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Sample records for alamos trident laser

  1. Trident Pair Production in Strong Laser Pulses

    SciTech Connect

    Ilderton, Anton

    2011-01-14

    We calculate the trident pair production amplitude in a strong laser background. We allow for finite pulse durations, while still treating the laser fields nonperturbatively in strong-field QED. Our approach reveals explicitly the individual contributions of the one-step and two-step processes. We also expose the role gauge invariance plays in the amplitudes and discuss the relation between our results and the optical theorem.

  2. Relativistic Transparency Experiments at the Trident Laser

    NASA Astrophysics Data System (ADS)

    Cobble, J. A.; Palaniyappan, S.; Gautier, D. C.; Kim, Y. H.; Clark, D. D.; Johnson, R. P.; Shimada, T.; Fernandez, J. C.; Herrmann, H. W.

    2013-10-01

    With near-diffraction-limited irradiance of 3 × 1020 W/cm2 on target and prelase contrast better than 10-9, we have accessed the regime of relativistic transparency (RT) at the Trident Laser. The goal was to assess electron debris emitted from the target rear surface with phase-contrast imaging (PCI) and current density measurements (hence, the total electron current). Companion diagnostics show whether the experiments are in the target-normal-sheath-acceleration mode or in the RT regime. The superb laser contrast allows us to shoot targets as thin as 50 nm. PCI at 527 nm is temporally resolved to 600 fs. It has shown the evolution of electron behavior over tens of ps, including thermal electrons accompanying the ion jet, accelerated to many tens of MeV earlier in time. Faraday-cup measurements indicate the transfer of many uC of charge during the laser drive. As a ride-along experiment using a gas Cherenkov detector (GCD), we have detected gamma rays of energy >5 MeV. This radiation has a prompt component and a lesser source, driven by accelerated ions, that is time resolved by the GCD. The ion time of flight is compared to Thomson parabola data. Electron energy spectra are also collected. This work has been performed under the auspices of the US DOE contract number DE-AC52-06NA25396.

  3. Article on Trident Laser Facility for NA-11 Stockpile Stewardship Quarterly

    SciTech Connect

    Barnes, Cris W.

    2012-08-13

    The Trident Intermediate-Scale Laser Facility at Los Alamos National Laboratory is an extremely versatile Nd:glass laser system dedicated to high energy density laboratory physics and weapons physics research and fundamental laser-matter interactions. Trident is a three-beam, 200 J/beam at the second harmonic for glass (527 nm wavelength), facility with tremendous flexibility and high beam quality. Pulse durations varying over 6 orders of magnitude, from 0.5 picoseconds to 1.0 microsecs, can be directed to either of two different target chambers with changeable illumination geometries, including the ability to achieve near-diffraction limited focus. This provides a unique range of capability at one facility from sub-picosecond pulses (and high-intensity laser science) to nanosecond pulses (and LPI physics relevant to ICF) to microsecond pulses (and driving flyer plates for supported shock dynamic materials science.) When in short-pulse mode (less than picosecond pulse), a single beam can provide up to 200 TW of power with uniquely controllable and measured pre-pulse contrast of 10 orders of magnitude. A recent external capability review at Los Alamos concluded that 'Trident is generating excellent, cutting edge science and is a leading intermediate scale laser system worldwide.'

  4. Trident Web page

    SciTech Connect

    Johnson, Randall P.; Fernandez, Juan C.

    2012-06-25

    An Extensive Diagnostic Suite Enables Cutting-edge Research at Trident The Trident Laser Facility at Los Alamos National Laboratory is an extremely versatile Nd:glass laser system dedicated to high energy density physics research and fundamental laser-matter interactions. Trident's Unique Laser Capabilities Provide an Ideal Platform for Many Experiments. The laser system consists of three high energy beams which can be delivered into two independent target experimental areas. The target areas are equipped with an extensive suite of diagnostics for research in ultra-intense laser matter interactions, dynamic material properties, and laser-plasma instabilities. Several important discoveries and first observations have been made at Trident including laser-accelerated MeV mono-energetic ions, nonlinear kinetic plasma waves, transition between kinetic and fluid nonlinear behavior, as well as other fundamental laser-matter interaction processes. Trident's unique long-pulse capabilities have enabled state-of-the-art innovations in laser-launched flyer-plates, and other unique loading techniques for material dynamics research.

  5. Neutron imaging with the short-pulse laser driven neutron source at the Trident laser facility

    NASA Astrophysics Data System (ADS)

    Guler, N.; Volegov, P.; Favalli, A.; Merrill, F. E.; Falk, K.; Jung, D.; Tybo, J. L.; Wilde, C. H.; Croft, S.; Danly, C.; Deppert, O.; Devlin, M.; Fernandez, J.; Gautier, D. C.; Geissel, M.; Haight, R.; Hamilton, C. E.; Hegelich, B. M.; Henzlova, D.; Johnson, R. P.; Schaumann, G.; Schoenberg, K.; Schollmeier, M.; Shimada, T.; Swinhoe, M. T.; Taddeucci, T.; Wender, S. A.; Wurden, G. A.; Roth, M.

    2016-10-01

    Emerging approaches to short-pulse laser-driven neutron production offer a possible gateway to compact, low cost, and intense broad spectrum sources for a wide variety of applications. They are based on energetic ions, driven by an intense short-pulse laser, interacting with a converter material to produce neutrons via breakup and nuclear reactions. Recent experiments performed with the high-contrast laser at the Trident laser facility of Los Alamos National Laboratory have demonstrated a laser-driven ion acceleration mechanism operating in the regime of relativistic transparency, featuring a volumetric laser-plasma interaction. This mechanism is distinct from previously studied ones that accelerate ions at the laser-target surface. The Trident experiments produced an intense beam of deuterons with an energy distribution extending above 100 MeV. This deuteron beam, when directed at a beryllium converter, produces a forward-directed neutron beam with ˜5 × 109 n/sr, in a single laser shot, primarily due to deuteron breakup. The neutron beam has a pulse duration on the order of a few nanoseconds with an energy distribution extending from a few hundreds of keV to almost 80 MeV. For the experiments on neutron-source spot-size measurements, our gated neutron imager was setup to select neutrons in the energy range of 2.5-35 MeV. The spot size of neutron emission at the converter was measured by two different imaging techniques, using a knife-edge and a penumbral aperture, in two different experimental campaigns. The neutron-source spot size is measured ˜1 mm for both experiments. The measurements and analysis reported here give a spatial characterization for this type of neutron source for the first time. In addition, the forward modeling performed provides an empirical estimate of the spatial characteristics of the deuteron ion-beam. These experimental observations, taken together, provide essential yet unique data to benchmark and verify theoretical work into the

  6. Recent High-Intensity Experiments at the Trident Laser

    NASA Astrophysics Data System (ADS)

    Cobble, James; Palaniyappan, Sasikumar; Gautier, Cort; Kim, Yongho; Huang, Chengkun

    2014-10-01

    With near-diffraction-limited irradiance of 2 × 1020 W/cm2 on target and prelase contrast better than 10-8, we have accessed the regime of relativistic transparency (RT) at the Trident Laser. The goal was to assess electron debris emitted from the target rear surface with phase-contrast imaging (PCI) and current density measurements (hence, the total electron current). Companion diagnostics show whether the experiments are in the target-normal-sheath-acceleration mode or in the RT regime. The superb laser contrast allows us to shoot targets as thin as 50 nm. PCI at 527 nm is temporally resolved to 600 fs. It has shown the evolution of electron behavior over tens of ps, including thermal electrons accompanying the ion jet, accelerated to many tens of MeV earlier in time. Faraday-cup measurements indicate the transfer of many microC of charge during the laser drive. As a ride-along experiment using a gas Cherenkov detector (GCD), we have detected gamma rays of energy >5 MeV. This radiation has a prompt component and a lesser source, driven by accelerated ions, that is time resolved by the GCD. The ion time of flight is compared to Thomson parabola data. Electron energy spectra are also collected. This work is supported by US DOE/NNSA, performed at LANL, operated by LANS LLC under Contract DE-AC52-06NA25396.

  7. Los Alamos Laser Eye Investigation.

    SciTech Connect

    Odom, C. R.

    2005-01-01

    A student working in a laser laboratory at Los Alamos National Laboratory sustained a serious retinal injury to her left eye when she attempted to view suspended particles in a partially evacuated target chamber. The principle investigator was using the white light from the flash lamp of a Class 4 Nd:YAG laser to illuminate the particles. Since the Q-switch was thought to be disabled at the time of the accident, the principal investigator assumed it would be safe to view the particles without wearing laser eye protection. The Laboratory Director appointed a team to investigate the accident and to report back to him the events and conditions leading up to the accident, equipment malfunctions, safety management causal factors, supervisory and management action/inaction, adequacy of institutional processes and procedures, emergency and notification response, effectiveness of corrective actions and lessons learned from previous similar events, and recommendations for human and institutional safety improvements. The team interviewed personnel, reviewed documents, and characterized systems and conditions in the laser laboratory during an intense six week investigation. The team determined that the direct and primary failures leading to this accident were, respectively, the principle investigator's unsafe work practices and the institution's inadequate monitoring of worker performance. This paper describes the details of the investigation, the human and institutional failures, and the recommendations for improving the laser safety program.

  8. Results from colliding magnetized plasma jet experiments executed at the Trident laser facility

    NASA Astrophysics Data System (ADS)

    Manuel, M. J.-E.; Rasmus, A. M.; Kurnaz, C. C.; Klein, S. R.; Davis, J. S.; Drake, R. P.; Montgomery, D. S.; Hsu, S. C.; Adams, C. S.; Pollock, B. B.

    2015-11-01

    The interaction of high-velocity plasma flows in a background magnetic field has applications in pulsed-power and fusion schemes, as well as astrophysical environments, such as accretion systems and stellar mass ejections into the magnetosphere. Experiments recently executed at the Trident Laser Facility at the Los Alamos National Laboratory investigated the effects of an expanding aluminum plasma flow into a uniform 4.5-Tesla magnetic field created using a solenoid designed and manufactured at the University of Michigan. Opposing-target experiments demonstrate interesting collisional behavior between the two magnetized flows. Preliminary interferometry and Faraday rotation measurements will be presented and discussed. This work is funded by the U.S Department of Energy, through the NNSA-DS and SC-OFES Joint Program in High-Energy-Density Laboratory Plasmas, grant number DE-NA0001840. Support for this work was provided by NASA through Einstein Postdoctoral Fellowship grant number PF3-140111 awarded by the Chandra X-ray Center, which is operated by the Astrophysical Observatory for NASA under contract NAS8-03060.

  9. Control of laser-accelerated ions: Recent advances and preliminary results from the new Trident 250-TW laser

    NASA Astrophysics Data System (ADS)

    Hegelich, B. Manuel; Albright, Brian J.; Yin, Lin; Flippo, Kirk A.; Cort Gautier, D.; Letzring, Samuel; Schulze, Roland; Schmitt, Mark; Fernandez, Juan C.

    2007-11-01

    Advanced target design, treatment and characterization enable progress in laser-driven ion acceleration. We demonstrate spectral shaping and mono-energetic features from in-situ formed source layers on different substrate materials. Advanced targets and experimental techniques allow control of the properties of laser accelerated ion beams, which is of importance to future applications like Ion Fast Ignition (IFI), WDM research and others. We will also present preliminary results from the new 250-TW Trident laser system that will allow the extrapolation of scaling laws similar to those derived for proton acceleration.

  10. Implementation of STUD Pulses at the Trident Laser and Initial Results

    NASA Astrophysics Data System (ADS)

    Johnson, R. P.; Shimada, T.; Montgomery, D. S.; Afeyan, B.; Hüller, S.

    2012-10-01

    Controlling and mitigating laser-plasma instabilities such as stimulated Brillouin scattering, stimulated Raman scattering, and crossed-beam energy transfer is important to achieve high-gain inertial fusion using laser drivers. Recent theory and simulations show that these instabilities can be largely controlled using laser pulses consisting of spike trains of uneven duration and delay (STUD) by modulating the laser on a picosecond time scale [1,2]. We have designed and implemented a STUD pulse generator at the LANL Trident Laser Facility using Fourier synthesis to produce a 0.5-ns envelope of psec-duration STUD pulses using a spatial light modulator. Initial results from laser propagation tests and measurements as well as initial laser-plasma characterization experiments will be presented.[4pt] [1] B. Afeyan and S. H"uller, ``Optimal Control of Laser Plasma Instabilities using STUD pulses,'' IFSA 2011, P.Mo.1, to appear in Euro. Phys. J. Web of Conf. (2012).[2] S. H"uller and B. Afeyan, ``Simulations of drastically reduced SBS with STUD pulses,'' IFSA 2011, O.Tu8-1, to appear in Euro. Phys. J. Web of Conf. (2012).

  11. Above scaling short-pulse ion acceleration from flat foil and ``Pizza-top Cone'' targets at the Trident laser facility

    NASA Astrophysics Data System (ADS)

    Flippo, Kirk; Hegelich, B. Manuel; Cort Gautier, D.; Johnson, J. Randy; Kline, John L.; Shimada, Tsutomu; Fernández, Juan C.; Gaillard, Sandrine; Rassuchine, Jennifer; Le Galloudec, Nathalie; Cowan, Thomas E.; Malekos, Steve; Korgan, Grant

    2006-10-01

    Ion-driven Fast Ignition (IFI) has certain advantages over electron-driven FI due to a possible large reduction in the amount of energy required. Recent experiments at the Los Alamos National Laboratory's Trident facility have yielded ion energies and efficiencies many times in excess of recent published scaling laws, leading to even more potential advantages of IFI. Proton energies in excess of 35 MeV have been observed from targets produced by the University of Nevada, Reno - dubbed ``Pizza-top Cone'' targets - at intensities of only 1x10^19 W/cm^2 with 20 joules in 600 fs. Energies in excess of 24 MeV were observed from simple flat foil targets as well. The observed energies, above any published scaling laws, are attributed to target production, preparation, and shot to shot monitoring of many laser parameters, especially the laser ASE prepulse level and laser pulse duration. The laser parameters are monitored in real-time to keep the laser in optimal condition throughout the run providing high quality, reproducible shots.

  12. A multipurpose TIM-based optical telescope for Omega and the Trident laser facilities

    SciTech Connect

    Oertel, J.A.; Murphy, T.J.; Berggren, R.R.

    1998-12-31

    The authors have recently designed and are building a telescope which acts as an imaging light collector relaying the image to an optical table for experiment dependent analysis and recording. The expected primary use of this instrument is a streaked optical pyrometer for witness plate measurements of Hohlraum drive temperature. The telescope is based on University of Rochester`s Ten-Inch Manipulator (TIM) which allows compatibility between Omega, Trident, and the NIF lasers. The optics capture a f/7 cone of light, have a field of view of 6-mm, have a spatial resolution of 5 to 7-{micro}m per line pair at the object plane, and are optimized for operation at 280-nm. The image is at a magnification of 11.7x, which is convenient for many experiments, but can be changed using additional optics that reside outside the TIM.

  13. Overview of laser technology at Los Alamos National Laboratory

    SciTech Connect

    Lewis, G.K.; Cremers, D.A.

    1994-09-01

    Los Alamos National Laboratory has had a long history of involvement in laser sciences and has been recognized both for its large laser programs and smaller scale developments in laser technology and applications. The first significant program was with the Rover nuclear-based rocket propulsion system in 1968 to study laser initiated fusion. From here applications spread to programs in laser isotope separation and development of large lasers for fusion. These programs established the technological human resource base of highly trained laser physicists, engineers, and chemists that remain at the Laboratory today. Almost every technical division at Los Alamos now has some laser capability ranging from laser development, applications, studies on nonlinear processes, modeling and materials processing. During the past six years over eight R&D-100 Awards have been received by Los Alamos for development of laser-based techniques and instrumentation. Outstanding examples of technology developed include LIDAR applications to environmental monitoring, single molecule detection using fluorescence spectroscopy, a laser-based high kinetic energy source of oxygen atoms produced by a laser-sustained plasma, laser-induced breakdown spectroscopy (LIBS) for compositional, analysis, thin film high temperature superconductor deposition, multi-station laser welding, and direct metal deposition and build-up of components by fusing powder particles with a laser beam.

  14. Mercury: The Los Alamos ICF KrF laser system

    SciTech Connect

    Czuchlewski, S.J.; York, G.W.; Bigio, I.J.; Brucker, J.; Hanson, D.; Honig, E.M.; Kurnit, N.; Leland, W.; McCown, A.W.; McLeod, J.; Rose, E.; Thomas, S.; Thompson, D.

    1993-01-19

    The Mercury KrF laser facility at Los Alamos is being built with the benefit of lessons learned from the Aurora system. An increased understanding of KrF laser engineering, and the designed implementation of system flexibility, will permit Mercury to serve as a tested for a variety of advanced KrF technology concepts.

  15. Recent progress of the Los Alamos advanced free electron laser

    SciTech Connect

    Nguyen, D.C.; Austin, R.H.; Chan, K.C.D.; Feldman, D.W.; Goldstein, J.C.; Gierman, S.M.; Kinross-Wright, J.M.; Kong, S.H.; Plato, J.G.; Russell, S.J.

    1994-05-01

    Many industrial and research applications can benefit from the availability of a compact, user-friendly, broadly tunable and high average power free electron laser (FEL). Over the past four years, the Los Alamos Advanced FEL has been built with these design goals. The key to a compact FEL is the integration of advanced beam technologies such as a high-brightness photoinjector, a high-gradient compact linac, and permanent magnet beamline components. These technologies enable the authors to shrink the FEL size yet maintain its high average power capability. The Advanced FEL has been in operation in the near ir (4-6 {mu}m) since early 1993. Recent results of the Advanced FEL lasing at saturation and upgrades to improve its average power are presented.

  16. Los Alamos Using Neutrons to Stop Nuclear Smugglers

    ScienceCinema

    Favalli, Andrea; Swinhoe, Martyn

    2016-07-12

    Los Alamos National Laboratory researchers have successfully demonstrated for the first time that laser-generated neutrons can be enlisted as a useful tool in the War on Terror. The international research team used the short-pulse laser at Los Alamos's TRIDENT facility to generate a neutron beam with novel characteristics that interrogated a closed container to confirm the presence and quantity of nuclear material inside. The successful experiment paves the way for creation of a table-top-sized or truck-mounted neutron generator that could be installed at strategic locations worldwide to thwart smugglers trafficking in nuclear materials.

  17. Los Alamos Using Neutrons to Stop Nuclear Smugglers

    SciTech Connect

    Favalli, Andrea; Swinhoe, Martyn

    2013-06-03

    Los Alamos National Laboratory researchers have successfully demonstrated for the first time that laser-generated neutrons can be enlisted as a useful tool in the War on Terror. The international research team used the short-pulse laser at Los Alamos's TRIDENT facility to generate a neutron beam with novel characteristics that interrogated a closed container to confirm the presence and quantity of nuclear material inside. The successful experiment paves the way for creation of a table-top-sized or truck-mounted neutron generator that could be installed at strategic locations worldwide to thwart smugglers trafficking in nuclear materials.

  18. Potential biomedical application of the Los Alamos infrared free-electron laser: DNA spectroscopy

    NASA Astrophysics Data System (ADS)

    Lumpkin, A. H.; Trewhella, J.; Garcia, A. E.

    Recently, the Los Alamos Free-Electron Laser has demonstrated optical output at wavelengths from 9 to 45 microns. Potential application of such a laser are proposed for the study of vibrational modes predicted in different conformations of DNA and in DNA complexed with drugs and/or proteins that regulate replication and/or transcription.

  19. Overview of recent advances in excimer laser technology at Los Alamos

    SciTech Connect

    Bigio, I.J.; Sze, R.C.; Taylor, A.J.; Gibson, R.B.

    1988-01-01

    From among the areas of excimer laser development at Los Alamos two are selected for further discussion: ultra-high brightness excimer laser systems and discharge-pumped XeF(C..-->..A) lasers operating in the blue-green portion of the spectrum. Two different high brightness systems are described. One is based on small-aperture KrF amplifiers, while the other is based on a large-aperture XeCl amplifier. The XeF(C..-->..A) laser is tunable from 435 to 525 nm, and may one day become a viable alternative to pulsed dye lasers for many applications. 14 refs., 4 figs.

  20. Short-pulse, high-intensity lasers at Los Alamos

    SciTech Connect

    Taylor, A.J.; Roberts, J.P.; Rodriguez, G.; Fulton, R.D.; Kyrala, G.A.; Schappert, G.T.

    1994-03-01

    Advances in ultrafast lasers and optical amplifiers have spurred the development of terawatt-class laser systems capable of delivering focal spot intensities approaching 10{sup 20} W/cm{sup 2}. At these extremely high intensities, the optical field strength is more than twenty times larger than the Bohr electric field, permitting investigations of the optical properties of matter in a previously unexplored regime. The authors describe two laser systems for high intensity laser interaction experiments: The first is a terawatt system based on amplification of femtosecond pulses in XeCl which yields 250 mJ in 275 fs and routinely produces intensifies on target in excess of 10{sup 18} W/cm{sup 2}. The second system is based on chirped pulse amplification of 100-fs pulses in Ti:sapphire.

  1. Research on fission induced plasmas and nuclear pumped lasers at the Los Alamos Scientific Laboratory

    NASA Technical Reports Server (NTRS)

    Helmick, H. H.

    1979-01-01

    A program of research on gaseous uranium and uranium plasmas is being conducted at The Los Alamos Scientific Laboratory under sponsorship of the National Aeronautics and Space Administration. The objective of this work is twofold: (1) to demonstrate the proof of principle of a gaseous uranium fueled reactor, and (2) pursue fundamental research on nuclear pumped lasers. The relevancy of the two parallel programs is embodied in the possibility of a high-performance uranium plasma reactor being used as the power supply for a nuclear pumped laser system. The accomplishments in the two above fields are summarized

  2. Information about Practicums at Los Alamos

    SciTech Connect

    Bradley, Paul A.

    2012-07-24

    The Los Alamos Neutron Science Center is the premier facility for neutron science experiments ranging from cross section measurements, neutron scattering experiments, proton radiography, cold neutrons, actinide neutronic properties, and many other exciting topics. The National High Magnetic Field Laboratory is home to several powerful magnets, including the one that created the first non-destructive 100 Tesla field in March 2012. They probe the electronic structure of superconductors, magnetic properties of materials (including magneto-quantum effects). Research is also conducted in correlated materials, thermoacoustics, and magnetic properties of actinides. The Trident Laser has a unique niche with very high power, short pulse experiments, with a peak power of 10{sup 20} W in short pulse mode. Discoveries range from production of monoenergetic MeV ion beam, nonlinear kinetic plasma waves, the transition between kinetic and fluid nonlinear behavior and other laser-plasma interaction processes.

  3. Characterization of the Los Alamos IPG YLR-6000 fiber laser using multiple optical paths and laser focusing optics

    SciTech Connect

    Milewski, John O; Bernal, John E

    2009-01-01

    Fiber laser technology has been identified as the replacement power source for the existing Los Alamos TA-55 production laser welding system. An IPG YLR-6000 fiber laser was purchased, installed at SM-66 R3, and accepted in February 2008. No characterization of the laser and no welding was performed in the Feb 2008 to May 2009 interval. T. Lienert and J. Bernal (Ref. 1, July 2009) determined the existing 200 mm Rofin collimator and focus heads used with the Rofin diode pumped lasers were inadequate for use with the IPG laser due to clipping of the IPG laser beam. Further efforts in testing of the IPG laser with Optoskand fiber delivery optics and a Rofin 120 mm collimator proved problematic due to optical fiber damage. As a result, IPG design optical fibers were purchased as replacements for subsequent testing. Within the same interval, an IPG fiber-to-fiber (F2F) connector, custom built for LANL, (J. Milewski, S. Gravener, Ref.2) was demonstrated and accepted at IPG Oxford, MA in August 2009. An IPG service person was contracted to come to LANL to assist in the installation, training, troubleshooting and characterization of the multiple beam paths and help perform laser head optics characterization. The statement of work is provided below: In summary the laser system, optical fibers, F2F connector, Precitec head, and a modified Rofin type (w/120mm Optoskand collimator) IWindowIBoot system focus head (Figure 1) were shown to perform well at powers up to 6 kW CW. Power measurements, laser spot size measurements, and other characterization data and lessons learned are contained within this report. In addition, a number of issues were identified that will require future resolution.

  4. TRIDENT high-energy-density facility experimental capabilities and diagnostics.

    PubMed

    Batha, S H; Aragonez, R; Archuleta, F L; Archuleta, T N; Benage, J F; Cobble, J A; Cowan, J S; Fatherley, V E; Flippo, K A; Gautier, D C; Gonzales, R P; Greenfield, S R; Hegelich, B M; Hurry, T R; Johnson, R P; Kline, J L; Letzring, S A; Loomis, E N; Lopez, F E; Luo, S N; Montgomery, D S; Oertel, J A; Paisley, D L; Reid, S M; Sanchez, P G; Seifter, A; Shimada, T; Workman, J B

    2008-10-01

    The newly upgraded TRIDENT high-energy-density (HED) facility provides high-energy short-pulse laser-matter interactions with powers in excess of 200 TW and energies greater than 120 J. In addition, TRIDENT retains two long-pulse (nanoseconds to microseconds) beams that are available for simultaneous use in either the same experiment or a separate one. The facility's flexibility is enhanced by the presence of two separate target chambers with a third undergoing commissioning. This capability allows the experimental configuration to be optimized by choosing the chamber with the most advantageous geometry and features. The TRIDENT facility also provides a wide range of standard instruments including optical, x-ray, and particle diagnostics. In addition, one chamber has a 10 in. manipulator allowing OMEGA and National Ignition Facility (NIF) diagnostics to be prototyped and calibrated.

  5. TRIDENT high-energy-density facility experimental capabilities and diagnosticsa)

    NASA Astrophysics Data System (ADS)

    Batha, S. H.; Aragonez, R.; Archuleta, F. L.; Archuleta, T. N.; Benage, J. F.; Cobble, J. A.; Cowan, J. S.; Fatherley, V. E.; Flippo, K. A.; Gautier, D. C.; Gonzales, R. P.; Greenfield, S. R.; Hegelich, B. M.; Hurry, T. R.; Johnson, R. P.; Kline, J. L.; Letzring, S. A.; Loomis, E. N.; Lopez, F. E.; Luo, S. N.; Montgomery, D. S.; Oertel, J. A.; Paisley, D. L.; Reid, S. M.; Sanchez, P. G.; Seifter, A.; Shimada, T.; Workman, J. B.

    2008-10-01

    The newly upgraded TRIDENT high-energy-density (HED) facility provides high-energy short-pulse laser-matter interactions with powers in excess of 200TW and energies greater than 120J. In addition, TRIDENT retains two long-pulse (nanoseconds to microseconds) beams that are available for simultaneous use in either the same experiment or a separate one. The facility's flexibility is enhanced by the presence of two separate target chambers with a third undergoing commissioning. This capability allows the experimental configuration to be optimized by choosing the chamber with the most advantageous geometry and features. The TRIDENT facility also provides a wide range of standard instruments including optical, x-ray, and particle diagnostics. In addition, one chamber has a 10in. manipulator allowing OMEGA and National Ignition Facility (NIF) diagnostics to be prototyped and calibrated.

  6. Laser-Launched Flyer Plates and Direct Laser Shocks for Dynamic Material Property Measurements

    NASA Astrophysics Data System (ADS)

    Paisley, D. L.; Swift, D. C.; Johnson, R. P.; Kopp, R. A.; Kyrala, G. A.

    2002-07-01

    The Trident laser at Los Alamos was used to impart known and controlled shocks in various materials by launching flyer plates or by irradiating the sample directly. Materials investigated include copper, gold, NiTi, SS316, and other metals and alloys. Tensile spall strength, elastic-plastic transition, phase boundaries, and equation of state can be determined with small samples. Using thin samples (0.1 - 1.0 mm thick) as targets, high pressure gradients can be generated with relatively low pressures, resulting in high tensile strain rates (105 to 108 s-1). Free surface and interface velocities are recorded with point- and line-imaging VISARs. The flexible spatial and temporal pulse profiles of Trident, coupled with the use of laser-launched flyer plates, provides capabilities which complement experiments conducted using gas guns and tensile bars.

  7. Control of linear accelerator noise in the Los Alamos free-electron laser (FEL)

    SciTech Connect

    Lynch, M.T.

    1986-01-01

    The Los Alamos FEL requires tight control of the amplitudes and phases of the fields in two linear accelerator tanks to obtain stable lasing. The accelerator control loops must establish constant, stable, repeatable amplitudes and phases of the rf fields and must have excellent bandwidth to control high-frequency noise components. A model of the feedback loops has been developed that agrees well with measurements and allows easy substitution of components and circuits, thus reducing breadboarding requirements. The model permits both frequency and time-domain analysis. This paper describes the accelerator control scheme and our model and discusses the control of noise in feedback loops, showing how low-frequency-noise components (errors) can be corrected, but high-frequency-noise components (errors) are actually amplified by the feedback circuit. Measurements of noise in both open- and closed-loop modes are shown and comparison is made with results from the model calculations.

  8. A New Gated X-Ray Detector for the Orion Laser Facility

    SciTech Connect

    Clark, David D.; Aragonez, Robert J.; Archuleta, Thomas N.; Fatherley, Valerie E.; Hsu, Albert H.; Jorgenson, H. J.; Mares, Danielle; Oertel, John A.; Oades, Kevin; Kemshall, Paul; Thomas, Philip; Young, Trevor; Pederson, Neal

    2012-08-08

    Gated X-Ray Detectors (GXD) are considered the work-horse target diagnostic of the laser based inertial confinement fusion (ICF) program. Recently, Los Alamos National Laboratory (LANL) has constructed three new GXDs for the Orion laser facility at the Atomic Weapons Establishment (AWE) in the United Kingdom. What sets these three new instruments apart from the what has previously been constructed for the National Ignition Facility (NIF) at Lawrence Livermore National Laboratory (LLNL) is: improvements in detector head microwave transmission lines, solid state embedded hard drive and updated control software, and lighter air box design and other incremental mechanical improvements. In this paper we will present the latest GXD design enhancements and sample calibration data taken on the Trident laser facility at Los Alamos National Laboratory using the newly constructed instruments.

  9. A new gated x-ray detector for the Orion laser facility

    NASA Astrophysics Data System (ADS)

    Clark, David D.; Aragonez, Robert; Archuleta, Thomas; Fatherley, Valerie; Hsu, Albert; Jorgenson, Justin; Mares, Danielle; Oertel, John; Oades, Kevin; Kemshall, Paul; Thomas, Phillip; Young, Trevor; Pederson, Neal

    2012-10-01

    Gated X-Ray Detectors (GXD) are considered the work-horse target diagnostic of the laser based inertial confinement fusion (ICF) program. Recently, Los Alamos National Laboratory (LANL) has constructed three new GXDs for the Orion laser facility at the Atomic Weapons Establishment (AWE) in the United Kingdom. What sets these three new instruments apart from what has previously been constructed for the National Ignition Facility (NIF) at Lawrence Livermore National Laboratory (LLNL) is: improvements in detector head microwave transmission lines, solid state embedded hard drive and updated control software, and lighter air box design and other incremental mechanical improvements. In this paper we will present the latest GXD design enhancements and sample calibration data taken on the Trident laser facility at Los Alamos National Laboratory using the newly constructed instruments.

  10. Trident Technical College 1999 Fact Book.

    ERIC Educational Resources Information Center

    Trident Technical Coll., Charleston, SC.

    Presents the 12th edition of the Trident Technical College (South Carolina) Fact Book, which offers relevant information on principal characteristics and strengths of the college. Includes the following chapters: (1) general information, such as vision and mission statements, institutional goals, history, and accreditation; (2) enrollment…

  11. Experimental investigation of strong field trident production

    SciTech Connect

    Esberg, J.; Kirsebom, K.; Knudsen, H.; Thomsen, H. D.; Uggerhoej, E.; Uggerhoej, U. I.; Sona, P.; Mangiarotti, A.; Ketel, T. J.; Dizdar, A.; Dalton, M. M.; Ballestrero, S.; Connell, S. H.

    2010-10-01

    We show by experiment that an electron impinging on an electric field that is of critical magnitude in its rest frame, may produce an electron-positron pair. Our measurements address higher-order QED, using the strong electric fields obtainable along particular crystallographic directions in single crystals. For the amorphous material our data are in good agreement with theory, whereas a discrepancy with theory on the magnitude of the trident enhancement is found in the precisely aligned case where the strong electric field acts.

  12. Laser-launched flyer plates and direct laser shocks for dynamic material property measurements

    NASA Astrophysics Data System (ADS)

    Paisley, Dennis; Swift, Damian; Johnson, Randall; Kopp, Roger; Kyrala, George

    2001-06-01

    The Trident laser at Los Alamos was used to impart known and controlled shocks in various materials by launching flyer plates or by irradiating the sample directly. Materials investigated include copper, gold, NiTi, SS316, and other metals and alloys. Tensile spall strength, elastic-plastic transition, phase boundaries, and equation of state can be determined with small samples. Using thin samples (0.1 - 1.0 mm thick) as targets, high pressure gradients can be generated with relatively low pressures, resulting in high tensile strain rates (10^5 to 10^8 s-1). Free surface and interface velocities are recorded with point- and line-imaging VISARs. The flexible spatial and temporal pulse profiles of Trident, coupled with the use of laser-launched flyer plates, provides capabilities which complement experiments conducted using gas guns and tensile bars. These samples spalled at high strain rates will be compared with samples spalled at lower strain rates to elucidate mechanisms for the initiation and growth of spall.

  13. TRIDENT flyer plate Impact technique: comparison to gas gun plate impact technique

    SciTech Connect

    Koller, Darcie D; Gray, III, George T; Luo, Sheng-Nian

    2009-03-01

    This report describes the details of a series of plate impact experiments that were conducted on a gas gun in an effort to validate a new technique for plate impact using the TRIDENT laser to launch thin flyers. The diagnostics fielded were VISAR and identical samples and impactors were used on both platforms. All experimenters agree that the VISAR results should have agreed between the two experimental platforms. The VISAR results did not agree across the platforms and experimenters offer explanations and implications for this outcome.

  14. Drawing Mononuclear Octahedral Coordination Compounds Containing Tridentate Chelating Ligands

    ERIC Educational Resources Information Center

    Mohamadou, Aminou; Ple, Karen; Haudrechy, Arnaud

    2011-01-01

    Complexes with tridentate ligands of the type [M(A-B-C)2], where A [not equal to] B [not equal to] C and with an imposed bonding sequence A-B-C, require special attention to draw all possible stereoisomers. Depending on the nature of the central donor atom B of the tridentate ligand, an easy drawing method is presented that shows seven chiral…

  15. Laser-driven ion acceleration from relativistically transparent nanotargets

    NASA Astrophysics Data System (ADS)

    Hegelich, B. M.; Pomerantz, I.; Yin, L.; Wu, H. C.; Jung, D.; Albright, B. J.; Gautier, D. C.; Letzring, S.; Palaniyappan, S.; Shah, R.; Allinger, K.; Hörlein, R.; Schreiber, J.; Habs, D.; Blakeney, J.; Dyer, G.; Fuller, L.; Gaul, E.; Mccary, E.; Meadows, A. R.; Wang, C.; Ditmire, T.; Fernandez, J. C.

    2013-08-01

    Here we present experimental results on laser-driven ion acceleration from relativistically transparent, overdense plasmas in the break-out afterburner (BOA) regime. Experiments were preformed at the Trident ultra-high contrast laser facility at Los Alamos National Laboratory, and at the Texas Petawatt laser facility, located in the University of Texas at Austin. It is shown that when the target becomes relativistically transparent to the laser, an epoch of dramatic acceleration of ions occurs that lasts until the electron density in the expanding target reduces to the critical density in the non-relativistic limit. For given laser parameters, the optimal target thickness yielding the highest maximum ion energy is one in which this time window for ion acceleration overlaps with the intensity peak of the laser pulse. A simple analytic model of relativistically induced transparency is presented for plasma expansion at the time-evolving sound speed, from which these times may be estimated. The maximum ion energy attainable is controlled by the finite acceleration volume and time over which the BOA acts.

  16. Imaging X-ray crystal spectrometer for laser-produced plasmas

    NASA Astrophysics Data System (ADS)

    Gamboa, E. J.; Montgomery, D. S.; Hall, I. M.; Drake, R. P.

    2011-04-01

    X-ray Thomson scattering (XRTS) is a powerful technique for measuring state variables in dense plasmas. In this paper, we report on the development of a one-dimensional imaging spectrometer for use in characterizing spatially nonuniform, dense plasmas using XRTS. Diffraction of scattered x-rays from a toroidally curved crystal images along a one-dimensional spatial profile while simultaneously spectrally resolving along the other. An imaging spectrometer was fielded at the Trident laser at Los Alamos National Laboratory, yielding a FWHM spatial resolution of < 25 μm, spectral resolution of 4 eV, spectral range of 350 eV, and spatial range of > 3 mm. A geometrical analysis is performed yielding a simple analytical expression for the throughput of the imaging spectrometer scheme. The SHADOW code is used to perform a ray tracing analysis on the spectrometer fielded at the Trident Laser Facility understand the alignment tolerances on the spatial and spectral resolutions. The analytical expression for the throughput was found to agree well with the results from the ray tracing.

  17. Trident Technical College 1998 Graduate Follow-Up.

    ERIC Educational Resources Information Center

    Trident Technical Coll., Charleston, SC.

    Presents the results of South Carolina's Trident Technical College's (TTC's) 1998 graduate follow-up survey report of 915 TTC graduates. Graduates were surveyed and results were obtained for the following items: graduate goals, employment, placement rates, graduates in related fields, when job were obtained, job finding methods, job locations, job…

  18. Trident Technical College 1999 Graduate Follow-Up Report.

    ERIC Educational Resources Information Center

    Trident Technical Coll., Charleston, SC.

    Presents the results of South Carolina's Trident Technical College's (TTC's) 1999 graduate follow-up survey report. Graduates were surveyed and results were obtained for the following items: graduate goals, employment, placement rates, graduates in related fields, when job obtained, job finding methods, job locations, job satisfaction, job…

  19. Development of the Trident 1 aerodynamic saike mechanism

    NASA Technical Reports Server (NTRS)

    Waterman, M. D.; Richter, B. J.

    1979-01-01

    The Aerospike drag reduction mechanism was designed and developed for use on the Trident I submarine launched ballistic missile. This mechanism encounters a unique combination of environments necessitating unique design solutions to ensure satisfactory operation over its design life. The development of the Aerospike is reviewed emphasizing the unique and interesting problems encountered and their solutions.

  20. Stockpile Stewardship: Los Alamos

    SciTech Connect

    McMillan, Charlie; Morgan, Nathanial; Goorley, Tom; Merrill, Frank; Funk, Dave; Korzekwa, Deniece; Laintz, Ken

    2012-01-26

    "Heritage of Science" is a short video that highlights the Stockpile Stewardship program at Los Alamos National Laboratory. Stockpile Stewardship was conceived in the early 1990s as a national science-based program that could assure the safety, security, and effectiveness of the U.S. nuclear deterrent without the need for full-scale underground nuclear testing. This video was produced by Los Alamos National Laboratory for screening at the Lab's Bradbury Science Museum in Los Alamos, NM and is narrated by science correspondent Miles O'Brien.

  1. Stockpile Stewardship: Los Alamos

    ScienceCinema

    McMillan, Charlie; Morgan, Nathanial; Goorley, Tom; Merrill, Frank; Funk, Dave; Korzekwa, Deniece; Laintz, Ken

    2016-07-12

    "Heritage of Science" is a short video that highlights the Stockpile Stewardship program at Los Alamos National Laboratory. Stockpile Stewardship was conceived in the early 1990s as a national science-based program that could assure the safety, security, and effectiveness of the U.S. nuclear deterrent without the need for full-scale underground nuclear testing. This video was produced by Los Alamos National Laboratory for screening at the Lab's Bradbury Science Museum in Los Alamos, NM and is narrated by science correspondent Miles O'Brien.

  2. Structure, function, and cortical representation of the rat submandibular whisker trident.

    PubMed

    Thé, Lydia; Wallace, Michael L; Chen, Christopher H; Chorev, Edith; Brecht, Michael

    2013-03-13

    Although the neurobiology of rodent facial whiskers has been studied intensively, little is known about sensing in other vibrissae. Here we describe the under-investigated submandibular "whisker trident" on the rat's chin. In this three-whisker array, a unique unpaired midline whisker is laterally flanked by two slightly shorter whiskers. All three whiskers point to the ground and are curved backwards. Unlike other whiskers, the trident is not located on an exposed body part. Trident vibrissae are not whisked and do not touch anything over long stretches of time. However, trident whiskers engage in sustained ground contact during head-down running while the animal is exploring or foraging. In biomechanical experiments, trident whiskers follow caudal ground movement more smoothly than facial whiskers. Remarkably, deflection angles decrease with increasing ground velocity. We identified one putative trident barrel in the left somatosensory cortex and two barrels in the right somatosensory cortex. The elongated putative trident-midline barrel is the longest and largest whisker barrel, suggesting that the midline trident whisker is of great functional significance. Cortical postsynaptic air-puff responses in the trident representation show much less temporal precision than facial whisker responses. Trident whiskers do not provide as much high-resolution information about object contacts as facial whiskers. Instead, our observations suggest an idiothetic function: their biomechanics allow trident whiskers to derive continuous measurements about ego motion from ground contacts. The midline position offers unique advantages in sensing heading direction in a laterally symmetric manner. The changes in trident deflection angle with velocity suggest that trident whiskers might function as a tactile speedometer.

  3. Tracking Near-Earth Asteroids: A Trident Scholar Project

    NASA Astrophysics Data System (ADS)

    Campbell, D. T.; Katz-Stone, D. M.

    2000-05-01

    At the U. S. Naval Academy, the most elite students are given an opportunity to do a year-long research project. This "Trident Scholar" project teaches students about all aspects of research including writing and defending a research proposal as well as communicating results in a written paper, a poster display and an oral presentation. This Trident Scholar project employed the newly updated observatory at the U. S. Naval Academy. The scientific goal of this research focused upon tracking several near-earth asteroids (NEAs) in order to determine their orbits. In addition, lightcurves were observed for a subset of these NEAs in order to find their rotational periods and their general shapes. The poster presented here shows the scientific results of this project as well as the some of the insights this student has gained by doing his own research.

  4. Automatic Provenance Recording for Scientific Data using Trident

    NASA Astrophysics Data System (ADS)

    Simmhan, Y.; Barga, R.; van Ingen, C.

    2008-12-01

    Provenance is increasingly recognized as being critical to the understanding and reuse of scientific datasets. Given the rapid generation of scientific data from sensors and computational model results, it is not practical to manually record provenance for data and automated techniques for provenance capture are essential. Scientific workflows provide a framework for representing computational models and complex transformations of scientific data, and present a means for tracking the operations performed to derive a dataset. The Trident Scientific Workbench is a workflow system that natively incorporates provenance capture of data derived as part of the workflow execution. The applications used as part of a Trident workflow can execute on a remote computational cluster, such as a supercomputing center on in the Cloud, or on the local desktop of the researcher, and provenance on data derived by the applications is seamlessly captured. Scientists also have the option to annotate the provenance metadata using domain specific tags such as, for example, GCMD keywords. The provenance records thus captured can be exported in the Open Provenance Model* XML format that is emerging as a provenance standard in the eScience community or visualized as a graph of data and applications. The Trident workflow system and provenance recorded by it has been successfully applied in the Neptune oceanography project and is presently being tested in the Pan-STARRS astronomy project. *http://twiki.ipaw.info/bin/view/Challenge/OPM

  5. Strategic defense initiatives at Los Alamos National Laboratory

    SciTech Connect

    Rockwood, S.D.

    1985-01-01

    This presentation reviews the Strategic Defense Initiative (SDI) programs at Los Alamos National Laboratory, noting especially the needs for and applications of optics and optical technologies. Table I lists the various activities at Los Alamos contributing to SDI programs. The principal, nonnuclear SDI programs are: (1) the free-electron laser, and (2) neutral particle beams. Both should be considered as potential long-range-kill systems, but still in the futuristic category.

  6. Los Alamos offers Fellowships

    NASA Astrophysics Data System (ADS)

    Los Alamos National Laboratory in New Mexico is calling for applications for postdoctoral appointments and research fellowships. The positions are available in geoscience as well as other scientific disciplines.The laboratory, which is operated by the University of California for the Department of Energy, awards J. Robert Oppenheimer Research Fellowships to scientists that either have or will soon complete doctoral degrees. The appointments are for two years, are renewable for a third year, and carry a stipend of $51,865 per year. Potential applicants should send a resume or employment application and a statement of research goals to Carol M. Rich, Div. 89, Human Resources Development Division, MS P290, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 by mid-November.

  7. The Los Alamos primer

    SciTech Connect

    Serber, R.

    1992-01-01

    This book contains the 1943 lecture notes of Robert Serber. Serber was a protege of J. Robert Oppenheimer and member of the team that built the first atomic bomb - reveal what the Los Alamos scientists knew, and did not know, about the terrifying weapon they were building.

  8. Recent Trident Single Hot Spot Experiments: Evidence for kinetic effects, and observation of LDI cascade

    NASA Astrophysics Data System (ADS)

    Montgomery, D. S.

    2001-10-01

    Single hot spot experiments offer several unique opportunities for developing a quantitative understanding of laser-plasma instabilities. These include the ability to perform direct numerical simulations of the experiment due to the finite interaction volume, isolation of instabilities due to the nearly ideal laser intensity distribution, and observation of fine structure due to the very homogeneous plasma conditions. Recent experiments have been performed in the single hot spot regime^1 using the Trident laser, and have focused on the following issues. First, the intensity scaling of stimulated Raman scattering (SRS) for classically large damping regimes (kλ_D=0.35) was examined, and compared to classical SRS theory. SRS onset was observed at intensities much lower than expected (2 x 10^15 W/cm^2), from which non-classical damping is inferred. Second, scattering from a plasma wave was observed whose frequency and phase velocity are between an ion acoustic wave and an electron plasma wave^2. The presence of this wave cannot be explained by linear Landau theory, and it is shown to be consistent with a BGK-like mode due to electron trapping^3. These waves have been observed in past laser-plasma experiments, but were previously misinterpreted^4,5. Finally, Thomson scattering was used to probe plasma waves driven by SRS, and structure was observed in the scattered spectra consistent with multiple steps of the Langmuir decay instability. 1. D.S. Montgomery et al., Phys. Rev. Lett. 84, 678 (2000). 2. D.S. Montgomery et al., to appear in Phys. Rev. Lett. (2001). 3. J.P. Holloway and J.J. Dorning, Phys. Lett. 138, 279 (1989). 4. D.S. Montgomery et al., Phys. Plasmas 3, 1728 (1996). 5. J.A. Cobble et al., Phys. Plasmas 7, 323 (2000). Work performed under the auspices of the U.S. D.O.E. by LANL under contract no. W-7405-ENG-36

  9. Review of liquid metal heat pipe work at Los Alamos

    NASA Astrophysics Data System (ADS)

    Reid, Robert S.; Merrigan, Michael A.; Sena, J. Tom

    A survey of space-power related liquid metal heat pipe work at Los Alamos National Laboratory is presented. Heat pipe development at Los Alamos has been on-going since 1963. Heat pipes were initially developed for thermionic nuclear-electrical power production in space. Since then Los Alamos has developed liquid metal heat pipes for numerous applications related to high temperature systems in both the space and terrestrial environments. Some of these applications include thermionic electrical generators, thermoelectric energy conversion (both in-core and direct radiation), thermal energy storage, hypersonic vehicle leading edge cooling, and heat pipe vapor laser cells. Some of the work performed at Los Alamos has been documented in internal reports that are often little-known. A representative description and summary of progress in space-related liquid metal heat pipe technology is provided followed by a reference section citing sources where these works may be found.

  10. Review of liquid metal heat pipe work at Los Alamos

    SciTech Connect

    Reid, R.S.; Merrigan, M.A.; Sena, J.T. )

    1991-01-10

    A survey of space-power related liquid metal heat pipe work at Los Alamos National Laboratory is presented. Heat pipe development at Los Alamos has been on-going since 1963. Heat pipes were initially developed for thermionic nuclear-electrical power production in space. Since then Los Alamos has developed liquid metal heat pipes for numerous applications related to high temperature systems in both the space and terrestrial environments. Some of these applications include thermionic electrical generators, thermoelectric energy conversion (both in-core and direct radiation), thermal energy storage, hypersonic vehicle leading edge cooling, and heat pipe vapor laser cells. Some of the work performed at Los Alamos has been documented in internal reports that are often little-known. A representative description and summary of progress in space-related liquid metal heat pipe technology is provided followed by a reference section citing sources where these works may be found.

  11. Review of liquid metal heat pipe work at Los Alamos

    NASA Astrophysics Data System (ADS)

    Reid, Robert S.; Merrigan, Michael A.; Sena, J. Tom

    1991-01-01

    A survey of space-power related liquid metal heat pipe work at Los Alamos National Laboratory is presented. Heat pipe development at Los Alamos has been on-going since 1963. Heat pipes were initially developed for thermionic nuclear-electrical power production in space. Since then Los Alamos has developed liquid metal heat pipes for numerous applications related to high temperature systems in both the space and terrestrial environments. Some of these applications include thermionic electrical generators, thermoelectric energy conversion (both in-core and direct radiation), thermal energy storage, hypersonic vehicle leading edge cooling, and heat pipe vapor laser cells. Some of the work performed at Los Alamos has been documented in internal reports that are often little-known. A representative description and summary of progress in space-related liquid metal heat pipe technology is provided followed by a reference section citing sources where these works may be found.

  12. Review of liquid metal heat pipe work at Los Alamos

    NASA Astrophysics Data System (ADS)

    Reid, Robert S.; Merrigan, Michael A.; Sena, J. T.

    A survey of space-power related liquid metal heat pipe work at Los Alamos National Laboratory is presented. Heat pipe development at Los Alamos has been on-going since 1963. Heat pipes were initially developed for thermionic nuclear-electrical power production in space. Since then Los Alamos has developed liquid metal heat pipes for numerous applications related to high temperature systems in both the space and terrestrial environments. Some of these applications include thermionic electrical generators, thermoelectric energy conversion (both in-core and direct radiation), thermal energy storage, hypersonic vehicle leading edge cooling, and heat pipe vapor laser cells. Some of the work performed at Los Alamos has been documented in internal reports that are often little-known. A representative description and summary of progress in space-related liquid metal heat pipe technology is provided followed by reference section citing sources where these works may be found.

  13. Review of liquid metal heat pipe work at Los Alamos

    SciTech Connect

    Reid, R.S.; Merrigan, M.A.; Sena, J.T.

    1990-01-01

    A survey of space-power related liquid metal heat pipe work at Los Alamos National Laboratory is presented. Heat pipe development at Los Alamos has been on-going since 1963. Heat pipes were initially developed for thermionic nuclear-electrical power production in space. Since then Los Alamos has developed liquid metal heat pipes for numerous applications related to high temperature systems in both the space and terrestrial environments. Some of these applications include thermionic electrical generators, thermoelectric energy conversion (both in-core and direct radiation), thermal energy storage, hypersonic vehicle leading edge cooling, and heat pipe vapor laser cells. Some of the work performed at Los Alamos has been documented in internal reports that are often little-known. A representative description and summary of progress in space-related liquid metal heat pipe technology is provided followed by a reference section citing sources where these works may be found. 53 refs.

  14. Representation of egomotion in rat's trident and E-row whisker cortices.

    PubMed

    Chorev, Edith; Preston-Ferrer, Patricia; Brecht, Michael

    2016-10-01

    The whisker trident, a three-whisker array on the rat's chin, has been implicated in egomotion sensing and might function as a tactile speedometer. Here we study the cortical representation of trident whiskers and E-row whiskers in barrel cortex. Neurons identified in trident cortex of anesthetized animals showed sustained velocity-sensitive responses to ground motion. In freely moving animals, about two-thirds of the units in the trident and E-row whisker cortices were tuned to locomotion speed, a larger fraction of speed-tuned cells than in the somatosensory dysgranular zone. Similarly, more units were tuned to acceleration and showed sensitivity to turning in trident and E-row whisker cortices than in the dysgranular zone. Microstimulation in locomoting animals evoked small but significant speed changes, and such changes were larger in the trident and E-row whisker representations than in the dysgranular zone. Thus, activity in trident and E-row cortices represents egomotion information and influences locomotion behavior. PMID:27526205

  15. High speed optical and X-ray methods for evaluating laser-generated shock-wave in materials

    SciTech Connect

    Paisley, D.; Swift, D.

    2000-11-01

    Optical diagnostic techniques including interferometry, electronic streak photography, and transient x-ray diffraction are used to study the dynamic material response to shock loading by direct laser irradiation and impact by laser-launched plates. The Los Alamos Trident laser is one of several lasers that have been used to generate shocks of 10 Kbar to several Mbar in single crystal and polycrystalline materials. Incorporating optical velocity interferometry (line-VISAR and point-VISAR) with transient x-ray diffraction can provide a complete understanding of the dynamic material response to shock compression and release. Laser-launched flyer plates provide an ideal method to generate one-dimensional shocks in materials. The quality of the one-dimensionality of the launch and acceleration of plates is evaluated by line-imaging VISA.R. The line-imaging VISAR images the fringes along a line across the diameter of the plate. Each fringe maxima and minima provide acceleration and velocity information at the specific point on the plate. By varying the fringe constant number of fringes and fringe spacing on the plate, detailed experimental data can be obtained. For our experiments, most plates are 3-mm diameter and accelerated to 0.2-->6 km/sec.

  16. Lynx maritime radar in USN experiment Trident Warrior 2011

    NASA Astrophysics Data System (ADS)

    Dunkel, R.; Link, Z.; Verge, T.; Laue, J.

    2012-06-01

    General Atomics Aeronautical Systems Inc. (GA-ASI) participated in the joint naval experiment Trident Warrior 2011 at Combat Direction Systems Activity (CDSA), Dam Neck, Va., in July 2011. The goal was to introduce the Lynx® Multi-Mode Radar's new Maritime Wide Area Search (MWAS) mode and display a viable Unmanned Aircraft System (UAS) full kill chain solution for the naval environment. GA-ASI presented a manned platform, a Beechcraft Super King Air 200 modified with an operators console, Lynx Multi-mode Radar, FLIR Star SAFIRE 380-HD EO/IR camera system, and an L-3 TCDL (aircraft data link system) as a surrogate for the Predator® B/ MQ-9 UAS.

  17. Catalytic hydrogenation using complexes of base metals with tridentate ligands

    DOEpatents

    Vasudevan, Kalyan V.; Zhang, Guoqi; Hanson, Susan K.

    2016-09-06

    Complexes of cobalt and nickel with tridentate ligand PNHP.sup.R are effective for hydrogenation of unsaturated compounds. Cobalt complex [(PNHP.sup.Cy)Co(CH.sub.2SiMe.sub.3)]BAr.sup.F.sub.4 (PNHP.sup.Cy=bis[2-(dicyclohexylphosphino)ethyl]amine, BAr.sup.F.sub.4=B(3,5-(CF.sub.3).sub.2C.sub.6H.sub.3).sub.4)) was prepared and used with hydrogen for hydrogenation of alkenes, aldehydes, ketones, and imines under mild conditions (25-60.degree. C., 1-4 atm H.sub.2). Nickel complex [(PNHP.sup.Cy)Ni(H)]BPh.sub.4 was used for hydrogenation of styrene and 1-octene under mild conditions. (PNP.sup.Cy)Ni(H) was used for hydrogenating alkenes.

  18. Ultlra-intense laser-matter interactions at extreme parameters

    SciTech Connect

    Hegellich, Bjorn M

    2010-11-24

    The field of shortpulse lasers has seen rapid growth in the recent years with the three major boundaries of energy, pulse duration and repetition rate being pushed in ever extremer regions. At peak powers, already exceeding 10{sup 22} W/cm{sup 2}, in virtually every experiment in relativistic laser physics, the laser pulse interacts with a more or less extended and heated plasma, due to prepulses and ASE-like pedestals on ps - ns time scales. By developing a new technique for ultrahigh contrast, we were able to initiate the next paradigm shift in relativistic laser-matter interactions, allowing us to interact ultrarelativistic pulses volumetrically with overdense targets. This becomes possible by using target and laser parameters that will turn the target relativistically transparent during the few 10s-100s femtoseconds fo the interaction. Specifically, we interact an ultraintese, ultrahigh contrast pulse with solid density, free standing, nanometer diamond target. This paradigm change towards a volumetric overdense interaction in turn enables new particle acceleration mechanisms for both electrons and ions, as well as forward directed relativistic surface harmonics. We report here on first experiments done on those topics at the 200 TW Trident laser at Los Alamos as well as at the Ti:Sapphire system at MBI. We will compare the experimental data to massive large scale 3D simulations done on the prototype of LANL's new Petafiop supercomputer Roadrunner, which is leading the current top 500 list. Specifically, we developed a shortpulse OPA based pulse cleaning technique. Fielding it at the Trident 200 TW laser at Los Alamos, we were able to improve the pulse contrast by 6 orders of magnitude to better than 2 x 10{sup -12} at less than a ps. This enabled for the first time the interaction of a 100J, 200TW laser pulse with a truly solid target with virtually no expansion before the main pulse - target interaction, making possible the use of very thin targets, The

  19. Power beam technology at Los Alamos/A review of research and development activities

    SciTech Connect

    Casey, H.

    1990-01-01

    This document discusses techniques and research programs in power beam welding at Los Alamos National Laboratories. Specific areas discussed are in plasma welding, electron beam welding and laser welding. 11 refs., 9 figs. (FSD)

  20. Lasers.

    ERIC Educational Resources Information Center

    Schewe, Phillip F.

    1981-01-01

    Examines the nature of laser light. Topics include: (1) production and characteristics of laser light; (2) nine types of lasers; (3) five laser techniques including holography; (4) laser spectroscopy; and (5) laser fusion and other applications. (SK)

  1. Tridentate benzimidazole-pyridine-tetrazolates as sensitizers of europium luminescence.

    PubMed

    Shavaleev, Nail M; Eliseeva, Svetlana V; Scopelliti, Rosario; Bünzli, Jean-Claude G

    2014-05-19

    We report on new anionic tridentate benzimidazole-pyridine-tetrazolate ligands that form neutral 3:1 complexes with trivalent lanthanides. The ligands are UV-absorbing chromophores that sensitize the red luminescence of europium with energy-transfer efficiency of 74-100%. The lifetime and quantum yield of the sensitized europium luminescence increase from 0.5 ms and 12-13% for the as-prepared solids to 2.8 ms and 41% for dichloromethane solution. From analysis of the data, the as-prepared solids can be described as aqua-complexes [Ln(κ(3)-ligand)2(κ(1)-ligand)(H2O)x] where the coordinated water molecules are responsible for the strong quenching of the europium luminescence. In solution, the coordinated water molecules are replaced by the nitrogen atoms of the κ(1)-ligand to give anhydrous complexes [Ln(κ(3)-ligand)3] that exhibit efficient europium luminescence. X-ray structures of the anhydrous complexes confirm that the lanthanide ion (La(III), Eu(III)) is nine-coordinate in a distorted tricapped trigonal prismatic environment and that coordination of the lanthanide ion by tetrazolate is weaker than by carboxylate.

  2. Los Alamos National Laboratory

    SciTech Connect

    Dogliani, Harold O

    2011-01-19

    The purpose of the briefing is to describe general laboratory technical capabilities to be used for various groups such as military cadets or university faculty/students and post docs to recruit into a variety of Los Alamos programs. Discussed are: (1) development and application of high leverage science to enable effeictive, predictable and reliability outcomes; (2) deter, detect, characterize, reverse and prevent the proliferation of weapons of mass destruction and their use by adversaries and terrorists; (3) modeling and simulation to define complex processes, predict outcomes, and develop effective prevention, response, and remediation strategies; (4) energetic materials and hydrodynamic testing to develop materials for precise delivery of focused energy; (5) materials cience focused on fundamental understanding of materials behaviors, their quantum-molecular properties, and their dynamic responses, and (6) bio-science to rapidly detect and characterize pathogens, to develop vaccines and prophylactic remedies, and to develop attribution forensics.

  3. ASC platforms at Los Alamos.

    SciTech Connect

    Shaw, S. R.

    2004-01-01

    This talk describes the history, current state, and future plans for ASC computational and data storage service at Los Alamos. The of the systems and services described is limited to those installed in and managed by Group CCN-7.

  4. Los Alamos National Laboratory Overview

    SciTech Connect

    Neu, Mary

    2010-06-02

    Mary Neu, Associate Director for Chemistry, Life and Earth Sciences at Los Alamos National Laboratory, delivers opening remarks at the "Sequencing, Finishing, Analysis in the Future" meeting in Santa Fe, NM

  5. 33 CFR 334.600 - TRIDENT Basin adjacent to Canaveral Harbor at Cape Canaveral Air Force Station, Brevard County...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 33 Navigation and Navigable Waters 3 2011-07-01 2011-07-01 false TRIDENT Basin adjacent to... DANGER ZONE AND RESTRICTED AREA REGULATIONS § 334.600 TRIDENT Basin adjacent to Canaveral Harbor at Cape... at latitude 28°24′37″, longitude 80°35′26″ and the entire basin. (b) Regulations. (1) No...

  6. Creation of Pure Frozen Gas Targets for Ion Acceleration using Short Pulse Lasers

    NASA Astrophysics Data System (ADS)

    McCary, Edward; Stehr, Florian; Jiao, Xuejing; Quevedo, Hernan; Franke, Philip; Agustsson, Ronald; Oshea, Finn; Berry, Robert; Chao, Dennis; Woods, Kayley; Gautier, Donald; Letzring, Sam; Hegelich, Bjorn

    2015-11-01

    A system for shooting interchangeable frozen gas targets was developed at the University of Texas and will be tested at Los Alamos National Lab. A target holder which can hold up to five substrates used for target growing was cryogenically cooled to temperatures below 14 K. The target substrates consist of holes with diameters ranging from 15 μm-500 μm and TEM grids with micron scale spacing, across which films of ice are frozen by releasing small amounts of pure gas molecules directly into the vacuum target chamber. Frozen gas targets comprised of simple molecules like methane and single element gasses like hydrogen and deuterium will provide novel target configuations that will be compared with laser plasma interaction simulations. The targets will be shot with the ultra-intense short-pulse Trident laser. Accelerated ion spectra will be characterized using a Thomson Parabola with magnetic field strength of 0.92T and electric field strength of 30kV. Hydrogen targets will be additionally characterized using stacks of copper which become activated upon exposure to energetic protons resulting in a beta decay signal which be imaged on electron sensitive imaging plates to provide an energy spectrum and spacial profile of the proton beam. Details of target creation and pre-shot characterization will be presented.

  7. Tridentate hydrazone metal complexes derived from cephalexin and 2-hydrazinopyridine: Synthesis, characterization and antibacterial activity

    NASA Astrophysics Data System (ADS)

    Anacona, J. R.; Rincones, Maria

    2015-04-01

    Metal(II) coordination compounds of a tridentate hydrazone ligand (HL) derived from the condensation of cephalexin antibiotic with 2-hydrazinopyridine were synthesized. The hydrazone ligand and mononuclear [ML(OAc)(H2O)] (M(II) = Mn, Co, Ni, Cu, Zn, Ag) complexes were characterized by several techniques, including elemental and thermal analysis, molar conductance and magnetic susceptibility measurements, electronic, FT-IR, EPR and 1H NMR spectral studies. The cephalexin 2-pyridinylhydrazone ligand HL behaves as a monoanionic tridentate NNO chelating agent. The biological applications of complexes have been studied on three bacteria strains (Escherichia coli, Acinetobacter baumannii and Enterococcus faecalis) by agar diffusion disc method.

  8. A novel chiral yttrium complex with a tridentate linked amido-indenyl ligand for intramolecular hydroamination.

    PubMed

    Chai, Zhuo; Hua, Dezhi; Li, Kui; Chu, Jiang; Yang, Gaosheng

    2014-01-01

    A new chiral silicon-linked tridentate amido-indenyl ligand was developed from indene and enantiopure 1,2-cyclohexanediamine. Its yttrium complex was synthesized, characterized and applied to efficiently catalyze the intramolecular hydroamination of non-activated olefins with up to 97% ee.

  9. 77 FR 29620 - Notice of Availability of Record of Decision for TRIDENT Support Facilities Explosives Handling...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-05-18

    ... Department of the Navy Notice of Availability of Record of Decision for TRIDENT Support Facilities Explosives Handling Wharf at Naval Base Kitsap at Bangor, Kitsap County, WA AGENCY: Department of the Navy, DoD. ACTION: Notice. SUMMARY: The United States Department of the Navy (DoN), after carefully weighing...

  10. Ultra-High-Contrast Laser Acceleration of Relativistic Electrons in Solid Targets

    SciTech Connect

    Higginson, Drew Pitney

    2013-01-01

    The cone-guided fast ignition approach to Inertial Con nement Fusion requires laser-accelerated relativistic electrons to deposit kilojoules of energy within an imploded fuel core to initiate fusion burn. One obstacle to coupling electron energy into the core is the ablation of material, known as preplasma, by laser energy proceeding nanoseconds prior to the main pulse. This causes the laser-absorption surface to be pushed back hundreds of microns from the initial target surface; thus increasing the distance that electrons must travel to reach the imploded core. Previous experiments have shown an order of magnitude decrease in coupling into surrogate targets when intentionally increasing the amount of preplasma. Additionally, for electrons to deposit energy within the core, they should have kinetic energies on the order of a few MeV, as less energetic electrons will be stopped prior to the core and more energetic electrons will pass through the core without depositing much energy. Thus a quantitative understanding of the electron energy spectrum and how it responds to varied laser parameters is paramount for fast ignition. For the rst time, this dissertation quantitatively investigates the acceleration of electrons using an ultra-high-contrast laser. Ultra-high-contrast lasers reduce the laser energy that reaches the target prior to the main pulse; drastically reducing the amount of preplasma. Experiments were performed in a cone-wire geometry relevant to fast ignition. These experiments irradiated the inner-tip of a Au cone with the laser and observed electrons that passed through a Cu wire attached to the outer-tip of the cone. The total emission of K x-rays is used as a diagnostic to infer the electron energy coupled into the wire. Imaging the x-ray emission allowed an e ective path-length of electrons within the wire to be determined, which constrained the electron energy spectrum. Experiments were carried out on the ultra-high-contrast Trident laser at Los

  11. The Los Alamos high-brightness photoinjector

    SciTech Connect

    O'Shea, P.G.

    1991-01-01

    For a number of years Los Alamos National Laboratory has been developing photocathode RF guns for high-brightness electron beam applications such as free-electron lasers (FELs). Previously thermionic high-voltage guns have been the source of choice for the electron accelerators used to drive FELs. The performance of such FELs is severely limited by the emittance growth produced by the subharmonic bunching process and also by the low peak current of the source. In a photoinjector, a laser driven photocathode is placed directly in a high-gradient RF accelerating cavity. A photocathode allows unsurpassed control over the current, and the spatial and temporal profile of the beam. In addition the electrodeless emission'' avoids many of the difficulties associated with multi-electrode guns, i.e. the electrons are accelerated very rapidly to relativistic energies, and there are no electrodes to distort the accelerating fields. For the past two years we have been integrating a photocathode into our existing FEL facility by replacing our thermionic gun and subharmonic bunchers with a high-gradient 1.3 GHz photoinjector. The photoinjector, which is approximately 0.6 m in length, produces 6 MeV, 300 A, 15 ps linac, and accelerated to a final energy of 40 MeV. We have recently begun lasing at wavelengths near 3 {mu}m. 16 refs., 2 figs., 5 tabs.

  12. Los Alamos Critical Assemblies Facility

    SciTech Connect

    Malenfant, R.E.

    1981-06-01

    The Critical Assemblies Facility of the Los Alamos National Laboratory has been in existence for thirty-five years. In that period, many thousands of measurements have been made on assemblies of /sup 235/U, /sup 233/U, and /sup 239/Pu in various configurations, including the nitrate, sulfate, fluoride, carbide, and oxide chemical compositions and the solid, liquid, and gaseous states. The present complex of eleven operating machines is described, and typical applications are presented.

  13. Center takes hard line with press. The missing infant incident at Columbia Trident Medical Center.

    PubMed

    Moore, P L

    1997-01-01

    When the body of a stillborn infant went missing from the Columbia Trident morgue, the press pounced. The hospital was accused of everything from neglect to a police-protected cover-up. Reporters stopped patients in the parking lot to ask them if they felt safe. Others used the incident to question Columbia's proposed merger with the local university medical center. In response, Columbia Trident initiated a strict policy that prohibits the press from showing up unannounced and stridently protects the rights of patients and employees. The case provokes questions about the role of public relations professionals in an age of sensationalism. When is withholding information justified and when is it an obstruction of justified inquiry? How far is too far for the press? PMID:10165816

  14. Trident and MISTY: a universal pipeline for generating and sharing synthetic spectra

    NASA Astrophysics Data System (ADS)

    Hummels, Cameron; Smith, Britton; Silvia, Devin; Peeples, Molly; Prochaska, X.; Tejos, Nicolas

    2016-03-01

    Astrophysical simulations are useful insofar as they aid in the interpretation of telescopic observations. Thus, a primary task in simulation analysis is in producing synthetic observations for direct comparison against observational data. Furthermore, we as a field need an effective means for storing these synthetic observable data products, such that they are accessible and searchable by the entire population of researchers. In this talk, we present Trident, a universal pipeline for producing synthetic spectra from any of the major hydrodynamics codes, and MISTY, a means of storing these spectra on the HST MAST data archive. Trident and MISTY are our attempts to solve the difficult problems of synthetic data production and publicly-accessible storage for the scientific communities studying the intergalactic medium and circumgalactic medium.

  15. Synthesis of new tridentate 5-(arylazo) salicylaldimine ligands and their Cu (II) complexes

    NASA Astrophysics Data System (ADS)

    Abbas, Samir Y.; Basyouni, Wahid M.; El-Bayouki, Khairy A. M.

    2013-10-01

    New tridentate Schiff base ligands (H2L) were synthesized via condensation of 5-(arylazo)salicylaldehydes and 2-aminophenol or 2-aminothiophenol. When the new salicylaldimines were subjected to react with CuCl2 in the presence of N(Et)3 yield the new complexes. The structure of the metal complexes was established by microanalyses, IR, UV spectra and thermal analyses. The results suggest that the ligands were coordinated to the copper ion in tridentate manner with ONO (or ONS) donor sites of the deprotonated phenolic-OH, azomethine-N, and deprotonated phenolic-OH (or deprotonated thiophenolic-SH). Furthermore, one water molecule was coordinated to the central metal atom. The composition of complexes can be represented as CuLṡH2O.

  16. Charge-transfer luminescence from ruthenium(II) complexes containing tridentate ligands

    NASA Astrophysics Data System (ADS)

    Stone, M. L.; Crosby, G. A.

    Four complexes of the general formula Ru(NNN) 2+2 (N NN = tridentate N-heterocyclic ligand) were synthesized and studied spectroscopically. All exhibit visible absorption spectra that are charge-transfer-to-ligand in origin, are luminescent in glasses at 77 K, and display emission spectra that possess energies, structures, and decay tines that label them as charge transfer.

  17. The Max Rover submersible is tested at the Trident pier, Port Canaveral

    NASA Technical Reports Server (NTRS)

    1997-01-01

    Kennedy Space Center's Advanced Systems Development organization conducts a test of an unmanned robotic submersible to evaluate its ability to assist divers in the task of recovering spent solid rocket boosters (SRBs) in the Atlantic Ocean. NASA and contractor Deep Sea Systems of Falmouth, Mass., demonstrated the Max Rover submersible at Port Canaveral's Trident pier. The fact- finding tests are part of NASA's effort to make SRB recovery operations safer and less strenuous.

  18. Neutrino trident production: a powerful probe of new physics with neutrino beams.

    PubMed

    Altmannshofer, Wolfgang; Gori, Stefania; Pospelov, Maxim; Yavin, Itay

    2014-08-29

    The production of a μ+ μ- pair from the scattering of a muon neutrino off the Coulomb field of a nucleus, known as neutrino trident production, is a subweak process that has been observed in only a couple of experiments. As such, we show that it constitutes an exquisitely sensitive probe in the search for new neutral currents among leptons, putting the strongest constraints on well-motivated and well-hidden extensions of the standard model gauge group, including the one coupled to the difference of the lepton number between the muon and tau flavor, Lμ-Lτ. The new gauge boson Z', increases the rate of neutrino trident production by inducing additional (μγαμ)(νγ(α)ν) interactions, which interfere constructively with the standard model contribution. Existing experimental results put significant restrictions on the parameter space of any model coupled to muon number Lμ, and disfavor a putative resolution to the muon g-2 discrepancy via the loop of Z' for any mass mZ'≳400  MeV. The reach to the models' parameter space can be widened with future searches of the trident production at high-intensity neutrino facilities such as the LBNE. PMID:25215977

  19. Los Alamos Science: Number 16

    SciTech Connect

    Cooper, N.G.

    1988-01-01

    It was an unusually stimulating day and a half at Los Alamos when two Nobel Laureates in physiology, a leading paleontologist, and a leading bio-astrophysicist came together to discuss ''Unsolved Problems in the Science of Life,'' the topic of the second in a series of special meetings sponsored by the Fellows of the Laboratory. Just like the first one on ''Creativity in Science,'' this colloquium took us into a broader arena of ideas and viewpoints than is our usual daily fare. To contemplate the evolution and mysteries of intelligent life from the speakers' diverse points of view at one time, in one place was indeed a rare experience.

  20. Eruption of Trident Volcano, Katmai National Monument, Alaska, February-June 1953

    USGS Publications Warehouse

    Snyder, George L.

    1954-01-01

    Trident Volcano, one of several 'extinct' volcanoes in Katmai National Monument, erupted on February 15, 1953. Observers in a U. S. Navy plane, 50 miles away, and in King Salmon, 75 miles away, reported an initial column of smoke that rose to an estimated 30, 000 feet. Thick smoke and fog on the succeeding 2 days prevented observers from identifying the erupting volcano or assessing the severity of the eruption. It is almost certain, however, that during the latter part of this foggy period, either Mount Martin or Mount Mageik, or both, were also erupting sizable ash clouds nearby. The first close aerial observations were made in clear weather on February 18. At this time a thick, blocky lava flow was seen issuing slowly from a new vent at an altitude of 3,600 feet on the southwest flank of Trident Volcano. Other volcanic orifices in the area were only steaming mildly on this and succeeding days. Observations made in the following weeks from Naval aircraft patrolling the area indicated that both gas and ash evolution and lava extrusion from the Trident vent were continuing without major interruption. By March 11 an estimated 80-160 million cubic yards of rock material had been extruded. Air photographs taken in April and June show that the extrusion of lava had continued intermittently and, by June 17, the volume of the pile was perhaps 300-400 million cubic yards of rock material. Ash eruptions also apparently occurred sporadically during this period, the last significant surge taking place June 30. No civilian or military installations have been endangered by this eruption at the date of writing.

  1. Synthesis and characterisation of nonclassical ruthenium hydride complexes containing chelating bidentate and tridentate phosphine ligands.

    PubMed

    Prechtl, Martin H G; Ben-David, Yehoshoa; Giunta, Daniela; Busch, Stefan; Taniguchi, Yuki; Wisniewski, Wolfgang; Görls, Helmar; Mynott, Richard J; Theyssen, Nils; Milstein, David; Leitner, Walter

    2007-01-01

    The synthesis and characterisation of nonclassical ruthenium hydride complexes containing bidentate PP and tridentate PCP and PNP pincer-type ligands are described. The mononuclear and dinuclear ruthenium complexes presented have been synthesised in moderate to high yields by the direct hydrogenation route (one-pot synthesis) or in a two-step procedure. In both cases [Ru(cod)(metallyl)(2)] served as a readily available precursor. The influences of the coordination geometry and the ligand framework on the structure, binding, and chemical properties of the M--H(2) fragments were studied by X-ray crystal structure analysis, spectroscopic methods, and reactivity towards N(2), D(2), and deuterated solvents.

  2. Los Alamos opacity web page

    SciTech Connect

    Magee, N.H. Jr.; Clark, R.E.H.

    1998-02-01

    The Los Alamos opacity data base is now available on the World Wide Web at http://t4.lanl.gov. The data base contains both the original Astrophysical Opacity Library distributed worldwide in the 1980`s (for historical reference) and the new improved opacities from the Light Element Detailed Configuration OPacity (LEDCOP) code. Users can access the opacity data using the multigroup opacity code TOPS to obtain Rosseland and Planck gray opacities, group mean opacities over selected energy ranges, the monochromatic absorption coefficients and the average ionization over a wide range of temperatures and densities. As described in this paper, these quantities are available for all of the elements presently on the data base and TOPS will provide the same quantities for any arbitrary mixture of these elements.

  3. Los Alamos PC estimating system

    SciTech Connect

    Stutz, R.A.; Lemon, G.D.

    1987-01-01

    The Los Alamos Cost Estimating System (QUEST) is being converted to run on IBM personal computers. This very extensive estimating system is capable of supporting cost estimators from many different and varied fields. QUEST does not dictate any fixed method for estimating. QUEST supports many styles and levels of detail estimating. QUEST can be used with or without data bases. This system allows the estimator to provide reports based on levels of detail defined by combining work breakdown structures. QUEST provides a set of tools for doing any type of estimate without forcing the estimator to use any given method. The level of detail in the estimate can be mixed based on the amount of information known about different parts of the project. The system can support many different data bases simultaneously. Estimators can modify any cost in any data base.

  4. Availability of ground water in the area surrounding the Trident submarine construction facility, Kitsap County, Washington

    USGS Publications Warehouse

    Hansen, Arnold J.; Molenaar, Dee

    1976-01-01

    General information is presented on water resources--with emphasis on ground-water occurrence and availability--in that part of Kitsap County (referred to as Trident Impact Area) that would be most affected by the development of the Trident submarine construction facility at Bangor, Washington. The estimated 1970 water use in the study area averaged about 13 million gallons per day (mgd); of this amount about 9 mgd came from surface-water sources--from a large reservoir outside the study area--and about 4 mgd came from ground water pumped from two aquifers in the area. Anticipated water use soon will be about 18 to 21 mgd; virtually all the additional quantity required (about 5 to 8 mgd) above present use must come from ground-water sources. Preliminary evaluation of the aquifers suggests that an additional 1.5 mgd can be developed from the upper aquifer and 7 mgd from the lower aquifer. Existing wells tapping the lower aquifer might yield additional water and increase the total yield in the area by 3.5 mgd, and new wells drilled in selected areas could produce an additional 3.5 mgd from this aquifer. However, additional, large-scale ground-water withdrawal from the lower aquifer could induce saltwater intrusion into wells situated in coastal areas. (Woodard-USGS)

  5. [Lasers].

    PubMed

    Passeron, T

    2012-11-01

    Lasers are a very effective approach for treating many hyperpigmented lesions. They are the gold standard treatment for actinic lentigos and dermal hypermelanocytosis, such as Ota nevus. Becker nevus, hyperpigmented mosaicisms, and lentigines can also be successfully treated with lasers, but they could be less effective and relapses can be observed. However, lasers cannot be proposed for all types of hyperpigmentation. Thus, freckles and café-au-lait macules should not be treated as the relapses are nearly constant. Due to its complex pathophysiology, melasma has a special place in hyperpigmented dermatoses. Q-switched lasers (using standard parameters or low fluency) should not be used because of consistent relapses and the high risk of post-inflammatory hyperpigmentation. Paradoxically, targeting the vascular component of the melasma lesion with lasers could have a beneficial effect. However, these results have yet to be confirmed. In all cases, a precise diagnosis of the type of hyperpigmentation is mandatory before any laser treatment, and the limits and the potential side effects of the treatment must be clearly explained to patients.

  6. Lasers.

    PubMed

    Passeron, T

    2012-12-01

    Lasers are a very effective approach for treating many hyperpigmented lesions. They are the gold standard treatment for actinic lentigos and dermal hypermelanocytosis, such as Ota nevus. Becker nevus, hyperpigmented mosaicisms, and lentigines can also be successfully treated with lasers, but they could be less effective and relapses can be observed. However, lasers cannot be proposed for all types of hyperpigmentation. Thus, freckles and café-au-lait macules should not be treated as the relapses are nearly constant. Due to its complex pathophysiology, melasma has a special place in hyperpigmented dermatoses. Q-switched lasers (using standard parameters or low fluency) should not be used because of consistent relapses and the high risk of post-inflammatory hyperpigmentation. Paradoxically, targeting the vascular component of the melasma lesion with lasers could have a beneficial effect. However, these results have yet to be confirmed. In all cases, a precise diagnosis of the type of hyperpigmentation is mandatory before any laser treatment, and the limits and the potential side effects of the treatment must be clearly explained to patients.

  7. Sunset at the ALaMO

    NASA Video Gallery

    A new color all-sky camera has opened its eyes at the ALaMO, or Automated Lunar and Meteor Observatory, at NASA's Marshall Space Flight Center in Huntsville, Ala. Watch its inaugural video below, s...

  8. Publications of Los Alamos research 1988

    SciTech Connect

    Varjabedian, K.; Dussart, S.A.; McClary, W.J.; Rich, J.A.

    1989-12-01

    This bibliography lists unclassified publications of work done at the Los Alamos National Laboratory for 1988. The entries, which are subdivided by broad subject categories, are cross-referenced with an author index and a numeric index.

  9. New Rad Lab for Los Alamos

    SciTech Connect

    2008-08-06

    The topping out ceremony for a key construction stage in the Los Alamos National Laboratory's newest facility, the Radiological Laboratory Utility & Office Building. This is part of the National Nu...  

  10. Environmental surveillance at Los Alamos during 1994

    SciTech Connect

    1996-07-01

    This report describes environmental monitoring activities at Los Alamos National Laboratory for 1994. Data were collected to assess external penetrating radiation, airborne emissions, liquid effluents, radioactivity of environmental materials and food stuffs, and environmental compliance.

  11. New Rad Lab for Los Alamos

    ScienceCinema

    None

    2016-07-12

    The topping out ceremony for a key construction stage in the Los Alamos National Laboratory's newest facility, the Radiological Laboratory Utility & Office Building. This is part of the National Nu...  

  12. Edward Teller Returns to LOS Alamos

    NASA Astrophysics Data System (ADS)

    Hecker, Siegfried S.

    2010-01-01

    I was asked to share some reflections of Edward Teller's return to Los Alamos during my directorship. I met Teller late in his life. My comments focus on that time and they will be mostly in the form of stories of my interactions and those of my colleagues with Teller. Although the focus of this symposium is on Teller's contributions to science, at Los Alamos it was never possible to separate Teller's science from policy and controversy ...

  13. Internship at Los Alamos National Laboratory

    SciTech Connect

    Dunham, Ryan Q.

    2012-07-11

    Los Alamos National Laboratory (LANL) is located in Los Alamos, New Mexico. It provides support for our country's nuclear weapon stockpile as well as many other scientific research projects. I am an Undergraduate Student Intern in the Systems Design and Analysis group within the Nuclear Nonproliferation division of the Global Security directorate at LANL. I have been tasked with data analysis and modeling of particles in a fluidized bed system for the capture of carbon dioxide from power plant flue gas.

  14. Los Alamos Space Weather Summer School

    NASA Astrophysics Data System (ADS)

    Koller, J.

    2011-12-01

    Los Alamos National Lab recently initiated a new summer school specializing on space science, space weather, and instrumentation. The school is geared towards graduate level students and has been established to bring graduate students together with internationally recognized scientists at the Los Alamos National Lab. Students are receiving a prestigious Vela Fellowship to cover relocation expenses and cost of living for the duration of their stay in Los Alamos. For two months students have the opportunity to attend science lectures given by distinguished researchers at LANL. Topics are related to space weather research including plasma physics, radiation belts, numerical modeling, solar wind physics, spacecraft charging, and instrumentation. Students are also working closely with a Los Alamos mentor on exciting space weather science topics with access to Los Alamos GPS and geosynchronous data. The summer school concludes with project presentations by the students in a technical forum. The program is designed for graduate students currently enrolled at US Universities and open to all nationalities. We are presenting an overview of this exciting new program funded by IGPP (Institute of Geophysics and Planetary Physics), the Global Security Directorate, and the Directorate for Science, Technology and Engineering at Los Alamos National Lab.

  15. 33 CFR 334.600 - TRIDENT Basin adjacent to Canaveral Harbor at Cape Canaveral Air Force Station, Brevard County...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Canaveral Harbor at Cape Canaveral Air Force Station, Brevard County, Fla.; danger zone. 334.600 Section 334... DANGER ZONE AND RESTRICTED AREA REGULATIONS § 334.600 TRIDENT Basin adjacent to Canaveral Harbor at Cape Canaveral Air Force Station, Brevard County, Fla.; danger zone. (a) The danger zone. From the west side...

  16. The Max Rover submersible is tested at the Trident pier, Port Canaveral

    NASA Technical Reports Server (NTRS)

    1997-01-01

    Technicians lower the unmanned robotic submersible recovery system, known as Max Rover, into the water at the Trident Pier at Port Canaveral during a test of the system. Kennedy Space Center's solid rocket booster (SRB) retrieval team and Advanced Systems Development laboratory staff hope that the new robotic technology will make the process of inserting the Diver Operated Plug (DOP) into the aft nozzle of a spent SRB safer and less strenuous. Currently, scuba divers manually insert the DOP into the aft nozzle of a jettisoned SRB 60 to 70 feet below the surface of the Atlantic Ocean. After the plug is installed, water is pumped out of the booster allowing it to float horizontally. It is then towed back to Hangar AF at Cape Canaveral Air Station. Deep Sea Systems of Falmouth, Mass., built the submersible for NASA.

  17. The Max Rover submersible is tested at the Trident pier, Port Canaveral

    NASA Technical Reports Server (NTRS)

    1997-01-01

    A scuba diver stands by as the unmanned Max Rover submersible goes down to insert a Diver Operated Plug (DOP) into an aft nozzle like the ones used on the Space Shuttle's solid rocket boosters (SRBs). NASA and contractor Deep Sea Systems demonstrated the submersible at Port Canaveral's Trident pier. Kennedy Space Center's SRB retrieval team and Advanced Systems Development laboratory staff hope that the new robotic technology will make the process of inserting the plug into spent SRBs safer and less strenuous. Currently, scuba divers manually insert the DOP into the aft nozzle of a jettisoned SRB 60 to 70 feet below the surface of the Atlantic Ocean. After the plug is installed, water is pumped out of the booster allowing it to float horizontally. It is then towed back to Hangar AF at Cape Canaveral Air Station for refurbishment. Deep Sea Systems of Falmouth, Mass., built the submersible for NASA.

  18. The Max Rover submersible is tested at the Trident pier, Port Canaveral

    NASA Technical Reports Server (NTRS)

    1997-01-01

    As scuba divers stand by, a Diver Operated Plug (DOP) is lowered into the water at the Trident Pier at Port Canaveral during a test of the unmanned robotic submersible recovery system, known as Max Rover. Kennedy Space Center's solid rocket booster (SRB) retrieval team and Advanced Systems Development laboratory staff hope that the new robotic technology will make the process of inserting the plug into spent SRBs safer and less strenuous. Currently, scuba divers manually insert the DOP into the aft nozzle of a jettisoned SRB 60 to 70 feet below the surface of the Atlantic Ocean. After the plug is installed, water is pumped out of the booster allowing it to float horizontally. It is then towed back to Hangar AF at Cape Canaveral Air Station for refurbishment. Deep Sea Systems of Falmouth, Mass., built the submersible for NASA.

  19. Synthesis, spectroscopy, electrochemistry and thermal study of vanadyl tridentate Schiff base complexes

    NASA Astrophysics Data System (ADS)

    Kianfar, Ali Hossein; Paliz, Marzeh; Roushani, Mahmoud; Shamsipur, Mojtaba

    2011-11-01

    The VO(IV) complexes of tridentate ONO Schiff ligands were synthesised and characterized by IR, UV-vis and elemental analysis. The electrochemical properties of the vanadyl complexes were investigated by cyclic voltammetry. A good correlation was observed between the oxidation potentials and the electron withdrawing character of the substituents on the Schiff base ligands, showing the following trend: MeO < H < Br < NO 2 and H < Cl. The thermogravimetry (TG) and differential thermoanalysis (DTA) of the VO(IV) complexes were carried out in the range of 20-700 °C. The VOL 1(OH 2) decomposed in two steps whereas the remaining six complexes decomposed in three steps. The thermal decomposition of these complexes is closely related to the nature of the Schiff base ligands and proceeds via first order kinetics.

  20. The Los Alamos suite of relativistic atomic physics codes

    SciTech Connect

    Fontes, C. J.; Zhang, H. L.; Jr, J. Abdallah; Clark, R. E. H.; Kilcrease, D. P.; Colgan, J.; Cunningham, R. T.; Hakel, P.; Magee, N. H.; Sherrill, M. E.

    2015-05-28

    The Los Alamos SuitE of Relativistic (LASER) atomic physics codes is a robust, mature platform that has been used to model highly charged ions in a variety of ways. The suite includes capabilities for calculating data related to fundamental atomic structure, as well as the processes of photoexcitation, electron-impact excitation and ionization, photoionization and autoionization within a consistent framework. These data can be of a basic nature, such as cross sections and collision strengths, which are useful in making predictions that can be compared with experiments to test fundamental theories of highly charged ions, such as quantum electrodynamics. The suite can also be used to generate detailed models of energy levels and rate coefficients, and to apply them in the collisional-radiative modeling of plasmas over a wide range of conditions. Such modeling is useful, for example, in the interpretation of spectra generated by a variety of plasmas. In this work, we provide a brief overview of the capabilities within the Los Alamos relativistic suite along with some examples of its application to the modeling of highly charged ions.

  1. The Los Alamos suite of relativistic atomic physics codes

    DOE PAGES

    Fontes, C. J.; Zhang, H. L.; Jr, J. Abdallah; Clark, R. E. H.; Kilcrease, D. P.; Colgan, J.; Cunningham, R. T.; Hakel, P.; Magee, N. H.; Sherrill, M. E.

    2015-05-28

    The Los Alamos SuitE of Relativistic (LASER) atomic physics codes is a robust, mature platform that has been used to model highly charged ions in a variety of ways. The suite includes capabilities for calculating data related to fundamental atomic structure, as well as the processes of photoexcitation, electron-impact excitation and ionization, photoionization and autoionization within a consistent framework. These data can be of a basic nature, such as cross sections and collision strengths, which are useful in making predictions that can be compared with experiments to test fundamental theories of highly charged ions, such as quantum electrodynamics. The suitemore » can also be used to generate detailed models of energy levels and rate coefficients, and to apply them in the collisional-radiative modeling of plasmas over a wide range of conditions. Such modeling is useful, for example, in the interpretation of spectra generated by a variety of plasmas. In this work, we provide a brief overview of the capabilities within the Los Alamos relativistic suite along with some examples of its application to the modeling of highly charged ions.« less

  2. Synthesis, Characterization, Anticancer, and Antioxidant Studies of Ru(III) Complexes of Monobasic Tridentate Schiff Bases

    PubMed Central

    Ejidike, Ikechukwu P.

    2016-01-01

    Mononuclear Ru(III) complexes of the type [Ru(LL)Cl2(H2O)] (LL = monobasic tridentate Schiff base anion: (1Z)-N′-(2-{(E)-[1-(2,4-dihydroxyphenyl)ethylidene]amino}ethyl)-N-phenylethanimidamide [DAE], 4-[(1E)-N-{2-[(Z)-(4-hydroxy-3-methoxybenzylidene)amino]ethyl}ethanimidoyl]benzene-1,3-diol [HME], 4-[(1E)-N-{2-[(Z)-(3,4-dimethoxybenzylidene)amino]ethyl}ethanimidoyl]benzene-1,3-diol [MBE], and N-(2-{(E)-[1-(2,4-dihydroxyphenyl)ethylidene]amino}ethyl)benzenecarboximidoyl chloride [DEE]) were synthesized and characterized using the microanalytical, conductivity measurements, electronic spectra, and FTIR spectroscopy. IR spectral studies confirmed that the ligands act as tridentate chelate coordinating the metal ion through the azomethine nitrogen and phenolic oxygen atom. An octahedral geometry has been proposed for all Ru(III)-Schiff base complexes. In vitro anticancer studies of the synthesized complexes against renal cancer cells (TK-10), melanoma cancer cells (UACC-62), and breast cancer cells (MCF-7) was investigated using the Sulforhodamine B assay. [Ru(DAE)Cl2(H2O)] showed the highest activity with IC50 valves of 3.57 ± 1.09, 6.44 ± 0.38, and 9.06 ± 1.18 μM against MCF-7, UACC-62, and TK-10, respectively, order of activity being TK-10 < UACC-62 < MCF-7. The antioxidant activity by DPPH and ABTS inhibition assay was also examined. Scavenging ability of the complexes on DPPH radical can be ranked in the following order: [Ru(DEE)Cl2(H2O)] > [Ru(HME)Cl2(H2O)] > [Ru(DAE)Cl2(H2O)] > [Ru(MBE)Cl2(H2O)]. PMID:27597814

  3. Synthesis, Characterization, Anticancer, and Antioxidant Studies of Ru(III) Complexes of Monobasic Tridentate Schiff Bases

    PubMed Central

    Ejidike, Ikechukwu P.

    2016-01-01

    Mononuclear Ru(III) complexes of the type [Ru(LL)Cl2(H2O)] (LL = monobasic tridentate Schiff base anion: (1Z)-N′-(2-{(E)-[1-(2,4-dihydroxyphenyl)ethylidene]amino}ethyl)-N-phenylethanimidamide [DAE], 4-[(1E)-N-{2-[(Z)-(4-hydroxy-3-methoxybenzylidene)amino]ethyl}ethanimidoyl]benzene-1,3-diol [HME], 4-[(1E)-N-{2-[(Z)-(3,4-dimethoxybenzylidene)amino]ethyl}ethanimidoyl]benzene-1,3-diol [MBE], and N-(2-{(E)-[1-(2,4-dihydroxyphenyl)ethylidene]amino}ethyl)benzenecarboximidoyl chloride [DEE]) were synthesized and characterized using the microanalytical, conductivity measurements, electronic spectra, and FTIR spectroscopy. IR spectral studies confirmed that the ligands act as tridentate chelate coordinating the metal ion through the azomethine nitrogen and phenolic oxygen atom. An octahedral geometry has been proposed for all Ru(III)-Schiff base complexes. In vitro anticancer studies of the synthesized complexes against renal cancer cells (TK-10), melanoma cancer cells (UACC-62), and breast cancer cells (MCF-7) was investigated using the Sulforhodamine B assay. [Ru(DAE)Cl2(H2O)] showed the highest activity with IC50 valves of 3.57 ± 1.09, 6.44 ± 0.38, and 9.06 ± 1.18 μM against MCF-7, UACC-62, and TK-10, respectively, order of activity being TK-10 < UACC-62 < MCF-7. The antioxidant activity by DPPH and ABTS inhibition assay was also examined. Scavenging ability of the complexes on DPPH radical can be ranked in the following order: [Ru(DEE)Cl2(H2O)] > [Ru(HME)Cl2(H2O)] > [Ru(DAE)Cl2(H2O)] > [Ru(MBE)Cl2(H2O)].

  4. Synthesis, Characterization, Anticancer, and Antioxidant Studies of Ru(III) Complexes of Monobasic Tridentate Schiff Bases.

    PubMed

    Ejidike, Ikechukwu P; Ajibade, Peter A

    2016-01-01

    Mononuclear Ru(III) complexes of the type [Ru(LL)Cl2(H2O)] (LL = monobasic tridentate Schiff base anion: (1Z)-N'-(2-{(E)-[1-(2,4-dihydroxyphenyl)ethylidene]amino}ethyl)-N-phenylethanimidamide [DAE], 4-[(1E)-N-{2-[(Z)-(4-hydroxy-3-methoxybenzylidene)amino]ethyl}ethanimidoyl]benzene-1,3-diol [HME], 4-[(1E)-N-{2-[(Z)-(3,4-dimethoxybenzylidene)amino]ethyl}ethanimidoyl]benzene-1,3-diol [MBE], and N-(2-{(E)-[1-(2,4-dihydroxyphenyl)ethylidene]amino}ethyl)benzenecarboximidoyl chloride [DEE]) were synthesized and characterized using the microanalytical, conductivity measurements, electronic spectra, and FTIR spectroscopy. IR spectral studies confirmed that the ligands act as tridentate chelate coordinating the metal ion through the azomethine nitrogen and phenolic oxygen atom. An octahedral geometry has been proposed for all Ru(III)-Schiff base complexes. In vitro anticancer studies of the synthesized complexes against renal cancer cells (TK-10), melanoma cancer cells (UACC-62), and breast cancer cells (MCF-7) was investigated using the Sulforhodamine B assay. [Ru(DAE)Cl2(H2O)] showed the highest activity with IC50 valves of 3.57 ± 1.09, 6.44 ± 0.38, and 9.06 ± 1.18 μM against MCF-7, UACC-62, and TK-10, respectively, order of activity being TK-10 < UACC-62 < MCF-7. The antioxidant activity by DPPH and ABTS inhibition assay was also examined. Scavenging ability of the complexes on DPPH radical can be ranked in the following order: [Ru(DEE)Cl2(H2O)] > [Ru(HME)Cl2(H2O)] > [Ru(DAE)Cl2(H2O)] > [Ru(MBE)Cl2(H2O)]. PMID:27597814

  5. Los Alamos Guns Take Aim at Material's Mysteries

    SciTech Connect

    Byers, Mark; Moore, David; Dimarino, Steve

    2014-04-14

    Los Alamos National Laboratory scientists and technicians conduct thousands of experiments a year, delving into the fundamental nature of everything from supernovas to subatomic particles. One set of instruments used to better understand the fundamental nature of various materials are 10 scientific gun systems that fire various projectiles at high-tech targets to create enormous velocities, pressures, and temperatures - and using laser, x-ray, and other diagnostics - explore the very nature of metals and other materials. The hundreds of gun-based experiments conducted every year at the Laboratory require a highly-skilled staff of scientists and technicians, and has given rise to a special organization called the "gun working group" to foster open communications, cooperation, problem-solving, and a healthy safety culture.

  6. Los Alamos Guns Take Aim at Material's Mysteries

    ScienceCinema

    Byers, Mark; Moore, David; Dimarino, Steve

    2016-07-12

    Los Alamos National Laboratory scientists and technicians conduct thousands of experiments a year, delving into the fundamental nature of everything from supernovas to subatomic particles. One set of instruments used to better understand the fundamental nature of various materials are 10 scientific gun systems that fire various projectiles at high-tech targets to create enormous velocities, pressures, and temperatures - and using laser, x-ray, and other diagnostics - explore the very nature of metals and other materials. The hundreds of gun-based experiments conducted every year at the Laboratory require a highly-skilled staff of scientists and technicians, and has given rise to a special organization called the "gun working group" to foster open communications, cooperation, problem-solving, and a healthy safety culture.

  7. Gas geothermometry for typical and atypical hydrothermal gases: A case study of Mount Mageik and Trident Volcanoes, Alaska

    NASA Astrophysics Data System (ADS)

    Taryn, Lopez; Tassi, Franco; Capecchiacci, Francesco; Chiodini, Giovanni; Fiebig, Jens; Rizzo, Andrea; Caliro, Stefano

    2016-04-01

    The chemical and isotopic composition of volcanic gases can be used to detect subsurface magma, qualitatively constrain magma degassing depth, evaluate temperature and pressure conditions of hydrothermal reservoirs, and constrain volatile sources, all of which are important for volcano monitoring, eruption forecasting and hazard mitigation. Two persistently degassing and seismically active volcanoes from the Katmai Volcanic Complex, Alaska, were targeted during this study to characterize subvolcanic conditions. Fumarole and steam condensate samples were collected for chemical and isotopic analysis from Mount Mageik and Trident Volcanoes in July 2013. These volcanoes are located within 10 km of each other, both show evidence for active hydrothermal systems, and both have boiling point temperature fumaroles, yet emit notably different gas compositions. Mount Mageik's gases are composed primarily of H20, CO2, H2S, and N2, with minor CH4, CO and H2 and negligible HCl amounts, reflecting a typical "hydrothermal" gas composition. Although, Trident's gases are somewhat similar in composition to those of Mount Mageik, they show several unusual features for hydrothermal fluids, most notably extremely high concentrations of reduced gas species. Specifically, the H2/H2O values are ≈1 log-unit lower (i.e. more reducing) than those produced by the rock redox buffers commonly dominating in a hydrothermal environment. These anomalous ratios are accompanied by relatively high concentrations high-temperature (CO, and H2S), and low temperature (CH4) gases, suggesting a strong chemical disequilibrium and/or chemical-physical conditions far from those typically acting on hydrothermal fluids. Additionally, when δ13C ratios of methane, ethane and propane are considered, a deviation from the expected "hydrothermal" carbon number trend is observed for Trident volcano, suggesting an "abiogenic reversal". Gas geothermometry in the H2O-CO2-H2-CO-CH4 system provides estimated temperatures

  8. Status of Monte Carlo at Los Alamos

    SciTech Connect

    Thompson, W.L.; Cashwell, E.D.

    1980-01-01

    At Los Alamos the early work of Fermi, von Neumann, and Ulam has been developed and supplemented by many followers, notably Cashwell and Everett, and the main product today is the continuous-energy, general-purpose, generalized-geometry, time-dependent, coupled neutron-photon transport code called MCNP. The Los Alamos Monte Carlo research and development effort is concentrated in Group X-6. MCNP treats an arbitrary three-dimensional configuration of arbitrary materials in geometric cells bounded by first- and second-degree surfaces and some fourth-degree surfaces (elliptical tori). Monte Carlo has evolved into perhaps the main method for radiation transport calculations at Los Alamos. MCNP is used in every technical division at the Laboratory by over 130 users about 600 times a month accounting for nearly 200 hours of CDC-7600 time.

  9. New Generation of Los Alamos Opacity Tables

    NASA Astrophysics Data System (ADS)

    Colgan, James; Kilcrease, D. P.; Magee, N. H.; Sherrill, M. E.; Abdallah, J.; Hakel, P.; Fontes, C. J.; Guzik, J. A.; Mussack, K. A.

    2016-05-01

    We present a new generation of Los Alamos OPLIB opacity tables that have been computed using the ATOMIC code. Our tables have been calculated for all 30 elements from hydrogen through zinc and are publicly available through our website. In this poster we discuss the details of the calculations that underpin the new opacity tables. We also show several recent applications of the use of our opacity tables to solar modeling and other astrophysical applications. In particular, we demonstrate that use of the new opacities improves the agreement between solar models and helioseismology, but does not fully resolve the long-standing `solar abundance' problem. The Los Alamos National Laboratory is operated by Los Alamos National Security, LLC for the National Nuclear Security Administration of the U.S. Department of Energy under Contract No. DE-AC5206NA25396.

  10. Publications of Los Alamos Research, 1983

    SciTech Connect

    Sheridan, C.J.; McClary, W.J.; Rich, J.A.; Rodriguez, L.L.

    1984-10-01

    This bibliography is a compilation of unclassified publications of work done at the Los Alamos National Laboratory for 1983. Papers published in 1982 are included regardless of when they were actually written. Publications received too late for inclusion in earlier compilations have also been listed. Declassification of previously classified reports is considered to constitute publication. All classified issuances are omitted - even those papers, themselves unclassified, which were published only as part of a classified document. If a paper was published more than once, all places of publication are included. The bibliography includes Los Alamos National Laboratory reports, papers released as non-Laboratory reports, journal articles, books, chapters of books, conference papers either published separately or as part of conference proceedings issued as books or reports, papers publishd in congressional hearings, theses, and US patents. Publications by Los Alamos authors that are not records of Laboratory-sponsored work are included when the Library becomes aware of them.

  11. Publications of Los Alamos research 1980

    SciTech Connect

    Salazar, C.A.; Willis, J.K.

    1981-09-01

    This bibliography is a compilation of unclassified publications of work done at the Los Alamos National Laboratory for 1980. Papers published in 1980 are included regardless of when they were actually written. Publications received too late for inclusion in earlier compilations have also been listed. Declassification of previously classified reports is considered to constitute publication. All classified issuances are omitted-even those papers, themselves unclassified, which were published only as part of a classified document. If a paper was pubished more than once, all places of publication are included. The bibliography includes Los Alamos National Laboratory reports, papers released as non-laboratory reports, journal articles, books, chapters of books, conference papers published either separately or as part of conference proceedings issued as books or reports, papers published in congressional hearings, theses, and US patents. Publications by Los Alamos authors that are not records of Laboratory-sponsored work are included when the Library becomes aware of them.

  12. SEDs at Los Alamos: A Personal Memoir

    NASA Astrophysics Data System (ADS)

    Bederson, Benjamin

    2001-03-01

    I have written this personal memoir approximately 55 years after the events I describe. It is based almost exclusively on memory, since apart from the diary I kept while on Tinian, I have few documents concerning it. It covers my service in the U.S. Army's Special Engineering Detachment (SED) in Oak Ridge and Los Alamos in 1944-45, on Tinian island, the launching pad for the bombing raids on Japan, in the summer and fall of 1945, and my return to Los Alamos until my discharge in January 1946.

  13. Initial electron-beam characterizations for the Los Alamos APEX Facility

    SciTech Connect

    Lumpkin, A.H.; Feldman, R.B.; Apgar, S.A.; Feldman, D.W.; O'Shea, P.G. ); Fiorito, R.B.; Rule, D.W. )

    1991-01-01

    The ongoing upgrade of the Los Alamos Free-Electron Laser (FEL) Facility involves the addition of a photoelectric injector (PEI) and acceleration capability to about 40 MeV. The electron-beam and high-speed diagnostics provide key measurements of charge, beam position and profile, divergence emittance, energy (centroid, spread, slew, and extraction efficiency), micropulse duration, and phase stability. Preliminary results on the facility include optical transition radiation interferometer measurements of divergence (1 to 2 mrad), FEL extraction efficiency (0.6 {plus minus} 0.2%), and drive laser phase stability (< 2 ps (rms)). 10 refs.

  14. Earthquake Triggering by Fluid Overpressure at Trident and Novarupta Volcanoes, Alaska

    NASA Astrophysics Data System (ADS)

    Prejean, S. G.; Thurber, C. H.; Murphy, R. A.; Pesicek, J. D.

    2011-12-01

    In 2008 the region of Trident and Novarupta volcanoes (TN) in the Katmai volcanic cluster, Alaska, experienced a swarm of small shallow earthquakes in association with a series of deep (>25 km) long-period (DLP) earthquakes. We captured the latter half of the swarm with a dense array of 10 temporary broadband seismometers deployed within the larger-scale permanent network of 20 stations. This level of seismic coverage is exceptional for a remote Alaskan volcano. We computed ~100 first motion fault plane solutions for brittle failure earthquakes in the Katmai region. Roughly 30% of the earthquakes located in the TN area have high quality P-wave polarities that are inconsistent with the best fitting double-couple fault plane solutions. We computed full moment tensors for a subset of these events following Julian and Foulger (Bull. Seis. Soc. Am., v.86, 972-980, 1996) based on P-wave amplitudes and P to SH amplitude ratios. Ray parameters and path-averaged Q corrections used in the inversions were derived from three dimensional velocity and attenuation models. Computed fault plane solutions in the TN region are highly diverse, unlike those of some neighboring Katmai area volcanoes. Results suggest that this area is a normal to strike-slip faulting environment where the vertical effective stress and most compressive horizontal effective stress were roughly equal in magnitude at the time of the swarm. Moment tensor results indicate that the majority of these earthquakes have positive isotropic components, indicative of volume increase, and CLVD components with major dipoles directed outward. These moment tensors are similar to those calculated at several geothermal areas globally and are consistent with simultaneous shear faulting and hydraulic fracturing, as water or gas rapidly intrudes into tensile cracks. Taken together, these observations suggest that earthquakes in the 2008 swarm occur on a complex network of normal and strike-slip faults in a high pore pressure

  15. Pyrazolyl conjugates of bombesin: a new tridentate ligand framework for the stabilization of fac-[M(CO)3]+ moiety.

    PubMed

    Alves, Susana; Correia, Joao D G; Santos, Isabel; Veerendra, Bhadrasetty; Sieckman, Gary L; Hoffman, Timothy J; Rold, Tammy L; Figueroa, Said Daibes; Retzloff, Lauren; McCrate, Joseph; Prasanphanich, Adam; Smith, Charles J

    2006-07-01

    We have described the synthesis of tridentate pyrazolyl ligand frameworks for coordination to the fac-[*M(CO)(3)](+) metal fragment (*M=(186/188)Re or (99m)Tc). These ligands impart a degree of kinetic inertness on the metal center, warranting their study in biological systems. We herein report in vitro/in vivo radiolabeling investigations of a new series of pyrazolyl bombesin (BBN) conjugates radiolabeled via the Isolink kit. These new conjugates are based on the general structure [(99m)Tc-pyrazolyl-X-BBN[7-14]NH(2)], where X=beta-alanine, serylserylserine or glycylglycylglycine. The pyrazolyl ligand is a tridentate ligand framework that coordinates the metal center through nitrogen donor atoms. The results of these investigations demonstrate the ability of these new conjugates to specifically target the gastrin-releasing peptide receptor subtype 2, which is overexpressed on human prostate PC-3 cancerous tissues. Therefore, these studies suggest the tridentate pyrazolyl ligand framework to be an ideal candidate for the design and development of low-valent (99m)Tc-based diagnostic radiopharmaceuticals based on BBN or other targeting vectors. PMID:16843837

  16. Induction inserts at the Los Alamos PSR

    SciTech Connect

    King-Yuen Ng

    2002-09-30

    Ferrite-loaded induction tuners installed in the Los Alamos Proton Storage Ring have been successful in compensating space-charge effects. However, the resistive part of the ferrite introduces unacceptable microwave instability and severe bunch lengthening. An effective cure was found by heating the ferrite cores up to {approx} 130 C. An understanding of the instability and cure is presented.

  17. Los Alamos waste drum shufflers users manual

    SciTech Connect

    Rinard, P.M.; Adams, E.L.; Painter, J.

    1993-08-24

    This user manual describes the Los Alamos waste drum shufflers. The primary purpose of the instruments is to assay the mass of {sup 235}U (or other fissile materials) in drums of assorted waste. It can perform passive assays for isotopes that spontaneously emit neutrons or active assays using the shuffler technique as described on this manual.

  18. Proceedings of the Los Alamos neutrino workshop

    SciTech Connect

    Boehm, F.; Stephenson, G.J. Jr.

    1982-08-01

    A workshop on neutrino physics was held at Los Alamos from June 8 to 12, 1981. The material presented has been provided in part by the organizers, in part by the chairmen of the working sessions. Closing date for contributions was October 1981.

  19. Los Alamos Fires From Landsat 7

    NASA Technical Reports Server (NTRS)

    2002-01-01

    On May 9, 2000, the Landsat 7 satellite acquired an image of the area around Los Alamos, New Mexico. The Landsat 7 satellite acquired this image from 427 miles in space through its sensor called the Enhanced Thematic Mapper Plus (ETM+). Evident within the imagery is a view of the ongoing Cerro Grande fire near the town of Los Alamos and the Los Alamos National Laboratory. Combining the high-resolution (30 meters per pixel in this scene) imaging capacity of ETM+ with its multi-spectral capabilities allows scientists to penetrate the smoke plume and see the structure of the fire on the surface. Notice the high-level of detail in the infrared image (bottom), in which burn scars are clearly distinguished from the hotter smoldering and flaming parts of the fire. Within this image pair several features are clearly visible, including the Cerro Grande fire and smoke plume, the town of Los Alamos, the Los Alamos National Laboratory and associated property, and Cerro Grande peak. Combining ETM+ channels 7, 4, and 2 (one visible and two infrared channels) results in a false color image where vegetation appears as bright to dark green (bottom image). Forested areas are generally dark green while herbaceous vegetation is light green. Rangeland or more open areas appear pink to light purple. Areas with extensive pavement or urban development appear light blue or white to purple. Less densely-developed residential areas appear light green and golf courses are very bright green. The areas recently burned appear black. Dark red to bright red patches, or linear features within the burned area, are the hottest and possibly actively burning areas of the fire. The fire is spreading downslope and the front of the fire is readily detectable about 2 kilometers to the west and south of Los Alamos. Combining ETM+ channels 3, 2, and 1 provides a true-color image of the greater Los Alamos region (top image). Vegetation is generally dark to medium green. Forested areas are very dark green

  20. A Mn(iii) single ion magnet with tridentate Schiff-base ligands.

    PubMed

    Realista, S; Fitzpatrick, A J; Santos, G; Ferreira, L P; Barroso, S; Pereira, L C J; Bandeira, N A G; Neugebauer, P; Hrubý, J; Morgan, G G; van Slageren, J; Calhorda, M J; Martinho, P N

    2016-08-01

    Single ion magnet behaviour is reported for a mononuclear Mn(iii) ion with tridentate Schiff-base ligands which exhibits a tetragonal Jahn-Teller elongation along the Namine-Mn-Namine axis and crystallises with two crystallographically distinct Mn(iii) cations (unit A and unit B). While magnetic measurements show a large and negative axial zero-field splitting (D = -4.73 cm(-1)), HF-EPR reveal two distinct large axial Ds (D = -4.60 cm(-1) for unit A and D = -4.18 cm(-1) for unit B), thus resulting in the largest D known to date for a Mn(iii) single ion magnet. AC magnetic measurements at 2000 Oe allowed determination of the energy barrier for spin reversal (10.19 K) and spin reversal relaxation time (1.476 × 10(-6) s) for the Mn(iii) ion. Computational studies were used to characterise the electronic structure and substantiate the zero field splitting in the Mn(iii) complex. PMID:27440193

  1. The Max Rover submersible is tested at the Trident pier, Port Canaveral

    NASA Technical Reports Server (NTRS)

    1997-01-01

    Thomas Lippitt of NASA's Advanced Systems Development (ASD) laboratory observes robotic operations as Chris Nicholson, owner of Deep Sea Systems, and Bill Jones of NASA's ASD laboratory operate the unmanned robotic submersible recovery system, known as Max Rover, during a test of the system at the Trident Pier at Port Canaveral. The submersible is seen in the water with the Diver Operated Plug (DOP). Kennedy Space Center's solid rocket booster (SRB) retrieval team and ASD laboratory staff hope that the new robotic technology will make the process of inserting the plug safer and less strenuous. Currently, scuba divers manually insert the DOP into the aft nozzle of a jettisoned SRB 60 to 70 feet below the surface of the Atlantic Ocean. After the plug is installed, water is pumped out of the booster allowing it to float horizontally. It is then towed back to Hangar AF at Cape Canaveral Air Station for refurbishment. Deep Sea Systems of Falmouth, Mass., built the submersible for NASA.

  2. TRIDENT: an Infrared Differential Imaging Camera Optimized for the Detection of Methanated Substellar Companions

    SciTech Connect

    Marois, C; Doyon, R; Nadeau, D; Racine, R; Riopel, M; Vallee, P; Lafreniere, D

    2005-04-08

    A near-infrared camera in use at the Canada-France-Hawaii Telescope (CFHT) and at the 1.6-m telescope of the Observatoire du Mont-Megantic is described. The camera is based on a Hawaii-1 1024 x 1024 HgCdTe array detector. Its main feature is to acquire three simultaneous images at three wavelengths across the methane absorption bandhead at 1.6 {micro}m, enabling, in theory, an accurate subtraction of the stellar point spread function (PSF) and the detection of faint close methanated companions. The instrument has no coronoagraph and features fast data acquisition, yielding high observing efficiency on bright stars. The performance of the instrument is described, and it is illustrated by laboratory tests and CFHT observations of the nearby stars GL526, {nu}-And and {chi}-And. TRIDENT can detect (6{sigma}) a methanated companion with {Delta}H = 9.5 at 0.5'' separation from the star in one hour of observing time. Non-common path aberrations and amplitude modulation differences between the three optical paths are likely to be the limiting factors preventing further PSF attenuation. Instrument rotation and reference star subtraction improve the detection limit by a factor of 2 and 4 respectively. A PSF noise attenuation model is presented to estimate the non-common path wavefront difference effect on PSF subtraction performance.

  3. Ru alkylidene compounds bearing tridentate, dianionic ligands: Lewis acid activation and olefin metathesis.

    PubMed

    McKinty, Adam M; Stephan, Douglas W

    2016-03-01

    The series of tridentate complexes of Ru-alkylidenes (L)Ru(CHPh)(SCH2CH2)2E (E = O, L = SIMes 1, PCy3 2, E = S, L = SIMes 3, PCy3 4; E = PPh 7, L = PCy3), (L)Ru(CHPh)(SC6H4)2S (L = SIMes 5, PCy3 6), (L)Ru(CHPh) (OCH2CH2)2O (L = SIMes 8, PCy3 9) were prepared and shown to react with one equivalent of BCl3 to give the complexes (L)Ru(CHPh)Cl[E(CH2CH2S)2BCl2] (E = O, L = SIMes 10, PCy3 11, E = S, L = SIMes 12a/b, PCy3 13, E = PPh, L = PCy3 16) and (L)Ru(CHPh)(SC6H4)2O (L = SIMes 14, PCy3 15). In the case of 1 and 2 reaction with two equivalents of BCl3 affording the corresponding cation via chloride abstraction. These cations coordinate MeCN to give the six coordinate Ru cation salts [(L)Ru(CHPh)- (NCMe)(O(CH2CH2S)2BCl2)][BCl4] L = SIMes 17, PCy3 18). The generated five coordinate cations derived from 2-9 via addition of two equivalents of BCl3 were evaluated in standard preliminary tests for olefin metathesis catalysis.

  4. Luminescent heterometallic gold-copper alkynyl complexes stabilized by tridentate phosphine.

    PubMed

    Shakirova, Julia R; Grachova, Elena V; Gurzhiy, Vladislav V; Koshevoy, Igor O; Melnikov, Alexei S; Sizova, Olga V; Tunik, Sergey P; Laguna, Antonio

    2012-03-14

    The reactions between trinuclear gold complex tppmAu(3)Cl(3) (tppm = tris(diphenylphosphino)methane), arylacetylenes HC(2)C(6)H(4)X and Cu(+) under basic conditions result in formation of the heterometallic complexes [tppm(AuC(2)C(6)H(4)X)(3)Cu](+), X = H (1), COOMe (2), CN (3), OMe (4), NH(2) (5). These compounds belong to one structural motif and consist of the heterometallic {(AuC(2)C(6)H(4)X)(3)Cu} core stabilized by the tridentate phosphine. Compounds 1-5 were characterized by polynuclear NMR and IR spectroscopy, ESI-MS and single-crystal X-ray analysis. Luminescence properties of these complexes have been studied and revealed a substantial red shift of the emission maxima with the increase in the electron donicity of the alkynyl ligands substituents in the 550-680 nm range. The theoretical calculations of the electronic structures showed that variations of the substituents on the alkynyl ligands display very little effect on the molecular structural parameters but show appreciable influence on the orbital energies and luminescence characteristics of the compounds under study. PMID:22266767

  5. TRIDENT: an infrared camera optimized for the detection of methanated substellar companions of nearby stars

    NASA Astrophysics Data System (ADS)

    Marois, Christian; Doyon, Rene; Nadeau, Daniel; Racine, Rene; Riopel, Martin; Vallee, Philippe

    2003-02-01

    A near-infrared camera in use at the Canada-France-Hawaii Telescope and at the 1.6m telescope of the Observatoire du Mont-Mégantic is described. The camera is based on a Hawaii-1 1024×1024 HgCdTe array detector. Its main feature is to acquire three simultaneous images at three wavelengths (simultaneous differential imaging) across the methane absorption bandhead at 1.6 micron, enabling an accurate subtraction of the stellar point spread function (PSF) and the detection of faint close methanated companions. The instrument has no coronagraph and features a fast (1 MHz) data acquisition system without reset anomaly, yielding high observing efficiencies on bright stars. The performance of the instrument is described, and it is illustrated by CFHT images of the nearby star Ups And. TRIDENT can detect (3 sigma) a methanated companion with Delta H=10 at 0.5" from the star in one hour of observing time. Non-common path aberrations between the three optical paths are the limiting factors preventing further PSF attenuation. Reference star subtraction and instrument rotation improve the detection limit by one order of magnitude.

  6. Ru alkylidene compounds bearing tridentate, dianionic ligands: Lewis acid activation and olefin metathesis.

    PubMed

    McKinty, Adam M; Stephan, Douglas W

    2016-03-01

    The series of tridentate complexes of Ru-alkylidenes (L)Ru(CHPh)(SCH2CH2)2E (E = O, L = SIMes 1, PCy3 2, E = S, L = SIMes 3, PCy3 4; E = PPh 7, L = PCy3), (L)Ru(CHPh)(SC6H4)2S (L = SIMes 5, PCy3 6), (L)Ru(CHPh) (OCH2CH2)2O (L = SIMes 8, PCy3 9) were prepared and shown to react with one equivalent of BCl3 to give the complexes (L)Ru(CHPh)Cl[E(CH2CH2S)2BCl2] (E = O, L = SIMes 10, PCy3 11, E = S, L = SIMes 12a/b, PCy3 13, E = PPh, L = PCy3 16) and (L)Ru(CHPh)(SC6H4)2O (L = SIMes 14, PCy3 15). In the case of 1 and 2 reaction with two equivalents of BCl3 affording the corresponding cation via chloride abstraction. These cations coordinate MeCN to give the six coordinate Ru cation salts [(L)Ru(CHPh)- (NCMe)(O(CH2CH2S)2BCl2)][BCl4] L = SIMes 17, PCy3 18). The generated five coordinate cations derived from 2-9 via addition of two equivalents of BCl3 were evaluated in standard preliminary tests for olefin metathesis catalysis. PMID:26822161

  7. Increased efficiency of short-pulse laser-generated proton beams from novel flat-top cone targets

    SciTech Connect

    Flippo, K. A.; Gautier, D. C.; Kline, J. L.; Albright, B.; Johnson, R. P.; Letzring, S.; Shimada, T.; Fernandez, J. C.; Hegelich, B. M.; D'Humieres, E.; Rassuchine, J.; Bakeman, M.; Renard-LeGalloudec, N.; Sentoku, Y.; Cowan, T. E.; Gaillard, S. A.; Schollmeier, M.; Nuernberg, F.; Harres, K.; Roth, M.

    2008-05-15

    Ion-driven fast ignition (IFI) may have significant advantages over electron-driven FI due to the potentially large reduction in the amount of energy required for the ignition beam and the laser driver. Recent experiments at the Los Alamos National Laboratory's Trident facility employing novel Au flat-top cone targets have produced a fourfold increase in laser-energy to ion-energy efficiency, a 13-fold increase in the number of ions above 10 MeV, and a few times increase in the maximum ion energy compared to Au flat-foil targets. Compared to recently published scaling laws, these gains are even greater. If the efficiency scales with intensity in accordance to flat-foil scaling, then, with little modification, these targets can be used to generate the pulse of ions needed to ignite thermonuclear fusion in the fast ignitor scheme. A proton energy of at least 30 MeV was measured from the flat-top cone targets, and particle-in-cell (PIC) simulations show that the maximum cutoff energy may be as high as 40-45 MeV at modest intensity of 1x10{sup 19} W/cm{sup 2} with 20 J in 600 fs. Simulations indicate that the observed energy and efficiency increase can be attributed to the cone target's ability to guide laser light into the neck to produce hot electrons and transport these electrons to the flat-top of the cone where they can be heated to much higher temperatures, creating a hotter, denser sheath. The PIC simulations also elucidate the critical parameters for obtaining superior proton acceleration such as the dependence on laser contrast/plasma prefill, as well as longitudinal and transverse laser pointing, and cone geometry. These novel cones have the potential to revolutionize inertial confinement fusion target design and fabrication via their ability to be mass produced. In addition, they could have an impact on the general physics community studying basic electron and radiation transport phenomena or as better sources of particle beams to study equations of state

  8. Nuclear Forensics at Los Alamos National Laboratory

    SciTech Connect

    Podlesak, David W; Steiner, Robert E.; Burns, Carol J.; LaMont, Stephen P.; Tandon, Lav

    2012-08-09

    The overview of this presentation is: (1) Introduction to nonproliferation efforts; (2) Scope of activities at Los Alamos National Laboratory; (3) Facilities for radioanalytical work at LANL; (4) Radiochemical characterization capabilities; and (5) Bulk chemical and materials analysis capabilities. Some conclusions are: (1) Analytical chemistry measurements on plutonium and uranium matrices are critical to numerous defense and non-defense programs including safeguards accountancy verification measurements; (2) Los Alamos National Laboratory operates capable actinide analytical chemistry and material science laboratories suitable for nuclear material forensic characterization; (3) Actinide analytical chemistry uses numerous means to validate and independently verify that measurement data quality objectives are met; and (4) Numerous LANL nuclear facilities support the nuclear material handling, preparation, and analysis capabilities necessary to evaluate samples containing nearly any mass of an actinide (attogram to kilogram levels).

  9. Water Supply at Los Alamos during 1997

    SciTech Connect

    M. N. Maes; S. G. McLin; W. D. Purtymun

    1998-12-01

    Production of potable municipal water supplies during 1997 totaled about 1,285.9 million gallons from wells in the Guaje, Pajarito, and Otowi well fields. There was no water used from the spring gallery in Water Canyon or from Guaje Reservoir during 1997. About 2.4 million gallons of water from Los Alamos Reservoir was used to irrigate public parks and recreational lands. The total water usage in 1997 was about 1,288.3 million gallons, or about 135 gallons per day per person living in Los Alamos County. Groundwater pumpage was down about 82.2 million gallons in 1997 compared with the pumpage in 1996. Four new replacement wells were drilled and cased in Guaje Canyon between October 1997 and March 1998. These wells are currently being developed and aquifer tests are being performed. A special report summarizing the geological, geophysical, and well construction logs will be issued in the near future for these new wells.

  10. Los Alamos Team Demonstrates Bottle Scanner Technology

    ScienceCinema

    Espy, Michelle; Schultz, Larry

    2016-07-12

    Los Alamos scientists are demonstrating a Nuclear Magnetic Resonance Imaging (NMR) technology that may provide a breakthrough for screening liquids at airport security. By adding low-power X-ray data to the NMR mix, scientists believe they have unlocked a new detection technology. Funded in part by the Department of Homeland Security's Science and Technology Directorate, the new technology is called MagRay.

  11. Status of the Los Alamos Anger camera

    SciTech Connect

    Seeger, P.A.; Nutter, M.J.

    1985-01-01

    Results of preliminary tests of the neutron Anger camera being developed at Los Alamos are presented. This detector uses a unique encoding scheme involving parellel processing of multiple receptive fields. Design goals have not yet been met, but the results are very encouraging and improvements in the test procedures are expected to show that the detector will be ready for use on a small-angle scattering instrument next year. 3 refs., 4 figs.

  12. Los Alamos synchronous orbit data set

    SciTech Connect

    Baker, D.N.; Higbie, P.R.; Belian, R.D.; Hones, E.W.; Klebesadel, R.W.

    1981-01-01

    Energetic electron (30-15000 keV) and proton 145 keV to 150 MeV) measurements made by Los Alamos National Laboratory sensors at geostationary orbit (6.6 R/sub E/) are summarized. The instrumentation employed and the satellite positions are described. The spacecraft have been variously located, but in their present configuration the Los Alamos satellites designated 1976-059, 1977-007, and 1979-053 are located, respectively, at approx. 70/sup 0/W, approx. 70/sup 0/E, and approx. 135/sup 0/W longitude. Several examples of the high temporal and full three-dimensional spatial measurement capabilities of these instruments are illustrated by examples from the published literature. Discussion is also given for the Los Alamos Synoptic Data Set (SDS) which gives a broad overview of the Los Alamos geostationary orbit measurements. The SDS data are plotted in terms of daily average spectra, 3-hour local time averages, and in a variety of statistical formats. The data summarize conditions from mid-1976 through 1978 (S/C 1976-059) and from early 1977 through 1978 (S/C 1977-007). The SDS compilations presented correspond to measurements at 35/sup 0/W, 70/sup 0/W, and 135/sup 0/W geographic longitude and thus are indicative of conditions at 9/sup 0/, 11/sup 0/, and 4.8/sup 0/ geomagnetic latitude, respectively. The bulk of the SDS report presents data plots which are organized according to Carrington solar rotations and, as such, the data are readily comparable to solar rotation-dependent interplanetary conditions. Potential applications of the Synoptic Data Set (available to all interested users in June 1981) are discussed.

  13. Amphibians and Reptiles of Los Alamos County

    SciTech Connect

    Teralene S. Foxx; Timothy K. Haarmann; David C. Keller

    1999-10-01

    Recent studies have shown that amphibians and reptiles are good indicators of environmental health. They live in terrestrial and aquatic environments and are often the first animals to be affected by environmental change. This publication provides baseline information about amphibians and reptiles that are present on the Pajarito Plateau. Ten years of data collection and observations by researchers at Los Alamos National Laboratory, the University of New Mexico, the New Mexico Department of Game and Fish, and hobbyists are represented.

  14. Los Alamos Team Demonstrates Bottle Scanner Technology

    SciTech Connect

    Espy, Michelle; Schultz, Larry

    2014-05-06

    Los Alamos scientists are demonstrating a Nuclear Magnetic Resonance Imaging (NMR) technology that may provide a breakthrough for screening liquids at airport security. By adding low-power X-ray data to the NMR mix, scientists believe they have unlocked a new detection technology. Funded in part by the Department of Homeland Security's Science and Technology Directorate, the new technology is called MagRay.

  15. The Los Alamos accelerator code group

    SciTech Connect

    Krawczyk, F.L.; Billen, J.H.; Ryne, R.D.; Takeda, Harunori; Young, L.M.

    1995-05-01

    The Los Alamos Accelerator Code Group (LAACG) is a national resource for members of the accelerator community who use and/or develop software for the design and analysis of particle accelerators, beam transport systems, light sources, storage rings, and components of these systems. Below the authors describe the LAACG`s activities in high performance computing, maintenance and enhancement of POISSON/SUPERFISH and related codes and the dissemination of information on the INTERNET.

  16. Los Alamos Novel Rocket Design Flight Tested

    SciTech Connect

    Tappan, Bryce

    2014-10-23

    Los Alamos National Laboratory scientists recently flight tested a new rocket design that includes a high-energy fuel and a motor design that also delivers a high degree of safety. Researchers will now work to scale-up the design, as well as explore miniaturization of the system, in order to exploit all potential applications that would require high-energy, high-velocity, and correspondingly high safety margins.

  17. Los Alamos Novel Rocket Design Flight Tested

    ScienceCinema

    Tappan, Bryce

    2016-07-12

    Los Alamos National Laboratory scientists recently flight tested a new rocket design that includes a high-energy fuel and a motor design that also delivers a high degree of safety. Researchers will now work to scale-up the design, as well as explore miniaturization of the system, in order to exploit all potential applications that would require high-energy, high-velocity, and correspondingly high safety margins.

  18. Los Alamos National Laboratory Facility Review

    SciTech Connect

    Nelson, Ronald Owen

    2015-06-05

    This series of slides depicts the Los Alamos Neutron Science Center (LANSCE). The Center's 800-MeV linac produces H+ and H- beams as well as beams of moderated (cold to 1 MeV) and unmoderated (0.1 to 600 MeV) neutrons. Experimental facilities and their capabilities and characteristics are outlined. Among these are LENZ, SPIDER, and DANCE.

  19. Critical partnerships: Los Alamos, universities, and industry

    SciTech Connect

    Berger, C.L.

    1997-04-01

    Los Alamos National Laboratory, situated 35 miles northwest of Santa Fe, NM, is one of the Department of Energy`s three Defense Programs laboratories. It encompasses 43 square miles, employees approximately 10,000 people, and has a budget of approximately $1.1B in FY97. Los Alamos has a strong post-cold war mission, that of reducing the nuclear danger. But even with that key role in maintaining the nation`s security, Los Alamos views partnerships with universities and industry as critical to its future well being. Why is that? As the federal budget for R&D comes under continued scrutiny and certain reduction, we believe that the triad of science and technology contributors to the national system of R&D must rely on and leverage each others capabilities. For us this means that we will rely on these partners to help us in 5 key ways: We expect that partnerships will help us maintain and enhance our core competencies. In doing so, we will be able to attract the best scientists and engineers. To keep on the cutting edge of research and development, we have found that partnerships maintain the excellence of staff through new and exciting challenges. Additionally, we find that from our university and corporate partners we often learn and incorporate {open_quotes}best practices{close_quotes} in organizational management and operations. Finally, we believe that a strong national system of R&D will ensure and enhance our ability to generate revenues.

  20. Exploration geochemistry: The Los Alamos experience

    SciTech Connect

    Maassen, L.W.; Bolivar, S.L.

    1989-01-01

    Los Alamos National Laboratory became actively involved in geochemical exploration in 1975 by conducting a reconnaissance-scale exploration program for uranium as part of the National Uranium Resource Evaluation program. Initially, only uranium and thorium were analyzed. By 1979 Los Alamos was analyzing a multielement suite. The data were presented in histograms and as black and white concentration plots for uranium and thorium only. Data for the remaining elements were presented as hard copy data listings in an appendix to the report. In 1983 Los Alamos began using exploration geochemistry for the purpose of finding economic mineral deposits to help stimulate the economies of underdeveloped countries. Stream-sediment samples were collected on the Caribbean island of St. Lucia and a geochemical atlas of that island was produced. The data were statistically smoothed and presented as computer-generated color plots of each element of the multielement suite. Studies for the US Bureau of Land Management in 1984 consisted of development of techniques for the integration of several large data sets, which could then be used for computer-assisted mineral resource assessments. A supervised classification technique was developed which compares the attributes of grid cells containing mines or mineral occurrences with attributes of unclassified cells not known to contain mines or occurrences. Color maps indicate how closely unclassified cells match in attributes the cells with mines or occurrences. 20 refs., 1 fig., 1 tab.

  1. Los Alamos National Laboratory building cost index

    SciTech Connect

    Orr, H.D.; Lemon, G.D.

    1982-10-01

    The Los Alamos National Laboratory Building Cost Index indicates that actual escalation since 1970 is near 10% per year. Therefore, the Laboratory will continue using a 10% per year escalation rate for construction estimates through 1985 and a slightly lower rate of 8% per year from 1986 through 1990. The computerized program compares the different elements involved in the cost of a typical construction project, which for our purposes, is a complex of office buildings and experimental laboratories. The input data used in the program consist primarily of labor costs and material and equipment costs. The labor costs are the contractual rates of the crafts workers in the Los Alamos area. For the analysis, 12 field-labor craft categories are used; each is weighted corresponding to the labor craft distribution associated with the typical construction project. The materials costs are current Los Alamos prices. Additional information sources include material and equipment quotes obtained through conversations with vendors and from trade publications. The material and equipment items separate into 17 categories for the analysis and are weighted corresponding to the material and equipment distribution associated with the typical construction project. The building cost index is compared to other national building cost indexes.

  2. Los Alamos National Laboratory Building Cost Index

    SciTech Connect

    Orr, H.D.; Lemon, G.D.

    1983-01-01

    The Los Alamos National Laboratory Building Cost Index indicates that actual escalation since 1970 is near 10% per year. Therefore, the Laboratory will continue using a 10% per year escalation rate for construction estimates through 1985 and a slightly lower rate of 8% per year from 1986 through 1990. The computerized program compares the different elements involved in the cost of a typical construction project, which for our purposes, is a complex of office buildings and experimental laboratores. The input data used in the program consist primarily of labor costs and material and equipment costs. The labor costs are the contractural rates of the crafts workers in the Los Alamos area. For the analysis, 12 field-labor draft categories are used; each is weighted corresponding to the labor craft distribution associated with the typical construction project. The materials costs are current Los Alamos prices. Additional information sources include material and equipment quotes obtained through conversations with vendors and from trade publications. The material and equipment items separate into 17 categories for the analysis and are weighted corresponding to the material and equipment distribution associated with the typical construction project. The building cost index is compared to other national building cost indexes.

  3. Gold(III) complexes with ONS-Tridentate thiosemicarbazones: Toward selective trypanocidal drugs.

    PubMed

    Rettondin, Andressa R; Carneiro, Zumira A; Gonçalves, Ana C R; Ferreira, Vanessa F; Oliveira, Carolina G; Lima, Angélica N; Oliveira, Ronaldo J; de Albuquerque, Sérgio; Deflon, Victor M; Maia, Pedro I S

    2016-09-14

    Tridentate thiosemicarbazone ligands with an ONS donor set, H2L(R) (R = Me and Et) were prepared by reactions of 1-phenyl-1,3-butanedione with 4-R-3-thiosemicarbazides. H2L(R) reacts with Na[AuCl4]·2H2O in MeOH in a 1:1 M ratio under formation of green gold(III) complexes of composition [AuCl(L(R))]. These compounds represent the first examples of gold(III) complexes with ONS chelate-bonded thiosemicarbazones. The in vitro anti-Trypanosoma cruzi activity against both trypomastigote and amastigote forms (IC50try/ama) of CL Brener strains as well as the cytotoxicity against LLC-MK2 cells of the free ligands and complexes was evaluated. The complex [AuCl(L(Me))] was found to be more active and more selective than its precursor ligand and the standard drug benznidazole with a SItry/ama value higher than 200, being considered as a lead candidate for Chagas disease treatment. Moreover the in vitro activity against the replicative amastigote form (IC50ama) of T. cruzi was additionally investigated revealing that [AuCl(L(Me))] was also more potent than benznidazole still with a similar selectivity index. Finally, docking studies showed that free ligands and complexes interact with the same residues of the parasite protease cruzain but with different intensities, suggesting that this protease could be a possible target for the trypanocidal action of the obtained compounds. PMID:27191616

  4. Spectroscopic, structural and theoretical studies of copper(II) complexes of tridentate NOS Schiff bases

    NASA Astrophysics Data System (ADS)

    Olalekan, Temitope E.; Ogunlaja, Adeniyi S.; VanBrecht, Bernardus; Watkins, Gareth M.

    2016-10-01

    Two newly synthesized Schiff bases (L4 and L5) were derived from the condensation reaction of 2-(methylthiomethyl)anilines and 4-methoxysalicylaldehyde. Coordination complexes of these and four previously reported NOS Schiff bases, Cu(L1)2-Cu(L6)2, were synthesized via the reflux reaction of the various Schiff base ligands with CuCl2·2H2O. The compounds were characterized by means of elemental analysis, FTIR and UV-Vis. The crystal structures of Cu(L1)2 and Cu(L2)2 were obtained by X-ray diffraction. The Schiff bases were coordinated to copper ion as monobasic tridentate ligands through the phenolic oxygen, azomethine nitrogen and thioether sulfur. The microanalyses of the coordination complexes were agreeable with bimolar binding of the ligands to the copper metal ion. The crystal structures of the copper complexes confirmed an octahedral geometry around the metal centre and showed they are mononuclear. The magnetic moment values indicated the presence of a lone electron in each copper(II) orbital and confirmed the mononuclearity of the complexes. The electronic spectra of the coordination compounds consist of the intraligand, charge transfer and d→d bands. Molecular modeling studies on the complexes (Cu(L1)2-Cu(L6)2) by employing DFT revealed that complex Cu(L5)2 possessed the smallest optimization energy as well as a small HOMO-LUMO energy gap which may best explain its higher polarizability as well as reactivity in comparison to the other complexes.

  5. Palladium(II) and platinum(II) complexes with tridentate iminophosphine ligands; synthesis and structural studies.

    PubMed

    Ní Dhubhghaill, Orla M; Lennon, Joanne; Drew, Michael G B

    2005-10-01

    The previously synthesised Schiff-base ligands 2-(2-Ph(2)PC(6)H(4)N[double bond, length as m-dash]CH)-R'-C(6)H(3)OH (R'= 3-OCH(3), HL(1); 5-OCH(3), HL(2); 5-Br, HL(3); 5-Cl, HL(4)) were prepared by a faster, more efficient route involving a microwave assisted co-condensation of 2-(diphenylphosphino)aniline with the appropriate substituted salicylaldehyde. HL(1-4) react directly with M(II)Cl(2)(M = Pd, Pt) or Pt(II)I(2)(cod) affording neutral square-planar complexes of general formula [M(II)Cl(eta(3)-L(1-4))](M = Pd, Pt, 1-8) and [Pt(II)I(eta(3)-L(1-4))](M = Pd, Pt, 9-12). Reaction of complexes 1-4 with the triarylphosphines PR(3)(R = Ph, p-tolyl) gave the novel ionic complexes [Pd(II)(PR(3))(eta(3)-L(1-4))]ClO(4)(13-20). Substituted platinum complexes of the type [Pt(II)(PR(3))(eta(3)-L(1-4))]ClO(4)(R = P(CH(2)CH(2)CN)(3)21-24) and [Pt(II)(P(p-tolyl)(3))(eta(3)-L(3,4))]ClO(4)( 25 and 26 ) were synthesised from the appropriate [Pt(II)Cl(eta(3)-L(1-4))] complex (5-8) and PR(3). The complexes are characterised by microanalytical and spectroscopic techniques. The crystal structures of 3, 6, 10, 15, 20 and 26 were determined and revealed the metal to be in a square-planar four-coordinate environment containing a planar tridentate ligand with an O,N,P donor set together with one further atom which is trans to the central nitrogen atom. PMID:16172647

  6. Uniform heating of materials into the warm dense matter regime with laser-driven quasimonoenergetic ion beams

    SciTech Connect

    Bang, W.; Albright, B. J.; Bradley, P. A.; Vold, E. L.; Boettger, J. C.; Fernández, J. C.

    2015-12-01

    In a recent experiment at the Trident laser facility, a laser-driven beam of quasimonoenergetic aluminum ions was used to heat solid gold and diamond foils isochorically to 5.5 and 1.7 eV, respectively. Here theoretical calculations are presented that suggest the gold and diamond were heated uniformly by these laser-driven ion beams. According to calculations and SESAME equation-of-state tables, laser-driven aluminum ion beams achievable at Trident, with a finite energy spread of ΔE/E~20%, are expected to heat the targets more uniformly than a beam of 140-MeV aluminum ions with zero energy spread. As a result, the robustness of the expected heating uniformity relative to the changes in the incident ion energy spectra is evaluated, and expected plasma temperatures of various target materials achievable with the current experimental platform are presented.

  7. Uniform heating of materials into the warm dense matter regime with laser-driven quasimonoenergetic ion beams

    DOE PAGES

    Bang, W.; Albright, B. J.; Bradley, P. A.; Vold, E. L.; Boettger, J. C.; Fernández, J. C.

    2015-12-01

    In a recent experiment at the Trident laser facility, a laser-driven beam of quasimonoenergetic aluminum ions was used to heat solid gold and diamond foils isochorically to 5.5 and 1.7 eV, respectively. Here theoretical calculations are presented that suggest the gold and diamond were heated uniformly by these laser-driven ion beams. According to calculations and SESAME equation-of-state tables, laser-driven aluminum ion beams achievable at Trident, with a finite energy spread of ΔE/E~20%, are expected to heat the targets more uniformly than a beam of 140-MeV aluminum ions with zero energy spread. As a result, the robustness of the expected heatingmore » uniformity relative to the changes in the incident ion energy spectra is evaluated, and expected plasma temperatures of various target materials achievable with the current experimental platform are presented.« less

  8. DETERMINISTIC TRANSPORT METHODS AND CODES AT LOS ALAMOS

    SciTech Connect

    J. E. MOREL

    1999-06-01

    The purposes of this paper are to: Present a brief history of deterministic transport methods development at Los Alamos National Laboratory from the 1950's to the present; Discuss the current status and capabilities of deterministic transport codes at Los Alamos; and Discuss future transport needs and possible future research directions. Our discussion of methods research necessarily includes only a small fraction of the total research actually done. The works that have been included represent a very subjective choice on the part of the author that was strongly influenced by his personal knowledge and experience. The remainder of this paper is organized in four sections: the first relates to deterministic methods research performed at Los Alamos, the second relates to production codes developed at Los Alamos, the third relates to the current status of transport codes at Los Alamos, and the fourth relates to future research directions at Los Alamos.

  9. Three-Dimensional Dynamics of Breakout Afterburner Ion Acceleration Using High-Contrast Short-Pulse Laser and Nanoscale Targets

    NASA Astrophysics Data System (ADS)

    Yin, L.; Albright, B. J.; Bowers, K. J.; Jung, D.; Fernández, J. C.; Hegelich, B. M.

    2011-07-01

    Breakout afterburner (BOA) laser-ion acceleration has been demonstrated for the first time in the laboratory. In the BOA, an initially solid-density target undergoes relativistically induced transparency, initiating a period of enhanced ion acceleration. First-ever kinetic simulations of the BOA in three dimensions show that the ion beam forms lobes in the direction orthogonal to laser polarization and propagation. Analytic theory presented for the electron dynamics in the laser ponderomotive field explains how azimuthal symmetry breaks even for a symmetric laser intensity profile; these results are consistent with recent experiments at the Trident laser facility.

  10. Three-dimensional dynamics of breakout afterburner ion acceleration using high-contrast short-pulse laser and nanoscale targets.

    PubMed

    Yin, L; Albright, B J; Bowers, K J; Jung, D; Fernández, J C; Hegelich, B M

    2011-07-22

    Breakout afterburner (BOA) laser-ion acceleration has been demonstrated for the first time in the laboratory. In the BOA, an initially solid-density target undergoes relativistically induced transparency, initiating a period of enhanced ion acceleration. First-ever kinetic simulations of the BOA in three dimensions show that the ion beam forms lobes in the direction orthogonal to laser polarization and propagation. Analytic theory presented for the electron dynamics in the laser ponderomotive field explains how azimuthal symmetry breaks even for a symmetric laser intensity profile; these results are consistent with recent experiments at the Trident laser facility.

  11. Los Alamos Before and After the Fire

    NASA Technical Reports Server (NTRS)

    2002-01-01

    On May 4, 2000, a prescribed fire was set at Bandelier National Monument, New Mexico, to clear brush and dead and dying undergrowth to prevent a larger, subsequent wildfire. Unfortunately, due to high winds and extremely dry conditions in the surrounding area, the prescribed fire quickly raged out of control and, by May 10, the blaze had spread into the nearby town of Los Alamos. In all, more than 20,000 people were evacuated from their homes and more than 200 houses were destroyed as the flames consumed about 48,000 acres in and around the Los Alamos area. The pair of images above were acquired by the Enhanced Thematic Mapper Plus (ETM+) sensor, flying aboard NASA's Landsat 7 satellite, shortly before the Los Alamos fire (top image, acquired April 14) and shortly after the fire was extinguished (lower image, June 17). The images reveal the extent of the damage caused by the fire. Combining ETM+ channels 7, 4, and 2 (one visible and two infrared channels) results in a false-color image where vegetation appears as bright to dark green. Forested areas are generally dark green while herbaceous vegetation is light green. Rangeland or more open areas appear pink to light purple. Areas with extensive pavement or urban development appear light blue or white to purple. Less densely-developed residential areas appear light green and golf courses are very bright green. In the lower image, the areas recently burned appear bright red. Landsat 7 data courtesy United States Geological Survey EROS DataCenter. Images by Robert Simmon, NASA GSFC.

  12. Biological assessment for the effluent reduction program, Los Alamos National Laboratory, Los Alamos, New Mexico

    SciTech Connect

    Cross, S.P.

    1996-08-01

    This report describes the biological assessment for the effluent recution program proposed to occur within the boundaries of Los Alamos National Laboratory. Potential effects on wetland plants and on threatened and endangered species are discussed, along with a detailed description of the individual outfalls resulting from the effluent reduction program.

  13. LAMPF II workshop, Los Alamos National Laboratory, Los Alamos, New Mexico, February 1-4, 1982

    SciTech Connect

    Thiessen, H.A.

    1982-01-01

    This report contains the proceedings of the first LAMPF II Workshop held at Los Alamos February 1 to 4, 1982. Included are the talks that were available in written form. The conclusion of the participants was that there are many exciting areas of physics that will be addressed by such a machine.

  14. Los Alamos National Laboratory strategic directions

    SciTech Connect

    Hecker, S.

    1995-10-01

    It is my pleasure to welcome you to Los Alamos. I like the idea of bringing together all aspects of the research community-defense, basic science, and industrial. It is particularly important in today`s times of constrained budgets and in fields such as neutron research because I am convinced that the best science and the best applications will come from their interplay. If we do the science well, then we will do good applications. Keeping our eye focused on interesting applications will spawn new areas of science. This interplay is especially critical, and it is good to have these communities represented here today.

  15. Experience with confirmation measurement at Los Alamos

    SciTech Connect

    Marshall, R.S.; Wagner, R.P.; Hsue, F.

    1985-01-01

    Confirmation measurements are used at Los Alamos in support of incoming and outgoing shipment accountibility and for support of both at /sup 235/U and Pu inventories. Statistical data are presented to show the consistency of measurements on items of identical composition and on items measured at two facilitis using similar instruments. A description of confirmation measurement techniques used in support of /sup 235/U and Pu inventories and a discussion on the ability of the measurements to identify items with misstated SNM are given.

  16. Materials accounting at Los Alamos National Laboratory

    SciTech Connect

    Roberts, N.J.; Erkkila, B.H.; Kelso, H.F.

    1985-07-20

    The materials accounting system at Los Alamos has evolved from an ''80-column'' card system to a very sophisticated near-real-time computerized nuclear material accountability and safeguards system (MASS). The present hardware was designed and acquired in the late 70's and is scheduled for a major upgrade in fiscal year 1986. The history of the system from 1950 through the DYMAC of the late 70's up to the present will be discussed. The philosophy of the system along with the details of the system will be covered. This system has addressed the integrated problems of management, control, and accounting of nuclear material successfully. 8 refs., 3 figs., 1 tab.

  17. Environmental Programs at Los Alamos National Laboratory

    SciTech Connect

    Jones, Patricia

    2012-07-11

    Summary of this project is: (1) Teamwork, partnering to meet goals - (a) Building on cleanup successes, (b) Solving legacy waste problems, (c) Protecting the area's environment; (2) Strong performance over the past three years - (a) Credibility from four successful Recovery Act Projects, (b) Met all Consent Order milestones, (c) Successful ramp-up of TRU program; (3) Partnership between the National Nuclear Security Administration's Los Alamos Site Office, DOE Carlsbad Field Office, New Mexico Environment Department, and contractor staff enables unprecedented cleanup progress; (4) Continued focus on protecting water resources; and (5) All consent order commitments delivered on time or ahead of schedule.

  18. Los Alamos National Laboratory computer benchmarking 1982

    SciTech Connect

    Martin, J.L.

    1983-06-01

    Evaluating the performance of computing machinery is a continual effort of the Computer Research and Applications Group of the Los Alamos National Laboratory. This report summarizes the results of the group's benchmarking activities performed between October 1981 and September 1982, presenting compilation and execution times as well as megaflop rates for a set of benchmark codes. Tests were performed on the following computers: Cray Research, Inc. (CRI) Cray-1S; Control Data Corporation (CDC) 7600, 6600, Cyber 73, Cyber 825, Cyber 835, Cyber 855, and Cyber 205; Digital Equipment Corporation (DEC) VAX 11/780 and VAX 11/782; and Apollo Computer, Inc., Apollo.

  19. Progress on the Los Alamos heavy-ion injector

    SciTech Connect

    Wilson, D.C.; Riepe, K.B.; Ballard, E.O.; Meyer, E.A.; Shurter, R.P.; Van Haaften, F.W.; Humphries, S. Jr.

    1986-01-01

    Heavy-ion fusion using an induction linac requires injection of multiple high-current beams from a pulsed electrostatic accelerator at as high a voltage as practical. Los Alamos National Laboratory is developing a 16-beam, 2-MeV, pulsed electrostatic accelerator for Al/sup +/ ions. The ion source will use a pulsed metal vapor arc plasma. A biased grid will control plasma flux into the ion extraction region. This source has achieved a normalized emittance of epsilon/sub n/ < 3.10/sup -7/..pi..-m-rad with Al/sup +/ ions. An 800 kV Marx prototype with a laser fired diverter is being assembled. The ceramic accelerating column sections have been brazed and leak tested. Voltage hold off on a brazed sample was more than doubled by selective removal of the Ticusil braze fillet extending along the ceramic. A scaled test module held 250 kV for 50 ..mu..s, giving confidence that the full module can hold 175 kV per section. The pressure vessel should be received in June 1986. High-voltage testing of a 1 MV column will begin by early 1987.

  20. Progress on the Los Alamos heavy-ion injector

    NASA Astrophysics Data System (ADS)

    Wilson, D. C.; Riepe, K. B.; Ballard, E. O.; Meyer, E. A.; Shurter, R. P.; Van Haaften, F. W.; Humphries, S.

    1986-01-01

    Heavy-ion fusion using an induction linac requires injection of multiple high-current beams from a pulsed electrostatic accelerator at as high a voltage as practical. Los Alamos National Laboratory is developing a 16-beam, 2-MeV, pulsed electrostatic accelerator for Al+ ions. The ion source will use a pulsed metal vapor arc plasma. A biased grid wil control plasma flux into the ion extraction region. This source has achieved a normalized emittance of ɛn<3ṡ10-7π-m-rad with Al+ ions. An 800 kV Marx prototype with a laser fired diverter is being assembled. The ceramic accelerating column sections have been brazed and leak tested. Voltage hold off on a brazed sample was more than doubled by selective removal of the Ticusil braze fillet extending along the ceramic. A scaled test module held 250 kV for 50 μs, giving confidence that the full module can hold 175 kV per section. The pressure vessel should be received in June 1986. High-voltage testing of a 1 MV column will begin by early 1987.

  1. New [Mo(eta3-allyl)(CO)2L3]+ complexes with monodentate or tridentate nitrogen-donor ligands.

    PubMed

    Pérez, Julio; Morales, Dolores; Nieto, Sonia; Riera, Lucía; Riera, Víctor; Miguel, Daniel

    2005-03-01

    Cationic complexes [Mo(eta(3)-allyl)(CO)2L3]+ (L3 = either nitrogen-donor tridentate ligand or three monodentate ligands) were prepared in high yield and under mild conditions using as precursors either the triflato complex [Mo(eta(3)-allyl)(OTf)(CO)2(NCMe)2] or the combination of the chloro complex [Mo(eta(3)-allyl)Cl(CO)2(NCMe)2] and the salt NaBAr'(4)(Ar'= 3,5-bis(trifluoromethyl)phenyl). The tridentate ligands employed were 2,2':6',2'-terpyridine (terpy) and cis,cis-1,3,5-cyclohexanetriamine (CHTA), whereas the monodentate ligands imidazole (im) and 3,5-dimethylpyrazole (dmpz) were chosen. In order to stabilize the labile intermediates, an excess of acetonitrile was used in most of the syntheses. However, the pyrazole complex was prepared through a nitrile-free route to avoid reactions at the coordinated nitrile. The solid state structures of [Mo(eta(3)-methallyl)(CO)2(terpy)]OTf (2), [Mo(eta(3)-methallyl)(CO)2(CHTA)]BAr'4 (3), [Mo(eta(3)-methallyl)(CO)2(NCMe)3]BAr'4 (4), [Mo(eta(3)-allyl)(CO)2(im)3]OTf (5) and [Mo(eta(3)-allyl)(CO)2(dmpz)3]BAr'4 (6) were determined by means of single-crystal X-ray diffraction. PMID:15726140

  2. The Climate at Los Alamos; Are we measurement changes?

    SciTech Connect

    Dewart, Jean Marie

    2015-04-16

    A new report shows new graphic displays of the weather trends in Los Alamos, New Mexico, and at the Los Alamos National Laboratory (LANL). The graphs show trends of average, minimum average, and maximum average temperature for summer and winter months going back decades. Records of summer and winter precipitation are also included in the report.

  3. The Los Alamos Science Pillars The Science of Signatures

    SciTech Connect

    Smith, Joshua E.; Peterson, Eugene J.

    2012-09-13

    As a national security science laboratory, Los Alamos is often asked to detect and measure the characteristics of complex systems and to use the resulting information to quantify the system's behavior. The Science of Signatures (SoS) pillar is the broad suite of technical expertise and capability that we use to accomplish this task. With it, we discover new signatures, develop new methods for detecting or measuring signatures, and deploy new detection technologies. The breadth of work at Los Alamos National Laboratory (LANL) in SoS is impressive and spans from the initial understanding of nuclear weapon performance during the Manhattan Project, to unraveling the human genome, to deploying laser spectroscopy instrumentation on Mars. Clearly, SoS is a primary science area for the Laboratory and we foresee that as it matures, new regimes of signatures will be discovered and new ways of extracting information from existing data streams will be developed. These advances will in turn drive the development of sensing instrumentation and sensor deployment. The Science of Signatures is one of three science pillars championed by the Laboratory and vital to supporting our status as a leading national security science laboratory. As with the other two pillars, Materials for the Future and Information Science and Technology for Predictive Science (IS&T), SoS relies on the integration of technical disciplines and the multidisciplinary science and engineering that is our hallmark to tackle the most difficult national security challenges. Over nine months in 2011 and 2012, a team of science leaders from across the Laboratory has worked to develop a SoS strategy that positions us for the future. The crafting of this strategy has been championed by the Chemistry, Life, and Earth Sciences Directorate, but as you will see from this document, SoS is truly an Institution-wide effort and it has engagement from every organization at the Laboratory. This process tapped the insight and

  4. Portable MRI developed at Los Alamos

    SciTech Connect

    Espy, Michelle

    2015-04-22

    Scientists at Los Alamos National Laboratory are developing an ultra-low-field Magnetic Resonance Imaging (MRI) system that could be low-power and lightweight enough for forward deployment on the battlefield and to field hospitals in the World's poorest regions. "MRI technology is a powerful medical diagnostic tool," said Michelle Espy, the Battlefield MRI (bMRI) project leader, "ideally suited for imaging soft-tissue injury, particularly to the brain." But hospital-based MRI devices are big and expensive, and require considerable infrastructure, such as large quantities of cryogens like liquid nitrogen and helium, and they typically use a large amount of energy. "Standard MRI machines just can't go everywhere," said Espy. "Soldiers wounded in battle usually have to be flown to a large hospital and people in emerging nations just don't have access to MRI at all. We've been in contact with doctors who routinely work in the Third World and report that MRI would be extremely valuable in treating pediatric encephalopathy, and other serious diseases in children." So the Los Alamos team started thinking about a way to make an MRI device that could be relatively easy to transport, set up, and use in an unconventional setting. Conventional MRI machines use very large magnetic fields that align the protons in water molecules to then create magnetic resonance signals, which are detected by the machine and turned into images. The large magnetic fields create exceptionally detailed images, but they are difficult and expensive to make. Espy and her team wanted to see if images of sufficient quality could be made with ultra-low-magnetic fields, similar in strength to the Earth's magnetic field. To achieve images at such low fields they use exquisitely sensitive detectors called Superconducting Quantum Interference Devices, or SQUIDs. SQUIDs are among the most sensitive magnetic field detectors available, so interference with the signal is the primary stumbling block. "SQUIDs are

  5. Environmental surveillance at Los Alamos during 1987

    SciTech Connect

    Not Available

    1988-05-01

    This report describes the environmental surveillance program conducted by Los Alamos National Laboratory during 1987. Routine monitoring for radiation and radioactive or chemical materials is conducted on the Laboratory site as well as in the surrounding region. Monitoring results are used to determine compliance with appropriate standards and to permit early identification of potentially undesirable trends. Results and interpretation of data for 1987 cover: external penetrating radiation; quantities of airborne emissions and liquid effluents; concentrations of chemicals and radionuclides in ambient air, surface and ground waters, municipal water supply, soils and sediments, and foodstuffs; and environmental compliance. Comparisons with appropriate standards, regulations, and background levels provide the basis for concluding that environmental effects from Laboratory operations are insignificant and do not pose a threat to the public, Laboratory employees, or the environment. 113 refs., 33 figs., 120 tabs.

  6. Environmental surveillance at Los Alamos during 1995

    SciTech Connect

    1996-10-01

    This report describes the environmental surveillance program at Los Alamos National Laboratory (LANL or the Laboratory) during 1995. The Laboratory routinely monitors for radiation and for radioactive and nonradioactive materials at (or on) Laboratory sites as well as in the surrounding region. LANL uses the monitoring result to determine compliance with appropriate standards and to identify potentially undesirable trends. Data were collected in 1995 to assess external penetrating radiation; quantities of airborne emissions and liquid effluents; concentrations of chemicals and radionuclides in ambient air, surface waters and groundwaters, municipal water supply, soils and sediments, and foodstuffs; and environmental compliance. Using comparisons with standards, regulations, and background levels, this report concludes that environmental effects from Laboratory operations are small and do not pose a demonstrable threat to the public, Laboratory employees, or the environment.

  7. Environmental surveillance at Los Alamos during 1979

    SciTech Connect

    Not Available

    1980-04-01

    This report documents the environmental surveillance program conducted by the Los Alamos Scientific Laboratory (LASL) in 1979. Routine monitoring for radiation and radioactive or chemical substances was conducted on the Laboratory site and in the surrounding region to determine compliance with appropriate standards and permit early identification of possible undesirable trends. Results and interpretation of the data for 1979 on penetrating radiation, chemical and radiochemical quality of ambient air, surface and ground water, municipal water supply, soils and sediments, food, and airborne and liquid effluents are included. Comparisons with appropriate standards and regulations or with background levels from natural or other non-LASL sources provide a basis for concluding that environmental effects attributable to LASL operations are minor and cannot be considered likely to result in any hazard to the population of the area. Results of several special studies provide documentation of some unique environmental conditions in the LASL environs.

  8. Environmental surveillance at Los Alamos during 1989

    SciTech Connect

    Not Available

    1990-12-01

    This report describes the environmental surveillance program conducted by Los Alamos National Laboratory during 1989. Routine monitoring for radiation and radioactive or chemical materials is conducted on the Laboratory site as well as in the surrounding region. Monitoring results are used to determine compliance with appropriate standards and to permit early identification of potentially undesirable trends. Results and interpretation of data for 1989 cover external penetrating radiation; quantities of airborne emissions and effluents; concentrations of chemicals and radionuclides in ambient air, surface and ground waters, municipal water supply, soils and sediments, and foodstuffs; and environmental compliance. Comparisons with appropriate standards, regulations, and background levels provide the basis for concluding that environmental effects from Laboratory operations are small and do not pose a threat to the public, Laboratory employees, or the environment. 58 refs., 31 figs., 39 tabs.

  9. Environmental surveillance at Los Alamos during 1992

    SciTech Connect

    Kohen, K.; Stoker, A.; Stone, G.

    1994-07-01

    This report describes the environmental surveillance program at Los Alamos National Laboratory during 1992. The Laboratory routinely monitors for radiation and for radioactive and nonradioactive materials at (or on) Laboratory sites as well as in the surrounding region. LANL uses the monitoring results to determine compliance with appropriate standards and to identify potentially undesirable trends. Data were collected in 1992 to assess external penetrating radiation; quantities of airborne emissions and liquid effluents; concentrations of chemicals and radionuclides in ambient air, surface waters and groundwaters, municipal water supply, soils and sediments, and foodstuffs; and environmental compliance. Using comparisons with standards, regulations, and background levels, this report concludes that environmental effects from Laboratory operations are small and do not pose a demonstrable threat to the public, laboratory employees, or the environment.

  10. The Los Alamos Intense Neutron Source

    SciTech Connect

    Nebel, R.A.; Barnes, D.C.; Bollman, R.; Eden, G.; Morrison, L.; Pickrell, M.M.; Reass, W.

    1997-10-01

    The Intense Neutron Source (INS) is an Inertial Electrostatic Confinement (IEC) fusion device presently under construction at Los Alamos National Laboratory. It is designed to produce 10{sup 11} neutrons per second steady-state using D-T fuel. Phase 1 operation of this device will be as a standard three grid IEC ion focus device. Expected performance has been predicted by scaling from a previous IEC device. Phase 2 operation of this device will utilize a new operating scheme, the Periodically Oscillating Plasma Sphere (POPS). This scheme is related to both the Spherical Reflect Diode and the Oscillating Penning Trap. With this type of operation the authors hope to improve plasma neutron production to about 10{sup 13} neutrons/second.

  11. Environmental analysis of Lower Pueblo/Lower Los Alamos Canyon, Los Alamos, New Mexico

    SciTech Connect

    Ferenbaugh, R.W.; Buhl, T.E.; Stoker, A.K.; Becker, N.M.; Rodgers, J.C.; Hansen, W.R.

    1994-12-01

    The radiological survey of the former radioactive waste treatment plant site (TA-45), Acid Canyon, Pueblo Canyon, and Los Alamos Canyon found residual contamination at the site itself and in the channel and banks of Acid, Pueblo, and lower Los Alamos Canyons all the way to the Rio Grande. The largest reservoir of residual radioactivity is in lower Pueblo Canyon, which is on DOE property. However, residual radioactivity does not exceed proposed cleanup criteria in either lower Pueblo or lower Los Alamos Canyons. The three alternatives proposed are (1) to take no action, (2) to construct a sediment trap in lower Pueblo Canyon to prevent further transport of residual radioactivity onto San Ildefonso Indian Pueblo land, and (3) to clean the residual radioactivity from the canyon system. Alternative 2, to cleanup the canyon system, is rejected as a viable alternative. Thousands of truckloads of sediment would have to be removed and disposed of, and this effort is unwarranted by the low levels of contamination present. Residual radioactivity levels, under either present conditions or projected future conditions, will not result in significant radiation doses to persons exposed. Modeling efforts show that future transport activity will not result in any residual radioactivity concentrations higher than those already existing. Thus, although construction of a sediment trap in lower Pueblo Canyon is a viable alternative, this effort also is unwarranted, and the no-action alternative is the preferred alternative.

  12. Environmental surveillance at Los Alamos during 2009

    SciTech Connect

    Fuehne, David; Poff, Ben; Hjeresen, Denny; Isaacson, John; Johnson, Scot; Morgan, Terry; Paulson, David; Salzman, Sonja; Rogers, David

    2010-09-30

    Environmental Surveillance at Los Alamos reports are prepared annually by the Los Alamos National Laboratory (the Laboratory) environmental organization, as required by US Department of Energy Order 5400.1, General Environmental Protection Program, and US Department of Energy Order 231.1A, Environment, Safety, and Health Reporting. These annual reports summarize environmental data that are used to determine compliance with applicable federal, state, and local environmental laws and regulations, executive orders, and departmental policies. Additional data, beyond the minimum required, are also gathered and reported as part of the Laboratory’s efforts to ensure public safety and to monitor environmental quality at and near the Laboratory. Chapter 1 provides an overview of the Laboratory’s major environmental programs and explains the risks and the actions taken to reduce risks at the Laboratory from environmental legacies and waste management operations. Chapter 2 reports the Laboratory’s compliance status for 2009. Chapter 3 provides a summary of the maximum radiological dose the public and biota populations could have potentially received from Laboratory operations and discusses chemical exposures. The environmental surveillance and monitoring data are organized by environmental media (air in Chapter 4; water and sediments in Chapters 5 and 6; soils in Chapter 7; and foodstuffs and biota in Chapter 8) in a format to meet the needs of a general and scientific audience. Chapter 9 provides a summary of the status of environmental restoration work around LANL. The new Chapter 10 describes the Laboratory’s environmental stewardship efforts and provides an overview of the health of the Rio Grande. A glossary and a list of acronyms and abbreviations are in the back of the report. Appendix A explains the standards for environmental contaminants, Appendix B explains the units of measurements used in this report, Appendix C describes the Laboratory’s technical

  13. Environmental surveillance at Los Alamos during 2008

    SciTech Connect

    Fuehne, David; Gallagher, Pat; Hjeresen, Denny; Isaacson, John; Johson, Scot; Morgan, Terry; Paulson, David; Rogers, David

    2009-09-30

    Environmental Surveillance at Los Alamos reports are prepared annually by the Los Alamos National Laboratory (the Laboratory) Environmental Programs Directorate, as required by US Department of Energy Order 450.1, General Environmental Protection Program, and US Department of Energy Order 231.1A, Environment, Safety, and Health Reporting. These annual reports summarize environmental data that are used to determine compliance with applicable federal, state, and local environmental laws and regulations, executive orders, and departmental policies. Additional data, beyond the minimum required, are also gathered and reported as part of the Laboratory’s efforts to ensure public safety and to monitor environmental quality at and near the Laboratory. Chapter 1 provides an overview of the Laboratory’s major environmental programs and explains the risks and the actions taken to reduce risks at the Laboratory from environmental legacies and waste management operations. Chapter 2 reports the Laboratory’s compliance status for 2007. Chapter 3 provides a summary of the maximum radiological dose the public and biota populations could have potentially received from Laboratory operations and discusses chemical exposures. The environmental surveillance and monitoring data are organized by environmental media (Chapter 4, air; Chapters 5 and 6, water and sediments; Chapter 7, soils; and Chapter 8, foodstuffs and biota) in a format to meet the needs of a general and scientific audience. Chapter 9 provides a summary of the status of environmental restoration work around LANL. A glossary and a list of acronyms and abbreviations are in the back of the report. Appendix A explains the standards for environmental contaminants, Appendix B explains the units of measurements used in this report, Appendix C describes the Laboratory’s technical areas and their associated programs, and Appendix D provides web links to more information.

  14. Environmental surveillance at Los Alamos during 2005

    SciTech Connect

    2006-09-30

    Environmental Surveillance at Los Alamos reports are prepared annually by the Los Alamos National Laboratory (LANL or the Laboratory) environmental organization, as required by US Department of Energy Order 5400.1, General Environmental Protection Program, and US Department of Energy Order 231.IA, Environment, Safety, and Health Reporting. These annual reports summarize environmental data that are used to determine compliance with applicable federal, state, and local environmental laws and regulations, executive orders, and departmental policies. Additional data, beyond the minimum required, are also gathered and reported as part of the Laboratory's efforts to ensure public safety and to monitor environmental quality at and near the Laboratory. Chapter 1 provides an overview of the Laboratory's major environmental programs. Chapter 2 reports the Laboratory's compliance status for 2005. Chapter 3 provides a summary of the maximum radiological dose the public and biota populations could have potentially received from Laboratory operations. The environmental surveillance and monitoring data are organized by environmental media (Chapter 4, Air; Chapters 5 and 6, Water and Sediments; Chapter 7, Soils; and Chapter 8, Foodstuffs and Biota) in a format to meet the needs of a general and scientific audience. Chapter 9, new for this year, provides a summary of the status of environmental restoration work around LANL. A glossary and a list ofacronyms and abbreviations are in the back of the report. Appendix A explains the standards for environmental contaminants, Appendix B explains the units of measurements used in this report, Appendix C describes the Laboratory's technical areas and their associated programs, and Appendix D provides web links to more information.

  15. Synthesis, characterization and antibacterial activity of a tridentate Schiff base derived from cephalothin and sulfadiazine, and its transition metal complexes.

    PubMed

    Anacona, J R; Noriega, Natiana; Camus, Juan

    2015-02-25

    Metal(II) coordination compounds of a cephalothin Schiff base (H2L) derived from the condensation of cephalothin antibiotic with sulfadiazine were synthesized. The Schiff base ligand, mononuclear [ML(H2O)3] (M(II)=Mn,Co,Ni,Zn) complexes and magnetically diluted dinuclear copper(II) complex [CuL(H2O)3]2 were characterized by several techniques, including elemental and thermal analysis, molar conductance and magnetic susceptibility measurements, electronic, FT-IR, EPR and (1)H NMR spectral studies. The cephalothin Schiff base ligand H2L behaves as a dianionic tridentate NOO chelating agent. The biological applications of complexes have been studied on two bacteria strains (Escherichia coli and Staphylococcus aureus) by agar diffusion disc method.

  16. Click N-benzyl iminodiacetic acid: novel silica-based tridentate zwitterionic stationary phase for hydrophilic interaction liquid chromatography.

    PubMed

    Yin, Wei; Chai, Huihui; Liu, Renhua; Chu, Changhu; Palasota, John A; Cai, Xiaohui

    2015-01-01

    Iminodiacetic acid (IDA) is dicarboxylic acid amine, which may produce stronger interaction with polar or charged compounds than bidentate α,β-amino acid. In this article, a novel type of tridentate zwitterionic HILIC stationary phase was prepared by covalently bonding N-benzyl IDA on silica gel via copper(I) catalyzed Huisgen azide-alkyne 1,3-dipolar cycloaddition (CuAAC). The structure of this stationary phase and all related intermediates was confirmed by NMR, FT-IR, MS spectrum and elemental analysis. The new stationary phase showed good HILIC characteristics and high column efficiency (the theoretical plate number is up to 44000 plates m(-1) in the case of guanosine) in the application of separation of polar compounds, including organic acids, organic bases, as well as highly polar and hydrophilic compounds, such as cephalosporins and carbapenems. Most of them displayed good peak shape and selectivity. PMID:25476290

  17. Mercury: A second-generation KrF laser for inertial fusion research

    SciTech Connect

    Bigio, I.J.; York, G.; McLeod, J.; Czuchlewski, J.; Rose, E.; Hanson, D.E.; Kurnit, N.A.; McCown, A.

    1992-10-01

    The ``Mercury`` KrF laser facility at Los Alamos is being built with the benefit of lessons learned from the Aurora KrF laser. An increased understanding of KrF laser engineering, and the designed implementation of system flexibility, will permit Mercury to serve as a testbed for a variety of advanced KrF technology concepts.

  18. Mercury: A second-generation KrF laser for inertial fusion research

    SciTech Connect

    Bigio, I.J.; York, G.; McLeod, J.; Czuchlewski, J.; Rose, E.; Hanson, D.E.; Kurnit, N.A.; McCown, A.

    1992-01-01

    The Mercury'' KrF laser facility at Los Alamos is being built with the benefit of lessons learned from the Aurora KrF laser. An increased understanding of KrF laser engineering, and the designed implementation of system flexibility, will permit Mercury to serve as a testbed for a variety of advanced KrF technology concepts.

  19. Explosive Flux Compression: 50 Years of Los Alamos Activities

    SciTech Connect

    Fowler, C.M.; Thomson, D.B.; Garn, W.B.

    1998-10-18

    Los Alamos flux compression activities are surveyed, mainly through references in view of space limitations. However, two plasma physics programs done with Sandia National Laboratory are discussed in more detail.

  20. Environmental Surveillance at Los Alamos during 2007

    SciTech Connect

    2008-09-30

    Environmental Surveillance at Los Alamos reports are prepared annually by the Los Alamos National Laboratory (the Laboratory) Environmental Directorate, as required by US Department of Energy Order 450.1, General Environmental Protection Program, and US Department of Energy Order 231.1A, Environment, Safety, and Health Reporting. These annual reports summarize environmental data that are used to determine compliance with applicable federal, state, and local environmental laws and regulations, executive orders, and departmental policies. Additional data, beyond the minimum required, are also gathered and reported as part of the Laboratory’s efforts to ensure public safety and to monitor environmental quality at and near the Laboratory. Chapter 1 provides an overview of the Laboratory’s major environmental programs and explains the risks and the actions taken to reduce risks at the Laboratory from environmental legacies and waste management operations. Chapter 2 reports the Laboratory’s compliance status for 2007. Chapter 3 provides a summary of the maximum radiological dose the public and biota populations could have potentially received from Laboratory operations and discusses chemical exposures. The environmental surveillance and monitoring data are organized by environmental media (Chapter 4, air; Chapters 5 and 6, water and sediments; Chapter 7, soils; and Chapter 8, foodstuffs and biota) in a format to meet the needs of a general and scientific audience. Chapter 9 provides a summary of the status of environmental restoration work around LANL. A glossary and a list of acronyms and abbreviations are in the back of the report. Appendix A explains the standards for environmental contaminants, Appendix B explains the units of measurements used in this report, Appendix C describes the laboratory’s technical areas and their associated programs, and Appendix D provides web links to more information. In printed copies of this report or Executive Summary, we have

  1. Los Alamos low-level waste performance assessment status

    SciTech Connect

    Wenzel, W.J.; Purtymun, W.D.; Dewart, J.M.; Rodgers, J.E.

    1986-06-01

    This report reviews the documented Los Alamos studies done to assess the containment of buried hazardous wastes. Five sections logically present the environmental studies, operational source terms, transport pathways, environmental dosimetry, and computer model development and use. This review gives a general picture of the Los Alamos solid waste disposal and liquid effluent sites and is intended for technical readers with waste management and environmental science backgrounds but without a detailed familiarization with Los Alamos. The review begins with a wide perspective on environmental studies at Los Alamos. Hydrology, geology, and meteorology are described for the site and region. The ongoing Laboratory-wide environmental surveillance and waste management environmental studies are presented. The next section describes the waste disposal sites and summarizes the current source terms for these sites. Hazardous chemical wastes and liquid effluents are also addressed by describing the sites and canyons that are impacted. The review then focuses on the transport pathways addressed mainly in reports by Healy and Formerly Utilized Sites Remedial Action Program. Once the source terms and potential transport pathways are described, the dose assessment methods are addressed. Three major studies, the waste alternatives, Hansen and Rogers, and the Pantex Environmental Impact Statement, contributed to the current Los Alamos dose assessment methodology. Finally, the current Los Alamos groundwater, surface water, and environmental assessment models for these mesa top and canyon sites are described.

  2. NIST--Los Alamos racetrack microtron status

    SciTech Connect

    Wilson, M.A.; Ayres, R.L.; Cutler, R.I.; Debenham, P.H.; Lindstrom, E.R.; Mohr, D.L.; Penner, S.; Rose, J.E.; Young, L.M.

    1988-01-01

    The NIST-Los Alamos Racetrack Microtron (RTM) is designed to deliver a low-emittance electron beam of up to 0.5 mA cw over an energy range of 17 MeV to 185 MeV. Fed by a 5 MeV injector, the RTM contains two 180/degree/ end magnets that recirculate the beam up to 15 times through a 12 MeV RF linac. The linac, which operates in a standing-wave mode at 2380 MHz, has been tested to nearly full RF power. At present, the injector has undergone beam tests, and the beam transport system is complete through the 12 MeV linac. A temporary beam line has been installed at the exit of one end magnet to measure the beam energy, energy spread, and emittance after one pass through the accelerator. Preliminary results indicate that the accelerated beam energy spread and emittance are within design goals. 4 refs., 7 figs.

  3. Historic Manhattan Project Sites at Los Alamos

    SciTech Connect

    McGehee, Ellen

    2014-05-22

    The Manhattan Project laboratory constructed at Los Alamos, New Mexico, beginning in 1943, was intended from the start to be temporary and to go up with amazing speed. Because most of those WWII-era facilities were built with minimal materials and so quickly, much of the original infrastructure was torn down in the late '40s and early '50s and replaced by more permanent facilities. However, a few key facilities remained, and are being preserved and maintained for historic significance. Four such sites are visited briefly in this video, taking viewers to V-Site, the buildings where the first nuclear explosive device was pre-assembled in preparation for the Trinity Test in Southern New Mexico. Included is another WWII area, Gun Site. So named because it was the area where scientists and engineers tested the so-called "gun method" of assembling nuclear materials -- the fundamental design of the Little Boy weapon that was eventually dropped on Hiroshima. The video also goes to Pajarito Site, home of the "Slotin Building" and "Pond Cabin." The Slotin Building is the place where scientist Louis Slotin conducted a criticality experiment that went awry in early 1946, leading to his unfortunate death, and the Pond Cabin served the team of eminent scientist Emilio Segre who did early chemistry work on plutonium that ultimately led to the Fat Man weapon.

  4. Expanded recycling at Los Alamos National Laboratory

    SciTech Connect

    Betschart, J.F.; Malinauskas, L.; Burns, M.

    1996-07-01

    The Pollution Prevention Program Office has increased recycling activities, reuse, and options to reduce the solid waste streams through streamlining efforts that applied best management practices. The program has prioritized efforts based on volume and economic considerations and has greatly increased Los Alamos National Laboratory`s (LANL`s) recycle volumes. The Pollution Prevention Program established and chairs a Solid Waste Management Solutions Group to specifically address and solve problems in nonradioactive, Resource Conservation and Recovery Act (RCRA), state-regulated, and sanitary and industrial waste streams (henceforth referred to as sanitary waste in this paper). By identifying materials with recycling potential, identifying best management practices and pathways to return materials for reuse, and introducing the concept and practice of {open_quotes}asset management,{open_quotes} the Group will divert much of the current waste stream from disposal. This Group is developing procedures, agreements, and contracts to stage, collect, sort, segregate, transport and process materials, and is also garnering support for the program through the involvement of upper management, facility managers, and generators.

  5. Historic Manhattan Project Sites at Los Alamos

    ScienceCinema

    McGehee, Ellen

    2016-07-12

    The Manhattan Project laboratory constructed at Los Alamos, New Mexico, beginning in 1943, was intended from the start to be temporary and to go up with amazing speed. Because most of those WWII-era facilities were built with minimal materials and so quickly, much of the original infrastructure was torn down in the late '40s and early '50s and replaced by more permanent facilities. However, a few key facilities remained, and are being preserved and maintained for historic significance. Four such sites are visited briefly in this video, taking viewers to V-Site, the buildings where the first nuclear explosive device was pre-assembled in preparation for the Trinity Test in Southern New Mexico. Included is another WWII area, Gun Site. So named because it was the area where scientists and engineers tested the so-called "gun method" of assembling nuclear materials -- the fundamental design of the Little Boy weapon that was eventually dropped on Hiroshima. The video also goes to Pajarito Site, home of the "Slotin Building" and "Pond Cabin." The Slotin Building is the place where scientist Louis Slotin conducted a criticality experiment that went awry in early 1946, leading to his unfortunate death, and the Pond Cabin served the team of eminent scientist Emilio Segre who did early chemistry work on plutonium that ultimately led to the Fat Man weapon.

  6. Saving Water at Los Alamos National Laboratory

    SciTech Connect

    Erickson, Andy

    2015-03-16

    Los Alamos National Laboratory decreased its water usage by 26 percent in 2014, with about one-third of the reduction attributable to using reclaimed water to cool a supercomputing center. The Laboratory's goal during 2014 was to use only re-purposed water to support the mission at the Strategic Computing Complex. Using reclaimed water from the Sanitary Effluent Reclamation Facility, or SERF, substantially decreased water usage and supported the overall mission. SERF collects industrial wastewater and treats it for reuse. The reclamation facility contributed more than 27 million gallons of re-purposed water to the Laboratory's computing center, a secured supercomputing facility that supports the Laboratory’s national security mission and is one of the institution’s larger water users. In addition to the strategic water reuse program at SERF, the Laboratory reduced water use in 2014 by focusing conservation efforts on areas that use the most water, upgrading to water-conserving fixtures, and repairing leaks identified in a biennial survey.

  7. Investigation of stimulated raman scattering using short-pulse diffraction limited laser beam near the instability threshold

    SciTech Connect

    Kline, John L; Montgomery, David S; Flippo, Kirk A; Rose, Harvey A; Yin, L; Albright, B J; Johnson, R P; Shimada, T; Bowers, K; Rousseaux, C; Tassin, V; Baton, S D; Amiranoff, F; Hardin, R A

    2008-01-01

    Short pulse laser plasma interaction experiments using diffraction limited beams provide an excellent platform to investigate the fundamental physics of Stimulated Raman Scattering. Detailed understanding of these laser plasma instabilities impacts the current inertial confinement fusion ignition designs and could potentially impact fast ignition when higher energy lasers are used with longer pulse durations ( > 1 kJ and> 1 ps). Using short laser pulses, experiments can be modeled over the entire interaction time of the laser using particle-in-cell codes to validate our understanding quantitatively. Experiments have been conducted at the Trident laser facility and the LULI (Laboratoire pour l'Utilisation des Lasers Intenses) to investigate stimulated Raman scattering near the threshold of the instability using 527 nm and 1059 nm laser light respectively with 1.5-3.0 ps pulses. In both experiments, the interaction beam was focused into a pre-ionized He gas-jet plasma. Measurements of the reflectivity as a function of intensity and k{lambda}{sub D} were completed at the Trident laser facility. At LULI, a 300 fs Thomson scattering probe is used to directly measure the density fluctuations of the driven electron plasma and ion acoustic waves. Work is currently underway comparing the results of the experiments with simulations using the VPIC [K. J. Bowers, et at., Phys. Plasmas, 15 055703 (2008)] particle-in-cell code. Details of the experimental results are presented in this manuscript.

  8. Tridentate Lewis Acids Based on 1,3,5-Trisilacyclohexane Backbones and an Example of Their Host-Guest Chemistry.

    PubMed

    Weisheim, Eugen; Reuter, Christian G; Heinrichs, Peter; Vishnevskiy, Yury V; Mix, Andreas; Neumann, Beate; Stammler, Hans-Georg; Mitzel, Norbert W

    2015-08-24

    Directed tridentate Lewis acids based on the 1,3,5-trisilacyclohexane skeleton with three ethynyl groups [CH2Si(Me)(C2H)]3 were synthesised and functionalised by hydroboration with HB(C6F5)2, yielding the ethenylborane {CH2Si(Me)[C2H2B(C6F5)2]}3, and by metalation with gallium and indium organyls affording {CH2Si(Me)[C2M(R)2]}3 (M = Ga, In, R = Me, Et). In the synthesis of the backbone the influence of substituents (MeO, EtO and iPrO groups at Si) on the orientation of the methyl group was studied with the aim to increase the abundance of the all-cis isomer. New compounds were identified by elemental analyses, multi-nuclear NMR spectroscopy and in some cases by IR spectroscopy. Crystal structures were obtained for cis-trans-[CH2Si(Me)(Cl)]3, all-cis-[CH2Si(Me)(H)]3, all-cis-[CH2Si(Me)(C2H)]3, cis-trans-[CH2Si(Me)(C2H)]3 and all-cis-[CH2Si(Me)(C2SiMe3)]3. A gas-phase electron diffraction experiment for all-cis-[CH2Si(Me)(C2H)]3 provides information on the relative stabilities of the all-equatorial and all-axial form; the first is preferred in both solid and gas phase. The gallium-based Lewis acid {CH2Si(Me)[C2Ga(Et)2]}3 was reacted with a tridentate Lewis base (1,3,5-trimethyl-1,3,5-triazacyclohexane) in an NMR titration experiment. The generated host-guest complexes involved in the equilibria during this reaction were identified by DOSY NMR spectroscopy by comparing measured diffusion coefficients with those of the suitable reference compounds of same size and shape.

  9. Tridentate Lewis Acids Based on 1,3,5-Trisilacyclohexane Backbones and an Example of Their Host-Guest Chemistry.

    PubMed

    Weisheim, Eugen; Reuter, Christian G; Heinrichs, Peter; Vishnevskiy, Yury V; Mix, Andreas; Neumann, Beate; Stammler, Hans-Georg; Mitzel, Norbert W

    2015-08-24

    Directed tridentate Lewis acids based on the 1,3,5-trisilacyclohexane skeleton with three ethynyl groups [CH2Si(Me)(C2H)]3 were synthesised and functionalised by hydroboration with HB(C6F5)2, yielding the ethenylborane {CH2Si(Me)[C2H2B(C6F5)2]}3, and by metalation with gallium and indium organyls affording {CH2Si(Me)[C2M(R)2]}3 (M = Ga, In, R = Me, Et). In the synthesis of the backbone the influence of substituents (MeO, EtO and iPrO groups at Si) on the orientation of the methyl group was studied with the aim to increase the abundance of the all-cis isomer. New compounds were identified by elemental analyses, multi-nuclear NMR spectroscopy and in some cases by IR spectroscopy. Crystal structures were obtained for cis-trans-[CH2Si(Me)(Cl)]3, all-cis-[CH2Si(Me)(H)]3, all-cis-[CH2Si(Me)(C2H)]3, cis-trans-[CH2Si(Me)(C2H)]3 and all-cis-[CH2Si(Me)(C2SiMe3)]3. A gas-phase electron diffraction experiment for all-cis-[CH2Si(Me)(C2H)]3 provides information on the relative stabilities of the all-equatorial and all-axial form; the first is preferred in both solid and gas phase. The gallium-based Lewis acid {CH2Si(Me)[C2Ga(Et)2]}3 was reacted with a tridentate Lewis base (1,3,5-trimethyl-1,3,5-triazacyclohexane) in an NMR titration experiment. The generated host-guest complexes involved in the equilibria during this reaction were identified by DOSY NMR spectroscopy by comparing measured diffusion coefficients with those of the suitable reference compounds of same size and shape. PMID:26213228

  10. Tridentate assembling ligands based on oxazoline and phosphorus donors in dinuclear Pd(I)-Pd(I) complexes.

    PubMed

    Zhang, Jing; Pattacini, Roberto; Braunstein, Pierre

    2009-12-21

    To examine the bonding preferences of potentially tridentate phosphorus, nitrogen donor ligands on a dinuclear metal core, we have studied the coordination of the oxazoline-based ligands bis(4,5-dihydro-2-oxazolylmethyl)phenylphosphine (NPN) and bis(4,4-dimethyl-2-oxazolyl dimethylmethoxy)phenylphosphine (NOPON(Me2)) toward the dinuclear d(9)-d(9) Pd(I) complex [Pd(2)(NCMe)(6)][BF(4)](2). In the dinuclear product [Pd(2)(NPN-N,P,N)(2)](BF(4))(2) (1), in which the Pd-Pd bond length of 2.5489(7) A is rather short, the two interacting metal centers are P,N bridged by two molecules of the NPN ligand, forming two six-membered rings. The other oxazoline ring of each ligand further chelates a Pd center through its nitrogen atom, forming five-membered chelates, as in the mononuclear complex [PdCl(2)(NPN-N,P)] (5). In contrast, the reaction between [Pd(2)(NCMe)(6)](BF(4))(2) and NOPON(Me2) in the presence of LiCl afforded the mononuclear cationic complex [Pd(NOPON(Me2)-N,P,N)Cl](BF(4)) (3), which is also obtained by halide abstraction from [Pd(NOPON(Me2)-N,P)Cl(2)] with NaBF(4). When this reaction was performed in the presence of 1 equiv of t-BuNC, the new dinuclear Pd(I)-Pd(I) complex [Pd(2)Cl(2)(CNt-Bu)(NOPON(Me2)-N,P,N)] (4) was isolated, which can also be obtained from a comproportionation reaction between Pd(II) and Pd(0) complexes. The oxazoline in the P,N bridge is involved in a seven-membered ring moiety, a situation rarely encountered in Pd(I)-Pd(I) chemistry. Its nitrogen atom is coordinated trans to the isonitrile ligand whereas that of the P,N chelate at Pd(1) is trans to Pd(2). The fluxional processes involving the oxazoline moieties of the NPN and NOPON(Me2) ligands in 1 and 4, respectively, were examined by variable-temperature NMR spectroscopy. The crystal structures of 1, 3.0.5CH(3)CN, and 4 have been determined by X-ray diffraction. Prior to this work, relatively few complexes have been reported in the literature in which a potentially tridentate functional

  11. Ruthenium(III) Complexes of Heterocyclic Tridentate (ONN) Schiff Base: Synthesis, Characterization and its Biological Properties as an Antiradical and Antiproliferative Agent

    PubMed Central

    Ejidike, Ikechukwu P.; Ajibade, Peter A.

    2016-01-01

    The current work reports the synthesis, spectroscopic studies, antiradical and antiproliferative properties of four ruthenium(III) complexes of heterocyclic tridentate Schiff base bearing a simple 2′,4′-dihydroxyacetophenone functionality and ethylenediamine as the bridging ligand with RCHO moiety. The reaction of the tridentate ligands with RuCl3·3H2O lead to the formation of neutral complexes of the type [Ru(L)Cl2(H2O)] (where L = tridentate NNO ligands). The compounds were characterized by elemental analysis, UV-vis, conductivity measurements, FTIR spectroscopy and confirmed the proposed octahedral geometry around the Ru ion. The Ru(III) compounds showed antiradical potentials against 2,2-Diphenyl-1-Picrylhydrazyl (DPPH) and 2,2′-azinobis-(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS) radicals, with DPPH scavenging capability in the order: [(PAEBOD)RuCl2] > [(BZEBOD)RuCl2] > [(MOABOD)RuCl2] > [Vit. C] > [rutin] > [(METBOD)RuCl2], and ABTS radical in the order: [(PAEBOD)RuCl2] < [(MOABOD)RuCl2] < [(BZEBOD)RuCl2] < [(METBOD)RuCl2]. Furthermore, in vitro anti-proliferative activity was investigated against three human cancer cell lines: renal cancer cell (TK-10), melanoma cancer cell (UACC-62) and breast cancer cell (MCF-7) by SRB assay. PMID:26742030

  12. Ruthenium(III) Complexes of Heterocyclic Tridentate (ONN) Schiff Base: Synthesis, Characterization and its Biological Properties as an Antiradical and Antiproliferative Agent.

    PubMed

    Ejidike, Ikechukwu P; Ajibade, Peter A

    2016-01-04

    The current work reports the synthesis, spectroscopic studies, antiradical and antiproliferative properties of four ruthenium(III) complexes of heterocyclic tridentate Schiff base bearing a simple 2',4'-dihydroxyacetophenone functionality and ethylenediamine as the bridging ligand with RCHO moiety. The reaction of the tridentate ligands with RuCl₃·3H₂O lead to the formation of neutral complexes of the type [Ru(L)Cl₂(H₂O)] (where L = tridentate NNO ligands). The compounds were characterized by elemental analysis, UV-vis, conductivity measurements, FTIR spectroscopy and confirmed the proposed octahedral geometry around the Ru ion. The Ru(III) compounds showed antiradical potentials against 2,2-Diphenyl-1-Picrylhydrazyl (DPPH) and 2,2'-azinobis-(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS) radicals, with DPPH scavenging capability in the order: [(PAEBOD)RuCl₂] > [(BZEBOD)RuCl₂] > [(MOABOD)RuCl₂] > [Vit. C] > [rutin] > [(METBOD)RuCl₂], and ABTS radical in the order: [(PAEBOD)RuCl₂] < [(MOABOD)RuCl₂] < [(BZEBOD)RuCl₂] < [(METBOD)RuCl₂]. Furthermore, in vitro anti-proliferative activity was investigated against three human cancer cell lines: renal cancer cell (TK-10), melanoma cancer cell (UACC-62) and breast cancer cell (MCF-7) by SRB assay.

  13. Ruthenium(III) Complexes of Heterocyclic Tridentate (ONN) Schiff Base: Synthesis, Characterization and its Biological Properties as an Antiradical and Antiproliferative Agent.

    PubMed

    Ejidike, Ikechukwu P; Ajibade, Peter A

    2016-01-01

    The current work reports the synthesis, spectroscopic studies, antiradical and antiproliferative properties of four ruthenium(III) complexes of heterocyclic tridentate Schiff base bearing a simple 2',4'-dihydroxyacetophenone functionality and ethylenediamine as the bridging ligand with RCHO moiety. The reaction of the tridentate ligands with RuCl₃·3H₂O lead to the formation of neutral complexes of the type [Ru(L)Cl₂(H₂O)] (where L = tridentate NNO ligands). The compounds were characterized by elemental analysis, UV-vis, conductivity measurements, FTIR spectroscopy and confirmed the proposed octahedral geometry around the Ru ion. The Ru(III) compounds showed antiradical potentials against 2,2-Diphenyl-1-Picrylhydrazyl (DPPH) and 2,2'-azinobis-(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS) radicals, with DPPH scavenging capability in the order: [(PAEBOD)RuCl₂] > [(BZEBOD)RuCl₂] > [(MOABOD)RuCl₂] > [Vit. C] > [rutin] > [(METBOD)RuCl₂], and ABTS radical in the order: [(PAEBOD)RuCl₂] < [(MOABOD)RuCl₂] < [(BZEBOD)RuCl₂] < [(METBOD)RuCl₂]. Furthermore, in vitro anti-proliferative activity was investigated against three human cancer cell lines: renal cancer cell (TK-10), melanoma cancer cell (UACC-62) and breast cancer cell (MCF-7) by SRB assay. PMID:26742030

  14. High-resolution X-ray spectroscopy of hollow atoms created in plasma heated by subpicosecond laser radiation

    SciTech Connect

    Faenov, A.Ya.; Magunov, A.I.; Pikuz, T.A.

    1997-10-01

    The investigations of ultrashort (0.4-0.6 ps) laser pulse radiation interaction with solid targets have been carried out. The Trident subpicosecond laser system was used for plasma creation. The X-ray plasma emission was investigated with the help of high-resolution spectrographs with spherically bent mica crystals. It is shown that when high contrast ultrashort laser pulses were used for plasma heating its emission spectra could not be explained in terms of commonly used theoretical models, and transitions in so called {open_quotes}hollow atoms{close_quotes} must be taken into account for adequate description of plasma radiation.

  15. Recent UCN source developments at Los Alamos

    SciTech Connect

    Seestrom, S.J.; Anaya, J.M.; Bowles, T.J.

    1998-12-01

    The most intense sources of ultra cold neutrons (UCN) have bee built at reactors where the high average thermal neutron flux can overcome the low UCN production rate to achieve usable densities of UCN. At spallation neutron sources the average flux available is much lower than at a reactor, though the peak flux can be comparable or higher. The authors have built a UCN source that attempts to take advantage of the high peak flux available at the short pulse spallation neutron source at the Los Alamos Neutron Science Center (LANSCE) to generate a useful number of UCN. In the source UCN are produced by Doppler-shifted Bragg scattering of neutrons to convert 400-m/s neutrons down into the UCN regime. This source was initially tested in 1996 and various improvements were made based on the results of the 1996 running. These improvements were implemented and tested in 1997. In sections 2 and 3 they discuss the improvements that have been made and the resulting source performance. Recently an even more interesting concept was put forward by Serebrov et al. This involves combining a solid Deuterium UCN source, previously studied by Serebrov et al., with a pulsed spallation source to achieve world record UCN densities. They have initiated a program of calculations and measurements aimed at verifying the solid Deuterium UCN source concept. The approach has been to develop an analytical capability, combine with Monte Carlo calculations of neutron production, and perform benchmark experiments to verify the validity of the calculations. Based on the calculations and measurements they plan to test a modified version of the Serebrov UCN factory. They estimate that they could produce over 1,000 UCN/cc in a 15 liter volume, using 1 {micro}amp of 800 MeV protons for two seconds every 500 seconds. They will discuss the result UCN production measurements in section 4.

  16. Waste characterization at Los Alamos National Laboratory

    SciTech Connect

    Corpion, J.C.; Grieggs, A.R.

    1991-01-01

    Most industries generate limited types of solid wastes of a result of their manufacturing processes. The Los Alamos National Laboratory (LANL), a research and development facility, generates a large variety of solid wastes, some exotic. Over 50,000 distinct waste streams are currently generated in the 43 square mile area defining LANL. These wastes include refuse, medical, infectious, hazardous, radioactive, and mixed wastes. LANL is subject to federal and State oversight on matters concerning management of solid wastes. In order to assure regulatory agencies such as the New Mexico Environment Department (NMED) and the US Environmental Protection Agency (EPA) that the Laboratory is properly managing and disposing all solid wastes. LANL has undertaken an extensive waste characterization program to identify sources and ultimate disposition of all solid wastes. Given the number of solid waste streams expected, LANL has taken a two-pronged approach to characterizing wastes: (a) physical identification of all sources of solid wastes including interviews with waste generators; and (b) characterization of wastes from the point of generation. The former approach consists of canvassing all structures within the LANL complex, interviewing waste generators, and identifying sources of waste generation. Data gathered by these interviews are compiled in a database in order to identify the types and rates of waste generation and correct mismanagement of wastes identified during the interviews. The latter approach consists of characterizing all solid wastes which are controlled administratively or subject to stricter controls than municipal solid wastes (i.e., infectious, hazardous, radioactive, and mixed wastes). This characterization forms the basis by which LANL will manage solid waste in accordance to NMED/EPA regulations and US Department of Energy Orders. 8 refs., 3 figs.

  17. Toward equatorial planarity about uranyl: synthesis and structure of tridentate nitrogen-donor {UO2}2+ complexes.

    PubMed

    Copping, Roy; Jeon, Byoungseon; Pemmaraju, C Das; Wang, Shuao; Teat, Simon J; Janousch, Markus; Tyliszczak, Tolek; Canning, Andrew; Grønbech-Jensen, Niels; Prendergast, David; Shuh, David K

    2014-03-01

    The reaction of UO2Cl2·3THF with the tridentate nitrogen donor ligand 2,6-bis(2-benzimidazolyl)pyridine (H2BBP) in pyridine leads to the formation of three different complexes: [(UO2)(H2BBP)Cl2] (1), [(UO)2(HBBP)(Py)Cl] (2), and [(UO2)(BBP)(Py)2] (3) after successive deprotonation of H2BBP with a strong base. Crystallographic determination of 1-3 reveals that increased charge through ligand deprotonation and displacement of chloride leads to equatorial planarity about uranyl as well as a more compact overall coordination geometry. Near-Edge X-ray Absorption Fine Structure (NEXAFS) spectra of 1-3 at the U-4d edges have been recorded using a soft X-ray Scanning Transmission X-ray Microscope (STXM) and reveal the uranium 4d5/2 and 4d3/2 transitions at energies associated with uranium in the hexavalent oxidation state. First-principles Density Functional Theory (DFT) electronic structure calculations for the complexes have been performed to determine and validate the coordination characteristics, which correspond well to the experimental results.

  18. Highly luminescent charge-neutral europium(iii) and terbium(iii) complexes with tridentate nitrogen ligands.

    PubMed

    Senthil Kumar, Kuppusamy; Schäfer, Bernhard; Lebedkin, Sergei; Karmazin, Lydia; Kappes, Manfred M; Ruben, Mario

    2015-09-21

    We report on the synthesis of tridentate-nitrogen pyrazole-pyridine-tetrazole (L(1)H) and pyrazole-pyridine-triazole (L(2)H) ligands and their complexation with lanthanides (Ln = Gd(iii), Eu(iii) and Tb(iii)) resulting in stable, charge-neutral complexes Ln(L(1))3 and Ln(L(2))3, respectively. X-ray crystallographic analysis of the complexes with L(1) ligands revealed tricapped trigonal coordination geometry around the lanthanide ions. All complexes show bright photoluminescence (PL) in the solid state, indicating efficient sensitization of the lanthanide emission via the triplet states of the ligands. In particular, the terbium complexes show high PL quantum yields of 65 and 59% for L(1) and L(2), respectively. Lower PL efficiencies of the europium complexes (7.5 and 9%, respectively) are attributed to large energy gaps between the triplet states of the ligands and accepting levels of Eu(iii). The triplet state energy can be reduced by introducing an electron withdrawing (EW) group at the 4 position of the pyridine ring. Such substitution of L(1)H with a carboxylic ester (COOMe) EW group leads to a europium complex with increased PL quantum yield of 31%. A comparatively efficient PL of the complexes dissolved in ethanol indicates that the lanthanide ions are shielded against nonradiative deactivation via solvent molecules.

  19. Synthesis, spectral characterization and DNA bindings of tridentate N2O donor Schiff base metal(II) complexes.

    PubMed

    Kathiresan, Sellamuthu; Anand, Thangavel; Mugesh, Subramanian; Annaraj, Jamespandi

    2015-07-01

    To evaluate the biological preference of synthetic small drugs towards DNA target, new metal based chemotherapeutic agents of Cu(II), Co(II), Ni(II) and Zn(II), 2,4-diiodo-6-((pyridin-2-ylmethylimino)methyl)phenol (L) Schiff base complexes (1, 2, 3 &4) having N,N,O donor system respectively were synthesized and thoroughly characterized. The IR results confirmed the tridentate binding of the ligand with metal centre during complexation and reflects the proposed structure. The density function theory calculations were also used to further investigate the electronic structure and properties of ligand and complexes. The preliminary investigation of herring Sperm (HS-DNA) interaction propensity of complexes 1-4 were carried out in Tris-HCl buffer at pH 7.1 to demonstrate their mode of interactions. The obtained results reveal that these complexes significantly interact with DNA on the grooves, further, this observed mode of interactions was also confirmed by molecular docking evaluations. The complexes 1-4 were also screened for antimicrobial evaluations which demonstrated that their significant activity against various human pathogens. The cleavage studies with pBR322 plasmid DNA revealed higher nuclease activity of 1 as compared to other complexes. PMID:26000741

  20. Synthesis, structural, thermal studies and biological activity of a tridentate Schiff base ligand and their transition metal complexes.

    PubMed

    Abd El-halim, Hanan F; Omar, M M; Mohamed, Gehad G

    2011-01-01

    Schiff base (L) ligand is prepared via condensation of pyridine-2,6-dicarboxaldehyde with -2-aminopyridine. The ligand and its metal complexes are characterized based on elemental analysis, mass, IR, solid reflectance, magnetic moment, molar conductance, and thermal analyses (TG, DTG and DTA). The molar conductance reveals that all the metal chelates are non-electrolytes. IR spectra shows that L ligand behaves as neutral tridentate ligand and bind to the metal ions via the two azomethine N and pyridine N. From the magnetic and solid reflectance spectra, it is found that the geometrical structures of these complexes are octahedral (Cr(III), Fe(III), Co(II), Ni(II), Cu(II), and Th(IV)) and tetrahedral (Mn(II), Cd(II), Zn(II), and UO2(II)). The thermal behaviour of these chelates shows that the hydrated complexes losses water molecules of hydration in the first step followed immediately by decomposition of the anions and ligand molecules in the subsequent steps. The activation thermodynamic parameters, such as, E*, ΔH*, ΔS* and ΔG* are calculated from the DTG curves using Coats-Redfern method. The synthesized ligand, in comparison to their metal complexes also was screened for its antibacterial activity against bacterial species, Escherichia coli, Pseudomonas aeruginosa, Staphylococcus pyogones and Fungi (Candida). The activity data shows that the metal complexes to be more potent/antibacterial than the parent Schiff base ligand against one or more bacterial species.

  1. Binuclear Cu(II) and Co(II) Complexes of Tridentate Heterocyclic Shiff Base Derived from Salicylaldehyde with 4-Aminoantipyrine

    PubMed Central

    Al-Obaidi, Omar Hamad Shihab

    2012-01-01

    New binuclear Co(II) and Co(II) complexes of ONO tridentate heterocyclic Schiff base derived from 4-aminoantipyrine with salicylaldehyde have been synthesized and characterized on the bases of elemental analysis, UV-Vis., FT-IR, and also by aid of molar conductivity measurements, magnetic measurements, and melting points. It has been found that the Schiff bases with Cu(II) or Co(II) ion forming binuclear complexes on (1 : 1) “metal : ligand” stoichiometry. The molar conductance measurements of the complexes in DMSO correspond to be nonelectrolytic nature for all prepared complexes. Distorted octahedral environment is suggested for metal complexes. A theoretical treatment of the formation of complexes in the gas phase was studied, and this was done by using the HyperChem-6 program for the molecular mechanics and semi-empirical calculations. The free ligand and its complexes have been tested for their antibacterial activities against two types of human pathogenic bacteria: the first type (Staphylococcus aureus) is Gram positive and the second type (Escherichia coli) is Gram negative (by using agar well diffusion method). Finally, it was found that compounds show different activity of inhibition on growth of the bacteria. PMID:22611346

  2. Spectral characterization, electrochemical and anticancer studies on some metal(II) complexes containing tridentate quinoxaline Schiff base

    NASA Astrophysics Data System (ADS)

    Chellaian, Justin Dhanaraj; Johnson, Jijo

    2014-06-01

    Co(II), Ni(II), Cu(II) and Zn(II) complexes of a tridentate ONO donor Schiff base ligand derived from 3-(2-aminoethylamino)quinoxalin-2(1H)-one were synthesized. The ligand and its metal complexes were characterized using elemental analysis, molar conductance, IR, 1H NMR, mass, magnetic susceptibility, electronic spectra and ESR spectral studies. Electrochemical behavior of the synthesized compounds was studied using cyclic voltammetry. The grain size of the synthesized compounds was determined by powder XRD. The Schiff base and its complexes have been screened for their antimicrobial activities against the bacterial species E. coli, K. pneumoniae, P. aeruginosa and S. aureus; fungal species include, A. niger, and C. albicans by disc diffusion method. The results show that the complexes have higher activity than the free ligand. The interaction of the complexes with calf thymus DNA (CT DNA) has been investigated by electronic absorption method. Furthermore, the DNA cleavage activity of the complexes was studied using agarose gel electrophoresis. In vitro anticancer studies of the ligand and its complexes using MTT assay was also done.

  3. Synthesis, spectral characterization and DNA bindings of tridentate N2O donor Schiff base metal(II) complexes.

    PubMed

    Kathiresan, Sellamuthu; Anand, Thangavel; Mugesh, Subramanian; Annaraj, Jamespandi

    2015-07-01

    To evaluate the biological preference of synthetic small drugs towards DNA target, new metal based chemotherapeutic agents of Cu(II), Co(II), Ni(II) and Zn(II), 2,4-diiodo-6-((pyridin-2-ylmethylimino)methyl)phenol (L) Schiff base complexes (1, 2, 3 &4) having N,N,O donor system respectively were synthesized and thoroughly characterized. The IR results confirmed the tridentate binding of the ligand with metal centre during complexation and reflects the proposed structure. The density function theory calculations were also used to further investigate the electronic structure and properties of ligand and complexes. The preliminary investigation of herring Sperm (HS-DNA) interaction propensity of complexes 1-4 were carried out in Tris-HCl buffer at pH 7.1 to demonstrate their mode of interactions. The obtained results reveal that these complexes significantly interact with DNA on the grooves, further, this observed mode of interactions was also confirmed by molecular docking evaluations. The complexes 1-4 were also screened for antimicrobial evaluations which demonstrated that their significant activity against various human pathogens. The cleavage studies with pBR322 plasmid DNA revealed higher nuclease activity of 1 as compared to other complexes.

  4. Design, synthesis and excited-state properties of mononuclear Ru(II) complexes of tridentate heterocyclic ligands.

    PubMed

    Pal, Amlan K; Hanan, Garry S

    2014-09-01

    Artificial photosynthetic systems that contain light-harvesting coordination complexes may one day replace conventional non-renewable sources of energy with renewable solar energy sources. Light-Harvesting Complexes (LHC) are important components of natural photosynthetic systems and are also sought after in artificial systems as well. Polynuclear photoactive complexes are therefore very attractive, and those based on stereogenic [Ru(2,2'-bipyridine)3](2+) are photophysically appealing, but difficult to obtain in a stereochemically pure form. On the other hand, polynuclear complexes based on the achiral [Ru(2,2':6',2''-terpyridine)2](2+) motif are easy to synthesise, however, these complexes are devoid of attractive excited-state properties. Hence strategies to increase the r.t. excited-state lifetime of these complexes would be of practical importance in vectorial electron and/or electron transfer in various optoelectronic applications. This tutorial review will report on the sophisticated synthetic strategies currently in use to enhance the photophysical properties of mononuclear Ru(II) complexes of tridentate ligands at room temperature. PMID:24919706

  5. Toward equatorial planarity about uranyl: synthesis and structure of tridentate nitrogen-donor {UO2}2+ complexes.

    PubMed

    Copping, Roy; Jeon, Byoungseon; Pemmaraju, C Das; Wang, Shuao; Teat, Simon J; Janousch, Markus; Tyliszczak, Tolek; Canning, Andrew; Grønbech-Jensen, Niels; Prendergast, David; Shuh, David K

    2014-03-01

    The reaction of UO2Cl2·3THF with the tridentate nitrogen donor ligand 2,6-bis(2-benzimidazolyl)pyridine (H2BBP) in pyridine leads to the formation of three different complexes: [(UO2)(H2BBP)Cl2] (1), [(UO)2(HBBP)(Py)Cl] (2), and [(UO2)(BBP)(Py)2] (3) after successive deprotonation of H2BBP with a strong base. Crystallographic determination of 1-3 reveals that increased charge through ligand deprotonation and displacement of chloride leads to equatorial planarity about uranyl as well as a more compact overall coordination geometry. Near-Edge X-ray Absorption Fine Structure (NEXAFS) spectra of 1-3 at the U-4d edges have been recorded using a soft X-ray Scanning Transmission X-ray Microscope (STXM) and reveal the uranium 4d5/2 and 4d3/2 transitions at energies associated with uranium in the hexavalent oxidation state. First-principles Density Functional Theory (DFT) electronic structure calculations for the complexes have been performed to determine and validate the coordination characteristics, which correspond well to the experimental results. PMID:24528285

  6. Synthesis, characterization, biological activity and equilibrium studies of metal(II) ion complexes with tridentate hydrazone ligand derived from hydralazine

    NASA Astrophysics Data System (ADS)

    El-Sherif, Ahmed A.; Shoukry, Mohamed M.; Abd-Elgawad, Mohamed M. A.

    2012-12-01

    In the present study, a new hydrazone ligand (2-((2-phthalazin-1-yl)hydrazono)methyl)phenol) prepared by condensation of hydralazine (1-Hydralazinophthalazine) with salicylaldehyde (SAH). The synthesized SAH-hydrazone and its metal complexes have been characterized by elemental analyses, IR, 1H NMR, solid reflectance, magnetic moment, molar conductance, mass spectra, UV-vis and thermal analysis (TGA). The analytical data of the complexes show the formation of 1:1 [M:L] ratio, where M represents Ni(II), Co(II) and Cu(II) ions, while L represents the deprotonated hydrazone ligand. IR spectra show that SAH is coordinated to the metal ions in a tridentate manner through phthalazine-N, azomethine-N and phenolic-oxygen groups. The ligand and their metal chelates have been screened for their antimicrobial activities using the disc diffusion method against the selected bacteria and fungi. Proton-ligand association constants of (SAH) and the stepwise stability constants of its metal complexes are determined potentiometrically in 0.1 M NaNO3 at different temperatures and the corresponding thermodynamic parameters were derived and discussed. The order of -ΔG° and -ΔH° were found to obey Mn2+ < Co2+ < Ni2+ < Cu2+, in accordance with the Irving-Williams order. The complexes were stabilized by enthalpy changes and the results suggest that the complexation is an enthalpy-driven process. The concentration distribution diagrams of the complexes are evaluated.

  7. Synthesis, characterization, biological activity and equilibrium studies of metal(II) ion complexes with tridentate hydrazone ligand derived from hydralazine.

    PubMed

    El-Sherif, Ahmed A; Shoukry, Mohamed M; Abd-Elgawad, Mohamed M A

    2012-12-01

    In the present study, a new hydrazone ligand (2-((2-phthalazin-1-yl)hydrazono)methyl)phenol) prepared by condensation of hydralazine (1-Hydralazinophthalazine) with salicylaldehyde (SAH). The synthesized SAH-hydrazone and its metal complexes have been characterized by elemental analyses, IR, (1)H NMR, solid reflectance, magnetic moment, molar conductance, mass spectra, UV-vis and thermal analysis (TGA). The analytical data of the complexes show the formation of 1:1 [M:L] ratio, where M represents Ni(II), Co(II) and Cu(II) ions, while L represents the deprotonated hydrazone ligand. IR spectra show that SAH is coordinated to the metal ions in a tridentate manner through phthalazine-N, azomethine-N and phenolic-oxygen groups. The ligand and their metal chelates have been screened for their antimicrobial activities using the disc diffusion method against the selected bacteria and fungi. Proton-ligand association constants of (SAH) and the stepwise stability constants of its metal complexes are determined potentiometrically in 0.1 M NaNO(3) at different temperatures and the corresponding thermodynamic parameters were derived and discussed. The order of -ΔG° and -ΔH° were found to obey Mn(2+)

  8. Investigation of Stimulated Raman Scattering Using Short-Pulse Diffraction Limited Laser Beam near the Instability Threshold

    NASA Astrophysics Data System (ADS)

    Kline, J. L.; Montgomery, D. S.; Yin, L.; Flippo, K. A.; Albright, B. J.; Johnson, R. P.; Shimada, T.; Rose, H. A.; Rousseaux, C.; Tassin, V.; Baton, S. D.; Amiranoff, F.; Hardin, R. A.

    2008-11-01

    Short pulse laser plasma interaction experiments using diffraction limited beams provide an excellent platform to investigate the fundamental physics of Stimulated Raman (SRS) and Stimulated Brillouin (SBS) Scattering. Detailed understanding of these laser plasma instabilities impacts the current inertial confinement fusion ignition designs and could potentially impact fast ignition when higher energy lasers are used with longer pulse durations ( > 1 kJ and > 1 ps). Using short laser pulses, experiments can be modeled over the entire interaction time of the laser using PIC codes to validate our understanding. Experiments have been conducted at the Trident laser and the LULI to investigate SRS near the threshold of the instability using 527 and 1064 nm laser light respectively with 1.5 -- 3 ps pulses. In the case of both experiments, the interaction beam was focused into a pre-ionized He gasjet plasma. Measurements of the reflectivity as a function of intensity and k?D were completed at the Trident laser. At LULI, a 300 fs Thomson scattering probe is used to directly measure the density fluctuations of the driven electron plasma and ion acoustic waves. Details of the experimental results will be presented.

  9. Formation of a Metal-to-Nitrogen Bond of Normal Length by a Neutral Sufonamide Group within a Tridentate Ligand. A New Approach to Radiopharmaceutical Bioconjugation

    PubMed Central

    Perera, Theshini; Abhayawardhana, Pramuditha; Marzilli, Patricia A.; Fronczek, Frank R.

    2014-01-01

    We demonstrate that a tertiary sulfonamide group, N(SO2R)R′2, can re-hybridize to form a M–N bond of normal length even when the group is in a linear tridentate ligand, such as in the new tridentate N(SO2R)dpa ligands derived from di-(2-picolyl)amine (N(H)dpa). N(SO2R)dpa ligands were used to prepare fac-[Re(CO)3(N(SO2R)dpa)](PF6 or BF4) complexes. Structural characterization of the new complexes established that the tertiary sulfonamide nitrogen atom binds to Re with concomitant sp2-to-sp3 re-hybridization, facilitating facial coordination. The new fac-[Re(CO)3(N(SO2R)dpa)]X structures provide the only examples for any metal with the sulfonamide as part of a noncyclic linear tridentate ligand and with a normal metal-to-nitrogen(tertiary sulfonamide) bond length. Rare previous examples of such normal M–N bonds have been found only in more constrained situations, such as with tripodal tetradentate ligands. Our long-term objectives for the new tridentate N(SO2R)dpa ligands are to develop the fundamental chemistry relevant to the eventual use of the fac-[MI(CO)3]+ core (M = 99mTc, 186/188Re) in imaging and therapy. The sulfonamide group uniquely contributes to two of our goals: expanding ways to conjugate the fac-[MI(CO)3]+ core to biological molecules and also developing new symmetrical tridentate ligands that can coordinate facially to this core. Tests of our conjugation method, conducted by linking the fac-[ReI(CO)3]+ core to a new tetraarylporphyrin (T(N(SO2C6H4)dpa)P) as well as to a dansyl (5-(dimethylamino)naphthalene-1-sulfonyl) group, demonstrate that large molecular fragments can be tethered via a coordinated tertiary sulfonamide linkage to this core. PMID:23421481

  10. Characteristic x-ray emission from undermines plasmas irradiated by ultra-intense lasers

    SciTech Connect

    Niemann, Christoph

    2012-05-05

    Between FY09 and FY11 we have conducted more than a dozen three-week experimental campaigns at high-power laser facilities around the world to investigate laser-channeling through x-ray and optical imaging and the conversion from laser-energy to xrays. We have performed simultaneous two-wavelength x-ray imaging (K-alpha and He-alpha) to distinguish the hot-plasma region (hot-spot) from the laser-produced electrons (K-alpha). In addition, we have initiated a new collaboration with SNL and have performed first shots on the 100 TW beamlet chamber to commission a fast x-ray streak camera to be used to investigate the temporal evolution of our K-alpha sources. We also collaborated on campaigns at the Rutherford Appleton Laboratory (UK) and the LANL Trident laser to employ laser produced x-ray sources for Thomson scattering off dense matter.

  11. 1993 Northern goshawk inventory on portions of Los Alamos National Laboratory, Los Alamos, NM. Final report

    SciTech Connect

    Sinton, D.T.; Kennedy, P.L.

    1994-06-01

    Northern goshawks (Accipiter gentilis) (hereafter referred to as goshawk) is a large forest dwelling hawk. Goshawks may be declining in population and reproduction in the southwestern United States. Reasons for the possible decline in goshawk populations include timber harvesting resulting in the loss of nesting habitat, toxic chemicals, and the effects of drought, fire, and disease. Thus, there is a need to determine their population status and assess impacts of management activities in potential goshawk habitat. Inventory for the goshawk was conducted on 2,254 ha of Los Alamos National Laboratory (LANL) to determine the presence of nesting goshawks on LANL lands. This information can be incorporated into LANL`s environmental management program. The inventory was conducted by Colorado State University personnel from May 12 to July 30, 1993. This report summarizes the results of this inventory.

  12. Integrated review software advances at Los Alamos

    SciTech Connect

    Klosterbuer, S. F.; Michel, K. D.; Betts, S. E.; Determan, J. C.; Longo, J. F.; Parker, R. F.; Pelowitz, D. G.; Rothrock, R. B.; Schneider, C. M.; Nordquist, H. M.

    2004-01-01

    Since 1988, Los Alamos National Laboratory (LANL) has been developing software for unattended monitoring systems. These systems are composed of three categories of software: acquisition, collection and review. The data acquisition software is contained in modular instrumentation distributed throughout facilities to continuously acquire data from devices ranging from radiation detectors to cameras to binary switches. The data collection software runs on computers connected to the instruments and offloads and stores the acquired data. The review software enables the end user to quickly and easily examine the data collected from these different systems and compare the results to declared operator activities. This paper addresses the review software. The original standalone review software processed only radiation data. This software was expanded to include new programs (tools) to display and correlate video and operator declarations and added an interface to the standard neutron coincidence counter analysis program. This expanded review software containing multiple review tools is referred to collectively as the Integrated Review Software (IRS). The IRS continues to expand and evolve. Two primary IRS developments will be described in this paper. First, the IRS was expanded to include review tools to display and analyze new data types. Position Review was developed to display Global Positioning System (GPS) location data to aid in tracking radiation movements. Isotopic Review is being developed to provide a link to the standard gamma isotopic analysis software. In addition significant enhancements are being added to the existing review tools such as Operator Review, Radiation Review and Digital Video Review. A second IRS development is to produce standardized components with published interfaces enabling other parties to produce custom components that plug into review software. It is anticipated that there will be four primary types of components that could be

  13. Water Supply at Los Alamos 1998-2001

    SciTech Connect

    Richard J. Koch; David B. Rogers

    2003-03-01

    For the period 1998 through 2001, the total water used at Los Alamos from all sources ranged from 1325 million gallons (Mg) in 1999 to 1515 Mg in 2000. Groundwater production ranged from 1323 Mg in 1999 to 1506 Mg in 2000 from the Guaje, Pajarito, and Otowi fields. Nonpotable surface water used from Los Alamos reservoir ranged from zero gallons in 2001 to 9.3 Mg in 2000. For years 1998 through 2001, over 99% of all water used at Los Alamos was groundwater. Water use by Los Alamos National Laboratory (LANL) between 1998 and 2001 ranged from 379 Mg in 2000 to 461 Mg in 1998. The LANL water use in 2001 was 393 Mg or 27% of the total water use at Los Alamos. Water use by Los Alamos County ranged from 872 Mg in 1999 to 1137 Mg in 2000, and averaged 1006 Mg/yr. Four new replacement wells in the Guaje field (G-2A, G-3A, G-4A, and G-5A) were drilled in 1998 and began production in 1999; with existing well G-1A, the Guaje field currently has five producing wells. Five of the old Guaje wells (G-1, G-2, G-4, G-5, and G-6) were plugged and abandoned in 1999, and one well (G-3) was abandoned but remains as an observation well for the Guaje field. The long-term water level observations in production and observation (test) wells at Los Alamos are consistent with the formation of a cone of depression in response to water production. The water level decline is gradual and at most has been about 0.7 to 2 ft per year for production wells and from 0.4 to 0.9 ft/yr for observation (test) wells. The largest water level declines have been in the Guaje field where nonpumping water levels were about 91 ft lower in 2001 than in 1951. The initial water levels of the Guaje replacement wells were 32 to 57 ft lower than the initial water levels of adjacent original Guaje wells. When production wells are taken off-line for pump replacement or repair, water levels have returned to within about 25 ft of initial static levels within 6 to 12 months. Thus, the water-level trends suggest no adverse

  14. A progress report on UNICOS misuse detection at Los Alamos

    SciTech Connect

    Thompson, J.L.; Jackson, K.A.; Stallings, C.A.; Simmonds, D.D.; Siciliano, C.L.B.; Pedicini, G.A.

    1995-10-01

    An effective method for detecting computer misuse is the automatic monitoring and analysis of on-line user activity. During the past year, Los Alamos enhanced its Network Anomaly Detection and Intrusion Reporter (NADIR) to include analysis of user activity on Los Alamos` UNICOS Crays. In near real-time, NADIR compares user activity to historical profiles and tests activity against expert rules. The expert rules express Los Alamos` security policy and define improper or suspicious behavior. NADIR reports suspicious behavior to security auditors and provides tools to aid in follow-up investigations. This paper describes the implementation to date of the UNICOS component of NADIR, along with the operational experiences and future plans for the system.

  15. Publications of Los Alamos research, 1977-1981

    SciTech Connect

    Sheridan, C.J.; Garcia, C.A.

    1983-03-01

    This bibliography is a compilation of unclassified publications of work done at the Los Alamos National Laboratory for 1977-1981. Papers published in those years are included regardless of when they were actually written. Publications received too late for inclusion in earlier compilations have also been listed. Declassification of previously classified reports is considered to constitute publication. All classified issuances are omitted - even those papers, themselves unclassified, which were published only as part of a classified document. If a paper was published more than once, all places of publication are included. The bibliography includes Los Alamos National Laboratory reports, papers released as non-Laboratory reports, journal articles, books, chapters of books, conference papers either published separately or as part of conference proceedings issued as books or reports, papers published in congressional hearings, theses, and US patents. Publications by Los Alamos authors that are not records of Laboratory-sponsored work are included when the Library becomes aware of them.

  16. Windward islands passages monitoring program: Physical oceanographic data collected on cruises WI-04, HMBS trident, 7-13 December 1992, WI-05, JMBS trident, 7-12 February 1993, and WI-06, JMBS trident, 24-28 March 1993. Technical memo

    SciTech Connect

    Wilson, W.D.; Johns, W.E.; Routt, J.A.; Hendry, M.D.

    1995-03-01

    During 1991, a collaborative program between the United States and Barbados was established with the support of NOAA`s Climate and Global Change Atlantic Climate Change Program, to conduct regular measurements of the transport and water mass characteristics in the major southern passages to the Caribbean Sea. This program involves the use of a Barbados Coast Guard vessel, the HMBS Trident, which makes routine monthly patrols in the area and has been equipped to collect standard hydrographic measurements (CTDO2 profiles and water samples) and velocity profile measurements using a downward-looking acoustic Doppler current profiler (ADCP). The purpose of the program is to determine the quantity and time-variability of South Atlantic surface, thermocline, and intermediate waters flowing into the North Atlantic in compensation for southward cross-equatorial transport of North Atlantic Deep Water, and to establish an economical means for future monitoring of this transport loop. This report contains data collected on cruises WI - 04, WI - 05, and WI - 06 of this program.

  17. Water supply at Los Alamos during 1993. Progress report

    SciTech Connect

    Purtymun, W.D.; Stoker, A.K.; McLin, S.G.; Maes, M.N.; Glasco, T.A.

    1995-10-01

    This report summarizes production and aquifer conditions for water wells in the Guaje, Pajarito, and Otowi Well Fields. These wells supplied all of the potable water used for municipal and some industrial purposes in Los Alamos County and the Los Alamos National Laboratory during 1993. The wells in the Los Alamos Well Field were transferred to San Ildefonso Pueblo in 1992. Four of the wells in the Los Alamos Well Field were plugged in 1993. One of the two new wells in the Otowi Well Field became operational in 1993. The spring gallery in Water Canyon supplied nonpotable water for industrial use, while surface water from the Los Alamos Reservoir was diverted for irrigation. In 1993 no water was used from the Guaje Reservoir. Due to the maintenance and operating cost of diverting water from the reservoirs, it is not economically feasible to continue their use for irrigation. This report fulfills some of the requirements of the Los Alamos Groundwater Protection Management Program by documenting use of the groundwater for water supply and providing information hydrologic characteristics of the main aquifer. This report is a joint effort between the Laboratory Water Quality and Hydrology Group and the Utilities Department of Johnson Controls World Services Inc. (JCI). The purpose of this report is to ensure a continuing historical record and to provide guidance for management of water resources in long-range planning for the water supply system. We have issued one summary report for the period of 1947 to 1971 and 22 annual reports that contain the results of our studies of these water supplies. An additional report summarized the hydrology of the main aquifer with reference to future development of groundwater supplies. A report was issued in 1988 that examined the status of wells and future water supply.

  18. Ultra-High-Contrast Laser Acceleration of Relativistic Electrons in Solid Targets

    NASA Astrophysics Data System (ADS)

    Higginson, Drew Pitney

    The cone-guided fast ignition approach to Inertial Confinement Fusion requires laser-accelerated relativistic electrons to deposit kilojoules of energy within an imploded fuel core to initiate fusion burn. One obstacle to coupling electron energy into the core is the ablation of material, known as preplasma, by laser energy proceeding nanoseconds prior to the main pulse. This causes the laser-absorption surface to be pushed back hundreds of microns from the initial target surface; thus increasing the distance that electrons must travel to reach the imploded core. Previous experiments have shown an order of magnitude decrease in coupling into surrogate targets when intentionally increasing the amount of preplasma. Additionally, for electrons to deposit energy within the core, they should have kinetic energies on the order of a few MeV, as less energetic electrons will be stopped prior to the core and more energetic electrons will pass through the core without depositing much energy. Thus a quantitative understanding of the electron energy spectrum and how it responds to varied laser parameters is paramount for fast ignition. For the first time, this dissertation quantitatively investigates the acceleration of electrons using an ultra-high-contrast laser. Ultra-high-contrast lasers reduce the laser energy that reaches the target prior to the main pulse; drastically reducing the amount of preplasma. Experiments were performed in a cone-wire geometry relevant to fast ignition. These experiments irradiated the inner-tip of a Au cone with the laser and observed electrons that passed through a Cu wire attached to the outer-tip of the cone. The total emission of Kalpha x-rays is used as a diagnostic to infer the electron energy coupled into the wire. Imaging the x-ray emission allowed an effective path-length of electrons within the wire to be determined, which constrained the electron energy spectrum. Experiments were carried out on the ultra-high-contrast Trident laser

  19. The development of the atomic bomb, Los Alamos

    SciTech Connect

    Seidel, R.W.

    1993-11-01

    The historical presentation begins with details of the selection of Los Alamos as the site of the Army installation. Wartime efforts of the Army Corps of Engineers, and scientists to include the leader of Los Alamos, Robert Oppenheimer are presented. The layout and construction of the facilities are discussed. The monumental design requirements of the bombs are discussed, including but not limited to the utilization of the second choice implosion method of detonation, and the production of bomb-grade nuclear explosives. The paper ends with a philosophical discussion on the use of nuclear weapons.

  20. Fifty-one years of Los Alamos Spacecraft

    SciTech Connect

    Fenimore, Edward E.

    2014-09-04

    From 1963 to 2014, the Los Alamos National Laboratory was involved in at least 233 spacecraft. There are probably only one or two institutions in the world that have been involved in so many spacecraft. Los Alamos space exploration started with the Vela satellites for nuclear test detection, but soon expanded to ionospheric research (mostly barium releases), radioisotope thermoelectric generators, solar physics, solar wind, magnetospheres, astrophysics, national security, planetary physics, earth resources, radio propagation in the ionosphere, and cubesats. Here, we present a list of the spacecraft, their purpose, and their launch dates for use during RocketFest

  1. A physicists guide to The Los Alamos Primer

    NASA Astrophysics Data System (ADS)

    Reed, B. Cameron

    2016-11-01

    In April 1943, a group of scientists at the newly established Los Alamos Laboratory were given a series of lectures by Robert Serber on what was then known of the physics and engineering issues involved in developing fission bombs. Serber’s lectures were recorded in a 24 page report titled The Los Alamos Primer, which was subsequently declassified and published in book form. This paper describes the background to the Primer and analyzes the physics contained in its 22 sections. The motivation for this paper is to provide a firm foundation of the background and contents of the Primer for physicists interested in the Manhattan Project and nuclear weapons.

  2. Contributions of chemistry in early day Los Alamos

    SciTech Connect

    Penneman, R.A.; Meade, R.A.

    1990-01-01

    During 1943--1945, the premier physics laboratory in the world was at Los Alamos, but chemistry contributions were vital. Major chemical impacts on the success of the Los Alamos wartime mission included electrochemistry, which found the true melting point of plutonium metal to be hundreds of degrees lower than anticipated. This discovery had profound simplifying effects regarding crucibles to contain molten plutonium and on its production. Other significant chemical contributions involved constant purification of plutonium for reuse, producing carrier-free gamma sources at unprecedented kilo-curie levels, and high polonium work. 8 refs.

  3. Needs assessment for fire department services and resources for the Los Alamos National Laboratory, Los Alamos, New Mexico. Final report

    SciTech Connect

    1995-11-15

    This report has been developed in response to a request from the Los Alamos National Laboratory (LANL) to evaluate the need for fire department services so as to enable the Laboratory to plan effective fire protection and thereby: meet LANL`s regulatory and contractual obligations; interface with the Department of Energy (DOE) and other agencies on matters relating to fire and emergency services; and ensure appropriate protection of the community and environment. This study is an outgrowth of the 1993 Fire Department Needs Assessment (prepared for DOE) but is developed from the LANL perspective. Input has been received from cognizant and responsible representatives at LANL, DOE, Los Alamos County (LAC) and the Los Alamos Fire Department (LAFD).

  4. A survey of macromycete diversity at Los Alamos National Laboratory, Bandelier National Monument, and Los Alamos County; A preliminary report

    SciTech Connect

    Jarmie, N.; Rogers, F.J.

    1997-11-01

    The authors have completed a 5-year survey (1991--1995) of macromycetes found in Los Alamos County, Los Alamos National Laboratory, and Bandelier National Monument. The authors have compiled a database of 1,048 collections, their characteristics, and identifications. The database represents 123 (98%) genera and 175 (73%) species reliably identified. Issues of habitat loss, species extinction, and ecological relationships are addressed, and comparisons with other surveys are made. With this baseline information and modeling of this baseline data, one can begin to understand more about the fungal flora of the area.

  5. A novel tridentate bis(phosphinic acid)phosphine oxide based europium(III)-selective Nafion membrane luminescent sensor.

    PubMed

    Sainz-Gonzalo, F J; Popovici, C; Casimiro, M; Raya-Barón, A; López-Ortiz, F; Fernández, I; Fernández-Sánchez, J F; Fernández-Gutiérrez, A

    2013-10-21

    A new europium(III) membrane luminescent sensor based on a new tridentate bis(phosphinic acid)phosphine oxide (3) system has been developed. The synthesis of this new ligand is described and its full characterization by NMR, IR and elemental analyses is provided. The luminescent complex formed between europium(III) chloride and ligand 3 was evaluated in solution, observing that its spectroscopic and chemical characteristics are excellent for measuring in polymer inclusion membranes. Included in a Nafion membrane, all the parameters (ligand and ionic additives) that can affect the sensitivity and selectivity of the sensing membrane as well as the instrumental conditions were carefully optimized. The best luminescence signal (λexc = 229.06 nm and λem = 616.02 nm) was exhibited by the sensing film having a Nafion : ligand composition of 262.3 : 0.6 mg mL(-1). The membrane sensor showed a short response time (t95 = 5.0 ± 0.2 min) and an optimum working pH of 5.0 (25 mM acetate buffer solution). The membrane sensor manifested a good selectivity toward europium(III) ions with respect to other trivalent metals (iron, chromium and aluminium) and lanthanide(III) ions (lanthanum, samarium, terbium and ytterbium), although a small positive interference of terbium(III) ions was observed. It provided a linear range from 1.9 × 10(-8) to 5.0 × 10(-6) M with a very low detection limit (5.8 × 10(-9) M) and sensitivity (8.57 × 10(-7) a.u. per M). The applicability of this sensing film has been demonstrated by analyzing different kinds of spiked water samples obtaining recovery percentages of 95-97%.

  6. It's all about Me: methyl-induced control of coordination stereochemistry by a flexible tridentate N,C,N' ligand.

    PubMed

    Kariuki, Benson M; Platts, James A; Newman, Paul D

    2014-02-21

    A chiral, tridentate, pyridyl-functionalised NHC pro-ligand, S-L(Me)-H[PF₆], has been prepared diastereoselectively via a five step synthesis starting from 1R,3S-diamino-1,2,2-trimethylcyclopentane. The S prefix refers to the stereochemistry of a methyl substituted stereogenic carbon in one of the pyridyl arms which is generated by a stereoselective BH4(-) reduction of an imine precursor. The ligand has been coordinated to Rh(I) and Ir(I) to give trigonal bipyramidal complexes of the type [M(κ(3)-N,C,N'-S-L(Me))(1,5-COD)]PF6 (M = Rh, Ir) as single diastereomers. A combination of spectroscopic and X-ray techniques confirm the stereoselective formation of the thermodynamically preferred endo,endo isomer. Similar reactions with R,S-L(Me)-H[PF₆] gave a mixture of endo,endo-[M(κ(3)-N,C,N'-S-L(Me))(1,5-COD)](+) and exo,exo-[M(κ(3)-N,C,N'-R-L(Me))(1,5-COD)](+). The absolute configuration at the metal is, therefore, solely dictated by the stereochemistry of the single methylpyridyl carbon. The observation of stereoselection extends to the square planar Ni(II) complex [Ni(δ-κ(3)-N,C,N'-S-L(Me))Cl](+) which is isolated as one (δ) of the two possible conformational isomers. DFT studies have been employed to explain the observed stereoselectivity with the configurations observed in the solid state being confirmed as those of lowest energy. PMID:24346145

  7. Oxidovanadium(IV) and dioxidovanadium(V) complexes of tridentate salicylaldehyde semicarbazones: searching for prospective antitrypanosomal agents.

    PubMed

    Fernández, Mariana; Becco, Lorena; Correia, Isabel; Benítez, Julio; Piro, Oscar E; Echeverria, Gustavo A; Medeiros, Andrea; Comini, Marcelo; Lavaggi, María Laura; González, Mercedes; Cerecetto, Hugo; Moreno, Virtudes; Pessoa, Joao Costa; Garat, Beatriz; Gambino, Dinorah

    2013-10-01

    As a contribution to the identification of the relevant species for biological activity and the understanding of structure-activity relationships of [V(IV)O(L-2H)(NN)] antitrypanosomal complexes (NN is a bidentate polypyridyl DNA intercalator; L is a tridentate salicylaldehyde semicarbazone derivative), new [V(V)O2(L-2H)] complexes and [V(IV)O(L-2H)(NN)] complexes including bipy or dppz (dipyrido[3,2-a: 2',3'-c]phenazine) co-ligands are prepared and characterized in the solid state and in solution. Their activity is evaluated on Trypanosoma cruzi. The lipophilicity, as structural descriptor related to bioactivity, of the whole [V(IV)O(L-2H)(NN)] series is determined. Furthermore, the antiproliferative effect of those new compounds showing activity against T. cruzi is evaluated on the genetically related parasite T. brucei with the aim to develop broad spectrum agents. The new [V(IV)O(L-2H)(dppz)] complexes are about ten to fifteen times more toxic to T. cruzi than the bipy analogues and show quite good in vitro activity on T. brucei brucei. They are shown to interact with DNA, suggesting that this biomolecule may be the parasite target. The stability of the V(IV)O-complexes in solution is accessed by several techniques. Globally the data suggest that the relevant species for biological activity are the [V(IV)O(L-2H)(NN)] compounds, their order of activity being dependent on the NN nature, but not much on the substitution on the salicylaldehyde semicarbazone moiety. A parabolic relationship between biological response and lipophilicity (determined as RM=log [(1/Rf)-1] by a TLC method) is obtained. From this correlation an optimum RM value, close to 1.44, was found, which may be used as design guide for future development of antitrypanosomal compounds.

  8. Thermodynamic study of the complexation of trivalent actinide and lanthanide cations by ADPTZ, a tridentate N-donor ligand.

    PubMed

    Miguirditchian, Manuel; Guillaneux, Denis; Guillaumont, Dominique; Moisy, Philippe; Madic, Charles; Jensen, Mark P; Nash, Kenneth L

    2005-03-01

    To better understand the bonding in complexes of f-elements by polydentate N-donor ligands, the complexation of americium(III) and lanthanide(III) cations by 2-amino-4,6-di-(pyridin-2-yl)-1,3,5-triazine (ADPTZ) was studied using a thermodynamic approach. The stability constants of the 1:1 complexes in a methanol/water mixture (75/25 vol %) were determined by UV-visible spectrophotometry for every lanthanide(III) ion (except promethium), and yttrium(III) and americium(III) cations. The thermodynamic parameters (DeltaH degrees , DeltaS degrees) of complexation were determined from the temperature dependence of the stability constants and by microcalorimetry. The trends of the variations of DeltaG degrees , DeltaH degrees , and DeltaS degrees across the lanthanide series are compared with published results for other tridentate ligands and confirm strongly ionic bonding in the lanthanide-ADPTZ complexes. Comparison of the thermodynamic properties between the Am- and Ln-ADPTZ complexes highlights an increase in stability of the complexes by a factor of 20 in favor of the americium cation. This difference arises from a more exothermic reaction enthalpy in the case of Am, which is correlated with a greater degree of covalency in the americium-nitrogen bonds. Quantum chemistry calculations performed on a series of trivalent actinide and lanthanide-ADPTZ complexes support the experimental results, showing a slightly greater covalence in the actinide-ligand bonds that originates from a charge transfer from the ligand sigma orbitals to the 5f and 6d orbitals of the actinide ion. PMID:15732980

  9. Technical manpower needs and resources at Los Alamos National Laboratory

    SciTech Connect

    Freese, K.B.

    1984-01-01

    The Los Alamos National Laboratory has begun a program to share its scientific and technological expertise with students and teachers in the surrounding area. The goal of the Laboratory's Educational Outreach Program is to stimulate an awareness of professional opportunities in the sciences and engineering.

  10. Direct-current proton-beam measurements at Los Alamos

    SciTech Connect

    Sherman, Joseph; Stevens, Ralph R.; Schneider, J. David; Zaugg, Thomas

    1995-09-15

    Recently, a CW proton accelerator complex was moved from Chalk River Laboratories (CRL) to Los Alamos National Laboratory. This includes a 50-keV dc proton injector with a single-solenoid low-energy beam transport system (LEBT) and a CW 1.25-MeV, 267-MHz radiofrequency quadrupole (RFQ). The move was completed after CRL had achieved 55-mA CW operation at 1.25 MeV using 250-kW klystrode tubes to power the RFQ. These accelerator components are prototypes for the front end of a CW linac required for an accelerator-driven transmutation linac, and they provide early confirmation of some CW accelerator components. The injector (ion source and LEBT) and emittance measuring unit are installed and operational at Los Alamos. The dc microwave ion source has been operated routinely at 50-keV, 75-mA hydrogen-ion current. This ion source has demonstrated very good discharge and H2 gas efficiencies, and sufficient reliability to complete CW RFQ measurements at CRL. Proton fraction of 75% has been measured with 550-W discharge power. This high proton fraction removes the need for an analyzing magnet. Proton LEBT emittance measurements completed at Los Alamos suggest that improved transmission through the RFQ may be achieved by increasing the solenoid focusing current. Status of the final CW RFQ operation at CRL and the installation of the RFQ at Los Alamos will be given.

  11. Direct-current proton-beam measurements at Los Alamos

    SciTech Connect

    Sherman, J.; Stevens, R.R.; Schneider, J.D.; Zaugg, T.

    1994-08-01

    Recently, a CW proton accelerator complex was moved from Chalk River Laboratories (CRL) to Los Alamos National Laboratory. This includes a 50-keV dc proton injector with a single-solenoid low-energy beam transport system (LEBT) and a CW 1.25-MeV, 267-MHz radiofrequency quadrupole (RFQ). The move was completed after CRL had achieved 55-mA CW operation at 1.25 MeV using 250-kW klystrode tubes to power the RFQ. These accelerator components are prototypes for the front end of a CW linac required for an accelerator-driven transmutation linac, and they provide early confirmation of some CW accelerator components. The injector (ion source and LEBT) and emittance measuring unit are installed and operational at Los Alamos. The dc microwave ion source has been operated routinely at 50-keV, 75-mA hydrogen-ion current. This ion source has demonstrated very good discharge and H{sub 2} gas efficiencies, and sufficient reliability to complete CW RFQ measurements at CRL. Proton fraction of 75% has been measured with 550-W discharge power. This high proton fraction removes the need for an analyzing magnet. Proton LEBT emittance measurements completed at Los Alamos suggest that improved transmission through the RFQ may be achieved by increasing the solenoid focusing current. Status of the final CW RFQ operation at CRL and the installation of the RFQ at Los Alamos is given.

  12. Summary of environmental surveillance at Los Alamos during 1995

    SciTech Connect

    1996-10-01

    Linking the Rio Grande Valley and the Jemez Mountains, New Mexico`s Pajarito Plateau is home to a world-class scientific institution. Los Alamos National Laboratory (or the Laboratory), managed by the Regents of the University of California, is a government-owned, Department of Energy-supervised complex investigating all areas of modern science for the purposes of national defense, health, conservation, and ecology. The Laboratory was founded in 1943 as part of the Manhattan Project, whose members assembled to create the first nuclear weapon. Occupying the campus of the Los Alamos Ranch School, American and British scientists gathered on the isolated mesa tops to harness recently discovered nuclear power with the hope of ending World War II. In July 1945, the initial objective of the Laboratory, a nuclear device, was achieved in Los Alamos and tested in White Sands, New Mexico. Today the Laboratory continues its role in defense, particularly in nuclear weapons, including developing methods for safely handling weapons and managing waste. For the past twenty years, the Laboratory has published an annual environmental report. This pamphlet offers a synopsis that briefly explains important concepts, such as radiation and provides a summary of the monitoring results and regulatory compliance status that are explained at length in the document entitled Environmental Surveillance at Los Alamos during 1995.

  13. The Controlled-Air Incinerator at Los Alamos

    SciTech Connect

    Newmyer, J.N.

    1994-04-01

    The Controlled-Air Incinerator (CAI) at Los Alamos is being modified and upgraded to begin routine operations treating low-level mixed waste (LLMW), radioactively contaminated polychlorinated biphenyl (PCB) wastes, low-level liquid wastes, and possibly transuranic (TRU) wastes. This paper describes those modifications. Routine waste operations should begin in late FY95.

  14. The Los Alamos Space Science Outreach (LASSO) Program

    NASA Astrophysics Data System (ADS)

    Barker, P. L.; Skoug, R. M.; Alexander, R. J.; Thomsen, M. F.; Gary, S. P.

    2002-12-01

    The Los Alamos Space Science Outreach (LASSO) program features summer workshops in which K-14 teachers spend several weeks at LANL learning space science from Los Alamos scientists and developing methods and materials for teaching this science to their students. The program is designed to provide hands-on space science training to teachers as well as assistance in developing lesson plans for use in their classrooms. The program supports an instructional model based on education research and cognitive theory. Students and teachers engage in activities that encourage critical thinking and a constructivist approach to learning. LASSO is run through the Los Alamos Science Education Team (SET). SET personnel have many years of experience in teaching, education research, and science education programs. Their involvement ensures that the teacher workshop program is grounded in sound pedagogical methods and meets current educational standards. Lesson plans focus on current LANL satellite projects to study the solar wind and the Earth's magnetosphere. LASSO is an umbrella program for space science education activities at Los Alamos National Laboratory (LANL) that was created to enhance the science and math interests and skills of students from New Mexico and the nation. The LASSO umbrella allows maximum leveraging of EPO funding from a number of projects (and thus maximum educational benefits to both students and teachers), while providing a format for the expression of the unique science perspective of each project.

  15. Optical velocimetry at the Los Alamos Proton Radiography Facility

    NASA Astrophysics Data System (ADS)

    Tupa, Dale; Tainter, Amy; Neukirch, Levi; Hollander, Brian; Buttler, William; Holtkamp, David; The Los Alamos Proton Radiography Team Team

    2016-05-01

    The Los Alamos Proton Radiography Facility (pRad) employs a high-energy proton beam to image the properties and behavior of materials driven by high explosives. We will discuss features of pRad and describe some recent experiments, highlighting optical diagnostics for surface velocity measurements.

  16. Working with Fermi at Chicago and Los Alamos

    NASA Astrophysics Data System (ADS)

    Garwin, Richard L.

    2010-02-01

    I discuss my experience with Enrico Fermi as student and fellow faculty member at Chicago and with him as consultants to the Los Alamos Scientific Laboratory in 1950-1952. The talk shares observations about this great physicist and exemplary human being. )

  17. Review of multi-dimensional large-scale kinetic simulation and physics validation of ion acceleration in relativistic laser-matter interaction

    SciTech Connect

    Wu, Hui-Chun; Hegelich, B.M.; Fernandez, J.C.; Shah, R.C.; Palaniyappan, S.; Jung, D.; Yin, L; Albright, B.J.; Bowers, K.; Huang, C.; Kwan, T.J.

    2012-06-19

    Two new experimental technologies enabled realization of Break-out afterburner (BOA) - High quality Trident laser and free-standing C nm-targets. VPIC is an powerful tool for fundamental research of relativistic laser-matter interaction. Predictions from VPIC are validated - Novel BOA and Solitary ion acceleration mechanisms. VPIC is a fully explicit Particle In Cell (PIC) code: models plasma as billions of macro-particles moving on a computational mesh. VPIC particle advance (which typically dominates computation) has been optimized extensively for many different supercomputers. Laser-driven ions lead to realization promising applications - Ion-based fast ignition; active interrogation, hadron therapy.

  18. Mixed tridentate π -donor and monodentate π -acceptor ligands as chelating systems for rhenium-188 and technetium-99m nitrido radiopharmaceuticals.

    PubMed

    Boschi, Alessandra; Uccelli, Licia; Pasquali, Micol; Pasqualini, Roberto; Guerrini, Remo; Duatti, Adriano

    2013-09-01

    A new molecular metallic fragment for labeling biologically active molecules with 99mTc and 188Re is described. This system is composed of a combination of tridentate π-donor and monodentate π-acceptor ligands bound to a [M Ξ N]2+ group (M = (99m)Tc, 188Re) in a pseudo square-pyramidal geometry. A simple structural model of the new metallic fragment was obtained by reacting the ligand 2, 2'-iminodiethanethiol [H2NS2 = NH(CH2CH2SH)2] and monodentate tertiary phosphines with the [M Ξ N]2+ group (M = (99m)Tc, (188)Re). In the resulting complexes (dubbed3+1complexes), the tridentate ligand binds the [M Ξ N]2+ core through the two deprotonated, negatively charged, thiol sulfur atoms and the neutral, protonated, amine nitrogen atom. The residual fourth position of the five-coordinated arrangement is occupied by a phosphine ligand. The chemical identity of these model (99m)Tc and (188)Re compounds was established by comparison with the chromatographic properties of the corresponding complexes obtained at the macroscopic level with the long-lived (99)Tc and natural Re isotopes. The investigation was further extended to comprise a series of ligands formed by simple combinations of two basic amino acids or pseudo-amino acids to yield potential tridentate chelating systems having [S, N, S] and [N, N, S] as sets of π-donor atoms. Labeling yields and in vitro stability were investigated using different ancillary ligands. Results showed that SNS-type ligands afforded the highest labeling yields and the most robust 3+1 nitrido complexes with both (99m)Tc and (188)Re. Thus, the new chelating system can be conveniently employed for labeling peptides and other biomolecules with the [M Ξ N]2+ group.

  19. Influence of the chelator structures on the stability of Re and Tc tricarbonyl complexes with iminodiacetic acid tridentate ligands: a computational study.

    PubMed

    Hernández-Valdés, Daniel; Rodríguez-Riera, Zalua; Díaz-García, Alicia; Benoist, Eric; Jáuregui-Haza, Ulises

    2016-08-01

    The development of novel radiopharmaceuticals for nuclear medicine based on M(CO)3 (M = Tc, Re) complexes has attracted great attention. The versatility of this core and the easy production of the fac-[M(CO)3(H2O)3](+) precursor could explain this interest. The main characteristics of these tricarbonyl complexes are the high substitution stability of the three CO ligands and the corresponding lability of the coordinated water molecules, yielding, via easy exchange of a variety of bi- and tridentate ligands, complexes xof very high kinetic stability. Here, a computational study of different tricarbonyl complexes of Re(I) and Tc(I) was performed using density functional theory. The solvent effect was simulated using the polarizable continuum model. These structures were used as a starting point to investigate the relative stabilities of tricarbonyl complexes with various tridentate ligands. These complexes included an iminodiacetic acid unit for tridentate coordination to the fac-[M(CO)3](+) moiety (M = Re, Tc), an aromatic ring system bearing a functional group (-NO2, -NH2, and -Cl) as a linking site model, and a tethering moiety (a methylene, ethylene, propylene butylene, or pentylene bridge) between the linking and coordinating sites. The optimized complexes showed geometries comparable to those inferred from X-ray data. In general, the Re complexes were more stable than the corresponding Tc complexes. Furthermore, using NH2 as the functional group, a medium length carbon chain, and ortho substitution increased complex stability. All of the bonds involving the metal center presented a closed shell interaction with dative or covalent character, and the strength of these bonds decreased in the sequence Tc-CO > Tc-O > Tc-N. PMID:27406231

  20. fac-Re(CO)3L complexes containing tridentate monoanionic ligands (L-) with a seldom-studied sulfonamido group as one terminal ligating group.

    PubMed

    Christoforou, Anna Maria; Fronczek, Frank R; Marzilli, Patricia A; Marzilli, Luigi G

    2007-08-20

    To achieve a net-neutral coordination unit in radiopharmaceuticals with a fac-M(CO)3+ core (M = Tc, Re), facially coordinated monoanionic tridentate ligands are needed. New neutral fac-Re(CO)3L complexes were obtained by treating fac-[Re(CO)3(H2O)3]+ with unsymmetrical tridentate NNN donor ligands (LH) based primarily on a diethylenetriamine (dien) moiety with an aromatic group linked to a terminal nitrogen through a sulfonamide. LHs contain 2,4,6-trimethylbenzenesulfonyl (tmbSO2) and 5-(dimethylamino)naphthalene-1-sulfonyl (DNS) groups. X-ray crystallographic and NMR analyses confirm that in both the solid and the solution states all L- in fac-Re(CO)3L complexes are bound in a tridentate fashion with one donor being nitrogen from a deprotonated sulfonamido group. Another fundamental property that is important in radiopharmaceuticals is shape, which in turn depends on ring pucker. For L- = tmbSO2-dien-, tmbSO2-N'-Medien-, and tmbSO2-N,N-Me2dien-, the two chelate rings have a different pucker chirality, as is commonly found for a broad range of metal complexes. However, for fac-Re(CO)3(DNS-dien), both chelate rings have the same pucker chirality because the sulfonamido ring has an unusual pucker for the absolute configuration at Re; a finding that is attributable to intramolecular and intermolecular hydrogen bonds from the sulfonamido oxygens to the NH2 groups. Averaging of tmb NMR signals, even at -90 degrees C for Re(CO)3(tmbSO2-N,N-Me2dien), indicates rapid dynamic motion in the complexes with this group. However, examination of the structures suggests that free rotation about the S-C(tmb) bond is not possible but that concerted coupled rotations about the N-S and the S-C bonds can explain the NMR data. PMID:17655222

  1. Mixed tridentate π -donor and monodentate π -acceptor ligands as chelating systems for rhenium-188 and technetium-99m nitrido radiopharmaceuticals.

    PubMed

    Boschi, Alessandra; Uccelli, Licia; Pasquali, Micol; Pasqualini, Roberto; Guerrini, Remo; Duatti, Adriano

    2013-09-01

    A new molecular metallic fragment for labeling biologically active molecules with 99mTc and 188Re is described. This system is composed of a combination of tridentate π-donor and monodentate π-acceptor ligands bound to a [M Ξ N]2+ group (M = (99m)Tc, 188Re) in a pseudo square-pyramidal geometry. A simple structural model of the new metallic fragment was obtained by reacting the ligand 2, 2'-iminodiethanethiol [H2NS2 = NH(CH2CH2SH)2] and monodentate tertiary phosphines with the [M Ξ N]2+ group (M = (99m)Tc, (188)Re). In the resulting complexes (dubbed3+1complexes), the tridentate ligand binds the [M Ξ N]2+ core through the two deprotonated, negatively charged, thiol sulfur atoms and the neutral, protonated, amine nitrogen atom. The residual fourth position of the five-coordinated arrangement is occupied by a phosphine ligand. The chemical identity of these model (99m)Tc and (188)Re compounds was established by comparison with the chromatographic properties of the corresponding complexes obtained at the macroscopic level with the long-lived (99)Tc and natural Re isotopes. The investigation was further extended to comprise a series of ligands formed by simple combinations of two basic amino acids or pseudo-amino acids to yield potential tridentate chelating systems having [S, N, S] and [N, N, S] as sets of π-donor atoms. Labeling yields and in vitro stability were investigated using different ancillary ligands. Results showed that SNS-type ligands afforded the highest labeling yields and the most robust 3+1 nitrido complexes with both (99m)Tc and (188)Re. Thus, the new chelating system can be conveniently employed for labeling peptides and other biomolecules with the [M Ξ N]2+ group. PMID:24106999

  2. Advanced laser remote sensing

    SciTech Connect

    Schultz, J.; Czuchlewski, S.; Karl, R.

    1996-11-01

    This is the final report of a three-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory. Remote measurement of wind velocities is critical to a wide variety of applications such as environmental studies, weather prediction, aircraft safety, the accuracy of projectiles, bombs, parachute drops, prediction of the dispersal of chemical and biological warfare agents, and the debris from nuclear explosions. Major programs to develop remote sensors for these applications currently exist in the DoD and NASA. At present, however, there are no real-time, three-dimensional wind measurement techniques that are practical for many of these applications and we report on two new promising techniques. The first new technique uses an elastic backscatter lidar to track aerosol patterns in the atmosphere and to calculate three dimensional wind velocities from changes in the positions of the aerosol patterns. This was first done by Professor Ed Eloranta of the University of Wisconsin using post processing techniques and we are adapting Professor Eloranta`s algorithms to a real-time data processor and installing it in an existing elastic backscatter lidar system at Los Alamos (the XM94 helicopter lidar), which has a compatible data processing and control system. The second novel wind sensing technique is based on radio-frequency (RF) modulation and spatial filtering of elastic backscatter lidars. Because of their compactness and reliability, solid state lasers are the lasers of choice for many remote sensing applications, including wind sensing.

  3. Sterically (un)encumbered mer-tridentate N-heterocyclic carbene complexes of titanium(iv) for the copolymerization of cyclohexene oxide with CO2.

    PubMed

    Hessevik, Julie; Lalrempuia, Ralte; Nsiri, Hajar; Törnroos, Karl W; Jensen, Vidar R; Le Roux, Erwan

    2016-10-01

    Titanium(iv) complexes bearing an unsubstituted tridentate bis(phenolate) N-heterocyclic carbene (NHC) were synthesized and structurally identified. While sterically unencumbered NHC-Ti(iv) complexes bearing chloro and alkoxy co-ligands tend to dimerize in solution and in solid-state, the use of a bulky aryloxy as co-ligand favors the monomeric species. Upon activation by onium salts, all these complexes were found to be highly selective towards the copolymerization of cyclohexene oxide (CHO) with CO2 under mild conditions (PCO2 < 1 bar), albeit the sterically unencumbered NHC-Ti(iv) complexes are less stable and active than their structural analogues bearing bulkier substituents.

  4. Environmental Survey preliminary report, Los Alamos National Laboratory, Los Alamos, New Mexico

    SciTech Connect

    Not Available

    1988-01-01

    This report presents the preliminary findings from the first phase of the Environmental Survey of the United States Department of Energy's (DOE) Los Alamos National Laboratory (LANL), conducted March 29, 1987 through April 17, 1987. The Survey is being conducted by an interdisciplinary team of environmental specialists, led and managed by the Office of Environment, Safety and Health's Office of Environmental Audit. Individual team components are outside experts being supplied by a private contractor. The objective of the Survey is to identify environmental problems and areas of environmental risk associated with the LANL. The Survey covers all environmental media and all areas of environmental regulation. It is being performed in accordance with the DOE Environmental Survey Manual. The on-site phase of the Survey involves the review of existing site environmental data, observations of the operations carried on at the LANL, and interviews with site personnel. The Survey team developed Sampling and Analysis Plan to assist in further assessing certain of the environmental problems identified during its on-site activities. The Sampling and Analysis Plan will be executed by the Idaho National Engineering Laboratory. When completed, the results will be incorporated into the LANL Environmental Survey Interim Report. The Interim Report will reflect the final determinations of the Survey for the LANL. 65 refs., 68 figs., 73 tabs.

  5. Environmental assessment for effluent reduction, Los Alamos National Laboratory, Los Alamos, New Mexico

    SciTech Connect

    1996-09-11

    The Department of Energy (DOE) proposes to eliminate industrial effluent from 27 outfalls at Los Alamos National Laboratory (LANL). The Proposed Action includes both simple and extensive plumbing modifications, which would result in the elimination of industrial effluent being released to the environment through 27 outfalls. The industrial effluent currently going to about half of the 27 outfalls under consideration would be rerouted to LANL`s sanitary sewer system. Industrial effluent from other outfalls would be eliminated by replacing once-through cooling water systems with recirculation systems, or, in a few instances, operational changes would result in no generation of industrial effluent. After the industrial effluents have been discontinued, the affected outfalls would be removed from the NPDES Permit. The pipes from the source building or structure to the discharge point for the outfalls may be plugged, or excavated and removed. Other outfalls would remain intact and would continue to discharge stormwater. The No Action alternative, which would maintain the status quo for LANL`s outfalls, was also analyzed. An alternative in which industrial effluent would be treated at the source facilities was considered but dismissed from further analysis because it would not reasonably meet the DOE`s purpose for action, and its potential environmental effects were bounded by the analysis of the Proposed Action and the No Action alternatives.

  6. Commercialization of Los Alamos National Laboratory technologies via small businesses. Final report

    SciTech Connect

    Brice, R.; Carton, D.; Rhyne, T.

    1997-06-01

    Appendices are presented from a study performed on a concept model system for the commercialization of Los Alamos National Laboratory technologies via small businesses. Topics include a summary of information from the joint MCC/Los Alamos technology conference; a comparison of New Mexico infrastructure to other areas; a typical licensing agreement; technology screening guides; summaries of specific DOE/UC/Los Alamos documents; a bibliography; the Oak Ridge National Laboratory TCRD; The Ames Center for Advanced Technology Development; Los Alamos licensing procedures; presentation of slides from monthly MCC/Los Alamos review meetings; generalized entrepreneurship model; and a discussion on receiving equity for technology.

  7. Trident: A three-pronged galaxy survey. I. Lyman alpha emitting galaxies at z ~ 2 in GOODS North

    NASA Astrophysics Data System (ADS)

    Sandberg, A.; Guaita, L.; Östlin, G.; Hayes, M.; Kiaeerad, F.

    2015-08-01

    Context. Lyman alpha (Lyα) emitting galaxies (LAEs) are used to probe the distant universe and are therefore important for galaxy evolution studies and for providing clues to the nature of the epoch of reionization. However, the exact circumstances under which Lyα escapes a galaxy are still not fully understood. Aims: The Trident project is designed to simultaneously examine Lyα, Hα, and Lyman continuum emission from galaxies at redshift z ~ 2, thus linking these three aspects of ionizing radiation in galaxies. In this paper, we outline the strategy of this project and examine the properties of LAEs in the GOODS North field. Methods: We performed a narrowband LAE survey in GOODS North using existing filters and two custom made filters at the Nordic Optical Telescope with MOSCA. We use complementary broadband archival data in the field to make a careful candidate selection and perform optical to near-IR SED fitting. We also estimate far-IR luminosities by matching our candidates to detections in Spitzer/MIPS 24 μm and Herschel/PACS catalogues. Results: We find a total of 25 LAE candidates, probing mainly the bright end of the LAE luminosity function with LLyα ~ 1-15 × 1042 erg s-1. They display a range of masses of ~ 0.5-50 × 109M⊙, and average ages from a few tens of Myr to 1 Gyr when assuming a constant star formation history. The majority of our candidates also show signs of recent elevated star formation. Three candidates have counterparts in the GOODS-Herschel far-IR catalogue, with luminosities consistent with ultra-luminous infrared galaxies (ULIRGs). Conclusions: The wide range of parameters derived from our SED fitting, as well as part of our sample being detected as ULIRGs, seems to indicate that at these Lyα luminosities, LAEs do not necessarily have to be young dwarfs, and that a lack of dust is not required for Lyα to escape. Based on observations made with the Nordic Optical Telescope, operated by the Nordic Optical Telescope Scientific

  8. A novel bis tridentate bipyridine carboxamide ligand and its complexation to copper(II): synthesis, structure, and magnetism.

    PubMed

    Wang, Jian; Djukic, Brandon; Cao, Jingyi; Alberola, Antonio; Razavi, Fereidoon S; Pilkington, Melanie

    2007-10-15

    A new bis tridentate ligand 2,2'-bipyridine-3,3'-[2-pyridinecarboxamide] H(2)L(1) which can bind transition metal ions has been synthesized via the condensation of 3,3'-diamino-2,2'-bipyridine together with 2-pyridine carbonyl chloride. Two copper(II) coordination compounds have been prepared and characterized: [Cu(2)(L(1))(hfac)(2)].3CH(3)CN.H(2)O (1) and [Cu(2)(L(1))Cl(2)].CH(3)CN (2). The single-crystal X-ray structures reveal that complex 1 crystallizes in the triclinic space group P1, with the unit cell parameters a = 12.7185(6) A, b = 17.3792(9) A, c = 19.4696(8) A, alpha = 110.827(2) degrees, beta = 99.890(3) degrees, gamma = 97.966(3) degrees, V = 3868.3(3) A3, Z = 4, R = 0.0321 and R(w) = 0.0826. Complex 2 crystallizes in the monoclinic space group P2(1)/n with the unit cell parameters a = 12.8622(12) A, b = 9.6100(10) A, c = 19.897(2) A, beta = 102.027(3) degrees, V = 2405.3(4) A(3), Z = 4, R = 0.0409 and R(w) = 0.1005. In both complexes the ligand is in the dianionic form and coordinates the divalent Cu(II) ions via one amido and two pyridine nitrogen donor atoms. In 1, the coordination geometry around both Cu(II) ions is best described as distorted trigonal bipyramidal where the remaining two coordination sites are satisfied by hexafluoroacetylacetonate counterions. In 2 both Cu(II )ions adopt a (4 + 1) distorted square pyramidal geometry. One copper forms a longer apical bond to an adjacent carbonyl oxygen atom, whereas the second copper is chelated to a neighboring Cu-Cl chloride ion to afford a mu-Cl-bridged dimerized [Cu(2)(L(1))Cl(2)](2) complex. The magnetic susceptibility data for 1 (2 -270 K), reveal the occurrence of weak antiferromagnetic interactions between the Cu(II) ions. In contrast, variable-temperature magnetic susceptibility measurements for 2 reveal more complex magnetic properties, with the presence of a weak antiferromagnetic exchange (J = -10.1 K) between the copper ions in each dinuclear copper complex and a stronger ferromagnetic

  9. Stability and Size-Discriminating Effects in Mononuclear Lanthanide Triple-Helical Building Blocks with Tridentate Aromatic Ligands.

    PubMed

    Petoud, Stéphane; Bünzli, Jean-Claude G.; Renaud, Fabien; Piguet, Claude; Schenk, Kurt J.; Hopfgartner, Gérard

    1997-12-01

    The planar aromatic tridentate ligand 2,6-bis(1-methylbenzimidazol-2-yl)pyridine (L(1)) reacts with Ln(III) (Ln = La-Lu) in acetonitrile to give the successive complexes [Ln(L(1))(n)()](3+) (n = 1-3). Stability constants determined by spectrophotometry and potentiometric competitive titrations with Ag(I) show that the 1:1 and the 1:2 complexes display the usual thermodynamic behavior associated with electrostatic effects while the 1:3 complexes exhibit an unusual selectivity for the midrange Ln(III) ions (Delta log K(3)(Gd-Lu) approximately 4). A detailed investigation of the solution structure of [Ln(L(1))(3)](3+) (Ln = La-Dy) reveals that the closely packed triple-helical structure found in the crystal structure of [Eu(L(1))(3)](3+) is retained in acetonitrile for the complete series. A sharp control of the coordination cavity results from the interstrand pi-stacking interactions which appear to be optimum for Gd(III). For Yb(III), for instance, a 1:2 complex only could be isolated, which crystallizes as a hydroxo-bridged dimer [Yb(OH)(L(1))(2)](2)(ClO(4))(4)(HClO(4))(0.5)(CH(3)CN)(7.32)(L(1))(0.5) (triclinic, P&onemacr;, a = 13.250(2) Å, b = 16.329(2) Å, c = 27.653(3) Å, alpha = 99.941(9) degrees, beta = 93.394(9) degrees, gamma = 108.114(9) degrees, Z = 2). The binding of bulky substituents to the nitrogen atoms of the benzimidazole side arms in L(4) (i) severely affects the wrapping process, (ii) leads to less stable triple-helical building blocks, and (iii) removes the size-discriminating effect. The last can however be restored if a strong electron-donor group is connected to the central pyridine ring in L(8). Stability and solution structure data for [Ag(2)(L(i)())(2)](2+) (i = 1, 4, 8) are also reported and discussed. PMID:11670196

  10. Laser interaction with pseudoblood clots

    NASA Astrophysics Data System (ADS)

    Paisley, Dennis L.; Stahl, David B.

    1997-05-01

    In recent years lasers have become a common tool for medical procedures. Lasers are typically used to deliver energy/power to a biological specimen to alter its characteristics, fuse tissue or destroy a particular structure. Under a Los Alamos CRADA, we have been working with a medical laser company and a laser medical center to study the laser interaction with pseudo-blood clots that are typical of those found in human coronary arteries. A 577-nm flash lamp pumped dye laser beam is pulsed through a 300- micron optical fiber to deliver the laser energy on the surface of a pseudo-clot material. The fiber and pseudo-clot are surrounded by water or x-ray contrast fluid transparent at 577 and 514 nm. The laser-pulse/clot interaction creates a bubble at the water-clot interface. The bubble expands out and collapses back on the pseudo-clot resulting part of the clot being removed. Using a backlight technique with an electronic framing camera we record the bubble growth, expansion, and collapse, and the debris generated by the interaction.

  11. Synthesis, crystal structure, fluorescence and electrochemical studies of a new tridentate Schiff base ligand and its nickel(II) and palladium(II) complexes

    NASA Astrophysics Data System (ADS)

    Shafaatian, Bita; Soleymanpour, Ahmad; Kholghi Oskouei, Nasim; Notash, Behrouz; Rezvani, Seyyed Ahmad

    2014-07-01

    A new unsymmetrical tridentate Schiff base ligand was derived from the 1:1 M condensation of ortho-vanillin with 2-mercaptoethylamine. Nickel and palladium complexes were obtained by the reaction of the tridentate Schiff base ligand with nickel(II) acetate tetrahydrate and palladium(II) acetate in 2:1 M ratio. In nickel and palladium complexes the ligand was coordinated to metals via the imine N and enolic O atoms. The S groups of Schiff bases were not coordinated to the metals and S-S coupling was occured. The complexes have been found to possess 1:2 Metal:Ligand stoichiometry and the molar conductance data revealed that the metal complexes were non-electrolytes. The complexes exhibited octahedral coordination geometry. The emission spectra of the ligand and its complexes were studied in methanol. Electrochemical properties of the ligand and its metal complexes were investigated in the CH3CN solvent at the 100 mV s-1 scan rate. The ligand and metal complexes showed both reversible and quasi-reversible processes at this scan rate. The Schiff base and its complexes have been characterized by IR, 1H NMR, UV/Vis, elemental analyses and conductometry. The crystal structure of nickel complex has been determined by single crystal X-ray diffraction.

  12. Synthesis, crystal structure, fluorescence and electrochemical studies of a new tridentate Schiff base ligand and its nickel(II) and palladium(II) complexes.

    PubMed

    Shafaatian, Bita; Soleymanpour, Ahmad; Kholghi Oskouei, Nasim; Notash, Behrouz; Rezvani, Seyyed Ahmad

    2014-07-15

    A new unsymmetrical tridentate Schiff base ligand was derived from the 1:1M condensation of ortho-vanillin with 2-mercaptoethylamine. Nickel and palladium complexes were obtained by the reaction of the tridentate Schiff base ligand with nickel(II) acetate tetrahydrate and palladium(II) acetate in 2:1M ratio. In nickel and palladium complexes the ligand was coordinated to metals via the imine N and enolic O atoms. The S groups of Schiff bases were not coordinated to the metals and S-S coupling was occured. The complexes have been found to possess 1:2 Metal:Ligand stoichiometry and the molar conductance data revealed that the metal complexes were non-electrolytes. The complexes exhibited octahedral coordination geometry. The emission spectra of the ligand and its complexes were studied in methanol. Electrochemical properties of the ligand and its metal complexes were investigated in the CH3CN solvent at the 100 mV s(-1) scan rate. The ligand and metal complexes showed both reversible and quasi-reversible processes at this scan rate. The Schiff base and its complexes have been characterized by IR, (1)H NMR, UV/Vis, elemental analyses and conductometry. The crystal structure of nickel complex has been determined by single crystal X-ray diffraction.

  13. Ruthenium(II) bipyridine complexes bearing quinoline-azoimine (NN‧N″) tridentate ligands: Synthesis, spectral characterization, electrochemical properties and single-crystal X-ray structure analysis

    NASA Astrophysics Data System (ADS)

    Al-Noaimi, Mousa; Abdel-Rahman, Obadah S.; Fasfous, Ismail I.; El-khateeb, Mohammad; Awwadi, Firas F.; Warad, Ismail

    Four octahedral ruthenium(II) azoimine-quinoline complexes having the general molecular formula [RuII(Lsbnd Y)(bpy)Cl](PF6) {Lsbnd Y = YC6H4Ndbnd NC(COCH3)dbnd NC9H6N, Y = H (1), CH3 (2), Br (3), NO2 (4) and bpy = 2,2‧-bipyrdine} were synthesized. The azoimine-quinoline based ligands behave as NN‧N″ tridentate donors and coordinated to ruthenium via azo-N‧, imine-N‧ and quinolone-N″ nitrogen atoms. The composition of the complexes has been established by elemental analysis, spectral methods (FT-IR, electronic, 1H NMR, UV/Vis and electrochemical (cyclic voltammetry) techniques. The crystal structure of complex 1 is reported. The Ru(II) oxidation state is greatly stabilized by the novel tridentate ligands, showing Ru(III/II) couples ranging from 0.93-1.27 V vs. Cp2Fe/Cp2Fe+. The absorption spectrum of 1 in dichloromethane was modeled by time-dependent density functional theory (TD-DFT).

  14. Metal-assisted in situ formation of a tridentate acetylacetone ligand for complexation of fac-Re(CO)3+ for radiopharmaceutical applications.

    PubMed

    Benny, Paul D; Fugate, Glenn A; Barden, Adam O; Morley, Jennifer E; Silva-Lopez, Elsa; Twamley, Brendan

    2008-04-01

    Reaction of [NEt4]2[ReBr3(CO)3] with 2,4-pentanedione (acac) yields a complex of the type fac-Re(acac)(OH2)(CO)3 (1) under aqueous conditions. 1 was further reacted with a monodentate ligand (pyridine) to yield a fac-Re(acac)(pyridine)(CO)3 complex (2). Complex 1 was found to react with primary amines to generate a Schiff base (imine) in aqueous solutions. When a mixed-nitrogen donor bidentate ligand, 2-(2-aminoethyl)pyridine, that has different coordination affinities for fac-Re(acac)(OH2)(CO)3 was utilized, a unique tridentate ligand was formed in situ utilizing a metal-assisted Schiff base formation to yield a complex fac-Re(CO)3(3[(2-phenylethyl)imino]-2-pentanone) (3). Tridentate ligand formation was found to occur only with the Re-coordinated acac ligand. Reactions of acac with fac-Re(CO)3Br(2-(2-aminoethyl)pyridine) (4) or a mixture of [NEt4]2[ReBr3(CO)3], acac, and 2-(2-aminoethyl)pyridine did not yield the formation of complex 3 in water. PMID:18298058

  15. Synthesis, characterization and electrochemical behavior of some Ni(II), Cu(II), Co(II) and Cd(II) complexes of ONS type tridentate Schiff base ligand

    NASA Astrophysics Data System (ADS)

    Durmus, Sefa; Atahan, Alparslan; Zengin, Mustafa

    2011-12-01

    Tridentate Schiff base (H 2L) ligand was synthesized via condensation of o-hydroxybenzaldehyde and 2-aminothiophenol. The metal complexes were prepared from reaction of the ligand with corresponding metal salts presence of substituted pyridine in two different solvents (MeOH or MeCN). The ligand and metal complexes were then characterized by using FTIR, TGA, 1H NMR and 13C NMR spectroscopies. The FTIR spectra showed that H 2L was coordinated to the metal ions in tridentate manner with ONS donor sites of the azomethine N, deprotonated phenolic-OH and phenolic-SH. Furthermore, substituted pyridine was coordinated to the central metal atoms. The thermal behavior of the complexes was investigated by using TGA method and dissociations indicated that substituted pyridine and ligand were leaved from coordination. This coordination of the metal complexes was correlated by 1H NMR and 13C NMR. Finally, electrochemical behavior of the ligand and a Ni(II) complex were investigated.

  16. The engineering institute of Los Alamos National Laboratory

    SciTech Connect

    Farrar, Charles R; Park, Gyuhae; Cornwell, Phillip J; Todd, Michael D

    2008-01-01

    Los Alamos National Laboratory (LANL) and the University of California, San Diego (UCSD) have taken the unprecedented step of creating a collaborative, multi-disciplinary graduate education program and associated research agenda called the Engineering Institute. The mission of the Engineering Institute is to develop a comprehensive approach for conducting LANL mission-driven, multidisciplinary engineering research and to improve recruiting, revitalization, and retention of the current and future staff necessary to support the LANL' s national security responsibilities. The components of the Engineering Institute are (1) a joint LANL/UCSD degree program, (2) joint LANL/UCSD research projects, (3) the Los Alamos Dynamic Summer School, (4) an annual workshop, and (5) industry short courses. This program is a possible model for future industry/government interactions with university partners.

  17. Tiger Team Assessment of the Los Alamos National Laboratory

    SciTech Connect

    Not Available

    1991-11-01

    This report documents the Tiger Team Assessment of the Los Alamos National Laboratory (LANL) located in Los Alamos, New Mexico. LANL is operated for the US Department of Energy (DOE) by the University of California. The Tiger Team Assessment was conducted from September 23 to November 8, 1991, under the auspices of the DOE Office of Special Projects, Office of Assistant Secretary for Environment, Safety and Health. The assessment was comprehensive, encompassing environmental, safety, and health (ES H) disciplines; management; and contractor and DOE self-assessments. Compliance with applicable Federal, state, and local regulations; applicable DOE Orders; best management practices; and internal LANL site requirements was assessed. In addition, an evaluation of the adequacy and effectiveness of the DOE and the site contractors' management of ES H/quality assurance programs was conducted. This volume discusses findings concerning the environmental assessment.

  18. Airport-Noise Levels and Annoyance Model (ALAMO) user's guide

    NASA Technical Reports Server (NTRS)

    Deloach, R.; Donaldson, J. L.; Johnson, M. J.

    1986-01-01

    A guide for the use of the Airport-Noise Level and Annoyance MOdel (ALAMO) at the Langley Research Center computer complex is provided. This document is divided into 5 primary sections, the introduction, the purpose of the model, and an in-depth description of the following subsystems: baseline, noise reduction simulation and track analysis. For each subsystem, the user is provided with a description of architecture, an explanation of subsystem use, sample results, and a case runner's check list. It is assumed that the user is familiar with the operations at the Langley Research Center (LaRC) computer complex, the Network Operating System (NOS 1.4) and CYBER Control Language. Incorporated within the ALAMO model is a census database system called SITE II.

  19. Penetrating radiation: applications at Los Alamos National Laboratory

    NASA Astrophysics Data System (ADS)

    Watson, Scott; Hunter, James; Morris, Christopher

    2013-09-01

    Los Alamos has used penetrating radiography extensively throughout its history dating back to the Manhattan Project where imaging dense, imploding objects was the subject of intense interest. This interest continues today as major facilities like DARHT1 have become the mainstay of the US Stockpile Stewardship Program2 and the cornerstone of nuclear weapons certification. Meanwhile, emerging threats to national security from cargo containers and improvised explosive devices (IEDs) have invigorated inspection efforts using muon tomography, and compact x-ray radiography. Additionally, unusual environmental threats, like those from underwater oil spills and nuclear power plant accidents, have caused renewed interest in fielding radiography in severe operating conditions. We review the history of penetrating radiography at Los Alamos and survey technologies as presently applied to these important problems.

  20. Using the Internet in Middle Schools: A Model for Success. A Collaborative Effort between Los Alamos National Laboratory (LANL) and Los Alamos Middle School (LAMS).

    ERIC Educational Resources Information Center

    Addessio, Barbara K.; And Others

    Los Alamos National Laboratory (LANL) developed a model for school networking using Los Alamos Middle School as a testbed. The project was a collaborative effort between the school and the laboratory. The school secured administrative funding for hardware and software; and LANL provided the network architecture, installation, consulting, and…

  1. Automated medical information system of the Los Alamos Scientific Laboratory

    SciTech Connect

    Eagan, G.D.; Grier, R.S.

    1980-01-01

    The Medical Information System (MIS) at the Los Alamos Scientific Laboratory automates the acquisition, storage, and retrieval of medical information concerning the nine thousand project-connected personnel. The MIS incorporates an on-line, interactive medical history questionnaire, mark sense form processing, and automated coronary risk assesment in the medical evaluation process. Also, MIS has created the ability for long-term study and comparison of employee health as well as made the physician's time more effective.

  2. Los Alamos Canyon Ice Rink Parking Flood Plain Assessment

    SciTech Connect

    Hathcock, Charles Dean

    2015-02-10

    The project location is in Los Alamos Canyon east of the ice rink facility at the intersection of West and Omega roads (Figure 1). Forty eight parking spaces will be constructed on the north and south side of Omega Road, and a lighted walking path will be constructed to the ice rink. Some trees will be removed during this action. A guardrail of approximately 400 feet will be constructed along the north side of West Road to prevent unsafe parking in that area.

  3. Evolution of some Los Alamos flux compression programs

    SciTech Connect

    Fowler, C.M.; Goforth, J.H.

    1996-12-31

    When we were approached to give a general discussion of some aspects of the Los Alamos flux compression program, we decided to present historical backgrounds of a few topics that have some relevance to programs that we very much In the forefront of activities going on today. Of some thirty abstracts collected at Los Alamos for this conference, ten of them dealt with electromagnetic acceleration of materials, notably the compression of heavy liners, and five dealt with plasma compression. Both of these topics have been under investigation, off and on, from the time a formal flux compression program was organized at Los Alamos. We decided that a short overview of work done In these areas would be of some interest. Some of the work described below has been discussed in Laboratory reports that, while referenced and available, are not readily accessible. For completeness, some previously published, accessible work Is also discussed but much more briefly. Perhaps the most striking thing about the early work In these two areas is how primitive much of it was when compared to the far more sophisticated, related activities of today. Another feature of these programs, actually for most programs, Is their cyclic nature. Their relevance and/or funding seems to come land go. Eventually, many of the older programs come back into favor. Activities Involving the dense plasma focus (DPF), about which some discussions will be given later, furnish a classic example of this kind, coming Into and then out of periods of heightened interest. We devote the next two sections of this paper to a review of our work In magnetic acceleration of solids and of plasma compression. A final section gives a survey of our work In which thin foils are imploded to produce intense quantities of son x-rays. The authors are well aware of much excellent work done elsewhere In all of these topics, but partly because of space limitations, have confined this discussion to work done at Los Alamos.

  4. Los Alamos Science: The Human Genome Project. Number 20, 1992

    DOE R&D Accomplishments Database

    Cooper, N. G.; Shea, N. eds.

    1992-01-01

    This document provides a broad overview of the Human Genome Project, with particular emphasis on work being done at Los Alamos. It tries to emphasize the scientific aspects of the project, compared to the more speculative information presented in the popular press. There is a brief introduction to modern genetics, including a review of classic work. There is a broad overview of the Genome Project, describing what the project is, what are some of its major five-year goals, what are major technological challenges ahead of the project, and what can the field of biology, as well as society expect to see as benefits from this project. Specific results on the efforts directed at mapping chromosomes 16 and 5 are discussed. A brief introduction to DNA libraries is presented, bearing in mind that Los Alamos has housed such libraries for many years prior to the Genome Project. Information on efforts to do applied computational work related to the project are discussed, as well as experimental efforts to do rapid DNA sequencing by means of single-molecule detection using applied spectroscopic methods. The article introduces the Los Alamos staff which are working on the Genome Project, and concludes with brief discussions on ethical, legal, and social implications of this work; a brief glimpse of genetics as it may be practiced in the next century; and a glossary of relevant terms.

  5. Los Alamos, Toshiba probing Fukushima with cosmic rays

    ScienceCinema

    Morris, Christopher

    2016-07-12

    Los Alamos National Laboratory has announced an impending partnership with Toshiba Corporation to use a Los Alamos technique called muon tomography to safely peer inside the cores of the Fukushima Daiichi reactors and create high-resolution images of the damaged nuclear material inside without ever breaching the cores themselves. The initiative could reduce the time required to clean up the disabled complex by at least a decade and greatly reduce radiation exposure to personnel working at the plant. Muon radiography (also called cosmic-ray radiography) uses secondary particles generated when cosmic rays collide with upper regions of Earth's atmosphere to create images of the objects that the particles, called muons, penetrate. The process is analogous to an X-ray image, except muons are produced naturally and do not damage the materials they contact. Muon radiography has been used before in imaginative applications such as mapping the interior of the Great Pyramid at Giza, but Los Alamos's muon tomography technique represents a vast improvement over earlier technology.

  6. Los Alamos, Toshiba probing Fukushima with cosmic rays

    SciTech Connect

    Morris, Christopher

    2014-06-16

    Los Alamos National Laboratory has announced an impending partnership with Toshiba Corporation to use a Los Alamos technique called muon tomography to safely peer inside the cores of the Fukushima Daiichi reactors and create high-resolution images of the damaged nuclear material inside without ever breaching the cores themselves. The initiative could reduce the time required to clean up the disabled complex by at least a decade and greatly reduce radiation exposure to personnel working at the plant. Muon radiography (also called cosmic-ray radiography) uses secondary particles generated when cosmic rays collide with upper regions of Earth's atmosphere to create images of the objects that the particles, called muons, penetrate. The process is analogous to an X-ray image, except muons are produced naturally and do not damage the materials they contact. Muon radiography has been used before in imaginative applications such as mapping the interior of the Great Pyramid at Giza, but Los Alamos's muon tomography technique represents a vast improvement over earlier technology.

  7. James L. Tuck Los Alamos ball lightning pioneer

    SciTech Connect

    Baker, D.A.

    1999-07-01

    James Tuck was well known for starting the Project Sherwood group at Los Alamos Scientific Laboratory in 1952. This group was formed to study and develop concepts for controlled fusion energy. In his later years after retiring from Controlled Fusion Division, he continued research at Los Alamos on the topic of ball lightning. He traveled widely giving lectures on both observations of others and his own experimental efforts. He collected anecdotal observations obtained from those in his lecture audiences during his travels and from responses from newspaper articles where he asked for specific information from ball lightning observers. He finally cut off this collection of data when the number of responses became overwhelming. The author's primary publication on ball lightning was a short laboratory report. He planned on publishing a book on the subject but this was never completed before his death. Tuck focused his experimental effort on attempting to duplicate the production of plasma balls claimed to be observed in US Navy submarines when a switch was opened under overload conditions with battery power. During lunch breaks he made use of a Los Alamos N-division battery bank facility to mock up a submarine power pack and switch gear. This non-funded effort was abruptly terminated when an explosion occurred in the facility. An overview of Tuck's research and views will be given. The flavor Jim's personality as well as a ball produced with his experimental apparatus will be shown using video chips.

  8. Los Alamos Science: The Human Genome Project. Number 20, 1992

    SciTech Connect

    Cooper, N G; Shea, N

    1992-01-01

    This article provides a broad overview of the Human Genome Project, with particular emphasis on work being done at Los Alamos. It tries to emphasize the scientific aspects of the project, compared to the more speculative information presented in the popular press. There is a brief introduction to modern genetics, including a review of classic work. There is a broad overview of the Genome Project, describing what the project is, what are some of its major five-year goals, what are major technological challenges ahead of the project, and what can the field of biology, as well as society expect to see as benefits from this project. Specific results on the efforts directed at mapping chromosomes 16 and 5 are discussed. A brief introduction to DNA libraries is presented, bearing in mind that Los Alamos has housed such libraries for many years prior to the Genome Project. Information on efforts to do applied computational work related to the project are discussed, as well as experimental efforts to do rapid DNA sequencing by means of single-molecule detection using applied spectroscopic methods. The article introduces the Los Alamos staff which are working on the Genome Project, and concludes with brief discussions on ethical, legal, and social implications of this work; a brief glimpse of genetics as it may be practiced in the next century; and a glossary of relevant terms.

  9. Laser-launched flyers with organic working fluids

    NASA Astrophysics Data System (ADS)

    Mulford, Roberta; Swift, Damian

    2003-10-01

    The TRIDENT laser has been used to launch flyers by depositing IR energy in a thin layer of material - the working fluid - sandwiched between the flyer and a transparent substrate. We have investigated the use of working fluids based on organics, chosen as they are quite efficient absorbers of IR energy and should also convert heat to mechanical work more efficiently than materials such as carbon. A thermodynamically complete equation of state was developed for one of the fluids investigated experimentally - a carbohydrate solution - by chemical equilibrium calculations using the CHEETAH program. Continuum mechanics simulations were made of the flyer launch process, modeling the effect of the laser as energy deposition in the working fluid, and taking into account the compression and recoil of the substrate. We compare the simulations with a range of experiments and demonstrate the optimization of substrate and fluid thickness for a given flyer thickness and speed.

  10. The Trident Pacific model. Part 2: role of long equatorial wave reflection on sea surface temperature anomalies during the 1993-1998 TOPEX/POSEIDON period

    NASA Astrophysics Data System (ADS)

    Boulanger, J.-P.; Menkes, C.

    The present study aims to give a quantitative description of the role played by long equatorial waves on sea surface temperature anomalies during the 1993-1998 TOPEX/POSEIDON period and more specifically during the 1997-1998 El Niño using a new Pacific Ocean model called Trident. In a companion paper, the Trident dynamical component was described and validated with observations. Briefly, the model exhibits skill in simulating not only sea level but also surface zonal current variability in the equatorial wave guide. Here the model thermodynamics are described and validated. The thermodynamics of Trident consist of one single equation for interannual sea surface temperature anomalies. Compared to other similar models, the introduction in the temperature equation of a term equivalent to a vertical mixing term improves significantly the temperature simulations in the eastern Pacific. Thus the model comparison to interannual sea level, zonal current and sea surface temperature anomalies is fairly good over the entire equatorial Pacific Ocean. The model is found to be sensitive to both subsurface variability (central and eastern Pacific) and to zonal current advection, especially near the dateline where the data suggest that advection is a first order process for determining sea surface temperature changes. The role of long equatorial wave reflection observed in TOPEX/POSEIDON data is studied by either cancelling the eastern boundary or western boundary reflection. First, at the eastern boundary, although the reflected Rossby waves were found to act against the warming during the onset phase of the 1997-1998 El Niño through zonal advection, the major impact of these reflected Rossby waves was to reinforce the deepening of the thermocline in the eastern Pacific initiated by the impinging Kelvin waves. Therefore, all things considered, the Rossby waves strongly contributed to the warming in 1997-1998 east of 120°W. Secondly, at the western boundary, Rossby wave

  11. Self-assembly of copper(II) complexes with a dibasic tridentate ligand and monodentate N-heterocycles: structural, magnetic and EPR studies

    NASA Astrophysics Data System (ADS)

    Das, Sunirban; Pal, Samudranil

    2005-05-01

    Three ternary copper(II) complexes of general formula [Cu(bhac)(hc)], with a tridentate Schiff base, acetylacetone benzoylhydrazone (H 2bhac) and monodentate N-heterocycles (hc=pyrazole, imidazole and pyridine), have been synthesized. Elemental analysis, various forms of spectroscopy (infrared, electronic absorption and EPR), cyclic voltammetry, cryomagnetic measurements and X-ray crystallography were used for the characterization of the complexes. Analytical data, infrared and electronic spectral features and molar conductivity values are consistent with the proposed molecular formulae and the +2 oxidation state of the metal ion in these complexes. In each complex, the enolate-O, the imine-N and the deprotonated amide-O donor tridentate ligand (bhac 2-) and the sp 2 N donor heterocycle form an O 2N 2 square-plane around the metal ion. The whole molecule of none of the complexes is perfectly planar because of different orientation of the phenyl ring plane of the tridentate ligand and that of the heterocycle ring plane with respect to the plane containing rest of the molecule. In the solid state, the complexes having the pyrazole and the pyridine as the heterocyclic ligand, exist as centrosymmetric dimeric species due to very weak apical coordination of the metal bound enolate-O. The complex of imidazole has no such apical coordination and exists as a monomer. In the crystal lattice, the molecules of these complexes are involved in a variety of intermolecular non-covalent interactions such as O-H⋯O, N-H⋯O, N-H⋯N, C-H⋯π and π⋯π. Self-assembly via these interactions lead to a one-dimensional arrangement of [Cu(bhac)(Hpyrz)]·C 2H 5OH, a two-dimensional layered structure of [Cu(bhac)(Himdz)] and a three-dimensional network of [Cu(bhac)(py)]. Cryomagnetic and EPR spectral measurements indicates weak antiferromagnetic spin-exchange in all the three complexes.

  12. Audit Report, "Fire Protection Deficiencies at Los Alamos National Laboratory"

    SciTech Connect

    2009-06-01

    The Department of Energy's Los Alamos National Laboratory (Los Alamos) maintains some of the Nation's most important national security assets, including nuclear materials. Many of Los Alamos' facilities are located in close proximity to one another, are occupied by large numbers of contract and Federal employees, and support activities ranging from nuclear weapons design to science-related activities. Safeguarding against fires, regardless of origin, is essential to protecting employees, surrounding communities, and national security assets. On June 1, 2006, Los Alamos National Security, LLC (LANS), became the managing and operating contractor for Los Alamos, under contract with the Department's National Nuclear Security Administration (NNSA). In preparation for assuming its management responsibilities at Los Alamos, LANS conducted walk-downs of the Laboratory's facilities to identify pre-existing deficiencies that could give rise to liability, obligation, loss or damage. The walk-downs, which identified 812 pre-existing fire protection deficiencies, were conducted by subject matter professionals, including fire protection experts. While the Los Alamos Site Office has overall responsibility for the effectiveness of the fire protection program, LANS, as the Laboratory's operating contractor, has a major, day-to-day role in minimizing fire-related risks. The issue of fire protection at Los Alamos is more than theoretical. In May 2000, the 'Cerro Grande' fire burned about 43,000 acres, including 7,700 acres of Laboratory property. Due to the risk posed by fire to the Laboratory's facilities, workforce, and surrounding communities, we initiated this audit to determine whether pre-existing fire protection deficiencies had been addressed. Our review disclosed that LANS had not resolved many of the fire protection deficiencies that had been identified in early 2006: (1) Of the 296 pre-existing deficiencies we selected for audit, 174 (59 percent) had not been corrected

  13. Two new copper(II) complexes with the shortest (N N) diazine based rigid ligand: Example of unusual tridentate coordination mode

    NASA Astrophysics Data System (ADS)

    Karmakar, Ruma; Choudhury, Chirantan Roy; Batten, Stuart R.; Mitra, Samiran

    2007-01-01

    Two new five coordinated Cu(II) complexes, Cu(L)Cl 2,CH 3OH ( 1) and Cu(L)Br 2 ( 2) derived from the flexidentate ligand (L), 2-pyridinealdazine, have been synthesised and characterised by spectroscopic and electrochemical studies. Single crystal structures of the complexes were determined. Crystal structures of both the complexes contain monomeric entities of five coordinated copper(II) ions where the Schiff base ligand, 2-pyridinealdazine, acts in a tridentate fashion. The central part of the ligand in complex 2 is disordered over two positions: N8 sbnd N9 make up the major position and N8A sbnd N9A make up the minor position.

  14. Iron-Catalyzed Ortho C-H Methylation of Aromatics Bearing a Simple Carbonyl Group with Methylaluminum and Tridentate Phosphine Ligand.

    PubMed

    Shang, Rui; Ilies, Laurean; Nakamura, Eiichi

    2016-08-17

    Iron-catalyzed C-H functionalization of aromatics has attracted widespread attention from chemists in recent years, while the requirement of an elaborate directing group on the substrate has so far hampered the use of simple aromatic carbonyl compounds such as benzoic acid and ketones, much reducing its synthetic utility. We describe here a combination of a mildly reactive methylaluminum reagent and a new tridentate phosphine ligand for metal catalysis, 4-(bis(2-(diphenylphosphanyl)phenyl)phosphanyl)-N,N-dimethylaniline (Me2N-TP), that allows us to convert an ortho C-H bond to a C-CH3 bond in aromatics and heteroaromatics bearing simple carbonyl groups under mild oxidative conditions. The reaction is powerful enough to methylate all four ortho C-H bonds in benzophenone. The reaction tolerates a variety of functional groups, such as boronic ester, halide, sulfide, heterocycles, and enolizable ketones.

  15. Zn(II), Ni(II), Cu(II) and Pb(II) complexes of tridentate asymmetrical Schiff base ligands: Synthesis, characterization, properties and biological activity

    NASA Astrophysics Data System (ADS)

    Şahin, Mustafa; Koçak, Nuriye; Erdenay, Damla; Arslan, Uğur

    2013-02-01

    New asymmetrical tridentate Schiff base ligands were synthesized using 1,2-phenylenediamine, 4-methyl-1,2-phenylenediamine, 2-hydroxy-1-napthaldehyde, 9-anthracenecarboxaldehyde. Schiff base ligands and their metal complexes were synthesised and characterized by using FT-IR, 1H NMR, 13C NMR, UV-Vis, XRD, ESR, elemental analysis and fluorescence studies. The antimicrobial activity of the ligands and their metal complexes were studied against Staphylococcus aureus ATCC 29213, S. aureus ATCC 25923, Streptococcus mutans RSHM 676, Enterococcus faecalis ATCC 29212, Escherichia coli ATCC 25922, Pseudomonas aeruginosa ATCC 27853. The determination of the antibacterial activity was done using the broth microdilution methods. In general, it has been determined that the studied compounds have MIC values similar to Gram-positive and Gram-negative bacteria. It has been found that Ni, Pb, Zn derivatives of HL1A and ZnL2A has lower MIC values than ampicillin for P. aeruginosa ATCC 27853 strain.

  16. Iron-Catalyzed Ortho C-H Methylation of Aromatics Bearing a Simple Carbonyl Group with Methylaluminum and Tridentate Phosphine Ligand.

    PubMed

    Shang, Rui; Ilies, Laurean; Nakamura, Eiichi

    2016-08-17

    Iron-catalyzed C-H functionalization of aromatics has attracted widespread attention from chemists in recent years, while the requirement of an elaborate directing group on the substrate has so far hampered the use of simple aromatic carbonyl compounds such as benzoic acid and ketones, much reducing its synthetic utility. We describe here a combination of a mildly reactive methylaluminum reagent and a new tridentate phosphine ligand for metal catalysis, 4-(bis(2-(diphenylphosphanyl)phenyl)phosphanyl)-N,N-dimethylaniline (Me2N-TP), that allows us to convert an ortho C-H bond to a C-CH3 bond in aromatics and heteroaromatics bearing simple carbonyl groups under mild oxidative conditions. The reaction is powerful enough to methylate all four ortho C-H bonds in benzophenone. The reaction tolerates a variety of functional groups, such as boronic ester, halide, sulfide, heterocycles, and enolizable ketones. PMID:27487172

  17. Luminescent cyclometalated alkynylplatinum(II) complexes with a tridentate pyridine-based N-heterocyclic carbene ligand: synthesis, characterization, electrochemistry, photophysics, and computational studies.

    PubMed

    Leung, Sammual Yu-Lut; Lam, Elizabeth Suk-Hang; Lam, Wai Han; Wong, Keith Man-Chung; Wong, Wing-Tak; Yam, Vivian Wing-Wah

    2013-07-29

    A new class of luminescent alkynylplatinum(II) complexes with a tridentate pyridine-based N-heterocyclic carbene (2,6-bis(1-butylimidazol-2-ylidenyl)pyridine) ligand, [Pt(II)(C^N^C)(C≡CR)][PF6], and their chloroplatinum(II) precursor complex, [Pt(II)(C^N^C)Cl][PF6], have been synthesized and characterized. One of the alkynylplatinum(II) complexes has also been structurally characterized by X-ray crystallography. The electrochemistry, electronic absorption and luminescence properties of the complexes have been studied. Nanosecond transient absorption (TA) spectroscopy has also been performed to probe the nature of the excited state. The origin of the absorption and emission properties has been supported by computational studies. PMID:23788216

  18. Photocathodes for free electron lasers

    SciTech Connect

    Kong, S.H.; Kinross-Wright, J.; Nuguyen, D.C.; Sheffield, R.L.

    1994-09-01

    Many different photocathodes have been used as electron sources for FELs and other electron accelerator systems. In choosing one, a compromise between lifetime and quantum efficiency have been unavoidable. High quantum efficiency photocathodes such as CsK{sub 2}Sb, Cs{sub 3}Sb, and cesiated GaAs have short operational lifetimes and require an ultrahigh-vacuum environment. Long lifetime photocathodes such as LaB{sub 6}, Cu, and Y have relatively low quantum efficiencies. However, recently, cesium telluride was found to be an exception. Initial results from CERN and now at Los Alamos have shown that Cs{sub 2}Te is reasonably rugged with a high quantum efficiency below 270 nm. Further studies were carried out at Los Alamos in determining its performance as an electron source for the Los Alamos Advanced FEL. The Los Alamos Advanced FEL was successfully operated at 5-6 microns with a Cs{sub 2}Te photocathode driven by a frequency quadrupled Nd:YLF laser as the electron source. Cs{sub 2}Te photocathodes with quantum efficiencies of 12-18% at 254 mn were fabricated in an ultrahigh-vacuum chamber and transferred under high vacuum to the FEL. The authors estimated that the operational lifetime of Cs{sub 2}Te photocathodes to be at least 20 times that for K{sub 2}CsSb photocathodes. Furthermore, experiments in the fabrication chamber have shown that heating to 150-200{degrees}C photocathodes exposed for one hour at 2{times}10{sup {minus}4} torr of air was sufficient to revive the quantum efficiency from below 1% to about 10%. The electron beam for the FEL extracted from a cesium telluride target was also characterized. The emittance, response time, saturation level and dark current of cesium telluride photocathodes was determined to be sufficient for FEL applications.

  19. Groundwater Level Status Report for 2005 Los Alamos National Laboratory

    SciTech Connect

    S.P. Allen; R.J. Koch

    2006-05-15

    The status of groundwater level monitoring at Los Alamos National Laboratory (LANL) in 2005 is provided in this report. The Groundwater Level Monitoring Project was instituted in 2005 to provide a framework for the collection and processing of quality controlled groundwater level data. This report summarizes groundwater level data for 137 monitoring wells, including 41 regional aquifer wells, 22 intermediate wells, and 74 alluvial wells. Pressure transducers were installed in 118 monitoring wells for continuous monitoring of groundwater levels. Time-series hydrographs of groundwater level data are presented along with pertinent construction and location information for each well.

  20. Decommissioning of surplus facilities at Los Alamos National Laboratory

    SciTech Connect

    Stout, D.S.

    1995-03-01

    Decommissioning Buildings 3 and 4 South at Technical Area 21, Los Alamos National Laboratory, involves the decontamination, dismantlement, and demolition of two enriched-uranium processing buildings containing process equipment and ductwork holdup. The Laboratory has adopted two successful management strategies to implement this project: Rather than characterize an entire site, upfront, investigators use the ``observational approach,`` in which they collect only enough data to begin decommissioning activities and then determine appropriate procedures for further characterization as the work progresses. Project leaders augment work packages with task hazard analyses to fully define specific tasks and inform workers of hazards; all daily work activities are governed by specific work procedures and hazard analyses.

  1. End magnets for the NBS-Los Alamos racetrack microtron

    SciTech Connect

    Debenham, P.H.; Lindstrom, E.R.; Mohr, D.L.

    1983-01-01

    Two end magnets have been designed and constructed for the 185 MeV NBS-Los Alamos racetrack microtron. The field has been measured in the first magnet and is uniform over a 0.62 m/sup 2/ area to within +-2 x 10/sup -4/ at 1 T. The magnet meets all performance specifications. Field measurements are underway on the second magnet. In this paper, design and construction details which play an important role in magnetic performance are described, and the measured fields are compared with calculations.

  2. Mac configuration management at the Los Alamos National Laboratory

    SciTech Connect

    Marcus, Allan B

    2010-01-01

    The Los Alamos National Laboratory (LANL) had a need for central configuration management of non-Windows computers. LANL has three to five thousand Macs and an equal number of Linux based systems. The primary goal was to be able to inventory all non-windows systems and patch Mc OS X systems. LANL examined a number of commercial and open source solutions and ultimately selected Puppet. This paper will discuss why we chose Puppet, how we implemented it, and some lessons we learned along the way.

  3. Theoretical atomic physics code development at Los Alamos

    SciTech Connect

    Clark, R.E.H.; Abdallah, J. Jr.

    1989-01-01

    We have developed a set of computer codes for atomic physics calculations at Los Alamos. These codes can calculate a large variety of data with a minimum of effort on the part of the user. In particular, differential cross sections and electron impact coherence parameters can be readily obtained for arbitrary ions or atoms. Currently, the theory consists of non-relativistic Hartree-Fock structure calculations and non relativistic distorted wave approximation or first order many body theory collisional calculations. 12 refs., 2 figs., 5 tabs.

  4. Groundwater level status report for 2010, Los Alamos National Laboratory

    SciTech Connect

    Koch, Richard J.; Schmeer, Sarah

    2011-03-01

    The status of groundwater level monitoring at Los Alamos National Laboratory in 2010 is provided in this report. This report summarizes groundwater level data for 194 monitoring wells, including 63 regional aquifer wells (including 10 regional/intermediate wells), 34 intermediate wells, 97 alluvial wells, and 12 water supply wells. Pressure transducers were installed in 162 monitoring wells for continuous monitoring of groundwater levels. Time-series hydrographs of groundwater level data are presented along with pertinent construction and location information for each well. The report also summarizes the groundwater temperatures recorded in intermediate and regional aquifer monitoring wells and seasonal responses to snowmelt runoff observed in intermediate wells.

  5. The Los Alamos National Laboratory Nuclear Vision Project

    SciTech Connect

    Arthur, E.D.; Wagner, R.L. Jr.

    1996-09-01

    Los Alamos National Laboratory has initiated a project to examine possible futures associated with the global nuclear enterprise over the course of the next 50 years. All major components are included in this study--weapons, nonproliferation, nuclear power, nuclear materials, and institutional and public factors. To examine key issues, the project has been organized around three main activity areas--workshops, research and analyses, and development of linkages with other synergistic world efforts. This paper describes the effort--its current and planned activities--as well as provides discussion of project perspectives on nuclear weapons, nonproliferation, nuclear energy, and nuclear materials focus areas.

  6. Los Alamos safeguards program overview and NDA in safeguards

    SciTech Connect

    Keepin, G.R.

    1988-01-01

    Over the years the Los Alamos safeguards program has developed, tested, and implemented a broad range of passive and active nondestructive analysis (NDA) instruments (based on gamma and x-ray detection and neutron counting) that are now widely employed in safeguarding nuclear materials of all forms. Here very briefly, the major categories of gamma ray and neutron based NDA techniques, give some representative examples of NDA instruments currently in use, and cite a few notable instances of state-of-the-art NDA technique development. Historical aspects and a broad overview of the safeguards program are also presented.

  7. Tiger Team Assessment of the Los Alamos National Laboratory

    SciTech Connect

    Not Available

    1991-11-01

    The purpose of the safety and health assessment was to determine the effectiveness of representative safety and health programs at the Los Alamos National Laboratory (LANL). Within the safety and health programs at LANL, performance was assessed in the following technical areas: Organization and Administration, Quality Verification, Operations, Maintenance, Training and Certification, Auxiliary Systems, Emergency Preparedness, Technical Support, Packaging and Transportation, Nuclear Criticality Safety, Security/Safety Interface, Experimental Activities, Site/Facility Safety Review, Radiological Protection, Personnel Protection, Worker Safety and Health (OSHA) Compliance, Fire Protection, Aviation Safety, Explosives Safety, Natural Phenomena, and Medical Services.

  8. Los Alamos Science, Number 25 -- 1997: Celebrating the neutrino

    SciTech Connect

    Cooper, N.G.

    1997-12-31

    This issue is devoted to the neutrino and its remaining mysteries. It is divided into the following areas: (1) The Reines-Cowan experiment -- detecting the poltergeist; (2) The oscillating neutrino -- an introduction to neutrino masses and mixing; (3) A brief history of neutrino experiments at LAMPF; (4) A thousand eyes -- the story of LSND (Los Alamos neutrino oscillation experiment); (5) The evidence for oscillations; (6) The nature of neutrinos in muon decay and physics beyond the Standard Model; (7) Exorcising ghosts -- in pursuit of the missing solar neutrinos; (8) MSW -- a possible solution to the solar neutrino problem; (8) Neutrinos and supernovae; and (9) Dark matter and massive neutrinos.

  9. Recent developments in the Los Alamos radiation transport code system

    SciTech Connect

    Forster, R.A.; Parsons, K.

    1997-06-01

    A brief progress report on updates to the Los Alamos Radiation Transport Code System (LARTCS) for solving criticality and fixed-source problems is provided. LARTCS integrates the Diffusion Accelerated Neutral Transport (DANT) discrete ordinates codes with the Monte Carlo N-Particle (MCNP) code. The LARCTS code is being developed with a graphical user interface for problem setup and analysis. Progress in the DANT system for criticality applications include a two-dimensional module which can be linked to a mesh-generation code and a faster iteration scheme. Updates to MCNP Version 4A allow statistical checks of calculated Monte Carlo results.

  10. Upgrade of the Los Alamos Plutonium Facility control system

    SciTech Connect

    Pope, N.G.; Turner, W.J.; Brown, R.E.; Bibeau, R.A.; Davis, R.R.; Hogan, K.

    1996-05-01

    After 20 yrs service, the Los Alamos Plutonium Facility is undergoing an upgrade to its aging Facility Control System. The new system design includes a network of redundantly-paired programmable logic controllers that will interface with about 2200 field data points. The data communications network that has been designed includes a redundant, self-healing fiber optic data highway as well as a fiber optic ethernet. Commercially available human-machine interface software running on a UNIX-based system displays facility subsystem status operator X-terminals. Project design features, methods, costs, and schedule are discussed.

  11. Groundwater level status report for 2008, Los Alamos National Laboratory

    SciTech Connect

    Koch, Richard J.; Schmeer, Sarah

    2009-03-01

    The status of groundwater level monitoring at Los Alamos National Laboratory in 2008 is provided in this report. This report summarizes groundwater level data for 179 monitoring wells, including 45 regional aquifer wells, 28 intermediate wells, 8 regional/intermediate wells, 106 alluvial wells, and 12 water supply wells. Pressure transducers were installed in 166 monitoring wells for continuous monitoring of groundwater levels. Time-series hydrographs of groundwater level data are presented along with pertinent construction and location information for each well. The report also summarizes the groundwater temperatures recorded in intermediate and regional aquifer monitoring wells.

  12. Groundwater level status report for 2009, Los Alamos National Laboratory

    SciTech Connect

    Koch, Richard J.; Schmeer, Sarah

    2010-03-01

    The status of groundwater level monitoring at Los Alamos National Laboratory in 2009 is provided in this report. This report summarizes groundwater level data for 179 monitoring wells, including 55 regional aquifer wells (including 11 regional/intermediate wells), 26 intermediate wells, 98 alluvial wells, and 12 water supply wells. Pressure transducers were installed in 161 monitoring wells for continuous monitoring of groundwater levels. Time-series hydrographs of groundwater level data are presented along with pertinent construction and location information for each well. The report also summarizes the groundwater temperatures recorded in intermediate and regional aquifer monitoring wells.

  13. Water supply at Los Alamos during 1985: Progress report

    SciTech Connect

    Purtymun, W.D.; Becker, N.M.; Maes, M.N.

    1986-10-01

    Well field operations during 1985 were satisfactory with municipal and industrial supplies consisting of 1587 x 10/sup 6/ gal from wells in three well fields and 37 x 10/sup 6/ gal from the gallery in Water Canyon. About 2.8 x 10/sup 6/ gal of water from Guaje Reservoir and 0.9 x 10/sup 6/ gal from Los Alamos Reservoir were used for irrigation; thus the total water usage in 1985 was about 1628 x 10/sup 6/ gal. Primary and secondary chemical quality of water in the distribution system is in compliance with federal regulations.

  14. Single-interface Richtmyer-Meshkov turbulent mixing at the Los Alamos Vertical Shock Tube

    DOE PAGES

    Wilson, Brandon Merrill; Mejia Alvarez, Ricardo; Prestridge, Katherine Philomena

    2016-04-12

    We studied Mach number and initial conditions effects on Richtmyer–Meshkov (RM) mixing by the vertical shock tube (VST) at Los Alamos National Laboratory (LANL). At the VST, a perturbed stable light-to-heavy (air–SF6, A=0.64) interface is impulsively accelerated with a shock wave to induce RM mixing. We investigate changes to both large and small scales of mixing caused by changing the incident Mach number (Ma=1.3 and 1.45) and the three-dimensional (3D) perturbations on the interface. Simultaneous density (quantitative planar laser-induced fluorescence (PLIF)) and velocity (particle image velocimetry (PIV)) measurements are used to characterize preshock initial conditions and the dynamic shocked interface.more » Initial conditions and fluid properties are characterized before shock. Using two types of dynamic measurements, time series (N=5 realizations at ten locations) and statistics (N=100 realizations at a single location) of the density and velocity fields, we calculate several mixing quantities. Mix width, density-specific volume correlations, density–vorticity correlations, vorticity, enstrophy, strain, and instantaneous dissipation rate are examined at one downstream location. Results indicate that large-scale mixing, such as the mix width, is strongly dependent on Mach number, whereas small scales are strongly influenced by initial conditions. Lastly, the enstrophy and strain show focused mixing activity in the spike regions.« less

  15. Laser Technology.

    ERIC Educational Resources Information Center

    Gauger, Robert

    1993-01-01

    Describes lasers and indicates that learning about laser technology and creating laser technology activities are among the teacher enhancement processes needed to strengthen technology education. (JOW)

  16. Industrial application for the Los Alamos Materials Modeling Platform

    SciTech Connect

    Lesar, R.; Charbon, C.; Kothe, D.; Wu, D.; Reddy, A.

    1996-09-01

    This is the final report of a one-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). Casting and solidification of molten metals and metal alloys is a critical step in the production of high-quality metal stock and in the fabrication of finished parts. Control of the casting process can be the determining factor in both the quality and cost of the final metal product. Major problems with the quality of cast stock or finished parts can arise because of the difficulty of preventing variations in the alloy content, the generation of porosity or poor surface finish, and the loss of microstructure controlled strength and toughness resulting from the poor understanding and design of the mold filling and solidification processes. In this project, we sought to develop a new set of applications focused on adding the ability to accurately model solidification and grain growth to casting simulations. We implemented these applications within the Los Alamos Materials Modeling Platform, LAMMP, a graphical-based materials, and materials modeling environment being created at the Computational Testbed for Industry.

  17. The Los Alamos universe: Using multimedia to promote laboratory capabilities

    SciTech Connect

    Kindel, J.

    2000-03-01

    This project consists of a multimedia presentation that explains the technological capabilities of Los Alamos National Laboratory. It takes the form of a human-computer interface built around the metaphor of the universe. The project is intended promote Laboratory capabilities to a wide audience. Multimedia is simply a means of communicating information through a diverse set of tools--be they text, sound, animation, video, etc. Likewise, Los Alamos National Laboratory is a collection of diverse technologies, projects, and people. Given the ample material available at the Laboratory, there are tangible benefits to be gained by communicating across media. This paper consists of three parts. The first section provides some basic information about the Laboratory, its mission, and its needs. The second section introduces this multimedia presentation and the metaphor it is based on along with some basic concepts of color and user interaction used in the building of this project. The final section covers construction of the project, pitfalls, and future improvements.

  18. Solar pond research at the Los Alamos National Laboratory

    SciTech Connect

    Jones, G.F.; Meyer, K.A.; Hedstrom, J.C.; Grimmer, D.P.

    1984-01-01

    A description of solar pond research at Los Alamos National Laboratory is presented. The main issues in the theory of solar ponds are discussed. Among these are the interfacial-boundary-layer model, models for interface motion and pond performance, heat extraction, and ground heat loss. The core of the research effort at Los Alamos was the development of a one-dimensional computer program to accurately predict dynamic performance of a solar pond. The computer model and the experiments that were designed and performed to validate it are described. The experiments include two laboratory tanks wherein temperature, salinity, and flow visualization data were obtained and a 232 m/sup 2/ outdoor solar pond. Results from preliminary validation show good agreement between the pond's predicted dynamic behavior and that which actually occurred in the experiments. More validation using data from full-sized solar ponds is needed. A new correlation for the ratio of interfacial salt-flux to heat-flux is proposed which agrees well with our data. Recommendations for future research are given.

  19. Los Alamos Center for Computer Security formal computer security model

    SciTech Connect

    Dreicer, J.S.; Hunteman, W.J.; Markin, J.T.

    1989-01-01

    This paper provides a brief presentation of the formal computer security model currently being developed at the Los Alamos Department of Energy (DOE) Center for Computer Security (CCS). The need to test and verify DOE computer security policy implementation first motivated this effort. The actual analytical model was a result of the integration of current research in computer security and previous modeling and research experiences. The model is being developed to define a generic view of the computer and network security domains, to provide a theoretical basis for the design of a security model, and to address the limitations of present formal mathematical models for computer security. The fundamental objective of computer security is to prevent the unauthorized and unaccountable access to a system. The inherent vulnerabilities of computer systems result in various threats from unauthorized access. The foundation of the Los Alamos DOE CCS model is a series of functionally dependent probability equations, relations, and expressions. The model is undergoing continued discrimination and evolution. We expect to apply the model to the discipline of the Bell and LaPadula abstract sets of objects and subjects. 6 refs.

  20. Fuels Inventories in the Los Alamos National Laboratory Region: 1997

    SciTech Connect

    Balice, R.G.; Oswald, B.P.; Martin, C.

    1999-03-01

    Fifty-four sites were surveyed for fuel levels, vegetational structures, and topographic characteristics. Most of the surveyed sites were on Los Alamos National Laboratory property, however, some surveys were also conducted on U.S. Forest Service property. The overall vegetation of these sites ranged from pinon-juniper woodlands to ponderosa pine forests to mixed conifer forests, and the topographic positions included canyons, mesas, and mountains. The results of these surveys indicate that the understory fuels are the greatest in mixed conifer forests and that overstory fuels are greatest in both mixed conifer forests and ponderosa pine forests on mesas. The geographic distribution of these fuels would suggest a most credible wildfire scenario for the Los Alamos region. Three major fires have occurred since 1954 and these fires behaved in a manner that is consistent with this scenario. The most credible wildfire scenario was also supported by the results of BEHAVE modeling that used the fuels inventory data as inputs. Output from the BEHAVE model suggested that catastrophic wildfires would continue to occur during any season with sufficiently dry, windy weather.

  1. Cleanup at Los Alamos National Laboratory - the challenges - 9493

    SciTech Connect

    Stiger, Susan G; Hargis, Kenneth M; Graham, Michael J; Rael, George J

    2008-01-01

    This paper provides an overview of environmental cleanup at the Los Alamos National Laboratory (LANL) and some of the unique aspects and challenges. Cleanup of the 65-year old Department of Energy Laboratory is being conducted under a RCRA Consent Order with the State of New Mexico. This agreement is one of the most recent cleanup agreements signed in the DOE complex and was based on lessons learned at other DOE sites. A number of attributes create unique challenges for LANL cleanup -- the proximity to the community and pueblos, the site's topography and geology, and the nature of LANL's on-going missions. This overview paper will set the stage for other papers in this session, including papers that present: Plans to retrieve buried waste at Material Disposal Area B, across the street from oen of Los Alamos' commercial districts and the local newspaper; Progress to date and joint plans with WIPP for disposal of the remaining inventory of legacy transuranic waste; Reviews of both groundwater and surface water contamination and the factors complicating both characterization and remediation; Optimizing the disposal of low-level radioactive waste from ongoing LANL missions; A stakeholder environmental data transparency project (RACER), with full public access to all available information on contamination at LANL, and A description of the approach to waste processing cost recovery from the programs that generate hazardous and radioactive waste at LANL.

  2. An organizational survey of the Los Alamos Site

    SciTech Connect

    Shurberg, D.A.; Haber, S.B.

    1991-11-01

    An Organizational Survey (OS) was administered at the Los Alamos Site that queried employees on the subjects of organizational culture, various aspects of communications, employee commitment, work group cohesion, coordination of work, environmental, safety, and health concern, hazardous nature of work, safety and overall job satisfaction. The purpose of the OS is to measure in a quantitative and objective way the notion of ``culture;`` that is, the values, attitudes, and beliefs of the individuals working within the organization. In addition, through the OS, a broad sample of individuals can be reached that would probably not be interviewed or observed during the course of a typical assessment. The OS also provides a descriptive profile of the organization at one point in time that can then be compared to a profile taken at a different point in time to assess changes in the culture of the organization. While comparisons among groups are made, it is not the purpose of this report to make evaluative statements of which profile may be positive or negative. However, using the data presented in this report in conjunction with other evaluative activities, may provide useful insight into the organization. The OS administration at the Los Alamos Site was the ninth to occur at a Department of Energy (DOE) facility. All data from the OS is presented in group summaries, by organization, department or directorate within organization, supervisory level both overall and within organization, and staff classification within organization. Statistically significant differences between groups are identified and discussed. 9 refs., 94 figs., 11 tabs.

  3. An organizational survey of the Los Alamos Site

    SciTech Connect

    Shurberg, D.A.; Haber, S.B.

    1991-11-01

    An Organizational Survey (OS) was administered at the Los Alamos Site that queried employees on the subjects of organizational culture, various aspects of communications, employee commitment, work group cohesion, coordination of work, environmental, safety, and health concern, hazardous nature of work, safety and overall job satisfaction. The purpose of the OS is to measure in a quantitative and objective way the notion of culture;'' that is, the values, attitudes, and beliefs of the individuals working within the organization. In addition, through the OS, a broad sample of individuals can be reached that would probably not be interviewed or observed during the course of a typical assessment. The OS also provides a descriptive profile of the organization at one point in time that can then be compared to a profile taken at a different point in time to assess changes in the culture of the organization. While comparisons among groups are made, it is not the purpose of this report to make evaluative statements of which profile may be positive or negative. However, using the data presented in this report in conjunction with other evaluative activities, may provide useful insight into the organization. The OS administration at the Los Alamos Site was the ninth to occur at a Department of Energy (DOE) facility. All data from the OS is presented in group summaries, by organization, department or directorate within organization, supervisory level both overall and within organization, and staff classification within organization. Statistically significant differences between groups are identified and discussed. 9 refs., 94 figs., 11 tabs.

  4. Exploding metallic foil fuse modeling at Los Alamos

    SciTech Connect

    Lindemuth, I.R.; Reinovsky, R.E.; Goforth, J.H.

    1989-01-01

    A ''first-principles'' computational model of exploding metallic foil behavior has been developed at Los Alamos. The model couples zero-dimensional magnetohydrodynamics with ohmic heating and electrical circuit equations and uses the Los Alamos SESAME atomic data base computer library to determine the foil material's temperature- and density-dependent pressure, specific energy, and electrical conductivity. The model encompasses many previously successful empirical models and offers plausible physical explanations of phenomena not treated by the empirical models. In addition to addressing the electrical circuit performance of an exploding foil, the model provides information on the temporal evolution of the foil material's density, temperature, pressure, electrical conductivity, and expansion and translational velocities. In this paper, we report the physical insight gained by computational studies of two opening switch concepts being developed for application in an FCG-driven 1-MJ-class imploding plasma z-pinch experiment. The first concept considered is a ''conventional'' electrically exploded fuse, which has been demonstrated to operate at 16 MA driven by the 15-MJ-class FCG to be used in the 1 MJ implosion experiment. The second concept considered is a Type 2 explosively formed fuse (EFF), which has been demonstrated to operate at the 8 MA level by a 1-MJ-class FCG.

  5. Exploding metallic foil fuse modeling at Los Alamos

    NASA Astrophysics Data System (ADS)

    Lindemuth, Irvin R.; Reinovsky, Robert E.; Goforth, James H.

    A first-principles computational model of exploding metallic foil behavior was developed at Los Alamos. The model couples zero-dimensional magnetohydrodynamics with ohmic heating and electrical circuit equations and uses the Los Alamos SESAME atomic data base computer library to determine the foil material's temperature- and density-dependent pressure, specific energy, and electrical conductivity. The model encompasses many previously successful empirical models and offers plausible physical explanations of phenomena not treated by the empirical models. In addition to addressing the electrical circuit performance of an exploding foil, the model provides information on the temporal evolution of the foil material's density, temperature, pressure, electrical conductivity, and expansion and translational velocities. The physical insight gained by computational studies of two opening switch concepts being developed for application in an FCG-driven 1-MJ-class imploding plasma z-pinch experiment are reported. The first concept considered is a conventional electrically exploded fuse, which was demonstrated to operate at 16 MA driven by the 15-MJ-class FCG to be used in the 1 MJ implosion experiment. The second concept considered is a Type 2 explosively formed fuse (EFF), which was demonstrated to operate at the 8 MA level by a 1-MJ-class FCG.

  6. Water supply at Los Alamos during 1987: Progress report

    SciTech Connect

    Purtymun, W.D.; Stoker, A.K.; Maes, M.N.

    1989-01-01

    Municipal and industrial water supply during 1987 was 1594 /times/ 10W gal from wells in three fields and 34 /times/ 10W gal from the spring gallery in Water Canyon. About 2.8 /times/ 10W gal of nonpotable water from the Guaje Reservoir and 3.2 /times/ 10W gal from the Los Alamos Reservoir were used for irrigation; thus, the total water usage in 1987 was about 1634 /times/ 10W gal. Water supply was satisfactory in that the production met demand and water quality in the distribution system was in compliance with state and federal regulations. However, in 1987 two wells were lost because of deterioration of the casing and screen. In spite of rehabilitation attempts to maintain the yield, production from the older wells continued to decline. A comprehensive evaluation of the wells and well fields made in late 1987 concluded that replacement wells and new wells were needed soon to ensure a reliable water supply for the Laboratory and the county of Los Alamos. 25 refs., 6 figs., 7 tabs.

  7. Seismic vulnerability study Los Alamos Meson Physics Facility (LAMPF)

    SciTech Connect

    Salmon, M.; Goen, L.K.

    1995-12-01

    The Los Alamos Meson Physics Facility (LAMPF), located at TA-53 of Los Alamos National Laboratory (LANL), features an 800 MeV proton accelerator used for nuclear physics and materials science research. As part of the implementation of DOE Order 5480.25 and in preparation for DOE Order 5480.28, a seismic vulnerability study of the structures, systems, and components (SSCs) supporting the beam line from the accelerator building through to the ends of die various beam stops at LAMPF has been performed. The study was accomplished using the SQUG GIP methodology to assess the capability of the various SSCs to resist an evaluation basis earthquake. The evaluation basis earthquake was selected from site specific seismic hazard studies. The goals for the study were as follows: (1) identify SSCs which are vulnerable to seismic loads; and (2) ensure that those SSCs screened during die evaluation met the performance goals required for DOE Order 5480.28. The first goal was obtained by applying the SQUG GIP methodology to those SSCS represented in the experience data base. For those SSCs not represented in the data base, information was gathered and a significant amount of engineering judgment applied to determine whether to screen the SSC or to classify it as an outlier. To assure the performance goals required by DOE Order 5480.28 are met, modifications to the SQUG GIP methodology proposed by Salmon and Kennedy were used. The results of this study ire presented in this paper.

  8. Performance programming with the Los Alamos macro accelerator

    NASA Astrophysics Data System (ADS)

    Cort, G.

    The CCC macro facility, as extended by Version 2.0 of Softool's Change and Configuration Control Environment, offers many new and powerful features. Among these are a vastly extended suite of commands, error trapping, and structured constructs. In concert with previously existing Version 1.x features (notably the very powerful symbol substitution and parameter passage facilities), these features combine to transform the macro facility from a simple command language into an extremely flexible programming language which is suitable for developing very large and complex applications. This paper presents the results of a performance analysis of the CCC macro facility conducted at the Los Alamos National Laboratory Weapons Neutron Research Facility. The goal of this work was to identify and evaluate major factors that can contribute to the degradation of performance of the CCC macro facility, and to develop strategies for countering their effects. In particular, we report on the Los Alamos Macro Accelerator, which can produce dramatic increases in execution speed for many applications.

  9. Investigation of excess thyroid cancer incidence in Los Alamos County

    SciTech Connect

    Athas, W.F.

    1996-04-01

    Los Alamos County (LAC) is home to the Los Alamos National Laboratory, a U.S. Department of Energy (DOE) nuclear research and design facility. In 1991, the DOE funded the New Mexico Department of Health to conduct a review of cancer incidence rates in LAC in response to citizen concerns over what was perceived as a large excess of brain tumors and a possible relationship to radiological contaminants from the Laboratory. The study found no unusual or alarming pattern in the incidence of brain cancer, however, a fourfold excess of thyroid cancer was observed during the late-1980`s. A rapid review of the medical records for cases diagnosed between 1986 and 1990 failed to demonstrate that the thyroid cancer excess had resulted from enhanced detection. Surveillance activities subsequently undertaken to monitor the trend revealed that the excess persisted into 1993. A feasibility assessment of further studies was made, and ultimately, an investigation was conducted to document the epidemiologic characteristics of the excess in detail and to explore possible causes through a case-series records review. Findings from the investigation are the subject of this report.

  10. Mixed low-level waste minimization at Los Alamos

    SciTech Connect

    Starke, T.P.

    1998-12-01

    During the first six months of University of California 98 Fiscal Year (July--December) Los Alamos National Laboratory has achieved a 57% reduction in mixed low-level waste generation. This has been accomplished through a systems approach that identified and minimized the largest MLLW streams. These included surface-contaminated lead, lead-lined gloveboxes, printed circuit boards, and activated fluorescent lamps. Specific waste minimization projects have been initiated to address these streams. In addition, several chemical processing equipment upgrades are being implemented. Use of contaminated lead is planned for several high energy proton beam stop applications and stainless steel encapsulated lead is being evaluated for other radiological control area applications. INEEL is assisting Los Alamos with a complete systems analysis of analytical chemistry derived mixed wastes at the CMR building and with a minimum life-cycle cost standard glovebox design. Funding for waste minimization upgrades has come from several sources: generator programs, waste management, the generator set-aside program, and Defense Programs funding to INEEL.

  11. School Finance in a Federal City: Los Alamos as a Case Study.

    ERIC Educational Resources Information Center

    Smith, Duane W.

    The Los Alamos schools obtain support from a combination of local, state, and Department of Energy funds mandated by the Atomic Energy Commission Community Act. Each year the Los Alamos schools prepare three budgets, and during any week the schools may work directly with all three levels of government concerning funding. In 1974 the state of New…

  12. Recollections of a very junior physicist at Los Alamos, 1944-1946

    NASA Astrophysics Data System (ADS)

    French, Anthony P.

    2008-04-01

    The author came to Los Alamos as a member of the British Mission after two years of making fission cross section measurements at the Cavendish Laboratory. He worked in a group headed by Egon Bretscher in Enrico Fermi's F Division. The talk presents his personal memories and experiences at Los Alamos as compared to his life and work in wartime Britain.

  13. Final Report: Cooling Molecules with Laser Light

    SciTech Connect

    Di Rosa, Michael D.

    2012-05-08

    Certain diatomic molecules are disposed to laser cooling in the way successfully applied to certain atoms and that ushered in a revolution in ultracold atomic physics, an identification first made at Los Alamos and which took root during this program. Despite their manipulation into numerous achievements, atoms are nonetheless mundane denizens of the quantum world. Molecules, on the other hand, with their internal degrees of freedom and rich dynamical interplay, provide considerably more complexity. Two main goals of this program were to demonstrate the feasibility of laser-cooling molecules to the same temperatures as laser-cooled atoms and introduce a means for collecting laser-cooled molecules into dense ensembles, a foundational start of studies and applications of ultracold matter without equivalence in atomic systems.

  14. Understanding lasers

    SciTech Connect

    Gibilisco, S.

    1989-01-01

    Covering all different types of laser applications-Gibilisco offers an overview of this fascinating phenomenon of light. Here he describes what lasers are and how they work and examines in detail the different kinds of lasers in use today. Topics of particular interest include: the way lasers work; the different kinds of lasers; infrared, ultraviolet and x-ray lasers; use of lasers in industry and manufacturing; use of lasers for long-distance communications; fiberoptic communications; the way laser shows work; the reality of Star Wars; lasers in surgical and medical applications; and holography and the future of laser technology.

  15. Synthesis, Characterization and Biological Properties of Tridentate NNO, NNS and NNN Donor Thiazole-Derived Furanyl, Thiophenyl and Pyrrolyl Schiff Bases and Their Co(II), Cu(II), Ni(II) and Zn(II) Metal Chelates

    PubMed Central

    Kausar, Samina

    2000-01-01

    2-Aminothiazole undergoes condensation reactions with furane-, thiophene- and pyrrole-2-carboxylaldehyde to give tridentate NNO, NNS and NNN Schiff bases respectively. These tridentate Schiff bases formed complexes of the type [M (L)2]X2 where [M=Co(II), Cu(II), Ni(II) or Zn(II), L=N-(2-furanylmethylene)-2-aminothiazole (L1), N-(2-thiophenylmethylene)-2-aminothiazole (L2, N-(2-pyrrolylmethylene)-2-aminothiazole (L3) and X=Cl. The structures of these Schiff bases and of their complexes have been determined on the basis of their physical, analytical and spectral data. The screening results of these compounds indicated them to possess excellent antibacterial activity against tested pathogenic bacterial organisms e.g., Escherichia coli, Staphylococcus aureous and Pseudomonas aeruginosa. However, in comparison, their metal chelates have been shown to possess more antibacterial activity than the uncomplexed Schiff bases. PMID:18475919

  16. Synthesis, Characterization and Biological Properties of Tridentate NNO, NNS and NNN Donor Thiazole-Derived Furanyl, Thiophenyl and Pyrrolyl Schiff Bases and Their Co(II), Cu(II), Ni(II) and Zn(II) Metal Chelates.

    PubMed

    Chohan, Z H; Kausar, S

    2000-01-01

    2-Aminothiazole undergoes condensation reactions with furane-, thiophene- and pyrrole-2-carboxylaldehyde to give tridentate NNO, NNS and NNN Schiff bases respectively. These tridentate Schiff bases formed complexes of the type [M (L)(2)]X(2) where [M=Co(II), Cu(II), Ni(II) or Zn(II), L=N-(2-furanylmethylene)-2-aminothiazole (L(1)), N-(2-thiophenylmethylene)-2-aminothiazole (L(2), N-(2-pyrrolylmethylene)-2-aminothiazole (L(3)) and X=Cl. The structures of these Schiff bases and of their complexes have been determined on the basis of their physical, analytical and spectral data. The screening results of these compounds indicated them to possess excellent antibacterial activity against tested pathogenic bacterial organisms e.g., Escherichia coli, Staphylococcus aureous and Pseudomonas aeruginosa. However, in comparison, their metal chelates have been shown to possess more antibacterial activity than the uncomplexed Schiff bases.

  17. Los Alamos Plutonium Facility implementation support project report

    SciTech Connect

    Thomas, C.C. Jr.; Ford, W.; Hsue, S.T.; Marshall, R.S.

    1982-05-01

    During FY 1981 the TA-55 Implementation Support Project provided assistance to the Los Alamos Plutonium Facility in materials accounting and control, including testing and evaluation of a solution mass measurement system, development and testing of a low-level plutonium assay system, holdup measurements, instrument design, and advice and consultation following the observation of semiannual inventories. This report describes the program envisioned for FY 1982, including demonstration of the solution mass measurement system and the associated calibration system, extension of the low-level plutonium assay system to solutions with americium/plutonium ratios of 10: to 20:1, and development and demonstration of a method to calibrate and routinely verify the plutonium oxalate assay instrument performance. The FY 1982 program is subject to changes based on TA-55 reevaluation of facility needs.

  18. Operational status of the Los Alamos neutron science center (LANSCE)

    SciTech Connect

    Jones, Kevin W; Erickson, John L; Schoenberg, Kurt F

    2010-01-01

    The Los Alamos Neutron Science Center (LANSCE) accelerator and beam delivery complex generates the proton beams that serve three neutron production sources; the thermal and cold source for the Manuel Lujan Jr. Neutron Scattering Center, the Weapons Neutron Research (WNR) high-energy neutron source, and a pulsed Ultra-Cold Neutron Source. These three sources are the foundation of strong and productive multi-disciplinary research programs that serve a diverse and robust user community. The facility also provides multiplexed beams for the production of medical radioisotopes and proton radiography of dynamic events. The recent operating history of these sources will be reviewed and plans for performance improvement will be discussed, together with the underlying drivers for the proposed LANSCE Refurbishment project. The details of this latter project are presented in a separate contribution.

  19. Los Alamos Explosives Performance Key to Stockpile Stewardship

    SciTech Connect

    Dattelbaum, Dana

    2014-11-03

    As the U.S. Nuclear Deterrent ages, one essential factor in making sure that the weapons will continue to perform as designed is understanding the fundamental properties of the high explosives that are part of a nuclear weapons system. As nuclear weapons go through life extension programs, some changes may be advantageous, particularly through the addition of what are known as "insensitive" high explosives that are much less likely to accidentally detonate than the already very safe "conventional" high explosives that are used in most weapons. At Los Alamos National Laboratory explosives research includes a wide variety of both large- and small-scale experiments that include small contained detonations, gas and powder gun firings, larger outdoor detonations, large-scale hydrodynamic tests, and at the Nevada Nuclear Security Site, underground sub-critical experiments.

  20. Neutron Capture Experiments Using the DANCE Array at Los Alamos

    NASA Astrophysics Data System (ADS)

    Dashdorj, D.; Mitchell, G. E.; Baramsai, B.; Chyzh, A.; Walker, C.; Agvaanluvsan, U.; Becker, J. A.; Parker, W.; Sleaford, B.; Wu, C. Y.; Bredeweg, T. A.; Couture, A.; Haight, R. C.; Jandel, M.; Rundberg, R. S.; Ullmann, J. L.; Vieira, D. J.; Wouters, J. M.; Krtička, M.; Bečvář, F.

    2009-03-01

    The Detector for Advanced Neutron Capture Experiments (DANCE) is designed for neutron capture measurements on very small and/or radioactive targets. The DANCE array of 160 BaF2 scintillation detectors is located at the Lujan Center at the Los Alamos Neutron Science Center (LANSCE). Accurate measurements of neutron capture data are important for many current applications as well as for basic understanding of neutron capture. The gamma rays following neutron capture reactions have been studied by the time-of-flight technique using the DANCE array. The high granularity of the array allows measurements of the gamma-ray multiplicity. The gamma-ray multiplicities and energy spectra for different multiplicities can be measured and analyzed for spin and parity determination of the resolved resonances.

  1. Tiger Team Assessment of the Los Alamos National Laboratory

    SciTech Connect

    Not Available

    1991-11-01

    The Management Subteam conducted a management and organization assessment of environment, safety, and health (ES H) activities performed by the Los Alamos National Laboratory (LANL) and onsite contractor personnel. The objectives of the assessment were to (1) evaluate the effectiveness of management systems and practices in terms of ensuring environmental compliance and the safety and health of workers and the general public, (2) identify key findings, and (3) identify root causes for all ES H findings and concerns. The scope of the assessment included examinations of the following from an ES H perspective: (1) strategic and program planning; (2) organizational structure and management configuration; (3) human resource management, including training and staffing; (4) management systems, including performance monitoring and assessment; (5) conduct of operations; (6) public and institutional interactions; and (7) corporate'' parent support.

  2. Los Alamos Discovers Super Efficient Solar Using Perovskite Crystals

    SciTech Connect

    Mohite, Aditya; Nie, Wanyi

    2015-01-29

    State-of-the-art photovoltaics using high-purity, large-area, wafer-scale single-crystalline semiconductors grown by sophisticated, high temperature crystal-growth processes offer promising routes for developing low-cost, solar-based clean global energy solutions for the future. Solar cells composed of the recently discovered material organic-inorganic perovskites offer the efficiency of silicon, yet suffer from a variety of deficiencies limiting the commercial viability of perovskite photovoltaic technology. In research to appear in Science, Los Alamos National Laboratory researchers reveal a new solution-based hot-casting technique that eliminates these limitations, one that allows for the growth of high-quality, large-area, millimeter-scale perovskite crystals and demonstrates that highly efficient and reproducible solar cells with reduced trap assisted recombination can be realized.

  3. The legacy and future of CFD at Los Alamos

    SciTech Connect

    Johnson, N.L.

    1996-06-01

    The early history is presented of the prolific development of CFD methods in the Fluid Dynamics Group (T-3) at Los Alamos National Laboratory in the years from 1958 to the late 1960`s. Many of the currently used numerical methods--PIC, MAC, vorticity-stream-function, ICE, ALE methods and the {kappa}-{var_epsilon} method for turbulence--originated during this time. The rest of the paper summarizes the current research in T-3 for CFD, turbulence and solids modeling. The research areas include reactive flows, multimaterial flows, multiphase flows and flows with spatial discontinuities. Also summarized are modern particle methods and techniques developed for large scale computing on massively parallel computing platforms and distributed processors.

  4. Environmental surveillance at Los Alamos during 1991. Environmental protection group

    SciTech Connect

    Dewart, J.; Kohen, K.L.

    1993-08-01

    This report describes the environmental surveillance program conducted by Los Alamos National Laboratory during 1991. Routine monitoring for radiation and for radioactive and chemical materials is conducted on the Laboratory site as well as in the surrounding region. Monitoring results are used to determine compliance with appropriate standards and to permit early identification of potentially undesirable trends. Results and interpretation of data for 1991 cover external penetrating radiation; quantities of airborne emissions and effluents; concentrations of chemicals and radionuclides in ambient air, surface waters and groundwaters, municipal water supply, soils and sediments, and foodstuffs; and environmental compliance. Comparisons with appropriate standards, regulations, and background levels provide the basis for concluding that environmental effects from Laboratory operations are small and do not pose a threat to the public, Laboratory employees, or the environment.

  5. Root lengths of plants on Los Alamos National Laboratory lands

    SciTech Connect

    Tierney, G.D.; Foxx, T.S.

    1987-01-01

    Maximum root lengths of 22 plant species occurring on Los Alamos National Laboratory lands were measured. An average of two longest roots from each species were dug up and their lengths, typical shapes, and qualitative morphologics were noted along with the overstory dimensions of the plant individual with which the roots were associated. Maximum root lengths were compared with overstory (height times width) dimensions. Among the life forms studied, the shrubs tend to show the longest roots in relation to overstory size. Forbs show the shortest roots in relation to overstory size. Measurements of tree roots suggest only that immature trees on the Pajarito Plateau may have root-length to overstory-size ratios near one. 30 refs., 14 figs., 2 tabs.

  6. Misuse and intrusion detection at Los Alamos National Laboratory

    SciTech Connect

    Jackson, K.A.; Neuman, M.C.; Simmonds, D.D.; Stallings, C.A.; Thompson, J.L.; Christoph, G.G.

    1995-04-01

    An effective method for detecting computer misuse is the automatic auditing and analysis of on-line user activity. This activity is reflected in system audit records, in system vulnerability postures, and in other evidence found through active system testing. Since 1989 we have implemented a misuse and intrusion detection system at Los Alamos. This is the Network Anomaly Detection and Intrusion Reporter, or NADIR. NADIR currently audits a Kerberos distributed authentication system, file activity on a mass, storage system, and four Cray supercomputers that run the UNICOS operating system. NADIR summarizes user activity and system configuration in statistical profiles. It compares these profiles to expert rules that define security policy and improper or suspicious behavior. It reports suspicious behavior to security auditors and provides tools to aid in follow-up investigations, As NADIR is constantly evolving, this paper reports its development to date.

  7. Los Alamos Neutron Science Center (LANSCE) Nuclear Science Facilities

    SciTech Connect

    Nelson, Ronald Owen; Wender, Steve

    2015-06-19

    The Los Alamos Neutron Science Center (LANSCE) facilities for Nuclear Science consist of a high-energy "white" neutron source (Target 4) with 6 flight paths, three low-energy nuclear science flight paths at the Lujan Center, and a proton reaction area. The neutron beams produced at the Target 4 complement those produced at the Lujan Center because they are of much higher energy and have shorter pulse widths. The neutron sources are driven by the 800-MeV proton beam of the LANSCE linear accelerator. With these facilities, LANSCE is able to deliver neutrons with energies ranging from a milli-electron volt to several hundreds of MeV, as well as proton beams with a wide range of energy, time and intensity characteristics. The facilities, instruments and research programs are described briefly.

  8. The Los ALamos Neutron Science Center Hydrogen Moderator System

    NASA Astrophysics Data System (ADS)

    Jarmer, J. J.; Knudson, J. N.

    2006-04-01

    At the Los Alamos Neutron Science Center (LANSCE), spallation neutrons are produced by an 800-MeV proton beam interacting with tungsten targets. Gun-barrel-type penetrations through the heavy concrete and steel shielding that surround the targets collimate neutrons to form neutron beams used for scattering experiments. Two liquid hydrogen moderators of one-liter volume each are positioned adjacent to the neutron-production targets. Some of the neutrons that pass through a moderator interact with or scatter from protons in the hydrogen. The neutron-proton interaction reduces the energy or moderates neutrons to lower energies. Lower energy "moderated" neutrons are the most useful for some neutron scattering experiments. We provide a description of the LANSCE hydrogen-moderator system and its cryogenic performance with proton beams of up to 125 micro-amp average current.

  9. Los Alamos Explosives Performance Key to Stockpile Stewardship

    ScienceCinema

    Dattelbaum, Dana

    2016-07-12

    As the U.S. Nuclear Deterrent ages, one essential factor in making sure that the weapons will continue to perform as designed is understanding the fundamental properties of the high explosives that are part of a nuclear weapons system. As nuclear weapons go through life extension programs, some changes may be advantageous, particularly through the addition of what are known as "insensitive" high explosives that are much less likely to accidentally detonate than the already very safe "conventional" high explosives that are used in most weapons. At Los Alamos National Laboratory explosives research includes a wide variety of both large- and small-scale experiments that include small contained detonations, gas and powder gun firings, larger outdoor detonations, large-scale hydrodynamic tests, and at the Nevada Nuclear Security Site, underground sub-critical experiments.

  10. Neutron Capture Experiments Using the DANCE Array at Los Alamos

    SciTech Connect

    Dashdorj, D.; Mitchell, G. E.; Baramsai, B.; Chyzh, A.; Walker, C.; Agvaanluvsan, U.; Becker, J. A.; Parker, W.; Sleaford, B.; Wu, C. Y.; Bredeweg, T. A.; Couture, A.; Haight, R. C.; Jandel, M.; Rundberg, R. S.; Ullmann, J. L.; Vieira, D. J.; Wouters, J. M.; Krticka, M.; Becvar, F.

    2009-03-31

    The Detector for Advanced Neutron Capture Experiments (DANCE) is designed for neutron capture measurements on very small and/or radioactive targets. The DANCE array of 160 BaF{sub 2} scintillation detectors is located at the Lujan Center at the Los Alamos Neutron Science Center (LANSCE). Accurate measurements of neutron capture data are important for many current applications as well as for basic understanding of neutron capture. The gamma rays following neutron capture reactions have been studied by the time-of-flight technique using the DANCE array. The high granularity of the array allows measurements of the gamma-ray multiplicity. The gamma-ray multiplicities and energy spectra for different multiplicities can be measured and analyzed for spin and parity determination of the resolved resonances.

  11. Smoking patterns among Los Alamos National Laboratory employees

    SciTech Connect

    Mahoney, M.C.; Wilkinson, G.S.

    1987-06-01

    Smoking patterns among 5507 employees at Los Alamos National Laboratory were investigated for those who underwent physical examinations by occupational physicians from 1978 to 1983. More male than female employees smoked, although differences in smoking rates between the sexes were not as large as differences observed for national smoking rates. Employees over 40 were more likely to smoke than younger employees, males consumed more cigarettes than did females, and Anglo employees smoked more cigarettes than did Hispanic employees. Highly educated employees smoked less than did less-educated workers, and staff members exhibited the lowest rates of smoking. Smoking cessation programs for Laboratory employees should be directed toward those subpopulations with the highest rates of smoking. 31 refs., 8 figs., 1 tab.

  12. Plans for an Ultra Cold Neutron source at Los Alamos

    SciTech Connect

    Seestrom, S.J.; Bowles, T.J.; Hill, R.; Greene, G.L.

    1996-10-01

    Ultra Cold Neutrons (UCN) can be produced at spallation sources using a variety of techniques. To date the technique used has been to Bragg scatter and Doppler shift cold neutrons into UCN from a moving crystal. This is particularly applicable to short-pulse spallation sources. We are presently constructing a UCN source at LANSCE using this method. In addition, large gains in UCN density should be possible using cryogenic UCN sources. Research is under way at Gatchina to demonstrate technical feasibility of a frozen deuterium source. If successful, a source of this type could be implemented at future spallation source, such as the long pulse source being planned at Los Alamos, with a UCN density that may be two orders of magnitude higher than that presently available at reactors.

  13. Los Alamos National Laboratory Develops ''Quick to WIPP'' Strategy

    SciTech Connect

    Jones, R.; Allen, G.; Kosiewicz, S.; Martin, B,; LANL; Nunz, J.; Biedscheid, J.; Sellmer, T.; Willis, J.; Orban, J.; Liekhus, K.; Djordjevic, S.

    2003-02-25

    The Cerro Grande forest fire in May of 2000 and the terrorist events of September 11, 2001 precipitated concerns of the vulnerability of legacy contact-handled (CH), high-wattage transuranic (TRU) waste stored at Los Alamos National Laboratory (LANL). An analysis of the 9,100 cubic meters of stored CH-TRU waste revealed that 400 cubic meters or 4.5% of the inventory represented 61% of the risk. The analysis further showed that this 400 cubic meters was contained in only 2,000 drums. These facts and the question ''How can the disposition of this waste to the Waste Isolation Pilot Plant (WIPP) be accelerated?'' formed the genesis of LANL's Quick to WIPP initiative.

  14. Los Alamos National Laboratory support to IAEA environmental safeguards

    SciTech Connect

    Steiner, Robert E; Dry, Don E; Roensch, Fred R; Kinman, Will S; Roach, Jeff L; La Mont, Stephen P

    2010-12-01

    The nuclear and radiochemistry group provides sample preparation and analysis support to the International Atomic Energy Agency (IAEA) Network of Analytical Laboratories (NWAL). These analyses include both non-destructive (alpha and gamma-ray spectrometry) and destructive (thermal ionization mass spectrometry and inductively coupled plasma mass spectrometry) methods. On a bi-annual basis the NWAL laboratories are invited to meet to discuss program evolution and issues. During this meeting each participating laboratory summarizes their efforts over the previous two years. This presentation will present Los Alamos National Laboratories efforts in support of this program. Data showing results from sample and blank analysis will be presented along with capability enhancement and issues that arose over the previous two years.

  15. Los Alamos National Laboratory capability reviews - FY 2011 status

    SciTech Connect

    Springer, Everett P

    2011-01-12

    Capability reviews are the Los Alamos National Laboratory approach to assess the quality of its science, technology, and engineering (STE), and its integration across the Laboratory. There are seven capability reviews in FY 2011 reviews. The Weapons Science and Engineering review will be replaced by the National Nuclear Security Administration's Predictive Science Panel for 2011 . Beginning in 2011, third-year LORD projects will be reviewed by capability review committees rather than the first-year LORD projects that have been performed for the last three years. This change addresses concerns from committees about reviewing a project before it had made any substantive progress. The current schedule, and chairs for the 2011 capability reviews is presented. The three-year cycle (2011-2013) for capability reviews are presented for planning purposes.

  16. Decommissioning the UHTREX Reactor Facility at Los Alamos, New Mexico

    SciTech Connect

    Salazar, M.; Elder, J.

    1992-08-01

    The Ultra-High Temperature Reactor Experiment (UHTREX) facility was constructed in the late 1960s to advance high-temperature and gas-cooled reactor technology. The 3-MW reactor was graphite moderated and helium cooled and used 93% enriched uranium as its fuel. The reactor was run for approximately one year and was shut down in February 1970. The decommissioning of the facility involved removing the reactor and its associated components. This document details planning for the decommissioning operations which included characterizing the facility, estimating the costs of decommissioning, preparing environmental documentation, establishing a system to track costs and work progress, and preplanning to correct health and safety concerns in the facility. Work to decommission the facility began in 1988 and was completed in September 1990 at a cost of $2.9 million. The facility was released to Department of Energy for other uses in its Los Alamos program.

  17. Environmental surveillance and compliance at Los Alamos during 1996

    SciTech Connect

    1997-09-01

    This report presents environmental data that characterize environmental performance and addresses compliance with environmental standards and requirements at Los Alamos National Laboratory (LANL or the Laboratory) during 1996. The Laboratory routinely monitors for radiation and for radioactive nonradioactive materials at Laboratory sites as well as in the surrounding region. LANL uses the monitoring results to determine compliance with appropriate standards and to identify potentially undesirable trends. Data were collected in 1996 to assess external penetrating radiation; quantities of airborne emissions; and concentrations of chemicals and radionuclides in ambient air, surface waters and groundwaters, the municipal water supply, soils and sediments, and foodstuffs. Using comparisons with standards and regulations, this report concludes that environmental effects from Laboratory operations are small and do not pose a demonstrable threat to the public, Laboratory employees, or the environment. Laboratory operations were in compliance with all major environmental regulations.

  18. Common ground: An environmental ethic for Los Alamos National Laboratory

    SciTech Connect

    Menlove, F.L.

    1991-01-01

    Three predominant philosophies have characterized American business ethical thinking over the past several decades. The first phase is the ethics of self-interest'' which argues that maximizing self-interest coincidentally maximizes the common good. The second phase is legality ethics.'' Proponents argue that what is important is knowing the rules and following them scrupulously. The third phase might be called stake-holder ethics.'' A central tenant is that everyone affected by a decision has a moral hold on the decision maker. This paper will discuss one recent initiative of the Los Alamos National Laboratory to move beyond rules and regulations toward an environmental ethic that integrates the values of stakeholder ethics'' into the Laboratory's historical culture and value systems. These Common Ground Principles are described. 11 refs.

  19. Los Alamos National Laboratory TRU waste sampling projects

    SciTech Connect

    Yeamans, D.; Rogers, P.; Mroz, E.

    1997-02-01

    The Los Alamos National Laboratory (LANL) has begun characterizing transuranic (TRU) waste in order to comply with New Mexico regulations, and to prepare the waste for shipment and disposal at the Waste Isolation Pilot Plant (WIPP), near Carlsbad, New Mexico. Sampling consists of removing some head space gas from each drum, removing a core from a few drums of each homogeneous waste stream, and visually characterizing a few drums from each heterogeneous waste stream. The gases are analyzed by GC/MS, and the cores are analyzed for VOC`s and SVOC`s by GC/MS and for metals by AA or AE spectroscopy. The sampling and examination projects are conducted in accordance with the ``DOE TRU Waste Quality Assurance Program Plan`` (QAPP) and the ``LANL TRU Waste Quality Assurance Project Plan,`` (QAPjP), guaranteeing that the data meet the needs of both the Carlsbad Area Office (CAO) of DOE and the ``WIPP Waste Acceptance Criteria, Rev. 5,`` (WAC).

  20. 2013 Los Alamos National Laboratory Hazardous Waste Minimization Report

    SciTech Connect

    Salzman, Sonja L.; English, Charles J.

    2015-08-24

    Waste minimization and pollution prevention are inherent goals within the operating procedures of Los Alamos National Security, LLC (LANS). The US Department of Energy (DOE) and LANS are required to submit an annual hazardous waste minimization report to the New Mexico Environment Department (NMED) in accordance with the Los Alamos National Laboratory (LANL or the Laboratory) Hazardous Waste Facility Permit. The report was prepared pursuant to the requirements of Section 2.9 of the LANL Hazardous Waste Facility Permit. This report describes the hazardous waste minimization program (a component of the overall Waste Minimization/Pollution Prevention [WMin/PP] Program) administered by the Environmental Stewardship Group (ENV-ES). This report also supports the waste minimization and pollution prevention goals of the Environmental Programs Directorate (EP) organizations that are responsible for implementing remediation activities and describes its programs to incorporate waste reduction practices into remediation activities and procedures. LANS was very successful in fiscal year (FY) 2013 (October 1-September 30) in WMin/PP efforts. Staff funded four projects specifically related to reduction of waste with hazardous constituents, and LANS won four national awards for pollution prevention efforts from the National Nuclear Security Administration (NNSA). In FY13, there was no hazardous, mixedtransuranic (MTRU), or mixed low-level (MLLW) remediation waste generated at the Laboratory. More hazardous waste, MTRU waste, and MLLW was generated in FY13 than in FY12, and the majority of the increase was related to MTRU processing or lab cleanouts. These accomplishments and analysis of the waste streams are discussed in much more detail within this report.

  1. SNM holdup assessment of Los Alamos exhaust ducts. Final report

    SciTech Connect

    Marshall, R.S.

    1994-02-01

    Fissile material holdup in glovebox and fume hood exhaust ducting has been quantified for all Los Alamos duct systems. Gamma-based, nondestructive measurements were used to quantify holdup. The measurements were performed during three measurement campaigns. The first campaign, Phase I, provided foot-by-foot, semiquantitative measurement data on all ducting. These data were used to identify ducting that required more accurate (quantitative) measurement. Of the 280 duct systems receiving Phase I measurements, 262 indicated less than 50 g of fissile holdup and 19 indicated fissile holdup of 50 or more grams. Seven duct systems were measured in a second campaign, called Series 1, Phase II. Holdup estimates on these ducts ranged from 421 g of {sup 235}U in a duct servicing a shut-down uranium-machining facility to 39 g of {sup 239}Pu in a duct servicing an active plutonium-processing facility. Measurements performed in the second campaign proved excessively laborious, so a third campaign was initiated that used more efficient instrumentation at some sacrifice in measurement quality. Holdup estimates for the 12 duct systems measured during this third campaign ranged from 70 g of {sup 235}U in a duct servicing analytical laboratories to 1 g of {sup 235}U and 1 g of {sup 239}Pu in a duct carrying exhaust air to a remote filter building. These quantitative holdup estimates support the conclusion made at the completion of the Phase I measurements that only ducts servicing shut-down uranium operations contain about 400 g of fissile holdup. No ventilation ducts at Los Alamos contain sufficient fissile material holdup to present a criticality safety concern.

  2. Pinon Pine Tree Study, Los Alamos National Laboratory: Source document

    SciTech Connect

    P. R. Fresquez; J. D. Huchton; M. A. Mullen; L. Naranjo, Jr.

    2000-01-01

    One of the dominant tree species growing within and around Los Alamos National Laboratory (LANL), Los Alamos, NM, lands is the pinon pine (Pinus edulis) tree. Pinon pine is used for firewood, fence posts, and building materials and is a source of nuts for food--the seeds are consumed by a wide variety of animals and are also gathered by people in the area and eaten raw or roasted. This study investigated the (1) concentration of {sup 3}H, {sup 137}Cs, {sup 90}Sr, {sup tot}U, {sup 238}Pu, {sup 239,240}Pu, and {sup 241}Am in soils (0- to 12-in. [31 cm] depth underneath the tree), pinon pine shoots (PPS), and pinon pine nuts (PPN) collected from LANL lands and regional background (BG) locations, (2) concentrations of radionuclides in PPN collected in 1977 to present data, (3) committed effective dose equivalent (CEDE) from the ingestion of nuts, and (4) soil to PPS to PPN concentration ratios (CRs). Most radionuclides, with the exception of {sup 3}H in soils, were not significantly higher (p < 0.10) in soils, PPS, and PPN collected from LANL as compared to BG locations, and concentrations of most radionuclides in PPN from LANL have decreased over time. The maximum net CEDE (the CEDE plus two sigma minus BG) at the most conservative ingestion rate (10 lb [4.5 kg]) was 0.0018 mrem (0.018 {micro}Sv). Soil-to-nut CRs for most radionuclides were within the range of default values in the literature for common fruits and vegetables.

  3. Post-Cold War Science and Technology at Los Alamos

    NASA Astrophysics Data System (ADS)

    Browne, John C.

    2002-04-01

    Los Alamos National Laboratory serves the nation through the development and application of leading-edge science and technology in support of national security. Our mission supports national security by: ensuring the safety, security, and reliability of the U.S. nuclear stockpile; reducing the threat of weapons of mass destruction in support of counter terrorism and homeland defense; and solving national energy, environment, infrastructure, and health security problems. We require crosscutting fundamental and advanced science and technology research to accomplish our mission. The Stockpile Stewardship Program develops and applies, advanced experimental science, computational simulation, and technology to ensure the safety and reliability of U.S. nuclear weapons in the absence of nuclear testing. This effort in itself is a grand challenge. However, the terrorist attack of September 11, 2001, reminded us of the importance of robust and vibrant research and development capabilities to meet new and evolving threats to our national security. Today through rapid prototyping we are applying new, innovative, science and technology for homeland defense, to address the threats of nuclear, chemical, and biological weapons globally. Synergistically, with the capabilities that we require for our core mission, we contribute in many other areas of scientific endeavor. For example, our Laboratory has been part of the NASA effort on mapping water on the moon and NSF/DOE projects studying high-energy astrophysical phenomena, understanding fundamental scaling phenomena of life, exploring high-temperature superconductors, investigating quantum information systems, applying neutrons to condensed-matter and nuclear physics research, developing large-scale modeling and simulations to understand complex phenomena, and exploring nanoscience that bridges the atomic to macroscopic scales. In this presentation, I will highlight some of these post-cold war science and technology advances

  4. Rhenium(V) and technetium(V) nitrido complexes with mixed tridentate π-donor and monodentate π-acceptor ligands.

    PubMed

    Boschi, Alessandra; Cazzola, Emiliano; Uccelli, Licia; Pasquali, Micol; Ferretti, Valeria; Bertolasi, Valerio; Duatti, Adriano

    2012-03-01

    Mixed-ligand [M(N)(SNS)(PPh(3))] complexes (M = Tc, Re) (1, 2) were prepared by reaction of the precursor [M(N)Cl(2)(PPh(3))(2)] with ligand 2,2'-dimercaptodiethylamine [H(2)SNS = NH(CH(2)CH(2)SH)(2)] in refluxing dichloromethane/ethanol mixtures. In these compounds, 2,2'-dimercaptodiethylamine acts as a dianionic tridentate chelating ligand bound to the [M≡N](2+) group through the two π-donor deprotonated sulfur atoms and the protonated amine nitrogen atom. Triphenylphosphine completes the coordination sphere, acting as a monodentate ligand. [M(N)(NS(2))(PPh(3))] complexes can assume two different isomeric forms depending on the syn and anti orientations of the hydrogen atom bound to the central nitrogen atom of the SNS ligand with respect to the M≡N moiety. X-ray crystallography of the syn isomer of complex 2 demonstrated that it has a distorted trigonal bipyramidal geometry with the nitrido group and the two sulfur atoms defining the equatorial plane, the phosphorus atom of the monophosphine and the protonated amine nitrogen of the tridentate ligand spanning the two reciprocal trans positions along the axis perpendicular to the trigonal plane. Synthesis of the analogous Tc derivatives with tris(2-cyanoethyl)phosphine, [Tc(N)(SNS)(PCN)] [(PCN = P(CH(2)CH(2)CN)(3)], required the preliminary preparation of the new precursor [Tc(N)(PCN)(2)Cl(2)](2) (3), which was prepared by reacting [n-NBu(4)][Tc(N)Cl(4)] with a high excess of PCN. The crystal structure of compound 3 consists of a noncrystallographic centrosymmetric dimer of Tc(V) nitrido complexes having an octahedral geometry. In this arrangement, the apical positions are occupied by two tris(2-cyanoethyl)phosphine groups and the equatorial positions by the nitrido group whereas the two Cl(-) anions and one cyano ligand belong to the other octahedral component of the dimer. By reacting the new precursor [Tc(N)(PCN)(2)Cl(2)](2) with the ligand H(2)SNS the complex [Tc(N)(SNS)(PCN)] (5) was finally obtained in

  5. Rhenium(V) and technetium(V) nitrido complexes with mixed tridentate π-donor and monodentate π-acceptor ligands.

    PubMed

    Boschi, Alessandra; Cazzola, Emiliano; Uccelli, Licia; Pasquali, Micol; Ferretti, Valeria; Bertolasi, Valerio; Duatti, Adriano

    2012-03-01

    Mixed-ligand [M(N)(SNS)(PPh(3))] complexes (M = Tc, Re) (1, 2) were prepared by reaction of the precursor [M(N)Cl(2)(PPh(3))(2)] with ligand 2,2'-dimercaptodiethylamine [H(2)SNS = NH(CH(2)CH(2)SH)(2)] in refluxing dichloromethane/ethanol mixtures. In these compounds, 2,2'-dimercaptodiethylamine acts as a dianionic tridentate chelating ligand bound to the [M≡N](2+) group through the two π-donor deprotonated sulfur atoms and the protonated amine nitrogen atom. Triphenylphosphine completes the coordination sphere, acting as a monodentate ligand. [M(N)(NS(2))(PPh(3))] complexes can assume two different isomeric forms depending on the syn and anti orientations of the hydrogen atom bound to the central nitrogen atom of the SNS ligand with respect to the M≡N moiety. X-ray crystallography of the syn isomer of complex 2 demonstrated that it has a distorted trigonal bipyramidal geometry with the nitrido group and the two sulfur atoms defining the equatorial plane, the phosphorus atom of the monophosphine and the protonated amine nitrogen of the tridentate ligand spanning the two reciprocal trans positions along the axis perpendicular to the trigonal plane. Synthesis of the analogous Tc derivatives with tris(2-cyanoethyl)phosphine, [Tc(N)(SNS)(PCN)] [(PCN = P(CH(2)CH(2)CN)(3)], required the preliminary preparation of the new precursor [Tc(N)(PCN)(2)Cl(2)](2) (3), which was prepared by reacting [n-NBu(4)][Tc(N)Cl(4)] with a high excess of PCN. The crystal structure of compound 3 consists of a noncrystallographic centrosymmetric dimer of Tc(V) nitrido complexes having an octahedral geometry. In this arrangement, the apical positions are occupied by two tris(2-cyanoethyl)phosphine groups and the equatorial positions by the nitrido group whereas the two Cl(-) anions and one cyano ligand belong to the other octahedral component of the dimer. By reacting the new precursor [Tc(N)(PCN)(2)Cl(2)](2) with the ligand H(2)SNS the complex [Tc(N)(SNS)(PCN)] (5) was finally obtained in

  6. Tridentate ligands containing the SNS donor atom set as a novel backbone for the development of technetium brain-imaging agents.

    PubMed

    Mastrostamatis, S G; Papadopoulos, M S; Pirmettis, I C; Paschali, E; Varvarigou, A D; Stassinopoulou, C I; Raptopoulou, C P; Terzis, A; Chiotellis, E

    1994-09-30

    In developing 99mTc complexes as potential brain-imaging agents, we investigated the coordination chemistry of ligands containing sulfur and nitrogen donor atoms with the general formula R-CH2CH2N(CH2CH2SH)2 (R = C2H5S, (C2H5)2N). These ligands act as tridentate SNS chelates to the TcO3+ core, leaving open one coordination site cis to the oxo group. In reactions with the highly reactive [99TcOCl4]- precursor, this vacancy was occupied by a chlorine atom. When the ligands reacted in the presence of 4-methoxythiophenol, using 99Tc(V)-gluconate as precursor, the vacancy was filled with 4-methoxythiophenol, which acted as coligand. Thus neutral mixed ligand complexes of the general formula [TcO((SCH2CH2)2NCH2CH2R)X], where X = Cl or 4-methoxythiophenol, were synthesized. The complexes were characterized by UV-vis, IR, 1H NMR, crystallographic, and elemental analyses. The crystal structures of 3a (R = C2H5S, X = Cl) and 4b (R = (C2H5)2N, X = 4-methoxythiophenol) demonstrated that the coordination geometry is trigonal bipyramidal with the N1 and Cl or S3 occupying the apical positions and the basal plane defined by the S1 and S2 of the tridentate ligand and the oxo group. The complexes 4a(99mTc) (R = C2H5S, X = 4-methoxythiophenol) and 4b(99mTc) were prepared using 99mTc-glucoheptonate as precursor and were purified by HPLC. Biodistribution in mice showed high initial brain uptake (3.68% and 3.56% dose/organ for 4a(99mTc) and 4b(99m-Tc), respectively). Complex 4b(99mTc) displayed significantly higher brain/blood values and prolonged retention in brain as well. The results suggest that structural modifications based on configurations 4a,b may provide novel 99mTc brain-imaging agents with improved biological characteristics. PMID:7932548

  7. Environmental Assessment for Electrical Power System Upgrades at Los Alamos National Laboratory, Los Alamos, New Mexico - Final Document

    SciTech Connect

    N /A

    2000-03-09

    The ''National Environmental Policy Act of 1969'' (NEPA) requires Federal agency officials to consider the environmental consequences of their proposed actions before decisions are made. In complying with NEPA, the United States (U.S.) Department of Energy (DOE) follows the Council on Environmental Quality (CEQ) regulations (40 Code of Federal Regulations [CFR] 1500-1508) and DOE's NEPA implementing procedures (10 CFR 1021). The purpose of an Environmental Assessment (EA) is to provide Federal decision makers with sufficient evidence and analysis to determine whether to prepare an Environmental Impact Statement (EIS) or issue a Finding of No Significant Impact. In this case, the DOE decision to be made is whether to construct and operate a 19.5-mile (mi) (31-kilometer [km]) electric transmission line (power line) reaching from the Norton Substation, west across the Rio Grande, to locations within the Los Alamos National Laboratory (LANL) Technical Areas (TAs) 3 and 5 at Los Alamos, New Mexico. The construction of one electric substation at LANL would be included in the project as would the construction of two line segments less than 1,200 feet (ft) (366 meters [m]) long that would allow for the uncrossing of a portion of two existing power lines. Additionally, a fiber optics communications line would be included and installed concurrently as part of the required overhead ground conductor for the power line. The new power line would improve the reliability of electric service in the LANL and Los Aktrnos County areas as would the uncrossing of the crossed segments of the existing lines. Additionally, installation of the new power line would enable the LANL and the Los Alamos County electric grid, which is a shared resource, to be adapted to accommodate the future import of increased power when additional power service becomes available in the northern New Mexico area. Similarly, the fiber optics line would allow DOE to take advantage of future opportunities in

  8. Los Alamos Conference on Optics '81, 2nd, Los Alamos, NM, April 7-10, 1981, Proceedings

    SciTech Connect

    Liebenberg, D.H.

    1981-01-01

    Among the topics discussed are improved aluminum coatings for UV optical components, thick optical films for the conduction of optical and IR radiation, glancing incidence optics for high-power lasers, the optical quality of pulsed aerodynamic laser windows, optical tooling for Antares, modeling the CF4 laser, optical fiber probes, ultraviolet phase conjugation and its implications, laser-induced bioluminescence, the use of a free-expansion jet in ultrahigh-resolution Raman spectroscopy, and sub-Doppler optoacoustic spectroscopy. Also considered are new liquid scintillators for fiber optic applications, the frequency response of the thermal lens, meteorological lidar developments, the design and performance of a new emission-line coronagraph, Smartt interferometers, multigigahertz beam diagnostics for laser fusion, and the surface characterization of metal optics.

  9. Audit of the radioactive liquid waste treatment facility operations at the Los Alamos National Laboratory

    SciTech Connect

    1997-11-19

    Los Alamos National Laboratory (Los Alamos) generates radioactive and liquid wastes that must be treated before being discharged to the environment. Presently, the liquid wastes are treated in the Radioactive Liquid Waste Treatment Facility (Treatment Facility), which is over 30 years old and in need of repair or replacement. However, there are various ways to satisfy the treatment need. The objective of the audit was to determine whether Los Alamos cost effectively managed its Treatment Facility operations. The audit determined that Los Alamos` treatment costs were significantly higher when compared to similar costs incurred by the private sector. This situation occurred because Los Alamos did not perform a complete analysis of privatization or prepare a {open_quotes}make-or-buy{close_quotes} plan for its treatment operations, although a {open_quotes}make-or-buy{close_quotes} plan requirement was incorporated into the contract in 1996. As a result, Los Alamos may be spending $2.15 million more than necessary each year and could needlessly spend $10.75 million over the next five years to treat its radioactive liquid waste. In addition, Los Alamos has proposed to spend $13 million for a new treatment facility that may not be needed if privatization proves to be a cost effective alternative. We recommended that the Manager, Albuquerque Operations Office (Albuquerque), (1) require Los Alamos to prepare a {open_quotes}make-or-buy{close_quotes} plan for its radioactive liquid waste treatment operations, (2) review the plan for approval, and (3) direct Los Alamos to select the most cost effective method of operations while also considering other factors such as mission support, reliability, and long-term program needs. Albuquerque concurred with the recommendations.

  10. Experimental studies of X-ray emission physics and hydrodynamics using short wavelength lasers

    NASA Astrophysics Data System (ADS)

    Goldstone, P. D.; Casperson, D. E.; Cobble, J. A.; Coggeshall, S. V.; Gomez, C. C.; Hauer, A.; Kyrala, G. A.; Lee, P. H. Y.; Mead, W. C.; Schappert, G. T.

    Several experimental efforts are currently under way at Low Alamos to study issues of importance for inertial confinement fusion with short wavelength lasers. These issues include the physics of X-ray conversion and the dynamics of short-wavelength laser interaction with high-Z plasmas; filamentation and self-focusing processes; and the growth of instabilities in laser-driven implosions. Most of these experiments are being pursued in collaboration with other laboratories, notably the University of Rochester and Lawrence Livermore National Laboratory. In addition, we are undertaking basic studies of the interaction of both atomic systems and solids with ultra-intense (approximately 10 to the minus 17th W/sq cm) subpicosecond lasers at Los Alamos. These experiments explore the response of atomic systems to strong fields, multiphoton excitation, and transient phenomena in dense plasmas.

  11. NEPA and NHPA- successful decommissioning of historic Manhattan Project properties at Los Alamos National Laboratory, Los Alamos, New Mexico

    SciTech Connect

    McGehee, E.D.; Pendergrass, A.K.

    1997-05-21

    This paper describes experiences at Los Alamos National Laboratory during the process of planning and executing decommissioning and decontamination activities on a number of properties constructed as part of the Manhattan project. Many of these buildings had been abandoned for many years and were in deteriorating condition, in addition to being contaminated with asbestos, lead based paints and high explosive residues. Due to the age and use of the structures they were evaluated against criteria for the National Register of Historic Places. This process is briefly reviewed, along with the results, as well as actions implemented as a result of the condition and safety of the structures. A number of the structures have been decontaminated and demolished. Planning is still ongoing for the renovation of one structure, and the photographic and drawing records of the properties is near completion.

  12. Ecological baseline studies in Los Alamos and Guaje Canyons County of Los Alamos, New Mexico. A two-year study

    SciTech Connect

    Foxx, T.S.

    1995-11-01

    During the summers of 1993 and 1994, the Biological Resource Evaluations Team (BRET) of the Environmental Protection Group (ESH-8) conducted baseline studies within two canyon systems, Los Alamos and Guaje Canyons. Biological data was collected within each canyon to provide background and baseline information for Ecological Risk models. Baseline studies included establishment of permanent vegetation plots within each canyon along the elevational gradient. Then, in association with the various vegetation types, surveys were conducted for ground dwelling insects, birds, and small mammals. The stream channels associated with the permanent vegetation plots were characterized and aquatic macroinvertebrates collected within the stream monthly throughout a six-month period. The Geographic Position System (GPS) in combination with ARC INFO was used to map the study areas. Considerable data was collected during these surveys and are summarized in individual chapters.

  13. Process Modeling and Analysis for Radioactive Solid Waste Management at Los Alamos

    SciTech Connect

    Kornreich, D.E.; Parker, R.Y.; Gonzales-Lujan, J.M.

    2006-07-01

    Los Alamos National Laboratory has created a discrete-event simulation model of the nuclear waste drum characterization operations the 'processing/inspection - Los Alamos model of drums equivalent' ({pi} a la mode). This model takes drum inventory data, process-related information, and planned processing priorities related to the solid-waste management operations at Los Alamos to assess the resulting characterization process and resulting schedule for drum shipments to the Waste Isolation Pilot Plant. The model tracks the drum inventory, material inventory, and equipment as a function of time. Data from the model and some sample results are presented in this paper. (authors)

  14. Los Alamos National Laboratory: 21st century solutions to urgent national challenges

    SciTech Connect

    Mcbranch, Duncan

    2008-01-01

    Los Alamos National Laboratory has been called upon to meet urgent national challenges for more than 65 years. The people, tools, and technologies at Los Alamos are a world class resource that has proved decisive through our history, and are needed in the future. We offer expertise in nearly every science, technology, and engineering discipline, a unique integrated capability for large-scale computing and experimentation, and the proven ability to deliver solutions involving the most complex and difficult technical systems. This white paper outlines some emerging challenges and why the nation needs Los Alamos, the premier National Security Science Laboratory, to meet these challenges.

  15. Radionuclide concentrations in pinto beans, sweet corn, and zucchini squash grown in Los Alamos Canyon at Los Alamos National Laboratory

    SciTech Connect

    Fresquez, P.R.; Mullen, M.A.; Naranjo, L. Jr.; Armstrong, D.R.

    1997-05-01

    Pinto beans, sweet corn, and zucchini squash (Cucurbita pepo var. black beauty) were grown in a randomized complete-block field/pot experiment at a site that contained the highest observed levels of surface gross gamma radioactivity within Los Alamos Canyon (LAC) at Los Alamos National Laboratory. Soils as well as washed edible and nonedible crop tissues were analyzed for various radionuclides and heavy metals . Most radionuclides, with the exception of {sup 3}H and {sup tot}U, in soil from LAC were detected in significantly higher concentrations (p <0.01) than in soil collected from regional background (RBG) locations. Similarly, most radionuclides in edible crop portions of beans, squash, and corn were detected in significantly higher (p <0.01 and 0.05) concentrations than RBG. Most soil-to-plant concentration ratios for radionuclides in edible and nonedible crop tissues from LAC were within the default values given by the Nuclear Regulatory Commission and Environmental Protection Agency. All heavy metals in soils, as well as edible and nonedible crop tissues grown in soils from LAC, were within RBG concentrations. Overall, the total maximum net positive committed effective dose equivalent (CEDE)--the CEDE plus two sigma for each radioisotope minus background and then all positive doses summed--to a hypothetical 50-year resident that ingested 160 kg of beans, corn, and squash in equal proportions, was 74 mrem y{sup -1}. This dose was below the International Commission on Radiological Protection permissible dose limit (PDL) of 100 mrem y{sup -1} from all pathways; however, the addition of other internal and external exposure route factors may increase the overall dose over the PDL. Also, the risk of an excess cancer fatality, based on 74 mrem y{sup -1}, was 3.7 x 10{sup -5} (37 in a million), which is above the Environmental Protection Agency`s (acceptable) guideline of one in a million. 31 refs., 15 tabs.

  16. Qualification of diode foil materials for excimer lasers

    NASA Astrophysics Data System (ADS)

    Anderson, R. G.; Shurter, R. P.; Rose, E. A.

    The Aurora facility at Los Alamos National Laboratory uses KrF excimer lasers to produce 248 nm light for inertial confinement fusion applications. Diodes in each amplifier produce relativistic electron beams to pump a Kr-F-Ar gas mixture. A foil is necessary to separate the vacuum diode from the laser gas. High tensile strength, high electron transmission, low ultraviolet reflectivity, and chemical compatibility with fluorine have been identified as requisite foil properties. Several different materials were acquired and tested for use as diode foils. Transmission and fluorine compatibility tests were performed using the Electron Gun Test Facility (EGTF) at Los Alamos. Off-line tests of tensile strength and reflectivity were performed. Titanium foil, which is commonly used as a diode foil, was found to generate solid and gaseous fluoride compounds, some of which are highly reactive in contact with water vapor.

  17. Open coordination sites-induced structural diversity of a new series of Cu(II) complexes with tridentate aroylhydrazone Schiff base

    NASA Astrophysics Data System (ADS)

    Xu, Guohong; Tang, Beibei; Gu, Leilei; Zhou, Pei; Li, Hui

    2016-09-01

    Six Cu(II) complexes containing the NO2 donor tridentate asymmetrical aroylhydrazone ligand (E)-4-hydroxy-N‧-((2-hydroxynaphthalen-1-yl)methylene)benzohydrazide (HL), namely, [Cu(L)Cl]·2H2O (1), [Cu(L)(CH3OH)2]·NO3 (2), [Cu(L)(NO3)(H2O)]·H2O (3), [Cu(L)(CH3OH)Cl]·CH3OH (4), [Cu(L)(SCN)(DMF)]·DMF (5) and {[Cu(L)(4,4‧-bipy)]ClO4·4DMF}n (6) have been synthesized and analysized by X-ray singal crystal diffraction. The structures of 1-6 are varied from zero-dimensional (0D) mononuclear complex to one-dimensional (1D) polymer based on the control of solvents, anions or auxiliary ligands, which can occupy the open coordination sites of Cu(II). Different hydrogen bonding interactions can also be observed in these complexes.

  18. o-, m-, and p-Pyridyl isomer effects on construction of 1D loop-and-chains: Silver(I) coordination polymers with Y-type tridentate ligands

    NASA Astrophysics Data System (ADS)

    Kim, Jeong Gyun; Cho, Yoonjung; Lee, Haeri; Lee, Young-A.; Jung, Ok-Sang

    2016-10-01

    Self-assembly of silver(I) hexafluorophosphate with unique Y-type tridentate ligands (2,6-bis[(2-picolinoyloxy-5-methylphenyl)methyl]-p-tolylpicolinate (o-L), 2-nicotinoyloxy- (m-L), and 2-isonicotinoyloxy- (p-L)) produces single crystals consisting of 1D loop-and-chain coordination polymers of [Ag(o-L)](PF6)·Me2CO·CHCl3, [Ag(m-L)](PF6)·Me2CO, and [Ag3(p-L)2](PF6)3·2H2O·2C2H5OH·4CH2Cl2 with quite different trigonal prismatic, trigonal, and linear silver(I) coordination geometry, respectively. Coordinating ability of the three ligands for AgPF6 is in the order of p-L > o-L > m-L. The solvate molecules of [Ag(o-L)](PF6)·Me2CO·CHCl3 can be removed, and be replaced reversibly in the order of acetone ≫ chloroform ≈ dichloromethane ≫ benzene, without destruction of its skeleton.

  19. Binary and ternary copper(II) complexes of a tridentate ONS ligand derived from 2-aminochromone-3 carboxaldehyde and thiosemicarbazide: Synthesis, spectral studies and antimicrobial activity

    NASA Astrophysics Data System (ADS)

    Shebl, Magdy; Ibrahim, M. A.; Khalil, Saied M. E.; Stefan, S. L.; Habib, H.

    2013-11-01

    A tridentate ONS donor ligand, HL, was synthesized by the condensation of 2-aminochromone-3-carboxaldehyde with thiosemicarbazide. The structure of the ligand was elucidated by elemental analyses, IR, 1H and 13C NMR, electronic and mass spectra. Reaction of the ligand with several copper(II) salts, including AcO-, NO3-, SO42-, Cl-, Br- and ClO4- afforded different metal complexes that reflect the non-coordinating or weakly coordinating power of the ClO4- and Br- anions as compared to the strongly coordinating power of AcO-, SO42-, Cl- and NO3- anions. Also, the ligand was allowed to react with Cu(II) ion in the presence of a secondary ligand (L‧) [N,O-donor; 8-hydroxyquinoline or N,N-donor; 1,10-phenanthroline]. Characterization and structure elucidation of the prepared complexes were achieved by elemental and thermal analyses, IR, electronic, mass and EPR spectra as well as conductivity and magnetic susceptibility measurements. The EPR spin Hamiltonian parameters of some complexes were calculated. The metal complexes exhibited octahedral and square planar geometrical arrangements depending on the nature of the anion. The ligand and most of its metal complexes showed antibacterial activity towards Gram-positive bacteria (Staphylococcus aureus and Bacillus subtilis), Gram-negative bacteria (Salmonella typhimurium and Escherichia coli), yeast (Candida albicans) and fungus (Aspergillus fumigatus).

  20. Synthesis, spectroscopic studies, thermal analyses, biological activity of tridentate coordinated transition metal complexes of bi(pyridyl-2-ylmethyl)amine]ligand

    NASA Astrophysics Data System (ADS)

    Abd El-Halim, Hanan F.; Mohamed, Gehad G.

    2016-01-01

    A new tridentate acyclic pincer ligand, [bi(pyridin-2-methyl)amine] (bpma, HL), was synthesized and reacted to form complexes with copper(II), nickel(II), iron(II), cobalt(II) and zinc(II) ions. Both the ligand and its complexes were characterized using elemental analysis, molar conductance, infrared, 1H-NMR-spectroscopy, mass and thermal analyses. According to the spectroscopic data, all of the complexes share the same coordination environment around the metal atoms, consisting two nitrogen-pyridine entities, one nitrogen-methylamine entity, one/two water molecules and/or one/two chloride or bromide ions. Complexes also showed molar conductivity according to the presence of two halide anions outer the coordination sphere except Co(II) and Zn(II) complexes are non electrolytes. Analysis indicates that the metal ions have trigonal bipyramidal structure. Cu(II), Ni(II), Fe(II), Co(II), and Zn(II) metal complexes were screened for their antibacterial activity against Bacillus subtilis, Staphylococcus aureus (G+) and Escherichia coli, and Pseudomonas aeruginosa (G-) bacteria. They showed remarkable antimicrobial activity.

  1. Coordination chemistry of Co complexes containing tridentate SNS ligands and their application as catalysts for the oxidation of n-octane.

    PubMed

    Soobramoney, Lynette; Bala, Muhammad D; Friedrich, Holger B

    2014-11-14

    The selective oxidation of saturated hydrocarbons to terminal oxygenates under mild catalytic conditions has remained a centuries long challenge in chemical catalysis. In an attempt to address this challenge, two series of tridentate donor ligands {2,6-bis(RSCH2)pyridine and bis(RSCH2CH2)amine [R = alkyl, aryl]} and their respective cobalt complexes {Co[2,6-bis(RSCH2)pyridine]Cl2 and Co[bis(RSCH2CH2)amine]Cl2} were synthesized and characterized. Crystal structures of Co[2,6-bis(RSCH2)pyridine]Cl2 [R = -CH3 (), -CH2CH3 (), -CH2CH2CH2CH3 () and -C6H5 ()] are reported in which crystallized as a homo-bimetallic dimer that incorporated two bridging chloride atoms in an octahedral geometry around each cobalt center, while , and crystallized as mono-metallic species characterized by trigonal bipyramidal arrangement of ligands around each cobalt center. As catalysts for the homogeneous selective oxidation of n-octane, the catalysts yielded ketones as the dominant products with a selectivity of ca. 90% for the most active catalyst Co[bis(CH2CH2SCH2CH2)amine]Cl2 () at a total n-octane conversion of 23%. Using tert-butyl hydroperoxide (TBHP) as an oxidant, optimization of reaction conditions is also reported.

  2. Complexes of cis-dioxomolybdenum(VI) and oxovanadium(IV) with a tridentate ONS donor ligand: synthesis, spectroscopic properties, X-ray crystal structure and catalytic activity.

    PubMed

    Fayed, Ahmed M; Elsayed, Shadia A; El-Hendawy, Ahmed M; Mostafa, Mohamed R

    2014-08-14

    New cis-dioxomolybdenum(VI) and oxovanadium(IV) complexes of the Schiff base, derived from S-methyl dithiocarbazate and 2,3-dihydroxybenzaldehyde (H2dhsm), have been synthesized. The complexes of the type cis-[MoO2(dhsm)] (1a), cis-[MoO2(dhsm)(D)] (1b-1d) [D=neutral monodentate ligand; EtOH, pyridine (py) or imidazole (imz)], [VO(dhsm)(NN)] (2a, 2b) [NN=2,2'-bipyridine (bipy) or 1,10-phenanthroline (phen)] and [VO(dhsm)] (2c) have been isolated, characterized by (1)H NMR, IR, UV-Vis and EPR spectral studies and investigated by cyclic voltammetry. The X-ray crystal structure of cis-[MoO2(dhsm)(EtOH)] (1b) has been determined and shows that the complex has a distorted octahedral geometry in which the H2dhsm behaves as a dianionic ONS tridentate ligand coordinating via phenoxide oxygen, hydrazinic nitrogen and thiolate sulfur. The oxomolybdenum(IV) complex [MoO(dhsm)] (1e) has obtained from dioxomolybdenum(VI) complex (1b) by oxo abstraction with PPh3. The reactivity of the complexes toward catalytic oxidation of alcohols in the presence of H2O2 and t-BuOOH as co-oxidants under solvent free conditions is reported. PMID:24747851

  3. A new tridentate Schiff base Cu(II) complex: Synthesis, experimental and theoretical studies on its crystal structure, FT-IR and UV-Visible spectra

    NASA Astrophysics Data System (ADS)

    Saheb, Vahid; Sheikhshoaie, Iran; Setoodeh, Nasim; Rudbari, Hadi Amiri; Bruno, Giuseppe

    2013-06-01

    A new Cu(II) complex [Cu(L)(NCS)] has been synthesized, using 1-(N-salicylideneimino)-2-(N,N-methyl)-aminoethane as tridentate ONN donor Schiff base ligand (HL). The dark green crystals of the compound are used for single-crystal X-ray analysis and measuring Fourier Transform Infrared (FT-IR) and UV-Visible spectra. Electronic structure calculations at the B3LYP and MP2 levels of theory are performed to optimize the molecular geometry and to calculate the UV-Visible and FT-IR spectra of the compound. Vibrational assignments and analysis of the fundamental modes of the compound are performed. Time-dependent density functional theory (TD-DFT) method is used to calculate the electronic transitions of the complex. A scaling factor of 1.015 is obtained for vibrational frequencies computed at the B3LYP level using basis sets 6-311G(d,p). It is found that solvent has a profound effect on the electronic absorption spectrum. The UV-Visible spectrum of the complex recorded in DMSO and DMF solution can be correctly predicted by a model in which DMSO and DMF molecules are coordinated to the central Cu atom via their oxygen atoms.

  4. Complexes of cis-dioxomolybdenum(VI) and oxovanadium(IV) with a tridentate ONS donor ligand: Synthesis, spectroscopic properties, X-ray crystal structure and catalytic activity

    NASA Astrophysics Data System (ADS)

    Fayed, Ahmed M.; Elsayed, Shadia A.; El-Hendawy, Ahmed M.; Mostafa, Mohamed R.

    2014-08-01

    New cis-dioxomolybdenum(VI) and oxovanadium(IV) complexes of the Schiff base, derived from S-methyl dithiocarbazate and 2,3-dihydroxybenzaldehyde (H2dhsm), have been synthesized. The complexes of the type cis-[MoO2(dhsm)] (1a), cis-[MoO2(dhsm)(D)] (1b-1d) [D = neutral monodentate ligand; EtOH, pyridine (py) or imidazole (imz)], [VO(dhsm)(Nsbnd N)] (2a, 2b) [Nsbnd N = 2,2‧-bipyridine (bipy) or 1,10-phenanthroline (phen)] and [VO(dhsm)] (2c) have been isolated, characterized by 1H NMR, IR, UV-Vis and EPR spectral studies and investigated by cyclic voltammetry. The X-ray crystal structure of cis-[MoO2(dhsm)(EtOH)] (1b) has been determined and shows that the complex has a distorted octahedral geometry in which the H2dhsm behaves as a dianionic ONS tridentate ligand coordinating via phenoxide oxygen, hydrazinic nitrogen and thiolate sulfur. The oxomolybdenum(IV) complex [MoO(dhsm)] (1e) has obtained from dioxomolybdenum(VI) complex (1b) by oxo abstraction with PPh3. The reactivity of the complexes toward catalytic oxidation of alcohols in the presence of H2O2 and t-BuOOH as co-oxidants under solvent free conditions is reported.

  5. Reactivity of tris(acetylacetonato) iron(III) with tridentate [ONO] donor Schiff base as an access to newer mixed-ligand iron(III) complexes

    NASA Astrophysics Data System (ADS)

    Bhattacharjee, Chira R.; Goswami, Pankaj; Pramanik, Harun A. R.; Paul, Pradip C.; Mondal, Paritosh

    2011-05-01

    Two new mixed-ligand iron(III) complexes, [Fe(L n)(acac)(C 2H 5OH)] incorporating coordinated ethanol from the reaction solvent were accessed from the reaction of [Fe(acac) 3] with [ONO] donor dibasic tridentate unsymmetrical Schiff base ligands derived from condensation of 2-hydroxy-1-napthaldehyde with 2-aminophenol (H 2L 1) or 2-aminobenzoic acid (H 2L 2). The thermal study (TGA-DTA) provided evidence for weakly bound ethanol which is readily substituted by neutral N-donor molecule imidazole, benzimidazole or pyridine to produce an array of newer complexes, [Fe(L n)(acac)X] ( n = 1, 2; X = Im, Bim, Py). The compounds were characterized by elemental analyses, FT-IR, UV-vis, solution electrical conductivity, FAB mass, 1H and 13C NMR spectroscopy. Room temperature magnetic susceptibility measurements ( μeff ˜ 5.8 B.M.) are consistent with spin-free octahedral iron(III) complexes. Cyclic voltammetry of ethanol complexes revealed a quasi-reversible one electron redox response (Δ Ep > 100 mV) for the Fe(III)/Fe(II) couple. Low half wave redox potential ( E1/2) values suggested easy redox susceptibility. The ground state geometries of the ethanol and imidazole complexes have been ascertained to be distorted octahedral by density functional theory using DMol3 program at BLYP/DNP level.

  6. Cu(II) complexes of monobasic bi- or tridentate (NO, NNO) azo dye ligands: Synthesis, characterization, and interaction with Cu-nanoparticles

    NASA Astrophysics Data System (ADS)

    Gaber, Mohamed; El-Sayed, Yusif S.; El-Baradie, Kamal; Fahmy, Rowaida M.

    2013-01-01

    A series of copper(II) azo complexes having the formula [CuL1-4(nH2O)]·OAc·xH2O where (n = 1-2) and (x = 0-1) have been synthesized using azo dyes containing the triazol and thiadiazole moieties. The azodyes and their metal complexes were characterized by elemental analysis, molar conductance, IR, electronic, mass, ESR spectra, magnetic moment measurements, and thermal analyses. IR spectra showed that the ligands having triazole moiety were coordinated with the copper(II) ion in a tridentate manner with ONN donor sites of the naphthyl OH, N-atoms of azo group, and triazole moiety while azodyes having thiadiazole moiety were coordinated with the copper(II) ion in a bidentate manner with ON donor sites of the naphthyl OH and the N-atom of the group. The thermodynamic activation parameters such as ΔE*, ΔH*, ΔS*, and ΔG* were calculated from the TG curves. Prepared spherical copper nanoparticles were characterized using UV-Vis spectroscopy and transition electron microscope (TEM). The spectral data showed the formation of surface complex between azo-dye ligands and colloidal copper nanoparticles through (sbnd OH) anchoring group. The stability constant of the prepared copper nanoparticles complexes is higher compared with the corresponding bulk ones due to the larger surface area of copper nanoparticles.

  7. Diagnostics of high-brightness short-pulse lasers and the plasmas they generate

    SciTech Connect

    Kyrala, G.A.; Fulton, R.D.; Cobble, J.A.; Schappert, G.T.; Taylor, A.J.

    1994-02-01

    The properties of a laser influence the interaction of the intense laser light with materials. The authors will describe some of the diagnostics that they have implemented at the Los Alamos Bright Source to correlate the changes in the x-ray spectrum and temporal history of a laser generated silicon plasmas with the changes of the incident XeCl laser light. One property is of special interest, the existence of a short prepulse. They find that the prepulse enhances the generation of the x-rays from a later pulse.

  8. A Tracer Test at the Los Alamos Canyon Weir

    NASA Astrophysics Data System (ADS)

    Levitt, D. G.; Stone, W. J.; Newell, D. L.; Wykoff, D. S.

    2002-12-01

    A low-head weir was constructed in the Los Alamos Canyon to reduce the transport of contaminant-bearing sediment caused by fire-enhanced runoff off Los Alamos National Laboratory (LANL) property towards the Rio Grande following the May 2000 Cerro Grande fire at Los Alamos, New Mexico. Fractured basalt was exposed in the channel by grading during construction of the weir, and water temporarily ponds behind the weir following periods of runoff. In order to monitor any downward transport of contaminants into fractured basalt, and potentially downward to the regional ground water, three boreholes (one vertical, one at 43 degrees, and one at 34 degrees from horizontal) were installed for environmental monitoring. The boreholes penetrate to depths ranging from approximately 9 to 82 m below the weir floor. The two angled boreholes are fitted with flexible FLUTe liners with resistance sensors to measure relative moisture content and absorbent sampling pads for contaminant and environmental tracer sampling within the vadose zone. The two angled boreholes are also monitored for relative changes in moisture content by neutron logging. The vertical borehole penetrates three perched water zones and is equipped with four screens and sampling ports. In April 2002, a tracer test was initiated with the application of a 0.2 M (16,000 ppm) solution of potassium bromide (KBr) onto the weir floor. The tracer experiment was intended to provide data on travel times through the complex hydrogeologic media of fractured basalt. A precipitation and runoff event in June 2002 resulted in approximately 0.61 m of standing water behind the weir. If the KBr and flood waters were well mixed, the concentration of KBr in the flood waters was approximately 24 ppm. Bromide was detected in the absorbent membrane in the 43 degree hole at concentrations up to 2 ppm. Resistance sensors in the 43 degree borehole detected moisture increases within 3 days at a depth of 27 m, indicating an average wetting

  9. Geothermal investigation of spring and well waters of the Los Alamos Region, New Mexico

    SciTech Connect

    Goff, F.E.; Sayer, S.

    1980-04-01

    The chemical and isotopic characters of 20 springs and wells in the Los Alamos area were investigated for indications of geothermal potential. These waters were compared with known hot and mineral springs from adjacent Valles Caldera and San Ysidro. All waters in the Los Alamos area are composed of meteoric water. Isotopic data show that the two primary aquifers beneath the Los Alamos region have different recharge areas. Relatively high concentrations of lithium, arsenic, chlorine, boron, and fluorine in some of the Los Alamos wells suggest these waters may contain a small fraction of thermal/mineral water of deep origin. Thermal water probably rises up high-angle faults associated with a graben of the Rio Grande rift now buried by the Pajarito Plateau.

  10. Los Alamos National Laboratory Science Education Programs. Quarterly progress report, April 1--June 30, 1995

    SciTech Connect

    Gill, D.

    1995-09-01

    This report is quarterly progress report on the Los Alamos National Laboratory Science Education Programs. Included in the report are dicussions on teacher and faculty enhancement, curriculum improvement, student support, educational technology, and institutional improvement.

  11. Shock pressures induced in condensed matter by laser ablation

    NASA Astrophysics Data System (ADS)

    Swift, Damian C.; Tierney, Thomas E.; Kopp, Roger A.; Gammel, J. Tinka

    2004-03-01

    The Trident laser was used to induce shock waves in samples of solid elements, with atomic numbers ranging from Be to Au, using pulses of 527 nm light around 1 ns long with irradiances of the order of 0.1 to 10 PW/m2. States induced by the resulting ablation process were investigated using laser Doppler velocimetry to measure the velocity history of the opposite surface. By varying the energy in the laser pulse, relations were inferred between the irradiance and the induced pressure. For samples in vacuo, an irradiance constant in time does not produce a constant pressure. Radiation hydrodynamics simulations were used to investigate the relationship between the precise pulse shape and the pressure history. In this regime of time and irradiance, it was possible to reproduce the experimental data to within their uncertainty by including conductivity-dependent deposition of laser energy, heat conduction, gray radiation diffusion, and three temperature hydrodynamics in the treatment of the plasma, with ionizations calculated using the Thomas-Fermi equation. States induced in the solid sample were fairly insensitive to the details of modeling in the plasma, so Hugoniot points may be estimated from experiments of this type given a reasonable model of the plasma. More useful applications include the generation of dynamic loading to investigate compressive strength and phase transitions, and for sample recovery.

  12. Nonlinear neutrino-photon interactions inside strong laser pulses

    NASA Astrophysics Data System (ADS)

    Meuren, Sebastian; Keitel, Christoph H.; Di Piazza, Antonino

    2015-06-01

    Even though neutrinos are neutral particles and interact only via the exchange of weak gauge bosons, charged leptons and quarks can mediate a coupling to the photon field beyond tree level. Inside a relativistically strong laser field nonlinear effects in the laser amplitude can play an important role, as electrons and positrons interact nonperturbatively with the coherent part of the photon field. Here, we calculate for the first time the leading-order contribution to the axial-vector-vector current-coupling tensor inside an arbitrary plane-wave laser field (which is taken into account exactly by employing the Furry picture). The current-coupling tensor appears in the calculation of various electroweak processes inside strong laser fields like photon emission or trident electron-positron pair production by a neutrino. Moreover, as we will see below, the axial-vector-vector current-coupling tensor contains the Adler-Bell-Jackiw (ABJ) anomaly. This occurrence renders the current-coupling tensor also interesting from a fundamental point of view, as it is the simplest Feynman diagram in an external field featuring this kind of anomaly.

  13. LOS ALAMOS NATIONAL LABORATORIES: LASER-INDUCED BREAKDOWN SPECTROMETER FOR METALS-CONTAMINATED SOIL CHARACTERIZATION

    EPA Science Inventory

    The U.S. Environmental Protection Agency (EPA), through the Environmental Technology Verification Program, is working to accelerate the acceptance and use of innovative technologies that improve the way the United States manages its environmental problems. This report describes ...

  14. Small Mammal Sampling in Mortandad and Los Alamos Canyons, 2005

    SciTech Connect

    Bennett, Kathy; Sherwood, Sherri; Robinson, Rhonda

    2006-08-15

    As part of an ongoing ecological field investigation at Los Alamos National Laboratory, a study was conducted that compared measured contaminant concentrations in sediment to population parameters for small mammals in the Mortandad Canyon watershed. Mortandad Canyon and its tributary canyons have received contaminants from multiple solid waste management units and areas of concern since establishment of the Laboratory in the 1940s. The study included three reaches within Effluent and Mortandad canyons (E-1W, M-2W, and M-3) that had a spread in the concentrations of metals and radionuclides and included locations where polychlorinated biphenyls and perchlorate had been detected. A reference location, reach LA-BKG in upper Los Alamos Canyon, was also included in the study for comparison purposes. A small mammal study was initiated to assess whether potential adverse effects were evident in Mortandad Canyon due to the presence of contaminants, designated as contaminants of potential ecological concern, in the terrestrial media. Study sites, including the reference site, were sampled in late July/early August. Species diversity and the mean daily capture rate were the highest for E-1W reach and the lowest for the reference site. Species composition among the three reaches in Mortandad was similar with very little overlap with the reference canyon. Differences in species composition and diversity were most likely due to differences in habitat. Sex ratios, body weights, and reproductive status of small mammals were also evaluated. However, small sample sizes of some species within some sites affected the analysis. Ratios of males to females by species of each site (n = 5) were tested using a Chi-square analysis. No differences were detected. Where there was sufficient sample size, body weights of adult small mammals were compared between sites. No differences in body weights were found. Reproductive status of species appears to be similar across sites. However, sample

  15. A Journey From Sandia To Los Alamos - 12465

    SciTech Connect

    Goyal, K.K.; Humphrey, B.J.; Krause, T.J.; Gluth, J.W.; Kiefer, M.L.; Haynes, S.

    2012-07-01

    The U.S. Department of Energy (DOE) relies on laboratory experiments and computer-based models to verify the reliability of the nation's nuclear stockpile. Sandia National Laboratories/New Mexico (SNL/NM) tests various materials in extreme environments designed to mimic those of nuclear explosions using the Z machine. The Z machine is a key tool in the National Nuclear Security Administration's (NNSA) stockpile stewardship mission and is used to study the dynamic properties of nuclear weapon materials. In 2006, SNL/NM and Los Alamos National Laboratory (LANL) signed a Memorandum of Understanding (MOU) defining experiments to be conducted in the Z machine involving plutonium (Pu) provided by LANL. Five Pu experiments have been completed with as many as 20 more planned through 2016. The experimental containment vessel used for the experiment and containing the Pu residues, becomes transuranic (TRU) waste after the experiment and termination of safeguards and is considered a LANL waste stream. Each containment vessel is placed in a 55-gallon Type A drum or standard waste box (SWB) for shipment back to LANL for final certification and eventual disposal at the Waste Isolation Pilot Plant (WIPP). The experimental containment vessels are greater than 99% metallic materials (ferrous and non-ferrous metals). In addition to the Pu targets, detonators with high explosives (HE) are used in the experiments to isolate the containment vessel from the Z machine as energy is delivered to the Pu samples. The characterization requirements, transportation issues, required documentation, and the approvals needed before shipments were challenging and required close coordination between SNL/NM, Sandia Site Office, LANL, Los Alamos Site Office, Washington TRU Solutions, Inc., the Central Characterization Project, and the Carlsbad Field Office. Between 2006 and 2010, representatives from SNL/NM and LANL worked to develop an approved path forward to meet the requirements of all stakeholders

  16. 2015 Los Alamos Space Weather Summer School Research Reports

    SciTech Connect

    Cowee, Misa; Chen, Yuxi; Desai, Ravindra; Hassan, Ehab; Kalmoni, Nadine; Lin, Dong; Depascuale, Sebastian; Hughes, Randall Scott; Zhou, Hong

    2015-11-24

    The fifth Los Alamos Space Weather Summer School was held June 1st - July 24th, 2015, at Los Alamos National Laboratory (LANL). With renewed support from the Institute of Geophysics, Planetary Physics, and Signatures (IGPPS) and additional support from the National Aeronautics and Space Administration (NASA) and the Department of Energy (DOE) Office of Science, we hosted a new class of five students from various U.S. and foreign research institutions. The summer school curriculum includes a series of structured lectures as well as mentored research and practicum opportunities. Lecture topics including general and specialized topics in the field of space weather were given by a number of researchers affiliated with LANL. Students were given the opportunity to engage in research projects through a mentored practicum experience. Each student works with one or more LANL-affiliated mentors to execute a collaborative research project, typically linked with a larger ongoing research effort at LANL and/or the student’s PhD thesis research. This model provides a valuable learning experience for the student while developing the opportunity for future collaboration. This report includes a summary of the research efforts fostered and facilitated by the Space Weather Summer School. These reports should be viewed as work-in-progress as the short session typically only offers sufficient time for preliminary results. At the close of the summer school session, students present a summary of their research efforts. Titles of the papers included in this report are as follows: Full particle-in-cell (PIC) simulation of whistler wave generation, Hybrid simulations of the right-hand ion cyclotron anisotropy instability in a sub-Alfvénic plasma flow, A statistical ensemble for solar wind measurements, Observations and models of substorm injection dispersion patterns, Heavy ion effects on Kelvin-Helmholtz instability: hybrid study, Simulating plasmaspheric electron densities with a two

  17. Priorities and strategies, Los Alamos computer science institute.

    SciTech Connect

    Oldehoeft, R. R.

    2004-01-01

    On March 18-19, 2002 the Los Alamos Computer Science Institute (LACSI) Executive Committee and Principal Investigators met to discuss methods of addressing issues raised in the 2001 LACSI Contract Review. The body was tasked to develop priorities and strategies to meet future programmatic and LANL computer science needs. A framework was developed to address long-term strategic thrust areas. Specific objectives were called out as near-term priorities. The objectives were folded into the framework to form a coherent planning view. On both April 8-9, 2003 and February 19-20, 2004, the LACSI Executive Committee and Principal Investigators met with senior LANL personnel to revise the framework, priorities, and strategies established at the planning meeting in 2002. The current framework outlines five strategic thrust areas: Components, Systems, Computational Science, Application and System Performance, and Computer Science Community Interaction. This document presents the research vision and implementation strategy in each of these areas. The goal of the component architectures effort is to make application development easier through the use of modular codes that integrate powerful components at a high level of abstraction. Through modularization and the existence of well-defined component boundaries (specified by programming interfaces), components allow scientists and software developers to focus on a their own areas of expertise. For example, components and modern scripting languages enable physicists to program at a high level of abstraction (by composing off-the-shelf components into an application), leaving the development of components to expert programmers. In addition, because components foster a higher level of code reuse, components provide an increased economy of scale, making it possible for resources to be shifted to areas such as performance, testing, and platform dependencies, thus improving software quality, portability, and application performance. A

  18. Building an artificial intelligence capability at Los Alamos

    SciTech Connect

    Marinuzzi, J.G.

    1988-01-01

    In 1985, after three years of preliminary work, Management of the Los Alamos National Laboratory started an ambitious program to develop a strong technical capability in the rapidly emerging field of Artificial Intelligence/Knowledge Based Systems (AI/KBS). When this AI development program began, except for a few staff members doing basic AI research, AI was essentially nonexistent at the laboratory. The basics, including such things as AI computer hardware and software, literature, books, knowledgeable personnel, or even a general knowledge of what AI was, were most difficult if not impossible to find. For this reason, we had to approach the problem with a very broad perspective, which strongly addressed the basics while aiming toward more advanced AI program elements. Broad, intensive education was the ''bootstrapping'' tool used in this five year, multi-million dollar AI capability development program. Halfway through the program, our accomplishments indicate that the program is extremely successful. In terms of trained staff, active programs and ''state-of-the-art equipment,'' we have developed one of the strongest AI technical capabilities within the Department of Energy (DOE) and the Department of Defense(DOD). However, a great deal more must be done before the full potential of the program can be realized. 1 fig.

  19. Response of `Alamo` switchgrass (Panicum virgatum) to weed management practices

    SciTech Connect

    Sledge, S.L.; Walker, R.H.

    1995-11-01

    Field studies were conducted in 1992 and 1994 to evaluate herbicides that would provide weed control and biomass yield of `Alamo` switchgrass during the year of establishment. For grass weed control, bensulide was applied preplant incorporated (PPI) at 4.4 kg ai ha{sup -1}, while MSMA was applied postemergence over the top (POST) at 2.2 kg ai ha{sup -1} to switchgrass that had two to four leaves. Herbicides applied POST for control of broadleaf weed species included 2,4-D at 0.6 kg ai ha{sup -1} or metsulfuron at 0.02 kg ai ha{sup -1}. Herbicide treatments included bensulide and MSMA applied alone or in combination with s,3-D or metsulfuron. They were arranged in a randomized complete block design and replicated four times. Weed control, crop tolerance and yield data were taken over time. Bensulide or MSMA applied alone provided 80% or greater control of large crabgrass, broadleaf signalgrass and fall panicum for the two years. The addition of metsulfuron or 2,4-D provided acceptable control of smooth pigweed, prickly sida, pitted morningglory and sicklepod. MSMA treatments produced slight PANVI injury that ranged from 20 to 36%. Bensulide injury was mostly moderate ranging from 19 to 88%. Although less injury was recorded with MSMA treatments, bensulide treatments trended higher for establishment-year biomass production that averaged 5123 kg ha{sup -1} as compared to 4239 kg ha{sup -1} for MSMA treatments.

  20. Electron clearing in the Los Alamos Proton Storage Ring

    SciTech Connect

    Plum, M.A.; Allen, J.; Borden, M.J.; Fitzgerald, D.H.; Macek, R.J.; Wang, T.S.

    1995-05-01

    The instability observed in the Los Alamos Proton Storage Ring (PSR) has been tentatively identified as an electron-proton instability. A source of electrons must exist for this instability to occur. The PSR injection section contains the stripper foil, and therefore provides several strong sources of electrons. An electron clearing system was installed in the injection section to clear out these electrons. The system comprised: (1) a foil biasing system to clear the SEM and thermionic electrons, (2) a pair of low-field bending magnets with a Faraday cup to clear the convoy electrons, and (3) two pairs of clearing electrodes, one upstream and one downstream of the stripper foil, to clear the remaining electrons. This paper discusses the design and performance of the Electron Clearing System, and its effect on the instability. Also presented are some results from other charge-collection experiments that suggest there is also substantial electron production in parts of the ring other than the injection section.

  1. Carbon stripper foils used in the Los Alamos PSR

    SciTech Connect

    Borden, M.J.; Plum, M.A.; Sugai, I.

    1997-12-01

    Carbon stripper foils produced by the modified controlled ACDC arc discharge method (mCADAD) at the Institute for Nuclear Study have been tested and used for high current 800-MeV beam production in the Proton Storage Ring (PSR) since 1993. Two foils approximately 110 {mu}g/cm{sup 2} each are sandwiched together to produce an equivalent 220 {mu}g/cm{sup 2} foil. The foil sandwitch is supported by 4-5 {mu}m diameter carbon filters attached to an aluminum frame. These foils have survived as long as five months during PSR normal beam production of near 70 {mu}A average current on target. Typical life-times of other foils vary from seven to fourteen days with lower on-target average current. Beam loss data also indicate that these foils have slower shrinkage rates than standard foils. Equipment has been assembled and used to produce foils by the mCADAD method at Los Alamos. These foils will be tested during 1997 operation.

  2. Integrated sequence and immunology filovirus database at Los Alamos.

    PubMed

    Yusim, Karina; Yoon, Hyejin; Foley, Brian; Feng, Shihai; Macke, Jennifer; Dimitrijevic, Mira; Abfalterer, Werner; Szinger, James; Fischer, Will; Kuiken, Carla; Korber, Bette

    2016-01-01

    The Ebola outbreak of 2013-15 infected more than 28 000 people and claimed more lives than all previous filovirus outbreaks combined. Governmental agencies, clinical teams, and the world scientific community pulled together in a multifaceted response ranging from prevention and disease control, to evaluating vaccines and therapeutics in human trials. As this epidemic is finally coming to a close, refocusing on long-term prevention strategies becomes paramount. Given the very real threat of future filovirus outbreaks, and the inherent uncertainty of the next outbreak virus and geographic location, it is prudent to consider the extent and implications of known natural diversity in advancing vaccines and therapeutic approaches. To facilitate such consideration, we have updated and enhanced the content of the filovirus portion of Los Alamos Hemorrhagic Fever Viruses Database. We have integrated and performed baseline analysis of all family ITALIC! Filoviridaesequences deposited into GenBank, with associated immune response data, and metadata, and we have added new computational tools with web-interfaces to assist users with analysis. Here, we (i) describe the main features of updated database, (ii) provide integrated views and some basic analyses summarizing evolutionary patterns as they relate to geo-temporal data captured in the database and (iii) highlight the most conserved regions in the proteome that may be useful for a T cell vaccine strategy.Database URL:www.hfv.lanl.gov. PMID:27103629

  3. World's Largest Gold Crystal Studied at Los Alamos

    SciTech Connect

    Vogel, Sven; Nakotte, Heinz

    2014-04-03

    When geologist John Rakovan needed better tools to investigate whether a dazzling 217.78-gram piece of gold was in fact the world's largest single-crystal specimen - a distinguishing factor that would not only drastically increase its market value but also provide a unique research opportunity - he traveled to Los Alamos National Laboratory's Lujan Neutron Scattering Center to peer deep inside the mineral using neutron diffractometry. Neutrons, different from other probes such as X-rays and electrons, are able to penetrate many centimeters deep into most materials. Revealing the inner structure of a crystal without destroying the sample - imperative, as this one is worth an estimated $1.5 million - would allow Rakovan and Lujan Center collaborators Sven Vogel and Heinz Nakotte to prove that this exquisite nugget, which seemed almost too perfect and too big to be real, was a single crystal and hence a creation of nature. Its owner, who lives in the United States, provided the samples to Rakovan to assess the crystallinity of four specimens, all of which had been found decades ago in Venezuela.

  4. Los Alamos Neutron Science Center (LANSCE) accelerator timing system upgrade

    SciTech Connect

    Rybarcyk, L.J.; Shelley, F.E. Jr.

    1997-10-01

    The Los Alamos Neutron Science Center (LANSCE) 800 MeV proton linear accelerator (linac) operates at a maximum repetition rate of twice the AC power line frequency, i.e. 120 Hz. The start of each machine cycle occurs a fixed delay after each zero-crossing of the AC line voltage. Fluctuations in the AC line frequency and phase are therefore present on all linac timing signals. Proper beam acceleration along the linac requires that the timing signals remain well synchronized to the AC line. For neutron chopper spectrometers, e.g., PHAROS at the Manuel Lujan Jr. Neutron Scattering Center, accurate neutron energy selection requires that precise synchronization be maintained between the beam-on-target arrival time and the neutron chopper rotor position. This is most easily accomplished when the chopper is synchronized to a stable, fixed frequency signal. A new zero-crossing circuit which employs a Phase-Locked Loop (PLL) has been developed to increase the phase and frequency stability of the linac timing signals and thereby improve neutron chopper performance while simultaneously maintaining proper linac operation. Results of timing signal data analysis and modeling and a description of the PLL circuit are presented.

  5. Atomic Structure Calculations from the Los Alamos Atomic Physics Codes

    DOE Data Explorer

    Cowan, R. D.

    The well known Hartree-Fock method of R.D. Cowan, developed at Los Alamos National Laboratory, is used for the atomic structure calculations. Electron impact excitation cross sections are calculated using either the distorted wave approximation (DWA) or the first order many body theory (FOMBT). Electron impact ionization cross sections can be calculated using the scaled hydrogenic method developed by Sampson and co-workers, the binary encounter method or the distorted wave method. Photoionization cross sections and, where appropriate, autoionizations are also calculated. Original manuals for the atomic structure code, the collisional excitation code, and the ionization code, are available from this website. Using the specialized interface, you will be able to define the ionization stage of an element and pick the initial and final configurations. You will be led through a series of web pages ending with a display of results in the form of cross sections, collision strengths or rates coefficients. Results are available in tabular and graphic form.

  6. HELIOSEISMIC TESTS OF THE NEW LOS ALAMOS OPACITIES

    SciTech Connect

    J. GUZIK; ET AL

    2001-01-01

    We compare the helioseismic properties of two solar models, one calibrated with the OPAL opacities and the other with the recent Los Alamos LEDCOP opacities. We show that, in the radiative interior of the Sun, the small differences between the two sets of opacities (up to 6% near the base of the convection zone) lead to noticeable differences in the solar structure (up to 0.4% in sound speed), with the OPAL model being the closest to the helioseismic data. More than half of the difference between the two opacity sets results from the interpolation scheme and from the relatively widely spaced temperature grids used in the tables. The remaining 3% intrinsic difference between the OPAL and the LEDCOP opacities in the radiative interior of the Sun is well within the error bars on the opacity calculations resulting from the uncertainties on the physics. We conclude that the OPAL and LEDCOP opacity sets do about as well in the radiative interior of the Sun.

  7. Organizational cultural survey of the Los Alamos Site

    SciTech Connect

    Not Available

    1991-11-01

    An Organizational Survey (OS) was administered at the Los Alamos Site that queried employees on the subjects of organizational culture, various aspects of communications, employee commitment, work group cohesion, coordination of work, environmental, safety, and health concerns, hazardous nature of work, safety and overall job satisfaction. The purpose of the OS is to measure in a quantitative and objective way the notion of culture;'' that is, the values, attitudes, and beliefs of the individuals working within the organization. In addition, through the OS, a broad sample of individuals can be reached that would probably not be interviewed or observed during the course of a typical assessment. The OS also provides a descriptive profile of the organization at one point in time that can then be compared to a profile taken at a different point in time to assess changes in the culture of the organization. While comparisons among groups are made, it is not the purpose of this report to make evaluative statements of which profile may be positive or negative. However, using the data presented in this report in conjunction with other evaluative activities, may provide useful insight into the organization.

  8. Organizational cultural survey of the Los Alamos Site

    SciTech Connect

    Not Available

    1991-11-01

    An Organizational Survey (OS) was administered at the Los Alamos Site that queried employees on the subjects of organizational culture, various aspects of communications, employee commitment, work group cohesion, coordination of work, environmental, safety, and health concerns, hazardous nature of work, safety and overall job satisfaction. The purpose of the OS is to measure in a quantitative and objective way the notion of ``culture;`` that is, the values, attitudes, and beliefs of the individuals working within the organization. In addition, through the OS, a broad sample of individuals can be reached that would probably not be interviewed or observed during the course of a typical assessment. The OS also provides a descriptive profile of the organization at one point in time that can then be compared to a profile taken at a different point in time to assess changes in the culture of the organization. While comparisons among groups are made, it is not the purpose of this report to make evaluative statements of which profile may be positive or negative. However, using the data presented in this report in conjunction with other evaluative activities, may provide useful insight into the organization.

  9. Los Alamos Shows Airport Security Technology at Work

    SciTech Connect

    Espy, Michelle; Schultz, Larry; Hunter, James

    2013-11-25

    Los Alamos scientists have advanced a Magnetic Resonance Imaging (MRI) technology that may provide a breakthrough for screening liquids at airport security. They've added low-power X-ray data to the mix, and as a result have unlocked a new detection technology. Funded in part by the Department of Homeland Security's Science and Technology Directorate, the new system is named MagRay. The goal is to quickly and accurately distinguish between liquids that visually appear identical. For example, what appears to be a bottle of white wine could potentially be nitromethane, a liquid that could be used to make an explosive. Both are clear liquids, one would be perfectly safe on a commercial aircraft, the other would be strictly prohibited. How to tell them apart quickly without error at an airport security area is the focus of Michelle Espy, Larry Schultz and their team. In this video, Espy and the MagRay team explain how the new technology works, how they've developed an easy operator interface, and what the next steps might be in transitioning this technology to the private sector.

  10. Integrated sequence and immunology filovirus database at Los Alamos

    PubMed Central

    Yoon, Hyejin; Foley, Brian; Feng, Shihai; Macke, Jennifer; Dimitrijevic, Mira; Abfalterer, Werner; Szinger, James; Fischer, Will; Kuiken, Carla; Korber, Bette

    2016-01-01

    The Ebola outbreak of 2013–15 infected more than 28 000 people and claimed more lives than all previous filovirus outbreaks combined. Governmental agencies, clinical teams, and the world scientific community pulled together in a multifaceted response ranging from prevention and disease control, to evaluating vaccines and therapeutics in human trials. As this epidemic is finally coming to a close, refocusing on long-term prevention strategies becomes paramount. Given the very real threat of future filovirus outbreaks, and the inherent uncertainty of the next outbreak virus and geographic location, it is prudent to consider the extent and implications of known natural diversity in advancing vaccines and therapeutic approaches. To facilitate such consideration, we have updated and enhanced the content of the filovirus portion of Los Alamos Hemorrhagic Fever Viruses Database. We have integrated and performed baseline analysis of all family Filoviridae sequences deposited into GenBank, with associated immune response data, and metadata, and we have added new computational tools with web-interfaces to assist users with analysis. Here, we (i) describe the main features of updated database, (ii) provide integrated views and some basic analyses summarizing evolutionary patterns as they relate to geo-temporal data captured in the database and (iii) highlight the most conserved regions in the proteome that may be useful for a T cell vaccine strategy. Database URL: www.hfv.lanl.gov PMID:27103629

  11. Los Alamos Shows Airport Security Technology at Work

    ScienceCinema

    Espy, Michelle; Schultz, Larry; Hunter, James

    2016-07-12

    Los Alamos scientists have advanced a Magnetic Resonance Imaging (MRI) technology that may provide a breakthrough for screening liquids at airport security. They've added low-power X-ray data to the mix, and as a result have unlocked a new detection technology. Funded in part by the Department of Homeland Security's Science and Technology Directorate, the new system is named MagRay. The goal is to quickly and accurately distinguish between liquids that visually appear identical. For example, what appears to be a bottle of white wine could potentially be nitromethane, a liquid that could be used to make an explosive. Both are clear liquids, one would be perfectly safe on a commercial aircraft, the other would be strictly prohibited. How to tell them apart quickly without error at an airport security area is the focus of Michelle Espy, Larry Schultz and their team. In this video, Espy and the MagRay team explain how the new technology works, how they've developed an easy operator interface, and what the next steps might be in transitioning this technology to the private sector.

  12. Final Progress Report: Internship at Los Alamos National Laboratory

    SciTech Connect

    Dunham, Ryan Q.

    2012-08-10

    Originally I was tasked fluidized bed modeling, however, I changed projects. While still working with ANSYS Fluent, I performed a study of particle tracks in glove boxes. This is useful from a Health-Physics perspective, dealing respirable particles that can be hazardous to the human body. I iteratively tested different amounts of turbulent particles in a steady-state flow. The goal of this testing was to discover how Fluent handles built-in Rosin-Rammler distributions for particle injections. I worked on the health physics flow problems and distribution analysis under the direction of two mentors, Bruce Letellier and Dave Decroix. I set up and ran particle injection calculations using Fluent. I tried different combinations of input parameters to produce sets of 500,000, 1 million, and 1.5 million particles to determine what a good test case would be for future experiments. I performed a variety of tasks in my work as an Undergraduate Student Intern at LANL this summer, and learned how to use a powerful CFD application in addition to expanding my skills in MATLAB. I enjoyed my work at LANL and hope to be able to use the experience here to further my career in the future working in a security-conscious environment. My mentors provided guidance and help with all of my projects and I am grateful for the opportunity to work at Los Alamos National Laboratory.

  13. ACCELERATION OF LOS ALAMOS NATIONAL LABORATORY TRANSURANIC WASTE DISPOSITION

    SciTech Connect

    O'LEARY, GERALD A.

    2007-01-04

    One of Los Alamos National Laboratory's (LANL's) most significant risks is the site's inventory of transuranic waste retrievably stored above and below-ground in Technical Area (TA) 54 Area G, particularly the dispersible high-activity waste stored above-ground in deteriorating facilities. The high activity waste represents approximately 50% (by activity) of the total 292,000 PE-Ci inventory remaining to be disposed. The transuramic waste inventory includes contact-handled and remote-handled waste packaged in drums, boxes, and oversized containers which are retrievably stored both above and below-ground. Although currently managed as transuranic waste, some of the inventory is low-level waste that can be disposed onsite or at approved offsite facilities. Dispositioning the transuranic waste inventory requires retrieval of the containers from above and below-ground storage, examination and repackaging or remediation as necessary, characterization, certification and loading for shipment to the Waste Isolation Pilot Plant in Carlsbad New Mexico, all in accordance with well-defined requirements and controls. Although operations are established to process and characterize the lower-activity contact-handled transuranic waste containers, LAN L does not currently have the capability to repack high activity contact-handled transuranic waste containers (> 56 PE-Ci) or to process oversized containers with activity levels over 0.52 PE-Ci. Operational issues and compliance requirements have resulted in less than optimal processing capabilities for lower activity contact-handled transuranic waste containers, limiting preparation and reducing dependability of shipments to the Waste Isolation Pilot Plant. Since becoming the Los Alamos National Laboratory contract in June 2006, Los Alamos National Security (LANS) L.L.C. has developed a comprehensive, integrated plan to effectively and efficiently disposition the transuranic waste inventory, working in concert with the Department of

  14. World's Largest Gold Crystal Studied at Los Alamos

    ScienceCinema

    Vogel, Sven; Nakotte, Heinz

    2016-07-12

    When geologist John Rakovan needed better tools to investigate whether a dazzling 217.78-gram piece of gold was in fact the world's largest single-crystal specimen - a distinguishing factor that would not only drastically increase its market value but also provide a unique research opportunity - he traveled to Los Alamos National Laboratory's Lujan Neutron Scattering Center to peer deep inside the mineral using neutron diffractometry. Neutrons, different from other probes such as X-rays and electrons, are able to penetrate many centimeters deep into most materials. Revealing the inner structure of a crystal without destroying the sample - imperative, as this one is worth an estimated $1.5 million - would allow Rakovan and Lujan Center collaborators Sven Vogel and Heinz Nakotte to prove that this exquisite nugget, which seemed almost too perfect and too big to be real, was a single crystal and hence a creation of nature. Its owner, who lives in the United States, provided the samples to Rakovan to assess the crystallinity of four specimens, all of which had been found decades ago in Venezuela.

  15. Chemical decontamination technical resources at Los Alamos National Laboratory (2008)

    SciTech Connect

    Moore, Murray E

    2008-01-01

    This document supplies information resources for a person seeking to create planning or pre-planning documents for chemical decontamination operations. A building decontamination plan can be separated into four different sections: Pre-planning, Characterization, Decontamination (Initial response and also complete cleanup), and Clearance. Of the identified Los Alamos resources, they can be matched with these four sections: Pre-planning -- Dave Seidel, EO-EPP, Emergency Planning and Preparedness; David DeCroix and Bruce Letellier, D-3, Computational fluids modeling of structures; Murray E. Moore, RP-2, Aerosol sampling and ventilation engineering. Characterization (this can include development projects) -- Beth Perry, IAT-3, Nuclear Counterterrorism Response (SNIPER database); Fernando Garzon, MPA-11, Sensors and Electrochemical Devices (development); George Havrilla, C-CDE, Chemical Diagnostics and Engineering; Kristen McCabe, B-7, Biosecurity and Public Health. Decontamination -- Adam Stively, EO-ER, Emergency Response; Dina Matz, IHS-IP, Industrial hygiene; Don Hickmott, EES-6, Chemical cleanup. Clearance (validation) -- Larry Ticknor, CCS-6, Statistical Sciences.

  16. Radiometric sources for the Los Alamos National Laboratory calibration Laboratory

    SciTech Connect

    Maier, W.B. II; Holland, R.; Bender, S.; Byrd, D.; Michaud, F.D.; Moore, S.; O`Brian, T.R.

    1994-07-01

    Los Alamos is developing a laboratory that will support state of the art calibration of moderate-aperture instrumentation (< 40 cm diameter) having high spatial and thermal resolution. Highly accurate calibration in the reflected solar and thermal infrared spectral regions are required for newly developed instrumentation. Radiometric calibration of the instrumentation requires well-characterized, extensive sources of radiation from 0.45 to 12 {mu}m. For wavelengths above 2.5 {mu}m, blackbodies having temperature control and radiometric uniformity to within 100 mK are being designed and will be radiometrically characterized at the National Institute of Standards and Technology (NIST). For the spectral range 0.45--2.5 {mu}m, a ``whitebody`` integrating sphere equipped with tungsten-halogen lamps and enclosed inside a vacuum shroud will be used; this vacuum-compatible extensive standard diffuse source utilizes well-known technology and will be characterized at NIST`s existing facilities. Characterization of instrumental contrast performance for wavelengths, {lambda}, beyond 2.5 {mu}m will utilize a recently designed absolute variable-contrast IR radiometric calibrator, and preliminary data indicate that this calibrator will perform satisfactorily. Conceptual design and status of these extensive broad-band sources and of a monochromatic source to be used for spectral calibrations will be presented.

  17. New Mexicans` perceptions of Los Alamos National Laboratory. Final report

    SciTech Connect

    1994-09-01

    Since May, 1990, the Institute for Public Policy (IPP) has published Quarterly Profiles (QPs) of New Mexico`s citizenry. Each QP has focused on a different issue, but they have all asked a set of standard items, including questions about the public`s perceptions of the Los Alamos National Laboratories (LANL). Each year, the IPP has used the University of New Mexico`s Survey Research Center to conduct a telephone survey of a representative random sample of New Mexicans, and respondents were asked whether they had favorable or unfavorable views of LANL and the degree to which they perceived LANL as an environmentally responsible institution. As a result of this sustained research effort, the IPP now has a collection of fifteen consecutive QPs. With an aggregate sample size of over 8800, we are now able to make precise statistical inferences with greater confidence than was possible when using individual QP samples. Such an extremely large sample mitigates two kinds of common survey research problems.

  18. Wildlife use of NPDES outfalls at Los Alamos National Laboratory

    SciTech Connect

    Foxx, T.; Blea-Edeskuty, B.

    1995-09-01

    From July through October of 1991, the Biological Resources Evaluation Team (BRET) surveyed 133 of the 140 National Pollutant Discharge and Elimination System outfalls at Los Alamos National Laboratory (LANL). The purpose of the survey was to determine the use of these wastewater outfalls by wildlife. BRET observed wildlife or evidence of wildlife (scat, tracks, or bedding) by 35 vertebrate species in the vicinity of the outfalls, suggesting these animals could be using water from outfalls. Approximately 56% of the outfalls are probably used or are suitable for use by large mammals as sources of drinking water. Additionally, hydrophytic vegetation grows in association with approximately 40% of the outfalls-a characteristic that could make these areas eligible for wetland status. BRET recommends further study to accurately characterize the use of outfalls by small and medium-sized mammals and amphibians. The team also recommends systematic aquatic macroinvertebrate studies to provide information on resident communities and water quality. Wetland assessments may be necessary to ensure compliance with wetland regulations if LANL activities affect any of the outfalls supporting hydrophytic vegetation.

  19. Population Files for use with CAP88 at Los Alamos

    SciTech Connect

    McNaughton, Michael W; Brock, Burgandy R

    2012-07-10

    CAP88 (Clean Air Act Assessment Package 1988) is a computer model developed for the US Environmental Protection Agency to assess the potential dose from radionuclide emissions to air and to demonstrate compliance with the Clean Air Act. It has options to calculate either individual doses, in units of mrem, or a collective dose, also called population dose, in units of person-rem. To calculate the collective dose, CAP88 uses a population file such as LANL.pop, that lists the number of people in each sector (N, NNE, NE, etc.) as a function of distance (1 to 2 km, etc.) out to a maximum radius of 80 km. Early population files are described in the Los Alamos National Laboratory (LANL) Environmental Reports for 1985 (page 14) and subsequent years. LA-13469-MS describes a population file based on the 1990 census. These files have been updated several times, most recently in 2006 for CAP88 version 3. The 2006 version used the US census for 2000. The present paper describes the 2012 updates, using the 2010 census.

  20. Los Alamos National Laboratory compliance with cultural resource management legislation

    SciTech Connect

    Olinger, C.E.; Rea, K.H.

    1984-01-01

    Cultural resources management is one aspect of NEPA-induced legislation increasingly affecting federal land managers. A number of regulations, some of them recent, outline management criteria for protecting cultural resources on federal land. Nearly all construction projects at the 11,135 hectare Los Alamos National Laboratory in northern New Mexico are affected by cultural resource management requirements. A substantial prehistoric Puebloan population occupied the Laboratory area from the 13th to the early 16th centuries. Grazing, timbering, and homesteading followed Indian occupation. Therefore, archaeological and historical ruins and artifacts are abundant. The Laboratory has developed a cultural resources management program which meets both legal and project planning requirements. The program operates in coordination with the New Mexico State Historical Preservation Office. Major elements of the Laboratory program are illustrated by a current project involving relocation of a homesteader's cabin located on land required for a major new facility. The Laboratory cultural resource management program couples routine oversight of all engineering design projects with onsite resource surveys and necessary mitigation prior to construction. The Laboratory has successfully protected major archaeological and historical ruins, although some problems remain. The cultural resource program is intended to be adjustable to new needs. A cultural resource management plan will provide long-term management guidance.

  1. Factors affecting radionuclide availability to vegetables grown at Los Alamos

    SciTech Connect

    White, G.C.; Hakonson, T.E.; Ahlquist, A.J.

    1981-07-01

    A field study was conducted in 1977 on /sup 238/ /sup 239/Pu and /sup 137/Cs availability to zucchini squash (Curcurbita melopepo, hybrid seneca) and green bush beans (Phaseolus vulgaris, Landreths stringless) grown under home-garden conditions in an area at Los Alamos National Laboratory used for treated radioactive liquid waste disposal. Radionuclide concentrations were measured as a function of tissue type, height above the soil, fertilization regime, and for the squash, food-cleansing procedures. Analysis of variance procedures was used to analyze the data. Ratios of the concentration of a radionuclide in oven-dried vegetation to dry soil ranged from 0.0004 to 0.116 for the Pu isotopes, and from 0.051 to 0.255 for /sup 137/Cs. Fertilization with cattle manure reduced the Pu concentration ratios by 30% and /sup 137/Cs by 50%. Vegetative parts sampled within 20 cm of the ground surface were contaminated about four times as much as those parts growing further from the ground surface. About 65% of the contamination was removed by washing, indicating the presence of surficial contamination. The 50-year radiation dose commitment to humans consuming vegetables from the garden plot would be less than 0.05 mrem and would be due almost entirely to /sup 137/Cs.

  2. Integrated sequence and immunology filovirus database at Los Alamos

    SciTech Connect

    Yusim, Karina; Yoon, Hyejin; Foley, Brian; Feng, Shihai; Macke, Jennifer; Dimitrijevic, Mira; Abfalterer, Werner; Szinger, James; Fischer, Will; Kuiken, Carla; Korber, Bette

    2016-01-01

    The Ebola outbreak of 2013–15 infected more than 28,000 people and claimed more lives than all previous filovirus outbreaks combined. Governmental agencies, clinical teams, and the world scientific community pulled together in a multifaceted response ranging from prevention and disease control, to evaluating vaccines and therapeutics in human trials. We report that as this epidemic is finally coming to a close, refocusing on long-term prevention strategies becomes paramount. Given the very real threat of future filovirus outbreaks, and the inherent uncertainty of the next outbreak virus and geographic location, it is prudent to consider the extent and implications of known natural diversity in advancing vaccines and therapeutic approaches. To facilitate such consideration, we have updated and enhanced the content of the filovirus portion of Los Alamos Hemorrhagic Fever Viruses Database. We have integrated and performed baseline analysis of all family Filoviridae sequences deposited into GenBank, with associated immune response data, and metadata, and we have added new computational tools with web-interfaces to assist users with analysis. Here, we (i) describe the main features of updated database, (ii) provide integrated views and some basic analyses summarizing evolutionary patterns as they relate to geo-temporal data captured in the database and (iii) highlight the most conserved regions in the proteome that may be useful for a T cell vaccine strategy.

  3. Integrated sequence and immunology filovirus database at Los Alamos

    DOE PAGES

    Yusim, Karina; Yoon, Hyejin; Foley, Brian; Feng, Shihai; Macke, Jennifer; Dimitrijevic, Mira; Abfalterer, Werner; Szinger, James; Fischer, Will; Kuiken, Carla; et al

    2016-01-01

    The Ebola outbreak of 2013–15 infected more than 28,000 people and claimed more lives than all previous filovirus outbreaks combined. Governmental agencies, clinical teams, and the world scientific community pulled together in a multifaceted response ranging from prevention and disease control, to evaluating vaccines and therapeutics in human trials. We report that as this epidemic is finally coming to a close, refocusing on long-term prevention strategies becomes paramount. Given the very real threat of future filovirus outbreaks, and the inherent uncertainty of the next outbreak virus and geographic location, it is prudent to consider the extent and implications of knownmore » natural diversity in advancing vaccines and therapeutic approaches. To facilitate such consideration, we have updated and enhanced the content of the filovirus portion of Los Alamos Hemorrhagic Fever Viruses Database. We have integrated and performed baseline analysis of all family Filoviridae sequences deposited into GenBank, with associated immune response data, and metadata, and we have added new computational tools with web-interfaces to assist users with analysis. Here, we (i) describe the main features of updated database, (ii) provide integrated views and some basic analyses summarizing evolutionary patterns as they relate to geo-temporal data captured in the database and (iii) highlight the most conserved regions in the proteome that may be useful for a T cell vaccine strategy.« less

  4. Explorer at Los Alamos: A library for the future

    SciTech Connect

    Waters, M.; McDonald, J.

    1998-03-01

    Since 1993, Los Alamos National Laboratory, has been developing World Wide Web (WWW) applications to facilitate access to vast quantities of information critical to the successful operation of a nuclear weapons facility Explorer is a web-based tool that integrates full-text search and retrieval technology, custom user in interface faces, user-friendly navigation tools, extremely large document collections, and data collection and workflow applications. Explorer`s first major thrust was to enable quick access to regulatory and policy information used by Department of Energy facilities throughout the country. Today, Explorer users can easily search document collections containing, millions of pages of information scattered across Web sites around the country. Over fifteen large applications containing multiple collections are searchable through Explorer, and the subject areas range from DOE regulations to quality management-related resources to technology transfer opportunities. Explorer has succeeded because it provides quick and easy access to stored data across the Web; it saves time and reduces costs in comparison with traditional information distribution, access, and retrieval methods.

  5. The Los Alamos National Laboratory Transuranic Waste Retireval Project

    SciTech Connect

    Montoya, G.M.; Christensen, D.V.; Stanford, A.R.

    1997-02-01

    This paper presents the status of the Los Alamos National Laboratory (LANL) project for remediation of transuranic (TRU) and TRU mixed waste from Pads 1, 2, and 4. Some of the TRU waste packages retrieved from Pad I are anticipated to be part of LANL`s initial inventory to be shipped to the Waste Isolation Pilot Plant (WIPP) in April 1998. The TRU Waste Inspectable Storage Project (TWISP) was initiated in February 1993 in response to the New Mexico Environment Department`s (NMED`s) Consent Agreement for Compliance Order, ``New Mexico Hazardous Waste Agreement (NMHWA) 93-03.`` The TWISP involves the recovery of approximately 16,865 TRU and TRU-mixed waste containers currently under earthen cover on Pads 1, 2, and 4 at Technical Area 54, Area G, and placement of that waste into inspectable storage. All waste will be moved into inspectable storage by September 30, 2003. Waste recovery and storage operations emphasize protection of worker safety, public health, and the environment.

  6. Los Alamos National Laboratory 1995 self assessment report

    SciTech Connect

    1995-06-30

    The Los Alamos National Laboratory (LANL) Safeguards and Security (S and S) Assurance Program (AP) is designed to ensure the adequacy and effectiveness of the LANL S and S program. The Assurance Program provides a mechanism for discovering deficiencies, determining causes, conducting risk assessments, implementing corrective actions, and documenting the assessment process. Selection of organizations for self assessments is based on the criteria established in the LANL S and S Assurance Program. For FY 1995, 12 organizations were selected for self assessments, these organizations are identified fin the schedule at Appendix A. The S and S topical areas selected for review in each organization varied depending on their security interests and included: Program Planning and Management (PPM); Protection Program Operations (PPO); Material Control and Accountability (MC and A); Computer and Communications Security (COMPSEC and COMSEC); Information Security (INFOSEC); Personnel Security (PERSEC); and Operational Security (OPSEC). The objective was to ascertain the effectiveness of S and S programs in each organization, its formality of operations, and its integration with the overall Laboratory S and S program. The goal was to meet both the DOE self-assessment requirements and the UC performance criteria and document the results.

  7. Environmental Assessment for the Installation and Operation of Combustion Turbine Generators at Los Alamos National Laboratory, Los Alamos, New Mexico

    SciTech Connect

    N /A

    2002-12-12

    NEPA requires Federal agency officials to consider the environmental consequences of their proposed actions before decisions are made. In complying with NEPA, the U.S. DOE, NNSA, follows the Council on Environmental Quality regulations (40 Code of Federal Regulations [CFR] 1500-1508) and DOE's NEPA implementing procedures (10 CFR 1021). The purpose of an environmental assessment (EA) is to provide Federal decision makers with sufficient evidence and analysis to determine whether to prepare an environmental impact statement (EIS) or issue a Finding of No Significant Impact (FONSI). At this time, the NNSA must make a decision regarding installing, operating and maintaining two approximately 20 Megawatt (MW) combustion turbine generators (CTGs) within the Technical Area (TA)-3 Co-generation Complex (Building 3-22) at Los Alamos National Laboratory (LANL). LANL is a Federal facility located at Los Alamos, New Mexico, that comprises 43 square miles (111 square kilometers) of buildings, structures, and forested land (Figure 1). LANL is administered by NNSA for the Federal government and managed and operated under contract by the University of California (UC). This EA has been prepared to assess the potential environmental consequences of the Proposed Action--installing and operating two CTGs--and of the No Action Alternative. The objectives of this EA are to (1) describe the underlying purpose and need for DOE action; (2) describe the Proposed Action and identify and describe any reasonable alternatives that satisfy the purpose and need for Agency Action; (3) describe baseline environmental conditions at LANL; (4) analyze the potential indirect, direct, and cumulative effects to the existing environment from implementation of the Proposed Action; and (5) compare the effects of the Proposed Action with the effects of the No Action Alternative and other reasonable alternatives. For the purposes of compliance with NEPA, reasonable alternatives are identified as being those

  8. Environmental assessment for the proposed CMR Building upgrades at the Los Alamos National Laboratory, Los Alamos, New Mexico. Final document

    SciTech Connect

    1997-02-04

    In order to maintain its ability to continue to conduct uninterrupted radioactive and metallurgical research in a safe, secure, and environmentally sound manner, the US Department of Energy (DOE) proposes to upgrade the Los Alamos National Laboratory (LANL) Chemistry and Metallurgy Research (CMR) Building. The building was built in the early 1950s to provide a research and experimental facility for analytical chemistry, plutonium and uranium chemistry, and metallurgy. Today, research and development activities are performed involving nuclear materials. A variety of radioactive and chemical hazards are present. The CMR Building is nearing the end of its original design life and does not meet many of today`s design codes and standards. The Proposed Action for this Environmental Assessment (EA) includes structural modifications to some portions of the CMR Building which do not meet current seismic criteria for a Hazard Category 2 Facility. Also included are upgrades and improvements in building ventilation, communications, monitoring, and fire protection systems. This EA analyzes the environmental effects of construction of the proposed upgrades. The Proposed Action will have no adverse effects upon agricultural and cultural resources, wetlands and floodplains, endangered and threatened species, recreational resources, or water resources. The Proposed Action would have negligible effects on human health and transportation, and would not pose a disproportionate adverse health or environmental impact on minority or low-income populations within an 80 kilometer (50 mile) radius of the CMR Building.

  9. Geology and physical properties of the near-surface rocks of Mesita de los Alamos, Los Alamos County, New Mexico

    USGS Publications Warehouse

    Purtymun, W.D.

    1967-01-01

    The surface of Mesita de los Alamos is formed by units 2b and 3 of the Tshirege Member of the Bandelier Tuff. These units dip gently east-southeastward at 3 to 6 degrees. The units are faulted near the center of the mesa by a north-south trending normal strike slip fault, that is downthrown about 14 feet to the east. The units east of the fault have moved about 14 feet south relative to the units on the west side of the fault. Units 2b and 3 have bulk density values ranging from 80 to 120 pounds per cubic foot. The moisture content of the tuff below the soil zone and near surface tuff was less than 5 percent by volume in five of the 25 test holes drilled during a foundation investigation for the Meson Facility. The temperature of the tuff in the bottom of three test holes (depth 16 to 43 feet) varied from 50?F to 54?F. Temperature variations were a function of density and amount of solar radiation.

  10. Nano structure zinc (II) Schiff base complexes of a N3-tridentate ligand as new biological active agents: spectral, thermal behaviors and crystal structure of zinc azide complex.

    PubMed

    Montazerozohori, M; Mojahedi Jahromi, S; Masoudiasl, A; McArdle, P

    2015-03-01

    In this work, synthesis of some new five coordinated zinc halide/pseudo-halide complexes of a N3-tridentate ligand is presented. All complexes were subjected to spectroscopic and physical methods such as FT-IR, UV-visible, (1)H and (13)C NMR spectra, thermal analyses and conductivity measurements for identification. Based on spectral data, the general formula of ZnLX2 (X=Cl(-), Br(-), I(-), SCN(-) and N3(-)) was proposed for the zinc complexes. Zinc complexes have been also prepared in nano-structure sizes under ultrasonic irradiation. X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were applied for confirmation of nano-structure character for the complexes. Among the complexes, zinc azide complex structure was analyzed by X-ray crystallography. This complex crystallizes as a triplet in trigonal system with space group of P31. The coordination sphere around the zinc center is well shown as a distorted trigonal bipyramidal with three nitrogen atoms from Schiff base ligand and two terminal azide nitrogen atoms attached to zinc ion. Various intermolecular interactions such as NH⋯N, CH⋯N and CH⋯π hydrogen bonding interactions stabilize crystalline lattice so that they causes a three dimensional supramolecular structure for the complex. In vitro screening of the compounds for their antimicrobial activities showed that ZnLI2, ZnL(N3)2, ZnLCl2 and ZnL(NCS)2 were found as the most effective compound against bacteria of Bacillus subtilis, Staphylococcus aureus, Pseudomonas aeruginosa and Escherichia coli respectively. Also ZnLI2 and ZnLCl2 complexes were found more effective against two selected fungi than others. Finally, thermal behaviors of the zinc complexes showed that they are decomposed via 2-4 thermal steps from room temperature up to 1000°C. PMID:25528511

  11. Mixed ligand copper(II) complexes of 2,9-dimethyl-1,10-phenanthroline: tridentate 3N primary ligands determine DNA binding and cleavage and cytotoxicity.

    PubMed

    Ganeshpandian, Mani; Ramakrishnan, Sethu; Palaniandavar, Mallayan; Suresh, Eringathodi; Riyasdeen, Anvarbatcha; Akbarsha, Mohammad Abdulkadher

    2014-11-01

    A series of mononuclear mixed ligand copper(II) complexes of the type [Cu(L)(2,9-dmp)](ClO4)21-4, where L is a tridentate 3N ligand such as diethylenetriamine (L1) (1) or N-methyl-N'-(pyrid-2-yl-methyl)ethylenediamine (L2) (2) or di(2-picolyl)amine (L3) (3) or bis(pyrid-2-ylmethyl)-N-methylamine (L4) (4) and 2,9-dmp is 2,9-dimethyl-1,10-phenanthroline, has been isolated and characterized. The complexes 1 and 3 possess square-based pyramidal coordination geometry. Absorption spectral studies reveal that the intrinsic DNA binding affinity varies as 1>2>3>4. The higher DNA binding affinity of 1 arises from L1, which offers lower steric hindrance toward intercalation of 2,9-dmp co-ligand into DNA base pairs and is involved in hydrogen bonding interaction with DNA. Interestingly, all the complexes cleave pUC19 supercoiled DNA in the absence of an activating agent. They also exhibit oxidative (H2O2) DNA cleavage ability, which varies as 1>2>3>4, the highest cleavage efficiency of 1 being due to the largest amount of ROS it generates. The tryptophan emission-quenching experiment reveals that the stronger binding of 3 and 4 with bovine serum albumin (BSA) in the hydrophobic region, which is in line with DNA viscosity measurements. The IC50 values of 1-4 for MCF-7 breast cancer cell line are lower than that of cisplatin. Flow cytometry analysis reveals that 1 mediates the arrest of S and G2/M phases in the cell cycle progression at 24h harvesting time, which progresses into apoptosis. Hoechst 33258 staining studies indicate the higher potency of 1 to induce apoptosis.

  12. Nano structure zinc (II) Schiff base complexes of a N3-tridentate ligand as new biological active agents: Spectral, thermal behaviors and crystal structure of zinc azide complex

    NASA Astrophysics Data System (ADS)

    Montazerozohori, M.; Mojahedi Jahromi, S.; Masoudiasl, A.; McArdle, P.

    2015-03-01

    In this work, synthesis of some new five coordinated zinc halide/pseudo-halide complexes of a N3-tridentate ligand is presented. All complexes were subjected to spectroscopic and physical methods such as FT-IR, UV-visible, 1H and 13C NMR spectra, thermal analyses and conductivity measurements for identification. Based on spectral data, the general formula of ZnLX2 (X = Cl-, Br-, I-, SCN- and N3-) was proposed for the zinc complexes. Zinc complexes have been also prepared in nano-structure sizes under ultrasonic irradiation. X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were applied for confirmation of nano-structure character for the complexes. Among the complexes, zinc azide complex structure was analyzed by X-ray crystallography. This complex crystallizes as a triplet in trigonal system with space group of P31. The coordination sphere around the zinc center is well shown as a distorted trigonal bipyramidal with three nitrogen atoms from Schiff base ligand and two terminal azide nitrogen atoms attached to zinc ion. Various intermolecular interactions such as Nsbnd H⋯N, Csbnd H⋯N and Csbnd H⋯π hydrogen bonding interactions stabilize crystalline lattice so that they causes a three dimensional supramolecular structure for the complex. In vitro screening of the compounds for their antimicrobial activities showed that ZnLI2, ZnL(N3)2, ZnLCl2 and ZnL(NCS)2 were found as the most effective compound against bacteria of Bacillus subtilis, Staphylococcus aureus, Pseudomonas aeruginosa and Escherichia coli respectively. Also ZnLI2 and ZnLCl2 complexes were found more effective against two selected fungi than others. Finally, thermal behaviors of the zinc complexes showed that they are decomposed via 2-4 thermal steps from room temperature up to 1000 °C.

  13. Modulating the near-infrared luminescence of neodymium and ytterbium complexes with tridentate ligands based on benzoxazole-substituted 8-hydroxyquinolines.

    PubMed

    Shavaleev, Nail M; Scopelliti, Rosario; Gumy, Frédéric; Bünzli, Jean-Claude G

    2009-04-01

    An improved synthesis of 2-(2'-benzothiazole)- and 2-(2'-benzoxazole)-8-hydroxyquinoline ligands that combine a tridentate N,N,O-chelating unit for metal binding and extended chromophore for light harvesting is developed. The 2-(2'-benzoxazole)-8-hydroxyquinoline ligands form mononuclear nine-coordinate complexes with neodymium, [Nd(kappa(3)-ligand)(3)], and an eight-coordinate complex with ytterbium, [Yb(kappa(3)-ligand)(2) x (kappa(1)-ligand) x H(2)O], as verified by crystallographic characterization of five complexes with four different ligands. The chemical stability of the complexes increases when the ligand contains 5,7-dihalo-8-hydroxyquinoline versus an 8-hydroxyquinoline group. The complexes feature a ligand-centered visible absorption band with a maximum at 508-527 nm and an intensity of (7.5-9.6) x 10(3) M(-1) x cm(-1). Upon excitation with UV and visible light within ligand absorption transitions, the complexes display characteristic lanthanide luminescence in the near-infrared at 850-1450 nm with quantum yields and lifetimes in the solid state at room temperature as high as 0.33% and 1.88 micros, respectively. The lanthanide luminescence in the complexes is enhanced upon halogenation of the 5,7-positions in the 8-hydroxyquinoline group and upon the addition of electron-donating substituents to the benzoxazole ring. Facile modification of chromophore units in 2-(2'-benzoxazole)-8-hydroxyquinoline ligands provides means for controlling the luminescence properties of their lanthanide complexes.

  14. Copper(II) complexes with tridentate N-(benzoyl)-N‧-(salicylidine)-hydrazine and monodentate N-heterocycles: Investigations of intermolecular interactions in the solid state

    NASA Astrophysics Data System (ADS)

    Das, Sunirban; Pal, Samudranil

    2005-10-01

    Ternary copper(II) complexes having the general formula [Cu(bhs)(hc)], with a tridentate Schiff base, N-(benzoyl)- N'-(salicylidine)-hydrazine (H 2bhs) and monodentate N-heterocycles (hc=3,5-dimethylpyrazole, pyrazole, imidazole, and pyridine), are described. The complexes were characterized by elemental analysis, spectroscopic and cryomagnetic measurements and X-ray crystallography. Analytical data, infrared and electronic spectral features and molar conductivity values are consistent with the proposed molecular formula and the +2 oxidation state of the metal ion in these complexes. Cryomagnetic and EPR spectral measurements showed weak antiferromagnetic spin-exchange in all four complexes. In each complex, the metal ion is in N 2O 2 square-plane constituted by the phenolate-O, the imine-N, and the deprotonated amide-O donor bhs 2- and the sp 2 N-donor neutral heterocycle. In the solid state, the complexes having 3,5-dimethylpyrazole, imidazole, and pyridine as the heterocyclic ligand, exist as centrosymmetric dimeric species due to weak apical coordination of the metal bound phenolate-O. On the other hand, only one of the two molecules present in the asymmetric unit of the complex containing pyrazole forms the centrosymmetric dimeric species due to weak apical coordination of the metal bound amide-O. In the crystal lattice, intermolecular π-π, C-H⋯π, C-H⋯N, O-H⋯N and N-H⋯O interactions involving the complex and the solvent molecules lead to one- and two-dimensional supramolecular structures.

  15. Advanced tunable laser source for DoD applications

    SciTech Connect

    Cockroft, N.; Early, J.; Johnson, C.; Lester, C.; Quick, C.; Shimada, T.; Tiee, J.

    1996-06-01

    This is a final report of a two year project at the Los Alamos National Laboratory (LANL). The project sought to develop a new solid- state laser transmitter that can be tuned over an exceptionally broad spectral range and integrated with LIDAR remote sensing systems for applications in species specific chemical sensing. Activities have included non-linear frequency conversion of tunable chromium doped LiSAF laser radiation to the ultraviolet and infrared spectral regions. This system is capable of the detection of chemical species previously unapproachable, as well as an improvement in detection sensitivity of 1-2 orders of magnitude for species currently studied.

  16. Massively parallel simulation with DOE's ASCI supercomputers : an overview of the Los Alamos Crestone project

    SciTech Connect

    Weaver, R. P.; Gittings, M. L.

    2004-01-01

    The Los Alamos Crestone Project is part of the Department of Energy's (DOE) Accelerated Strategic Computing Initiative, or ASCI Program. The main goal of this software development project is to investigate the use of continuous adaptive mesh refinement (CAMR) techniques for application to problems of interest to the Laboratory. There are many code development efforts in the Crestone Project, both unclassified and classified codes. In this overview I will discuss the unclassified SAGE and the RAGE codes. The SAGE (SAIC adaptive grid Eulerian) code is a one-, two-, and three-dimensional multimaterial Eulerian massively parallel hydrodynamics code for use in solving a variety of high-deformation flow problems. The RAGE CAMR code is built from the SAGE code by adding various radiation packages, improved setup utilities and graphics packages and is used for problems in which radiation transport of energy is important. The goal of these massively-parallel versions of the codes is to run extremely large problems in a reasonable amount of calendar time. Our target is scalable performance to {approx}10,000 processors on a 1 billion CAMR computational cell problem that requires hundreds of variables per cell, multiple physics packages (e.g. radiation and hydrodynamics), and implicit matrix solves for each cycle. A general description of the RAGE code has been published in [l],[ 2], [3] and [4]. Currently, the largest simulations we do are three-dimensional, using around 500 million computation cells and running for literally months of calendar time using {approx}2000 processors. Current ASCI platforms range from several 3-teraOPS supercomputers to one 12-teraOPS machine at Lawrence Livermore National Laboratory, the White machine, and one 20-teraOPS machine installed at Los Alamos, the Q machine. Each machine is a system comprised of many component parts that must perform in unity for the successful run of these simulations. Key features of any massively parallel system

  17. Multimedia contaminant environmental exposure assessment methodology as applied to Los Alamos, New Mexico

    SciTech Connect

    Whelan, G.; Thompson, F.L.; Yabusaki, S.B.

    1983-02-01

    The MCEA (Multimedia Contaminant Environmental Exposure Assessment) methodology assesses exposures to air, water, soil, and plants from contaminants released into the environment by simulating dominant mechanisms of contaminant migration and fate. The methodology encompasses five different pathways (i.e., atmospheric, terrestrial, overland, subsurface, and surface water) and combines them into a highly flexible tool. The flexibility of the MCEA methodology is demonstrated by encompassing two of the pathways (i.e., overland and surface water) into an effective tool for simulating the migration and fate of radionuclides released into the Los Alamos, New Mexico region. The study revealed that: (a) the /sup 239/Pu inventory in lower Los Alamos Canyon increased by approximately 1.1 times for the 50-y flood event; (b) the average contaminant /sup 239/Pu concentrations (i.e., weighted according to the depth of the respective bed layer) in lower Los Alamos Canyon for the 50-y flood event decreased by 5.4%; (c) approx. 27% of the total /sup 239/Pu contamination resuspended from the entire bed (based on the assumed cross sections) for the 50-y flood event originated from lower Pueblo Canyon; (d) an increase in the /sup 239/Pu contamination of the bed followed the general deposition patterns experienced by the sediment in Pueblo-lower Los Alamos Canyon; likewise, a decrease in the /sup 239/Pu contamination of the bed followed general sediment resuspension patterns in the canyon; (e) 55% of the /sup 239/Pu reaching the San Ildefonso Pueblo in lower Los Alamos Canyon originated from lower Los Alamos Canyon; and (f) 56% of the /sup 239/Pu contamination reaching the San Ildefonso Pueblo in lower Los Alamos Canyon was carried through towards the Rio Grande. 47 references, 41 figures, 29 tables.

  18. Transportation of pyrochemical salts from Rocky Flats to Los Alamos

    SciTech Connect

    Schreiber, S.B.

    1997-02-01

    Radioactive legacy wastes or residues are currently being stored on numerous Sites around the former Department of Energy`s (DOE) Nuclear Weapons Complex. Since most of the operating facilities were shut down and have not operated since before the declared end to the Cold War in 1993, the historical method for treating these residues no longer exists. The risk associated with continued storage of these residues will dramatically increase with time. Thus, the DOE was directed by the Defense Nuclear Facility Safety Board in its Recommendation 94-1 to address and stabilize these residues and established an eight year time frame for doing so. There are only two options available to respond to this requirement: (1) restart existing facilities to treat and package the residues for disposal or (2) transport the residues to another operating facility within the Complex where they can be treated and packaged for disposal. This paper focuses on one such residue type, pyrochemical salts, produced at one Complex site, the Rocky Flats Plant located northwest of Denver, Colorado. One option for treating the salts is their shipment to Los Alamos, New Mexico, for handling at the Plutonium Facility. The safe transportation of these salts can be accomplished at present with several shipping containers including a DOT 6M, a DOE 9968, Type A or Type B quantity 55-gallon drum overpacks, or even the TRUPACT II. The tradeoffs between each container is examined with the conclusion that none of the available shipping containers is fully satisfactory. Thus, the advantageous aspects of each container must be utilized in an integrated and efficient way to effectively manage the risk involved. 1 fig.

  19. 2011 Los Alamos National Laboratory Riparian Inventory Results

    SciTech Connect

    Norris, Elizabeth J.; Hansen, Leslie A.; Hathcock, Charles D.; Keller, David C.; Zemlick, Catherine M.

    2012-03-29

    A total length of 36.7 kilometers of riparian habitat were inventoried within LANL boundaries between 2007 and 2011. The following canyons and lengths of riparian habitat were surveyed and inventoried between 2007 and 2011. Water Canyon (9,669 m), Los Alamos Canyon (7,131 m), Pajarito Canyon (6,009 m), Mortandad Canyon (3,110 m), Two-Mile Canyon (2,680 m), Sandia Canyon (2,181 m), Three-Mile Canyon (1,883 m), Canyon de Valle (1,835 m), Ancho Canyon (1,143 m), Canada del Buey (700 m), Sandia Canyon (221 m), DP Canyon (159 m) and Chaquehui Canyon (50 m). Effluent Canyon, Fence Canyon and Potrillo Canyon were surveyed but no areas of riparian habitat were found. Stretches of inventoried riparian habitat were classified for prioritization of treatment, if any was recommended. High priority sites included stretches of Mortandad Canyon, LA Canyon, Pajarito Canyon, Two-Mile Canyon, Sandia Canyon and Water Canyon. Recommended treatment for high priority sites includes placement of objects into the stream channel to encourage sediment deposition, elimination of channel incision, and to expand and slow water flow across the floodplain. Additional stretches were classified as lower priority, and, for other sites it was recommended that feral cattle and exotic plants be removed to aid in riparian habitat recovery. In June 2011 the Las Conchas Wildfire burned over 150,000 acres of land in the Jemez Mountains and surrounding areas. The watersheds above LA Canyon, Water Canyon and Pajarito Canyon were burned in the Las Conchas Wildfire and flooding and habitat alteration were observed in these canyon bottoms (Wright 2011). Post fire status of lower priority areas may change to higher priority for some of the sites surveyed prior to the Las Conchas Wildfire, due to changes in vegetation cover in the adjacent upland watershed.

  20. Tritium monitor calibration at Los Alamos National Laboratory

    SciTech Connect

    Bjork, C.J.; Aikin, D.J.; Houlton, T.W.

    1997-08-01

    Tritium in air is monitored at Los Alamos National Laboratory (LANL) with air breathing instruments based on ionization chambers. Stack emissions are continuously monitored from sample tubes which each connect to a Tritium bubble which differentially collects HTO and HT. A set of glass vials of glycol capture the HTO. The HT is oxidized with a palladium catalyst and the resultant HTO is captured in a second set of vials of glycol. The glycol is counted with a liquid scintillation counter. All calibrations are performed with tritium containing gas. The Radiation Instrumentation and Calibration (RIC) Team has constructed and maintains two closed loop gas handling systems based on femto TECH model U24 tritium ion chamber monitors: a fixed system housed in a fume hood and a portable system mounted on two two wheeled hand trucks. The U24 monitors are calibrated against tritium in nitrogen gas standards. They are used as standard transfer instruments to calibrate other ion chamber monitors with tritium in nitrogen, diluted with air. The gas handling systems include a circulation pump which permits a closed circulation loop to be established among the U24 monitor and typically two to four other monitors of a given model during calibration. Fixed and portable monitors can be calibrated. The stack bubblers are calibrated in the field by: blending a known concentration of tritium in air within the known volume of the two portable carts, coupled into a common loop; releasing that gas mixture into a ventilation intake to the stack; collecting oxidized tritium in the bubbler; counting the glycol; and using the stack and bubbler flow rates, computing the bubbler`s efficiency. Gas calibration has become a convenient and quality tool in maintaining the tritium monitors at LANL.

  1. Los Alamos National Laboratory considers the use of biodiesel.

    SciTech Connect

    Matlin, M. K.

    2002-01-01

    A new EPA-approved alternative fuel, called biodiesel, may soon be used at Los Alamos National Laboratory in everything from diesel trucks to laboratory equipment. Biodiesel transforms vegetable oils into a renewable, cleaner energy source that can be used in any machinery that uses diesel fuel. For the past couple years, the Laboratory has been exploring the possibility of switching over to soybean-based biodiesel. This change could lead to many health and environmental benefits, as well as help reduce the nation's dependence on foreign oil. Biodiesel is a clean, renewable diesel fuel substitute made from soybean and other vegetable oil crops, as well as from recycled cooking oils. A chemical process breaks down the vegetable oil into a usable form. Vegetable oil has a chain of about 18 carbons and ordinary diesel has about 12 or 13 carbons. The process breaks the carbon chains of the vegetable oil and separates out the glycerin (a fatty substance used in creams and soaps). The co-product of glycerin can be used by pharmaceutical and cosmetic companies, as well as many other markets. Once the chains are shortened and the glycerin is removed from the oil, the remaining liquid is similar to petroleum diesel fuel. It can be burned in pure form or in a blend of any proportion with petroleum diesel. To be considered an alternative fuel source by the EPA, the blend must be at least 20 percent biodiesel (B20). According to the U.S. Department of Energy (DOE), biodiesel is America's fastest growing alternative fuel.

  2. Los Alamos National Laboratory accelerated tru waste workoff strategies

    SciTech Connect

    Kosiewicz, S.T.; Triay, I.R.; Rogers, P.Z.; Christensen, D.V.

    1997-03-01

    During 1996, the Los Alamos National Laboratory (LANL) developed two transuranic (TRU) waste workoff strategies that were estimated to save $270 - 340M through accelerated waste workoff and the elimination of a facility. The planning effort included a strategy to assure that LANL would have a significant quantity (3000+ drums) of TRU waste certified for shipment to the Waste Isolation Pilot Plant (WIPP) beginning in April of 1998, when WIPP was projected to open. One of the accelerated strategies can be completed in less than ten years through a Total Optimization of Parameters Scenario ({open_quotes}TOPS{close_quotes}). {open_quotes}TOPS{close_quotes} fully utilizes existing LANL facilities and capabilities. For this scenario, funding was estimated to be unconstrained at $23M annually to certify and ship the legacy inventory of TRU waste at LANL. With {open_quotes}TOPS{close_quotes} the inventory is worked off in about 8.5 years while shipping 5,000 drums per year at a total cost of $196M. This workoff includes retrieval from earthen cover and interim storage costs. The other scenario envisioned funding at the current level with some increase for TRUPACT II loading costs, which total $16M annually. At this funding level, LANL estimates it will require about 17 years to work off the LANL TRU legacy waste while shipping 2,500 drums per year to WIPP. The total cost will be $277M. This latter scenario decreases the time for workoff by about 19 years from previous estimates and saves an estimated $190M. In addition, the planning showed that a $70M facility for TRU waste characterization was not needed. After the first draft of the LANL strategies was written, Congress amended the WIPP Land Withdrawal Act (LWA) to accelerate the opening of WIPP to November 1997. Further, the No Migration Variance requirement for the WIPP was removed. This paper discusses the LANL strategies as they were originally developed. 1 ref., 3 figs., 2 tabs.

  3. Nuclear accident dosimetry studies at Los Alamos National Laboratory

    SciTech Connect

    Casson, W.H.; Buhl, T.E.; Upp, D.L.

    1995-12-01

    Two critical assemblies have been characterized at the Los Alamos Critical Experiments Facility (LACEF) for use in testing nuclear accident dosimeters and related devices. These device, Godiva IV and SHEBA II, have very different characteristics in both operation and emitted neutron energy spectra. The Godiva assembly is a bare metal fast burst device with a hard spectrum. This spectrum can be modified by use of several shields including steel, concrete, and plexiglas. The modified spectra vary in both average neutron energy and in the specific distribution of the neutron energies in the intermediate energy range. This makes for a very favorable test arrangement as the response ratios between different activation foils used in accident dosimeters are significantly altered such as the ratio between gold, copper, and sulfur elements. The SHEBA device is a solution assembly which has both a slow ramp and decay period and a much softer spectrum. The uncertainly introduced in the response of fast decay foils such as indium can therefore be evaluated into the test results. The neutron energy spectrum for each configuration was measured during low power operations with a multisphere system. These measurements were extended to high dose pulsed operation by use of TLDs moderated TLDs, and special activation techniques. The assemblies were used in the testing of several accident dosimetry devices in studies modeled after the Nuclear Accident Dosimetry Studies that were conducted at Oak Ridge National Laboratory for about 25 years using the Health Physics Research Reactor. It is our intention to conduct these studies approximately annually for the evaluation of the nuclear accident dosimeter systems currently in use within the DOE, alternative systems used internationally, and new dosimeter designs being developed or considered for field application. Participation in selected studies will be open to all participants.

  4. ZERT Final Scientific Report Los Alamos National Laboratory

    SciTech Connect

    Pawar, Rajesh J.

    2011-01-01

    Los Alamos National Laboratory's (LANL) activities for the Center for Zero Emission Research and Technology (ZERT) have fallen into three broad research areas: (1) How do you reduce uncertainty in assuring prior to operation that an engineered geologic site will meet a specific performance goal (e.g., <0.01% leak per year)? (2) What are key monitoring needs for verifying that an engineered geologic site is meeting a performance goal? (3) What are potential vulnerabilities for breeches in containment of CO{sub 2}, and how could they be mitigated either prior to operation or in the event that a threshold is exceeded? We have utilized LANL's multi-disciplinary expertise and an integrated approach combining laboratory experiments, field observations and numerical simulations to address various research issues related to above-mentioned areas. While there have been a number of major milestones achieved as described in past quarterly reports, two of the major accomplishments resulting from LANL's efforts include: (1) Development of the CO{sub 2}-PENS systems framework for long-term performance analysis of geologic CO{sub 2} sequestration sites. CO{sub 2}-PENS is first-ever systems analysis tool designed for assessment of CO{sub 2} sequestration sites. (2) One of the few field studies to-date focused on understanding impact of CO{sub 2} leakage on shallow groundwater chemistry. Two major conclusions of the study are as follows: the impact of co-contaminants transported with deeper brine on shallow groundwater quality is likely to be much larger than that of the CO{sub 2} and CO{sub 2}-induced geochemical reactions and in certain geochemical environment the reactivity of pure CO{sub 2} will not be sufficient to mobilize metals beyond background levels.

  5. Los Alamos National Laboratory W76 Pit Tube Lifetime Study

    SciTech Connect

    Abeln, Terri G.

    2012-04-25

    A metallurgical study was requested as part of the Los Alamos National Laboratory (LANL) W76-1 life-extension program (LEP) involving a lifetime analysis of type 304 stainless steel pit tubes subject to repeat bending loads during assembly and disassembly operations at BWXT/Pantex. This initial test phase was completed during the calendar years of 2004-2006 and the report not issued until additional recommended tests could be performed. These tests have not been funded to this date and therefore this report is considered final. Tubes were reportedly fabricated according to Rocky Flats specification P14548 - Seamless Type 304 VIM/VAR Stainless Steel Tubing. Tube diameter was specified as 0.125 inches and wall thickness as 0.028 inches. A heat treat condition is not specified and the hardness range specification can be characteristic of both 1/8 and 1/4 hard conditions. Properties of all tubes tested were within specification. Metallographic analysis could not conclusively determine a specified limit to number of bends allowable. A statistical analysis suggests a range of 5-7 bends with a 99.95% confidence limit. See the 'Statistical Analysis' section of this report. The initial phase of this study involved two separate sets of test specimens. The first group was part of an investigation originating in the ESA-GTS [now Gas Transfer Systems (W-7) Group]. After the bend cycle test parameters were chosen (all three required bends subjected to the same amount of bend cycles) and the tubes bent, the investigation was transferred to Terri Abeln (Metallurgical Science and Engineering) for analysis. Subsequently, another limited quantity of tubes became available for testing and were cycled with the same bending fixture, but with different test parameters determined by T. Abeln.

  6. Benchmarking of Back Thinned 512x512 X-ray CCD Camera Measurements with DEF X-ray film

    NASA Astrophysics Data System (ADS)

    Shambo, N. A.; Workman, J.; Kyrala, G.; Hurry, T.; Gonzales, R.; Evans, S. C.

    1999-11-01

    Using the Trident Laser Facility at Los Alamos National Laboratory 25-micron thick, 2mm diameter titanium disks were shot with a 527nm(green) laser light to measure x-ray yield. 1.0 mil and 0.5 mil Aluminum steps were used to test the linearity of the CCD Camera and DEF X-ray film was used to test the calibration of the CCD Camera response at 4.75keV. Both laser spot size and incident laser intensity were constrained to give constancy to the experimental data. This poster will discuss both the experimental design and results.

  7. RCRA facility investigation for the townsite of Los Alamos, New Mexico

    SciTech Connect

    Dorries, A.M.; Conrad, R.C.; Nonno, L.M.

    1992-01-01

    During World War II, Los Alamos, New Mexico was established as an ideal location for the secrecy and safety needed for the research and development required to design a nuclear fission bomb. Experiments carried out in the 1940s generated both radioactive and hazardous waste constituents on what is presently part of the Los Alamos townsite. Under the RCRA permit issued to Los alamos national Laboratory in 1990, the Laboratory is scheduled for investigation of its solid waste management units (SWMUs). The existing information on levels of radioactivity on the townsite is principally data from soil samples taken during the last site decontamination in 1976, little information on the presence of hazardous constituents exists today. This paper addresses pathway analysis and a preliminary risk assessment for current residents of the Los Alamos townsite. The estimated dose levels, in mrem per year, show that the previously decontaminated SWMU areas on the Los Alamos townsite will not contribute a radiation dose of any concern to the current residents.

  8. RCRA facility investigation for the townsite of Los Alamos, New Mexico

    SciTech Connect

    Dorries, A.M.; Conrad, R.C.; Nonno, L.M.

    1992-02-01

    During World War II, Los Alamos, New Mexico was established as an ideal location for the secrecy and safety needed for the research and development required to design a nuclear fission bomb. Experiments carried out in the 1940s generated both radioactive and hazardous waste constituents on what is presently part of the Los Alamos townsite. Under the RCRA permit issued to Los alamos national Laboratory in 1990, the Laboratory is scheduled for investigation of its solid waste management units (SWMUs). The existing information on levels of radioactivity on the townsite is principally data from soil samples taken during the last site decontamination in 1976, little information on the presence of hazardous constituents exists today. This paper addresses pathway analysis and a preliminary risk assessment for current residents of the Los Alamos townsite. The estimated dose levels, in mrem per year, show that the previously decontaminated SWMU areas on the Los Alamos townsite will not contribute a radiation dose of any concern to the current residents.

  9. Evaluation of Macroinvertebrate Communities and Habitat for Selected Stream Reaches at Los Alamos National Laboratory

    SciTech Connect

    L.J. Henne; K.J. Buckley

    2005-08-12

    This is the second aquatic biological monitoring report generated by Los Alamos National Laboratory's (LANL's) Water Quality and Hydrology Group. The study has been conducted to generate impact-based assessments of habitat and water quality for LANL waterways. The monitoring program was designed to allow for the detection of spatial and temporal trends in water and habitat quality through ongoing, biannual monitoring of habitat characteristics and benthic aquatic macroinvertebrate communities at six key sites in Los Alamos, Sandia, Water, Pajarito, and Starmer's Gulch Canyons. Data were collected on aquatic habitat characteristics, channel substrate, and macroinvertebrate communities during 2001 and 2002. Aquatic habitat scores were stable between 2001 and 2002 at all locations except Starmer's Gulch and Pajarito Canyon, which had lower scores in 2002 due to low flow conditions. Channel substrate changes were most evident at the upper Los Alamos and Pajarito study reaches. The macroinvertebrate Stream Condition Index (SCI) indicated moderate to severe impairment at upper Los Alamos Canyon, slight to moderate impairment at upper Sandia Canyon, and little or no impairment at lower Sandia Canyon, Starmer's Gulch, and Pajarito Canyon. Habitat, substrate, and macroinvertebrate data from the site in upper Los Alamos Canyon indicated severe impacts from the Cerro Grande Fire of 2000. Impairment in the macroinvertebrate community at upper Sandia Canyon was probably due to effluent-dominated flow at that site. The minimal impairment SCI scores for the lower Sandia site indicated that water quality improved with distance downstream from the outfall at upper Sandia Canyon.

  10. Environmental Assessment for Proposed Access Control and Traffic Improvements at Los Alamos National Laboratory, Los Alamos, New Mexico

    SciTech Connect

    N /A

    2002-08-23

    The National Nuclear Security Administration (NNSA) has assigned a continuing role to Los Alamos National Laboratory (LANL) in carrying out NNSA's national security mission. It is imperative that LANL continue this enduring responsibility and that NNSA adequately safeguard LANL capabilities. NNSA has identified the need to restrict vehicular access to certain areas within LANL for the purpose of permanently enhancing the physical security environment at LANL. It has also identified the need to change certain traffic flow patterns for the purpose of enhancing physical safety at LANL. The Proposed Action would include the construction of eastern and western bypass roads around the LANL Technical Area (TA) 3 area and the installation of vehicle access controls and related improvements to enhance security along Pajarito Road and in the LANL core area. This Proposed Action would modify the current roadway network and traffic patterns. It would also result in traversing Areas of Environmental Interest identified in the LANL Habitat Management Plan, demolition of part of an historic structure at Building 3-40, and traversing several potential release sites and part of the Los Alamos County landfill. The No Action Alternative was also considered. Under this alternative NNSA would not construct the eastern or western bypass roads, any access-control stations, or related improvements. Diamond Drive would continue to serve as the primary conduit for most vehicle traffic within the LANL core area regardless of actual trip destinations. The No Action Alternative does not meet NNSA's purpose and need for action. The proposed bypass road corridors traverse both developed and undeveloped areas. Several potential release sites are present. These would either be sampled and remediated in accordance with New Mexico Environment Department requirements before construction or avoided to allow for future remediation. In some cases, contaminant levels may fall below remediation thresholds

  11. Large excimer lasers for fusion

    SciTech Connect

    Jensen, R.J.

    1986-01-01

    Important goals in DOE and DOD programs require multimegajoule laser pulses. For inertial confinement fusion there is also a requirement to deliver the pulse in about 25 nsec with a very particular power vs time profile - all at high overall efficiency and low cost per joule. After exhaustive consideration of various alternatives, our studies have shown that the most cost effective approach to energy scaling is to increase the size of the final amplifiers up to the 200 to 300 kJ level. This conclusion derives largely from the fact that, at a given complexity, costs increase slowly with increasing part size while output energy should increase dramatically. Extrapolations to low cost by drastic cuts in the unit cost of smaller devices through mass production are considered highly risky. At a minimum the requirement to provide, space, optics and mounts for such systems will remain expensive. In recent years there have been dramatic advances in scaling. The Los Alamos LAM has produced over 10 kJ in a single 1/2 nsec pulse. In this paper we explore the issues involved in scaling to higher energy while still maintaining high efficiencies. In the remainder of this paper we will discuss KrF laser scaling for the fusion mission. We will omit most of the discussion of the laser system design, but address only KrF amplifiers.

  12. Environmental Assessment for the High Explosives Wastewater Treatment Facility, Los Alamos National Laboratory, Los Alamos, New Mexico

    SciTech Connect

    1995-08-03

    The Department of Energy (DOE) has identified a need to improve the management of wastewater resulting from high explosives (HE) research and development work at Los Alamos National Laboratory (LANL). LANL`s current methods off managing HE-contaminated wastewater cannot ensure that discharged HE wastewater would consistently meet the Environmental Protection Agency`s (EPA`s) standards for wastewater discharge. The DOE needs to enhance He wastewater management to e able to meet both present and future regulatory standards for wastewater discharge. The DOE also proposes to incorporate major pollution prevention and waste reduction features into LANL`s existing HE production facilities. Currently, wastewater from HE processing buildings at four Technical Areas (TAs) accumulates in sumps where particulate HE settles out and barium is precipitated. Wastewater is then released from the sumps to the environment at 15 permitted outfalls without treatment. The released water may contain suspended and dissolved contaminants, such as HE and solvents. This Environmental Assessment (EA) analyzes two alternatives, the Proposed Action and the Alternative Action, that would meet the purpose and need for agency action. Both alternatives would treat all HE process wastewater using sand filters to remove HE particulates and activated carbon to adsorb organic solvents and dissolved HE. Under either alternative, LANL would burn solvents and flash dried HE particulates and spent carbon following well-established procedures. Burning would produce secondary waste that would be stored, treated, and disposed of at TA-54, Area J. This report contains the Environmental Assessment, as well as the Finding of No Significant Impact and Floodplain Statement of Findings for the High Explosives Wastewater Treatment Facility.

  13. Shock and Detonation Physics at Los Alamos National Laboratory

    SciTech Connect

    Robbins, David L; Dattelbaum, Dana M; Sheffield, Steve A

    2012-08-22

    WX-9 serves the Laboratory and the Nation by delivering quality technical results, serving customers that include the Nuclear Weapons Program (DOE/NNSA), the Department of Defense, the Department of Homeland Security and other government agencies. The scientific expertise of the group encompasses equations-of-state, shock compression science, phase transformations, detonation physics including explosives initiation, detonation propagation, and reaction rates, spectroscopic methods and velocimetry, and detonation and equation-of-state theory. We are also internationally-recognized in ultra-fast laser shock methods and associated diagnostics, and are active in the area of ultra-sensitive explosives detection. The facility capital enabling the group to fulfill its missions include a number of laser systems, both for laser-driven shocks, and spectroscopic analysis, high pressure gas-driven guns and powder guns for high velocity plate impact experiments, explosively-driven techniques, static high pressure devices including diamond anvil cells and dilatometers coupled with spectroscopic probes, and machine shops and target fabrication facilities.

  14. Laser Analyzer

    NASA Technical Reports Server (NTRS)

    1993-01-01

    Dopant level analysis is important to the laser system designer because it allows him to model the laser's performance. It also allows the end user to determine what went wrong when a laser fails to perform as expected. Under a Small Business Innovation Research (SBIR) contract, Scientific Materials Corporation has developed a process for producing uniform laser rods in which the amount of water trapped in the crystal during growth is reduced. This research led to the formation of a subsidiary company, Montana Analytical Services, which conducts analysis of laser rods for dopant ion concentrations. This is a significant advance in laser technology.

  15. Monitoring Sensitive Bat Species at Los Alamos National Laboratory

    SciTech Connect

    Schoenberg, Kari M.

    2014-01-15

    Bats play a critical role in ecosystems and are vulnerable to disturbance and disruption by human activities. In recent decades, bat populations in the United States and elsewhere have decreased tremendously. There are 47 different species of bat in the United States and 28 of these occur in New Mexico with 15 different species documented at the Los Alamos National Laboratory (LANL) and surrounding areas. Euderma maculatum(the spotted bat) is listed as “threatened” by the state of New Mexico and is known to occur at LANL. Four other species of bats are listed as “sensitive” and also occur here. In 1995, a four year study was initiated at LANL to assess the status of bat species of concern, elucidate distribution and relative abundance, and obtain information on roosting sites. There have been no definitive studies since then. Biologists in the Environmental Protection Division at LANL initiated a multi-year monitoring program for bats in May 2013 to implement the Biological Resources Management Plan. The objective of this ongoing study is to monitor bat species diversity and seasonal activity over time at LANL. Bat species diversity and seasonal activity were measured using an acoustic bat detector, the Pettersson D500X. This ultrasound recording unit is intended for long-term, unattended recording of bat and other high frequency animal calls. During 2013, the detector was deployed at two locations around LANL. Study sites were selected based on proximity to water where bats may be foraging. Recorded bat calls were analyzed using Sonobat, software that can help determine specific species of bat through their calls. A list of bat species at the two sites was developed and compared to lists from previous studies. Species diversity and seasonal activity, measured as the number of call sequences recorded each month, were compared between sites and among months. A total of 17,923 bat calls were recorded representing 15 species. Results indicate that there is a

  16. Background radioactivity in sediments near Los Alamos, New Mexico.

    PubMed

    McLin, Stephen G

    2004-07-26

    River and reservoir sediments have been collected annually by Los Alamos National Laboratory since 1974 and 1979, respectively. These background samples are collected from five river stations and four reservoirs located throughout northern New Mexico and southern Colorado. Analyses include 3H, 90Sr, 137Cs, total U, 238Pu, 239,240Pu, 241Am, gross alpha, gross beta, and gross gamma radioactivity. Surprisingly, there are no federal or state regulatory standards in the USA that specify how to compute background radioactivity values on sediments. Hence, the sample median (or 0.50 quantile) is proposed for this background because it reflects central data tendency and is distribution-free. Estimates for the upper limit of background radioactivity on river and reservoir sediments are made for sampled analytes using the 0.95 quantile (two-tail). These analyses also show that seven of ten analytes from reservoir sediments are normally distributed, or are normally distributed after a logarithmic or square root transformation. However, only three of ten analytes from river sediments are similarly distributed. In addition, isotope ratios for 137Cs/238Pu, 137Cs/239,240Pu, and 239,240Pu/238Pu from reservoir sediments are independent of clay content, total organic carbon/specific surface area (TOC/SSA) and cation exchange capacity/specific surface area (CEC/SSA) ratios. These TOC/SSA and CEC/SSA ratios reflect sediment organic carbon and surface charge densities that are associated with radionuclide absorption, adsorption, and ion exchange reactions on clay mineral structures. These latter ratio values greatly exceed the availability of background radionuclides in the environment, and insure that measured background levels are a maximum. Since finer-grained reservoir sediments contain larger clay-sized fractions compared to coarser river sediments, they show higher background levels for most analytes. Furthermore, radioactivity values on reservoir sediments have remained

  17. Los Alamos National Laboratory Yucca Mountain Site Characterization Project 1993 Quality Program status report

    SciTech Connect

    Bolivar, S.L.

    1995-05-01

    This status report is for calendar year 1993. It summarizes the annual activities and accomplishments of the Los Alamos National Laboratory (Los Alamos) Yucca Mountain Site Characterization Project (YMP or Project) quality assurance program. By identifying the accomplishments of the quality program, we establish a baseline that will assist in decision making, improve administrative controls and predictability, and allow us to annually identify long term trends and to evaluate improvements. This is the third annual status report (Bolivar, 1992; Bolivar, 1994). This report is divided into two primary sections: Program Activities and Trend Analysis. Under Program Activities, programmatic issues occurring in 1993 are discussed. The goals for 1993 are also listed, followed by a discussion of their status. Lastly, goals for 1994 are identified. The Trend Analysis section is a summary of 1993 quarterly trend reports and provides a good overview of the quality assurance issues of the Los Alamos YMP.

  18. Los Alamos National Laboratory Human and Intellectual Capital for Sustaining Nuclear Deterrence

    SciTech Connect

    McAlpine, Bradley

    2015-04-01

    This paper provides an overview of the current human and intellectual capital at Los Alamos National Laboratory, through specific research into the statistics and demographics as well as numerous personal interviews at all levels of personnel. Based on this information, a series of recommendations are provided to assist Los Alamos National Laboratory in ensuring the future of the human and intellectual capital for the nuclear deterrence mission. While the current human and intellectual capital is strong it stands on the precipice and action must be taken to ensure Los Alamos National Laboratory maintains leadership in developing and sustaining national nuclear capabilities. These recommendations may be applicable to other areas of the nuclear enterprise, including the Air Force, after further research and study.

  19. A proposal for a long-pulse spallation source at Los Alamos National Laboratory

    SciTech Connect

    Pynn, R.; Weinacht, D.

    1995-12-01

    Los Alamos National Laboratory is proposing a new spallation neutron source that will provide the US with an internationally competitive facility for neutron science and technology that can be built in approximately three years for less than $100 million. The establishment of a 1-MW, long-pulse spallation source (LPSS) at the Los Alamos Neutron Science Center (LANSCE) will meet many of the present needs of scientists in the neutron scattering community and provide a significant boost to neutron research in the US. The new facility will support the development of a future, more intense spallation neutron source, that is planned by DOE`s Office of Energy Research. Together with the existing short pulse spallation source (SPSS) at the Manual Lujan, Jr. Neutron Scattering Center (MLNSC) at Los Alamos, the new LPSS will provide US scientists with a complementary pair of high-performance neutron sources to rival the world`s leading facilities in Europe.

  20. Enabling completion of the material disposition area G closure at the Los Alamos National Laboratory

    SciTech Connect

    Blankenhorn, James Allen; Bishop, Milton L

    2010-01-01

    Los Alamos National Security, LLC (LANS) and the Los Alamos Site Office (LASO) have developed and are implementing an integrated strategy to accelerate the disposition of Los Alamos National Laboratory (LANL) legacy transuranic waste inventory currently stored in Technical Area 54, Material Disposition Area (MDA) G. As that strategy has been implemented the easier waste streams have been certified and shipped leaving the harder more challenging wastes to be dispositioned. Lessons learned from around the complex and a partnership with the National Transuranic Program located in Carlsbad, New Mexico, are enabling this acceleration. The Waste Disposition Program is responsible for the removal of both the above ground and below grade, retrievably stored transuranic waste in time to support the negotiated consent order with the State of New Mexico which requires closure of MDA G by the year 2015. The solutions and strategy employed at LANL are applicable to any organization that is currently managing legacy transuranic waste.

  1. Wide-area Gigabit networking: Los Alamos HIPPI-SONET Gateway

    SciTech Connect

    St. John, W.B.; DuBois, D.H.

    1995-05-01

    This paper describes a HIPPI-SONET Gateway which has been designed by members of the Computer Network Engineering Group at Los Alamos National Laboratory. The Gateway has been used in the CASA Gigabit Testbed at Caltech, Los Alamos National Laboratory, and the San Diego Supercomputer Center to provide communications between the sites. This paper will also make some qualitative statements as to lessons learned during the deployment and maintenance of this wide area network. We report record throughput for transmission of data across a wide area network. We have sustained data rates using the TCP/IP protocol of 550 Mbits/second and the rate of 792 Mbits/second for raw HIPPI data transfer over the 2,000 kilometers from the San Diego Supercomputer Center to the Los Alamos National Laboratory.

  2. ChemCam Rock Laser for the Mars Science Laboratory

    SciTech Connect

    LANL

    2008-03-24

    Los Alamos has a long history of space-related instr... Los Alamos has a long history of space-related instruments, tied primarily to its role in defense-related treaty verification. Space-based detectors have helped determine the differences between signals from lightning bolts and potential nuclear explosions. LANL-developed gamma-ray detection instruments first revealed the existence of what we now know as gamma-ray bursts, an exciting area of astrophysical research. And the use of LANL instruments on varied space missions continues with such products as the ChemCam rock laser for NASA, shown here. The Engineering Model of the ChemCam Mars Science Laboratory rover instrument arrived at NASA's Jet Propulsion Laboratory on February 6, 2008. ChemCam will use imaging and laser-induced breakdown spectroscopy (LIBS) to determine rock and soil compositions on Mars, up to 9 meters from the rover. The engineering model is being integrated into the rover test bed for the development and testing of the rover software. The actual flight model components are concurrently being assembled at Los Alamos and in Toulouse, France, and will be delivered to JPL in July. The Mars Science Laboratory is scheduled to launch in 2009. Animations courtesy of JPL/NASA.

  3. ChemCam Rock Laser for the Mars Science Laboratory

    ScienceCinema

    LANL

    2016-07-12

    Los Alamos has a long history of space-related instr... Los Alamos has a long history of space-related instruments, tied primarily to its role in defense-related treaty verification. Space-based detectors have helped determine the differences between signals from lightning bolts and potential nuclear explosions. LANL-developed gamma-ray detection instruments first revealed the existence of what we now know as gamma-ray bursts, an exciting area of astrophysical research. And the use of LANL instruments on varied space missions continues with such products as the ChemCam rock laser for NASA, shown here. The Engineering Model of the ChemCam Mars Science Laboratory rover instrument arrived at NASA's Jet Propulsion Laboratory on February 6, 2008. ChemCam will use imaging and laser-induced breakdown spectroscopy (LIBS) to determine rock and soil compositions on Mars, up to 9 meters from the rover. The engineering model is being integrated into the rover test bed for the development and testing of the rover software. The actual flight model components are concurrently being assembled at Los Alamos and in Toulouse, France, and will be delivered to JPL in July. The Mars Science Laboratory is scheduled to launch in 2009. Animations courtesy of JPL/NASA.

  4. Lasers of All Sizes

    NASA Astrophysics Data System (ADS)

    Balcou, Philippe; Forget, Sébastien Robert-Philip, Isabelle

    2015-10-01

    * Introduction * The Laser in All Its Forms * Gas lasers * Dye lasers * Solid-state lasers * Lasers for Every Taste * The rise of lasers * Lasers of all sizes * The colors of the rainbow... and beyond * Shorter and shorter lasers * Increasingly powerful lasers * Lasers: A Universal Tool? * Cutting, welding, and cleaning * Communicating * Treating illnesses * Measuring * Supplying energy? * Entertaining * Understanding * Conclusion

  5. Coordination versatility of tridentate pyridyl aroylhydrazones towards iron: tracking down the elusive aroylhydrazono-based ferric spin-crossover molecular materials.

    PubMed

    Shongwe, Musa S; Al-Rahbi, Sumaiya H; Al-Azani, Mariam A; Al-Muharbi, Abdulaziz A; Al-Mjeni, Faizah; Matoga, Dariusz; Gismelseed, Abbasher; Al-Omari, Imaddin A; Yousif, Ali; Adams, Harry; Morris, Michael J; Mikuriya, Masahiro

    2012-02-28

    The two potentially tridentate and monoprotic Schiff bases acetylpyridine benzoylhydrazone (HL(1)) and acetylpyridine 4-tert-butylbenzoylhydrazone (HL(2)) demonstrate remarkable coordination versatility towards iron on account of their propensity to undergo tautomeric transformations as imposed by the metal centre. Each of the pyridyl aroylhydrazone ligands complexes with the ferrous or ferric ion under strictly controlled reaction conditions to afford three six-coordinate mononuclear compounds [Fe(II)(HL)(2)](ClO(4))(2), [Fe(II)L(2)] and [Fe(III)L(2)]ClO(4) (HL = HL(1) or HL(2)) displaying distinct colours congruent with their intense CT visible absorptions. The synthetic manoeuvres rely crucially on the stoichiometry of the reactants, the basicities of the reaction mixtures and the choice of solvent. Electrochemically, each of these iron compounds exhibits a reversible metal-centred redox process. By all appearances, [Fe(III)(L(1))(2)]ClO(4) is one of only two examples of a crystallographically elucidated iron(III) bis-chelate compound of a pyridyl aroylhydrazone. Several pertinent physical measurements have established that each of the Schiff bases stabilises multiple spin states of iron; the enolate form of these ligands exhibits greater field strength than does the corresponding neutral keto tautomer. To the best of our knowledge, [Fe(III)(L(1))(2)]ClO(4) and [Fe(III)(L(2))(2)]ClO(4) are the first examples of ferric spin crossovers of aroylhydrazones. Whereas in the former the spin crossover (SCO) is an intricate gradual process, in the latter the (6)A(1)↔(2)T(2) transition curve is sigmoidal with T(½)∼280 K and the SCO is virtually complete. As regards [Fe(III)(L(1))(2)]ClO(4), Mössbauer and EPR spectroscopic techniques have revealed remarkable dependence of the spin transition on sample type and extent of solvation. In frozen MeOH solution at liquid nitrogen temperature, both iron(III) compounds exist wholly in the doublet ground state. PMID:22216420

  6. Reactions of copper(II)-H2O2 adducts supported by tridentate bis(2-pyridylmethyl)amine ligands: sensitivity to solvent and variations in ligand substitution.

    PubMed

    Kunishita, Atsushi; Scanlon, Joseph D; Ishimaru, Hirohito; Honda, Kaoru; Ogura, Takashi; Suzuki, Masatatsu; Cramer, Christopher J; Itoh, Shinobu

    2008-09-15

    The copper(II) complexes 1(H) and 1(Ar(X)), supported by the N,N-di(2-pyridylmethyl)benzylamine tridentate ligand (L(H)) or its derivatives having m-substituted phenyl group at the 6-position of pyridine donor groups (L(Ar(X))), have been prepared, and their reactivity toward H2O2 has been examined in detail at low temperature. Both copper(II) complexes exhibited a novel reactivity in acetone, giving 2-hydroxy-2-hydroperoxypropane (HHPP) adducts 2(H) and 2(Ar(X)), respectively. From 2(Ar(X)), an efficient aromatic ligand hydroxylation took place to give phenolate-copper(II) complexes 4(Ar(X)). Detailed spectroscopic and kinetic analyses have revealed that the reaction proceeds via an electrophilic aromatic substitution mechanism involving copper(II)-carbocation intermediates 3(Ar(X)). Theoretical studies at the density functional theory (DFT) level have strongly implicated conjugate acid/base catalysis in the O-O bond cleavage and C-O bond formation steps that take the peroxo intermediate 2(Ar(X)) to the carbocation intermediate 3(Ar(X)). In contrast to the 2(Ar(X)) cases, the HHPP-adduct 2(H) reacted to give a copper(II)-acetate complex [Cu(II)(L(H))(OAc)](ClO4) (6(H)), in which one of the oxygen atoms of the acetate co-ligand originated from H2O2. In this case, a mechanism involving a Baeyer-Villiger type 1,2-methyl shift from the HHPP-adduct and subsequent ester hydrolysis has been proposed on the basis of DFT calculations; conjugate acid/base catalysis is implicated in the 1,2-methyl shift process as well. In propionitrile, both 1(H) and 1(Ar(X)) afforded simple copper(II)-hydroperoxo complexes LCu(II)-OOH in the reaction with H2O2, demonstrating the significant solvent effect on the reaction between copper(II) complexes and H2O2.

  7. Laser microphone

    DOEpatents

    Veligdan, James T.

    2000-11-14

    A microphone for detecting sound pressure waves includes a laser resonator having a laser gain material aligned coaxially between a pair of first and second mirrors for producing a laser beam. A reference cell is disposed between the laser material and one of the mirrors for transmitting a reference portion of the laser beam between the mirrors. A sensing cell is disposed between the laser material and one of the mirrors, and is laterally displaced from the reference cell for transmitting a signal portion of the laser beam, with the sensing cell being open for receiving the sound waves. A photodetector is disposed in optical communication with the first mirror for receiving the laser beam, and produces an acoustic signal therefrom for the sound waves.

  8. Measurements at Los Alamos National Laboratory Plutonium Facility in Support of Global Security Mission Space

    SciTech Connect

    Stange, Sy; Mayo, Douglas R.; Herrera, Gary D.; McLaughlin, Anastasia D.; Montoya, Charles M.; Quihuis, Becky A.; Trujillo, Julio B.; Van Pelt, Craig E.; Wenz, Tracy R.

    2012-07-13

    The Los Alamos National Laboratory Plutonium Facility at Technical Area (TA) 55 is one of a few nuclear facilities in the United States where Research & Development measurements can be performed on Safeguards Category-I (CAT-I) quantities of nuclear material. This capability allows us to incorporate measurements of CAT-IV through CAT-I materials as a component of detector characterization campaigns and training courses conducted at Los Alamos. A wider range of measurements can be supported. We will present an overview of recent measurements conducted in support of nuclear emergency response, nuclear counterterrorism, and international and domestic safeguards. This work was supported by the NNSA Office of Counterterrorism.

  9. Los Alamos plutonium facility applied systems integration project status report for period ending August 31, 1981

    SciTech Connect

    Shirk, D.G.; Bearse, R.C.; Marshall, R.S.; Baker, A.L.; Thomas, C.C. Jr.

    1982-02-01

    The conceptual design of an on-line, near-real-time nondestructive assay instrumentation network for the Los Alamos Plutonium Facility is complete. Analysis of instrument history data indicates that the instrument certification procedures need improvement. Analysis of exhaust filter data has led to the derivation of a buildup prediction equation that is a function of throughput. This suggests that development of a generalized model is possible. A number of routine reports are now available from the Plutonium Facility/Los Alamos Safeguards System including inventories and active reports.

  10. Los Alamos Air Monitoring Data Related to the Fukushima Daiichi Reactor

    SciTech Connect

    McNaughton, Michael

    2011-01-01

    In response to the disasters in Japan on March 11, 2011, Los Alamos National Laboratory (LANL) is collecting air data and analyzing the data for fission products. At present, we report preliminary data from three high-volume air samplers and one stack sampler. Iodine-131 (I-131) is not optimally measured by our standard polypropylene filters. In addition to the filter data, we have one measurement obtained from a charcoal cartridge. These data, together with measurements of other radionuclides are adequate for a preliminary assessment and assure us that radionuclides from Fukushima Daiichi do not present a threat to human health at or near Los Alamos.

  11. Concentration Ratios for Cesium and Strontium in Produce Near Los Alamos

    SciTech Connect

    S. Salazar, M.McNaughton, P.R. Fresquez

    2006-03-01

    The ratios of the concentrations of radionuclides in produce (fruits, vegetables, and grains) to the concentrations in the soil have been measured for cesium and strontium at locations near Los Alamos. The Soil, Foodstuffs, and Biota Team of the Meteorology and Air Quality Group of the Los Alamos National Laboratory (LANL) obtained the data at locations within a radius of 50 miles of LANL. The concentration ratios are in good agreement with previous measurements: 0.01 to 0.06 for cesium-137 and 0.1 to 0.5 for strontium-90 (wet-weight basis).

  12. Los Alamos Controlled Air Incinerator for radioactive waste. Volume II. Engineering design reference manual

    SciTech Connect

    Koenig, R.A.; Draper, W.E.; Newmyer, J.M.; Warner, C.L.

    1982-10-01

    This two-volume report is a detailed design and operating documentation of the Los Alamos National Laboratory Controlled Air Incinerator (CAI) and is an aid to technology transfer to other Department of Energy contractor sites and the commercial sector. Volume I describes the CAI process, equipment, and performance, and it recommends modifications based on Los Alamos experience. It provides the necessary information for conceptual design and feasibility studies. Volume II provides descriptive engineering information such as drawings, specifications, calculations, and costs. It aids duplication of the process at other facilities.

  13. 75 FR 24957 - Decision to Evaluate a Petition to Designate a Class of Employees From the Los Alamos National...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-05-06

    ... designate a class of employees from the Los Alamos National Laboratory, Los Alamos, New Mexico, to be..., New Mexico. Job Titles and/or Job Duties: All employees of the Department of Energy, its predecessor... HUMAN SERVICES Decision to Evaluate a Petition to Designate a Class of Employees From the Los...

  14. Fabrication of Optical Fiber Mechanical Shock Sensors for the Los Alamos HERT (High Explosive Radio Telemetry) Project

    SciTech Connect

    P. E. Klingsporn

    2005-11-14

    This document lists the requirements for the fiber optic mechanical shock sensor for the Los Alamos HERT (High Explosive Radio Telemetry) project and provides detailed process steps for fabricating, testing, and assembling the fiber shock sensors for delivery to Los Alamos.

  15. Laser ignition

    DOEpatents

    Early, James W.; Lester, Charles S.

    2004-01-13

    Sequenced pulses of light from an excitation laser with at least two resonator cavities with separate output couplers are directed through a light modulator and a first polarzing analyzer. A portion of the light not rejected by the first polarizing analyzer is transported through a first optical fiber into a first ignitor laser rod in an ignitor laser. Another portion of the light is rejected by the first polarizing analyzer and directed through a halfwave plate into a second polarization analyzer. A first portion of the output of the second polarization analyzer passes through the second polarization analyzer to a second, oscillator, laser rod in the ignitor laser. A second portion of the output of the second polarization analyzer is redirected by the second polarization analyzer to a second optical fiber which delays the beam before the beam is combined with output of the first ignitor laser rod. Output of the second laser rod in the ignitor laser is directed into the first ignitor laser rod which was energized by light passing through the first polarizing analyzer. Combined output of the first ignitor laser rod and output of the second optical fiber is focused into a combustible fuel where the first short duration, high peak power pulse from the ignitor laser ignites the fuel and the second long duration, low peak power pulse directly from the excitation laser sustains the combustion.

  16. Advanced Laser Particle Accelerator Development at LANL: From Fast Ignition to Radiation Oncology

    SciTech Connect

    Flippo, K. A.; Offermann, D. T.; Cobble, J. A.; Schmitt, M. J.; Gautier, D. C.; Kwan, T. J.; Montgomery, D. S.; Gaillard, S. A.; Kluge, T.; Bussmann, M.; Cowan, T. E.; Bartal, T.; Beg, F. N.; Gall, B.; Kovaleski, S.; Geissel, M.; Schollmeier, M.; Korgan, G.; Malekos, S.; Lockard, T.

    2010-11-04

    Laser-plasma accelerated ion and electron beam sources are an emerging field with vast prospects, and promise many superior applications in a variety of fields such as hadron cancer therapy, compact radioisotope generation, table-top nuclear physics, laboratory astrophysics, nuclear forensics, waste transmutation, Special Nuclear Material (SNM) detection, and inertial fusion energy. LANL is engaged in several projects seeking to develop compact high-current and high-energy ion and electron sources. We are especially interested in two specific applications: ion fast ignition/capsule perturbation and radiation oncology. Laser-to-beam conversion efficiencies of over 10% are needed for practical applications, and we have already shown inherent efficiencies of >5% from flat foils, on Trident using only a 5th of the intensity and energy of the Nova Petawatt laser. With clever target designs, like structured curved cone targets, we have also been able to achieve major ion energy gains, leading to the highest energy laser-accelerated proton beams in the world [3]. These new target designs promise to help usher in the next generation of particle sources realizing the potential of laser-accelerated beams.

  17. Advanced Laser Particle Accelerator Development at LANL: From Fast Ignition to Radiation Oncology

    NASA Astrophysics Data System (ADS)

    Flippo, K. A.; Gaillard, S. A.; Kluge, T.; Bussmann, M.; Offermann, D. T.; Cobble, J. A.; Schmitt, M. J.; Bartal, T.; Beg, F. N.; Cowan, T. E.; Gall, B.; Gautier, D. C.; Geissel, M.; Kwan, T. J.; Korgan, G.; Kovaleski, S.; Lockard, T.; Malekos, S.; Montgomery, D. S.; Schollmeier, M.; Sentoku, Y.

    2010-11-01

    Laser-plasma accelerated ion and electron beam sources are an emerging field with vast prospects, and promise many superior applications in a variety of fields such as hadron cancer therapy, compact radioisotope generation, table-top nuclear physics, laboratory astrophysics, nuclear forensics, waste transmutation, Special Nuclear Material (SNM) detection, and inertial fusion energy. LANL is engaged in several projects seeking to develop compact high-current and high-energy ion and electron sources. We are especially interested in two specific applications: ion fast ignition/capsule perturbation and radiation oncology. Laser-to-beam conversion efficiencies of over 10% are needed for practical applications, and we have already shown inherent efficiencies of >5% from flat foils, on Trident using only a 5th of the intensity [1] and energy of the Nova Petawatt laser [2]. With clever target designs, like structured curved cone targets, we have also been able to achieve major ion energy gains, leading to the highest energy laser-accelerated proton beams in the world [3]. These new target designs promise to help usher in the next generation of particle sources realizing the potential of laser-accelerated beams.

  18. Electronic and geometric structures of Au30 clusters: a network of 2e-superatom Au cores protected by tridentate protecting motifs with u3-S

    NASA Astrophysics Data System (ADS)

    Tian, Zhimei; Cheng, Longjiu

    2015-12-01

    Density functional theory calculations have been performed to study the experimentally synthesized Au30S(SR)18 and two related Au30(SR)18 and Au30S2(SR)18 clusters. The patterns of thiolate ligands on the gold cores for the three thiolate-protected Au30 nanoclusters are on the basis of the ``divide and protect'' concept. A novel extended protecting motif with u3-S, S(Au2(SR)2)2AuSR, is discovered, which is termed the tridentate protecting motif. The Au cores of Au30S(SR)18, Au30(SR)18 and Au30S2(SR)18 clusters are Au17, Au20 and Au14, respectively. The superatom-network (SAN) model and the superatom complex (SAC) model are used to explain the chemical bonding patterns, which are verified by chemical bonding analysis based on the adaptive natural density partitioning (AdNDP) method and aromatic analysis on the basis of the nucleus-independent chemical shift (NICS) method. The Au17 core of the Au30S(SR)18 cluster can be viewed as a SAN of one Au6 superatom and four Au4 superatoms. The shape of the Au6 core is identical to that revealed in the recently synthesized Au18(SR)14 cluster. The Au20 core of the Au30(SR)18 cluster can be viewed as a SAN of two Au6 superatoms and four Au4 superatoms. The Au14 core of Au30S2(SR)18 can be regarded as a SAN of two pairs of two vertex-sharing Au4 superatoms. Meanwhile, the Au14 core is an 8e-superatom with 1S21P6 configuration. Our work may aid understanding and give new insights into the chemical synthesis of thiolate-protected Au clusters.Density functional theory calculations have been performed to study the experimentally synthesized Au30S(SR)18 and two related Au30(SR)18 and Au30S2(SR)18 clusters. The patterns of thiolate ligands on the gold cores for the three thiolate-protected Au30 nanoclusters are on the basis of the ``divide and protect'' concept. A novel extended protecting motif with u3-S, S(Au2(SR)2)2AuSR, is discovered, which is termed the tridentate protecting motif. The Au cores of Au30S(SR)18, Au30(SR)18 and Au30S

  19. CW laser pumped emerald laser

    SciTech Connect

    Shand, M.L.; Lai, S.T.

    1984-02-01

    A CW laser-pumped emerald laser is reported. A 34 percent output power slope efficiency is observed with longitudinal pumping by a krypton laser in a nearly concentric cavity. The laser has been tuned from 728.8 to 809.0 nm. Losses in emerald are larger than those of alexandrite determined in a similar cavity. The present data also indicate that the excited state absorption minimum is shifted from that of alexandrite. 13 references.

  20. Cutaneous lasers.

    PubMed

    Fedok, Fred G; Garritano, Frank; Portela, Antonio

    2013-02-01

    There has been a remarkable development and evolution of laser technology, leading to adaptation of lasers for medical use and the treatment of skin problems and disorders. Many treatments that required incisional surgery and other invasive methods are now preferentially treated with a laser. Although laser advances have resulted in the availability of some amazing tools, they require the clinical skill and judgment of the clinician for their optimal use. This article provides a clinically oriented overview of many of the lasers valuable in facial plastic surgery. Basic science, clinical adaptations, and patient management topics are covered.

  1. Laser device

    DOEpatents

    Scott, Jill R.; Tremblay, Paul L.

    2004-11-23

    A laser device includes a target position, an optical component separated a distance J from the target position, and a laser energy source separated a distance H from the optical component, distance H being greater than distance J. A laser source manipulation mechanism exhibits a mechanical resolution of positioning the laser source. The mechanical resolution is less than a spatial resolution of laser energy at the target position as directed through the optical component. A vertical and a lateral index that intersect at an origin can be defined for the optical component. The manipulation mechanism can auto align laser aim through the origin during laser source motion. The laser source manipulation mechanism can include a mechanical index. The mechanical index can include a pivot point for laser source lateral motion and a reference point for laser source vertical motion. The target position can be located within an adverse environment including at least one of a high magnetic field, a vacuum system, a high pressure system, and a hazardous zone. The laser source and an electro-mechanical part of the manipulation mechanism can be located outside the adverse environment. The manipulation mechanism can include a Peaucellier linkage.

  2. Laser device

    DOEpatents

    Scott, Jill R.; Tremblay, Paul L.

    2007-07-10

    A laser device includes a target position, an optical component separated a distance J from the target position, and a laser energy source separated a distance H from the optical component, distance H being greater than distance J. A laser source manipulation mechanism exhibits a mechanical resolution of positioning the laser source. The mechanical resolution is less than a spatial resolution of laser energy at the target position as directed through the optical component. A vertical and a lateral index that intersect at an origin can be defined for the optical component. The manipulation mechanism can auto align laser aim through the origin during laser source motion. The laser source manipulation mechanism can include a mechanical index. The mechanical index can include a pivot point for laser source lateral motion and a reference point for laser source vertical motion. The target position can be located within an adverse environment including at least one of a high magnetic field, a vacuum system, a high pressure system, and a hazardous zone. The laser source and an electro-mechanical part of the manipulation mechanism can be located outside the adverse environment. The manipulation mechanism can include a Peaucellier linkage.

  3. Laser ignition

    DOEpatents

    Early, James W.; Lester, Charles S.

    2003-01-01

    In the apparatus of the invention, a first excitation laser or other excitation light source is used in tandem with an ignitor laser to provide a compact, durable, engine deployable fuel ignition laser system. Reliable fuel ignition is provided over a wide range of fuel conditions by using a single remote excitation light source for one or more small lasers located proximate to one or more fuel combustion zones. In a third embodiment, alternating short and long pulses of light from the excitation light source are directed into the ignitor laser. Each of the embodiments of the invention can be multiplexed so as to provide laser light energy sequentially to more than one ignitor laser.

  4. Surface water data at Los Alamos National Laboratory: 1996 water year. Progress report

    SciTech Connect

    Shaull, D.A.; Alexander, M.R.; Reynolds, R.P.; McLean, C.T.

    1996-11-01

    The principle investigators collected and computed surface water discharge data from 17 stream-gaging stations that cover most of Los Alamos National Laboratory. The data show less runoff than do data for the 1995 water year. Water chemistry data from larger storm events occurring at some stations are also published here.

  5. Determination of 100-year floodplain elevations at Los Alamos National Laboratory

    SciTech Connect

    McLin, S.G.

    1992-08-01

    Under existing permit requirements. the US Environmental Protection Agency stipulates that facilities regulated by the Resource Conservation and Recovery Act must delineate all 100-yr floodplain elevations within their boundaries. At Los Alamos these floodplains are located within ungaged watersheds that drain Pajarito Plateau. This report documents the floodplain computational mapping procedure and, along with supporting maps, is untended to satisfy this permit requirement.

  6. Los Alamos flux comperssion systems, ASI focus area I program plan

    SciTech Connect

    Goforth, James H; Heger, Sharif

    2010-12-14

    This document is a final summary of an original plan submitted as LA-UR 10-06693. There are minor revisions, some new items have been completed, and there is a statement of some funding shortfalls. Program plan focuses on using Ranchero Technology for the ASI 43 cm Ranchero generators are being fabricated to provide a small scale load and diagnostics test capability at Los Alamos - LLNL loads and Los Alamos multi-shell loads. 43 cm Ranchero tests continue as long as they are useful. 1 or 1.4 m Ranchero tests follow in the out years - Multi-shell loads have identified needs for full length generators and one 1.4 m generator is on hand. Both LLNL and Los Alamos loads will require larger current capability, and Ranchero will be scaled up in diameter when full scale current is defined. Increased scale tests expected in FY-12. The bulk of the Los Alamos Effort will be directed toward two thrusts: (1) Perform tests for LLNL load development and (2) explore multi-shell loads. ASC program assesses development against ASI results then provides new designs.

  7. Calculation of Moments from Measurements by the Los Alamos Magnetospheric Plasma Analyzer

    SciTech Connect

    M. F. Thomsen; E. Noveroske; J. E. Borovsky; D. J. McComas

    1999-05-01

    The various steps involved in computing the moments (density, velocity, and temperature) of the ion and electron distributions measured with the Los Alamos Magnetospheric Plasma Analyzer (MPA) are described. The assumptions, constants, and algorithms contained in the FORTRAN code are presented, as well as the output parameters produced by the code.

  8. IMPACTS OF DRILLING ADDITIVES ON DATA OBTAINED FROM HYDROGEOLOGIC CHARACTERIZATION WELLS AT LOS ALAMOS NATIONAL LABORATORY

    EPA Science Inventory

    Personnel at the EPA Ground Water and Ecosystems Restoration Division (GWERD) were requested by EPA Region 6 to evaluate the impacts of well drilling practices at the Los Alamos National Laboratory (LANL). The focus of this review involved analysis of the impacts of bentonite- a...

  9. Simplifying Complexity: Miriam Blake--Los Alamos National Laboratory Research Library, NM

    ERIC Educational Resources Information Center

    Library Journal, 2004

    2004-01-01

    The holy grail for many research librarians is one-stop searching: seamless access to all the library's resources on a topic, regardless of the source. Miriam Blake, Library Without Walls Project Leader at Los Alamos National laboratory (LANL), is making this vision a reality. Blake is part of a growing cadre of experts: a techie who is becoming a…

  10. Surface Water Data at Los Alamos National Laboratory: 1999 Water Year

    SciTech Connect

    D. A. Shaull; M. R. Alexander; R. P. Reynolds; C. T. McLean; R. P. Romero

    2000-04-01

    The principal investigators collected and computed surface water discharge data from 22 stream-gaging stations that cover most of Los Alamos National Laboratory with one at Bandelier National Monument. Also included are discharge data from three springs that flow into Canon de Valle and nine partial-record storm water stations.

  11. Surface Water Data at Los Alamos National Laboratory 2000 Water Year

    SciTech Connect

    D.A.Shaull; M.R.Alexander; R.P.Reynolds; R.P.Romero; E.T.Riebsomer; C.T.McLean

    2001-06-02

    The principal investigators collected and computed surface water discharge data from 23 stream-gaging stations that cover most of Los Alamos National Laboratory and one at Bandelier National Monument. Also included are discharge data from three springs, two that flow into Canon del Valle and one that flows into Water Canyon.

  12. Surface Water Data at Los Alamos National Laboratory 2006 Water Year

    SciTech Connect

    R.P. Romero, D. Ortiz, G. Kuyumjian

    2007-08-01

    The principal investigators collected and computed surface water discharge data from 44 stream-gaging stations that cover most of Los Alamos National Laboratory and one at Bandelier National Monument. Also included are discharge data from three springs--two that flow into Canon de Valle and one that flows into Water Canyon--and peak flow data for 44 stations.

  13. Surface Water Data at Los Alamos National Laboratory: 2002 Water Year

    SciTech Connect

    D.A. Shaull; D. Ortiz; M.R. Alexander; R.P. Romero

    2003-03-03

    The principal investigators collected and computed surface water discharge data from 34 stream-gaging stations that cover most of Los Alamos National Laboratory and one at Bandelier National Monument. Also included are discharge data from three springs--two that flow into Canon de Valle and one that flows into Water Canyon--and peak flow data from 16 stations.

  14. A relational database system for the maintenance and verification of the Los Alamos sequence library.

    PubMed Central

    Kanehisa, M; Fickett, J W; Goad, W B

    1984-01-01

    The nucleic acid sequence databases of Los Alamos National Laboratory, European Molecular Biology Laboratory, and others are organized in a single relational database. This organization with a suitable relational database management program facilitates the tasks of reporting statistics, making cross-references, and double-checking of the original databases. PMID:6694899

  15. A Wildfire Behavior Modeling System at Los Alamos National Laboratory for Operational Applications

    SciTech Connect

    S.W. Koch; R.G.Balice

    2004-11-01

    To support efforts to protect facilities and property at Los Alamos National Laboratory from damages caused by wildfire, we completed a multiyear project to develop a system for modeling the behavior of wildfires in the Los Alamos region. This was accomplished by parameterizing the FARSITE wildfire behavior model with locally gathered data representing topography, fuels, and weather conditions from throughout the Los Alamos region. Detailed parameterization was made possible by an extensive monitoring network of permanent plots, weather towers, and other data collection facilities. We also incorporated a database of lightning strikes that can be used individually as repeatable ignition points or can be used as a group in Monte Carlo simulation exercises and in other randomization procedures. The assembled modeling system was subjected to sensitivity analyses and was validated against documented fires, including the Cerro Grande Fire. The resulting modeling system is a valuable tool for research and management. It also complements knowledge based on professional expertise and information gathered from other modeling technologies. However, the modeling system requires frequent updates of the input data layers to produce currently valid results, to adapt to changes in environmental conditions within the Los Alamos region, and to allow for the quick production of model outputs during emergency operations.

  16. A review of the Los Alamos effort in the development of nuclear rocket propulsion

    SciTech Connect

    Durham, F.P.; Kirk, W.L.; Bohl, R.J.

    1991-01-01

    This paper reviews the achievements of the Los Alamos nuclear rocket propulsion program and describes some specific reactor design and testing problems encountered during the development program along with the progress made in solving these problems. The relevance of these problems to a renewed nuclear thermal rocket development program for the Space Exploration Initiative (SEI) is discussed. 11 figs.

  17. 75 FR 1793 - Study Team for the Los Alamos Historical Document Retrieval and Assessment (LAHDRA) Project

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-01-13

    ... HUMAN SERVICES Centers for Disease Control and Prevention Study Team for the Los Alamos Historical..., the Department of Health and Human Services (HHS) was given the responsibility and resources for... progress to date, provide a forum for community interaction, and serve as a vehicle for members of...

  18. Long-Range Strategic Planning for the Alamo Community College District. Position Papers.

    ERIC Educational Resources Information Center

    McClenney, Byron N.; Moore, Kay M.

    Prepared for use in long-range planning in the Alamo Community College District (ACCD), this report presents an overview of the District and position papers containing data and interpretive discussion on five planning concerns. Following an overview of ACCD enrollments, personnel, and finances, the first position paper outlines population…

  19. Los Alamos National Laboratory Training Capabilities (Possible Applications in the Global Initiatives for Proliferation Prevention Program)

    SciTech Connect

    Martin, Olga

    2012-06-04

    The briefing provides an overview of the training capabilities at Los Alamos National Laboratory that can be applied to nonproliferation/responsible science education at nuclear institutes in the Former Soviet Union, as part of the programmatic effort under the Global Initiatives for Proliferation Prevention program (GIPP).

  20. Multi-pulse extraction from Los Alamos Proton Storage Ring for radiographic applications

    SciTech Connect

    Thiessen, H.A.; Neri, F.; Rust, K.; Redd, D.B.

    1997-08-01

    In Proton Radiography, one of the goals is a motion picture of a rapidly moving object. The Los Alamos Proton Storage Ring (PSR) in its normal operating mode, delivers a single pulse approximately 120 ns wide (fwhm). In development runs at the PSR, the authors successfully demonstrated operation of a technique to deliver two pulses, each 40 nsec wide, with adjustable spacing.

  1. Mapping the future of CIC Division, Los Alamos National Laboratory. Final report

    SciTech Connect

    1996-01-01

    This report summarizes three scenario-based strategic planning workshops run for the CIC Division of the Los Alamos National Laboratory during November and December, 1995. Each of the two-day meetings was facilitated by Northeast Consulting Resources, Inc. (NCRI) of Boston, MA. using the Future Mapping{reg_sign} methodology.

  2. The Los Alamos primer: The first lectures on how to build an atomic bomb

    SciTech Connect

    Serber, R.; Rhodes, R.

    1992-01-01

    When the work on the atomic bomb was started in Los Alamos, a series of 5 lectures by Robert Serber, presented what was then known about the physics of nuclear explosions. Some supplemental material has been added to the basic lectures. The book is not for the non-physicist, remaining mathamatical and using many basic concepts of physics.

  3. 75 FR 72829 - Los Alamos Historical Document Retrieval and Assessment (LAHDRA) Project

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-11-26

    ..., Public Health Advisor, Radiation Studies Branch, Division of Environmental Hazards and Health Effects... HUMAN SERVICES Centers for Disease Control and Prevention Los Alamos Historical Document Retrieval and... of Health and Human Services (HHS) was given the responsibility and resources for conducting...

  4. Commercialization of Los Alamos National Laboratory technologies via small businesses. Final report

    SciTech Connect

    Brice, R.; Cartron, D.; Rhyne, T.; Schulze, M.; Welty, L.

    1997-06-01

    Over the past decade, numerous companies have been formed to commercialize research results from leading U.S. academic and research institutions. Emerging small businesses in areas such as Silicon Valley, Boston`s Route 128 corridor, and North Carolina`s Research Triangle have been especially effective in moving promising technologies from the laboratory bench to the commercial marketplace--creating new jobs and economic expansion in the process. Unfortunately, many of the U.S. national laboratories have not been major participants in this technology/commercialization activity, a result of a wide variety of factors which, until recently, acted against successful commercialization. This {open_quotes}commercialization gap{close_quotes} exists partly due to a lack, within Los Alamos in particular and the DOE in general, of in-depth expertise and experience in such business areas as new business development, securities regulation, market research and the determination of commercial potential, the identification of entrepreneurial management, marketing and distribution, and venture capital sources. The immediate consequence of these factors is the disappointingly small number of start-up companies based on technologies from Los Alamos National Laboratory that have been attempted, the modest financial return Los Alamos has received from these start-ups, and the lack of significant national recognition that Los Alamos has received for creating and commercializing these technologies.

  5. Los Alamos neutron science user facility - control system risk mitigation & updates

    SciTech Connect

    Pieck, Martin

    2011-01-05

    LANSCE User Facility is seeing continuing support and investments. The investment will sustain reliable facility operations well into the next decade. As a result, the LANSCE User Facility will continue to be a premier Neutron Science Facility at the Los Alamos National Laboratory.

  6. Produce and fish sampling program of Los Alamos National Laboratory's Environmental Surveillance Group

    SciTech Connect

    Salazar, J.G.

    1984-09-01

    This report describes produce and fish sampling procedures of the Environmental Surveillance Group at the Los Alamos National Laboratory. The program monitors foodstuffs and fish for possible radioactive contamination from Laboratory operations. Data gathered in this program on radionuclide concentrations help to estimate radiation doses to Laboratory personnel and the public. 3 references, 7 figures, 2 tables.

  7. Leading Change: A Case Study of Alamo Academies--An Industry-Driven Workforce Partnership Program

    ERIC Educational Resources Information Center

    Hu, Xiaodan; Bowman, Gene

    2016-01-01

    In this study, the authors focus on the initiation and development of the Alamo Academies, aiming to illustrate an exemplary industry-driven model that addresses workforce development in local community. After a brief introduction of the context, the authors summarized major factors that contribute to the success of the collaboration model,…

  8. Los Alamos compact toroid, fast-liner, and high-density Z-pinch programs

    SciTech Connect

    Linford, R.K.; Sherwood, A.R.; Hammel, J.E.

    1981-03-01

    The Compact Toroid (CT) and High Density Z-Pinch (HDZP) are two of the plasma configurations presently being studied at Los Alamos. The purpose of these two programs, plus the recently terminated (May 1979) Fast Liner (FL) program, is summarized in this section along with a brief description of the experimental facilities. The remaining sections summarize the recent results and the experimental status.

  9. Frequency Estimates for Aircraft Crashes into Nuclear Facilities at Los Alamos National Laboratory (LANL)

    SciTech Connect

    George D. Heindel

    1998-09-01

    In October 1996, the Department of Energy (DOE) issued a new standard for evaluating accidental aircraft crashes into hazardous facilities. This document uses the method prescribed in the new standard to evaluate the likelihood of this type of accident occurring at Los Alamos National Laboratory's nuclear facilities.

  10. Los Alamos Scientific Laboratory waste management technology development activities. Summary progress report, 1979

    SciTech Connect

    Johnson, L.J.

    1980-10-01

    Summary reports on the Department of Energy's Nuclear Energy-sponsored waste management technology development projects at the Los Alamos Scientific Laboratory describe progress for calendar year 1979. Activities in airborne, low-level, and transuranic waste management areas are discussed. Work progress on waste assay, treatment, disposal, and environmental monitoring is reviewed.

  11. The LASL program in nuclear pumped liquid lasers

    NASA Technical Reports Server (NTRS)

    Mansfield, C. R.; Bird, P. F.; Davis, J. F.

    1979-01-01

    The development of nuclear-pumped, liquid-based lanthanide ion lasers is discussed. Early investigations of lanthanide ion lasers have lead to solid-state and gaseous neodymium lasers, and a demonstration of lasing in the liquid state. Solvents containing organic chelating agents have been employed in liquid Eu(+3) and Tb(+3) lasers to extend fluorescence lifetimes, however aprotic solvents have been found to enable the development of large-scale liquid lasers. The advantages to be gained from high-power nuclear-pumped lasers based on lanthanide solutions include the high density of fissile materials possible, and a nuclear pumping cell which can operate in either a nuclear or optical pumping mode is being fabricated at the Los Alamos Scientific Laboratory to investigate the nuclear pumping of liquid lanthanide ion lasers. Areas that need exploration before specific laser design features can be considered include energy channeling within the liquid upon excitation, radiation damage due to solvent dissociation, and reactor technology for the development of a self-critical liquid reactor.

  12. Relativistic transparency and non-axisymmetry of laser-accelerated ion beams from the Break-Out Afterburner

    NASA Astrophysics Data System (ADS)

    Albright, B. J.; Yin, L.; Bowers, Kevin J.; Huang, Chengkun; Jung, D.; Fernández, J. C.; Hegelich, B. M.

    2010-11-01

    In the Break-Out Afterburner (BOA) ion acceleration mechanism [1], an ultraintense, ultrahigh contrast laser interacts with a nano-scale, solid-density target, which expands as the electrons under the laser spot heat to relativistic temperatures. When the electron density drops below the relativistic critical density, the target turns transparent and a period of enhanced ion acceleration, called the Break Out Afterburner, ensues. A large (tens of TeV), longitudinal electric field forms that co-moves with the target ions. A defining features of the BOA, as seen in VPIC kinetic plasma simulations and observed in experiments at the LANL Trident laser facility, is that the ion beams form as a pair of lobes with density and energy possessing maxima in the direction orthogonal to the laser polarization. This paper will focus on analytic theory explaining how these lobes form as a consequence of subtle effects of the laser ponderomotive force. [1] Yin et al. Laser and Part. Beams 24, 2, 291 (2006).

  13. Advanced flat top laser heating system for high pressure research at GSECARS: application to the melting behavior of germanium

    SciTech Connect

    Prakapenka, V.B.; Kubo, A.; Kuznetzov, A.; Laskin, A.; Shkurkhin, O.; Dera, P.; Rivers, M.L.; Sutton, S.R.

    2008-09-29

    Laser heating plays an essential role for in-situ high pressure high temperature studies into the physical and chemical properties of materials in the diamond anvil cell (DAC) and minerals at conditions relevant to the Earth's deep interior. High temperature experiments in the multi-Mbar (over 100 GPa) pressure range require the use of very small samples and consequently the utmost stability and controllability of the laser heating is crucial. To accomplish this, we have modified the laser heating system at GSECARS employing newly developed beam shaping optics combined with two diode-pumped, single mode fiber lasers. Varying the settings of the laser heating system, we were able to shape the beam to almost any desired intensity profile and size on the surface of the sample in the DAC, including tight focus, flat top, trident and doughnut types. The advantages and excellent performance of the flat top laser heating (FTLH) technique were demonstrated in melting experiments on germanium in the DAC at pressures up to 40 GPa.

  14. A spectroscopic investigation of a tridentate Cu-complex mimicking the tyrosine-histidine cross-link of cytochrome C oxidase.

    PubMed

    Offenbacher, Adam; White, Kimberly N; Sen, Indranil; Oliver, Allen G; Konopelski, Joseph P; Barry, Bridgette A; Einarsdóttir, Olöf

    2009-05-21

    Heme-copper oxidases have a crucial role in the energy transduction mechanism, catalyzing the reduction of dioxygen to water. The reduction of dioxygen takes place at the binuclear center, which contains heme a3 and CuB. The X-ray crystal structures have revealed that the C6' of tyrosine 244 (bovine heart numbering) is cross-linked to a nitrogen of histidine 240, a ligand to CuB. The role of the cross-linked tyrosine at the active site still remains unclear. In order to provide insight into the function of the cross-linked tyrosine, we have investigated the spectroscopic and electrochemical properties of chemical analogues of the CuB-His-Tyr site. The analogues, a tridentate histidine-phenol cross-linked ether ligand and the corresponding Cu-containing complex, were previously synthesized in our laboratory (White, K.; et al. Chem. Commun. 2007, 3252-3254). Spectrophotometric titrations of the ligand and the Cu-complex indicate a pKa of the phenolic proton of 8.8 and 7.7, respectively. These results are consistent with the cross-linked tyrosine playing a proton delivery role at the cytochrome c oxidase active site. The presence of the phenoxyl radical was investigated at low temperature using electron paramagnetic resonance (EPR) and Fourier transform infrared (FT-IR) difference spectroscopy. UV photolysis of the ligand, without bound copper, generated a narrow g=2.0047 signal, attributed to the phenoxyl radial. EPR spectra recorded before and after UV photolysis of the Cu-complex showed a g=2 signal characteristic of oxidized copper, suggesting that the copper is not spin-coupled to the phenoxyl radical. An EPR signal from the phenoxyl radical was not observed in the Cu-complex, either due to spin relaxation of the two unpaired electrons or to masking of the narrow phenoxyl radical signal by the strong copper contribution. Stable isotope (13C) labeling of the phenol ring (C1') Cu-complex, combined with photoinduced difference FT-IR spectroscopy, revealed bands at

  15. A SPECTROSCOPIC INVESTIGATION OF A TRIDENTATE Cu-COMPLEX MIMICKING THE TYROSINE-HISTIDINE CROSS-LINK OF CYTOCHROME c OXIDASE

    PubMed Central

    Offenbacher, Adam; White, Kimberley N.; Sen, Indranil; Oliver, Allen G.; Konopelski, Joseph P.; Barry, Bridgette A.

    2009-01-01

    Heme-copper oxidases have a crucial role in energy transduction mechanism, catalyzing the reduction of dioxygen to water. The reduction of dioxygen takes place at the binuclear center, which contains heme a3 and CuB. The X-ray crystal structures have revealed that the C6' of tyrosine 244 (bovine heart numbering) is cross-linked to a nitrogen of histidine 240, a ligand to CuB. The role of the cross-linked tyrosine at the active site still remains unclear. In order to provide insight into the function of the cross-linked tyrosine, we have investigated the spectroscopic and electrochemical properties of chemical analogs of the CuB-His-Tyr site. The analogs, a tridentate histidine-phenol cross-linked ether ligand and the corresponding Cu-containing complex, were previously synthesized in our laboratory (White K. et al.; Chem. Commun. 3252–3254, 2007). Spectrophotometric titrations of the ligand and the Cu-complex indicate a pKA of the phenolic proton of 8.8 and 7.7, respectively. These results are consistent with the cross-linked tyrosine playing a proton delivery role at the cytochrome oxidase active site. The presence of the phenoxyl radical was investigated at low temperature using electron paramagnetic resonance (EPR) and Fourier transform infrared (FT-IR) difference spectroscopy. UV-photolysis of the ligand, without bound copper, generated a narrow g = 2.0047 signal, attributed to the phenoxyl radial. EPR spectra recorded before and after UV photolysis of the Cu-complex showed a g = 2 signal characteristic of oxidized copper, suggesting that the copper is not spin-coupled to the phenoxyl radical. An EPR signal from the phenoxyl radical was not observed in the Cu-complex, either due to spin relaxation of the two unpaired electrons or to masking of the narrow phenoxyl radical signal by the strong copper contribution. Stable isotope (13C) labeling of the phenol ring (C1') Cu-complex, combined with photo-induced difference FT-IR-spectroscopy, revealed bands at 1485

  16. Bis(alkyl) rare-earth complexes supported by a new tridentate amidinate ligand with a pendant diphenylphosphine oxide group. Synthesis, structures and catalytic activity in isoprene polymerization.

    PubMed

    Tolpygin, Aleksei O; Glukhova, Tatyana A; Cherkasov, Anton V; Fukin, Georgy K; Aleksanyan, Diana V; Cui, Dongmei; Trifonov, Alexander A

    2015-10-01

    A new tridentate amidine 2-[Ph2P(O)]C6H4NHC(tBu)[double bond, length as m-dash]N(2,6-Me2C6H3) (1) bearing a side chain pendant Ph2P[double bond, length as m-dash]O group was synthesized and proved to be a suitable ligand for coordination to rare-earths ions. Bis(alkyl) complexes {2-[Ph2P(O)]C6H4NC(tBu)N(2,6-Me2C6H3)}Ln(CH2SiMe3)2(THF)n (Ln = Y, n = 1 (3), Ln = Er, n = 1 (4), Ln = Lu, n = 0 (5)) were prepared using alkane elimination reactions of and Ln(CH2SiMe3)3(THF)2 (Ln = Y, Er, Lu) in hexane and were isolated in 50, 70 and 75% yields respectively. The X-ray studies revealed that complexes 2-5 feature intramolecular coordination of P[double bond, length as m-dash]O groups to metal ions. The lutetium complex 5 proved to be rather stable: at 20 °C its half-life time is 1155 h, while for the yttrium analogue the half-life time was found to be 63 h. Complexes 3-5 were evaluated as precatalysts for isoprene polymerization. The systems Ln/borate/AliBu3 (Ln = 3-5, borate = [PhNHMe2][B(C6F5)4], [Ph3C][B(C6F5)4]) turned out to be highly efficient in isoprene polymerization and enable complete conversion of 1000-10,000 equivalents of monomer into polymer at 20 °C within 0.5-2.5 h affording polyisoprenes with a very high content of 1,4-cis units (up to 96.6%) and from narrow (1.49) to moderate (3.54) polydispersities. A comparative study of catalytic performance of the related bis(alkyl) yttrium complexes supported by amidinate ligands of different denticities and structures [tBuC(N-2,6iPr2C6H4)2](-), [tBuC(N-2,6-iPr2C6H4)(N-2-MeOC6H4)](-) and {2-[Ph2P(O)]C6H4NC(tBu)N(2,6-Me2C6H3)}(-) demonstrated that the introduction of a pendant donor group (2-MeOC6H4 or Ph2P(O)) into a side chain of amidinate scaffolds results in a significant increase in catalytic activity. The amidinate ligand bearing a Ph2P(O)-group provides a high isoprene polymerization rate along with excellent control over regio- and stereoselectivities and allows us to obtain polyisoprenes with a reasonable

  17. Iron and chromium complexes containing tridentate chelates based on nacnac and imino- and methyl-pyridine components: triggering C-X bond formation.

    PubMed

    Morris, Wesley D; Wolczanski, Peter T; Sutter, Jörg; Meyer, Karsten; Cundari, Thomas R; Lobkovsky, Emil B

    2014-07-21

    Nacnac-based tridentate ligands containing a pyridyl-methyl and a 2,6-dialkyl-phenylamine (i.e., (2,6-R2-C6H3N═C(Me)CH═C(Me)NH(CH2py); R = Et, {Et(nn)PM}H; R = (i)Pr, {(i)Pr(nn)PM}H) were synthesized by condensation routes. Treatment of M{N(TMS)2}THFn (M = Cr, n = 2; M = Fe, Co, n = 1; TMS = trimethylsilane; THF = tetrahydrofuran) with {(i)Pr(nn)PM}H) afforded {(i)Pr(nn)PM}MN(TMS)2 (1-M(iPr); M = Cr, Fe); {Et(nn)PM}MN(TMS)2 (1-M(Et); M = Fe, Co) was similarly obtained. {R(nn)PM}FeBr (R = (i)Pr, Et; 2-Fe(R)) were prepared from FeBr2 and {R(nn)PM}Li, and alkylated to generate {R(nn)PM}Fe(neo)Pe (R = (i)Pr, Et; 3-Fe(R)). Carbonylation of 3-Fe(R) provided {(i)Pr(nn)PM}Fe(CO(neo)Pe)CO (4-Fe(iPr)), and carbonylations of 1-Fe(R) (R = Et, (i)Pr) and 1-Cr(iPr) induced deamination to afford {R(nn)PI}Fe(CO)2 (R = (i)Pr, 5-Fe(iPr); Et, 5-Fe(Et)), where PI is pyridine-imine, and {κ(2)-N,N-pyrim-pyr}Cr(CO)4 (6-Cr(iPr)), in which the aryl-amide side of the nacnac attacked the incipient PI group. Carbon-carbon bonds were formed at the imine carbon of the {R(nn)PI} ligand. Addition of [{(i)Pr(nn)PI}(2-)](K(+)(THF)x)2 to FeCl3 generated {(i)Pr(nn)CHpy}2Fe2Cl2 (7-Fe(iPr)), and TMSN3 induced the deamination of 1-Fe(Et), but with disproportionation to provide {[Et(nn)CHpy]2}Fe (8-Fe(Et)). Ph2CN2 induced C-C bond formation with 1-Fe(iPr) via its thermal degradation to ultimately afford {(i)Pr(nn)CHpy}2(FeN═CPh2)2 (9-Fe(iPr)). The compounds were examined by X-ray crystallography (1-M(iPr), M = Cr, Fe; 1-Co(Et); 2-Fe(iPr); 4-Fe(iPr); 5-Fe(iPr); 6-Cr(iPr); 7-Fe(iPr); 8-Fe(Et); 9-Fe(iPr)), Mössbauer spectroscopy, and NMR spectroscopy. Structural parameters assessing redox noninnocence are discussed, as are structural and mechanistic consequences of the various electronic environments.

  18. Laser Systems

    NASA Technical Reports Server (NTRS)

    1985-01-01

    Tunable diode lasers are employed as radiation sources in high resolution infrared spectroscopy to determine spectral characteristics of gaseous compounds. With other laser systems, they are produced by Spectra-Physics, and used to monitor chemical processes, monitor production of quantity halogen lamps, etc. The Laser Analytics Division of Spectra-Physics credits the system's reliability to a program funded by Langley in the 1970s. Company no longer U.S.-owned. 5/22/97

  19. All-Solid-State Four-Color Laser

    SciTech Connect

    Gosnell, T.R.; Xie, P.

    1999-06-03

    This is the final report of a three-year, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). The goal of this project is to develop a solid state laser that produces visible output wavelengths, including the commercially compelling blue wavelength. The basic architecture of the device consists of a single-mode optical fiber doped with Pr{sup 3+} and Yb{sup 3+} ions. When the ions are simultaneously pumped with a near infrared laser (860 nm), complex energy transfer processes involving multiple excited ions leads to population of a high-lying energy level of Pr{sup 3+}. Results include the demonstration of the existence of a photon avalanche mechanism responsible for creation of the population inversion and demonstration of the highest optical-to-optical efficiency of any up-conversion laser reported to date. A US Patent was awarded for this invention in 1998.

  20. Biocavity Lasers

    SciTech Connect

    Gourley, P.L.; Gourley, M.F.

    2000-10-05

    Laser technology has advanced dramatically and is an integral part of today's healthcare delivery system. Lasers are used in the laboratory analysis of human blood samples and serve as surgical tools that kill, burn or cut tissue. Recent semiconductor microtechnology has reduced the size o f a laser to the size of a biological cell or even a virus particle. By integrating these ultra small lasers with biological systems, it is possible to create micro-electrical mechanical systems that may revolutionize health care delivery.