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Sample records for alkaline pluton kola

  1. Typochemistry of rinkite and products of its alteration in the Khibiny Alkaline pluton, Kola Peninsula

    NASA Astrophysics Data System (ADS)

    Konopleva, N. G.; Ivanyuk, G. Yu.; Pakhomovsky, Ya. A.; Yakovenchuk, V. N.; Mikhailova, Yu. A.; Selivanova, E. A.

    2015-12-01

    The occurrence, morphology, and composition of rinkite are considered against the background of zoning in the Khibiny pluton. Accessory rinkite is mostly characteristic of foyaite in the outer part of pluton, occurs somewhat less frequently in foyaite and rischorrite in the central part of pluton, even more sparsely in foidolites and apatite-nepheline rocks, and sporadically in fenitized xenoliths of the Lovozero Formation. The largest, up to economic, accumulations of rinkite are related to the pegmatite and hydrothermal veins, which occur in nepheline syenite on both sides of the Main foidolite ring. The composition of rinkite varies throughout the pluton. The Ca, Na, and F contents in accessory rinkite and amorphous products of its alteration progressively increase from foyaite and fenitized basalt of the Lovozero Formation to foidolite, rischorrite, apatite-nepheline rocks, and pegmatite-hydrothermal veins.

  2. Rock-Forming feldspars of the Khibiny alkaline pluton, Kola Peninsula, Russia

    NASA Astrophysics Data System (ADS)

    Ivanyuk, G. Yu.; Pakhomovsky, Ya. A.; Konopleva, N. G.; Kalashnikov, A. O.; Korchak, Yu. A.; Selivanova, E. A.; Yakovenchuk, V. N.

    2010-12-01

    This paper describes the structural-compositional zoning of the well-known Khibiny pluton in regard to rock-forming feldspars. The content of K-Na-feldspars increases inward and outward from the Main foidolite ring. The degree of coorientation of tabular K-Na-feldspar crystals sharply increases in the Main ring zone, and microcline-dominant foyaite turns into orthoclase-dominant foyaite. The composition of K-Na-feldspars in the center of the pluton and the Main ring zone is characterized by an enrichment in Al. This shift is compensated by a substitution of some K and Na with Ba (the Main ring zone) or by an addition of K and Na cations to the initially cation-deficient microcline (the central part of the pluton). Feldspars of volcanosedimentary rocks occurring as xenoliths in foyaite primarily corresponded to plagioclase An15-40, but high-temperature fenitization and formation of hornfels in the Main ring zone gave rise to the crystallization of anorthoclase subsequently transformed into orthoclase and albite due to cooling and further fenitization. Such a zoning is the result of filling the Main ring fault zone within the homogeneous foyaite pluton with a foidolite melt, which provided the heating and potassium metasomatism of foyaite and xenoliths of volcanosedimentary rocks therein. The process eventually led to the transformation of foyaite into rischorrite-lyavochorrite, while xenoliths were transformed into aluminum hornfels with anorthoclase, annite, andalusite, topaz, and sekaninaite.

  3. Kyanoxalite, a new cancrinite-group mineral species with extraframework oxalate anion from the Lovozero alkaline pluton, Kola Peninsula

    NASA Astrophysics Data System (ADS)

    Chukanov, N. V.; Pekov, I. V.; Olysych, L. V.; Massa, W.; Yakubovich, O. V.; Zadov, A. E.; Rastsvetaeva, R. K.; Vigasina, M. F.

    2010-12-01

    Kyanoxalite, a new member of the cancrinite group, has been identified in hydrothermally altered hyperalkaline rocks and pegmatites of the Lovozero alkaline pluton, Kola Peninsula, Russia. It was found at Mount Karnasurt (holotype) in association with nepheline, aegirine, sodalite, nosean, albite, lomonosovite, murmanite, fluorapatite, loparite, and natrolite and at Mt. Alluaiv. Kyanoxalite is transparent, ranging in color from bright light blue, greenish light blue and grayish light blue to colorless. The new mineral is brittle, with a perfect cleavage parallel to (100). Mohs hardness is 5-5.5. The measured and calculated densitiesare 2.30(1) and 2.327 g/cm3, respectively. Kyanoxalite is uniaxial, negative, ω = 1.794(1), ɛ = 1.491(1). It is pleochroic from colorless along E to light blue along O. The IR spectrum indicates the presence of oxalate anions C2O{4/2-} and water molecules in the absence of CO{3/2-} Oxalate ions are confirmed by anion chromatography. The chemical composition (electron microprobe; water was determined by a modified Penfield method and carbon was determined by selective sorption from annealing products) is as follows, wt %: 19.70 Na2O, 1.92 K2O, 0.17 CaO, 27.41 Al2O3, 38.68 SiO2, 0.64 P2O5, 1.05 SO3, 3.23 C2O3, 8.42 H2O; the total is 101.18. The empirical formula (Z = 1) is (Na6.45K0.41Ca0.03)Σ6.89(Si6.53Al5.46O24)[(C2O4)0.455(SO4)0.13(PO4)0.09(OH)0.01]Σ0.68 · 4.74H2O. The idealized formula is Na7(Al5-6Si6-7O24)(C2O4)0.5-1 · 5H2O. Kyanoxalite is hexagonal, the space group is P63, a = 12.744(8), c = 5.213(6) -ray powder diffraction pattern are as follows, [ d, [A] ( I, %)( hkl)]: 6.39(44) (110), 4.73 (92) (101), 3.679 (72) (300), 3.264 (100) (211, 121), 2.760 (29) (400), 2.618 (36) (002), 2.216, (29) (302, 330). According to the X-ray single crystal study ( R = 0.033), two independent C2O4 groups statistically occupy the sites on the axis 63. The new mineral is the first natural silicate with an additional organic anion and is the most

  4. Yegorovite, Na4[Si4O8(OH)4]·7H2O, a new mineral from the Lovozero alkaline pluton, Kola Peninsula

    NASA Astrophysics Data System (ADS)

    Pekov, I. V.; Zubkova, N. V.; Chukanov, N. V.; Zadov, A. E.; Grishin, V. G.; Pushcharovsky, D. Yu.

    2010-12-01

    A new mineral, yegorovite, has been identified in the late hydrothermal, low-temperature assemblage of the Palitra hyperalkaline pegmatite at Mt. Kedykverpakhk, Lovozero alkaline pluton, Kola Peninsula, Russia. The mineral is intimately associated with revdite and megacyclite, earlier natrosilite, microcline, and villiaumite. Yegorovite occurs as coarse, usually split prismatic (up to 0.05 × 0.15 × 1 mm) or lamellar (up to 0.05 × 0.7 × 0.8 mm) crystals. Polysynthetic twins and parallel intergrowths are typical. Mineral individuals are combined in bunches or chaotic groups (up to 2 mm); radial-lamellar clusters are less frequent. Yegorovite is colorless, transparent with vitreous luster. Cleavage is perfect parallel to (010) and (001). Fracture is splintery; crystals are readily split into acicular fragments. The Mohs hardness is ˜2. Density is 1.90(2) g/cm3 (meas) and 1.92 g/cm3 (calc). Yegorovite is biaxial (-), with α = 1.474(2), β = 1.479(2), and γ = 1.482(2), 2 V meas > 70°, 2 V calc = 75°. The optical orientation is X ∧ a ˜ 15°, Y = c, Z = b. The IR spectrum is given. The chemical composition determined using an electron microprobe (H2O determined from total deficiency) is (wt %): 23.28 Na2O, 45.45 SiO2, 31.27 H2Ocalc; the total is 100.00. The empirical formula is Na3.98Si4.01O8.02(OH)3.98 · 7.205H2O. The idealized formula is Na4[Si4O8(OH)4] · 7H2O. Yegorovite is monoclinic, space group P21/ c. The unit-cell dimensions are a = 9.874, b= 12.398, c = 14.897 Å, β = 104.68°, V = 1764.3 Å3, Z = 4. The strongest reflections in the X-ray powder pattern ( d, Å ( I, %)([ hkl]) are 7.21(70)[002], 6.21(72)[012, 020], 4.696(44)[022], 4.003(49)[211], 3.734(46)[ bar 2 13], 3.116(100)[024, 040], 2.463(38)[ bar 4 02, bar 2 43]. The crystal structure was studied by single-crystal method, R hkl = 0.0745. Yegorovite is a representative of a new structural type. Its structure consists of single chains of Si tetrahedrons [Si4O8(OH)4]∞ and sixfold polyhedrons

  5. Shlykovite KCa[Si4O9(OH)] · 3H2O and cryptophyllite K2Ca[Si4O10] · 5H2O, new mineral species from the Khibiny alkaline pluton, Kola Peninsula, Russia

    NASA Astrophysics Data System (ADS)

    Pekov, I. V.; Zubkova, N. V.; Filinchuk, Ya. E.; Chukanov, N. V.; Zadov, A. E.; Pushcharovsky, D. Yu.; Gobechiya, E. R.

    2010-12-01

    New minerals, shlykovite and cryptophyllite, hydrous Ca and K phyllosilicates, have been identified in hyperalkaline pegmatite at Mount Rasvumchorr, Khibiny alkaline pluton, Kola Peninsula, Russia. They are the products of low-temperature hydrothermal activity and are associated with aegirine, potassium feldspar, nepheline, lamprophyllite, eudialyte, lomonosovite, lovozerite, tisinalite, shcherbakovite, shafranovskite, ershovite, and megacyclite. Shlykovite occurs as lamellae up to 0.02 × 0.02 × 0.5 mm in size or fibers up to 0.5 mm in length usually combined in aggregates up to 3 mm in size, crusts, and parallel-columnar veinlets. Cryptophyllite occurs as lamellae up to 0.02 × 0.1 × 0.2 mm in size intergrown with shlykovite being oriented parallel to {001} or chaotically arranged. Separate crystals of the new minerals are transparent and colorless; the aggregates are beige, brownish, light cream, and pale yellowish-grayish. The cleavage is parallel to (001) perfect. The Mohs hardness of shlykovite is 2.5-3. The calculated densities of shlykovite and cryptophyllite are 2.444 and 2.185 g/cm3, respectively. Both minerals are biaxial; shlykovite: 2 V meas = -60(20)°; cryptophyllite: 2 V meas > 70°. The refractive indices are: shlykovite: α = 1.500(3), β = 1.509(2), γ = 1.515(2); cryptophyllite: α = 1.520(2), β = 1.523(2), γ = 1.527(2). The chemical composition of shlykovite determined by an electron microprobe (H2O determined from total deficiency) is as follows, wt %: 0.68 Na2O, 11.03 K2O, 13.70 CaO, 59.86 SiO2, 14.73 H2O; the total is 100.00. The empirical formula calculated on the basis of 13 O atoms (OH/H2O calculated from the charge balance) is (K0.96Na0.09)Σ1.05Ca1.00Si4.07O9.32(OH)0.68 · 3H2O. The idealized formula is KCa[Si4O9(OH)] · 3H2O. The chemical composition of cryptophyllite determined by an electron microprobe (H2O determined from the total deficiency) is as follows, wt %: 1.12 Na2O, 17.73 K2O, 11.59 CaO, 0.08 Al2O3, 50.24 SiO2, 19.24 H2

  6. Davinciite, Na12K3Ca6Fe{3/2+}Zr3(Si26O73OH)Cl2, a New K,Na-Ordered mineral of the eudialyte group from the Khibiny Alkaline Pluton, Kola Peninsula, Russia

    NASA Astrophysics Data System (ADS)

    Khomyakov, A. P.; Nechelyustov, G. N.; Rastsvetaeva, R. K.; Rozenberg, K. A.

    2013-12-01

    This paper presents a description of a new zirconosilicate of the eudialyte group, which was named davinciite in honor of Leonardo da Vinci (1452-1519), a famous Italian scientist, painter, sculptor and architect. The new mineral has been found in hyperagpaitic pegmatite at the Rasvumchorr Mountain, Khibiny Pluton, Kola Peninsula, as relict inclusions, up to 1-2 mm in size in a rastsvetaevite matrix. It is associated with nepheline, sodalite, potassium feldspar, delhayelite, aegirine, shcherbakovite, villiaumite, nitrite, nacaphite, rasvumite, and djerfisherite. Davinciite is dark lavender and transparent, with a vitreous luster and white streak. The new mineral is brittle, with conchoidal fracture; the Mohs' hardness is 5. No indications of cleavage or parting were observed. The measured density is 2.82(2) g/cm3 (volumetric method); the calculated density is 2.848 g/cm3. Davinciite is optically uniaxial, positive; ω = 1.603(2), ɛ = 1.605(2). It is nonpleochroic and nonfluorescent in UV light. The new mineral slowly breaks down and gelates in 50% HCl and HNO3. It is trigonal, space group R3m. The unit-cell dimensions are a = 14.2956(2), c = 30.0228(5) Å, V=5313.6(2) Å3. The strongest reflections in the X-ray powder diffraction pattern [ d, Å ( I, %) ( hkl)] are as follows: 2.981(100)(315), 2.860(96)(404), 4.309(66)(205), 3.207(63)(208), 6.415(54)(104), 3.162(43)(217). The chemical composition (electron microprobe, H2O calculated from X-ray diffraction data) is as follows, wt %: 12.69 Na2O, 3.53 K2O, 11.02 CaO, 0.98 SrO, 0.15 BaO, 5.33 FeO, 0.37 MnO, 0.07 Al2O3, 51.20 SiO2, 0.39 TiO2, 11.33 ZrO2, 0.21HfO2, 0.09 Nb2O5, 1.89 Cl, 0.93H2O, -O = Cl2 0.43; total is 99.75. The empirical formula calculated on the basis of Si + Al + Zr + Hf + Ti + Nb = 29 ( Z = 3) is (Na1l.75Sr0.29Ba0.03)Σ12.07(K2.28Na0.72)Σ3Ca5.99(Fe2.26Mn0.16)Σ2.42(Zr2.80Ti0.15Hf0.03Nb0.02) Σ3(Si1.96Al0.04)Σ2[Si3O9]2 [Si9O27]2[(OH)1.42O0.58]Σ2[Cl1.62(H2O)0.38]Σ2 · 0.48H2O. The simplified

  7. Voronkovite, Na15(Na,Ca,Ce)3(Mn,Ca)3Fe3Zr3Si26O72(OH,O)4Cl · H2O, a new mineral species of the eudialyte group from the Lovozero alkaline pluton, Kola Peninsula, Russia

    NASA Astrophysics Data System (ADS)

    Khomyakov, A. P.; Nechelyustov, G. N.; Rastsvetaeva, R. K.

    2009-12-01

    This paper describes a new member of the eudialyte group named in honor of Alexander Alexandrovich Voronkov (1928-1982), the prominent Russian crystallographer. The new mineral has been found in the Shkatulka hyperalkaline pegmatite body at Mt. Alluaiv, Lovozero alkaline pluton, Kola Peninsula, Russia. The mineral is associated with microcline, sodalite, nepheline, aegirine, terskite, lomonosovite, vuonnemite, shkatulkalite, manganoneptunite, and sphalerite. Voronkovite occurs as rounded, poorly faced crystals up to 2-5 mm across. The new mineral is light brown, with vitreous luster and conchoidal fracture. The streak is white. Voronkovite is transparent and brittle; the Mohs hardness is 5; cleavage or parting is not observed. D(meas) = 2.97(2) g/cm3 (volumetric method); D(calc) = 2.95 g/cm3. The new mineral is uniaxial, positive, pleochroic from lemon yellow along X to brownish pink along Y, and is not luminescent in UV light. Voronkovite easily dissolves and gelates in acid at room temperature. The new mineral is trigonal, space group R3, a = 14.205(7), c = 30.265(15) Å, V = 5289(8) Å3, Z = 3. The strongest reflections in the X-ray diffraction pattern [ d, Å ( I)( hkl)] are 2.970(100)(315), 4.316(85)(205), 2.848(84)(404), 3.221(43)(208), 3.536(41)(027), 3.039(41)(119). The chemical composition (electron microprobe, H2O determined with chemical analysis) is as follows, wt %: 15.84 Na2O, 0.28 K2O, 3.08 CaO, 1.76 SrO, 4.65 MnO, 3.53 FeO, 0.93 La2O3, 1.36 Ce2O3, 0.68 Nd2O3, 0.15 Al2O3, 49.48 SiO2, 0.33 TiO2, 14.11 ZrO2, 0.23 HfO2, 0.91 Nb2O5, 0.44 Cl, 0.21 F, 1.56 H2O, 0.19 -O = (Cl,F)2; total is 99.34. The empirical formula calculated on the basis of Si + Al = 26 ( Z = 3) is as follows: (Na13.96Sr0.54K0.19)Σ14.69(Na1.64Ca0.92Ce0.26 La0.18)Σ3.00(Mn2.06Ca0.81Nd0.13)Σ3.00(F1.54Zr0.60Na0.48Nb0.21Ti0.13Hf0.04)Σ3.00Zr3.00(Si1.91Al0.09)Σ2.00(Si24O72)[(OH)2.98 O1.02]Σ4(Cl0.39F0.35)Σ0.74 · 1.23H2O. The simplified formula is Na15(Na,Ca,Ce)3(Mn,Ca)3Fe3Zr3Si26O72(OH

  8. Dualite, Na30(Ca,Na,Ce,Sr)12(Na,Mn,Fe,Ti)6Zr3Ti3MnSi51O144(OH,H2O,Cl)9, a new zircono-titanosilicate with a modular eudialyte-like structure from the Lovozero alkaline Pluton, Kola Peninsula, Russia

    NASA Astrophysics Data System (ADS)

    Khomyakov, A. P.; Nechelyustov, G. N.; Rastsvetaeva, R. K.

    2008-12-01

    Dualite has been found at Mount Alluaiv, the Lovozero Pluton, the Kola Peninsula in peralkaline pegmatoid as sporadic, irregularly shaped grains up to 0.3-0.5 mm across. K-Na feldspar, nepheline, sodalite, cancrinite, aegirine, alkaline amphibole, eudialyte, lovozerite, lomonosovite, vuonnemite, lamprophyllite, sphalerite, and villiaumite are associated minerals. Dualite is yellow, transparent or translucent, with conchoidal fracture. The new mineral is brittle, with vitreous luster and white streaks. The Mohs hardness is 5. The measured density is 2.84(3) g/cm3 (volumetric method); the calculated density is 2.814 g/cm3. Dualite dissolves and gelates in acid at room temperature. It is nonfluorescent. The new mineral is optically uniaxial and positive; ω = 1.610(1), ɛ = 1.613(1). Dualite is trigonal, space group R3 m. The unit cell dimensions are a = 14.153(9), c = 60.72(5) Å, V = 10533(22) Å, Z = 3. The strongest reflections in the X-ray powder pattern [ d, Å ( I,%)( hkl)] are as follows: 7.11(40)(110), 4.31(50)(0.2.10), 2.964(100)(1.3.10), 2.839(90)(048), 2.159(60)(2.4.10, 0.4.20), 1.770(60)(2.4.22, 4.0.28, 440), 1362(50)(5.5.12, 3.0.42). The chemical composition (electron microprobe, H2O calculated from X-ray diffraction data) is as follows, wt %: 17.74 Na2O, 0.08 K2O, 8.03 CaO, 1.37 SrO, 0.29 BaO, 2.58 MnO, 1.04 FeO, 0.79 La2O3, 1.84 C2O3, 0.88 Nd2O3, 0.20 Al2O3, 51.26 SiO2, 4.40 TiO2, 5.39 ZrO2, 1.94 Nb2O5, 0.58 Cl, 1.39 H2O,-O = 0.13 Cl2; they total is 99.67. The empirical formula calculated on the basis of 106 cations as determined by crystal structure is (Na29.79Ba0.1K0.10)Σ30(Ca8.55Na1.39REE1.27Sr0.79)Σ12 · (Na3.01Mn1.35Fe{0.87/2+}Ti0.77)Σ6(Zr2.61Nb0.39)Σ3 (Ti2.52Nb0.48)Σ3(Mn0.82Si0.18)Σ1(Si50.77Al0.23)Σ51 O144[(OH)6.54(H2O)1.34·Cl0.98]Σ8.86). The simplified formula is Na30(Ca,Na,Ce,Sr)12(Na,Mn,Fe,Ti)6Zr3Ti3 MnSi51O144 (OH,H2O,Cl)9). The name dualite is derived from Latin dualis (dual) alluding to the dual taxonomic membership of this mineral

  9. Uranium-lead dating of perovskite from the Afrikanda plutonic complex (Kola Peninsula, Russia) using LA-ICP-MS.

    NASA Astrophysics Data System (ADS)

    Reguir, E.; Camacho, A.; Yang, P.; Chakhmouradian, A. R.; Halden, N. M.

    2009-04-01

    Perovskite (CaTiO3) is a common early crystallizing accessory phase in a variety of alkaline rocks, and has been shown to contain enough U and Th for U-Pb dating. U and Pb analysis of perovskite has been primarily carried out using the SHRIMP or ID-TIMS techniques, and the resulting U-Pb dates commonly yield the emplacement age of the host rock. To our knowledge, only one U-Pb study of perovskite has been done using the LA-ICP-MS (Cox and Wilton, 2006). Some of the advantages of this method over the SHRIMP and ID-TIMS techniques include greater speed and lower cost of analysis. In this work, the U-Pb ages of perovskite from the Afrikanda plutonic complex (Russia) were obtained in situ using the LA-ICP-MS. The measured 238U/206Pb and 207Pb/206Pb ratios were corrected for time-dependent mass-bias using the well-calibrated zircon standard GJ-1 (608.5 ± 0.4 Ma; Jackson et al., 2004). On a Tera-Wasserburg diagram (Tera and Wasserburg, 1972) the analyses of perovskite from two magmatic phases (clinopyroxenite and carbonatite) plot in separate clusters. Although the variations in the 238U/206Pb and 207Pb/206Pb ratios within each group are small, there is enough dispersion between the two clusters to obtain a reasonably precise age of 375 ± 13 Ma (2; MSWD = 0.23), which strongly suggests that the carbonatitic rocks are broadly coeval with the clinopyroxenite. The only other isotopic study on the Afrikanda Complex was done on a clinopyroxenite using the Rb-Sr method and yielded a whole rock-mineral (perovskite, biotite, augite and apatite) isochron age of 364.0 ± 3.1 Ma (2; MSWD = 0.72). This age is within error of our U-Pb date, which demonstrates that LA-ICP-MS-based U-Pb dating of perovskite can serve as a reliable geochronological tool. References Cox, R.A. and Wilton, D.H.C. (2006) U-Pb dating of perovskite by LA-ICP-MS: An example from the Oka carbonatite, Quebec, Canada. Chem. Geol., 235, 21-32. Jackson, S.E., Pearson, N.J., Griffin, W.L. and Belousova, E.A. (2004

  10. Martian alkaline basites chemically resemble basic rocks of the Lovozero alkaline massif, Kola peninsula

    NASA Astrophysics Data System (ADS)

    Kochemasov, G.

    " (syenite, granite) for Mars [5]. Actually the martian missions successively discovered andesite, dacite, low-Fe highlands. Now "Spirit" has found on a small outlier of highlands -Columbia Hills -a batch of thinly layered gently dipping light rocks that surely are not impact melts as at very short distance there is a sharp transition from light Fe-poor to ultrabasic rocks (on opposite slopes of this small hill) [6]. This layered sequence of more or less altered and weathered rocks resembles differentiated sequences of Lovozero and other alkaline and UB-alkaline massifs of Kola Peninsula (though fresh and much richer in alkalis). Here we compare compositions of alkaline basic rocks of Columbia Hills (dyke or sill [4]) with that of basic volcanics and a later dyke at Lovozero. 5 analyses in wt.%: 1-Backstay (tra1 chybasalt) & 2-Irvine (basalt) of CH, 3-augiteporphyrite, 4-essexite-porphyrite, 5- alkali- lamprophyre dyke of Lovozero. SiO2 -49.9, 47.7, 45.78, 48.09, 41.57; TiO2 - 0.93, 1.07, 7.80, 2.35, 2.92; Al2 O3 -13.2; 10.8, 8.08; 13.74; 11.77; Fe2 O3 -3.40, 7.79 (4.99), 5.90, 6.00, 4.53; FeO -10.6, 12.5 (15.0), 8.65, 7.60, 8.28; MnO -0.25, 0.37, 0.12, 0.17, 0.28; MgO -8.36, 10.8, 7.61, 7.19, 10.59; CaO -6.09, 6.12, 10.73, 8.77, 11.24; Na2 O -4.02, 2.72, 2.80, 2.84, 3.63; K2 O -1.02, 0.69, 1.97, 2.09, 1.38. Compositional similarities between basites occurring in alkaline conditions on both planets can be found. References: [1] Kochemasov G.G. (1999) Theorems of wave planetary tectonics // Geophys. Res. Abstr., v. 1, # 3, 700; [2] Gellert R. et al. (2006) JGR Planets, v. 111, #E2, EO2505; [3] Squyres S.W. et al. (2006) JGR Planets, v.111, #E2, EO2511; [4] McSween H.Y. et al. (2006) JGR Planets, submitted ; [5] Kochemasov G. G. (1995) Golombek M.P., Edgett K.S., Rice J.W. Jr. (Eds). Mars Pathfinder Landing Site Workshop II: Characteristics of the Ares Vallis Region and Field trips to the Channeled Scabland, Washington. LPI Tech. Rpt. 95-01. Pt.1.LPI, Houston, 1995, 63 pp.; [6

  11. Zvyaginite, NaZnNb2Ti[Si2O7]2O(OH,F)3(H2O)4 + x ( x < 1), a new mineral of the epistolite group from the Lovozero Alkaline Pluton, Kola Peninsula, Russia

    NASA Astrophysics Data System (ADS)

    Pekov, I. V.; Lykova, I. S.; Chukanov, N. V.; Yapaskurt, V. O.; Belakovskiy, D. I.; Zolotarev, A. A.; Zubkova, N. V.

    2014-12-01

    A new mineral, zvyaginite, a member of the epistolite group, has been found at Mt. Malyi Punkaruaiv, Lovozero Alkaline Complex, Kola Peninsula, Russia. It occurs in a hydrothermally altered peralkaline pegmatite and is associated with ussingite, microcline, aegirine, sphalerite, vigrishinite, and sauconite. Zvyaginite forms rectangular or irregular-shaped lamellae up to 0.1 × 1 × 2 cm in size when flattened [001]. The mineral is translucent to transparent and colorless, pearly-white, yellowish brownish, pale pink, or violet pink. The luster is nacreous on crystal faces and greasy on broken surfaces. Its Mohs' hardness is 2.5-3. Zvyaginite is brittle. The cleavage parallel to {001} is perfect. D meas = 2.88(3), D calc = 2.94 g/cm3. The mineral is optically biaxial (-), α = 1.626(5), β = 1.714(3), γ = 1.740(5), 2 V meas = 45(15)°, 2 V calc = 55°. The IR spectrum is given. Chemical composition is as follows (wt %; average of five point analyses; H2O was determined using the modified Penfield method): 4.74 Na2O, 0.22 K2O, 0.77 CaO, 1.36 MnO, 0.24 FeO, 9.61 ZnO, 0.19 Al2O3, 29.42 SiO2, 12.33 TiO2, 27.22 Nb2O5, 1.94 F, 12.65 H2O, -0.82 -O = F2, for a total of 99.87. The empirical formula calculated on the basis of Si + Al = 4 is: Na1.24K0.04Ca0.11Mn0.16Fe0.03Zn0.96Nb1.66Ti1.25(Si3.97Al0.03)Σ4O15.07(OH)2.10F0.83(H2O)4.64. The simplified formula is: NaZnNb2Ti[Si2O7]2O(OH,F)3(H2O)4 + x ( x < 1), Zvyaginite is triclinic, , a = 8.975(3), b = 8.979(3), c = 12.135(4) Å, α = 74.328(9)°, β = 80.651(8)°, γ = 73.959(8)°, V = 900.8(6) Å3, Z = 2. The strongest reflections in the X-ray powder pattern ( d, Å- I[ hkl]) are: 11.72-100[001], 5.83-40[002], 5.28-53[-1-11, 112], 4.289-86[200, 021], 3.896-36[-1-12, -201, 003, 022, 113], 2.916-57[310, 132, 004], 2.862-72[130, 312]. The model of the crystal structure was obtained on a single crystal, R = 0.159. Zvyaginite and epistolite are similar in the structure of the NbTiSiO motif, but differ from each other in composition

  12. Late Proterozoic and Silurian alkaline plutons within the southeastern New England Avalon zone

    SciTech Connect

    Hermes, O.D. ); Zartman, R.E. )

    1992-07-01

    Distinct pulses of quartz-bearing, alkaline plutonism and volcanism are known to have occurred in the Avalon zone of southeastern New England during the Late Ordovician, Early Silurian, Devonian, and Carboniferous. Zircon separates from the Franklin and Dartmouth plutons demonstrate that two additional, previously unrecognized periods of alkaline magmatism occurred. The Franklin pluton yields an age of 417 {plus minus} 6 Ma (Late Silurian), whereas the Dartmouth pluton is Late Proterozoic (595 {plus minus} 5 Ma) and markedly older than the other plutons of alkaline affinity. The new ages further emphasize the episodic nature and long-term duration of such alkaline igneous events within the southeastern New England Avalon zone. The Dartmouth pluton may represent a post-collisional alkaline granite emplaced in the Late Proterozoic, almost immediately after a major period of calcalkaline igneous activity that accompanied plate convergence and continental accretion. The abrupt change from orogenic calcalkaline igneous activity to post-collisional alkaline granite, followed by younger episodes of anorogenic emplacement, is remarkably similar to igneous events reported from pan-African mobile belts widespread throughout Africa. In addition, parts of the Dartmouth pluton exhibit features indicative of mixing and commingling of felsic and mafic melts that are associated with coevally formed mylonitic fabrics. Because these fabrics are conformable to those in adjacent gneisses, but discordant with Alleghanian fabrics in the nearby Carboniferous Narragansett basin, they represent some of the best candidates for pre-Alleghanian structures thus far identified in the southeastern New England Avalon zone.

  13. Paleoproterozoic layered PGE-bearing Monchetundra pluton, Kola Peninsula: Sm-Nd age of metamorphic alteration of mafic rocks

    NASA Astrophysics Data System (ADS)

    Kunakkuzin, E. L.; Serov, P. A.; Bayanova, T. B.; Nerovich, L. I.; Borisenko, E. S.

    2015-09-01

    The aim of this work is Sm-Nd study of metamorphic alteration of massive gabbronorites from the Monchetundra pluton. The mafic rocks of the pluton are unevenly metamorphosed up to amphibolite facies with the formation of garnet, hornblende, and other minerals. The presence of garnet is a distinctive feature of this pluton in comparison with other Paleoproterozoic PGE-bearing plutons of the eastern part of the Baltic shield: Mt. General'skaya, Fedorovo-Pana, Imandra lopolith, and Monchepluton [9]. The degree of metamorphic alteration of rocks increases near the faults, the largest of which is Monchetundra fault separating the studied pluton from the Monchepluton. This fault was formed about 1.9-2.0 Ga ago according to Sm-Nd and Rb-Sr mineral isochrons for minerals from metagabbro-anorthosites of the M1 well.

  14. Rare gas isotopes and parent trace elements in ultrabasic-alkaline-carbonatite complexes, Kola Peninsula: identification of lower mantle plume component

    NASA Astrophysics Data System (ADS)

    Tolstikhin, I. N.; Kamensky, I. L.; Marty, B.; Nivin, V. A.; Vetrin, V. R.; Balaganskaya, E. G.; Ikorsky, S. V.; Gannibal, M. A.; Weiss, D.; Verhulst, A.; Demaiffe, D.

    2002-03-01

    During the Devonian magmatism (370 Ma ago) ˜20 ultrabasic-alkaline-carbonatite complexes (UACC) were formed in the Kola Peninsula (north-east of the Baltic Shield). In order to understand mantle and crust sources and processes having set these complexes, rare gases were studied in ˜300 rocks and mineral separates from 9 UACC, and concentrations of parent Li, K, U, and Th were measured in ˜70 samples. 4He/ 3He ratios in He released by fusion vary from pure radiogenic values ˜10 8 down to 6 × 10 4. The cosmogenic and extraterrestrial sources as well as the radiogenic production are unable to account for the extremely high abundances of 3He, up to 4 × 10 -9 cc/g, indicating a mantle-derived fluid in the Kola rocks. In some samples helium extracted by crushing shows quite low 4He/ 3He = 3 × 10 4, well below the mean ratio in mid ocean ridge basalts (MORB), (8.9 ± 1.0) × 10 4, indicating the contribution of 3He-rich plume component. Magnetites are principal carriers of this component. Trapped 3He is extracted from these minerals at high temperatures 1100°C to 1600°C which may correspond to decrepitation or annealing primary fluid inclusions, whereas radiogenic 4He is manly released at a temperature range of 500°C to 1200°C, probably corresponding to activation of 4He sites degraded by U, Th decay. Similar 4He/ 3He ratios were observed in Oligocene flood basalts from the Ethiopian plume. According to a paleo-plate-tectonic reconstruction, 450 Ma ago the Baltica (including the Kola Peninsula) continent drifted not far from the present-day site of that plume. It appears that both magmatic provinces could relate to one and the same deep-seated mantle source. The neon isotopic compositions confirm the occurrence of a plume component since, within a conventional 20Ne/ 22Ne versus 21Ne/ 22Ne diagram, the regression line for Kola samples is indistinguishable from those typical of plumes, such as Loihi (Hawaii). 20Ne/ 22Ne ratios (up to 12.1) correlate well with 40

  15. Minerals of zirconolite group from fenitized xenoliths in nepheline syenites of Khibiny and Lovozero plutons, Kola Peninsula

    NASA Astrophysics Data System (ADS)

    Menshikov, Yu. P.; Mikhailova, Yu. A.; Pakhomovsky, Ya. A.; Yakovenchuk, V. N.; Ivanyuk, G. Yu.

    2015-12-01

    Zirconolite, its Ce-, Nd-, and Y-analogs, and laachite, another member of the zirconolite group, are typomorphic minerals of the fenitized xenoliths in nepheline syenite and foidolite of the Khibiny-Lovozero Complex, Kola Peninsula, Russia. All these minerals are formed at the late stage of fenitization as products of ilmentie alteration under the effect of Zr-bearing fluids. The diversity of these minerals is caused by the chemical substitutions of Na and Ca for REE, Th, and U compensated by substitution of Ti and Zr for Nb, Fe and Ta, as well as by the redistribution of REE between varieties enriched in Ti (HREE) or Nb (LREE). The results obtained can be used in the synthesis of Synroc-type titanate ceramics assigned for the immobilization of actinides.

  16. Trace-element study and uranium-lead dating of perovskite from the Afrikanda plutonic complex, Kola Peninsula (Russia) using LA-ICP-MS

    NASA Astrophysics Data System (ADS)

    Reguir, Ekaterina P.; Camacho, Alfredo; Yang, Panseok; Chakhmouradian, Anton R.; Kamenetsky, Vadim S.; Halden, Norman M.

    2010-11-01

    The U-Pb geochronology of perovskite is a powerful tool in constraining the emplacement age of silica-undersaturated rocks. The trace-element and U-Pb isotopic compositions of perovskite from clinopyroxenite and silicocarbonatite from the Afrikanda plutonic complex (Kola, Russia) were determined by laser-ablation inductively-coupled mass-spectrometry (LA-ICP-MS). In addition, the Sr isotopic composition of perovskite was measured by isotope-dilution mass-spectrometry to better constrain the relations between its host rocks. Perovskite from the two rock types shows a different degree of enrichment in Na, Mg, Mn, Pb, Fe, Al, V, rare-earth elements, Zr, Hf, Th, U and Ta. The perovskite 87Sr/86Sr values are within analytical uncertainty of one another and fall within the range of mantle values. The 206Pb/238U ages (corrected for common lead using 207Pb-method) of perovskite from silicocarbonatite statistically yield a single population with a weighted mean of 371 ± 8 Ma (2σ; MSWD = 0.071). This age is indistinguishable, within uncertainty, to the clinopyroxenite weighted mean 206Pb/238U age of 374 ± 10 Ma (2σ; MSWD = 0.18). Our data are in good agreement with the previous geochronological study of the Afrikanda complex. The observed variations in trace-element composition of perovskite from silicocarbonatite and clinopyroxenite indicate that these rocks are not related by crystal fractionation. The Sr isotopic ratios and the fact that the two rocks are coeval suggest that they were either produced from a single parental melt by liquid immiscibility, or from two separate magmas derived at different degrees of partial melting from an isotopically equilibrated, but modally complex mantle source.

  17. 1.1 Ga K-rich alkaline plutonism in the SW Grenville Province

    NASA Astrophysics Data System (ADS)

    Corriveau, Louise; Heaman, Larry M.; Marcantonio, Franco; van Breemen, Otto

    1990-09-01

    U-Pb zircon and baddeleyite dating of six syenitic stocks establishes that the ultrapotassic, potassic alkaline and shoshonitic magmatism with island-arc affinities in the Central Metasedimentary Belt (CMB) of the southwestern Grenville Province, Canada took place between 1089 and 1076 Ma, along a 400-km-long, northeast-trending plutonic belt. These ages indicate that ultrapotassic rocks with arc affinities are not unique to the Phanerozoic. West to east emplacement ages along a northern and southern cross-section of this belt range from 1083±2 Ma (Kensington), through 1081±2 Ma (Lac Rouge) to 1076{-1/+3}Ma (Loranger) in the north, and from 1089{-3/+4}Ma (loon Lake) and 1088±2 Ma (Calabogie), to 1076±2 Ma (Westport) in the south. Although closely spaced in time, in detail these ages suggest a slight younging of this magmatic activity to the southeast. Integration of the geochronological data with the spatial extent and potassic character of the plutons shows that the K-rich alkaline suite is distinct from the nepheline-syenite belt of the Bancroft terrane and from the syenite-monzonite suite of the Frontenac terrane of the CMB, and it is considered to be a magmatic episode unique to the Elzevir terrane and its Gatineau segment. The timing and the postmetamorphic emplacement of these plutons indicate that the regional greenschist to granulite-facies metamorphism of the country rock (precise age unknown) is older than 1089 Ma throughout the entire Elzevir terrane. The potassic magmatism is interpreted as the initiation of the 1090 1050 Ma Ottawan Orogeny in the Elzevir terrane; thus, the regional metamorphism in this terrane, previously assigned to the Ottawan Orogeny, is an earlier event. The contemporaneous emplacement of this postmetamorphic plutonic belt with Keweenawan volcanism is at variance with current tectonic models which consider the Keweenawan rift to be formed at the same time as regional metamorphism in the CMB.

  18. Magmatic evolution of the differentiated ultramafic, alkaline and carbonatite intrusion of Vuoriyarvi (Kola Peninsula, Russia). A LA-ICP-MS study of apatite

    NASA Astrophysics Data System (ADS)

    Brassinnes, S.; Balaganskaya, E.; Demaiffe, D.

    2005-11-01

    The nature of the petrogenetic links between carbonatites and associated silicate rocks is still under discussion (i.e., [ Gittins J., Harmer R.E., 2003. Myth and reality of the carbonatite-silicate rock "association". Period di Mineral. 72, 19-26.]). In the Paleozoic Kola alkaline province (NW Russia), the carbonatites are spatially and temporally associated to ultramafic cumulates (clinopyroxenite, wehrlite and dunite) and alkaline silicate rocks of the ijolite-melteigite series [ Kogarko, L.N., 1987. Alkaline rocks of the eastern part of the Baltic Shield (Kola Peninsula). In: Fitton, J.G., and Upton, B.G.J. (eds). Alkaline igneous rocks. Geol. Soc. Special Publication 30, 531-544; Kogarko, L.N., Kononova, V.A., Orlova, M.P., Woolley, A.R., 1995. Alkaline rocks and carbonatites of the world. Part 2. Former USSR. Chapman and Hall, London, 225 pp; Verhulst, A., Balaganskya, E., Kirnarsky, Y., Demaiffe, D., 2000. Petrological and geochemical (trace elements and Sr-Nd isotopes) characteristics of the Paleozoic Kovdor ultramafic, alkaline and carbonatite intrusion (Kola Peninsula, NW Russia). Lithos 51, 1-25; Dunworth, E.A., Bell, K., 2001. The Turiy Massif, Kola Peninsula, Russia; isotopic and geochemical evidence for a multi-source evolution. J. Petrol. 42, 377-405; Woolley, A.R., 2003. Igneous silicate rocks associated with carbonatites: their diversity, relative abundances and implications for carbonatite genesis. Period. di Mineral. 72, 9-17)]. In the small (≈ 20 km 2) Vuoriyarvi massif, apatite is typically a liquidus phase during the magmatic evolution and so it can be used to test genetic relationships. Trace elements contents have been obtained for both whole rocks and apatite (by LA-ICP-MS). The apatites define a single continuous chemical evolution marked by an increase in REE and Na (belovite-type of substitution, i.e., 2Ca 2+ = Na + + REE 3+). This evolution possibly reflects a fractional crystallisation process of a single batch of isotopically

  19. Unusual rocks and mineralisation in a new carbonatite complex at Kandaguba, Kola Peninsula, Russia

    NASA Astrophysics Data System (ADS)

    Pilipiuk, A. N.; Ivanikov, V. V.; Bulakh, A. G.

    2001-04-01

    The paper presents the results from a reconnaissance investigation of carbonatites in a newly discovered alkaline complex in the Kola peninsula, Russia. The Kandaguba complex differs from other carbonatite plutons of the Kola alkaline province by (a) the absence of ultrabasic rocks, (b) widespread occurrence of nepheline-, cancrinite- and nepheline-cancrinite syenites and carbonatites and (c) presence of apatite-calcite ijolites and feldspar ijolites as separate intrusive phase. The Kandaguba carbonatites are notable for the predominance of late ferromagnesian varieties together with quartz and numerous accessory mineral species. The association of phosphates (monazite, gorseixite, goyazite, apatite), sulphides and tellurides (pyrite, sphalerite, galena, hessite), ilmenorutile, barite with quartz and ankerite is a remarkable feature of these carbonatites. The Kandaguba carbonatites are inferred to have been generated as the products of liquid immiscibility followed by differentiation of the carbonatite melt.

  20. Britholite-group minerals as sensitive indicators of changing fluid composition during pegmatite formation: evidence from the Keivy alkaline province, Kola peninsula, NW Russia

    NASA Astrophysics Data System (ADS)

    Zozulya, Dmitry R.; Lyalina, Lyudmila M.; Savchenko, Yevgeny E.

    2017-01-01

    The Keivy alkaline province, Kola Peninsula, NW Russia, consists of vast alkali granite massifs and several dike-like nepheline syenite bodies. It contains numerous rare-metal occurrences, formed by a complex sequence of magmatic, late-magmatic and post-magmatic (including pegmatitic) processes. The Sakharjok nepheline syenite pegmatite contains a remarkably diverse number of britholite group minerals, pointing to different physico-chemical conditions in the fluid. REE and actinides distribution in the host rock indicates that the late-magmatic (and pegmatitic) fluids were alkaline, with significant amounts of F and CO2. From REE and F variations of the britholite group minerals possible fluid compositions at different stages are suggested. The earliest fluorbritholite-(Ce) formed locally from a late magmatic, high temperature F-rich fluid. Fluorbritholite-(Y) presumably crystallized from a F-bearing and CO2-rich fluid; marked F saturation resulted in precipitation of abundant fluorite due to a temperature drop. Variations in REE and F contents in the most abundant fluorcalciobritholite indicate a successive decrease of F in the fluid during its evolution. The relationship between intergrown fluorapatite and fluorcalciobritholite and the presence of zones with a REE-rich fluorapatite between them indicate a continuous to sudden crystallization in this mineral sequence. The crystallization of the latest "calciobritholite" is related to the input into the fluid of CO2 and/or H2O.

  1. Evolution and geochemistry of the Tertiary calc-alkaline plutons in the Adak Island region of the central Aleutian oceanic island arc

    NASA Astrophysics Data System (ADS)

    Kay, Suzanne; Citron, Gary P.; Kay, Robert W.; Jicha, Brian; Tibbetts, Ashley

    2014-05-01

    Calc-alkaline plutons are major crustal building blocks of continental margin mountain belts like the Mesozoic to Tertiary Andes and the Sierra Nevada, but are rare in oceanic island arcs. Some of the most calc-alkaline I-type island arc plutons are in the Central Aleutians with the most extreme signatures, as indicated by FeO/MgO ratios of < ~2 at 48-70% wt. % SiO2, in the ~10 km wide Oligocene Hidden Bay pluton on southern Adak Island and the 10 km wide Miocene Kagalaska pluton to the north on eastern Adak and the adjacent Kagalaska Island. Although small compared to most continental plutons, similarities in intrusive units, mineralogy and chemistry suggest common formation processes. The Aleutian calc-alkaline plutonic rocks mainly differ from continental plutons in having more oceanic like isotopic (87Sr/86Sr = 0.703-0.7033; Epsilon Nd = 9-7.8) and LIL (e.g., higher K/Rb) ratios. The Adak region plutons differ from Tertiary plutons on Unalaska Island further east in being more K-rich and in having a more oxidized and lower-temperature mineralogy. From a regional perspective, the Adak area plutons intrude Eocene/Oligocene Finger Bay Formation mafic volcanic and sedimentary rocks and postdate the small ~38 Ma tholeiitic Finger Bay pluton. The chemistry of these older magmatic rocks is basically similar to that of young Central Aleutian magmatic rocks with boninites and arc tholeiitic magmas seemingly being absent. The formation of the calc-alkaline plutons seems to require a sufficient crustal thickness, fluid concentration and contractional stress such that magma chambers can stabilize significant amounts of pargasitic hornblende. Seismic receiver function analyses (Janiszewski et al., 2013) indicate the modern Adak crust is ~ 37 km thick. Existing and new hornblende, plagioclase and biotite Ar/Ar ages from 16 Hidden Bay pluton and Gannet Lake stock gabbro, porphyritic diorite, diorite, granodiorite, leucogranodiorite and aplite samples range from 34.6 to 30

  2. Phosphoinnelite, Ba4Na3Ti3Si4O14(PO4,SO4)2(O,F)3, a new mineral species from peralkaline pegmatite of the Kovdor pluton, Kola Peninsula

    NASA Astrophysics Data System (ADS)

    Pekov, I. V.; Chukanov, N. V.; Kulikova, I. M.; Belakovsky, D. I.

    2007-12-01

    Phosphoinnelite, an analogue of innelite with P > S, has been found in a peralkaline pegmatite vein crosscutting calcite carbonatite at the phlogopite deposit, Kovdor pluton, Kola Peninsula. Cancrinite (partly replaced with thomsonite-Ca), orthoclase, aegirine-augite, pectolite, magnesioarfvedsonite, golyshevite, and fluorapatite are associated minerals. Phosphoinnelite occurs as lath-shaped crystals up to 0.2 × 1 × 6 mm in size, which are combined typically in bunch-, sheaf-, and rosettelike segregations. The color is yellow-brown, with vitreous luster on crystal faces and greasy luster on broken surfaces. The mineral is transparent. The streak is pale yellowish. Phosphoinnelite is brittle, with perfect cleavage parallel to the {010} and good cleavage parallel to the {100}; the fracture is stepped. The Mohs hardness is 4.5 to 5. Density is 3.82 g/cm3 (meas.) and 3.92 g/cm3 (calc.). Phosphoinnelite is biaxial (+), α = 1.730, β = 1.745, and γ = 1.764, 2V (meas.) is close to 90°. Optical orientation is Z^c ˜ 5°. Chemical composition determined by electron microprobe is as follows (wt %): 6.06 Na2O, 0.04 K2O, 0.15 CaO, 0.99 SrO, 41.60 BaO, 0.64 MgO, 1.07 MnO, 1.55 Fe2O3, 0.27 Al2O3, 17.83 SiO2, 16.88 TiO2, 0.74 Nb2O5, 5.93 P2O5, 5.29 SO3, 0.14 F, -O=F2 = -0.06, total is 99.12. The empirical formula calculated on the basis of (Si,Al)4O14 is (Ba3.59Sr0.13K0.01)Σ3.73(Na2.59Mg0.21Ca0.04)Σ3.04(Ti2.80Fe{0.26/3+}Nb0.07)Σ3.13[(Si3.93Al0.07)Σ4O14(P1.11S0.87)Σ1.98O7.96](O2.975F0.10)Σ3.075. The simplified formula is Ba4Na3Ti3Si4O14(PO4,SO4)2(O,F)3. The mineral is triclinic, space group P overline 1 or P1. The unit cell dimensions are a = 5.38, b = 7.10, c = 14.76 Å; α = 99.00°, β = 94.94°, γ = 90.14°; and V = 555 Å3, Z = 1. The strongest lines of the X-ray powder pattern [ d, Å in ( I)( hkl)] are: 14.5(100)(001), 3.455(40)(103), 3.382(35)(0overline 2 2), 2.921(35)(005), 2.810(40)(1overline 1 4), 2.683(90)(200, overline 2 01), 2.133(80)(overline 2 overline

  3. A New Occurrence of Alkaline Magmatism on the Kola Peninsula: An Agpaitic Dyke in the Kandalaksha Region.

    NASA Astrophysics Data System (ADS)

    Akimenko, Mariya; Kogarko, Lia; Sorokhtina, Natalia; Kononkova, Natalia; Mamontov, Vladimir

    2015-04-01

    A new occurrence of alkaline dyke magmatism was discovered in 2010 during the geological works performed by the Murmansk Geological Prospecting Expedition in the "Mokhnatye Roga" area located 55 km to the southeast of the Kovdor massif (67°15' N, 31°30' E). The "Mokhnatye Roga" area is located in the Ensk segment of the northwestern part of the Belomorian mobile belt. We performed a complete petrological and geochemical description of the sections in Holes 19 and 24, which reveal one of the largest dykes in the area. The dyke, with a length of ≈4 km and a width of ≈160 m, has an eastern orientation with steep dipping (60°-90°) to the north. The thickness of Quaternary deposits ranges from 0.8 to 4.0 m; alkaline rocks occur in the range of 4.0-93.9 m being followed by host amphibole-biotite gneiss with interbeds of plagioamphibolite (AR2 mt) along the section. Among the major minerals of the dyke are the minerals of the lamprophyllite group (20-25 vol %), aegirine-augite (10-15 vol %), enigmatite (10-15 vol %), nepheline (10-15 vol %), orthoclase (15-20 vol %), alkaline amphibole (5-10 vol %), and astrophyllite (up to 5 vol %). The minor minerals are represented by shcherbakovite, sodalite, natrolite, barite, Mn carbonate, ilmenite, rutile, sphalerite, and goethite. The texture of the rock is porphyric: the groundmass is composed of finegranular nepheline and orthoclase, which are observed as individual large euhedral crystals as well. In addition, large phenocrysts are represented by the minerals of the lamprophyllite, enigmatite, pyroxene, and alkaline amphibole groups. Based on the generally accepted classifications [1], the studied agpaitic rock may be related to nepheline syenite; according to the mineral and chemical compositions, it is close to syenite of the Niva massif [2] located 35 km to the northeast from the "Mokhnatye Roga" area. Agpaitic syenite of the "Mokhnatye Roga" area is extremely enriched in dispersed and rare lithophile elements. The

  4. Vigrishinite, Zn2Ti4 - x Si4O14(OH,H2O,□)8, a new mineral from the Lovozero alkaline complex, Kola Peninsula, Russia

    NASA Astrophysics Data System (ADS)

    Pekov, I. V.; Britvin, S. N.; Zubkova, N. V.; Chukanov, N. V.; Bryzgalov, I. A.; Lykova, I. S.; Belakovskiy, D. I.; Pushcharovsky, D. Yu.

    2013-12-01

    A new mineral vigrishinite, epistolite-group member and first layer titanosilicate with species-defining Zn, was found at Mt. Malyi Punkaruaiv, in the Lovozero alkaline complex, Kola Peninsula, Russia. It occurs in a hydrothermally altered peralkaline pegmatite and is associated with microcline, ussingite, aegirine, analcime, gmelinite-Na, and chabazite-Ca. Vigrishinite forms rectangular or irregularly shaped lamellae up to 0.05 × 2 × 3 cm flattened on [001]. They are typically slightly split and show blocky character. The mineral is translucent to transparent and pale pink, yellowish-pinkish or colorless. The luster is vitreous. The Mohs' hardness is 2.5-3. Vigrishinite is brittle. Cleavage is {001} perfect. D meas = 3.03(2), D calc = 2.97 g/cm3. The mineral is optically biaxial (-), α = 1.755(5), β = 1.82(1), γ = 1.835(8), 2 V meas = 45(10)°, 2 V calc = 50°. IR spectrum is given. The chemical composition (wt %; average of 9 point analyses, H2O is determined by modified Penfield method) is as follows: 0.98 Na2O, 0.30 K2O, 0.56 CaO, 0.05 SrO, 0.44 BaO, 0.36 MgO, 2.09 MnO, 14.39 ZnO, 2.00 Fe2O3, 0.36 Al2O3, 32.29 SiO2, 29.14 TiO2, 2.08 ZrO2, 7.34 Nb2O5, 0.46 F, 9.1 H2O, -0.19 O=F2, total is 101.75. The empirical formula calculated on the basis of Si + Al = 4 is: H7.42(Zn1.30Na0.23Mn0.22Ca0.07Mg0.07K0.05Ba0.02)Σ1.96(Ti2.68Nb0.41Fe{0.18/3+}Zr0.12)Σ3.39(Si3.95Al0.05)Σ4 20.31F0.18. The simplified formula is: Zn2Ti4- x Si4O14(OH,H2O,□)8 ( x < 1). Vigrishinite is triclinic, space group P , a = 8.743(9), b = 8.698(9), c = 11.581(11)Å, α = 91.54(8)°, β = 98.29(8)°, γ = 105.65(8)°, V = 837.2(1.5) Å3, Z = 2. The strongest reflections in the X-ray powder pattern ( d, Å, - I[ hkl]) are: 11.7-67[001], 8.27-50[100], 6.94-43[01, 10], 5.73-54[11, 002], 4.17-65[020, 2, 200], and 2.861-100[30, 22, 004, 11]. The crystal structure model was obtained on a single crystal, R = 0.171. Vigrishinite and murmanite are close in the structure of the TiSiO motif, but

  5. Aqualite, a new mineral species of the eudialyte group from the Inagli alkaline pluton, Sakha-Yakutia, Russia, and the problem of oxonium in hydrated eudialytes

    NASA Astrophysics Data System (ADS)

    Khomyakov, A. P.; Nechelyustov, G. N.; Rastsvetaeva, R. K.

    2007-12-01

    Aqualite, a new eudialyte-group mineral from hydrothermally altered peralkaline pegmatites of the Inagli alkaline pluton (Sakha-Yakutia, Russia) is described in this paper. Natrolite, microcline, eckermanite, aegirine, batisite, innelite, lorezenite, thorite, and galena are associated minerals. Aqualite occurs as isometric crystals up to 3-cm across. The color is pale pink, with a white streak and vitreous luster. The mineral is transparent. The fracture is conchoidal. The mineral is brittle; no cleavage or parting is observed. The Mohs’ hardness is 4 to 5. The density is 2.58(2) g/cm3 (measured by the volumetric method) and 2.66 g/cm3 (calculated). Aqualite is optically uniaxial (+), α = 1.569(1) and β = 1.571(1). The mineral is pleochroic from colorless to pale pink on X and pink on Y, α < β. Aqualite is weakly fluorescent with a dull yellow color under ultraviolet light. The mineral is stable in 50% HCl and HNO3 at room temperature. Weight loss after ignition at 500°C is 9.8%. Aqualite is monoclinic, and the space group is R3. The unit-cell dimensions are a = 14.078(3) Å, c = 31.24(1) Å, V = 5362 Å3, and Z = 3. The strongest reflections in the X-ray powder pattern [ d, Å ( I)( hkl)] are: 4.39(100)(2005), 2.987(100)(315), 2.850(79)(404), 10.50(44)(003), 6.63(43)(104), 7.06(42)(110), 3.624(41)(027), and 11.43(39)(101). The chemical composition (electron microprobe, H2O determined with the Penfield method) is as follows (wt %): 2.91 Na2O, 1.93 K2O, 11.14 CaO, 1.75 SrO, 2.41 BaO, 0.56 FeO, 0.30 MnO, 0.17 La2O3, 0.54 Ce2O3, 0.36 Nd2O3, 0.34 Al2O3, 52.70 SiO2, 12.33 ZrO2, O.78 TiO2, 0.15 Nb2O5; 1.50 Cl, 9.93 H2O,-O=Cl2 0.34; where the total is 99.46. The empirical formula calculated on the basis of Si + Zr + Ti + Al + Nb = 29 apfu is as follows: [(H3O)7.94Na2.74K1.20Sr0.49Ba0.46Fe0.23Mn0.12]Σ13.18(Ca5.79REE0.19)Σ5.98 (Zr2.92Ti0.08)Σ3.0(Si25.57Ti0.21Al0.19Nb0.03)S26.0[O66.46(OH)5.54]Σ72.0 [(OH)2.77Cl1.23]Σ4.0. The simplified formula is (H3O)8(Na,K,Sr)5

  6. High-K calc-alkaline magmatism at the Archaean-Proterozoic boundary: implications for mantle metasomatism and continental crust petrogenesis. Example of the Bulai pluton (Central Limpopo Belt, South Africa)

    NASA Astrophysics Data System (ADS)

    Laurent, Oscar; Martin, Hervé; Doucelance, Régis; Moyen, Jean-François; Paquette, Jean-Louis

    2010-05-01

    The Neoarchaean Bulai pluton, intrusive within the supracrustal granulites of the Central Limpopo Belt (Limpopo Province, South Africa) is made up of large volumes of porphyritic granodiorites with subordinate enclaves and dykes which have monzodioritic and charno-enderbitic compositions. New U-Pb LA-ICP-MS dating on separated zircons yielded pluton emplacement ages ranging between 2.60 and 2.63 Ga, which are slightly older than previous proposed ages (~ 2.57-2.61 Ga). The whole-rock major- and trace-element composition of the Bulai pluton evidences unequivocal affinities with "high-Ti" late-Archaean sanukitoids. It belongs to a high-K calc-alkaline differentiation suite, with metaluminous affinities (0.7 < A/CNK < 1) and relatively high Mg# (0.4-0.6). These rocks have "juvenile" affinities, such as eNd ranging between -0.5 and 0.5, and in addition, are very rich in all incompatible trace elements, which is particularly obvious in monzodioritic enclaves and enderbites where primitive mantle-normalized LILE and LREE contents are up to 300. These characteristics point to an enriched mantle source for the Bulai batholith. Chondrite normalized, REE patterns are strongly fractionated ([La/Yb]N ~ 25-80), mainly due to high LREE contents (LaN ~ 250-630), and chiefly high HFSE contents (Nb ~ 15-45 ppm ; up to 770 ppm Zr) indicate that the metasomatic agent is a silicic melt rather than a hydrous fluid. Moreover, based on high Nb/Ta, Th/Rb, La/Rb and low Sr/Nd and Ba/La, we suggest that the metasomatic agent is a granitic melt generated by melting of terrigenous sediments. Interactions of this melt with mantle peridotites implies that sediments are located under a mantle slice; geometry which is easily achieved in subduction zone settings. This conclusion is supported by the fact that Bulai trace element patterns are very similar to those of sub-actual potassic magmas generated in magmatic arc environments by interactions between mantle and terrigenous sediments (e.g. Sunda

  7. Early Paleozoic alkalic and calc-alkalic plutonism and associated contact metamorphism, central Virginia Piedmont

    USGS Publications Warehouse

    Pavlides, Louis; Arth, Joseph G.; Sutter, J.F.; Stern, T.W.; Cortesini, Henry

    1994-01-01

    Early Paleozoic plutonism in the central Virginia Piedmont consists of the igneous Lahore Complex and Ellisville Pluton. The Lahore Complex consists of a small altered mafic pluton intruded by the shoshonitic, alkalic monzonites of the Lahore Pluton (-450 Ma) that, in turn, is intruded by the calc-alkaline, granodioritic Ellisville Pluton (-440 Ma). These plutons were emplaced at about 760aC at a depth of 12 to 18 km within greenschist-facies rocks and are enclosed by contact-metamorphosed rocks.

  8. PRECIPITATION OF PLUTONOUS PEROXIDE

    DOEpatents

    Barrick, J.G.; Manion, J.P.

    1961-08-15

    A precipitation process for recovering plutonium values contained in an aqueous solution is described. In the process for precipitating plutonium as plutonous peroxide, hydroxylamine or hydrazine is added to the plutoniumcontaining solution prior to the addition of peroxide to precipitate plutonium. The addition of hydroxylamine or hydrazine increases the amount of plutonium precipitated as plutonous peroxide. (AEC)

  9. Magma-mixing in the genesis of Hercynian calc-alkaline granitoids: an integrated petrographic and geochemical study of the Sázava intrusion, Central Bohemian Pluton, Czech Republic

    NASA Astrophysics Data System (ADS)

    Janoušek, Vojtěch; Braithwaite, Colin J. R.; Bowes, D. R.; Gerdes, Axel

    2004-10-01

    The Devonian-early Carboniferous (354.1±3.5 Ma: conventional zircon U-Pb age) Sázava intrusion (biotite-amphibole quartz diorite, tonalite and granodiorite) of the Central Bohemian Pluton (CBP) associated with bodies of (olivine, pyroxene-) amphibole gabbro, gabbrodiorite, (quartz) diorite and rare hornblendite, gives an opportunity for a comparative study of a rather shallow, calc-alkaline magma-mixing zone at two levels, separated by a vertical difference of approximately 1 km. The deeper section (Příbram) displays the direct evidence for the existence of a long-lived, periodically tapped and replenished, floored magma chamber (MASLI). The contacts between the subhorizontal sheet-like basic bodies and the surrounding, commonly cumulus-rich, Sázava granitoid, are arcuate, and cut by a series of veins and ascending pipes. Shallow-dipping swarms of strongly elongated and flow-aligned mafic microgranular enclaves (MME), concordant with the contacts of the basic bodies, are commonplace. The higher level (Teletín) section shows relatively independent basic intrusions, some of them distinctly hybrid in character and mainly of quartz dioritic composition, surrounded by relatively homogeneous, nearly cumulus-free Sázava tonalite rich in texturally variable MME. Larger quartz microdiorite bodies and the MME, both interpreted as hybrids, contain varying proportions of highly heterogeneous plagioclase megacrysts with complex zoning, particularly well shown by cathodoluminescence (CL). Most often the megacrysts have cores of labradorite-anorthite, partly resorbed and overgrown by andesine rims but some are strongly brecciated and fragments have been annealed by rim growth. Also characteristic are long prisms of apatite, oikocrysts of quartz and K-feldspar and zoned amphibole. The latter has brown pargasite and magnesiohastingsite cores, resorbed and overgrown by magnesiohornblende, compositionally similar to the amphibole in the Sázava tonalite. The brown cores are

  10. Petrology of the Plutonic Rocks of west-central Alaska

    USGS Publications Warehouse

    Miller, Thomas P.

    1970-01-01

    A series of plutons in west-central Alaska defines the Hogatza plutonic belt which extends for about 200 miles in an east-west direction from the northeastern Seward Peninsula to the Koyukuk River. The plutonic rocks have an aggregate area of about 1,200 square miles and their composition, distribution, and possible petrogenesis are discussed for the first time in this report. Field, petrographic and chemical data supported by K/Ar age dating indicate the plutonic rocks are divisible into two suites differing in age, location, and composition. The western plutons are mid-Cretaceous (~100 m.y.) in age and consist of a heterogeneous assemblage of monzonite, syenite, quartz monzonite. Associated with these granitic rocks is a group of alkaline sub-silicic rocks that forma belt of intrusive complexes extending for a distance of at least 180 miles from west-central Alaska to the Bering Sea. The complex at Granite Mountain shows a rare example of zoning from an alkaline rim to a quartz-bearing core. The occurrence of a similar complex at Cape Dezhnev on the easternmost tip of Siberia suggests the alkaline province may extend into Siberia. The easternmost plutons are Late Cretaceous (180 m.y.) in age and composed primarily of granodiorite and quartz monzonite similar to calc-alkaline plutons found throughout the North America Cordillera. The plutons are epizonal and intrude deformed but unmetamorphosed Lower Cretaceous andesitic volcanics and volcanic graywacke which constitute the highly mobile Yukon-Koyukuk volcanogenic province of west-central Alaska. No older rocks have been found within the confines of this vast tract; the occurrence of a bounding ophiolite sequence has lead to the suggestion that the province was formed by large-scale rifting and is underlain by oceanic crust. The possibility of no juvenile sialic crust over much of the area suggests that the potassium-rich magma now represented by the alkaline rocks originated in the mantle. The distribution of the

  11. Late Jurassic plutonism in the southwest U.S. Cordillera

    USGS Publications Warehouse

    Barth, A.P.; Wooden, J.L.; Howard, K.A.; Richards, J.L.

    2008-01-01

    Although plate reconstructions suggest that subduction was an approximately steady-state process from the mid-Mesozoic through the early Tertiary, recent precise geochronologic studies suggest highly episodic emplacement of voluminous continental-margin batholiths in the U.S. Cordillera. In central and southern California and western Arizona, major episodes of batholithic magmatism are known to have occurred in Permian-Triassic, Middle Jurassic, and late Early to Late Cretaceous time. However, recent studies of forearc-basin and continental-interior sediments suggest that Late Jurassic time was probably also a period of significant magmatism, although few dated plutons of this age have been recognized. We describe a belt of Late Jurassic plutonic and hypabyssal rocks at least 200 km in length that extends from the northwestern Mojave Desert through the Transverse Ranges. The belt lies outboard of both the voluminous Middle Jurassic arc and the ca. 148 Ma Independence dike swarm at these latitudes. The plutons include two intrusive suites emplaced between 157 and 149 Ma: a calc-alkaline suite compositionally unlike Permian-Triassic and Middle Jurassic mon-zonitic suites but similar to Late Cretaceous arc plutons emplaced across this region, and a contemporaneous but not comagmatic alkaline suite. The Late Jurassic was thus a time of both tectonic and magmatic transitions in the southern Cordillera. ?? 2008 The Geological Society of America.

  12. Late Silurian plutons in Yucatan

    NASA Astrophysics Data System (ADS)

    Steiner, M. B.; Walker, J. Douglas

    1996-08-01

    U-Pb measurements of zircons from two composite plutons in the Maya Mountains of the Yucatan Block (Belize) give Late Silurian ages. Zircons from one of the five compositional phases of the Mountain Pine Ridge pluton yield an age of 418±3.6 Ma. A second compositional phase gives a minimum age of 404 Ma, and zircons from a third phase, although plagued with high common Pb, yield ages consistent with the other two. Zircons from one compositional phase of the Hummingbird-Mullins River pluton indicate an age of about 410-420 Ma. These data demonstrate that two of the three Maya Mountains plutons residing among the strata of the Late Pennsylvanian through Permian Santa Rosa Group are older than that sedimentation. Although the third pluton was not dated, both the similarity of sedimentary facies patterns adjacent to it to those adjacent to one of the plutons dated as Late Silurian and a published single Rb-Sr age of 428 ± 41 Ma suggest this third pluton also was emergent during Santa Rosa deposition. Thus the new U/Pb dates and other data suggest that all three Maya Mountains plutons pre-date Late Carboniferous sedimentation and that none intrude the Santa Rosa Group. Although very uniform ages of about 230 Ma amongst all plutons, derived from abundant earlier dating by the K-Ar system, led to the conclusion that intrusion mostly had occurred in the Late Triassic, the U-Pb ages (obtained from the same sites as the K-Ar dates) demonstrate that the K-Ar ages do not derive from a Late Triassic intrusive episode. The K-Ar dates probably are a signature of the rifting associated with Pangean breakup and formation of the Gulf of Mexico. In a reconstructed Pangea, the position of the Maya Mountains Late Silurian plutons suggests that the Late Silurian Acadian-Caledonian orogen of eastern North America extended through the region of the future Gulf of Mexico. Finally, the U-Pb ages of the Maya Mountains plutons are the same as those of a group of shocked zircons found in the

  13. Late-stage sinking of plutons

    USGS Publications Warehouse

    Glazner, A.F.; Miller, D.M.

    1997-01-01

    Many granodiorite to diorite plutons in the Great Basin of western North America are surrounded by rim monoclines or anticlines that suggest relative downward movement of the plutons while wall rocks were hot and ductile. We propose that such plutons rise to a level of approximately neutral buoyancy and then founder as their densities increase ??? 40% during crystallization. Late-stage sinking of intermediate to mafic plutons should be common when wall rocks are rich in weak, low-density minerals such as quartz and calcite. Structures related to sinking will overprint those related to initial pluton emplacement and may be mistaken for regional tectonic structures.

  14. Igneous layering in the peralkaline intrusions ,Kola Peninsula :leading role of gravitational differentiation

    NASA Astrophysics Data System (ADS)

    Kogarko, L. N..

    2012-04-01

    In the center of Kola Peninsula there are two large layered intrusions of agpaitic nepheline syenites - Khibina and Lovozero. . The Khibina alkaline massif (Kola Peninsula,Russia) hosts the world's largest and economically most important apatite deposit. The Khibina massif is a complex multiphase body built up from a number of ring-like and conical intrusions. The apatite bearing intrusion is ring-like and is represented by a layered body of ijolitic composition with a thickness of about 1 - 2 km. The upper zone is represented by different types of apatite ores. These rocks consist of 60-90% euhedral very small (tenths of mm)apatite crystals. The lower zone has mostly ijolitic composition. The lower zone grades into underlying massive urtite consisting of 75-90% large (several mm) euhedral nepheline. Our experimental studies of systems with apatite demonstrated the near-eutectic nature of the apatite-bearing intrusion, resulting in practically simultaneous crystallization of nepheline, apatite and pyroxene. The mathematical model of the formation of the layered apatite-bearing intrusion based on the processes of sedimentation under the conditions of steady state convection taking account of crystal sizes is proposed. Under the conditions of steady-state convection large crystals of nepheline continuously had been settling forming massive underlying urtite whereas smaller crystals of pyroxenes, nepheline and apatite had been stirred in the convecting melt. During the cooling the intensity of convection decreased causing a settling of smaller crystals of nepheline and pyroxene and later very small crystalls of apatite in the upper part of alkaline magma chamber. The Lovozero massif, the largest of the Globe layered peralkaline intrusion, comprises super-large rare-metal (Nb, Ta, REE) deposit. The main ore mineral is loparite (Na, Ce, Ca)2 (Ti, Nb)2O6 which was mined during many years. The composition of cumulus loparite changed systematically upward through the

  15. Potential use ofGarcinia kola as hop substitute in lager beer brewing.

    PubMed

    Aniche, G N; Uwakwe, G U

    1990-09-01

    The chemical, brewing and anti-microbial properties of a tropical seed,Garcinia kola, were compared with traditional hops. Treatment ofGarcinia kola with methanolic lead acetate produced a yellow precipitate from which organic acids (alpha acids) were contirmed to be present by thin-layer chromatography. Hops, however, had a higher concentration of organic acids thanGarcinia kola. Laboratory brewing trials withGarcinia kola and hops gave beers with simillar chemical properties. Organoleptically,Garcinia kola beer was as acceptable to tasters as hopped beer except that it had an improved bitterness.Garcinia kola and hop extracts exerted similar anti-microbial effects on two beer spollage micro-organisms (Lactobacillus delbruckii andCandida vini).

  16. Technology for NPP decantate treatment realized at Kola NPP

    SciTech Connect

    Stakhiv, Michael; Avezniyazov, Slava; Savkin, Alexander; Fedorov, Denis; Dmitriev, Sergei; Kornev, Vladimir

    2007-07-01

    At Moscow SIA 'Radon' jointly with JSC 'Alliance Gamma', the technology for NPP Decantate Treatment was developed, tested and realized at Kola NPP. This technology consists of dissolving the salt residue and subsequent treatment by ozonization, separation of the deposits formed from ozonization and selective cleaning by ferro-cyanide sorbents. The nonactive salt solution goes to an industrial waste disposal site or a repository specially developed at NPP sites for 'exempt waste' products by IAEA classification. This technology was realized at Kola NPP in December 2006 year. At this time more than 1000 m{sup 3} of decantates log time stored are treated. It allows solving very old problem to empty decantates' tanks at NPPs in environmentally safe manner and with high volume reduction factor. (authors)

  17. A comparative study of two rear-arc plutons and implications for the Fuegian Andes tectonic evolution: Mount Kranck Pluton and Jeu-Jepén Monzonite, Argentina

    NASA Astrophysics Data System (ADS)

    González-Guillot, M.; Prezzi, C.; Acevedo, R. D.; Escayola, M.

    2012-10-01

    A petrologic, geochemical and geophysical study of two Late Cretaceous plutons of the Fuegian Andes is carried out: the Jeu-Jepén Monzonite (JJM) and the Mt. Kranck Pluton (MKP). The plutons show a wide lithological spectrum from ultramafic lithologies (clinopyroxenites and hornblendites), gabbros, diorites to late stage K-feldspar syenite veins. They represent the top of magmatic chambers exposed at or close to the roof level. Mode and chemistry indicate a monzonitic-mildly alkaline trend with high K2O content, equivalent to shoshonitic series. Trace element composition is typical of arc magmas. These features plus their high LILE content (Ba 320-1600 ppm, Sr 475-1560 ppm), high LILE/HFSE ratio (Rb/Zr 0.6-1.6) and age confirm they belong to a rear-arc, monzonitic to mildly alkaline suite (the Fuegian Potassic Magmatism). Therefore, they represent the farthest-from-the-trench plutons in the suite. The petrographical and chemical characteristics of the plutons suggest the lithological spectrum is the result of magmatic differentiation. The process involved crystal accumulation and magma mingling at the early stages, favored either by injections of fresh magma from deeper reservoirs and/or the action of convective currents within the chamber. Country rock assimilation also took part simultaneously with crystallization. The JJM and MKP lie along the trace of a Cenozoic left-lateral strike-slip fault (Magallanes-Fagnano fault system), on opposite blocks. However, lithological, chemical and geophysical subtle differences between these two plutons suggest they evolved in individual magmatic chambers and therefore the distance between them cannot be used as an estimation of total offset along the fault, as was indicated in previous studies.

  18. Time of formation and genesis of yttrium-zirconium mineralization in the Sakharjok massif, Kola Peninsula

    NASA Astrophysics Data System (ADS)

    Vetrin, V. R.; Skublov, S. G.; Balashov, Yu. A.; Lyalina, L. M.; Rodionov, N. V.

    2014-12-01

    The Kola geotectonic province in the northeastern Fennoscandian Shield accommodates a significant number of alkaline rock massifs differing in age. They are of mantle and mantle-crustal origin (alkali and nepheline syenites, carbonatites) and related to crustal sources (Neoarchean alkali granites). Among them, the Neoarchean Sakharjok nepheline syenite massif is related to the oldest intrusions of this kind bearing yttrium-zirconium mineralization. The crystallization of alkali syenite pertaining to the first intrusive phase of the intrusive Sakharjok massif is dated to 2645 ± 7 Ma, and this implies that this syenite postdated alkali granites (2.66-2.67 Ga). To date the yttrium-zirconium ore, we applied the local U-Pb method to zircon crystals occurring in the mineralized block hosted in nepheline syenite. The earliest fragments of zircon crystallized 1832 ± 7 Ma ago; the age of metamorphism is estimated at 1784 ± 13 Ma. These dates indicate the Paleoproterozoic age of the yttrium-zirconium mineralization, which was formed as a product of fluid reworking of the Neoarchean nepheline syenite of the Sakharjok massif.

  19. Apatite Fission Track Thermochronology of Khibina Massif (Kola Peninsula, Russia): Implications for post-Devonian Tectonics of the NE Fennoscandia

    NASA Astrophysics Data System (ADS)

    Veselovskiy, R. V.; Thomson, S. N.; Arzamastsev, A.

    2015-12-01

    The thermal history of the Kola Peninsula area of NE Fennoscandia remains almost fully unknown because of absence of any thermochronological data such as apatite and/or zircon fission track or (U-Th)/He ages. In order to fill this gap and to constrain the post-Devonian erosion and exhumation history of this region, we present the results of apatite fission track (AFT) dating of eleven samples selected from the cores taken from different depths of the northern part of the Khibina intrusive massif. This alkaline magmatic complex is located at the center of Kola Peninsula and formed at about 370 Ma (Kramm and Kogarko, 1994). Samples were analyzed from depths between +520 to -950 meters and yielded AFT ages between 290-268 Ma with an average age uncertainty (1σ) of ±30 Ma. Mean track lengths (MTL) lie between 12.5-14.4 μm. We used the most reliable AFT ages and distribution of MTL in two samples, corresponding to depths of +280 and -920 m, to conduct inverse time-temperature modelling of the Khibina massif. Thermal histories that best predict the measured data show three stages: (1) 290-250 Ma - rapid cooling from >110°C to 70°C/50°C for lower/upper sample correspondingly; (2) 250-50 Ma - a stable temperature stage; (3) 50-0 Ma - slightly increased cooling rates down to modern temperatures. We propose that the first cooling stage is related to late-Hercynian orogenesis; the second cooling stage may be associated with tectonics accompanying with opening of Arctic oceanic basin. The obtained data show that geothermal gradient at the center of Kola Peninsula has remained close to the modern value of 20°C/km for at least the last 250 Myr. AFT data show that the Khibina massif has been exhumed not more then 5-6 km in the last 290 Myr. This study was funded by grants 15-35-20599, 15-05-02116, 15-05-01860 and 13-05-01033 from the Russian Foundation of Basic Research, grant 3.38.224.2015 from the St. Petersburg State University, grant 14.Z50.31.0017 from the Government

  20. Dichotomy of The Messada Pluton, Serbo-Macedonian Massif, Greece: From Rifting to Subduction

    NASA Astrophysics Data System (ADS)

    Vasilatos, Charalampos

    2016-10-01

    The Messada pluton is a mafic intrusion that is located about 12 km SW of Serres town, (Macedonia Greece) that intrudes the two mica, biotite and the augen gneisses of the Vertiskos formation (Serbo-Macedonian massif). The aim of this study is to investigate, define and evaluate the geochemical characteristics of the pluton in order to determine the geotectonic environment in which the parental magma has been formed. The Mesada pluton is a mid to coarse grained intrusion presenting petrographic variety from diorite and quartz diorite to tonalite and granodiorite. The variety in petrography reflects its chemical inhomogeneity in major and trace elements. It is suggested that parts of pluton have been formed by distinctly different types of magmas originated in diverse geotectonic settings. Those parts of quartz diorite and tonalite composition, present similar geochemical characteristics, LILE/HFSE ratios and negative Nb, but no Ti anomalies in their primitive mantle normalized trace elements spider grams. They exhibit higher HFS values than those of granodioritic composition. Moreover, their ORG normalized spider grams not only suggest that they have been evolved by a common parental magma, but also present the typical characteristics of a “crust dominated” within plate pluton that may have been formed in an early stage during rifting, prior to a subsequent subduction episode. This interpretation may be in accordance with the suggestion for the Gondwanian origin of the more silicic Triassic rift related meta-granites (e.g. Arnea plutonic complex) of the Serbo-Macedonian massif. In contrary; the parts of Mesada pluton of granodioritic composition, exhibit a calc-alkaline to high K calc-alkaline magmatic suite and present higher LILE/HFSE and LREE/HREE ratios, related to a higher crustal component contribution for the magma genesis. Furthermore, their primitive mantle normalized spider grams’ present negative anomalies at Nb and Ti. These characteristics

  1. Plutonic rock types series: discrimination of various granitoid series and related rocks

    NASA Astrophysics Data System (ADS)

    Lameyre, Jean; Bowden, Peter

    1982-10-01

    The Streckeisen QAP diagram discriminates four characteristic type series among the large variety of granitoids associated in intrusions. Three of them integrate varied compositions from basic to acid terms: (1) the calcalkaline series with its low K (or trondhiemite), medium K (or granodioritic), high K (or monzonitic) variants; (2) the alkaline series with its characteristic syenitic members; (3) the tholeiitic series, deprived of K feldspars. The fourth (4) corresponds to mobilizates associated with migmatites of varied composition but always quartz rich. The generalization in the QAPF system, allowing the plotting of undersaturated alkaline series, provides an excellent visual display of the major associations and trends for the plutonic rocks.

  2. MEASUREMENTS OF THE CONFINEMENT LEAKTIGHTNESS AT THE KOLA NUCLEAR POWER STATION (UNIT 2) IN RUSSIA

    SciTech Connect

    GREENE,G.A.; GUPPY,J.G.

    1998-08-01

    This is the final report on the INSP project entitled, ``Kola Confinement Leaktightness'' conducted by BNL under the authorization of Project Work Plan WBS 1.2.2.1. This project was initiated in February 1993 to assist the Russians to reduce risks associated with the continued operation of older Soviet-designed nuclear power plants, specifically the Kola VVER-440/230 Units 1 and 2, through upgrades in the confinement performance to reduce the uncontrolled leakage rate. The major technical objective of this-project was to improve the leaktightness of the Kola NPP VVER confinement boundaries, through the application of a variety of sealants to penetrations, doors and hatches, seams and surfaces, to the extent that current technology permitted. A related objective was the transfer, through training of Russian staff, of the materials application procedures to the staff of the Kola NPP. This project was part of an overall approach to minimizing uncontrolled releases from the Kola NPP VVER440/230s in the event of a serious accident, and to thereby significantly mitigate the consequences of such an accident. The US provided materials, application technology, and applications equipment for application of sealant materials, surface coatings, potting materials and gaskets, to improve the confinement leaktightness of the Kola VVER-440/23Os. The US provided for training of Russian personnel in the applications technology.

  3. Prevalence and associated risk factors of Kola nut chewing among secondary school students in Osogbo, Nigeria

    PubMed Central

    Erinfolami, Adebayo; Eegunranti, Adekunle; Ogunsemi, Olawale; Oguntuase, Akin; Akinbode, Abiola; Erinfolami, Gloria

    2011-01-01

    The objectives of this study were to determine the prevalence and pattern of Kola nut use among secondary school students in Osogbo, Osun State, Nigeria. The study also aimed to determine the association of socio-demographic variables (of the students and their parents) with kola nut chewing. A questionnaire consisting of socio-demographic variables, the stimulant use section of the WHO Students Drug Use Questionnaire was administered on three hundred and eighty-five (385) randomly selected students of the two Local Government Areas of Osogbo. The prevalence rate of kola nut use was calculated and some socio demographic variables were determined. The 30-day prevalence rate of kola nut use was 11.2%. The one-year prevalence of kola nut use was 29.1 percent and the lifetime rate was 74.8 percent. Majority of users started at age 14 years or below. Kola nut use was associated with lower age group, poor school attendance, polygamous background, low education of mother, high education of father and the description of mother as being too permissive. The findings suggest the need to increase the awareness of the dangers of kolanut use among adolescents. Control program are urgently needed to prevent student wastage. PMID:25478098

  4. Distinctly different parental magmas for plutons and lavas in the central Aleutian arc

    NASA Astrophysics Data System (ADS)

    Cai, Y.; Rioux, M. E.; Kelemen, P. B.; Goldstein, S. L.; Bolge, L.; Kylander-Clark, A. R.

    2014-12-01

    While it is generally agreed that continental crust is generated by arc magmatism, average arc lavas are basaltic while the bulk continental crust is andesitic, and this has led to many models for secondary reprocessing of the arc crust in order to form continental crust. We report new data on calc-alkaline plutons in the central Aleutians showing that they have distinctly different sources compared to Holocene tholeiitic lavas. Therefore the lavas are not representative of the net magmatic transfer from the mantle into the arc crust. Eocene to Miocene (9-39 Ma) intermediate to felsic plutonic rocks from the central Aleutian arc show higher SiO2 at a given Mg#, higher ɛNd- and ɛHf-values, and lower Pb isotope ratios than Holocene volcanic rocks from the same region. Instead, the plutonic rocks resemble volcanics from the western Aleutians isotopically, and have chemical compositions similar to bulk continental crust. These data could reflect temporal variation of Aleutian magma source compositions, from Eocene-Miocene "isotopically depleted" and predominantly calc-alkaline to Holocene "isotopically enriched" and predominantly tholeiitic. Alternatively, they may reflect different transport and emplacement processes for the magmas that form plutons and lavas: calc-alkaline magmas with higher Si content and high viscosity may preferentially form plutons, perhaps after extensive mid-crustal degassing of initially high water contents. The latter case implies that the upper and middle arc crust is more like the calc-alkaline bulk composition of the continental crust than the lavas alone. Crustal reprocessing mechanisms that preserve upper and middle arc crust, while removing lower arc crust, can account for the genesis and evolution of continental crust. Since gabbroic lower arc crust extends from ca 20-40 km depth, and is density stable over most of this depth range, "delamination" of dense lithologies [1] may not be sufficient to accomplish this. Alternatively

  5. Origin of adakite-like plutons in southern Korea

    NASA Astrophysics Data System (ADS)

    Oh, Jeong-Im; Choi, Sung Hi; Yi, Keewook

    2016-10-01

    We present Sr-Nd-Pb isotopic compositions for two adakite-like intrusions in southern Korea (Jindong and Bongnae), including major and trace element concentrations, and the sensitive high-resolution ion microprobe (SHRIMP) zircon U-Pb age. Our aim is to constrain the origin and tectonomagmatic processes that gave rise to the plutons. A SHRIMP U-Pb zircon age of 88.7 ± 0.7 Ma was obtained from a Jindong granodiorite sample. The Jindong plutons belong to the medium-K calc-alkaline series, and have an overall enrichment in large ion lithophile elements (LILE), such as K, Rb, Ba, and Pb, and a relative depletion in high field strength elements, such as Nb, Ta, and Ti, compared with the neighboring elements in the primitive mantle-normalized multi-trace element variation diagram. It was found that (87Sr/86Sr)i = 0.70475-0.70596, (143Nd/144Nd)i = 0.512547-0.512604, [(εNd)i = + 0.4 to 2.2], and (206Pb/204Pb)i = 18.19-18.37, which fall within the field of the arc-type Cretaceous to Tertiary Bulguksa intrusive rocks in the Sr-Nd and Pb-Pb isotopic correlation diagrams. The elevated Sr/Y (17-40), but low La/Yb (3.7-8.8) ratios of the Jindong plutons, together with their coherent geochemical trends and U-shaped rare earth element (REE) patterns, indicate that they were not formed by slab melting, but by amphibole-dominated fractional crystallization of the Bulguksa-like arc magma. A SHRIMP U-Pb zircon age of 226.5 ± 2.5 Ma was obtained from a Bongnae tonalite sample. The Bongnae plutons belong to the shoshonitic series. Their trace element patterns resemble the Jindong samples, but are characterized by significantly negative U anomalies in mafic rocks. They also have elevated MgO, Ni, Co, Cr, Rb, Ba, Sr, and low Al2O3 and Na2O contents at a given SiO2 concentration compared with the Jindong plutons, and are typified by highly radiogenic Sr and unradiogenic Nd and Pb isotopic compositions: [(87Sr/86Sr)i = 0.71096-0.71290, (143Nd/144Nd)i = 0.511641-0.511681, (εNd)i = - 13

  6. Nature of Phyllosilicates and Magma Types in the Plutonic Complexes of NE Egypt

    NASA Astrophysics Data System (ADS)

    Abdel-Rahman, A.

    2007-05-01

    The Late Proterozoic plutonic complexes of northeastern Egypt belong to a number of magma types of variable tectonic regimes, and exhibit a variety of phyllosilicate minerals. The results show that the phyllosilicates define three compositionally distinct groups. Phyllosilicates in the anorogenic peralkaline granites, which were developed from a hypersolvus felsic melt, are restricted to iron-rich siliceous annites and belong to type A-biotite (referring to biotite in anorogenic alkaline A-type suites). Such Fe-enriched, Al-depleted mica compositions suggest that the substitutions Fe3+ = Al, 3Fe2+ = 2Al, Fe2+ = Mg and (Fe2+ + Si) = 2Al are vital in producing annitic compositions in the peralkaline granites. In sharp contrast, phyllosilicates in the trondhjemitic pluton that crystallized from a peraluminous felsic melt, are siderophyllitic in composition and belong to type P-biotite (referring to biotite in peraluminous, including S-type suites). The substitutions Fe2+ = Mg, along with the Tschermaks substitution (Fe2+, Mg) + Si = 2Al are vital in producing siderophyllitic compositions in the trondhjemite pluton. The substitution 2Al = 3Mg (or Fe2+) also plays a role when referring to a possible solid solution between phlogopite (or annite) end-member and muscovite end-member. This pluton also contains late- to post-magmatic muscovite. Phyllosilicates in the diorite-tonalite and the voluminous granodiorite-adamellite orogenic complexes (crystallized from calcic to calc-alkaline subsolvus magmas), cover a wide range of composition, and belong to type C-biotite (referring to biotite in calcic and calc- alkaline, mostly I-type suites). The nature of micas and the magmatic stages of their development were controlled by the various physiochemical conditions (including the behavior of volatiles) prevailed during the crystallization of these hypersolvus, dry, anorogenic magmas versus subsolvus, wet, orogenic magmatic systems.

  7. Petrology and radiogeology of the Stripa pluton

    SciTech Connect

    Wollenberg, H.; Flexser, S.; Andersson, L.

    1980-12-01

    Both the quartz monzonite and the metavolcanic leptite which it intruded are strongly fractured. Two stages of fracture filling are evident; an earlier stage encompassing quartz, sericite, feldspar, epidote, and chlorite, and a later stage dominated by carbonate minerals. The Stripa quartz monozite is chemically and mineralogically distinct from other plutons in the region. Muscovite is the predominant mica in the quartz monzonite; biotite has been altered to chlorite, hornblende is absent, and accessory minerals are scarce. In contrast, in other plutons in the Stripa region, biotite and hornblende are prominent mafic minerals and accessory minerals are abundant. The Stripa quartz monzonite is also considerably more radioactive than the the leptite and other plutons in the region. Uranium and thorium abundances are both approx. 30 ppM, considerably higher than in normal granitic rocks where the thorium-to-uranium ratio generally exceeds 2. Potassium-argon dating of muscovite from the Stripa quartz monzonite indicates that this rock may be older, at 1691 million years than granitic rock of the neighboring Gusselby and Kloten massifs, whose ages, based on K-Ar dating of biotite, are respectively 1604 and 1640 m.y. Heat flow and heat productivity considerations show that although Stripa quartz monzonite contains high abundances of radioelements, the pluton has little efect on the regional heat flow. If it occurs in a layered plutonic setting, it is not more than 1.5 km thick; otherwise it may comprise a stock, dike, or border phase that is relatively small compared with the large granitic plutons exposed in the region.

  8. Bullialdus - Strengthening the case for lunar plutons

    NASA Astrophysics Data System (ADS)

    Pieters, Carle M.

    1991-11-01

    Although many craters expose materials of a composition different from that of the local surroundings, Bullialdus has excavated material representing three distinct stratigraphic zones that occur in the upper 6 km of crust, the top two of which are gabbroic and the deepest of which is noritic. This three-component stratigraphy at Bullialdus provides strong evidence that the lunar crust includes pockets of compositionally layered material reminiscent of mafic layered plutons. When combined with previous information on the compositional diversity at other large craters, these remote analyses obtained in a geologic context substantially strengthen the hypothesis suggested from lunar samples that plutons play an integral role in lunar crustal evolution.

  9. Mineralization related to Alvand pluton in the Hamadan, western Iran

    NASA Astrophysics Data System (ADS)

    Salehi, M. H.; Doosti, E. A.; Ahadnejad, V.

    2009-04-01

    The Alvand (Hamadan) plutonic batholith is one of the largest plutonic bodies in the Sanandaj-Sirjan metamorphic belt. This complex is consist of mafic part (gabbro-diorite-tonalite), intermediate (granite-granodiorite porphyroids), and hololeucocratic granitoids. Previous studies have shown that S-type granite-granodiorites are mostly peraluminous and calc-alkaline; the gabbro-diorite-tonalite suite is mostly metaluminous and tholeiitic to calc-alkaline (Sepahi, 2008). High initial 87Sr-86Sr ratios (0.7081 to 0.7115), low epsilon Nd values (-1.0 to -3.3), and peraluminous character reflects a different origin for the granites, possibly crustal sources (Ghalamghash et al, 2007). Aplite-pegmatite dikes are intruded in granitoide rocks, metamorphic rocks and the contact of Alvand granite with metamorphic rocks. The contact of Alvand granite with metamorphic rocks is sharp. By using heavy mineral studies on the alluvium of Alvand complex, it is recognized 28 minerals amongst Scheelite, Cassiterite, Ilmenite, Zircon and Garnet. Different geostatistical studies such as variant, bivariant and multivariant studies have been done on rough data of heavy minerals. They showed normal concentration of gold in studied rocks and low enrichment of tin and tungsten. The index of the ore elements average, frequeney distribution criteria of elements, the ratio of elements index and multielements show that Alvand granite is barren. Mineralography studies did not recognized any tin and tungsten minerals. The grains of gold was recognized in some of the microscopic thin sections. Calcopyrotite is the most important ore mineral that is accompanied with oxides and iron carbonates. The contacts of aplite-pegmatite dikes with granitoide rocks mostly are not prolific. For recognizing Scheelite, some samples of rocks studied by ultraviolet and few Scheelite is recognized in the samples. Some alteration zone observed in this area but they are not accompany with main mineralization. Although

  10. Geochemistry of Mesozoic plutons, southern Death Valley region, California: Insights into the origin of Cordilleran interior magmatism

    USGS Publications Warehouse

    Ramo, O.T.; Calzia, J.P.; Kosunen, P.J.

    2002-01-01

    Mesozoic granitoid plutons in the southern Death Valley region of southeastern California reveal substantial compositional and isotopic diversity for Mesozoic magmatism in the southwestern US Cordillera. Jurassic plutons of the region are mainly calc-alkaline mafic granodiorites with ??Ndi of -5 to -16, 87Sr/86Sri of 0.707-0.726, and 206Pb/204Pbi of 17.5-20.0. Cretaceous granitoids of the region are mainly monzogranites with ??Ndi of -6 to -19, 87Sr/86Sri of 0.707-0.723, and 206Pb/204Pbi of 17.4-18.6. The granitoids were generated by mixing of mantle-derived mafic melts and pre-existing crust - some of the Cretaceous plutons represent melting of Paleoproterozoic crust that, in the southern Death Valley region, is exceptionally heterogeneous. A Cretaceous gabbro on the southern flank of the region has an unuasually juvenile composition (??Ndi -3.2, 87Sr/86Sri 0.7060). Geographic position of the Mesozoic plutons and comparison with Cordillera plutonism in the Mojave Desert show that the Precambrian lithosphere (craton margin) in the eastern Mojave Desert region may consists of two crustal blocks separated by a more juvenile terrane.

  11. Multiphase groundwater flow near cooling plutons

    USGS Publications Warehouse

    Hayba, D.O.; Ingebritsen, S.E.

    1997-01-01

    We investigate groundwater flow near cooling plutons with a computer program that can model multiphase flow, temperatures up to 1200??C, thermal pressurization, and temperature-dependent rock properties. A series of experiments examines the effects of host-rock permeability, size and depth of pluton emplacement, single versus multiple intrusions, the influence of a caprock, and the impact of topographically driven groundwater flow. We also reproduce and evaluate some of the pioneering numerical experiments on flow around plutons. Host-rock permeability is the principal factor influencing fluid circulation and heat transfer in hydrothermal systems. The hottest and most steam-rich systems develop where permeability is of the order of 10-15 m2. Temperatures and life spans of systems decrease with increasing permeability. Conduction-dominated systems, in which permeabilities are ???10-16m2, persist longer but exhibit relatively modest increases in near-surface temperatures relative to ambient conditions. Pluton size, emplacement depth, and initial thermal conditions have less influence on hydrothermal circulation patterns but affect the extent of boiling and duration of hydrothermal systems. Topographically driven groundwater flow can significantly alter hydrothermal circulation; however, a low-permeability caprock effectively decouples the topographically and density-driven systems and stabilizes the mixing interface between them thereby defining a likely ore-forming environment.

  12. Petrology and radiogeology of the Stripa pluton

    SciTech Connect

    Wollenberg, Harold; Flexser, Steve; Andersson, Lennart

    1980-12-01

    To better define the character of the rock encompassing the thermomechanical and hydrological experiments at the Stripa mine in central Sweden, and to help determine the size of the Stripa pluton, detailed studies were conducted of the petrology and radiogeology of the quartz monzonite and adjacent rocks. Petrologic studies emphasized optical petrography, with supplementary X-ray diffraction, X-ray fluorescence and microprobe analyses. Radiogeologic investigations were based primarily on surface and underground gamma-ray spectrometric measurements of uranium, thorium and potassium, supplemented by laboratory gamma spectrometric analyses and fission-track radiographic determinations of the locations and abundance of uranium in the rock matrix. Both the quartz monzonite and the metavolcanic leptite which it intruded are strongly fractured. Two stages of fracture filling are evident; an earlier stage encompassing quartz, sericite, feldspar, epidote, and chlorite, and a later stage dominated by carbonate minerals. The Stripa quartz monzonite is chemically and mineralogically distinct from other plutons in the region. Muscovite is the predominant mica in the quartz monzonite; biotite has been altered to chlorite, hornblende is absent, and accessory minerals are scarce. In contrast, in other plutons in the Stripa region biotite and hornblende are prominent mafic minerals and accessory minerals are abundant. The Stripa quartz monzonite is also considerably more radioactive than the leptite and other plutons in the region. Uranium and thorium abundances are both- 30 ppm, considerably higher than in "normal" granitic rocks where the thorium-to-uranium ratio generally exceeds 2. Potassium-argon dating of muscovite from the Stripa quartz monzonite indicates that this rock may be older, at 1691 million years than granitic rock of the neighboring Gusselby and Kloten massifs, whose ages, based on K-Ar dating of biotite, are respectively 1604 and 1640 m.y. Heat flow and heat

  13. Model of formation of the Khibiny-Lovozero ore-bearing volcanic-plutonic complex

    NASA Astrophysics Data System (ADS)

    Arzamastsev, A. A.; Arzamastseva, L. V.; Zhirova, A. M.; Glaznev, V. N.

    2013-09-01

    The paper presents the results of a study of the large Paleozoic ore-magmatic system in the northeastern Fennoscandian Shield comprising the Khibiny and Lovozero plutons, the Kurga intrusion, volcanic rocks, and numerous alkaline dike swarms. As follows from the results of deep drilling and 3D geophysical simulation, large bodies of rocks pertaining to the ultramafic alkaline complex occur at the lower level of the ore-magmatic system. Peridotite, pyroxenite, melilitolite, melteigite, and ijolite occupy more than 50 vol % of the volcanic-plutonic complex within the upper 15 km accessible to gravity exploration. The proposed model represents the ore-magmatic system as a conjugate network of mantle magmatic sources localized at different depth levels and periodically supplying the melts belonging to the two autonomous groups: (1) ultramafic alkaline rocks with carbonatites and (2) alkali syenites-peralkaline syenites, which were formed synchronously having a common system of outlet conduits. With allowance for the available isotopic datings and new geochronological evidence, the duration of complex formation beginning from supply of the first batches of melt into calderas and up to postmagmatic events, expressed in formation of late pegmatoids, was no less than 25 Ma.

  14. Digital relief 3D model of the Khibiny massive (Kola peninsula)

    NASA Astrophysics Data System (ADS)

    Chesalova, Elena; Asavin, Alex

    2015-04-01

    On the basis of maps of 1: 50,000 and 1: 200,000 3D model Khibiny massif developed. We used software ARC / INFO v10.2 ESRI. This project will be organised to build background for gas pollution monitoring network. We planned to use the model to estimate local heterogeneities in the composition of the atmosphere at the emanation of greenhouse gases in the area, the construction of models of vertical distribution of the content of trace gases in the rock mass. In addition to the project GIS digital elevation model contains layers of geological and tectonic map that allows us to estimate the area of the output of certain petrographic rock groups characterized by different ratios of emitted hydrocarbons (CH4/ H2). The model allows to construct a classification of fault in the array. At first glance, there are two groups of faults - the ancient associated with the formation of the intrusive phases sequence, and the young - due to recent tectonic shifts. Ancient faults form a common semicircular structure of the pluton cause overall asymmetry Khibin heights with the transition to the border area between the Khibiny and Lovoozero. Modern tectonics mainly represented by radial and chord faults which are formed narrow mountain valleys and troughs. It remains an open question as to which system fault (old or young) is more productive to gas emanations? On the one hand the system characterized by a large old depth, on the other hand a young more active faults. Address these issues require further detailed observations. The essential question is to assess the possibility of maintaining a constant concentration gradient of these impurities in the atmosphere due to gas emanations of fracture zones and areas enriched occluded gases. In the simulation of these processes can be used initially set parameters: 1 the flow rate of the gas impurities 2 the value of wind flows in closed and open valley 3 Assessment of thermal diffusion coefficients determined by the temperature gradient

  15. Genesis of peat-bog soils in the northern taiga spruce forests of the Kola Peninsula

    SciTech Connect

    Nikonov, V.V.

    1981-01-01

    The characteristics of soil formation processes in the Peat-Bog soils of waterlogged spruce phytocenoses on the Kola Peninsula are investigated. It is found that the ash composition of the peat layer is determined primarily by the composition of the buried plant residues. The effect of the chemical composition of water feeding the peat bogs is determined. (Refs. 7).

  16. Petrogenesis of Post-collisional high Ba-Sr granitoids: the Solarya Pluton, NW Turkey

    NASA Astrophysics Data System (ADS)

    Unal, Alp; Kamaci, Omer; Altunkaynak, Safak

    2015-04-01

    In NW Turkey, the Late Oligocene-Early Miocene phase of post-collisional magmatism is characterized by widespread granitic pluton emplacements straddling the continental collision zone marked by the Izmir-Ankara suture zone (IASZ). This granitic magmatism produced both low Ba-Sr- and high Ba-Sr granitoids with distinct geochemical properties. One of the major plutons emplaced to the north of İzmir-Ankara suture zone, the Solarya pluton is representative of high Ba-Sr granitoids. We present here whole-rock chemical and Sr-Nd-Pb-O isotopic compositions, as well as 40Ar/39Ar ages of the Solarya pluton to evaluate the timing, nature and genesis of potassic, high Ba-Sr granites. The Solarya pluton consists of three coeval granitic members (K-Feldspar megacrystalline granodiorite, fine grained granodiorite and haplogranite) and associated mafic magmatic enclaves/dykes of gabbroic diorite to dioritic in composition. K-feldspar megacrystalline granodiorite, fine grained granodiorite and haplogranite are high K calc-alkaline in character whereas low silica mafic magmatic enclaves and dykes are mildly alkaline and display shoshonitic affinity. Both granitic members and mafic enclaves/dykes are characterized by high Ba (710-2489 ppm), Sr (305-708ppm), low Y and HREE contents and lack of significant negative Eu anomalies. They are metaluminous and display enrichment in LILE and depletion in P, Ta, Nb and Ti. Sr-Nd-Pb and O isotope compositions of mafic enclaves and dykes are similar to their host granitoids. They have initial 87Sr/86Sr values of 0.70702- 0.70805 and 143Nd/144Nd values of 0.51235-0.51250 and their ɛNd values range between -4,9 and -2,05. 206Pb/204Pb and 207Pb/204 Pb isotopic values vary from 18,75 to 18,88 and 15,68 to 15,73, respectivelly. Whole rock and quartz 18O isotopic ratios range between 8 and 10,6. All these isotopic characteristics and major-trace element compositions of Solarya pluton and associated mafic enclaves/dykes suggest a subcontinental

  17. Amino acid composition of two masticatory nuts (Cola acuminata and Garcinia kola) and a snack nut (Anacardium occidentale).

    PubMed

    Adeyeye, E I; Asaolu, S S; Aluko, A O

    2007-06-01

    The amino acid compositions of Cola acuminata, Garcinia kola and Anacardium occidentale were evaluated by ion-exchange chromatography. Glutamic acid was the most concentrated acid in the samples. In all the amino acids determined, A. occidentale had the most concentrated acid on a pairwise basis. The total amino acids were 356.24 mg/g protein, 112.90 mg/g protein and 659.17 mg/g protein for C. acuminata, G. kola and A. occidentale, respectively. The percentage total essential amino acids were 38.39% (C. acuminata), 47.05% (G. kola) and 51.04% (A. occidentale). Also the percentage total acidic amino acids were 38.16% (C. acuminata), 30.61% (G. kola) and 30.35% (A. occidentale). The calculated isoelectric points were 2.0 (C. acuminata), 0.7 (G. kola) and 3.9 (A. occidentale), showing they can all be precipitated at acidic pH. While threonine was the limiting amino acid in A. occidentale, it was valine in both C. acuminata and G. kola. The percentage cystine (Cys) levels in the total sulphur amino acid were 44.27% (C. acuminata), 37.75% (G. kola) and 50.51% (A. occidentale). The aim of this work was to compare the amino acid profile of the samples. It is recommended that C. acuminata and G. kola consumption be avoided by ulcer patients because of their high levels of acidic amino acids. A. occidentale amino acid scores ranged from 42% to 127%, suggesting that it could be used to enhance the protein quality of cereals through food complementation.

  18. Proterozoic subduction and terrane amalgamation in the southwestern Grenville province, Canada: Evidence from ultrapotassic to shoshonitic plutonism

    NASA Astrophysics Data System (ADS)

    Corriveau, Louise

    1990-07-01

    A late Grenvillian (1089-1076 Ma) subduction regime followed by terrane amalgamation is postulated as the paleoenvironment of a 400-km-long belt of potassium-rich alkaline and shoshonitic plutons in the Central metasedimentary belt of the southwestern Grenville province, Canada. Emplacement of the plutons postdates the regional metamorphism in the country rock, but predates major shear zones that form a structural boundary for the plutonic belt. The extent, timing, and magmatic affinities of the suite delineate the Gatineau domain within the current Mont-Laurier terrane of Quebec and are compelling evidence for the allochthonous nature of the Elzevir terrane and its extension eastward to Rideau Lake in Ontario and northward into the Gatineau domain. The belt trends northeast, the emplacement ages are younger to the southeast, and the magmatic affinities are those of island-arc ultrapotassic to shoshonitic rocks. This is interpreted to reflect the existence of a southeast-dipping, northeast-trending subduction zone beneath the combined Elzevir-Gatineau terrane between 1089 and 1076 Ma. Subsequent to subduction, amalgamation of the Elzevir terrane to the other terranes formed the Central metasedimentary belt, which then accreted and collided with the allochthonous polycyclic belt. These events provide evidence that the Ottawan orogeny commenced at ca. 1090 Ma in the Central metasedimentary belt. A modern analogue of this plutonism and its tectonic setting may have been the magmatism and arc-continent collision and subduction setting of the Sunda are, Indonesia.

  19. Infrasound research at Kola Regional Seismological Centre, Russia

    NASA Astrophysics Data System (ADS)

    Asming, Vladimir; Kremenetskaya, Elena

    2013-04-01

    A small-aperture infrasound array has been installed in Kola Peninsula, Russia 17 km far from the town of Apatity in the year 2000. It comprises 3 Chaparral V microbarographs placed closely to the APA seismic array sensors and equipped with pipe wind reducing filters. The data are digitized at the array site and transmitted in real time to a processing center in Apatity. To search for infrasound events (arrivals of coherent signals) a beamforming-style detector has been developed. Now it works in near real time. We analyzed the detecting statistics for different frequency bands. Most man-made events are detected in 1-5 Hz band, microbaromes are typically detected in 0.2-1 Hz band. In lower frequencies we record mostly a wind noise. A data base of samples of infrasound signals of different natures has been collected. It contains recordings of microbaromes, industrial and military explosions, airplane shock waves, infrasound of airplanes, thunders, rocket launches and reentries, bolides etc. The most distant signals we have detected are associated with Kursk Magnetic Anomaly explosions (1700 km far from Apatity). We implemented an algorithm for association of infrasound signals and preliminary location of infrasound events by several arrays. It was tested with Apatity data together with data of Sweden - Finnish infrasound network operated by the Institute of Space Physics in Umea (Sweden). By agreement with NORSAR we have a real-time access to the data of Norwegian experimental infrasound installation situated in Karasjok (North Norway). Currently our detection and location programs work both with Apatity and Norwegian data. The results are available in Internet. Finnish militaries routinely destroy out-of-date weapon in autumns at the same compact site in North Finland. This is a great source of repeating infrasound signals of the same magnitude and origin. We recorded several hundreds of such explosions. The signals have been used for testing our location routines

  20. Petrogenesis of Mesoproterozoic granitic plutons, eastern Llano Uplift, central Texas, USA

    NASA Astrophysics Data System (ADS)

    Smith, R. K.; Gray, Walt; Gibbs, Tyson; Gallegos, M. A.

    2010-08-01

    The Llano Uplift of central Texas is a gentle structural dome exposing ˜ 1370 to 1230 Ma metaigneous and metasedimentary rocks of Grenville affinity along the southern margin of Laurentia. The metamorphic rocks were subsequently intruded by ˜ 1119 to 1070 Ma late syn- to post-tectonic granites collectively known as the Town Mountain Granite (TMG). The eastern most of the TMG, the Marble Falls (MF), Kingsland (KL), and Lone Grove (LG) plutons, are metaluminous to marginally peraluminous, high-K, calc-alkaline, ferroan, biotite-calcic amphibole granites [Fe/(Fe + Mg) = 0.71-0.92 and 0.78-0.91 for biotite and calcic amphibole, respectively] displaying distinct variation trends with increasing silica content. They are chemically and texturally zoned and have mineralogical and chemical characteristics similar to A-type granites; i.e., 1) Fe-rich biotites, calcic amphiboles, accessory fluorite, and sporadic rapakivi texture, 2) high K 2O (> 4 wt.%), 3) low Al 2O 3 (< 16 wt.%) and CaO (< 3 wt.%), 4) high Fe/(Fe + Mg), 5) enrichments in Zr, Nb, REE, Ga/Al, and 6) depleted Eu. However, in contrast to typical A-type granites (having low Sr and Ba) the MF, KL,and LG plutons are enriched in Sr and Ba; i.e., up to 229 ppm and 1090 ppm, respectively. On granite discrimination diagrams [(K 2O + Na 2O)/CaO vs. Zr + Nb + Ce + Y (ppm) and Zr (ppm) vs. Ga/Al*10,000] the KL and MF plutons plot within the A-type field, whereas the LG pluton compositions are divided between A-type and fractionated granite fields (I-, S- and M-types). On tectonic discrimination diagrams (Y vs. Nb ) the MF and KL granites plot in the "within-plate" granite field, but the LG pluton plots across several fields including "within-plate" and "volcanic arc plus syn-collisional" fields. Consequently the tectonic classification on a geochemical basis for the LG pluton is unclear. Based on thermal metamorphic mineral assemblages, normative Q-Ab-Or plots, and Q-Ab-Or-H 2O experimental data (Johannes and Holtz

  1. Petrology of Aztec Wash pluton, Eldorado Mountains, southern Nevada

    SciTech Connect

    Falkner, C.M.; Miller, C.F. ); Wooden, J.L. )

    1993-04-01

    Aztec Wash pluton, a 50 km[sup 2] intrusive complex in the northern Eldorado Mountains, was emplaced ca. 16 Ma (Faulds et al., 1990) during extension within the Colorado River Corridor. The pluton displays extreme compositional variability, ranging from olivine gabbro (ca. 50 wt% SiO[sub 2]) to highly evolved aplite (76% SiO[sub 2]). Most of the intrusion is medium grained, homogeneous granite (ca. 72% SiO[sub 2]), but 1/3 is highly heterogeneous and dominated by mafic to intermediate rocks; a 6 [times] 3km, N-S mafic zone almost bisects the pluton. Well-displayed magma mingling and late mafic and felsic dikes verify the coexistence of mafic and felsic melts. Hornblende barometry indicates that the entire exposed portion of Aztec Wash pluton was emplaced at very shallow depth (pluton has undergone little tilting. Mafic dikes that preceded emplacement of the pluton are variably dipping and in some cases sub horizontal, possibly suggesting a more complex pre-pluton deformational history. The authors propose the following emplacement history for Aztec Wash pluton: felsic magma intruded shallow levels of crust; the base of the magma chamber was intruded by basalt; after the upper portion of the initial magma was largely crystallized, basalt ascended into, perhaps remobilized, and mingled with felsic magma; this ascent may have been facilitated by E-W extension of the crystallizing pluton; more discrete syn- to post-pluton, mafic to felsic dikes mark additional intrusive pulses triggered by basalt intrusion and extensional fracturing. Field relations suggest that the mingling led to mixing in both the main units and the late dikes, but geochemical data indicate that mixing, if it occurred, was not a simple 2-end member process.

  2. Thermal Modeling of Large Composite Plutons

    NASA Astrophysics Data System (ADS)

    Bartley, J. M.; Wohletz, K.; Coleman, D. S.; Glazner, A. F.

    2004-12-01

    Field and geochronologic evidence indicate that large plutons commonly amalgamate from many small intrusive increments [e.g., Glazner et al., 2004, GSA Today; Coleman et al., 2004, Geology]. To investigate the thermal consequences of this process, we model the growth of composite intrusions using the program HEAT. HEAT uses a finite-difference scheme to track transport and storage of heat, and resulting temperature variations, in a 2-D or 3-D intrusion and its wall rocks. Heat advected by wall-rock displacement is conserved kinematically by distributing the heat of intruded rock into adjacent mesh locations following a system determined by the aspect ratio of each intrusive increment. Modeling to date focuses on laccolithic plutons formed by stacking of sills. In a typical model, an 1100°C sill of intermediate-composition magma with a solidus of 750°C, 100-m-thick and 10-km-wide, is emplaced every 10 ka (10 mm/yr vertical inflation rate) for 600 ka to form a tabular pluton 6 km thick. Model runs to date have yielded at least three intriguing results. 1) Stacking of sills from bottom to top produces higher sustained temperatures than stacking from top to bottom. Over the first half of a 600 ka emplacement time, a bottom-up intrusion completely solidifies between increments but, during the latter half, a partial-melt zone becomes a steady-state feature. Dimensions of the partial melt zone vary through a 10 ka intrusive cycle, but the thickness reaches nearly 2 km by the time the last sill is emplaced. An otherwise identical top-down intrusion solidifies completely after each intrusive increment until the last 35 ka, when a small zone of partial melt persists between increments. The large composite complexes of the Sierra Nevada such as the Tuolumne and Whitney intrusive suites appear to have grown from their tops down, but bottom-up plutons also have been widely reported. 2) The partial-melt zone in a bottom-up intrusion mainly forms below each new intrusive

  3. Cooling history of nested plutons from the Variscan Tichka plutonic complex (Morocco)

    NASA Astrophysics Data System (ADS)

    Lécuyer, Christophe; Gasquet, Dominique; Allemand, Pascal; Martineau, François; Martinez, Isabelle

    2017-03-01

    Four imbricated mafic to felsic plutons of Variscan age from Morocco have been investigated for their cooling history and geochemical interactions with surrounding continental rocks. Oxygen isotope compositions of whole rocks and minerals have been used to model the cooling rates of these kilometer-sized intrusions. By combining both the knowledge of oxygen-self diffusion data of rock-forming minerals and the determination by IR-spectroscopy of the water content of quartz, the cooling times are estimated ranging from 105 to 5 × 105 years in agreement with the shallow emplacement (4-6 km depth) of these intrusions into the continental crust. Such fast cooling rates could explain why after assimilation of the various country rocks, heterogeneities of both neodymium and strontium isotope ratios were still preserved. A progressive δ18O increase from the mafic to felsic terms of the plutonic suite, which does not excess 1 to 1.5‰, could be explained by the assimilation of metamorphosed pelitic and volcanic rocks that constitute the basement of the Tichka plutonic complex.

  4. Reconstruction of early Holocene paleoclimate and environment in the SW Kola region, Russian Arctic

    NASA Astrophysics Data System (ADS)

    Grekov, Ivan; Kolka, Vasiliy; Syrykh, Liudmila; Nazarova, Larisa

    2016-04-01

    In the current period of the global climate change it becomes necessary to have a clear understanding of not only the changes taking place in the components of the natural environment, but also to understand development of all interactions between those components. Quaternary terrigenic sediments and lakes of the Kola Peninsula store information about the development of the region in the Late Glacial and Holocene: movements of the glacier, neotectonic activity, post-glacial rebound, formation and development of natural environments after deglaciation. Multi-proxy study of landscapes evolution of the Kola Peninsula in the Late Quaternary will help to establish a detailed reconstruction of climatic and environmental changes of this poor studied sector of the Arctic. Quaternary history on the Kola Peninsula is represented mainly by Late Pleistocene and Holocene sediments covering the Baltic Shield (Lavrova, 1960; Evzerov, 2015). Several palaeolimnological investigations in the Baltic Shield area have been performed earlier (Donner et al., 1977; Anundsen, 1985; Berglund, 2004). Studies of the southern coast of the Kola Peninsula have shown that marine transgression took place in the Late Pleistocene that was then replaced by a regression with variable speed. The slowdown of the uplift of the area took place between 8800 - 6800 BP (cal. years) and corresponded to the time of the Tapes transgression of the Arctic Ocean (Evzerov et al. 2010; Kolka, et al., 2013). Palaeoclimatic studies based on micro-paleontological analyzes indicate uneven development of the Kola Peninsula landscapes in the Late Glacial and Early Holocene. The northern coast of the Peninsula became free of ice first. In this area tundra-steppe vegetation was established for a short time and was later replaced by tundra (Snyder et al, 2000). Southern part of the Kola Peninsula was dependent on the conditions of deglaciation of the White Sea basin and cleared of ice much later (Evzerov et al., 2010; Kolka

  5. Intrusive rocks and plutonic belts of southeastern Alaska, U.S.A.

    USGS Publications Warehouse

    Brew, David A.; Morrell, Robert P.; Roddick, J.A.

    1983-01-01

    About 30 percent of the 175,000-km2 area of southeastern Alaska is underlain by intrusive igneous rocks. Compilation of available information on the distribution, composition, and ages of these rocks indicates the presence of six major and six minor plutonic belts. From west to east, the major belts are: the Fairweather-Baranof belt of early to mid-Tertiary granodiorite; the Muir-Chichagof belt of mid-Cretaceous tonalite and granodiorite; the Admiralty-Revillagigedo belt of porphyritic granodiorite, quartz diorite, and diorite of probable Cretaceous age; the Klukwan-Duke belt of concentrically zoned or Alaskan-type ultramafic-mafic plutons of mid-Cretaceous age within the Admiralty-Revillagigedo belt; the Coast Plutonic Complex sill belt of tonalite of unknown, but perhaps mid-Cretaceous, age; and the Coast Plutonic Complex belt I of early to mid-Tertiary granodiorite and quartz monzonite. The minor belts are distributed as follows: the Glacier Bay belt of Cretaceous and(or) Tertiary granodiorite, tonalite, and quartz diorite lies within the Fair-weather-Baranof belt; layered gabbro complexes of inferred mid-Tertiary age lie within and are probably related to the Fairweather-Baranof belt; the Chilkat-Chichagof belt of Jurassic granodiorite and tonalite lies within the Muir-Chichagof belt; the Sitkoh Bay alkaline, the Kendrick Bay pyroxenite to quartz monzonite, and the Annette and Cape Fox trondhjemite plutons, all interpreted to be of Ordovician(?) age, together form the crude southern southeastern Alaska belt within the Muir-Chichagof belt; the Kuiu-Etolin mid-Tertiary belt of volcanic and plutonic rocks extends from the Muir-Chichagof belt eastward into the Admiralty-Revillagigedo belt; and the Behm Canal belt of mid- to late Tertiary granite lies within and next to Coast Plutonic Complex belt II. In addition, scattered mafic-ultramafic bodies occur within the Fairweather-Baranof, Muir-Chichagof, and Coast Plutonic Complex belts I and II. Palinspastic

  6. Relationship of voluminous ignimbrites to continental arc plutons: Petrology of Jurassic ignimbrites and contemporaneous plutons in southern California

    USGS Publications Warehouse

    Fohey-Breting, N. K.; Barth, A.P.; Wooden, J.L.; Mazdab, F.K.; Carter, C.A.; Schermer, E.R.

    2010-01-01

    Volcanism was broadly associated in both space and time with Mesozoic plutonism in the Cordillera continental margin arc, but the precise petrogenetic relationships between volcanic rocks and adjacent zoned plutons are not known. Igneous rocks in a tilted crustal section in California include four laterally extensive Jurassic ash flow tuffs from 550 to >1100 m thick underlain at deeper structural levels by Jurassic plutons. Zircon geochronology confirms previous correlations of individual tuffs, suggesting ignimbrites with eruptive volumes up to 800 km3 were deposited both during the apparent Early Jurassic plutonic lull as well as contemporaneous with solidification of regionally widespread Middle and Late Jurassic plutons. The tuffs are weakly to strongly porphyritic (5 to 55% phenocrysts) monotonous intermediate porphyritic dacite to low-silica rhyolite and show strong bulk rock chemical affinity to contemporaneous plutons. Trace element compositions of zircons from the tuffs and contemporaneous plutonic rocks record large and consistent differences in Hf/Zr and REE over similar ranges in Ti abundances, supporting bulk compositional similarities and illuminating similarities and variations in thermal histories despite the effects of hydrothermal alteration. ?? 2009 Elsevier B.V. All rights reserved.

  7. From steep feeders to tabular plutons - Emplacement controls of syntectonic granitoid plutons in the Damara Belt, Namibia

    NASA Astrophysics Data System (ADS)

    Hall, Duncan; Kisters, Alexander

    2016-01-01

    Granitoid plutons in the deeply eroded south Central Zone of the Damara Belt in Namibia commonly show tabular geometries and pronounced stratigraphic controls on their emplacement. Subhorizontal, sheet-like pluton geometries record emplacement during regional subhorizontal shortening, but the intrusion of spatially and temporally closely-related granitoid plutons at different structural levels and in distinct structural settings suggests independent controls on their levels of emplacement. We describe and evaluate the controls on the loci of the dyke-to-sill transition that initiated the emplacement of three syntectonic (560-530 Ma) plutons in the basement-cover stratigraphy of the Erongo region. Intrusive relationships highlight the significance of (1) rigidity anisotropies associated with competent sedimentary packages or pre-existing subhorizontal granite sheets and (2) rheological anisotropies associated with the presence of thick ductile marble horizons. These mechanical anisotropies may lead to the initial deflection of steep feeder conduits as well as subsequent pluton assembly by the repeated underaccretion of later magma batches. The upward displacement of regional isotherms due to the heat advection associated with granite emplacement is likely to have a profound effect on the mechanical stratification of the upper crust and, consequently, on the level at which granitoid pluton emplacement is initiated. In this way, pluton emplacement at progressively shallower crustal depths may have resulted in the unusually high apparent geothermal gradients recorded in the upper crustal levels of the Damara Belt during its later evolution.

  8. Plume-derived rare gases in 380 Ma carbonatites from the Kola region (Russia) and the argon isotopic composition in the deep mantle

    NASA Astrophysics Data System (ADS)

    Marty, Bernard; Tolstikhin, Igor; Kamensky, Igor L.; Nivin, Valentin; Balaganskaya, Elena; Zimmermann, Jean-Louis

    1998-12-01

    In an effort to document the source of the parental melts to carbonatites, we have measured rare gases in 380 Ma carbonatites and associated mineral assemblages from the Kola Peninsula, eastern part of the Baltic shield in Russia. These series were emplaced during widespread Devonian magmatism when several large ultrabasic-alkaline-carbonatite massifs were formed. 4He/ 3He ratios vary from 1×10 6 to 1×10 7 in the bulk He extracted by melting of samples from three localities, including the large Kovdor massif. A comparison of measured abundances of 3He and 4He with those expected from in-situ production revealed a large (up to 10 5 times) excess of 3He, implying a significant contribution from a mantle-derived 3He-bearing fluid. Crushing of these samples allowed extraction of fluids with 4He/ 3He ratios down to 38,000, lower than those of mid-ocean ridge basalts and in the range of 4He/ 3He observed in 3He-rich ocean island basalts (OIBs) related to mantle plumes. 20Ne/ 22Ne up to 12.1±0.2 are higher than the atmospheric value of 9.80, implying the occurrence of primordial (solar-type) neon in the carbonatite source. 20Ne/ 22Ne and 21Ne/ 22Ne ratios display a good correlation, with the regression line close to (slightly to the right of) the Loihi Seamount correlation. Extrapolation of the regression to solar 20Ne/ 22Ne of 13.8 gives a 21Ne/ 22Ne of 0.045 for the plume end-member, well below the mid-ocean ridge basalt (MORB) source (upper mantle) end-member of 0.07. The measured 40Ar/ 36Ar ratios up to 2790 correlate very well with the Ne isotopic ratios, and the best estimate of the 40Ar/ 36Ar ratio of the plume source is within 5000±1000. Although the 3He/ 22Ne ratio in the plume source appears to be comparable to the solar value within a factor of 2, the 22Ne/ 36Ar ratio, computed from Ne-Ar isotope correlation, is two orders of magnitude lower than the solar value. Such difference is unlikely to be due to magmatic fractionation since the observed 4He/ 40Ar

  9. The chemical and isotopic differentiation of an epizonal magma body: Organ Needle pluton, New Mexico

    USGS Publications Warehouse

    Verplanck, P.L.; Farmer, G.L.; McCurry, M.; Mertzman, S.A.

    1999-01-01

    Major and trace element, and Nd and Sr isotopic compositions of whole rocks and mineral separates from the Oligocene, alkaline Organ Needle pluton (ONP), southern New Mexico, constrain models for the differentiation of the magma body parental to this compositionally zoned and layered epizonal intrusive body. The data reveal that the pluton is rimmed by lower ??(Nd) (~-5) and higher 87Sr/86Sr (~0.7085) syenitic rocks than those in its interior (??(Nd) ~ 2, 87Sr/86Sr ~0.7060) and that the bulk compositions of the marginal rocks become more felsic with decreasing structural depth. At the deepest exposed levels of the pluton, the ??(Nd)~-5 lithology is a compositionally heterogeneous inequigranular syenite. Modal, compositional and isotopic data from separates of rare earth element (REE)-bearing major and accesory mineral phases (hornblende, titanite, apatite, zircon) demonstrate that this decoupling of trace and major elements in the inequigranular syenite results from accumulation of light REE (LREE)-bearing minerals that were evidently separated from silicic magmas as the latter rose along the sides of the magma chamber. Chemical and isotopic data for microgranular mafic enclaves, as well as for restite xenoliths of Precambrian granite wall rock, indicate that the isotopic distinction between the marginal and interior facies of the ONP probably reflects assimilation of the wall rock by ??(Nd) ~-2 mafic magmas near the base of the magma system. Fractional crystallization and crystal liquid separation of the crystally contaminated magma at the base and along the margins of the chamber generated the highly silicic magmas that ultimately pooled at the chamber top.

  10. Discrimination of alkalinity in granitoid Rocks: A potential TIMS application

    NASA Technical Reports Server (NTRS)

    Ruff, Steven W.

    1995-01-01

    In mineral exploration, the ability to distinguish and map petrochemical variations of magmatic rocks can be a useful reconnaissance tool. Alkalinity is one such petrochemical parameter and is used in the characterization of granitoid rocks. In quartz normative plutonic rocks, alkalinity is related to the composition and abundance of feldspars. Together with quartz abundance, knowledge of feldspar modes allows the classification of these igneous rocks according to the Streckeisen diagram. Alternative classification schemes rely on whole rock geochemistry instead of mineral identifications. The relative ease of obtaining whole rock analyses means that geochemical classifications tend to be favored in exploration geology. But the technique of thermal infrared spectroscopy of rocks yields information on mineralogy and is one that can be applied remotely. The goal of the current work then is to establish whether data from TIMS can be used to distinguish the mineralogical variations that relate to alkalinity. An ideal opportunity to test this thesis arises from the work presented in a paper by Dewitt (1989). This paper contains the results of mapping and analysis of Proterozoic plutonic rocks in north-central Arizona. The map resulting from this work delineates plutons according to alkalinity in an effort to establish a trend or polarity in the regional magmatism. Also contained within this paper are brief descriptions of the mineralogy of half of the region's plutons. This combination of mineralogical and geochemical information was the rationale behind choosing this area as a site for TIMS over flights. A portion of the region centered on the northern Bradshaw Mountains was selected because it contains plutons of all three alkalinity classifications (alkali-calcic, calc-alkalic, and calic) present on DeWitt's map within a relatively small area. The site was flown in August of 1994 and the data received a few days before the writing of this manuscript. Most of this

  11. Latest Mesozoic-Early Cenozoic Continental Extension and Related Alkaline Magmatism in Central Anatolia, Turkey

    NASA Astrophysics Data System (ADS)

    Kadioglu, Y. K.

    2009-04-01

    The Central Anatolian crystalline complex (CACC) in Turkey includes a suite of latest Mesozoic-early Cenozoic plutonic rocks intruding the metamorphic and ophiolitic basement rocks. The intrusive rocks consist of three groups of granitoid, syenitoid, and gabbroids plutons. The granitoid units occur around the periphery of the CACC as large plutonic bodies, whereas the syenitoid assemblages crop out in the inner part of the CACC as small plutons. All the felsic plutons are crosscut by the gabbroid rocks in the region. The alkaline rocks of the CACC change in composition from nordmarkite through pulaskite to lusitanite, and are made of silica-saturated and silica-undersaturated magmas. The silica under-saturated alkaline rocks have gradual contacts with the silica-saturated alkaline rocks and constitute the main component of the alkaline rocks in the CACC. Nepheline, pseudoleucite, cancrinite, nosean, melanite and arfvedsonite are the main typical mineral compositions of the silica-undersaturated alkaline rocks. The leucite- and pseudoleucite-bearing rocks have porphyritic textures intruding the other main subunits of the alkaline rocks at high topographic elevations in the region. They are mostly composed of foid syenite, monzosyenite, monzodiorite and include rare amount of monzogabbro and foidolite. Each subunit has a transitional contact with the others and is crosscut by alkali feldspar foid syenite veins. Felsic dykes intrude the alkaline rock units and fluorite-bearing hydrothermal veins, which manifest themselves as alteration zones. The alkaline rocks have an abundance of xenolithic enclaves but lack any magma mixing-mingling produced enclaves. Normalized elemental patterns of the analyzed alkaline rocks show a slight enrichment in large ion lithophile elements (LILE) and light rare earth elements relatively to high field strength elements (HFSE) and heavy rare earth elements (HREE). The less fluid mobile, LILE and LREE concentration in the alkaline rocks

  12. Paleocene plutonism and its tectonic implications, North Cascades, Washington

    SciTech Connect

    Miller, R.B. ); Bowring, S.A. ); Hoppe, W.J. )

    1989-09-01

    U-Pb zircon geochronology has identified a northwest-trending belt of Paleocene (68-59 Ma) plutons within the crystalline core of the North Cascades. Most of these plutons show amphibolite facies assemblages and solid-state foiliation. They document extensive Paleogene dynamothermal metamorphism in the core, and combined with other recent studies, demonstrate ongoing metamorphism from mid-Cretaceous to mid-Eocene time. The Paleocene plutons were emplaced during an interval that marked a magmatic lull throughout much of the northern Cordillera. The distribution of latest Cretaceous and Paleocene plutons suggests that magmatism in the North Cascades core records the same eastward retreat that occurred farther north in the Cordillera.

  13. Plutonic rocks of Jurassic age in the Alaska-Aleutian Range batholith: chemical variation and polarity.

    USGS Publications Warehouse

    Reed, B.I.; Miesch, A.T.; Lanphere, M.A.

    1983-01-01

    Plutonic rocks of Jurassic age exposed on the Pacific side of this batholith form a compositionally continuous calc-alkaline suite that ranges from hornblende gabbro to quartz monzonite. Tonalite and quartz diorite are the dominant rock types. Trend-surface analysis of 102 samples indicates that the direction of slope of the trend is approximately normal to the Jurassic magmatic arc. K2O and SiO2 increase towards the E-SE and the other oxides towards the W-NW. If the chemical trends reflect the approximate geometry of a palaeo-subduction zone, the polarity of the Jurassic magmatic arc is to the NW, i.e. subduction was directed towards the SE. Thus the palaeo-subduction zone is on the opposite side of the arc from the position that has generally been assumed, indicating that the Jurassic plutonic rocks were not generated in response to classical Andean-type convergent plate margins. The magmatic arc may have been formed in an intra-ocean environment and subsequently has been rafted northwards and accreted to this part of the N Pacific rim during the late Mesozoic. Middle and Upper Jurassic clastics underlying Cook Inlet to the SE and derived from the magmatic arc are classified as back-arc deposits, rather than as an arc-trench gap sequence.-L.C.H.

  14. Petrogenesis of the reversely-zoned Turtle pluton, southeastern California

    SciTech Connect

    Allen, C.M.

    1989-01-01

    Few plutons with a reversed geometry of a felsic rim and mafic core have been described in the geologic literature. The Turtle pluton of S.E. California is an intrusion composed of a granitic rim and granodioritic core and common microgranitoid enclaves. Field observations, mineral textures and chemistries, major and trace element geochemistry, and isotopic variability support a petrogenetic model of in situ, concomitant, magma mixing and fractional crystallization of rhyolitic magma progressively mixed with an increasing volume of andesitic magma, all without chemical contribution from entrained basaltic enclaves. Hornblende geobarometry indicates the Turtle pluton crystallized at about 3.5 kb. A crystallization sequence of biotite before hornblende (and lack of pyroxenes) suggests the initial granitic magma contained less than 4 wt% H{sub 2}O at temperatures less than 780C. U-Pb, Pb-Pb, Rb-Sr and oxygen isotope studies indicate the terrane intruded by the Turtle pluton is 1.8 Ga, that the Turtle pluton crystallized at 130 Ma, that the Target Granite and garnet aplites are about 100 Ma, and that these intrusions were derived from different sources. Models based on isotopic data suggest the rhyolitic end member magma of the Turtle pluton was derived from mafic igneous rocks, and was not derived from sampled Proterozoic country rocks. Similarity of common Sr and Pb isotopic ratios of these rocks to other Mesozoic intrusions in the Colorado River Region suggest the Turtle pluton and Target Granite have affinities like rocks to the east, including the Whipple Mountains and plutons of western Arizona. P-T-t history of the southern Turtle Mountains implies uplift well into the upper crust by Late Cretaceous time so that the heating and deformation events of the Late Cretaceous and Tertiary observed in flanking ranges did not affect the study area.

  15. Geophysical modeling and structure of Ushuaia Pluton, Fuegian Andes, Argentina

    NASA Astrophysics Data System (ADS)

    Peroni, Javier Ignacio; Tassone, Alejandro Alberto; Menichetti, Marco; Cerredo, María Elena

    2009-10-01

    Within the area of Ushuaia Bay (Tierra del Fuego, southernmost South America) the deformed Lower Cretaceous sedimentary rocks of Yahgán Formation host the Ushuaia Pluton. The intrusive body is oval in map view; it is compositionally varied with rocks ranging from the ultrabasic to the mesosiliceous realm. The emplacement time is constrained within the Albian-Cenomanian span by new amphibole K/Ar data. Meso- and microstructures of Ushuaia Pluton and its host indicate a synkinematic emplacement with a dominant extensional component. A set of transcurrent and normal faults related to the sinistral strike-slip Beagle Channel Fault System affects the pluton and its host. On the basis of aeromagnetic data combined with field information, a new model is presented for the Ushuaia Pluton. Modeling results fit well with a laccolithic body with an estimated volume of around 111 km 3. The model pluton cross-section displays a central zone with an average thickness of 2000 m which progressively thins toward the margins (˜ 500 m) and a southern root which reaches 5000 m deep. The combined structural and geophysical model supports a transtensive scenario for the Ushuaia Pluton emplacement at Early-Late Cretaceous boundary.

  16. Comprehensive paleoseismic geological studies in a key site in southwestern Kola Peninsula (Northeast of the Fennoscandian Shield)

    NASA Astrophysics Data System (ADS)

    Nikolaeva, S. B.; Nikonov, A. A.; Shvarev, S. V.; Rodkin, M. V.

    2016-07-01

    This paper considers the results of detailed paleoseismic and geological investigations in a key site in the wall of the Imandra Lake depression (Kola Peninsula Region, Northeast of the Fennoscandian Shield). Study of different groups of paleoseismic deformations developed in the fault zone and the application of new methods and techniques made it possible to identify a large seismotectonic zone characterized by great earthquakes at the end of the Late Glacial and in the Holocene. The investigation data are indicative of the necessity to estimate the seismic potential in the Kola Atomic plant area in a different way.

  17. Pb isotopes in Ascension Island rocks: oceanic origin for the gabbroic to granitic plutonic xenoliths

    NASA Astrophysics Data System (ADS)

    Weis, D.

    1983-02-01

    The Pb isotopic compositions and U and Pb concentrations of the lava series (alkali basalt to comendite) and of their plutonic xenoliths (gabbro to alkaline granite) of Ascension Island are reported. The data are used to evaluate the source of the xenoliths which formed two differentiation suites: the acidic and intermediate xenoliths together with most of the lavas on the one hand, and the gabbroic xenoliths and a basaltic tuff on the other hand. The Pb isotopic compositions imply a mantle origin for the source magmas of the xenoliths and confirm the possibility of generating granitic rocks in an oceanic environment by fractional crystallization of a mantle-derived magma whose geochemical and isotopic characteristics are comparable to the source magmas of oceanic island basalts.

  18. Zircon crystal morphology and internal structures as a tool for constraining magma sources: Examples from northern Portugal Variscan biotite-rich granite plutons

    NASA Astrophysics Data System (ADS)

    Brites Martins, Helena C.; Simões, Pedro P.; Abreu, Joana

    2014-09-01

    In northern Portugal, large volumes of granitoids were emplaced during the last stage (D3) of the Variscan orogeny and display a wide range of petrological signatures. We studied the morphologies and internal structures of zircons from syn-, late- and post-D3 granitoids. The sin-D3 granitoids include the Ucanha-Vilar, Lamego, Felgueiras, Sameiro, and Refoios do Lima plutons, the late- and post-D3 granitoids are represented by the Vieira do Minho and the Vila Pouca de Aguiar plutons, respectively. Typological investigations after Pupin (1980) along with scanning electron microprobe imaging reveal that the external morphology of zircon changes consistently with a decrease in the crystallization temperature. Zircon populations from the Refoios do Lima and the Vieira do Minho granites show gradual changes in the internal morphologies and their typologic evolution trends are consistent with their mainly crustal origin. The Sameiro, Felgueiras, Lamego and Ucanha-Vilar granites have more complex internal and external morphology and typological evolution trends that cross the domain of the calc-alkaline to the aluminous granites compatible with a mixing process. Finally, the morphological types of the Vila Pouca de Aguiar granites are found both in calc-alkaline and sub-alkaline granites and their typological evolutionary trends follow the calc-alkaline/sub-alkaline trend, suggesting crustal sources with some mantle contribution.

  19. Alpine-type tectonics in the Paleoproterozoic Lapland-Kola Orogen

    NASA Astrophysics Data System (ADS)

    Mudruk, S. V.; Balagansky, V. V.; Gorbunov, I. A.; Raevsky, A. B.

    2013-07-01

    The Kola region in the northeastern Baltic Shield is characterized by diverse Paleoproterozoic collision processes. The Keivy Terrane is one of the major tectonic units in the northeastern foreland of the Paleoproterozoic Lapland-Kola Collisional Orogen, which markedly differs in a number of parameters from other tectonic units of the Kola region. The study of the Keivy Terrane allowed us to unravel one more basic difference: the large Paleoproterozoic sheath synform of the Serpovidny (Crescentic) Range localized in this terrane. Its core is occupied by volcanic and sedimentary rocks, which correlate with the fill of the Imandra-Varzuga Rift; the limbs are composed of metamorphosed mature sedimentary rocks known as Keivy paraschists of Neoarchean or Paleoproterozoic age. The lower limb of the Serpovidny Synform is strongly squeezed, whereas the upper limb consists of almost undeformed rocks. The deformed rocks underwent ductile flow under conditions of simple or general shear. In the degree of its asymmetry and main parameters, the Serpovidny Synform is similar to the plunging and recumbent anticlines in the Helvetic nappes of the Alps. It is concluded that the Paleoproterozoic core of the Serpovidny Sheath Synform, or plunging anticline, is a fragment of the almost completely eroded deep Serpovidny Nappe of the Helvetic type. During the collision related to the Lapland-Kola Orogeny (1.9-2.0 Ga), this nappe was pushed out northward from the Paleoproterozoic Imandra-Varzuga Rift, which is situated 50 km south of the Serpovidny structure, and thrust over the Keivy paraschists. The latter, together with underlying the Lebyazhka Gneiss, were folded in the process of thrusting and were involved in the structure of the Serpovidny Synform. The Keivy paraschists make up a para-autochthon or a separate nappe of the Pennine type. The Archean Lebyazhka metafelsic volcanics underlie the Keivy paraschists and overlie granitoids of the Archean basement that remained undeformed

  20. Garcinia kola seeds: is the aqueous extract a true aphrodisiac in male Wistar rats?

    PubMed

    Yakubu, M T; Quadri, A L

    2012-01-01

    The age long acclaimed aphrodisiac potentials of Garcinia kola seeds in some parts of Western Nigeria has not been substantiated with scientific evidence. In this study, we have decided to evaluate the effect of aqueous seed extract of G. kola at the doses of 25, 50 and 100 mg/kg body weight on sexual behaviour of male rats. Male rats weighing 215.00 ± 18.58 g were randomized completely into four groups (A-D) of six animals each. Animals in group A received, orally, 0.5 ml of distilled water only while those in groups B, C and D received same volume containing 25, 50 and 100 mg/kg body weight of the seed extract respectively. Frequencies of mount (MF), intromission (IF), genital toilet (GTF) and ejaculation (EF) as well as latencies of mount (ML), intromission (IL) and ejaculation (EL) were evaluated following the pairing of male rats (1:1) with non-oestrous female rats. The parameters were monitored for the first (15-30 min), second (75-90 min) and third (180195 min) observatory periods. The levels of testosterone, luteinizing (LH) and follicle stimulating hormones (FSH) were also determined. Phytochemical screening of the extract revealed the presence of saponins (2.78%), cardiac glycosides (0.26%), cardenolides and dienolides (0.24%), flavonoids (1.28%) and steroids (1.14%). The 25 and 100 mg/kg body weight increased (P<0.05) the MF whereas the ML was decreased by all the doses of the extract. MF and ML were not altered during the second observatory period whereas the 50 mg/kg body weight increased these parameters during the third observatory period. Other sexual behaviour parameters as well as serum testosterone, FSH and LH were not significantly altered throughout the observatory periods. Overall, the results revealed that G. kola seeds did not have sex enhancing potential as claimed. Therefore, the acclaimed pro sexual effect of Garcinia kola seeds is scientifically untrue. This study has refuted the claim that one of the rationales for consuming the seeds

  1. Adakitic-like magmatism in western Ossa-Morena Zone (Portugal): Geochemical and isotopic constraints of the Pavia pluton

    NASA Astrophysics Data System (ADS)

    Lima, S. M.; Neiva, A. M. R.; Ramos, J. M. F.

    2013-02-01

    Granitic rocks are a major component of the Earth's continental crust and occur in a wide variety of tectonic settings. Their chemical and isotopic characterization is crucial to the recognition of the potential sources and mechanisms involved in their generation. In this study, we present the first whole rock chemical and isotopic (Sr-Nd-O) data for the Pavia pluton (328-317 Ma), located near the western border of the Ossa-Morena Zone (Évora Massif, Portugal). Major and trace element geochemistry suggests that the different granitic phases composing this intrusive body (enclaves, granites (s.l.) and crosscutting dikes) represent independent magma pulses and the majority is similar to TTGs and adakites. The little Sr-Nd-O isotopic variation, with (87Sr/86Sr)328 = 0.70428-0.70560, ɛNd328 ranging between - 3.4 and + 0.4 and δ18O varying from + 5.6‰ to + 8.4‰ implies an isotopically similar protolith for all phases. The most viable mechanism for the generation of the Pavia pluton adakitic-like magmatism is assimilation-fractional crystallization of a mantle-derived magma. This mechanism was also invoked to explain the genesis of other plutons within the Évora Massif but they have a distinct chemistry (typical arc calc-alkaline rocks). The chemical differences between them and the Pavia pluton granitic rocks are interpreted as the result of lower degrees of crustal assimilation and higher degrees of contamination of mantle-derived magmas by the sinking slab (after subduction blocking and subsequent slab break-off).

  2. Impact of acid and trace metals deposition on freshwater invertebrates in north-eastern Fennoscandia and Kola Peninsula

    SciTech Connect

    Yakovlev, V.

    1996-12-31

    Freshwater invertebrate communities in a total 400 lakes and streams in northeastern Norway, Finnish Lapland and the Kola Peninsula, subjected to the atmospheric deposition were studied. The severe influence of toxic heavy metals, dusts from smelters and mineral enrichment factories were found in the Kola Peninsula. The negative acidification effects on benthic communities were found in the Jarfjord (Norway), Enontekio, Ranua-Posio and Kittila-Kolari (Finnish Lapland) areas and in the Kola Peninsula (Russia). Taxa groups, known to be sensitive to acidification, such as gammarids, snails, mayflies, stone flies, were represented with few species and in a low abundance. Heavy metals accumulation in biota is recorded in areas surrounding nickel smelters in the Kola Peninsula. The metal concentration invertebrates in remote areas is rather wide and depend on an air deposition, characteristics of lake catchment areas, as well as water acidity. The environmental variables, such as lake hydrological type, altitude of lakes, dominant substratum type, abundance of macrophytes and mosses in sampling area, content of pollutants in water also show significant relationships with metal concentration in invertebrates. The most severe negative effects on biota were found in waters with low pH and simultaneously contaminated by heavy metals. The biological method for estimation of simultaneously water acidification and contamination is suggested.

  3. Anatomy of the Cretaceous Hobenzan pluton, SW Japan: Internal structure of a small zoned pluton, and its genesis

    NASA Astrophysics Data System (ADS)

    Imaoka, Teruyoshi; Nakashima, Kazuo; Kamei, Atsushi; Hayasaka, Yasutaka; Ogita, Yasuo; Ikawa, Toshiyuki; Itaya, Tetsumaru; Takahashi, Yoshio; Kagami, Hiroo

    2014-11-01

    Field, petrographic, geochemical, and K-Ar and U-Pb age data were used to elucidate the internal structure of the Cretaceous Hobenzan pluton, SW Japan, and the processes which generated that structure. The pluton is elongated E-W with dimensions of about 6.5 × 2.0 km (13 km2), and was emplaced at ~ 95 Ma as a pluton in accretionary complexes. The pluton contains an early tonalite, but most of the body consists of later granitoids that show a continuous differentiation series from biotite-hornblende granodiorite (GD) to hornblende-biotite granite (HBG) and biotite granite (BG). The contacts between the GD and HBG are gradational. The pluton provides an exceptional cross-sectional view of a simple cooling magma body. The GD shows no vertical variations in modal and chemical compositions, whereas the HBG displays differentiation from the lowermost exposure to the top of the pluton. Initial Sr isotope ratios (SrI) in the HBG increase from the lower part to the top of the pluton. The granitoids show continuous compositional variations from 65 to 79 wt.% SiO2 (anhydrous basis), and magmatic differentiation was dominantly controlled by crystal fractionation of hornblende and plagioclase. Field, elemental and Sr-Nd isotope data are consistent with limited operation of assimilation with pelitic rocks and fractional crystallization (AFC), in which assimilation increased with higher degrees of differentiation. The Hobenzan pluton retains a history of granitoid magma evolution in a subvolcanic magma reservoir. The GD formed as a rigid sponge, and melt fraction increases inwards from the walls, forming the HBG mush by fractional crystallization, coupled with small degrees of assimilation of adjacent schists. A more evolved and enriched low-density melt segregated from the mushy cumulate of the HBG by incomplete crystal-melt separation, and moved upwards with the assistance of gas-driven filter pressing, as indicated by the presence of miarolitic cavities, thus forming the BG

  4. Survey of lunar plutonic and granulitic lithic fragments

    NASA Technical Reports Server (NTRS)

    Bickel, C. E.; Warner, J. L.

    1978-01-01

    A catalog of lunar plutonic rocks and granulitic impactites belonging to the ANT suite has been compiled. The coarser-grained, plutonic rocks in the compilation are probably pristine; they belong to two groups, Mg-rich plutonic rocks and anorthosites, with a preponderance of the latter type. The granulitic impactites, however, have bulk and mineral compositions that fall between the two groups defined by the pristine nonmare samples of Warren and Wasson (1977). Thus the granulitic impactites may have originated by metamorphism of mixed impactites in early breccia sheets. The catalog, representative of the lunar crust before the end of heavy bombardment, suggests a crust with over 78 vol. % plagioclase and about equal proportions of material with noritic and troctolitic affinity.

  5. An AMS study of the Takidani pluton (Japan)

    NASA Astrophysics Data System (ADS)

    Hartung, Eva; Caricchi, Luca; Floess, David; Wallis, Simon; Harayama, Satoru

    2016-04-01

    Large plutonic bodies are typically constructed incrementally often by under-accretion of distinct successive magma pulses. Petrography and geochemistry of the Takidani Pluton (1.54 Ma ± 0.23 Ma) in the Northern Japanese Alps show that the chemical and textural variability observed at the roof of this intrusion is best explained by the segregation of residual melt from a crystallising magma body. We carried out a magnetic susceptibility survey (bulk susceptibility and anisotropy of magnetic susceptibility) to identify the structures associated with the emplacement and extraction of residual melts from a magmatic mush. Additionally, we determined shape preferred orientations (SPO) of amphibole at several locations within the Takidani pluton. From bottom to top of the intrusion, the bulk susceptibility is about constant in the main granodioritic part, decreases roofwards within the porphyritic unit, before increasing again within the marginal granodiorite close to the contact with the overlaying Hotaka Andesite. Such variability mimics the major and trace elements compositional variability measured in the whole rock samples. Magnetic foliations are observed at the western tectonic contact of the pluton potentially indicating overprint, while most other magnetic fabrics across the pluton are characterised by triaxial ellipsoids of magnetic susceptibility or magnetic lineations. Our preliminary data and the lack of internal contacts indicate that Takidani Pluton was likely emplaced as a series of successive magma pulses finally merging to produce a large connected magma body. While amphibole foliations may likely be the results of super-solidus tectonic overprint, anisotropy of magnetic susceptibility data may be related to post-emplacement melt segregation.

  6. A Pan-African alkaline pluton intruding the Saramuj Conglomerate, south-west Jordan

    NASA Astrophysics Data System (ADS)

    Jarrar, Ghaleb; Wachendorf, Horst; Zachmann, Dieter

    1993-04-01

    The geological setting, petrography and bulk mineral chemistry of a monzodiorite and a presumably consanguineous megaporphyry with large (up to 25 cm) labradorite megacrysts, both intruding the upper Proterozoic Saramuj Conglomerate in south-west Jordan (south eastern shore of the Dead Sea), were examined. The crystallization temperatures of the monzodiorite and the megaporphyry as determined from pyroxene thermometry and supported by contact metamorphic mineralogy are about 700 and 900°C, respectively. The intrusion depth of the monzodiorite is about 3 4 km. The monzodiorite was emplaced in the Saramuj Conglomerate at about 595 + 2 Ma ago according to Rb/Sr and U/Pb age determinations. The stratigraphic positions of the monzodiorite, megaporphyry and their host rock (the Saramuj Conglomerate) were compared with time-equivalent lithologies in the Arabian-Nubian Shield.

  7. The geochemical and genetic role of organic substances in postmagmatic derivatives of alkaline plutons

    NASA Astrophysics Data System (ADS)

    Ermolaeva, V. N.; Chukanov, N. V.; Pekov, I. V.; Kogarko, L. N.

    2009-12-01

    Solid bituminous substances (SBS) are common components of the late hydrothermal mineral assemblages of peralkaline pegmatites. SBS are formed in a reductive setting as a result of progressive sorption of minor carbon-bearing molecules (CO, CO2, CH4, C2H6, C2H4, etc.), their polymerization, transformation into aromatic compounds (reformation), and selective oxidation on microporous zeolite-like Ti-, Nb-, and Zrsilicates serving as sorbents and catalysts. The oxygen-bearing aromatic compounds with hydrophile functional groups (-OH, -C=O, -COOH, -COO) act as complexing agents with respect to Th, REE, U, Zr, Ti, Nb, Ba, Sr, Ca, resulting in transfer of these bitumenophile elements under low-temperature hydrothermal conditions in the form of water-soluble macroassociates of the micelle type. Th, REE, and to a lesser extent, U, Zr, Ti, and Nb concentrate at the late stage of the hydrothermal process as microphases impregnating SBS or macroscopic segregations of Th and REE minerals. At the final stage, homogeneous SBS break down into organic (partly together with Ca, Sr, Ba, and Pb) and mineral (with Th, Ln, Y, Ti, Nb, Ca, Na, K, Si) microphases.

  8. ABCGheritage project - promoting geotourism in northern Finland, northern Norway and the Kola Peninsula

    NASA Astrophysics Data System (ADS)

    Pihlaja, Jouni; Johansson, Peter; Lauri, Laura S.

    2014-05-01

    Nature tourism has been a growing business sector in the Barents area during the recent decades. With the purpose to develop nature tourism in a sustainable way, a cooperation project ABCGheritage - Arctic Biological, Cultural and Geological Heritage has been carried out. Project has received partial funding from the EU Kolarctic ENPI program. In the geoheritage part of the project the main activities were aimed to develop pro-environmental ways of geotourism in the area. The three main participants in the geoheritage part of the project are the Geological Survey of Finland, Northern Finland Office, the Geological Institute of the Kola Science Centre of the Russian Academy of Sciences and Bioforsk Soil and Environment from northeastern Norway. The duration of the project is 2012-2014 and most of the work has already been completed even if most of the results are not published yet. Totally ten different tasks have been implemented in the geological part of the project. The largest task has been the preparation of a geological outdoor map and guide book of the Khibiny Tundra locating in the central part of the Kola Peninsula. In Finland already 11 such maps have been published, and the experiences gained during their production have been used in this project, too. Geological heritage trails to the Khibiny Tundra have also been created and they will be drawn on the map. The second concrete result is the Barents Tour for Geotourist -guide, which will be published as a guide book, web pages and an exhibition. The route comprises ca 35 best geological demonstration sites along the circle route from northern Finland to northeastern Norway, from there to Kola Peninsula and then back to Finland. Information of the route will be available for all interested travelers. In addition to the geological outdoor map of the Khibiny Tundra and "Barents Tour for Geotourists"-guide, the primary outputs of the project are the geological nature trails on the field, geological

  9. The primary circuit materials properties results analysis performed on archive material used in NPP V-1 and Kola NPP Units 1 and 2

    SciTech Connect

    Kupca, L.; Beno, P.

    1997-04-01

    A very brief summary is provided of a primary circuit piping material properties analysis. The analysis was performed for the Bohunice V-1 reactor and the Kola-1 and -2 reactors. Assessment was performed on Bohunice V-1 archive materials and primary piping material cut from the Kola units after 100,000 hours of operation. Main research program tasks included analysis of mechanical properties, corrosion stability, and microstructural properties. Analysis results are not provided.

  10. Efficiency of remediation of technogenic barrens around the Pechenganikel works in the Kola Subarctic

    NASA Astrophysics Data System (ADS)

    Koptsik, G. N.; Koptsik, S. V.; Smirnova, I. E.

    2014-05-01

    Remediation of the technogenic barrens around the Pechenganikel works on the Kola Peninsula resulted in the improvement of the soil properties, namely, in a decrease in acidity and enrichment with nutrients, which continued for several years. However, the reaction of most of the treated soils remained strongly acid, and the concentrations of available calcium, magnesium, potassium, and phosphorus were much lower than their background levels and the demands of the plants for nutrients (especially, for magnesium and potassium). The soils were depleted in available manganese and zinc. Most of the treated soils contained the same (or higher) amounts of available nickel and copper compounds in comparison with their untreated analogues. The willow plantations on the remediated plots were in a satisfactory state, but they experienced a deficit of magnesium, manganese, and zinc; they consumed elevated amounts of nickel and copper. Recommendations on the nutrient regime of the soils aimed at decreasing the mobility and biological availability of heavy metals were made.

  11. Alternative technologies for remediation of technogenic barrens in the Kola Subarctic

    NASA Astrophysics Data System (ADS)

    Koptsik, G. N.; Koptsik, S. V.; Smirnova, I. E.

    2016-11-01

    The efficiency of remediation of technogenic barrens under the reduction of air pollutant emissions from the Severonikel smelter in the Kola Subarctic is determined largely by the soil state and the technology applied. The covering of the contaminated soils with artificially made material based on organomineral substrates and the following liming and fertilization promoted a sharp and long-term reduction of acidity, decrease in the biological availability of heavy metals, increase in the supply with nutrients, and improvement of the life state of willow and birch plantations. The effect of economically more profitable chemo-phytostabilization is short-term; it requires constant maintenance. Under the current production and a high level of soil contamination, repeated measures are required to optimize the soil reaction, supply with nutrients, and to correct the availability of heavy metals in the soils based on the results of continuous monitoring

  12. An ecotoxicity assessment of contaminated forest soils from the Kola Peninsula.

    PubMed

    Paton, Graeme I; Viventsova, Ekaterina; Kumpene, Jurate; Wilson, Michael J; Weitz, Hedda J; Dawson, Julian J C

    2006-02-15

    Point source copper and nickel contamination emanating from smelters of the Kola Peninsula, NW Russia, has been observed since the mid-1960s. Previous studies have concentrated on the spatial distribution of heavy metals and their effects on forest ecology and indigenous mammals and birds. Soil is perceived as the major repository for the metal pollutants but there is a need to link the soil concentration of pollutants on the Kola Peninsula with biological parameters. Many standard methods currently used in soil ecotoxicology are developed and refined with artificial amendments and rarely modified for use in historically contaminated environments. In this study, forest soils were sampled along a 34 km transect from the smelter and analysed both chemically and with a range of ecologically relevant biological tests. Soil respiration, total nematode count, microbial heterotrophic numbers and minimal inhibitory concentrations to copper and nickel were carried out on bulk soil. The soil pore water was tested with bacterial and fungal bioluminescence-based biosensors. The heterotrophic numbers and their inhibitory concentration showed strong correlation with heavy metal concentrations while decreasing biosensor luminescence was related to increasing copper concentrations present in the pore waters. Overall, there were considerable impacts on some microbial parameters but other measures including respiration and nematode populations were insensitive to pollutant levels. While chemical analysis of heavy metals proved essential in defining the extent of contamination, environmentally relevant ecotoxicological tests complemented these data by demonstrating pollutant impact. Ecotoxicological approaches that study both the bulk soil and pore water may represent the key to understanding the fate of heavy metal in soils.

  13. Ferrobasalt-rhyolite immiscibility in tholeiitic volcanic and plutonic series (Invited)

    NASA Astrophysics Data System (ADS)

    Charlier, B.; Namur, O.; Kamenetsky, V. S.; Grove, T. L.

    2013-12-01

    One atmosphere experiments show that silicate liquid immiscibility develops between Fe-rich and Si-rich melts below 1000-1020°C in compositionally diverse lavas that represent classical tholeiitic trends, such as Mull, Iceland, Snake River Plain and Sept Iles. Extreme iron enrichment along the evolution trend is not necessary; immiscibility also develops during iron depletion and silica enrichment after Fe-Ti oxide saturation. Natural liquid lines of descent for major tholeiitic series also approach or intersect the experimentally-defined compositional space of immiscibility. The importance of ferrobasalt-rhyolite unmixing in both volcanic and plutonic environments is supported by worldwide occurrence of immiscible globules in the mesostasis of erupted basalts, and by unmixed melt inclusions in cumulus phases of major layered intrusions such as Sept Iles, Skaergaard and Sudbury. A clear case of liquid immiscibility is also recorded in intrusive tholeiitic gabbros from the Siberian Large Igneous Province and is evidenced by textures and compositions of millimeter-sized silicate melt pools trapped in native iron. An important implication of immiscibility in natural ferrobasaltic provinces is the development of a compositional gap characterized by the absence of intermediate compositions, a major feature observed in many tholeiitic provinces and referred to as the Daly gap. The compositions of experimental silica-rich immiscible melts coincide with those of natural rhyolites with high FeOtot and low Al2O3, which suggests a potential role for large-scale immiscibility in the petrogenesis of late-stage ferroan silicic melts. No evidence for the paired ferrobasaltic melt is observed in volcanic provinces, probably because of its uneruptable characteristics. Instead, Fe-Ti×P-rich gabbros crystallized at depth and are the cumulate products of immiscible Fe-rich melts in plutonic settings, a feature clearly evidenced in the Sept Iles intrusion. The production of

  14. SHRIMP U-Pb dating and geochemistry of the Cretaceous plutonic rocks in the Korean Peninsula: A new tectonic model of the Cretaceous Korean Peninsula

    NASA Astrophysics Data System (ADS)

    Kim, Sung Won; Kwon, Sanghoon; Park, Seung-Ik; Lee, Changyeol; Cho, Deung-Lyong; Lee, Hong-Jin; Ko, Kyoungtae; Kim, Sook Ju

    2016-10-01

    The Cretaceous tectonomagmatism of the Korean Peninsula was examined based on geochemical and geochronological data of the Cretaceous plutonic rocks, along with distribution of volcano-sedimentary nonmarine N- to NE-trending fault bounded sedimentary basins. We conducted sensitive high-resolution ion microprobe (SHRIMP) zircon U-Pb ages and whole-rock geochemical compositions of 21 Cretaceous plutonic rocks, together with previously published data, from the central to southern Korean Peninsula. Four age groups of plutonic rocks were identified: Group I (ca. 119-106 Ma) in the northern to central area, Group II (ca. 99-87 Ma) in the central southern area, Group III (ca. 85-82 Ma) in the central to southern area, and Group IV (ca. 76-67 Ma) in the southernmost area. These results indicate a sporadic trenchward-younging trend of the Cretaceous magmatism in the Korean Peninsula. The Group I, II, and III rocks are dominated by high-K calc-alkaline I-type rocks with rift-related A-type granitoids. In contrast, the Group IV rocks are high-K calc-alkaline I-type plutonic rocks with no A-type rocks. The geochemical signatures of the entire groups indicated LREEs (light rare earth elements) enrichments and negative Nb, Ta, and Ti anomalies, indicating normal arc magmatism. A new tectonic model of the Cretaceous Korean Peninsula was proposed based on temporal and spatial distribution of the Cretaceous plutons represented by four age groups; 1) magmatic quiescence throughout the Korean Peninsula from ca. 160 to 120 Ma, 2) intrusions of the I- and A-type granitoids in the northern and central Korean Peninsula (Group I plutonic rocks from ca. 120 to 100 Ma) resulted from the partial melting of the lower continental crust due to the rollback of the Izanagi plate expressed as the conversion from flat-lying subduction to normal subduction. The Gyeongsang nonmarine sedimentary rift basin in the Korean Peninsula and adakite magmatism preserved in the present-day Japanese Islands

  15. Emplacement and fabric-forming conditions of plutons from structural and magnetic fabric analysis: A case study of the Plana pluton (Central Bulgaria)

    NASA Astrophysics Data System (ADS)

    Georgiev, Neven; Henry, Bernard; Jordanova, Neli; Jordanova, Diana; Naydenov, Kalin

    2014-08-01

    The relationship between intensity parameters, such as the corrected anisotropy degree P‧ and mean susceptibility Km for plutons with similar magnetic mineralogy, yields a criterion to determine the origin of their magnetic fabric: for a same mineralogy, the higher the P‧ values for the same mean susceptibility Km (irrespective of its absolute value) the higher tectonic effect was possible. Using this criterion, comparison of the magnetic fabric of the Upper Cretaceous mid- to shallow crustal level Plana pluton with that of other small Upper Cretaceous plutonic bodies in Sredna Gora Zone (Central and Southeast Bulgaria) highlights the structural evolution of the Plana pluton. The central part of Plana pluton and its southwest, west and east margins have preserved their emplacement fabric. Along its northern contact the pluton is affected by the last movements within the Okol Shear Zone where high-temperature S/L mylonites developed. The fabric of the pluton at its southeastern border was disturbed during the intrusion of the neighboring Gutsal pluton. The similarity in the orientation of magmatic and magnetic structures preserved in the central and southern parts of the Plana pluton and the transition from magmatic to high-temperature superimposed foliations and lineations at its north contact point to a composite superimposed shear-induced and emplacement-related magmatic magnetic fabric. Nearly vertical orientation of magnetic and magmatic foliations and lineations from the undeformed parts of the pluton shows a process of vertical magma rising and emplacement. The sub-vertical high-temperature solid-state mylonitic foliation and dip-parallel stretching lineation in the pluton along its northern contact reveals the transpression nature of the deformation in the vicinity of Okol Shear Zone with a strong pure shear component. The smooth transition between the deformed and undeformed parts of Plana pluton reveals the syn-kinematic character of the emplacement.

  16. The Plutón Diorítico Moat: Mildly alkaline monzonitic magmatism in the Fuegian Andes of Argentina

    NASA Astrophysics Data System (ADS)

    González Guillot, M.; Escayola, M.; Acevedo, R.; Pimentel, M.; Seraphim, G.; Proenza, J.; Schalamuk, I.

    2009-12-01

    The Plutón Diorítico Moat (Moat Dioritic Pluton, PDM) is the largest of several isolated Cretaceous plutons exposed in the Fuegian Andes of Argentina. It is made of a large variety of rock types ranging from ultramafic bodies (pyroxenites and hornblendites) to syenites. The petrological diversity is thought to have been originated by fractional crystallization of a mantle-derived magma combined with minor assimilation of continental crust (AFC). Its geochemical characteristics indicate a mildly-alkaline monzonitic affinity, contrasting with the typical calc-alkaline plutons of the Southern Patagonian Batholith (PB) to the south, in the Chilean archipelago. The PDM original magma is arc-related and its crystallization, as indicated by the Rb-Sr mineral isochron age of 115 ± 3 Ma, is coeval with some plutons of the PB. Therefore a similar tectonic regime is assumed for the emplacement of these plutonic bodies, both south and north of the Beagle channel. Differences in magma sources and degree of partial melting are inferred to account for the contrasting lithological and geochemical characteristics of the PB and PDM. The data suggest that the original magmas of the PDM were generated at greater depths in the mantle, by a smaller degree of partial melting, compared with the PB. The Barros Arana basalts, exposed to the north in Chile, forming a back-arc volcanic complex, display the same mildly-alkaline shoshonitic affinity, and are considered in this study as the volcanic equivalents of the PDM. All the plutons in the Argentinean Fuegian Andes display similar lithological and geochemical characteristics and are, therefore, grouped in this work under the name of Magmatismo Potásico Fueguino ( Fuegian Potassic Magmatism).

  17. The San Blas Pluton: An example of Carboniferous plutonism in the Sierras Pampeanas, Argentina

    NASA Astrophysics Data System (ADS)

    Dahlquist, J. A.; Pankhurst, R. J.; Rapela, C. W.; Casquet, C.; Fanning, C. M.; Alasino, P.; Baez, M.

    2006-03-01

    New geochronological and geochemical data are reported for the San Blas Pluton (SBP), in the northwestern Sierra de Velasco, Sierras Pampeanas, which intrudes Ordovician granitoids developed during the Famatinian orogeny. A precise Carboniferous age of 340±3 Ma is established by U-Pb dating of zircon using a sensitive high-resolution ion microprobe (SHRIMP). The SBP illustrates several petrological and geochemical characteristics of previously reported Carboniferous granitoids in the Sierras Pampeanas. Their generation is consistent with a regional reheating of the crust at approximately 342 Ma, which resulted in the formation of relatively large amounts of granitic melts that were emplaced in higher crustal levels along master fractures (older master shear zones of Lower Paleozoic age). The SBP can be chemically defined as a typical A-type granitoid related to postcollisonal or postorogenic magmatism. Its high REE content and extraordinarily high U and Th concentrations may have economic significance. Many previously published Devonian and Carboniferous K-Ar dates are reset Ordovician ages, but the existence of other Carboniferous bodies in the Sierra de Velasco cannot be discounted until detailed mapping of the whole Sierra is completed.

  18. Paleomagnetism of Devonian dykes in the northern Kola Peninsula and its bearing on the apparent polar wander path of Baltica in the Precambrian

    NASA Astrophysics Data System (ADS)

    Veselovskiy, Roman V.; Bazhenov, Mikhail L.; Arzamastsev, Andrey A.

    2016-04-01

    Mafic dykes and large alkaline and carbonatite intrusions of Middle-Late Devonian age are widespread on the Kola Peninsula in NE Fennoscandia. These magmatic rocks are well characterized with petrographic, geochemical and geochronological data but no paleomagnetic results have been reported yet. We studied dolerite dykes from the northern part of the Peninsula and isolated three paleomagnetic components in these rocks. A low-temperature component is aligned along the present-day field, while a major constituent of natural remanent magnetization is an intermediate-temperature component (Decl. = 79.6°, Inc. = 78.5°, α95 = 5,9°, N = 17 sites) that is present in most Devonian dykes but is found in some baked metamorphic rocks and Proterozoic dykes too. Finally, a primary Devonian component could be reliably isolated from two dykes only. Rock-magnetic studies point to presumably primary low-Ti titanomagnetite and/or pure magnetite as the main remanence carriers but also reveal alteration of the primary minerals and the formation of new magnetic phases. The directions of a major component differ from the Middle Paleozoic reference data for Baltica but closely match those for the 190 ± 10 Ma interval recalculated from the apparent polar wander path of the craton. We assume that this Early Jurassic component is a low-temperature overprint of chemical origin. The main impact of the new results is not to mid-Paleozoic or Early Mesozoic times but to much older epochs. Analysis of paleomagnetic data shows that the directionally similar remanences are present in objects with the ages ranging from 500 Ma to 2 Ga over entire Fennoscandia. Hence we argue that an Early Jurassic remagnetization is of regional extent but cannot link it to a certain process and a certain tectonic event. If true, this hypothesis necessitates a major revision of the APWP for Baltica over a wide time interval.

  19. Nutrient and phytochemical composition of two varieties of Monkey kola (Cola parchycarpa and Cola lepidota): An underutilised fruit.

    PubMed

    Ene-Obong, Henrietta N; Okudu, Helen O; Asumugha, Ukamaka V

    2016-02-15

    The nutrient and phytochemical composition of two varieties of Monkey kola: Cola parchycarpa and Cola lepidota were determined. The pulps were extracted, grated and dried using solar dryer. Dried pulps were milled into flour with attrition milling machine (0.5mm sieve size). The nutrient compositions were determined using standard AOAC methods. Gravimetric and spectrophotometric methods were used for phytochemical determinations. There were significant (p<0.05) differences in the proximate and some mineral and vitamin composition of the two varieties. Most abundant minerals were calcium (195-199mg for C. parchycarpa), potassium (204-209mg/100g for C. lepidota) and β-carotene (2755-5028μg/100g for C. parchycarpa). Calcium:phosphorus and sodium:potassium ratios were adequate (>1.0 and ⩽0.06, respectively). Monkey kola had substantial amounts of iron, zinc, and copper; the B-vitamins and vitamin C. The phytochemical contents were quiet high, the most abundant being flavonoids (415-494mg/100g). Monkey kola is a fruit that should be fully exploited for its potential health benefits.

  20. Effect of dietary Garcinia kola seed on selected serum electrolytes and trace metals in male Albino rats.

    PubMed

    Agada, P O; Braide, V B

    2009-06-01

    The effects of various doses of dietary intake of Garcinia kola seed powder [incorporated in animal feed at levels of 5% w/w, 10% w/w and 20% w/w and fed daily for six weeks] on serum levels of selected electrolytes [K+, Na+, CI-, HCO3-, Mg2+ and Ca2+] and trace metals [Cu2+, Zn2+ and Mn2+] were studied in male Albino rats [100-150 g body wt]. The pair-fed controls received basal feed diet daily for six weeks. Results showed a significant [P<0.05] dose dependent elevation of serum CI-, HCO3-, Ca2+, Mg2+, Cu2+, Zn2+ and Mn2+. These findings point to a possible relationship with already documented histopathology of various organs [such as the gonads] induced by Garcinia kola seed. It is also conjectured that the documented antibacterial, anti-inflammatory, anti-spasmodic, antidiabetic and antifertility effects of Garcinia kola seed may have underlying involvement of alterations in body levels of trace metals and electrolytes.

  1. Miscellaneous investigations series: Bedrock geologic map of the Lone Mountain pluton area, Esmeralda County, Nevada

    SciTech Connect

    Maldonado, F.

    1984-12-31

    The joint attitudes were measured in the field and plotted on aerial photos at a scale of 1:24,000. The pluton is intensely jointed, primarily as a result of cooling and movement of the magma within a northwest-trending stress field. Foliation, in general, is poorly developed, and quality varies from area to area, but it is best developed close to the contacts with the metasedimentary rocks. A prominent northwest foliation direction was observed that parallels the northwest elongation of the exposed pluton. Faults in the pluton are difficult to identify because of the homogeneity of the rock. Several faults were mapped in the northern part of the area where they have a northeast trend and intersect the northwest-trending lamprophyre dikes with little apparent displacement. A major fault that bounds the northern part of the pluton is downthrown to the north and strikes northeast. This fault offsets the alluvium, the metasedimentary rocks, and the pluton and forms fault scraps as high as 10 m. Aeromagnetic data (US Geological Survey, 1979) suggest the following: (1) the local magnetic highs in the central part of the Lone Mountain pluton are probably related to topographic highs (peaks) where the flight lines are closer to the pluton; (2) a magnetic low in the northeastern part of Lone Mountain coincides with the pluton-country rock contact, which may be very steep; (3) the contours for the southwestern part of the mapped area indicate that the pluton-country rock contact is not as steep as that in the northeastern part and that the pluton probably coalesces at depth with the Weepah pluton, a pluton exposed south of the mapped area; and (4) the contours for the area of the Lone Mountain pluton express a northwest-trending gradient that parallels the northwest elongation of the Lone Mountain pluton and the northwest-trending stress field. 10 refs.

  2. Geochemistry and zircon U-Pb-Hf isotopes of the granitoids of Baolidao and Halatu plutons in Sonidzuoqi area, Inner Mongolia: Implications for petrogenesis and geodynamic setting

    NASA Astrophysics Data System (ADS)

    Hu, Chuansheng; Li, Wenbo; Xu, Cheng; Zhong, Richen; Zhu, Feng

    2015-01-01

    The Baolidao and Halatu plutons are located in the Northern Orogenic Belt (NOB) in Sonidzuoqi area of Inner Mongolia, which has an important significance for the tectonic evolution of Xing-Meng Orogenic Belt (XMOB). The two plutons have been intensively studied but the conclusions are still controversial. Combined with the previous study, this paper gives new geological data about the two correlative plutons for gaining a better understanding of their petrogenesis and the geodynamic setting. The Baolidao granitoids contain two different series, calc-alkaline series mainly formed in the Ordovician and high K calc-alkaline series mainly formed in the Carboniferous. The Halatu granites are formed in the Triassic and belong to high-K calc-alkaline series. This study got the zircon U-Pb ages of 316-322 Ma for the Baolidao granitoids and 233 ± 2 Ma for the Halatu syenogranites, respectively. In the tectonic discrimination diagrams, they mainly fall into the area of post-orogenic granites (POG). Hf isotopic analyses for the Baolidao granitoids (Sample BLD-1 and 3) shows εHf (t) = 3.0-14.0, with two-stage Hf model age (TDM2) of 436-1138 Ma. The Halatu syenogranite (Sample HLT-1) also shows a depleted εHf (t) = 3.8-8.2, with TDM2 of 741-1024 Ma, suggesting the major involvement of juvenile crustal components. The various εHf values of the Carboniferous Baolidao and Triassic Halatu granitoids indicates a hybrid magma source of juvenile material with old crustal component, and the εHf (t) values decrease from the Carboniferous to Triassic, suggesting the increasing proportion of old continental material during this period. Combined with the regional geology, the Carboniferous Baolidao granitoids are possibly not arc rocks, but originated from the post-collisional setting. The Triassic Halatu granites were formed in the subsequently extensional environment.

  3. Archean to Paleoproterozoic polymetamorphic history of the Salma eclogite in Kola Peninsula, Russia

    NASA Astrophysics Data System (ADS)

    Imayama, Takeshi; Oh, Chang-Whan; Park, Chan-Soo; Yi, Keewook; Jung, Haemyeong

    2015-04-01

    One of the most important questions in the Earth Science is when and how plate tectonics operate in the Precambrian time. The tectonic and thermal evolution of the Precambrian eclogite is significant key for understanding the Precambrian geodynamic mechanisms. Eclogites in Kola Peninsula, Russia are some of the oldest eclogites of the world, but there has been much debate about the timing of eclogite-facies metamorphism: Archean (e.g. Volodichev et al. 2004; Mints et al., 2010) or Paleoproterozoic (e.g. Skublob et al., 2011, 2012). The controversy is mainly because of the lack of zircon dating coupled with the formation of garnet and omphacite. In this study, we present geochronological, petrographic, and geochemical data from the Salma eclogites in the Kola Peninsula, Russia to characterize subduction and collision processes in the Precambrian. Microstructural observations, P-T analyses, zircon inclusion analyses, and U-Pb zircon dating revealed multiple metamorphic stages that the Salma eclogite underwent. The amphibolite facies metamorphic event firstly occurred at 2.73-2.72 Ga during Archean. In the Paleoproterozoic period, the Salma eclogites underwent prograde stage of epidote-amphibolite facies metamorphism. The eclogite facies metamorphic event took place under the P-T condition of 16-18 kbar and 740-770 °C at 1.89-1.88 Ga, with a subsequent granulite facies metamorphism during decompression stage from 18 kbar to 9-12 kbar. Finally, later amphibolite facies metamorphism occurred at 8-10 kbar and 590-610 °C on cooling. The Archean metamorphic zircons that contain inclusions of Grt + Am + Bt + Pl + Qtz + Rt are unzoned grains with dark CL, and they are relatively enriched in HREE. In contrast, the 1.89-1.88 Ga sector or concentric zoned zircons with pale-grey CL include inclusions of Grt + Omp + Ca-Cpx + Am + Bt + Qtz + Rt, and they have the flat pattern of HREE due to the amounts of abundant garnet during the eclogite-facies metamorphism. Whole rock

  4. Estimation of Pressure and Temperature of Intrusive Rocks Crystallisation: A Case Study of Naqadeh, Pasveh and Delkeh Plutons, W Iran

    NASA Astrophysics Data System (ADS)

    Mazhari, Seyed Ali; Bea, Fernando; Amini, Sadraddin; Ghalamghash, Jalil

    The Naqadeh, Pasveh and Delkeh plutons of North Sanandaj-Sirjan Zone, W Iran, are medium to high potassium calc-alkaline intrusive rocks composed of mafic and felsic rocks. Six samples were selected as representative of different units of these plutons for estimation of pressure and temperature of magmatic crystallisation. Al-in-hornblende barometry and crosstie contents of amphiboles suggest <4.5 kbar (1.6-4.5 kbar) pressure for emplacement depth of intrusives. Different thermometer methods indicate various stages of magmatic evolution from near liquidus to sub-solidus temperatures. The highest temperature resulted from orthopyroxene-clinopyroxene solvus thermometry which is more than 1100°C, reflecting initial crystallisation of pyroxene from dioritic magma. Hornblende-clinopyroxene thermometry show another hyper-solidus crystallisation phase during magmatic cooling. The temperature come from hornblende-plagioclase thermometer (695-760°C) probably refer to late stage crystallisation of the magma near solidus condition. Calculated temperature of feldspar thermometry show scatter results (281-1086°C) implies sub-solidus re-equilibration of the feldspar during magmatic and post-magmatic evolution.

  5. Magma flow recorded by magmatic and magnetic fabrics in a shallow granitic pluton: La Gloria Pluton, central Chile

    NASA Astrophysics Data System (ADS)

    Payacán, I. J.; Gutiérrez, F. J.; Gelman, S. E.; Bachmann, O.; Parada, M. A.

    2013-12-01

    To better understand the dynamics of a small, shallow, silicic magma reservoir, magmatic and magnetic (AMS) fabrics are compared in samples obtained from La Gloria Pluton (LGP), a 10 Ma granitic intrusion located in southern Andes. The magnetic fabric of LGP, mainly given by magnetite, is characterized by oblate shapes. Magnetic lineations have a NW trend with subhorizontal dip, following the main pluton elongation, while magnetic foliation planes have dips varying gradually from vertical at the walls to subhorizontal toward the center and the roof of the pluton. On the basis of numerical simulations, magnetic fabric was interpreted to represent the shear record induced by magmatic convection along solidification fronts as the reservoir reached its rheological locking point. Magmatic fabric (mineral orientation) was determined on 12 samples along the pluton. Three mutually orthogonal thin sections were produced for each sample, perpendicular to the AMS tensor axes. Size and orientation of individual crystals were obtained by image analysis. A 2-D tensor for two mineral groups (plagioclase and amphibole+biotitie) was defined in each mineral plane projecting the crystal lengths on the main crystal orientation (given by Bingham statistics). A 3-D magmatic fabric tensor was obtained. In order to compare the magmatic and magnetic fabrics, magmatic anisotropy parameters were defined similar to the AMS tensors. Magmatic fabric and anisotropy parameter values vary depending on the location inside the pluton: (1) Samples located at the borders exhibit vertical foliations and lineations with a NW trend, similar to the magnetic fabric tensors and higher anisotropy values for plagioclase than amphibole+biotite,; (2) samples located at the center of the LGP commonly present subvertical foliations/lineations, which differ from the magnetic fabric, and higher magmatic anisotropy degree values for amphibole+biotite than plagioclase. Based on numerical simulations of the fluid

  6. Anorthosites and alkaline rocks from the deep crust of peninsular India

    NASA Technical Reports Server (NTRS)

    Leelanandam, C.; Ratnakar, J.; Reddy, M. Narsimha

    1988-01-01

    The anorthosite and alkaline rock localities in the Precambrian Shield of Peninsular India were reviewed. There are approximately 50 localities of such rocks, generally restricted to the Eastern Ghats mobile belt. The alkaline plutons are typically confined to the margin of the Eastern Ghats. The anorthosites are all greater than 500 sq km, but many exhibit similarities to one another. It was suggested that the anorthosites are associated with cryptic sutures, and are thought to have originated as a result of ponding of basaltic magmas. An analogy was drawn between the Eastern Ghats belt and the Grenville Province of the Canadian Shield.

  7. Fracture controls on valley persistence: the Cairngorm Granite pluton, Scotland

    NASA Astrophysics Data System (ADS)

    Hall, A. M.; Gillespie, M. R.

    2016-12-01

    Valleys are remarkably persistent features in many different tectonic settings, but the reasons for this persistence are rarely explored. Here, we examine the structural controls on valleys in the Cairngorms Mountains, Scotland, part of the passive margin of the eastern North Atlantic. We consider valleys at three scales: straths, glens and headwater valleys. The structural controls on valleys in and around the Cairngorm Granite pluton were examined on satellite and aerial photographs and by field survey. Topographic lineaments, including valleys, show no consistent orientation with joint sets or with sheets of microgranite and pegmatitic granite. In this granite landscape, jointing is not a first-order control on valley development. Instead, glens and headwater valleys align closely to quartz veins and linear alteration zones (LAZs). LAZs are zones of weakness in the granite pluton in which late-stage hydrothermal alteration and hydro-fracturing have greatly reduced rock mass strength and increased permeability. LAZs, which can be kilometres long and >700 m deep, are the dominant controls on the orientation of valleys in the Cairngorms. LAZs formed in the roof zone of the granite intrusion. Although the Cairngorm pluton was unroofed soon after emplacement, the presence of Old Red Sandstone (ORS) outliers in the terrain to the north and east indicates that the lower relief of the sub-ORS basement surface has been lowered by <500 m. Hence, the valley patterns in and around the Cairngorms have persisted through >1 km of vertical erosion and for 400 Myr. This valley persistence is a combined product of regionally low rates of basement exhumation and of the existence of LAZs in the Cairngorm pluton and sub-parallel Caledonide fractures in the surrounding terrain with depths that exceed 1 km.

  8. Interplay of plutonism and regional deformation in an obliquely convergent arc, southern Coast Belt, British Columbia

    NASA Astrophysics Data System (ADS)

    Brown, E. H.; Talbot, J. L.; McClelland, W. C.; Feltman, J. A.; Lapen, T. J.; Bennett, J. D.; Hettinga, M. A.; Troost, M. L.; Alvarez, K. M.; Calvert, A. T.

    2000-06-01

    The Coast Plutonic Complex is an extensive zone of continental growth that formed along the Mesozoic convergent margin of northwestern North America. The orogeny creating this belt involved terrane accretion and assembly, massive upward transfer and emplacement of sial in the form of batholiths constituting a magmatic arc, and transformation of broad tracts of sedimentary and volcanic rocks into crystalline continental crust, all operating in more or less the same space and time. The mechanisms and interplay of these orogenic processes are well displayed in the Harrison Lake area of the southern Coast Belt, British Columbia. Great structural relief across the area exhibits a present-day architecture defined by thin, thrust-stacked terrane sheets and early concordant pluton sheets folded on a macroscopic scale, all truncated by oblique dextral-reverse faults and overlain by later floored plutons. Construction of this complex began with terrane assembly on orogen-normal thrusts during a lull in plutonism in the Early Cretaceous. Low-grade metamorphism during this event indicates only modest crustal thickening. Subsequent plutons intruded into the assembled terranes appear to be composites of sheets. Early pluton sheets are now steeply dipping due to folding but were likely intruded as horizontal bodies. Large ovoid post folding plutons are mostly subhorizontal floored bodies, at least in part sheeted. These plutons are underlain by Barrovian mineralogic aureoles that indicate downward vertical displacement of 10 km or more during plutonism, suggesting pluton emplacement by vertical inflation. Magmatic fabrics in these bodies, and the discordant relation of plutons to regional structures, preclude emplacement in active fault zones. Penetrative strain aureoles flanking plutons are mostly limited to zones a few hundred meters wide, and regional tectonic structures are widely preserved. Tectonic deformation of the arc is characterized by contraction and strike-slip, not

  9. The comparative effects of chronic consumption of kola nut (Cola nitida) and caffeine diets on locomotor behaviour and body weights in mice.

    PubMed

    Umoren, E B; Osim, E E; Udoh, P B

    2009-06-01

    The comparative effects of chronic [28 days] consumption of kola nut and its active constituent, caffeine diets on locomotor behaviour and body weights in mice were investigated. Thirty adult Swiss white mice [15-30 g body weight], were used for the study. The open field-maze was employed for the evaluation of locomotor behaviour. Mice in the control group [n=10] were fed normal rodent chow, mice in the kola nut-fed group [n=10] were fed kola diet [25 % wt/wt of rodent chow] while those in the caffeine-fed group [n=10] were fed caffeine diet [0.66% wt/wt of rodent chow] for 4 weeks. All animals were allowed free access to clean drinking water. Daily food intake, water intake and body weight change were also measured. Daily food intake in the kola nut and caffeine-fed group of mice was significantly [P<0.001 respectively] lower than the control. There was also a significant [P<0.001] decrease in daily water intake in the caffeine-fed group compared to the control whereas, the apparent decrease of water intake in the kola nut-fed group was not significantly different from the control. Body weight change was also significantly [P<0.001 and P<0.05 respectively] lower in the kola nut and caffeine-fed groups of mice when compared to the control. The frequency of rearing in the open field was significantly [P<0.01] lower in the caffeine-fed group of mice when compared to the control. The frequency of grooming was also significantly [P<0.05] lower in the caffeine-fed group of mice when compared to the control. There was also a significant [P<0.05] decrease in the frequency of light-dark transitions in the light/dark transition box for the caffeine-fed group when compared to the control. The results showed that chronic consumption of kola nut and caffeine diets caused decrease in food intake and body weight. Consumption of caffeine-diet also significantly decreased water intake and locomotor activity. The effect of kola nut-diets on water intake and locomotor activity was

  10. Petrogenesis and tectonic implications of the Early Carboniferous to the Late Permian Barleik plutons in the West Junggar (NW China)

    NASA Astrophysics Data System (ADS)

    Liu, Bo; Han, Bao-Fu; Ren, Rong; Chen, Jia-Fu; Wang, Zeng-Zhen; Zheng, Bo

    2017-02-01

    The Paleozoic accretionary orogenesis and continental crustal growth in Central Asia are thought to have close relationship with the evolution of the Paleo-Asian Ocean (PAO). The well-exposed plutons in the northern Barleik Mountains of the West Junggar region, NW China, may provide essential insights into the evolution of the Junggar Ocean, a branch of the PAO, and mechanism of continental crustal growth. Our work on the Barleik plutons indicates an early suite of 324-320 Ma diorite and a late suite of 314-259 Ma quartz syenite and granitic porphyry. All the plutons are characterized by high-K calc-alkaline to shoshonitic signatures, varying depletion in Nb, Ta, Sr, P, Eu, and Ti, low initial 87Sr/86Sr ratios (0.70241-0.70585), strongly positive εNd(t) values (+ 5.7-+7.7), and young one-stage Nd model ages (390-761 Ma), suggesting that they resulted from different batches of magma that were produced by fractional crystallization of a metasomatized mantle source with minor crustal contamination. The diorite is coeval with the youngest arc magmatic rocks, indicating a subduction-related origin. By contrast, the quartz syenite and granitic porphyry are geochemically similar to A2-type granites, with high Zr, Ga, and FeOT/[FeOT + MgO], and are coeval with the widespread plutons in the West Junggar. This, together with the occurrence of Late Carboniferous fluvial deposits and the lack of < 320 Ma ophiolitic and subduction-related metamorphic lithologies, definitively indicates a post-collisional setting after the closure of the Junggar Ocean. Slab breakoff accompanied by asthenospheric upwelling and basaltic underplating is a possible geodynamic process that is responsible for the post-collisional magmatism and vertical crustal growth in the region. Thus a tectonic switch from subduction to post-collision started at the end of the Early Carboniferous ( 320 Ma), probably as a result of the final closure of the Junggar Ocean.

  11. Reconnaissance study of the Taylor Mountains pluton, southwestern Alaska

    USGS Publications Warehouse

    Hudson, Travis L.; Miller, Marti L.; Klimasauskas, Edward P.; Layer, Paul W.

    2010-01-01

    The Taylor Mountains pluton is a Late Cretaceous to early Tertiary (median age 65 + or ? 2 Ma) epizonal, composite biotite granite stock located about 235 km (145 mi) northeast of Dillingham in southwestern Alaska. This 30 km2 (12 mi2) pluton has sharp and discordant contacts with hornfels that developed in Upper Cretaceous clastic sedimentary rocks of the Kuskokwim Group. The three intrusive phases in the Taylor Mountains pluton, in order of emplacement, are (1) porphyritic granite containing large K-feldspar phenocrysts in a coarse-grained groundmass, (2) porphyritic granite containing large K-feldspar and smaller, but still coarse, plagioclase, quartz, and biotite phenocrysts in a fine-grained groundmass, and (3) fine-grained, leucocratic, equigranular granite. The porphyritic granites have different emplacement histories, but similar compositions; averages are 69.43 percent SiO2, 1.62 percent CaO, 5.23 percent FeO+MgO, 3.11 percent Na2O, and 4.50 percent K2O. The fine-grained, equigranular granite is distinctly felsic compared to porphyritic granite; it averages 75.3 percent SiO2, 0.49 percent CaO, 1.52 percent FeO+MgO, 3.31 percent Na2O, and 4.87 percent K2O. Many trace elements including Ni, Cr, Sc, V, Ba, Sr, Zr, Y, Nb, La, Ce, Th, and Nd are strongly depleted in fine-grained equigranular granite. Trace elements are not highly enriched in any of the granites. Known hydrothermal alteration is limited to one tourmaline-quartz replacement zone in porphyritic granite. Mineral deposits in the Taylor Mountains area are primarily placer gold (plus wolframite, cassiterite, and cinnabar); sources for these likely include scattered veins in hornfels peripheral to the Taylor Mountain pluton. The granite magmas that formed the Taylor Mountains pluton are thought to represent melted continental crust that possibly formed in response to high heat flow in the waning stage of Late Cretaceous subduction beneath interior Alaska.

  12. Nd and Sr isotopic signatures of Mesozoic plutons in northeastern North America

    SciTech Connect

    Foland, K.A.; Jiang-feng, C.; Gilbert, L.A.; Hofmann, A.W.

    1988-08-01

    Nd and Sr initial isotope ratios are reported for 17 Mesozoic plutons of the Monteregian Hills and White Mountain series provinces in northeastern North America. Some variation in the isotopic ratios at most localities is caused by crustal-contamination processes. When the crustal assimilation effects are taken into account, the initial ratios for apparently uncontaminated, mantle-derived parental magmas show only restricted range in /sup 87/Sr//sup 86/Sr (0.7032 to 0.7040) and epsilon/sub Nd/ (T) (+5.4 to +2.3), which are inversely correlated. These ratios characterize alkaline to subalkaline magmas emplaced over more than 400 km/sup 2/ and about 80 m.y. The isotopic and trace-element characteristics are broadly similar to those of many modern ocean-island basalts, specifically the New England Seamounts, suggesting similar time-integrated, lithophile-element-depleted mantle sources. The results are consistent with plume-related mantle sources deeper than the subcontinental mantle.

  13. Raman spectra of probably shock-metamorphosed zircon in structures of the Kola Peninsula

    NASA Astrophysics Data System (ADS)

    Kaulina, Tatiana; Nerovich, Luidmila; Lialina, Luidmila; Il'chenko, Vadim; Bocharov, Vladimir; Kunakkuzin, Evgeny

    2016-04-01

    Zircon crystals were studied by means of Raman spectroscopy from certain structures of the Kola Peninsula, for which impact events are expected according to geological and geochemical data: circular structure in Javrozersky area of the Tanaelv belt and granophyres of Jarva-Varaka layered massif of the Monchegorsky ore district. Zircons from anorthosites of the Javrozersky area showed some features of impact zircons: wavy extinction, blurred "aurora-like" CL image and a presence of additional bands in the Raman spectrum, which may indicate the presence of ZrSiO4 with the scheelite-type structure (reidite) surrounded by zircon material. Zircon crystals of Yavra-Varaka granophyres showed variation of Raman spectra from the core part of crystals with typical zircon Raman pattern to complete absence of spectral bands in the marginal parts and rims. There was also a transition zone between cores and marginal parts of crystals, where the Raman spectrum is "blurred". Such pattern may be associated with the transformation of crystalline zircon to diaplectic glass under the influence of shock metamorphism, since the Jarva-Varaka massif according to geological and geochemical data is compared with the Sudbury structure, for which impact origin is assumed. The work is supported by RSF grant N 16-17-10051.

  14. Mantle plume related Paleozoic riftogenic alkaline magmatism of Mongolia: isotope and geocemical evidence.

    NASA Astrophysics Data System (ADS)

    Yarmolyuk, V.; Savatenkov, V.; Kozlovsky, A.

    2003-04-01

    Paleozoic alkaline magmatic activity in Mongolia associates with series of W-E trending rifts, ranged from south to north. The rifts system was evolved northward at three stages beginning from later Carboniferous-earlier Permian to later Permian. The isotopic-geochemical composition of the rocks from five volcano-plutonic bimodal complexes was studied. These complexes belong to the Gobi-Tien Shan Zone (GTZ) 310-290 Ma and the Gobi-Altai Zone (GAZ) 270 Ma of riftogenic alkaline magmatism. The studied volcano-plutonic complexes are formed by mafic rocks alkaline basalts and felsic rocks alkaline riolites (comendite and pantelerite) with subordinate rocks of intermedial composition (trachidacites, trachiandesites) and associated plutons of alkaline granites. Basaltic rocks of GTZ are characterized by positive eNd(T) values (+4.2 +7.0), 87Sr/86Sr(T) value ranged from 0.7036 to 0.7049, enrichment in Th, LREE, Sr, P, Zr, Hf, Ti and pronounced depletion in Nb and Ta. GTZ felsic rocks have general enrichment in most incompatible trace element (K, Rb, Th, Zr, Hf and REE) and depletion in Nb, Ta, Sr, P, Eu and Ti. The range of eNd(T) of alkaline riolites demonstrates general shift to more positive values (+5.8 +7.3) comparatively to that of basalts. Generally rocks of GAZ and GTZ volcano-plutonic complexes have similar geochemical features. However the GAZ alkaline riolites have more differentiated character (higher silica content, more strong depletion in Ti, Sr and Eu, enrichment in Rb and REE). Furthermore eNd(T) and 87Sr/86Sr(T) values of GAZ basalts demonstrate more wide scatter from +0.2 to +8.1 and from 0.7037 to 0.7054 respectively. Geochemical trends in the trace elements (REE, Y, Th, Nb, Ta) and in Sr-Nd isotope composition suggest that basaltic rocks were derived from OIB-like mantle sourse and underwent contamination during of fraction crystallization by material of subduced oceanic crust (Neoproterozoic ?). Felsic rocks were generated from OIB-like basaltic melt

  15. Evolution of Icelandic Central Volcanoes: Evidence from the Austurhorn Plutonic and Vestmannaeyjar Volcanic Complexes

    DTIC Science & Technology

    1989-09-01

    Austurhorn Plutonic and Vestmannaeyjar Volcanic Complexes by Tanya Helen Furman September 1989 EUTAf:?u~)N STATF󈨠TP A Apc, tved tor pubL’c releae...Di3tribution Unnmited WHOI-89-29 Evolution of Icelandic Central Volcanoes: Evidence from the Austurhorn Plutonic and Vestmannaeyjar Volcanic Complexes by...Furman, 1989. Evolution of Icelandic Central Volcanoes: Evidence from the Austurhorn Plutonic and Vestmannaeyjar Volcanic Complexes. Ph.D. Thesis. MIT

  16. Crystal structure of hydrogen-bearing vuonnemite from the Lovozero alkaline massif

    SciTech Connect

    Rastsvetaeva, R. K. Aksenov, S. M.; Verin, I. A.; Lykova, I. S.

    2011-05-15

    Hydrogen-bearing vuonnemite from the Shkatulka hyperagpaitic pegmatite (the Lovozero alkaline massif, Kola Peninsula) was studied by single-crystal X-ray diffraction. The triclinic unit-cell parameters are as follows: a = 5.4712(1) Angstrom-Sign , b = 7.1626(1) Angstrom-Sign , c = 14.3702(3) Angstrom-Sign , {alpha} = 92.623(2) Degree-Sign , {beta} = 95.135(1) Degree-Sign , {gamma} = 90.440(1) Degree-Sign , sp. gr. P1, R = 3.4%. The Na{sup +} cations and H{sub 2}O molecules are ordered in sites between the packets. The water molecules are hydrogen bonded to the PO{sub 4} tetrahedra.

  17. Origin and evolution of calcalkaline plutons in the Northeast Kingdom batholith, Vermont

    SciTech Connect

    Ayuso, R.A.; Arth, J.G.

    1985-01-01

    Geochemical and petrographic study of five calcalkaline Devonian plutons in the Northeast Kingdom batholith suggests that they were generated from similar sources but evolved differently. The modally homogeneous Willoughby granite (WG) and the Derby granodiorite (DG) are the most aluminous plutons and contain muscovite and biotite (+/- garnet). The West Charleston diorite (WCD) and the Nulhegan granodiorite (NG) are relatively mafic plutons containing pyroxene, hornblende, and biotite. The Echo Pond (EP) has a granodioritic core but is dioritic along its southern margin. Regular variations of major and trace elements are found in NG and in the relatively sodic DG. More erratic chemical variations are found for WG. The more mafic plutons have higher Sr and lower Rb, Nb and Ta compared to the more felsic WG and DG. Rare-earth patterns for all plutons show higher light than heavy rare-earths. However, the more mafic plutons are comparatively less enriched, have smaller Eu anomalies, and tend to have higher contents of heavy rare earths than the WG and DG. The felsic Willoughby pluton is the best candidate for an upper crustal minimum melt. A deeper origin for the more mafic plutons is likely. Significant differences in the rare earths and ferromagnesian elements indicate that the WG, DG, and EP cannot be related by a simple fractionation scheme to the more mafic plutons.

  18. Anodes for alkaline electrolysis

    DOEpatents

    Soloveichik, Grigorii Lev

    2011-02-01

    A method of making an anode for alkaline electrolysis cells includes adsorption of precursor material on a carbonaceous material, conversion of the precursor material to hydroxide form and conversion of precursor material from hydroxide form to oxy-hydroxide form within the alkaline electrolysis cell.

  19. Use of Digital Elevation Models to understand map landforms and history of the magmatism Khibiny Massif (Kola Peninsula, Russia)

    NASA Astrophysics Data System (ADS)

    Chesalova, Elena; Asavin, Alex

    2016-04-01

    most intense free gas emission. The technical possibilities that are offered by Remote Sensing (RS) and Geographical Information Systems (GIS) facilitate the geomorphological investigation of inhospitable and inaccessible mountain areas Digital Elevation Models (DEMs) are valuable tools for approximation of the real world's continuous surface. They allow a visual analysis of the earth's surface morphology, quanti?cation of sediment volumes and the calculation of topographic derivatives such as the slope gradient, slope aspect and pro?le curvature that consume ?eld investigations and optimize time The project has been sponsored by programmm Presidium of RAS P44. Reference Ivanyuk G, Kalashnikov A, Mikhailova J, Konoplyova N, Goryainov P, Yakovenchuk V, Pakhomovsky Y. Self-Organization of the Khibiny Alkaline Massif (Kola Peninsula, Russia). In Earth Sciences, Dr. Imran Ahmad Dar(Ed.), ISBN: 978-953-307-861-8, InTech, Available from: http://www.intechopen.com/books/earth-sciences/self-organization-of-the-khibiny-alkaline -massif -kolapeninsula-russia INTECH Open Access Publisher; 2012, Head7, P.131-156.

  20. Why are plutons dry? Outgassing mechanisms of crustal magmatic bodies

    NASA Astrophysics Data System (ADS)

    parmigiani, andrea; Huber, Christian; Bachmann, Olivier; Leclaire, Sébastien

    2016-04-01

    Magma bodies crystallizing to completion within the crust (i.e., forming plutons) typically undergo significant amounts of second boiling (i.e. cooling and crystallization of dominantly anhydrous minerals lead to volatile saturation and bubble nucleation/growth). The low water content (< 1 wt % H2O) and vanishing residual porosity of most plutons, despite the high volatile concentrations of their magma sources (commonly > 6 wt % H2O for evolved compositions in subduction zones), testify that outgassing from crystalline mushy reservoirs must be an efficient and widespread process. Understanding this outgassing mechanism is key to understand how volatiles are transferred from mantle depths to the surface. From the hydrodynamics point of view, the mass balance of exsolved volatiles in these plutonic bodies is controlled by the difference between the rate of degassing (formation of bubbles by 2nd boiling) and outgassing (transport of gas out of the magma body). In this study, we use pore-scale multiphase modeling to constrain these rates as function of the crystal and volatile contents in the magma. Because second boiling is a slow process, one can consider equilibrium degassing as a valid assumption. Outgassing, on the other end, is controlled by the competition between buoyancy, capillary and viscous forces. Our numerical simulations are used to determine the most efficient setting for gas to escape its magmatic trap. The high viscosity of interstitial melts and capillary forces (due to the non-wetting nature of the gas phase with most of the mineral phases in magmatic systems) strongly limits gas transport until vertically extensive gas channels are generated. We show that channels can readily form in volatile-rich coarse-grained mush zones in the upper crust, and allow efficient outgassing at crystallinities around 50-75 vol%, when millimetric bubbles can still win capillary resistive forces.

  1. Perspectives of humic substances application in remediation of highly heavy metals contaminated soils in Kola Subarctic

    NASA Astrophysics Data System (ADS)

    Tregubova, Polina; Turbaevskaya, Valeria; Zakharenko, Andrey; Kadulin, Maksim; Smirnova, Irina; Stepanov, Andrey; Koptsik, Galina

    2016-04-01

    Northwestern part of Russia, the Kola Peninsula, is one of the most heavy metals (HM) contaminated areas in the northern hemisphere. The main polluters, mining-and-metallurgical integrated works "Pechenganikel" and "Severonikel", are surrounded by heavily damaged barren lands that require remediation. The main contaminating metals are Ni and Cu. Using of exogenous humic substances could be possible effective and cost-efficient solution of HM contamination problem. Rational application of humates (Na-K salts of humic acids) can result in improvement of soil properties, localization of contamination and decreasing bioavailability through binding HM in relatively immobile organic complexes. Our research aim was to evaluate the influence of increasing doses of different origin humates on i) basic properties of contaminated soils; ii) mobility and bioavailability of HMs; iii) vegetation state and chemistry. In summer 2013 a model field experiment was provided in natural conditions of the Kola Peninsula. We investigated the Al-Fe-humus abrazem, soil type that dominates in technogenic barren lands around the "Severonikel" work. These soils are strongly acid: pHH2O was 3.7-4.1; pHKCl was 3.4-4.0. The exchangeable acidity is low (0.8-1.6 cmol(+)/kg) due to the depletion of fine particles and organic matter, being the carriers of exchange positions. The abrazems of barrens had lost organic horizon. 12 sites were created in 1 km from the work. In those sites, except 2 controls, various amendments were added: i) two different by it's origin types of humates: peat-humates and coal-humates, the last were in concentrations 0.5% and 1%; ii) lime; iii) NPK-fertilizer; iv) biomates (organic degradable cover for saving warm and erosion protection). As a test-culture a grass mixture with predominance of Festuca rubra and Festuca ovina was sowed. As a result we concluded that humates of different origin have unequal influence on soil properties and cause decreasing as well as

  2. Emplacement mode of a composite post-collisonal pluton in the Klamath Mountains (California, USA)

    NASA Astrophysics Data System (ADS)

    Machek, M.; Zavada, P.; Spicak, A.

    2011-12-01

    The Klamath Mountains represent an accreationary complex on the northwest California and southwestern Oregon. It consists of four arcuate belts representing terranes of former island archipelago environments that span in age from Paleozoic to Jurrasic and are divided by eastward dipping thrust faults (Snoke and Barnes, 2006). During and after the accretion, the entire thrust sheet was penetrated by numerous plutonic bodies. The Castle Crags pluton was selected for detailed internal fabrics to understand the emplacement mode of post-collisional plutons. Castle Crags pluton that intruded the Eastern Klamath terrane and in particular ultramafic Trinity Complex subterrane is an elliptical NW-SE elongated pluton with 12 km and 7 km in its long and short dimension, respectively. It is a well exposed composite plutonic body with about 1 km vertical crossfall. The pluton is affected by prominent NW-SE trending vertical joints and another less well developed vertical set perpendicular to the first one. The pluton is zoned and consists of three following igneous varieties: 1) marginal fine-grained granodioritic facies with abundant subsolidus shear zones, 2) coarse-grained granodiorite and 3) central, circular in plan-form and about 2 km in diameter, domain of trondhjemite. Numerous miarolitic cavities with macroscopically measurable trends mark the transition between the central trondhjemite and surrounding granodiorite (Vennum, 1980 a,b). Macroscopic foliations, jointing and sampling on the Castle Crags was carried out along the main crest of the pluton and numerous sideway crests and valleys gaining about 70 samples. The internal magmatic foliations and magnetic foliations show a concentric pattern of margin-parallel vertical foliations. The magnetic lineations reveal plunge trends parallel to the margins of the pluton and continuously increasing plunge angles from the margin to the core of the pluton. The zonality and fabric pattern of the pluton can reflect either

  3. Assessment of current exposure levels in different population groups of the Kola Peninsula.

    PubMed

    Travnikova, I G; Shutov, V N; Bruk, G Ya; Balonov, M I; Skuterud, L; Strand, P; Pogorely, Ju A; Burkova, T F

    2002-01-01

    Activity concentrations of 137Cs and 90Sr in samples of vegetation and natural food products collected in the Kola Peninsula in 1998 and 1999 indicate a very slow decrease in contamination levels during the last decade, mainly due to the physical decay of the radionuclides. The activity concentrations of 137Cs in reindeer meat decreased with a half-life of about 9 years. 137Cs in lichen, moss and fungi is significantly higher than in natural vegetation (grasses) and agricultural plants (potatoes). The activity concentrations of 137Cs in reindeer meat were two orders of magnitude higher than those in locally produced beef and pork. Consumption of reindeer meat, fish, mushrooms and berries constituted the main contribution to the internal dose from 137Cs and 90Sr for reindeer-breeders in the Lovozero area. The estimated committed doses due to 137Cs intake in this group were about 10 microSv per month in summer 1998 and 15 microSv per month in winter, 1999. There was good agreement between internal dose estimates based on intake assessment and whole body measurements. The population of Umba settlement, which is not involved in reindeer breeding, received individual committed doses due to 137Cs intake of about 0.5 microSv per month, about a factor of 20 less than the reindeer-breeders in Lovozero. In this case, the main contribution to the internal dose of the general population came from consumption the of 137Cs in mushrooms and forest berries. The contribution of 90Sr to the internal dose varied from 1% to 5% in the different population groups studied.

  4. Alkaline battery operational methodology

    DOEpatents

    Sholklapper, Tal; Gallaway, Joshua; Steingart, Daniel; Ingale, Nilesh; Nyce, Michael

    2016-08-16

    Methods of using specific operational charge and discharge parameters to extend the life of alkaline batteries are disclosed. The methods can be used with any commercial primary or secondary alkaline battery, as well as with newer alkaline battery designs, including batteries with flowing electrolyte. The methods include cycling batteries within a narrow operating voltage window, with minimum and maximum cut-off voltages that are set based on battery characteristics and environmental conditions. The narrow voltage window decreases available capacity but allows the batteries to be cycled for hundreds or thousands of times.

  5. Guidelines to classification and nomenclature of Arabian felsic plutonic rocks

    USGS Publications Warehouse

    Ramsay, C.R.; Stoeser, D.B.; Drysdall, A.R.

    1986-01-01

    Well-defined procedures for classifying the felsic plutonic rocks of the Arabian Shield on the basis of petrographic, chemical and lithostratigraphic criteria and mineral-resource potential have been adopted and developed in the Saudi Arabian Deputy Ministry for Mineral Resources over the past decade. A number of problems with conventional classification schemes have been identified and resolved; others, notably those arising from difficulties in identifying precise mineral compositions, continue to present difficulties. The petrographic nomenclature used is essentially that recommended by the International Union of Geological Sciences. Problems that have arisen include the definition of: (1) rocks with sodic, zoned or perthitic feldspar, (2) trondhjemites, and (3) alkali granites. Chemical classification has been largely based on relative molar amounts of alumina, lime and alkalis, and the use of conventional variation diagrams, but pilot studies utilizing univariate and multivariate statistical techniques have been made. The classification used in Saudi Arabia for stratigraphic purposes is a hierarchy of formation-rank units, suites and super-suites as defined in the Saudi Arabian stratigraphic code. For genetic and petrological studies, a grouping as 'associations' of similar and genetically related lithologies is commonly used. In order to indicate mineral-resource potential, the felsic plutons are classed as common, precursor, specialized or mineralized, in order of increasing exploration significance. ?? 1986.

  6. Guidelines to classification and nomenclature of Arabian felsic plutonic rocks

    NASA Astrophysics Data System (ADS)

    Ramsay, C. R.; Stoeser, D. B.; Drysdall, A. R.

    Well-defined procedures for classifying the felsic plutonic rocks of the Arabian Shield on the basis of petrographic, chemical and lithostratigraphic criteria and mineral-resource potential have been adopted and developed in the Saudi Arabian Deputy Ministry for Mineral Resources over the past decade. A number of problems with conventional classification schemes have been identified and resolved; others, notably those arising from difficulties in identifying precise mineral compositions, continue to present difficulties. The petrographic nomenclature used is essentially that recommended by the International Union of Geological Sciences. Problems that have arisen include the definition of: (1) rocks with sodic, zoned or perthitic feldspar, (2) trondhjemites, and (3) alkali granites. Chemical classification has been largely based on relative molar amounts of alumina, lime and alkalis, and the use of conventional variation diagrams, but pilot studies utilizing univariate and multivariate statistical techniques have been made. The classification used in Saudi Arabia for stratigraphic purposes is a hierarchy of formation-rank units, suites and super-suites as defined in the Saudi Arabian stratigraphic code. For genetic and petrological studies, a grouping as 'associations' of similar and genetically related lithologies is commonly used. In order to indicate mineral-resource potential, the felsic plutons are classed as common, precursor, specialized or mineralized, in order of increasing exploration significance.

  7. Geochronology, geochemistry and origins of the Paleozoic-Triassic plutons in the Langshan area, western Inner Mongolia, China

    NASA Astrophysics Data System (ADS)

    Wang, Zeng-Zhen; Han, Bao-Fu; Feng, Li-Xia; Liu, Bo

    2015-01-01

    The Langshan area is the northeastern part of the Alxa block and adjacent to the Inner Mongolia-Da Hinggan Orogenic Belt (IMDOB) to the north, and geochronological and geochemical studies of the Langshan plutons would be helpful for unraveling the relationship of the magmatism in the Langshan area with that in the IMDOB. Based on zircon U-Pb ages presented in this study and in published papers, five magmatic stages are recognized in Langshan area: Late Silurian (∼418 Ma), Carboniferous (328-304 Ma), Early Permian (294-272 Ma), Late Permian (260-254 Ma) and Middle-Late Triassic (245-227 Ma). The Late Silurian two-mica granite is peraluminous and has a source from ancient continental crust, indicating a collision event. The late Early Carboniferous mafic plutons are subalkaline, show appinitic affinities, and may originate from the subduction-modified continental lithospheric mantle. The late Early Permian granodiorite is weakly peraluminous and high-K calc-alkaline and may be derived from ancient continental crust, while the late Early Permian alkaline gabbro-diorite displays EM I-like Sr-Nd isotopic signatures, indicating an enriched subcontinental lithospheric mantle source. The Late Permian granodiorite is calc-alkaline and peraluminous and may result from the partial melting of ancient lower continental crust, whereas the Late Permian leuconorite belongs to low-K tholeiitic series and has a cumulate origin from an enriched mantle source with the input of juvenile mantle materials. The Paleozoic-Triassic magmatic stages in the Langshan area are consistent with the main magmatic periods in the northern NCC, which are the Late Silurian to Middle Devonian (∼418-386 Ma) and Early Carboniferous to Late Triassic (∼342-211 Ma, with three magmatic stages of Carboniferous, Permian and Triassic). Especially, the Carboniferous to Late Triassic magmatic period in the northern NCC are closely comparable with that in the IMDOB, indicating the two domains might be

  8. Emplacement, rapid burial, and exhumation of 90-Ma plutons in southeastern Alaska

    USGS Publications Warehouse

    Himmelberg, G.R.; Haeussler, P.J.; Brew, D.A.

    2004-01-01

    In southeastern Alaska, granodiorite-tonalite plutons of the Admiralty-Revillagigedo belt intruded the Jurassic-Cretaceous Gravina belt along the eastern side of the Alexander terrane around 90 Ma. These plutons postdate some deformation related to a major contractional event between the previously amalgamated Wrangellia and Alexander terranes and the previously accreted terranes of the North American margin. We studied the aureole mineral assemblages of these plutons near Petersburg, Alaska, determined pressure and temperature of equilibration, and examined structures that developed within and adjacent to these plutons. Parallelism of magmatic and submagmatic fabrics with fabrics in the country rock indicates synchroneity of pluton emplacement with regional deformation and suggests that magma transport to higher crustal levels was assisted by regional deformation. Replacement of andalusite by kyanite or sillimanite indicates crustal thickening soon after pluton emplacement. Regional structural analysis indicates the crustal thickening was accomplished by thrust burial. Thermobarometric analyses indicate the aureoles reached near-peak temperatures of 525 to 635 ??C at pressures of 570 to 630 MPa. Consideration of the rate of thermal decay of the aureoles suggests that burial was rapid and occurred at rates around 5 to 8 mm/year. Structural observations indicate there was contractional deformation before, during, and after emplacement of the 90-Ma plutons. Initial exhumation of the Admiralty-Revillagedo belt in the Petersburg area may have occurred along a thrust west of the pluton belt within the Gravina belt. ?? 2004 NRC Canada.

  9. Plutons and accretionary episodes of the Klamath Mountains, California and Oregon

    USGS Publications Warehouse

    Irwin, William P.; Wooden, Joseph L.

    1999-01-01

    The Klamath Mountains consist of various accreted terranes and include many plutons that range in composition from gabbro to granodiorite. Some of the plutons (preaccretionary plutons) were parts of terranes before the terranes accreted; others (accretionary plutons) intruded during or after the accretion of their host terrane(s). This report attempts to (1) graphically illustrate how the Klamath Mountains grew by the accretion of allochthonous oceanic terranes during early Paleozoic to Cretaceous times, (2) identify the plutons as either preaccretionary or accretionary, and (3) genetically relate the plutonic intrusions to specific accretionary episodes. The eight accretionary episodes portrayed in this report are similar to those shown by Irwin and Mankinen (1998) who briefly described the basis for the timing of the episodes and who illustrated the ~110 degrees of clockwise rotation of the Klamath Mountains since Early Devonian time. Each episode is named for the accreting terrane. In all episodes (Figs. 1-8), the heavy black line represents a fault that separates the accreting oceanic rocks on the left from earlier accreted terranes on the right. The preaccretionary plutons are shown within the accreting oceanic crustal rocks to the left of the heavy black line, and the accretionary plutons in most instances are shown intruding previously accreted terranes to the right. Episodes earlier than the Central Metamorphic episode (Fig. 1), and that may have been important in the formation of the early Paleozoic nucleous of the province (the Eastern Klamath terrane), are not known. The 'Present Time' distribution of the accreted terranes and plutons is shown at a large scale in Figure 9. The schematic vertical section (Fig. 10) depicts the terranes as a stack of horizontal slabs that include or are intruded by vertical plutons. Note that at their base the ~170 Ma preaccretionary plutons of the Western Hayfork subterrane are truncated by the ~164 Ma Salt Creek

  10. A PCR Detection Method for Rapid Identification of Melissococcus pluton in Honeybee Larvae

    PubMed Central

    Govan, V. A.; Brözel, V.; Allsopp, M. H.; Davison, S.

    1998-01-01

    Melissococcus pluton is the causative agent of European foulbrood, a disease of honeybee larvae. This bacterium is particularly difficult to isolate because of its stringent growth requirements and competition from other bacteria. PCR was used selectively to amplify specific rRNA gene sequences of M. pluton from pure culture, from crude cell lysates, and directly from infected bee larvae. The PCR primers were designed from M. pluton 16S rRNA sequence data. The PCR products were visualized by agarose gel electrophoresis and confirmed as originating from M. pluton by sequencing in both directions. Detection was highly specific, and the probes did not hybridize with DNA from other bacterial species tested. This method enabled the rapid and specific detection and identification of M. pluton from pure cultures and infected bee larvae. PMID:9572987

  11. Age and intrusive relations of the Lamarck granodiorite and associated mafic plutons, Sierra Nevada, California

    SciTech Connect

    Joye, J.L.; Bachl, C.A.; Miller, J.S.; Glazner, A.F. . Dept. of Geology); Frost, T.P. ); Coleman, D.S. . Dept. of Earth, Atmospheric and Planetary Sciences)

    1993-04-01

    The compositionally zoned Late Cretaceous Lamarck granodiorite, west of Bishop, hosts numerous mafic intrusions ranging from hornblende gabbro to mafic granodiorite. Frost and Mahood (1987) suggested from field relations that the Lamarck and the associated mafic plutons were co-intrusive. Contact relations between the Lamarck host and the mafic intrusions are variable (sharp to diffuse) and in places suggest commingling. In order to constrain the intrusive relationships between the Lamarck and its associated mafic plutons, the authors have analyzed feldspars from the Mt. Gilbert pluton and the Lamarck granodiorite to see if feldspar compositions in the Mt. Gilbert overlap those in the Lamarck host and determined U-Pb zircon ages for the Mt. Gilbert and Lake Sabrina plutons to see if they have the same age as the Lamarck granodiorite. Feldspars from the Lamarck granodiorite are normally zoned and range compositionally from An[sub 38--32]; those in the Mt. Gilbert diorite are also normally zoned but range compositionally from An[sub 49--41] and do not overlap the Lamarck host. Four to five zircon fractions from each pluton were handpicked and dated using U-Pb methods. The Mt. Gilbert mafic diorite has a concordant age of 92.5 Ma and the Lake Sabrina diorite has a concordant age of 91.5 Ma. Ages for the two plutons overlap within error, but multiple fractions from each suggest that the Lake Sabrina pluton is slightly younger than the Mt. Gilbert pluton. These data and field relationships indicate: (1) plagioclase phenocrysts in the Mt. Gilbert pluton were not derived from the Lamarck granodiorite despite their textural similarity; but (2) the Lamarck granodiorite and its associated mafic plutons are co-intrusive as supported by the close agreement of the ages with the crystallization age obtained by Stern and others for the Lamarck granodiorite.

  12. Melt segregation evidence from a young pluton, Takidani Granodiorite (Japan)

    NASA Astrophysics Data System (ADS)

    Hartung, Eva; Caricchi, Luca; Floess, David; Wallis, Simon; Harayama, Satoru; Chiaradia, Massimo; Kouzmanov, Kalin

    2016-04-01

    We are presenting new petrological data from one of the youngest exposed plutons in the world, the Takidani Granodiorite (Japan), which has been suggested as a source for large volume ignimbrites (> 300km3). Takidani Granodiorite (1.54 Ma ± 0.23 Ma) is located within the active Norikura Volcanic Chain in the Northen Japan Alps and has been previously linked to large andesitic (1.76 Ma ± 0.17 Ma) and rhyolitic eruptions (1.75 Ma ± 0.17 Ma). The pluton is vertically zoned and consists of granites (67 to 68 wt.% SiO2) in the lower section, granodiorites (65 to 66 wt.% SiO2) in the middle section, a chemically more evolved fine-grained porphyritic unit (67 to 71 wt.% SiO2) near the roof and a marginal granodiorite at the roof (67 to 68 wt.% SiO2). The porphyritic texture of the more evolved unit near the roof indicates rapid crystallisation, which could be the result of the late intrusion of this unit at the roof of the magmatic system. However, no sharp contact is found between the underlying granodiorite and the porphyritic unit. Instead, a gradual change in rock fabric, whole-rock chemistry and mineralogy is observed suggesting that melt was extracted from the granodiorite. Electron microprobe analyses of plagioclases show three main crystal populations (Type I, II and III) with distinct anorthite and Fe contents. Type I plagioclase (An30-40) occurs dominantly within the marginal granodiorite at the roof. Type II plagioclase (An40-45) are common in the granodiorite and porphyritic unit. Type III plagioclase (An45-50) is predominantly present in the granite. All plagioclase populations share a common sodic rim (An22) across the different units. Takidani Granodiorite rocks are compared to crystallisation experiments from similar magmatic suites. Emplacement conditions of the Takidani Granodiorite are obtained from the latter as well as barometry, thermometry and hygrometry indicating that magmas were ultimately emplaced at around 200 MPa, 850° C to 875° C and

  13. [Impact of industrial pollution on emission of carbon dioxide by soils in the Kola Subarctic Region].

    PubMed

    Koptsik, G N; Kadulin, M S; Zakharova, A I

    2015-01-01

    Soil emission of carbon dioxide, the key component of carbon cycle and the characteristic of soil biological activity, has been studied in background and polluted ecosystems in the Kola subarctic, the large industrial region of Russia. Long-term air pollution by emissions of "Pechenganikel" smelter, the largest source of sulphur dioxide and heavy metals in Northern Europe, has caused the technogenic digression of forest ecosystems. As a result of the digression, the tree layer was destructed, the number of plant species was diminished, the activity of soil biota was weakened, the soils were polluted and exhausted, biogeochemical cycles of elements were disturbed and productivity of ecosystems shrunk. Field investigations revealed the decrease of the in.situ soil respiration in average from 190-230 mg C-CO2/m2 x per h in background pine forests to 130-160, 100, and 20 mg C-CO2/m2.per h at the stages of pine defoliation, sparse pine forest and technogenic barrens of the technogenic succession, respectively. The soil respira- tion in birch forests was more intense than in pine forests and tended to decrease from about 290 mg C-CO2/m2 x per h in background forests to 210-220 and 170-190 mg C-CO2/m2 x per h in defoliating forests and technogenic sparse forests, respectively. Due to high spatial variability of soil respiration in both pine and birch forests significant differences from the background level were found only in technogenic sparse forests and barrens. Soil respiration represents total production of carbon dioxide by plant roots and soil microorganisms. The decrease in share of root respiration in the total soil respiration with the rise of pollution from 38-57% in background forests up to zero in technogenic barrens has been revealed for the first time for this region. This indicates that plants seem to be more sensitive to pollution as compared to relatively resistant microorganisms. Soil respiration and the contribution of roots to the total respiration

  14. Efficacy of Garcinia kola 0.5% Aqueous Eye Drops in Patients with Primary Open-Angle Glaucoma or Ocular Hypertension

    PubMed Central

    Adefule-Ositelu, Adebukunola O.; Adegbehingbe, Bernice O.; Adefule, Adebayo K.; Adegbehingbe, Olayinka O.; Samaila, Elsie; Oladigbolu, Kehinde

    2010-01-01

    Purpose: To evaluate the intraocular pressure (IOP) lowering efficacy of Garcinia kola 0.5% aqueous solution eye drops in patients with newly diagnosed primary open-angle glaucoma or ocular hypertension (POAG/OH). Materials and Methods: A randomized, double-masked, multicenter, active-controlled prospective study. Patients who met the inclusion criteria were randomly assigned in equal numbers to receive Timolol 0.5% eye drops as a control medication (A = Group 1 eyes) or Garcinia kola 0.5% eye drops as the study medication (B = Group 2 eyes). All drops were instilled at 6 am and 6 pm daily. Goldman applanation tonometry was performed at 9 am, 12 pm and 3 pm at baseline, week-6, week-12 and week-24 visits. Voluntary and actively elicited reports of adverse events were documented. The mean change in IOP over 24 weeks was the primary outcome measure. Both groups were compared for statistically significant differences at all visits. A P < 0.05 was considered statistically significant. Results: A total of 178 patients were randomly assigned to G. kola and Timolol groups. At baseline there were no differences in mean IOP between groups, based on age, sex, or diagnosis. At the end of the study period (24th week), the mean (± SD) reduction in IOP was 12.93 ± 2.3 mmHg (47.8% ± 0.8% reduction) in G. Kola group and 13.09 ± 2.8 mm Hg (48.2% ± 1.03% reduction) in the Timolol group (P > 0.05). Adverse events were mild in nature with no statistically significant differences between groups (P > 0.05). Conclusions: Garcinia kola ophthalmic solution significantly reduces IOP as compared to baseline. The IOP lowering effect of both treatments was equivalent. PMID:20543944

  15. Petrological imaging of an active pluton beneath Cerro Uturuncu, Bolivia

    NASA Astrophysics Data System (ADS)

    Muir, Duncan D.; Blundy, Jon D.; Hutchinson, Michael C.; Rust, Alison C.

    2014-03-01

    Uturuncu is a dormant volcano in the Altiplano of SW Bolivia. A present day ~70 km diameter interferometric synthetic aperture radar (InSAR) anomaly roughly centred on Uturuncu's edifice is believed to be a result of magma intrusion into an active crustal pluton. Past activity at the volcano, spanning 0.89 to 0.27 Ma, is exclusively effusive and almost all lavas and domes are dacitic with phenocrysts of plagioclase, orthopyroxene, biotite, ilmenite and Ti-magnetite plus or minus quartz, and microlites of plagioclase and orthopyroxene set in rhyolitic groundmass glass. Plagioclase-hosted melt inclusions (MI) are rhyolitic with major element compositions that are similar to groundmass glasses. H2O concentrations plotted versus incompatible elements for individual samples describe a trend typical of near-isobaric, volatile-saturated crystallisation. At 870 °C, the average magma temperature calculated from Fe-Ti oxides, the average H2O of 3.2 ± 0.7 wt% and CO2 typically <160 ppm equate to MI trapping pressures of 50-120 MPa, approximately 2-4.5 km below surface. Such shallow storage precludes the role of dacite magma emplacement into pre-eruptive storage regions as being the cause of the observed InSAR anomaly. Storage pressures, whole-rock (WR) chemistry and phase assemblage are remarkably consistent across the eruptive history of the volcano, although magmatic temperatures calculated from Fe-Ti oxide geothermometry, zircon saturation thermometry using MI and orthopyroxene-melt thermometry range from 760 to 925 °C at NNO ± 1 log. This large temperature range is similar to that of saturation temperatures of observed phases in experimental data on Uturuncu dacites. The variation in calculated temperatures is attributed to piecemeal construction of the active pluton by successive inputs of new magma into a growing volume of plutonic mush. Fluctuating temperatures within the mush can account for sieve-textured cores and complex zoning in plagioclase phenocrysts

  16. Cretaceous plutonic rocks in the Donner Lake-Cisco Grove area, northern Sierra Nevada, California

    USGS Publications Warehouse

    Kulow, Matthew J.; Hanson, Richard E.; Girty, Gary H.; Girty, Melissa S.; Harwood, David S.

    1998-01-01

    The northernmost occurrences of extensive, glaciated exposures of the Sierra Nevada batholith occur in the Donner Lake-Cisco Grove area of the northern Sierra Nevada. The plutonic rocks in this area, which are termed here the Castle Valley plutonic assemblage, crop out over an area of 225 km2 and for the most part are shown as a single undifferentiated mass on previously published geological maps. In the present work, the plutonic assemblage is divided into eight separate intrusive units or lithodemes, two of which each consist of two separate plutons. Compositions are dominantly granodiorite and tonalite, but diorite and granite form small plutons in places. Spectacular examples of comb layering and orbicular texture occur in the diorites. U-Pb zircon ages have been obtained for all but one of the main units and range from ~120 to 114 Ma, indicating that the entire assemblage was emplaced in a narrow time frame in the Early Cretaceous. This is consistent with abundant field evidence that many of the individual phases were intruded penecontemporaneously. The timing of emplacement correlates with onset of major Cretaceous plutonism in the main part of the Sierra Nevada batholith farther south. The emplacement ages also are similar to isotopic ages for gold-quartz mineralization in the Sierran foothills west of the study area, suggesting a direct genetic relationship between the voluminous Early Cretaceous plutonism and hydrothermal gold mineralization.

  17. Plutonism, oblique subduction, and continental growth: An example from the Mesozoic of California

    SciTech Connect

    Glazner, A.F. )

    1991-08-01

    Major episodes of Mesozoic plutonism in California correlate with periods of oblique subduction and trench-parallel transport of western California along intrabatholithic faults. Major episodes of plutonism occurred in the Late Jurassic, during left-oblique convergence, and in the mid-Cretaceous, during right-oblique convergence. In contrast, a conspicuous lull in plutonism (but continuation of volcanism) in the earliest Cretaceous coincides with a time when the North America-Farallon convergence vector, although large in magnitude, was oriented perpendicular to the trench. This correlation suggests that plutonism is facilitated by strike-slip faulting within the batholithic belt; one explanation, which helps to solve the plutonic room problem, is that plutons are passively emplaced at releasing bends in the strike-slip faults, and volume is conserved by thrusting at the trench. If this correlation is generally applicable, then it implies that mid-crustal plutonism is limited beneath areas in which the convergence vector is subperpendicular to the trench. Continental growth in such areas may occur dominantly by volcanism.

  18. Ar/Ar age data of muscovite from the Keivy Terrane (central Kola Peninsula, arctic European Russia) imply a prolonged fluid-assisted recrystallisation

    NASA Astrophysics Data System (ADS)

    de Jong, K.; Ruffet, G.; Marker, M.

    2012-04-01

    Single grain muscovite 40Ar/39Ar age data from metasediments of the Keivy Terrane point to a prolonged recrystallisation, and imply that the younger age set in metamorphic terranes with a long history cannot always be simply interpreted as due to late and slow cooling. The Keivy terrane is an element of the Palaeoproterozoic Lapland-Kola collisional belt developed along the northern margin of the Fennoscandian (Baltic) Shield. It comprises a lower series of late Archaean meta-volcanic rocks, intruded by earliest Palaeoproterozoic alkali granites that are covered by strongly deformed quartz-rich kyanite-staurolite-garnet-micaschists of the Keivy unit that have yielded magmatic zircons as young as ~2.35 Ga, which were derived from the substratum's alkaline granite. 40Ar/39Ar step-heating dating with a defocussed laser beam of muscovite grains from seven metasediments of the Keivy unit yielded saddle-shaped age spectra in most experiments. In five out of seven cases the base of the saddle corresponded to a plateau age in the range of 1667 to 1593 Ma (60-90% of the gas release; 1 sigma errors: 1.0-1.2 Ma). We do not simply interpret these 40Ar/39Ar ages in the classical way as due to cooling, because the saddle shape of the spectra enables a more complete and detailed interpretation. Saddle-shaped age spectra may result from the presence of different argon reservoirs in partially recrystallised and chemically distinct micas that degas over a different energy interval: a primary, not recrystallised or inherited domain (low and high temperature steps) and a newly formed or recrystallised one (saddle minimum in the intermediate steps). The younger subdomains formed by growth or recrystallisation could characterise the last isotopic record during an extended (re)crystallisation history. It is striking that 1612 and 1615 Ma saddle minimum ages in two samples correspond to a plateau age of 1612 Ma in another sample. Also elevated high and/or low temperature apparent ages of

  19. Zircon U-Pb age, Lu-Hf isotope, mineral chemistry and geochemistry of Sundamalai peralkaline pluton from the Salem Block, southern India: Implications for Cryogenian adakite-like magmatism in an aborted-rift

    NASA Astrophysics Data System (ADS)

    Renjith, M. L.; Santosh, M.; Li, Tang; Satyanarayanan, M.; Korakoppa, M. M.; Tsunogae, T.; Subba Rao, D. V.; Kesav Krishna, A.; Nirmal Charan, S.

    2016-01-01

    The Sundamalai peralkaline pluton is one among the Cryogenian alkaline plutons occurring in the Dharmapuri Rift Zone (DRZ) of the Salem Block in the Southern Granulite Terrane (SGT) of India. Here we present zircon U-Pb age and Lu-Hf isotopic composition, mineral chemistry and geochemistry of the pluton to explore the petrogenesis and geodynamic implications. Systematic modal variation of orthoclase, Na-plagioclase, Ca-amphibole (ferro-edenite and hastingsite) and quartz developed quartz-monzonite and granite litho units in the Sundamalai pluton. Thermometry based on amphibole-plagioclase pair suggests that the pluton was emplaced and solidified at around 4.6 kbar pressure with crystallization of the major phases between 748 and 661 °C. Estimated saturation temperature of zircon (712-698 °C) is also well within this range. However, apatite saturation occurred at higher temperatures between 835 and 870 °C, in contrast with monazite saturation (718-613 °C) that continued up to the late stage of crystallization. Estimated oxygen fugacity values (log fO2: -14 to -17) indicate high oxidation state for the magma that stabilized titanite and magnetite. The magmatic zircons from Sundamalai pluton yielded a weighted mean 206Pb/238U age of 832.6 ± 3.2 Ma. Geochemically, the Sundamalai rocks are high-K to shoshonitic, persodic (Na2O/K2O ratio > 1), silica-saturated (SiO2:65-72 wt.%), and peralkaline in composition (aluminum saturation index, ASI < 1; Alkalinity index, AI < 0). The initial magma was mildly metaluminous which evolved to strongly peralkaline as result of fractional crystallization (plagioclase effect) controlled differentiation between quartz-monzonite and granite. Both rock types have high content of Na2O (5.1-6.3 wt.%), Ba (350-2589 ppm) and Sr (264-1036 ppm); low content of Y (8.7-17 ppm) and Yb (0.96-1.69 ppm); elevated ratios of La/Yb (11-46) and Sr/Y (46-69) and are depleted in Ti, with a positive Sr anomaly suggesting an adakite-like composition and

  20. [Occupational morbidity among miners engaged into contemporary method of extracting copper-nickel ores in Kola Transpolar regions].

    PubMed

    Siurin, S A; Shilov, V V

    2014-01-01

    The risks for developing occupational pathology and its specific features were studied in 358 Kola Transpolar copper-nickel miners who were diagnosed with 722 cases of occupational diseases (OD) in the years 1990-2013. The highest risk for developing OD, which are dominated by the diseases of the musculoskeletal system, has been found in tunnellers (OR = 12,8) and operators of drilling rigs (OR = 10,4). A significant increase in the risk of OD has been established in miners with length of service at 11-15 years and over 25 years. The conclusion is made about the need to improve the technical, medical and organizational measures targetted at preventing health problems in this group of workers.

  1. Changes in the molecular hydrogen concentration in an underground mine (Lovozero rare-metal deposit, Kola Peninsula)

    NASA Astrophysics Data System (ADS)

    Nivin, V. A.; Pukha, V. V.; Lovchikov, A. V.; Rakhimov, R. G.

    2016-12-01

    Long-term monitoring yielded significant variations in the hydrogen volume concentration in an underground mine at the developed Lovozero rare-metal deposit of the nepheline-syenite massif in the Kola Peninsula. The deposit is characterized by emission of natural combustible gases. Basic structural elements of the time series obtained include relatively stable and long ranges of low background concentrations, low- and medium-amplitude rises of various duration, and short-term, commonly high-amplitude peaks. The range structure is characterized by a general decreasing trend, a low intensity random noise component, and seasonal and off-seasonal periodic and other cyclical components. Periodic circadian and semidiurnal harmonics are the most pronounced.

  2. Effectiveness of Gotu Kola Extract 750 mg and 1000 mg Compared with Folic Acid 3 mg in Improving Vascular Cognitive Impairment after Stroke

    PubMed Central

    Wibowo, Samekto

    2016-01-01

    This study aimed to determine the effectiveness of gotu kola (Centella asiatica) in improving cognitive function in patients with vascular cognitive impairment (VCI). This study uses a quasi-experimental design. Subjects in this study were patients with poststroke cognitive impairment who were treated at two hospitals in Yogyakarta, Indonesia. The number of subjects was 48: 17 subjects were treated with 1000 mg/day of gotu kola extract, 17 subjects treated with 750 mg/day of gotu kola extract, and 14 subjects treated with 3 mg/day of folic acid for 6 weeks. A Montreal Cognitive Assessment-Indonesian version (MoCA-Ina) was conducted at the beginning of treatment and after 6 weeks of therapy. It was found that all trials effectively improved poststroke VCI based on MoCA-Ina scores over the course of the study. There is no significant difference in ΔMoCA-Ina (score at the 6th week of treatment − score at the beginning) mean score among the three groups, indicating that gotu kola is as effective as folic acid in improving poststroke VCI. Gotu kola was shown to be more effective than folic acid in improving memory domain. This study suggested that gotu kola extract is effective in improving cognitive function after stroke. PMID:27340413

  3. Alkaline flooding injection strategy

    SciTech Connect

    French, T.R.; Josephson, C.B.

    1992-03-01

    The objective of this project is to improved alkali-surfactant flooding methods, and this includes determining the proper design of injection strategy. Several different injection strategies have been used or suggested for recovering heavy oils with surfactant-enhanced alkaline flooding methods. Oil recovery was compared for four different injection strategies: (1) surfactant followed by polymer, (2) surfactant followed by alkaline polymer, (3) alkaline surfactant followed by polymer, and (4) alkali, surfactant, and polymer mixed in a single formulation. The effect of alkaline preflush was also studied under two different conditions. All of the oil recovery experiments were conducted under optimal conditions with a viscous, non-acidic oil from Hepler (KS) oil field. The coreflood experiments were conducted with Berea sandstone cores since field core was not available in sufficient quantity for coreflood tests. The Tucker sand of Hepler field is a Class I fluvial dominated deltaic reservoir, as classified by the Department of Energy, which has been selected as the site of a DOE-sponsored field pilot test.

  4. Platinum-Group Element Mineralization in the Fedorovatundra layered intrusion, Kola Peninsula, Russia

    NASA Astrophysics Data System (ADS)

    Groshev, Nikolay; Subbotin, Victor; Korchagin, Alexey

    2016-04-01

    The 2526 to 2485 Ma Fedorovatundra layered mafic intrusion in the central part of the Kola Peninsula, Russia, is the western massif of the Fedorova-Pana Complex (2526-2446 Ma), which is situated along the northern contact of the Early Proterozoic Imandra-Varzuga rift and Archean granite gneiss. The Fedorovatundra intrusion of approximately 4 km thick has two major parts: (1) located at the bottom of the intrusion Taxitic series (10 to 900 m) and composing the main volume of the massif Layered series (4000 m). The Taxitic series is distinctive, due to its predominant vary-textured often quartz-saturated norites and gabbronorites (with fewer amounts of leucogabbro, melanorite and Ol-gabbronorite) and abundant pyroxenite, less harzburgite xenoliths. Medium to coarse-grained mottled or massive leucocratic gabbronorite and leucogabbro prevails in the Layered series with mesocratic gabbronorite, pyroxenite and troctolite as subordinate rocks. Depending on its localization, geochemical features, mineral composition and economic value platinum-group element (PGE) mineralization of the Fedorovatundra intrusion is divided into 'marginal' (basal, contact) and 'reef' types. 'Marginal' type of mineralization is presented by irregular disseminated interstitial sulfides (1-2 vol. %) of pentlandite-pyrrhotite-chalcopyrite association (Cu/Ni = 1.8) in the Taxitic series. Less sulfides occur as uniformly disseminated aggregates, thin massive lenses and nests. PGE and base metals are concentrated in several ore horizons of 3.5 km long complicated structure. Thickness of ore horizons varies generally within 10-150 m, but it can rise up to 280 m in bulges. In the most common ore-bearing rock (taxitic gabbronorite) average Pt + Pd content is 1.6 ppm (Pd/Pt 4.5). The pyroxenite xenoliths occurring within the Taxitic series are practically barren of sulfide and can dilute higher PGE and base metal grades in the gabbronorite matrix. 'Marginal' mineralization of the Fedorovotundrovsky

  5. Volcanic-plutonic parity and the differentiation of the continental crust.

    PubMed

    Keller, C Brenhin; Schoene, Blair; Barboni, Melanie; Samperton, Kyle M; Husson, Jon M

    2015-07-16

    The continental crust is central to the biological and geological history of Earth. However, crustal heterogeneity has prevented a thorough geochemical comparison of its primary igneous building blocks-volcanic and plutonic rocks-and the processes by which they differentiate to felsic compositions. Our analysis of a comprehensive global data set of volcanic and plutonic whole-rock geochemistry shows that differentiation trends from primitive basaltic to felsic compositions for volcanic versus plutonic samples are generally indistinguishable in subduction-zone settings, but are divergent in continental rifts. Offsets in major- and trace-element differentiation patterns in rift settings suggest higher water content in plutonic magmas and reduced eruptibility of hydrous silicate magmas relative to dry rift volcanics. In both tectonic settings, our results indicate that fractional crystallization, rather than crustal melting, is predominantly responsible for the production of intermediate and felsic magmas, emphasizing the role of mafic cumulates as a residue of crustal differentiation.

  6. Iron variation within a granitic pluton as determined by near-infrared reflectance

    NASA Technical Reports Server (NTRS)

    Baird, A. K.

    1984-01-01

    One-hundred fifty-one previously chemically analyzed samples of tonalite from the Lakeview Mountains pluton, southern California batholith, were analyzed for their iron content using near-infrared spectrophotometry. Compared to the earlier analyses of the same sample set by X-ray fluorescence spectrography, the infrared data have higher analytical variance but clearly define patterns of compositional zonation in the pluton which are closely similar to those patterns obtained from X-ray data; petrogenetic interpretations for the pluton would be the same from either data set. Infrared spectral data can be obtained directly in the field with relatively simple instruments and field measurements can be made to average local heterogeneities that often mask significant plutonic variations.

  7. Petrology and Geochemistry of Neoproterozoic Arc Plutons Beneath the Atlantic Coastal Plain, SRS, SC

    SciTech Connect

    Maryak, M.

    1998-10-21

    In this report is presented first a brief review of the regional geologic setting of the Savannah River Site, descriptions of the plutonic rock units sampled here, whole rock geochemical data on the plutonic igneous rocks, and finally, a discussion of how the crystalline basement rocks of the Savannah River Site formed and how they may correlate with other terranes exposed in the Piedmont of the Carolinas, Georgia, and Virginia.

  8. Tertiary epizonal plutonic rocks of the Selway-Bitterroot Wilderness, Idaho County, Idaho

    SciTech Connect

    Motzer, W.E.

    1996-01-01

    Geologic mapping in the Selway-Bitterroot Wilderness identified approximately 731 kmS of epizonal plutonic granitic rocks within the Bitterroot lobe of the Idaho batholith. From north to south, the intrusions are the Rock Lake Creek stock and the Whistling Pig, Running Creek, Bad Luck and Painted Rocks plutons. The stock and plutons consist of medium- to coarse-grained biotite and hornblende-biotite syenorgranite to monzogranite and quartz syenite capped by fine-grained biotite leucogranite. These rocks are intruded by late-synplutonic leucogranite dikes and post plutonic porphyritic rhyolite to rhyodacite and basalt dikes. The medium-grained granitic rocks are high in SiO2, K2O, Na2O, Ga, Th, U, W and Zr, but low in Al7O3, CaO, MgO, Cr, Ni, Co and V. Most of the granites are peraluminous. Rare-earth element (REE) plots (rock sample/chondrite) show enrichment in light REE over heavy REE with strong EU depletions. K-Ar biotite radiometric age determinations for medium-grained granites in all of the plutons range from approximately 51 Ma (Whistling Pig pluton) to 43.7 Ma (Painted Rocks pluton). Petrogenetic studies suggest that the plutons were rapidly emplaced to within 3.0 km of the paleosurface. The types, textures and color of the rocks result from devolatilization of the crystallizing melt and very low-grade hydrothermal alteration. The fluorine-rich melts are the fractionated with accumulate residue; they are considered to be anorogenic (A-type) granites intruded into the center of a metamorphic core complex.

  9. Uranium-Lead Zircon Ages and Sr, Nd, and Pb Isotope Geochemistry of Selected Plutonic Rocks from Western Idaho

    USGS Publications Warehouse

    Unruh, Daniel M.; Lund, Karen; Kuntz, Mel A.; Snee, Lawrence W.

    2008-01-01

    Across the Salmon River suture in western Idaho, where allochthonous Permian to Cretaceous oceanic rocks are juxtaposed against Proterozoic North American rocks, a wide variety of plutonic rocks are exposed. Available data indicate much variation in composition, source, and structural state of these plutons. The plutonic rocks were long described as the western border zone of the Cretaceous Idaho batholith but limited pre-existing age data indicate more complicated origins. Because the affinity and age of the plutonic rocks cannot be reliably determined from field relations, TIMS U-Pb dating in conjunction with Sr, Nd, and Pb isotopic studies of selected plutons across the suture in western Idaho were undertaken. The data indicate three general groups of plutons including (1) those that intruded the island arc terranes during the Triassic and Jurassic, those that intruded near the western edge of oceanic rocks along the suture in the Early Cretaceous, and the plutons of the Idaho batholith that intruded Proterozoic North American rocks in the Late Cretaceous. Plutons that intruded Proterozoic North American rocks commonly include xenocrystic zircons and in several cases, ages could not be determined. The least radiogenic Sr and most radiogenic Nd are found among the Blue Mountains superterrane island arc samples. Suture-zone plutons have isotopic characteristics that span the range between Idaho batholith and island arc samples but mostly follow island arc signatures. Plutons of the Idaho batholith have the most radiogenic initial Pb and Sr ratios and the least radiogenic Nd of the samples analyzed.

  10. Possible cryptic tectono-magnetic fabrics in `post-tectonic' granitoid plutons of the Canadian Shield

    NASA Astrophysics Data System (ADS)

    Borradaile, Graham J.; Kehlenbeck, Manfred M.

    1996-01-01

    Two late Archean granitic plutons forcefully intruded and thermally metamorphosed Archean schists. Feldspar magacrysts aligned concentrically with the margins during inflation. Substantial tectonic deformation never affected the plutons. Nevertheless, both plutons show the same, consistently oriented, cryptic magnetic fabric revealed by anisotropy of low field susceptibility (AMS) from 134 samples. They have an NE-SW vertical magnetic foliation and a magnetic lineation trending 060/15. Eigenvalues of the orientation distribution of principal susceptibilities show that the magnetic fabrics have almost identical strengths, orientations and symmetry in both plutons. We propose a post-magmatic reactivation of the earlier regional tectonic shortening. This imparted a 'cryptic tectonic' magnetic fabric on the plutons that overprinted the magmatic AMS fabric in most outcrops. The plutons' AMS fabrics are subparallel to the much older schistosity of the country rocks. Because multidomain magnetite provides > 99% of the low field susceptibility of the rocks, it controls the AMS. However, we see no alignment of the magnetite grains. Thus, magnetic anisotropy may be due to stress alignment of intragranular domain walls and not controlled by grain shape, as usually assumed for magnetite.

  11. Isotopic constraints on the petrogenesis of jurassic plutons, Southeastern California

    USGS Publications Warehouse

    Mayo, D.P.; Anderson, J.L.; Wooden, J.L.

    1998-01-01

    The 165 Ma Eagle Mountain intrusion is a heterogeneous, enclave-bearing, metaluminous remnant of the Cordilleran Jurassic arc that cuts regionally metamorphosed pre-Mesozoic rocks in the southeastern Mojave Desert of California. The main phase of the intrusion consists of granodiorite to tonalite host facies, diorite mixed facies, and homogeneous monzogranite facies. The host facies contains microdiorite enclaves interpreted as intermingled masses of mafic magma. Late-phase leucogranite stocks cut the main phase. Mineral equilibria indicate emplacement at ???6.5 km depth, with solidus temperatures ranging from 760??C for diorite to 700??C for felsic granodiorite. Although uniform radiogenic-isotope compositions (Sri = 0.7085, ???Ndi = -9.4) suggest derivation from a single source, no known source has the composition required. A hybrid source is proposed, consisting of various proportions of juvenile mantle and recycled lower crust. Calculations indicate that the source of the Eagle Mountain intrusion comprised >60% juvenile mantle and <40% recycled crust. On the basis of their isotopic compositions, other mafic Jurassic plutons in the region were derived from sources containing different proportions of mantle and crustal components.

  12. Alkaline quinone flow battery.

    PubMed

    Lin, Kaixiang; Chen, Qing; Gerhardt, Michael R; Tong, Liuchuan; Kim, Sang Bok; Eisenach, Louise; Valle, Alvaro W; Hardee, David; Gordon, Roy G; Aziz, Michael J; Marshak, Michael P

    2015-09-25

    Storage of photovoltaic and wind electricity in batteries could solve the mismatch problem between the intermittent supply of these renewable resources and variable demand. Flow batteries permit more economical long-duration discharge than solid-electrode batteries by using liquid electrolytes stored outside of the battery. We report an alkaline flow battery based on redox-active organic molecules that are composed entirely of Earth-abundant elements and are nontoxic, nonflammable, and safe for use in residential and commercial environments. The battery operates efficiently with high power density near room temperature. These results demonstrate the stability and performance of redox-active organic molecules in alkaline flow batteries, potentially enabling cost-effective stationary storage of renewable energy.

  13. Advanced alkaline water electrolysis

    NASA Astrophysics Data System (ADS)

    Wakabayashi, N.; Torikai, E.; Kawami, Y.; Takenaka, H.

    Results are presented of experimental studies of possible separators and electrodes for use in advanced, high-temperature, high-pressure alkaline water electrolyzers. Material evaluations in alkaline water electrolyzers at temperatures from 100 to 120 C have shown a new type polytetrafluoroethylene membrane impregnated with potassium titanate to be the most promising when the separator is prepared by the hydrothermal treatment of a porous PFTE membrane impregnated with hydrated titanium oxide. Measurements of cell voltages in 30% KOH at current densities from 5 to 100 A/sq dm at temperatures up to 120 C with nickel electrodes of various structures have shown the foamed nickel electrode, with an average pore size of 1-1.5 mm, to have the best performance. When the foamed nickel is coated by fine powdered nickel, carbonyl nickel or Raney nickel to increase electrode surface areas, even lower cell voltages were found, indicating better performance.

  14. An unusually rich scuttle fly fauna (Diptera, Phoridae) from north of the Arctic Circle in the Kola Peninsula, N. W. Russia.

    PubMed

    Disney, R H L

    2013-01-01

    64 species of Phoridae, in 6 genera, are reported from the Kola Peninsula, north of the Arctic Circle. The new species Megaselia elenae and Megaselia kozlovi are described. 33 species of Megaselia, only known from females, are given code numbers. Keys to the species of all the females of Megaselia and Phora are provided; and also a key to the males European Megaselia species with a notopleural cleft.

  15. The results of marine electromagnetic sounding with a high-power remote source in the Kola Bay in the Barents Sea

    NASA Astrophysics Data System (ADS)

    Grigoriev, V. F.; Korotaev, S. M.; Kruglyakov, M. S.; Orekhova, D. A.; Popova, I. V.; Tereshchenko, E. D.; Tereshchenko, P. E.; Schors, Yu. G.

    2013-05-01

    The first Russian six-component seafloor electromagnetic (EM) receivers were tested in an experiment carried out in Kola Bay in the Barents Sea. The signals transmitted by a remote high-power ELF source at several frequencies in the decahertz range were recorded by six receivers deployed on the seafloor along the profile crossing the Kola Bay. Although not all the stations successfully recorded all the six components due to technical failures, the quality of the data overall is quite suitable for interpretation. The interpretation was carried out by the three-dimensional (3D) modeling of an electromagnetic field with neural network inversion. The a priori geoelectrical model of Kola Bay, which was reconstructed by generalizing the previous geological and geophysical data, including the data of the ground magnetotelluric sounding and magnetovariational profiling, provided the EM fields that are far from those measured in the experiment. However, by a step-by-step modification of the initial model, we achieved quite a satisfactory fit. The resulting model provides the basis for introducing the corrections into the previous notions concerning the regional geological and geophysical structure of the region and particularly the features associated with fault tectonics.

  16. INSTALLATION OF A POST-ACCIDENT CONFINEMENT HIGH-LEVEL RADIATION MONITORING SYSTEM IN THE KOLA NUCLEAR POWER STATION (UNIT 2) IN RUSSIA

    SciTech Connect

    GREENE,G.A.; GUPPY,J.G.

    1998-09-01

    This is the final report on the INSP project entitled, ``Post-Accident Confinement High-Level Radiation Monitoring System'' conducted by BNL under the authorization of Project Work Plan WBS 1.2.2.6 (Attachment 1). This project was initiated in February 1993 to assist the Russians in reducing risks associated with the continued operation of older Soviet-designed nuclear power plants, specifically the Kola VVER-440/230 Unit 2, through improved accident detection capability, specifically by the installation of a dual train high-level radiation detection system in the confinement of Unit 2 of the Kola NPP. The major technical objective of this project was to provide, install and make operational the necessary hardware inside the confinement of the Kola NPP Unit 2 to provide early and reliable warning of the release of radionuclides from the reactor into the confinement air space as an indication of the occurrence of a severe accident at the plant. In addition, it was intended to provide hands-on experience and training to the Russian plant workers in the installation, operation, calibration and maintenance of the equipment in order that they may use the equipment without continued US assistance as an effective measure to improve reactor safety at the plant.

  17. Morphological and biochemical investigation into the possible neuroprotective effects of kolaviron (Garcinia kola bioflavonoid) on the brains of rats exposed to vanadium.

    PubMed

    Igado, Olumayowa O; Olopade, James O; Adesida, Adebukola; Aina, Oluwasanmi O; Farombi, Ebenezer O

    2012-10-01

    In this study, the morphological and biochemical susceptibility of the rat brain to vanadium, in the form of sodium metavanadate, and the comparative ameliorative effect of Garcinia kola and kolaviron (G. kola extract), was examined. Brain regions examined were the cerebrum, cerebellum, hippocampus and the olfactory bulb. We showed that vanadium administration caused cellular vacuolation, congestion, and Purkinje cell degeneration and a marked reduction in myelin tracts. Biochemical tests revealed increased lipid peroxidation induced by vanadium, which was ameliorated with the administration of G. kola and kolaviron. Vanadium administration caused an increase in thiobarbituric acid-reactive substances (TBARS) in the cerebrum and hippocampus, whereas the administration of kolaviron resulted in a reduction of the TBARS level by 65.7 and 80%, respectively, in the regions aforementioned. Also, the administration of kolaviron resulted in an increased activity of superoxide dismutase (61.24%) in all brain regions assessed, when compared with the group administered vanadium alone. Results obtained from this study led to the conclusion that kolaviron reduces vanadium-induced oxidative stress in the brain.

  18. Constraints on the depth of generation and emplacement of a magmatic epidote-bearing quartz diorite pluton in the Coast Plutonic Complex, British Columbia

    USGS Publications Warehouse

    Chang, J.M.; Andronicos, C.L.

    2009-01-01

    Petrology and P-T estimates indicate that a magmatic epidote-bearing quartz diorite pluton from Mt. Gamsby, Coast Plutonic Complex, British Columbia, was sourced at pressures below ???1.4 GPa and cooled nearly isobarically at ???0.9 GPa. The P-T path indicates that the magma was within the stability field of magmatic epidote early and remained there upon final crystallization. The pluton formed and crystallized at depths greater than ???30 km. REE data indicate that garnet was absent in the melting region and did not fractionate during crystallization. This suggests that the crust was less than or equal to ???55 km thick at 188 Ma during the early phases of magmatism in the Coast Plutonic Complex. Late Cretaceous contractional deformation and early Tertiary extension exhumed the rocks to upper crustal levels. Textures of magmatic epidote and other magmatic phases, combined with REE data, can be important for constraining the P-T path followed by magmas. ?? 2009 Blackwell Publishing Ltd.

  19. Is there a geochemical link between volcanic and plutonic rocks in the Organ Mountains caldera?

    NASA Astrophysics Data System (ADS)

    Memeti, V.; Davidson, J.

    2013-12-01

    Results from separate volcanic and plutonic studies have led to inconsistent conclusions regarding the origins and thus links between volcanic and plutonic systems in continental arcs and the magmatic processes and time scales responsible for their compositional variations. Some have suggested that there is a geochemical and geochronological disconnect between volcanic and plutonic rocks and hence have questioned the existence of magma mush columns beneath active volcanoes. Investigating contemporary volcanic and plutonic rocks that are spatially connected is thus critical in exploring these issues. The ca. 36 Ma Organ Mountains caldera in New Mexico, USA, represents such a system exposing contemporaneous volcanic and plutonic rocks juxtaposed at the surface due to tilting during extensional tectonics along the Rio Grande Rift. Detailed geologic and structural mapping [1] and 40Ar/39Ar ages of both volcanics and plutons [2] demonstrate the spatial and temporal connection of both rock types with active magmatism over >2.5 myr. Three caldera-forming ignimbrites erupted within 600 kyr [2] from this system with a total erupted volume of 500-1,000 km3 as well as less voluminous pre- and post-caldera trachyte and andesite lavas. The ignimbrite sequence ranges from a crystal-poor, high-SiO2 rhyolite at the base to a more crystal-rich, low-SiO2 rhyolite at the top. Compositional zoning with quartz-monzonite at the base grading to syenite and alaskite at the top is also found in the Organ Needle pluton, the main intrusion, which is interpreted to be the source for the ignimbrites [1]. Other contemporaneous and slightly younger plutons have dioritic to leucogranitic compositions. We examined both volcanic and plutonic rocks with petrography and their textural variations with color cathodoluminescence, and used whole rock element and Sr, Nd and Pb isotope geochemistry to constrain magma compositions and origins. Electron microprobe analyses on feldspars have been completed to

  20. Mineral potential of selected felsic plutons in the eastern and southeastern Arabian Shield, Kingdom of Saudi Arabia

    USGS Publications Warehouse

    du Bray, Edward A.

    1983-01-01

    Most of the plutons studied are similar to metallogenically specialized granites described elsewhere in the world and found associated with deposits of tin, tungsten, or molybdenum and other rare metals. Only four of the plutons, the Sitarah, Tarban, and Gaharra monzogranites and the Bwana granite, contained highly anomalous amounts of tin, tungsten, or molybdenum and altered zones- and (or) numerous quartz veins and otherwise appeared to have noteworthy mineral potential. Additional work on at least these four plutons is suggested.

  1. Melt segregation and assembly of the youngest exposed magma chamber in the world: Takidani Pluton (Japan)

    NASA Astrophysics Data System (ADS)

    Hartung, E.; Caricchi, L.; Floess, D.; Wallis, S.; Harayama, S.

    2014-12-01

    Segregation of residual melt from partially crystallized magmas is a process of paramount importance for the chemical evolution of magmas and the construction of reservoirs of potentially eruptible magma. In this study we investigate the Takidani pluton, one of the youngest exposed plutons on Earth (˜1Ma). This chemically zoned magmatic body is located within the active Norikura Volcanic Chain in the Northern Japan Alps and associated with large dacitic to rhyolitic deposits (Nyukawa Pyroclastic Flow Deposit and Ebisutoge-Fukuda tephra). Our study focuses on the physical processes responsible for the extraction of residual melt from a crystallizing magma and the construction of the subvolcanic reservoirs that fed large silicic eruptions. Detailed structural mapping and sampling along four transects from the base to the top of the pluton were carried out along with a magnetic susceptibility survey. Our preliminary results indicate that the pluton was assembled by multiple intrusions. The pluton can be broadly separated into three distinct lithological units: 1) fine grained granite; 2) equigranular granodiorite that locally grades into either porphyritic granodiorite or granite towards the roof of the intrusion; and 3) mafic granodiorite. Units 1) and 2) form the core of the intrusion and together represent about 70% of the total volume of the pluton. Our results show that the equigranular granodiorite is internally inhomogeneous with felsic lenses of lower magnetic susceptibility. The magnetic susceptibility decreases gradually towards the roof of the pluton reaching its lowest value within leucrocratic porphyritic units. Higher magnetic susceptibility values at the contact with the roof correspond to a slightly more mafic porphyritic unit. Melt segregation and evolution of the Takidani Granodiorite are being further investigated using bulk rock and mineral chemistry (EMPA and LA-ICP-MS) together with anisotropy of magnetic susceptibility.

  2. Pressure, temperature and oxygen fugacity conditions of calc-alkaline granitoids, Eastern Desert of Egypt, and tectonic implications

    NASA Astrophysics Data System (ADS)

    Helmy, H. M.; Ahmed, A. F.; El Mahallawi, M. M.; Ali, S. M.

    2004-02-01

    Five calc-alkaline plutons; Um Tagher, Abu Zawil, Um Gidri, Um Anab and El Ghuzah, in the northern Eastern Desert of Egypt were subjected to petrographic and mineralogical investigations. They are composed of varying proportions of quartz + plagioclase + potash feldspar + biotite + hornblende ± epidote ± calcite + titanite + magnetite + apatite and zircon. Electron microprobe analyses of coexisting hornblende and plagioclase (hornblende-plagioclase thermometry), Al content in hornblende (aluminum-in-hornblende barometry) and the assemblage titanite-magnetite-quartz were used to constrain the P, T and fO 2 during the crystallization of the parent magmas in the different plutons. The plutons crystallized under varying pressures (5.4-2.1 kbar) and wide range of temperature (785-588 °C) from highly oxidized magmas (log fO 2 -21 to -13). The pressure data discriminate three categories of granitoid emplaced at different crustal levels: (a) upper crust granitoids (e.g., El Ghuzah, and Abu Zawil) emplaced at depths <9 km; (b) intermediate crust granitoids (e.g., Um Gidri and Um Anab) emplaced at depths <13 km; and (c) lower crust granitoids (e.g., Um Tagher) emplaced at depths <21 km. The depths of emplacement seem to increase from northwest to southeast. It is likely that the magmas forming these plutons were generated at different depths; they were similar in composition but varied substantially in their water and volatile contents. High water and volatile contents allowed the magma of some plutons to reach shallower crustal levels without complete solidification. Although these complexes were crystallized at different depths, they were later uplifted to the same level by upward faulting.

  3. Long-term aerosol and trace gas measurements in Eastern Lapland, Finland: the impact of Kola air pollution to new particle formation and potential CCN

    NASA Astrophysics Data System (ADS)

    Kyrö, Ella-Maria; Väänänen, Riikka; Kerminen, Veli-Matti; Virkkula, Aki; Asmi, Ari; Nieminen, Tuomo; Dal Maso, Miikka; Petäjä, Tuukka; Keronen, Petri; Aalto, Pasi; Riipinen, Ilona; Lehtipalo, Katrianne; Hari, Pertti; Kulmala, Markku

    2014-05-01

    Sulphur and primary emissions have been decreasing largely all over Europe, resulting in improved air quality and decreased direct radiation forcing by aerosols. The smelter industry in Kola Peninsula is one of largest sources of anthropogenic SO2 within the Arctic domain and since late 1990s the sulphur emissions have been decreasing rapidly (Paatero et al., 2008; Prank et al., 2010). New particle formation (NPF) is tightly linked with the oxidizing product of SO2, namely sulphuric acid (H2SO4), since it is known to be the key component in atmospheric nucleation (Sipilä et al., 2010). Thus, decreasing sulphur pollution may lead to less NPF. However, low values of condensation sink (CS), which is determined by the amount of pre-existing particles, favours NPF. We used 14 years (1998-2011) of aerosol number size distribution and trace gas data from SMEAR I station in Eastern Lapland, Finland, to investigate these relationships between SO2, NPF and CS. The station is a clean background station with occasional sulphur pollution episodes when the air masses arrive over Kola Peninsula. We found that while SO2 decreased by 11.3 % / year, the number of clear NPF event days was also decreasing by 9.9 % / year. At the same time, CS was decreasing also (-8.0 % / year) leading to formation of more particles per single NPF event (J3 increased by 29.7 % / year in 2006-2011) but the low vapour concentrations of H2SO4 (proxy decreased by 6.2 % / year) did not allow them to grow into climatically relevant sizes. Over the time, concentrations of potential CCN (cloud condensing nuclei) were also decreasing with more moderate pace, -4.0 % / year. The events started on average earlier after sunrise when the SO2 concentration during the start of the event was higher and NPF occurred more frequently in air masses which were travelling over Kola. Despite the total decrease in sulphur pollution originating from Kola there is currently no evidence of cleaning of the emissions, rather the

  4. Granitoid pluton formation by spreading of continental crust: the Wiley Glacier complex, northwest Palmer Land, Antarctica

    NASA Astrophysics Data System (ADS)

    Vaughan, Alan P. M.; Wareham, Christopher D.; Millar, Ian L.

    1997-12-01

    The emplacement mechanism, geometry, and isotope geochemistry of plutons of the Wiley Glacier complex suggest that new continental crust grew by multiple injection of tonalitic dykes during dextral transtension in the Antarctic Peninsula magmatic arc in Early Cretaceous times. The suggested mechanism is analogous to basalt dyke injection during sea-floor spreading. During normal-dextral shear, the Burns Bluff pluton, a sheeted, moderately east-dipping, syn-magmatically sheared tonalite-granodiorite intruded syn-magmatically sheared quartz diorite of the Creswick Gap pluton and 140 ± 5 Ma hornblende gabbro. UPb dating of zircon and ArAr dating of hornblende and biotite suggest that both granite s.l. plutons were emplaced between 145 and 140 Ma, but that extensional shearing was active from the time of emplacement until ca. 127 Ma. The Burns Bluff pluton is chilled at its margin, and grades through mylonitised, porphyritic tonalite-granodiorite sheets and tonalite-granodiorite sheets with minor chilling, to a kilometre-scale body of coarse-grained, hypidiomorphic tonalite-granodiorite. Co-magmatic microdiorite forms dykes and abundant synplutonic mafic enclaves. These dykes opened as echelon veins during episodic dextral shear and were deformed to trains of enclaves during continued normal-dextral shear. Pluton-marginal porphyritic and hypidiomorphic tonalite-granodiorite forms large, fault-hosted sheets emplaced progressively under extension with minor dextral shear. Kinematic indicators from pluton-marginal granite s.l. dykes suggest that early in pluton accretion, intrusive sheets cooled rapidly, with simple shear prior to full crystallisation changing to ductile simple shear during cooling. Kinematic indicators towards the pluton core suggest that as the pluton grew, and cooled more slowly, emplacement switched from sheeting to in situ inflation with simple shear distributed across a broad zone prior to full crystallisation of magma. Cross

  5. Strontium and oxygen isotopic variations in Mesozoic and Tertiary plutons of central Idaho

    USGS Publications Warehouse

    Fleck, R.J.; Criss, R.E.

    1985-01-01

    Regional variations in initial 87Sr/86Sr ratios (ri) of Mesozoic plutons in central Idaho locate the edge of Precambrian continental crust at the boundary between the late Paleozoic-Mesozoic accreted terranes and Precambrian sialic crust in western Idaho. The ri values increase abruptly but continuously from less than 0.704 in the accreted terranes to greater than 0.708 across a narrow, 5 to 15 km zone, characterized by elongate, lens-shaped, highly deformed plutons and schistose metasedimentary and metavolcanic units. The chemical and petrologic character of the plutons changes concomitantly from ocean-arc-type, diorite-tonalite-trondhjemite units to a weakly peraluminous, calcic to calcalkalic tonalite-granodiorite-granite suite (the Idaho batholith). Plutons in both suites yield Late Cretaceous ages, but Permian through Early Cretaceous bodies are confined to the accreted terranes and early Tertiary intrusions are restricted to areas underlain by Precambrian crust. The two major terranes were juxtaposed between 75 and 130 m.y. ago, probably between 80 and 95 m.y. Oxygen and strontium isotopic ratios and Rb and Sr concentrations of the plutonic rocks document a significant upper-crustal contribution to the magmas that intrude Precambrian crust. Magmas intruding the arc terranes were derived from the upper mantle/subducted oceanic lithosphere and may have been modified by anatexis of earlier island-arc volcanic and sedimentary units. Plutons near the edge of Precambrian sialic crust represent simple mixtures of the Precambrian wall-rocks with melts derived from the upper mantle or subducted oceanic lithosphere with ri of 0.7035. Rb/Sr varies linearly with ri, producing "pseudoisochrons" with apparent "ages" close to the age of the wall rocks. Measured ??18O values of the wall rocks are less than those required for the assimilated end-member by Sr-O covariation in the plutons, however, indicating that wall-rock ??18O was reduced significantly by exchange with

  6. Geochemistry of biotite granites from the Lamas de Olo Pluton, northern Portugal

    NASA Astrophysics Data System (ADS)

    Fernandes, Susana; Gomes, Maria; Teixeira, Rui; Corfu, Fernando

    2013-04-01

    In the Central Iberian Zone (CIZ) extensive crustal recycling occurred during the post-thickening extension stage of the Variscan orogeny (~330-290 Ma). After the ductile deformation phase D3 (~320-300 Ma), characterized by the intrusion of large volumes of highly peraluminous granitic magmas, rapid and drastic tectonic changes at about 300 Ma gave rise to the brittle phase of deformation D4 that controlled the emplacement of Fe-K subalkaline granites (296-290 Ma; Dias et al. 1998). The Lamas de Olo Pluton (LOP) is controlled by NE-SW and NW-SE fracture systems, probably related to the Régua-Verin fault zone (Pereira, 1989). The LOP is a medium to coarse-grained, porphyritic biotite granite, accompanied by medium- to fine grained, porphyritic biotite granite (Alto dos Cabeços- AC) and a more leucocratic, fine-grained, slightly porphyritic biotite-muscovite granite (Barragens- BA). The contacts between LO and AC are generally diffuse, whereas those to BA are sharp. In fact, the BA granite can occur in dykes and sills cutting LO and AC. Microgranular enclaves and xenoliths are very rare. The LOP intrudes the Douro Group, presumably of Precambrian to Cambrian age, and two-mica granites from the Vila Real composite massif. The LOP granites consist of quartz, microcline, plagioclase, biotite, zircon, titanite, tourmaline apatite, fluorite, ilmenite, magnetite, and rutile, with muscovite in BA granite and rare allanite in the LO and AC granites. The plagioclase composition is of oligoclase (An12) - andesine (An35) for LO granite, albite (An9) - andesine (An30) for CA granite and albite (An5) - oligoclase (An20) for BA granite. There are decreases in: a) anorthite content from phenocryst to matrix plagioclase; b) Ba content from phenocryst to matrix microcline in all granites. The Fe2+ biotite has a composition similar to that of biotite from calc-alkaline to sub-alkaline rock series. The LO and AC granites are meta- to peraluminous with ASI variable between 1.05 and 1

  7. Geochemistry, geochronology and zircon Hf isotopic study of peralkaline-alkaline intrusions along the northern margin of the North China Craton and its tectonic implication for the southeastern Central Asian Orogenic Belt

    NASA Astrophysics Data System (ADS)

    Zhao, Pan; Jahn, Bor-ming; Xu, Bei; Liao, Wen; Wang, Yanyang

    2016-09-01

    A giant Permian alkaline magmatic belt has recently been identified in southern Inner Mongolia, along the northern margin of the North China Craton (NCC). This belt is mainly composed of syenite, quartz syenite, alkaline granite and mafic microgranular enclaves (MME)-bearing granodiorite. In order to study the petrogenesis and tectonic implications of these rocks, we undertook zircon U-Pb dating and geochemical analysis of two Permian alkaline plutons. The first Guangxingyuan Pluton occurs in the Hexigten area and is composed of MME-bearing tonalite, K-feldspar granite and syenite. The second Durenwuliji Pluton, located in the Xianghuangqi area, comprises syenite, quartz syenite and K-feldspar granite. Zircon U-Pb dating on tonalite, K-feldspar granite, syenite and quartz syenite from the two plutons yielded a tight range of ages from 259 to 267 Ma. The peralkaline-alkaline rocks show high abundance of total alkalis (K2O + Na2O = 7.9-12.9%) and K2O contents (3.9-8.0%), enrichment in large ion lithophile elements (LILE) and light rare earth element (LREE), and depletion of high field strength elements (HFSE). The associated tonalite and MMEs display I-type granitic geochemical affinity, with less total abundance of trace elements than the peralkaline-alkaline rocks. Zircon Hf isotopic analysis of the Guangxingyuan pluton yielded a large range of εHf(t) values from - 15.5 to + 6.7 and model ages (TDMC) from 781 to 2012 Ma. By contrast, the Hf isotopic data of the Durenwuliji pluton shows a small range of εHf(t) from + 6.2 to + 8.9 and TDMC from 667 to 816 Ma. The geochemical and Hf isotopic characteristics indicate that the parental magma was derived from a mixing of metasomatic mantle-derived mafic magma with different amount of crust-derived felsic magma, and followed by fractional crystallization. Considering previous tectonic studies in Inner Mongolia, a Permian post-orogenic extension was proposed to account for these peralkaline-alkaline intrusions following

  8. Emission of CO2 by soils in the impact zone of the Severonikel smelter in the Kola subarctic region

    NASA Astrophysics Data System (ADS)

    Kadulin, M. S.; Koptsik, G. N.

    2013-11-01

    The intensity of the in situ soil respiration in the background northern taiga spruce forests of the Kola subarctic region reaches 120-290 mg C-CO2/m2 per h. In the impact zone of the Severonikel smelter, it decreases to 90-140, 30, and 15-30 mg C-CO2/m2 per h at the stages of spruce defoliation, spruce-birch woodland, and technogenic barrens of the technogenic succession, respectively. For the first time, the impact of the industrial pollution on root respiration has been assessed, and the dependences of the CO2 emission, the contribution of mineral soil horizons to this process, the microbial biomass, and root respiration on the concentrations of available nickel and copper compounds have been determined. The efficiency of two remediation technologies applied to technogenic barrens near the smelter has been evaluated on the basis of four parameters of the soil biological activity. The results indicate that remediation with the creation of a new filled soil layer is more efficient than chemical and phytoremediation methods.

  9. Emissions from the copper-nickel industry on the Kola Peninsula and at Noril'sk, Russia

    USGS Publications Warehouse

    Boyd, Ron; Barnes, S.-J.; De Caritat, P.; Chekushin, V.A.; Melezhik, V.A.; Reimann, C.; Zientek, M.L.

    2009-01-01

    Published estimates for base metal emissions from the copper-nickel industry on the Kola Peninsula are re-examined in the light of (a) chemical data on the composition of the ores; (b) official emission figures for 1994; and (c) modelled emissions based on dry and wet deposition estimates derived from data for snow and rain samples collected in 1994. The modelled emissions, official emission figures and chemical data are mutually compatible for Ni, Cu and Co and show that previously published figures underestimated the emissions of the major elements, Ni and Cu (though within the same order of magnitude) and overestimated the emissions of As, Pb, Sb and Zn by up to several orders of magnitude, in some cases exceeding the calculated total input to the plants. Published estimates have neglected information on the nature and chemistry of the ores processed in metallurgical industries in the Noril'sk area of Siberia and the Urals. Revised emission estimates for 1994, using knowledge of the chemistry of the ores, are proposed: taken with published information on total emissions up to 2000 these data give an indication of emission levels in more recent years. ?? 2008 Elsevier Ltd. All rights reserved.

  10. Autumn migration and wintering areas of Peregrine Falcons Falco peregrinus nesting on the Kola Peninsula, northern Russia

    USGS Publications Warehouse

    Ganusevich, S.A.; Maechtle, T.L.; Seegar, W.S.; Yates, M.A.; McGrady, M.J.; Fuller, M.; Schueck, L.; Dayton, J.; Henny, C.J.

    2004-01-01

    Four female Peregrine Falcons Falco peregrinus breeding on the Kola Peninsula, Russia, were fitted with satellite-received transmitters in 1994. Their breeding home ranges averaged 1175 (sd = ??714) km2, and overlapped considerably. All left their breeding grounds in September and migrated generally south-west along the Baltic Sea. The mean travel rate for three falcons was 190 km/day. Two Falcons wintered on the coasts of France and in southern Spain, which were, respectively, 2909 and 4262 km from their breeding sites. Data on migration routes suggested that Falcons took a near-direct route to the wintering areas. No prolonged stopovers were apparent. The 90% minimum convex polygon winter range of a bird that migrated to Spain encompassed 213 km2 (n = 54). The area of the 50% minimum convex polygon was 21.5 km2 (n = 29). Data from this study agree with others from North America that show that Falcons breeding in a single area do not necessarily follow the same migratory path southward and do not necessarily use the same wintering grounds.

  11. Thermochronology of the Cornubian batholith in southwest England: Implications for pluton emplacement and protracted hydrothermal mineralization

    USGS Publications Warehouse

    Chesley, J.T.; Halliday, A.N.; Snee, L.W.; Mezger, K.; Shepherd, T.J.; Scrivener, R.C.

    1993-01-01

    The metalliferous ore deposits of southwest England are associated with biotite-muscovite granites that intruded upper Paleozoic sediments and volcanic rocks at the end of the Hercynian Orogeny. The hydrothermal mineralization can be subdivided into four stages: 1. (1) exoskarns 2. (2) high-temperature tin and tungsten oxide-bearing sheeted greisen bordered veins and Sn-bearing tourmaline veins and breccias 3. (3) polymetallic quartz-tourmaline-chlorite-sulfide-fluorite-bearing fissure veins, which represent the main episode of economic mineralization 4. (4) late-stage, low-temperature polymetallic fluorite veins. U-Pb dating of monazite and xenotime and 40Ar 39Ar dating of muscovite were used to determine emplacement ages and cooling times for individual plutons within the Cornubian batholith, as well as separate intrusive phases within the plutons. In addition, 40Ar 39Ar ages from hornblende and secondary muscovite and Sm-Nd isochron ages from fluorite were employed to determine the relationship between pluton emplacement and different stages of mineralization. The U-Pb ages indicate that granite magmatism was protracted from ~300 Ma down to ~275 Ma with no evidence of a major hiatus. There is no systematic relation between the age of a pluton and its location within the batholith. The U-Pb ages for separate granite phases within a single pluton are resolvable and indicate that magma emplacement within individual plutons occurred over periods of as much as 4.5 myrs. Felsic porphyry dike emplacement was coeval with plutonism, but continued to ~270 Ma. The geochronologic data suggest that the Cornubian batholith originated from repeated melting events over 30 myrs and was formed by a series of small coalescing granitic bodies. Cooling rates of the main plutons are unrelated to emplacement age, but decrease from the southwest to the northeast from ~210??C myr-1 to ~60??C myr-1 with a mean of 100??C myr-1. These slow cooling rates appear to reflect the addition of

  12. Reconnaissance geochemical exploration of plutons of syenite and shonkinite, southern Asir, Kingdom of Saudi Arabia

    SciTech Connect

    Overstreet, W.C.; Assegaff, A.B.; Hussain, M.A.; Naqvi, M.I.; Selner, G.I.; Matzko, J.J.

    1985-01-01

    Reconnaissance geochemical exploration for rare metals in plutons of syenite and shonkinite disclosed generally less than 20 ppM Nb in rocks, wadi sediments, and concentrates. The sparsity of Nb is accompanied by low values for La, Sn, W, Y, and Zr and relatively high but insignificant values for Be and Mo. Base and precious metals are either below their respective limits of determination in the various sample media or are present at background levels commensurate with average crustal abundances in felsic rocks. Pegmatite dikes associated with the syenite plutons are rare and lack vermiculite. The present investigation disclosed no possible ore deposits in the plutons covered by the field work. Known kyanite-topaz-natroalunite rocks in the vicinity of the surveyed areas should be examined for possible deposits of Cu, Mo, or Au associated with high-alumina hydrothermal deposits. 27 refs., 7 figs., 21 tabs.

  13. Comparing magnetic and magmatic fabrics to constrain the magma flow record in La Gloria pluton, central Chile

    NASA Astrophysics Data System (ADS)

    Payacán, Italo; Gutiérrez, Francisco; Gelman, Sarah E.; Bachmann, Olivier; Parada, Miguel Ángel

    2014-12-01

    This contribution illustrates a case study of a pluton (La Gloria pluton; LGP) where magnetic and magmatic fabrics are locally decoupled. We compare the magmatic fabric with the available magnetic fabric data to explore their abilities and elucidate the magma flow record of LGP. Results indicate that magnetic (controlled by multi-domain magnetite) and magmatic fabrics are generally consistent throughout LGP. Foliations define an axisymmetric pattern that gradually changes from vertical near lateral margins to less steep in the pluton interior, whereas lineations are subhorizontal following the elongation direction of the pluton. However, samples at the pluton center show marked differences between both fabrics: magnetic fabrics indicate subhorizontal magnetic lineations and foliations, and magmatic fabrics indicate subvertical lineations and foliations. Both magnetic and magmatic fabrics are interpreted to record strain caused by magma flow during thermal convection and lateral magma propagation at the transition between low and high crystallinity stages. We suggest that fabrics acquisition and consistency were determined by shear conditions (pure/simple shear rates ratio) and the orientation of the magma flow direction with respect to a rigid boundary (critical crystalline region) of the pluton. Magmatic fabric differs at the center of the pluton because pure shear is dominant and ascendant flows are orthogonal to the horizontal rigid boundary. LGP represents a whole-scale partly molten magma reservoir, where both thermal convection and lateral propagation of the magma are recorded simultaneously. This study highlights the importance of characterizing both fabrics to properly interpret magma flow recorded in plutons.

  14. Late Cretaceous and early Tertiary plutonism and deformation in the Skagit Gneiss Complex, north Cascade Range, Washington and British Columbia

    USGS Publications Warehouse

    Haugerud, R.A.; Van Der Heyden, P.; Tabor, R.W.; Stacey, J.S.; Zartman, R.E.

    1991-01-01

    The Skagit Gneiss Complex forms a more-or-less continuous terrane within the North Cascade Range. The complex comprises abundant plutons intruded at mid-crustal depths into a variety of metamorphosed supracrustal rocks of both oceanic and volcanic-arc origin. U-Pb zircon ages from gneissis plutons within and near the Skagit Gneiss Complex indicate magmatic crystallziations between 75 and 60 Ma. Deformation, recrystallization, and migmatization in part postdate intrusion of the 75-60 Ma plutons. This latest Cretaceous and earliest Tertiary plutonism and migmatization may reflect thermal relaxation following early Late Cretaceous orogeny. The complex was ductilely extended northwest-southeast shortly after intrusion of granite dikes at ~45 Ma, but before emplacement of the earliest (~34 Ma) plutons of the Cascade arc. -from Authors

  15. Petrology, geochemistry and thermobarometry of the northern area of the Flamenco pluton, Coastal Range batholith, northern Chile. A thermal approach to the emplacement processes in the Jurassic andean batholiths

    NASA Astrophysics Data System (ADS)

    Rodríguez, Natalia; Díaz-Alvarado, Juan; Rodríguez, Carmen; Riveros, Karl; Fuentes, Paulina

    2016-04-01

    The Flamenco pluton is part of a N-S alignment of Late Triassic to Early Jurassic intrusive belt comprising the westernmost part of the Coastal Range batholith in northern Chile. The Jurassic-Cretaceous voluminous magmatism related to subduction in the western active continental margin of Gondwana is emplaced in the predominantly metasedimentary Paleozoic host-rocks of the Las Tórtolas formation, which in the northern area of the Flamenco pluton present an intense deformation, including the Chañaral mélange. Geochemically, the Flamenco pluton shows a wide compositional variability (SiO2 between 48wt % and 67wt %). Gabbros, Qtz-diorites and tonalites, mesocratic and leucocratic granodiorites are classified as calc-alkaline, calcic, magnesian and metaluminous magmatism. Flamenco granitoids define cotectic linear evolution trends, typical of magmatic fractionation processes. Geochemical trends are consistent with magmas evolved from undersaturated and low-pressure melts, even though the absence of transitional contacts between intrusive units precludes in-situ fractionation. Although some granodioritic samples show crossed geochemical trends that point to the compositional field of metasediments, and large euhedral prismatic pinnite-biotite crystals, typical Crd pseudomorph, are observed in contact magmatic facies, geochemical assimilation processes are short range, and the occurrence of host-rocks xenoliths is limited to a few meters from the pluton contact. A thermal approach to the emplacement process has been constrained through the thermobarometric results and a 2D thermo-numerical model of the contact aureole. Some Qtz-diorites and granodiorites located in the north area of the pluton exhibit granulitic textures as Hbl-Pl-Qtz triple junctions, poikiloblastic Kfs and Qtz recrystallization. The Hbl-Pl pairs have been used for the thermobarometric study of this metamorphic process, resulting granoblastic equilibrium temperatures between 770 and 790 °C, whereas

  16. Granodiorite Pluton Formation at the Mid-Cenozoic Never Summer Igneous Complex, North-Central Colorado

    NASA Astrophysics Data System (ADS)

    Jacob, K. H.; Farmer, G.

    2012-12-01

    Field observations, major- and trace-element geochemistry, and Sr and Nd isotopic data were used to assess the petrogenesis of epizonal intrusive rocks and related volcanic rocks from the ~28 Ma Never Summer igneous complex in north-central Colorado. Intrusive igneous rocks at this igneous center consist of an older granodiorite pluton (the Mt Richthofen stock, MRS) that is intruded by the granitic Mt. Cumulus stock. The latter has a uniform bulk composition equivalent to that of high silica rhyolite (~77 wt % SiO2, ɛNd(T) ~ -6). Whole rock studies of the MRS reveal that it is compositionally zoned (55-67 wt % SiO2,ɛNd(T) -0.5 to -5.7, 87Sr/86Sr(T) 0.7049 to 0.7119), with the lowest wt % SiO2 and highest ɛNd(T) occurring along the western margin of the pluton. Field observations, combined with the observed compositional variations, suggest that the pluton was originally a shallowly intruded (< 2 km), ~1 km thick sill that was vertically zoned from a mafic base to more felsic roof. The entire pluton has been tilted ~25 degrees to the west after emplacement. Given the lack of obvious wall-rock assimilation at the level of pluton emplacement, the isotopic variations in the pluton most likely reflect differences in the isotopic compositions of melts from which the pluton was assembled. Obvious field evidence exists for underplating of the developing pluton by mafic, high ɛNd (T) (>-2) melts and illustrates that mafic magmas were present in the uppermost crust and likely participated in pluton formation. The higher wt % SiO2 and lower ɛNd(T) portions of the MRS, however, could not have been derived directly from the mafic magmas in any closed system process. One option is that the MRS ultimately represents the product of mixing of >70 wt % SiO2 melts (+ crystals), analogous to the melts from which the Mt. Cumulus stock crystallized, and underplating mafic magma. This model implies that two primary magmas types, high silica rhyolite and basalt/basaltic andesite

  17. Construction of the Devonian bimodal Gouldsboro pluton via multiple intrusion, coastal Maine, USA

    NASA Astrophysics Data System (ADS)

    Koteas, C.

    2006-12-01

    The Gouldsboro pluton (377 ± 19 ma) (Metzger et al., 1982) of the eastern coastal Maine magmatic province preserves abundant evidence of mechanical interaction between mafic and felsic magmas, as well as the stoping and doming of country rock. Coastal Maine is a unique location where subequal volumes of felsic and mafic material have interacted and are preserved in both plutonic and volcanic complexes. The effects of generation and mobilization of large volumes of magma in the shallow crust are well-preserved. The Gouldsboro pluton provides an excellent perspective from the highest to lowest sections (southwest to northeast) of a hybrid magmatic system. The Gouldsboro magmatic complex is hosted by undated greenstone to the north that is overlain by the 477 ± 18 ma (Metzger, 1977) meta-volcanic/meta-sedimentary Bar Harbor formation. Blocks of both units are discernable as 10 cm to 2 m-diameter blocks within the pluton. The Gouldsboro granite is dominantly a fine to medium grained feldspar- rich leucocratic hornblende granite, although biotite is sometimes present. Miarolitic cavities are common in the highest exposure of the system, especially in the south where the finest grained, most leucocratic granite occurs. Other units include, from lowest to highest in the system, hybrid diorite-gabbro, hybrid granite-granodiorite, granite hosting 30 cm to 3 m-diameter globular basaltic pillows, and a previously unrecognized pyroclastic unit, very similar to the lowermost member of the Cranberry Isle series, a volcanic breccia (Seaman et al., 1999). The pyroclastic unit is intruded by medium grained granite hosting angular fragments of volcanic, mafic plutonic, and country rock. While the contact between gabbro near the base of the pluton and granite in the middle of the pluton is commonly gradational, there are complex intrusive breccias in some areas where fine to coarse, angular diorite to gabbro xenoliths are hosted by granodiorite and granite. Enclave-rich zones

  18. Map showing the distribution and characteristics of plutonic rocks in the Tonopah 1 degree by 2 degrees Quadrangle, central Nevada

    USGS Publications Warehouse

    John, D.A.

    1987-01-01

    The accompanying table includes the name (if any) of the pluton and its location, the age of the pluton (either a radiometric age or an age inferred from field relations), modal composition, texture, mineralogy, hydrothermal alteration and mineralization related to the pluton, the source of mapping shown on this map, and published references on the pluton. Radiometric ages are either published K-Ar and fission track ages or new whole-rock Rb-Sr ages determined by A. C. Robinson on samples collected either for this study or as part of regional Sr-isotope studies by R.W. Kistler and A.C. Robinson. K-Ar ages published prior to 1977 are corrected using the new I.U.C.S. constants (Steiger and Jager, 1977). Muscovite alteration ages are reported for several plutons and represent minimum ages for emplacement of these plutons. Compositional classification follows the T. J. G.S. system (“Streckeisen, 1976) and is based either on modal analyses of slabs or estimates from hand specimens. All modes, unless otherwise noted, were measured in this study. The number of modes determined is shown in parentheses, and the range in volume percent of major minerals is given. Where no modal data are available, the color index (percentage of mafic minerals) and major mafic minerals are given for most plutons. Data tabulated on hydrothermal alteration and mineralization related to plutons are based on observations made during field studies for this project. Clear genetic relation between granitic plutonism and several mineral deposits previously attributed to granitic plutonism were not substantiated, and these inconsistencies are noted in the table.

  19. Early Variscan I-type pluton in the pre-Alpine basement of the Western Alps: The ca. 360 Ma Cogne diorite (NW-Italy)

    NASA Astrophysics Data System (ADS)

    Guillot, François; Bertrand, Jean-Michel; Bussy, François; Lanari, Pierre; Cosma, Ludovic; Pin, Christian

    2012-11-01

    Located at the internal border of the Grand-Saint-Bernard Zone, the diorite and its aureole lie on top of intensively studied Alpine eclogitic units but this pluton, poorly studied yet, has kept locally almost undeformed. The pluton intruded, at ~ 360 Ma, country-rocks mostly composed of dark shales with Na2O > K2O and minor mafic intercalations of tholeiitic basalt affinity. This association is characteristic of the Vanoise (France) basement series, where available age determinations suggest an Early Paleozoic age. Parts of the pluton, and of its hornfels aureole that is evidenced here for the first time, in the Punta Bioula section of Valsavaranche valley (NW-Italy), have been well-preserved from the Alpine deformation. Syn-emplacement hardening, dehydration-induced, probably prevented strain-enhanced Alpine recrystallization. Magmatic rock-types range continuously from subordinate mafic types at SiO2 ~ 48%, of hornblendite with cumulative or appinite affinities, to the main body of quartz diorite to quartz monzonite (SiO2 up to 62%). P-T estimates for the pluton emplacement, based on the abundance of garnet in the hornfelses, using also zircon and apatite saturation thermometry and Al-in-hornblende barometry, suggest T ~ 800-950 °C and minimum P in the 0.2-0.5 GPa range, with records of higher pressure conditions (up to 1-2 GPa?) in hornblendite phlogopite-cored amphibole. The high-K, Na > K, calc-alkaline geochemistry is in line with a destructive plate-margin setting. Based on major element data and radiogenic isotope signature (ɛNd360 Ma from - 1.2 to + 0.9, 87Sr/86Sr360 Ma from 0.7054 to 0.7063), the parental magmas are interpreted in terms of deep-seated metabasaltic partial melts with limited contamination from shallower sources, the low radiogenic Nd-content excluding a major contribution from Vanoise tholeiites. There is no other preserved evidence for Variscan magmatism of similar age and composition in the Western Alps, but probable analogs are known

  20. Iron mineralization and associated skarn development around southern contact of the Eğrigöz pluton (northern Menderes Massif-Turkey)

    NASA Astrophysics Data System (ADS)

    Uǧurcan, Okşan Gökçen; Oyman, Tolga

    2016-11-01

    The Eğrigöz pluton is located in the northern portion of the Menderes Massif, which is the largest known metamorphic core complex that is also characterized by large-scale extension. Kalkan and Karaağıl skarn deposits are located on the southern border of the Eğrigöz Pluton, whereas Katrandağ mineralization developed along the roof pendant. Skarnization in these three areas is associated with the peraluminous, I-type, calc-alkaline, high-K calc-alkaline Eğrigöz Pluton. Geochemical characteristics of the pluton indicate that it was generated in a continental arc setting. Kalkan, Karaağıl, and Katrandağ skarns are hosted in marble bands in two-mica gneiss of the Kalkan Formation, a locally dolomitic and clay-bearing limestone of the Arıkaya Formation and locally dolomitised limestone of the Balıkbaşı Formation, respectively. Skarn development occurred sequentially in two stages, prograde and retrograde. In Kalkan skarn, prograde stage is characterized by clinopyroxene (Di56-73 Hd26-43 Joh1-2), garnet (Adr45-69 Grs30-52 Alm0-1.4 Sps0.7-2.3), amphibole, and magnetite, whereas retrograde stage is dominated by epidote, amphibole, chlorite, quartz, and calcite. In Karaağıl, both calcic and magnesian skarn association occurred as a result of local variations in dolomite content in Arıkaya Formation. The prograde assemblage of magnesian skarn is composed chiefly of spinel, amphibole and olivine. These mineral assemblages were, partially or fully, altered to serpentine, talc, and chlorite during retrograde alteration. Mesh textures of the serpentine indicates that the serpentine was altered from olivine. Olivine was completely destroyed during retrograde alteration without relict grains remaining. Calcic skarn paragenesis include garnet (Grs36-80Adr20-62Alm0-2.2Sps0.2-2.6), clinopyroxene (Di81-92 Hd7-19 Jo0-1), and plagioclase, that belongs to the earlier stage, and amphibole of the retrograde stage. High grossular end member of the garnet probably

  1. Subduction-related Late Carboniferous to Early Permian Magmatism in the Eastern Pontides, the Camlik and Casurluk plutons: Insights from geochemistry, whole-rock Sr-Nd and in situ zircon Lu-Hf isotopes, and U-Pb geochronology

    NASA Astrophysics Data System (ADS)

    Karsli, Orhan; Dokuz, Abdurrahman; Kandemir, Raif

    2016-12-01

    Late Carboniferous to early Permian granitoid rocks represent a volumetrically minor component of the Eastern Pontide lithosphere, but they preserve useful information about the region's tectonomagmatic history. The Casurluk and Camlik plutons primarily consist of gabbro, gabbroic diorite, diorite, monzogabbro, monzodiorite and monzonite, which intrude early to middle Carboniferous granitic basement rocks in the region. In this study, we use in situ zircon U-Pb ages and Lu-Hf isotopic values, whole-rock Sr-Nd isotopic values, and mineral chemistry and geochemistry of these plutons to determine petrogenesis and crustal evolution; we also discuss geodynamic implications. LA-ICP-MS zircon U-Pb dating of magmatic zircons from the rocks suggests that the plutons were emplaced during the late Carboniferous to early Permian (302 Ma). The metaluminous and I-type intrusive rocks belong to the high-K calc-alkaline series. In addition, they are relatively enriched in light rare earth elements (LREEs) and large-ion lithophile elements (LILEs); they are depleted in heavy rare earth elements (HREEs) and high field strength elements (HFSEs), such as Nb and Ti. All of the samples have homogeneous initial ISr values (0.70675 to 0.70792) and low εNd (t) values (- 5.1 to - 3.3). Zircons from the rocks of both plutons have uniform negative to slightly positive εHf (t) values (- 3.5 to 1.4) and old Hf two-stage model ages (1323 to 1548 Ma), implying that they have the same source, as well as suggesting the involvement of old enriched lithospheric mantle materials during their magma genesis. These results, combined with the εHf (t) values and two-stage model ages, demonstrate that the primary magmas were derived from partial melting of old lithospheric mantle material metasomatized by subduction-related fluids. Considering other regional geological data from the Sakarya Zone where these plutons formed, we conclude that late Carboniferous to early Permian magmatism in the area

  2. Isotopic disequilibrium among commingled hybrid magmas: Evidence for a two-stage magma mixing-commingling process in the Mt. Perkins Pluton, Arizona

    SciTech Connect

    Metcalf, R.V.; Smith, E.I.; Reed, R.C.

    1995-09-01

    The syn-extensional Miocene Mt. Perkins pluton, northwestern Arizona, cooled rapidly due to its small size (6 km{sup 2}) and shallow emplacement (7.5 km) and allows examination of commingled rocks that experienced little isotopic exchange. Within the pluton, quartz dioritic to granodioritic host rocks (58-68 wt% SiO{sub 2}) enclose dioritic enclaves (50-55 wt% SiO{sub 2}) and a portion contains enclave-free granodiorite (70-74 wt% SiO{sub 2}). Fine-grained, crenulate enclave margins and a lack of advanced mixing structures (e.g., schlieren, flow fabrics, etc.) indicate an incipient stage of commingling. Isotopic variation between enclaves and enclosing host rocks is large (6.8 to 10.6 {epsilon}{sub Nd} units; 0.0036 to 0.0046 {sup 87}Sr/{sup 86}Sr units), suggesting isotopic disequilibrium. Comparison of an enclave core and rim suggests that isotopic exchange with the host magma was limited to the enclave rim. Enclaves and hosts collectively form a calc-alkaline suite exhibiting a large range of {epsilon}{sub Nd} (+1.2 to -12.5) and initial {sup 87}Sr/{sup 86}Sr (0.705 to 0.71267) with a correlation among {epsilon}{sub Nd}, initial {sup 87}Sr/{sup 86}Sr, and major and trace element compositions. Modeling suggests that the suite formed by magma hybridization involving magma mixing accompanied by fractional crystallization. The magma mixing must have predated commingling at the present exposure level and indicates a larger mixing chamber at depth. Isotopic and trace element data suggests mixing end-members were asthenospheric mantle-derived mafic and crustal-derived felsic magmas. Fractional crystallization facilitated mixing by reducing the rheological contrasts between the mafic and felsic mixing end-members. 58 refs., 11 figs., 3 tabs.

  3. Field Guide to Plutonic and Metamorphic Rocks. Earth Science Curriculum Project Pamphlet Series PS-5.

    ERIC Educational Resources Information Center

    Romey, William D.

    Suggested are methods for the collection of field evidence about processes that form plutonic and metamorphic rock. Description and discussion of these types of rocks are provided. The planning and execution of a successful field trip is discussed. Advanced field projects are also discussed. Included are five appendices, references, and a…

  4. Chaotic Flow Patterns from a Deep Plutonic Environment: a Case Study on Natural Magma Mixing

    NASA Astrophysics Data System (ADS)

    De Campos, Cristina P.

    2015-07-01

    This work focuses on the mixing between basalt and granite in a deep plutonic environment. The description of mixing patterns and measurements of fractal dimensions, and the evaluation of geochemical data from a Cambro-Ordovician granitic pluton are summarized and discussed. Different morphologic domains within the pluton reveal concentric fragmented and/or folded layers of granite in a gabbro/granite mixed matrix. This stands in contrast to two predominantly regular gabbroic regions. These regular regions are separated by tightly stretched filament areas, in which mixing is enhanced. Sharp and gradational contacts between granitic and gabbroic domains depict the interplay among frozen flows (mingling) and convection-enhanced diffusion processes (mixing). Measurements of fractal dimensions at different scales and analysis of normalized concentration variance for major elements point towards magma mixing: the compositional variability and flow patterns of the studied pluton have been greatly controlled by a natural chaotic mixing process between a granitic and a basaltic end-member. During the mixing process, coeval fractional crystallization no doubt contributed to increasing the complexity of the system. However, since flow, and therefore mixing, stops with temperature decrease, flow patterns must have retained the predominant morphology and composition of the moment at which both contrasting magmas came together and froze. Flow patterns have been preserved. With further temperature decrease, fractional crystallization took over and hybrid rocks were generated from the fractionation of magmas previously mixed in different proportions.

  5. Structural characterization and composition of Y-rich hainite from Sakharjok nepheline syenite pegmatite (Kola Peninsula, Russia)

    NASA Astrophysics Data System (ADS)

    Lyalina, L.; Zolotarev, A.; Selivanova, E.; Savchenko, Ye.; Zozulya, D.; Krivovichev, S.; Mikhailova, Yu.

    2015-08-01

    Y-rich hainite occurs in nepheline syenite pegmatite of the Sakharjok massif (Kola Peninsula, Russia). It forms euhedral prismatic crystals up to 2 mm in length as well as rims around an unidentified mineral phase (silicate of Ca, Y, Zr and Ti). The mineral is triclinic, space group P-1, a 9.6054(10), b 5.6928(6), c 7.3344(7) Å, α 89.903(2), β 101.082(2), γ 100.830(2)°, V 386.32(7) Å3, Z = 1. The calculated density is 3.39 g/cm3. Chemical composition of Sakharjok hainite is different from the previously published data by much higher Y and Nb contents up to 0.72 and 0.20 atoms per formula unit, respectively, by the two- to five-fold depletion in the LREEs and by the strong enrichment of the HREEs. From the single-crystal X-ray diffraction data, there is a significant amount of Y in the M1 site associated with the absence of Zr in it. Nb and Zr are concentrated in the M5 site substituting Ti. Combination of single-crystal X-ray diffraction data and electron microprobe data give the empirical formula (Ca1.04Y0.63REE0.24Mn0.02)∑1.93(Na0.92Ca0.77)∑1.69Ca2.00(Na0.65Ca0.10)∑0.75(Ti0.60Zr0.21Nb0.15Fe0.03)∑0.99((Si4.00Al0.02)∑4.02O14) (F2.61O1.39)∑4.00.

  6. Organochlorine pesticides, chlorinated dioxins and furans, and PCBs in peregrine falcon Falco peregrinus eggs from the Kola peninsula, Russia

    USGS Publications Warehouse

    Henny, C.J.; Ganusevich, S.A.; Ward, F.P.; Schwartz, T.R.; Meyburg, B-U.; Chancellor, R.D.

    1994-01-01

    Nesting of a bog-associated population of mlgfatory Peregrine Falcons, Falco peregrinus, along the Ponoy River depression, Kola Peninsula, Russia, has been studied since 1977. In 1987 91 production rates averaged 1.94 young per active nest and the number of breeding pairs increased from 4 to 10. In 1991, most eyrie sites were visited during the egg stage and a 'sample' egg was collected for contaminant analysis. Eight Peregrine Falcon eggs contained relatively low concentrations of p,p' -DOE (DOE) (geometric mean 3.5 g/g) and of other organochlorine pesticides. These DOE concentrations are similar to those reported in Peregrine Falcon eggs from an Alaskan population that had also showed a recent population increase. Eggshell thinning (11.4%) was similar to that found in Alaska. Concentrations of polychlorinated biphenyls (PCBs) were higher than DOE concentrations, comparable to the contamination profile shown by Peregrine Falcon populations in Fennoscandia, and were higher than those found in Alaskan birds. Before this study, no Peregrine Falcon eggs from Russia had 'been analyzed for PCB congeners, polychlorinated dibenzo- p-dioxins (PCDDs), or pol ychlorinated dibenzofurans (PCD Fs). Conversions of analytical concentrations of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD), other PCDDs, PCDFs and PCB congeners based on relative aryl hydrocarbon hydroxylase induction potencies allowed the estimation of total 2,3,7,8- TCDD equivalents (TEQs). The TEQs are in the range that is associated with embryonic mortality in other species. Even though the Peregrine Falcon population now seems to be released from decades of a DOT problem, exposure to other contaminant continues. There is an obvious need to assess further the sources and longer-term trends of the PCBs. We also report residue concentrations from one White-tailed Eagle, Haliaeetus albicilla, egg.

  7. Urinary Schistosomiasis among Children in Murbai and Surbai Communities of Ardo-Kola Local Government Area, Taraba State, Nigeria

    PubMed Central

    Agere, H.; Wama, B. E.; Bingbeng, J. B.; Amuta, E. U.

    2016-01-01

    Background. This cross-sectional study was conducted to determine the prevalence, intensity of infection, and risk factors associated with urinary schistosomiasis among children in Murbai and Surbai communities of Ardo-Kola Local Government Area (LGA), Taraba State, Nigeria. Methods. Urine samples were analysed by the standard filtration technique using 10 ml syringe, Swinnex polypropylene filter holder (13 mm diameter), and polycarbonate membrane filters (12 μm porosity). Sociodemographic data and water contact activities were collated from children using structured questionnaires. Results. A point prevalence of 58.54% was reported out of the urine samples examined. Males were significantly more infected than their female counterparts (71.15% versus 43.66%, χ2 = 89.12, p = 0.000). The age-related prevalence showed 6–10 and 11–15 years significantly infected with 78.70% and 73.02%, respectively (χ2 = 89.12, p = 0.000). Light intensity of infection, 62.51%, was significantly higher than heavy intensity, 37.48%, among the infected children (χ2 = 365.8, p = 0.000). Water contact activities such as fishing (OR = 4.01, CI = 3.04–5.61, p = 0.000), rice farming (OR = 4.01, CI = 2.96–5.36, p = 0.000), and dry season farming (OR = 4.78, CI = 3.68–6.22, p = 0.000) were the risk factors exposing children to infection in the area. Conclusion. There is an urgent need to undertake a large scale deworming control programme using praziquantel in the area. PMID:28096819

  8. Formation of the Yandangshan volcanic-plutonic complex (SE China) by melt extraction and crystal accumulation

    NASA Astrophysics Data System (ADS)

    Yan, Li-Li; He, Zhen-Yu; Jahn, Bor-ming; Zhao, Zhi-Dan

    2016-12-01

    The association of volcanic and shallow plutonic rocks in caldera may provide important clues to the geochemical evolution of silicic magma systems. The Yandangshan caldera is a typical example of late Mesozoic volcanic-plutonic complex in SE China. It is composed of a series of rhyolitic extrusives and subvolcanic intrusions of porphyritic quartz syenites. In this work, we conducted petrological and geochemical studies, as well as zircon dating, on the coexisting volcanic and plutonic rocks from the Yandangshan caldera. The results of SHRIMP and LA-ICP-MS zircon U-Pb dating revealed that the crystallization of the rhyolitic extrusives and subvolcanic intrusions was contemporaneous within analytical errors and in a short period (104-98 Ma). Geochemically, the volcanic rocks are characterized by high Rb/Sr and Rb/Ba ratios and depletion in Ba, Sr, P, Eu and Ti, while the shallow plutons show high K, Ba, Al, Fe and low Rb/Sr and Rb/Ba ratios with insignificant negative Eu anomalies. The volcanic and plutonic rocks have a similar range of zircon Hf isotopic compositions (εHf(t) = - 10.0 to + 1.5) and TDM2 model ages of 2.10-1.23 Ga. They also have comparable whole-rock Sr and Nd isotopic compositions ((87Sr/86Sr)i = 0.7084-0.7090; εNd(t) = - 7.8 to - 6.5) and zircon oxygen isotopic compositions (δ18O mainly = 4.5 to 6.0‰). We argue that the volcanic-plutonic complex of the Yandangshan caldera was formed by reworking of Paleoproterozoic lower crusts in the eastern Cathaysia block, and that the complex could be linked by fractional crystallization and crystal accumulation in a shallow magma chamber. The volcanic rocks represent the highly fractionated end-member, whereas the subvolcanic intrusions of porphyritic quartz syenites could be the residual crystal mushes. This case study could have a general implication for the genetic relationship between volcanic and shallow plutonic rocks in calderas.

  9. Insights Into the Formation of Rhyolite From the Searchlight Pluton: Evidence from Oriented Quartz Clusters

    NASA Astrophysics Data System (ADS)

    Froemming, N.; Deering, C. D.; Beane, R. J.; Bachmann, O.

    2012-12-01

    The Miocene Searchlight pluton (SLP) in the Colorado River extensional corridor of southern Nevada, is well-exposed and tilted near-vertical for exceptional cross-sectional study of magma reservoir dynamics and crystal fractionation of a mid- to upper-crustal pluton (3 to 13 km depth). The upper quartz monzonite section is dominated by minerals in apparent random orientation with a medium- to fine-grained texture due to direct contact with the cold host rock. The middle granitic section is dominated by coarse-grained quartz and feldspar, and interpreted to be a zone of extracted liquid from an intermediate magma. The lower monzonite section is composed of coarse-grained plagioclase and potassium feldspar. We used the crystallographic orientations of quartz clusters, as determined by Electron Backscatter Diffraction (EBSD), to test for crystal accumulation in the SLP. Clusters of quartz crystals with matched dipyramidal faces (parallel or Esterel twin orientation) may indicate a period of crystal accumulation. By analyzing representative samples from each section of the pluton, we found that the lower section (intermediate cumulate) and upper section (crystallization front) do not have quartz clusters with matched dipyramidal faces. Although plagioclase grains are aligned in the lower section, the late crystallization of quartz appears to have prevented aligned or preferred growth orientations. In contrast, the middle section has a high percentage of quartz clusters with matched dipyramidal faces - similar to that found in granite porphyry of the Vinalhaven pluton, Maine. The aligned grains may have formed by fractional crystallization, compaction and synneusis of the early forming quartz in this granitic section. We interpret the middle section of the Searchlight pluton as being similar to shallow, upper crustal plutons (3-8 km depth) such as Vinalhaven pluton. The deep vertical exposure of the SLP, shows that the middle section was formed from periodic episodes of

  10. Alkaline battery, separator therefore

    NASA Technical Reports Server (NTRS)

    Schmidt, George F. (Inventor)

    1980-01-01

    An improved battery separator for alkaline battery cells has low resistance to electrolyte ion transfer and high resistance to electrode ion transfer. The separator is formed by applying an improved coating to an electrolyte absorber. The absorber, preferably, is a flexible, fibrous, and porous substrate that is resistant to strong alkali and oxidation. The coating composition includes an admixture of a polymeric binder, a hydrolyzable polymeric ester and inert fillers. The coating composition is substantially free of reactive fillers and plasticizers commonly employed as porosity promoting agents in separator coatings. When the separator is immersed in electrolyte, the polymeric ester of the film coating reacts with the electrolyte forming a salt and an alcohol. The alcohol goes into solution with the electrolyte while the salt imbibes electrolyte into the coating composition. When the salt is formed, it expands the polymeric chains of the binder to provide a film coating substantially permeable to electrolyte ion transfer but relatively impermeable to electrode ion transfer during use.

  11. Crystal structure of modular sodium-rich and low-iron eudialyte from Lovozero alkaline massif

    NASA Astrophysics Data System (ADS)

    Rozenberg, K. A.; Rastsvetaeva, R. K.; Aksenov, S. M.

    2016-09-01

    The structure of the sodium-rich representative of the eudialyte group found by A.P. Khomyakov at the Lovozero massif (Kola Peninsula) is studied by X-ray diffraction. The trigonal cell parameters are: a = 14.2032(1) and c = 60.612(1) Å, V = 10589.13 Å3, space group R3m. The structure is refined to the final R = 5.0% in the anisotropic approximation of atomic displacement parameters using 3742|F| > 3σ( F). The idealized formula ( Z = 3) is Na37Ca10Mn2FeZr6Si50(Ti, Nb)2O144(OH)5Cl3 · H2O. Like other 24-layer minerals of the eudialyte group, this mineral has a modular structure. Its structure contains two modules, namely, "alluaivite" (with an admixture of "eudialyte") and "kentbrooksite," called according to the main structural fragments of alluaivite, eudialyte, and kentbrooksite. The mineral found at the Lovozero alkaline massif shows some chemical and symmetry-structural distinctions from the close-in-composition labyrinthite modular mineral from the Khibiny massif. The difference between the minerals stems from different geochemical conditions of mineral formation in the two regions.

  12. Pluton pinning of an active Miocene detachment fault system, eastern Mojave Desert, California

    NASA Astrophysics Data System (ADS)

    Davis, Gregory A.; Fowler, T. Kenneth; Bishop, Kim M.; Brudos, Thomas C.; Julio Friedmann, S.; Burbank, Douglas W.; Parke, Mary A.; Burchfiel, B. C.

    1993-07-01

    The Miocene Kingston Range-Halloran Hills detachment fault system of the eastern Mojave Desert, California, delineates part of the eastern breakaway zone for a profoundly extended area between the Sierra Nevada and the Spring Mountains structural blocks. The shallow-dipping, west-rooting detachment fault cuts discordantly across Paleozoic and Precambrian units in the Mesozoic foreland fold-and-thrust belt, exhibits west- to southwest-trending corrugations with structural relief of up to 1.5 km, and underlies the terrestrial Shadow Valley basin. Middle Miocene fault displacement and syntectonic sedimentation in the northern basin were terminated at ˜12.4 Ma by intrusion of the large (˜130 km2), shallow-level (≥4 km depth) Kingston Peak pluton across the detachment fault soon after faulting began. Basin sedimentation and fault displacement southeast of the pluton were not, however, disrupted by its emplacement and continued to evolve. Northern "pluton-pinned" and southern "pluton-free" domains were separated by the Blacksmith Hills fault, a northeast-striking, right-slip lateral ramp that accommodated more than 3 km of postpluton differential extension between pinned and nonpinned domains. In more western regions, late phases of detachment-fault-related extension beneath formerly pinned areas (including western and central parts of the pluton itself) are believed to have led to the development of two generations of east-striking left-slip faults. Collectively, these dextral and sinistral transfer faults illustrate the complex patterns of differential extension and accommodation that can characterize detachment-fault systems as adjacent areal domains of extension are generated and die.

  13. Structural interplay between plutons during the construction of a batholith (Cerro Aspero batholith, Sierras de Córdoba, Argentina)

    NASA Astrophysics Data System (ADS)

    Pinotti, Lucio; Tubía, José M.; D'Eramo, Fernando; Vegas, Néstor; Sato, Ana M.; Coniglio, Jorge; Aranguren, Aitor

    2006-05-01

    Magnetic fabric patterns and microstructures of granitic rocks provide evidence of structural modifications as a result of the coalescence of two plutons, Alpa Corral and Talita, during the construction of a large granitic batholith, Cerro Aspero, in the Sierras Pampeanas of Córdoba (Argentina). The Alpa Corral granite is a small and nearly circular pluton, while the larger Talita pluton displays a marked N-S elongation. The NW quadrangle of the Alpa Corral pluton underwent a deformation resulting in foliation trajectories that outline a crescent moon pattern whose inner arc is concordant with the Alpa Corral/Talita contact. The highest values for the magnetic susceptibility and its anisotropy are concentrated in the coalescence zone between both plutons. The magmatic and sub-magmatic nature of the microstructures demonstrates that such a deformation was caused by the southward overriding of the largest Talita pluton while the Alpa Corral pluton was not yet fully crystallized. Rb-Sr geochronology indicates that this process took place 369±9 Ma ago, long after the Famatinian (Ordovician to Early Devonian) deformation of the country rocks, which confirms a synmagmatic, rather than a regional, deformational event.

  14. U-Pb dating and emplacement history of granitoid plutons in the northern Sanandaj-Sirjan Zone, Iran

    NASA Astrophysics Data System (ADS)

    Mahmoudi, Shahryar; Corfu, Fernando; Masoudi, Fariborz; Mehrabi, Behzad; Mohajjel, Mohammad

    2011-05-01

    The Sanandaj-Sirjan Zone (SSZ), which runs parallel to the Zagros fold and thrust belt of Iran, underwent a multistage evolution starting with Neotethys initiation, its subsequent subduction below the Iranian continental crust, and eventual closure during convergence of Arabia towards central Iran. Plutonic complexes are well developed in the northern part of the SSZ and we have dated a number of them by ID-TIMS U-Pb on zircon. The new data record the following events: a Mid Jurassic period that formed the Boroujerd Plutonic Complex (169 Ma), the Astaneh Pluton (168 Ma) and the Alvand Pluton (165 Ma); Late Jurassic emplacement of the Gorveh Pluton (157-149 Ma); Mid Cretaceous (109 Ma) formation of a I-type phase in the Hasan Salary Pluton near Saqqez, followed by Early Paleocene (60 Ma) intrusion of A-type granite in the same pluton; and the youngest intrusive event recorded so far in the SSZ with the intrusion of granite in the Gosheh-Tavandasht Complex near Boroujerd at 34.9 Ma. These different events reflect specific stages of subduction-related magmatism prior to the eventual Miocene collision between the two continental blocks.

  15. Numerical modeling of forceful pluton emplacement and associated deformation at different crustal levels - instantaneous, continuous or episodic intrusion?

    NASA Astrophysics Data System (ADS)

    Chen, Y.; Nabelek, P. I.

    2015-12-01

    The Papoose Flat pluton in the White-Inyo Range, California, is one of the best examples of forceful magma emplacement at mid-crustal levels that is revealed by a highly strained aureole. A thermo-rheological 2-D model of the pluton and its aureole is proposed. We explored how the frequency of magma input, from instantaneous to continuous to the bottom of the laccolith, affects the ductile width of the aureole and the crystallinity of the pluton, which has implications for eruption of magma. We modeled these aspects at mid- and upper-crustal levels. The pluton was assumed to be 5 km thick in the middle and 13 km wide. Except for instantaneous growth, pluton was assumed to grow over 5 m.y. The aureole was assumed to have power-law rheology of quartz with dependence on H2O fugacity, which was calculated using the CORK equation (Holland & Powell, 1991) Our result shows that the bottom of the Papoose Flat pluton was emplaced at the brittle-ductile transition zone of the crust. The crustal rheology profile assisted the softening of rocks around the pluton. The simulated temperature and strength profiles confirm that ductile deformation was related to thermal weakening (Saint-Blanquat et al., 2001). Results of incremental growth calculations show that the pluton remains hot and only partially crystalline for millions of years when it grows by frequent input of small batches of liquid. At the mid-crustal level, the ductile region around the pluton is much wider and exists longer than at the shallow crustal level. Brittle rheology is dominant during the late stage growth at the shallow depth. When the pluton grows instantly or by only few episodes of large batches of input, the mobile part of the pluton is thin and the ductile aureole is narrower. High-frequency incremental growth by smaller magma batches produces a large volume of mobile magma that has the potential to induce internal magmatic layering that may be reflected in aligned acquired magnetic susceptibility (AMS

  16. Apatite trace element and halogen compositions as petrogenetic-metallogenic indicators: Examples from four granite plutons in the Sanjiang region, SW China

    NASA Astrophysics Data System (ADS)

    Pan, Li-Chuan; Hu, Rui-Zhong; Wang, Xin-Song; Bi, Xian-Wu; Zhu, Jing-Jing; Li, Chusi

    2016-06-01

    The abundances of trace elements including Sr, Ga and rare earth elements (REE) and halogens in apatite crystals from four intermediate-felsic plutons in the Zhongdian terrane in the Sanjiang region have been determined using electron microprobe and laser ablation inductively coupled plasma mass spectrometry to evaluate the potential of apatite as a petrogenic-metallogenic indicator. The selected plutons include one that is not mineralized (the Triassic Xiuwacu pluton, or the TXWC pluton), one that hosts a porphyry-type Cu deposit (the Pulang pluton, or the PL pluton), one that hosts a porphyry-type Mo deposit (the Tongchanggou pluton, or the TCG pluton), and one that hosts a vein-type Mo deposit (the Cretaceous Xiuwacu pluton, or the CXWC pluton). Except for the CXWC pluton, the other three plutons have adakite-like trace element signatures in whole rocks. The results from this study show that REE, Sr and halogens in apatite can be used to track magma compositions, oxidation states and crystallization history. Apatite crystals from the adakite-like plutons are characterized by much higher Sr/Y and δEu than the non-adakite-type pluton. This means that apatite, which is not susceptible to alteration, is a useful tool for identifying the adakite-like plutons that no longer preserve the initial Sr/Y ratios in whole rocks due to weathering and hydrothermal alteration. Based on apatite Ga contents and δEu values, it is inferred that the parental magmas for the two adakite-like plutons containing porphyry-type Cu and Mo mineralization are more oxidized than that for the non-adakite-type pluton containing vein-type Mo mineralization. Apatite crystals from the vein-type Mo deposit have much lower Cl/F ratios than those from the porphyry-type Cu and Mo deposits. Apatite crystals from the adakite-like pluton without Cu or Mo mineralization is characterized by much lower Cl/F ratios than those from the adakite-like plutons that host the porphyry-type Cu and Mo deposits. The

  17. Genesis and evolution of water in a two-mica pluton: A hydrogen isotope study

    USGS Publications Warehouse

    Brigham, R.H.; O'Neil, J.R.

    1985-01-01

    Measurements were made of the hydrogen isotope composition of 74 samples of muscovite, biotite, vein quartz and whole rocks from the Papoose Flat pluton, eastern California, U.S.A., and adjacent metamorphic and sedimentary rocks in order to elucidate the genesis and evolution of water and hydrous minerals in a two-mica granodiorite. Electron microprobe analyses were made of all micas so that the Suzuoki-Epstein equation could be used in evaluating the data. Based on experimental, theoretical and textural evidence of mica paragenesis, a model of hydrogen isotope fractionation between an aqueous vapor and a magma during crystallization has been constructed. This model accounts for the observed hydrogen isotope relations and implies that primary hydrogen isotope compositions have been preserved in a large portion of the pluton. The ?? D-values of biotites vary widely over the range -103 to -66% with most values lying between -90 and -70??? Muscovites, on the other hand, are isotopically more uniform and have ?? D-values of -61 to -41??? with most values lying between -50 and -46??? These data are consistent with the interpretation that biotite formed over a long period of crystallization whereas muscovite formed in a narrow interval, presumably during the final stages of crystallization when alumina and water contents were at their highest. Only 8 of the 21 muscovite-biotite pairs analyzed are in hydrogen isotope equilibrium as calculated from the Suzuoki-Epstein equation. Biotites in the western half of the pluton have relatively low ?? D-values of around -85???, whereas those in the eastern half have higher values of up to -66??? This pattern is a consequence of a loss of permeability associated with the syn-intrusive deformation of the western margin of the pluton. This loss of permeability enhanced the preservation of primary hydrogen isotope relations there by diverting water evolved from the magma out through the eastern half of the pluton where some deuteric

  18. Volcanic-Plutonic Connection in the Tilzapotla Caldera Ignimbrites in Southern Mexico

    NASA Astrophysics Data System (ADS)

    Martiny, B. M.; Moran Zenteno, D. J.; Roberge, J.; Zuñiga-Lagunes, L.; Flores-Huerta, D.; Solari, L.; Lopez-Martinez, M.

    2011-12-01

    Age and compositional similarities in broad exposures of volcanic and plutonic rocks in the central sector of the late Eocene-early Oligocene silicic volcanic province in southern Mexico provide an excellent opportunity for studying the genetic connection between the volcanic and plutonic realms. The Taxco-Tilzapotla sector is of particular interest given the presence of a NW-SE oriented elliptical dome structure (50 x 35 km) that encloses the Tilzapotla caldera, three medium-grained plutons one of which contains mafic magmatic enclaves, hypabyssal intrusive bodies, rhyolitic domes, and voluminous ignimbrites. North-south trending Laramide folds in Cretaceous marine sedimentary rocks were disrupted when late Eocene magmas intruded into the upper crust, forming the dome and producing opposite plunges in pre-dome fold axes north and south of the elliptical structure. We have obtained LA-ICPMS zircon U-Pb and Ar-Ar mineral ages as well as electron microscope analyses of different magmatic facies in order to: better understand the chronology of magmatic evolution in the area; examine the possible genetic relationship between the plutonic rocks and the principal ignimbritic units, in particular the crystal-rich units; and determine possible compositional differences that might suggest the injection of different batches of magma. U-Pb crystallization ages of 37-36 Ma were determined on zircons from different facies of the Coxcatlan granodiorite. Slightly younger zircon U-Pb crystallization ages were obtained for ignimbrites from the Tilzapotla caldera (36-35 Ma) and for the more mafic Chiautle pluton (34.6 Ma) that is exposed near the southern boundary of the dome structure. Earlier work by our group established caldera collapse and extrusion of the Tilzapotla ignimbrite at 34.3 Ma. Ar-Ar dating gives cooling ages of 33 Ma in sanidine for an intracaldera ignimbrite and some late stage silicic and intermediate magmas yielded mainly between 33-32 Ma. The new and previous

  19. Amphibole Thermometry and a Comparison of Results from Plutonic and Volcanic Systems

    NASA Astrophysics Data System (ADS)

    Sherman, T. M.; Putirka, K. D.; De Los Reyes, A. M. A.; Ratschbacher, B. C.

    2015-12-01

    Recent work (Ridolfi and Renzulli 2014) shows that amphiboles can be used to infer magmatic temperatures, even without knowledge of co-existing liquids. Here, we apply this approach, using new calibrations, to investigate felsic-mafic magma interactions, in a volcanic (Lassen Volcanic Center, a Cascade volcano) and plutonic (the Jurassic Guadalupe Igneous Complex) system. Preliminary data suggest that volcanic processes, as might be expected, preserve higher temperatures than plutonic materials (on average, volcanic amphiboles recorded 907±57.3°C while plutonic amphiboles recorded 764±59.7°C). We also find that the average T of a given mineral grain decreases with increased mineral size such that those crystallized below 800°C sometimes reach sizes beyond ~1mm, while those near 900°C appear truncated to ~0.3mm. It is not clear if T is the only control on amphibole crystal growth; however, our results would imply that larger grains not only require more time to grow but require continued undercooling. Significant cooling or heating is also recorded in many volcanically- and plutonically-grown grains, which may reflect transitioning between magmas of different T and composition. Core-to-rim cooling trends (with a common T of drop of 80oC) likely represent mafic-to-felsic magma transitions, whereas core-to-rim heating of similar magnitudes indicate a felsic-mafic transition. Some grains, though, exhibit a constant T (in the range 700-900°C) from core to rim, which perhaps indicates some shielding from magma mixing processes. Amphiboles might thus provide a reliable record of the intensity of magma mingling and mixing experienced by any particular enclave. Interestingly, volcanically-derived amphiboles appear to mostly record cooling towards the rims, while their plutonic counterparts tend to experience heating. It would thus appear that at Lassen, amphiboles are unaffected by later mafic magma recharge, but at the GIC, the plutonic amphiboles are more likely to

  20. The alkaline and alkaline-carbonatite magmatism from Southern Brazil

    NASA Astrophysics Data System (ADS)

    Ruberti, E.; Gomes, C. D. B.; Comin-Chiaramonti, P.

    2015-12-01

    Early to Late Cretaceous lasting to Paleocene alkaline magmatism from southern Brazil is found associated with major extensional structural features in and around the Paraná Basin and grouped into various provinces on the basis of several data. Magmatism is variable in size, mode of occurrence and composition. The alkaline rocks are dominantly potassic, a few occurrences showing sodic affinity. The more abundant silicate rocks are evolved undersaturated to saturated in silica syenites, displaying large variation in igneous forms. Less evolved types are restricted to subvolcanic environments and outcrops of effusive suites occur rarely. Cumulatic mafic and ultramafic rock types are very common, particularly in the alkali-carbonatitic complexes. Carbonatite bodies are represented by Ca-carbonatites and Mg-carbonatites and more scarcely by Fe-carbonatites. Available radiometric ages for the alkaline rocks fit on three main chronological groups: around 130 Ma, subcoveal with the Early Cretaceous flood tholeiites of the Paraná Basin, 100-110 Ma and 80-90 Ma (Late Cretaceous). The alkaline magmatism also extends into Paleocene times, as indicated by ages from some volcanic lavas. Geochemically, alkaline potassic and sodic rock types are distinguished by their negative and positive Nb-Ta anomalies, respectively. Negative spikes in Nb-Ta are also a feature common to the associated tholeiitic rocks. Sr-Nd-Pb systematics confirm the contribution of both HIMU and EMI mantle components in the formation of the alkaline rocks. Notably, Early and Late Cretaceous carbonatites have the same isotopic Sr-Nd initial ratios of the associated alkaline rocks. C-O isotopic Sr-Nd isotopic ratios indicate typical mantle signature for some carbonatites and the influence of post-magmatic processes in others. Immiscibility of liquids of phonolitic composition, derived from mafic alkaline parental magmas, has been responsible for the origin of the carbonatites. Close association of alkaline

  1. Soil organic carbon sequestration as affected by afforestation: the Darab Kola forest (north of Iran) case study.

    PubMed

    Kooch, Yahya; Hosseini, Seyed Mohsen; Zaccone, Claudio; Jalilvand, Hamid; Hojjati, Seyed Mohammad

    2012-09-01

    Following the ratification of the Kyoto Protocol, afforestation of formerly arable lands and/or degraded areas has been acknowledged as a land-use change contributing to the mitigation of increasing atmospheric CO(2) concentration in the atmosphere. In the present work, we study the soil organic carbon sequestration (SOCS) in 21 year old stands of maple (Acer velutinum Bioss.), oak (Quercus castaneifolia C.A. Mey.), and red pine (Pinus brutia Ten.) in the Darab Kola region, north of Iran. Soil samples were collected at four different depths (0-10, 10-20, 20-30, and 30-40 cm), and characterized with respect to bulk density, water content, electrical conductivity, pH, texture, lime content, total organic C, total N, and earthworm density and biomass. Data showed that afforested stands significantly affected soil characteristics, also raising SOCS phenomena, with values of 163.3, 120.6, and 102.1 Mg C ha(-1) for red pine, oak and maple stands, respectively, vs. 83.0 Mg C ha(-1) for the control region. Even if the dynamics of organic matter (OM) in soil is very complex and affected by several pedo-climatic factors, a stepwise regression method indicates that SOCS values in the studied area could be predicted using the following parameters, i.e., sand, clay, lime, and total N contents, and C/N ratio. In particular, although the chemical and physical stabilization capacity of organic C by soil is believed to be mainly governed by clay content, regression analysis showed a positive correlation between SOCS and sand (R = 0.86(**)), whereas a negative correlation with clay (R = -0.77(**)) was observed, thus suggesting that most of this organic C occurs as particulate OM instead of mineral-associated OM. Although the proposed models do not take into account possible changes due to natural and anthropogenic processes, they represent a simple way that could be used to evaluate and/or monitor the potential of each forest plantation in immobilizing organic C in soil (thus

  2. Timing and nature of tertiary plutonism and extension in the Grouse Creek Mountains, Utah

    USGS Publications Warehouse

    Egger, A.E.; Dumitru, T.A.; Miller, E.L.; Savage, C.F.I.; Wooden, J.L.

    2003-01-01

    The Grouse Creek-Albion-Raft River metamorphic core complex in northwestern Utah and southern Idaho is characterized by several Tertiary plutons with a range of ages and crosscutting relations that help constrain the timing of extensional deformation. In the Grouse Creek Mountains, at least three distinct, superimposed, extension-related Tertiary deformational events are bracketed by intrusive rocks, followed by a fourth event: motion on range-bounding faults. The Emigrant Pass plutonic complex was emplaced at depths of less than 10 km into Permianage rocks. SHRIMP U-Pb zircon analysis indicates a three-stage intrusion of the complex at 41.3 ?? 0.3 Ma, 36.1 ?? 0.2 Ma, and 34.3 ?? 0.3 Ma. The two youngest phases represent distinctly younger intrusive event(s) than the oldest phase, separated by more than 5 m.y. The oldest phase cuts several metamorphosed and deformed younger-on-older faults, providing a pre-41 Ma age bracket for oldest extension-related deformation in the region. The youngest phase(s) are interpreted to have been intruded during delelopment of a map-scale. N-S-trending recumbent fold, the Bovine Mountain fold, formed during vertical shortening of roof rocks during intrusion. This second event folded older normal faults that are likely pre-41 Ma. Zircons from the youngest part of the pluton show inheritance from Archean basement (???2.5 Ga) and from its Proterozoic sedimentary cover (???1.65 Ga). The Red Butte pluton, emplaced at 15-20 km depth, intruded highly metamorphosed Archean orthogneiss at 25.3 ?? 0.5 Ma; cores of some zircons yield latest Archean ages of 2.55 Ga. The pluton is interpreted to have been intruded during a third deformational and metamorphic event that resulted in vertical flattening fabrics formed during NW to EW stretching, ultimately leading to thinning of cover and top-to-the west motion on the Ingham Pass fault. The Ingham Pass fault represents an important structure in the Grouse Creek Mountains, as it juxtaposes two parts

  3. Hiding the Evidence: Growth of plutons by incremental emplacement of sheets in crystal mush

    NASA Astrophysics Data System (ADS)

    Miller, C. F.; Furbish, D. J.; Claiborne, L. L.; Walker, B. A.; Bleick, H. A.; Steinwinder, T. R.; Koteas, G. C.

    2006-12-01

    Growing evidence supports the notion that plutons are constructed incrementally, commonly over long periods of time, yet field evidence for the multiple injections that seem to be required is commonly sparse or absent (e.g. Glazner et al. 2004). Timescales of up to several million years, among other arguments, indicate that the dominant volume does not remain largely molten, yet if growing plutons are constructed from rapidly solidifying increments it is unlikely that intrusive contacts would escape notice. A model wherein magma increments are emplaced into crystal mush rather than either solid or crystal-poor material provides a plausible explanation for this apparent conundrum. A partially solidified intrusion undoubtedly comprises zones with contrasting melt fraction and therefore strength. The emplacement of dikes that intrude such a strength-zoned intrusion will be guided by the contrasts in the same way that dikes intruding solid media: magma spreads rather than continuing to propagate upward where it encounters a zone of higher rigidity (e.g. experiments by Kavanagh et al. 2006). We propose that ascending magma is in essence trapped by low-strength zones in plutonic mushes that are relatively melt-rich. In many cases, such zones may be subhorizontal and thus sill-like in geometry, but shapes and orientations could be highly variable, depending on the prior history of the composite intrusion. Contacts will commonly be obscure from the start because the contrast between intruding material (crystal-poorer magma) and host (crystal-richer mush) is subtle, and it may be obscured even further by subsequent destabilization of the mush. Field evidence and zircon zoning stratigraphy in plutons of the Colorado River region of southern Nevada support the hypothesis that emplacement of magma replenishments into a mush host is important in pluton construction. Except for highly fractionated dikes and sills, the dominant granite unit of the Spirit Mountain batholith

  4. Petrology and U-Pb geochronology of buried Avalonian plutonic rocks on southeastern Cape Cod

    USGS Publications Warehouse

    Leo, G.W.; Mortensen, J.K.; Barreiro, B.; Phillips, J.D.

    1993-01-01

    Plutonic rocks have been intersected by two separate drill holes on souteastern Cape Cod. Hole CC2 is located about 7 km south of the Nauset anomaly, an east-northeast-trending magnetic lineament that was considered to separate the distinct plutonic zones of Avalon terrane. This drill hole intersected weakly foliated, fairly homogeneous biotite granite. Zircons from this granite give a U-Pb age of 584+9/-8 Ma. Hole CC1 is located about 12 km north of the Nauset anomaly. The drill core intersected foliated, sheared, biotite granodiorite and biotite-hornblende-clinopyroxene-quartz gabbro, metamorphosed to greenschist facies. The deformed and altered state of these rocks, as well as their geochemistry, suggest that their origin and possibly their ages are distinct from the granite in hole CC2. No datable zircons were obtained from rocks in CC1. -from Authors

  5. An underground characterization program for a nuclear fuel waste disposal vault in plutonic rock

    SciTech Connect

    Thompson, P.M.; Everitt, R.A.

    1993-12-31

    The Canadian Nuclear Fuel Waste Management Program (CNFWMP) is developing a concept for disposing of nuclear fuel waste that involves placing and sealing it in a disposal vault excavated 500 to 1,000 m deep in the stable plutonic rock of the Canadian Shield. In this concept, engineered and natural barriers serve to isolate the waste from the biosphere. Since 1983, underground characterization and testing in support of the CNFWMP has been ongoing at the Underground Research Laboratory (URL) in southeastern Manitoba. This paper draws on experience gained at the URL to recommend an approach to underground characterization that would provide the necessary information to make design decisions for a disposal vault in plutonic rock.

  6. Pennsylvanian pluton stitching of Wrangellia and the Alexander terrane, Wrangell Mountains, Alaska

    SciTech Connect

    Gardner, M.C.; Bergman, S.C.; Cushing, G.W. ); Plafker, G. ); Campbell, R.B.; Dodds, C.J. ); McClelland, W.C. ); Mueller, P.A. ); MacKevett, E.M. Jr.

    1988-11-01

    A quartz monzonite-syenite-alkali granite plutonic complex in eastern Alaska crosscuts the contact of the Alexander terrane and Wrangellia and intrudes the basement rocks of both terranes. Zircon U-Pb data indicate an intrusion age of 309 {plus minus} 5 Ma (Middle Pennsylvanian) for the pluton, and {sup 40}K-{sup 40}Ar age for hornblende separates indicate cooling to about 450 C during Middle Pennsylvanian-Early Permian time. The new field relations and age data demonstrate the Wrangellia and the Alexander terrane were contiguous during the Middle Pennsylvanian. This conclusion provides an important new constraint on paleogeographic reconstructions of the northwest Cordillera, and necessitates reassessment of stratigraphic and paleomagnetic data that were cited as evidence that the terranes evolved separately until the late Mesozoic.

  7. River Valley pluton, Ontario - A late-Archean/early-Proterozoic anorthositic intrusion in the Grenville Province

    NASA Technical Reports Server (NTRS)

    Ashwal, Lewis D.; Wooden, Joseph L.

    1989-01-01

    This paper presents Nd, Sr, and Pb isotopic data indicating a late-Archean/early-Proterozoic age for the River Valley anorthositic pluton of the southwestern Grenville Province of Sudbury, Ontario. Pb-Pb isotopic data on 10 whole-rock samples ranging in composition from anorthosite to gabbro yield an age of 2560 + or - 155 Ma. The River Valley pluton is thus the oldest anorthositic intrusive yet recognized within the Grenville Province. The Sm-Nd isotopic system records an age of 2377 + or - 68 Ma. High Pb-208/Pb-204 of deformed samples relative to igneous-textured rocks implies Th introduction and/or U loss during metamorphism in the River Valley area. Rb-Sr data from igneous-textured and deformed samples and from mineral separates give an age of 2185 + or - 105 Ma, indicating substantial disturbance of the Rb-Sr isotopic system.

  8. Paleomagnetic results from seven middle Paleozoic plutons in the Appalachian Piedmont of North and South Carolina

    USGS Publications Warehouse

    Hagstrum, J.T.

    1983-01-01

    Seven isotopically dated plutons of similar middle Paleozoic age (approx. 400 Ma) were sampled for paleomagnetic study. The results from 12 sites (152 samples) within these plutons show two types of remanence behavior that appear fairly consistent with rock composition. The more leucocratic rocks (9 sites) tend to yield single-component magnetizations, of generally lower coercivities and blocking temperatures relative to the other units, that are considered to represent a recent viscous overprint, The mesocratic to melanocratic rocks show both single- and multicomponent magnetizations, the latter giving characteristic directions isolated through remagnetization-plane analysis. Three sites are considered reliable and yield paleomagnetic poles, of inferred Early Devonian age, that may reflect a 30? southward displacement from stable North America. One large site (25 samples) gives a remagnetized pole position of inferred Carboniferous age consistent with poles from North America, perhaps indicating that the Piedmont may have become part of the North American plate by this time.

  9. Geochemical study of Palong Pluton at Negeri Sembilan-Pahang border

    NASA Astrophysics Data System (ADS)

    Selamat Din, Khairil Izam Bin; Umor, Mohd Rozi

    2013-11-01

    The geochemical studies are carried out for igneous rocks from Palong Pluton at the border area of Negeri Sembilan and Pahang. The study area is about 250 km2, covering the area of Kemayan, Pasoh and Serting. The purposes of the geochemical study are to classify and determine the chemical characteristic of the granitic rocks, to correlate and interpret the crystallization history of igneous rocks, to determine the rock genesis and to determine the origin of magma. The Palong Pluton is divided into three groups, namely the Kemayan Granite, Serting Granite and Lui Granite. The geochemical data are presented by TAS and Harker Diagrams. The geochemical results show that Kemayan Granite, Serting Granite and Lui Granite are naturally originated from a single magma source. The magma evolution started from Kemayan Granite to Lui Granite and Serting Granite by differentiation proceses.

  10. Felsic plutonic rocks of the Midyan region, Kingdom of Saudi Arabia—I. Distribution, classification and resource potential

    NASA Astrophysics Data System (ADS)

    Ramsay, Colin R.; Drysdall, Alan R.; Clark, Malcolm D.

    About 80 large felsic plutons were emplaced in the Midyan region of the northwestern Arabian Shield between 725 and 570 Ma ago. Polymetallic mineralization, including Mo, Nb, REE, Sn, Ta, U, W and Zr, is associated with particular varieties. Five intrusive suites of regional extent and five other plutons have been identified. The oldest extensive unit is the Muwaylih suite, consisting of trondhjemite, tonalite, diorite and gabbro, with generally trondhjemitic compositional affinities and no known mineral potential. The most voluminous is the Ifal suite, a heterogeneous assemblage of biotite—hornblende monzogranite, granodiorite and quartz monzodiorite in large, oval to irregular plutons characterized by numerous intraplutonic dikes, but with no known mineral potential. The Ifal suite is intruded by plutons of the Atiyah monzogranite, with a variable number of dikes. The Muwaylih, Ifal and Atiyah suites are chemically metaluminous, but the Midyan suite consists of alkali granite to alkali-feldspar granite which is metaluminous to peralkaline. Large, irregular plutons of the Haql suite are composed of perthite leucogranite which is metaluminous to marginally peraluminous or peralkaline. Plutonic rock units of local significance include the Lawz complex, consisting of commonly granophyric syenogranite to monzogranite, the Mowasse quartz syenite and the Sawda (nepheline syenite) complex. Polymetallic Nb sbnd Zr deposits, such as those at Jabal Tawlah and Ghurayyah, are the most important known mineral resources and are related to alkali granite of the Midyan suite. Plumasitic specialized plutons, such as the Ratamah granite, have weak Sn sbnd W sbnd Ta sbnd Nb mineralization, and are related to the Haql suite. Apical and contact zones of plutons of these suites are favorable exploration target areas.

  11. Batievaite-(Y), Y2Ca2Ti[Si2O7]2(OH)2(H2O)4, a new mineral from nepheline syenite pegmatite in the Sakharjok massif, Kola Peninsula, Russia

    NASA Astrophysics Data System (ADS)

    Lyalina, L. M.; Zolotarev, A. A.; Selivanova, E. A.; Savchenko, Ye. E.; Krivovichev, S. V.; Mikhailova, Yu. A.; Kadyrova, G. I.; Zozulya, D. R.

    2016-12-01

    Batievaite-(Y), Y2Ca2Ti[Si2O7]2(OH)2(H2O)4, is a new mineral found in nepheline syenite pegmatite in the Sakharjok alkaline massif, Western Keivy, Kola Peninsula, Russia. The pegmatite mainly consists of nepheline, albite, alkali pyroxenes, amphiboles, biotite and zeolites. Batievaite-(Y) is a late-pegmatitic or hydrothermal mineral associated with meliphanite, fluorite, calcite, zircon, britholite-group minerals, leucophanite, gadolinite-subgroup minerals, titanite, smectites, pyrochlore-group minerals, zirkelite, cerianite-(Ce), rutile, behoite, ilmenite, apatite-group minerals, mimetite, molybdenite, and nickeline. Batievaite-(Y) is pale-cream coloured with white streak and dull, greasy or pearly luster. Its Mohs hardness is 5-5.5. No cleavage or parting was observed. The measured density is 3.45(5) g/cm3. Batievaite-(Y) is optically biaxial positive, α 1.745(5), β 1.747(5), γ 1.752(5) (λ 589 nm), 2 V meas. = 60(5)°, 2 V calc. = 65°. Batievaite-(Y) is triclinic, space group P-1, a 9.4024(8), b 5.5623(5), c 7.3784(6) Å, α 89.919(2), β 101.408(2), γ 96.621(2)°, V 375.65(6) Å3 and Z = 1. The eight strongest lines of the X-ray powder diffraction pattern [ d(Å)(I)( hkl)] are: 2.991(100)(11-2), 7.238(36)(00-1), 3.061(30)(300), 4.350(23)(0-1-1), 9.145(17)(100), 4.042(16)(11-1), 2.819(16)(3-10), 3.745(13)(2-10). The chemical composition determined by electron probe microanalysis (EPMA) is (wt.%): Nb2O5 2.25, TiO2 8.01, ZrO2 2.72, SiO2 29.96, Al2O3 0.56, Fe2O3 0.43, Y2O3 11.45, La2O3 0.22, Ce2O3 0.33, Nd2O3 0.02, Gd2O3 0.07, Dy2O3 0.47, Er2O3 1.07, Tm2O3 0.25, Yb2O3 2.81, Lu2O3 0.45, CaO 24.98, MnO 1.31, MgO 0.01, Na2O 1.13, K2O 0.02, F 2.88, Cl 0.19, H2O 6.75 (determined on the basis of crystal structure data), O = (F,Cl) -1.25, total 97.09 wt.%. The empirical formula based on the EPMA and single-crystal structure analyses is (Y0.81Ca0.65Mn0.15Zr0.12Yb0.11Er0.04Fe3+ 0.04Ce0.02Dy0.02Lu0.02La0.01Tm0.01)Σ2.00((H2O)0.75Ca0.70□0.55)Σ2.00Ca2.00(□0.61Na0

  12. Geochemical evaluation of felsic plutonic rocks in the eastern and southeastern Arabian Shield, Kingdom of Saudi Arabia

    USGS Publications Warehouse

    Du Bray, E.A.; Elliott, James E.; Stoeser, D.B.

    1983-01-01

    In a geochemical evaluation of the eastern and southeastern Arabian Shield, which included collection of 696 rock samples and 694 pan concentrate samples, a province of tin-anomalous granitoid plutons was defined. Pan concentrates collected in and around these plutons were enriched in tin and tungsten relative to the concentrate population. Rock samples of these leucocratic, muscovite-bearing, peraluminous granites contained anomalously high concentrations of lithium, fluorine, beryllium, lead, rubidium, niobium, yttrium, tin, bismuth, silver, and tungsten. Ten tin-anomalous plutons were located in the study area. The plutons are typically small, less than 10 km2 in areal extent, and circular to elliptical in plan view. The resource potential of these latest Proterozoic plutons has not been established; economically exploitable concentrations of tin, tungsten, molybdenum, or zinc may be present, and followup studies are warranted. Further, two of the plutons are characterized by higher than normal total-count radioactivity and have potential for uranium, thorium, or rare-earth element deposits.

  13. Multiple mafic and felsic magma interaction as exhibited in the Dartmouth Pluton, Avalon zone, southeastern Massachusetts

    SciTech Connect

    Hamidzada, N.A.; Hermes, O.D.; Murray, D.P. . Dept. of Geology)

    1993-03-01

    Dioritic to quartz monzonitic rocks of the Dartmouth Pluton exhibit excellently preserved, diverse features produced by mingling and mixing of mafic and felsic magma during multiple events. The related mafic and hybridized intermediate composition rocks occur both as discrete outcrop-sized masses or as enclaves within quartz monzonite or early-stage mixed rocks. Enclaves are rounded, lack chilled margins, and in some cases exhibit cuspate margins; they range in size from 1m--<1cm. Outcrops dominated by dioritic rock consist of well developed mafic pillows with inter-pillow infillings of hybridized rock that had been subjected to magma mixing during or prior to the final mingling process. Dioritic rocks are fine-grained with sparse plagioclase phenocrysts; they contain small, darker-colored enclaves indicative of preceding magma interaction. Major and trace element variation diagrams for this suite of rocks exhibit general linear trends consistent with mixing processes. Overall, field, petrographic, and geochemical relationships in the Dartmouth Pluton demonstrate: (1) widespread mingling of mafic and felsic magma, (2) variable degrees of mafic and felsic magma mixing, and (3) multiple and repeated episodes of mafic and felsic magma interaction. Significantly, some spatially associated dioritic and granitic rocks, including a 595 Ma alkali feldspar granite formerly considered to be part of the Dartmount Pluton, are geochemically related. Field mapping demonstrates that rocks of the mixed suite are intrusive into these rocks, thus establishing a maximum age, but raising the questions that the suite may be considerably younger.

  14. Erupted frothy xenoliths may explain lack of country-rock fragments in plutons

    PubMed Central

    Burchardt, Steffi; Troll, Valentin R.; Schmeling, Harro; Koyi, Hemin; Blythe, Lara

    2016-01-01

    Magmatic stoping is discussed to be a main mechanism of magma emplacement. As a consequence of stoping, abundant country-rock fragments should occur within, and at the bottom of, magma reservoirs as “xenolith graveyards”, or become assimilated. However, the common absence of sufficient amounts of both xenoliths and crustal contamination have led to intense controversy about the efficiency of stoping. Here, we present new evidence that may explain the absence of abundant country-rock fragments in plutons. We report on vesiculated crustal xenoliths in volcanic rocks that experienced devolatilisation during heating and partial melting when entrained in magma. We hypothesise that the consequential inflation and density decrease of the xenoliths allowed them to rise and become erupted instead of being preserved in the plutonic record. Our thermomechanical simulations of this process demonstrate that early-stage xenolith sinking can be followed by the rise of a heated, partially-molten xenolith towards the top of the reservoir. There, remnants may disintegrate and mix with resident magma or erupt. Shallow-crustal plutons emplaced into hydrous country rocks may therefore not necessarily contain evidence of the true amount of magmatic stoping during their emplacement. Further studies are needed to quantify the importance of frothy xenolith in removing stoped material. PMID:27804996

  15. Erupted frothy xenoliths may explain lack of country-rock fragments in plutons

    NASA Astrophysics Data System (ADS)

    Burchardt, Steffi; Troll, Valentin R.; Schmeling, Harro; Koyi, Hemin; Blythe, Lara

    2016-11-01

    Magmatic stoping is discussed to be a main mechanism of magma emplacement. As a consequence of stoping, abundant country-rock fragments should occur within, and at the bottom of, magma reservoirs as “xenolith graveyards”, or become assimilated. However, the common absence of sufficient amounts of both xenoliths and crustal contamination have led to intense controversy about the efficiency of stoping. Here, we present new evidence that may explain the absence of abundant country-rock fragments in plutons. We report on vesiculated crustal xenoliths in volcanic rocks that experienced devolatilisation during heating and partial melting when entrained in magma. We hypothesise that the consequential inflation and density decrease of the xenoliths allowed them to rise and become erupted instead of being preserved in the plutonic record. Our thermomechanical simulations of this process demonstrate that early-stage xenolith sinking can be followed by the rise of a heated, partially-molten xenolith towards the top of the reservoir. There, remnants may disintegrate and mix with resident magma or erupt. Shallow-crustal plutons emplaced into hydrous country rocks may therefore not necessarily contain evidence of the true amount of magmatic stoping during their emplacement. Further studies are needed to quantify the importance of frothy xenolith in removing stoped material.

  16. Erupted frothy xenoliths may explain lack of country-rock fragments in plutons.

    PubMed

    Burchardt, Steffi; Troll, Valentin R; Schmeling, Harro; Koyi, Hemin; Blythe, Lara

    2016-11-02

    Magmatic stoping is discussed to be a main mechanism of magma emplacement. As a consequence of stoping, abundant country-rock fragments should occur within, and at the bottom of, magma reservoirs as "xenolith graveyards", or become assimilated. However, the common absence of sufficient amounts of both xenoliths and crustal contamination have led to intense controversy about the efficiency of stoping. Here, we present new evidence that may explain the absence of abundant country-rock fragments in plutons. We report on vesiculated crustal xenoliths in volcanic rocks that experienced devolatilisation during heating and partial melting when entrained in magma. We hypothesise that the consequential inflation and density decrease of the xenoliths allowed them to rise and become erupted instead of being preserved in the plutonic record. Our thermomechanical simulations of this process demonstrate that early-stage xenolith sinking can be followed by the rise of a heated, partially-molten xenolith towards the top of the reservoir. There, remnants may disintegrate and mix with resident magma or erupt. Shallow-crustal plutons emplaced into hydrous country rocks may therefore not necessarily contain evidence of the true amount of magmatic stoping during their emplacement. Further studies are needed to quantify the importance of frothy xenolith in removing stoped material.

  17. Cryogenian alkaline magmatism in the Southern Granulite Terrane, India: Petrology, geochemistry, zircon U-Pb ages and Lu-Hf isotopes

    NASA Astrophysics Data System (ADS)

    Santosh, M.; Yang, Qiong-Yan; Ram Mohan, M.; Tsunogae, T.; Shaji, E.; Satyanarayanan, M.

    2014-11-01

    The Southern Granulite Terrane (SGT) in India preserves the records of the formation and recycling of continental crust from Mesoarchean through Paleoproterozoic to Neoproterozoic and Cambrian, involving multiple subduction-accretion-collision associated with major orogenic cycles. A chain of unmetamorphosed and undeformed alkaline magmatic intrusions occurs along the northern margin of the SGT aligned along paleo-suture zones. Here we investigate two representative plutons from this suite, the Angadimogar syenite (AM) and the Peralimala alkali granite (PM) through field, petrological, geochemical, zircon U-Pb and Lu-Hf studies. Magma mixing and mingling textures and mineral assemblages typical of alkaline rocks are displayed by these plutons. The whole-rock major and trace element data characterize their alkaline nature. In trace element discrimination diagrams, the AM rocks straddle between the VAG (volcanic-arc granites) and WPG (within plate granites) fields with most of the samples confined to the VAG field, whereas the PM rocks are essentially confined to the WPG field. The diversity in some of the geochemical features between the two plutons is interpreted to be the reflection of source heterogeneities. Most zircon grains from the AM and PM plutons display oscillatory zoning typical of magmatic crystallization although some grains, particularly those from the PM pluton, show core-rim structures with dark patchy zoned cores surrounded by irregular thin rims resulting from fluid alteration. The weighted mean 206Pb/238U ages of the magmatic zircons from three samples of the AM syenite are in the range of 781.8 ± 3.8 Ma to 798 ± 3.6 Ma and those from two samples of the PM alkali granite yield ages of 797.5 ± 3.7 Ma and 799 ± 6.2 Ma. A mafic magmatic enclave from the AM pluton shows weighted mean 206Pb/238U age of 795 ± 3.3 Ma. The AM and PM plutons also carry rare xeneocrystic zircons which define upper intercept concordia ages of 3293 ± 13 Ma and 2530

  18. Early Paleozoic subduction processes of the Paleo-Asian Ocean: Insights from geochronology and geochemistry of Paleozoic plutons in the Alxa Terrane

    NASA Astrophysics Data System (ADS)

    Liu, Qian; Zhao, Guochun; Sun, Min; Han, Yigui; Eizenhöfer, Paul R.; Hou, Wenzhu; Zhang, Xiaoran; Zhu, Yanlin; Wang, Bo; Liu, Dongxing; Xu, Bing

    2016-10-01

    The Alxa Terrane is situated in a key area between the North China and Tarim cratons. Paleozoic magmatic records in this terrane place important constraints on the subduction processes of the southern Paleo-Asian Ocean. New data of zircon U-Pb ages and whole-rock elemental and isotopic data reveal two groups of intermediate to felsic plutons in the Alxa Terrane. One group consists of diorites and granitoids that were emplaced at ca. 460-440 Ma and characterized by lower Al2O3/TiO2 ratios and higher TiO2 contents, implying high temperature-low pressure crystallization conditions and a shallow source region. The second group is dominated by granitoids aged at ca. 420-407 Ma and displays high Sr and Ba, low Y and high rare earth elements, with very high Sr/Y ratios and mostly positive Eu anomalies. These characteristics imply low temperature-high pressure crystallization conditions and source regions at deep crustal levels where garnet is stable in the residual phase. Both of the two groups are mostly calc-alkaline to high-K calc-alkaline, depleted in Nb, Ta and Ti and enriched in Ba, K and Sr, indicative of an arc affinity most likely related to the southward subduction of the Paleo-Asian Ocean. Zircon εHf(t) and whole-rock εNd(t) values of these magmatic rocks decrease from 458 Ma to 440 Ma and increase from 417 Ma to 407 Ma, whereas whole-rock initial 87Sr/86Sr ratios display an opposite trend. Such an isotopic change suggests a tectonic switch from an advancing to a retreating subduction regime at 407 Ma. Synthesized data from this and previous studies suggest that the 460-400 Ma magmatic arc in the Alxa Terrane represented the western extension of the Paleozoic arc belt on the northern margin of the North China Craton.

  19. From Migmatites to Plutons: Power Law Relationships in the Evolution of Magmatic Bodies

    NASA Astrophysics Data System (ADS)

    Soesoo, Alvar; Bons, Paul D.

    2015-07-01

    Magma is generated by partial melting from micrometre-scale droplets at the source and may accumulate to form >100 km-scale plutons. Magma accumulation thus spans well over ten orders of magnitude in scale. Here we provide measurements of migmatitic leucosomes and granitic veins in drill cores from the Estonian Proterozoic basement and outcrops at Masku in SW Finland and Montemor-o-Novo, central Portugal. Despite the differences in size and number of measured leucosomes and magmatic veins, differences in host rock types and metamorphic grades, the cumulative width distribution of the studied magmatic leucosomes/veins follows a power law with exponents usually between 0.7 and 1.8. Published maps of the SE Australian Lachlan Fold Belt were used to investigate the distribution of granitoid pluton sizes. The granites occupy ca. 22 % of the 2.6 × 105 km2 area. The cumulative pluton area distributions show good power law distributions with exponents between 0.6 and 0.8 depending on pluton area group. Using the self-affine nature of pluton shapes, it is possible to estimate the total volume of magma that was expelled from the source in the 2.6 × 105 km2 map area, giving an estimated 0.8 km3 of magma per km2. It has been suggested in the literature that magma batches in the source merge to form ever-bigger batches in a self-organized way. This leads to a power law for the cumulative distribution of magma volumes, with an exponent m V between 1 for inefficient melt extraction, and 2/3 for maximum accumulation efficiency as most of the volume resides in the largest batches that can escape from the source. If m V ≥ 1, the mass of the magma is dominated by small batches; in case m = 2/3, about 50 % of all magma in the system is placed in a single largest batch. Our observations support the model that the crust develops a self-organized critical state during magma generation. In this state, magma batches accumulate in a non-continuous, step-wise manner to form ever

  20. Geochemistry and petrogenesis of late Ediacaran (605-580 Ma) post-collisional alkaline rocks from the Katherina ring complex, south Sinai, Egypt

    NASA Astrophysics Data System (ADS)

    Azer, M. K.; Obeid, M. A.; Ren, M.

    2014-10-01

    The Katherina ring complex (KRC) in the central part of south Sinai, Egypt, is a typical ring complex of late Neoproterozoic age (605-580 Ma). It was developed during the final tectono-magmatic stage of the north Arabian-Nubian Shield (ANS) during evolution of the Pan-African crust. The KRC includes Katherina volcanics, subvolcanic bodies, ring dykes and Katherina granitic pluton. The Katherina volcanics represent the earliest stage of the KRC, which was subsequently followed by emplacement of the subvolcanic bodies and ring dykes. The Katherina granitic pluton depicts as the latest evolution stage of the KRC that intruded all the early formed rock units in the concerned area. The Katherina volcanics are essentially composed of rhyolites, ignimbrite, volcanic breccia and tuffs. Mineralogically, the peralkaline rhyolites contain sodic amphiboles and aegirine. The rhyolite whole rock chemistry has acmite-normative character. The subvolcanic bodies of the KRC are represented by peralkaline microgranite and porphyritic quartz syenite. The ring dykes are semicircular in shape and consist mainly of quartz syenite, quartz trachyte and trachybasalt rock types. The Katherina subvolcanic rocks, volcanic rocks as well as the ring dykes are alkaline or/and peralkaline in nature. The alkaline granitic pluton forms the inner core of the KRC, including the high mountainous areas of G. Abbas Pasha, G. Bab, G. Katherina and G. Musa. These mountains are made up of alkaline syenogranite and alkali feldspar granite. The mantle signature recorded in the KRC indicates a juvenile ANS crust partial melting process for the generation of this system. The evolution of the KRC rocks is mainly dominated by crystal fractionation and crustal contamination. Mineral geothermometry points to the high temperature character of the KRC, up to 700-1100 °C.

  1. Effect of gavage treatment with pulverised Garcinia kola seeds on erythrocyte membrane integrity and selected haematological indices in male albino Wistar rats.

    PubMed

    Ahumibe, A A; Braide, V B

    2009-06-01

    This study examines the effect of the whole seed of Garcinia kola [GKS] on various blood parameters, in adult male albino rats. Five groups, of 6 animals per group, were treated by gavage with suspensions of graded concentrations of GKS daily for 5 weeks. The animals were then sacrificed and blood was obtained for estimation of the data herein presented. Packed red cell volume [PCV], hemoglobin concentration [Hb], and red blood cell count [RBC] showed significantly [P<0.05], increased response to treatment with GKS; while the platelet and white blood cell [WBC] counts showed no corresponding increase with increasing GKS dosage. The mean red blood cell volume [MCV] and mean cell hemoglobin [MCH] levels decreased with increasing GKS dosage. Prothrombin time [PT] and activated partial thromboplastin time [APPT] were both prolonged with increased GKS dosage; while the serum lipids (cholesterol and triglycerides) decreased significantly [P<0.05] with increased GKS dosage.

  2. Evaluation of the dust and methanol extracts of Garcinia kolae for the control of Callosobruchus maculatus (F.) and Sitophilus zeamais (Mots).

    PubMed

    Ogunleye, R F; Adefemi, S O

    2007-12-01

    Insecticidal effects of different doses of the dust and methanol extracts of Garcinia kolae on Callosobruchus maculatus and Sitophilus zeamais were tested. The dust had no significant effect on the two insects; none of them died even at 3 d after treatment. The methanol extracts, however, had rapid lethal effects on both C. maculatus and S. zeamais. The mortality of C. maculatus by the lowest concentration of methanol extracts ranged from 95%~100% whereas in S. zeamais, the mortality ranged from 87.5% to approximately 100% and 70% to approximately 100% in concentrations of 1 g extract+3 ml methanol and 1 g extract+5 ml methanol, respectively, from 24 to 48 h. The least concentration of 1 g extract+15 ml methanol had no significant lethal effect on Sitophilus zeamais.

  3. Zinc electrode in alkaline electrolyte

    SciTech Connect

    McBreen, J.

    1995-12-31

    The zinc electrode in alkaline electrolyte is unusual in that supersaturated zincate solutions can form during discharge and spongy or mossy zinc deposits can form on charge at low overvoltages. The effect of additives on regular pasted ZnO electrodes and calcium zincate electrodes is discussed. The paper also reports on in situ x-ray absorption (XAS) results on mossy zinc deposits.

  4. Was the Devonian geomagnetic field dipolar or multipolar? Palaeointensity studies of Devonian igneous rocks from the Minusa Basin (Siberia) and the Kola Peninsula dykes, Russia

    NASA Astrophysics Data System (ADS)

    Shcherbakova, V. V.; Biggin, A. J.; Veselovskiy, R. V.; Shatsillo, A. V.; Hawkins, L.; Shcherbakov, V. P.; Zhidkov, G. V.

    2017-02-01

    Defining variations in the behaviour of the geomagnetic field through geological time is critical to understanding the dynamics of Earth's core and its response to mantle convection and planetary evolution. Furthermore, the question of whether the axial dipole dominance of the recent palaeomagnetic field persists through the whole of Earth's history is fundamental to determining the reliability of palaeogeographic reconstructions and the efficacy of the magnetosphere in shielding Earth from solar wind radiation. Previous palaeomagnetic directional studies have suggested that the palaeofield had a complex configuration in the Devonian period (419-359 Ma). Here we present new palaeointensity determinations from rocks aged between 408 and 375 Ma from the Minusa Basin (southern Siberia), and the Kola Peninsula to investigate the strength of the field during this enigmatic period. Palaeointensity experiments were performed using the thermal Thellier, microwave Thellier, and Wilson methods on 165 specimens from 25 sites. Six out of eight successful sites from the Minusa Basin and all four successful sites from the Kola Peninsula produced extremely low palaeointensities (< 10 μT). These findings challenge the uniformitarian view of the palaeomagnetic field: field intensities of nearly an order of magnitude lower than Neogene values (except during relatively rare geomagnetic excursions and reversals) together with the widespread appearance of strange directions found in the Devonian suggest that the Earth's field during this time may have had a dominantly multipolar geometry. A persistent, low intensity multipolar magnetic field and associated diminished magnetosphere would increase the impact of solar particles on the Earth's magnetosphere, ionosphere and atmosphere with potential major implications for Earth's climate and biosphere.

  5. Intrusive rocks of the Holden and Lucerne quadrangles, Washington; the relation of depth zones, composition, textures, and emplacement of plutons

    USGS Publications Warehouse

    Cater, Fred W.

    1982-01-01

    The core of the northern Cascade Range in Washington consists of Precambrian and upper Paleozoic metamorphic rocks cut by numerous plutons, ranging in age from early Triassic to Miocene. The older plutons have been eroded to catazonal depths, whereas subvolcanic rocks are exposed in the youngest plutons. The Holden and Lucerne quadrangles span a -sizeable and representative part of this core. The oldest of the formations mapped in these quadrangles is the Swakane Biotite Gneiss, which was shown on the quadrangle maps as Cretaceous and older in age. The Swakane has yielded a middle Paleozoic metamorphic age, and also contains evidence of zircon inherited from some parent material more than 1,650 m.y. old. In this report, the Swakane is assigned an early Paleozoic or older age. It consists mostly of biotite gneiss, but interlayered with it are scattered layers and lenses of hornblende schist and gneiss, clinozoisite-epidote gneiss, and quartzite. Thickness of the Swakane is many thousands of meters, and the base is not exposed. The biotite gneiss is probably derived from a pile of siliceous volcanic rocks containing scattered sedimentary beds and basalt flows. Overlying the Swakane is a thick sequence of eugeosynclinal upper Paleozoic rocks metamorphosed to amphibolite grade. The sequence includes quartzite and thin layers of marble, hornblende schist and gneiss, graphitic schist, and smaller amounts of schist and gneiss of widely varying compositions. The layers have been tightly and complexly folded, and, in places, probably had been thrust over the overlying Swakane prior to metamorphism. Youngest of the supracrustal rocks in the area are shale, arkosic sandstone, and conglomerate of the Paleocene Swauk Formation. These rocks are preserved in the Chiwaukum graben, a major structural element of the region. Of uncertain age, but possibly as old as any of the intrusive rocks in the area, are small masses of ultramafic rocks, now almost completely altered to

  6. The features of element concentration in natural waters of the Kola North in conditions of environmental contamination

    NASA Astrophysics Data System (ADS)

    Bazova, Mariya; Moiseenko, Tatyana

    2016-04-01

    The intensive use of fossil fuels and industrial development in last century led to the formation of acid rain and water acidification. The problem of water acidification greatly was denoted in the middle of last century in North America and in Europe as a result of air emissions of acid gases, primarily sulfur dioxide. The process of water acidification due to the interaction of two factors: 1) the high deposition of acidifying substances, taking into account the duration of exposure; 2) the sensitivity of the natural catchment area of geological, landscape, geographic and climatic characteristics (Moiseenko, 2005). The effects of acid rains on metal migration and cycling were discussed in a number of previous studies (Jeffries, 1997; Moiseenko, 1999; Manio, 2001; Moiseenko, Gashkina, 2007). The distribution of elements in water lakes has been mixed and due to the change of geochemical cycles of elements occurring in the catchment area and in water. On the Kola Peninsula as a result of long-term operation of the copper-nickel smelter was the anthropogenic acidification and water pollution metals. Increased contents of elements due to the combined effect of three factors: 1) landscape-geochemical characteristics of watersheds; 2) dispersion with flue emissions; 3) leaching elements and bonding of metals with organic matter, especially in forested watersheds and wetlands. This region is subject to long-term effects of mining and smelting industries, and therefore difficult to find of water bodies, which can serve as a background lakes. It is proved that manmade acid rain lead to leach into the water of a large group of elements entering the water as a result of man-made streams, as well as the elements that consist of the rocks forming the watersheds. In order to identify the relationships between the components of the elemental composition of the water in the lake was made a factor analysis using a computer program «STATISTICA 10". Factor analysis revealed the

  7. Multiple intrusive events in the formation of granite plutons: Evidence from the Lee Vining Diorite, eastern California

    SciTech Connect

    McCarthy, T.C.; Furman, T. . Dept. of Environmental Sciences); Reid, J.B. Jr. . School of Natural Sciences)

    1993-03-01

    The Cretaceous Lee Vining Diorite (eastern Sierra Nevada) preserves important field, petrographic and geochemical evidence for complex intrusive events in a mesozonal magma body. The pluton comprises primarily light grey unfoliated quartz diorite, with color index varying between 10--50. A 1,400 m transect across the pluton yielded samples of (1) mafic diorite from a 300 m thick sill, (2) disaggregated basaltic dikes, (3) rounded mafic inclusions and (4) rounded hornblende-cumulate inclusions in addition to (5) quartz diorite of variable texture and color index. Internal intrusive contacts are observed in several places; the upper contact of the sill is indistinct locally, suggesting a low thermal contrast with host quartz diorite at the time of intrusion. Textural analysis of plagioclase crystals form throughout the pluton indicates a history of pervasive magma mixing. In each thin section, 20--90% of the plagioclase crystals are pitted or corroded, and up to 50% of these crystals are also completely zoned. Disequilibrium plagioclase crystals are not preferentially associated with mafic inclusion, but are distributed randomly within the pluton. Major and trace element analyses of over 40 samples taken along the transect show variations that cannot be explained through simple magma mixing or through progressive crystallization of a single magma body. The pluton is not zoned geochemically, but rather comprises small regions (< 200 m across) of uniform composition that are juxtaposed randomly. Chemical variations across the pluton likely result from both missing of small magma batches and fractional crystallization of mixed magmas. This interpretation is consistent with field and textural requirements for multiple intrusive episodes in the formation of the diorite pluton.

  8. Fractionation of Zr and Hf during the differentiation of peralkaline magmatic system (Lovozero rare metal deposit, Kola Peninsula)

    NASA Astrophysics Data System (ADS)

    Kogarko, Liya

    2016-04-01

    Zirconium and hafnium are valuable strategic metals. We assessed principal features of the distribution of these elements in peralkaline rocks, ores and rock-forming and accessory minerals of Lovozero complex. The accumulation of these elements during the evolution of alkaline magma of Lovozero deposit up to extremely high concentrations in eudialyte ores (5-8% ZrO2 and 1200-1800 ppm Hf) has been established. These ores represent valuable complex raw material not only for Zr and Hf, but for REE as well. We evaluated partition coefficients of these elements in alkaline pyroxenes (aegirines) from porphyry-like agpaitic lujavrites of Lovozero massif which are 0.40 for zirconium and 0.58 for hafnium. We assessed variations of Zr/Hf ratio for all the rocks of Lovozero alkaline massif. The growth of this ratio in the course of the evolution of alkaline magma has been observed from 38 in the earliest magmatic phase, to 44 in the second phase and to 51-53 in the latest manifestation of alkaline magmatsm. On the basis of the obtained data and equations of equilibrium and fractional crystallization the model of the fractionation of zirconium and hafnium during the evolution of Lovozero intrusion has been constructed. We have demonstrated that the source of strongly enriched magmatic systems similar to Lovozero rare metal deposit is short-lived enriched reservoir - metasomatized and carbonatized mantle substrate. We investigated the fractionation of zirconium and hafnium in carbonatized mantle xenoliths from East Antarctica. The elevated Zr/Hf ratios (up to 125) in metasomatized xenoliths by comparison with the chondritic value have been found. The main reactions of carbonate metasomatism lead to the replacement of primary orthopyroxene by clinopyroxene 2Mg2Si2O6 + CaMg(CO3)2 = 2Mg2SiO4 + CaMgSi2O6 + 2CO2 3CaMg(CO3)2 + CaMgSi2O6 = 4CaCO3 + 2Mg2SiO4 + 2CO2 The substantial expansion of the clinopyroxene crystallization field results in increase of Zr/Hf ratio in equilibrium

  9. The Middle Fork Plutonic Complex: A plutonic association of coeval peralkaline and metaluminous magmas in the north-central Alaska Range

    SciTech Connect

    Solie, D.N.

    1988-01-01

    The 57 m.y. Middle Fork Plutonic Complex (MFPC) intrudes Paleozoic metasedimentary rocks south of the Farewell Fault zone in the north-central Alaska Range. Though spatially related to the late Cretaceous - Early Tertiary subduction-related Alaska Range batholith, MFPC is more characteristic of an extensional or anorogenic setting. A swarm of basalt, hawaiite and rhyolite dikes east of the complex intruded, and was intruded by, the plutonic rocks. Approximately 30% of the exposed rock in the 125 km[sup 2] complex is hedenbergite - fayalite syenite, [approx equal]20% is peralkalin arfvedsonite-biotite alkali-feldspar granite (AF granite), and [le]20% is pyroxene-olivine-biotite gabbro. The rest is a mixed unit including clinopyroxene-biotite-amphibole diorite, and hornblende-biotite granite (HB granite). K-Ar and Rb-Sr radiometric dating of rock types shows that they are coeval. Their close spatial and temporal relationships led to complex magmatic interactions. Calculated initial [sup 87]Sr/[sup 86]Sr for gabbro and diorite group is around 0.705 to 0.706. HB granites are heterogeneous, but fall mostly around 0.707 to 0.708. Hypersolvus syenites and AF granites form an isochron with initial [sup 87]Sr/[sup 86]Sr of 0.70965. These groupings suggest that at least three different magmas formed the MFPC; scatter of isotopic data reflects mutual contamination and assimilation. Consanguinous hypersolvus syenite and AF granite mineralogy appears to be controlled by fluorine in the magma chamber. Eruptive stratigraphy, as predicted by intrusive history of MFPC, compares favorably with volcanic stratigraphies of peralkaline volcanic systems worldwide, and MFPC may be modelled as the root zone of a peralkaline volcanic system.

  10. Nucleotide sequences encoding a thermostable alkaline protease

    DOEpatents

    Wilson, David B.; Lao, Guifang

    1998-01-01

    Nucleotide sequences, derived from a thermophilic actinomycete microorganism, which encode a thermostable alkaline protease are disclosed. Also disclosed are variants of the nucleotide sequences which encode a polypeptide having thermostable alkaline proteolytic activity. Recombinant thermostable alkaline protease or recombinant polypeptide may be obtained by culturing in a medium a host cell genetically engineered to contain and express a nucleotide sequence according to the present invention, and recovering the recombinant thermostable alkaline protease or recombinant polypeptide from the culture medium.

  11. Nucleotide sequences encoding a thermostable alkaline protease

    DOEpatents

    Wilson, D.B.; Lao, G.

    1998-01-06

    Nucleotide sequences, derived from a thermophilic actinomycete microorganism, which encode a thermostable alkaline protease are disclosed. Also disclosed are variants of the nucleotide sequences which encode a polypeptide having thermostable alkaline proteolytic activity. Recombinant thermostable alkaline protease or recombinant polypeptide may be obtained by culturing in a medium a host cell genetically engineered to contain and express a nucleotide sequence according to the present invention, and recovering the recombinant thermostable alkaline protease or recombinant polypeptide from the culture medium. 3 figs.

  12. Plutonism in the central part of the Sierra Nevada Batholith, California

    USGS Publications Warehouse

    Bateman, Paul C.

    1992-01-01

    The Sierra Nevada batholith comprises the plutonic rocks of Mesozoic age that underlie most of the Sierra Nevada, a magnificent mountain range that originated in the Cenozoic by the westward tilting of a huge block of the Earth's crust. Scattered intrusions west of the batholith in the western metamorphic belt of the Sierra Nevada and east of the Sierra Nevada in the Benton Range and the White and Inyo Mountains are satellitic to but not strictly parts of the Sierra Nevada batholith. Nevertheless, all the plutonic rocks are related in origin. The batholith lies along the west edge of the Paleozoic North American craton, and Paleozoic and early Mesozoic oceanic crust underlies its western margin. It was emplaced in strongly deformed but weakly metamorphosed strata ranging in age from Proterozoic to Cretaceous. Sedimentary rocks of Proterozoic and Paleozoic age crop out east of the batholith in the White and Inyo Mountains, and metamorphosed sedimentary and volcanic rocks of Paleozoic and Mesozoic age crop out west of the batholith in the western metamorphic belt. A few large and many small, generally elongate remnants of metamorphic rocks lie within the batholith. Sparse fossils from metasedimentary rocks and isotopic ages for metavolcanic rocks indicate that the metamorphic rocks in the remnants range in age from Early Cambrian to Early Cretaceous. Within the map area (the Mariposa 1 0 by 2 0 quadrangle), the bedding, cleavage, and axial surfaces of folds generally trend about N. 35 0 W., parallel to the long axis of the Sierra Nevada. The country rocks comprise strongly deformed but generally coherent sequences; however, some units in the western metamorphic belt may partly consist of melanges. Most sequences are in contact with other sequences, at least for short distances, but some sequences within the batholith are bounded on one or more sides by plutonic rocks. Proterozoic and Paleozoic sedimentary strata east of the Sierra Nevada and Paleozoic strata in

  13. Asymmetric textural and structural patterns of a granitic body emplaced at shallow levels: The La Chinchilla pluton, northwestern Argentina

    NASA Astrophysics Data System (ADS)

    Macchioli Grande, M.; Alasino, P. H.; Rocher, S.; Larrovere, M. A.; Dahlquist, J. A.

    2015-12-01

    New mapping and a detailed structural study of the La Chinchilla stock, Sierra de Velasco, NW Argentina, suggest an asymmetrical shape of the pluton and provide strong evidence for its shallow emplacement depth. The pluton is a Lower Carboniferous monzogranite composed of K-feldspar, quartz, plagioclase and biotite. It exhibits an internal asymmetric textural zoning, defined by porphyritic granite in the southeastern region to equigranular granite in the northwestern region. The presence of subhorizontal dikes in the northwestern area, where the contacts dip shallowly, and subvertical dikes intruding the host rock nearby steep-dipping intrusive contacts in the southeastern region are compatible with an overall asymmetrical shape and internal structure of this pluton. Considering published crystallization ages, a dominant strain field occurring at around 12 Ma is inferred based on magmatic fabrics in the pluton and its host rock (the Huaco pluton), with a principal shortening direction oriented SW-NE, consistent with the general NW-SE strike of the body. Field evidence supports brittle fracturing and block displacement as the dominant emplacement mechanism, suggesting that magmatic stoping dominated during the late stage of the evolution of the magma chamber.

  14. River Valley pluton, Ontario: A late-Archean/early-Proterozoic anorthositic intrusion in the Grenville Province

    SciTech Connect

    Ashwal, L.D. ); Wooden, J.L. )

    1989-03-01

    The River Valley pluton is a ca. 100 km{sup 2} body of anorthositic and gabbroic rocks located about 50 km northeast of Sudbury, Ontario. The pluton is situated entirely within the Grenville Province, but its western margin is a series of imbricate thrust faults associated with the Grenville Front Tectonic Zone. It is dominated by coarse leuconorite and leucogabbro, with lesser anorthosite, gabbro, and rare ultramafics. Igneous textured rocks are abundant and consist of plagioclase (An{sub 60-70}) charged with Fe-Ti oxide inclusions, low Ca pyroxene (orthopyroxene and/or inverted pigeonite) and augite. The most unfractionated rocks are minor olivine gabbros with Fo{sub 70-80}. A variety of deformed and recrystallized equivalents of the igneous-textured rocks is also present, and these are composed largely of calcic plagioclase and hornblende. An Sm-Nd isochron from 3 igneous-textured leucogabbros and an augite mineral separate gives 2,377 {plus minus} 68 Ma, implying slight disturbance of the Sm-Nd whole-rock-mineral system during later metamorphism. The Rb-Sr system has been substantially disturbed, giving an age of 2,185 {plus minus} 105 Ma, which is similar to internal Pb-Pb isochron ages of 2,165 {plus minus} 130 Ma and 2,100 {plus minus} 35 Ma for two igneous-textured rocks. Initial isotopic ratios for the River Valley pluton correspond to single-stage model parameters of {mu} = 8.06, {epsilon}{sub Nd} = O to {minus}3, and I{sub Sr} = 0.7015 to 0.7021. Collectively, these suggest either an enriched mantle source or crustal contamination of a mantle-derived magma. The crustal component involved must have been older and more radiogenic than the majority of rocks exposed at the surface in the nearby Superior Province.

  15. Ti in zircon from the Boggy Plain zoned pluton: implications for zircon petrology and Hadean tectonics

    NASA Astrophysics Data System (ADS)

    Ickert, R. B.; Williams, I. S.; Wyborn, D.

    2011-08-01

    The understanding of zircon crystallization, and of the Ti-in-zircon thermometer, has been enhanced by Ti concentration measurements of zircon from a small, concentrically zoned pluton in south-eastern Australia, the Boggy Plain zoned pluton (BPZP). Zircon crystals from rocks ranging in composition from gabbro to aplite were analysed for U-Th-Pb dating and Ti concentrations by an ion microprobe. Geochronological data yield a 206Pb/238U age of 417.2 ± 2.0 Ma (95% confidence) and demonstrate the presence of older inherited or xenocrystic zircon. Titanium measurements ( n = 158) yield a mean Ti concentration of 11.7 ± 6.1 ppm (2SD) which corresponds to a mean crystallization temperature of 790°C for an α-TiO2 = 0.74 (estimated using mineral equilibria), or 760°C for an α-TiO2 = 1.0. Apparent zircon crystallization temperatures are similar in all intrusive phases, although the gabbro yields slightly higher values, indicating that crystallization occurred at the same temperature in all rock types. This finding is consistent with previous work on the BPZP, which indicates that liquid-crystal sorting (crystal fractionation) was the dominant control on chemical differentiation, and that late, differentiated liquids were similar in composition for all rock types. A simple forward model approximately predicts the range of crystallization temperatures, but not the shape of the distributions, due to sampling biases and complexities in the cooling and crystallization history of the pluton. The distribution of Ti concentrations has a mode at a higher Ti (higher temperature) than the sample set of Hadean detrital zircon. This is consistent with the hypothesis that the skew to low-T in the Hadean dataset is due to the presence of zircon that crystallized from wet anatectic melts.

  16. Timing of Proterozoic deformation, plutonism, and metamorphism in the Los Pinos Mountains, Central New Mexico

    SciTech Connect

    Shastri, L.L. . Dept. of Geology); Bowring, S.A. )

    1992-01-01

    Geochronologic, structural, and metamorphic studies within the Los Pinos Mountains (LPM), central NM provide new insights into the Proterozoic geologic history of this area. The LPM consist of a NE-trending, NW-dipping sequence of complexly deformed amphibolites and felsic schists. These have been intruded by a pervasively deformed granitic pluton. Two predominant deformational fabrics exist in the LPM. S1 is an early northwest-trending foliation, commonly parallel to compositional layering, which is folded about S2. S2 is axial planar foliation to tight to isoclinal folds and is the regional NE-trending fabric. Other fabrics and complex fold interference patterns may be related to localized strain partitioning around granitic bodies. A network of granitic dikes associated with the pluton crosscuts S2 but contains a weak foliation parallel to S2, suggesting synkinematic intrusion of the dikes. Regional metamorphism in the LPM took place at upper greenschist to lower amphibolite facies. Electron microprobe traverses of garnets show compositional variation indicative of growth zoning. No abrupt changes in composition representative of multiple metamorphic events are observed. Garnet-biotite geothermometry yields average rim temperatures of 454 [+-] 50 C. U-Pb geochronology of zircons from amphibolite, granite, and a granite dike indicates essentially the same age for all three units (1.66 Ga). The amphibolite contains abundant zircons which have complex morphologies typical of metamorphic growth; however, an igneous origin cannot yet be precluded. Spheres from the same amphibolite yield a near concordant age of 1.62 Ga. Thus, deformation, plutonism, and possibly the peak of metamorphism, were coeval at ca. 1.66 Ga, with metamorphism cooling through the blocking temperature of sphene at 1.62 Ga. The LPM are similar to other mountain ranges in south-central New Mexico where 1.66 Ga ages have been reported.

  17. Volcanic Perspective on Plutonism based on Patterns in Evolution in Long-Lived Continental Volcanic Systems

    NASA Astrophysics Data System (ADS)

    Grunder, A. L.; Harris, R. N.; Walker, B. A.; Giles, D.; Klemetti, E. W.

    2008-12-01

    Volcanic rocks represent a biased view of magmatism, but provide critical quenched samples and temporal constraints of magmatic evolution obscured in the plutonic record. We here draw on the records from the Aucanquilcha Volcanic Cluster (AVC; 10 to 0 Ma) in northern Chile and from the mid-Tertiary volcanic field in east-central Nevada (ECNVF; ~40-32 Ma) to consider how evolutionary patterns of intermediate composition volcanic systems bear on the magmatic reworking of the continental crust by plutons and batholiths. Despite disparate tectonic setting (subduction vs extension) and volumes (70 km crust for the ~300 km 3 AVC versus and ~40 km crust for the ~3000 km 3 ECNVF) both volcanic systems share a history of early compositionally diverse volcanism, followed by a stage of more centralized and voluminous dacitic volcanism, which in turn is followed by waning of volcanism. The compositional change and the rapid increase in magma output rate after about half the lifetime of the system is a characteristic pattern of long- lived continental volcanic systems based on a compilation of volume-composition data. The middle, voluminous stage corresponds to the hottest upper crustal conditions, deduced from Al-in-amphibole geothermobarometry and Ti-in-zircon thermometry of the AVC. The middle stage rocks also have textures indicating hybridization of mixed magmas. Simple thermal models of heat input via intraplating readily allow for generation of partially molten crust above the sill, but they do not emulate the rapid increase of magma after some incubation time. We propose that there is a feedback in which a critical thickness of partially molten crust, consisting in part of magmatic precursors, can be readily convectively stirred and mixed with magma of the underplating sill, rapidly creating a large, hybrid and relatively hot body of magma. Stirring facilitates separation of a liquid-enriched extract. The volume of liquid extracted may be small relative to residual

  18. The secondary alkaline zinc electrode

    NASA Astrophysics Data System (ADS)

    McLarnon, Frank R.; Cairns, Elton J.

    1991-02-01

    The worldwide studies conducted between 1975 and 1990 with the aim of improving cell lifetimes of secondary alkaline zinc electrodes are overviewed. Attention is given the design features and characteristics of various secondary alkaline zinc cells, including four types of zinc/nickel oxide cell designs (vented static-electrolyte, sealed static-electrolyte, vibrating-electrode, and flowing-electrolyte); two types of zinc/air cells (mechanically rechargeable consolidated-electrode and mechanically rechargeable particulate-electrode); zinc/silver oxide battery; zinc/manganese dioxide cell; and zinc/ferric cyanide battery. Particular consideration is given to recent research in the fields of cell thermodynamics, zinc electrodeposition, zinc electrodissolution, zinc corrosion, electrolyte properties, mathematical and phenomenological models, osmotic pumping, nonuniform current distribution, and cell cycle-life perforamnce.

  19. Development of alkaline fuel cells.

    SciTech Connect

    Hibbs, Michael R.; Jenkins, Janelle E.; Alam, Todd Michael; Janarthanan, Rajeswari; Horan, James L.; Caire, Benjamin R.; Ziegler, Zachary C.; Herring, Andrew M.; Yang, Yuan; Zuo, Xiaobing; Robson, Michael H.; Artyushkova, Kateryna; Patterson, Wendy; Atanassov, Plamen Borissov

    2013-09-01

    This project focuses on the development and demonstration of anion exchange membrane (AEM) fuel cells for portable power applications. Novel polymeric anion exchange membranes and ionomers with high chemical stabilities were prepared characterized by researchers at Sandia National Laboratories. Durable, non-precious metal catalysts were prepared by Dr. Plamen Atanassovs research group at the University of New Mexico by utilizing an aerosol-based process to prepare templated nano-structures. Dr. Andy Herrings group at the Colorado School of Mines combined all of these materials to fabricate and test membrane electrode assemblies for single cell testing in a methanol-fueled alkaline system. The highest power density achieved in this study was 54 mW/cm2 which was 90% of the project target and the highest reported power density for a direct methanol alkaline fuel cell.

  20. Ductile strain rate recorded in the Symvolon syn-extensional plutonic body (Rhodope core complex, Greece)

    NASA Astrophysics Data System (ADS)

    Cirrincione, Rosolino; Fazio, Eugenio; Ortolano, Gaetano; Fiannacca, Patrizia; Kern, Hartmut; Mengel, Kurt; Pezzino, Antonino; Punturo, Rosalda

    2016-04-01

    The present contribution deals with quantitative microstructural analysis, which was performed on granodiorites of the syn-tectonic Symvolon pluton (Punturo et al., 2014) at the south-western boundary of the Rhodope Core Complex (Greece). Our purpose is the quantification of ductile strain rate achieved across the pluton, by considering its cooling gradient from the centre to the periphery, using the combination of a paleopiezometer (Shimizu, 2008) and a quartz flow law (Hirth et al., 2001). Obtained results, associated with a detailed cooling history (Dinter et al., 1995), allowed us to reconstruct the joined cooling and strain gradient evolution of the pluton from its emplacement during early Miocene (ca. 700°C at 22 Ma) to its following cooling stage (ca. 500-300°C at 15 Ma). Shearing temperature values were constrained by means of a thermodynamic approach based on the recognition of syn-shear assemblages at incremental strain; to this aim, statistical handling of mineral chemistry X-Ray maps was carried out on microdomains detected at the tails of porphyroclasts. Results indicate that the strain/cooling gradients evolve "arm in arm" across the pluton, as also testified by the progressive development of mylonitic fabric over the magmatic microstructures approaching the host rock. References • Dinter, D. A., Macfarlane, A., Hames, W., Isachsen, C., Bowring, S., and Royden, L. (1995). U-Pb and 40Ar/39Ar geochronology of the Symvolon granodiorite: Implications for the thermal and structural evolution of the Rhodope metamorphic core complex, northeastern Greece. Tectonics, 14 (4), 886-908. • Shimizu, I. (2008). Theories and applicability of grain size piezometers: The role of dynamic recrystallization mechanisms. Journal of Structural Geology, 30 (7), 899-917. • Hirth, G., Teyssier, C., and Dunlap, J. W. (2001). An evaluation of quartzite flow laws based on comparisons between experimentally and naturally deformed rocks. International Journal of Earth

  1. K-alkaline rocks and lamproites of Tomtor massif

    NASA Astrophysics Data System (ADS)

    Vladykin, Nikolai

    2015-04-01

    Tomtor massif of the largest volcano-plutonic deep alkaline-carbonatite massifs world central type. Area of massif occupy 240 km2 and carbonatites stock is 40 km2. The super large deposit of Nb, TR, Y, Sc, Sr ,REE (Frolov et al. 2001)is found within the massif. The numerical publication are devoted to the ore mineralization there. But the geological struc-ture of the massif and the chemistry of its constituting rocks are not well understood. We obtained new ages based on U-Pb zircon and mica Ar-Ar method (Kotov, Vladykin et al. 2014 Vladykin et al. 2015). The massif was created in 2 stages: 700 and 400 Ma. We (Vla-dykin et al 1998) found rocks of lamproite series and proposed a new scheme of magmatism and the ore.genesis (Vladykin 2007, 2009). Biotite - pyroxenite, peridotite originated in first stage and then intruded iolites, nepheline and alkali syenite. Syenites occupy 70% of -massif and contain 12-13% K2O and 2-4% Na2O showing the K-alkaline-ultramafic nature of Tomtor volcano-plutonic massif (Vladykin 2009). The first stage was accomplished by nelsonitov calcite, dolomite and ankerite carbonatites. Second stage (400Ma) volcanics picrite - lamproite veins and eruptive breccias meli-lite, melanephelinites, tinguaites appered. These rocks are cut by carbonatites of second stage. It was finished by intensive explosive eruption of a silicate (lamproite) tuffs lavobrec-cia kimberlite formed Ebelyakhdiamondiferous placer, melilite rocks in diatremes (feeders), as well as carbonate-phosphate (kamaforite) explosive tuffs with siderite ores. This carbona-tite complex is preserved within the subsidence caldera. Tuff eruption in conjunction with gas and hydrothermal activity determined its rare metal mineralization. These rocks contain to: Nb- 21%, TR-15%, Y-1.5%, Sc-1%, Zr- 0,5% Zn-, Sr-6%, Ti-8%, Ba-4%, V - 8000 ppm, Be- 300 ppm, Ga- 80 ppm, Cr- 1200ppm, Ni- 230 ppm, Mo- 145 ppm, Pb- 4300 ppm, Th- 1500 ppm, U-193 ppm. Picrite - olivine (rare leucite) lamproite and

  2. Source variation for Mesozoic granitoid plutons in the White-Inyo Range, California, and implications for changes in the lithospheric structure

    NASA Astrophysics Data System (ADS)

    Gammel, E.; Nabelek, P. I.; Phillips, E. H. W.; Scott, S. R.; Sims, K. W. W.

    2015-12-01

    The White-Inyo Range (WIR) of eastern California lies to the east of Owen's Valley and the Sierra Nevada batholith (SNB). Over twenty recognized Mesozoic, granitic to gabbroic plutons intruded into Precambrian and Cambrian sedimentary units that were previously metamorphosed to the greenschist facies. These plutons represent intrusive equivalents of volcanics erupted during two magmatic events at ca. 180-167 Ma and 102-86 Ma (Coleman et al, 2003). The motivation of this study is to understand changes in magma sources over this time period. We propose there is a time-transgressive change in source material in the WIR. Preliminary trace element data suggest that Jurassic plutons were sourced from deep crustal material, whereas later Cretaceous plutons may have had a shallower origin. This is supported by high Sr/Y ratios in the Jurassic plutons (up to 300) and relatively lower ratios in Cretaceous plutons (down to 14). Chiaradia (2015) suggests elevated Sr/Y ratios are directly linked to increasing crustal thickness, therefore the WIR plutons may record the period of crustal thinning in this region or maturation of the crust that allowed shallower melting in the Cretaceous. The highest values also suggest possible adakitic source material. REE patterns suggest that the youngest plutons (e.g. Sage Hen Flat) are more similar to samples collected from the eastern Sierra Nevada batholith than older plutons with higher La/Yb ratios. Relatively flat patterns REE patterns of Tertiary basalts and a late diabase dike in the WIR are also similar to SNB samples. Another goal of this study is to determine the degree of mixing as a function of time during the emplacement of plutons in the range. Field and petrographic analyses suggest that older plutons represent more mafic materials and younger plutons are more granitic with mafic enclaves. We propose either (1) older plutons represent initial lower lithosphere melting, and with time, there is an increase of incorporation of

  3. Ancient plutonic processes on Mars inferred from the detection of possible anorthositic terrains

    NASA Astrophysics Data System (ADS)

    Carter, J.; Poulet, F.

    2013-12-01

    The mineralogical diversity preserved on ancient terrains of Mars provides insights into the planet's early geological state and subsequent evolution. The martian crust is predominantly composed of mafic rocks with low silica contents, with the exception of a few localized volcanic sequences that indicate some compositional evolution towards compositions richer in silicate minerals. Anorthosite, which is dominated by the silicate mineral plagioclase, is rare in the Solar System. It is thought to require an evolved magmatic source in which lighter elements have been concentrated. Anorthosite has been observed previously only on Earth within localized continental plutons of intrusive igneous origin, and more widely on the Moon where the anorthositic highland crust is thought to derive from crystallization of a primordial magma ocean. Using near-infrared spectral data obtained by the Mars Reconnaissance Orbiter, we report the detection of iron-bearing plagioclase-rich rocks at eight sites in the southern highlands of Mars with a spectral signature consistent with ferroan anorthosites. The paucity of detections suggests a localized plutonic origin similar to terrestrial anorthosites, although a lunar-like global anorthosite crust on early Mars cannot be entirely excluded. Our detections of anorthositic compositions at several locations on the martian surface suggest that magmatic processes that produce highly evolved melts were active on ancient Mars.

  4. Mingled mafic and felsic magmas in the Jurassic Eagle Mountain pluton, southeastern California

    SciTech Connect

    Mayo, D.P. . Dept. of Geological Sciences); Wooden, J.L. )

    1993-04-01

    The metalluminous, compositionally expanded Eagle Mountain pluton ([approx] 165 Ma) was epizonally emplaced within Proterozoic metaigneous and Proterozoic-Paleozoic metasedimentary rocks in the Eagle Mountains of southeastern California. The evolution of the pluton involved mingling and partial mixing between mafic and felsic magmas. Heterogeneous rocks consisting of discrete biotite-clinopyroxene microdioritic enclaves (49--54% SiO[sub 2]) enclosed in hornblende-biotite granodiorite (57--61% SiO[sub 2]) grade into complexly mingled microdiorite and granodiorite as the proportion of microdiorite increases. The dioritic enclaves are notably potassic (2.1 [+-] .2 wt. %), containing abundant biotite (up to 23%) and interstitial patches of K-feldspar. These features are attributed to selective potassium enrichment of dioritic magma by diffusion during mingling with host granodioritic magma. A similar phenomenon was observed in experiments by Johnston and Wyllie, and attributed to relatively rapid diffusion of potassium from felsic to mafic magma. Calculated Sr[sub i] for the enclaves, intermediate dioritoids, and three of four analyzed host rocks cluster at 0.7085 [+-] 0.0002. Several homogeneous monzogranites not associated with enclaves have slightly higher Sr[sub i] (up to 0.7094) and define two separate mixing/AFC arrays on a plot of Sr[sub i] vs. 1/Sr, both anchored at the cluster of less radiogenic rocks. Alternatively, relatively rapid self-diffusion of Sr may have contributed to isotopic homogeneity during mingling of magmas from isotopically distinct sources.

  5. Emplacement and geochemical evolution of eocene plutonic rocks in the Colville batholith

    SciTech Connect

    Holder, R.W.

    1986-01-01

    Eocene plutonic rocks in the Colville batholith are divided on the basis of field evidence and chemical composition into, in order of decreasing age, (1) several calc-alkalic biotite-hornblende monzodiorite to granodiorite intrusions referred to as the Devils Elbow suite, and (2) compositionally variable calc-alkalic to alkali-calcic intrusions referred to as the Herron Creek suite. These Eocene suites are distinct from older, more voluminous, leucocratic granite and granodiorite intrusions, designated the Keller Butte suite, which are calcic and characteristically lack hornblende. Results of qualitative and computer modeling of major element variation and quantitative models of trace element variation in the chemically coherent Bridge Creek intrusions, a member of the Herron Creek suite, are compatible with fractionation of plagioclase feldspar + hornblende + biotite + magnetite + apatite from a parent magma of andesitic composition to account for the observed variation. Strongly curved variation trends preclude mixing as the primary mechanism for the observed variation. It is suggested that parallel variation trends in the other Eocene intrusions are also the result of crystal fractionation. Lateral chemical variations including a decrease in silica saturation suggest the chemical characteristics of these rocks reflect those of parental magmas derived from the mantle, with an unknown amount of crustal contribution. Rotated and angular xenoliths, discordant contacts, and temporal and spatial proximity to graben structures indicate that the Eocene plutons were passively implaced into the upper crust along graben-bounding faults during graben formation, the earlier stages of which appear to have been contemporaneous with regional mylonitic deformation.

  6. Reworked old crust-derived shoshonitic magma: The Guarany pluton, Northeastern Brazil

    NASA Astrophysics Data System (ADS)

    Ferreira, Valderez P.; Sial, Alcides N.; Pimentel, Marcio M.; Armstrong, Richard; Guimarães, Ignez P.; da Silva Filho, Adejardo F.; de Lima, Mariucha Maria C.; da Silva, Thyego R.

    2015-09-01

    The 572 Ma Guarany stock consists of magmatic epidote-bearing hornblende monzodiorite to biotite granite that intruded Paleoproterozoic orthogneisses about 10 km inland from the coast in northeastern Brazil. Co-magmatic diorite enclaves and dikes are abundant throughout the pluton. The monzodiorite-granite pluton and diorite enclaves are shoshonitic and display continuous trends in variation diagrams. They display chemical and isotopic characteristics of crustal melts, such as enrichment in incompatible elements, high back-calculated initial 87Sr/86Sr ratios (avg. 0.71253), negative εNd (0.57Ga) values (avg. - 14.58), as well as high and variable (+ 9.1 to + 11.1‰VSMOW) δ18O (zircon) values. Correlations between O-isotope and whole-rock silica contents, as well as initial 87Sr/86Sr ratios with 1/Sr concentrations, suggest hybridization of a lower continental crustal melt with more felsic crustal rocks, concomitant with fractional crystallization. Amphibole chemistry and whole rock Zr, TiO2 and P2O5 contents suggest magma solidification at a pressure 7 kbar and near liquidus temperature 900 °C. The parental magma was likely formed by partial melting of old (tDM = 2.0 Ga) amphibolitic lower continental crustal rocks, in a post-collisional setting, probably triggered by underplating of mantle-derived mafic magma during the period of relaxation after collision.

  7. Geochemistry of uranium and thorium and natural radioactivity levels of the western Anatolian plutons, Turkey

    NASA Astrophysics Data System (ADS)

    Papadopoulos, Argyrios; Altunkaynak, Şafak; Koroneos, Antonios; Ünal, Alp; Kamaci, Ömer

    2017-01-01

    Seventy samples from major plutons (mainly granitic) of Western Anatolia (Turkey) have been analyzed by γ-ray spectrometry to determine the specific activities of 238U, 226Ra, 232Th and 40K (Bq/kg). Τhe natural radioactivity ranged up to 264 Bq/kg for 238U, 229.62 Bq/kg for 226Ra, up to 207.32 Bq/kg for 232Th and up to 2541.95 Bq/kg for 40K. Any possible relationship between the specific activities of 226Ra, 238U, 232Th and 40K and some characteristics of the studied samples (age, rock-type, colour, grain size, occurrence, chemical and mineralogical composition) was investigated. Age, major and trace element geochemistry, color, pluton location and mineralogical composition are likely to affect the concentrations of the measured radionuclides. The range of the Th/U ratio was large (0.003-11.374). The latter, along with 226Ra/238U radioactive secular disequilibrium, is also discussed and explained by magmatic processes during differentiation.

  8. Syn-extensional plutonism and peak metamorphism in the albion-raft river-grouse creek metamorphic core complex

    USGS Publications Warehouse

    Strickland, A.; Miller, E.L.; Wooden, J.L.; Kozdon, R.; Valley, J.W.

    2011-01-01

    The Cassia plutonic complex (CPC) is a group of variably deformed, Oligocene granitic plutons exposed in the lower plate of the Albion-Raft River- Grouse Creek (ARG) metamorphic core complex of Idaho and Utah. The plutons range from granodiorite to garnet-bearing, leucogranite, and during intrusion, sillimanite- grade peak metamorphism and ductile attenuation occurred in the country rocks and normal-sense, amphibolite-grade deformation took place along the Middle Mountain shear zone. U-Pb zircon geochronology from three variably deformed plutons exposed in the lower plate of the ARG metamorphic core complex revealed that each zircon is comprised of inherited cores (dominantly late Archean) and Oligocene igneous overgrowths. Within each pluton, a spread of concordant ages from the Oligocene zircon overgrowths is interpreted as zircon recycling within a long-lived magmatic system. The plutons of the CPC have very low negative whole rock ??Nd values of -26 to -35, and initial Sr values of 0.714 to 0.718, consistent with an ancient, crustal source. Oxygen isotope ratios of the Oligocene zircon overgrowths from the CPC have an average ??18O value of 5.40 ?? 0.63 permil (2SD, n = 65) with a slight trend towards higher ??18O values through time. The ??18O values of the inherited cores of the zircons are more variable at 5.93 ?? 1.51 permil (2SD, n = 29). Therefore, we interpret the plutons of the CPC as derived, at least in part, from melting Archean crust based on the isotope geochemistry. In situ partial melting of the exposed Archean basement that was intruded by the Oligocene plutons of the CPC is excluded as the source for the CPC based on field relationships, age and geochemistry. Correlations between Ti and Hf concentrations in zircons from the CPC suggest that the magmatic system may have become hotter (higher Ti concentration in zircon) and less evolved (lower Hf in zircon concentration) through time. Therefore, the CPC represents prolonged or episodic magmatism

  9. Reconnaissance geochemical exploration of the plutons of quartz monzonite and granite in the Jabal Lababa and Ar Rayth areas, southern Asir, Kingdom of Saudi Arabia

    USGS Publications Warehouse

    Overstreet, W.C.; Assegaff, A.B.; Jambi, Mohammed; Hussain, M.A.; Selner, G.I.; Matzko, J.J.

    1985-01-01

    Three nonmagnetic high-density concentrates containing 1,000 to 15,000 ppm lead were found on the granitic pluton near Ar Rayth. The source of the lead is not galena, and high values for lead appear to be characteristic of the pluton but do not indicate an ore deposit.

  10. Petrogenesis and tectonic implications of the high-K Alamas calc-alkaline granitoids at the northwestern margin of the Tibetan Plateau: Geochemical and Sr-Nd-Hf-O isotope constraints

    NASA Astrophysics Data System (ADS)

    Zhang, Qichao; Liu, Yan; Huang, He; Wu, Zhenhan; Zhou, Qing

    2016-09-01

    The Alamas granitoid pluton in the eastern part of the Western Kunlun Orogen, the northwestern margin of the Tibetan Plateau, is composed of quartz diorite. Zircon separates from the pluton has SIMS U-Pb age of ∼446 Ma. Rocks from the pluton have a narrow range of SiO2 (56.84-62.57 wt%), MgO (1.76-2.94 wt%), and total alkalis (Na2O + K2O = 5.14-9.59 wt%), and are metaluminous and high-K calc-alkaline to shoshonitic in composition. They are enriched in light rare earth elements (LREEs), with (La/Yb)N = 14-25, and show weakly negative Eu anomalies. These rocks are relatively enriched in Sr (472-676 ppm) and Ba (435-2388 ppm), and depleted in Nb, Ta, Th, and Ti. Their εNd(t) values range from -6.4 to -8.4, and (87Sr/86Sr)i = 0.7184-0.7200. Zircons from the pluton show εHf(t) values of -1.4 to -8.8, and δ18O = 6.4-9.0‰. Geochemical data indicate that the granitoids were likely derived from the reworking of an ancient, deep crustal source, influenced by a minor mantle-derived component. Magmatic differentiation was dominated by the fractional crystallization of hornblende, biotite, and accessory minerals such as apatite, allanite, and Fe-Ti oxides. In summary, the Late Ordovician Alamas pluton is an I-type granitoid that was emplaced in a post-collisional environment, suggesting that this tectonic stage had already initiated prior to ∼445 Ma.

  11. River Valley pluton, Ontario: A late-Archean/early-Proterozoic anorthositic intrusion in the Grenville Province

    USGS Publications Warehouse

    Ashwal, L.D.; Wooden, J.L.

    1989-01-01

    The River Valley pluton is a ca. 100 km2 body of anorthositic and gabbroic rocks located about 50 km northeast of Sudbury, Ontario. The pluton is situated entirely within the Grenville Province, but its western margin is a series of imbricate thrust faults associated with the Grenville Front Tectonic Zone. It is dominated by coarse leuconorite and leucogabbro, with lesser anorthosite, gabbro, and rare ultramafics. Igneous textured rocks are abundant and consist of plagioclase (An60-70) charged with Fe-Ti oxide inclusions, low Ca pyroxene (orthopyroxene and/or inverted pigeonite) and augite. The most unfractionated rocks are minor olivine gabbros with Fo70-80. A variety of deformed and recrystallized equivalents of the igneous-textured rocks is also present, and these are composed largely of calcic plagioclase and hornblende. Ten samples, including both igneous and deformed lithologies give a Pb-Pb whole-rock isochron of 2560??155Ma, which is our best estimate of the time of primary crystallization. The River Valley pluton is thus the oldest anorthositic intrusive yet reported from the Grenville Province, but is more calcic and augitic than typical massifs, and lacks their characteristic Fe-Ti oxide ore deposits. The River Valley body may be more akin to similar gabbro-anorthosite bodies situated at the boundary between the Archean Superior Province and Huronian supracrustal belt of the Southern Province west of the Grenville Front. An Sm-Nd isochron from 3 igneous-textured leucogabbros and an augite mineral separate gives 2377 ?? 68 Ma, implying slight disturbance of the Sm-Nd whole-rock-mineral system during later metamorphism. The Rb-Sr system has been substantially disturbed, giving an age of 2185 ?? 105 Ma, which is similar to internal Pb-Pb isochron ages of 2165 ?? 130 Ma and 2100 ?? 35 Ma for two igneous-textured rocks. It is uncertain whether these ages correspond to a discrete event at this time or represent a partial resetting of the Rb-Sr and Pb

  12. Diclofenac salts. III. Alkaline and earth alkaline salts.

    PubMed

    Fini, Adamo; Fazio, Giuseppe; Rosetti, Francesca; Angeles Holgado, M; Iruín, Ana; Alvarez-Fuentes, Josefa

    2005-11-01

    Diclofenac salts containing the alkaline and two earth alkaline cations have been prepared and characterized by scanning electron microscopy (SEM) and EDAX spectroscopy; and by thermal and thermogravimetric analysis (TGA): all of them crystallize as hydrate when precipitated from water. The salts dehydrate at room temperature and more easily on heating, but recovery the hydration, when placed in a humid environment. X-ray diffraction spectra suggest that on dehydration new peaks appear on diffractograms and the lattice of the salts partially looses crystallinity. This phenomenon is readily visible in the case of the calcium and magnesium salts, whose thermograms display a crystallization exotherm, before melting or decomposing at temperatures near or above 200 degrees C; these last salts appear to form solvates, when prepared from methanol. The thermogram of each salt shows a complex endotherm of dehydration about 100 degrees C; the calcium salt displays two endotherms, well separated at about 120 and 160 degrees C, which disappear after prolonged heating. Decomposition exotherms, before or soon after the melting, appear below 300 degrees C. The ammonium salt is thermally unstable and, when heated to start dehydration, dissociates and leaves acidic diclofenac.

  13. Alkaline fuel cell performance investigation

    NASA Technical Reports Server (NTRS)

    Martin, R. E.; Manzo, M. A.

    1988-01-01

    An exploratory experimental fuel cell test program was conducted to investigate the performance characteristics of alkaline laboratory research electrodes. The objective of this work was to establish the effect of temperature, pressure, and concentration upon performance and evaluate candidate cathode configurations having the potential for improved performance. The performance characterization tests provided data to empirically establish the effect of temperature, pressure, and concentration upon performance for cell temperatures up to 300 F and reactant pressures up to 200 psia. Evaluation of five gold alloy cathode catalysts revealed that three doped gold alloys had more that two times the surface areas of reference cathodes and therefore offered the best potential for improved performance.

  14. Using Oxygen Isotopes of Zircon to Evaluate Magmatic Evolution and Crustal Contamination in the Halifax Pluton, Nova Scotia

    NASA Astrophysics Data System (ADS)

    Murray, K. E.; Lackey, J.; Valley, J. W.; Nowak, R.

    2007-12-01

    Oxygen isotope analysis of zircon (Zrc) is well suited for parsing out the magmatic history in granitoids. The Halifax pluton is the largest pluton (1060 km2) in the peraluminous South Mountain batholith. The Halifax pluton is mapped as a concentrically zoned body, with outer units comprising granodiorite, monzogranite and a mafic porphyry; these units are locally rich in metasedimentary xenoliths and magmatic enclaves. The exterior units surround a more felsic core of leucogranite [1]. Previous oxygen isotope studies of the pluton report high whole rock δ18O values that range from 10.7-11.7‰ [2], and indicate a significant supracrustal component in the source of the pluton. We report the first δ18O(Zrc) values from the Peggy's Cove monzogranite and an associated mafic porphyry. Samples were collected across 30 km of discontinuous exposures of the monzogranite. Values of δ18O(Zrc) vary from 7.71-8.26‰ (average = 8.15±±0.32‰(2 S.D.); n = 10). Small but systematic E-W regional variation in δ18O(Zrc) values suggests heterogeneous magmatic contamination within the monzogranite. Meter-scale magmatic enclaves, observed in close association with pods of diverse xenoliths and smaller enclaves at the western Cranberry Head locality, are slightly enriched in δ18O relative to the host monzogranite. These data combined support a model of magma mingling and heterogeneous mixing at the rim of the pluton, with contamination by high-δ18O rocks. Additional high-δ18O(Zrc) data from granodiorites on the northern margin of the Halifax pluton concur with these observations [3]. Typically, closed magmatic systems show increasing δ18O with SiO2 because more felsic magmas have a greater percentage of high-δ18O minerals such as quartz and feldspar. Thus, the Halifax pluton appears to exhibit an enrichment trend opposite of what would be expected of a closed evolving system. Emplacement mechanisms for the Halifax pluton proposed by previous workers suggest that the outer

  15. Open vs. closed-system behaviors in granitoid rocks during granulite-facies metamorphism: a case study from the Bulai Pluton (Central Limpopo Belt, South Africa)

    NASA Astrophysics Data System (ADS)

    Laurent, Oscar; Moyen, Jean-François; Martin, Hervé; Doucelance, Régis; Paquette, Jean-Louis

    2010-05-01

    The late-Archaean, high-K calc-alkaline Bulai pluton emplaced within the Central Zone of the Limpopo Belt, a polymetamorphic terrane characterized by at least three granulite-facies events. The youngest, Paleoproterozoic (~2.0 Ga), D3/M3 structural-metamorphic overprint reached pressure-temperature conditions as high as 9-10 kbar and 830°C. As it post-dates the emplacement of the Bulai magmas (~ 2.6 Ga), we investigated the textural and geochemical record of this event in the plutonic rocks of the batholith, focusing on chemical and isotopic re-equilibration. The regional D3/M3 episode is associated with complex strain patterns, including large shear zones, folding and possibly horizontal nappe tectonics. However, in the core of the pluton, there is very little structural field evidence for subsolidus deformation. In addition, no granulite-facies paragenesis developed in the Bulai rocks during the D3/M3 overprint, except in discrete undeformed granulitic veins that are probably related to this event. On the other hand, all rock types display granoblastic polygonal textures, suggesting that the thermal peak induced annealing, almost complete in some cases. Mineral compositions also show evidence for re-equilibration during the Paleoproterozoic metamorphism. Indeed, plagioclase is systematically unzoned, and its chemical composition is notably constant (An29-33) regardless the whole-rock composition over large ranges of SiO2 (47-75 wt.%), CaO (1.5-8 wt.%) and Na2O (2.5-4 wt.%). Similarly, hornblende and biotite compositions are homogeneous within the whole Bulai suite, and present high Ti contents suggesting equilibration at high temperatures. Furthermore, hornblende-plagioclase thermometry indicates temperatures up to 800-900°C, consistent with the thermal peak of the D3/M3 metamorphic episode. 147Sm/147Nd data on whole-rock and separated minerals provided further evidence for grain-scale equilibration, as internal isochrons of 4 individual samples yield ages

  16. Alkaline detergent recycling via ultrafiltration

    SciTech Connect

    Steffani, C.; Meltzer, M.

    1995-06-01

    The metal finishing industry uses alkaline cleaners and detergents to remove oils and dirt from manufactured parts, often before they are painted or plated. The use of these cleaners has grown because environmental regulations are phasing out ozone depleting substances and placing restrictions on the use and disposal of many hazardous solvents. Lawrence Livermore National Laboratory is examining ultrafiltration as a cleaning approach that reclaims the cleaning solutions and minimizes wastes. The ultrafiltration membrane is made from sheets of polymerized organic film. The sheets are rolled onto a supporting frame and installed in a tube. Spent cleaning solution is pumped into a filter chamber and filtered through the membrane that captures oils and dirt and allows water and detergent to pass. The membrane is monitored and when pressure builds from oil and dirt, an automatic system cleans the surface to maintain solution flow and filtration quality. The results show that the ultrafiltration does not disturb the detergent concentration or alkalinity but removed almost all the oils and dirt leaving the solution in condition to be reused.

  17. Minerals and melt inclusions as keys to understanding magma reservoir processes during formation of volcanic and plutonic mafic-ultramafic complexes in the Maimecha Kotui Province (Polar Siberia)

    NASA Astrophysics Data System (ADS)

    Simonov, Vladimir; Vasiliev, Yurii; Kotlyarov, Alexey; Stupakov, Sergey

    2016-04-01

    Magmatic complexes in the Maimecha Kotui Province (Polar Siberia) attract attention of researchers because they contain ultramafic volcanic rocks - meimechites, being products of crystallization of the ultrabasic deep mantle melts (Sobolev et al., 1991, 2009, 2011; Ryabchikov et al., 2002; Vasiliev, Gora, 2014). Effusive meimechites together with intrusive dunites of the Guli massif form ancient (253-246 Ma) volcanic and plutonic association, in which also pyroxenites and alkaline rocks are situated. Conditions of formation of this association were established with the help of minerals and melt inclusions study. The cumulative structure of the Guli massif dunites consists of rather large (2-4 mm) olivine crystals and dividing them zones (0.5-0.7 mm), filled with fine grains of clinopyroxenes and ore minerals (magnetite, ilmenite and chromite). The extended forms of well faceted pyroxene crystals testify to their fast growth from melt between cumulative olivines. Thus, crystallization of clinopyroxenes and ore minerals leads to formation between olivines ore pyroxenites, which are presented in the Guli massif by independent bodies. Analysis of olivine, Cr-spinel and clinopyroxene compositions testify to similarity of conditions of the Guli massif dunites crystallization on the one hand with formation of platinum-bearing Uralian-Alaskan-type mafic-ultramafic complexes and with another - show participation of meimechite magma. Major element composition of melt inclusions in Cr-spinel has shown that dunites of the Guli massif were crystallized with participation of subalkaline picrite magmatic systems, that are relative to melts, responsible of formation of platinum-bearing mafic-ultramafic complexes and meimechites. Peculiarities of trace and rare-earth elements distribution in melt inclusions in Cr-spinel of dunites are actually similar to inclusions in olivine of meimechites. Overall, data on composition of inclusions directly testify to formation of considered

  18. Felsic plutonism in the Al Amar—Idsas area, Kingdom of Saudi Arabia

    NASA Astrophysics Data System (ADS)

    Le Bel, L.; Laval, M.

    A tonalite—trondhjemite suite, calc-alkalic plutons and alkali-feldspar granites dated 670 and 580 Ma, intrude thick volcano-sedimentary rocks of the Al Amar group E of the Al Amar fault and the Abt schist W of the fault. The tonalite—trondhjemite suite (group I) is characterized by low Rb (50 ppm) and Sr (100-400 ppm) and by weakly fractionated rare-earth patterns (La/Yb Nca 2-3) with a weak negative Eu anomaly. Calc-alkalic plutons (group II) are richer in Rb (50-150 ppm), contain variable Sr (50-1000 ppm), and have strongly fractionated rare-earth patterns (La/Yb Nca 6-22) with no Eu anomaly. Alkali-feldspar granite (group III) is characterized by high Rb (150-200 ppm) and shows fractionated rare-earth patterns (La/Yb Nca 6-18) with a well-developed Eu anomaly. Group III includes 'specialized granites' with high Rb (300-400 ppm) and Sn (28-66 ppm), and rare-earth patterns showing a distinctive 'sea gull' profile with a very strong Eu anomaly (Eu*/Eu = 20). Oxygen isotope geochemistry suggests that group I rocks (¯x δ18O ca 7.0) were mantle-derived, and that group II and III rocks intruding the Al Amar group ( δ18O ca 7.9 and 8.8 respectively) were derived by remelting of group I, whereas those intruding Abt schist ( δ18O ca 8.7 and 10.8 respectively) were partially derived by anatexis of the Afif block. Magmatogenesis reflects an island-arc development. Rocks of group I represent the initial subduction phase. Syn- to late-tectonic plutons of group II intruded the arc east of the Al Amar fault and the accretionary prism (Abt schist) to the west, which was in collision with the older Afif block. Post-tectonic group III rocks were emplaced in an already cratonized area.

  19. Compositional and kinetic controls on liquid immiscibility in ferrobasalt-rhyolite volcanic and plutonic series

    NASA Astrophysics Data System (ADS)

    Charlier, Bernard; Namur, Olivier; Grove, Timothy L.

    2013-07-01

    We present major element compositions of basalts and their differentiation products for some major tholeiitic series. The dry, low-pressure liquid lines of descent are shown to approach or intersect the experimentally-defined compositional space of silicate liquid immiscibility. Ferrobasalt-rhyolite unmixing along tholeiitic trends in both volcanic and plutonic environments is supported by worldwide occurrence of immiscible globules in the mesostasis of erupted basalts, unmixed melt inclusions in cumulus phases of major layered intrusions such as Skaergaard and Sept Iles, and oxide-rich ferrogabbros closely associated with plagiogranites in the lower oceanic crust. Liquid immiscibility is promoted by low-pressure, anhydrous fractional crystallization that drives the low Al2O3, high FeO liquids into the two-liquid field. Kinetic controls can be important in the development of two-liquid separation. The undercooling that occurs at the slow cooling rates of plutonic environments promotes early development of liquid immiscibility at higher temperature. In contrast rapid cooling in erupted lavas leads to large undercoolings and liquid immiscibility develops at significantly lower temperatures. Unmixing leads to the development of a compositional gap characterized by the absence of intermediate compositions, a feature of many tholeiitic provinces. The compositions of experimental unmixed silica-rich melts coincide with those of natural rhyolites and plagiogranites with high FeOtot and low Al2O3, suggesting the potential role of large-scale separation of immiscible Si-rich liquid in the petrogenesis of late-stage residual melts. No trace of the paired ferrobasaltic melt is found in volcanic environments because of its uneruptable characteristics. Instead, Fe-Ti ± P-rich gabbros are the cumulate products of immiscible Fe-rich melts in plutonic settings. The immiscibility process may be difficult to identify because both melts crystallize the same phases with the same

  20. Oxygen Isotope Perspectives on Magma Sources and Pluton Assembly in Convergent Margin Batholiths

    NASA Astrophysics Data System (ADS)

    Lackey, J.

    2008-12-01

    Oxygen isotope (δ18O) analysis of zircon in the Sierra Nevada batholith (SNB) yields fresh insight on the origin of this and other convergent margin batholiths. Zircon precisely and accurately maps (δ18O) variation by circumventing the effects of differentiation and sub-solidus alteration[1]. New temporal and spatial δ18O patterns are recognized, and the findings have bearing in current debates on the tempo and mode of pluton and intrusive suite assembly [2-4]. At large scales, regional belts of high and low δ18O reveal markedly contrasting budgets of crust and mantle in magma sources at different points during formation of the batholith. Contrary to original thinking, recycling of supracrustal rocks is greater in the western than eastern SNB. Gradients of δ18O show variable input of crust and mantle within these regional belts; however, sharp shifts in δ18O between some belts suggest pre-batholith lithospheric breaks. Generally, δ18O breaks do not coincide with the 0.706 Sri line suggesting isotopic decoupling, either in sources or during crustal contamination. Where present, crustal contamination is limited to veneers on plutons, and is largely restricted to the western SNB. Careful investigation of individual intrusive suites, reveals details of source longevity. In the Tuolumne suite, limited variability of δ18O suggests remarkably source homogeneity despite evidence for protracted emplacement[2,4]. In contrast, the John Muir suite shows distinct trends in its older and younger plutons, with a δ18O transition recorded in the Lake Edison granodiorite. Thus, some suites may draw from stable sources over several million years, with differentiation in the upper crust creating zoning and textural diversity; others record source switching or depletion of sources. Over time, shifts in δ18O in the SNB are punctuated by major pulses of magmatism suggesting reorganization of sources, likely in response to intra-arc deformation[5]. Overall, results show that a

  1. Natural radioactivity and radiation index of the major plutonic bodies in Greece.

    PubMed

    Papadopoulos, A; Christofides, G; Koroneos, A; Papadopoulou, L; Papastefanou, C; Stoulos, S

    2013-10-01

    The natural radioactivity of the major plutonic bodies in Greece, as well as the assessment of any potential health hazard due to their usage as decorative building materials is studied. One hundred and twenty one samples from every major plutonic body in Greece, including various rock-types from gabbro to granite, have been measured for their natural radioactivity using γ-spectrometry methodology. According to the experimental results, the natural radioactivity levels were ranged up to 315 Bq kg(-1) for (226)Ra, up to 376 Bq kg(-1) for (232)Th and up to 1632 Bq kg(-1) for (40)K, with arithmetic mean values and standard deviations of 74 (±51), 85 (±54) and 881 (±331) Bq kg(-1) respectively, which are below the international representative mean values for granite stones. The excess on the effective dose received annually indoors due to granite tiles usage is estimated considering a standard room model where granite tiles with 1.5 cm in thickness cover only the floor of the room. The increment on the external γ-radiation effective dose rate shows a Gaussian distribution well dispersed below 0.3 mSv y(-1), presenting a mean value of 0.14 (±0.06) mSv y(-1). In case of the internal α-radiation a log-normal distribution is appeared scattering below 0.5 mSv y(-1) with a mean value 0.19 (±0.13) mSv y(-1), for a well-ventilated living environment. In case of a poor-ventilated room the increment on internal effective dose rate is estimated with a mean value 0.27 (±0.19) mSv y(-1) scattering below 0.8 mSv y(-1). The majority of the samples increase the external as well as the internal dose less than 30% of the maximum permitted limit of the effective dose rate. Therefore, at least from radiological point of view, the plutonic rocks of Greece could be safely used as decorative building materials.

  2. Alkaline and alkaline earth metal phosphate halides and phosphors

    DOEpatents

    Lyons, Robert Joseph; Setlur, Anant Achyut; Cleaver, Robert John

    2012-11-13

    Compounds, phosphor materials and apparatus related to nacaphite family of materials are presented. Potassium and rubidium based nacaphite family compounds and phosphors designed by doping divalent rare earth elements in the sites of alkaline earth metals in the nacaphite material families are descried. An apparatus comprising the phosphors based on the nacaphite family materials are presented herein. The compounds presented is of formula A.sub.2B.sub.1-yR.sub.yPO.sub.4X where the elements A, B, R, X and suffix y are defined such that A is potassium, rubidium, or a combination of potassium and rubidium and B is calcium, strontium, barium, or a combination of any of calcium, strontium and barium. X is fluorine, chlorine, or a combination of fluorine and chlorine, R is europium, samarium, ytterbium, or a combination of any of europium, samarium, and ytterbium, and y ranges from 0 to about 0.1.

  3. Transpressional granite-emplacement model: Structural and magnetic study of the Pan-African Bandja granitic pluton (West Cameroon)

    NASA Astrophysics Data System (ADS)

    Sandjo, A. F. Yakeu; Njanko, T.; Njonfang, E.; Errami, E.; Rochette, P.; Fozing, E.

    2016-02-01

    The Pan-African NE-SW elongated Bandja granitic pluton, located at the western part of the Pan-African belt in Cameroon, is a K-feldspar megacryst granite. It is emplaced in banded gneiss and its NW border underwent mylonitization. The magmatic foliation shows NE-SW and NNE-SSW strike directions with moderate to strong dip respectively in its northern and central parts. This mostly, ferromagnetic granite displays magnetic fabrics carried by magnetite and characterized by (i) magnetic foliation with best poles at 295/34, 283/33 and 35/59 respectively in its northern, central and southern parts and (ii) a subhorizontal magnetic lineation with best line at 37/8, 191/9 and 267/22 respectively in the northern, central and southern parts. Magnetic lineation shows an `S' shape trend that allows to (1) consider the complete emplacement and deformation of the pluton during the Pan-African D 2 and D 3 events which occurred in the Pan-African belt in Cameroon and (2) reorganize Pan-African ages from Nguiessi Tchakam et al. (1997) compared with those of the other granitic plutons in the belt as: 686 ±17 Ma (Rb/Sr) for D 1 age of metamorphism recorded in gneiss; and the period between 604-557 Ma for D 2-D 3 emplacement and deformation age of the granitic pluton in a dextral ENE-WSW shear movement.

  4. Constraints on the Depth of Generation and Emplacement of Magma in the Coast Plutonic Complex, British Columbia, From Magmatic Epidote Textures

    NASA Astrophysics Data System (ADS)

    Hamblock, J. M.; Andronicos, C. L.

    2007-12-01

    We have examined magmatic epidote-bearing plutons in the Coast Plutonic Complex to understand the depth at which they were generated and emplaced. Mt. Gamsby, located east of the Coast shear zone between Kitimat and Bella Coola, British Columbia, contains a magmatic epidote-bearing tonalite-quartz diorite pluton. This pluton had a crystallization sequence of pyroxene, amphibole, epidote, plagioclase, and biotite. The lack of garnet is consistent with trace element data, which indicate that garnet was not present in the source region and, therefore, that the magma was sourced at pressures less than ca. 1.4 GPa. Epidote inclusions in plagioclase constrain the pressure during early crystallization of the epidote to greater than 1 GPa. P-T estimates from the pluton and surrounding country rock suggest that the magma migrated to shallower levels and was emplaced at depths of ca. 0.8-1.0 GPa. Magmatic epidote also occurs in the Ecstall, Butedale, and Captain Cove plutons west of the Coast shear zone south of Prince Rupert. In the Captain Cove pluton, textures show that plagioclase crystallized before epidote, and pluton crystallization pressures are estimated to be 0.65-0.75 GPa. These data are consistent with experimental work that indicates that the crystallization of plagioclase before epidote occurs at a lower pressure than epidote before plagioclase. The magmatic epidote in the Ecstall and Butedale plutons commonly occurs as large vermicular grains intergrown with quartzofeldspathic minerals. We interpret this texture to indicate late crystallization of epidote, consistent with prior studies. Pressure estimates for the Ecstall pluton are between ca. 0.5 and 0.8 GPa and vary along strike. The pressure of emplacement of the Butedale pluton is not well constrained, but Al-in-hornblende pressures of 0.6 and 0.8 GPa have been obtained from a portion of the pluton. The pressures in the Butedale and Ecstall plutons are lower than pressures at Mt. Gamsby, which shows early

  5. Geological and petrological aspects of Ni-Cu-PGE mineralization in the early Paleoproterozoic Monchegorsk layered mafic-ultramafic complex, Kola Peninsula

    NASA Astrophysics Data System (ADS)

    Sharkov, E. V.; Chistyakov, A. V.

    2014-05-01

    The Early Paleoproterozoic Monchegorsk Complex comprises two independent large layered mafic-ultramafic intrusions: the Monchegorsk pluton and the Main Range massif formed about 2.50 and 2.46 Ga ago, respectively. They are composed of similar cumulates, though they differ somewhat in the isotopic parameters of rocks, cumulate stratigraphy and derived from siliceous high-Mg series melts that arose in the same large long-living volcanic center. The economic syngenetic Ni-Cu-PGE sulfide mineralization related to the earlier Monchegorsk pluton is represented by two types of ores. The first type, pertaining to fractionation of the primary melt, is opposite to the reef formed due to injection of a special ore-bearing melt into the solidifying intrusive chamber. The primary magmatic mineralization is largely composed of Ni-Fe-Cu sulfides and Pd-Pt sulfides, bismuthides, and tellurides. Only small PGE and probably chromite occurrences are related to the Main Range massif. In the Mid-Paleoproterozoic (2.0-1.9 Ga), the complex was transformed into a collage of tectonic blocks confined to the regional fault zone. The Monchegorsk pluton was retained better, and only rocks of its southern framework were involved into tectonic and metamorphic reworking with the formation of economic metamorphic low-sulfide PGE mineralization with widespread Pd and Pt telluro-bismuthides, arsenides, stannides, antimonides, and selenides. The ore formation was accompanied by PGE redistribution and segregation of lenticular orebodies with diffuse contours. Thus, the Monchegorsk ore cluster is characterized by juxtaposition of unaltered primary magmatic deposits and those formed as a result of their metamorphism and distinguished from the former by structure and composition. The comparative study of these deposits opens up new possibilities for comprehending ore-forming processes in the same situations.

  6. The probable continuum between emplacement of plutons and mare volcanism in lunar crustal evolution

    NASA Technical Reports Server (NTRS)

    Pieters, Carle M.

    1991-01-01

    A scenario for the formation of the Moon is advanced and is argued to be consistent with both known data and the leading hypothesis regarding the formation of the Moon. It is concluded that, although the volume of mare basalts is estimated to be only 0.1 percent of the lunar total, this value should not be taken to represent the amount of partial melt produced within the lunar interior, nor should the mare basalts be viewed as representing the only products of internal heating. The actual amount of magnetic activity is certain to be substantially larger, but cannot be estimated without a global assessment of lunar highland heterogeneity and the character, scale, and abundance of lunar plutons.

  7. The probable continuum between emplacement of plutons and mare volcanism in lunar crustal evolution

    NASA Astrophysics Data System (ADS)

    Pieters, Carle M.

    1991-06-01

    A scenario for the formation of the Moon is advanced and is argued to be consistent with both known data and the leading hypothesis regarding the formation of the Moon. It is concluded that, although the volume of mare basalts is estimated to be only 0.1 percent of the lunar total, this value should not be taken to represent the amount of partial melt produced within the lunar interior, nor should the mare basalts be viewed as representing the only products of internal heating. The actual amount of magnetic activity is certain to be substantially larger, but cannot be estimated without a global assessment of lunar highland heterogeneity and the character, scale, and abundance of lunar plutons.

  8. Exploring the plutonic crust at a fast-spreading ridge:new drilling at Hess Deep

    SciTech Connect

    Gillis, Kathryn M.; Snow, Jonathan E.; Klaus, Adam; Guerin, Gilles; Abe, Natsue; Akizawa, Norikatsu; Ceuleneer, Georges; Cheadle, Michael J.; Adriao, Alden de Brito; Faak, Kathrin; Falloon, Trevor J.; Friedman, Sarah A.; Godard, Marguerite M.; Harigane, Yumiko; Horst, Andrew J.; Hoshide, Takashi; Ildefonse, Benoit; Jean, Marlon M.; John, Barbara E.; Koepke, Juergen H.; Machi, Sumiaki; Maeda, Jinichiro; Marks, Naomi E.; McCaig, Andrew M.; Meyer, Romain; Morris, Antony; Nozaka, Toshio; Python, Marie; Saha, Abhishek; Wintsch, Robert P.

    2013-02-28

    Integrated Ocean Drilling Program (IODP) Hess Deep Expedition 345 was designed to sample lower crustal primitive gabbroic rocks that formed at the fast-spreading East Pacific Rise (EPR) in order to test models of magmatic accretion and the intensity of hydrothermal cooling at depth. The Hess Deep Rift was selected to exploit tectonic exposures of young EPR plutonic crust, building upon results from ODP Leg 147 as well as more recent submersible, remotely operated vehicle, and near-bottom surveys. The primary goal was to acquire the observations required to test end-member crustal accretion models that were in large part based on relationships from ophiolites, in combination with mid-ocean ridge geophysical studies. This goal was achieved with the recovery of primitive layered olivine gabbros and troctolites with many unexpected mineralogical and textural relationships, such as the abundance of orthopyroxene and the preservation of delicate skeletal olivine textures.

  9. Intermetallic compounds, copper and palladium alloys in Au-Pd ore of the Skaergaard pluton, Greenland

    NASA Astrophysics Data System (ADS)

    Rudashevsky, N. S.; Rudashevsky, V. N.; Nielsen, T. F. D.

    2015-12-01

    Copper-palladium intermetallic compounds and alloys (2314 grains) from the Au-Pd ore of the Skaergaard layered gabbroic pluton have been studied. Skaergaardite PdCu, nielsenite PdCu3, (Cu,Pd)β, (Cu,Pd)α, (Pd,Cu,Au,Pt) alloys, and native palladium have been identified as a result of 1680 microprobe analyses. The average compositions and various chemical varieties of these minerals are characterized, as well as vertical and lateral zoning in distribution of noble metals. The primary Pd-Cu alloys were formed within a wide temperature interval broadly synchronously with cooling and crystallization of host gabbro and in close association with separation of Fe-Cu sulfide liquid. In the course of crystallization of residual gabbroic melt enriched in iron, noble and heavy metals and saturated with the supercritical aqueous fluid, PGE and Au are selectively concentrated in the Fe-Cu sulfide phase as Pd-Cu and Cu-Au alloys.

  10. The plutonic-volcanic connection: are we even on the right track? (Invited)

    NASA Astrophysics Data System (ADS)

    Lundstrom, C.; Chakraborty, P.; Zambardi, T.

    2013-12-01

    The connection between silicic volcanic and plutonic rocks is full of contradictions. Foremost, granitic plutons reflect long slow incremental emplacement yet vast amounts of aphyric ignimbrite can be erupted rapidly. Heat flow, geophysical tomography, geochronology, geochemistry and petrology all provide observations, yet we are far from any consensus. The two most popular suggestions for forming ignimbrites, extraction of partial melt from a granitic upper crust reservoir or lower crustal hot zone melting, are each inconsistent with some observations/constraints. 100% melting of a granite mush, which may be consistent with many observations, was previously proposed1 but dismissed due to the large amount of latent heat needed to completely melt a mush. This work first presents new non-traditional isotope ratio data (Fe, Si) for plutonic and volcanic rocks suites showing that like Harker diagrams, volcanics and plutonics produce identical systematic behavior with differentiation. δ56Fe forms upwardly curving trends with increasing silica whereas δ30Si increases linearly. The logical deduction is that volcanics reflect 100% mobilization of a granite mush (not necessarily melting). While the origin of NTSI variations remains debated, the systematic NTSI trends are consistent with prediction of a top-down thermal migration zone refining (TMZR) process2. In part 2, we assume TMZR generates a granitic mush and propose that an instability in this mush leads to a runaway effect that results in eruption of aphyric ignimbrite. Experiments show that wet andesite evolves to granite at the cold (400°C) end of a thermal gradient3 with hydrous peralkaline melt existing interstitially. Previous work4 shows that such melts show retrograde immiscibility, segregating into a water rich melt and a water poor melt with temperature increase. Thus, as the mush builds down into hot crust, it crosses the immiscibility boundary triggering release of the water-rich phase; buoyant rise and

  11. Magmatic construction and duration of solidification of Searchlight pluton, Eldorado Mountains, Nevada (USA)

    NASA Astrophysics Data System (ADS)

    Miller, J. S.; Cates, N. L.; Miller, C. F.; Wooden, J. L.; Means, M. A.; Ericksen, S.

    2003-12-01

    The process of chamber construction and the residence time of magma in mid- to upper crustal magma bodies have been illuminated by recent advances in high-resolution geochronology. Most work has so far concentrated on young volcanic systems; few geochrononlogic data have addressed magma chamber longevity and history from studying plutons. Plutons offer an important complementary record of magma processing and solidification, and can therefore reveal much about the internal workings of magma chambers. The Miocene Searchlight pluton (Nevada, USA) is a spectacular example of a very thick magma chamber (10-12 km). Crystal accumulation (mafic quartz monzonite cumulate), coupled with roof-down solidification (upper quartz monzonite) resulted in segregation of evolved felsic melt in the chamber interior (middle granite). Initially horizontal and gradational internal contacts and coplanar magmatic fabrics between all major units, geochemical mass balance, and very limited isotopic variation among major units, suggest that the entire pluton was molten at one time. However, the time inteval over which the chamber solidified was not well known. New TIMS and in situ ion microprobe U/Pb dating of zircon, combined with our earlier and ongoing field and isotopic studies, now appear to document a protracted magma chamber history. TIMS and ion microprobe dating (Stanford/USGS SHRIMP-RG) was done on two samples, and a third sample was dated by ion microprobe only. A multi-grain, multi-fraction discordia lower intercept age of 16.7+/-0.5 Ma (MSWD=22) was obtained by TIMS from the lower mafic quartz monzonite cumulate. Ion probe dating of zircons from the same sample yielded a 206Pb/238U age of 16.9+/-0.2 Ma (MSWD=1.3; N=24) in agreement with the TIMS lower intercept age. A discordia lower intercept age of 15.7+/-0.4 Ma (MSWD=3.7, one concordant point at 15.8 Ma) was obtained from the middle granite unit. Ion probe dating of zircons from the same sample yielded a 206Pb/238U age of 16

  12. Ordovician volcanic and plutonic complexes of the Sakmara allochthon in the southern Urals

    NASA Astrophysics Data System (ADS)

    Ryazantsev, A. V.; Tolmacheva, T. Yu.

    2016-11-01

    The Ordovician terrigenous, volcanic-sedimentary and volcanic sequences that formed in rifts of the active continental margin and igneous complexes of intraoceanic suprasubduction settings structurally related to ophiolites are closely spaced in allochthons of the Sakmara Zone in the southern Urals. The stratigraphic relationships of the Ordovician sequences have been established. Their age and facies features have been specified on the basis of biostratigraphic and geochronological data. The gabbro-tonalite-trondhjemite complex and the basalt-andesite-rhyolite sequence with massive sulfide mineralization make up a volcanic-plutonic association. These rock complexes vary in age from Late Ordovician to Early Silurian in certain structural units of the Sakmara Allochthon and to the east in the southern Urals. The proposed geodynamic model for the Ordovician in Paleozoides of the southern Urals reconstructs the active continental margin, whose complexes formed under extension settings, and the intraoceanic suprasubduction structures. The intraoceanic complexes display the evolution of a volcanic arc, back-, or interarc trough.

  13. A topaz- and amazonite-bearing leucogranite pluton in eastern Xinjiang, NW China and its zoning

    NASA Astrophysics Data System (ADS)

    Gu, Lian-xing; Zhang, Zun-zhong; Wu, Chang-zhi; Gou, Xiao-qin; Liao, Jing-juan; Yang, Hao

    2011-10-01

    The highly evolved Baishitouquan (BST) beryl-mineralised and topaz-bearing amazonite granite pluton is situated in the eastern Tianshan orogen of northwestern China. This pluton exhibits five well-exposed lithological zones, which, gradational from the lowest level, are leucogranite (zone-a), amazonite-bearing granite (zone-b), amazonite granite (zone-c), topaz-bearing amazonite granite (zone-d) and topaz albite granite (zone-e). The rocks are composed mainly of quartz, albite, and K-feldspar with varying amounts of topaz and amazonite. Quartz and topaz phenocrysts are the earliest phases that crystallised from the melt. Amazonite which replaced albite and K-feldspar was formed at the late magmatic stage or during the magmatic-hydrothermal transition. Geochemically, this pluton is characterised by high F (>2 wt.%) and Rb (499.5-1087.04 ppm), low P 2O 5 (⩽0.06 wt.%), Na 2O > K 2O, A/NKC = 1.00-1.11, low ratios of K/Rb, Al/Ga, Y/Ho, Zr/Ha and Nb/Ta, Σ14 REE = 28.6-231.9 ppm with gull wing-shaped distribution patterns (La CN/Lu CN = 0.11-0.68, Eu/Eu * = 0.0005-0.0110) and tetrad effects, and δ 18O = 9.75-7.32‰. Melt and fluid-melt inclusions coexist with liquid and vapour inclusions. The rocks were originated from a highly evolved granitic magma. The BST pluton exhibits transition in the following aspects from zone-a to zone-e: (1) As quartz and topaz phenocrysts progressively increase in size and crystal euhedral shape, rock textures change from equigranular to porphyritic. (2) Amazonite begins to appear in zone-b and becomes most concentrated in zone-c, whereas topaz begins to appear in zone-d becoming highly concentrated in zone-e. (3) Li and (Al + Ti) increase in white mica. (4) Petrochemically, there are general trends of increasing F, Al 2O 3 and Na 2O, and decreasing SiO 2, (Fe 2O 3 + FeO + MgO + MnO) and K 2O. Plots of normative compositions on the Qz-Ab-Or diagram move gradually towards the Ab apex. (5) Overall, Cr, Ni, Co, V, W, Nb, Zr, U, Th and Y

  14. Transport and Depositional Model for Large Country Rock Blocks Within the Searchlight Pluton, Southern Nevada

    NASA Astrophysics Data System (ADS)

    Perrault, D. S.; Furbish, D. J.; Miller, C. F.

    2006-05-01

    Searchlight pluton, a steeply tilted, 10 km thick Miocene intrusion in the Colorado River Extensional Corridor, exposes a zone with abundant, 5-400 m long blocks of Proterozoic gneiss. Blocks are present within a pair of subparallel horizons that make up a 2 km-thick zone and extend about 6 km laterally away from the pluton's north margin slightly oblique to the initially subhorizontal boundary between the pluton's middle unit (granite) and lower unit (qtz monzonite). Blocks are a variety of Precambrian metasedimentary gneisses, granitic gneisses, and mylonites. Blocks are commonly polylithologic and well foliated, with long and intermediate dimensions parallel to both their own foliation and that of the granitic host. Their average aspect ratio is ~ 4:1. Blocks within these horizons are interpreted as stoped (detached country rock that experience gravity- induced displacement) based on several lines of evidence. First, the distribution and abundances of blocks are not consistent with an isolated panel of wall rock (screen). The zone is laterally discontinuous (local abundances vary from ~ 0-40 %); transects a gradational (cm-m scale) internal contact at a slightly oblique angle; and tapers away from the pluton's margin. Second, while block foliations are homoclinal and show fairly consistent attitudes from block to block, block foliations are discordant with wall rock foliations at the same stratigraphic level (adjacent north wall). Third, mush disturbance features such as schlieren and enhanced feldspar foliation beneath blocks suggest a downward compaction. We interpret the blocks to have been emplaced after wall collapse events. We are using scaled settling experiments to clarify how blocks move within viscous fluids and interact with crystal mushes. The experiments, involving tabular ceramic blocks with density ρ = 1.75-2.20 g cm-3 settling in shampoo (ρ = 1.02 g cm-3) with viscosity μ = 20.35 Pa s, are scaled to order-of-magnitude by the particle Reynolds

  15. Calc-alkaline mafic rocks of the Black Dyke Formation: Remnants of the final activity of a submerged Permian volcano

    SciTech Connect

    Blein, O.; Lapierre, H.; Pecher, A. ); Schweickert, R.A. . Dept. of Geological Science)

    1993-04-01

    The Permian Black Dyke Fm., which occurs as large tectonic slices within the Luning allochthon in the Excelsior Mountains, NV, forms an E-W trending anticline at Black Dyke Mountain. The 800-m thick stratigraphic succession consists of volcanic and pyroclastic rocks overlain conformably by volcaniclastic sediments. Along the northern limb of the anticline, the rocks consist of mafic porphyritic lavas, breccias, and graded and ungraded pyroclastic beds. The sedimentary unit consists of thick volcaniclastic turbidites overlain by conglomerates, sandstones, and mudstones. Along the southern limb of the anticline, the sequence is replaced by reworked breccia, tuffs, and sandstones. Mafic plutonic rocks occur as xenoliths in the lavas and breccias, and as coeval plugs intruding the section. Gabbros show cumulate or porphyritic textures and are composed of amph, cpx, and zoned plag. Their Ti/V (14.5--15) and Nb/Y (0.25--0.3) ratios fall in the range commonly found in calc-alkaline rocks. Diorite porphyry shows high Al[sub 2]O[sub 3], ZrO[sub 2], and REE abundances indicating that this rock is more fractionated. Basalts and andesites are plag-cpx-opx phyric. They often include glomeroporphyritic clots of cpx with amph coronas. Some rocks exhibit fluidal textures. Both volcanic and plutonic rocks show homogeneous geochemical features and similar crystallization sequences: Fe-Ti oxides---->plag---->opx + cpx----> brown zoned hbl, suggesting that they are cogenetic. Thus, the lower part of the Black Dyke Fm. likely represents the final products formed in a calc-alkaline magma chamber because pyroclastic rocks prevail over lava flows and abundant early crystal cumulates occur as plugs or as inclusions in the lavas and breccias.

  16. Spatially controlled Fe and Si isotope variations: an alternative view on the formation of the Torres del Paine pluton

    NASA Astrophysics Data System (ADS)

    Gajos, Norbert A.; Lundstrom, Craig C.; Taylor, Alexander H.

    2016-11-01

    We present new Fe and Si isotope ratio data for the Torres del Paine igneous complex in southern Chile. The multi-composition pluton consists of an approximately 1 km vertical exposure of homogenous granite overlying a contemporaneous 250-m-thick mafic gabbro suite. This first-of-its-kind spatially dependent Fe and Si isotope investigation of a convergent margin-related pluton aims to understand the nature of granite and silicic igneous rock formation. Results collected by MC-ICP-MS show a trend of increasing δ56Fe and δ30Si with increasing silica content as well as a systematic increase in δ56Fe away from the mafic base of the pluton. The marginal Torres del Paine granites have heavier Fe isotope signatures (δ56Fe = +0.25 ± 0.02 2se) compared to granites found in the interior pluton (δ56Fe = +0.17 ± 0.02 2se). Cerro Toro country rock values are isotopically light in both Fe and Si isotopic systems (δ56Fe = +0.05 ± 0.02 ‰; δ30Si = -0.38 ± 0.07 ‰). The variations in the Fe and Si isotopic data cannot be accounted for by local assimilation of the wall rocks, in situ fractional crystallization, late-stage fluid exsolution or some combination of these processes. Instead, we conclude that thermal diffusion or source magma variation is the most likely process producing Fe isotope ratio variations in the Torres del Paine pluton.

  17. Jurassic plutons in the Desolation wilderness, northern Sierra Nevada batholith, California: A new segment in the Jurassic magmatic arc

    SciTech Connect

    Sabine, C. . Quaternary Sciences Center)

    1993-04-01

    A 164[+-]7 Ma U-P zircon date establishes a Middle- to Late-Jurassic age for the Pyramid Peak granite and synplutonic dioritoids and hybrid rocks that comprise the Crystal Range suite, located southwest of Lake Tahoe. A Jurassic age is also assigned to the Keiths Dome quartz monzonite and the Desolation Valley and Camper Flat granodiorites (Loomis', 1983, Early Granitic Group) which are distinctly older than surrounding Cretaceous granitoids. The Keiths Dome quartz monzonite, the oldest pluton of the group, may be as old as 180 Ma and is distinguished by ductile shear zones and recrystallization textures which indicate an episode of deformation not undergone by other plutons. The Camper flat and Desolation Valley granodiorites are the youngest plutons of the group. ENE-trending microdiorite dikes filled extensional fractures, perpendicular to the direction of shortening, in all Jurassic plutons but on none of the Cretaceous bodies. Jurassic plutons may help constrain ages of metasedimentary and metavolcanic rocks and associated structures in the Mount Tallac roof pendant. The Pyramid Peak granite intrudes the Sailor Canyon Formation which bears Late Pliensbachian ammonites (Fisher, 1990), and the Keiths Dome quartz monzonite intrudes the overlying Tuttle Lake Formation and transects faults and shear zones in the pendant. Initial Sr isotope ratios for the Pyramid Peak granite range between 0.705427 and 0.706874, spanning the 0.706 value taken by some to mark the western limit of sialic lower crust. Data suggest an isotopically mixed source containing mantle and crustal components. Such an environment is not inconsistent with a passive continental margin where mafic magma invades rifted continental crust.

  18. A Structural-Thermal Model of the Karkonosze Pluton (Sudetes Mountains, SW Poland) for Hot Dry Rock (HDR) Geothermal Use

    NASA Astrophysics Data System (ADS)

    Bujakowski, Wiesław; Barbacki, Antoni; Miecznik, Maciej; Pająk, Leszek; Skrzypczak, Robert

    2016-12-01

    The main objective of this study was to develop a spatial temperature distribution of the Karkonosze Pluton to indicate optimum locations for HDR systems at drillable depth. HDR geothermal technology makes it possible to extract heat from the Earth in areas where no hydro-geothermal resources are present. To produce electricity in a binary cycle, system temperatures of > 100°C are usually required. In this paper, the authors have analysed the potential opportunities for applying HDR technology in the area of the Karkonosze Pluton, which is regarded as an optimum location for the application of the HDR concept (due to the potential for stimulation offered by the mechanical properties of the granites, radiogenic heat production, modern tectonic activity, and the thickness of the pluton). The model used in the analysis, which takes into account a hypothetical assessment of the manner and paths of fluid migration within the pluton, provides an insight into the spatial distribution of subsurface temperatures. It thus allows the location of relatively shallow high-temperature zones, which are optimal for the efficient application of HDR technology, to be identified. With respect to this technology, the Szklarska Poręba area and the NE part of the pluton seem to be better targets than the Cieplice central area, where the model indicated much lower temperatures (e.g. at a depth of 5,000 m, estimated temperatures in the vicinity of Szklarska Poręba were about 185°C and in the vicinity of Cieplice they were about 140°C).

  19. Petrology and geochemistry of the Russian peak pluton, Klamath Mountains, northern California

    SciTech Connect

    Cotkin, S.J.

    1987-01-01

    The Jurassic Russian Peak pluton consists of an older peridotite-to-quartz diorite complex intruded by younger granodiorite. U-Pb ages of 159 Ma have been obtained for both units. The peridotite-to-quartz diorite complex consists principally of quartz diorite; however, cumulate ultramafic rocks occur where it is in contact with Ordovician serpentinite, and the following zonation from serpentinite to quartz diorite is present: peridotite, pyroxenite, hornblendite, eucrite, and diorite. In order to evaluate the petrogenesis of the pluton a combination of field, petrographic, microprobe, X-ray fluorescence, and instrumental neutron activation analysis, and Rb-Sr data have been collected. Major and trace element modeling indicates that quartz-rich quartz diorite formed by crystallization, quartz-poor quartz diorite by accumulation of crystals plus trapped liquid, and ultramafic rocks by assimilation of serpentinite. Granodiorite on the other hand can be modeled by crystallization alone, with the precipitation of plagioclase, amphibole, and biotite accounting for the major and minor element variations. REE modeling indicates that a garnet-clinopyroxene amphibolite is a plausible source. A variety of techniques have been used to decipher the conditions of crystallization in each unit, including a comparison of paragenesis with crystallization experiments, geological thermometry and barometry, and phase equilibria. Pressure of intrusion is considered to have been approximately 3 kbar. The peridotite-to-quartz diorite complex intruded at about 1000/sup 0/C and was completely crystalline at 790/sup 0/C. Granodiorite intruded at somewhat lower temperatures and was completely crystalline at about 700/sup 0/C. The oxygen fugacity for both units was slightly above QFM. At its solidus, granodiorite was saturated with H/sub 2/O, which may account for the pervasive deuteric alteration of this unit.

  20. Europium mass balance in polymict samples and implications for plutonic rocks of the lunar crust

    SciTech Connect

    Korotev, R.L.; Haskin, L.A. )

    1988-07-01

    From correlations of SM concentration and Sm/Eu ratio with Th concentration for a large number of polymict samples from various locations in the lunar highlands and the value of 0.91 {mu}g/g for the mean Th concentration of the highlands surface crust obtained by the orbiting gamma-ray experiments. The authors estimate the mean concentrations of Sm and Eu in the lunar surface crust to be between 2 and 3 {mu}g/g Sm and 0.7 and 1.2 {mu}g/g Eu. The compositional trends indicate that there is no significant enrichment or depletion of Eu, on the average, compared to Sm relative to chondritic abundances, i.e., there is no significant Eu anomaly in average upper crust. Although rich in plagioclase ({approximately}70%), the upper crust does not offer evidence for a gross vertical separation of plagioclase from the final liquid from which it crystallized. This and the chondritic ratio of Eu/Al in average highlands material imply that the net effect of the processes that led to formation of the lunar crust was to put most of the Al and incompatible elements in the crust. Among plutonic rocks, only plagioclase in rocks from the magnesian suite can supply the excess Eu in the polymict rocks. Owing to the intermediate value of the mean Mg/Fe ratio of the crust, a significant fraction of the mafic rocks of the lunar highlands must have lower Mg/Fe ratios than the norites and troctolites of the magnesian-suite of plutonic rocks. A large fraction of the plagioclase in the lunar crust is associated not with ferroan anorthosite, but with more mafic rocks. There is little evidence in the Eu data that the lunar crust ever consisted of a thick shell of nearly pure plagioclase, as envisioned in some formulations of the magma ocean model of its formation.

  1. Metamorphism and plutonism around the middle and south forks of the Feather River, California

    USGS Publications Warehouse

    Hietanen, Anna Martta

    1976-01-01

    The area around the Middle and South Forks of the Feather River provides information on metamorphic and igneous processes that bear on the origin of andesitic and granitic magmas in general and on the variation of their potassium content in particular. In the north, the area joins the Pulga and Bucks Lake quadrangles studied previously. Tectonically, this area is situated in the southern part of an arcuate segment of the Nevadan orogenic belt in the northwestern Sierra Nevada. The oldest rocks are metamorphosed calcalkaline island-arc-type andesite, dacite, and sodarhyolite with interbedded tuff layers (the Franklin Canyon Formation), all probably correlative with Devonian rocks in the Klamath Mountains. Younger rocks form a sequence of volcanic, volcaniclastic, and sedimentary rocks including some limestone (The Horseshoe Bend Formation), probably Permian in age. All the volcanic and sedimentary rocks were folded and recrystallized to the greenschist facies during the Nevadan (Jurassic) orogeny and were invaded by monzotonalitic magmas shortly thereafter. A second lineation and metamorphism to the epidote-amphibolite facies developed in a narrow zone around the plutons. In light of the concept of plate tectonics, it is suggested that the early (Devonian?) island-arc-type andesite, dacite, and sodarhyolite (the Franklin Canyon Formation) were derived from the mantle above a Benioff zone by partial melting of peridotite in hydrous conditions. The water was probably derived from an oceanic plate descending to the mantle. Later (Permian?) magmas were mainly basaltic; some discontinuous layers of potassium-rich rhyolite indicate a change into anhydrous conditions and a deeper level of magma generation. The plutonic magmas that invaded the metamorphic rocks at the end of the Jurassic may contain material from the mantle, the subducted oceanic lithosphere, and the downfolded metamorphic rocks. The ratio of partial melts from these three sources may have changed with time

  2. Geology and geochemistry of the Mount Riley-Mount Cox pluton, Dona Ana County, New Mexico

    SciTech Connect

    Zimbelman, D.R.; Siems, D.F.; Kilburn, J.E.; Hubert, A.E.

    1985-01-01

    The Mount Riley-Mount Cox area is comprised of a relatively homogeneous pluton of rhyodacite rising some 1600 feet above the La Mesa surface. The pluton, of apparent Tertiary age, intrudes Cretaceous sedimentary rocks and Tertiary ( ) latite and tuff. The rhyodacite is holocrystalline, light gray to pinkish gray, porphyritic to microporphyritic, and locally banded. Phenocrysts include hornblende, quartz, biotite, and calcite. The phenocrysts range in size from 0.2 to 2 mm and make up one to fifteen percent of the rock. The phenocrysts often display a glomerophyric texture within a trachytic groundmass. The groundmass ranges from cryptocrystalline to very fine grained and is composed of plagioclase, quartz, potassium feldspar, hornblende/biotite, and iron-oxide material. Locally, the rhyodacite displays millimeter-scale banding and a poikilitic texture consisting of quartz oikiocrysts and plagioclase chadocrysts. The rhyodacite averages 68.74%, SiO/sub 2/, 0.39% TiO/sub 2/, 16.40% Al/sub 2/O/sub 3/, 2.87% Fe/sub t/, 0.10% MnO, 1.21% MgO, 2.56% CaO, 3.79% Na/sub 2/O, and 3.96% K/sub 2/O. The rhyodacite is cut by veins and veinlets of brown to white calcite. The veins attain a maximum thickness of one meter, are locally bordered by calcite-cemented breccia zones, and locally include pyrite. The veins trend north or northwest, consistent with regional trends for the Rio Grande rift and the Texas Lineament, respectively. Sixty-five samples of rhyodacite, breccia, and vein were analyzed for 31 elements by emission-spectrographic methods. Trace-element data suggestive of hydrothermal mineralization was not recognized.

  3. Epithermal and plutonic gold mineralizations related to paleoproterozoic acid magmatism in the Tapajós Gold province, Amazonian craton, Brazil

    NASA Astrophysics Data System (ADS)

    Juliani, C.; Corrêa-Silva, R. H.; Monteiro, L. V.; Bettencourt, J. S.; dall Agnol, R.

    2003-04-01

    The Tapajós Gold Province (TGP) is part of the Tapajós-Parima geologic province, that includes ˜2.1 Ga volcano-sedimentary sequences (Jacareacanga Group) and the magmatic arcs of the Cuiú-Cuiú Complex (˜2.01 Ga), Creporizäo Intrusive Suite (1.97-1.95 Ga), Rio das Tropas Tonalite (˜1.90 Ga) and Parauari Intrusive Suite (˜1.88 Ga). Andesitic to rhyolitic volcanic and volcaniclastic rocks of the Iriri Group (1.88 Ga) overlie plutonic rocks and are cut by anorogenic Maloquinha Intrusive Suite (˜1.87 Ga). Paleoproterozoic fluvial to marine sequences (Buiuçú Formation), and several mafic intrusion events are also identified in the TGP. Paleoproterozoic gold mineralizations in the TGP are mainly classified as mesothermal orogenic lodes, intrusion-related gold systems, and epithermal and mesothermal lodes in shear zones. Recently, it was discovered a 1.869 Ga epithermal high-sulfidation (quartz-alunite) and low-sulfidation (adularia-sericite) gold and base metal mineralizations hosted in calc-alkaline volcanic and volcaniclastic rocks of the Iriri Group. In the high-sulfidation mineralization, hydrothermal breccias are strongly affected by high-temperature advanced argillic alteration, with alunite, natroalunite, woodhouseiite-svanbergite, andalusite, diaspore and enargite, besides argillic and propylitic hydrothermal alterations. Over the hydrothermal breccia pipe occurs a hematite-rich silica cap and in the deeper zones sericitic alteration is also present. The epithermal high- and low-sulfidation mineralizations are geneticaly linked to stocks of hydrothermalized granophyry, and rhyolitic and rhyodacitic porphyry dikes and are hosted by late ring composite volcanoes, related to evolution of nested ash-flow caldera complexes. The caldera genesis is atributed to emplacement of shalow late- to post-tectonic calc-alkaline batholits of the Parauari Intrusive Suite in back-arc rifts. The mesozonal relatively reduced Batalha Granite hosts gold mineralizations and

  4. Closed type alkaline storage battery

    SciTech Connect

    Hayama, H.

    1980-06-10

    The alkaline storage battery employs a metallic hat shaped terminal closure which has a piercing needle as well as a puncturable metallic diaphragm positioned below the piercing needle. The needle is fixed by caulking at its peripheral edge portion to a edge of the closure. A comparatively thick and hard metal plate is placed on the inner surface of the diaphragm and is applied to an open portion of a tubular metallic container which has a battery element. A peripheral edge portion of the closure, the diaphragm and the metallic plate are clamped in airtight relationship through a packing between the caulked end portion and an inner annular step portion of the metallic container of the battery. A lead wire extends from one polarity electrode of the battery element and is connected to a central portion of the metallic plate.

  5. Structural evolution of the Rieserferner Pluton: insight into the localization of deformation and regional tectonics implications

    NASA Astrophysics Data System (ADS)

    Ceccato, Alberto; Pennacchioni, Giorgio

    2016-04-01

    The Rieserferner pluton (RFP, Eastern Alps, 32.2±0.4 Ma, Romer et al. 2003) represents a relatively deep intrusion (12-15 km; Cesare, 1994) among Periadriatic plutons. The central portion of the RFP consists of dominant tonalites and granodiorites that show a sequence of solid-state deformation structures developed during pluton cooling and exhumation. This sequence includes: (1) quartz veins, filling two set of steeply-dipping joints trending respectively E-W and NW-SE, commonly showing a millimetric grain size and associated with strike-slip displacement. (2) Quartz- and locally epidote-filled shallowly E-dipping joint set, commonly exploited as discrete derived from both the quartz veins and the host tonalite. These mylonites show a composite sense of shear with a first stage of left-lateral strike-slip followed by a top-to-E dip-slip (normal) movement. The synmylonitic assemblage includes biotite + plagioclase + white mica + epidote ± sphene ± garnet. (3) Set of N-S-trending steeply-dipping joints. These joints are concentrated in zones 1-2 m wide, separated by otherwise un-jointed domains a few tens to hundred meters wide, and are commonly exploited as brittle-ductile faults with dominant dip-slip (normal) kinematics. The mineral assemblage of fault rocks includes white mica + calcite ± chlorite ± quartz. The joints/faults are locally involved in folding. (4) Mafic dikes, dated at 26.3±3 Ma (Steenken et al., 2000), locally injecting the N-S trending set of joints. (5) Cataclasite- and pseudotachylyte-bearing faults also forming a set of steeply-dipping N-S-trending structures. These faults are commonly associated with epidote veins surrounded by bleaching haloes. (6) Zeolite-bearing faults marked by whitish cataclasites, fault gouges and mirror-like surfaces. These faults have a complex oblique- to strike-slip kinematics with an overall N-S trending lineation. As observed in other plutons (e.g. Adamello; Pennacchioni et al., 2006), the network of

  6. Evolution of alkaline phosphatases in primates.

    PubMed Central

    Goldstein, D J; Rogers, C; Harris, H

    1982-01-01

    Alkaline phosphatase [orthophosphoric-monoester phosphohydrolase (alkaline optimum), EC 3.1.3.1] in placenta, intestine, liver, kidney, bone, and lung from a variety of primate species has been characterized by quantitative inhibition, thermostability, and immunological studies. Characteristic human placental-type alkaline phosphatase occurs in placentas of great apes (chimpanzee and orangutan) but not in placentas of other primates, including gibbon. It is also present in trace amounts in human lung but not in lung or other tissues of various Old and New World monkeys. However, a distinctive alkaline phosphatase resembling it occurs in substantial amounts in lungs from Old World monkeys but not New World monkeys. It appears that duplication of alkaline phosphatase genes and mutations of genetic elements controlling their tissue expression have occurred relatively recently in mammalian evolution. Images PMID:6950431

  7. Alkaline pH sensor molecules.

    PubMed

    Murayama, Takashi; Maruyama, Ichiro N

    2015-11-01

    Animals can survive only within a narrow pH range. This requires continual monitoring of environmental and body-fluid pH. Although a variety of acidic pH sensor molecules have been reported, alkaline pH sensor function is not well understood. This Review describes neuronal alkaline pH sensors, grouped according to whether they monitor extracellular or intracellular alkaline pH. Extracellular sensors include the receptor-type guanylyl cyclase, the insulin receptor-related receptor, ligand-gated Cl- channels, connexin hemichannels, two-pore-domain K+ channels, and transient receptor potential (TRP) channels. Intracellular sensors include TRP channels and gap junction channels. Identification of molecular mechanisms underlying alkaline pH sensing is crucial for understanding how animals respond to environmental alkaline pH and how body-fluid pH is maintained within a narrow range.

  8. Geochemical and Isotopic Data for Oligocene Ignimbrites, Calderas, and Granitic Plutons, Southern Stillwater Range and Clan Alpine Mountains: Insights into the Volcanic-Plutonic Connection and Crustal Evolution in Western Nevada

    NASA Astrophysics Data System (ADS)

    John, D. A.; Colgan, J. P.; Watts, K. E.; Henry, C.; Cousens, B.

    2015-12-01

    Oligocene calderas and underlying plutons in the southern Stillwater Range (SSR) and Clan Alpine Mountains (CAM) in western Nevada were tilted (40->90°) by large-magnitude Miocene extension and unconformably overlain by 15-13 Ma intermediate and mafic lava flows. New geologic mapping, geochemistry, and Ar-Ar and U-Pb dating document 2 brief periods of magmatism resulting in 5 nested calderas and related plutons in sections locally ≥9 km thick. Early magmatism at ~29 Ma included the Deep Canyon caldera in CAM, and in the SSR, pre-caldera rhyolites, ~5 km of pre- and post-collapse intermediate lavas and rhyolite tuff that filled Job Canyon caldera (JC, ~29.4 to 28.8 Ma), and the >4-5 km thick IXL pluton (~28.5 Ma) that intruded JC and is compositionally similar to the tuff and lava flows. The second period included 3 ignimbrite units in 3 calderas: small-volume tuff of Louderback Mountains (LM, low-silica rhyolite; ≥600 m thick; ~25.3 Ma); multiple cooling units of tuff of Poco Canyon (PC, high-silica rhyolite; ≤4.5 km thick; ~25.3 Ma); and ≥2500 km3 of tuff of Elevenmile Canyon (EC, trachydacite to rhyolite; ≤4.5 km thick; 25.1 Ma) that covers ~1600 km2 and extends east from SSR to the northern Desatoya Mountains. The composite Freeman Creek pluton (granodiorite, ~25.0 Ma; granite, ~24.8 Ma) and Chalk Mountain rhyolite porphyry (~25.2 Ma) and granite (~24.8 Ma) plutons intruded LM, PC and EC calderas. Radiogenic isotopes in all caldera units are similar (Sri~0.7050, ΕNd~0.0), while oxygen isotope compositions are variable (δ18Oquartz=5.7-8.4‰, δ18Ozircon=4.1-6.3‰), corresponding to a magmatic range of 5.6-7.6‰, including <6‰ values for JC and lower PC rhyolites. U-Pb zircon dating shows homogeneous age populations and few/no xenocrysts or antecrysts. These data show that (1) thick plutons (>2-5 km) underlie compositionally and temporally related caldera-filling ignimbrites, (2) caldera-forming cycles are isotopically variable, requiring

  9. A paleomagnetic and magnetic fabric study of the Illapel Plutonic Complex, Coastal Range, central Chile: Implications for emplacement mechanism and regional tectonic evolution during the mid-Cretaceous

    NASA Astrophysics Data System (ADS)

    Ferrando, Rodolfo; Roperch, Pierrick; Morata, Diego; Arriagada, César; Ruffet, Gilles; Córdova, Maria Loreto

    2014-03-01

    The Illapel Plutonic Complex (IPC), located in the Coastal Range of central Chile (31°-33° S), is composed of different lithologies, ranging from gabbros to trondhjemites, including diorites, tonalites and granodiorites. U/Pb geochronological data shows that the IPC was amalgamated from, at least, four different magmatic pulses between 117 and 90 Ma (Lower to mid-Cretaceous). We present new paleomagnetic results including Anisotropy of Magnetic Susceptibility (AMS) from 62 sites in the plutonic rocks, 10 sites in country rocks and 7 sites in a mafic dyke swarm intruding the plutonic rocks.

  10. A 2 Million Year History of Plutonism and Volcanism in the Searchlight Magma System, Eldorado Mountains, Nevada (USA)

    NASA Astrophysics Data System (ADS)

    Miller, J.; Miller, C.; Wooden, J.; Perrault, D.; Hodge, K.; Faulds, J.; Cates, N.; Means, M.

    2006-12-01

    Subvolcanic plutons provide an important record of magma processing and solidification of upper crustal magma bodies but rarely can they be compared with volcanic output from the same magma system. In the Colorado River extensional corridor of southern Nevada, steep tilting caused by crustal extension has exposed outstanding examples of large intrusions that have complementary volcanic output. One of the best examples is the 12 km thick Searchlight pluton and its overlying volcanic cover. Earlier work in the pluton documented vertical growth, wherein crystal accumulation (mafic quartz monzonite cumulate) and roof-down solidification (upper quartz monzonite) resulted in segregation of evolved felsic melt in the chamber interior (middle granite). This general evolutionary sequence is mirrored by lava flow stratigraphy in steeply tilted volcanic sections that are structurally above the roof of Searchlight pluton. We have obtained more than 400 ion microprobe U/Pb zircon ages (Stanford/USGS SHRIMP-RG) on more than 20 samples for the pluton and overlying volcanic rocks in order to temporally link the volcanic rocks with the intrusive rocks. The oldest unit from Searchlight pluton is a gabbro pod near the northern margin of the lower Searchlight quartz monzonite that yielded a 206Pb/238U age of 17.7±0.3 Ma (all age errors reported are 1σ; MSWD ~1 or lower except where noted) but the main lower quartz monzonite from structurally deep has a 206Pb/238U age of 16.9±0.2 Ma. This age is the same age as trachydacite porphyry dikes and pods (16.6±0.3 Ma) that intrude upper Searchlight (but not lower Searchlight) and an identical trachydacite lava flow from near the base of a sequence of trachydacite flows above the pluton (16.9±0.4 Ma; MSWD 1.9). Samples of the middle granite and a gabbro that interacts with the granite are interpreted to be the last materials to solidify in the pluton and have 206Pb/238U ages ranging from 15.9-16.2 Ma but with MSWD's >3. Distinct age peaks

  11. The role of felsic microgranular enclaves on the evolution of some Neoproterozoic granite plutons in SE Brazil

    NASA Astrophysics Data System (ADS)

    Alves, Adriana; Janasi, Valdecir A.; Pereira, Giovanna

    2010-05-01

    Recent studies of granite petrogenesis are strongly influenced by the finding that mafic microgranular enclaves (mme) witness frequent and volumetrically significant contribution of mantle-derived magmas to the origin and evolution of granitic melts, be it as a heat source and/or as a source compositional diversity. On the other hand, the origin of felsic microgranular enclaves (fme) is still a matter of debate; current hypotheses consider them as fragments of chilled margins, products of protracted hybridization between invading basic magmas and resident granite mushes or products of interaction between fairly similar melts. Felsic microgranular enclaves are widespread in various granite plutons from SE Brazil, in many cases surpassing mme in size and volume. Two groups of occurrences are studied in more detail illustrate different scenarios, with and without clear connections with mafic magmas. In the Mauá and Mogi das Cruzes plutons, made up of (muscovite)-biotite monzogranite, only fme occur, and the participation of more mafic melts is not evident from field structures or from whole rock and mineral chemical/isotope data. Our preferred model relate the fme to self-mixing events, suggesting mingling/mixing between highly viscous and chemically similar felsic endmembers. In the Itu Batholith, mme enclaves occur, albeit in very different volumes, in three chemically distinct plutons, all with A-type chemical affinities, In the rapakivi Salto Pluton, fme are large (dm to meter-sized) and widespread, except in a central body of porphyry granite. Scattered cm-sized mme of variable composition, some clearly brought as inclusions in the fme, are thought to represent different stages of hybridization, as indicated by disequilibrum features common also in the host syenogranites (rapakivi texture; mafic-rimmed quartz). The enclave assemblage of the Cabreúva Pluton is similarly dominated by fme, but larger mme and small diorite occurrences are evidence that basic magmas

  12. The generation of high Sr/Y plutons following Late Jurassic arc-arc collision, Blue Mountains province, NE Oregon

    NASA Astrophysics Data System (ADS)

    Schwartz, Joshua J.; Johnson, Kenneth; Miranda, Elena A.; Wooden, Joseph L.

    2011-09-01

    High Sr/Y plutons (Sr/Y > 40) occupy large areas in ancient and modern orogenic belts, yet considerable controversy exists regarding mechanisms of their generation, the tectonic settings in which they form, and their relationship to contractional deformation through time. In the Blue Mountains province (NE Oregon), a suite of Late Jurassic (148-145 Ma), high Sr/Y plutons intrude Middle Jurassic (162-157 Ma), low Sr/Y (< 40) arc-related lavas and plutons in the Dixie Butte area immediately after widespread Late Jurassic arc-arc collision (159-154 Ma). Early, pre- to syn-kinematic low Sr/Y lavas and plutons (162-157 Ma) have flat to slightly enriched light rare earth element (REE) abundances, low Sr (< 400 ppm) and Sr/Y values (< 40), and strongly positive initial epsilon Hf values (+ 10.1 to + 12.3: 2σ weighted average). Ce/Y values from basalts and gabbros yield a maximum crustal thickness of ~ 23 km. These geochemical and isotopic features suggest derivation from a depleted-mantle source and/or shallow-level (≪ 40 km) melting of pre-existing island arc crust with little to no evolved crustal input. In contrast, post-kinematic high Sr/Y plutons (148-145 Ma) are more compositionally restricted (tonalite-trondhjemite-granodiorite) and display depleted heavy REE abundances, an absence of Eu anomalies, elevated Sr (> 600 ppm) and Sr/Y values (> 40), and positive initial epsilon Hf values (+ 10.5 to + 7.8: 2σ weighted average). These geochemical and isotopic results are consistent with geochemical models suggesting derivation from partial melting of island arc crust in the presence of a plagioclase-poor to absent, clinopyroxene + hornblende + garnet-bearing source (depths > 35-40 km). We propose that the transition from low Sr/Y to high Sr/Y magmatism resulted from orogenic thickening of island arc crust in the Dixie Butte area during Late Jurassic arc-arc collision between the Olds Ferry and Wallowa island arcs at 159-154 Ma. This fundamental change in crustal

  13. Calc-Alkaline magmatism associated with lithospheric extension in the Eocene and Miocene of the Pacific Northwest, U. S. A

    SciTech Connect

    Hooper, P.R.; Bailey, D.G.; Holder, G.A.M.; Urbanzcyk, K.M. . Dept. of Geology)

    1993-04-01

    A basic tenet of igneous petrology is that calc-alkaline suites are created in the subduction process and that extension is associated with alkalic and bimodal suites. Tectonic models of older terranes often use calc-alkaline suites as sure evidence of subduction. Eocene magmatism in the Pacific Northwest and Miocene volcanism associated with the northern limits of the Basin and Range province appear to contradict these tenets and so to raise reservations concerning their use in developing tectonic models. In northeast Washington State, extension in the Eocene is evidenced by gneissic core complexes and grabens. Recent precise dating of structures and magmatism (plutons, dikes and lavas) leaves no doubt that magmatism and extension are products of the same process. South of the Columbia Plateau, in the Miocene, the Powder River volcanic field consists of basalts, andesites, dacites and rhyolites erupted within the La Grande and Baker grabens; the magmatism clearly coincidental with graben development at ca. 14 Ma. Both basalts and more silicic flows have the typical subduction-related trace element signature. In neither province is progression from calc-alkaline to bimodal volcanism apparent. Both the Eocene and Miocene suites are associated with alkalic rocks. The authors suggest that in areas such as the western Cordillera extension causes the partial melting of sources which already carry the subduction-related signature. This could be crust (intermediate to more silicic magmas) or a depleted subcontinental mantle enriched during an earlier subduction event (basalts); that is, that while calc-alkaline rocks are associated with subduction, they may not require contemporaneous subduction, as is usually assumed.

  14. Kolaviron, a biflavonoid complex of Garcinia kola seeds modulates apoptosis by suppressing oxidative stress and inflammation in diabetes-induced nephrotoxic rats.

    PubMed

    Ayepola, Omolola R; Cerf, Marlon E; Brooks, Nicole L; Oguntibeju, Oluwafemi O

    2014-12-15

    Diabetic nephropathy is a complex disease that involves increased production of free radicals which is a strong stimulus for the release of pro-inflammatory factors. We evaluated the renal protective effect of kolaviron (KV) - a Garcinia kola seed extract containing a mixture of 5 flavonoids, in diabetes-induced nephrotoxic rats. Male Wistar rats were divided into 4 groups: untreated controls (C); normal rats treated with kolaviron (C+KV); untreated diabetic rats (D); kolaviron treated diabetic rats (D+KV). A single intraperitoneal injection of streptozotocin (STZ, 50mg/kg) was used for the induction of diabetes. Renal function parameters were estimated in a clinical chemistry analyzer. Markers of oxidative stress in the kidney homogenate were analyzed in a Multiskan Spectrum plate reader and Bio-plex Promagnetic bead-based assays was used for the analysis of inflammatory markers. The effect of kolaviron on diabetes-induced apoptosis was assessed by TUNEL assay. In the diabetic rats, alterations in antioxidant defenses such as an increase in lipid peroxidation, glutathione peroxidase (GPX) activity and a decrease in catalase (CAT) activity, glutathione (GSH) levels and oxygen radical absorbance capacity (ORAC) were observed. There was no difference in superoxide dismutase (SOD) activity. Diabetes induction increased apoptotic cell death and the levels of interleukin (IL)-1β and tumor necrosis factor (TNF)-α with no effect on IL-10. Kolaviron treatment of diabetic rats restored the activities of antioxidant enzymes, reduced lipid peroxidation and increased ORAC and GSH concentration in renal tissues. Kolaviron treatment of diabetic rats also suppressed renal IL-1β. The beneficial effects of kolaviron on diabetes-induced kidney injury may be due to its inhibitory action on oxidative stress, IL-1β production and apoptosis.

  15. Geological structure and ore mineralization of the South Sopchinsky and Gabbro-10 massifs and the Moroshkovoe Lake target, Monchegorsk area, Kola Peninsula, Russia

    NASA Astrophysics Data System (ADS)

    Pripachkin, Pavel V.; Rundkvist, Tatyana V.; Miroshnikova, Yana A.; Chernyavsky, Alexey V.; Borisenko, Elena S.

    2016-12-01

    The South Sopchinsky massif (SSM), Gabbro-10 (G-10) massif, and Moroshkovoe Lake (ML) target Monchegorsk area, Kola Peninsula, are located at the junction of the Monchepluton and Monchetundra layered intrusions. The intrusions were studied in detail as they are targets for platinum-group element (PGE) mineralization. The rocks in these targets comprise medium- to coarse-grained mesocratic to leucocratic gabbronorites, medium-grained mesocratic to melanocratic norites and pyroxenites, and various veins mainly comprising norite, plagioclase-amphibole-magnetite rocks, and quartz-magnetite rocks. The veins contain Ni-Cu-PGE mineralization associated with magnetite and chromite. In all targets, the contacts between gabbronorite and norite-pyroxenite are undulating, and the presence of magmatic (intrusive) breccias suggests that these rocks formed through mingling of two distinct magmatic pulses. In places, the gabbronorites clearly crosscut the modal layering of the norites and pyroxenites. Trace element data indicate that the gabbronorites have similar compositions to rocks of the upper part of the Monchetundra intrusion, whereas the norites and pyroxenites resemble rocks from the lower to intermediate stratigraphic levels of the Monchepluton, such as in the Nude-Poaz and Sopcha massifs. Sulfide mineralization in the studied targets principally consists of secondary bornite, millerite, and chalcopyrite. In contrast, the primary sulfide assemblage within the layered sequence of the adjacent Monchepluton is characterized by pentlandite, chalcopyrite, and pyrrhotite. Therefore, the mineralization in the studied targets is interpreted to be of a contact style. We argue that the studied area represents the contact zone between gabbronorites of the Monchetundra intrusion and norites and pyroxenites of the Monchepluton. In addition, the rocks were overprinted by postmagmatic veining and remobilization of contact style sulfide and PGE mineralization.

  16. Composition of coarse-grained magnetite from pegmatite dikes related to plutons of quartz monzonite in the Jabal Lababa area, Kingdom of Saudi Arabia

    USGS Publications Warehouse

    Overstreet, William C.; Mousa, Hassan; Matzko, John J.

    1985-01-01

    Crystals of magnetite as large as 30 mm long and 7 mm thick are locally present in quartz-rich zones of interior and exterior pegmatite dikes related to plutons of quartz monzonite in the Jabal Lababa area. Niobium, tin, and yttrium are strongly enriched in six specimens of magnetite from interior pegmatite dikes in a small pluton where these elements form geochemical anomalies in nonmagnetic heavy-mineral concentrates from wadi sediment. Less abundant anomalous elements in the magnetite are molybdenum, lead, and zirconium, which also tend to be present in anomalous amounts in the nonmagnetic concentrates from the niobium-bearing pluton. The most anomalous trace element in the magnetite is zinc, which is at least 10 times as abundant as it is in the quartz monzonite plutons or in the nonmagnetic concentrates. The capacity of magnetite to scavenge molybdenum, zinc, niobium, lead, tin, yttrium, and zirconium suggests the possible utility of magnetite as a geochemical sample medium.

  17. Process for extracting technetium from alkaline solutions

    DOEpatents

    Moyer, Bruce A.; Sachleben, Richard A.; Bonnesen, Peter V.

    1995-01-01

    A process for extracting technetium values from an aqueous alkaline solution containing at least one alkali metal hydroxide and at least one alkali metal nitrate, the at least one alkali metal nitrate having a concentration of from about 0.1 to 6 molar. The solution is contacted with a solvent consisting of a crown ether in a diluent for a period of time sufficient to selectively extract the technetium values from the aqueous alkaline solution. The solvent containing the technetium values is separated from the aqueous alkaline solution and the technetium values are stripped from the solvent.

  18. Alkaline sorbent injection for mercury control

    DOEpatents

    Madden, Deborah A.; Holmes, Michael J.

    2002-01-01

    A mercury removal system for removing mercury from combustion flue gases is provided in which alkaline sorbents at generally extremely low stoichiometric molar ratios of alkaline earth or an alkali metal to sulfur of less than 1.0 are injected into a power plant system at one or more locations to remove at least between about 40% and 60% of the mercury content from combustion flue gases. Small amounts of alkaline sorbents are injected into the flue gas stream at a relatively low rate. A particulate filter is used to remove mercury-containing particles downstream of each injection point used in the power plant system.

  19. Alkaline sorbent injection for mercury control

    DOEpatents

    Madden, Deborah A.; Holmes, Michael J.

    2003-01-01

    A mercury removal system for removing mercury from combustion flue gases is provided in which alkaline sorbents at generally extremely low stoichiometric molar ratios of alkaline earth or an alkali metal to sulfur of less than 1.0 are injected into a power plant system at one or more locations to remove at least between about 40% and 60% of the mercury content from combustion flue gases. Small amounts of alkaline sorbents are injected into the flue gas stream at a relatively low rate. A particulate filter is used to remove mercury-containing particles downstream of each injection point used in the power plant system.

  20. Temporal Evolution of Volcanic and Plutonic Magmas Related to Porphyry Copper Ores Based on Zircon Geochemistry

    NASA Astrophysics Data System (ADS)

    Dilles, J. H.; Lee, R. G.; Wooden, J. L.; Koleszar, A. M.

    2015-12-01

    Porphyry Cu (Mo-Au) and epithermal Au-Ag ores are globally associated with shallow hydrous, strongly oxidized, and sulfur-rich arc intrusions. In many localities, long-lived magmatism includes evolution from early andesitic volcanic (v) and plutonic (p) rocks to later dacitic or rhyolitic compositions dominated by plutons. We compare zircon compositions from three igneous suites with different time spans: Yerington, USA (1 m.y., p>v), El Salvador, Chile (4 m.y., p>v), and Yanacocha, Peru (6 m.y., v>p). At Yerington granite dikes and ores formed in one event, at ES in 2 to 3 events spanning 3 m.y., and at Yanacocha in 6 events spanning 5 m.y. At both ES and Yanacocha, high-Al amphiboles likely crystallized at high temperature in the mid-crust and attest to deep magmas that periodically recharged the shallow chambers. At Yanacocha, these amphiboles contain anhydrite inclusions that require magmas were sulfur-rich and strongly oxidized (~NNO+2). The Ti-in-zircon geothermometer provides estimates of 920º to 620º C for zircon crystallization, and records both core to rim cooling and locally high temperature rim overgrowths. Ore-related silicic porphyries yield near-solidus crystallization temperatures of 750-650°C consistent with low zircon saturation temperatures. The latter zircons have large positive Ce/Ce* and small negative Eu/Eu*≥0.4 anomalies attesting to strongly oxidized conditions (Ballard et al., 2001), which we propose result from crystallization and SO2 loss to the magmatic-hydrothermal ore fluid (Dilles et al., 2015). The Hf, REE, Y, U, and Th contents of zircons are diverse in the magma suites, and Th/U vs Yb/Gd plots suggest a dominant role of crystal fractionation with lesser roles for both crustal contamination and mixing with high temperature deep-sourced mafic magma. Ce/Sm vs Yb/Gd plots suggest that magma REE contents at <900°C are dominated by early crystallization of hornblende and apatite, and late crystallization (~<780°C) of titanite

  1. Rock-magnetic properties of single zircon crystals sampled from the Tanzawa tonalitic pluton, central Japan

    NASA Astrophysics Data System (ADS)

    Sato, M.; Yamamoto, S.; Yamamoto, Y.; Ohno, M.; Tsunakawa, H.; Maruyama, S.

    2015-12-01

    This paper reports on the rock-magnetic properties of single zircon crystals, which are essential for future work establishing the paleointensity method using single zircon crystals. Zircon crystals used in this study were sampled from the Nakagawa River, which crosses the Tanzawa tonalitic pluton in central Japan. Rock-magnetic measurements were conducted on 1037 grains of zircons, but many of these measurements are below the limits of the sensitivity of the magnetometers employed. Isothermal remanent magnetizations (IRMs) of 876 zircon crystal are below the practical resolution of this study; we infer that these crystal contain no or only minute quantities of ferromagnetic minerals. The other zircon crystals contain enough magnetic minerals to be measured in the DC SQUID magnetometer. For 81 zircon crystals, IRM intensity (MIRM) are larger than 4 × 10-12 Am2, while natural remanent magnetization (NRM) intensity (MNRM) are below 4 × 10-12 Am2, indicating that these crystals are inappropriate for the paleomagnetic study. For the samples that had values of MNRM ≥ 4 × 10-12 Am2 and MIRM ≥ 4 × 10-12 Am2, combining the rock-magnetic parameter, we proposed the sample selection criteria for future study of paleointensity experiments using single zircon crystals. In the case that the samples had high Bc values (>10 mT) or high MNRM/MIRM values (>~0.1), main remanence carriers are probably pyrrhotite and these samples are inappropriate for the paleointensity study. In the case that the samples had low Bc values (<10 mT) and low MNRM/MIRM values (<~0.1), main remanence carrier seem to be nearly pure magnetite with PSD grain sizes and these samples are expected to appropriate for the paleointensity study. Total thermoremanent magnetization (TRM) acquisition experiments were also carried out for 12 samples of the zircon crystals satisfying the above criteria. The TRM intensity was comparable with that of NRM, and a rough estimation of the paleointensity using NRM

  2. Rock-magnetic properties of single zircon crystals sampled from the Tanzawa tonalitic pluton, central Japan

    NASA Astrophysics Data System (ADS)

    Sato, Masahiko; Yamamoto, Shinji; Yamamoto, Yuhji; Okada, Yoshihiro; Ohno, Masao; Tsunakawa, Hideo; Maruyama, Shigenori

    2015-09-01

    This paper reports on the rock-magnetic properties of single zircon crystals, which are essential for future work establishing the reliable paleointensity method using single zircon crystals. Zircon crystals used in this study were sampled from the Nakagawa River, which crosses the Tanzawa tonalitic pluton in central Japan. Rock-magnetic measurements were conducted on 1037 grains of zircons, but many of these measurements are below the limits of the sensitivity of the magnetometers employed. Isothermal remanent magnetizations (IRMs) of 876 zircon crystal are below the practical resolution of this study; we infer that these crystals contain no or only minute quantities of ferromagnetic minerals. The other zircon crystals contain enough magnetic minerals to be measured in the DC SQUID magnetometer. For 81 zircon crystals, IRM intensities ( M IRM) are larger than 4 × 10-12 Am2, while natural remanent magnetization (NRM) intensities ( M NRM) are below 4 × 10-12 Am2, indicating that these crystals are inappropriate for the paleomagnetic study. For the samples that had values of M NRM ≥ 4 × 10-12 Am2 and M IRM ≥ 4 × 10-12 Am2 (80 zircons), combining the rock-magnetic parameter, we proposed the sample-selection criteria for future study of paleointensity experiments using single zircon crystals. In the case that the samples had high coercivity ( B c) values (>10 mT) or high M NRM/ M IRM values (>~0.1), main remanence carriers are probably pyrrhotite and these samples are inappropriate for the paleointensity study. In the case that the samples had low B c values (<10 mT) and low M NRM/ M IRM values (<~0.1), main remanence carriers seem to be nearly pure magnetite with pseudo-single-domain grain sizes, and these samples are expected to appropriate for the paleointensity study. Total thermoremanent magnetization (TRM) acquisition experiments were also carried out for 12 samples satisfying the above criteria. The TRM intensity was comparable with that of NRM, and a

  3. Evolution of Mutnovsky Volcano, Kamchatka with Implications for Arc Pluton Growth

    NASA Astrophysics Data System (ADS)

    Simon, A.; Robertson, K.; Smith, E. I.; Kiryukhin, A. V.; Selyangin, O.; Mulcahy, S. R.; Walker, J. D.

    2011-12-01

    are consistent with the downward building of the sub-volcanic pre-eruptive magma plumbing system at Mutnovsky and have implications for the emplacement and iterative assembly of sub-volcanic plutons in arc environments. The model pressures yield calculated pre-eruptive magma storage depths that deepen from 13 km for Mutnovsky I and II, to 16 km for Mutnovsky III, to 30 km Mutnovsky IV. These data imply the potential for amalgamation of the residual magma chambers into a large pluton provided that the erupted volume of material from Mutnovsky I, II, III and IV represents a small fraction of the total pre-eruptive magma volume beneath each volcanic center.

  4. Review of ''Draft - Area Recommendation Report for the Crystalline Repository Project'', January 1986. [Rolesville pluton and Elk River complex

    SciTech Connect

    Butler, J.R.

    1986-03-13

    The Draft-Area Recommendation Report identifies portions of crystalline rock bodies as proposed potentially acceptable sites for consideration as repositories of high-level radioactive waste. The review is in three parts. Part I is a general summary of the main comments, written in semi-technical language and without detailed documentation or references. It includes summaries of comments on the two preliminary candidate areas for a nuclear-waste repository in North Carolina (Rolesville pluton and Elk River complex) and on the rest of the report. The following two parts are written in the technical language of a geological report and include both documentation and references for each of the points discussed: Part II - Rolesville pluton, Site SE-4; Part III - Elk River complex, Site SE-5.

  5. The distribution, geochronology and geochemistry of early Paleozoic granitoid plutons in the North Altun orogenic belt, NW China: Implications for the petrogenesis and tectonic evolution

    NASA Astrophysics Data System (ADS)

    Meng, Ling-Tong; Chen, Bai-Lin; Zhao, Ni-Na; Wu, Yu; Zhang, Wen-Gao; He, Jiang-Tao; Wang, Bin; Han, Mei-Mei

    2017-01-01

    Abundant early Paleozoic granitoid plutons are widely distributed in the North Altun orogenic belt. These rocks provide clues to the tectonic evolution of the North Altun orogenic belt and adjacent areas. In this paper, we report an integrated study of petrological features, U-Pb zircon dating, in situ zircon Hf isotope and whole-rock geochemical compositions for the Abei, 4337 Highland and Kaladawan Plutons from north to south in the North Altun orogenic belt. The dating yielded magma crystallization ages of 514 Ma for the Abei Pluton, 494 Ma for the 4337 Highland Pluton and 480-460 Ma for the Kaladawan Pluton, suggesting that they are all products of oceanic slab subduction because of the age constraint. The Abei monzogranites derived from the recycle of Paleoproterozoic continental crust under low-pressure and high-temperature conditions are products of subduction initiation. The 4337 Highland granodiorites have some adakitic geochemical signatures and are sourced from partial melting of thickened mafic lower continental crust. The Kaladawan quartz diorites are produced by partial melting of mantle wedge according to the positive εHf(t) values, and the Kaladawan monzogranite-syenogranite are derived from partial melting of Neoproterozoic continental crust mixing the juvenile underplated mafic material from the depleted mantle. These results, together with existing data, provide significant information about the evolution history of oceanic crust subduction during the 520-460 Ma. The initiation of subduction occurred during 520-500 Ma with formation of Abei Pluton; subsequent transition from steep-angle to flat-slab subduction at ca.500 Ma due to the arrival of buoyant oceanic plateaus, which induces the formation of 4337 Highland Pluton. With ongoing subduction, the steep-angle subduction system is reestablished to cause the formation of 480-460 Ma Kaladawan Pluton. Meanwhile, it is this model that account for the temporal-spatial distribution of these early

  6. A paleomagnetic and stable isotope study of the pluton at Rio Hondo near Questa, New Mexico: implications for CRM related to hydrothermal alteration

    USGS Publications Warehouse

    Hagstrum, J.T.; Johnson, C.M.

    1986-01-01

    Paleomagnetic and rock magnetic data combined with stable isotope data from the middle Tertiary pluton along the Rio Hondo in northern New Mexico suggest that its magnetic remanence has both thermal (TRM) and high-temperature chemical (CRM) components. Oxygen isotope temperatures indicate that magnetite associated with the more rapidly cooled higher levels of the pluton, and with mafic inclusions and cogenetic rhyolitic dikes sampled at lower levels of exposure, ceased subsolidus recrystallization and isotopic exchange above its Curie temperature (580??C) in the presence of a magmatic fluid. Continued cooling imparted a TRM to these portions of the pluton. The more slowly cooled granodiorite at lower levels has quartz-magnetite isotopic temperatures that are below the Curie temperature of magnetite implying that its magnetization is high-temperature CRM. Sub-Curie isotopic temperatures for other granitic plutons in the western U.S.A. suggest that CRM may be commonly derived from subsolidus interactions between magnetite and magmatic fluids in plutonic rocks. A meteoric-hydrothermal system generated by the cooling Rio Hondo pluton, and not by younger adjacent intrusions, resulted in limited alteration along zones of high permeability near the southern margin of the Rio Hondo pluton, and in more prevasive alteration of the pluton to the north. The meteoric-hydrothermal alteration occurred at relatively high temperatures (> 350??C) and, with the exception of local chloritization, caused little visible alteration of the rocks. The isotopic ratios indicate that little of the magnetite could have grown from or exchanged with a meteoric-hydrothermal fluid. ?? 1986.

  7. Forceful emplacement of the Eureka Valley-Joshua Flat-Beer Creek composite pluton into a structural basin in eastern California; internal structure and wall rock deformation

    NASA Astrophysics Data System (ADS)

    Morgan, Sven; Law, Richard; de Saint Blanquat, Michel

    2013-11-01

    Anisotropy of Magnetic Susceptibility parameters have been analyzed at 311 locations in the Eureka Valley-Joshua Flat-Beer Creek (EJB) pluton of eastern California. The large amount of data has allowed for the AMS parameters to be contoured using techniques that both reveal map-scale trends and emphasize small-scale differences. The contour maps suggest that magnetic susceptibility is dominantly controlled by composition of the magma but may also be affected by emplacement-related strain as the magma chamber inflated and forced the wall rocks outward. Pluton construction involved two major pulses of different composition magmas that were emplaced sequentially but with overlapping periods of crystallization. The magmas initially intruded as sill-like bodies into a structural basin. The magnetic foliation of the pluton cuts across internal magmatic contacts on the map scale and is parallel to local contacts between the pluton and surrounding metasedimentary wall rocks. The magnetic fabric is similar in orientation and symmetry to intense flattening strains recorded in the aureole rocks. The metasedimentary wall rocks have been shortened between 60 and 70% and this strain magnitude is approximately equal on the west, south, and east margins of the pluton. Strain in the wall rocks is dominantly flattening and concentrated into a narrow (1 km wide) inner aureole. Mapping of bedding/cleavage intersection lineations south of the pluton indicates that the magma made room for itself by translating the wall rocks outward and rotating the already inward dipping wall rocks of the structural basin to sub-vertical. Stretching of the inner aureole around an expanding magma chamber was responsible for the intense shortening. Limited data on the Marble Canyon pluton to the south of the EJB pluton indicates a very similar emplacement process.

  8. Formation of rhyolite at the Okataina Volcanic Complex, New Zealand: New insights from analysis of quartz clusters in plutonic lithics

    NASA Astrophysics Data System (ADS)

    Graeter, K.; Beane, R. J.; Deering, C. D.; Gravley, D. M.; Bachmann, O.

    2014-12-01

    Granitoid lithic clasts from the 0.7 ka Kaharoa eruption at the Tarawera volcano (Okataina Volcanic Complex, Taupo Volcanic Zone, New Zealand) - the world's most productive region where rhyolite volcanism is currently active - give insight into the processes of rhyolite formation. The plutonic lithic clasts of the Kaharoa eruption consist of (1) quartz phenocrysts, which are often grouped into clusters of two to eight quartz grains, (2) plagioclase phenocrysts with anorthitic cores and albitic rims, and (3) interstitial potassium feldspar. Quartz orientations obtained through electron backscatter diffraction (EBSD) methods show that 78% of the 82 analyzed clusters have at least one pair of quartz grains with matched dipyramidal faces that are in either parallel or Esterel twin orientation. Variations in cathodoluminescence (CL) zoning patterns of the quartz suggest that quartz clusters in the plutonic lithics formed after initial crystal growth and that many quartz crystals were subject to one or more resorption events. Thus, individual quartz crystals with different magmatic histories came together into preferred orientations to form clusters; this process is indicative of oriented quartz synneusis and suggests a history of crystal accumulation. The quartz clusters are interpreted to have formed as part of a crystal cumulate mush within a shallow magma chamber where quartz crystals rotated into contact along their dipyramidal faces during hindered settling and/or compaction. Therefore, the preservation of oriented quartz clusters from the Kaharoa plutonic lithics provides direct evidence for synchronous, shallow pluton formation from a cumulate mush during active volcanism. This result is consistent with a model whereby melt-rich, high-silica rhyolite formation occurs via interstitial melt extraction from a low-silica rhyolite mush in the shallow crust.

  9. Regional geochemical study of the felsic plutonic rocks in the Nuqrah Quadrangle, sheet 25E, Kingdom of Saudi Arabia

    USGS Publications Warehouse

    Hall, W.E.; Dellinger, David; Selner, G.I.

    1985-01-01

    Pan-concentration samples collected from wadis draining the north end of Jabal Safad contain anomalous Sn, Mo, Pb, and La. Four samples contain 250 to 1,000 ppm of tin. The tin anomaly is associated with a small aplitic pluton intrusive into the Jabal Safad alkalic granite complex. A brief reconnaissance of the area did not reveal any greisen or cassiterite mineralization. However, further exploration work in the area is recommended.

  10. High temperature fracturing and ductile deformation during cooling of a pluton: The Lake Edison granodiorite (Sierra Nevada batholith, California)

    NASA Astrophysics Data System (ADS)

    Pennacchioni, Giorgio; Zucchi, Eleonora

    2013-05-01

    In the Bear Creek area of the Sierra Nevada batholith, California, the high temperature postmagmatic deformation structures of the Lake Edison granodiorite include steeply-dipping orthogneiss foliations, joints, and ductile shear zones that nucleated on joints and leucocratic dykes. Exploitation of segmented joints resulted in sharply bounded, thin shear zones and in large slip gradients near the shear zone tips causing the deformation of the host rock at contractional domains. The orthogneiss foliation intensifies towards the contact with the younger Mono Creek granite and locally defines the dextral Rosy Finch Shear Zone (RFSZ), a major kilometre-wide zone crosscutting the pluton contacts. Joints predominantly strike at N70-90°E over most of the Lake Edison pluton and are exploited as sinistral shear zones, both within and outside the RFSZ. In a narrow (˜250 m thick) zone at the contact with the younger Mono Creek granite, within the RFSZ, the Lake Edison granodiorite includes different sets of dextral and sinistral shear zones/joints (the latter corresponding to the set that dominates over the rest of the Lake Edison pluton). These shear zones/joints potentially fit with a composite Y-R-R' shear fracture pattern associated with the RFSZ, or with a pattern consisting of Y-R-shear fractures and rotated T' mode I extensional fractures. The mineral assemblage of shear zones, and the microstructure and texture of quartz mylonites indicate that ductile deformation occurred above 500 °C. Joints and ductile shearing alternated and developed coevally. The existing kinematic models do not fully capture the structural complexity of the area or the spatial distribution of the deformation and magmatic structures. Future models should account more completely for the character of ductile and brittle deformation as these plutons were emplaced and cooled.

  11. Ion-adsorption REEs in regolith of the Liberty Hill pluton, South Carolina, USA: An effect of hydrothermal alteration

    USGS Publications Warehouse

    Bern, Carleton R.; Yesavage, Tiffany; Foley, Nora K.

    2017-01-01

    Ion-adsorbed rare earth element (REE) deposits supply the majority of world heavy REE production and substantial light REE production, but relatively little is known of their occurrence outside Southeast Asia. We examined the distribution and forms of REEs on a North American pluton located in the highly weathered and slowly eroding South Carolina Piedmont. The Hercynian Liberty Hill pluton experiences a modern climate that includes ~ 1500 mm annual rainfall and a mean annual temperature of 17 °C. The pluton is medium- to coarse-grained biotite-amphibole granite with minor biotite granite facies. REE-bearing phases are diverse and include monazite, zircon, titanite, allanite, apatite and bastnäsite. Weathered profiles were sampled up to 7 m-deep across the ~ 400 km2 pluton. In one profile, ion-adsorbed REEs plus yttrium (REE + Y) ranged up to 581 mg/kg and accounted for up to 77% of total REE + Y in saprolite. In other profiles, ion-adsorbed REE + Y ranged 12–194 mg/kg and only accounted for 3–37% of totals. The profile most enriched in ion-adsorbed REEs was located along the mapped boundary of two granite facies and contained trioctahedral smectite in the saprolite, evidence suggestive of hydrothermal alteration of biotite at that location. Post-emplacement deuteric alteration can generate easily weathered REE phases, particularly fluorocarbonates. In the case of Liberty Hill, hydrothermal alteration may have converted less soluble to more soluble REE minerals. Additionally, regolith P content was inversely correlated with the fraction ion-adsorbed REEs, and weathering related secondary REE-phosphates were found in some regolith profiles. Both patterns illustrate how low P content aids in the accumulation of ion-adsorbed REEs. The localized occurrence at Liberty Hill sheds light on conditions and processes that generate ion-adsorbed REEs.

  12. Jim River and Hodzana plutons, Alaska: the role of assimilation in the petrogenesis of syenite and granite

    SciTech Connect

    Blum, J.D.; Blum, A.E.; Dillon, J.T.

    1985-01-01

    Early Cretaceous plutonic rocks in central Alaska intrude both Devonian to Jurassic oceanic rocks of the Angayuchum terrane (AT) and early Paleozoic to Precambrian continental metasediments of the Ruby terrane (RT). Most plutons intrude only the RT and are biotite and two-mice granite. The Hodzana pluton intrudes both fault-bounded terranes, constraining movement between them to the emplacement age of about 110 million years, and is mainly biotite-amphibole granite with some monzodiorite. Modal and chemical data from the Jim River and Hodzana plutons define two distinct compositional trends. One trend is monzonitic to syenitic while the other is mostly granitic. The two suites are the same age, yet cannot be related by simple differentiation due to a pronounced chemical discontinuity. Rb-Sr whole-rock isochrons yield an age of 112 million years and (87Sr/86Sr)o of .7078 for the syenitic suite, and an age of 108 million years and (87Sr/86Sr)o of .7079 for the granitic suite. The authors suggest that the monzonite represents a primary magma that formed in the lower crust or mantle and initiated upper crustal melting as it intruded the AT and RT. Assimilation of continental crust could have allowed the portion of the magma that intruded the RT to evolve from a monzonite to a granite. Fractionation of these two parent magmas may have resulted in the contemporaneous syenitic and granitic suites. The two suites may reflect the contrasting composition of assimilated wallrock across the AT-RT boundary. Isotopic studies of the wallrocks are in progress and may help to constrain the amount and composition of crust that was assimilated where the magma intruded the AT versus the RT.

  13. The Ajo Mining District, Pima County, Arizona--Evidence for Middle Cenozoic Detachment Faulting, Plutonism, Volcanism, and Hydrothermal Alteration

    USGS Publications Warehouse

    Cox, Dennis P.; Force, Eric R.; Wilkinson, William H.; More, Syver W.; Rivera, John S.; Wooden, Joseph L.

    2006-01-01

    Introduction: The Ajo porphyry copper deposit and surrounding Upper Cretaceous rocks have been separated from their plutonic source and rotated by detachment faulting. Overlying middle Cenozoic sedimentary and volcanic rocks have been tilted and show evidence for two periods of rotation. Following these rotations, a granitic stock (23.7?0.2 Ma) intruded basement rocks west of the Ajo deposit. This stock was uplifted 2.5 km to expose deep-seated Na-Ca alteration.

  14. Mineralogy and geochemistry of the Late Neoproterozoic rare metal granitoids of Gabal El-Ineigi pluton, Northern Arabian-Nubian Shield, Egypt

    NASA Astrophysics Data System (ADS)

    Sami, Mabrouk; Ntaflos, Theodoros; Mohamed, Haroun A.; Farahat, Esam S.; Ahmed, Awaad F.

    2016-04-01

    Gabal El-Ineigi granitoid pluton is situated in the Central Eastern Desert of Egypt and is considered as one of the good examples of the fluorite bearing rare metal granites in the Arabian Nubian Shield (ANS). It constitutes a multiphase pluton consists of porphyritic syenogranites (SG) and coarse to medium grained highly evolved alkali-feldspar granites (AFG) intruded into the older granodiorites and metagabbro-diorite rocks. Petrographic features indicate that quartz, K-feldspar (perthite, Or97-99), plagioclase (albite, An0-6) and biotite are the major mineral phases of both granitic types with subordinate muscovite that is observed only in the AFG. Columbite, rutile, fluorite, zircon and thorite are the significant accessory minerals in the AFG while, allanite is exclusively encountered in the SG. Mineral chemistry study reveals that Nb-Ta-Ti-bearing oxides [columbite-group minerals (CGM)] and Nb-bearing oxides (ilmenorutile) represent the most common Nb-Ta host in the AFG. The CGM are represented mostly by complex zoned columbite-(Fe) and rarely by yttrocolumbite-(Y), with Mn/(Mn+Fe) ratios ranging from 0.17 to 0.31. Xenomorphic fluorite (F=46-51 wt%) is commonly filling the spaces between the major mineral phases and sometimes host rare metal minerals, e.g. columbite and thorite. Euhedral zoned allanite (Ce-Nd) is the common REE bearing mineral encountered in the SG. Geochemically, Gabal El-Ineigi granitoids are metaluminous (A/CNK= 0.95-0.99) related to post-collosional A2-type granites. The late phase AFG have distinctive geochemical features typical of rare-metal granites. They are highly fractionated calc-alkaline granitoids characterized by high Rb, Nb, Y, U and many HFSE contents, and extremely low Sr and Ba contents (4-35 and 13-18 ppm, respectively). Moreover, their REE patterns show pronounced negative Eu anomalies (Eu/Eu*=0.03 - 0.05) and tetrad effect (TE1,3=1.16 and 1.42), implying extensive fractionation via fluid-rock interaction that

  15. Is the southeast Coast Plutonic Complex the consequence of accretion of the insular superterrane Evidence from U-Pb zircon geochronometry in the northern Washington Cascades

    SciTech Connect

    Walker, N.W. ); Brown, E.H. )

    1991-07-01

    Zircon U-Pb geochronometry of orthogneisses and plutons in the southwestern crystalline core of the North Cascades, coupled with fabric and textural studies of the orthogneisses, plutons, and their metamorphic host rocks, indicates extensive synmetamorphic plutonism at 89-96 Ma. Metamorphic mineral assemblages define a culmination composed of an axial kyanite-sillimanite zone rimmed by lower grade zones. High-grade index minerals are typically syntectonic to posttectonic. Metamorphic fabrics are characterized by an orogen-parallel, northwest-striking, steep foliation that contains a subhorizontal stretching and mineral lineation interpreted to be the product of ductile strike-slip deformation. This fabric is crosscut by 96-92 Ma plutons yet is imprinted on 92-89 Ma orthogneisses, suggesting spatially diachronous fabric development during orogeny. Documentation of the spatial and temporal coincidence of magmatism with the peak of orogeny, together with the kinematic significance of the metamorphic fabric, precludes generation of the metamorphic fabric and plutons in response to thrust loading. The authors suggest that this part of the Coast Plutonic Complex evolved as a transpressional magmatic arc.

  16. Paleoproterozoic structural frame of the Yetti domain (Eglab shield, Algeria): Emplacement conditions of the Tinguicht late pluton from magnetic fabric study

    NASA Astrophysics Data System (ADS)

    Merabet, Nacer-eddine; Mahdjoub, Yamina; Henry, Bernard; Abtout, Abdeslam; Maouche, Said; Kahoui, Mohamed; Lamali, Atmane; Ayache, Mohamed

    2016-02-01

    The Tinguicht pluton is part of the ˜2.07 Ga post-collisional magmatic suites that intruded the Yetti Paleoproterozoic volcano-sedimentary series of the western part of the Eglab Shield (West African Craton). It represents one of the most recent units of these suites. This pluton, with a NW-SE elliptic shape, is unfoliated, and its deformational structures are practically restricted to fracturing and faulting. New structural, microstructural and aeromagnetic data are presented in order to analyze in particular the relationship between the Tinguicht pluton emplacement and the related NNW-SSE major mega-shear zone, separating the Yetti and Eglab domains. To constrain the context of the regional post-collisional evolution of the Eglab shield, a structural analysis was performed by mapping the magnetic structures (foliation and lineation) using AMS. The combination of the results of all the used approaches leads to a new and enriched image of this granitic pluton and of its tectonic emplacement context. The elliptic shape of the granitic body and the AMS strain pattern are consistent with the presence of a NNW-SSE major structure. NNW-SSE is also one of the major directions highlighted by the aeromagnetic data. This study thus evidences the role of the pre-existing major shear zones in controlling emplacement of post-collisional Paleoproterozoic plutons like Tinguicht, as shown for Drissa pluton in the Eglab domain earlier.

  17. Regional geochemical study of the felsic plutonic rocks in the Nuqrah quadrangle, sheet 25E, Kingdom of Saudi Arabia

    SciTech Connect

    Hall, W.E.; Dellinger, D.; Selner, G.I.

    1985-01-01

    A regional geochemical investigation of the felsic plutonic rocks of the Nuqrah quadrangle, sheet 25 E, Kingdom of Saudi Arabia, in which pan concentrates of 384 wadi samples, and 145 rock samples, were collected, defined two separate and distinct anomalous areas. One area contains Jabal Tuwalah and Jabal Awja, and the other is at the north end of Jabal Safad. Both pan concentrates and the rock samples in the Jabal Tuwalah and Jabal Awja areas contain high concentrations of Be, F, La, Mo, Nb, Pb, Th, U, Sn, Y, and Zr, and the plutons underlying those areas are characterized by high total-count radioactivity. These elements are sited in highly evolved alkalic granites and have not been concentrated into a potentially metalliferous deposit related to a hydrothermal ore system. They may be a potential metal source of the future. Pan-concentration samples collected from wadis draining the north end of Jabal Safad contain anomalous Sn, Mo, Pb, and La. Four samples contain 250 to 1000 ppM of tin. The tin anomaly is associated with a small aplitic pluton intrusive into the Jabal Safad alkalic granite complex. A brief reconnaissance of the area did not reveal any greisen or cassiterite mineralization. However, further exploration work in the area is recommended. 23 refs., 10 figs., 3 tabs.

  18. A tale of 10 plutons - Revisited: Age of granitic rocks in the White Mountains, California and Nevada

    USGS Publications Warehouse

    McKee, E.H.; Conrad, J.E.

    1996-01-01

    40Ar/39Ar incremental heating analysis and conventional K-Ar age determinations on plutonic rocks of the White Mountains define two stages of magmatic emplacement: Late Cretaceous, between ca. 90 Ma and 75 Ma, and Middle-Late Jurassic, between ca. 180 and 140 Ma. The Jurassic stage can be divided into two substages, 180-165 Ma and 150-140 Ma. Thermal effects of the younger plutons on the older granitoids partially to completely reset ages, making it difficult to determine the age of emplacement and cooling of several of the plutons even by 40Ar/39Ar incremental heating analyses. New data together with published ages and regional geochronological synthesis of the Sierra Nevada batholith indicate that regions within the batholith have coherent periods or episodes of magmatic activity. In the White Mountains and Sierra Nevada directly to the west there was little or no activity in Early Jurassic and Early Cretaceous time; magmatism took place during relatively short intervals of 15 m.y. or less in the Middle and Late Jurassic and Late Cretaceous periods. The new K-Ar and 40Ar/39Ar analyses of granitoids from the White Mountains help, but do not completely clarify the complex history of emplacement, cooling, and reheating of the batholith.

  19. Contrasting magmatic structures between small plutons and batholiths emplaced at shallow crustal level (Sierras de Córdoba, Argentina)

    NASA Astrophysics Data System (ADS)

    Pinotti, Lucio P.; D'Eramo, Fernando J.; Weinberg, Roberto F.; Demartis, Manuel; Tubía, José María; Coniglio, Jorge E.; Radice, Stefania; Maffini, M. Natalia; Aragón, Eugenio

    2016-11-01

    Processes like injection, magma flow and differentiation and influence of the regional strain field are here described and contrasted to shed light on their role in the formation of small plutons and large batholiths their magmatic structures. The final geometric and compositional arrangement of magma bodies are a complex record of their construction and internal flow history. Magma injection, flow and differentiation, as well as regional stresses, all control the internal nature of magma bodies. Large magma bodies emplaced at shallow crustal levels result from the intrusion of multiple magma batches that interact in a variety of ways, depending on internal and external dynamics, and where the early magmatic, growth-related structures are commonly overprinted by subsequent history. In contrast, small plutons emplaced in the brittle-ductile transition more likely preserve growth-related structures, having a relatively simple cooling history and limited internal magma flow. Outcrop-scale magmatic structures in both cases record a rich set of complementary information that can help elucidate their evolution. Large and small granitic bodies of the Sierra Pampeanas preserve excellent exposures of magmatic structures that formed as magmas stepped through different rheological states during pluton growth and solidification. These structures reveal not only the flow pattern inside magma chambers, but also the rheological evolution of magmas in response to temperature evolution.

  20. Carboniferous magmatism in the Evora Massif (southwest Portugal, Ossa-Morena Zone): from typical arc calc-alkaline to adakitic-like magmatism

    NASA Astrophysics Data System (ADS)

    Lima, Selma M.; Neiva, Ana M. R.; Ramos, Joao M. F.

    2014-05-01

    The Evora Massif is one of the subdivisions of western Ossa-Morena Zone. It is a dome-like structure mainly composed of Ediacaran, Cambrian and Ordovician country rocks, affected by medium- and high-grade metamorphism coeval with the emplacement of several mafic to felsic intrusive bodies. The last magmatic event recorded in this area (Carboniferous) consists of calc-alkaline volcanism and voluminous plutonism (mainly composed by tonalites, gabbros, diorites and late-orogenic granodiorites and granites) [1]. Detailed chemical and isotopic studies from Evora Massif plutons were performed in the last few years. Whole-rock chemical and isotopic data suggest that the Hospitais tonalite (HT), Alto de Sao Bento area (ASB) and Reguengos de Monsaraz pluton (RM) resulted from fractional crystallization of mantle-derived magmas followed by mixing with variable proportions of crustal melts [2-4]. U-Pb ID-TIMS data indicate an age of 337-335 for the RM [4]. The Pavia pluton is a multiphase granitic body constructed incrementally by the episodic emplacement of several batches of magma (at 328 Ma, ca. 324 Ma and 319-317 Ma) [5]. The main granitic phases range from tonalite to two-mica granite that contain rare surmicaceous and fine-grained enclaves, and granitic and amphibolitic xenoliths. On the other hand, they are cut by abundant rhyodacite porphyries, microgranites (s.l.) and pegmatite dikes, predominantly oriented NE-SW and NW-SE. Although each phase seems to represent a distinct batch of magma, whole-rock Sr-Nd isotopic data suggest a similar and fairly homogenous source for all the constituent phases. Initial 87Sr/86Sr varies between 0.70428 and 0.7058 and ɛ Ndt ranges from -3.4 to +0.4, pointing towards a mantle or juvenile crust origin. A higher variation is observed in whole-rock δ18O (5.6-9.6 o), consistent with assimilation of crust. The PP was interpreted as the result of assimilation-fractional crystallization of a basaltic magma. Substantial differences between

  1. Alkaline tolerant dextranase from streptomyces anulatus

    DOEpatents

    Decker, Stephen R.; Adney, William S.; Vinzant, Todd B.; Himmel, Michael E.

    2003-01-01

    A process for production of an alkaline tolerant dextranase enzyme comprises culturing a dextran-producing microorganism Streptomyces anulatus having accession no. ATCC PTA-3866 to produce an alkaline tolerant dextranase, Dex 1 wherein the protein in said enzyme is characterized by a MW of 63.3 kDa and Dex 2 wherein its protein is characterized by a MW of 81.8 kDa.

  2. Technetium recovery from high alkaline solution

    DOEpatents

    Nash, Charles A.

    2016-07-12

    Disclosed are methods for recovering technetium from a highly alkaline solution. The highly alkaline solution can be a liquid waste solution from a nuclear waste processing system. Methods can include combining the solution with a reductant capable of reducing technetium at the high pH of the solution and adding to or forming in the solution an adsorbent capable of adsorbing the precipitated technetium at the high pH of the solution.

  3. Toxicity of alkalinity to Hyalella azteca

    USGS Publications Warehouse

    Lasier, P.J.; Winger, P.V.; Reinert, R.E.

    1997-01-01

    Toxicity testing and chemical analyses of sediment pore water have been suggested for use in sediment quality assessments and sediment toxicity identification evaluations. However, caution should be exercised in interpreting pore-water chemistry and toxicity due to inherent chemical characteristics and confounding relationships. High concentrations of alkalinity, which are typical of sediment pore waters from many regions, have been shown to be toxic to test animals. A series of tests were conducted to assess the significance of elevated alkalinity concentrations to Hyalella azteca, an amphipod commonly used for sediment and pore-water toxicity testing. Toxicity tests with 14-d old and 7-d old animals were conducted in serial dilutions of sodium bicarbonate (NaHCO3) solutions producing alkalinities ranging between 250 to 2000 mg/L as CaCO3. A sodium chloride (NaCl) toxicity test was also conducted to verify that toxicity was due to bicarbonate and not sodium. Alkalinity was toxic at concentrations frequently encountered in sediment pore water. There was also a significant difference in the toxicity of alkalinity between 14-d old and 7-d old animals. The average 96-h LC50 for alkalinity was 1212 mg/L (as CaCO3) for 14-d old animals and 662 mg/L for the younger animals. Sodium was not toxic at levels present in the NaHCO3 toxicity tests. Alkalinity should be routinely measured in pore-water toxicity tests, and interpretation of toxicity should consider alkalinity concentration and test-organism tolerance.

  4. Young cumulate complex beneath Veniaminof caldera, Aleutian arc, dated by zircon in erupted plutonic blocks

    USGS Publications Warehouse

    Bacon, C.R.; Sison, T.W.; Mazdab, F.K.

    2007-01-01

    Mount Veniaminof volcano, Alaska Peninsula, provides an opportunity to relate Quaternary volcanic rocks to a coeval intrusive complex. Veniaminof erupted tholeiitic basalt through dacite in the past ???260 k.y. Gabbro, diorite, and miarolitic granodiorite blocks, ejected 3700 14C yr B.P. in the most recent caldera-forming eruption, are fragments of a shallow intrusive complex of cumulate mush and segregated vapor-saturated residual melts. Sensitive high-resolution ion microprobe (SHRIMP) analyses define 238U-230Th isochron ages of 17.6 ?? 2.7 ka, 5+11/-10 ka, and 10.2 ?? 4.0 ka (2??) for zircon in two granodiorites and a diorite, respectively. Sparse zircons from two gabbros give 238-230Th model ages of 36 ?? 8 ka and 26 ?? 7 ka. Zircons from granodiorite and diorite crystallized in the presence of late magmatic aqueous fluid. Although historic eruptions have been weakly explosive Strombolian fountaining and small lava effusions, the young ages of plutonic blocks, as well as late Holocene dacite pumice, are evidence that the intrusive complex remains active and that evolved magmas can segregate at shallow levels to fuel explosive eruptions. ?? 2007 The Geological Society of America.

  5. Geochemical Database for the Boulder Batholith and Its Satellitic Plutons, Southwest Montana

    USGS Publications Warehouse

    du Bray, Edward A.; Lund, Karen; Tilling, Robert I.; Denning, Paul D.; DeWitt, Ed

    2009-01-01

    Geochemical data presented in this report pertain to Cretaceous igneous intrusions of the Boulder batholith and its satellitic plutons in southwest Montana. The geographic area addressed in this compilation is approximately bounded by lats 45.6 deg and 46.7 deg N. and longs 112.75 deg and 111.5 deg W. These data were compiled in order to establish the geologic framework for world-class mineral deposits of the Butte district. Although these deposits and their host rocks have been the subject of many investigations, the petrologic characteristics of associated intrusive rocks have not been systematically compiled, synthesized, or interpreted. Abundant late Mesozoic intrusions in the study area are probably byproducts of subduction-related processes, including back-arc magmatism that prevailed along the west edge of the North American plate during this interval. The ultimate goal of this effort will be an evaluation of the time-space-compositional evolution of Mesozoic magmatism associated with the Boulder batholith and identification of genetic associations between magmatic and mineralizing processes in this region.

  6. Distribution of manganese between coexisting biotite and hornblende in plutonic rocks

    USGS Publications Warehouse

    Greenland, L.P.; Gottfried, D.; Tilling, R.I.

    1968-01-01

    The distribution of manganese between coexisting biotite and hornblende for 80 mineral pairs from igneous rocks of diverse provenance (including Southern California, Sierra Nevada, Boulder, and Boulder Creek batholiths and the Jemez Mountains volcanics) has been determined by neutron activation analysis. Data on the distribution ratio (Kd = Mnhornblende Mnbiotite) indicate that an equilibrium distribution of Mn is closely approached, though not completely attained, in most samples from plutonic environments. Comparison of Kd values of mineral pairs with bulk chemical composition of host rocks reveals no correlation. Because initial crystallization temperatures vary with rock composition, the lack of correlation of composition with Kd suggests that the equilibrium distribution of Mn between biotite and hornblende reflects exchange at subsolidus temperatures rather than initial crystallization temperatures. The highest Kd values are for volcanic rocks, in which rapid quenching prevents subsolidus redistribution of Mn. For sample pairs from the Southern California and Sierra Nevada batholiths there is a positive correlation of Kd with TiO2 content of biotite. Though the evidence is not compelling, Kd may also correlate with the rate of cooling and/or the presence or absence of sphene in the rock. ?? 1968.

  7. Metamorphism and plutonism in the Quetico Belt, Superior Province, N.W. Ontario

    NASA Technical Reports Server (NTRS)

    Percival, J. A.

    1986-01-01

    The Quetico Belt lies between the metavolcanic Wawa-Shebandowan and Wabigoon Belts. It consists of marginal metasedimentary rocks and central pelitic, gneissic and plutonic rocks. Metamorphism is Barrovian, at depths less than 10 km, and grade increases from margins to core of the belt: the outermost pelites are at chlorite-muscovite grade; inward a garnet-andalusite zone formed throughout the inner margin; and the central zone ranges form garnet-andalusite in the west and garnet-sillimanite-muscovite to garnet-sillimanite-cordierite and rare kyanite 6 to 150 km to the east. This increase is correlated with granitic intrusives. Migmatites in the core have intrusive leucosomes in the west and locally derived ones in the east. Isograd surfaces are steep where the belt is narrow and dip gently where it is wide. The Quetico Park intrusive complex of the central region of the Quetico Belt shows a zonation across it 20 to 50 km width from older, medium grained biotite composition to younger, coarse to pegmatitic granitic composition. Sediment of the Quetico basin had its source in the bordering metavolcanic belts and was deposited ca. 2.75 to 2.70 Ga ago. Boundaries of the belt dip inward, so it essentially is a graben of inter-arc or back-arc type.

  8. A petrologic comparison of Triassic plutonism in the San Gabriel and Mule Mountains, southern California

    SciTech Connect

    Barth, A.P. ); Tosdal, R.M.; Wooden, J.L. )

    1990-11-10

    Triassic magmatism in the southwest US Cordillera forms a semicontinuous magmatic arc extending from northwestern Nevada to southeastern California. Quartz monzodioritic and quartz monzonitic rocks and associated diorites and granites are widespread in southeastern California, and the authors suggest that these rocks represent exposure of a structurally deeper part of the Triassic arc, where it was emplaced into comparatively thick Proterozoic crust. Elemental and isotopic data suggest that Triassic quartz monzodiorites and quartz monzonites in the Mule and San Gabriel Mountains were derived from a relatively undepleted, nonradiogenic mafic lithospheric source, with virtually no upper crustal interaction. Very limited data for associated Triassic ( ) diorites indicate a wide range in composition and a surprisingly radiogenic isotopic signature. Younger Triassic( ) granites record a strong geochemical signature of interaction with continental crust, including inherited zircon and high initial Sr ratios but comparatively less radiogenic Pb isotopic compositions. The major and trace element geochemistry of Late Triassic plutonic rocks in southeastern California is similar in many respects to akalic components of the Triassic arc in the Mojave Desert. However, contemporaneous rocks farther north have a calc-alkalic signature, perhaps reflecting the variation in age and composition of lithosphere across which the Triassic arc was constructed.

  9. Phase equilibria of a fluorine-rich leucogranite from the St. Austell pluton, Cornwall

    SciTech Connect

    Weidner, J.R.; Martin, R.F.

    1987-06-01

    Highly evolved leucogranitic rocks in the St. Austell pluton, Cornwall, of Hercynian age, contain accessory muscovite, topaz and fluorite. The authors have studied the H/sub 2/O-saturated melting behavior of one representative sample. Its solidus and liquidus pass through the points 663 and 725/sup 0/C, respectively, at 1 kbar, 640 and 665/sup 0/C at 2 kbar, 610 and 717/sup 0/C at 4 kbar, and 608 and 700+/sup 0/C at 8 kbar. Plagioclase is on the liquidus at low pressure, and topaz is on the liquidus at 4 kbar. The fluorite is consumed in the formation of the first-formed liquid. Calcium can partition into an evolved granitic melt if complexed by fluorine. The fluorite appears to be largely primary in fresh fluorite granite at St. Austell, and not to reflect the albitization of oligoclase in the surrounding biotite granite. Such fluorine-rich leucogranites can be expected to be of subsolvus character.

  10. Alkaline Water and Longevity: A Murine Study

    PubMed Central

    Magro, Massimiliano; Corain, Livio; Ferro, Silvia; Baratella, Davide; Bonaiuto, Emanuela; Terzo, Milo; Corraducci, Vittorino; Salmaso, Luigi; Vianello, Fabio

    2016-01-01

    The biological effect of alkaline water consumption is object of controversy. The present paper presents a 3-year survival study on a population of 150 mice, and the data were analyzed with accelerated failure time (AFT) model. Starting from the second year of life, nonparametric survival plots suggest that mice watered with alkaline water showed a better survival than control mice. Interestingly, statistical analysis revealed that alkaline water provides higher longevity in terms of “deceleration aging factor” as it increases the survival functions when compared with control group; namely, animals belonging to the population treated with alkaline water resulted in a longer lifespan. Histological examination of mice kidneys, intestine, heart, liver, and brain revealed that no significant differences emerged among the three groups indicating that no specific pathology resulted correlated with the consumption of alkaline water. These results provide an informative and quantitative summary of survival data as a function of watering with alkaline water of long-lived mouse models. PMID:27340414

  11. Performed surfactant-optimized aqueous alkaline flood

    SciTech Connect

    Thigpen, D.R.; Lawson, J.B.; Nelson, R.C.

    1991-11-26

    This paper describes improvement in a process for recovering oil from an acidic oil reservoir by injecting an aqueous alkaline solution comprising water, sodium chloride, and alkaline material for reacting with the reservoir oil forming a petroleum acid soap to form an in-situ surfactant system. The improvement comprises: selecting a preformed cosurfactant which is soluble in both the aqueous solution and the reservoir oil and has a solubility ratio which is grater than the solubility ratio of the petroleum acid soap where the solubility ratio is the ratio of solubility in the aqueous alkaline solution to the solubility in the reservoir oil; combining with the alkaline solution an amount of the preformed cosurfactant which will result in the in-situ surfacant system having a salinity about equal to a salinity which results in minimal interfacial tension between the oil in the reservoir and the in-situ surfactant system at reservoir temperature, wherein the amount of the preformed cosurfactant is about 0.3 percent by weight in the aqueous alkaline solution; and injecting the cosurfactant-aqueous alkaline solution mixture into the reservoir to displace oil toward a fluid production location.

  12. Emplacement of kamafugite lavas from the Goiás alkaline province, Brazil: constraints from whole-rock simulations

    NASA Astrophysics Data System (ADS)

    Junqueira-Brod, Tereza Cristina; Gaspar, José Carlos; Brod, José Affonso; Jost, Hardy; Barbosa, Elisa Soares Rocha; Kafino, Camilla Vasconcelos

    2005-03-01

    The Late Cretaceous Goiás alkaline province (GAP) is composed of alkaline plutonic bodies (north), diatremes with subordinate flows, dykes, and plugs (central), and dominant lava flows and pyroclastics (south). In this work, we describe field and petrographic aspects of coherent kamafugites from Santo Antônio da Barra in the southern GAP and Águas Emendadas in the central GAP. Intensive variables inferred from simulations using whole-rock chemical data constrain the behavior of these kamafugitic magmas from their origin in the mantle to their final emplacement as upper-crust magma chambers, diatreme structures, and lava flows. In most cases, the evidence indicates that differentiation in both deep- and shallow-seated magma chambers intervened in their evolution. The discordance between the Precambrian basement and the Phanerozoic sedimentary rocks is the most likely site where the shallow chambers were established, whereas the deeper chambers were probably located in the upper crust. CO 2 seems to be the most important volatile phase. An interplay of various possible evolution paths involving crystal fractionation, magma mixing, and liquid immiscibility may explain the range of observed features in GAP kamafugites.

  13. [Alkaline phosphatase in Amoeba proteus].

    PubMed

    Sopina, V A

    2005-01-01

    In free-living Amoeba proteus (strain B), 3 phosphatase were found after disc-electrophoresis of 10 microg of protein in PAGE and using 1-naphthyl phosphate as a substrate a pH 9.0. These phosphatases differed in their electrophoretic mobilities - "slow" (1-3 bands), "middle" (one band) and "fast" (one band). In addition to 1-naphthyl phosphate, "slow" phosphatases were able to hydrolyse 2-naphthyl phosphate and p-nitrophenyl phosphate. They were slightly activated by Mg2+, completely inhibited by 3 chelators (EDTA, EGTA and 1,10-phenanthroline), L-cysteine, sodium dodecyl sulfate and Fe2+, Zn2+ and Mn2+ (50 mM), considerably inactivated by orthovanadate, molybdate, phosphatase inhibitor cocktail 1, p-nitrophenyl phosphate, Na2HPO4, DL-dithiothreitol and urea and partly inhibited by H2O2, DL-phenylalanine, 2-mercaptoethanol, phosphatase inhibitor cocktail 2 and Ca2+. Imidazole, L-(+)-tartrate, okadaic acid, NaF and sulfhydryl reagents -p-(hydroxy-mercuri)benzoate and N-ethylmaleimide - had no influence on the activity of "slow" phosphatases. "Middle" and "fast" phosphatases, in contrast to "slow" ones, were not inactivated by 3 chelators. The "middle" phosphatase differed from the "fast" one by smaller resistance to urea, Ca2+, Mn2+, phosphates and H2O2 and greater resistance to dithiothreitol and L-(+)-tartrate. In addition, the "fast" phosphatase was inhibited by L-cysteine but the "middle" one was activated by it. Of 5 tested ions (Mg2+, Cu2+, Mn2+, Ca2+ and Zn2+), only Zn2+ reactivated "slow" phosphatases after their inactivation by EDTA treatment. The reactivation of apoenzyme was only partial (about 35 %). Thus, among phosphatases found in amoebae at pH 9.0, only "slow" ones are Zn-metalloenzymes and may be considered as alkaline phosphatases (EC 3.1.3.1). It still remains uncertain, to which particular phosphatase class "middle" and "fast" phosphatases (pH 9.0) may belong.

  14. Growth of a Large Composite Magma System: the EJB Pluton, Eastern California.

    NASA Astrophysics Data System (ADS)

    Matty, D. J.; Vervoort, J.; Dufrane, A.; Hart, G.; Student, J.; Morgan, S.

    2008-12-01

    The composite EJB pluton crops out in the White-Inyo Mountains of eastern California, and comprises the Eureka Valley monzonite (EVM), the Joshua Flat quartz monzonite (JFQM), the Beer Creek granite (BCG), and an unnamed diorite. While sometimes equivocal, field relationships suggest that the EVM was emplaced first, followed by the JFQM, and finally the BCG; the diorite predates the BCG. Sylvester and others (GSAB, 1978) reported zircon U-Pb ages of 179±2 Ma for the EVM and 174±5 Ma for the JFQM. Coleman and others (GSAB, 2003) determined a U-Pb age of 179±3 Ma (via Pb-loss trajectory) for the BCG. Because of the uncertainty in the ages and ambiguous field relations, the sequence and duration of EJB magmatism remain unclear. To understand more fully the timing of EJB magmatism, we separated zircons from 12 samples collected from each of the main EJB units. These samples were characterized using light microscopy, SEM and CL techniques. U-Pb ages were determined from individual zircons by LA-ICP-MS following the method of Chang and others (G3, 2006). For the ages reported below, the reported uncertainties are based on factors within the analysis, but do not include external factors such as sample/standard bias or other matrix effects. Overall uncertainty in LA-ICPMS U-Pb geochronology is hard to assess, but we estimate that all ages reported below are subject to a minimum 2% uncertainty. We determined a concordant U-Pb age of 180±2 Ma for the EVM, which agrees with the results of Sylvester and others (1978). The unnamed diorite produced a concordant U-Pb age of 177±3 Ma. Concordant U-Pb ages of 172±2, 172±3, 173±2, 174±2, and 175±2 Ma were determined for individual samples of the JFQM and agree with the age reported by Sylvester and others (1978) of 174±5 Ma. Concordant U-Pb ages of 168±4, 168±3, 169±1, 172±2, and 172±2 Ma were determined for individual BCG samples. Within the reported error, there is no difference in age between individual samples of

  15. The Fractal Behavior of Crystal Distribution of la Gloria Pluton, Chile

    NASA Astrophysics Data System (ADS)

    Gutiérrez, F. J.; Payacán, I. J.; Pasten, D.; Aravena, A.; Gelman, S. E.; Bachmann, O.; Parada, M. A.

    2013-12-01

    We utilize fractal analysis to study the spatial distributions of crystals in a 10 Ma granitic intrusion (La Gloria pluton) located in the central Chilean Andes. Previous work determined the crystal size distribution (CSD) and anisotropy of magnetic susceptibility (AMS) tensors throughout this pluton. Using orthogonal thin sections oriented along the AMS tensor axes, we have applied fractal analysis in three magmatic crystal families: plagioclase, ferromagnesian minerals (biotite and amphibole), and Fe-Ti oxides (magnetite with minor ilmenite). We find that plagioclase and ferromagnesian minerals have a Semi-logarithmic CSD (S-CSD), given by: log(n/n0)= -L/C (1) where n [mm-4], n0 [mm-4], L [mm] and C [mm] are crystal density, intercept (nucleation density; L=0), size of crystals (three axes) and characteristic length, respectively. In contrast, Fe-Ti oxides have a Fractal CSD (F-CSD, power law size distribution), given by: log(n)= - Dn log(L) + n1 (2) where Dn and n1 [log(mm-4)] are a non-dimensional proportionality constant and the logarithm of the initial crystallization density (n1 = log(n(L=1 mm))), respectively. Finally, we calculate the fractal dimension (D0) by applying the box-counting method on each crystal thin section image, using: log(N) = -D0 log(ɛ) (3) where N and ɛ are the number of boxes occupied by minerals and the length of the square box, respectively. Results indicate that D0 values (eq. 3) are well defined for all minerals, and are higher for plagioclase than for ferromagnesian minerals and lowest for Fe-Ti oxides. D0 values are correlated with n0 and -1/C for S-CSD (eq. 1), and with n1 values for F-CSD (eq. 2). These correlations between fractal dimensions with CSD parameters suggest crystal growth follows a fractal behaviour in magmatic systems. Fractal behaviour of CSD means that the spatial distribution of crystals follows an all-scale pattern as part of a self-organized magmatic system. We interpret S-CSD of plagioclase and

  16. Late magmatic stage of the zoned Caleu pluton (Central Chile): insights from zircon crystallization conditions

    NASA Astrophysics Data System (ADS)

    Molina, P. G.; Parada, M.; Gutierrez, F. J.; Chang-Qiang, M.; Jianwei, L.; Yuanyuan, L.

    2012-12-01

    The Caleu pluton consists of three N-S elongated lithological zones: Gabbro-Diorite Zone (GDZ), Tonalite Zone (TZ) and Granodiorite Zone (GZ); western, middle and eastern portions of the pluton, respectively. The zones are thought to be previously differentiated in a common, isotopically depleted (Sr-Nd), subjacent magma reservoir at a 4 kbar equivalent depth. The emplacement should have occurred at the climax of the Cretaceous rifting. We present preliminary results of U238/Pb206 zircon geochronology; zircon saturation, Tsat(Zrn), and crystallization temperatures (Ti-in-Zrn); as well as relative oxidation states at time of crystallization, based on: (i) the sluggish REE and HFSE subsolidus diffusivities in zircon; (ii) the behavior of Ti4+↔Si4+ and Ce4+↔Zr4+ isovalent replacement, in addition to a constrained TiO2 activity in almost all typical crustal rocks; and (iii) relative oxidation states at time of crystallization, respectively. The latter are obtained by interpolation of the partition coefficients of trivalent (REE) and tetravalent (HFSE) curves in Onuma diagrams for each zircon, and then estimating relative Ce(IV)/Ce(III) ratios. Results obtained from 4 samples (a total of 77 zircon grains) collected from the three mentioned lithological zones indicate U/Pb ages of approximately 99.5 ±1.5 Ma, 96.8 ±0.6 Ma, and 94.4 +2.2 -0.8 Ma; and Ti-in Zrn ranges of ca. 720-870°C, ca. 680-820°C and ca. 750-840°C, for the GDZ, TZ and GZ samples, respectively. On the other hand Tsat(Zrn) of ca. 750-780°C in the TZ, and ca. 830-890°C in the GZ, were obtained. As expected saturation temperatures are similar or higher than Ti-in-Zrn obtained in zircon grains of TZ and GZ, respectively. Cathodoluminiscence images in zircon suggest a magmatic origin, due to absence of complex zoning patterns and fairly well conserved morphologies. Exceptionally the GDZ sample zircons show evidence of inheritance, indicating a xenocrystic and/or antecrystic origin. A relative Ce

  17. Multi-sensor geophysical constraints on crustal melt in the central Andes: the PLUTONS project

    NASA Astrophysics Data System (ADS)

    Pritchard, M. E.; Comeau, M. J.; West, M. E.; Christensen, D. H.; Mcfarlin, H. L.; Farrell, A. K.; Del Potro, R.; Gottsmann, J.; McNutt, S. R.; Michelfelder, G.; Diez, M.; Elliott, J.; Henderson, S. T.; Keyson, L.; Delgado, F.; Unsworth, M. J.

    2015-12-01

    The central Andes is a key global location to quantify storage, transport, and volumes of magma in the Earth's crust as it is home to the world's largest zone of partial melt (the Altiplano-Puna Magma or Mush Body, APMB) as well as the more recently documented Southern Puna Magma Body (SPMB). We describe results from the recently completed international PLUTONS project that focused inter-disciplinary study on two sites of large-scale surface uplift that presumably represent ongoing magmatic intrusions in the mid to upper crust - Uturuncu, Bolivia (in the center of the APMB) and Lazufre on the Chile-Argentina border (on the edge of the SPMB). In particular, a suite of geophysical techniques (seismology, gravity, surface deformation, and electro-magnetic methods) have been used to infer the current subsurface distribution and quantity of partial melts in combination with geochemical and lab studies on samples from the area. Both Uturuncu and Lazufre show separate geophysical anomalies in the upper and mid/lower crust (e.g., low seismic velocity, low resistivity, etc.) indicating multiple distinct reservoirs of magma and/or hydrothermal fluids with different properties. The characteristics of the geophysical anomalies differ somewhat depending on the technique used - reflecting the different sensitivity of each method to subsurface melt of different compositions, connectivity, and volatile content. For example, the depth to the top of the APMB is shallower in a joint ambient noise tomography and receiver function analysis compared to a 3D magnetotelluric inversion. One possibility is that the seismic methods are detecting brines above the APMB that do not have a large electromagnetic signature. Comparison of the geophysical measurements with laboratory experiments at the APMB indicate a minimum of 4-25% melt averaged over the region is needed -- higher melt volumes are permitted by the gravity and MT data and may exist in small regions. However, bulk melt values above

  18. Origin and interaction of some alkalic and silicic plutons in the Vermilion Granitic Complex, NE Minnesota

    SciTech Connect

    McCall, G.W.; Nabelek, P.I.; Bauer, R.L.; Glascock, M.D.

    1985-01-01

    Alkalic gabbros and tonalites comprise a significant portion of the Archaean crust in the Vermilion Granitic Complex of NE Minnesota. The origin of these and associated rocks has been modeled using major and trace element approaches. Samples of the alkalic gabbro collected from three different intrusions have similar major element, REE, and transition metal concentrations. The REE patterns of these rocks can be modeled as the result of 1% to 3% melting of an undepleted garnet herzolite mantle with REE concentrations three times that of chondrites. However, their Al/sub 2/O/sub 3//CaO ratios of 2 - 3, Sr content of 900-1400 ppm and Ba of 100 - 1600 ppm suggest that the source may have been an enriched, metasomatized mantle. The hornblendites associated with these alkalic rocks have REE patterns which are consistent with crystallization and accumulation from the gabbroic magma. Major and trace element modeling suggest that the granitic dikes which are common throughout the area may be residual liquids formed by 60% crystallization of plagioclase, biotite, hornblende and apatite from the nearby tonalites such as the Burntside of Wakemup Bay plutons. Porphyritic hornblende monzonites composed of centimeter sized hornblende crystals floating in a granitic matrix occur locally. The field relations as well as the major and trace element data are consistent with the formation of these monzonitic rocks by mixing of the granite with partially consolidated hornblendite. These results suggest a complex interaction between alkalic gabbros and tonalites involving fractionation and mixing during the development of the Archaean crust of NE Minnesota.

  19. The origin of rhythmic layering in the Cape Neddick Plutonic Complex, Maine

    SciTech Connect

    Shipley, J. . Dept. of Geology)

    1993-03-01

    The Cape Neddick Plutonic Complex located along the southwestern coast of Maine is a small layered gabbroic body. It contains four concentric gabbros of differing composition, From the center to the exterior these are Cortlandtitic, Anorthositic, Normal, and Pegmatitic gabbros. They vary slightly in the proportion of essential minerals; plagioclase, clinopyroxene, hornblende, and biotite [+-] opaques and olivine. Rhythmic layering is seen in all four gabbros. This layering is also concentric around the center of the complex. The best exposure of the layering is along the coast where non-graded and graded rhythmic layering is seen extensively in the Normal gabbro. Only non-graded layering is seen in the Anorthositic gabbro. Non-graded layers were sampled at two localities. One locality is on Cape Nubble Island in the Normal gabbro. The second locality is in the Anorthositic gabbro along the northern coast. The layers are roughly 5--8 cm in width and are continuous around the complex. They are identified on weathered surfaces as alternating bands of felsic and mafic minerals. Layers are not obvious in hand sample. Approximately 15--20 layers were sampled perpendicular to layering. Petrographic and geochemical studies will help constrain the origin of rhythmic layering in the Cape Neddick Complex. Crystal settling or structural processes seem highly unlikely due to the small distance between the layers and the fact that they are not graded. Possible models include multiple pulses of magma within the same magma chamber, density currents, or in situ fractionation by a nucleation-diffusion process. Modal and chemical analysis of mineral phases within individual layers will allow comparison of the bulk composition of each layer. Analysis of coexisting pyroxene and plagioclase can be used to estimate compositional variations in the parent liquid.

  20. Petrological and geochemical constraints on granitoid formation: The Waldoboro Pluton Complex, Maine

    SciTech Connect

    Barton, M. . Dept. of Geological Science); Sidle, W.S. )

    1992-01-01

    The Waldoboro Pluton Complex (WPC) comprises seven units ranging from qtz-diorite to aplite. The country rocks are biotite-rich metagraywackes with minor shales mostly belonging to the Proterozoic Z-Ordovician Bucksport Formation. Field evidence strongly suggests that the WPC formed in-situ: contacts with the country rock are cryptic, transitional and concordant; restitic minerals in the granitoids are identical to those in the country rocks; prolific metasedimentary enclaves in the WPC are locally derived. Major and trace element data for country rock and the most voluminous units of the WPC define consistent linear trends suggesting limited melt segregation and retention of a high proportion of restite. Mixing models and partial melting models require 54--76% melting for generation of the gneissic granites and two-mica granites. Garnet-biotite geothermometry and garnet-Al[sub 2]SiO[sub 5]-SiO[sub 2]-plagioclase geobarometry indicate that the WPC formed at T = 740--780 C and P = 0.4--0.7 GPa. Published experimental data show that < 50% melting is likely under these conditions if melting is controlled by dehydration reactions. Bucksport lithologies contain < 20% biotite, suggesting that the maximum amount of melt that could have formed by dehydration melting is < 20%, even if all biotite was consumed during melting. It seems probable that a free fluid phase was required to generate the WPC. Migmatization is apparent in all lithologies (including amphibolites) in the vicinity of the WPC, consistent with fluid-present melting. Fluid may have ingressed along the St. George thrust, but the source of the fluid is unknown.

  1. Geologic and hydrologic controls on the economic potential of hydrothermal systems associated with upper crustal plutons

    NASA Astrophysics Data System (ADS)

    Weis, Philipp; Driesner, Thomas; Scott, Samuel; Lecumberri-Sanchez, Pilar

    2016-04-01

    Heat and mass transport in hydrothermal systems associated with upper crustal magmatic intrusions can result in resources with large economic potential (Kesler, 1994). Active hydrothermal systems can form high-enthalpy geothermal reservoirs with the possibility for renewable energy production. Fossil continental or submarine hydrothermal systems may have formed ore deposits at variable crustal depths, which can be mined near today's surface with an economic profit. In both cases, only the right combination of first-order geologic and hydrologic controls may lead to the formation of a significant resource. To foster exploration for these hydrothermal georesources, we need to improve our understanding of subsurface fluxes of mass and energy by combining numerical process modelling, observations at both active and fossil systems, as well as knowledge of fluid and rock properties and their interactions in natural systems. The presentation will highlight the role of non-linear fluid properties, phase separation, salt precipitation, fluid mixing, permeability structure, hydraulic fracturing and the transition from brittle to ductile rock behavior as major geologic and hydrologic controls on the formation of high-enthalpy and supercritical geothermal resources (Scott et al., 2015), and magmatic-hydrothermal mineral resources, such as porphyry copper, massive sulfide and epithermal gold deposits (Lecumberri-Sanchez et al., 2015; Weis, 2015). References: Kesler, S. E., 1994: Mineral Resources, economics and the environment, New York, McMillan, 391. Lecumberri-Sanchez, P., Steele-MacInnis, M., Weis, P., Driesner, T., Bodnar, R.J. (2015): Salt precipitation in magmatic-hydrothermal systems associated with upper crustal plutons. Geology, v. 43, p. 1063-1066, doi:10.1130/G37163.1 Scott, S., Driesner, T., Weis, P. (2015): Geologic controls on supercritical geothermal resources above magmatic intrusions. Nature Communications, 6:7837 doi: 10.1038/ncomms8837 Weis, P. (2015): The

  2. Polychronous (Early Cretaceous to Palaeogene) emplacement of the Mundwara alkaline complex, Rajasthan, India: 40Ar/39Ar geochronology, petrochemistry and geodynamics

    NASA Astrophysics Data System (ADS)

    Pande, Kanchan; Cucciniello, Ciro; Sheth, Hetu; Vijayan, Anjali; Sharma, Kamal Kant; Purohit, Ritesh; Jagadeesan, K. C.; Shinde, Sapna

    2016-07-01

    The Mundwara alkaline plutonic complex (Rajasthan, north-western India) is considered a part of the Late Cretaceous-Palaeogene Deccan Traps flood basalt province, based on geochronological data (mainly 40Ar/39Ar, on whole rocks, biotite and hornblende). We have studied the petrology and mineral chemistry of some Mundwara mafic rocks containing mica and amphibole. Geothermobarometry indicates emplacement of the complex at middle to upper crustal levels. We have obtained new 40Ar/39Ar ages of 80-84 Ma on biotite separates from mafic rocks and 102-110 Ma on whole-rock nepheline syenites. There is no evidence for excess 40Ar. The combined results show that some of the constituent intrusions of the Mundwara complex are of Deccan age, but others are older and unrelated to the Deccan Traps. The Mundwara alkaline complex is thus polychronous and similar to many alkaline complexes around the world that show recurrent magmatism, sometimes over hundreds of millions of years. The primary biotite and amphibole in Mundwara mafic rocks indicate hydrous parental magmas, derived from hydrated mantle peridotite at relatively low temperatures, thus ruling out a mantle plume. This hydration and metasomatism of the Rajasthan lithospheric mantle may have occurred during Jurassic subduction under Gondwanaland, or Precambrian subduction events. Low-degree decompression melting of this old, enriched lithospheric mantle, due to periodic diffuse lithospheric extension, gradually built the Mundwara complex from the Early Cretaceous to Palaeogene time.

  3. The Pan-African high-K calc-alkaline peraluminous Elat granite from southern Israel: geology, geochemistry and petrogenesis

    NASA Astrophysics Data System (ADS)

    Eyal, M.; Litvinovsky, B. A.; Katzir, Y.; Zanvilevich, A. N.

    2004-10-01

    Calc-alkaline leucocratic granites that were emplaced at the late post-collision stage of the Pan-African orogeny are abundant in the northern half of the Arabian-Nubian Shield. Commonly, they are referred to as the Younger Granite II suite. In southern Israel such rocks are known as Elat granite. Studies of these rocks enable to recognize two types of granites: coarse-grained, massive Elat granite (EG), and fine- to medium-grained Shahmon gneissic granite (SGG). Both granite types are high-K and peraluminous ( ASI ranges from 1.03 to 1.16). They are similar in modal composition, mineral and whole-rock chemistry. Within the EG, a noticeable distinction in whole-rock chemistry and mineral composition is observed between rocks making up different plutons. In particular, the granite of Wadi Shelomo, as compared to the Rehavam pluton, is enriched in SiO 2, FeO∗, K 2O, Ba, Zr, Th, LREE and impoverished in MgO, Na 2O, Sr, and HREE. The Eu/Eu∗ values in the granite are low, up to 0.44. Mass-balance calculations suggest that chemical and mineralogical variations were caused by fractionation of ˜16 wt.% plagioclase from the parental Rehavam granite magma at temperature of 760-800 °C (muscovite-biotite geothermometer). The Rb-Sr isochrons yielded a date of 623 ± 24 Ma for the EG, although high value of age-error does not allow to constrain time of emplacement properly. The Rb-Sr date for SGG is 640 ± 9 Ma; however, it is likely that this date points to the time of metamorphism. A survey of the literature shows that peraluminous, high-K granites, similar to the EG, are abundant among the Younger Granite II plutons in the Sinai Peninsula and Eastern Desert, Egypt. They were emplaced at the end of the batholithic (late post-collision) stage. The most appropriate model for the generation of the peraluminous granitic magma is partial melting of metapelite and metagreywacke.

  4. Intermediate range order in alkaline borate glasses

    NASA Astrophysics Data System (ADS)

    Crupi, C.; Carini, G.; Ruello, G.; D'Angelo, G.

    2016-03-01

    We describe the neutron diffraction patterns of a series of alkaline borate glasses at different metal oxide content. Strong differences are observed in the intermediate range order as a function of the specific alkaline ion and of its concentration. On these results, we propose that the first sharp diffraction peak arises from correlations of atoms of voids and show that the compositional variation of this peak intensity in alkaline borate glasses is due to changes in the distribution of void sizes within the three-dimensional network. We argue that our interpretation in terms of interstitial (empty and/or filled) voids, having different sizes, provides a general explanation for all anomalous behaviours revealed for the first sharp diffraction peak.

  5. Plutonism at Different Crustal Levels of an Arc: Insights From the 5 to 40 km (Paleodepth) North Cascades Crustal Section, Washington

    NASA Astrophysics Data System (ADS)

    Miller, R. B.; Paterson, S. R.; Matzel, J. P.

    2008-12-01

    The crystalline core of the North Cascades preserves a Cretaceous crustal section that facilitates evaluation of pluton construction, emplacement, geometry, composition, and deformation at widely variable crustal levels (~5 to 40 km paleodepth) in a thick (> 55 km) continental magmatic arc. The oldest and largest pulse of plutonism was focused between 96-89 Ma when fluxes were a minimum of 3.9x10-6km3/yr/km of arc length, but the coincidence with regional crustal thickening and underthrusting of a cool outboard terrane resulted in relatively low mid- to deep-crustal temperatures for an arc. A second, smaller peak of magmatism at 78-71 Ma (minimum of 8.2x10-7km3/yr/km of arc length) occurred during regional transpression. Tonalite dominates at all levels of the section. Intrusions range from large plutons to thin (< 50 m) dispersed sheets encased in metamorphic rocks that record less focused magmatism. The percentage of igneous rocks increases systematically from shallow to middle to deep levels; from approximately 37% to 55% to 65% of the total rock volume. Unfocused magmas comprise much higher percentages (approximately 19%) of the total plutonic rock at deep- and mid-crustal depths, but only 1% at shallower levels, whereas the largest intrusions were emplaced into shallow crust. Plutons have a range of shapes, including: asymmetric wedges to funnels; subhorizontal tabular sheets; steep-sided, blade-shaped bodies with high aspect ratios in map view; and steep-sided, vertically extensive (> 8 km) bodies shaped like thick disks and/or hockey pucks. Sheeted intrusions and gently dipping tabular bodies are more common with depth. Some of these plutons fit the model that most intrusions are subhorizontal and tabular, but many do not, reflecting the complex changes in lithology and rheology in arc crust undergoing regional shortening. The steep sheeted plutons partly represent magma transfer zones that fed the large shallow plutons, which were sites of intermittent

  6. Laser direct write of planar alkaline microbatteries

    NASA Astrophysics Data System (ADS)

    Arnold, C. B.; Kim, H.; Piqué, A.

    We are developing a laser engineering approach to fabricate and optimize alkaline microbatteries in planar geometries. The laser direct-write technique enables multicapability for adding, removing and processing material and provides the ability to pattern complicated structures needed for fabricating complete microbattery assemblies. In this paper, we demonstrate the production of planar zinc-silver oxide alkaline cells under ambient conditions. The microbattery cells exhibit 1.55-V open-circuit potentials, as expected for the battery chemistry, and show a flat discharge behavior under constant-current loads. High capacities of over 450 μAhcm-2 are obtained for 5-mm2 microbatteries.

  7. Alkaline earth filled nickel skutterudite antimonide thermoelectrics

    DOEpatents

    Singh, David Joseph

    2013-07-16

    A thermoelectric material including a body centered cubic filled skutterudite having the formula A.sub.xFe.sub.yNi.sub.zSb.sub.12, where A is an alkaline earth element, x is no more than approximately 1.0, and the sum of y and z is approximately equal to 4.0. The alkaline earth element includes guest atoms selected from the group consisting of Be, Mb, Ca, Sr, Ba, Ra and combinations thereof. The filled skutterudite is shown to have properties suitable for a wide variety of thermoelectric applications.

  8. Alkaline Capacitors Based on Nitride Nanoparticles

    NASA Technical Reports Server (NTRS)

    Aldissi, Matt

    2003-01-01

    High-energy-density alkaline electrochemical capacitors based on electrodes made of transition-metal nitride nanoparticles are undergoing development. Transition- metal nitrides (in particular, Fe3N and TiN) offer a desirable combination of high electrical conductivity and electrochemical stability in aqueous alkaline electrolytes like KOH. The high energy densities of these capacitors are attributable mainly to their high capacitance densities, which, in turn, are attributable mainly to the large specific surface areas of the electrode nanoparticles. Capacitors of this type could be useful as energy-storage components in such diverse equipment as digital communication systems, implanted medical devices, computers, portable consumer electronic devices, and electric vehicles.

  9. 3.30 Ga high-silica intraplate volcanic-plutonic system of the Gavião Block, São Francisco Craton, Brazil: Evidence of an intracontinental rift following the creation of insulating continental crust

    NASA Astrophysics Data System (ADS)

    Zincone, Stefano A.; Oliveira, Elson P.; Laurent, Oscar; Zhang, Hong; Zhai, Mingguo

    2016-12-01

    High-silica rhyolites having U-Pb zircon ages of 3303 ± 11 Ma occur along the eastern border of the Gavião Block (Brazil) associated with the Contendas-Mirante and Mundo Novo supracrustal belts. Unlike many Archean greenstone sequences, they are not interlayered with mafic to intermediate units. Instead, they belong to an inter-related plutonic-volcanic system, together with granitic massifs having similar zircon crystallization ages of ca. 3293 ± 3 Ma and 3328 ± 3 Ma and plotting along the same geochemical trends as the rhyolites. The rhyolites show well-preserved primary volcanic features such as magma flow textures and euhedral phenocrysts. High emplacement temperatures are indicated by petrographic evidence (β-quartz phenocrysts), zircon saturation temperatures (915-820 °C) and geochemical data, especially high SiO2 (74-79 wt.%) together with elevated Fe2O3(T) ( 3 wt.%), MgO (0.5-1.5 wt.%) and low Al2O3 (< 11 wt.%). The rhyolites show homogeneous trace element ratios (La/YbN 4.8 ± 1.8; EuN/Eu* 0.55; Sr/Y 0.7) and negative ԐHf(3.3 Ga) from 0 to - 7, indicating derivation from a single crustal source for both occurrences. Specifically, the rhyolites would have derived from extraction and eruption of highly silicic residual liquid formed by crystallization of granitic magma in a relatively shallow (< 10 km) reservoir, now represented by the granite massifs. The granite magma was formed by melting or differentiation of material similar to the diorite gneiss that occurs regionally. The 3.30 Ga volcanic-plutonic systems formed after a period of crustal growth and stabilization of a thick continental lithosphere, represented by massive 3.40-3.33 Ga TTG and medium to high-K calk-alkaline magmatism in the Gavião Block. The 3.30 Ga-old rhyolites and granites would therefore have formed in an intracontinental tectonic setting after the formation and stabilization of new continental crust, and accordingly would represent the first stages of rifting and continental

  10. Indoor radon risk associated to post-tectonic biotite granites from Vila Pouca de Aguiar pluton, northern Portugal.

    PubMed

    Martins, L M O; Gomes, M E P; Teixeira, R J S; Pereira, A J S C; Neves, L J P F

    2016-11-01

    At Vila Pouca de Aguiar area, northern Portugal, crops out a post-tectonic Variscan granite pluton, related with the Régua-Vila Real-Verín fault zone, comprising three types of biotite granites. Among these granites, PSG granite yield the highest average contents of U, probably due to its enrichment in accessory U-bearing minerals such as zircon. In the proximity of faults and joints, these granites are often affected by different degrees of hydrothermal alteration, forming reddish altered rocks, commonly known as "episyenites". These altered rocks are probably associated to the occurrence of hydrothermal processes, which led to uranium enrichment in the most advanced stages of episyenitization. In these granites, both average gamma absorbed dose rates in outdoor and indoor air are higher than those of the world average. Furthermore, even in the worst usage scenario, all these granites can be used as a building material, since their annual effective doses are similar to the limit defined by the European Commission. The geometric mean of radon activity of 91 dwellings located at the Vila Pouca de Aguiar pluton is 568Bqm(-3), exceeding that of other northern Portuguese granites. Measurements carried out during a winter season, indicate that 62.6% of the analysed dwellings yield higher indoor radon average values than the Portuguese legislation limit (400Bqm(-3)), and annual effective doses due higher than the world's average value (1.2mSvy(-1)). The interaction of geogenic, architectural and anthropogenic features is crucial to explain the variance in the geometric mean of radon activity of dwellings from Vila Pouca de Aguiar pluton, but the role of geologic faults is probably the most important decisive factor to increase the indoor radon concentration in dwellings. Hence, the development of awareness campaigns in order to inform population about the incurred radiological risks to radon exposure are highly recommended for this specific area.

  11. Constraints on ages of Taconian and Acadian deformation from zircon evaporation ages of felsic plutons from western Massachusetts

    SciTech Connect

    Williamson, B.F.; Karabinos, P. . Dept. of Geology)

    1993-03-01

    New dates on three felsic plutons constrain the age of Taconian and Acadian deformation in western Massachusetts. The tonalitic Hallockville Pond Gneiss intrudes the Moretown Formation of the Rowe-Hawley belt and shows deformation comparable in degree and orientation to that of the surrounding rocks. The Middlefield Granite, a quartz monzonite, intrudes the Rowe and Moretown Formations at their contact. The Williamsburg Granodiorite, of minimum-melt composition, intrudes Silurian and Devonian formations of the Connecticut Valley Synclinorium, east of the Row-Hawley belt, and contains no obvious deformation fabric. [sup 207]Pb/[sup 206]Pb single-grain zircon evaporation ages for these plutons are as follows: the Hallockville Pond Gneiss, 484 [plus minus] 7 Ma; the Middlefield Granite, 447 [plus minus] 3 Ma (weighted average of 4 grains); and the Williamsburg Granodiorite, 373 [plus minus] 5 Ma (weighted average of 3 grains). The Moretown Formation, presently correlated with the Middle Ordovician Beauceville Formation in Quebec, must be older than 484 Ma (Early Ordovician), the age of the intruding Hallockville Pond Gneiss, which might be related to rocks in the proposed Shelburne Falls arc of similar age (Karabinos and Tucker, 1992). Field relations and the age of the Middlefield Granite show that if the Rowe-Moretown contact is a fault, one interpretation suggested by Stanley and Hatch (1988) and advocated by Ratcliffe et al. (1992), then Taconian thrusting in this area ended by 447 Ma because the pluton is not offset by faults. The 373 Ma age of the unfoliated Williamsburg Granodiorite, together with a U-Pb zircon age on a strongly deformed sill in the Granville dome of 376 [plus minus] 4 Ma, tightly constrains the timing of the main phase of Acadian deformation in western Massachusetts.

  12. Plutonic xenoliths from Martinique, Lesser Antilles: evidence for open system processes and reactive melt flow in island arc crust

    NASA Astrophysics Data System (ADS)

    Cooper, George F.; Davidson, Jon P.; Blundy, Jon D.

    2016-10-01

    The Lesser Antilles Volcanic Arc is remarkable for the abundance and variety of erupted plutonic xenoliths. These samples provide a window into the deeper crust and record a more protracted crystallisation history than is observed from lavas alone. We present a detailed petrological and in situ geochemical study of xenoliths from Martinique in order to establish their petrogenesis, pre-eruptive storage conditions and their contribution to construction of the sub-volcanic arc crust. The lavas from Martinique are controlled by crystal-liquid differentiation. Amphibole is rarely present in the erupted lavas, but it is a very common component in plutonic xenoliths, allowing us to directly test the involvement of amphibole in the petrogenesis of arc magmas. The plutonic xenoliths provide both textural and geochemical evidence of open system processes and crystal `cargos'. All xenoliths are plagioclase-bearing, with variable proportions of olivine, spinel, clinopyroxene, orthopyroxene and amphibole, commonly with interstitial melt. In Martinique, the sequence of crystallisation varies in sample type and differs from other islands of the Lesser Antilles arc. The compositional offset between plagioclase (~An90) and olivine (~Fo75), suggests crystallisation under high water contents and low pressures from an already fractionated liquid. Texturally, amphibole is either equant (crystallising early in the sequence) or interstitial (crystallising late). Interstitial amphibole is enriched in Ba and LREE compared with early crystallised amphibole and does not follow typical fractionation trends. Modelling of melt compositions indicates that a water-rich, plagioclase-undersaturated reactive melt or fluid percolated through a crystal mush, accompanied by the breakdown of clinopyroxene, and the crystallisation of amphibole. Geothermobarometry estimates and comparisons with experimental studies imply the majority of xenoliths formed in the mid-crust. Martinique cumulate xenoliths are

  13. Mineral associations produced by sodic-calcic hydrothermal alteration in the Buffalo Mountain pluton, north-central Nevada

    SciTech Connect

    McBride, D. . Dept. of Geology and Geography)

    1993-03-01

    Sodic-calcic (Na-Ca) hydrothermal alteration is prevalent throughout Mesozoic-age arc igneous rocks in the western US. The middle Jurassic Buffalo Mountain pluton, located in north-central Nevada, contains particularly well developed Na-Ca metasomatism. The Buffalo Mountain pluton is composed of porphyritic syenite, quartz monzonite, small bordering stocks (which account for less than 1% of the pluton), and an extensive felsic dike swarm. Quartz monzonite intruded syenite and constitutes the majority of the surface area. Unaltered porphyritic syenite is composed of perthite, plagioclase, quartz, augite, hornblende, biotite, olivine, magnetite, and other minerals accounting for less than 1% of the rock. Unaltered quartz monzonite is an aggregate of K-feldspar, plagioclase, quartz, biotite, hornblende, and accessory minerals accounting for less than 1% of the rock. The dikes cut both phases of the total intrusive rock body and are closely related in space to zones of Na-Ca alteration. Alteration variably affects all igneous rock types and exists as both fracture-controlled and pervasive Na-Ca alteration. Sodic-calcic alteration resulted in the following mineral reactions: K-feldspar is replaced by chalky-colored plagioclase, and primary mafic minerals react to form pale green diopside or, less commonly, actinolite. Garnet, scapolite, and epidote are often spatially associated with Na-Ca altered rocks. The fact that Na-Ca alteration occurs most commonly in and around dikes suggests that they might have been the source of channel for fluid entry into the surrounding igneous rocks. Further study will seek to constrain the origins and pathways of Na-Ca fluids.

  14. Investigation of Plutonic Rocks in Biga Peninsula, NW Turkey, using 3D Normalized Full Gradient of Magnetic Data

    NASA Astrophysics Data System (ADS)

    Ekinci, Y. L.; Yiǧitbaş, E.

    2012-04-01

    Airborne magnetic data of Biga Peninsula were investigated by using 3D Normalized Full Gradient (NFG) technique. The NFG procedure is based on the downward continuation of the potential field data and the NFG amplitude is calculated by dividing the Analytic Signal (AS) of downward continued magnetic data by the average of AS. Application of NFG technique usually enhances the anomalies by computing the anomaly to a level close to the source bodies and points to the boundaries of causative bodies. To that end, a MATLAB based code consisting of a series of linked functions was developed and used for analyses. Study area covers an area of 120 km x 180 km and the data were collected with 1-2 km profile intervals and with about 70 m sampling from 625 m above the ground surface by MTA (General Directorate of Mineral Research and Exploration). 2 km sampling intervals for both north and east directions were used for gridding of the magnetic data. Regional anomalies were approximated by means of element shape functions used in finite element method and then residuals were computed. Prior to the application of 3D NFG, Reduction to the Pole (RTP) transformation was applied to residual data in order to remove the complexity due to the effects of the direction of magnetization and ambient field. RTP transformation process was performed using 55 and 4 degrees for inclination and declination angles, respectively. 3D NFG operation was performed to reduced to pole data for 6 different depth levels (-200, -400, -600, -800, -1000 and -1200 m). Analyzing the resulting anomaly maps of different depth levels together with the geological map (1/500.000) showed that the locations of maximum NFG amplitudes indicate the boundaries of plutonic rocks having high magnetization intensity. Additionally, horizontal and vertical extensions of plutonic rocks were also determined. Keywords: Airborne magnetic data, normalized full gradient, plutonic rocks, Biga Peninsula-Turkey

  15. Crystallization conditions of porphyritic high-K calc-alkaline granitoids in the extreme northeastern Borborema Province, NE Brazil, and geodynamic implications

    NASA Astrophysics Data System (ADS)

    Campos, Benedita Cleide Souza; Vilalva, Frederico Castro Jobim; Nascimento, Marcos Antônio Leite do; Galindo, Antônio Carlos

    2016-10-01

    An integrated textural and chemical study on amphibole, biotite, plagioclase, titanite, epidote, and magnetite was conducted in order to estimate crystallization conditions, along with possible geodynamic implications, for six Ediacaran porphyritic high-K calc-alkaline granite plutons (Monte das Gameleiras, Barcelona, Acari, Caraúbas, Tourão, and Catolé do Rocha) intrusive into Archean to Paleoproterozoic rocks of the São José do Campestre (SJCD) and Rio Piranhas-Seridó (RPSD) domains, northern Borborema Province. The studied rocks include mainly porphyritic leucocratic monzogranites, as well as quartz-monzonites and granodiorites. Textures are marked by K-feldspar megacrysts (5-15 cm long) in a fine-to medium-grained matrix composed of quartz, plagioclase, amphibole, biotite, as well as titanite, epidote, Fesbnd Ti oxides, allanite, apatite, and zircon as accessory minerals. Amphibole, biotite and titanite share similar compositional variations defined by increasing Al and Fe, and decreasing Mg contents from the plutons emplaced into the SJCP (Monte das Gameleiras and Barcelona) towards those in the RPSD (Acari, Caraúbas, Tourão, and Catolé do Rocha). Estimated intensive crystallization parameters reveal a weak westward range of increasing depth of emplacement, pressure and temperature in the study area. The SJCD plutons (to the east) crystallized at shallower crustal depths (14-21 km), under slightly lower pressure (3.8-5.5 kbar) and temperature (701-718 °C) intervals, and high to moderate oxygen fugacity conditions (+0.8 < ΔFQM < +2.0). On the other hand, the RPSD plutons (to the west) were emplaced at slightly deeper depths (18-23 km), under higher, yet variable pressures (4.8-6.2 kbar), temperatures (723-776 °C), and moderate to low oxygen fugacity conditions (-1.0 < ΔFQM < +1.8). These results reinforce the contrasts between the tectono-strutuctural domains of São José do Campestre and Rio Piranhas-Seridó in the northern Borborema Province.

  16. Multiple origins for the Middle Jurassic to Early Cretaceous high-K calc-alkaline I-type granites in northwestern Fujian province, SE China and tectonic implications

    NASA Astrophysics Data System (ADS)

    Wang, Guo-Chang; Jiang, Yao-Hui; Liu, Zheng; Ni, Chun-Yu; Qing, Long; Zhang, Qiao; Zhu, Shu-Qi

    2016-03-01

    A comprehensive study of zircon U-Pb dating and in situ Hf isotopes, whole-rock major and trace element geochemistry and Sr-Nd isotopes was carried out for three late Mesozoic granitic plutons (Waitun, Shipi and Taiyuan) in northwestern Fujian province, SE China. We assess the origin of the granites and their relationship to the evolution of the late Mesozoic volcanic-intrusive complex belt in SE China. LA-ICP-MS zircon U-Pb dating shows that three plutons were emplaced in the Middle Jurassic to Early Cretaceous (168-109 Ma), in which the Waitun and Shipi plutons are intrusive complexes. All the plutons are composed of high-K calc-alkaline I-type granites with a great diversity in elemental and isotopic compositions. The granites have SiO2 contents of 68.3-78.5 wt.%, showing a gradual decrease in initial 87Sr/86Sr (0.7181 to 0.7091) and increase in εNd (T) (- 16.7 to - 8.1) and εHf (T) (in-situ zircon) (- 20.6 to - 6.9) with decreasing emplacement ages. Geochemical data suggest that the Middle Jurassic ( 168 Ma) Waitun granites are of purely crustal origin, derived by partial melting of a mixed source of Paleoproterozoic metaigneous ( 78%) and metasedimentary ( 22%) rocks at a depth of 30-40 km triggered by underplating of basaltic magma. Mixing of such crustal melts with about 10% basaltic magma could account for the origin of the Late Jurassic ( 161 Ma) Waitun granites. The Late Jurassic ( 156 Ma) Shipi and Early Cretaceous ( 134 Ma) Taiyuan granites were produced by extensive fractional crystallization of primary crustal melts, the source of which show relatively high proportion ( 82%) of metaigneous rocks. The Early Cretaceous ( 109 Ma) Shipi granites were generated by partial melting of a mixed source of Paleoproterozoic metaigneous ( 92%) and metasedimentary ( 8%) rocks at a depth of 30 km plus additional ( 15%) input from coeval basaltic magma. The granites were formed in a continental arc setting induced by northwestward subduction of the Paleo

  17. Mineral potential of felsic plutonic rocks in the north-central Arabian Shield, Kingdom of Saudi Arabia

    USGS Publications Warehouse

    Moore, W.J.

    1985-01-01

    The muscovite-bearing monzogranites containing anomalous tin and tungsten in rock and (or) wadi sediment samples occur generally east of long 42°30' E. Two of these, Jabal Minya and Jabal Khinzir, are recommended for immediate follow-up studies. Of the alkali granites, most of which occur in the area west of long 42°30' E., the composite plutons of Jabal Hadb ad Dayahin and Jabal Tuqfah have the highest potential for rare-element mineralization and warrant prompt systematic investigation. Evaluation of isolated one- or two-element anomalies should be coordinated with current high-density geochemical prospecting programs of the Riofinex Geological Mission.

  18. Structural characterization of the Misajé granitic pluton (NW Cameroon): constraints from magnetic and field observations

    NASA Astrophysics Data System (ADS)

    Fozing, Eric Martial; Njanko, Théophile; Naba, Séta; Kwékam, Maurice; Njonfang, Emmanuel; Rochette, Pierre

    2016-11-01

    The Misajé granitic pluton, emplaced between 569 and 560 Ma in an amphibolitic and gneissic host rock, comprises four petrographic units namely biotite-hornblende granite (BHG), granodiorite (Gd), biotite granite (BG), and leucocratic granite (LG). Four major tectonic events have been described in the studied area: a D1-early tectonic event, responsible of the E-W flat foliation which has been progressively transposed by a D2 tectonic event. A D2 event has developed heterogeneous simple shear in a dextral transpressive context with moderate to strong dipping NE-SW striking foliation; a D3 tectonic event has lead to a sinistral N-S ductile shear characterized by N- to ENE-striking foliation and E-W strike-slip shear corridors and a D4 tectonic event that developed N-S dextral ductile strike-slip deformation. The magnetic study of the pluton, based on the AMS parameters, reveals the coexistence of both paramagnetic (dominated by iron-bearing silicates; 54 % of sites) and ferromagnetic (due to the occurrence of PSD and MD grains of magnetite or other ferromagnetic minerals; 46 % of sites) behaviors. Magnetic foliation shows best poles at 55/82 for the whole pluton, 95/32 in BHG, and 273/83 in BG, and the magnetic lineation trends are mostly NNE-SSW with best lines at 210/8, 198/19, and 36/3, respectively. The trend of the magnetic lineation in BG indicates an S-shape trajectory, suggesting a sinistral sense of shear motion along discrete E-W corridors situated at the northern and southern ends. Kinematic indicators in BG point to a sinistral sense of shear, suggesting its emplacement during the D3 event. The close relationship between K 1 and K 3 points to a syn-kinematic emplacement and crystallization of the Misajé granitic pluton during the Pan-African event, and the tectonic evolution of the study area is considered to be coeval with the tectonic evolution of the trans-Saharan Pan-African belt of eastern Nigeria.

  19. The Alkaline Diet: Is There Evidence That an Alkaline pH Diet Benefits Health?

    PubMed Central

    Schwalfenberg, Gerry K.

    2012-01-01

    This review looks at the role of an alkaline diet in health. Pubmed was searched looking for articles on pH, potential renal acid loads, bone health, muscle, growth hormone, back pain, vitamin D and chemotherapy. Many books written in the lay literature on the alkaline diet were also reviewed and evaluated in light of the published medical literature. There may be some value in considering an alkaline diet in reducing morbidity and mortality from chronic diseases and further studies are warranted in this area of medicine. PMID:22013455

  20. The alkaline diet: is there evidence that an alkaline pH diet benefits health?

    PubMed

    Schwalfenberg, Gerry K

    2012-01-01

    This review looks at the role of an alkaline diet in health. Pubmed was searched looking for articles on pH, potential renal acid loads, bone health, muscle, growth hormone, back pain, vitamin D and chemotherapy. Many books written in the lay literature on the alkaline diet were also reviewed and evaluated in light of the published medical literature. There may be some value in considering an alkaline diet in reducing morbidity and mortality from chronic diseases and further studies are warranted in this area of medicine.

  1. New Constraints on the Origin and Emplacement of Granitoid Magmas in the Waldoboro Pluton Complex, Maine

    NASA Astrophysics Data System (ADS)

    Riley, D. N.; Barton, M.; Osborn, T. G.

    2001-12-01

    The Waldoboro Pluton Complex (WPC) is dominated by two-mica granite and by granodiorite that intruded the Merrimack-Harpswell and St. Croix terranes of Coastal Maine in the late Devonian (ca. 368 Ma). The country rock in the vicinity of the WPC contains numerous layer-parallel granitic veins and contacts between the WPC and the country rock are frequently gradational. These and other observations have been interpreted to indicate in-situ granite formation by melting of metamorphosed (amphibolite facies) wackes of the Bucksport Formation. However, new modal and mineral chemical data make this interpretation unlikely. In particular, hydrous mineral (biotite and amphibole) abundances in the Bucksport Formation are too low to provide the water necessary to generate abundant granite melt at the P-T conditions (0.5 GPa, 670-740 OC) inferred for crystallization of the WPC. Also, Bucksport lithologies are characterized by An-rich plagioclase (29-91 mol%), Ca-rich garnet (0.9-1 afu) and (mostly) Ti-poor biotite (0.1-0.22 afu) and appear to be inappropriate source rocks for peraluminous granitoids. Detailed studies of samples from individual localities reveal large compositional differences between feldspar (>29 versus <10 mol% An), garnet (>25 versus <1 mol% grossular; <15 versus >25 mol% spessartine) and biotite (Mg#<0.12 versus 0.35; Ti>0.36 versus 0.22 afu) in host Bucksport-like country rock and granitic veins. This strongly suggests that the granitic veins represent injected melts rather than migmatite leucosomes and that most garnets in the granitoids are magmatic rather than restitic. Some garnets with Ca-rich cores and Ca-poor rims in the granitoids are probably xenocrysts derived from the country rock and indicate mixing between country rock and magma. Field observations indicate that intrusion of the WPC locally induced melting in pelitic lithologies (eg. those of the Penobscot Formation), and this interpretation is supported by mineral chemical data (feldspars

  2. Evolution of the fluid in the REE-rich pegmatites of the Strange Lake pluton

    NASA Astrophysics Data System (ADS)

    Vasyukova, O.; Williams-Jones, A. E.

    2015-12-01

    Five types of aqueous inclusions are observed in the Mid-proterozoic peralkaline granites and pegmatites of the Strange Lake pluton (Québec-Labrador, Canada). From earliest to latest they are: primary aqueous inclusions associated with melt inclusions (type 1), with CH4 inclusions (types 2 a and b enriched in H2 and higher hydrocarbons respectively), and CO2 inclusions (type 3), primary aqueous inclusions, which show no apparent association with any gas-rich fluid (type 4) and secondary aqueous inclusions associated with mineral pseudomorphs (type 5). The salinity of the fluid decreases from the earliest type 1 (24.1 wt.% NaCl eq.) to type 2 a and b (21.2 and 14.2 wt.% NaCl eq. respectively), to type 3 (10.1 wt.% NaCl eq.) and type 4 inclusions (8.2 wt.% NaCl eq.). The salinity of type 5 inclusions is high, i.e., 16.6 wt.% NaCl eq.. The gas composition changes systematically from CH4 ± H2 in type 1 and 2a to CH4 + higher hydrocarbons in type 2b and to CO2 dominant type 3 inclusions. Most of the inclusions show re-equilibration texures ('implosion' halos). Another typical feature is a tendency to decrepitate at temperatures higher than 140-150 °C. The fluid evolution started with the exsolution of a saline aqueous liquid (~25 wt.% NaCl eq.) from the pegmatitic melt at a temperature of about 400 °C and a pressure around 1100 bars. Further evolution occurred due to cooling (isobaric) and oxidation of the fluid. Early initial oxidation led to formation of higher hydrocarbons by oxidative coupling of methane, and later, full-blown oxidation led to the production of CO2. The CO2 reacted with Na-rich fluid to form nahcolite, which caused a significant decrease in the apparent salinity down to a critical level, below which further oxidation led to an increase in the CO2/CH4 ratio and eventual disappearance of CH4. Isobaric cooling continued down to at least 150-170 °C, at which temperature the CO2 component was consumed to form REE-rich flurocarbonates. Nahcolite

  3. Observations and models of ground deformation from the PLUTONS Project: Lazufre and Uturuncu, Central Andes

    NASA Astrophysics Data System (ADS)

    Henderson, S. T.; Pritchard, M. E.; Elliott, J.; Del Potro, R.; Delgado, F.

    2014-12-01

    The Central Andes Volcanic Zone (CVZ, 14°-28°S) is one of three distinct arc segments the Nazca-South America subduction system. In comparison to the Northern and Southern segments, the CVZ contains approximately 40% of volcanoes active during the Holocene, but less than 20% of documented eruptions. It is therefore surprising that synoptic geodetic observations since 1992 have so far revealed half of the 20 known uplifting volcanoes in the Andes are in the CVZ. Furthermore, an especially high concentration of Miocene ignimbrite deposits (> 10,000 km^3) suggests that in the past large volumes of eruptible magma traversed the crust in this region. We utilize geodetic modeling to address the following questions: What are physically plausible depths, geometries, volumes, and transport mechanisms of intrusions? What are the conditions for plutonism versus volcanism in the CVZ? Our modeling efforts are focused on two of the spatially largest (>2,000 km^2) volcanic uplift events observed globally (Lazufre and Uturuncu). We present a synthesis of InSAR, continuous GPS, and campaign GPS (collected from a small network of sites around Lazurfre in Nov. 2011 and March 2014). New InSAR processing of Envisat ScanSAR (09/2003 - 11/2009), ALOS (02/2007 - 02/2011), and TSX (04/2008 - 07/2014) confirm continued Lazufre uplift rates of approximately 3 cm/yr. Neither TSX data (06/2012 - 07/2014), nor two continuous GPS sites on and around Uturuncu show evidence of continued 1 cm/yr vertical motion since the sites were installed in April 2010. Analytic elastic models of uplift suggest intrusions accumulate in reservoirs in the mid-to-upper crust at both volcanic centers. However, peripheral subsidence at Uturuncu and observations of an extensive low velocity zone motivate the exploration of alternative realistic models that consider the influence of a feeder reservoir in the lower crust and heterogeneous crustal structure. The dual-reservoir model provides a first-order estimate of

  4. The Swansea Plutonic Suite: Synextensional magmatism in the Buckskin and Rawhide Mountains, west-central Arizona

    SciTech Connect

    Bryant, B.; Nealey, L.D. . Denver Federal Center); Wooden, J.L. )

    1993-04-01

    About 200 km[sup 2] of the crystalline rocks exposed below the Buckskin-Rawhide detachment fault in west-central Arizona consists of gabbro to granite of the 20--30 Ma Swansea Plutonic Suite. Gabbro is only locally mylonitized and is intruded by more felsic rocks of the suite. The felsic rocks have a well-developed mylonitic texture and northeast-trending mineral lineation formed by ductily deformed quartz grains and aggregates. The felsic rocks are generally fine to medium grained except for a distinctive porphyritic phase, in which K-feldspar phenocrysts (now porphyroclasts) are as much as 3 cm in diameter. The suite is calcic to alkali calcic, metaluminous to weakly peraluminous (A/CNK = 0.7--1), and has average Th/U of 4.8 and Rb/Sr of 0.11. It shows a wide range in total rare-earth abundances (REE = 132--393 ppm), light to heavy REE enrichment (chondrite normalized [CN] La/Yb = 3--52), and heavy REE enrichment (CN Yb = 2.6--24.5). Intermediate and silicic members are depleted in HREE compared with mafic members, indicating magmatic control by clinopyroxene with or without amphibole or garnet. The porphyritic phase has the highest total REE and HREE abundances. Lead isotope ratios cluster in tight groups between reference lines for the Mohave and central Arizona crustal provinces. Lead in the porphyritic phase is distinctly less radiogenic than in the other phases. U-Pb zircon age of a granite in the suite is 21 [+-] 1.5 Ma. Upper intercept of the discordia line is 1,420 [+-] 54 Ma, indicating that 1,400-Ma rock dominates the source region for at least the felsic rocks of the suite. The suite was emplaced during the beginning and early phases of crustal extension and was probably pulled southwest out from beneath the Colorado Plateau transition zone as extension progressed. Thus the suite may represent roots of subaerial volcanic centers at the margin of the transition zone, which chemically resemble rocks of the suite in major-element chemistry.

  5. Characteristics of Young Rhyolites at Taupo, New Zealand: Implications for the Sub-Surface Plutonic System

    NASA Astrophysics Data System (ADS)

    Wilson, C. J.; Charlier, B. L.

    2007-12-01

    The young history of Taupo volcano captures the growth and destruction in the 26.5 ka ca. 530 km3 Oruanui eruption of a large rhyolitic magma body, together with the subsequent rejuvenation of magma sources below the volcano. Integration of field information with petrological and isotopic studies at the whole-pumice and single- crystal scales provide a picture of this history. Several important contrasts are inferred to exist between Taupo and comparably-sized, long-lived silicic foci such at Long Valley and in the Bishop Tuff. At Taupo the following are demonstrable. 1. Even in crystal-poor rhyolites like the Oruanui, many grains are inherited antecrysts or xenocrysts. The Oruanui crystal-poor rhyolite body was an open system, with influxes of crystals (plus melt) from remobilised older crystal mush, melted metasedimentary country rocks and plutonics, and crystal-poor basaltic to andesitic magmas. 2. All the Taupo rhyolites were well mixed prior to eruption, and there are no gradients in the eruption products to suggest that the holding chamber(s) were stratified to any extent. 3. Mafic magmas rose into, interacted with, and ponded on the floors of crystal-poor rhyolite in the Oruanui and Waimihia (3.5 ka) examples, again implying that the chamber floor was sharply defined, not a gradual progression down into a more crystal- rich root zone. 4. Pre-Oruanui activity involved contrasting magma types being generated simultaneously, but erupting from geographically separated vents. Post-Oruanui activity has seen (subtly) contrasting magma groups being erupted from vents in the same geographic area, but separated in time. The Oruanui and post-Oruanui magmas are different and do not appear to be related by consanguinity or by mixing - the Oruanui eruption effectively destroyed its magma body. These features are consistent with rhyolite magma generation at Taupo that is exceptionally fast, driven by high fluxes of mafic magmas into a highly heterogeneous crustal melange

  6. Negative Electrode For An Alkaline Cell

    DOEpatents

    Coco, Isabelle; Cocciantelli, Jean-Michel; Villenave, Jean-Jacques

    1998-07-14

    The present invention concerns a negative electrode for an alkaline cell, comprising a current collector supporting a paste containing an electrochemically active material and a binder, characterized in that said binder is a polymer containing hydrophilic and hydrophobic groups, said polymer being selected from an acrylic homopolymer, copolymer and terpolymer, an unsaturated organic acid copolymer and an unsaturated acid anhydride copolymer.

  7. Alkaline electrochemical cells and method of making

    NASA Technical Reports Server (NTRS)

    Hoyt, H. E.; Pfluger, H. L. (Inventor)

    1970-01-01

    Equilibrated cellulose ether membranes of increased electrolytic conductivity for use as separators in concentrated alkaline electrochemical cells are investigated. The method of making such membranes by equilibration to the degree desired in an aqueous alkali solution mantained at a temperature below about 10 C is described.

  8. Kinetics of the alkaline hydrolysis of nitrocellulose.

    PubMed

    Christodoulatos, C; Su, T L; Koutsospyros, A

    2001-01-01

    Cellulose nitrate (nitrocellulose) is an explosive solid substance used in large quantities in various formulations of rocket and gun propellants. Safe destruction of nitrocellulose can be achieved by alkaline hydrolysis, which converts it to biodegradable products that can then be treated by conventional biological processes. The kinetics of the alkaline hydrolysis of munitions-grade nitrocellulose in sodium hydroxide solutions were investigated in completely mixed batch reactors. Experiments were conducted using solutions of alkaline strength ranging from 0.1 to 15% by mass and temperatures in the range of 30 to 90 degrees C. Regression analysis of the kinetic data revealed that alkaline hydrolysis of nitrocellulose is of the order 1.0 and 1.5 with respect to nitrocellulose and hydroxide concentration, respectively. The activation energy of the hydrolysis reaction was found to be 100.9 kJ/mol with a preexponential Arrhenius constant of 4.73 x 10(13). Nitrite and nitrate, in a 3:1 ratio, were the primary nitrogen species present in the posthydrolysis solution. The kinetic information is pertinent to the development and optimization of nitrocellulose chemical-biological treatment systems.

  9. MERCURIC CHLORIDE CAPTURE BY ALKALINE SORBENTS

    EPA Science Inventory

    The paper gives results of bench-scale mechanistic studies of mercury/sorbent reactions that showed that mercuric chloride (HgC12) is readily adsorbed by alkaline sorbents, which may offers a less expensive alternative to the use of activated carbons. A laboratory-scale, fixed-b...

  10. ISSUES WITH ALKALINE TREATMENT OF SLUDGE

    EPA Science Inventory

    This presentation begins with a discussion of the use of lime and other alkaline materials from the very earliest times to the present for killing bacteria, viruses and parasites and for controlling odors in wastewaters and sludge. It answers the question "How did EPA arrive at i...

  11. Petrography and mineral chemistry of the composite Deboullie Pluton, northern Maine, USA: implications for the genesis of Cu-Mo mineralization

    USGS Publications Warehouse

    Loferski, P.J.; Ayuso, R.A.

    1995-01-01

    Biotite and apatite mineral chemistry, particularly halogen abundances and ratios, are used to investigate the relation of the two contrasting parts of the Deboullie composite pluton (syenite-granodiorite) located in northern Maine. Biotite mineral chemistry helps to classify the weakly developed porphyry-style mineralization (Cu-Mo) associated with syenitic rocks of the Deboullie pluton. Biotite and apatite occur within the matrix of the rocks and within small multiphase inclusions hosted by clinopyroxene. The inclusions are interpreted to be crystallized melt inclusions rather than solid inclusions, that were trapped by clinopyroxene during growth. The multiphase inclusions consist of K-feldspar + quartz + biotite + apatite + magnetite. On a regional scale, biotite compositions from granitic plutons in Maine do not vary in a systematic manner. -from Authors

  12. 40Ar/39Ar and U-Pb Ages and Isotopic Data for Oligocene Ignimbrites, Calderas, and Granitic Plutons, Southern Stillwater Range and Clan Alpine Mountains: Insights into the Volcanic-Plutonic Connection and Crustal Evolution in Western Nevada

    NASA Astrophysics Data System (ADS)

    John, D. A.; Watts, K. E.; Henry, C.; Colgan, J. P.; Cousens, B.

    2014-12-01

    Calderas in the southern Stillwater Range (SSR) and Clan Alpine Mountains (CAM) were formed during the mid-Tertiary ignimbrite flareup and subsequently tilted (40->90°) by large-magnitude extension. New geologic mapping, geochemistry, and 40Ar/39Ar and SHRIMP U-Pb zircon dating document 2 periods of magmatism resulting in 4 nested calderas and related granitoid plutons in sections up to 10 km thick. The first period included pre-caldera rhyolite lava domes (30(?) Ma), ~5 km of pre- and post-collapse intermediate lavas and rhyolite tuff that filled the Job Canyon caldera (~29.4 to 28.8 Ma), and the >4-5 km thick, geochemically similar IXL pluton (28.9±0.4 Ma) that intruded the Job Canyon caldera. The second period included pre-caldera rhyolite lava domes and dikes (~25.5 Ma) and 3 ignimbrite units in 3 calderas: tuff of the Louderback Mountains (low-silica rhyolite; ≥600 m thick; ~25.2 Ma); tuff of Poco Canyon (high-silica rhyolite; up to 4.3 km thick; 25.27±0.05 Ma); and ≥2000 km3 tuff of Elevenmile Canyon (trachydacite to rhyolite; up to 4.5 km thick; 25.12±0.01 Ma). The composite Freeman Creek pluton (granite, 24.8±0.4 Ma; granodiorite, 25.0±0.2 Ma) and Chalk Mountain rhyolite porphyry (25.2±0.2 Ma) and granite (24.8±0.3 Ma) plutons intruded the Poco Canyon and Elevenmile Canyon calderas. Early (30 Ma) rhyolites have the least radiogenic compositions (Sri~0.7040), whereas other units are relatively homogeneous (Sri~0.7050, ENd~0.0). Oxygen isotope compositions for SSR and CAM calderas are highly variable (d18Oquartz=5.6-8.2‰, d18Osanidine=5.5-7.0‰, d18Ozircon= 4.1-6.3‰), corresponding to a magmatic range of 5.7-7.9‰. U-Pb dating of zircons indicates homogeneous age populations and few/no xenocrysts and antecrysts. These data show that (1) thick plutons (>2-5 km) underlie compositionally and temporally related caldera-filling ignimbrites, (2) caldera-forming cycles are isotopically variable, requiring divergent magmatic sources in relatively

  13. A vibrational spectroscopic study of the phosphate mineral rimkorolgite (Mg,Mn2+)5(Ba, Sr)(PO4)4·8H2O from Kovdor massif, Kola Peninsula, Russia

    NASA Astrophysics Data System (ADS)

    Frost, Ray L.; López, Andrés; Theiss, Federick L.; Aarão, Guilherme Marcos; Scholz, Ricardo

    2014-11-01

    We have studied aspect of the molecular structure of the phosphate mineral rimkorolgite from Zheleznyi iron mine, Kovdor massif, Kola Peninsula, Russia, using SEM with EDX and vibrational spectroscopy. Qualitative chemical analysis shows a homogeneous phase, composed by P, Mg, Ba, Mn and Ca. Small amounts of Si were also observed. An intense Raman peak at 975 cm-1 is assigned to the PO43- ν1 symmetric stretching mode. The Raman band at 964 cm-1 is attributed to the HPO42- ν1 symmetric stretching vibration. Raman bands observed at 1016, 1035, 1052, 1073, 1105 and 1135 cm-1 are attributed to the ν3 antisymmetric stretching vibrations of the HPO42- and PO43- units. Complexity in the spectra of the phosphate bending region is observed. The broad Raman band at 3272 cm-1 is assigned to the water stretching vibration. Vibrational spectroscopy enables aspects on the molecular structure of rimkorolgite to be undertaken.

  14. Alkaline earth metal catalysts for asymmetric reactions.

    PubMed

    Kobayashi, Shū; Yamashita, Yasuhiro

    2011-01-18

    The group 2 alkaline earth metals calcium (Ca), strontium (Sr), and barium (Ba) are among the most common elements on Earth, abundant in both the sea and the Earth's crust. Although they are familiar in our daily lives, their application to organic synthesis has, so far, been limited. Some particularly useful properties of these elements include (i) low electronegativity, (ii) a stable oxidation state of +2, meaning that they can potentially form two covalent bonds with anions, and (iii) the ability to occupy a variety of coordination sites due to their large ionic radius. Furthermore, the alkaline earth metals, found between the group 1 and group 3 elements, show mild but significant Lewis acidity, which can be harnessed to control coordinative molecules via a Lewis acid-base interaction. Taken together, these characteristics make the metals Ca, Sr, and Ba very promising components of highly functionalized acid-base catalysts. In this Account, we describe the development of chiral alkaline earth metal catalysts for asymmetric carbon-carbon bond-forming reactions. Recently prepared chiral alkaline earth metal complexes have shown high diastereo- and enantioselectivities in fundamental and important chemical transformations. We chose chiral bisoxazoline (Box) derivatives bearing a methylene tether as a ligand for chiral modification. These molecules are very useful because they can covalently coordinate to alkaline earth metals in a bidentate fashion through deprotonation of the tether portion. It was found that chiral calcium-Box complexes could successfully promote catalytic asymmetric 1,4-addition and [3 + 2] cycloaddition reactions with high diastereo- and enantioselectivities. Both the calcium-Box complexes and chiral strontium-bis-sulfonamide and chiral barium-BINOLate complexes could catalyze asymmetric 1,4-addition reactions with high enantioselectivities. Furthermore, we designed a calcium-neutral coordinative ligand complex as a new type of chiral alkaline

  15. Crystal structure of alkaline cellulase K: insight into the alkaline adaptation of an industrial enzyme.

    PubMed

    Shirai, T; Ishida, H; Noda, J; Yamane, T; Ozaki, K; Hakamada, Y; Ito, S

    2001-07-27

    The crystal structure of the catalytic domain of alkaline cellulase K was determined at 1.9 A resolution. Because of the most alkaliphilic nature and it's highest activity at pH 9.5, it is used commercially in laundry detergents. An analysis of the structural bases of the alkaliphilic character of the enzyme suggested a mechanism similar to that previously proposed for alkaline proteases, that is, an increase in the number of Arg, His, and Gln residues, and a decrease in Asp and Lys residues. Some ion pairs were formed by the gained Arg residues, which is similar to what has been found in the alkaline proteases. Lys-Asp ion pairs are disfavored and partly replaced with Arg-Asp ion pairs. The alkaline adaptation appeared to be a remodeling of ion pairs so that the charge balance is kept in the high pH range.

  16. Increasing background seismicity and dynamic triggering behaviors with nearby mining activities around Fangshan Pluton in Beijing, China

    NASA Astrophysics Data System (ADS)

    Wang, Weijun; Meng, Xiaofeng; Peng, Zhigang; Chen, Qi-Fu; Liu, Ning

    2015-08-01

    Dynamic triggering in western Fangshan Pluton, Beijing, China, has been repeatedly identified, but previous studies are limited by sparse seismic station coverage. Here we systematically analyze continuous waveforms recorded by both permanent stations and a temporary seismic network 40 days before and after the 11 March 2011 Mw 9.1 Tohoku-Oki and the 14 April 2012 Mw 8.6 Indian Ocean earthquakes. We first build a template database using a short-term average to long-term average method. Next, we apply the matched filter technique that cross correlates the template waveforms with continuous data to detect additional seismic events. Overall, we detect 1956 and 950 seismic events around the Tohoku-Oki and Indian Ocean main shocks, respectively. Most detected events are shallow (<5 km) and clustered at Beiling Syncline in western Fangshan Pluton, which is adjacent to a running coalmine. Seven and 10 events are detected during the large-amplitude surface waves of the two main shocks, respectively, but no similar burst is detected following their major foreshock and aftershocks. Multiple statistical tests indicate that the short-term bursts after the two main shocks are dynamically triggered. We suggest that mining-related activities may perturb the subsurface stress conditions and hence make the region more susceptible for dynamic triggering than other places.

  17. Geochemistry and petrogenesis of anorogenic basic volcanic-plutonic rocks of the Kundal area, Malani Igneous Suite, western Rajasthan, India

    NASA Astrophysics Data System (ADS)

    Krishnakanta Singh, A.; Vallinayagam, G.

    2004-12-01

    The Kundal area of Malani Igneous Suite consists of volcano-plutonic rocks. Basalt flows and gabbro intrusives are associated with rhyolite. Both the basic rocks consist of similar mineralogy of plagioclase, clinopyroxene as essential and Fe-Ti oxides as accessories. Basalt displays sub-ophitic and glomeroporphyritic textures whereas gabbro exhibits sub-ophitic, porphyritic and intergrannular textures. They show comparable chemistry and are enriched in Fe, Ti and incompatible elements as compared to MORB/CFB. Samples are enriched in LREE and slightly depleted HREE patterns with least significant positive Eu anomalies. Petrographical study and petrogenetic modeling of [Mg]-[Fe], trace and REE suggest cogenetic origin of these basic rocks and they probably derived from Fe-enriched source with higher Fe/Mg ratio than primitive mantle source. Thus, it is concluded that the basic volcano-plutonic rocks of Kundal area are the result of a low to moderate degree (< 30%) partial melting of source similar to picrite/komatiitic composition. Within plate, anorogenic setting for the basic rocks of Kundal area is suggested, which is in conformity with the similar setting for Malani Igneous Suite.

  18. Paleozoic subduction complex and Paleozoic-Mesozoic island-arc volcano-plutonic assemblages in the northern Sierra terrane

    USGS Publications Warehouse

    Hanson, Richard E.; Girty, Gary H.; Harwood, David S.; Schweickert, Richard A.

    2000-01-01

    This field trip provides an overview of the stratigraphic and structural evolution of the northern Sierra terrane, which forms a significant part of the wall rocks on the western side of the later Mesozoic Sierra Nevada batholith in California. The terrane consists of a pre-Late Devonian subduction complex (Shoo Fly Complex) overlain by submarine arc-related deposits that record the evolution of three separate island-arc systems in the Late Sevonian-Early Mississippian, Permian, and Late Triassic-Jurassic. The two Paleozoic are packages and the underlying Shoo Fly Complex have an important bearing on plate-tectonic processes affecting the convergent margin outboard of the Paleozoic Cordilleran miogeocline, although their original paleogeographic relations to North America are controversial. The third arc package represents an overlap assemblage that ties the terrane to North America by the Late Triassic and helps constrain the nature and timing of Mesozoic orogenesis. Several of the field-trip stops examine the record of pre-Late Devonian subduction contained in the Shoo Fly Complex, as well as the paleovolcanology of the overlying Devonian to Jurassic arc rocks. Excellent glaciated exposures provide the opportunity to study a cross section through a tilted Devonian volcano-plutonic association. Additional stops focus on plutonic rocks emplaced during the Middle Jurassic arc magmatism in the terrane, and during the main pulse of Cretaceous magmatism in the Sierra Nevada batholith to the east.

  19. Isotopic studies of the Eye-Dashwa Lakes pluton and the long-term integrity of whole-rock and mineral systems

    USGS Publications Warehouse

    Peterman, Zell E.; Kamineni, D.C.

    1990-01-01

    This report presents results of isotopic studies of the Eye-Dashwa Lakes pluton, located near Atikokan, Ontario. Suites of pristine 'unaltered' and 'highly altered' core samples from deep boreholes were used to study Rb-Sr, U-Th-Pb and Sr-Nd systematics, whole-rock Pb isotopes and fission track dating of apatite. The results have been used to investigate natural analogues for radionuclide migration in the geosphere, the tectonic stability of the pluton and the extent of water-rock interaction in fracture zones.

  20. The link between volcanism and plutonism in epizonal magma systems; high-precision U-Pb zircon geochronology from the Organ Mountains caldera and batholith, New Mexico

    NASA Astrophysics Data System (ADS)

    Rioux, Matthew; Farmer, G. Lang; Bowring, Samuel A.; Wooton, Kathleen M.; Amato, Jeffrey M.; Coleman, Drew S.; Verplanck, Philip L.

    2016-02-01

    The Organ Mountains caldera and batholith expose the volcanic and epizonal plutonic record of an Eocene caldera complex. The caldera and batholith are well exposed, and extensive previous mapping and geochemical analyses have suggested a clear link between the volcanic and plutonic sections, making this an ideal location to study magmatic processes associated with caldera volcanism. Here we present high-precision thermal ionization mass spectrometry U-Pb zircon dates from throughout the caldera and batholith, and use these dates to test and improve existing petrogenetic models. The new dates indicate that Eocene volcanic and plutonic rocks in the Organ Mountains formed from ~44 to 34 Ma. The three largest caldera-related tuff units yielded weighted mean 206Pb/238U dates of 36.441 ± 0.020 Ma (Cueva Tuff), 36.259 ± 0.016 Ma (Achenback Park tuff), and 36.215 ± 0.016 Ma (Squaw Mountain tuff). An alkali feldspar granite, which is chemically similar to the erupted tuffs, yielded a synchronous weighted mean 206Pb/238U date of 36.259 ± 0.021 Ma. Weighted mean 206Pb/238U dates from the larger volume syenitic phase of the underlying Organ Needle pluton range from 36.130 ± 0.031 to 36.071 ± 0.012 Ma, and the youngest sample is 144 ± 20 to 188 ± 20 ka younger than the Squaw Mountain and Achenback Park tuffs, respectively. Younger plutonism in the batholith continued through at least 34.051 ± 0.029 Ma. We propose that the Achenback Park tuff, Squaw Mountain tuff, alkali feldspar granite and Organ Needle pluton formed from a single, long-lived magma chamber/mush zone. Early silicic magmas generated by partial melting of the lower crust rose to form an epizonal magma chamber. Underplating of the resulting mush zone led to partial melting and generation of a high-silica alkali feldspar granite cap, which erupted to form the tuffs. The deeper parts of the chamber underwent continued recharge and crystallization for 144 ± 20 ka after the final eruption. Calculated magmatic

  1. The sulphate-reduction alkalinity pump tested

    NASA Astrophysics Data System (ADS)

    Meister, Patrick; Petrishcheva, Elena

    2016-04-01

    Carbonate precipitation has been suggested to be induced by alkalinity increase during sulphate reduction under anoxic conditions. This mechanism may explain the formation of carbonate deposits in shallow marine environments, either within a redox stratified sediment inhabited by phototrophic microbial mats or in shallow water within the photic zone where sulphidic water is upwelling onto the shelf. The alkalinity pump may work as long as the sulphide is not reoxidized to sulphate, a process that would acidify the surrounding. The alkalinity effect of sulphate reduction was recently tested by Aloisi (2008) for microbial mats using a model approach. He found that sulphate reduction does not significantly increase or even decrease carbonate saturation and is unlikely to have played a significant role through Earth history. The model considers many environmental factors, including the effect of carbonate precipitation itself on the carbonate equilbrium and on the alkalinity. We used a modified version of Aloisi's (2008) model to simulate the saturation states of aragonite, calcite and dolomite without the effects of carbonate precipitation. This is necessary to evaluate the effect of microbial metabolisms exclusively on carbonate saturation, since carbonate precipitation is only the consequence, but not the cause of oversaturation. First results show that the saturation state is increased in the zone of phototrophic CO2 uptake. In contrast, the saturation state is strongly decreased in the zone where dissolved oxygen overlaps with dissolved sulphide. Aerobic sulphide oxidation consumes most of the HS- and dissipates most of the alkalinity produced in the sulphate reduction zone below. Hence, our results are consistent with the findings of Aloisi (2008), and they even more clearly show that sulphate reduction does not induce carbonate precipitation nor contributes to carbonate precipitation in combination with phototrophic CO2 uptake. The alkalinity effect of sulphate

  2. [Leucocyte alkaline phosphatase in normal and pathological pregnancy (author's transl)].

    PubMed

    Stark, K H; Zaki, I; Sobolewski, K

    1981-01-01

    The activities of leucocyte alkaline phosphatase were determined in 511 patients with normal and pathological pregnancy. Mean values were compared and the enzyme followed up, and the conclusion was drawn that leucocyte alkaline phosphatase was no safe indicator of foetal condition. No direct relationship were found to exist between leucocyte alkaline phosphatase, total oestrogens, HSAP, HLAP, HPL, and oxytocinase.

  3. A Fresh Plutonic Igneous Angrite Containing Grain Boundary Glass From Tamassint, Northwest Africa

    NASA Astrophysics Data System (ADS)

    Irving, A. J.; Kuehner, S. M.; Rumble, D.

    2006-12-01

    Tamassint Angrite: A small fragmented stone found in June 2006 south of Tamassint oasis in the Morocco-Algeria border region represents a new type of angrite lithology, unlike the coarse grained metamorphic or fine grained "basaltic" to quench-textured examples known previously. This extremely fresh, fusion-crusted specimen has a coarse grained (0.6-12 mm) plutonic igneous cumulate texture, and is composed of Al-Ti-rich clinopyroxene (33.4%), pure anorthite (28.6%), Ca-rich olivine (18.7%) with prominent exsolution lamellae (10-50 μm wide) of kirschsteinite, ulvöspinel (18.5%), and accessory glass, troilite and metal. Subhedral anorthite grains are partially enclosed within larger ulvöspinel grains. Mineral compositions are as follows: clinopyroxene (Fs20.8-33.3Wo53-54.9, Al2O3 = 5.7 to 9.4 wt.%, TiO2 = 0.9 to 2.9 wt.%, FeO/MnO = 85-278), olivine (Fa72.6-74.7Ln3.5-3.6, CaO = 2.1 wt.%, FeO/MnO = 70-87), kirschsteinite (Fa44.7-45.4Ln46-47.2, FeO/MnO = 73-82), ulvöspinel (TiO2 = 27.6 wt.%, Al2O3 = 5.5 wt.%). Reintegration of the kirschsteinite lamellae gives a pre-exsolution olivine composition of Fa68.1Ln12.2 with 7.3 wt.% CaO. Present along grain boundaries (notably between anorthite and ulvöspinel) are narrow (5-20 μm) curvilinear zones of glass associated with secondary kirschteinite, clinopyroxene and olivine (which show similar curvilinear morphology and truncate kirschsteinite lamellae). Glass compositions plot close to a mixing line between anorthite and ulvöspinel. Replicate oxygen isotopic analyses of acid-washed minerals by laser fluorination gave δ18O = 3.881, 3.845, δ17O = 1.967, 1.927, Δ17O = -0.0745, -0.0956 per mil (for TFL slope = 0.526). Comparison With NWA 2999: We previously showed [1] that angrite Northwest Africa 2999 is a metamorphically annealed breccia with distinctive symplectites and coronas representing forward and reverse versions of the same solid state reaction. We suggested that these disequilibrium textures required burial

  4. Surfactant-enhanced alkaline flooding field project

    SciTech Connect

    French, T.R.

    1991-10-01

    The Tucker sand of Helper (KS) field is a candidate for surfactant-enhanced alkaline flooding. The geology of the Helper site is typical of many DOE Class I reservoirs. The Tucker sand of Helper field was deposited in a fluvial dominated deltaic environment. Helper oil can be mobilized with either chemical system 2 or chemical system 3, as described in this report. Oil fields in the Gulf Coast region are also good candidates for surfactant-enhanced alkaline flooding. The results from laboratory tests conducted in Berea sandstone cores with oil brine from Helper (KS) field are encouraging. The crude oil is viscous and non-acidic and, yet, was mobilized by the chemical formulations described in this report. Significant amounts of the oil were mobilized under simulated reservoir conditions. The results in Berea sandstone cores were encouraging and should be verified by tests with field core. Consumption of alkali, measured with field core, was very low. Surfactant loss appeared to be acceptable. Despite the good potential for mobilization of Helper oil, certain reservoir characteristics such as low permeability, compartmentalization, and shallow depth place constraints on applications of any chemical system in the Tucker sand. These constraints are typical of many DOE Class I reservoirs. Although Hepler field is not a perfect reservoir in which to apply surfactant- enhanced alkaline flooding, Hepler oil is particularly amenable to mobilization by surfactant-enhanced alkaline systems. A field test is recommended, dependent upon final evaluation of well logs and cores from the proposed pilot area. 14 refs., 21 figs., 10 tabs.

  5. The alkaline earth intercalates of molybdenum disulfide

    NASA Technical Reports Server (NTRS)

    Somoano, R. B.; Hadek, V.; Rembaum, A.; Samson, S.; Woollam, J. A.

    1975-01-01

    Molybdenum disulfide has been intercalated with calcium and strontium by means of the liquid ammonia technique. Chemical, X-ray, and superconductivity data are presented. The X-ray data reveal a lowering of crystal symmetry and increase of complexity of the structure upon intercalation with the alkaline earth metals. The Ca and Sr intercalates start to superconduct at 4 and 5.6 K, respectively, and show considerable anisotropy regarding the critical magnetic field.

  6. Alkaline earth cation extraction from acid solution

    DOEpatents

    Dietz, Mark; Horwitz, E. Philip

    2003-01-01

    An extractant medium for extracting alkaline earth cations from an aqueous acidic sample solution is described as are a method and apparatus for using the same. The separation medium is free of diluent, free-flowing and particulate, and comprises a Crown ether that is a 4,4'(5')[C.sub.4 -C.sub.8 -alkylcyclohexano]18-Crown-6 dispersed on an inert substrate material.

  7. Oxidation catalysts on alkaline earth supports

    DOEpatents

    Mohajeri, Nahid

    2017-03-21

    An oxidation catalyst includes a support including particles of an alkaline earth salt, and first particles including a palladium compound on the support. The oxidation catalyst can also include precious metal group (PMG) metal particles in addition to the first particles intermixed together on the support. A gas permeable polymer that provides a continuous phase can completely encapsulate the particles and the support. The oxidation catalyst may be used as a gas sensor, where the first particles are chemochromic particles.

  8. Inhibition of Alkaline Phosphatase by Several Diuretics

    DTIC Science & Technology

    1980-01-01

    August 20th, 1979) . . Summary , . Acetazolamide, furosemide, ethacrynic acid and chlorothiazide, diuretics of considerable structural diversity, inhibit...Ki is calculated to be 8.4, 7.0, 2.8 and 0.1 mmol/l for acetazolamide, furosemide, ethacrynic acid and chlorothiazide, respectively. Chlorothiazide...is a much more potent inhibitor of alkaline phos- phatase than the other three diuretics. The combination of ethacrynic acid and cysteine, itself an

  9. Alkaline flooding for enhanced oil recovery

    SciTech Connect

    Gittler, W.E.

    1983-09-01

    There are over 12 active projects of varying size using one of 3 major types of alkaline agents. These include sodium silicate, caustic soda, and soda ash. Among the largest pilots currently is the THUMS project in the Wilmington field, California. Plans called for the injection of a 4% weight concentration of sodium orthosilicate over a 60% PV. Through the first 3 yr, over 27 million bbl of chemicals have been injected. Gulf Oil is operating several alkaline floods, one of which is located off shore in the Quarantine Bay field, Louisiana. In this pilot, sodium hydroxide in a weight concentration of 5 to 12% is being injected. Belco Petroleum Corp. has reported that their pilot operating in the Isenhour Unit in Wyoming is using a .5% weight concentration of soda ash in conjunction with a polymer. Other uses for alkaline agents in chemical flooding include the use of silicate as a preflush or sacrificial agent in micellar/polymer and surfactant recovery systems. In addition, caustic has been tested in the surface-mixed caustic emulsion process while orthosilicate has been tested in a recovery method known as mobility-controlled caustic floods.

  10. Alkaline phosphatase of Physarum polycephalum is insoluble.

    PubMed

    Furuhashi, Kiyoshi

    2008-02-01

    The plasmodia of Physarum polycephalum grow as multinucleated cells in the presence of sufficient humidity and nutriment. Under non-illuminating conditions, stresses such as low temperature or high concentrations of salts transform the plasmodia into spherules whereas dehydration induces sclerotization. Some phosphatases including protein phosphatase and acid phosphatase have been purified from the plasmodia, but alkaline phosphatase remains to be elucidated. Phosphatase of the plasmodia, spherules and sclerotia was visualized by electrophoresis gel-staining assay using 5-bromo-4-chloro-3-indolyl phosphate. Insoluble fractions of the sclerotia were abundant in phosphatase activity. The phosphatase which was extracted by nonionic detergent was subjected to column chromatography and preparative electrophoresis. Purified phosphatase showed the highest activity at pH 8.8, indicating that this enzyme belongs to alkaline phosphatase. The apparent molecular mass from sodium dodecyl sulfate-polyacrylamide gel electrophoresis under non-reducing condition was estimated to be 100 kDa whereas that under reducing was 105 kDa. An amount of 1% sodium dodecyl sulfate or 0.5 M NaCl had no effects on the activity although the phosphatase showed heat instability, Mg(2+)-dependency and sensitivity to 2-glycerophosphate or NaF. The extracting conditions and enzymatic properties suggest that this alkaline phosphatase which is in a membrane-bound form plays important roles in phosphate metabolism.

  11. The Paradox of the Axial Melt Lens: Petrology and Geochemistry of the Upper Plutonics at Hess Deep

    NASA Astrophysics Data System (ADS)

    Lissenberg, C. J.; Loocke, M. P.; MacLeod, C. J.

    2014-12-01

    The axial melt lens (AML) is a steady-state magma-rich body located at the dyke-gabbro transition at intermediate- and fast-spreading ridges. It is widely believed to be the reservoir from which mid-ocean ridge basalt (MORB) is erupted. The paradox of the axial melt lens is that the plutonic rocks that occur at this level are far too evolved to be in equilibrium with MORB, which is basaltic by definition; hence, the plutonic and volcanic records do not match. We explore this paradox by study of the first comprehensive sample suite of the uppermost plutonics of a fast-spreading ridge, taken by remotely-operated vehicle from the Hess Deep rift during cruise JC21. 23 samples (8 dolerites, 14 gabbronorites, and 1 gabbro) were collected from a section containing the transition from the uppermost gabbroic section into sheeted dykes. We present the results of a detailed petrographic and microanalytical investigation of these samples. They are dominated by evolved, varitextured (both in hand sample and thin section) oxide gabbronorites; olivine occurs in only one sample. A preponderance of the samples have positive Eu/Eu* and Sr/Sr*, indicating a cumulate origin. However, the minerals have evolved compositions, and are in equilibrium with melts significantly more evolved than East Pacific Rise MORB. Furthermore, the trace element contents of clinopyroxene differ significantly from clinopyroxene in equilibrium with MORB, being more enriched in incompatible elements. To account for both the evidence of derivation of MORB from the AML and the evolved nature of its rock record, we posit that the AML must be fed by melts on two different timescales: continual low-volume feeding by evolved interstitial melt from the cumulus pile below is augmented episodically by delivery of high volumes of more primitive melt. The latter episodes may trigger eruptions; hence the primitive melts are held in the magma chamber for only short periods, and erupt on the seafloor before significant

  12. Constraining the magma flow record based on magmatic and magnetic data in La Gloria Pluton, central Chile

    NASA Astrophysics Data System (ADS)

    Gutierrez, F. J.; Payacán, I.; Gelman, S. E.; Bachmann, O.; Creative Physical Petrology Team

    2013-05-01

    The magmatic origin of the anisotropy of magnetic susceptibility (AMS) is examined in comparison with magmatic anisotropy data in a small, shallow, silicic magma reservoir in the upper crust. La Gloria Pluton (LGP) is a 10 Ma granodiorite/quartz monzonite of about 250 km3 located in the southern Andes, central Chile. LGP represents a particularly simple case of a silicic intrusion that was assembled in only a few pulses and cooled over a short time interval. Hornblende, biotite and minor magnetite are ubiquitous mafic phases. The AMS tensor indicates that magnetic fabric has an oblate shape (i.e. magnetic foliation is higher than magnetic lineation). Lineations are weak (values up to 1.05), have a N-NW trend with a nearly horizontal dip and are interpreted to represent axisymmetric convection parallel to the main pluton elongation. Foliations are more pronounced (values up to 1.14), having NW trends and dips that vary gradually from vertical at the walls, to horizontal at the center and near the roof of the chamber. We selected 12 samples from AMS sites to obtain petrographic data (well-distributed throughout the pluton, containing samples from the walls, the center and the roof of LGP), and then, determine the magmatic fabric (anisotropy, lineation, foliation). We made 3 oriented thin sections per sample oriented with the AMS. Magmatic anisotropy data were obtained by measuring mineral length, width and orientation in photomicrographs of the three main planes of the AMS tensor, producing 3-D mineral data which were collected for plagioclase and amphibole + bitotite independently. For each site, a Bingham distribution with 95% of confidence is used to determine the mean mineral orientations and their angle difference with the AMS axes. Magmatic anisotropy tensor and rotations with respect to the AMS tensor are determined using both eigenvalues and minimization algorithms. Preliminary results indicate that crystals are coherently oriented in both mineral groups, and

  13. Polytopic Vector Analysis (PVA) modelling of whole-rock and apatite chemistry from the Karkonosze composite pluton (Poland, Czech Republic)

    NASA Astrophysics Data System (ADS)

    Lisowiec, Katarzyna; Słaby, Ewa; Förster, Hans-Jürgen

    2015-08-01

    This study presents a novel approach for analysing the magma evolution path in composite plutons, applying the so-termed Polytopic Vector Analysis (PVA) to whole-rock and apatite chemistry. As an example of a multiphase magmatic body the Karkonosze granitoid pluton was chosen, which formed by a combination of magma mixing and fractional crystallization of two distinct melts - granitic crust-derived and lamprophyric mantle-derived. The goal was to model end-member magma compositions recorded by apatite and to estimate to what extent these end-members interacted with each other. Although using single minerals as proxies to magma compositions is tricky, the studied apatite well reflects the compositional trends within the magma (e.g., decreasing LREE/Y ratios, varying halogen content, increasing Mn and Na concentrations). The results of PVA simulations for whole-rock geochemistry demonstrate a model similar to that constrained from previous studies. Apart from the main trend of mixing between a felsic (~ 80 wt.% SiO2) and a mafic (~ 53 wt.% SiO2) end-member (EM), an additional process has been recognized, representing most probably the continuous evolution of the mafic end-member, responsible for the compositional diversity of some rocks. One felsic (REE-poor, Mn-F-rich) and one mafic (Cl-Sr-Si-REE-rich) apatite end-members were recognized, whereas the third one represents most probably a fluid component (enriched in Si, Y, Ce and Nd), present at all magmatic stages, however, most prominent during the late stage. The widest range of EM proportions and the highest contribution of the mafic EM are displayed by apatites from the early stage. During the middle and late stages, the apatites present a narrow range of EM proportions, with almost all apatites bearing a felsic signature. This pattern reflects the progressive homogenization of the system. Although the PVA method applied to mineral chemistry poses some limitations, it may provide a more detailed image of the

  14. Strain Localization Within a Syn-Tectonic Pluton in a Back-Arc Extensional Context: the Naxos granodiorite (Cyclades, Greece)

    NASA Astrophysics Data System (ADS)

    Bessiere, Eloïse; Rabillard, Aurélien; Arbaret, Laurent; Jolivet, Laurent; Augier, Romain; Menant, Armel

    2016-04-01

    Naxos Island is part of the central Cyclades (Aegean Sea, Greece) where a series of migmatite-cored metamorphic domes were exhumed below large-scale detachment systems during a Cenozoic back-arc extension. On Naxos, the Miocene exhumation history of the high-temperature metamorphic dome was notably achieved through two anastomosing and closely spaced top-to-the-north detachments belonging to the Naxos-Paros detachment system. According to previous contributions, the late exhumation stages were accompanied by the emplacement of a syn-kinematic I-type granodiorite that intruded a ductile-then-brittle detachment. Later the detachment migrated at the interface between the pluton and the metamorphic unit under ductile-to-brittle conditions. To clarify how extensional deformation was precisely distributed within the pluton, a multi-scale approach from field observations to laboratory investigations was undertaken. Through macro- to micro-structural observations, we show a continuous deformation history from magmatic to solid-state ductile/brittle conditions under an overall north-directed shearing deformation. The early magmatic or sub-solidus deformation is evidenced in a large part of the granodiorite, notably in its southern part where the original intrusive contact is still preserved. Solid-state deformation is recorded further north when approaching the detachment zone, highlighted by a thicker cataclastic zone and numerous pseudotachylite veins. From these field observations, we defined six strain facies, leading us to propose a qualitative strain map of the Naxos granodiorite. Based on field pictures and X-ray tomography of oriented samples collected along the strain gradient, we quantified the intensity of mineralogical fabrics in 2D and 3D. This step required the treatment of 600 rocks samples and pictures using SPO2003 (Shape Preferred Orientation) and Intercepts2003. Measured shape variations of the strain ellipsoid thus corroborate the large-scale strain

  15. Felsic plutonic rocks of the Midyan region, Kingdom of Saudi Arabia—II. Pilot study in chemical classification of Arabian granitoids

    NASA Astrophysics Data System (ADS)

    Ramsay, Colin R.; Odell, John; Drysdall, Alan R.

    A universal classification scheme for felsic plutonic rocks of the Arabian Shield remains an important and elusive objective. The extensive data available for felsic plutonic rocks of the Midyan region, which have been assigned to intrusive suites of the alkali granite, alkali-feldspar granite, monzogranite, granodiorite and trondhjemite associations, provide material for a pilot study. Discriminant analysis of compositional data has yielded multivariate classification functions which successfully assign samples to their proper suites. Functions which use major-oxide values have a better success rate than those based on trace elements, but both are particularly effective in distinguishing samples of the two suites with important mineralizing potential. Test classification of data from another part of the Arabian Shield suggests that the technique and the classification functions are effective beyond the Midyan region. Multivariate discriminant analysis can therefore be used as an aid to mapping, correlating and/or assessing the mineral potential of felsic plutons, and may form the basis for an objective, sensitive and concise classification scheme for Arabian felsic plutonic rocks.

  16. Time-scales of assembly and thermal history of a composite felsic pluton: constraints from the Emerald Lake area, northern Canadian Cordillera, Yukon

    NASA Astrophysics Data System (ADS)

    Coulson, Ian M.; Villeneuve, Mike E.; Dipple, Gregory M.; Duncan, Robert A.; Russell, James K.; Mortensen, James K.

    2002-05-01

    Knowledge of the time-scales of emplacement and thermal history during assembly of composite felsic plutons in the shallow crust are critical to deciphering the processes of crustal growth and magma chamber development. Detailed petrological and chemical study of the mid-Cretaceous, composite Emerald Lake pluton, from the northern Canadian Cordillera, Yukon Territory, coupled with U-Pb and 40Ar/ 39Ar geochronology, indicates that this pluton was intruded as a series of magmatic pulses. Intrusion of these pulses produced a strong petrological zonation from augite syenite, hornblende quartz syenite and monzonite, to biotite granite. Our data further indicate that multiple phases were emplaced and cooled to below the mineral closure temperatures over a time-scale on the order of the resolution of the 40Ar/ 39Ar technique (˜1 Myr), and that emplacement occurred at 94.3 Ma. Simple thermal modelling and heat conduction calculations were used to further constrain the temporal relationships within the intrusion. These calculations are consistent with the geochronology and show that emplacement and cooling were complete in less than 100 kyr and probably 70±5 kyr. These results demonstrate that production, transport and emplacement of the different phases of the Emerald Lake pluton occurred essentially simultaneously, and that these processes must also have been closely related in time and space. By analogy, these results provide insights into the assembly and petrogenesis of other complex intrusions and ultimately lead to an understanding of the processes involved in crustal development.

  17. Plutonism, deformation, and metamorphism in the Proterozoic Flin Flon greenstone belt, Canada: Limits on timing provided by the single-zircon Pb-evaporation technique

    SciTech Connect

    Ansdell, K.M.; Kyser, T.K. )

    1991-05-01

    The authors have used the single-zircon Pb-evaporation technique to determine the age of granitoids in the western Flin Flon domain of the Trans-Hudson orogen in Canada and to constrain the timing of molasse sedimentation, deformation, metamorphism, and mesothermal gold mineralization. The plutons were intruded between 1,860 and 1,834 Ma, about 30 m.y. after volcanism, and provide further evidence of a major period of intrusive activity throughout the Trans-Hudson orogen at that time. The older plutons (1,860 to 1,848 Ma) are synchronous with P2 deformation and the early stages of peak metamorphism, whereas the younger plutons are synchronous with or postdate the P3 deformation event. Molasse sedimentary units are deformed and metamorphosed; thus, deposition must have begun at about 1,860 Ma. Mesothermal gold mineralization postdates all plutons and may be related to high-grade peak metamorphism in adjacent terranes at about 1,815 Ma. This study also provides further support for the use of the Pb-evaporation technique as a suitable method for dating single zircons and indicates that the {sup 208}Pb/{sup 206}Pb ratio of zircons may be a useful tool in detecting the presence and source of xenocrystic zircons.

  18. Reconnaissance geochemical exploration of the plutons of quartz monzonite and granite in the Jabal Lababa and Ar Rayth areas, Southern Asir, Kingdom of Saudi Arabia

    SciTech Connect

    Overstreet, W.C.; Assegaff, A.B.; Jambi, M.; Hussain, M.A.; Selner, G.I.; Matzko, J.J.

    1985-01-01

    Geochemical reconnaissance for rare metals in plutons of albite-muscovite granite and quartz monzonite in the vicinity of Jabal Lababa disclosed positive geochemical anomalies for beryllium, tantalum, thorium, lanthanum, niobium, tin, yttrium, and zirconium. The low anomalous values for the rare metals in rocks and the short mechanical dispersion trains, seldom exceeding 4 km in length, of rare-metal-bearing heavy minerals, are interpreted to indicate that primary deposits of these metals are lacking, and any placers would be small and low in tenor. Small positive anomalies for barium were detected at scattered localities in the metasediments adjacent to the plutons in the Jabal Lababa area. Positive anomalies for the precious metals are lacking, and the low values observed for base metals do not indicate the presence of sulfide deposits. The abundant quartz lag gravel in the eastern part of the area is unmineralized. Small books of muscovite are present in some pegmatite, but is of non-commercial volume and quality. A subcircular structure at the coast of the Red Sea near the month of Wadi Nahb should be tested to determine if it is a buried salt dome. Three nonmagnetic high-density concentrates containing 1000 to 15,000 ppm lead were found on the granitic pluton near Ar Rayth. The source of the lead is not galena, and high values for lead appear to be characteristic of the pluton but do not indicate an ore deposit. 74 refs., 11 figs., 43 tabs.

  19. Pluton-dyke relationships in a Variscan granitic complex from AMS and gravity modelling. Inception of the extensional tectonics in the South Armorican Domain (France)

    NASA Astrophysics Data System (ADS)

    Turrillot, P.; Faure, M.; Martelet, G.; Chen, Y.; Augier, R.

    2011-11-01

    The Carnac granitic Complex (South Armorican Domain, Western France) was emplaced during Late Carboniferous times in the deepest Variscan unit, roofed by two major extensional shear zones. Through the acquisition and interpretation of field data, Anisotropy of Magnetic Susceptibility and gravity data, emphasized by petrological and structural observations, we address the emplacement model and possible magmatic processes involved between dyking to massive plutonism in a synkinematic context. Gravity modelling highlights an overall eastward thinning of the pluton, and several deep zones in the western part of the complex, interpreted as the pluton feeder zones. The internal granitic fabric, developed in a sub-solidus state, shows marked planar-linear anisotropy, consistent with a vertical shortening in the WNW-ESE regional stretching regime and eastward magma spreading. This study documents the occurrence of numerous NNE-SSW trending dykes within the eastern part of the pluton, suggesting that this granitic Complex formed by the coalescence of dykes oriented perpendicular to the regional stretching direction, and thus interpreted as large-scale “tension gashes”. The synkinematic character of the Carnac Complex intrusion, recently dated at ca. 319 ± 6 Ma, thus times the inception of the late-orogenic extensional deformation experienced in the whole South Armorican Domain.

  20. Isotopic characteristics of mantle sources for Quaternary continental alkaline magmas in the northern Canadian Cordillera

    NASA Astrophysics Data System (ADS)

    Carignan, Jean; Ludden, John; Francis, Don

    1994-12-01

    Three mantle compositions are identified as potential source end members for Quaternary to recent alkaline volcanic rocks from Fort Selkirk, Llangorse-Hirschfeld, Alligator Lake and Mt. Edziza in the northern Canadian Cordillera. These are: (1) an amphibole-rich source, characterized by unradiogenic Sr, Nd and Pb, from which the olivine nephelinite lavas formed, (2) the continental lithospheric mantle which is characterised by high Pb-207/Pb-204 and appears to be involved in the formation of the alkali olivine basalts of Fort Selkirk, and (3) a mantle with radiogenic Pb and unradiogenic Sr (HIMU-type) represented by lavas from Mt. Edziza. The Mt. Edziza volcano is the largest of the volcanic centres in the region, and is considered to reflect melting of sublithospheric mantle of HIMU composition below central British Columbia. Incipient melting of amphibole-veined subcontinental mantle lithosphere resulted from plume upwelling and/or transtensional pressure release and produced the small nephelinite to olivine basalt centres of the northern Cordilleran Province. The source of the nephelinite magmas is slightly more radiogenic than present-day Pacific Mid-Ocean ridge basalts (MORB), and is best represented by the most depleted component of the Aleutian magmas. This suggests enrichment of the subcontinental lithosphere in the northern Cordillera by melts of this isotopic composition during Cretaceous subduction. The Alligator Lake complex is anomalous and charaterized by the most radiogenic lavas. Despite the presence of crustal xenoliths there is no clear geochemical signature for crustal contamination and, in contrast to the other volcanic centers which were erupted through the Intermontain Belt, the lavas of this center may have been derived from a highly radiogenic lithospheric mantle beneath the Coast Plutonic complex.

  1. Mesozoic mafic alkaline magmatism of southern Scandinavia

    NASA Astrophysics Data System (ADS)

    Tappe, Sebastian

    2004-11-01

    More than 100 volcanic necks in central Scania (southern Sweden) are the product of Jurassic continental rift-related mafic alkaline magmatism at the southwest margin of the Baltic Shield. They are mainly basanites, with rarer melanephelinites. Both rock groups display overlapping primitive Mg-numbers, Cr and Ni contents, steep chondrite-normalized rare earth element patterns (LaN /YbN = 17 27) and an overall enrichment in incompatible elements. However, the melanephelinites are more alkaline and have stronger high field strength element enrichment than the basanites. The existence of distinct primary magmas is also indicated by heterogeneity in highly incompatible element ratios (e.g. Zr/Nb, La/Nb). Trace element modelling indicates that the magmas were generated by comparably low degrees of melting of a heterogeneous mantle source. Such a source can best be explained by a metasomatic overprint of the mantle lithosphere by percolating evolved melts. The former existence of such alkaline trace element-enriched melts can be demonstrated by inversion of the trace element content of green-core clinopyroxenes and anorthoclase which occur as xenocrysts in the melanephelinites and are interpreted as being derived from crystallization of evolved mantle melts. Jurassic magmatic activity in Scania was coeval with the generation of nephelinites in the nearby Egersund Basin (Norwegian North Sea). Both Scanian and North Sea alkaline magmas share similar trace element characteristics. Mantle enrichment processes at the southwest margin of the Baltic Shield and the North Sea Basin generated trace element signatures similar to those of ocean island basalts (e.g. low Zr/Nb and La/Nb) but there are no indications of plume activity during the Mesozoic in this area. On the contrary, the short duration of rifting, absence of extensive lithospheric thinning, and low magma volumes argue against a Mesozoic mantle plume. It seems likely that the metasomatic imprint resulted from the

  2. Alkaline and ultrasound assisted alkaline pretreatment for intensification of delignification process from sustainable raw-material.

    PubMed

    Subhedar, Preeti B; Gogate, Parag R

    2014-01-01

    Alkaline and ultrasound-assisted alkaline pretreatment under mild operating conditions have been investigated for intensification of delignification. The effect of NaOH concentration, biomass loading, temperature, ultrasonic power and duty cycle on the delignification has been studied. Most favorable conditions for only alkaline pretreatment were alkali concentration of 1.75 N, solid loading of 0.8% (w/v), temperature of 353 K and pretreatment time of 6 h and under these conditions, 40.2% delignification was obtained. In case of ultrasound-assisted alkaline approach, most favorable conditions obtained were alkali concentration of 1N, paper loading of 0.5% (w/v), sonication power of 100 W, duty cycle of 80% and pretreatment time of 70 min and the delignification obtained in ultrasound-assisted alkaline approach under these conditions was 80%. The material samples were characterized by FTIR, SEM, XRD and TGA technique. The lignin was recovered from solution by precipitation method and was characterized by FTIR, GPC and TGA technique.

  3. Alkaline solution/binder ratio as a determining factor in the alkaline activation of aluminosilicates

    SciTech Connect

    Ruiz-Santaquiteria, C.; Fernandez-Jimenez, A.; Palomo, A.

    2012-09-15

    This study investigates the effect of the alkaline solution/binder (S/B) ratio on the composition and nanostructure of the reaction products generated in the alkaline activation of aluminosilicates. The experiments used two mixtures of fly ash and dehydroxylated white clay and for each of these, varying proportions of the solution components. The alkali activator was an 8 M NaOH solution (with and without sodium silicate) used at three S/B ratios: 0.50, 0.75 and 1.25. The {sup 29}Si, {sup 27}Al MAS NMR and XRD characterisation of the reaction products reveal that for ratios nearest the value delivering suitable paste workability, the reaction-product composition and structure depend primarily on the nature and composition of the starting materials and the alkaline activator used. However, when an excess alkaline activator is present in the system, the reaction products tend to exhibit SiO{sub 2}/Al{sub 2}O{sub 3} ratios of approximately 1, irrespective of the composition of the starting binder or the alkaline activator.

  4. La Escalerilla pluton, San Luis Argentina: The orogenic and post-orogenic magmatic evolution of the famatinian cycle at Sierras de San Luis

    NASA Astrophysics Data System (ADS)

    Morosini, Augusto Francisco; Ortiz Suárez, Ariel Emilio; Otamendi, Juan Enrique; Pagano, Diego Sebastián; Ramos, Gabriel Alejandro

    2017-01-01

    Field relationships, geochemical analysis and two new absolute ages (LA-MC-ICP-MS U/Pb-zircon) allow the division of the La Escalerilla pluton (previously considered to be a single granitic body) into two different plutons: a new La Escalerilla pluton (s.s.), dated at 476.7 ± 9.6 Ma, that represents the northern portion, and the El Volcán pluton, dated at 404.5 ± 8.5 Ma, located in the southern sector. The La Escalerilla pluton is composed of three facies: (1) biotite-bearing granodiorite, (2) porphyritic biotite-bearing granite, and (3) porphyritic two micas-bearing leucogranite, being the presence of late-magmatic dykes in these facies common. The El Volcán pluton is composed of two main facies: 1) porphyritic biotite-bearing granite, and 2) two micas-bearing leucogranite, but amphibole-bearing monzodioritic and tonalititic mega-enclaves are also common, as well as some dykes of amphibole and clinopyroxene-bearing syenites. A peculiarity between the two plutons is that their most representative facies (porphyritic biotite-bearing granites) have, apart from different absolute ages, distinctive geochemical characteristics in their concentrations of trace elements; the La Escalerilla granite is comparatively poorer in Ba, Sr, Nb, La, Ce, P, and richer in Rb, Tb, Y, Tm and Yb. The El Volcán granite is notably enriched in Sr and depleted in Y, resulting in high Sr/Y ratios (12.67-39.08) compared to the La Escalerilla granite (1.11-2.41). These contrasts indicate that the separation from their sources occurred at different depths: below 25 km for the La Escalerilla, and above 30 km for the El Volcán. Moreover, the contrasts allow us to interpret a thin crust linked to an environment of pre-collisional subduction for the first case, and a thickened crust of post-collisional environment for the second, respectively.

  5. Geochemistry and Geochronology of Eocene Plutons in Northeastern Washington: A Test of Farallon Slab Rollback as a Cause of the Challis Event

    NASA Astrophysics Data System (ADS)

    Caulfield, L.; Tepper, J. H.

    2015-12-01

    The causes of widespread magmatism and extension that affected the Pacific Northwest during the Eocene "Challis Event" are poorly understood. Two models that have been advanced to explain this activity are passage of a slab window (e.g., Haeussler et al., 2011) and rollback of the subducting Farallon slab following accretion of Siletzia (Schmandt and Humphreys, 2011). Both scenarios would have resulted in widespread magmatism but with different temporal patterns. Based on reconstructed plate motion vectors magmatism related to a slab window should produce a younging-to-the-NW pattern whereas magmatism associated with slab rollback should young to the S or SW. Existing dates on Eocene igneous units in NE Washington appear to show an overall younging to the SW, consistent with the slab rollback model. However, many of these dates (mainly K-Ar) have large uncertainties so we are conducting a U-Pb dating and geochemical survey of Eocene plutons across the region. An initial set of zircon U-Pb ages (by LA-MC-ICP-MS) from five intrusions in east-central WA range from 50.7 - 46.7 Ma and young to the SW, a trend similar to that observed among Eocene rocks in the Idaho Batholith (Gaschnig et al., 2013). To further investigate this pattern we are dating an additional ten plutonic units that define a ~100 km SW-NE transect through NE WA. From NE to SW the units in this transect are (with dates from WA DNR mapping) as follows: Sheppard granite (undated), Herron Creek intrusion (51.4 +/- 1.9 Ma), Mt. Bonaparte pluton (52.8 +/- 2.6 Ma), Daisy Trail granite (49.9 +/- 0.3 Ma), Swimptkin Creek pluton (48.2 +/- 1.2 Ma), Moses pluton (48.6 +/- 1.2 Ma), Keller Butte granite (52.9 +/- 0.4 Ma), Johnny George plutonic complex (49.9 +/- 0.45 Ma), Manilla Creek (undated), and Swawilla Basin pluton (58.8 +/- 2.2 Ma). Results of this study should lead to a better understanding of the cause(s) of Challis magmatism and specifically its relationship to the ~50-48 Ma accretion of Siletzia.

  6. Zircon U-Pb ages, geochemical and Sr-Nd-Pb-Hf isotopic constraints on petrogenesis of the Tarom-Olya pluton, Alborz magmatic belt, NW Iran

    NASA Astrophysics Data System (ADS)

    Nabatian, Ghasem; Jiang, Shao-Yong; Honarmand, Maryam; Neubauer, Franz

    2016-02-01

    A petrological, geochemical and Sr-Nd-Pb isotopic study was carried out on the Tarom-Olya pluton, Iran, in the central part of the Alpine-Himalayan orogenic belt. The pluton is composed of diorite, monzonite, quartz-monzonite and monzogranite, which form part of the Western Alborz magmatic belt. LA-ICP-MS analyses of zircons yield ages from 35.7 ± 0.8 Ma to 37.7 ± 0.5 Ma, interpreted as the ages of crystallization of magmas. Rocks from the pluton have SiO2 contents ranging from 57.0 to 69.9 wt.%, high K2O + Na2O (5.5 to 10.3 wt.%) and K2O/Na2O ratio of 0.9 to 2.0. Geochemical discrimination criteria show I-type and shoshonitic features for the studied rocks. All investigated rocks are enriched in light rare earth elements (LREEs), large ion lithophile elements (LILEs), depleted in high-field strength elements (HFSEs), and show weak or insignificant Eu anomalies (Eu/Eu* = 0.57-1.02) in chondrite-normalized trace element patterns. The Tarom-Olya pluton samples also show depletions in Nb, Ta and Ti typical of subduction-related arc magmatic signatures. The samples have relatively low ISr (0.7047-0.7051) and positive εNd(36 Ma) (+ 0.39 to + 2.10) values. The Pb isotopic ratios show a (206Pb/204Pb)i ratio of 18.49-18.67, (207Pb/204Pb)i ratio of 15.58-15.61 and (208Pb/204Pb)i ratio of 38.33-38.77. The εHf(t) values of the Tarom-Olya pluton zircons vary from - 5.9 to + 8.4, with a peak at + 2 to + 4. The depleted mantle Hf model ages for the Tarom-Olya samples are close to 600 Ma. These isotope evidences indicate contribution of juvenile sources in petrogenesis of the Tarom-Olya pluton. Geochemical and isotopic data suggest that the parental magma of the Tarom-Olya pluton was mainly derived from a sub-continental lithospheric mantle source, which was metasomatized by fluids and melts from the subducted Neotethyan slab with a minor crustal contribution. Subsequent hot asthenospheric upwelling and lithospheric extension caused decompression melting in the final stage of

  7. The Pombal granite pluton: Magnetic fabric, emplacement and relationships with the Brasiliano strike-slip setting of NE Brazil (Paraiba State)

    NASA Astrophysics Data System (ADS)

    Archanjo, C. J.; Bouchez, J.-L.; Corsini, M.; Vauchez, A.

    1994-03-01

    The Pombal pluton (500 km 2), a suite of diorite, syenite and porphyritic granite bodies, is here used to constrain kinematics of Brasiliano-age tectonic episodes in northeast Brazil. The pluton intrudes high-grade to migmatitic gneiss forming the western basement of the Seridó belt, and is located at the intersection between two sets of continental-scale dextral strike-slip shear zones. The northern set of shear zone strikes NE-SW and branches, southwards, into the E-W Patos mega-shear zone. A detailed microstructural and low-field magnetic susceptibility study was performed to unravel the relationships between solid-state deformation in the country rocks and magma emplacement. Porphyritic granite and syenite have quite high magnetic susceptibilities (10 -3-10 -2 SI units) indicative of magnetite as the principal carrier of susceptibility. The magnetic fabric is remarkably homogeneous in orientation throughout the pluton. It is characterized by a shape-preferred alignment of magnetite, itself parallel to the shape fabric of mainly biotite (±amphibole), i.e. to the magmatic fabric. Even close to the contact with the high-temperature mylonites of the Patos shear zone, south of Pombal, no imprint of the E-W-trending structures is observed in the fabrics of either the granite or the host rocks. Granite emplacement and its internal fabric development is concluded to be independent of the movement of the Patos shear zone. In the southwestern border of the pluton, a low-dip foliation bearing a NE-SW-striking lineation is shared in both the magmatic fabric of the pluton and the solid-state fabric. Farther to the north, approaching the NE-SW strike-slip shear zone, the magmatic fabric is characterized by a steeply dipping NE-striking foliation carrying a subhorizontal lineation. Transition from low to steep dips of the planar fabrics is progressive. Two models are proposed for emplacement of the Pombal pluton. One considers magma injection during an early episode of

  8. SHRIMP and 40Ar/39Ar age constraints for timing of plutonism and mineralization in the Boulder batholith

    USGS Publications Warehouse

    Lund, K.D.; Aleinikoff, John N.; Kunk, Michael J.; Unruh, Dan M.; Zeihen, G.D.; Hodges, W.C.; du Bray, Edward A.; O'Neill, J Michael

    2002-01-01

    The 66 Ma age for the quartz monzodiorite of Boulder Baldy and consideration of previous dating studies in the region indicate that small ca. 66 Ma plutonic systems may be common in the Boulder batholith region and especially to the east. The approximately 64 Ma porphyry copper systems at Butte and gold mineralization at Miller Mountain are indicative of regionally important mineralizing systems of this age in the Boulder batholith region. Resolution of the age and probable magmatic source of the Butte pre-Main Stage porphyry copper-molybdenum system and of the silver-rich polymetallic quartz vein systems in the northern part of the Boulder batholith documents that these deposits formed from two discrete periods of hydrothermal mineralization related to two discrete magmatic events.

  9. Zircon U-Pb geochronology, Sr-Nd-Hf isotopic composition and geological significance of the Late Triassic Baijiazhuang and Lvjing granitic plutons in West Qinling Orogen

    NASA Astrophysics Data System (ADS)

    Duan, Meng; Niu, Yaoling; Kong, Juanjuan; Sun, Pu; Hu, Yan; Zhang, Yu; Chen, Shuo; Li, Jiyong

    2016-09-01

    The Qinling Orogen was a consequence of continental collision of the South China Craton with the North China Craton in the Triassic and caused widespread granitoid magmatism. However, the petrogenesis of these granitoids remains controversial. In this paper, we choose the Baijiazhuang (BJZ) and Lvjing (LJ) plutons in the West Qinling Orogen for a combined study of the zircon U-Pb geochronology, whole-rock major and trace element compositions and Sr-Nd-Hf isotopic characteristics. We obtained zircon crystallization ages of 216 Ma and 212 Ma for the BJZ and the LJ plutons, respectively. The granitoid samples from both plutons have high K2O metaluminous to peraluminous compositions. They are enriched in large ion lithophile elements (LILEs), light rare earth elements (LREEs) and depleted in high field-strength elements (HFSEs) with significant negative Eu anomalies. The BJZ samples have initial Sr isotopic ratios of 0.7032 to 0.7078, εNd(t) of - 10.99 to - 8.54 and εHf (t) of - 10.22 to - 6.41. The LJ granitoids have initial Sr isotopic ratios of 0.7070 to 0.7080, εNd(t) of - 5.37 to - 4.58 and εHf(t) of - 3.64 to - 1.78. The enriched isotopic characteristics of the two plutons are consistent with their source being dominated by ancient continental crust. However, two BJZ samples show depleted Sr isotope compositions, which may infer possible involvement of mantle materials. Mantle-derived melt, which formed from partial melting of mantle wedge peridotite facilitated by dehydration of the subducted/subducting Mianlue ocean crust, provide the required heat for the crustal melting while also contributing to the compositions of these granitoids. That is, the two granitic plutons are magmatic responses to the closure of the Mianlue ocean basin and the continental collision between the Yangtze and South Qinling crustal terranes.

  10. Character of the pre-Mesozoic basement along the edge of the western US craton: Pb isotopic evidence from Mesozoic plutonism

    SciTech Connect

    Wooden, J.L.; Kistler, R.W.; Robinson, A.; Tosdal, R.M. ); Wright, J.E. . Dept. of Geology and Geophysics)

    1993-04-01

    The pre-Mesozoic cratonic crust of the western US was a composite of provinces composed mostly of Archean and Early Proterozoic rocks that had been truncated by Late Proterozoic rifting and had some new Paleozoic crust added along the western edge. Mesozoic and younger geologic events greatly obscured this pre-Mesozoic basement along the craton edge. However, the Pb isotopic signatures of Mesozoic plutons provide significant clues to the character of the crust in which they formed or were emplaced because of a strong contrast in Pb concentration between low-Pb, mantle-derived melts and Pb-rich crust. Thus, magmas whether derived from the crust or the mantle with subsequent crustal interaction, will likely have Pb isotopic compositions that reflect those of the crust. In the western US the Pb isotopic compositions of Mesozoic plutonic rocks have strong regional characteristics. Within the Early Proterozoic Mojave crustal province, Mesozoic plutonic rocks have a large range of 206Pb/204Pb ratios that plot above the crustal average, relatively high 207Pb/204Pb ratios that suggest an Archean contribution, and Pb and Sr isotopic compositions that are not correlated and that do not distinguish age groups. At the southern and western edge of this province where some 1.1 Ga rocks are exposed, 208Pb/204Pb ratios lie along the average crust model curve. These data suggest that any individual pluton provides a composite Pb isotopic composition for a discrete vertical section of the crust. Pb isotopic compositions of plutons in the Sierra Nevada and Great Basin are very different from those described above with 206Pb/204Pb ratios starting at 18.6, well-correlated Pb isotopic trends starting below the crustal model but extending to values that require input from the very radiogenic Wyoming province Archean crust, and good correlations between Pb and (1) Sr isotopic compositions and (2) W-E geographic position.

  11. Magmatic and solid state structures of the Abu Ziran pluton: Deciphering transition from thrusting to extension in the Eastern Desert of Egypt

    NASA Astrophysics Data System (ADS)

    Fritz, Harald; Loizenbauer, Jürgen; Wallbrecher, Eckart

    2014-11-01

    The 606 Ma old Abu Ziran granite of the Eastern Desert of Egypt intruded the southern margin of the Meatiq dome in a sinistral shear extensional setting. Its emplacement was enabled by a system of NW-trending sinistral shears, related Riedel shears and N-S extensional shear zones and faults. Magmatic flow was east-directed and controlled by Riedel shears that progressively rotated to an orientation favourable for extension. Strain markers that document magmatic flow show eastward decreasing strain together with strain increase from pluton centre to margins. This is explained by Newtonian flow between non-parallel plates and differences in flow velocities across the pluton. Solid state fabrics including shear fabrics, orientation of late magmatic dykes and quartz tension gashes, together with quartz C-axes distributions, document southward extensional shear within the solidified pluton and adjacent host rocks. Extensional shear is correlated with exhumation of the Meatiq dome coeval and soon after pluton solidification (585 Ma). Pressure temperature evolutionary paths, derived from fluid inclusions, show a clockwise path with exhumation by isothermal decompression in the Meatiq dome. By contrast, the overlying volcanosedimentary nappes experienced an anti-clockwise path released by temperature rise due to pluton emplacement followed by isobaric cooling. Quartz fabrics indicate high-temperature coaxial N-S flow in the northern Meatiq dome and lower-temperature, non-coaxial southward flow within the overlaying superficial nappe. This is explained by the exhumation process itself that progressively localised into simple shear domains when rocks approached higher crustal levels. Late extension at ca. 580 Ma was pure shear dominated and resulted in reversal of shear, now dextral, in the western Meatiq shear zone.

  12. Age and zircon inheritance of eastern Blue Ridge plutons, southwestern North Carolina and northeastern Georgia, with implications for magma history and evolution of the southern Appalachian origin

    SciTech Connect

    Miller, C.F.; Hatcher, R.D. Jr.; Ayers, J.C.; Coath, C.D.; Harrison, T.M.

    2000-02-01

    High-resolution ion microprobe analysis of zircon has provided ages for previously undated plutons of the high-grade eastern Blue Ridge of northeastern Georgia and southwestern North Carolina. These data, together with backscattered electron imaging, reveal the presence of nearly ubiquitous inherited cores of highly variable age and magmatic rims that have experienced variable Pb loss, thus making interpretation of conventional U-Pb analyses very difficult. Ion probe rim analyses indicate that the plutons were emplaced during both the mod-Ordovician and mid-Devonian. Zircons from all intrusions have predominantly 1.0 to 1.25 Ga cores (Grenvillian). In addition, both Devonian and Ordovician plutons have smaller populations of Late Proterozoic-early Paleozoic (0.5--0.75 Ga), Middle Proterozoic (1.4 Ga), and Late Archean (2.6--2.9 Ga) cores. The ubiquitous, round cores and thick magmatic rims suggest significant resorption and then protracted growth within the melts. Zircon saturation temperatures based on whole-rock ({approximately}melt) Zr concentrations are lower than expected for magma generation (710--760 C). Zirconium concentrations may not reflect saturation at maximum temperature, if melting was very rapid (<{approximately}10{sup 5} yrs), or if zircon cores represent grains that were shielded from melt inside host grains for much of the magmatic history. Ages of magmatic and inherited zones of zircon from the plutons demonstrate that similar crust underlay the eastern Blue Ridge during both Taconian and Acadian orogenies, that there was no single episode of voluminous magmatism, and that metamorphism and deformation began before 470 Ma and continued after 370 Ma. These plutons do not constitute a significant convergence-related arc, though it is possible that they represent a displaced part of an arc that lies primarily to the east (in the Inner Piedmont?).

  13. Paleomagnetism and magnetic fabric of Miocene plutons of the Tonalá shearz zone, Chiapas, Mexico: evidence of rotation of the remanence vector

    NASA Astrophysics Data System (ADS)

    Molina-Garza, Roberto S.; Geissman, John W.

    2016-04-01

    The Late Miocene plutons of coastal Chiapas are elongated parallel to the Tonalá mylonite belt, and some plutons show asymmetric outcrop patterns with sheared tails that trail behind the intrusions. Plutons were emplaced within a transpressional sinistral shear zone. Magnetic fabrics in the plutons are well-developed, and are subparallel to the structural trend of the Tonalá mylonitic belt, but locally magmatic fabrics are preserved. Magnetic fabrics in undeformed granites with igneous textures are also subparallel to the shear zone axis. Strongly deformed plutons have Ṕvalues as high as 1.7. Fabric ellipsoids are predominantly oblate, but they are triaxial in sites with igneous textures. Characteristic magnetizations reside in a cubic phase, such as low-Ti magnetite, but abundant particles in the MD range prevent isolating a stable magnetization in many of the sites. Site means are NW to NE directed, and of moderate positive inclination (or its antipodal), but locally they are very discordant in declination. The overall mean, discarding highly discordant sites is of D= 359.5 and I=41.9 (k=14.2, alpha95=8.1), which is nearly concordant with the NA reference direction indicating gentle northward tilt of less than about 10°. We explain the highly discordant directions as caused by continuing, progressive, deformation in the transpressive shear zone of a thermochemical remanence acquired during deformation. Deformation resulted in rotations, both in a clockwise and an anticlockwise sense. These results are interpreted as paleomagnetic vectors affected by distortional strain, which based on AMS exceed 40% shortening and accommodate shape and volume change in the rock.

  14. Tyramine functions as a toxin in honey bee larvae during Varroa-transmitted infection by Melissococcus pluton.

    PubMed

    Kanbar, G; Engels, W; Nicholson, G J; Hertle, R; Winkelmann, G

    2004-05-01

    From wounds of honey bee pupae, caused by the mite Varroa destructor, coccoid bacteria were isolated and identified as Melissococcus pluton. The bacterial isolate was grown anaerobically in sorbitol medium to produce a toxic compound that was purified on XAD columns, gelfiltration and preparative HPLC. The toxic agent was identified by GC-MS and FTICR-MS as tyramine. The toxicity of the isolated tyramine was tested by a novel mobility test using the protozoon Stylonychia lemnae. A concentration of 0.2 mg/ml led to immediate inhibition of mobility. In addition the toxicity was studied on honey bee larvae by feeding tyramine/water mixtures added to the larval jelly. The lethal dosis of tyramine on 4-5 days old bee larvae was determined as 0.3 mg/larvae when added as a volume of 20 microl to the larval food in brood cells. Several other biogenic amines, such as phenylethylamine, histamine, spermine, cadaverine, putrescine and trimethylamine, were tested as their hydrochloric salts for comparison and were found to be inhibitory in the Stylonychia mobility test at similar concentrations. A quantitative hemolysis test with human red blood cells revealed that tyramine and histamine showed the highest membranolytic activity, followed by the phenylethylamine, trimethylamine and spermine, while the linear diamines, cadaverine and putrescine, showed a significantly lower hemolysis when calculated on a molar amine basis. The results indicate that tyramine which is a characteristic amine produced by M. pluton in culture, is the causative agent of the observed toxic symptoms in bee larvae. Thus this disease, known as European foulbrood, is possibly an infection transmitted by the Varroa destructor mite.

  15. Updated paleomagnetic pole from Cretaceous plutonic rocks of the Sierra Nevada, California: Tectonic displacement of the Sierra Nevada block

    USGS Publications Warehouse

    Hillhouse, J.W.; Gromme, S.

    2011-01-01

    We report remanent magnetization measurements from 13 sites in Cretaceous plutonic rocks in the northern Sierra Nevada (38??N-39.5??N). By increasing the number of available paleomagnetic sites, the new data tighten constraints on the displacement history of the Sierra Nevada block and its pre-extensional position relative to interior North America. We collected samples in freshly exposed outcrops along four highway transects. The rocks include diorite, granodiorite, and tonalite with potassium-argon ages (hornblende) ranging from 100 Ma to 83 Ma. By combining our results with previous paleomagnetic determinations from the central and southern Sierra Nevada (excluding sites from the rotated southern tip east of the White Wolf-Kern Canyon fault system), we find a mean paleomagnetic pole of 70.5??N, 188.2??E, A95 = 2.6?? (N = 26, Fisher concentration parameter, K = 118). Thermal demagnetization indicates that the characteristic remanence is generally unblocked in a narrow range within 35 ??C of the Curie temperature of pure magnetite. Small apparent polar wander during the Cretaceous normal-polarity superchron, plus prolonged acquisition of remanence at the site level, may account for the low dispersion of virtual geomagnetic poles and relatively large K value. Tilt estimates based on overlapping sediments, stream gradients, and thermochronology of the Sierra Nevada plutons vary from 0?? to 3?? down to the southwest. Without tilt correction, the mean paleomagnetic pole for the Sierra Nevada is essentially coincident with the North American reference pole during the Cretaceous stillstand (125 Ma to 80 Ma). At 95% confidence, the apparent latitude shift is 1.1?? ?? 3.0?? (positive northward), and the apparent rotation is negligible, 0.0?? ?? 4.7??. Correcting for each degree of tilt, which is limited to 3?? on geologic evidence, increases the rotation anomaly 2.2?? counterclockwise, while the apparent latitude shift remains unchanged. ?? 2011 Geological Society of

  16. Uranium-rich accessory minerals in the peraluminous and perphosphorous Belvís de Monroy pluton (Iberian Variscan belt)

    NASA Astrophysics Data System (ADS)

    Pérez-Soba, Cecilia; Villaseca, Carlos; Orejana, David; Jeffries, Teresa

    2014-05-01

    The strongly peraluminous, perphosphorous (<0.85 wt% P2O5) and low-Ca granites from the Belvís de Monroy pluton contain the most U-rich monazite-(Ce) and xenotime known in igneous rocks. Along with these accessory minerals, P-rich zircon occurs, reaching uncommon compositions particularly in the more fractionated units of this zoned pluton. Monazite displays a wide compositional variation of UO2 (<23.13 wt%) and ThO2 (<19.58 wt%), positively correlated with Ca, Si, P, Y and REE. Xenotime shows a high UO2 content (2.37-13.34 wt%) with parallel increases of LREE, Ca and Si. Zircon contains comparatively much lower UO2 (<1.53 wt%) but high P2O5 (<14.91 wt%), Al2O3 (<6.96 wt%), FeO (<2.93 wt%) and CaO (<2.24 wt%) contents. The main mechanism of incorporating large U and Th amounts in studied monazite and U in xenotime is the cheralite-type [(Th,U)4+ + Ca2+ = 2(Y,REE)3+] substitution. Zircon requires several coupled mechanisms to charge balance the P substitution, resulting in non-stoichiometric compositions with low analytical totals. Compositional variations in the studied accessory phases indicate that the substitution mechanisms during crystal growth depend on the availability of non-formula elements. The strong P-rich character of the studied granites increases monazite crystallization, triggering a progressive impoverishment in Th and LREE in the residual melts, and consequently increasing extraordinarily the U content in monazite and xenotime. This is in marked contrast to other peraluminous (I-type or P-poor S-type) granite series. The P-rich and low-Ca peraluminous melt inhibits uraninite crystallization, so contributing to the U availability for monazite and xenotime.

  17. Sr and Pb isotopic geochemistry of feldspars and implications for the growth of megacrysts in plutonic settings.

    NASA Astrophysics Data System (ADS)

    Munnikhuis, J.; Glazner, A. F.; Coleman, D. S.; Mills, R. D.

    2015-12-01

    Why megacrystic textures develop in silicic igneous rocks is still unknown. One hypothesis is that these crystals nucleate early in a magma chamber with a high liquid content. A supportive observation of this hypothesis is areas in plutons with high concentrations of megacrysts suggesting flow sorting. Another group of hypotheses suggest megacrystic textures form during protracted late-stage coarsening in a low-melt, interlocked matrix due to either thermal oscillations from incremental pluton emplacement, or Ostwald ripening. Isotopic analyses of large, euhedral K-feldspar megacrysts from the Cretaceous intrusive suites of the Sierra Nevada batholith (SNB) provide new insight into their origin. Megacrysts from the SNB reach the decimeter scale, are Or rich (85-90%), are perthitic, and host mineral inclusions of nearly all phases in the host rock. In-situ micro-drilling of transects, from core to rim, of the alkali feldspars provides material for Sr and Pb isotopic analyses by thermal ionization mass spectrometry (TIMS). Preliminary 87Sr/86Sr(i) isotopic data from samples from the Cathedral Peak Granodiorite, of the Tuolumne Intrusive Suite range from 0.706337 to 0.706452 (~1.6ɛSr) near the cores, whereas a sawtooth pattern with larger variability, 0.706179 to 0.706533 (~5ɛSr), occurs nears the rims. We interpret these preliminary data to indicate that the late portion of growth (i.e. crystal rim) was dominated by either cannibalism of small K-feldspar crystals with isotopic variability, or by addition of isotopically diverse late components to the magma. By comparing the Sr and Pb isotopic stratigraphy of megacrysts from a variety of rock matrices and different granitoids in the SNB isotopic trends can be evaluated to determine if crystals sizes are dependent on disequilibrium processes or grow at a steady state.

  18. Tectonic accretion and the origin of the two major metamorphic and plutonic welts in the Canadian Cordillera

    NASA Astrophysics Data System (ADS)

    Monger, J. W. H.; Price, R. A.; Tempelman-Kluit, D. J.

    1982-02-01

    The Omineca Crystalline Belt and Coast Plutonic Complex are the two major regional tectonic welts in the Canadian Cordillera in which were concentrated intense deformation, regional metamorphism, granitic magmatism, uplift, and erosion. The welts, which formerly were thought to result from subduction of Pacific Ocean lithosphere beneath the western edge of North America, can now be viewed partly as the result of tectonic overlap and/or compressional thickening of crustal rocks during collisions between North America and two large, composite, allochthonous terranes that were accreted to its ancient western margin. The inner composite terrane, Terrane I, includes four smaller terranes that apparently were together by the end of Triassic time. The outer composite terrane, Terrane II, comprises two terranes, amalgamated by Late Jurassic time. The Omineca Crystalline Belt formed mainly from mid-Jurassic time onward, during and following the collision of Terrane I with North America. This belt straddles the zone of overlap of autochthonous and allochthonous terranes, and its characteristic metamorphism and structure are superimposed on both. The Coast Plutonic Complex formed mainly in Cretaceous to early Tertiary time during and following the attachment of Terrane II to the new, Jurassic, continental margin. It lies along the boundary of Terrane I and Terrane II and involves elements of both terranes. The collisions took place within the overall setting of the North American plate moving relatively westward into various Pacific plates from Jurassic time onward and in conjunction with subduction of Pacific Ocean lithosphere. *Present address: Geological Survey of Canada, 601 Booth Street, Ottawa, Ontario K1A OE8, Canada

  19. Kamafugitic diatremes: their textures and field relationships with examples from the Goiás alkaline province, Brazil

    NASA Astrophysics Data System (ADS)

    Junqueira-Brod, Tereza Cristina; Gaspar, José Carlos; Brod, José Affonso; Kafino, Camilla Vasconcelos

    2005-03-01

    Kamafugitic rocks intruded the Precambrian basement and Phanerozoic sediments at the northeast border of the Paraná basin as part of the Late Cretaceous Goiás alkaline province (GAP). Plutonic complexes dominate the north of the province, whereas lavas and pyroclastic rocks prevail in the south. The central GAP is characterized by kamafugitic diatremes, which may crop out continuously for up to 850 m and consist of a central breccia body, surrounded and overlain by lava flows and crosscut by dykes. The breccias contain some special spheroidal juvenile fragments—namely, accretionary and armored lapilli, frozen droplets, spinning droplets, and wrapped fragments—whose textural and mineralogical aspects are described in detail. Irregularly shaped tuff pockets that occur within the breccias contain textures and structures similar to those of subaerial surge deposits and formed in confined, high gas to solid+liquid ratio domains in the conduit. Diatreme emplacement affected the country rock through thermal metamorphism, development of columnar jointing, and formation of peperite-like mixtures. There is no evidence of phreatomagmatic activity in the diatremes, and CO 2, rather than H 2O, seems to have been the major volatile component of the kamafugitic magmas. This finding implies that features such as accretionary lapilli and peperites are not exclusively associated with H 2O-dominated processes.

  20. Desialylated alkaline phosphatase: activation by 4-nitrophenol.

    PubMed

    Nayudu, P R

    1984-01-01

    Mouse ileal alkaline phosphatase is a sialyl enzyme (12-14 moles per mole of enzyme). When partially desialylated by treatment with neuraminidase, the enzyme loses most of its activity, associated with reduced apparent Vmax and Km. Part of that loss, however, is recovered as the product 4-nitrophenol's concentration builds up in the cuvette. Experimental results are presented to demonstrate that the activation is due to the binding of 4-nitrophenol as a ligand by the partially desialylated enzyme and that both the loss of activity by sialic acid removal and activation by ligand-binding are correlated with changes in protein conformation.

  1. Alkaline chemistry of transuranium elements and technetium and the treatment of alkaline radioactive wastes

    SciTech Connect

    Delegard, C.H.; Peretrukhin, V.F.; Shilov, V.P.; Pikaev, A.K.

    1995-05-01

    Goal of this survey is to generalize the known data on fundamental physical-chemical properties of TRUs and Tc, methods for their isolation, and to provide recommendations that will be useful for partitioning them from alkaline high-level wastes.

  2. Response of Desulfovibrio vulgaris to alkaline stress.

    PubMed

    Stolyar, Sergey; He, Qiang; Joachimiak, Marcin P; He, Zhili; Yang, Zamin Koo; Borglin, Sharon E; Joyner, Dominique C; Huang, Katherine; Alm, Eric; Hazen, Terry C; Zhou, Jizhong; Wall, Judy D; Arkin, Adam P; Stahl, David A

    2007-12-01

    The response of exponentially growing Desulfovibrio vulgaris Hildenborough to pH 10 stress was studied using oligonucleotide microarrays and a study set of mutants with genes suggested by microarray data to be involved in the alkaline stress response deleted. The data showed that the response of D. vulgaris to increased pH is generally similar to that of Escherichia coli but is apparently controlled by unique regulatory circuits since the alternative sigma factors (sigma S and sigma E) contributing to this stress response in E. coli appear to be absent in D. vulgaris. Genes previously reported to be up-regulated in E. coli were up-regulated in D. vulgaris; these genes included three ATPase genes and a tryptophan synthase gene. Transcription of chaperone and protease genes (encoding ATP-dependent Clp and La proteases and DnaK) was also elevated in D. vulgaris. As in E. coli, genes involved in flagellum synthesis were down-regulated. The transcriptional data also identified regulators, distinct from sigma S and sigma E, that are likely part of a D. vulgaris Hildenborough-specific stress response system. Characterization of a study set of mutants with genes implicated in alkaline stress response deleted confirmed that there was protective involvement of the sodium/proton antiporter NhaC-2, tryptophanase A, and two putative regulators/histidine kinases (DVU0331 and DVU2580).

  3. Autonomous in situ measurements of seawater alkalinity.

    PubMed

    Spaulding, Reggie S; DeGrandpre, Michael D; Beck, James C; Hart, Robert D; Peterson, Brittany; De Carlo, Eric H; Drupp, Patrick S; Hammar, Terry R

    2014-08-19

    Total alkalinity (AT) is an important parameter for describing the marine inorganic carbon system and understanding the effects of atmospheric CO2 on the oceans. Measurements of AT are limited, however, because of the laborious process of collecting and analyzing samples. In this work we evaluate the performance of an autonomous instrument for high temporal resolution measurements of seawater AT. The Submersible Autonomous Moored Instrument for alkalinity (SAMI-alk) uses a novel tracer monitored titration method where a colorimetric pH indicator quantifies both pH and relative volumes of sample and titrant, circumventing the need for gravimetric or volumetric measurements. The SAMI-alk performance was validated in the laboratory and in situ during two field studies. Overall in situ accuracy was -2.2 ± 13.1 μmol kg(-1) (n = 86), on the basis of comparison to discrete samples. Precision on duplicate analyses of a carbonate standard was ±4.7 μmol kg(-1) (n = 22). This prototype instrument can measure in situ AT hourly for one month, limited by consumption of reagent and standard solutions.

  4. Advanced inorganic separators for alkaline batteries

    NASA Technical Reports Server (NTRS)

    Sheibley, D. W. (Inventor)

    1982-01-01

    A flexible, porous battery separator comprising a coating applied to a porous, flexible substrate is described. The coating comprises: (1) a thermoplastic rubber-based resin which is insoluble and unreactive in the alkaline electrolyte; (2) a polar organic plasticizer which is reactive with the alkaline electrolyte to produce a reaction product which contains a hydroxyl group and/or a carboxylic acid group; and (3) a mixture of polar particulate filler materials which are unreactive with the electrolyte, the mixture comprising at least one first filler material having a surface area of greater than 25 meters sq/gram, at least one second filler material having a surface area of 10 to 25 sq meters/gram, wherein the volume of the mixture of filler materials is less than 45% of the total volume of the fillers and the binder, the filler surface area per gram of binder is about 20 to 60 sq meters/gram, and the amount of plasticizer is sufficient to coat each filler particle. A method of forming the battery separator is also described.

  5. DNA DAMAGE QUANTITATION BY ALKALINE GEL ELECTROPHORESIS.

    SciTech Connect

    SUTHERLAND,B.M.; BENNETT,P.V.; SUTHERLAND, J.C.

    2004-03-24

    Physical and chemical agents in the environment, those used in clinical applications, or encountered during recreational exposures to sunlight, induce damages in DNA. Understanding the biological impact of these agents requires quantitation of the levels of such damages in laboratory test systems as well as in field or clinical samples. Alkaline gel electrophoresis provides a sensitive (down to {approx} a few lesions/5Mb), rapid method of direct quantitation of a wide variety of DNA damages in nanogram quantities of non-radioactive DNAs from laboratory, field, or clinical specimens, including higher plants and animals. This method stems from velocity sedimentation studies of DNA populations, and from the simple methods of agarose gel electrophoresis. Our laboratories have developed quantitative agarose gel methods, analytical descriptions of DNA migration during electrophoresis on agarose gels (1-6), and electronic imaging for accurate determinations of DNA mass (7-9). Although all these components improve sensitivity and throughput of large numbers of samples (7,8,10), a simple version using only standard molecular biology equipment allows routine analysis of DNA damages at moderate frequencies. We present here a description of the methods, as well as a brief description of the underlying principles, required for a simplified approach to quantitation of DNA damages by alkaline gel electrophoresis.

  6. Thermodynamic model for an alkaline fuel cell

    NASA Astrophysics Data System (ADS)

    Verhaert, Ivan; De Paepe, Michel; Mulder, Grietus

    Alkaline fuel cells are low temperature fuel cells for which stationary applications, e.g. cogeneration in buildings, are a promising market. In order to guarantee a long life, water and thermal management has to be done in a careful way. In order to better understand the water, alkali and thermal flows, a two-dimensional model for an Alkaline Fuel Cell is developed using a control volume approach. In each volume the electrochemical reactions together with the mass and energy balance are solved. The model is created in Aspen Custom Modeller, the development environment of Aspen Plus, where special attention is given to the physical flow of hydrogen, water and air in the system. In this way the developed component, the AFC-cell, can be built into stack configurations to understand its effect on the overall performance. The model is validated by experimental data from measured performance by VITO with their Cell Voltage Monitor at a test case, where the AFC-unit is used as a cogeneration unit.

  7. The effect of alkaline agents on retention of EOR chemicals

    SciTech Connect

    Lorenz, P.B.

    1991-07-01

    This report summarizes a literature survey on how alkaline agents reduce losses of surfactants and polymers in oil recovery by chemical injection. Data are reviewed for crude sulfonates, clean anionic surfactants, nonionic surfactants, and anionic and nonionic polymers. The role of mineral chemistry is briefly described. Specific effects of various alkaline anions are discussed. Investigations needed to improve the design of alkaline-surfactant-polymer floods are suggested. 62 refs., 28 figs., 6 tabs.

  8. Petrochemistry of ultrapotassic tephrites and associated cognate plutonic xenoliths with carbonatite affinities from the late Quaternary Qa’le Hasan Ali maars, central Iran

    NASA Astrophysics Data System (ADS)

    Saadat, S.; Stern, C. R.; Moradian, A.

    2014-08-01

    The Quaternary Qa’le Hasan Ali (QHA) maars in central Iran occur at the intersection of the north-south Nayband fault, which defines the western boundary of the Lut micro-continental block, and a system of northwest-southeast faults, subparallel to the Zagros suture zone, that formed during the Arabian-Eurasian collision. These post-collisional maars intrude Eocene volcanic rocks of the Urumieh-Dokhtar magmatic belt, which was generated by the subduction of Neotethys oceanic lithosphere below Iran. The highly potassic, Ti-phlogopite + Mg-rich (Fo89-92) olivine + diopside-augite + aegirine-augite basanite tephrites forming the tuff rims of the QHA maars contain tephrite-coated plutonic xenoliths, some of which are interpreted as co-genetic with the tephrites based on their similar mineralogy and Sr isotopic composition (87Sr/86Sr = 0.70590). Cognate plutonic xenoliths have up to ∼20 vol% calcite, considered to be magmatic calcite because of (1) its grain size, which is similar to feldspars and aegirine-augite pyroxenes in these rocks, (2) the occurrence of fine-grained inclusions of pyroxene and apatite within these calcite grains, and (3) the similarity of the Sr-isotopic composition of this calcite with the other minerals in these rocks. The fact that the magmatic calcite has remained intact and did not volatilize during the transport of these xenoliths to the surface in the hot tephrite magma implies a short transit time, indicating that they are samples of a shallow plutonic complex, as does the presence of anorthoclase in these plutonic xenoliths. Their high modal proportion of magmatic calcite suggests that this shallow plutonic complex has affinities with carbonatites. The magmatic calcite-bearing plutonic xenoliths have high LREE/HREE ratios and contain REE-rich allanite (with up to ∼20 wt% LREE) and britholite (∼60 wt% LREE) that make up ∼3 modal percent of the most calcite-rich samples. Similar to many post-collisional highly potassic rocks

  9. Emplacement mechanism of the Middle-Late Jurassic Qitianling pluton and its implications on the Mesozoic tectonics of South China Block

    NASA Astrophysics Data System (ADS)

    Liu, Hongsheng; Chen, Yan; Faure, Michel; Scaillet, Bruno; Wang, Bo; Martelet, Guillaume; Huang, Fangfang; Zhu, Jinchu; Wang, Rucheng; Erdmann, Saskia

    2016-04-01

    The widespread Mesozoic magmatism that extends about 1500km along the NE-SW strike and 800km wide in the southeastern part of the South China Block is a remarkable feature that has attracted the attention of geoscientists since 1940's. Numerous studies have been carried out, and consequently, several geodynamic models related to the emplacement mechanism have been proposed, based essentially on petrology, geochronology, and (isotopic) geochemistry. Recently, a general consensus is apparently achieved within the geosciences community on the tectonic contexts of the South China Block during the Triassic (compressive) and Cretaceous (extensive) periods, however the tectonic setting of the Jurassic is still in debate, moreover the Jurassic magmatism is closely related to abundant mineralization of rare metal elements. Due to the similarities in age, rock type and major geochemical feature of Jurassic granite, the Qitianling granitic pluton, situated in the Nanling area and dated at ca. 157 Ma, was chosen as the target of this study among 41 visited plutons. Previous studies divide the Qitianling pluton into three petrographic facies, namely: i) Bt + Qtz + Fsd + Amp, ii) Bt + Qtz + Fsd + (Amp) , iii) Bt + Qtz + Fsd. Zircon U-Pb dating indicate the age peak of these different facies at 161Ma, 157-156Ma and 149Ma, respectively. The field observation shows that: 1) the granite is isotropic without visible preferred mineral orientation or deformation; 2) the contact between the granite and country rocks is sharp, with a 1-10m narrow thermal aureole, but without any visible deformation. The microscopic observation on the thin sections of wall rocks and granite doesn't show any mineral preferred orientation consisting to the field observation. Therefore, a total of 53 sampling sites and 318 oriented cores were collected from the Qitianling pluton for an Anisotropy of Magnetic Susceptibility (AMS) study. The investigation on rock magnetism shows the pseudo

  10. Evidence for multiple mechanisms of crustal contamination of magma from compositionally zoned plutons and associated ultramafic intrusions of the Alaska Range

    USGS Publications Warehouse

    Reiners, P.W.; Nelson, B.K.; Nelson, S.W.

    1996-01-01

    Models of continental crustal magmagenesis commonly invoke the interaction of mafic mantle-derived magma and continental crust to explain geochemical and petrologic characteristics of crustal volcanic and plutonic rocks. This interaction and the specific mechanisms of crustal contamination associated with it are poorly understood. An excellent opportunity to study the progressive effects of crustal contamination is offered by the composite plutons of the Alaska Range, a series of nine early Tertiary, multiply intruded, compositionally zoned (peridotite to granite) plutons. Large initial Sr and Nd isotopic contrasts between the crustal country rock and likely parental magmas allow evaluation of the mechanisms and extents of crustal contamination that accompanied the crystallization of these ultramafic through granitic rocks. Three contamination processes are distinguished in these plutons. The most obvious of these is assimilation of crustal country rock concurrent with magmatic fractional crystallization (AFC), as indicated by a general trend toward crustal-like isotopic signatures with increasing differentiation. Second, many ultramafic and mafic rocks have late-stage phenocryst reaction and orthocumulate textures that suggest interaction with felsic melt. These rocks also have variable and enriched isotopic compositions that suggest that this felsic melt was isotopically enriched and probably derived from crustal country rock. Partial melt from the flysch country rock may have reacted with and contaminated these partly crystalline magmas following the precipitation and accumulation of the cumulus phenocrysts but before complete solidification of the magma. This suggests that in magmatic mush (especially of ultramafic composition) crystallizing in continental crust, a second distinct process of crustal contamination may be super-imposed on AFC or magma mixing involving the main magma body. Finally, nearly all rocks, including mafic and ultramafic rocks, have (87Sr

  11. Geochemistry of intrusive rocks associated with the Latir volcanic field, New Mexico, and contrasts between evolution of plutonic and volcanic rocks

    USGS Publications Warehouse

    Johnson, C.M.; Czamanske, G.K.; Lipman, P.W.

    1989-01-01

    Plutonic rocks associated with the Latir volcanic field comprise three groups: 1) ???25 Ma high-level resurgent plutons composed of monzogranite and silicic metaluminous and peralkaline granite, 2) 23-25 Ma syenogranite, and alkali-feldspar granite intrusions emplaced along the southern caldera margin, and 3) 19-23 Ma granodiorite and granite plutons emplaced south of the caldera. Major-element compositions of both extrusive and intrusive suites in the Latir field are broadly similar; both suites include high-SiO2 rocks with low Ba and Sr, and high Rb, Nb, Th, and U contents. Moreover, both intermediateto siliciccomposition volcanic and plutonic rocks contain abundant accessory sphene and apatite, rich in rare-earth elements (REE), as well as phases in which REE's are essential components. Strong depletion in Y and REE contents, with increasing SiO2 content, in the plutonic rocks indicate a major role for accessory mineral fractionation that is not observed in volcanic rocks of equivalent composition. Considerations of the rheology of granitic magma suggest that accessory-mineral fractionation may occur primarily by filter-pressing evolved magmas from crystal-rich melts. More limited accessory-mineral crystallization and fractionation during evolution of the volcanic magmas may have resulted from markedly lower diffusivities of essential trace elements than major elements. Accessory-mineral fractionation probably becomes most significant at high crystallinities. The contrast in crystallization environments postulated for the extrusive and intrusive rocks may be common to other magmatic systems; the effects are particularly pronounced in highly evolved rocks of the Latir field. High-SiO2 peralkaline porphyry emplaced during resurgence of the Questa caldera represents non-erupted portions of the magma that produced the Amalia Tuff during caldera-forming eruption. The peralkaline porphyry continues compositional and mineralogical trends found in the tuff. Amphibole

  12. Deformation, Migmatization, and Intrusive Diatexites Along the Contact of the ~~470 Ma Vega Pluton, Helgeland Nappe Complex, North-Central Norway

    NASA Astrophysics Data System (ADS)

    Anderson, H.; Yoshinobu, A.; Barnes, C.

    2005-12-01

    The ~470 Ma (U/Pb) Vega pluton is a large, S-type granodiorite that intrudes folded marble, pelitic, psammitic, and calc-silicate rocks of the Helgeland Nappe Complex (HNC). Emplacement occurred at greather than or equal to 400 MPa based on the presence of kyanite in the contact aureole. The pluton contains a large volume of metasedimentary enclaves including calc-silicate, marble, diatexitic migmatite and probable mafic magmatic enclaves. Mapping coastal exposures of the northwestern contact revealed a ~2 km-wide structural aureole that is characterized by at least two phases of regional deformation (D1-2) and one emplacement-related deformation event (D3). D1 is an early fabric-forming event and is transposed by D2. D2 is defined by NW-trending, moderately plunging isoclines and boudinage with NW-plunging necklines. These structures are folded about E-W-trending, upright, open to tight D3 folds whose axial planes are sub-parallel to the pluton contact. Penetrative D3 structures become less pervasive >2 km northeast of the pluton contact although D3 structures occur outside of the aureole. A composite sheet of diatexite and granodiorite (50-150 m wide) intrudes the calc-silicate rocks 300 m north of the pluton contact. Granodiorite within the sheet is texturally and lithologically comparable to the Vega pluton. The contact between the diatexitic and granodioritic parts of the sheet is gradational over a few meters. Syn-magamtic shear bands and asymmetrical, top to the east dextral folds within the diatexite are parallel to F3 axial planes. Leucogranitic dikes intrude parallel to D3 foliation, locally cross cut D3 folds, and are boudined and folded about F3 axial planes. These observations suggest that emplacement of the diatexite-granodiorite sheet, the leucogranitic dikes and syn-magmatic deformation of these bodies was syn-tectonic with regional D3 deformation. This indicates that D1 and D2 were pre-470 Ma events and likely related to regional migmatization seen

  13. A 17 Ma onset for the post-collisional K-rich calc-alkaline magmatism in the Maghrebides: Evidence from Bougaroun (northeastern Algeria) and geodynamic implications

    NASA Astrophysics Data System (ADS)

    Abbassene, Fatiha; Chazot, Gilles; Bellon, Hervé; Bruguier, Olivier; Ouabadi, Aziouz; Maury, René C.; Déverchére, Jacques; Bosch, Delphine; Monié, Patrick

    2016-04-01

    Bougaroun is the largest pluton (~ 200 km2) in the 1200 km-long Neogene magmatic belt located along the Mediterranean coast of Maghreb. New U-Pb dating on zircons and K-Ar ages on whole rocks and separated minerals document its emplacement at 17 Ma within the Lesser Kabylian basement, a continental block that collided with the African margin during the Neogene. This Upper Burdigalian intrusion is therefore the oldest presently identified K-rich calc-alkaline massif in the whole Maghrebides magmatic lineament and marks the onset of its activity. The Bougaroun peraluminous felsic rocks display a very strong crustal imprint. Associated mafic rocks (LREE-enriched gabbros) have preserved the "orogenic" (subduction-related) geochemical signature of their mantle source. Older depleted gabbros cropping out at Cap Bougaroun are devoid of clear subduction-related imprint and yielded Ar-Ar hornblende ages of 27.0 ± 3.0 Ma and 23.3 ± 3.2 Ma. We suggest that they are related to the Upper Oligocene back-arc rifted margin and Early Miocene oceanic crust formation of the nearby Jijel basin, an extension of the Algerian basin developed during the African (Tethyan) slab rollback. The fact that the Bougaroun pluton intrudes exhumed Kabylian lower crustal units, mantle slices and flysch nappes indicates that the Kabylian margin was already stretched and in a post-collisional setting at 17 Ma. We propose a tectono-magmatic model involving an Early Miocene Tethyan slab breakoff combined with delamination of the edges of the African and Kabylian continental lithospheres. At 17 Ma, the asthenospheric thermal flux upwelling through the slab tear induced the thermal erosion of the Kabylian lithospheric mantle metasomatized during the previous subduction event and triggered its partial melting. We attribute the strong trace element and isotopic crustal signature of Bougaroun felsic rocks to extensive interactions between ascending mafic melts and the African crust underthrust beneath the

  14. Geochemical and Isotopic Study of a Plutonic Suite and Related Early Volcanic Sequences in the Southern Mariana Forearc

    NASA Astrophysics Data System (ADS)

    Johnson, J. A.; Hickey-Vargas, R.; Fryer, P.; Salters, V. J.; Reagan, M. K.

    2012-12-01

    In the southern Izu-Bonin-Mariana (IBM) arc, rocks associated with the early formation of the arc are found in the submerged forearc and forearc islands. Previous studies of the early arc have focused on volcanic rocks, which were recovered by drilling, dredging, submersible dives and from outcrops on the forearc islands. Intermediate and felsic plutonic arc-related rocks have been recovered in only a few locations across the entire arc and their study has revealed different petro