was detected to be caused by the dissolution/coarsening of carbides. The microstructural features such as dispersed carbides were characterized by optical metallography, X-ray diffraction, scanning electron microscopy, energy dispersive X-ray analysis, and microhardness. Continued annealing to a long time led to the completion of secondary recrystallization and the subsequent reappearance of normal growth mode. Another instance of abnormal grain growth was observed at homologous temperatures higher than 0.8, which may be attributed to the grain boundary faceting/defaceting phenomenon. It was also found that when the size of abnormal grains reached a critical value, their size will not change too much and the grain growth behavior becomes practically stagnant. - Highlights: • Abnormal grain growth (secondary recrystallization) in AISI 304L stainless steel • Exaggerated grain growth due to dissolution/coarsening of carbides • The enrichment of carbide particles by titanium • Abnormal grain growth due to grain boundary faceting at very high temperatures • The stagnancy of abnormal grain growth by annealing beyond a critical time.

  3. Surface textural features and its formation process of AISI 304 stainless steel subjected to massive LSP impacts

    NASA Astrophysics Data System (ADS)

    Luo, K. Y.; Yao, H. X.; Dai, F. Z.; Lu, J. Z.

    2014-04-01

    The effects of massive laser shock peening (LSP) impacts on surface textural feature of AISI 304 stainless steel (AISI 304 SS), including surface waviness, surface roughness, and machining texture and direction, have been investigated by using WKYO-NT1100 surface profiler and TR300 stylus roughness shape measuring instrument. Experimental results show that massive LSP impacts have an important influence on the surface waviness of the AISI 304 SS sample, but do not have a measurable impact on the surface roughness. Moreover, massive LSP impacts with constraint and ablation mode generate a novel compound texture on the surface of the AISI 304 SS sample. In addition, the formation process of surface compound texture in AISI 304 SS by massive LSP impacts is also entirely revealed.

  4. Stoichiometric titanium dioxide ion implantation in AISI 304 stainless steel for corrosion protection

    NASA Astrophysics Data System (ADS)

    Hartwig, A.; Decker, M.; Klein, O.; Karl, H.

    2015-12-01

    The aim of this study is to evaluate the applicability of highly chemically inert titanium dioxide synthesized by ion beam implantation for corrosion protection of AISI 304 stainless steel in sodium chloride solution. More specifically, the prevention of galvanic corrosion between carbon-fiber reinforced plastic (CFRP) and AISI 304 was investigated. Corrosion performance of TiO2 implanted AISI 304 - examined for different implantation and annealing parameters - is strongly influenced by implantation fluence. Experimental results show that a fluence of 5 × 1016 cm-2 (Ti+) and 1 × 1017 cm-2 (O+) is sufficient to prevent pitting corrosion significantly, while galvanic corrosion with CFRP can already be noticeably reduced by an implantation fluence of 5 × 1015 cm-2 (Ti+) and 1 × 1016 cm-2 (O+). Surface roughness, implantation energy and annealing at 200 °C and 400 °C show only little influence on the corrosion behavior. TEM analysis indicates the existence of stoichiometric TiO2 inside the steel matrix for medium fluences and the formation of a separated metal oxide layer for high fluences.

  5. Influence of nitrogen alloying on hydrogen embrittlement in AISI 304-type stainless steels

    NASA Astrophysics Data System (ADS)

    Hannula, Simo-Pekka; Hänninen, Hannu; Tähtinen, Seppo

    1984-12-01

    Hydrogen embrittlement of AISI 304-type austenitic stainless steels has been studied with special emphasis on the effects of the nitrogen content of the steels. Hydrogen charging was found to degrade the mechanical properties of all the steels studied, as measured by a tensile test. The fracture surfaces of hydrogen charged specimens were brittle cleavage-like whereas the uncharged specimens showed ductile, dimpled fracture. In sensitized materials transgranular cleavage mode of fracture was replaced by an intergranular mode of fracture and the losses of mechanical properties were higher. Nitrogen alloying decreased the hydrogen-induced losses of mechanical properties by increasing the stability of austenite. In sensitized steels the stability of austenite and nitrogen content were found to have only a minor effect on hydrogen embrittlement, except when sensitization had caused α'-martensite transformation at the grain boundaries.

  6. Plasma nitriding process by direct current glow discharge at low temperature increasing the thermal diffusivity of AISI 304 stainless steel

    SciTech Connect

    Prandel, L. V.; Somer, A.; Assmann, A.; Camelotti, F.; Costa, G.; Bonardi, C.; Jurelo, A. R.; Rodrigues, J. B.; Cruz, G. K.

    2013-02-14

    This work reports for the first time on the use of the open photoacoustic cell technique operating at very low frequencies and at room temperature to experimentally determine the thermal diffusivity parameter of commercial AISI304 stainless steel and AISI304 stainless steel nitrided samples. Complementary measurements of X-ray diffraction and scanning electron microscopy were also performed. The results show that in standard AISI 304 stainless steel samples the thermal diffusivity is (4.0 {+-} 0.3) Multiplication-Sign 10{sup -6} m{sup 2}/s. After the nitriding process, the thermal diffusivity increases to the value (7.1 {+-} 0.5) Multiplication-Sign 10{sup -6} m{sup 2}/s. The results are being associated to the diffusion process of nitrogen into the surface of the sample. Carrying out subsequent thermal treatment at 500 Degree-Sign C, the thermal diffusivity increases up to (12.0 {+-} 2) Multiplication-Sign 10{sup -6} m{sup 2}/s. Now the observed growing in the thermal diffusivity must be related to the change in the phases contained in the nitrided layer.

  7. Niobized AISI 304 stainless steel bipolar plate for proton exchange membrane fuel cell

    NASA Astrophysics Data System (ADS)

    Wang, Lixia; Sun, Juncai; Li, Pengbin; Jing, Bo; Li, Song; Wen, Zhongsheng; Ji, Shijun

    2012-06-01

    AISI 304 stainless steel (SS) has been niobized by a plasma surface diffusion alloying method. A 3 μm niobized layer with dominant niobium elements has been formed on the 304 SS surface and the performances of the niobized 304 SS has been examined and evaluated as bipolar plate for proton exchange membrane fuel cell (PEMFC). Results show that the average contact angle with water for the niobized 304 SS is about 90.4°, demonstrating better hydrophobicity as compared with the untreated 304 SS (68.1°). The corrosion resistance of the 304 SS is considerably improved by the niobized layer with the corrosion current densities decreased at 0.2 and 0.4 μA cm-2 in simulated PEMFC anode purged with hydrogen and the cathode purged with air condition (0.05 M H2SO4 + 2 ppm F- solution at 70 °C), respectively. The interfacial contact resistance (ICR) for the as-prepared niobized 304 SS is 10.53 mΩ cm2 at the compaction of 140 N cm-2. Furthermore, after 4 h potentiostatic tests, the niobizied specimens exhibit much lower ICR than that for the untreated ones. Thus, the niobized layer can act as a conductively protective layer of the 304 SS bipolar plate for PEMFC.

  8. Some aspects of thermomechanical fatigue of AISI 304L stainless steel: Part I. creep- fatigue damage

    NASA Astrophysics Data System (ADS)

    Zauter, R.; Christ, H. J.; Mughrabi, H.

    1994-02-01

    Thermomechanical fatigue (TMF) tests on the austenitic stainless steel AISI 304L have been conducted under “true≓ plastic-strain control in vacuum. This report considers the damage oc-curring during TMF loading. It is shown how the temperature interval and the phasing (in-phase, out-of-phase) determine the mechanical response and the lifetime of the specimens. If creep-fatigue interaction takes place during in-phase cycling, the damage occurs inside the ma-terial, leading to intergranular cracks which reduce the lifetime considerably. Out-of-phase cy-cling inhibits creep-induced damage, and no lifetime reduction occurs, even if the material is exposed periodically to temperatures in the creep regime. A formula is proposed which allows prediction of the failure mode, depending on whether creep-fatigue damage occurs or not. At a given strain rate, the formula is able to estimate the temperature of transition between pure fatigue and creep-fatigue damage.

  9. Microstructure, Texture, and Mechanical Property Analysis of Gas Metal Arc Welded AISI 304 Austenitic Stainless Steel

    NASA Astrophysics Data System (ADS)

    Saha, Saptarshi; Mukherjee, Manidipto; Pal, Tapan Kumar

    2015-03-01

    The present study elaborately explains the effect of welding parameters on the microstructure, texture, and mechanical properties of gas metal arc welded AISI 304 austenitic stainless steel sheet (as received) of 4 mm thickness. The welded joints were prepared by varying welding speed (WS) and current simultaneously at a fixed heat input level using a 1.2-mm-diameter austenitic filler metal (AISI 316L). The overall purpose of this study is to investigate the effect of the variation of welding conditions on: (i) Microstructural constituents using optical microscope and transmission electron microscope; (ii) Micro-texture evolution, misorientation distributions, and grain boundaries at welded regions by measuring the orientation data from electron back scattered diffraction; and (iii) Mechanical properties such as hardness and tensile strength, and their correlation with the microstructure and texture. It has been observed that the higher WS along with the higher welding current (weld metal W1) can enhance weld metal mechanical properties through alternation in microstructure and texture of the weld metal. Higher δ-ferrite formation and high-angle boundaries along with the <101> + <001> grain growth direction of the weld metal W1 were responsible for dislocation pile-ups, SFs, deformation twinning, and the induced martensite with consequent strain hardening during tensile deformation. Also, fusion boundary being the weakest link in the welded structure, failure took place mainly at this region.

  10. High temperature oxidation behavior of austenitic stainless steel AISI 304 in steam of nanofluids contain nanoparticle ZrO2

    SciTech Connect

    Prajitno, Djoko Hadi Syarif, Dani Gustaman

    2014-03-24

    The objective of this study is to evaluate high temperature oxidation behavior of austenitic stainless steel SS 304 in steam of nanofluids contain nanoparticle ZrO{sub 2}. The oxidation was performed at high temperatures ranging from 600 to 800°C. The oxidation time was 60 minutes. After oxidation the surface of the samples was analyzed by different methods including, optical microscope, scanning electron microscope (SEM) and X-ray diffraction (XRD). X-ray diffraction examination show that the oxide scale formed during oxidation of stainless steel AISI 304 alloys is dominated by iron oxide, Fe{sub 2}O{sub 3}. Minor element such as Cr{sub 2}O{sub 3} is also appeared in the diffraction pattern. Characterization by optical microscope showed that cross section microstructure of stainless steel changed after oxidized with the oxide scale on the surface stainless steels. SEM and x-ray diffraction examination show that the oxide of ZrO{sub 2} appeared on the surface of stainless steel. Kinetic rate of oxidation of austenite stainless steel AISI 304 showed that increasing oxidation temperature and time will increase oxidation rate.

  11. Microstructure and Mechanical Properties of Plasma Arc Brazed AISI 304L Stainless Steel and Galvanized Steel Plates

    NASA Astrophysics Data System (ADS)

    Jin, Yajuan; Li, Ruifeng; Yu, Zhishui; Wang, Yu

    2016-04-01

    Plasma arc brazing is used to join the AISI 304L stainless steel and galvanized steel plate butt joints with the CuSi3Mn1 filler wire. The effect of parameters on weld surface appearance, interfacial microstructure, and composition distribution in the joint was studied. The microhardness and mechanical tests were conducted to determine the mechanical properties of the welded specimens. The results indicated that good appearance, bead shape, and sufficient metallurgical bonding could be obtained when the brazing process was performed with a wire feeding speed of 0.8 m/min, plasma gas flow rate of 3.0 l/min, welding current of 100 A, and welding speed of 27 cm/min. During plasma arc brazing process, the top corner of the stainless steel and galvanized steel plate were heated and melted, and the melted quantity of stainless steel was much more than that of the galvanized steel due to the thermal conductivity coefficient difference between the dissimilar materials. The microhardness test results shows that the microhardness value gradually increased from the side of the galvanized steel to the stainless steel in the joint, and it is good for improving the mechanical properties of joint. The tensile strength was a little higher than that of the brazing filler, and the fracture position of weld joint was at the base metal of galvanized steel plate.

  12. Microstructural Evolutions During Annealing of Plastically Deformed AISI 304 Austenitic Stainless Steel: Martensite Reversion, Grain Refinement, Recrystallization, and Grain Growth

    NASA Astrophysics Data System (ADS)

    Naghizadeh, Meysam; Mirzadeh, Hamed

    2016-08-01

    Microstructural evolutions during annealing of a plastically deformed AISI 304 stainless steel were investigated. Three distinct stages were identified for the reversion of strain-induced martensite to austenite, which were followed by the recrystallization of the retained austenite phase and overall grain growth. It was shown that the primary recrystallization of the retained austenite postpones the formation of an equiaxed microstructure, which coincides with the coarsening of the very fine reversed grains. The latter can effectively impair the usefulness of this thermomechanical treatment for grain refinement at both high and low annealing temperatures. The final grain growth stage, however, was found to be significant at high annealing temperatures, which makes it difficult to control the reversion annealing process for enhancement of mechanical properties. Conclusively, this work unravels the important microstructural evolution stages during reversion annealing and can shed light on the requirements and limitations of this efficient grain refining approach.

  13. Application of Deep Cryogenic Treatment to Uncoated Tungsten Carbide Inserts in the Turning of AISI 304 Stainless Steel

    NASA Astrophysics Data System (ADS)

    Özbek, Nursel Altan; Çİçek, Adem; Gülesİn, Mahmut; Özbek, Onur

    2016-12-01

    This study investigated the effects of deep cryogenic treatment (DCT) on the wear performance of uncoated tungsten carbide inserts. AISI 304 austenitic stainless steel, widely used in industry, was selected as the workpiece material. Cutting experiments showed that the amount of wear significantly increased with increasing cutting speed. In addition, it was found that DCT contributed to the wear resistance of the turning inserts. The treated turning inserts were less worn by 48 and 38 pct in terms of crater wear and notch wear, respectively, whereas they exhibited up to 18 pct superior wear performance in terms of flank wear. This was attributed to the precipitation of new and finer η-carbides and their homogeneous distribution in the microstructure of the tungsten carbide material after deep cryogenic treatment. Analyses via image processing, hardness measurements, and SEM observations confirmed these findings.

  14. Comparison of Roller Burnishing Method with Other Hole Surface Finishing Processes Applied on AISI 304 Austenitic Stainless Steel

    NASA Astrophysics Data System (ADS)

    Akkurt, Adnan

    2011-08-01

    Component surface quality and selection of the optimum material are the main factors determining the performance of components used in machine manufacturing. The level of hole surface quality can be evaluated by the measurements regarding surface roughness, micro-hardness, and cylindricity. In this study, data had been obtained for different hole drilling methods. The characteristics of materials obtained after applications were compared for different hole-finishing processes to identify best hole drilling method. AISI 304 austenitic stainless steel material was used. Surface finishing of holes were performed using drilling, turning, reaming, grinding, honing, and roller burnishing methods. The results of the study show that the roller burnishing method gives the best results for mechanical, metallurgical properties, and hole surface quality of the material. On the other hand, the worst characteristics were obtained in the drilling method.

  15. Some aspects of thermomechanical fatigue of AISI 304L stainless steel; Part 1: Creep-fatigue damage

    SciTech Connect

    Zauter, R. ); Christ, H.J. . Inst. of Materials Technology); Mughrabi, H. . Inst. for Materials Science)

    1994-02-01

    Thermomechanical fatigue (TMF) tests on the austenitic stainless steel AISI 304L have been conducted under true' plastic-strain control in vacuum. This report considers the damage occurring during TMF loading. It is shown how the temperature interval and the phasing (in phase, out-of-phase) determine the mechanical response and the lifetime of the specimens. If creep-fatigue interaction takes place during in-phase cycling, the damage occurs inside the material, leading creep-induced damage, and no lifetime reduction occurs, even if the material is exposed periodically to temperature in the creep regime. A formula is proposed which allows prediction of the failure mode, depending on whether creep-fatigue damage occurs or not. At a given strain rate, the formula is able to estimate the temperature of transition between pure fatigue and creep-fatigue damage.

  16. Correlation between surface physicochemical properties and the release of iron from stainless steel AISI 304 in biological media.

    PubMed

    Hedberg, Yolanda; Karlsson, Maria-Elisa; Blomberg, Eva; Odnevall Wallinder, Inger; Hedberg, Jonas

    2014-10-01

    Stainless steel is widely used in biological environments, for example as implant material or in food applications, where adsorption-controlled ligand-induced metal release is of importance from a corrosion, health, and food safety perspective. The objective of this study was to elucidate potential correlations between surface energy and wettability of stainless steel surfaces and the release of iron in complexing biological media. This was accomplished by studying changes in surface energies calculated from contact angle measurements, surface oxide composition (X-ray photoelectron spectroscopy), and released iron (graphite furnace atomic absorption spectroscopy) for stainless steel grade AISI 304 immersed in fluids containing bovine serum albumin or citric acid, and non-complexing fluids such as NaCl, NaOH, and HNO3. It was shown that the surface wettability and polar surface energy components were all influenced by adventitious atmospheric carbon (surface contamination of low molecular weight), rather than differences in surface oxide composition in non-complexing solutions. Adsorption of both BSA and citrate, which resulted in ligand-induced metal release, strongly influenced the wettability and the surface energy, and correlated well with the measured released amount of iron.

  17. Exploration of surface hydrophilic properties on AISI 304 stainless steel and silicon wafer against aging after atmospheric pressure plasma treatment

    NASA Astrophysics Data System (ADS)

    Chuang, Shang-I.; Duh, Jenq-Gong

    2014-11-01

    The aim of this work is to seek the enhanced surface hydrophilic properties on AISI 304 stainless steel and silicon wafer after atmospheric pressure plasma treatment using a specifically designed atmospheric pressure plasma jet. The aging tendency of surface hydrophilic property under air is highlighted. It is concluded that both of the silicon wafer and stainless steel treated with plasma generated from supply gas of argon 15 slm mixed with oxygen 40 sccm shows a better tendency on remaining high water contact angle as compared to that with pure argon and nitrogen addition. Additional peaks of O I (777, 844 nm), O II (408 nm) are detected by optical emission spectroscope indicating the presence of the oxygen radicals and ionic species, which interact with surfaces and thus contribute to low water contact angle (WCA) surfaces. Moreover, the result acquired from X-ray photoelectron spectroscopy (XPS) indicates that the increase in the oxygen-related bonding exhibits a better contribution on remaining high surface energy over a period of time.

  18. Determination of Neutron Exposure of AISI 304 Stainless Steel from a BWR Top Guide using Retrospective Dosimetry

    SciTech Connect

    Greenwood, Lawrence R.; Garner, Francis A.; Oliver, Brian M.; Bruemmer, Stephen M.

    2007-03-31

    Retrospective dosimetry was used to determine the accumulated neutron exposure of AISI 304 stainless steel removed from the top guide of a boiling water reactor located at the Oyster Creek nuclear power station. The material was removed from areas adjacent to cracks that were observed after ~20 years of operation. Using the plant operational history and a variety of measurements of various radioisotopes or non-radioactive transmutation products produced by irradiation, it was possible to determine the integrated flux spectra experienced by the cracked region and to specify the accumulated displacement dose. Dose estimates on two separate specimens adjacent to the cracks were found to average 1.5 ± 0.2 dpa, possibly reflecting some uncertainty in measurement but more likely suggesting a small gradient in neutron flux-spectra within the section from which the various analysis specimens were cut. This report demonstrates that it is possible to examine defective components lying outside of the core region and where neutron flux-spectra are not well known, and to use the induced transmutation products to determine the neutron exposure with some confidence by using the examined specimen as its own dosimeter.

  19. Nano-Borides and Silicide Dispersed Composite Coating on AISI 304 Stainless Steel by Laser-Assisted HVOF Spray Deposition

    NASA Astrophysics Data System (ADS)

    Sharma, Prashant; Majumdar, Jyotsna Dutta

    2014-10-01

    The study concerned a detailed microstructural investigation of nano-borides (Cr2B and Ni3B) and nano-silicide (Ni2Si) dispersed γ-nickel composite coating on AISI 304 stainless steel by HVOF spray deposition of the NiCrBSi precursor powder and subsequent laser surface melting. A continuous wave diode laser with an applied power of 3 kW and scan speed of 20 mm/s in argon shroud was employed. The characterization of the surface in terms of microstructure, microtexture, phases, and composition were carried out and compared with the as-coated (high-velocity oxy-fuel sprayed) surface. Laser surface melting led to homogenization and refinement of microstructures with the formation of few nano-silicides of nickel along with nano-borides of nickel and chromium (Ni3B, Cr2B, and Cr2B3). A detailed microtexture analysis showed the presence of no specific texture in the as-sprayed and laser-melted surface of Cr2B and Ni3B phases. The average microhardness was improved to 750-900 VHN as compared to 250 VHN of the as-received substrate. Laser surface melting improved the microhardness further to as high as 1400 VHN due to refinement of microstructure and the presence of silicides.

  20. Comparison of the Electrochemical Behavior of Ti and Nanostructured Ti-Coated AISI 304 Stainless Steel in Strongly Acidic Solutions

    NASA Astrophysics Data System (ADS)

    Attarzadeh, Farid Reza; Elmkhah, Hassan; Fattah-Alhosseini, Arash

    2017-02-01

    In this study, the electrochemical behaviors of pure titanium (Ti) and nanostructured (NS) Ti-coated AISI 304 stainless steel (SS) in strongly acidic solutions of H2SO4 were investigated and compared. A type of physical vapor deposition method, cathodic arc evaporation, was applied to deposit NS Ti on 304 SS. Scanning electron microscope and X-ray diffraction were used to characterize surface coating morphology. Potentiodynamic polarization, electrochemical impedance spectroscopy, and Mott-Schottky (M-S) analysis were used to evaluate the passive behavior of the samples. Electrochemical measurements revealed that the passive behavior of NS Ti coating was better than that of pure Ti in 0.1 and 0.01 M H2SO4 solutions. M-S analysis indicated that the passive films behaved as n-type semiconductors in H2SO4 solutions and the deposition method did not affect the semiconducting type of passive films formed on the coated samples. In addition, this analysis showed that the NS Ti coating had lower donor densities. Finally, all electrochemical tests showed that the passive behavior of the Ti-coated samples was superior, mainly due to the formation of thicker, yet less defective passive films.

  1. Finite Element Analysis of Cross Rolling on AISI 304 Stainless Steel: Prediction of Stress and Strain Fields

    NASA Astrophysics Data System (ADS)

    Rout, Matruprasad; Pal, Surjya Kanta; Singh, Shiv Brat

    2017-02-01

    Studies on the effect of strain path during rolling has been carried out for a long time, but the same has not been done using Finite Element Analysis (FEA). Change in strain path affects the state variables in the rolled plate like stress, strain, temperature etc. In the current work, Finite Element Analysis for cross rolling of AISI 304 austenitic stainless steel has been carried out by rotating the plate by 90° in between the passes. To analyze stress and strain fields in the material for cross rolling, a full 3D model of work-roll and plate has been developed using rigid-viscoplastic finite element method. The stress and strain fields, considering von-Mises yield criteria, are calculated by using updated Lagrangian method. In addition to these, the model also calculates the normal pressure and strain rate distribution in the plate during cross rolling. The nature of the variations of stress and strain fields in the plate, predicted by the model, is in good agreement with the previously published works for unidirectional rolling.

  2. Acoustic emission studies on welded and thermally treated AISI 304 stainless steel during tensile deformation

    SciTech Connect

    Mukherjee, P.; Barat, P.; Jayakumar, T.; Kalyanasundaram, P.; Rajagopalan, C.; Raj, B.

    1997-10-15

    The present investigations are planned to study the influence of prior martensites formed due to cold treatment as 77K in AISI 304 SS welded specimens, on strain-induced martensites occurred during tensile deformation using AE technique. AE parameters like count rate and root mean square (r.m.s.) voltage have been used to characterize AE activities generated during tensile deformation process in as-welded and welded-treated samples. Frequency spectrum analysis of AE signals captured from the samples has been done to understand the dynamic behavior of the martensite phase formation. Tensile properties of these samples have also been reported. Volume fraction of the magnetic phase (martensite and delta ferrite) formed in these samples are measured before and after straining. X-ray diffraction (XRD) technique has been used to support the presence of delta ferrite (formed during welding) and martensite in the weld region.

  3. Flux effect on the ion-beam nitriding of austenitic stainless-steel AISI 304L

    SciTech Connect

    Abrasonis, G.; Riviere, J.P.; Templier, C.; Pranevicius, L.; Barradas, N.P.

    2005-06-15

    The effect of flux and Ar pretreatment during ion-beam nitriding of austenitic stainless steel is investigated. The ion energy and temperature were 1.2 keV and 400 deg. C, respectively, the ion current densities were 0.5, 0.67, and 0.83 mA cm{sup -2}. The nitrogen distribution profiles were measured using nuclear reaction analysis. The obtained nitrogen distribution profiles were analyzed by the means of the nitrided layer thickness evolution due to sputtering and diffusion and the model of trapping-detrapping. Both approaches could fit well the experimental results, however, different diffusion coefficients have to be assumed for each current density. In addition, the diffusion coefficients are higher for higher current densities. On the other hand, it is shown that the pretreatment with Ar-ion beam at nitriding temperatures produces only a thermal effect without any other influence on the following nitrogen diffusion. The results are discussed in relation with surface and temperature effects and atomic transport mechanisms.

  4. The effect of inhibitor sodium nitrate on pitting corrosion of dissimilar material weldment joint of stainless steel AISI 304 and mild steel SS 400

    NASA Astrophysics Data System (ADS)

    Hilca, B. R.; Triyono

    2016-03-01

    This study experimentally evaluated the effect of Sodium Nitrate inhibitor (NaNO3) of 0.1%, 0.3%, and 0.5% on NaCl 3.5% toward pitting corrosion of dissimilar metal welding joint between stainless steel AISI 304 and mild steel SS 400. Electrochemical corrosion was tested using potentiodynamic polarization. Further the Scanning Electron Microscope (SEM) conducted to analyze the specimen. Chemical composition analysis used Energy Dispersive X-ray Spectrometry (EDS). The highest efficiency of sodium nitrate for ER 308 attained 63.8% and 64.89%for ER 309L. The specimen surface which observed through SEM showed decrease of pitting corrosion respectively with the addition of sodium nitrate content as inhibitor.

  5. Fracture and the formation of sigma phase, M[sub 23]C[sub 6], and austenite from delta-ferrite in an AISI 304L stainless steel

    SciTech Connect

    Tseng, C.C.; Shen, Y.; Thompson, S.W.; Krauss, G. . Dept. of Metallurgical and Materials Engineering); Mataya, M.C. )

    1994-06-01

    The decomposition of delta-ferrite and its effects on tensile properties and fracture of a hot-rolled AISI 304L stainless steel plate were studied. Magnetic response measurements of annealed specimens showed that the transformation rate of delta-ferrite was highest at 720 C. Transformation behavior was characterized by light microscopy, transmission electron microscopy, scanning electron microscopy, and energy-dispersive spectroscopy on thin foils. The initial transformation of delta-ferrite ([delta]) to austenite ([gamma]) and a chromium-rich carbide (M[sub 23]C[sub 6]) occurred by a lamellar eutectoid reaction, [sigma] [r reversible] M[sub 23]C[sub 6] + [gamma]. The extent of the reaction was limited by the low carbon content of the 304L plate, and the numerous, fine M[sub 23]C[sub 6] particles of the eutectoid structure provide microvoid nucleation sites in tensile specimens annealed at 720 C for short times. Sigma phase ([sigma]) formed as a result of a second eutectoid reaction, [delta] [r reversible] [sigma] + [gamma]. Brittle fracture associated with the plate-shaped sigma phase of the second eutectoid structure resulted in a significant decrease in reduction of area (RA) in the transverse tensile specimens. The RA for longitudinal specimens was not affected by the formation of sigma phase. Tensile strengths were little affected by delta-ferrite decomposition products in either longitudinal or transverse orientations.

  6. Microstructural Characterization and Wear Behavior of Nano-Boride Dispersed Coating on AISI 304 Stainless Steel by Hybrid High Velocity Oxy-Fuel Spraying Laser Surface Melting

    NASA Astrophysics Data System (ADS)

    Sharma, Prashant; Majumdar, Jyotsna Dutta

    2015-07-01

    The current study concerns the detailed microstructural characterization and investigation of wear behavior of nano-boride dispersed coating developed on AISI 304 stainless steel by high velocity oxy-fuel spray deposition of nickel-based alloy and subsequent laser melting. There is a significant refinement and homogenization of microstructure with improvement in microhardness due to laser surface melting (1200 VHN as compared to 945 VHN of as-sprayed and 250 VHN of as-received substrate). The high temperature phase stability of the as-coated and laser melted surface has been studied by differential scanning calorimeter followed by detailed phase analysis at room and elevated temperature. There is a significant improvement in wear resistance of laser melted surface as compared to as-sprayed and the as-received one due to increased hardness and reduced coefficient of friction. The mechanism of wear has been investigated in details. Corrosion resistance of the coating in a 3.56 wt pct NaCl solution is significantly improved (4.43 E-2 mm/year as compared to 5 E-1 mm/year of as-sprayed and 1.66 mm/year of as-received substrate) due to laser surface melting as compared to as-sprayed surface.

  7. Characteristics of diamond-like carbon film synthesized on AISI 304 austenite stainless steel using plasma immersion ion implantation and deposition

    NASA Astrophysics Data System (ADS)

    Liang, J. H.; Chen, M. H.; Tsai, W. F.; Lee, S. C.; Ai, C. F.

    2007-04-01

    This study examines the characteristics of diamond-like carbon (DLC) film synthesized on AISI 304 austenite stainless steel by means of a hybrid process of plasma immersion ion implantation and deposition (PIII&D) maintained at 60 °C. The former and latter processes under investigation were carried out using methane (0-20 kV) and acetylene (1-2 kV, 0.13-0.40 Pa) plasmas, respectively. Glow discharge spectrometry (GDS), Raman scattering spectroscopy (RSS), atomic force microscopy (AFM), a nano-indentation probe (NIP) and a Rockwell-C hardness tester were employed to characterize, respectively, elemental depth profiles, sp3-to-sp2 ratio, surface morphology, hardness and adhesion strength of the DLC specimen. The results revealed that the mixing layer at the interface generated by plasma immersion ion implantation of methane at a higher voltage could enhance adhesive strength of the DLC film to the substrate. Furthermore, a higher sp3-to-sp2 ratio, a smoother surface, greater hardness, but weaker adhesion strength were obtained for the DLC film synthesized using plasma immersion ion deposition of acetylene at a lower bias voltage or higher gas pressure.

  8. Laser-assisted direct joining of AISI304 stainless steel with polycarbonate sheets: Thermal analysis, mechanical characterization, and bonds morphology

    NASA Astrophysics Data System (ADS)

    Lambiase, F.; Genna, S.

    2017-02-01

    Laser-Assisted Metal and Plastic bonding (LAMP) of AISI304 sheets with polycarbonate sheets is investigated in this work. The process was performed by means of a high power diode laser with a maximum power of 200 W. The study introduces an integrated experimental approach aimed at understanding how the main process conditions (laser power and scanning speed) influence the direct-bonds quality, dimensions and presence of defects. To this end, the bonds dimension, shear strength, formation and dimension of bubbles in the bonded region were related to the temperature measurements and process parameters. According to the achieved results, the processing window that enables a good adhesion of the two materials is relatively small; this is due the activation of the adhesion phenomena that require overcoming an energy threshold. However, excessive energy levels reduce the bonds strength due to the increase in defects (bubbles) dimension that may combine (coalescence) leading to the formation of a central tunnel where the two substrates are completely detached.

  9. Comparative study of pulsed Nd:YAG laser welding of AISI 304 and AISI 316 stainless steels

    NASA Astrophysics Data System (ADS)

    Kumar, Nikhil; Mukherjee, Manidipto; Bandyopadhyay, Asish

    2017-02-01

    Laser welding is a potentially useful technique for joining two pieces of similar or dissimilar materials with high precision. In the present work, comparative studies on laser welding of similar metal of AISI 304SS and AISI 316SS have been conducted forming butt joints. A robotic control 600 W pulsed Nd:YAG laser source has been used for welding purpose. The effects of laser power, scanning speed and pulse width on the ultimate tensile strength and weld width have been investigated using the empirical models developed by RSM. The results of ANOVA indicate that the developed models predict the responses adequately within the limits of input parameters. 3-D response surface and contour plots have been developed to find out the combined effects of input parameters on responses. Furthermore, microstructural analysis as well as hardness and tensile behavior of the selected weld of 304SS and 316SS have been carried out to understand the metallurgical and mechanical behavior of the weld. The selection criteria are based on the maximum and minimum strength achieved by the respective weld. It has been observed that the current pulsation, base metal composition and variation in heat input have significant influence on controlling the microstructural constituents (i.e. phase fraction, grain size etc.). The result suggests that the low energy input pulsation generally produce fine grain structure and improved mechanical properties than the high energy input pulsation irrespective of base material composition. However, among the base materials, 304SS depict better microstructural and mechanical properties than the 316SS for a given parametric condition. Finally, desirability function analysis has been applied for multi-objective optimization for maximization of ultimate tensile strength and minimization of weld width simultaneously. Confirmatory tests have been conducted at optimum parametric conditions to validate the optimization techniques.

  10. Corrosion inhibition of stainless steel type AISI 304 by Mn coating and subsequent annealing with flow of nitrogen at different temperatures

    NASA Astrophysics Data System (ADS)

    Grayeli-Korpi, Ali-Reza; Savaloni, Hadi; Habibi, Maryam

    2013-07-01

    This work reports the enhancement of stainless steel corrosion resistance coated with Mn and post-annealed with flow of nitrogen at different annealing temperatures. Crystallographic variation of the samples by annealing temperature is studied by X-ray diffraction (XRD) while their surface morphology and surface roughness was obtained by means of atomic force microscope (AFM) and scanning electron microscope (SEM) analyses before and after corrosion test respectively. Elemental analysis of samples after corrosion test was investigated by energy dispersive spectroscope (EDS) analysis. The corrosion behaviour of the samples was evaluated by potentiodynamic polarization test in 0.6 M NaCl solution. A critical annealing temperature is found at which the highest corrosion resistance can be achieved. Correlation between corrosion resistance, structural and surface morphology results is obtained.

  11. Mechanical properties of cold-rolled AISI 304LN steel at low temperatures

    SciTech Connect

    Ilola, R.J.; Haenninen, H.E.; Heinaekari, M.J.

    1996-12-01

    Mechanical properties of 0--70% cold-rolled AISI 304LN steel (0, 16 wt.% N) were investigated by means of tensile and Charpy V-notch impact tests between room temperature and {minus}196 C. Fracture surfaces of the tested specimens were investigated using SEM (scanning electron microscope). Austenite stability against {alpha}{prime}-martensite formation during cooling and during deformation in cold-rolling and mechanical testing was determined using magnetic measurements.

  12. Metal objects mapping after small charge explosions. A study on AISI 304Cu steel with two different grain sizes.

    PubMed

    Firrao, Donato; Matteis, Paolo; Scavino, Giorgio; Ubertalli, Graziano; Ienco, Maria G; Pellati, Gabriella; Piccardo, Paolo; Pinasco, Maria R; Stagno, Enrica; Costanza, Girolamo; Montanari, Roberto; Tata, Maria E; Brandimarte, Giovanni; Petralia, Santo

    2006-05-01

    Evidence of exposure of a metal component to a small charge explosion can be detected by observing microstructural modifications; they may be present even if the piece does not show noticeable overall plastic deformations. Particularly, if an austenitic stainless steel (or another metal having a face-centered cubic structure and a low stacking fault energy) is exposed to an explosive shock wave, high-speed deformation induces primarily mechanical twinning, whereas, in nonexplosive events, a lower velocity plastic deformation first induces slip. The occurrence of mechanical twins can be detected even if the surface is damaged or oxidized in successive events. In the present research, optical metallography (OM) and scanning electron microscopy (SEM), and scanning tunneling microscopy (STM) were used to detect microstructural modifications caused on AISI 304Cu steel disks by small-charge explosions. Spherical charges of 54.5 or 109 g TNT equivalent mass were used at explosive-to-target distances from 6.5 to 81.5 cm, achieving peak pressures from 160 to 0.5 MPa. Explosions induced limited or no macro-deformation. Two alloy grain sizes were tested. Surface OM and SEM evidenced partial surface melting, zones with recrystallization phenomena, and intense mechanical twinning, which was also detected by STM and X-ray diffraction. In the samples' interior, only twins were seen, up to some distance from the explosion impinged surface and again, at the shortest charge-to-sample distances, in a thin layer around the reflecting surface. For forensic science locating purposes after explosions, the maximum charge-to-target distance at which the phenomena disappear was singled out for each charge or grain size and related to the critical resolved shear stress for twinning.

  13. Rutherford backscattering spectrometry (RBS) characterization of oxide scale formed on (AISI-304) steel after surface deposition of lanthanum

    SciTech Connect

    Ager, F.J.; Respaldiza, M.A.; Benitez, J.J.; Odriozola, J.A.; Botella, J.; Soares, J.C.; Silva, M.F. da

    1996-02-01

    Oxidized AISI-304 steel samples coated with lanthanum have been investigated by Rutherford backscattering spectrometry (RBS) in order to determine the composition profile of the oxide scale. In this sense, RBS technique has been revealed as a very reliable and nondestructive method for depth profile analysis. Lanthanum deposition, specially over preoxidized specimens, has proven to improve their resistance to high temperature oxidation. The formation of a LaCrO{sub 3} perovskite-like phase uniformly distributed along the oxide scale is proposed as being responsible for this behavior.

  14. Nickel release from stainless steels.

    PubMed

    Haudrechy, P; Mantout, B; Frappaz, A; Rousseau, D; Chabeau, G; Faure, M; Claudy, A

    1997-09-01

    In 1994, a study of nickel release and allergic contact dermatitis from nickel-plated metals and stainless steels was published in this journal. It was shown that low-sulfur stainless steel grades like AISI 304, 316L or 430 (S < or = 0.007%) release less than 0.03 microgram/cm2/week of nickel in acid artificial sweat and elicit no reactions in patients already sensitized to nickel. In contrast, nickel-plated samples release around 100 micrograms/cm2/week of Ni and high-sulfur stainless steel (AISI 303-S approximately 0.3%) releases about 1.5 micrograms/cm2/week in this acid artificial sweat. Applied on patients sensitized to nickel, these metals elicit positive reactions in 96% and 14%, respectively, of the patients. The main conclusion was that low-sulfur stainless steels like AISI 304, 316L or 430, even when containing Ni, should not elicit nickel contact dermatitis, while metals having a mean corrosion resistance like a high-sulfur stainless steel (AISI 303) or nickel-plated steel should be avoided. The determining characteristic was in fact the corrosion resistance in chloride media, which, for stainless steels, is connected, among other factors, to the sulfur content. Thus, a question remained concerning the grades with an intermediate sulfur content, around 0.03%, which were not studied. They are the object of the study presented in this paper. 3 tests were performed: leaching experiments, dimethylglyoxime and HNO3 spot tests, and clinical patch tests; however, only stainless steels were tested: a low-sulfur AISI 304 and AISI 303 as references and 3 grades with a sulfur content around 0.03%: AISI 304L, AISI 304L added with Ca, AISI 304L+Cu. Leaching experiments showed that the 4 non-resulfurised grades released less than 0.5 microgram/cm2/week in acid sweat while the reulfurized AISI 303 released around or more than 0.5 microgram/cm2/week. This is explained by the poorer corrosion resistance of the resulfurized grade. Yet all these grades had the same

  15. Mechanical behavior of AISI 304SS determined by miniature test methods after neutron irradiation to 28 dpa

    SciTech Connect

    Ellen M. Rabenberg; Brian J. Jaques; Bulent H. Sencer; Frank A. Garner; Paula D. Freyer; Taira Okita; Darryl P. Butt

    2014-05-01

    The mechanical properties of AISI 304 stainless steel irradiated for over a decade in the Experimental Breeder Reactor (EBR-II) were measured using miniature mechanical testing methods. The shear punch method was used to evaluate the shear strengths of the neutron-irradiated steel and a correlation factor was empirically determined to predict its tensile strength. The strength of the stainless steel slightly decreased with increasing irradiation temperature, and significantly increased with increasing dose until it saturated above approximately 5 dpa. Ferromagnetic measurements were used to observe and deduce the effects of the stress-induced austenite to martensite transformation as a result of shear punch testing.

  16. Erosion and Corrosion Behavior of Laser Cladded Stainless Steels with Tungsten Carbide

    NASA Astrophysics Data System (ADS)

    Singh, Raghuvir; Kumar, Mukesh; Kumar, Deepak; Mishra, Suman K.

    2012-11-01

    Laser cladding of tungsten carbide (WC) on stainless steels 13Cr-4Ni and AISI 304 substrates has been performed using high power diode laser. The cladded stainless steels were characterized for microstructural changes, hardness, solid particle erosion resistance and corrosion behavior. Resistance of the clad to solid particle erosion was evaluated using alumina particles according to ASTM G76 and corrosion behavior was studied by employing the anodic polarization and open circuit potential measurement in 3.5% NaCl solution and tap water. The hardness of laser cladded AISI 304 and 13Cr-4Ni stainless steel was increased up to 815 and 725Hv100 g, respectively. The erosion resistance of the modified surface was improved significantly such that the erosion rate of cladded AISI 304 (at 114 W/mm2) was observed ~0.74 mg/cm2/h as compared to ~1.16 and 0.97 mg/cm2/h for untreated AISI 304 and 13Cr-4Ni, respectively. Laser cladding of both the stainless steels, however, reduced the corrosion resistance in both NaCl and tap water.

  17. Effects of biofilm formation on the electrochemical behavior of AISI 304 SS in board machine environment

    SciTech Connect

    Carp, L.; Hakkarainen, T.; Raaska, L.

    1999-11-01

    The electrochemical behavior of and biofilm formation on AISI 304 stainless steel were studied in board machine environment with natural bacteria population. Open circuit potentials, redox-potential as well as different electrochemical measurements were performed. The biofilms formed were analyzed by microbial cultivation and by epifluorescence microscopy. The results of the measurements were compared with those performed both in sterilized white water and in artificial white water. The anodic polarization behavior of just immersed specimens was very similar in biotic (real), artificial and abiotic (sterilized) white water. Pitting initiated at very low potentials and continued to very negative values. The initiation of pitting became more difficult when the immersion time increased to 7 or 8 days in real, artificial or sterilized water. When the immersion time further increased, the pitting nucleated more easily in sterilized white water as well as in artificial white water than in biotic white water. In the laboratory equipment it was possible to maintain the biofilm already formed in the board mill, but the amount of sulfate reducing bacteria decreased and the amount of biofilm did not further increase. The composition and structure of the biofilm formed in laboratory differed from that formed in board mill conditions. The preliminary results indicate that the formation of biofilm in biotic white water rather inhibits than enhances the pitting corrosion of type AISI 304 stainless steel.

  18. Substitution for chromium in 304 stainless steel. [effects on oxidation and corrosion resistance

    NASA Technical Reports Server (NTRS)

    Stephens, J. R.; Barrett, C. A.

    1978-01-01

    An investigation was conducted to determine the effects of substituting less strategic elements for Cr on oxidation and corrosion resistance of AISI 304 stainless steel. Cyclic oxidation resistance was evaluated at 870 C. Corrosion resistance was determined by exposure of specimens to a boiling copper-rich solution of copper sulfate and sulfuric acid. Alloy substitutes for Cr included Al, Mn, Mo, Si, Ti, V, Y, and misch metal. A level of about 12% Cr was the minimum amount of Cr required for adequate oxidation and corrosion resistance in the modified composition 304 stainless steels. This represents a Cr saving of 33 percent. Two alloys containing 12% Cr plus 2% Al plus 2% Mo and 12% Cr plus 2.65% Si were identified which exhibited oxidation and corrosion resistance comparable to AISI 304 stainless steel.

  19. Nondestructive evaluation of stresses within AISI stainless steel 304 material -- A magnetometric approach

    SciTech Connect

    Manglik, V.K.; Vaghmare, R.; Modi, H.M.

    1995-12-31

    Stainless steel is widely used industrial material and also used in fabrication of satellite components. The use of optimum section of components calls for Non-Destructive Evaluation of structure to avoid catastrophic failures which are predominantly due to the high stress level. The effect of cold working and/or stress on the magnetic properties of stainless steel was discussed in the past. An attempt is made in present work to correlate the induced magnetic flux density in stainless steel AISI-304 with the stress level. In the present work, various samples of stainless steel were prepared for experiment after confirming the material belongs to AISI-304 by detailed chemical and physical analysis. These samples were also heat treated at 1,066 deg. C. to eliminate presence of initial stresses and obtain austenitic structure. Stresses in identical samples were generated by torsional deformation and induced magnetic flux density were measured in a very well configured test set up which has the resolution of 1 nT (nano-tesla). Finally, a correlation is presented between the induced magnetic flux density and stress level which could be very helpful tool in non-destructive evaluation of stresses in stainless steel AISI-304.

  20. Performance optimization of water-jet assisted underwater laser cutting of AISI 304 stainless steel sheet

    NASA Astrophysics Data System (ADS)

    Mullick, Suvradip; Madhukar, Yuvraj K.; Roy, Subhransu; Nath, Ashish K.

    2016-08-01

    Recent development of water-jet assisted underwater laser cutting has shown some advantages over the gas assisted underwater laser cutting, as it produces much less turbulence, gas bubble and aerosols, resulting in a more gentle process. However, this process has relatively low efficiency due to different losses in water. Scattering is reported to be a dominant loss mechanism, which depends on the growth of vapor layer at cut front and its removal by water-jet. Present study reports improvement in process efficiency by reducing the scattering loss using modulated laser power. Judicious control of laser pulse on- and off-time could improve process efficiency through restricting the vapor growth and its effective removal by water-jet within the laser on- and off-time, respectively. Effects of average laser power, duty cycle and modulation frequency on specific energy are studied to get an operating zone for maximum efficiency. Next, the variation in laser cut quality with different process parameters are studied within this operating zone using Design of experiment (DOE). Response surface methodology (RSM) is used by implementing three level Box-Behnken design to optimize the variation in cut quality, and to find out the optimal process parameters for desired quality. Various phenomena and material removal mechanism involved in this process are also discussed.

  1. Multiaxial fatigue criteria for AISI 304 and 2-1/4 Cr-1 Mo steel at 538/sup 0/C with applications to strain-range partitioning and linear summation of creep and fatigue damage

    SciTech Connect

    Blass, J.J.

    1982-01-01

    An improved multiaxial fatigue failure criterion was developed based on the results of combined axial-torsional strain cycling tests of AISI 304 and 2-1/4 Cr-1 Mo steel conducted at 538/sup 0/C (1000/sup 0/F). The formulation of this criterion involves the shear and normal components of inelastic strain range on the planes of maximum inelastic shear strain range. Optimum values of certain parameters contained in the formulation were obtained for each material by the method of least squares. The ability of this criterion to correlate the test results was compared with that of the usual (Mises) equivalent inelastic strain range criterion. An improved definition of equivalent inelastic strain range resulting from these considerations was used to generalize the theory of Strain Range Partitioning to multiaxial stress-strain conditions and was also applied to the linear summation of creep and fatigue damage.

  2. Ion-nitriding of austenitic stainless steels

    SciTech Connect

    Pacheco, O.; Hertz, D.; Lebrun, J.P.; Michel, H.

    1995-12-31

    Although ion-nitriding is an extensively industrialized process enabling steel surfaces to be hardened by nitrogen diffusion, with a resulting increase in wear, seizure and fatigue resistance, its direct application to stainless steels, while enhancing their mechanical properties, also causes a marked degradation in their oxidation resistance. However, by adaption of the nitriding process, it is possible to maintain the improved wear resistant properties while retaining the oxidation resistance of the stainless steel. The controlled diffusion permits the growth of a nitrogen supersaturated austenite layer on parts made of stainless steel (AISI 304L and 316L) without chromium nitride precipitation. The diffusion layer remains stable during post heat treatments up to 650 F for 5,000 hrs and maintains a hardness of 900 HV. A very low and stable friction coefficient is achieved which provides good wear resistance against stainless steels under diverse conditions. Electrochemical and chemical tests in various media confirm the preservation of the stainless steel characteristics. An example of the application of this process is the treatment of Reactor Control Rod Cluster Assemblies (RCCAs) for Pressurized Water Nuclear Reactors.

  3. Enhancement of Stainless Steel's Mechanical Properties via Carburizing Process

    NASA Astrophysics Data System (ADS)

    Ahmad, S.; Alias, S. K.; Abdullah, B.; Hafiz Mohd Bakri, Mohd.; Hafizuddin Jumadin, Muhammad; Mat Shah, Muhammad Amir

    2016-11-01

    Carburizing process is a method to disperse carbon into the steel surface in order to enhance its mechanical properties such as hardness and wear resistance. This paper study investigates the effect of carburizing temperature to the carbon dispersion layer in stainless steel. The standard AISI 304 stainless steel was carburized in two different temperatures which were 900°C and 950°C. The effect of carbon dispersion layers were observed and the results indicated that the increasing value of the average dispersion layer from 1.30 mm to 2.74 mm thickness was found to be related to increment of carburizing holding temperature . The increment of carbon thickness layer also resulted in improvement of hardness and tensile strength of carburized stainless steel.

  4. The Use of Austenitic Stainless Steel versus Monel (Ni-Cu) Alloy in Pressurized Gaseous Oxygen (GOX) Life Support Systems.

    DTIC Science & Technology

    1985-03-01

    micron 2219 Aluminum particles as the projectiles. Monel proved superior as Porter was unable to ignite Monel, but was able to icnite AISI 304L CRES with...800 micron 2219 Aluminum particles in the high velocity test appratus (see Figure 3.10). 2. Friction Tribology has been studied as a method of...Monel 400 Copper 102 Aluminum 6061- T6 1015 Carbon Steel Inconel 600 Hastelloy X Inconel718 440C Stainless Steel 17-4 PH Stainless Steel Invar 36 Brass 360

  5. Nickel release from nickel-plated metals and stainless steels.

    PubMed

    Haudrechy, P; Foussereau, J; Mantout, B; Baroux, B

    1994-10-01

    Nickel release from nickel-plated metals often induces allergic contact dermatitis, but, for nickel-containing stainless steels, the effect is not well-known. In this paper, AISI 304, 316L, 303 and 430 type stainless steels, nickel and nickel-plated materials were investigated. 4 tests were performed: patch tests, leaching experiments, dimethylglyoxime (DMG) spot tests and electrochemical tests. Patch tests showed that 96% of the patients were intolerant to Ni-plated samples, and 14% to a high-sulfur stainless steel (303), while nickel-containing stainless steels with a low sulfur content elicited no reactions. Leaching experiments confirmed the patch tests: in acidic artificial sweat, Ni-plated samples released about 100 micrograms/cm2/week of nickel, while low-sulfur stainless steels released less than 0.03 microgram/cm2/week of nickel, and AISI 303 about 1.5 micrograms/cm2/week. Attention is drawn to the irrelevance of the DMG spot test, which reveals Ni present in the metal bulk but not its dissolution rate. Electrochemical experiments showed that 304 and 316 grades remain passive in the environments tested, while Ni-plated steels and AISI 303 can suffer significant cation dissolution. Thus, Ni-containing 304 and 316 steels should not induce contact dermatitis, while 303 should be avoided. A reliable nitric acid spot test is proposed to distinguish this grade from other stainless steels.

  6. Correlation Between Shear Punch and Tensile Strength for Low-Carbon Steel and Stainless Steel Sheets

    NASA Astrophysics Data System (ADS)

    Mahmudi, R.; Sadeghi, M.

    2013-02-01

    The deformation behavior of AISI 1015 low-carbon steel, and AISI 304 stainless steel sheets was investigated by uniaxial tension and the shear punch test (SPT). Both materials were cold rolled to an 80% thickness reduction and subsequently annealed in the temperature range 25-850 °C to produce a wide range of yield and ultimate strength levels. The correlations between shear punch and tensile yield and ultimate stresses were established empirically. Different linear relationships having different slopes and intercepts were found for the low-carbon and stainless steel sheets, and the possible parameters affecting the correlation were discussed. It was shown that, within limits, yield and tensile strength of thin steel sheets can be predicted from the shear data obtained by the easy-to-perform SPT.

  7. Analysis of the elements sputtered during the lanthanum implantation in stainless steels

    NASA Astrophysics Data System (ADS)

    Ager, F. J.; Respaldiza, M. A.; Paúl, A.; Odriozola, J. A.; Lobato, J. M.; da Silva, M. F.; Redondo, L. M.; Soares, J. C.

    1998-04-01

    The evidence of the modification of the surface structure of the AISI-304 stainless steel during the implantation of lanthanum makes the analysis of the sputtered elements very interesting. Those sputtered elements are deposited on a carbon sheet placed in front of the steel being implanted, and studied by means of RBS and PIXE, together with the implanted specimens. Besides, the protective effect of the implanted ions during the high temperature oxidation is also studied by those techniques together with XRD and thermogravimetric methods.

  8. Tailoring plasticity of austenitic stainless steels for nuclear applications: Review of mechanisms controlling plasticity of austenitic steels below 400 °C

    NASA Astrophysics Data System (ADS)

    Meric de Bellefon, G.; van Duysen, J. C.

    2016-07-01

    AISI 304 and 316 austenitic stainless steels were invented in the early 1900s and are still trusted by materials and mechanical engineers in numerous sectors because of their good combination of strength, ductility, and corrosion resistance, and thanks to decades of experience and data. This article is part of an effort focusing on tailoring the plasticity of both types of steels to nuclear applications. It provides a synthetic and comprehensive review of the plasticity mechanisms in austenitic steels during tensile tests below 400 °C. In particular, formation of twins, extended stacking faults, and martensite, as well as irradiation effects and grain rotation are discussed in details.

  9. Some Temperature Effects on AISI-304 Nitriding in an Inductively Coupled RF Plasma

    SciTech Connect

    Valencia-Alvarado, R.; Barocio, S. R.; Mercado-Cabrera, A.; Pena-Eguiluz, R.; Munoz-Castro, A. E.; Piedad-Beneitez, A. de la; Rosa-Vazquez, J. de la; Lopez-Callejas, R.; Godoy-Cabrera, O. G.

    2006-12-04

    Some recent results obtained from nitriding AISI 304 stainless steel samples, 1.2 cm in diameter and 0.5 cm thick are reported here in the case of an 85% hydrogen and 15% nitrogen mixture work gas. The process was carried out from 300 to 400 W for (13.56 MHz) inductively coupled plasma within a 60 cm long pyrex glass tube 3.5 cm in diameter where the samples were biased up to -300 V with respect to earth. The resulting hardness appears to be a function of the substrate temperature which varied from 200 deg. C at a 0 V bias to 550 deg. C at -300 V. The plasma density at 400 W reached 3x1010 cm-3 with a 4 eV electron temperature. Prior to nitriding, all the samples were polished with 0.05 {mu}m diamond paste, leading to a 30 nm average roughness (Ra). After nitriding at -300 V, the Ra rose until {approx}400 nm while hardness values of 1500 HV under 300 g loads were measured. X ray diffraction indicates that the extended phase amplitude ({gamma}N), Fe and Cr nitride depends on the substrate temperature.

  10. On the Electrochemical Behavior of PVD Ti-Coated AISI 304 Stainless Steel in Borate Buffer Solution

    NASA Astrophysics Data System (ADS)

    Fattah-alhosseini, Arash; Elmkhah, Hassan; Attarzadeh, Farid Reza

    2017-03-01

    This work aims at studying the electrochemical behavior of annealed pure titanium (Ti) and nano-structured (NS) Ti coating in borate buffer solutions. Cathodic arc evaporation was successfully applied to deposit NS Ti coating. Samples were characterized by means of scanning electron microscope and x-ray diffraction. Potentiodynamic polarization tests, electrochemical impedance spectroscopy, and Mott-Schottky analysis were employed to discuss the electrochemical behavior of samples thoroughly. Electrochemical measurements showed that the deposited NS Ti coating offers a superior passivity in borate buffer solutions of pH 9.0 and 9.5. Mott-Schottky analysis revealed that all passive films are of n-type semiconducting nature in these alkaline solutions and the deposition process did not alter the semiconducting type of passive films formed on samples. Additionally, this analysis showed that the NS Ti coating possessed lower levels of donor densities. Finally, all electrochemical tests showed that passive behavior of the NS Ti samples was superior, mainly due to the formation of thicker and less defective passive films.

  11. Deformation localization and dislocation channel dynamics in neutron-irradiated austenitic stainless steels

    SciTech Connect

    Gussev, Maxim N.; Field, Kevin G.; Busby, Jeremy T.

    2015-02-24

    We investigated dynamics of deformation localization and dislocation channel formation in situ in a neutron irradiated AISI 304 austenitic stainless steel and a model 304-based austenitic alloy by combining several analytical techniques including optic microscopy and laser confocal microscopy, scanning electron microscopy, electron backscatter diffraction and transmission electron microscopy. Channel formation was observed at 70% of the formal tensile yield stress for both alloys. It was shown that triple junction points do not always serve as a source of dislocation channels; at stress levels below the yield stress, channels often formed near the middle of the grain boundary. For a single grain, the role of elastic stiffness value (Young modulus) in the channel formation was analyzed; it was shown that in the irradiated 304 steels the initial channels appeared in soft grains with a high Schmid factor located near stiff grains with high elastic stiffness. Moreover, the spatial organization of channels in a single grain was analyzed; it was shown that secondary channels operating in the same slip plane as primary channels often appeared at the middle or at one third of the way between primary channels. The twinning nature of dislocation channels was analyzed for grains of different orientation using TEM. Finally, it was shown that in the AISI 304 steel, channels were twin-free in grains oriented close to [001] and [101] of standard unit triangle; [111]-grains and grains oriented close to Schmid factor maximum contained deformation twins.

  12. Deformation localization and dislocation channel dynamics in neutron-irradiated austenitic stainless steels

    DOE PAGES

    Gussev, Maxim N.; Field, Kevin G.; Busby, Jeremy T.

    2015-02-24

    We investigated dynamics of deformation localization and dislocation channel formation in situ in a neutron irradiated AISI 304 austenitic stainless steel and a model 304-based austenitic alloy by combining several analytical techniques including optic microscopy and laser confocal microscopy, scanning electron microscopy, electron backscatter diffraction and transmission electron microscopy. Channel formation was observed at 70% of the formal tensile yield stress for both alloys. It was shown that triple junction points do not always serve as a source of dislocation channels; at stress levels below the yield stress, channels often formed near the middle of the grain boundary. For amore » single grain, the role of elastic stiffness value (Young modulus) in the channel formation was analyzed; it was shown that in the irradiated 304 steels the initial channels appeared in soft grains with a high Schmid factor located near stiff grains with high elastic stiffness. Moreover, the spatial organization of channels in a single grain was analyzed; it was shown that secondary channels operating in the same slip plane as primary channels often appeared at the middle or at one third of the way between primary channels. The twinning nature of dislocation channels was analyzed for grains of different orientation using TEM. Finally, it was shown that in the AISI 304 steel, channels were twin-free in grains oriented close to [001] and [101] of standard unit triangle; [111]-grains and grains oriented close to Schmid factor maximum contained deformation twins.« less

  13. Corrosion Performance of Stainless Steels in a Simulated Launch Environment

    NASA Technical Reports Server (NTRS)

    Calle, Luz Marina; Vinje, Rubiela D.; MacDowell, Louis

    2004-01-01

    At the Kennedy Space Center, NASA relies on stainless steel (SS) tubing to supply the gases and fluids required to launch the Space Shuttle. 300 series SS tubing has been used for decades but the highly corrosive environment at the launch pad has proven to be detrimental to these alloys. An upgrade with higher alloy content materials has become necessary in order to provide a safer and long lasting launch facility. In the effort to find the most suitable material to replace the existing AISI 304L SS ([iNS S30403) and AISI 316L SS (UNS S31603) shuttle tubing, a study involving atmospheric exposure at the corrosion test site near the launch pads and electrochemical measurements is being conducted. This paper presents the results of an investigation in which stainless steels of the 300 series, 304L, 316L, and AISI 317L SS (UNS S31703) as well as highly alloyed stainless steels 254-SMO (UNS S32154), AL-6XN (N08367) and AL29-4C ([iNS S44735) were evaluated using direct current (DC) electrochemical techniques under conditions designed to simulate those found at the Space Shuttle Launch pad. The electrochemical results were compared to the atmospheric exposure data and evaluated for their ability to predict the long-term corrosion performance of the alloys.

  14. Oxidation and corrosion behavior of modified-composition, low-chromium 304 stainless steel alloys

    NASA Technical Reports Server (NTRS)

    Stephens, J. R.; Barrett, C. A.

    1977-01-01

    The effects of substituting less strategic elements than Cr on the oxidation and corrosion resistance of AISI 304 stainless steel were investigated. Cyclic oxidation resistance was evaluated at 870 C. Corrosion resistance was determined by exposure of specimens to a boiling copper-rich solution of copper sulfate and sulfuric acid. Alloy substitutes for Cr included Al, Mn, Mo, Si, Ti, V, Y, and misch metal. A level of about 12% Cr was the minimum amount of Cr required for adequate oxidation and corrosion resistance in the modified composition 304 stainless steels. This represents a Cr saving of at least 33%. Two alloys containing 12% Cr and 2% Al plus 2% Mo and 12% Cr plus 2.65% Si were identified as most promising for more detailed evaluation.

  15. Supertough Stainless Bearing Steel

    NASA Technical Reports Server (NTRS)

    Olson, Gregory B.

    1995-01-01

    Composition and processing of supertough stainless bearing steel designed with help of computer-aided thermodynamic modeling. Fracture toughness and hardness of steel exceeds those of other bearing steels like 440C stainless bearing steel. Developed for service in fuel and oxidizer turbopumps on Space Shuttle main engine. Because of strength and toughness, also proves useful in other applications like gears and surgical knives.

  16. Biofilm formation by Listeria monocytogenes on stainless steel surface and biotransfer potential

    PubMed Central

    de Oliveira, Maíra Maciel Mattos; Brugnera, Danilo Florisvaldo; Alves, Eduardo; Piccoli, Roberta Hilsdorf

    2010-01-01

    An experimental model was proposed to study biofilm formation by Listeria monocytogenes ATCC 19117 on AISI 304 (#4) stainless steel surface and biotransfer potential during this process. In this model, biofilm formation was conducted on the surface of stainless steel coupons, set on a stainless steel base with 4 divisions, each one supporting 21 coupons. Trypic Soy Broth was used as bacterial growth substrate, with incubation at 37 °C and stirring of 50 rpm. The number of adhered cells was determined after 3, 48, 96, 144, 192 and 240 hours of biofilm formation and biotransfer potential from 96 hours. Stainless steel coupons were submitted to Scanning Electron Microscopy (SEM) after 3, 144 and 240 hours. Based on the number of adhered cells and SEM, it was observed that L. monocytogenes adhered rapidly to the stainless steel surface, with mature biofilm being formed after 240 hours. The biotransfer potential of bacterium to substrate occurred at all the stages analyzed. The rapid capacity of adhesion to surface, combined with biotransfer potential throughout the biofilm formation stages, make L. monocytogenes a potential risk to the food industry. Both the experimental model developed and the methodology used were efficient in the study of biofilm formation by L. monocytogenes on stainless steel surface and biotransfer potential. PMID:24031469

  17. Welding irradiated stainless steel

    SciTech Connect

    Kanne, W.R. Jr.; Chandler, G.T.; Nelson, D.Z.; Franco-Ferreira, E.A.

    1993-12-31

    Conventional welding processes produced severe underbead cracking in irradiated stainless steel containing 1 to 33 appm helium from n,a reactions. A shallow penetration overlay technique was successfully demonstrated for welding irradiated stainless steel. The technique was applied to irradiated 304 stainless steel that contained 10 appm helium. Surface cracking, present in conventional welds made on the same steel at the same and lower helium concentrations, was eliminated. Underbead cracking was minimal compared to conventional welding methods. However, cracking in the irradiated material was greater than in tritium charged and aged material at the same helium concentrations. The overlay technique provides a potential method for repair or modification of irradiated reactor materials.

  18. Surface-protein interactions on different stainless steel grades: effects of protein adsorption, surface changes and metal release.

    PubMed

    Hedberg, Y; Wang, X; Hedberg, J; Lundin, M; Blomberg, E; Wallinder, I Odnevall

    2013-04-01

    Implantation using stainless steels (SS) is an example where an understanding of protein-induced metal release from SS is important when assessing potential toxicological risks. Here, the protein-induced metal release was investigated for austenitic (AISI 304, 310, and 316L), ferritic (AISI 430), and duplex (AISI 2205) grades in a phosphate buffered saline (PBS, pH 7.4) solution containing either bovine serum albumin (BSA) or lysozyme (LSZ). The results show that both BSA and LSZ induce a significant enrichment of chromium in the surface oxide of all stainless steel grades. Both proteins induced an enhanced extent of released iron, chromium, nickel and manganese, very significant in the case of BSA (up to 40-fold increase), whereas both proteins reduced the corrosion resistance of SS, with the reverse situation for iron metal (reduced corrosion rates and reduced metal release in the presence of proteins). A full monolayer coverage is necessary to induce the effects observed.

  19. Surface temperature distribution of GTA weld pools on thin-plate 304 stainless steel

    SciTech Connect

    Zacharia, T.; David, S.A.; Vitek, J.M.; Kraus, H.G.

    1995-11-01

    A transient multidimensional computational model was utilized to study gas tungsten arc (GTA) welding of thin-plate 304 stainless steel (SS). The model eliminates several of the earlier restrictive assumptions including temperature-independent thermal-physical properties. Consequently, all important thermal-physical properties were considered as temperature dependent throughout the range of temperatures experienced by the weld metal. The computational model was used to predict surface temperature distribution of the GTA weld pools in 1.5-mm-thick AISI 304 SS. The welding parameters were chosen so as to correspond with an earlier experimental study that produced high-resolution surface temperature maps. One of the motivations of the present study was to verify the predictive capability of the computational model. Comparison of the numerical predictions and experimental observations indicate excellent agreement, thereby verifying the model.

  20. Upset Resistance Welding of Carbon Steel to Austenitic Stainless Steel Narrow Rods

    NASA Astrophysics Data System (ADS)

    Ozlati, Ashkaan; Movahedi, Mojtaba; Mohammadkamal, Helia

    2016-11-01

    Effects of welding current (at the range of 2-4 kA) on the microstructure and mechanical properties of upset resistance welds of AISI-1035 carbon steel to AISI-304L austenitic stainless steel rods were investigated. The results showed that the joint strength first increased by raising the welding current up to 3 kA and then decreased beyond it. Increasing trend was related to more plastic deformation, accelerated diffusion, reduction of defects and formation of mechanical locks at the joint interface. For currents more than 3 kA, decrease in the joint strength was mainly caused by formation of hot spots. Using the optimum welding current of 3 kA, tensile strength of the joint reached to 76% of the carbon steel base metal strength. Microstructural observations and microhardness results confirmed that there was no hard phase, i.e., martensite or bainite, at the weld zone. Moreover, a fully austenitic transition layer related to carbon diffusion from carbon steel was observed at the weld interface.

  1. Gas-phase hydrogen permeation through alpha iron, 4130 steel, and 304 stainless steel from less than 100 C to near 600 C

    NASA Technical Reports Server (NTRS)

    Nelson, H. G.; Stein, J. E.

    1973-01-01

    Gas phase hydrogen permeation studies were conducted on hollow, cylindrical membranes of triply zone-refined alpha iron, AISI 304 austenitic stainless steel, and AISI-SAE 4130 steel in both the normalized (ferrite and carbide) and quenched and tempered (martensite) conditions. Membrane temperature was varied from less than 100 C to near 600 C and hydrogen pressure was varied. For one membrane material, normalized 4130 steel, gas phase hydrogen transport under both steady state and nonsteady state conditions was demonstrated to be controlled by lattice diffusion. Additionally, Sievert's law was shown to be applicable. For all membrane materials, expressions for the coefficients for hydrogen permeation were determined by analysis of steady state transport; the coefficients for diffusion were determined by the lag time technique applied to nonsteady state transport; and through a knowledge of the Sievert's constants, the subsurface equilibrium lattice hydrogen concentrations were determined.

  2. Deterioration in Fracture Toughness of 304LN Austenitic Stainless Steel Due to Sensitization

    NASA Astrophysics Data System (ADS)

    Ghosh, Swati; Kain, V.; Ray, A.; Roy, H.; Sivaprasad, S.; Tarafder, S.; Ray, K. K.

    2009-12-01

    The aim of this report is to examine the influence of sensitization on the mechanical properties of AISI grade 304LN stainless steel with special emphasis on its fracture toughness. A series of stainless steel samples has been sensitized by holding at 1023 K for different time periods ranging from 1 to 100 hours followed by water quenching. The degree of sensitization (DOS) for each type of the varyingly heat-treated samples has been measured by an electrochemical potentiodynamic reactivation (EPR) test. The microstructures of these samples have been characterized by optical metallography, scanning electron microscopy, transmission electron microscopy (TEM), and X-ray diffraction (XRD) analyses, together with measurements of their hardness and tensile properties. The fracture toughness of the samples has been measured by the ball indentation (BI) technique and the results are validated by conducting conventional J-integral tests. It is revealed for the first time that the fracture toughness and ductility of AISI 304LN stainless steel deteriorate significantly with increased DOS, while the tensile strength (TS) values remain almost unaltered. The results have been critically discussed in terms of the depletion of solid solution strengtheners, the nature of the grain boundary precipitations, and the strain-induced martensite formation with the increasing DOS of the 304LN stainless steel.

  3. Low-Temperature Nitriding of Deformed Austenitic Stainless Steels with Various Nitrogen Contents Obtained by Prior High-Temperature Solution Nitriding

    NASA Astrophysics Data System (ADS)

    Bottoli, Federico; Winther, Grethe; Christiansen, Thomas L.; Dahl, Kristian Vinter; Somers, Marcel A. J.

    2016-08-01

    In the past decades, high nitrogen steels (HNS) have been regarded as substitutes for conventional austenitic stainless steels because of their superior mechanical and corrosion properties. However, the main limitation to their wider application is their expensive production process. As an alternative, high-temperature solution nitriding has been applied to produce HNS from three commercially available stainless steel grades (AISI 304L, AISI 316, and EN 1.4369). The nitrogen content in each steel alloy is varied and its influence on the mechanical properties and the stability of the austenite investigated. Both hardness and yield stress increase and the alloys remain ductile. In addition, strain-induced transformation of austenite to martensite is suppressed, which is beneficial for subsequent low-temperature nitriding of the surface of deformed alloys. The combination of high- and low-temperature nitriding results in improved properties of both bulk and surface.

  4. Articles comprising ferritic stainless steels

    SciTech Connect

    Rakowski, James M.

    2016-06-28

    An article of manufacture comprises a ferritic stainless steel that includes a near-surface region depleted of silicon relative to a remainder of the ferritic stainless steel. The article has a reduced tendency to form an electrically resistive silica layer including silicon derived from the steel when the article is subjected to high temperature oxidizing conditions. The ferritic stainless steel is selected from the group comprising AISI Type 430 stainless steel, AISI Type 439 stainless steel, AISI Type 441 stainless steel, AISI Type 444 stainless steel, and E-BRITE.RTM. alloy, also known as UNS 44627 stainless steel. In certain embodiments, the article of manufacture is a fuel cell interconnect for a solid oxide fuel cell.

  5. Stainless steel tanks

    SciTech Connect

    Hagen, T.

    1995-12-31

    There is currently no recognized code or standard for the design, fabrication and construction of atmospheric and low pressure stainless steel tanks. At the present time these tanks are being designed to individual specifications, manufacturers standards or utilizing other codes and standards that may not be entirely applicable. Recognizing the need, the American Petroleum Institute will be publishing a new appendix to the API STD 650 Standard which will cover stainless steel tanks. The new Appendix was put together by a Task Group of selected individuals from the API Subcommittee of Pressure Vessels and Tanks from the Committee on Refinery Equipment. This paper deals with the development and basis of the new appendix. The new appendix will provide a much needed standard to cover the material, design, fabrication, erection and testing requirements for vertical, cylindrical, austenitic stainless steel aboveground tanks in nonrefrigerated service.

  6. Intergranular Corrosion Behavior of Low-Nickel and 304 Austenitic Stainless Steels

    NASA Astrophysics Data System (ADS)

    Bansod, Ankur V.; Patil, Awanikumar P.; Moon, Abhijeet P.; Khobragade, Nilay N.

    2016-09-01

    Intergranular corrosion (IGC) susceptibility for Cr-Mn austenitic stainless steel and 304 austenitic stainless steel (ASS) was estimated using electrochemical techniques. Optical and SEM microscopy studies were carried out to investigate the nature of IGC at 700 °C with increasing time (15, 30, 60, 180, 360, 720, 1440 min) according to ASTM standard 262 A. Quantitative analysis was performed to estimate the degree of sensitization (DOS) using double loop electrochemical potentiokinetic reactivation (DLEPR) and EIS technique. DLEPR results indicated that with the increase in thermal aging duration, DOS becomes more severe for both types of stainless steel. The DOS for Cr-Mn ASS was found to be higher (65.12% for 1440 min) than that of the AISI 304 ASS (23% for 1440 min). The higher degree of sensitization resulted in lowering of electrical charge capacitance resistance. Chronoamperometry studies were carried out at a passive potential of 0.4 V versus SCE and was observed to have a higher anodic dissolution of the passive film of Cr-Mn ASS. EDS studies show the formation of chromium carbide precipitates in the vicinity of the grain boundary. The higher Mn content was also observed for Cr-Mn ASS at the grain boundary.

  7. Effect of prior cold work on intergranular and transgranular corrosion in type 304 stainless steels: Quantitative discrimination by image analysis

    SciTech Connect

    Garcia, C.; Martin, F.; De Tiedra, P.; Heredero, J.A.; Aparicio, M.L.

    2000-03-01

    Stainless steel (AISI 304 [UNS S30400]) was evaluated as a function of prior cold work and several thermal sensitization treatments. Traditional experimental techniques such as ASTM A262, practice A; modified Strauss test; electrochemical potentiokinetic reactivation (EPR); and electrochemical potentiokinetic reactivation double-loop (EPRDL) were used. Microstructural studies also were conducted. Analysis of the results showed the presence of transgranular attack (TGA) and intergranular attack (IGA) and a transition phenomenon between them. The IGA and TBA contributions to this transition phenomenon were analyzed and quantified by a new procedure based on quantitative metallography performed by image analysis. Using this new methodology, it was possible to determine the most dangerous degrees of deformation for the development of intergranular corrosion (IGC), transgranular corrosion (TGC), intergranular stress corrosion cracking (IGSCC), and transgranular stress corrosion cracking (TGSCC) for different sensitization conditions.

  8. Antibacterial silver nanocluster/silica composite coatings on stainless steel

    NASA Astrophysics Data System (ADS)

    Ferraris, M.; Perero, S.; Ferraris, S.; Miola, M.; Vernè, E.; Skoglund, S.; Blomberg, E.; Odnevall Wallinder, I.

    2017-02-01

    A coating made of silver nanocluster/silica composites has been deposited, via a radio frequency (RF) co-sputtering technique, for the first time onto stainless steel (AISI 304L) with the aim to improve its antibacterial properties. Different thermal treatments after coating deposition have been applied in order to optimize the coating adhesion, cohesion and its antibacterial properties. Its applicability has been investigated at realistic conditions in a cheese production plant. The physico-chemical characteristics of the coatings have been analyzed by means of different bulk and surface analytical techniques. Field emission scanning electron microscopy (FESEM), X-ray Photoelectron Spectroscopy (XPS), contact angle measurements and atomic force microscopy (AFM) were employed to assess coating morphology, composition, surface roughness, wetting properties, size and local distribution of the nanoparticles within the coating. Tape tests were used to determine the adhesion/cohesion properties of the coating. The amount and time-dependence of released silver in solutions of acetic acid, artificial water, artificial tap water and artificial milk were determined by means of Atomic Absorption Spectroscopy (AAS). The antibacterial effect of the coating was evaluated at different experimental conditions using a standard bacterial strain of Staphylococcus aureus in compliance with National Committee for Clinical Laboratory Standards (NCCLS) and AATCC 147 standards. The Ahearn test was performed to measure the adhesion of bacteria to the coated stainless steel surface compared with a control surface. The antibacterial coating retained its antibacterial activity after thermal treatment up to 450 °C and after soaking in common cleaning products for stainless steel surfaces used for e.g. food applications. The antibacterial capacity of the coating remained at high levels for 1-5 days, and showed a good capacity to reduce the adhesion of bacteria up to 30 days. Only a few

  9. Adsorption and protein-induced metal release from chromium metal and stainless steel.

    PubMed

    Lundin, M; Hedberg, Y; Jiang, T; Herting, G; Wang, X; Thormann, E; Blomberg, E; Wallinder, I Odnevall

    2012-01-15

    A research effort is undertaken to understand the mechanism of metal release from, e.g., inhaled metal particles or metal implants in the presence of proteins. The effect of protein adsorption on the metal release process from oxidized chromium metal surfaces and stainless steel surfaces was therefore examined by quartz crystal microbalance with energy dissipation monitoring (QCM-D) and graphite furnace atomic absorption spectroscopy (GFAAS). Differently charged and sized proteins, relevant for the inhalation and dermal exposure route were chosen including human and bovine serum albumin (HSA, BSA), mucin (BSM), and lysozyme (LYS). The results show that all proteins have high affinities for chromium and stainless steel (AISI 316) when deposited from solutions at pH 4 and at pH 7.4 where the protein adsorbed amount was very similar. Adsorption of albumin and mucin was substantially higher at pH 4 compared to pH 7.4 with approximately monolayer coverage at pH 7.4, whereas lysozyme adsorbed in multilayers at both investigated pH. The protein-surface interaction was strong since proteins were irreversibly adsorbed with respect to rinsing. Due to the passive nature of chromium and stainless steel (AISI 316) surfaces, very low metal release concentrations from the QCM metal surfaces in the presence of proteins were obtained on the time scale of the adsorption experiment. Therefore, metal release studies from massive metal sheets in contact with protein solutions were carried out in parallel. The presence of proteins increased the extent of metals released for chromium metal and stainless steel grades of different microstructure and alloy content, all with passive chromium(III)-rich surface oxides, such as QCM (AISI 316), ferritic (AISI 430), austentic (AISI 304, 316L), and duplex (LDX 2205).

  10. A technique for brazing graphite/graphite and stainless steel/high-carbon steel joints

    SciTech Connect

    Ohmura, H.; Kawashiri, K. . Dept. of Metals and Inorganic Materials); Yoshida, T. . Vehicle Machine Engineering Dept.); Yoshimoto, O. . Quality Control Dept.)

    1994-10-01

    A new brazing technique for joining graphite to itself or to metals such as Mo, W, or Cu, with conventional brazing filler metals has been developed. Essentially, it is impossible to braze graphite with Cu filler metal because no wetting occurs. However, when a graphite base material is combined with an Fe base metal in Cu brazing, the Fe base metal dissolves in molten Cu. Simultaneously, the dissolved Fe grows as part of a columnar Fe-9 [approximately] 6Cu-1.6C alloy phase at the graphite interface at a constant brazing temperature, that is, the dissolution and deposit of base metal takes place. By placing an Fe foil insert between both graphite base materials, therefore, the columnar phase is formed at both graphite faces and grows toward the Fe foil during heating. As a result, both graphite base materials are united by the columnar phase through the Fe foil. In the same way, a graphite/Mo or /W joint can be produced. Moreover, when using BAu-1, which has a lower melting point than that of BCu-1, it is also possible to braze graphite to Cu. The shear strength of a graphite/graphite joint with a 0.12-mm thick Fe foil at room temperature was about 32 MPa. Further, the bending strength of the graphite/graphite and /Cu joints at 873 K (1,112 F), as measured using the four-point bending test, was 35 and 11 MPa, respectively. In addition, the technique can be applied to the brazing of AISI 304 stainless steel to high-C steel with BCu-1 where, normally, Cr[sub 23]C[sub 6] and Cr[sub 7]C[sub 3] layers are formed at the high-C steel braze interface; these carbide layers result in the loss of mechanical properties of the joint.

  11. Photocatalytic activity of ferric oxide/titanium dioxide nanocomposite films on stainless steel fabricated by anodization and ion implantation

    NASA Astrophysics Data System (ADS)

    Zhan, Wei-ting; Ni, Hong-wei; Chen, Rong-sheng; Yue, Gao; Tai, Jun-kai; Wang, Zi-yang

    2013-08-01

    A simple surface treatment was used to develop photocatalytic activity for stainless steel. AISI 304 stainless steel specimens after anodization were implanted by Ti ions at an extracting voltage of 50 kV with an implantation dose of 3 × 1015 atoms·cm-2 and then annealed in air at 450°C for 2 h. The morphology was observed by scanning electron microscopy. The microstructure was characterized by X-ray diffraction and X-ray photoelectron spectroscopy. The photocatalytic degradation of methylene blue solution was carried out under ultraviolet light. The corrosion resistance of the stainless steel was evaluated in NaCl solution (3.5 wt%) by electrochemical polarization curves. It is found that the Ti ions depth profile resembles a Gaussian distribution in the implanted layer. The nanostructured Fe2O3/TiO2 composite film exhibits a remarkable enhancement in photocatalytic activity referenced to the mechanically polished specimen and anodized specimen. Meanwhile, the annealed Ti-implanted specimen remains good corrosion resistance.

  12. Stainless Steel Permeability

    SciTech Connect

    Buchenauer, Dean A.; Karnesky, Richard A.

    2015-09-01

    An understanding of the behavior of hydrogen isotopes in materials is critical to predicting tritium transport in structural metals (at high pressure), estimating tritium losses during production (fission environment), and predicting in-vessel inventory for future fusion devices (plasma driven permeation). Current models often assume equilibrium diffusivity and solubility for a class of materials (e.g. stainless steels or aluminum alloys), neglecting trapping effects or, at best, considering a single population of trapping sites. Permeation and trapping studies of the particular castings and forgings enable greater confidence and reduced margins in the models. For FY15, we have continued our investigation of the role of ferrite in permeation for steels of interest to GTS, through measurements of the duplex steel 2507. We also initiated an investigation of the permeability in work hardened materials, to follow up on earlier observations of unusual permeability in a particular region of 304L forgings. Samples were prepared and characterized for ferrite content and coated with palladium to prevent oxidation. Issues with the poor reproducibility of measurements at low permeability were overcome, although the techniques in use are tedious. Funding through TPBAR and GTS were secured for a research grade quadrupole mass spectrometer (QMS) and replacement turbo pumps, which should improve the fidelity and throughput of measurements in FY16.

  13. Stacking fault energy decrease in austenitic stainless steels induced by hydrogen pairs formation

    SciTech Connect

    Hermida, J.D.; Roviglione, A.

    1998-09-15

    The decrease of the Stacking Fault Energy (SFE), induced by hydrogen in austenitic stainless steels, was always invoked to explain the formation of {epsilon}-martensite at room temperature during cathodic charging of hydrogen. Pontini and Hermida measured by XRD a reduction of 37 pct of the SPE of an AISI 304 steel at room temperature, in the presence of only 274 ppm of hydrogen. However, the nature of this phenomenon is still unknown. Recently, Obiol et a., using the Atoms Superposition and Electron Delocalization-Molecular Obital (ASED-MO) method, calculated the binding energy for H-H pair formation in the faulted zone of an FCC iron matrix. It was shown that, the H-H pair formation is more likely to occur along directions connecting octahedral interstices of the HCP stacking sequence and that are normal to the {l_brace}111{r_brace} planes. The binding energy found was {minus}5.75 eV, being this value significantly larger than the corresponding one for vacuum: {minus}4.75 eV. In this work, an explanation of the SFE decrease is developed on the basis of this previous result.

  14. Welding tritium exposed stainless steel

    SciTech Connect

    Kanne, W.R. Jr.

    1994-11-01

    Stainless steels that are exposed to tritium become unweldable by conventional methods due to buildup of decay helium within the metal matrix. With longer service lives expected for tritium containment systems, methods for welding on tritium exposed material will become important for repair or modification of the systems. Solid-state resistance welding and low-penetration overlay welding have been shown to mitigate helium embrittlement cracking in tritium exposed 304 stainless steel. These processes can also be used on stainless steel containing helium from neutron irradiation, such as occurs in nuclear reactors.

  15. Chromium-Makes stainless steel stainless

    USGS Publications Warehouse

    Kropschot, S.J.; Doebrich, Jeff

    2010-01-01

    Chromium, a steely-gray, lustrous, hard metal that takes a high polish and has a high melting point, is a silvery white, hard, and bright metal plating on steel and other material. Commonly known as chrome, it is one of the most important and indispensable industrial metals because of its hardness and resistance to corrosion. But it is used for more than the production of stainless steel and nonferrous alloys; it is also used to create pigments and chemicals used to process leather.

  16. Microstructural Characterization of Deformation Localization at Small Strains in a Neutron Irradiated 304 Stainless Steel

    SciTech Connect

    Field, Kevin G; Gussev, Maxim N; Busby, Jeremy T

    2014-01-01

    Deformation localization and structure evolution were investigated in an AISI 304 austenitic stainless steel deformed to 0.8% strain. Using SEM-EBSD, it was shown local plastic deformation may reach significant levels even when the bulk averaged strain level remains below 1%. Local misorientation values up to 24 were observed in these regions of high local plastic deformation. EBSD analysis of FIB lift-out specimens demonstrated that local misorientation level was highest near the free surface and diminished with increasing depth. (S)TEM observations on the same specimen indicated the local density of dislocation channels may vary up to an order of magnitude depending on local grain configuration, distance to the surface and/or local grain boundary structure. It was found that in the case of RT deformation, dislocation defect-free channels may contain twin or may be twin-free with twinning occurring inside channels. Formation of BCC-phase colonies (martensite) was observed in near-surface layer whereas no transformation in the volume of the specimen was detected at this strain level. Martensite formation was associated with channel-grain boundary intersection points where high local misorientation was observed using EBSD.

  17. Multi-response optimization of CO 2 laser-welding process of austenitic stainless steel

    NASA Astrophysics Data System (ADS)

    Benyounis, K. Y.; Olabi, A. G.; Hashmi, M. S. J.

    2008-02-01

    Recently, laser welding of austenitic stainless steel has received great attention in industry. This is due to its widespread application in petroleum refinement stations, power plants, the pharmaceutical industry and also in households. Therefore, mechanical properties should be controlled to obtain good welded joints. The welding process should be optimized by the proper mathematical models. In this research, the tensile strength and impact strength along with the joint-operating cost of laser-welded butt joints made of AISI304 was investigated. Design-expert software was used to establish the design matrix and to analyze the experimental data. The relationships between the laser-welding parameters (laser power, welding speed and focal point position) and the three responses (tensile strength, impact strength and joint-operating cost) were established. Also, the optimization capabilities in design-expert software were used to optimize the welding process. The developed mathematical models were tested for adequacy using analysis of variance and other adequacy measures. In this investigation, the optimal welding conditions were identified in order to increase the productivity and minimize the total operating cost. Overlay graphs were plotted by superimposing the contours for the various response surfaces. The process parameters effect was determined and the optimal welding combinations were tabulated.

  18. Thin stainless steel sandwich structural panels all welded by laser technology

    NASA Astrophysics Data System (ADS)

    Daurelio, Giuseppe; Ludovico, Antonio D.; Nenci, Fabio; Chiasera, Albino; Guadio, Maurizio

    1997-08-01

    This paper reports the results obtained by employing materials such as austenitic stainless steel (AISI 304) sheets, with different face thicknesses and core geometry's, usually some trapezoidal ones. A ROFIN SINAR C.W.CO2 laser has been used as a fast axial flow source and a 1500 W max power level to weld the many bases of the corrugated cores to the external faces has been utilized. Four different constructional solutions, for the preparation of some new modular structural elements, with one or two beads for each welded base, have been experimented. Each modular structure has sizes 300 mm wide, 700 mm length and 60 mm height. After studying many different mechanical clampings, the best one has been realized. So, eight different constructional solutions and different operative sequences of the welds have been made. All this for evaluating the effect of the weld sequence on the distortion of the panel and for obtaining different localization of the residual stresses on the structural element.

  19. How to guide lubricants - Tailored laser surface patterns on stainless steel

    NASA Astrophysics Data System (ADS)

    Grützmacher, Philipp G.; Rosenkranz, Andreas; Gachot, Carsten

    2016-05-01

    In this experimental study, periodic line-like structures with different periodicities (5, 10, 19, and 300 μm) and structural depths (approximately 1 and 4 μm) were fabricated on stainless steel samples (AISI-304) by short-pulse laser interference and ultrashort-pulse laser patterning. A detailed characterization of the resulting surface topography was performed by white light interferometry and scanning electron microscopy. The spreading dynamics of additive-free synthetic polyalphaolefine oil on a polished reference sample are compared to laser patterned surfaces. These studies are conducted using a newly developed test rig, which allowed for controlled temperature gradients and a precise recording of the spreading dynamics of lubricants on sample surfaces. It could be demonstrated that the spreading velocity parallel to the surface pattern is higher for all samples which can be explained by increased capillary forces and liquid pinning induced by the surface patterning. Furthermore, a decline of the spreading velocity over time for all samples and orientations is clearly visible which can be traced back to a viscosity increase induced by the temperature gradient and a reduced droplet volume. For parallel orientation, the experimental findings are in good agreement with the Lucas-Washburn equation and established models.

  20. Femtosecond laser fabrication of highly hydrophobic stainless steel surface with hierarchical structures fabricated by combining ordered microstructures and LIPSS

    NASA Astrophysics Data System (ADS)

    Martínez-Calderon, M.; Rodríguez, A.; Dias-Ponte, A.; Morant-Miñana, M. C.; Gómez-Aranzadi, M.; Olaizola, S. M.

    2016-06-01

    In this work we have developed hierarchical structures that consist of micro-patterned surfaces covered by nanostructures with a femtosecond laser. The first part of this work is a study to determine the microscale modifications produced on a stainless steel alloy (AISI304) surface at high pulse energy, different velocities, and number of overscans in order to obtain microstructures with a selected depth of around 10 μm and line widths of 20 μm. The second part of the work is focused on finding the optimal irradiation parameters to obtain the nanostructure pattern. Nanostructures have been defined by means of Laser Induced Periodical Surface Structures (LIPSS) around 250 nm high and a period of 580 nm, which constitute the nanostructure pattern. Finally, dual scale gratings of 50 mm2 were fabricated with different geometries and their effect on the measured contact angle. Combining the micro-pattern with the LIPSS nano-pattern, highly hydrophobic surfaces have been developed with measured static contact angles higher than 150° on a stainless steel alloy.

  1. Determination of creep compliance and creep-swelling coupling coefficients for neutron-irradiated titanium-modified stainless steel at {approximately}400{degree}C

    SciTech Connect

    Toloczko, M.B.; Garner, F.A.; Eiholzer, C.R.

    1991-11-01

    Irradiation creep data from FFTF-MOTA at {approximately}400{degrees}C were analyzed for nine 20% cold-worked titanium-modified type 316 stainless steels, each of which exhibits a different duration for the transient regime of swelling. One of these steels was the fusion prime candidate alloy designated PCA. The others were various developmental breeder reactor heats. The analysis was based on the assumption that the B{sub 0} + DS creep model applies to these steels at this temperature. This assumption was found to be valid. A creep-swelling coupling coefficient of D {approx} 0.6 {times} 10{sup {minus}2} MPa{sup {minus}1} was found for all steels that had developed a significant level of swelling. This result is in excellent agreement with the results of earlier studies conducted in EBR-II using annealed AISI 304L and also 10% and 20% cold-worked AISI 316 stainless steels. There appears to be some enhancement of swelling by stress, contradicting an important assumption in the analysis and leading to an apparent but misleading nonlinearity of creep with respect to stress.

  2. Determination of creep compliance and creep-swelling coupling coefficients for neutron-irradiated titanium-modified stainless steel at @400 degree C

    SciTech Connect

    Toloczko, M.B. ); Garner, F.A. ); Eiholzer, C.R. )

    1991-11-01

    Irradiation creep data from FFTF-MOTA at {approximately}400{degrees}C were analyzed for nine 20% cold-worked titanium-modified type 316 stainless steels, each of which exhibits a different duration for the transient regime of swelling. One of these steels was the fusion prime candidate alloy designated PCA. The others were various developmental breeder reactor heats. The analysis was based on the assumption that the B{sub 0} + DS creep model applies to these steels at this temperature. This assumption was found to be valid. A creep-swelling coupling coefficient of D {approx} 0.6 {times} 10{sup {minus}2} MPa{sup {minus}1} was found for all steels that had developed a significant level of swelling. This result is in excellent agreement with the results of earlier studies conducted in EBR-II using annealed AISI 304L and also 10% and 20% cold-worked AISI 316 stainless steels. There appears to be some enhancement of swelling by stress, contradicting an important assumption in the analysis and leading to an apparent but misleading nonlinearity of creep with respect to stress.

  3. A Study on Deformation Behavior of 304L Stainless Steel During and After Plate Rolling at Elevated Temperatures

    NASA Astrophysics Data System (ADS)

    Pourabdollah, P.; Serajzadeh, S.

    2017-02-01

    In this work, microstructural evolutions and mechanical properties of AISI 304L stainless steel were studied after rolling operations at elevated temperatures. Rolling experiments were conducted under warm and hot rolling conditions in the range of 600-1000 °C employing different reductions. Then, the developed microstructures and the mechanical properties of the steel were evaluated by means of uniaxial tensile testing, metallographic observations, and x-ray diffraction method. Besides, two-dimensional finite element analysis coupled with artificial neural network modeling was developed to assess thermo-mechanical behavior of the steel during and after rolling. The results show that inhomogeneities in strain and temperature distributions are reduced under warm rolling conditions. Static recrystallization can be operative under hot rolling conditions and relatively low reduction, i.e., reduction of 25%. However, for the case of higher reductions, the rate of recrystallization decreases considerably owing to severe temperature drop in the plate being rolled. Furthermore, the rolled plates show negative strain rate sensitivity while this phenomenon is affected by the rolling temperature.

  4. A Study on Deformation Behavior of 304L Stainless Steel During and After Plate Rolling at Elevated Temperatures

    NASA Astrophysics Data System (ADS)

    Pourabdollah, P.; Serajzadeh, S.

    2016-12-01

    In this work, microstructural evolutions and mechanical properties of AISI 304L stainless steel were studied after rolling operations at elevated temperatures. Rolling experiments were conducted under warm and hot rolling conditions in the range of 600-1000 °C employing different reductions. Then, the developed microstructures and the mechanical properties of the steel were evaluated by means of uniaxial tensile testing, metallographic observations, and x-ray diffraction method. Besides, two-dimensional finite element analysis coupled with artificial neural network modeling was developed to assess thermo-mechanical behavior of the steel during and after rolling. The results show that inhomogeneities in strain and temperature distributions are reduced under warm rolling conditions. Static recrystallization can be operative under hot rolling conditions and relatively low reduction, i.e., reduction of 25%. However, for the case of higher reductions, the rate of recrystallization decreases considerably owing to severe temperature drop in the plate being rolled. Furthermore, the rolled plates show negative strain rate sensitivity while this phenomenon is affected by the rolling temperature.

  5. Anti-adherence potential of Enterococcus durans cells and its cell-free supernatant on plastic and stainless steel against foodborne pathogens.

    PubMed

    Amel, Ait Meddour; Farida, Bendali; Djamila, Sadoun

    2015-07-01

    It is demonstrated that numerous bacteria are able to attach to surfaces of equipment used for food handling or processing. In this study, a strain of Enterococcus durans, originally isolated from a milking machine surface, was firstly studied for its biofilm formation potential on plastic and stainless steel supports. The strain was found to be a biofilm producer either at 25, 30 or 37 °C on polystyrene microtitre plates, with a best adherence level observed at 25 °C. En. durans showed a strong adhesion to stainless steel AISI-304. Antibacterial and anti-adherence activities of En. durans were tested against four foodborne pathogens (Escherichia coli ATCC 25922, Staphylococcus aureus ATCC 25923, Pseudomonas aeruginosa ATCC 27853 and Listeria innocua CLIP 74915) which were shown as biofilm producers on both plastic and stainless steel. En. durans cells and cell-free culture supernatant showed a significant (P < 0.05) inhibition potential of the pathogens either on solid media or in broth co-cultures. Characterization of the antibacterial substances indicated their proteinaceous nature which assigned them most probably to bacteriocins group.

  6. Thermal Linear Expansion of Nine Selected AISI Stainless Steels

    DTIC Science & Technology

    1978-04-01

    stainless steels. The nine selected stainless steels are AISI 303, 304, 304L, 316, 317, 321, 347, 410 , and 430. The recoended values Include the...point of the stainless steels. The nine selected stainless steels are AISI 303, 304, 304L, 316, 317, 321, 347, 410 , and 430. The recommended values...Stainless Steel..................................26 8. AISI 410 Stainless Steel..................................29 9. AISI 430 Stainless Steel

  7. Void Swelling at Low Displacement Rates in Annealed X18H10T Stainless Steel at 4 to 56 DPA and 280-332 degrees centigrade

    SciTech Connect

    Garner, Francis A.; Porollo, S. I.; Vorobjev, A. N.; Konobeev, Yu V.; Dvoriashin, A. M.

    2001-10-01

    Various components of pressurized water power reactors (PWRs) and some proposed fusion devices such as ITER will operate at lower temperatures and displacement rates than are encountered in many test reactors such as EBR-II, FFTF and HFIR. The question arises if the presence and magnitude of void swelling can be predicted for such irradiation environments. Data on Russian steel can be used to address part of this question. In reactor applications where Western countries typically use annealed AISI 304 stainless steel, it is the Russian practice to use annealed X18H10T, a titanium-stabilized 18Cr-10Ni stainless steel analogous to AISI 321. Using a flow restrictor component from the low-flux breeder zone of the BN-350 reactor in Kazakhstan, it was possible to examine the behavior of void swelling at relatively low temperatures and low displacement rates after 12 years of irradiation. The temperature of this component ranged from 270-340 degrees centigrade with a peak dose rate of 1.6 x 10{sup -7} power dpa/sec and a peak dose of 56 dpa. Careful sectioning of the component has yielded a large number of microscopy specimens over a ITER-relevant range of temperatures and displacement rates. Microstructural data are presented and show that void swelling at 10 to 50 dpa persists down to {approx}306 degrees centigrade for dose rates on the order of 1 x 10{sup -7} power dpa/sec.

  8. Development of New Stainless Steel

    SciTech Connect

    Robert F. Buck

    2005-08-30

    A new family of innovative martensitic stainless steels, 521-A, 521-B, and 521-C has been developed by Advanced Steel Technology, LLC (Trafford, PA) as high strength fastener (bolt) materials for use at moderate temperatures in turbine engines, including steam turbines, gas turbines, and aircraft engines. The primary objective of the development program was to create a martensitic stainless steel with high strength at moderate temperatures, and which could replace the expensive nickel-based superalloy IN 718 in some fasteners applications. A secondary objective was to replace conventional 12Cr steels such as AISI 422 used as blades, buckets and shafts that operate at intermediate temperatures in turbine engines with stronger steel. The composition of the new alloys was specifically designed to produce excellent mechanical properties while integrating heat treatment steps into production to reduce energy consumption during manufacturing. As a result, production costs and energy consumption during production of rolled bar products is significantly lower than conventional materials. Successful commercialization of the new alloys would permit the installed cost of certain turbine engines to be reduced without sacrificing high availability or operational flexibility, thereby enhancing the global competitiveness of U.S. turbine engine manufacturers. Moreover, the domestic specialty steel industry would also benefit through increased productivity and reduced operating costs, while increasing their share of the international market for turbine engine fasteners, blades, buckets and shafts.

  9. Nano-composite stainless steel

    DOEpatents

    Dehoff, Ryan R.; Blue, Craig A.; Peter, William H.; Chen, Wei; Aprigliano, Louis F.

    2015-07-14

    A composite stainless steel composition is composed essentially of, in terms of wt. % ranges: 25 to 28 Cr; 11 to 13 Ni; 7 to 8 W; 3.5 to 4 Mo; 3 to 3.5 B; 2 to 2.5 Mn; 1 to 1.5 Si; 0.3 to 1.7 C; up to 2 O; balance Fe. The composition has an austenitic matrix phase and a particulate, crystalline dispersed phase.

  10. Nickel: makes stainless steel strong

    USGS Publications Warehouse

    Boland, Maeve A.

    2012-01-01

    Nickel is a silvery-white metal that is used mainly to make stainless steel and other alloys stronger and better able to withstand extreme temperatures and corrosive environments. Nickel was first identified as a unique element in 1751 by Baron Axel Fredrik Cronstedt, a Swedish mineralogist and chemist. He originally called the element kupfernickel because it was found in rock that looked like copper (kupfer) ore and because miners thought that "bad spirits" (nickel) in the rock were making it difficult for them to extract copper from it. Approximately 80 percent of the primary (not recycled) nickel consumed in the United States in 2011 was used in alloys, such as stainless steel and superalloys. Because nickel increases an alloy's resistance to corrosion and its ability to withstand extreme temperatures, equipment and parts made of nickel-bearing alloys are often used in harsh environments, such as those in chemical plants, petroleum refineries, jet engines, power generation facilities, and offshore installations. Medical equipment, cookware, and cutlery are often made of stainless steel because it is easy to clean and sterilize. All U.S. circulating coins except the penny are made of alloys that contain nickel. Nickel alloys are increasingly being used in making rechargeable batteries for portable computers, power tools, and hybrid and electric vehicles. Nickel is also plated onto such items as bathroom fixtures to reduce corrosion and provide an attractive finish.

  11. Frictional and structural characterization of ion-nitrided low and high chromium steels

    NASA Technical Reports Server (NTRS)

    Spalvins, T.

    1985-01-01

    Low Cr steels AISI 41410, AISI 4340, and high Cr austenitic stainless steels AISI 304, AISI 316 were ion nitrided in a dc glow discharge plasma consisting of a 75 percent H2 - 25 percent N2 mixture. Surface compound layer phases were identified, and compound layer microhardness and diffusion zone microhardness profiles were established. Distinct differences in surface compound layer hardness and diffusion zone profiles were determined between the low and high Cr alloy steels. The high Cr stainless steels after ion nitriding displayed a hard compound layer and an abrupt diffusion zone. The compound layers of the high Cr stainless steels had a columnar structure which accounts for brittleness when layers are exposed to contact stresses. The ion nitrided surfaces of high and low Cr steels displayed a low coefficient of friction with respect to the untreated surfaces when examined in a pin and disk tribotester.

  12. Dependence on displacement rate of radiation-induced changes in microstructure and tensile properties of AISI 304 and 316

    SciTech Connect

    Brager, H.R.; Blackburn, L.D.; Greenslade, D.L.

    1983-08-01

    Annealed specimens of AISI 304 and 316 were irradiated in the EBR-II fast reactor at approx. 400/sup 0/C over a range of neutron fluxes and energy spectra. Tensile tests show that the hardening of the AISI 304 is sensitive to the displacement rate while the hardening of AISI 316 is not. However, the microstructures of both AISI 304 and 316 are influenced by displacement rate. The increase in yield strength of the specimens is correlated with the contribution of the various microstructural components produced during irradiation. The insensitivity in the hardening of AISI 316 to displacement rate arises because the strengthening contribution from precipitates increases with displacement rate, whereas the strengthening contribution from voids decreases.

  13. Copper-Nickel Cladding on Stainless Steel

    DTIC Science & Technology

    2005-07-01

    steel,. Monel (65Ni/35Cu) alloy consumables should be used as they can tolerate more iron dilution from the steel than the 70-30 copper-nickel alloy ...Cooper Alloys , 400 , K-500 Stainless Steel - Tyles 302, 304, 321, 347 N ickel 200 Silver Braze Alloys Nickel-Chromium Alloy 600 Nickel-Aluminum Bronze 70...cladding of austenitic stainless steels may also offer some ballistic, non-magnetic, and electromagnetic signature advantages over current hull alloys and

  14. Diffusion brazing nickel-plated stainless steel

    NASA Technical Reports Server (NTRS)

    Beuyukian, C. S.; Mitchell, M. J.

    1976-01-01

    To bond parts, sandwich assembly is made up of aluminum core, aluminum face sheet with brazing alloy interface, and nickel plated stainless steel part. Sandwich is placed between bottom and top glide sheet that is placed in stainless steel retort where assembly is bonded at 580 C.

  15. METHOD FOR JOINING ALUMINUM TO STAINLESS STEEL

    DOEpatents

    Lemon, L.C.

    1960-05-24

    Aluminum may be joined to stainless steel without the use of flux by tinning the aluminum with a tin solder containing 1% silver and 1% lead, tinning the stainless steel with a 50% lead 50% tin solder, and then sweating the tinned surfaces together.

  16. Strain induced grain boundary migration effects on grain growth of an austenitic stainless steel during static and metadynamic recrystallization

    SciTech Connect

    Paggi, A.; Angella, G.; Donnini, R.

    2015-09-15

    Static and metadynamic recrystallization of an AISI 304L austenitic stainless steel was investigated at 1100 °C and 10{sup −} {sup 2} s{sup −} {sup 1} strain rate. The kinetics of recrystallization was determined through double hit compression tests. Two strain levels were selected for the first compression hit: ε{sub f} = 0.15 for static recrystallization (SRX) and 0.25 for metadynamic recrystallization (MDRX). Both the as-deformed and the recrystallized microstructures were investigated through optical microscopy and electron back-scattered diffraction (EBSD) technique. During deformation, strain induced grain boundary migration appeared to be significant, producing a square-like grain boundary structure aligned along the directions of the maximum shear stresses in compression. EBSD analysis revealed to be as a fundamental technique that the dislocation density was distributed heterogeneously in the deformed grains. Grain growth driven by surface energy reduction was also investigated, finding that it was too slow to explain the experimental data. Based on microstructural results, it was concluded that saturation of the nucleation sites occurred in the first stages of recrystallization, while grain growth driven by strain induced grain boundary migration (SIGBM) dominated the subsequent stages. - Highlights: • Recrystallization behavior of a stainless steel was investigated at 1100 °C. • EBSD revealed that the dislocation density distribution was heterogeneous during deformation. • Saturation of nucleation sites occurred in the first stages of recrystallization. • Strain induced grain boundary migration (SIGBM) effects were significant. • Grain growth driven by SIGBM dominated the subsequent stages.

  17. Corrosion of stainless steel, 2. edition

    SciTech Connect

    Sedriks, A.J.

    1996-10-01

    The book describes corrosion characteristics in all the major and minor groups of stainless steels, namely, in austenitic, ferritic, martensitic, duplex, and precipitation hardenable steels. Several chapters are spent on those special forms of corrosion that are investigated in the great detail in stainless steels, namely, pitting corrosion, crevice corrosion, and stress corrosion cracking. The influences of thermal treatment (heat affected zone cases), composition, and microstructure on corrosion are given good coverage. Corrosive environments include high temperature oxidation, sulfidation as well as acids, alkalis, various different petroleum plant environments, and even human body fluids (stainless steels are commonly used prosthetic materials).

  18. Tritiated Water Interaction with Stainless Steel

    SciTech Connect

    Glen R. Longhurst

    2007-05-01

    Experiments conducted to study tritium permeation of stainless steel at ambient and elevated temperatures revealed that HT converts relatively quickly to HTO. Further, the HTO partial pressure contributes essentially equally with elemental tritium gas in driving permeation through the stainless steel. Such permeation appears to be due to dissociation of the water molecule on the hot stainless steel surface. There is an equilibrium concentration of HTO vapor above adsorbed gas on the walls of the experimental apparatus evident from freezing transients. The uptake process of tritium from the carrier gas involves both surface adsorption and isotopic exchange with surface bound water.

  19. Tribological and microstructural characteristics of ion-nitrided steels

    NASA Technical Reports Server (NTRS)

    Spalvins, T.

    1983-01-01

    Three steels AISI 4140, AISI 4340 and AISI 304 stainless steel were ion nitrided in a plasma consisting of a 75:25 mixture of H2:N2, sometimes with a trace of CH4. Their surface topography was characterized by SEM and two distinct compound phases were identified: the gamma and the epsilon. The core-case hardness profiles were also established. The low Cr alloy steels have an extended diffusion zone in contrast to the 304 stainless steels which have a sharp interface. The depth of ion-nitriding is increased as the Cr content is decreased. Friction tests reveal that the gamma surface phase has a lower coefficient of friction than the epsilon phase. The lowest coefficient of friction is achieved when both the rider and the specimen surface are ion nitrided.

  20. Impact Welding of Aluminum to Copper and Stainless Steel by Vaporizing Foil Actuator: Effect of Heat Treatment Cycles on Mechanical Properties and Microstructure

    NASA Astrophysics Data System (ADS)

    Vivek, Anupam; Hansen, Steven; Benzing, Jake; He, Mei; Daehn, Glenn

    2015-10-01

    This work studies the mechanical property effect of microstructure on impact welds of aluminum alloy AA6061 with both copper alloy Cu 110 and stainless steel AISI 304. AA6061-T6 and T4 temper aluminum sheets of 1 mm thickness were launched toward copper and stainless steel targets using the vaporizing foil actuator technique. Flyer plate velocities, measured via photonic Doppler velocimetry, were observed to be approximately 800 m/s. The welded aluminum-copper samples were subjected to instrumented peel testing, microhardness testing, energy-dispersive X-ray spectroscopy, and scanning electron microscopy. The welded joints exhibited cracks through their continuous intermetallic layers. The cracks were impeded upon encountering a ductile metallic wave. The welds created with T6 temper flyer sheets were found to have smaller intermetallic-free and wavy interface regions as compared to those created with T4 temper flyer sheets. Peel strength tests of the two weld combinations resulted in failure along the interface in the case of the T6 flyer welds, while the failure generally occurred in the parent aluminum for the T4 temper flyer welds. Half of the T4 flyer welds were subjected to aging for 18 h at 433 K (160 °C) to convert the aluminum sheet to the T6 condition. Although the aged flyer material did not attain the hardness of the as-received T6 material, it was found to be significantly stronger than the T4 material. These welds retained their strength after the aging process, and diffusion across the interface was minimal. The welded aluminum-stainless steel samples were analyzed on a more basic level than aluminum-copper samples, but were found to exhibit similar results.

  1. Precise carbon control of fabricated stainless steel

    DOEpatents

    Nilsen, R.J.

    1975-12-01

    A process is described for controlling the carbon content of fabricated stainless steel components including the steps of heat treating the component in hydrogen atmospheres of varying dewpoints and carbon potentials.

  2. Stainless Steel to Titanium Bimetallic Transitions

    SciTech Connect

    Kaluzny, J. A.; Grimm, C.; Passarelli, D.

    2015-01-01

    In order to use stainless steel piping in an LCLS-II (Linac Coherent Light Source Upgrade) cryomodule, stainless steel to titanium bimetallic transitions are needed to connect the stainless steel piping to the titanium cavity helium vessel. Explosion bonded stainless steel to titanium transition pieces and bimetallic transition material samples have been tested. A sample transition tube was subjected to tests and x-ray examinations between tests. Samples of the bonded joint material were impact and tensile tested at room temperature as well as liquid helium temperature. The joint has been used successfully in horizontal tests of LCLS-II cavity helium vessels and is planned to be used in LCLS-II cryomodules. Results of material sample and transition tube tests will be presented.

  3. Hydrogen compatibility handbook for stainless steels

    SciTech Connect

    Caskey, G.R. Jr.

    1983-06-01

    This handbook compiles data on the effects of hydrogen on the mechanical properties of stainless steels and discusses this data within the context of current understanding of hydrogen compatibility of metals. All of the tabulated data derives from continuing studies of hydrogen effects on materials that have been conducted at the Savannah River Laboratory over the past fifteen years. Supplementary data from other sources are included in the discussion. Austenitic, ferritic, martensitic, and precipitation hardenable stainless steels have been studied. Damage caused by helium generated from decay of tritium is a distinctive effect that occurs in addition to the hydrogen isotopes protium and deuterium. The handbook defines the scope of our current knowledge of hydrogen effects in stainless steels and serves as a guide to selection of stainless steels for service in hydrogen.

  4. Stainless Steels’ Resistance to Hydroerosion,

    DTIC Science & Technology

    1980-07-30

    Omel’chenko, engineer, S. L. Millichenko, A. G. Aleksandrov, Candidates of Technical Sciences Thanks to a high corrosion resistance stainless steels have...has great significance. The resistance to hydroerosion of several of the most common types of stainless steels which have roughly the same corrosion ...the failure is first localized in the ferrite phase and occurs by means of plastic deformation and the development of fatigue micro- cracks both

  5. Stainless steel recycle FY94 progress report

    SciTech Connect

    Imrich, K.J.

    1994-10-28

    The Materials Technology Section (MTS) of the Savannah River Technology Center (SRTC) was asked to demonstrate the practicality of recycling previously contaminated stainless steel components such as reactor heat exchanger heads, process water piping and slug buckets into 208 liters (55 gallon) drums and 2.8 cubic meter (100 ft{sup 3}) storage boxes. Radioactively contaminated stainless steel scrap will be sent to several industrial partners where it will be melted, decontaminated/cast into ingots, and rolled into plate and sheet and fabricated into the drums and boxes. As part of this recycle initiative, MTS was requested to demonstrate that radioactively contaminated Type 304L stainless steel could be remelted and cast to meet the applicable ASTM specification for fabrication of drums and boxes. In addition, MTS was requested to develop the technical basis of melt decontamination and establish practicality of using this approach for value added products. The findings presented in this investigation lead to the following conclusions: recycle of 18 wt% Cr-8 wt% Ni alloy can be achieved by melting Type 304 stainless steel in a air vacuum induction furnace; limited melt decontamination of the contaminated stainless steel was achieved, surface contamination was removed by standard decontamination techniques; carbon uptake in the as-cast ingots resulted from the graphite susceptor used in this experiment and is unavoidable with this furnace configuration. A new furnace optimized for melting stainless steel has been installed and is currently being tested for use in this program.

  6. High Mn austenitic stainless steel

    DOEpatents

    Yamamoto, Yukinori [Oak Ridge, TN; Santella, Michael L [Knoxville, TN; Brady, Michael P [Oak Ridge, TN; Maziasz, Philip J [Oak Ridge, TN; Liu, Chain-tsuan [Knoxville, TN

    2010-07-13

    An austenitic stainless steel alloy includes, in weight percent: >4 to 15 Mn; 8 to 15 Ni; 14 to 16 Cr; 2.4 to 3 Al; 0.4 to 1 total of at least one of Nb and Ta; 0.05 to 0.2 C; 0.01 to 0.02 B; no more than 0.3 of combined Ti+V; up to 3 Mo; up to 3 Co; up to 1W; up to 3 Cu; up to 1 Si; up to 0.05 P; up to 1 total of at least one of Y, La, Ce, Hf, and Zr; less than 0.05 N; and base Fe, wherein the weight percent Fe is greater than the weight percent Ni, and wherein the alloy forms an external continuous scale including alumina, nanometer scale sized particles distributed throughout the microstructure, the particles including at least one of NbC and TaC, and a stable essentially single phase FCC austenitic matrix microstructure that is essentially delta-ferrite-free and essentially BCC-phase-free.

  7. Forming "dynamic" membranes on stainless steel

    NASA Technical Reports Server (NTRS)

    Brandon, C. A.; Gaddis, J. L.

    1979-01-01

    "Dynamic" zirconium polyacrylic membrane is formed directly on stainless steel substrate without excessive corrosion of steel. Membrane is potentially useful in removal of contaminated chemicals from solution through reversed osmosis. Application includes use in filtration and desalination equipment, and in textile industry for separation of dyes from aqueous solvents.

  8. Comparison of ECN measurements and analysis during the SCC processes on stainless steel under different mechanical conditions

    SciTech Connect

    Leban, M.; Doletek, V.; Legat, A.; Kuhar, V.

    1999-11-01

    Electrochemical noise measurements have been performed on electrodes made from the same piece of stainless steel, of type AISI 304. Potential and current noise were measured under open circuit conditions in a three-electrode system, where one of the electrodes was kept under the load and acted as a common working electrode. Two types of electrode set-ups were used, differing in the method of load application. In the first case the common electrode was in the shape of a U-bend (under a static, undefined load), whereas in the second case the common electrode was subjected to a constant slowly increasing stress (the SSRT test). The first type of test was performed in a concentrated magnesium chloride solution at an elevated temperature. In order to detect the time when cracks initiated, the probes were dismantled daily, and examined visually using an optical microscope. SSRT tests were performed in diluted sodium thiocyanate solution with or without additions of chlorides. Electrochemical voltage and current noise and changes of stress and elongation were measured simultaneously. During the latter part of both types of tests, significant simultaneous spikes of voltage and current noise were observed. The spikes detected during the SSRT test were correlated with drops in stress and sudden increases in elongation. After the measurements had been performed, several characteristic time series (cracking non-active and cracking active) were subjected to spectral and chaos analysis. So far, analysis of such non-stationary signals, in particular of electrochemical systems (a U-bend exposed to a concentrated magnesium chloride solution) during uniform corrosion, cannot yet provide any satisfactory explanation of the complex mechanisms of stress-corrosion cracking processes.

  9. A Facile Method to Modify the Characteristics and Corrosion Behavior of 304 Stainless Steel by Surface Nanostructuring toward Biomedical Applications.

    PubMed

    Thangaraj, Balusamy; Nellaiappan, Sankara Narayanan T S; Kulandaivelu, Ravichandran; Lee, Min Ho; Nishimura, Toshiyasu

    2015-08-19

    The study addresses how surface nanostructuring of AISI 304 stainless steel (SS) by surface mechanical attrition treatment (SMAT) influences its characteristic properties and corrosion behavior in Ringer's solution. SMAT of 304 SS induced plastic deformation, enabled surface nanocrystallization, refined the grain size, transformed the austenite phase to strain induced α'-martensite phase, increased the surface roughness, induced defects/dislocations, imparted compressive residual stresses at the surface, decreased the contact angle, and increased surface energy. The change in properties of 304 SS following treatment using 5 and 8 mm ⌀ balls for 15, 30, 45, and 60 min has caused a deleterious influence on its corrosion resistance in Ringer's solution, while an improvement in corrosion behavior is observed for those treated using 2 mm ⌀ balls. The increase in surface roughness, transformation of the austenite to α'-martensite phase, a higher extent of deformation, and the presence of larger number of defects/dislocations are main factors responsible for the lower corrosion resistance observed for 304 SS treated using 5 and 8 mm ⌀ balls in Ringer's solution. In spite of having these attributes with a relatively lower extent, 304 SS treated using 2 mm ⌀ balls offered a better corrosion resistance and exhibits a better passivity. For those treated using 2 mm ⌀ balls, the ability of the nanocrystalline surface to promote passivation outweighs the deleterious influences caused by the limited amount of deformation and defects/dislocations. Based on the findings of this study, it is recommend that SMAT of 304 SS using 2 mm ⌀ balls for 15-30 min is the optimum condition to achieve the suitable surface profile, surface characteristics with better corrosion resistance.

  10. Aging degradation of cast stainless steel

    SciTech Connect

    Chopra, O.K.; Chung, H.M.

    1985-10-01

    A program is being conducted to investigate the significance of in-service embrittlement of cast-duplex stainless steels under light-water reactor operating conditions. Data from room-temperature Charpy-impact tests for several heats of cast stainless steel aged up to 10,000 h at 350, 400, and 450/sup 0/C are presented and compared with results from other studies. Microstructures of cast-duplex stainless steels subjected to long-term aging either in the laboratory or in reactor service have been characterized. The results indicate that at least two processes contribute to the low-temperature embrittleent of duplex stainless steels, viz., weakening of the ferrite/austenite phase boundary by carbide precipitation and embrittlement of ferrite matrix by the formation of additional phases such as G-phase, Type X, or the ..cap alpha..' phase. Carbide precipitation has a significant effect on the onset of embrittlement of CF-8 and -8M grades of stainless steels aged at 400 or 450/sup 0/C. The existing correlations do not accurately represent the embrittlement behavior over the temperature range 300 to 450/sup 0/C. 18 refs., 13 figs.

  11. Superplastic forming of stainless steel automotive components

    SciTech Connect

    Bridges, B.; Elmer, J.; Carol, L.

    1997-02-06

    Exhaust emission standards are governmentally controlled standards, which are increasingly stringent, forcing alternate strategies to meet these standards. One approach to improve the efficiency of the exhaust emission equipment is to decrease the time required to get the catalytic converter to optimum operating temperature. To accomplish this, automotive manufacturers are using double wall stainless steel exhaust manifolds to reduce heat loss of the exhaust gases to the converter. The current method to manufacture double wall stainless steel exhaust components is to use a low-cost alloy with good forming properties and extensively form, cut, assemble, and weld the pieces. Superplastic forming (SPF) technology along with alloy improvements has potential at making this process more cost effective. Lockheed Martin Energy Systems (LMES), Lawrence Livermore National Laboratory (LLNL) and USCAR Low Emission Partnership (LEP) worked under a Cooperative Research And Development Agreement (CRADA) to evaluate material properties, SPF behavior, and welding behavior of duplex stainless steel alloy for automotive component manufacturing. Battelle Pacific Northwest National Laboratory (PNNL) has a separate CRADA with the LEP to use SPF technology to manufacture a double wall stainless steel exhaust component. As a team these CRADAs developed and demonstrated a technical plan to accomplish making double wall stainless steel exhaust manifolds.

  12. Ultrasonic Spectroscopy of Stainless Steel Sandwich Panels

    NASA Technical Reports Server (NTRS)

    Cosgriff, Laura M.; Lerch, Bradley A.; Hebsur, Mohan G.; Baaklini, George Y.; Ghosn, Louis J.

    2003-01-01

    Enhanced, lightweight material systems, such as 17-4PH stainless steel sandwich panels are being developed for use as fan blades and fan containment material systems for next generation engines. In order to improve the production for these systems, nondestructive evaluation (NDE) techniques, such as ultrasonic spectroscopy, are being utilized to evaluate the brazing quality between the 17-4PH stainless steel face plates and the 17-4PH stainless steel foam core. Based on NDE data, shear tests are performed on sections representing various levels of brazing quality from an initial batch of these sandwich structures. Metallographic characterization of brazing is done to corroborate NDE findings and the observed shear failure mechanisms.

  13. 21 CFR 872.3350 - Gold or stainless steel cusp.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 8 2013-04-01 2013-04-01 false Gold or stainless steel cusp. 872.3350 Section 872...) MEDICAL DEVICES DENTAL DEVICES Prosthetic Devices § 872.3350 Gold or stainless steel cusp. (a) Identification. A gold or stainless steel cusp is a prefabricated device made of austenitic alloys or...

  14. 21 CFR 878.4495 - Stainless steel suture.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 8 2013-04-01 2013-04-01 false Stainless steel suture. 878.4495 Section 878.4495...) MEDICAL DEVICES GENERAL AND PLASTIC SURGERY DEVICES Surgical Devices § 878.4495 Stainless steel suture. (a) Identification. A stainless steel suture is a needled or unneedled nonabsorbable surgical suture composed of...

  15. 21 CFR 878.4495 - Stainless steel suture.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 8 2012-04-01 2012-04-01 false Stainless steel suture. 878.4495 Section 878.4495...) MEDICAL DEVICES GENERAL AND PLASTIC SURGERY DEVICES Surgical Devices § 878.4495 Stainless steel suture. (a) Identification. A stainless steel suture is a needled or unneedled nonabsorbable surgical suture composed of...

  16. 77 FR 64545 - Drawn Stainless Steel Sinks From China

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-10-22

    ... COMMISSION Drawn Stainless Steel Sinks From China Scheduling of the final phase of countervailing duty and... retarded, by reason of subsidized and less-than-fair-value imports from China of drawn stainless steel... merchandise as ``drawn stainless steel sinks with single or multiple drawn bowls, with or without drain...

  17. 21 CFR 872.3350 - Gold or stainless steel cusp.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 8 2011-04-01 2011-04-01 false Gold or stainless steel cusp. 872.3350 Section 872...) MEDICAL DEVICES DENTAL DEVICES Prosthetic Devices § 872.3350 Gold or stainless steel cusp. (a) Identification. A gold or stainless steel cusp is a prefabricated device made of austenitic alloys or...

  18. 21 CFR 872.3350 - Gold or stainless steel cusp.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Gold or stainless steel cusp. 872.3350 Section 872...) MEDICAL DEVICES DENTAL DEVICES Prosthetic Devices § 872.3350 Gold or stainless steel cusp. (a) Identification. A gold or stainless steel cusp is a prefabricated device made of austenitic alloys or...

  19. 77 FR 1504 - Stainless Steel Wire Rod From India

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-01-10

    ... COMMISSION Stainless Steel Wire Rod From India Determination On the basis of the record \\1\\ developed in the... antidumping duty order on stainless steel wire rod From India would be likely to lead to continuation or... contained in USITC Publication 4300 (January 2012), entitled Stainless Steel Wire Rod From...

  20. 21 CFR 872.3350 - Gold or stainless steel cusp.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 8 2012-04-01 2012-04-01 false Gold or stainless steel cusp. 872.3350 Section 872...) MEDICAL DEVICES DENTAL DEVICES Prosthetic Devices § 872.3350 Gold or stainless steel cusp. (a) Identification. A gold or stainless steel cusp is a prefabricated device made of austenitic alloys or...

  1. 21 CFR 872.3350 - Gold or stainless steel cusp.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 8 2014-04-01 2014-04-01 false Gold or stainless steel cusp. 872.3350 Section 872...) MEDICAL DEVICES DENTAL DEVICES Prosthetic Devices § 872.3350 Gold or stainless steel cusp. (a) Identification. A gold or stainless steel cusp is a prefabricated device made of austenitic alloys or...

  2. 21 CFR 878.4495 - Stainless steel suture.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Stainless steel suture. 878.4495 Section 878.4495...) MEDICAL DEVICES GENERAL AND PLASTIC SURGERY DEVICES Surgical Devices § 878.4495 Stainless steel suture. (a) Identification. A stainless steel suture is a needled or unneedled nonabsorbable surgical suture composed of...

  3. 21 CFR 878.4495 - Stainless steel suture.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 8 2011-04-01 2011-04-01 false Stainless steel suture. 878.4495 Section 878.4495...) MEDICAL DEVICES GENERAL AND PLASTIC SURGERY DEVICES Surgical Devices § 878.4495 Stainless steel suture. (a) Identification. A stainless steel suture is a needled or unneedled nonabsorbable surgical suture composed of...

  4. 78 FR 21417 - Drawn Stainless Steel Sinks From China

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-04-10

    ... COMMISSION Drawn Stainless Steel Sinks From China Determinations On the basis of the record \\1\\ developed in... drawn stainless steel sinks from China, provided for in subheading 7324.10.00 of the Harmonized Tariff... notification of a preliminary determinations by Commerce that imports of drawn stainless steel sinks from...

  5. 21 CFR 878.4495 - Stainless steel suture.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 8 2014-04-01 2014-04-01 false Stainless steel suture. 878.4495 Section 878.4495...) MEDICAL DEVICES GENERAL AND PLASTIC SURGERY DEVICES Surgical Devices § 878.4495 Stainless steel suture. (a) Identification. A stainless steel suture is a needled or unneedled nonabsorbable surgical suture composed of...

  6. Stainless Steel Microstructure and Mechanical Properties Evaluation

    SciTech Connect

    Switzner, Nathan T

    2010-06-01

    A nitrogen strengthened 21-6-9 stainless steel plate was spinformed into hemispherical test shapes. A battery of laboratory tests was used to characterize the hemispheres. The laboratory tests show that near the pole (axis) of a spinformed hemisphere the yield strength is the lowest because this area endures the least “cold-work” strengthening, i.e., the least deformation. The characterization indicated that stress-relief annealing spinformed stainless steel hemispheres does not degrade mechanical properties. Stress-relief annealing reduces residual stresses while maintaining relatively high mechanical properties. Full annealing completely eliminates residual stresses, but reduces yield strength by about 30%.

  7. Friction Drilling of Stainless Steels Pipes

    SciTech Connect

    Fernandez, A.; Lopez de Lacalle, L. N.; Lamikiz, A.

    2011-01-17

    This work describes the experimental study of the friction drilling process in stainless steel by means of an optimization of the machining conditions. For such purpose austenitic stainless steel with different thicknesses were analyzed through controlled tests at different rotation speeds and feed rates. On one hand, the torque and the thrust force were computed and monitorized. On the other hand, the dimensional tolerances of the holes were evaluated, mainly the accuracy of the hole diameter and the burr thickness at different depths. Another topic of interest inherent to this special technique is the temperature level reached during the friction process which is crucial when it comes to development of microstructural transformations.

  8. Assessment of elemental composition, microstructure, and hardness of stainless steel endodontic files and reamers.

    PubMed

    Darabara, Myrsini; Bourithis, Lefteris; Zinelis, Spiros; Papadimitriou, George D

    2004-07-01

    The purpose of this study was to determine the elemental composition, microstructure, and hardness of commercially available reamers, K files, and H files. Five instruments of each type from different manufacturers (Antaeos, FKG, Maillefer, Mani, and Micromega) were embedded in epoxy resin along their longitudinal axis. After metallographic grinding and polishing, the specimens were chemically etched and their microstructure investigated under an incident light microscope. The specimens were studied under a scanning electron microscope, and their elemental compositions were determined by energy dispersive X-ray microanalysis. The same surfaces were repolished and X-ray diffraction was performed. The same specimen surface was used for the assessment of the Vickers hardness (HV200) by using a microhardness tester with a 200-g load and 20-s contact time. The hardness results were statistically analyzed with two-way ANOVA and Tukey's test (a = 0.05). All files demonstrated extensively elongated grains parallel to longitudinal file axis because of cold drawing. The elemental composition of Maillefer and Mani reamers, Antaeos K files, and Mani H files were found in the range of AISI 303 SS, whereas all the rest were determined as AISI 304 SS. Two different phases (austenite SSt and martensite SSt) were identified with X-ray diffraction for all files tested. The results of hardness classified reamers in the following decreasing order (HMV200): Micromega = 673 +/- 29, Mani = 662 +/- 24, Maillefer = 601 +/- 34, Antaeos = 586 +/- 18, FKG = 557 +/- 19, and the K files (HV200): FKG = 673 +/- 16, Mani = 647 +/- 19, Maillefer = 603 +/- 41, Antaeos = 566 +/- 21, Micromega = 555 +/- 15, and the H files (HMV200): Mani = 640 +/- 12, FKG = 583 +/- 31, Maillefer = 581 +/- 5, Antaeos = 573 +/- 3, Micromega = 546 +/- 14. Although only two stainless steel alloys were used for the production of endodontic files, the differences in hardness are independent to the alloys used, implying that

  9. Dendritic inhomogeneity of stainless maraging steels

    SciTech Connect

    Krasnikova, S.I.; Drobot, A.V.; Shmelev, A.Y.; Vukelich, S.B.

    1986-03-01

    The authors investigated dendritic inhomogeneity in industrial ingots 630 mm (steel I) in diameter and 500 mm (steel II) in diameter. The variation in the degree of dendritic inhomogeneity was investigated over the height of the ingots and across the sections on an MS-46 microprobe. It was established that the elements can be placed in the following order in accordance with the degree of reduction in the liquation factor: titanium, molybdenum, nickel, chromium, and cobalt. Titanium and molybdenum exhibit forward liquation in both steels, and chromium in steel II. The distribution of nickel and chromium in the steel I ingots and cobalt in the steel II ingots is unconventional. Dendritic inhomogeneity, which must be considered in assigning the heat treatment for finished articles, develops during the crystallization of stainless maraging steels.

  10. 77 FR 28568 - Grant of Authority for Subzone Status; North American Stainless, (Stainless Steel), Ghent, KY

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-05-15

    ... Steel), Ghent, KY Pursuant to its authority under the Foreign-Trade Zones Act of June 18, 1934, as... authority to establish a special-purpose subzone at the stainless steel mill of North American Stainless... subzone status for activity related to the manufacturing and distribution of stainless steel at...

  11. Nickel-free austenitic stainless steels for medical applications

    PubMed Central

    Yang, Ke; Ren, Yibin

    2010-01-01

    The adverse effects of nickel ions being released into the human body have prompted the development of high-nitrogen nickel-free austenitic stainless steels for medical applications. Nitrogen not only replaces nickel for austenitic structure stability but also much improves steel properties. Here we review the harmful effects associated with nickel in medical stainless steels, the advantages of nitrogen in stainless steels, and emphatically, the development of high-nitrogen nickel-free stainless steels for medical applications. By combining the benefits of stable austenitic structure, high strength and good plasticity, better corrosion and wear resistances, and superior biocompatibility compared to the currently used 316L stainless steel, the newly developed high-nitrogen nickel-free stainless steel is a reliable substitute for the conventional medical stainless steels. PMID:27877320

  12. Laser Rewelding of 304L Stainless Steel.

    SciTech Connect

    Maguire, Michael Christopher; Rodelas, Jeffrey

    2016-11-01

    Laser welding of 304L stainless steel during component fabrication has been found to alter the chemical composition of the steel due to material evaporation. During repair or rework, or during potential reuse/ rewelding of certain components, the potential exists to alter the composition to the extent that the material becomes prone to solidification cracking. This work aims to characterize the extent of this susceptibility in order to make informed decisions regarding rewelding practice and base metal chemistry allowances.

  13. Austenitic stainless steels for cryogenic service

    SciTech Connect

    Dalder, E.N.C.; Juhas, M.C.

    1985-09-19

    Presently available information on austenitic Fe-Cr-Ni stainless steel plate, welds, and castings for service below 77 K are reviewed with the intent (1) of developing systematic relationships between mechanical properties, composition, microstructure, and processing, and (2) of assessing the adequacy of these data bases in the design, fabrication, and operation of engineering systems at 4 K.

  14. Materials data handbook: Stainless steel type 301

    NASA Technical Reports Server (NTRS)

    Muraca, R. F.; Whittick, J. S.

    1972-01-01

    A summary of the materials property information for stainless steel type 301 is presented. The scope of the information includes physical and mechanical properties at cryogenic, ambient, and elevated temperatures. Information on material procurement, metallurgy of the alloy, corrosion, environmental effects, fabrication, and bonding is developed.

  15. Finite element based simulation on friction stud welding of metal matrix composites to steel

    NASA Astrophysics Data System (ADS)

    Hynes, N. Rajesh Jesudoss; Tharmaraj, R.; Velu, P. Shenbaga; Kumar, R.

    2016-05-01

    Friction welding is a solid state joining technique used for joining similar and dissimilar materials with high integrity. This new technique is being successfully applied to the aerospace, automobile, and ship building industries, and is attracting more and more research interest. The quality of Friction Stud Welded joints depends on the frictional heat generated at the interface. Hence, thermal analysis on friction stud welding of stainless steel (AISI 304) and aluminium silicon carbide (AlSiC) combination is carried out in the present work. In this study, numerical simulation is carried out using ANSYS software and the temperature profiles are predicted at various increments of time. The developed numerical model is found to be adequate to predict temperature distribution of friction stud weld aluminium silicon carbide/stainless steel joints.

  16. The stainless steel beneficial reuse integrated demonstration

    SciTech Connect

    Boettinger, W.L.; Lutz, R.N.

    1994-12-31

    Process water heat exchangers at SRS contains over 95% 304 stainless steel which could be recycled back to DOE in a ``controlled release`` manner, that is, the radioactive scrap metal (RSM) could be reprocessed into new reusable products for return to DOE for use within the DOE Complex. In 1994, a demonstration was begun to recycle recycle contaminated stainless steel by melting 60 tons of RSM and refabricating it into containers for long-term temporary storage. The demonstration covers the entire recycle chain; the melting and the fabrication are to be done through subcontracts with private industry. Activity level of RSM to be supplied to industry is less than one curie total; the average specific activity level of the cobalt-60 which will be imbedded in the final products was estimated to be 117 pico curies per gram (4.31 becquerels/gram).

  17. Weldability of Additive Manufactured Stainless Steel

    NASA Astrophysics Data System (ADS)

    Matilainen, Ville-Pekka; Pekkarinen, Joonas; Salminen, Antti

    Part size in additive manufacturing is limited by the size of building area of AM equipment. Occasionally, larger constructions that AM machines are able to produce, are needed, and this creates demand for welding AM parts together. However there is very little information on welding of additive manufactured stainless steels. The aim of this study was to investigate the weldability aspects of AM material. In this study, comparison of the bead on plate welds between AM parts and sheet metal parts is done. Used material was 316L stainless steel, AM and sheet metal, and parts were welded with laser welding. Weld quality was evaluated visually from macroscopic images. Results show that there are certain differences in the welds in AM parts compared to the welds in sheet metal parts. Differences were found in penetration depths and in type of welding defects. Nevertheless, this study presents that laser welding is suitable process for welding AM parts.

  18. Dislocation substructure in fatigued duplex stainless steel

    SciTech Connect

    Polak, J. . Lab. de Mecanique de Lille Inst. of Physical Metallurgy, Brno . Academy of Sciences); Degallaix, S. . Lab. de Mecanique de Lille); Kruml, T. . Academy of Sciences)

    1993-12-15

    Cyclic plastic straining of crystalline materials results in the formation of specific dislocation structures. Considerable progress in mapping and understanding internal dislocation structures has been achieved by studying single crystal behavior: however, most structural materials have a polycrystalline structure and investigations of polycrystals in comparison to single crystal behavior of simple metals prove to be very useful in understanding more complex materials. There are some classes of materials, however, with complicated structure which do not have a direct equivalent in single crystalline form. Moreover, the specific dimensions and shapes of individual crystallites play an important role both in the cyclic stress-strain response of these materials and in the formation of their interior structure in cyclic straining. Austenitic-ferritic duplex stainless steel, which is a kind of a natural composite, is a material of this type. The widespread interest in the application of duplex steels is caused by approximately doubled mechanical properties and equal corrosion properties, when compared with classical austenitic stainless steels. Fatigue resistance of these steels as well as the surface damage evolution in cyclic straining have been studied; however, much less is known about the internal substructure development in cyclic straining. In this study the dislocation arrangement in ferritic and austenitic grains of the austenitic-ferritic duplex steel alloyed with nitrogen and cyclically strained with two strain amplitudes, is reported and compared to the dislocation arrangement found in single and polycrystals of austenitic and ferritic materials of a similar composition and with the surface relief produced in cyclic plastic straining.

  19. Properties of cryogenically worked metals. [stainless steels

    NASA Technical Reports Server (NTRS)

    Schwartzberg, F. R.; Kiefer, T. F.

    1975-01-01

    A program was conducted to determine whether the mechanical properties of cryogenically worked 17-7PH stainless steel are suitable for service from ambient to cryogenic temperatures. It was determined that the stress corrosion resistance of the cryo-worked material is quite adequate for structural service. The tensile properties and fracture toughness at room temperature were comparable to titanium alloy 6Al-4V. However, at cryogenic temperatures, the properties were not sufficient to recommend consideration for structural service.

  20. Pitting corrosion resistant austenite stainless steel

    DOEpatents

    van Rooyen, D.; Bandy, R.

    A pitting corrosion resistant austenite stainless steel comprises 17 to 28 wt. % chromium, 15 to 26 wt. % nickel, 5 to 8 wt. % molybdenum, and 0.3 to 0.5 wt. % nitrogen, the balance being iron, unavoidable impurities, minor additions made in the normal course of melting and casting alloys of this type, and may optionally include up to 10 wt. % of manganese, up to 5 wt. % of silicon, and up to 0.08 wt. % of carbon.

  1. Effect of ferrite on cast stainless steels

    SciTech Connect

    Nadezhdin, A.; Cooper, K. ); Timbers, G. . Kraft Pulp Division)

    1994-09-01

    Premature failure of stainless steel castings in bleach washing service is attributed to poor casting quality high porosity and to a high ferrite content, which makes the castings susceptible to corrosion by hot acid chloride solutions. A survey of the chemical compositions and ferrite contents of corrosion-resistant castings in bleach plants at three pulp mills found high [delta]-ferrite levels in the austenitic matrix due to the improper balance between austenite and ferrite stabilizers.

  2. The use of stainless steel crowns.

    PubMed

    Seale, N Sue

    2002-01-01

    The stainless steel crown (SSC) is an extremely durable restoration with several clear-cut indications for use in primary teeth including: following a pulpotomy/pulpectomy; for teeth with developmental defects or large carious lesions involving multiple surfaces where an amalgam is likely to fail; and for fractured teeth. In other situations, its use is less clear cut, and caries risk factors, restoration longevity and cost effectiveness are considerations in decisions to use the SSC. The literature on caries risk factors in young children indicates that children at high risk exhibiting anterior tooth decay and/or molar caries may benefit by treatment with stainless steel crowns to protect the remaining at-risk tooth surfaces. Studies evaluating restoration longevity, including the durability and lifespan of SSCs and Class II amalgams demonstrate the superiority of SSCs for both parameters. Children with extensive decay, large lesions or multiple surface lesions in primary molars should be treated with stainless steel crowns. Because of the protection from future decay provided by their feature of full coverage and their increased durability and longevity, strong consideration should be given to the use of SSCs in children who require general anesthesia. Finally, a strong argument for the use of the SSC restoration is its cost effectiveness based on its durability and longevity.

  3. SRS stainless steel beneficial reuse program

    SciTech Connect

    Boettinger, W.L.

    1997-02-01

    The US Department of Energy`s (DOE) Savannah River Site (SRS) has thousands of tons of stainless steel radioactive scrap metal (RSNI). Much of the metal is volumetrically contaminated. There is no {open_quotes}de minimis{close_quotes} free release level for volumetric material, and therefore no way to recycle the metal into the normal commercial market. If declared waste, the metal would qualify as low level radioactive waste (LLW) and ultimately be dispositioned through shallow land buried at a cost of millions of dollars. The metal however could be recycled in a {open_quotes}controlled release{close_quote} manner, in the form of containers to hold other types of radioactive waste. This form of recycle is generally referred to as {open_quotes}Beneficial Reuse{close_quotes}. Beneficial reuse reduces the amount of disposal space needed and reduces the need for virgin containers which would themselves become contaminated. Stainless steel is particularly suited for long term storage because of its resistance to corrosion. To assess the practicality of stainless steel RSM recycle the SRS Benficial Reuse Program began a demonstration in 1994, funded by the DOE Office of Science and Technology. This paper discusses the experiences gained in this program.

  4. Impact Testing of Stainless Steel Materials

    SciTech Connect

    R. K. Blandford; D. K. Morton; T. E. Rahl; S. D. Snow

    2005-07-01

    Stainless steels are used for the construction of numerous spent nuclear fuel or radioactive material containers that may be subjected to high strains and moderate strain rates (10 to 200 per second) during accidental drop events. Mechanical characteristics of these materials under dynamic (impact) loads in the strain rate range of concern are not well documented. The goal of the work presented in this paper was to improve understanding of moderate strain rate phenomena on these materials. Utilizing a drop-weight impact test machine and relatively large test specimens (1/2-inch thick), initial test efforts focused on the tensile behavior of specific stainless steel materials during impact loading. Impact tests of 304L and 316L stainless steel test specimens at two different strain rates, 25 per second (304L and 316L material) and 50 per second (304L material) were performed for comparison to their quasi-static tensile test properties. Elevated strain rate stress-strain curves for the two materials were determined using the impact test machine and a “total impact energy” approach. This approach considered the deformation energy required to strain the specimens at a given strain rate. The material data developed was then utilized in analytical simulations to validate the final elevated stress-strain curves. The procedures used during testing and the results obtained are described in this paper.

  5. Antimicrobial Cu-bearing stainless steel scaffolds.

    PubMed

    Wang, Qiang; Ren, Ling; Li, Xiaopeng; Zhang, Shuyuan; Sercombe, Timothy B; Yang, Ke

    2016-11-01

    Copper-bearing stainless steel scaffolds with two different structures (Body Centered Cubic and Gyroid labyrinth) at two solid fractions (25% and 40%) were fabricated from both 316L powder and a mixture of 316L and elemental Cu powder using selective laser melting, and relative 316L scaffolds were served as control group. After processing, the antimicrobial testing demonstrated that the 316L-Cu scaffolds presented excellent antimicrobial activity against Escherichia coli and Staphylococcus aureus, and the cell viability assay indicated that there was no cytotoxic effect of 316L-Cu scaffolds on rat marrow mesenchymal stem cells. As such, these have the potential to reduce implant-associated infections. The Cu was also found to homogeneously distribute within the microstructure by scanning electronic microcopy. The addition of Cu would not significantly affect its strength and stiffness compared to 316L scaffold, and the stiffness of all the scaffolds (3-20GPa) is similar to that of bone and much less than that of bulk stainless steel. Consequently, fabrication of such low stiffness porous structures, especially coupled with the addition of antimicrobial Cu, may provide a new direction for medical stainless steels.

  6. Cast Stainless Steel Ferrite and Grain Structure

    SciTech Connect

    Ruud, Clayton O.; Ramuhalli, Pradeep; Meyer, Ryan M.; Mathews, Royce; Diaz, Aaron A.; Anderson, Michael T.

    2012-09-01

    In-service inspection requirements dictate that piping welds in the primary pressure boundary of light-water reactors be subject to a volumetric examination based on the rules contained within the American Society of Mechanical Engineers Boiler and Pressure Vessel Code, Section XI. The purpose of the inspection is the reliable detection and accurate sizing of service-induced degradation and/or material flaws introduced during fabrication. The volumetric inspection is usually carried out using ultrasonic testing (UT) methods. However, the varied metallurgical macrostructures and microstructures of cast austenitic stainless steel piping and fittings, including statically cast stainless steel and centrifugally cast stainless steel (CCSS), introduce significant variations in the propagation and attenuation of ultrasonic energy. These variations complicate interpretation of the UT responses and may compromise the reliability of UT inspection. A review of the literature indicated that a correlation may exist between the microstructure and the delta ferrite content of the casting alloy. This paper discusses the results of a recent study where the goal was to determine if a correlation existed between measured and/or calculated ferrite content and grain structure in CCSS pipe.

  7. Decontaminating and Melt Recycling Tritium Contaminated Stainless Steel

    SciTech Connect

    Clark, E.A.

    1995-04-03

    The Westinghouse Savannah River Company, Idaho National Engineering Laboratory, and several university and industrial partners are evaluating recycling radioactively contaminated stainless steel. The goal of this program is to recycle contaminated stainless steel scrap from US Department of Energy national defense facilities. There is a large quantity of stainless steel at the DOE Savannah River Site from retired heavy water moderated Nuclear material production reactors (for example heat exchangers and process water piping), that will be used in pilot studies of potential recycle processes. These parts are contaminated by fission products, activated species, and tritium generated by neutron irradiation of the primary reactor coolant, which is heavy (deuterated) water. This report reviews current understanding of tritium contamination of stainless steel and previous studies of decontaminating tritium exposed stainless steel. It also outlines stainless steel refining methods, and proposes recommendations based on this review.

  8. Aging degradation of cast stainless steel

    SciTech Connect

    Chopra, O.K.; Chung, H.M.

    1986-10-01

    A program is being conducted to investigate the significance of in-service embrittlement of cast duplex stainless steels under light-water reactor operating conditions. Microstructures of cast materials subjected to long-term aging either in reactor service or in the laboratory have been characterized by TEM, SANS, and APFIM techniques. Two precipitate phases, i.e., the Cr-rich ..cap alpha..' and Ni- and Si-rich G phase, have been identified in the ferrite matrix of the aged steels. The results indicate that the low-temperature embrittlement is primarily caused by ..cap alpha..' precipitates which form by spinodal decomposition. The relative contribution of G phase to loss of toughness is now known. Microstructural data also indicate that weakening of ferrite/austenite phase boundary by carbide precipitates has a significant effect on the onset and extent of embrittlement of the high-carbon CF-8 and CF-8M grades of stainless steels, particularly after aging at 400 or 450/sup 0/C. Data from Charpy-impact, tensile, and J-R curve tests for several heats of cast stainless steel aged up to 10,000 h at 350, 400, and 450/sup 0/C are presented and correlated with the microstructural results. Thermal aging of the steels results in an increase in tensile strength and a decrease in impact energy, J/sub IC/, and tearing modulus. The fracture toughness results show good agreement with the Charpy-impact data. The effects of compositional and metallurgical variables on loss of toughness are discussed.

  9. A Stem Analysis of Two Rapidly Solidified Stainless Steels.

    DTIC Science & Technology

    1980-03-25

    slightly faster rate than the 303 stainless steel powder and therefore few usable specimens were obtained by electropolishing . The unsuccessful...CONCLUSIONS Rapid solidification processing of a high- sulphur austenitic type 303 stainless steel produces a significant refinement in the...A STEM ANALYSTS OF TWO RAPIDLY SOLIDIFIED STAINLESS STEELS . (U) UN D MAR 80 T F KELLY, J B VANDER SANDE NOBOI-76-C-0171 UNLSSFE7Minrnc UNCLASSIFIED

  10. Characterization of thermal aging of duplex stainless steel by SQUID

    SciTech Connect

    Isobe, Y.; Kamimura, A.; Aoki, K.; Nakayasu, F.

    1995-08-01

    Thermal aging is a growing concern for long-term-aged duplex stainless steel piping in nuclear power plants. Superconducting QUantum Interference Device (SQUID) was used for the detection of thermal aging of SUS329 rolled duplex stainless steel and SCS16 cast duplex stainless steel. It was found that the SQUID output signal pattern in the presence of AC magnetic field applied to the specimen was sensitive to the changes in electromagnetic properties due to thermal aging.

  11. Stainless Steel Leaches Nickel and Chromium into Foods During Cooking

    PubMed Central

    Kamerud, Kristin L.; Hobbie, Kevin A.; Anderson, Kim A.

    2014-01-01

    Toxicological studies show that oral doses of nickel and chromium can cause cutaneous adverse reactions such as dermatitis. Additional dietary sources, such as leaching from stainless steel cookware during food preparation, are not well characterized. This study examined stainless steel grades, cooking time, repetitive cooking cycles, and multiple types of tomato sauces for their effects on nickel and chromium leaching. Trials included three types of stainless steels and a stainless steel saucepan; cooking times of 2 to 20 hours, ten consecutive cooking cycles, and four commercial tomato sauces. After a simulated cooking process, samples were analyzed by ICP-MS for Ni and Cr. After six hours of cooking, Ni and Cr concentrations in tomato sauce increased up to 26- and 7-fold respectively, depending on the grade of stainless steel. Longer cooking durations resulted in additional increases in metal leaching, where Ni concentrations increased 34 fold and Cr increased approximately 35 fold from sauces cooked without stainless steel. Cooking with new stainless steel resulted in the largest increases. Metal leaching decreases with sequential cooking cycles and stabilized after the sixth cooking cycle, though significant metal contributions to foods were still observed. The tenth cooking cycle, resulted in an average of 88 μg of Ni and 86 μg of Cr leached per 126 g serving of tomato sauce. Stainless steel cookware can be an overlooked source of nickel and chromium, where the contribution is dependent on stainless steel grade, cooking time, and cookware usage. PMID:23984718

  12. Stainless steel leaches nickel and chromium into foods during cooking.

    PubMed

    Kamerud, Kristin L; Hobbie, Kevin A; Anderson, Kim A

    2013-10-02

    Toxicological studies show that oral doses of nickel and chromium can cause cutaneous adverse reactions such as dermatitis. Additional dietary sources, such as leaching from stainless steel cookware during food preparation, are not well characterized. This study examined stainless steel grades, cooking time, repetitive cooking cycles, and multiple types of tomato sauces for their effects on nickel and chromium leaching. Trials included three types of stainless steels and a stainless steel saucepan, cooking times of 2-20 h, 10 consecutive cooking cycles, and four commercial tomato sauces. After a simulated cooking process, samples were analyzed by ICP-MS for Ni and Cr. After 6 h of cooking, Ni and Cr concentrations in tomato sauce increased up to 26- and 7-fold, respectively, depending on the grade of stainless steel. Longer cooking durations resulted in additional increases in metal leaching, where Ni concentrations increased 34-fold and Cr increased approximately 35-fold from sauces cooked without stainless steel. Cooking with new stainless steel resulted in the largest increases. Metal leaching decreases with sequential cooking cycles and stabilized after the sixth cooking cycle, although significant metal contributions to foods were still observed. The tenth cooking cycle resulted in an average of 88 μg of Ni and 86 μg of Cr leached per 126 g serving of tomato sauce. Stainless steel cookware can be an overlooked source of nickel and chromium, where the contribution is dependent on stainless steel grade, cooking time, and cookware usage.

  13. Weldment for austenitic stainless steel and method

    DOEpatents

    Bagnall, Christopher; McBride, Marvin A.

    1985-01-01

    For making defect-free welds for joining two austenitic stainless steel mers, using gas tungsten-arc welding, a thin foil-like iron member is placed between the two steel members to be joined, prior to making the weld, with the foil-like iron member having a higher melting point than the stainless steel members. When the weld is formed, there results a weld nugget comprising melted and then solidified portions of the joined members with small portions of the foil-like iron member projecting into the solidified weld nugget. The portions of the weld nugget proximate the small portions of the foil-like iron member which project into the weld nugget are relatively rich in iron. This causes these iron-rich nugget portions to display substantial delta ferrite during solidification of the weld nugget which eliminates weld defects which could otherwise occur. This is especially useful for joining austenitic steel members which, when just below the solidus temperature, include at most only a very minor proportion of delta ferrite.

  14. 77 FR 58355 - Drawn Stainless Steel Sinks From the People's Republic of China: Countervailing Duty Investigation

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-09-20

    ... International Trade Administration Drawn Stainless Steel Sinks From the People's Republic of China... Department'') initiated antidumping and countervailing duty investigations of drawn stainless steel sinks... countervailing duty determination.\\2\\ \\1\\ See Drawn Stainless Steel Sinks From the People's Republic of...

  15. Superhard Nanocrystalline Homometallic Stainless Steel on Steel for Seamless Coatings

    NASA Technical Reports Server (NTRS)

    Tobin, Eric J.; Hafley, R. (Technical Monitor)

    2002-01-01

    The objective of this work is to deposit nanocrystalline stainless steel onto steel substrates (homometallic) for enhanced wear and corrosion resistance. Homometallic coatings provide superior adhesion, and it has been shown that ultrafine-grained materials exhibit the increased hardness and decreased permeability desired for protective coatings. Nanocrystals will be produced by controlling nucleation and growth and use of an ion beam during deposition by e-beam evaporation or sputtering. Phase I is depositing 31 6L nanocrystalline stainless steel onto 31 6L stainless steel substrates. These coatings exhibit hardnesses comparable to those normally obtained for ceramic coatings such ZrO2, and possess the superior adhesion of seamless, homometallic coatings. Hardening the surface with a similar material also enhances adhesion, by avoiding problems associated with thermal and lattice mismatch. So far we have deposited nanocrystalline homometallic 316L stainless steel coatings by varying the ions and the current density of the ion beams. For all deposition conditions we have produced smooth, uniform, superhard coatings. All coatings exhibit hardness of at least 200% harder than that of bulk materials. Our measurements indicate that there is a direct relationship between nanohardness and the current density of the ion beam. Stress measurements indicate that stress in the films is increasingly proportional to current density of the ion beam. TEM, XPS, and XRD results indicate that the coated layers consist of FCC structure nanocrystallites with a dimension of about 10 to 20 nm. The Ni and Mo concentration of these coating are lower than those of bulk 316L but the concentration of Cr is higher.

  16. Fracture mechanism of borated stainless steel

    SciTech Connect

    He, J.Y.; Soliman, S.E.; Baratta, A.J.; Balliett, T.A.

    2000-05-01

    The mechanical properties and fracture mechanism of irradiated and unirradiated boron containing Type 304 stainless steel are studied. Four different batches with different boron weight percentages are used. One of these batches was manufactured by a conventional wrought technique, while the others were manufactured by a powder metallurgy technique. The irradiated specimens were subjected to a fluence level of 5 x 10{sup 19} or 1 {times} 10{sup 21} n/m{sup 2}. The mechanical and fracture tests were performed at temperatures of 233, 298, and 533 K. No significant effects on the mechanical properties or fracture behavior were observed as a result of neutron irradiation and/or temperature. The ductility and toughness of the borated steel were found to decrease with increasing boron content. The effect of boride on void nucleation and linkage was found to play an important role in the fracture behavior of borated steel.

  17. 3. INTERIOR VIEW OF SMOKEHOUSE UNIT; NOTE STAINLESS STEEL NOZZLES ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    3. INTERIOR VIEW OF SMOKEHOUSE UNIT; NOTE STAINLESS STEEL NOZZLES THAT INTRODUCED SMOKE INTO UNIT; FLOOR IS UNPAINTED STEEL - Rath Packing Company, Smokehouse-Hog Chilling Building, Sycamore Street between Elm & Eighteenth Streets, Waterloo, Black Hawk County, IA

  18. Nanostructured nickel-free austenitic stainless steel/hydroxyapatite composites.

    PubMed

    Tulinski, Maciej; Jurczyk, Mieczyslaw

    2012-11-01

    In this work Ni-free austenitic stainless steels with nanostructure and their nanocomposites with hydroxyapatite are presented and characterized by means of X-ray diffraction and optical profiling. The samples were synthesized by mechanical alloying, heat treatment and nitriding of elemental microcrystalline powders with addition of hydroxyapatite (HA). In our work we wanted to introduce into stainless steel hydroxyapatite ceramics that have been intensively studied for bone repair and replacement applications. Such applications were chosen because of their high biocompatibility and ability to bond to bone. Since nickel-free austenitic stainless steels seem to have better mechanical properties, corrosion resistance and biocompatibility compared to 316L stainless steels, it is possible that composite made of this steel and HA could improve properties, as well. Mechanical alloying and nitriding are very effective technologies to improve the corrosion resistance of stainless steel. Similar process in case of nanocomposites of stainless steel with hydroxyapatite helps achieve even better mechanical properties and corrosion resistance. Hence nanocrystalline nickel-free stainless steels and nickel-free stainless steel/hydroxyapatite nanocomposites could be promising bionanomaterials for use as a hard tissue replacement implants, e.g., orthopedic implants. In such application, the surface roughness and more specifically the surface topography influences the proliferation of cells (e.g., osteoblasts).

  19. 75 FR 81309 - Stainless Steel Plate from Belgium, Italy, Korea, South Africa, and Taiwan

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-12-27

    ... COMMISSION [Investigation Nos. 701-TA-376 and 379 and 731-TA-788, 790-793 (Second Review)] Stainless Steel... stainless steel plate from Belgium and South Africa and the antidumping duty orders on stainless steel plate... steel plate from Belgium and South Africa and/or the antidumping duty orders on stainless steel...

  20. Coating method enables low-temperature brazing of stainless steel

    NASA Technical Reports Server (NTRS)

    Seaman, F. D.

    1965-01-01

    Gold coated stainless steel tubes containing insulated electrical conductors are brazed at a low temperature to a copper coated stainless steel sealing block with a gold-copper eutectic. This produces an effective seal without using flux or damaging the electrical conductors.

  1. 6. DETAIL VIEW OF SPIN FORM FURNACE FOR STAINLESS STEEL ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    6. DETAIL VIEW OF SPIN FORM FURNACE FOR STAINLESS STEEL FABRICATION. STAINLESS STEEL WAS MACHINED IN SIDE A OF THE BUILDING, BEGINNING IN 1957. (4/24/78) - Rocky Flats Plant, Uranium Rolling & Forming Operations, Southeast section of plant, southeast quadrant of intersection of Central Avenue & Eighth Street, Golden, Jefferson County, CO

  2. 77 FR 23752 - Drawn Stainless Steel Sinks From China

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-04-20

    ... From the Federal Register Online via the Government Publishing Office INTERNATIONAL TRADE COMMISSION Drawn Stainless Steel Sinks From China Determinations On the basis of the record \\1\\ developed in... (April 2012), entitled Drawn Stainless Steel Sinks from China: Investigation Nos. 701-TA-489 and...

  3. THE CLEANING OF 303 STAINLESS STEEL

    SciTech Connect

    Shen, T H

    2004-04-20

    The sulfur found on the surfaces of stainless steel 303 (SS303) after nitric acid passivation originated from the MnS inclusions in the steel. The nitric acid attacked and dissolved these MnS inclusions, and redeposited micron-sized elemental sulfur particles back to the surface. To develop an alternative passivation procedure for SS303, citric and phosphoric acids have been evaluated. The experimental results show neither acid causes a significant amount of sulfur deposit. Thus, these two acids can be used as alternatives to nitric acid passivation for NIF applications. For SS303 previously passivated by nitric acid, NaOH soak can be used as a remedial cleaning process to effectively remove the sulfur deposits.

  4. Attachment of Shiga toxigenic Escherichia coli to stainless steel.

    PubMed

    Rivas, Lucia; Fegan, Narelle; Dykes, Gary A

    2007-04-01

    Shiga toxigenic Escherichia coli (STEC) are important foodborne pathogens causing gastrointestinal disease worldwide. Bacterial attachment to food surfaces, such as stainless steel may lead to cross contamination of foods and subsequent foodborne disease. A variety of STEC isolates, including E. coli O157:H7/H- strains, were grown in planktonic (broth) and sessile (agar) culture, following which initial attachment to stainless steel was determined using epifluorescence microscopy. Experiments were performed to determine whether the number of bacteria attached to stainless steel differed between STEC strains and between the two modes of growth. No relationship was found between STEC strains and the number of bacteria attached to stainless steel. Five STEC strains, including one non-toxigenic O157 isolate, attached in significantly greater (p<0.05) numbers to stainless steel following growth in planktonic culture compared to sessile culture. In contrast, two clinical strains of O157:H7 attached in significantly greater (p<0.05) numbers following growth in sessile culture compared to planktonic culture. Thirteen out of twenty E. coli strains showed no significant difference (p>0.05) in attachment when grown in planktonic or sessile culture. The change of interfacial free energy between the bacterial strains and stainless steel was calculated and the influence of free energy in attachment was determined. Although a significant variation (p<0.05) in free energy values was found between STEC strains, no correlation was found between free energy values and bacterial counts on stainless steel. In addition, no correlation was also found between bacterial hydrophobicity and surface charge values or production of surface structures (type I fimbriae or flagella) (previously determined) with the number of bacteria attached to stainless steel. The results of this study suggest that different growth conditions (planktonic and sessile) can influence the attachment of STEC to

  5. Cast alumina forming austenitic stainless steels

    DOEpatents

    Muralidharan, Govindarajan; Yamamoto, Yukinori; Brady, Michael P

    2013-04-30

    An austenitic stainless steel alloy consisting essentially of, in terms of weight percent ranges 0.15-0.5C; 8-37Ni; 10-25Cr; 2.5-5Al; greater than 0.6, up to 2.5 total of at least one element selected from the group consisting of Nb and Ta; up to 3Mo; up to 3Co; up to 1W; up to 3Cu; up to 15Mn; up to 2Si; up to 0.15B; up to 0.05P; up to 1 total of at least one element selected from the group consisting of Y, La, Ce, Hf, and Zr; <0.3Ti+V; <0.03N; and, balance Fe, where the weight percent Fe is greater than the weight percent Ni, and wherein the alloy forms an external continuous scale comprising alumina, and a stable essentially single phase FCC austenitic matrix microstructure, the austenitic matrix being essentially delta-ferrite free and essentially BCC-phase-free. A method of making austenitic stainless steel alloys is also disclosed.

  6. Antibacterial polyelectrolyte micelles for coating stainless steel.

    PubMed

    Falentin-Daudré, Céline; Faure, Emilie; Svaldo-Lanero, Tiziana; Farina, Fabrice; Jérôme, Christine; Van De Weerdt, Cécile; Martial, Joseph; Duwez, Anne-Sophie; Detrembleur, Christophe

    2012-05-08

    In this study, we report on the original synthesis and characterization of novel antimicrobial coatings for stainless steel by alternating the deposition of aqueous solutions of positively charged polyelectrolyte micelles doped with silver-based nanoparticles with a polyanion. The micelles are formed by electrostatic interaction between two oppositely charged polymers: a polycation bearing 3,4-dihydroxyphenylalanine units (DOPA, a major component of natural adhesives) and a polyanion (poly(styrene sulfonate), PSS) without using any block copolymer. DOPA units are exploited for their well-known ability to anchor to stainless steel and to form and stabilize biocidal silver nanoparticles (Ag(0)). The chlorine counteranion of the polycation forms and stabilizes biocidal silver chloride nanoparticles (AgCl). We demonstrate that two layers of micelles (alternated by PSS) doped with silver particles are enough to impart to the surface strong antibacterial activity against gram-negative E. coli. Moreover, micelles that are reservoirs of biocidal Ag(+) can be easily reactivated after depletion. This novel water-based approach is convenient, simple, and attractive for industrial applications.

  7. Citric Acid Passivation of Stainless Steel

    NASA Technical Reports Server (NTRS)

    Yasensky, David; Reali, John; Larson, Chris; Carl, Chad

    2009-01-01

    Passivation is a process for cleaning and providing corrosion protection for stainless steel. Currently, on Kennedy Space Center (KSC), only parts passivated with nitric acid are acceptable for use. KSC disposes of approximately 125gal of concentrated nitric acid per year, and receives many parts from vendors who must also dispose of used nitric acid. Unfortunately, nitric acid presents health and environmental hazards. As a result, several recent industry studies have examined citric acid as an alternative. Implementing a citric acid-based passivation procedure would improve the health and environmental safety aspects of passivation process. However although there is a lack of published studies that conclusively prove citric acid is a technically sound passivation agent. In 2007, NASA's KSC Materials Advisory Working Group requested the evaluation of citric acid in place of nitric acid for passivation of parts at KSC. United Space Alliance Materials & Processes engineers have developed a three-phase test plan to evaluate citric acid as an alternative to nitric acid on three stainless steels commonly used at KSC: UNS S30400, S41000, and S17400. Phases 1 and 2 will produce an optimized citric acid treatment based on results from atmospheric exposure at NASA's Beach Corrosion Facility. Phase 3 will compare the optimized solution(s) with nitric acid treatments. If the results indicate that citric acid passivates as well or better than nitric acid, NASA intends to approve this method for parts used at the Kennedy Space Center.

  8. Assessment of thermal embrittlement of cast stainless steels

    SciTech Connect

    Chopra, O.K.; Shack, W.J.

    1994-05-01

    A procedure and correlations are presented for assessing thermal embrittlement and predicting Charpy-impact energy and fracture toughness J-R curve of cast stainless steel components under Light Water Reactor operating conditions from known material information. The ``saturation`` impact strength and fracture toughness of a specific cast stainless steel, i.e., the minimum value that would be achieved for the material after long-term service, is estimated from the chemical composition of the steel. Fracture properties as a function of time and temperature of reactor service are estimated from the kinetics of embrittlement, which are also determined from chemical composition. A common ``predicted lower-bound`` J-R curve for cast stainless steels of unknown chemical composition is also defined for a given grade of steel, ferrite content, and temperature. Examples of estimating fracture toughness of cast stainless steel components during reactor service are presented.

  9. Global stainless steel cycle exemplifies China's rise to metal dominance.

    PubMed

    Reck, Barbara K; Chambon, Marine; Hashimoto, Seiji; Graedel, T E

    2010-05-15

    The use of stainless steel, a metal employed in a wide range of technology applications, has been characterized for 51 countries and the world for the years 2000 and 2005. We find that the global stainless steel flow-into-use increased by more than 30% in that 5 year period, as did additions to in-use stocks. This growth was mainly driven by China, which accounted for almost half of the global growth in stainless steel crude production and which tripled its flow into use between 2000 and 2005. The global stainless steel-specific end-of-life recycling rate increased from 66% (2000) to 70% (2005); the landfilling rate was 22% for both years, and 9% (2000) to 12% (2005) was lost into recycled carbon and alloy steels. Within just 5 years, China passed such traditionally strong stainless steel producers and users as Japan, USA, Germany, and South Korea to become the dominant player of the stainless steel industry. However, China did not produce any significant stainless steel end-of-life flows in 2000 or 2005 because its products-in-use are still too new to require replacements. Major Chinese discard flows are expected to begin between 2015 and 2020.

  10. 75 FR 81308 - Stainless Steel Sheet And Strip From Germany, Italy, Japan, Korea, Mexico, And Taiwan

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-12-27

    ... COMMISSION Stainless Steel Sheet And Strip From Germany, Italy, Japan, Korea, Mexico, And Taiwan AGENCY... countervailing duty order on stainless steel sheet and strip from Korea and antidumping duty orders on stainless... on stainless steel sheet and strip from Korea and/or the antidumping duty orders on stainless...

  11. 76 FR 1599 - Stainless Steel Bar From Brazil: Final Results of Antidumping Duty Administrative Review

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-01-11

    ... International Trade Administration Stainless Steel Bar From Brazil: Final Results of Antidumping Duty... results of its administrative review of the antidumping duty order on stainless steel bar from Brazil. The... stainless steel bar (SSB) from Brazil. See Stainless Steel Bar From Brazil: Preliminary Results...

  12. 76 FR 87 - Grant of Authority for Subzone Status; ThyssenKrupp Steel and Stainless USA, LLC; (Stainless and...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-01-03

    ... Foreign-Trade Zones Board Grant of Authority for Subzone Status; ThyssenKrupp Steel and Stainless USA, LLC; (Stainless and Carbon Steel Products) Calvert, AL Pursuant to its authority under the Foreign-Trade Zones Act... establish a special- purpose subzone at the stainless and carbon steel products manufacturing facility...

  13. Subcascade formation ratio in neutron-irradiated stainless steels

    NASA Astrophysics Data System (ADS)

    Yoshiie, T.; Satoh, Y.; Huang, S. S.; Horiki, M.; Sato, K.; Xu, Q.

    2016-01-01

    High-energy-particle irradiation in metals produces cascade damage. If the particle energy is high enough, a cascade is divided into subcascades. In each subcascade, a vacancy rich area is surrounded by an interstitial area. Vacancy clusters are expected to form directly in the vacancy rich area. In this study, the vacancy cluster formation ratio in subcascades was estimated by positron annihilation lifetime spectroscopy and transmission electron microscopy in commercial stainless steels and their model alloys. The vacancy cluster formation ratio was 1.7×10-3 and 9.1×10-5 in austenitic stainless steel and ferritic/martensitic stainless steel, respectively

  14. Materials compatibility of hydride storage materials with austenitic stainless steels

    SciTech Connect

    Clark, E.A.

    1992-09-21

    This task evaluated the materials compatibility of LaNi[sub 5-x]Al[sub x] (x= 0.3, 0.75) hydrides and palladium coated kieselguhr with austenitic stainless steel in hydrogen and tritium process environments. Based on observations of retired prototype hydride storage beds and materials exposure testing samples designed for this study, no materials compatibility problem was indicated. Scanning electron microscopy observations of features on stainless steel surfaces after exposure to hydrides are also commonly found on as-received materials before hydriding. These features are caused by either normal heat treating and acid cleaning of stainless steel or reflect the final machining operation.

  15. Materials compatibility of hydride storage materials with austenitic stainless steels

    SciTech Connect

    Clark, E.A.

    1992-09-21

    This task evaluated the materials compatibility of LaNi{sub 5-x}Al{sub x} (x= 0.3, 0.75) hydrides and palladium coated kieselguhr with austenitic stainless steel in hydrogen and tritium process environments. Based on observations of retired prototype hydride storage beds and materials exposure testing samples designed for this study, no materials compatibility problem was indicated. Scanning electron microscopy observations of features on stainless steel surfaces after exposure to hydrides are also commonly found on as-received materials before hydriding. These features are caused by either normal heat treating and acid cleaning of stainless steel or reflect the final machining operation.

  16. [Study on biocompatibility of MIM 316L stainless steel].

    PubMed

    Wang, Guohui; Zhu, Shaihong; Li, Yiming; Zhao, Yanzhong; Zhou, Kechao; Huang, Boyun

    2007-04-01

    This study was aimed to evaluate the biocompatibility of metal powder injection molding (MIM) 316L stainless steel. The percentage of S-period cells was detected by flow cytometry after L929 cells being incubated with extraction of MIM 316L stainless steel, and titanium implant materials for clinical application were used as control. In addition, both materials were implanted in animals and the histopathological evaluations were carried out. The statistical analyses show that there are no significant differences between the two groups (P > 0.05), which demonstrate that MIM 316L stainless steel has good biocompatibility.

  17. Microbial-Influenced Corrosion of Corten Steel Compared with Carbon Steel and Stainless Steel in Oily Wastewater by Pseudomonas aeruginosa

    NASA Astrophysics Data System (ADS)

    Mansouri, Hamidreza; Alavi, Seyed Abolhasan; Fotovat, Meysam

    2015-07-01

    The microbial corrosion behavior of three important steels (carbon steel, stainless steel, and Corten steel) was investigated in semi petroleum medium. This work was done in modified nutrient broth (2 g nutrient broth in 1 L oily wastewater) in the presence of Pseudomonas aeruginosa and mixed culture (as a biotic media) and an abiotic medium for 2 weeks. The behavior of corrosion was analyzed by spectrophotometric and electrochemical methods and at the end was confirmed by scanning electron microscopy. The results show that the degree of corrosion of Corten steel in mixed culture, unlike carbon steel and stainless steel, is less than P. aeruginosa inoculated medium because some bacteria affect Corten steel less than other steels. According to the experiments, carbon steel had less resistance than Corten steel and stainless steel. Furthermore, biofilm inhibits separated particles of those steels to spread to the medium; in other words, particles get trapped between biofilm and steel.

  18. Automatic Welding of Stainless Steel Tubing

    NASA Technical Reports Server (NTRS)

    Clautice, W. E.

    1978-01-01

    To determine if the use of automatic welding would allow reduction of the radiographic inspection requirement, and thereby reduce fabrication costs, a series of welding tests were performed. In these tests an automatic welder was used on stainless steel tubing of 1/2, 3/4, and 1/2 inch diameter size. The optimum parameters were investigated to determine how much variation from optimum in machine settings could be tolerate and still result in a good quality weld. The process variables studied were the welding amperes, the revolutions per minute as a function of the circumferential weld travel speed, and the shielding gas flow. The investigation showed that the close control of process variables in conjunction with a thorough visual inspection of welds can be relied upon as an acceptable quality assurance procedure, thus permitting the radiographic inspection to be reduced by a large percentage when using the automatic process.

  19. Radiation resistant austenitic stainless steel alloys

    DOEpatents

    Maziasz, P.J.; Braski, D.N.; Rowcliffe, A.F.

    1987-02-11

    An austenitic stainless steel alloy, with improved resistance to radiation-induced swelling and helium embrittlement, and improved resistance to thermal creep at high temperatures, consisting essentially of, by weight percent: from 16 to 18% nickel; from 13 to 17% chromium; from 2 to 3% molybdenum; from 1.5 to 2.5% manganese; from 0.01 to 0.5% silicon; from 0.2 to 0.4% titanium; from 0.1 to 0.2% niobium; from 0.1 to 0.6% vanadium; from 0.06 to 0.12% carbon; from 0.01 to 0.03% nitrogen; from 0.03 to 0.08% phosphorus; from 0.005 to 0.01% boron; and the balance iron, and wherein the alloy may be thermomechanically treated to enhance physical and mechanical properties. 4 figs.

  20. Radiation resistant austenitic stainless steel alloys

    DOEpatents

    Maziasz, Philip J.; Braski, David N.; Rowcliffe, Arthur F.

    1989-01-01

    An austenitic stainless steel alloy, with improved resistance to radiation-induced swelling and helium embrittlement, and improved resistance to thermal creep at high temperatures, consisting essentially of, by weight percent: from 16 to 18% nickel; from 13 to 17% chromium; from 2 to 3% molybdenum; from 1.5 to 2.5% manganese; from 0.01 to 0.5% silicon; from 0.2 to 0.4% titanium; from 0.1 to 0.2% niobium; from 0.1 to 0.6% vanadium; from 0.06 to 0.12% carbon; from 0.01% to 0.03% nitrogen; from 0.03 to 0.08% phosphorus; from 0.005 to 0.01% boron; and the balance iron, and wherein the alloy may be thermomechanically treated to enhance physical and mechanical properties.

  1. Stainless steel anodes for alkaline water electrolysis and methods of making

    SciTech Connect

    Soloveichik, Grigorii Lev

    2014-01-21

    The corrosion resistance of stainless steel anodes for use in alkaline water electrolysis was increased by immersion of the stainless steel anode into a caustic solution prior to electrolysis. Also disclosed herein are electrolyzers employing the so-treated stainless steel anodes. The pre-treatment process provides a stainless steel anode that has a higher corrosion resistance than an untreated stainless steel anode of the same composition.

  2. Evaluation of stainless steels for their resistance to intergranular corrosion

    NASA Astrophysics Data System (ADS)

    Korostelev, A. B.; Abramov, V. Ya.; Belous, V. N.

    1996-10-01

    Austenitic stainless steels are being considered as structural materials for first wall/blanket systems in the International Thermonuclear Reactor (ITER). The uniform corrosion of stainless steels in water is well known and is not a critical issue limiting its application for the ITER design. The sensitivity of austenitic steels to intergranular corrosion (IGC) can be estimated rather accurately by means of calculation methods, considering structure and chemical composition of steel. There is a maximum permissible carbon content level, at which sensitization of stainless steel is eliminated: K = Cr eff - αC eff, where α-thermodynamic coefficient, Cr eff-effective chromium content (regarding molybdenum influence) and C eff-effective carbon content (taking into account nickel and stabilizing elements). Corrosion tests for 16Cr11Ni3MoTi, 316L and 316LN steel specimens, irradiated up to 2 × 10 22 n/cm 2 fluence have proved the effectiveness of this calculation technique for determination of austenitic steels tendency to IGC. This method is directly applicable in austenitic stainless steel production and enables one to exclude complicated experiments on determination of stainless steel susceptibility to IGC.

  3. Phase Transformations in Cast Duplex Stainless Steels

    SciTech Connect

    Kim, Yoon-Jun

    2004-01-01

    Duplex stainless steels (DSS) constitute both ferrite and austenite as a matrix. Such a microstructure confers a high corrosion resistance with favorable mechanical properties. However, intermetallic phases such as σ and χ can also form during casting or high-temperature processing and can degrade the properties of the DSS. This research was initiated to develop time-temperature-transformation (TTT) and continuous-cooling-transformation (CCT) diagrams of two types of cast duplex stainless steels, CD3MN (Fe-22Cr-5Ni-Mo-N) and CD3MWCuN (Fe-25Cr-7Ni-Mo-W-Cu-N), in order to understand the time and temperature ranges for intermetallic phase formation. The alloys were heat treated isothermally or under controlled cooling conditions and then characterized using conventional metallographic methods that included tint etching, and also using electron microscopy (SEM, TEM) and wavelength dispersive spectroscopy (WDS). The kinetics of intermetallic-phase (σ + χ) formation were analyzed using the Johnson-Mehl-Avrami (MA) equation in the case of isothermal transformations and a modified form of this equation in the case of continuous cooling transformations. The rate of intermetallic-phase formation was found to be much faster in CD3MWCuN than CD3MN due mainly to differences in the major alloying contents such as Cr, Ni and Mo. To examine in more detail the effects of these elements of the phase stabilities; a series of eight steel castings was designed with the Cr, Ni and Mo contents systematically varied with respect to the nominal composition of CD3MN. The effects of varying the contents of alloying additions on the formation of intermetallic phases were also studied computationally using the commercial thermodynamic software package, Thermo-Calc. In general, σ was stabilized with increasing Cr addition and χ by increasing Mo addition. However, a delicate balance among Ni and other minor elements such as N and Si also exists. Phase equilibria in DSS can be affected by

  4. Electrolytic etching process provides effective bonding surface on stainless steel

    NASA Technical Reports Server (NTRS)

    1966-01-01

    Electrolytic etching process prepares surfaces of a stainless steel shell for reliable, high strength adhesive bonding to dielectric materials. The process uses a 25 percent aqueous solution of phosphoric acid.

  5. Stainless-steel elbows formed by spin forging

    NASA Technical Reports Server (NTRS)

    1964-01-01

    Large seamless austenitic stainless steel elbows are fabricated by spin forging /rotary shear forming/. A specially designed spin forging tool for mounting on a hydrospin machine has been built for this purpose.

  6. 27. STAINLESS STEEL FERMENTING CASKS MADE BY ZERO MANG OF ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    27. STAINLESS STEEL FERMENTING CASKS MADE BY ZERO MANG OF WASHINGTON, MISSOURI. VIEW LOOKING NORTH TOWARD VAULT OF THE TWELVE APOSTLES - Stone Hill Winery, 401 West Twelfth Street, Hermann, Gasconade County, MO

  7. Stress corrosion cracking evaluation of precipitation-hardening stainless steel

    NASA Technical Reports Server (NTRS)

    Humphries, T. S.; Nelson, E. E.

    1970-01-01

    Accelerated test program results show which precipitation hardening stainless steels are resistant to stress corrosion cracking. In certain cases stress corrosion susceptibility was found to be associated with the process procedure.

  8. Nafion coated stainless steel for anti-biofilm application.

    PubMed

    Zhong, Li Juan; Pang, Li Qing; Che, Li Ming; Wu, Xue E; Chen, Xiao Dong

    2013-11-01

    Biofilms can adhere to most surfaces and have caused a wide range of problems in various industrial processes as well as daily life activities. In this work, the anti-biofilm ability of Nafion-coated stainless steel surface was investigated and our results showed that stainless steel discs coated with 1% Nafion can significantly reduce E. coli adhesion. Nafion has a large amount of negatively charged sulphonate groups, and the findings of this study suggest that the negative surface charge can greatly reduce bacterial adhesion through increasing the electrostatic repulsion between negatively charged bacterial cells and Nafion coated stainless steel surface. The roughness of coated and uncoated stainless steel discs made no significant differences while the hydrophobic of the discs increased after coated with Nafion.

  9. Surface modified stainless steels for PEM fuel cell bipolar plates

    DOEpatents

    Brady, Michael P [Oak Ridge, TN; Wang, Heli [Littleton, CO; Turner, John A [Littleton, CO

    2007-07-24

    A nitridation treated stainless steel article (such as a bipolar plate for a proton exchange membrane fuel cell) having lower interfacial contact electrical resistance and better corrosion resistance than an untreated stainless steel article is disclosed. The treated stainless steel article has a surface layer including nitrogen-modified chromium-base oxide and precipitates of chromium nitride formed during nitridation wherein oxygen is present in the surface layer at a greater concentration than nitrogen. The surface layer may further include precipitates of titanium nitride and/or aluminum oxide. The surface layer in the treated article is chemically heterogeneous surface rather than a uniform or semi-uniform surface layer exclusively rich in chromium, titanium or aluminum. The precipitates of titanium nitride and/or aluminum oxide are formed by the nitriding treatment wherein titanium and/or aluminum in the stainless steel are segregated to the surface layer in forms that exhibit a low contact resistance and good corrosion resistance.

  10. Compressive Strength of Stainless-Steel Sandwiches at Elevated Temperatures

    NASA Technical Reports Server (NTRS)

    Mathauser, Eldon E.; Pride, Richard A.

    1959-01-01

    Experimental results are presented from crippling tests of stainless-steel sandwich specimens in the temperature range from 80 F to 1,200 F. The specimens included resistance-welded 17-7 PH stainless-steel sandwiches with single-corrugated cores, type 301 stainless-steel sandwiches with double-corrugated cores, and brazed 17-7 PH stainless-steel sandwiches with honeycomb cores. The experimental strengths are compared with predicted buckling and crippling strengths. The crippling strengths were predicted from the calculated maximum strength of the individual plate elements of the sandwiches and from a correlation procedure which gives the elevated-temperature crippling strength when the experimental room-temperature crippling strengths are known. Photographs of some of the tested specimens are included to show the modes of failure.

  11. Cavitation erosion of duplex and super duplex stainless steels

    SciTech Connect

    Kwok, C.T.; Man, H.C.; Cheng, F.T.

    1998-10-05

    Owing to their excellent corrosion resistance, stainless steels are widely used both in the marine, urban water, chemical and food industries. In addition to the corrosive environment, high fluid flow speeds are always encountered for components used in these industries. The cavitation characteristics of S30400 and S31600 austenitic stainless steels and duplex stainless steels were studied in detail by a number of authors. It was generally agreed that S30400 has higher cavitation erosion resistance than that of S31600 due to higher tendency of strain induced martensitic transformation under high impulse of stress. A considerable number of results on stress corrosion cracking characteristics of SDSS and duplex stainless steels have been published but data concerning their cavitation erosion property are extremely rare.

  12. Ultrasonics permits brazing complex stainless steel assembly without flux

    NASA Technical Reports Server (NTRS)

    Baker, W. H.

    1967-01-01

    Ultrasonic vibration of an assembly of stainless steel instrumentation tubes ensures brazing without flux. Vibration with an ultrasonic transducer permits the brazing material to flow down each tube in contact with a seal plug installed in a pressure vessel wall.

  13. Eddy sensors for small diameter stainless steel tubes.

    SciTech Connect

    Skinner, Jack L.; Morales, Alfredo Martin; Grant, J. Brian; Korellis, Henry James; LaFord, Marianne Elizabeth; Van Blarigan, Benjamin; Andersen, Lisa E.

    2011-08-01

    The goal of this project was to develop non-destructive, minimally disruptive eddy sensors to inspect small diameter stainless steel metal tubes. Modifications to Sandia's Emphasis/EIGER code allowed for the modeling of eddy current bobbin sensors near or around 1/8-inch outer diameter stainless steel tubing. Modeling results indicated that an eddy sensor based on a single axial coil could effectively detect changes in the inner diameter of a stainless steel tubing. Based on the modeling results, sensor coils capable of detecting small changes in the inner diameter of a stainless steel tube were designed, built and tested. The observed sensor response agreed with the results of the modeling and with eddy sensor theory. A separate limited distribution SAND report is being issued demonstrating the application of this sensor.

  14. Corrosion fatigue of surgical stainless steel in synthetic physiological solution.

    PubMed

    Cahoon, J R; Holte, R N

    1981-03-01

    Fatigue tests conducted both in air and synthetic physiological solution show that the fatigue strength of surgical stainless steel in synthetic physiological solution is about 10% lower than the strength in air for a given endurance level. It is proposed that surgical stainless steel which is normally passive in physiological solution suffers corrosion fatigue because of susceptibility to crevice corrosion which occurs at extrusions and intrusions (crevices) on the surface thereby shortening the crack initiation time and the fatigue life.

  15. Measurement of intergranular attack in stainless steel using ultrasonic energy

    DOEpatents

    Mott, Gerry; Attaar, Mustan; Rishel, Rick D.

    1989-08-08

    Ultrasonic test methods are used to measure the depth of intergranular attack (IGA) in a stainless steel specimen. The ultrasonic test methods include a pitch-catch surface wave technique and a through-wall pulse-echo technique. When used in combination, these techniques can establish the extent of IGA on both the front and back surfaces of a stainless steel specimen from measurements made on only one surface.

  16. Procedure for flaw detection in cast stainless steel

    DOEpatents

    Kupperman, David S.

    1988-01-01

    A method of ultrasonic flaw detection in cast stainless steel components incorporating the steps of determining the nature of the microstructure of the cast stainless steel at the site of the flaw detection measurements by ultrasonic elements independent of the component thickness at the site; choosing from a plurality of flaw detection techniques, one such technique appropriate to the nature of the microstructure as determined and detecting flaws by use of the chosen technique.

  17. Decomposition of energetic chemicals contaminated with iron or stainless steel.

    PubMed

    Chervin, Sima; Bodman, Glenn T; Barnhart, Richard W

    2006-03-17

    Contamination of chemicals or reaction mixtures with iron or stainless steel is likely to take place during chemical processing. If energetic and thermally unstable chemicals are involved in a manufacturing process, contamination with iron or stainless steel can impact the decomposition characteristics of these chemicals and, subsequently, the safety of the processes, and should be investigated. The goal of this project was to undertake a systematic approach to study the impact of iron or stainless steel contamination on the decomposition characteristics of different chemical classes. Differential scanning calorimetry (DSC) was used to study the decomposition reaction by testing each chemical pure, and in mixtures with iron and stainless steel. The following classes of energetic chemicals were investigated: nitrobenzenes, tetrazoles, hydrazines, hydroxylamines and oximes, sulfonic acid derivatives and monomers. The following non-energetic groups were investigated for contributing effects: halogens, hydroxyls, amines, amides, nitriles, sulfonic acid esters, carbonyl halides and salts of hydrochloric acid. Based on the results obtained, conclusions were drawn regarding the sensitivity of the decomposition reaction to contamination with iron and stainless steel for the chemical classes listed above. It was demonstrated that the most sensitive classes are hydrazines and hydroxylamines/oximes. Contamination of these chemicals with iron or stainless steel not only destabilizes them, leading to decomposition at significantly lower temperatures, but also sometimes causes increased severity of the decomposition. The sensitivity of nitrobenzenes to contamination with iron or stainless steel depended upon the presence of other contributing groups: the presence of such groups as acid chlorides or chlorine/fluorine significantly increased the effect of contamination on decomposition characteristics of nitrobenzenes. The decomposition of sulfonic acid derivatives and tetrazoles

  18. X-ray attenuation properties of stainless steel (u)

    SciTech Connect

    Wang, Lily L; Berry, Phillip C

    2009-01-01

    Stainless steel vessels are used to enclose solid materials for studying x-ray radiolysis that involves gas release from the materials. Commercially available stainless steel components are easily adapted to form a static or a dynamic condition to monitor the gas evolved from the solid materials during and after the x-ray irradiation. Experimental data published on the x-ray attenuation properties of stainless steel, however, are very scarce, especially over a wide range of x-ray energies. The objective of this work was to obtain experimental data that will be used to determine how a poly-energetic x-ray beam is attenuated by the stainless steel container wall. The data will also be used in conjunction with MCNP (Monte Carlos Nuclear Particle) modeling to develop an accurate method for determining energy absorbed in known solid samples contained in stainless steel vessels. In this study, experiments to measure the attenuation properties of stainless steel were performed for a range of bremsstrahlung x-ray beams with a maximum energy ranging from 150 keV to 10 MeV. Bremsstrahlung x-ray beams of these energies are commonly used in radiography of engineering and weapon components. The weapon surveillance community has a great interest in understanding how the x-rays in radiography affect short-term and long-term properties of weapon materials.

  19. Performance of ferritic stainless steels for automobile muffler corrosion

    SciTech Connect

    Tarutani, Y.; Hashizume, T.

    1995-11-01

    Corrosion behavior of ferritic stainless steels was studied in artificial exhaust gas condensates containing corrosive ions such as Cl{sup {minus}} and SO{sub 3}{sup 2{minus}}. Continuous immersion tests in flasks and Dip and Dry tests by using the alternate corrosion tester with a heating system clarified the effects of chromium and molybdenum additions on the corrosion resistance of a ferritic stainless steel in the artificial exhaust gas condensates. Effects of surface oxidation on the corrosion behavior were investigated in a temperature range of 573K to 673K. Oxidation of 673K reduced the corrosion resistance of the ferritic stainless steels in the artificial environment of the automobile muffler. Particulate matter deposited on the muffler inner shell from the automobile exhaust gas was also examined. Deposited particulate matter increased the corrosion rate of the ferritic stainless steel. Finally, the authors also investigated the corrosion of the automobile mufflers made of Type 436L ferritic stainless steel with 18% chromium-1.2% molybdenum after 24 months, in Japan. The sets of results clarified that Type 436L ferritic stainless steel as the material for the automobile muffler exhibited acceptable corrosion resistance.

  20. Microstructure, Properties and Weldability of Duplex Stainless Steel 2101

    NASA Astrophysics Data System (ADS)

    Ma, Li; Hu, Shengsun; Shen, Junqi

    2017-01-01

    The continuous development of duplex stainless steels (DSSs) is due to their excellent corrosion resistance in aggressive environments and their mechanical strength, which is usually twice of conventional austenitic stainless steels (ASSs). In this paper, a designed lean duplex stainless steel 2101, with the alloy design of reduced nickel content and increased additions of manganese and nitrogen, is studied by being partly compared with typical ASS 304L steels. The microstructure, mechanical properties, impact toughness, corrosion resistance and weldability of the designed DSS 2101 were conducted. The results demonstrated that both 2101 steel and its weldment show excellent mechanical properties, impact toughness and corrosion resistance, so DSS 2101 exhibits good comprehensive properties and can be used to replace 304L in numerous applications.

  1. Fabrication of stainless steel clad tubing. [gas pressure bonding

    NASA Technical Reports Server (NTRS)

    Kovach, C. W.

    1978-01-01

    The feasibility of producing stainless steel clad carbon steel tubing by a gas pressure bonding process was evaluated. Such a tube product could provide substantial chromium savings over monolithic stainless tubing in the event of a serious chromium shortage. The process consists of the initial assembly of three component tubesets from conventionally produced tubing, the formation of a strong metallurgical bond between the three components by gas pressure bonding, and conventional cold draw and anneal processing to final size. The quality of the tubes produced was excellent from the standpoint of bond strength, mechanical, and forming properties. The only significant quality problem encountered was carburization of the stainless clad by the carbon steel core which can be overcome by further refinement through at least three different approaches. The estimated cost of clad tubing produced by this process is greater than that for monolithic stainless tubing, but not so high as to make the process impractical as a chromium conservation method.

  2. Creep cavitation in 304 stainless steel

    SciTech Connect

    Chen, I.W.; Argon, A.S.

    1981-01-01

    Creep cavitation in 304 stainless steel at 0.5 T/sub m/ was investigated. Two specially developed techniques were used to study the nucleation and growth of grain-boundary cavities. It was found that cavities nucleated heterogeneously throughout the creep history and those observed were well in their growth stage. Comparison of these observations with the theory for cavity nucleation requires that a high interfacial stress be present. Experiments suggest that such stress concentrations are present in the early stages of boundary sliding, and in additional transients associated with intermittent sliding of boundaries throughout the creep life. It was found that microstructural variations such as those caused by twins which strongly affect initial particle densities on boundaries can alter cavitation behavior drastically. Our results also show that wedge cracks are the result of accelerated linking of growing cavities in the triple point region of stress concentration and are not a separate phenomenon. Furthermore, at higher strain rates growth of cavities can be accelerated by grain boundary sliding. Lastly, evidence is given to support the view that in engineering alloys which contain complex phas constitutents particularly along grain-boundaries, cavitation in long term service is likely to be caused by cavities nucleated in connection with a prior cold forming operation. 15 figures.

  3. Micro-electrospray with stainless steel emitters.

    PubMed

    Shui, Wenqing; Yu, Yanling; Xu, Xuejiao; Huang, Zhenyu; Xu, Guobing; Yang, Pengyuan

    2003-01-01

    The physical processes underlying micro-electrospray (micro-ES) performance were investigated using a stainless steel (SS) emitter with a blunt tip. Sheathless micro-ES could be generated at a blunt SS tip without any tapering or sanding if ESI conditions were optimized. The Taylor cone was found to shrink around the inner diameter of the SS tubing, which permitted a low flow rate of 150 nL/min for sheathless microspray on the blunt tip (100 microm i.d. x 400 microm o.d.). It is believed that the wettability and/or hydrophobicity of SS tips are responsible for their micro-ES performance. The outlet orifice was further nipped to reduce the size of the spray cone and limit the flow rate to 50-150 nL/min, resulting in peptide detection down to attomole quantities consumed per spectrum. The SS emitter was also integrated into a polymethylmethacrylate microchip and demonstrated satisfactory performance in the analysis and identification of a myoglobin digest.

  4. Welding Behavior of Free Machining Stainless Steel

    SciTech Connect

    BROOKS,JOHN A.; ROBINO,CHARLES V.; HEADLEY,THOMAS J.; MICHAEL,JOSEPH R.

    2000-07-24

    The weld solidification and cracking behavior of sulfur bearing free machining austenitic stainless steel was investigated for both gas-tungsten arc (GTA) and pulsed laser beam weld processes. The GTA weld solidification was consistent with those predicted with existing solidification diagrams and the cracking response was controlled primarily by solidification mode. The solidification behavior of the pulsed laser welds was complex, and often contained regions of primary ferrite and primary austenite solidification, although in all cases the welds were found to be completely austenite at room temperature. Electron backscattered diffraction (EBSD) pattern analysis indicated that the nature of the base metal at the time of solidification plays a primary role in initial solidification. The solid state transformation of austenite to ferrite at the fusion zone boundary, and ferrite to austenite on cooling may both be massive in nature. A range of alloy compositions that exhibited good resistance to solidification cracking and was compatible with both welding processes was identified. The compositional range is bounded by laser weldability at lower Cr{sub eq}/Ni{sub eq} ratios and by the GTA weldability at higher ratios. It was found with both processes that the limiting ratios were somewhat dependent upon sulfur content.

  5. Austenitic stainless steel for high temperature applications

    DOEpatents

    Johnson, Gerald D.; Powell, Roger W.

    1985-01-01

    This invention describes a composition for an austenitic stainless steel which has been found to exhibit improved high temperature stress rupture properties. The composition of this alloy is about (in wt. %): 12.5 to 14.5 Cr; 14.5 to 16.5 Ni; 1.5 to 2.5 Mo; 1.5 to 2.5 Mn; 0.1 to 0.4 Ti; 0.02 to 0.08 C; 0.5 to 1.0 Si; 0.01 maximum, N; 0.02 to 0.08 P; 0.002 to 0.008 B; 0.004-0.010 S; 0.02-0.05 Nb; 0.01-0.05 V; 0.005-0.02 Ta; 0.02-0.05 Al; 0.01-0.04 Cu; 0.02-0.05 Co; 0.03 maximum, As; 0.01 maximum, O; 0.01 maximum, Zr; and with the balance of the alloy being essentially iron. The carbon content of the alloy is adjusted such that wt. % Ti/(wt. % C+wt. % N) is between 4 and 6, and most preferably about 5. In addition the sum of the wt. % P+wt. % B+wt. % S is at least 0.03 wt. %. This alloy is believed to be particularly well suited for use as fast breeder reactor fuel element cladding.

  6. Weldable, age hardenable, austenitic stainless steel

    DOEpatents

    Brooks, J.A.; Krenzer, R.W.

    1975-07-22

    An age hardenable, austenitic stainless steel having superior weldability properties as well as resistance to degradation of properties in a hydrogen atmosphere is described. It has a composition of from about 24.0 to about 34.0 weight percent (w/o) nickel, from about 13.5 to about 16.0 w/o chromium, from about 1.9 to about 2.3 w/o titanium, from about 1.0 to about 1.5 w/ o molybdenum, from about 0.01 to about 0.05 w/o carbon, from about 0 to about 0.25 w/o manganese, from about 0 to about 0.01 w/o phosphorous and preferably about 0.005 w/o maximum, from about 0 to about 0.010 w/o sulfur and preferably about 0.005 w/o maximum, from about 0 to about 0.25 w/o silicon, from about 0.1 to about 0.35 w/o aluminum, from about 0.10 to about 0.50 w/o vanadium, from about 0 to about 0.0015 w/o boron, and the balance essentially iron. (auth)

  7. Corrosion of stainless steel during acetate production

    SciTech Connect

    Qi, J.S.; Lester, G.C.

    1996-07-01

    Corrosion of types 304, 304L, 316, and 316L stainless steel (SS) during the esterification of acetic acid and alcohol or glycol ether was investigated. The catalyst for this reaction, sulfuric acid or para-toluene sulfonic acid (PTSA), was shown to cause more corrosion on reactor equipment than CH{sub 3}COOH under the process conditions commonly practiced in industry. The corrosive action of the catalyst occurred only in the presence of water. Thus, for the batch processes, corrosion occurred mostly during the initial stage of esterification, where water produced by the reaction created an aqueous environment. After water was distilled off, the corrosion rate declined to a negligible value. The corrosion inhibitor copper sulfate, often used in industrial acetate processes, was found to work well for a low-temperature process (< 95 C) such as in production of butyl acetate, but it accelerated corrosion in the glycol ether acetate processes where temperatures were > 108 C. Process conditions that imparted low corrosion rates were determined.

  8. NanoComposite Stainless Steel Powder Technologies

    SciTech Connect

    DeHoff, R.; Glasgow, C.

    2012-07-25

    Oak Ridge National Laboratory has been investigating a new class of Fe-based amorphous material stemming from a DARPA, Defense Advanced Research Projects Agency initiative in structural amorphous metals. Further engineering of the original SAM materials such as chemistry modifications and manufacturing processes, has led to the development of a class of Fe based amorphous materials that upon processing, devitrify into a nearly homogeneous distribution of nano sized complex metal carbides and borides. The powder material is produced through the gas atomization process and subsequently utilized by several methods; laser fusing as a coating to existing components or bulk consolidated into new components through various powder metallurgy techniques (vacuum hot pressing, Dynaforge, and hot isostatic pressing). The unique fine scale distribution of microstructural features yields a material with high hardness and wear resistance compared to material produced through conventional processing techniques such as casting while maintaining adequate fracture toughness. Several compositions have been examined including those specifically designed for high hardness and wear resistance and a composition specifically tailored to devitrify into an austenitic matrix (similar to a stainless steel) which poses improved corrosion behavior.

  9. 75 FR 30434 - Stainless Steel Plate From Belgium, Italy, Korea, South Africa, and Taiwan

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-06-01

    ... COMMISSION [Investigation Nos. 701-TA-376 and 379 and 731-TA-788, 790-793 (Second Review)] Stainless Steel... steel plate from Belgium and South Africa and the antidumping duty orders on stainless steel plate from... determine whether revocation of the countervailing duty orders on stainless steel plate from Belgium...

  10. 78 FR 34644 - Stainless Steel Plate in Coils From Belgium: Preliminary Results of Antidumping Duty...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-06-10

    ... International Trade Administration Stainless Steel Plate in Coils From Belgium: Preliminary Results of... administrative review of the antidumping duty order on stainless steel plate in coils (steel plate) from Belgium...: Scope of the Order The product covered by this order is certain stainless steel plate in...

  11. From flint to stainless steel: observations on surgical instrument composition.

    PubMed Central

    Kirkup, J.

    1993-01-01

    Man's failure to extract deeply embedded thorns and arrowheads, with bare hands and teeth, stimulated 'instrument substitutes' mimicking these appendages. Evidence from primitive communities suggest animal, plant and mineral items were employed, both before and after metal became the standard material of today's armamentarium. Changing surgical instrument composition has mirrored concurrent technology and manufacturing methods both of which are reviewed. Particular significance is accorded flint, bronze, crucible steel, thermal sterilisation, nickel-plate, stainless steel and disposable plastics. The paper is based on an exhibition From Flint to Stainless Steel on display at the College. Images Figure 1 Figure 2 Figure 3 Figure 4 Figure 5 PMID:8215156

  12. Stainless steel tube-based cell cryopreservation containers.

    PubMed

    Shih, Wei-Hung; Yu, Zong-Yan; Wu, Wei-Te

    2013-12-01

    This study focused on increasing the freezing rate in cell vitrification cryopreservation by using a cryopreservation container possessing rigid mechanical properties and high heat-transfer efficiency. Applying a fast freezing rate in vitrification cryopreservation causes a rapid temperature change in the cryopreservation container and has a substantial impact on mechanical properties; therefore, a highly rigid cryopreservation container that possesses a fast freezing rate must be developed. To produce a highly rigid cryopreservation container possessing superior heat transfer efficiency, this study applies an electrochemical machining (ECM) method to an ANSI 316L stainless steel tube to treat the surface material by polishing and roughening, thereby increasing the freezing rate and reducing the probability of ice crystal formation. The results indicated that the ECM method provided high-quality surface treatment of the stainless steel tube. This method can reduce internal surface roughness in the stainless steel tube, thereby reducing the probability of ice crystal formation, and increase external surface roughness, consequently raising convection heat-transfer efficiency. In addition, by thinning the stainless steel tube, this method reduces heat capacity and thermal resistance, thereby increasing the freezing rate. The freezing rate (3399 ± 197 °C/min) of a stainless steel tube after interior and exterior polishing and exterior etching by applying ECM compared with the freezing rate (1818 ± 54 °C/min) of an original stainless steel tube was increased by 87%, which also exceeds the freezing rate (2015 ± 49 °C/min) of an original quartz tube that has a 20% lower heat capacity. However, the results indicated that increasing heat-transferring surface areas and reducing heat capacities cannot effectively increase the freezing rate of a stainless steel tube if only one method is applied; instead, both techniques must be implemented concurrently to improve the

  13. Stress Relaxation in Tensile Deformation of 304 Stainless Steel

    NASA Astrophysics Data System (ADS)

    Li, Xifeng; Li, Jiaojiao; Ding, Wei; Zhao, Shuangjun; Chen, Jun

    2017-01-01

    Improved ductility by stress relaxation has been reported in different kinds of steels. The influence of stress relaxation and its parameters on the ductility of 304 stainless steel has not been established so far. Stress relaxation behavior during tensile tests at different strain rates is studied in 304 stainless steel. It is observed that stress relaxation can obviously increase the elongation of 304 stainless steel in all cases. The elongation improvement of interrupted tension reaches to 14.9% compared with monotonic tension at 0.05 s-1. Contradicting with the published results, stress drop during stress relaxation increases with strain at all strain rates. It is related with dislocation motion velocity variation and martensitic transformation.

  14. Machinability of a Stainless Steel by Electrochemical Discharge Microdrilling

    SciTech Connect

    Coteata, Margareta; Pop, Nicolae; Slatineanu, Laurentiu; Schulze, Hans-Peter; Besliu, Irina

    2011-05-04

    Due to the chemical elements included in their structure for ensuring an increased resistance to the environment action, the stainless steels are characterized by a low machinability when classical machining methods are applied. For this reason, sometimes non-traditional machining methods are applied, one of these being the electrochemical discharge machining. To obtain microholes and to evaluate the machinability by electrochemical discharge microdrilling, test pieces of stainless steel were used for experimental research. The electrolyte was an aqueous solution of sodium silicate with different densities. A complete factorial plan was designed to highlight the influence of some input variables on the sizes of the considered machinability indexes (electrode tool wear, material removal rate, depth of the machined hole). By mathematically processing of experimental data, empirical functions were established both for stainless steel and carbon steel. Graphical representations were used to obtain more suggestive vision concerning the influence exerted by the considered input variables on the size of the machinability indexes.

  15. Magnetic properties of stainless steels at room and cryogenic temperatures

    NASA Astrophysics Data System (ADS)

    Oxley, Paul; Goodell, Jennifer; Molt, Robert

    2009-07-01

    The magnetic properties of ten types of ferritic and martensitic stainless steels have been measured at room temperature and at 77 K. The steel samples studied were in the annealed state as received from the manufacturer. Our room temperature measurements indicate significantly harder magnetic properties than those quoted in the ASM International Handbook, which studied fully annealed stainless steel samples. Despite having harder magnetic properties than fully annealed steels some of the as-received steels still display soft magnetic properties adequate for magnetic applications. The carbon content of the steels was found to affect the permeability and coercive force, with lower-carbon steels displaying significantly higher permeability and lower coercive force. The decrease in coercive force with reduced carbon content is attributed to fewer carbide inclusions which inhibit domain wall motion. Cooling to 77 K resulted in harder magnetic properties. Averaged over the ten steels tested the maximum permeability decreased by 8%, the coercive force increased by 14%, and the residual and saturation flux densities increased by 4% and 3%, respectively. The change in coercive force when cooled is comparable to the theoretical prediction for iron, based on a model of domain wall motion inhibited by inclusions. The modest changes of the magnetic properties indicate that the stainless steels can still be used in magnetic applications at very low temperatures.

  16. [Restoration of composite on etched stainless steel crowns. (1)].

    PubMed

    Goto, G; Zang, Y; Hosoya, Y

    1990-01-01

    Object of investigation The retention of composite resin to etched stainless steel crowns was tested as a possible method for restoring primary anterior teeth. Method employed 1) SEM observation Stainless steel crowns (Sankin Manufacture Co.) were etched with an aqua resia to create surface roughness and undercut to retain the composite resin to the crowns. Etching times were 1, 2, 3, 5, 8, 10 and 20 minutes, then washed in a 70% alcohol solution using an ultrasonic washer and dried. A total of 96 etched samples and non etched control samples were observed through the scanning electron microscope (Hitachi 520). 2) Shear bond strength test Stainless steel crowns were etched in an aqua resia from 1 to 20 minutes, then washed and dried. Composite resin (Photo Clearfil A, Kuraray Co.) with the bonding agent was placed on the crowns and the shear bond strength was tested in 56 samples using an Autograph (DCS-500, Shimazu). Results 1) SEM observation showed that the etching surface of stainless steel crowns created surface roughness and undercut. The most desirable surface was obtained in the 3 to 5 minute etching time specimens. 2) The highest bond strength was obtained in a 3 minute etching specimen. It was 42.12 MPa, although 29.26 MPa in mean value. Conclusion Etching with an aqua resia increased the adherence of composite resin to the surface of stainless steel crowns.

  17. Work of adhesion of dairy products on stainless steel surface

    PubMed Central

    Bernardes, Patrícia Campos; Araújo, Emiliane Andrade; dos Santos Pires, Ana Clarissa; Queiroz Fialho Júnior, José Felício; Lelis, Carini Aparecida; de Andrade, Nélio José

    2012-01-01

    The adhesion of the solids presents in food can difficult the process of surface cleaning and promotes the bacterial adhesion process and can trigger health problems. In our study, we used UHT whole milk, chocolate based milk and infant formula to evaluate the adhesion of Enterobacter sakazakii on stainless steel coupons, and we determine the work of adhesion by measuring the contact angle as well as measured the interfacial tension of the samples. In addition we evaluated the hydrophobicity of stainless steel after pre-conditioning with milk samples mentioned. E. sakazakii was able to adhere to stainless steel in large numbers in the presence of dairy products. The chocolate based milk obtained the lower contact angle with stainless steel surface, higher interfacial tension and consequently higher adhesion work. It was verified a tendency of decreasing the interfacial tension as a function of the increasing of protein content. The preconditioning of the stainless steel coupons with milk samples changed the hydrophobic characteristics of the surfaces and became them hydrophilic. Therefore, variations in the composition of the milk products affect parameters important that can influence the procedure of hygiene in surface used in food industry. PMID:24031951

  18. Aging of cast duplex stainless steels in LWR systems

    SciTech Connect

    Chopra, O.K.; Chung, H.M.

    1984-10-01

    A program is being conducted to investigate the significance of in-service embrittlement of cast duplex stainless steels under light-water reactor operating conditions. The existing data are evaluated to determine the expected embrittlement of cast components during the operating lifetime of reactors and to define the objectives and scope of the investigation. This presentation describes the status of the program. Data for the metallurgical characterization of the various cast stainless steels used in the investigation are presented. Charpy impact tests on short-term aged material indicate that CF-3 stainless steels are less susceptible to embrittlement than CF-8 or CF-8M stainless steels. Microstructural characterization of cast stainless steels that were obtained from Georg Fischer Co. and aged for up to 70,000 h at 300, 350, and 400/sup 0/C reveals the formation of four different types of precipitates that are not ..cap alpha..'. Embrittlement of the ferrite phase is primarily due to pinning of the dislocations by two of these precipitates, designated as Type M and Type X. The ferrite phase is embrittled after approx. 8 y at 300/sup 0/C and shows cleavage fracture. Examination of the fracture surfaces of the impact-test specimens indicates that the toughness of the long-term aged material is determined by the austenite phase. 8 figures, 3 tables.

  19. Antibacterial effect of silver nanofilm modified stainless steel surface

    NASA Astrophysics Data System (ADS)

    Fang, F.; Kennedy, J.; Dhillon, M.; Flint, S.

    2015-03-01

    Bacteria can attach to stainless steel surfaces, resulting in the colonization of the surface known as biofilms. The release of bacteria from biofilms can cause contamination of food such as dairy products in manufacturing plants. This study aimed to modify stainless steel surfaces with silver nanofilms and to examine the antibacterial effectiveness of the modified surface. Ion implantation was applied to produce silver nanofilms on stainless steel surfaces. 35 keV Ag ions were implanted with various fluences of 1 × 1015 to 1 × 1017 ions•cm-2 at room temperature. Representative atomic force microscopy characterizations of the modified stainless steel are presented. Rutherford backscattering spectrometry spectra revealed the implanted atoms were located in the near-surface region. Both unmodified and modified stainless steel coupons were then exposed to two types of bacteria, Pseudomonas fluorescens and Streptococcus thermophilus, to determine the effect of the surface modification on bacterial attachment and biofilm development. The silver modified coupon surface fluoresced red over most of the surface area implying that most bacteria on coupon surface were dead. This study indicates that the silver nanofilm fabricated by the ion implantation method is a promising way of reducing the attachment of bacteria and delay biofilm formation.

  20. DETECTION OF BACTERIAL BIOFILM ON STAINLESS STEEL BY HYPERSPECTRAL FLUORESCENCE IMAGING

    Technology Transfer Automated Retrieval System (TEKTRAN)

    In this study, hyperspectral fluorescence imaging techniques were investigated for detection of microbial biofilm on stainless steel plates typically used to manufacture food processing equipment. Stainless steel coupons were immersed in bacterium cultures consisting of nonpathogenic E. coli, Pseudo...

  1. Evaluation of Direct Diode Laser Deposited Stainless Steel 316L on 4340 Steel Substrate for Aircraft Landing Gear Application

    DTIC Science & Technology

    2010-03-01

    AFRL-RX-WP-TP-2010-4149 EVALUATION OF DIRECT DIODE LASER DEPOSITED STAINLESS STEEL 316L ON 4340 STEEL SUBSTRATE FOR AIRCRAFT LANDING GEAR...March 2010 – 01 March 2010 4. TITLE AND SUBTITLE EVALUATION OF DIRECT DIODE LASER DEPOSITED STAINLESS STEEL 316L ON 4340 STEEL SUBSTRATE FOR...Code) N/A Standard Form 298 (Rev. 8-98) Prescribed by ANSI Std. Z39-18 Evaluation of Direct Diode Laser Deposited Stainless Steel 316L on

  2. Wastewater minimization at a stainless steel manufacturing facility

    SciTech Connect

    Hayward-Browne, A.; Ackroyd, D.S.; Dave, B.B.

    1996-08-01

    As the environmental regulations associated with discharging water from industrial installations become increasingly more stringent and water in some areas becomes more scarce, water costs, both for purchase and disposal, become increasingly more expensive. So the importance of reusing and recycling water is heightened. This paper investigates the desire of a stainless steel manufacturing plant to improve the final product surface quality. Simple upgrading of the once-through rinsing process would have presented operational problems for the on-site effluent treatment plant and exceeded site discharge limits. A more innovative approach was sought. Explained are the stages taken to audit the plant, the initial work in proposing water recycle options and a computer modeling methodology for predicting water chemistry and economics. In conclusion, the stainless steel manufacturer discusses the implementation of the recycle project. Not only are the operational demands met, but the recycle option actually provides a return on investment to the stainless steel manufacturer rather than an additional cost.

  3. Practical handbook of stainless steels and nickel alloys

    SciTech Connect

    Lamb, S.

    1999-07-01

    This new handbook is an up-to-date technical guide to the grades, properties, fabrication characteristics, and applications of stainless steels and nickel alloys. The individual chapters were written by industry experts and focus on the key properties and alloy characteristics important in material selection and specification as well as the practical factors that influence the development and application of these materials. The contents include: alloy grades and their welding and fabrication characteristics and their application; monel metal; iron-based and nickel-based alloys; ferritic, austenitic, superaustenitic, and martensitic stainless steels; hastelloys; alloys 20, G, and 825; AOD and new refining technology; duplex stainless steels; 6-Mo alloys; corrosion-resistant castings; specification cross-reference tables; trade names; hardness conversions; list of common abbreviations.

  4. Guided growth by a stainless-steel tubular plate.

    PubMed

    Lin, Tung-Yi; Kao, Hsuan-Kai; Li, Wei-Chun; Yang, Wen-E; Chang, Chia-Hsieh

    2013-07-01

    Guided growth using titanium tension band plates is an advancement in the correction of angular deformity. We applied two-hole stainless-steel one-third tubular plates for the same purpose. There were 14 deformities around the knees in eight children, mean age 10.8 years at operation. The success rate was 92.9% (13/14). The average correction rate per month was 0.59° in the femur and 0.65° in the tibia. No premature physeal arrest, overcorrection, or rebound phenomenon was observed. A stainless-steel plate is a safe and effective option for guided growth surgery in countries where only stainless-steel plates are available.

  5. Evaluation of Additive Manufacturing for Stainless Steel Components

    SciTech Connect

    Peter, William H.; Lou, Xiaoyuan; List, III, Frederick Alyious; Webber, David

    2016-09-01

    This collaboration between Oak Ridge National Laboratory and General Electric Company aimed to evaluate the mechanical properties, microstructure, and porosity of the additively manufactured 316L stainless steel by ORNL’s Renishaw AM250 machine for nuclear application. The program also evaluated the stress corrosion cracking and corrosion fatigue crack growth rate of the same material in high temperature water environments. Results show the properties of this material to be similar to the properties of 316L stainless steel fabricated additively with equipment from other manufacturers with slightly higher porosity. The stress corrosion crack growth rate is similar to that for wrought 316L stainless steel for an oxygenated high temperature water environment and slightly higher for a hydrogenated high temperature water environment. Optimized heat treatment of this material is expected to improve performance in high temperature water environments.

  6. 76 FR 50495 - Stainless Steel Plate From Belgium, Italy, Korea, South Africa, and Taiwan

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-08-15

    ... COMMISSION Stainless Steel Plate From Belgium, Italy, Korea, South Africa, and Taiwan Determinations On the.... 1675(c)), that revocation of the countervailing duty order on stainless steel plate from South Africa and revocation of the antidumping duty orders on stainless steel plate from Belgium, Korea,...

  7. 75 FR 32503 - Stainless Steel Wire Rod From Italy, Japan, Korea, Spain, and Taiwan

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-06-08

    ... COMMISSION Stainless Steel Wire Rod From Italy, Japan, Korea, Spain, and Taiwan Determinations On the basis...)), that revocation of the antidumping duty orders on stainless steel wire rod from Italy, Japan, Korea... contained in USITC Publication 4154 (May 2010), entitled Stainless Steel Wire Rod from Italy, Japan,...

  8. 77 FR 27815 - Aging Management of Stainless Steel Structures and Components in Treated Borated Water

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-05-11

    ... COMMISSION Aging Management of Stainless Steel Structures and Components in Treated Borated Water AGENCY..., ``Aging Management of Stainless Steel Structures and Components in Treated Borated Water.'' This LR-ISG... stainless steel structures and components exposed to treated borated water. The NRC published Revision 2...

  9. 77 FR 39735 - Stainless Steel Butt-Weld Pipe Fittings From Italy, Malaysia, and the Philippines

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-07-05

    ...)] Stainless Steel Butt-Weld Pipe Fittings From Italy, Malaysia, and the Philippines Determination On the basis...)), that revocation of the antidumping duty orders on stainless steel butt-weld pipe fittings From Italy... the Commission are contained in USITC Publication 4337 (June 2012), entitled Stainless Steel...

  10. 75 FR 53714 - Stainless Steel Butt-Weld Pipe Fittings From Japan, Korea, and Taiwan

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-09-01

    ... 564 (Third Review)] Stainless Steel Butt-Weld Pipe Fittings From Japan, Korea, and Taiwan AGENCY... antidumping duty orders on stainless steel butt-weld pipe fittings from Japan, Korea, and Taiwan. SUMMARY: The... stainless steel butt-weld pipe fittings from Japan, Korea, and Taiwan would be likely to lead...

  11. 76 FR 69292 - Aging Management of Stainless Steel Structures and Components in Treated Borated Water

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-11-08

    ... COMMISSION Aging Management of Stainless Steel Structures and Components in Treated Borated Water AGENCY... Staff Guidance (LR-ISG), LR- ISG-2011-01, ``Aging Management of Stainless Steel Structures and... Learned (GALL) Report for the aging management of stainless steel structures and components exposed...

  12. 77 FR 3231 - Certain Stainless Steel Wire Rods From India: Continuation of Antidumping Duty Order

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-01-23

    ... Stainless Steel Wire Rods From India: Continuation of Antidumping Duty Order AGENCY: Import Administration... antidumping duty order on certain stainless steel wire rods from India would likely lead to continuation or... reviews of the antidumping duty order on certain stainless steel wire rods (``wire rods'') from...

  13. 75 FR 30437 - Stainless Steel Sheet and Strip From Germany, Italy, Japan, Korea, Mexico, and Taiwan

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-06-01

    ... COMMISSION Stainless Steel Sheet and Strip From Germany, Italy, Japan, Korea, Mexico, and Taiwan AGENCY... countervailing duty order on stainless steel sheet and strip from Korea and the antidumping duty orders on stainless steel sheet and strip from Germany, Italy, Japan, Korea, Mexico, and Taiwan. SUMMARY:...

  14. 75 FR 59744 - Stainless Steel Plate From Belgium, Italy, Korea, South Africa, and Taiwan

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-09-28

    ... COMMISSION [Investigation Nos. 701-TA-376 and 379 and 731-TA-788, 790-793 (Second Review)] Stainless Steel... countervailing duty orders on stainless steel plate from Belgium and South Africa and the antidumping duty orders on stainless steel plate from Belgium, Italy, Korea, South Africa, and Taiwan. SUMMARY:...

  15. 75 FR 59744 - Stainless Steel Sheet and Strip From Germany, Italy, Japan, Korea, Mexico, and Taiwan

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-09-28

    ... COMMISSION Stainless Steel Sheet and Strip From Germany, Italy, Japan, Korea, Mexico, and Taiwan AGENCY... five-year reviews concerning the countervailing duty order on stainless steel sheet and strip from Korea and the antidumping duty orders on stainless steel sheet and strip from Germany, Italy,...

  16. 77 FR 60673 - Drawn Stainless Steel Sinks From the People's Republic of China: Antidumping Duty Investigation

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-10-04

    ... International Trade Administration Drawn Stainless Steel Sinks From the People's Republic of China: Antidumping...'') preliminarily determines that drawn stainless steel sinks (``drawn sinks'') from the People's Republic of China... unfinished, regardless of type of finish, gauge, or grade of stainless steel. Mounting clips,...

  17. 76 FR 49726 - Continuation of Antidumping and Countervailing Duty Orders: Stainless Steel Sheet and Strip in...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-08-11

    ... International Trade Administration Continuation of Antidumping and Countervailing Duty Orders: Stainless Steel... stainless steel sheet and strip in coils from Japan, Korea, and Taiwan would likely lead to continuation or recurrence of dumping, that revocation of the countervailing duty (``CVD'') order on stainless steel...

  18. 75 FR 64709 - Stainless Steel Plate in Coils From Belgium: Notice of Rescission of Antidumping Duty...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-10-20

    ... International Trade Administration Stainless Steel Plate in Coils From Belgium: Notice of Rescission of... ``Opportunity to Request Administrative Review'' of the antidumping duty order on stainless steel plate in coils... of an administrative review of the antidumping duty order on stainless steel plate in coils...

  19. 76 FR 31588 - Stainless Steel Plate in Coils From Belgium: Rescission of Countervailing Duty Administrative Review

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-06-01

    ... International Trade Administration Stainless Steel Plate in Coils From Belgium: Rescission of Countervailing... countervailing duty (``CVD'') order on stainless steel plate in coils from Belgium. See Antidumping or... initiating an administrative review of the CVD order on stainless steel plate in coils from Belgium...

  20. 77 FR 39467 - Stainless Steel Bar From India: Final Results of the Antidumping Duty Administrative Review

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-07-03

    ... International Trade Administration Stainless Steel Bar From India: Final Results of the Antidumping Duty... the administrative review of the antidumping duty order on stainless steel bar from India. The review..., 2012, the Department published Stainless Steel Bar From India: Preliminary Results and...

  1. 78 FR 7395 - Stainless Steel Bar From India: Preliminary Results of Antidumping Duty Administrative Review...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-02-01

    ... International Trade Administration Stainless Steel Bar From India: Preliminary Results of Antidumping Duty... the antidumping duty order on stainless steel bar (SSB) from India. The period of review (POR) is... Review: Stainless Steel Bar from India'' dated concurrently with this notice (``Preliminary...

  2. 77 FR 18211 - Drawn Stainless Steel Sinks From the People's Republic of China: Initiation of Countervailing...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-03-27

    ... International Trade Administration Drawn Stainless Steel Sinks From the People's Republic of China: Initiation...'') petition concerning imports of drawn stainless steel sinks from the People's Republic of China (``PRC... Antidumping and Countervailing Duties Against Drawn Stainless Steel Sinks from the People's Republic of...

  3. 78 FR 13019 - Drawn Stainless Steel Sinks From the People's Republic of China: Investigation, Final Determination

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-02-26

    ... International Trade Administration Drawn Stainless Steel Sinks From the People's Republic of China... Drawn Stainless Steel Sinks From the People's Republic of China: Antidumping Duty Investigation, 77 FR... Co., Ltd. in the Investigation of Drawn Stainless Steel Sinks from the People's Republic of...

  4. 76 FR 18518 - Stainless Steel Sheet and Strip in Coils From Mexico: Rescission of Antidumping Duty...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-04-04

    ... International Trade Administration Stainless Steel Sheet and Strip in Coils From Mexico: Rescission of... stainless steel sheet and strip in coils from Mexico. The period of review is July 1, 2009, through June 30... American Stainless, and AK Steel Corporation (collectively ``petitioners''), we are now rescinding...

  5. 76 FR 54207 - Stainless Steel Plate in Coils From Italy: Revocation of Antidumping Duty Order

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-08-31

    ... International Trade Administration Stainless Steel Plate in Coils From Italy: Revocation of Antidumping Duty... antidumping duty order on stainless steel plate in coils (SSPC) from Italy. See Initiation of Five-Year... in the United States within a reasonably foreseeable time. See Stainless Steel Plate From...

  6. 76 FR 31585 - Forged Stainless Steel Flanges From India: Notice of Rescission of Antidumping Duty...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-06-01

    ... International Trade Administration Forged Stainless Steel Flanges From India: Notice of Rescission of... stainless steel flanges from India. The period of review is February 1, 2010, through January 22, 2011... stainless steel flanges from India. See Antidumping or Countervailing Duty Order, Finding, or...

  7. 75 FR 39663 - Stainless Steel Bar From Brazil: Final Results of Antidumping Duty Administrative Review

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-07-12

    ... International Trade Administration Stainless Steel Bar From Brazil: Final Results of Antidumping Duty... of its administrative review of the antidumping duty order on certain stainless steel bar from Brazil... results of its administrative review of the antidumping duty order on certain stainless steel bar...

  8. 75 FR 67689 - Stainless Steel Bar From Brazil: Preliminary Results of Antidumping Duty Administrative Review

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-11-03

    ... International Trade Administration Stainless Steel Bar From Brazil: Preliminary Results of Antidumping Duty... antidumping duty order on certain stainless steel bar from Brazil. The review covers one producer/ exporter of... Department published in the Federal Register an antidumping duty order on certain stainless steel bar...

  9. 78 FR 4383 - Stainless Steel Bar From Brazil: Preliminary Results of Antidumping Duty Administrative Review...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-01-22

    ... International Trade Administration Stainless Steel Bar From Brazil: Preliminary Results of Antidumping Duty... the antidumping duty order on stainless steel bar (SSB) from Brazil. The period of review (POR) is... Antidumping Duty Administrative Review: Stainless Steel Bar from Brazil'' dated concurrently with this...

  10. 76 FR 76437 - Certain Welded Stainless Steel Pipe From Korea and Taiwan

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-12-07

    ... COMMISSION Certain Welded Stainless Steel Pipe From Korea and Taiwan Determination On the basis of the record... revocation of the antidumping duty orders on certain welded stainless steel pipe from Korea and Taiwan would... Publication 4280 (December 2011), entitled Certain Welded Stainless Steel Pipe from Korea and...

  11. 76 FR 28809 - Stainless Steel Plate From Belgium; Termination of Five-Year Review

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-05-18

    ... COMMISSION Stainless Steel Plate From Belgium; Termination of Five-Year Review AGENCY: United States... review concerning the countervailing duty order on stainless steel plate from Belgium (75 FR 30777 and 75... its full five-year review of the countervailing duty order concerning stainless steel plate...

  12. 49 CFR 178.47 - Specification 4DS welded stainless steel cylinders for aircraft use.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 3 2013-10-01 2013-10-01 false Specification 4DS welded stainless steel cylinders...) SPECIFICATIONS FOR PACKAGINGS Specifications for Cylinders § 178.47 Specification 4DS welded stainless steel... stainless steel sphere (two seamless hemispheres) or circumferentially welded cylinder both with a...

  13. 78 FR 45271 - Welded Stainless Steel Pressure Pipe From Malaysia, Thailand, and Vietnam

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-07-26

    ... COMMISSION Welded Stainless Steel Pressure Pipe From Malaysia, Thailand, and Vietnam Determination On the... injured by reason of imports from Malaysia, Thailand, and Vietnam of welded stainless steel pressure pipe... injured or threatened with material injury by reason of LTFV imports of welded stainless steel...

  14. 49 CFR 178.47 - Specification 4DS welded stainless steel cylinders for aircraft use.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 3 2011-10-01 2011-10-01 false Specification 4DS welded stainless steel cylinders...) SPECIFICATIONS FOR PACKAGINGS Specifications for Cylinders § 178.47 Specification 4DS welded stainless steel... stainless steel sphere (two seamless hemispheres) or circumferentially welded cylinder both with a...

  15. 76 FR 46323 - Stainless Steel Sheet and Strip From Germany, Italy, Japan, Korea, Mexico, and Taiwan

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-08-02

    ... COMMISSION Stainless Steel Sheet and Strip From Germany, Italy, Japan, Korea, Mexico, and Taiwan... U.S.C.1675(c)), that revocation of the antidumping duty orders on stainless steel sheet and strip... revocation of the countervailing duty order on stainless steel sheet and strip from Korea and revocation...

  16. 49 CFR 178.47 - Specification 4DS welded stainless steel cylinders for aircraft use.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 3 2012-10-01 2012-10-01 false Specification 4DS welded stainless steel cylinders...) SPECIFICATIONS FOR PACKAGINGS Specifications for Cylinders § 178.47 Specification 4DS welded stainless steel... stainless steel sphere (two seamless hemispheres) or circumferentially welded cylinder both with a...

  17. 75 FR 67110 - Forged Stainless Steel Flanges From India and Taiwan

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-11-01

    ... COMMISSION Forged Stainless Steel Flanges From India and Taiwan AGENCY: United States International Trade... stainless steel flanges from India and Taiwan. SUMMARY: The Commission hereby gives notice that it has... determine whether revocation of the antidumping duty orders on forged stainless steel flanges from India...

  18. 49 CFR 178.47 - Specification 4DS welded stainless steel cylinders for aircraft use.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 3 2014-10-01 2014-10-01 false Specification 4DS welded stainless steel cylinders...) SPECIFICATIONS FOR PACKAGINGS Specifications for Cylinders § 178.47 Specification 4DS welded stainless steel... stainless steel sphere (two seamless hemispheres) or circumferentially welded cylinder both with a...

  19. 77 FR 45653 - Stainless Steel Bar From Brazil, India, Japan, and Spain; Determination

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-08-01

    ... (Third Review)] Stainless Steel Bar From Brazil, India, Japan, and Spain; Determination Determination On... U.S.C. 1675(c)), that revocation of the antidumping duty orders on stainless steel bar from Brazil... (July 2012), entitled Stainless Steel Bar from Brazil, India, Japan, and Spain: Investigation Nos....

  20. 77 FR 60478 - Control of Ferrite Content in Stainless Steel Weld Metal

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-10-03

    ... COMMISSION Control of Ferrite Content in Stainless Steel Weld Metal AGENCY: Nuclear Regulatory Commission... Ferrite Content in Stainless Steel Weld Metal.'' This guide describes a method that the NRC staff considers acceptable for controlling ferrite content in stainless steel weld metal. Revision 4 updates...

  1. Radiation embrittlement of manganese-stabilized martensitic stainless steel

    SciTech Connect

    Gelles, D.S.; Hu, W.L.

    1986-12-01

    Fractographic examination has been performed on selected Charpy specimens of manganese stabilized martensitic stainless steels in order to identify the cause of irradiation embrittlement. Embrittlement was found to be partly due to enhanced failure at grain boundaries arising from precipitation. Microstructural examination of a specimen irradiated at higher temperature has demonstrated the presence of Fe-Cr-Mn chi phase, a body centered cubic intermetallic phase known to cause embrittlement. This work indicated that manganese stabilized martensitic stainless steels are prone to intermetallic phase formation which is detrimental to mechanical properties.

  2. Comparison of carbon fiber and stainless steel root canal posts.

    PubMed

    Purton, D G; Payne, J A

    1996-02-01

    This in vitro study compared physical properties of root canal posts made of carbon fiber-reinforced epoxy resin with those of stainless steel posts. Three-point bending tests were used to derive the transverse modulus of elasticity of the posts. Resin composite cores on the posts were subjected to tensile forces to test the bonds between the cores and posts. Carbon fiber posts appeared to have adequate rigidity for their designed purpose. The bond strength of the resin composite cores to the carbon fiber posts was significantly less than that to the stainless steel posts.

  3. Ozone decay on stainless steel and sugarcane bagasse surfaces

    NASA Astrophysics Data System (ADS)

    Souza-Corrêa, Jorge A.; Oliveira, Carlos; Amorim, Jayr

    2013-07-01

    Ozone was generated using dielectric barrier discharges at atmospheric pressure to treat sugarcane bagasse for bioethanol production. It was shown that interaction of ozone molecules with the pretreatment reactor wall (stainless steel) needs to be considered during bagasse oxidation in order to evaluate the pretreatment efficiency. The decomposition coefficients for ozone on both materials were determined to be (3.3 ± 0.2) × 10-8 for stainless steel and (2.0 ± 0.3) × 10-7 for bagasse. The results have indicated that ozone decomposition has occurred more efficiently on the biomass material.

  4. The use of titanium and stainless steel in fracture fixation.

    PubMed

    Hayes, J S; Richards, R G

    2010-11-01

    The use of metal in fracture fixation has demonstrated unrivalled success for many years owing to its high stiffness, strength, biological toleration and overall reliable function. The most prominent materials used are electropolished stainless steel and commercially pure titanium, along with the more recent emergence of titanium alloys. Despite the many differences between electropolished stainless steel and titanium, both materials provide a relatively predictable clinical outcome, and offer similar success for fulfilling the main biomechanical and biological requirements of fracture fixation despite distinctive differences in implant properties and biological responses. This article explores these differences by highlighting the limitations and advantages of both materials, and addresses how this translates to clinical success.

  5. Accelerated corrosion of stainless steel in thiocyanate-containing solutions

    SciTech Connect

    Pistorius, P Chris; Li, Wen

    2012-09-19

    It is known that reduced sulfur compounds (such as thiocyanate and thiosulfate) can accelerate active corrosion of austenitic stainless steel in acid solutions, but before we started this project the mechanism of acceleration was largely unclear. This work combined electrochemical measurements and analysis using scanning electron microscopy (SEM) and X-ray photo-electron spectroscopy (XPS), which provided a comprehensive understanding of the catalytic effect of reduced sulfur species on the active corrosion of stainless steel. Both the behavior of the pure elements and the steel were studied and the work focused on the interaction between the pure elements of the steel, which is the least understood area. Upon completion of this work, several aspects are now much clearer. The main results from this work can be summarized as follows: The presence of low concentrations (around 0.1 mM) of thiocyanate or tetrathionate in dilute sulfuric acid greatly accelerates the anodic dissolution of chromium and nickel, but has an even stronger effect on stainless steels (iron-chromium-nickel alloys). Electrochemical measurements and surface analyses are in agreement with the suggestion that accelerated dissolution really results from suppressed passivation. Even well below the passivation potential, the electrochemical signature of passivation is evident in the electrode impedance; the electrode impedance shows clearly that this pre-passivation is suppressed in the presence of thiocyanate. For the stainless steels, remarkable changes in the morphology of the corroded metal surface and in the surface concentration of chromium support the suggestion that pre-passivation of stainless steels is suppressed because dissolution of chromium is accelerated. Surface analysis confirmed that adsorbed sulfur / sulfide forms on the metal surfaces upon exposure to solutions containing thiocyanate or thiosulfate. For pure nickel, and steels containing nickel (and residual copper), bulk sulfide

  6. No genotoxicity of a new nickel-free stainless steel.

    PubMed

    Montanaro, L; Cervellati, M; Campoccia, D; Prati, C; Breschi, L; Arciola, C R

    2005-01-01

    Stainless steel is a metallic alloy largely employed in orthopedics, maxillofacial surgery and orthodontic therapy. However, the presence in its composition of a high quantity of nickel, an agent known to trigger toxic, allergic and cancerogenous responses in humans, is cause of some concern. In this study, we have investigated the in vitro mutagenicity and genotoxicity of a new nickel-free stainless steel, namely P558, in comparison to the conventional stainless steel AISI 316L. The cytogenetic effects were evaluated by studying the frequency of Sister Chromatid Exchanges (SCE) and chromosomal aberrations. Ames test was performed to detect the mutagenic activity. Both P558 and AISI 316L did not cause any significant increase in the average number of SCE and in chromosomal aberrations, either with or without metabolic activation. Furthermore, the Ames test showed that the extracts of both P558 and of AISI 316L are not mutagenic. Overall, these findings prove that P558 is devoid of genotoxicity and mutagenicity. The present results, together with other previous interesting observations that P558 promotes osseointegration, suggest that this new nickel-free stainless steel can represent a better alternative to other conventional steel alloys.

  7. Bactericidal behavior of Cu-containing stainless steel surfaces

    NASA Astrophysics Data System (ADS)

    Zhang, Xiangyu; Huang, Xiaobo; Ma, Yong; Lin, Naiming; Fan, Ailan; Tang, Bin

    2012-10-01

    Stainless steels are one of the most common materials used in health care environments. However, the lack of antibacterial advantage has limited their use in practical application. In this paper, antibacterial stainless steel surfaces with different Cu contents have been prepared by plasma surface alloying technology (PSAT). The steel surface with Cu content 90 wt.% (Cu-SS) exhibits strong bactericidal activity against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) within 3 h. Although the Cu-containing surface with Cu content 2.5 wt.% (CuNi-SS) can also kill all tested bacteria, this process needs 12 h. SEM observation of the bacterial morphology and an agarose gel electrophoresis were performed to study the antibacterial mechanism of Cu-containing stainless steel surfaces against E. coli. The results indicated that Cu ions are released when the Cu-containing surfaces are in contact with bacterial and disrupt the cell membranes, killing the bacteria. The toxicity of Cu-alloyed surfaces does not cause damage to the bacterial DNA. These results provide a scientific explanation for the antimicrobial applications of Cu-containing stainless steel. The surfaces with different antibacterial abilities could be used as hygienic surfaces in healthcare-associated settings according to the diverse requirement of bactericidal activities.

  8. High-temperature brazing of stainless steel

    NASA Technical Reports Server (NTRS)

    Beuyukian, C. S.; Heisman, R. M.; Mitchell, M. J.

    1978-01-01

    Prevention of iron contamination of platens is eliminated by placing alumina/silica ceramic-fiber blankets between platens and carbon-steel plate. Carbon-steel plates provide rigidity and improve heat transfer.

  9. Preparation and characterization of 304 stainless steel/Q235 carbon steel composite material

    NASA Astrophysics Data System (ADS)

    Shen, Wenning; Feng, Lajun; Feng, Hui; Cao, Ying; Liu, Lei; Cao, Mo; Ge, Yanfeng

    The composite material of 304 stainless steel reinforced Q235 carbon steel has been prepared by modified hot-rolling process. The resulted material was characterized by scanning electron microscope, three-electrode method, fault current impact method, electrochemical potentiodynamic polarization curve measurement and electrochemical impedance spectroscopy. The results showed that metallurgical bond between the stainless steel layer and carbon steel substrate has been formed. The composite material exhibited good electrical conductivity and thermal stability. The average grounding resistance of the composite material was about 13/20 of dip galvanized steel. There has no surface crack and bubbling formed after fault current impact. The composite material led to a significant decrease in the corrosion current density in soil solution, compared with that of hot dip galvanized steel and bare carbon steel. On the basis polarization curve and EIS analyses, it can be concluded that the composite material showed improved anti-corrosion property than hot-dip galvanized steel.

  10. Localized corrosion of stainless steels in ammonium chloride solutions

    SciTech Connect

    Forsen, O.; Aromaa, J.; Tavi, M.; Virtanen, J.

    1997-05-01

    Ammonium chloride deposition is a well-known problem in oil refining. When these deposits form in a moist environment, they are corrosive to carbon steel. When unexpected corrosion problems are faced, the material is often changed to alloys like stainless steels (SS). Electrochemical measurements were used to study the corrosion resistance of SS in ammonium chloride environments with different chloride contents and at different temperatures.

  11. 37. REDUCTION PLANT DRYER Stainless steel screen cylinder, encased ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    37. REDUCTION PLANT - DRYER Stainless steel screen cylinder, encased within an outer steel shell (top half missing). As fish were tumbled by the rotating screen, they were cooked and dried by live steam piped into the dryer through overhead pipes. The dryer is mounted on a slight angle, aiding the process by moving the drying fish towards the exhaust end of the dryer. - Hovden Cannery, 886 Cannery Row, Monterey, Monterey County, CA

  12. Effect of ultrafine grain on tensile behaviour and corrosion resistance of the duplex stainless steel.

    PubMed

    Jinlong, Lv; Tongxiang, Liang; Chen, Wang; Limin, Dong

    2016-05-01

    The ultrafine grained 2205 duplex stainless steel was obtained by cold rolling and annealing. The tensile properties were investigated at room temperature. Comparing with coarse grained stainless steel, ultrafine grained sample showed higher strength and plasticity. In addition, grain size changed deformation orientation. The strain induced α'-martensite was observed in coarse grained 2205 duplex stainless steel with large strain. However, the grain refinement inhibited the transformation of α'-martensite;nevertheless, more deformation twins improved the strength and plasticity of ultrafine grained 2205 duplex stainless steel. In addition, the grain refinement improved corrosion resistance of the 2205 duplex stainless steel in sodium chloride solution.

  13. Graphene Nanoplatelets Based Protective and Functionalizing Coating for Stainless Steel.

    PubMed

    Mondal, Jayanta; Kozlova, Jekaterina; Sammelselg, Väino

    2015-09-01

    Stainless steel is the most widely used alloy for many industrial and everyday applications, and protection of this alloy substrate against corrosion is an important industrial issue. Here we report a promising application of graphene oxide and graphene nanoplatelets as effective corrosion inhibitors for AISI type 304 stainless steel alloy. The graphene oxide and graphene coatings on the stainless steel substrates were prepared using spin coating techniques. Homogeneous and complete surface coverage by the graphene oxide and graphene nanoplatelets were observed with a high-resolution scanning electron microscope. The corrosion inhibition ability of these materials was investigated through measurement of open circuit potential and followed by potentiodymamic polarization analysis in aqueous sodium chloride solution before and after a month of immersion. Analyzed result exhibits effective corrosion inhibition for both substrates coated with graphene oxide or graphene nanoplatelets by increasing corrosion potential, pitting potential and decreasing passive current density. The corrosion inhibition ability of the coated substrates has not changed even after the long-term immersion. The result showed both graphene materials can be used as an effective corrosion inhibitor for the stainless steel substrates, which would certainly increase lifetime the substrate. However, long-term protection ability of the graphene coated susbtsrate showed somewhat better inhibition performance than the ones coated with graphene oxide.

  14. Bending Behavior of Porous Sintered Stainless Steel Fiber Honeycombs

    NASA Astrophysics Data System (ADS)

    Zou, Shuiping; Wan, Zhenping; Lu, Longsheng; Tang, Yong

    2017-02-01

    A novel porous honeycomb-type substrate has been developed using solid-state sintering stainless steel fibers. The porous sintered stainless steel fiber honeycombs (PSSSFH) are composed of a skeleton of sintered stainless steel fibers, three-dimensionally interconnected porous structures and multiple parallel microchannels. The bending behavior of the PSSSFH is investigated using three-point bending tests. Four stages, including an elastic stage, a yielding stage with a plateau, a hardening stage and a failure stage, are observed during the bending process of the PSSSFH. In the initial yielding stage, the bending forces increase slowly with displacement increasing, and then a yielding plateau follows, which is unique compared with other porous materials. Moreover, the structure parameters of the PSSSFH are varied to investigate the influence on the bending strength. It is determined that the multiple parallel microchannels can enhance the bending strength of porous stainless steel fiber sintered substrates (PSSFSS) and do not influence the variation trend of bending strength of PSSFSS with porosity increasing. The open ratio is conducive to increasing the bending strength, and the microchannel diameters ranging from 0.5 mm to 1.5 mm have little influence on the bending strength. In addition, both the increasing of sintering temperature and sintering time can strengthen the PSSSFH.

  15. Quantitative measurement and modeling of sensitization development in stainless steel

    SciTech Connect

    Bruemmer, S.M.; Atteridge, D.G.

    1992-09-01

    The state-of-the-art to quantitatively measure and model sensitization development in austenitic stainless steels is assessed and critically analyzed. A modeling capability is evolved and validated using a diverse experimental data base. Quantitative predictions are demonstrated for simple and complex thermal and thermomechanical treatments. Commercial stainless steel heats ranging from high-carbon Type 304 and 316 to low-carbon Type 304L and 316L have been examined including many heats which correspond to extra-low-carbon, nuclear-grade compositions. Within certain limits the electrochemical potentiokinetic reactivation (EPR) test was found to give accurate and reproducible measurements of the degree of sensitization (DOS) in Type 304 and 316 stainless steels. EPR test results are used to develop the quantitative data base and evolve/validate the quantitative modeling capability. This thesis represents a first step to evolve methods for the quantitative assessment of structural reliability in stainless steel components and weldments. Assessments will be based on component-specific information concerning material characteristics, fabrication history and service exposure. Methods will enable fabrication (e.g., welding and repair welding) procedures and material aging effects to be evaluated and ensure adequate cracking resistance during the service lifetime of reactor components. This work is being conducted by the Oregon Graduate Institute with interactive input from personnel at Pacific Northwest Laboratory.

  16. 6. DETAIL OF STAINLESS STEEL VISCERA CHUTE IN SOUTHEAST CORNER ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    6. DETAIL OF STAINLESS STEEL VISCERA CHUTE IN SOUTHEAST CORNER OF LEVEL4; ENTRAILS WERE DROPPED INTO CHUTE, THEN PASSED THROUGH THE FLOOR TO THE GUT SHANTY ON LEVEL 3 TO BE SORTED AND CLEANED - Rath Packing Company, Hog Dressing Building, Sycamore Street between Elm & Eighteenth Streets, Waterloo, Black Hawk County, IA

  17. Bending Behavior of Porous Sintered Stainless Steel Fiber Honeycombs

    NASA Astrophysics Data System (ADS)

    Zou, Shuiping; Wan, Zhenping; Lu, Longsheng; Tang, Yong

    2016-12-01

    A novel porous honeycomb-type substrate has been developed using solid-state sintering stainless steel fibers. The porous sintered stainless steel fiber honeycombs (PSSSFH) are composed of a skeleton of sintered stainless steel fibers, three-dimensionally interconnected porous structures and multiple parallel microchannels. The bending behavior of the PSSSFH is investigated using three-point bending tests. Four stages, including an elastic stage, a yielding stage with a plateau, a hardening stage and a failure stage, are observed during the bending process of the PSSSFH. In the initial yielding stage, the bending forces increase slowly with displacement increasing, and then a yielding plateau follows, which is unique compared with other porous materials. Moreover, the structure parameters of the PSSSFH are varied to investigate the influence on the bending strength. It is determined that the multiple parallel microchannels can enhance the bending strength of porous stainless steel fiber sintered substrates (PSSFSS) and do not influence the variation trend of bending strength of PSSFSS with porosity increasing. The open ratio is conducive to increasing the bending strength, and the microchannel diameters ranging from 0.5 mm to 1.5 mm have little influence on the bending strength. In addition, both the increasing of sintering temperature and sintering time can strengthen the PSSSFH.

  18. 73. View of line of stainless steel coolant storage tanks ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    73. View of line of stainless steel coolant storage tanks for bi-sodium sulfate/water coolant solution at first floor of transmitter building no. 102. - Clear Air Force Station, Ballistic Missile Early Warning System Site II, One mile west of mile marker 293.5 on Parks Highway, 5 miles southwest of Anderson, Anderson, Denali Borough, AK

  19. Nanoparticle Treated Stainless Steel Filters for Metal Vapor Sequestration

    NASA Astrophysics Data System (ADS)

    Murph, Simona E. Hunyadi; Larsen, George K.; Korinko, Paul; Coopersmith, Kaitlin J.; Summer, Ansley J.; Lewis, Rebecca

    2016-12-01

    The ability to sequester vapor phase radioactive compounds during industrial processes reduces the exposure of workers and the environment to dangerous radioactive materials. Nanomaterials have a lot of potential in this area because they typically demonstrate size- and shape-dependent properties with higher reactivity than bulk. This is due to the increased surface area-to-volume ratio and quantum size effects. In this report, we developed a gold nanomaterial-treated stainless steel filter, namely wools and coupons, that can be efficiently used for zinc vapor sequestration. Without nanoparticle modification, stainless steel coupons do not react or alloy with Zn. Gold nanomaterials were grown onto various stainless steel filters using solution chemistry that is amenable to scaling up. Materials were characterized by electron microscopy, inductively coupled plasma mass spectroscopy and dynamic light scattering before and after exposure to zinc vapors. X-ray diffraction, high-resolution transmission electron microscopy, energy dispersive x-ray spectroscopy mapping and ultraviolet-visible spectroscopy confirm the formation of gold-zinc alloys after Zn vapor exposure. The effect of surface topography on nanoparticle morphology, size and loading density were also investigated, and stainless steel surface defects were found to have an impact on the Au NP growth and subsequently Zn sequestration.

  20. Cataract Section Across Temporary Stainless-Steel Sutures

    PubMed Central

    MacDonald, R. Keith

    1965-01-01

    The purpose of the technique described was to combine the advantages of a cleanedged Graefe-knife incision with those of safety and near-perfect apposition offered by preplaced sutures: a preliminary to cataract extraction. Uncuttable preplaced 2-mm. stainless steel sutures were finally replaced after completion of the incision by attached braided silk for closure purposes. PMID:14291461

  1. Nanoparticle Treated Stainless Steel Filters for Metal Vapor Sequestration

    NASA Astrophysics Data System (ADS)

    Murph, Simona E. Hunyadi; Larsen, George K.; Korinko, Paul; Coopersmith, Kaitlin J.; Summer, Ansley J.; Lewis, Rebecca

    2017-02-01

    The ability to sequester vapor phase radioactive compounds during industrial processes reduces the exposure of workers and the environment to dangerous radioactive materials. Nanomaterials have a lot of potential in this area because they typically demonstrate size- and shape-dependent properties with higher reactivity than bulk. This is due to the increased surface area-to-volume ratio and quantum size effects. In this report, we developed a gold nanomaterial-treated stainless steel filter, namely wools and coupons, that can be efficiently used for zinc vapor sequestration. Without nanoparticle modification, stainless steel coupons do not react or alloy with Zn. Gold nanomaterials were grown onto various stainless steel filters using solution chemistry that is amenable to scaling up. Materials were characterized by electron microscopy, inductively coupled plasma mass spectroscopy and dynamic light scattering before and after exposure to zinc vapors. X-ray diffraction, high-resolution transmission electron microscopy, energy dispersive x-ray spectroscopy mapping and ultraviolet-visible spectroscopy confirm the formation of gold-zinc alloys after Zn vapor exposure. The effect of surface topography on nanoparticle morphology, size and loading density were also investigated, and stainless steel surface defects were found to have an impact on the Au NP growth and subsequently Zn sequestration.

  2. New equation of state for stainless steel 347

    SciTech Connect

    Boettger, J.C.

    1993-12-01

    A new SESAME equation of state (EOS) for stainless steel 347 has been generated using the computer program GRIZZLY, and has been added to the SESAME EOS library as material number 4271. This new EOS is superior to its predecesser (material number 4270) in several respects.

  3. Materials data handbook: Stainless steel alloy A-286

    NASA Technical Reports Server (NTRS)

    Muraca, R. F.; Whittick, J. S.

    1972-01-01

    A summary of the materials property information for stainless steel alloy A-286 is presented. The scope of the information includes physical and mechanical properties at cryogenic, ambient, and elevated temperatures. Information on material procurement, metallurgy of the alloy, corrosion, environmental effects, fabrication, and bonding is developed.

  4. Method of forming dynamic membrane on stainless steel support

    NASA Technical Reports Server (NTRS)

    Gaddis, Joseph L. (Inventor); Brandon, Craig A. (Inventor)

    1988-01-01

    A suitable member formed from sintered, powdered, stainless steel is contacted with a nitrate solution of a soluble alkali metal nitrate and a metal such as zirconium in a pH range and for a time sufficient to effect the formation of a membrane of zirconium oxide preferably including an organic polymeric material such as polyacrylic acid.

  5. Metal release from stainless steel in biological environments: A review.

    PubMed

    Hedberg, Yolanda S; Odnevall Wallinder, Inger

    2015-03-29

    Due to its beneficial corrosion resistance, stainless steel is widely used in, e.g., biomedical applications, as surfaces in food contact, and for products intended to come into skin contact. Low levels of metals can be released from the stainless steel surface into solution, even for these highly corrosion resistant alloys. This needs to be considered in risk assessment and management. This review aims to compile the different metal release mechanisms that are relevant for stainless steel when used in different biological settings. These mechanisms include corrosion-induced metal release, dissolution of the surface oxide, friction-induced metal release, and their combinations. The influence of important physicochemical surface properties, different organic species and proteins in solution, and of biofilm formation on corrosion-induced metal release is discussed. Chemical and electrochemical dissolution mechanisms of the surface oxides of stainless steel are presented with a focus on protonation, complexation/ligand-induced dissolution, and reductive dissolution by applying a perspective on surface adsorption of complexing or reducing ligands and proteins. The influence of alloy composition, microstructure, route of manufacture, and surface finish on the metal release process is furthermore discussed as well as the chemical speciation of released metals. Typical metal release patterns are summarized.

  6. Failure Assessment Diagram for Brazed 304 Stainless Steel Joints

    NASA Technical Reports Server (NTRS)

    Flom, Yory

    2011-01-01

    Interaction equations were proposed earlier to predict failure in Albemet 162 brazed joints. Present study demonstrates that the same interaction equations can be used for lower bound estimate of the failure criterion in 304 stainless steel joints brazed with silver-based filler metals as well as for construction of the Failure Assessment Diagrams (FAD).

  7. Battery and fuel cell electrodes containing stainless steel charging additive

    DOEpatents

    Zuckerbrod, David; Gibney, Ann

    1984-01-01

    An electrode for use in electrochemical energy cells is made, comprising a hydrophilic layer and a hydrophobic layer, where the hydrophilic layer comprises a hydrophilic composite which includes: (i) carbon particles; (ii) stainless steel particles; (iii) a nonwetting agent; and (iv) a catalyst, where at least one current collector contacts said composite.

  8. Behavior of stainless steels in pressurized water reactor primary circuits

    NASA Astrophysics Data System (ADS)

    Féron, D.; Herms, E.; Tanguy, B.

    2012-08-01

    Stainless steels are widely used in primary circuits of pressurized water reactors (PWRs). Operating experience with the various grades of stainless steels over several decades of years has generally been excellent. Nevertheless, stress corrosion failures have been reported in few cases. Two main factors contributing to SCC susceptibility enhancement are investigated in this study: cold work and irradiation. Irradiation is involved in the stress corrosion cracking and corrosion of in-core reactor components in PWR environment. Irradiated assisted stress corrosion cracking (IASCC) is a complex and multi-physics phenomenon for which a predictive modeling able to describe initiation and/or propagation is not yet achieved. Experimentally, development of initiation smart tests and of in situ instrumentation, also in nuclear reactors, is an important axis in order to gain a better understanding of IASCC kinetics. A strong susceptibility for SCC of heavily cold worked austenitic stainless steels is evidenced in hydrogenated primary water typical of PWRs. It is shown that for a given cold-working procedure, SCC susceptibility of austenitic stainless steels materials increases with increasing cold-work. Results have shown also strong influences of the cold work on the oxide layer composition and of the maximum stress on the time to fracture.

  9. Pitting corrosion of low-Cr austenitic stainless steels

    SciTech Connect

    Bullard, Sophie J.; Covino, Bernard S. Jr.

    1996-01-01

    The Albany Research Center has investigated the pitting corrosion resistance of experimental low-Cr stainless steels and several commercial stainless steels in chloride-containing aqueous and atmospheric environments. Previous research had shown the experimental alloys to be as corrosion resistant as commercial stainless steels in chloride-free acid environments. The alloys studied were Fe-8Cr-16Ni-5.5Si-1Cu-(0-1)Mo, 304 SS, and 316 SS. These alloys were examined by immersion and electrochemical tests in 3.5 wt. pct. NaCl and 6 wt.pct.FeCl{sub 3}. Results of these tests showed that the addition of one weight percent Mo improved the pitting resistance of the low-Cr alloy and that the Mo-containing experimental alloy was as resistant to pitting as the commercial alloys. Electrochemical tests did, however, show the experimental alloys to be slightly less resistant to pitting than the commercial alloys. Because of these results, the low-Cr alloy with one weight percent Mo and 304 SS were exposed for one year to a marine atmospheric environment on the coast of Oregon. The marine atmospheric corrosion resistance of the low-Cr alloy was found to be comparable to that for type 304 stainless steel.

  10. [The question of nickel release from stainless steel cooking pots].

    PubMed

    Vrochte, H; Schätzke, M; Dringenberg, E; Wölwer-Rieck, U; Büning-Pfaue, H

    1991-09-01

    For three items of foods (rhubarb, spinach, sauerkraut) the possible release of nickel (by means of AAS) was analysed, a release which may be caused by a possible corrosive effect of the concerned (oxalic-, milk-, vinegar-) acids (as well as common salt) within a normal domestic food-preparation. For this analysis stainless steel cooking pots of different manufacturers, various types and in a representative selection and quantity were taken into consideration; the detailed analyses were extended so far that clear statistical evaluations were possible. This method complies regulations for accuracy to determine traces of heavy metal. For all three analysed food-stuffs an identical result was reached that no nickel release from the stainless steel cooking pots into the food was found. Differences of the various stainless steel cooking pots with regard to their surfaces' quality or their origin (manufacturers) were not yielded, either. All detected concentrations of nickel are within the reach of the natural nickel content of the analysed food-stuffs and their amount is even much lower than other food's content of nickel. This leads up to the conclusion that the former view of a possible nickel release of stainless steel cooking pots has to be revised because these assumptions were not confirmed in the presented results of this analysis and therefore have to be regarded as not correct.

  11. Immobilization of mesoporous silica particles on stainless steel plates

    NASA Astrophysics Data System (ADS)

    Pasqua, Luigi; Morra, Marco

    2017-03-01

    A preliminary study aimed to the nano-engineering of stainless steel surface is presented. Aminopropyl-functionalized mesoporous silica is covalently and electrostatically anchored on the surface of stainless steel plates. The anchoring is carried out through the use of a nanometric spacer, and two different spacers are proposed (both below 2 nm in size). The first sample is obtained by anchoring to the stainless steel amino functionalized, a glutaryl dichloride spacer. This specie forms an amide linkage with the amino group while the unreacted acyl groups undergo hydrolysis giving a free carboxylic group. The so-obtained functionalized stainless steel plate is used as substrate for anchoring derivatized mesoporous silica particles. The second sample is prepared using 2-bromo-methyl propionic acid as spacer (BMPA). Successively, the carboxylic group of propionic acid is condensed to the aminopropyl derivatization on the external surface of the mesoporous silica particle through covalent bond. In both cases, a continuous deposition (coating thickness is around 10 μm) is obtained, in fact, XPS data do not reveal the metal elements constituting the plate. The nano-engineering of metal surfaces can represent an intriguing opportunity for producing long-term drug release or biomimetic surface.

  12. Stainless steel 301 and Inconel 718 hydrogen embrittlement

    NASA Technical Reports Server (NTRS)

    Allgeier, R. K.; Forman, R.

    1970-01-01

    Conditions and results of tensile tests of 26 Inconel 718 and four cryoformed stainless steel specimens are presented. Conclusions determine maximum safe hydrogen operating pressure for cryogenic pressure vessels and provide definitive information concerning flaw growth characteristics under the most severe temperature and pressure conditions

  13. Laves intermetallics in stainless steel-zirconium alloys

    SciTech Connect

    Abraham, D.P.; McDeavitt, S.M.; Richardson, J.W. Jr.

    1997-05-01

    Laves intermetallics have a significant effect on properties of metal waste forms being developed at Argonne National Laboratory. These waste forms are stainless steel-zirconium alloys that will contain radioactive metal isotopes isolated from spent nuclear fuel by electrometallurgical treatment. The baseline waste form composition for stainless steel-clad fuels is stainless steel-15 wt.% zirconium (SS-15Zr). This article presents results of neutron diffraction measurements, heat-treatment studies and mechanical testing on SS-15Zr alloys. The Laves intermetallics in these alloys, labeled Zr(Fe,Cr,Ni){sub 2+x}, have both C36 and C15 crystal structures. A fraction of these intermetallics transform into (Fe,Cr,Ni){sub 23}Zr{sub 6} during high-temperature annealing; the authors have proposed a mechanism for this transformation. The SS-15Zr alloys show virtually no elongation in uniaxial tension, but exhibit good strength and ductility in compression tests. This article also presents neutron diffraction and microstructural data for a stainless steel-42 wt.% zirconium (SS-42Zr) alloy.

  14. Electroless nickel plating on stainless steels and aluminum

    NASA Technical Reports Server (NTRS)

    1966-01-01

    Procedures for applying an adherent electroless nickel plating on 303 SE, 304, and 17-7 PH stainless steels, and 7075 aluminum alloy was developed. When heat treated, the electroless nickel plating provides a hard surface coating on a high strength, corrosion resistant substrate.

  15. Alternative to Nitric Acid for Passivation of Stainless Steel Alloys

    NASA Technical Reports Server (NTRS)

    Lewis, Pattie L.; Kolody, Mark; Curran, Jerry

    2013-01-01

    Corrosion is an extensive problem that affects the Department of Defense (DoD) and National Aeronautics and Space Administration (NASA). The deleterious effects of corrosion result in steep costs, asset downtime affecting mission readiness, and safety risks to personnel. Consequently, it is vital to reduce corrosion costs and risks in a sustainable manner. The DoD and NASA have numerous structures and equipment that are fabricated from stainless steel. The standard practice for protection of stainless steel is a process called passivation. Typical passivation procedures call for the use of nitric acid; however, there are a number of environmental, worker safety, and operational issues associated with its use. Citric acid offers a variety of benefits including increased safety for personnel, reduced environmental impact, and reduced operational cost. DoD and NASA agreed to collaborate to validate citric acid as an acceptable passivating agent for stainless steel. This paper details our investigation of prior work developing the citric acid passivation process, development of the test plan, optimization of the process for specific stainless steel alloys, ongoing and planned testing to elucidate the process' resistance to corrosion in comparison to nitric acid, and preliminary results.

  16. 76 FR 13357 - Stainless Steel Sheet and Strip in Coils From Mexico; Correction Notice to Amended Final Results...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-03-11

    ... International Trade Administration Stainless Steel Sheet and Strip in Coils From Mexico; Correction Notice to... administrative review for stainless steel sheet and strip in coils from Mexico. See Stainless Steel Sheet and.... See Stainless Steel Sheet and Strip in Coils from Mexico; Final Results of Antidumping...

  17. Phase formation at bonded vanadium and stainless steel interfaces

    SciTech Connect

    Summers, T.S.E.

    1992-01-01

    The interface between vanadium bonded to stainless steel was studies to determine whether a brittle phase formed during three joining operations. Inertia friction welds between V and 21-6-9 stainless steel were examined using TEM. In the as-welded condition, a continuous, polygranular intermetallic layer about 0.25 {mu}m thick was present at the interface. This layer grew to about 50 {mu}m thick during heat treatment at 1000{degrees}C for two hours. Analysis of electron diffraction patterns confirmed that this intermetallic was the {omega} phase. The interface between vanadium and type 304, SANDVIK SAF 2205, and 21-6-9 stainless steel bonded by a co-extrusion process had intermetallic particles at the interface in the as-extruded condition. Heat treatment at 1000{degrees}C for two hours caused these particles to grow into continuous layers in all three cases. Based on the appearance, composition and hardness of this interfacial intermetallic, it was also concluded to be {omega} phase. Bonding V to type 430 stainless steel by co-extrusion caused V-rich carbides to form at the interface due to the higher concentration of C in the type 430 than in the other stainless steels investigated. The carbide particles initially present grew into a continuous layer during a two-hour heat treatment at 1000{degrees}C. Co-hipping 21-6-9 stainless steel tubing with V rod resulted in slightly more concentric specimens than the co-extruded ones, but a continuous layer of the {omega} phase formed during the hipping operation. This brittle layer could initiate failure during subsequent forming operations. The vanadium near the stainless steel interface in the co-extruded and co-hipped tubing in some cases was harder than before heat treatment. It was concluded that this hardening was due to thermal straining during cooling following heat treatment and that thermal strains might present a greater problem than seen here when longer tubes are used in actual applications.

  18. Cavitation Erosion of Sensitized UNS S31803 Duplex Stainless Steels

    NASA Astrophysics Data System (ADS)

    Mitelea, Ion; Micu, Lavinia Mădălina; Bordeaşu, Ilare; Crăciunescu, Corneliu Marius

    2016-05-01

    During processing or use, duplex steels can be subjected to heating at high temperatures that can affect their behavior. This work aims to correlate the influence of the sensitization treatment on the ultrasonic cavitation erosion behavior of a UNS S31803 (X2CrNiMoN22-5-3) duplex stainless steel. Duplex stainless steels, formed as a result of rapid cooling after solution annealing, are sensitized at temperatures of 475 and 850 °C, respectively, leading to hardening and embrittlement due to the spinodal decomposition of the ferrite and the precipitation of secondary phases. The ultrasonic cavitation erosion experiments showed that the sensitization at 850 °C reduced the mean depth of erosion by about 11% and the mean depth of erosion rate by 28%. By contrast, the sensitization at 475 °C deteriorates the cavitation erosion resistance, increasing the erosion parameters by up to 22%, compared to the solution annealed state.

  19. Evaluation of the wear properties of high interstitial stainless steels

    SciTech Connect

    Tylczak, J.H.; Rawers, J.C.; Alman, D.E.

    2007-04-01

    Adding carbon to high nitrogen steels increases interstitial concentrations over what can be obtained with nitrogen addition alone. This can results in an increase in hardness, strength, and wear resistance. The alloys produced for this study were all based on commercially available high-nitrogen Fe-18Cr-18Mn stainless steel. This study is the first significant wear study of these new high interstitial nitrogen-carbon stainless steel alloys. Wear tests included: scratch, pin-on-disk abrasion, dry sand/rubber wheel abrasion, impeller impact, and jet erosion. Increasing interstitial concentration increased strength and hardness and improved wear resistance under all test conditions. The results are discussed in terms of overall interstitial alloy concentration.

  20. Achievement of a superpolish on bare stainless steel

    SciTech Connect

    Howells, M.R.; Casstevens, J.

    1997-08-01

    We report the achievement of a superpolished surface, suitable for x-ray reflection, on bare stainless steel. The rms roughness obtained on various samples varied from 2.2 to 4.2 {angstrom}, as measured by an optical profiler with a bandwidth 0.29-100 mm{sup -1}. The type 17-4 PH precipitation-hardening stainless steel used to make the mirrors is also capable of ultrastability and has good manufactureability. This combination of properties makes it an excellent candidate material for mirror substrates. We describe the successful utilization of this type of steel in making elliptical-cylinder mirrors for a soft-x-ray microprobe system at the Advanced Light Source, and discuss possible for its unusual stability and polishability.

  1. Low Temperature Surface Carburization of Stainless Steels

    SciTech Connect

    Collins, Sunniva R; Heuer, Arthur H; Sikka, Vinod K

    2007-12-07

    Low-temperature colossal supersaturation (LTCSS) is a novel surface hardening method for carburization of austenitic stainless steels (SS) without the precipitation of carbides. The formation of carbides is kinetically suppressed, enabling extremely high or colossal carbon supersaturation. As a result, surface carbon concentrations in excess of 12 at. % are routinely achieved. This treatment increases the surface hardness by a factor of four to five, improving resistance to wear, corrosion, and fatigue, with significant retained ductility. LTCSS is a diffusional surface hardening process that provides a uniform and conformal hardened gradient surface with no risk of delamination or peeling. The treatment retains the austenitic phase and is completely non-magnetic. In addition, because parts are treated at low temperature, they do not distort or change dimensions. During this treatment, carbon diffusion proceeds into the metal at temperatures that constrain substitutional diffusion or mobility between the metal alloy elements. Though immobilized and unable to assemble to form carbides, chromium and similar alloying elements nonetheless draw enormous amounts of carbon into their interstitial spaces. The carbon in the interstitial spaces of the alloy crystals makes the surface harder than ever achieved before by more conventional heat treating or diffusion process. The carbon solid solution manifests a Vickers hardness often exceeding 1000 HV (equivalent to 70 HRC). This project objective was to extend the LTCSS treatment to other austenitic alloys, and to quantify improvements in fatigue, corrosion, and wear resistance. Highlights from the research include the following: • Extension of the applicability of the LTCSS process to a broad range of austenitic and duplex grades of steels • Demonstration of LTCSS ability for a variety of different component shapes and sizes • Detailed microstructural characterization of LTCSS-treated samples of 316L and other alloys

  2. Aging degradation of cast stainless steels: Effects on mechanical properties

    SciTech Connect

    Chopra, O.K.; Chung, H.M.

    1987-06-01

    A program is being conducted to investigate the significance of in-service embrittlement of cast duplex stainless steels under light-water operating conditions. Mechanical property data are presented from Charpy-impact, tensile, and J-R curve tests for several heats of cast stainless steel aged up to 10,000 h at 450, 400, 350, 320, and 290/sup 0/C. The results indicate that thermal aging increases the tensile strength and decreases the impact energy, J/sub IC/, and tearing modulus of the steels. Also, the ductile-to-brittle transition curve shifts to higher temperatures. The fracture toughness results are consistent with the Charpy-impact data, i.e., the relative reduction in J/sub IC/ is similar to the relative decrease in impact energy. The ferrite content and concentration of C in the steel have a strong effect on the overall process of low-temperature embrittlement. The low-carbon CF-3 steels are the most resistant and Mo-containing CF-8M steels are most susceptible to embrittlement. Weakening of the ferrite/austenite phase boundaries by carbide precipitates has a significant effect on the kinetics and extent of embrittlement of the high-carbon CF-8 and CF-8M steels, particularly after aging at temperatures greater than or equal to400/sup 0/C. The influence of N content and distribution of ferrite on loss of toughness are discussed. The data also indicate that existing correlations do not accurately represent the embrittlement behavior over the temperature range 280 to 450/sup 0/C, i.e., extrapolation of high-temperature data to reactor temperatures may not be valid for some compositions of cast stainless steel.

  3. Antibacterial activity against Porphyromonas gingivalis and biological characteristics of antibacterial stainless steel.

    PubMed

    Zhang, Dan; Ren, Ling; Zhang, Yang; Xue, Nan; Yang, Ke; Zhong, Ming

    2013-05-01

    To evaluate the possibility of an alternative to the traditional orthodontic stainless steel implants, the antibacterial activity against Porphyromonas gingivalis (P. gingivalis) and the related cytotoxicity of a type 304 Cu bearing antibacterial stainless steel were studied. The results indicated that the antibacterial stainless steel showed excellent antibacterial property against P. gingivalis, compared with the control steel (a purchased medical grade 304 stainless steel). Compared to the control steel, there were fewer bacteria on the surface of the antibacterial stainless steel, with significant difference in morphology. The cytotoxicities of the antibacterial stainless steel to both MG-63 and KB cells were all grade 1, the same as those of the control steel. There were no significant differences in the apoptosis rates on MG-63 and KB cells between the antibacterial stainless steel and the control steel. This study demonstrates that the antibacterial stainless steel is possible to reduce the incidence of implant-related infections and can be a more suitable material for the micro-implant than the conventional stainless steel in orthodontic treatment.

  4. Reduction of Aeromonas hidrophyla biofilm on stainless stell surface by essential oils

    PubMed Central

    Millezi, Alessandra Farias; Cardoso, Maria das Graças; Alves, Eduardo; Piccoli, Roberta Hilsdorf

    2013-01-01

    This study demonstrates the possibility of using sanitizing detergents based on natural products for the elimination and/or reduction of Aeromonas hydrophila biofilm formed on stainless steel surfaces. The goal of this work was to determine the reduction effect of sanitizing detergents containing essential oils of Thymus vulgaris (thyme) and Cymbopogon citratus (lemongrass) on biofilm formed by A. hydrophila on AISI 304 stainless steel coupons, using UHT skimmed milk as substratum. There was adhesion and biofilm formation by A. hydrophila at 28 °C, presenting 7.60 log cfu.cm−2 after the fourth day of cultivation. There was no significant difference between the lemongrass treatment and that of the thyme oil (p < 0.05). However, both treatments significantly reduced the biofilm, differing significantly from the NaOH control (p > 0.05). The treatment with lemongrass solution reduced the biofilm by 4.51 log cfu cm−2 at 25 °C. The thyme detergent also reduced the number of cfu cm−2 by 3.84 log cycles at 25 °C. The use of the lemongrass and thyme solutions efficiently reduced the A. hydrophila biofilm. PMID:24159286

  5. 2012 ACCOMPLISHMENTS - TRITIUM AGING STUDIES ON STAINLESS STEELS

    SciTech Connect

    Morgan, M.

    2013-01-31

    This report summarizes the research and development accomplishments during FY12 for the tritium effects on materials program. The tritium effects on materials program is designed to measure the long-term effects of tritium and its radioactive decay product, helium-3, on the structural properties of forged stainless steels which are used as the materials of construction for tritium reservoirs. The FY12 R&D accomplishments include: (1) Fabricated and Thermally-Charged 150 Forged Stainless Steel Samples with Tritium for Future Aging Studies; (2) Developed an Experimental Plan for Measuring Cracking Thresholds of Tritium-Charged-and-Aged Steels in High Pressure Hydrogen Gas; (3) Calculated Sample Tritium Contents For Laboratory Inventory Requirements and Environmental Release Estimates; (4) Published report on “Cracking Thresholds and Fracture Toughness Properties of Tritium-Charged-and-Aged Stainless Steels”; and, (5) Published report on “The Effects of Hydrogen, Tritium, and Heat Treatment on the Deformation and Fracture Toughness Properties of Stainless Steels”. These accomplishments are highlighted here and references given to additional reports for more detailed information.

  6. Wetting Properties of Liquid Lithium on Stainless Steel and Enhanced Stainless Steel Surfaces

    NASA Astrophysics Data System (ADS)

    Fiflis, P.; Xu, W.; Raman, P.; Andruczyk, D.; Ruzic, D. N.; Curreli, D.

    2012-10-01

    Research into lithium as a first wall material has proven its ability to effectively getter impurities and reduce recycling of hydrogen ions at the wall. Current schemes for introducing lithium into a fusion device consist of lithium evaporators, however, as these devices evolve from pulsed to steady state, new methods will need to be employed such as the LIMIT concept of UIUC, or thin flowing film lithium walls. Critical to their implementation is understanding the interactions of liquid lithium with various surfaces. One such interaction is the wetting of materials by lithium, which may be characterized by the contact angle between the lithium and the surface. Experiments have been performed at UIUC into the contact angle of liquid lithium with a given surface, as well as methods to increase it. To reduce the oxidation rate of the droplets, the experiments were performed in vacuum, using a lithium injector to deposit drops on each surface. Among the materials investigated are stainless steel, both untreated and coated with a diamond like carbon (DLC) layer, molybdenum, and boronized molybdenum. The contact angle and its dependence on temperature is measured.

  7. 77 FR 41969 - Stainless Steel Bar From Japan: Rescission of Antidumping Duty Administrative Review

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-07-17

    ... International Trade Administration Stainless Steel Bar From Japan: Rescission of Antidumping Duty Administrative...) initiated an administrative review of the antidumping duty order on stainless steel bar from Japan (the... review of the Order with respect to Misumi. See Letter from Suruga to the Secretary, ``Stainless...

  8. New hermetic sealing material for vacuum brazing of stainless steels

    NASA Astrophysics Data System (ADS)

    Hildebrandt, S.; Wiehl, G.; Silze, F.

    2016-03-01

    For vacuum brazing applications such as in vacuum interrupter industry Hermetic Sealing Materials (HSM) with low partial pressure are widely used. AgCu28 dominates the hermetic sealing market, as it has a very good wetting behavior on copper and metallized ceramics. Within recent decades wetting on stainless steel has become more and more important. However, today the silver content of HSMs is more in focus than in the past decades, because it has the biggest impact on the material prices. Umicore Technical Materials has developed a new copper based HSM, CuAg40Ga10. The wettability on stainless steel is significantly improved compared to AgCu28 and the total silver content is reduced by almost 44%. In this article the physical properties of the alloy and its brazed joints will be presented compared to AgCu28.

  9. Corrosion behavior of stainless steel-zirconium alloy waste forms.

    SciTech Connect

    Abraham, D. P.

    1999-01-13

    Stainless steel-zirconium (SS-Zr) alloys are being considered as waste forms for the disposal of metallic waste generated during the electrometallurgical treatment of spent nuclear fuel. The baseline waste form for spent fuels from the EBR-II reactor is a stainless steel-15 wt.% zirconium (SS-15Zr) alloy. This article briefly reviews the microstructure of various SS-Zr waste form alloys and presents results of immersion corrosion and electrochemical corrosion tests performed on these alloys. The electrochemical tests show that the corrosion behavior of SS-Zr alloys is comparable to those of other alloys being considered for the Yucca Mountain geologic repository. The immersion tests demonstrate that the SS-Zr alloys are resistant to selective leaching of fission product elements and, hence, suitable as candidates for high-level nuclear waste forms.

  10. Corrosion testing of stainless steel-zirconium metal waste form.

    SciTech Connect

    Abraham, D. P.

    1998-12-14

    Stainless steel-zirconium (SS-Zr) alloys are being considered as waste forms for the disposition of metallic waste generated during the electrometallurgical treatment of spent nuclear fuel. The waste forms contain irradiated cladding hulls, components of the alloy fuel, noble metal fission products, and actinide elements. The baseline waste form is a stainless steel-15 wt% zirconium (SS-15Zr) alloy. This article presents microstructure and some of the corrosion studies being conducted on the waste form alloys. Electrochemical corrosion, immersion corrosion, and vapor hydration tests have been performed on various alloy compositions to evaluate corrosion behavior and resistance to selective leaching of simulated fission products. The SS-Zr waste forms are successful at the immobilization and retention of fission products and show potential for acceptance as high-level nuclear waste forms.

  11. Surface treatment and corrosion behaviour of austenitic stainless steel biomaterial

    NASA Astrophysics Data System (ADS)

    Oravcová, M.; Palček, P.; Zatkalíková, V.; Tański, T.; Król, M.

    2017-02-01

    In this article results from corrosion behaviour of austenitic stainless steel AISI 316L after different surface treatments are published. “As received” surface and surface after grinding resulted in lower resistance to pitting corrosion in physiological solution than electrochemically polished in H3PO4+H2SO4+H2O. Electropolishing also improved the surface roughness in comparison with the “as received” surface. Deposition of Al2O3 nanometric ALD coating improves the corrosion resistance of stainless steel in chloride-containing environment by shifting the breakdown potential toward more positive values. This oxide coating not only improves the corrosion resistance but it also affects the wettability of the surface, resulting in hydrophobic surface.

  12. STAINLESS STEEL INTERACTIONS WITH SALT CONTAINING PLUTONIUM OXIDES

    SciTech Connect

    Nelson, Z.; Chandler, G.; Dunn, K.; Stefek, T.; Summer, M.

    2010-02-01

    Salt containing plutonium oxide materials are treated, packaged and stored within nested, stainless steel containers based on requirements established in the DOE 3013 Standard. The moisture limit for the stored materials is less than 0.5 weight %. Surveillance activities which are conducted to assess the condition of the containers and assure continuing 3013 container integrity include the destructive examination of a select number of containers to determine whether corrosion attack has occurred as a result of stainless steel interactions with salt containing plutonium oxides. To date, some corrosion has been observed on the innermost containers, however, no corrosion has been noted on the outer containers and the integrity of the 3013 container systems is not expected to be compromised over a 50 year storage lifetime.

  13. Investigation of Laser Peening Effects on Hydrogen Charged Stainless Steels

    SciTech Connect

    Zaleski, Tania M.

    2008-10-30

    Hydrogen-rich environments such as fuel cell reactors can exhibit damage caused by hydrogen permeation in the form of corrosion cracking by lowering tensile strength and decreasing material ductility. Coatings and liners have been investigated, but there were few shot-peening or laser peening studies referenced in the literature with respect to preventing hydrogen embrittlement. The surface compressive residual stress induced by laser peening had shown success in preventing stress corrosion cracking (SCC) for stainless steels in power plants. The question arose if the residual stresses induced by laser peening could delay the effects of hydrogen in a material. This study investigated the effect of laser peening on hydrogen penetration into metal alloys. Three areas were studied: laser peening, hydrogenation, and hydrogen detection. This study demonstrated that laser peening does not reduce the hydrogen permeation into a stainless steel surface nor does it prevent hydrogen embrittlement. The effect of laser peening to reduce hydrogen-assisted fatigue was unclear.

  14. Failure Assessment of Stainless Steel and Titanium Brazed Joints

    NASA Technical Reports Server (NTRS)

    Flom, Yury A.

    2012-01-01

    Following successful application of Coulomb-Mohr and interaction equations for evaluation of safety margins in Albemet 162 brazed joints, two additional base metal/filler metal systems were investigated. Specimens consisting of stainless steel brazed with silver-base filler metal and titanium brazed with 1100 Al alloy were tested to failure under combined action of tensile, shear, bending and torsion loads. Finite Element Analysis (FEA), hand calculations and digital image comparison (DIC) techniques were used to estimate failure stresses and construct Failure Assessment Diagrams (FAD). This study confirms that interaction equation R(sub sigma) + R(sub tau) = 1, where R(sub sigma) and R(sub t u) are normal and shear stress ratios, can be used as conservative lower bound estimate of the failure criterion in stainless steel and titanium brazed joints.

  15. Emissivity of sodium wetted and oxidized Type 304 stainless steel

    SciTech Connect

    Haines, N.L.; Craig, R.E.; Forsyth, D.R.; Novendstern, E.H.

    1980-01-01

    The emissivity of sodium wetted and oxidized Type 304 stainless steel was determined to provide data for calculating the heat flow through Liquid Metal Fast Breeder Reactor (LMFBR) reflector plates, located above the sodium pool, to the reactor closure head. An emissivity experiment using a Type 304 stainless steel specimen was performed in an inerted glovebox. Relatively high oxygen concentrations of 10,000 and 50 vppm were used in the argon/oxygen mixtures to reduce reaction time. Following wetting and oxidation, the specimen was heated to a maximum temperature of 450/sup 0/C and the emissivity of the oxidized coating was calculated. Results indicate that the emissivity of the coating ranged from 0.55 to 0.92.

  16. Milling and Drilling Evaluation of Stainless Steel Powder Metallurgy Alloys

    SciTech Connect

    Lazarus, L.J.

    2001-12-10

    Near-net-shape components can be made with powder metallurgy (PM) processes. Only secondary operations such as milling and drilling are required to complete these components. In the past and currently production components are made from powder metallurgy (PM) stainless steel alloys. process engineers are unfamiliar with the difference in machining properties of wrought versus PM alloys and have had to make parts to develop the machining parameters. Design engineers are not generally aware that some PM alloy variations can be furnished with machining additives that greatly increase tool life. Specimens from a MANTEC PM alloy property study were made available. This study was undertaken to determine the machining properties of a number of stainless steel wrought and PM alloys under the same conditions so that comparisons of their machining properties could be made and relative tool life determined.

  17. Interaction of cobalt with a stainless steel oxide surface

    SciTech Connect

    Taylor, J.B. )

    1991-01-01

    The deposition of radioactive cobalt ions from aqueous solutions in the pH range from 1 to 12 onto the internal surface of a stainless steel vessel or pipework can lead to the buildup of tenacious surface activity. For liquid streams of low specific activity (measured in becquerels per millilitre), the surface activity buildup may create a more dominant gamma radiation field than the activity suspended in the liquid. Failure to adequately predict this buildup for an operational nuclear plant can lead to an underestimate of potential gamma dose rates. This may lead to an economic penalty if additional shielding or other protective measures are necessary following plant operation. A theoretical method of determining the cobalt mass/activity deposition from aqueous liquor onto stainless steel is outlined in this paper. A validation of the method is given, and the limits of its application are discussed.

  18. Electrochemical Corrosion Testing of Borated Stainless Steel Alloys

    SciTech Connect

    lister, tedd e; Mizia, Ronald E

    2007-05-01

    The Department of Energy Office of Civilian Radioactive Waste Management has specified borated stainless steel manufactured to the requirements of ASTM A 887-89, Grade A, UNS S30464, to be the material used for the fabrication of the fuel basket internals of the preliminary transportation, aging, and disposal canister system preliminary design. The long-term corrosion resistance performance of this class of borated materials must be verified when exposed to expected YMP repository conditions after a waste package breach. Electrochemical corrosion tests were performed on crevice corrosion coupons of Type 304 B4 and Type 304 B5 borated stainless steels exposed to single postulated in-package chemistry at 60°C. The results show low corrosion rates for the test period

  19. Electrochemical Corrosion Testing of Borated Stainless Steel Alloys

    SciTech Connect

    lister, tedd e; Mizia, Ronald E

    2007-09-01

    The Department of Energy Office of Civilian Radioactive Waste Management has specified borated stainless steel manufactured to the requirements of ASTM A 887-89, Grade A, UNS S30464, to be the material used for the fabrication of the fuel basket internals of the preliminary transportation, aging, and disposal canister system preliminary design. The long-term corrosion resistance performance of this class of borated materials must be verified when exposed to expected YMP repository conditions after a waste package breach. Electrochemical corrosion tests were performed on crevice corrosion coupons of Type 304 B4 and Type 304 B5 borated stainless steels exposed to single postulated in-package chemistry at 60°C. The results show low corrosion rates for the test period

  20. Stainless steel porous substrates produced by tape casting

    NASA Astrophysics Data System (ADS)

    Mercadelli, Elisa; Gondolini, Angela; Pinasco, Paola; Sanson, Alessandra

    2017-01-01

    In this work the technological issues related to the production of tape cast large-area porous stainless steel supports for Solid Oxide Fuel Cells (SOFC) applications were carefully investigated. The slurry formulation was optimized in terms of amount and nature of the organic components needed: rice starch and polymethyl metacrylate were found to be, respectively, the most suitable pore former and binder because easily eliminated during the thermal treatment in reducing atmosphere. The compatibility of the binder system chosen with the most widely used solvents for screen printing inks was also evaluated. Finally the influence of the sintering temperature and of the refractory supports to be used during the thermal treatments onto the production of porous stainless steel supports was discussed. The whole process optimization allows to produce flat, crack-free metallic substrate 900-1000 μm thick, dimensions up to 5×5 cm and with a tailored porosity of 40% suitable for SOFCs application.

  1. Kinetic evaluation of intergranular fracture in austenitic stainless steels

    SciTech Connect

    Simonen, E.P.; Bruemmer, S.M.

    1995-12-31

    A second, higher-dose threshold exists for irradiation-assisted stress corrosion cracking (IASCC) of austenitic stainless steels in non-oxidizing environments. The data supporting this concept have stimulated interest in the mechanical aspects of intergranular (IG) fracture. Cracking in a non-oxidizing environment suggests that mechanically-induced IG fracture may play an important role in the IASCC mechanism under these conditions. Radiation alters deformation processes in austenitic alloys and may influence the fracture mode during either in-situ or post-irradiation straining. Radiation effects that must be considered include radiation strengthening, radiation creep and radiation-induced flow localization. The present evaluation relates these radiation-induced phenomena to IG fracture relevant to IASCC. The evaluation indicates that radiation strengthening retards matrix deformation and allows intergranular fracture to occur at higher stresses and lower temperatures than expected for unirradiated stainless steel.

  2. Technique to eliminate helium induced weld cracking in stainless steels

    SciTech Connect

    Chin-An Wang; Chin, B.A.; Grossbeck, M.L.

    1992-12-31

    Experiments have shown that Type 316 stainless steel is susceptible to heat-affected-zone (HAZ) cracking upon cooling when welded using the gas tungsten arc (GTA) process under lateral constraint. The cracking has been hypothesized to be caused by stress-assisted helium bubble growth and rupture at grain boundaries. This study utilized an experimental welding setup which enabled different compressive stresses to be applied to the plates during welding. Autogenous GTA welds were produced in Type 316 stainless steel doped with 256 appm helium. The application of a compressive stress, 55 Mpa, during welding suppressed the previously observed catastrophic cracking. Detailed examinations conducted after welding showed a dramatic change in helium bubble morphology. Grain boundary bubble growth along directions parallel to the weld was suppressed. Results suggest that stress-modified welding techniques may be used to suppress or eliminate helium-induced cracking during joining of irradiated materials.

  3. 77 FR 13631 - Drawn Stainless Steel Sinks From China; Institution and Scheduling of Preliminary Phase...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-03-07

    ... From the Federal Register Online via the Government Publishing Office INTERNATIONAL TRADE COMMISSION Drawn Stainless Steel Sinks From China; Institution and Scheduling of Preliminary Phase... the United States is materially retarded, by reason of imports from China of drawn stainless...

  4. SELECTIVE SEPARATION OF URANIUM FROM FERRITIC STAINLESS STEELS

    DOEpatents

    Beaver, R.J.; Cherubini, J.H.

    1963-05-14

    A process is described for separating uranium from a nuclear fuel element comprising a uranium-containing core and a ferritic stainless steel clad by heating said element in a non-carburizing atmosphere at a temperature in the range 850-1050 un. Concent 85% C, rapidly cooling the heated element through the temperature range 815 un. Concent 85% to 650 EC to avoid annealing said steel, and then contacting the cooled element with an aqueous solution of nitric acid to selectively dissolve the uranium. (AEC)

  5. Stainless steel mesh-acrylic cranioplasty.

    PubMed

    Tysvaer, A T; Hovind, K H

    1977-03-01

    Twenty-four steel mesh-acrylic plates have been used for repair of skull defects in 1970-73. Three plates had to be removed due to complications, two due to infection and one due to an allergic reaction. The plate is easy to mould, strong, and light. The cosmetic results are excellent.

  6. Surface nanocrystallization of stainless steel for reduced biofilm adherence

    NASA Astrophysics Data System (ADS)

    Yu, Bin; Davis, Elisabeth M.; Hodges, Robert S.; Irvin, Randall T.; Li, D. Y.

    2008-08-01

    Stainless steel is one of the most common metallic biomedical materials. For medical applications, its resistance to the adherence of biofilms is of importance to the elimination or minimization of bacterial infections. In this study, we demonstrate the effectiveness of a process combining surface nanocrystallization and thermal oxidation (or a recovery heat treatment in air) for reducing the biofilm's adherence to stainless steel. During this treatment, a target surface was sandblasted and the resultant dislocation cells in the surface layer were turned into nanosized grains by a subsequent recovery treatment in air. This process generated a more protective oxide film that blocked the electron exchange or reduced the surface activity more effectively. As a result, the biofilm's adherence to the treated surface was markedly minimized. A synthetic peptide was utilized as a substitute of biofilms to evaluate the adhesion between a treated steel surface and biofilms using an atomic force microscope (AFM) through measuring the adhesive force between the target surface and a peptide-coated AFM tip. It was shown that the adhesive force decreased with a decrease in the grain size of the steel. The corresponding surface electron work function (EWF) of the steel was also measured, which showed a trend of variation in EWF with the grain size, consistent with corresponding changes in the adhesive force.

  7. Method of polishing nickel-base alloys and stainless steels

    DOEpatents

    Steeves, Arthur F.; Buono, Donald P.

    1981-01-01

    A chemical attack polish and polishing procedure for use on metal surfaces such as nickel base alloys and stainless steels. The chemical attack polish comprises Fe(NO.sub.3).sub.3, concentrated CH.sub.3 COOH, concentrated H.sub.2 SO.sub.4 and H.sub.2 O. The polishing procedure includes saturating a polishing cloth with the chemical attack polish and submicron abrasive particles and buffing the metal surface.

  8. Attack polish for nickel-base alloys and stainless steels

    DOEpatents

    Steeves, Arthur F.; Buono, Donald P.

    1983-01-01

    A chemical attack polish and polishing procedure for use on metal surfaces such as nickel base alloys and stainless steels. The chemical attack polish comprises Fe(NO.sub.3).sub.3, concentrated CH.sub.3 COOH, concentrated H.sub.2 SO.sub.4 and H.sub.2 O. The polishing procedure includes saturating a polishing cloth with the chemical attack polish and submicron abrasive particles and buffing the metal surface.

  9. Attack polish for nickel-base alloys and stainless steels

    DOEpatents

    Not Available

    1980-05-28

    A chemical attack polish and polishing procedure for use on metal surfaces such as nickel base alloys and stainless steels is described. The chemical attack polich comprises FeNO/sub 3/, concentrated CH/sub 3/COOH, concentrated H/sub 2/SO/sub 4/ and H/sub 2/O. The polishing procedure includes saturating a polishing cloth with the chemical attack polish and submicron abrasive particles and buffing the metal surface.

  10. An improved method for stainless steel wire mesh cranioplasty.

    PubMed

    Forni, C; Pagni, C A

    1985-07-01

    A method for stainless steel wire mesh cranioplasty is described. The method has proved simple and quick. Cosmetic results have been very good and no complications have been observed so far. This method seems particularly suitable in very large skull defects. It seems to reduce the incidence of the major complications of the wire mesh cranioplasties, viz. lifting of the margins, depression of the prosthetic vault and electrolytic interference with the circulating fluids.

  11. Manganese-stabilized austenitic stainless steels for fusion applications

    DOEpatents

    Klueh, Ronald L.; Maziasz, Philip J.

    1990-08-07

    An austenitic stainless steel that is comprised of Fe, Cr, Mn, C but no Ni or Nb and minimum N. To enhance strength and fabricability minor alloying additions of Ti, W, V, B and P are made. The resulting alloy is one that can be used in fusion reactor environments because the half-lives of the elements are sufficiently short to allow for handling and disposal.

  12. Manganese-stabilized austenitic stainless steels for fusion applications

    DOEpatents

    Klueh, Ronald L.; Maziasz, Philip J.

    1990-01-01

    An austenitic stainless steel that is comprised of Fe, Cr, Mn, C but no Ni or Nb and minimum N. To enhance strength and fabricability minor alloying additions of Ti, W, V, B and P are made. The resulting alloy is one that can be used in fusion reactor environments because the half-lives of the elements are sufficiently short to allow for handling and disposal.

  13. Laser surface modification of 316L stainless steel.

    PubMed

    Balla, Vamsi Krishna; Dey, Sangeetha; Muthuchamy, Adiyen A; Janaki Ram, G D; Das, Mitun; Bandyopadhyay, Amit

    2017-02-28

    Medical grade 316L stainless steel was laser surface melted (LSM) using continuous wave Nd-YAG laser in argon atmosphere at 1 and 5 mm/s. The treated surfaces were characterized using electron backscatter diffraction to study the influence of top surface crystallographic orientation and type of grain boundaries on corrosion resistance, wettability, and biocompatibility. The laser scan velocity was found to have a marginal influence on the surface roughness and the type of grain boundaries. However, the crystal orientation density was found to be relatively high in 1 mm/s samples. The LSM samples showed a higher concentration of {101} and {123} planes parallel to the sample surface as well as a higher fraction of low-angle grain boundaries. The LSM samples were found to exhibit better surface wettability and enhanced the viability and proliferation of human fetal osteoblast cells in vitro when compared to the untreated samples. Further, the corrosion protection efficiency of 316L stainless steel was improved up to 70% by LSM in as-processed condition. The increased concentration of {101} and {123} planes on surfaces of LSM samples increases their surface energy, which is believed to be responsible for the improved in vitro cell proliferation. Further, the increased lattice spacing of these planes and high concentration of low-energy grain boundaries in LSM samples would have contributed to the better in vitro corrosion resistance than untreated 316L stainless steel. Our results indicate that LSM can be a potential treatment option for 316L stainless steel-based biomedical devices to improve biocompatibility and corrosion resistance. © 2017 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater, 2017.

  14. Linear Friction Welding Process Model for Carpenter Custom 465 Precipitation-Hardened Martensitic Stainless Steel

    DTIC Science & Technology

    2014-04-11

    Carpenter Custom 465 precipitation-hardened martensitic stainless steel to develop a linear friction welding (LFW) process model for this material...Model for Carpenter Custom 465 Precipitation-Hardened Martensitic Stainless Steel The views, opinions and/or findings contained in this report are...Carpenter Custom 465 precipitation-hardened martensiticstainless steel , linear friction welding, process modeling REPORT DOCUMENTATION PAGE 11

  15. 76 FR 34964 - Stainless Steel Bar From India: Partial Rescission of Antidumping Duty Administrative Review

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-06-15

    ... FR 5559 (February 1, 2011). On February 28, 2011, Venus Wire Industries Pvt. Ltd (``Venus'') and... review of Venus, Ambica Steels Limited (``Ambica''), Atlas Stainless Corporation (``Atlas Stainless..., Chandan, Facor, Grand Foundry, India Steel, Meltroll, Mukand, Sindia Steels, Snowdrop and Venus....

  16. 75 FR 973 - Certain Welded Stainless Steel Pipes From the Republic of Korea: Preliminary Results of...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-01-07

    ... International Trade Administration Certain Welded Stainless Steel Pipes From the Republic of Korea: Preliminary... administrative review of the antidumping duty order on certain welded stainless steel pipes (WSSP) from the... review covers one respondent, SeAH Steel Corporation (SeAH). We preliminarily determine that sales...

  17. Impact Testing of Stainless Steel Material at Cold Temperatures

    SciTech Connect

    Spencer D. Snow; D. Keith Morton; Robert K. Blandford

    2008-07-01

    Stainless steels are used for the construction of numerous spent nuclear fuel or radioactive material containers that may be subjected to high strains and moderate strain rates during accidental drop events. Mechanical characteristics of these base materials and their welds under dynamic loads in the strain rate range of concern are not well documented. However, a previous paper [1] reported on impact testing and analysis results performed at the Idaho National Laboratory using 304/304L and 316/316L stainless steel base material specimens at room and elevated temperatures. The goal of the work presented herein is to add recently completed impact tensile testing results at -20 degrees F conditions for dual-marked 304/304L and 316/316L stainless steel material specimens (hereafter referred to as 304L and 316L, respectively). Recently completed welded material impact testing at -20 degrees F, room, 300 degrees F, and 600 degrees F is also reported. Utilizing a drop-weight impact test machine and 1/4-inch to 1/2-inch thick dog-bone shaped test specimens, the impact tests achieved strain rates in the 4 to 40 per second range, depending upon the material temperature. Elevated true stress-strain curves for these materials reflecting varying strain rates and temperatures are presented herein.

  18. Austenitic stainless steel patterning by plasma assisted diffusion treatments

    NASA Astrophysics Data System (ADS)

    Czerwiec, T.; Marcos, G.; Thiriet, T.; Guo, Y.; Belmonte, T.

    2009-09-01

    The new concept of surface texturing or surface patterning on austenitic stainless steel by plasma assisted diffusion treatment is presented in this paper. It allows the creation of uniform micro or nano relief with regularly shaped asperities or depressions. Plasma assisted diffusion treatments are based on the diffusion of nitrogen and/or carbon in a metallic material at moderate to elevated temperatures. Below 420°C, a plasma assisted nitriding treatment of austenitic stainless steel produces a phase usually called expanded austenite. Expanded austenite is a metastable nitrogen supersaturated solid solution with a disordered fcc structure and a distorted lattice. The nitrided layer with the expanded austenite is highly enriched in nitrogen (from 10 to 35 at%) and submitted to high compressive residual stresses. From mechanical consideration, it is shown that the only possible deformation occurs in the direction perpendicular to the surface. Such an expansion of the layer from the initial surface of the substrate to the gas phase is used here for surface patterning of stainless steel parts. The surface patterning is performed by using masks (TEM grid) and multi-dipolar plasmas.

  19. Thermo-mechanical behavior of stainless steel knitted structures

    NASA Astrophysics Data System (ADS)

    Hamdani, Syed Talha Ali; Fernando, Anura; Maqsood, Muhammad

    2016-09-01

    Heating fabric is an advanced textile material that is extensively researched by the industrialists and the scientists alike. Ability to create highly flexible and drapeable heating fabrics has many applications in everyday life. This paper presents a study conducted on the comparison of heatability of knitted fabric made of stainless steel yarn. The purpose of the study is to find a suitable material for protective clothing against cold environments. In the current research the ampacity of stainless steel yarn is observed in order to prevent the overheating of the heating fabrics. The behavior of the knitted structure is studied for different levels of supply voltage. Infrared temperature sensing is used to measure the heat generated from the fabrics in order to measure the temperature of the fabrics without physical contact. It is concluded that interlock structure is one of the most suited structures for knitted heating fabrics. As learnt through this research, fabrics made of stainless steel yarn are capable of producing a higher level of heating compared to that of knitted fabric made using silver coated polymeric yarn at the same supply voltage.

  20. Mechanical Properties of Austenitic Stainless Steel Made by Additive Manufacturing

    PubMed Central

    Luecke, William E; Slotwinski, John A

    2014-01-01

    Using uniaxial tensile and hardness testing, we evaluated the variability and anisotropy of the mechanical properties of an austenitic stainless steel, UNS S17400, manufactured by an additive process, selective laser melting. Like wrought materials, the mechanical properties depend on the orientation introduced by the processing. The recommended stress-relief heat treatment increases the tensile strength, reduces the yield strength, and decreases the extent of the discontinuous yielding. The mechanical properties, assessed by hardness, are very uniform across the build plate, but the stress-relief heat treatment introduced a small non-uniformity that had no correlation to position on the build plate. Analysis of the mechanical property behavior resulted in four conclusions. (1) The within-build and build-to-build tensile properties of the UNS S17400 stainless steel are less repeatable than mature engineering structural alloys, but similar to other structural alloys made by additive manufacturing. (2) The anisotropy of the mechanical properties of the UNS S17400 material of this study is larger than that of mature structural alloys, but is similar to other structural alloys made by additive manufacturing. (3) The tensile mechanical properties of the UNS S17400 material fabricated by selective laser melting are very different from those of wrought, heat-treated 17-4PH stainless steel. (4) The large discontinuous yielding strain in all tests resulted from the formation and propagation of Lüders bands. PMID:26601037

  1. Iodine susceptibility of pseudomonads grown attached to stainless steel surfaces

    NASA Technical Reports Server (NTRS)

    Pyle, B. H.; McFeters, G. A.

    1990-01-01

    Pseudomonads were adapted to grow in phosphate-buffered water and on stainless steel surfaces to study the iodine sensitivity of attached and planktonic cells. Cultures adapted to low nutrient growth were incubated at room temperature in a circulating reactor system with stainless steel coupons to allow biofilm formation on the metal surfaces. In some experiments, the reactor was partially emptied and refilled with buffer at each sampling time to simulate a "fill-and-draw" water system. Biofilms of attached bacteria, resuspended biofilm bacteria, and reactor suspension, were exposed to 1 mg l-1 iodine for 2 min. Attached bacterial populations which established on coupons within 3 to 5 days displayed a significant increase in resistance to iodine. Increased resistance was also observed for resuspended cells from the biofilm and planktonic bacteria in the system suspension. Generally, intact biofilms and resuspended biofilm cells were most resistant, followed by planktonic bacteria and phosphate buffer cultures. Thus, biofilm formation on stainless steel surfaces within water systems can result in significantly increased disinfection resistance of commonly-occurring water-borne bacteria that may enhance their ability to colonise water treatment and distribution systems.

  2. Stress corrosion cracking evaluation of martensitic precipitation hardening stainless steels

    NASA Technical Reports Server (NTRS)

    Humphries, T. S.; Nelson, E. E.

    1980-01-01

    The resistance of the martensitic precipitation hardening stainless steels PH13-8Mo, 15-5PH, and 17-4PH to stress corrosion cracking was investigated. Round tensile and c-ring type specimens taken from several heats of the three alloys were stressed up to 100 percent of their yield strengths and exposed to alternate immersion in salt water, to salt spray, and to a seacoast environment. The results indicate that 15-5PH is highly resistant to stress corrosion cracking in conditions H1000 and H1050 and is moderately resistant in condition H900. The stress corrosion cracking resistance of PH13-8Mo and 17-4PH stainless steels in conditions H1000 and H1050 was sensitive to mill heats and ranged from low to high among the several heats included in the tests. Based on a comparison with data from seacoast environmental tests, it is apparent that alternate immersion in 3.5 percent salt water is not a suitable medium for accelerated stress corrosion testing of these pH stainless steels.

  3. Mechanical Properties of Austenitic Stainless Steel Made by Additive Manufacturing.

    PubMed

    Luecke, William E; Slotwinski, John A

    2014-01-01

    Using uniaxial tensile and hardness testing, we evaluated the variability and anisotropy of the mechanical properties of an austenitic stainless steel, UNS S17400, manufactured by an additive process, selective laser melting. Like wrought materials, the mechanical properties depend on the orientation introduced by the processing. The recommended stress-relief heat treatment increases the tensile strength, reduces the yield strength, and decreases the extent of the discontinuous yielding. The mechanical properties, assessed by hardness, are very uniform across the build plate, but the stress-relief heat treatment introduced a small non-uniformity that had no correlation to position on the build plate. Analysis of the mechanical property behavior resulted in four conclusions. (1) The within-build and build-to-build tensile properties of the UNS S17400 stainless steel are less repeatable than mature engineering structural alloys, but similar to other structural alloys made by additive manufacturing. (2) The anisotropy of the mechanical properties of the UNS S17400 material of this study is larger than that of mature structural alloys, but is similar to other structural alloys made by additive manufacturing. (3) The tensile mechanical properties of the UNS S17400 material fabricated by selective laser melting are very different from those of wrought, heat-treated 17-4PH stainless steel. (4) The large discontinuous yielding strain in all tests resulted from the formation and propagation of Lüders bands.

  4. Thermal Aging Phenomena in Cast Duplex Stainless Steels

    SciTech Connect

    Byun, T. S.; Yang, Y.; Overman, N. R.; Busby, J. T.

    2015-11-12

    We used cast stainless steels (CASSs)for the large components of light water reactor (LWR) power plants such as primary coolant piping and pump casing. The thermal embrittlement of CASS components is one of the most serious concerns related to the extended-term operation of nuclear power plants. Many past researches have concluded that the formation of Cr-rich alpha-phase by Spinodal decomposition of delta-ferrite phase is the primary mechanism for the thermal embrittlement. Cracking mechanism in the thermally-embrittled duplex stainless steels consists of the formation of cleavage at ferrite and its propagation via separation of ferrite-austenite interphase. This article intends to provide an introductory overview on the thermal aging phenomena in LWR-relevant conditions. Firstly, the thermal aging effect on toughness is discussed in terms of the cause of embrittlement and influential parameters. Moreover, an approximate analysis of thermal reaction using Arrhenius equation was carried out to scope the aging temperatures for the accelerated aging experiments to simulate the 60 and 80 years of services. Further, an equilibrium precipitation calculation was performed for model CASS alloys using the CALPHAD program, and the results are used to describe the precipitation behaviors in duplex stainless steels. Our results are also to be used to guide an on-going research aiming to provide knowledge-based conclusive prediction for the integrity of the CASS components of LWR power plants during the service life extended up to and beyond 60 years.

  5. Electroless Plated Nanodiamond Coating for Stainless Steel Passivation

    SciTech Connect

    Li, D.; Korinko, P.; Spencer, W.; Stein, E.

    2016-09-15

    Tritium gas sample bottles and manifold components require passivation surface treatments to minimize the interaction of the hydrogen isotopes with surface contamination on the stainless steel containment materials. Conventional passivation processes using chemical and electrochemical means are usually insufficient to passivate tritium containment vessels and piping. Previous work demonstrated that both nitric acid and citric acid passivation on stainless steel would not prevent the catalyzed isotope exchange reaction H2 + D2 → 2HD, while electropolishing passivation resulted in surfaces that did not catalyze this hydrogen isotope exchange. The current vendor for surface passivation treatment, Tek-Vac Industries Inc., provided the best passivation technology for the stainless steel components used at SRTE. However, this vendor recently built gas sample bottles that failed to meet site criteria and has since ceased operations. The loss of this vendor created a source gap, as well as a knowledge gap. A practical and reliable robust process to develop tritium passive surfaces is needed.

  6. Thermal Aging Phenomena in Cast Duplex Stainless Steels

    SciTech Connect

    Byun, T. S.; Yang, Y.; Overman, N. R.; Busby, J. T.

    2016-02-28

    Cast stainless steels (CASSs) have been extensively used for the large components of light water reactor (LWR) power plants such as primary coolant piping and pump casing. The thermal embrittlement of CASS components is one of the most serious concerns related to the extended-term operation of nuclear power plants. Many past researches have concluded that the formation of Cr–rich α'-phase by Spinodal decomposition of δ-ferrite phase is the primary mechanism for the thermal embrittlement. Cracking mechanism in the thermally-embrittled duplex stainless steels consists of the formation of cleavage at ferrite and its propagation via separation of ferrite-austenite interphase. This article intends to provide an introductory overview on the thermal aging phenomena in LWR relevant conditions. Firstly, the thermal aging effect on toughness is discussed in terms of the cause of embrittlement and influential parameters. An approximate analysis of thermal reaction using Arrhenius equation was carried out to scope the aging temperatures for the accelerated aging experiments to simulate the 60 and 80 years of services. Further, equilibrium precipitation calculation was performed for model CASS alloys using the CALPHAD program and the results are used to describe the precipitation behaviors in duplex stainless steels. These results are also to be used to guide an on-going research aiming to provide knowledge-based conclusive prediction for the integrity of the CASS components of LWR power plants during the service life extended up to and beyond 60 years.

  7. Surface interactions of cesium and boric acid with stainless steel

    SciTech Connect

    Grossman-Canfield, N.

    1995-08-01

    In this report, the effects of cesium hydroxide and boric acid on oxidized stainless steel surfaces at high temperatures and near one atmosphere of pressure are investigated. This is the first experimental investigation of this chemical system. The experimental investigations were performed using a mass spectrometer and a mass electrobalance. Surfaces from the different experiments were examined using a scanning electron microscope to identify the presence of deposited species, and electron spectroscopy for chemical analysis to identify the species deposited on the surface. A better understanding of the equilibrium thermodynamics, the kinetics of the steam-accelerated volatilizations, and the release kinetics are gained by these experiments. The release rate is characterized by bulk vaporization/gas-phase mass transfer data. The analysis couples vaporization, deposition, and desorption of the compounds formed by cesium hydroxide and boric acid under conditions similar to what is expected during certain nuclear reactor accidents. This study shows that cesium deposits on an oxidized stainless steel surface at temperatures between 1000 and 1200 Kelvin. Cesium also deposits on stainless steel surfaces coated with boric oxide in the same temperature ranges. The mechanism for cesium deposition onto the oxide layer was found to involve the chemical reaction between cesium and chromate. Some revaporization in the cesium hydroxide-boric acid system was observed. It has been found that under the conditions given, boric acid will react with cesium hydroxide to form cesium metaborate. A model is proposed for this chemical reaction.

  8. Thermal Aging Phenomena in Cast Duplex Stainless Steels

    NASA Astrophysics Data System (ADS)

    Byun, T. S.; Yang, Y.; Overman, N. R.; Busby, J. T.

    2016-02-01

    Cast stainless steels (CASSs) have been extensively used for the large components of light water reactor (LWR) power plants such as primary coolant piping and pump casing. The thermal embrittlement of CASS components is one of the most serious concerns related to the extended-term operation of nuclear power plants. Many past researches have concluded that the formation of Cr-rich α'-phase by Spinodal decomposition of δ-ferrite phase is the primary mechanism for the thermal embrittlement. Cracking mechanism in the thermally-embrittled duplex stainless steels consists of the formation of cleavage at ferrite and its propagation via separation of ferrite-austenite interphase. This article intends to provide an introductory overview on the thermal aging phenomena in LWR-relevant conditions. Firstly, the thermal aging effect on toughness is discussed in terms of the cause of embrittlement and influential parameters. An approximate analysis of thermal reaction using Arrhenius equation was carried out to scope the aging temperatures for the accelerated aging experiments to simulate the 60 and 80 years of services. Further, an equilibrium precipitation calculation was performed for model CASS alloys using the CALPHAD program, and the results are used to describe the precipitation behaviors in duplex stainless steels. These results are also to be used to guide an on-going research aiming to provide knowledge-based conclusive prediction for the integrity of the CASS components of LWR power plants during the service life extended up to and beyond 60 years.

  9. Compatibility Assessment of Advanced Stainless Steels in Sodium

    SciTech Connect

    Pawel, Steven J

    2012-01-01

    Type 316L stainless steel capsules containing commercially pure sodium and miniature tensile specimens of HT-UPS (austenitic, 14Cr-16Ni), NF-616 (ferritic/martensitic, 9Cr-2W-0.5Mo), or 316L (austenitic, 17Cr-10Ni-2Mo) stainless steel were exposed at 600 or 700 C for 100 and 400 h as a screening test for compatibility. Using weight change, tensile testing, and metallographic analysis, HT-UPS and 316L were found to be largely immune to changes resulting from sodium exposure, but NF-616 was found susceptible to substantial decarburization at 700 C. Subsequently, two thermal convection loops (TCLs) constructed of 316L and loaded with commercially pure sodium and miniature tensile specimens of HT-UPS and 316L were operated for 2000 h each one between 500 and 650 C, the other between 565 and 725 C at a flow rate of about 1.5 cm/s. Changes in specimen appearance, weight, and tensile properties were observed to be very minor in all cases, and there was no metallographic evidence of microstructure changes, composition gradients, or mass transfer resulting from prolonged exposure in a TCL. Thus, it appears that HT-UPS and 316L stainless steels are similarly compatible with commercially pure sodium under these exposure conditions.

  10. Mechanical Behavior and Fractography of 304 Stainless Steel with High Hydrogen Concentration

    SciTech Connect

    Au, M.

    2003-02-05

    Hydrogen embrittlement of 304 stainless steel with different hydrogen concentrations has been investigated. An electrochemical technique was used to effectively charge the high level of hydrogen into 304 stainless steel in a short period of time. At 25 ppm of hydrogen, 304 stainless steel loses 10 percent of its original mechanical strength and 20 percent plasticity. Although the ductile feature dominates the fractography, the brittle crown area near the outer surface shows the intergranular rupture effected by hydrogen. At 60 ppm of hydrogen, 304 stainless steel loses 23 percent of its strength and 38 percent plasticity, where the brittle mode dominates the fracture of the materials. Experimental results show that hydrogen damage to the performance of 304 stainless steel is significant even at very low levels. The fractograph analysis indicates the high penetration ability of hydrogen in 304 stainless steel. This work also demonstrates the advantages of the electrochemical charging technique in the study of hydrogen embrittlement.

  11. Microstructural characterization in dissimilar friction stir welding between 304 stainless steel and st37 steel

    SciTech Connect

    Jafarzadegan, M.; Feng, A.H.; Abdollah-zadeh, A.; Saeid, T.; Shen, J.; Assadi, H.

    2012-12-15

    In the present study, 3 mm-thick plates of 304 stainless steel and st37 steel were welded together by friction stir welding at a welding speed of 50 mm/min and tool rotational speed of 400 and 800 rpm. X-ray diffraction test was carried out to study the phases which might be formed in the welds. Metallographic examinations, and tensile and microhardness tests were used to analyze the microstructure and mechanical properties of the joint. Four different zones were found in the weld area except the base metals. In the stir zone of the 304 stainless steel, a refined grain structure with some features of dynamic recrystallization was evidenced. A thermomechanically-affected zone was characterized on the 304 steel side with features of dynamic recovery. In the other side of the stir zone, the hot deformation of the st37 steel in the austenite region produced small austenite grains and these grains transformed to fine ferrite and pearlite and some products of displacive transformations such as Widmanstatten ferrite and martensite by cooling the material after friction stir welding. The heat-affected zone in the st37 steel side showed partially and fully refined microstructures like fusion welding processes. The recrystallization in the 304 steel and the transformations in the st37 steel enhanced the hardness of the weld area and therefore, improved the tensile properties of the joint. - Highlights: Black-Right-Pointing-Pointer FSW produced sound welds between st37 low carbon steel and 304 stainless steel. Black-Right-Pointing-Pointer The SZ of the st37 steel contained some products of allotropic transformation. Black-Right-Pointing-Pointer The material in the SZ of the 304 steel showed features of dynamic recrystallization. Black-Right-Pointing-Pointer The finer microstructure in the SZ increased the hardness and tensile strength.

  12. Particle Impact Ignition Test Data on a Stainless Steel Hand Valve

    NASA Technical Reports Server (NTRS)

    Peralta, Stephen

    2010-01-01

    This slide presentation reviews the particle impact ignition test of a stainless steel hand valve. The impact of particles is a real fire hazard with stainless steel hand valves, however 100 mg of particulate can be tolerated. Since it is unlikely that 100 mg of stainless steel contaminant particles can be simultaneously released into this type of valve in the WSTF configuration, this is acceptable and within statistical confidence as demonstrated by testing.

  13. New research progressing of surface modification of medical 316L stainless steels

    NASA Astrophysics Data System (ADS)

    Xu, Lin; Ba, Dechun; Wang, Qing; Guo, Deyu

    2013-12-01

    316L stainless steels are widely used in clinical and medical fields because of their comprehensive performance. This paper analyses the current development situation and major existing problems of medical 316L stainless steels. The new methods and research achievement of surface modification in recent years are described in detail. It indicates that surface modification is an effective way to solve clinical application problems, and provides new opportunities for medical 316L stainless steels in medical applications.

  14. Evaluation of stainless steel cladding for use in current design LWRs. Final report

    SciTech Connect

    Strasser, A.; Santucci, J.; Lindquist, K.; Yario, W.; Stern, G.; Goldstein, L.; Joseph, L.

    1982-12-01

    The design of stainless steel-clad LWR fuel and its performance at steady-state, transient, and accident conditions were reviewed. The objective was to evaluate the potential benefits and disadvantages of substituting stainless steel-clad fuel for the currently used Zircaloy-clad fuel. For a large, modern PWR, the technology and the fuel-cycle costs of stainless steel- and Zircaloy-clad fuels were compared.

  15. Stainless steel and silicon direct interface synthesis: Chemical bonding effects

    NASA Astrophysics Data System (ADS)

    Cox, Michael J.

    Planar stainless steel/stainless steel interfaces, with and without a titanium interlayer and silicon/silicon interfaces have been produced in an ultra high vacuum (UHV) diffusion bonding/deposition instrument. Interface synthesis was accomplished by diffusion bonding two substrates after subjecting the substrate surfaces to a variety of pre-bonding treatments including heat treating, ion-beam sputter cleaning and thin film deposition. Chemical characterization was performed in situ by Auger electron spectroscopy (AES) prior to deposition and/or bonding and ex situ by energy dispersive X-ray spectroscopy (EDS) and electron energy loss spectroscopy (EELS). Additionally, transmission electron microscopy (TEM), scanning electron microscopy (SEM) and atomic force microscopy (AFM) were used to study interfaces before and after bonding. Diffusion bonding behavior of stainless steel depends strongly on the chemistry of the surfaces to be bonded. Very smooth, mechanically polished and lapped substrates would bond completely in UHV in 1 hour at 1000°C under 3.5 MPa uniaxial pressure, if the native oxide on the substrates was removed by ion beam cleaning. No voids were observed in these bonded interfaces as studied by TEM and the strength was equal to the unbonded bare material. When an electron beam deposited, 200 A titanium interlayer was added to the stainless steel interface, while bonding under the same conditions, mechanical tensile testing resulted in very low strength when compared with that of chemically clean stainless steel interfaces. Analytical inspection of the interfaces, performed with EELS, EDS, and convergent beam electron diffraction (CBED) coupled with images from TEM and SEM, showed the reason for the significantly reduced strength is a result of limited contact area and delamination between titanium carbide particles precipitated in the interface. Silicon wafers bicrystals were synthesized by bonding two single-crystal substrates. Silicon wafers were

  16. 77 FR 73013 - Stainless Steel Plate in Coils From Belgium: Antidumping Duty Administrative Review, 2010-2011

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-12-07

    ... International Trade Administration Stainless Steel Plate in Coils From Belgium: Antidumping Duty Administrative... results of the antidumping duty order on stainless steel plate in coils (steel plate) from Belgium.\\1... Administrative Review: Stainless Steel Plate in Coils from Belgium. Extension of Deadline for Final...

  17. 77 FR 32517 - Stainless Steel Plate in Coils From Belgium: Notice of Preliminary Results of Antidumping Duty...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-06-01

    ... International Trade Administration Stainless Steel Plate in Coils From Belgium: Notice of Preliminary Results of... review of the antidumping duty order on stainless steel plate in coils (steel plate) from Belgium.... (AMS Belgium) in an antidumping changed circumstances review. See Stainless Steel Plate in Coils...

  18. Improved corrosion resistance of 316L stainless steel by nanocrystalline and electrochemical nitridation in artificial saliva solution

    NASA Astrophysics Data System (ADS)

    Lv, Jinlong; Liang, Tongxiang

    2015-12-01

    The fluoride ion in artificial saliva significantly changed semiconductor characteristic of the passive film formed on the surface of 316L stainless steels. The electrochemical results showed that nanocrystalline α‧-martensite improved corrosion resistance of the stainless steel in a typical artificial saliva compared with coarse grained stainless steel. Moreover, comparing with nitrided coarse grained stainless steel, corrosion resistance of the nitrided nanocrystalline stainless steel was also improved significantly, even in artificial saliva solution containing fluoride ion. The present study showed that the cryogenic cold rolling and electrochemical nitridation improved corrosion resistance of 316L stainless steel for the dental application.

  19. Electrochemical and passivation behavior investigation of ferritic stainless steel in simulated concrete pore media.

    PubMed

    Luo, Hong; Su, Huaizhi; Dong, Chaofang; Xiao, Kui; Li, Xiaogang

    2015-12-01

    The applications of stainless steel are one of the most reliable solutions in concrete structures to reduce chloride-induced corrosion problems and increase the structures service life, however, due to high prices of nickel, especially in many civil engineering projects, the austenitic stainless steel is replaced by the ferritic stainless steels. Compared with austenite stainless steel, the ferritic stainless steel is known to be extremely resistant of stress corrosion cracking and other properties. The good corrosion resistance of the stainless steel is due to the formation of passive film. While, there is little literature about the electrochemical and passive behavior of ferritic stainless steel in the concrete environments. So, here, we present the several corrosion testing methods, such as the potentiodynamic measurements, EIS and Mott-Schottky approach, and the surface analysis methods like XPS and AES to display the passivation behavior of 430 ferritic stainless steel in alkaline solution with the presence of chloride ions. These research results illustrated a simple and facile approach for studying the electrochemical and passivation behavior of stainless steel in the concrete pore environments.

  20. Fabrication of stainless steel spherical anodes for use with boat-mounted boom electroshocker

    USGS Publications Warehouse

    Martinez, Patrick J.; Tiffan, Kenneth F.

    1992-01-01

    A frugal method of fabricating spherical anodes from stainless steel mixing bowls is presented. We believe that the purported mechanical disadvantages of using spherical electrodes are largely unfounded.

  1. Electrochemical and passivation behavior investigation of ferritic stainless steel in simulated concrete pore media

    PubMed Central

    Luo, Hong; Su, Huaizhi; Dong, Chaofang; Xiao, Kui; Li, Xiaogang

    2015-01-01

    The applications of stainless steel are one of the most reliable solutions in concrete structures to reduce chloride-induced corrosion problems and increase the structures service life, however, due to high prices of nickel, especially in many civil engineering projects, the austenitic stainless steel is replaced by the ferritic stainless steels. Compared with austenite stainless steel, the ferritic stainless steel is known to be extremely resistant of stress corrosion cracking and other properties. The good corrosion resistance of the stainless steel is due to the formation of passive film. While, there is little literature about the electrochemical and passive behavior of ferritic stainless steel in the concrete environments. So, here, we present the several corrosion testing methods, such as the potentiodynamic measurements, EIS and Mott–Schottky approach, and the surface analysis methods like XPS and AES to display the passivation behavior of 430 ferritic stainless steel in alkaline solution with the presence of chloride ions. These research results illustrated a simple and facile approach for studying the electrochemical and passivation behavior of stainless steel in the concrete pore environments. PMID:26501086

  2. Tensile behavior of irradiated manganese-stabilized stainless steel

    SciTech Connect

    Klueh, R.L.

    1996-10-01

    Tensile tests were conducted on seven experimental, high-manganese austenitic stainless steels after irradiation up to 44 dpa in the FFTF. An Fe-20Mn-12Cr-0.25C base composition was used, to which various combinations of Ti, W, V, B, and P were added to improve strength. Nominal amounts added were 0.1% Ti, 1% W, 0.1% V, 0.005% B, and 0.03% P. Irradiation was carried out at 420, 520, and 600{degrees}C on the steels in the solution-annealed and 20% cold-worked conditions. Tensile tests were conducted at the irradiation temperature. Results were compared with type 316 SS. Neutron irradiation hardened all of the solution-annealed steels at 420, 520, and 600{degrees}C, as measured by the increase in yield stress and ultimate tensile strength. The steel to which all five elements were added to the base composition showed the least amount of hardening. It also showed a smaller loss of ductility (uniform and total elongation) than the other steels. The total and uniform elongations of this steel after irradiation at 420{degrees}C was over four times that of the other manganese-stabilized steels and 316 SS. There was much less difference in strength and ductility at the two higher irradiation temperatures, where there was considerably less hardening, and thus, less loss of ductility. In the cold-worked condition, hardening occured only after irradiation at 420{degrees}C, and there was much less difference in the properties of the steels after irradiation. At the 420{degrees}C irradiation temperature, most of the manganese-stabilized steels maintained more ductility than the 316 SS. After irradiation at 420{degrees}C, the temperature of maximum hardening, the steel to which all five of the elements were added had the best uniform elongation.

  3. Superplastic Forming of Duplex Stainless Steel for Aerospace Part

    NASA Astrophysics Data System (ADS)

    Lee, Ho-Sung; Yoon, Jong-Hoon; Yoo, Joon-Tae; Yi, Young-Moo

    2011-08-01

    In this study, the high temperature forming behavior of duplex stainless steel has been characterized and the outer shell of a combustion chamber was fabricated with pressure difference of hot gas. It consists of two parts which are the outer skin made of stainless steel to sustain the internal pressure and the inner shell made of copper alloy for regenerative cooling channels. Two outer skins partitioned to half with respect to the symmetric axis was prepared by hot gas forming process with a maximum pressure of 7 MPa following to FEM analysis. For inner layer, copper alloy was machined for cooling channels and then placed in the gas pressure welding fixture. It is shown that the optimum condition of gas pressure welding is 7 MPa at 890 °C, for one hour. EDX analysis and scanning electron microscope micrograph confirm the atomic diffusion process is observed at the interface and copper atoms diffuse into steel, while iron and chrome atoms diffuse into copper. The result shows that the manufacturing method with superplastic forming and gas pressure welding of steel and copper alloy has been successful for near net shape manufacturing of scaled combustion chamber of launch vehicle.

  4. Superplastic Forming of Duplex Stainless Steel for Aerospace Part

    SciTech Connect

    Lee, Ho-Sung; Yoon, Jong-Hoon; Yoo, Joon-Tae; Yi, Young-Moo

    2011-08-22

    In this study, the high temperature forming behavior of duplex stainless steel has been characterized and the outer shell of a combustion chamber was fabricated with pressure difference of hot gas. It consists of two parts which are the outer skin made of stainless steel to sustain the internal pressure and the inner shell made of copper alloy for regenerative cooling channels. Two outer skins partitioned to half with respect to the symmetric axis was prepared by hot gas forming process with a maximum pressure of 7 MPa following to FEM analysis. For inner layer, copper alloy was machined for cooling channels and then placed in the gas pressure welding fixture. It is shown that the optimum condition of gas pressure welding is 7 MPa at 890 deg. C, for one hour. EDX analysis and scanning electron microscope micrograph confirm the atomic diffusion process is observed at the interface and copper atoms diffuse into steel, while iron and chrome atoms diffuse into copper. The result shows that the manufacturing method with superplastic forming and gas pressure welding of steel and copper alloy has been successful for near net shape manufacturing of scaled combustion chamber of launch vehicle.

  5. The interaction between nitride uranium and stainless steel

    NASA Astrophysics Data System (ADS)

    Shornikov, D. P.; Nikitin, S. N.; Tarasov, B. A.; Baranov, V. G.; Yurlova, M. S.

    2016-04-01

    Uranium nitride is most popular nuclear fuel for Fast Breeder Reactor New Generation. In-pile experiments at reactor BOR-60 was shown an interaction between nitride fuel and stainless steel in the range of 8-11% burn up (HA). In order to investigate this interaction has been done diffusion tests of 200 h and has been shown that the reaction occurs in the temperature range 1000-1100 ° C. UN interacted with steel in case of high pollution oxygen (1000-2000 ppm). Also has been shown to increase interaction UN with EP-823 steel in the presence of cesium. In this case the interaction layer had a thickness about 2-3 μm. Has been shown minimal interaction with new ODS steel EP-450. The interaction layer had a thickness less then 2 μm. Did not reveal the influence of tellurium and iodine increased interaction. It was show compatibility at 1000 °C between UN and EP-450 ODS steel, chrome steel, alloying aluminium and silicium.

  6. Pitting and crevice corrosion of stainless steels in ammonium chloride solutions

    SciTech Connect

    Forsen, O.; Aromaa, J.; Virtanen, J.; Tavi, M.

    1995-09-01

    Carbon steel is the most commonly used construction material in oil refining. Ammonium chloride deposition is a well known problem in oil refining. When these deposits form in a moist environment, they are corrosive to carbon steel. When unexpected corrosion problems are faced the material is often changed zn to alloys like stainless steels. The main drawback of stainless steels is that they are prone to different forms of localized corrosion, especially in the presence of halides. In this paper the use of electrochemical measurements to study the corrosion resistance of stainless steels is discussed.

  7. A review on nickel-free nitrogen containing austenitic stainless steels for biomedical applications.

    PubMed

    Talha, Mohd; Behera, C K; Sinha, O P

    2013-10-01

    The field of biomaterials has become a vital area, as these materials can enhance the quality and longevity of human life. Metallic materials are often used as biomaterials to replace structural components of the human body. Stainless steels, cobalt-chromium alloys, commercially pure titanium and its alloys are typical metallic biomaterials that are being used for implant devices. Stainless steels have been widely used as biomaterials because of their very low cost as compared to other metallic materials, good mechanical and corrosion resistant properties and adequate biocompatibility. However, the adverse effects of nickel ions being released into the human body have promoted the development of "nickel-free nitrogen containing austenitic stainless steels" for medical applications. Nitrogen not only replaces nickel for austenitic structure stability but also much improves steel properties. Here we review the harmful effects associated with nickel and emphatically the advantages of nitrogen in stainless steel, as well as the development of nickel-free nitrogen containing stainless steels for medical applications. By combining the benefits of stable austenitic structure, high strength, better corrosion and wear resistance and superior biocompatibility in comparison to the currently used austenitic stainless steel (e.g. 316L), the newly developed nickel-free high nitrogen austenitic stainless steel is a reliable substitute for the conventionally used medical stainless steels.

  8. Sensitization of Laser-beam Welded Martensitic Stainless Steels

    NASA Astrophysics Data System (ADS)

    Dahmen, Martin; Rajendran, Kousika Dhasanur; Lindner, Stefan

    Ferritic and martensitic stainless steels are an attractive alternative in vehicle production due to their inherent corrosion resistance. By the opportunity of press hardening, their strength can be increased to up to 2000 MPa, making them competitors for unalloyed ultra-high strength steels. Welding, nevertheless, requires special care, especially when it comes to joining of high strength heat treated materials. With an adopted in-line heat treatment of the welds in as-rolled as well as press hardened condition, materials with sufficient fatigue strength and acceptable structural behavior can be produced. Because of microstructural transformations in the base material such as grain coarsening and forced carbide precipitation, the corrosion resistance of the weld zone may be locally impaired. Typically the material in the heat-affected zone becomes sensitive to intergranular cracking in the form of knife-edge corrosion besides the fusion line. The current study comprises of two text scenarios. By an alternating climate test, general response in a corroding environment is screened. In order to understand the corrosion mechanisms and to localize the sensitive zones, sensitisation tests were undertaken. Furthermore, the applicability of a standard test according to ASTM 763-83 was examined. It was found that the alternative climate test does not reveal any corrosion effects. Testing by the oxalic acid test revealed clearly the effect of welding, weld heat treatment and state of thermal processing. Also application of the standard which originally suited for testing ferritic stainless steels could have been justified.

  9. Barnacle cement: An etchant for stainless steel 316L?

    PubMed

    Sangeetha, R; Kumar, R; Doble, M; Venkatesan, R

    2010-09-01

    Localized corrosion of stainless steel beneath the barnacle-base is an unsolved issue for the marine industry. In this work, we clearly bring out for the first time the role of the barnacle cement in acting as an etchant, preferentially etching the grain boundaries, and initiating the corrosion process in stainless steel 316L. The investigations include structural characterization of the cement and corroded region, and also chemical characterization of the corrosion products generated beneath the barnacle-base. Structural characterization studies using scanning electron microscopy (SEM) reveals the morphological changes in the cement structure across the interface of the base-plate and the substrate, modification of the steel surface by the cement and the corrosion pattern beneath the barnacle-base. Fourier transform infrared spectroscopy (FTIR) of the corrosion products show that they are composed of mainly oxides of iron thereby implying that the corrosion is aerobic in nature. A model for the etching and corrosion mechanism is proposed based on our observations.

  10. Barnacle cement: an etchant for stainless steel 316L?

    PubMed

    Sangeetha, R; Kumar, R; Doble, M; Venkatesan, R

    2010-09-01

    Localized corrosion of stainless steel beneath the barnacle-base is an unsolved issue for the marine industry. In this work, we clearly bring out for the first time the role of the barnacle cement in acting as an etchant, preferentially etching the grain boundaries, and initiating the corrosion process in stainless steel 316L. The investigations include structural characterization of the cement and corroded region, and also chemical characterization of the corrosion products generated beneath the barnacle-base. Structural characterization studies using scanning electron microscopy (SEM) reveals the morphological changes in the cement structure across the interface of the base-plate and the substrate, modification of the steel surface by the cement and the corrosion pattern beneath the barnacle-base. Fourier transform infrared spectroscopy (FTIR) of the corrosion products show that they are composed of mainly oxides of iron thereby implying that the corrosion is aerobic in nature. A model for the etching and corrosion mechanism is proposed based on our observations.

  11. Moessbauer measurements of microstructural change in aged duplex stainless steel

    SciTech Connect

    Kirihigashi, A.; Sakamoto, N.; Yamaoka, T.; Nasu, S.

    1995-08-01

    A duplex stainless steel (ASME SA351 CF8M) has usually been manufactured by a continuous casting technique. It consists of a paramagnetic austenite phase and a ferromagnetic ferrite phase. It has been known that the ferrite phase decomposition occurs in this steel after aging between 300 and 450 C. As a result of phase decomposition, a Fe-rich phase and a Cr-rich phase are produced in the ferrite phase. It is difficult to detect the phase decomposition even by not only optical microscopy but also transmission electron microscopy, since the decomposed structure is very fine. However, Moessbauer measurements that can detect the magnetic hyperfine field of magnetic substance may detect the microstructural change. An averaged magnetic hyperfine field increases in the ferrite phase, due to the production of the Fe-rich phase which has high magnetic hyperfine field. Therefore, the authors investigated the phase decomposition of the duplex stainless steel caused by aging, utilization Moessbauer spectroscopy which has capability of detecting this structural change in the atomic level quantitatively. The authors also investigated the potential of backscattering Moessbauer method for NDE technique.

  12. Cold Spray Repair of Martensitic Stainless Steel Components

    NASA Astrophysics Data System (ADS)

    Faccoli, M.; Cornacchia, G.; Maestrini, D.; Marconi, G. P.; Roberti, R.

    2014-12-01

    The possibility of using cold spray as repair technique of martensitic stainless steel components was evaluated through laboratory investigations. An austenitic stainless steel feedstock powder was chosen, instead of soft metals powders like nickel, copper, or aluminum, used for repairing components made in light alloy or cast iron. The present study directly compares the microstructure, the residual stresses, and the micro-hardness of repairs obtained by cold spray and by TIG welding, that is commonly used as repair technique in large steel components. XRD and optical metallographic analysis of the repairs showed that cold spray offers some advantages, inducing compressive residual stresses in the repair and avoiding alterations of the interface between repair and base material. For these reasons, a heat treatment after the cold spray repair is not required to restore the base material properties, whereas a post-weld heat treatment is needed after the welding repair. Cold spray repair also exhibits a higher micro-hardness than the welding repair. In addition, the cavitation erosion resistance of a cold spray coating was investigated through ultrasonic cavitation tests, and the samples worn surfaces were observed by scanning electron microscopy.

  13. Electron Microscopy Study of Stainless Steel Radiation Damage Due to Long-Term Irradation by Alpha Particles Emitted From Plutonium

    SciTech Connect

    Unlu, Kenan; Rios-Martinez, Carlos; Saglam, Mehmet; Hart, Ron R.; Shipp, John D.; Rennie, John

    1998-04-16

    Radiation damage and associated surface and microstructural changes produced in stainless steel encapsulation by high-fluence alpha particle irradiations from weapons-grade plutonium of 316-stainless steel are being investigated.

  14. Aging and Embrittlement of High Fluence Stainless Steels

    SciTech Connect

    Was, gary; Jiao, Zhijie; der ven, Anton Van; Bruemmer, Stephen; Edwards, Dan

    2012-12-31

    Irradiation of austenitic stainless steels results in the formation of dislocation loops, stacking fault tetrahedral, Ni-Si clusters and radiation-induced segregation (RIS). Of these features, it is the formation of precipitates which is most likely to impact the mechanical integrity at high dose. Unlike dislocation loops and RIS, precipitates exhibit an incubation period that can extend from 10 to 46 dpa, above which the cluster composition changes and a separate phase, (G-phase) forms. Both neutron and heavy ion irradiation showed that these clusters develop slowly and continue to evolve beyond 100 dpa. Overall, this work shows that the irradiated microstructure features produced by heavy ion irradiation are remarkably comparable in nature to those produced by neutron irradiation at much lower dose rates. The use of a temperature shift to account for the higher damage rate in heavy ion irradiation results in a fairly good match in the dislocation loop microstructure and the precipitate microstructure in austenitic stainless steels. Both irradiations also show segregation of the same elements and in the same directions, but to achieve comparable magnitudes, heavy ion irradiation must be conducted at a much higher temperature than that which produces a match with loops and precipitates. First-principles modeling has confirmed that the formation of Ni-Si precipitates under irradiation is likely caused by supersaturation of solute to defect sinks caused by highly correlated diffusion of Ni and Si. Thus, the formation and evolution of Ni-Si precipitates at high dose in austenitic stainless steels containing Si is inevitable.

  15. Osteogenic ability of Cu-bearing stainless steel.

    PubMed

    Ren, Ling; Wong, Hoi Man; Yan, Chun Hoi; Yeung, Kelvin W K; Yang, Ke

    2015-10-01

    A newly developed copper-bearing stainless steel (Cu-SS) by directly immobilizing proper amount of Cu into a medical stainless steel (317L SS) during the metallurgical process could enable continuous release of trace amount of Cu(2+) ions, which play the key role to offer the multi-biofunctions of the stainless steel, including the osteogenic ability in the present study. The results of in vitro experiments clearly demonstrated that Cu(2+) ions from Cu-SS could promote the osteogenic differentiation by stimulating the Alkaline phosphatase enzyme activity and the osteogenic gene expressions (Col1a1, Opn, and Runx2), and enhancing the adhesion and proliferation of osteoblasts cultured on its surface. The in vivo test further proved that more new bone tissue formed around the Cu-SS implant with more stable bone-to-implant contact in comparison with the 317L SS. In addition, Cu-SS showed satisfied biocompatibility according to the results of in vitro cytotoxicity and in vivo histocompatibility, and its daily released amount of Cu(2+) ions in physiological saline solution was at trace level of ppb order (1.4 ppb/cm(2) ), which is rather safe to human health. Apart from these results, it was also found that Cu-SS could inhibit the happening of inflammation with lower TNF-α expression in the bone tissue post implantation compared with 317L SS. In addition to good biocompatibility, the overall findings demonstrated that the Cu-SS possessed obvious ability of promoting osteogenesis, indicating a unique application advantage in orthopedics.

  16. Thermal Aging Phenomena in Cast Duplex Stainless Steels

    DOE PAGES

    Byun, T. S.; Yang, Y.; Overman, N. R.; ...

    2015-11-12

    We used cast stainless steels (CASSs)for the large components of light water reactor (LWR) power plants such as primary coolant piping and pump casing. The thermal embrittlement of CASS components is one of the most serious concerns related to the extended-term operation of nuclear power plants. Many past researches have concluded that the formation of Cr-rich alpha-phase by Spinodal decomposition of delta-ferrite phase is the primary mechanism for the thermal embrittlement. Cracking mechanism in the thermally-embrittled duplex stainless steels consists of the formation of cleavage at ferrite and its propagation via separation of ferrite-austenite interphase. This article intends to providemore » an introductory overview on the thermal aging phenomena in LWR-relevant conditions. Firstly, the thermal aging effect on toughness is discussed in terms of the cause of embrittlement and influential parameters. Moreover, an approximate analysis of thermal reaction using Arrhenius equation was carried out to scope the aging temperatures for the accelerated aging experiments to simulate the 60 and 80 years of services. Further, an equilibrium precipitation calculation was performed for model CASS alloys using the CALPHAD program, and the results are used to describe the precipitation behaviors in duplex stainless steels. Our results are also to be used to guide an on-going research aiming to provide knowledge-based conclusive prediction for the integrity of the CASS components of LWR power plants during the service life extended up to and beyond 60 years.« less

  17. Microanalytical evaluation of a prototype stainless bearing steel

    NASA Astrophysics Data System (ADS)

    Kinkus, T. J.; Olson, G. B.

    1992-04-01

    A novel bearing steel composition intended for a space shuttle main engine turbopump application has been designed by computer-aided thermodynamic modelling. Property objectives for the martensitic stainless steel are a doubling of KIC toughness and KISCC stress-corrosion resistance relative to existing bearing steels. The composition is designed to achieve sufficient refinement of M 2C carbides to provide the required hardness of RC = 60 at 0.30C, and to achieve a high stability austenite dispersion for transformation toughening. Microanalytical study of the prototype steel of composition Fe-22.5Co-12Cr-8.5Ni- 0.3Mo-0.25V-0.30C has tested key model predictions. STEM microanalysis of extracted Cr and CrMo carbides was used to evaluate solution treatment response between 1100 and 1150°C. Atom-probe microanalysis was employed to measure compositions of fine M 2C carbides in cryogenically-formed martensitic material tempered at 500°C to a slightly c raged condition promoting high toughness. The observed composition of (Cr 0.88Mo 0.03V 0.03Fe 0.06) 2 C 0.92 lies between computed values corresponding to coherent and incoherent equilibrium. The prototype steel exceeds the design toughness objectives, giving a KIC toughness of 47 MPa √ m at RC = 60.4 hardness.

  18. 77 FR 18861 - Stainless Steel Bar From Brazil, India, Japan, and Spain; Scheduling of Expedited Five-Year Reviews

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-03-28

    ... COMMISSION Stainless Steel Bar From Brazil, India, Japan, and Spain; Scheduling of Expedited Five-Year... orders on stainless steel bar from Brazil, India, Japan, and Spain would be likely to lead to... Inc. Co., Universal Stainless & Alloy Products, Inc., and Valbruna Slater Stainless, Inc. to...

  19. General and Localized Corrosion of Borated Stainless Steels

    SciTech Connect

    T.E. Lister; Ronald E. Mizia; A.W. Erickson; T.L. Trowbridge; B. S. Matteson

    2008-03-01

    The Transportation, Aging and Disposal (TAD) canister-based system is being proposed to transport and store spent nuclear fuel at the Monitored Geologic Repository (MGR) located at Yucca Mountain, Nevada. The preliminary design of this system identifies borated stainless steel as the neutron absorber material that will be used to fabricate fuel basket inserts for nuclear criticality control. This paper discusses corrosion test results for verifying the performance of this material manufactured to the requirements of ASTM A887, Grade A, under the expected repository conditions.

  20. Shrinkage Prediction for the Investment Casting of Stainless Steels

    SciTech Connect

    Sabau, Adrian S

    2007-01-01

    In this study, the alloy shrinkage factors were obtained for the investment casting of 17-4PH stainless steel parts. For the investment casting process, unfilled wax and fused silica with a zircon prime coat were used for patterns and shell molds, respectively. Dimensions of the die tooling, wax pattern, and casting were measured using a Coordinate Measurement Machine in order to obtain the actual tooling allowances. The alloy dimensions were obtained from numerical simulation results of solidification, heat transfer, and deformation phenomena. The numerical simulation results for the shrinkage factors were compared with experimental results.

  1. Carbon, nitrogen, and oxygen ion implantation of stainless steel

    SciTech Connect

    Rej, D.J.; Gavrilov, N.V.; Emlin, D.

    1995-12-31

    Ion implantation experiments of C, N, and O into stainless steel have been performed, with beam-line and plasma source ion implantation methods. Acceleration voltages were varied between 27 and 50 kV, with pulsed ion current densities between 1 and 10 mA/cm{sup 2}. Implanted doses ranged from 0.5 to 3 {times} 10{sup 18}cm{sup -2}, while workpiece temperatures were maintained between 25 and 800 C. Implant concentration profiles, microstructure, and surface mechanical properties of the implanted materials are reported.

  2. AM363 martensitic stainless steel: A multiphase equation of state

    NASA Astrophysics Data System (ADS)

    De Lorenzi-Venneri, Giulia; Crockett, Scott D.

    2017-01-01

    A multiphase equation of state for stainless steel AM363 has been developed within the Opensesame approach and has been entered as material 4295 in the LANL-SESAME Library. Three phases were constructed separately: the low pressure martensitic phase, the austenitic phase and the liquid. Room temperature data and the explicit introduction of a magnetic contribution to the free energy determined the martensitic phase, while shock Hugoniot data was used to determine the austenitic phase and the phase boundaries. More experimental data or First Principles calculations would be useful to better characterize the liquid.

  3. Electroformation of Giant Unilamellar Vesicles on Stainless Steel Electrodes

    PubMed Central

    2017-01-01

    Giant unilamellar vesicles (GUVs) are well-established model systems for studying membrane structure and dynamics. Electroformation, also referred to as electroswelling, is one of the most prevalent methods for producing GUVs, as it enables modulation of the lipid hydration process to form relatively monodisperse, defect-free vesicles. Currently, however, it is expensive and time-consuming compared with other methods. In this study, we demonstrate that 1,2-dioleoyl-sn-glycero-3-phosphatidylcholine GUVs can be prepared readily at a fraction of the cost on stainless steel electrodes, such as commercially available syringe needles, without any evidence of lipid oxidation or hydrolysis. PMID:28393132

  4. Apparatus and process for ultrasonic seam welding stainless steel foils

    DOEpatents

    Leigh, Richard W.

    1992-01-01

    An ultrasonic seam welding apparatus having a head which is rotated to form contact, preferably rolling contact, between a metallurgically inert coated surface of the head and an outside foil of a plurality of layered foils or work materials. The head is vibrated at an ultrasonic frequency, preferably along a longitudinal axis of the head. The head is constructed to transmit vibration through a contacting surface of the head into each of the layered foils. The contacting surface of the head is preferably coated with aluminum oxide to prevent the head from becoming welded to layered stainless steel foils.

  5. Oxidation resistant high creep strength austenitic stainless steel

    DOEpatents

    Brady, Michael P.; Pint, Bruce A.; Liu, Chain-Tsuan; Maziasz, Philip J.; Yamamoto, Yukinori; Lu, Zhao P.

    2010-06-29

    An austenitic stainless steel displaying high temperature oxidation and creep resistance has a composition that includes in weight percent 15 to 21 Ni, 10 to 15 Cr, 2 to 3.5 Al, 0.1 to 1 Nb, and 0.05 to 0.15 C, and that is free of or has very low levels of N, Ti and V. The alloy forms an external continuous alumina protective scale to provide a high oxidation resistance at temperatures of 700 to 800.degree. C. and forms NbC nanocarbides and a stable essentially single phase fcc austenitic matrix microstructure to give high strength and high creep resistance at these temperatures.

  6. Portable probe to measure sensitization of stainless steel

    DOEpatents

    Park, Jang Y.

    1979-01-01

    An electrochemical cell for making field measurements of metals such as stainless steel comprises a cylinder containing a reservoir of an electrolyte, a reference electrode, a capillary tube connecting the electrolyte to the surface of the metal to be measured and another electrode in electrical contact with the electrolyte. External connections from the reference electrode, the other electrode, and the sample to a measuring device provide means for maintaining the potential of the electrolyte while sweeping the potential difference between the electrolyte and the metal. Such a sweep enables the determination of a current-voltage characteristic that is a measure of sensitization in the metal.

  7. Evaluation of tantalum 316 stainless steel transition joints

    NASA Technical Reports Server (NTRS)

    Stoner, D. R.

    1972-01-01

    Tubular transition joints providing a metallurgically bonded connection between tantalum and 316 stainless steel pipe sections were comparatively evaluated for durability under thermal cycling conditions approximating the operation of a SNAP-8 mercury boiler. Both coextruded and vacuum brazed transition joints of 50mm (2 inch) diameter were tested by thermal cycling 100 times between 730 C and 120 C(1350 F and 250 F) in a high vacuum environment. The twelve evaluated transition joints survived the full test sequence without developing leaks, although liquid penetrant bond line indications eventually developed in all specimens. The brazed transition joints exhibited the best dimensional stability and bond line durability.

  8. An advanced cavitation resistant austenitic stainless steel for pumps

    SciTech Connect

    McCaul, C.

    1996-10-01

    Cavitation damage is a chronic problem leading to impaired pump performance, and eventual failure in a wide range of industrial applications. Pump manufacturers recognize that cavitation damage can be minimized by utilizing advanced hydraulic designs and employing new state-of-the-art materials. The materials solution is particularly attractive because it does not involve detailed engineering studies, new pattern equipment, or long lead times. This paper traces the development, over the past decade, of a new class of cavitation resistant stainless steels. The properties and engineering characteristics of these alloys are described, and several initial field applications are discussed.

  9. Use of duplex stainless steel castings in control valves

    SciTech Connect

    Gossett, J.L.

    1996-07-01

    Duplex stainless steels have enjoyed rapidly increasing popularity in recent years. For numerous reasons the availability of these alloys in the cast form has lagged behind the availability of the wrought form. Commercial demand for control valves in these alloys has driven development of needed information to move into production. A systematic approach was used to develop specifications, suppliers and weld procedures. Corrosion, stress corrosion cracking (SCC), sulfide stress cracking (SSC) and hardness results are also presented for several alloys including; CD3MN (UNS J92205), CD4MCu (UNS J93370) and CD7MCuN (cast UNS S32550).

  10. Modeling of Linear Gas Tungsten Arc Welding of Stainless Steel

    NASA Astrophysics Data System (ADS)

    Maran, P.; Sornakumar, T.; Sundararajan, T.

    2008-08-01

    A heat and fluid flow model has been developed to solve the gas tungsten arc (GTA) linear welding problem for austenitic stainless steel. The moving heat source problem associated with the electrode traverse has been simplified into an equivalent two-dimensional (2-D) transient problem. The torch residence time has been calculated from the arc diameter and torch speed. The mathematical formulation considers buoyancy, electromagnetic induction, and surface tension forces. The governing equations have been solved by the finite volume method. The temperature and velocity fields have been determined. The theoretical predictions for weld bead geometry are in good agreement with experimental measurements.

  11. Mechanical Property Data 15-5PH (H1025) Stainless Steel Alloy: Hot-Rolled Plate.

    DTIC Science & Technology

    1984-05-01

    fatigue data of unnotched 15 - 5PH stainless steel (H1025, longitudinal). - ~ ~ 5 l5PH Stumhuts Sisa Pmae. Csinuutae M al 110 -- R*01,Kf-3.0 R.T. 100 1.00...40 - 00 Lsishii. of. cruam Figure 2. Axial load fatigue data of notched 15 -SPH stainless steel (H1025, longitudinal). 3 I 20 15 - 5PH Stainless Stee...600 020 ; I I a -ALI AT 4W4C002 100 TO0 6W 30O 0 4 -5 0 07 Ufetime, Nw Cycles Figure 4. Axial load fatigue data of notched 15 - 5PH stainless steel

  12. Novel Approach for Welding Stainless Steel Using Cr-Free Welding Consumables

    DTIC Science & Technology

    2004-12-31

    compared to type 304L stainless steel. Keywords: Welding , Corrosion , Stainless steel, Nickel, Copper, Palladium , Molybdenum, Dilution... Corrosion Center, Dept. of Materials Science and Engineering **Dept. of Industrial, Welding and Systems Engineering The Ohio State University...PERFORMING ORGANIZATION NAME(S) AND ADDRESS(ES) *Fontana Corrosion Center, Dept. of Materials Science and Engineering **Dept. of Industrial, Welding and

  13. Corrosion characteristics of ferric and austenitic stainless steels for dental magnetic attachment.

    PubMed

    Endo, K; Suzuki, M; Ohno, H

    2000-03-01

    The corrosion behaviors of four ferric stainless steels and two austenitic stainless steels were examined in a simulated physiological environment (0.9% NaCl solution) to obtain basic data for evaluating the appropriate composition of stainless steels for dental magnetic attachments. The corrosion resistance was evaluated by electrochemical techniques and the analysis of released metal ions by atomic absorption spectrophotometry. The surface of the stainless steels was analyzed by X-ray photoelectron spectroscopy (XPS). The breakdown potential of ferric stainless steels increased and the total amount of released metal ions decreased linearly with increases in the sum of the Cr and Mo contents. The corrosion rate of the ferric stainless steels increased 2 to 6 times when they were galvanically coupled with noble metal alloys but decreased when coupled with commercially pure Ti. For austenitic stainless steels, the breakdown potential of high N-bearing stainless steel was approximately 500 mV higher than that of SUS316L, which is currently used as a component in dental magnetic attachments. The enriched nitrogen at the alloy/passive film interface may be effective in improving the localized corrosion resistance.

  14. Stablization of Nanotwinned Microstructures in Stainless Steels Through Alloying and Microstructural Design

    DTIC Science & Technology

    2013-08-23

    stable nanotwinned microstructure---high-temperature strength. The long - term goal of this effort is to develop austenitic stainless steels capable of...microstructures. The long - term alloy design strategy focuses on microalloying additions to 1) reduce the stacking fault energy (SFE), enhance twinning formation...15. SUBJECT TERMS materials design, stainless steels , plastic deformation by twinning, computational materials science, experimental characterization

  15. 75 FR 76025 - Stainless Steel Butt-Weld Pipe Fittings From Japan, Korea, and Taiwan

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-12-07

    ... From the Federal Register Online via the Government Publishing Office INTERNATIONAL TRADE COMMISSION Stainless Steel Butt-Weld Pipe Fittings From Japan, Korea, and Taiwan AGENCY: United States... stainless steel butt-weld pipe fittings from Japan, Korea, and Taiwan would be likely to lead...

  16. Assessment of bacterial biofilm on stainless steel by hyperspectral fluorescence imaging

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Hyperspectral fluorescence imaging techniques were investigated for detection of two genera of microbial biofilms on stainless steel material which is commonly used to manufacture food processing equipment. Stainless steel coupons were deposited in nonpathogenic E. coli O157:H7 and Salmonella cultu...

  17. 78 FR 63517 - Control of Ferrite Content in Stainless Steel Weld Metal

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-10-24

    ... Information The NRC published DG-1279 in the Federal Register on October 3, 2012 (77 FR 60479), for a 60-day... COMMISSION Control of Ferrite Content in Stainless Steel Weld Metal AGENCY: Nuclear Regulatory Commission... revision to Regulatory Guide (RG) 1.31, ``Control of Ferrite Content in Stainless Steel Weld Metal.''...

  18. Precipitation sequence in niobium-alloyed ferritic stainless steel

    NASA Astrophysics Data System (ADS)

    Fujita, Nobuhiro; Bhadeshia, H. K. D. H.; Kikuchi, Masao

    2004-03-01

    Niobium is an important alloying element in the design of heat-resistant ferritic stainless steels for automotive exhaust systems. When in solid solution, it improves both the high temperature strength and the resistance to thermal fatigue. However, it also forms several kinds of precipitates during service. These reactions have been modelled, taking into account the multicomponent nature of the diffusion process and allowing for capillarity effects. It has been possible to estimate not only the volume fractions but also the particle sizes for Fe2Nb (Laves phase) and Fe3Nb3C (M6C) carbide in a 19Cr-0.8Nb steel, with good agreement against experimental data.

  19. Beneficially reusing LLRW the Savannah River Site Stainless Steel Program

    SciTech Connect

    Boettinger, W.L.

    1993-09-09

    With 68 radioactively contaminated excess Process Water Heat Exchangers the Savannah River Site launched its program to turn potential LLRW metal liabilities into assets. Each Heat Exchanger contains approximately 100 tons of 304 Stainless Steel and could be disposed as LLRW by land burial. Instead the 7000 tons of metal will be recycled into LLRW, HLW, and TRU waste containers thereby eliminating the need for near term land disposal and also eliminating the need to add more clean metal to the waste stream. Aspects of the partnership between DOE and Private Industry necessary to accomplish this new mission are described. A life cycle cost analysis associated with past practices of using carbon steel containers to indefinitely store material (contributing to the creation of today`s legacy waste problems) is presented. The avoided cost calculations needed to support the economics of the ``Indifference`` decision process in assessing the Beneficial Reuse option relative to the Burial option are described.

  20. Stress corrosion cracking of duplex stainless steels in caustic solutions

    NASA Astrophysics Data System (ADS)

    Bhattacharya, Ananya

    Duplex stainless steels (DSS) with roughly equal amount of austenite and ferrite phases are being used in industries such as petrochemical, nuclear, pulp and paper mills, de-salination plants, marine environments, and others. However, many DSS grades have been reported to undergo corrosion and stress corrosion cracking in some aggressive environments such as chlorides and sulfide-containing caustic solutions. Although stress corrosion cracking of duplex stainless steels in chloride solution has been investigated and well documented in the literature but the SCC mechanisms for DSS in caustic solutions were not known. Microstructural changes during fabrication processes affect the overall SCC susceptibility of these steels in caustic solutions. Other environmental factors, like pH of the solution, temperature, and resulting electrochemical potential also influence the SCC susceptibility of duplex stainless steels. In this study, the role of material and environmental parameters on corrosion and stress corrosion cracking of duplex stainless steels in caustic solutions were investigated. Changes in the DSS microstructure by different annealing and aging treatments were characterized in terms of changes in the ratio of austenite and ferrite phases, phase morphology and intermetallic precipitation using optical micrography, SEM, EDS, XRD, nano-indentation and microhardness methods. These samples were then tested for general and localized corrosion susceptibility and SCC to understand the underlying mechanisms of crack initiation and propagation in DSS in the above-mentioned environments. Results showed that the austenite phase in the DSS is more susceptible to crack initiation and propagation in caustic solutions, which is different from that in the low pH chloride environment where the ferrite phase is the more susceptible phase. This study also showed that microstructural changes in duplex stainless steels due to different heat treatments could affect their SCC

  1. Type 304L stainless steel surface microstructure: Performance in hydride storage and acid cleaning

    SciTech Connect

    Clark, E.A.

    1994-07-01

    The performance of stainless steel as the container in hydride storage bed systems has been evaluated, primarily using scanning electron microscopy. No adverse reaction between Type 304L stainless steel and either LaNi{sub 5{minus}x},Al{sub x}, or palladium supported on Kieselguhr granules (silica) during exposure in hydrogen was found in examination of retired prototype storage bed containers and special compatibility test samples. Intergranular surface ditching, observed on many of the stainless steel surfaces examined, was shown to result from air annealing and acid cleaning of stainless steel during normal fabrication. The ditched air annealed and acid cleaned stainless steel samples were more resistant to subsequent acid attack than vacuum annealed or polished samples without ditches.

  2. Biocompatibility of 17-4 PH stainless steel foam for implant applications.

    PubMed

    Mutlu, Ilven; Oktay, Enver

    2011-01-01

    In this study, biocompatibility of 17-4 PH stainless steel foam for biomedical implant applications was investigated. 17-4 PH stainless steel foams having porosities in the range of 40-82% with an average pore size of around 600 μm were produced by space holder-sintering technique. Sintered foams were precipitation hardened for times of 1-6 h at temperatures between 450-570 °C. Compressive yield strength and Young's modulus of aged stainless steel foams were observed to vary between 80-130 MPa and 0.73-1.54 GPa, respectively. Pore morphology, pore size and the mechanical properties of the 17-4 PH stainless steel foams were close to cancellous bone. In vitro evaluations of cytotoxicity of the foams were investigated by XTT and MTT assays and showed sufficient biocompatibility. Surface roughness parameters of the stainless steel foams were also determined to characterize the foams.

  3. 75 FR 45605 - Stainless Steel Plate in Coils From Belgium: Correction to Notice of Final Results of Antidumping...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-08-03

    ... International Trade Administration Stainless Steel Plate in Coils From Belgium: Correction to Notice of Final... following notice: Stainless Steel Plate in Coils From Belgium: Final Results of Antidumping Duty... administrative review for all shipments of stainless steel plate in coils (``SSPC'') from Belgium entered,...

  4. 75 FR 17378 - Stainless Steel Sheet and Strip in Coils from Taiwan: Notice of Extension of Time Limits for...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-04-06

    ... International Trade Administration Stainless Steel Sheet and Strip in Coils from Taiwan: Notice of Extension of... administrative review of the antidumping duty order on stainless steel sheet and strip in coils from Taiwan. See... stainless steel sheet and strip in coils from Taiwan for the POR with respect to 23 companies....

  5. 77 FR 38271 - Stainless Steel Bar From Japan: Final Results of Antidumping Duty Changed-Circumstances Review...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-06-27

    ... International Trade Administration Stainless Steel Bar From Japan: Final Results of Antidumping Duty Changed... changed-circumstances review with intent to revoke in part the order on stainless steel bar (SSBar) from... February 1, 2010. \\1\\ See Stainless Steel Bar From Japan: Initiation and Preliminary Results of...

  6. 76 FR 78614 - Welded ASTM A-312 Stainless Steel Pipe From South Korea and Taiwan: Continuation of Antidumping...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-12-19

    ... International Trade Administration Welded ASTM A-312 Stainless Steel Pipe From South Korea and Taiwan... welded ASTM A-312 stainless steel pipe from South Korea (Korea) and Taiwan would likely lead to... published the antidumping duty orders on welded ASTM A-312 stainless steel pipe from Korea and Taiwan.\\1\\...

  7. 76 FR 64106 - Certain Welded Stainless Steel Pipe From Korea and Taiwan; Scheduling of Expedited Five-Year...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-10-17

    ... COMMISSION Certain Welded Stainless Steel Pipe From Korea and Taiwan; Scheduling of Expedited Five-Year Reviews Concerning the Antidumping Duty Orders on Certain Welded Stainless Steel Pipe From Korea and... duty orders on certain welded stainless steel pipe (specifically ASTM A-312 pipe) from Korea and...

  8. 76 FR 66271 - Stainless Steel Plate in Coils From Belgium: Notice of Preliminary Results of Antidumping Duty...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-10-26

    ... International Trade Administration Stainless Steel Plate in Coils From Belgium: Notice of Preliminary Results of... circumstances review (``CCR'') of the antidumping duty order of stainless steel plate in coils (``SSPC'') from... the argument. \\1\\ See Stainless Steel Plate in Coils From Belgium: Notice of Initiation of...

  9. 78 FR 22227 - Stainless Steel Bar From Brazil: Final Results of Antidumping Duty Administrative Review; 2011-2012

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-04-15

    ... International Trade Administration Stainless Steel Bar From Brazil: Final Results of Antidumping Duty... preliminary results of the administrative review of the antidumping duty order on stainless steel bar (SSB..., through January 31, 2012. \\1\\ See Stainless Steel Bar From Brazil: Preliminary Results of Antidumping...

  10. 75 FR 4044 - Stainless Steel Bar From Brazil: Extension of Time Limit for Preliminary Results of Antidumping...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-01-26

    ... International Trade Administration Stainless Steel Bar From Brazil: Extension of Time Limit for Preliminary...) initiated an administrative review of the antidumping duty order on certain stainless steel bar from Brazil... until January 29, 2010. See Stainless Steel Bar From Brazil: Extension of Time Limit for...

  11. 75 FR 62103 - Stainless Steel Plate in Coils From South Africa: Final Results of Expedited Sunset Review

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-10-07

    ... International Trade Administration Stainless Steel Plate in Coils From South Africa: Final Results of Expedited... review of the countervailing duty order (``CVD'') on stainless steel plate in coils from South Africa... review of the CVD order on stainless steel plate in coils from South Africa pursuant to section 751(c)...

  12. 75 FR 76700 - Stainless Steel Sheet and Strip in Coils From Taiwan: Final Results of Antidumping Duty...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-12-09

    ... International Trade Administration Stainless Steel Sheet and Strip in Coils From Taiwan: Final Results of... preliminary results of the administrative review of the antidumping duty order on stainless steel sheet and... administrative review of the antidumping duty order on SSSSC from Taiwan. See Stainless Steel Sheet and Strip...

  13. 75 FR 6627 - Stainless Steel Sheet and Strip in Coils From Mexico; Final Results of Antidumping Duty...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-02-10

    ... International Trade Administration Stainless Steel Sheet and Strip in Coils From Mexico; Final Results of... preliminary ] results of the administrative review of the antidumping duty order on stainless steel sheet and strip (S4) in coils from Mexico. See Stainless Steel Sheet and Strip in Coils From Mexico;...

  14. 76 FR 67672 - Certain Stainless Steel Wire Rods From India: Final Results of the Expedited Sunset Review of the...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-11-02

    ... International Trade Administration Certain Stainless Steel Wire Rods From India: Final Results of the Expedited...) initiated the third sunset review of the antidumping duty order on certain stainless steel wire rods from... notice of initiation of the sunset review of the antidumping duty order on certain stainless steel...

  15. 77 FR 47595 - Stainless Steel Bar From Brazil, India, Japan, and Spain: Continuation of Antidumping Duty Orders

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-08-09

    ... International Trade Administration Stainless Steel Bar From Brazil, India, Japan, and Spain: Continuation of... stainless steel bar from Brazil, India, Japan, and Spain pursuant to section 751(c) of the Tariff Act of..., 2011). \\1\\ Antidumping Duty Orders: Stainless Steel Bar from Brazil, India and Japan, 60 FR...

  16. 75 FR 27987 - Certain Welded Stainless Steel Pipes From the Republic of Korea: Final Results of Antidumping...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-05-19

    ... International Trade Administration Certain Welded Stainless Steel Pipes From the Republic of Korea: Final... welded stainless steel pipes (WSSP) from the Republic of Korea (Korea). This review covers one producer... antidumping duty order on WSSP from Korea. See Certain Welded Stainless Steel Pipes from the Republic of...

  17. 76 FR 74807 - Stainless Steel Bar From Brazil, India, Japan, and Spain; Institution of Five-Year Reviews

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-12-01

    ... COMMISSION Stainless Steel Bar From Brazil, India, Japan, and Spain; Institution of Five-Year Reviews AGENCY...)) (the Act) to determine whether revocation of the antidumping duty orders on stainless steel bar from... Department of Commerce issued antidumping duty orders on imports of stainless steel bar from Brazil,...

  18. 75 FR 62101 - Stainless Steel Sheet and Strip in Coils From the Republic of Korea: Final Results of Expedited...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-10-07

    ... International Trade Administration Stainless Steel Sheet and Strip in Coils From the Republic of Korea: Final...'') initiated the second sunset review of the countervailing duty order (``CVD'') on stainless steel sheet and... domestic producers of stainless steel sheet and strip in coils in the United States and certified...

  19. 77 FR 22561 - Drawn Stainless Steel Sinks From the People's Republic of China: Correction to Notice of...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-04-16

    ... International Trade Administration Drawn Stainless Steel Sinks From the People's Republic of China: Correction..., the Department of Commerce (``Department'') published the notice Drawn Stainless Steel Sinks from the... countervailing duty (``CVD'') petition concerning imports of drawn stainless steel sinks from the...

  20. 76 FR 38686 - Stainless Steel Wire Rod From India; Institution of a Five-Year Review Concerning the Antidumping...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-07-01

    ... COMMISSION Stainless Steel Wire Rod From India; Institution of a Five-Year Review Concerning the Antidumping Duty Order on Stainless Steel Wire Rod From India AGENCY: United States International Trade Commission... the antidumping duty order on stainless steel wire rod from India would be likely to lead...

  1. 77 FR 18207 - Drawn Stainless Steel Sinks From the People's Republic of China: Initiation of Antidumping Duty...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-03-27

    ... International Trade Administration Drawn Stainless Steel Sinks From the People's Republic of China: Initiation...'') concerning imports of drawn stainless steel sinks from the People's Republic of China (``PRC'') filed in... Countervailing Duties Against Drawn Stainless Steel Sinks From The People's Republic of China,'' filed on March...

  2. 78 FR 34337 - Stainless Steel Bar From India: Final Results of Antidumping Duty Administrative Review; 2011-2012

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-06-07

    ... International Trade Administration Stainless Steel Bar From India: Final Results of Antidumping Duty... results of the administrative review of the antidumping duty order on stainless steel bar from India... that Ambica has not sold subject merchandise at less than normal value. \\1\\ See Stainless Steel...

  3. 78 FR 14270 - Stainless Steel Sheet and Strip in Coils From Mexico: Notice of Settlement of NAFTA Proceedings

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-03-05

    ... International Trade Administration Stainless Steel Sheet and Strip in Coils From Mexico: Notice of Settlement of... July 27, 1999, the Department published the antidumping duty order on stainless steel sheet and strip in coils from Mexico (SSSS from Mexico). See Stainless Steel Sheet and Strip in Coils from Mexico,...

  4. 76 FR 2332 - Stainless Steel Sheet and Strip in Coils From Mexico; Final Results of Antidumping Duty...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-01-13

    ... International Trade Administration Stainless Steel Sheet and Strip in Coils From Mexico; Final Results of... preliminary results of the administrative review of the antidumping duty order on stainless steel sheet and strip (S4) in coils from Mexico. See Stainless Steel Sheet and Strip in Coils From Mexico;...

  5. 78 FR 72864 - Drawn Stainless Steel Sinks From the People's Republic of China: Initiation of New Shipper Review

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-12-04

    ... International Trade Administration Drawn Stainless Steel Sinks From the People's Republic of China: Initiation... stainless steel sinks (``drawn sinks'') from the People's Republic of China (``PRC''), received on October...\\ Success identified itself as an exporter of the subject merchandise. \\1\\ See Drawn Stainless Steel...

  6. 76 FR 64105 - Stainless Steel Wire Rod From India; Scheduling of an Expedited Five-Year Review Concerning the...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-10-17

    ... COMMISSION Stainless Steel Wire Rod From India; Scheduling of an Expedited Five-Year Review Concerning the Antidumping Duty Order on Stainless Steel Wire Rod From India AGENCY: United States International Trade... determine whether revocation of the antidumping duty order on stainless steel wire rod from India would...

  7. 76 FR 45511 - Stainless Steel Plate in Coils From Belgium: Notice of Initiation of Antidumping Duty Changed...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-07-29

    ... International Trade Administration Stainless Steel Plate in Coils From Belgium: Notice of Initiation of...'') is initiating a changed circumstances review of the antidumping duty order on stainless steel plate... the Federal Register an antidumping duty order on stainless steel plate in coils from Belgium;...

  8. 77 FR 42697 - Stainless Steel Butt-Weld Pipe Fittings From Italy, Malaysia, and the Philippines: Continuation...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-07-20

    ...), whether finished or unfinished. The product encompasses all grades of stainless steel and ``commodity... specification for Wrought Austenitic Stainless Steel Piping Fittings, or its foreign equivalents (e.g., DIN or... International Trade Administration Stainless Steel Butt-Weld Pipe Fittings From Italy, Malaysia, and...

  9. 77 FR 24459 - Stainless Steel Butt-Weld Pipe Fittings From Italy: Final Results of Antidumping Duty...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-04-24

    ... grades of stainless steel and ``commodity'' and ``specialty'' fittings. Specifically excluded from the... International Trade Administration Stainless Steel Butt-Weld Pipe Fittings From Italy: Final Results of... stainless steel butt-weld pipe fittings (SSBW pipe fittings) from Italy.\\1\\ This review covers...

  10. 77 FR 14002 - Stainless Steel Butt-Weld Pipe Fittings From Italy, Malaysia, and the Philippines: Final Results...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-03-08

    ... unfinished. The product encompasses all grades of stainless steel and ``commodity'' and ``specialty... Austenitic Stainless Steel Piping Fittings, or its foreign equivalents (e.g., DIN or JIS specifications... International Trade Administration Stainless Steel Butt-Weld Pipe Fittings From Italy, Malaysia, and...

  11. The retention of iodine in stainless steel sample lines

    SciTech Connect

    Evans, G.J.; Deir, C.; Ball, J.M.

    1995-02-01

    Following an accident in a multi-unit CANDU nuclear generating station, decontamination of air vented from containment would play a critical role in minimizing the release of iodine to the environment. The concentration of gas phase iodine in containment air would be measured using the post accident radiation monitoring system, requiring that air samples be passed through a considerable length of tubing to a remote location where the desired measurements could safely be made. A significant loss of iodine, due to adsorption on the sample line surfaces, could greatly distort the measurement. In this study, the retention of I{sub 2}(g) on stainless steel was evaluated in bench scale experiments in order to evaluate, and if possible minimise, the extent of any such line losses. Experiments at the University of Toronto were performed using 6 inch lengths of 1/4 inch stainless steel tubing. Air, containing I-131 labelled I{sub 2}(g), ranging in concentration from 10{sup {minus}10} to 10{sup {minus}6} mol/dm{sup 3} and relative humidity (:RH) from 20 to 90 %, was passed through tubing samples maintained at temperatures ranging from 25 to 90{degrees}C. Adsorption at low gas phase iodine concentrations differed substantially from that at higher concentrations. The rate of deposition was proportional to the gas phase concentration, giving support to the concept of a first order deposition velocity. The surface loading increased with increasing relative humidity, particularly at low RH values, while the deposition rate decreased with increasing temperature. Surface water on the steel may play an important role in the deposition process. The chemisorbed iodine was located primarily in areas of corrosion. Furthermore, water used to wash the steel contained Fe, Mn and iodine in the form of iodide, suggesting that I{sub 2} reacted to form metal iodides. The deposition of I{sub 2} was also found to depend on the initial surface condition.

  12. Study on tempering behaviour of AISI 410 stainless steel

    SciTech Connect

    Chakraborty, Gopa; Das, C.R.; Albert, S.K.; Bhaduri, A.K.; Thomas Paul, V.; Panneerselvam, G.; Dasgupta, Arup

    2015-02-15

    Martensitic stainless steels find extensive applications due to their optimum combination of strength, hardness and wear-resistance in tempered condition. However, this class of steels is susceptible to embrittlement during tempering if it is carried out in a specific temperature range resulting in significant reduction in toughness. Embrittlement of as-normalised AISI 410 martensitic stainless steel, subjected to tempering treatment in the temperature range of 673–923 K was studied using Charpy impact tests followed by metallurgical investigations using field emission scanning electron and transmission electron microscopes. Carbides precipitated during tempering were extracted by electrochemical dissolution of the matrix and identified by X-ray diffraction. Studies indicated that temper embrittlement is highest when the steel is tempered at 823 K. Mostly iron rich carbides are present in the steel subjected to tempering at low temperatures of around 723 K, whereas chromium rich carbides (M{sub 23}C{sub 6}) dominate precipitation at high temperature tempering. The range 773–823 K is the transition temperature range for the precipitates, with both Fe{sub 2}C and M{sub 23}C{sub 6} types of carbides coexisting in the material. The nucleation of Fe{sub 2}C within the martensite lath, during low temperature tempering, has a definite role in the embrittlement of this steel. Embrittlement is not observed at high temperature tempering because of precipitation of M{sub 23}C{sub 6} carbides, instead of Fe{sub 2}C, preferentially along the lath and prior austenite boundaries. Segregation of S and P, which is widely reported as one of the causes for temper embrittlement, could not be detected in the material even through Auger electron spectroscopy studies. - Highlights: • Tempering behaviour of AISI 410 steel is studied within 673–923 K temperature range. • Temperature regime of maximum embrittlement is identified as 773–848 K. • Results show that type of

  13. Measured Biaxial Residual Stress Maps in a Stainless Steel Weld

    SciTech Connect

    Olson, Mitchell D.; Hill, Michael R.; Patel, Vipul I.; Muransky, Ondrej; Sisneros, Thomas A.

    2015-09-16

    Here, this paper describes a sequence of residual stress measurements made to determine a two-dimensional map of biaxial residual stress in a stainless steel weld. A long stainless steel (316L) plate with an eight-pass groove weld (308L filler) was used. The biaxial stress measurements follow a recently developed approach, comprising a combination of contour method and slitting measurements, with a computation to determine the effects of out-of-plane stress on a thin slice. The measured longitudinal stress is highly tensile in the weld- and heat-affected zone, with a maximum around 450 MPa, and compressive stress toward the transverse edges around ₋250 MPa. The total transverse stress has a banded profile in the weld with highly tensile stress at the bottom of the plate (y = 0) of 400 MPa, rapidly changing to compressive stress (at y = 5 mm) of ₋200 MPa, then tensile stress at the weld root (y = 17 mm) and in the weld around 200 MPa, followed by compressive stress at the top of the weld at around ₋150 MPa. Finally, the results of the biaxial map compare well with the results of neutron diffraction measurements and output from a computational weld simulation.

  14. Microstructural characterization of titanium to 304 stainless steel brazed joints

    SciTech Connect

    Camargo, P.R.C.; Liu, S. . Center for Welding and Joining Research); Trevisan, R.E. . Dept. of Fabrication Engineering)

    1993-12-01

    The formation of intermetallic compounds in brazed joints between titanium and 304 stainless steel is of major concern, since they considerably degrade the joint properties. This research examined the vacuum brazing of commercially pure titanium to 304 stainless steel using two different silver-copper brazing filler metals. Pure copper and silver were used to prepare the brazing filler metals in these experiments. Special attention was given to the characterization of the different phases formed at the brazed joint and the effect of the intermetallic compounds on the mechanical properties of the brazed joints. Light and electron microscopy, electron probe microanalysis, microhardness, and shear testing were used to support the investigation. From the mechanical properties point of view, brazed joints using an eutectic composition filler metal (Ag-28 wt-% Cu) proved to be superior compared to the joints prepared with a filler metal of composition Ag-46 wt-% Cu. To maximize the shear strength of the joint, the brazing time must be optimized such that interfacial reactions, titanium-iron intermetallics formation are minimized.

  15. Stainless Steel RSM Beneficial Reuse technical feasibility to business reality

    SciTech Connect

    Boettinger, W.L.; Mishra, G.

    1997-08-01

    The Stainless Steel Beneficial Reuse Program began in 1994 as a demonstration funded by the DOE Office of Science and Technology. The purpose was to assess the practicality of stainless steel radioactive scrap metal (RSM) recycle. Technical feasibility has been demonstrated through the production of a number of products made from recycled RSM. A solid business foundation is yet to be achieved. However, a business environment is beginning to develop as multiple markets and applications for RSM are surfacing around the Complex. The criteria for a successful business reality includes: - affordable programs, - a continuing production base from which to expand, - real products needs, - adequate RSM supply, and - a multi-year program This program currently sponsored by SRS and DOE-ORO to fabricate Defense Waste Processing Facility (DWPF) canisters from RSM provides an activity that satisfies these criteria. The program status is discussed. A comparison of the cost of DWPF canisters fabricated from recycled RSM and virgin metal is presented. The comparison is a function of several factors: disposal costs, the fabrication cost of virgin metal canisters, the fabrication cost of recycled RSM canisters, free release decontamination costs, and the cost to accumulate the RSM. These variables are analyzed and the relationship established to show the break-even point for various values of each parameter.

  16. Adsorption of Benzoic Compounds onto Stainless Steel Particles

    PubMed

    Suzuki; Shibata; Inoue

    1997-09-15

    Equilibrium experiment was conducted to investigate the factors determining the adsorption of benzoic acid (BA) and its derivatives, m- and p-hydroxy BA, onto SUS316L stainless steel particles of 8-10 &mgr;m diameter and under 100 mesh. Adsorption isotherms of these benzoic compounds were determined in the presence of 0.05 M NaCl at pH 4 and 30°C. The adsorptions of the these compounds were described well by a Langmuirian model for both adsorbents. When the maximum number of the benzoic compound adsorption sites was expressed on the basis of unit surface area (N, mol/m2), the N values were relatively constant, while the greatest value of the affinity (K, ml/&mgr;mol) was obtained for p-hydroxy BA, although its value was in the same range as that of the other two adsorbates. Diffuse-reflectance Fourier transform infrared spectra of the fine adsorbent (8-10 &mgr;m diameter) after equilibration suggest that the adsorption mainly takes place through the carboxyl group of the adsorbate-stainless steel surface interaction for all adsorbates, whereas concomitant interaction occurs in part with participation of the phenolic hydroxyl group for p-OH BA adsorbate, accounting for the difference in adsorption properties. Copyright 1997 Academic Press. Copyright 1997Academic Press

  17. Corrosion study of bare and coated stainless steel

    NASA Technical Reports Server (NTRS)

    Morrison, J. D.

    1972-01-01

    A program was conducted at Kennedy Space Center from February 1968 to February 1971 to evaluate the performance of austenitic stainless steel alloys used in fluid systems lines. For several years, there had been numerous failures of stainless steel hardware caused by pitting and stress corrosion cracking. Several alloys were evaluated for effectiveness of certain sacrificial-type protective coverings in preventing corrosion failures. Samples were tested in specially designed racks placed 91 meters (100 yards) above high-tide line at Cape Kennedy. It is concluded that: (1) unprotected tubing samples showed evidence of pitting initiation after 2 weeks; (2) although some alloys develop larger pits than others, it is probable that the actual pitting rate is independent of alloy type; (3) the deepest pitting occurred in the sheltered part of the samples; and (4) zinc-rich coatings and an aluminum-filled coating have afforded sacrificial protection against pitting for at least 28 months. It is believed that a much longer effective coating life can be expected.

  18. In Situ Measurement of Tritium Permeation Through Stainless Steel

    SciTech Connect

    Luscher, Walter G.; Senor, David J.; Clayton, Kevin; Longhurst, Glen

    2013-06-01

    The TMIST-2 irradiation experiment was conducted in the Advanced Test Reactor at Idaho National Laboratory to evaluate tritium permeation through Type 316 stainless steel (316 SS). The interior of a 316 SS seamless tube specimen was exposed to a 4He carrier gas mixed with a specified quantity of tritium (T2) to yield partial pressures of 0.1, 5, and 50 Pa at 292° and 330°C. In-situ tritium permeation measurements were made by passing a He-Ne sweep gas over the outer surface of the specimen to carry the permeated tritium to a bubbler column for liquid scintillation counting. An irradiation enhancement factor (IEF) was determined by comparing in-situ permeation data with a correlation for ex-reactor hydrogen permeation through austenitic stainless steel developed from literature data and reported by Le Claire. Nominal values for the IEF ranged between 3 and 5 for 316 SS. In-situ permeation data were also used to derive an in-reactor permeation correlation as a function of temperature and pressure. In addition, the triton recoil contribution to tritium permeation, which results from the transmutation of 3He to T, was also evaluated by introducing a 4He carrier gas mixed with 3He at a partial pressure of 1013 Pa at 330°C. Less than 3% of the tritium resulting from 3He transmutation contributed to tritium permeation.

  19. IN-SITU MEASUREMENT OF TRITIUM PERMEATION THROUGH STAINLESS STEEL

    SciTech Connect

    Luscher, Walter G.; Senor, David J.; Clayton, Kevin; Longhurst, Glen R.

    2013-06-01

    The TMIST-2 irradiation experiment was conducted in the Advanced Test Reactor at Idaho National Laboratory to evaluate tritium permeation through Type 316 stainless steel (316 SS). The interior of a 316 SS seamless tube specimen was exposed to a 4He carrier gas mixed with a specified quantity of tritium (T2) to yield partial pressures of 0.1, 5, and 50 Pa at 292° and 330°C. In-situ tritium permeation measurements were made by passing a He-Ne sweep gas over the outer surface of the specimen to carry the permeated tritium to a bubbler column for liquid scintillation counting. An irradiation enhancement factor (IEF) was determined by comparing in-situ permeation data with a correlation for ex-reactor hydrogen permeation through austenitic stainless steel developed from literature data and reported by Le Claire. Nominal values for the IEF ranged between 3 and 5 for 316 SS. In-situ permeation data were also used to derive an in-reactor permeation correlation as a function of temperature and pressure. In addition, the triton recoil contribution to tritium permeation, which results from the transmutation of 3He to T, was also evaluated by introducing a 4He carrier gas mixed with 3He at a partial pressure of 1013 Pa at 330°C. Less than 3% of the tritium resulting from 3He transmutation contributed to tritium permeation.

  20. Aging degradation of cast stainless steel: status and program

    SciTech Connect

    Chopra, O.K.; Ayrault, G.

    1983-10-01

    A program has been initiated to investigate the significance of in-service embrittlement of cast duplex stainless steels under light-water reactor operating conditions. The existing data are reviewed to determine the critical parameters that control the aging behavior and to define the objectives and scope of the investigation. The test matrices for microstructural studies and mechanical property measurements are presented. The initial experimental effort is focussed on characterizing the microstructure of long-term, low-temperature aged material. Specimens from three heats of cast CF-8 and CF-8M stainless steel aged for up to 70,000 h at 300, 350, and 400/sup 0/C were obtained from George Fisher Ltd., of Switzerland. Initial analyses reveal the formation of three different types of precipitates which are not ..cap alpha..'. An FCC phase, similar to the M/sub 23/C/sub 6/ precipitates, was present in all the long-term aged material. 15 references, 10 figures, 2 tables.

  1. Water Lubrication of Stainless Steel using Reduced Graphene Oxide Coating

    PubMed Central

    Kim, Hae-Jin; Kim, Dae-Eun

    2015-01-01

    Lubrication of mechanical systems using water instead of conventional oil lubricants is extremely attractive from the view of resource conservation and environmental protection. However, insufficient film thickness of water due to low viscosity and chemical reaction of water with metallic materials have been a great obstacle in utilization of water as an effective lubricant. Herein, the friction between a 440 C stainless steel (SS) ball and a 440 C stainless steel (SS) plate in water lubrication could be reduced by as much as 6-times by coating the ball with reduced graphene oxide (rGO). The friction coefficient with rGO coated ball in water lubrication was comparable to the value obtained with the uncoated ball in oil lubrication. Moreover, the wear rate of the SS plate slid against the rGO coated ball in water lubrication was 3-times lower than that of the SS plate slid against the uncoated ball in oil lubrication. These results clearly demonstrated that water can be effectively utilized as a lubricant instead of oil to lower the friction and wear of SS components by coating one side with rGO. Implementation of this technology in mechanical systems is expected to aid in significant reduction of environmental pollution caused by the extensive use of oil lubricants. PMID:26593645

  2. Magnetic anisotropy of ultrafine 316L stainless steel fibers

    NASA Astrophysics Data System (ADS)

    Shyr, Tien-Wei; Huang, Shih-Ju; Wur, Ching-Shuei

    2016-12-01

    An as-received 316L stainless steel fiber with a diameter of 20 μm was drawn using a bundle drawing process at room temperature to form ultrafine stainless steel fibers with diameters of 12, 8, and 6 μm. The crystalline phases of the fibers were analyzed using the X-ray diffraction (XRD) profile fitting technique. The grain sizes of γ-austenite and α‧-martensite were reduced to nanoscale sizes after the drawing process. XRD analysis and focused ion beam-scanning electron microscope observations showed that the newly formed α‧-martensitic grains were closely arrayed in the drawing direction. The magnetic property was measured using a superconducting quantum interference device vibrating sample magnetometer. The magnetic anisotropy of the fibers was observed by applying a magnetic field parallel and perpendicular to the fiber axis. The results showed that the microstructure anisotropy including the shape anisotropy, magnetocrystalline anisotropy, and the orientation of the crystalline phases strongly contributed to the magnetic anisotropy.

  3. Measured Biaxial Residual Stress Maps in a Stainless Steel Weld

    DOE PAGES

    Olson, Mitchell D.; Hill, Michael R.; Patel, Vipul I.; ...

    2015-09-16

    Here, this paper describes a sequence of residual stress measurements made to determine a two-dimensional map of biaxial residual stress in a stainless steel weld. A long stainless steel (316L) plate with an eight-pass groove weld (308L filler) was used. The biaxial stress measurements follow a recently developed approach, comprising a combination of contour method and slitting measurements, with a computation to determine the effects of out-of-plane stress on a thin slice. The measured longitudinal stress is highly tensile in the weld- and heat-affected zone, with a maximum around 450 MPa, and compressive stress toward the transverse edges around ₋250more » MPa. The total transverse stress has a banded profile in the weld with highly tensile stress at the bottom of the plate (y = 0) of 400 MPa, rapidly changing to compressive stress (at y = 5 mm) of ₋200 MPa, then tensile stress at the weld root (y = 17 mm) and in the weld around 200 MPa, followed by compressive stress at the top of the weld at around ₋150 MPa. Finally, the results of the biaxial map compare well with the results of neutron diffraction measurements and output from a computational weld simulation.« less

  4. Localized weld metal corrosion in stainless steel water tanks

    SciTech Connect

    Strum, M.J.

    1995-05-25

    The rapidly developed leaks within the TFC and TFD tanks (LLNL groundwater treatment facilities) were caused by localized corrosion within the resolidified weld metal. The corrosion was initiated by the severe oxidation of the backsides of the welds which left the exposed surfaces in a condition highly susceptible to aqueous corrosion. The propagation of surface corrosion through the thickness of the welds occurred by localized corrosive attack. This localized attack was promoted by the presence of shielded aqueous environments provided by crevices at the root of the partial penetration welds. In addition to rapid corrosion of oxidized surfaces, calcium carbonate precipitation provided an additional source of physical shielding from the bulk tank environment. Qualification testing of alternate weld procedures showed that corrosion damage can be prevented in 304L stainless steel GTA welds by welding from both sides while preventing oxidation of the tank interior through the use of an inert backing gas such as argon. Corrosion resistance was also satisfactory in GMA welds in which oxidized surfaces were postweld cleaned by wire brushing and chemically passivated in nitric acid. Further improvements in corrosion resistance are expected from a Mo-containing grade of stainless steel such as type 316L, although test results were similar for type 304L sheet welded with type 308L filler metal and type 316L sheet welded with type 316L filler metal.

  5. A porous stainless steel membrane system for extraterrestrial crop production

    NASA Technical Reports Server (NTRS)

    Koontz, H. V.; Prince, R. P.; Berry, W. L.; Knott, W. M. (Principal Investigator)

    1990-01-01

    A system was developed in which nutrient flow to plant roots is controlled by a thin (0.98 or 1.18 mm) porous (0.2 or 0.5 microns) stainless steel sheet membrane. The flow of nutrient solution through the membrane is controlled by adjusting the relative negative pressure on the nutrient solution side of the membrane. Thus, the nutrient solution is contained by the membrane and cannot escape from the compartment even under microgravity conditions if the appropriate pressure gradient across the membrane is maintained. Plant roots grow directly on the top surface of the membrane and pull the nutrient solution through this membrane interface. The volume of nutrient solution required by this system for plant growth is relatively small, since the plenum, which contains the nutrient solution in contact with the membrane, needs only to be of sufficient size to provide for uniform flow to all parts of the membrane. Solution not passing through the membrane to the root zone is recirculated through a reservoir where pH and nutrient levels are controlled. The size of the solution reservoir depends on the sophistication of the replenishment system. The roots on the surface of the membrane are covered with a polyethylene film (white on top, black on bottom) to maintain a high relative humidity and also limit light to prevent algal growth. Seeds are sown directly on the stainless steel membrane under the holes in the polyethylene film that allow a pathway for the shoots.

  6. Development of cryogenic thermal control heat pipes. [of stainless steels

    NASA Technical Reports Server (NTRS)

    1978-01-01

    The development of thermal control heat pipes that are applicable to the low temperature to cryogenic range was investigated. A previous effort demonstrated that stainless steel axially grooved tubing which met performance requirements could be fabricated. Three heat pipe designs utilizing stainless steel axially grooved tubing were fabricated and tested. One is a liquid trap diode heat pipe which conforms to the configuration and performance requirements of the Heat Pipe Experiment Package (HEPP). The HEPP is scheduled for flight aboard the Long Duration Flight Exposure Facility (LDEF). Another is a thermal switch heat pipe which is designed to permit energy transfer at the cooler of the two identical legs. The third thermal component is a hybrid variable conductance heat pipe (VCHP). The design incorporates both a conventional VCHP system and a liquid trap diode. The design, fabrication and thermal testing of these heat pipes is described. The demonstrated heat pipe behavior including start-up, forward mode transport, recovery after evaporator dry-out, diode performance and variable conductance control are discussed.

  7. Intergranular stress distributions in polycrystalline aggregates of irradiated stainless steel

    NASA Astrophysics Data System (ADS)

    Hure, J.; El Shawish, S.; Cizelj, L.; Tanguy, B.

    2016-08-01

    In order to predict InterGranular Stress Corrosion Cracking (IGSCC) of post-irradiated austenitic stainless steel in Light Water Reactor (LWR) environment, reliable predictions of intergranular stresses are required. Finite elements simulations have been performed on realistic polycrystalline aggregate with recently proposed physically-based crystal plasticity constitutive equations validated for neutron-irradiated austenitic stainless steel. Intergranular normal stress probability density functions are found with respect to plastic strain and irradiation level, for uniaxial loading conditions. In addition, plastic slip activity jumps at grain boundaries are also presented. Intergranular normal stress distributions describe, from a statistical point of view, the potential increase of intergranular stress with respect to the macroscopic stress due to grain-grain interactions. The distributions are shown to be well described by a master curve once rescaled by the macroscopic stress, in the range of irradiation level and strain considered in this study. The upper tail of this master curve is shown to be insensitive to free surface effect, which is relevant for IGSCC predictions, and also relatively insensitive to small perturbations in crystallographic texture, but sensitive to grain shapes.

  8. A porous stainless steel membrane system for extraterrestrial crop production.

    PubMed

    Koontz, H V; Prince, R P; Berry, W L

    1990-06-01

    A system was developed in which nutrient flow to plant roots is controlled by a thin (0.98 or 1.18 mm) porous (0.2 or 0.5 microns) stainless steel sheet membrane. The flow of nutrient solution through the membrane is controlled by adjusting the relative negative pressure on the nutrient solution side of the membrane. Thus, the nutrient solution is contained by the membrane and cannot escape from the compartment even under microgravity conditions if the appropriate pressure gradient across the membrane is maintained. Plant roots grow directly on the top surface of the membrane and pull the nutrient solution through this membrane interface. The volume of nutrient solution required by this system for plant growth is relatively small, since the plenum, which contains the nutrient solution in contact with the membrane, needs only to be of sufficient size to provide for uniform flow to all parts of the membrane. Solution not passing through the membrane to the root zone is recirculated through a reservoir where pH and nutrient levels are controlled. The size of the solution reservoir depends on the sophistication of the replenishment system. The roots on the surface of the membrane are covered with a polyethylene film (white on top, black on bottom) to maintain a high relative humidity and also limit light to prevent algal growth. Seeds are sown directly on the stainless steel membrane under the holes in the polyethylene film that allow a pathway for the shoots.

  9. Water Lubrication of Stainless Steel using Reduced Graphene Oxide Coating

    NASA Astrophysics Data System (ADS)

    Kim, Hae-Jin; Kim, Dae-Eun

    2015-11-01

    Lubrication of mechanical systems using water instead of conventional oil lubricants is extremely attractive from the view of resource conservation and environmental protection. However, insufficient film thickness of water due to low viscosity and chemical reaction of water with metallic materials have been a great obstacle in utilization of water as an effective lubricant. Herein, the friction between a 440 C stainless steel (SS) ball and a 440 C stainless steel (SS) plate in water lubrication could be reduced by as much as 6-times by coating the ball with reduced graphene oxide (rGO). The friction coefficient with rGO coated ball in water lubrication was comparable to the value obtained with the uncoated ball in oil lubrication. Moreover, the wear rate of the SS plate slid against the rGO coated ball in water lubrication was 3-times lower than that of the SS plate slid against the uncoated ball in oil lubrication. These results clearly demonstrated that water can be effectively utilized as a lubricant instead of oil to lower the friction and wear of SS components by coating one side with rGO. Implementation of this technology in mechanical systems is expected to aid in significant reduction of environmental pollution caused by the extensive use of oil lubricants.

  10. Fusion welding of a modern borated stainless steel

    SciTech Connect

    Robino, C.V.; Cieslak, M.J.

    1997-01-01

    Experiments designed to assess the fabrication and service weldability of 304B4A borated stainless steel were conducted. Welding procedures and parameters for manual gas tungsten arc (GTA) welding, autogenous electron beam (EB) welding and filler-added EB welding were developed and found to be similar to those for austenitic stainless steels. Following the procedure development, four test welds were produced and evaluated by microstructural analysis and Charpy impact testing. Further samples were used for determination of the postweld heat treatment (PWHT) response of the welds. The fusion zone structure of welds in this alloy consists of primary austenite dendrites with an interdendritic eutectic-like austenite/boride constituent. Welds also show an appreciable partially molten zone that consists of the austenite/boride eutectic surrounding unmelted austenite islands. The microstructure of the EB welds was substantially finer than that of the GTA welds, and boride coarsening was not observed in the solid state heat-affected zone (HAZ) of either weld type. The impact toughness of as-welded samples was found to be relatively poor, averaging less than 10 J for both GTA and EB welds. For fusion zone notched GTA and EB samples and centerline notched EB samples, fracture generally occurred along the boundary between the partially molten and solid-state regions of the HAZ. The results of the PWHT study were very encouraging, with typical values of the impact energy for HAZ notched samples approaching 40 J, or twice the minimum code-acceptable value.

  11. Development of Cast Alumina-Forming Austenitic Stainless Steels

    NASA Astrophysics Data System (ADS)

    Muralidharan, G.; Yamamoto, Y.; Brady, M. P.; Walker, L. R.; Meyer, H. M., III; Leonard, D. N.

    2016-11-01

    Cast Fe-Ni-Cr chromia-forming austenitic stainless steels with Ni levels up to 45 wt.% are used at high temperatures in a wide range of industrial applications that demand microstructural stability, corrosion resistance, and creep strength. Although alumina scales offer better corrosion protection at these temperatures, designing cast austenitic alloys that form a stable alumina scale and achieve creep strength comparable to existing cast chromia-forming alloys is challenging. This work outlines the development of cast Fe-Ni-Cr-Al austenitic stainless steels containing about 25 wt.% Ni with good creep strength and the ability to form a protective alumina scale for use at temperatures up to 800-850°C in H2O-, S-, and C-containing environments. Creep properties of the best alloy were comparable to that of HK-type cast chromia-forming alloys along with improved oxidation resistance typical of alumina-forming alloys. Challenges in the design of cast alloys and a potential path to increasing the temperature capability are discussed.

  12. Effect of Harmonic Microstructure on the Corrosion Behavior of SUS304L Austenitic Stainless Steel

    NASA Astrophysics Data System (ADS)

    Rai, Prabhat K.; Shekhar, S.; Nakatani, M.; Ota, M.; Vajpai, S. K.; Ameyama, K.; Mondal, K.

    2016-12-01

    Corrosion behavior of a harmonic structured SUS304L austenitic stainless steel was examined and compared with nonharmonic structured SUS304L stainless steel and conventional 304 stainless steel in 3.5 pct NaCl solution. The study was performed using linear polarization, potentiodynamic polarization, cyclic polarization, and a salt fog exposure test for 30 days. Characterization was accomplished using a scanning electron microscope, an electron probe microanalyzer, and Raman spectroscopy. Improved pitting corrosion resistance was found in the case of the harmonic structured steel as compared to that of the nonharmonic and the conventional 304 stainless steel. Harmonically distributed fine-grained structure, less porosity, and higher fraction of passive α-FeOOH are attributed to the improvement in corrosion resistance of the harmonic structured steel.

  13. Hot Corrosion Behavior of Stainless Steel with Al-Si/Al-Si-Cr Coating

    NASA Astrophysics Data System (ADS)

    Fu, Guangyan; Wu, Yongzhao; Liu, Qun; Li, Rongguang; Su, Yong

    2017-03-01

    The 1Cr18Ni9Ti stainless steel with Al-Si/Al-Si-Cr coatings is prepared by slurry process and vacuum diffusion, and the hot corrosion behavior of the stainless steel with/without the coatings is studied under the condition of Na2SO4 film at 950 °C in air. Results show that the corrosion kinetics of stainless steel, the stainless steel with Al-Si coating and the stainless steel with Al-Si-Cr coating follow parabolic laws in several segments. After 24 h corrosion, the sequence of the mass gain for the three alloys is the stainless steel with Al-Si-Cr coating < the stainless steel with Al-Si coating < the stainless steel without any coating. The corrosion products of the three alloys are layered. Thereinto, the corrosion products of stainless steel without coating are divided into two layers, where the outside layer contains a composite of Fe2O3 and FeO, and the inner layer is Cr2O3. The corrosion products of the stainless steel with Al-Si coating are also divided into two layers, of which the outside layer mainly consists of Cr2O3, and the inner layer is mainly SiO2. The corrosion film of the stainless steel with Al-Si-Cr coating is thin and dense, which combines well with substrate. Thereinto, the outside layer is mainly Cr2O3, and the inside layer is Al2O3. In the matrix of all of the three alloys, there exist small amount of sulfides. Continuous and protective films of Cr2O3, SiO2 and Al2O3 form on the surface of the stainless steel with Al-Si and Al-Si-Cr coatings, which prevent further oxidation or sulfide corrosion of matrix metals, and this is the main reason for the much smaller mass gain of the two alloys than that of the stainless steel without any coatings in the 24 h hot corrosion process.

  14. Attenuation of shock waves in copper and stainless steel

    SciTech Connect

    Harvey, W.B.

    1986-06-01

    By using shock pins, data were gathered on the trajectories of shock waves in stainless steel (SS-304L) and oxygen-free-high-conductivity copper (OFHC-Cu). Shock pressures were generated in these materials by impacting the appropriate target with thin (approx.1.5 mm) flying plates. The flying plates in these experiments were accelerated to high velocities (approx.4 km/s) by high explosives. Six experiments were conducted, three using SS-304L as the target material and three experiments using OFHC-Cu as the target material. Peak shock pressures generated in the steel experiments were approximately 109, 130, and 147 GPa and in the copper experiments, the peak shock pressures were approximately 111, 132, and 143 GPa. In each experiment, an attenuation of the shock wave by a following release wave was clearly observed. An extensive effort using two characteristic codes (described in this work) to theoretically calculate the attenuation of the shock waves was made. The efficacy of several different constitutive equations to successfully model the experiments was studied by comparing the calculated shock trajectories to the experimental data. Based on such comparisons, the conclusion can be drawn that OFHC-Cu enters a melt phase at about 130 GPa on the principal Hugoniot. There was no sign of phase changes in the stainless-steel experiments. In order to match the observed attenuation of the shock waves in the SS-304L experiments, it was necessary to include strength effects in the calculations. It was found that the values for the parameters in the strength equations were dependent on the equation of state used in the modeling of the experiments. 66 refs., 194 figs., 77 tabs.

  15. Dissimilar Friction Stir Welding Between UNS S31603 Austenitic Stainless Steel and UNS S32750 Superduplex Stainless Steel

    NASA Astrophysics Data System (ADS)

    Theodoro, Maria Claudia; Pereira, Victor Ferrinho; Mei, Paulo Roberto; Ramirez, Antonio Jose

    2015-02-01

    In order to verify the viability of dissimilar UNS S31603 austenitic and UNS S32750 superduplex stainless steels joined by friction stir welding, 6-mm-thick plates were welded using a PCBN-WRe tool. The welded joints were performed in position control mode at rotational speeds of 100 to 300 rpm and a feed rate of 100 mm/min. The joints performed with 150 and 200 rpm showed good appearance and no defects. The metallographic analysis of both joints showed no internal defects and that the material flow pattern is visible only in the stirred zone (SZ) of the superduplex steel. On the SZ top, these patterns are made of regions of different phases (ferrite and austenite), and on the bottom and central part of the SZ, these patterns are formed by alternated regions of different grain sizes. The ferrite grains in the superduplex steel are larger than those in the austenitic ones along the SZ and thermo-mechanically affected zone, explained by the difference between austenite and ferrite recrystallization kinetics. The amount of ferrite islands present on the austenitic steel base metal decreased near the SZ interface, caused by the dissolving of the ferrite in austenitic matrix. No other phases were found in both joints. The best weld parameters were found to be 200 rpm rotation speed, 100 mm/min feed rate, and tool position control.

  16. Persistence of deposited metals in the lungs after stainless steel and mild steel welding fume inhalation in rats.

    PubMed

    Antonini, James M; Roberts, Jenny R; Stone, Samuel; Chen, Bean T; Schwegler-Berry, Diane; Chapman, Rebecca; Zeidler-Erdely, Patti C; Andrews, Ronnee N; Frazer, David G

    2011-05-01

    Welding generates complex metal fumes that vary in composition. The objectives of this study were to compare the persistence of deposited metals and the inflammatory potential of stainless and mild steel welding fumes, the two most common fumes used in US industry. Sprague-Dawley rats were exposed to 40 mg/m(3) of stainless or mild steel welding fumes for 3 h/day for 3 days. Controls were exposed to filtered air. Generated fume was collected, and particle size and elemental composition were determined. Bronchoalveolar lavage was done on days 0, 8, 21, and 42 after the last exposure to assess lung injury/inflammation and to recover lung phagocytes. Non-lavaged lung samples were analyzed for total and specific metal content as a measure of metal persistence. Both welding fumes were similar in particle morphology and size. Following was the chemical composition of the fumes-stainless steel: 57% Fe, 20% Cr, 14% Mn, and 9% Ni; mild steel: 83% Fe and 15% Mn. There was no effect of the mild steel fume on lung injury/inflammation at any time point compared to air control. Lung injury and inflammation were significantly elevated at 8 and 21 days after exposure to the stainless steel fume compared to control. Stainless steel fume exposure was associated with greater recovery of welding fume-laden macrophages from the lungs at all time points compared with the mild steel fume. A higher concentration of total metal was observed in the lungs of the stainless steel welding fume at all time points compared with the mild steel fume. The specific metals present in the two fumes were cleared from the lungs at different rates. The potentially more toxic metals (e.g., Mn, Cr) present in the stainless steel fume were cleared from the lungs more quickly than Fe, likely increasing their translocation from the respiratory system to other organs.

  17. A peptide-stainless steel reaction that yields a new bioorganic-metal state of matter.

    PubMed

    Davis, Elisabeth M; Li, Dong-Yang; Irvin, Randall T

    2011-08-01

    A synthetic peptide derived from the native protein sequence of a metal binding bacterial pilus was observed to spontaneously react with stainless steel via a previously unreported type of chemical interaction to generate an altered form of stainless steel which we term bioorganic stainless steel. Bioorganic stainless steel has a significantly increased electron work function (4.9 ± 0.05 eV compared to 4.79 ± 0.07 eV), decreased material adhesive force (19.4 ± 8.8 nN compared to 56.7 ± 10.5 nN), and is significantly harder than regular 304 stainless steel (~40% harder). A formal or semi-formal organo-metallic covalent bond is generated between a pilin receptor binding domain and stainless steel based on XPS analysis which indicates that the electronic state of the surface is altered. Further, we establish that the peptide-steel reaction demonstrates a degree of stereospecificity as the reaction of native L-peptide, D-peptide and a retro-inverso-D-peptide yields bioorganic steel products that can be differentiated via the resulting EWF (4.867 ± 0.008 eV, 4.651 ± 0.008 eV, and 4.919 ± 0.007 eV, respectively). We conclude that electron sharing between the peptide and steel surface results in the stabilization of surface electrons to generate bioorganic steel that displays altered properties relative to the initial starting material. The bioorganic steel generated from the retro-inverso-D-peptide yields a protease stable product that is harder (41% harder at a 400 μN load), and has a 50% lower corrosion rate compared with regular stainless steel (0.11 ± 0.03 mpy and 0.22 ± 0.04 mpy, respectively). Bioorganic steel is readily fabricated.

  18. Accurate modelling of anisotropic effects in austenitic stainless steel welds

    SciTech Connect

    Nowers, O. D.; Duxbury, D. J.; Drinkwater, B. W.

    2014-02-18

    The ultrasonic inspection of austenitic steel welds is challenging due to the formation of highly anisotropic and heterogeneous structures post-welding. This is due to the intrinsic crystallographic structure of austenitic steel, driving the formation of dendritic grain structures on cooling. The anisotropy is manifested as both a ‘steering’ of the ultrasonic beam and the back-scatter of energy due to the macroscopic granular structure of the weld. However, the quantitative effects and relative impacts of these phenomena are not well-understood. A semi-analytical simulation framework has been developed to allow the study of anisotropic effects in austenitic stainless steel welds. Frequency-dependent scatterers are allocated to a weld-region to approximate the coarse grain-structures observed within austenitic welds and imaged using a simulated array. The simulated A-scans are compared against an equivalent experimental setup demonstrating excellent agreement of the Signal to Noise (S/N) ratio. Comparison of images of the simulated and experimental data generated using the Total Focusing Method (TFM) indicate a prominent layered effect in the simulated data. A superior grain allocation routine is required to improve upon this.

  19. A new constitutive model for nitrogen austenitic stainless steel

    NASA Astrophysics Data System (ADS)

    Fréchard, S.; Lichtenberger, A.; Rondot, F.; Faderl, N.; Redjaïmia, A.; Adoum, M.

    2003-09-01

    Quasi-static, quasi-dynamic and dynamic compression tests have been performed on a nitrogen alloyed austenitic stainless steel. For all strain rates, a high strain hardening rate and a good ductility have been achieved. In addition, this steel owns a great strain rate sensitivity. The temperature sensitivity bas been determined between 20°C and 400°C. Microstructural analysis has been performed after different loading conditions in relation to the behaviour of the material. Johnson-Cook and Zerilli-Armstrong models have been selected to fit the experimental data into constitutive equations. These models do not reproduce properly the behaviour of this type of steel over the complete range. A new constitutive model that fits very well all the experimental data at different strain, strain rate and temperature has been determined. The model is based on empirical considerations on the separated influence of the main parameters. Single Taylor tests have been realized to validate the models. Live observations of the specimen during impact have been achieved using a special CCD camera set-up. The overall profile at different times are compared to numerical predictions using LS-DYNA code.

  20. Laser beam surface melting of high alloy austenitic stainless steel

    SciTech Connect

    Woollin, P.

    1996-12-31

    The welding of high alloy austenitic stainless steels is generally accompanied by a substantial reduction in pitting corrosion resistance relative to the parent, due to microsegregation of Mo and Cr. This prevents the exploitation of the full potential of these steels. Processing to achieve remelting and rapid solidification offers a means of reducing microsegregation levels and improving corrosion resistance. Surface melting of parent UNS S31254 steel by laser beam has been demonstrated as a successful means of producing fine, as-solidified structures with pitting resistance similar to that of the parent, provided that an appropriate minimum beam travel speed is exceeded. The use of N{sub 2} laser trail gas increased the pitting resistance of the surface melted layer. Application of the technique to gas tungsten arc (GTA) melt runs has shown the ability to raise the pitting resistance significantly. Indeed, the use of optimized beam conditions, N{sub 2} trail gas and appropriate surface preparation prior to laser treatment increased the pitting resistance of GTA melt runs to a level approaching that of the parent material.

  1. Assessment of hydrophobicity and roughness of stainless steel adhered by an isolate of Bacillus cereus from a dairy plant

    PubMed Central

    Bernardes, Patrícia Campos; de Andrade, Nélio José; Ferreira, Sukarno Olavo; de Sá, João Paulo Natalino; Araújo, Emiliane Andrade; Delatorre, Deyse Maria Zanom; Luiz, Lívia Maria Pinheiro

    2010-01-01

    The interaction between the surface of stainless steel and Bacillus cereus was studied in terms of the characteristics of interfacial interaction determined from the measurement of the contact angle of the surface of B. cereus and stainless steel in the presence or absence of B. cereus adherence. The microtopographies and the roughness of the surface of stainless steel and stainless steel adhered by B. cereus were evaluated with the help of atomic force microscopy and perfilometry. The strain of B. cereus studied was considered hydrophilic, whereas the stainless steel was considered hydrophobic. The adhesion was not thermodynamically favorable (ΔGadhesion > 0) between the stainless steel and the strain of B. cereus studied. Thus, the interaction between them was not favored by the thermodynamic aspect of adhesion. There was no difference (p > 0.05) in the roughness of the surfaces of stainless steel adhered by B. cereus when analyzed by atomic force microscope and perfilometry. PMID:24031578

  2. Holographic investigation of residual deformations induced by a pulsed ion implanter

    NASA Astrophysics Data System (ADS)

    Kaufmann, Guillermo H.; Feugeas, Jorge N.; Marino, B. M.; Galizzi, Gustavo E.

    1990-07-01

    An ap1ication of holcgraphic interferartry to investigate the residual deformations izi1uc1 in nitrogen implantel specirrens by a plana focus device is reported. ExperilTental results Obtained for AISI 304 stainless steel specinns are presented.

  3. Experimental and Theoretical Investigations of Hot Isostatically Pressed-Produced Stainless Steel/High Alloy Tool Steel Compound Materials

    NASA Astrophysics Data System (ADS)

    Lindwall, Greta; Flyg, Jesper; Frisk, Karin; Sandberg, Odd

    2011-05-01

    Consolidation of tool steel powders and simultaneous joining to a stainless 316L steel are performed by hot isostatic pressing (HIP). Two tool steel grades are considered: a high vanadium alloyed carbon tool steel, and a high vanadium and chromium alloyed nitrogen tool steel. The boundary layer arising during diffusion bonding is in focus and, in particular, the diffusion of carbon and nitrogen over the joint. Measurements of the elemental concentration profiles and corrosion tests by the double loop-electrochemical potentiokinetic reactivation (DL-EPR) method are performed. Comparative calculations with the DICTRA software are performed and are found to be in agreement with the experimental results. It is found that the carbon tool steel grade has a more critical influence on the corrosion resistance of the stainless 316L steel in comparison to the nitrogen tool steel grade.

  4. Study of biocompatibility of medical grade high nitrogen nickel-free austenitic stainless steel in vitro.

    PubMed

    Li, Menghua; Yin, Tieying; Wang, Yazhou; Du, Feifei; Zou, Xingzheng; Gregersen, Hans; Wang, Guixue

    2014-10-01

    Adverse effects of nickel ions being released into the living organism have resulted in development of high nitrogen nickel-free austenitic stainless steels for medical applications. Nitrogen not only replaces nickel for austenitic structure stability but also improves steel properties. The cell cytocompatibility, blood compatibility and cell response of high nitrogen nickel-free austenitic stainless steel were studied in vitro. The mechanical properties and microstructure of this stainless steel were compared to the currently used 316L stainless steel. It was shown that the new steel material had comparable basic mechanical properties to 316L stainless steel and preserved the single austenite organization. The cell toxicity test showed no significant toxic side effects for MC3T3-E1 cells compared to nitinol alloy. Cell adhesion testing showed that the number of MC3T3-E1 cells was more than that on nitinol alloy and the cells grew in good condition. The hemolysis rate was lower than the national standard of 5% without influence on platelets. The total intracellular protein content and ALP activity and quantification of mineralization showed good cell response. We conclude that the high nitrogen nickel-free austenitic stainless steel is a promising new biomedical material for coronary stent development.

  5. An esthetic technique for veneering anterior stainless steel crowns with composite resin.

    PubMed

    Wiedenfeld, K R; Draughn, R A; Welford, J B

    1994-01-01

    The restoration of primary anterior teeth presents complicated esthetic and retention problems to the clinician. A technique is described for the chairside veneering of composite resin to stainless steel crowns, which results in well contoured restorations with superior durability and esthetics. A trimmed and fitted stainless steel crown can be veneered in three to five minutes. This provides the adaptability and gingival contour benefits of the stainless steel crown in conjunction with the cosmetics of the composite facings. The technique described produced composite veneers with a mean sheer bond strength of 3520 PSI (24.4 Mpa).

  6. Regular subwavelength surface structures induced by femtosecond laser pulses on stainless steel.

    PubMed

    Qi, Litao; Nishii, Kazuhiro; Namba, Yoshiharu

    2009-06-15

    In this research, we studied the formation of laser-induced periodic surface structures on the stainless steel surface using femtosecond laser pulses. A 780 nm wavelength femtosecond laser, through a 0.2 mm pinhole aperture for truncating fluence distribution, was focused onto the stainless steel surface. Under different experimental condition, low-spatial-frequency laser-induced periodic surface structures with a period of 526 nm and high-spatial-frequency laser-induced periodic surface structures with a period of 310 nm were obtained. The mechanism of the formation of laser-induced periodic surface structures on the stainless steel surface is discussed.

  7. Adhesion of a fluorinated poly(amic acid) with stainless steel surfaces

    NASA Astrophysics Data System (ADS)

    Jung, Youngsuk; Song, Sunjin; Kim, Sangmo; Yang, Yooseong; Chae, Jungha; Park, Tai-Gyoo; Dong Cho, Myung

    2013-01-01

    The authors elucidate an origin and probable mechanism of adhesion strength change at an interface of fluorinated poly(amic acid) and stainless steel. Fluorination provides favorable delamination with release strength weaker than 0.08 N/mm from a metal surface, once the amount of residual solvent becomes less than 35 wt. %. However, the release strength critically depends on film drying temperature. Characterization on stainless steel surfaces and thermodynamic analyses on wet films reveal a drying temperature of 80 °C fosters interaction between the metal oxides at stainless steel surface and the free electron donating groups in poly(amic acid).

  8. Evaluation of Alternate Stainless Steel Surface Passivation Methods

    SciTech Connect

    Clark, Elliot A.

    2005-05-31

    Stainless steel containers were assembled from parts passivated by four commercial vendors using three passivation methods. The performance of these containers in storing hydrogen isotope mixtures was evaluated by monitoring the composition of initially 50% H{sub 2} 50% D{sub 2} gas with time using mass spectroscopy. Commercial passivation by electropolishing appears to result in surfaces that do not catalyze hydrogen isotope exchange. This method of surface passivation shows promise for tritium service, and should be studied further and considered for use. On the other hand, nitric acid passivation and citric acid passivation may not result in surfaces that do not catalyze the isotope exchange reaction H{sub 2} + D{sub 2} {yields} 2HD. These methods should not be considered to replace the proprietary passivation processes of the two current vendors used at the Savannah River Site Tritium Facility.

  9. Chaotic analysis of electrochemical noise measured on stainless steel

    SciTech Connect

    Legat, A.; Dolecek, V.

    1995-06-01

    Corrosion reactions spontaneously generate fluctuations of the corrosion potential and corrosion current, known as electrochemical noise. In certain cases good correlation between electrochemical noise and corrosion rates and types can be achieved by means of spectral analysis. However, due to the chaotic nature of corrosion processes, a special kind of mathematical treatment may be needed. In this paper, the correlation dimension and the maximum Lyapunov exponent of electrochemical noise measured on stainless steel have been examined in order to characterize the mechanism of this noise. The relationship between the different types of corrosion and the chaotic characteristics of electrochemical noise have been also established. It has been shown that the general corrosion rate has no influence on the fractal dimensions of the noise. It is concluded that localized corrosion is generated by a deterministic chaotic process, whereas uniform corrosion is a random process.

  10. Comparison of repassivation kinetics of stainless steels in chloride solution

    NASA Astrophysics Data System (ADS)

    Park, Chan-Jin; Kwon, Hyuk-Sang

    2005-08-01

    Using a rapid scratching electrode technique, the repassivation kinetics of type 304, 316, 444, and 2205 stainless steels (SS) were investigated in a chloride solution. The value of cBV in a log i(t) versus 1/q(t) plot as an effective measure of the repassivation rate was used to compare the reapssivation behaviors among the alloys. During repassivation, lower values of cBV for SS corresponded with faster repassivation rates with the formation of a more protective passive film. In a comparison of repassivation rates based on the alloy's cBV values, the best repassivation behavior was shown by 2205 SS, followed by 444 SS and 316 SS. However, 304 SS exhibited an inflection point in the log i(t) versus 1/q(t) curve, suggesting that dissolution by localized corrosion rather than SCC may occur in the alloy under given conditions.

  11. Laser milling of martensitic stainless steels using spiral trajectories

    NASA Astrophysics Data System (ADS)

    Romoli, L.; Tantussi, F.; Fuso, F.

    2017-04-01

    A laser beam with sub-picosecond pulse duration was driven in spiral trajectories to perform micro-milling of martensitic stainless steel. The geometry of the machined micro-grooves channels was investigated by a specifically conceived Scanning Probe Microscopy instrument and linked to laser parameters by using an experimental approach combining the beam energy distribution profile and the absorption phenomena in the material. Preliminary analysis shows that, despite the numerous parameters involved in the process, layer removal obtained by spiral trajectories, varying the radial overlap, allows for a controllable depth of cut combined to a flattening effect of surface roughness. Combining the developed machining strategy to a feed motion of the work stage, could represent a method to obtain three-dimensional structures with a resolution of few microns, with an areal roughness Sa below 100 nm.

  12. Sensitization and stabilization of type 409 ferritic stainless steel

    SciTech Connect

    Fritz, J.D.; Franson, I.A.

    1997-08-01

    Type 409 (UNS S40900) ferritic stainless steel, used widely in automotive exhaust systems, can be subject to intergranular corrosion (IGC) of weld heat-affected zones (HAZ), even though ASTM stabilization requirements (Ti = 6 {times} C) are met. A boiling Cu/6% CuSO{sub 4}/0.5% H{sub 2}SO{sub 4} test is shown to be appropriate for detecting IGC of welds and HAZ. This test was used to establish stabilization requirements for type 409, whether dual-stabilized with Ti + Nb or singly stabilized with Ti alone. It was found that the stabilization requirement should be Ti + Nb {ge} 0.08 + 8 (C + N). Benefits of dual stabilization include improved surface quality and formability without sacrifice of mechanical properties or weldability.

  13. Fracture properties evaluation of stainless steel piping for LBB applications

    SciTech Connect

    Kim, Y.J.; Seok, C.S.; Chang, Y.S.

    1997-04-01

    The objective of this paper is to evaluate the material properties of SA312 TP316 and SA312 TP304 stainless steels and their associated welds manufactured for shutdown cooling line and safety injection line of nuclear generating stations. A total of 82 tensile tests and 58 fracture toughness tests on specimens taken from actual pipes were performed and the effect of various parameters such as the pipe size, the specimen orientation, the test temperature and the welding procedure on the material properties are discussed. Test results show that the effect of the test temperature on the fracture toughness was significant while the effects of the pipe size and the specimen orientation on the fracture toughness were negligible. The material properties of the GTAW weld metal was in general higher than those of the base metal.

  14. Laser additive manufacturing of stainless steel micro fuel cells

    NASA Astrophysics Data System (ADS)

    Scotti, Gianmario; Matilainen, Ville; Kanninen, Petri; Piili, Heidi; Salminen, Antti; Kallio, Tanja; Franssila, Sami

    2014-12-01

    This paper introduces laser additive manufacturing as a new method for the fabrication of micro fuel cells: The method opens up the capability of ultrafast prototyping, as the whole device can be produced at once, starting from a digital 3D model. In fact, many different devices can be produced at once, which is useful for the comparison of competing designs. The micro fuel cells are made of stainless steel, so they are very robust, thermally and chemically inert and long-lasting. This enables the researcher to perform a large number of experiments on the same cell without physical or chemical degradation. To demonstrate the validity of our method, we have produced three versions of a micro fuel cell with square pillar flowfield. All three have produced high current and power density, with maximum values of 1.2 A cm-2 for the current and 238 mW cm-2 for power.

  15. Crevice and pitting corrosion behavior of stainless steels in seawater

    SciTech Connect

    Zaragoza-Ayala, A.E.; Orozco-Cruz, R.

    1999-11-01

    Pitting and crevice corrosion tests in natural seawater were performed on a series of stainless steels (i.e., S31603, N08904, S32304, S31803, S32520, N08925 and S31266) in order to determine their resistance to these types of localized corrosion. Open circuit potential (OCP) measurements for these alloys show for short exposure times an ennoblement in the OCP. After a certain time, occasional fall and rise in the OCP values was observed, which can be related to nucleation and repassivation of pits and/or crevices on the metal surface. Analysis of the electrochemical behavior and microscopic observations shows that only S31603 and S32304 alloys were susceptible to crevice and pitting corrosion, whereas the remaining alloys exhibited good resistance. Pitting potentials determined by the potentiodynamic technique also show S3 1603 and S32304 are susceptible to pitting corrosion under the experimental conditions used in this work.

  16. Interface nanochemistry effects on stainless steel diffusion bonding

    NASA Astrophysics Data System (ADS)

    Cox, M. J.; Carpenter, R. W.; Kim, M. J.

    2002-02-01

    The diffusion-bonding behavior of single-phase austenitic stainless steel depends strongly on the chemistry of the surfaces to be bounded. We found that very smooth (0.5 nm root-mean-square (RMS) roughness), mechanically polished and lapped substrates would bond completely in ultrahigh vacuum (UHV) in 1 hour at 1000 °C under 3.5 MPa uniaxial pressure, if the native oxide on the substrates was removed by ion-beam cleaning, as shown by in-situ Auger analysis. No voids were observed in these bonded interfaces by transmission electron microscopy (TEM), and the strength was equal to that of the unbounded bare material. No bond formed between the substrates if in-situ ion cleaning was not used. The rougher cleaned substrates partially bonded, indicating that roughness, as well as native oxides, reduced the bonding kinetics.

  17. Stress corrosion cracking susceptibility of irradiated Type 304 stainless steels

    SciTech Connect

    Chung, H.M.; Ruther, W.E.; Sanecki, J.E.; Kassner, T.F.

    1992-08-01

    Slow-strain-rate tensile tests and microstructural analysis by Auger electron spectroscopy were conducted on specimens of high- and commercial-purity (HP and CP) heats of Type 304 stainless steel obtained from neutron absorber tubes and a control blade sheath after irradiation up to 2.5 [times] 10[sup 2l] n[center dot]cm[sup [minus]2] (E > l MeV) in boiling water reactors (BWRs). The susceptibility of the HP absorber tubes to intergranular stress corrosion cracking (IGSCC) was higher than that of the CP absorber tubes or the CP control blade sheath. IGSCC susceptibilities of the BWR components could not be correlated to segregation impurities on grain boundaries. However for comparable fluence levels, Cr on grain-boundaries.

  18. Stress corrosion cracking susceptibility of irradiated Type 304 stainless steels

    SciTech Connect

    Chung, H.M.; Ruther, W.E.; Sanecki, J.E.; Kassner, T.F.

    1992-08-01

    Slow-strain-rate tensile tests and microstructural analysis by Auger electron spectroscopy were conducted on specimens of high- and commercial-purity (HP and CP) heats of Type 304 stainless steel obtained from neutron absorber tubes and a control blade sheath after irradiation up to 2.5 {times} 10{sup 2l} n{center_dot}cm{sup {minus}2} (E > l MeV) in boiling water reactors (BWRs). The susceptibility of the HP absorber tubes to intergranular stress corrosion cracking (IGSCC) was higher than that of the CP absorber tubes or the CP control blade sheath. IGSCC susceptibilities of the BWR components could not be correlated to segregation impurities on grain boundaries. However for comparable fluence levels, Cr on grain-boundaries.

  19. Laser surface modification of stainless steels for cavitation erosion resistance

    NASA Astrophysics Data System (ADS)

    Kwok, Chi Tat

    1999-12-01

    Austenitic stainless steel UNS S31603 (Fe -17.6Cr -11.2Ni -2.5Mo -1.4Mn -0.4Si -0.03C) has higher pitting corrosion resistance but lower cavitation erosion resistance than that of UNS S30400. This is because of its lower tendency for strain induced martensitic transformation and higher stacking fault energy as compared with those of UNS S30400. In order to improve its cavitation erosion resistance, surface modification of S31603 was performed by laser surface melting and laser surface alloying using a 2-kW CW Nd-YAG laser and a 3-kW CW CO2 laser. For laser surface melting, austenitic stainless steel UNS S30400, super duplex stainless steel UNS S32760 and martensitic stainless steel UNS S42000 were also investigated for comparison purpose. For laser surface alloying, alloying materials including various elements (Co, Cr, Ni, Mo, Mn, Si & C), alloys (AlSiFe & NiCrSiB), ceramics (Si3N 4, SiC, Cr3C2, TiC, CrB & Cr2O 3) and alloys-ceramics (Co-WC, Ni-WC, Ni-Al2O3, Ni-Cr2C3) were used to modify the surface of S31603. The alloyed surface was achieved first by flame spraying or pre-placing of the alloy powder on the S31603 surface and then followed by laser surface remelting. The cavitation erosion characteristics of laser surface modified specimens in 3.5% NaCl solution at 23°C were studied by means of a 20-kHz ultrasonic vibrator at a peak-to-peak amplitude of 30 mum. In addition, their pitting corrosion behaviour was evaluated by electrochemical techniques. The microstructures, compositions, phase changes and damage mechanisms under cavitation erosion were investigated by optical microscopy, SEM, EDAX and X-ray diffractometry. Mechanical properties such as microhardness profile were also examined. The cavitation erosion resistance Re (reciprocal of the mean depth of penetration rate) of laser surface melted S31603 was found to be improved by 22% and was attributed to the existence of tensile residual stress. Improvement on the Re of S42000 was found to be 8.5 times

  20. Dynamic recrystallization in friction surfaced austenitic stainless steel coatings

    SciTech Connect

    Puli, Ramesh Janaki Ram, G.D.

    2012-12-15

    Friction surfacing involves complex thermo-mechanical phenomena. In this study, the nature of dynamic recrystallization in friction surfaced austenitic stainless steel AISI 316L coatings was investigated using electron backscattered diffraction and transmission electron microscopy. The results show that the alloy 316L undergoes discontinuous dynamic recrystallization under conditions of moderate Zener-Hollomon parameter during friction surfacing. - Highlights: Black-Right-Pointing-Pointer Dynamic recrystallization in alloy 316L friction surfaced coatings is examined. Black-Right-Pointing-Pointer Friction surfacing leads to discontinuous dynamic recrystallization in alloy 316L. Black-Right-Pointing-Pointer Strain rates in friction surfacing exceed 400 s{sup -1}. Black-Right-Pointing-Pointer Estimated grain size matches well with experimental observations in 316L coatings.

  1. Defouling and cleaning using nanobubbles on stainless steel.

    PubMed

    Chen, Hongbing; Mao, Huiling; Wu, Liping; Zhang, Jun; Dong, Yaming; Wu, Zhihua; Hu, Jun

    2009-01-01

    The present work demonstrates that nanobubbles can be used as cleaning agents on stainless steel (SS) surfaces. Cleaning efficiency has been quantified. Using an Atomic Force Microscope (AFM), it was demonstrated that nanobubbles can be produced by electrochemical treatment on a SS surface either with or without adsorbed bovine serum albumin (BSA). After allowing adsorption on SS overnight, radio-labeled BSA was removed by electrochemically generated nanobubbles, and then the remaining BSA on the surface was quantified by radioactivity measurement. The results indicate that nanobubbles can remove >10% of the protein in each 3-min electrochemical treatment while in a control group, washing with water and electrolyte resulted in no more than 3% of the protein being removed each time. Cleaning of conducting surfaces by nanobubbles is promising in any system where fouling occurs in biomedia.

  2. Formability analysis of austenitic stainless steel-304 under warm conditions

    NASA Astrophysics Data System (ADS)

    Lade, Jayahari; Singh, Swadesh Kumar; Banoth, Balu Naik; Gupta, Amit Kumar

    2013-12-01

    A warm deep drawing process of austenitic stainless steel-304 (ASS-304) of circular blanks with coupled ther mal analysis is studied in this article. 65 mm blanks were deep drawn at different temperatures and thickness distribution is experimentally measured after cutting the drawn component into two halves. The process is simulated using explicit fin ite element code LS-DYNA. A Barlat 3 parameter model is used in the simulation, as the material is anisotropic up to 30 0°C. Material properties for the simulation are determined at different temperatures using a 5 T UTM coupled with a furn ace. In this analysis constant punch speed and variable blank holder force (BHF) is applied to draw cups without wrinkle.

  3. High Resolution Temperature Estimation During Laser Cladding of Stainless Steel

    NASA Astrophysics Data System (ADS)

    Devesse, Wim; De Baere, Dieter; Hinderdael, Michaël; Guillaume, Patrick

    Laser cladding is a technique that is used for the coating, repair and production of metallic parts. Material is added to the surface of the part by injecting a flow of powder into a melt pool that is created with a high power laser beam. When the beam scans the surface of the substrate, strong local heating and cooling results. A good knowledge of the temperature distribution history during the laser cladding process is vital to predict and optimize the material properties of the final part. This paper presents a contactless temperature measurement system with high temporal and spatial resolution based on a hyperspectral line camera. High temperature measurements were made during laser cladding of AISI 316L stainless steel. A good correlation is shown between the temperature measurements and microscope images taken after creation of the clad.

  4. New grain formation during warm deformation of ferritic stainless steel

    SciTech Connect

    Belyakov, A.; Sakai, Taku; Kaibyshev, R.

    1998-01-01

    Microstructural evolution accompanied by localization of plastic flow was studied in compression of a ferritic stainless steel with high stacking fault energy (SFE) at 873 K ({approx} 0.5 Tm). The structure evolution is characterized by the formation of dense dislocation walls at low strains and subsequently of microbands and their clusters at moderate strains, followed by the evolution of fragmented structure inside the clusters of microbands at high strains. The misorientations of the fragmented boundaries and the fraction of high-angle grain boundaries increase substantially with increasing strain. Finally, further straining leads to the formation of new fine grains with high-angle boundaries, which become more equiaxed than the previous fragmented structure. The mechanisms operating during such structure changes are discussed in detail.

  5. Stainless steel crown aspiration during sedation in pediatric dentistry.

    PubMed

    Adewumi, A; Kays, David W

    2008-01-01

    Foreign body aspiration (FBA) causes death in more than 300 children every year in the United States. Morbidity and mortality are increased in children due to narrow airways and immature protective mechanisms. Factors to consider in pediatric dentistry are: (1) the patient's age and behavior; (2) presence and extent of disability; (3) local anesthesia; (4) body positioning; and (5) loose teeth. FBA requires prompt recognition and early treatment to minimize potentially serious and sometimes fatal consequences. The purpose of this case report was to describe the aspiration of a stainless steel crown in a 5-year-old boy during conscious sedation. It also discusses how a prompt and accurate diagnosis, early referral, and immediate treatment helped prevent serious complications.

  6. Ultrasound treatment of centrifugally atomized 316 stainless steel powders

    NASA Astrophysics Data System (ADS)

    Rawers, James C.; McCune, Robert A.; Dunning, John S.

    1991-12-01

    The Bureau of Mines is studying the surface characteristics of rapidly solidified powders and the potential for surface modification of fine powders prior to consolidation. The surface modification and work hardening of fine powders were accomplished by applying high-energy ultrasound to centrifugally atomized austenitic 316 stainless steel powders suspended in liquid media. Cavitation implosion changed the surface morphology, hammering the surface and occasionally fretting off microchips of work-hardened metal. Ultrasound-cavitation work-hardened metal powder surfaces producing a strained, duplex austenite face-centered cubic (fcc)-martensite body-centered tetragonal (bct) phase structure. The amount of work hardening depended upon the quantity of ultrasound energy used, considering both power level and experimental time. Work hardening was relatively independent of the liquid media used.

  7. Crack initiation mechanisms in IASCC of stainless steel alloys

    SciTech Connect

    Cookson, J.M.; Was, G.S.; Andresen, P.L.

    1995-12-31

    An abnormally high oxygen concentration was recently discovered in a high purity stainless steel alloy widely used in IASCC studies. This led to an investigation into the role of oxygen on the initiation of intergranular cracking in irradiated samples in high temperature water. The concentration of oxygen in the alloys correlated with the number of cracks initiated in the proton irradiated region of samples strained in water containing 0.5 {micro}S/cm H{sub 2}SO{sub 4} at 288 C. This suggests that the presence of oxygen, in the form of spinel oxide particles, can lead to a substantial increase in the likelihood of crack initiation. This effect is only observed in irradiated samples strained in water, not in either unirradiated (non-sensitized) samples strained in water or irradiated samples strained in argon This paper examines the possible role of oxides in promoting crack initiation and the implications for IASCC.

  8. Weld Properties of a Free Machining Stainless Steel

    SciTech Connect

    J. A. Brooks; S. H. Goods; C. V. Robino

    2000-08-01

    The all weld metal tensile properties from gas tungsten arc and electron beam welds in free machining austenitic stainless steels have been determined. Ten heats with sulfur contents from 0.04 to 0.4 wt.% and a wide range in Creq/Nieq ratios were studied. Tensile properties of welds with both processes were related to alloy composition and solidification microstructure. The yield and ultimate tensile strengths increased with increasing Creq/Nieq ratios and ferrite content, whereas the ductility measured by RA at fracture decreased with sulfur content. Nevertheless, a range in alloy compositions was identified that provided a good combination of both strength and ductility. The solidification cracking response for the same large range of compositions are discussed, and compositions identified that would be expected to provide good performance in welded applications.

  9. Corrosion resistance of kolsterised austenitic 304 stainless steel

    SciTech Connect

    Abudaia, F. B. Khalil, E. O. Esehiri, A. F. Daw, K. E.

    2015-03-30

    Austenitic stainless suffers from low wear resistance in applications where rubbing against other surfaces is encountered. This drawback can be overcome by surface treatment such as coating by hard materials. Other treatments such as carburization at relatively low temperature become applicable recently to improve hardness and wear resistance. Carburization heat treatment would only be justified if the corrosion resistance is unaffected. In this work samples of 304 stainless steels treated by colossal supersaturation case carburizing (known as Kolsterising) carried out by Bodycote Company was examined for pitting corrosion resistance at room temperature and at 50 °C. Comparison with results obtained for untreated samples in similar testing conditions show that there is no deterioration in the pitting resistance due to the Kolsterising heat treatment. X ray diffraction patterns obtained for Kolsterising sample showed that peaks correspond to the austenite phase has shifted to lower 2θ values compared with those of the untreated sample. The shift is an indication for expansion of austenite unit cells caused by saturation with diffusing carbon atoms. The XRD of Kolsterising samples also revealed additional peaks appeared in the patterns due to formation of carbides in the kolsterised layer. Examination of these additional peaks showed that these peaks are attributed to a type of carbide known as Hagg carbide Fe{sub 2}C{sub 5}. The absence of carbides that contain chromium means that no Cr depletion occurred in the layer and the corrosion properties are maintained. Surface hardness measurements showed large increase after Kolsterising heat treatment.

  10. Corrosion resistance of kolsterised austenitic 304 stainless steel

    NASA Astrophysics Data System (ADS)

    Abudaia, F. B.; Khalil, E. O.; Esehiri, A. F.; Daw, K. E.

    2015-03-01

    Austenitic stainless suffers from low wear resistance in applications where rubbing against other surfaces is encountered. This drawback can be overcome by surface treatment such as coating by hard materials. Other treatments such as carburization at relatively low temperature become applicable recently to improve hardness and wear resistance. Carburization heat treatment would only be justified if the corrosion resistance is unaffected. In this work samples of 304 stainless steels treated by colossal supersaturation case carburizing (known as Kolsterising) carried out by Bodycote Company was examined for pitting corrosion resistance at room temperature and at 50 °C. Comparison with results obtained for untreated samples in similar testing conditions show that there is no deterioration in the pitting resistance due to the Kolsterising heat treatment. X ray diffraction patterns obtained for Kolsterising sample showed that peaks correspond to the austenite phase has shifted to lower 2θ values compared with those of the untreated sample. The shift is an indication for expansion of austenite unit cells caused by saturation with diffusing carbon atoms. The XRD of Kolsterising samples also revealed additional peaks appeared in the patterns due to formation of carbides in the kolsterised layer. Examination of these additional peaks showed that these peaks are attributed to a type of carbide known as Hagg carbide Fe2C5. The absence of carbides that contain chromium means that no Cr depletion occurred in the layer and the corrosion properties are maintained. Surface hardness measurements showed large increase after Kolsterising heat treatment.

  11. NDE Assessments of Cast Stainless Steel Reactor Piping Components

    SciTech Connect

    Diaz, Aaron A.; Anderson, Michael T.; Cumblidge, Stephen E.; Doctor, Steven R.; Mathews, Royce

    2006-02-01

    Studies conducted at the Pacific Northwest National Laboratory (PNNL) in Richland, Washington, have focused on developing and evaluating the effectiveness and reliability of novel NDE approaches for the inspection of coarse-grained, cast stainless steel reactor components. The primary objective of this work is to provide information to the United States Nuclear Regulatory Commission (US NRC) on the utility, effectiveness and reliability of ultrasonic testing (UT) and eddy current testing (ET) inspection techniques as related to the in-service inspection of primary piping components in pressurized water reactors (PWRs). This paper describes recent developments and results from assessments of three different NDE approaches including an ultrasonic phased array inspection methodology, an eddy current testing technique and a low-frequency ultrasonic inspection methodology coupled with a synthetic aperture focusing technique (SAFT). Westinghouse Owner’s Group (WOG) cast stainless steel pipe segments with thermal and mechanical fatigue cracks located close to the weld roots, were used for assessing the inspection methods. ET studies were conducted on the inner diameter (ID) surface of piping specimens while the ultrasonic inspection methods were performed from the outer diameter (OD) surface of the specimens. The ET technique employed a ZETEC MIZ-27SI Eddy Current instrument and a ZETEC Z0000857-1 cross point spot probe with an operating frequency of 250 kHz. On some samples where noise levels were high, degaussing of the sample resulted in significant improvements. The phased array approach was implemented using an RD Tech Tomoscan III system operating at 1 MHz and composite volumetric images of the samples were generated. The low-frequency ultrasonic method employs a zone-focused, multi-incident angle; inspection protocol (operating at 250-450 kHz) coupled with a synthetic aperture focusing technique (SAFT) for improved signal-to-noise and advanced imaging

  12. Interactions between stainless steel, shear stress, and monocytes.

    PubMed

    Messer, Regina L W; Mickalonis, John; Lewis, Jill B; Omata, Yo; Davis, Cortney M; Brown, Yolanda; Wataha, John C

    2008-10-01

    Angioplasty with stent placement is commonly used to treat coronary atherosclerosis. However, 20-40% of stainless steel stents restenose within 6 months via a prolonged inflammatory response mediated by monocytic infiltration and cytokine secretion. In the current study, we tested a hypothesis that blood flow and monocytes interact to alter stent corrosion. We assessed the effects of THP1 monocytes on the corrosion rate of 316L stainless steel (316LSS) under shear stress (0.5-50 dyn/cm(2)). In addition, THP1 cytokine secretion was determined using cytokine arrays and ELISA analyses. Data were compared using ANOVA and Tukey post hoc analysis (alpha = 0.05). Monocytes significantly lowered 316LSS corrosion rates without limiting current density. However, shear stress alone did not alter the corrosion rate of 316LSS. THP1 cells adhered to the 316LSS surface at all flow rates. Exposure to the 316LSS/corrosion test under high fluid flow rates increased (>twofold) the secretion of 7 of the 42 cytokines tested (angeogenin, GRO, I309, interleukin 8, interleukin 6, interleukin 1beta, and macrophage chemoattractant protein-1). Each of these cytokines play a role in wound healing, macrophage differentiation, and cell proliferation, all hallmarks of in-stent restenosis. Furthermore, only IL8 levels were significantly higher than any of the system controls during the 316LSS/corrosion test conditions. The IL8 levels from the 316LSS/corrosion tests were not significantly different from the +LPS control. Together, these data suggest that monocytic cells maybe activated by exposure to 316LSS stents and could contribute to in-stent restenosis and altered corrosion of the stent.

  13. Documentation of Stainless Steel Lithium Circuit Test Section Design. Suppl

    NASA Technical Reports Server (NTRS)

    Godfroy, Thomas J. (Compiler); Martin, James J.

    2010-01-01

    The Early Flight Fission-Test Facilities (EFF-TF) team was tasked by Naval Reactors Prime Contract Team (NRPCT) to design, fabricate, and test an actively pumped lithium (Li) flow circuit. This Li circuit takes advantage of work in progress at the EFF TF on a stainless steel sodium/potassium (NaK) circuit. The effort involved modifying the original stainless steel NaK circuit such that it could be operated with Li in place of NaK. This new design considered freeze/thaw issues and required the addition of an expansion tank and expansion/extrusion volumes in the circuit plumbing. Instrumentation has been specified for Li and circuit heaters have been placed throughout the design to ensure adequate operational temperatures and no uncontrolled freezing of the Li. All major components have been designed and fabricated prior to circuit redesign for Li and were not modified. Basic circuit components include: reactor segment, Li to gas heat exchanger, electromagnetic liquid metal pump, load/drain reservoir, expansion reservoir, instrumentation, and trace heaters. The reactor segment, based on a Los Alamos National Laboratory 100-kW design study with 120 fuel pins, is the only prototypic component in the circuit. However, due to earlier funding constraints, a 37-pin partial-array of the core, including the central three rings of fuel pins (pin and flow path dimensions are the same as those in the full design), was selected for fabrication and test. This Technical Publication summarizes the design and integration of the pumped liquid metal Li flow circuit as of May 1, 2005. This supplement contains drawings, analysis, and calculations

  14. Documentation of Stainless Steel Lithium Circuit Test Section Design

    NASA Technical Reports Server (NTRS)

    Godfroy, T. J.; Martin, J. J.; Stewart, E. T.; Rhys, N. O.

    2010-01-01

    The Early Flight Fission-Test Facilities (EFF-TF) team was tasked by Naval Reactors Prime Contract Team (NRPCT) to design, fabricate, and test an actively pumped lithium (Li) flow circuit. This Li circuit takes advantage of work in progress at the EFF TF on a stainless steel sodium/potassium (NaK) circuit. The effort involved modifying the original stainless steel NaK circuit such that it could be operated with Li in place of NaK. This new design considered freeze/thaw issues and required the addition of an expansion tank and expansion/extrusion volumes in the circuit plumbing. Instrumentation has been specified for Li and circuit heaters have been placed throughout the design to ensure adequate operational temperatures and no uncontrolled freezing of the Li. All major components have been designed and fabricated prior to circuit redesign for Li and were not modified. Basic circuit components include: reactor segment, Li to gas heat exchanger, electromagnetic liquid metal pump, load/drain reservoir, expansion reservoir, instrumentation, and trace heaters. The reactor segment, based on a Los Alamos National Laboratory 100-kW design study with 120 fuel pins, is the only prototypic component in the circuit. However, due to earlier funding constraints, a 37-pin partial-array of the core, including the central three rings of fuel pins (pin and flow path dimensions are the same as those in the full design), was selected for fabrication and test. This Technical Publication summarizes the design and integration of the pumped liquid metal Li flow circuit as of May 1, 2005.

  15. Role of nanocrystalline cerium oxide coatings on austenitic stainless steels

    NASA Astrophysics Data System (ADS)

    Zhang, Haiying

    Protective nanocrystalline cerium oxide coating has been applied to ASTM grade 304L and 304 austenitic stainless steels to improve its oxidation resistance at elevated temperatures. Experimentally, the selected alloy was exposed to 800°C/1000°C under dry air conditions. Weight changes (DeltaW/A) were monitored as a function of time and the results were compared with uncoated alloys tested under similar conditions. It was found that the oxidation resistances of 304L and 304 stainless steels were significantly improved. A comparison of the oxidation rates indicated that the nanocrystalline cerium oxide coating reduced the rate of oxidation by more than two orders of magnitude. Nevertheless, a comprehensive understanding of the mechanisms responsible for the reduction in the oxidation rate is not clear. Consequently, this work is aimed at investigating the mechanisms involved during scale growth in the presence or absence of nanocrystalline coatings. For this purpose, density functional theory was carried out in order to predict oxygen and iron diffusion microscopic activation energies and reveal the intrinsic characteristics of nanocrystalline coatings. A numerical simulation of corrosion process has also been conducted to predict the corrosion rates of alloys with and without coatings. Hence, the results from simulations are compared with the experimental outcome, and possible explanations are given to account for the reduction in the exhibited oxidation rates. The simulation results will provide a highly valuable tool for the realization of functional nanostructures and architectures "by design", particularly in the development of novel coatings, and a new approach of life assessment.

  16. Impact Tensile Testing of Stainless Steels at Various Temperatures

    SciTech Connect

    D. K. Morton

    2008-03-01

    Stainless steels are used for the construction of numerous spent nuclear fuel or radioactive material containers that may be subjected to high strains and moderate strain rates during accidental drop events. Mechanical characteristics of these base materials and their welds under dynamic loads in the strain rate range of concern (1 to 300 per second) are not well documented. However, research is being performed at the Idaho National Laboratory to quantify these characteristics. The work presented herein discusses tensile impact testing of dual-marked 304/304L and 316/316L stainless steel material specimens. Both base material and welded material specimens were tested at -20 oF, room temperature, 300 oF, and 600 oF conditions. Utilizing a drop weight impact test machine and 1/4-inch and 1/2-inch thick dog bone-shaped test specimens, a strain rate range of approximately 4 to 40 per second (depending on initial temperature conditions) was achieved. Factors were determined that reflect the amount of increased strain energy the material can absorb due to strain rate effects. Using the factors, elevated true stress-strain curves for these materials at various strain rates and temperatures were generated. By incorporating the strain rate elevated true stress-strain material curves into an inelastic finite element computer program as the defined material input, significant improvement in the accuracy of the computer analyses was attained. However, additional impact testing is necessary to achieve higher strain rates (up to 300 per second) before complete definition of strain rate effects can be made for accidental drop events and other similar energy-limited impulsive loads. This research approach, using impact testing and a total energy analysis methodology to quantify strain rate effects, can be applied to many other materials used in government and industry.

  17. Hydrogen embrittlement of duplex stainless steel and maraging steel in sea water: Effect of pressure

    SciTech Connect

    Pohjanne, P.; Festy, D.

    1994-12-31

    Hydrogen embrittlement behavior of cast super duplex stainless steel and cast maraging steel was examined as a function of electrode potential and hydrostatic pressure, i.e, the water depth, in synthetic sea water using fracture mechanics bolt-loaded wedge-opening (WOL) specimens. The experimental variables investigated included: (1) Electrode potential: free corrosion potential and cathodic protection; (2) Hydrostatic pressure: ambient and 10 MPa corresponding depth of 1,000 meters. The duplex stainless-,steel was not susceptible to hydrogen embrittlement with initial stress intensity values of 30 MPa{radical}m < K{sub i} < 45 MPa{radical}m at ambient pressure. However, at pressure of 10 MPa slight crack growth was observed at open circuit potential and the crack growth was enhanced by the cathodic protection. The maraging steel was susceptible to hydrogen embrittlement in all tests, with all examined initial stress intensity values, K{sub i} < 36 MPa{radical}m. At the open circuit potential the crack growth rate was almost independent of the pressure. Cathodic protection enhanced crack growth and lowered the threshold stress intensity value at ambient as well as at 10 MPa pressure and the crack growth rate increased clearly as pressure increased from 0.1 MPa to 10 MPa. According to these experimental results the combined effect of cathodic protection and hydrostatic pressure must be taken into consideration when designing new offshore structures and equipment especially for deep sea application.

  18. Biocompatibly Coated 304 Stainless Steel as Superior Corrosion-Resistant Implant Material to 316L Steel

    NASA Astrophysics Data System (ADS)

    Paul, Subir; Mandal, Chandranath

    2013-10-01

    Surface treatments of 304 stainless steel by electro-coating and passivating in few inorganic electrolytes were found to be very effective in drastically reducing the corrosion rate of the material in stimulated body fluid (SBF) by several orders in comparison to that of 316L steel, presently being used for orthopedic implants. Polarization studies of electrodeposited hydroxyl apatite coating on 304 steel showed remarkably improved corrosion current. Cyclic polarization of the material in SBF reflected the broadened passivity region, much lower passive current, and narrower hysteresis loops. Similar effects were also found through the formation of inorganic coatings by passivation in NaF, CaNO3, and calcium phosphate buffer solutions. Surface characterization by XRD showed the peaks of the respective coating crystals. The morphology of the coatings studied by SEM showed a flake-type structure for hydroxyapatite coating and fine spherical-subspherical particles for other coatings.

  19. Effect of Oxidation on the Bonding Formation of Plasma-Sprayed Stainless Steel Splats onto Stainless Steel Substrate

    NASA Astrophysics Data System (ADS)

    Wang, Jun; Li, Chang-Jiu; Yang, Guan-Jun; Li, Cheng-Xin

    2017-01-01

    Stainless steel splats were deposited on 304 stainless substrates with different thicknesses of oxide layer to examine the effect of substrate oxidation on splat morphology and splat-substrate interface bonding by inert low-pressure plasma spraying. The cross sections of splats showing the splat-substrate interface were prepared by focus ion beam (FIB). The splat morphology and splat-substrate interface bonding state were characterized by scanning electron microscopy. The interface bonding was also examined by an electrolytic etching process. Results showed that with increasing oxide layer thickness and surface roughness, the morphology of splat changed from disk shape to splashed finger-like shape. The examination into the interface bonding by using FIB-prepared cross-sectional samples revealed that the splat interface bonding depended on the oxide roughness and composition. The interface bonding with a ratio of 44% was formed at the inner part of a splat on the pre-oxidized substrate when iron oxide presented on the surface, and the roughness of oxide scale was <5 nm. When the pre-oxidizing temperature exceeded 800 °C, the surface roughness increased to 14 nm and chromium oxide covered the pre-oxidized surface, resulting in no effective bonding forming at the whole interface. Thus, surface roughness and oxide composition have a significant influence on the splat interface bonding formation.

  20. Galvanic corrosion between dental precious alloys and magnetic stainless steels used for dental magnetic attachments.

    PubMed

    Takahashi, Noriko; Takada, Yukyo; Okuno, Osamu

    2008-03-01

    In this study, we examined the corrosion behavior of dental precious alloys and magnetic stainless steels, namely SUS 444, SUS XM27, and SUS 447J1, used for dental magnetic attachments. Their galvanic corrosion behavior was evaluated from the viewpoint of corrosion potentials when they were in contact with each other. Rest potentials of the precious alloys were constantly higher than those of magnetic stainless steels. Since most gold alloys raised the corrosion potential more significantly than silver alloys did, silver alloys seemed to be better suited than gold alloys for combination with magnetic stainless steels. However, all corrosion potential values were sufficiently lower than the breakdown potentials of the stainless steels and existed within their passive regions. Based on the findings of this study, SUS XM27 and SUS 447J1--which exhibited higher breakdown potentials than SUS 444--emerged as the preferred choices for combination with gold alloys.