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Sample records for alberta tar sands

  1. Is promise of Alberta's tar sands nearing reality

    SciTech Connect

    Stauffer, T.

    1993-10-15

    Alberta's far north shares a vital element with Saudi Arabia: Many hundreds of billions of barrels of oil. The Energy Resources and Conservation Board counts one trillion barrels, four to five times above Saudi Arabia's reserves. To date, though, it has not been economic to tap these reserves, which are in the form of tar sands. Now, however, a new process, proven at the pilot stage, finally may transform these resources into a possible competitor to OPEC. Its unpronounceable acronym, SAGD, stands for steam-assisted gravity drainage. The SAGD technique involves a couple of major innovations. First, it reverses the traditional approach. Instead of mining the sands from the surface downward, the systems developed and proven by the Alberta Oil Sands Technology and Research Authority (AOSTRA) starts from the bottom up. The oil is produced from underneath the bedded tar sands. Second, the system is intrinsically small scale. It does not rely upon megaprojects to try to realize economies of scale. The earlier surface-mining projects were sized at 100,000-200,000 barrels per day (b/d). In contrast, the optimum economic scale of the SAGD system is roughly 30,000 b/d, making it a more manageable and less risky technology. SAGD involves the marriage of conventional shaft and tunnel mining with the new precision possible in horizontal drilling. The cost savings are dramatic, and the environmental insult from the operation is greatly reduced. Instead of stripping overburden and then strip-mining the tarry sands, the SAGD technique starts underground with tunnels drilled beneath the tar sands strata. From the tunnels, pairs of horizontal wells are drilled up into the beds. Steam injected into the upper well fluidizes the tar, creating a void, from which the liquid tar flows down into the lower producing well.

  2. Tar sands

    SciTech Connect

    Wennekers, J.H.N.

    1981-10-01

    The four largest oil sand deposits contain over 90% of the world's known heavy oil. The total heavy oil and bitumen in place, estimated at nearly 6 trillion barrels is almost entirely concentrated in western Canada, principally Alberta, and eastern Venezuela. The known tar sand resource in the United States consists of about 550 occurrences located in 22 states. The total oil in place in 39 of these occurrences is estimated to be between 23.7 billion and 32.7 billion barrels. At least 90% of this resource is located in Utah. Other significant deposits are in Texas, New Mexico, California, and Kentucky. Bituminous sand deposits and petroleum-impregnated rocks are found in Malagasy, Albania, Rumania, the USSR, and Trinidad. 4 figures, 2 tables. (DP)

  3. Extracting Oil From Tar Sands

    NASA Technical Reports Server (NTRS)

    Ford, L. B.; Daly, D.

    1984-01-01

    Recovery of oil from tar sands possible by batch process, using steam produced by solar heater. In extraction process, solar heater provides steam for heating solvent boiler. Boiling solvent removes oil from tar sands in Soxhlet extractor.

  4. Treating tar sands formations with karsted zones

    SciTech Connect

    Vinegar, Harold J.; Karanikas, John Michael

    2010-03-09

    Methods for treating a tar sands formation are described herein. The tar sands formation may have one or more karsted zones. Methods may include providing heat from one or more heaters to one or more karsted zones of the tar sands formation to mobilize fluids in the formation. At least some of the mobilized fluids may be produced from the formation.

  5. Treating tar sands formations with dolomite

    SciTech Connect

    Vinegar, Harold J.; Karanikas, John Michael

    2010-06-08

    Methods for treating a tar sands formation are described herein. The tar sands formation may include dolomite and hydrocarbons. Methods may include providing heat at less than the decomposition temperature of dolomite from one or more heaters to at least a portion of the formation. At least some of the hydrocarbon fluids are mobilized in the formation. At least some of the hydrocarbon fluids may be produced from the formation.

  6. Creating fluid injectivity in tar sands formations

    DOEpatents

    Stegemeier, George Leo; Beer, Gary Lee; Zhang, Etuan

    2012-06-05

    Methods for treating a tar sands formation are described herein. Methods for treating a tar sands may include heating a portion of a hydrocarbon layer in the formation from one or more heaters located in the portion. The heat may be controlled to increase the permeability of at least part of the portion to create an injection zone in the portion with an average permeability sufficient to allow injection of a fluid through the injection zone. A drive fluid and/or an oxidizing fluid may be provided into the injection zone. At least some hydrocarbons including mobilized hydrocarbons are produced from the portion.

  7. Creating fluid injectivity in tar sands formations

    SciTech Connect

    Stegemeier, George Leo; Beer, Gary Lee; Zhang, Etuan

    2010-06-08

    Methods for treating a tar sands formation are described herein. Methods for treating a tar sands may include heating a portion of a hydrocarbon layer in the formation from one or more heaters located in the portion. The heat may be controlled to increase the permeability of at least part of the portion to create an injection zone in the portion with an average permeability sufficient to allow injection of a fluid through the injection zone. A drive fluid and/or an oxidizing fluid may be provided into the injection zone. At least some hydrocarbons are produced from the portion.

  8. Nigeria to step up tar sands activity

    SciTech Connect

    Not Available

    1987-03-01

    The Nigerian government has directed its Ministry of Mines, Power and Steel to assume responsibility for the exploration and exploitation of tar sands deposits in Bendel, Ondo and Oyo States. The directive resulted from a survey report by the University of Ife's geological consultancy unit on bituminous sand deposits in the area. The statement said the government was satisfied that there were large commercial quantities of the sands in the three states. The survey had reported that Nigeria could recover between 31 and 40 billion barrels of heavy crude from the tar sand deposits. Exploration for hydrocarbons is currently going on in Anambra and Lake Chad basins as well as the Benue Trough. Apart from the Nigerian National Petroleum Corporation, Shell Petroleum and Gulf Oil have begun exploration activities in the Ondo area. Meanwhile, Nigeria has had to import heavy crude from Venezuela, for processing at the Kaduna refinery.

  9. Solvent extraction of southern US tar sands

    SciTech Connect

    Not Available

    1989-05-01

    The socioeconomic aspects of the tar sands recovery were investigated by Diversified Petroleum Recovery, Inc. Mineral Resources Institute at the University of Alabama conducted characterization and beneficiation studies on Alabama tar sands. Two sources in the state were identified, namely, Black Wax Hill and Spring Creek. Samples were obtained, beneficiated, then shared with the University of Arkansas. The University of Arkansas conducted research in three areas, namely, solvation and characterization of the tar sands phase equilibria as well as the design and operation of a bench-scale batch model. In the solvation studies, the results indicate that grinding the tar sands too fine results in downstream processing problems. Also, preliminary indications are that the beneficiation step may not be necessary in the solvation of the bitumen. The phase equilibria of the heptane/brine/isopropyl alcohol/XTOL{trademark} system is very complex. The salt concentration of the brine is significant in the partitioning of the isopropanol and heptane. Equilibrium data for some of the various combinations of chemical constituents have been obtained. Also included are appendices: statistical data on highways; petrography; Dean-Starke technique; FTIR and NMR spectra; FORTRAN computer program for GC; simulation of flash behavior for IPA/brine/fatty acid/N-C{sub 7} mixture; and previous progress reports. 32 figs., 28 tabs.

  10. Method for filtering solvent and tar sand mixtures

    SciTech Connect

    Kelterborn, J. C.; Stone, R. A.

    1985-09-03

    A method for filtering spent tar sands from a bitumen and organic solvent solution comprises separating the solution into two streams wherein the bulk of the coarser spent tar sand is in a first stream and has an average particle size of about 10 to about 100 mesh and the bulk of the finer spent tar sand is in a second stream; producing a filter cake by filtering the coarser spent tar sand from the first stream; and filtering the finer spent tar sand from the second stream with the filter cake. The method is particularly useful for filtering solutions of bitumen extracted from bitumen containing diatomite, spent diatomite and organic solvent.

  11. Textural characteristics of the Nigerian tar sands

    NASA Astrophysics Data System (ADS)

    Enu, E. I.

    1985-05-01

    Extensive tar sands with reserves of about 41 billion barrels of oil are known to occur in Cretaceous terrigenous sediments in Ondo and Ogun States of Nigeria. The hydrocarbon occurs in two predominantly sandy zones separated by an 8 m thick oil shale. The lower (Horizon Y) is mostly quartz sand, 3-26 m thick. It shows an upward fining of grains and increased consolidation updip. The upper Horizon X is 10-22 m of sandstone with interbedded shales and siltstones. The sands are loosely consolidated. Cementing material is lacking, the grains being held together largely by the tarry oil. Porosity is about 30% and mean oil saturation in both zones is 12%. The recorded clay content (2-7%) is considerably lower than the average for Athabasca, Canada (10-25%) and may enhance the settling properties of the tailing ponds. The sands are water-wet, fine- to medium-grained, moderately well sorted, mesokurtic and positively skewed to near symmetrical. The Nigerian tar sands compare closely with the Athabasca sands in all the above textural parameters. They would thus be expected to show identical response to mining processing, except for the influence of higher ground-water table and the high humidity and ambient temperatures in Nigeria.

  12. Aspects of tar sands development in Nigeria

    SciTech Connect

    Adewusi, V.A. )

    1992-07-01

    Development of Nigerian massive reserves of crude bitumen and associated heavy oil is imminent in view of the impacts that the huge importation of these materials and their products have on the nation's economy, coupled with the depleting reserves of Nigeria and highlights the appropriate production technology options and their environmental implications. The utilization potentials of these resources are also enumerated, as well as the government's role in achieving accelerated, long-term tar sands development in the country.

  13. Solvent extraction of Southern US tar sands

    SciTech Connect

    Penney, W.R.

    1990-01-01

    The Department of Chemical Engineering at the University of Arkansas, in association with Diversified Petroleum Recovery, Inc. (DPR) of Little Rock, Arkansas, has been developing a solvent extraction process for the recovery of bitumen from tar sands for the past five years. The unique feature of the process is that the bitumen is recovered from the solvent by contacting with a co-solvent, which causes the bitumen to precipitate. The overall purpose of this project is to study both the technical and economic feasibility of applying this technology for recovery of bitumen from tar sands by (1) investigating the socioeconmic factors which affect (a) plant siting and (b) the market value of recovered bitumen; (2) operating a process demonstration unit at the rate of 1 lb/hr recovered bitumen while producing clean sand and recyclable solvents; and (3) determine the economic conditions which will make a bitumen recovery project economical. DPR has analyzed the historical trends of domestic production, consumption, discoveries and reserves of crude oil. They have started an investigation of the volatility in the price of crude oil and of gasoline prices and of the differential between gasoline and crude oil. DPR continues to analyze the geographical movement and demand for asphalt products. Utah does not appear economically attractive as a site for a bitumen from tar sands asphalt plant. Oklahoma sites are now being studied. This report also contains the quarterly progress report from a University of Nevada study to determine bitumen composition, oxygen uptake rates, and viscosities of Alabama and Utah bitumens. Both reports have been indexed separately for inclusion on the data base.

  14. 43 CFR 3141.2 - Prelease exploration within Special Tar Sand Areas.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... Sand Areas. 3141.2 Section 3141.2 Public Lands: Interior Regulations Relating to Public Lands... SPECIAL TAR SAND AREAS Leasing in Special Tar Sand Areas § 3141.2 Prelease exploration within Special Tar Sand Areas....

  15. 43 CFR 3141.2 - Prelease exploration within Special Tar Sand Areas.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... Sand Areas. 3141.2 Section 3141.2 Public Lands: Interior Regulations Relating to Public Lands... SPECIAL TAR SAND AREAS Leasing in Special Tar Sand Areas § 3141.2 Prelease exploration within Special Tar Sand Areas....

  16. 43 CFR 3141.2 - Prelease exploration within Special Tar Sand Areas.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... Sand Areas. 3141.2 Section 3141.2 Public Lands: Interior Regulations Relating to Public Lands... SPECIAL TAR SAND AREAS Leasing in Special Tar Sand Areas § 3141.2 Prelease exploration within Special Tar Sand Areas....

  17. 43 CFR 3141.2 - Prelease exploration within Special Tar Sand Areas.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... Sand Areas. 3141.2 Section 3141.2 Public Lands: Interior Regulations Relating to Public Lands... SPECIAL TAR SAND AREAS Leasing in Special Tar Sand Areas § 3141.2 Prelease exploration within Special Tar Sand Areas....

  18. New production techniques for alberta oil sands.

    PubMed

    Carrigy, M A

    1986-12-19

    Low world oil prices represent a serious threat to expanded commercial development of the Canadian oil sands in the near term, as they do to all of the higher cost alternatives to crude oil such as oil shales and coal liquefaction. Nonetheless, research and field testing of new technology for production of oil from oil sands are being pursued by industry and government in Alberta. New production technology is being developed in Canada to produce synthetic oil from the vast resources of bitumen trapped in the oil sands and bituminous carbonates of northern Alberta. This technology includes improved methods of mining, extraction, and upgrading of bitumen from near-surface deposits as well as new drilling and production techniques for thermal production of bitumen from the more deeply buried reservoirs. Of particular interest are the cluster drilling methods designed to reduce surface disturbance and the techniques for horizontal drilling of wells from underground tunnels to increase the contact of injection fluids with the reservoir. PMID:17816505

  19. Heating tar sands formations while controlling pressure

    DOEpatents

    Stegemeier, George Leo [Houston, TX; Beer, Gary Lee [Houston, TX; Zhang, Etuan [Houston, TX

    2010-01-12

    Methods for treating a tar sands formation are described herein. Methods may include heating at least a section of a hydrocarbon layer in the formation from a plurality of heaters located in the formation. A pressure in the majority of the section may be maintained below a fracture pressure of the formation. The pressure in the majority of the section may be reduced to a selected pressure after the average temperature reaches a temperature that is above 240.degree. C. and is at or below pyrolysis temperatures of hydrocarbons in the section. At least some hydrocarbon fluids may be produced from the formation.

  20. Heating tar sands formations to visbreaking temperatures

    DOEpatents

    Karanikas, John Michael; Colmenares, Tulio Rafael; Zhang, Etuan; Marino, Marian; Roes, Augustinus Wilhelmus Maria; Ryan, Robert Charles; Beer, Gary Lee; Dombrowski, Robert James; Jaiswal, Namit

    2009-12-22

    Methods for treating a tar sands formation are described herein. Methods may include heating at least a section of a hydrocarbon layer in the formation from a plurality of heaters located in the formation. The heat may be controlled so that at least a majority of the section reaches an average temperature of between 200.degree. C. and 240.degree. C., which results in visbreaking of at least some hydrocarbons in the section. At least some visbroken hydrocarbon fluids may be produced from the formation.

  1. Process for separating high viscosity bitumen from tar sands

    SciTech Connect

    Miller, J.D.; Misra, M.

    1983-10-18

    A novel process is disclosed for separating high viscosity bitumen from tar sand. The process includes grinding the tar sand to obtain phase disengagement of the bitumen phase from the sand phase and thereafter using flotation techniques to obtain phase separation of the bitumen phase from the sand phase. Phase disengagement is assisted by using a suitable wetting agent during the crushing step while the phase separation step is assisted by the inclusion of a promoter oil for the flotation step.

  2. Process for separating high viscosity bitumen from tar sands

    SciTech Connect

    Miller, J.D.; Misra, M.

    1983-10-18

    A process is described for separating high viscosity bitumen from tar sand. The process includes grinding the tar sand to obtain disengagement of the bitumen from the sand phase and thereafter using flotation techniques to obtain phase separation of the bitumen phase from the sand phase. Phase disengagement is assisted by using a suitable wetting agent during the crushing step, while the phase separation step is assisted by the inclusion of a promoter oil for the flotation step. 6 claims.

  3. The extraction of bitumen from western tar sands. Annual report

    SciTech Connect

    Oblad, A.G.; Bunger, J.W.; Deo, M.D.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1990-07-01

    Topics discussed include: characterization of bitumen impregnated sandstone, water based tar sand separation technology, electrophoretic characterization of bitumen and fine mineral particles, bitumen and tar sand slurry viscosity, the hot water digestion-flotation process, electric field use on breaking water-in-oil emulsions, upgrading of bitumens and bitumen-derived liquids, solvent extraction.

  4. The extraction of bitumen from western tar sands

    SciTech Connect

    Oblad, A.G.; Bunger, J.W.; Deo, M.D.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1990-07-01

    Topics discussed include: characterization of bitumen impregnated sandstone, water based tar sand separation technology, electrophoretic characterization of bitumen and fine mineral particles, bitumen and tar sand slurry viscosity, the hot water digestion-flotation process, electric field use on breaking water-in-oil emulsions, upgrading of bitumens and bitumen-derived liquids, solvent extraction.

  5. Method and apparatus for hydrocarbon recovery from tar sands

    DOEpatents

    Westhoff, James D.; Harak, Arnold E.

    1989-01-01

    A method and apparatus for utilizing tar sands having a broad range of bitumen content is disclosed. More particularly, tar sands are pyrolyzed in a cyclone retort with high temperature gases recycled from the cyclone retort to produce oil and hydrocarbon products. The spent tar sands are then burned at 2000.degree. F. in a burner to remove residual char and produce a solid waste that is easily disposable. The process and apparatus have the advantages of being able to utilize tar sands having a broad range of bitumen content and the advantage of producing product gases that are free from combustion gases and thereby have a higher heating value. Another important advantage is rapid pyrolysis of the tar sands in the cyclone so as to effectively utilize smaller sized reactor vessels for reducing capitol and operating costs.

  6. Method and apparatus for hydrocarbon recovery from tar sands

    DOEpatents

    Westhoff, J.D.; Harak, A.E.

    1988-05-04

    A method and apparatus for utilizing tar sands having a broad range of bitumen content is disclosed. More particularly, tar sands are pyrolyzed in a cyclone retort with high temperature gases recycled from the cyclone retort to produce oil and hydrocarbon products. The spent tar sands are then burned at 2000/degree/F in a burner to remove residual char and produce a solid waste that is easily disposable. The process and apparatus have the advantages of being able to utilize tar sands having a broad range of bitumen content and the advantage of producing product gases that are free from combustion gases and thereby have a higher heating value. Another important advantage is rapid pyrolysis of the tar sands in the cyclone so as to effectively utilize smaller sized reactor vessels for reducing capitol and operating costs. 1 fig., 1 tab.

  7. FY 80 Tar Sands Program first quarterly report, January 1980

    SciTech Connect

    Fox, R.L.; Wayland, J.R.

    1980-05-01

    Research and development efforts in support of the Tar Sands program well completions and stimulation subactivity and new and novel concepts task have been initiated. The objectives of the well completion and stimulation efforts are to carry out research and development in areas with significant for long-range tar sand extraction development as well as provide potential interaction and support of the near-term tar sand field experiments. Evaluation testing of packers and computational analysis of well bore insulation for tar sands steam recovery injection wells have been investigated this quarter. Production well completions for the tar sand steam drive experiment have been examined, and a program to measure downhole steam quality in the experiment is under development. Initial examination of the application of the DOE downhole steam generator program to tar sand reservoirs has commenced. The examination of new and novel concepts for extraction of tar sands has been initiated. An overburden replacement technique was evaluated both computationally and in a laboratory scale experiment. Analyses of both microwave heating and in situ hydrogenation are being initiated.

  8. FY 80 Tar Sands program. Second quarterly report, April 1980

    SciTech Connect

    Wayland, J.R.; Fox, R.L.

    1980-09-01

    The research and development efforts in support of the Tar Sands program reservoir access and alternate extraction activities that were initiated last quarter have been continued and expanded. The development of a short course on the utilization of specialized drilling technology to Tar Sands has been investigated. The steam quality sampler is undergoing laboratory testing. Plans for a Tar Sands enhanced permeability workshop have been initiated. A special report on possible application of sand control methods to the Tar Sands steam injection test (TS-1S) experiment has been prepared. The first stage of the analysis of rf and microwave heating has been completed. The results of a series of laboratory experiments on in-situ hydrogenation are presented.

  9. Supercritical-Fluid Extraction of Oil From Tar Sands

    NASA Technical Reports Server (NTRS)

    Compton, L. E.

    1982-01-01

    New supercritical solvent mixtures have been laboratory-tested for extraction of oil from tar sands. Mixture is circulated through sand at high pressure and at a temperature above critical point, dissolving organic matter into the compressed gas. Extract is recovered from sand residues. Low-temperature super-critical solvents reduce energy consumption and waste-disposal problems.

  10. An evaluation of the potential end uses of a Utah tar sand bitumen. [Tar sand distillate

    SciTech Connect

    Thomas, K.P.; Harnsberger, P.M.; Guffey, F.D.

    1986-09-01

    To date the commercial application of tar sand deposits in the United States has been limited to their use as paving materials for county roads, parking lots, and driveways because the material, as obtained from the quarries, does not meet federal highway specifications. The bitumen in these deposits has also been the subject of upgrading and refining studies to produce transportation fuels, but the results have not been encouraging from an economic standpoint. The conversion of tar sand bitumen to transportation fuels cannot compete with crude oil refining. The purposes of this study were two-fold. The first was to produce vacuum distillation residues and determine if their properties met ASTM asphalt specifications. The second was to determine if the distillates could serve as potential feedstocks for the production of aviation turbine fuels. The bitumen used for this study was the oil produced during an in situ steamflood project at the Northwest Asphalt Ridge (Utah) tar sand deposit. Two distillation residues were produced, one at +316/sup 0/C and one at +399/sup 0/C. However, only the lower boiling residue met ASTM specifications, in this case as an AC-30 asphalt. The original oil sample met specifications as an AC-5 asphalt. These residue samples showed some unique properties in the area of aging; however, these properties need to be investigated further to determine the implications. It was also suggested that the low aging indexes and high flow properties of the asphalts may be beneficial for pavements that require good low-temperature performance. Two distillate samples were produced, one at IBP-316/sup 0/C and one at IBP-399/sup 0/C. The chemical and physical properties of these samples were determined, and it was concluded that both samples appear to be potential feedstocks for the production of aviation turbine fuels. However, hydrogenation studies need to be conducted and the properties of the finished fuels determined to verify the prediction. 14 refs

  11. Creating and maintaining a gas cap in tar sands formations

    SciTech Connect

    Vinegar, Harold J.; Karanikas, John Michael; Dinkoruk, Deniz Sumnu; Wellington, Scott Lee

    2010-03-16

    Methods for treating a tar sands formation are disclosed herein. Methods for treating a tar sands formation may include providing heat to at least part of a hydrocarbon layer in the formation from one or more heaters located in the formation. Pressure may be allowed to increase in an upper portion of the formation to provide a gas cap in the upper portion. At least some hydrocarbons are produced from a lower portion of the formation.

  12. Process for separating high viscosity bitumen from tar sands

    SciTech Connect

    Miller, J.D.; Misra, M.

    1984-12-04

    A novel process for separating high viscosity bitumen from tar sand. The process includes grinding the tar sand to obtain phase disengagement of the bitumen phase from the sand phase and thereafter using flotation techniques to obtain phase separation of the bitumen phase from the sand phase. Phase disengagement is assisted by using a suitable wetting agent such as sodium carbonate or sodium silicate during the grinding step, while the phase separation step is assisted by the inclusion of a promoter oil for the flotation step.

  13. Extraction of vanadium from athabasca tar sands fly ash

    NASA Astrophysics Data System (ADS)

    Gomez-Bueno, C. O.; Spink, D. R.; Rempel, G. L.

    1981-06-01

    The production of refinery grade oil from the Alberta tar sands deposits as currently practiced by Suncor (formally Great Canadian Oil Sands Ltd.—GCOS) generates a substantial amount of petroleum coke fly ash which contains appreciable amounts of valuable metals such as vanadium, nickel and titanium. Although the recovery of vanadium from petroleum ash is a well established commercial practice, it is shown in the present work that such processes are not suitable for recovery of vanadium from the GCOS fly ash. The fact that the GCOS fly ash behaves so differently when compared to other petroleum fly ash is attributed to its high silicon and aluminum contents which tie up the metal values in a silica-alumina matrix. Results of experiments carried out in this investigation indicate that such matrices can be broken down by application of a sodium chloride/water roast of the carbon-free fly ash. Based on results from a series of preliminary studies, a detailed investigation was undertaken in order to define optimum conditions for a vanadium extraction process. The process developed involves a high temperature (875 to 950 °C) roasting of the fly ash in the presence of sodium chloride and water vapor carried out in a rotary screw kiln, followed by dilute sodium hydroxide atmosphereic leaching (98 °C) to solublize about 85 pet of the vanadium originally present in the fly ash. It was found that the salt roasting operation, besides enhancing vanadium recovery, also inhibits silicon dissolution during the subsequent leaching step. The salt roasting treatment is found to improve vanadium recovery significantly when the fly ash is fully oxidized. This is easily achieved by burning off the carbon present in the “as received” fly ash under excess air. The basic leaching used in the new process selectively dissolves vanadium from the roasted ash, leaving nickel and titanium untouched.

  14. Potential hydrologic impacts of a tar-sand industry in 11 special tar sand areas in eastern Utah

    USGS Publications Warehouse

    Lindskov, K.L.

    1983-01-01

    About 93 percent of the Nation 's estimated 30 billion barrels of crude oil in tar sand deposits is in 11 tar-sand deposits in eastern Utah that were chosen for leasing by the Federal government. The Tar Sand Triangle area, which contains about 15 billion barrels of oil, is the largest. This area and the Sunnyside and P R Springs areas contain more than three-fourths of the Utah reserves. About 88,000 acre-feet of water per year would be required for a commercial tar-sand industry producing about 365,000 barrels per day. At this rate, most of the recoverable oil would be mined within 30 years. About 22,000 acre-feet of water per year would be required for a commercial tar-sand industry producing about 83,000 barrels per day. Impacts on local hydrology would be greatest in the Tar Sand Triangle, Sunnyside, and P R Springs areas. Impacts could be minimized with proper construction of surface facilities to decrease erosion, sediment transport, and impoundment of mining and retort water. Increases in salinity of the Colorado River at Imperial Dam, Ariz.-Calif., could be about 3 milligrams per liter, with a peak of 9 milligrams per liter, for a 365 ,000-barrel-per-day industry and less than 1 milligram per liter , with a peak of 2 milligrams per liter, for an 83 ,000-barrel-per-day industry. (USGS)

  15. Process and apparatus for recovery of oil from tar sands

    SciTech Connect

    Brewer, J.C.

    1982-11-30

    A crude oil product is extracted from a tar sand by first crushing the tar sand as mined and then fine grinding the crushed material in a grinding mill in the presence of a cleansing liquid, such as an aqueous solution of a caustic. The resulting slurry is passed into suitable extractor-classifier equipment, such as that shown in U.S. Pat. No. 3,814,336, in which a body of cleansing liquid is maintained. Agitation of the slurry in such maintained body of cleansing liquid substantially completes removal of the bituminous matter from the sand, and the resulting crude oil and cleansing liquid phase is discharged separately from the sand solid phase. The liquid phase is treated for the removal of residual sand particles and for the separation of residual cleansing liquid from the crude oil. The cleansing liquid so recovered is recycled and the crude oil is passed to further processing or for use as such.

  16. Proposed water treatment approach for commercial tar sand wastewaters

    SciTech Connect

    Kocornik, D.

    1986-09-01

    Waters produced during the steamflood extraction of bitumen from tar sand require treatment before they can be recycled as feedwater for steam generation. The characterization of two waters from commercial-scale tar sand operations indicates that the levels of hardness, oil and grease, silica, suspended solids, and iron must be reduced before these waters can be reused in the bitumen extraction process. The Western Research Institute proposes two treatment methods (electrocoagulation and ultrafiltration) that may, when used in conjunction with standard practices, improve the efficiency of the overall treatment process. 21 refs., 3 tabs.

  17. In situ recovery of oil from Utah tar sand: a summary of tar sand research at the Laramie Energy Technology Center

    SciTech Connect

    Marchant, L.C.; Westhoff, J.D.

    1985-10-01

    This report describes work done by the United States Department of Energy's Laramie Energy Technology Center from 1971 through 1982 to develop technology for future recovery of oil from US tar sands. Work was concentrated on major US tar sand deposits that are found in Utah. Major objectives of the program were as follows: determine the feasibility of in situ recovery methods applied to tar sand deposits; and establish a system for classifying tar sand deposits relative to those characteristics that would affect the design and operation of various in situ recovery processes. Contents of this report include: (1) characterization of Utah tar sand; (2) laboratory extraction studies relative to Utah tar sand in situ methods; (3) geological site evaluation; (4) environmental assessments and water availability; (5) reverse combustion field experiment, TS-1C; (6) a reverse combustion followed by forward combustion field experiment, TS-2C; (7) tar sand permeability enhancement studies; (8) two-well steam injection experiment; (9) in situ steam-flood experiment, TS-1S; (10) design of a tar sand field experiment for air-stream co-injection, TS-4; (11) wastewater treatment and oil analyses; (12) economic evaluation of an in situ tar sand recovery process; and (13) appendix I (extraction studies involving Utah tar sands, surface methods). 70 figs., 68 tabs.

  18. II international conference on heavy crude and tar sands. Summary report

    SciTech Connect

    Not Available

    1982-01-01

    The Second International Conference on Heavy Crude and Tar Sands clearly demonstrated that the world has abundant heavy and extra heavy crudes that will sustain the petroleum age for decades. Perhaps even more important for many developed and developing countries is that these resources are widely distributed throughout the world, for deposits are known to exist in at least forty-nine countries. Moreover, the rapid expansion over the last two and a half years of knowledge of the magnitude of these resources suggests there is much more to be added to the world's list of useful energy assets. The current ample supply of crude oil does not appear to have lessened the resolve to develop heavy crude and tar sands. Major industrial countries are eager to develop their heavy oil resources to free themselves from dependence on OPEC and the developing nations hope to reduce their cash outflows for imported oil which they can ill afford. Venezuela and Canada, which both have massive heavy crude reserves, are intent on developing their resources to supplement declining supplies of light oil. Despite the weakening international price of oil, the economics for many heavy crude ventures seem favorable. Statistics quoted at the conference suggest considerable heavy crude production can be brought on stream at costs approaching the finding costs of light conventional crude. At the same time, it has to be acknowledged that those large tar sands projects, like Alberta's multi-billion dollar ventures, are sufficiently marginal that they may be held back by current soft oil demand. This summary report covers the following areas: resources; international cooperation; production; environment; technological developments; upgrading and refining; marketing; and future of heavy crude oil and tar sands.

  19. The extraction of bitumen from western tar sands. Annual report, July 1990--July 1991

    SciTech Connect

    Oblad, A.G.; Bunger, J.W.; Deo, M.D.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1992-04-01

    Contents of this report include the following: executive summary; characterization of the native bitumen from the Whiterocks oil sand deposit; influence of carboxylic acid content on bitumen viscosity; water based oil sand separation technology; extraction of bitumen from western oil sands by an energy-efficient thermal method; large- diameter fluidized bed reactor studies; rotary kiln pyrolysis of oil sand; catalytic upgrading of bitumen and bitumen derived liquids; ebullieted bed hydrotreating and hydrocracking; super critical fluid extraction; bitumen upgrading; 232 references; Appendix A--Whiterocks tar sand deposit bibliography; Appendix B--Asphalt Ridge tar sand deposit bibliography; and Appendix C--University of Utah tar sands bibliography.

  20. Systems and methods for producing hydrocarbons from tar sands formations

    DOEpatents

    Li, Ruijian; Karanikas, John Michael

    2009-07-21

    A system for treating a tar sands formation is disclosed. A plurality of heaters are located in the formation. The heaters include at least partially horizontal heating sections at least partially in a hydrocarbon layer of the formation. The heating sections are at least partially arranged in a pattern in the hydrocarbon layer. The heaters are configured to provide heat to the hydrocarbon layer. The provided heat creates a plurality of drainage paths for mobilized fluids. At least two of the drainage paths converge. A production well is located to collect and produce mobilized fluids from at least one of the converged drainage paths in the hydrocarbon layer.

  1. Production from multiple zones of a tar sands formation

    DOEpatents

    Karanikas, John Michael; Vinegar, Harold J

    2013-02-26

    A method for treating a tar sands formation includes providing heat to at least part of a hydrocarbon layer in the formation from a plurality of heaters located in the formation. The heat is allowed to transfer from the heaters to at least a portion of the formation. Fluids are produced from the formation through at least one production well that is located in at least two zones in the formation. The first zone has an initial permeability of at least 1 darcy. The second zone has an initial of at most 0.1 darcy. The two zones are separated by a substantially impermeable barrier.

  2. Alberta's economic development of the Athabasca oil sands

    NASA Astrophysics Data System (ADS)

    Steinmann, Michael

    This dissertation examines the 61-year evolution of public policies pertaining to development of Alberta's non-conventional source of crude oil. The Athabasca oil sands contain an estimated 1.5 trillion barrels and provide for a safe continental supply. The Provincial Government first sponsored this undertaking in 1943. The period from then to 1971 was one of a transition from a wheat economy to a natural-resource economic base. A stable government emerged and was able to negotiate viable development policies. A second period, 1971 to 1986, was marked by unstable world conditions that afforded the Alberta government the ability to set terms of development with multi-national oil firms. A 50% profit-sharing plan was implemented, and basic 1973 terms lasted until 1996. However, 1986 was a critical year because the Organization of Petroleum Exporting Countries (OPEC) reduced prices, causing the Alberta economy to lapse into recession. During a third period, 1986 to 1996, the Alberta Government was unable to adapt quickly to world conditions. A new leadership structure in 1996 made major changes to create ongoing fiscal and development policies. That history provides answers to two primary research questions: How do public policies affect the behaviors of the modern corporation and visa versa? What are the implications for development theory? Two sources of information were used for this study. First, it was possible to review the Premier's files located in the Provincial Archives. Materials from various government libraries were also examined. Some 7,000 documents were used to show the evolution of government policymaking. Second, interviews with leaders of oil companies and federal research facilities were important. Findings support the thesis that, to facilitate oil sands development, government and the private sector have closely collaborated. In particular, revenue policies have allowed for effective R&D organization. Relying on intensive technological

  3. Trace metals in heavy crude oils and tar sand bitumens

    SciTech Connect

    Reynolds, J.G.

    1990-11-28

    Fe, Ni, and V are considered trace impurities in heavy crude oils and tar sand bitumens. In order to understand the importance of these metals, we have examined several properties: (1) bulk metals levels, (2) distribution in separated fractions, (3) size behavior in feeds and during processing, (4) speciation as a function of size, and (5) correlations with rheological properties. Some of the results of these studies show: (1) V and Ni have roughly bimodal size distributions, (2) groupings were seen based on location, size distribution, and Ni/V ratio of the sample, (3) Fe profiles are distinctively different, having a unimodal distribution with a maximum at relatively large molecular size, (4) Fe concentrations in the tar sand bitumens suggest possible fines solubilization in some cases, (5) SARA separated fractions show possible correlations of metals with asphaltene properties suggesting secondary and tertiary structure interactions, and (6) ICP-MS examination for soluble ultra-trace metal impurities show the possibility of unexpected elements such as U, Th, Mo, and others at concentrations in the ppB to ppM range. 39 refs., 13 figs., 5 tabs.

  4. Geology and resources of the Tar Sand Triangle, southeastern Utah

    SciTech Connect

    Dana, G.F.; Oliver, R.L.; Elliott, J.R.

    1984-05-01

    The Tar Sand Triangle is located in southeastern Utah between the Dirty Devil and Colorado Rivers and covers an area of about 200 square miles. The geology of the area consists of gently northwest dipping strata exposed in the box canyons and slopes of the canyonlands morphology. Strata in the area range in age from Jurassic to Permian. The majority of tar sand saturation is found in the Permian White Rim Sandstone Member of the Cutler Formation. The White Rim Sandstone Member consists of a clean, well-sorted sandstone which was deposited in a shallow marine environment. Resources were calculated from analytical data from the three coreholes drilled by the Laramie Energy Technology Center and other available data. The total in-place resources, determined from this study, are 6.3 billion barels. Previous estimates ranged from 2.9 to 16 million barrels. More coring and analyses will be necessary before a more accurate determination of resources can be attempted. 8 references, 11 figures, 7 tables.

  5. Creating new landscapes and ecosystems: the Alberta Oil Sands.

    PubMed

    Johnson, E A; Miyanishi, K

    2008-01-01

    Extraction of oil from the Alberta Oil Sands through surface mining involves the removal of the overburden and oil sand to a depth of up to 100 m and over extremely large areas. While the operation of the bitumen processing plants has serious environmental impacts on downstream habitats, this article focuses on the reclamation of areas from which the oil sands have been removed, processed, and returned. This reclamation following closure of the mines will entail the complete re-creation of landforms and ecosystems at a landscape scale, with the goal of producing suitable habitats for plants, animals, and people. Such projects will require a reasonable understanding of the geophysical and ecological processes that operate at a wide range of scales. Some information is provided on the climate, hydrology, vegetation, and land use (past and current) of the Oil Sands area, situated within the Boreal Plain ecozone, to provide a framework for discussion of issues to be addressed in, and proposed guidelines for, such large-scale reclamation. Although none of the mines has yet closed, numerous consultant reports have been produced with recommendations for various aspects of such reclamation projects (e.g., wetland hydrology, vegetation, wildlife habitat). The scientific basis of such reports is found to vary with respect to depth of understanding of the relevant processes. PMID:18566092

  6. Quantifying Sources of Methane in the Alberta Oil Sands

    NASA Astrophysics Data System (ADS)

    Baray, S.; Darlington, A. L.; Gordon, M.; Hayden, K.; Li, S. M.; Mittermeier, R. L.; O'brien, J.; Staebler, R. M.; McLaren, R.

    2015-12-01

    In the summer of 2013, an aircraft measurement campaign led by Environment Canada with participation from university researchers took place to investigate the sources and transformations of gas pollutants in the Alberta oil sands region close to Fort McMurray, Alberta. Apart from its ability to change the radiative forcing of the atmosphere, methane is also a significant precursor to the formation of formaldehyde, an important radical source. Thus, emissions of methane from facilities need to be understood since they can have air quality implications through alteration of the radical budget and hence, the oxidation capacity of the air mass. Methane was measured, along with other gases, via a cavity ring-down spectroscopy instrument installed on the Convair-580 aircraft. In total, there were 22 flights with 82 hours of measurements in the vicinity of oil sands facilities between August 13 and September 7, 2013. Various tools have been used to visualize the spatial and temporal variation in mixing ratios of methane and other trace gases in order to identify possible sources of methane. Enhancements of methane from background levels of 1.9 ppm up to ~4 ppm were observed close to energy mining facilities in the oil sands region. Sources of methane identified include open pit mining, tailings ponds, upgrader stacks and in-situ mining operations. Quantification of the emission rates of methane from distinct sources has been accomplished from box flights and downwind screen flights by identifying the ratios of trace gases emitted and through use of the Top-down Emission Rate Retrieval Algorithm (TERRA). Methane emission rates for some of these sources will be presented.

  7. Tar sand occurrences in the Bush Butte Quadrangle, Wyoming, with emphasis on the Trapper Canyon Deposit

    SciTech Connect

    VerPloeg, A.J.; DeBruin, R.H.

    1983-01-01

    The Trapper Canyon Tar Sand Deposit is located in the eastern Bighorn Basin, approximately 25 miles east of Greybull, Wyoming. This project not only involved detailed geologic mapping of the Trapper Canyon Tar Sand Deposit, but also sampling and describing the tar zone as well as the bounding barren zones. Samples were analyzed for porosity, permeability, oil saturation, and characteristics of the oil. Thin sections from both the tar zone and barren zones were made and examined to determine textural characteristics and kinds of pore-filling cements. In addition, samples were analyzed using the scanning electron microscope to gain insight into the diagenesis of the reservoir rock and trapping mechanisms. The Trapper Canyon Tar Sand Deposit was investigated because it was considered potentially commercial, and the results of the study could aid in forming an economical plan of development for this deposit and similar deposits elsewhere in the State. Also, the area provided an excellent opportunity to examine surface exposures of a tar sand deposit. The final phase of the study involved mapping the Bush Butte quadrangle and looking for additional tar sand deposits in the quadrangle. The search for additional deposits was carried out based on a model developed by examination of the Trapper Canyon Deposit. 16 references, 14 figures, 3 tables.

  8. Paleontological overview of oil shale and tar sands areas in Colorado, Utah, and Wyoming.

    SciTech Connect

    Murphey, P. C.; Daitch, D.; Environmental Science Division

    2009-02-11

    In August 2005, the U.S. Congress enacted the Energy Policy Act of 2005, Public Law 109-58. In Section 369 of this Act, also known as the ''Oil Shale, Tar Sands, and Other Strategic Unconventional Fuels Act of 2005,'' Congress declared that oil shale and tar sands (and other unconventional fuels) are strategically important domestic energy resources that should be developed to reduce the nation's growing dependence on oil from politically and economically unstable foreign sources. In addition, Congress declared that both research- and commercial-scale development of oil shale and tar sands should (1) be conducted in an environmentally sound manner using management practices that will minimize potential impacts, (2) occur with an emphasis on sustainability, and (3) benefit the United States while taking into account concerns of the affected states and communities. To support this declaration of policy, Congress directed the Secretary of the Interior to undertake a series of steps, several of which are directly related to the development of a commercial leasing program for oil shale and tar sands. One of these steps was the completion of a programmatic environmental impact statement (PEIS) to analyze the impacts of a commercial leasing program for oil shale and tar sands resources on public lands, with an emphasis on the most geologically prospective lands in Colorado, Utah, and Wyoming. For oil shale, the scope of the PEIS analysis includes public lands within the Green River, Washakie, Uinta, and Piceance Creek Basins. For tar sands, the scope includes Special Tar Sand Areas (STSAs) located in Utah. This paleontological resources overview report was prepared in support of the Oil Shale and Tar Sands Resource Management Plan Amendments to Address Land Use Allocations in Colorado, Utah, and Wyoming and PEIS, and it is intended to be used by Bureau of Land Management (BLM) regional paleontologists and field office staff to support future projectspecific analyses

  9. On the Periphery of the Tar Sands. Documents in the Classroom.

    ERIC Educational Resources Information Center

    Hodysh, Henry W.

    2000-01-01

    Explores the diary of Karl Clark that focuses on his experiences in the Athabasca tar sands. The diary helps decipher the nature of 1920s town life and the pioneering spirit involved in exploring the oil sands. Includes background information on Clark. (CMK)

  10. Ultrasonic reactor for the recovery of bitumen from tar sand: Final report

    SciTech Connect

    Bunger, J.W.; Miller, J.D.; Johnson, S.A.

    1987-07-28

    A bench scale ultrasonic reactor was designed for testing to determine its feasiblity for enhancing the dissolution and extraction of bitumen from Utah tar sands using both solvent and water as a liquid medium for dissolution and extraction and to compare the results. The ultrasonic reactor did not significantly enhance dissolution of bitumen into the sovlent. Ultrasonic energy did appear to enhance intraparticle diffusion in consolidated tar sand. The rate of disengagement of the bitumen from the sand in hot water extraction was slightly enhanced and a continuous flow unit may show promise for the recovery of bitumen from tar sands. Assuming that high recovery efficiency can be obtained, the energy requirements for the ultrasonic reactor did not appear to be prohibitive. 5 figs., 3 tabs.

  11. Satellite Based Analysis of Carbon Monoxide Levels Over Alberta Oil Sand

    NASA Astrophysics Data System (ADS)

    Marey, H. S.; Hashisho, Z.; Fu, L.; Gille, J. C.

    2014-12-01

    The rapid expansion of oil sands activities and massive energy requirements to extract and upgrade the bitumen require a comprehensive understanding of their potential environmental impacts, particularly on air quality. In this study, satellite-based analysis of carbon monoxide (CO) levels was used to assess the magnitude and distribution of this pollutant throughout Alberta oil sands region. Measurements of Pollution in the Troposphere (MOPITT) V5 multispectral product that uses both near-infrared and the thermal-infrared radiances for CO retrieval were used. MOPITT-based climatology and inter-annual variations were examined for 12 years (2002-2013) on spatial and temporal scales. Seasonal climatological maps for CO total columns indicated conspicuous spatial variations in all seasons except in winter where the CO spatial variations are less prominent. High CO loadings are observed to extend from the North East to North West regions of Alberta, with highest values in spring. The CO mixing ratios at the surface level in winter and spring seasons exhibited dissimilar spatial distribution pattern where the enhancements are detected in south eastern rather than northern Alberta. Analyzing spatial distributions of Omega at 850 mb pressure level for four seasons implied that, conditions in northeastern Alberta are more favorable for up lofting while in southern Alberta, subsidence of CO emissions are more likely. Time altitude CO profile climatology as well as the inter-annual variability were investigated for the oil sands and main urban regions in Alberta to assess the impact of various sources on CO loading. Monthly variations over urban regions are consistent with the general seasonal cycle of CO in Northern Hemisphere which exhibits significant enhancement in winter and spring, and minimum mixing ratios in summer. The typical seasonal CO variations over the oil sands region are less prominent. This study has demonstrated the potential use of multispectral CO

  12. In situ heat treatment of a tar sands formation after drive process treatment

    SciTech Connect

    Vinegar, Harold J.; Stanecki, John

    2010-09-21

    A method for treating a tar sands formation includes providing a drive fluid to a hydrocarbon containing layer of the tar sands formation to mobilize at least some hydrocarbons in the layer. At least some first hydrocarbons from the layer are produced. Heat is provided to the layer from one or more heaters located in the formation. At least some second hydrocarbons are produced from the layer of the formation. The second hydrocarbons include at least some hydrocarbons that are upgraded compared to the first hydrocarbons produced by using the drive fluid.

  13. Industry use of saline water not expected in tar sand triangle

    SciTech Connect

    Not Available

    1986-09-01

    An environmental assessment of the Dirty Devil River Salinity Control Unit resulted in a finding of no significant impact. The purpose of the unit is to reduce salinity in the Colorado River by collecting flows below two saline springs and disposing of them by deep-well injection into the Coconino Sandstone. During formulation of the salinity control plan, the potential use of saline water in the development of tar sand resources was considered, but it was concluded that saline water would not be needed for this purpose in the foreseeable future, because of the currently depressed world oil market and the development status of tar sand extraction technologies.

  14. Post-Secondary Learning Priorities of Workers in an Oil Sands Camp in Northern Alberta

    ERIC Educational Resources Information Center

    Fahy, Patrick J.; Steel, Nancy

    2008-01-01

    This paper reports results to date of a three-year project by Athabasca University, intended to determine the education and training needs and interests of employees in a work camp in northern Alberta's oil sands. (Future reports will address results of efforts to provide programming suiting the needs identified, and the uptake, satisfaction,…

  15. Analysis of reverse combustion in tar sands: a one-dimensional model

    SciTech Connect

    Amr, A.

    1980-08-01

    This paper describes a one-dimensional numerical model which simulates oil recovery from tar sands by reverse combustion. The method of lines is used to solve the nonlinear differential equations describing the flow. The effects of volumetric air flux on the peak temperature, flame velocity, and oil recovery efficiency are reported. The results are compared to the results of relevant experimental studies.

  16. Examination of the mining of heavy oil and tar sands by overburden substitution

    SciTech Connect

    Fox, R.L.

    1982-02-01

    A mining procedure which removes the geologic formations above an oil or tar sand bearing reservoir by strip mining techniques, then floods the upper surface of the reservoir with a pool of water, is examined by computational models and laboratory scale experiments. The results of the studies indicate low production rates are achieved by such a procedure.

  17. Unconventional pilot steam drive, tar V sand, Long Beach unit, Wilmington Field, CA

    SciTech Connect

    Jung, K.D.

    1984-04-01

    This paper reviews the design, implementation and history of the unconventional pilot steam drive (greater than 2,500 ft measured depth) that has been underway since December 24, 1980 in the Tar reservoir in the Long Beach Unit, Wilmington Field, Los Angeles County, California. This paper describes the project through November 30, 1983. The Tar V reservoir is a series of interbedded sands, siltstones and shales in the Middle Repetto formation of lower Pliocene age. The Tar V reservoir in the Long Beach Unit is approximately 200 acres in areal extent, has a vertical gross thickness of 185 ft and a maximum vertical net oil sand thickness of 90 ft comprised of 8 to 10 separate sand units. Oil in place is estimated at 27 MMbbl of stock tank oil. The study area is 9.2 acres in areal extent with an average net oil sand thickness of 81.7 ft. The pilot steam drive was originally installed as an isolated 5.6 acre inverted 5-spot pattern.

  18. Transformism in Alberta: The Environmental Political Economy of the Bituminous Sands

    NASA Astrophysics Data System (ADS)

    Katz-Rosene, Ryan

    This thesis attempts to help establish environmental political economy as a viable academic field while providing an example of work in the discipline. It offers an analysis of societal processes resulting in the co-optation and/or neutralization of critical environmentalist ideas. Using Alberta's bituminous sands as a case study, and a Gramsci-influenced eco-Marxist theory as a foundation, the thesis argues that the term 'environmental transformism' (inspired by the Gramscian term trasformismo) is helpful in describing and framing such processes. Accordingly, the ensuing chapters provide an analysis of why environmental transformism is happening in Alberta, and demonstrate how this mechanism works at protecting the status quo from threatening ideologies, thereby consolidating neoliberal capitalism. A concluding argument discusses the inherent dangers posed to society by the transformism of certain environmental subjectivities. The thesis begins by introducing the contentious social and environmental issues surrounding the development of the bituminous sands.

  19. Method of producing drive fluid in situ in tar sands formations

    DOEpatents

    Mudunuri, Ramesh Raju; Jaiswal, Namit; Vinegar, Harold J.; Karanikas, John Michael

    2010-03-23

    Methods of treating a tar sands formation are described herein. Methods for treating a tar sands may include providing heat to at least part of a hydrocarbon layer in the formation from one or more heaters located in the formation. The heat may be allowed to transfer from the heaters to at least a portion of the formation such that a drive fluid is produced in situ in the formation. The drive fluid may move at least some mobilized, visbroken, and/or pyrolyzed hydrocarbons from a first portion of the formation to a second portion of the formation. At least some of the mobilized, visbroken, and/or pyrolyzed hydrocarbons may be produced from the formation.

  20. Controlling and assessing pressure conditions during treatment of tar sands formations

    DOEpatents

    Zhang, Etuan; Beer, Gary Lee

    2015-11-10

    A method for treating a tar sands formation includes providing heat to at least part of a hydrocarbon layer in the tar sands formation from a plurality of heaters located in the formation. Heat is allowed to transfer from the heaters to at least a portion of the formation. A pressure in the portion of the formation is controlled such that the pressure remains below a fracture pressure of the formation overburden while allowing the portion of the formation to heat to a selected average temperature of at least about 280.degree. C. and at most about 300.degree. C. The pressure in the portion of the formation is reduced to a selected pressure after the portion of the formation reaches the selected average temperature.

  1. Tar sand extraction by steam stimulation and steam drive: measurement of physical properties

    SciTech Connect

    Linberg, W.R.

    1980-09-10

    The measurement of the following thermophysical properties of Utah tar sands is in progress: thermal conductivity, specific heat relative permeability, and viscosity (of the recovered bitumen). During the report period (October 1, 1978 to November 1, 1979), experimental procedures have been developed and a basic data set has been measured. Additionally, standard core analysis has been performed for four drill sites in the Asphalt Ridge, Utah area.

  2. New insights into halocarbon emissions in boreal regions: Forest fires and Alberta oil sands

    NASA Astrophysics Data System (ADS)

    Simpson, I. J.; Barletta, B.; Meinardi, S.; Marrero, J.; Rowland, F. S.; Akagi, S. K.; Yokelson, R. J.; Blake, D. R.

    2011-12-01

    Boreal forest fires and Alberta oil sands represent two major co-located trace gas emission sources within the boreal ecosystem. During the airborne ARCTAS mission in summer 2008, UC-Irvine performed the most comprehensive characterization of halocarbon emissions from boreal forest fires to date. In summer 2008 and 2010 we also performed the first independent characterizations of halocarbon emissions from Alberta's oil sands industry. In both cases the measurements were made using whole air sampling followed by gas chromatography analysis using electron capture detection and mass spectrometer detection. In the case of boreal forest fires, of 26 speciated halocarbons that were measured, only the simplest halocarbons were emitted from the fires (CH3Cl, CH3Br, CH3I, 1,2-C2H4Cl2, C2H5Cl and CH2Br2) (Simpson et al., 2011). These compounds were released in relatively small quantities and together they represented <0.3% of the total carbon released from boreal forest fires in the form of non-methane volatile organic compounds (NMVOCs). Even though CH3Cl was the most abundantly emitted halocarbon, its average global emission from boreal forest fires (0.011 ± 0.003 Tg yr-1) was very small compared to its global source budget. The poly-chlorinated compounds CH2Cl2, CHCl3 and CH3CCl3 were not released from the fires. In the case of the Alberta oil sands, based on airborne measurements during the ARCTAS mission, 15 of 26 measured halocarbons were statistically enhanced over the oil sands compared to local background values (Simpson et al., 2010). The short-lived solvents C2HCl3, C2Cl4, C2H5Cl and CHCl3 were the most strongly enhanced halocarbons, with maximum values that were 1.5-34× the local background. A subsequent ground-based study in 2010 detected even stronger halocarbon enhancements downwind of upgraders and tailings sand at the oil sands surface mining sites. For example C2HCl3 and CHBrCl2 mixing ratios were up to 60-85× the local background values. Long

  3. Vegetation and soil water interactions on a tailings sand storage facility in the athabasca oil sands region of Alberta Canada

    NASA Astrophysics Data System (ADS)

    Naeth, M. A.; Chanasyk, D. S.; Burgers, T. D.

    The relationship between vegetation and soil water was studied on the Syncrude South West Sand Storage facility in the Athabasca Oil Sands region of Alberta, Canada. Soil water and relevant soil chemical and physical properties were measured at the soil surface, as well as above and below the reclamation soil and tailings sand interface, in areas of low and high vegetation cover. The interface between the reclamation soil and the tailings sand acted as a capillary barrier. Water content was highest under low vegetation cover but soil water conditions above field capacity were rare and unlikely to have impacted vegetation. Periods of water stress occurred, where volumetric water content was below wilting point; these periods were of short duration and generally typical of ecosystems in the study area. Differences in surface soil water between the two vegetation covers were attributed to evapotranspiration and/or canopy interception. Differences above and below the interface were attributed to variation in canopy cover at the surface and resulting quantities of water available for percolation through the soil profiles. At the interface of the reclamation soil and tailings sand, water movement was restricted. High and low canopy covers responded differently to precipitation events; low vegetation cover areas had greater fluctuations in volumetric water content at all depths. The occurrence of a capillary barrier effect will need to be accounted for in developing reclamation soil profiles.

  4. InSAR Monitoring of Surface Deformation in Alberta's Oil Sands

    NASA Astrophysics Data System (ADS)

    Pearse, J.; Singhroy, V.; Li, J.; Samsonov, S. V.; Shipman, T.; Froese, C. R.

    2013-05-01

    Alberta's oil sands are among the world's largest deposits of crude oil, and more than 80% of it is too deep to mine, so unconventional in-situ methods are used for extraction. Most in situ extraction techniques, such as Steam-Assisted Gravity Drainage (SAGD), use steam injection to reduce the viscosity of the bitumen, allowing it to flow into wells to be pumped to the surface. As part of the oil sands safety and environmental monitoring program, the energy regulator uses satellite radar to monitor surface deformation associated with in-situ oil extraction. The dense vegetation and sparse infrastructure in the boreal forest of northern Alberta make InSAR monitoring a challenge; however, we have found that surface heave associated with steam injection can be detected using traditional differential InSAR. Infrastructure and installed corner reflectors also allow us to use persistent scatterer methods to obtain time histories of deformation at individual sites. We have collected and processed several tracks of RADARSAT-2 data over a broad area of the oil sands, and have detected surface deformation signals of approximately 2-3 cm per year, with time series that correlate strongly with monthly SAGD steam injection volumes.

  5. Class I cultural resource overview for oil shale and tar sands areas in Colorado, Utah and Wyoming.

    SciTech Connect

    O'Rourke, D.; Kullen, D.; Gierek, L.; Wescott, K.; Greby, M.; Anast, G.; Nesta, M.; Walston, L.; Tate, R.; Azzarello, A.; Vinikour, B.; Van Lonkhuyzen, B.; Quinn, J.; Yuen, R.; Environmental Science Division

    2007-11-01

    In August 2005, the U.S. Congress enacted the Energy Policy Act of 2005, Public Law 109-58. In Section 369 of this Act, also known as the 'Oil Shale, Tar Sands, and Other Strategic Unconventional Fuels Act of 2005', Congress declared that oil shale and tar sands (and other unconventional fuels) are strategically important domestic energy resources that should be developed to reduce the nation's growing dependence on oil from politically and economically unstable foreign sources. The Bureau of Land Management (BLM) is developing a Programmatic Environmental Impact Statement (PEIS) to evaluate alternatives for establishing commercial oil shale and tar sands leasing programs in Colorado, Wyoming, and Utah. This PEIS evaluates the potential impacts of alternatives identifying BLM-administered lands as available for application for commercial leasing of oil shale resources within the three states and of tar sands resources within Utah. The scope of the analysis of the PEIS also includes an assessment of the potential effects of future commercial leasing. This Class I cultural resources study is in support of the Draft Oil Shale and Tar Sands Resource Management Plan Amendments to Address Land Use Allocations in Colorado, Utah, and Wyoming and Programmatic Environmental Impact Statement and is an attempt to synthesize archaeological data covering the most geologically prospective lands for oil shale and tar sands in Colorado, Utah, and Wyoming. This report is based solely on geographic information system (GIS) data held by the Colorado, Utah, and Wyoming State Historic Preservation Offices (SHPOs). The GIS data include the information that the BLM has provided to the SHPOs. The primary purpose of the Class I cultural resources overview is to provide information on the affected environment for the PEIS. Furthermore, this report provides recommendations to support planning decisions and the management of cultural resources that could be impacted by future oil shale and tar

  6. Oil shale, tar sand, coal research advanced exploratory process technology, jointly sponsored research

    SciTech Connect

    Speight, J.G.

    1992-01-01

    Accomplishments for the past quarter are presented for the following five tasks: oil shale; tar sand; coal; advanced exploratory process technology; and jointly sponsored research. Oil shale research covers oil shale process studies. Tar sand research is on process development of Recycle Oil Pyrolysis and Extraction (ROPE) Process. Coal research covers: coal combustion; integrated coal processing concepts; and solid waste management. Advanced exploratory process technology includes: advanced process concepts;advanced mitigation concepts; and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; CROW field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; PGI demonstration project; operation and evaluation of the CO[sub 2] HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesaverde Group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced oil recovery techniques; surface process study for oil recovery using a thermal extraction process; NMR analysis of samples from the ocean drilling program; in situ treatment of manufactured gas plant contaminated soils demonstration program; and solid state NMR analysis of naturally and artificially matured kerogens.

  7. Oil shale, tar sand, coal research, advanced exploratory process technology jointly sponsored research

    SciTech Connect

    Not Available

    1992-01-01

    Accomplishments for the quarter are presented for the following areas of research: oil shale, tar sand, coal, advanced exploratory process technology, and jointly sponsored research. Oil shale research includes; oil shale process studies, environmental base studies for oil shale, and miscellaneous basic concept studies. Tar sand research covers process development. Coal research includes; underground coal gasification, coal combustion, integrated coal processing concepts, and solid waste management. Advanced exploratory process technology includes; advanced process concepts, advanced mitigation concepts, and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO[sub 2] HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesa Verde Group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced recovery techniques; and menu driven access to the WDEQ Hydrologic Data Management Systems.

  8. Development of an inclined liquid fluidized bed for tar sand processing

    SciTech Connect

    Johnson, L.A. Jr.

    1989-12-01

    An inclined liquid fluidized-bed reactor (ILFBR) system has been developed and successfully operated for 24 hours. Modifications to the previously tested ILFBR systems include incorporation of a oil fluidizing zone in the front of the fluid bed, an increase in the angle of the fluid bed to {minus}12{degree} (the minus sign shows that the discharges is below the horizontal level of the inlet), and reduction of the fluidizing gas velocities equal to or below the minimum fluidization velocity. These changes produced a functional bubbling slurry bed for the processing of tar sand. The produced oils and spent sand resemble the products from screw pyrolysis reactor (SPR) tests suggesting that the ILFBR system functioned similar to the SPR systems with the recycle oil pyrolysis and extraction (ROPE{copyright}) process. With slight modifications in the heater control and placement, the system will be ready for development of operational parameters for the surface processing of tar sand. 10 refs., 2 figs., 1 tab.

  9. Fundamentals of asphaltene phase behavior in heavy oil and tar sands

    SciTech Connect

    Carnahan, N.F.; Quintero, L.

    1995-12-31

    As a continuation and update of work presented at the 5th UNITAR International Conference on Heavy Crude and Tar Sands, this presentation addresses the phase behavior of asphaltenes in terms of traditional thermodynamics of mixtures and in terms of interfacial phenomena known to be an integral part of the problem. Recent experimental studies have demonstrated the pressure effect on apparent reverse micelle behavior of asphaltenes in petroleum fluids. Published results have shown that certain commercial surfactants have been effective in ameliorating the problem of asphaltene precipitation in crude oils, and in solubilizing asphaltenes deposited in porous media. These recent observations correspond well with the concepts advanced in our previous studies. Phase behavior of asphaltenes in heavy crude and in tar sands is again addressed from the fundamental point of view, at the molecular level, to interpret observed behavior and to provide a logical means of forecasting expected behavior in these fluids under many different physical and chemical conditions. Interactions between resins and asphaltenes, in the presence of heavy crude or tar sands, do not follow classical thermodynamics, at least, not faithfully. Resins tend to interact as amphiphiles between the asphaltene-free material and the asphaltenes. Resins may be in solution with the asphaltene-free material; however, resins are adsorbed at the surface of the asphaltene aggregations, forming micelles or other amphiphilic structures. Phase behavior of asphaltenes, therefore, depends upon the thermodynamic equilibrium of resins distributed between the asphaltenes and the asphaltene-free material. In crude oils, resins may form solutions which reasonably conform to the Modified Regular Solution Theory, as described previously. At the asphaltene-resin interface, adsorption can be described in terms of classical theories of adsorption and/or similar association mechanisms for interfacial phenomena.

  10. In situ heat treatment from multiple layers of a tar sands formation

    SciTech Connect

    Vinegar, Harold J.

    2010-11-30

    A method for treating a tar sands formation is disclosed. The method includes providing a drive fluid to a first hydrocarbon containing layer of the formation to mobilize at least some hydrocarbons in the first layer. At least some of the mobilized hydrocarbons are allowed to flow into a second hydrocarbon containing layer of the formation. Heat is provided to the second layer from one or more heaters located in the second layer. At least some hydrocarbons are produced from the second layer of the formation.

  11. Method of condensing vaporized water in situ to treat tar sands formations

    DOEpatents

    Hsu, Chia-Fu

    2010-03-16

    Methods for treating a tar sands formation are described herein. Methods may include heating at least a section of a hydrocarbon layer in the formation from a plurality of heaters located in the formation. Heat may be allowed to transfer from the heaters to at least a first portion of the formation. Conditions may be controlled in the formation so that water vaporized by the heaters in the first portion is selectively condensed in a second portion of the formation. At least some of the fluids may be produced from the formation.

  12. Environmental, health, safety, and socioeconomic concerns associated with oil recovery from US tar-sand deposits: state-of-knowledge

    SciTech Connect

    Daniels, J.I.; Anspaugh, L.R.; Ricker, Y.E.

    1982-01-08

    Tar-sand petroleum-extraction procedures undergoing field testing for possible commercial application in the US include both surface (above-ground) and in situ (underground) procedures. The surface tar-sand systems currently being field tested in the US are thermal decomposition processes (retorting), and suspension methods (solvent extraction). Underground bitumen extraction procedures that are also being field tested domestically are in situ combustion and steam-injection. Environmental, health, safety, and socioeconomic concerns associated with construction and operation of 20,000-bbl/d commercial tar-sand surface and in situ facilities have been estimated and are summarized in this report. The principal regulations that commercial tar-sand facilities will need to address are also discussed, and environmental control technologies are summarized and wherever possible, projected costs of emission controls are stated. Finally, the likelihood-of-occurrence of potential environmental, health, and safety problems that have been determined are reviewed, and from this information inference is made as to the environmental acceptability of technologically feasible 20,000-bbl/d commercial tar-sand oil-extraction procedures.

  13. Volatile Organic Compound Observations near Oil Sands Mining, Upgrading and Refining Facilities in Alberta, Canada

    NASA Astrophysics Data System (ADS)

    Simpson, I. J.; Marrero, J.; Meinardi, S.; Barletta, B.; Krogh, E.; Blake, D. R.

    2012-12-01

    The oil sands of Alberta are the world's third-largest proven oil reserve. Even though the expansion of the oil sands industry has led to concerns about its impact on air quality, water quality and human health, emissions from the oil sands industry are very poorly characterized in the literature. During 2008-2012 our group collected 398 whole air samples downwind of (1) oil sands surface mining and upgrading facilities north of Fort McMurray, Alberta, and (2) chemical, petrochemical, and oil and gas facilities in the "Industrial Heartland" region of Fort Saskatchewan, Alberta. These high-precision measurements were made primarily in July 2008, August 2010, and July 2012 using canister sampling followed by multi-column gas chromatography analysis for 80 speciated volatile organic compounds (VOCs), with ppt-level detection limits. Strong VOC enhancements were measured downwind of upgrading operations near Fort McMurray, especially alkanes, aromatics and solvents. For example, maximum concentrations of 2,3-dimethylbutane, p-xylene and n-octane were 800-2400× the local background value (LBV), and the industrial solvent trichloroethene was up to 260× the LBV. We measured only small VOC enhancements at sites of naturally exposed oil sands, confirming that degraded air quality results from industrial activity rather than emission from natural sources. Remarkably strong VOC enhancements were detected in the Industrial Heartland, which is the largest hydrocarbon processing region in Canada. Some of the largest VOC excesses were measured in samples designated as "no smell", showing that absence of odor is not necessarily an indicator of good air quality. The maximum concentrations of methyl tert-butyl ether and ethylbenzene were 6200× the LBV, and concentrations of 1,3-butadiene, a known carcinogen, were 2400× the LBV. Thirty VOCs were present at levels above 1 ppbv, and maximum propene and i-pentane levels exceeded 100 ppbv. Remarkably, the maximum propene

  14. Historical trends in greenhouse gas emissions of the Alberta oil sands (1970-2010)

    NASA Astrophysics Data System (ADS)

    Englander, Jacob G.; Bharadwaj, Sharad; Brandt, Adam R.

    2013-12-01

    There has been increased scrutiny of the Alberta oil sands due to their high carbon intensity (CI) relative to conventional crude oil. Relying entirely on public and peer-reviewed data sources, we examine historical trends in the CI of oil sands extraction, upgrading, and refining. Monthly data were collected and interpolated from 1970 to 2010 (inclusive) for each oil sands project. Results show a reduction in oil sands CI over time, with industry-average full-fuel cycle (well-to-wheels, WTW) CI declining from 165 gCO2e MJ-1 higher heating value (HHV) of reformulated gasoline (RFG) to 105 (-12, +9) gCO2e MJ-1 HHV RFG. 2010 averages by production pathways are 102 gCO2e MJ-1 for Mining and 111 gCO2e MJ-1 for in situ. The CI of mining-based projects has declined due to upgrader efficiency improvements and a shift away from coke to natural gas as a process fuel. In situ projects have benefitted from substantial reductions in fugitive emissions from bitumen batteries. Both mining and in situ projects have benefitted from improved refining efficiencies. However, despite these improvements, the CI of oil sands production (on a pathway-average basis) ranges from 12 to 24% higher than CI values from conventional oil production. Due to growing output, total emissions from the oil sands continue to increase despite improved efficiency: total upstream emissions were roughly 65 MtCO2e in 2010, or 9% of Canada’s emissions.

  15. Evaluating the oil sands reclamation process: Assessing policy capacity and stakeholder access for government and non-governmental organizations operating in Alberta's oil sands

    NASA Astrophysics Data System (ADS)

    Patterson, Tyler

    By employing interpretive policy analysis this thesis aims to assess, measure, and explain policy capacity for government and non-government organizations involved in reclaiming Alberta's oil sands. Using this type of analysis to assess policy capacity is a novel approach for understanding reclamation policy; and therefore, this research will provide a unique contribution to the literature surrounding reclamation policy. The oil sands region in northeast Alberta, Canada is an area of interest for a few reasons; primarily because of the vast reserves of bitumen and the environmental cost associated with developing this resource. An increase in global oil demand has established incentive for industry to seek out and develop new reserves. Alberta's oil sands are one of the largest remaining reserves in the world, and there is significant interest in increasing production in this region. Furthermore, tensions in several oil exporting nations in the Middle East remain unresolved, and this has garnered additional support for a supply side solution to North American oil demands. This solution relies upon the development of reserves in both the United States and Canada. These compounding factors have contributed to the increased development in the oil sands of northeastern Alberta. Essentially, a rapid expansion of oil sands operations is ongoing, and is the source of significant disturbance across the region. This disturbance, and the promises of reclamation, is a source of contentious debates amongst stakeholders and continues to be highly visible in the media. If oil sands operations are to retain their social license to operate, it is critical that reclamation efforts be effective. One concern non-governmental organizations (NGOs) expressed criticizes the current monitoring and enforcement of regulatory programs in the oil sands. Alberta's NGOs have suggested the data made available to them originates from industrial sources, and is generally unchecked by government

  16. Characterization and distribution of metal and nonmetal elements in the Alberta oil sands region of Canada.

    PubMed

    Huang, Rongfu; McPhedran, Kerry N; Yang, Lingling; El-Din, Mohamed Gamal

    2016-03-01

    This review covers the characterization and distribution of metals and nonmetals in the Alberta oil sands region (AOSR) of Canada. The development of the oil sands industry has resulted in the release of organic, metal and nonmetal contaminants via air and water to the AOSR. For air, studies have found that atmospheric deposition of metals in the AOSR decreased exponentially with distance from the industrial emission sources. For water, toxic metal concentrations often exceeded safe levels leading to the potential for negative impacts to the receiving aquatic environments. Interestingly, although atmospheric deposition, surface waters, fish tissues, and aquatic bird eggs exhibited increasing level of metals in the AOSR, reported results from river sediments showed no increases over time. This could be attributed to physical and/or chemical dynamics of the river system to transport metals to downstream. The monitoring of the airborne emissions of relevant nonmetals (nitrogen and sulphur species) was also considered over the AOSR. These species were found to be increasing along with the oil sands developments with the resultant depositions contributing to nitrogen and sulphur accumulations resulting in ecosystem acidification and eutrophication impacts. In addition to direct monitoring of metals/nonmetals, tracing of air emissions using isotopes was also discussed. Further investigation and characterization of metals/nonmetals emissions in the AOSR are needed to determine their impacts to the ecosystem and to assess the need for further treatment measures to limit their continued output into the receiving environments. PMID:26766359

  17. Airborne Lidar Measurements of Pollution above the Oil Sands Region in Northern Alberta

    NASA Astrophysics Data System (ADS)

    Aggarwal, Monika; Whiteway, James; Seabrook, Jeffrey; Gray, Lawrence; Strawbridge, Kevin B.

    2016-06-01

    Lidar measurements of ozone and aerosol were conducted from a Twin Otter aircraft above the oil sands region of northern Alberta. For the majority of the flights, significant amounts of aerosol were observed within the boundary layer, up to an altitude of 2.0 km above sea level (ASL), while the ozone concentration remained at background levels (30-45 ppb) downwind of the industry. On August 24th the lidar measured a separated layer of aerosol above the boundary layer, at a height of 2.0 km ASL, in which the ozone mixing ratio increased to 70 ppb. Backward trajectory calculations revealed that the air containing this separated aerosol layer had passed over an area of forest fires. Directly below the layer of forest fire smoke, pollution from the oil sands industry was observed. Measurements of the backscatter linear depolarization ratio were obtained with a ground based lidar operated by Environment Canada within the oil sands region. The depolarization measurements aided in discriminating between the separate sources of pollution from industry and forest fires. The depolarization ratio was 5-6% in forest fire smoke and 7-10% in the industrial pollution.

  18. Control of small mammal damage in the Alberta oil sands reclamation and afforestation program

    SciTech Connect

    Radvanyi, A.

    1980-12-01

    Open-pit mining procedures being conducted in the oil sands of northeast Alberta greatly disrupt many acres of the environment. The reclamation and afforestation program intended to restore the forest habitat encountered an unanticipated problem when a large percentage of young nursery-raised trees planted on a tailings pond dyke and on overburden dump sites were found to have been girdled by a population of meadow voles which had become established in the dense grass habitat created to stabilize steep sandy slopes of the spoil piles. The study monitored small mammal populations through a high, low, and a second high level commensurate with the 3- to 4-year population cycle of small mammals. A control technique utilizing grain treated with an anticoagulant rodenticide made available to the mice in poisoned bait feeder stations effectively reduced small mammal numbers to very low levels and reduced girdling damage from an average of 50% to 1-2%.

  19. Environmental survey - tar sands in situ processing research program (Vernal, Uintah County, Utah). [Reverse-forward combustion; steam injection

    SciTech Connect

    Skinner, Q.

    1980-03-01

    Research will be done on the reverse-forward combustion and steam injection for the in-situ recovery of oil from tar sands. This environmental survey will serve as a guideline for the consideration of environmental consequences of such research. It covers the construction phase, operational phase, description of the environment, potential impacts and mitigations, coordination, and alternatives. (DLC)

  20. Varying properties of in situ heat treatment of a tar sands formation based on assessed viscosities

    DOEpatents

    Karanikas, John Michael; Vinegar, Harold J

    2014-03-04

    A method for treating a tar sands formation includes providing heat to at least part of a hydrocarbon layer in the formation from a plurality of heaters located in the formation. The heat is allowed to transfer from the heaters to at least a portion of the formation. A viscosity of one or more zones of the hydrocarbon layer is assessed. The heating rates in the zones are varied based on the assessed viscosities. The heating rate in a first zone of the formation is greater than the heating rate in a second zone of the formation if the viscosity in the first zone is greater than the viscosity in the second zone. Fluids are produced from the formation through the production wells.

  1. Moving hydrocarbons through portions of tar sands formations with a fluid

    DOEpatents

    Stegemeier, George Leo; Mudunuri, Ramesh Raju; Vinegar, Harold J.; Karanikas, John Michael; Jaiswal, Namit; Mo, Weijian

    2010-05-18

    A method for treating a tar sands formation is disclosed. The method includes heating a first portion of a hydrocarbon layer in the formation from one or more heaters located in the first portion. The heat is controlled to increase a fluid injectivity of the first portion. A drive fluid and/or an oxidizing fluid is injected and/or created in the first portion to cause at least some hydrocarbons to move from a second portion of the hydrocarbon layer to a third portion of the hydrocarbon layer. The second portion is between the first portion and the third portion. The first, second, and third portions are horizontally displaced from each other. The third portion is heated from one or more heaters located in the third portion. Hydrocarbons are produced from the third portion of the formation. The hydrocarbons include at least some hydrocarbons from the second portion of the formation.

  2. Technology assessment: environmental, health, and safety impacts associated with oil recovery from US tar-sand deposits

    SciTech Connect

    Daniels, J.I.; Anspaugh, L.R.; Ricker, Y.E.

    1981-10-13

    The tar-sand resources of the US have the potential to yield as much as 36 billion barrels (bbls) of oil. The tar-sand petroleum-extraction technologies now being considered for commercialization in the United States include both surface (above ground) systems and in situ (underground) procedures. The surface systems currently receiving the most attention include: (1) thermal decomposition processes (retorting); (2) suspension methods (solvent extraction); and (3) washing techniques (water separation). Underground bitumen extraction techniques now being field tested are: (1) in situ combustion; and (2) in situ steam-injection procedures. At this time, any commercial tar-sand facility in the US will have to comply with at least 7 major federal regulations in addition to state regulations; building, electrical, and fire codes; and petroleum-industry construction standards. Pollution-control methods needed by tar-sand technologies to comply with regulatory standards and to protect air, land, and water quality will probably be similar to those already proposed for commercial oil-shale systems. The costs of these systems could range from about $1.20 to $2.45 per barrel of oil produced. Estimates of potential pollution-emisson levels affecting land, air, and water were calculated from available data related to current surface and in situ tar-sand field experiments in the US. These data were then extrapolated to determine pollutant levels expected from conceptual commercial surface and in situ facilities producing 20,000 bbl/d. The likelihood-of-occurrence of these impacts was then assessed. Experience from other industries, including information concerning health and ecosystem damage from air pollutants, measurements of ground-water transport of organic pollutants, and the effectiveness of environmental-control technologies was used to make this assessment.

  3. InSAR Observations and Modeling of Anthropogenic Surface Deformation in the Alberta Oil Sands

    NASA Astrophysics Data System (ADS)

    Pearse, J.; Singhroy, V.; Samsonov, S. V.; Li, J.

    2014-12-01

    Recent Interferometric Synthetic Aperture Radar (InSAR) observations over northern Alberta, Canada show persistent surface uplift occurring at rates of 1-4 cm/year, localized at several sites where the Steam-Assisted Gravity Drainage (SAGD) technique is currently being used to extract bitumen from the Athabasca oil sands. We find that uplift rates above the horizontal injector wells are strongly correlated with rates of steam injection, even though there is a net fluid loss from the reservoir pore space as oil and water are withdrawn through the production wells. In combination with available steam injection and bitumen production data at four sites, we use numerical reservoir flow models to explain how the thermal and geomechanical effects of steam injection on an oil sand reservoir can generate uplift at the surface. Results of our numerical experiments show that persistent surface heave consistent with observed rates can be driven by stress changes in the reservoir due to porous flow and thermal expansion.

  4. Method of extracting liquid and gaseous fuel from oil shale and tar sand

    SciTech Connect

    Alterman, I.; Rom, J.; Shwartz, J.

    1981-05-12

    Kerogen and other combustible matter can be extracted from an area of oil shale or rar sand by drilling boreholes in a selected pattern through the overlying soil and rock without removing it. Each borehole mouth is tightly closed by a cover provided with an air inlet pipe and a gas exhaust pipe. In the covers of one or several boreholes, the inlet pipe is centrally guided and longitudinally movable in an upward and downward direction, and a laser beam generated by a laser source is inroduced into the upper end of the pipe and directed centrally to its bottom where it is diverted toward the borehole wall by a mirror assembly. The laser beam moved along the borehole wall irradiates the oil shale or tar sand and ignites the combustible matter contained therein which liquefies and evaporates. Combustion spreads from the initially ignited bore to the remaining bores in the area through the fissures in the formation and likewise serves to liquefy and evaporate the kerogen there. The combustion is maintained by pressurized air or oxygen introduced through the air inlet pipe, which also serves to cool the mirror assembly. The pressure thus created drives the evaporated kerogen out of the borehold through the exhaust pipe into a storage vessel. After the output has become too low, the process is discontinued and liquefied kerogen which has gathered at the bottom of the bores is pumped out or floated to the surface.

  5. Oil shale, tar sand, coal research, advanced exploratory process technology, jointly sponsored research

    SciTech Connect

    Not Available

    1992-01-01

    Progress made in five research programs is described. The subtasks in oil shale study include oil shale process studies and unconventional applications and markets for western oil shale.The tar sand study is on recycle oil pyrolysis and extraction (ROPE) process. Four tasks are described in coal research: underground coal gasification; coal combustion; integrated coal processing concepts; and sold waste management. Advanced exploratory process technology includes: advanced process concepts; advanced mitigation concepts; and oil and gas technology. Jointly sponsored research covers: organic and inorganic hazardous waste stabilization; CROW field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; PGI demonstration project; operation and evaluation of the CO[sub 2] HUFF-N-PUFF process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesaverde group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; shallow oil production using horizontal wells with enhanced oil recovery techniques; NMR analysis of sample from the ocean drilling program; and menu driven access to the WDEQ hydrologic data management system.

  6. Measurements of oxygenated volatile organic compounds in the oil sands region of Alberta

    NASA Astrophysics Data System (ADS)

    Moussa, S. G.; Leithead, A.; Li, S. M.; Gordon, M.; Hayden, K. L.; Wang, D. K.; Staebler, R. M.; Liu, P.; O'Brien, J.; Mittermeier, R.; Liggio, J.

    2014-12-01

    Oxygenated volatile organic compounds (OVOCs) are ubiquitous in the atmosphere, and represent an important fraction of volatile organic compounds. Additionally some OVOC species may pose health risks. OVOCs can affect the oxidative and radiative budget of the atmosphere since they are precursors to ground level ozone, hydroxyl radicals and secondary organic aerosols (SOA). OVOCs such as methanol, formaldehyde, acetaldehyde, acetone, crotonaldehyde, methylvinylketone (MVK), methylethylketone (MEK) and acrolein can be emitted from anthropogenic and biogenic sources. Additionally, they are the secondary products of the photo-oxidation of hydrocarbons (biogenic and anthropogenic). Understanding the magnitude of these sources is a prerequisite for accurate representations of radical cycling, ozone production and SOA formation in air quality models. The sources of OVOCs in the Alberta Oil Sands (OS) region have not previously been well characterized. In the summer of 2013, airborne measurements of various OVOCs were made in the Athabasca oil sands region between August 13 and September 7, 2013. Proton Transfer Reaction-Time of Flight-Mass Spectrometry (PTR-ToF-MS) was used to measure methanol, formaldehyde, acetaldehyde, acetone, crotonaldehyde, MVK, MEK, acrolein as well as other hydrocarbons. Emission ratios (ER) for several OVOCs (relative to carbon monoxide; CO) were used to estimate direct anthropogenic emissions from OS industrial sources, while the calculated OH radical exposures were used to estimate the production and removal of secondary anthropogenic OVOCs. The results indicate that OVOCs such as acetaldehyde, crotonaldehyde and MVK have both primary and secondary anthropogenic and biogenic sources. However, species such as methanol and acrolein are from biogenic and anthropogenic sources, respectively. The results of this work will help to characterize sources of OVOCs and the factors influencing their atmospheric fate in the Oil Sands region.

  7. Fifteen-year trends in criteria air pollutants in oil sands communities of Alberta, Canada.

    PubMed

    Bari, Md; Kindzierski, Warren B

    2015-01-01

    An investigation of ambient air quality was undertaken at three communities within the Athabasca Oil Sands Region (AOSR) of Alberta, Canada (Fort McKay, Fort McMurray, and Fort Chipewyan). Daily and seasonal patterns and 15-year trends were investigated for several criteria air pollutants over the period of 1998 to 2012. A parametric trend detection method using percentiles from frequency distributions of 1h concentrations for a pollutant during each year was used. Variables representing 50th, 65th, 80th, 90th, 95th and 98th percentile concentrations each year were identified from frequency distributions and used for trend analysis. Small increasing concentration trends were observed for nitrogen dioxide (<1ppb/year) at Fort McKay and Fort McMurray over the period consistent with increasing emissions of oxides of nitrogen (ca. 1000tons/year) from industrial developments. Emissions from all oil sands facilities appear to be contributing to the trend at Fort McKay, whereas both emissions from within the community (vehicles and commercial) and oil sands facility emissions appear to be contributing to the trend at Fort McMurray. Sulfur dioxide (SO2) emissions from industrial developments in the AOSR were unchanged during the period (101,000±7000tons/year; mean±standard deviation) and no meaningful trends were judged to be occurring at all community stations. No meaningful trends occurred for ozone and fine particulate matter (PM2.5) at all community stations and carbon monoxide at one station in Fort McMurray. Air quality in Fort Chipewyan was much better and quite separate in terms of absence of factors influencing criteria air pollutant concentrations at the other community stations. PMID:25454237

  8. Tracing industrial ammonium in atmospheric deposition in the Athabasca Oil Sands Region, Alberta, Canada

    NASA Astrophysics Data System (ADS)

    Mayer, B.; Proemse, B. C.; Fenn, M. E.

    2013-12-01

    The expanding industrial development in the Athabasca oil sands region (AOSR) in northeastern Alberta, Canada, has raised concerns about increasing nitrogen (N) emissions from oil sands operations and their potential effects on the surrounding terrestrial and aquatic ecosystems. Stable isotope techniques may help to trace industrial emissions provided that they are isotopically distinct from background isotope ratios of atmospheric N compounds. Ammonium deposition rates (NH4-N) typically exceed nitrate deposition rates (NO3-N) in the AOSR (Proemse et al., 2013), suggesting that emissions of reduced nitrogen compounds play a significant role for the atmospheric nitrogen budget in the AOSR. We collected atmospheric ammonium in open field bulk deposition and throughfall using ion exchange resins over ~6 months time periods from summer 2007 to summer 2011 located at distances between 3 to 113 km to one of the major oil sands developments in the AOSR. Ammonium deposition rates and δ15N-NH4 values were determined using ion chromatography and the ammonium diffusion method (Sebilo et al., 2004) on resin extracts. Atmospheric ammonium deposition rates in open field bulk collectors and throughfall collectors ranged from 1.0 to 4.7 kg ha-1 yr-1 NH4-N, and from 1.0 to 18.3 kg ha-1 yr-1 NH4-N, respectively. δ15N-NH4 values varied from -6.3 to +14.8‰ with the highest δ15N values typically associated with elevated NH4-N deposition rates. δ15N-NH4 values of up to +20.1‰ were observed for industrially emitted NH4 in particulate matter (PM2.5) emissions (Proemse et al., 2012) suggesting that industrial NH3 and NH4 emissions are associated with elevated δ15N values providing a potential tracer. Applying a two-end-member mixing analysis using a background δ15N-NH4 value of -3.6‰ for summer and -3.2‰ for winter periods revealed that particularly sites within ~30 km radius from the main oil sands developments are significantly affected by industrial contributions to

  9. Airborne Measurements of Secondary Organic Aerosol Formation in the Oil Sands Region of Alberta

    NASA Astrophysics Data System (ADS)

    Liggio, J.; Hayden, K.; Liu, P.; Leithead, A.; Moussa, S. G.; Staebler, R. M.; Gordon, M.; O'brien, J.; Li, S. M.

    2014-12-01

    The Alberta oil sands (OS) region represents a strategic natural resource and is a key driver of economic development. Its rapid expansion has led to a need for a more comprehensive understanding of the associated potential cumulative environmental impacts. In summer 2013, airborne measurements of various gaseous and particulate substances were made in the Athabasca oil sands region between August 13 and Sept 7, 2013. In particular, organic aerosol mass and composition measurements were performed with a High Resolution Time of flight Aerosol Mass Spectrometer (HR-ToF-AMS) supported by gaseous measurements of organic aerosol precursors with Proton Transfer Reaction (PTR) and Chemical Ionization (CI) mass spectrometers. These measurement data on selected flights were used to estimate the potential for local anthropogenic OS emissions to form secondary organic aerosol (SOA) downwind of precursor sources, and to investigate the importance of the surrounding biogenic emissions to the overall SOA burden in the region. The results of several flights conducted to investigate these transformations demonstrate that multiple distinct plumes were present downwind of OS industrial sources, each with differing abilities to form SOA depending upon factors such as NOx level, precursor VOC composition, and oxidant concentration. The results indicate that approximately 100 km downwind of an OS industrial source most of the measured organic aerosol (OA) was secondary in nature, forming at rates of ~6.4 to 13.6 μgm-3hr-1. Positive matrix factor (PMF) analysis of the HR-ToF-AMS data suggests that the SOA was highly oxidized (O/C~0.6) resulting in a measured ΔOA (difference above regional background OA) of approximately 2.5 - 3 despite being 100 km away from sources. The relative contribution of biogenic SOA to the total SOA and the factors affecting SOA formation during a number of flights in the OS region will be described.

  10. Small mammals as sentinels of oil sands related contaminants and health effects in northeastern Alberta, Canada.

    PubMed

    Rodríguez-Estival, Jaime; Smits, Judit E G

    2016-02-01

    The extraction of bitumen in areas of northeastern Alberta (Canada) has been associated with the release of complex mixtures of metals, metalloids, and polycyclic aromatic compounds (PACs) to the environment. To mitigate effects on ecosystems, Canadian legislation mandates that disturbed areas be reclaimed to an ecologically sustainable state after active operations. However, as part of reclamation activities, exposure to, and effects on wildlife living in these areas is not generally assessed. To support successful reclamation, the development of efficient methods to assess exposure and health effects in potentially exposed wildlife is required. In the present study, we investigated the usefulness of two native mammalian species (deer mouse Peromyscus maniculatus, and meadow vole Microtus pennsylvanicus) as sentinels of oil sands related contaminants by examining biomarkers of exposure and indicators of biological costs. Tissue residues of 31 metals and metalloids in kidneys and muscle, activity of the hepatic detoxification enzyme EROD (as a biomarker of exposure to organic contaminants), body condition, and the relative mass of liver, kidney, spleen, and testes were compared in animals from one reclaimed area and a reference site. Deer mice from the reclaimed site had higher renal levels of Co, Se and Tl compared to animals from the reference site, which was associated with reduced body condition. Lower testis mass was another feature that distinguished mice from the reclaimed site in comparison to those from the reference site. One mouse and one vole from the reclaimed site also showed increased hepatic EROD activity. In marked contrast, no changes were evident for these variables in meadow voles. Our results show that deer mouse is a sensitive sentinel species and that the biomarkers and indicators used here are efficient means to detect local contamination and associated biological effects in native mammals inhabiting reclaimed areas on active oil sands mine

  11. Assessment of Research Needs for Oil Recovery from Heavy-Oil Sources and Tar Sands (FERWG-IIIA)

    SciTech Connect

    Penner, S.S.

    1982-03-01

    The Fossil Energy Research Working Group (FERWG), at the request of J.W. Mares (Assistant Secretary for Fossil Energy) and A.W. Trivelpiece (Director, Office of Energy Research), has reviewed and evaluated the U.S. programs on oil recovery from heavy oil sources and tar sands. These studies were performed in order to provide an independent assessment of research areas that affect the prospects for oil recovery from these sources. This report summarizes the findings and research recommendations of FERWG.

  12. Method and apparatus for producing tar sand deposits containing conductive layers

    SciTech Connect

    Glandt, C.A.; Vinegar, H.J.; Gardner, J.W.

    1991-08-27

    This patent describes a process for recovering hydrocarbon from tar sand deposits containing high conductivity layers and a hydrocarbon rich zone. It comprises selecting a thin high conductivity target layer near the hydrocarbon rich zone; installing at least one pair of horizontal production wells that are horizontal electrodes during an electrical heating stage, and are production wells during a production stage, wherein the horizontal electrodes, when electrically excited, span the high conductivity target layer and divide the target layer into electrically heated zones and non-electrically heated zones; providing at least one injection well for hot fluid injection into the hydrocarbon rich zone; electrically exciting the horizontal electrodes during the electrical heating stage to electrically heat the high conductivity target layer to form a thin preheated hydrocarbon rich zone immediately adjacent to the target layer; injecting a hot fluid into the deposit adjacent to the high conductivity target layer and within the thin preheated hydrocarbon rich zone to displace the hydrocarbons to the production wells; and recovering hydrocarbons from the production wells.

  13. Long-term reliability of the Athabasca River (Alberta, Canada) as the water source for oil sands mining

    NASA Astrophysics Data System (ADS)

    St-Jacques, J. M.; Sauchyn, D.; Luckman, B. H.

    2015-12-01

    Exploitation of the Alberta oil sands, the world's third largest crude oil reserve, requires fresh water from the Athabasca River, an allocation of 4.4% of the mean annual flow. This allocation takes into account seasonal fluctuations but not long-term climatic variability and change. This paper examines the decadal-scale variability in river discharge in the Athabasca River Basin (ARB) with 1) a generalized-least-squares (GLS) regression analysis of the trend and variability in gauged flow, and 2) a 900-year tree-ring reconstruction of the water-year flow of the Athabasca River at Athabasca, Alberta. The GLS analysis removes confounding transient trends related to the Pacific Decadal Oscillation (PDO) and Pacific North American mode (PNA). It shows long-term declining flows throughout the ARB. The tree-ring record reveals a larger range of flows and severity of hydrologic deficits than those captured by the instrumental records that are the basis for surface water allocation. It includes periods of sustained low flow of multiple decades in duration, suggesting the influence of the PDO and PNA teleconnections. These results together demonstrate that low-frequency variability must be considered in ARB water allocation, which has not been the case. We show that the current and projected surface water allocations from the Athabasca River for the exploitation of the Alberta oil sands are based on an untenable assumption of the representativeness of the short instrumental record.

  14. Long-term reliability of the Athabasca River (Alberta, Canada) as the water source for oil sands mining

    PubMed Central

    Sauchyn, David J.; St-Jacques, Jeannine-Marie; Luckman, Brian H.

    2015-01-01

    Exploitation of the Alberta oil sands, the world’s third-largest crude oil reserve, requires fresh water from the Athabasca River, an allocation of 4.4% of the mean annual flow. This allocation takes into account seasonal fluctuations but not long-term climatic variability and change. This paper examines the decadal-scale variability in river discharge in the Athabasca River Basin (ARB) with (i) a generalized least-squares (GLS) regression analysis of the trend and variability in gauged flow and (ii) a 900-y tree-ring reconstruction of the water-year flow of the Athabasca River at Athabasca, Alberta. The GLS analysis removes confounding transient trends related to the Pacific Decadal Oscillation (PDO) and Pacific North American mode (PNA). It shows long-term declining flows throughout the ARB. The tree-ring record reveals a larger range of flows and severity of hydrologic deficits than those captured by the instrumental records that are the basis for surface water allocation. It includes periods of sustained low flow of multiple decades in duration, suggesting the influence of the PDO and PNA teleconnections. These results together demonstrate that low-frequency variability must be considered in ARB water allocation, which has not been the case. We show that the current and projected surface water allocations from the Athabasca River for the exploitation of the Alberta oil sands are based on an untenable assumption of the representativeness of the short instrumental record. PMID:26392554

  15. Potential impacts to perennial springs from tar sand mining, processing, and disposal on the Tavaputs Plateau, Utah, USA.

    PubMed

    Johnson, William P; Frederick, Logan E; Millington, Mallory R; Vala, David; Reese, Barbara K; Freedman, Dina R; Stenten, Christina J; Trauscht, Jacob S; Tingey, Christopher E; Kip Solomon, D; Fernandez, Diego P; Bowen, Gabriel J

    2015-11-01

    Similar to fracking, the development of tar sand mining in the U.S. has moved faster than understanding of potential water quality impacts. Potential water quality impacts of tar sand mining, processing, and disposal to springs in canyons incised approximately 200 m into the Tavaputs Plateau, at the Uinta Basin southern rim, Utah, USA, were evaluated by hydrogeochemical sampling to determine potential sources of recharge, and chemical thermodynamic estimations to determine potential changes in transfer of bitumen compounds to water. Because the ridgetops in an area of the Tavaputs Plateau named PR Spring are starting to be developed for their tar sand resource, there is concern for potential hydrologic connection between these ridgetops and perennial springs in adjacent canyons on which depend ranching families, livestock, wildlife and recreationalists. Samples were collected from perennial springs to examine possible progression with elevation of parameters such as temperature, specific conductance, pH, dissolved oxygen, isotopic tracers of phase change, water-rock interaction, and age since recharge. The groundwater age dates indicate that the springs are recharged locally. The progression of hydrogeochemical parameters with elevation, in combination with the relatively short groundwater residence times, indicate that the recharge zone for these springs includes the surrounding ridges, and thereby suggests a hydrologic connection between the mining, processing, disposal area and the springs. Estimations based on chemical thermodynamic approaches indicate that bitumen compounds will have greatly enhanced solubility in water that comes into contact with the residual bitumen-solvent mixture in disposed tailings relative to water that currently comes into contact with natural tar. PMID:26057623

  16. Reclamation of peat-based wetlands affected by Alberta, Canada's oil sands development

    NASA Astrophysics Data System (ADS)

    Foote, Lee; Ciborowski, Jan; Dixon, D. George; Liber, Karsten; Smits, Judit

    2013-04-01

    The ability to construct or reclaim functional peat-based wetlands as a replacement for those lost to development activity is uncertain. Oil sands development in northern Alberta, Canada will ultimately result in the removal of over 85 km2 of peat-based wetlands. To examine potential replacement of these lost peatlands we compared four treatments assigned to 16 known-age wetlands where we followed plant community, carbon dynamics, water quality, invertebrates and top predators for 5 years. Key questions followed by a synopsis of findings include: (1) Will wetland communities become more natural with age? - Yes, however industrial effluents of salinity and napthenates will slow succession and may truncate development compared to natural systems; (2) Can community succession be accelerated? - Yes, the addition of carbon-rich soils can facilitate development in some zones but cautions are raised about a "green desert" of vigorous plant stands with low insect and vertebrate diversity; (3) Is productivity sustainable? - Maybe, limitations of water chemistry (salinity and napthenates) and hydrologic regime appear to play large roles; (4) Will production support top predators? Sometimes; insectivorous birds, some small fish and a few amphibians persisted under all except the most saline and napthenate-enriched sites; (5) What is the role of the compromised water quality in reclamation? - Reduced diversity of plants, insects and vertebrates, reduced plant physiological efficiency and thus slower rates of reclamation. It is axiomatic and well demonstrated throughout Europe that it is easier and more cost effective to protect peatlands than it is to reclaim or create them. This is complicated, though, where mineral or property values soar to over 1 million per hectare. Industrial planners, governments and the public need to understand the options, possibilities, time frames and costs of peatland replacement to make the best land use decisions possible. Our research provides

  17. Oil Sands Operations in Alberta, Canada: A large source of secondary organic aerosol

    NASA Astrophysics Data System (ADS)

    Liggio, J.; Li, S. M.; Hayden, K.; Taha, Y. M.; Stroud, C.; Darlington, A. L.; Drollette, B.; Gordon, M.; Lee, P.; Liu, P.; Leithead, A.; Moussa, S.; Wang, D.; O'Brien, J.; Mittermeier, R. L.; Brook, J.; Lu, G.; Staebler, R. M.; Han, Y.; Tokarek, T. W.; Osthoff, H. D.; Makar, P.; Zhang, J.; Plata, D.; Gentner, D. R.

    2015-12-01

    Little is known of the reaction products of emissions to the atmosphere from extraction of oil from unconventional sources in the oil sands (OS) region of Alberta, Canada. This study examines these reaction products, and in particular, the extent to which they form secondary organic aerosol (SOA), which can significantly contribute to regional particulate matter formation. An aircraft measurement campaign was conducted over the Athabasca oil sands region between August 13 and September 7, 2013. A broad suite of measurements were made during 22 flights, including organic aerosol mass and composition with a High Resolution Time of Flight Aerosol Mass Spectrometer (HR-ToF-AMS) and organic aerosol gas-phase precursors by Proton Transfer Reaction (PTR) and off-line gas chromatography mass spectrometry. Large concentrations of organic aerosol were measured downwind of the OS region, which we show to be entirely secondary in nature. Laboratory experiments demonstrated that bitumen (the mined product) contains semi-volatile vapours in the C12-C18 range that will be emitted at ambient temperatures. When oxidized, these vapours form SOA with highly similar HR-ToF-AMS spectra to the SOA measured in the flights. Box modelling of the OS plume evolution indicated that the measured levels of traditional volatile organic compounds (VOCs) are not capable of accounting for the amount of SOA formed in OS plumes. This discrepancy is only reconciled in the model by including bitumen vapours along with their oxidation and condensation into the model. The concentration of bitumen vapours required to produce SOA matching observations is similar to that of traditional VOC precursors of SOA. It was further estimated that the cumulative SOA mass formation approximately 100 km downwind of the OS during these flights, and under these meteorological conditions was up to 82 tonnes/day. The combination of airborne measurements, laboratory experiments and box modelling indicated that semi

  18. Atmospheric dry deposition of sulfur and nitrogen in the Athabasca Oil Sands Region, Alberta, Canada.

    PubMed

    Hsu, Yu-Mei; Bytnerowicz, Andrzej; Fenn, Mark E; Percy, Kevin E

    2016-10-15

    Due to the potential ecological effects on terrestrial and aquatic ecosystems from atmospheric deposition in the Athabasca Oil Sands Region (AOSR), Alberta, Canada, this study was implemented to estimate atmospheric nitrogen (N) and sulfur (S) inputs. Passive samplers were used to measure ambient concentrations of ammonia (NH3), nitrogen dioxide (NO2), nitric acid/nitrous acid (HNO3/HONO), and sulfur dioxide (SO2) in the AOSR. Concentrations of NO2 and SO2 in winter were higher than those in summer, while seasonal differences of NH3 and HNO3/HONO showed an opposite trend, with higher values in summer. Concentrations of NH3, NO2 and SO2 were high close to the emission sources (oil sands operations and urban areas). NH3 concentrations were also elevated in the southern portion of the domain indicating possible agricultural and urban emission sources to the southwest. HNO3, an oxidation endpoint, showed wider ranges of concentrations and a larger spatial extent. Concentrations of NH3, NO2, HNO3/HONO and SO2 from passive measurements and their monthly deposition velocities calculated by a multi-layer inference model (MLM) were used to calculate dry deposition of N and S. NH3 contributed the largest fraction of deposited N across the network, ranging between 0.70-1.25kgNha(-1)yr(-1), HNO3/HONO deposition ranged between 0.30-0.90kgNha(-1)yr(-1), and NO2 deposition between 0.03-0.70kgNha(-1)yr(-1). During the modeled period, average dry deposition of the inorganic gaseous N species ranged between 1.03 and 2.85kgNha(-1)yr(-1) and SO4-S deposition ranged between 0.26 and 2.04kgha(-1)yr(-1). Comparisons with co-measured ion exchange resin throughfall data (8.51kgSha(-1)yr(-1)) indicate that modeled dry deposition combined with measured wet deposition (1.37kgSha(-1)yr(-1)) underestimated S deposition. Gas phase NH3 (71%) and HNO3 plus NO2 (79%) dry deposition fluxes dominated the total deposition of NH4-N and NO3-N, respectively. PMID:27295600

  19. Airborne Measurements of Aerosol Emissions From the Alberta Oil Sands Complex

    NASA Astrophysics Data System (ADS)

    Howell, S. G.; Clarke, A. D.; McNaughton, C. S.; Freitag, S.

    2012-12-01

    The Alberta oil sands contain a vast reservoir of fossil hydrocarbons. The extremely viscous bitumen requires significant energy to extract and upgrade to make a fluid product suitable for pipelines and further refinement. The mining and upgrading process constitute a large industrial complex in an otherwise sparsely populated area of Canada. During the ARCTAS project in June/July 2008, while studying forest fire plumes, the NASA DC-8 and P-3B flew through the plume a total of 5 times. Once was a coordinated visit by both aircraft; the other 3 were fortuitous passes downwind. One study has been published about gas emissions from the complex. Here we concentrate on aerosol emissions and aging. As previously reported, there appear to be at least 2 types of plumes produced. One is an industrial-type plume with vast numbers of ultrafine particles, SO2, sulfate, black carbon (BC), CO, and NO2. The other, probably from the mining, has more organic aerosol and BC together with dust-like aerosols at 3 μm and a 1 μm mode of unknown origin. The DC-8 crossed the plume about 10 km downwind of the industrial site, giving time for the boundary layer to mix and enabling a very crude flux calculation suggesting that sulfate and organic aerosols were each produced at about 500 g/s (estimated errors are a factor of 2, chiefly due to concerns about vertical mixing). Since this was a single flight during a project dedicated to other purposes and operating conditions and weather may change fluxes considerably, this may not be a typical flux. As the plume progresses downwind, the ultrafine particles grow to sizes effective as cloud condensation nucei (CCN), SO2 is converted to sulfate, and organic aerosol is produced. During fair weather in the summer, as was the case during these flights, cloud convection pumps aerosol above the mixed layer. While the aerosol plume is difficult to detect from space, NO2 is measured by the OMI instrument an the Aura satellite and the oil sands plume

  20. Statistical planning and analysis for treatments of tar sand wastewater. Final report

    SciTech Connect

    Pirie, W.R.

    1984-03-01

    The first part of this report discusses the overall statistical planning, coordination and design for several tar sand wastewater treatment projects contracted by the Laramie Energy Technology Center (LETC) of the Department of Energy. A general discussion of the benefits of consistent statistical design and analysis for data-oriented projects is included, with recommendations for implementation. A detailed outline of the principles of general linear models design is followed by an introduction to recent developments in general linear models by ranks (GLMR) analysis and a comparison to standard analysis using Gaussian or normal theory (GLMN). A listing of routines contained in the VPI Nonparametric Statistics Package (NPSP), installed on the Cyber computer system at the University of Wyoming is included. Part 2 describes in detail the design and analysis for treatments by Gas Flotation, Foam Separation, Coagulation, and Ozonation, with comparisons among the first three methods. Rank methods are used for most analyses, and several detailed examples are included. For optimization studies, the powerful tools of response surface analysis (RSA) are employed, and several sections contain discussion on the benefits of RSA. All four treatment methods proved to be effective for removal of TOC and suspended solids from the wastewater. Because the processes and equipment designs were new, optimum removals were not achieved by these initial studies and reasons for that are discussed. Pollutant levels were nevertheless reduced to levels appropriate for recycling within the process, and for such reuses as steam generation, according to the DOE/LETC project officer. 12 refs., 8 figs., 21 tabs.

  1. Surface chemistry features in the hot water processing of Utah tar sand

    SciTech Connect

    Misra, M.; Aguilar, R.; Miller, J.D.

    1981-01-01

    The hot water processing of Utah tar sand involves two important steps in the process sequence, phase disengagement (digestion) and phase separation (flotation). Inasmuch as phase separation is accomplished by flotation, the hydrophobic/hydrophilic balance at the surface of the bitumen droplets was studied in conjunction with the system's solution chemistry and the results correlated with the flotation response. Contact angle measurements of solvent extracted bitumen revealed a moderate hydrophobic character; however, air bubble attachment at the surface of bitumen obtained from a hot water concentrate was difficult and required long induction times. These results suggest that the phase separation by flotation is dependent on air bubble entrapment by bitumen droplets rather than attachment due to surface hydrophobicity. In addition, identification of surface functional groups and components solubilized during hot water digestion was attempted using IR and NMR spectra. Strong absorption peaks at 1708 cm/sup -1/, and 2855 cm/sup -1/ for the solubilized components together with NMR spectra indicate the presence of dissolved paraffinic carboxylates, the amount of which increased as the digestion pH was increased. Potentiometric titration of the water soluble constituents indicated an acid dissociation constant of pK/sub a/ approx. = 5 which would be expected for such carboxylate species. This phenomenon appears to account, in part, for the polar bitumen surface and the hydrophilic character of the digested bitumen. These and other results indicate that phase disengagement during digestion and bitumen hydrophobicity may be mutually exclusive effects and reinforce the notion that flotation separation is achieved by entrapment of air bubbles in the viscous bitumen droplets. 10 figures.

  2. Approach to Assessing the Effects of Aerial Deposition on Water Quality in the Alberta Oil Sands Region.

    PubMed

    Dayyani, Shadi; Daly, Gillian; Vandenberg, Jerry

    2016-02-01

    Snow cover forms a porous medium that acts as a receptor for aerially deposited polycyclic aromatic hydrocarbons (PAHs) and metals. The snowpack, acting as a temporary storage reservoir, releases contaminants accumulating over the winter during a relatively short melt period. This process could result in elevated concentrations of contaminants in melt water. Recent studies in the Alberta oil sands region have documented increases in snowpack and lake sediment concentrations; however, no studies have addressed the fate and transport of contaminants during the snowmelt period. This study describes modelling approaches that were developed to assess potential effects of aerially deposited PAHs and metals to snowpack and snowmelt water concentrations. The contribution of snowmelt to freshwater PAH concentrations is assessed using a dynamic, multi-compartmental fate model, and the contribution to metal concentrations is estimated using a mass-balance approach. The modelling approaches described herein were applied to two watersheds in the Alberta oil sands region for two planned oil sands developments. Accumulation of PAHs in a lake within the deposition zone was also modelled for comparison to observed concentrations. PMID:26803105

  3. Risk estimates of impacts from emerging tar-sand technologies. Paper IAEA-SM-254/26

    SciTech Connect

    Daniels, J.I.; Anspaugh, L.R.; Ricker, Y.E.; Rotariu, G.J.

    1981-06-11

    The risk of occurrence of significant unfavorable environmental, health, and safety impacts associated with tar-sand technologies have been estimated. These estimates were made from information related to typical emerging surface (above ground) and in situ (underground) tar-sand oil-recovery processes. Both types of processes are being developed for use on tar-sand deposits in the US and may also be applicable to deposits in other countries. The levels of pollutant emissions affecting land, air, and water were determined from data related to current US field experiments involving surface processes (including retort and solvent extraction methods), and in situ techniques (including combustion and steam-injection methods). Next, these data were extrapolated to determine pollutant levels expected from conceptual commercial facilities producing 20,000 bbl/d. These estimates predict the nature and magnitude of environmental, health, and safety impacts. The likelihood-of-occurrence of these impacts was then assessed. Experience from other industries, including information concerning health and ecosystem damage from air pollutants, measurements of ground-water transport of organic pollutants, and the effectiveness of environmental-control-technologies, was used to make this assessment. It was concluded from this assessment that certain adverse effects are more likely to occur than others. These effects can be ordered for surface and in situ technologies according to their likelihood-of-occurrence. Occupational health problems including those related to worker exposure to carcinogenic and other hazardous substances are likely to occur during surface extraction. Public health and ecosystem effects may occur from both technologies but will be localized and/or controllable. (DMC)

  4. Measurements of HONO in a Forested Region of Alberta Impacted by Oil Sands Processing Facilities

    NASA Astrophysics Data System (ADS)

    McLaren, R.; Nikelski, K.; Lobo, A.; Davis, Z.

    2015-12-01

    During the summer of 2013, measurements of NO2, SO2 and HONO were made at a ground site in a rural forested region of Alberta known to be impacted by several oil sands processing facilities. Such sources are known to be the main sources of NOx and SOx emissions in the region. Nitrous acid (HONO) can be emitted directly from combustion sources in addition to being formed from the heterogeneous hydrolysis of NO2 on moist surfaces. The measurements were made both day and night by Differential Optical Absorption Spectroscopy (DOAS) along a 2.304 km optical return path through the forest canopy using a 30-corner cube reflector. Nitrous acid (HONO) is of particular relevance to atmospheric chemistry as it can contribute to photochemical production of the OH radical, the main daytime oxidant in the troposphere, which was estimated to exceed 2•107 molec cm-3 on several days during the study, giving rise to rapid aerosol formation. Typically in urban areas HONO mixing ratios accumulate during the night, and are lost the next morning due to photolysis (HONO + hv→ OH + NO2). During this study however, HONO mixing ratios were found to be quite low with a median nightime mixing ratio of ~ 200 ppt. This is attributed to the very low nighttime NO2 precursor levels, perhaps in combination with a high surface area for deposition on the coniferous canopy. The low nighttime mixing ratios of NO2 and SO2 were driven by limited nocturnal mixing of elevated plumes down to the surface, while high daytime levels of NO2 and SO2 were episodic and frequently driven by daytime fumigation of the elevated plumes to the surface with additional contribution from surface sources of NOx. Daytime mixing ratios of HONO persisted longer than expected with median noontime mixing ratios of >50ppt. While this can imply an additional daytime source of HONO as has been observed by many others, it may also result from reduced photolysis rates below the canopy. This issue is being pursued more

  5. Elevated Nitrogen Deposition from Alberta Oil Sands Development Stimulates Phosphatase Activity in Dominant Sphagnum Moss Species

    NASA Astrophysics Data System (ADS)

    Kashi, N. N.; Wieder, R.; Vile, M. A.

    2013-12-01

    Emissions of NOx associated with Alberta oil sands (AOS) development are leading to locally elevated atmospheric N deposition, in a region where background N deposition has been historically quite low (< 1 kg/ha/yr). This elevated N deposition has the potential to alter the ecosystem structure and function of nutrient-poor boreal peatlands. Nitrogen enrichment may alter soil microbial activity, which could be manifested in changes in extracellular enzyme activities. Since 2011, we have been experimentally adding N as NH4NO3 in simulated precipitation at 0, 5, 10, 15, 20, and 25 kg N ha/yr/ plus no-water controls to a boreal bog and a poor fen (3 replicate plots per treatment). In 2013, acid phosphatase activities in living plant capitulum of Sphagnum angustifolium, Sphagnum fuscum, and Sphagnum magellanicum were quantified in June and July using 4-methyumbelliferylphosphate and fluorescence detection of the enzymatically released methylumbelliferone (MUF). Phosphatase activities did not differ with N treatment for S. angustifolium in the bog (p=0.3409) or the poor fen (p=0.0629), or for S. fuscum in the bog (p=0.1950), averaging 35.0 × 0.7, 61.6 × 1.2, and 41.6 × 0.9 μmol MUF/g DWT/hr, respectively. For S. fuscum in the poor fen, phosphatase activities differed between N treatments (p=0.0275), ranging 40.6 × 1.1 μmol MUF/g DWT/hr in the control plots to 73.7 × 2.0 μmol MUF/g DWT/hr in the 5 kg/ha/yr N treatment plots; increasing N deposition did not result in a gradual change in enzyme activity. On the other hand, S. magellanicum phosphatase activities differed between N treatments (p=0.0189) and showed a pattern of generally increasing activity with increasing N deposition (37.4 × 0.5 μmol MUF/g DWT/hr in control plots; 97.9 × 4.5 μmol MUF/g DWT/hr in the 25 kg/ha/yr N treatment plots). The differing phosphatase responses between these dominant Sphagnum species suggest unique differences in nutrient balance and/or microbial activity. Combining the

  6. Bog Plant Tissue Chemistry as Indicators of Regionally Elevated Atmospheric N and S Deposition in the Alberta Oil Sands Region

    NASA Astrophysics Data System (ADS)

    Wieder, R.; Vile, M. A.; Scott, K. D.; Vitt, D. H.; Quinn, J.

    2011-12-01

    Nitrogen oxide and sulfur oxide emission from ongoing development of oil sands in northern Alberta results in regionally elevated atmospheric deposition of N and S in an area where background deposition of both N and S is exceptionally low (less than 1 kg/ha/yr). Because bogs, which represent major landforms in the Alberta oil sands region, are believed to be N-limited and potentially sensitive to S inputs, we have been investigating the effects of elevated N deposition on C, N, and S cycling in bogs, as well as the potential of bogs to serve as monitors of N and S deposition. Toward this latter end, we have measured seasonal variation (5 sampling dates between June and October 2009) concentrations of N and S, as well as δ15N value, in leaf tissues (Picea mariana (ectomycorrhizal); Ledum groenlandicum, Oxycoccos microcarpon, Vaccinium vitis-idaea (ericoid mycorrhizal); Rubus chamaemorus, and Smilacina trifolia (nonmycorrhizal), Sphagnum (S. fuscum, S. capillifolium, S. magellanicum, S. angustifolium) moss capitula (top 1-cm of plant) and lichens (Cladina mitis and Evernia mesomorpha) at 5 bogs at distances ranging from 14 to 300 km from the heart of the oil sands mining area. Averaged across all sites and sampling dates, N concentrations in ectomycorrhizal, ericoid mycorrhizal, nonmycorrhizal, Sphagnum, and lichens was 8.6 + 0.2, 11.9 + 0.2, 26.3 + 0.6, 10.2 + 0.1, 7.2 + 0.2 mg/g, respectively; δ15N values were -10.3 + 0.1, -6.0 + 0.1, 1.7 + 0.2, -5.3 + 0.1, -4.7 + 0.1 mg/g, respectively, and S concentrations were 1.07 + 0.2, 1.31 + 0.2, 1.94 + 0.6, 1.46 + 0.2, 1.11 + 0.3 mg/g, respectively. Plant functional groups and individual species behaved differently with respect to both seasonal variation and site differences, often with significant interactions when analyzed using two-way analyses of variance. Some species exhibited seasonal variation in some aspects

  7. Potential methane production and oxidation in soil reclamation covers of an oil sands mining site in Alberta, Canada

    NASA Astrophysics Data System (ADS)

    Pum, Lisa; Reichenauer, Thomas; Germida, Jim

    2015-04-01

    Anthropogenic activities create a number of significant greenhouse gases and thus potentially contribute to global warming. Methane production is significant in some agricultural production systems and from wetlands. In soil, methane can be oxidised by methanotrophic bacteria. However, little is known about methane production and oxidation in oil sand reclamation covers. The purpose of this study was to investigate methane production and oxidation potential of tailing sands and six different reclamation layers of oil sands mining sites in Alberta, Canada. Methane production and oxidation potential were investigated in laboratory scale microcosms through continuous headspace analysis using gas chromatography. Samples from a reclamation layer were collected at the Canadian Natural Resources Limited (CNRL) reclamation site at depths of 0-10 cm, 10-20 cm and 20-40 cm in October 2014. In addition, tailing sands provided by Suncor Energy Inc. and soil from a CNRL wetland were studied for methane production. Samples were dried, crushed and sieved to 4 mm, packed into serum bottle microcosms and monitored for eight weeks. Methane production potential was assessed by providing an anoxic environment and by adjusting the samples to a moisture holding capacity of 100 %. Methane oxidation potential was examined by an initial application of 2 vol % methane to the microcosms and by adjusting the samples to a moisture holding capacity of 50 %. Microcosm headspace gas was analysed for methane, carbon dioxide, nitrous oxide and oxygen. All experiments were carried out in triplicates, including controls. SF6 and Helium were used as internal standards to detect potential leaks. Our results show differences for methane production potential between the soil depths, tailing sands and wetlands. Moreover, there were differences in the methane oxidation potential of substrate from the three depths investigated and between the reclamation layers. In conclusion, the present study shows that

  8. Determining air pollutant emission rates based on mass balance using airborne measurement data over the Alberta oil sands operations

    NASA Astrophysics Data System (ADS)

    Gordon, M.; Li, S.-M.; Staebler, R.; Darlington, A.; Hayden, K.; O'Brien, J.; Wolde, M.

    2015-09-01

    Top-down approaches to measure total integrated emissions provide verification of bottom-up, temporally resolved, inventory-based estimations. Aircraft-based measurements of air pollutants from sources in the Canadian oil sands were made in support of the Joint Canada-Alberta Implementation Plan for Oil Sands Monitoring during a summer intensive field campaign between 13 August and 7 September 2013. The measurements contribute to knowledge needed in support of the Joint Canada-Alberta Implementation Plan for Oil Sands Monitoring. This paper describes the top-down emission rate retrieval algorithm (TERRA) to determine facility emissions of pollutants, using SO2 and CH4 as examples, based on the aircraft measurements. In this algorithm, the flight path around a facility at multiple heights is mapped to a two-dimensional vertical screen surrounding the facility. The total transport of SO2 and CH4 through this screen is calculated using aircraft wind measurements, and facility emissions are then calculated based on the divergence theorem with estimations of box-top losses, horizontal and vertical turbulent fluxes, surface deposition, and apparent losses due to air densification and chemical reaction. Example calculations for two separate flights are presented. During an upset condition of SO2 emissions on one day, these calculations are within 5 % of the industry-reported, bottom-up measurements. During a return to normal operating conditions, the SO2 emissions are within 11 % of industry-reported, bottom-up measurements. CH4 emissions calculated with the algorithm are relatively constant within the range of uncertainties. Uncertainty of the emission rates is estimated as less than 30 %, which is primarily due to the unknown SO2 and CH4 mixing ratios near the surface below the lowest flight level.

  9. Coupling lead isotopes and element concentrations in epiphytic lichens to track sources of air emissions in the Alberta Oil Sands Region

    EPA Science Inventory

    A study was conducted that coupled use of element concentrations and lead (Pb) isotope ratios in the lichen Hypogymnia physodes collected during 2002 and 2008, to assess the impacts of air emissions from the Alberta Oil Sands Region (AOSR, Canada) mining and processing operations...

  10. Could Poor Fens BE More Sensitive than Bogs to Elevated N Deposition in the Oil Sands Region of Northern Alberta?

    NASA Astrophysics Data System (ADS)

    Wieder, R. K.; Vile, M. A.; Scott, K. D.

    2015-12-01

    Bogs and fens cover 29% of the 140,000 km2 Oil Sands Administrative Area (OSAA) in northern Alberta, a region characterized by quite low background N deposition (1-2 kg/ha/yr). However, development of the oil sands resource has led to increasing emission of nitrogen oxides, which are then returned to regional ecosystems as elevated atmospheric N deposition. Given the nutrient deficient nature of bogs and poor fens, elevated N deposition from oil sands development could potentially affect peatland ecosystem structure and function. To evaluate the ecosystem-level effects of N deposition, since 2011, we have experimentally applied N to a bog and a poor fen near Mariana Lakes, Alberta, located far enough from the OSAA to be unaffected by oil sands emissions. Treatments include simulated rainfall equivalent to N deposition of 0, 5, 10, 15, 20, and 25 kg/ha/yr, plus control plots receiving no added water (3 replicate plots per site per N treatment). Concentrations of NH4+-N, NO3- N, and DON at the top of the peatland water table did not increase with increasing N deposition, averaging 0.61, 0.09, and 1.07 mg/L, respectively, in the bog, and 0.53, 0.10, and 0.81 mg/L, respectively, in the poor fen. Ericaceous shrub abundance increased with increasing N deposition in both the bog and the poor fen, although plot-scale greenness (hand-held spectral measurement of the Normalized Difference Red Edge (NDRE) index) increased with N deposition in the poor fen, but not in the bog. Segmented regression indicated that in the poor fen, at N deposition above 14-16 kg/ha/yr, total microbial, bacterial, and fungal biomass in the top 5 cm of peat increased with N deposition, with no effect at lower N deposition. No effect of N deposition on microbial, bacterial, or fungal biomass was observed at 5-10 cm in the poor fen, or at either 0-5 or 5-10 cm in the bog. In the poor fen, microbial, bacterial, and fungal biomass increased with NDRE, but the effect was not significant in the bog

  11. Understanding ozone formation and the radical budget during oil sands plume transport in the Athabasca region of Alberta

    NASA Astrophysics Data System (ADS)

    Moussa, S. G.; Leithead, A.; Li, S. M.; Wang, D. K.; O'brien, J.; Mittermeier, R. L.; Gordon, M.; Staebler, R. M.; Liu, P.; Liggio, J.

    2015-12-01

    The sources of ozone and hydroxyl radicals (OH) in the Alberta oil sands (OS) region have not previously been well characterized. In the summer of 2013, airborne measurements of various volatile organic compounds (VOCs), nitrogen oxides (NOx = NO2+NO) and ozone were made in the Athabasca OS region between August 13 and September 7, 2013. Proton Transfer Reaction-Time of Flight-Mass Spectrometry (PTR-ToF-MS) and whole air samples were used to measure VOCs. A box model incorporating the Master Chemical Mechanism (MCM v3.3), was constrained by measured chemical species and meteorological parameters and used to simulate the evolution of an OS plume. In doing so, an improved understanding of the chemical factors controlling the radical budget and the evolution of ozone in oil sands plumes is achieved. Our results indicate that approximately 20% of the in-plume generated OH radicals are derived from primary sources (HCHO, O3 and HONO photolysis). The remaining OH is derived from the recycling of hydroperoxyl radical (HO2). The HO2 and alkyl peroxyl radical (RO2) chemistry leads to 35% of the ozone formation in the plume, while the main sink for ozone in the plume was via reactions with alkenes (anthropogenic and biogenic). The results of this work will help to characterize ozone formation and the factors influencing its atmospheric fate in the oil sands region.

  12. Polycyclic aromatic hydrocarbons in caribou, moose, and wolf scat samples from three areas of the Alberta oil sands.

    PubMed

    Lundin, Jessica I; Riffell, Jeffrey A; Wasser, Samuel K

    2015-11-01

    Impacts of toxic substances from oil production in the Alberta oil sands (AOS), such as polycyclic aromatic hydrocarbons (PAHs), have been widely debated. Studies have been largely restricted to exposures from surface mining in aquatic species. We measured PAHs in Woodland caribou (Rangifer tarandus caribou), moose (Alces americanus), and Grey wolf (Canis lupus) across three areas that varied in magnitude of in situ oil production. Our results suggest a distinction of PAH level and source profile (petro/pyrogenic) between study areas and species. Caribou samples indicated pyrogenic sourced PAHs in the study area previously devastated by forest fire. Moose and wolf samples from the high oil production area demonstrated PAH ratios indicative of a petrogenic source and increased PAHs, respectively. These findings emphasize the importance of broadening monitoring and research programs in the AOS. PMID:26284348

  13. An NMR (Nuclear Magnetic Resonance) Investigation of the Chemical Association and Molecular Dynamics in Asphalt Ridge Tar Sand Ore and Bitumen

    DOE R&D Accomplishments Database

    Netzel, D. A.; Coover, P. T.

    1987-09-01

    Preliminary studies on tar sand bitumen given in this report have shown that the reassociation of tar sand bitumen to its original molecular configuration after thermal stressing is a first-order process requiring nearly a week to establish equilibrium. Studies were also conducted on the dissolution of tar sand bitumen in solvents of varying polarity. At a high-weight fraction of solute to solvent the apparent molecular weight of the bitumen molecules was greater than that of the original bitumen when dissolved in chloroform-d{sub 1} and benzene-d{sub 6}. This increase in the apparent molecular weight may be due to micellar formation or a weak solute-solvent molecular complex. Upon further dilution with any of the solvents studied, the apparent molecular weight of the tar sand bitumen decreased because of reduced van der Waals forces of interaction and/or hydrogen bonding. To define the exact nature of the interactions, it will be necessary to have viscosity measurements of the solutions.

  14. An NMR (nuclear magnetic resonance) investigation of the chemical association and molecular dynamics in asphalt ridge tar sand ore and bitumen

    SciTech Connect

    Netzel, D.A.; Coover, P.T.

    1987-09-01

    Preliminary studies on tar sand bitumen given in this report have shown that the reassociation of tar sand bitumen to its original molecular configuration after thermal stressing is a first-order process requiring nearly a week to establish equilibrium. Studies were also conducted on the dissolution of tar sand bitumen in solvents of varying polarity. At a high-weight fraction of solute to solvent the apparent molecular weight of the bitumen molecules was greater than that of the original bitumen when dissolved in chloroform-d/sub 1/ and benzene-d/sub 6/. This increase in the apparent molecular weight may be due to micellar formation or a weak solute-solvent molecular complex. Upon further dilution with any of the solvents studied, the apparent molecular weight of the tar sand bitumen decreased because of reduced van der Waals forces of interaction and/or hydrogen bonding. To define the exact nature of the interactions, it will be necessary to have viscosity measurements of the solutions. 30 refs., 3 figs., 3 tabs.

  15. Geologic influences on the in situ processing of tar sand at the Northwest Asphalt Ridge deposit, Utah

    SciTech Connect

    Sinks, D.J.

    1985-01-01

    The Laramie Energy Technology Center, Department of Energy, completed three in situ oil recovery field experiments, two combustion and one steamflood, in tar sand at Northwest Asphalt Ridge, Utah. Inadequate resource and site characterization prior to the field experiments contributed to process design and operation problems. The 10-acre field site is part of the Sohio Shale Oil Co. D tract located west of Vernal, Uintah County. The target zone, the middle portion of the Cretaceous Rim Rock Sandstone of the Mesaverde Group, varied from 300 to 500 feet deep. From petrographic analyses of the target zone, this portion is classified as a moderately sorted litharenite with an average visible porosity of 18%. Dominant constituents include quartz, rock fragments, chert, feldspars and clay minerals. X-ray analyses of selected core samples from the Rim Rock and Asphalt Ridge Sandstones indicate the presence of quartz, calcite, dolomite, ankerite, microcline, orthoclase, anorthite, kaolinite and muscovite. Carbonate mineral species were present only in the lower Rim Rock and Asphalt Ridge Sandstones. Reservoir characteristics of the target zone which adversely affected the field experiments include faulting at all three experiment areas, lateral and vertical heterogeneities of permeability and porosity, inadequate target zone confinement, rough surface texture of clastic grains, and oil-wet grains. Favorable target zone characteristics include high quartz content; absence of carbonates; lack of clay minerals bridging and cementing pore spaces; and sufficient porosity, initial oil saturation and overburden. Recommended geologic evaluation methods to aid in the identification of potentially suitable resources and sites for in situ oil recovery from tar sands include seismic surveys; well logging; coring and core analyses; petrographic, binocular, and scanning electron microscopy; and x-ray analyses. 54 references, 25 figures, 8 tables.

  16. Dissolved organic carbon in a constructed and natural fens in the Athabasca oil sands region, Alberta, Canada.

    PubMed

    Khadka, Bhupesh; Munir, Tariq M; Strack, Maria

    2016-07-01

    In the Athabasca oil sands region near Fort McMurray, Alberta, Canada, peatlands are disturbed extensively in order to recover bitumen below the surface. Hence, following oil sands mining, landscape reclamation is a part of the mine closure process in order to return functioning ecosystems, including peatlands, to the region. This study was conducted at a pilot fen reclamation project and three other diverse natural (poor, rich and saline) fens in the oil sands region during the growing seasons of 2013 and 2014, the first and second year post-construction. Ecosystem functioning of the constructed fen (CF) was evaluated with reference to natural fens based on pore water dissolved organic carbon (DOC) concentration and chemistry. Significant variation of DOC concentration among the reference fens was observed, varying from an average of 42.0mg/L at the rich fen (RF) to 70.8mg/L at the saline fen (SF). Dissolved organic carbon concentration at CF was significantly lower than at all reference fens, but increased significantly over the first two years. Seasonal variation of DOC concentration was also observed in each site with concentration increasing over the growing season. At CF, DOC was comprised of larger, more humic and complex aromatic compounds than reference fens in the first year post-construction based on its spectrophotometric properties; however, these differences were reduced in the second year. Initial DOC concentration and chemistry at CF was indicative of the source being largely the peat placed during fen construction. Changes in chemistry and increasing concentration of DOC in the second growing season likely resulted from increasing inputs from plants established on site. These results suggest that DOC concentration is likely to increase in future at CF as vascular plant productivity increases and in response to salinity sourced from tailing sand used to construct the catchment. PMID:27037879

  17. Phytoremediation of Alberta oil sand tailings using native plants and fungal endophytes

    NASA Astrophysics Data System (ADS)

    Repas, T.; Germida, J.; Kaminskyj, S.

    2012-04-01

    Fungal endophytes colonize host plants without causing disease. Some endophytes confer plant tolerance to harsh environments. One such endophyte, Trichoderma harzianum strain TSTh20-1, was isolated from a plant growing on Athabasca oil sand tailings. Tailing sands are a high volume waste product from oil sand extraction that the industry is required to remediate. Tailing sands are low in organic carbon and mineral nutrients, and are hydrophobic due to residual polyaromatic hydrocarbons. Typically, tailing sands are remediated by planting young trees in large quantities of mulch plus mineral fertilizer, which is costly and labour intensive. In greenhouse trials, TSTh20-1 supports growth of tomato seedlings on tailing sands without fertilizer. The potential use of TSTh20-1 in combination with native grasses and forbs to remediate under field conditions is being assessed. Twenty-three commercially available plant species are being screened for seed germination and growth on tailing sands in the presence of TSTh20-1. The best candidates from this group will be used in greenhouse and small scale field trials. Potential mechanisms that contribute to endophyte-induced plant growth promotion, such as plant hormone production, stress tolerance, mineral solubilization, and uptake are also being assessed. As well, TSTh20-1 appears to be remarkably frugal in its nutrient requirements and the possibility that this attribute is characteristic of other plant-fungal endophytes from harsh environments is under study.

  18. Characterization of Clay Minerals and Kerogen in Alberta Oil Sands Geological End Members

    NASA Astrophysics Data System (ADS)

    Zheng, Limin

    The high degree of variability of oil sands ores can be attributed to a mixture of different geological end members, i.e., estuarine sand, estuarine clay, marine sand and marine clay. This study focused on the mineralogy, especially of clay minerals, and toluene insoluble organic matter, referred to as kerogen, in different oil sands end members. Clays and kerogens will likely have a significant impact on solvent recovery from the gangue following non-aqueous bitumen extraction. The bitumen-free solids were subjected to mineralogical and geochemical analysis. Kerogens were isolated and analyzed by various characterization methods. The types of clays were identified in oriented samples by X-ray diffraction analysis. The nitrogen to carbon ratio in the isolated kerogens is found to be higher than in bitumen. There are more type III kerogens in estuarine samples and more type II kerogens in marine samples.

  19. Natural radioactivity of the tar-sand deposits of Ondo State, Southwestern Nigeria

    NASA Astrophysics Data System (ADS)

    Fasasi, M. K.; Oyawale, A. A.; Mokobia, C. E.; Tchokossa, P.; Ajayi, T. R.; Balogun, F. A.

    2003-06-01

    A combination of gamma spectrometry and energy dispersive X-ray fluorescence was used to determine the presence and level of radioactivity of radionuclides in bituminous sand and overburden obtained from bituminous sand deposits in Ondo State Nigeria for the purpose of providing baseline data and assessing its impact on the environment. The radionuclides identified with reliable regularity belong to the decay series of naturally occurring radionuclides headed by 238U and 232Th. The non-decay series of naturally occurring 40K was found to be below the limit of detection. The average specific activity concentration values obtained for 214 Bi, 208Tl, and 226Ra in the overburden are 165.64±2.91, 150.25±2.91 and 60.97±2.27 Bq kg -1, respectively. The measured activity in the bituminous sand layer is so low that it can be said to be non-radioactive. The result of the EDXRF supports the presence of radioelements in the overburden, which are likely to be embedded in accessory minerals like zircon and tourmaline. Thus, surface exploration technique using soil-gas radon measurement will not yield the desired result. Furthermore, the level of radioelements and associated decay daughter 222Rn is not expected to cause any health hazard.

  20. Has Alberta Oil Sands Development Altered Delivery of Polycyclic Aromatic Compounds to the Peace-Athabasca Delta?

    PubMed Central

    Hall, Roland I.; Wolfe, Brent B.; Wiklund, Johan A.; Edwards, Thomas W. D.; Farwell, Andrea J.; Dixon, D. George

    2012-01-01

    Background The extent to which Alberta oil sands mining and upgrading operations have enhanced delivery of bitumen-derived contaminants via the Athabasca River and atmosphere to the Peace-Athabasca Delta (200 km to the north) is a pivotal question that has generated national and international concern. Accounts of rare health disorders in residents of Fort Chipewyan and deformed fish in downstream ecosystems provided impetus for several recent expert-panel assessments regarding the societal and environmental consequences of this multi-billion-dollar industry. Deciphering relative contributions of natural versus industrial processes on downstream supply of polycyclic aromatic compounds (PACs) has been identified as a critical knowledge gap. But, this remains a formidable scientific challenge because loading from natural processes remains unknown. And, industrial activity occurs in the same locations as the natural bitumen deposits, which potentially confounds contemporary upstream-downstream comparisons of contaminant levels. Methods/Principal Findings Based on analyses of lake sediment cores, we provide evidence that the Athabasca Delta has been a natural repository of PACs carried by the Athabasca River for at least the past two centuries. We detect no measureable increase in the concentration and proportion of river-transported bitumen-associated indicator PACs in sediments deposited in a flood-prone lake since onset of oil sands development. Results also reveal no evidence that industrial activity has contributed measurably to sedimentary concentration of PACs supplied by atmospheric transport. Conclusions/Significance Findings suggest that natural erosion of exposed bitumen in banks of the Athabasca River and its tributaries is a major process delivering PACs to the Athabasca Delta, and the spring freshet is a key period for contaminant mobilization and transport. This baseline environmental information is essential for informed management of natural resources

  1. Evaluating Function of a Constructed Fen in Alberta's Oil Sands Region Using Dissolved Organic Carbon Concentration and Chemistry

    NASA Astrophysics Data System (ADS)

    Strack, M.; Khadka, B.

    2014-12-01

    Peatlands, mainly fens, account for close to 65% of the landscape in the oil sands region near Fort McMurray, Alberta. Since mine closure plans require landscape reclamation, methods for fen construction are being investigated. As reclamation goals include the return of ecosystem function, criteria for evaluation must be developed. In this study we compare soil concentrations and spectrophometric properties of dissolved organic carbon (DOC) from a constructed fen during its first growing season with that collected from three diverse, undisturbed reference fens in the region. The constructed fen had lower DOC concentration than all the reference fens. Based on E2/E3, E4/E6 and specific UV absorbance of the DOC, the constructed fen had DOC with significantly greater humic content, aromatic nature, and larger molecular size than the reference fens. Results from laboratory DOC production studies indicate that these patterns are likely due to the limited DOC contribution from the newly planted vegetation at the constructed fen, resulting in DOC largely derived from humified peat placed during construction. These preliminary results suggest that DOC concentration and chemistry provide information about the ecological development of the constructed system that could be useful for evaluating reclamation success through time.

  2. Characterization and utilization of hydrotreated products produced from the Whiterocks (Utah) tar sand bitumen-derived liquid

    SciTech Connect

    Tsai, C.H.; Longstaff, D.C.; Deo, M.D.; Hanson, F.V.; Oblad, A.G.

    1991-01-01

    The bitumen-derived liquid produced in a 4-inch diameter fluidized-bed reactor from the mined and crushed ore from the Whiterocks tar sand deposit has been hydrotreated in a fixed-bed reactor. The purpose was to determine the extent of upgrading as a function of process operating variable. A sulfided nickel-molybendum on alumina hydrodenitrogenation catalyst was used in all experiments. Moderately severe operating conditions were employed; that is, high reaction temperature (617--680 K) high reactor pressure (11.0--17.1 MPa) and low liquid feed rate (0.18--0.77 HSV); to achieve the desired reduction in heteroatom content. Detailed chemical structures of the bitumen-derived liquid feedstock and the hydrotreated total liquid products were determined by high resolution gas chromatography - mass spectrometry analyses. The compounds identified in the native bitumen included isoprenoids; bicyclic, tricycle, and tetracyclic terpenoids; steranes; hopanes; and perhydro-{beta}-carotenes. In addition, normal and branched alkanes and alkenes and partially dehydrogenated hydroaromatics were identified in the bitumen-derived liquid. The dominant pyrolysis reactions were: (1) the dealkylation of long alkyl side chains to form {alpha} - and isoolefins; and (2) the cleavage of alkyl chains linking aromatic and hydroaromatic clusters. Olefinic bonds were not observed in the hydrotreated product and monoaromatic hydrocarbons were the predominant aromatic species. The properties of the jet fuel fractions from the hydrotreated products met most of the jet fuel specifications. The cetane indices indicated these fractions would be suitable for use as diesel fuels.

  3. Characterization and utilization of hydrotreated products produced from the Whiterocks (Utah) tar sand bitumen-derived liquid

    SciTech Connect

    Tsai, C.H.; Longstaff, D.C.; Deo, M.D.; Hanson, F.V.; Oblad, A.G.

    1991-12-31

    The bitumen-derived liquid produced in a 4-inch diameter fluidized-bed reactor from the mined and crushed ore from the Whiterocks tar sand deposit has been hydrotreated in a fixed-bed reactor. The purpose was to determine the extent of upgrading as a function of process operating variable. A sulfided nickel-molybendum on alumina hydrodenitrogenation catalyst was used in all experiments. Moderately severe operating conditions were employed; that is, high reaction temperature (617--680 K) high reactor pressure (11.0--17.1 MPa) and low liquid feed rate (0.18--0.77 HSV); to achieve the desired reduction in heteroatom content. Detailed chemical structures of the bitumen-derived liquid feedstock and the hydrotreated total liquid products were determined by high resolution gas chromatography - mass spectrometry analyses. The compounds identified in the native bitumen included isoprenoids; bicyclic, tricycle, and tetracyclic terpenoids; steranes; hopanes; and perhydro-{beta}-carotenes. In addition, normal and branched alkanes and alkenes and partially dehydrogenated hydroaromatics were identified in the bitumen-derived liquid. The dominant pyrolysis reactions were: (1) the dealkylation of long alkyl side chains to form {alpha} - and isoolefins; and (2) the cleavage of alkyl chains linking aromatic and hydroaromatic clusters. Olefinic bonds were not observed in the hydrotreated product and monoaromatic hydrocarbons were the predominant aromatic species. The properties of the jet fuel fractions from the hydrotreated products met most of the jet fuel specifications. The cetane indices indicated these fractions would be suitable for use as diesel fuels.

  4. Method and apparatus for producing tar sand deposits containing conductive layers having little or no vertical communication

    SciTech Connect

    Glandt, C.A.; Vinegar, H.J.; Gardner, J.W.

    1991-10-29

    This patent describes a process for recovering hydrocarbons from hydrocarbon-bearing deposits containing thin highly conductive layers adjacent to at least one hydrocarbon rich zone. It comprises selecting a hydrocarbon-bearing deposit which contains a thin highly conductive layer within the deposit; installing at least one pair of horizontal electrodes spanning the highly conductive layer and dividing the layer into electrically heated and non-electrically heated zones; providing at least one vertical injection well for hot fluid injection into the hydrocarbon rich zone; providing at least one vertical production well for production of hydrocarbons; electrically heating the thin highly conductive layer to form a preheated zone immediately adjacent to the thin highly conductive layer while simultaneously stimulating the wells with steam; injecting the hot fluid into the deposit adjacent to the thin highly conductive layer and within the thin preheated zone to displace the hydrocarbons to the production wells; and recovering hydrocarbons from the production wells. This patent also describes an apparatus for recovering hydrocarbons from tar sand deposits containing highly conductive layers. It comprises at least two pairs of horizontal electrodes which span the highly conductive layer and divide the highly conductive layer into at least two horizontally displaced electrically heated zones separated by non-electrically heated zones; at least one vertical injection well; and at least one vertical production well.

  5. Evaluating the Metal Tolerance Capacity of Microbial Communities Isolated from Alberta Oil Sands Process Water

    PubMed Central

    Frankel, Mathew L.; Demeter, Marc A.; Lemire, Joe A.; Turner, Raymond J.

    2016-01-01

    Anthropogenic activities have resulted in the intensified use of water resources. For example, open pit bitumen extraction by Canada’s oil sands operations uses an estimated volume of three barrels of water for every barrel of oil produced. The waste tailings–oil sands process water (OSPW)–are stored in holding ponds, and present an environmental concern as they are comprised of residual hydrocarbons and metals. Following the hypothesis that endogenous OSPW microbial communities have an enhanced tolerance to heavy metals, we tested the capacity of planktonic and biofilm populations from OSPW to withstand metal ion challenges, using Cupriavidus metallidurans, a known metal-resistant organism, for comparison. The toxicity of the metals toward biofilm and planktonic bacterial populations was determined by measuring the minimum biofilm inhibitory concentrations (MBICs) and planktonic minimum inhibitory concentrations (MICs) using the MBEC ™ assay. We observed that the OSPW community and C. metallidurans had similar tolerances to 22 different metals. While thiophillic elements (Te, Ag, Cd, Ni) were found to be most toxic, the OSPW consortia demonstrated higher tolerance to metals reported in tailings ponds (Al, Fe, Mo, Pb). Metal toxicity correlated with a number of physicochemical characteristics of the metals. Parameters reflecting metal-ligand affinities showed fewer and weaker correlations for the community compared to C. metallidurans, suggesting that the OSPW consortia may have developed tolerance mechanisms toward metals present in their environment. PMID:26849649

  6. Evaluating the Metal Tolerance Capacity of Microbial Communities Isolated from Alberta Oil Sands Process Water.

    PubMed

    Frankel, Mathew L; Demeter, Marc A; Lemire, Joe A; Turner, Raymond J

    2016-01-01

    Anthropogenic activities have resulted in the intensified use of water resources. For example, open pit bitumen extraction by Canada's oil sands operations uses an estimated volume of three barrels of water for every barrel of oil produced. The waste tailings-oil sands process water (OSPW)-are stored in holding ponds, and present an environmental concern as they are comprised of residual hydrocarbons and metals. Following the hypothesis that endogenous OSPW microbial communities have an enhanced tolerance to heavy metals, we tested the capacity of planktonic and biofilm populations from OSPW to withstand metal ion challenges, using Cupriavidus metallidurans, a known metal-resistant organism, for comparison. The toxicity of the metals toward biofilm and planktonic bacterial populations was determined by measuring the minimum biofilm inhibitory concentrations (MBICs) and planktonic minimum inhibitory concentrations (MICs) using the MBEC ™ assay. We observed that the OSPW community and C. metallidurans had similar tolerances to 22 different metals. While thiophillic elements (Te, Ag, Cd, Ni) were found to be most toxic, the OSPW consortia demonstrated higher tolerance to metals reported in tailings ponds (Al, Fe, Mo, Pb). Metal toxicity correlated with a number of physicochemical characteristics of the metals. Parameters reflecting metal-ligand affinities showed fewer and weaker correlations for the community compared to C. metallidurans, suggesting that the OSPW consortia may have developed tolerance mechanisms toward metals present in their environment. PMID:26849649

  7. Early Cretaceous to Paleocene North American Drainage Reorganization and Sediment Routing from Detrital Zircons: Significance to the Alberta Oil Sands and Gulf of Mexico Petroleum Provinces

    NASA Astrophysics Data System (ADS)

    Blum, M. D.

    2014-12-01

    Detrital zircons (DZs) represent a powerful tool for reconstructing continental paleodrainage. This paper uses new DZ data from Lower Cretaceous strata of the Alberta foreland basin, and Upper Cretaceous and Cenozoic strata of the Gulf of Mexico passive margin, to reconstruct paleodrainage and sediment routing, and illustrate significance to giant hydrocarbon systems. DZ populations from the Lower Cretaceous Mannville Group of Alberta and Saskatchewan infer a continental-scale river system that routed sediment from the eastern 2/3rds of North America to the Boreal Sea. Aptian McMurray Formation fluvial sands were derived from a drainage sourced in the Appalachians that was similar in scale to the modern Amazon. Albian fluvial sandstones of the Clearwater and Grand Rapids Formations were derived from the same Appalachian-sourced drainage area, which had expanded to include tributaries from the Cordilleran arc of the northwest US and southwest Canada. DZ populations from the Gulf of Mexico coastal plain complement this view, showing that only the southern US and Appalachian-Ouachita cordillera was integrated with the Gulf through the Late Cretaceous. However, by the Paleocene, drainage from the US Western Cordillera to the Appalachians had been routed to the Gulf of Mexico, establishing the template for sediment routing that persists today. The paleodrainage reorganization and changes in sediment routing described above played key roles in establishment of the Alberta oil sands and Gulf of Mexico as giant petroleum provinces. Early Cretaceous routing of a continental-scale fluvial system to the Alberta foreland provided large and contiguous fluvial point-bar sand bodies that became economically viable reservoirs, whereas mid- to late Cretaceous drainage reorganization routed greatly increased sediment loads to the Gulf of Mexico, which loaded the shelf, matured source rocks, and drove the gravitational and salt tectonics that helped establish the working hydrocarbon

  8. Peroxycarboxylic Nitric Anhydrides as Markers of Anthropogenic and Biogenic VOC Photo-oxidation in the Alberta Oil Sands

    NASA Astrophysics Data System (ADS)

    Osthoff, H. D.; Huo, J. A.; Tokarek, T. W.; Odame-Ankrah, C. A.; Saowapon, M. T.; Chen, X.

    2014-12-01

    The peroxycarboxylic nitric anhydrides (molecular formula RC(O)O2NO2) are well-known byproducts of the photo-oxidation chemistry between NOx and volatile organic compounds (VOCs) that produces ozone (O3) and photochemical smog. More than 43 different PAN species are known; their relative abundances are chemical markers of the types and quantities of the VOCs involved in the O3-formation process. For example, MPAN (R: CH2=C(CH3)-) is primarily derived from isoprene and thus a marker of biogenic VOC oxidation, whereas PPN (R: C2H5-) is a photo-oxidation byproduct of anthropogenic VOCs. In the summer of 2013 an intensive air quality measurement campaign was conducted to investigate the impacts of emissions from the Alberta oil sands mining operations on the chemical composition of ambient air. As part of this effort, several peroxycarboxylic nitric anhydrides, specifically PAN (R: CH3-), PPN, MPAN, APAN (R: CH2=CH-), and PiBN (R: iC3H7-), were quantified by gas chromatography with electron capture detection at the AMS13 ground site near Fort McKay, Alberta. Furthermore, total peroxyacyl nitrates (ΣPAN) were quantified by thermal dissociation cavity ring-down spectroscopy (TD-CRDS). PAN mixing ratios typically peaked in the mid-afternoon (maximum PAN mixing ratio of 0.85 ppbv), constituting up to 25% of total odd nitrogen (NOy), and were usually below detection limits at night. ΣPAN was generally greater than the amount calculated by summation of individually measured PANs (SPANi) suggesting the presence of PAN species not measured by GC. During times of active photo-oxidation chemistry, the PPN:PAN and MPAN:PAN ratios varied considerably between days, depending on air mass origin and VOC composition. A linear combination model (LCM) was used to assess regional O3 production from the oxidation of biogenic hydrocarbons (via MPAN) relative to that of anthropogenic hydrocarbons (via PPN). The relative contribution of anthropogenic VOCs to regional O3 production varied

  9. Vegetation community composition in wetlands created following oil sand mining in Alberta, Canada.

    PubMed

    Roy, Marie-Claude; Foote, Lee; Ciborowski, Jan J H

    2016-05-01

    Reclaiming wetlands following open pit mining for industrial oil sand extraction is challenging due to the physical and chemical conditions of the post-mined landscape. The aim of our study was to examine and compare the influence of oil sands process water (OSPW) and material (fine fluid tails or FFT) on the plant community composition of created wetlands. Compared to created-unamended and natural wetlands, the created wetlands amended with OSPW and/or FFT (created-tailings wetlands) had significantly higher water salinity, conductivity, dissolved oxygen concentration and lower oxidative-reductive potential. Water chemistry parameters of created-unamended did not differ significantly from those of natural wetlands. The sediment of created wetlands had significantly less moisture, total nitrogen, and organic content than the natural wetlands. The application of OSPW/FFT in created wetlands will likely lead to initial vegetation composition atypical of natural regional wetlands. For the objective of reclaiming vegetation composition to the status of natural regional wetlands, unamended wetlands were the best reclamation option, based on the physical and chemical parameters measured. Despite being the favored reclamation option, created-unamended wetlands' physical and chemical characteristics remain atypical of natural wetlands. Most significantly, the basin morphometry of created wetlands was significantly different from that of naturally-formed wetlands in the region, and this appears to partly explain difference in vegetation composition. We also demonstrate that species richness alone is not a useful measure in wetland monitoring. Instead, plant community composition is a better indicator of wetland conditions. PMID:26921562

  10. Desalination of oil sands process-affected water and basal depressurization water in Fort McMurray, Alberta, Canada: application of electrodialysis.

    PubMed

    Kim, Eun-Sik; Dong, Shimiao; Liu, Yang; Gamal El-Din, Mohamed

    2013-01-01

    The high content of inorganic species in water used to extract bitumen from the Alberta oil sands and in the groundwater below the oil sands is an increasing environmental concern. These water matrices require treatment before they can be reused or safely discharged. Desalination of the oil sands process-affected water (OSPW) and groundwater, or basal depressurization water (BDW), can be accomplished with deionization techniques such as electrodialysis (ED). In order to achieve the effective ED treatment, OSPW and BDW were pretreated with coagulation-flocculation-sedimentation to remove solid species and turbidity. We demonstrated that a conductivity range for industrial reuse of OSPW and BDW can be achieved with the ED treatment and showed the possibility of applying ED in the oil sands industry. A continuous ED system that reuses the diluate stream as a source for the concentrate stream was designed. The cost of a hypothetical ED water treatment plant in Fort McMurray, Alberta, was estimated to be C$10.71 per cubic meter of treated water. PMID:24355856

  11. Multicomponent seismic reservoir characterization of a steam-assisted gravity drainage (SAGD) heavy oil project, Athabasca oil sands, Alberta

    NASA Astrophysics Data System (ADS)

    Schiltz, Kelsey Kristine

    Steam-assisted gravity drainage (SAGD) is an in situ heavy oil recovery method involving the injection of steam in horizontal wells. Time-lapse seismic analysis over a SAGD project in the Athabasca oil sands deposit of Alberta reveals that the SAGD steam chamber has not developed uniformly. Core data confirm the presence of low permeability shale bodies within the reservoir. These shales can act as barriers and baffles to steam and limit production by prohibiting steam from accessing the full extent of the reservoir. Seismic data can be used to identify these shale breaks prior to siting new SAGD well pairs in order to optimize field development. To identify shale breaks in the study area, three types of seismic inversion and a probabilistic neural network prediction were performed. The predictive value of each result was evaluated by comparing the position of interpreted shales with the boundaries of the steam chamber determined through time-lapse analysis. The P-impedance result from post-stack inversion did not contain enough detail to be able to predict the vertical boundaries of the steam chamber but did show some predictive value in a spatial sense. P-impedance from pre-stack inversion exhibited some meaningful correlations with the steam chamber but was misleading in many crucial areas, particularly the lower reservoir. Density estimated through the application of a probabilistic neural network (PNN) trained using both PP and PS attributes identified shales most accurately. The interpreted shales from this result exhibit a strong relationship with the boundaries of the steam chamber, leading to the conclusion that the PNN method can be used to make predictions about steam chamber growth. In this study, reservoir characterization incorporating multicomponent seismic data demonstrated a high predictive value and could be useful in evaluating future well placement.

  12. Temporal variation in the deposition of polycyclic aromatic compounds in snow in the Athabasca Oil Sands area of Alberta.

    PubMed

    Manzano, Carlos A; Muir, Derek; Kirk, Jane; Teixeira, Camilla; Siu, May; Wang, Xiaowa; Charland, Jean-Pierre; Schindler, David; Kelly, Erin

    2016-09-01

    Atmospheric deposition of polycyclic aromatic compounds (PACs) via and onto snow, and their releasing during spring snowmelt has been a concern in the Athabasca Oil Sands Region of Alberta. This study was designed to evaluate the concentrations, loadings, and distribution of PACs in springtime snowpack and how they have changed since the first study in 2008. Snowpack samples were collected in late winters 2011-2014 at varying distances from the main developments. PAC concentration and deposition declined exponentially with distance, with pyrenes, chrysenes, and dibenzothiophenes dominating the distribution within the first 50 km. The distribution of PACs was different between sites located close to upgraders and others located close to mining facilities. Overall, PAC loadings were correlated with priority pollutant elements and water chemistry parameters, while wind direction and speed were not strong contributors to the variability observed. Total PAC mass deposition during winter months and within the first 50 km was initially estimated by integrating the exponential decay function fitted through the data using a limited number of sites from 2011 to 2014: 1236 kg (2011), 1800 kg (2012), 814 kg (2013), and 1367 (2014). Total loadings were estimated to have a twofold increase between 2008 and 2014, although the increase observed was not constant. Finally, kriging interpolation is presented as an alternative and more robust approach to estimate PAC mass deposition in the area. After a more intensive sampling campaign in 2014, the PAC mass deposition was estimated to be 1968 kg. PMID:27581009

  13. Twelve-year trends in ambient concentrations of volatile organic compounds in a community of the Alberta Oil Sands Region, Canada.

    PubMed

    Bari, Md Aynul; Kindzierski, Warren B; Spink, David

    2016-05-01

    Environmental exposure to volatile organic compounds (VOCs) in ambient air is one of a number of concerns that the First Nation Community of Fort McKay, Alberta has related to development of Canada's oil sands. An in-depth investigation of trends in ambient air VOC levels in Fort McKay was undertaken to better understand the role and possible significance of emissions from Alberta's oil sands development. A non-parametric trend detection method was used to investigate trends in emissions and ambient VOC concentrations over a 12-year (2001-2012) period. Relationships between ambient VOC concentrations and production indicators of oil sands operations around Fort McKay were also examined. A weak upward trend (significant at 90% confidence level) was found for ambient concentrations of total VOCs based on sixteen detected species with an annual increase of 0.64μg/m(3) (7.2%) per year (7.7μg/m(3) increase per decade). Indicators of production (i.e., annual bitumen production and mined oil sands quantities) were correlated with ambient total VOC concentrations. Only one of 29 VOC species evaluated (1-butene) showed a statistically significant upward trend (p=0.05). Observed geometric (arithmetic) mean and maximum ambient concentrations of selected VOCs of public health concern for most recent three years of the study period (2010-2012) were below chronic and acute health risk screening criteria of the U.S. Agency for Toxic Substances and Disease Registry and U.S. Environmental Protection Agency. Thirty-two VOCs are recommended for tracking in future air quality investigations in the community to better understand whether changes are occurring over time in relation to oil sands development activities and to inform policy makers about whether or not these changes warrant additional attention. PMID:26909813

  14. Oil shale, tar sand, coal research advanced exploratory process technology, jointly sponsored research. Quarterly technical progress report, October--December 1992

    SciTech Connect

    Speight, J.G.

    1992-12-31

    Accomplishments for the past quarter are presented for the following five tasks: oil shale; tar sand; coal; advanced exploratory process technology; and jointly sponsored research. Oil shale research covers oil shale process studies. Tar sand research is on process development of Recycle Oil Pyrolysis and Extraction (ROPE) Process. Coal research covers: coal combustion; integrated coal processing concepts; and solid waste management. Advanced exploratory process technology includes: advanced process concepts;advanced mitigation concepts; and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; CROW field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; PGI demonstration project; operation and evaluation of the CO{sub 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesaverde Group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced oil recovery techniques; surface process study for oil recovery using a thermal extraction process; NMR analysis of samples from the ocean drilling program; in situ treatment of manufactured gas plant contaminated soils demonstration program; and solid state NMR analysis of naturally and artificially matured kerogens.

  15. Oil shale, tar sand, coal research, advanced exploratory process technology, jointly sponsored research. Quarterly technical progress report, January--March 1993

    SciTech Connect

    Not Available

    1993-09-01

    Accomplishments for the past quarter are briefly described for the following areas of research: oil shale; tar sand; coal; advanced exploratory process technology; and jointly sponsored research. Oil shale and tar sand researches cover processing studies. Coal research includes: coal combustion; integrated coal processing concepts; and solid waste management. Advanced exploratory process technology covers: advanced process concepts; advanced mitigation concepts; and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; CROW{sup TM} field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO{sub 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid-state NMR analysis of Mesaverde Group, Greater Green River Basin tight gas sands; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced oil recovery techniques; surface process study for oil recovery using a thermal extraction process; oil field waste cleanup using tank bottom recovery process; remote chemical sensor development; in situ treatment of manufactured gas plant contaminated soils demonstration program; solid-state NMR analysis of naturally and artificially matured kerogens; and development of an effective method for the clean-up of natural gas.

  16. Oil shale, tar sand, coal research, advanced exploratory process technology jointly sponsored research. Quarterly technical progress report, April--June 1992

    SciTech Connect

    Not Available

    1992-12-01

    Accomplishments for the quarter are presented for the following areas of research: oil shale, tar sand, coal, advanced exploratory process technology, and jointly sponsored research. Oil shale research includes; oil shale process studies, environmental base studies for oil shale, and miscellaneous basic concept studies. Tar sand research covers process development. Coal research includes; underground coal gasification, coal combustion, integrated coal processing concepts, and solid waste management. Advanced exploratory process technology includes; advanced process concepts, advanced mitigation concepts, and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO{sub 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesa Verde Group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced recovery techniques; and menu driven access to the WDEQ Hydrologic Data Management Systems.

  17. Use of pre-industrial floodplain lake sediments to establish baseline river metal concentrations downstream of Alberta oil sands: a new approach for detecting pollution of rivers

    NASA Astrophysics Data System (ADS)

    Wiklund, Johan A.; Hall, Roland I.; Wolfe, Brent B.; Edwards, Thomas WD; Farwell, Andrea J.; Dixon, D. George

    2014-12-01

    In the Alberta oil sands region, insufficient knowledge of pre-disturbance reference conditions has undermined the ability of the Regional Aquatics Monitoring Program (RAMP) to detect pollution of the Athabasca River, because sampling began three decades after the industry started and the river naturally erodes oil-bearing strata. Here, we apply a novel approach to characterize pre-industrial reference metal concentrations in river sediment downstream of Alberta oil sands development by analyzing metal concentrations in sediments deposited in floodplain lakes of the Athabasca Delta during 1700-1916, when they were strongly influenced by Athabasca River floodwaters. We compared results to metal concentrations in surficial bottom sediments sampled by RAMP (2010-2013) at downstream sites of the Athabasca River and distributaries. When normalized to lithium content, concentrations of vanadium (a metal of concern in the oil sands region) and other priority pollutants (Be, Cd, Cr, Cu, Pb, Ni, Zn) in nearly all of the RAMP river sediment samples lie below the upper 95% prediction interval linearly extrapolated from the river-derived lake sediments. Assuming the RAMP protocols obtained recently deposited sediment, this indicates that the metal concentrations in downstream Athabasca River sediment have not increased above pre-disturbance levels. Reference conditions derived from the lake sediment data were used to develop profiles of metal residual concentrations versus time for the RAMP river sediment data, which provides an excellent tool for decision-makers to identify and quantify levels of metal pollution for any given sample, and to monitor for future trends. We recommend that the approach be applied to resurrect the utility of RAMP data at other river sampling locations closer to the development, and for ongoing risk assessment. The approach is also readily transferable to other rivers where insufficient pre-disturbance reference data impairs an ability to determine

  18. A multi-isotope approach for estimating industrial contributions to atmospheric nitrogen deposition in the Athabasca oil sands region in Alberta, Canada.

    PubMed

    Proemse, Bernadette C; Mayer, Bernhard; Fenn, Mark E; Ross, Christopher S

    2013-11-01

    Industrial nitrogen (N) emissions in the Athabasca oil sands region (AOSR), Alberta, Canada, affect nitrate (NO3) and ammonium (NH4) deposition rates in close vicinity of industrial emitters. NO3-N and NH4-N open field and throughfall deposition rates were determined at various sites between 3 km and 113 km distance to the main oil sand operations between May 2008 and May 2009. NO3 and NH4 were analyzed for δ(15)N-NO3, δ(18)O-NO3, Δ(17)O-NO3 and δ(15)N-NH4. Marked differences in the δ(18)O and Δ(17)O values between industrial emissions and background deposition allowed for the estimation of minimum industrial contributions to atmospheric NO3 deposition. δ(15)N-NH4 values also allowed for estimates of industrial contributions to atmospheric NH4 deposition. Results revealed that particularly sites within ~30 km radius from the main oil sands developments are significantly affected by industrial contributions to atmospheric NO3 and NH4 deposition. PMID:23896680

  19. Bog Plant Tissue Chemistry and N and S Accumulation in Peat are Influenced by Elevated N and S Deposition from Alberta Oil Sands Development

    NASA Astrophysics Data System (ADS)

    Wieder, R.; Vile, M. A.; Quinn, J.; Albright, C. M.; Scott, K. D.; Vitt, D. H.

    2013-12-01

    Development of the oil sands resource in northern Alberta, Canada has led to elevated atmospheric N and S deposition, the N coming mainly from the exhaust of diesel fueled-trucks that haul the raw oil sands from the mine sites and the S coming mainly from refining. Against a background deposition of < 1 kg/ha/yr for both N and S, at sites within 15 km of the oil sands mining region we have measured current N and S deposition to be as high as 2 and 27 kg/ha/yr. With a goal of developing monitoring tools to assess the spatial extent of elevated N and S deposition in the region, we collected leaves, needles, or whole plants of 12 bog species (lichens: Cladina mitis and Evernia mesomorpha; Sphagnum mosses: S. capillifolium and S. fuscum; a tree: Picea mariana; ericaceous shrubs: Ledum groenlandicum, Oxycoccos microcarpus and Vaccinium vitis-idaea; deciduous forbs: Rubus chamaemorus and Smilacina trifolia) from 5 bogs ranging from 11 to over 250 km from the oil sands mining area. Samples were collected on 23 dates between May and October of 2009-2012 and were analyzed for C, N, and S concentrations. Six species (C. mitis, E. mesomorpha, S. fuscum, O. microcarpus, V. vitis-idaea, and R. chamaemorus) exhibited statistically significant increases in C:N ratio with increasing distance from the oil sands mining area. Five species (C. mitis, E. mesomorpha, S. fuscum, S. capillifolium, O. microcarpus) exhibited statistically significant increases in C:S ratio with increasing distance from the oil sands mining area. For three species (S. fuscum, E. mesomorpha, O. microcarpus), N concentrations gradually and significantly increased (C:N ratios decreased) over the four years of the study, with the rate of increase as high as 1 mg/g/yr at sites in close proximity to the oil sands mining area. In contrast, S concentrations in plant tissues generally did not increase over the four years, possibly because of increasing efforts to control S emissions from stacks. Using 210Pb

  20. Effects of canopy-deposition interaction on H+ supply to soils in Pinus banksiana and Populus tremuloides ecosystems in the Athabasca oil sands region in Alberta, Canada.

    PubMed

    Jung, Kangho; Chang, Scott X; Arshad, M A Charlie

    2011-05-01

    Soil acidification has been of concern in the oil sands region in Alberta due to increased acid deposition. Using the canopy budget model, and accounting for H(+) canopy leaching by organic acids, we determined sources and sinks of H+ in throughfall in jack pine (Pinus banksiana) and trembling aspen (Populus tremuloides) stands in two watersheds from 2006 to 2009. In pine stands, H+ deposition was greater in throughfall than in bulk precipitation while the opposite was true in aspen stands. The annual H+ interception deposition was 148.8-193.8 and 49.7-70.0 molcha(-1) in pine and aspen stands, respectively; while the annual H+ canopy leaching was 127.1-128.7 and 0.0-6.0 molcha(-1), respectively. The greater H+ supply in pine stands was caused by greater interception deposition of SO4(2-) and organic acids released from the pine canopy. Such findings have significant implications for establishing critical loads for various ecosystems in the oil sands region. PMID:21310518

  1. Oil shale, tar sand, coal research, advanced exploratory process technology, jointly sponsored research. Quarterly technical progress report, April--June 1993

    SciTech Connect

    Not Available

    1993-09-01

    Progress made in five areas of research is described briefly. The subtask in oil shale research is on oil shale process studies. For tar sand the subtask reported is on process development. Coal research includes the following subtasks: Coal combustion; integrated coal processing concepts; and solid waste management. Advanced exploratory process technology includes the following: Advanced process concepts; advanced mitigation concepts; oil and gas technology. Jointly sponsored research includes: Organic and inorganic hazardous waste stabilization; CROW{sup TM} field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO{sup 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid-state NMR analysis of Mesaverde Group, Greater Green River Basin, tight gas sands; characterization of petroleum residua; shallow oil production using horizontal wells with enhanced oil recovery techniques; surface process study for oil recovery using a thermal extraction process;NMR analysis of samples from the ocean drilling program; oil field waste cleanup using tank bottom recovery process; remote chemical sensor development; in situ treatment of manufactured gas plant contaminated soils demonstration program; solid-state NMR analysis of Mowry formation shale from different sedimentary basins; solid-state NMR analysis of naturally and artificially matured kerogens; and development of effective method for the clean-up of natural gas.

  2. Oil shale, tar sand, coal research, advanced exploratory process technology, jointly sponsored research. Quarterly technical progress report, July--September 1992

    SciTech Connect

    Not Available

    1992-12-31

    Progress made in five research programs is described. The subtasks in oil shale study include oil shale process studies and unconventional applications and markets for western oil shale.The tar sand study is on recycle oil pyrolysis and extraction (ROPE) process. Four tasks are described in coal research: underground coal gasification; coal combustion; integrated coal processing concepts; and sold waste management. Advanced exploratory process technology includes: advanced process concepts; advanced mitigation concepts; and oil and gas technology. Jointly sponsored research covers: organic and inorganic hazardous waste stabilization; CROW field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; PGI demonstration project; operation and evaluation of the CO{sub 2} HUFF-N-PUFF process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesaverde group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; shallow oil production using horizontal wells with enhanced oil recovery techniques; NMR analysis of sample from the ocean drilling program; and menu driven access to the WDEQ hydrologic data management system.

  3. Characterization of nickel and vanadium compounds in tar sand bitumen by petroporphyrin quantitation and size exclusion chromatography coupled with element specific detection

    SciTech Connect

    Reynolds, J.G.; Jones, E.L.; Bennett, J.A.; Biggs, W.R.

    1988-02-01

    Previously, we have examined the Ni and V in heavy crude oils, residua, and processed products by several metal speciation techniques to ascertain molecular structure and processing behavior. Two classes of metal compounds were found/--/metallopetroporphyrins and metallo-nonporphyrins/--/each having unique reactivity during processing. In efforts to better understand the binding of metals in the oil medium, we have now examined Ni and V in tar sand bitumens. The bitumen was solvent extracted from the sand matrix and was separated by column chromatography to quantitate petroporphyrin content. The petroporphyrin contents ranged from virtually none to over 36% of the total metals. Asphalt Ridge (Utah) has primarily Ni petroporphyrins; Big Clifty (Kentucky) and Athabasca (Canada) have primarily V petroporphyrins; Arroyo Grande and McKittrick (California) have roughly equal amounts of both types; and Sunnyside (Utah) has virtually none of either. Size characteristic profiles (SEC-HPLC-ICP) were generated for the extracted bitumens. The profiles are generally bimodal in shape and resemble several different specific heavy crude oils and residua. For examples, Arroyo Grande and McKittrick appear to be similar to Kern River (California) 650/degree/F+ residuum, while Athabasca resembles Morichal (Venezuela) 650/degree/F+ residuum. These results will be discussed in terms of generalized profile and petroporphyrin behavior. 23 refs., 3 figs., 3 tabs.

  4. Detoxification, endocrine, and immune responses of tree swallow nestlings naturally exposed to air contaminants from the Alberta oil sands.

    PubMed

    Cruz-Martinez, Luis; Fernie, Kim J; Soos, Catherine; Harner, Tom; Getachew, Fitsum; Smits, Judit E G

    2015-01-01

    Changes in environmental and wildlife health from contaminants in tailings water on the Canadian oil sands have been well-studied; however, effects of air contaminants on wildlife health have not. A field study was conducted to assess biological costs of natural exposure to oil sands-related air emissions on birds. Nest boxes for tree swallows (Tachycineta bicolor) were erected at two sites; within 5 km of active oil sands mining and extraction, and ≥ 60 km south, at one reference site. Passive air monitors were deployed at the nest boxes to measure nitrogen dioxide, sulfur dioxide, ozone, volatile organic compounds, and polycyclic aromatic hydrocarbons (PAHs). Nestlings were examined at day 9 post hatching to assess T cell function and morphometry. At day 14 post hatching, a subset of nestlings was euthanized to measure detoxification enzymes, endocrine changes, and histological alterations of immune organs. Except for ozone, all air contaminants were higher at the two oil sands sites than the reference site (up to 5-fold). Adult birds had similar reproductive performance among sites (p>0.05). Nestlings from industrial sites showed higher hepatic ethoxyresorufin O-dealkylase (EROD) induction (p<0.0001) with lower relative hepatic mass (p=0.0001), a smaller T cell response to the phytohemagglutinin skin test (p=0.007), and smaller bursae of Fabricius (p<0.02); a low sample size for one site indicating lower body condition scores (p=0.01) at day 14 warrants cautious interpretation. There were no differences among nestlings for feather corticosterone (p>0.6), and no histological alterations in the spleen or bursa of Fabricius (p>0.05). This is the first report examining toxicological responses in wild birds exposed to air contaminants from industrial activity in the oil sands. It is also the first time that small, individual air contaminant monitors have been used to determine local contaminant levels in ambient air around nest boxes of wild birds. PMID:25240100

  5. Research investigations in oil shale, tar sand, coal research, advanced exploratory process technology, and advanced fuels research: Volume 1 -- Base program. Final report, October 1986--September 1993

    SciTech Connect

    Smith, V.E.

    1994-05-01

    Numerous studies have been conducted in five principal areas: oil shale, tar sand, underground coal gasification, advanced process technology, and advanced fuels research. In subsequent years, underground coal gasification was broadened to be coal research, under which several research activities were conducted that related to coal processing. The most significant change occurred in 1989 when the agreement was redefined as a Base Program and a Jointly Sponsored Research Program (JSRP). Investigations were conducted under the Base Program to determine the physical and chemical properties of materials suitable for conversion to liquid and gaseous fuels, to test and evaluate processes and innovative concepts for such conversions, to monitor and determine environmental impacts related to development of commercial-sized operations, and to evaluate methods for mitigation of potential environmental impacts. This report is divided into two volumes: Volume 1 consists of 28 summaries that describe the principal research efforts conducted under the Base Program in five topic areas. Volume 2 describes tasks performed within the JSRP. Research conducted under this agreement has resulted in technology transfer of a variety of energy-related research information. A listing of related publications and presentations is given at the end of each research topic summary. More specific and detailed information is provided in the topical reports referenced in the related publications listings.

  6. Oil sands development and its impact on atmospheric wet deposition of air pollutants to the Athabasca Oil Sands Region, Alberta, Canada.

    PubMed

    Lynam, Mary M; Dvonch, J Timothy; Barres, James A; Morishita, Masako; Legge, Allan; Percy, Kevin

    2015-11-01

    Characterization of air pollutant deposition resulting from Athabasca oil sands development is necessary to assess risk to humans and the environment. To investigate this we collected event-based wet deposition during a pilot study in 2010-2012 at the AMS 6 site 30 km from the nearest upgrading facility in Fort McMurray, AB, Canada. Sulfate, nitrate and ammonium deposition was (kg/ha) 1.96, 1.60 and 1.03, respectively. Trace element pollutant deposition ranged from 2 × 10(-5) - 0.79 and exhibited the trend Hg < Se < As < Cd < Pb < Cu < Zn < S. Crustal element deposition ranged from 1.4 × 10(-4) - 0.46 and had the trend: La < Ce < Sr < Mn < Al < Fe < Mg. S, Se and Hg demonstrated highest median enrichment factors (130-2020) suggesting emissions from oil sands development, urban activities and forest fires were deposited. High deposition of the elements Sr, Mn, Fe and Mg which are tracers for soil and crustal dust implies land-clearing, mining and hauling emissions greatly impacted surrounding human settlements and ecosystems. PMID:26277649

  7. Vertical Profiles of SO2 and NO2 in the Alberta Oil Sands: MAX-DOAS Measurements and Comparison to in-situ Instrumentation

    NASA Astrophysics Data System (ADS)

    Davis, Zoe; Lobo, Akshay; McLaren, Robert

    2015-04-01

    Understanding the levels of industrially emitted gas pollutants in the Alberta oil sands is essential to making quality environmental management decisions but is currently limited due to scarcity of top-down quantification studies. Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) measurements of nitrogen dioxide (NO2) and sulfur dioxide (SO2) , important tropospheric trace gas pollutants, contributes to improved knowledge of these pollutants' levels, vertical distributions and chemical transformations. A mini-MAX-DOAS instrument measured spectra at multiple viewing elevation angles in order to retrieve NO2 and SO2 differential slant column densities (dSCDs) at an Environment Canada research site north of Fort McMurray, Alberta in the fall of 2013. For the first time in the oil sands, tropospheric vertical profiles of NO2 and SO2 were retrieved by applying the optimal estimation technique to the MAX-DOAS measurements. The DOAS fit retrievals of SO2 dSCDs were validated by comparison with retrievals obtained with a quartz calibration cell with known SO2 SCD placed in front of the MAX-DOAS telescope at multiple elevation angles on a clean day. Retrieved SO2 dSCDs varied significantly from the true value depending on the chosen wavelength fitting interval. At the lowest wavelength intervals, interference by stray light and O3 differential structures significantly reduced dSCDs and caused an elevation angle dependence. These results indicate that MAX-DOAS dSCD retrieval settings, particularly for weak absorbers with differential absorption structures in low-intensity spectral regions, must be chosen carefully in order to achieve the most accurate results. Tropospheric vertical column densities (VCDs) and vertical profile retrievals of NO2, SO2 and aerosol extinction during significant pollution events will be illustrated. Trace gas vertical profiles exhibited significant variability between days and at different times of day and were often spatially

  8. Critical loads and H+ budgets of forest soils affected by air pollution from oil sands mining in Alberta, Canada

    NASA Astrophysics Data System (ADS)

    Jung, Kangho; Chang, Scott X.; Ok, Yong Sik; Arshad, M. A.

    2013-04-01

    We investigated the critical load (CL) and exceedance (EX) of sulfur (S) deposition, temporal changes in soil chemistry, and H+ budget of soils in plots dominated by Pinus banksiana (jack pine) or Populus tremuloides (trembling aspen, aspen) in two acid-sensitive watersheds to assess the risk of soil acidification by S emissions from oil sands mining in the Athabasca oil sands region (AOSR), Canada. The CLs and EXs were determined by two methods: one was based on bulk deposition and the other based on total deposition (as a sum of bulk deposition and interception deposition). The CLs ranged from 223 to 711 molc ha-1 yr-1 based on bulk deposition. Those values were similar to that obtained based on total deposition. However, EXs based on bulk deposition were significantly lower (p < 0.001) than those based on total deposition due to the relative increase of SO concentrations in interception deposition, indicating that EXs based on bulk deposition only could underestimate the risk of soil acidification in the AOSR. The S deposition did not exceed CLs in the long-term for both methods. The pH in the forest floor increased and available SO (as the sum of soluble and adsorbed SO) in the forest floor and surface mineral soils increased in both jack pine and aspen stands between 2005 and 2010. The H+ budget ranged from -289 to -130 molc ha-1 yr-1 in jack pine stands and from -510 to -371 molc ha-1 yr-1 in aspen stands. Our results suggest that 1) soils in the studied forest stands have recovered from acidification based on the increasing soil pH over time and the negative H+ budget, and 2) the risk of soil acidification should be assessed by CL and EX calculated based on total deposition.

  9. Boron in tree-ring as an indicator of forest disturbances in the Lower Athabasca Oil Sands region, Northeastern Alberta, Canada

    NASA Astrophysics Data System (ADS)

    Bégin, Christian; Savard, Martine M.; Marion, Joëlle; Thiffault, Évelyne; Pinno, Brad

    2016-04-01

    Industrial activities related to oil sands (OS) extraction in northeastern Alberta (Canada) have generated, since 1967, important quantities of NOx and SO2 emissions that can lead to several negative effects on forest ecosystems including the potential for soil acidification. In addition, mining processes, tailing pond treatments and heavy transport (haul roads) in mining areas are considered important sources of air contaminants that have the potential to impair forest health by affecting the nutrient balance and physiology of trees. In this study, we analysed micronutrients (B, Fe, Zn, Na, Cu) and macronutrients (Ca, Mg, Mn, K) in the tree-ring series of jack pine (Pinus banksiana) and spruce (Picea glauca and Picea mariana) trees growing at different distances from the heart of mining operations (two sites for each species). Based on tree-ring records, our aims were to provide a historical perspective on the nutritional status of forest ecosystems and to identify temporal changes in tree-ring chemistry that can be attributed to OS activities. One of the key findings of this research is the direct and immediate response of boron (B) in woody tissues of all studied species to mining operations. During the pre-mining period (prior to 1967) [B] variations in tree-rings of the three species covary with other elements such as Na and Fe and are likely controlled by environmental factors, namely climatic conditions. After 1970, [B] increases and strongly departs from trends of other elements. In jack pine trees (54 km NNE of the centre of industrial operations) the increasing trend is abrupt with mean [B] increasing from 11.7 mg/kg during the pre-industrial period to 14.3 mg/kg during mining period. In spruce trees at the proximal site (14 km NE), [B] increases gradually and nicely reproduces the historical pattern of industrial emissions with mean pre-mining [B] of 29.5 mg/kg increasing to 92.1 mg/kg during the mining period. At the four spruce sites, the increasing

  10. Atmospheric deposition of nitrogen, sulfur and base cations in jack pine stands in the Athabasca Oil Sands Region, Alberta, Canada.

    PubMed

    Fenn, M E; Bytnerowicz, A; Schilling, S L; Ross, C S

    2015-01-01

    Atmospheric deposition in the Athabasca Oil Sands Region decreased exponentially with distance from the industrial center. Throughfall deposition (kg ha(-1) yr(-1)) of NH(4)-N (.8-14.7) was double that of NO(3)-N (.3-6.7), while SO(4)-S ranged from 2.5 to 23.7. Gaseous pollutants (NO(2), HNO(3), NH(3), SO(2)) are important drivers of atmospheric deposition but weak correlations between gaseous pollutants and deposition suggest that particulate deposition is also important. The deposition (eq ha(-1)) of base cations (Ca + Mg + Na) across the sampling network was highly similar to N + S deposition, suggesting that acidic deposition is neutralized by base cation deposition and that eutrophication impacts from excess N may be of greater concern than acidification. Emissions from a large forest fire in summer 2011 were most prominently reflected in increased concentrations of HNO(3) and throughfall deposition of SO4-S at some sites. Deposition of NO(3)-N also increased as did NH(4)-N deposition to a lesser degree. PMID:25236261

  11. Development and testing of an index of biotic integrity based on submersed and floating vegetation and its application to assess reclamation wetlands in Alberta's oil sands area, Canada.

    PubMed

    Rooney, Rebecca C; Bayley, Suzanne E

    2012-01-01

    We developed and tested a plant-based index of biological integrity (IBI) and used it to evaluate the existing reclamation wetlands in Alberta's oil sands mining region. Reclamation plans call for >15,000 ha of wetlands to be constructed, but currently, only about 25 wetlands are of suitable age for evaluation. Reclamation wetlands are typically of the shallow open water type and range from fresh to sub-saline. Tailings-contaminated wetlands in particular may have problems with hydrocarbon- and salt-related toxicity. From 60 initial candidate metrics in the submersed aquatic and floating vegetation communities, we selected five to quantify biological integrity. The IBI included two diversity-based metrics: the species richness of floating vegetation and the percent of total richness contributed by Potamogeton spp. It also included three relative abundance-based metrics: that of Ceratophyllum demersum, of floating leafed species and of alkali-tolerant species. We evaluated the contribution of nonlinear metrics to IBI performance but concluded that the correlation between IBI scores and wetland condition was not improved. The method used to score metrics had an influence on the IBI sensitivity. We conclude that continuous scoring relative to the distribution of values found in reference sites was superior. This scoring approach provided good sensitivity and resolution and was grounded in reference condition theory. Based on these IBI scores, both tailings-contaminated and tailings-free reclamation wetlands have significantly lower average biological integrity than reference wetlands (ANOVA: F(2,59) = 34.7, p = 0.000000000107). PMID:21484300

  12. Devonian salt dissolution-collapse breccias flooring the Cretaceous Athabasca oil sands deposit and development of lower McMurray Formation sinkholes, northern Alberta Basin, Western Canada

    NASA Astrophysics Data System (ADS)

    Broughton, Paul L.

    2013-01-01

    The sub-Cretaceous paleotopography underlying giant Lower Cretaceous Athabasca oil sands, northern Alberta, has an orthogonal lattice pattern of troughs up to 50 km long and 100 m deep between pairs of cross-cutting lineaments. These structures are interpreted to have been inherited from a similar pattern of dissolution collapse-subsidence troughs in the underlying Middle Devonian salt beds. Removal of more than 100 m of halite salt fragmented the overlying Upper Devonian strata into fault blocks and collapse breccias that subsided into the underlying dissolution troughs. The unusually low 1:2 to 1:3 thickness ratios of halite salts to the overlying strata resulted in the Upper Devonian strata collapse-subsidence into underlying salt dissolution troughs being more cataclysmic during the first phase of salt removal. The second phase of slower but complete salt removal between the earlier troughs resulted in a more gradual subsidence of the overlying strata. This obliterated the earlier pattern of giant cross-cutting dissolution troughs bounded by major lineaments. The collapse breccia fabrics underlying the earlier troughs differ from those from areas between the troughs. Collapse breccias underlying the large troughs often have crushed fabrics distributed in zones that rapidly pinched out between fault blocks. Breccias between troughs developed as giant mosaics of detached carbonate blocks that formed breccia pipe complexes. Multiple sinkholes up to 100 m deep aligned along multi-km linear valley trends that dissected the sub-Cretaceous paleotopography. These sinkhole trends formed orthogonal patterns inherited from underlying lattice of NW-SE and NE-SW salt structured lineaments. These cross-cutting sinkhole trends have a smaller 5 km scale reticulate pattern similar to the giant 50 km scale pattern of collapse-subsidence troughs. Other sinkholes developed as lower McMurray strata sagged when underlying Devonian fault blocks and breccia pipes differentially

  13. Modeling and mapping the effects of heat and pressure outside a SAGD steam chamber using time-lapse multicomponent seismic data, Athabasca oil sands, Alberta

    NASA Astrophysics Data System (ADS)

    Zeigler, Loren Michelle

    The field of study is a bitumen producing reservoir within the McMurray Formation. The deposit is a part of the Athabasca oil sands trend in Northeastern Alberta, Canada. This field contains 16 well pads that are, combined, producing more than 41,000 BOPD. Bitumen reservoirs are unique as a result of their high viscosity, low API gravity oil. This oil in this field has been produced by means of a method called Steam Assisted Gravity Drainage (SAGD), since 2007. In this method, two vertically stacked, horizontal wells are drilled. The upper well injects high temperature, high pressure steam and as the viscosity of the bitumen decreases it will begin to flow, via gravity, down to the lower producing well. Reservoir monitoring in this field is very important for multiple reasons, including the shallow depth and the large velocity changes that result from SAGD production. In order to map these changes, time-lapse multicomponent data were incorporated with rock physics modeling in order to map and interpret changes in Vp/Vs with production. When fluid substitution results and pressure estimations are combined, the resulting velocities are consistent with the core sample modeling done by Kato et al. (2008). These results were then compared with the seismic data in order to identify areas affected by steam, heat, and pressure within the reservoir through time-lapse Vp/Vs. PP time-lapse results show the location of the steam chamber within the reservoir, however these data do not give any information about the effects of pressure or heat. Converted-wave (PS) data can be used to image pressure and viscosity changes in the reservoir. When these data are combined into a Vp/Vs volume, the effects of steam, heat and pressure can be identified. Vp/Vs areas of little to no difference indicate steamed zones while the surrounding areas with large differences indicate heated and pressured zones.

  14. Modelling Effects of Cover Material and Cover Depth on Hydrological Regime and Salt Redistribution in Reclaimed Oil Sand Landscapes in Northern Alberta

    NASA Astrophysics Data System (ADS)

    Welegedara, N.; Grant, R. F.; Quideau, S.; Lloret, E.

    2014-12-01

    Large-Scale surface mining is continuing in the Athabasca oil sands region in northern Alberta, Canada, causing significant ecosystem disturbances and changes in hydrology. Reclamation efforts in this region require understanding processes that control water, nutrient and salt fluxes through reclaimed landscapes which is critical to restoring their productivity. These processes were tested in a comprehensive mathematical model, ecosys, which was used to determine the effect of different cover thicknesses on water balance, water buffering capacity, salinity and the productivity in the South Bison Hills reclamation site of Syncrude Canada (SCL). This site was constructed in 1999 by capping peat mineral mix and secondary (glacial till) soil over saline sodic overburden. The site was constructed with three different soil cover thicknesses: 35 cm (thin), 50 cm (intermediate) and 100 cm (thick) along a 20% north facing slope. Model outputs were validated with field measured volumetric water content, runoff, snow data, electrical conductivity (EC) and plant productivity data recorded from 1999 to 2013. Model and field results show differences in horizontal and vertical water transport among the three reclaimed prototype covers. Lower water retention capacity in the 35 cm cover compared to the 50 cm and 100 cm covers caused greater soil moisture variation so that permanent wilting point was reached during dry years, decreasing plant growth due to water stress. In addition, the modeled and field-measured EC values indicated some upward salt movement from overburden to cover material over the time. This movement caused higher EC values (6 - 8 dS m-1) to be reached in the shallow rooting zone of the 35 cm and 50 cm covers than of the 100 cm cover several years after the covers were established. The determination of cost effective but ecologically sustainable cover depth is a challenge and will be a focus in future simulations.

  15. Distribution of Total Dissolved Solids in McMurray Formation Water in the Athabasca Oil Sands Region, Alberta, Canada: Implications for Oil Sands Mining and In Situ Resource Development

    NASA Astrophysics Data System (ADS)

    Cowie, B.; Mayer, B.

    2013-12-01

    Saline water management is a significant environmental challenge for mining and in-situ resource development in the Athabasca oil sands region (AOSR), Alberta, Canada. In the AOSR, the Cretaceous aged McMurray formation that bears the majority of the oil sands resources is underlain by saline Devonian formations containing saline water. Vertical connectivity between Devonian and Cretaceous aquifer systems has been uncovered by mining operations in the AOSR over the past several years, inducing occasional and local saline water flow into mining areas. The observed upward flow of groundwater from Devonian to Cretaceous systems necessitates detailed characterization of the spatial extent of high salinity formation waters to improve water management decisions in the AOSR. This study used published data from recent government reports and Environmental Impact Assessments to map total dissolved solids (TDS) of 355 McMurray formation water samples across the Athabasca oil sands region (54 to 58° N and 110 to 114° W). McMurray formation waters varied from non-saline (TDS < 4 000 mg/L) to brine (TDS > 100 000 mg/L) with a locally high salinity formation waters trending parallel to the dissolution edge of the Devonian-aged Prairie evaporite formation across the AOSR. The simplest hydrogeological explanation for the observed formation water salinity data is that Devonian aquifers are locally connected to the McMurray formation via conduits in the sub-Cretaceous karst system in the region overlying the partial dissolution edge of the Prairie evaporite formation. The driving force for upward formation water flow was provided by the Pleistocene glaciation events that reversed the regional flow system in the Devonian strata over the past 2 Ma. This study demonstrates that a detailed approach to hydrogeological assessment is required to elucidate total dissolved solids concentrations in McMurray formation waters at an individual lease-area scale, and to manage potential impacts

  16. Characterization of trace gases measured over Alberta oil sands mining operations: 76 speciated C2-C10 volatile organic compounds (VOCs), CO2, CH4, CO, NO, NO2, NOy, O3 and SO2

    NASA Astrophysics Data System (ADS)

    Simpson, I. J.; Blake, N. J.; Barletta, B.; Diskin, G. S.; Fuelberg, H. E.; Gorham, K.; Huey, L. G.; Meinardi, S.; Rowland, F. S.; Vay, S. A.; Weinheimer, A. J.; Yang, M.; Blake, D. R.

    2010-08-01

    Oil sands comprise 30% of the world's oil reserves and the crude oil reserves in Canada's oil sands deposits are second only to Saudi Arabia. The extraction and processing of oil sands is much more challenging than for light sweet crude oils because of the high viscosity of the bitumen contained within the oil sands and because the bitumen is mixed with sand and contains chemical impurities such as sulphur. Despite these challenges, the importance of oil sands is increasing in the energy market. To our best knowledge this is the first peer-reviewed study to characterize volatile organic compounds (VOCs) emitted from Alberta's oil sands mining sites. We present high-precision gas chromatography measurements of 76 speciated C2-C10 VOCs (alkanes, alkenes, alkynes, cycloalkanes, aromatics, monoterpenes, oxygenates, halocarbons, and sulphur compounds) in 17 boundary layer air samples collected over surface mining operations in northeast Alberta on 10 July 2008, using the NASA DC-8 airborne laboratory as a research platform. In addition to the VOCs, we present simultaneous measurements of CO2, CH4, CO, NO, NO2, NOy, O3 and SO2, which were measured in situ aboard the DC-8. Methane, CO, CO2, NO, NO2, NOy, SO2 and 53 VOCs (e.g., halocarbons, sulphur species, NMHCs) showed clear statistical enhancements (up to 1.1-397×) over the oil sands compared to local background values and, with the exception of CO, were higher over the oil sands than at any other time during the flight. Twenty halocarbons (e.g., CFCs, HFCs, halons, brominated species) either were not enhanced or were minimally enhanced (< 10%) over the oil sands. Ozone levels remained low because of titration by NO, and three VOCs (propyne, furan, MTBE) remained below their 3 pptv detection limit throughout the flight. Based on their mutual correlations, the compounds emitted by the oil sands industry fell into two groups: (1) evaporative emissions from the oil sands and its products and/or from the diluent used to

  17. Dust is the dominant source of "heavy metals" to peat moss (Sphagnum fuscum) in the bogs of the Athabasca Bituminous Sands region of northern Alberta.

    PubMed

    Shotyk, William; Bicalho, Beatriz; Cuss, Chad W; Duke, M John M; Noernberg, Tommy; Pelletier, Rick; Steinnes, Eiliv; Zaccone, Claudio

    2016-01-01

    Sphagnum fuscum was collected from twenty-five ombrotrophic (rain-fed) peat bogs surrounding open pit mines and upgrading facilities of Athabasca Bituminous Sands (ABS) in northern Alberta (AB) in order to assess the extent of atmospheric contamination by trace elements. As a control, this moss species was also collected at a bog near Utikuma (UTK) in an undeveloped part of AB and 264km SW of the ABS region. For comparison, this moss was also collected in central AB, in the vicinity of the City of Edmonton which is approximately 500km to the south of the ABS region, from the Wagner Wetland which is 22km W of the City, from Seba Beach (ca. 90km W) and from Elk Island National Park (ca. 45km E). All of the moss samples were digested and trace elements concentrations determined using ICP-SMS at a commercial laboratory, with selected samples also analyzed using instrumental neutron activation analysis at the University of Alberta. The mosses from the ABS region yielded lower concentrations of Ag, As, Bi, Cd, Cu, Pb, Sb, Tl, and Zn compared to the moss from the Edmonton area. Concentrations of Ni and Mo in the mosses were comparable in these two regions, but V was more abundant in the ABS samples. Compared with the surface vegetation of eight peat cores collected in recent years from British Columbia, Ontario, Quebec and New Brunswick, the mean concentrations of Ag, As, Bi, Cd, Cu, Mo, Ni, Pb, Sb, Tl and Zn in the mosses from the ABS region are generally much lower. In fact, the concentrations of these trace elements in the samples from the ABS region are comparable to the corresponding values in forest moss from remote regions of central and northern Norway. Lithophile element concentrations (Ba, Be, Ga, Ge, Li, Sc, Th, Ti, Zr) explain most of the variation in trace metal concentrations in the moss samples. The mean concentrations of Th and Zr are greatest in the moss samples from the ABS region, reflecting dust inputs to the bogs from open pit mines, aggregate

  18. Measurement of polynuclear aromatic hydrocarbons (PAHs) in epiphytic lichens and from PM 2.5 filters for receptor modeling in the Alberta Oil Sands Region (Invited)

    NASA Astrophysics Data System (ADS)

    Studabaker, W. B.; Jayanty, J.; Raymer, J. H.; Krupa, S.

    2013-12-01

    As mining and refinery operations in the Alberta Oil Sands Region (AOSR) have expanded, there has been increasing concern for the impacts of air pollution generated by those operations on both human and ecosystem health. The inaccessibility of much of the AOSR makes it difficult to establish conventional air quality monitoring stations to the extent needed to model long-range impacts of emissions from the AOSR operations. Epiphytic lichens are important markers of ecosystem health, are well-established bioaccumulators of trace metals, and are potentially useful biomonitors of air pollution. However, their ability to take up organic pollutants has not been extensively explored, and only recently have they been used for biomonitoring of pollution by PAHs. Here we describe the determination of polynuclear aromatic hydrocarbons (PAHs) in lichens, collected from sites throughout the AOSR, for modeling emissions associated with mining and oil extraction operations. We also describe preliminary results of the determination of PAHs in PM 2.5 filters from dichotomous samplers stationed in the AOSR, in the context of the biological sample data. Lichens (Hypogymnia physodes) were collected on two separate occasions. During the summer of 2009, single samples were taken from 200 sites in the AOSR; a subset of 20 of these was selected for determination of PAHs. During the summer of 2011, triplicate samples (from separate trees within a site) were collected from 20 sites representing similar locations to the 2008 sites. Lichens were milled in a cryogenic impactor, then were extracted with cyclohexane. Extracts were purified on silica gel using automated solid phase extraction and analyzed by gas chromatography with mass selective detection. Method detection limits for individual PAHs were 2-4 ng/g. Total PAHs in the samples from both collection events ranged from 50 ng/g to 350 ng/g, and declined with increasing distance from the mining and refinery operations. The relative

  19. Isotopic characterization of nitrate, ammonium and sulfate in stack PM2.5 emissions in the Athabasca Oil Sands Region, Alberta, Canada

    NASA Astrophysics Data System (ADS)

    Proemse, Bernadette C.; Mayer, Bernhard; Chow, Judith C.; Watson, John G.

    2012-12-01

    Stable isotope techniques may be a suitable tool for tracing industrial emissions in the atmosphere and the environment provided that the isotopic compositions of industrial emissions are distinct. We determined the isotopic compositions of nitrate, ammonium and sulfate in PM2.5 emitted from two industrial stacks at a large upgrader site in the Athabasca oil sands region (AOSR), northeastern Alberta, Canada, and compared them to the nitrogen and sulfur isotopic compositions of source materials and upgrading by-products. We found distinct isotopic compositions of nitrate and ammonium in PM2.5 compared to those reported for atmospheric nitrate and ammonium in the literature. Nitrate in PM2.5 had δ15N values of 9.4‰ (Stack A) and 16.1 ± 1.2‰ (Stack B) that were significantly enriched in 15N compared to the feedstock materials (˜2.5‰), by-products of upgrading (-0.3-1.3‰), and atmospheric N2 (0‰). δ15N of ammonium in PM2.5 showed a large range with values between - 4.5 to +20.1‰ (Stack B). We report the first measurements of the triple oxygen isotopic composition of industrial emitted nitrate. Nitrate emitted as PM2.5 is not mass-independently enriched in 17O resulting in Δ17O = 0.5 ± 0.9‰ (Stack B) and is therefore distinct from atmospheric nitrate, constituting an excellent indicator of industrial derived nitrate. δ18O values of nitrate in PM2.5 (36.0 and 17.6 ± 1.8‰ for Stack A and B, respectively) were also significantly lower than δ18O values of atmospheric nitrates and hence isotopically distinct. δ34S values of sulfate in PM2.5 were with 7.3 ± 0.3‰ (Stack A) and 9.4 ± 2.0‰ (Stack B) slightly enriched in 34S compared to δ34S in bitumen (4.3 ± 0.3‰) and coke (3.9 ± 0.2‰). δ18O values of sulfate in PM2.5 were 18.9 ± 2.9‰ and 14.2 ± 2.8‰ for Stack A and Stack B, respectively. The isotopic composition of sulfate in PM2.5 was not sufficiently different from δ34S and δ18O values of sulfate in long-range atmospheric

  20. Inter-comparison of MAX-DOAS Retrieved Vertical Profiles of Aerosol Extinction, SO2 and NO2 in the Alberta Oil Sands with LIDAR Data and GEM-MACH Air Quality Model.

    NASA Astrophysics Data System (ADS)

    Davis, Zoe; Friess, Udo; Strawbridge, Kevin; Whiteway, James; Aggarwal, Monika; Makar, Paul; Li, Shao-Meng; O'Brien, Jason; Baray, Sabour; Schnitzler, Elijah; Olfert, Jason S.; Osthoff, Hans D.; Lobo, Akshay; McLaren, Robert

    2016-04-01

    Understanding industrial emissions of trace gas pollutants in the Alberta oil sands is essential to maintaining air quality standards and informing public policy. Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) measurements of trace gases can improve knowledge of pollutant levels, vertical distribution and chemical transformation. During an intensive air measurement campaign to study emissions, transport, transformation and deposition of oil sands air pollutants from August to September of 2013, a MAX-DOAS instrument was deployed at a site north of Fort McMurray, Alberta to determine the vertical profiles of aerosol extinction, NO2 and SO2 through retrieval from the MAX-DOAS spectral measurements using an optimal estimation method. The large complement of data collected from multiple instruments deployed during this field campaign provides a unique opportunity to validate and characterize the performance of the MAX-DOAS vertical profile retrievals. Aerosol extinction profiles determined from two Light Detection and Ranging (LIDAR) instruments, one collocated and the other on a Twin Otter aircraft that flew over the site during the study, will be compared to the MAX-DOAS aerosol extinction profile retrievals. Vertical profiles of NO2 and SO2 retrieved from the MAX-DOAS measurements will be further compared with the composite vertical profiles measured from the flights of a second aircraft, the NRC-Convair 580, over the field site during the same measurement period. Finally, the MAX-DOAS retrieved tropospheric vertical column densities (VCDs) of SO2 and NO2 will be compared to the predicted VCDs from Environment and Climate Change Canada's Global Environmental Multi-scale - Modelling Air quality and Chemistry (GEM-MACH) air quality model over the grid cell containing the field site. Emission estimates of SO2 from the major oil mining facility Syncrude Mildred Lake using the MAX-DOAS VCD results, validated through the detailed characterization above

  1. Characterization of trace gases measured over Alberta oil sands mining operations: 76 speciated C2-C10 volatile organic compounds (VOCs), CO2, CH4, CO, NO, NO2, NOy, O3 and SO2

    NASA Astrophysics Data System (ADS)

    Simpson, I. J.; Blake, N. J.; Barletta, B.; Diskin, G. S.; Fuelberg, H. E.; Gorham, K.; Huey, L. G.; Meinardi, S.; Rowland, F. S.; Vay, S. A.; Weinheimer, A. J.; Yang, M.; Blake, D. R.

    2010-12-01

    Oil sands comprise 30% of the world's oil reserves and the crude oil reserves in Canada's oil sands deposits are second only to Saudi Arabia. The extraction and processing of oil sands is much more challenging than for light sweet crude oils because of the high viscosity of the bitumen contained within the oil sands and because the bitumen is mixed with sand and contains chemical impurities such as sulphur. Despite these challenges, the importance of oil sands is increasing in the energy market. To our best knowledge this is the first peer-reviewed study to characterize volatile organic compounds (VOCs) emitted from Alberta's oil sands mining sites. We present high-precision gas chromatography measurements of 76 speciated C2-C10 VOCs (alkanes, alkenes, alkynes, cycloalkanes, aromatics, monoterpenes, oxygenated hydrocarbons, halocarbons and sulphur compounds) in 17 boundary layer air samples collected over surface mining operations in northeast Alberta on 10 July 2008, using the NASA DC-8 airborne laboratory as a research platform. In addition to the VOCs, we present simultaneous measurements of CO2, CH4, CO, NO, NO2, NOy, O3 and SO2, which were measured in situ aboard the DC-8. Carbon dioxide, CH4, CO, NO, NO2, NOy, SO2 and 53 VOCs (e.g., non-methane hydrocarbons, halocarbons, sulphur species) showed clear statistical enhancements (1.1-397×) over the oil sands compared to local background values and, with the exception of CO, were greater over the oil sands than at any other time during the flight. Twenty halocarbons (e.g., CFCs, HFCs, halons, brominated species) either were not enhanced or were minimally enhanced (<10%) over the oil sands. Ozone levels remained low because of titration by NO, and three VOCs (propyne, furan, MTBE) remained below their 3 pptv detection limit throughout the flight. Based on their correlations with one another, the compounds emitted by the oil sands industry fell into two groups: (1) evaporative emissions from the oil sands and its

  2. Photochemical model evaluation of the ground-level ozone impacts on ambient air quality and vegetation health in the Alberta oil sands region: Using present and future emission scenarios

    NASA Astrophysics Data System (ADS)

    Vijayaraghavan, Krish; Cho, Sunny; Morris, Ralph; Spink, David; Jung, Jaegun; Pauls, Ron; Duffett, Katherine

    2016-09-01

    One of the potential environmental issues associated with oil sands development is increased ozone formation resulting from NOX and volatile organic compound emissions from bitumen extraction, processing and upgrading. To manage this issue in the Athabasca Oil Sands Region (AOSR) in northeast Alberta, a regional multi-stakeholder group, the Cumulative Environmental Management Association (CEMA), developed an Ozone Management Framework that includes a modelling based assessment component. In this paper, we describe how the Community Multi-scale Air Quality (CMAQ) model was applied to assess potential ground-level ozone formation and impacts on ambient air quality and vegetation health for three different ozone precursor cases in the AOSR. Statistical analysis methods were applied, and the CMAQ performance results met the U.S. EPA model performance goal at all sites. The modelled 4th highest daily maximum 8-h average ozone concentrations in the base and two future year scenarios did not exceed the Canada-wide standard of 65 ppb or the newer Canadian Ambient Air Quality Standards of 63 ppb in 2015 and 62 ppb in 2020. Modelled maximum 1-h ozone concentrations in the study were well below the Alberta Ambient Air Quality Objective of 82 ppb in all three cases. Several ozone vegetation exposure metrics were also evaluated to investigate the potential impact of ground-level ozone on vegetation. The chronic 3-months SUM60 exposure metric is within the CEMA baseline range (0-2000 ppb-hr) everywhere in the AOSR. The AOT40 ozone exposure metric predicted by CMAQ did not exceed the United Nations Economic Commission for Europe (UN/ECE) threshold of concern of 3000 ppb-hr in any of the cases but is just below the threshold in high-end future emissions scenario. In all three emission scenarios, the CMAQ predicted W126 ozone exposure metric is within the CEMA baseline threshold of 4000 ppb-hr. This study outlines the use of photochemical modelling of the impact of an industry (oil

  3. Examination of mercury and organic carbon dynamics from a constructed fen in the Athabasca oil sands region, Alberta, Canada using in situ and laboratory fluorescence measurements

    NASA Astrophysics Data System (ADS)

    Oswald, C.; Carey, S. K.

    2013-12-01

    In the Athabasca oil sands region, mined landscapes must be reclaimed to a functioning natural ecosystem as part of the mine closure process. To test wetland construction techniques on oil sands tailings, 55 ha of mined landscape on the Syncrude Canada Ltd. property is being reclaimed to a watershed containing a graminoid fen. The 18 ha constructed fen consists of an approximately 50 cm thick peat-mineral soil layer separated from underlying tailings sand by a thin layer of clay till. The water table in the fen is maintained by pumping water into the fen from a nearby lake and controlling outflow with under-drains. The objective of this study was to assess total mercury (THg) and methyl mercury (MeHg) concentration dynamics in water exported from the fen in relation to organic carbon quantity and composition. Water quality data from summer 2012 when the fen pumps were first turned on show that dissolved organic carbon (DOC) concentrations are on average twice as high in water flowing through the underlying tailings sand aquifer (median: 42.0 mg/L) compared to DOC concentrations in water flowing through the fen peat package (median: 20.3 mg/L). Given these DOC concentrations, filtered THg concentrations are very low (median values are 0.81 ng/L and 0.17 ng/L for water flowing through the fen peat and sand tailings, respectively) compared to concentrations reported for other boreal wetlands. Although a relationship was identified between filtered THg and DOC (r2=0.60), its slope (0.06 ng Hg/mg C) is an order-of-magnitude smaller than the typical range of slopes found at other wetland sites potentially suggesting a small pool of mercury in the peat and/or limited partitioning of mercury into solution. Filtered MeHg concentrations in all water samples are near the limit of detection and suggest that biogeochemical conditions conducive to methylation did not exist in the fen peat or tailings sand at the time of sampling. In addition to these baseline THg and Me

  4. Research investigations in oil shale, tar sand, coal research, advanced exploratory process technology, and advanced fuels research: Volume 2 -- Jointly sponsored research program. Final report, October 1986--September 1993

    SciTech Connect

    Smith, V.E.

    1994-09-01

    Numerous studies have been conducted in five principal areas: oil shale, tar sand, underground coal gasification, advanced process technology, and advanced fuels research. In subsequent years, underground coal gasification was broadened to be coal research, under which several research activities were conducted that related to coal processing. The most significant change occurred in 1989 when the agreement was redefined as a Base Program and a Jointly Sponsored Research Program (JSRP). Investigations were conducted under the Base Program to determine the physical and chemical properties of materials suitable for conversion to liquid and gaseous fuels, to test and evaluate processes and innovative concepts for such conversions, to monitor and determine environmental impacts related to development of commercial-sized operations, and to evaluate methods for mitigation of potential environmental impacts. This report is divided into two volumes: Volume 1 consists of 28 summaries that describe the principal research efforts conducted under the Base Program in five topic areas. Volume 2 describes tasks performed within the JSRP. Research conducted under this agreement has resulted in technology transfer of a variety of energy-related research information. A listing of related publications and presentations is given at the end of each research topic summary. More specific and detailed information is provided in the topical reports referenced in the related publications listings.

  5. Fostering Innovation in Alberta

    ERIC Educational Resources Information Center

    Online Submission, 2005

    2005-01-01

    In 2005, the Minister of Alberta Advanced Education initiated a comprehensive exercise to establish a new direction for Alberta's advanced education system. Through the A Learning Alberta review, a new vision and policy outcomes for the advanced education system will be articulated. The process provides an opportunity for government, stakeholders,…

  6. The extraction of bitumen from western oil sands. Final report, July 1989--September 1993

    SciTech Connect

    Oblad, A.G.; Bunger, J.W.; Dahlstrom, D.A.; Deo, M.D.; Fletcher, J.V.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1994-03-01

    Research and development of surface extraction and upgrading processes of western tar sands are described. Research areas included modified hot water, fluidized bed, and rotary kiln pyrolysis of tar sands for extraction of bitumen. Bitumen upgrading included solvent extraction of bitumen, and catalytic hydrotreating of bitumen. Characterization of Utah tar sand deposits is also included.

  7. Ten Years of Growing Season Water, Energy and Carbon Exchange From an Oil sands Reclamation Site, Fort McMurray, Alberta

    NASA Astrophysics Data System (ADS)

    Carey, S. K.; Drewitt, G. B.

    2013-12-01

    The oil sands mining industry in Canada has made a commitment to restore disturbed areas to an equivalent capability to that which existed prior to mining. Certification requires successful reclamation, which can in part be evaluated through long-term ecosystem studies. A reclamation site, informally named South Bison Hill (SBH) has had growing season water, energy and carbon fluxes measured via the eddy covariance method for 10 years since establishment. SBH was capped with a 0.2 m peat-glacial till mixture overlying 0.8 m of reworked glacial till soil. The site was seeded to barley cultivar (Hordeum spp.) in the summer of 2002 and later planted to white spruce (Picea glauca) and aspen (Populus spp.) in the summer/fall of 2004. Since 2007, the major species atop SBH has been aspen, and by 2012 was on average ~ 4 m in height. Climatically, mean growing temperature did not vary greatly, yet there was considerable difference in rainfall among years, with 2012 having the greatest rainfall at 321 mm, whereas 2011 and 2007 were notably dry at 180 and 178 mm, respectively. The partitioning of energy varied among years, but the fraction of latent heat as a portion of net radiation increased with the establishment of aspen, along with concomitant increases in LAI and growing season net ecosystem exchange (NEE). Peat growing season ET was smallest in 2004 at 2.3 mm/d and greatest in 2010 at ~3.9 mm/d. ET rates showed a marked increase in 2008 corresponding with the increase in LAI attributed to the aspen cover. Since the establishment of a surface cover and vegetation in 2003, SBH has been a growing season sink for carbon dioxide. Values of NEE follow similar patterns to those of ET, with values gradually becoming more negative (greater carbon uptake) as the aspen forest established. Comparison with other disturbed and undisturbed boreal aspen stands show that SBH exhibits similar water, energy and carbon flux patterns during the growing season.

  8. Alberta Literacy Inventory Report.

    ERIC Educational Resources Information Center

    Alberta Dept. of Advanced Education, Calgary.

    This report presents results of a study to identify existing literacy programs and resource centers in Alberta and profile the individuals who hold a stake in Alberta's literacy programming efforts. It begins with highlights of project results related to programs, program administrators, instructors/tutors, and learners (all groups) and a summary…

  9. Treating tar sands formations with dolomite

    SciTech Connect

    Vinegar, Harold J.; Karanikas, John Michael

    2013-10-15

    A method for treating a karsted formation containing heavy hydrocarbons and dolomite includes providing heat to at least part of one or more karsted layers in the formation from one or more heaters located in the karsted layers. A temperature in at least one of the karsted layers is allowed to reach a decomposition temperature of dolomite in the formation. The dolomite is allowed to decompose and at least some hydrocarbons are produced from at least one of the karsted layers of the formation.

  10. Evaluation of surfactant flushing for remediating EDC-tar contamination.

    PubMed

    Liang, Chenju; Hsieh, Cheng-Lin

    2015-01-01

    Ethylene dichloride tar (EDC-tar) is a dense non-aqueous phase liquid (DNAPL) waste originated from the process of vinyl chloride production, with major constituents including chlorinated aliphatic and aromatic hydrocarbons. This study investigated the feasibility of Surfactant Enhanced Aquifer Remediation (SEAR) for treating EDC-tar contaminated aquifers. Initial experiments explored the potential to enhance the apparent solubility of EDC-tar using single or mixed surfactants. The results showed that an aqueous solution mixed anionic and non-ionic surfactants (i.e., SDS/Tween 80) exhibited higher EDC-tar apparent solubility and lower surface tension than other surfactant systems tested. Additionally, alkaline pH aids in increasing the EDC-tar apparent solubility. In column flushing experiments, it was seen that the alkaline mixed SDS/Tween 80 solution showed better removal of pure EDC-tar from silica sand porous media. Furthermore, separation of EDC-tar in the surfactant solution was conducted employing a salting-out effect. Significant separation of DNAPL was observed when 13 wt.% or more NaCl was added to the solution. Overall, this study evaluates the feasibility of using SEAR for remediating EDC-tar contaminated subsurface soil and groundwater. PMID:25941757

  11. Evaluation of surfactant flushing for remediating EDC-tar contamination

    NASA Astrophysics Data System (ADS)

    Liang, Chenju; Hsieh, Cheng-Lin

    2015-06-01

    Ethylene dichloride tar (EDC-tar) is a dense non-aqueous phase liquid (DNAPL) waste originated from the process of vinyl chloride production, with major constituents including chlorinated aliphatic and aromatic hydrocarbons. This study investigated the feasibility of Surfactant Enhanced Aquifer Remediation (SEAR) for treating EDC-tar contaminated aquifers. Initial experiments explored the potential to enhance the apparent solubility of EDC-tar using single or mixed surfactants. The results showed that an aqueous solution mixed anionic and non-ionic surfactants (i.e., SDS/Tween 80) exhibited higher EDC-tar apparent solubility and lower surface tension than other surfactant systems tested. Additionally, alkaline pH aids in increasing the EDC-tar apparent solubility. In column flushing experiments, it was seen that the alkaline mixed SDS/Tween 80 solution showed better removal of pure EDC-tar from silica sand porous media. Furthermore, separation of EDC-tar in the surfactant solution was conducted employing a salting-out effect. Significant separation of DNAPL was observed when 13 wt.% or more NaCl was added to the solution. Overall, this study evaluates the feasibility of using SEAR for remediating EDC-tar contaminated subsurface soil and groundwater.

  12. Drilling of three horizontal hole pattern Fort McMurray, Alberta

    SciTech Connect

    Pugh, G.E.

    1982-01-01

    Between Oct. 1980 and Feb. 1981, Texaco Canada Resources Ltd. drilled 3 horizontal holes in soft, shallow, unconsolidated Athabasca tar sands at their Fort McMurray Pilot Plant, Alberta, Can. Objectives of the project were to produce bitumen at very shallow depths with minimum drilling cost, lease cost, and environmental impact. The accomplishment is believed unique in that all 3 wells were drilled from the same drilling pad, each well being spudded in at a vertical angle of 45, and a horizontal attitude was achieved at a true vertical depth from surface of ca 125 m (410 ft). Over 350 m (1,000 ft) of horizontal hole was drilled to complete each well. A new, innovative, hydraulically operated drilling rig was built for this project with a 110,000 kg. (240,000 lb) hoist and 22,700 kg (50,000 lb) push-down capacity. New techniques were developed to drill, enlarge, and underream the horizontal hole up to 368.3 mm (14-1/2 in.) diameter. Mud motors were used to power the bit and the force on the bit was accomplished by pushing down on the drill pipe.

  13. Alberta Unites on Teaching Quality

    ERIC Educational Resources Information Center

    Crow, Tracy

    2010-01-01

    Education policy in the province of Alberta is set by Alberta Education, a ministry led by the province's minister of education. There are two key policies or ministerial orders that guide professional learning in Alberta. The Teaching Quality Standard outlines the knowledge, skills, and attributes that teachers are expected to possess. The…

  14. Plant response to aqueous effluents derived from in-situ fossil-fuel processing. Part III. Three grass species and their response to Omega 9 and to five produced retort waters: oil shale, tar sands and underground coal gasification. [Basin wildrye; western wheatgrass; alkali sacaton

    SciTech Connect

    Skinner, Q.D.

    1981-12-01

    In situ produced waters collected from retorting oil shale and tar sands to produce oil and in-situ coal gasification to produce gas were tested for their effect on plant growth. Three native grass plant species were utilized for monitoring growth response. Root weight, shoot weight, total dry weight, leaf area, root/shoot ratio and shoot/leaf area ratio were parameters measured. All experiments were conducted under greenhouse conditions using hydroponic techniques and commercial grade perlite as support systems. Measurements were collected after a 10-week growth period. The hypothesis tested was, there is a difference between produced waters diluted by ground water and those where dilution is non-existent and their effect on plant growth. Results indicated that retort water diluted by ground water has a less toxic effect on plant species tested.

  15. Plant response to aqueous effluents derived from in-situ fossil-fuel processing. Part II. Five grass plant species and their response to five produced retort waters: oil shale, tar sands, and underground coal gasification. [Wildrye; wheatgrass; alkali sacaton; alkaligrass

    SciTech Connect

    Skinner, Q.D.

    1981-11-01

    In situ produced waters collected from retorting oil shale and tar sands to produce oil and in-situ coal gasification to produce gas were tested for their effect on plant growth. Five native grass plant species were utilized for monitoring growth response. Root weight, shoot weight, total dry weight, leaf area, root/shoot ratio and shoot/leaf area ratio were parameters measured. All experiments were conducted under greenhouse conditions using hydroponic techniques and commercial grade perlite as support systems. Measurements were collected after a 10 week growth period. Hypotheses tested were: (a) there is a difference between in situ produced waters, and (b) plant species respond differently to various retort waters. Results indicated that the stated hypotheses were true.

  16. Utilization of acid tars

    SciTech Connect

    Frolov, A.F.; Denisova, T.L.; Aminov, A.N.

    1987-01-01

    Freshly produced acid tar (FPAT), obtained as refinery waste in treating petroleum oils with sulfuric acid and oleum, contains 80% or more sulfuric acid. Of such tars, pond acid tars, which contain up to 80% neutral petroleum products and sulfonated resins, are more stable, and have found applications in the production of binders for paving materials. In this article the authors are presenting results obtained in a study of the composition and reactivity of FPAT and its stability in storage in blends with asphalts obtained in deasphalting operations, and the possibility of using the FPAT in road construction has been examined. In this work, wastes were used which were obtained in treating the oils T-750, KhF-12, I-8A, and MS-14. Data on the change in group chemical composition of FPAT are shown, and the acidity, viscosity, needle penetration, and softening point of acid tars obtained from different grades of oils are plotted as functions of the storage time. It is also shown that the fresh and hardened FPATs differ in their solubilities in various solvents.

  17. A Learning Alberta: Fostering Innovation in Alberta. A Discussion Document

    ERIC Educational Resources Information Center

    Alberta Advanced Education, 2005

    2005-01-01

    The Minister has initiated a comprehensive exercise to establish a new direction for Alberta's advanced education system. Through "A Learning Alberta," a new vision and policy outcomes for the advanced education system will be articulated. The process provides an opportunity for government, stakeholders, and the public to consider how the advanced…

  18. Alberta Education's Computer Technology Project.

    ERIC Educational Resources Information Center

    Thiessen, Jim

    This description of activities initiated through the Computer Technology Project of the provincial education ministry in Alberta, Canada, covers the 2-year period beginning with establishment of the project by the Alberta Department of Education in October 1981. Activities described include: (1) the establishment of the Office of Educational…

  19. Implementation of an ex situ stabilization technique at the Sand Springs superfund site to solidify and stabilize acid tar sludges involving a quick-lime based stabilization process and innovative equipment design

    SciTech Connect

    McManus, R.W.; Grajczak, P.; Wilcoxson, J.C.; Webster, S.D.

    1997-12-31

    An old refinery site was safely remediated a year before schedule and for 25% less than final engineering estimates for the stabilization remedy thanks to energetic project management and innovative design involving ex situ stabilization/solidification of acid tar sludges. A quicklime based process, Dispersion by Chemical Reaction (DCR{trademark}), was employed to solidify and stabilize (SS) over 103,000 cubic meters (135,000 cubic yards) of petroleum waste, mostly acidic tarry sludge. The SS process was selected over competing methods because it afforded minimal volume increase, could readily achieve Record of Decision (ROD) specified physical and chemical treatment goals, could be implemented with treatment equipment that minimized emissions, and could be performed with low reagent usage and at low cost. To ensure treatment goals were achieved and an accelerated schedule met, a custom designed and fabricated transportable treatment unit (TTU) was employed to implement the process. The treated material was visually soil-like in character, it was left in stockpiles for periods of time, and it was placed and compacted in the on site landfill using standard earth-moving equipment.

  20. Study on tar generated from downdraft gasification of oil palm fronds.

    PubMed

    Atnaw, Samson Mekbib; Kueh, Soo Chuan; Sulaiman, Shaharin Anwar

    2014-01-01

    One of the most challenging issues concerning the gasification of oil palm fronds (OPF) is the presence of tar and particulates formed during the process considering its high volatile matter content. In this study, a tar sampling train custom built based on standard tar sampling protocols was used to quantify the gravimetric concentration of tar (g/Nm3) in syngas produced from downdraft gasification of OPF. The amount of char, ash, and solid tar produced from the gasification process was measured in order to account for the mass and carbon conversion efficiency. Elemental analysis of the char and solid tar samples was done using ultimate analysis machine, while the relative concentration of the different compounds in the liquid tar was determined making use of a liquid gas chromatography (GC) unit. Average tar concentration of 4.928 g/Nm3 and 1.923 g/Nm3 was obtained for raw gas and cleaned gas samples, respectively. Tar concentration in the raw gas sample was found to be higher compared to results for other biomass materials, which could be attributed to the higher volatile matter percentage of OPF. Average cleaning efficiency of 61% which is comparable to that of sand bed filter and venturi scrubber cleaning systems reported in the literature was obtained for the cleaning system proposed in the current study. PMID:24526899

  1. Study on Tar Generated from Downdraft Gasification of Oil Palm Fronds

    PubMed Central

    Atnaw, Samson Mekbib; Kueh, Soo Chuan; Sulaiman, Shaharin Anwar

    2014-01-01

    One of the most challenging issues concerning the gasification of oil palm fronds (OPF) is the presence of tar and particulates formed during the process considering its high volatile matter content. In this study, a tar sampling train custom built based on standard tar sampling protocols was used to quantify the gravimetric concentration of tar (g/Nm3) in syngas produced from downdraft gasification of OPF. The amount of char, ash, and solid tar produced from the gasification process was measured in order to account for the mass and carbon conversion efficiency. Elemental analysis of the char and solid tar samples was done using ultimate analysis machine, while the relative concentration of the different compounds in the liquid tar was determined making use of a liquid gas chromatography (GC) unit. Average tar concentration of 4.928 g/Nm3 and 1.923 g/Nm3 was obtained for raw gas and cleaned gas samples, respectively. Tar concentration in the raw gas sample was found to be higher compared to results for other biomass materials, which could be attributed to the higher volatile matter percentage of OPF. Average cleaning efficiency of 61% which is comparable to that of sand bed filter and venturi scrubber cleaning systems reported in the literature was obtained for the cleaning system proposed in the current study. PMID:24526899

  2. Centrifuge treatment of coal tar

    SciTech Connect

    L.A. Kazak; V.Z. Kaidalov; L.F. Syrova; O.S. Miroshnichenko; A.S. Minakov

    2009-07-15

    New technology is required for the removal of water and heavy fractions from regular coal tar. Centrifuges offer the best option. Purification of coal tar by means of centrifuges at OAO NLMK permits the production of pitch coke or electrode pitch that complies with current standards.

  3. Millennium Open Pit Mine, Alberta, Canada

    NASA Technical Reports Server (NTRS)

    2007-01-01

    Near Fort McMurray, Alberta, Canada, on the east bank of the Athabasca River, are found the Steepbank and Millennium mines. These open pit mines produce oil sands that are processed to recover bitumen, and then upgrade it to refinery-ready raw crude oil, and diesel fuel.

    The ASTER images were acquired September 22, 2000 and July 31, 2007, cover an area of 22.5 x 25.5 km, and are located near 57 degrees north latitude, 111.5 degrees west longitude.

    The U.S. science team is located at NASA's Jet Propulsion Laboratory, Pasadena, Calif. The Terra mission is part of NASA's Science Mission Directorate.

  4. Remediation of Former Manufactured Gas Plant Tars Using Alkaline Flushing

    NASA Astrophysics Data System (ADS)

    Hauswirth, S.; Rylander, S.; Birak, P. S.; Miller, C. T.

    2010-12-01

    The remediation of former manufactured gas plant (FMGP) tars in the subsurface is particularly difficult due to the wetting behavior and high viscosities of these dense non-aqueous liquids (DNAPLs). Alkaline flooding is a technique which has proven effective in improving the recovery of crude oils, which share some characteristics with FMGP tars. For this study, we measured the effect of NaOH solutions on interfacial tension and conducted column experiments to investigate the feasibility of applying this technique to FMGP tars. The pendant drop technique was used to measure interfacial tensions for solutions ranging from 0-1% NaOH. Column experiments were conducted by contaminating sands with tars recovered from a FMGP then flushing the columns with NaOH solutions. A final, 70% v/v ethanol cosolvent flush was conducted to investigate the effectiveness of a two-stage remediation approach. The mass removal of tar, as well as 26 individual PAHs, was measured, along with the aqueous phase mass flux of PAHs after each flushing stage. The interfacial tension was reduced from about 20 mN/m with pure water to a minimum of 0.05 mN/m at a concentration of 0.1% NaOH. In the column experiments, alkaline flushing resulted in a 50% reduction of the residual saturation. Aqueous phase PAH concentrations, however, were similar before and after the alkaline flushing stage. The combination of alkaline and cosolvent flushing resulted in an overall reduction of 95% of the total mass of the 16 EPA PAHs. Final aqueous phase concentrations were reduced significantly for lower molecular weight PAHs, but increased slightly for the higher molecular weight compounds, likely due to their increased mole fraction within the remaining tar. Additional work is being conducted to improve the effectiveness of the alkaline flushing through the use of surfactants and polymers.

  5. Modeling the impact of bubbling bed hydrodynamics on tar yield and its fluctuations during biomass fast pyrolysis

    SciTech Connect

    Xiong, Qingang; Ramirez, Emilio; Pannala, Sreekanth; Daw, C. Stuart; Xu, Fei

    2015-10-09

    The impact of bubbling bed hydrodynamics on temporal variations in the exit tar yield for biomass fast pyrolysis was investigated using computational simulations of an experimental laboratory-scale reactor. A multi-fluid computational fluid dynamics model was employed to simulate the differential conservation equations in the reactor, and this was combined with a multi-component, multi-step pyrolysis kinetics scheme for biomass to account for chemical reactions. The predicted mean tar yields at the reactor exit appear to match corresponding experimental observations. Parametric studies predicted that increasing the fluidization velocity should improve the mean tar yield but increase its temporal variations. Increases in the mean tar yield coincide with reducing the diameter of sand particles or increasing the initial sand bed height. However, trends in tar yield variability are more complex than the trends in mean yield. The standard deviation in tar yield reaches a maximum with changes in sand particle size. As a result, the standard deviation in tar yield increases with the increases in initial bed height in freely bubbling state, while reaches a maximum in slugging state.

  6. Modeling the impact of bubbling bed hydrodynamics on tar yield and its fluctuations during biomass fast pyrolysis

    DOE PAGESBeta

    Xiong, Qingang; Ramirez, Emilio; Pannala, Sreekanth; Daw, C. Stuart; Xu, Fei

    2015-10-09

    The impact of bubbling bed hydrodynamics on temporal variations in the exit tar yield for biomass fast pyrolysis was investigated using computational simulations of an experimental laboratory-scale reactor. A multi-fluid computational fluid dynamics model was employed to simulate the differential conservation equations in the reactor, and this was combined with a multi-component, multi-step pyrolysis kinetics scheme for biomass to account for chemical reactions. The predicted mean tar yields at the reactor exit appear to match corresponding experimental observations. Parametric studies predicted that increasing the fluidization velocity should improve the mean tar yield but increase its temporal variations. Increases in themore » mean tar yield coincide with reducing the diameter of sand particles or increasing the initial sand bed height. However, trends in tar yield variability are more complex than the trends in mean yield. The standard deviation in tar yield reaches a maximum with changes in sand particle size. As a result, the standard deviation in tar yield increases with the increases in initial bed height in freely bubbling state, while reaches a maximum in slugging state.« less

  7. [Effect of various kinds of tar and tar concentrations on anthralin erythema].

    PubMed

    Wemmer, U; Schulze, H J; Mahrle, G; Steigleder, G K

    1986-06-15

    The effect of tar on anthralin-induced erythema was epicutaneously tested in ten patients. 3%, 5%, or 10% crude coal tar or coal tar solution was added to vaseline containing anthralin. A 5% or 10% tar preparation significantly suppressed the anthralin erythema induced by 0.5 to 1.0% anthralin having been applied for 24 hrs. In these concentrations, coal tar solution was at least as effective as coal tar itself. PMID:3751210

  8. Topical tar: Back to the future

    SciTech Connect

    Paghdal, K.V.; Schwartz, R.A.

    2009-08-15

    The use of medicinal tar for dermatologic disorders dates back to the ancient times. Although coal tar is utilized more frequently in modern dermatology, wood tars have also been widely employed. Tar is used mainly in the treatment of chronic stable plaque psoriasis, scalp psoriasis, atopic dermatitis, and seborrheic dermatitis, either alone or in combination therapy with other medications, phototherapy, or both. Many modifications have been made to tar preparations to increase their acceptability, as some dislike its odor, messy application, and staining of clothing. One should consider a tried and true treatment with tar that has led to clearing of lesions and prolonged remission times. Occupational studies have demonstrated the carcinogenicity of tar; however, epidemiologic studies do not confirm similar outcomes when used topically. This article will review the pharmacology, formulations, efficacy, and adverse effects of crude coal tar and other tars in the treatment of selected dermatologic conditions.

  9. Recognition and delineation of Paleokarst zones by the use of wireline logs in the bitumen-saturated upper Devonian Grosmont formation of Northeastern Alberta, Canada

    SciTech Connect

    Dembicki, E.A.; Machel, H.G.

    1996-05-01

    The Upper Devonian Grosmont Formation in northeastern Alberta, Canada, is a shallow-marine carbonate platform complex that was subaerially exposed for hundreds of millions of years between the Mississippian(?) and Cretaceous. During this lengthy exposure period, an extensive karst system developed that is characterized by an irregular erosional surface, meter-size (several feet) dissolution cavities, collapse breccias, sinkholes, paleosols, and fractures. The karsted Grosmont Formation, which contains giant reserves of bitumen, sub-crops beneath Cretaceous clastic sediments of the giant Athabasca tar sands deposit. The paleokarst in the Grosmont Formation can be recognized on wireline logs in relatively nonargillaceous carbonate intervals (<30 API units on the gamma-ray log) as excursions of the caliper log, off-scale neutron-density porosity readings, and severe cycle skipping of the acoustic log. The paleokarst is more prevalent in the upper units of the Grosmont Formation, and the effects of karstification decrease toward stratigraphically older and deeper units. The paleokarst usually occurs within 35 m (115 ft) of the erosional surface. The reservoir properties of the Grosmont Formation (e.g., thickness, porosity, permeability, and seal effectiveness) are significantly influenced by karstification. Depending upon the location, karstification has either benefited or degraded the reservoir characteristics. Benefits include porosity values greater than 40% (up to 100% in caverns) and permeability values of 30,000 md in severely fractured intervals. Detrimental reservoir characteristics include erosion, porosity and permeability reduction, and seal ineffectiveness.

  10. Coal tar phototherapy for psoriasis reevaluated: erythemogenic versus suberythemogenic ultraviolet with a tar extract in oil and crude coal tar

    SciTech Connect

    Lowe, N.J.; Wortzman, M.S.; Breeding, J.; Koudsi, H.; Taylor, L.

    1983-06-01

    Recent studies have questioned the therapeutic value of coal tar versus ultraviolet (UV) radiation and their relative necessity in phototherapy for psoriasis. In this investigation, different aspects of tar phototherapy have been studied in single-blind bilateral paired comparison studies. The effects of 1% crude coal tar were compared with those of petrolatum in conjunction with erythemogenic and suberythemogenic doses of ultraviolet light (UVB) using a FS72 sunlamp tubed cabinet. Crude coal tar was clinically superior to petrolatum with suberythemogenic ultraviolet. With the erythemogenic UVB, petrolatum was equal in efficacy to crude coal tar. Suberythemogenic UVB was also used adjunctively to compare the effects of a 5% concentration of a tar extract in an oil base to 5% crude coal tar in petrolatum or the oil base without tar. The tar extract in oil plus suberythemogenic UVB produced significantly more rapid improvement than the oil base plus UVB. The direct bilateral comparison of equal concentrations of tar extract in oil base versus crude coal tar in petrolatum in a suberythemogenic UV photo regimen revealed no statistical differences between treatments. In a study comparing tar extract in oil and the oil base without ultraviolet radiation, the tar extract in oil side responded more rapidly.

  11. Spectroscopic characterization of visbreaking tars

    SciTech Connect

    Scotti, R.; Clericuzio, M.; Pirovano, C.

    1995-12-31

    The stability of visbreaking tars (VB-tar) constitutes a limit for converting petroleum residues into distillates. Depending on the severity of the process (temperature and/or residence time), a progressive thermal dealkylation of asphaltene molecules occurs, resulting in an increase of aromaticity. As a consequence asphaltenes are hardly maintained in stable suspensions and tend to separate. In the present work VB-tars (350{degrees}C+ and 500{degrees}C+) with different degrees of stability were produced in a continuous bench-scale plant under isothermal conditions (442{degrees}C) with different residence times. The VB-tars were investigated by: (1) NIR and FT-IR to detect the functional groups, (2) UV-VIS and Fluorescence spectroscopies to follow the evolution of aromatic components of the ters, (3) {sup 1}H- and {sup 13}C-NMR to quantify the aromatic content, the degree of substitution of aromatic carbons and the main length of the aliphatic side chains, (4) EPR to study the nature and the amount of radicals. The results of structural investigation and their relations to VB-tar stability will be critically discussed.

  12. Satisfaction with Education in Alberta.

    ERIC Educational Resources Information Center

    McEwen, Nelly

    1998-01-01

    Annual Alberta surveys of parents, high school students, and the public are part of accountability processes and provide public consultation on policy issues and reform efforts. Selected results of the 1995 and 1996 surveys are presented, related to provincial educational objectives, and compared to similar U.S. and Ontario surveys and established…

  13. Bovine Stephanofilarial Dermatitis in Alberta

    PubMed Central

    Dies, Ken H.; Pritchard, Jane

    1985-01-01

    The nematode, Stephanofilaria stilesi was recovered from two mature beef cattle in Alberta. The appearance of the skin and the histological lesions are described. The life cycle of the parasite and the development of lesions are reviewed. ImagesFigure 1.Figure 2.Figure 3. PMID:17422593

  14. Alberta. Reference Series No. 26.

    ERIC Educational Resources Information Center

    Department of External Affairs, Ottawa (Ontario).

    This booklet, one of a series featuring the Canadian provinces, presents a brief overview of Alberta and is suitable for teacher reference or student reading. Separate sections discuss the history and population, the provincial government, the economy, transportation, communications, mineral resources, agriculture, manufacturing, forest products,…

  15. Spectroscopic characterization of visbreaking tars

    SciTech Connect

    Scotti, R.; Clericuzio, M.; Pirovano, C.

    1995-12-31

    Visbreaking (VB) is a thermal cracking process, widely used in the refineries of Western Europe to obtain distillates (gasoil, naphtha) from a petroleum residue (feedstock). The visbroken residue (tar) is used to produce fuel oil, after addition of the appropriate amounts of cutter-stock. Even if the highest conversion of feedstock would be desirable, the severity of the VB process is limited by the stability of the resulting VB tars. The stability index (SI) here employed is: SI = I + V{sub cet}, where V{sub cet} is the maximum amount of n-cetane, expressed as ml of cetane for g of sample, that can be added before the flocculation of asphaltenes starts. VB tars having SI<1.1 are considered to be unstable and cannot be used in the preparation of fuel oils with the appropriate specifications. Several papers can be found in the literature dealing with the molecular changes occuring during the VB process. The present paper is aimed at verifying the amount of information that can be extracted from optical spectroscopies and, in particular, the possibility of directly monitoring the physico-chemical modifications caused by VB process. To this purpose a series of VB tars, produced from a single feedstock at different severities, were investigated by a number of spectroscopic techniques, viz.: NIR; UV-Vis; Fluorescence; {sup 1}H and {sup 13}C NUR, EPR.

  16. Heavy and tar sand oil deposits of Europe

    SciTech Connect

    Cornelius, C.D.

    1984-09-01

    Several hundred heavy and extra-heavy oil and natural bitumen occurrences from 26 European countries (including European Turkey and the western borderlands of the USSR) were compiled. The definitions used for heavy crude oils and natural bitumens, as proposed by or prepared with the UNITAR/UNDP information center, were applied. Information on stratigraphy, lithology, and depth as well as on gravity, viscosity, and gas and water content, is given. Deposits are characteristically distributed along the flanks of the basins or within the separating uplifts. Nevertheless, they are found from the surface down to depths of 3000 m (9800 ft). Up to now, big accumulations have been exploited in Albania and Sicily, but they have been discovered also in the British North Sea, France, Spain, and West Germany. In carbonates, they were mostly encountered in fractures of synsedimentary or tectonic origin. The accumulations are the result of either intrusion of immature heavy oil from a source rock or of the immigration of mature oil, which was biodegraded afterward. In many cases, there have been at least two separate migration/accumulation events. In some cases paleoseepages did supply a source rock with asphaltic material or became an effective seal of a later hydrocarbon accumulation.

  17. Method for treating tar sands emulsion and apparatus therefor

    SciTech Connect

    Bialek, R.F.

    1986-04-15

    A method is described for resolving a hot bitumen emulsion comprised primarily of bitumen, water and chemical diluents. The method consists of: providing separate but communicated emulsion mixing, and emulsion settling chamber, passing the hot bitumen emulsion through a first elongated mixing passage in the mixing chamber wherein a rapidly flowing stream of recycled emulsion is combined with a minor portion of unrecycled bitumen emulsion, to form a combined bitumen emulsion stream, thereafter passing the combined bitumen emulsion stream into an elongated discontinuous mixing passage comprised of vertically arranged and interconnected mixing passages within the emulsion mixer, where in the combined bitumen emulsion stream passes at a slower rate than in the first elongated mixing passage, passing the combined bitumen emulsion stream into an overflow passage communicated with the second elongated mixing passage, introducing a part of the combined emulsion stream from the overflow passage into the emulsion settling chamber, recycling the remainder of the combined emulsion stream from the overflow passage into the first elongated mixing passage, and removing separated flows of bitumen and water from the settling chamber.

  18. Hydrogeology of formation waters, northwestern Alberta basin

    SciTech Connect

    Bachu, S.; Underschultz, J.R. )

    1993-10-01

    Generally, temperature seems to be the main controlling factor on salinity distributions. The salinity of formation waters increases in the vicinity of evaporitic beds, and decreases close to the surface because of mixing with fresh meteoric water introduced through local flow systems. The Lower and Middle Devonian pre-Prairie aquifer systems, beneath the regionally extensive Prairie aquiclude, are characterized by regional topographically-driven flow updip to the northeast. The flow of formation waters in the northeastern Alberta played an important role in the formation of the huge Athabasca oil sands deposits. Hydrocarbons that migrated into the area from the west were trapped into local reservoirs, and biodegraded and washed by fresh meteoric water introduced by local flow systems. Environmentally, the subsurface hydrogeology in the area imposes specific constraints on waste disposal in deep formations mostly because of the absence of a thick, continuous regional aquitard and because most aquifers subcrop at shallow depth or crop out and discharge along the valleys of the Athabasca River system and at the basin edge.

  19. Tar loads on Omani beaches

    SciTech Connect

    Badawy, M.I.; Al-Harthy, F.T. )

    1991-11-01

    Owing to Oman's geographic position and long coastal line, the coastal areas of Oman are particularly vulnerable to oil pollution from normal tanker operations, illegal discharges, and accidental spills as well as local sources of oil input. UNEP carried out a survey on the coasts of Oman to determine the major sources of oil pollution and concluded that the major shoreline pollution problems in Oman arose from operational discharges of oil from passing vessels traffic. The oil, because of the high sea and air temperatures in the area, was subjected to relatively high rates of evaporation and photo-oxidation and tended to arrive at the coast as heavy petroleum particulate residues (tar balls). The aim of the present study was to measure the loads of tar balls in Omani coastal areas and to identify the source of oil pollutants on beaches.

  20. Process for hydrogenation of hydrocarbon tars

    DOEpatents

    Dolbear, Geoffrey E.

    1978-07-18

    Hydrocarbon tars of high asphaltene content such as tars obtained from pyrolysis of coal are dissolved in a solvent formed from the hydrogenation of the coal tars, and the resultant mixture hydrogenated in the presence of a catalyst at a pressure from about 1500 to 5000 psig at a temperature from about 500.degree. F to about the critical temperature of the solvent to form a light hydrocarbon as a solvent for the tars. Hydrogen content is at least three times the amount of hydrogen consumed.

  1. A Study of Private Schools in Alberta.

    ERIC Educational Resources Information Center

    Alberta Dept. of Education, Edmonton. Planning Services Branch.

    This study was commissioned by Alberta Education to examine the development and organization of private schools in Alberta and to consider future directions. It examines the financial issues related to private schools, the effect of private schools on public school systems and on the education of children, and implications for public school…

  2. The American Imprint on Alberta Politics

    ERIC Educational Resources Information Center

    Wiseman, Nelson

    2011-01-01

    Characteristics assigned to America's classical liberal ideology--rugged individualism, market capitalism, egalitarianism in the sense of equality of opportunity, and fierce hostility toward centralized federalism and socialism--are particularly appropriate for fathoming Alberta's political culture. The author contends that Alberta's early…

  3. Inclusion's Confusion in Alberta

    ERIC Educational Resources Information Center

    Gilham, Chris; Williamson, W. John

    2014-01-01

    This hermeneutic paper interprets a recent series of reforms to inclusive education policy undertaken by the ministry of education in the province of Alberta, Canada. A 2007 Alberta Education review of the 16,000 student files in the province that school boards had claimed met the criteria for severe disability codification status -- the level of…

  4. Alberta Associations for Bright Children Members' Handbook.

    ERIC Educational Resources Information Center

    Alberta Association for Bright Children, Edmonton.

    This handbook is designed to provide information to parents of gifted children in Alberta, Canada. The handbook outlines the mission and objectives of the Alberta Associations for Bright Children and describes the structure of the non-profit organization. The booklet then addresses: (1) the characteristics of gifted children; (2) the rights of…

  5. Petrophysical Analysis of Oil Sand in Athabasca

    NASA Astrophysics Data System (ADS)

    cheong, S.; Lee, H.

    2013-12-01

    Oil sands are the major unconventional energy sources which have great reserves in Alberta, Canada. Recovery techniques such as CSS (Cyclic Steam Stimulation) and SAGD (Steam Assisted Gravity Drainage) enabled to develop deeper bitumen about several hundred meter depth. Before applying CSS and SAGD, reservoir heterogeneity of mud barriers or shale breccias should be clarified to establish injection and production wells successfully. We conducted the integrated petro-physical analysis for oil sands deposits in Athabasca by correlating well logs with seismic data. From 33 well logs and 3D seismic, we have made P-wave impedance by recursive inversion. Target formations of our analysis were the top of Wabiskaw member. Using inverted impedance and multi-attributes, porosity volume was derived at a target depth. Porosity of time slice 375 ms ranged 20 ~ 40 % stretching porous sand body from NE to SW direction. Characteristics of porosity distribution may be useful to design optimum oil sands recovery in Athabasca.

  6. TARS-HT1 and TARS-HT2 heat-tolerant dry bean germplasm

    Technology Transfer Automated Retrieval System (TEKTRAN)

    TARS-HT1 (Reg no. __, PI ___) and TARS-HT2 (Reg no. __, PI ___) are heat tolerant dark red and light red, respectively, kidney beans (Phaseolus vulgaris L.) developed cooperatively by the USDA-ARS Tropical Agriculture Research Station (TARS), the University of Puerto Rico, Cornell University, and th...

  7. Ground-level ozone in Alberta

    SciTech Connect

    Sandhu, H.S.

    1999-11-01

    This literature review on ground-level ozone in Alberta begins with introductory sections on the precursors and products of ozone formation, the chemistry and meteorology of ozone, and atmospheric ozone models. The subsequent section reviews ozone data from ambient air quality monitoring stations in Alberta. The final section discusses trends in ozone concentrations in urban and rural areas of Alberta, human and environmental health effects of ozone, proposed national ambient objectives and Canada-wide standards for ground-level ozone, and options for an ozone concentration standard for Alberta. Appendices include an outline of air pollutant monitoring methods used in Alberta, lists of monitoring stations, and tables of monitoring results for nitrogen oxides, total hydrocarbons, and volatile organic compounds at Calgary and Edmonton sites.

  8. Ground-level ozone in Alberta

    SciTech Connect

    Sandhu, H.S.

    1999-01-01

    This literature review on ground-level ozone in Alberta begins with introductory sections on the precursors and products of ozone formation, the chemistry and meteorology of ozone, and atmospheric ozone models. The subsequent section reviews ozone data from ambient air quality monitoring stations in Alberta. The final section discusses trends in ozone concentrations in urban and rural areas of Alberta, human and environmental health effects of ozone, proposed national ambient objectives and Canada-wide standards for ground-level ozone, and options for an ozone concentration standard for Alberta. Appendices include an outline of air pollutant monitoring methods used in Alberta, lists of monitoring stations, and tables of monitoring results for nitrogen oxides, total hydrocarbons, and volatile organic compounds at Calgary and Edmonton sites.

  9. Sydney Tar Ponds Remediation: Experience to China

    ERIC Educational Resources Information Center

    Liu, Fan; Bryson, Ken A.

    2009-01-01

    The infamous "Sydney Tar Ponds" are well known as one of the largest toxic waste sites of Canada, due to almost 100 years of steelmaking in Sydney, a once beautiful and peaceful city located on the east side of Cape Breton Island, Nova Scotia. This article begins with a contextual overview of the Tar Ponds issue including a brief introduction and…

  10. Receptor Modeling of Epiphytic Lichens to Elucidate the Sources and SpatialDistribution of Inorganic Air Pollution in the Athabasca Oil Sands Region

    EPA Science Inventory

    The contribution of inorganic air pollutant emissions to atmospheric deposition in the Athabasca Oil Sands Region (AOSR) of Alberta, Canada was investigated in the surrounding boreal forests, using a common epiphytic lichen bio-indicator species (Hypogymnia physodes) and applyi...

  11. Alberta's Acute Care Funding Project.

    PubMed

    Jacobs, P; Hall, E M; Lave, J R; Glendining, M

    1992-01-01

    Alberta initiated the Acute Care Funding Project (ACFP) in 1988, a new hospital funding system that institutes case mix budgeting adjustments to the global budget so that hospitals can be treated more equitably. The initiative is a significant departure in principle from the former method of funding. The ACFP is summarized and critiqued, and focuses on the inpatient side of the picture. The various elements of the project are discussed, such as the hospital performance index, the hospital performance measure, the Refined Diagnostic Related Group, case weights, typical and outlier cases, and the costing mechanisms. Since its implementation, the ACFP has undergone substantial changes; these are discussed, as well as some of the problems that still need to be addressed. Overall, the system offers incentives to reduce length of stay and to increase the efficiency with which inpatient care is provided. PMID:10121446

  12. Alberta Education's Clearinghouse: Functions and Findings.

    ERIC Educational Resources Information Center

    Wighton, David

    1984-01-01

    Discusses functions of the Alberta (Canada) Computer Technology Project's courseware clearinghouse, reviews findings on instructional software quality, identifies software development trends, and discusses need for support systems to facilitate the incorporation of computer assisted instruction in Canadian schools. (MBR)

  13. Sands-on Learning.

    ERIC Educational Resources Information Center

    Vandervoort, Frances S.

    1989-01-01

    Provides information for the development of a lesson which teaches students about sand, discusses facts about sands, sand studies, life in the sands, and sand activities. Includes diagrams showing the range in sand grain shape, formation of sand ripples, and sand samples from around the world. (RT)

  14. Coal liquefaction with coal tar solvent

    SciTech Connect

    Gir, S.; Rhodes, D.E.

    1986-12-16

    A method is described of liquefying coal, comprising: mixing solid coal with a process solvent comprising coal tar material which has been at least partially hydrogenated under conditions which selectively hydrogenate aromatic coal tar components to hydroaromatics and which preserve the integrity of organonitrogen coal tar components, to produce a coal-solvent slurry; treating the coal-solvent slurry under coal-liquefying conditions in a liquefaction zone to produce a solution containing coal liquefaction products; and recovering coal liquefaction products from the solution.

  15. Evaluation of LISBON TAR SSR radar

    NASA Astrophysics Data System (ADS)

    Fuller, I.

    1987-04-01

    The evaluation was carried out to investigate the TAR SSR performance with various combinations of antenna tilt, transmitter power and PRF in order to determine an optimum solution for TMA and long range detection performance with minimum false alarm rate. The evaluation was carried out in two stages: (1) on site visual evaluation of individual targets on the TAR SSR for each configuration, concurrently recordings were made of plots and local track data for TAR, MONTE JUNTO and FOIA, and (2) evaluation of the recordings using LAURENCE chain of program at EEC for probability of detection, plot reliability. The EEC note presents the results of both stages of the evaluation for selected configurations of the TAR SSR.

  16. Time scales of organic contaminant dissolution from complex source zones: coal tar pools vs. blobs

    NASA Astrophysics Data System (ADS)

    Eberhardt, Christina; Grathwohl, Peter

    2002-11-01

    Groundwater contamination due to complex organic mixtures such as coal tar, creosote and fuels is a widespread problem in industrialized regions. Although most compounds in these mixtures are biodegradable, the contaminant sources are very persistent for many decades after the contamination occurred (e.g., more than 100 years ago at gasworks sites). This limited bioavailability is due to slow dissolution processes. This study presents results from a large scale tank experiment (8 m long) on the long-term (354 days) dissolution kinetics of BTEX and PAHs from a 2.5 m long coal tar pool and 0.5 m long (smear) zone containing coal tar blobs distributed in a coarse sand. The results indicate (1) that Raoult's law holds for estimation of the saturation aqueous concentrations of the coal tar constituents, (2) that for the dissolution of smear zones longer than approximately 0.1 m and with more than 3-5% residual saturation, the local equilibrium assumption is valid and (3) that although very small (<0.1 mm), the transverse vertical dispersivity dominates the pool dissolution processes. Typical time scales for removal of the pollutants from the blob zone and the pool are in the order of a few weeks to more than 10,000 years, respectively.

  17. Time scales of organic contaminant dissolution from complex source zones: coal tar pools vs. blobs.

    PubMed

    Eberhardt, Christina; Grathwohl, Peter

    2002-11-01

    Groundwater contamination due to complex organic mixtures such as coal tar, creosote and fuels is a widespread problem in industrialized regions. Although most compounds in these mixtures are biodegradable, the contaminant sources are very persistent for many decades after the contamination occurred (e.g., more than 100 years ago at gasworks sites). This limited bioavailability is due to slow dissolution processes. This study presents results from a large scale tank experiment (8 m long) on the long-term (354 days) dissolution kinetics of BTEX and PAHs from a 2.5 m long coal tar pool and 0.5 m long (smear) zone containing coal tar blobs distributed in a coarse sand. The results inidicate (1) that Raoult's law holds for estimation of the saturation aqueous concentrations of the coal tar constituents, (2) that for the dissolution of smear zones longer than approximately 0.1 m and with more than 3-5% residual saturation, the local equilibrium assumption is valid and (3) that although very small (< 0.1 mm), the transverse vertical dispersivity dominates the pool dissolution processes. Typical time scales for removal of the pollutants from the blob zone and the pool are in the order of a few weeks to more than 10,000 years, respectively. PMID:12683639

  18. High numbers of Vibrio vulnificus in tar balls collected from oiled areas of the north-central Gulf of Mexico following the 2010 BP Deepwater Horizon oil spill.

    PubMed

    Tao, Zhen; Bullard, Stephen; Arias, Covadonga

    2011-12-01

    The Deepwater Horizon Oil Spill was the largest oil spill in USA history releasing approximately 4.9 million barrels of crude oil into the Gulf of Mexico. Soon after the spill started, tar balls and other forms of weathered oil appeared in large numbers on beaches in Mississippi and Alabama. In this study, we analyzed tar balls for total aerobic bacterial (TAB) counts and also for the presence of Vibrio vulnificus, a human pathogen known to be abundant in the Gulf Coast environment and capable of causing severe wound infections by contact with contaminated surfaces. Our results showed that TAB counts were significantly higher in tar balls than in sand and seawater collected at the same location. In addition, V. vulnificus numbers were 10× higher in tar balls than in sand and up to 100× higher than in seawater. Densities of V. vulnificus were higher than 10(5) colony forming units/g of tar ball in all samples analyzed. Our data suggest that tar balls can act as reservoirs for bacteria including human pathogens. PMID:22109669

  19. Sedimentology, diagenesis, and trapping style, Chesterian Tar Springs sandstone at Inman Field, Gallatin County, Illinois

    SciTech Connect

    Morse, D.G.

    1996-09-01

    The Tar Springs Sandstone in southern Illinois is often over-looked as a pay, yet it can be a prolific producer. The Inman Field, discovered in 1940, produces from several cyclic Chesterian sandstones from structural-stratigraphic traps in the Wabash Valley Fault System of southeastern Illinois. The oil was sourced from the Devonian New Albany Shale and apparently migrated vertically along the Wabash Valley faults to its present location, thus charging many of the Chesterian and lower Pennsylvanian sands in the field. The Tar Springs Sandstone produces from stacked distributary channel sand reservoirs up to 125 feet thick which have cut up to 40 feet into laterally equivalent non-reservoir, delta-fringe facies and the underlying Glen Dean Limestone. The reservoir sands are well-sorted, fine- to medium-grained quartz arenites with less than 5% feldspar and chert. Quartz grains have quartz overgrowths. Feldspar grains are clouded in thin-section and show pronounced etching and dissolution in SEM. Diagenetic kaolinite and small amounts of illite and magnesium-rich chlorite occur in intergranular pores. Sparry, iron-rich dolomite or ankerite that fills pores in irregular millimeter-size patches, occupies up to 10% of the reservoir rock. Typical reservoir porosity ranges from 16 to 19 percent and permeability ranges from 60 to 700 md. By contrast non-reservoir delta-fringe sands typically have porosities of 6 to 12 percent and permeabilities of 1 to 20 md. Delta-fringe Tar Springs shales act as impermeable lateral and vertical seals, aiding in stratigraphic trapping.

  20. Alberta Advanced Education Annual Report 2005-06

    ERIC Educational Resources Information Center

    Alberta Advanced Education, 2006

    2006-01-01

    The Public Accounts of Alberta are prepared in accordance with the Financial Administration Act and the "Government Accountability Act." The Public Accounts consist of the annual report of the Government of Alberta and the annual reports of each of the 24 ministries. The annual report of the Government of Alberta released June 26, 2006 contains…

  1. An assessment of high and low temperature tars in Psoriasis.

    PubMed

    Chapman, R S; Finn, O A

    1976-01-01

    Comparison of the efficacy of crude coal tar from high and low temperature sources in the treatment of patients suffering from chronic psoriasis showed the tars to be equally effective. High temperature tar was then compared with standard refined tar. Again, an equal therapeutic response was achieved. Crude coal tars obtained by the carbonization of coal in coke ovens and in smokeless fuel manufacture can be employed in dermatological therapy in place of the dwindling supplies of crude tar of gasworks origin. PMID:1252342

  2. Pulse Dipolar ESR of Doubly Labeled Mini TAR DNA and Its Annealing to Mini TAR RNA

    PubMed Central

    Sun, Yan; Borbat, Peter P.; Grigoryants, Vladimir M.; Myers, William K.; Freed, Jack H.; Scholes, Charles P.

    2015-01-01

    Pulse dipolar electron-spin resonance in the form of double electron electron resonance was applied to strategically placed, site-specifically attached pairs of nitroxide spin labels to monitor changes in the mini TAR DNA stem-loop structure brought on by the HIV-1 nucleocapsid protein NCp7. The biophysical structural evidence was at Ångstrom-level resolution under solution conditions not amenable to crystallography or NMR. In the absence of complementary TAR RNA, double labels located in both the upper and the lower stem of mini TAR DNA showed in the presence of NCp7 a broadened distance distribution between the points of attachment, and there was evidence for several conformers. Next, when equimolar amounts of mini TAR DNA and complementary mini TAR RNA were present, NCp7 enhanced the annealing of their stem-loop structures to form duplex DNA-RNA. When duplex TAR DNA-TAR RNA formed, double labels initially located 27.5 Å apart at the 3′- and 5′-termini of the 27-base mini TAR DNA relocated to opposite ends of a 27 bp RNA-DNA duplex with 76.5 Å between labels, a distance which was consistent with the distance between the two labels in a thermally annealed 27-bp TAR DNA-TAR RNA duplex. Different sets of double labels initially located 26–27 Å apart in the mini TAR DNA upper stem, appropriately altered their interlabel distance to ∼35 Å when a 27 bp TAR DNA-TAR RNA duplex formed, where the formation was caused either through NCp7-induced annealing or by thermal annealing. In summary, clear structural evidence was obtained for the fraying and destabilization brought on by NCp7 in its biochemical function as an annealing agent and for the detailed structural change from stem-loop to duplex RNA-DNA when complementary RNA was present. PMID:25692594

  3. Higher temperature coal tar enamel fights corrosion

    SciTech Connect

    Johnson, J.R.; Henegar, S.; Roder, B.

    1996-10-01

    High temperatures create new challenges for pipeline coatings. Cracking, adhesion breakdown and electrochemical corrosion are accelerated by higher service temperatures. A new epoxy primer/coal tar pipeline coating system utilizes the latent heat of the coal tar application to fully cure the newly developed primer to achieve outstanding bonding integrity and high temperature cathodic disbondment resistance. A key reason for this overall high performance is the marriage of a newly developed epoxy primer that provides outstanding adhesion with coal tar enamel, which provides excellent long-term water resistance. The paper describes experimental studies, pilot plant application, cathodic disbondment testing, and results from hot water soak tests and the low temperature cracking test.

  4. Tar Management and Recycling in Biomass Gasification and Syngas Purification

    NASA Astrophysics Data System (ADS)

    McCaffrey, Zach

    Removal of tars is critical to the design and operation of biomass gasification systems as most syngas utilization processing equipment (e.g. internal combustion engines, gas turbines, fuel cells, and liquid fuel synthesis reactors) have a low tolerance for tar. Capturing and disposal of tar is expensive due to equipment costs, high hazardous waste disposal costs where direct uses cannot be found, and system energy losses incurred. Water scrubbing is an existing technique commonly used in gasification plants to remove contaminants and tar; however using water as the absorbent is non-ideal as tar compounds have low or no water solubility. Hydrophobic solvents can improve scrubber performance and this study evaluated tar solubility in selected solvents using slip-streams of untreated syngas from a laboratory fluidized bed reactor operated on almond composite feedstock using both air and steam gasification. Tar solubility was compared with Hansen's solubility theory to examine the extent to which the tar removal can be predicted. As collection of tar without utilization leads to a hazardous waste problem, the study investigated the effects of recycling tars back into the gasifier for destruction. Prior to experiments conducted on tar capture and recycle, characterizations of the air and steam gasification of the almond composite mix were made. This work aims to provide a better understanding of tar collection and solvent selection for wet scrubbers, and to provide information for designing improved tar management systems for biomass gasification.

  5. Integration of High Temperature Gas-cooled Reactor Technology with Oil Sands Processes

    SciTech Connect

    L.E. Demick

    2011-10-01

    This paper summarizes an evaluation of siting an HTGR plant in a remote area supplying steam, electricity and high temperature gas for recovery and upgrading of unconventional crude oil from oil sands. The area selected for this evaluation is the Alberta Canada oil sands. This is a very fertile and active area for bitumen recovery and upgrading with significant quantities piped to refineries in Canada and the U.S Additionally data on the energy consumption and other factors that are required to complete the evaluation of HTGR application is readily available in the public domain. There is also interest by the Alberta oil sands producers (OSP) in identifying alternative energy sources for their operations. It should be noted, however, that the results of this evaluation could be applied to any similar oil sands area.

  6. Defrosting Sand

    NASA Technical Reports Server (NTRS)

    2005-01-01

    19 June 2005 This Mars Global Surveyor (MGS) Mars Orbiter Camera (MOC) image shows dark spots formed in carbon dioxide frost that covers the surfaces of patches of sand in the south polar region. As spring arrived this year in the martian southern hemisphere, so began the annual defrosting process. The fact that sand dunes begin to defrost earlier than other surfaces, and that the defrosting process involves the formation of spots like these, has been known since the earliest days of the MGS mission.

    Location near: 66.8oS, 15.7oW Image width: 3 km (1.9 mi) Illumination from: upper left Season: Southern Spring

  7. Pandemic Planning Guide for Alberta School Authorities

    ERIC Educational Resources Information Center

    Alberta Education, 2008

    2008-01-01

    A crisis always seems like something that happens somewhere else - that is, until it arrives on your doorstep. Although other issues and challenges scream for your attention, School Authorities should not postpone developing an influenza pandemic plan. The "Pandemic Planning Guide for Alberta School Authorities" (the "Guide") is designed to assist…

  8. Assessment in Alberta: Six Areas of Concern

    ERIC Educational Resources Information Center

    Aitken, Nola; Webber, Charles F.; Lupart, Judy; Scott, Shelleyann; Runte, Robert

    2011-01-01

    This report on the Alberta Student Assessment Study describes the context, methodology, and emergent themes. It outlines the purposes and uses of assessment according to the various stakeholder groups. Using both qualitative and quantitative data from students and parents, as well as educators at all levels, there were six areas or themes that…

  9. Echinococcus multilocularis in Urban Coyotes, Alberta, Canada

    PubMed Central

    Catalano, Stefano; Lejeune, Manigandan; Liccioli, Stefano; Verocai, Guilherme G.; Gesy, Karen M.; Jenkins, Emily J.; Kutz, Susan J.; Fuentealba, Carmen; Duignan, Padraig J.

    2012-01-01

    Echinococcus multilocularis is a zoonotic parasite in wild canids. We determined its frequency in urban coyotes (Canis latrans) in Alberta, Canada. We detected E. multilocularis in 23 of 91 coyotes in this region. This parasite is a public health concern throughout the Northern Hemisphere, partly because of increased urbanization of wild canids. PMID:23017505

  10. Senior Executive Views on Education in Alberta.

    ERIC Educational Resources Information Center

    Meanwell, Richard J.; Barrington, Gail V.

    Interviews were conducted with 60 senior executives in the private sector to determine the strengths and weaknesses of the education system in Alberta, Canada from their perspective. The executives' views were solicited on the following topics: (1) current strengths of the education system; (2) necessary improvements in educational programs and…

  11. A Guide to Native Organizations in Alberta.

    ERIC Educational Resources Information Center

    Alberta Dept. of Native Affairs, Edmonton.

    Names, addresses, names of directors, and telephone numbers for 182 organizations formed by or serving Canada Natives in Alberta are presented, grouped by their area of interest. Listed are 17 arts and crafts organizations, 10 business and employment development services, 8 radio stations and newspapers, 12 cultural groups, 19 educational…

  12. Epizootic hemorrhagic disease in Alberta, Canada.

    PubMed

    Pybus, Margo J; Ravi, Madhu; Pollock, Colleen

    2014-07-01

    Epizootic hemorrhagic disease (EHD) virus serotype 2 was identified by reverse-transcription (RT)-PCR in a white-tailed deer (Odocoileus virginianus) found dead in southern Alberta in September 2013. Field observations indicate at least 50 deer, primarily white-tailed deer, and three pronghorn antelope (Antilocapra americana) died during a suspected localized EHD outbreak. PMID:24807363

  13. Education in Alberta: Facts and Figures, 1989.

    ERIC Educational Resources Information Center

    Alberta Dept. of Education, Edmonton.

    A statistical overview of the educational system in Alberta (Canada) for 1989 is presented. The report includes data and analyses concerning demographics; family and social structure; economy and workforce; early childhood services enrollments and projections; public and separate school enrollments and projections; private school enrollments;…

  14. Alberta Catholic Schools...A Social History.

    ERIC Educational Resources Information Center

    Tkach, Nicholas

    The purposes of this book are to trace the influence of major social forces on the Alberta, Canada, public and Catholic school systems and to detail the evolution of these two systems. Beginning with a review of "The First People" of the Northwest Territories, chapter I examines political, economic, and sociocultural developments and their impact…

  15. Spaceborne Methane Observations by Airs Over Alberta

    NASA Astrophysics Data System (ADS)

    Marey, H. S.; Hashisho, Z., Sr.; Fu, L.; Gille, J. C.; Chance, K.

    2015-12-01

    Methane (CH4) emitted from natural (e.g. wetland) and anthropogenic (e.g. oil and gas industry, and waste management) sources contribute to Alberta's GHG emission. The focus of this study is to examine the spatio-temporal variation of total column CH4 over Alberta, using data from the Atmospheric Infrared Sounder (AIRS) on the EOS/Aqua satellite from 2003 to 2013. Spaceborne measurements by AIRS provide a global view of CH4 distribution in the mid-upper troposphere. This study demonstrates a significant rise of CH4 levels in Alberta in the last ten years. This ascending trend is consistent with the increase of global methane levels in the same time period. Monthly variations indicate a significant increase of CH4 levels in summer with maximum in August, which is probably driven by enhanced convection. Spatial distributions of CH4 reveal a strong west-east gradient with maximum levels in northern regions (55-65 N). The enhanced summer levels over northern and eastern regions suggest possible pathways for CH4 emitted from natural sources (wetlands, lakes and permafrost) in high northern latitude regions and Canadian wetlands (e.g. Hudson Bay wetland). However, the abrupt increase of CH4 concentration coincides with significant change in economic activities during that time period. Since some of the wetland CH4 fluxes are collocated with large anthropogenic source, it is difficult to account for different source contribution. Thus, further studies about CH4 emission and transport over Alberta are recommended to reduce the uncertainties about the natural and anthropogenic contributions of Alberta to Canada's CH4 emissions.

  16. Method for Extraction and Multielement Analysis of Hypogymnia Physodes Samples from the Athabasca Oil Sands Region

    EPA Science Inventory

    A microwave-assisted digestion technique followed by ICPMS (inductively coupled plasma-mass spectrometry) analysis was used to measure concentrations of 43 elements in Hypogymnia physodes samples collected in the Athabasca Oil Sands Region (AOSR) of northern Alberta, Canad...

  17. 40 CFR 721.10532 - Tar, brown coal.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Tar, brown coal. 721.10532 Section 721... Tar, brown coal. (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified as tar, brown coal (PMN P-12-167, CAS No. 101316-83-0) is subject...

  18. 40 CFR 721.10532 - Tar, brown coal.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 32 2013-07-01 2013-07-01 false Tar, brown coal. 721.10532 Section 721... Tar, brown coal. (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified as tar, brown coal (PMN P-12-167, CAS No. 101316-83-0) is subject...

  19. Coal tar analysis by LC/MS

    SciTech Connect

    Herod, A.A.; Ladner, W.R.; Stokes, B.J.; Berry, A.J.; Games, D.E.

    1986-04-01

    The application of LC/MS to the analysis of an aromatic fraction of a hydropyrolysis tar is described. The results are compared with those obtained by GC/MS, low eV probe mass spectrometry and field desorption mass spectrometry.

  20. Spatial and temporal variation of CO over Alberta using measurements from satellite, aircrafts, and ground stations

    NASA Astrophysics Data System (ADS)

    Marey, H. S.; Hashisho, Z.; Fu, L.; Gille, J.

    2014-12-01

    Alberta is Canada's largest oil producer and its oil sand deposits comprise 30% of the world's oil reserves. The process of bitumen extraction and upgrading releases trace gases and aerosols to the atmosphere. In this study we present satellite-based analysis to explore, for the first time, various contributing factors that affect tropospheric carbon monoxide (CO) levels over Alberta. The multispectral product that uses both near-infrared (NIR) and the thermal-infrared (TIR) radiances for CO retrieval from the Measurements of Pollution in the Troposphere (MOPITT) are examined for the 12 year period from 2002-2013. Moderate Resolution Imaging Spectroradiometer (MODIS) thermal anomaly product from 2001 to 2013 is employed to investigate the seasonal and temporal variations of forest fires. Additionally, in situ CO measurements at industrial and urban sites are compared to satellite data. Furthermore, the available MOZAIC/IAGOS (Measurement of Ozone, Water Vapor, Carbon Monoxide, Nitrogen Oxide by Airbus In-Service Aircraft/In service Aircraft for Global Observing System) aircraft CO profiles (April 2009-December 2011) are used to validate MOPITT CO data. The climatological time curtain plot and spatial maps for CO over northern Alberta indicate the signatures of transported CO for two distinct biomass burning seasons, summer and spring. Distinct seasonal patterns of CO at the urban site s (Edmonton and Calgary cities) point to the strong influence of traffic. Meteorological parameters play an important role on the CO spatial distribution at various pressure levels. Northern Alberta shows stronger upward lifting motion which leads to larger CO total column values while the poor dispersion in central and south Alberta exacerbates the surface CO pollution. Inter-annual variations of satellite data depict a slightly decreasing trend for both regions while the decline trend is more evident from ground observations, especially at the urban sites. MOPITT CO vertical

  1. Spatial and temporal variation in CO over Alberta using measurements from satellites, aircraft, and ground stations

    NASA Astrophysics Data System (ADS)

    Marey, H. S.; Hashisho, Z.; Fu, L.; Gille, J.

    2015-04-01

    Alberta is Canada's largest oil producer, and its oil sands deposits comprise 30% of the world's oil reserves. The process of bitumen extraction and upgrading releases trace gases and aerosols to the atmosphere. In this study we present satellite-based analysis to explore, for the first time, various contributing factors that affect tropospheric carbon monoxide (CO) levels over Alberta. The multispectral product that uses both near-infrared (NIR) and the thermal-infrared (TIR) radiances for CO retrieval from the Measurements of Pollution in the Troposphere (MOPITT) is examined for the 12-year period from 2002 to 2013. The Moderate Resolution Imaging Spectroradiometer (MODIS) thermal anomaly product from 2001 to 2013 is employed to investigate the seasonal and temporal variations in forest fires. Additionally, in situ CO measurements at industrial and urban sites are compared to satellite data. Furthermore, the available MOZAIC/IAGOS (Measurement of Ozone, Water Vapor, Carbon Monoxide, Nitrogen Oxide by Airbus In-Service Aircraft/In service Aircraft for Global Observing System) aircraft CO profiles (April 2009-December 2011) are used to validate MOPITT CO data. The climatological time curtain plot and spatial maps for CO over northern Alberta indicate the signatures of transported CO for two distinct biomass burning seasons: summer and spring. Distinct seasonal patterns of CO at the urban sites (Edmonton and Calgary) point to the strong influence of traffic. Meteorological parameters play an important role in the CO spatial distribution at various pressure levels. Northern Alberta shows a stronger upward lifting motion which leads to larger CO total column values, while the poor dispersion in central and southern Alberta exacerbates the surface CO pollution. Interannual variations in satellite data depict a slightly decreasing trend for both regions, while the decline trend is more evident from ground observations, especially at the urban sites. MOPITT CO vertical

  2. Comparative anti-dandruff efficacy between a tar and a non-tar shampoo.

    PubMed

    Piérard-Franchimont, C; Piérard, G E; Vroome, V; Lin, G C; Appa, Y

    2000-01-01

    A randomized double-blind clinical study was conducted on two groups of 30 volunteers using either a non-tar shampoo (2% salicylic acid, 0.75% piroctone olamine and 0.5% elubiol) or a 0.5% coal tar shampoo. Subjects were diagnosed as having moderate to marked dandruff. The study consisted of a 3-week washout, followed by a 4-week treatment and a 4-week posttreatment regression phase. The clinical evaluations and subject self-assessments showed that the non-tar shampoo was as effective as the tar shampoo. Both received high approval ratings (> or =70%). Biometrological methods proved to be more sensitive than clinical evaluations to assess the efficacy of the shampoos. The non-tar shampoo yielded a significantly better reduction of Malassezia spp. counts (p<0.02) during the treatment phase and reduced the spontaneous increase in squamometry values (p< 0.01) during the posttreatment phase. It is concluded that a formulation associating salicylic acid, piroctone olamine and elubiol exhibited increased beneficial effects compared to the coal tar shampoo. PMID:10773717

  3. Information on tar and nicotine yields on cigarette packages.

    PubMed Central

    Davis, R M; Healy, P; Hawk, S A

    1990-01-01

    We examined information on tar and nicotine yields on the packages of 160 cigarette brands, 58 percent of the 275 brands for which tar and nicotine yields were listed in a recent Federal Trade Commission report. The tar yield was indicated on 14 percent, the nicotine yield was indicated on 11 percent. As tar yield increased among brands, the yield was progressively less likely to be shown on the package and was not disclosed on the package of any cigarette yielding 11 mg or more of tar. PMID:2327530

  4. Industrial sand and gravel

    USGS Publications Warehouse

    Dolley, T.P.

    2011-01-01

    Domestic production of industrial sand and gravel in 2010 was about 26.5 Mt (29.2 million st), a 6-percent increased from 2009. Certain end uses of industrial sand and gravel, such as sand for container glass, golf course sand, recreational sand, specialty glass and water filtration, showed increased demand in 2010.

  5. Atmospheric tar balls: aged primary droplets from biomass burning?

    NASA Astrophysics Data System (ADS)

    Tóth, A.; Hoffer, A.; Nyirő-Kósa, I.; Pósfai, M.; Gelencsér, A.

    2013-12-01

    Atmospheric tar balls are particles of special morphology and composition that are abundant in the plumes of biomass smoke. These particles form a specific subset of brown carbon (BrC) which has been shown to play a significant role in atmospheric shortwave absorption and thus climate forcing. Formerly tar balls were hypothesized to be formed in secondary processes in the atmosphere from lignin pyrolysis products. Based on their typical size distributions, morphology, chemical characteristics and other features we now suggest that tar balls are initially produced by the emission of primary tar droplets upon biomass burning. To verify our hypothesis tar balls were produced under laboratory conditions with the total exclusion of flame processes. An all-glass apparatus was designed and tar ball particles were generated from liquid tar obtained previously by dry distillation of wood. The size range, morphology and the chemical composition of the laboratory-generated tar ball particles were similar to those observed in biomass smoke plumes or elsewhere in the atmosphere. Based on our results and the chemical and physical characteristics of tar we suggest that tar balls can be formed by the chemical transformation of emitted primary tar droplets.

  6. Investigation of coal tar mobility at a former MGP site

    SciTech Connect

    Moo-Young, H.K.; Mo, X.H.; Waterman, R.; Coleman, A.; Saroff, S.

    2009-11-15

    The presence of coal tar in the subsurface of former manufactured gas plant sites poses an environmental hazard and a potential threat to public health. Coal tar can release various chemical compounds that are transported into the groundwater. Before any efforts can be made to remove coal tar from contaminated subsurface soils, it is recommended to characterize coal tar properties and composition and to delineate the residual saturation point between mobile and immobile coal tar. This paper presents a new innovative field device, the Res-SAT field tool, and laboratory procedures that can be used to determine the saturation-capillary pressure relationship for a soil-water coal-tar system and the critical pressure for coal tar mobility.

  7. Sand Diver

    NASA Astrophysics Data System (ADS)

    Scott, Alan J.

    2005-01-01

    A few years ago, I was preparing to teach a summer enrichment program for middle school students at the University of Wisconsin-Stout. With swimming on the minds of most kids during the summer, I thought buoyancy would be a fun topic to discuss. An interesting way to introduce this concept is by discussing the beer-drinking balloonist who, in a lawn chair, floated to 11,000 feet above Los Angeles in 1997. However, I needed a hands-on project and was not about to go purchase some lawn chairs to duplicate this experiment. A simple submersible called the "Sand Diver" was designed and is now used as a hands-on activity for my introductory physics course.

  8. Fire, Aim… Ready? Alberta's Big Bang Approach to Healthcare Disintegration.

    PubMed

    Donaldson, Cam

    2010-08-01

    Alberta's abolition in 2008 of its health regions and the creation of Alberta Health Services (AHS) was a bold move, but the reasons for the change remain hazy. The stated goals were to "help make Alberta's … system more effective and efficient" and to "provide equitable access to health services and long-term sustainability." Data show, however, that Alberta's health regions were already performing well on these goals relative to other provinces, and where changes have since occurred, they cannot necessarily be attributed to AHS. PMID:21804836

  9. Sand resistance of sunscreens.

    PubMed

    Caswell, Michael; Wood, Caryl; Martinez, Alexa

    2012-01-01

    Like water resistance in sunscreens, sand resistance in sunscreens is the ability of the sunscreen to retain its effectiveness while undergoing sand treatment. The influence of the type of sand on the sand resistance of sunscreens has not been described. The sand resistance of a control standard sunscreen, P2, and data on three grades of Quickrete commercial grade sand, #1961, #1962, and #1152, are described. These sands represent a fine sand, a medium sand, and an all-purpose sand. Using the methodology described in the 2007 proposed amendment of the Final Monograph (1) with one exception, we obtained an SPF of 16.5 (1.6) for the control standard, compared to the expected SPF of 16.3 (3.4). After a five-minute treatment of sand #1961, #1962, or #1151, the SPF of the control standard was 18.3 (1.6), 18.4 (2.0), and 17.5 (2.2), respectively. Thus, all three sands exhibited a similar sand-resistance response. Thus, there was no significant difference in the average SPF with and without sand. The medium grade sand, Quickrete commercial grade #1962, was preferred for sand-resistance testing because the fine sand was difficult to remove from the subject's backs and the coarse sand was unpleasant to the subjects. PMID:23193889

  10. Occupational exposure to crystalline silica at Alberta work sites.

    PubMed

    Radnoff, Diane; Todor, Maria S; Beach, Jeremy

    2014-01-01

    Although crystalline silica has been recognized as a health hazard for many years, it is still encountered in many work environments. Numerous studies have revealed an association between exposure to respirable crystalline silica and the development of silicosis and other lung diseases including lung cancer. Alberta Jobs, Skills, Training and Labour conducted a project to evaluate exposure to crystalline silica at a total of 40 work sites across 13 industries. Total airborne respirable dust and respirable crystalline silica concentrations were quite variable, but there was a potential to exceed the Alberta Occupational Exposure Limit (OEL) of 0.025 mg/m(3) for respirable crystalline silica at many of the work sites evaluated. The industries with the highest potentials for overexposure occurred in sand and mineral processing (GM 0.090 mg/m(3)), followed by new commercial building construction (GM 0.055 mg/m(3)), aggregate mining and crushing (GM 0.048 mg/m(3)), abrasive blasting (GM 0.027 mg/m(3)), and demolition (GM 0.027 mg/m(3)). For worker occupations, geometric mean exposure ranged from 0.105 mg/m(3) (brick layer/mason/concrete cutting) to 0.008 mg/m(3) (dispatcher/shipping, administration). Potential for GM exposure exceeding the OEL was identified in a number of occupations where it was not expected, such as electricians, carpenters and painters. These exposures were generally related to the specific task the worker was doing, or arose from incidental exposure from other activities at the work site. The results indicate that where there is a potential for activities producing airborne respirable crystalline silica, it is critical that the employer include all worker occupations at the work site in their hazard assessment. There appears to be a relationship between airborne total respirable dust concentration and total respirable dust concentrations, but further study is require to fully characterize this relationship. If this relationship holds true

  11. Evaluation of geothermal energy as a heat source for the oilsands industry in Northern Alberta (Canada)

    NASA Astrophysics Data System (ADS)

    Majorowicz, J. A.; Unsworth, M.; Gray, A.; Nieuwenhuis, G.; Babadagli, T.; Walsh, N.; Weides, S.; Verveda, R.

    2012-12-01

    energy to provide usable heat for oil sands processing can only be found within the crystalline basement rocks beneath the WCSB. Lower temperature geothermal resources can be found in the 2 km thick layer of sedimentary rocks in the Peace River area and beneath urban centres in Northern Alberta. Modeling shows that heat extraction for oilsands processing with a doublet or triplet of 5km wells, operated for 15 years, could be marginally economic when compared to the currently low gas prices. This type of heat extraction would be economically competitive if the system had a life span greater than 20 years or with higher natural gas prices.

  12. Subsurface Geophysical Characterization of the Crystalline Canadian Shield in NE Alberta: Implications to Geothermal Development

    NASA Astrophysics Data System (ADS)

    Chan, J.; Schmitt, D. R.; Lee, M. D.; Moeck, I. S.

    2013-12-01

    The availability of a deep borehole offers an unprecedented opportunity to correlate surface seismic data to borehole measurements in the metamorphic rocks of northeastern Alberta, Canada. As part of the feasibility study for the development of engineered geothermal systems (EGS) in Alberta under the Helmholtz-Alberta Initiative (HAI), this project provides a detailed subsurface characterization of the basement rocks by integrating the existing deep surface seismic profile with the borehole seismic and log measurements that were mostly acquired in July 2011. The purpose of geothermal energy research in Alberta is to implement alternative energy resources for water heating in oil sands processing toward minimizing greenhouse gas emissions in the province. Existing thermal gradient studies suggested that deep drilling into the crystalline basement rocks is needed to reach the desired temperature for the development of geothermal energy in northeastern Alberta. Crystalline basement rocks are known for their low porosity but the presence of highly-fractured rocks still provides an ideal environment for the development of any geothermal systems. As such, physical discontinuities including cracks, voids and joint systems, and major faults and fractures are features to target for geothermal exploration. The focus of this project is on identifying any geological features including zones of fractures in the basement rocks that could act as indicators of enhanced fluid potential - a necessary component for any geothermal systems to be viable. By integrating the results from a comprehensive suite of geophysical borehole logs, seismic reflection surveys, zero-offset and walk-away vertical seismic profiles, the final results provide useful information on the in-situ physical properties of the rocks, depths to fracture zones and seismic reflectors, types of fractures, stress directions, and the acoustic responses of rock properties. Significant P-wave velocity anisotropy is also

  13. Industrial sand and gravel

    USGS Publications Warehouse

    Dolley, T.P.

    2012-01-01

    Domestic production of industrial sand and gravel in 2011 was about 30 Mt (33 million st), increasing slightly compared with 2010. Some important end uses for industrial sand and gravel include abrasives, filtration, foundry, glassmaking, hydraulic fracturing sand (frac sand) and silicon metal applications.

  14. Industrial sand and gravel

    USGS Publications Warehouse

    Dolley, T.P.

    2013-01-01

    Domestic production of industrial sand and gravel in 2012 was about 49.5 Mt (55 million st), increasing 13 percent compared with that of 2011. Some important end uses for industrial sand and gravel include abrasives, filtration, foundry, glassmaking, hydraulic fracturing sand (frac sand) and silicon metal applications.

  15. Research Funding at Alberta Universities, 2000-2001 Report.

    ERIC Educational Resources Information Center

    Alberta Innovation and Science, Edmonton. University Research and Strategic Investments Branch.

    This report presents facts related to the funding of research at Alberta, Canada, universities. Data are provided by the universities, derived from audited financial schedules. Research at Alberta universities is supported in part by the provincial government through a number of programs. Sponsored research funding, funding received outside of…

  16. Research Funding at Alberta Universities. 2001/2002 Report.

    ERIC Educational Resources Information Center

    Alberta Innovation and Science, Edmonton. University Research and Strategic Investments Branch.

    This report summarizes sponsored research revenues at Alberta Universities. Sponsored research revenues are those that are received outside of regular university operating grant and include both research grants and research contracts. Research at Alberta universities is supported in part by the provincial government through a number of programs.…

  17. Learning and Technology in Alberta (1975 to 2009)

    ERIC Educational Resources Information Center

    Alberta Education, 2009

    2009-01-01

    Alberta's education system is a leader in the use of technology in teaching and learning. New information technologies create options for how teachers teach, how students learn, and how classrooms look and operate. This document chronicles the history of computer technology in Alberta from 1975-2009. The information is arranged in a tabulated…

  18. Circle of Courage Infusion into the Alberta Indigenous Games 2011

    ERIC Educational Resources Information Center

    Marchand, Dawn Marie

    2011-01-01

    Thousands of indigenous people from across North America came to the Enoch Cree Nation for the Alberta Indigenous Games, six days of sport, education, and cultural awakening. The vision of the Alberta Indigenous Games is to recognize the value and potential of Indigenous culture and the young people. Activities include sports, indigenous arts,…

  19. FOIPP and Technology Highlights: Best Practices for Alberta School Jurisdictions.

    ERIC Educational Resources Information Center

    Alberta Dept. of Education, Edmonton.

    The information in this document is based on a study that Alberta Education commissioned on establishing technology systems that are responsive to the requirements of Alberta's Freedom of Information and Protection of Privacy Act (FOIPP). This document provides an overview of key issues and suggested strategies in the following areas: (1)…

  20. A Learning Alberta: Dialogue and Direction. The Forum Background

    ERIC Educational Resources Information Center

    Alberta Advanced Education, 2005

    2005-01-01

    Participants in "A Learning Alberta--Dialogue and Direction," the Minister's Forum on Advanced Learning are an important part of a process that has been underway across Alberta since January of 2005. Led by the Honourable Dave Hancock, Minister of Advanced Education, a new vision and policy framework is being developed to guide future directions…

  1. A Retrospective Survey of Diseases of Feedlot Cattle in Alberta

    PubMed Central

    Church, T. L.; Radostits, O. M.

    1981-01-01

    A survey of feedlot managers was used to obtain information on disease occurrence, management practices and preventive techniques employed in feedlots in Alberta. Respiratory diseases were reported to be the most frequent causes of sickness and death. Costs associated with disease occurrence were estimated to be C $15.6 million in feedlots in Alberta annually during the period under study. PMID:7225993

  2. Education in Alberta: Some Major Societal Trends. Revised.

    ERIC Educational Resources Information Center

    Alberta Dept. of Education, Edmonton. Planning and Policy Secretariat.

    The major societal trends happening in Alberta, Canada, have an impact on educational effectiveness in the region. Statistics are provided in the areas of demographics, family and society, Alberta's youth, labor force, and advances in science and technology. The section on demographics includes data on population growth, births, fertility rates,…

  3. A Learning Alberta: Dialogue and Direction. Regional Discussions Summary

    ERIC Educational Resources Information Center

    Alberta Advanced Education, 2005

    2005-01-01

    "A Learning Alberta: Framing the Challenge" is a comprehensive review of the advanced education system in Alberta. The review brought together thousands of Albertans to talk about and seek answers to the challenges of creating a knowledge-based province. In particular, Albertans were encouraged to comment on a proposed policy framework that will…

  4. Mobilization of Manufactured Gas Plant Tar with Alkaline Flushing Solutions

    PubMed Central

    Hauswirth, Scott C.; Birak, Pamela Schultz; Rylander, Seth C.; Miller, Cass T.

    2011-01-01

    This experimental study investigates the use of alkaline and alkaline-polymer solutions for the mobilization of former manufactured gas plant (FMGP) tars. Tar-aqueous interfacial tensions (IFTs) and contact angles were measured, and column flushing experiments were conducted. NaOH solutions (0.01–1 wt.%) were found to significantly reduce tar-aqueous IFT. Contact angles indicated a shift to strongly water-wet, then to tar-wet conditions as NaOH concentration increased. Column experiments were conducted with flushing solutions containing 0.2, 0.35, and 0.5% NaOH, both with and without xanthan gum (XG). Between 10 and 44% of the residual tar was removed by solutions containing only NaOH, while solutions containing both NaOH and XG removed 81–93% of the tar with final tar saturations as low as 0.018. The mechanism responsible for the tar removal is likely a combination of reduced IFT, a favorable viscosity ratio, and tar bank formation. Such an approach may have practical applications and would be significantly less expensive than surfactant-based methods. PMID:22091957

  5. VAPOR PRESSURES AND HEATS OF VAPORIZATION OF PRIMARY COAL TARS

    SciTech Connect

    Eric M. Suuberg; Vahur Oja

    1997-07-01

    This project had as its main focus the determination of vapor pressures of coal pyrolysis tars. It involved performing measurements of these vapor pressures and from them, developing vapor pressure correlations suitable for use in advanced pyrolysis models (those models which explicitly account for mass transport limitations). This report is divided into five main chapters. Each chapter is a relatively stand-alone section. Chapter A reviews the general nature of coal tars and gives a summary of existing vapor pressure correlations for coal tars and model compounds. Chapter B summarizes the main experimental approaches for coal tar preparation and characterization which have been used throughout the project. Chapter C is concerned with the selection of the model compounds for coal pyrolysis tars and reviews the data available to us on the vapor pressures of high boiling point aromatic compounds. This chapter also deals with the question of identifying factors that govern the vapor pressures of coal tar model materials and their mixtures. Chapter D covers the vapor pressures and heats of vaporization of primary cellulose tars. Chapter E discusses the results of the main focus of this study. In summary, this work provides improved understanding of the volatility of coal and cellulose pyrolysis tars. It has resulted in new experimentally verified vapor pressure correlations for use in pyrolysis models. Further research on this topic should aim at developing general vapor pressure correlations for all coal tars, based on their molecular weight together with certain specific chemical characteristics i.e. hydroxyl group content.

  6. Sunflower oil in the treatment of hot tar burns.

    PubMed

    Türegün, M; Oztürk, S; Selmanpakoğlu, N

    1997-08-01

    Hot tar burns compose a unique class of thermal injury, because removal of this highly sticky compound may be very difficult without inflicting additional tissue damage. Early removal of tar facilitates assessment of the burn and improves patient comfort. Although the use of many substances for the painless removal of tar has been described, we used sunflower oil effectively in the treatment of four tar burn patients. This first report describes the practical and successful use of sunflower oil which was easily obtained from the hospital kitchen. PMID:9426916

  7. Wet sand flows better than dry sand

    NASA Astrophysics Data System (ADS)

    Wagner, Christian

    2015-03-01

    Wet sand that does not contain too much water is known to be stiff enough to build sand castles or in physical words has a significant yield stress. However, we could recently show that there are quite a few conditions under which such wet sand opposes less resistant to flow than its dry counterpart. This effect might have been already known to the old Egyptians: The Ancient painting of El Bersheh at the tomb of Tehutihetep shows that there was liquid poured in front of the sledge that was used to transport heavy weight stones and statues. While archeologist have attributed this to a sacral ceremony, our data clearly show that wetting the sand ground drastically decreases the effective sliding friction coefficient. We first study the stress-strain behavior of sand with and without small amounts of liquid under steady and oscillatory shear. Using a technique to quasistatically push the sand through a tube with an enforced parabolic (Poiseuille-like) profile, we minimize the effect of avalanches and shear localization. We observe that the resistance against deformation of the wet (partially saturated) sand is much smaller than that of the dry sand, and that the latter dissipates more energy under flow. Second we show experimentally that the sliding friction on sand is greatly reduced by the addition of some--but not too much--water. The formation of capillary water bridges increases the shear modulus of the sand, which facilitates the sliding.

  8. Geomorphology and sedimentology of hummocky terrain, south-central Alberta, Canada

    NASA Astrophysics Data System (ADS)

    Munro-Stasiuk, Mandy J.

    The landscape in south-central Alberta, Canada, is dominated by a suite of landforms that formed beneath the Laurentide Ice Sheet. This thesis explores the origins of those landforms, specifically hummocky terrain. Sediments in the hummocks, hummock form, and associations with other landforms are examined to determine hummock genesis. Sediment was examined from over one hundred exposures through the "Buffalo Lake Moraine" at Travers Reservoir, McGregor Reservoir, and the Little Bow River. This belt of hummocky terrain (like most hummocky terrain regions) is traditionally interpreted as forming at, or near, the stagnating margins of the Laurentide Ice Sheet by supraglacial letdown. However, hummocks in south-central Alberta contain a complex variety of sediments and materials atypical of supraglacial letdown: in situ bedrock, thrust bedrock, lodgement till, melt-out till, sorted sand and gravel, rippled sand, rhythmically-bedded sand, silt, and clay, and pervasively sheared beds. All sediment types and deformation structures were deposited, or formed, subglacially. Also, the deposits make up in situ stratigraphies that record the history of initial Laurentide Ice Sheet advance into the area (lodgment till and thrust bedrock), the extensive accumulation of water at the bed (glaciolacustrine beds), and ice stagnation (melt-out till). Regardless of the genesis of sediments in hummocks, sedimentary units and structures are abruptly truncated by the surface that represents the hummock and trough morphology, demonstrating that the hummocks are erosional forms and that they represent a landscape unconformity. Subglacial sediments predating the erosion and subglacial eskers overlying the erosion surface strongly suggest that hummock erosion was subglacial. Also, hummock morphology, lithostratigraphy correlated from hummock to hummock, abrupt truncation at the land surface, and widespread boulder lags support meltwater erosion for hummocky terrain in the region. Well

  9. Exploration strategy in Keg River carbonates of northwestern Alberta, Canada

    SciTech Connect

    Majid, A.H.

    1987-05-01

    The analysis of reservoir quality and seal capacity of the Middle Devonian Keg River carbonate reservoirs in northwestern Alberta requires facies studies of rock units of the Keg River Formation and of the overlying Muskeg and Sulphur Point formations. Using lithologic criteria, faunal type, and stratigraphic positions, the entire sequence is subdivided into ten major facies. The system used is that of standard facies belts with second-order modification to Wilson's terminology. These facies are (from basin to land): basin, open sea shelf, toe of slope, foreslope, organic buildup, shoal lime sand, open lagoon, restricted lagoon, tidal flats, and sabkha evaporites. The upper member of the Keg River Formation is the main hydrocarbon reservoir in the study area. It consists of floatstone, rudstone, and boundstone with wackestone, packstone, and grainstone matrix. The principal faunal constituents are crinoids, brachiopods, stromatoporoids, corals, and stachyodes. The reservoir porosity is of primary intergranular and intragranular and secondary vugular textures. The upper Keg River member is composed of two major facies: patch reefs and banks. Both facies are formed in an open lagoon environment fronted by Presqu'ile barrier to the west-northwest. Water depth was the main factor in controlling the distribution of the bank and patch reef facies. Patch reefs were developed in areas of deeper water, whereas banks were formed in shallower areas of the open lagoon. Recent analogs of the Keg River buildups are found on the Bermuda Platform and Belize Shelf. A direct relationship exists between the thickness of overlying anhydrites of the Muskeg Formation and hydrocarbon occurrences in the Keg River Formation. Generally in areas where patch reefs are developed, the thickness of the anhydrite is more than 30 ft. However, areas of bank are covered by less than 30 ft of anhydrite.

  10. Organochlorine residues in northeaster Alberta otters

    SciTech Connect

    Somers, J.D.; Goski, B.C.; Barrett, M.W.

    1987-11-01

    The use of organochlorine pesticides in North America has for the most part been legislatively curtailed during the last decade, and North American production of polychlorinated biphenyls (PCS's) was stopped in the 1970's. However, monitoring of chemical residues in fish and wildlife indicates that these persistent compound are still much in evidence throughout North America. Data on chemical residues in Alberta wildlife, particularly non-migratory species, is for the most part unknown. Otters (Lutra canadensis) are consumers of fish, invertebrates, amphibians and small mammals cohabiting their aquatic habitat. As carnivores at the terminus of their respective food chains, semi-aquatic mammals such as otter and mink (Mustela vison) may be expected to accumulate pesticides, PCBs and heavy metals. Otters are relatively sedentary and monitoring of chemical residues in their tissues might yield a diverse contaminant profile unique to the specific environs from which the animals are collected. The purpose of this report is to present chemical residue data for otters collected from aquatic habitats in northeastern Alberta.

  11. Tar content of cigarettes in relation to lung cancer.

    PubMed

    Kaufman, D W; Palmer, J R; Rosenberg, L; Stolley, P; Warshauer, E; Shapiro, S

    1989-04-01

    Although it is generally considered established that the risk of lung cancer is directly related to the tar content of cigarettes, an examination of the results of previous studies does not yield conclusive evidence in favor of the hypothesis. The authors evaluated this issue in a study of 881 cases of lung cancer and 2,570 hospital controls who were 40 to 69 years of age; data were collected by interview in hospitals in the United States and Canada from November 1981 to June 1986. For each year of smoking, cigarette brands were classified according to their tar content as published in regular Federal Trade Commission reports (from 1967 to 1985) or the Reader's Digest (from 1957 to 1966). Tar values for years for which there was no published information were estimated by interpolation. Smokers were divided, according to the tar content of their cigarette brands averaged over a specified period, into low (less than 22 mg/cigarette), medium (22-28 mg/cigarette), and high (greater than or equal to 29 mg/cigarette) tar smokers. When the average tar content was based on cigarettes smoked at least 10 years previously, the relative risk estimates for medium and high tar smokers compared with low tar smokers were 3.0 and 4.0 after control for potentially confounding factors, including the number of cigarettes smoked per day. The trend was significant (p = 0.002). The tendency for the risk of lung cancer to increase with increasing tar content was consistent among men and women. The results provide further support for the hypothesis that the tar content of cigarettes is directly related to lung cancer risk. However, the data were limited in that there were very few subjects whose lifetime tar exposure averaged less than 10 mg/cigarette. PMID:2923118

  12. 48 CFR Appendix to Part 1252 - Tar Matrix

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 48 Federal Acquisition Regulations System 5 2011-10-01 2011-10-01 false Tar Matrix Appendix to Part 1252 Federal Acquisition Regulations System DEPARTMENT OF TRANSPORTATION CLAUSES AND FORMS SOLICITATION PROVISIONS AND CONTRACT CLAUSES Pt. 1252, App. Appendix to Part 1252—Tar Matrix...

  13. 48 CFR Appendix to Part 1252 - Tar Matrix

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 48 Federal Acquisition Regulations System 5 2012-10-01 2012-10-01 false Tar Matrix Appendix to Part 1252 Federal Acquisition Regulations System DEPARTMENT OF TRANSPORTATION CLAUSES AND FORMS SOLICITATION PROVISIONS AND CONTRACT CLAUSES Pt. 1252, App. Appendix to Part 1252—Tar Matrix...

  14. 48 CFR Appendix to Part 1252 - Tar Matrix

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 48 Federal Acquisition Regulations System 5 2013-10-01 2013-10-01 false Tar Matrix Appendix to Part 1252 Federal Acquisition Regulations System DEPARTMENT OF TRANSPORTATION CLAUSES AND FORMS SOLICITATION PROVISIONS AND CONTRACT CLAUSES Pt. 1252, App. Appendix to Part 1252—Tar Matrix...

  15. 48 CFR Appendix to Part 1252 - Tar Matrix

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 48 Federal Acquisition Regulations System 5 2014-10-01 2014-10-01 false Tar Matrix Appendix to Part 1252 Federal Acquisition Regulations System DEPARTMENT OF TRANSPORTATION CLAUSES AND FORMS SOLICITATION PROVISIONS AND CONTRACT CLAUSES Pt. 1252, App. Appendix to Part 1252—Tar Matrix...

  16. 48 CFR Appendix to Part 1252 - Tar Matrix

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 48 Federal Acquisition Regulations System 5 2010-10-01 2010-10-01 false Tar Matrix Appendix to Part 1252 Federal Acquisition Regulations System DEPARTMENT OF TRANSPORTATION CLAUSES AND FORMS SOLICITATION PROVISIONS AND CONTRACT CLAUSES Pt. 1252, App. Appendix to Part 1252—Tar Matrix...

  17. Environmental stability of PAH source indices in pyrogenic tars

    SciTech Connect

    Uhler, A.D.; Emsbo-Mattingly, S.D.

    2006-04-15

    Polycyclic aromatic hydrocarbons (PAHs) are widespread environmental contaminants found in soil, sediments, and airborne particulates. The majority of PAHs found in modern soils and sediments arise from myriad anthropogenic petrogenic and pyrogenic sources. Tars and tar products such as creosote produced from the industrial pyrolysis of coal or oil at former manufactured gas plants (MGPs) or in coking retorts are viscous, oily substances that contain significant concentrations of PAH, usually in excess of 30% w/w. Pyrogenic tars and tar products have unique PAH patterns (source signatures) that are a function of their industrial production. Among pyrogenic materials, certain diagnostic ratios of environmentally recalcitrant 4-, 5- and 6-ring PAHs have been identified as useful environmental markers for tracking the signature of tars and petroleum in the environment. The use of selected PAH source ratios is based on the concept that PAHs with similar properties (i.e., molecular weight, partial pressure, solubility, partition coefficients, and biotic/abiotic degradation) will weather at similar rates in the environment thereby yielding stable ratios. The stability of more than 30 high molecular weight PAH ratios is evaluated during controlled studies of tar evaporation and aerobic biodegradation. The starting materials in these experiments consisted of relatively unweathered tars derived from coal and petroleum, respectively. The PAH ratios from these laboratory studies are compared to those measured in PAH residues found in tar-contaminated soils at a former MGP that operated with a carburetted water gas process.

  18. 33 CFR 117.831 - Pamlico and Tar Rivers.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 33 Navigation and Navigable Waters 1 2011-07-01 2011-07-01 false Pamlico and Tar Rivers. 117.831 Section 117.831 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY BRIDGES DRAWBRIDGE OPERATION REGULATIONS Specific Requirements North Carolina § 117.831 Pamlico and Tar Rivers....

  19. 33 CFR 117.831 - Pamlico and Tar Rivers.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 33 Navigation and Navigable Waters 1 2010-07-01 2010-07-01 false Pamlico and Tar Rivers. 117.831 Section 117.831 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY BRIDGES DRAWBRIDGE OPERATION REGULATIONS Specific Requirements North Carolina § 117.831 Pamlico and Tar Rivers....

  20. Micro-seismicity in Alberta recorded by the Canadian Rockies and Alberta Network

    NASA Astrophysics Data System (ADS)

    Schultz, R.; Gu, Y. J.

    2012-12-01

    Documented seismicity throughout Alberta, Canada has been relatively low in recent history, with fewer than fifteen events (ML > 3.5) recorded by the Geological Survey of Canada (GSC) since 1985. The notable lack of seismicity could be partially attributed to limited or intermittent station coverage in the province. For this reason, the Alberta Geological Survey (AGS) has been involved in a continued effort to maintain, improve and expand regional seismic networks. Broadband seismic data from the Canadian Rockies and Alberta Network (CRANE) and catalog excerpts from the Canadian National Seismic Network (CNSN) were analyzed. Micro-seismic hypocenters were located using Antelope, a software package from Boulder Real Time Technologies, Inc.. Analysis of data from September, 2006 to June, 2010 shows these events are typically naturally occurring or anthropogenic (e.g., mining blasts, which are not usually part of the earthquake catalogs). More than one hundred and twenty natural earthquakes were located in western and central Alberta, with the majority occurring along the Rocky Mountain foothills. During this period, earthquakes magnitudes (ML) ranging from 0.5 to 4.0 were measured and the magnitude of completeness is ~2.8 for this dataset. The substantial number of unreported events suggests that the existing earthquake catalogs, based exclusively on national seismic network stations, are incomplete. The addition of the CRANE dataset has improved the understanding of background seismicity by providing updated hypocenter locations and waveforms of more than thirty previously unrecorded earthquakes. Future endeavors to incorporate data from additional networks would prove invaluable for the identification of emergent trends or induced events.

  1. Imaging of sand production in horizontal packs by x-ray computed tomography

    SciTech Connect

    Tremblay, B.; Sedgwick, G.; Forshner, K.

    1995-12-31

    Production rates for wells in the Cold Lake area of Alberta that are on {open_quotes}coldflow{close_quotes} production can be much higher than expected from estimates based on radial Darcy flow. Coldflow production here refers to a recovery process used in unconsolidated heavy oil reservoirs in which sand and oil are produced together under primary conditions. A laboratory experiment was designed to model sand production into a perforation in a vertical well drilled into the heavy oil formation. In this experiment, heavy oil (21,500 cP) flowed through a horizontal sand pack and into an orifice simulating a perforation. The flowing oil induced the co-production of sand from the pack when the pressure gradient at the orifice reached 33 Mpa/cm. The sand pack was scanned using X-ray computed tomography (CT). The CT images revealed that a high permeability circular channel (wormhole) had formed in the pack while sand was being produced. The wormhole followed the regions within the sand pack where the porosity was higher and consequently the compressive strength was lower. The porosity within the wormhole was much higher (55%) than the porosity within the undisturbed sand pack (32 %). No significant fines migration was observed before sand production occurred. The particle size distribution of the produced sand was the same as that remaining within the wormhole.

  2. Steam-Reforming Characteristics of Heavy and Light Tars Derived from Cellulose

    NASA Astrophysics Data System (ADS)

    Watanabe, Hirotatsu; Morinaga, Yosuke; Okazaki, Ken

    In this study, tar formation and steam-reforming mechanisms are discussed by separating the tars into heavy, middle, and light tars. Cellulose was heated in a drop-tube furnace under an Ar or Ar/steam atmosphere. After the tars were passed through the furnace for thermal cracking and polymerization, they were trapped by filters set at different temperatures (573, 393, and 273 K), and were respectively defined as heavy, middle, and light tars. Incondensable volatiles and gaseous products were measured using gas chromatography with thermal conductivity (GC-TCD), and flame ionization (GC-FID) detectors. The middle and light tars obtained under an Ar atmosphere were first characterized using time-of-flight mass spectrometry (TOF-MS). The analysis showed that the middle tar did not contain any low-boiling-point light tar components, while the light tar did contain them. It was also found that complex species in the tars were separated to a certain degree by changing the trap temperature. Moreover, the formation of heavy tar was quite different from that of the light tar. With increasing temperature, the formation of heavy tar was inhibited, while that of the light tar was enhanced during pyrolysis. The steam-reforming characteristics of these tars were also different. The heavy tar was barely reformed at a low temperature of 873 K, even with a long residence time, while the middle tar was well reformed by steam. While it was difficult to describe the tar formation and steam-reforming characteristics when the tar was considered as a single condensable matter, the tar formation and steam-reforming characteristics were clarified by separating the tars. This study shows that, to prevent tar emissions, the formation of heavy tar, which barely reacts with steam, should be inhibited during pyrolysis by controlling the heating.

  3. Bat Rabies in Alberta 1979-1982

    PubMed Central

    Rosatte, Richard C.

    1985-01-01

    The infection rate among eight species of bats submitted for rabies diagnosis in Alberta during 1979-82 was 4.6%. Prevalence of rabies was greatest (24%) for hoary bats Lasiurus cinereus, while the big brown bat Eptesicus fuscus was the species in which rabies was most commonly diagnosed, and the species submitted most frequently for rabies diagnosis was the little brown bat Myotis lucifugus. The rabies infection rate among male hoary bats was significantly greater than in either sex of all other submitted species. The frequency of rabies diagnosis in hoary bats submitted during 1979-82 was also significantly higher than in those submitted between 1971 and 1978. There has been a significant decrease in the rabies prevalence or infection rate of little brown bats since 1971-78. PMID:17422507

  4. Swayback (Enzootic Ataxia) in Alberta Lambs

    PubMed Central

    Chalmers, G. A.

    1974-01-01

    Swayback (enzootic ataxia), a disease not previously described in Canada, occurred in newborn lambs in Alberta in 1972. Of 100 lambs born in one flock, over 60 succumbed in the enzootic. The diagnosis was based on the presence of a) gross cavitations and gelatinous lesions of the cerebral white matter in 16 of 24 (66.67%) lambs examined, b) central chromatolysis and hyalinization of neurons of the red and vestibular nuclei and reticular formation and of the lateral and ventral horns of the spinal cord, c) myelin deficiencies of the dorsolateral and sulcomarginal funiculi of the spinal cord and d) low hepatic and serum copper levels in affected lambs and low serum copper levels in the ewes. The feeding of sugar beet-(beta saccharifera) top silage to the ewes during pregnancy, lambing and lactation, and its relationship to the enzootic is discussed. ImagesFig. 1.Fig. 2.Fig. 3.Fig. 4. PMID:4274817

  5. Restoring the Nitrogen Cycle in the Boreal Forest - a Case Study from Northern Alberta

    NASA Astrophysics Data System (ADS)

    Masse, Jacynthe; Grayston, Sue; Prescott, Cindy; Quideau, Sylvie

    2014-05-01

    The Athabasca oil sands deposit, located in the boreal forests of Northern Alberta, is one of the largest single oil deposits in the world. This deposit rests underneath 40,200 square kilometres of land. To date, an area of about 715 square kilometres has been disturbed by oil sands mining activity (Government of Alberta, 2013). Following surface mining, companies have the legal obligation to restore soil-like profiles that can support the previous land capabilities (Powter et al., 2012). Because of its importance for site productivity, re-establishment of the nitrogen cycle between these reconstructed soils and plants is one of the most critical factors required to insure long term sustainability of reclaimed boreal landscape. High nitrogen deposition recorded in the oil sands area combined with the high level of nitrate found in reclaimed soils raised concerns about the possibility of these reclaimed soils being in early stages of N saturation (Laxton et al 2010; Hemsley, 2012), although little evidence of net nitrification in these reclaimed soils suggests the contrary (Laxton et al. 2012). To date, results on the behaviour of the nitrogen cycle in the reclaimed sites are contradictory. A systematic study of the nitrogen cycle, and especially rates of gross mineralization, nitrification and denitrification, is needed. Our research aimed at 1) measuring the gross rates of nitrogen transformations under different vegetation treatments in both reclaimed and naturally-disturbed (fire) sites and 2) characterizing the microbial communities participating in the nitrogen cycle within the same soils. A series of 20 soils, covering different vegetation treatments (plots planted with aspen (Populus tremuloides), spruce (Picea glauca) and grassland) were investigated. Gross nitrogen transformation rates were measured using 15N pool-dilution (Müller et al. 2007). Microbial communities participating in the N-cycle were characterized using qPCR and pyrosequencing. Differences

  6. Using Usability Evaluation to Inform Alberta's Personal Health Record Design.

    PubMed

    Price, Morgan; Bellwood, Paule; Davies, Iryna

    2015-01-01

    Alberta Health is deploying the Personal Health Portal (PHP) (MyHealth.Alberta.ca) to all people in the province of Alberta, Canada. The PHP will include several components such as a Personal Health Record (PHR) where users can enter and access their own health data. For the first PHR of its kind in Canada, Alberta Health asked the University of Victoria's eHealth Observatory to evaluate the PHP, including the PHR. The evaluation includes pre-design, design, and adoption evaluation. This paper focuses on early usability evaluations of the PHR software. Persona-based usability inspection was combined with usability testing sessions using think aloud. These evaluations found that while people were familiar with the web-based technology, several aspects of the PHR information architecture, content, and presentation could be improved to better support and provide value to the users. The findings could be helpful to others designing and implementing similar PHR software. PMID:25676994

  7. Atmospheric tar balls: aged primary droplets from biomass burning?

    NASA Astrophysics Data System (ADS)

    Tóth, A.; Hoffer, A.; Nyirő-Kósa, I.; Pósfai, M.; Gelencsér, A.

    2014-07-01

    Atmospheric tar balls are particles of special morphology and composition that are fairly abundant in the plumes of biomass smoke. These particles form a specific subset of brown carbon (BrC) which has been shown to play a significant role in atmospheric shortwave absorption and, by extension, climate forcing. Here we suggest that tar balls are produced by the direct emission of liquid tar droplets followed by heat transformation upon biomass burning. For the first time in atmospheric chemistry we generated tar-ball particles from liquid tar obtained previously by dry distillation of wood in an all-glass apparatus in the laboratory with the total exclusion of flame processes. The particles were perfectly spherical with a mean optical diameter of 300 nm, refractory, externally mixed, and homogeneous in the contrast of the transmission electron microscopy (TEM) images. They lacked any graphene-like microstructure and exhibited a mean carbon-to-oxygen ratio of 10. All of the observed characteristics of laboratory-generated particles were very similar to those reported for atmospheric tar-ball particles in the literature, strongly supporting our hypothesis regarding the formation mechanism of atmospheric tar-ball particles.

  8. Recognition of HIV TAR RNA by triazole linked neomycin dimers

    PubMed Central

    Kumar, Sunil

    2013-01-01

    A series of neomycin dimers have been synthesized using “click chemistry” with varying linker functionality and length to target the TAR RNA region of HIV virus. TAR (Trans Activation Response) RNA region, a 59 base pair stem loop structure located at 5′-end of all nascent HIV-1 transcripts interacts with a key regulatory protein, Tat, and necessitates the replication of HIV-1 virus. Neomycin, an aminosugar, has been shown to exhibit more than one binding site with HIV TAR RNA. Multiple TAR binding sites of neomycin prompted us to design and synthesize a small library of neomycin dimers using click chemistry. The binding between neomycin dimers and HIV TAR RNA was characterized using spectroscopic techniques including FID (Fluorescent Intercalator Displacement) titration and UV-thermal denaturation. UV thermal denaturation studies demonstrate that neomycin dimer binding increase the melting temperature (Tm) of the HIV TAR RNA up to 10 °C. Ethidium bromide displacement titrations revealed nanomolar IC50 between neomycin dimers and HIV TAR RNA, whereas with neomycin, a much higher IC50 in the micromolar range is observed. PMID:21757341

  9. Ultrasound assisted, thermally activated persulfate oxidation of coal tar DNAPLs.

    PubMed

    Peng, Libin; Wang, Li; Hu, Xingting; Wu, Peihui; Wang, Xueqing; Huang, Chumei; Wang, Xiangyang; Deng, Dayi

    2016-11-15

    The feasibility of ultrasound assisted, thermally activated persulfate for effective oxidation of twenty 2-6 ringed coal tar PAHs in a biphasic tar/water system and a triphasic tar/soil/water system were investigated and established. The results indicate that ultrasonic assistance, persulfate and elevated reaction temperature are all required to achieve effective oxidation of coal tar PAHs, while the heating needed can be provided by ultrasonic induced heating as well. Further kinetic analysis reveals that the oxidation of individual PAH in the biphasic tar/water system follows the first-order kinetics, and individual PAH oxidation rate is primary determined by the mass transfer coefficients, tar/water interfacial areas, the aqueous solubility of individual PAH and its concentration in coal tar. Based on the kinetic analysis and experimental results, the contributions of ultrasound, persulfate and elevated reaction temperature to PAHs oxidation were characterized, and the effects of ultrasonic intensity and oxidant dosage on PAHs oxidation efficiency were investigated. In addition, the results indicate that individual PAH degradability is closely related to its reactivity as well, and the high reactivity of 4-6 ringed PAHs substantially improves their degradability. PMID:27450342

  10. Evaluation of air quality indicators in Alberta, Canada - An international perspective.

    PubMed

    Bari, Md Aynul; Kindzierski, Warren B

    2016-01-01

    There has been an increase in oil sands development in northern Alberta, Canada and an overall increase in economic activity in the province in recent years. An evaluation of the state of air quality was conducted in four Alberta locations - urban centers of Calgary and Edmonton, and smaller communities of Fort McKay and Fort McMurray in the Athabasca Oil Sands Region (AOSR). Concentration trends, diurnal hourly and monthly average concentration profiles, and exceedances of provincial, national and international air quality guidelines were assessed for several criteria air pollutants over the period 1998 to 2014. Two methods were used to evaluate trends. Parametric analysis of annual median 1h concentrations and non-parametric analysis of annual geometric mean 1h concentrations showed consistent decreasing trends for NO2 and SO2 (<1ppb per year), CO (<0.1ppm per year) at all stations, decreasing for THC (<0.1ppm per year) and increasing for O3 (≤0.52ppb per year) at most stations and unchanged for PM2.5 at all stations in Edmonton and Calgary over a 17-year period. Little consistency in trends was observed among the methods for the same air pollutants other than for THC (increasing in Fort McKay <0.1ppm per year and no trend in Fort McMurray), PM2.5 in Fort McKay and Fort McMurray (no trend) and CO (decreasing <0.1ppm per year in Fort McMurray) over the same period. Levels of air quality indicators at the four locations were compared with other Canadian and international urban areas to judge the current state of air quality. Median and annual average concentrations for Alberta locations tended to be the smallest in Fort McKay and Fort McMurray. Other than for PM2.5, Calgary and Edmonton tended to have median and annual average concentrations comparable to and/or below that of larger populated Canadian and U.S. cities, depending upon the air pollutant. PMID:27071052

  11. Improving cumulative effects assessment in Alberta: Regional strategic assessment

    SciTech Connect

    Johnson, Dallas Lalonde, Kim; McEachern, Menzie; Kenney, John; Mendoza, Gustavo; Buffin, Andrew; Rich, Kate

    2011-09-15

    The Government of Alberta, Canada is developing a regulatory framework to better manage cumulative environmental effects from development in the province. A key component of this effort is regional planning, which will lay the primary foundation for cumulative effects management into the future. Alberta Environment has considered the information needs of regional planning and has concluded that Regional Strategic Assessment may offer significant advantages if integrated into the planning process, including the overall improvement of cumulative environmental effects assessment in the province.

  12. Alberta Initiative for School Improvement: Opportunities and Challenges. Symposium at the Annual Meeting of the Canadian Society for the Study of Education (Edmonton, Alberta, Canada, May 24, 2000).

    ERIC Educational Resources Information Center

    McEwen, Nelly, Ed.

    This document describes the outcome of a 1999 symposium that was convened to develop the goal, principles, key considerations, and administrative requirements for a student-improvement program in Alberta. Named the Alberta Initiative for School Improvement (AISI), this program is an extension of Alberta's accountability framework that has been in…

  13. A coke oven model including thermal decomposition kinetics of tar

    SciTech Connect

    Munekane, Fuminori; Yamaguchi, Yukio; Tanioka, Seiichi

    1997-12-31

    A new one-dimensional coke oven model has been developed for simulating the amount and the characteristics of by-products such as tar and gas as well as coke. This model consists of both heat transfer and chemical kinetics including thermal decomposition of coal and tar. The chemical kinetics constants are obtained by estimation based on the results of experiments conducted to investigate the thermal decomposition of both coal and tar. The calculation results using the new model are in good agreement with experimental ones.

  14. The contribution of low tar cigarettes to environmental tobacco smoke

    SciTech Connect

    Chortyk, O.T.; Schlotzhauer, W.S. )

    1989-05-01

    A series of low tar cigarettes (LTC) were smoked and the quantities of condensable mainstream (inhaled) and sidestream (between puffs) smoke compounds were determined and compared to those produced by a high tar, nonfilter cigarette. It was found that the LTC produced large quantities of sidestream smoke condensates, about equal to the high tar cigarette, and contained very high levels of toxic or cocarcinogenic phenols. On an equal weight basis, the LTC emitted more of these hazardous compounds into sidestream and environmental tobacco smoke. Higher smoke yields of a flavor additive and a sugar degradation product indicated addition of such compounds during the manufacture of LTC. It was concluded that, compared to a high tar cigarette, smoking LTC may be better for the smoker, but not for the nearby nonsmoker. Information should be developed to allow smokers to choose LTC that produce lower levels of hazardous compounds in their environmentally emitted sidestream smoke.

  15. Preparation of meso-carbon microbeads from coal tars

    SciTech Connect

    Ling, L.C.; Liu, L.; Zhang, B.J.; Wu, D.

    1997-12-31

    Coal tar (CT0) with 3.7wt% primary pyridine insoluble fraction (PI) was chosen as the raw material to prepare mesocarbon microbeads (MCMB). The tar was filtered to remove PI, obtaining PI-free coal tar (CT1). CT0, CT1 and their mixtures with different proportions were carbonized under pressure for 2 hours respectively. The polymerizates were filtered, and the residues were extracted with pyridine, and thus MCMB was obtained as a pyridine insoluble fraction. Both the yield and the size of resultant MCMB increased with the decreasing of primary PI content in raw coal tars. No clear evidence was observed that the primary PI particles exhibited active sites during the formation of MCMB, while it`s certain that they restricted coalescence between mesophase spheres.

  16. Phytotoxicity of oil sands naphthenic acids and dissipation from systems planted with emergent aquatic macrophytes.

    PubMed

    Armstrong, Sarah A; Headley, John V; Peru, Kerry M; Germida, James J

    2008-01-01

    Differences in dissipation and phytotoxicity were measured for two naphthenic acid mixtures in hydroponically grown emergent macrophytes (Typha latifolia, Phragmites australis, and Scirpus acutus). One of the naphthenic acid (NA) mixtures was extracted from tailings pond water of an oil sands operation in Fort McMurray, Alberta, Canada. The other mixture was a commercially available NA mixture. While the oil sands NA mixture was less phytotoxic to wetland plants compared to the commercially available NA mixture, they were not sequestered by wetland plants like their commercial NA counterparts. The small loss of commercial NAs from the spiked hydroponic system appeared to be selective and dependant on the specific NA compound. The results of this study indicate that plants alone may not mitigate NAs from oil sands tailings pond water. In addition, caution should be taken when making predictions on the environmental fate of oil sands naphthenic acids when using commercial NAs as surrogates. PMID:18161556

  17. Primary Carcinoma of the Liver in Alberta

    PubMed Central

    Nett, A. E.; Gilbert, J. A. L.

    1966-01-01

    A survey was made to determine the incidence and to elucidate the manifestations of primary carcinoma of the liver in Alberta. The findings were compared with other reported series. Ninety-six cases were identified: 69 hepatomas, 25 cholangiomas and two cholangiohepatomas. Seventy-four of the patients were male and 22 were female, a male preponderance of greater than 3:1. Ages ranged from 7 days to 92 years, but the majority of the patients (58%) were in the seventh and eighth decades. The incidence of associated cirrhosis (38.5%) was lower than that noted in most series. Hepatomegaly, abdominal pain, weight loss and ascites were the outstanding clinical features. Gastrointestinal hemorrhage was frequent and second only to hepatic failure as the immediate cause of death. An abdominal mass and pleural effusion occurred in higher frequency than that cited in the literature. Associated disorders included peptic ulceration and cholelithiasis. Surgical biopsy was superior to needle biopsy in establishing the diagnosis. Laboratory tests and routine radiographs may be of diagnostic aid. PMID:4287068

  18. Atmospheric Tar Balls: Particles from Biomass and Biofuel Burning

    NASA Technical Reports Server (NTRS)

    Posfai, Mihaly; Gelencser, Andras; Simonics, Renata; Arato, Krisztina; Li, Jia; Hobbs, Peter V.; Buseck, Peter R.

    2004-01-01

    Tar balls are amorphous, carbonaceous spherules that occur in the tropospheric aerosol as a result of biomass and biofuel burning. They form a distinct group of particles with diameters typically between 30 and 500 nm and readily identifiable with electron microscopy. Their lack of a turbostratic microstructure distinguishes them from soot, and their morphology and composition (approximately 90 mol% carbon) renders them distinct from other carbonaceous particles. Tar balls are particularly abundant in slightly aged (minutes to hours old) biomass smoke, indicating that they likely form by gas-to-particle conversion within smoke plumes. The material of tar balls is initially hygroscopic; however, the particles become largely insoluble as a result of free radical polymerization of their organic molecules. Consequently, tar balls are primarily externally mixed with other particle types, and they do not appreciably increase in size during aging. When tar balls coagulate with water-bearing particles, their material may partly dissolve and no longer be recognizable as distinct particles. Tar balls may contain organic compounds that absorb sunlight. They are an important, previously unrecognized type of carbonaceous (organic) atmospheric particle.

  19. Oil shales and tar sands: a bibliography. Supplement 2, Parts 1 and 2

    SciTech Connect

    Grissom, M.C.

    1984-07-01

    This bibliography includes 4715 citations arranged in the broad subject categories: reserves and exploration; site geology and hydrology; drilling, fracturing, and mining; oil production, recovery, and refining; properties and composition; direct uses and by-products; health and safety; marketing and economics; waste research and management; environmental aspects; regulations; and general. There are corporate, author, subject, contract number, and report number indexes.

  20. Canadian tar sands predicted to double, but little United States output in fifteen years

    SciTech Connect

    Not Available

    1986-06-01

    Based on major long-term forces, L.M. Woods, former Executive Vice President of Mobil Oil Corporation, believes that alternative energy supplies will begin to find their place in the sun in the late 1990s. Small variations in economic growth can speed up or slow down the beginning of a commercial alternate energy industry by five or more years. Woods then recites the obvious: to date, synthetic fuels have proved a rotten investment; any payout is too distant and too uncertain. Yet, when the market tightens the almost instant production of meaningful quantities of alternate energy will be demanded politically. Thus the reduction of lead-times should be the one great objective of long-term national energy policy. Any reduction in lead-time will require the acquisition of new knowledge. For synfuels R and D, there no longer appears to be a prospect for high-risk, big-payoff breakthroughs. An evolutionary mode of research is required to set the stage for a successful transition to the fuels of the future. The risks will remain too large and the payoffs too distant for decisions, by the private or public sectors, to commit huge sums to capacity until the research and development phase has matured. The research investment does not appear attractive to the private sector because the lead-times are abnormally long. Thus the government must play an important role, and every avenue to new energy supplies must be thoroughly explored. But if government develops capacity too soon, then resources and talent will be wasted. Woods believes the R and D phase may even require the development and construction of a number of alternative full-scale production modules.

  1. Reservoir sedimentology of the M. Triassic Halfway Fm. , Wembley field, Alberta

    SciTech Connect

    Willis, A.J. )

    1991-03-01

    The Middle Triassic Halfway Formation of west-central Alberta is interpreted as a prograding barrier island shoreline deposit. A detailed sedimentological study based on 130 cored sequences and 300 well logs in the Wembley area (Townships 72-73, Ranges 7-9, West of Sixth Meridian) has enabled the author to delineate the geometry of reservoir units, interpreted as tidal inlet fill, upper shoreface, and flood-tidal delta sandstones. Complete shoreface sequences average 15 m in thickness and form mappable trends tens of kilometers along depositional strike, but are only continuous for a few kilometers across dip, with the intervening areas having been reworked by one or more migrating tidal inlets. The strike-elongate inlet-fill sequences cover more than 50% of the field area. They are typically 10 m thick and exhibit the best porosities due to leaching of bioclastic material in the lower part of the fill, but the down-cutting of successive inlets makes the reservoir sands laterally discontinuous. Inlet sands extend up-dip into flood-tidal delta sandbodies that average 4 m in thickness and pinch out in lagoonal muds. Although showing much greater lateral continuity than the other reservoir units, the upper shoreface sandstones do not exhibit biomoldic porosity and are a less productive unit. Such an understanding of the architecture of the various reservoir components present in a barrier island shoreline system is essential when planning a secondary recovery program.

  2. Thermally Released Arsenic in Porewater from Sediments in the Cold Lake Area of Alberta, Canada.

    PubMed

    Javed, Muhammad Babar; Siddique, Tariq

    2016-03-01

    Elevated arsenic (As) in aquifers in close proximity to in situ oil sands extraction in the Cold Lake area, Alberta, Canada is attributed to high temperature steam (~200 °C) injected into oil sands deposits to liquefy bitumen. Heat propagated from hot injection wells alters physicochemical properties of the surrounding sediments and associated porewater. Seven sediments from four different cores drilled up to ~300 m depth collected from different locations in the area were used to study the thermal effect (~200 °C) on As distribution in the sediments and its release into porewater. Sediments were moistened with synthetic aquifer or deionized water according to the moisture regimes present in aquitard, aquifer and fractured zones. Heat application greatly released As in the porewater (500-5200 and 1200-6600 μg L(-1)) from aquifer and fractured sediments, respectively. Mass balance of As chemical fractionation showed that ~89-100% of As in porewater was released from exchangeable and specifically adsorbed As in the sediments. Heat application also altered As distribution in the sediments releasing As from exchange surfaces and amorphous Fe oxides to soluble As fraction. The results provide great insight into As release mechanisms warranting development of strategies to mitigate groundwater As contamination during industrial operation. PMID:26839972

  3. Industrial sand and gravel

    USGS Publications Warehouse

    Dolley, T.P.

    2006-01-01

    In 2005, domestic production of industrial sand and gravel was about 31 Mt, a 5% increase from 2004. This increase was bouyed by robust construction and petroleum sectors of the US economy. Based on estimated world production figures, the United States was the world's leading producer and consumer of industrial sand and gravel. In the short term, local shortages of industrial sand and gravel will continue to increase.

  4. Mercury Concentration and Isotopic Composition of Epiphytic Tree Lichens in the Alberta Oil Sands Region

    EPA Science Inventory

    Mercury (Hg) is a toxic heavy metal that is found associated with fossil fuel deposits and that can be released to the atmosphere during fossil fuel combustion and/or processing. Hg emitted to the atmosphere can be deposited to aquatic and terrestrial ecosystems where it can be m...

  5. Variations in treatment of femoral neck fractures in Alberta

    PubMed Central

    Cree, Marilyn; Yang, Qian; Scharfenberger, Angela; Johnson, David; Carrière, K.C.

    2002-01-01

    Objectives To examine, in the province of Alberta, temporal trends, regional variations in treatment options and in-hospital death rates after a femoral neck fracture. Design A retrospective cohort study. Patients Six years’ data were abstracted from the Alberta Morbidity File, the Alberta Health Stakeholder File and the Alberta Health Care Claims File. Patients were included if they were Alberta residents, aged 65 years or older, had sustained a femoral neck fracture and had undergone internal fixation, hemiarthroplasty or total hip arthroplasty. Main outcome measures Death rates, arthroplasty rates and hospital stay. Results In-hospital death rates were similar across hospitals, with risks being higher for men, patients aged 80 years or older and those with more comorbid conditions. Arthroplasty rates varied from 58% to 77% among hospitals, and hospital stays associated with arthroplasty were significantly longer than those associated with internal fixation. The chance of undergoing arthroplasty varied from hospital to hospital by gender and by the number of comorbid conditions. Conclusion Regional variations suggest lack of agreement among Alberta’s surgeons as to how best to treat femoral neck fractures. PMID:12174977

  6. Steam sand dryer in northeast part of sand tower. View ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Steam sand dryer in northeast part of sand tower. View to northeast - Duluth & Iron Range Rail Road Company Shops, Sand Tower, Southwest of downtown Two Harbors, northwest of Agate Bay, Two Harbors, Lake County, MN

  7. Biogeochemical gradients above a coal tar DNAPL.

    PubMed

    Scherr, Kerstin E; Backes, Diana; Scarlett, Alan G; Lantschbauer, Wolfgang; Nahold, Manfred

    2016-09-01

    Naturally occurring distribution and attenuation processes can keep hydrocarbon emissions from dense non aqueous phase liquids (DNAPL) into the adjacent groundwater at a minimum. In a historically coal tar DNAPL-impacted site, the de facto absence of a plume sparked investigations regarding the character of natural attenuation and DNAPL resolubilization processes at the site. Steep vertical gradients of polycyclic aromatic hydrocarbons, microbial community composition, secondary water quality and redox-parameters were found to occur between the DNAPL-proximal and shallow waters. While methanogenic and mixed-electron acceptor conditions prevailed close to the DNAPL, aerobic conditions and very low dissolved contaminant concentrations were identified in three meters vertical distance from the phase. Comprehensive two-dimensional gas chromatography-mass spectrometry (GC×GC-MS) proved to be an efficient tool to characterize the behavior of the present complex contaminant mixture. Medium to low bioavailability of ferric iron and manganese oxides of aquifer samples was detected via incubation with Shewanella alga and evidence for iron and manganese reduction was collected. In contrast, 16S rDNA phylogenetic analysis revealed the absence of common iron reducing bacteria. Aerobic hydrocarbon degraders were abundant in shallow horizons, while nitrate reducers were dominating in deeper aquifer regions, in addition to a low relative abundance of methanogenic archaea. Partial Least Squares - Canonical Correspondence Analysis (PLS-CCA) suggested that nitrate and oxygen concentrations had the greatest impact on aquifer community structure in on- and offsite wells, which had a similarly high biodiversity (H' and Chao1). Overall, slow hydrocarbon dissolution from the DNAPL appears to dominate natural attenuation processes. This site may serve as a model for developing legal and technical strategies for the treatment of DNAPL-impacted sites where contaminant plumes are absent or

  8. Tar Production from Biomass Pyrolysis in a Fluidized Bed Reactor: A Novel Turbulent Multiphase Flow Formulation

    NASA Technical Reports Server (NTRS)

    Bellan, J.; Lathouwers, D.

    2000-01-01

    A novel multiphase flow model is presented for describing the pyrolysis of biomass in a 'bubbling' fluidized bed reactor. The mixture of biomass and sand in a gaseous flow is conceptualized as a particulate phase composed of two classes interacting with the carrier gaseous flow. The solid biomass is composed of three initial species: cellulose, hemicellulose and lignin. From each of these initial species, two new solid species originate during pyrolysis: an 'active' species and a char, thus totaling seven solid-biomass species. The gas phase is composed of the original carrier gas (steam), tar and gas; the last two species originate from the volumetric pyrolysis reaction. The conservation equations are derived from the Boltzmann equations through ensemble averaging. Stresses in the gaseous phase are the sum of the Newtonian and Reynolds (turbulent) contributions. The particulate phase stresses are the sum of collisional and Reynolds contributions. Heat transfer between phases, and heat transfer between classes in the particulate phase is modeled, the last resulting from collisions between sand and biomass. Closure of the equations must be performed by modeling the Reynolds stresses for both phases. The results of a simplified version (first step) of the model are presented.

  9. China Dust and Sand

    Atmospheric Science Data Center

    2013-04-16

    ... article title:  Dust and Sand Sweep Over Northeast China     View Larger Image ... these views of the dust and sand that swept over northeast China on March 10, 2004. Information on the height of the dust and an ...

  10. An Affair with Sand.

    ERIC Educational Resources Information Center

    Stroud, Sharon

    1980-01-01

    Described is a resource idea developed for the teaching of oceanography to junior high students. Sand is studied to help make the study of beaches more relevant to students who may have never seen an ocean. Sand samples are brought into the classroom from various coastal cities, then analyzed and compared. (Author/DS)

  11. Attracting, Preparing, and Retaining Under-Represented Populations in Rural and Remote Alberta-North Communities

    ERIC Educational Resources Information Center

    Steel, Nancy; Fahy, Patrick J.

    2011-01-01

    For several years, the government of the western Canadian province of Alberta has drafted policies and conducted research on the problem of populations under-represented in adult education. This Alberta-North and Athabasca University study, funded by the Alberta government's Innovation Fund, uses the advice and educational experiences of northern…

  12. Those Who Care: A Report on Approved Family Day Home Providers in Alberta.

    ERIC Educational Resources Information Center

    Read, Malcolm; LaGrange, Annette

    This study examines the characteristics and work environments of approved family day home providers in Alberta. Family day home agency coordinators from across Alberta completed questionnaires, as did approved providers who contracted with 12 agencies in central Alberta. Typical providers were married, had children, and had lived in their present…

  13. 77 FR 10502 - MATL LLP; Montana Alberta Tie, Ltd; Notice of Petition for Declaratory Order

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-02-22

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF ENERGY Federal Energy Regulatory Commission MATL LLP; Montana Alberta Tie, Ltd; Notice of Petition for Declaratory Order Take notice that on February 13, 2012, MATL LLP (MATL) and Montana Alberta Tie Ltd (Montana Alberta...

  14. 2007/2008 Employer Satisfaction Survey Employers of Alberta High School Graduates

    ERIC Educational Resources Information Center

    Alberta Education, 2008

    2008-01-01

    The 2007/2008 Employer Satisfaction Survey was commissioned by Alberta Education and Alberta Advanced Education and Technology. Data collection for the survey was conducted by CCI Research Inc. between December 1st, 2007 and January 11th, 2008. The objective of the survey was to assess employer satisfaction with recent graduates from Alberta's…

  15. Biodegradation of naphthalene from coal tar. Research progress report

    SciTech Connect

    Ghoshal, S.; Ramaswami, A.; Luthy, R.G.

    1994-02-07

    Biodegradation experiments were conducted to evaluate the mineralization of naphthalene released from coal tar entrapped in microporous silica media. Tests were performed with two coal tars recovered from former manufactured gas plant sites. Results from these tests showed that the degradation end point for naphthalene was significantly lower than the total amount of naphthalene present in coal tar. The role of physico-chemical and biological processes on the rate of biotransformation of naphthalene was evaluated. Mass transfer rates for dissolution of naphthalene from entrapped coal tar were measured in batch, flow-through systems. The rate of naphthalene mass transfer from the coal tar was found to be significantly greater than the rate of naphthalene biomineralization in batch slurry reactors. This implied that the rate acting factor for the biodegradation process was related to biokinetic phenomena rather than mass transfer processes. Further tests indicated that conditions inhibitory to bacteria limited the biodegradation of naphthalene, and in some cases the inhibition was reversible upon dilution of the reactor contents.

  16. Assessment of tar pollution on the United Arab emirates beaches

    SciTech Connect

    Abu-Hilal, A.H.; Khordagui, H.K. )

    1993-01-01

    In light of the inadequate information concerning stranded tar on the southwest beaches of the Arabian Gulf and the Gulf of Oman, particularly following the massive oil releases during the Gulf War, the present investigation was designed to provide reference-integrated information on the nature, location, and levels of stranded tar balls on the beaches of the United Arab Emirates (UAE). The recorded levels appeared to be higher than expected or previously reported. The tar distribution pattern, in addition to the degree of weathering, indicates that the massive oil release during the Gulf War did not reach the UAE shorelines. The highest reported levels of stranded tar ever recorded in the Arabian Gulf at Jabal Dhannah apparently originated from oil spills and tankers' ballast water at the main oil terminal at the Al-Ruwaiss oil refinery some 10 km to the east. The surprising, relatively high levels of stranded tar on the beaches of the Gulf of Oman were solely attributed to the heavy navigation traffic close to the shorelines. 19 refs., 2 figs., 3 tabs.

  17. Mars Rover Curiosity Traverses of Sand Ripples

    NASA Astrophysics Data System (ADS)

    Stein, N.; Arvidson, R. E.; Zhou, F.; Heverly, M.; Maimone, M.; Hartman, F.; Bellutta, P.; Iagnemma, K.; Senatore, C.

    2014-12-01

    Martian sand ripples present a challenge for rover mobility, with drives over ripples often characterized by high wheel sinkage and slippage that can lead to incipient embedding. Since landing in Gale Crater, Curiosity has traversed multiple sand ripples, including the transverse aeolian ridge (TAR) straddling Dingo Gap on sols 533 and 535. On sol 672, Curiosity crossed backward over a series of sand ripples before ending its drive after high motor currents initiated visual odometry (VO) processing, which detected 77% slip, well in excess of the imposed 60% slip limit. At the end of the drive, the right front wheel was deeply embedded at the base of a ripple flank with >20 cm sinkage and the rear wheels were near a ripple crest. As Curiosity continues its approach to Mount Sharp it will have to cross multiple ripples, and thus it is important to understand Curiosity's performance on sol 672 and over similar ripples. To this end the sol 672 drive was simulated in ARTEMIS (Adams-Based Rover Terramechanics Interaction Simulator), a software tool consisting of realistic rover mechanical models, a wheel-terrain interaction module for deformable and non-deformable surfaces, and realistic terrain models. ARTEMIS results, Dumont Dunes tests performed in the Mojave Desert using the Scarecrow test rover, and single wheel tests performed at MIT indicate that the high slip encountered on sol 672 likely occurred due to a combination of rover attack angle, ripple geometry, and soil properties. When ripple wavelength approaches vehicle length, the rover can reach orientations in which the leading wheels carry minimal normal loads and the trailing wheels sink deeply, resulting in high slippage and insufficient thrust to propel the rover over ripples. Even on relatively benign (i.e. low tilt) terrains, local morphology can impose high sinkage, thus impeding rover motion. Work is underway to quantify Curiosity's drive performance over various ripple geometries to retrieve soil

  18. A microbiological survey of selected Alberta-grown fresh produce from farmers' markets in Alberta, Canada.

    PubMed

    Bohaychuk, V M; Bradbury, R W; Dimock, R; Fehr, M; Gensler, G E; King, R K; Rieve, R; Romero Barrios, P

    2009-02-01

    Previously there was no available information on the levels of indicator bacteria and the prevalence of pathogens in fresh produce grown in Alberta, Canada. Baseline information on the occurrence and levels of Escherichia coli and the prevalence of foodborne pathogens in selected produce items available to consumers from farmers' and public markets in two large urban centers and surrounding areas in Alberta was obtained. A total of 10 large markets with between 1 and 12 produce vendors and 26 small markets with between 1 and 6 produce vendors were sampled from 21 June to 7 October 2007. Lettuce (128 samples), spinach (59 samples), tomatoes (120 samples), carrots (206 samples), green onions (129 samples), and strawberries (31 samples) were analyzed for E. coli, Salmonella, E. coli O157:H7, and Campylobacter spp. Lettuce, spinach, green onion, and strawberry samples were also tested for the presence of Cryptosporidium spp. Information on whether produce was grown using organic or conventional practices was obtained from the produce vendors. E. coli was isolated from 8.2% of the samples that included lettuce, spinach, carrots, and green onions. The bacterial counts ranged from <0.48 to >3.04 Log most probable number per g. E. coli was not isolated from tomatoes or strawberries. The percentage of positive samples ranged from 4.4% for carrots to 27.1% for spinach. Salmonella, E. coli O157:H7, and Campylobacter spp. were not isolated from any of the samples. Cryptosporidium was identified by PCR in one sample of spinach (0.6% of the samples). PMID:19350990

  19. Basaltic island sand provenance

    SciTech Connect

    Marsaglia, K.M. . Dept. of Geological Sciences)

    1992-01-01

    The Hawaiian Islands are an ideal location to study basaltic sand provenance in that they are a series of progressively older basaltic shield volcanoes with arid to humid microclimates. Sixty-two sand samples were collected from beaches on the islands of Hawaii, Maui, Oahu and Kauai and petrographically analyzed. The major sand components are calcareous bioclasts, volcanic lithic fragments, and monomineralic grains of dense minerals and plagioclase. Proportions of these components vary from island to island, with bioclastic end members being more prevalent on older islands exhibiting well-developed fringing reef systems and volcanic end members more prevalent on younger, volcanically active islands. Climatic variations across the island of Hawaii are reflected in the percentage of weathered detritus, which is greater on the wetter, northern side of the island. The groundmass of glassy, basaltic lithics is predominantly black tachylite, with lesser brown sideromelane; microlitic and lathwork textures are more common than holohyaline vitric textures. Other common basaltic volcanic lithic fragments are holocrystalline aggregates of silt-sized pyroxene or olivine, opaque minerals and plagioclase. Sands derived from alkalic lavas are texturally and compositionally indistinguishable from sands derived from tholeiitic lavas. Although Hawaiian basaltic sands overlap in composition with magmatic arc-derived sands in terms of their relative QFL, QmPK and LmLvLs percentages, they are dissimilar in that they lack felsic components and are more enriched in lathwork volcanic lithic fragments, holocrystalline volcanic lithic fragments, and dense minerals.

  20. Coal tar phototoxicity: characteristics of the smarting reaction

    SciTech Connect

    Diette, K.M.; Gange, R.W.; Stern, R.S.; Arndt, K.A.; Parrish, J.A.

    1985-04-01

    The properties and ultraviolet exposure parameters of tar smarts were examined in an effort to elucidate the mechanisms involved. It was show that irradiation with 1 minimal smarting dose (MSD) of UVA immediately following tar removal lowered the MSD for 6 h, demonstrated by subsequent challenge with UVA. Following 3 MSDs this memory effect was demonstrable for 24 h. The smarting reaction was area dependent--smaller areas of exposure require higher doses of UVA to induce smarting. Smarting followed reciprocity over a 6-fold range of irradiances (2-12.5 mW/cm2) but higher irradiances required higher doses of UVA, perhaps due to a delay in the recognition and reporting of smarting. The smarting reaction and delayed erythema due to UVA and tar were equally blocked by sunscreen.

  1. Industrial sand and gravel

    USGS Publications Warehouse

    Dolley, T.P.

    2010-01-01

    Domestic production of industrial sand and gravel in 2009 was about 27 Mt (30 million st), declining by 10 percent compared with 2008. Certain end uses of industrial sand and gravel, such as foundry and glassmaking sand, may have declined by a factor greater than 10 percent in 2009. U.S. apparent consumption was 24.7 Mt (27.2 million st) in 2009, down by 10 percent from the previous year, and imports declined to 83 kt (91,000 st).

  2. Formulae for TAR and SAR calculation for Co-60 beam.

    PubMed

    Tripathi, U B

    1980-04-01

    Tissue-air ratio (TAR) and scatter-air ratio (SAR) are very important concepts in radiation dosimetry. In absence of any analytical relation for computation of these quantities a number of empirical equations have been fitted to experimentally measured data. This paper describes the derivation of analytical formulae from first principles. The resultant equations are very simple and can even be evaluated with the help of a slide rule. The computed values of TAR and SAR agree within 1% with the experimental data of Gupta and Cunningham (1966). PMID:7368231

  3. Vehicular fuels and oxychemicals from biomass thermochemical tars

    SciTech Connect

    Soltes, E.J.; Lin, S.C.K.

    1983-01-01

    Catalytic hydroprocessing (hydrotreating and hydrocracking) of biomass thermochemical tars can yield mixtures of liquid hydrocarbons and alkyl aromatics of chemical compositions similar to those presently used in diesel and gasoline engine fuels. Phenolics can be coproduced. Compositions of hydroprocessed tars are similar regardless of biomass feedstock used, suggesting that the two-stage process of pyrolysis and hydroprocessing may afford a somewhat universal route to the generation of useful hydrocarbons and oxychemicals from a variety of agricultural and forestry residues. 26 references, 6 figures, 1 table.

  4. Student Street. Students' Union Housing, University of Alberta

    ERIC Educational Resources Information Center

    Dixon, John Morris

    1974-01-01

    The world's longest skylighted galleria (main street for student residents at the University of Alberta) is the lifeline of a 950-foot long complex of apartments and shops sponsored by the student government and architecturally designed to fit over an existing street. (Author/MF)

  5. Principal Quality Practice in Alberta: Education 900 Introduction Paper

    ERIC Educational Resources Information Center

    Ennest, Robert

    2010-01-01

    Purpose: The purpose of this study was to examine the efficacy of Alberta's Principal Quality Practice Standard as a framework for the roles and responsibilities of school principals. Methodology: Three principals participated in the study, and each principal had more than 25 years of teaching and school administration experience. Each…

  6. Academic Achievement of Red Deer College Students at Alberta Universities.

    ERIC Educational Resources Information Center

    Burford, Charles Thomas

    The purpose of this study was to report on the academic achievement of Red Deer College transfer students at three Alberta Universities for 1968-1971. Transfer students were matched with native students from the universities using session year, year of program, degree sought, age, sex, and first year cumulative grade-point average. These matched…

  7. Alberta Learning: Early Development Instrument Pilot Project Evaluation.

    ERIC Educational Resources Information Center

    Meaney, Wanda; Harris-Lorenze, Elayne

    The Early Development Instrument (EDI) was designed by McMaster University to measure the outcomes of childrens early years as they influence their readiness to learn at school. The EDI was piloted in several Canadian cities in recent years through two national initiatives. Building on these initiatives, Alberta Learning piloted the EDI as a…

  8. FOIPP and Technology: Best Practices for Alberta School Jurisdictions.

    ERIC Educational Resources Information Center

    Gillis, R. Peter; Whitemarsh, Judith

    This study provides suggestions and best practices for superintendents, Freedom of Information and Protection of Privacy (FOIPP) coordinators and school information technologists in dealing with the impact of Alberta's FOIPP Act on the application of information technologies within their organizations. The study explores the relationship between…

  9. Framing a New Standard for Teaching in Alberta

    ERIC Educational Resources Information Center

    Hull, John E.

    2013-01-01

    A research panel asked to frame the discussion for a new Teaching Quality Standard in Alberta assumes this task requires a paradigm shift away from the status quo efficiency movement. As a member of the panel, the author provides an analysis of paradigm shifts in education and recounts important lessons to be learned. The author challenges the…

  10. Educational Quality Indicators: Developing Indicator Systems in Alberta.

    ERIC Educational Resources Information Center

    McEwen, Nelly

    The Educational Quality Indicators (EQI) initiative, a collaboration between Alberta Education and 12 school jurisdictions in the province, is described, and its implications are discussed. The EQIs developed are designed to provide information to assist practitioners in assessing the quality of educational programs and the delivery system by…

  11. Essential Inclusive Education-Related Outcomes for Alberta Preservice Teachers

    ERIC Educational Resources Information Center

    Loreman, Tim

    2010-01-01

    This article examines the knowledge, skills, and attributes (KSAs) that Alberta preservice teachers need to develop over the course of their teacher preparation programs in order to work effectively in inclusive classrooms. Inclusive classrooms are those where all students regardless of diversity learn in the same contexts. These KSAs are…

  12. Evaluation of the Alberta School for the Deaf.

    ERIC Educational Resources Information Center

    Clarke, S. C. T.; Nyberg, V. R.

    The report summarized a formative evaluation of the Alberta (Canada) School for the Deaf (ASD). Data were collected via observations by 12 consultants; interviews; and questionnaires completed by parents, teachers, students, and administrators. The evaluation was designed to focus on such aspects as instruction (including curriculum) and total…

  13. Supporting Positive Behaviour in Alberta Schools: An Intensive Individualized Approach

    ERIC Educational Resources Information Center

    Souveny, Dwaine

    2008-01-01

    Drawing on current research and best practices, this third part of the three-part resource, "Supporting Positive Behaviour in Alberta Schools," provides information and strategies for providing intensive, individualized support and instruction for the small percentage of students requiring a high degree of intervention. This system of individual…

  14. Some Aspects of Leadership in Independent Schools in Alberta.

    ERIC Educational Resources Information Center

    Decoux, Bruce V.; Holdaway, Edward A.

    1999-01-01

    A study used interviews, observations, and documents to examine perceptions of principals in eight accredited, independent schools in Alberta (Canada) about major factors affecting their leadership role. Factors included philosophical congruence enhanced by respect and trust, as well as personal relationships, school culture, symbolism, and…

  15. Locating Leadership: The Blind Spot in Alberta's Technology Policy Discourse

    ERIC Educational Resources Information Center

    Brooks, Charmaine

    2011-01-01

    Over the last 20 years, technology and education policy discourse in Alberta, Canada has been philosophically polarized and dominated by value-neutral ways of thinking about technology (Brooks, 2011). While technology policy implementation has significant ramifications for schools and systems, for much of this time, system leaders, specifically…

  16. Indian Tribes of Alberta. Revised, Expanded, and Updated.

    ERIC Educational Resources Information Center

    Dempsey, Hugh A.

    This book recounts the story of the Indians in Alberta, Canada. Pictures and maps help in the explanation of these facts. The Indians described include the: (1) Blackfoot Nation (Blackfoot, Blood, Peigan Tribes); (2) Sarcee Tribe; (3) Stoney Indians; (4) Plains Cree; (5) Woodland Cree; (6) Chipewyan Indians; (7) Beaver Indians; (8) Slavey Indians;…

  17. International Medical Graduates: Learning for Practice in Alberta, Canada

    ERIC Educational Resources Information Center

    Lockyer, Jocelyn; Hofmeister, Marianna; Crutcher, Rodney; Klein, Douglas; Fidler, Herta

    2007-01-01

    Introduction: There is little known about the learning that is undertaken by physicians who graduate from a World Health Organization-listed medical school outside Canada and who migrate to Canada to practice. What do physicians learn and what resources do they access in adapting to practice in Alberta, a province of Canada? Methods: Telephone…

  18. Faculty Salaries in Alberta's Colleges & Institutes, 1993 to 2000.

    ERIC Educational Resources Information Center

    Barnetson, Bob

    This report outlines changes in salaries earned by full-time, permanent faculty members at Alberta's public colleges and technical institutes between September 1993 and September 2000. The Colleges Act and Technical Institutes Act create academic staff associations at each institution and mandate each institution's Board of Governors to negotiate…

  19. Biology and Life Science Classroom Teaching Environment in Southern Alberta.

    ERIC Educational Resources Information Center

    Guay, Julian

    This study provides information about the biology and life science classroom teaching environments in Southern Alberta. Responses (N=53) to questionnaires sent to junior and senior high school teachers in rural and urban settings revealed information regarding school facilities, texts and reference materials, field trips, outdoor education…

  20. A Review of School Board Cyberbullying Policies in Alberta

    ERIC Educational Resources Information Center

    Nosworthy, Nicole; Rinaldi, Christina

    2012-01-01

    An online search for school board cyberbullying/bullying policies in Alberta was conducted. The results showed that while only five school boards had a bullying policy, many schools had technology or Internet use guidelines. The online search included an assessment of one extensive school board cyberbullying policy as well as Internet use…

  1. Alberta High School, College Elevate Learning with Rare Joint Venture

    ERIC Educational Resources Information Center

    Pearson, George

    2012-01-01

    The refusal by a group of parents in Olds, Alberta, in 2003 to accept a provincial grant to renovate their high school set in motion a remarkable collaboration that spawned an innovative learning campus for an entire community and beyond. The new Olds High School, which opened in 2010, is part of a new Community Learning Campus (CLC), a joint…

  2. School Identity in the Context of Alberta Charter Schools

    ERIC Educational Resources Information Center

    Thompson, Merlin; Gereluk, Dianne; Kowch, Eugene

    2016-01-01

    The central tenet of this investigation is that educational institutions possess their own school identity. Acknowledging that school identity is influenced by institutional mechanisms and personal dynamics, we examine school identity in the context of 13 Alberta charter schools. Narratives of 73 educational stakeholders across the network of…

  3. Foundry sand reclamation

    SciTech Connect

    Filipovitch, A.J.; Bleuenstein, J.M.

    1984-05-22

    A dry method of conditioning spent foundry sand is disclosed. After having sized the sand and removal of tramp metallic elements, the sand is subjected to a sequence of squeezing under a high-stress low kinetic energy system for a period of 5-30 minutes, and then propelled against a target with high-kinetic energy in the presence of a suction for several minutes. This sequence can be preferably repeated to increase the quality of the resulting product which should have 0.1% or less of fine particles, a pH of 6-9, a clay content and organic combustible content of substantially zero. The reclaimed sand will exhibit a density of at least 100 grams/biscuit when compacted for core making or molding.

  4. Sand Volcano Following Earthquake

    NASA Technical Reports Server (NTRS)

    1989-01-01

    Sand boil or sand volcano measuring 2 m (6.6 ft.) in length erupted in median of Interstate Highway 80 west of the Bay Bridge toll plaza when ground shaking transformed loose water-saturated deposit of subsurface sand into a sand-water slurry (liquefaction) in the October 17, 1989, Loma Prieta earthquake. Vented sand contains marine-shell fragments. Sand and soil grains have faces that can cause friction as they roll and slide against each other, or even cause sticking and form small voids between grains. This complex behavior can cause soil to behave like a liquid under certain conditions such as earthquakes or when powders are handled in industrial processes. Mechanics of Granular Materials (MGM) experiments aboard the Space Shuttle use the microgravity of space to simulate this behavior under conditions that carnot be achieved in laboratory tests on Earth. MGM is shedding light on the behavior of fine-grain materials under low effective stresses. Applications include earthquake engineering, granular flow technologies (such as powder feed systems for pharmaceuticals and fertilizers), and terrestrial and planetary geology. Nine MGM specimens have flown on two Space Shuttle flights. Another three are scheduled to fly on STS-107. The principal investigator is Stein Sture of the University of Colorado at Boulder. (Credit: J.C. Tinsley, U.S. Geological Survey)

  5. Microcomputers in Alberta Schools--1985. A Final Report on the Results of a Resource Survey of Alberta Schools.

    ERIC Educational Resources Information Center

    Petruk, Milton W.

    To determine the number and current use of microcomputers in Alberta's elementary, junior, and senior high schools, a total of 1,509 schools were surveyed. The results, as reported by 1,271 schools (84.2%), showed the total number of microcomputers to be 13,748. To provide more in-depth information, schools were categorized by six instructional…

  6. 29 CFR 1910.1002 - Coal tar pitch volatiles; interpretation of term.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 29 Labor 6 2012-07-01 2012-07-01 false Coal tar pitch volatiles; interpretation of term. 1910.1002... Hazardous Substances § 1910.1002 Coal tar pitch volatiles; interpretation of term. As used in § 1910.1000 (Table Z-1), coal tar pitch volatiles include the fused polycyclic hydrocarbons which volatilize from...

  7. 29 CFR 1910.1002 - Coal tar pitch volatiles; interpretation of term.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 29 Labor 6 2010-07-01 2010-07-01 false Coal tar pitch volatiles; interpretation of term. 1910.1002... Hazardous Substances § 1910.1002 Coal tar pitch volatiles; interpretation of term. As used in § 1910.1000 (Table Z-1), coal tar pitch volatiles include the fused polycyclic hydrocarbons which volatilize from...

  8. 29 CFR 1910.1002 - Coal tar pitch volatiles; interpretation of term.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 29 Labor 6 2013-07-01 2013-07-01 false Coal tar pitch volatiles; interpretation of term. 1910.1002... Hazardous Substances § 1910.1002 Coal tar pitch volatiles; interpretation of term. As used in § 1910.1000 (Table Z-1), coal tar pitch volatiles include the fused polycyclic hydrocarbons which volatilize from...

  9. 29 CFR 1910.1002 - Coal tar pitch volatiles; interpretation of term.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 29 Labor 6 2014-07-01 2013-07-01 true Coal tar pitch volatiles; interpretation of term. 1910.1002... Hazardous Substances § 1910.1002 Coal tar pitch volatiles; interpretation of term. As used in § 1910.1000 (Table Z-1), coal tar pitch volatiles include the fused polycyclic hydrocarbons which volatilize from...

  10. 48 CFR 1201.301-70 - Amendment of (TAR) 48 CFR chapter 12.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 48 Federal Acquisition Regulations System 5 2010-10-01 2010-10-01 false Amendment of (TAR) 48 CFR... Amendment of (TAR) 48 CFR chapter 12. (a) Changes to the regulation may be the result of recommendations...., Washington, DC 20590: (1) Problem: Succinctly state the problems created by current (TAR) 48 CFR chapter...

  11. 48 CFR 1201.301-70 - Amendment of (TAR) 48 CFR chapter 12.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ...., Washington, DC 20590: (1) Problem: Succinctly state the problems created by current (TAR) 48 CFR chapter 12... 48 Federal Acquisition Regulations System 5 2014-10-01 2014-10-01 false Amendment of (TAR) 48 CFR... Amendment of (TAR) 48 CFR chapter 12. (a) Changes to the regulation may be the result of...

  12. 48 CFR 1201.301-70 - Amendment of (TAR) 48 CFR chapter 12.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ...., Washington, DC 20590: (1) Problem: Succinctly state the problems created by current (TAR) 48 CFR chapter 12... 48 Federal Acquisition Regulations System 5 2013-10-01 2013-10-01 false Amendment of (TAR) 48 CFR... Amendment of (TAR) 48 CFR chapter 12. (a) Changes to the regulation may be the result of...

  13. 48 CFR 1201.301-70 - Amendment of (TAR) 48 CFR chapter 12.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ...., Washington, DC 20590: (1) Problem: Succinctly state the problems created by current (TAR) 48 CFR chapter 12... 48 Federal Acquisition Regulations System 5 2011-10-01 2011-10-01 false Amendment of (TAR) 48 CFR... Amendment of (TAR) 48 CFR chapter 12. (a) Changes to the regulation may be the result of...

  14. 48 CFR 1201.301-70 - Amendment of (TAR) 48 CFR chapter 12.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ...., Washington, DC 20590: (1) Problem: Succinctly state the problems created by current (TAR) 48 CFR chapter 12... 48 Federal Acquisition Regulations System 5 2012-10-01 2012-10-01 false Amendment of (TAR) 48 CFR... Amendment of (TAR) 48 CFR chapter 12. (a) Changes to the regulation may be the result of...

  15. Coal tar-containing asphalt - resource or hazardous waste?

    SciTech Connect

    Andersson-Skold, Y.; Andersson, K.; Lind, B.; Claesson, A.; Larsson, L.; Suer, P.; Jacobson, T.

    2007-09-30

    Coal tar was used in Sweden for the production of asphalt and for the drenching of stabilization gravel until 1973. The tar has high concentrations of polycyclic aromatic hydrocarbons (PAH), some of which may be strongly carcinogenic. Approximately 20 million tonnes of tar-containing asphalt is present in the public roads in Sweden. Used asphalt from rebuilding can be classified as hazardous waste according to the Swedish Waste Act. The cost of treating the material removed as hazardous waste can be very high due to the large amount that has to be treated, and the total environmental benefit is unclear. The transport of used asphalt to landfill or combustion will affect other environmental targets. The present project, based on three case studies of road projects in Sweden, evaluates the consequences of four scenarios for handling the material: reuse, landfill, biological treatment, and incineration. The results show that reuse of the coal tar-containing materials in new road construction is the most favorable alternative in terms of cost, material use, land use, energy consumption, and air emissions.

  16. Release of polyaromatic hydrocarbons from coal tar contaminated soils

    SciTech Connect

    Priddy, N.D.; Lee, L.S.

    1996-11-01

    A variety of process wastes generated from manufactured gas production (MGP) have contaminated soils and groundwater at production and disposal sites. Coal tar, consisting of a complex mixture of hydrocarbons present as a nonaqueous phase liquid, makes up a large portion of MGP wastes. Of the compounds in coal tar, polyaromatic hydrocarbons (PAHs) are the major constituents of environmental concern due to their potential mutagenic and carcinogenic hazards. Characterization of the release of PAHs from the waste-soil matrix is essential to quantifying long-term environmental impacts in soils and groundwater. Currently, conservative estimates for the release of PAHs to the groundwater are made assuming equilibrium conditions and using relationships derived from artificially contaminated soils. Preliminary work suggests that aged coal tar contaminated soils have much lower rates of desorption and a greater affinity for retaining organic contaminants. To obtain better estimates of desorption rates, the release of PAHs from a coal tar soil was investigated using a flow-interruption, miscible displacement technique. Methanol/water solutions were employed to enhance PAH concentrations above limits of detection. For each methanol/water solution employed, a series of flow interrupts of varying times was invoked. Release rates from each methanol/water solution were estimated from the increase in concentration with duration of flow interruption. Aqueous-phase release rates were then estimated by extrapolation using a log-linear cosolvency model.

  17. CONTROL TECHNOLOGIES FOR PARTICULATE AND TAR EMISSIONS FROM COAL CONVERTERS

    EPA Science Inventory

    The report gives results of a characterization of solid and tar particulate emissions in raw product gases from several types of coal gasifiers, in terms of their total quantities, chemical composition, and size distribution. Fixed-bed gasifiers produce the smallest particulate l...

  18. SULFUR TOLERANT CATALYSTS FOR BIOMASS TAR REMOVAL - PHASE I

    EPA Science Inventory

    In this Small Business Innovation Research (SBIR) project, NexTech Materials proposes a catalytic reforming approach to remove waste tar from gasified biomass on nickel-based catalysts. Biomass gasification is a potential renewable route to producing electricity, liquid fue...

  19. Glove permeation by shale oil and coal tar extract

    SciTech Connect

    Nelson, G.O.; Carlson, G.J.; Buerer, A.L.

    1980-02-14

    The vapor penetration of shale oil and coal tar extract through protective gloves composed of either polyethylene, polyvinyl chloride, vinyl, latex, neoprene, Buna-N, acrylonitrile, natural rubber, or nitrile rubber was tested and measured. We used flame ionization techniques to determine the permeation characteristics of the gloves. Neoprene, Buna-N, acrylonitrile and nitrile gloves offered the best protection against the vapors tested.

  20. Phytotoxicity and Plant Productivity Analysis of Tar-Enriched Biochars

    NASA Astrophysics Data System (ADS)

    Keller, M. L.; Masiello, C. A.; Dugan, B.; Rudgers, J. A.; Capareda, S. C.

    2008-12-01

    Biochar is one of the three by-products obtained by the pyrolysis of organic material, the other two being syngas and bio-oil. The pyrolysis of biomass has generated a great amount of interest in recent years as all three by-products can be put toward beneficial uses. As part of a larger project designed to evaluate the hydrologic impact of biochar soil amendment, we generated a biochar through fast pyrolysis (less than 2 minutes) of sorghum stock at 600°C. In the initial biochar production run, the char bin was not purged with nitrogen. This inadvertent change in pyrolysis conditions produced a fast-pyrolysis biochar enriched with tars. We chose not to discard this batch, however, and instead used it to test the impact of tar-enriched biochars on plants. A suite of phytotoxicity tests were run to assess the effects of tar-rich biochar on plant germination and plant productivity. We designed the experiment to test for negative effects, using an organic carbon and nutrient-rich, greenhouse- optimized potting medium instead of soil. We used Black Seeded Simpson lettuce (Lactuca sativa) as the test organism. We found that even when tars are present within biochar, biochar amendment up to 10% by weight caused increased lettuce germination rates and increased biomass productivity. In this presentation, we will report the statistical significance of our germination and biomass data, as well as present preliminary data on how biochar amendment affects soil hydrologic properties.

  1. Wet scrubbing of biomass producer gas tars using vegetable oil

    NASA Astrophysics Data System (ADS)

    Bhoi, Prakashbhai Ramabhai

    The overall aims of this research study were to generate novel design data and to develop an equilibrium stage-based thermodynamic model of a vegetable oil based wet scrubbing system for the removal of model tar compounds (benzene, toluene and ethylbenzene) found in biomass producer gas. The specific objectives were to design, fabricate and evaluate a vegetable oil based wet scrubbing system and to optimize the design and operating variables; i.e., packed bed height, vegetable oil type, solvent temperature, and solvent flow rate. The experimental wet packed bed scrubbing system includes a liquid distributor specifically designed to distribute a high viscous vegetable oil uniformly and a mixing section, which was designed to generate a desired concentration of tar compounds in a simulated air stream. A method and calibration protocol of gas chromatography/mass spectroscopy was developed to quantify tar compounds. Experimental data were analyzed statistically using analysis of variance (ANOVA) procedure. Statistical analysis showed that both soybean and canola oils are potential solvents, providing comparable removal efficiency of tar compounds. The experimental height equivalent to a theoretical plate (HETP) was determined as 0.11 m for vegetable oil based scrubbing system. Packed bed height and solvent temperature had highly significant effect (p0.05) effect on the removal of model tar compounds. The packing specific constants, Ch and CP,0, for the Billet and Schultes pressure drop correlation were determined as 2.52 and 2.93, respectively. The equilibrium stage based thermodynamic model predicted the removal efficiency of model tar compounds in the range of 1-6%, 1-4% and 1-2% of experimental data for benzene, toluene and ethylbenzene, respectively, for the solvent temperature of 30° C. The NRTL-PR property model and UNIFAC for estimating binary interaction parameters are recommended for modeling absorption of tar compounds in vegetable oils. Bench scale

  2. [Effect of coal tar on cignolin erythema--1 hour treatment of psoriasis with high-dose cignolin with and without tar].

    PubMed

    Schauder, S; Mahrle, G

    1985-06-01

    Coal tar applied simultaneously showed a suppressive effect on anthralin erythema. This effect was demonstrated by an epicutaneous test 24 hours (27 patients) and 1 hour (46 patients) after application of various concentrations of anthralin combined with tar 3%. In a clinical study on 9 patients, anthralin 3% alone or combined with tar 10% were administered in a right and left comparison on symmetrical chronic psoriatic lesions for 1 hour daily. Anthralin plus tar exhibited a stronger anti-psoriatic effect than anthralin alone did. Tar reduced the anthralin erythema in the perilesional skin. These findings favor the combination of coal tar and anthralin in the 1-hour treatment schedule of psoriasis. PMID:3160177

  3. Designing the IShTAR antenna: Physics and engineering aspects

    NASA Astrophysics Data System (ADS)

    Louche, F.; Jacquot, J.; Crombé, K.; Van Eester, D.; D'Inca, R.; Devaux, S.; Faudot, E.; Faugel, H.; Fünfgelder, H.; Heuraux, S.; Morgal, I.; Moritz, J.; Ochoukov, R.; Noterdaeme, J.-M.

    2015-12-01

    IShTAR (Ion cyclotron Sheath Test ARrangement) is a magnetised plasma test facility installed at the Max-Planck-Institut für Plasmaphysik in Garching, Germany. The main purpose of this device is the study of RF sheaths generated in front of ICRF (Ion Cyclotron Range of Frequency) antennas in magnetically confined plasmas. The plasma is generated by a helical RF antenna potentially able to reach a helicon mode. We present in this work recent modelling activities dedicated to IShTAR. On the one hand a parameterized magnetostatic model of the magnetic configuration was created with the finite element solver COMSOL Multiphysics [3]. The model considers two non-axial sets of coils and notably reproduces the magnetic field lines deviation at the center of the main vessel and the ripples observed during experiments. From this model we can infer that kA are required in the 2 main large coils of IShTAR for 1 kA in the 4 small coils to generate a "smooth" magnetic field along field lines. On the other hand an ICRF antenna has been designed for IShTAR. A tridimensional model of the IShTAR vessel was developed with the electromagnetic code MicroWave Studio (MWS [4]) for this purpose and a first antenna model made of a single strap inside a box was included. The strap is fed through the upper port located at the helicon source side. The antenna is fully immersed into the loading medium (plasma or homogeneous dielectric) and the curved strap front face is aligned with the magnetic surfaces to simplify the modelling. The initial design of this antenna has been studied with MWS in the presence of homogeneous dielectric. The presence of a back wall will be discussed.

  4. Tertiary recovery potential of CO2 flooding in Joffre Viking pool, Alberta

    SciTech Connect

    Ko, S.C.M.; Stanton, P.M.

    1983-01-01

    Significant tertiary oil recovery by CO2 flooding in a watered-out Joffre Viking sand unit in central Alberta, as determined in a preliminary feasibility study, prompted further detailed evaluation of the CO2 process. Consequently, reservoir simulation models are used in the study to further investigate the technical feasibility and prediction of CO2 flood performance. Using a Black Oil simulator (BETA II), history matching of primary and waterflood production performance on a selected portion of the Joffre Viking Pool involving 85 wells was undertaken. This step provided for proper initialization of fluid and pressure distribution and a reservoir description for the miscible CO2 flood model (COMP II). Sensitivity analysis and process optimization using a typical pattern approach were conducted to optimize the tertiary CO2 flood performance. Simulation results indicated that in the presence of a trapped oil saturation due to water blocking oil from contact by the injected CO2, a larger CO2 slug and/or a smaller water slug are required in a water-alternating-with-gas process for more efficient displacements. 13 references.

  5. Evidence for limits on the acceptability of lowest-tar cigarettes.

    PubMed Central

    Kozlowski, L T

    1989-01-01

    The sales of the lowest yield cigarettes (1-3 mg tar) seem to have been particularly resistant to the effects of promotion and advertising, while the sales of other low-yield cigarettes (4-9 mg tar) seem to have been increased by promotional efforts. This finding is consistent with the existence of a boundary of tar and nicotine acceptability below which consumers in general are not prepared to go. Use of lower tar cigarettes may be helpful for those who cannot stop smoking, but, since 1979, the percentage of cigarettes under 16 mg tar has changed little. PMID:2913841

  6. Management of hot tar burn using vitamin e ointment containing petroleum and polyoxyethylene sorbitan.

    PubMed

    Ng, Karen; Dalen, Dawn; Rhine, David

    2013-09-01

    Tar burns are primarily an occupational hazard associated with the road paving or roofing industry. Management of tar burns requires safe and effective removal of solidified tar from the skin using a dissolution or emulsifying agent to prevent inflicting further injury and pain. We report a case of a patient with tar burns on 10% of his body surface area involving the lower arms bilaterally and splashes to the facial area. The tar was efficiently removed with Webber Vitamin E Ointment without toxicity, irritation, or other complications. PMID:23972137

  7. Sidewinding snakes on sand

    NASA Astrophysics Data System (ADS)

    Marvi, Hamidreza; Dimenichi, Dante; Chrystal, Robert; Mendelson, Joseph; Goldman, Daniel; Hu, David; Georgia Tech and Zoo Atlanta Collaboration

    2012-11-01

    Desert snakes such as the rattlesnake Crotalus cerastes propel themselves over sand using sidewinding, a mode of locomotion relying upon helical traveling waves. While sidewinding on hard ground has been described, the mechanics of movement on more natural substrates such as granular media remain poorly understood. In this experimental study, we use 3-D high speed video to characterize the motion of a sidewinder rattlesnake as it moves on a granular bed. We study the movement both on natural desert sand and in an air-fluidized bed trackway which we use to challenge the animal on different compactions of granular media. Particular attention is paid to rationalizing the snake's thrust on this media using friction and normal forces on the piles of sand created by the snake's body. The authors thank the NSF (PHY-0848894), Georgia Tech, and the Elizabeth Smithgall Watts endowment for support. We would also like to thank Zoo Atlanta staff for their generous help with this project.

  8. Ganges Chasma Sand Sheet

    NASA Technical Reports Server (NTRS)

    2005-01-01

    [figure removed for brevity, see original site]

    Our topic for the weeks of April 4 and April 11 is dunes on Mars. We will look at the north polar sand sea and at isolated dune fields at lower latitudes. Sand seas on Earth are often called 'ergs,' an Arabic name for dune field. A sand sea differs from a dune field in two ways: 1) a sand sea has a large regional extent, and 2) the individual dunes are large in size and complex in form.

    Today's sand sheet is located in the Ganges Chasma portion of Valles Marineris. As with yesterday's image, note that the dune forms are seen only at the margin and that the interior of the sand sheet at this resolution appears to completely lack dune forms.

    Image information: VIS instrument. Latitude -6.4, Longitude 310.7 East (49.3 West). 19 meter/pixel resolution.

    Note: this THEMIS visual image has not been radiometrically nor geometrically calibrated for this preliminary release. An empirical correction has been performed to remove instrumental effects. A linear shift has been applied in the cross-track and down-track direction to approximate spacecraft and planetary motion. Fully calibrated and geometrically projected images will be released through the Planetary Data System in accordance with Project policies at a later time.

    NASA's Jet Propulsion Laboratory manages the 2001 Mars Odyssey mission for NASA's Office of Space Science, Washington, D.C. The Thermal Emission Imaging System (THEMIS) was developed by Arizona State University, Tempe, in collaboration with Raytheon Santa Barbara Remote Sensing. The THEMIS investigation is led by Dr. Philip Christensen at Arizona State University. Lockheed Martin Astronautics, Denver, is the prime contractor for the Odyssey project, and developed and built the orbiter. Mission operations are conducted jointly from Lockheed Martin and from JPL, a division of the California Institute of Technology in Pasadena.

  9. Using infrastructure optimization to reduce greenhouse gas emissions from oil sands extraction and processing.

    PubMed

    Middleton, Richard S; Brandt, Adam R

    2013-02-01

    The Alberta oil sands are a significant source of oil production and greenhouse gas emissions, and their importance will grow as the region is poised for decades of growth. We present an integrated framework that simultaneously considers economic and engineering decisions for the capture, transport, and storage of oil sands CO(2) emissions. The model optimizes CO(2) management infrastructure at a variety of carbon prices for the oil sands industry. Our study reveals several key findings. We find that the oil sands industry lends itself well to development of CO(2) trunk lines due to geographic coincidence of sources and sinks. This reduces the relative importance of transport costs compared to nonintegrated transport systems. Also, the amount of managed oil sands CO(2) emissions, and therefore the CCS infrastructure, is very sensitive to the carbon price; significant capture and storage occurs only above 110$/tonne CO(2) in our simulations. Deployment of infrastructure is also sensitive to CO(2) capture decisions and technology, particularly the fraction of capturable CO(2) from oil sands upgrading and steam generation facilities. The framework will help stakeholders and policy makers understand how CCS infrastructure, including an extensive pipeline system, can be safely and cost-effectively deployed. PMID:23276202

  10. Differential Absorption Lidar (DIAL) in Alberta: A New Remote Sensing Tool for Wide Area Measurement of Particulates, CO2, and CH4 Emissions from Energy Extraction and Production Sites

    NASA Astrophysics Data System (ADS)

    Wojcik, M.; Lemon, R.; Crowther, B. G.; Valupadas, P.; Fu, L.; Yang, Z.; Huda, Q.; Leung, B.; Chambers, A.

    2014-12-01

    Alberta Environmental Monitoring, Evaluation and Reporting Agency (AEMERA) in cooperation with the Space Dynamics Laboratory (SDL) of Utah State University, have developed a mobile DIAL sensor designed specifically for particle, CO2 and CH4 emissions measurement. Rapid expansion of the oil and gas industry in Alberta, including the oil sands, has challenged the Alberta Government to keep pace in its efforts to monitor and mitigate the environmental impacts of development. The limitations of current monitoring systems has pushed the provincial government to seek out advanced sensing technologies such as differential absorption lidar (DIAL) to help assess the impact of energy development and industrial operations. This instrument is housed inside a 36' trailer and can be quickly staged and used to characterize source emissions and to locate fugitive leaks. DIAL is capable of measuring concentrations for carbon dioxide (CO2) and methane (CH4) at ranges of up to 3 km with a spatial resolution of 1.5 m. DIAL can map both CO2 and CH4, as well as particulate matter (PM) in a linear fashion; by scanning the laser beam in both azimuth and elevation, DIAL can create images of emissions concentrations and ultimately can be used to determine emission factors, locate fugitive leaks, assess plume dispersion and confirm air dispersion modeling. The DIAL system has been deployed at a landfill, a coal-fired power plant, and an oil sands production area. A system overview of the DIAL instrument and recent results will be discussed.

  11. Sand Dunes with Frost

    NASA Technical Reports Server (NTRS)

    2004-01-01

    9 May 2004 This Mars Global Surveyor (MGS) Mars Orbiter Camera (MOC) image shows a suite of frost-covered sand dunes in the north polar region of Mars in early spring, 2004. The dunes indicate wind transport of sand from left to right (west to east). These landforms are located near 78.1oN, 220.8oW. This picture is illuminated by sunlight from the lower left and covers an area about 3 km (1.9 mi) across.

  12. Alberta's acute care funding plan: update to December 1994.

    PubMed

    Jacobs, P; Hall, E M; Plain, R H

    1995-01-01

    From 1990 until 1994 Alberta Health adjusted the acute care portion of hospital budgets based on a case mix index, initially called the Hospital Performance Index (HPI). The HPI formula method was a temporary measure; in November 1993, Alberta Health announced that, commencing in 1994, hospitals would be funded on a prospective basis, although they would still use the core of the HPI in the setting of funding rates. The creation of 17 health regions in June 1994 created the need for a new system of funding which would supplant the modified prospective system. In this paper we review the evolution of the HPI plan and its individual components-patient data, patient classification, funding weights, inpatient costs and adjustment factors. PMID:10144217

  13. Hantavirus pulmonary syndrome: Report of four Alberta cases

    PubMed Central

    Singh, Ameeta E; Werker, Denise H; Boychuk, Lesia R; Miedzinski, Lilly J

    1995-01-01

    Four Alberta cases of hantavirus pulmonary syndrome are reported. Three cases required intensive care, with one experiencing a fulminant course resulting in death. A fourth case with milder illness was identified after epidemiological investigations. Ribavirin was used in one patient who experienced a successful outcome. A recent open label trial has not supported the efficacy of this drug. The epidemiology of Peromyscus maniculatus, the primary rodent host, and the clinical features of this syndrome are summarized. PMID:22514394

  14. The temporal relationship between advertising and sales of low‐tar cigarettes

    PubMed Central

    Reed, Mark B; Anderson, Christy M; Burns, David M

    2006-01-01

    Objective and hypothesis To determine whether a temporal relationship exists between the advertising and sales of low‐tar cigarettes. It was hypothesised that increases in the advertising of low‐tar cigarettes would precede increases in sales for these cigarettes. Methods The themes of cigarette advertisements were reviewed and coded for 20 low‐tar cigarette brands advertised in 13 widely read magazines in the US between 1960 and 1996. These 20 brands represented most of the low‐tar cigarette advertisements and cigarette sales from 1967 to 1996. Cigarette sales data were obtained from the 1994 Maxwell report that summarises all cigarette sales from 1925 to 1990. If the advertisement referred to the low‐tar attributes of the cigarette advertised, the advertisement was coded as having a low‐tar theme and was included in the analysis. Results Five different graphical presentations of the relationship between the advertising and sales of the 20 low‐tar cigarette brands showed a temporal relationship between low‐tar advertising and sales for these brands. This relationship was observed for brands that introduced a low‐tar alternative into an existing brand family (eg, Marlboro Light) and for new exclusively low‐tar brands (eg, Carlton). Despite large increases in the advertising for the exclusively low‐tar brands, sales of these brands remained low relative to sales of the low‐tar alternative brands. Conclusions Increases in print advertising of 20 of the most popular low‐tar cigarette brands were followed by increases in sales for these cigarettes. Despite increases in the advertising of exclusively low‐tar brands in the mid‐1970s and early 1980s, the sales of these brands never matched the sales of the low‐tar alternative brands. This suggests that it may have been easier to get smokers to switch to low‐tar brands within a brand family compared with entirely new low‐tar brands. Over the past 30 years, the marketing of low‐tar

  15. Hospital reimbursement in Alberta: outcomes management is on the way.

    PubMed

    MacKenzie, T A; Reynolds, D; Greenaway-Coates, A

    1992-01-01

    The Alberta government has initiated a process to alter fundamentally the way it pays hospitals. As with most provinces, Alberta has been paying hospitals for what they spend. The new Alberta model will initially pay hospitals for what they do and ultimately will pay hospitals for what they ought to do; that is, for the outcomes that should be achieved. This article describes the initial step of what is expected to be a lengthy journey. The principles underlying the model are: it should be a prospective case-based system; there should be performance linkages between types of hospitals; severity should be incorporated into the model; and cost or cost proxies should be used where possible in weight development and clinical concerns, both nursing and medical, should be addressed. For the past two years funding adjustments have been made on the basis of the calculation of a Hospital Performance Index (HPI). The HPI is the average predicted cost per case divided by the unweighted average actual cost per case. The HPI is intended as an interim measure only. Ultimately, the system will evolve into a true prospective case-based system with volume controlled via role statements and linked to clinical outcomes. PMID:10123272

  16. Building with Sand

    ERIC Educational Resources Information Center

    Ashbrook, Peggy

    2010-01-01

    Children playing in damp sand invariably try to make a tower or a tunnel. By providing experiences with a variety of materials, alone and together, teachers set up the conditions for children to learn through their senses and ensure that a class approaches a topic with a common set of experiences to build on. Learning about the properties of…

  17. Ganges Chasma Sands

    NASA Technical Reports Server (NTRS)

    2005-01-01

    8 July 2005 This Mars Global Surveyor (MGS) Mars Orbiter Camera (MOC) image shows dark, windblown sand in the form of dunes and a broad, relatively flat, sand sheet in Ganges Chasma, part of the eastern Valles Marineris trough complex. The winds responsible for these dunes blew largely from the north. Sand dunes on Mars, unlike their Earthly counterparts, are usually dark in tone. This is a reflection of their composition, which includes minerals that are more rich in iron and magnesium than the common silica-rich dunes of Earth. Similar dark sands on Earth are found in volcanic regions such as Iceland and Hawaii. A large dune field of iron/magnesium-rich grains, in the form fragments of the volcanic rock, basalt, occurs south of Moses Lake, Washington, in the U.S.

    Location near: 7.7oS, 45.3oW Image width: 3 km (1.9 mi) Illumination from: lower left Season: Southern Spring

  18. Western Gas Sands Subprogram

    SciTech Connect

    Not Available

    1983-12-01

    The Western Gas Sands Subprogram (WGSS) is a multidisciplinary research effort within the US Department of Energy program on Unconventional Gas Recovery. The subprogram, managed by DOE's Morgantown Energy Technology Center, is directed towards the development of tight (very low permeability) lenticular gas sands in the western United States. The purpose of the subprogram is to demonstrate the feasibility of economically producing natural gas from low-permeability reservoirs. The subprogram has two broad goals: (1) to reduce the uncertainty of the reservoir production potential and (2) to improve the extraction technology. With input from the gas industry, universities, and geologic and engineering consulting firms, the WGSS was broadened to include more fundamental research and development. Consequently, for the last five years it has focused on improving diagnostic instrumentation, geophysical and engineering interpretation, and stimulation techniques. Integrated geologic studies of the three priority basins containing tight sands and selected by DOE as research targets have also been pursued as part of this new effort. To date, the following tentative conclusions have evolved: Permeability of the tight gas sands can be as much as three to four orders of magnitude lower than conventional gas deposits. Nineteen western geologic basins and trends containing significant amounts of tight gas have been identified. Gas resources in the priority geologic basins are Piceance Basin, 49 tcf., Uinta Basin, 20 tcf., and Greater Green River Basin, 136 tcf. The presence of natural micro-fractures within the production zone of a reservoir and the effective propped length of hydraulically-induced fractures are the critical parameters for successful development of tight sand resources. 8 figures.

  19. Northern Sand Sea

    NASA Technical Reports Server (NTRS)

    2005-01-01

    [figure removed for brevity, see original site]

    Our topic for the weeks of April 4 and April 11 is dunes on Mars. We will look at the north polar sand sea and at isolated dune fields at lower latitudes. Sand seas on Earth are often called 'ergs,' an Arabic name for dune field. A sand sea differs from a dune field in two ways: 1) a sand sea has a large regional extent, and 2) the individual dunes are large in size and complex in form.

    This VIS image was taken at 82 degrees North latitude during Northern spring. The image is completely dominated by dunes. In sand seas, it is very common for a single type of dune to occur, and for a single predominate wind to control the alignment of the dunes.

    Image information: VIS instrument. Latitude 82.2, Longitude 152.5 East (207.5 West). 19 meter/pixel resolution.

    Note: this THEMIS visual image has not been radiometrically nor geometrically calibrated for this preliminary release. An empirical correction has been performed to remove instrumental effects. A linear shift has been applied in the cross-track and down-track direction to approximate spacecraft and planetary motion. Fully calibrated and geometrically projected images will be released through the Planetary Data System in accordance with Project policies at a later time.

    NASA's Jet Propulsion Laboratory manages the 2001 Mars Odyssey mission for NASA's Office of Space Science, Washington, D.C. The Thermal Emission Imaging System (THEMIS) was developed by Arizona State University, Tempe, in collaboration with Raytheon Santa Barbara Remote Sensing. The THEMIS investigation is led by Dr. Philip Christensen at Arizona State University. Lockheed Martin Astronautics, Denver, is the prime contractor for the Odyssey project, and developed and built the orbiter. Mission operations are conducted jointly from Lockheed Martin and from JPL, a division of the California Institute of Technology in Pasadena.

  20. Crustal Seismic Structure of Central Alberta from Receiver Function Inversions

    NASA Astrophysics Data System (ADS)

    Chen, Y.; Dokht, R.; Gu, Y. J.; Sacchi, M. D.

    2013-12-01

    It is widely believed that the basement structure of central Alberta represents the tectonic assembly and evolution of several Archean lithospheric fragments. These fragments underwent episodes of rifting, collision, subduction and melting during the Proterozoic, giving rise to a complex network of tectonic domains with considerable differences in the crustal magnetic and seismic signatures. Observational support for these episodes, e.g., the coeval subduction around the Hearne province, has been limited due to the lack of exposed geology and insufficient teleseismic data prior to 2006. Since mid 2007, the establishment of the Canadian Rockies and Alberta Network (CRANE) has greatly improved the broadband seismic data coverage in central and southern Alberta. Based on 5+ years of CRANE data, we systematically analyze crust and shallow mantle shear velocities through simultaneous inversions of low and high frequency receiver functions. P-to-S converted waves from several stations in central Alberta suggest a significant mid crustal low velocity zone (LVZ), where shear velocity could vary by as much as 35 percent in a depth range of 15-35 km. This structure is not required by the receiver functions from stations along the foothills of the Rocky Mountains. While LVZ of notable magnitudes have been suggested previously in an overlapped part of the study region and attributed to the presence of serpentine or intrusive sill, the spatial dimensions of the anomaly reported in the current study is significantly larger: this anomaly spans hundreds of kilometers horizontally and is generally thicker than 10 km. The presence of mid/lower crustal LVZ in central Alberta is supported by recent group velocity maps based on noise correlation tomography, and the southeastward orientation of this LVZ is consistent with the proposed direction of the subducted oceanic microplate beneath the northwestern Hearne province during the Proterozoic. Still, the cause of the LVZ remains

  1. Mass spectrometric analysis of the composition of shale tar

    SciTech Connect

    Brodskii, E.S.; Lukashenko, I.M.; Rang, S.A.

    1985-01-01

    The composition of the 170-250/sup 0/C fraction of the generator tar from Estonian combustible shales after separation with the aid of thin-layer chromatography and complex-formation with urea has been studied by low-resolution mass spectrometry. Normal alkanes and cycloalkanes containing from one to four rings, alkanes, aromatic hydrocarbons and aliphatic and aromatic oxygen-containing compounds have been identified and determined quantitatively.

  2. Brown carbon in tar balls from smoldering biomass combustion

    NASA Astrophysics Data System (ADS)

    Chakrabarty, R. K.; Moosmüller, H.; Chen, L.-W. A.; Lewis, K.; Arnott, W. P.; Mazzolen, C.; Dubey, M.; Wold, C. E.; Hao, W. M.; Kreidenweis, S. M.

    2010-03-01

    We report the direct observation of large-scale production of spherical, carbonaceous particles - "tar balls" - from smoldering combustion of two commonly occurring dry mid-latitude fuels. Real-time measurements indicate that brown carbon is an important component of tar balls. The spectrum of the imaginary parts of their complex refractive indices can be described with a Lorentzian-like model with an effective resonance wavelength in the ultraviolet (UV) spectral region. Sensitivity calculations for aerosols containing traditional organic carbon (no absorption at visible and UV wavelengths) and brown carbon suggest that accounting for UV absorption by brown carbon leads to a significant increase in aerosol radiative forcing efficiency and increased atmospheric warming. Since particles from smoldering combustion account for nearly three-fourths of the total carbonaceous aerosol mass emitted globally, inclusion of the optical properties of tar balls into radiative forcing models has significance for the Earth's radiation budget, optical remote sensing, and understanding of anomalous UV absorption in the troposphere.

  3. Brown carbon in tar balls from smoldering biomass combustion

    NASA Astrophysics Data System (ADS)

    Chakrabarty, R. K.; Moosmüller, H.; Chen, L.-W. A.; Lewis, K.; Arnott, W. P.; Mazzoleni, C.; Dubey, M. K.; Wold, C. E.; Hao, W. M.; Kreidenweis, S. M.

    2010-07-01

    We report the direct observation of laboratory production of spherical, carbonaceous particles - "tar balls" - from smoldering combustion of two commonly occurring dry mid-latitude fuels. Real-time measurements of spectrally varying absorption Ångström coefficients (AAC) indicate that a class of light absorbing organic carbon (OC) with wavelength dependent imaginary part of its refractive index - optically defined as "brown carbon" - is an important component of tar balls. The spectrum of the imaginary parts of their complex refractive indices can be described with a Lorentzian-like model with an effective resonance wavelength in the ultraviolet (UV) spectral region. Sensitivity calculations for aerosols containing traditional OC (no absorption at visible and UV wavelengths) and brown carbon suggest that accounting for near-UV absorption by brown carbon leads to an increase in aerosol radiative forcing efficiency and increased light absorption. Since particles from smoldering combustion account for nearly three-fourths of the total carbonaceous aerosol mass emitted globally, inclusion of the optical properties of tar balls into radiative forcing models has significance for the Earth's radiation budget, optical remote sensing, and understanding of anomalous UV absorption in the troposphere.

  4. Anomalous surface heave induced by enhanced oil recovery in northern Alberta: InSAR observations and numerical modeling

    NASA Astrophysics Data System (ADS)

    Pearse, Jill; Singhroy, Vern; Samsonov, Sergey; Li, Junhua

    2014-08-01

    Recent interferometric synthetic aperture radar observations over northern Alberta, Canada, show persistent surface heave occurring at rates of 1-4 cm/yr, localized at sites where the steam-assisted gravity drainage technique is currently used to extract bitumen from the Athabasca oil sands. We find that uplift rates above the horizontal injector wells are strongly correlated with rates of steam injection, even though there is a net fluid loss from the reservoir pore space as oil and water are withdrawn through the production wells. In combination with available steam injection and bitumen production data at four sites, we use reservoir flow models to explain how the thermal and geomechanical effects of steam injection on an oil sand reservoir can generate uplift at the surface. Results of our numerical experiments show that persistent surface heave consistent with observed rates can be driven by stress changes in the reservoir due to porous flow and thermal expansion. We also observe an unexpected localized uplift, of magnitude equal to or greater than the heave above the sites of steaming but located at clusters of wellheads which are outside the region of influence of the steam chambers. We show that this "wellhead" deformation can be explained by thermal expansion of rock near the injector wells.

  5. Source Apportionment of Background PAHs in the Peace-Athabasca Delta (Alberta, Canada) Using Molecular Level Radiocarbon Analysis.

    PubMed

    Jautzy, Josué J; Ahad, Jason M E; Hall, Roland I; Wiklund, Johan A; Wolfe, Brent B; Gobeil, Charles; Savard, Martine M

    2015-08-01

    The downstream accumulation of polycyclic aromatic hydrocarbons (PAHs) in the Peace-Athabasca Delta (PAD), an ecologically important landscape, is a key issue of concern given the rapid development of the oil sands industry in Northern Alberta, Canada. In addition to PAHs derived from industrial activity (i.e., oil sands mining) within the Athabasca watershed, however, forest fires and erosion of fossil fuel deposits within both the Athabasca and Peace watersheds are two potentially important natural sources of PAHs delivered to the PAD. Consequently, evaluating the environmental impact of mining activities requires a quantitative understanding of natural, background PAHs. Here, we utilize molecular-level natural-abundance radiocarbon measurements on an amalgamated sediment record from a Peace River flood-susceptible oxbow lake in the northern Peace sector of the PAD to quantitatively discriminate sources of naturally occurring alkylated PAHs (fossil and modern biomass). A radiocarbon mass balance quantified a predominantly natural petrogenic source (93% petrogenic, 7% forest fire) for alkylated PAHs during the past ∼50 years. Additionally, a significant petrogenic component determined for retene, a compound usually considered a biomarker for softwood combustion, suggests that its use as a unique forest fire indicator may not be suitable in PAD sediments receiving Peace watershed-derived fluvial inputs. PMID:26115178

  6. Phenol-formaldehyde resin substitutes from biomass tars

    SciTech Connect

    Himmelblau, D.A.

    1995-11-01

    Approximately 320,000 tonnes of phenol and formaldehyde are currently used annually in North America to make adhesive resins that are used to make exterior-grade structural panels. The demand for phenol-formaldehyde (PF) resins is growing faster than the demand for panels, because more adhesive is required to join/coat the surface of wood flakes (for oriented strand board - OSB) than is required to join veneer; OSB is replacing plywood as logs large enough for veneer become scarcer. Also, competitive uses for phenol and methanol (for making formaldehyde) have increased raw materials cost and threatened availability. Production of adhesive resins from biomass to reduce reliance on raw materials derived from commodity petrochemicals and to lower resin cost looks attractive. A simple fluidized-bed reactor system can be used to produce tars that can substitute for a major portion of the phenol and formaldehyde in PF resin adhesives. This can be done in an air-fluidized, single-bed reactor; no inert gas or dual-bed system is required. The key is recognizing that optimum phenolic character in the tar is not produced at the maximum tar yield, but at reactor temperatures around 600{degrees}C and short gas-phase residence times that produce a yield of about 25 to 30 weight percent. A wide range of phenols, aldehydes and other compounds capable of polymerization are produced. Feedstock can be any wood waste larger than sander dust; low cost agricultural wastes such as bagasse are also suitable. Adhesive resin is produced from the entire tar product by shifting the pH from acidic to basic with NaOH, and combining and heating the resulting resole with phenol and formaldehyde, similarly to conventional resins. Approximately half of the phenol and formaldehyde by weight can be replaced with tar. A plant producing 13,865,000 kg (30,566,000 lb) annually from 308 tonnes (340 tons) per day of green wood chips would cost approximately $8,400,000.

  7. Ecotoxicological impacts of effluents generated by oil sands bitumen extraction and oil sands lixiviation on Pseudokirchneriella subcapitata.

    PubMed

    Debenest, T; Turcotte, P; Gagné, F; Gagnon, C; Blaise, C

    2012-05-15

    The exploitation of Athabasca oil sands deposits in northern Alberta has known an intense development in recent years. This development has raised concern about the ecotoxicological risk of such industrial activities adjacent to the Athabasca River. Indeed, bitumen extraction generated large amounts of oil sands process-affected water (OSPW) which are discharged in tailing ponds in the Athabasca River watershed. This study sought to evaluate and compare the toxicity of OSPW and oil sands lixiviate water (OSLW) with a baseline (oil sands exposed to water; OSW) on a microalgae, Pseudokirchneriella subcapitata, at different concentrations (1.9, 5.5, 12.25, 25 and 37.5%, v/v). Chemical analyses of water-soluble contaminants showed that OSPW and OSLW were enriched in different elements such as vanadium (enrichment factor, EF=66 and 12, respectively), aluminum (EF=64 and 15, respectively), iron (EF=52.5 and 17.1, respectively) and chromium (39 and 10, respectively). The toxicity of OSPW on cells with optimal intracellular esterase activity and chlorophyll autofluorescence (viable cells) (72h-IC 50%<1.9%) was 20 times higher than the one of OSW (72h-IC 50%>37.5%, v/v). OSLW was 4.4 times less toxic (IC 50%=8.5%, v/v) than OSPW and 4.5 times more toxic than OSW. The inhibition of viable cell growth was significantly and highly correlated (<-0.7) with the increase of arsenic, beryllium, chromium, copper, lead, molybdenum and vanadium concentrations. The specific photosynthetic responses studied with JIP-test (rapid and polyphasic chlorophyll a fluorescence emission) showed a stimulation of the different functional parameters (efficiency of PSII to absorb energy from photons, size of effective PSII antenna and vitality of photosynthetic apparatus for energy conversion) in cultures exposed to OSPW and OSLW. To our knowledge, our study highlights the first evidence of physiological effects of OSPW and OSLW on microalgae. PMID:22387878

  8. PROCESSING OF MONAZITE SAND

    DOEpatents

    Calkins, G.D.; Bohlmann, E.G.

    1957-12-01

    A process for the recovery of thorium, uranium, and rare earths from monazite sands is presented. The sands are first digested and dissolved in concentrated NaOH, and the solution is then diluted causing precipitation of uranium, thorium and rare earth hydroxides. The precipitate is collected and dissolved in HCl, and the pH of this solution is adjusted to about 6, precipitating the hydroxides of thorium and uranium but leaving the rare earths in solution. The rare earths are then separated from the solution by precipitation at a still higher pH. The thorium and uranium containing precipitate is redissolved in HNO/sub 3/ and the two elements are separated by extraction into tributyl phosphate and back extraction with a weakly acidic solution to remove the thorium.

  9. Windblown Sand Dunes

    NASA Technical Reports Server (NTRS)

    2003-01-01

    MGS MOC Release No. MOC2-557, 27 November 2003

    This Mars Global Surveyor (MGS) Mars Orbiter Camera (MOC) image shows sand dunes and large ripples in a crater in the Hellespontus region of Mars. The winds that formed these dunes generally blew from the left/lower-left (west/southwest). Unlike the majority of dunes on Earth, sand dunes on Mars are mostly made up of dark, rather than light, grains. This scene is located near 50.3oS, 327.5oW. The image covers an area 3 km (1.9 mi) wide, and is illuminated by sunlight from the upper left.

  10. Dynamic sand dunes.

    PubMed

    Amarouchene, Y; Boudet, J F; Kellay, H

    2001-05-01

    When sand falling in the spacing between two plates goes past an obstacle, a dynamic dune with a parabolic shape and an inner triangular region of nonflowing or slowly creeping sand forms. The angle of the triangular zone increases with the height of the dune and saturates at a value determined by the geometry of the cell. The width of the dune, related to the radius of curvature at the tip, shows universal features versus its height rescaled by geometrical parameters. The velocity profile in the flowing part is determined and found to be nonlinear. The parabolic shape can be accounted for using a simple driven convection-diffusion equation for the interface. PMID:11328156

  11. Biological N2-fixation in Boreal Peatlands of Alberta Canada Following Acute N-Deposition: Down-Regulation and Subsequent Post-Recovery Projections.

    NASA Astrophysics Data System (ADS)

    Vile, M. A.; Fillingim, H.

    2015-12-01

    Globally, boreal peatlands cover a mere 3-4 % of the Earth's land surface, yet store ~ 30% of the world's soil carbon and ~9-16% of global soil nitrogen. Biological N2-fixation is the primary input of new nitrogen (N) to bogs in Alberta. We have demonstrated that this process is down regulated in the presence of enhanced atmospheric N deposition such as that from the growing Oil Sands Mining Operations in northern Alberta Canada. An important question for understanding the long term function of bogs in Alberta is whether N2-fixation can recover upon cessation of N pollution, and if so, how quickly? Here we present our preliminary findings in pursuit of this question. We measured rates of biological N2-fixation using the acetylene reduction assay (ARA), with subsequent calibration using 15N2 on separate, but paired incubations. Sphagnum fuscum from bogs at two different sites from northern Alberta were incubated over the course of 3 years, in 3 experimentally added treatments in the field; controls, plots receiving no added N and no water, water only treatments (no added N), and plots that were fertilized with N at a rate of 20 kg·ha-1·yr-1, and plots which had been fertilized with 20 kg·ha-1·yr-1in 2012-2013, but not since. In 2014, the rates of N2-fixation in the 20 kg·ha-1·yr-1plots and the recovering 20 kg·ha-1·yr-1plots were not significantly different, but both were significantly lower than the controls (p<0.05). In 2015, control plots had significantly higher rates of N2-fixation than the plots that had previously received 20 kg·ha-1·yr-1 in 2012 and 2013, and the plots that had not received 20 kg·ha-1·yr-1 since 2013 had significantly higher rates of biological N2-fixation. These data suggest that in a low atmospheric N deposition scenario, and over a short time frame, peatlands of northern Alberta may be able to recover from chronic atmospheric N deposition.

  12. Dark Sand Dunes

    NASA Technical Reports Server (NTRS)

    2005-01-01

    13 January 2004 This Mars Global Surveyor (MGS) Mars Orbiter Camera (MOC) image shows dark sand dunes in the north polar region of Mars. The dominant winds responsible for these dunes blew from the lower left (southwest). They are located near 76.6oN, 257.2oW. The picture covers an area 3 km (1.9 mi) across; sunlight illuminates the scene from the upper right.

  13. Western gas sands

    SciTech Connect

    Not Available

    1985-03-01

    The purpose of this research is to demonstrate the feasibility of economically producing natural gas from low-permeability reservoirs. Two broad research goals have been defined: (1) reducing the uncertainty of the reservoir production potential, and (2) improving the extraction technology. These goals are being pursued by conducting research and encouraging industrial efforts in developing the necessary technology, including: (1) providing fundamental research into the nature of tight, lenticular gas sands and the technologies for diagnosing and developing them: (2) developing and verifying the technology for effective gas production; and (3) promoting the transfer of research products and technology advances to the gas industry in usable forms. The focus of the research for the last several years has been improving diagnostic instrumentation for reservoir and stimulation performance evaluation, geophysical and engineering interpretation, and stimulation techniques. Integrated geologic studies of three basins containing tight lenticular sands, which were selected by DOE as priority research targets, have also been pursued as part of this new effort. To date, the following tentative conclusions have been formed: Permeability of the tight gas sands can be as much as three to four orders of magnitude lower than that of conventional gas deposits. Nineteen western geologic basins and trends containing significant volumes of tight gas have been identified. Gas resources in the priority geologic basins have been estimated - Piceance Basin 49 Tcf.; Greater Green River Basin, 136 Tcf.; Uinta Basin, 20 Tcf. Presence of natural micro-fractures within a reservoir and the effective propped length of hydraulically induced fratures are the critical parameters for successful development of tight sand resources. Stimulation technology at the present time is insufficient to efficiently recover gas from lenticular tight reservoirs. 8 figs., 3 tabs.

  14. Intricately Rippled Sand Deposits

    NASA Technical Reports Server (NTRS)

    2006-01-01

    [figure removed for brevity, see original site] Click on the image for Intricately Rippled Sand Deposits (QTVR)

    NASA's Mars Exploration Rover Spirit welcomed the beginning of 2006 on Earth by taking this striking panorama of intricately rippled sand deposits in Gusev Crater on Mars. This is an approximate true-color rendering of the 'El Dorado' ripple field provided by Spirit over the New Year's holiday weekend. The view spans about 160 degrees in azimuth from left to right and consists of images acquired by Spirit's panoramic camera on Spirit's 708th and 710th Martian days, or sols, (Dec. 30, 2005 and Jan. 1, 2006). Spirit used the Pancam's 750-nanometer, 530-nanometer and 430-nanometer filters to capture the colors on Mars. Scientists have eliminated seams between individual frames in the sky portion of the mosaic to better simulate the vista a person standing on Mars would see. Spirit spent several days acquiring images, spectral data, and compositional and mineralogical information about these large sand deposits before continuing downhill toward 'Home Plate.'

  15. Metal catalysts for steam reforming of tar derived from the gasification of lignocellulosic biomass.

    PubMed

    Li, Dalin; Tamura, Masazumi; Nakagawa, Yoshinao; Tomishige, Keiichi

    2015-02-01

    Biomass gasification is one of the most important technologies for the conversion of biomass to electricity, fuels, and chemicals. The main obstacle preventing the commercial application of this technology is the presence of tar in the product gas. Catalytic reforming of tar appears a promising approach to remove tar and supported metal catalysts are among the most effective catalysts. Nevertheless, improvement of catalytic performances including activity, stability, resistance to coke deposition and aggregation of metal particles, as well as catalyst regenerability is greatly needed. This review focuses on the design and catalysis of supported metal catalysts for the removal of tar in the gasification of biomass. The recent development of metal catalysts including Rh, Ni, Co, and their alloys for steam reforming of biomass tar and tar model compounds is introduced. The role of metal species, support materials, promoters, and their interfaces is described. PMID:25455089

  16. Forensic source differentiation of petrogenic, pyrogenic, and biogenic hydrocarbons in Canadian oil sands environmental samples.

    PubMed

    Wang, Zhendi; Yang, C; Parrott, J L; Frank, R A; Yang, Z; Brown, C E; Hollebone, B P; Landriault, M; Fieldhouse, B; Liu, Y; Zhang, G; Hewitt, L M

    2014-04-30

    To facilitate monitoring efforts, a forensic chemical fingerprinting methodology has been applied to characterize and differentiate pyrogenic (combustion derived) and biogenic (organism derived) hydrocarbons from petrogenic (petroleum derived) hydrocarbons in environmental samples from the Canadian oil sands region. Between 2009 and 2012, hundreds of oil sands environmental samples including water (snowmelt water, river water, and tailings pond water) and sediments (from river beds and tailings ponds) have been analyzed. These samples were taken from sites where assessments of wild fish health, invertebrate communities, toxicology and detailed chemistry are being conducted as part of the Canada-Alberta Joint Oil Sands Monitoring Plan (JOSMP). This study describes the distribution patterns and potential sources of PAHs from these integrated JOSMP study sites, and findings will be linked to responses in laboratory bioassays and in wild organisms collected from these same sites. It was determined that hydrocarbons in Athabasca River sediments and waters were most likely from four sources: (1) petrogenic heavy oil sands bitumen; (2) biogenic compounds; (3) petrogenic hydrocarbons of other lighter fuel oils; and (4) pyrogenic PAHs. PAHs and biomarkers detected in snowmelt water samples collected near mining operations imply that these materials are derived from oil sands particulates (from open pit mines, stacks and coke piles). PMID:24632369

  17. Groundwater Flow and Salt Transport at a Sand Tailings Dam: Field Observations and Modelling Results.

    NASA Astrophysics Data System (ADS)

    Price, A. C.; Mendoza, C. A.

    2004-05-01

    Large volumes of sand tailings are produced during the extraction of bitumen from the oil sands of Northeastern Alberta. The long-term groundwater response and subsequent movement of water and solutes within the large permeable sand tailings storage areas is uncertain. At the Southwest Sand Storage (SWSS) Facility, located at Syncrude's Mildred Lake operations near Ft. McMurray, there is concern that salts from the tailings water may discharge to newly placed reclamation material that covers the sand tailings. This saline discharge water could destroy the reclamation soil structure and negatively impact vegetation. The steady-state groundwater flow and transient movement of salts at the local (bench and slope) and intermediate (pile) scales in the SWSS are investigated. Water levels, seepage and groundwater quality (including TDS) have been measured for over a year along two transects of piezometers installed in the SWSS. The field data have been used to complete traditional hydrogeological interpretations of the site, and to develop a conceptual model of flow and transport. The local and intermediate flow systems and salt transport in the dam are being evaluated with numerical models. The models will allow possible future hydrogeological behaviour of the structure to be tested. Preliminary results show differences in flow systems and salinity distribution that depend on the deposition of the SWSS. This research will facilitate better long-term environmental management of this and similar sites.

  18. Microbial processes in the Athabasca Oil Sands and their potential applications in microbial enhanced oil recovery.

    PubMed

    Harner, N K; Richardson, T L; Thompson, K A; Best, R J; Best, A S; Trevors, J T

    2011-11-01

    The Athabasca Oil Sands are located within the Western Canadian Sedimentary Basin, which covers over 140,200 km(2) of land in Alberta, Canada. The oil sands provide a unique environment for bacteria as a result of the stressors of low water availability and high hydrocarbon concentrations. Understanding the mechanisms bacteria use to tolerate these stresses may aid in our understanding of how hydrocarbon degradation has occurred over geological time, and how these processes and related tolerance mechanisms may be used in biotechnology applications such as microbial enhanced oil recovery (MEOR). The majority of research has focused on microbiology processes in oil reservoirs and oilfields; as such there is a paucity of information specific to oil sands. By studying microbial processes in oil sands there is the potential to use microbes in MEOR applications. This article reviews the microbiology of the Athabasca Oil Sands and the mechanisms bacteria use to tolerate low water and high hydrocarbon availability in oil reservoirs and oilfields, and potential applications in MEOR. PMID:21853326

  19. Booming Sand Dunes

    NASA Astrophysics Data System (ADS)

    Vriend, Nathalie

    "Booming" sand dunes are able to produce low-frequency sound that resembles a pure note from a music instrument. The sound has a dominant audible frequency (70-105 Hz) and several higher harmonics and may be heard from far distances away. A natural or induced avalanche from a slip face of the booming dune triggers the emission that may last for several minutes. There are various references in travel literature to the phenomenon, but to date no scientific explanation covered all field observations. This thesis introduces a new physical model that describes the phenomenon of booming dunes. The waveguide model explains the selection of the booming frequency and the amplification of the sound in terms of constructive interference in a confined geometry. The frequency of the booming is a direct function of the dimensions and velocities in the waveguide. The higher harmonics are related to the higher modes of propagation in the waveguide. The experimental validation includes quantitative field research at the booming dunes of the Mojave Desert and Death Valley National Park. Microphone and geophone recordings of the acoustic and seismic emission show a variation of booming frequency in space and time. The analysis of the sensor data quantifies wave propagation characteristics such as speed, dispersion, and nonlinear effects and allows the distinction between the source mechanism of the booming and the booming itself. The migration of sand dunes results from a complicated interplay between dune building, wind regime, and precipitation. The morphological and morphodynamical characteristics of two field locations are analyzed with various geophysical techniques. Ground-penetrating radar images the subsurface structure of the dunes and reveal a natural, internal layering that is directly related to the history of dune migration. The seismic velocity increases abruptly with depth and gradually increases with downhill position due to compaction. Sand sampling shows local

  20. Alberta's systems approach to chronic disease management and prevention utilizing the expanded chronic care model.

    PubMed

    Delon, Sandra; Mackinnon, Blair

    2009-01-01

    Alberta's integrated approach to chronic disease management programming embraces client-centred care, supports self-management and facilitates care across the continuum. This paper presents strategies implemented through collaboration with primary care to improve care of individuals with chronic conditions, evaluation evidence supporting success and lessons learned from the Alberta perspective. PMID:20057258

  1. The Principal Quality Practice Guideline: Promoting Successful School Leadership in Alberta

    ERIC Educational Resources Information Center

    Alberta Education, 2009

    2009-01-01

    This Principal Quality Practice Guideline (PQPG) represents a first step in a process to develop a framework for quality school leadership in Alberta. It includes a statement on Principal Quality Practice and seven leadership dimensions, with supporting descriptors, reflecting the Alberta context. The PQPG is to be used as a basis for many…

  2. Exploring Principals' Perceptions of Applications, Benefits, and Barriers of Alberta's SuperNet

    ERIC Educational Resources Information Center

    Anderson, Terry; Christiansen, Jo-An

    2007-01-01

    The Alberta SuperNet, a very high speed, broadband network, was built to bring high-speed connectivity to every school, library, and municipal office in Alberta. This CDN $294 million investment was made based on the perceived need for high-speed connectivity to stimulate economic and community development and to enhance government services,…

  3. A Financial Plan for Alberta Colleges and Universities: Recommendations and Research Results.

    ERIC Educational Resources Information Center

    Sheehan, Bernard S.; And Others

    This is the final report of the Financial Plan Project for Colleges and Universities. Its primary purpose is to present proposals on a financial plan for Alberta universities and public colleges. Following a brief review of financing postsecondary education in Canada, it focuses on the last ten years of Alberta practice; the treatment is…

  4. Research and Development Project Behavior Management Services Northwest Alberta. Final Report.

    ERIC Educational Resources Information Center

    Dennis, S.; Stierhoff, K. A.

    The study examines the status of behavioral management services for disabled persons in Alberta, Canada, and offers recommendations regarding alternative service delivery models for the Northwest Region of Alberta. Existing systems are addressed in terms of centralized service models, outreach service models, and combined residential and outreach…

  5. Alberta Initiative for School Improvement: AISA Handbook for Cycle 4. 2009-2012

    ERIC Educational Resources Information Center

    Alberta Education, 2008

    2008-01-01

    The Alberta Initiative for School Improvement (AISI) is a bold approach to improving student learning by encouraging teachers, parents, and the community to work collaboratively to introduce innovative projects that address local needs. Initiated in 1999 by the Alberta Government and its partners, AISI provides targeted funding to school…

  6. Government Policy and Postsecondary Education in Alberta: A "Field Theory" Analysis

    ERIC Educational Resources Information Center

    Schmaus, David; Wimmer, Randolph

    2013-01-01

    While the landscape of postsecondary education in Alberta continues to expand and diversify, there seems to be very little written about the organization of postsecondary education in the province over the past 15 to 20 years (Wimmer & Schmaus, 2010). This paper provides an analysis of postsecondary education in Alberta over the past 15 to 20…

  7. Visions 2000. A Vision of Educational Technology in Alberta by the Year 2000. A Discussion Paper.

    ERIC Educational Resources Information Center

    Alberta Dept. of Education, Edmonton.

    Arguing that technology should be incorporated into the curriculum so that students learn "about technology,""in technology," and "through technology," the Alberta Technology in Education Committee looks forward to the year 2000 and assesses ways in which technology can be applied both in the classroom and in distance education in Alberta, Canada.…

  8. Maintaining the Momentum. Alberta Apprenticeship and Industry Training Board, 2002-2003 Annual Report.

    ERIC Educational Resources Information Center

    Alberta Learning, Edmonton. Apprenticeship and Industry Training.

    Alberta's apprenticeship system offers training in 50 designated trades and 4 designated occupations and includes 40,398 registered apprentices and 11,1984 employers. The main components of Alberta's apprenticeship and training system are as follows: (1) a network of local and provincial apprenticeship committees in the designated occupations; (2)…

  9. Alberta Post-Secondary Graduate Outcomes Survey: 2005-06 Transfer Graduates

    ERIC Educational Resources Information Center

    Alberta Advanced Education and Technology, 2008

    2008-01-01

    In November of 2007, Alberta Advanced Education and Technology contracted Insightrix Research, Inc. to conduct a survey of individuals who graduated from post-secondary institutions in Alberta in the fall of 2005 or the spring of 2006 (excluding apprenticeship graduates, who are surveyed through a separate initiative). The purpose of the survey is…

  10. Alberta Post-Secondary Graduate Outcomes Survey: Class of 2005-06

    ERIC Educational Resources Information Center

    Alberta Advanced Education and Technology, 2008

    2008-01-01

    In November of 2007, Alberta Advanced Education and Technology contracted Insightrix Research, Inc. to conduct a survey of individuals who graduated from post-secondary institutions in Alberta in the fall of 2005 or the spring of 2006 (excluding apprenticeship graduates, who are surveyed through a separate initiative). The purpose of the survey is…

  11. Alberta Post-Secondary Graduate Outcomes Survey: Class of 2003/2004

    ERIC Educational Resources Information Center

    Alberta Advanced Education and Technology, 2006

    2006-01-01

    In November of 2005, Alberta Advanced Education contracted Insightrix Research Services to conduct a survey of individuals who graduated from four Alberta universities, eight university colleges, fifteen public colleges and two technical institutes in the fall of 2003 or the spring of 2004 (excluding apprenticeship graduates, who are surveyed…

  12. The Support Service Approach to University Education for Native Students in Alberta.

    ERIC Educational Resources Information Center

    Moore-Eyman, Evelyn

    Of the four universities within the Province of Alberta, the University of Calgary has most effectively met the bicultural needs of Native students. Athabasca University's correspondence courses are usually not effective for Native students. The University of Alberta's "Morningstar" program allows teacher certification before completion of degrees…

  13. Satisfaction with Education in Alberta Survey, 2007/08. Summary Report

    ERIC Educational Resources Information Center

    Alberta Education, 2008

    2008-01-01

    Alberta Education conducts a set of annual telephone surveys to obtain feedback from education system stakeholders regarding their perceptions of Alberta's education system. Respondents for the survey include senior high school students, parents of children in the K-12 education system, parents of children with severe special needs, teachers in…

  14. The Politics of Educational Reform: The Alberta Charter School Experiment 20 Years Later

    ERIC Educational Resources Information Center

    Bosetti, Lynn; Butterfield, Phil

    2016-01-01

    In this paper we examine the public charter school movement in the Province of Alberta, Canada over the past 20 years to determine how charter school policy and regulations have limited and controlled the impact of charter schools on public education. Specifically we focus on the extent to which charter schools in Alberta fulfilled the aims and…

  15. Deformation analysis of terrestrial monitoring observations on Turtle Mountain, Alberta

    NASA Astrophysics Data System (ADS)

    Ebeling, Axel; Chow, Jacky; Teskey, W. F.

    2011-05-01

    Deformation monitoring has been carried out in two epochs on Turtle Mountain, Alberta, using a high-precision total station and a terrestrial laser scanner. From the total station observations, coordinates have been computed for seven signalized target points in a least-squares network adjustment. Then, a deformation analysis using a Multi-Parameter Transformation has been performed to derive movements between epochs. The two point clouds obtained with the laser scanner were registered using the iterative closest point algorithm. Differences in elevation between the two point clouds were then derived for the entire scene. Results indicate a downward movement of South Peak, and no significant horizontal deformations were found.

  16. Asthma-related productivity losses in Alberta, Canada

    PubMed Central

    Thanh, Nguyen X; Ohinmaa, Arto; Yan, Charles

    2009-01-01

    Objectives: To estimate the number and cost of asthma-related productivity loss days due to absenteeism and presenteeism (at work but not fully functioning) in Alberta in 2005. Methods: Using data from the 2005 Canadian Community Health Survey, this study focused on people of working age (18–64 years), who reported having an asthma diagnosis. Total asthma-related disability days, including in-bed days and activity-restricted days, were estimated by multiplying the difference in the means of total disability days between asthmatics and nonasthmatics adjusted for sociodemographic characteristics and other health conditions by a multiple linear regression, with the number of asthmatics in the population. Number of productivity loss days was a sum between the number of in-bed days (absenteeism) and the number of activity-restricted days multiplied by a reduction in functional level (presenteeism), adjusted for five working days per week. Other data from Alberta or Canadian published literature, such as a reduction in functional level of 20%–30%, a labor participation rate of 73%, and an average wage of $158 per day in 2005, were also used for analyses. Results: The prevalence of asthma was estimated at 8.5% among approximately 2.1 million people of working age in Alberta in 2005. The difference in the means of total disability days between asthmatics and nonasthmatics was 0.487 (95% CI: 0.286–0.688) in a period of two weeks or 12.7 (7.5–17.9) in one year. With the reduction in functional level of 20%–30%, the number of asthma-related productivity loss days was estimated from 442 (259–624) to 533 (313–753) thousand, respectively. The corresponding cost was from $70 ($41–$99) to $84 ($49–$119) million. Of these, the presenteeism accounted for 42% to 52%. Conclusions: The results suggest that an improvement in the controlling of asthma could have a significant economic impact in Alberta and that presenteeism plays an important role in asthma

  17. Pesticide and PCB levels in fish from Alberta (Canada)

    SciTech Connect

    Chovelon, A.; George, L.; Gulayets, C.; Hoyano, Y.; McGuinness, E.; Moore, J.; Ramamoorthy, S.; Ramamoorthy, S.; Singer, P.; Smiley, K.

    1984-01-01

    Pesticide and PCB analyses were completed on fat and muscle samples of 750 fish collected from 11 major lakes and rivers in Alberta. Although phenoxy and organophosphate residues were always below detectable limits, traces of chlorinated pesticides and their derivatives, particularly DDE, DDD and chlordane, were detected in most fat samples. PCB levels exceeded 25 mg/kg in the fat of several species from the North Saskatchewan River but were generally lower in the other systems. Analysis of 160 sediment samples from the North Saskatchewan River revealed no point source of PCB contamination.

  18. Selected Alberta science and research success stories. Volume 2

    SciTech Connect

    1996-12-31

    This publication provides a sampling of the value of science and research to Albertans, to the Alberta economy, and to the global community as revealed in stories of successful science and research activities in the province. Each story includes name of developer, inventor, company, and/or supporter; names of co-operating agencies, if any; contact name and address for further information; and a list of expected or realized benefits. The stories are organized under subject areas relating to agriculture and agri-food, arts and culture, biotechnology, construction, education, energy, environment, forest sector, health and medicine, human and community development, information and communications, manufacturing, mineral sector, tourism, and transportation.

  19. Role of TAR RNA splicing in translational regulation of simian immunodeficiency virus from rhesus macaques.

    PubMed Central

    Viglianti, G A; Rubinstein, E P; Graves, K L

    1992-01-01

    The untranslated leader sequences of rhesus macaque simian immunodeficiency virus mRNAs form a stable secondary structure, TAR. This structure can be modified by RNA splicing. In this study, the role of TAR splicing in virus replication was investigated. The proportion of viral RNAs containing a spliced TAR structure is high early after infection and decreases at later times. Moreover, proviruses containing mutations which prevent TAR splicing are significantly delayed in replication. These mutant viruses require approximately 20 days to achieve half-maximal virus production, in contrast to wild-type viruses, which require approximately 8 days. We attribute this delay to the inefficient translation of unspliced-TAR-containing mRNAs. The molecular basis for this translational effect was examined in in vitro assays. We found that spliced-TAR-containing mRNAs were translated up to 8.5 times more efficiently than were similar mRNAs containing an unspliced TAR leader. Furthermore, these spliced-TAR-containing mRNAs were more efficiently associated with ribosomes. We postulate that the level of TAR splicing provides a balance for the optimal expression of both viral proteins and genomic RNA and therefore ultimately controls the production of infectious virions. Images PMID:1629957

  20. Literacy, More Than Words: Summary of Input on a Literacy Framework for Alberta. Pan-Canadian Interactive Literacy Forum

    ERIC Educational Resources Information Center

    Alberta Advanced Education and Technology, 2008

    2008-01-01

    This document summarizes comments from 539 individuals on a literacy framework for Alberta, provided during the Alberta Literacy Forum held in Edmonton from April 14 to 16, 2008. The Forum was Alberta's contribution to the Council of Ministers of Education, Canada (CMEC) Pan-Canadian Interactive Literacy Forum, which involved all of Canada's…

  1. Sedimentology of paleochannels on foreland coastal plain, Judith River Formation (upper Cretaceous), southeast Alberta

    SciTech Connect

    Koster, E.H.

    1984-04-01

    The upper 90 m (295 ft) of the sub-Bearpaw Judith River Formation, continuously exposed in the badlands along the Red Deer River 185 km (115 mi) east of Calgary, is famous for the unrivaled assemblage of dinosaur fossils. Dinosaur Provincial Park presents are a rare opportunity to view the architecture of a foreland coastal-plain sequence as well as to clarify the origin and distribution of subbituminous coal zones and gas reservoirs associated with this formation across southeast Alberta. The distal reaches of paleodrainage from the developing Cordillera to the Western Interior seaway are being examined by north-south traversed across the badlands. Sharp-based paleochannel units, enclosed by rooted, olive-gray mudstone sequences that are commonly 4-6 m (13-20 ft) thick, vary between 2 end members. The first contains laterally accreted sand-mud couplets with abundant macrofloral debris, and represents cyclical, low-energy growth of point bars, possible with an estuarine influence. The second, mainly comprising cosets of large trough cross-beds with mudstone intraclasts, was formed by episodic aggradation of high-energy systems. An intermediate composite type displays evidence for an energy increase as channel sinuosity decreased. This variation in paleochannel type is attributed to alternating alluviation/rejuvenation associated with an unstable base level. Coal zones and potential reservoirs appear to be associated with the transgressive and regressive phases, respectively, of the Bearpaw coast. Amalgamation of paleochannels - marked by laterally extensive horizons of bone fragments, lithic and intraclastic gravel - is more common seaward over the axial region of the Sweetgrass arch.

  2. Transverse Aeolian Ridges (TARs) on Mars II: Distributions, orientations, and ages

    NASA Astrophysics Data System (ADS)

    Berman, Daniel C.; Balme, Matthew R.; Rafkin, Scot C. R.; Zimbelman, James R.

    2011-05-01

    Transverse Aeolian Ridges (TARs), 10 m scale, ripple-like aeolian bedforms with simple morphology, are widespread on Mars but it is unknown what role they play in Mars' wider sediment cycle. We present the results of a survey of all Mars Global Surveyor Narrow angle images in a pole-to-pole study area, 45° longitude wide. Following on from the classification scheme and preliminary surveys of Balme et al. (Balme, M.R., Berman, D.C., Bourke, M.C., Zimbelman, J.R. [2008a]. Geomorphology 101, 703-720) and Wilson and Zimbelman (Wilson, S.A., Zimbelman, J.R. [2004]. J. Geophys. Res. 109 (E10). doi: 10.1029/2004JE002247) we searched more than 10,000 images, and found that over 2000 reveal at least 5% areal cover by TARs. The mean TAR areal cover in the study area is about 7% (3% in the northern hemisphere and 11% in the southern hemisphere) but TARs are not homogenously distributed - they are concentrated in the mid-low latitudes and almost absent poleward of 35°N and 55°S. We found no clear correlation between TAR distribution and any of thermal inertia, kilometer-scale roughness, or elevation. We did find that TARs are less common at extremes of elevation. We found that TARs are most common near the equator (especially in the vicinity of Meridiani Planum, in which area they have a distinctive "barchan-like" morphology) and in large southern-hemisphere impact craters. TARs in the equatorial band are usually associated with outcrops of layered terrain or steep slopes, hence their relative absence in the northern hemisphere. TARs in the southern hemisphere are most commonly associated with low albedo, intercrater dune fields. We speculate that the mid-latitude mantling terrain (e.g., Mustard, J.F., Cooper, C.D., Rifkin, M.K. [2001]. Nature 412, 411-414; Kreslavsky, M.A., Head, J.W. [2002]. J. Geophys. Res. 29 (15). doi: 10.1029/2002GL015392) could also play a role in covering TARs or inhibiting saltation. We compared TAR distribution with general circulation model (GCM

  3. Sand Dunes, Afghanistan

    NASA Technical Reports Server (NTRS)

    2001-01-01

    This ASTER image covers an area of 10.5 x 15 km in southern Afghanistan and was acquired on August 20, 2000. The band 3-2-1 composite shows part of an extensive field of barchan sand dunes south of Kandahar. The shape of the dunes indicates that the prevailing wind direction is from the west. The image is located at 30.7 degrees north latitude and 65.7 degrees east longitude.

    The U.S. science team is located at NASA's Jet Propulsion Laboratory, Pasadena, Calif. The Terra mission is part of NASA's Science Mission Directorate.

  4. Ganges Rocks and Sand

    NASA Technical Reports Server (NTRS)

    2005-01-01

    17 January 2004 The top half of this Mars Global Surveyor (MGS) Mars Orbiter Camera (MOC) image shows wind-eroded remnants of sedimentary rock outcrops in Ganges Chasma, one of the troughs of the Valles Marineris system. The lower half shows a thick accumulation of dark, windblown sand. The image covers an area about 3 km (1.9 mi) wide and is illuminated by sunlight from the upper left. These features are located near 7.6oS, 49.4oW.

  5. Fortune Cookie Sand Dunes

    NASA Technical Reports Server (NTRS)

    2003-01-01

    MGS MOC Release No. MOC2-432, 25 July 2003

    This Mars Global Surveyor (MGS) Mars Orbiter Camera (MOC) image shows a field of small barchan sand dunes in the north polar region near 71.7oN, 51.3oW. Some of them are shaped like fortune cookies. The message these dunes provide: winds blow through this region from the lower right toward the upper left. The steep slip face slopes of these dunes, which point toward the upper left, indicate the wind direction. The scene is illuminated by sunlight from the upper right. The image is 3 km (1.9 mi) wide.

  6. Sand dollar sites orogenesis

    NASA Astrophysics Data System (ADS)

    Amos, Dee

    2013-04-01

    The determinology of the humble sand dollars habitat changing from inception to the drastic evolution of the zone to that of present day. Into the cauldron along the southern Californian 'ring of fire' lithosphere are evidence of geosynclinals areas, metasedimentary rock formations and hydrothermal activity. The explanation begins with 'Theia' and the Moon's formation, battles with cometary impacts, glacial ages, epochs with evolutionary bottlenecks and plate tectonics. Fully illustrated the lecture includes localised diagrams and figures with actual subject photographic examples of plutonic, granitic, jade and peridodite. Finally, the origins of the materials used in the lecture are revealed for prosecution by future students and the enjoyment of interested parties in general.

  7. Defrosting Sand Dunes

    NASA Technical Reports Server (NTRS)

    2003-01-01

    MGS MOC Release No. MOC2-434, 27 July 2003

    This Mars Global Surveyor (MGS) Mars Orbiter Camera (MOC) picture shows retreating patches of frost on a field of large, dark sand dunes in the Noachis region of Mars. Large, windblown ripples of coarse sediment are also seen on some of the dunes. This dune field is located in a crater at 47.5oS, 326.3oW. The scene is illuminated by sunlight from the upper left.

  8. Sand Dunes in Hellas

    NASA Technical Reports Server (NTRS)

    2003-01-01

    MGS MOC Release No. MOC2-537, 7 November 2003

    The smooth, rounded mounds in this Mars Global Surveyor (MGS) Mars Orbiter Camera (MOC) picture are sand dunes. The scene is located in southern Hellas Planitia and was acquired in mid-southern autumn, the ideal time of year for Hellas imaging. Sunlight illuminates the scene from the upper left. These dunes are located near 49.1oS, 292.6oW. The picture covers an area 3 km (1.9 mi) wide.

  9. Alberta Soil Moisture Analyses using CaLDAS

    NASA Astrophysics Data System (ADS)

    Dyck, S.; Carrera, M. L.; Belair, S.; Abrahamowicz, M.; Husain, S.; Bilodeau, B.; Gauthier, N.

    2012-12-01

    In order to improve soil moisture analyses, used to initialize numerical prediction systems, Environment Canada has developed the new Canadian Land Data Assimilation System (CaLDAS). CaLDAS uses the Global Environment Multi-scale (GEM) off-line land surface model and has been configured to assimilate Soil Moisture Ocean Salinity (SMOS) L-band soil moisture brightness temperatures using an Ensemble Kalman Filter framework and the Community Microwave Emission Modelling Platform as the radiative transfer forward model. One of the biggest challenges so far has been to correct the systematic dry bias of the off-line land surface model in order to provide an accurate first guess in which to assimilate SMOS brightness temperatures. Using a network of soil moisture stations in Alberta [Alberta Agriculture and Rural Development] we have improved and validated parameterizations using the Interactions between Soil, Biosphere, and Atmosphere (ISBA) land surface scheme. Results will be presented for the off-line model both alone and with the assimilation of bias corrected SMOS brightness temperatures for the summers of 2010 and 2012.

  10. Community mental health nursing in Alberta, Canada: an oral history.

    PubMed

    Boschma, Geertje

    2012-01-01

    Community mental health nurses had a central role in the construction of new rehabilitative practices and community mental health services in the 1960s and 1970s. The purpose of this article is, first, to explore how nurses understood and created their new role and identity in the turbulent context of deinstitutionalization. The development of after care services for patients discharged from Alberta Hospital in Ponoka (AH-Ponoka), a large mental institution in Calgary, in the Canadian province of Alberta, will be used as a case study. I specifically focus on the establishment of outpatient services in a new psychiatric department at Foothills General Hospital in Calgary. Second, I examine how deinstitutionalization itself shaped community mental health nurses' work. Oral history interviews with nurses and other mental health professionals, who had a central role in this transformation process, provide a unique lens through which to explore this social change. The article concludes that new rehabilitative, community-based mental health services can better be understood as a transformation of former institutional practices rather than as a definite break with them. PMID:22360000

  11. Sage-grouse habitat selection during winter in Alberta

    USGS Publications Warehouse

    Carpenter, J.; Aldridge, C.; Boyce, M.S.

    2010-01-01

    Greater sage-grouse (Centrocercus urophasianus) are dependent on sagebrush (Artemisia spp.) for food and shelter during winter, yet few studies have assessed winter habitat selection, particularly at scales applicable to conservation planning. Small changes to availability of winter habitats have caused drastic reductions in some sage-grouse populations. We modeled winter habitat selection by sage-grouse in Alberta, Canada, by using a resource selection function. Our purpose was to 1) generate a robust winter habitat-selection model for Alberta sage-grouse; 2) spatially depict habitat suitability in a Geographic Information System to identify areas with a high probability of selection and thus, conservation importance; and 3) assess the relative influence of human development, including oil and gas wells, in landscape models of winter habitat selection. Terrain and vegetation characteristics, sagebrush cover, anthropogenic landscape features, and energy development were important in top Akaike's Information Criterionselected models. During winter, sage-grouse selected dense sagebrush cover and homogenous less rugged areas, and avoided energy development and 2-track truck trails. Sage-grouse avoidance of energy development highlights the need for comprehensive management strategies that maintain suitable habitats across all seasons. ?? 2010 The Wildlife Society.

  12. Compressive behavior of fine sand.

    SciTech Connect

    Martin, Bradley E.; Kabir, Md. E.; Song, Bo; Chen, Wayne

    2010-04-01

    The compressive mechanical response of fine sand is experimentally investigated. The strain rate, initial density, stress state, and moisture level are systematically varied. A Kolsky bar was modified to obtain uniaxial and triaxial compressive response at high strain rates. A controlled loading pulse allows the specimen to acquire stress equilibrium and constant strain-rates. The results show that the compressive response of the fine sand is not sensitive to strain rate under the loading conditions in this study, but significantly dependent on the moisture content, initial density and lateral confinement. Partially saturated sand is more compliant than dry sand. Similar trends were reported in the quasi-static regime for experiments conducted at comparable specimen conditions. The sand becomes stiffer as initial density and/or confinement pressure increases. The sand particle size become smaller after hydrostatic pressure and further smaller after dynamic axial loading.

  13. Effect of wastewater treatment processes on the pyrolysis properties of the pyrolysis tars from sewage sludges

    NASA Astrophysics Data System (ADS)

    Wu, Xia; Xie, Li-Ping; Li, Xin-Yu; Dai, Xiao-Hong; Fei, Xue-Ning; Jiang, Yuan-Guang

    2011-06-01

    The pyrolysis properties of five different pyrolysis tars, which the tars from 1# to 5# are obtained by pyrolyzing the sewage sludges of anaerobic digestion and indigestion from the A2/O wastewater treatment process, those from the activated sludge process and the indigested sludge from the continuous SBR process respectively, were studied by thermal gravimetric analysis at a heating rate of 10 °C/min in the nitrogen atmosphere. The results show that the pyrolysis processes of the pyrolysis tars of 1#, 2#, 3# and 5# all can be divided into four stages: the stages of light organic compounds releasing, heavy polar organic compounds decomposition, heavy organic compounds decomposition and the residual organic compounds decomposition. However, the process of 4# pyrolysis tar is only divided into three stages: the stages of light organic compounds releasing, decomposition of heavy polar organic compounds and the residual heavy organic compounds respectively. Both the sludge anaerobic digestion and the "anaerobic" process in wastewater treatment processes make the content of light organic compounds in tars decrease, but make that of heavy organic compounds with complex structure increase. Besides, both make the pyrolysis properties of the tars become worse. The pyrolysis reaction mechanisms of the five pyrolysis tars have been studied with Coats-Redfern equation. It shows that there are the same mechanism functions in the first stage for the five tars and in the second and third stage for the tars of 1#, 2#, 3# and 5#, which is different with the function in the second stage for 4# tar. The five tars are easy to volatile.

  14. Identification of sources of tar balls deposited along the Southwest Caspian Coast, Iran using fingerprinting techniques.

    PubMed

    Shirneshan, Golshan; Bakhtiari, Alireza Riyahi; Memariani, Mahmoud

    2016-10-15

    In 2012, a significant number of tar balls occurred along the Southwest coasts of the Caspian Sea (Iran). Several oil fields of Turkmenistan, Azerbaijan and Iran might be sources of oil spills and lead to the formation of these tar balls. For source identification, 6 tar ball samples were collected from the Southwest beaches of the Caspian Sea and subjected to fingerprint analysis based on the distribution of the source-specific biomarkers of pentacyclic tri-terpanes and steranes. Comparing the diagenic ratios revealed that the tar balls were chemically similar and originated from the same source. Results of double ratio plots (e.g., C29/C30 versus ∑C31-C35/C30 and C28 αββ/(C27 αββ+C29 αββ) versus C29 αββ/(C27 αββ+C28 αββ)) in the tar balls and oils from Iran, Turkmenistan and Azerbaijan indicated that the tar balls might be the result of spills from Turkmenistan oil. Moreover, principle component analysis (PCA) using biomarker ratios on the tar balls and 20 crude oil samples from different wells of Azerbaijan, Iran and Turkmenistan oils showed that the tar balls collected at the Southwest beaches are highly similar to the Turkmenistan oil but one of the Azerbaijan oils (from Bahar field oils) was found to be also slightly close to the tar balls. The weathering characterizations based on the presence of UCM (unresolved complex mixture) and low/high molecular weight ratios (L/H) of alkanes and PAHs indicated the tar ball samples have been significantly influenced by natural weathering processes such as evaporation, photo-degradation and biodegradation. This is the first study of its kind in Iran to use fingerprinting for source identification of tar balls. PMID:27369093

  15. The extraction of bitumen from western oil sands. Annual report, July 1991--July 1992

    SciTech Connect

    Oblad, A.G.; Bunger, J.W.; Dahlstrom, D.A.; Deo, M.D.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1992-08-01

    The University of Utah tar sand research and development program is concerned with research and development on Utah is extensive oil sands deposits. The program has been intended to develop a scientific and technological base required for eventual commercial recovery of the heavy oils from oil sands and processing these oils to produce synthetic crude oil and other products such as asphalt. The overall program is based on mining the oil sand, processing the mined sand to recover the heavy oils and upgrading them to products. Multiple deposits are being investigated since it is believed that a large scale (approximately 20,000 bbl/day) plant would require the use of resources from more than one deposit. The tasks or projects in the program are organized according to the following classification: Recovery technologies which includes thermal recovery methods, water extraction methods, and solvent extraction methods; upgrading and processing technologies which covers hydrotreating, hydrocracking, and hydropyrolysis; solvent extraction; production of specialty products; and environmental aspects of the production and processing technologies. These tasks are covered in this report.

  16. Do peat amendments to oil sands wet sediments affect Carex aquatilis biomass for reclamation success?

    PubMed

    Roy, Marie-Claude; Mollard, Federico P O; Foote, A Lee

    2014-06-15

    The oil sands industries of Alberta (Canada) have reclamation objectives to return the mined landscape to equivalent pre-disturbance land capability. Industrial operators are charged with reclaiming a vast landscape of newly exposed sediments on saline-sodic marine-shales sediments. Incorporated in these sediments are by-products resulting from bitumen extraction (consolidated tailings (CT), tailings-sand (TS), and oil sands processed water (OSPW)). A sedge community dominated by Carex aquatilis was identified as a desirable and representative late-succession community for wet-meadow zones of oil sands-created marshes. However, the physical and chemical conditions, including high salinity and low nutrient content of CT and TS sediments suppress plant growth and performance. We experimentally tested the response of C. aquatilis to amendments with peat-mineral-mix (PM) on oil sand sediments (CT and TS). In a two factorial design experiment, we also tested the effects of OSPW on C. aquatilis. We assessed survival, below- and aboveground biomass, and physiology (chlorophyll a fluorescence). We demonstrated that PM amendments to oil sands sediments significantly increased C. aquatilis survival as well as below and aboveground biomass. The use of OSPW significantly reduced C. aquatilis belowground biomass and affected its physiological performance. Due to its tolerance and performance, we verified that C. aquatilis was a good candidate for use in reclaiming the wet-meadow zones of oil sands-created marshes. Ultimately, amending CT and TS with PM expedited the reclamation of the wetland to a C. aquatilis-community which was similar in gross structure to undisturbed wetlands of the region. PMID:24694323

  17. Investigation of the rank dependence of tar evolution

    SciTech Connect

    Freihaut, J.D.; Proscia, W.M.

    1990-01-01

    Despite its high nitrogen concentration levels relative to the parent coal samples, 7.2% vs. 1.4 - 2.0%, little volatile nitrogen evolution is observed until decomposition temperatures of 600[degree]C or greater are obtained. Due to the lack of decomposition via tar evolution and as contrasted to parent coals, no significant bound nitrogen is evolved with heavy hydrocarbons at particle temperatures less than 600[degree]C. Similar to virgin'' chars and tars formed during rapid devolatilization, the polyimide samples begin to evolve significant fractions of bound nitrogen as IR-active light gases at particle temperatures between 650 and 750[degree]C. Unlike coal samples, however, relatively large fractions of the light gases are observed to be ammonia. The IR-active, nitrogen-containing light gas evolution rapidly declines at polyimide char temperatures greater than 750[degree]C, again in contrast to observed behavior in virgin coal char samples. It is not certain if the nitrogen evolution kinetics changes from selectively forming ammonia and hydrogen cyanide to benzonitriles or free nitrogen at these temperatures. The light gas evolution pattern with decomposition temperature of polymide could contribute to our understanding of the low conversion efficiencies observed for bound nitrogen to NO[sub x] conversion in the char combustion phase of pfc combustion.

  18. Parameter study of ICRH wave propagation in IShTAR

    NASA Astrophysics Data System (ADS)

    Crombé, K.; van Eester, D.

    2016-04-01

    > A crude first assessment of how waves behave is commonly made relying on decoupled dispersion equation roots. In the low density, low temperature region behind the last closed flux surface in a tokamak - where the density decays exponentially and where the lower hybrid resonance is crossed but where the thermal velocity is small enough to justify dropping kinetic (hot plasma) effects - the study of the wave behaviour requires the roots of the full cold plasma dispersion equation. The IShTAR (Ion cyclotron Sheath Test ARrangement) device will be adopted in the coming years to shed light on the dynamics of wave-plasma interactions close to radio frequency (RF) launchers and in particular on the impact of the waves on the density and their role in the formation of RF sheaths close to metallic objects. As IShTAR is incapable of mimicking the actual conditions reigning close to launchers in tokamaks; a parameter range needs to be identified for the test stand to permit highlighting of the relevant wave physics. Studying the coupled dispersion equation roots allowed us to find a suitable operation domain for performing experiments.

  19. Elevated Nitrogen Deposition Enhances the Net CO2 Sink Strength in Alberta Bogs along a Post-fire Chronosequence

    NASA Astrophysics Data System (ADS)

    Wieder, R. K.; Vile, M. A.; Albright, C. M.; Scott, K. D.

    2014-12-01

    About 30% of the landscape of northern Alberta, Canada is occupied by peatlands, which persist at the low end range of both mean annual precipitation (<500 mm/yr) and mean annual atmospheric nitrogen (N) deposition (< 1 kg/ha/yr) across which peatlands are found globally. Ombrotrophic bogs in this region function as a net sink for atmospheric CO2 of over 75 g/m2/yr, taking into consideration changes in CO2 sink strength as a function of time since fire. In addition to fire, a new disturbance is emerging in the Athabasca Oil Sands Region (AOSR) of northern Alberta, where development of the oil sands resource has increased atmospheric N deposition to as much as 2.5 kg/ha/yr. To examine the effects of elevated N deposition on bog C cycling, we experimentally applied N (as NH4NO3 solutions) to replicated plots at levels equivalent to 0 (water added with no N), 10, and 20 kg/ha/yr, and controls (no waher, no N added) at five bog sites, aged at 2, 12, 32, 73, and 113 years since fire in 2013 (6 plots per N treatment per site). Understory net ecosystem exchange of CO2 (NEE) was measured repeatedly throughout the 2013 and 2014 growing season (and in 2011 and 2012 at the most recently burned site) using the closed chamber approach. Using a rectangular hyperbola equation to characterize NEE as a function of photosynthetically active radiation (PAR) and near-surface air temperature (T), monthly and annual NEE was estimated based on hourly measurements of PAR and T at each site. Across all sites, a general pattern emerged that N additions enhanced the net CO2 sink strength of the bogs, with no effect on ecosystem respiration. Net primary production of Sphagnum fuscum, the dominant peat-forming moss, was not affected by N addition, suggesting that the overall response of NEE to N addition is the result of enhanced growth of ericaceous shrubs. These findings suggest that while elevated N deposition in the AOSR may enhance the strength of the overall CO2 sink of bogs in the short

  20. Relationship Between the Composition and Interfacial Tension of Former Manufactured Gas Plant Tars

    NASA Astrophysics Data System (ADS)

    Hauswirth, S.; Birak, P. S.; Miller, C. T.

    2011-12-01

    Former manufactured gas plant (FMGP) tars pose significant environmental hazards and present a challenge to regulators and industry professionals. The tars, which were produced as a byproduct of the gas manufacturing process, were frequently released into the environment through improper disposal or leaks in plant infrastructure. The interfacial tension (IFT) is a primary factor controlling the mobility of tars in porous media, and is therefore important to understand for both predicting the migration of tars and designing remediation strategies. In this study, we characterized nine field-collected FMGP tars and a commercially available coal tar by means of chemical extractions (asphaltenes, resins, acids, and bases), gas chromatography-mass spectrometry (GC-MS), and Fourier transform infrared (FTIR) spectroscopy. Additionally, the IFT and contact angle of each tar was determined for a pH range of 3-11. The IFT was found to be similar for all tars at pH 5 and 7 regardless of composition. Slight decreases in IFT at lower pH were correlated with higher concentrations of extractable bases, which consisted primarily of nitrogen-containing heterocyclic aromatic compounds. Much greater reductions of IFT were observed at high pH. These reductions were found to be associated with the presence of carbonyl or carboxyl groups in the asphaltenes. It is likely that the larger size of the asphaltene molecules (as compared to the extractable compounds) resulted in species with greater surface activity when ionized.

  1. 29 CFR 1926.1102 - Coal tar pitch volatiles; interpretation of term.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 29 Labor 8 2012-07-01 2012-07-01 false Coal tar pitch volatiles; interpretation of term. 1926.1102 Section 1926.1102 Labor Regulations Relating to Labor (Continued) OCCUPATIONAL SAFETY AND HEALTH... Hazardous Substances § 1926.1102 Coal tar pitch volatiles; interpretation of term. Note: The...

  2. 29 CFR 1915.1002 - Coal tar pitch volatiles; interpretation of term.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 29 Labor 7 2010-07-01 2010-07-01 false Coal tar pitch volatiles; interpretation of term. 1915.1002 Section 1915.1002 Labor Regulations Relating to Labor (Continued) OCCUPATIONAL SAFETY AND HEALTH... Toxic and Hazardous Substances § 1915.1002 Coal tar pitch volatiles; interpretation of term. Note:...

  3. 29 CFR 1926.1102 - Coal tar pitch volatiles; interpretation of term.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 29 Labor 8 2014-07-01 2014-07-01 false Coal tar pitch volatiles; interpretation of term. 1926.1102 Section 1926.1102 Labor Regulations Relating to Labor (Continued) OCCUPATIONAL SAFETY AND HEALTH... Hazardous Substances § 1926.1102 Coal tar pitch volatiles; interpretation of term. Note: The...

  4. 29 CFR 1915.1002 - Coal tar pitch volatiles; interpretation of term.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 29 Labor 7 2013-07-01 2013-07-01 false Coal tar pitch volatiles; interpretation of term. 1915.1002 Section 1915.1002 Labor Regulations Relating to Labor (Continued) OCCUPATIONAL SAFETY AND HEALTH... Toxic and Hazardous Substances § 1915.1002 Coal tar pitch volatiles; interpretation of term. Note:...

  5. 29 CFR 1926.1102 - Coal tar pitch volatiles; interpretation of term.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 29 Labor 8 2010-07-01 2010-07-01 false Coal tar pitch volatiles; interpretation of term. 1926.1102 Section 1926.1102 Labor Regulations Relating to Labor (Continued) OCCUPATIONAL SAFETY AND HEALTH... Hazardous Substances § 1926.1102 Coal tar pitch volatiles; interpretation of term. Note: The...

  6. 29 CFR 1926.1102 - Coal tar pitch volatiles; interpretation of term.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 29 Labor 8 2011-07-01 2011-07-01 false Coal tar pitch volatiles; interpretation of term. 1926.1102 Section 1926.1102 Labor Regulations Relating to Labor (Continued) OCCUPATIONAL SAFETY AND HEALTH... Hazardous Substances § 1926.1102 Coal tar pitch volatiles; interpretation of term. Note: The...

  7. 29 CFR 1915.1002 - Coal tar pitch volatiles; interpretation of term.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 29 Labor 7 2012-07-01 2012-07-01 false Coal tar pitch volatiles; interpretation of term. 1915.1002 Section 1915.1002 Labor Regulations Relating to Labor (Continued) OCCUPATIONAL SAFETY AND HEALTH... Toxic and Hazardous Substances § 1915.1002 Coal tar pitch volatiles; interpretation of term. Note:...

  8. 29 CFR 1915.1002 - Coal tar pitch volatiles; interpretation of term.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 29 Labor 7 2014-07-01 2014-07-01 false Coal tar pitch volatiles; interpretation of term. 1915.1002 Section 1915.1002 Labor Regulations Relating to Labor (Continued) OCCUPATIONAL SAFETY AND HEALTH... Toxic and Hazardous Substances § 1915.1002 Coal tar pitch volatiles; interpretation of term. Note:...

  9. 29 CFR 1915.1002 - Coal tar pitch volatiles; interpretation of term.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 29 Labor 7 2011-07-01 2011-07-01 false Coal tar pitch volatiles; interpretation of term. 1915.1002 Section 1915.1002 Labor Regulations Relating to Labor (Continued) OCCUPATIONAL SAFETY AND HEALTH... Toxic and Hazardous Substances § 1915.1002 Coal tar pitch volatiles; interpretation of term. Note:...

  10. Nuclear Factor 90(NF90) targeted to TAR RNA inhibits transcriptional activation of HIV-1

    PubMed Central

    Agbottah, Emmanuel T; Traviss, Christine; McArdle, James; Karki, Sambhav; St Laurent, Georges C; Kumar, Ajit

    2007-01-01

    Background Examination of host cell-based inhibitors of HIV-1 transcription may be important for attenuating viral replication. We describe properties of a cellular double-stranded RNA binding protein with intrinsic affinity for HIV-1 TAR RNA that interferes with Tat/TAR interaction and inhibits viral gene expression. Results Utilizing TAR affinity fractionation, North-Western blotting, and mobility-shift assays, we show that the C-terminal variant of nuclear factor 90 (NF90ctv) with strong affinity for the TAR RNA, competes with Tat/TAR interaction in vitro. Analysis of the effect of NF90ctv-TAR RNA interaction in vivo showed significant inhibition of Tat-transactivation of HIV-1 LTR in cells expressing NF90ctv, as well as changes in histone H3 lysine-4 and lysine-9 methylation of HIV chromatin that are consistent with the epigenetic changes in transcriptionally repressed gene. Conclusion Structural integrity of the TAR element is crucial in HIV-1 gene expression. Our results show that perturbation Tat/TAR RNA interaction by the dsRNA binding protein is sufficient to inhibit transcriptional activation of HIV-1. PMID:17565699

  11. Structural Analysis of the Ligand-Binding Domain of the Aspartate Receptor Tar from Escherichia coli.

    PubMed

    Mise, Takeshi

    2016-07-01

    The Escherichia coli cell-surface aspartate receptor Tar mediates bacterial chemotaxis toward an attractant, aspartate (Asp), and away from a repellent, Ni(2+). These signals are transmitted from the extracellular region of Tar to the cytoplasmic region via the transmembrane domain. The mechanism by which extracellular signals are transmitted into the cell through conformational changes in Tar is predicted to involve a piston displacement of one of the α4 helices of the homodimer. To understand the molecular mechanisms underlying the induction of Tar activity by an attractant, the three-dimensional structures of the E. coli Tar periplasmic domain with and without bound aspartate, Asp-Tar and apo-Tar, respectively, were determined. Of the two ligand-binding sites, only one site was occupied, and it clearly showed the electron density of an aspartate. The slight changes in conformation and the electrostatic surface potential around the aspartate-binding site were observed. In addition, the presence of an aspartate stabilized residues Phe-150' and Arg-73. A pistonlike displacement of helix α4b' was also induced by aspartate binding as predicted by the piston model. Taken together, these small changes might be related to the induction of Tar activity and might disturb binding of the second aspartate to the second binding site in E. coli. PMID:27292793

  12. Cultivation of yeast on light-oil fractions of hard-coal tar

    SciTech Connect

    Kucher, R.V.; Dzumeozei, N.V.; Pavlyuk, M.I.; Tyrovskii, A.A.

    1982-01-01

    The results are given of experiments on the cultivation of the yeast Candida tropicalis on light-oil fractions of coal-tar. It has been shown that a light fraction can serve as the sole source of carbon and energy. Surface active agents stimulate the growth of the yeast on the light-oil fractions of hard-coal tar.

  13. 78 FR 41691 - Safety Zone; Pamlico River and Tar River; Washington, NC

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-07-11

    ...) 366-9826. SUPPLEMENTARY INFORMATION: ] Table of Acronyms DHS Department of Homeland Security FR... SECURITY Coast Guard 33 CFR Part 165 RIN 1625-AA00 Safety Zone; Pamlico River and Tar River; Washington, NC... zone on the navigable waters of the Pamlico and Tar Rivers in Washington, NC in support of a...

  14. Theater as Representation (TAR) in the Teaching of Teacher and Administrator Preparation Programs

    ERIC Educational Resources Information Center

    Meyer, Matthew J.

    2004-01-01

    Theater as representation (TAR) has been used in pre-service and in-service teacher and administrator preparation programs since 1998. This paper places TAR within a pedagogical arena that further solidifies its place as an instrument for leadership professional development in B.Ed., M.Ed., and in-service programs. Maxine Greene (1995) challenges…

  15. Purifying filter-clogging coal tar formed from low-temperature coal carbonization

    SciTech Connect

    Kokot, H.; Romey, I.

    1980-11-04

    A process is provided for purifying filter-clogging coal tar residue of the type obtained by low-temperature carbonization of coal. Such coal tar residues include viscous organic coal tar constituents, particulate solid impurities and liquid water. Applicants' process includes the step of heating coal at 450*-700* C. At least substantially in the absence of air to thereby decompose the coal to products including coal tar, the coal tar being of the type containing liquid water, particulate solid impurities, and viscous organic coal tar constituents including light oils, the light oils incidentally combining with the liquid water to produce a filter-clogging emulsion. The thusformed coal tar is then heated to a temperature above the boiling point of water and sufficiently high to thereby distill off substantially all of the water and the light oils to thereby obtain an intermediate product which is substantially free from the presence of liquid water and light oil constituents which in combination form a filter-clogging emulsion. Finally, the intermediate product is subsequently filtered to thereby separate the particulate solid impurities from the undistilled viscous constituents of the coal tar.

  16. Microbial metabolism alters pore water chemistry and increases consolidation of oil sands tailings.

    PubMed

    Arkell, Nicholas; Kuznetsov, Petr; Kuznetsova, Alsu; Foght, Julia M; Siddique, Tariq

    2015-01-01

    Tailings produced during bitumen extraction from surface-mined oil sands ores (tar sands) comprise an aqueous suspension of clay particles that remain dispersed for decades in tailings ponds. Slow consolidation of the clays hinders water recovery for reuse and retards volume reduction, thereby increasing the environmental footprint of tailings ponds. We investigated mechanisms of tailings consolidation and revealed that indigenous anaerobic microorganisms altered porewater chemistry by producing CO and CH during metabolism of acetate added as a labile carbon amendment. Entrapped biogenic CO decreased tailings pH, thereby increasing calcium (Ca) and magnesium (Mg) cations and bicarbonate (HCO) concentrations in the porewater through dissolution of carbonate minerals. Soluble ions increased the porewater ionic strength, which, with higher exchangeable Ca and Mg, decreased the diffuse double layer of clays and increased consolidation of tailings compared with unamended tailings in which little microbial activity was observed. These results are relevant to effective tailings pond management strategies. PMID:25602329

  17. Microwave-induced cracking of pyrolytic tars coupled to microwave pyrolysis for syngas production.

    PubMed

    Beneroso, D; Bermúdez, J M; Montes-Morán, M A; Arenillas, A; Menéndez, J A

    2016-10-01

    Herein a new process is proposed to produce a syngas-rich gas fraction (>80vol% H2+CO) from biowaste based on microwave heating within two differentiated steps in order to avoid tars production. The first step consists of the microwave pyrolysis of biowaste induced by a char-based susceptor at 400-800°C; tars, char and syngas-rich gas fractions being produced. The tars are then fed into the second step where a portion of the char from the first step is used as a bed material in a 0.3:1wt% ratio. This bed is heated up by microwaves up to 800°C, allowing thermal cracking of tars and additional syngas (>90vol% H2+CO) being then produced. This new concept arises as an alternative technology to the gasification of biowastes for producing syngas with no need for catalysts or gasifying reagents to minimise tars production. PMID:27420155

  18. Task 3.9 -- Catalytic tar cracking. Semi-annual report, January 1--June 30, 1995

    SciTech Connect

    Young, B.C.; Timpe, R.C.

    1995-12-31

    Tar produced in the gasification of coal is deleterious to the operation of downstream equipment including fuel cells, gas turbines, hot-gas stream cleanup filters, and pressure swing adsorption systems. Catalytic cracking of tars to smaller hydrocarbons can be an effective means to remove these tars from gas streams and, in the process, generate useful products, e.g., methane gas, which is crucial to the operation of molten carbonate fuel cells. The objectives of this project are to investigate whether gasification tars can be cracked by synthetic nickel-substituted micamontmorillonite, zeolite, or dolomite material; and whether the tars can be cracked selectively by these catalysts to produce a desired liquid and/or gas stream. Results to date are presented in the cited papers.

  19. Science Learning in the Sand.

    ERIC Educational Resources Information Center

    Sexton, Ursula

    1997-01-01

    Presents activities that allow students to think about the Earth in a contextual manner and become familiar with constructive and destructive processes as they relate to sand - its origins, cyclical processes, and yielding of new products. Explores the bigger idea with a developmentally appropriate study of water, rocks, sand, physical phenomena,…

  20. Sand and Dust on Mars

    NASA Technical Reports Server (NTRS)

    Greeley, Ronald; Haberle, Robert M.

    1991-01-01

    Mars is a planet of high scientific interest. Various studies are currently being made that involve vehicles that have landed on Mars. Because Mars is known to experience frequent wind storms, mission planners and engineers require knowledge of the physical and chemical properties of Martian windblown sand and dust, and the processes involved in the origin and evolution of sand and dust storms.

  1. Vacuum Head Removes Sanding Dust

    NASA Technical Reports Server (NTRS)

    Bengle, C. G.; Holt, J. W.

    1982-01-01

    Vacuum sander prevents sanding dust from entering a work area, since dust particles are drawn off as quickly as they are produced. Tool is useful where dust presents health hazards, interferes with such processes as semiconductor manufacture, or could destroy wet paint or varnish finishes. Could be used to sand such materials as lead paint.

  2. Assessing accumulation and biliary excretion of naphthenic acids in yellow perch exposed to oil sands-affected waters.

    PubMed

    van den Heuvel, Michael R; Hogan, Natacha S; MacDonald, Gillian Z; Berrue, Fabrice; Young, Rozlyn F; Arens, Collin J; Kerr, Russell G; Fedorak, Phillip M

    2014-01-01

    Naphthenic acids are known to be the most prevalent group of organic compounds in oil sands tailings-associated waters. Yellow perch (Perca flavescens) were exposed for four months to oil sands-influenced waters in two experimental systems located on an oil sands lease 30 km north of Fort McMurray Alberta: the Demonstration Pond, containing oil sands tailings capped with natural surface water, and the South Bison Pond, integrating lean oil sands. Yellow perch were also sampled from three lakes: Mildred Lake that receives water from the Athabasca River, Sucker Lake, at the edge of oil sands extraction activity, and Kimowin Lake, a distant reference site. Naphthenic acids were measured in perch muscle tissue using gas chromatography-mass spectrometry (GC-MS). Bile metabolites were measured by GC-MS techniques and by high performance liquid chromatography (HPLC) with fluorescence detection at phenanthrene wavelengths. A method was developed using liquid chromatography-high resolution mass spectrometry (LC-HRMS) to evaluate naphthenic acids in bile. Tissue analysis did not show a pattern of naphthenic acids accumulation in muscle tissue consistent with known concentrations in exposed waters. Bile fluorescence and LC-HRMS methods were capable of statistically distinguishing samples originating from oil sands-influenced waters versus reference lakes. Although the GC-MS and HPLC fluorescence methods were correlated, there were no significant correlations of these methods and the LC-HRMS method. In yellow perch, naphthenic acids from oil sands sources do not concentrate in tissue at a measurable amount and are excreted through a biliary route. LC-HRMS was shown to be a highly sensitive, selective and promising technique as an indicator of exposure of biota to oil sands-derived naphthenic acids. PMID:24182406

  3. Energy and environmental research emphasizing low-rank coal: Task 3.9 catalytic tar cracking

    SciTech Connect

    Timpe, R.C.

    1995-09-01

    Tar produced in the gasification of coal is deleterious to the operation of downstream equipment, including fuel cells, gas turbines, hot-gas stream cleanup filters, and pressure-swing absorption systems. Catalytic cracking of tars to smaller hydrocarbons can be an effective means of removing these tars from gas streams and, in the process, generating useful products, such as methane gas, which is crucial to operation of molten carbonate fuel cells. Aerosol tars are not readily removed from gas streams by conventional means and, as a consequence, often end up plugging filters or fouling fuel cells, turbines, or sorbents. Catalytic cracking of these tars to molecular moieties of C{sub 10} or smaller would prevent the problems commonly attributed to the tars. As an example, the moving Bourdon fixed-bed gasifier, by virtue of its efficient countercurrent heat exchange and widespread commercial use, may offer the lowest-cost integrated gasification combined-cycle (IGCC) system if tar generation and wastewater contamination can be minimized. We evaluate the potential of selected catalysts to minimize tar accumulation and maximize char conversion to useful liquid and/or gaseous products. Owing to the potential for production of extremely toxic nickel carbonyl gas, care must be exercised in the use of a NISMM catalyst for cracking tars at high temperatures in reducing atmospheres such as those produced by coal gasification. We observed a fifty percent or more of tar produced during steam gasification of Beulah lignite at temperatures of 400{degrees}-800+{degrees}C when cracked by either dolomite or zeolite maintained at a temperature of 50{degrees}C-100{degrees}C below that of the reactor.

  4. Atlas of Dutch drift sands

    NASA Astrophysics Data System (ADS)

    Riksen, Michel; Jungerius, Pieter

    2013-04-01

    The Netherlands is well known for its aeolian landscapes. Frequent storms during the High Middle Ages (1000-1300 AD) reactivated Pleistocene coversands and river dunes and are responsible for the formation of the Holocene drift sands at a scale which is unique for Europe. A hypothesized relationship with farmer practices for making plaggensoils has recently been refuted, because drift sand formation began centuries earlier. The coastal dune belt with their parabolic dunes dates from the same period as the drift sand. An estimate of the extent of drift sands can be made from soil maps: drift sands are too young to show much profile development (Regosols). With this method Koster estimated the maximum extent of Holocene drift sands in the Netherlands to be about 800 km2 (Koster 2005). Laser altimetry allows a more precise estimate of the total surface affected by wind from the characteristic relief patterns produced by the Holocene wind, which is different from the smooth surface of cover sand deposits. Laser altimetry has been used before to investigate the mechanism of drift sand formation (Jungerius & Riksen 2010). Most of the surface affected by wind is not active anymore, but the tell-tale rough surface survived ages of different landuse. The total affected surface amounts to 825 km2. It is noteworthy that both methods give comparable results. We recorded a total number of 367 of affected areas of varying shapes, ranging in size from 1.6 ha to a large complex of drif sands of 7,119.5 ha. As is to be expected from their mode of origin, most occurrences are associated with cover sands, and with river dunes along the river Meuse and smaller rivers in other parts of the country. Particularly the final phases of cover sand and river dunes that show more relief as parabolic dunes were affected. There are also small aeolian deposits at the lee side blown from fallow agricultural fields but they are (sub)recent. Most of the relief is irregular, but the larger

  5. Unchanging Desert Sand Dunes

    NASA Astrophysics Data System (ADS)

    Gadhiraju, S.; Banerjee, B.; Buddhiraju, K.; Shah, V.

    2013-12-01

    Deserts are one of the major landforms on earth. They occupy nearly 20% of the total land area but are relatively less studied. With the rise in human population, desert regions are being gradually occupied for settlement posing a management challenge to the concerned authorities. Unrestrained erosion is generally a feature of bare dunes. Stabilized dunes, on the other hand, do not undergo major changes in textures, and can thus facilitate the growth of vegetation. Keeping in view of the above factors, better mapping and monitoring of deserts and particularly of sand dunes is needed. Mapping dunes using field instruments is very arduous and they generate relatively sparse data. In this communication, we present a method of clustering and monitoring sand dunes through imagery captured by remote sensing sensors. Initially Radon spectrum of an area is obtained by decomposition of the image into various projections sampled at finer angular directions. Statistical features such as mode, entropy and standard deviation of Radon spectrum are used in delineation and clustering of regions with different dune orientations. These clustered boundaries are used to detect if there are any changes occurring in the dune regions. In the experiment's, remote sensing data covering various dune regions of the world are observed for possible changes in dune orientations. In all the cases, it is seen that there are no major changes in desert dune orientations. While these findings have implications for understanding of dune geomorphology and changes occurring in dune directions, they also highlight the importance of a wider study of dunes and their evolution both at regional and global scales. Results for Dataset 1 & Dataset 2 Results for Dataset 3

  6. Sand and Water

    NASA Technical Reports Server (NTRS)

    2003-01-01

    [figure removed for brevity, see original site]

    Released 7 November 2003

    This image shows a relatively small crater (35 km across) in the heavily cratered terrain of the southern highlands. At the midlatitudes, this area is known both for its water-formed gullies and its sand dunes. This crater shows spectacular examples of both. In fact, the gullies running down the northern edge of the crater made it to the cover of Science magazine on June 30, 2000. The large dark spot in the floor of the crater is sand that has accumulated into one large dune with a single curvilinear crest.

    Image information: VIS instrument. Latitude -54.9, Longitude 17.5 East (342.5 West). 19 meter/pixel resolution.

    Note: this THEMIS visual image has not been radiometrically nor geometrically calibrated for this preliminary release. An empirical correction has been performed to remove instrumental effects. A linear shift has been applied in the cross-track and down-track direction to approximate spacecraft and planetary motion. Fully calibrated and geometrically projected images will be released through the Planetary Data System in accordance with Project policies at a later time.

    NASA's Jet Propulsion Laboratory manages the 2001 Mars Odyssey mission for NASA's Office of Space Science, Washington, D.C. The Thermal Emission Imaging System (THEMIS) was developed by Arizona State University, Tempe, in collaboration with Raytheon Santa Barbara Remote Sensing. The THEMIS investigation is led by Dr. Philip Christensen at Arizona State University. Lockheed Martin Astronautics, Denver, is the prime contractor for the Odyssey project, and developed and built the orbiter. Mission operations are conducted jointly from Lockheed Martin and from JPL, a division of the California Institute of Technology in Pasadena.

  7. The geometry of folds in granitoid rocks of northeastern Alberta

    NASA Astrophysics Data System (ADS)

    Willem Langenberg, C.; Ramsden, John

    1980-06-01

    Granitoid rocks which predominate in the Precambrian shield of northeastern Alberta show large-scale fold structures. A numerical procedure has been used to obtain modal foliation orientations. This procedure results in the smoothing of folded surfaces that show roughness on a detailed scale. Statistical tests are used to divide the study areas into cylindrical domains. Structural sections can be obtained for each domain, and horizontal and vertical sections are used to construct block diagrams. The projections are performed numerically and plotted by computer. This method permits blocks to be viewed from every possible angle. Both perspective and orthographic projections can be produced. The geometries of a dome in the Tulip Lake area and a synform in the Hooker Lake area have been obtained. The domal structure is compared with polyphase deformational interference patterns and with experimental diapiric structures obtained in a centrifuge system. The synform in the Hooker Lake area may be genetically related to the doming in the Tulip Lake area.

  8. Care of the elderly program at the University of Alberta

    PubMed Central

    Charles, Lesley; Dobbs, Bonnie; Triscott, Jean; McKay, Rhianne

    2014-01-01

    Abstract Problem addressed The population is aging rapidly and there are implications for health care delivery in the face of few physicians specializing in care of the elderly (COE). Objective of program To train physicians wishing to provide COE services. Program description The COE program at the University of Alberta in Edmonton is an enhanced skills diploma program lasting 6 months to 1 year, with core program requirements including geriatric inpatient care, geriatric psychiatry, ambulatory care, continuing care, and outreach. There is a longitudinal clinic component and a research project requirement. The program is designed to cover the 85 core competencies in the CanMEDS– Family Medicine roles. Conclusion There is a need for COE physicians to provide clinical care as well as fill educational, administrative, and research roles to meet the health care needs of medically complex seniors. These physicians require alternative funding and a departmental home within a university if they are to provide an academic service. PMID:25551143

  9. NUANCE: Naturalistic University of Alberta Nonlinear Correlation Explorer.

    PubMed

    Hollis, Geoff; Westbury, Chris

    2006-02-01

    In this article, we describe the Naturalistic University of Alberta Nonlinear Correlation Explorer (NUANCE), a computer program for data exploration and analysis. NUANCE is specialized for finding nonlinear relations between any number of predictors and a dependent value to be predicted. It searches the space of possible relations between the predictors and the dependent value by using natural selection to evolve equations that maximize the correlation between their output and the dependent value. In this article, we introduce the program, describe how to use it, and provide illustrative examples. NUANCE is written in Java, which runs on most computer platforms. We have contributed NUANCE to the archival Web site of the Psychonomic Society (www.psychonomic.org/archive), from which it may be freely downloaded. PMID:16817509

  10. Petrogenesis of the Late Cretaceous northern Alberta kimberlite province

    NASA Astrophysics Data System (ADS)

    Eccles, D. Roy; Heaman, Larry M.; Luth, Robert W.; Creaser, Robert A.

    2004-09-01

    At present, 48 Late Cretaceous (ca. 70-88 Ma) kimberlitic pipes have been discovered in three separate areas of the northern Alberta: the Mountain Lake cluster, the Buffalo Head Hills field and the Birch Mountains field. The regions can be distinguished from one another by their non-archetypal kimberlite signature (Mountain Lake) or, in the case of kimberlite fields, primitive (Buffalo Head Hills) to evolved (Birch Mountains) magmatic signatures. The dominant process of magmatic differentiation is crystal fractionation and accumulation of olivine, which acts as the main criteria to distinguish between primitive and evolved Group I-type kimberlite fields in the northern Alberta. This is important from the viewpoint of diamond exploration because the majority (about 80%) of the more primitive Buffalo Head Hills kimberlites are diamondiferous, whereas the more evolved Birch Mountains pipes are barren of diamonds for the most part. Petrographically, the Buffalo Head Hills samples are distinct from the Birch Mountains samples in that they contain less carbonate, have a smaller modal abundance of late-stage minerals such as phlogopite and ilmenite, and have a higher amount of fresh, coarse macrocrystal (>0.5 mm) olivine. Consequently, samples from the Buffalo Head Hills have the highest values of MgO, Cr and Ni, and have chemistries similar to those of primitive hypabyssal kimberlite in the Northwest Territories. Based on whole-rock isotopic data, the Buffalo Head Hills K6 kimberlite has 87Sr/ 86Sr and ɛNd values similar to those of South African Group I kimberlites, whereas the Birch Mountains Legend and Phoenix kimberlites have similar ɛNd values (between 0 and +1.9), but distinctly higher 87Sr/ 86Sr values (0.7051-0.7063). The lack of whole-rock geochemical overlap between kimberlite and the freshest, least contaminated Mountain Lake South pipe rocks reflects significant mineralogical differences and Mountain Lake is similar geochemically to olivine alkali basalt

  11. Nutrition Education Practices and Opinions of Alberta Family Physicians

    PubMed Central

    Kelly, S. Ann; Joffres, Michel R.

    1990-01-01

    A questionnaire was mailed to a random sample of 532 members of the Alberta Chapter of the College of Family Physicians in order to assess the role of physicians in providing nutrition education to their patients. Of the 255 respondents (53% response rate), over 97% agreed that “educating patients about nutrition is an important role for physicians.” Physicians most often gave nutrition information on obesity, constipation, heart disease and hypertension, alcohol, coffee, infant feeding, osteoporosis, and prenatal nutrition. Female physicians gave nutrition information significantly more often than male physicians on four maternal and child health topics. Perceived barriers to nutrition education included lack of reimbursement for physicians (86%), lack of time (48%), and limited access to patient information (42%). Most physicians often informed patients on the seven most common nutrition topics despite these concerns. PMID:21249103

  12. Strategic Clinical Networks: Alberta's Response to Triple Aim.

    PubMed

    Noseworthy, Tom; Wasylak, Tracy; O'Neill, Blair J

    2016-01-01

    Verma and Bhatia make a compelling case for the Triple Aim to promote health system innovation and sustainability. We concur. Moreover, the authors offer a useful categorization of policies and actions to advance the Triple Aim under the "classic functions" of financing, stewardship and resource generation (Verma and Bhatia 2016). The argument is tendered that provincial governments should embrace the Triple Aim in the absence of federal government leadership, noting that, by international standards, we are at best mediocre and, more realistically, fighting for the bottom in comparative, annual cross-country surveys. Ignoring federal government participation in Medicare and resorting solely to provincial leadership seems to make sense for the purposes of this discourse; but, it makes no sense at all if we are attempting to achieve high performance in Canada's non-system (Canada Health Action: Building on the Legacy 1997; Commission on the Future of Health Care in Canada 2002; Lewis 2015). As for enlisting provincial governments, we heartily agree. A great deal can be accomplished by the Council of the Federation of Canadian Premiers. But, the entire basis for this philosophy and the reference paper itself assumes a top-down approach to policy and practice. That is what we are trying to change in Alberta and we next discuss. Bottom-up clinically led change, driven by measurement and evidence, has to meet with the top-down approach being presented and widely practiced. While true for each category of financing, stewardship and resource generation, in no place is this truer than what is described and included in "health system stewardship." This commentary draws from Verma and Bhatia (2016) and demonstrates how Alberta, through the use of Strategic Clinical Networks (SCNs), is responding to the Triple Aim. We offer three examples of provincially scaled innovations, each representing one or more arms of the Triple Aim. PMID:27009587

  13. Development of wear resistant nanostructured duplex coatings by high velocity oxy-fuel process for use in oil sands industry.

    PubMed

    Saha, Gobinda C; Khan, Tahir I; Glenesk, Larry B

    2009-07-01

    Oil sands deposits in Northern Alberta, Canada represent a wealth of resources attracting huge capital investment and significant research focus in recent years. As of 2005, crude oil production from the current oil sands operators accounted for 50% of Canada's domestic production. Alberta's oil sands deposits contain approximately 1.7 trillion barrels of bitumen, of which over 175 billion are recoverable with current technology, and 315 billion barrels are ultimately recoverable with technological advances. A major problem of operating machinery and equipment in the oil sands is the unpredictable failure from operating in this highly aggressive environment. One of the significant causes of that problem is premature material wear. An approach to minimize this wear is the use of protective coatings and, in particular, a cermet thin coating. A high level of coating homogeneity is critical for components such as bucketwheels, draglines, conveyors, shovels, heavyhauler trucks etc. that are subjected to severe degradation through abrasive wear. The identification, development and application of optimum wear solutions for these components pose an ongoing challenge. Nanostructured cermet coatings have shown the best results of achieving the degree of homogeneity required for these applications. In this study, WC-17Co cermet powder with nanocrystalline WC core encapsulated with 'duplex' Co layer was used to obtain a nanostructured coating. To apply this coating, high velocity oxy-fuel (HVOF) thermal spraying technique was used, as it is known for producing wear-resistant coatings superior to those obtained from plasma-based techniques. Mechanical, sliding wear and microstructural behavior of the coating was compared with those of the microstructured coating obtained from spraying WC-10Co-4Cr cermet powder by HVOF technique. Results from the nanostructured coating, among others, showed an average of 25% increase in microhardness, 30% increase in sliding wear resistance and

  14. Physical Properties of Kaolin/Sand Slurry Used During Submersible Mixer Pump Tests at TNX

    SciTech Connect

    HANSEN, ERICHK.

    2004-08-18

    The purpose of this task is to characterize the physical properties of kaolin/sand slurry used to test the performance of a new submersible mixer pump which is undergoing performance testing at the TNT Waste Tank mockup facility. Three different sample locations, the SMP cooling water exit, the SMP fluid flow field, and SMP effective cleaning radius were used for sampling over the seven day test. The physical properties determinations for the kaolin/sand slurry samples include rheology, weight percent total solids (wt TS), density, and particle size distribution were requested, though not all these determinations were performed on all the samples. The physical properties determinations are described in more detail in section 1.0. Measurements were performed at Savannah River National Laboratory in accordance with the Technical Assistance Request (TAR)1. The data, average of two measurements, is shown in the table below. This data clearly shows that the SMP-CWE samples contained more so lids than those at other sample locations for a given sample day. The SMP-FFF and SMP-ECR were similar in solids content. The rheology of the samples is dependent on the wt solids concentration and are all within the bounds stated in the TAR.

  15. Applying the Analytic Hierarchy Process to Oil Sands Environmental Compliance Risk Management

    NASA Astrophysics Data System (ADS)

    Roux, Izak Johannes, III

    Oil companies in Alberta, Canada, invested $32 billion on new oil sands projects in 2013. Despite the size of this investment, there is a demonstrable deficiency in the uniformity and understanding of environmental legislation requirements that manifest into increased project compliance risks. This descriptive study developed 2 prioritized lists of environmental regulatory compliance risks and mitigation strategies and used multi-criteria decision theory for its theoretical framework. Information from compiled lists of environmental compliance risks and mitigation strategies was used to generate a specialized pairwise survey, which was piloted by 5 subject matter experts (SMEs). The survey was validated by a sample of 16 SMEs, after which the Analytic Hierarchy Process (AHP) was used to rank a total of 33 compliance risks and 12 mitigation strategy criteria. A key finding was that the AHP is a suitable tool for ranking of compliance risks and mitigation strategies. Several working hypotheses were also tested regarding how SMEs prioritized 1 compliance risk or mitigation strategy compared to another. The AHP showed that regulatory compliance, company reputation, environmental compliance, and economics ranked the highest and that a multi criteria mitigation strategy for environmental compliance ranked the highest. The study results will inform Alberta oil sands industry leaders about the ranking and utility of specific compliance risks and mitigations strategies, enabling them to focus on actions that will generate legislative and public trust. Oil sands leaders implementing a risk management program using the risks and mitigation strategies identified in this study will contribute to environmental conservation, economic growth, and positive social change.

  16. Sand, Syrup and Supervolcanoes

    NASA Astrophysics Data System (ADS)

    Kennedy, B.; Jellinek, M.; Stix, J.

    2006-12-01

    Supervolcanic eruptions are amongst the most awesome events in the history of the Earth. A supervolcano can erupt thousands of cubic kilometers of ash devastating entire countries and changing the climate for decades. During the eruption, the magma chamber partially empties and collapses. As the chamber collapses at depth, a massive subsidence pit develops at the surface, called a caldera, some calderas can be the size of the entire San Francisco Bay Area. Fortunately, a supervolcano of this size has not erupted since the development of modern man. Due to the infrequency and massive scale of these eruptions, volcanologists do not yet fully understand how calderas form and how the eruption is affected by the roof collapse and vice versa. Therefore, simple analogue experiments are amongst the best ways to understand these eruptions. We present two of these experiments that can be fun, cheap, and helpful to high school and university instructors to demonstrate caldera formation. The first experiment illustrates how magma chamber roofs collapse to produce different style calderas, the second experiment demonstrates how the magma in the chamber affects the collapse style and magma mixing during a supervolcanic eruption. The collapse of a magma chamber can be demonstrated in a simple sandbox containing a buried balloon filled with air connected to a tube that leads out of the sandbox. At this small scale the buried balloon is a good analogue for a magma chamber and sand has an appropriate strength to represent the earths crust. Faults propagate through the sand in a similar way to faults propagating through the crust on a larger scale. To form a caldera just let the air erupt out of the balloon. This experiment can be used to investigate what controls the shape and structure of calderas. Different shaped balloons, and different burial depths all produce sand calderas with different sizes and structures. Additionally, experiments can be done that erupt only part of the

  17. The growing season water balance and controls on evapotranspiration in wetland reclamation test cells Fort McMurray, Alberta

    NASA Astrophysics Data System (ADS)

    Faubert, Jean-Pascal R.

    In the oil sands mining region near Fort McMurray, Alberta, efforts to establish specific wetland reclamation techniques are underway. During the 2010 growing season, the water balance of 12 plots (cells) of different soil and vegetation treatments were studied with emphasis on understanding the controls on evapotranspiration (ET) and the effects of construction techniques. Cell hydrologic behaviour was distinct from natural wetlands due to frequent artificial irrigation. ET ranged from ˜0 6 mm day-1 to ˜8.2 mm day-1 with a mean of ˜3.2 mm day-1 and variation among the cells was attributed to the construction techniques used, specifically placement period and soil depth. ET was weakly correlated to individual environmental variables; however, multivariate statistical models revealed complex interactions among environmental variables that acted to control ET. Cumulative water balances indicated certain construction techniques produced ET rates comparable to natural wetlands, which may be an important factor in improving the long-term sustainability of reclaimed wetlands.

  18. Structure and mechanism of Staphylococcus aureus TarM, the wall teichoic acid α-glycosyltransferase

    PubMed Central

    Sobhanifar, Solmaz; Worrall, Liam James; Gruninger, Robert J.; Wasney, Gregory A.; Blaukopf, Markus; Baumann, Lars; Lameignere, Emilie; Solomonson, Matthew; Brown, Eric D.; Withers, Stephen G.; Strynadka, Natalie C. J.

    2015-01-01

    Unique to Gram-positive bacteria, wall teichoic acids are anionic glycopolymers cross-stitched to a thick layer of peptidoglycan. The polyol phosphate subunits of these glycopolymers are decorated with GlcNAc sugars that are involved in phage binding, genetic exchange, host antibody response, resistance, and virulence. The search for the enzymes responsible for GlcNAcylation in Staphylococcus aureus has recently identified TarM and TarS with respective α- and β-(1–4) glycosyltransferase activities. The stereochemistry of the GlcNAc attachment is important in balancing biological processes, such that the interplay of TarM and TarS is likely important for bacterial pathogenicity and survival. Here we present the crystal structure of TarM in an unusual ternary-like complex consisting of a polymeric acceptor substrate analog, UDP from a hydrolyzed donor, and an α-glyceryl-GlcNAc product formed in situ. These structures support an internal nucleophilic substitution-like mechanism, lend new mechanistic insight into the glycosylation of glycopolymers, and reveal a trimerization domain with a likely role in acceptor substrate scaffolding. PMID:25624472

  19. Application of organic geochemistry to coastal tar residues from Central California

    USGS Publications Warehouse

    Kvenvolden, K.A.; Rosenbauer, R.J.; Hostettler, F.D.; Lorenson, T.D.

    2000-01-01

    Tar residues are common on the coastline of the Monterey Bay National Marine Sanctuary. These coastal tar residues have been washed ashore and usually occur on headlands near the high-tide line. In this study, 18 coastal tar residues were collected and analyzed to determine their carbon isotopic compositions and the values of selected biomarker ratios. All of the residues have very heavy (13C-enriched) carbon isotopic compositions spanning a narrow range (??13C = -22.2 to -23.4???), and 28,30-bisnorhopane is present in all samples. These same geochemical characteristics are found in Monterey Formation oils from which the coastal tar residues were likely derived. These coastal residues could result from natural seeps or from accidental spills. Statistically the coastal tar residues can be organized into three groups, each of which may represent different spill or seep events. Seven samples of potential local representative sources for the tar residues were examined, but none could account for the coastal tars.

  20. Determining the characteristics of the direct coke oven gas tar fog

    SciTech Connect

    Nazarov, V.G.; Vshivtsev, G.; Simonov, S.P.

    1982-01-01

    In the cooling of coke oven gas, the principal part of the tar in the gas main condenses and is discharged to the mechanical clarifiers with the water. The remaining part of the tar is present chiefly in the form of fog. The vapor phase of the tar is insignificant and consists primarily of fractions boiling below 300/sup 0/C. Separation of the tar from the direct gas in the primary gas coolers is determined principally by the conditions of precipitation of the aerosols and absorption of the low-boiling fractions of tar, naphthalene and crude benzol on the drops of tar fog. The particle size of the aerosols in the direct gas is described by a log normal distribution curve. The diameter of the principal part of the particles is 0.8 to 7.0 microns. In the direct gas after the primary gas coolers with vertical tubes at temperatures below 40/sup 0/C there are three condensed phases: naphthalene crystals, water droplets and tar. (JMT)

  1. Impact of Asphaltenes and Resins on the Wetting Characteristics of Tars at Former Manufactured Gas Plants

    NASA Astrophysics Data System (ADS)

    Hauswirth, S. C.; Birak, P. S.; Rylander, S.; Pedit, J. A.; Miller, C. T.

    2008-12-01

    Tars produced as a byproduct of coal and oil gasification at manufactured gas plants (MGPs) during the 19th and early 20th centuries were often released into the environment through poor disposal practices or leaks in holding tanks and piping. These tars are persistent contaminants, leaching polycyclic aromatic hydrocarbons (PAHs) into groundwater and posing a significant risk to human and ecological health. MGP tars also have several properties that make them notoriously difficult to remediate. They are denser than water, so they can migrate to depths which make direct removal difficult or impossible, and their relatively high viscosities and ability to alter the wetting characteristics of porous media result in inefficient removal by traditional pump-and-treat methods. In this study, we investigate the last of these properties. Previous studies have linked wetting changes to asphaltenes---polar, high molecular weight compounds present in the tars. However, we have conducted qualitative bottle tests for tar samples collected from two former MGPs which indicate that there is no direct correlation between asphaltene concentration and the tendency to alter wetting characteristics of porous media. To better understand the factors controlling wetting behavior, we isolate asphaltenes and resins, another class of polar compounds, from a tar sample and recombine them with the remaining PAH mixture to create a series of tars of varying composition. We assess the relative impact of each of the fractions on wettability through contact angle measurements conducted at three different pHs.

  2. TAR-independent replication of human immunodeficiency virus type 1 in glial cells.

    PubMed Central

    Bagasra, O; Khalili, K; Seshamma, T; Taylor, J P; Pomerantz, R J

    1992-01-01

    The molecular mechanisms involved in the replication of human immunodeficiency virus type 1 (HIV-1) may differ in various cell types and with various exogenous stimuli. Astrocytic glial cells, which can support HIV-1 replication in cell cultures and may be infected in vivo, are demonstrated to provide a cellular milieu in which TAR mutant HIV-1 viruses may replicate. Using transfections of various TAR mutant HIV-1 proviral constructs, we demonstrate TAR-independent replication in unstimulated astrocytic cells. We further demonstrate, using viral constructs with mutations in the tat gene and in the nuclear factor kappa B (NF-kappa B)-binding sites (enhancer) of the HIV-1 long terminal repeat, that TAR-independent HIV-1 replication in astrocytic cells requires both intact NF-kappa B moiety-binding motifs in the HIV-1 long terminal repeat and Tat expression. We measured HIV-1 p24 antigen production, syncytium formation, and levels and patterns of viral RNA expression by Northern (RNA) blotting to characterize TAR-independent HIV-1 expression in astrocytic glial cells. This alternative regulatory pathway of TAR-independent, Tat-responsive viral production may be important in certain cell types for therapies which seek to perturb Tat-TAR binding as a strategy to interrupt the viral lytic cycle. Images PMID:1433528

  3. Catalytic Tar Reduction for Assistance in Thermal Conversion of Space Waste for Energy Production

    NASA Technical Reports Server (NTRS)

    Caraccio, Anne Joan; Devor, Robert William; Hintze, Paul E.; Muscatello, Anthony C.; Nur, Mononita

    2014-01-01

    The Trash to Gas (TtG) project investigates technologies for converting waste generated during spaceflight into various resources. One of these technologies was gasification, which employed a downdraft reactor designed and manufactured at NASA's Kennedy Space Center (KSC) for the conversion of simulated space trash to carbon dioxide. The carbon dioxide would then be converted to methane for propulsion and water for life support systems. A minor byproduct of gasification includes large hydrocarbons, also known as tars. Tars are unwanted byproducts that add contamination to the product stream, clog the reactor and cause complications in analysis instrumentation. The objective of this research was to perform reduction studies of a mock tar using select catalysts and choose the most effective for primary treatment within the KSC downdraft gasification reactor. Because the KSC reactor is operated at temperatures below typical gasification reactors, this study evaluates catalyst performance below recommended catalytic operating temperatures. The tar reduction experimentation was observed by passing a model tar vapor stream over the catalysts at similar conditions to that of the KSC reactor. Reduction in tar was determined using gas chromatography. Tar reduction efficiency and catalyst performances were evaluated at different temperatures.

  4. Environmental management in resource-rich Alberta, Canada: first world jurisdiction, Third World analogue?

    PubMed

    Timoney, K; Lee, P

    2001-12-01

    Economic growth is frequently touted as a cure for environmental ills, particularly for those in Third World countries. Here we examine that paradigm in a case study of Alberta, Canada, a wealthy, resource-rich province within a wealthy nation. Through provincial-scale datasets, we examine the increasing pressures of the forest, petroleum, and agricultural industries upon the ecosystems of Alberta within management, economic, and political contexts. We advance the thesis that economic activity leads to environmental degradation unless ecosystem-based management is integrated into economic decision making. Agricultural lands cover 31.7%, and forest management areas leased to industry cover 33.4% of Alberta; both continue to increase in extent. The rate of logging (focused on old-growth by government policy) continues a decades-long exponential rise. Current Alberta annual petroleum production is 52.5 million m3 crude oil and 117 billion m3 of gas. As of early 1999, there were approximately 199,025 oil and gas wells and a conservative total of approximately 1.5-1.8 million km of seismic lines in Alberta. Fire occurrence data indicate no downward trends in annual area burned by wildfire, which may be characterized as driven by climate and inherently variable. When logging and wildfire are combined, the annual allowable cut in Alberta is unsustainable, even when only timber supply is considered and the effects of expanding agriculture and oil and gas activities are ignored. Ecosystem degradation in Alberta is pervasive and contrasts prominently with a high standard of living. A wealth of ecological data exists that indicates current resource-based economic activities are non-sustainable and destructive of ecosystem health yet these data are not considered within the economic decision making process. Given the complex, compounded, and increasing ecosystem perturbations, a future of unpleasant ecological surprises is likely. We conclude with tentative predictions as to

  5. Identification of a novel HIV-1 TAR RNA bulge binding protein.

    PubMed

    Baker, B; Muckenthaler, M; Vives, E; Blanchard, A; Braddock, M; Nacken, W; Kingsman, A J; Kingsman, S M

    1994-08-25

    The Tat protein binds to TAR RNA to stimulate the expression of the human immunodeficiency virus type 1 (HIV-1) genome. Tat is an 86 amino acid protein that contains a short region of basic residues (aa49-aa57) that are required for RNA binding and TAR is a 59 nucleotide stem-loop with a tripyrimidine bulge in the upper stem. TAR is located at the 5' end of all viral RNAs. In vitro, Tat specifically interacts with TAR by recognising the sequence of the bulge and upper stem, with no requirement for the loop. However, in vivo the loop sequence is critical for activation, implying a requirement for accessory cellular TAR RNA binding factors. A number of TAR binding cellular factors have been identified in cell extracts and various models for the function of these factors have been suggested, including roles as coactivators and inhibitors. We have now identified a novel 38 kD cellular factor that has little general, single-stranded or double-stranded RNA binding activity, but that specifically recognises the bulge and upper stem region of TAR. The protein, referred to as BBP (bulge binding protein), is conserved in mammalian and amphibian cells and in Schizosaccharomyces pombe but is not found in Saccharomyces cerevisiae. BBP is an effective competitive inhibitor of Tat binding to TAR in vitro. Our data suggest that the bulge-stem recognition motif in TAR is used to mediate cellular factor/RNA interactions and indicates that Tat action might be inhibited by such competing reactions in vivo. PMID:8078772

  6. Bacterial mutagenicity of pyrolysis tars produced from chloro-organic fuels.

    PubMed Central

    Mulholland, J A; Sarofim, A F; Longwell, J P; Lafleur, A L; Thilly, W G

    1994-01-01

    Droplets of toluene and three chlorinated organics, ortho-dichlorobenzene, 1,2-dichloroethane, and trichloroethylene, were pyrolyzed in pure nitrogen. The composition and bacterial mutagenicity of the product tars were measured. The presence of organic chlorine was found to affect both pyrolysis product tar composition and total tar mutagenicity. Pyrolysis in the absence of chlorine produced tars whose bacterial mutagenicity was found to be largely due to the presence of cyclopenta[cd]pyrene, fluoranthene, and benzo[a]pyrene. Small amounts of chlorine in the fuel (i.e., Cl/H molar ratios of less than 0.3) enhanced the formation of highly condensed polycyclic aromatic hydrocarbons (including cyclopenta[cd]pyrene) and increased tar mutagenicity. Larger amounts of organic chlorine (Cl/H ratios of between 0.3 and 0.6) resulted in significant yields of mono- and dichlorinated aromatics and higher levels of tar mutagenicity, which could not be accounted for by the presence of mutagens produced by pyrolysis in the absence of chlorine. Furthermore, unlike tars containing little or no chlorine, tars containing aryl chlorine were more mutagenic in the absence of added enzymes (intended to mimic in vivo mammalian metabolism) than in their presence. We hypothesize that at least one of the chlorinated aromatic products is strongly mutagenic. Two specific conditions that gave notably different results were a) the low-temperature (i.e., below 1400 K) pyrolysis of ortho-dichlorobenzene, which produced tri- and tetrachlorinated biphenyls almost exclusively; and b) the chlorine-rich pyrolysis of trichloroethylene, during which mostly perchloroaromatics were formed. Neither of these tars was found to mutate bacteria. PMID:8187720

  7. Characterization of Waste Tar Associated with Abandoned Wood Chemical Plant Sites in Northwest Pennsylvania, USA

    SciTech Connect

    Edendorn, H.M.; Severson, D.

    2007-07-01

    Over 70 wood chemical plants operated in northern Pennsylvania between ca. 1890 and 1950, all located within 72 km of the New York state border. Their original purpose was to salvage the small unwanted hardwood trees left behind by the lumber mills, and to make charcoal, calcium acetate and methanol for a number of industrial uses via destructive distillation. At many old wood chemical plant sites, unknown quantities of wood tar remain as a residual contaminant and pose a pollution threat to aquatic life in nearby streams. Research on the composition and properties of residual wood tars from five abandoned industrial sites in Pennsylvania are described. Weathered wood tars were more viscous and contained fewer volatile and semivolatile organic compounds than did soil-buried tars. Phenol, 2-methylphenol (o-cresol), 4-methylphenol (p-cresol), and 2, 4-dimethylphenol were found in all sampled tars. These water-soluble phenolic compounds were released quasi-instantaneously in aqueous solution, followed by a slower rate of release, consistent with the behavior of similar compounds in other dense non-aqueous liquids. Air-exposed wood tar deposits developed a hard crust, which contained fewer volatiles and semivolatiles and had a higher softening point than other samples. These tars eroded to form a powdered soil colonized by lichens and mosses. Residual wood tar material found at one site was shown to be thermally altered, likely during the historical destruction of the chemical plant by fire. Recovered wood tar wastes have a relatively high heating value and may have use as a potential, but limited, alternate energy source.

  8. Carbazole is a naturally occurring inhibitor of angiogenesis and inflammation isolated from antipsoriatic coal tar

    SciTech Connect

    Jack L. Arbiser; Baskaran Govindarajan; Traci E. Battle; Rebecca Lynch; David A. Frank; Masuko Ushio-Fukai; Betsy N. Perry; David F. Stern; G. Tim Bowden; Anquan Liu; Eva Klein; Pawel J. Kolodziejski; N. Tony Eissa; Chowdhury F. Hossain; Dale G. Nagle

    2006-06-15

    Coal tar is one of the oldest and an effective treatment for psoriasis. Coal tar has been directly applied to the skin, or used in combination with UV light as part of the Goeckerman treatment. The use of coal tar has caused long-term remissions in psoriasis, but has fallen out of favor because the treatment requires hospitalization and coal tar is poorly acceptable aesthetically to patients. Thus, determining the active antipsoriatic component of coal tar is of considerable therapeutic interest. We fractionated coal tar into its components, and tested them using the SVR angiogenesis inhibitor assay. Treatment of SVR endothelial cells with coal tar fractions resulted in the isolation of a single fraction with antiangiogenic activity. The active antiangiogenic compound in coal tar is carbazole. In addition to antiangiogenic activity, carbazole inhibited the production of inflammatory IL-15 by human mononuclear cells. IL-15 is elevated in psoriasis and is thought to contribute to psoriatic inflammation. Carbazole treatment also reduced activity of inducible nitric oxide synthase (iNOS), which is proinflammatory and elevated in psoriasis. The effect of carbazole on upstream pathways in human psoriasis was determined, and carbazole was shown to inhibit signal transducer and activator of transcription (stat)3-mediated transcription, which has been shown to be relevant in human psoriasis. IL-15, iNOS, and stat3 activation require the activation of the small GTPase rac for optimal activity. Carbazole was found to inhibit rac activation as a mechanism for its inhibition of downstream inflammatory and angiogenic pathways. Given its antiangiogenic and anti-inflammatory activities, carbazole is likely a major component of the antipsoriatic activity of coal tar. Carbazole and derivatives may be useful in the therapy of human psoriasis.

  9. Offshore sand bank dynamics

    NASA Astrophysics Data System (ADS)

    Williams, J. J.; MacDonald, N. J.; O'Connor, B. A.; Pan, S.

    2000-02-01

    The present paper reports some key results from field investigations and numerical modelling studies of the tide- and wind-induced hydrodynamics and sediment dynamics of Middelkerke Bank (MB) in the southern North Sea of Europe conducted during December 1992 to March 1993. Strong surface current refraction and acceleration effects were observed over MB using the HF radar system OSCR ( Ocean Surface Current Radar). Results suggest that OSCR data may be used remotely to monitor large-scale bathymetry in shallow coastal environments. Spatial variation in tidal propagation characteristics and modification of shoreward propagating waves was not detected at locations around MB during the experiment. Observed residual currents were found to be correlated strongly with wind speed and direction during the period 26 February to 18 March 1993. However, in low wind stress condition, a three-dimensional numerical model (3D-Bank) indicated the presence of a clockwise residual circulation of water around MB consistent with theory. Spatial and temporal variation in the average total drag coefficient ( Cd) of MB were investigated and found to correlate strongly with tidal current speed. Fluorescent sand tracers, used to monitor net sediment transport pathways, revealed a net clockwise movement of sediments around MB consistent with predictions by 3D-Bank and with theory.

  10. Saltation of Non-Spherical Sand Particles

    PubMed Central

    Wang, Zhengshi; Ren, Shan; Huang, Ning

    2014-01-01

    Saltation is an important geological process and the primary source of atmospheric mineral dust aerosols. Unfortunately, no studies to date have been able to precisely reproduce the saltation process because of the simplified theoretical models used. For example, sand particles in most of the existing wind sand movement models are considered to be spherical, the effects of the sand shape on the structure of the wind sand flow are rarely studied, and the effect of mid-air collision is usually neglected. In fact, sand grains are rarely round in natural environments. In this paper, we first analyzed the drag coefficients, drag forces, and starting friction wind speeds of sand grains with different shapes in the saltation process, then established a sand saltation model that considers the coupling effect between wind and the sand grains, the effect of the mid-air collision of sand grains, and the effect of the sand grain shape. Based on this model, the saltation process and sand transport rate of non-spherical sand particles were simulated. The results show that the sand shape has a significant impact on the saltation process; for the same wind speed, the sand transport rates varied for different shapes of sand grains by as much as several-fold. Therefore, sand shape is one of the important factors affecting wind-sand movement. PMID:25170614

  11. Shakedown operations in commercial production of sulfuric acid from acid tar

    SciTech Connect

    Perfil'ev, V.M.; Golyshev, V.B.; Goncharenko, A.D.; Shtafinskaya, A.M.; Sushchev, V.S.

    1985-07-01

    The authors describe process technology for processing acid tars to obtain sulfuric acid by means of high temperature splitting to regenerate spent sulfuric acid contaminated with organic impurities. An illustration presents a simplified flow plan for acid tar processing. The authors conclude, from experience with this unit, that process indexes meet design requirements, in particular with respect to the degree of decomposition of the acid tar, the temperature conditions the SO/sub 2/ conversion, the SO/sub 3/ adsorption, and the quality and quantity of the oleum and commercial sulfuric acid obtained.

  12. Coal-tar-based pavement sealcoat—Potential concerns for human health and aquatic life

    USGS Publications Warehouse

    Mahler, Barbara J.; Woodside, Michael D.; Van Metre, Peter C.

    2016-01-01

    Aquatic Life Concerns—Runoff from coal-tar-sealcoated pavement, even runoff collected more than 3 months after sealcoat application, is acutely toxic to fathead minnows and water fleas, two species commonly used to assess toxicity to aquatic life. Exposure to even highly diluted runoff from coal-tar-sealcoated pavement can cause DNA damage and impair DNA repair. These findings demonstrate that coal-tar-sealcoat runoff can remain a risk to aquatic life for months after application.

  13. METHOD OF PROCESSING MONAZITE SAND

    DOEpatents

    Calkins, G.D.

    1957-10-29

    A method is given for the pretreatment of monazite sand with sodium hydroxide. When momazite sand is reacted with sodium hydroxide, the thorium, uranium, and rare earths are converted to water-insoluble hydrous oxides; but in the case of uranium, the precipitate compound may at least partly consist of a slightly soluble uranate. According to the patent, monazite sand is treated with an excess of aqueous sodium hydroxide solution, and the insoluble compounds of thorium, uranium, and the rare earths are separated from the aqueous solution. This solution is then concentrated causing sodium phosphate to crystallize out. The crystals are removed from the remaining solution, and the solution is recycled for reaction with a mew supply of momazite sand.

  14. Aeolian sand ripples around plants.

    PubMed

    Zhang, Qian-Hua; Miao, Tian-De

    2003-05-01

    Plants in the desert may locally change the aeolian process, and hence the pattern of sand ripples traveling nearby. The effect of plants on ripples is investigated using a coupled map lattice model with nonuniform coupling coefficients. PMID:12786143

  15. Diurnal patterns of blowing sand

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The diurnal pattern of blowing sand results from a complex process that involves an interaction between solar heating, thermal instability, atmospheric turbulence, wind strength, and surface threshold conditions. During the day, solar heating produces thermal instability, which enhances the convect...

  16. Sulfur Biogeochemistry of an Oil Sands Composite Tailings Deposit.

    PubMed

    Warren, Lesley A; Kendra, Kathryn E; Brady, Allyson L; Slater, Greg F

    2015-01-01

    Composite tailings (CT), an engineered, alkaline, saline mixture of oil sands tailings (FFT), processed sand and gypsum (CaSO4; 1 kg CaSO4 per m(3) FFT) are used as a dry reclamation strategy in the Alberta Oil Sands Region (AOSR). It is estimated that 9.6 × 10(8) m(3) of CT are either in, or awaiting emplacement in surface pits within the AOSR, highlighting their potential global importance in sulfur cycling. Here, in the first CT sulfur biogeochemistry investigation, integrated geochemical, pyrosequencing and lipid analyses identified high aqueous concentrations of ∑H2S (>300 μM) and highly altered sulfur compounds composition; low cell biomass (3.3 × 10(6)- 6.0 × 10(6) cells g(-1)) and modest bacterial diversity (H' range between 1.4 and 1.9) across 5 depths spanning 34 m of an in situ CT deposit. Pyrosequence results identified a total of 29,719 bacterial 16S rRNA gene sequences, representing 131 OTUs spanning19 phyla including 7 candidate divisions, not reported in oil sands tailings pond studies to date. Legacy FFT common phyla, notably, gamma and beta Proteobacteria, Firmicutes, Actinobacteria, and Chloroflexi were represented. However, overall CT microbial diversity and PLFA values were low relative to other contexts. The identified known sulfate/sulfur reducing bacteria constituted at most 2% of the abundance; however, over 90% of the 131 OTUs identified are capable of sulfur metabolism. While PCR biases caution against overinterpretation of pyrosequence surveys, bacterial sequence results identified here, align with phospholipid fatty acid (PLFA) and geochemical results. The highest bacterial diversities were associated with the depth of highest porewater [∑H2S] (22-24 m) and joint porewater co-occurrence of Fe(2+) and ∑H2S (6-8 m). Three distinct bacterial community structure depths corresponded to CT porewater regions of (1) shallow evident Fe((II)) (<6 m), (2) co-occurring Fe((II)) and ∑H2S (6-8 m) and (3) extensive ∑H2S (6-34 m) (Uni

  17. Sulfur Biogeochemistry of an Oil Sands Composite Tailings Deposit

    PubMed Central

    Warren, Lesley A.; Kendra, Kathryn E.; Brady, Allyson L.; Slater, Greg F.

    2016-01-01

    Composite tailings (CT), an engineered, alkaline, saline mixture of oil sands tailings (FFT), processed sand and gypsum (CaSO4; 1 kg CaSO4 per m3 FFT) are used as a dry reclamation strategy in the Alberta Oil Sands Region (AOSR). It is estimated that 9.6 × 108 m3 of CT are either in, or awaiting emplacement in surface pits within the AOSR, highlighting their potential global importance in sulfur cycling. Here, in the first CT sulfur biogeochemistry investigation, integrated geochemical, pyrosequencing and lipid analyses identified high aqueous concentrations of ∑H2S (>300 μM) and highly altered sulfur compounds composition; low cell biomass (3.3 × 106– 6.0 × 106 cells g−1) and modest bacterial diversity (H' range between 1.4 and 1.9) across 5 depths spanning 34 m of an in situ CT deposit. Pyrosequence results identified a total of 29,719 bacterial 16S rRNA gene sequences, representing 131 OTUs spanning19 phyla including 7 candidate divisions, not reported in oil sands tailings pond studies to date. Legacy FFT common phyla, notably, gamma and beta Proteobacteria, Firmicutes, Actinobacteria, and Chloroflexi were represented. However, overall CT microbial diversity and PLFA values were low relative to other contexts. The identified known sulfate/sulfur reducing bacteria constituted at most 2% of the abundance; however, over 90% of the 131 OTUs identified are capable of sulfur metabolism. While PCR biases caution against overinterpretation of pyrosequence surveys, bacterial sequence results identified here, align with phospholipid fatty acid (PLFA) and geochemical results. The highest bacterial diversities were associated with the depth of highest porewater [∑H2S] (22–24 m) and joint porewater co-occurrence of Fe2+ and ∑H2S (6–8 m). Three distinct bacterial community structure depths corresponded to CT porewater regions of (1) shallow evident Fe(II) (<6 m), (2) co-occurring Fe(II) and ∑H2S (6–8 m) and (3) extensive ∑H2S (6–34 m) (Uni

  18. Modern Graywacke-Type Sands.

    PubMed

    Hollister, C D; Heezen, B C

    1964-12-18

    A preliminary study of more than 100 deep-sea cores from abyssal plains has revealed two examples of recent muddy sands of the graywacke type which, together with the microcrystalline matrix, form a bimodal-size distribution sands have a well-sorted framework of quartz, feldspar, and rock fragments which, together with the microcrystalline matrix, form a bimodal-size distribution that is also typical of ancient graywackes. The matrix is considered to be primary. PMID:17775982

  19. Dust and Sand Mixing

    NASA Technical Reports Server (NTRS)

    2003-01-01

    [figure removed for brevity, see original site]

    Released 10 November 2003

    The bright and dark tones observed in this THEMIS image of part of an unnamed impact crater (85 km in diameter) near the larger impact crater Schiaparelli are due to variable amounts of bright dust and dark sand covering the surface. Wind Shadows observed around small impact craters at the top of the image and small grooves and ripple-like marks observed throughout the scene illustrate dynamic and continued aeolian processes on Mars.

    Image information: VIS instrument. Latitude -1.4, Longitude 10.9 East (349.1 West). 19 meter/pixel resolution.

    Note: this THEMIS visual image has not been radiometrically nor geometrically calibrated for this preliminary release. An empirical correction has been performed to remove instrumental effects. A linear shift has been applied in the cross-track and down-track direction to approximate spacecraft and planetary motion. Fully calibrated and geometrically projected images will be released through the Planetary Data System in accordance with Project policies at a later time.

    NASA's Jet Propulsion Laboratory manages the 2001 Mars Odyssey mission for NASA's Office of Space Science, Washington, D.C. The Thermal Emission Imaging System (THEMIS) was developed by Arizona State University, Tempe, in collaboration with Raytheon Santa Barbara Remote Sensing. The THEMIS investigation is led by Dr. Philip Christensen at Arizona State University. Lockheed Martin Astronautics, Denver, is the prime contractor for the Odyssey project, and developed and built the orbiter. Mission operations are conducted jointly from Lockheed Martin and from JPL, a division of the California Institute of Technology in Pasadena.

  20. Combined Tree-Ring Carbon and Nitrogen Isotopes to infer past atmospheric deposition in Northeastern Alberta

    NASA Astrophysics Data System (ADS)

    Savard, M. M.; Bégin, C.; Marion, J.

    2013-12-01

    Monitoring atmospheric emissions from industrial centers in North America is significantly younger than the emitting activities themselves. Attention should be placed on SOx and NOx emissions as they have been increasing over the last 15 years in western Canada. In Northeastern Alberta in particular, two distinct diffuse pollution contexts deserve attention: the Lower Athabasca Oil Sands (OS) district (north of Fort McMurray), and the coal fired power plant (CFPP) area (west of Edmonton). The NOx and SO2 emissions started in 1967 and 1956, but the direct air quality monitoring has been initiated in 1997 and 1985, in these respective contexts. In an attempt to address the gap in emission and deposition monitoring, we explored the δ13C and δ15N patterns of spruce trees (Picea glauca and Picea mariana) growing in four stands in the OS district and one stand, in the CFPP area. Tree-ring series collected from these five sites all covering the 1880-2010 period were analyzed and their δ13C and δ15N values examined along with the climatic parameters and SOx and NOx emission proxies. For two stands in the OS district where soil drainage was poor δ15N series did not vary significantly, but the intermediate and long-term δ13C and δ15N trends inversely correlate in the three other studied stands. For these three sites statistical analyses for the pre-operation calibration periods (1910-1961 and 1900-1951) allowed developing transfer functions and predicting the natural δ13C and δ15N responses to climatic conditions for the operation periods. The measured series all depart from the modeled natural trends, depicting anomalies. Interestingly, the anomalies in the two regions can be nicely reproduced by multiple-regression models combining local climatic parameters with acidifying emissions. Notwithstanding the significant inverse correlations between the δ13C and δ15N series for the three well drained sites and their link to acidifying emissions, it is too early to