alder bigleaf maple: Topics by Science.gov

Sample records for alder bigleaf maple

Chip Debarking of Several Western Species

Treesearch

William A. Hillstrom

1974-01-01

Discusses processing and conditioning treatments before and aftger compression debarking of western hemlock, Douglas fir, red alder, and bigleaf maple. Bark removal and wood recovery from red alder far exceeded the other species tested. Approximately 90 percent of the wood fiber input was recovered at a residual bark content of less than 2 percent by weight.
Predicting crown weight and bole volume of five Western hardwoods.

Treesearch

J.A. Kendall Snell; Susan N. Little

1983-01-01

Regression equations are presented for estimating biomass of five western hardwoods: red alder (Alnus rubra Bong.), giant chinkapin (Castanopsis chrysophylla (Dougl.) A. DC.), bigleaf maple (Acer macrophyllum Pursh), Pacific madrone (Arbutus menziesii Pursh), and tanoak (...
The hardwood resource in western Oregon.

Treesearch

John H. Poppino; Donald R. Gedney

1984-01-01

The hardwood resource in western Oregon is described by species and ownership. Changes in the private hardwood resource between 1961-62 and 1973-76 are shown. Statistics of size, volume, and ownership by county are presented for red alder (Alnus rubra Bong.) and bigleaf maple (Acer macrophyllum Pursh).
Diversity of Riparian Plants among and within Species Shapes River Communities

PubMed Central

Jackrel, Sara L.; Wootton, J. Timothy

2015-01-01

Organismal diversity among and within species may affect ecosystem function with effects transmitting across ecosystem boundaries. Whether recipient communities adjust their composition, in turn, to maximize their function in response to changes in donor composition at these two scales of diversity is unknown. We use small stream communities that rely on riparian subsidies as a model system. We used leaf pack experiments to ask how variation in plants growing beside streams in the Olympic Peninsula of Washington State, USA affects stream communities via leaf subsidies. Leaves from red alder (Alnus rubra), vine maple (Acer cinereus), bigleaf maple (Acer macrophyllum) and western hemlock (Tsuga heterophylla) were assembled in leaf packs to contrast low versus high diversity, and deployed in streams to compare local versus non-local leaf sources at the among and within species scales. Leaves from individuals within species decomposed at varying rates; most notably thin leaves decomposed rapidly. Among deciduous species, vine maple decomposed most rapidly, harbored the least algal abundance, and supported the greatest diversity of aquatic invertebrates, while bigleaf maple was at the opposite extreme for these three metrics. Recipient communities decomposed leaves from local species rapidly: leaves from early successional plants decomposed rapidly in stream reaches surrounded by early successional forest and leaves from later successional plants decomposed rapidly adjacent to later successional forest. The species diversity of leaves inconsistently affected decomposition, algal abundance and invertebrate metrics. Intraspecific diversity of leaf packs also did not affect decomposition or invertebrate diversity. However, locally sourced alder leaves decomposed more rapidly and harbored greater levels of algae than leaves sourced from conspecifics growing in other areas on the Olympic Peninsula, but did not harbor greater aquatic invertebrate diversity. In contrast to alder, local intraspecific differences via decomposition, algal or invertebrate metrics were not observed consistently among maples. These results emphasize that biodiversity of riparian subsidies at the within and across species scale have the potential to affect aquatic ecosystems, although there are complex species-specific effects. PMID:26539714
Diversity of Riparian Plants among and within Species Shapes River Communities.

PubMed

Jackrel, Sara L; Wootton, J Timothy

2015-01-01

Organismal diversity among and within species may affect ecosystem function with effects transmitting across ecosystem boundaries. Whether recipient communities adjust their composition, in turn, to maximize their function in response to changes in donor composition at these two scales of diversity is unknown. We use small stream communities that rely on riparian subsidies as a model system. We used leaf pack experiments to ask how variation in plants growing beside streams in the Olympic Peninsula of Washington State, USA affects stream communities via leaf subsidies. Leaves from red alder (Alnus rubra), vine maple (Acer cinereus), bigleaf maple (Acer macrophyllum) and western hemlock (Tsuga heterophylla) were assembled in leaf packs to contrast low versus high diversity, and deployed in streams to compare local versus non-local leaf sources at the among and within species scales. Leaves from individuals within species decomposed at varying rates; most notably thin leaves decomposed rapidly. Among deciduous species, vine maple decomposed most rapidly, harbored the least algal abundance, and supported the greatest diversity of aquatic invertebrates, while bigleaf maple was at the opposite extreme for these three metrics. Recipient communities decomposed leaves from local species rapidly: leaves from early successional plants decomposed rapidly in stream reaches surrounded by early successional forest and leaves from later successional plants decomposed rapidly adjacent to later successional forest. The species diversity of leaves inconsistently affected decomposition, algal abundance and invertebrate metrics. Intraspecific diversity of leaf packs also did not affect decomposition or invertebrate diversity. However, locally sourced alder leaves decomposed more rapidly and harbored greater levels of algae than leaves sourced from conspecifics growing in other areas on the Olympic Peninsula, but did not harbor greater aquatic invertebrate diversity. In contrast to alder, local intraspecific differences via decomposition, algal or invertebrate metrics were not observed consistently among maples. These results emphasize that biodiversity of riparian subsidies at the within and across species scale have the potential to affect aquatic ecosystems, although there are complex species-specific effects.
Maple sirup production from bigleaf maple.

Treesearch

Robert H. Ruth; J. Clyde Underwood; Clark E. Smith; Hoya Y. Yang

1972-01-01

Bigleaf maple sap flow during the 1970-71 season ranged from none to 16.9 gallons per taphole and sugar content of the sap from 1.0 to 2.6 percent. Sugar content also varied seasonally, with the sweetest sap flowing in late January. The sirup was very flavorful, although not as strong in typical maple flavor as that made from eastern sugar maple. Sirup production...
Chemical control of bigleaf maple trees and stump sprouts.

Treesearch

Carl M. Berntsen

1960-01-01

Control of bigleaf maple (Acer macrophyllum) has become an important consideration in many western Oregon areas that are managed primarily for Douglas-fir (Pseudotsuga menziesii) and associated conifers. The problem is acute on areas where damaged and defective maples are left after harvest of commercial timber. They sprout...
Boron toxicity characteristics of four northern California endemic tree species

DOE Office of Scientific and Technical Information (OSTI.GOV)

Glaubig, B.A.; Bingham, F.T.

A greenhouse study was undertaken to determine the characteristics of soil B toxicity for four tree species endemic to The Geysers area in northern California: digger pine (Pinus sabiniana Dougl. ex D. Don), California laurel (or, California bay) (Umbellularia californica (Hoo. and Arn. Nutt.)), madrone (Arbutus menziesii Pursh), and bigleaf maple (Acer macrophyllum Pursh). Significant exponential relationships were found between soil B concentration and relative growth, and between tissue B concentration and relative growth for the four species. Significant linear relationships were found between both soil and tissue B concentration and foliar damage for the four species. Foliar damages overmore » 25% of the leaf or needle area on digger pine, California laurel, madrone, and bigleaf maple, respectively, occurred at saturated soil extract concentrations (mmol B/L) of 1.2, 0.4, 0.5, and 0.08. Twenty-five percent foliar damage was associated with leaf or needle tissue concentrations (mmol B/kg) of 115, 100, 50, and 30 for the digger pine, California laurel, madrone, and bigleaf maple, respectively. Growth decrements of 25% occurred at saturated soil extract concentrations (mmol B/L) of 1.6, 0.3, 0.2, 0.5 for the digger pine, California laurel, madrone, and bigleaf maple, respectively. Twenty-five percent growth decrements were associated with leaf or needle tissue concentrations (mmol B/kg) of 140, 100, 20, and 7 for the digger pine, California laurel, madrone, and bigleaf maple, respectively. By comparison with two agronomic crops - cotton (Gossypium hirsutum L.) and cowpea (Vigna unguiculata L.) - the four tree species were placed into one of six B tolerance classes.« less
Effects of cutting time, stump height, parent tree characteristics, and harvest variables on development of bigleaf maple sprout clumps

USGS Publications Warehouse

Tappeiner, J. C.; Zasada, J.; Maxwell, B.

1996-01-01

In order to determine the effects of stump height, year of cutting, parent-tree size, logging damage, and deer browsing on bigleaf maple (Acer macrophyllum) sprout clump development, maple trees were cut to two stump heights at three different times. Stump height had the greatest impact on sprout clump size. Two years after clearcutting, the sprout clump volume for short stumps was significantly less than that for tall stumps. The sprout clump volume, area, and number of sprouts were significantly less for trees cut 1 and 2 yr before harvest than for trees cut at harvest. Sprout clump size was positively correlated with parent tree stem diameter and stump volume, and negatively correlated with the percentage of bark removed during logging. Browsing had no significant impact on average clump size. Uncut trees produced sprout clumps at their base and epicormic branches along the length of their stems; thus their crown volume averaged four to five times that of cut trees. Cutting maple in clearcuts to low stumps may reduce maple competition with Douglas-fir regeneration and still maintain maple in the next stand.
Tree species and soil nutrient profiles in old-growth forests of the Oregon Coast Range

USGS Publications Warehouse

Cross, Alison; Perakis, Steven S.

2011-01-01

Old-growth forests of the Pacific Northwest provide a unique opportunity to examine tree species – soil relationships in ecosystems that have developed without significant human disturbance. We characterized foliage, forest floor, and mineral soil nutrients associated with four canopy tree species (Douglas-fir (Pseudotsuga menziesii (Mirbel) Franco), western hemlock (Tsuga heterophylla (Raf.) Sarg.), western redcedar (Thuja plicata Donn ex D. Don), and bigleaf maple (Acer macrophyllum Pursh)) in eight old-growth forests of the Oregon Coast Range. The greatest forest floor accumulations of C, N, P, Ca, Mg, and K occurred under Douglas-fir, primarily due to greater forest floor mass. In mineral soil, western hemlock exhibited significantly lower Ca concentration and sum of cations (Ca + Mg + K) than bigleaf maple, with intermediate values for Douglas-fir and western redcedar. Bigleaf maple explained most species-based differences in foliar nutrients, displaying high concentrations of N, P, Ca, Mg, and K. Foliar P and N:P variations largely reflected soil P variation across sites. The four tree species that we examined exhibited a number of individualistic effects on soil nutrient levels that contribute to biogeochemical heterogeneity in these ecosystems. Where fire suppression and long-term succession favor dominance by highly shade-tolerant western hemlock, our results suggest a potential for declines in both soil Ca availability and soil biogeochemical heterogeneity in old-growth forests.
Seeds in Flight

ERIC Educational Resources Information Center

Martin, Willard K.

1978-01-01

Discussed are the seed dispersal mechanisms of six different plants: big-leaf maple, pincushion tree, tree of heaven, squirting cucumber, digger pine, and bull thistle. Elaborate color and black-and-white drawings illustrate the text. (MA)
Equations for total, wood, and saw-log volume for thirteen California hardwoods.

Treesearch

Norman H. Pillsbury; Michael L. Kirkley

1984-01-01

Volume equations for thirteen species of California hardwoods were developed from measurements of 766 sample trees from all parts of the state. The species included: bigleaf maple (Acer macrophyllum Pursh), Pacific madrone (Arbutus menziesii Pursh), giant chinkapin (Castanopsis chrysophylla (Dougl.) A. DC...
Pre-epidemic mortality rates for common Phytophthora ramorum host tree species in California

Treesearch

T.M. Barrett

2006-01-01

Understanding the impacts of Phytophthora ramorum on forests will require knowledge of pre-disease distribution, abundance, and rates of change for affected species. This study estimated pre-epidemic mortality rates for nine common host tree species: bigleaf maple (Acer macrophyllum), California bay laurel (Umbellularia...
Programmatic Environmental Assessment for Standard Targetry Replacement

DTIC Science & Technology

2006-04-01

Appalachian oak and pine-oak stands. Pine barrens with grassy savannas are found in dry sandy soils, with thick shrubs often growing beneath the... fir . In interior valleys, the coniferous forest is less dense than along the coast; and often contains deciduous trees, such as big-leaf maple...Oregon ash, and black cottonwood. There are prairies that support open stands of oaks, or are broken by groves of Douglas fir and other trees
Ecotoxicity effects triggered in aquatic organisms by invasive Acer negundo and native Alnus glutinosa leaf leachates obtained in the process of aerobic decomposition.

PubMed

Manusadžianas, Levonas; Darginavičienė, Jūratė; Gylytė, Brigita; Jurkonienė, Sigita; Krevš, Alina; Kučinskienė, Alė; Mačkinaitė, Rimutė; Pakalnis, Romas; Sadauskas, Kazys; Sendžikaitė, Jūratė; Vitkus, Rimantas

2014-10-15

The replacement of autochthonous tree species by invasive ones in coastal zones of freshwater bodies induces additional alteration of hydrochemical and microbiological characteristics due to decomposition of fallen leaves of non-indigenous species, which can lead to ecotoxic response of the littoral biota. Leaves of invasive to Lithuania boxelder maple (Acer negundo) and autochthonous black alder (Alnus glutinosa) lost more than half of biomass and released stable amount of DOC (60-70 mg/L) throughout 90-day mesocosm experiment under aerobic conditions. This, along with the relatively small BOD7 values detected after some variation within the first month confirms effective biodegradation by fungi and bacteria. The ambient water was more enriched with different forms of N and P by decomposing boxelder maple than by alder leaves. During the first month, both leachates were more toxic to charophyte (Nitellopsis obtusa) at mortality and membrane depolarization levels, while later to two crustacean species. Biomarker response, H(+)-ATPase activity in membrane preparations from N. obtusa, was stronger for A. negundo. Generally, boxelder maple leaf leachates were more toxic to tested hydrobionts and this coincides with previous study on leaves of the same pair of tree species conducted under microaerobic conditions (Krevš et al., 2013). Copyright © 2014 Elsevier B.V. All rights reserved.
Ecotoxicological effects evoked in hydrophytes by leachates of invasive Acer negundo and autochthonous Alnus glutinosa fallen off leaves during their microbial decomposition.

PubMed

Krevš, Alina; Darginavičienė, Jūratė; Gylytė, Brigita; Grigutytė, Reda; Jurkonienė, Sigita; Karitonas, Rolandas; Kučinskienė, Alė; Pakalnis, Romas; Sadauskas, Kazys; Vitkus, Rimantas; Manusadžianas, Levonas

2013-02-01

Throughout 90-day biodegradation under microaerobic conditions, invasive to Lithuania species boxelder maple (Acer negundo) leaves lost 1.5-fold more biomass than that of autochthonous black alder (Alnus glutinosa), releasing higher contents of N(tot), ammonium and generating higher BOD(7). Boxelder maple leaf leachates were characterized by higher total bacterial numbers and colony numbers of heterotrophic and cellulose-decomposing bacteria than those of black alder. The higher toxicity of A. negundo aqueous extracts and leachates to charophyte cell (Nitellopsis obtusa), the inhabitant of clean lakes, were manifested at mortality and membrane depolarization levels, while the effect on H(+)-ATPase activity in membrane preparations from the same algae was stronger in case of A. glutinosa. Duckweed (Lemna minor), a bioindicator of eutrophic waters, was more sensitive to leaf leachates of A. glutinosa. Fallen leaves and leaf litter leachates from invasive and native species of trees, which enter water body, affect differently microbial biodestruction and aquatic vegetation in freshwater systems. Copyright © 2012 Elsevier Ltd. All rights reserved.
Why hardwoods do not grow naturally in the west

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J. A. Larsen

1924-01-01

Unfortunately the beautiful hardwood trees which are native to the Eastern States do not grow naturally in the West. We have here only aspen, cottonwood, small birch, hawthorns, cherry, and alder. On the Pacific coast are oak and maple, but limited largely to lower moist sites such as streams bed and canyons. The general absence of broad leaf trees in the West is most...
Phase 2 Site Investigations Report. Volume 2 of 3: site-Specific Investigations

DTIC Science & Technology

1994-09-01

overstory regeneration. In addition, poison ivy and Virginia creeper are common vines. Various asters, grasses, and goldenrods comprise the sparsely...and silky dogwood. Poison ivy dominates the ground cover. In general these areas combine several distinct upland habitats which support wildlife...hemlock, speckled alder, red maple saplings and a variety of herbaceous and emergent plants, such as water lilies, cattails, jewelweed , sensitive fern
Growth responses of woody species to long- and short-term fumigation with sulfur dioxide

Treesearch

Keith F. Jensen; Leon S. Dochinger

1979-01-01

Height growth of silver maple, white ash, yellow-poplar, sycamore, eastern cottonwood, and white spruce seedlings was not significantly influenced by 0.15 ppm SO2 for 8 hours/day, 5 days/week. A fumigation treatment of 0.25 ppm SO2 for 8 hourd/day, 5 days/week did not significantly affect height growth of black alder,...
Marine Riparian Vegetation Communities of Puget Sound

DTIC Science & Technology

2007-02-01

species . In areas of frequent disturbance, early successional trees , such as red alder and maple, dominated coastal forests. Douglas fir is currently...sea level to the mountain tops), forest types are broken into zones, represented by the dominant canopy ( tree ) species , or cli- max community, with...Within each zone, there is also vertical stratification of vegetation types, including dominant canopy tree species , understory trees and shrubs, and

EFFECT OF SIMULATED SULFURIC ACID RAIN ON THE CHEMISTRY OF A SULFATE-ADSORBING FOREST SOIL

EPA Science Inventory

Simulated H2SO4 rain (pH 3.0, 3.5, 4.0) or control rain (pH 5.6) was applied for 3.5 yr to large lysimeter boxes containing a sulfate-adsorbing forest soil and either red alder (Alnus rubra) or sugar maple (Acer saccharum) seedlings. After removal of the plants and the litter lay...
Predicted distribution of visible and near-infrared radiant flux above and below a transmittant leaf

NASA Technical Reports Server (NTRS)

Roberts, Dar A.; Adams, John B.; Smith, Milton O.

1990-01-01

The effects are studied analytically of leaf size, leaf height, and background reflectance on the upward and downward radiant flux (RF) of a leaf. The leaf is horizontal and isotropically scattering in the computer model which examines the light environment in three regions about the leaf. The spectral properties of the leaf are based on measurements of the big-leaf maple, and the model is interpreted in terms of relative RF which is defined as a percentage of the total light in the model. The results demonstrate the dependence of upward relative RF on the light's wavelength and background reflectance with large variations in the NIR. Brightness varies directly with distance from background with maximum brightness achieved at lower heights for smaller leaves. These and other results suggest that NIR canopy reflectance due to leaves is highly dependent on the background reflectance.
Height Growth of Mahogany Seedlings, St. Croix, Virgin Islands

Treesearch

R. W. Nobles; C. B. Briscoe

1966-01-01

Small-leaf mahogany seedlings grew more rapidly than bigleaf and their hybrids grew more rapidly than either for the first two years. However, by age 4 and continuing through age 7, both hybrids and bigleaf were significantly taller than small-leaf. Bigleaf suffered the most mortality, followed by small-leaf, then the two hybrids.
Modeling the Impact of Land Use Change on Regional Water Flux in Northern Wisconsin-Species Effects on Transpiration and Canopy Average Stomatal Conductance

NASA Astrophysics Data System (ADS)

Ewers, B. E.; Mackay, D. S.; Ahl, D. E.; Burrows, S. N.; Samanta, S. S.; Gower, S. T.

2001-05-01

Land use change has created a diversity of forest cover types in northern Wisconsin. Our objective was to determine if changes in forest cover would result in a significant change in regional water flux. To adequately sample these forest cover types we chose four cover types red pine, sugar maple/basswood, quaking aspen/balsam fir, and northern white-cedar/balsam fir/green alder that represent more than 80 percent of the ground area. The remainder of the ground area is mostly non-forested grassland, shrubland, and open water. Within each cover type we measured sap flux of 8 trees of each species. We scaled point measurements of sap flux to tree transpiration using sensors positioned radially into the conducting sapwood and on both the north and south sides of the tree. We found that aspen/balsam fir had the highest average daily transpiration rates. There was no difference in the northern white-cedar/balsam fir/green alder and red pine cover types. The sugar maple/basswood cover type had the lowest daily average transpiration rate. These changes in transpiration could not be explained by differences in leaf area index. Thus, we calculated canopy average stomatal conductance (GS) using an inversion of the Penman-Monteith equation and tree leaf area. We modified a regional hydrology model to include a simple tree hydraulic sub-model that assumes stomatal regulation of leaf water potential. We tested the behavior of the sub-model by evaluating GS response to vapor pressure deficit, radiation, temperature, and soil moisture for each species. We hypothesize that species with a high canopy average stomatal conductance at low vapor pressure deficit will have to have greater sensitivity to vapor pressure deficit in order to maintain minimal leaf water potential as suggested by the model. Our results indicate that changes to forest cover such as conversion from low transpiring sugar maple/basswood to high transpiring aspen/fir will result in predictable changes to the regional water balance of northern Wisconsin.
Leaf Size in Swietenia

Treesearch

Charles B. Briscoe; F. Bruce Lamb

1962-01-01

A study was made of the putative hybrid of bigleaf and small-leaf mahoganies. Initial measurements indicated that bigleaf mahogany can be distinguished from small-leaf mahogany by gross measurements of leaflets. Isolated mother trees yield typical progeny. Typical mother trees in mixed stands yield like progeny plus, usually, mediumleaf progeny. Mediumleaf mother trees...
Height Growth of Mahogany Seedlings

Treesearch

C. B. Briscoe; R. W. Nobles

1962-01-01

Since the recognition of natural hybridization of small-leaf (West Indies) mahogany (Swietenia mahagoni Jacq.) with bigleaf (Honduras) mahogany (S. macrophylla King) there has been conjecture about their relative growth rates. One would expect small-leaf to be the fastest growing on dry sites, the hybrids to be fastest on intermediate sites, and bigleaf to excel on wet...
A novel disease of big-leaf mahogany caused by two Fusarium species in Mexico

USDA-ARS?s Scientific Manuscript database

Swietenia macrophylla is valued for its high-quality wood and use in urban landscapes in Mexico. During surveys of mango-producing areas in the central western region of Mexico, symptoms of malformation, the most important disease of mango in the area, were observed on big-leaf mahogany trees. The o...
Big-Leaf Mahogany on CITES Appendix II: Big Challenge, Big Opportunity

Treesearch

JAMES GROGAN; PAULO BARRETO

2005-01-01

On 15 November 2003, big-leaf mahogany (Swietenia macrophylla King, Meliaceae), the most valuable widely traded Neotropical timber tree, gained strengthened regulatory protection from its listing on Appendix II of the Convention on International Trade in Endangered Species ofWild Fauna and Flora (CITES). CITES is a United Nations-chartered agreement signed by 164...
Big-leaf mahogany (Swietenia macrophylla) seedling survival and growth across a topographic gradient in southeast Pará, Brazil

Treesearch

James Grogana; Mark S. Ashtona; Galv& atilde; Jurandir oc

2003-01-01

Adult populations of big-leaf mahogany (Swietenia macrophylla) occur in aggregations along seasonal streams in transitional evergreen forests of southeast Pará, Brazil. To test whether variable seedling survival and growth across topography may underlie this observed distribution pattern, we planted nursery-grown seedlings in the...
NIRS Identification of Swietenia Macrophylla is Robust Across Specimens from 27 Countries

Treesearch

Maria C.J. Bergo; Tereza C.M. Pastore; Vera T.R. Coradin; Alex C. Wiedenhoeft; Jez W.B. Braga

2016-01-01

Big-leaf mahogany is the worldâs most valuable widely traded tropical timber species and Near Infrared Spectroscopy (NIRS) has been applied as a tool for discriminating its wood from similar species using multivariate analysis. In this study four look-alike timbers of Swietenia macrophylla (mahogany or big-leaf mahogany), Carapa...
The importance of tree size and fecundity for wind dispersal of big-leaf mahogany

Treesearch

Julian M. Norghauer; Charles A. Nock; James Grogan

2011-01-01

Seed dispersal by wind is a critical yet poorly understood process in tropical forest trees. How tree size and fecundity affect this process at the population level remains largely unknown because of insufficient replication across adults. We measured seed dispersal by the endangered neotropical timber species big-leaf mahogany (Swietenia macrophylla King, Meliaceae)...
Conservative nutrient use by big-leaf mahogany (Swietenia macrophylla King) planted under contrasting environmental conditions

Treesearch

E. Medina; E. Cuevas; A.E. Lugo; E. Terezo; J. Jimenez-Osornio; P.A. Macario-Mendoza; P. Montanez

2014-01-01

We analyzed the nutritional composition and isotope ratios (C and N) of big-leaf mahogany (Swietenia macrophylla King) leaves in plantations established on contrasting soils and climates in Central America (State of Quintana Roo, Yucatan, Mexico) and South America (State of Para, Brazil). The objective was to determine the adaptability of this species to large...
Over-harvesting driven by consumer demand leads to population decline: big-leaf mahogany in South America

Treesearch

James Grogan; Arthur G. Blundell; R. Matthew Landis; Ani Youatt; Raymond E. Gullison; Martha Martinez; Roberto Kometter; Marco Lentini; Richard E. Rice

2010-01-01

Consumer demand for the premier neotropical luxury timber, big-leaf mahogany (Swietenia macrophylla), has driven boom-and-bust logging cycles for centuries, depleting local and regional supplies from Mexico to Bolivia. We revise the standard historic range map for mahogany in South America and estimate the extent to which commercial stocks have been depleted using...
Growth response by big-leaf mahogany (Swietenia macrophylla) advance seedling regeneration to overhead canopy release in southeast Pará, Brazil

Treesearch

James Grogana; R. Matthew Landisc; Mark S. Ashtona; Jurandir Galva˜od

2005-01-01

Big-leaf mahogany (Swietenia macrophylla) is a valuable neotropical timber species whose seedling survival and growth dynamics in natural forests are poorly understood. To document regeneration dynamics of mahogany in seasonal transitional evergreen forests of southeast Pará, Brazil, we followed naturally established seedlings in the forest understory...
Flowering phenology and its implications for management of big-leaf mahogany Swietenia macrophylla in Brazilian Amazonia

Treesearch

J. Grogan; M. D. Loveless

2013-01-01

Premise of the study: Flowering phenology is a crucial determinant of reproductive success and offspring genetic diversity in plants. We measure the fl owering phenology of big-leaf mahogany ( Swietenia macrophylla , Meliaceae), a widely distributed neotropical tree, and explore how disturbance from logging impacts its reproductive biology. â¢ Methods: We use a crown...
Factors Limiting Post-logging Seedling Regeneration by Big-leaf Mahogany (Swietenia macrophylla) in Southeastern Amazonia, Brazil, and Implications for Sustainable Management

Treesearch

James Grogan; Jurandir Galvao

2006-01-01

Post-logging seedling regeneration density by big-leaf mahogany (Swietenia macrophylla), a nonpioneer light-demanding timber species, is generally reported to be low to nonexistent. To investigate factors limiting seedling density following logging within the study region, we quantified seed production rates, germinability, dispersal patterns, and seed fates on the...
Variation of Specific Gravity in Plantation-Grown Trees of Bigleaf Mahogany

Treesearch

C. B. Briscoe; J. B. Harris; D. Wyckoff

1963-01-01

As a prelude to tree improvement work in the genus Swietenia, a study was made of specific gravity variation within the bole of six plantation-grown trees of bigleaf mahogany. Variation was appreciable, from 0.36 to 0.65 , and several patterns were determined. Specific gravity of the tree increased with growth rate, as expressed in diameter at breast height, but not...
Survival, growth and reproduction by big-leaf mahogany (Swietenia macrophylla) in open clearing vs. forested conditions in Brazil

Treesearch

James Grogan; Mark Schulze; Jurandir Galvao

2010-01-01

Big-leaf mahogany (Swietenia macrophylla) trees are often retained in agricultural fields and pastures for seed and timber production after selective logging and forest clearing in the Brazilian Amazon. At a forest management site in southeast ParaÂ´, we censused trees growing scattered across a large open clearing after forest removal and in heavily disturbed forest...
Modeling canopy-level productivity: is the "big-leaf" simplification acceptable?

NASA Astrophysics Data System (ADS)

Sprintsin, M.; Chen, J. M.

2009-05-01

The "big-leaf" approach to calculating the carbon balance of plant canopies assumes that canopy carbon fluxes have the same relative responses to the environment as any single unshaded leaf in the upper canopy. Widely used light use efficiency models are essentially simplified versions of the big-leaf model. Despite its wide acceptance, subsequent developments in the modeling of leaf photosynthesis and measurements of canopy physiology have brought into question the assumptions behind this approach showing that big leaf approximation is inadequate for simulating canopy photosynthesis because of the additional leaf internal control on carbon assimilation and because of the non-linear response of photosynthesis on leaf nitrogen and absorbed light, and changes in leaf microenvironment with canopy depth. To avoid this problem a sunlit/shaded leaf separation approach, within which the vegetation is treated as two big leaves under different illumination conditions, is gradually replacing the "big-leaf" strategy, for applications at local and regional scales. Such separation is now widely accepted as a more accurate and physiologically based approach for modeling canopy photosynthesis. Here we compare both strategies for Gross Primary Production (GPP) modeling using the Boreal Ecosystem Productivity Simulator (BEPS) at local (tower footprint) scale for different land cover types spread over North America: two broadleaf forests (Harvard, Massachusetts and Missouri Ozark, Missouri); two coniferous forests (Howland, Maine and Old Black Spruce, Saskatchewan); Lost Creek shrubland site (Wisconsin) and Mer Bleue petland (Ontario). BEPS calculates carbon fixation by scaling Farquhar's leaf biochemical model up to canopy level with stomatal conductance estimated by a modified version of the Ball-Woodrow-Berry model. The "big-leaf" approach was parameterized using derived leaf level parameters scaled up to canopy level by means of Leaf Area Index. The influence of sunlit/shaded leaf separation on GPP prediction was evaluated accounting for the degree of the deviation of 3-dimensional leaf spatial distribution from the random case. More specifically, we compared and evaluated the behavior of both models showing the advantages of sunlit/shaded leaf separation strategy over a simplified big-leaf approach. Keywords: canopy photosynthesis, leaf area index, clumping index, remote sensing.
What loggers leave behind: Impacts on big-leaf mahogany (Swietenia macrophylla) commercial populations and potential for post-logging recovery in the Brazilian Amazon.

Treesearch

James Grogan; Stephen B. Jennings; R. Matthew Landis; Mark Schulze; Anadilza M.V. Baima; do Carmo A. Lopes J.; Julian M. Norghauer; L. Rog& eacute Oliveira; rio; Frank Pantoja; Diane Pinto; Jose Natalino M. Silva; Edson Vidal; Barbara L. Zimmerman

2008-01-01

The sustainability of current harvest practices for high-value Meliaceae can be assessed by quantifying logging intensity and projecting growth and survival by post-logging populations over anticipated intervals between harvests. From 100%-area inventories of big-leaf mahogany (Swietenia macrophylla) covering 204 ha or more at eight logged and unlogged forest sites...

Growth history and crown vine coverage are principal factors influencing growth and mortality rates of big-leaf mahogany Swietenia macrophylla in Brazil

Treesearch

James Grogan; R. Matthew Landis

2009-01-01

1. Current efforts to model population dynamics of high-value tropical timber species largely assume that individual growth history is unimportant to population dynamics, yet growth autocorrelation is known to adversely affect model predictions. In this study, we analyse a decade of annual census data from a natural population of big-leaf mahogany Swietenia macrophylla...
Performance and genetic variation of big-leaf mahogany (Swietenia macrophylla King) in provenance and progeny trials in the Yucatan Peninsula of Mexico.

Treesearch

Kevyn E. Wightman; Sheila E. Ward; Jeremy P. Haggar; Bartolo Rodriguez Santiago; Jonathan P. Cornelius

2008-01-01

Stocks of the valuable big-leaf mahogany (Swietenia macrophylla King) are declining, and trials for growth and pest resistance are needed to select material for plantations. Seeds were collected from 67 open-pollinated trees from five provenances in the Yucatan Peninsula of Mexico and planted in three provenance/progeny trials in the state of Quintana Roo, Mexico, in...
Red alder stand development and dynamics.

Treesearch

R.L. Deal

2006-01-01

This paper synthesizes information on the development of natural pure red alder stands and dynamics of mixed alder-conifer stands. Early research on red alder growth and yield focused on developing stand volume and normal yield. tables for alder in the Pacific Northwest. Recent site-index estimation and height-growth curves were developed on a 20-year site base age....
Silvical characteristics of red maple (Acer rubrum)

Treesearch

Russell J. Hutnik; Harry W. Yawney

1961-01-01

Red maple (Acer rubrum L.) is also known as Carolina red maple, scarlet maple, soft maple, swamp maple, water maple, and white maple. Taxonomists recognize several varieties of red maple. The most common is Drummond red maple (Acer rubrum var. drummondii (Hook, & Arn.) Sarg.).
Comparative effects of precommercial thinning, urea fertilizer, and red alder in a site II, coast Douglas-fir plantation.

Treesearch

Richard E. Miller; Edmund L. Obermeyer; Harry W. Anderson

1999-01-01

We varied the number of red alder retained with 300 Douglas-fir per acre on a high-quality site in coastal Oregon. Alder densities of 0, 20, 40, and 80 per acre were tested. Our fifth treatment eliminated nitrogen-fixing alder, but substituted nitrogen fertilizer. Treatment 6 had neither thinning nor alder control. Treatments were randomly assigned within each of three...
The role of red alder in riparian forest structure along headwater streams in southeastern Alaska

USGS Publications Warehouse

Orlikowska, E.H.; Deal, R.L.; Hennon, P.E.; Wipfli, M.S.

2004-01-01

We assessed the influence of red alder on tree species composition, stand density, tree size distribution, tree mortality, and potential for producing large conifers, in 38-42 yr old riparian forests along 13 headwater streams in the Maybeso and Harris watersheds on Prince of Wales Island, Alaska. Red alder ranged from 0 to 53% of the total live basal area of the stands. Tree density, basal area of live and dead trees, and mean diameter of live conifers were not significantly related to the percent of alder as a proportion of total stand live basal area within these riparian forests. The mean diameter of the 100 largest conifers per hectare (the largest trees) was similar among different sites and appeared unrelated to the amount of alder in the stands. The mean diameter of dead conifers increased slightly with increasing proportion of red alder. Most dead trees were small and died standing. Red alder was much more concentrated immediately along stream margins (within 0-1 m distance from the stream bank vs. > 1 m). The presence of red alder did not inhibit the production of large-diameter conifers, and both alder and conifers provided small woody debris for fishless headwater streams in southeastern Alaska. Red alder is an important structural component of young-growth riparian stands.
Origins of Stereoselectivity in the trans-Diels-Alder Paradigm

PubMed Central

Paton, Robert S.; Mackey, Joel L.; Kim, Woo Han; Lee, Jun Hee; Danishefsky, Samuel J.; Houk, K. N.

2010-01-01

The regioselectivity and stereoselectivity aspects of the Diels-Alder/radical hydrodenitration reaction sequence leading to trans-fused ring systems have been investigated with density functional calculations. A continuum of transition structures representing Diels-Alder and hetero-Diels-Alder cycloadditions as well as a sigmatropic rearrangement have been located, and they all lie very close in energy on the potential energy surface. All three pathways are found to be important in the formation of the Diels-Alder adduct. Reported regioselectivities are reproduced by the calculations. The stereoselectivity of radical hydrodenitration of the cis-Diels-Alder adduct is found to be related to the relative conformational stabilities of bicyclic radical intermediates. Overall, the computations provide understanding of the regioselectivities and stereoselectivities of the trans-Diels-Alder paradigm. PMID:20557046
Scaling up stomatal conductance from leaf to canopy using a dual-leaf model for estimating crop evapotranspiration.

PubMed

Ding, Risheng; Kang, Shaozhong; Du, Taisheng; Hao, Xinmei; Zhang, Yanqun

2014-01-01

The dual-source Shuttleworth-Wallace model has been widely used to estimate and partition crop evapotranspiration (λET). Canopy stomatal conductance (Gsc), an essential parameter of the model, is often calculated by scaling up leaf stomatal conductance, considering the canopy as one single leaf in a so-called "big-leaf" model. However, Gsc can be overestimated or underestimated depending on leaf area index level in the big-leaf model, due to a non-linear stomatal response to light. A dual-leaf model, scaling up Gsc from leaf to canopy, was developed in this study. The non-linear stomata-light relationship was incorporated by dividing the canopy into sunlit and shaded fractions and calculating each fraction separately according to absorbed irradiances. The model includes: (1) the absorbed irradiance, determined by separately integrating the sunlit and shaded leaves with consideration of both beam and diffuse radiation; (2) leaf area for the sunlit and shaded fractions; and (3) a leaf conductance model that accounts for the response of stomata to PAR, vapor pressure deficit and available soil water. In contrast to the significant errors of Gsc in the big-leaf model, the predicted Gsc using the dual-leaf model had a high degree of data-model agreement; the slope of the linear regression between daytime predictions and measurements was 1.01 (R2 = 0.98), with RMSE of 0.6120 mm s-1 for four clear-sky days in different growth stages. The estimates of half-hourly λET using the dual-source dual-leaf model (DSDL) agreed well with measurements and the error was within 5% during two growing seasons of maize with differing hydrometeorological and management strategies. Moreover, the estimates of soil evaporation using the DSDL model closely matched actual measurements. Our results indicate that the DSDL model can produce more accurate estimation of Gsc and λET, compared to the big-leaf model, and thus is an effective alternative approach for estimating and partitioning λET.
Alder (Alnus crispa) effects on soils in ecosystems of the Agashashok River valley, northwest Alaska

USGS Publications Warehouse

Rhoades, Charles; Oskarsson, Hlynur; Binkley, Dan; Stottlemeyer, Robert

2001-01-01

At the northern limit of the boreal forest biome, alder (Alnus crispa [Ait.] Pursh) shrubs occur in a variety of ecosystems. We assessed the effects of individual alder shrubs on soil properties and understory plant tissue nitrogen in floodplain terraces, valley slopes and tussock tundra ridges. The three ecosystems differed with respect to soil properties and abiotic conditions and supported distinct plant communities. Alder increased resin-exchangeable soil N and NO3 production significantly in each ecosystem. The greatest difference between alder canopy and surrounding soil NO3 measured both under field and laboratory conditions occurred in floodplain sites. The shrub effect on soil pH and soil organic matter was greatest on tundra ridges. Alder shrubs also influenced the nitrogen nutrition of plants growing beneath their canopies. Plants growing below alder canopies had higher foliar nitrogen concentration and natural abundance 15N composition and lower carbon to nitrogen ratio than open-grown plants. Similar to soil N availability, understory plant leaf chemistry responded more to alder on floodplains than on slope or tundra ecosystems. This pattern suggests that understory plants rely more heavily on alder-fixed-N in this resource-poor ecosystem.
Site curves for red alder.

Treesearch

Daniel M. Bishop; Floyd A. Johnson

1958-01-01

The increasing commercial importance of red alder (Alnus rubra) in the Pacific Northwest has created a demand for research on this species. Noting the lack of information on growth of alder, the Puget Sound Research Center Advisory Committee established a subcommittee in January 1956 to undertake construction of alder yield tables. Through the...
Red alder potential in Alaska

Treesearch

Allen Brackley; David Nicholls; Mike Hannan

2010-01-01

Over the past several decades, red alder has established itself as a commercially important species in the Pacific Northwest. Once considered a weed species, red alder now commands respect within many markets, including furniture, architectural millwork, and other secondary manufactured products. Although red alder's natural range extends to southeast Alaska, an...
Microwave-based reaction screening: tandem retro-Diels-Alder/Diels-Alder cycloadditions of o-quinol dimers.

PubMed

Dong, Suwei; Cahill, Katharine J; Kang, Moon-Il; Colburn, Nancy H; Henrich, Curtis J; Wilson, Jennifer A; Beutler, John A; Johnson, Richard P; Porco, John A

2011-11-04

We have accomplished a parallel screen of cycloaddition partners for o-quinols utilizing a plate-based microwave system. Microwave irradiation improves the efficiency of retro-Diels-Alder/Diels-Alder cascades of o-quinol dimers which generally proceed in a diastereoselective fashion. Computational studies indicate that asynchronous transition states are favored in Diels-Alder cycloadditions of o-quinols. Subsequent biological evaluation of a collection of cycloadducts has identified an inhibitor of activator protein-1 (AP-1), an oncogenic transcription factor.
Heterogeneous Diels–Alder catalysis for biomass-derived aromatic compounds

DOE PAGES

Settle, Amy E.; Berstis, Laura; Rorrer, Nicholas A.; ...

2017-05-17

In this tutorial review, we provide an overview of heterogeneous Diels–Alder catalysis for the production of lignocellulosic biomass-derived aromatic compounds. Diels–Alder reactions afford an extremely selective and efficient route for carbon–carbon cycloadditions to produce intermediates that can readily undergo subsequent dehydration or dehydrogenation reactions for aromatization. As a result, catalysis of Diels–Alder reactions with biomass-derived dienes and dienophiles has seen a growth of interest in recent years; however, significant opportunities remain to (i) tailor heterogeneous catalyst materials for tandem Diels–Alder and aromatization reactions, and (ii) utilize biomass-derived dienes and dienophiles to access both conventional and novel aromatic monomers. As such,more » this review discusses the mechanistic aspects of Diels–Alder reactions from both an experimental and computational perspective, as well as the synergy of Brønsted–Lewis acid catalysts to facilitate tandem Diels–Alder and aromatization reactions. Heterogeneous catalyst design strategies for Diels–Alder reactions are reviewed for two exemplary solid acid catalysts, zeolites and polyoxometalates, and recent efforts for targeting direct replacement aromatic monomers from biomass are summarized. In conclusion, we point out important research directions for progressing Diels–Alder catalysis to target novel, aromatic monomers with chemical functionality that enables new properties compared to monomers that are readily accessible from petroleum.« less
Reclamation of a lignite combustion waste disposal site with alders (Alnus sp.): assessment of tree growth and nutrient status within 10 years of the experiment.

PubMed

Pietrzykowski, Marcin; Woś, Bartłomiej; Pająk, Marek; Wanic, Tomasz; Krzaklewski, Wojciech; Chodak, Marcin

2018-06-01

Combustion wastes are characterised by extremely low N contents. Therefore, introduction of nitrogen-fixing species at the first stage of their biological reclamation is required. This paper presents an assessment of the growth parameters of alders (Alnus sp.) 10 years after their introduction to a disposal site of lignite combustion waste in Central Poland. Black (Alnus glutinosa) and grey alders (Alnus incana) were planted directly in the combustion waste. The soil amendment included three variants: control with pure combustion waste, admixture of lignite culm and addition of acid sand. Both alder species displayed good growth parameters comparable to those of alders in natural habitats. However, black alder had better growth parameters, such as stand density index (SDI), diameter at breast height (DBH) and height (H) than grey alder. The lignite amendment exerted a positive effect on tree growth, reflected in a higher SDI and H, whereas the acid sand amendment did not affect any of the growth parameters of the studied alder species. Despite the good growth parameters, the measured N:P and N:K ratios in the alder leaves largely differed from the optimal values indicating insufficient P and K supply at the combustion waste disposal site. This may pose a threat to further development of the introduced tree plantings. The introduction of alders along with the lignite addition into the planting holes seems to be a successful method of combustion waste revegetation.
Utilization and management of alder.

Treesearch

David G. Briggs; Dean S. DeBell; William A. Atkinson

1978-01-01

In the Pacific Northwest and British Columbia, red alder often grows on forest lands following natural or man-caused disturbances. Frequently ignored as a pest or weed, many alder stands have developed to the point where important utilization and management questions are being asked. It is recognized that alder is a fast growing species, and that its rapid early growth...
Red alder: a state of knowledge.

Treesearch

Robert L. Deal; Constance A. Harrington

2006-01-01

In March 23-25, 2005, an international symposium on red alder was held at the University of Washington Center for Urban Horticulture in Seattle, WA. The symposium was entitled "Red alder: A State of Knowledge" and brought together regional experts to critically examine the economic, ecological and social values of red alder. The primary goal of the symposium...
Microwave-Based Reaction Screening: Tandem Retro-Diels-Alder/Diels-Alder Cycloadditions of ortho-Quinol Dimers

PubMed Central

Dong, Suwei; Cahill, Kath arine J.; Kang, Moon -Il; Colburn, Nancy H.; Henrich, Curtis J.; Wilson, Jennifer A.; Beutler, John A.; Johnson, Richard P.; Porco, John A.

2011-01-01

We have accomplished a parallel screen of cycloaddition partners for ortho-quinols utilizing a plate-based microwave system. Microwave irradiation improves the efficiency of retro-Diels-Alder/Diels-Alder cascades of ortho-quinol dimers which generally proceed in a diastereoselective fashion. Computational studies indicate that asynchronous transition states are favored in Diels-Alder cycloadditions of ortho-quinols. Subsequent biological evaluation of a collection of cycloadducts has identified an inhibitor of activator protein-1 (AP-1), an oncogenic transcription factor. PMID:21942286
210 Study on the Sensitization Rates to Airbone Pollen and Mold in Children

PubMed Central

Park, So Hyun; Lim, Dae Hyun; Son, Byong Kwan; Kim, Jeong Hee; Oh, In Bo; Kim, Yang Ho; Lee, Keun Hwa; Kim, Su Young; Hong, Sung Chul

2012-01-01

Background Aeroallergens are important causative factors for allergies such as allergic rhinitis, allergic conjunctivitis and asthma. Previous studies for the sensitization rate to aeroallergen were based on those patient groups who had visited the pediatric allergy clinic. Compared to that, we inquired into the sensitization rates based on general school aged student population group in the city of Incheon, Jeju and Ulsan. Methods With informed consent, skin prick tests were performed on 5,094 students between April and June, 2010. Common 21 aeroallergens were used on elementary school student while middle and high school students were tested upon 28 allergens. 28 allergen list as positive control (1%Histamine), negative control (Normal saline), D.pteronyssinus, D.farinae, Citrus red mite, pollen (Birch, Alder, Oak, Japanese cedar, Pine, Willow, Elm, Maple, Bermuda grass, Timothy grass, Rye grass, Orchard, Meadow grass, Vernal grass, Mugwort, Japanese hop, Fat hen, Ragweed, Plantain), mold (Penicillatum, Asperugillus, Cladosporium, Alternaria) and 21 kinds of allergens that were used on elementary school students count as same as above except Elm, Rye grass, Orchard, Meadow grass, Vernal grass, Fat hen, Plantain. Results If arranged in rates of higher sensitization were D. pteronyssinus (25.79%), D. farinae (18.66%), Mugwort (6.20%), Willow (4.07%) in Incheon, D. pteronyssinus (33.35%), D. farinae (24.78%), Japanese cedar (15.36%), Alternaria (7.33%) in Jeju, D. pteronyssinus (32.79%), D. farinae (30.27%), Alder (10.13%), Birch (8.68%) in Ulsan respectively. The sensitization rate of Japanese cedar was statistically significantly higher in Jeju. The sensitization rate of Birch, Alder, Oak was higher in Ulsan. The sensitization rate of Ragweed was 0.99% in Incheon, 1.07% in Jeju, 0.81% in Ulsan. The sensitization rate of Mugwort in Incheon was 6.20% which was meaningfully higher in comparison to 2.32% of Jeju and 2.73% of Ulsan. The sensitization rate of Alternaria was 2.98% in Incheon, 7.33% in Jeju, 2.39% in Ulsan and as we can see it was higher in Jeju. The sensitization rate of Dermatophagoides had an increasing tendency with increasing age. Conclusions Changes in exposure rate to allergens with increasing ages brings changes in sensitization rates. And because there are changes in sensitization rates due to different regional living environmental status and discrepancies of surrounding biologic species, this would leave us there lies needs for subsequent studies and nationwide researches.
Effects of Alder Mine on the Water, Sediments, and Benthic Macroinvertebrates of Alder Creek, 1998 Annual Report.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peplow, Dan

1999-05-28

The Alder Mine, an abandoned gold, silver, copper, and zinc mine in Okanogan County, Washington, produces heavy metal-laden effluent that affects the quality of water in a tributary of the Methow River. The annual mass loading of heavy metals from two audits at the Alder Mine was estimated to exceed 11,000 kg per year. In this study, water samples from stations along Alder Creek were assayed for heavy metals by ICP-AES and were found to exceed Washington State's acute freshwater criteria for cadmium (Cd), copper (Cu), selenium (Se), and zinc (Zn).
Understory plant diversity in riparian alder-conifer stands after logging in southeast Alaska.

Treesearch

Robert L. Deal

1997-01-01

Stand structure, tree height growth, and understory plant diversity were assessed in five mixed alder-conifer stands after logging in southeast Alaska. Tree species composition ranged from 7- to 91-percent alder, and basal area ranged from 30 to 55 m2/ha. The alder exhibited rapid early height growth, but recent growth has slowed considerably. Some conifers have...

Control of red alder by cutting.

Treesearch

Dean S. DeBell; Thomas C. Turpin

1989-01-01

Effects of tree age, month of cut, and height and angle of cut on sprouting of red alder stumps were evaluated in a study designed to develop an effective method for controlling red alder in Douglas-fir plantations. Ninety-five percent or more of alder stumps cut in June or July died by the end of the next growing season; mortality was 88, 70, and 22 percent for stumps...
DOE Office of Scientific and Technical Information (OSTI.GOV)

Settle, Amy E.; Berstis, Laura; Rorrer, Nicholas A.

In this tutorial review, we provide an overview of heterogeneous Diels–Alder catalysis for the production of lignocellulosic biomass-derived aromatic compounds. Diels–Alder reactions afford an extremely selective and efficient route for carbon–carbon cycloadditions to produce intermediates that can readily undergo subsequent dehydration or dehydrogenation reactions for aromatization. As a result, catalysis of Diels–Alder reactions with biomass-derived dienes and dienophiles has seen a growth of interest in recent years; however, significant opportunities remain to (i) tailor heterogeneous catalyst materials for tandem Diels–Alder and aromatization reactions, and (ii) utilize biomass-derived dienes and dienophiles to access both conventional and novel aromatic monomers. As such,more » this review discusses the mechanistic aspects of Diels–Alder reactions from both an experimental and computational perspective, as well as the synergy of Brønsted–Lewis acid catalysts to facilitate tandem Diels–Alder and aromatization reactions. Heterogeneous catalyst design strategies for Diels–Alder reactions are reviewed for two exemplary solid acid catalysts, zeolites and polyoxometalates, and recent efforts for targeting direct replacement aromatic monomers from biomass are summarized. In conclusion, we point out important research directions for progressing Diels–Alder catalysis to target novel, aromatic monomers with chemical functionality that enables new properties compared to monomers that are readily accessible from petroleum.« less
Chemical and physical properties of two-year short-rotation deciduous species. [Olea sp. , Populus deltoides, Platanus sp. , Alnus glutinosa, Paulownia tomentosa, Robina pseudoacacia, Acer saccharinum

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee, C.S

1982-01-01

The following seven broadleaved species were tested: autumn olive (Olea sp.) eastern cottonwood (Populus deltoides), sycamore (Platanus species), black alder (Alnus glutinosa), royal paulownia (Paulownia tomentosa), black locust (Robina pseudoacacia) and silver maple (Acer saccharinum). The species and portions both significantly affected the chemical and the physical findings of the juvenile wood. The ages, which were tested in factorial combination with the species, also showed a significant effect on both the chemical and the physical properties of wood. All of the results indicated that both chemical and physical properties did vary with species, among the portions of the wood, andmore » according to the ages of the wood. From the portion standpoint, the bark had higher gross heat content, sulphur content, ash content and lignin content, and it was also higher in all three kinds of extractives contents. The wood portion was found to be rich in holocellulose, alpha-cellulose and pentosan. In considering the chemical and physical properties of juvenile wood among the species, eastern cottonwood was found to have the highest value for ash content and all of the three kinds of extractives content. Paulownia had the highest value for sulphur content. Black locust had highest gross heat content, holocellulose and alpha-cellulose contents. Silver maple had highest lignin content. Results from this study showed that these seven juvenile hardwood species can produce high biomass yields of fibre and energy when grown under intensive care in central and southern Illinois sites. The best species of these seven tested woods seem to be black locust, which could also serve as a raw material for the pulp and paper industry, as well as for a fuel for energy generation. However, further economic and energy efficiency analyses are needed before judging the feasibility of these short-rotation juvenile hardwood species.« less
Enzymatic catalysis of the Diels-Alder reaction in the biosynthesis of natural products.

PubMed

Oikawa, Hideaki; Tokiwano, Tetsuo

2004-06-01

Recent studies on enzymes catalyzing the Diels- Alder reaction. often named "Diels-Alderases", clearlydemonstrated the involvement of this synthetically useful reaction in the biosynthesis of natural products.This review covers natural Diels-Alder type cycloadducts. synthetic efforts on the chemical feasibility ofthe biosynthctic Diels - Alder reaction and a brief history of studies on Diels-Alderases. In addition,reaction mechanisms of artificial and natural Diels--Alderases are discussed.
A facile microwave-assisted Diels-Alder reaction of vinylboronates.

PubMed

Sarotti, Ariel M; Pisano, Pablo L; Pellegrinet, Silvina C

2010-11-21

The Diels-Alder reaction of vinylboronates can be easily performed using microwave irradiation giving excellent yields of the cycloadducts. Pinacol vinylboronate was the reagent of choice due to its stability towards hydrolysis, operational simplicity and yields of Diels-Alder products. To the best of our knowledge, this is the first example of microwave-assisted Diels-Alder reaction of boron-substituted dienophiles. Subsequent in situ oxidation of the cycloadducts with alkaline hydrogen peroxide afforded the alcohols efficiently.
Development and UFLC-MS/MS Characterization of a Product-Specific Standard for Phenolic Quantification of Maple-Derived Foods.

PubMed

Liu, Yongqiang; Ma, Hang; Seeram, Navindra P

2016-05-04

The phenolic contents of plant foods are commonly quantified by the Folin-Ciocalteu assay based on gallic acid equivalents (GAEs). However, this may lead to inaccuracies because gallic acid is not always representative of the structural heterogeneity of plant phenolics. Therefore, product-specific standards have been developed for the phenolic quantification of several foods. Currently, maple-derived foods (syrup, sugar, sap/water, and extracts) are quantified for phenolic contents based on GAEs. Because lignans are the predominant phenolics present in maple, herein, a maple phenolic lignan-enriched standard (MaPLES) was purified (by chromatography) and characterized (by UFLC-MS/MS with lignans previously isolated from maple syrup). Using MaPLES and secoisolariciresinol (a commercially available lignan), the phenolic contents of the maple-derived foods increased 3-fold compared to GAEs. Therefore, lignan-based standards are more appropriate for phenolic quantification of maple-derived foods versus GAEs. Also, MaPLES can be utilized for the authentication and detection of fake label claims on maple products.
7 CFR 1437.107 - Maple sap.

Code of Federal Regulations, 2014 CFR

2014-01-01

... Yield Coverage Using Actual Production History § 1437.107 Maple sap. (a) NAP assistance for maple sap is... maple sap. (g) The actual production history for maple sap shall be recorded on the basis of gallons of...
7 CFR 1437.107 - Maple sap.

Code of Federal Regulations, 2011 CFR

2011-01-01

... Yield Coverage Using Actual Production History § 1437.107 Maple sap. (a) NAP assistance for maple sap is... maple sap. (g) The actual production history for maple sap shall be recorded on the basis of gallons of...
21 CFR 168.140 - Maple sirup.

Code of Federal Regulations, 2010 CFR

2010-04-01

... § 168.140 Maple sirup. (a) Maple sirup is the liquid food derived by concentration and heat treatment of the sap of the maple tree (Acer) or by solution in water of maple sugar (mapel concrete) made from...
21 CFR 168.140 - Maple sirup.

Code of Federal Regulations, 2013 CFR

2013-04-01

... § 168.140 Maple sirup. (a) Maple sirup is the liquid food derived by concentration and heat treatment of the sap of the maple tree (Acer) or by solution in water of maple sugar (mapel concrete) made from...
21 CFR 168.140 - Maple sirup.

Code of Federal Regulations, 2014 CFR

2014-04-01

... § 168.140 Maple sirup. (a) Maple sirup is the liquid food derived by concentration and heat treatment of the sap of the maple tree (Acer) or by solution in water of maple sugar (mapel concrete) made from...
21 CFR 168.140 - Maple sirup.

Code of Federal Regulations, 2012 CFR

2012-04-01

... § 168.140 Maple sirup. (a) Maple sirup is the liquid food derived by concentration and heat treatment of the sap of the maple tree (Acer) or by solution in water of maple sugar (mapel concrete) made from...
21 CFR 168.140 - Maple sirup.

Code of Federal Regulations, 2011 CFR

2011-04-01

... § 168.140 Maple sirup. (a) Maple sirup is the liquid food derived by concentration and heat treatment of the sap of the maple tree (Acer) or by solution in water of maple sugar (mapel concrete) made from...
Maple sap predominant microbial contaminants are correlated with the physicochemical and sensorial properties of maple syrup.

PubMed

Filteau, Marie; Lagacé, Luc; Lapointe, Gisèle; Roy, Denis

2012-03-01

Maple sap processing and microbial contamination are significant aspects that affect maple syrup quality. In this study, two sample sets from 2005 and 2008 were used to assess the maple syrup quality variation and its relationship to microbial populations, with respect to processing, production site and harvesting period. The abundance of maple sap predominant bacteria (Pseudomonas fluorescens group and two subgroups, Rahnella spp., Janthinobacterium spp., Leuconostoc mesenteroides) and yeast (Mrakia spp., Mrakiella spp.,Guehomyces pullulans) was assessed by quantitative PCR. Maple syrup properties were analyzed by physicochemical and sensorial methods. Results indicate that P. fluorescens, Mrakia spp., Mrakiella spp. G. pullulans and Rahnella spp. are stable contaminants of maple sap, as they were found for every production site throughout the flow period. Multiple factor analysis reports a link between the relative abundance of P. fluorescens group and Mrakia spp. in maple sap with maple and vanilla odor as well as flavor of maple syrup. This evidence supports the contribution of these microorganisms or a consortium of predominant microbial contaminants to the characteristic properties of maple syrup. Copyright © 2011 Elsevier B.V. All rights reserved.
The effect of the tariff on the maple industry

Treesearch

Paul E. Sendak

1972-01-01

The U. S. maple tariff is a tax on maple syrup and sugar imports from Canada into the United States. An analysis of the maple tariff indicates that it was never very effective in protecting the domestic maple industry from foreign competition. The tariff has been especially ineffective since World War II. Its removal will not hurt the U. S. maple syrup industry.
Normal yield tables for red alder.

Treesearch

Norman P. Worthington; Floyd A. Johnson; George R. Staebler; William J. Lloyd

1960-01-01

Increasing interest in the management of red alder (Alnus rubra) has created a need for reliable yield information. Existing yield tables for red alder have been very useful as interim sources of information, but they are generally inadequate for current and prospective management needs. The advisory committee for the Station's Olympia...
Climate sensitivity of thinleaf alder growth on an interior Alaska floodplain

Treesearch

Dana R. Nossov; Roger W. Ruess; Teresa N. Hollingsworth

2010-01-01

This study examined the climate sensitivity of the growth of riparian Alnus incana ssp. tenuifolia (thinleaf alder), a keystone nitrogen-fixer, on the Tanana River floodplain of interior Alaska. We investigated correlations between alder radial growth and inter-annual variation in monthly meteorology and hydrology, spatial...
Interspecific Plant Interactions Reflected in Soil Bacterial Community Structure and Nitrogen Cycling in Primary Succession

DOE Office of Scientific and Technical Information (OSTI.GOV)

Knelman, Joseph E.; Graham, Emily B.; Prevéy, Janet S.

Past research demonstrating the importance plant-microbe interactions as drivers of ecosystem succession has focused on how plants condition soil microbial communities, impacting subsequent plant performance and successional trajectories in plant community assembly. These studies, however, largely treat microbial communities as a black box. In this study we sought to examine how emblematic shifts from early-successional Alnus sinuata (alder) to late successional Picea sitchensis (spruce) in primary succession may be reflected in specific belowground changes in bacterial community structure and nitrogen cycling related to the interaction of these two plants. We examined early successional alder-conditioned soils in a glacial forefield tomore » delineate how alders alter the soil microbial community with increasing dominance. Further, we assessed the impact of late-successional spruce plants on these early-successional alder-conditioned microbiomes and related nitrogen cycling through a leachate addition microcosm experiment. We show how increasingly abundant alder select for particular bacterial taxa. Additionally, we found that spruce leachate drives shifts in the relative abundance of major taxa of bacteria in alder-influenced soils, including declines in those that are enriched by alder. We found these effects to be spruce-specific, beyond a general leachate effect. Our work also demonstrates a unique influence of spruce on ammonium availability. Our results show that spruce leachate addition more strongly structures bacterial communities than alders (less dispersion in bacterial community beta diversity). Such insights bolster theory relating the importance of plant-microbe interactions with late-successional plants and interspecific plant interactions more generally.« less
Heavy metal stress in alders: Tolerance and vulnerability of the actinorhizal symbiosis.

PubMed

Bélanger, Pier-Anne; Bellenger, Jean-Philippe; Roy, Sébastien

2015-11-01

Alders have already demonstrated their potential for the revegetation of both mining and industrial sites. These actinorhizal trees and shrubs and the actinobacteria Frankia associate in a nitrogen-fixing symbiosis which could however be negatively affected by the presence of heavy metals, and accumulate them. In our hydroponic assay with black alders, quantification of the roots and shoots metal concentrations showed that, in the absence of stress, symbiosis increases Mo and Ni root content and simultaneously decreases Mo shoot content. Interestingly, the Mo shoot content also decreases in the presence of Ni, Cu, Pb, Zn and Cd for symbiotic alders. In symbiotic alders, Pb shoot translocation was promoted in presence of Pb. On the other hand, Cd exclusion in symbiotic root tissues was observed with Pb and Cd. In the presence of symbiosis, only Cd and Pb showed translocation into aerial tissues when present in the nutrient solution. Moreover, the translocation of Ni to shoot was prevented by symbiosis in the presence of Cd, Ni and Pb. The hydroponic experiment demonstrated that alders benefit from the symbiosis, producing more biomass (total, root and shoot) than non nodulated alders in control condition, and in the presence of metals (Cu, Ni, Zn, Pb and Cd). Heavy metals did not reduce the nodule numbers (SNN), but the presence of Zn or Cd did reduce nodule allocation. Our study suggests that the Frankia-alder symbiosis is a promising (and a compatible) plant-microorganism association for the revegetation of contaminated sites, with minimal risk of metal dispersion. Copyright © 2015 Elsevier Ltd. All rights reserved.
Interactions between white spruce and shrubby alders at three boreal forest sites in Alaska.

Treesearch

Tricia L. Wurtz

2000-01-01

To document possible soil nitrogen mosaics before timber harvesting on three boreal forest sites in Alaska, maps of the distribution of understory green (Alnus crispa (Ait.) Pursh) and Sitka alder (A. sitchensis(Reg.) Rydb.) stems were made. Understory alders were regularly distributed throughout the northernmost site (Standard...

Diels-Alder Cycloadditions of Masked o-Benzoquinones with Alkenes.

PubMed

Georgopanou, Effie; Martini, Katerina-Irene; Pantazis, Panagiotis; Pelagias, Paulos; Voulgari, Penelope; Hadjiarapoglou, Lazaros P

2015-10-02

Diels-Alder cycloadditions of 3-oxobut-1-enyl substituted orthoquinone monoketals with olefinic dienophiles furnished functionalized ortho-endo bicyclo[2.2.2]octenone derivatives with high regio- and stereoselectivities. The competition between self-dimerization and Diels-Alder cycloaddition with an external dienophile usually exists, except in the case of 5-substituted orthoquinone monoketal.
Linking Landscape Characteristics and High Stream Nitrogen in the Oregon Coast Range: Red Alder Complicates Use of Nutrient Criteria

EPA Science Inventory

Red alder (a nitrogen-fixing tree) and sea salt inputs can strongly influence stream nitrogen concentrations in western Oregon and Washington. We compiled a database of stream nitrogen and landscape characteristics in the Oregon Coast Range. Basal area of alder, expressed as a ...
CADMIUM EFFECTS ON THE NITROGEN FIXATION SYSTEM OF RED ALDER

EPA Science Inventory

Red alder (Alnus rubra) was grown in sand culture in the greenhouse to obtain data on the effects of cadmium (Cd) on a symbiotic nitrogen (N) fixation system which contributes to the fertility of forest soils. Treatment of red alder seedlings for 11 weeks with 0.545 to 136 microm...
Effect of dark-colored maple syrup on cell proliferation of human gastrointestinal cancer cell

PubMed Central

Yamamoto, Tetsushi; Sato, Kanta; Kubota, Yuika; Mitamura, Kuniko; Taga, Atsushi

2017-01-01

Maple syrup is a natural sweetener that is commonly consumed worldwide. While maple syrup mainly comprises sucrose, it also contains phytochemicals that present various biological effects. Maple syrup is made by boiling down sap, and its color and composition vary in accordance with the sap collection season. Typically, seasonal progression is associated with darker syrup color, and antioxidant activity is proportional to the increasingly dark color. The authors previously reported that maple syrup demonstrated inhibitory effects on colorectal cancer cell growth and invasion, which correlated with darker maple syrup color. In the present study, they examined the effects of two different grades of maple syrup on gastrointestinal cancer cell proliferation, to investigate whether the dark-color maple syrup was suitable as a phytomedicine for gastrointestinal cancer treatment. Administration of dark-color maple syrup significantly inhibited gastrointestinal cancer cell growth as compared to non-treated cancer cells. Moreover, administration of dark-color maple syrup clearly inhibited protein kinase B (AKT) phosphorylation and did not impact mitogen-associated protein kinase phosphorylation. These data suggested that dark-color maple syrup may inhibit cell proliferation through suppression of AKT activation and, thus, may be suitable as a phytomedicine for gastrointestinal cancer treatment. PMID:28685052
Effect of dark-colored maple syrup on cell proliferation of human gastrointestinal cancer cell.

PubMed

Yamamoto, Tetsushi; Sato, Kanta; Kubota, Yuika; Mitamura, Kuniko; Taga, Atsushi

2017-07-01

Maple syrup is a natural sweetener that is commonly consumed worldwide. While maple syrup mainly comprises sucrose, it also contains phytochemicals that present various biological effects. Maple syrup is made by boiling down sap, and its color and composition vary in accordance with the sap collection season. Typically, seasonal progression is associated with darker syrup color, and antioxidant activity is proportional to the increasingly dark color. The authors previously reported that maple syrup demonstrated inhibitory effects on colorectal cancer cell growth and invasion, which correlated with darker maple syrup color. In the present study, they examined the effects of two different grades of maple syrup on gastrointestinal cancer cell proliferation, to investigate whether the dark-color maple syrup was suitable as a phytomedicine for gastrointestinal cancer treatment. Administration of dark-color maple syrup significantly inhibited gastrointestinal cancer cell growth as compared to non-treated cancer cells. Moreover, administration of dark-color maple syrup clearly inhibited protein kinase B (AKT) phosphorylation and did not impact mitogen-associated protein kinase phosphorylation. These data suggested that dark-color maple syrup may inhibit cell proliferation through suppression of AKT activation and, thus, may be suitable as a phytomedicine for gastrointestinal cancer treatment.
Isolation, Identification, and Biological Evaluation of Phenolic Compounds from a Traditional North American Confectionery, Maple Sugar.

PubMed

Liu, Yongqiang; Rose, Kenneth N; DaSilva, Nicholas A; Johnson, Shelby L; Seeram, Navindra P

2017-05-31

Maple sap, collected from the sugar maple (Acer saccharum) tree, is boiled to produce the popular plant-derived sweetener, maple syrup, which can then be further evaporated to yield a traditional North American confectionery, maple sugar. Although maple sap and maple syrup have been previously studied, the phytochemical constituents of maple sugar are unknown. Herein, 30 phenolic compounds, 1-30, primarily lignans, were isolated and identified (by HRESIMS and NMR) from maple sugar. The isolates included the phenylpropanoid-based lignan tetramers (erythro,erythro)-4″,4‴-dihydroxy-3,3',3″,3‴,5,5'-hexamethoxy-7,9';7',9-diepoxy-4,8″;4',8‴-bisoxy-8,8'-dineolignan-7″,7‴,9″,9‴-tetraol, 29, and (threo,erythro)-4″,4‴-dihydroxy-3,3',3″,3‴,5,5'-hexamethoxy-7,9';7',9-diepoxy-4,8″;4',8‴-bisoxy-8,8'-dineolignan-7″,7‴,9″,9‴-tetraol, 30, neither of which have been identified from maple sap or maple syrup before. Twenty of the isolates (selected on the basis of sample quantity available) were evaluated for their potential biological effects against lipopolysaccharide-induced inflammation in BV-2 microglia in vitro and juglone-induced oxidative stress in Caenorhabditis elegans in vivo. The current study increases scientific knowledge of possible bioactive compounds present in maple-derived foods including maple sugar.
Antioxidant activity, inhibition of nitric oxide overproduction, and in vitro antiproliferative effect of maple sap and syrup from Acer saccharum.

PubMed

Legault, Jean; Girard-Lalancette, Karl; Grenon, Carole; Dussault, Catherine; Pichette, André

2010-04-01

Antioxidant activity, inhibition of nitric oxide (NO) overproduction, and antiproliferative effect of ethyl acetate extracts of maple sap and syrup from 30 producers were evaluated in regard to the period of harvest in three different regions of Québec, Canada. Oxygen radical absorbance capacity (ORAC) values of maple sap and syrup extracts are, respectively, 12 +/- 6 and 15 +/- 5 micromol of Trolox equivalents (TE)/mg. The antioxidant activity was also confirmed by a cell-based assay. The period of harvest has no statistically significant incidence on the antioxidant activity of both extracts. The antioxidant activity of pure maple syrup was also determined using the ORAC assay. Results indicate that the ORAC value of pure maple syrup (8 +/- 2 micromol of TE/mL) is lower than the ORAC value of blueberry juice (24 +/- 1 micromol of TE/mL) but comparable to the ORAC values of strawberry (10.7 +/- 0.4 micromol of TE/mL) and orange (10.8 +/- 0.5 micromol of TE/mL) juices. Maple sap and syrup extracts showed to significantly inhibit lipopolysaccharide-induced NO overproduction in RAW264.7 murine macrophages. Maple syrup extract was significantly more active than maple sap extract, suggesting that the transformation of maple sap into syrup increases NO inhibition activity. The highest NO inhibition induced by the maple syrup extracts was observed at the end of the season. Moreover, darker maple syrup was found to be more active than clear maple syrup, suggesting that some colored oxidized compounds could be responsible in part for the activity. Finally, maple syrup extracts (50% inhibitory concentration = 42 +/- 6 microg/mL) and pure maple syrup possess a selective in vitro antiproliferative activity against cancer cells.
Factors associated with rapid mortality of sugar maple in Pennsylvania

Treesearch

Thomas J. Hall; James D. Unger; Thomas C. Bast; Bradley S. Regester

1999-01-01

Mortality of sugar maple and red maple was observed throughout Pennsylvania in 1995 following an outbreak in 1994 by forest tent caterpillar and elm spanworm on sugar maple and red maple, respectively. Symptoms of leaf anthracnose caused by Discula campestris (Pass.) were observed during the refoliation period from July through September 1994: the...
The Maple Products: An Outdoor Education Unit.

ERIC Educational Resources Information Center

Yaple, Charles; And Others

Designed to take advantage of the spring season, this resource packet on maple products centers upon a field lesson in harvesting and making maple syrup. The resources in this packet include: a narrative on the origins of maple sugar; an illustrated description of "old time maple sugarin'"; suggestions for pre-trip activities (history of…
Production of triploid Hydrangea macrophylla via unreduced gamete breeding

USDA-ARS?s Scientific Manuscript database

Hydrangea macrophylla (Thunb.) Ser., florist’s or bigleaf hydrangea, is the most economically important member of the Hydrangea genus, which accounted for 73,000,000 in US nursery sales in 2007. Diploid and triploid cultivars exist and there is some evidence triploidy leads to larger plant and flora...
Growth response of speckled alder and willow to depth of flooding

Treesearch

M. Dean Knighton

1981-01-01

Growth and survival of speckled alder and willow were determined for two growing seasons with continuous flooding at different depths. Growth was at least four times greater when the water table was below the root crown than when it was 15 cm above. Mortality increased with flooding depth and as greatest for alder.
Production and assessment of red alder planting stock.

Treesearch

M.A. Radwan; Y. Tanaka; A. Dobkowskl; W. Fangen

1992-01-01

A series of experiments was conducted over 4 years to test and develop methods to produce acceptable red alder planting stock and to assess quality and outplanting performance of resulting stock. Results indicated that red alder planting stock can be produced as containerized seedlings (plugs) or as bare-root nontransplant and transplant trees. In general, bare-root...
Climate, canker, and alder mortality in the Southern Rockies

Treesearch

James J. Worrall

2012-01-01

An increase in dieback and mortality of thinleaf alder (Alnus incana ssp. tenuifolia) raised concern in southern Wyoming and Colorado two decades ago. In 1990, there was concern over extensive mortality of thinleaf alder along Big Laramie River near Jelm, WY, as well as in multiple locations in Colorado.2 Trees of all ages were...
Character-marked furniture made from red alder harvested in southeast Alaska: product perspectives from consumers and retailers

Treesearch

Matthew Bumgardner; Nicholls David; Valerie Barber

2009-01-01

In recent decades, red alder (Alnus rubra Bong.) has become an important Pacific Northwest hardwood in appearance-grade lumber markets, such as exports, furniture, and cabinets. However, red alder generally is a short-lived pioneer species, and small logs can result in proportionally large volumes of lower grade...
Volume and taper tables for red alder.

Treesearch

Robert O. Curtis; David Bruce; Caryanne VanCoevering

1968-01-01

Red alder is a species of increasing importance in the Pacific Northwest. Interest in improved volume tables for the species resulted in publication of the 1949 volume tables. More recently, Browne (1962) published cubic-foot-volume tables for red alder in British Columbia, and Hoyer (1966) presented tarif access tables, based on the 1949 tables, for use with the...
Stand dynamics of mixed red alder-conifer forests of southeast Alaska.

Treesearch

Robert L. Deal; Paul E. Hennon; Ewa H. Orlikowska; David V. D' Amore

2004-01-01

Stand structure and dynamics were evaluated in mixed red alder (Alnus rubra Bong.) - conifer forests of southeast Alaska. We assessed stand development, tree density, total basal area, diameter distribution of live and dead trees, height distribution of live trees, and mean diameter of all and largest conifers in 40-year-old red alder - conifer...
Red alder kitchen cabinets—How does application of commercial stains influence customer choice?

Treesearch

David Nicholls; Joseph Roos

2007-01-01

A better understanding of consumer reaction and preferences for red alder (Alnus rubra Bong.) secondary products will help Alaska producers in entering new markets. In this study, red alder kitchen cabinets were commercially stained to six different levels and displayed at home shows in Portland, Oregon, and Anchorage, Alaska. The stains simulated...
Volume tables for red alder.

Treesearch

Floyd A. Johnson; R. M. Kallander; Paul G. Lauterbach

1949-01-01

The increasing importance of red alder as a commercial species in the Pacific Northwest has prompted the three agencies listed above to pool their tree measurement data for the construction of standard regional red alder volume tables. The tables included here were based on trees from a variety of sites and form classes. Approximately one quarter of the total number of...
Correlation of maple sap composition with bacterial and fungal communities determined by multiplex automated ribosomal intergenic spacer analysis (MARISA).

PubMed

Filteau, Marie; Lagacé, Luc; LaPointe, Gisèle; Roy, Denis

2011-08-01

During collection, maple sap is contaminated by bacteria and fungi that subsequently colonize the tubing system. The bacterial microbiota has been more characterized than the fungal microbiota, but the impact of both components on maple sap quality remains unclear. This study focused on identifying bacterial and fungal members of maple sap and correlating microbiota composition with maple sap properties. A multiplex automated ribosomal intergenic spacer analysis (MARISA) method was developed to presumptively identify bacterial and fungal members of maple sap samples collected from 19 production sites during the tapping period. Results indicate that the fungal community of maple sap is mainly composed of yeast related to Mrakia sp., Mrakiella sp., Guehomyces pullulans, Cryptococcus victoriae and Williopsis saturnus. Mrakia, Mrakiella and Guehomyces peaks were identified in samples of all production sites and can be considered dominant and stable members of the fungal microbiota of maple sap. A multivariate analysis based on MARISA profiles and maple sap chemical composition data showed correlations between Candida sake, Janthinobacterium lividum, Williopsis sp., Leuconostoc mesenteroides, Mrakia sp., Rhodococcus sp., Pseudomonas tolaasii, G. pullulans and maple sap composition at different flow periods. This study provides new insights on the relationship between microbial community and maple sap quality. Copyright © 2011 Elsevier Ltd. All rights reserved.
Vertebrate Herbivore Browsing on Neighboring Forage Species Increases the Growth and Dominance of Siberian Alder Across a Latitudinal Transect in Northern Alaska.

NASA Astrophysics Data System (ADS)

McNeill, E. M.; Ruess, R. W.

2017-12-01

Vertebrate herbivores strongly influence plant growth and architecture, biogeochemical cycling, and successional dynamics in boreal and arctic ecosystems. One of the most notable impacts of vertebrate herbivory is on the growth and spread of alder, a chemically-defended, N-fixing shrub whose distribution in the Alaskan arctic has expanded dramatically over the past 60 years. Although herbivore effects on thin-leaf alder are well described for interior Alaskan floodplains, no work has been conducted on the effects of herbivores on Siberian alder (Alnus viridis spp fruticosa), despite the increasing importance of this species to high latitude ecosystems. We characterized browsing by snowshoe hares, moose, and willow ptarmigan on dominant shrub species across topo-edaphic sequences within 5 ecoregions along a 600 km latitudinal transect extending from interior Alaska to the North Slope. Ptarmigan browsed wind-blown lowland and alpine sites devoid of trees in all regions; moose browsed predominantly willow species in hardwood and mixed forests and were absent north of the Brooks Range; snowshoe hares selected habitats and forage based on their local density and vulnerability to predators. Browsing intensity on Siberian alder was either undetectable or low, limited primarily to hare browsing on young ramets in the northern boreal forest where hare density relative to forage availability is highest. Overall, alder height growth was positively correlated with levels of herbivory on competing shrub species. Our data support the hypothesis that vertebrate herbivore browsing is indirectly augmenting the growth, dominance, and possible spread of Siberian alder throughout its northern Alaskan range. Given the potential high rates of N-fixation inputs by Siberian alder, we believe herbivores are also having strong indirect effects on biogeochemical cycling and possibly C storage in these landscapes.

The patterns of Corylus and Alnus pollen seasons and pollination periods in two Polish cities located in different climatic regions.

PubMed

Puc, Małgorzata; Kasprzyk, Idalia

2013-01-01

This study compares phenological observations of Corylus (hazel) and Alnus (alder) flowering with airborne pollen counts of these taxa recorded using volumetric spore traps (2009-2011). The work was carried out in the Polish cities of Szczecin and Rzeszów that are located in different climatic regions. Correlations between pollen concentrations and meteorological data were investigated using Spearman's rank correlation analysis. The timings of hazel and alder pollination and the occurrence of airborne pollen varied greatly and were significantly influenced by meteorological conditions ( p < 0.05). The flowering synchronization of hazel and alder pollination in Szczecin and Rzeszów varied over the study period. Hazel and alder trees flowered notably earlier in stands located in places that were exposed to sunlight (insolated) and sheltered from the wind. On the other hand, a delay in the timing of pollination was observed in quite sunny but very windy sites. In Rzeszów, maximum hazel pollen concentrations did not coincide with the period of full pollination (defined as between 25 % hazel and alder and 75 % of flowers open). Conversely, in Szczecin, the highest hazel pollen concentrations were recorded during phenophases of the full pollination period. The period when the highest alder pollen concentrations were recorded varied between sites, with Rzeszów recording the highest concentrations at the beginning of pollination and Szczecin recording alder pollen throughout the full pollination period. Substantial amounts of hazel and alder pollen grains were recorded in the air of Rzeszów (but not Szczecin) before the onset of the respective pollen seasons.
Consumer Preference for Graded Maple Syrup

Treesearch

Paul E. Sendak

1978-01-01

The three grades of maple syrup and a commercial table syrup containing artificial flavor and 3 percent pure maple syrup were evaluated by 1,018 women in four cities. The results indicate that differences in preference for flavor are related to how close the respondents are to a maple syrup-production region. Differences in preference among grades of pure maple syrup...
Height diameter relations of maple street trees

Treesearch

David J. Nowak

1990-01-01

Height and diameter measurements were taken for silver, sugar and Norway maple street trees in Rochester and Syracuse, New York. Mature silver maples proved to be the tallest of the three species. Average sugar maple height was consistently taller than Norway maple height until diameters reached 28 inches. Average mature tree height for all three species level off in...
Morphological measurements and ITS sequences show that the new alder rust in Europe is conspecific with Melampsoridium hiratsukanum in eastern Asia.

PubMed

Hantula, J; Kurkela, T; Hendry, S; Yamaguchi, T

2009-01-01

Three species of Melampsoridium have been reported to infect hosts in genus Alnus. An epidemic of foliar rust affecting A. glutinosa and A. incana began in Europe in the mid-1990s, and the associated pathogen was identified as Melampsoridium hiratsukanum based on morphology. In this investigation we analyzed the morphology and genetic variation of alder rusts from Europe and Japan and the host specificity of the European epidemic rust. Our results showed that two rusts occur on the leaves of alders native to northern Europe; in Scotland an endemic rust indistinguishable from M. betulinum occurs, whereas alders in areas of Europe affected by the current epidemic were infected by M. hiratsukanum. M. hiratsukanum from naturally infected alder in Finland produced aecia on all Larix species tested but did not infect Betula leaves.
Climate Change in the School Yard: Monitoring the Health of Acer Saccharum with A Maple Report Card

NASA Astrophysics Data System (ADS)

Carlson, M.; Diller, A.; Rock, B. N.

2012-12-01

K-12 Teachers and students engage in authentic science and a research partnership with scientists in Maple Watch, a University of New Hampshire outreach program. Maple Watch is a hands-on, inquiry-based program in which students learn about climate change and air quality as well as many other environmental stress factors which may affect the health of sugar maple. The iconic New England tree is slated to lose 52% of its range in this century. Maple Watch builds on the 20-year record of Forest Watch, a K-12 program in which students and teachers have contributed annual research specimens and data to a UNH study of tropospheric ozone and its impact on white pine (Pinus strobus). Maple Watch students monitor sugar maples (Acer saccharum) year-round for signals of strain and disease. Students report the first run in sap season, bud burst and leaf development, and leaf senescence and fall. Across New England the timing of these phenologic events is changing with climate warming. Students assess maple health with simple measures of leaf development in May, leaf senescence in early fall and bud quality in late fall. Simple student arithmetic rankings of leaf and bud health correlate with chlorophyll content and spectral reflectance measures that students can analyze and compare with researchers at UNH. Grading their trees for each test on a one-two-three scale, students develop a Maple Report Card for each type of measurement, which presents an annual portrait of tree health. Year-by-year, schools across the sugar maple's 31 million acre range could monitor changes in tree health. The change over time in maple health can be graphed in parallel with the Goddard Space Institute's Common Sense Climate Index. Four teachers, listed as co-authors here, began a pilot study with Maple Watch in 2010, contributing sap samples and sharing curricular activities with UNH. Pilot Maple Watch schools already manage stands of sugar maples and make maple syrup and are assisting in training new schools in Maple Watch protocols. The program also includes assessment of educational philosophy as we consider how to discuss climate change with K-12 students. Maple Watch teachers are learning how to discuss the death of a tree, extirpation of a species, and human connections with nature.
Factors affecting distribution of wood, detritus, and sediment in headwater streams draining managed young-growth red alder-conifer forests in southeast Alaska

Treesearch

Takashi Gomi; Adelaide C. Johnson; Robert L. Deal; Paul E. Hennon; Ewa H. Orlikowska; Mark S. Wipfli

2006-01-01

Factors (riparian stand condition, management regimes, and channel properties) affecting distributions of wood, detritus (leaves and branches), and sediment were examined in headwater streams draining young-growth red alder (Alnus rubra Bong.)-conifer riparian forests (40 years old) in southeast Alaska. More riparian red alder were found along...
Character-marked furniture made from red alder harvested in southeast Alaska: product perspectives from consumers and retailers

Treesearch

Matthew Bumgardner; David Nicholls; Valerie Barber

2009-01-01

In recent decades. red alder (Alnus rubra Bong.) has become an important Pacific Northwest hardwood in appearance-grade lumber markets, such as exports, furniture, and cabinets. However, red alder generally is a short-lived pioneer species, and small logs can result in proportionally large volumes of lower grade lumber containing numerous visual...
Growth and development of red alder compared with conifers in 30-year-old stands.

Treesearch

Carl M. Berntsen

1961-01-01

Red alder (Alnus rubra), although a widespread tree species in Pacific coast forests, has only in recent years attained commercial importance as a source of wood material for diversified products including furniture, paneling, and paper pulp. With the rapid increase in the harvest of red alder, both public agencies and private industry are making a...
An evaluation of the grades and value of red alder lumber in southeast Alaska

Treesearch

Allen M. Brackley; David Nicholls; Michael Hannan

2009-01-01

Many stands in southeast Alaska harvested since 1950, especially where there has been a high degree of disturbance of mineral soil, have regenerated to red alder (Alnus rubra Bong.) and are now approaching maturity. The availability of red alder raises questions addressed in this study about the recovery of lumber from this resource. Information in...
Computational design of an enzyme catalyst for a stereoselective bimolecular Diels-Alder reaction

PubMed Central

Siegel, Justin B.; Zanghellini, Alexandre; Lovick, Helena M.; Kiss, Gert; Lambert, Abigail R.; St.Clair, Jennifer L.; Gallaher, Jasmine L.; Hilvert, Donald; Gelb, Michael H.; Stoddard, Barry L.; Houk, Kendall N.; Michael, Forrest E.; Baker, David

2011-01-01

The Diels-Alder reaction is a cornerstone in organic synthesis, forming two carbon-carbon bonds and up to four new stereogenic centers in one step. No naturally occurring enzymes have been shown to catalyze bimolecular Diels-Alder reactions. We describe the de novo computational design and experimental characterization of enzymes catalyzing a bimolecular Diels-Alder reaction with high stereoselectivity and substrate specificity. X-ray crystallography confirms that the structure matches the design for the most active of the enzymes, and binding site substitutions reprogram the substrate specificity. Designed stereoselective catalysts for carbon-carbon bond forming reactions should be broadly useful in synthetic chemistry. PMID:20647463
Computational design of an enzyme catalyst for a stereoselective bimolecular Diels-Alder reaction.

PubMed

Siegel, Justin B; Zanghellini, Alexandre; Lovick, Helena M; Kiss, Gert; Lambert, Abigail R; St Clair, Jennifer L; Gallaher, Jasmine L; Hilvert, Donald; Gelb, Michael H; Stoddard, Barry L; Houk, Kendall N; Michael, Forrest E; Baker, David

2010-07-16

The Diels-Alder reaction is a cornerstone in organic synthesis, forming two carbon-carbon bonds and up to four new stereogenic centers in one step. No naturally occurring enzymes have been shown to catalyze bimolecular Diels-Alder reactions. We describe the de novo computational design and experimental characterization of enzymes catalyzing a bimolecular Diels-Alder reaction with high stereoselectivity and substrate specificity. X-ray crystallography confirms that the structure matches the design for the most active of the enzymes, and binding site substitutions reprogram the substrate specificity. Designed stereoselective catalysts for carbon-carbon bond-forming reactions should be broadly useful in synthetic chemistry.
Inhibitory effect of maple syrup on the cell growth and invasion of human colorectal cancer cells.

PubMed

Yamamoto, Tetsushi; Uemura, Kentaro; Moriyama, Kaho; Mitamura, Kuniko; Taga, Atsushi

2015-04-01

Maple syrup is a natural sweetener consumed by individuals of all ages throughout the world. Maple syrup contains not only carbohydrates such as sucrose but also various components such as organic acids, amino acids, vitamins and phenolic compounds. Recent studies have shown that these phenolic compounds in maple syrup may possess various activities such as decreasing the blood glucose level and an anticancer effect. In this study, we examined the effect of three types of maple syrup, classified by color, on the cell proliferation, migration and invasion of colorectal cancer (CRC) cells in order to investigate whether the maple syrup is suitable as a phytomedicine for cancer treatment. CRC cells that were administered maple syrup showed significantly lower growth rates than cells that were administered sucrose. In addition, administration of maple syrup to CRC cells caused inhibition of cell invasion, while there was no effect on cell migration. Administration of maple syrup clearly inhibited AKT phosphorylation, while there was no effect on ERK phosphorylation. These data suggest that maple syrup might inhibit cell proliferation and invasion through suppression of AKT activation and be suitable as a phytomedicine for CRC treatment, with fewer adverse effects than traditional chemotherapy.
Inhibitory effect of maple syrup on the cell growth and invasion of human colorectal cancer cells

PubMed Central

YAMAMOTO, TETSUSHI; UEMURA, KENTARO; MORIYAMA, KAHO; MITAMURA, KUNIKO; TAGA, ATSUSHI

2015-01-01

Maple syrup is a natural sweetener consumed by individuals of all ages throughout the world. Maple syrup contains not only carbohydrates such as sucrose but also various components such as organic acids, amino acids, vitamins and phenolic compounds. Recent studies have shown that these phenolic compounds in maple syrup may possess various activities such as decreasing the blood glucose level and an anticancer effect. In this study, we examined the effect of three types of maple syrup, classified by color, on the cell proliferation, migration and invasion of colorectal cancer (CRC) cells in order to investigate whether the maple syrup is suitable as a phytomedicine for cancer treatment. CRC cells that were administered maple syrup showed significantly lower growth rates than cells that were administered sucrose. In addition, administration of maple syrup to CRC cells caused inhibition of cell invasion, while there was no effect on cell migration. Administration of maple syrup clearly inhibited AKT phosphorylation, while there was no effect on ERK phosphorylation. These data suggest that maple syrup might inhibit cell proliferation and invasion through suppression of AKT activation and be suitable as a phytomedicine for CRC treatment, with fewer adverse effects than traditional chemotherapy. PMID:25647359
Headwater riparian invertebrate communities associated with red alder and conifer wood and leaf litter in southeastern Alaska

USGS Publications Warehouse

LeSage, C.M.; Merritt, R.W.; Wipfli, M.S.

2005-01-01

We examined how management of young upland forests in southeastern Alaska affect riparian invertebrate taxa richness, density, and biomass, in turn, potentially influencing food abundance for fish and wildlife. Southeastern Alaska forests are dominated by coniferous trees including Sitka spruce (Picea sitchensis (Bong.) Carr.), western hemlock (Tsuga heterophylla (Raf.) Sarg.), with mixed stands of red cedar (Thuja plicata Donn.). Red alder (Alnus rubra Bong.) is hypothesized to influence the productivity of young-growth conifer forests and through forest management may provide increased riparian invertebrate abundance. To compare and contrast invertebrate densities between coniferous and alder riparian habitats, leaf litter and wood debris (early and late decay classes) samples were collected along eleven headwater streams on Prince of Wales Island, Alaska, during the summers of 2000 and 2001. Members of Acarina and Collembola were the most abundant taxa collected in leaf litter with alder litter having significantly higher mean taxa richness than conifer litter. Members of Acarina were the most abundant group collected on wood debris and alder wood had significantly higher mean taxa richness and biomass than conifer wood. Alder wood debris in more advanced decay stages had the highest mean taxa richness and biomass, compared to other wood types, while conifer late decay wood debris had the highest densities of invertebrates. The inclusion of alder in young-growth conifer forests can benefit forest ecosystems by enhancing taxa richness and biomass of riparian forest invertebrates. ?? 2005 by the Northwest Scientific Association. All rights reserved.
The Chemical Composition of Maple Syrup

ERIC Educational Resources Information Center

Ball, David W.

2007-01-01

Maple syrup is one of several high-sugar liquids that humans consume. However, maple syrup is more than just a concentrated sugar solution. Here, we review the chemical composition of maple syrup. (Contains 4 tables and 1 figure.)
Genetic Selection for Improved Abzymes in E. Coli

DTIC Science & Technology

1994-08-03

immunoassay to scemen antibody phage libraries directly for catalysis of a bimolecular Diels - Alder reaction and have identified several active clones...sensitive growth selection assay in F coli for catalysts with chorismate mutase activity; and (3) we identified new abzymes for a Diels - Alder ...generated combinatorial antibody libraries from mRNA isolated from the spleens of mice hyperimmunized with transition state analogs for Diels - Alder and
Growth and Survival of Hardwoods and Pine Interplanted with European Alder

Treesearch

William T. Plass

1977-01-01

European black alder is recommended for planting on many surface mine spoils in the eastern United States. It grows rapidly on a range of spoil types and contributes to soil enrichment by fixing nitrogen and providing a leaf fall rich in nutrients. This study evaluated the effect of alder on the survival and growth of five hardwood and five pine species. After 10...
Comparison of Five Woody Species for Reclamation of an Upper Coastal Plain Spoil Bank

Treesearch

J.W. McMinn; R.R. Roth; C.R. Berry; W.H. McNab

1980-01-01

Third-year survival and height are compared for autumn olive. European black alder, flowering crab apple, sawtooth oak, and Virginia pine on a sandy clay loam spoil bank in South Carolina. Flowering crab apple and sawtooth oak exhibited the best survival, while autumn olive and European black alder had greater height growth. Only European black alder failed to become...
Acid-base status of upper rooting zone soil in declining and non-declining sugar maple (Acer saccharum Marsh) stands in Pennsylvania

Treesearch

William E. Sharpe; Troy L. Sunderland

1995-01-01

Sugar maple (Acer saccharum Marsh) is an important commercial tree species of the central hardwood region which is valued for its wood and maple sugar products. High elevation sugar maple stands in northcentral Pennsylvania have been in serious decline for about the last 15 years with more than 1,200 hectares of maple forest affected. The decline...
Diversity-Oriented Approaches to Polycyclics and Bioinspired Molecules via the Diels-Alder Strategy: Green Chemistry, Synthetic Economy, and Beyond.

PubMed

Kotha, Sambasivarao; Chavan, Arjun S; Goyal, Deepti

2015-05-11

We describe diverse approaches to various dienes and their utilization in the Diels-Alder reaction to produce a variety of polycycles. The dienes covered here are prepared by simple alkylation reaction or via the Claisen rearrangement or by enyne metathesis of alkyne or enyne building blocks. Here, we have also included the Diels-Alder chemistry of dendralenes, a higher analog of cross-conjugated dienes. The present article is inclusive of o-xylylene derivatives that are generated in situ starting with benzosultine or benzosulfone derivatives. The Diels-Alder reaction of these dienes with various dienophiles gave diverse polycyclic systems and biologically important targets.

Norway maple displays greater seasonal growth and phenotypic plasticity to light than native sugar maple.

PubMed

Paquette, Alain; Fontaine, Bastien; Berninger, Frank; Dubois, Karine; Lechowicz, Martin J; Messier, Christian; Posada, Juan M; Valladares, Fernando; Brisson, Jacques

2012-11-01

Norway maple (Acer platanoides L), which is among the most invasive tree species in forests of eastern North America, is associated with reduced regeneration of the related native species, sugar maple (Acer saccharum Marsh) and other native flora. To identify traits conferring an advantage to Norway maple, we grew both species through an entire growing season under simulated light regimes mimicking a closed forest understorey vs. a canopy disturbance (gap). Dynamic shade-houses providing a succession of high-intensity direct-light events between longer periods of low, diffuse light were used to simulate the light regimes. We assessed seedling height growth three times in the season, as well as stem diameter, maximum photosynthetic capacity, biomass allocation above- and below-ground, seasonal phenology and phenotypic plasticity. Given the north European provenance of Norway maple, we also investigated the possibility that its growth in North America might be increased by delayed fall senescence. We found that Norway maple had significantly greater photosynthetic capacity in both light regimes and grew larger in stem diameter than sugar maple. The differences in below- and above-ground biomass, stem diameter, height and maximum photosynthesis were especially important in the simulated gap where Norway maple continued extension growth during the late fall. In the gap regime sugar maple had a significantly higher root : shoot ratio that could confer an advantage in the deepest shade of closed understorey and under water stress or browsing pressure. Norway maple is especially invasive following canopy disturbance where the opposite (low root : shoot ratio) could confer a competitive advantage. Considering the effects of global change in extending the potential growing season, we anticipate that the invasiveness of Norway maple will increase in the future.
Chapter 1:Red and silver maples : resource availability, utilization, and costs

Treesearch

Henry Spelter

2005-01-01

Red maple (Acer rubrum) is a medium-sized tree 15 to 20 meters (50 to 65 feet) high and 30 to 60 centimeters (12 to 24 inches) in diameter with a generally fairly clear trunk. This species and silver maple (Acer saccharinum) are often called âsoft maplesâ to distinguish them from the higher density sugar and black maples that are commonly referred to...
The Importance of Tree Size and Fecundity for Wind Dispersal of Big-Leaf Mahogany

PubMed Central

Norghauer, Julian M.; Nock, Charles A.; Grogan, James

2011-01-01

Seed dispersal by wind is a critical yet poorly understood process in tropical forest trees. How tree size and fecundity affect this process at the population level remains largely unknown because of insufficient replication across adults. We measured seed dispersal by the endangered neotropical timber species big-leaf mahogany (Swietenia macrophylla King, Meliaceae) in the Brazilian Amazon at 25 relatively isolated trees using multiple 1-m wide belt transects extended 100 m downwind. Tree diameter and fecundity correlated positively with increased seed shadow extent; but in combination large, high fecundity trees contributed disproportionately to longer-distance dispersal events (>60 m). Among three empirical models fitted to seed density vs. distance in one dimension, the Student-t (2Dt) generally fit best (compared to the negative exponential and inverse power). When seedfall downwind was modelled in two dimensions using a normalised sample, it peaked furthest downwind (c. 25 m) for large, high-fecundity trees; with the inverse Gaussian and Weibull functions providing comparable fits that were slightly better than the lognormal. Although most seeds fell within 30 m of parent trees, relatively few juveniles were found within this distance, resulting in juvenile-to-seed ratios peaking at c. 35–45 m. Using the 2Dt model fits to predict seed densities downwind, coupled with known fecundity data for 2000–2009, we evaluated potential Swietenia regeneration near adults (≤30 m dispersal) and beyond 30 m. Mean seed arrival into canopy gaps >30 m downwind was more than 3× greater for large, high fecundity trees than small, high-fecundity trees. Tree seed production did not necessarily scale up proportionately with diameter, and was not consistent across years, and this resulting intraspecific variation can have important consequences for local patterns of dispersal in forests. Our results have important implications for management and conservation of big-leaf mahogany populations, and may apply to other threatened wind-dispersed Meliaceae trees. PMID:21408184
Early survival and growth of planted Douglas-fir with red alder in four mixed regimes.

Treesearch

Marshall D. Murray; Richard E. Miller

1986-01-01

To quantify between-species interactions, we measured and compared survival and growth of planted Douglas-fir and associated planted and volunteer red alder at a location on the west side of the Cascade Range in Washington. The planted alder were wildlings dug either from a nearby area or from a distant, coastal site and interplanted into a 3-year-old Douglas-fir...
Comparison of terrestrial invertebrate biomass and richness in young mixed red alder-conifer, young conifer, and old conifer stands of southeast Alaska.

Treesearch

Mark E. Schultz; Toni L. De Santo

2008-01-01

Coniferous stands that regenerate following clearcutting in southeast Alaska can be characterized by the amount of soil disturbance during logging. There are indications that red alder in mixed stands mitigates some of the negative effects of clearcutting. We compared invertebrate biomass in four stands each of (1) young conifers, (2) young mixed alder and conifer, and...
A preliminary study of the deterioration of alder and Douglas-fir chips in outdoor piles.

Treesearch

Ernest. Wright

1954-01-01

In the fall of 1952, E. E. Matson of the Pacific Northwest Forest and Range Experiment Station learned that the Fir-Tex Insulating Board Company bf St. Helens, Oregon was considering mixing alder with Douglas-fir chips for outside storage. Since alder heartwood i s more susceptible to decay than that of Douglas-fir, the question arose whether mixing the two might...
Can We Use Tree Rings of Black Alder to Reconstruct Lake Levels? A Case Study for the Mecklenburg Lake District, Northeastern Germany

PubMed Central

van der Maaten, Ernst; van der Maaten-Theunissen, Marieke; Buras, Allan; Scharnweber, Tobias; Simard, Sonia; Kaiser, Knut; Lorenz, Sebastian; Wilmking, Martin

2015-01-01

In this study, we explore the potential to reconstruct lake-level (and groundwater) fluctuations from tree-ring chronologies of black alder (Alnus glutinosa L.) for three study lakes in the Mecklenburg Lake District, northeastern Germany. As gauging records for lakes in this region are generally short, long-term reconstructions of lake-level fluctuations could provide valuable information on past hydrological conditions, which, in turn, are useful to assess dynamics of climate and landscape evolution. We selected black alder as our study species as alder typically thrives as riparian vegetation along lakeshores. For the study lakes, we tested whether a regional signal in lake-level fluctuations and in the growth of alder exists that could be used for long-term regional hydrological reconstructions, but found that local (i.e. site-specific) signals in lake level and tree-ring chronologies prevailed. Hence, we built lake/groundwater-level reconstruction models for the three study lakes individually. Two sets of models were considered based on (1) local tree-ring series of black alder, and (2) site-specific Standardized Precipitation Evapotranspiration Indices (SPEI). Although the SPEI-based models performed statistically well, we critically reflect on the reliability of these reconstructions, as SPEI cannot account for human influence. Tree-ring based reconstruction models, on the other hand, performed poor. Combined, our results suggest that, for our study area, long-term regional reconstructions of lake-level fluctuations that consider both recent and ancient (e.g., archaeological) wood of black alder seem extremely challenging, if not impossible. PMID:26317768
Bacillus amyloliquefaciens levansucrase-catalyzed the synthesis of fructooligosaccharides, oligolevan and levan in maple syrup-based reaction systems.

PubMed

Li, Mengxi; Seo, Sooyoun; Karboune, Salwa

2015-11-20

Maple syrups with selected degree Brix (°Bx) (15, 30, 60) were investigated as reaction systems for levansucrase from Bacillus amyloliquefaciens. The enzymatic conversion of sucrose present in the maple syrup and the production of the transfructosylation products were assessed over a time course of 48h. At 30°C, the use of maple syrup 30°Bx led to the highest levansucrase activity (427.53μmol/mg protein/min), while maple syrup 66°Bx led to the highest converted sucrose concentration (1.53M). In maple syrup 30°Bx, oligolevans (1080%). In maple syrup 66°Bx, the most abundant products were oligolevans at 30°C and levans (DP≥30) at 8°C. The acceptor specificity study revealed the ability of B. amyloliquefaciens levansucrase to synthesize a variety of hetero-fructooligosaccharides (FOSs) in maple syrups 15°Bx and 30°Bx enriched with various disaccharides, with lactose being the preferred fructosyl acceptor. The current study is the first to investigate maple-syrup-based reaction systems for the synthesis of FOSs/oligolevans/levans. Copyright © 2015 Elsevier Ltd. All rights reserved.
Ultra-fast liquid chromatography coupled with electrospray ionization time-of-flight mass spectrometry for the rapid phenolic profiling of red maple (Acer rubrum) leaves.

PubMed

Li, Chunting; Seeram, Navindra P

2018-03-07

The red maple (Acer rubrum) species is economically important to North America because of its sap, which is used to produce maple syrup. In addition, various other red maple plant parts, including leaves, were used as a traditional medicine by the Native Americans. Currently, red maple leaves are being used for nutraceutical and cosmetic applications but there are no published analytical methods for comprehensive phytochemical characterization of this material. Herein, a rapid and sensitive method using liquid chromatography with electrospray ionization time-of-flight tandem mass spectrometry was developed to characterize the phenolics in a methanol extract of red maple leaves and a proprietary phenolic-enriched red maple leaves extract (Maplifa™). Time-of-flight mass spectrometry and tandem mass spectrometry experiments led to the identification of 106 phenolic compounds in red maples leaves with the vast majority of these compounds also detected in Maplifa™. The compounds included 68 gallotannins, 25 flavonoids, gallic acid, quinic acid, catechin, epicatechin, and nine other gallic acid derivatives among which 11 are potentially new and 75 are being reported from red maple for the first time. The developed method to characterize red maple leaves phenolics is rapid and highly sensitive and could aid in future standardization and quality control of this botanical ingredient. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Comparative effects of urea fertilizer and red alder in a site III, coast Douglas-fir plantation in the Washington Cascade Range.

Treesearch

Richard E. Miller; Harry W. Anderson; Marshall Murray; Rick. Leon

2005-01-01

Five randomly assigned treatments were used to quantify effects of adding varying numbers of red alder (Alnus rubra Bong.) or nitrogen (N) fertilization on growth of a 10-year-old conifer plantation at a medium quality site in the western Washington Cascade Range. Zero, 20, 40, and 80 alder trees per acre were retained along with about 300 conifers...
Fe(II)/Fe(III)-Catalyzed Intramolecular Didehydro-Diels-Alder Reaction of Styrene-ynes.

PubMed

Mun, Hyeon Jin; Seong, Eun Young; Ahn, Kwang-Hyun; Kang, Eun Joo

2018-02-02

The intramolecular didehydro-Diels-Alder reaction of styrene-ynes was catalyzed by Fe(II) and Fe(III) to produce various naphthalene derivatives under microwave heating conditions. Mechanistic calculations found that the Fe(II) catalyst activates the styrenyl diene in an inverse-electron-demand Diels-Alder reaction, and the consecutive dehydrogenation reaction can be promoted by either Fe(II)-catalyzed direct dehydrogenation or an Fe(III)-catalyzed rearomatization/dehydrogenation pathway.
Enhancing the Scope of the Diels-Alder Reaction through Isonitrile Chemistry: Emergence of a New Class of Acyl-Activated Dienophiles

PubMed Central

Townsend, Steven D.; Wu, Xiangyang; Danishefsky, Samuel J.

2012-01-01

α,β-Unsaturated imides, formylated at the nitrogen atom, comprise a new and valuable family of dienophiles for servicing Diels-Alder reactions. These systems are assembled through extension of recently discovered isonitrile chemistry to the domain of α,β-unsaturated acids. Cycloadditions are facilitated by Et2AlCl, presumably via chelation between the two carbonyl groups of the N-formyl amide. Applications of the isonitrile/Diels-Alder logic to the IMDA reaction, as well as methodologies to modify the N-formyl amide of the resultant cycloaddition product, are described. It is expected that this easily executed chemistry will provide a significant enhancement for application of Diels-Alder reactions to many synthetic targets. PMID:22708980
Theoretical study of the Diels-Alder reaction between o-benzoquinone and norbornadiene

NASA Astrophysics Data System (ADS)

Quijano-Quiñones, Ramiro F.; Quesadas-Rojas, M.; Cuevas, Gabriel; Mena-Rejón, Gonzalo J.

2013-06-01

The reaction between norbornadiene and o-benzoquinone is an important step in polyalicyclic rigid structures synthesis. It has been considered that this reaction is an example of Diels-Alder (DA) and hetero-Diels-Alder (HDA) cycloadditions with o-benzoquinone acting as diene (forming C-C bonds) and heterodiene (forming O-C bonds). We have performed a Density Functional Theory study of this reaction, employing B3LYP, mPW1PW91, and B1B95 functionals and 6-31G(d,p) and 6-31+G(d,p) Gaussian type basis sets. The results indicate that Diels-Alder is a feasible mechanism for both reactions, but should not be the main route to the formation of products with C-C bonds.
Detection of Inulin, a Prebiotic Polysaccharide, in Maple Syrup.

PubMed

Sun, Jiadong; Ma, Hang; Seeram, Navindra P; Rowley, David C

2016-09-28

Maple syrup is a widely consumed plant-derived natural sweetener produced by concentrating xylem sap collected from certain maple (Acer) species. During thermal evaporation of water, natural phytochemical components are concentrated in maple syrup. The polymeric components from maple syrup were isolated by ethanol precipitation, dialysis, and anion exchange chromatography and structurally characterized by glycosyl composition analysis, glycosyl linkage analysis, and nuclear magnetic resonance spectroscopy. Among the maple syrup polysaccharides, one neutral polysaccharide was characterized as inulin with a broad molecular weight distribution, representing the first isolation of this prebiotic carbohydrate from a xylem sap. In addition, two acidic polysaccharides with structural similarity were identified as arabinogalactans derived from rhamnogalacturonan type I pectic polysaccharides.
Summary of bird-survey and banding results at W.L. Finley National Wildlife Refuge, 1998-2008

USGS Publications Warehouse

Hagar, Joan

2012-01-01

With some of the best remaining examples of oak habitats in the Willamette Valley, the Willamette Valley National Wildlife Refuge Complex (WVNWRC) has been implementing restoration efforts to reverse the successional trend towards Douglas-fir and maple that is threatening existing oak woodlands. The restoration work has been considered a model for other public and private efforts within the Willamette Valley, and has been showcased through the Oregon Oak Communities Working Group (http://www.oregonoaks.org). Although many oak restoration projects have been initiated over the last several years, and grant recipients typically identify wildlife species that are likely to benefit from their project, measures of success have not included the actual response of wildlife, such as a change in the probability of species occurrence or abundance. Monitoring in the WVNWRC has so far been limited to vegetative and structural changes within the plant community. Hagar and Stern (2001) identified bird species occurring in Willamette Valley oak woodlands that might be expected to benefit from such restoration efforts, including an endemic subspecies of the White-breasted Nuthatch (see Appendix 1 for scientific names of bird and plant species listed in this document), and the Acorn Woodpecker, both of which are species of concern in Oregon. However, empirical data documenting responses of bird assemblages to restoration actions are needed. The goal of this study was to document the effects of a restoration project in an Oregon White Oak woodland on Pigeon Butte in the W.L. Finley National Wildlife Refuge. Restoration treatments on Pigeon Butte include the removal of shade-tolerant tree species (primarily big-leaf maple and Douglas-fir) to reduce competition with oak trees and to return the stand to a more open structure. The objectives of this ongoing study are to compare abundance, survival, and productivity of diurnal songbird species before and after application of these restoration treatments. Monitoring these vital rates will provide crucial information about the effects of management on survival and productivity (DeSante and Rosenberg, 1998). Therefore, a constant-effort mist-netting project was continued in 2007 and 2008 that had previously collected songbird demographic data at Pigeon Butte from 1998 to 2002. Point-count surveys were conducted in the woodland to build on historical data available for the site (Anderson, 1970; Hagar and Stern, 2001). The data reported here represent 5 years of point count surveys and 6 years of banding before restoration treatment, but only one post-treatment sampling season. Continued monitoring of the bird population is recommended to determine both short-term effects and long-term trends following the habitat alterations that result from restoration treatment.
A requirement for sucrose in xylem sap flow from dormant maple trees.

PubMed

Johnson, R W; Tyree, M T; Dixon, M A

1987-06-01

The response of excised stem segments of several tree species to freezing and thawing cycles was studied. All species studied (Thuja occidentalis, Fagus grandifolia, and Betula papyrifera) except maple (Acer spp.) exuded sap while freezing and absorbed on thawing. Maple stems absorbed sap while freezing and exuded sap during the thaw only when sucrose was present in the vessel solution. Increased concentration of sucrose in the vessel sap led to increased exudation. In the absence of sucrose, maple stems absorbed sap on thawing. The presence of sucrose enhanced sap absorption during freezing cycles in maples. In general, large sugars, disaccharides and larger, could substitute for sucrose in the maple exudation response while sugar hexoses could not. The results are discussed in relation to the O'Malley-Milburn model (1983 Can J Bot 61: 3100-3106) of sap flow in maples.
A Requirement for Sucrose in Xylem Sap Flow from Dormant Maple Trees 1

PubMed Central

Johnson, Robert W.; Tyree, Melvin T.; Dixon, Michael A.

1987-01-01

The response of excised stem segments of several tree species to freezing and thawing cycles was studied. All species studied (Thuja occidentalis, Fagus grandifolia, and Betula papyrifera) except maple (Acer spp.) exuded sap while freezing and absorbed on thawing. Maple stems absorbed sap while freezing and exuded sap during the thaw only when sucrose was present in the vessel solution. Increased concentration of sucrose in the vessel sap led to increased exudation. In the absence of sucrose, maple stems absorbed sap on thawing. The presence of sucrose enhanced sap absorption during freezing cycles in maples. In general, large sugars, disaccharides and larger, could substitute for sucrose in the maple exudation response while sugar hexoses could not. The results are discussed in relation to the O'Malley-Milburn model (1983 Can J Bot 61: 3100-3106) of sap flow in maples. Images Fig. 2 PMID:16665468
Drought tolerance of sugar maple ecotypes

Treesearch

Richard J. Hauer; Jeffery O. Dawson

1995-01-01

Sugar maple declines periodically occur in rural and urban areas. These declines usually follow periods of below-average precipitation leading to the speculation that moisture deficiency is a primary cause of the decline. Sugar maple ecotypes with greater tolerance to drought should have greater longevity and vitality as a result of this tolerance. Sugar maple and...
Tapping the Sugar Maple--Learning and Appreciating

ERIC Educational Resources Information Center

Malone, Charles

1976-01-01

The article discusses how to tap a maple tree. Tapping a maple tree to produce maple syrup can: (1) lead to better understanding in many subject areas, (2) develop skills through participation in a rewarding activity, and (3) help students appreciate the many important roles that trees play in our environment and daily lives. (NQ)
Effects of air injection during sap processing on maple syrup color, chemical composition and flavor volatiles.

USDA-ARS?s Scientific Manuscript database

Air injection (AI) is a maple sap processing technology reported to increase the efficiency of maple syrup production by increasing production of more economically valuable light-colored maple syrup, and reducing development of loose scale mineral precipitates in syrup, and scale deposits on evapora...

Effects of Nitrogen Fertilization on Potato Leafhopper (Hemiptera: Cicadellidae) and Maple Spider Mite (Acari: Tetranychidae) on Nursery-Grown Maples.

PubMed

Prado, Julia; Quesada, Carlos; Gosney, Michael; Mickelbart, Michael V; Sadof, Clifford

2015-06-01

Although leaf nitrogen (N) has been shown to increase the suitability of hosts to herbivorous arthropods, the responses of these pests to N fertilization on susceptible and resistant host plants are not well characterized. This study determined how different rates of N fertilization affected injury caused by the potato leafhopper (Empoasca fabae Harris) and the abundance of maple spider mite (Oligonychus aceris (Shimer)) on 'Red Sunset' red maple (Acer rubrum) and 'Autumn Blaze' Freeman maple (Acer×freemanii) during two years in Indiana. N fertilization increased leaf N concentration in both maple cultivars, albeit to a lesser extent during the second year of the study. Overall, Red Sunset maples were more susceptible to E. fabae injury than Autumn Blaze, whereas Autumn Blaze maples supported higher populations of O. aceris. Differences in populations of O. aceris were attributed to differences between communities of stigmaeid and phytoseiid mites on each cultivar. Injury caused by E. fabae increased with N fertilization in a dose-dependent manner in both cultivars. Although N fertilization increased the abundance of O. aceris on both maple cultivars, there was no difference between the 20 and 40 g rates. We suggest the capacity of N fertilization to increase O. aceris on maples could be limited at higher trophic levels by the community of predatory mites. © The Authors 2015. Published by Oxford University Press on behalf of Entomological Society of America. All rights reserved. For Permissions, please email: journals.permissions@oup.com.
Red maple (Acer rubrum) leaf toxicosis in horses: a retrospective study of 32 cases.

PubMed

Alward, Ashley; Corriher, Candice A; Barton, Michelle H; Sellon, Debra C; Blikslager, Anthony T; Jones, Samuel L

2006-01-01

Ingestion of wilted red maple leaves by horses can result in severe hemolytic anemia and methemoglobinemia. Little is known about what factors influence the outcome of red maple leaf toxicosis in horses. Our hypothesis was that physical examination findings, clinicopathologic variables or therapeutic modalities may predict outcome in horses with red maple leaf toxicity. Horses with red maple leaf toxicosis presented to referral hospitals in the southeast region of the United States. A multi-institutional retrospective study was designed to identify factors that predict mortality in horses with red maple toxicosis. Thirty-two horses with red maple toxicosis were identified, 19 of which died. Twenty-nine horses presented with anemia and 24 had clinicopathologic evidence of systemic inflammation. Renal insufficiency was identified in 12/30 (41%) horses. Laminitis (9/28) and colic (13/30) also were identified in horses with red maple toxicosis, but development of these 2 conditions did not have a negative effect on short-term survival. Horses with red maple toxicosis that survived to discharge were likely to have developed pyrexia during hospitalization (P = .030). Horses that were treated with a corticosteroid had a significantly increased likelihood of death (P = .045). There was no significant relationship between initial serum hemoglobin concentration, methemoglobin concentration, or percentage methemoglobin and mortality in this horse series. This study suggests that information obtained on initial examination cannot be used to accurately predict survival in horses with red maple toxicosis, but horses that receive corticosteroids are unlikely to survive.
Interspecific Plant Interactions Reflected in Soil Bacterial Community Structure and Nitrogen Cycling in Primary Succession.

PubMed

Knelman, Joseph E; Graham, Emily B; Prevéy, Janet S; Robeson, Michael S; Kelly, Patrick; Hood, Eran; Schmidt, Steve K

2018-01-01

Past research demonstrating the importance plant-microbe interactions as drivers of ecosystem succession has focused on how plants condition soil microbial communities, impacting subsequent plant performance and plant community assembly. These studies, however, largely treat microbial communities as a black box. In this study, we sought to examine how emblematic shifts from early successional Alnus viridus ssp. sinuata (Sitka alder) to late successional Picea sitchensis (Sitka spruce) in primary succession may be reflected in specific belowground changes in bacterial community structure and nitrogen cycling related to the interaction of these two plants. We examined early successional alder-conditioned soils in a glacial forefield to delineate how alders alter the soil microbial community with increasing dominance. Further, we assessed the impact of late-successional spruce plants on these early successional alder-conditioned microbiomes and related nitrogen cycling through a leachate addition microcosm experiment. We show how increasingly abundant alder select for particular bacterial taxa. Additionally, we found that spruce leachate significantly alters the composition of these microbial communities in large part by driving declines in taxa that are enriched by alder, including bacterial symbionts. We found these effects to be spruce specific, beyond a general leachate effect. Our work also demonstrates a unique influence of spruce on ammonium availability. Such insights bolster theory relating the importance of plant-microbe interactions with late-successional plants and interspecific plant interactions more generally.
Interspecific Plant Interactions Reflected in Soil Bacterial Community Structure and Nitrogen Cycling in Primary Succession

PubMed Central

Knelman, Joseph E.; Graham, Emily B.; Prevéy, Janet S.; Robeson, Michael S.; Kelly, Patrick; Hood, Eran; Schmidt, Steve K.

2018-01-01

Past research demonstrating the importance plant–microbe interactions as drivers of ecosystem succession has focused on how plants condition soil microbial communities, impacting subsequent plant performance and plant community assembly. These studies, however, largely treat microbial communities as a black box. In this study, we sought to examine how emblematic shifts from early successional Alnus viridus ssp. sinuata (Sitka alder) to late successional Picea sitchensis (Sitka spruce) in primary succession may be reflected in specific belowground changes in bacterial community structure and nitrogen cycling related to the interaction of these two plants. We examined early successional alder-conditioned soils in a glacial forefield to delineate how alders alter the soil microbial community with increasing dominance. Further, we assessed the impact of late-successional spruce plants on these early successional alder-conditioned microbiomes and related nitrogen cycling through a leachate addition microcosm experiment. We show how increasingly abundant alder select for particular bacterial taxa. Additionally, we found that spruce leachate significantly alters the composition of these microbial communities in large part by driving declines in taxa that are enriched by alder, including bacterial symbionts. We found these effects to be spruce specific, beyond a general leachate effect. Our work also demonstrates a unique influence of spruce on ammonium availability. Such insights bolster theory relating the importance of plant–microbe interactions with late-successional plants and interspecific plant interactions more generally. PMID:29467741
Diels–Alder cycloaddition of 2-methylfuran and ethylene for renewable toluene

DOE Office of Scientific and Technical Information (OSTI.GOV)

Green, Sara K.; Patet, Ryan E.; Nikbin, Nima

Diels–Alder cycloaddition of biomass-derived 2-methylfuran and ethylene provides a thermochemical pathway to renewable toluene. In this work, the kinetics and reaction pathways of toluene formation have been evaluated with H-BEA and Sn-BEA catalysts. Kinetic analysis of the main reaction chemistries reveals the existence of two rate-controlling reactions: (i) Diels–Alder cycloaddition of 2-methylfuran and ethylene where the production rate is independent of the Brønsted acid site concentration, and (ii) dehydration of the Diels–Alder cycloadduct where the production rate is dependent on the Brønsted acid site concentration. Application of a reduced kinetic model supports the interplay of these two regimes with themore » highest concentration of toluene measured at a catalyst loading equal to the transition region between the two kinetic regimes. Selectivity to toluene never exceeded 46%, as 2-methylfuran was consumed by several newly identified reactions to side products, including dimerization of 2-methylfuran, the formation of a trimer following hydrolysis and ring-opening of 2-methylfuran, and the incomplete dehydration of the Diels–Alder cycloadduct of 2-methylfuran and ethylene.« less
Effect of Sugar Maple Root Exudate on Seedlings of Northern Conifer Species

Treesearch

Carl H. Tubbs

1976-01-01

It has been shows that a root exudate of sugar maple reduces the growth of yellow birch. A laboratory test indicated that the growth of northern conifers is also reduced in sugar maple root exudate. Allelopathy may play an important role in survival of species on sites where sugar maple is abundant.
Health of eastern North American sugar maple forests and factors affecting decline

Treesearch

Stephen B. Horsley; Robert P. Long; Scott W. Bailey; Richard A. Hallett; Philip M. Wargo

2002-01-01

Sugar maple (Acer saccharum) is a keystone species in the forests of the northeastern and Midwestern United States and eastern Canada. Its sustained health is an important issue in both managed and unmanaged forests. While sugar maple generally is healthy throughout its range, decline disease of sugar maple has occurred sporadically during the past...
Calculus of One and More Variables with Maple

ERIC Educational Resources Information Center

Samkova, Libuse

2012-01-01

This is a guide to using Maple in teaching fundamental calculus of one, two and three variables (limits, derivatives, integrals, etc.), also suitable for Maple beginners. It outlines one of the ways to effective use of computers in the teaching process. It scans advantages and disadvantages of using Maple in relation to students and teacher. The…
Using Maple to Implement eLearning Integrated with Computer Aided Assessment

ERIC Educational Resources Information Center

Blyth, Bill; Labovic, Aleksandra

2009-01-01

Advanced mathematics courses have been developed and refined by the first author, using an action research methodology, for more than a decade. These courses use the computer algebra system (CAS) Maple in an "immersion mode" where all presentations and student work are done using Maple. Assignments and examinations are Maple files downloaded from…
Chapter 2:Basic properties of undervalued hardwoods

Treesearch

John I. Zerbe

2005-01-01

Among the most abundant of our undervalued hardwoods are the soft maples. However, other species that are also underutilized include some species of birch and some lower grades of the hard maples. This chapter covers physical, mechanical, and other important properties of different soft maples, hard maples, and yellow birch and compares them with the properties of...
Analysis of pure maple syrup consumers

Treesearch

Paul E. Sendak

1974-01-01

Virtually all of the pure maple syrup productim in the United States is in the northern states of Maine, Massachusetts, Michigan, New Hampshire, New York, Ohio, Pennsylvania, Vermont, and Wisconsin. Pure maple syrup users living in the maple production area and users living in other areas of the United States were asked a series of questions about their use of pure...
Methyl gallate is a natural constituent of maple (Genus Acer) leaves.

PubMed

Abou-Zaid, Mamdouh M; Lombardo, Domenic A; Nozzolillo, Constance

2009-01-01

Methyl gallate was found in ethanolic extracts of red maple (Acer rubrum L.), silver maple (A. saccharinum L.) and sugar maple (A. saccharum Marsh) leaves, but more was present in methanolic extracts. The increased amount of methyl gallate in methanolic extracts was accompanied by a disappearance of m-digallate. It is concluded that only some of the methyl gallate detected in methanolic extracts is an artefact as a result of methanolysis of m-digallate. Its presence in ethanolic extracts is evidence that it is also a natural constituent of maple leaves.
Red alder harvesting opportunities in western Oregon.

Treesearch

Donald R. Gedney

1990-01-01

This report presents statistics on the present distribution and ownership of merchantable stands of red alder in western Oregon and the character of these stands as they affect harvesting opportunities.
Coupled hydraulic and photosynthetic feedbacks on forest transpiration throughout the growing season

NASA Astrophysics Data System (ADS)

Mackay, D. S.; Ewers, B. E.

2007-12-01

Ecosystem models account for vegetative controls on water fluxes using environmental drivers and hydraulic and/or biochemical limits on canopy stomatal conductance (Gs), variations in space and time of leaf area index (L), and species or biome specific parameters. However, some parameters, such as maximum stomatal conductance or its reference proxy at vapor pressure deficit of 1 kPa (Gsref), may not be strictly time-independent suggesting as yet undefined mechanisms in the models. We developed a model of coupled canopy water and carbon exchange, which allowed us to examine photosynthetic and hydraulic feedbacks on Gsref spanning the whole growing season for several dominant tree species in wetland and upland positions that collectively account for most a 1600 square km region centered on the WLEF AmeriFlux tower in Wisconsin, USA. The model assimilated half-hourly sap flux and micrometeorological data to quantify and explain temporal variations in Gsref for trembling aspen, sugar maple, and red pine in upland sites, and speckled alder and white cedar in wetland sites. Results show (1) phenological effects on photosynthetic activity with feedback on Gsref in all species, and (2) lags of up to two months between maximum per unit leaf area photosynthetic rates for conifer versus deciduous species. These results show that for given environmental conditions canopy transpiration depends on both L and timing of biochemical activation, both of which have implications for regional ecosystem water cycling.
Dual function catalysts. Dehydrogenation and asymmetric intramolecular Diels-Alder cycloaddition of N-hydroxy formate esters and hydroxamic acids: evidence for a ruthenium-acylnitroso intermediate.

PubMed

Chow, Chun P; Shea, Kenneth J

2005-03-23

The chiral ruthenium salen complex, 13b, functions as an efficient catalyst for the sequential oxidation and asymmetric Diels-Alder cycloaddition of hydroxamic acids and N-hydroxy formate esters. This result provides evidence for the formation of a ruthenium-nitroso formate (acyl nitroso) intermediate. The Diels-Alder precursors are prepared from simple building blocks, and the cycloadducts, bridged oxazinolactams, can serve as useful intermediates in organic synthesis.
Changes in sediment volume in Alder Lake, Nisqually River Basin, Washington, 1945-2011

USGS Publications Warehouse

Czuba, Jonathan A.; Olsen, Theresa D.; Czuba, Christiana R.; Magirl, Christopher S.; Gish, Casey C.

2012-01-01

The Nisqually River drains the southwest slopes of Mount Rainier, a glaciated stratovolcano in the Cascade Range of western Washington. The Nisqually River was impounded behind Alder Dam when the dam was completed in 1945 and formed Alder Lake. This report quantifies the volume of sediment deposited by the Nisqually and Little Nisqually Rivers in their respective deltas in Alder Lake since 1945. Four digital elevation surfaces were generated from historical contour maps from 1945, 1956, and 1985, and a bathymetric survey from 2011. These surfaces were used to compute changes in sediment volume since 1945. Estimates of the volume of sediment deposited in Alder Lake between 1945 and 2011 were focused in three areas: (1) the Nisqually River delta, (2) the main body of Alder Lake, along a 40-meter wide corridor of the pre-dam Nisqually River, and (3) the Little Nisqually River delta. In each of these areas the net deposition over the 66-year period was 42,000,000 ± 4,000,000 cubic meters (m3), 2,000,000 ± 600,000 m3, and 310,000 ± 110,000 m3, respectively. These volumes correspond to annual rates of accumulation of 630,000 ± 60,000 m3/yr, 33,000 ± 9,000 m3/yr, and 4,700 ± 1,600 m3/yr, respectively. The annual sediment yield of the Nisqually (1,100 ± 100 cubic meters per year per square kilometer [(m3/yr)/km2]) and Little Nisqually River basins [70 ± 24 (m3/yr)/km2] provides insight into the yield of two basins with different land cover and geomorphic processes. These estimates suggest that a basin draining a glaciated stratovolcano yields approximately 15 times more sediment than a basin draining forested uplands in the Cascade Range. Given the cumulative net change in sediment volume in the Nisqually River delta in Alder Lake, the total capacity of Alder Lake since 1945 decreased about 3 percent by 1956, 8 percent by 1985, and 15 percent by 2011.
Variation in sugar content in a budded sugar maple clone

Treesearch

Frank S., Jr. Santamour; Frank E. Cunningham

1964-01-01

The production of maple sugar and maple syrup from the sap of the sugar maple tree (Acer saccharum Marsh.) is an important industry in the Northeast, particularly in Vermont and New York. Although it has been recognized for a long time that some trees are sweeter than others - have a higher sugar content in their sap - systematic study of ways to...
Root-Crown Relations of Young Sugar Maple and Yellow Birch

Treesearch

Carl H. Tubbs

1977-01-01

Young forest-grown sugar maple and yellow birch (1 to 6 inches d.b.h.) crowns were mapped and roots excavated. Crown dimensions were compared. Sugar maple roots usually terminated within a few feet of the crown perimeter. Yellow birch roots frequently terminated well outside crown perimeters and roots of birch were more irregularly distributed than those of maple....
Dynamics of the sugar maple component of a white oak-yellow-poplar community

Treesearch

Richard C. Schlesinger

1989-01-01

The sugar maple (Acer saccharum Marsh) component in a southern Illinois forest increased over a 48-year period. By 1983 sugar maple was three times greater in importance than any other species in the stand. If the observed rate of increase were to continue, sugar maple would exclude all other species within another 50 to 60 years.
An Experimental Study on the aerodynamic and aeroacoustic performances of Maple-Seed-Inspired UAV Propellers

NASA Astrophysics Data System (ADS)

Hu, Hui; Ning, Zhe

2016-11-01

Due to the auto-rotating trait of maple seeds during falling down process, flow characteristics of rotating maple seeds have been studied by many researchers in recent years. In the present study, an experimental investigation was performed to explore maple-seed-inspired UAV propellers for improved aerodynamic and aeroacoustic performances. Inspired by the auto-rotating trait of maple seeds, the shape of a maple seed is leveraged for the planform design of UAV propellers. The aerodynamic and aeroacoustic performances of the maple-seed-inspired propellers are examined in great details, in comparison with a commercially available UAV propeller purchased on the market (i.e., a baseline propeller). During the experiments, in addition to measuring the aerodynamic forces generated by the maple-seed-inspired propellers and the baseline propeller, a high-resolution Particle Image Velocimetry (PIV) system was used to quantify the unsteady flow structures in the wakes of the propellers. The aeroacoustic characteristics of the propellers are also evaluated by leveraging an anechoic chamber available at the Aerospace Engineering Department of Iowa State University. The research work is supported by National Science Foundation under Award Numbers of OSIE-1064235.

Maple

NASA Astrophysics Data System (ADS)

Nicolaides, Roy A.; Walkington, Noel J.

1996-06-01

A knowledge of one or more high level symbolic mathematics programs is rapidly becoming a necessity for mathematics users from all fields of science. The aim of this book is to provide a solid grounding in Maple, one of the best known of these programs. The authors combine efficiency and economy of exposition with a complete coverage of Maple. The book has twelve chapters, of which eight are completely accessible to anyone who has completed calculus and linear sequences as taught in American universities. These chapters cover the great majority of Maple's capabilities. There are also three chapters on Maple programming that can be read without prior programming experience, although knowledge of a high level programming language (Basic, Fortran, C etc.) will help. There is also a chapter on some relevant aspects of algebra. Above all, the book allows the reader to extract value from Maple without wasting time and effort in the learning process. It is the fastest track to expertise for Maple users in mathematics and computer science.
Microwave processing of maple sap to maple syrup and maple syrup products.

PubMed

Favreau, D; Sosle, V; Raghavan, G S

2001-01-01

A study of the physical process of concentration of maple sap to maple syrup and preparation of maple syrup products by microwave heating is described. Duty cycles of 60, 75 and 100% were used for the microwave application. During the process, some of the drying kinetics are discussed, including the reduction of moisture content with time, the progress of the process in terms of increasing sugar concentration and the power absorbed. Obviously, the rate of water removal was higher in case of the higher duty cycles. The total time required for finishing the syrup was also dependent on the initial mass of the load and the initial sugar content. The products obtained were compared with commercial graded products for the quality and met the highest standards prescribed by the industry. The absence of heat damage or browning of the product was identified as a distinct advantage that could be derived from microwave processing of maple syrup.
A Diels-Alder Route to Angularly Functionalized Bicyclic Structures

PubMed Central

Kim, Woo Han; Lee, Jun Hee; Aussedat, Baptiste; Danishefsky, Samuel J.

2010-01-01

A Diels-Alder based route to trans-fused angularly functionalized bicyclic structures has been developed. This transformation features the use of a tetrasubstituted dienophile in the cycloaddition step. PMID:20717474
Herbivores limit the population size of big-leaf mahogany trees in an Amazonian forest

Treesearch

Julian M. Norghauer; Christopher M. Free; R. Matthew Landis; James Grogan; Jay R. Malcolm; Sean C. Thomas

2015-01-01

The Janzen -- Connell hypothesis proposes that specialized herbivores maintain high numbers of tree species in tropical forests by restricting adult recruitment so that host populations remain at low densities. We tested this prediction for the large timber tree species, Swietenia macrophylla, whose seeds and seedlings are preyed upon by small mammals and a host-...
Big-leaf mahogany Swietenia macrophylla population dynamics and implications for sustainable management

Treesearch

James Grogan; R. Matthew Landis; Christopher M. Free; Mark D. Schulze; Marco Lentini; Mark S. Ashton

2014-01-01

Summary 1. The impacts of selective harvesting in tropical forests on population recovery and future timber yields by high-value species remain largely unknown for lack of demographic data spanning all phases of life history, from seed to senescence. In this study, we use an individual- based model parameterized using 15 years of annual census data to simulate...
Regenerating mahogany (Swietenia macrophylla) from seed in Quintana Roo, Mexico: the effects of sowing method and clearing treatment.

Treesearch

Patricia Negreros-Castilloa; Laura K. Snookb; Carl W. Mize

2003-01-01

Honduras or bigleaf mahogany (Swietenia macrophylla King) is the most commercially important timber species in the Neotropics, but it often does not regenerate successfully after harvesting. Effective methods are needed to sustain or increase mahogany yields by increasing regeneration. This study evaluates the effects of three treatments (slash, fell and burn; slash,...
Regeneration of mahogany (Swietenia macrophylla) in the Yucatan

Treesearch

M.B. Dickinson; D.F. Whigham; D.F. Whigham

1999-01-01

Low rates of natural regeneration of big-leaf mahogany were found in gaps due to felling and natural treefalls in the Yucatan. This finding is consistent with low post-logging abundances of reproductive-sized trees as well as relatively low growth rates of planted mahogany seedlings in small felling gaps. High growth rates of seedlings in large felling gaps and...
Post-logging loss of genetic diversity in a mahogany (Swietenia macrophylla King, Meliaceae) population in Brazilian Amazonia

Treesearch

T. André; M.R. Lemes; J. Grogan; R. Gribel

2008-01-01

Big-leaf mahogany (Swietenia macrophylla King, Meliaceae) is the most valuable widely traded timber species from the Neotropics. Mahogany has been severely overexploited throughout its natural range, which stretches from southern Mexico through Central and South America as far south as the Bolivian Amazon.We investigated effects of selective logging on the genetic...
Diels–Alder Exo-Selectivity in Terminal-Substituted Dienes and Dienophiles: Experimental Discoveries and Computational Explanations

PubMed Central

Lam, Yu-hong; Cheong, Paul Ha-Yeon; Mata, José M. Blasco; Stanway, Steven J.; Gouverneur, Véronique; Houk, K. N.

2009-01-01

The Diels–Alder reactions of a series of silyloxydienes and silylated dienes with acyclic α,β-unsaturated ketones and N-acyloxazolidinones have been investigated. The endo/exo stereochemical outcome is strongly influenced by the substitution pattern of the reactants. High exo selectivity was observed when the termini of the diene and the dienophile involved in the shorter forming bond are both substituted, while the normal endo preference was found otherwise. The exo-selective asymmetric Diels–Alder reactions using Evans’ oxazolidinone chiral auxiliary furnished a high level of π-facial selectivity in the same sense as their well-documented endo-selective counterparts. Computational results of these Diels–Alder reactions were consistent with the experimental endo/exo selectivity in most cases. A twist-asynchronous model accounts for the geometries and energies of the computed transition structures. PMID:19154113
[Chemistry and biosynthesis of prenylflavonoids].

PubMed

Nomura, T

2001-07-01

Many isoprenylated flavonoids have been isolated from mulberry trees and related plants (Moraceae). Among them, kuwanons G (13) and H (14) were the first isolated active substances exhibiting a hypotensive effect from the Japanese Morus root bark. These compounds are considered to be formed through an enzymatic Diels-Alder reaction of a chalcone (15) and dehydro-kuwanon C (16) or its equivalent. Since that time, about forty kinds of Diels-Alder type adducts structurally similar to that of 13 have been isolated from the moraceous plants. Some strains of Morus alba as well as M. bombycis callus tissues have a high productivity of mulberry Diels-Alder type adducts, such as chalcomoracin (26) and kuwanon J (28). The biosynthesis of the mulberry Diels-Alder type adducts has been studied with the aid of the cell strain. Chalcomoracin (26) and kuwanon J (28) were proved to be enzymatic Diels-Alder type reaction products by the administration experiment with O-methylchalcone derivatives. Furthermore, for the isoprenoid biosynthesis of prenylflavonoids in Morus alba callus tissues, a novel way through the junction of glycolysis and pentose-phosphate cycle was proposed. The crude enzyme fraction catalyzing the Morus Diels-Alder type reaction could be isolated. Studies of phenolic constituents of licorice (Glycyrrhiza species) were carried out. On the course of the structure determination of the phenolic constituents of licorice, two new NMR structure determination methods for prenylflavonoids were found. Furthermore, the prenylphenols isolated from licorice were summarized according to the origin of the materials.
Chemistry and biosynthesis of isoprenylated flavonoids from Japanese mulberry tree

PubMed Central

Nomura, Taro; Hano, Yoshio; Fukai, Toshio

2009-01-01

Many isoprenylated flavonoids have been isolated from Japanese mulberry tree (Moraceae). Among them, kuwanons G (1) and H (2) were the first isolated active substances exhibiting a hypotensive effect. These compounds are considered to be formed through an enzymatic Diels-Alder type reaction between an isoprenyl portion of an isoprenylphenol as the diene and an α, β-double bond of chalcone as the dienophile. The absolute configurations of these Diels-Alder type adducts were confirmed by three different methods. The stereochemistries of the adducts were consistent with those of ones in the Diels-Alder reaction involving exo- and endo-addition. Some strains of Morus alba callus tissues have a high productivity of mulberry Diels-Alder type adducts, such as chalcomoracin (3) and kuwanon J (4). The biosynthetic studies of the mulberry Diels-Alder type adducts have been carried out with the aid of the cell strain. Chalcomoracin (3) and kuwanon J (4) were proved to be enzymatic Diels-Alder type reaction products by the administration experiments with O-methylchalcone derivatives. Furthermore, for the isoprenoid biosynthesis of prenylflavonoids in Morus alba callus tissues by administration of [1,3-13C2]- and [2-13C]-glycerol, a novel way through the junction of glycolysis and pentose-phosphate cycle was proved. Two independent isoprenoid biosynthetic pathways, that for sterols and that for isoprenoidphenols, operate in the Morus alba cell cultures. The former is susceptible to compactin (ML-236) and the latter resists to compactin in the cell cultures, respectively. PMID:19907125
75 FR 62520 - Combined Notice of Filings #1

Federal Register 2010, 2011, 2012, 2013, 2014

2010-10-12

... Thursday, October 7, 2010. Docket Numbers: ER10-2541-001. Applicants: Maple Analytics, LLC. Description: Maple Analytics, LLC submits tariff filing per 35: Maple Analytics, LLC Compliance Filing to be...
A guide to sugarbush stocking. Based on the crown diameter/D.b.h. relationship of open-grown sugar maples

Treesearch

H. Clay Smith; Carter B. Gibbs; Carter B. Gibbs

1970-01-01

Sugarbush managers have long needed a guide for determining the stocking of their sugar maple stands. The question is: for desirable sugar maple sap production, how many trees per acre are needed? To provide information about stocking, the USDA Forest Service's sugar maple sap production project at Burlington, Vermont, has made a regionwide study of the...
Measuring changes in stress and vitality indicators in limed sugar maple on the Allegheny Plateau in north-central Pennsylvania

Treesearch

Philip M. Wargo; Rakesh Minocha; Betty Wong; Robert P. Long; Stephen B. Horsley; Thomas J. Hall

2002-01-01

A study established in 1985 in north-central Pennsylvania to determine effects of lime fertilization on declining sugar maple (Acer saccharum Marsh.) was evaluated in 1993 and showed that liming positively affected growth and crown vitality in sugar maple. This effect of lime on sugar maple offered an opportunity to assess other indicators of tree...
Population dynamics of sugar maple through the southern portion of its range: implications for range migration

Treesearch

Justin L. Hart; Christopher M. Oswalt; Craig M. Turberville

2014-01-01

The range of sugar maple (Acer saccharum Marsh.) is expected to shift northward in accord with changing climate. However, a pattern of increased sugar maple abundance has been reported from sites throughout the eastern US. The goal of our study was to examine the stability of the sugar maple southern range boundary by analyzing its demography through...
Sap sugar parameters of silver maple provenances and clones grown on upland and bottomland sites

Treesearch

J. J. Zaczek; A. D. Carver; K. W. J. Williard; J. K. Buchheit; J. E. Preece; J. C. Mangun

2003-01-01

Sap sugar concentration (SSC), sap volume, and stem diameter were measured for 49 different silver maple clones representing a range-wide collection of 13 provenances within replicated upland and bottomland plantations in southern Illinois during the winter of 2001. For comparison, 42 sugar maple trees were sampled in a local sugarbush. Silver maple SSC averaged 1.51...
Foliar Nutrient Distribution Patterns in Sympatric Maple Species Reflect Contrasting Sensitivity to Excess Manganese.

PubMed

Fernando, Denise R; Marshall, Alan T; Lynch, Jonathan P

2016-01-01

Sugar maple and red maple are closely-related co-occurring tree species significant to the North American forest biome. Plant abiotic stress effects including nutritional imbalance and manganese (Mn) toxicity are well documented within this system, and are implicated in enhanced susceptibility to biotic stresses such as insect attack. Both tree species are known to overaccumulate foliar manganese (Mn) when growing on unbuffered acidified soils, however, sugar maple is Mn-sensitive, while red maple is not. Currently there is no knowledge about the cellular sequestration of Mn and other nutrients in these two species. Here, electron-probe x-ray microanalysis was employed to examine cellular and sub-cellular deposition of excessively accumulated foliar Mn and other mineral nutrients in vivo. For both species, excess foliar Mn was deposited in symplastic cellular compartments. There were striking between-species differences in Mn, magnesium (Mg), sulphur (S) and calcium (Ca) distribution patterns. Unusually, Mn was highly co-localised with Mg in mesophyll cells of red maple only. The known sensitivity of sugar maple to excess Mn is likely linked to Mg deficiency in the leaf mesophyll. There was strong evidence that Mn toxicity in sugar maple is primarily a symplastic process. For each species, leaf-surface damage due to biotic stress including insect herbivory was compared between sites with acidified and non-acidified soils. Although it was greatest overall in red maple, there was no difference in biotic stress damage to red maple leaves between acidified and non-acidified soils. Sugar maple trees on buffered non-acidified soil were less damaged by biotic stress compared to those on unbuffered acidified soil, where they are also affected by Mn toxicity abiotic stress. This study concluded that foliar nutrient distribution in symplastic compartments is a determinant of Mn sensitivity, and that Mn stress hinders plant resistance to biotic stress.
Foliar Nutrient Distribution Patterns in Sympatric Maple Species Reflect Contrasting Sensitivity to Excess Manganese

PubMed Central

Fernando, Denise R.; Marshall, Alan T.; Lynch, Jonathan P.

2016-01-01

Sugar maple and red maple are closely-related co-occurring tree species significant to the North American forest biome. Plant abiotic stress effects including nutritional imbalance and manganese (Mn) toxicity are well documented within this system, and are implicated in enhanced susceptibility to biotic stresses such as insect attack. Both tree species are known to overaccumulate foliar manganese (Mn) when growing on unbuffered acidified soils, however, sugar maple is Mn-sensitive, while red maple is not. Currently there is no knowledge about the cellular sequestration of Mn and other nutrients in these two species. Here, electron-probe x-ray microanalysis was employed to examine cellular and sub-cellular deposition of excessively accumulated foliar Mn and other mineral nutrients in vivo. For both species, excess foliar Mn was deposited in symplastic cellular compartments. There were striking between-species differences in Mn, magnesium (Mg), sulphur (S) and calcium (Ca) distribution patterns. Unusually, Mn was highly co-localised with Mg in mesophyll cells of red maple only. The known sensitivity of sugar maple to excess Mn is likely linked to Mg deficiency in the leaf mesophyll. There was strong evidence that Mn toxicity in sugar maple is primarily a symplastic process. For each species, leaf-surface damage due to biotic stress including insect herbivory was compared between sites with acidified and non-acidified soils. Although it was greatest overall in red maple, there was no difference in biotic stress damage to red maple leaves between acidified and non-acidified soils. Sugar maple trees on buffered non-acidified soil were less damaged by biotic stress compared to those on unbuffered acidified soil, where they are also affected by Mn toxicity abiotic stress. This study concluded that foliar nutrient distribution in symplastic compartments is a determinant of Mn sensitivity, and that Mn stress hinders plant resistance to biotic stress. PMID:27391424
Experimental Testing and Computational Fluid Dynamics Simulation of Maple Seeds and Performance Analysis as a Wind Turbine

NASA Astrophysics Data System (ADS)

Holden, Jacob R.

Descending maple seeds generate lift to slow their fall and remain aloft in a blowing wind; have the wings of these seeds evolved to descend as slowly as possible? A unique energy balance equation, experimental data, and computational fluid dynamics simulations have all been developed to explore this question from a turbomachinery perspective. The computational fluid dynamics in this work is the first to be performed in the relative reference frame. Maple seed performance has been analyzed for the first time based on principles of wind turbine analysis. Application of the Betz Limit and one-dimensional momentum theory allowed for empirical and computational power and thrust coefficients to be computed for maple seeds. It has been determined that the investigated species of maple seeds perform near the Betz limit for power conversion and thrust coefficient. The power coefficient for a maple seed is found to be in the range of 48-54% and the thrust coefficient in the range of 66-84%. From Betz theory, the stream tube area expansion of the maple seed is necessary for power extraction. Further investigation of computational solutions and mechanical analysis find three key reasons for high maple seed performance. First, the area expansion is driven by maple seed lift generation changing the fluid momentum and requiring area to increase. Second, radial flow along the seed surface is promoted by a sustained leading edge vortex that centrifuges low momentum fluid outward. Finally, the area expansion is also driven by the spanwise area variation of the maple seed imparting a radial force on the flow. These mechanisms result in a highly effective device for the purpose of seed dispersal. However, the maple seed also provides insight into fundamental questions about how turbines can most effectively change the momentum of moving fluids in order to extract useful power or dissipate kinetic energy.
Soil base saturation combines with Beech Bark Disease to influence composition and structure of Sugar Maple-Beech forests in an acid rain-impacted region

USGS Publications Warehouse

Lawrence, Gregory B.; McDonnell, Todd C.; Sullivan, Timothy J.; Dovciak, Martin; Bailey, Scott W.; Antidormi, Michael; Zarfos, Michael R.

2018-01-01

Sugar maple, an abundant and highly valued tree species in eastern North America, has experienced decline from soil calcium (Ca) depletion by acidic deposition, while beech, which often coexists with sugar maple, has been afflicted with beech bark disease (BBD) over the same period. To investigate how variations in soil base saturation combine with effects of BBD in influencing stand composition and structure, measurements of soils, canopy, subcanopy, and seedlings were taken in 21 watersheds in the Adirondack region of NY (USA), where sugar maple and beech were the predominant canopy species and base saturation of the upper B horizon ranged from 4.4 to 67%. The base saturation value corresponding to the threshold for Al mobilization (16.8%) helped to define the species composition of canopy trees and seedlings. Canopy vigor and diameter at breast height (DBH) were positively correlated (P < 0.05) with base saturation for sugar maple, but unrelated for beech. However, beech occupied lower canopy positions than sugar maple, and as base saturation increased, the average canopy position of beech decreased relative to sugar maple (P < 0.10). In low-base saturation soils, soil-Ca depletion and BBD may have created opportunities for gap-exploiting species such as red maple and black cherry, whereas in high-base saturation soils, sugar maple dominated the canopy. Where soils were beginning to recover from acidic deposition effects, sugar maple DBH and basal area increased progressively from 2000 to 2015, whereas for beech, average DBH did not change and basal area did not increase after 2010.

Root tensile strength of grey alder and mountain maple grown on a coarse grained eco-engineered slope in the Swiss Alps related to wood anatomical features

NASA Astrophysics Data System (ADS)

Kink, Dimitri; Bast, Alexander; Meyer, Christine; Meier, Wolfgang; Egli, Markus; Gärtner, Holger

2014-05-01

Steep, vegetation free slopes are a common feature in alpine areas. The material covering these slopes is prone to all kind of erosional processes, resulting in a high risk potential for population and infrastructure. This risk potential is likely to increase with the predicted change in the spatiotemporal distribution of precipitation events. A potential increase in extreme precipitation events will also result in a higher magnitude and frequency of erosional processes. In the Swiss Alps as in many other mountainous areas, there is a need to stabilize these slopes to reduce their direct or indirect hazard potential. In this regard, eco-engineering is a very promising and sustainable approach for slope stabilization. Planting trees and shrubs is a central task in eco-engineering. A developing vegetation cover will on one hand reduce the mechanical effects of rainfall by an increased interception, on the other hand, the root systems cause modifications of soil properties. Roots not only provide anchorage for the plants, they also promote soil aggregation and are able to penetrate possible shear horizons. Overall, anchorage of plants is at the same extend also stabilizing the near subsurface. When rainfall occurs, the saturated soil exerts downhill pressure to a tree or shrub. As long as the root distribution supports anchorage, the respective slope area remains stable. At this point, the tensile strength of the roots is a critical measure, because it is more likely that the supporting roots break than the entire root system being pulled out of the soil completely. As a consequence, root tensile strength is an important parameter in characterizing the soil stabilization potential of trees and shrubs. It is known that tree roots show a high variability in their anatomical structure depending on their depth below soil surface as well as their distance to the main stem. Therefore, we assume that these structural changes affect the tensile strength of every single root. In order to confirm this assumption and possibly find more important root properties which have an influence on soil stabilization, the root systems of seven trees (three grey alder, four mountain maple) were excavated and analyzed. The study site is a catchment, where shallow landslides are common. It is located in the Prättigau valley in the Eastern Swiss Alps and was eco-engineered in 1997. The substrate is coarse-grained morainic material, mean annual air temperature reaches 4.64°C, average precipitation is 1170 mm, and the altitude is about 1000 m a.s.l.. The root system of each tree was uncovered carefully by hand to keep the roots undamaged, before removal it was photographed in situ to document the root distribution. The root systems were then cut into single root pieces of about 20 cm length and the position of each sample was documented. The root samples were then hierarchically classified in several root classes. The tensile strength of more than 500 samples was determined. In addition, the values for age, diameter, and root moisture were ascertained. Since it was assumed, that the cellular structure of the roots has an influence on the tensile strength, two microscopic thin-sections were prepared from all successfully tested root samples. The microscopic analysis focused on anatomical parameters such as the size and number of vessels, their distribution as well as their conductivity. The results for the final correlation between the anatomical characteristics and the root's tensile strength are presented for both tree species.
The Phytophthora species assemblage and diversity in riparian alder ecosystems of western Oregon, USA.

PubMed

Sims, Laura Lee; Sutton, Wendy; Reeser, Paul; Hansen, Everett M

2015-01-01

Phytophthora species were systematically sampled, isolated, identified and compared for presence in streams, soil and roots of alder (Alnus species) dominated riparian ecosystems in western Oregon. We describe the species assemblage and evaluate Phytophthora diversity associated with alder. We recovered 1250 isolates of 20 Phytophthora species. Only three species were recovered from all substrates (streams, soil, alder roots): P. gonapodyides, the informally described "P. taxon Pgchlamydo", and P. siskiyouensis. P. alni ssp. uniformis along with five other species not previously recovered in Oregon forests are included in the assemblage: P.citricola s.l., P. gregata, P. gallica, P. nicotianae and P. parsiana. Phytophthora species diversity was greatest in downstream riparian locations. There was no significant difference in species diversity comparing soil and unwashed roots (the rhizosphere) to stream water. There was a difference between the predominating species from the rhizosphere compared to stream water. The most numerous species was the informally described "P. taxon Oaksoil", which was mainly recovered from, and most predominant in, stream water. The most common species from riparian forest soils and alder root systems was P. gonapodyides. © 2015 by The Mycological Society of America.
Comparison of the enhancement of plasma glucose levels in type 2 diabetes Otsuka Long-Evans Tokushima Fatty rats by oral administration of sucrose or maple syrup.

PubMed

Nagai, Noriaki; Ito, Yoshimasa; Taga, Atsushi

2013-01-01

Maple syrup is used as a premium natural sweeter, and is known for being good for human health. In the present study, we investigate whether maple syrup is suitable as a sweetener in the management of type 2 diabetes using Otsuka Long-Evans Tokushima Fatty (OLETF) rats, a model of type 2 diabetes mellitus. OLETF rats develop type 2 diabetes mellitus by 30 weeks of age, and 60-week-old OLETF rats show hyperglycemia and hypoinsulinemia via pancreatic β-cell dysfunction. The administration of sucrose or maple syrup following an OGT test increased plasma glucose (PG) levels in OLETF rats, but the enhancement in PG following the oral administration of maple syrup was lower than in the case of sucrose administration in both 30- and 60-week-old OLETF rats. Although, the insulin levels in 30-week-old OLETF rats also increased following the oral administration of sucrose or maple syrup, no increase in insulin levels was seen in 60-week-old OLETF rats following the oral administration of either sucrose or maple syrup. No significant differences were observed in insulin levels between sucrose- and maple syrup-administered OLETF rats at either 30 or 60 weeks of age. The present study strongly suggests that the maple syrup may have a lower glycemic index than sucrose, which may help in the prevention of type 2 diabetes.
The effect of pressure on microwave-enhanced Diels-Alder reactions. A case study.

PubMed

Kaval, Nadya; Dehaen, Wim; Kappe, C Oliver; Van der Eycken, Erik

2004-01-21

It is demonstrated that microwave-assisted Diels-Alder reactions of substituted 2(1H)-pyrazinones with ethylene are significantly more effective utilizing pre-pressurized (up to 10 bar) reaction vessels.
Seed production and advance regeneration in Allegheny hardwood forests

Treesearch

John C. Bjorkbom

1979-01-01

The production of flowers and seeds of black cherry, red maple, sugar maple, and white ash and their relation to advance regeneration were observed from 1971 through 1976 on the Allegheny Plateau of northwestern Pennsylvania. There were good seed crops 1 year out of 2 for black cherry, 1 year out of 3 for red maple, and 1 year out of 6 for sugar maple. No white ash...
Use of damage surveys and field inventories to evaluate oak and sugar maple health in the northern United States

Treesearch

Randall S Morin; Christopher W. Woodall; Jim Steinman; Charles H. Perry

2009-01-01

Oak species (Quercus spp.) and sugar maple (Acer saccharum) are substantial components of the forest ecosystems in the 24-state region spanning the northern U.S. During recent decades, both damage surveys and forest inventories have documented declines of sugar maple and oak health. In order to more fully assess the status of oak and sugar maple health, we examined...
An Investigation of bat durability by wood species

Treesearch

Eric Ruggiero; James Sherwood; Patrick Drane; David Kretschmann

2012-01-01

Northern white ash had been the wood of choice for Major League Baseball (MLB) bats until the introduction of hard maple in the late 1990s. Since the introduction of maple to the game, there has been a perceived increase in the rate of bats to exhibit multi-piece failures (MPF)both ash and maple. Lab and field data indicate that while a maple bat is as...
Synthesis of isochromene-type scaffolds via single-flask Diels-Alder-[4 + 2]-annulation sequence of a silyl-substituted diene with menadione.

PubMed

Lee, Jihoon; Panek, James S

2014-06-20

A sequential Diels-Alder reaction/silicon-directed [4 + 2]-annulation was developed to assemble hydroisochromene-type ring systems from menadione 2. In the first step, a Diels-Alder of the 1-silyl-substituted butadiene 1 with 2 furnished an intermediate cyclic allylsilane. Subsequently, TMSOTf promoted a [4 + 2]-annulation through trapping of an oxonium, generated by condensation between an aldehyde and the TBS protected alcohol resulted in the formation of a cis-fused hydroisochromene 13.
The influence of reaction conditions on the Diels-Alder cycloadditions of 2-thio-3-chloroacrylamides; investigation of thermal, catalytic and microwave conditions.

PubMed

Kissane, Marie; Lynch, Denis; Chopra, Jay; Lawrence, Simon E; Maguire, Anita R

2010-12-21

The Diels-Alder cycloadditions of cyclopentadiene and 2,3-dimethyl-1,3-butadiene to a range of 2-thio-3-chloroacrylamides under thermal, catalytic and microwave conditions is described. The influence of reaction conditions on the outcome of the cycloadditions, in particular the stereoselectivity and reaction efficiency, is discussed. While the cycloadditions have been attempted at the sulfide, sulfoxide and sulfone levels of oxidation, use of the sulfoxide derivatives is clearly beneficial for stereoselective construction of Diels-Alder cycloadducts.
Changes in plasma glucose in Otsuka Long-Evans Tokushima Fatty rats after oral administration of maple syrup.

PubMed

Nagai, Noriaki; Yamamoto, Tetsushi; Tanabe, Wataru; Ito, Yoshimasa; Kurabuchi, Satoshi; Mitamura, Kuniko; Taga, Atsushi

2015-01-01

We investigate whether maple syrup is a suitable sweetener in the management of type 2 diabetes using the Otsuka Long-Evans Tokushima Fatty (OLETF) rat. The enhancement in plasma glucose (PG) and glucose absorption in the small intestine were lower after the oral administration of maple syrup than after sucrose administration in OLETF rats, and no significant differences were observed in insulin levels. These data suggested that maple syrup might inhibit the absorption of glucose from the small intestine and preventing the enhancement of PG in OLETF rats. Therefore, maple syrup might help in the prevention of type 2 diabetes.
Widespread sugar maple decline and regeneration failure in the Adirondacks

Treesearch

Jerry C. Jenkins; Elizabeth Moffett; Daphne Ross

1999-01-01

Over large areas of the Adirondacks, hardwood stands whose canopies are dominated by or contain abundant mature sugar maple (Acer saccharum Marsh.) have almost no sugar maple saplings or seedlings in the understory.
Sugar maple ecology and health: proceedings of an international symposium

Treesearch

Stephen B. Horsley; Robert P. Long; eds.

1999-01-01

Contains 28 papers and abstracts on sugar maple history and ecology; recent sugar maple declines; nutrient and belowground dynamics in northeastern forests; and interactions of forest health with biotic and abiotic stressors.
After the Maples--What Then?

ERIC Educational Resources Information Center

Trisler, Carmen E.

1994-01-01

Uses models to illustrate the possible "migration route" of the sugar maple in response to predicted global climate change. Curriculum activities for students are provided that specifically address the sugar maple forests of the Great Lakes regions. (ZWH)
Factors affecting distribution of wood, detritus, and sediment in headwater streams draining managed young-growth red alder - Conifer forests in southeast Alaska

USGS Publications Warehouse

Gomi, T.; Johnson, A.C.; Deal, R.L.; Hennon, P.E.; Orlikowska, E.H.; Wipfli, M.S.

2006-01-01

Factors (riparian stand condition, management regimes, and channel properties) affecting distributions of wood, detritus (leaves and branches), and sediment were examined in headwater streams draining young-growth red alder (Alnus rubra Bong.) - conifer riparian forests (40 years old) remained in channels and provided sites for sediment and organic matter storage. Despite various alder-conifer mixtures and past harvesting effects, the abundance of large wood, fine wood, and detritus accumulations significantly decreased with increasing channel bank-full width (0.5-3.5 m) along relatively short channel distances (up to 700 m). Changes in wood, detritus, and sediment accumulations together with changes in riparian stand characteristics create spatial and temporal variability of in-channel conditions in headwater systems. A component of alder within young-growth riparian forests may benefit both wood production and biological recovery in disturbed headwater stream channels. ?? 2006 NRC.
Pure Maple Syrup: Nutritive Value.

PubMed

Leaf, A L

1964-02-28

Variations in concentrations of sugar, nitrogen, phosphorus, potassium, calcium, and magnesium of sap from sugar maple (Acer saccharum, Marsh.) trees are related to the time of sap collection and result in variation of the same components in pure maple syrup. Thirty milliliters (one fluid ounce) of pure maple syrup may contain 3 to 6 mg of phosphorus, 10 to 30 mg of potassium, 40 to 80 mg of calcium, and 4 to 25 mg of magnesium.
Widespread Expansion of Boreal Shrublands in the Siberian Low Arctic Is Linked to Cryogenic Disturbance and Geomorphology

NASA Astrophysics Data System (ADS)

Frost, G. V.; Epstein, H. E.; Walker, D. A.

2012-12-01

Declassified imagery from the KH-4B "Corona" and KH-7 "Gambit" Cold War satellite surveillance systems (1963-1972) are a unique, high-resolution dataset that establishes a baseline for landcover-change studies in the Russian Arctic spanning 6 decades. We co-registered Corona/Gambit and modern high-resolution imagery for seven ~65 km2 Low Arctic sites in northwest Siberia and Chukotka and quantified changes in the extent of tall shrublands dominated by Siberian alder (Alnus fruticosa) using a point-intercept sampling approach. We made ground observations at two sites to identify important geomorphic processes and physiographic units associated with shrub expansion. Alder shrubland cover increased at all sites; relative to the 1960s extent, shrubland extent increased by 5-31% at the northwest Siberian sites and by 9% at both Chukotkan sites,. In northwest Siberia, alder expansion was closely linked to cryogenic disturbances related to patterned-ground and active-layer detachments. At the Chukotkan sites, most alder expansion occurred on hillslope colluvium and floodplains; we also observed modest increases in Siberian dwarf pine (Pinus pumila). The close correspondence between expanding shrub patches and disturbance processes indicates that sparsely-vegetated, mineral-rich seedbeds strongly facilitate alder recruitment, and that the spatio-temporal attributes of disturbance mechanisms are a key determinant of landscape susceptibility to shrub expansion. Shrub expansion, in turn, initiates a cascade of effects on permafrost thermal regime and disturbance, promoting the accumulation of biomass and potentially buffering permafrost from climate warming.; Recently-established alder shrubs growing on non-sorted circles in patterned ground near Obskaya, northwest Siberia.
Scaling Up Stomatal Conductance from Leaf to Canopy Using a Dual-Leaf Model for Estimating Crop Evapotranspiration

PubMed Central

Ding, Risheng; Kang, Shaozhong; Du, Taisheng; Hao, Xinmei; Zhang, Yanqun

2014-01-01

The dual-source Shuttleworth-Wallace model has been widely used to estimate and partition crop evapotranspiration (λET). Canopy stomatal conductance (Gsc), an essential parameter of the model, is often calculated by scaling up leaf stomatal conductance, considering the canopy as one single leaf in a so-called “big-leaf” model. However, Gsc can be overestimated or underestimated depending on leaf area index level in the big-leaf model, due to a non-linear stomatal response to light. A dual-leaf model, scaling up Gsc from leaf to canopy, was developed in this study. The non-linear stomata-light relationship was incorporated by dividing the canopy into sunlit and shaded fractions and calculating each fraction separately according to absorbed irradiances. The model includes: (1) the absorbed irradiance, determined by separately integrating the sunlit and shaded leaves with consideration of both beam and diffuse radiation; (2) leaf area for the sunlit and shaded fractions; and (3) a leaf conductance model that accounts for the response of stomata to PAR, vapor pressure deficit and available soil water. In contrast to the significant errors of Gsc in the big-leaf model, the predicted Gsc using the dual-leaf model had a high degree of data-model agreement; the slope of the linear regression between daytime predictions and measurements was 1.01 (R2 = 0.98), with RMSE of 0.6120 mm s−1 for four clear-sky days in different growth stages. The estimates of half-hourly λET using the dual-source dual-leaf model (DSDL) agreed well with measurements and the error was within 5% during two growing seasons of maize with differing hydrometeorological and management strategies. Moreover, the estimates of soil evaporation using the DSDL model closely matched actual measurements. Our results indicate that the DSDL model can produce more accurate estimation of Gsc and λET, compared to the big-leaf model, and thus is an effective alternative approach for estimating and partitioning λET. PMID:24752329
Maple Flooring - How Architects View it

Treesearch

Gary R. Lindell

1971-01-01

In a study of architects'' opinions of maple flooring versus vinyl asbestos tile for school gymnasuims, resiliency and durability were found to be important factors favoring maple whereas vinyl asbestos tile was felt to be less costly and more dimesionally stable.
PECASE: Multi-Spectral Photon Detection in Polymer/Nanoparticle Composites-Toward IR Photodectors and Solar Cells Applicable to Unmanned Vehicles

DTIC Science & Technology

2016-03-31

in Polymer/Nanoparticle Composites-Toward IR Photodectors and Solar Cells Applicable to Sb. GRANT NUMBER Unmanned Vehicles N00014-1 0-1-0481 Sc...photodetectors and solar cells deposited by RIR-MAPLE, and developing a simulation tool for optoelectronic device performance that accounts for RIR...MAPLE film properties. 1S. SUBJECT TERMS Hybrid nanocomposites, MAPLE, RIR-MAPLE, intraband absorption, mid-IR photodetectors, organic solar cells
Neuroradiological findings in maple syrup urine disease

PubMed Central

Indiran, Venkatraman; Gunaseelan, R. Emmanuel

2013-01-01

Maple syrup urine disease is a rare inborn error of amino acid metabolism involving catabolic pathway of the branched-chain amino acids. This disease, if left untreated, may cause damage to the brain and may even cause death. These patients typically present with distinctive maple syrup odour of sweat and urine. Patients typically present with skin and urine smelling like maple syrup. Here we describe a case with relevant magnetic resonance imaging findings and confirmatory biochemical findings. PMID:23772241

Neuroradiological findings in maple syrup urine disease.

PubMed

Indiran, Venkatraman; Gunaseelan, R Emmanuel

2013-01-01

Maple syrup urine disease is a rare inborn error of amino acid metabolism involving catabolic pathway of the branched-chain amino acids. This disease, if left untreated, may cause damage to the brain and may even cause death. These patients typically present with distinctive maple syrup odour of sweat and urine. Patients typically present with skin and urine smelling like maple syrup. Here we describe a case with relevant magnetic resonance imaging findings and confirmatory biochemical findings.
Alder flycatcher

Treesearch

Scott H. Stoleson

2010-01-01

The alder flycatcher is a small flycatcher in the confusing genus Empidonax. It so closely resembles its look-alike congener, the willow flycatcher (E. traillii), that until 1973 they were considered a single species, Traill's flycatcher (American Ornithologists' Union 1973). As most published studies of Traill's...
Synthesis of 3,4-dihydro-1,8-naphthyridin-2(1H)-ones via microwave-activated inverse electron-demand Diels–Alder reactions

PubMed Central

Fadel, Salah; Hajbi, Youssef; Khouili, Mostafa; Lazar, Said

2014-01-01

Summary Substituted 3,4-dihydro-1,8-naphthyridin-2(1H)-ones have been synthesized with the inverse electron-demand Diels–Alder reaction from 1,2,4-triazines bearing an acylamino group with a terminal alkyne side chain. Alkynes were first subjected to the Sonogashira cross-coupling reaction with aryl halides, the product of which then underwent an intramolecular inverse electron-demand Diels–Alder reaction to yield 5-aryl-3,4-dihydro-1,8-naphthyridin-2(1H)-ones by an efficient synthetic route. PMID:24605148
Synthesis of 3,4-dihydro-1,8-naphthyridin-2(1H)-ones via microwave-activated inverse electron-demand Diels-Alder reactions.

PubMed

Fadel, Salah; Hajbi, Youssef; Khouili, Mostafa; Lazar, Said; Suzenet, Franck; Guillaumet, Gérald

2014-01-01

Substituted 3,4-dihydro-1,8-naphthyridin-2(1H)-ones have been synthesized with the inverse electron-demand Diels-Alder reaction from 1,2,4-triazines bearing an acylamino group with a terminal alkyne side chain. Alkynes were first subjected to the Sonogashira cross-coupling reaction with aryl halides, the product of which then underwent an intramolecular inverse electron-demand Diels-Alder reaction to yield 5-aryl-3,4-dihydro-1,8-naphthyridin-2(1H)-ones by an efficient synthetic route.
The Preparation and Properties of Thermo-reversibly Cross-linked Rubber Via Diels-Alder Chemistry.

PubMed

Polgar, Lorenzo Massimo; van Duin, Martin; Picchioni, Francesco

2016-08-25

A method for using Diels Alder thermo-reversible chemistry as cross-linking tool for rubber products is demonstrated. In this work, a commercial ethylene-propylene rubber, grafted with maleic anhydride, is thermo-reversibly cross-linked in two steps. The pending anhydride moieties are first modified with furfurylamine to graft furan groups to the rubber backbone. These pendant furan groups are then cross-linked with a bis-maleimide via a Diels-Alder coupling reaction. Both reactions can be performed under a broad range of experimental conditions and can easily be applied on a large scale. The material properties of the resulting Diels-Alder cross-linked rubbers are similar to a peroxide-cured ethylene/propylene/diene rubber (EPDM) reference. The cross-links break at elevated temperatures (> 150 °C) via the retro-Diels-Alder reaction and can be reformed by thermal annealing at lower temperatures (50-70 °C). Reversibility of the system was proven with infrared spectroscopy, solubility tests and mechanical properties. Recyclability of the material was also shown in a practical way, i.e., by cutting a cross-linked sample into small parts and compression molding them into new samples displaying comparable mechanical properties, which is not possible for conventionally cross-linked rubbers.
Effects of invasive European bird cherry (Prunus padus) on leaf litter processing by aquatic invertebrate shredder communities in urban Alaskan streams

USGS Publications Warehouse

Roon, David A.; Wipfli, Mark S.; Wurtz, Tricia L.

2014-01-01

European bird cherry (Prunus padus) (EBC) is an invasive ornamental tree that is spreading rapidly in riparian forests of urban Alaska. To determine how the spread of EBC affects leaf litter processing by aquatic invertebrate shredders, we conducted complementary leaf pack experiments in two streams located in Anchorage, Alaska. The first experiment contrasted invasive EBC with three native tree species—thin-leaf alder (Alnus tenuifolia), paper birch (Betula neoalaskana), and black cottonwood (Populus trichocarpa)—in one reach of Chester Creek; finding that EBC leaf litter broke down significantly faster than birch and cottonwood, but at a similar rate to alder. The second experiment contrasted EBC with alder in four reaches of Campbell and Chester creeks; finding that while EBC leaf litter broke down significantly faster than alder in Chester Creek, EBC broke down at a similar rate to alder in Campbell Creek. Although EBC sometimes supported fewer shredders by both count and mass, shredder communities did not differ significantly between EBC and native plants. Collectively, these data suggest that invasive EBC is not currently exhibiting strong negative impacts on leaf litter processing in these streams, but could if it continues to spread and further displaces native species over time.
An automated system for evaluation of the potential functionome: MAPLE version 2.1.0

PubMed Central

Takami, Hideto; Taniguchi, Takeaki; Arai, Wataru; Takemoto, Kazuhiro; Moriya, Yuki; Goto, Susumu

2016-01-01

Metabolic and physiological potential evaluator (MAPLE) is an automatic system that can perform a series of steps used in the evaluation of potential comprehensive functions (functionome) harboured in the genome and metagenome. MAPLE first assigns KEGG Orthology (KO) to the query gene, maps the KO-assigned genes to the Kyoto Encyclopedia of Genes and Genomes (KEGG) functional modules, and then calculates the module completion ratio (MCR) of each functional module to characterize the potential functionome in the user’s own genomic and metagenomic data. In this study, we added two more useful functions to calculate module abundance and Q-value, which indicate the functional abundance and statistical significance of the MCR results, respectively, to the new version of MAPLE for more detailed comparative genomic and metagenomic analyses. Consequently, MAPLE version 2.1.0 reported significant differences in the potential functionome, functional abundance, and diversity of contributors to each function among four metagenomic datasets generated by the global ocean sampling expedition, one of the most popular environmental samples to use with this system. MAPLE version 2.1.0 is now available through the web interface (http://www.genome.jp/tools/maple/) 17 June 2016, date last accessed. PMID:27374611
Maple sap as a rich medium to grow probiotic lactobacilli and to produce lactic acid.

PubMed

Cochu, A; Fourmier, D; Halasz, A; Hawari, J

2008-12-01

To demonstrate the feasibility of growing lactobacilli and producing lactic acid using maple sap as a sugar source and to show the importance of oligosaccharides in the processes. Two maple sap samples (Cetta and Pinnacle) and purified sucrose were used as carbon sources in the preparation of three culture media. Compared with the sucrose-based medium, both maple sap-based media produced increased viable counts in two strains out of five by a factor of four to seven. Maple sap-based media also enhanced lactic acid production in three strains. Cetta sap was found to be more efficient than Pinnacle sap in stimulating lactic acid production and, was also found to be richer in various oligosaccharides. The amendment of the Pinnacle-based medium with trisaccharides significantly stimulated Lactobacillus acidophilus AC-10 to grow and produce lactic acid. Maple sap, particularly if rich in oligosaccharides, represents a good carbon source for the growth of lactobacilli and the production of lactic acid. This study provides a proof-of-concept, using maple sap as a substrate for lactic acid production and for the development of a nondairy probiotic drink.
Seasonal and regional diversity of maple sap microbiota revealed using community PCR fingerprinting and 16S rRNA gene clone libraries.

PubMed

Filteau, Marie; Lagacé, Luc; LaPointe, Gisèle; Roy, Denis

2010-04-01

An arbitrary primed community PCR fingerprinting technique based on capillary electrophoresis was developed to study maple sap microbial community characteristics among 19 production sites in Québec over the tapping season. Presumptive fragment identification was made with corresponding fingerprint profiles of bacterial isolate cultures. Maple sap microbial communities were subsequently compared using a representative subset of 13 16S rRNA gene clone libraries followed by gene sequence analysis. Results from both methods indicated that all maple sap production sites and flow periods shared common microbiota members, but distinctive features also existed. Changes over the season in relative abundance of predominant populations showed evidence of a common pattern. Pseudomonas (64%) and Rahnella (8%) were the most abundantly and frequently represented genera of the 2239 sequences analyzed. Janthinobacterium, Leuconostoc, Lactococcus, Weissella, Epilithonimonas and Sphingomonas were revealed as occasional contaminants in maple sap. Maple sap microbiota showed a low level of deep diversity along with a high variation of similar 16S rRNA gene sequences within the Pseudomonas genus. Predominance of Pseudomonas is suggested as a typical feature of maple sap microbiota across geographical regions, production sites, and sap flow periods.
Time domain-nuclear magnetic resonance study of chars from southern hardwoods

Treesearch

Thomas Elder; Nicole Labbe; David Harper; Timothy Rials

2006-01-01

Chars from the thermal degradation of silver maple (Acer saccharinum), red maple (Acer rubrum), sugar maple (Acer saccharum), and white oak (Quercus spp.), performed at temperatures from 250 to 350 oC, were examined using time domain-nuclear magnetic resonance...
Altered Acer Rubrum Fecundity Induced By Chemical Climate Change

NASA Astrophysics Data System (ADS)

Deforest, J. L.; Peters, A.

2014-12-01

Red maple (Acer rubrum L.) is becoming the most dominating tree in North American eastern deciduous forests. Concurrently, human activities have altered the chemical climate of terrestrial ecosystems via acidic deposition, which increases the available of nitrogen (N), while decreasing phosphorus (P) availability. Once a minor forest component prior to European settlement, the abundance of red maple may be a symptom of the modern age. The current paradigm explaining red maple's rise to prominence concerns fire suppression that excludes competitors. However, this still does not explain why red maple is unique compared to other functionally similar trees. The objective of this study was to investigate the interactive influence of acid rain mitigation on the fecundity of red maple. Objectives were achieved by measuring flowering, seed production, germination, and growth from red maple on plots that have been experimentally manipulated to increase soil pH, P, or both in three unglaciated eastern deciduous hardwood forests. At least 50% of the red maple population is seed bearing in our control soils, however the median percent of seed-bearing trees declined to zero when mitigating soils from acidic deposition. This can be explained by the curious fact that red maple is polygamodioecious, or has labile sex-expression, in which an individual tree can change its sex-expression in response to the environment. Furthermore, seed-bearing trees in the mitigated plots grew less, produced less seeds, and germinated at lower rates than their counterparts in control soils. Our results provide evidence that chemical climate change could be the primary contributing factor accelerating the dominance of red maple in eastern North American forests. Our observations can provide a boarder conceptual framework for understanding how nutrient limitations can be applied beyond plant productivity towards explaining distribution changes in vegetation.
Dual mechanism of brain injury and novel treatment strategy in maple syrup urine disease.

PubMed

Zinnanti, William J; Lazovic, Jelena; Griffin, Kathleen; Skvorak, Kristen J; Paul, Harbhajan S; Homanics, Gregg E; Bewley, Maria C; Cheng, Keith C; Lanoue, Kathryn F; Flanagan, John M

2009-04-01

Maple syrup urine disease (MSUD) is an inherited disorder of branched-chain amino acid metabolism presenting with life-threatening cerebral oedema and dysmyelination in affected individuals. Treatment requires life-long dietary restriction and monitoring of branched-chain amino acids to avoid brain injury. Despite careful management, children commonly suffer metabolic decompensation in the context of catabolic stress associated with non-specific illness. The mechanisms underlying this decompensation and brain injury are poorly understood. Using recently developed mouse models of classic and intermediate maple syrup urine disease, we assessed biochemical, behavioural and neuropathological changes that occurred during encephalopathy in these mice. Here, we show that rapid brain leucine accumulation displaces other essential amino acids resulting in neurotransmitter depletion and disruption of normal brain growth and development. A novel approach of administering norleucine to heterozygous mothers of classic maple syrup urine disease pups reduced branched-chain amino acid accumulation in milk as well as blood and brain of these pups to enhance survival. Similarly, norleucine substantially delayed encephalopathy in intermediate maple syrup urine disease mice placed on a high protein diet that mimics the catabolic stress shown to cause encephalopathy in human maple syrup urine disease. Current findings suggest two converging mechanisms of brain injury in maple syrup urine disease including: (i) neurotransmitter deficiencies and growth restriction associated with branched-chain amino acid accumulation and (ii) energy deprivation through Krebs cycle disruption associated with branched-chain ketoacid accumulation. Both classic and intermediate models appear to be useful to study the mechanism of brain injury and potential treatment strategies for maple syrup urine disease. Norleucine should be further tested as a potential treatment to prevent encephalopathy in children with maple syrup urine disease during catabolic stress.
Water Relations of White Alder

Treesearch

Virginia I. Dains

1989-01-01

White alder (Alnus rhombifolia) is a potentially valuable indicator of water stress along California's waterways. Measurements of stomatal conductance, water potential and tissue water relations in conjunction with growth and morphological studies give evidence for the sensitivity of this species to changes in water availability. Potted...
Hardwood price reporting.

Treesearch

Brent L. Sohngen; Richard W. Haynes

1994-01-01

Prices for red alder (Alnus rubra Bong.) hardwood logs are published and analyzed for reliability, consistency, and robustness. Timberland managers can use these prices to make decisions about land management. They show that values for red alder logs have been increasing steadily for the last 11 years.
The Maple Sugar Festival

ERIC Educational Resources Information Center

Johnston, Basil

1978-01-01

Describing the Iroquoi's Maple Sugar Festival, this article details the symbolism of renewal, becoming, and regeneration celebrated by the Iroquoi as the sap from the maple trees begins to flow each year. The symbolic role of woman, the sweet sap itself, and man's fellow creatures are described. (JC)
Role of river flow and sediment mobilization in riparian alder establishment along a bedrock-gravel river, South Fork Eel River, California

NASA Astrophysics Data System (ADS)

Jablkowski, P.; Johnson, E. A.; Martin, Y. E.

2017-10-01

Climatic, hydraulics, hydrologic, and fluvial geomorphic processes are the main drivers of riparian white alder (Alnus rhombifolia Nutt.) distribution in northern California. The Mediterranean climate and canyon bound, bedrock-gravel morphology of the South Fork Eel have a distinct effect on these processes. White alder seeds are preferentially deposited on river bars where river hydraulics create eddies coinciding with the downstream part of riffles and the upstream part of pools. Seeds are generally deposited below bankfull elevations by the descending hydrograph during the spring season in this Mediterranean climate. For successful germination and establishment, the seeds must be deposited at a location such that they are not remobilized by late spring flows. The summer establishment period is defined from the date of seed deposition and germination to the fall/winter date of river sediment mobilization. Seedling root growth rate decreases exponentially with decreasing water potential. However, seedlings are shown not to be generally limited by water availability at the elevations they are most commonly deposited. The establishment of white alder seedlings following the first summer will therefore depend on their ability to resist fall/winter high flows. The method proposed here compares the predicted rooting depth to predicted sediment scour rates. The length of the establishment period rather than water availability determines final seedling rooting depth. Over the past 40 years, very few years had establishment periods that were long enough or had fast enough alder growth rates to survive winter floods that often scour deeper than the total root length. The low survival of seedlings in the first autumn season following germination is believed to be a principal reason for the missing age classes often found in alder distributions along rivers.
Landscape heterogeneity controls growth variability of alder, willow, and birch shrubs in response to observed increases in temperature and snow

NASA Astrophysics Data System (ADS)

Tape, K. D.; Hallinger, M.; Buras, A.; Wilmking, M.

2013-12-01

Over the last decade, evidence has emerged for a circumarctic trend of increasing shrub cover in tundra regions. On the Alaskan tundra, repeat photography has shown spatial differences in shrub patch dynamics: since 1950, most patches expanded while some remained stable. In this study we explore the underpinnings of this landscape heterogeneity by sampling the three dominant shrubs of the Alaskan tundra--alder, willow and birch--and creating shrub ring width chronologies to determine the influence of climate variability on shrub growth. Shrubs of expanding patches of all three species grew at higher rates than shrubs of stable patches. Alder and willow shrubs in expanding patches exhibited mainly positive growth trends, while their counterparts in stable patches exhibited mainly negative growth trends. Birch shrub growth declined in expanding and stable patches. Alder and willow shrub growth rates and responses to climate were controlled more by soil characteristics than by their genus; expanding alder and willow shrubs showed significant positive correlations with spring and summer temperatures, whereas alder and willow shrubs of stable patches were negatively influenced by winter precipitation. The widely-scattered stable shrub patches sampled here are considered ';moist tussock tundra,' which covers 13.4% of the low arctic landscape. In moist tussock tundra, and presumably also wet tussock tundra, the negative influence of deeper snow on shrubs outweighed the positive influence of deeper snow on ground temperature and nutrient stocks articulated by the snow-shrub-microbe hypothesis. Thus, while shrubs of expanding patches have generally profited from warmer summers, shrubs of stable patches have suffered from increased soil moisture resulting from increased snowmelt water. These results underscore the spatial and temporal complexity in shrub-climate dynamics, which will require considerable finesse to appropriately integrate into modeling efforts.
Management implications of long-term tree growth and mortality rates: A modeling study of big-leaf mahogany (Swietenia macrophylla) in the Brazilian Amazon

Treesearch

C.M. Free; R.M. Landis; J. Grogan; M.D. Schulze; M. Lentini; O. Dunisch; NO-VALUE

2014-01-01

Knowledge of tree age-size relationships is essential towards evaluating the sustainability of harvest regulations that include minimum diameter cutting limits and fixed-length cutting cycles. Although many tropical trees form annual growth rings and can be aged from discs or cores, destructive sampling is not always an option for valuable or threatened species. We...
Using Math With Maple Sugaring.

ERIC Educational Resources Information Center

Christenson, Gary

1984-01-01

Suggest several math activities using the simple technique of tapping a sugar maple tree for sap. Information and activities presented are useful in tapping one or two trees on school property, helping students who tap trees at home, or leading a field trip to a nearby maple sugaring site. (ERB)
Influence of flooding duration on the biomass growth of alder and willow.

Treesearch

Lewis F. Ohmann; M. Dean Knighton; Ronald McRoberts

1990-01-01

Simple second-order (quadratic) polynomials were used to model the relationship between 3-year biomass increase (net ovendry weight in grams) and flooding duration (days) for four combinations of shrub type (alder, willow) and soils type (fine-sand, clay-loam).

A recyclable fluorous organocatalyst for Diels-Alder reactions

PubMed Central

Chu, Qianli; Zhang, Wei; Curran, Dennis P.

2007-01-01

Chiral fluorous imidazolidinone catalyst 2 provides consistently high enantioselectivities in Diels-Alder reactions of dienes and α, β-unsaturated aldehydes. The catalyst can be readily separated from the reaction products by fluorous solid-phase extraction, and recovered in excellent purity for direct reuse. PMID:17710220
A new approach to the synthesis of monomers and polymers incorporating furan/maleimide Diels-Alder adducts

NASA Astrophysics Data System (ADS)

Banella, Maria Barbara; Gioia, Claudio; Vannini, Micaela; Colonna, Martino; Celli, Annamaria; Gandini, Alessandro

2016-05-01

The Diels-Alder reaction between furan and maleimide moieties is a well-known and widely used strategy to build bio-based macromolecular structures with peculiar properties. The furan-maleimide adducts are thermally reversible because they can be broken above about 120°C and recombined at lower temperatures. At the moment only the monomers exhibiting the furan or the maleimide moieties on their extremity are used in order to get linear or cross-linked polymeric structures. The innovative idea described here consists in using a monomer bearing two carboxylic acidic groups on its extremities and a furan-maleimide Diels-Alder adduct within its structure. This monomer can give rise to classical polycondensation reactions leading to polymers. These polymers (which are polyesters in the present case) can be broken at high temperatures in correspondence of the furane-maleimide Diels-Alder adduct leading to segments exhibiting furan or maleimide moieties at their extremities, which at lower temperature recombine leading to random or block copolymers.
Regiocontrol by remote substituents. An enantioselective total synthesis of frenolicin B via a highly regioselective Diels-Alder reaction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kraus, G.A.; Li, J.; Gordon, M.S.

1993-06-30

The quinone subunit is contained in a broad range of biologically important natural products such as frenolicin B, which is a member of the pyranonaphthoquinone family. The diverse biological activity of quinones has led to the development of several new synthetic methods for quinones. Among the pathways featuring a cycloaddition reaction, one of the most general methods for the regiospecific synthesis of substituted quinones was pioneered by H.J. Rapoport and others. This method involves the Diels-Alder reaction of a substituted quinone. As part of a program to evaluate the directing effects of functional groups not directly attached to the atomsmore » undergoing Diels-Alder cycloaddition, we now report that remote substituents on a dienophile can confer excellent regioselectivity in Diels-Alder reactions. This work has led to an extremely direct synthesis of the pyranonaphthoquinone framework and to the first synthesis of frenolicin B (1). 19 refs., 1 fig.« less
What's a sugar maple worth?

Treesearch

George L. Cook

1991-01-01

What is a sugar maple worth? This is an interesting question and not one which is easy to answer. I have some thoughts on this subject to share with you. Many of these have been discussed with county and district foresters, sugarmakers and people from the community who appreciate the maple tree very much.
Sapstreak Disease of Sugar Maple Found is Wisconsin for the First Time

Treesearch

Kenneth J. Jr. Kessler

1972-01-01

The first occurrence in Wisconsin of sapstreak disease of sugar maple is described. The outbreak of the disease was traced to past logging activities. To prevent further disease development, sugar maples should not be cut for a few years in areas contiguos to diseased trees
Maple Explorations, Perfect Numbers, and Mersenne Primes

ERIC Educational Resources Information Center

Ghusayni, B.

2005-01-01

Some examples from different areas of mathematics are explored to give a working knowledge of the computer algebra system Maple. Perfect numbers and Mersenne primes, which have fascinated people for a very long time and continue to do so, are studied using Maple and some questions are posed that still await answers.
75 FR 57016 - Maple Analytics, LLC; Supplemental Notice That Initial Market-Based Rate Filing Includes Request...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-09-17

... DEPARTMENT OF ENERGY Federal Energy Regulatory Commission [Docket No. ER10-2541-000] Maple Analytics, LLC; Supplemental Notice That Initial Market- Based Rate Filing Includes Request for Blanket... proceeding of Maple Analytics, LLC's application for market-based rate authority, with an accompanying rate...
America's Native Sweet: Chippewa Treaties and the Right to Harvest Maple Sugar.

ERIC Educational Resources Information Center

Keller, Robert H.

1989-01-01

Argues in favor of a Chippewa right to harvest maple sap from trees on federal land. Discusses the history of Indian production of and trade in maple sugar, examines relevant treaties, and draws parallels with tribal rights to fish and harvest wild rice. Contains 91 references. (SV)
Maple Sugar Harvesting/Wild Rice Harvesting.

ERIC Educational Resources Information Center

Minneapolis Public Schools, MN.

Comprised of two separate booklets, this resource unit assists elementary teachers in explaining how the Ojibwe people harvest maple sugar and wild rice. The first booklet explains the procedure of tapping the maple trees for sap, preparation for boiling the sap, and the three forms the sugar is made into (granulated, "molded," and…
An automated system for evaluation of the potential functionome: MAPLE version 2.1.0.

PubMed

Takami, Hideto; Taniguchi, Takeaki; Arai, Wataru; Takemoto, Kazuhiro; Moriya, Yuki; Goto, Susumu

2016-07-03

Metabolic and physiological potential evaluator (MAPLE) is an automatic system that can perform a series of steps used in the evaluation of potential comprehensive functions (functionome) harboured in the genome and metagenome. MAPLE first assigns KEGG Orthology (KO) to the query gene, maps the KO-assigned genes to the Kyoto Encyclopedia of Genes and Genomes (KEGG) functional modules, and then calculates the module completion ratio (MCR) of each functional module to characterize the potential functionome in the user's own genomic and metagenomic data. In this study, we added two more useful functions to calculate module abundance and Q-value, which indicate the functional abundance and statistical significance of the MCR results, respectively, to the new version of MAPLE for more detailed comparative genomic and metagenomic analyses. Consequently, MAPLE version 2.1.0 reported significant differences in the potential functionome, functional abundance, and diversity of contributors to each function among four metagenomic datasets generated by the global ocean sampling expedition, one of the most popular environmental samples to use with this system. MAPLE version 2.1.0 is now available through the web interface (http://www.genome.jp/tools/maple/) 17 June 2016, date last accessed. © The Author 2016. Published by Oxford University Press on behalf of Kazusa DNA Research Institute.
Relative resistance or susceptibility of maple (Acer) species, hybrids and cultivars to six arthropod pests of production nurseries.

PubMed

Seagraves, Bonny L; Redmond, Carl T; Potter, Daniel A

2013-01-01

Maples (Acer spp.) in production nurseries are vulnerable to numerous arthropod pests that can stunt or even kill the young trees. Seventeen cultivars representing various Acer species and hybrids were evaluated for extent of infestation or injury by shoot and trunk borers (Proteoteras aesculana, Chrysobothris femorata), potato leafhopper (Empoasca fabae), Japanese beetle (Popillia japonica), maple spider mite (Oligonychus aceris) and calico scale (Eulecanium cerasorum). Evaluations were done in replicated field plots in central and western Kentucky. All of the maples were susceptible, to varying degrees, to one or more key pest(s). Red maples (A. rubrum) were relatively vulnerable to potato leafhopper injury and borers but nearly free of Japanese beetle feeding and spider mites. Sugar maples sustained conspicuous Japanese beetle damage but had very low mite populations, whereas the opposite was true for Freeman maples (A. × freemanii). A. campestre was heavily infested by calico scale. Within each species or hybrid there were cultivar differences in degree of infestation or damage by particular pests. The results should help growers to focus pest management efforts on those plantings at greatest risk from particular pests, and to choose cultivars requiring fewer insecticide inputs to produce a quality tree. Copyright © 2012 Society of Chemical Industry.
A Monte-Carlo maplet for the study of the optical properties of biological tissues

NASA Astrophysics Data System (ADS)

Yip, Man Ho; Carvalho, M. J.

2007-12-01

Monte-Carlo simulations are commonly used to study complex physical processes in various fields of physics. In this paper we present a Maple program intended for Monte-Carlo simulations of photon transport in biological tissues. The program has been designed so that the input data and output display can be handled by a maplet (an easy and user-friendly graphical interface), named the MonteCarloMaplet. A thorough explanation of the programming steps and how to use the maplet is given. Results obtained with the Maple program are compared with corresponding results available in the literature. Program summaryProgram title:MonteCarloMaplet Catalogue identifier:ADZU_v1_0 Program summary URL:http://cpc.cs.qub.ac.uk/summaries/ADZU_v1_0.html Program obtainable from: CPC Program Library, Queen's University, Belfast, N. Ireland Licensing provisions: Standard CPC licence, http://cpc.cs.qub.ac.uk/licence/licence.html No. of lines in distributed program, including test data, etc.:3251 No. of bytes in distributed program, including test data, etc.:296 465 Distribution format: tar.gz Programming language:Maple 10 Computer: Acer Aspire 5610 (any running Maple 10) Operating system: Windows XP professional (any running Maple 10) Classification: 3.1, 5 Nature of problem: Simulate the transport of radiation in biological tissues. Solution method: The Maple program follows the steps of the C program of L. Wang et al. [L. Wang, S.L. Jacques, L. Zheng, Computer Methods and Programs in Biomedicine 47 (1995) 131-146]; The Maple library routine for random number generation is used [Maple 10 User Manual c Maplesoft, a division of Waterloo Maple Inc., 2005]. Restrictions: Running time increases rapidly with the number of photons used in the simulation. Unusual features: A maplet (graphical user interface) has been programmed for data input and output. Note that the Monte-Carlo simulation was programmed with Maple 10. If attempting to run the simulation with an earlier version of Maple, appropriate modifications (regarding typesetting fonts) are required and once effected the worksheet runs without problem. However some of the windows of the maplet may still appear distorted. Running time: Depends essentially on the number of photons used in the simulation. Elapsed times for particular runs are reported in the main text.
Diels–Alder reactions of myrcene using intensified continuous-flow reactors

PubMed Central

Álvarez-Diéguez, Miguel Á; Kohl, Thomas M; Tsanaktsidis, John

2017-01-01

This work describes the Diels–Alder reaction of the naturally occurring substituted butadiene, myrcene, with a range of different naturally occurring and synthetic dienophiles. The synthesis of the Diels–Alder adduct from myrcene and acrylic acid, containing surfactant properties, was scaled-up in a plate-type continuous-flow reactor with a volume of 105 mL to a throughput of 2.79 kg of the final product per day. This continuous-flow approach provides a facile alternative scale-up route to conventional batch processing, and it helps to intensify the synthesis protocol by applying higher reaction temperatures and shorter reaction times. PMID:28228853
An Appreciation: Berni Julian Alder

NASA Astrophysics Data System (ADS)

Graham Hoover, William

Berni Alder profoundly influenced my research career at Lawrence Livermore National Laboratory and the Davis Campus' Teller Tech, beginning in 1962 and lasting for over fifty years. I very much appreciate the opportunity provided by his Ninetieth Birthday Celebration to review some of the many high spots along the way.
Assembly of the Isoindolinone Core of Muironolide A by Asymmetric Intramolecular Diels-Alder Cycloaddition

PubMed Central

Flores, Beatris; Molinski, Tadeusz F.

2011-01-01

The hexahydro-1H-isoindolin-1-one core of muironolide A was prepared by asymmetric intramolecular Diels Alder cycloaddition using a variant of the MacMillan organocatalyst which sets the C4,C5 and C11 stereocenters. PMID:21751773
A microwave assisted intramolecular-furan-Diels-Alder approach to 4-substituted indoles.

PubMed

Petronijevic, Filip; Timmons, Cody; Cuzzupe, Anthony; Wipf, Peter

2009-01-07

The key steps of a versatile new protocol for the convergent synthesis of 3,4-disubstituted indoles are the addition of an alpha-lithiated alkylaminofuran to a carbonyl compound, a microwave-accelerated intramolecular Diels-Alder cycloaddition and an in situ double aromatization reaction.
Study of Polymer Crystallization by Physical Vapor Deposition

NASA Astrophysics Data System (ADS)

Jeong, Hyuncheol

When a polymer is confined under the submicron length scale, confinement size and interfaces can significantly impact the crystallization kinetics and resulting morphology. The ability to tune the morphology of confined polymer systems is of critical importance for the development of high-performance polymer microelectronics. The wisdom from the research on confined crystallization suggests that it would be beneficial to have a processing route in which the crystallization of polymers is driven by interface and temperature effects at a nanometer-scale confinement. In practice, for atomic and small-molecular systems, physical vapor deposition (PVD) has been recognized as the most successful processing route for the precise control of the film structure at surface utilizing confinement effects. While standard PVD technologies are not generally applicable to the deposition of the chemically fragile macromolecules, the development of matrix-assisted pulsed laser evaporation (MAPLE) now enables the non-destructive PVD of high-molecular weight polymers. In this thesis work, we investigated the use of MAPLE for the precise control of the crystallization of polymer films at a molecular level. We also sought to decipher the rules governing the crystallization of confined polymers, by using MAPLE as a tool to form confined polymer systems onto substrates with a controlled temperature. We first explored the early stages of film growth and crystallization of poly(ethylene oxide) (PEO) at the substrate surface formed by MAPLE. The unique mechanism of film formation in MAPLE, the deposition of submicron-sized polymer droplets, allowed for the manifestation of confinement and substrate effects in the crystallization of MAPLE-deposited PEO. Furthermore, we also focused on the property of the amorphous PEO film formed by MAPLE, showing the dependence of polymer crystallization kinetics on the thermal history of the amorphous phase. Lastly, we probed how MAPLE processing affected the semi-crystalline structure in MAPLE-deposited polyethylene (PE) films. Depositing PE at various temperatures remarkably allowed for the tunability of the melting temperature and crystallinity of the PE films, thus manipulating the semi-crystalline structure. By comparing the structure of PE formed by different processing routes, i.e., MAPLE and melt-crystallization, we discussed how processing routes affect the development of semi-crystalline phase in polymer films.
Monitoring the health of sugar maple, Acer saccharum

NASA Astrophysics Data System (ADS)

Carlson, Martha

The sugar maple, Acer saccharum, is projected to decline and die in 88 to 100 percent of its current range in the United States. An iconic symbol of the northeastern temperate forest and a dominant species in this forest, the sugar maple is identified as the most sensitive tree in its ecosystem to rising temperatures and a warming climate. This study measures the health of sugar maples on 12 privately owned forests and at three schools in New Hampshire. Laboratory quantitative analyses of leaves, buds and sap as well as qualitative measures of leaf and bud indicate that record high beat in 2012 stressed the sugar maple. The study identifies several laboratory and qualitative tests of health which seem most sensitive and capable of identifying stress early when intervention in forest management or public policy change might counter decline of the species. The study presents evidence of an unusual atmospheric pollution event which defoliated sugar maples in 2010. The study examines the work of citizen scientists in Forest Watch, a K-12 school program in which students monitor the impacts of ozone on white pine, Pinus strobus, another keystone species in New Hampshire's forest. Finally, the study examines three simple measurements of bud, leaf and the tree's acclimation to light. The findings of these tests illuminate findings in the first study. And they present examples of what citizen scientists might contribute to long-term monitoring of maples. A partnership between science and citizens is proposed to begin long-term monitoring and to report on the health of sugar maples.
ELF Communications System Ecological Monitoring Program: A Summary Report for 1982-1992

DTIC Science & Technology

1993-10-01

autumn- abscised alder leaves were used in the packs; since 1990, only fresh alder leaves have been used. Leaf packs were periodically retrieved and...red pine planting survival. Northern Journal of Applied Forestry, 5:14; 1988. 56. Connaughton, P. The effects of acid precipitation on nutrient levels
ROLE OF RED ALDER IN NITROGEN LOSSES FROM FORESTED WATERSHEDS IN THE OREGON COAST RANGE

EPA Science Inventory

Variations in plant community composition across the landscape may have strong impacts on nutrient losses from small forested watersheds. One extreme example of this impact is the role of the nitrogen-fixing tree, red alder, in the biogeochemistry of forested watersheds in the P...

Welcome and Reflections on Berni Alder

NASA Astrophysics Data System (ADS)

Tarter, C. Bruce

Good morning and welcome to Berni Alder's 90th Birthday Symposium. My name is Bruce Tarter and I'm representing Director Bill Goldstein, who could not be here this morning, but will be here for the afternoon session and will make comments of his own at the end of the Symposium…
WATERSHED BIOGEOCHEMISTRY IN THE OREGON COAST RANGE: THE ROLE OF RED ALDER AND SALMON

EPA Science Inventory

Variations in plant community composition across the landscape can influence nutrient retention and loss at the watershed scale. A striking example of plant species influence is the role of N2-fixing red alder (Alnus rubra) in the biogeochemistry of Pacific Northwest forests. T...
The Diels-Alder cyclization of ketenimines.

PubMed

Erb, Jeremy; Strull, Jessica; Miller, David; He, Jean; Lectka, Thomas

2012-04-20

A Diels-Alder reaction between cyclopentadiene and a variety of ketenimines is reported. A copper(I)-bis(phosphine complex catalyzes the cycloaddition across the C═N bond of the ketenimine in a [4 + 2] reaction to give an enamine intermediate that is hydrolyzed upon purification to generate aminoketones. © 2012 American Chemical Society
Red alder: A bibliography with abstracts

Treesearch

Charles F. Heebner; Mary Jane Bergener

1983-01-01

This bibliography lists 661 references to world literature through Hay 1978 containing information about red alder (Alnus rubra Bong.). Included are publications about its taxonomy, biology and silvics, chemical and physical information about its wood and fiber, studies on its nitrogen fixing properties, and reports on industrial uses and economic...
Edge-glued panels from Alaska hardwoods: retail manager perspectives

Treesearch

David Nicholls; Matthew Bumgardner; Valerie Barber

2010-01-01

In Alaska, red alder (Alnus rubra Bong.) and paper birch (Betula papyrifera Marsh.) are both lesser-known hardwoods grown, harvested, and manufactured into appearance products, with potential for increased utilization. The production of edgeglued panels from red alder and paper birch offers one expansion opportunity for wood...
A microwave assisted intramolecular-furan-Diels–Alder approach to 4-substituted indoles†

PubMed Central

Petronijevic, Filip; Timmons, Cody; Cuzzupe, Anthony; Wipf, Peter

2009-01-01

The key steps of a versatile new protocol for the convergent synthesis of 3,4-disubstituted indoles are the addition of an α-lithiated alkylaminofuran to a carbonyl compound, a microwave-accelerated intramolecular Diels–Alder cycloaddition and an in situ double aromatization reaction. PMID:19082013
Developing Biomass Equations for Western Hemlock and Red Alder Trees in Western Oregon Forests

Treesearch

Krishna Poudel; Hailemariam Temesgen

2016-01-01

Biomass estimates are required for reporting carbon, assessing feedstock availability, and assessing forest fire threat. We developed diameter- and height-based biomass equations for Western hemlock (Tsuga heterophylla (Raf.) Sarg.) and red alder (Alnus rubra Bong.) trees in Western Oregon. A system of component biomass...
A 20-year growth record for three stands of red alder.

Treesearch

Carl M. Berntsen

1962-01-01

Until very recently, only fragmentary growth information has been available for red alder (Alnus rubra). This gap has now been partially closed through the preparation of normal yield tabled based on temporary sample plot data collected in northwestern Oregon, western Washington, and southern British Columbia.
7 CFR 1437.107 - Maple sap.

Code of Federal Regulations, 2010 CFR

2010-01-01

... produced from trees that: (1) Are located on land the producer controls by ownership or lease; (2) Are... a maximum of 4 taps per tree according to the tree's diameter. (b) The crop year for maple sap... coverage in accordance with § 1437.6, tree acreage containing trees from which maple sap is produced or is...
Controlling taphole depth in maple sap production research

Treesearch

Melvin R. Koelling; Barton M. Blum

1967-01-01

Because bark thickness of sugar maple trees varies considerably, the depth of tapholes for collecting maple sap should be varied accordingly to get the taphole depth that will produce the best sap flow. A system of removable collars on the drill bit is recommended as a means of regulating taphole depth in research studies.
HOW to Identify and Control Sugar Maple Borer

Treesearch

William H. Hoffard; Philip T. Marshall

1978-01-01

The sugar maple borer, Glycobius speciosus (Say), a long-horned wood boring beetle, is a common pest of sugar maple (the only known host) throughout the range of the tree. Although borer-caused mortality is rare, infestations lead to value loss through lumber defect caused by larval galleries, discoloration, decay, and twisted grain.
Influence of demographic characteristics on production practices within the Ohio maple syrup industry

Treesearch

Gary W. Graham; P. Charles Goebel; Randall B. Heiligmann; Matthew S. Bumgardner

2007-01-01

Maple syrup production contributes approximately $5 million annually to Ohio's economy and provides supplemental nontimber forest product income for forestland owners. To better understand the factors that influence this important nontimber forest industry in Ohio, including producer heritage, producer age, sap collection methods, size of maple operation, and...
Effect of manganese on endomycorrhizal sugar maple seedlings

Treesearch

George A. Schier; Carolyn J. McQuattie

2002-01-01

Manganese (Mn) toxicity may play an important role in the poor survival of seedlings in declining sugar maple (Acer saccharum Marsh.) stands in northern Pennsylvania. To determine the effect of Mn on the growth of sugar maple seedlings, 1-year-old seedlings inoculated with vesicular-arbuscular mycorrhizal (VAM) fungi and growing in sand-vermiculite-...
Sugar maple: its characteristics and potentials

Treesearch

Ralph D. Nyland

1999-01-01

Sugar maple dominates the northern hardwood forest, but grows over a broader geographic area. Conditions of soil and climate largely limit its distribution, and account for its less continuous cover along fringes of the range. Sugar maple regenerates readily following a wide range of overstory treatments. Success depends upon its status as advance regeneration,...
Factors associated with the decline disease of sugar maple on the Allegheny Plateau

Treesearch

Stephen B. Horsley; Robert P. Long; Scott W. Bailey; Richard A. Hallett; Thomas J. Hall

2000-01-01

Mortality of sugar maple (Acer saccharum Marsh.) has reached unusually high levels across northern Pennsylvania since the early to mid-1980s. We evaluated the influence of glaciation, topographic position, foliage chemistry, defoliation history, and stand characteristics (species composition, structure, density) on the health of sugar maple in 43...
Infrared and colorimetric characterization of discolored kiln-dried hard maple lumber

Treesearch

Benjamin E. Dawson-Andoh; Michael Wiemann; Laurent Matuana; John Baumgras

2004-01-01

Discoloration of hard maple lumber commonly occurs during kiln-drying. In this study, discolored andnondiscolored kiln-dried hard maple lumber boards were characterized using a colorimetric method and Attenuated Total Reflectance-Fourier Transform Infrared Spectroscopy (ATR-FTIR). Colorimetric measurements (L*, a*, b*) were found to be in good agreement with visual...
Decay in yellow-poplar, maple, black gum, and ash in the central hardwood region

Treesearch

Frederick H. Berry

1977-01-01

In a study of decay in yellow-poplar (Liriodendron tulipifera L.), red maple (Acer rubrum L.), sugar maple (Acer saccharum Marsh.), black gum (Nyssa sylvatica Marsh.), and ash (Fraxinus spp.) in the central hardwood region, decay was found in 57 of 148 study trees. Extent of...
Comparison of oak and sugar maple distribution and regeneration in central Illinois upland oak forests

Treesearch

Peter J. Frey; Scott J. Meiners

2014-01-01

Changes in disturbance frequencies, habitat fragmentation, and other biotic pressures are allowing sugar maple (Acer saccharum) to displace oak (Quercus spp.) in the upland forest understory. The displacement of oaks by sugar maples represents a major management concern throughout the region. We collected seedling microhabitat data...
Preliminary silvicultural recommendations and an updated annotated bibliography for birdseye sugar maple

Treesearch

Don C. Bragg

2008-01-01

The birdseye grain abnormality in sugar maple can greatly enhance its commercial appeal. However, birdseye has been opportunistically exploited, without exploring management strategies that can improve its potential. Even though the initiation and development processes of birdseye maple are still largely unknown, useful silvicultural advice can still be provided for...
7 CFR 1437.107 - Maple sap.

Code of Federal Regulations, 2012 CFR

2012-01-01

... a maximum of 4 taps per tree according to the tree's diameter. (b) The crop year for maple sap... produced from trees that: (1) Are located on land the producer controls by ownership or lease; (2) Are... coverage in accordance with § 1437.6, tree acreage containing trees from which maple sap is produced or is...

7 CFR 1437.107 - Maple sap.

Code of Federal Regulations, 2013 CFR

2013-01-01

... a maximum of 4 taps per tree according to the tree's diameter. (b) The crop year for maple sap... produced from trees that: (1) Are located on land the producer controls by ownership or lease; (2) Are... coverage in accordance with § 1437.6, tree acreage containing trees from which maple sap is produced or is...
A ten-year regional assessment of sugar maple mortality

Treesearch

Douglas C. Allen; Andrew W. Molloy; Robert R. Cooke; Bruce A. Pendrel

1999-01-01

The North American Maple Project (NAMP) monitored annual sugar maple mortality from 1988 through 1997 in Maine, Massachusetts, New Brunswick/Nova Scotia, New Hampshire, New York. Ontario, Quebec, Vermont, and Wisconsin. Annual mortality in Minnesota, Ohio and Pennsylvania was evaluated for 1992 through 1997. When data from the dominant/codominant and intermediate/...
RIR-MAPLE deposition of conjugated polymers and hybrid nanocomposites for application to optoelectronic devices

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stiff-Roberts, Adrienne D.; Pate, Ryan; McCormick, Ryan

2012-07-30

Resonant infrared matrix-assisted pulsed laser evaporation (RIR-MAPLE) is a variation of pulsed laser deposition that is useful for organic-based thin films because it reduces material degradation by selective absorption of infrared radiation in the host matrix. A unique emulsion-based RIR-MAPLE approach has been developed that reduces substrate exposure to solvents and provides controlled and repeatable organic thin film deposition. In order to establish emulsion-based RIR-MAPLE as a preferred deposition technique for conjugated polymer or hybrid nanocomposite optoelectronic devices, studies have been conducted to demonstrate the value added by the approach in comparison to traditional solution-based deposition techniques, and this workmore » will be reviewed. The control of hybrid nanocomposite thin film deposition, and the photoconductivity in such materials deposited using emulsion-based RIR-MAPLE, will also be reviewed. The overall result of these studies is the demonstration of emulsion-based RIR-MAPLE as a viable option for the fabrication of conjugated polymer and hybrid nanocomposite optoelectronic devices that could yield improved device performance.« less
MAPLE deposition of nanomaterials

NASA Astrophysics Data System (ADS)

Caricato, A. P.; Arima, V.; Catalano, M.; Cesaria, M.; Cozzoli, P. D.; Martino, M.; Taurino, A.; Rella, R.; Scarfiello, R.; Tunno, T.; Zacheo, A.

2014-05-01

The matrix-assisted pulsed laser evaporation (MAPLE) has been recently exploited for depositing films of nanomaterials by combining the advantages of colloidal inorganic nanoparticles and laser-based techniques. MAPLE-deposition of nanomaterials meeting applicative purposes demands their peculiar properties to be taken into account while planning depositions to guarantee a congruent transfer (in terms of crystal structure and geometric features) and explain the deposition outcome. In particular, since nanofluids can enhance thermal conductivity with respect to conventional fluids, laser-induced heating can induce different ablation thermal regimes as compared to the MAPLE-treatment of soft materials. Moreover, nanoparticles exhibit lower melting temperatures and can experience pre-melting phenomena as compared to their bulk counterparts, which could easily induce shape and or crystal phase modification of the material to be deposited even at very low fluences. In this complex scenario, this review paper focuses on examples of MAPLE-depositions of size and shape controlled nanoparticles for different applications highlights advantages and challenges of the MAPLE-technique. The influence of the deposition parameters on the physical mechanisms which govern the deposition process is discussed.
Molecular weight dependent structure and charge transport in MAPLE-deposited poly(3-hexylthiophene) thin films

DOE PAGES

Dong, Ban Xuan; Smith, Mitchell; Strzalka, Joseph; ...

2018-02-06

In this work, poly(3-hexylthiophene) (P3HT) films prepared using the matrix-assisted pulsed laser evaporation (MAPLE) technique are shown to possess morphological structures that are dependent on molecular weight (MW). Specifically, the structures of low MW samples of MAPLE-deposited film are composed of crystallites/aggregates embedded within highly disordered environments, whereas those of high MW samples are composed of aggregated domains connected by long polymer chains. Additionally, the crystallite size along the side-chain (100) direction decreases, whereas the conjugation length increases with increasing molecular weight. This is qualitatively similar to the structure of spin-cast films, though the MAPLE-deposited films are more disordered. In-planemore » carrier mobilities in the MAPLE-deposited samples increase with MW, consistent with the notion that longer chains bridge adjacent aggregated domains thereby facilitating more effective charge transport. The carrier mobilities in the MAPLE-deposited simples are consistently lower than those in the solvent-cast samples for all molecular weights, consistent with the shorter conjugation length in samples prepared by this deposition technique.« less
Molecular weight dependent structure and charge transport in MAPLE-deposited poly(3-hexylthiophene) thin films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dong, Ban Xuan; Smith, Mitchell; Strzalka, Joseph

In this work, poly(3-hexylthiophene) (P3HT) films prepared using the matrix-assisted pulsed laser evaporation (MAPLE) technique are shown to possess morphological structures that are dependent on molecular weight (MW). Specifically, the structures of low MW samples of MAPLE-deposited film are composed of crystallites/aggregates embedded within highly disordered environments, whereas those of high MW samples are composed of aggregated domains connected by long polymer chains. Additionally, the crystallite size along the side-chain (100) direction decreases, whereas the conjugation length increases with increasing molecular weight. This is qualitatively similar to the structure of spin-cast films, though the MAPLE-deposited films are more disordered. In-planemore » carrier mobilities in the MAPLE-deposited samples increase with MW, consistent with the notion that longer chains bridge adjacent aggregated domains thereby facilitating more effective charge transport. The carrier mobilities in the MAPLE-deposited simples are consistently lower than those in the solvent-cast samples for all molecular weights, consistent with the shorter conjugation length in samples prepared by this deposition technique.« less
Quantification of metal loading to Silver Creek through the Silver Maple Claims area, Park City, Utah, May 2002

USGS Publications Warehouse

Kimball, Briant A.; Johnson, Kevin K.; Runkel, Robert L.; Steiger, Judy I.

2004-01-01

The Silver Maple Claims area along Silver Creek, near Park City, Utah, is administered by the Bureau of Land Management. To quantify possible sources of elevated zinc concentrations in Silver Creek that exceed water-quality standards, the U.S. Geological Survey conducted a mass-loading study in May 2002 along a 1,400-meter reach of Silver Creek that included the Silver Maple Claims area. Additional samples were collected upstream and downstream from the injection reach to investigate other possible sources of zinc and other metals to the stream. Many metals were investigated in the study, but zinc is of particular concern for water-quality standards. The total loading of zinc along the study reach from Park City to Wanship, Utah, was about 49 kilograms per day. The Silver Maple Claims area contributed about 38 percent of this load. The Silver Creek tailings discharge pipe, which empties just inside the Silver Maple Claims area, contributed more than half the load of the Silver Maple Claims area. Substantial zinc loads also were added to Silver Creek downstream from the Silver Maple Claims area. Ground-water discharge upstream from the waste-water treatment plant contributed 20 percent of the total zinc load, and another 17 percent was contributed near the waste-water treatment plant. By identifying the specific areas where zinc and other metal loads are contributed to Silver Creek, it is possible to assess the needs of a remediation plan. For example, removing the tailings from the Silver Maple Claims area could contribute to lowering the zinc concentration in Silver Creek, but without also addressing the loading from the Silver Creek tailings discharge pipe and the ground-water discharge farther downstream, the zinc concentration could not be lowered enough to meet water-quality standards. Additional existing sources of zinc loading downstream from the Silver Maple Claims area could complicate the process of lowering zinc concentration to meet water-quality standards.
Estimating the number of trees and forest area necessary to supply internationally traded volumes of big-leaf mahogany (Swietenia macrophylla) in Amazonia

Treesearch

J. Grogan; M. Schulze

2008-01-01

requires producer nations to certify that exported supplies were obtained in a manner non-detrimental to the speciesâ survival in its role in the ecosystem. Non-detriment findings based on annual export quotas should verify that current harvest rates are sustainable with respect to total commercial stocks. In order to assess this impact, a method for converting export...
Red oak in southern New England and big-leaf mahogany in the Yucatan Peninsula: can mixed-species forests be sustainably managed for single-species production?

Treesearch

M. Kelty; L. Camara-Cabrales; J. Grogan

2011-01-01

Complex mixed-species forests are the focus of conservation efforts that seek to maintain native biodiversity. However, much of this forestland is privately owned and is managed for timber income as well as for conservation. Management of these high-diversity forests is particularly difficult when only one tree species produces the majority of high-value timber. We...
Potential of fluorescence spectroscopy for the characterisation of maple syrup flavours.

PubMed

Panneton, Bernard; Clément, Alain; Lagacé, Luc

2013-10-01

Maple syrup has high maket value. It is produced in North East America from the heat-evaporated sap of Acer saccharum Marshall. For marketing purposes, there is interest in defining its flavour profile in a consistent and repeatable manner. An experiment was undertaken to explore the potential of autofluorescence of maple syrup induced at 275 and 360 nm to characterise flavours. A mixed data factor analysis revealed two independent groups of variables. One represents early season woody and late season empyreumatic flavours. The other is related to off-flavour, confectionery and maple flavours. Maple and confectionery flavours are subtle, difficult to distinguish and opposed to off-flavour. There were clear relationships among the two groups and fluorescence profiles. For each of the five basic flavours, discriminant models based on partial least squares regressions were developed. For each sample of syrup, flavours combined to form flavour profiles, and the results from the five discriminant models were aggregated to reproduce these profiles. For excitation at 275 nm, the woody/off-flavour and confectionery/empyreumatic/maple flavour profiles were classified correctly 86 and 78% of the time (cross-validation) respectively. Induced autofluorescence spectra were shown to contain information related to maple syrup flavours. This fluorescence-flavour relationship is not considered quantitative yet, and further research avenues are proposed. © 2013 Society of Chemical Industry.
A computational study of the Diels-Alder reactions between 2,3-dibromo-1,3-butadiene and maleic anhydride

NASA Astrophysics Data System (ADS)

Rivero, Uxía; Meuwly, Markus; Willitsch, Stefan

2017-09-01

The neutral and cationic Diels-Alder-type reactions between 2,3-dibromo-1,3-butadiene and maleic anhydride have been computationally explored as the first step of a combined experimental and theoretical study. Density functional theory calculations show that the neutral reaction is concerted while the cationic reaction can be either concerted or stepwise. Further isomerizations of the Diels-Alder products have been studied in order to predict possible fragmentation pathways in gas-phase experiments. Rice-Ramsperger-Kassel-Marcus (RRKM) calculations suggest that under single-collision experimental conditions the neutral product may reform the reactants and the cationic product will most likely eliminate CO2.
Nitropyrroles, Diels-Alder reactions assisted by microwave irradiation and solvent effect. An experimental and theoretical study

NASA Astrophysics Data System (ADS)

Mancini, Pedro M. E.; Kneeteman, María N.; Cainelli, Mauro; Ormachea, Carla M.; Domingo, Luis R.

2017-11-01

The behaviors of N-tosylnitropyrroles acting as electrophilic dienophiles in polar Diels-Alder reactions joint to different dienes of increeased nucleophilicity are analyzed. The reactions were developed under microwave irradiation using toluene or protic ionic liquids (PILs) as solvents and in free solvent conditions. In all the cases explored we observed good yields in short reaction times. For these reactions, the free solvent condition and the use of protic ionic liquids as solvents offer similar results. However, the free solvent conditions favor environmental sustainability. The role of PILs in these polar Diels-Alder reactions has been theoretically studied within the Molecular Electron Density Theory.
Seasonal variation in concentrations of fiber, crude protein, and phenolic compounds in leaves of red alder (Alnus rubra): Nutritional implications for cervids

USGS Publications Warehouse

Gonzalez-Hernandez, M. P.; Starkey, Edward E.; Karchesy, J.

2000-01-01

We sought to determine whether changes in chemical composition could be a factor in increased utilization of red alder (Alnus rubra) by the two cervids, the Columbian black-tailed deer (Odocoileus hemionus columbianus) and Roosevelt elk (Cervus elaphus roosevelti), during the fall in parts of the Douglas fir region of the Pacific Northwest. We found that concentrations and astringency of phenolic compounds decreased from spring through fall, while crude protein content remained high. We conclude that red alder leaves provide a significant source of digestible protein for cervids during fall, when availability of nutrients in most forage species is generally declining.
Tandem enyne metathesis-Diels-Alder reaction for construction of natural product frameworks.

PubMed

Rosillo, Marta; Domínguez, Gema; Casarrubios, Luis; Amador, Ulises; Pérez-Castells, Javier

2004-03-19

Enynes connected through aromatic rings are used as substrates for metathesis reactions. The reactivity of three ruthenium carbene complexes is compared. The resulting 1,3-dienes are suitable precursors of polycyclic structures via a Diels-Alder process. Some domino RCM-Diels-Alder reactions are performed, suggesting a possible beneficial effect of the ruthenium catalyst in the cycloaddition process. Other examples require Lewis acid cocatalyst. When applied to aromatic ynamines or enamines, a new synthesis of vinylindoles is achieved. Monitorization of several metathesis reactions with NMR shows the different behavior for ruthenium catalysts. New carbenic species are detected in some reactions with an important dependence on the solvent used.
Sapstreak disease of sugar maple

Treesearch

James W. Walters

1992-01-01

Sapstreak is a fatal disease of sugar maple that usually enters the tree through basal trunk scars or root wounds. The disease most often affects large, wounded trees left after logging. The fungus causing sapstreak readily infects stumps or cut logs during the summer months. So, wounding sugar maples during this time will increase the potential for disease spread. In...
Monitoring the Health of Sugar Maple, "Acer Saccharum"

ERIC Educational Resources Information Center

Carlson, Martha

2013-01-01

The sugar maple, "Acer saccharum," is projected to decline and die in 88 to 100 percent of its current range in the United States. An iconic symbol of the northeastern temperate forest and a dominant species in this forest, the sugar maple is identified as the most sensitive tree in its ecosystem to rising temperatures and a warming…
Passive Maple-Seed Robotic Fliers for Education, Research and Entrepreneurship

ERIC Educational Resources Information Center

Aslam, D. M.; Abu-Ageel, A.; Alfatlawi, M.; Varney, M. W.; Thompson, C. M.; Aslam, S. K.

2014-01-01

As inspirations from flora and fauna have led to many advances in modern technology, the concept of drawing ideas from nature for design should be reflected in engineering education. This paper focuses on a maple-seed robotic flier (MRF) with various complexities, a robotic platform modeled after the samaras of maple or ash trees, to teach STEM…
History of sugar maple decline

Treesearch

David R. Houston

1999-01-01

Only a few episodes of sugar maple dieback or decline were recorded during the first half of the 20th Century. In contrast, the last 50 years have provided numerous reports of both urban and forest dieback/decline. In the late 1950s, a defoliation-triggered decline, termed maple blight, that occurred in Wisconsin prompted the first comprehensive, multidisciplinary...
The cost of maple sugaring in Vermont

Treesearch

Paul E. Sendak; John P. Bennink; John P. Bennink

1985-01-01

An annual maple syrup production cost series was developed for the period 1972 to 1984. Comparisons were made between plastic tubing and metal bucket technology and wood- and oil-fired evaporation. The effects of sap- sugar content and size of operation were examined together with the relationships among major cost items. The information will be useful to maple syrup...
Optimum drying temperature to prevent oxidative stain in soft maple

Treesearch

Michael C. Wiemann; Mark Knaebe; Scott A. Bowe

2011-01-01

The objective of this paper is to determine the kiln conditions necessary to avoid interior enzymatic oxidative discoloration in soft maple. Three drying chambers were designed and constructed to control temperature and relative humidity of maple test samples. The tests showed that drying as soon as possible after harvest at temperatures below 42°C will...

Characterization of Nanostructured Polymer Films

DTIC Science & Technology

2014-12-23

discovered that polymer films with exceptional thermal and kinetic stability could be formed by Matrix Assisted Pulsed Laser Evaporation ( MAPLE ) onto...thermal properties of amorphous polymer nanoglobules fabricated via Matrix-Assisted Pulsed Laser Deposition ( MAPLE ). We discovered that stability in... MAPLE , Glass Transition Temperature 16. SECURITY CLASSIFICATION OF: 17. LIMITATION OF ABSTRACT 18. NUMBER OF PAGES 19a. NAME OF RESPONSIBLE PERSON
Some effects of forest preservation

Treesearch

William B. Leak

1974-01-01

Long-term preservation (no cutting) of a deciduous forest stand in New Hampshire is leading toward stable populations of beech, sugar maple, striped maple, mountain maple, and hobblebush, coupled with a decline or complete disappearance of other woody species. The humus has stabilized at a depth no greater than that of cut stands. Nitrate discharge in the streams is...
A Stocking Guide for Allegheny Hardwoods and Its Use in Controlling Intermediate Cuttings

Treesearch

Benjamin A. Roach

1977-01-01

A stocking guide for stands of Allegheny hardwoods (sugar maple or sugar maple-beech with varying admixtures of black cherry, red maple, white ash, sweet birch, and other species) on the Allegheny Plateau in northwestern Pennsylvania. Included are procedures for evaluating stocking and stand conditions, thinning even-aged stands, determining minimum residual stocking,...
Survival of striped maple following spring prescribed fires in pennsylvania

Treesearch

Patrick H. Brose; Gary W. Miller; Kurt W. Gottschalk

2007-01-01

Survival of striped maple (Acer pensylvanicum L.) was assessed after three spring prescribed fires in Pennsylvania mixed oak (Quercus spp.) stands. Portions of two stands were prescribe-burned in spring 2002 and the part of a third in spring 2004. Following the fires, each stand was divided into burned and unburned units. Striped maple sapling...
History and range of Norway maple

Treesearch

David J. Nowak; Rowan A. Rowntree

1990-01-01

The Norway maple, Acer platanoldes, was introduced into the United States about 1756 after being cultivated in England since 1683. This species remained in relative obscurity in the U.S. until the mid- to late-1800's, but is now one of the most popular urban trees. In certain regions of the United States, Norway maples dominate street tree...
MAPLE: reflected light from exoplanets with a 50-cm diameter stratospheric balloon telescope

NASA Astrophysics Data System (ADS)

Marois, Christian; Bradley, Colin; Pazder, John; Nash, Reston; Metchev, Stanimir; Grandmont, Frédéric; Maire, Anne-Lise; Belikov, Ruslan; Macintosh, Bruce; Currie, Thayne; Galicher, Raphaël.; Marchis, Franck; Mawet, Dimitri; Serabyn, Eugene; Steinbring, Eric

2014-08-01

Detecting light reflected from exoplanets by direct imaging is the next major milestone in the search for, and characterization of, an Earth twin. Due to the high-risk and cost associated with satellites and limitations imposed by the atmosphere for ground-based instruments, we propose a bottom-up approach to reach that ultimate goal with an endeavor named MAPLE. MAPLE first project is a stratospheric balloon experiment called MAPLE-50. MAPLE-50 consists of a 50 cm diameter off-axis telescope working in the near-UV. The advantages of the near-UV are a small inner working angle and an improved contrast for blue planets. Along with the sophisticated tracking system to mitigate balloon pointing errors, MAPLE-50 will have a deformable mirror, a vortex coronograph, and a self-coherent camera as a focal plane wavefront-sensor which employs an Electron Multiplying CCD (EMCCD) as the science detector. The EMCCD will allow photon counting at kHz rates, thereby closely tracking telescope and instrument-bench-induced aberrations as they evolve with time. In addition, the EMCCD will acquire the science data with almost no read noise penalty. To mitigate risk and lower costs, MAPLE-50 will at first have a single optical channel with a minimum of moving parts. The goal is to reach a few times 109 contrast in 25 h worth of flying time, allowing direct detection of Jovians around the nearest stars. Once the 50 cm infrastructure has been validated, the telescope diameter will then be increased to a 1.5 m diameter (MAPLE-150) to reach 1010 contrast and have the capability to image another Earth.
Chemical composition and deer browsing of red alder foliage

Treesearch

M.A. Radwan; W.D. Ellis; G.L. Crouch

1978-01-01

Chemical factors suspected of influencing seasonal change in deer preference for red alder leaves were investigated. There were many differences in the leaves between seasons. It is postulated, however, that changes in contents of crude fat and total phenols were the important factors in increasing deer preference for the species from June to September.
Maintaining cultures of wood-rotting fungi.

Treesearch

E.E. Nelson; H.A. Fay

1985-01-01

Phellinus weirii cultures were stored successfully for 10 years in small alder (Alnus rubra Bong.) disks at 2 Â°C. The six isolates tested appeared morphologically identical and after 10 years varied little in growth rate from those stored on malt agar slants. Long-term storage on alder disks reduces the time required for...
ADVANCED INTRAMOLECULAR DIELS-ALDER STUDY TOWARD THE SYNTHESIS OF (-)-MORPHINE: STRUCTURE CORRECTION OF A PREVIOUSLY REPORTED DIELS-ALDER PRODUCT. (R826113)

EPA Science Inventory

The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Concl...
NITROGEN EXPORT FROM FORESTED WATERSHEDS IN THE OREGON COAST RANGE: THE ROLE OF N2-FIXING RED ALDER

EPA Science Inventory

Variations in plant community composition across the landscape can influence nutrient retention and loss at the watershed scale. A striking example of plant species influence is the role of N2-fixing red alder (Alnus rubra) in the biogeochemistry of Pacific Northwest forests. T...
Ecology payoffs from red alder in southeast Alaska.

Treesearch

Sally Duncan

2004-01-01

Clearcutting has been the primary timber management practice in southeast Alaska forests since large-scale commercial forestry began in the 1950s. The dense, even-aged conifer stands that subsequently develop, however, may have undesirable consequences for some nontimber resources, most notably fish and wildlife.Red alder is frequently established in these...
Taper equation and volume tables for plantation-grown red alder.

Treesearch

Andrew A. Bluhm; Sean M. Garber; David E. Hibbs

2007-01-01

A taper equation and associated tables are presented for red alder (Alnus rubra Bong.) trees grown in plantations. The data were gathered from variable-density experimental plantations throughout the Pacific Northwest. Diameter inside bark along the stem was fitted to a variable exponent model form by using generalized nonlinear least squares and a...
Occurrence, structure, and function of the nitrogen-fixing microsymbiont Frankia from nodules of Arizona alder [Abstract

Treesearch

J. O. Dawson; G. J. Gottfried; D. Hahn

2005-01-01

Actinorhizal plants are nodulated by the symbiotic, nitrogen-fixing actinomycete Frankia. The genus Alnus in the family Betulaceae is one of the 25 genera in 8 families of angiospermous plants that are actinorhizal. Arizona alder (Alnus oblongifolia Torr.) occurs in isolated populations associated with the...
Consumer preferences for kitchen cabinets made from red alder: a comparison to other hardwoods.

Treesearch

David L. Nicholls; Geoffrey H. Donovan; Joseph Roos

2004-01-01

In Alaska, red alder (Alnus rubra Bong.) is an abundant but commercially underutilized species despite having properties suitable for higher value products, including furniture and cabinetry. However, it laces the name recognition of mote traditional hardwoods. Our research measured the effect of this lack of familiarity on consumer preferences...
N2 fixing alder (Alnus viridis spp.fruticosa) effects on soil properties across a secondary successional chronosequence in interior Alaska

Treesearch

Jennifer S. Mitchell; Roger W. Ruess

2009-01-01

Green alder (Alnus viridis ssp. fruticosa) is a dominant understory shrub during secondary successional development of upland forests throughout interior Alaska, where it contributes substantially to the nitrogen (N) economy through atmospheric N2 fixation. Across a replicated 200+ year old vegetation...
Level of endogenous formaldehyde in maple syrup as determined by spectrofluorimetry.

PubMed

Lagacé, Luc; Guay, Stéphane; Martin, Nathalie

2003-01-01

The level of endogenous formaldehyde in maple syrup was established from a large number (n = 300) of authentic maple syrup samples collected during 2000 and 2001 in the province of Quebec, Canada. The average level of formaldehyde from these authentic samples was measured at 0.18 mg/kg in 2000 and 0.28 mg/kg in 2001, which is lower than previously published. These average values can be attributed to the improved spectrofluorimetric method used for the determination. However, the formaldehyde values obtained demonstrate a relatively large distribution with maximums observed at 1.04 and 1.54 mg/kg. These values are still under the maximum tolerance level of 2.0 mg/kg paraformaldehyde pesticide residue. Extensive heat treatment of maple syrup samples greatly enhanced the formaldehyde concentration of the samples, suggesting that extensive heat degradation of the sap constituents during evaporation could be responsible for the highest formaldehyde values in maple syrup.
Computational Insights into an Enzyme-Catalyzed [4+2] Cycloaddition

PubMed Central

2017-01-01

The enzyme SpnF, involved in the biosynthesis of spinosyn A, catalyzes a formal [4+2] cycloaddition of a 22-membered macrolactone, which may proceed as a concerted [4+2] Diels–Alder reaction or a stepwise [6+4] cycloaddition followed by a Cope rearrangement. Quantum mechanics/molecular mechanics (QM/MM) calculations combined with free energy simulations show that the Diels–Alder pathway is favored in the enzyme environment. OM2/CHARMM free energy simulations for the SpnF-catalyzed reaction predict a free energy barrier of 22 kcal/mol for the concerted Diels–Alder process and provide no evidence of a competitive stepwise pathway. Compared with the gas phase, the enzyme lowers the Diels–Alder barrier significantly, consistent with experimental observations. Inspection of the optimized geometries indicates that the enzyme may prearrange the substrate within the active site to accelerate the [4+2] cycloaddition and impede the [6+4] cycloaddition through interactions with active-site residues. Judging from partial charge analysis, we find that the hydrogen bond between the Thr196 residue of SpnF and the substrate C15 carbonyl group contributes to the enhancement of the rate of the Diels–Alder reaction. QM/MM simulations show that the substrate can easily adopt a reactive conformation in the active site of SpnF because interconversion between the C5–C6 s-trans and s-cis conformers is facile. Our QM/MM study suggests that the enzyme SpnF does behave as a Diels-Alderase. PMID:29131960
Mixed, short rotation culture of red alder and black cottonwood: growth, coppicing, nitrogen fixation, and allelopathy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Heilman, P.; Stettler, R.F.

1985-01-01

Alnus rubra seedlings were grown in a 1:1 mixture at a spacing of 1.2 x 1.2 m with 28 Populus clones (25 clones pf P. trichocarpa, 2 of P. deltoides x P. trichocarpa, and one P. deltoides x P. nigra) in a study established in W. Washington in March 1979. Trees were harvested at 4 yr old. At harvest, average heights were: pure Populus, 10.2 m; Populus in the mixed stand 11.0 m; and alder 8.4 m. Most Populus sprouted satisfactorily after harvest (6.6 shoots/plant when pure, 7.6 shoots/plant in the mixture), but alder sprouted poorly (3.6 shoots/plant). Above-ground biomassmore » at harvest was 15.9 t/ha p.a. for the mixture and 16.7 t/ha p.a. for pure Populus, although the mixture had been more productive at 2 yr. Nitrogenase activity (nitrogen fixation as measured by acetylene reduction) of alder declines in the 4th season; competition was the most important factor influencing this decline. Soil N content had no effect on fixation. A pot study showed that ground Populus leaf and litter material inhibited the growth of red alder seedlings, although soil collected from Populus plots had no effect. Results indicated that allelopathy is probably a minor factor under field conditions, at most, and that growing mixed stands may, on balance, be beneficial. 20 references.« less
N2-fixing red alder indirectly accelerates ecosystem nitrogen cycling

USGS Publications Warehouse

Perakis, Steven S.; Matkins, Joselin J.; Hibbs, David E.

2012-01-01

Symbiotic N2-fixing tree species can accelerate ecosystem N dynamics through decomposition via direct pathways by producing readily decomposed leaf litter and increasing N supply to decomposers, as well as via indirect pathways by increasing tissue and detrital N in non-fixing vegetation. To evaluate the relative importance of these pathways, we compared three-year decomposition and N dynamics of N2-fixing red alder leaf litter (2.34 %N) to both low-N (0.68 %N) and high-N (1.21 %N) litter of non-fixing Douglas-fir, and decomposed each litter source in four forests dominated by either red alder or Douglas-fir. We also used experimental N fertilization of decomposition plots to assess elevated N availability as a potential mechanism of N2-fixer effects on litter mass loss and N dynamics. Direct effects of N2-fixing red alder on decomposition occurred primarily as faster N release from red alder than Douglas-fir litter, but direct increases in N supply to decomposers via fertilization did not stimulate decomposition of any litter. Fixed N indirectly influenced detrital dynamics by increasing Douglas-fir tissue and litter N concentrations, which accelerated litter N release without accelerating mass loss. By increasing soil N, tissue N, and the rate of N release from litter of non-fixers, we conclude that N2-fixing vegetation can indirectly foster plant-soil feedbacks that contribute to the persistence of elevated N availability in terrestrial ecosystems.
Ray tissues as an indirect measure of relative sap-sugar concentration in sugar maple

Treesearch

Peter W. Garrett; Kenneth R. Dudzik; Kenneth R. Dudzik

1989-01-01

Attempts to correlate ray tissue as a percentage of total wood volume with sap-sugar concentrations of sugar maple progenies were unsuccessful. These results raise doubts about our ability to use a relatively constant value such as ray-tissue volume in a selection program designed to increase the sap-sugar concentration of sugar maple seedlings.

Chapter 8:Properties of red maple laminated veneer lumber

Treesearch

Robert J. Ross; Xiping Wang; Brian K. Brashaw; John W. Forsman; John R. Erickson

2005-01-01

The purpose of the work reported in this chapter was to examine the flexural properties of LVL manufactured from ultrasonically rated red maple veneer sheets. The specific objectives were: 1. to determine the flatwise and edgewise bending properties of Â½ inch-(1.3-cm-) thick red maple LVL billets, and 2. to examine the relationship between nondestructive parameters of...
Influence of nutrition and stress on sugar maple at a regional scale

Treesearch

Richard A. Hallett; Scott W. Bailey; Stephen B. Horsley; Robert P. Long

2006-01-01

Sugar maple (Acer saccharum Marsh.) decline disease on the Allegheny Plateau (region 1) resulted in high levels of mortality during the 1990s. Sugar maple was predisposed to decline because of an imbalance in Mg, Ca, and Mn nutrition and incited to decline by repeated defoliation. We sampled 33 stands in New York, Vermont, and New Hampshire (region 2...
Exploring methods for prevention of oxidative stain in soft maple

Treesearch

Michael C. Wiemann; Richard D. Bergman; Mark Knaebe; Scott A. Bowe

2009-01-01

Interior gray enzymatic oxidative stain for white woods such as maple has plagued the wood industry for many years because methods that have been found to reduce stain are hard to scale up to industrial levels. We examined possible alternative treatments to eliminate stain in soft maple (Acer rubrum L.), and found that exposure to sulfur dioxide gas eliminates interior...
Maturation of sugar maple seed

Treesearch

Clayton M., Jr. Carl; Albert G., Jr. Snow; Albert G. Snow

1971-01-01

The seeds of a sugar maple tree (Acer saccharum Marsh.) do not mature at the same time every year. And different trees mature their seeds at different times. So time of year is not a reliable measure of when seeds are ripe. Better criteria are needed. In recent studies we have found that moisture content and color are the best criteria for judging when sugar maple...
Long-term impact of liming on growth and vigor of northern hardwoods

Treesearch

Robert P. Long; Stephen B. Horsley; Thomas J. Hall

2011-01-01

Sugar maple (Acer saccharum Marsh.) is a keystone species in the northern hardwood forest, and decline episodes have negatively affected the growth and health of sugar maple in portions of its range over the past 50+ years. Crown health, growth, survival, and flower and seed production of sugar maple were negatively affected by a widespread decline...
A sugar maple planting study in Vermont

Treesearch

Harry W. Yawney; Clayton M., Jr. Carl; Clayton M. Carl

1970-01-01

Past attempts to establish sugar maple (Acer saccharum Marsh.) by planting have generally met with little success. The failures have been blamed mainly on competition by other vegetation and on damage done by animals. Finding an effective way to establish sugar maple seedlings is a key part in the research being carried on in Vermont by the USDA Forest Service to...
Effects of defoliation and drought on root food reserves in sugar maple seedlings

Treesearch

Johnson Parker; Johnson Parker

1970-01-01

The artificial defoliation of sugar maple (Acer. saccharum Marsh.) can cause a marked decline in root food reserves, especially starch, and an increase in the levels of the reducing sugars, fructose and glucose. Defoliation can also bring on the dieback-decline syndrome in sugar maples (Parker and Houston 1968). Two experiments designed to examine this question were...
The Influence of Residual Stand Densities on Regeneration in Sugar Maple Stands

Treesearch

Carl H. Tubbs

1968-01-01

Studies of regeneration 2, 5, and 10 years after cutting mature and overmature sugar maple stands to several residual densities show that (1) sugar maple is still the predominant species under all stand densities (2) nearly all regeneration reaching larger size classes became established before cutting (3) heavier cuttings (30, 50, and 70 square feet) are more rapidly...
Phenology and recruitment of Ohio buckeye and sugar maple in Illinois forest stands

Treesearch

Michelle Henderson; Jeffery O. Dawson; Evan H. DeLucia

1993-01-01

Phenological patterns, light conditions, and photosynthetic activity of Ohio buckeye and sugar maple foliage on trees in the forest understory were monitored and compared over two growing seasons in two mesophytic upland woodlands in central Illinois. Ohio buckeye began leaf expansion three to four weeks earlier than sugar maple, started leaf senescence and shedding in...
Sugar maple: abundance and site relationships in the pre- and post- settlement forest

Treesearch

Gordon G. Whitney

1999-01-01

A review of the available historical evidence provides a picture of sugar maple's site relationstiips in the presettlement forest and its changing statis over the last 300 years. Sugar maple was widely distributed throughout the Northeast during the presettlerment period. it was particularly abundant on the richer, better drained, silt-rich sites. A comparison of...
Shrinkage and footage loss from drying 4/4-inch hard maple lumber.

Treesearch

Daniel E. Dunmire

1968-01-01

Equations are presented for estimating shrinkage and resulting footage losses due to drying hard maple lumber. The equations, based on board shrinkage data taken from a representative lumber sample, are chiefly intended for use with lots of hard maple lumber, such as carloads, truckloads, or kiln loads, but also can be used for estimating the average shrinkage of...
Red maple development in mixed hardwood stands in West Virginia

Treesearch

Brian Tift

1997-01-01

Recent evidence has shown that red maple (Acer rubrum) may become a more prominent species in eastern mixed hardwood stands. This study will examine the strategies used by red maple to reach dominant and codominant canopy positions on two different stands (one mesic and one drier). Stand level data such as dbh, height, crown class, height class, and...
Crown releasing of red maple poles to shorten high-quality sawlog rotations

Treesearch

Gayne G. Erdmann; Ralph M., Jr. Peterson; Robert R. Orberg

1985-01-01

The effects of six crown-release treatments on growth and bole quality development of 54-year-old dominant, codominant, and intermediate red maples (Acer rubrum L.) were evaluated on a good red maple site (site index = 19.3 mat 50 years) in upper Michigan. Results showed that crown release stimulated the growth of dominants, codominants, and strong...
An Assessment of the Red Maple Resource in the Northeastern United States

Treesearch

Delton R., Jr. Alderman; Matthew S. Bumgardner; John E. Baumgras; John E. Baumgras

2005-01-01

The red maple resource in the northeastern United States has exhibited dramatic gains in the past 3 decades in terms of stem numbers and net volume. Growing stock and sawtimber volumes have displayed extraordinary growth compared to other species, and red maple is replacing important market species that have historically been used in the Northeast. The increase in red...
Maple sugaring with vacuum pumping during the fall season

Treesearch

H. Clay Smith; Alan G., Jr. Snow

1971-01-01

Vacuum pumping of sugar maple trees during the late fall and early winter months is not advisable in northern Vermont. However, fall pumping may be profitable in other areas of the sugar maple range. It is recommended that the weather pattern in a given locale be observed; and if conditions are favorable, vacuum pumping should be tried on a small scale before...
Adaptation of sugar maple populations along altitudinal gradients: photosynthesis, respiration, and specific leaf weight

Treesearch

F. Thomas Ledig; Donald R. Korbobo

1983-01-01

Sugar maple seeds were collected from populations spaced along two altitudinal gradients in the White Mountains of New Hampshire. When grown in a uniform environment, progeny of stands less than 0.8 km apart differed significantly in photosynthesis, respiration, and leaf characteristics, despite a lack of physical barriers to gene migration. Sugar maple is a long-lived...
Nitrous oxide fluxes from tree stems of temperate forests

NASA Astrophysics Data System (ADS)

Wen, Yuan; Corre, Marife D.; Rachow, Christine; Veldkamp, Edzo

2017-04-01

Although trees are recognized as conduits of soil-generated N2O, little is known about N2O fluxes from mature trees under field conditions and thier contributions to total forest N2O fluxes. Here, we quantified in situ stem N2O fluxes from mature alder trees on poorly-drained soil and mature beech and spruce trees on well-drained soils in Solling, Germany from March to October 2015. Soil N2O fluxes, soil N2O concentrations at 40-cm depth, and soil and climatic variables known to influence N2O fluxes were also measured concurrently with the stem N2O fluxes. Alder, beech and spruce consistently emitted N2O via stems and all displayed higher emission rates in summer than in spring and in autumn. Stem N2O fluxes from alder stand were higher than those from beech and spruce stands (P < 0.01), which was attributed to the presence of aerenchyma and lenticels as well as higher soil water content and soil C and N availability in the alder stand (P < 0.01-0.05). The correlations of stem N2O fluxes from alder with soil N2O fluxes, soil N2O concentrations, soil and air temperature and vapor pressure deficit (R = 0.60 - 0.90, P < 0.01-0.05) suggest that N2O transport in alder was facilitated by a combination of passive gas diffusion through aerenchyma and active transport of dissolved N2O through sap flow. In the beech and spruce stands, correlations of stem N2O fluxes with soil and air temperature and vapor pressure deficit (R = 0.57 - 0.78, P < 0.01-0.07) suggest that active transport of dissolved N2O via xylem sap was the major mechanism for stem N2O emissions in upland trees. Stem N2O fluxes represented 8-11% of the total (soil + stem) N2O fluxes in the spruce and beech stands whereas in the alder stand, with its large soil N2O emission, stem emission contributed only 1% of the total flux. Our results suggest that the relative contribution of tree-mediated N2O fluxes is more important in upland trees than in wetland trees.
Hourly pattern of allergenic alder and birch pollen concentrations in the air: Spatial differentiation and the effect of meteorological conditions

NASA Astrophysics Data System (ADS)

Borycka, K.; Kasprzyk, I.

2018-06-01

In temperate climate widespread alder and birch are an important source of strong aeroallergens. The diurnal pattern of airborne pollen concentrations depends on the rhythm of pollen release from anthers as well as weather conditions, convection air currents, long-distance transport, pollen trap location and local vegetation. The aim of the study was to present a diurnal pattern of Alnus (alder) and Betula (birch) pollen concentrations in the air in a horizontal and vertical gradient and examine the weather parameters that had the greatest impact on the pattern. The study was conducted in Rzeszów City, southeast Poland over three years. Pollen grains were collected using a Hirst volumetric spore trap at three sampling points: two at 12 m the agl, and one at 1.5 m agl. Data were analysed using circular statistics and a nonlinear function. For alder, three models of hourly patterns were elaborated and the most common presented early morning minimum and early afternoon maximum. For birch, the most common model has one peak at night and a marked decrease in concentrations in early morning, although a second model has peak during early afternoon. A model with 3 peaks is much less common. These models are characteristic for warm temperate climate regions, where alders and birches are common. The diurnal patterns did not depend on the localization of traps or proximity of the pollen source, although these factors influenced the hourly concentrations, with higher values observed at roof level. Significant relationships between the hourly pollen counts and meteorological parameters were observed only for alder. Three incidents of increasing birch pollen concentrations were observed during the first two hours of precipitation and linked to a convection effect. Unstable weather conditions caused by air convection might strongly modify the circadian pattern and cause the nightly peaks concentrations. The general results are that people suffering from allergies may be exposed to high birch and alder pollen concentrations at almost all times during the day with the exception of the morning hours, as well as during the first hours of convective precipitation. Precise information on pollen concentrations aids in allergy prevention, so cities should provide aerobiological monitoring at least at "roof level" and "nose level".
Definite Integrals, Some Involving Residue Theory Evaluated by Maple Code

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bowman, Kimiko o

2010-01-01

The calculus of residue is applied to evaluate certain integrals in the range (-{infinity} to {infinity}) using the Maple symbolic code. These integrals are of the form {integral}{sub -{infinity}}{sup {infinity}} cos(x)/[(x{sup 2} + a{sup 2})(x{sup 2} + b{sup 2}) (x{sup 2} + c{sup 2})]dx and similar extensions. The Maple code is also applied to expressions in maximum likelihood estimator moments when sampling from the negative binomial distribution. In general the Maple code approach to the integrals gives correct answers to specified decimal places, but the symbolic result may be extremely long and complex.
Competition for nitrogen between European beech and sycamore maple shifts in favour of beech with decreasing light availability.

PubMed

Simon, Judy; Li, Xiuyuan; Rennenberg, Heinz

2014-01-01

Plant species use different strategies for maximizing growth and fitness under changing environmental conditions. At the ecosystem level, seedlings in particular compete with other vegetation components for light and nitrogen (N), which often constitute growth-limiting resources. In this study, we investigated the effect of light availability on the competition for N between seedlings of European beech and sycamore maple and analysed the consequences of this competition for the composition of N metabolites in fine roots. Our results show different strategies in N acquisition between beech and sycamore maple. Both species responded to reduced light availability by adapting their morphological and physiological traits with a decrease in biomass and net assimilation rate and an increase in specific leaf area and leaf area ratio. For beech seedlings, competition with sycamore maple led to a reduction in organic N uptake capacity. Reduced light availability led to a decrease in ammonium, but an increase in glutamine-N uptake capacity in sycamore maple. However, this response was stronger compared with that of beech and was accompanied by reduced growth. Thus, our results suggest better adaptation of N acquisition to reduced light availability in beech compared with sycamore maple seedlings.

Regional growth decline of sugar maple (Acer saccharum) and its potential causes

USGS Publications Warehouse

Bishop, Daniel A.; Beier, Colin M.; Pederson, Neil; Lawrence, Gregory B.; Stella, John C; Sullivan, Timothy J.

2015-01-01

Sugar maple (Acer saccharum Marsh) has experienced poor vigor, regeneration failure, and elevated mortality across much of its range, but there has been relatively little attention to its growth rates. Based on a well-replicated dendrochronological network of range-centered populations in the Adirondack Mountains (USA), which encompassed a wide gradient of soil fertility, we observed that the majority of sugar maple trees exhibited negative growth trends in the last several decades, regardless of age, diameter, or soil fertility. Such growth patterns were unexpected, given recent warming and increased moisture availability, as well as reduced acidic deposition, which should have favored growth. Mean basal area increment was greater on base-rich soils, but these stands also experienced sharp reductions in growth. Growth sensitivity of sugar maple to temperature and precipitation was non-stationary during the last century, with overall weaker relationships than expected. Given the favorable competitive status and age structure of the Adirondack sugar maple populations sampled, evidence of widespread growth reductions raises concern over this ecologically and economically important tree. Further study will be needed to establish whether growth declines of sugar maple are occurring more widely across its range.
A black alder plantation improves the greenhouse gas balance of a degraded moist peat grassland

NASA Astrophysics Data System (ADS)

Bereswill, Sarah; Hoffmann, Mathias; Huth, Vytas; Popova, Yulia; Zak, Dominik; Augustin, Jürgen

2017-04-01

Drained peatlands are among the strongest terrestrial sources of the greenhouse gases (GHG) CO2 and N2O. Therefore, activities of peatland revitalisation through rewetting, often combined with the implementation of peat forming vegetation, aim to restore the GHG sink function that is characteristic for pristine peatlands. Black alder (Alnus glutinosa) naturally occurs in temperate marshes and minerotrophic peatlands (= fens) and is also suitable for paludiculture, the cultivation of biomass on wet or rewetted peatlands. However, only little information exists, if a black alder plantation can reduce the climate impact of restored peatlands. Therefore, we investigated the effect of a newly established black alder plantation on the net GHG balance of a degraded fen in north-eastern Germany during a two-year study (August 2010 - August 2012). We compared the alder plantation (Awet) with an extensively used meadow (Mwet) both characterized by very moist soil conditions and a drier reference meadow (Mdry) characterized by moderately moist soil conditions. CO2, CH4 and N2O fluxes were measured monthly to bi-monthly with the manual closed chamber method. Fluxes were calculated using a modular R script and gap filled to obtain continuous daily fluxes. Awet was a net GHG sink of -4.8 t CO2-eq ha-1 yr-1, Mwet was climate neutral (-0.03 t CO2-eq ha-1 yr-1), and Mdry was a net GHG source of 15.7 t CO2-eq ha-1 yr-1. This was mainly caused by CO2 uptake at the two very moist sites and a high CO2 release at the drier reference site. In addition, Awet was a larger CO2 sink than Mwet, likely caused by an additional CO2 uptake of the alder stand. All sites were significant CH4 sources. Due to inundation following extraordinarily heavy precipitation in summer 2011 remarkable CH4emission peaks were found on all sites which accounted for up to 70 % of the cumulated two-year CH4emissions. However, overall Awet emitted significantly lesser CH4(4.9 g C m-2 yr-1). We assume that the black alders decreased the CH4emissions due to their effective O2 transport mechanism. N2O emissions were negligible at all three sites. Our results indicate that rewetting and planting black alders significantly improve the GHG balances of formerly drained fens already in the first two years after plantation. Furthermore, only one wet summer significantly increased the CH4 emissions of our study site, despite two-year average groundwater levels (GWL) of -0.2 to -0.35 m. This highlights the importance of acknowledging extreme precipitation events and groundwater fluctuations for the derivation of reliable GHG emission factors.
Effects of maple (Acer) plant part extracts on proliferation, apoptosis and cell cycle arrest of human tumorigenic and non-tumorigenic colon cells.

PubMed

González-Sarrías, Antonio; Li, Liya; Seeram, Navindra P

2012-07-01

Phenolic-enriched extracts of maple sap and syrup, obtained from the sugar and red maple species (Acer saccharum Marsh, A. rubrum L., respectively), are reported to show anticancer effects. Despite traditional medicinal uses of various other parts of these plants by Native Americans, they have not been investigated for anticancer activity. Here leaves, stems/twigs, barks and sapwoods of both maple species were evaluated for antiproliferative effects against human colon tumorigenic (HCT-116, HT-29, Caco-2) and non-tumorigenic (CCD-18Co) cells. Extracts were standardized to total phenolic and ginnalin-A (isolated in our laboratory) levels. Overall, the extracts inhibited the growth of the colon cancer more than normal cells (over two-fold), their activities increased with their ginnalin-A levels, with red > sugar maple extracts. The red maple leaf extract, which contained the highest ginnalin-A content, was the most active extract (IC₅₀ = 35 and 16 µg/mL for extract and ginnalin-A, respectively). The extracts were not cytotoxic nor did they induce apoptosis of the colon cancer cells. However, cell cycle analyses revealed that the antiproliferative effects of the extracts were mediated through cell cycle arrest in the S-phase. The results from the current study suggest that these maple plant part extracts may have potential anticolon cancer effects. Copyright © 2011 John Wiley & Sons, Ltd.
Nature's Strategy for Catalyzing Diels-Alder Reaction.

PubMed

Oikawa, Hideaki

2016-04-21

The enzymes catalyzing a Diels-Alder-type reaction have been attractive targets for organic chemists for years. Recently, Zheng et al. (2016) reported the structure of a formal monofunctional Diels-Alderase PyrI4 complexed with the product and unveiled a detailed catalytic mechanism of a highly important enzyme. Copyright © 2016 Elsevier Ltd. All rights reserved.
Size of Douglas-fir trees in relation to distance from a mixed red alder - Douglas-fir stand

Treesearch

R.E. Miller; D.L. Reukema; T.A. Max

1993-01-01

Variation in diameter, height, and stem volume of 57-year-old Douglas-fir(Pseudotsuga menziesii var. menziesii (Mirb.) Franco) was related to distance of these trees from a 27 m wide strip in the same Douglas-fir plantation that had been interplanted with red alder (Alnus rubra Bong.). Within the...
Greenhouse germination trials of pelletized western redcedar and red alder seeds

Treesearch

Nabil Khadduri

2007-01-01

Pelletized western redcedar (Thuja plicata Donn ex D. Don) and red alder (Alnus rubra Bong.) seeds exhibited lower total germination and delayed germination speed (G50 or days to 50% germination) when compared to non-pelletized ârawâ seeds in greenhouse trials. Averaged across two lots of western redcedar, pelletizing decreased...
Biology and ecology of red alder.

Treesearch

Constance A. Harrington

2006-01-01

Red alder is the most common hardwood in the Pacific Northwest with a range stretching from coastal southeast Alaska to southern California and east to isolated populations in Idaho. Soil moisture during the growing season influences where it grows and its growth rates; it can tolerate poor drainage but not droughty, hot sites. Due to its tolerance of wet soil...
Chemical basal treatment to control red alder.

Treesearch

Robert H. Ruth; Carl M. Berntsen

1956-01-01

A key to better restocking of conifers on recently cutover forest land in the Oregon Coast Range is the elimination of competition from red alder (Alnus rubra Bong.). This can be readily accomplished with a foliage spray containing 2,4-dichlorophenoxyacetic acid (2.4-D). Tests in 1954 and 1955 on the Cascade Head Experimental Forest have shown that...
Illustrating the Utility of X-Ray Crystallography for Structure Elucidation through a Tandem Aldol Condensation/Diels-Alder Reaction Sequence

ERIC Educational Resources Information Center

Hoang, Giang T.; Kubo, Tomohiro; Young, Victor G., Jr.; Kautzky, Jacob A.; Wissinger, Jane E.

2015-01-01

Two introductory organic chemistry laboratory experiments are described based on the Diels-Alder reaction of 2,3,4,5-tetraphenylcyclopentadienone, which is synthesized prior to or in a one-pot reaction, with styrene. Students are presented with three possible products, the "endo" and "exo" diastereomers and the decarbonylated…
Microwave-Enhanced Organic Syntheses for the Undergraduate Laboratory: Diels-Alder Cycloaddition, Wittig Reaction, and Williamson Ether Synthesis

ERIC Educational Resources Information Center

Baar, Marsha R.; Falcone, Danielle; Gordon, Christopher

2010-01-01

Microwave heating enhanced the rate of three reactions typically performed in our undergraduate organic chemistry laboratory: a Diels-Alder cycloaddition, a Wittig salt formation, and a Williamson ether synthesis. Ninety-minute refluxes were shortened to 10 min using a laboratory-grade microwave oven. In addition, yields improved for the Wittig…
Retro iminonitroso Diels-Alder reactions: interconversion of nitroso cycloadducts

PubMed Central

Yang, Baiyuan; Lin, Weimin; Krchnak, Viktor; Miller, Marvin J.

2009-01-01

Retro iminonitroso Diels-Alder reactions were investigated in both solution and solid phase. In thermal or Cu(I)-mediated reactions, interconversion of various nitroso cycloadducts occurred in the presence of separate dienes. Up to 99% of conversion was observed. Use of chiral ligands in the Cu(I)-medicated reactions gave new cycloadducts enantioselectively. PMID:20161032
A Computational Experiment of the Endo versus Exo Preference in a Diels-Alder Reaction

ERIC Educational Resources Information Center

Rowley, Christopher N.; Woo, Tom K.

2009-01-01

We have developed and tested a computational laboratory that investigates an endo versus exo Diels-Alder cycloaddition. This laboratory employed density functional theory (DFT) calculations to study the cycloaddition of N-phenylmaleimide to furan. The endo and exo stereoisomers of the product were distinguished by building the two isomers in a…
Sorocenols G and H, Anti-MRSA Oxygen Heterocyclic Diels-Alder-type Adducts from Sorocea muriculata Roots

USDA-ARS?s Scientific Manuscript database

Bioassay-guided fractionation of a root extract of Sorocea muriculata led to the isolation and identification of two new oxygen heterocyclic Diels-Alder-type adducts, sorocenols G (1) and H (2), along with lupeol-3-(3'R-hydroxytetradecanoate) and oxyresveratrol. The structures of 1 and 2 were eluci...
Occurrence, structure, and nitrogen-fixation of root nodules of actinorhizal Arizona alder

Treesearch

J. O. Dawson; Gerald J. Gottfried; D. Hahn

2005-01-01

Actinorhizal plants are nodulated by the symbiotic, nitrogen-fixing actinomycete Frankia. The genus Alnus in the family Betulaceae is one of the 24 genera in 8 families of angiospermous plants that are actinorhizal. Arizona alder (Alnus oblongifolia Torr.) occurs in isolated populations associated with the watersheds of Madrean Sky Islands in the...
Red alder, Alnus rubra, as a potential mitigating factor for wildlife habitat following clearcut logging in southeastern Alaska.

Treesearch

T.A. Hanley; J.C. Barnard

1998-01-01

Within-stand variation in understory species composition and biomass was studied in 16 even-aged stands of mixed red alder-Sitka spruce-western hemlcock (Alnus rubra-Picea sitchensis-Tsuga heterophylla) forest. The sites were upland sites, and the stands were 28-39 years old. We compared understory within...
The relationship between measures of tree vigor and pear thrips damage in sugar maple

Treesearch

Gretchen Smith; Christina M. Petersen; Roy Van Driesche; Charles Burnham

1991-01-01

In this presentation I will address three points associated with pear thrips damage and sugar maple. First, I will describe the impact of pear thrips on sugar maple in Massachusetts, in both the sugarbush and the natural forest stand, based on root starch assays that were completed this fall (1988). Secondly, I will discuss the relationship between tree health and...
Yield and ultrasonic modulus of elasticity of red maple veneer

Treesearch

Robert J. Ross; Steven Verhey; John R. Erickson; John W. Forsman; Brian K. Brashaw; Crystal L. Pilon; Xiping Wang

2004-01-01

The purpose of the study was to assess the potential for using red maple sawlogs to manufacture laminated veneer lumber (LVL). The primary objective was to determine the yield of ultrasonically graded veneer from red maple logs. A sample of 48 logs was obtained from six Eastern and Lake States in the United States. The logs were visually graded and shipped to a plywood...
Be on the lookout for Asian longhorned beetles

Treesearch

Therese M. Poland; Robert A. Haack; Dennis A. Haugen; Ian M. Wilson

2001-01-01

In New York City and Chicago, ALB is most often found in maples (Acer spp.), reflecting both a preferences for maples as well as the fact that maples are the most common urban trees in both cities. In the United States and China, the ALB also attacks a wide range of other deciduous trees including birches (Betula spp.), elms (Ulmus spp.), poplars (Populus spp.), and...
Evaluation of Sugar Maple Dieback in the Upper Great Lakes Region and Development of a Forest Health Youth Education Program

ERIC Educational Resources Information Center

Bal, Tara L.

2013-01-01

Sugar Maple, "Acer saccharum" Marsh., is one of the most valuable trees in the northern hardwood forests. Severe dieback was recently reported by area foresters in the western Upper Great Lakes Region. Sugar Maple has had a history of dieback over the last 100 years throughout its range and different variables have been identified as…
Reexamination of effects of paraformaldehyde on tissues around tapholes in sugar maple trees

Treesearch

David R. Houston; J. Chris Fagan

1997-01-01

Pellets containing paraformaldehyde (PFA) are sometimes placed behind spouts in tapped sugar maples to prolong sapflow and increase the yield of sap used to make maple syrup.The practice is controversial because the chemical has been shown to promote decay and is reported to cause cambial dieback around tapholes.This study reexamined the effects of PFA on tapped sugar...

The Changing Colors of Maple Hills: Intersections of Culture, Race, Language, and Exceptionality in a Rural Farming Community

ERIC Educational Resources Information Center

Scanlan, Martin

2016-01-01

This case describes Maple Hills Elementary, a K-8 school in a rural farming community of the Midwest. As a community, Maple Hills has historically experienced a narrow range of diversity across race, ethnicity, language, and religion. Residents have predominantly been White, with German and English heritage, speak English as a mother tongue, and…
Sugar maple growth in relation to nutrition and stress in the northeastern United States.

PubMed

Long, Robert P; Horsley, Stephen B; Hallett, Richard A; Bailey, Scott W

2009-09-01

Sugar maple, Acer saccharum, decline disease is incited by multiple disturbance factors when imbalanced calcium (Ca), magnesium (Mg), and manganese (Mn) act as predisposing stressors. Our objective in this study was to determine whether factors affecting sugar maple health also affect growth as estimated by basal area increment (BAI). We used 76 northern hardwood stands in northern Pennsylvania, New York, Vermont, and New Hampshire, USA, and found that sugar maple growth was positively related to foliar concentrations of Ca and Mg and stand level estimates of sugar maple crown health during a high stress period from 1987 to 1996. Foliar nutrient threshold values for Ca, Mg, and Mn were used to analyze long-term BAI trends from 1937 to 1996. Significant (P < or = 0.05) nutrient threshold-by-time interactions indicate changing growth in relation to nutrition during this period. Healthy sugar maples sampled in the 1990s had decreased growth in the 1970s, 10-20 years in advance of the 1980s and 1990s decline episode in Pennsylvania. Even apparently healthy stands that had no defoliation, but had below-threshold amounts of Ca or Mg and above-threshold Mn (from foliage samples taken in the mid 1990s), had decreasing growth by the 1970s. Co-occurring black cherry, Prunus serotina, in a subset of the Pennsylvania and New York stands, showed opposite growth responses with greater growth in stands with below-threshold Ca and Mg compared with above-threshold stands. Sugar maple growing on sites with the highest concentrations of foliar Ca and Mg show a general increase in growth from 1937 to 1996 while other stands with lower Ca and Mg concentrations show a stable or decreasing growth trend. We conclude that acid deposition induced changes in soil nutrient status that crossed a threshold necessary to sustain sugar maple growth during the 1970s on some sites. While nutrition of these elements has not been considered in forest management decisions, our research shows species specific responses to Ca and Mg that may reduce health and growth of sugar maple or change species composition, if not addressed.
Determination of complex electromechanical coefficients for piezoelectric materials

NASA Astrophysics Data System (ADS)

Du, Xiao-Hong

Sugar maple decline, a result of many possible biotic and abiotic causes, has been a problem in northern Pennsylvania since the early 1980s. Several studies have focused on specific causes, yet few have tried to look at a wide array. The purpose of this research was to investigate stresses in sugar maple forest plots in northern Pennsylvania. Three studies were undertaken. The first study examined the spatial extent of sugar maple on 248 plots in Bailey's ecoregions 212F and 212G, which are glaciated and unglaciated regions, respectively. In addition, a health assessment of sugar maple in Pennsylvania was made, with a resulting separation in population between healthy and unhealthy stands occurring at 20 percent dead sugar maple basal area. The second study was conducted to evaluate a statistical sampling design of 28 forested plots, from the above studies population of plots (248), and to provide data on physical and chemical soil variability and sample size estimation for other researchers. The variability of several soil parameters was examined within plots and between health classes of sugar maple and sample size estimations were derived for these populations. The effect of log-normal transformations on reducing variability and sample sizes was examined and soil descriptions of the plots sampled in 1998 were compared to the USDA Soil Survey mapping unit series descriptions for the plot location. Lastly, the effect of sampling intensity on the detection of significant differences between health class treatments was examined. The last study addressed sugar maple decline in northern Pennsylvania during the same period as the first study (approximately 1979-1989) but on 28 plots chosen from the first studies population. These were the same plots used in the second study on soil variability. Recent literature on sugar maple decline has focused on specific causes and few have tried to look at a wide array. This paper investigates stresses in sugar maple plots related to moisture and how these interact with other stresses such as chemistry, insect defoliation, geology, aspect, slope, topography, and atmospheric deposition.
Chemical compositional, biological, and safety studies of a novel maple syrup derived extract for nutraceutical applications.

PubMed

Zhang, Yan; Yuan, Tao; Li, Liya; Nahar, Pragati; Slitt, Angela; Seeram, Navindra P

2014-07-16

Maple syrup has nutraceutical potential given the macronutrients (carbohydrates, primarily sucrose), micronutrients (minerals and vitamins), and phytochemicals (primarily phenolics) found in this natural sweetener. We conducted compositional (ash, fiber, carbohydrates, minerals, amino acids, organic acids, vitamins, phytochemicals), in vitro biological, and in vivo safety (animal toxicity) studies on maple syrup extracts (MSX-1 and MSX-2) derived from two declassified maple syrup samples. Along with macronutrient and micronutrient quantification, thirty-three phytochemicals were identified (by HPLC-DAD), and nine phytochemicals, including two new compounds, were isolated and identified (by NMR) from MSX. At doses of up to 1000 mg/kg/day, MSX was well tolerated with no signs of overt toxicity in rats. MSX showed antioxidant (2,2-diphenyl-1-picrylhydrazyl (DPPH) assay) and anti-inflammatory (in RAW 264.7 macrophages) effects and inhibited glucose consumption (by HepG2 cells) in vitro. Thus, MSX should be further investigated for potential nutraceutical applications given its similarity in chemical composition to pure maple syrup.
Winter climate change and fine root biogenic silica in sugar maple trees (Acer saccharum): Implications for silica in the Anthropocene

NASA Astrophysics Data System (ADS)

Maguire, Timothy J.; Templer, Pamela H.; Battles, John J.; Fulweiler, Robinson W.

2017-03-01

Winter temperatures are projected to increase over the next century, leading to reductions in winter snowpack and increased frequency of soil freezing in many northern forest ecosystems. Here we examine biogenic silica (BSi) concentrations in sugar maple (Acer saccharum) fine roots collected from a snow manipulation experiment at Hubbard Brook Experimental Forest (New Hampshire, USA). Increased soil freezing significantly lowered the BSi content of sugar maple fine roots potentially decreasing their capacity to take up water and dissolved nutrients. The reduced silica uptake (8 ± 1 kmol silica km-2) by sugar maple fine roots is comparable to silica export from temperate forest watersheds. We estimate that fine roots account for 29% of sugar maple BSi, despite accounting for only 4% of their biomass. These results suggest that increased frequency of soil freezing will reduce silica uptake by temperate tree roots, thereby changing silica availability in downstream receiving waters.
Molecular organization in MAPLE-deposited conjugated polymer thin films and the implications for carrier transport characteristics

DOE PAGES

Dong, Ban Xuan; Li, Anton; Strzalka, Joseph; ...

2016-09-18

The morphological structure of poly(3-hexylthiophene) (P3HT) thin films deposited by both Matrix Assisted Pulsed Laser Evaporation (MAPLE) and solution spin-casting methods are investigated. We found that the MAPLE samples possessed a higher degree of disorder, with random orientations of polymer crystallites along the side-chain stacking, π-π stacking, and conjugated backbone directions. Furthermore, the average molecular orientations and relative degrees of crystallinity of MAPLE-deposited polymer films are insensitive to the chemistries of the substrates onto which they were deposited; this is in stark contrast to the films prepared by the conventional spin-casting technique. In spite of the seemingly unfavorable molecular orientations andmore » the highly disordered morphologies, the in-plane charge carrier transport characteristics of the MAPLE samples are comparable to those of spin-cast samples, exhibiting similar transport activation energies (56 meV versus 54 meV) to those reported in the literature for high mobility polymers.« less
Molecular organization in MAPLE-deposited conjugated polymer thin films and the implications for carrier transport characteristics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dong, Ban Xuan; Li, Anton; Strzalka, Joseph

The morphological structure of poly(3-hexylthiophene) (P3HT) thin films deposited by both Matrix Assisted Pulsed Laser Evaporation (MAPLE) and solution spin-casting methods are investigated. We found that the MAPLE samples possessed a higher degree of disorder, with random orientations of polymer crystallites along the side-chain stacking, π-π stacking, and conjugated backbone directions. Furthermore, the average molecular orientations and relative degrees of crystallinity of MAPLE-deposited polymer films are insensitive to the chemistries of the substrates onto which they were deposited; this is in stark contrast to the films prepared by the conventional spin-casting technique. In spite of the seemingly unfavorable molecular orientations andmore » the highly disordered morphologies, the in-plane charge carrier transport characteristics of the MAPLE samples are comparable to those of spin-cast samples, exhibiting similar transport activation energies (56 meV versus 54 meV) to those reported in the literature for high mobility polymers.« less
Chemical Compositional, Biological, and Safety Studies of a Novel Maple Syrup Derived Extract for Nutraceutical Applications

PubMed Central

2015-01-01

Maple syrup has nutraceutical potential given the macronutrients (carbohydrates, primarily sucrose), micronutrients (minerals and vitamins), and phytochemicals (primarily phenolics) found in this natural sweetener. We conducted compositional (ash, fiber, carbohydrates, minerals, amino acids, organic acids, vitamins, phytochemicals), in vitro biological, and in vivo safety (animal toxicity) studies on maple syrup extracts (MSX-1 and MSX-2) derived from two declassified maple syrup samples. Along with macronutrient and micronutrient quantification, thirty-three phytochemicals were identified (by HPLC-DAD), and nine phytochemicals, including two new compounds, were isolated and identified (by NMR) from MSX. At doses of up to 1000 mg/kg/day, MSX was well tolerated with no signs of overt toxicity in rats. MSX showed antioxidant (2,2-diphenyl-1-picrylhydrazyl (DPPH) assay) and anti-inflammatory (in RAW 264.7 macrophages) effects and inhibited glucose consumption (by HepG2 cells) in vitro. Thus, MSX should be further investigated for potential nutraceutical applications given its similarity in chemical composition to pure maple syrup. PMID:24983789
Watershed influences on the structure and function of riparian wetlands associated with headwater streams - Kenai Peninsula, Alaska.

PubMed

Whigham, D F; Walker, C M; Maurer, J; King, R S; Hauser, W; Baird, S; Keuskamp, J A; Neale, P J

2017-12-01

Riparian wetlands are dynamic components of landscapes. Located between uplands and aquatic environments, riparian habitats intercept sediments and nutrients before they enter aquatic environments. They are a source of organic matter and nutrients to aquatic systems, and they provide important habitat for animals, often serving as corridors for the movement of animals between habitats in fragmented landscapes. In this project, we focused on the structure and function of riparian wetlands associated with headwater streams in Alaska that serve as nursery habitats for juvenile salmonids. We asked whether or not the structure and function of headwater wetlands differed between watersheds with and without nitrogen-fixing Alder (Alnus spp.). We found that the aboveground biomass of riparian vegetation was higher in the watershed with Alder, but the largest differences were in the litter layer and belowground where vegetation in the watershed with no Alder had significantly higher root biomass. Interstitial water chemistry also differed between the study sites with significantly higher inorganic N and significantly different characteristics of colored dissolved organic matter at the site with Alder on the watershed. The biomass of litter that hung over the creek bank was less at the site with Alder on the watershed and an in situ decomposition experiment showed significant differences between the two systems. Results of the research demonstrates that watershed characteristics can impact the ecology of headwater streams in ways that had not been previously recognized. Copyright © 2017 The Author(s). Published by Elsevier B.V. All rights reserved.
Quantitative structure-activation barrier relationship modeling for Diels-Alder ligations utilizing quantum chemical structural descriptors.

PubMed

Nandi, Sisir; Monesi, Alessandro; Drgan, Viktor; Merzel, Franci; Novič, Marjana

2013-10-30

In the present study, we show the correlation of quantum chemical structural descriptors with the activation barriers of the Diels-Alder ligations. A set of 72 non-catalysed Diels-Alder reactions were subjected to quantitative structure-activation barrier relationship (QSABR) under the framework of theoretical quantum chemical descriptors calculated solely from the structures of diene and dienophile reactants. Experimental activation barrier data were obtained from literature. Descriptors were computed using Hartree-Fock theory using 6-31G(d) basis set as implemented in Gaussian 09 software. Variable selection and model development were carried out by stepwise multiple linear regression methodology. Predictive performance of the quantitative structure-activation barrier relationship (QSABR) model was assessed by training and test set concept and by calculating leave-one-out cross-validated Q2 and predictive R2 values. The QSABR model can explain and predict 86.5% and 80% of the variances, respectively, in the activation energy barrier training data. Alternatively, a neural network model based on back propagation of errors was developed to assess the nonlinearity of the sought correlations between theoretical descriptors and experimental reaction barriers. A reasonable predictability for the activation barrier of the test set reactions was obtained, which enabled an exploration and interpretation of the significant variables responsible for Diels-Alder interaction between dienes and dienophiles. Thus, studies in the direction of QSABR modelling that provide efficient and fast prediction of activation barriers of the Diels-Alder reactions turn out to be a meaningful alternative to transition state theory based computation.
Flexural properties of laminated veneer lumber manufactured from ultrasonically rated red maple veneer : a pilot study.

Treesearch

Xiping Wang; Robert J. Ross; Brian K. Brashaw; Steven A. Verhey; John W. Forsman; John R. Erickson

2003-01-01

The study described in this report was conducted to examine the flexural properties of laminated veneer lumber (LVL) manufactured from red maple veneer. Ultrasonically rated veneer, which was peeled from low value red maple saw-logs, was fabricated into 1/2-in.-(1.3-cm-) and 2-in.-(5-cm-) thick LVL billets. The flexural properties of the billets and of corresponding...
Effect of moisture content on warp in hardwood 2 by 6`s for structural use

Treesearch

William T. Simpson; John W. Forsman

Sugar maple (Acer saccharum), red maple (Acer rubrum), and yellow birch (Betula alleghaniensis) 2 by 6as were dried and evaluated for warp as it affects ability to meet softwood dimension lumber grading rule requirements for warp. In the first part of the study, sugar maple was kiln-dried to three levels of final moisture content: 27%, 19%, and 12%. Warp during kiln...
Spatial relationships between sugar maple (Acer saccharum Marsh), sugar maple decline, slope, aspect, and atmospheric deposition in northern Pennsylvania

Treesearch

Patrick Drohan; Susan Stout; Gary Peterson

1999-01-01

Sugar maple decline began to affect Allegheny Plateau forests in the early to mid-1980s. The forests of the region were exposed to several stresses In the period frorn 1985- 1996, including droughts during 1988, 1991, and 1995. Additionally, both native and exotic insects reached epidemic levels during this period (see, for example, Rhoads, 1993). Other documented...
Seed fall in an oldgrowth northern hardwood forest

Treesearch

Raymond E. Graber; William B. Leak; William B. Leak

1992-01-01

Seed fall was measured for 11 years in a 200-year-old stand of sugar maple, yellow birch, and beech in New Hampshire. Yellow birch had 5 good seed years, sugar maple had 3, and beech had none. Viable seed fall of yellow birch began in August and continued through autumn and winter. Most of the viable sugar maple seed fell during a short period in October. Beech seed...
An assessment of management history of damaged and undamaged trees 8 years after the ice storm in Rochester, New York, U.S.

Treesearch

Wayne C. Zipperer; Susan M. Sisinni; Jerry Bond; Chris Luley; Andrew G. Pleninger

2004-01-01

Rochester, New York, U.S., were reviewed to evaluate the city's storm related removal protocol and how maintenance varied by damage classes. Maintenance codes assigned in 1991 were used to identify ice-storm damage classes based on percentage of crown loss. We evaluated seven species Noway maple (Acer platanoides), silver maple (A. saccharinum), sugar maple (A....
Fire history and the establishment of oaks an maples in second-growth forests

Treesearch

Todd F. Hutchinson; Robert P. Long; Robert D. Ford; Elaine Kennedy Sutherland

2008-01-01

We used dendrochronology to examine the influence of past fires on oak and maple establishment. Six study units were located in southern Ohio, where organized fire control began in 1923. After stand thinning in 2000, we collected basal cross sections from cut stumps of oak (n = 137) and maple (n = 204). The fire history of each unit was developed from the oaks, and...
Environmental setting of Maple Creek watershed, Nebraska

USGS Publications Warehouse

Fredrick, Brian S.; Linard, Joshua I.; Carpenter, Jennifer L.

2006-01-01

The Maple Creek watershed covers a 955-square-kilometer area in eastern Nebraska, which is a region dominated by agricultural land use. The Maple Creek watershed is one of seven areas currently included in a nationwide study of the sources, transport, and fate of water and chemicals in agricultural watersheds. This study, known as the topical study of 'Agricultural Chemicals: Sources, Transport, and Fate' is part of the National Water-Quality Assessment Program being conducted by the U.S. Geological Survey. The Program is designed to describe water-quality conditions and trends based on representative surface- and ground-water resources across the Nation. The objective of the Agricultural Chemicals topical study is to investigate the sources, transport, and fate of selected agricultural chemicals in a variety of agriculturally diverse environmental settings. The Maple Creek watershed was selected for the Agricultural Chemicals topical study because its watershed represents the agricultural setting that characterizes eastern Nebraska. This report describes the environmental setting of the Maple Creek watershed in the context of how agricultural practices, including agricultural chemical applications and irrigation methods, interface with natural settings and hydrologic processes. A description of the environmental setting of a subwatershed within the drainage area of Maple Creek is included to improve the understanding of the variability of hydrologic and chemical cycles at two different scales.
Simulated changes in biogenic VOC emissions and ozone formation from habitat expansion of Acer Rubrum (red maple)

DOE PAGES

Drewniak, Beth A.; Snyder, Peter K.; Steiner, Allison L.; ...

2014-01-17

A new vegetation trend is emerging in northeastern forests of the United States, characterized by an expansion of red maple at the expense of oak. This has changed emissions of biogenic volatile organic compounds (BVOCs), primarily isoprene and monoterpenes. Oaks strongly emit isoprene while red maple emits a negligible amount. This species shift may impact nearby urban centers because the interaction of isoprene with anthropogenic nitrogen oxides can lead to tropospheric ozone formation and monoterpenes can lead to the formation of particulate matter. Here in this study the Global Biosphere Emissions and Interactions System was used to estimate the spatialmore » changes in BVOC emission fluxes resulting from a shift in forest composition between oak and maple. A 70% reduction in isoprene emissions occurred when oak was replaced with maple. Ozone simulations with a chemical box model at two rural and two urban sites showed modest reductions in ozone concentrations of up to 5–6 ppb resulting from a transition from oak to red maple, thus suggesting that the observed change in forest composition may benefit urban air quality. This study illustrates the importance of monitoring and representing changes in forest composition and the impacts to human health indirectly through changes in BVOCs.« less
Simulated changes in biogenic VOC emissions and ozone formation from habitat expansion of Acer Rubrum (red maple)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Drewniak, Beth A.; Snyder, Peter K.; Steiner, Allison L.

A new vegetation trend is emerging in northeastern forests of the United States, characterized by an expansion of red maple at the expense of oak. This has changed emissions of biogenic volatile organic compounds (BVOCs), primarily isoprene and monoterpenes. Oaks strongly emit isoprene while red maple emits a negligible amount. This species shift may impact nearby urban centers because the interaction of isoprene with anthropogenic nitrogen oxides can lead to tropospheric ozone formation and monoterpenes can lead to the formation of particulate matter. Here in this study the Global Biosphere Emissions and Interactions System was used to estimate the spatialmore » changes in BVOC emission fluxes resulting from a shift in forest composition between oak and maple. A 70% reduction in isoprene emissions occurred when oak was replaced with maple. Ozone simulations with a chemical box model at two rural and two urban sites showed modest reductions in ozone concentrations of up to 5–6 ppb resulting from a transition from oak to red maple, thus suggesting that the observed change in forest composition may benefit urban air quality. This study illustrates the importance of monitoring and representing changes in forest composition and the impacts to human health indirectly through changes in BVOCs.« less
Simulated changes in biogenic VOC emissions and ozone formation from habitat expansion of Acer Rubrum (red maple)

NASA Astrophysics Data System (ADS)

Drewniak, Beth A.; Snyder, Peter K.; Steiner, Allison L.; Twine, Tracy E.; Wuebbles, Donald J.

2014-01-01

A new vegetation trend is emerging in northeastern forests of the United States, characterized by an expansion of red maple at the expense of oak. This has changed emissions of biogenic volatile organic compounds (BVOCs), primarily isoprene and monoterpenes. Oaks strongly emit isoprene while red maple emits a negligible amount. This species shift may impact nearby urban centers because the interaction of isoprene with anthropogenic nitrogen oxides can lead to tropospheric ozone formation and monoterpenes can lead to the formation of particulate matter. In this study the Global Biosphere Emissions and Interactions System was used to estimate the spatial changes in BVOC emission fluxes resulting from a shift in forest composition between oak and maple. A 70% reduction in isoprene emissions occurred when oak was replaced with maple. Ozone simulations with a chemical box model at two rural and two urban sites showed modest reductions in ozone concentrations of up to 5-6 ppb resulting from a transition from oak to red maple, thus suggesting that the observed change in forest composition may benefit urban air quality. This study illustrates the importance of monitoring and representing changes in forest composition and the impacts to human health indirectly through changes in BVOCs.

Equine atypical myopathy caused by hypoglycin A intoxication associated with ingestion of sycamore maple tree seeds.

PubMed

Żuraw, A; Dietert, K; Kühnel, S; Sander, J; Klopfleisch, R

2016-07-01

Evidence suggest there is a link between equine atypical myopathy (EAM) and ingestion of sycamore maple tree seeds. To further evaluate the hypothesis that the ingestion of hypoglycin A (HGA) containing sycamore maple tree seeds causes acquired multiple acyl-CoA dehydrogenase deficiency and might be associated with the clinical and pathological signs of EAM. Case report. Necropsy and histopathology, using hematoxylin and eosin and Sudan III stains, were performed on a 2.5-year-old mare that died following the development of clinical signs of progressive muscle stiffness and recumbency. Prior to death, the animal ingested sycamore maple tree seeds (Acer pseudoplatanus). Detection of metabolites in blood and urine obtained post mortem was performed by rapid ultra-performance liquid chromatography-tandem mass spectrometry. Data from this case were compared with 3 geldings with no clinical history of myopathy. Macroscopic examination revealed fragments of maple tree seeds in the stomach and severe myopathy of several muscle groups including Mm. intercostales, deltoidei and trapezii. Histologically, the affected muscles showed severe, acute rhabdomyolysis with extensive accumulation of finely dispersed fat droplets in the cytoplasm of degenerated skeletal muscle cells not present in controls. Urine and serum concentrations of several acyl carnitines and acyl glycines were increased, and both contained metabolites of HGA, a toxic amino acid present in sycamore maple tree seeds. The study supports the hypothesis that ingestion of HGA-containing maple tree seeds may cause EAM due to acquired multiple acyl-CoA dehydrogenase deficiency. © 2015 EVJ Ltd.
Soil acidity and manganese in declining and nondeclining sugar maple stands in Pennsylvania.

PubMed

Kogelmann, Wilhelm J; Sharpe, William E

2006-01-01

For decades, the hardwood forests of northern Pennsylvania have been subjected to chronic atmospheric loading of acidifying agents. On marginal, high-elevation, unglaciated sites, sugar maples (Acer saccharum Marsh.) have experienced severe decline symptoms and mortality. Accelerated soil acidification, base cation leaching, and increased availability of toxic metals have been suggested as predisposing factors contributing to this decline. Manganese, an essential micronutrient, is also a potentially phytotoxic metal that may be a factor associated with poor sugar maple health on soils vulnerable to acidification from anthropogenic sources. We measured Mn levels in four compartments of the soil-tree system (soil, foliage, xylem wood, and sap) on three sugar maple stands in northern Pennsylvania. Two stands were classified as declining and one was in good health. Negative correlations were found between soil pH and Mn levels in the soil, foliage, sap, and xylem wood. Levels of Mn in these pools were consistently higher on declining sites, which correspondingly exhibited lower levels of Ca and Mg. Species differences between red maple (Acer rubrum L.) and sugar maple at the two declining sites suggested different tolerances to excessive Mn. Molar ratios of Mg/Mn and Ca/Mn were different among sites and showed potential as indicators of soil acidification. Significant correlations among soil, sap, foliage, and xylem wood Mn were also noted. These results show clear Mn differences among sites and, when viewed with recent Mn toxicity experiments and other observational studies, suggest that excessive Mn may play a role in the observed decline and mortality of sugar maple.
Variation in damage from growing-season frosts among open-pollinated families of red alder.

Treesearch

Kevin C. Peeler; Dean S. DeBell

1987-01-01

Repeated growing-season frosts during late April and early May 1985 caused extensive damage to red alder (Alnus rubra Bong.) seedlings in a newly planted research trial in western Washington. About two-thirds of the seedlings were severely damaged (entire stem damaged or necrotic). Such damage varied by family, from 50 percent of seedlings in the...
Time and distance to clear wood in pruned red alder saplings.

Treesearch

Dean S. DeBell; Constance A. Harrington; Barbara L. Gartner; Ryan. Singleton

2006-01-01

Pruning trials in young alder stands were sampled to evaluate response to pruning. Effects of pruning (1) live branches on different dates, and (2) dead branches with or without damaging the branch collar were assessed on trees pruned in 3- and 6-year-old plantations, respectively. Six years after pruning, stem sections were collected and dissected in the longitudinal-...
A method of site quality evaluation for red alder.

Treesearch

Constance A. Harrington

1986-01-01

A field guide to predict site index for red alder (Alnus rubra Bong.) was developed for use in western Washington and Oregon. The guide requires the user to evaluate 14 soil-site properties that are grouped into three general factors: (1) geographic and topographic position, (2) soil moisture and aeration during the growing season, and (3) soil fertility and physical...
61. Photocopy of Engine Room Floor Plan, White Alder. The ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

61. Photocopy of Engine Room Floor Plan, White Alder. The Niagara Shipbuilding Corp. Engineering Department, Buffalo, New York. Coast Guard Headquarters Drawing No. 540-WAGL-1604-10, dated February 1943; revised January 1963. Original drawing property of the U.S. Coast Guard. - U.S. Coast Guard Cutter WHITE HEATH, USGS Integrated Support Command Boston, 427 Commercial Street, Boston, Suffolk County, MA
Managing young upland forests in southeast Alaska for wood products, wildlife, aquatic resources, and fishes: problem analysis and study plan.

Treesearch

Mark S. Wipfli; Robert L. Deal; Paul E. Hennon; Adelaide C. Johnson; Toni L. de Santo; Thomas A. Hanley; Mark E. Schultz; Mason D. Bryant; Richard T. Edwards; Ewa H. Orlikowska; Takashi Gomi

2002-01-01

Red alder (Alnus rubra Bong.) appears to influence the productivity of young-growth conifer forests and affect the major resources (timber, wildlife, and fisheries) of forested ecosystems in southeast Alaska. We propose an integrated approach to understanding how alder influences trophic links and processes in young-growth ecosystems. The presence...
The Synthesis of "N"-Benzyl-2-Azanorbornene via Aqueous Hetero Diels-Alder Reaction: An Undergraduate Project in Organic Synthesis and Structural Analysis

ERIC Educational Resources Information Center

Sauvage, Xavier; Delaude, Lionel

2008-01-01

The synthesis of "N"-benzyl-2-azanorbornene via aqueous hetero Diels-Alder reaction of cyclopentadiene and benzyliminium chloride formed in situ from benzylamine hydrochloride and formaldehyde is described. Characterization of the product was achieved by IR and NMR spectroscopies. The spectral data acquired are thoroughly discussed. Numerous…
Development of Alnus tenuifolia stands on an Alaskan floodplain: patterns of recruitment, disease, and succession

Treesearch

Dana R. Nossov; Teresa N. Hollingsworth; Roger W. Ruess; Knut Kielland

2011-01-01

We investigated the population dynamics of the keystone symbiotic N-fixing species Alnus tenuifolia (thinleaf alder) and the patterns of primary succession on the Tanana River floodplains of interior Alaska, USA. The goals of this study were to characterize (i) the variation in the population structure of thinleaf alder and its influence on...
Relations between red alder composition and understory vegetation in young mixed forests of southeast Alaska.

Treesearch

Thomas A. Hanley; Robert L. Deal; Ewa H. Orlikowska

2006-01-01

Interest in mixed red alder (Alnus rubra Bong.)conifer young-growth stands has grown in southeast Alaska, USA, because they appear to provide much more productive understory vegetation and wildlife habitat than do similar-aged pure conifer stands. We studied understory vegetation in nine even-aged young-growth stands (38-42 years old)...
The reliability of determining age of red alder by ring counts

Treesearch

Dean S. DeBell; Boyd C. Wilson; Bernard T. Bormann

1978-01-01

Examination of cross-sections of 54 red alder trees from 14 stands of varying age and site conditions indicated that abnormal rings (false, partial, or missing) occur infrequently. Rings may be indistinct and ring counting must be done with great care, preferably on prepared surfaces (cross-sections or cores) and under magnification and good lighting. With such...
Design and Synthesis of a Library of Tetracyclic Hydroazulenoisoindoles

PubMed Central

Brummond, Kay M.; Mao, Shuli; Shinde, Sunita N.; Johnston, Paul J.; Day, Billy W.

2009-01-01

Forty-four tetracyclic hydroazulenoisoindoles were synthesized via a tandem cyclopropanation/Cope rearrangement followed by a Diels-Alder sequence from easily available five-membered cyclic cross-conjugated trienones. These trienones were obtained from two different routes depending upon whether R1 and R2 are alkyl or amino acid derived functional groups, via a rhodium(I)-catalyzed cycloisomerization reaction. In order to increase diversity, four maleimides and two 1,2,4-triazoline-3,5-diones were used as dienophiles in the Diels-Alder step. Several Diels-Alder adducts were further reacted under palladium-catalyzed hydrogenation conditions, leading to a diastereoselective reduction of the trisubstituted double bond. This library has demonstrated rapid access to a variety of structurally complex natural product-like compounds via stereochemical diversity and building block diversity approaches. PMID:19366169
Disturbance severity and canopy position control the radial growth response of maple trees (Acer spp.) in forests of northwest Ohio impacted by emerald ash borer (Agrilus planipennis)

Treesearch

K.C. Costilow; Kathleen Knight; Charles Flower

2017-01-01

Key message. Radial growth of silver and red maples was investigated across three forests in northwest Ohio following the outbreak of the invasive emerald ash borer. The growth response of maples was driven by an advancement in canopy class and disturbance severity. Context. Forest disturbances resulting in species-specific diffuse mortality cause shifts in aboveground...
Soil base saturation combines with beech bark disease to influence composition and structure of sugar maple-beech forests in an acid rain-impacted region

Treesearch

Gregory B. Lawrence; Todd C. McDonnell; Timothy J. Sullivan; Martin Dovciak; Scott W. Bailey; Michael R. Antidormi; Michael R. Zarfos

2017-01-01

Sugar maple, an abundant and highly valued tree species in eastern North America, has experienced decline from soil calcium (Ca) depletion by acidic deposition, while beech, which often coexists with sugar maple, has been afflicted with beech bark disease (BBD) over the same period. To investigate how variations in soil base saturation combine with effects of BBD in...
Managing for delicious ecosystem service under climate change: can United States sugar maple (Acer saccharum) syrup production be maintained in a warming climate?

Treesearch

Stephen N. Matthews; Louis R. Iverson

2017-01-01

Sugar maple (Acer saccharum) is a highly valued tree in United States (US) and Canada, and its sap when collected from taps and concentrated, makes a delicious syrup. Understanding how this resource may be impacted by climate change and other threats is essential to continue management for maple syrup into the future. Here, we evaluate the current...
Influence of crown class, diameter, and sprout rank on red maple (Acer rubrum L.) development during forest succession in Connecticut

Treesearch

Jeffery S. Ward; George R. Stephens

1993-01-01

Crown class, stem diameter, and sprout rank of 2067 red maples on medium quality sites were measured at 10-yr intervals between 1927-1987. Nominal stand age was 25 yrs in 1927. There was a progressive increase in the probability of an individual red maple ascending into the upper canopy and persisting in the upper canopy from suppressed through dominant crown classes...
A Profile of Lake States Maple Syrup Producers and Their Attitudes and Responses to Economic, Social, Ecological and Climate Challenges

Treesearch

Stephanie A. Snyder; Michael A. Kilgore; Marla R. Emery; Marissa Schmitz

2018-01-01

Maple syrup is an iconic as well as economically and culturally important non-timber forest product in North America. The economic benefits derived from maple syrup production are substantial. In 2016, the U.S. produced 4.2 million gallons of syrup worth an estimated $147 million (USDA, 2017b). In addition, sugaring provides many with a deep, personal connection to...
Dendrochronology and lakes: using tree-rings of alder to reconstruct lake levels

NASA Astrophysics Data System (ADS)

van der Maaten, Ernst; Buras, Allan; Scharnweber, Tobias; Simard, Sonia; Kaiser, Knut; Lorenz, Sebastian; van der Maaten-Theunissen, Marieke; Wilmking, Martin

2014-05-01

Climate change is considered a major threat for ecosystems around the world. Assessing its effects is challenging, amongst others, as we are unsure how ecosystems may respond to climate conditions they were not exposed to before. However, increased insight may be obtained by analyzing responses of ecosystems to past climate variability. In this respect, lake ecosystems appear as valuable sentinels, because they provide direct and indirect indicators of change through effects of climate. Lake-level fluctuations of closed catchments, for example, reflect a dynamic water balance, provide detailed insight in past moisture variations, and thereby allow for assessments of effects of anticipated climate change. Up to now, lake-level data are mostly obtained from gauging records and reconstructions from sediments and landforms. However, these records are in many cases only available over relatively short time periods, and, since geoscientific work is highly demanding, lake-level reconstructions are lacking for many regions. Here, we present and discuss an alternative method to reconstruct lake levels, which is based on tree-ring data of black alder (Alnus glutinosa L.). This tree species tolerates permanently waterlogged and temporally flooded conditions (i.e. riparian vegetation), and is often found along lakeshores. As the yearly growth of trees varies depending upon the experienced environmental conditions, annual rings of black alder from lakeshore vegetation likely capture information on variations in water table, and may therefore be used to reconstruct lake levels. Although alder is a relatively short-lived tree species, the frequent use of its' decay-resistant wood in foundations of historical buildings offers the possibility of extending living tree-chronologies back in time for several centuries. In this study, the potential to reconstruct lake-level fluctuations from tree-ring chronologies of black alder is explored for three lake ecosystems in the Mecklenburg Lake District, northeastern Germany. Tree-ring data were collected from black alder forests surrounding the lakes 'Tiefer See', 'Drewitzer See' and 'Großer Fürstenseer See'. At all research sites, increment cores were extracted from at least 15 trees (2 cores per tree) using an increment borer. In the tree-ring lab DendroGreif, these cores were prepared and annual tree-ring widths were measured. Thereafter, site-specific tree-ring chronologies were built using established detrending and standardization procedures. Preliminary results show that the growth of alder reacts upon water level fluctuations. We visually and statistically compare the developed tree-ring chronologies with historical lake-level records, and retrospectively model lake levels. Findings will be presented while critically reflecting upon the quality of these reconstructions.
Limited evaluation of physical and mechanical properties of Nepal alder grown in Hawaii

Treesearch

C. C. Gerhards

1964-01-01

Nepal alder (Alnus nepalensis ) grown in Hawaii was evaluated for shrinkage, strength in bending, and hardness. This Hawaii-grown wood was comparable in bending strength to wood of the same species grown in Bengal, India, but was lower in modulus of elasticity and exhibited greater hardness and shrinkage. It was also harder than such Mainland species as aspen (Populus...
Fourfold Diels-Alder reaction of tetraethynylsilane.

PubMed

Geyer, Florian L; Rode, Alexander; Bunz, Uwe H F

2014-12-08

A series of ethynylated silanes, including tetraethynylsilane, was treated with tetraphenylcyclopentadienone at 300 °C under microwave irradiation to give the aromatized Diels-Alder adducts as sterically encumbered mini-dendrimers with up to 20 benzene rings. The sterically most congested adducts display red-shifted emission through intramolecular π-π interactions in the excited state. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Diels-Alder cycloadditions by microwave-assisted, continuous flow organic synthesis (MACOS): the role of metal films in the flow tube.

PubMed

Shore, Gjergji; Organ, Michael G

2008-02-21

Thin Pd films have been deposited on the inside of capillary-sized tubes through which compounds undergoing Diels-Alder reactions have been flowed while being heated with microwave irradiation; dramatic rate accelerations are observed in the presence of the film, which has been shown to play both a heating and catalytic role.
Indole synthesis by palladium-catalyzed tandem allylic isomerization - furan Diels-Alder reaction.

PubMed

Xu, Jie; Wipf, Peter

2017-08-30

A Pd(0)-catalyzed elimination of an allylic acetate generates a π-allyl complex that is postulated to initiate a novel intramolecular Diels-Alder cycloaddition to a tethered furan (IMDAF). Under the reaction conditions, this convergent, microwave-accelerated cascade process provides substituted indoles in moderate to good yields after Pd-hydride elimination, aromatization by dehydration, and in situ N-Boc cleavage.
Improving germination of red elm (Ulmus rubra), gray alder (Alnus incana), and buffaloberry (Shepherdia canadensis) seeds with gibberellic acid

Treesearch

Brenda Morales; Charles Barden; Cheryl Boyer; Jason Griffin; Lillian Fisher; Joni Thompson

2012-01-01

Red elm (Ulmus rubra), gray alder (Alnus incana), and buffaloberry (Shepherdia canadensis) are considered important plants for many Native American tribes in the United States. Native Americans use these 3 species for a variety of traditional and medicinal purposes. For example, red elm is still the preferred firewood for the cultural ceremonies of several tribes....
Diels-Alder Cycloadditions: A MORE Experiment in the Organic Laboratory Including a Diene Identification Exercise Involving NMR Spectroscopy and Molecular Modeling

ERIC Educational Resources Information Center

Shaw, Roosevelt; Severin, Ashika; Balfour, Miguel; Nettles, Columbus

2005-01-01

Two Diels-Alder reactions are described that are suitable for a MORE (microwave-induced organic reaction enhanced) experiment in the organic chemistry laboratory course. A second experiment in which the splitting patterns of the vinyl protons in the nuclear magnetic resonance (NMR) spectra of two MORE adducts are used in conjunction with molecular…
Diels-Alder Synthesis of endo-cis-N-phenylbicyclo[2.2.2]oct-5-en-2,3-dicarboximide

ERIC Educational Resources Information Center

Baar, Marsha R.; Wustholz, Kristin

2005-01-01

A study investigated the Diels-Alder synthesis of endo-cis-N-phenylbicyclo [2.2.2]oct-5-en-2,3-dicarboximide. The amount of time taken by a reaction between the 1,3-cyclohexadiene and N-phenylmaleimide at room temperature and also whether the desired cycloadduct would precipitate directly from the reaction mixture was examined.
Origins of Stereoselectivity in Diels-Alder Cycloadditions Catalyzed by Chiral Imidazolidinones

PubMed Central

Gordillo, Ruth; Houk, K. N.

2011-01-01

B3LYP/6-31G(d) density functional theory has been used to study Diels-Alder reactions of cyclopentadiene with α,β-unsaturated aldehydes and ketones organocatalyzed by MacMillan’s chiral imidazolidinones. Preferred conformations of transition structures and reaction intermediates have been located. The dramatically different reactivities and enantioselectivities exhibited by two similar chiral imidazolidinones are rationalized. PMID:16536527
Nutrients, Antioxidant Capacity and Safety of Hot Water Extract from Sugar Maple (Acer saccharum M.) and Red Maple (Acer rubrum L.) Bark.

PubMed

Bhatta, Sagar; Ratti, Cristina; Poubelle, Patrice E; Stevanovic, Tatjana

2018-03-01

Sugar maple (Acer saccharum M.) and red maple (Acer rubrum L.) barks were treated with hot water to extract nutrients in order to explore, for the first time, its potential as safe dietary antioxidants. The organic and inorganic nutrients of these extracts, as well as their safety on human PLB-985 cells differentiated into neutrophils-like cells, were determined. Proximate analysis showed that both bark extracts were low in moisture and fat. Sugar maple bark extract (SM-BX) showed crude protein and ash content higher than those found in red maple bark extract (RM-BX). In addition, SM-BX had total sugars higher than those evaluated in RM-BX, while complex sugars (oligo- and/or poly-saccharides) were similarly abundant in both bark extracts. Furthermore, SM-BX demonstrated a wide array of vital minerals (K, Ca, Mg, P, Na, Fe and Cu) in quantity larger than that evaluated in RM-BX, whereas RM-BX have Zn and Mn levels higher than those found in SM-BX. Phytochemical analyses showed that RM-BX exhibited total phenolic and flavonoid contents higher than those measured in SM-BX. Consequently, RM-BX presented an antioxidant activity higher than that of SM-BX: 2.85-fold ABTS radical cation scavenging capacity and 1.9-fold oxygen radical absorbance capacity. Finally, RM-BX and SM-BX were greatly safe since, at concentration up to 100 μg/ml, they did not modify the viability of neutrophils as determined by flow-cytometry assay using Annexin V-FITC/Propidum Iodide as markers. In conclusion, our in vitro studies indicate that both red and sugar maple bark extracts have a real potential as food additives.
William R. Maples, forensic historian: four men, four centuries, four countries.

PubMed

Goza, W M

1999-07-01

Prior to 1984, William R. Maples, Ph.D. worked primarily with Medical Examiners in the State of Florida in investigation of and testimony in criminal cases. In 1984 the Republic of Peru requested him to identify skeletal remains thought to be those of Francisco Pizarro, conqueror of Peru and the Incas in the early 16th Century. Dr. Maples made a positive identification of those remains as Pizarro, resulting in their substitution in a glass-sided coffin in the Cathedral of Lima, where other remains had been displayed as those of Pizarro for a hundred years. In addition, it was proved that the remains removed could not have been those of Pizarro. In 1988, Dr. Maples examined the skeletal remains of Joseph Merrick ("The Elephant Man") at Royal London Hospital, Whitechapel, and made photographic studies of them for comparison with death casts of limbs and skull to ascertain depth of tissue by video-superimposition. In 1991, Dr. Maples, headed a team which removed President Zachary Taylor (1779-1842) from his tomb in Louisville, Kentucky. The purpose was to determine if he had been poisoned, as had been proposed by some at the time. Test results showed that he had not been. In 1992, Dr. Maples and a team of forensic specialists went by invitation to Ekaterinburg, Russia to study skeletal remains which the Russians had tentatively identified as the Russian Royal Family, and entourage, murdered in 1918. The American team identified them as Tsar Nicholas II, his wife, three of his children, his physician, and three of his servants. William Ross Maples died in Gainesville, Florida, 27 February 1997.
Analysis of plastic residues in maple sap and syrup collected from tubing systems sanitized with isopropyl alcohol.

PubMed

Lagacé, Luc; Charron, Carmen; Sadiki, Mustapha

2017-05-01

A plastic tubing system operated under vacuum is usually used to collect sap from maple trees during spring time to produce maple syrup. This system is commonly sanitized with isopropyl alcohol (IPA) to remove microbial contamination colonizing the system during the sugar season. Questions have been raised whether IPA would contribute to the leaching of plastic residues in maple sap and syrup coming from sanitized systems. First, an extraction experiment was performed in the lab on commercial plastic tubing materials that were submitted to IPA under harsh conditions. The results of the GC-MS analysis revealed the presence of many compounds that served has target for further tests. Secondly, tests were done on early and mid-season maple sap and syrup coming from many sugarbushes using IPA or not to determine potential concentrations of plastic residues. Results obtained from sap and syrup samples showed that no quantifiable (< 1-75 μg/L) concentration of any plastic molecules tested was determined in all samples coming from IPA treated or not treated systems. However, some samples of first sap run used as a rinse solution to be discarded before the season start and that were coming from non sanitized or IPA sanitized systems, showed quantifiable concentrations of chemical residue such as ultraviolet protector (octabenzone). These results show that IPA can be safely used to sanitize maple sap collection system in regards to the leaching of plastic residues in maple sap and syrup and reinforced the need to thoroughly rinse the tubing system at the beginning of the season for both sanitized and non sanitized systems.
Flambeau Mining Corporation, Ladysmith, Rusk County, Wisconsin. Proposed Open Pit Copper Mine and Waste Containment Area, Draft Environmental Impact Statement.

DTIC Science & Technology

1976-08-01

American elm Lonicera tatarica - tartarian honeysuckle Ulmus rubra - slippery elm Siiibucus canadenis - common elder Ulmus thoiii~sii - cork elm ...community borders the marshes and swamps. 2.060 The predominant species are the trembling aspen (Populus tremuloides), red maple (Acer rubrum), the elms ...succession. The most numerous trees (in descending order) are: white birch, red maple, aspen, sugar maple, black ash, basswood, elm (Ulmus sp.), hemlock
Improved detection of sugar addition to maple syrup using malic acid as internal standard and in 13C isotope ratio mass spectrometry (IRMS).

PubMed

Tremblay, Patrice; Paquin, Réal

2007-01-24

Stable carbon isotope ratio mass spectrometry (delta13C IRMS) was used to detect maple syrup adulteration by exogenous sugar addition (beet and cane sugar). Malic acid present in maple syrup is proposed as an isotopic internal standard to improve actual adulteration detection levels. A lead precipitation method has been modified to isolate quantitatively malic acid from maple syrup using preparative reversed-phase liquid chromatography. The stable carbon isotopic ratio of malic acid isolated from this procedure shows an excellent accuracy and repeatability of 0.01 and 0.1 per thousand respectively, confirming that the modified lead precipitation method is an isotopic fractionation-free process. A new approach is proposed to detect adulteration based on the correlation existing between the delta13Cmalic acid and the delta13Csugars-delta13Cmalic acid (r = 0.704). This technique has been tested on a set of 56 authentic maple syrup samples. Additionally, authentic samples were spiked with exogeneous sugars. The mean theoretical detection level was statistically lowered using this technique in comparison with the usual two-standard deviation approach, especially when maple syrup is adulterated with beet sugar : 24 +/- 12% of adulteration detection versus 48 +/- 20% (t-test, p = 7.3 x 10-15). The method was also applied to published data for pineapple juices and honey with the same improvement.
Competition for nitrogen between Fagus sylvatica and Acer pseudoplatanus seedlings depends on soil nitrogen availability.

PubMed

Li, Xiuyuan; Rennenberg, Heinz; Simon, Judy

2015-01-01

Competition for nitrogen (N), particularly in resource-limited habitats, might be avoided by different N acquisition strategies of plants. In our study, we investigated whether slow-growing European beech and fast-growing sycamore maple seedlings avoid competition for growth-limiting N by different N uptake patterns and the potential alteration by soil N availability in a microcosm experiment. We quantified growth and biomass indices, (15)N uptake capacity and N pools in the fine roots. Overall, growth indices, N acquisition and N pools in the fine roots were influenced by species-specific competition depending on soil N availability. With inter-specific competition, growth of sycamore maple reduced regardless of soil N supply, whereas beech only showed reduced growth when N was limited. Both species responded to inter-specific competition by alteration of N pools in the fine roots; however, sycamore maple showed a stronger response compared to beech for almost all N pools in roots, except for structural N at low soil N availability. Beech generally preferred organic N acquisition while sycamore maple took up more inorganic N. Furthermore, with inter-specific competition, beech had an enhanced organic N uptake capacity, while in sycamore maple inorganic N uptake capacity was impaired by the presence of beech. Although sycamore maple could tolerate the suboptimal conditions at the cost of reduced growth, our study indicates its reduced competitive ability for N compared to beech.
How Does Salinity Shape Bacterial and Fungal Microbiomes of Alnus glutinosa Roots?

PubMed Central

Thiem, Dominika; Gołębiewski, Marcin; Hulisz, Piotr; Piernik, Agnieszka; Hrynkiewicz, Katarzyna

2018-01-01

Black alder (Alnus glutinosa Gaertn.) belongs to dual mycorrhizal trees, forming ectomycorrhizal (EM) and arbuscular (AM) root structures, as well as represents actinorrhizal plants that associate with nitrogen-fixing actinomycete Frankia sp. We hypothesized that the unique ternary structure of symbionts can influence community structure of other plant-associated microorganisms (bacterial and fungal endophytes), particularly under seasonally changing salinity in A. glutinosa roots. In our study we analyzed black alder root bacterial and fungal microbiome present at two forest test sites (saline and non-saline) in two different seasons (spring and fall). The dominant type of root microsymbionts of alder were ectomycorrhizal fungi, whose distribution depended on site (salinity): Tomentella, Lactarius, and Phialocephala were more abundant at the saline site. Mortierella and Naucoria (representatives of saprotrophs or endophytes) displayed the opposite tendency. Arbuscular mycorrhizal fungi belonged to Glomeromycota (orders Paraglomales and Glomales), however, they represented less than 1% of all identified fungi. Bacterial community structure depended on test site but not on season. Sequences affiliated with Rhodanobacter, Granulicella, and Sphingomonas dominated at the saline site, while Bradyrhizobium and Rhizobium were more abundant at the non-saline site. Moreover, genus Frankia was observed only at the saline site. In conclusion, bacterial and fungal community structure of alder root microsymbionts and endophytes depends on five soil chemical parameters: salinity, phosphorus, pH, saturation percentage (SP) as well as total organic carbon (TOC), and seasonality does not appear to be an important factor shaping microbial communities. Ectomycorrhizal fungi are the most abundant symbionts of mature alders growing in saline soils. However, specific distribution of nitrogen-fixing Frankia (forming root nodules) and association of arbuscular fungi at early stages of plant development should be taken into account in further studies. PMID:29720967
How Does Salinity Shape Bacterial and Fungal Microbiomes of Alnus glutinosa Roots?

PubMed

Thiem, Dominika; Gołębiewski, Marcin; Hulisz, Piotr; Piernik, Agnieszka; Hrynkiewicz, Katarzyna

2018-01-01

Black alder ( Alnus glutinosa Gaertn.) belongs to dual mycorrhizal trees, forming ectomycorrhizal (EM) and arbuscular (AM) root structures, as well as represents actinorrhizal plants that associate with nitrogen-fixing actinomycete Frankia sp. We hypothesized that the unique ternary structure of symbionts can influence community structure of other plant-associated microorganisms (bacterial and fungal endophytes), particularly under seasonally changing salinity in A. glutinosa roots. In our study we analyzed black alder root bacterial and fungal microbiome present at two forest test sites (saline and non-saline) in two different seasons (spring and fall). The dominant type of root microsymbionts of alder were ectomycorrhizal fungi, whose distribution depended on site (salinity): Tomentella , Lactarius , and Phialocephala were more abundant at the saline site. Mortierella and Naucoria (representatives of saprotrophs or endophytes) displayed the opposite tendency. Arbuscular mycorrhizal fungi belonged to Glomeromycota (orders Paraglomales and Glomales), however, they represented less than 1% of all identified fungi. Bacterial community structure depended on test site but not on season. Sequences affiliated with Rhodanobacter , Granulicella , and Sphingomonas dominated at the saline site, while Bradyrhizobium and Rhizobium were more abundant at the non-saline site. Moreover, genus Frankia was observed only at the saline site. In conclusion, bacterial and fungal community structure of alder root microsymbionts and endophytes depends on five soil chemical parameters: salinity, phosphorus, pH, saturation percentage (SP) as well as total organic carbon (TOC), and seasonality does not appear to be an important factor shaping microbial communities. Ectomycorrhizal fungi are the most abundant symbionts of mature alders growing in saline soils. However, specific distribution of nitrogen-fixing Frankia (forming root nodules) and association of arbuscular fungi at early stages of plant development should be taken into account in further studies.
Biomass of Speckled Alder on an Air-Polluted Mountain Site and its Response to Fertilization

NASA Astrophysics Data System (ADS)

Kuneš, Ivan; Baláš, Martin; Koňasová, Tereza; Špulák, Ondřej; Balcar, Vratislav; Millerová, Kateřina Bednářová; Kacálek, Dušan; Jakl, Michal; Zahradník, Daniel; Vítámvás, Jan; Š´astná, Jaroslava; Jaklová Dytrtová, Jana

2014-12-01

The article summarizes outcomes of a biomass study conducted in a young speckled alder plantation on a cold mountain site. At this location, the previously existing old forest was clear felled because of damage from air pollution, and present-day surface humus is in need of restoration. The intention of this study was to quantify the biomass and nutrients accumulated by alders and their components and assess whether the initial fertilization resulted in increased biomass production and nutrient accumulation in the biomass. Besides the control, two fertilized treatments were installed. In the surface treatment (SUT), the amendment was applied as a base dressing in small circles around trees. In the planting-hole treatment (PHT), the amendment was incorporated into soil inside the planting holes. Five growth seasons after planting and fertilization, six alders from each treatment were harvested including roots. Their biomass was quantified and analyzed for macroelements. The greatest pool of dry mass (DM) was branches in the control and stem wood in the fertilized treatments. The greatest pools of macroelements were leaves and branches. The most pronounced effects of fertilization were recorded in the DM and consequently in the absolute quantities of nutrients. The DM of an average tree in the control, SUT, and PHT was 85, 226, and 231 g, respectively. The absolute contents of nutrients per tree in the fertilized treatments showed the following increases, as compared with the control: (N) 2.5-2.6 times; (P) 1.6-2.4 times; (K) 1.8-2.1 times; and (Mg) 1.8-2.0 times, respectively. Speckled alder responded positively to fertilization.
Symbiotic maple saps minimize disruption of the mice intestinal microbiota after oral antibiotic administration.

PubMed

Hammami, Riadh; Ben Abdallah, Nour; Barbeau, Julie; Fliss, Ismail

2015-01-01

This study was undertaken to evaluate the in vivo impact of new symbiotic products based on liquid maple sap or its concentrate. Sap and concentrate, with or without inulin (2%), were inoculated with Bifidobacterium lactis Bb12 and Lactobacillus rhamnosus GG valio at initial counts of 2-4 × 10(8) cfu mL(-1). The experiments started with intra-gastric administration of antibiotic (kanamycin 40 mg in 0.1 cc) (to induce microbiota disturbance and/or diarrhea) to 3-to-5-week-old C57BL/6 female mice followed by a combination of prebiotic and probiotics included in the maple sap or its concentrate for a week. The combination inulin and probiotics in maple sap and concentrate appeared to minimize the antibiotic-induced breakdown of mice microbiota with a marked effect on bifidobacterium and bacteroides levels, thus permitting a more rapid re-establishment of the baseline microbiota levels. Results suggest that maple sap and its concentrate represent good candidates for the production of non-dairy functional foods.
Synthesis of a Self-Healing Polymer Based on Reversible Diels-Alder Reaction: An Advanced Undergraduate Laboratory at the Interface of Organic Chemistry and Materials Science

ERIC Educational Resources Information Center

Weizman, Haim; Nielsen, Christian; Weizman, Or S.; Nemat-Nasser, Sia

2011-01-01

This laboratory experiment exposes students to the chemistry of self-healing polymers based on a Diels-Alder reaction. Students accomplish a multistep synthesis of a monomer building block and then polymerize it to form a cross-linked polymer. The healing capability of the polymer is verified by differential scanning calorimetry (DSC) experiments.…
Syntheses of the hexahydroindene cores of indanomycin and stawamycin by combinations of iridium-catalyzed asymmetric allylic alkylations and intramolecular Diels-Alder reactions.

PubMed

Gärtner, Martin; Satyanarayana, Gedu; Förster, Sebastian; Helmchen, Günter

2013-01-02

Short and concise syntheses of the hexahydroindene cores of the antibiotics indanomycin (X-14547 A) and stawamycin are presented. Key methods used are an asymmetric iridium-catalyzed allylic alkylation, a modified Julia olefination, a Suzuki-Miyaura coupling, and an intramolecular Diels-Alder reaction. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Processing Conjugated-Diene-Containing Polymers

NASA Technical Reports Server (NTRS)

Bell, Vernon L.; Havens, Stephen J.

1987-01-01

Diels-Alder reaction used to cross-linked thermoplastics. Process uses Diels-Alder reaction to cross-link and/or extend conjugated-diene-containing polymers by reacting them with bis-unsaturated dienophiles results in improved polymer properties. Quantities of diene groups required for cross-linking varies from very low to very high concentrations. Process also used to extend, or build up molecular weights of, low-molecular-weight linear polymers with terminal conjugated dienic groups.
Fast Hetero-Diels-Alder Reactions Using 4-Phenyl-1,2,4-Triazoline-3,5-Dione (PTAD) as the Dienophile

ERIC Educational Resources Information Center

Celius, Tevye C.

2010-01-01

A hetero-Diels-Alder reaction that proceeds rapidly and only requires a simple filtration to purify the product is presented. The dienophile, 4-phenyl-1,2,4-triazoline-3,5-dione (PTAD), is prepared by the heterogeneous oxidation of 4-phenylurazole by the bromenium ion, Br[superscript +], generated in situ by the oxidation of potassium bromide by…

Development of annualized diameter and height growth equations for red alder: preliminary results.

Treesearch

Aaron Weiskittel; Sean M. Garber; Greg Johnson; Doug Maguire; Robert A. Monserud

2006-01-01

Most individual-tree based growth and yield models use a 5- to 10-year time step, which can make projections for a fast-growing species like red alder quite difficult. Further, it is rather cumbersome to simulate the effects of intensive silvicultural treatments such as thinning or pruning on a time step longer than one year given the highly dynamic nature of growth...
Multicatalytic asymmetric synthesis of complex tetrahydrocarbazoles via a Diels-Alder/benzoin reaction sequence.

PubMed

Liu, Yankai; Nappi, Manuel; Escudero-Adán, Eduardo C; Melchiorre, Paolo

2012-03-02

Expanding upon the recently developed aminocatalytic asymmetric indole-2,3-quinodimethane strategy, a straightforward synthesis of structurally and stereochemically complex tetrahydrocarbazoles has been devised. The chemistry's complexity-generating power was further harnessed by designing a multicatalytic, one-pot Diels-Alder/benzoin reaction sequence to stereoselectively access trans-fused tetracyclic indole-based compounds having four stereogenic centers with very high fidelity. © 2012 American Chemical Society
Influence of red alder on chemical properties of a clay loam soil in western Washington.

Treesearch

D.S. DeBell; M.A. Radwan; J.M. Kraft

1983-01-01

Chemical characteristics of mineral soil beneath red alder (Alnus rubra Bong.) stands of various ages were studied. Total nitrogen (N) of the 0-to 20-centimeter (0- to 8-inch) soil layer increased with stand age, and pH of both the 0- to 20-centimeter and 20- to 50-centimeter (8- to 20-inch) layers decreased with stand age. Contents of some mineral...
Simultaneous analysis of 70 pesticides using HPlc/MS/MS: a comparison of the multiresidue method of Klein and Alder and the QuEChERS method.

PubMed

Riedel, Melanie; Speer, Karl; Stuke, Sven; Schmeer, Karl

2010-01-01

Since 2003, two new multipesticide residue methods for screening crops for a large number of pesticides, developed by Klein and Alder and Anastassiades et al. (Quick, Easy, Cheap, Effective, Rugged, and Safe; QuEChERS), have been published. Our intention was to compare these two important methods on the basis of their extraction efficiency, reproducibility, ruggedness, ease of use, and speed. In total, 70 pesticides belonging to numerous different substance classes were analyzed at two concentration levels by applying both methods, using five different representative matrixes. In the case of the QuEChERS method, the results of the three sample preparation steps (crude extract, extract after SPE, and extract after SPE and acidification) were compared with each other and with the results obtained with the Klein and Alder method. The extraction efficiencies of the QuEChERS method were far higher, and the sample preparation was much quicker when the last two steps were omitted. In most cases, the extraction efficiencies after the first step were approximately 100%. With extraction efficiencies of mostly less than 70%, the Klein and Alder method did not compare favorably. Some analytes caused problems during evaluation, mostly due to matrix influences.
Silica-promoted Diels-Alder reactions in carbon dioxide from gaseous to supercritical conditions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Weinstein, R.D.; Renslo, A.R.; Danheiser, R.L.

1999-04-15

Amorphous fumed silica (SiO{sub 2}) was shown to increase yields and selectivities of several Diels-Alder reactions in gaseous and supercritical CO{sub 2}. Pressure effects on the Diels-Alder reaction were explored using methyl vinyl ketone and penta-1,3-diene at 80 C. The selectivity of the reaction was not affected by pressure/density. As pressure was increased, the yield decreased. At the reaction temperature, adsorption isotherms at various pressures were obtained for the reactants and the Diels-Alder adduct. As expected when pressure is increased, the ratio of the amount of reactants adsorbed to the amount of reactants in the fluid phase decreases, thus causingmore » the yield to decrease. The Langmuir adsorption model fit the adsorption data. The Langmuir equilibrium partitioning constants all decreased with increasing pressure. The effect of temperature on adsorption was experimentally determined and traditional heats of adsorption were calculated. However, since supercritical CO{sub 2} is a highly compressible fluid, it is logical to examine the effect of temperature at constant density. In this case, entropies of adsorption were obtained. The thermodynamic properties that influence the real enthalpy and entropy of adsorption were derived. Methods of doping the silica and improving yields and selectivities were also explored.« less
Enantioselective Diels-Alder reactions of unsaturated beta-ketoesters catalyzed by chiral ruthenium PNNP complexes.

PubMed

Schotes, Christoph; Mezzetti, Antonio

2011-01-01

We report here dicationic ruthenium PNNP complexes that promote the enantioselective Diels-Alder reaction of alpha-methylene beta-ketoesters with various dienes. Complex [Ru(OEt2)2(PNNP)](PF6)2, formed in situ from [RuCl2,(PNNP)] and (Et3O)PF6 (2 equiv.), catalyzes the Diels-Alder reaction of such unsaturated beta-ketoesters to give novel alkoxycarbonyltetrahydro-1-indanone derivatives (nine examples) with up to 93% ee. The crystal structure of the substrate-catalyst adduct shows that the lower face of the substrate is shielded by a phenyl ring of the PNNP ligand, which accounts for the high enantioselectivity. The attack of the diene from the open re enantioface of the unsaturated beta-ketoester is consistent with the absolute configuration of the product. A useful application of this method is the reaction with Dane's diene to give estrone derivatives with up to 99% ee and an ester-exo:endo ratio of up to 145:1 (after recrystallization). Besides the enantioselective formation of all-carbon quaternary centers, this methodology is notable because unsaturated beta-ketoesters have been rarely used in Diels-Alder reactions. Furthermore, enantiomerically pure estrone derivatives are interesting in view of their potential applications, including the treatment of breast cancer.
Jackson Mills and Mine Falls Dams, Nashua, New Hampshire. Reconnaissance Report, Hydroelectric Feasibility. Volume 1, Jackson Mills Dam.

DTIC Science & Technology

1979-12-01

Catalpa Solidago sp. Goldenrod Aster novae - angliae New England Aster Acer saccharum Sugar Maple Ulmus rubra Slippery elm Solanum hi rum Common...red pine, and hemlock are the common softwood species, and the common hardwood species include red maple, silver maple, white oak, willow, slippery ... elm and birch. In 1972, between 70 and 7S percent of the total area of the watershed consisted of forests and primarily wooded land. (Reference 3
Xylary pH and Reduction Potential Levels of Iron-stressed Silver Maple (Acer saccharinum L.) 1

PubMed Central

Morris, Robert L.; Swanson, Bert T.

1980-01-01

Xylary fluid pH and reduction potentials were measured on silver maple (Acer saccharinum L.) grown under Fe and pH stress. Although pH and reduction potential (millivolt/59.2) varied significantly in the nutrient solution, xylary pH and reduction potential remained constant. It was concluded that changes in the pH and reduction potential in the xylary fluid of silver maple are not responsible for iron chlorosis. PMID:16661196
Flowering phenology and its implications for management of big-leaf mahogany Swietenia macrophylla in Brazilian Amazonia.

PubMed

Grogan, James; Loveless, Marilyn D

2013-11-01

Flowering phenology is a crucial determinant of reproductive success and offspring genetic diversity in plants. We measure the flowering phenology of big-leaf mahogany (Swietenia macrophylla, Meliaceae), a widely distributed neotropical tree, and explore how disturbance from logging impacts its reproductive biology. We use a crown scoring system to estimate the timing and duration of population-level flowering at three forest sites in the Brazilian Amazon over a five-year period. We combine this information with data on population structure and spatial distribution to consider the implications of logging for population flowering patterns and reproductive success. Mahogany trees as small as 14 cm diam flowered, but only trees > 30 cm diam flowered annually or supra-annually. Mean observed flowering periods by focal trees ranged from 18-34 d, and trees flowered sequentially during 3-4 mo beginning in the dry season. Focal trees demonstrated significant interannual correlation in flowering order. Estimated population-level flowering schedules resembled that of the focal trees, with temporal isolation between early and late flowering trees. At the principal study site, conventional logging practices eliminated 87% of mahogany trees > 30 cm diam and an estimated 94% of annual pre-logging floral effort. Consistent interannual patterns of sequential flowering among trees create incompletely isolated subpopulations, constraining pollen flow. After harvests, surviving subcommercial trees will have fewer, more distant, and smaller potential partners, with probable consequences for post-logging regeneration. These results have important implications for the sustainability of harvesting systems for tropical timber species.
Design challenges for matrix assisted pulsed laser evaporation and infrared resonant laser evaporation equipment

NASA Astrophysics Data System (ADS)

Greer, James A.

2011-11-01

Since the development of the Matrix Assisted Pulsed Laser Evaporation (MAPLE) process by the Naval Research Laboratory (NRL) in the late 1990s, MAPLE has become an active area of research for the deposition of a variety of polymer, biological, and organic thin films. As is often the case with advancements in thin-film deposition techniques new technology sometimes evolves by making minor or major adjustments to existing deposition process equipment and techniques. This is usually the quickest and least expensive way to try out new ideas and to "push the envelope" in order to obtain new and unique scientific results as quickly as possible. This process of "tweaking" current equipment usually works to some degree, but once the new process is further refined overall designs for a new deposition tool based on the critical attributes of the new process typically help capitalize more fully on the all the salient features of the new and improved process. This certainly has been true for the MAPLE process. In fact the first MAPLE experiments the polymer/solvent matrix was mixed and poured into a copper holder held at LN2 temperature on a laboratory counter top. The holder was then quickly placed onto a LN2 cooled reservoir in a vacuum deposition chamber and placed in a vertical position on a LN2 cooled stage and pumped down as quickly as possible. If the sample was not placed into the chamber quickly enough the frozen matrix would melt and drip into the bottom of the chamber onto the chambers main gate valve making a bit of a mess. However, skilled and motivated scientists usually worked quickly enough to make this process work most of the time. The initial results from these experiments were encouraging and led to several publications which sparked considerable interest in this newly developed technique Clearly this approach provided the vision that MAPLE was a viable deposition process, but the equipment was not optimal for conducting MAPLE experiments on a regular basis for several reasons. The first reason is that the polymer/solvent mix as well as the sample holder are both exposed to the humidity in the air which will coat the entire surface of the holder and target with water vapor. Some polymer and/or solvent materials may not react well with water vapor. Also, the layer of water vapor absorbed on the target surface may then absorb the incident laser radiation until it is removed from the surface. Thus, it may be unclear when the water vapor is fully removed from the polymer/solvent surface and the MAPLE deposition process actually occurs. This makes deposition of specific polymer thickness difficult to calculate. While it is well known that Quartz crystal microbalances do not work well for PLD of oxide materials it can be used for the deposition of MAPLE materials. However, with rastered laser beams the tooling factor becomes a dynamic number making interpretation of final thickness potentially difficult without careful pre-calibration. Another serious issue with the initial MAPLE process was related to the use of UV lasers such as an excimer operating at 193- or 248-nm or frequency tripled, Nd:YAG lasers at 355 nm. These lasers have high energy per photon (between about 6.4 to 3.5 eV) which can lead to a variety of deleterious photochemical mechanisms that can damage the polymer chains or organic structure. Such mechanisms can be direct photo-decomposition by photochemical bond breaking and photothermal effects. Alternative lasers, such as a Er:YAG laser operating at 2.9 microns produce photons with energy of ˜0.43 eV. Such longer wavelength lasers have been used for the IR-MAPLE process and may be very useful for future MAPLE systems. A third issue with the initial approach to MAPLE was that the process did not lend itself easily to growing multilayer films. Most standard pulsed laser deposition tools have "multi-target" carousels that allow for easy target changes and multilayer film growth. This is true for sputtering, MBE, and evaporation equipment as well. This multilayer feature would certainly benefit the MAPLE process for the growth of multilayer organic materials. Another more recent advancement in thin-film laser deposition is that of Resonant Infra Red Pulsed Laser Deposition (RIRPLD) of polymer materials. This process is more akin to standard PLD but uses tunable lasers with which to select the proper wavelength to couple to vibration bands of a solid polymer, or in some cases a polymer/solvent MAPLE mixture. This technique was developed under a collaboration of researchers at the Naval Research Labs and the Free Electron Laser (FEL) at Vanderbilt University. The wide tuning range of the FEL and its relatively high power make it a very attractive source for RIRPLD. However, the price of such lasers—of order several million dollars in capital costs alone—is very high and well beyond the budgets of most research institutions. Advances in RIRPLD are currently limited due to the scarcity of tunable lasers with sufficient power in the IR range of interest to obtain reasonable deposition rates. Over the past nine years commercial equipment for MAPLE has been on the market and new lasers are being developed that may significantly improve MAPLE and RIRPLD capabilities. Examples of basic single-target MAPLE equipment, as well as multiple target MAPLE systems are described. Discussion of current lasers for MAPLE and RIRPLD are given. Finally, even though these processes have been around for a significant amount of time there are still many unknowns associated with these techniques that still should be explored before these processes can be used for production of useful products. Some of these issues which need to be addressed will be discussed.
Artificial Sweeteners and Other Sugar Substitutes

MedlinePlus

... Lactitol Honey Sucralose (Splenda) Maltitol Maple syrup Mannitol Molasses Sorbitol Xylitol Advantame The topic of sugar substitutes ... for consumption are fruit juices and nectars, honey, molasses, and maple syrup. Natural sweeteners have a variety ...
Growth and development of browsed seedlings

Treesearch

Thomas R. Crow; Frederick T. Metzger

1992-01-01

For long it was assumed that deer browsing on the terminal shoot of sugar maple was detrimental to height growth, stem form, and vigor. Does browsing permanently damage sugar maple in northern hardwood stands?
29 CFR 780.816 - Processing of specific commodities.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Employment in Ginning of Cotton and Processing of Sugar Beets, Sugar-Beet Molasses, Sugarcane, or Maple Sap... processing of sugar beets, sugar-beet molasses, sugarcane, or maple sap is within the exemption. Operations...
29 CFR 780.816 - Processing of specific commodities.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Employment in Ginning of Cotton and Processing of Sugar Beets, Sugar-Beet Molasses, Sugarcane, or Maple Sap... processing of sugar beets, sugar-beet molasses, sugarcane, or maple sap is within the exemption. Operations...
29 CFR 780.801 - Statutory provisions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Ginning of Cotton and Processing of Sugar Beets, Sugar-Beet Molasses, Sugarcane, or Maple Sap into Sugar..., sugar-beet molasses, sugarcane, or maple sap, into sugar (other than refined sugar) or syrup. Section 13...
29 CFR 780.801 - Statutory provisions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Ginning of Cotton and Processing of Sugar Beets, Sugar-Beet Molasses, Sugarcane, or Maple Sap into Sugar..., sugar-beet molasses, sugarcane, or maple sap, into sugar (other than refined sugar) or syrup. Section 13...
29 CFR 780.816 - Processing of specific commodities.

Code of Federal Regulations, 2013 CFR

2013-07-01

... Employment in Ginning of Cotton and Processing of Sugar Beets, Sugar-Beet Molasses, Sugarcane, or Maple Sap... processing of sugar beets, sugar-beet molasses, sugarcane, or maple sap is within the exemption. Operations...
29 CFR 780.801 - Statutory provisions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... Ginning of Cotton and Processing of Sugar Beets, Sugar-Beet Molasses, Sugarcane, or Maple Sap into Sugar..., sugar-beet molasses, sugarcane, or maple sap, into sugar (other than refined sugar) or syrup. Section 13...
29 CFR 780.801 - Statutory provisions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... Ginning of Cotton and Processing of Sugar Beets, Sugar-Beet Molasses, Sugarcane, or Maple Sap into Sugar..., sugar-beet molasses, sugarcane, or maple sap, into sugar (other than refined sugar) or syrup. Section 13...
29 CFR 780.816 - Processing of specific commodities.

Code of Federal Regulations, 2014 CFR

2014-07-01

... Employment in Ginning of Cotton and Processing of Sugar Beets, Sugar-Beet Molasses, Sugarcane, or Maple Sap... processing of sugar beets, sugar-beet molasses, sugarcane, or maple sap is within the exemption. Operations...

29 CFR 780.816 - Processing of specific commodities.

Code of Federal Regulations, 2012 CFR

2012-07-01

... Employment in Ginning of Cotton and Processing of Sugar Beets, Sugar-Beet Molasses, Sugarcane, or Maple Sap... processing of sugar beets, sugar-beet molasses, sugarcane, or maple sap is within the exemption. Operations...
29 CFR 780.801 - Statutory provisions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... Ginning of Cotton and Processing of Sugar Beets, Sugar-Beet Molasses, Sugarcane, or Maple Sap into Sugar..., sugar-beet molasses, sugarcane, or maple sap, into sugar (other than refined sugar) or syrup. Section 13...
Red Maple (Acer rubrum) Aerial Parts as a Source of Bioactive Phenolics.

PubMed

Zhang, Yan; Ma, Hang; Yuan, Tao; Seeram, Navindra P

2015-08-01

The bark and stems of red maple (Acer rubrum) are reported to contain bioactive phenolics but its aerial parts, namely, flowers and leaves, remain largely unexplored. This is unfortunate considering that various parts of the red maple were used for traditional medicinal purposes by the indigenous peoples of eastern North America, where this species is found. Herein, we report the identification of twenty-five (1-25) phenolics, including two new galloyl derivatives (1 and 2), from red maple flowers and leaves. Of these, ten compounds (1-10), including the new compounds, were isolated and identified by NMR and HRESIMS data while the remaining fifteen compounds (11-25) were identified by HPLC-DAD analyses (by comparison with chemical standards). The isolates (1-10), along with the clinical drug, acarbose, were evaluated for their alpha-glucosidase enzyme inhibitory activities.
Competition for nitrogen between Fagus sylvatica and Acer pseudoplatanus seedlings depends on soil nitrogen availability

PubMed Central

Li, Xiuyuan; Rennenberg, Heinz; Simon, Judy

2015-01-01

Competition for nitrogen (N), particularly in resource-limited habitats, might be avoided by different N acquisition strategies of plants. In our study, we investigated whether slow-growing European beech and fast-growing sycamore maple seedlings avoid competition for growth-limiting N by different N uptake patterns and the potential alteration by soil N availability in a microcosm experiment. We quantified growth and biomass indices, 15N uptake capacity and N pools in the fine roots. Overall, growth indices, N acquisition and N pools in the fine roots were influenced by species-specific competition depending on soil N availability. With inter-specific competition, growth of sycamore maple reduced regardless of soil N supply, whereas beech only showed reduced growth when N was limited. Both species responded to inter-specific competition by alteration of N pools in the fine roots; however, sycamore maple showed a stronger response compared to beech for almost all N pools in roots, except for structural N at low soil N availability. Beech generally preferred organic N acquisition while sycamore maple took up more inorganic N. Furthermore, with inter-specific competition, beech had an enhanced organic N uptake capacity, while in sycamore maple inorganic N uptake capacity was impaired by the presence of beech. Although sycamore maple could tolerate the suboptimal conditions at the cost of reduced growth, our study indicates its reduced competitive ability for N compared to beech. PMID:25983738
Calcium and aluminum impacts on sugar maple physiology in a northern hardwood forest.

PubMed

Halman, Joshua M; Schaberg, Paul G; Hawley, Gary J; Pardo, Linda H; Fahey, Timothy J

2013-11-01

Forests of northeastern North America have been exposed to anthropogenic acidic inputs for decades, resulting in altered cation relations and disruptions to associated physiological processes in multiple tree species, including sugar maple (Acer saccharum Marsh.). In the current study, the impacts of calcium (Ca) and aluminum (Al) additions on mature sugar maple physiology were evaluated at the Hubbard Brook Experimental Forest (Thornton, NH, USA) to assess remediation (Ca addition) or exacerbation (Al addition) of current acidified conditions. Fine root cation concentrations and membrane integrity, carbon (C) allocation, foliar cation concentrations and antioxidant activity, foliar response to a spring freezing event and reproductive ability (flowering, seed quantity, filled seed and seed germination) were evaluated for dominant sugar maple trees in a replicated plot study. Root damage and foliar antioxidant activity were highest in Al-treated trees, while growth-associated C, foliar re-flush following a spring frost and reproductive ability were highest in Ca-treated trees. In general, we found that trees on Ca-treated plots preferentially used C resources for growth and reproductive processes, whereas Al-treated trees devoted C to defense-based processes. Similarities between Al-treated and control trees were observed for foliar cation concentrations, C partitioning and seed production, suggesting that sugar maples growing in native forests may be more stressed than previously perceived. Our experiment suggests that disruption of the balance of Ca and Al in sugar maples by acid deposition continues to be an important driver of tree health.
Juvenile wood effect in red alder : analysis of physical and mechanical data to delineate juvenile and mature wood zones

Treesearch

Joel W. Evans; John F. Senft; David W. Green

2000-01-01

The objective of this study was to investigate the influence of juvenile wood on the mechanical and physical properties of red alder. Tree growth in the first 10 to 20 years, usually referred to as juvenile wood, often influences wood quality by adversely affecting mechanical strength properties. Strength can be reduced up to 50 percent by the presence of juvenile wood...
Effects of fertilization on growth and foliar nutrients of red alder seedlings.

Treesearch

M.A. Radwan

1987-01-01

Effects of P, K, Ca, Mg, S, Co, and Mo fertilizers on growth and foliar nutrients of red alder seedlings potted in Grove, Bunker, and Wishkah forest soils were determined. Growth in Grove soil was stimulated most by P, Ca, and P + Ca + Mg + K + S. Growth in Bunker soil was improved only by P. In Wishkah soil, best growth was obtained when P was used alone; all...
A Thermal Dehydrogenative Diels–Alder Reaction of Styrenes for the Concise Synthesis of Functionalized Naphthalenes

PubMed Central

Kocsis, Laura S.; Benedetti, Erica

2012-01-01

Functionalized naphthalenes are valuable building blocks in many important areas. A microwave-assisted, intramolecular dehydrogenative Diels-Alder reaction of styrenyl derivatives to provide cyclopenta[b]naphthalene substructures not previously accessible using existing synthetic methods is described. The synthetic utility of these uniquely functionalized naphthalenes was demonstrated by a single-step conversion of one of these cycloadducts to a fluorophore bearing a structural resemblance to Prodan. PMID:22913473
A thermal dehydrogenative Diels-Alder reaction of styrenes for the concise synthesis of functionalized naphthalenes.

PubMed

Kocsis, Laura S; Benedetti, Erica; Brummond, Kay M

2012-09-07

Functionalized naphthalenes are valuable building blocks in many important areas. A microwave-assisted, intramolecular dehydrogenative Diels-Alder reaction of styrenyl derivatives to provide cyclopenta[b]naphthalene substructures not previously accessible using existing synthetic methods is described. The synthetic utility of these uniquely functionalized naphthalenes was demonstrated by a single-step conversion of one of these cycloadducts to a fluorophore bearing a structural resemblance to Prodan.
Structural basis for Diels-Alder ribozyme-catalyzed carbon-carbon bond formation

PubMed Central

Serganov, Alexander; Keiper, Sonja; Malinina, Lucy; Tereshko, Valentina; Skripkin, Eugene; Höbartner, Claudia; Polonskaia, Anna; Phan, Anh Tuân; Wombacher, Richard; Micura, Ronald; Dauter, Zbigniew; Jäschke, Andres; Patel, Dinshaw J

2015-01-01

The majority of structural efforts addressing RNA’s catalytic function have focused on natural ribozymes, which catalyze phosphodiester transfer reactions. By contrast, little is known about how RNA catalyzes other types of chemical reactions. We report here the crystal structures of a ribozyme that catalyzes enantioselective carbon-carbon bond formation by the Diels-Alder reaction in the unbound state and in complex with a reaction product. The RNA adopts a λ-shaped nested pseudoknot architecture whose preformed hydrophobic pocket is precisely complementary in shape to the reaction product. RNA folding and product binding are dictated by extensive stacking and hydrogen bonding, whereas stereoselection is governed by the shape of the catalytic pocket. Catalysis is apparently achieved by a combination of proximity, complementarity and electronic effects. We observe structural parallels in the independently evolved catalytic pocket architectures for ribozyme- and antibody-catalyzed Diels-Alder carbon-carbon bond-forming reactions. PMID:15723077
Enzymatic activity and partial purification of solanapyrone synthase: first enzyme catalyzing Diels-Alder reaction.

PubMed

Katayama, K; Kobayashi, T; Oikawa, H; Honma, M; Ichihara, A

1998-05-19

In cell-free extracts of Alternaria solani, an enzymatic activity converting prosolanapyrone II to solanapyrones A and D via oxidation and subsequent Diels-Alder reaction has been found. Chromatography with DEAE-Sepharose provided two active fractions, pools 1 and 2. The former fraction converted prosolanapyrone II to solanapyrones A and D in a ratio of 2.2:1 with optical purities of 99% and 45% ee, respectively. The latter fraction did so in a ratio of 7.6:1 with 99% and nearly 0% ee, respectively. The enzyme partially purified from pool 2 native molecular weight of 40-62 kD and a pl of 4.25. The high reactivity of prosolanapyrone III in aqueous solution and the chromatographic behavior of the enzyme in pool 2 suggest that a single enzyme catalyzes both the oxidation and Diels-Alder reaction.
"Clickable" Polymeric Nanofibers through Hydrophilic-Hydrophobic Balance: Fabrication of Robust Biomolecular Immobilization Platforms.

PubMed

Kalaoglu-Altan, Ozlem I; Sanyal, Rana; Sanyal, Amitav

2015-05-11

Fabrication of hydrophilic polymeric nanofibers that undergo facile and selective functionalization through metal catalyst-free Diels-Alder "click" reaction in aqueous environment is outlined. Electrospinning of copolymers containing an electron-rich furan moiety, hydrophobic methyl methacrylate units and hydrophilic poly(ethylene glycol)s as side chains provide specifically functionalizable yet antibiofouling fibers that remain stable in aqueous media due to appropriate hydrophobic hydrophilic balance. Efficient functionalization of these nanofibers is accomplished through the Diels-Alder reaction by exposing them to maleimide-containing molecules and ligands. Diels-Alder conjugation based functionalization is demonstrated through attachment of fluorescein-maleimide and a maleimide tethered biotin ligand. Biotinylated nanofibers were utilized to mediate immobilization of the protein streptavidin, as well as streptavidin coated quantum dots. Facile fabrication from readily available polymers and their effective functionalization under mild and reagent-free conditions in aqueous media make these "clickable" nanofibers attractive candidates as functionalizable scaffolds for various biomedical applications.
The hexadehydro-Diels-Alder reaction.

PubMed

Hoye, Thomas R; Baire, Beeraiah; Niu, Dawen; Willoughby, Patrick H; Woods, Brian P

2012-10-11

Arynes (aromatic systems containing, formally, a carbon-carbon triple bond) are among the most versatile of all reactive intermediates in organic chemistry. They can be 'trapped' to give products that are used as pharmaceuticals, agrochemicals, dyes, polymers and other fine chemicals. Here we explore a strategy that unites the de novo generation of benzynes-through a hexadehydro-Diels-Alder reaction-with their in situ elaboration into structurally complex benzenoid products. In the hexadehydro-Diels-Alder reaction, a 1,3-diyne is engaged in a [4+2] cycloisomerization with a 'diynophile' to produce the highly reactive benzyne intermediate. The reaction conditions for this simple, thermal transformation are notable for being free of metals and reagents. The subsequent and highly efficient trapping reactions increase the power of the overall process. Finally, we provide examples of how this de novo benzyne generation approach allows new modes of intrinsic reactivity to be revealed.
Polar Diels-Alder reactions using electrophilic nitrobenzothiophenes. A combined experimental and DFT study

NASA Astrophysics Data System (ADS)

Della Rosa, Claudia D.; Mancini, Pedro M. E.; Kneeteman, Maria N.; Lopez Baena, Anna F.; Suligoy, Melisa A.; Domingo, Luis R.

2015-01-01

The reactions between 2- and 3-nitrobenzothiophenes with three dienes of different nucleophilicity, 1-methoxy-3-trimethylsilyloxy-1,3-butadiene, 1-trimethylsilyloxy-1,3-butadiene and isoprene developed in anhydrous benzene and alternative under microwave irradiation with molecular solvents or in free solvent conditions, respectively, for produce dibenzothiophenes permit to conclude that both nitroheterocycles act as electrophile with the cited dienes. In the cases of the dienes 1-methoxy-3-trimethylsilyloxy-1,3-butadiene and 1-trimethylsilyloxy-1,3-butadiene which posses major nucleophilicity the observed product is the normal cycloaddition one. However when the diene is isoprene the product with both electrophiles follow the hetero Diels-Alder way. These reactions are considered polar cycloaddition reactions and the yields are reasonables. Moreover the polar Diels-Alder reactions of nitrobenzothiophenes with electron rich dienes 1-trimethylsilyloxy-1,3-butadiene have been theoretically studied using DFT methods.
Movement Disorders in Adult Surviving Patients with Maple Syrup Urine Disease

PubMed Central

Carecchio, Miryam; Schneider, Susanne A.; Chan, Heidi; Lachmann, Robin; Lee, Philip J.; Murphy, Elaine; Bhatia, Kailash P.

2014-01-01

Maple syrup urine disease is a rare metabolic disorder caused by mutations in the branched-chain α-keto acid dehydrogenase complex gene. Patients generally present early in life with a toxic encephalopathy because of the accumulation of the branched-chain amino acids leucine, isoleucine, and valine and the corresponding ketoacids. Movement disorders in maple syrup urine disease have typically been described during decompensation episodes or at presentation in the context of a toxic encephalopathy, with complete resolution after appropriate dietary treatment. Movement disorders in patients surviving childhood are not well documented. We assessed 17 adult patients with maple syrup urine disease (mean age, 27.5 years) with a special focus on movement disorders. Twelve (70.6%) had a movement disorder on clinical examination, mainly tremor and dystonia or a combination of both. Parkinsonism and simple motor tics were also observed. Pyramidal signs were present in 11 patients (64.7%), and a spastic-dystonic gait was observed in 6 patients (35.2%). In summary, movement disorders are common in treated adult patients with maple syrup urine disease, and careful neurological examination is advisable to identify those who may benefit from specific therapy. PMID:21484869
Movement disorders in adult surviving patients with maple syrup urine disease.

PubMed

Carecchio, Miryam; Schneider, Susanne A; Chan, Heidi; Lachmann, Robin; Lee, Philip J; Murphy, Elaine; Bhatia, Kailash P

2011-06-01

Maple syrup urine disease is a rare metabolic disorder caused by mutations in the branched-chain α-keto acid dehydrogenase complex gene. Patients generally present early in life with a toxic encephalopathy because of the accumulation of the branched-chain amino acids leucine, isoleucine, and valine and the corresponding ketoacids. Movement disorders in maple syrup urine disease have typically been described during decompensation episodes or at presentation in the context of a toxic encephalopathy, with complete resolution after appropriate dietary treatment. Movement disorders in patients surviving childhood are not well documented. We assessed 17 adult patients with maple syrup urine disease (mean age, 27.5 years) with a special focus on movement disorders. Twelve (70.6%) had a movement disorder on clinical examination, mainly tremor and dystonia or a combination of both. Parkinsonism and simple motor tics were also observed. Pyramidal signs were present in 11 patients (64.7%), and a spastic-dystonic gait was observed in 6 patients (35.2%). In summary, movement disorders are common in treated adult patients with maple syrup urine disease, and careful neurological examination is advisable to identify those who may benefit from specific therapy. © 2011 Movement Disorder Society. Copyright © 2011 Movement Disorder Society.
Identification of the bacterial community of maple sap by using amplified ribosomal DNA (rDNA) restriction analysis and rDNA sequencing.

PubMed

Lagacé, L; Pitre, M; Jacques, M; Roy, D

2004-04-01

The bacterial community of maple sap was characterized by analysis of samples obtained at the taphole of maple trees for the 2001 and 2002 seasons. Among the 190 bacterial isolates, 32 groups were formed according to the similarity of the banding patterns obtained by amplified ribosomal DNA restriction analysis (ARDRA). A subset of representative isolates for each ARDRA group was identified by 16S rRNA gene fragment sequencing. Results showed a wide variety of organisms, with 22 different genera encountered. Pseudomonas and Ralstonia, of the gamma- and beta-Proteobacteria, respectively, were the most frequently encountered genera. Gram-positive bacteria were also observed, and Staphylococcus, Plantibacter, and Bacillus were the most highly represented genera. The sampling period corresponding to 50% of the cumulative sap flow percentage presented the greatest bacterial diversity according to its Shannon diversity index value (1.1). gamma-Proteobacteria were found to be dominant almost from the beginning of the season to the end. These results are providing interesting insights on maple sap microflora that will be useful for further investigation related to microbial contamination and quality of maple products and also for guiding new strategies on taphole contamination control.
Identification of the fitness determinants of budding yeast on a natural substrate.

PubMed

Filteau, Marie; Charron, Guillaume; Landry, Christian R

2017-04-01

The budding yeasts are prime models in genomics and cell biology, but the ecological factors that determine their success in non-human-associated habitats is poorly understood. In North America Saccharomyces yeasts are present on the bark of deciduous trees, where they feed on bark and sap exudates. In the North East, Saccharomyces paradoxus is found on maples, which makes maple sap a natural substrate for this species. We measured growth rates of S. paradoxus natural isolates on maple sap and found variation along a geographical gradient not explained by the inherent variation observed under optimal laboratory conditions. We used a functional genomic screen to reveal the ecologically relevant genes and conditions required for optimal growth in this substrate. We found that the allantoin degradation pathway is required for optimal growth in maple sap, in particular genes necessary for allantoate utilization, which we demonstrate is the major nitrogen source available to yeast in this environment. Growth with allantoin or allantoate as the sole nitrogen source recapitulated the variation in growth rates in maple sap among strains. We also show that two lineages of S. paradoxus display different life-history traits on allantoin and allantoate media, highlighting the ecological relevance of this pathway.
Speed of tapping does not influence maple sap yields

Treesearch

H. Clay Smith; Richard J. LaMore

1971-01-01

Results of this study showed no statistical difference in the quantity or sweetness of sugar maple sap collected from tapholes that were drilled with a variety of tappers running at different drilling speeds
[Anaesthesia in patients with maple syrup urine disease. Case report and perioperative anaesthetic management].

PubMed

Haberstich, P; Kindler, C H; Schürch, M

2010-10-01

Maple syrup urine disease is a rare autosomal-recessive metabolic disorder caused by a deficit of oxidative decarboxylation of branched-chain amino acids. First symptoms appear in the neonatal period. Without treatment the disease is characterized by rapid progression of neurological symptoms. During stressful situations, such as infection or surgery, patients may experience severe ketoacidosis, rapid neurological deterioration and hypoglycemia. The perioperative management of a 26-year-old man with maple syrup urine disease is described, a review of the disease is given and anaesthesia-related implications are discussed.

Isoleucine Deficiency in a Neonate Treated for Maple Syrup Urine Disease Masquerading as Acrodermatitis Enteropathica.

PubMed

Ross, Benjamin; Kumar, Manish; Srinivasan, Hema; Ekbote, Alka V

2016-08-08

Special diet with restricted branched-chain-amino-acids used for treating maple syrup urine disease can lead to specific amino acid deficiencies. We report a neonate who developed skin lesions due to isoleucine deficiency while using specialised formula. Feeds were supplemented with expressed breast milk. This caused biochemical and clinical improvement with resolution of skin lesions. Breast milk is a valuable and necessary adjunct to specialized formula in maple syrup urine disease to prevent specific amino acid deficiency in the neonatal period.
29 CFR 780.800 - Scope and significance of interpretative bulletin.

Code of Federal Regulations, 2014 CFR

2014-07-01

..., or Maple Sap into Sugar or Syrup; Exemption From Overtime Pay Requirements Under Section 13(b)(15..., sugar-beet molasses, sugarcane or maple sap, into sugar (other than refined sugar) or syrup. The limited...
29 CFR 780.800 - Scope and significance of interpretative bulletin.

Code of Federal Regulations, 2012 CFR

2012-07-01

..., or Maple Sap into Sugar or Syrup; Exemption From Overtime Pay Requirements Under Section 13(b)(15..., sugar-beet molasses, sugarcane or maple sap, into sugar (other than refined sugar) or syrup. The limited...
29 CFR 780.800 - Scope and significance of interpretative bulletin.

Code of Federal Regulations, 2013 CFR

2013-07-01

..., or Maple Sap into Sugar or Syrup; Exemption From Overtime Pay Requirements Under Section 13(b)(15..., sugar-beet molasses, sugarcane or maple sap, into sugar (other than refined sugar) or syrup. The limited...
Stocking and structure for maximum growth in sugar maple selection stands.

Treesearch

Thomas R. Crow; Carl H. Tubbs; Rodney D. Jacobs; Robert R. Oberg

1981-01-01

The impacts of stocking, structure, and cutting cycle on basal area, cubic foot volume, board foot volume, and diameter growth are considered. Recommendations are provided for maximum growth in uneven-aged sugar maple stands.
Characterization of MAPLE deposited WO3 thin films for electrochromic applications

NASA Astrophysics Data System (ADS)

Boyadjiev, S. I.; Stefan, N.; Szilágyi, I. M.; Mihailescu, N.; Visan, A.; Mihailescu, I. N.; Stan, G. E.; Besleaga, C.; Iliev, M. T.; Gesheva, K. A.

2017-01-01

Tungsten trioxide (WO3) is a widely studied material for electrochromic applications. The structure, morphology and optical properties of WO3 thin films, grown by matrix assisted pulsed laser evaporation (MAPLE) from monoclinic WO3 nano-sized particles, were investigated for their possible application as electrochromic layers. A KrF* excimer (λ=248 nm, ζFWHM=25 ns) laser source was used in all experiments. The MAPLE deposited WO3 thin films were studied by atomic force microscopy (AFM), grazing incidence X-ray diffraction (GIXRD) and Fourier transform infrared spectroscopy (FTIR). Cyclic voltammetry measurements were also performed, and the coloring and bleaching were observed. The morpho-structural investigations disclosed the synthesis of single-phase monoclinic WO3 films consisting of crystalline nano-grains embedded in an amorphous matrix. All thin films showed good electrochromic properties, thus validating application of the MAPLE deposition technique for the further development of electrochromic devices.
Antimicrobial activity of biopolymer-antibiotic thin films fabricated by advanced pulsed laser methods

NASA Astrophysics Data System (ADS)

Cristescu, R.; Popescu, C.; Dorcioman, G.; Miroiu, F. M.; Socol, G.; Mihailescu, I. N.; Gittard, S. D.; Miller, P. R.; Narayan, R. J.; Enculescu, M.; Chrisey, D. B.

2013-08-01

We report on thin film deposition by matrix assisted pulsed laser evaporation (MAPLE) of two polymer-drug composite thin film systems. A pulsed KrF* excimer laser source (λ = 248 nm, τ = 25 ns, ν = 10 Hz) was used to deposit composite thin films of poly(D,L-lactide) (PDLLA) containing several gentamicin concentrations. FTIR spectroscopy was used to demonstrate that MAPLE-transferred materials exhibited chemical structures similar to those of drop cast materials. Scanning electron microscopy data indicated that MAPLE may be used to fabricate thin films of good morphological quality. The activity of PDLLA-gentamicin composite thin films against Staphylococcus aureus bacteria was demonstrated using drop testing. The influence of drug concentration on microbial viability was also assessed. Our studies indicate that polymer-drug composite thin films prepared by MAPLE may be used to impart antimicrobial activity to implants, medical devices, and other contact surfaces.
New Gallotannin and other Phytochemicals from Sycamore Maple (Acer pseudoplatanus) Leaves.

PubMed

Zhang, Lu; Tu, Zong-cai; Yuan, Tao; Ma, Hang; Niesen, Daniel B; Wang, Hui; Seeram, Navindra P

2015-11-01

The maple (Acer) genus is a reported source of bioactive (poly)phenols, including gallotannins, but several of its members, such as the sycamore maple (A. pseudoplatanus), remain uninvestigated. Herein, thirty-nine compounds, including a new gallotannin, 1,2,3-tri-O-galloyl-6-O-(p-hydroxybenzoyl)-β-D- glucopyranoside (1), and thirty-eight (2-39) known compounds, consisting of four gallotannins, one ellagitannin, thirteen flavonoids, eight hydroxycinnamic acids, ten benzoic acid derivatives, and two sesquiterpenoids, were isolated from sycamore maple leaves. Their structures were determined based on NMR and mass spectral analyses. The isolates were evaluated for α-glucosidase inhibitory and antioxidant activities. Among the isolates, the gallotannins were the most potent α-glucosidase inhibitors with thirteen-fold more potent activity compared with the clinical drug, acarbose (IC50 = 16-31 vs. 218 µM). Similarly, the gallotannins showed the highest antioxidant activities, followed by the other phenolic sub-classes, while the sesquiterpenoids were inactive.
Ecology of red maple swamps in the glaciated northeast: A community profile

DOE Office of Scientific and Technical Information (OSTI.GOV)

Golet, F.C.; Calhoun, A.J.K.; DeRagon, W.R.

1993-06-01

The report is part of a series of profiles on the ecology of wetland and deepwater habitats. This particular profile addresses red maple swamps in the glaciated northeastern United States. Red maple (Acer rubrum) swamp is a dominant wetland type in most of the region; it reaches the greatest abundance in southern New England and northern New Jersey; where it comprises 60-80% of all inland wetlands. Red maple swamps occur in a wide variety of hydrogeologic settings, from small, isolated basins in till or glaciofluvial deposits to extensive wetland complexes on glacial lake beds, and from hillside seeps to streammore » floodplains and lake edges. Individual swamps may be seasonally flooded, temporarily flooded, or seasonally saturated, and soils may be mineral or organic. As many as five distinct vegetation layers may occur in these swamps, including trees, saplings, shrubs, herbs, and ground cover plants such as bryophytes and clubmosses.« less
Ecology of red maple swamps in the glaciated northeast: A community profile

DOE Office of Scientific and Technical Information (OSTI.GOV)

Golet, F.C.; Calhoun, A.J.K.; DeRagon, W.R.

1993-06-01

In many areas of the glaciated northeastern United States, forested wetlands dominated by red maple (Acer rubrum) cover more of the landscape than all other nontidal wetland types combined. Yet surprisingly little of their ecology, functions, or social significance has been documented. Bogs, salt marshes, Atlantic white cedar swamps, and other less common types of wetlands have received considerable attention from scientists, but, except for botanical surveys, red maple swamps have been largely ignored. The report conveys what is known about these common wetlands and identifies topics most in need of investigation. Red maple swamps are so abundant and somore » widely distributed in the Northeast that their physical, chemical, and biological properties range widely as well, and their values to society are diverse. The central focus of the U.S. Fish and Wildlife Service community profile series is the plant and animal communities of wetlands and deepwater habitats.« less
National Research Council Resident Research Associateship (NRC-RRA) program

DTIC Science & Technology

1988-08-01

Davis, C. J. Dymek, J. J. P. Stewart, H. P. Clark, W. J. Lauderdale, J. Am. Chem. Soc., 107, 5041-5046 (1985). 7. "Mechanism of the Diels - Alder ...Package" Dewar Research Group and J. J. P. Stewart, Quantum Chemistry Program Exchange, no. 506, nn, nnn, (1986) 16. "Mechanism of the Diels - Alder ...Kvisle, 0. Nirisen, M. Ystenes, and H. A. Oye, Proceedings of 1986 International Symposium on Transition Metals Catalyzed Polymerizations, Institute of
The unexpected product of Diels-Alder reaction between "indanocyclon" and maleimide

NASA Astrophysics Data System (ADS)

Dobrowolski, Michał A.; Roszkowski, Piotr; Struga, Marta; Szulczyk, Daniel

2017-02-01

A heterocyclic compound commonly known as "indanocyclon" undergoes an unexpected Diels-Alder addition with maleimide. The resulting product has been isolated and characterized in order to get an information about its structure and possible mechanism of the reaction. Extensive comparison of single crystal properties of 3-(2,8-dioxo-1,3-diphenyl-2,8-dihydrocyclopenta[a]inden-8a(1H)-yl)pyrrolidine-2,5-dione and favorable product of the reaction has been also performed.
Early wide spacing in red alder (Alnus rubra Bong.): effects on stem form and stem growth.

Treesearch

Bernard T. Bormann

1985-01-01

A thinning trial was established in 1962 in a 7-year-old red alder stand in northwestern Washington. Spacings were 8 x 8 ft (dense), 12 x 12 it (intermediate), and 16 x 16 ft (open). The effect of early thinning on growth and stem form was measured in 1982, 20 years after spacing treatment. There was negligible tree lean and sweep in open and intermediate stands except...
Continuous-flow retro-Diels-Alder reaction: an efficient method for the preparation of pyrimidinone derivatives.

PubMed

Nekkaa, Imane; Palkó, Márta; Mándity, István M; Fülöp, Ferenc

2018-01-01

The syntheses of various pyrimidinones as potentially bioactive products by means of the highly controlled continuous-flow retro-Diels-Alder reaction of condensed pyrimidinone derivatives are presented. Noteworthy, the use of this approach allowed us to rapidly screen a selection of conditions and quickly confirm the viability of preparing the desired pyrimidinones in short reaction times. Yields typically higher than those published earlier using conventional batch or microwave processes were achieved.
Patterned-ground facilitates shrub expansion in Low Arctic tundra

NASA Astrophysics Data System (ADS)

Frost, Gerald V.; Epstein, Howard E.; Walker, Donald A.; Matyshak, Georgiy; Ermokhina, Ksenia

2013-03-01

Recent expansion of tall shrubs in Low Arctic tundra is widely seen as a response to climate warming, but shrubification is not occurring as a simple function of regional climate trends. We show that establishment of tall alder (Alnus) is strongly facilitated by small, widely distributed cryogenic disturbances associated with patterned-ground landscapes. We identified expanding and newly established shrub stands at two northwest Siberian sites and observed that virtually all new shrubs occurred on bare microsites (‘circles’) that were disturbed by frost-heave. Frost-heave associated with circles is a widespread, annual phenomenon that maintains mosaics of mineral seedbeds with warm soils and few competitors that are immediately available to shrubs during favorable climatic periods. Circle facilitation of alder recruitment also plausibly explains the development of shrublands in which alders are regularly spaced. We conclude that alder abundance and extent have increased rapidly in the northwest Siberian Low Arctic since at least the mid-20th century, despite a lack of summer warming in recent decades. Our results are consistent with findings in the North American Arctic which emphasize that the responsiveness of Low Arctic landscapes to climate change is largely determined by the frequency and extent of disturbance processes that create mineral-rich seedbeds favorable for tall shrub recruitment. Northwest Siberia has high potential for continued expansion of tall shrubs and concomitant changes to ecosystem function, due to the widespread distribution of patterned-ground landscapes.
Competition for nitrogen sources between European beech (Fagus sylvatica) and sycamore maple (Acer pseudoplatanus) seedlings.

PubMed

Simon, J; Waldhecker, P; Brüggemann, N; Rennenberg, H

2010-05-01

To investigate the short-term consequences of direct competition between beech and sycamore maple on root N uptake and N composition, mycorrhizal seedlings of both tree species were incubated for 4 days (i.e. beech only, sycamore maple only or both together) in an artificial nutrient solution with low N availability. On the fourth day, N uptake experiments were conducted to study the effects of competition on inorganic and organic N uptake. For this purpose, multiple N sources were applied with a single label. Furthermore, fine roots were sampled and analysed for total amino acids, soluble protein, total nitrogen, nitrate and ammonium content. Our results clearly show that both tree species were able to use inorganic and organic N sources. Uptake of inorganic and organic N by beech roots was negatively affected in the presence of the competing tree species. In contrast, the presence of beech stimulated inorganic N uptake by sycamore maple roots. Both the negative effect of sycamore maple on N uptake of beech and the positive effect of beech on N uptake of sycamore maple led to an increase in root soluble protein in beech, despite an overall decrease in total N concentration. Thus, beech compensated for the negative effects of the tree competitor on N uptake by incorporating less N into structural N components, but otherwise exhibited the same strategy as the competitor, namely, enhancing soluble protein levels in roots when grown under competition. It is speculated that enhanced enzyme activities of so far unknown nature are required in beech as a defence response to inter-specific competition.
De novo transcriptome sequencing of Acer palmatum and comprehensive analysis of differentially expressed genes under salt stress in two contrasting genotypes.

PubMed

Rong, Liping; Li, Qianzhong; Li, Shushun; Tang, Ling; Wen, Jing

2016-04-01

Maple (Acer palmatum) is an important species for landscape planting worldwide. Salt stress affects the normal growth of the Maple leaf directly, leading to loss of esthetic value. However, the limited availability of Maple genomic information has hindered research on the mechanisms underlying this tolerance. In this study, we performed comprehensive analyses of the salt tolerance in two genotypes of Maple using RNA-seq. Approximately 146.4 million paired-end reads, representing 181,769 unigenes, were obtained. The N50 length of the unigenes was 738 bp, and their total length over 102.66 Mb. 14,090 simple sequence repeats and over 500,000 single nucleotide polymorphisms were identified, which represent useful resources for marker development. Importantly, 181,769 genes were detected in at least one library, and 303 differentially expressed genes (DEGs) were identified between salt-sensitive and salt-tolerant genotypes. Among these DEGs, 125 were upregulated and 178 were downregulated genes. Two MYB-related proteins and one LEA protein were detected among the first 10 most downregulated genes. Moreover, a methyltransferase-related gene was detected among the first 10 most upregulated genes. The three most significantly enriched pathways were plant hormone signal transduction, arginine and proline metabolism, and photosynthesis. The transcriptome analysis provided a rich genetic resource for gene discovery related to salt tolerance in Maple, and in closely related species. The data will serve as an important public information platform to further our understanding of the molecular mechanisms involved in salt tolerance in Maple.
Bark thickness related to tree diameter in sugar maple (Acer saccharum Marsh.)

Treesearch

H. Clay Smith

1969-01-01

Bark thickness for sugar maple trees in Vermont was found to be related to tree diameter at breast height (d.b.h.). The relationship was positive-as the diameter increased, the bark thickness increased.
Phenotypic selection in sugar maple for superior sap sugar production

Treesearch

William J. Gabriel; William J. Gabriel

1972-01-01

This is a report on the results of the sugar maple selection program at Burlington, Vermont. Because of its possible value to other forestry workers, the method used in making the selections has been treated in detail.
The relationship between sap-flow rate and sap volume in dormant sugar maples

Treesearch

William J. Gabriel; Russell S. Walters; Donald W. Seegrist

1972-01-01

Sap-flow rate is closely correlated with the sap volume produced by dormant sugar maple trees (Acer saccharum Marsh.) and could be used in making phenotypic selections of trees for superior sap production.

Graphs and Enhancing Maple Multiplication.

ERIC Educational Resources Information Center

Cecil, David R.; Wang, Rongdong

2002-01-01

Description of a technique in Maple programming language that automatically prints all paths of any desired length along with the name of each vertex, proceeding in order from the beginning vertex to the ending vertex for a given graph. (Author/MM)
Influence of gelatinous fibers on the shrinkage of silver maple

Treesearch

Donals G. Arganbright; Dwight W. Bensend; Floyd G. Manwiller

1970-01-01

The degree of lean was found to have a significant influence on the logitudinal and transverse shrinkage of three soft maple trees. This may be accounted for by differences in the cell wall layer thickness and fibril angle.
Paraformaldehyde pellet not necessary in vacuum-pumped maple sap system

Treesearch

H. Clay Smith; Carter B. Gibbs

1970-01-01

In a study of sugar maple sap collection through a vacuum-pumped plastic tubing system, yields were compared between tapholes in which paraformaldehyde pellets were used and tapholes without pellets, Use of the pellets did not increase yield.
Proceedings of the Eighth Lake States Forest Tree Improvement conference, Sept. 12-13, 1967.

Treesearch

NCFES

1968-01-01

Presents 11 papers concerning recent research in forest genetics, physiology, and allied fields. Species discussed include red pine, jack pine, Scotch pine, black spruce, larch, yellow birch, sugar maple, silver maple, cottonwood, and walnut.
Deposition of Methylammonium Lead Triiodide by Resonant Infrared Matrix-Assisted Pulsed Laser Evaporation

NASA Astrophysics Data System (ADS)

Barraza, E. Tomas; Dunlap-Shohl, Wiley A.; Mitzi, David B.; Stiff-Roberts, Adrienne D.

2018-02-01

Resonant infrared matrix-assisted pulsed laser evaporation (RIR-MAPLE) was used to deposit the metal-halide perovskite (MHP) CH3NH3PbI3 (methylammonium lead triiodide, or MAPbI), creating phase-pure films. Given the moisture sensitivity of these crystalline, multi-component organic-inorganic hybrid materials, deposition of MAPbI by RIR-MAPLE required a departure from the use of water-based emulsions as deposition targets. Different chemistries were explored to create targets that properly dissolved MAPbI components, were stable under vacuum conditions, and enabled resonant laser energy absorption. Secondary phases and solvent contamination in the resulting films were studied through Fourier transform infrared (FTIR) absorbance and x-ray diffraction (XRD) measurements, suggesting that lingering excess methylammonium iodide (MAI) and low-vapor pressure solvents can distort the microstructure, creating crystalline and amorphous non-perovskite phases. Thermal annealing of films deposited by RIR-MAPLE allowed for excess solvent to be evaporated from films without degrading the MAPbI structure. Further, it was demonstrated that RIR-MAPLE does not require excess MAI to create stoichiometric films with optoelectronic properties, crystal structure, and film morphology comparable to films created using more established spin-coating methods for processing MHPs. This work marks the first time a MAPLE-related technique was used to deposit MHPs.
Identification of the fitness determinants of budding yeast on a natural substrate

PubMed Central

Filteau, Marie; Charron, Guillaume; Landry, Christian R

2017-01-01

The budding yeasts are prime models in genomics and cell biology, but the ecological factors that determine their success in non-human-associated habitats is poorly understood. In North America Saccharomyces yeasts are present on the bark of deciduous trees, where they feed on bark and sap exudates. In the North East, Saccharomyces paradoxus is found on maples, which makes maple sap a natural substrate for this species. We measured growth rates of S. paradoxus natural isolates on maple sap and found variation along a geographical gradient not explained by the inherent variation observed under optimal laboratory conditions. We used a functional genomic screen to reveal the ecologically relevant genes and conditions required for optimal growth in this substrate. We found that the allantoin degradation pathway is required for optimal growth in maple sap, in particular genes necessary for allantoate utilization, which we demonstrate is the major nitrogen source available to yeast in this environment. Growth with allantoin or allantoate as the sole nitrogen source recapitulated the variation in growth rates in maple sap among strains. We also show that two lineages of S. paradoxus display different life-history traits on allantoin and allantoate media, highlighting the ecological relevance of this pathway. PMID:27935595
Development of novel genic microsatellite markers from transcriptome sequencing in sugar maple (Acer saccharum Marsh.).

PubMed

Harmon, Monica; Lane, Thomas; Staton, Margaret; Coggeshall, Mark V; Best, Teodora; Chen, Chien-Chih; Liang, Haiying; Zembower, Nicole; Drautz-Moses, Daniela I; Hwee, Yap Zhei; Schuster, Stephan C; Schlarbaum, Scott E; Carlson, John E; Gailing, Oliver

2017-08-08

Sugar maple (Acer saccharum Marsh.) is a hardwood tree species native to northeastern North America and economically valued for its wood and sap. Yet, few molecular genetic resources have been developed for this species to date. Microsatellite markers have been a useful tool in population genetics, e.g., to monitor genetic variation and to analyze gene flow patterns. The objective of this study is to develop a reference transcriptome and microsatellite markers in sugar maple. A set of 117,861 putative unique transcripts were assembled using 29.2 Gb of RNA sequencing data derived from different tissues and stress treatments. From this set of sequences a total of 1068 microsatellite motifs were identified. Out of 58 genic microsatellite markers tested on a population of 47 sugar maple trees in upper Michigan, 22 amplified well, of which 16 were polymorphic and 6 were monomorphic. Values for expected heterozygosity varied from 0.224 to 0.726 for individual loci. Of the 16 polymorphic markers, 15 exhibited transferability to other Acer L. species. Genic microsatellite markers can be applied to analyze genetic variation in potentially adaptive genes relative to genomic reference markers as a basis for the management of sugar maple genetic resources in the face of climate change.
Identification of the Bacterial Community of Maple Sap by Using Amplified Ribosomal DNA (rDNA) Restriction Analysis and rDNA Sequencing

PubMed Central

Lagacé, L.; Pitre, M.; Jacques, M.; Roy, D.

2004-01-01

The bacterial community of maple sap was characterized by analysis of samples obtained at the taphole of maple trees for the 2001 and 2002 seasons. Among the 190 bacterial isolates, 32 groups were formed according to the similarity of the banding patterns obtained by amplified ribosomal DNA restriction analysis (ARDRA). A subset of representative isolates for each ARDRA group was identified by 16S rRNA gene fragment sequencing. Results showed a wide variety of organisms, with 22 different genera encountered. Pseudomonas and Ralstonia, of the γ- and β-Proteobacteria, respectively, were the most frequently encountered genera. Gram-positive bacteria were also observed, and Staphylococcus, Plantibacter, and Bacillus were the most highly represented genera. The sampling period corresponding to 50% of the cumulative sap flow percentage presented the greatest bacterial diversity according to its Shannon diversity index value (1.1). γ-Proteobacteria were found to be dominant almost from the beginning of the season to the end. These results are providing interesting insights on maple sap microflora that will be useful for further investigation related to microbial contamination and quality of maple products and also for guiding new strategies on taphole contamination control. PMID:15066796
Control of femtosecond laser driven retro-Diels-Alder-like reaction of dicyclopentadiene

PubMed Central

Das, Dipak Kumar; Goswami, Tapas; Goswami, Debabrata

2013-01-01

Using femtosecond time resolved degenerate pump-probe mass spectrometry coupled with simple linearly chirped frequency modulated pulse, we elucidate that the dynamics of retro-Diels-Alder-like reaction of diclopentadiene (DCPD) to cyclopentadiene (CPD) in supersonic molecular beam occurs in ultrafast time scale. Negatively chirped pulse enhances the ion yield of CPD, as compared to positively chirped pulse. This indicates that by changing the frequency (chirp) of the laser pulse we can control the ion yield of a chemical reaction. PMID:23814449
Regiochemically controlled synthesis of a β-4-β' [70]fullerene bis-adduct

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cerón, Maira R.; Castro, Edison; Neti, Venkata S. Pavan K.

2016-12-22

A β-4-β' C 70 bis-adduct regioisomer and an uncommon mono-adduct β-malonate C 70 derivative were synthesized by using a Diels–Alder cycloaddition followed by an addition–elimination of bromo-ethylmalonate and a retro-Diels–Alder cycloaddition reaction. Here, we also report the regioselective synthesis and spectroscopic characterization of C s-symmetric tris- and C 2v-symmetric tetra-adducts of C 70, which are the precursors of the mono- and bis-adduct final products.
Excellent acceleration of the Diels-Alder reaction by microwave irradiation for the synthesis of new fluorine-substituted ligands of NMDA receptor.

PubMed

Sasaki, S; Ishibashi, N; Kuwamura, T; Sano, H; Matoba, M; Nisikawa, T; Maeda, M

1998-11-03

A series of 6,11-ethanobenzo[b]quinolizinium derivatives was synthesized through the Diels-Alder reaction between azoniaanthracne and the corresponding 1,1-disubstituted olefin. After a systematic investigation for achieving rapid synthesis, it was found that the reaction is accelerated in polar media such as H2O and trifluoroethanol. In particular, excellent acceleration was effected by microwave irradiation. The new fluorine-substituted ligands thus obtained exhibited potential affinity toward NMDA receptors.
Microwave-Assisted Organocatalytic Intramolecular Knoevenagel/Hetero Diels-Alder Reaction with O-(Arylpropynyloxy)-Salicylaldehydes: Synthesis of Polycyclic Embelin Derivatives.

PubMed

Martín-Acosta, Pedro; Feresin, Gabriela; Tapia, Alejandro; Estévez-Braun, Ana

2016-10-21

A highly efficient and regioselective approach to new polycyclic embelin derivatives through a domino Knoevenagel condensation/intramolecular hetero Diels-Alder reaction using O-(arylpropynyloxy)-salicylaldehydes in the presence of ethylenediamine diacetate (EDDA) is reported. This organocatalyzed protocol is compatible toward a wide range of aryl-substituted alkynyl ethers with electron-donating and electron-withdrawing groups. When other active methylene compounds were subjected to this domino reaction the corresponding adducts were obtained in high yield.
Diels-Alder reactions of 12-hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione.

PubMed

Majetich, George; Zhang, Yong; Tian, Xinrong; Zou, Ge; Li, Yang; Wang, Yangyang; Hu, Shougang; Huddleston, Eric

2013-06-14

12-Hydroxy-9(10-->20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione (quinone 2) served as the dienophile in numerous intermolecular Diels-Alder reactions. These cycloadditions were conducted either thermally (including microwave heating) or with Lewis acid activation. While most dienes reacted with quinone 2 in good chemical yield, others were incompatible under the experimental conditions used.
Stereoselective protecting group free synthesis of D,L-gulose ethyl glycoside via multicomponent enyne cross metathesis--hetero Diels-Alder reaction.

PubMed

Castagnolo, Daniele; Botta, Lorenzo; Botta, Maurizio

2009-07-27

An efficient and stereoselective synthesis of D,L-gulose was described. The key step of the synthetic route is represented by a multicomponent enyne cross metathesis-hetero Diels-Alder reaction which allows the formation of the pyran ring from cheap and commercially available substrates in a single synthetic step. The synthesis of D,L-gulose was accomplished without the use of protecting groups making this approach highly desirable also in terms of atom economy.
High-speed microwave-promoted hetero-Diels-Alder reactions of 2(1H)-pyrazinones in ionic liquid doped solvents.

PubMed

Van Der Eycken, Erik; Appukkuttan, Prasad; De Borggraeve, Wim; Dehaen, Wim; Dallinger, Doris; Kappe, C Oliver

2002-11-01

Inter- and intramolecular hetero-Diels-Alder reactions in a series of functionalized 2(1H)-pyrazinones were investigated under controlled microwave irradiation. The cycloaddition reactions were efficiently performed in sealed tubes, utilizing either a combination of 1,2-dichloroethane and a thermally stable ionic liquid, or 1,2-dichlorobenzene as reaction medium. In all cases, a significant rate-enhancement using microwave flash heating as compared to thermal heating was observed.
Studies toward the synthesis of palhinine lycopodium alkaloids: a Morita-Baylis-Hillman/intramolecular Diels-Alder approach.

PubMed

Sizemore, Nicholas; Rychnovsky, Scott D

2014-02-07

A synthetic route to the isotwistane core of palhinine lycopodium alkaloids is described. A Morita-Baylis-Hillman/intramolecular Diels-Alder (IMDA) strategy sets the vicinal all-carbon quaternary centers present in this family of natural products. The regioselectivity of the IMDA reaction is dictated by the conditions employed for silyl enol ether formation, with one set of conditions providing the core of cardionine and alternate conditions generating the desired isotwistane core of isopalhinine.
Continuous-flow retro-Diels–Alder reaction: an efficient method for the preparation of pyrimidinone derivatives

PubMed Central

Nekkaa, Imane; Palkó, Márta; Mándity, István M

2018-01-01

The syntheses of various pyrimidinones as potentially bioactive products by means of the highly controlled continuous-flow retro-Diels–Alder reaction of condensed pyrimidinone derivatives are presented. Noteworthy, the use of this approach allowed us to rapidly screen a selection of conditions and quickly confirm the viability of preparing the desired pyrimidinones in short reaction times. Yields typically higher than those published earlier using conventional batch or microwave processes were achieved. PMID:29507637
Density and rectangularity of planting influence 20-year growth and development of red alder.

Treesearch

Dean S. DeBell; Constance A. Harrington

2002-01-01

Red alder (Alnus rubra Bong.) seedlings were planted in northwestern Oregon, U.S.A., at five initial spacings: 0.6 Ã 1.2 m, 1.2 Ã 1.2 m, 1.2 Ã 1.8 m, 1.8 Ã 1.8 m, and 2.5 Ã 2.5 m. Up to about age 10, tree and stand characteristics were correlated primarily with initial planting density in the expected manner; through age 20, however, tree growth...
Moderate forest disturbance as a stringent test for gap and big-leaf models

NASA Astrophysics Data System (ADS)

Bond-Lamberty, B. P.; Fisk, J.; Holm, J. A.; Bailey, V. L.; Gough, C. M.

2014-12-01

Disturbance-induced tree mortality is a key factor regulating the carbon balance of a forest, but tree mortality and its subsequent effects are poorly represented processes in terrestrial ecosystem models. In particular, it is unclear whether models can robustly simulate moderate (non-catastrophic) disturbances, which tend to increase biological and structural complexity and are increasingly common in aging U.S. forests. We tested whether three forest ecosystem models—Biome-BGC, a classic big-leaf model, and the ED and ZELIG gap-oriented models—could reproduce the resilience to moderate disturbance observed in an experimentally manipulated forest (the Forest Accelerated Succession Experiment in northern Michigan, USA, in which 38% of canopy dominants were stem girdled and compared to control plots). Each model was parameterized, spun up, and disturbed following similar protocols, and run for 5 years post-disturbance. The models replicated observed declines in aboveground biomass well. Biome-BGC captured the timing and rebound of observed leaf area index (LAI), while ED and ZELIG correctly estimated the magnitude of LAI decline. None of the models fully captured the observed post-disturbance C fluxes. Biome-BGC net primary production (NPP) was correctly resilient, but for the wrong reasons, while ED and ZELIG exhibited large, unobserved drops in NPP and net ecosystem production. The biological mechanisms proposed to explain the observed rapid resilience of the C cycle are typically not incorporated by these or other models. As a result we expect that most ecosystem models, developed to simulate processes following stand-replacing disturbances, will not simulate well the gradual and less extensive tree mortality characteristic of moderate disturbances.
Moderate forest disturbance as a stringent test for gap and big-leaf models

NASA Astrophysics Data System (ADS)

Bond-Lamberty, B.; Fisk, J.; Holm, J. A.; Bailey, V.; Gough, C. M.

2014-07-01

Disturbance-induced tree mortality is a key factor regulating the carbon balance of a forest, but tree mortality and its subsequent effects are poorly represented processes in terrestrial ecosystem models. In particular, it is unclear whether models can robustly simulate moderate (non-catastrophic) disturbances, which tend to increase biological and structural complexity and are increasingly common in aging US forests. We tested whether three forest ecosystem models - Biome-BGC, a classic big-leaf model, and the ED and ZELIG gap-oriented models - could reproduce the resilience to moderate disturbance observed in an experimentally manipulated forest (the Forest Accelerated Succession Experiment in northern Michigan, USA, in which 38% of canopy dominants were stem girdled and compared to control plots). Each model was parameterized, spun up, and disturbed following similar protocols, and run for 5 years post-disturbance. The models replicated observed declines in aboveground biomass well. Biome-BGC captured the timing and rebound of observed leaf area index (LAI), while ED and ZELIG correctly estimated the magnitude of LAI decline. None of the models fully captured the observed post-disturbance C fluxes. Biome-BGC net primary production (NPP) was correctly resilient, but for the wrong reasons, while ED and ZELIG exhibited large, unobserved drops in NPP and net ecosystem production. The biological mechanisms proposed to explain the observed rapid resilience of the C cycle are typically not incorporated by these or other models. As a result we expect that most ecosystem models, developed to simulate processes following stand-replacing disturbances, will not simulate well the gradual and less extensive tree mortality characteristic of moderate disturbances.

The effects of soak temperature on sugar maple seed germination

Treesearch

Carol A. Janerette

1978-01-01

The temperature at which sugar maple seeds were soaked before stratification significantly influenced their germination. Maximal germination was obtained when seeds were soaked at 4?C, but if seeds were soaked at 25?C, germination decreased and the stratification requirement increased.
Macronutrient deficiency symptoms in seedlings of four northern hardwoods.

Treesearch

Gayne G. Erdmann; Frederick T. Metzger; Robert R. Oberg

1979-01-01

Illustrates and describes the visual deficiency symptoms for N, P, K, Ca, Mg, and S in sugar maple, red maple, white ash, and paper birch seedlings. Effects of these deficiencies on the development and nutrient composition of seedlings are also examined.
Foliar nutrient concentrations of oak, hickory, and red maple

Treesearch

Amy J. Scherzer; Robert P. Long; Joanne Rebbeck

2003-01-01

Early autumn foliar nutrient concentrations of overstory oak (white oak [Quercus alba L.] or chestnut oak [Q. prinus L.]) understory hickory (mockernut hickory [Carya tomentosa (Poir.) Nutt.] or pignut hickory [C. glabra (Mill.) Sweet]), and both overstory and understory red maple (...
Leafhopper control in filed-grown red maples with systemic insecticides

USDA-ARS?s Scientific Manuscript database

Red maple, a popular landscape tree, can be susceptible to foliar damage caused by potato leafhopper feeding. Typical potato leafhopper injury includes distorted leaf tissue and reduced shoot growth. This research identified systemic neonicotinoid insecticides, Allectus and Discus, which controlled...
Effects of UV-B radiation on phenolic composition and deposition patterns and leaf physiology in three Eastern tree species

NASA Astrophysics Data System (ADS)

Sullivan, Joseph H.; Gitz, Dennis C.; Peek, Michael S.; McElrone, Andrew J.

2002-01-01

Quantitative changes in foliar chemistry in response to UVB radiation are frequently reported but less is known about the qualitative changes in putative UV-screening compounds. It has also not been conclusively shown whether qualitative differences in screening compounds or differences in localization patterns influences the sensitivity of plants to damage from UVB radiation. In this study we evaluated the chemical composition and deposition patterns of UV-absorbing compounds in three tree species and assayed these species for possible effects on gas exchange and photosynthetic carbon assimilation. Branches of mature trees of sweetgum (Liquidambar styraciflua), tulip poplar (Liriodendron tulipifera) and red maple (Acer rubrum) were exposed to supplemental levels of UVB radiation over three growing seasons. Controls for UVA were also measured by exposing branches to supplemental UVA only, and additional branches not irradiated were also used for controls. These species demonstrated contrasting chemical composition and deposition patterns with poplar being the most responsive in terms of epidermal accumulation of phenolics including flavonols and chlorogenic acid and hydroxycinnamates. Sweetgum and red maple showed increases primarily in hydroxycinnamates, particularly in the mesophyll in red maple. Leaf area was marginally influenced by UV exposure level. Assimilation was generally not reduced by UVB radiation in these species and was enhanced in red maple by both UVB and UVA and by UVA in sweetgum. These finding are consistent with a hypothesis that epidermal attenuation of UVB would only be reduced in poplar, which accumulated the additional epidermal screening compounds. It is possible that photosynthetic efficiency was enhanced in red maple by the increased absorption of blue light within the mesophyll. Stomatal conductance was generally reduced, and this led to an increase in water use efficiency in red maple and poplar.
Simulated root dynamics of a 160-year-old sugar maple (Acer saccharum Marsh.) tree with and without ozone exposure using the TREGRO model.

PubMed

Retzlaff, W. A.; Weinstein, D. A.; Laurence, J. A.; Gollands, B.

1996-01-01

Because of difficulties in directly assessing root responses of mature forest trees exposed to atmospheric pollutants, we have used the model TREGRO to analyze the effects of a 3- and a 10-year exposure to ozone (O(3)) on root dynamics of a simulated 160-year-old sugar maple (Acer saccharum Marsh.) tree. We used existing phenological, allometric, and growth data to parameterize TREGRO to produce a simulated 160-year-old tree. Simulations were based on literature values for sugar maple fine root production and senescence and the photosynthetic responses of sugar maple seedlings exposed to O(3) in open-top chambers. In the simulated 3-year exposure to O(3), 2 x ambient atmospheric O(3) concentrations reduced net carbon (C) gain of the 160-year-old tree. This reduction occurred in the C storage pools (total nonstructural carbohydrate, TNC), with most of the reduction occurring in coarse (woody) roots. Total fine root production and senescence were unaffected by the simulated 3-year exposure to O(3). However, extending the simulated O(3) exposure period to 10 years depleted the TNC pools of the coarse roots and reduced total fine root production. Similar reductions in TNC pools have been observed in forest-grown sugar maple trees exhibiting symptoms of stress. We conclude that modeling can aid in evaluating the belowground response of mature forest trees to atmospheric pollution stress and could indicate the potential for gradual deterioration of tree health under conditions of long-term stress, a situation similar to that underlying the decline of sugar maple trees.
An interpenetrating HA/G/CS biomimic hydrogel via Diels-Alder click chemistry for cartilage tissue engineering.

PubMed

Yu, Feng; Cao, Xiaodong; Zeng, Lei; Zhang, Qing; Chen, Xiaofeng

2013-08-14

In order to mimic the natural cartilage extracellular matrix, a novel biological degradable interpenetrating network hydrogel was synthesized from the gelatin (G), hyaluronic acid (HA) and chondroitin sulfate (CS) by Diels-Alder "click" chemistry. HA was modified with furylamine and G was modified with furancarboxylic acid respectively. (1)H NMR spectra and elemental analysis showed that the substitution degrees of HA-furan and G-furan were 71.5% and 44.5%. Then the hydrogels were finally synthesized by cross-linking furan-modified HA and G derivatives with dimaleimide poly(ethylene glycol) (MAL-PEG-MAL). The mechanical and degradation properties of the hydrogels could be tuned simply through varying the molar ratio between furan and maleimide. Rheological, mechanical and degradation studies demonstrated that the Diels-Alder "click" chemistry is an efficient method for preparing high performance biological interpenetrating hydrogels. This biomimic hydrogel with improved mechanical properties could have great potential applications in cartilage tissue engineering. Copyright © 2013 Elsevier Ltd. All rights reserved.
Theoretical study of Diels-Alder cycloadditions of butadiene to C{sub 70}. An insight into the chemical reactivity of C{sub 70} as compared to C{sub 60}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mestres, J.; Duran, M.; Sola, M.

1996-05-02

The eight unique Diels-Alder cycloadditions of butadiene to C{sub 70} are analyzed theoretically and compared with the well-established, two possible Diels-Alder cycloadditions of butadiene to C{sub 60}. Full geometry optimizations of reactants, adducts, and transition states are performed using the AMI semiempirical method followed by single-point ab initio energy calculations. The results show that the cycloaddition of butadiene to the C{sub 70} fullerene in the gas phase is slightly more reactive than that to C{sub 60}. However, in toluene solution calculations yield that the different solvent effects on C{sub 60} and C{sub 70} cause a significant decrease of the energymore » barrier in the C{sub 60} cycloaddition, thus predicting a larger reactivity for C{sub 60} as compared to the C{sub 70} fullerene. 36 refs., 2 figs., 3 tabs.« less
Deterioration of sugar maple following logging damage

Treesearch

Gene A. Hesterberg

1957-01-01

The northern hardwood forest comprises about 9 million acres in the Lake States region. Most of this timber is in Upper Michigan and Wisconsin, with lesser amounts in Minnesota, It consists primarily of sugar maple (Acer saccharum Marsh.), yellow birch (Betula alleghaniensis Britt,), basswood (Tilia americana...
Variation in bark characters and wood specific gravity of sugar maple

Treesearch

Robert L. Sajdak

1968-01-01

The external appearance of the bark of sugar maple (Acer saccharum Marsh.) has been described as "deeply furrowed," "fissured with long irregular thick plates or ridges," "somewhat scaly," "sometimes curling," and "highly variable." Adjacent trees in natural stands often have strikingly different...
Chapter 9:Red maple lumber resources for glued-laminated timber beams

Treesearch

John J. Janowiak; Harvey B. Manbeck; Roland Hernandez; Russell C. Moody

2005-01-01

This chapter evaluates the performance of red maple glulam beams made from two distinctly different lumber resources: 1. logs sawn using practices normally used for hardwood appearance lumber recovery; and 2. lower-grade, smaller-dimension lumber primarily obtained from residual log cants.
Identification of canopy strata in Allegheny hardwood stands

Treesearch

David W. McGill; Stephen B. Jones; Christopher A. Nowak

1995-01-01

Allegheny hardwood stands typically develop vertical canopy layers, or strata, due to differential species-specific growth rates and tolerance to shade. Across the Allegheny Plateau, black cherry dominates the main canopy, while sugar maple, American beech, and red maple are relegated to subcanopy strata.
Woody browse production

Treesearch

Tom Crow; Forest Stearns

1992-01-01

Sugar maple has great potential as wildlife food, especially as good winter fare for deer in the northern Lake States. Deer will diligently seek out sugar maple browse in the hardwood forests along the edges of a winter yard or in isolated islands of upland forest within a yard.
Improving students’ understanding of mathematical concept using maple

NASA Astrophysics Data System (ADS)

Ningsih, Y. L.; Paradesa, R.

2018-01-01

This study aimed to improve students’ understanding of mathematical concept ability through implementation of using Maple in learning and expository learning. This study used a quasi-experimental research with pretest-posttest control group design. The sample on this study was 61 students in the second semester of Mathematics Education of Universitas PGRI Palembang, South Sumatera in academic year 2016/2017. The sample was divided into two classes, one class as the experiment class who using Maple in learning and the other class as a control class who received expository learning. Data were collective through the test of mathematical initial ability and mathematical concept understanding ability. Data were analyzed by t-test and two ways ANOVA. The results of this study showed (1) the improvement of students’ mathematical concept understanding ability who using Maple in learning is better than those who using expository learning; (2) there is no interaction between learning model and students’ mathematical initial ability toward the improvement of students’ understanding of mathematical concept ability.
Współczesny opad pyłku lipy i klonu jako przyczynek do palinologicznej interpretacji gleb kopalnych / The deposition of lime and maple pollen as a contribution to the palynological interpretation of fossil soils

NASA Astrophysics Data System (ADS)

Mędrek, Karolina; Hołub, Beata; Bałaga, Krystyna

2013-06-01

This paper aims to explore the modern deposition of lime and maple pollen in various plant communities as compared to the results obtained in palynological analyses of the Holocene paleosols in Kaczórki (the Middle Roztocze) and the Błędów Desert which are characterized by very high amounts of the pollen of these trees. The research shows that a high annual deposition of both lime and maple pollen on the soil surface is possible. This deposition far surpasses the average pollen values recorded in the Holocene but is not as high as those recorded in fossil soils. In relation to paleosols in Kaczórki such results show that lime and maple were important components of forests surrounding dune and simultaneously point to the fact that the deposition of pollen in these soils was a complex process.
Institutional and relational determinants in high- and medium-extent food product crises: the inner perspective of a public health crisis.

PubMed

Charlebois, Sylvain; Horan, Hilary

2010-08-01

In 2008, Canada enacted its biggest-ever food recall in response to a Listeria crisis, stemming from a Maple Leaf Foods plant, that killed 22 Canadians. Afterwards, Maple Leaf's market share quickly returned to pre-crisis levels, but the long-term repercussions of the scare still reverberate in Maple Leaf's brand. In this case study, which offers an organizational perspective on the food recall, data was collected, through in-depth interviews of persons involved in the crisis response, and analyzed. The aim of this paper is to make transparent the ways in which Maple Leaf Foods organized their resources to manage the 2008 food recall. Results reveal that institutional and relational determinants are the most important factors in high- and medium-extent food product crises, whereas external and internal effects primarily influence an organization's capacity to cope with severe crises. Based on these findings, a conceptual framework is presented and managerial implications are discussed.
The changes in leaf reflectance of sugar maple seedlings (Acer saccharum Marsh) in response to heavy metal stress

NASA Technical Reports Server (NTRS)

Schwaller, M. R.; Schnetzler, C. C.; Marshall, P. E.

1981-01-01

The effects of heavy metal stress on leaf reflectance of sugar maple seedlings (Acer saccharum Marsh) are examined. It is found that sugar maple seedlings treated with anomalous amounts of heavy metals in the rooting medium exhibited an increased leaf reflectance over the entire range of investigated wavelengths, from 475 to 1650 nm. These results conform to those of a previous investigation in the wavelengths from 475 to 660nm, but tend to contradict the previous study in the near infrared wavelengths from 1000 to 1650nm. The differences may possible be due to different water regimes in the two investigations.
Supplement Analysis for the Transmission System Vegetation Management Program FEIS (DOE/EIS-0285/SA-60) - Rocky Reach - Maple Valley No. 1

DOE Office of Scientific and Technical Information (OSTI.GOV)

Martin, Mark A.

2002-04-15

Vegetation Management along the Rocky Reach – Maple Valley No. 1 Transmission Line ROW from structure 110/1 to the Maple Valley Substation. The transmission line is a 500 kV line. BPA proposes to clear targeted vegetation along access roads and around tower structures that may impede the operation and maintenance of the subject transmission line. BPA plans to conduct vegetation management along existing access road and around structure landings for the purpose of maintaining access to structures site. All work will be in accordance with the National Electrical Safety Code and BPA standards.
Maple syrup-production, composition, chemistry, and sensory characteristics.

PubMed

Perkins, Timothy D; van den Berg, Abby K

2009-01-01

Maple syrup is made from sap exuded from stems of the genus Acer during the springtime. Sap is a dilute solution of primarily water and sucrose, with varying amounts of amino and organic acids and phenolic substances. When concentrated, usually by heating, a series of complex reactions produce a wide variety of flavor compounds that vary due to processing and other management factors, seasonal changes in sap chemistry, and microbial contamination. Color also forms during thermal evaporation. Flavor and color together are the primary factors determining maple syrup grade, and syrup can range from very light-colored and delicate-flavored to very dark-colored and strong-flavored.
Histological relationship of Phytobia setosa to Acer saccharum

Treesearch

Robert Gregory; William Wallner

1979-01-01

The maple cambium miner, Phytobia setosa (Loew), attacks Acer spp., producing ray flecks which result in degrade in face veneer and furniture wood. Samples from infested sugar maple, Acer saccharum Marsh, trees demonstrated that while mines passed close to the vascular cambium the initial cells were not...

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