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Sample records for alkaline volcanic rocks

  1. Alkaline volcanic rocks from the Columbia Hills, Gusev crater, Mars

    USGS Publications Warehouse

    McSween, H.Y.; Ruff, S.W.; Morris, R.V.; Bell, J.F., III; Herkenhoff, K.; Gellert, Ralf; Stockstill, K.R.; Tornabene, L.L.; Squyres, S. W.; Crisp, J.A.; Christensen, P.R.; McCoy, T.J.; Mittlefehldt, D. W.; Schmidt, M.

    2006-01-01

    Irvine, Backstay, and Wishstone are the type specimens for three classes of fine-grained or fragmental, relatively unaltered rocks with distinctive thermal emission spectra, found as float on the flanks of the Columbia Hills. Chemical analyses indicate that these rocks are mildly alkaline basalt, trachybasalt, and tephrite, respectively. Their mineralogy consists of Na- and K-rich feldspar(s), low- and high-Ca pyroxenes, ferroan olivine, Fe-Ti (and possibly Cr) oxides, phosphate, and possibly glass. The texture of Wishstone is consistent with a pyroclastic origin, whereas Irvine and Backstay are lavas or possibly dike rocks. Chemical compositions of these rocks plot on or near liquid lines of descent for most elements calculated for Adirondack class rocks (olivine-rich basalts from the Gusev plains) at various pressures from 0.1 to 1.0 GPa. We infer that Wishstone-, Backstay-, and Irvine-class magmas may have formed by fractionation of primitive, oxidized basaltic magma similar to Adirondack-class rocks. The compositions of all these rocks reveal that the Gusev magmatic province is alkaline, distinct from the subalkaline volcanic rocks thought to dominate most of the planet's surface. The fact that differentiated volcanic rocks were not encountered on the plains prior to ascending Husband Hill may suggest a local magma source for volcanism beneath Gusev crater. Copyright 2006 by the American Geophysical Union.

  2. Magmatic evolution of the calk-alkaline rock in northern Kita-Hakkoda volcanic group, northern Honshu, Japan

    NASA Astrophysics Data System (ADS)

    Komatsu, S.; Ohba, T.

    2014-12-01

    Magmatic evolution in the northern Kita-Hakkoda, northern Honshu, Japan, was investigated from temporal variations of whole-rock chemistry and petrographic characteristics. The temporal variations are based on stratigrahic relation observed by geological survey and geomorphology. The volcanic activity of northern Kita-Hakkoda occurred about 0.4-0.2Ma. Rocks from northern Kita-Hakkoda are classified into two series on the AFM and the Miyashiro diagrams: calc-alkaline and tholeiite series. Calc-alkaline series rocks draw liner trends on Harker's diagrams of compatible elements (Ni, Cr, MgO), whereas the trends of tholeiitic series are convex downward. Some calc-alkaline rocks have disequilibrium mineral assemblages, e.g., coexistence of magnesian olivine and embayed quartz. The calc-alkaline rocks exhibit mineralogical features that indicate open system processes, e.g., coexistence of reversely zoned pyroxenes and normally zoned pyroxenes, dusty zoning in plagioclase. In contrast, no evidence for open system process is recorded in phenocrysts in the tholeiitic rocks. Previous studies (Sasaki et al.,1985; Ohba et al.,2009) accounted for the chemical variation of tholeiitic magma by crystallization differentiation. The calc-alkaline trend intersects the tholeiitic trend on Miyashiro diagram; therefore, the mafic endmember is tholeiitic basalt magma with a composition of the intersection. In this study, we conclude that the calc-alkaline series rocks were formed by magma mixing. Compared with the stratigraphic order, the calc-alkaline rocks changed in composition from SiO2 60wt% to SiO2 50wt% with a stratigraphic order, but the compositional variation accompanied a small fluctuation. Because the magma compositions of calc-alkaline magma were influenced by magma mixing, the chronological chemical variation was caused by temporal variation in mixing ratios of endmember magmas.

  3. Origin of metaluminous and alkaline volcanic rocks of the Latir volcanic field, northern Rio Grande rift, New Mexico

    NASA Astrophysics Data System (ADS)

    Johnson, Clark M.; Lipman, Peter W.

    1988-09-01

    Volcanic rocks of the Latir volcanic field evolved in an open system by crystal fractionation, magma mixing, and crustal assimilation. Early high-SiO2 rhyolites (28.5 Ma) fractionated from intermediate compositionmagmas that did not reach the surface. Most precaldera lavas have intermediate-compositions, from olivine basaltic-andesite (53% SiO2) to quartz latite (67% SiO2). The precaldera intermediate-composition lavas have anomalously high Ni and MgO contents and reversely zoned hornblende and augite phenocrysts, indicating mixing between primitive basalts and fractionated magmas. Isotopic data indicate that all of the intermediate-composition rocks studied contain large crustal components, although xenocrysts are found only in one unit. Inception of alkaline magmatism (alkalic dacite to high-SiO2 peralkaline rhyolite) correlates with, initiation of regional extension approximately 26 Ma ago. The Questa caldera formed 26.5 Ma ago upon eruption of the >500 km3 high-SiO2 peralkaline Amalia Tuff. Phenocryst compositions preserved in the cogenetic peralkaline granite suggest that the Amalia Tuff magma initially formed from a trace element-enriched, high-alkali metaluminous magma; isotopic data suggest that the parental magmas contain a large crustal component. Degassing of water- and halogen-rich alkali basalts may have provided sufficient volatile transport of alkalis and other elements into the overlying silicic magma chamber to drive the Amalia Tuff magma to peralkaline compositions. Trace element variations within the Amalia Tuff itself may be explained solely by 75% crystal fractionation of the observed phenocrysts. Crystal settling, however, is inconsistent with mineralogical variations in the tuff, and crystallization is thought to have occurred at a level below that tapped by the eruption. Spatially associated Miocene (15-11 Ma) lavas did not assimilate large amounts of crust or mix with primitive basaltic magmas. Both mixing and crustal assimilation processes

  4. Origin of metaluminous and alkaline volcanic rocks of the Latir volcanic field, northern Rio Grande rift, New Mexico

    USGS Publications Warehouse

    Johnson, C.M.; Lipman, P.W.

    1988-01-01

    Volcanic rocks of the Latir volcanic field evolved in an open system by crystal fractionation, magma mixing, and crustal assimilation. Early high-SiO2 rhyolites (28.5 Ma) fractionated from intermediate compositionmagmas that did not reach the surface. Most precaldera lavas have intermediate-compositions, from olivine basaltic-andesite (53% SiO2) to quartz latite (67% SiO2). The precaldera intermediate-composition lavas have anomalously high Ni and MgO contents and reversely zoned hornblende and augite phenocrysts, indicating mixing between primitive basalts and fractionated magmas. Isotopic data indicate that all of the intermediate-composition rocks studied contain large crustal components, although xenocrysts are found only in one unit. Inception of alkaline magmatism (alkalic dacite to high-SiO2 peralkaline rhyolite) correlates with, initiation of regional extension approximately 26 Ma ago. The Questa caldera formed 26.5 Ma ago upon eruption of the >500 km3 high-SiO2 peralkaline Amalia Tuff. Phenocryst compositions preserved in the cogenetic peralkaline granite suggest that the Amalia Tuff magma initially formed from a trace element-enriched, high-alkali metaluminous magma; isotopic data suggest that the parental magmas contain a large crustal component. Degassing of water- and halogen-rich alkali basalts may have provided sufficient volatile transport of alkalis and other elements into the overlying silicic magma chamber to drive the Amalia Tuff magma to peralkaline compositions. Trace element variations within the Amalia Tuff itself may be explained solely by 75% crystal fractionation of the observed phenocrysts. Crystal settling, however, is inconsistent with mineralogical variations in the tuff, and crystallization is thought to have occurred at a level below that tapped by the eruption. Spatially associated Miocene (15-11 Ma) lavas did not assimilate large amounts of crust or mix with primitive basaltic magmas. Both mixing and crustal assimilation processes

  5. Geochemistry and petrogenesis of the late Cretaceous potassic-alkaline volcanic rocks from the Amasya Region (northern Turkey)

    NASA Astrophysics Data System (ADS)

    Gülmez, Fatma; Genç, Can; Tüysüz, Okan; Karacık, Zekiye; Roden, Mike; Billor, Zeki; Hames, Willis

    2013-04-01

    The Cretaceous Lokman Formation (Alp, 1972) , is a volcano-sedimantary unit that comprises high- to ultra high-K alkaline volcanic rocks in Amasya Region (40°N, 35°E). The volcanic rocks expose as small outcrops and interfingered with pyroclastic and epiclastic rocks, and are classified as leucitite, tephriphonolite (LT), lamprophyres, trachytes and rarely andesites. LT and lamprophyres occur as dikes cutting each other, and rare lava flows. Trachytes are observed as small domes in the field and lots of pebbles and blocks within the clastic deposits derived from the domes. Samples of LT comprise lct+cpx (diopsite)+plg+mag+ap and classified as leucite-basanite mineralogically and tephri-phonolite geochemically. Ar-Ar age dating from leucites show that the leucite-bearing volcanic activity formed 75.6±3.7 Ma. The mineralogic composition of melanokratic lamprophyre dikes are represented by Kfs+cpx+mica+ap+mag. They defined geochemically as phono-tephrite and phonolite. The Ar-Ar plateau ages from the phlogopites from two different outcrops are 76.78 and 77.48 Ma. The main minerals of trachytic rocks are amp + bt + pl + Kfs + spn + ap +opq. They are classified as alkaline trachyandesite, geochemically. Radiometric age data from Kfs minerals reveal that the trachytic volcanism occurred 75.83±0.09 Ma. Except one andesitic sample, lamprophyres and trachytes of the Lokman Formation are the high- and ultra high-K and alkaline rocks. LT and lamprophyres are characterized by relatively high MgO (3.25-7.04 wt.%), K2O (4.34-6.54 wt.%), Na2O (3.42-5.74 wt.%). Total analcimization of leucite minerals let to decreasing its K2O, and increasing the Na2O contents. Therefore, K2O/Na2O values for LT and the lamprophyres (0.92-2.27) are relatively low. Trachytic suite is also high-K and alkaline in nature. On MORB normalized plots, all of the volcanic rocks from Lokman Formation display enrichment of LIL elements significantly relative to HFSE, and depletions of Nb-Ta and Ti

  6. Age, geochemical characteristics and petrogenesis of Cenozoic intraplate alkaline volcanic rocks in the Bafang region, West Cameroon

    NASA Astrophysics Data System (ADS)

    Tchuimegnie Ngongang, Nicaise Blaise; Kamgang, Pierre; Chazot, Gilles; Agranier, Arnaud; Bellon, Hervé; Nonnotte, Philippe

    2015-02-01

    The origin of the volcanism in the Cameroon Volcanic Line and the nature of its mantle sources are still highly controversial. We present major and trace element compositions as well as Sr-Nd-Pb-Hf isotopic results on mafic and intermediate lavas from the Bafang area in the central part of the Cameroon Volcanic Line. The lavas range from basanites and basalts to hawaiites and mugearites with an alkaline affinity and were emplaced between 10 and 6 Ma ago. The evolution from basalts and basanites to more differentiated rocks involved fractionation of olivine, clinopyroxene and Fe-Ti oxides, but the isotopic compositions show that crustal contamination processes affected some magmas during their ascent in the crust. Basalts and basanites originated from a garnet-bearing mantle source and their differences are mostly due to variable degrees of partial melting. The isotopic composition of the uncontaminated samples imply the participation of three distinct mantle components, the depleted MORB mantle (not dominant), an enriched component and a Pb radiogenic component similar to the source of the Mount Cameroon. Combined with previously published isotopic data from the Cameroon Volcanic Line, our new results indicate that the source of the volcanism mostly reside in the lithospheric mantle and is different from what can be expected from the melting of a mantle accreted from or modified during the emplacement of the St. Helena mantle plume.

  7. Mobility of elements during K-metasomatism of volcanic rocks by alkaline, saline brines

    SciTech Connect

    Chapin, C.E. )

    1992-01-01

    Silicic ignimbrites and interbedded mafic lavas of Oligocene age were altered by alkaline, saline brines in the Popotosa basin of the Rio Grande rift near Socorro, New Mexico. Alteration was toward a fine-grained assemblage of adularia + hematite [+-] quartz irrespective of initial rock composition. Elevated [delta][sup 18]O and the occurrence of zeolites, gypsum, and salt casts in overlying play a deposits indicates that the altering fluids were basin brines. Preliminary analysis of secondary inclusions in fractured quartz phenocrysts indicates temperatures near 100 C and salinities near 20 wt. % NaCl equivalent. To test element mobility, pairs of fresh and altered samples from each of 7 ignimbrite units plus 4 samples of interbedded mafic lavas were analyzed by XRF, INAA, and AA. The elements showing the greatest mobility during alteration of ignimbrites are listed below along with their enrichment factors (altered rock/fresh rock). Ignimbrites: enriched--K[sub 2]O 1.99, Rb 1.89, Ba 1.43, As 12.14, Sb 18.30, Pb 1.23; depleted--Na[sub 2]O 0.25, MgO 0.57, CaO 0.27, MnO 0.50, P[sub 2]O[sub 5] 0.75, Sr 0.54, Li 0.57, U 0.78, Br 0.67, Cu 0.90, Zn 0.69. The dramatic enrichment of As and Sb in both ignimbrites and mafic lavas indicates that these elements are highly mobile in oxidizing basin brine systems. K-metasomatism is a common type of alteration in rift basins, detachment terranes, aquifers through which brines have migrated.

  8. Alkaline igneous rocks

    SciTech Connect

    Fitton, J.G.; Upton, B.G.J.

    1987-01-01

    In this volume, an international team of scientists provides an up-to-date overview of the nature, origin, and evolution of alkaline magmas. Particular attention is paid to carbonatites, lamprophyres, and lamproites which are rock suites of current interest not recently reviewed elsewhere. Recent work on the classical alkaline provinces of East Africa, South Greenland, and the Kola Peninsula is included together with reviews of other areas of alkaline magmatism in North and South America, East Greenland, Europe, West Africa, and the ocean basins. Other papers discuss the impact of experimental isotopic and geochemical studies of the petrogenesis of alkaline rocks. This book will be of interest to petrologists and geochemists studying alkaline igneous rocks, and to other earth scientists as a reference on the rapidly expanding field of igneous petrology.

  9. Crystal accumulation and compositional trends in a calc-alkaline batholith: implications for correlation of plutonic and volcanic rocks

    NASA Astrophysics Data System (ADS)

    Barnes, C. G.; Coint, N.

    2013-12-01

    The Wooley Creek batholith is a tilted, calc-alkaline intrusive complex in the Klamath Mountain province, California, that can be divided into two main zones: lower (~159.2 × 0.2 Ma) and upper (~158.2 × 0.3 Ma), separated by a central transition zone. The lower zone consists of multiple intrusive units of gabbro through tonalite, with minor mafic synplutonic dikes and intrusive melagabbro and pyroxenite. Major and trace element data plot in two groups: a mafic group that encompasses pyroxenite to diorite, and a tonalitic group. For each group, Mg/Fe in augite was used to determine the approximate composition of equilibrium melt and then major element mass balance was used to calculate proportions of cumulate phases and melt. For the mafic group, no single parental magma can be identified, which is consistent with assembly via many magma batches. However, the most mafic rocks were derived from basaltic andesite magmas and represent 30 to 100% cumulate augite + opx × plagioclase × olivine. Interstitial melt in the tonalitic group was dacitic, and mass balance indicates from 30 to 80% cumulate pyroxenes + plagioclase × accessory apatite and Fe-Ti oxides. The parental magma was probably silicic andesite. The upper zone varies gradationally from structurally low quartz diorite to uppermost granite. Upper zone magmas ';leaked' to form dacitic to rhyodacitic ';roof dikes'. Previous work (Coint et al., Geosphere, in press) showed that the upper zone formed from an approximately homogeneous magma body and that compositional variation was related to upward percolation of melt. Mass balance supports this interpretation and indicates that (1) the parental magmas were andesitic, (2) structurally low rocks are 15 to 65 % cumulate hornblende + plagioclase × pyroxene, and (3) high-level granite and granodiorite are the fractionated products of this accumulation. These results show that the upper zone is a good example of fractional crystallization within a moderate

  10. The relationship between adakitic, calc-alkaline volcanic rocks and TTGs: implications for the tectonic setting of the Karelian greenstone belts, Baltic Shield

    NASA Astrophysics Data System (ADS)

    Samsonov, A. V.; Bogina, M. M.; Bibikova, E. V.; Petrova, A. Yu.; Shchipansky, A. A.

    2005-01-01

    Two types of coeval acid-intermediate rocks with different petrological, geochemical and isotopic features have been discovered among volcanic rocks and surrounding synkinematic tonalite-trondhjemite-granodiorite (TTG) plutons of Late Archaean greenstone belts in the Karelian granite-greenstone terrane. Type-1 rocks comprise trondhjemites and sub-volcanic, occasionally volcanic dacite-rhyolite rocks. They are characterized by high Sr, low Y and HREE contents, high Sr/Y ratios, and strongly fractionated REE patterns with no significant positive or negative Eu anomaly. Initial ɛNd is positive, indicating a generation from juvenile source with little or no contribution of ancient continental crust. Type 2 is represented by diorite-granodiorites and calc-alkaline basalt-andesite-dacite-rhyolite (BADR) series. As compared to type 1, these rocks differ by their lower Sr, higher Y and HREE contents, lower Sr/Y ratios and less fractionated HREE patterns with negative Eu anomalies. Initial ɛNd varies from negative to positive values, thus indicating a variable contribution of sialic crust. Geochemistry of the two magmatic series suggests their formation in a convergent plate margin setting. The type-1 rocks resemble Phanerozoic adakites, which represent slab-derived melts contaminated by overlying mantle wedge. The type-2 rocks resemble BADR series, which were derived from a mantle wedge metasomatized by slab-derived fluids and melts, with subsequent variable crustal contamination. The spatial distribution of these two types of magmatic series defines the asymmetry of the studied granite-greenstone structures, which presumably reflects the primary lateral zoning of island arc formed under specific thermal conditions in the Archaean mantle. Adakite melts upraised to the surface in the frontal part of the island arc, where mantle wedge was thin, showing no or little interaction with metasomatized mantle, and formed adakite-type plutonic and sub-volcanic rocks. At greater

  11. The Volatile Element Evolution of Intra-plate Alkaline Rocks as Recorded by Apatite: An Example from the Hegau Volcanic Field (Southwest Germany)

    NASA Astrophysics Data System (ADS)

    Von Der Handt, A.; Rahn, M. K. W.; Wang, L. X.; Marks, M. A. W.

    2014-12-01

    The role of volatiles in the petrogenesis of alkaline intra-plate magmas has been the subject of an increasing number of experimental studies. The study of naturally occurring rocks and their volatile contents is often complicated by syn- and post-eruptive degassing and alteration processes. Minerals that incorporate volatiles into their structure such as apatites are often more faithful recorders of the pre-eruptive volatile budget. The Hegau volcanic field in Southwest Germany is part of the Central European Volcanic Province, lies around 60-70 km to the east of the Upper Rhine graben and of Miocene age. Three main lithological units can be distinguished (1) olivine melilites (2) phonolites and (3) the "Deckentuff" series referring to a series of diatreme-filling pipe breccias and lapilli tuff layers. Carbonatites occur subordinately in the Hegau province. Earlier radiometric age dating suggested distinct phases of volcanic activity of Deckentuffs, melilites and phonolites with little overlap, but new apatite fission-track and (U-Th)/He age data suggest a synchronous activity. Apatite is an abundant accessory phase in the Deckentuff and phonolite series and we investigated its major, trace and volatile element composition by EPMA, SIMS and cathodoluminescence imaging. Pronounced core-rim zoning of apatite in places attests that diffusional equilibration was very limited and they likely retained their primary compositions. This allows us to trace the entire magmatic evolution of the Hegau province from its most primitive to most evolved products as well as resolve it in time by combining age dating with compositional analysis. Apatite compositions fall along the OH-F join with low Cl-contents (<0.5 wt%). Volatile contents (Cl, OH, S) are highest in most primitive compositions and decrease with further evolution while F increases. Multiple magmatic cycles can be discerned with a general trend to the more evolved phonolite compositions toward the end of volcanic

  12. Chemical characteristics of the volcanic gases from Nyiragongo lava lake and the generation of CH 4-rich fluid inclusions in alkaline rocks

    NASA Astrophysics Data System (ADS)

    Gerlach, T. M.

    1980-10-01

    Methods used previously to remove compositional modifications from volcanic gas analyses for Mount Etna and Erta'Ale lava lake have bean employed to estimate the gas phase composition at Nyiragongo lava lake, based on samples obtained in 1959. H 2O data were not reported in 11 of the 13 original analyses. The restoration methods have been used to estimate the H 2O contents of the samples and to correct the analyses for atmospheric contamination, loss of sulfur and for pre- and pest-collection oxidation of H 2S, S 2, and H 2. The estimated gas compositions are relatively CO 2-rich, low in total sulfur and reduced. They contain approximately 35-50% CO 2 45-55% H 2O, 1-2% SO 2, 1-2% H 2., 2-3% CO, 1.5-2.5% H 2S, 0.5% S 2 and 0.1% COS over,he collection temperature range 102° to 960° C. The oxygen fugacities of the gases are consistently about half an order of magnitude below quartz-magnetite-fayalite. The low total sulfur content and resulting low atomic S/C of the Nyiragongo gases appear to be related to the relatively low fO 2 of the crystallizing lava. At temperatures above 800°C and pressures of 1-1.5 k bar, the Nyiragongo gas compositions resemble those observed in primary fluid inclusions believed to have formed at similar temperatures and pressures in nephelines of intrusive alkaline rocks. Cooling to 300°C, with fO 2 buffered by the rock, results in gas compositions very rich in CH 4 (50-70%) and resembling secondary fluid inclusions formed at 200-500°C in alkaline rocks. Below 600°C the gases become supersaturated in carbon as graphite. These inferences are corroborated by several reports of hydrocarbons in plutonic alkaline rocks, and by the presence of CH 4-rich waters in Lake Kivu — a lake on the flanks of Nyiragongo volcano.

  13. Shoshonite and sub-alkaline magmas from an ultrapotassic volcano: Sr-Nd-Pb isotope data on the Roccamonfina volcanic rocks, Roman Magmatic Province, Southern Italy

    NASA Astrophysics Data System (ADS)

    Conticelli, Sandro; Marchionni, Sara; Rosa, Davide; Giordano, Guido; Boari, Elena; Avanzinelli, Riccardo

    2009-01-01

    The Roccamonfina volcano is characterised by two stages of volcanic activity that are separated by volcano-tectonic caldera collapses. Ultrapotassic leucite-bearing rocks are confined to the pre-caldera stage and display geochemical characteristics similar to those of other volcanoes in the Roman Province. After the major sector collapse of the volcano, occurred at ca. 400 ka, shoshonitic rocks erupted from cinder cones and domes both within the caldera and on the external flanks of the pre-caldera Roccamonfina volcano. On the basis of new trace element and Sr-Nd-Pb isotope data, we show that the Roccamonfina shoshonitic rocks are distinct from shoshonites of the Northern Roman Province, but are very similar to those of the Neapolitan volcanoes. The last phases of volcanic activity erupted sub-alkaline magmas as enclaves in trachytic domes, and as lavas within the Monte Santa Croce dome. Ultrapotassic rocks of the pre-caldera composite volcano are plagioclase-bearing leucitites characterised by high levels of incompatible trace elements with an orogenic signature having troughs at Ba, Ta, Nb, and Ti, and peaks at Cs, K, Th, U, and Pb. Initial values of 87Sr/86Sr range from 0.70926 to 0.70999, 143Nd/144Nd ranges from 0.51213 to 0.51217, while the lead isotope rations vary between 18.788-18.851 for 206Pb/204Pb, 15.685-15.701 for 207Pb/204Pb, and 39.048-39.076 for 208Pb/204Pb. Shoshonites show a similar pattern of trace element depletions and enrichments to the earlier ultrapotassic leucite-bearing rocks but have a larger degree of differentiation and lower concentrations of incompatible trace elements. On the other hand, shoshonitic rocks have Sr, Nd, and Pb isotopes consistently different than pre-caldera ultrapotassic leucite-bearing rocks. 87Sr/86Sr ranges from 0.70665 to 0.70745, 143Nd/144Nd ranges from 0.51234 to 0.51238, 206Pb/204Pb ranges from 18.924 to 19.153, 207Pb/204Pb ranges from 15.661 to 15.694, and 208Pb/204Pb ranges from 39.084 to 39.212. High-K calc-alkaline

  14. The Quaternary calc-alkaline volcanism of the Patagonian Andes close to the Chile triple junction: geochemistry and petrogenesis of volcanic rocks from the Cay and Maca volcanoes (˜45°S, Chile)

    NASA Astrophysics Data System (ADS)

    D'Orazio, M.; Innocenti, F.; Manetti, P.; Tamponi, M.; Tonarini, S.; González-Ferrán, O.; Lahsen, A.; Omarini, R.

    2003-08-01

    Major- and trace-element, Sr-Nd isotopes, and mineral chemistry data were obtained for a collection of volcanic rock samples erupted by the Cay and Maca Quaternary volcanoes, Patagonian Andes (˜45°S, Chile). Cay and Maca are two large, adjacent stratovolcanoes that rise from the Chiloe block at the southern end of the southern volcanic zone (SVZ) of the Andes. Samples from the two volcanoes are typical medium-K, calc-alkaline rocks that form two roughly continuous, largely overlapping series from subalkaline basalt to dacite. The overall geochemistry of the samples studied is very similar to that observed for most volcanoes from the southern SVZ. The narrow range of Sr-Nd isotope compositions ( 87Sr/ 86Sr=0.70389-0.70431 and 143Nd/ 144Nd=0.51277-0.51284) and the major- and trace-element distributions indicate that the Cay and Maca magmas differentiated by crystal fractionation without significant contribution by crustal contamination. This is in accordance with the thin (<30 km), relatively young (Paleozoic or more recent) continental crust beneath the volcanoes. The nature of the subduction-derived materials involved in the genesis of the Cay and Maca magmas is investigated by means of the relative concentration of fluid mobile (e.g. Ba) and fluid immobile (e.g. Nb, Ta, Zr, Y) elements and other relevant trace-element ratios (e.g. Sr/Y). The results indicate that small amounts (<1 wt%) of both subducted sediments and slab-released fluids were added to the mantle sources of the Cay and Maca volcanoes and that, despite the very young age (<10 Ma) of the oceanic lithosphere subducted beneath the volcanoes, slab melts were not involved in the magma genesis. Notwithstanding the proximity of the Cay and Maca magma sources to the northern edge of the slab window generated by the subduction of the Chile ridge under the South American plate, we did not find any geochemical evidence for a contribution of a subslab asthenospheric mantle. However, this mantle has been used

  15. Alkaline volcanisms in the Proto-Kuril forearc

    NASA Astrophysics Data System (ADS)

    Yutani, T.; Hirano, N.

    2015-12-01

    The Nemuro Group in the northeasternmost part of Japan represents forearc basin deposits of the Proto-Kuril arc that consist of Upper Cretaceous-Paleocene sedimentary rocks with andesitic volcaniclastics and alkaline lavas. Their occurrence in this setting is unusual because such alkaline lavas and intrusions are not commonly found in forearc environments. Here, we report new petrological and geological data to discuss the nature of magmatic process involved in their petrogenesis. Pillow and massive lava flows represent subaqueous volcanic activity, and the occurrence of inter-pillow sedimentary units indicates their eruption on unconsolidated sediments of the lower Nemuro Group. Sill intrusions with layered structures and thicknesses ranging from 10 to 130 m are also common widely distributed in the Nemuro Group. Major and trace element chemistry and mineralogical data distinguish the analyzed samples as K-rich alkaline rocks with low TiO2 or Nb contents, analogous to island arc-like tholeiites. These K-rich alkaline rocks can be classified into two groups of shoshonites: shoshonites containing olivine phenocrysts and intruding into the lower Nemuro Group (Group 1), and shoshonites with no olivine and making up the middle part of the Nemuro Group (Group 2). Group 1 shoshonites have higher MgO, Cr and Ni contents than those of Group 2. The bulk-rock composition of Group 2, which has lower MgO contents, shows higher SiO2 than that of Group 1. Such compositional differences possibly represent fractional crystallization of magmas between Groups 1 and 2. Based on the limited available data, we conclude that these alkaline rocks intruding into the Nemuro Group represent arc-shoshonites, and that the Group 1 magmas underwent fractional crystallization to produce the Group 2 magmas.

  16. Cenozoic volcanic rocks of Saudi Arabia

    USGS Publications Warehouse

    Coleman, R.G.; Gregory, R.T.; Brown, G.F.

    2016-01-01

    The historical record of volcanic activity in Saudi Arabia suggests that volcanism is dormant. The harrats should be evaluated for their potential as volcanic hazards and as sources of geothermal energy. The volcanic rocks are natural traps for groundwater; thus water resources for agriculture may be significant and should be investigated.

  17. Alkaline basaltic volcanism of the Sea of Japan and the Philippine Sea: Similar and distinct geochemical and genetic features

    NASA Astrophysics Data System (ADS)

    Lelikov, E. P.; Emelyanova, T. A.

    2016-05-01

    The results of study of the deep sources of volcanic rocks from the Sea of Japan and the Philippine Sea with continental and oceanic basements, respectively, are presented. This problem is considered with the example of alkaline volcanic rocks of the Middle Miocene to Pliocene complex of the Sea of Japan and the Eocene-Oligocene Urdaneta Plateau of the Philippine Sea. The rocks have a similar geochemistry typical of OIBs, which indicates their deep (plume) origin. The presence of the Oligocene calc-alkaline volcanic rocks, which were formed prior to the marginal sea volcanism in the Sea of Japan, however, is the main difference in volcanism of the Sea of Japan from that of the Urdaneta Plateau, and this is explained by the different basements of these seas.

  18. The Santiago Peak Volcanic rocks of the Peninsular Ranges batholith, Southern California: volcanic rocks associated with coeval gabbros

    NASA Astrophysics Data System (ADS)

    Tanaka, H.; Smith, T. E.; Huang, C. H.

    1984-03-01

    Analyses of the latest Jurassic Santiago Peak volcanic rocks from the western zone of the Peninsular Ranges batholith reveal the existence of two independent groups; one comprising basalts and andesites of the island arc tholeiitic series, and the second made up of the dacites and rhyolites of the subalkaline (calc-alkaline?) series or silicic series. The basalts and andesites have V, Co and Ni contents similar to those estimated for the residual melts in equilibrium with the Peninsular Ranges gabbros. This fact together with the tholeiitic nature of the gabbros and the intimate spatial and temporal relationship between the SPV and the gabbros suggests that the basalts and andesites had a common origin with the gabbros. The mafic volcanism and plutonism seems to have occurred in a youthful island arc and the silicic volcanism in a mature island arc or a continental margin.

  19. Fluid and rock interaction in permeable volcanic rock

    SciTech Connect

    Lindley, J.I.

    1985-02-01

    Four types of interrelated changes -geochemical, mineralogic, isotopic, and physical - occur in Oligocene volcanic units of the Mogollon-Datil volcanic field, New Mexico. These changes resulted from the operation of a geothermal system that, through fluid-rock interaction, affected 5 rhyolite ash-flow tuffs and an intercalated basaltic andesite lava flow causing a potassium metasomatism type of alteration. (1) Previous studies have shown enrichment of rocks in K/sub 2/O as much as 130% of their original values at the expense of Na/sub 2/O and CaO with an accompanying increase in Rb and decreases in MgO and Sr. (2) X-ray diffraction results of this study show that phenocrystic plagioclase and groundmass feldspar have been replaced with pure potassium feldspar and quartz in altered rock. Phenocrystic potassium feldspar, biotite, and quartz are unaffected. Pyroxene in basaltic andesite is replaced by iron oxide. (3) delta/sup 18/O increases for rhyolitic units from values of 8-10 permil, typical of unaltered rock, to 13-15 permil, typical of altered rock. Basaltic andesite, however, shows opposite behavior with a delta/sup 18/ of 9 permil in unaltered rock and 6 permit in altered. (4) Alteration results in a density decrease. SEM revealed that replacement of plagioclase by fine-grained quartz and potassium feldspar is not a volume for volume replacement. Secondary porosity is created in the volcanics by the chaotic arrangement of secondary crystals.

  20. Mechanism of Mesozoic Volcanism in Northeastern China: Evidence from New Distribution Maps of Volcanic Rock and Petrogenesis of Acid Rock in Deep Songliao Basin

    NASA Astrophysics Data System (ADS)

    Meng, Fanchao; Liu, Jiaqi; Rasskazov, Sergei; Gao, Jinliang; Zhang, Yutao

    2014-05-01

    Northeastern China is located in the eastern segment of the Central Asian Orogenic belt, which is characterized by widespread Mesozoic volcanic rocks. At present, there are two different opinions concerning the mechanism of volcanism: one proposal is that volcanism was associated with the closure of Mongolia-Okhotsk (MO) Bay, but another suggestion is that the Mesozoic volcanism is controlled by the subduction of Paleo-Pacific plate. However, most studies have mainly focused on the Mesozoic volcanic rocks in Great Xing'an Range(GXR), lack of evidence from Songliao Basin. In order to exactly reveal the mechanism of volcanic rocks in Northeastern China, five new distribution maps of volcanic rocks in Northeast China are drawn and petrogenesis of Mesozoic volcanic rocks in Songliao Basin are obtained. Based on 1: 50000 geological maps, five distribution maps of volcanic rocks (1:2000000) in Northeastern China are recompiled: Early Jurassic, Middle Jurassic, Late Jurassic, Early Cretaceous, and Late Cretaceous. The Early Jurassic volcanic rocks predominantly occur in the eastern Heilongjiang-Jilin province, with minor in Manzhouli in the western. The Middle Jurassic volcanic rocks are mainly founded in the western Liaoning provinces. The Early-Middle Jurassic volcanic rocks(170-146Ma) belong chemically to sub-alkaline series, implying an active continental margin setting. The Late Jurassic volcanic rocks(146-122Ma) mainly occur in the western GXR area, and the magma derived from enriched lithospheric mantle which is closely associated with the subduction of MO plate. The Early Cretaceous volcanic rocks(122-102Ma), widespread in GXR and Songliao basin, are mainly acid and erupt in extensional setting, probably associated with the lithospheric thinning and asthenospheric mantle upwelling caused by subduction of the Paleo-Pacific plate beneath eastern China. Constraints on the timing of MO Bay closure and the motion direction of Paleo-Pacific plate, we infer that:(1) In

  1. Petromagnetic characteristics of Cameroon Line volcanic rocks

    NASA Astrophysics Data System (ADS)

    Ubangoh, R. U.; Pacca, I. G.; Nyobe, J. B.; Hell, J.; Ateba, B.

    2005-04-01

    Volcanic rock samples collected from 154 sites on the Cameroon Line (CL) have been analysed to study their petromagnetic characteristics. Thermomagnetic experiments and electron microscope observations on the samples indicate that the principal magnetic mineral and carrier of Natural Remanent Magnetisation (NRM) in these rocks is titanomagnetite rich in titanium. These also indicate that the level and stability of magnetisation are dependent on the quantity and composition of the magnetic minerals (which are controlled by the composition of the original liquid magma), their oxidation states and grain sizes. The contribution of high- and low-temperature oxidation observed in some of the magnetic minerals was that of increasing their magnetic resistance. Rocks with abundant ilmenite lamellae in their titanomagnetite showed increased magnetic resistance during demagnetisation experiments. In the analysis, the samples exhibited a considerable magnetisation spectrum indicating that most of them are strongly magnetic. The general tendency in experimental magnetism of an increase in magnetic resistance with decrease in grain sizes of discrete magnetic minerals is not respected in this natural system because of the effects of the presence of many ilmenite lamellae and mini-fractures in some of the titanomagnetite grains. In this way, the conditions of low crystallisation temperature, high fO2 and high PH 2O , which were the conditions for the crystallisation of the most stable rocks (the hawaiites) on the line, were the conditions favourable for the acquisition of a stable magnetisation in the region. The low Curie temperatures (74-250 °C) found for a majority of the rocks indicate that the lower crust in the region and the upper mantle could be nonmagnetic. The high regional negative magnetic anomaly over the Cameroon Line that is not consistent with the small depth previewed by the Curie system and by the paramagnetic effect of the acid volcanic rocks in the region is

  2. Petrogenesis of coeval silica-saturated and silica-undersaturated alkaline rocks: Mineralogical and geochemical evidence from the Saima alkaline complex, NE China

    NASA Astrophysics Data System (ADS)

    Zhu, Yu-Sheng; Yang, Jin-Hui; Sun, Jin-Feng; Zhang, Ji-Heng; Wu, Fu-Yuan

    2016-03-01

    A combined study of zircon U-Pb ages, mineral chemistry, whole-rock elements and Sr-Nd-Hf isotopes was carried out for the Saima alkaline complex in the northeastern China, in order to investigate the source and petrogenesis of coeval silica-saturated and silica-undersaturated alkaline rocks. The Saima alkaline complex consists of nepheline syenites, quartz-bearing syenites and alkaline volcanic rocks (i.e., phonolite and trachyte), with minor mafic dikes and carbonatitic veins. Laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) and secondary ion mass spectrometry (SIMS) zircon U-Pb dating gives consistent ages of 230-224 Ma for these rocks, suggesting that they are coeval. All alkaline rocks in the Saima complex are enriched in large ion lithophile elements (LILEs) and light rare earth elements (LREEs), and depleted in high field strength elements (HFSEs) with significant negative Nb, Ta and Ti anomalies. Geochemical data and Sr-Nd-Hf isotopic compositions indicate that the various alkaline rocks were all derived from partial melting of an ancient, re-enriched lithospheric mantle in the garnet stability field, but experienced variable siliceous- or carbonate-rich crustal contamination. Based on petrographic evidence, mineral compositions, and whole-rock geochemical data, two distinct magmatic evolutionary trends are proposed to explain the coeval emplacement of the various rock types within the Saima alkaline complex. The silica-undersaturated rocks (nepheline syenites and phonolites) result from alkali feldspar + apatite + titanite crystal fractionation of an alkaline mafic parental melt combined with assimilation of marine carbonate host rocks. In contrast, the generation of silica-saturated rocks (quartz-bearing syenites and trachytes) may be attributed to subsequent and continued clinopyroxene + apatite + biotite crystal fractionation coupled with assimilation of siliceous sediments.

  3. Petrogenesis of Cenozoic volcanic rocks in the NW sector of the Gharyan volcanic field, Libya

    NASA Astrophysics Data System (ADS)

    Lustrino, Michele; Cucciniello, Ciro; Melluso, Leone; Tassinari, Colombo C. G.; dè Gennaro, Roberto; Serracino, Marcello

    2012-12-01

    The north-western sector of the Gharyan volcanic field (northern Libya) consists of trachytic-phonolitic domes emplaced between ~ 41 and 38 Ma, and small-volume mafic alkaline volcanic centres (basanites, tephrites, alkali basalts, hawaiites and rare benmoreites) of Middle Miocene-Pliocene age (~ 12-2 Ma). Two types of trachytes and phonolites have been recognized on the basis of petrography, mineralogy and geochemistry. Type-1 trachytes and phonolites display a smooth spoon-shaped REE pattern without negative Europium anomalies. Type-2 trachytes and phonolites show a remarkable Eu negative anomaly, higher concentration in HFSE (Nbsbnd Tasbnd Zrsbnd Hf), REE and Ti than Type-1 rocks. The origin of Type-1 trachytes and phonolites is compatible with removal of clinopyroxene, plagioclase, alkali feldspar, amphibole, magnetite and titanite starting from benmoreitic magmas, found in the same outcrops. Type-2 trachytes and phonolites could be the result of extensive fractional crystallization starting from mafic alkaline magma, without removal of titanite. In primitive mantle-normalized diagrams, the mafic rocks (Mg# = 62-68, Cr up to 514 ppm, Ni up to 425 ppm) show peaks at Nb and Ta and troughs at K. These characteristics, coupled with low 87Sr/86Sr(i) (0.7033-0.7038) and positive ɛNd (from + 4.2 to + 5.3) features typical of the mafic anorogenic magmas of the northern African plate and of HIMU-OIB-like magma in general. The origin of the mafic rocks is compatible from a derivation from low degree partial melting (3-9%) shallow mantle sources in the spinel/garnet facies, placed just below the rigid plate in the uppermost low-velocity zone. The origin of the igneous activity is considered linked to passive lithospheric thinning related to the development of continental rifts like those of Sicily Channel (e.g., Pantelleria and Linosa) and Sardinia (e.g., Campidano Graben) in the Central-Western Mediterranean Sea.

  4. Volcanic Rocks As Targets For Astrobiology Missions

    NASA Astrophysics Data System (ADS)

    Banerjee, N.

    2010-12-01

    Almost two decades of study highlight the importance of terrestrial subaqueous volcanic rocks as microbial habitats, particularly in glass produced by the quenching of basaltic lava upon contact with water. On Earth, microbes rapidly begin colonizing glassy surfaces along fractures and cracks exposed to water. Microbial colonization of basaltic glass leads to enhanced alteration through production of characteristic granular and/or tubular bioalteration textures. Infilling of formerly hollow alteration textures by minerals enable their preservation through geologic time. Basaltic rocks are a major component of the Martian crust and are widespread on other solar system bodies. A variety of lines of evidence strongly suggest the long-term existence of abundant liquid water on ancient Mars. Recent orbiter, lander and rover missions have found evidence for the presence of transient liquid water on Mars, perhaps persisting to the present day. Many other solar system bodies, notably Europa, Enceladus and other icy satellites, may contain (or have once hosted) subaqueous basaltic glasses. The record of terrestrial glass bioalteration has been interpreted to extend back ~3.5 billion years and is widespread in modern oceanic crust and its ancient metamorphic equivalents. The terrestrial record of glass bioalteration strongly suggests that glassy or formerly glassy basaltic rocks on extraterrestrial bodies that have interacted with liquid water are high-value targets for astrobiological exploration.

  5. K-alkaline rocks and lamproites of Tomtor massif

    NASA Astrophysics Data System (ADS)

    Vladykin, Nikolai

    2015-04-01

    Tomtor massif of the largest volcano-plutonic deep alkaline-carbonatite massifs world central type. Area of massif occupy 240 km2 and carbonatites stock is 40 km2. The super large deposit of Nb, TR, Y, Sc, Sr ,REE (Frolov et al. 2001)is found within the massif. The numerical publication are devoted to the ore mineralization there. But the geological struc-ture of the massif and the chemistry of its constituting rocks are not well understood. We obtained new ages based on U-Pb zircon and mica Ar-Ar method (Kotov, Vladykin et al. 2014 Vladykin et al. 2015). The massif was created in 2 stages: 700 and 400 Ma. We (Vla-dykin et al 1998) found rocks of lamproite series and proposed a new scheme of magmatism and the ore.genesis (Vladykin 2007, 2009). Biotite - pyroxenite, peridotite originated in first stage and then intruded iolites, nepheline and alkali syenite. Syenites occupy 70% of -massif and contain 12-13% K2O and 2-4% Na2O showing the K-alkaline-ultramafic nature of Tomtor volcano-plutonic massif (Vladykin 2009). The first stage was accomplished by nelsonitov calcite, dolomite and ankerite carbonatites. Second stage (400Ma) volcanics picrite - lamproite veins and eruptive breccias meli-lite, melanephelinites, tinguaites appered. These rocks are cut by carbonatites of second stage. It was finished by intensive explosive eruption of a silicate (lamproite) tuffs lavobrec-cia kimberlite formed Ebelyakhdiamondiferous placer, melilite rocks in diatremes (feeders), as well as carbonate-phosphate (kamaforite) explosive tuffs with siderite ores. This carbona-tite complex is preserved within the subsidence caldera. Tuff eruption in conjunction with gas and hydrothermal activity determined its rare metal mineralization. These rocks contain to: Nb- 21%, TR-15%, Y-1.5%, Sc-1%, Zr- 0,5% Zn-, Sr-6%, Ti-8%, Ba-4%, V - 8000 ppm, Be- 300 ppm, Ga- 80 ppm, Cr- 1200ppm, Ni- 230 ppm, Mo- 145 ppm, Pb- 4300 ppm, Th- 1500 ppm, U-193 ppm. Picrite - olivine (rare leucite) lamproite and

  6. Seychelles alkaline suite records the culmination of Deccan Traps continental flood volcanism

    NASA Astrophysics Data System (ADS)

    Owen-Smith, T. M.; Ashwal, L. D.; Torsvik, T. H.; Ganerød, M.; Nebel, O.; Webb, S. J.; Werner, S. C.

    2013-12-01

    Silhouette and North Islands in the Seychelles represent an alkaline plutonic-volcanic complex, dated at 63 to 63.5 Ma by U-Pb zircon and 40Ar/39Ar methods. This magmatism coincides with the final stages of the cataclysmic Deccan Traps continental flood volcanism in India (67 to 63 Ma), and thus a causal link has been suggested. Recent reconstructions have placed the Seychelles islands adjacent to the Laxmi Ridge and at the western margin of the Réunion mantle plume at the time of formation of the complex. Here we present geochemical evidence in support of the notion that the Seychelles alkaline magmatism was initiated by the peripheral activity of the Réunion mantle plume and is thus part of the Deccan magmatic event. Positive εNd (0.59 to 3.76) and εHf (0.82 to 6.79) and initial Sr of 0.703507 to 0.705643 at 65 Ma indicate derivation of the Seychelles alkaline magmas from a Réunion-like mantle source with an additional minor enriched component, suggesting entrainment of sub-continental lithospheric mantle. The similarity in trace element composition between the Seychelles suite and Deccan alkaline felsic and mafic rocks provides additional evidence for a common mantle source for the Seychelles and Deccan magmatism. Furthermore, we demonstrate the role of fractional crystallisation in the evolution of the alkaline suite. Modelling using major elements suggests that fractional crystallisation and varying degrees of accumulation of olivine, plagioclase, ilmenite, clinopyroxene, alkali feldspar and apatite can describe the spectrum of rock types, from gabbro, through syenite, to granite.

  7. Transition from alkaline to calc-alkaline volcanism during evolution of the Paleoproterozoic Francevillian basin of eastern Gabon (Western Central Africa)

    NASA Astrophysics Data System (ADS)

    Thiéblemont, Denis; Bouton, Pascal; Préat, Alain; Goujou, Jean-Christian; Tegyey, Monique; Weber, Francis; Ebang Obiang, Michel; Joron, Jean Louis; Treuil, Michel

    2014-11-01

    We report new geochemical data for the volcanic and subvolcanic rocks associated with the evolution of the Francevillian basin of eastern Gabon during Paleoproterozoic times (c. 2.1-2 Ga). Filling of this basin has proceeded through four main sedimentary or volcano-sedimentary episodes, namely FA, FB, FC and FD. Volcanism started during the FB episode being present only in the northern part of the basin (Okondja sub-basin). This volcanism is ultramafic to trachytic in composition and displays a rather constant alkaline geochemical signature. This signature is typical of a within-plate environment, consistent with the rift-setting generally postulated for the Francevillian basin during the FB period. Following FB, the FC unit is 10-20 m-thick silicic horizon (jasper) attesting for a massive input of silica in the basin. Following FC, the FD unit is a c. 200-400 m-thick volcano-sedimentary sequence including felsic tuffs and epiclastic rocks. The geochemical signatures of these rocks are totally distinct from those of the FB alkaline lavas. High Th/Ta and La/Ta ratios attest for a calc-alkaline signature and slight fractionation between heavy rare-earth suggests melting at a rather low pressure. Such characteristics are comparable to those of felsic lavas associated with the Taupo zone of New Zealand, a modern ensialic back-arc basin. Following FD, the FE detrital unit is defined only in the Okondja region, probably associated with a late-stage collapse of the northern part of the basin. It is suggested that the alkaline to calc-alkaline volcanic transition reflects the evolution of the Francevillian basin from a diverging to a converging setting, in response to the onset of converging movements in the Eburnean Belt of Central Africa.

  8. Strontium isotopic evidence for an enriched source for post-subduction volcanic rocks, Dominican Republic

    SciTech Connect

    Wertz, W.K.; Perfit, M.R.; Shuster, R.D.

    1985-01-01

    Later Cenozoic volcanic rocks from the eastern Las Cuevas region (ELCR), Dominican Republic are dominantly shoshonitic and are associated with a series of east-west trending faults. The ELCR rocks are highly enriched in Sr, Ba, and light REE, but contain relatively low amounts of Rb and HFS ions. Several basalts appear to be unfractionated and have Mg-numbers of >75. These transitional to alkalic volcanic rocks are atypical of Caribbean igneous rocks and are more similar to alkaline centers associated with late-stage, island arc volcanism in other regions. Elevated /sup 87/Sr//sup 86/Sr ratios (0.7041-0.7048) are high in comparison to most other igneous rocks from the Caribbean region and indicate that they were derived from a source relatively enriched in LIL and REE in comparison to the sources which gave rise to the majority of Caribbean igneous rocks. /sup 87/Sr//sup 86/Sr values increase linearly with increasing Sr contents, suggesting mixing of sources with relatively low Sr contents and depleted /sup 87/Sr//sup 86/Sr with material that is highly enriched in Sr and with /sup 87/Sr//sup 86/Sr values around 0.706. This enriched component may be a fluid derived from melting/dehydrating subducted oceanic crust and sediment which metasomatically veined the sub-arc mantle. Small degrees of partial melting (<7%) of this source may be responsible for the unusual and enriched chemical composition of the ELCR volcanic rocks.

  9. Contemporaneous trachyandesitic and calc-alkaline volcanism of the Huerto Andesite, San Juan Volcanic Field, Colorado, USA

    USGS Publications Warehouse

    Parat, F.; Dungan, M.A.; Lipman, P.W.

    2005-01-01

    Locally, voluminous andesitic volcanism both preceded and followed large eruptions of silicic ash-flow tuff from many calderas in the San Juan volcanic field. The most voluminous post-collapse lava suite of the central San Juan caldera cluster is the 28 Ma Huerto Andesite, a diverse assemblage erupted from at least 5-6 volcanic centres that were active around the southern margins of the La Garita caldera shortly after eruption of the Fish Canyon Tuff. These andesitic centres are inferred, in part, to represent eruptions of magma that ponded and differentiated within the crust below the La Garita caldera, thereby providing the thermal energy necessary for rejuvenation and remobilization of the Fish Canyon magma body. The multiple Huerto eruptive centres produced two magmatic series that differ in phenocryst mineralogy (hydrous vs anhydrous assemblages), whole-rock major and trace element chemistry and isotopic compositions. Hornblende-bearing lavas from three volcanic centres located close to the southeastern margin of the La Garita caldera (Eagle Mountain - Fourmile Creek, West Fork of the San Juan River, Table Mountain) define a high-K calc-alkaline series (57-65 wt % SiO2) that is oxidized, hydrous and sulphur rich. Trachyandesitic lavas from widely separated centres at Baldy Mountain-Red Lake (western margin), Sugarloaf Mountain (southern margin) and Ribbon Mesa (20 km east of the La Garita caldera) are mutually indistinguishable (55-61 wt % SiO2); they are characterized by higher and more variable concentrations of alkalis and many incompatible trace elements (e.g. Zr, Nb, heavy rare earth elements), and they contain anhydrous phenocryst assemblages (including olivine). These mildly alkaline magmas were less water rich and oxidized than the hornblende-bearing calc-alkaline suite. The same distinctions characterize the voluminous precaldera andesitic lavas of the Conejos Formation, indicating that these contrasting suites are long-term manifestations of San Juan

  10. Petrological and geochemical characteristics of Cenozoic high-K calc-alkaline volcanism in Konya, Central Anatolia, Turkey

    NASA Astrophysics Data System (ADS)

    Temel, Abidin; Gündoğdu, M. Niyazi; Gourgaud, Alain

    1998-10-01

    Late Miocene to Pliocene volcanic rocks outcrop west, northwest and southwest of the Konya area in Central Anatolia, Turkey. Volcanic products are lava domes, nuée ardentes and ignimbrite deposits, predominantly andesitic to dasitic in composition, together with rare basalt, basaltic andesite, basaltic trachyandesite and trachyandesite (50.35-69.39% SiO 2). The serie exhibits high-K calc-alkaline affinities. Fractional crystallization of pyroxene, plagioclase and Fe-Ti oxides is the main process in the magmatic evolution of Konya volcanic rocks. Volcanic units exhibit typical high-K calc-alkaline character. Their geochemical characteristics (e.g., enrichments in LIL elements such as K, Rb, Ba, Sr, depletion in HFSE such as Ti, Nb, and high Ba/Nb and Low Nb/Y ratios) are consistent with those of active continental margin regions. High 87Sr/ 86Sr (0.704841-0.707340) and low 143Nd/ 144Nd (0.512390-0.512618) ratios suggest crustal involvement in their petrogenesis. Correlations between 86Sr/ 87Sr isotope with Rb, Rb/Nb, Rb/Ba, and Rb/Sr also emphasize the effect of crustal contamination on the andesitic and dacitic magmas. As a consequence, Konya volcanic rocks are products of assimilation and fractional crystallization (AFC) processes of a magma which seems to be linked to the subduction of the African plate underneath the Anatolian plate during Miocene.

  11. Strain-dependent permeability of volcanic rocks.

    NASA Astrophysics Data System (ADS)

    Farquharson, Jamie; Heap, Michael; Baud, Patrick

    2016-04-01

    We explore permeability evolution during deformation of volcanic materials using a suite of rocks with varying compositions and physical properties (such as porosity ϕ). 40 mm × 20 mm cylindrical samples were made from a range of extrusive rocks, including andesites from Colima, Mexico (ϕ˜0.08; 0.18; 0.21), Kumamoto, Japan (ϕ˜0.13), and Ruapehu, New Zealand (ϕ˜0.15), and basalt from Mt Etna, Italy (ϕ˜0.04). Gas permeability of each sample was measured before and after triaxial deformation using a steady-state benchtop permeameter. To study the strain-dependence of permeability in volcanic rocks, we deformed samples to 2, 3, 4, 6, and 12 % axial strain at a constant strain rate of 10‑5 s‑1. Further, the influence of failure mode - dilatant or compactant - on permeability was assessed by repeating experiments at different confining pressures. During triaxial deformation, porosity change of the samples was monitored by a servo-controlled pore fluid pump. Below an initial porosity of ˜0.18, and at low confining pressures (≤ 20 MPa), we observe a dilatant failure mode (shear fracture formation). With increasing axial strain, stress is accommodated by fault sliding and the generation of ash-sized gouge between the fracture planes. In higher-porosity samples, or at relatively higher confining pressures (≥ 60 MPa), we observe compactant deformation characterised by a monotonous decrease in porosity with increasing axial strain. The relative permeability k' is given by the change in permeability divided by the initial reference state. When behaviour is dilatant, k' tends to be positive: permeability increases with progressive deformation. However, results suggest that after a threshold amount of strain, k' can decrease. k' always is negative (permeability decreases during deformation) when compaction is the dominant behaviour. Our results show that - in the absence of a sealing or healing process - the efficiency of a fault to transmit fluids is

  12. Spinel-group minerals in rocks of the Khibiny alkaline pluton, Kola Peninsula

    NASA Astrophysics Data System (ADS)

    Ivanyuk, G. Yu.; Pakhomovsky, Ya. A.; Konopleva, N. G.; Yakovenchuk, V. N.; Men'shikov, Yu. P.; Mikhailova, Yu. A.

    2007-12-01

    Seven spinel-group minerals in various geological settings have been revealed in the rocks of the Khibiny pluton. Hercynite, gahnite, and vuorelainenite occur only in xenoliths of hornfels after volcanic and sedimentary rocks, whereas spinel and magnesiochromite occur in alkaline ultramafic rocks of dike series. Franklinite has been discovered in a low-temperature hydrothermal vein. Ubiquitous magnetite is abundant in foyaite, foidolites, alkaline ultrabasic rocks, and pegmatite and hydrothermal veins and may even be the main mineral in some foidolite varieties. The spinel-group minerals are characterized by various chemical compositions due to the fractionation of nepheline syenites resulting in formation of the Main ring of foidolites and apatite-nepheline ore. Like most other minerals found throughout the pluton, magnetite is characterized by variation in the chemical composition along the radial line from the contact with country Proterozoic volcanic rocks to the geometric center of the pluton. Toward the center, the total Ti and Mn contents in magnetite increase from 5 15 up to 40 at %.

  13. 40Ar/ 39Ar ages for the alkaline volcanism and the basement of Gorringe Bank, North Atlantic ocean

    NASA Astrophysics Data System (ADS)

    Féraud, Gilbert; Gastaud, Janine; Auzende, Jean-Marie; Olivet, Jean-Louis; Cornen, Guy

    1982-01-01

    Gorringe Bank is situated on the Europe-Africa plate boundary at the eastern end of the Azores-Gibraltar fracture zone. It has two summits, Gettysburg Bank to the Southwest and Ormonde Bank to the northeast. We applied the 40Ar/ 39Ar stepwise heating method to date six samples of the alkaline volcanic rocks, two gabbros from the Ormonde Bank and a dolerite from the Gettysburg Bank. The results that the alkaline volcanism lasted probably for less than 6 Ma(66-60 Ma). Although the nature of this volcanism precludes any subduction feature during its setting, the alkaline volcanism of Ormonde is probably linked to Upper Cretaceous/Eocene compressive tectonic events. The basement rocks of Gorringe Bank reveal distrubed 40Ar/ 39Ar age spectra. One plagioclase and one biotite from a gabbro give evidence for a thermic event whose age is tentatively estimated at about 75 Ma, and related to a variation in the direction of the relative movement between Europe and Africa. The more probable age given by a plagioclase of another gabbro and by a dolerite (110 Ma) corresponds to tilting northeastward of the Gorringe massif.

  14. A Videotape Short Course on Volcanic Rock Textures.

    ERIC Educational Resources Information Center

    Chesner, Craig A.; Rose, William I.

    1987-01-01

    Reviews the objectives, themes, and content of a series of five color videotapes on volcanic rock textures. Explains how the tapes, which integrate petrographic observations of textures with computer graphics, can be used in undergraduate and graduate level courses. (ML)

  15. Petrology and Geochemistry of the Eocene Volcanic Rocks in the Kahrizak Mountains, Central Iran

    NASA Astrophysics Data System (ADS)

    Yazdani, S.; Castillo, P.; Tutti, F.

    2013-12-01

    The Eocene volcanic rocks in the Kahrizak (KH) Mountains in the northern part of Central Iran were mainly formed by magmatism that accompanied block-faulting tectonism in the region. In the KH area, the volcanic rocks are nonconformably overlain by Oligocene-Pliocene sedimentary deposits, suggesting that the Eocene magmatic activity in the region was followed by a sequence of uplift and shallow marine regression. The volcanic rocks consist of pyroclastics (tuff and ignimbrites) and lava flows (basalt, basaltic trachyandesite, trachyandesite, and rhyolite); superposition indicates an earlier explosive volcanic phase that caused the widespread distribution of rhyolitic ignimbrites and tuffs, and this was followed by a quieter phase of lava eruptions. Petrographic evidence such as mineral zoning, sieve texture and rounded crystals of plagioclase and pyroxene phenocrysts indicate non-equilibrium conditions between melt and crystals during magma cooling. These textures suggest magma mixing, although these may also be due to rapid decompression, where heat loss is minor relative to the ascent rate. The geochemistry of KH samples indicates their subalkaline to alkaline affinity. In terms of trace element contents, most samples exhibit the distinct geochemical trait of arc volcanism, i.e., Nb and Ta depletions relative to LILE (e.g., Ba, Rb) enrichment and positive Sr anomaly; however, Zr and Ti depletions are not prominent. The samples have a light-REE enriched but flat heavy-REE pattern and negative Eu anomaly in the rhyolites and trachyandesites. They have a ~narrow to ~moderate range of Pb isotopic ratios (206Pb/204Pb ~18.6-18.9, 207Pb/204Pb ~15.5-15.6, and 208Pb/204Pb ~38.5-38.8), with basaltic rocks somewhat higher than rhyolitic rocks. Available geochemical and isotopic data suggest a complex origin and evolution of the KH magmas. The magmas originated from an intrinsically ~heterogeneous source and, in addition to fractional crystallization, some of the

  16. Plutonic processes recorded in Iceland's volcanic rocks

    NASA Astrophysics Data System (ADS)

    Maclennan, J.

    2013-12-01

    It has long been understood that the compositions of volcanic rocks from basaltic provinces contain information about magmatic differentiation processes. Whole-rock or pillow-rim glass compositions have previously been sucessfully modelled using the single liquid line of descent (LLD) approach. While the expected cumulate products from the crystallisation and differentiation that drives these LLDs can be predicted from the models, this approach provides little information about the physical nature of the chambers that control basaltic evolution. Development in microanalysis now allows for new types of observations to be acquired that can be used to probe the physics of basaltic chambers. Here, we explore three distinct types of observations from the products of young Icelandic volcanic eruptions which can be used to understand plutonic processes in basaltic systems. Ultimately, these observations can be tied to simple physical models of magma chambers, with the aim of quantifying vigour of convection in magma chambers, the related timescales of evolution and the heights of liquid and mush layers in active chambers. The first observation is based on the relationship between the composition of melt inclusions and the forsterite content of their olivine hosts. Certain trace element ratios, such as La/Yb, are effectively passive tracers of mixing of diverse mantle melts under Iceland. The forsterite content of the host olivine tracks the cooling and differentiation of these mixing liquids. The observations indicate the cooling and mixing is concurrent and is likely to be coupled by convection in liquid layers of magma chambers. Relative rates of mixing and cooling can be quantified from these observations and linked to the vigour of convection in the liquid layer of the chamber. The absolute rate of cooling of these chambers is also linked to the Rayleigh number in this layer, and this value can be constrained by geochemical and geological observations from Iceland

  17. The calc-alkaline and adakitic volcanism of the Sabzevar structural zone (NE Iran): Implications for the Eocene magmatic flare-up in Central Iran

    NASA Astrophysics Data System (ADS)

    Moghadam, Hadi Shafaii; Rossetti, Federico; Lucci, Federico; Chiaradia, Massimo; Gerdes, Axel; Martinez, Margarita Lopez; Ghorbani, Ghasem; Nasrabady, Mohsen

    2016-04-01

    A major magmatic flare-up is documented along the Bitlis-Zagros suture zone in Eocene-Oligocene times. The Cenozoic magmatism of intraplate Central Iran is an integrant part of this tectono-magmatic scenario. The Cenozoic magmatism of the Sabzevar structural zone consists of mostly intermediate to felsic intrusions and volcanic products. These igneous rocks have calc-alkaline and adakitic geochemical signatures, with nearly coincident zircon U-Pb and mica Ar-Ar ages of ca. 45 Ma. Adakitic rocks have quite low HREE and high Sr/Y ratio, but share most of their geochemical features with the calc-alkaline rocks. The Sabzevar volcanic rocks have similar initial Sr, Nd and Pb isotope ratios, showing their cogenetic nature. Nd model ages cluster tightly around ~ 0.2-0.3 Ga. The geochemistry of the Sabzevar volcanic rocks, along with their isotopic signatures, might strangle that an upper mantle source, metasomatized by slab-derived melts was involved in generating the Sabzevar calc-alkaline rocks. A bulk rock trace element modeling suggests that amphibole-plagioclase-titanite-dominated replenishment-fractional crystallization (RFC) is further responsible for the formation of the middle Eocene Sabzevar adakitic rocks. Extensional tectonics accompanied by lithospheric delamination, possibly assisted by slab break-off and melting at depth was responsible for the Eocene formation of the Sabzevar magmatic rocks and, more in general, for the magmatic "flare-up" in Iran.

  18. Petrogenesis of extension-related alkaline volcanism in Karaburhan (Sivrihisar-Eskisehir), NW Anatolia, Turkey

    NASA Astrophysics Data System (ADS)

    Sarıfakıoğlu, Ender; Özen, Hayrettin; Hall, Chris

    2009-08-01

    Alkaline lavas were erupted as phonolites and trachytes around Karaburhan (Sivrihisar-Eskisehir, NW Anatolia) within the Izmir-Ankara-Erzincan suture zone. These volcanic rocks were emplaced as domes, close and parallel to the ophiolite thrust line. According to 40Ar/ 39Ar geochronological analyses of sanidine crystals from the phonolites, the age of the alkaline volcanics is 25 Ma (Late Oligocene-Early Miocene). The flow-textured phonolites are porphyritic and consist mainly of sanidine, clinopyroxene, and feldspathoid crystals. The clinopyroxenes show compositional zoning, with aegirine (Na 0.82-0.96Fe +30.68-0.83) rims and aegirine-augite cores (containing calcium, magnesium, and Fe +2). Some aegirine-augites are replaced with sodium-, calcium-, and magnesium-rich amphibole (hastingsite). Feldspathoid (hauyne) crystals enriched with elemental Na and Ca have been almost completely altered to zeolite and carbonate minerals. The fine-grained trachytes with a trachytic texture consist of feldspar (oligoclase and sanidine) phenocrystals and clinopyroxene microphenocrystals within a groundmass made up largely of alkali feldspar microlites. Although there are some differences in their element patterns, the phonolites and trachytes exhibit enrichment in LILEs (Sr, K, Rb, Ba, Th) and LREEs (La, Ce, Pr, Nd) and negative anomalies in Nb and Ta. These geochemical characteristics indicate a lithospheric mantle enriched by fluids extracted from the subduction component. In addition, the high 87Sr/ 86Sr (0.706358-0.708052) and low 143Nd/ 144Nd (0.512546-0.512646) isotope concentrations of the alkaline lavas reflect a mantle source that has undergone metasomatism by subduction-derived fluids. Petrogenetic modeling indicates that the alkaline lavas generated from the subduction-modified lithospheric mantle have undergone assimilation, fractional crystallization, and crustal contamination, acquiring high Pb, Ba, Rb, and Sr contents and Pb isotopic compositions during their ascent

  19. Lithium Isotope Systematics of Rift-related Alkaline Igneous Rocks

    NASA Astrophysics Data System (ADS)

    Halama, R.; McDonough, W. F.; Rudnick, R. L.; Trumbull, R.; Klaudius, J.; Keller, J.; Taubald, H.

    2006-05-01

    Intracontinental alkaline igneous rocks from the Proterozoic Gardar Province (Greenland), the Cretaceous Damaraland Province (Namibia), the Tertiary Kaiserstuhl complex (Germany) and from the Holocene volcano Oldoinyo Lengai (Tanzania) were analyzed to characterize Li isotopic compositions of their mantle sources and to determine the processes affecting δ7Li in alkaline igneous rocks. The inferred mantle Li isotope signatures of the primitive alkaline rocks (δ7Li = +1 to +7) are similar to those of present- day MORB, OIB and carbonatites, and appear to be relatively constant in time and space. Gabbros from the Gardar Province define a relatively small field of Li isotope compositions (δ7Li = +4 to +7). Mineral separates (clinopyroxene, plagioclase) mostly overlap with the whole-rock values, which we interpret to reflect the δ7Li of the mantle sources of the gabbros. Mantle-like δ7Li values are also observed for primitive alkaline rocks from the other regions. Li isotope compositions in more differentiated rocks (syenites, phonolites and rhyolites) are highly variable (+11 to -22 per mil) and reflect a diversity of evolutionary processes that may vary from complex to complex. δ7Li values vary independently of Sr and Nd isotope values and indices of differentiation (e.g. MgO content) or weathering (e.g. LOI). Consistently light δ7Li values (+2 to -22) occur in Gardar syenites associated with a carbonatite. These may be explained by weathering and sub-solidus alteration, as indicated by petrographic observations. Alternatively, fluid-assisted diffusion processes, related to a fenitizing fluid from the carbonatite, may have led to extreme Li isotope fractionation. Whole-rock oxygen isotope analyses will be carried out to evaluate interaction with meteoric water, which would be reflected in a decrease in δ18O compared to magmatic values. The heaviest Li isotopic composition (+11 per mil) was obtained for a rhyolite, probably related to the presence of quartz

  20. Oxygen isotopic compositions of Central Andean plutonic and volcanic rocks, latitudes 26°-29° south

    NASA Astrophysics Data System (ADS)

    Longstaffe, Frederick J.; Clark, Alan H.; McNutt, Robert H.; Zentilli, Marcos

    1983-07-01

    Oxygen isotope data are reported for 27 igneous rocks of Mesozoic to Quaternary age from the Central Andes. 26-29°S. The plutonic rocks, and most of the volcanics, have δ18O values between 6.2 and 8.3‰. The whole-rock δ 18O values show a weak correlation with initial 87Sr/ 86Sr data. This O-Sr array differs from documented trends for calc-alkaline plutonic suites from California, Scotland and northern Italy, but overlaps with data for volcanic and plutonic rocks from Ecuador, northern Chile and southern Perú. The oxygen isotope results indicate that the magmas evolved without significant contamination from supracrustal rocks (e.g., rocks that experienced 18O enrichment during surficial weathering). The available O, Sr and Pb isotopic data for these rocks are best explained by magma generation in the upper mantle or lower crust. From the Late Mesozoic on, the 87Sr/ 86Sr values were modified at depth by isotopic exchange between the magma and a continually thickening crust of plutonic rocks of Late Precambrian to early Mesozoic age.

  1. Tertiary volcanic rocks from the southern Pannonian Basin, Croatia

    SciTech Connect

    McKee, E.H.; Bullen, T.D.; Lanphere, M.A.

    1995-03-01

    The Tertiary volcanic rocks of the southern part of the Pannonian Basin are related to a sequence of tectonic events that occurred along the northern margin of the Dinarides when subduction ceased and after uplift of the region in middle Eocene time. The oldest rocks are andesites and dacites erupted during an Egerian to Eggenburgian marine transpression phase. In early Miocene time (about 17 Ma), rifting started, probably caused by the rise of the mantle, resulting in E-W extension and strike-slip faulting leading to formation of the Pannonian Basin. The initial rifting was accompanied by trachyandestic volcanism of Karpathian age, followed by Badenian-age (15 to 13 Ma) volcanic activity producing baslats, andesites, and dacites. During these volcanic phases the Pannonian Basin, or the Paratethys, probably was periodically connected with the Mediterranean Sea. The final period of volcanism (about 9 to 7 Ma) produced alkalic basalts and basalts and occurred in fresh-water environments. These volcanic rocks have had a complex petrological evolution, related to an active continental margin. Egerian-Eggenburgian andesites and dacites can be explained by upper crustal assimilation with fractional crystallization (ACF) of primary basalt magma. The three younger associations originated by partial melting of rocks from both the upper mantle and the lower crust. Their evolution was accompanied by crustal contamination. 39 refs., 12 figs., 5 tabs.

  2. Discrimination of alkalinity in granitoid Rocks: A potential TIMS application

    NASA Technical Reports Server (NTRS)

    Ruff, Steven W.

    1995-01-01

    In mineral exploration, the ability to distinguish and map petrochemical variations of magmatic rocks can be a useful reconnaissance tool. Alkalinity is one such petrochemical parameter and is used in the characterization of granitoid rocks. In quartz normative plutonic rocks, alkalinity is related to the composition and abundance of feldspars. Together with quartz abundance, knowledge of feldspar modes allows the classification of these igneous rocks according to the Streckeisen diagram. Alternative classification schemes rely on whole rock geochemistry instead of mineral identifications. The relative ease of obtaining whole rock analyses means that geochemical classifications tend to be favored in exploration geology. But the technique of thermal infrared spectroscopy of rocks yields information on mineralogy and is one that can be applied remotely. The goal of the current work then is to establish whether data from TIMS can be used to distinguish the mineralogical variations that relate to alkalinity. An ideal opportunity to test this thesis arises from the work presented in a paper by Dewitt (1989). This paper contains the results of mapping and analysis of Proterozoic plutonic rocks in north-central Arizona. The map resulting from this work delineates plutons according to alkalinity in an effort to establish a trend or polarity in the regional magmatism. Also contained within this paper are brief descriptions of the mineralogy of half of the region's plutons. This combination of mineralogical and geochemical information was the rationale behind choosing this area as a site for TIMS over flights. A portion of the region centered on the northern Bradshaw Mountains was selected because it contains plutons of all three alkalinity classifications (alkali-calcic, calc-alkalic, and calic) present on DeWitt's map within a relatively small area. The site was flown in August of 1994 and the data received a few days before the writing of this manuscript. Most of this

  3. Geochemistry of volcanic rocks from the Wawa greenstone belt

    NASA Technical Reports Server (NTRS)

    Schulz, K. J.; Sylvester, P. J.; Attoh, K.

    1983-01-01

    The Wawa greenstone belt is located in the District of Algoma and extends east-northeast from Lake Superior to the western part of the Sudbury District in Ontario, Canada. Recent mapping by Attoh has shown that an unconformity at the base of the Dore' Formation and equivalent sedimentary rocks marks a significant stratigraphic break which can be traced throughout the volcanic belt. This break has been used to subdivide the volcanic-sedimentary into pre- and post-Dore' sequences. The pre-Dore' sequence includes at least two cycles of mafic-to-felsic volcanism, each capped by an iron-formation unit. The post-Dore' sequence includes an older mafic-to-felsic unit, which directly overlies sedimentary rocks correlated with the Dore' Formation, and a younger felsic breccia unit interpreted to have formed as debris flows from a felsic volcanic center. In the present study, samples of both the pre-and post-Dore' volcanic sequences were analyzed for major and trace elements, incuding rare earths (REE). This preliminary study is part of an ongoing program to assess the petrogenesis of the volcanic rocks of the Wawa greenstone belt.

  4. Mantle xenocrysts of Chompolo field of the alkaline volcanics, Aldan shield, South Yakutia.

    NASA Astrophysics Data System (ADS)

    Nikolenko, Evgeny; Tychkov, Nikolay; Afanasiev, Valentin

    2015-04-01

    New mineralogical and chemical constraints for 10 dikes, veins (360-800m) and pipes (60-110 m) of Chompolo field discovered in 1957-1958 are discussed. Feld is located within Central Aldan Archean and Paleoproterozoic granulite-orthogneiss superterrane of Aldan-Stanovoy Shield, with peak of metamorphism - 2.1-1.9 Ga (Smelov, Timofeev, 2007). Originally (Shilina and Zeitlin 1959) and later (Kostrovitsky and Garanin 1992, Ashchepkov, Vladykin et al. 2001) these rocks were classified as kimberlites by mineralogy including pyrope, Cr spinel, and Cr diopside. Panina and Vladykin (1994), Davies et al, (2006) identified them as lamprophyres and lamproites. The age of Chompolo rocks is pre-Jurassic (Vladimirov et. al., 1989) dated by 40Ar/39Ar as 164.7±1 Ma (233.7±2.2 next plato)(unpublished Ashchepkov). The Rb-Sr isochron for lamprophyre "intrusions 104" indicate later age of 131±4 Ma (Zaitsev, Smelov, 2010). Magmatic bodies (Aldanskaya, Sputnik, Gornaya, Ogonek, Perevalnaya, Kilier-E) were studied during 2012-2013 fieldworks. Most of igneous rocks occur as inequigranular volcanic breccias with micro- or crypto-crystalline groundmass of K feldspar (up to 16.3 wt.% K2O, up to 3.2 wt.% FeO), chlorite, opaque minerals, melanocratic xenocrysts and phenocrysts (garnet, pyroxene, amphibole, Cr spinel, apatite, zircon, mica), and abundant xenogenic fragments of wallrock and crystalline basement. Garnet chemistry records the presence of mantle and crustal material. Mantle garnets lack the common megacryst, wehrlite, and high-temperature lherzolite varieties. Mantle mineralization prevails in the Aldan dike and the Sputnik, Gornaya, and Ogonek pipes, while crustal and elcogitic material is in the Perevalnaya and Kilier-E pipes. The Cr spinel consists of (in wt%) 3.5 to 50.9 Al2O3, 18.6-63.5 wt% Cr2O3, 6.1 to 19.1 MgO, and 0 to 1.61 TiO2. Al and Cr in spinels are in inverse proportion. The Chompolo alkaline volcanic rocks are most similar to the Central Aldan lamproites in trace

  5. Peralkaline silicic volcanic rocks in northwestern nevada.

    PubMed

    Noble, D C; Chipman, D W; Giles, D L

    1968-06-21

    Late Tertiary silicic ashflow tuffs and lavas peralkaline in chemical character (atomic Na + K greater than Al), mainly comendites, occur over wide areas in northwestern Nevada and appear to be widespread in southeastern Oregon. Such peralkaline rocks-which are not uncommon in the western United States-and other chemically unusual silicic rocks are found near the margins rather than toward the center of the Great Basin. PMID:17800671

  6. Corundum-group minerals in rocks of the Khibiny alkaline pluton, Kola Peninsula

    NASA Astrophysics Data System (ADS)

    Mikhailova, Yu. A.; Konopleva, N. G.; Yakovenchuk, V. N.; Ivanyuk, G. Yu.; Men'shikov, Yu. P.; Pakhomovsky, Ya. A.

    2007-12-01

    Five minerals of the corundum group have been identified in the Khibiny pluton with certainty. Corundum proper and karelianite occur only in hornfels after volcanic and sedimentary rocks. Xenoliths of hornfels mark the ring faults that bound foidalite within the field of foyaite. Hematite occurs in hydrothermally altered nepheline syenite and crosscutting hydrothermal veins related to the ring faults. Minerals of the ilmenite-pyrophanite series are present in all rocks of the pluton, including veins. Accessory ilmenite in foyaite varies from the manganese variety and pyrophanite in the inner and outer parts of the pluton to manganese-free ilmenite in zone of the Main Ring Fault. In xenoliths of volcanic rocks and alkaline ultramafic rocks, ilmenite is enriched in magnesium. The zoning in distribution of the above-mentioned minerals and the character of variation in their compositions from margins of the pluton to its center are consistent with the petrochemical zoning formed as a result of foyaite alteration of near ring faults.

  7. Evolution of volcanic rocks and associated ore deposits in the Marysvale volcanic field, Utah

    USGS Publications Warehouse

    Cunningham, Charles G.; Steven, Thomas A.; Rowley, Peter D.; Naeser, Charles W.; Mehnert, Harald H.; Hedge, Carl E.; Ludwig, Kenneth R.

    1994-01-01

    A geological account on the igneous activity and associated mineral deposition in the volcanic field of Marysvale in Utah is presented. Three episodes (34-22 Ma, 22-14 Ma and 9-5 Ma) involved in the volcanic rock eruption and associated mineralization are described. The first episode is believed to have occurred during the time of tectonic convergence when two contrasting suites of rocks, Mount Dutton Formation and Bullion Canyon Volcanics, erupted concurrently. Mineralization during this period was sparse. In the second episode, change from intermediate to bimodal volcanism occurred. During the third episode, basaltic compositions did not change. Although major element constituent had rhyolites similar to that of the second episode, rhyolites had a marked radiogenic isotope characteristic difference.

  8. Isotopic evidence for the origin of Cenozoic volcanic rocks in the Pinacate volcanic field, northwestern Mexico

    NASA Astrophysics Data System (ADS)

    Lynch, D. J.; Musselman, T. E.; Gutmann, J. T.; Patchett, P. J.

    1993-02-01

    Six volcanic rocks, reconnaissance samples representing most of the temporal and compositional variation in the Pinacate volcanic field of Sonora and Arizona, are characterized for major element and NdSr isotopic compositions. The samples consist of basanite through trachyte of an early shield volcano, and alkali basalts and a tholeiite from later craters and cinder cones. With the exception of the trachyte sample, which has increased 87Sr/ 86Sr due to crustal effects, all 87Sr/ 86Sr values fall between 0.70312 and 0.70342, while ɛNd values are all between + 5.0 and + 5.7. Clinopyroxene in a rare spinel-lherzolite nodule derived from the uppermost mantle beneath the field has 87Sr/ 86Sr of 0.70320 but ɛNd of + 8.8, three ɛNd units higher than the volcanic rocks. Both the volcanic rocks and the nodule record the presence of asthenospheric, rather than enriched lithospheric mantle beneath Pinacate. This is consistent with one or both of (a) proximity of Pinacate to the Gulf of California spreading center and (b) presence of similar asthenospheric mantle signatures in volcanic rocks over a wide contiguous area of the southwestern USA. We consider the comparison to other southwestern USA magma sources as the more relevant alternative, although a definite conclusion is not possible at this stage.

  9. Magmatism at the Eurasian–North American modern plate boundary: Constraints from alkaline volcanism in the Chersky Belt (Yakutia)

    PubMed Central

    Tschegg, Cornelius; Bizimis, Michael; Schneider, David; Akinin, Vyacheslav V.; Ntaflos, Theodoros

    2011-01-01

    The Chersky seismic belt (NE-Russia) forms the modern plate boundary of the Eurasian−North American continental plate. The geodynamic evolution of this continent−continent setting is highly complex and remains a matter of debate, as the extent and influence of the Mid-Arctic Ocean spreading center on the North Asian continent since the Eocene remains unclear. The progression from a tensional stress regime to a modern day transpressional one in the Chersky seismic belt, makes the understanding even more complicated. The alkaline volcanism that has erupted along the Chersky range from Eocene through to the Recent can provide constraints on the geodynamic evolution of this continental boundary, however, the source and petrogenetic evolution of these volcanic rocks and their initiating mechanisms are poorly understood. We studied basanites of the central Chersky belt, which are thought to represent the first alkaline volcanic activity in the area, after initial opening of the Arctic Ocean basin. We present mineral and bulk rock geochemical data as well as Sr–Nd–Pb–Hf isotopes of the alkaline suite of rocks combined with new precise K–Ar and 40Ar/39Ar dating, and discuss an integrated tectono-magmatic model for the Chersky belt. Our findings show that the basanites were generated from a homogeneous asthenospheric mantle reservoir with an EM-1 isotopic flavor, under relatively ‘dry’ conditions at segregation depths around 110 km and temperatures of ~ 1500 °C. Trace element and isotope systematics combined with mantle potential temperature estimates offer no confirmation of magmatism related to subduction or plume activity. Mineral geochemical and petrographical observations together with bulk geochemical evidence indicate a rapid ascent of melts and high cooling rates after emplacement in the continental crust. Our preferred model is that volcanism was triggered by extension and thinning of the lithosphere combined with adiabatic upwelling of the

  10. Deriving spatial patterns from a novel database of volcanic rock geochemistry in the Virunga Volcanic Province, East African Rift

    NASA Astrophysics Data System (ADS)

    Poppe, Sam; Barette, Florian; Smets, Benoît; Benbakkar, Mhammed; Kervyn, Matthieu

    2016-04-01

    The Virunga Volcanic Province (VVP) is situated within the western branch of the East-African Rift. The geochemistry and petrology of its' volcanic products has been studied extensively in a fragmented manner. They represent a unique collection of silica-undersaturated, ultra-alkaline and ultra-potassic compositions, displaying marked geochemical variations over the area occupied by the VVP. We present a novel spatially-explicit database of existing whole-rock geochemical analyses of the VVP volcanics, compiled from international publications, (post-)colonial scientific reports and PhD theses. In the database, a total of 703 geochemical analyses of whole-rock samples collected from the 1950s until recently have been characterised with a geographical location, eruption source location, analytical results and uncertainty estimates for each of these categories. Comparative box plots and Kruskal-Wallis H tests on subsets of analyses with contrasting ages or analytical methods suggest that the overall database accuracy is consistent. We demonstrate how statistical techniques such as Principal Component Analysis (PCA) and subsequent cluster analysis allow the identification of clusters of samples with similar major-element compositions. The spatial patterns represented by the contrasting clusters show that both the historically active volcanoes represent compositional clusters which can be identified based on their contrasted silica and alkali contents. Furthermore, two sample clusters are interpreted to represent the most primitive, deep magma source within the VVP, different from the shallow magma reservoirs that feed the eight dominant large volcanoes. The samples from these two clusters systematically originate from locations which 1. are distal compared to the eight large volcanoes and 2. mostly coincide with the surface expressions of rift faults or NE-SW-oriented inherited Precambrian structures which were reactivated during rifting. The lava from the Mugogo

  11. Late Cenozoic alkaline volcanism in the northwestern Caribbean - Tectonic setting and Sr isotopic characteristics

    NASA Technical Reports Server (NTRS)

    Wadge, G.; Wooden, J. L.

    1982-01-01

    The northwestern corner of the Caribbean plate has at least sixteen centers of alkalic volcanism, most of which is Quaternary in age. Sr-87/Sr-86 ratios of the rocks in these centers are used to distinguish three geographical groups: a low-ratio group (0.7026-0.7031) at the Nicaraguan Rise, an intermediate-ratio group (0.7036-0.7038) in northeastern Costa Rica, and a high-ratio group (0.7047-0.7063) in Hispaniola. It is suggested that the increased radiogenic strontium in both Costa Rica and Hispaniola may have come from volatile-rich fluids escaping from adjacent subducting slabs of oceanic crust. The isotopic differences between the two areas is explained by the relative longevity and high rate of subduction in Costa Rica compared to that in Hispaniola. The Costa Rican alkaline rocks cover a segment of the Cocos plate which is being subducted at a smaller angle (about 35 deg) than at the rest of the Central American arc.

  12. Loss of halogens from crystallized and glassy silicic volcanic rocks

    USGS Publications Warehouse

    Noble, D.C.; Smith, V.C.; Peck, L.C.

    1967-01-01

    One hundred and sixty-four F and Cl analyses of silicic welded tuffs and lavas and glass separates are presented. Comparison of the F and Cl contents of crystallized rocks with those of nonhydrated glass and hydrated glassy rocks from the same rock units shows that most of the halogens originally present were lost on crystallization. An average of about half of the F and four-fifths of the Cl originally present was lost. Analyses of hydrated natural glasses and of glassy rocks indicate that in some cases significant amounts of halogens may be removed from or added to hydrated glass through prolonged contact with ground water. The data show that the original halogen contents of the groundmass of a silicic volcanic rock can be reliably determined only from nonhydrated glass. ?? 1967.

  13. Relationships between ultrapotassic and carbonate-rich volcanic rocks in central Italy: petrogenetic and geodynamic implications

    NASA Astrophysics Data System (ADS)

    Peccerillo, Angelo

    1998-09-01

    The Pleistocene intra-Apennine volcanic (IAV) centres occurring east of the potassium-rich Roman comagmatic province show variable petrological and geochemical composition. Some rocks have a strongly undersaturated ultrapotassic kamafugitic affinity with K 2O/Na 2O=8-20, whereas the rocks from the southern center of Mt. Vulture are still strongly undersaturated in silica but are enriched in both Na 2O and K 2O with K/Na around unity. Carbonate-rich pyroclastic rocks, believed to represent carbonatitic magmas, are found in the IAV centers. Kamafugites have high abundances of LILE and high LILE/HFSE ratios, and their incompatible element patterns resemble closely those of ultrapotassic rocks from the adjoining Roman province. The Vulture volcanics also display high contents of LILE, but their LILE/HFSE ratios are intermediate between intraplate alkaline rocks and kamafugites. The carbonate-rich rocks exhibit an exotic mineralogy and high enrichments in LILE, which speaks for a carbonatitic affinity. However, they have similar incompatible element patterns but consistently lower abundances of almost all the elements than the associated silicate volcanics. These data favour the hypothesis that the IAV carbonate rocks may represent mixtures of silicate magmas and geochemically depleted carbonate material. The sedimentary carbonates that crop out extensively along the Apennine chain may be the source of barren carbonate material. Overall, geochemical data of IAV centres and of the rocks from the Roman province display strong geochemical and isotopic evidence of being generated in an upper mantle that was modified by addition of upper crustal material brought down by subduction processes. A possible exception is represented by Mt. Vulture which, however, occurs east of the main axis of the Apennines, on the western margin of the foreland Adria plate. The occurrence of strongly undersaturated alkaline rocks requires magma generation at high pressures and XCO 2. This is in

  14. Geochemical tectonomagnetic discrimination of metamorphosed Middle Jurassic volcanic rocks, northern Sierra Nevada, California

    SciTech Connect

    Templeton, J.H. . Dept. of Geosciences); Hanson, R.E. . Dept. of Geology); Harwood, D.S. )

    1993-04-01

    Jurassic island-arc rocks in the Northern Sierra terrane (NSt) are represented by the Lower to Middle Jurassic Sailor Canyon Formation, consisting mainly of distal andesitic turgidities, and the overlying, Middle Jurassic Tuttle Lake Formation (TLF); both units were metamorphosed to lower greenschist facies during Mesozoic orogenesis. The TLF is a 1.6-km-thick sequence of submarine tuff-breccia debris-flow deposits intercalated with minor isolated-pillow breccias and intruded by numerous cogenetic hypabyssal intrusions that underwent extensive interaction with wet sediments in near-vent setting. Here the authors report the first geochemical studies of these regionally significant arc rocks. Pillow breccias, hypabyssal intrusions, and clasts within debris-flow deposits are predominantly basalt to basaltic andesite in composition and contain abundant plagioclase and clinopyroxene phenocrysts. Although cpx is intensely altered to actinolite, microprobe analyses were carried out on relict cpx cores. Compositions are typical of cpx from orogenic lavas and fall in combined calc-alkaline and tholeiitic fields on cpx discrimination diagrams. Most major elements show significant scatter on Harker and AFM variation diagrams, reflecting the metamorphic overprint. Immobile trace element contents (Ti, Cr, Y, Yb, Zr, Hf, Ta, Th) clearly indicate volcanic arc and calc-alkaline affinities when plotted on a variety of discrimination diagrams. REE patterns show LREE-enrichment typical of calc-alkaline lavas, commonly with small negative Eu anomalies consistent with plagioclase fractionation. The TLF shows marked petrologic and stratigraphic differences from broadly coeval Jurassic arc rocks exposed in the fault-bounded Kettle Rock sequence in the northeastern part of the NSt. This may reflect relatively rapid along-strike variations within the Jurassic arc, or that the Kettle Rock sequence and the TLF arc rocks have been brought into proximity by later faulting.

  15. 40Ar/39Ar Geochronology, Isotope Geochemistry (Sr, Nd, Pb), and petrology of alkaline lavas near Yampa, Colorado: migration of alkaline volcanism and evolution of the northern Rio Grande rift

    USGS Publications Warehouse

    Cosca, Michael A.; Thompson, Ren A.; Lee, John P.; Turner, Kenzie J.; Neymark, Leonid A.; Premo, Wayne R.

    2014-01-01

    Volcanic rocks near Yampa, Colorado (USA), represent one of several small late Miocene to Quaternary alkaline volcanic fields along the northeast margin of the Colorado Plateau. Basanite, trachybasalt, and basalt collected from six sites within the Yampa volcanic field were investigated to assess correlations with late Cenozoic extension and Rio Grande rifting. In this paper we report major and trace element rock and mineral compositions and Ar, Sr, Nd, and Pb isotope data for these volcanic rocks. High-precision 40Ar/39Ar geochronology indicates westward migration of volcanism within the Yampa volcanic field between 6 and 4.5 Ma, and the Sr, Nd, and Pb isotope values are consistent with a primary source in the Proterozoic subcontinental lithospheric mantle. Relict olivine phenocrysts have Mg- and Ni-rich cores, whereas unmelted clinopyroxene cores are Na and Si enriched with finely banded Ca-, Mg-, Al-, and Ti-enriched rims, thus tracing their crystallization history from a lithospheric mantle source region to one in contact with melt prior to eruption. A regional synthesis of Neogene and younger volcanism within the Rio Grande rift corridor, from northern New Mexico to southern Wyoming, supports a systematic overall southwest migration of alkaline volcanism. We interpret this Neogene to Quaternary migration of volcanism toward the northeast margin of the Colorado Plateau to record passage of melt through subvertical zones within the lithosphere weakened by late Cenozoic extension. If the locus of Quaternary alkaline magmatism defines the current location of the Rio Grande rift, it includes the Leucite Hills, Wyoming. We suggest that alkaline volcanism in the incipient northern Rio Grande rift, north of Leadville, Colorado, represents melting of the subcontinental lithospheric mantle in response to transient infiltration of asthenospheric mantle into deep, subvertical zones of dilational crustal weakness developed during late Cenozoic extension that have been

  16. The strength of heterogeneous volcanic rocks: A 2D approximation

    NASA Astrophysics Data System (ADS)

    Heap, Michael J.; Wadsworth, Fabian B.; Xu, Tao; Chen, Chong-feng; Tang, Chun'an

    2016-06-01

    Volcanic rocks typically contain heterogeneities in the form of crystals and pores. We investigate here the influence of such heterogeneity on the strength of volcanic rocks using an elastic damage mechanics model in which we numerically deform two-dimensional samples comprising low-strength elements representing crystals and zero-strength elements representing pores. These circular elements are stochastically generated so that there is no overlap in a medium representing the groundmass. Our modelling indicates that increasing the fraction of pores and/or crystals reduces the strength of volcanic rocks, and that increasing the pore fraction results in larger strength reductions than increasing the crystal fraction. The model also highlights an important weakening role for pore diameter, but finds that crystal diameter has a less significant influence for strength. To account for heterogeneity (pores and crystals), we propose an effective medium approach where we define an effective pore fraction ϕp‧ = Vp/(Vp + Vg) where Vp and Vg are the pore and groundmass fractions, respectively. Highly heterogeneous samples (containing high pore and/or crystal fractions) will therefore have high values of ϕp‧, and vice-versa. When we express our numerical samples (more than 200 simulations spanning a wide range of crystal and pore fractions) in terms of ϕp‧, we find that their strengths can be described by a single curve for a given pore diameter. To provide a predictive tool for the strength of heterogeneous volcanic rocks, we propose a modified version of 2D solution for the Sammis and Ashby (1986) pore-emanating crack model, a micromechanical model designed to estimate strength using microstructural attributes such as porosity, pore radius, and fracture toughness. The model, reformulated to include ϕp‧ (and therefore crystal fraction), captures the strength curves for our numerical simulations over a sample heterogeneity range relevant to volcanic systems. We find

  17. Volcanic rock petrochemistry as an exploration technique for geothermal energy

    SciTech Connect

    Fultz, L.A.; Bell, E.J.; Trexler, D.T.

    1983-12-01

    Large high-level silicic magma chambers offer a high potential for economically viable geothermal systems. While purely basic volcanic systems rarely form thermal anomalies, they may provide the necessary long-term heat input to silicic systems, by underplating, to sustain a high-temperature geothermal system. Petrographic and microprobe, geochemical, geochronologic, and isotopic data on young volcanic rocks in west-central Nevada indicate compositions that may result from magmatic differentiation, crystal fractionation, variation in magmatic source regions and in particular, magma mixing. Analysis of the petrochemistry and the recognition of magma mixing textures of extrusive rocks may indicate interacting mafic magma with buried shallow silicic magma systems. These systems may provide a shallow heat source for development of geothermal resources.

  18. The geochemistry of primitive volcanic rocks of the Ankaratra volcanic complex, and source enrichment processes in the genesis of the Cenozoic magmatism in Madagascar

    NASA Astrophysics Data System (ADS)

    Melluso, L.; Cucciniello, C.; le Roex, A. P.; Morra, V.

    2016-07-01

    The Ankaratra volcanic complex in central Madagascar consists of lava flows, domes, scoria cones, tuff rings and maars of Cenozoic age that are scattered over 3800 km2. The mafic rocks include olivine-leucite-nephelinites, basanites, alkali basalts and hawaiites, and tholeiitic basalts. Primitive samples have high Mg# (>60), high Cr and Ni concentrations; their mantle-normalized patterns peak at Nb and Ba, have troughs at K, and smoothly decrease towards the least incompatible elements. The Ankaratra mafic rocks show small variation in Sr-Nd-Pb isotopic compositions (e.g., 87Sr/86Sr = 0.70377-0.70446, 143Nd/144Nd = 0.51273-0.51280, 206Pb/204Pb = 18.25-18.87). These isotopic values differ markedly from those of Cenozoic mafic lavas of northern Madagascar and the Comoro archipelago, typical Indian Ocean MORB and oceanic basalt end-members. The patterns of olivine nephelinitic magmas can be obtained through 3-10% partial melting of a mantle source that was enriched by a Ca-rich alkaline melt, and that contained garnet, carbonates and phlogopite. The patterns of tholeiitic basalts can be obtained after 10-12% partial melting of a source enriched with lower amounts of the same alkaline melt, in the spinel- (and possibly amphibole-) facies mantle, hence in volumes where carbonate is not a factor. The significant isotopic change from the northernmost volcanic rocks of Madagascar and those in the central part of the island implicates a distinct source heterogeneity, and ultimately assess the role of the continental lithospheric mantle as source region. The source of at least some volcanic rocks of the still active Comoro archipelago may have suffered the same time-integrated geochemical and isotopic evolution as that of the northern Madagascar volcanic rocks.

  19. Petrology of Quaternary volcanic rocks and related plutonic xenoliths from Gölcük volcano, Isparta Angle, Turkey: Origin and evolution of the high-K alkaline series

    NASA Astrophysics Data System (ADS)

    Platevoet, Bernard; Elitok, Ömer; Guillou, Hervé; Bardintzeff, Jacques-Marie; Yagmurlu, Fuzuli; Nomade, Sébastien; Poisson, André; Deniel, Catherine; Özgür, Nevzat

    2014-10-01

    The Quaternary volcanism of Isparta, south-western Anatolia, belongs to the post-collisional alkali-potassic to ultrapotassic magmatism, active since Miocene, from Afyon to Isparta. In the so-called Isparta Angle, the magmatism is contemporaneous with the Aegean extensional regime initiated during the Late Miocene and active throughout the Pliocene and Quaternary. The Gölcük volcano-forming stages consist of three main eruptive cycles: Cycle I comprising 200 m-thick pyroclastic flow deposits; Cycle II consisting of tephriphonolitic lava dome-flows extruded throughout the caldera; and Cycle III characterized by tuff-ring deposits related to the last phreatoplinian events. These late explosive events sampled plutonic xenoliths that allow to better constrain magma fractionation processes that operated at depth in the magma chamber. Magma evolution was first controlled by accumulation of clinopyroxene, phlogopite and apatite, then by phlogopite, amphibole and feldspars, with apatite, magnetite, titanite and zircon as accessories. Crystallization of clinopyroxene, phlogopite and amphibole probably controlled the silica-saturation trend of the whole series and faithfully reflect intensive H2O variations in the magma that were responsible of explosive cyclic events. The parental magma may have had a lamprophyric-tephritic composition. Trace element and isotope ratios indicate a prevalent asthenospheric source versus lithospheric one. Geochemical features, such as strong enrichment of LILE, REE, HFSE in the Gölcük magma point to the involvement of a asthenospheric OIB-type melt with a possible carbonatitic component, that interacted with remnants of the delaminated lithosphere during upwelling.

  20. Different sources involved in generation of continental arc volcanism: The Carboniferous-Permian volcanic rocks in the northern margin of the North China block

    NASA Astrophysics Data System (ADS)

    Zhang, Shuan-Hong; Zhao, Yue; Liu, Jian-Min; Hu, Zhao-Chu

    2016-01-01

    New zircon U-Pb dating results on the Carboniferous-Permian volcanic rocks in the northern margin of the North China block (NCB) indicate their eruption during the Early Carboniferous to Late Permian from 347 ± 3 Ma to 258 ± 1 Ma and a slight decrease of the upper limits of the volcanic sequences from west to east. They have a main rock association of basalt, basaltic andesite, andesite, dacite, rhyolite, tuff, and tufaceous sandstone. Most of them have calc-alkaline compositions and exhibit variable SiO2 contents from 48.2 wt.% to 77.1 wt.%. There is no significant gap between the mafic and felsic volcanic rocks in major and trace element classification diagrams, indicating that they are not bimodal in composition. The Carboniferous-Permian volcanic rocks exhibit subduction-related geochemical features such as negative Nb and Ta anomalies of mafic to intermediate rocks on primitive mantle-normalized diagrams, indicating they were formed in an Andean-type continental arc during southward subduction of the Paleo-Asian oceanic plate beneath the northern NCB. However, their wide range of whole-rock Sr-Nd and zircon Hf isotopic compositions indicate that their source areas are very complex and different sources were involved in generation of these volcanic rocks. Geochemical and Sr-Nd-Hf isotopic results show that the basalt and some andesite were produced by fractional crystallization of mafic magma derived from partial melting of mantle wedge and subducted oceanic crust; however, most of the intermediate to felsic volcanic rocks were derived from partial melting of lower continental crust. There is an increasing input of crustal materials from the Carboniferous to Permian as indicated by increasing volumes of felsic volcanic rocks in the volcanic sequences. The results show that origin of the continental arc volcanism is very complex and both materials from the subducted oceanic crust and sediments, mantle wedge and arc continental crust could be involved in their

  1. Examining ash fall sequences in calk-alkaline subduction related volcanism, southern New Mexico

    NASA Astrophysics Data System (ADS)

    Rentz, S. P.; Michelfelder, G.; Salings, E. E.; Sikes, E. R.

    2015-12-01

    The Mogollon-Datil volcanic field (MDVF) is a 40-20 ma cluster of caldera activity in southern New Mexico tied to the subduction of oceanic lithosphere beneath the North American continental plate. The calk-alkaline magmatism of the three calderas in this field (Mogollon, Bursum, and Gila Cliff Dwellings) produced several voluminous regionally dispersed ash flow tuffs. This study will specifically examine the volcanic rocks: Cooney Formation (a compositionally zoned rhyolitic to quartz latite ash flow tuff containing quartz>k-feldspar>plagioclase>biotite, and pumice and lithic fragments. Rb ranges from 213-317ppm, Sr from 104-108ppm, and 87Sr/86Srm from 0.71326-0.71534), Davis Canyon Tuff (a phenocryst poor, high-silica rhyolite ash flow tuff containing sanidine>quartz>sodic plagioclase. Rb ranges from 214-230ppm, Sr from 42.2-63.2ppm, and 87Sr/86Srm from 0.71383-0.71464), and the Shelley Peak Tuff (a compositionally zoned, crystal-rich rhyolite tuff containing sodic plagioclase>minor sanidine>biotite>cpx. Rb ranges from 154-213ppm, Sr from 105-245ppm, and 87Sr/86Srm from 0.70944-0.7112) to further elucidate their petrogenic origins, attempt to determine if they may be of the same magmatic source, and yield data that could help model processes that would generate magma of these particular compositions. This study will examine compositional variation between the Davis Canyon, Shelley Peak and Cooney Tuffs and help with understanding the magma plumbing system during each eruption. More specifically, we will evaluate possible crustal components of these units, along with looking for geochemical signatures of arc or rift related magmatism. We will compare previous geochronology results (K-Ar and U-Pb fission track) and whole rock major and trace element geochemistry to data obtained via 40Ar/39Ar and U/Pb dates and new whole rock Sr, Nd and Pb isotopic ratios.

  2. Cenozoic Bimodal Volcanic Rocks of the Northeast boundary of Tibetan Plateau: implication for the collision-induced mantle flow beneath the Tibetan Plateau

    NASA Astrophysics Data System (ADS)

    Yu, X.; Mo, X.; Zhao, Z.

    2011-12-01

    Cenozoic bimodal volcanic rocks of the Northeastern boundary of Tibetan Plateau are found in the area of West Qinling in China, E104°30'-105°36' and N33°35'-34°40',which located tectonically to the western boundary of Ordos block and also the north section of the N-S trending Helan mountain-Liupan mountain-Yunnan tectonic belt. The geological setting of the bimodal volcanic rocks belongs to an assemblage of Cratonic blocks composed of many small blocks linked by oroginic belts(Deng et al., 1996). The bimodal volcanic rocks, similar to those in East African rift, are consisted of kamafugite, volcanic eruption carbonatite, shoshonite, rhyolite and/or trachyte. The age of the bimodal volcanic rocks is between 23Ma to 7.1Ma according to isotopic dating of K/Ar and 39Ar/40Ar. All of these volcaic rocks in the volcanic assemblage have the characteristics rich in LREE and LIL. Not only that, the HFS, especially Nb, Zr and P in the volcanic rocks are higher than other Cenozoic alkaline volcanic rocks in Tibetan Plateau. The 87Sr/86Sr=0.704031-0.70525, 206Pb/204Pb=18.408-19.062, 207Pb/204Pb=15.476-15.677, 208Pb/204Pb=38.061-39.414 and ɛ(Nd) =0.3-5.3 of the volcanic rocks, all of these are akin to the feature of Neo-Tethyan mantle geochemical end member as represented by Yaluzangbu ophiolites defined by Zhao and Mo et al (2009), and also akin to the volcanic rocks related to Ontong Java and FOZO mantle plum(Yu et al.,2009). Cenozoic bimodal volcanic rocks in Western Qinling, Northeastern boundary of Tibetan Plateau provide ideal lithoprobes for understanding of the mantle beneath Tibetan Plateau and showed that the Cenozoic bimodal volcanic rocks bear the geochemical feature of Indian ocean mantle domain, and its genesis may be related to mantle plum, the magmatic source of the bimodal volcanic rocks should be a depleted mantle. For this reason, we suggest the bimodal volcaic rock is a rifting magmatisim, and its origin and genesis of the bimodal volcaic rocks of

  3. The carriers of magnetic fabric in volcanic rocks

    NASA Astrophysics Data System (ADS)

    Krása, D.; Herrero-Bervera, E.

    2004-12-01

    Studies of the magnetic fabric of volcanic rocks have become an important tool to characterize flow directions in lava bodies, and to investigate dike emplacement and the plumbing of volcanic systems in general. However, depending on factors like the composition of the primary magma, the cooling history and the alteration regime, the magnetic fabric information can be carried by a large variety of ferri- and paramagnetic minerals. The composition and genesis of these minerals influence the ability of volcanic rocks to acquire information about the above mentioned dynamic processes. This presentation focuses on the relation between magnetic mineralogy, magnetic fabric and the techniques to determine the latter. Previous work on the topic will be reviewed and a case study will be discussed. We studied samples from the dike complex of the Koolau volcano on Oahu, Hawaii. These dikes are exposed as a result of the Nuuanu giant landslide. This landslide removed approximately the upper 3000 m of the volcanic edifice of the Koolau volcano. The dikes were thus emplaced deeply inside the Koolau volcano and were subjected to mild metamorphism. AMS measurements show different types of magnetic fabric for the 8 studied dikes. Rock magnetic and microscopic investigations as well as microprobe analyses indicate that the dikes can be subdivided into two groups with distinct magnetic mineralogies: 1. Samples containing almost unaltered coarse grained Ti-poor titanomagnetite and 2. highly altered samples where the primary titanomagnetite is replaced by its alteration products, maghemite and hematite. In both AF and thermal demagnetisation experiments a reversed ChRM for both groups of samples can be isolated. The strongly altered samples (second group) display an antiparallel overprint which is removed between 200 and 300oC. Strong field thermomagnetic measurements show that above 400oC, the maghemite phase of the second group completely inverts to hematite. AMS measurements after

  4. Petrographic and geochemical data for Cenozoic volcanic rocks of the Bodie Hills, California and Nevada

    USGS Publications Warehouse

    du Bray, Edward A.; John, David A.; Box, Stephen E.; Vikre, Peter G.; Fleck, Robert J.; Cousens, Brian L.

    2013-01-01

    Petrographic and geochemical data for Cenozoic volcanic rocks of the Bodie Hills, California and Nevada // // This report presents petrographic and geochemical data for samples collected during investigations of Tertiary volcanism in the Bodie Hills of California and Nevada. Igneous rocks in the area are principally 15–6 Ma subduction-related volcanic rocks of the Bodie Hills volcanic field but also include 3.9–0.1 Ma rocks of the bimodal, post-subduction Aurora volcanic field. Limited petrographic results for local basement rocks, including Mesozoic granitoid rocks and their metamorphic host rocks, are also included in the compilation. The petrographic data include visual estimates of phenocryst abundances as well as other diagnostic petrographic criteria. The geochemical data include whole-rock major oxide and trace element data, as well as limited whole-rock isotopic data.

  5. Alteration of submarine volcanic rocks in oxygenated Archean oceans

    NASA Astrophysics Data System (ADS)

    Ohmoto, H.; Bevacqua, D.; Watanabe, Y.

    2009-12-01

    Most submarine volcanic rocks, including basalts in diverging plate boundaries and andesites/dacites in converging plate boundaries, have been altered by low-temperature seawater and/or hydrothermal fluids (up to ~400°C) under deep oceans; the hydrothermal fluids evolved from shallow/deep circulations of seawater through the underlying hot igneous rocks. Volcanogenic massive sulfide deposits (VMSDs) and banded iron formations (BIFs) were formed by mixing of submarine hydrothermal fluids with local seawater. Therefore, the behaviors of various elements, especially of redox-sensitive elements, in altered submarine volcanic rocks, VMSDs and BIFs can be used to decipher the chemical evolution of the oceans and atmosphere. We have investigated the mineralogy and geochemistry of >500 samples of basalts from a 260m-long drill core section of Hole #1 of the Archean Biosphere Drilling Project (ABDP #1) in the Pilbara Craton, Western Australia. The core section is comprised of ~160 m thick Marble Bar Chert/Jasper Unit (3.46 Ga) and underlying, inter-bedded, and overlying submarine basalts. Losses/gains of 65 elements were quantitatively evaluated on the basis of their concentration ratios against the least mobile elements (Ti, Zr and Nb). We have recognized that mineralogical and geochemical characteristics of many of these samples are essentially the same as those of hydrothermally-altered modern submarine basalts and also those of altered volcanic rocks that underlie Phanerozoic VMSDs. The similarities include, but are not restricted to: (1) the alteration mineralogy (chlorite ± sericite ± pyrophyllite ± carbonates ± hematite ± pyrite ± rutile); (2) the characteristics of whole-rock δ18O and δ34S values; (3) the ranges of depletion and enrichment of Si, Al, Mg, Ca, K, Na, Fe, Mn, and P; (4) the enrichment of Ba (as sulfate); (5) the increases in Fe3+/Fe2+ ratios; (6) the enrichment of U; (7) the depletion of Cr; and (8) the negative Ce anomalies. Literature data

  6. Paleogene volcanic rocks of the Matanuska Valley area and the displacement history of the Castle Mountain fault

    NASA Astrophysics Data System (ADS)

    Silberman, M. L.; Grantz, A.

    Primitive strontium-isotopic composition and overall bimodal distribution of silica in upper Paleocene and Eocene subalkalic tholeiitic to calc-alkaline basalt and low-potassium rhyolite of the Matanuska Valley and southern Talkeetna Mountains suggest that these rocks were derived from the mantle with little contamination by continental crust. The volcanic rocks consist of rhyolite tuff and ash flows, as well as basalt flows and dikes, in the nonmarine Arkose Ridge Formation of the southwestern Talkeetna Mountains; of subaerial basalt and andesite flows, tuff, and mafic intrusions in the southeastern Talkeetna Mountains; and of felsic and mafic dikes, sills, and small plutons in the Matanuska Valley. The generalized geology of the area in which the volcanic rocks occur and the localities sampled for potassium-argon-age determinations and for chemical and strontinum-isotopic analysis are shown. The analytical results are listed.

  7. Evaluation of ASR potential of quartz-rich rocks by alkaline etching of polished rock sections

    NASA Astrophysics Data System (ADS)

    Šachlová, Šárka; Kuchařová, Aneta; Pertold, Zdeněk; Přikryl, Richard

    2015-04-01

    Damaging effect of alkali-silica reaction (ASR) on concrete structures has been observed in various countries all over the World. Civil engineers and real state owners are demanding reliable methods in the assessment of ASR potential of aggregates before they are used in constructions. Time feasible methods are expected, as well as methods which enable prediction of long-term behaviour of aggregates in concrete. The most frequently employed accelerated mortar bar test (AMBT) quantifies ASR potential of aggregates according to the expansion values of mortar bars measured after fourteen days testing period. Current study aimed to develop a new methodical approach facilitating identification and quantification of ASR potential of aggregates. Polished rock sections of quartz and amorphous SiO2 (coming from orthoquartzite, quartz meta-greywacke, pegmatite, phyllite, chert, and flint) were subjected to experimental leaching in 1M NaOH solution at 80°C. After 14 days of alkaline etching, the rock sections were analyzed employing scanning electron microscope combined with energy dispersive spectrometer. Representative areas were documented in back scattered electron (BSE) images and measured using fully-automatic petrographic image analysis (PIA). Several features connected to alkaline etching were observed on the surface of polished rock sections: deep alkaline etching, partial leach-out of quartz and amorphous particles, alkaline etching connected to quartz grain boundaries, and alkaline etching without any connection to grain boundaries. All features mentioned above had significant influence on grey-scale spectrum of BSE images. A specific part of the grey-scale spectrum (i.e. grey-shade 0-70) was characteristic of areas affected by alkaline etching (ASR area). By measuring such areas we quantified the extent of alkaline etching in studied samples. Very good correlation was found between the ASR area and ASR potential of investigated rocks measured according to the

  8. Calc-alkaline mafic rocks of the Black Dyke Formation: Remnants of the final activity of a submerged Permian volcano

    SciTech Connect

    Blein, O.; Lapierre, H.; Pecher, A. ); Schweickert, R.A. . Dept. of Geological Science)

    1993-04-01

    The Permian Black Dyke Fm., which occurs as large tectonic slices within the Luning allochthon in the Excelsior Mountains, NV, forms an E-W trending anticline at Black Dyke Mountain. The 800-m thick stratigraphic succession consists of volcanic and pyroclastic rocks overlain conformably by volcaniclastic sediments. Along the northern limb of the anticline, the rocks consist of mafic porphyritic lavas, breccias, and graded and ungraded pyroclastic beds. The sedimentary unit consists of thick volcaniclastic turbidites overlain by conglomerates, sandstones, and mudstones. Along the southern limb of the anticline, the sequence is replaced by reworked breccia, tuffs, and sandstones. Mafic plutonic rocks occur as xenoliths in the lavas and breccias, and as coeval plugs intruding the section. Gabbros show cumulate or porphyritic textures and are composed of amph, cpx, and zoned plag. Their Ti/V (14.5--15) and Nb/Y (0.25--0.3) ratios fall in the range commonly found in calc-alkaline rocks. Diorite porphyry shows high Al[sub 2]O[sub 3], ZrO[sub 2], and REE abundances indicating that this rock is more fractionated. Basalts and andesites are plag-cpx-opx phyric. They often include glomeroporphyritic clots of cpx with amph coronas. Some rocks exhibit fluidal textures. Both volcanic and plutonic rocks show homogeneous geochemical features and similar crystallization sequences: Fe-Ti oxides---->plag---->opx + cpx----> brown zoned hbl, suggesting that they are cogenetic. Thus, the lower part of the Black Dyke Fm. likely represents the final products formed in a calc-alkaline magma chamber because pyroclastic rocks prevail over lava flows and abundant early crystal cumulates occur as plugs or as inclusions in the lavas and breccias.

  9. Two mantle sources, two plumbing systems: Tholeiitic and alkaline magmatism of the Maymecha River basin, Siberian flood volcanic province

    USGS Publications Warehouse

    Arndt, N.; Chauvel, C.; Czamanske, G.; Fedorenko, V.

    1998-01-01

    Rocks of two distinctly different magma series are found in a ???4000-m-thick sequence of lavas and tuffs in the Maymecha River basin which is part of the Siberian flood-volcanic province. The tholeiites are typical low-Ti continental flood basalts with remarkably restricted, petrologically evolved compositions. They have basaltic MgO contents, moderate concentrations of incompatible trace elements, moderate fractionation of incompatible from compatible elements, distinct negative Ta(Nb) anomalies, and ??Nd values of 0 to + 2. The primary magmas were derived from a relatively shallow mantle source, and evolved in large crustal magma chambers where they acquired their relatively uniform compositions and became contaminated with continental crust. An alkaline series, in contrast, contains a wide range of rock types, from meymechite and picrite to trachytes, with a wide range of compositions (MgO from 0.7 to 38 wt%, SiO2 from 40 to 69 wt%, Ce from 14 to 320 ppm), high concentrations of incompatible elements and extreme fractionation of incompatible from compatible elements (Al2O3/TiO2 ??? 1; Sm/Yb up to 11). These rocks lack Ta(Nb) anomalies and have a broad range of ??Nd values, from -2 to +5. The parental magmas are believed to have formed by low-degree melting at extreme mantle depths (>200 km). They bypassed the large crustal magma chambers and ascended rapidly to the surface, a consequence, perhaps, of high volatile contents in the primary magmas. The tholeiitic series dominates the lower part of the sequence and the alkaline series the upper part; at the interface, the two types are interlayered. The succession thus provides evidence of a radical change in the site of mantle melting, and the simultaneous operation of two very different crustal plumbing systems, during the evolution of this flood-volcanic province. ?? Springer-Verlag 1998.

  10. Erratic Continental Rocks on Volcanic Seamounts off California and Oregon

    NASA Astrophysics Data System (ADS)

    Paduan, J. B.; Clague, D. A.; Davis, A. S.

    2006-12-01

    The seamounts off the California continental margin, and those well offshore of California and Oregon that formed near mid-ocean ridges, are all constructed of basaltic lava flows and volcanic breccias and sandstones. However, explorations of these seamounts using dredges, and more recently, the remotely operated vehicle Tiburon, frequently recover rocks of a wide assortment of continental lithologies including gabbro, granodiorite, silicic volcanics, limestone, dolomite, and metamorphic rocks. These rocks are often rounded like river and beach cobbles, and the softer rocks are bored as by worms or bivalves. They are covered with manganese oxide crusts of thicknesses that range from a patina to several cm, approaching the thickness on the in-situ basaltic rocks. These rocks are often easier to collect than the basalts. We recognize these rocks to be erratics of continental origin. Erratics have been documented as being transported by icebergs at higher latitudes, but this mechanism is unlikely to be responsible for the erratics we have found as far south as 31.9° N. Three brief papers published by K.O. Emery from 1941 to 1954 proposed that such erratics found in many thick sections of fine-grained sedimentary sequences such as the Monterey Formation, were transported long distances by kelp holdfasts, tree roots, or in the guts of pinnipeds. We propose that these vectors also transport erratics to seamounts, where they have been accumulating since the seamounts formed millions of years ago. Those seamounts that were once islands would have intercepted even more erratics along their shorelines while they stood above sea level. We have recovered or observed such erratics on the Vance Seamounts; Gumdrop, Pioneer, Guide, Davidson, Rodriguez, San Juan, Little Joe, and San Marcos Seamounts; on the muddy bottom of Monterey Bay; and on Northeast Bank and along the Patton Escarpment at the western edge of the California Borderland. These locations are as far as 250 nautical

  11. Geochemistry and petrogenesis of late Ediacaran (605-580 Ma) post-collisional alkaline rocks from the Katherina ring complex, south Sinai, Egypt

    NASA Astrophysics Data System (ADS)

    Azer, M. K.; Obeid, M. A.; Ren, M.

    2014-10-01

    The Katherina ring complex (KRC) in the central part of south Sinai, Egypt, is a typical ring complex of late Neoproterozoic age (605-580 Ma). It was developed during the final tectono-magmatic stage of the north Arabian-Nubian Shield (ANS) during evolution of the Pan-African crust. The KRC includes Katherina volcanics, subvolcanic bodies, ring dykes and Katherina granitic pluton. The Katherina volcanics represent the earliest stage of the KRC, which was subsequently followed by emplacement of the subvolcanic bodies and ring dykes. The Katherina granitic pluton depicts as the latest evolution stage of the KRC that intruded all the early formed rock units in the concerned area. The Katherina volcanics are essentially composed of rhyolites, ignimbrite, volcanic breccia and tuffs. Mineralogically, the peralkaline rhyolites contain sodic amphiboles and aegirine. The rhyolite whole rock chemistry has acmite-normative character. The subvolcanic bodies of the KRC are represented by peralkaline microgranite and porphyritic quartz syenite. The ring dykes are semicircular in shape and consist mainly of quartz syenite, quartz trachyte and trachybasalt rock types. The Katherina subvolcanic rocks, volcanic rocks as well as the ring dykes are alkaline or/and peralkaline in nature. The alkaline granitic pluton forms the inner core of the KRC, including the high mountainous areas of G. Abbas Pasha, G. Bab, G. Katherina and G. Musa. These mountains are made up of alkaline syenogranite and alkali feldspar granite. The mantle signature recorded in the KRC indicates a juvenile ANS crust partial melting process for the generation of this system. The evolution of the KRC rocks is mainly dominated by crystal fractionation and crustal contamination. Mineral geothermometry points to the high temperature character of the KRC, up to 700-1100 °C.

  12. Petrology and geochemistry of mafic and ultramafic cumulates occurring as xenoliths in volcanic rocks from Polish part of Central European Volcanic Province.

    NASA Astrophysics Data System (ADS)

    Dajek, Michał; Matusiak-Małek, Magdalena; Puziewicz, Jacek; Ntaflos, Theodoros

    2015-04-01

    of diopside, but its mg# is lower than in other rocks (0.68-0.88). It is always LREE enriched and shows negative Eu, Ti and Sr anomalies. Orthopyroxene occurs only in norite from Wilcza Góra. It composition is strongly heterogenous and the mg# vary from 0.60 to 0.75. Fo- and NiO-poor (62-69% and 0.04-0.10 wt.%, respectively) olivine is present in gabbro from Winna Góra. Feldspar is typically plagioclase (An30-60), but in rims the composition grades toward ternary feldspar (Or up to 45%). Plagioclase is LREE enriched and shows strong positive Eu anomaly. It is enriched in Sr and depleted in Zr-Hf. Composition of opaques is similar to that in plagioclase-free rocks. Modelling based on the trace element composition of clinopyroxene suggest that all the studied xenoliths are precipitates from alkaline silicate magmas, usually similar to the host volcanic-rock. Relatively high content of iron in silicates suggest crystallization at crustal depths or at crust/mantle boundary, but ratios between AIV and AlVI in clinopyroxene suggest that plagioclase¬-bearing rocks crystalized in different conditions than pyroxenites (Aoki and Shiba, 1976). Origin of xenoliths from Złotoryja-Jawor Volcanic Complex is different than that of clinopyroxene-rich mafic rocks from Lutynia basanite (Lądek Zdrój Volcanic Complex (Ackerman et al., 2012; J. of Geosciences). This study was possible thanks to the project NCN 2011/03/B/ST10/06248 of Polish National Centre for Science.

  13. Uranium and thorium decay series disequilibria in young volcanic rocks

    SciTech Connect

    Williams, R.W.

    1988-01-01

    Two of the central questions in igneous geochemistry that study of radioactive disequilibria can help to answer are: what are the rates of magma genesis; and what are the timescales of magma separation and transport. In addition to the temporal information that may be extracted from disequilibria data, the {sup 230}Th/{sup 232}Th of a young rock may be used as a tracer of the Th/U ratio of its source region. Measurements were made by isotope dilution alpha-spectrometry of {sup 238}U, {sup 234}U, {sup 230}Th, and {sup 232}Th in 20 subduction related, 3 oceanic intraplate, and 10 continental intraplate volcanics. {sup 210}Pb was measured in all, {sup 226}Ra was measured in about half, and {sup 228}Th was measured in 10 of the most recent samples. Disequilibrium between {sup 228}Th and {sup 232}Th was found only in the Nacarbonatite samples from Oldoinyo Lengai volcano in Tanzania, which is attributable to {sup 228}Ra/{sup 232}Th {approximately} 27 at the time of eruption. These rocks also have {sup 226}Ra/{sup 230}Th > 60. Three Ra-enrichment models are developed which constrain carbonatite magma formation at less than 20 years before eruption. The effects of different partial melting processes on the {sup 238}U decay series are investigated. If mid-ocean ridge basalts are formed by a dynamic melting process, the {sup 230}Th/{sup 232}Th of the basalts provides a minimum estimate of the Th/U ratio of the source region. The {sup 238}U enrichment in arc volcanics is probably the results of metasomatism of the source by fluids derived from the subducting slab, and the {sup 230}Th enrichment observed for other volcanics is probably due to the partial melting process in the absence of U-bearing fluids.

  14. Suprasubduction volcanic rocks of the Char ophiolite belt, East Kazakhstan: new geochemical and first geochronological data

    NASA Astrophysics Data System (ADS)

    Safonova, Inna; Simonov, Vladimir; Seltmann, Reimar; Yamamoto, Shinji; Xiao, Wenjiao

    2016-04-01

    The Char ophiolite belt is located in the western Central Asian Orogenic Belt, a world largest accretionary orogen, which has evolved during more than 800 Ma. The Char belt formed during Kazakhstan - Siberia collision. It has been known for hosting fragments of Late Devonian-Early Carboniferous oceanic crust, MORB, OPB and OIB, of the Paleo-Asian Ocean (Safonova et al., 2012). The Char is surrounded by two Paleozoic island-arc terranes: Zharma-Saur in the west and Rudny Altai in the east, however, until recent times, no island-arc units have been found within it. We were the first to find island-arc units as tectonic sheets occurring adjacent to those consisting of oceanic rocks. In places, island-arc andesites cut oceanic basalts. The Char volcanic and subvolcanic rocks of a probable suprasubduction origin are basalt, microgabbro, dolerite, andesite, tonalite and dacite. The mafic to andesitic volcanics possessing low TiO2 (0.85 wt.%av.) and show MgO vs. major elements crystallization trends suggesting two magma series: tholeiitic and calc-alkaline. The tholeiitic varieties are less enriched in incompatible elements then the calc-alkaline ones. Two samples are high-Mg and low-Ti andesibasalts similar to boninites. The rocks possess moderately LREE enriched rare-earth element patterns and are characterized by negative Nb anomalies present on the multi-element spectra (Nb/Lapm = 0.14-0.47; Nb/Thpm = 0.7-1.6).The distribution of rare-earth elements (La/Smn = 0.8-2.3, Gd/Ybn = 0.7-1.9) and the results of geochemical modeling in the Nb-Yb system suggest high degrees of melting of a depleted harzburgite-bearing mantle source at spinel facies depths. Fractional crystallization of clinopyroxene, plagioclase and opaque minerals also affected the final composition of the volcanic rocks. Clinopyroxene monomineral thermometry indicates crystallization of melts at 1020-1180°C. Melt inclusion composition based numerical calculations show that primary melts were derived at 1350

  15. Late Cenozoic calc-alkaline volcanism over the Payenia shallow subduction zone, South-Central Andean back-arc (34°30‧-37°S), Argentina

    NASA Astrophysics Data System (ADS)

    Litvak, Vanesa D.; Spagnuolo, Mauro G.; Folguera, Andrés; Poma, Stella; Jones, Rosemary E.; Ramos, Víctor A.

    2015-12-01

    A series of mesosilicic volcanic centers have been studied on the San Rafael Block (SRB), 300 km to the east of the present-day volcanic arc. K-Ar ages indicate that this magmatic activity was developed in at least two stages: the older volcanic centers (˜15-10 Ma) are located in the central and westernmost part of the SRB (around 36°S and 69°W) and the younger centers (8-3.5 Ma) are located in an eastern position (around 36°S and 69°30‧W) with respect to the older group. These volcanic rocks have andesitic to dacitic compositions and correspond to a high-K calc-alkaline sequence as shown by their SiO2, K2O and FeO/MgO contents. Elevated Ba/La, Ba/Ta and La/Ta ratios show an arc-like signature, and primitive mantle normalized trace element diagrams show typical depletions of high field strength elements (HFSE) relative to large ion lithophile elements (LILE). Rare earth element (REE) patterns suggest pyroxene and amphibole crystallization. Geochemical data obtained for SRB volcanic rocks support the proposal for a shallow subduction zone for the latest Miocene between 34°30″-37°S. Regionally, SRB volcanism is associated with a mid-Miocene to early Pliocene eastward arc migration caused by the shallowing of the subducting slab in the South-Central Andes at these latitudes, which represents the evolution of the Payenia shallow subduction segment. Overall, middle Miocene to early Pliocene volcanism located in the Payenia back-arc shows evidence for the influence of slab-related components. The younger (8-3.5 Ma) San Rafael volcanic rocks indicate the maximum slab shallowing and the easternmost extent of slab influence in the back-arc.

  16. Sr-Nd-Pb Isotopic Compositions of Volcanic Rocks Associated to the Apan-Tlaloc Fault System, Trans-Mexican Volcanic Belt, Mexico

    NASA Astrophysics Data System (ADS)

    Solis-Pichardo, G.; Martinez-Serrano, R.; Garcia, G.; Correa, J.; Nuñez, Y.; Schaaf, P. E.

    2010-12-01

    The Apan-Tlaloc region is located in the east-central part of the Trans-Mexican Volcanic Belt (TMVB), north of Popocatepetl volcano. It is composed of different volcanic structures: domes, cinder cones, shield volcanoes with major lava flows, and pyroclastic deposits. Geological studies have shown that these structures are probably related to the presence of a NE-SW oriented normal fault system. In this study, the Apan volcanic rocks were grouped into a Basal Volcanic Unit (~13.4 to 12.6 Ma) and an Upper Volcanic Unit (~2.1 to 1.5 Ma). Basal Unit products have compositions ranging from andesites to porphyric dacites and rhyolitic ignimbrites derived from volcanic sources unrelated to the NE-SW faulting. Basalts and basaltic andesites are representative of the Upper Unit. According to age determinations and stratigraphic studies, the magmatism in the Apan region was not continuous through the Miocene to the Pliocene, an approx 10 Ma hiatus is observed between both units. All studied rocks are of a calc-alkaline nature but differ substantially in their SiO2 contents: more than 65 wt.% in the Basal Unit and less than 57 wt.% in the Upper Unit. Trace element patterns are relatively heterogeneous for both units. Basal Unit volcanics show LILE enrichments with respect to HFSE as well as negative anomalies of Nb, Ta, P, and Ti, and positive anomalies of Ba, Rb, and Pb, suggesting a depleted mantle source origin modified by subduction fluids. In contrast, Upper Unit volcanics do not show enrichment of LILE with respect to HFSE and negative Nb and Ta anomalies are absent. Negative P and Ti anomalies and positive Ba and Pb spikes are also observed. These patterns suggest a less depleted mantle source, which was also affected by fluids derived from subduction processes. REE patterns for both units show enrichment of LREE with respect to HREE, confirming a magma origin related to a subducted slab but from a different source. The isotopic results for all products show the

  17. Oligocene caldera complex and calc-alkaline tuffs and lavas of the Indian Peak volcanic field, Nevada and Utah

    USGS Publications Warehouse

    Best, M.G.; Christiansen, E.H.; Blank, H.R., Jr.

    1989-01-01

    The Indian Peak volcanic field is representative of the more than 50 000 km3 of ashflow tuff and tens of calderas in the Great Basin that formed during the Oligocene-early Miocene "ignimbrite flareup' in southwestern North America. These dominantly high-K calc-alkaline rocks are a record of the birth, maturation, and death of a large, open, continental magma system that was probably initiated and sustained by influx of mafic magma derived from a southward-migrating locus of magma production in the mantle. Recurrent production of very large batches (some greater than 3000 km3) of quite uniform dacite magmas appears to have required combination of andesite magma and crustal silicic material in vigorously convecting chambers. Compositional data indicate that rhyolites are polygenetic. As the main locus of mantle magma production shifted southward, trachydacite magma could have been produced by fractionation of andesitic magma within the crust. -from Author

  18. Volcanological, petrographical and geochemical characteristics of Late Cretaceous volcanic rocks around Borçka-Artvin region (NE Turkey)

    NASA Astrophysics Data System (ADS)

    Baser, Rasim; Aydin, Faruk; Oguz, Simge

    2015-04-01

    This study presents volcanological, petrographical and geochemical data for late Cretaceous volcanic rocks from the Borçka-Artvin region (NE Turkey) in order to investigate their origin and magmatic evolution. Based on the previous ages and recent field studies, the late Cretaceous time in the study area is characterized by two different bimodal volcanic periods. The first bimodal period of the late Cretaceous volcanism is mainly represented by mafic rock series (basaltic-basaltic andesitic pillow lavas and hyaloclastites) in the lower part, and felsic rock series (dacitic lavas, hyaloclastites, and pyrite-bearing tuffs) in the upper part. The second bimodal period of the late Cretaceous volcanism begins with mafic rock suites (basaltic-andesitic lavas and dikes-sills) and grades upward into felsic rock suites (biotite-bearing rhyolitic lavas and hyaloclastites), which are intercalated with hyaloclastites and red pelagic limestones. All volcano-sedimentary units are covered by Late Campanian-Paleocene clayey limestones and biomicrites with lesser calciturbidites. The mafic volcanic series of the study area, which comprise basaltic and andesitic rocks, generally show amygdaloidal and aphyric to porphyritic texture with phenocrysts of calcic to sodic plagioclase and augite in a hyalopilitic matrix of plag+cpx+mag. Zircon and magnetite are sometimes observed as accessory minerals, whereas chlorite, epidote and calcite are typical alteration products. On the other hand, the felsic volcanic series consisting of dacitic and rhyolitic rocks mostly display porphyritic and glomeroporphyritic textures with predominant feldspar, quartz and some biotite phenocrysts. The microgranular to felsophyric groundmass is mainly composed of aphanitic plagioclase, K-feldspar and quartz. Accessory minerals such as zircon, apatite and magnetite are common. Typical alteration products are sericite and clay minerals. Late Cretaceous Artvin-Borçka bimodal rock series generally display a

  19. Os isotopes in hornblende-bearing intra-plate alkaline lavas (Central European Volcanic Province; CEVP)

    NASA Astrophysics Data System (ADS)

    Mayer, B.; Jung, S.; Brauns, M.; Pfänder, J.

    2013-12-01

    alkaline lavas yielded an age of 24.1×0.1 Ma which precisely constrains the age of initial volcanism in this area. These ages indicate that the hornblende-bearing lavas are the first melts among the Rhön lavas in which the presence of kaersutite implies wet melting of a previously metasomatically enriched lithospheric mantle. It is also reasonable to assume that metasomatised pyroxenitic material will melt first and may contribute to the chemical and isotopic composition of early-rifting lavas. This study indicates that crustal contamination in primitive alkaline rocks is widespread and emphasizes the view that the lithospheric mantle beneath continents may contain a significant portion of pyroxenitic material.

  20. Major and EDXRF Trace Element Chemical Analyses of Volcanic Rocks from Lassen Volcanic National Park and Vicinity, California

    USGS Publications Warehouse

    Clynne, Michael A.; Muffler, L.J.P.; Siems, D.F.; Taggart, J.E., Jr.; Bruggman, Peggy

    2008-01-01

    This open-file report presents WDXRF major-element chemical data for late Pliocene to Holocene volcanic rocks collected from Lassen Volcanic National Park and vicinity, California. Data for Rb, Sr, Ba, Y, Zr, Nb, Ni, Cr, Zn and Cu obtained by EDXRF are included for many samples. Data are presented in an EXCEL spreadsheet and are keyed to rock units as displayed on the Geologic Map of Lassen Volcanic National Park and vicinity (Clynne and Muffler, in press). Location of the samples is given in latitude and longitude in degrees and decimal minutes and in decimal degrees.

  1. Paleomagnetism of Eocene volcanic rocks, Talkeetna Mountains, Alaska

    SciTech Connect

    Panuska, B.C. ); Stone, D.B.; Turner, D.L. )

    1990-05-10

    Previous paleomagnetic studies of Eocene rocks deposited in the Talkeetna Mountains on the northern edge of the combined Peninsular, Wrangellia, and Alexander terranes (the southern Alaska superterrane (SAS)) yield a paleolatitude of 76{degree}N, while Late Cretaceous rocks on the southern edge of the SAS record a 32{degree}N paleolatitude. At face value, these drastically different paleolatitudes imply that Wrangellia moved 44{degree} to the north in only 20 m.y., requiring a northward component of velocity of about 24 cm/yr. Alternatively, the discrepancy might be explained by postulating an unrecognized tectonic boundary separating the two localities, allowing different emplacement ages. The authors have tested the unrecognized tectonic boundary hypothesis by sampling Eocene volcanic rocks deposited near the southern edge of the SAS in the Talkeetna Mountains. The data set comprises measurements from 97 oriented cores collected from 26 lava flows and two tuffs distributed over a distance of 50 km. A primary remanence is indicated by positive fold tests and penecontemporaneous intrusion tests. Age control is provided by nine new K-Ar whole rock age determinations ranging from 38.8 to 53.6 Ma. The mean paleomagnetic pole calculated for this study is not significantly different from the pole derived from the Eocene flows to the north and gives a paleolatitude of 78{degree}, thus ruling out the hypothesis of an unrecognized suture accommodating major post-Eocene displacement. This result has prompted a reevaluation of the data. The bulk of the evidence suggests northward displacement from lower latitudes; however, the error limits are such that the dramatic velocities previously postulated are not required.

  2. Compositional evolution of nepheline in alkaline rocks from Messum Complex

    NASA Astrophysics Data System (ADS)

    Blancher, Simon; D'Arco, Philippe; Fonteilles, Michel; Pascal, Marie-Lola

    2010-05-01

    Nepheline can be described as a four end-member solid solution between Ne (NaAlSiO4), Ks (KAlSiO4), An (Ca1/2□1/2AlSiO4) and Qz (□Si2O4), where □ is a vacancy in the structure. Few studies have explored its compositional variations, considered by most authors to be small and hardly related to magmatic evolution. In the Messum complex, an alkaline silica-undersaturated series is well exposed from theralites to nepheline-diorites, nepheline-monzonites and nepheline-syenites. This wide range of nepheline-rocks allows to follow an evolution of nepheline composition through the evolution of parageneses. In theralites, olivine, titanaugite and plagioclase are cumulus phases on which pargasite grows. Then, nepheline and diopside appear at the expense of plagioclase and pargasite. In nepheline-diorites, pargasite replaces olivine and titanaugite, and plagioclase becomes more sodic. Next, in nepheline-syenites, alkali feldspar appears, plagioclase then pargasite disappear, and diopside becomes enriched in acmite-content up to 15%. Nepheline is present at all stages of this magmatic evolution. Its own evolution can be correlated with that of feldspars. In theralites, nephelines in equilibrium with a calcic plagioclase are calcic (15% An). The An-content decreases progressively with the An-content of plagioclase, down to 2% in plagioclase-free rocks. Variations in the Ks end-member are small, in the range 10 to 16%, first increasing until alkali feldspar appears, then decreasing as the alkali feldspar evolves towards albite. Qz and Ne contents increase regularly from theralites (3 and 68%, respectively ) to syenites (7 and 75%). This nepheline-series is crosscutted by more alkaline dykes, nephelinites and peralkaline syenites. In nephelinites, the paragenesis resembles that of theralites, except for the absence of plagioclase. Peralkaline syenites contain acmite and unmixed alkali-feldspar. These chemical/mineralogical differences are accompanied by differences in the

  3. Early Jurassic Volcanic Rocks from the Raohe Accretionary Complex of NE China: Petrogenesis and Tectonic Implications

    NASA Astrophysics Data System (ADS)

    Wang, Zhihui; Ge, Wenchun

    2016-04-01

    The Raohe accretionary complex is located at the boundary between the Russian Far East and Northeast China, and is an important part of the Western Pacific Ocean tectonic regime. However, owing to the lack of precise age and geochemical constraints, the tectonic setting and petrogenesis of magmatic rocks in this area have been controversial, which has led to the debate on crustal growth mechanisms and subduction accretionary processes in the Northeast China. Herein, we report newly-defined calc-alkaline andesites, dacites, rhyolites, Nb-enriched basaltic-andesites and andesites, and N-MORB type basalts and basaltic-andesites from the Raohe accretionary complex, NE China. All these volcanic rocks are collected from rocks mapped previously as the Late Triassic to Early Jurassic stratums. LA-ICP-MS zircon U-Pb dating for one andesite, one dacites and three rhyolites indicate the occurrence of magmatic events in the Early Jurassic (186-174 Ma). They have positive ɛHf(t) values of +3.4 to +10.6 and relatively high (87Sr/86Sr)i values of 0.704711 to 0.710235. The calc-alkaline andesites, dacites and rhyolites are typical arc magmas, with moderately enriched LILEs and LREEs, distinctly negative HFSEs, consistent with the chemistry of volcanic rocks from an active continental margin setting. The Nb-enriched basaltic-andesites and andesites have higher TiO2, Nb, and Zr contents, higher Nb/Ta (24.03-87.60), Nb/U (11.89-75.94), (Nb/Th)PM (0.67-2.70), and (Nb/La)PM (1.95-5.00) ratios than typical arc basalts. They are relatively enriched in Nb, Zr, Hf and Ti. They have negative ɛNd(t) values of -5.47 to -6.04 and relatively variable (87Sr/86Sr)i values of 0.704648 to 0.711430, suggesting that they were possibly generated by a partial melting of mantle wedge peridotites metasomatized by slab-derived adakitic melts and minor fluids. The N-MORB type basalts and basaltic-andesites have comparatively low TiO2 concentrations (1.18-1.42 wt.%), show almost flat REE patterns with

  4. Petrology and petrogenesis of the Eocene Volcanic rocks in Yildizeli area (Sivas), Central Anatolia, Turkey

    NASA Astrophysics Data System (ADS)

    Doğa Topbay, C.; Karacık, Zekiye; Genç, S. Can; Göçmengil, Gönenç

    2015-04-01

    -Na plagioclase + hornblend ± pyroxene ± biotite + opaques in a matrix comprised of mostly glass, microlites or crypto to micro crystalline feldspars. All the lavas show mainly pilotaxitic, intersertal, cumulophyric and poikilitic textures. Geochemically, Yıldızeli lavas ranging in composition from basalt to trachyandesite displaying the calc-alkaline affinity with medium-K and shoshonitic character. All intermediate and basic volcanic rocks show enrichment in large ion lithophile elements (LILE) and light rare earth elements (LREE) relative to the high field strength elements (HFSE) such as Nb, Ta, Zr and Ti. Volcanic rocks of the Yıldızeli region display the following range in Sr and Nd initial isotope ratios: 87Sr/86Sr = 0.704389 to 0.706291 and 143Nd/144Nd = 0.512671. The major- trace element geochemistry and isotopic values suggest that Yıldızeli volcanics derived possibly from a mantle source which was modified by subduction related fluids or was contaminated by the continental crustal components.

  5. Volcanostratigraphy, petrography and petrochemistry of Late Cretaceous volcanic rocks from the Görele area (Giresun, NE Turkey)

    NASA Astrophysics Data System (ADS)

    Oguz, Simge; Aydin, Faruk; Baser, Rasim

    2015-04-01

    dacite but those of the second period have biotite-bearing rhyolite. The basalts and basaltic andesites exhibit subaphyric to porphyritic texture with phenocrysts of calcic plagioclase and augite in a fine-grained to microcrystalline groundmass, consisting of plag+cpx+mag. Andesite samples display a porphyritic texture with phenocrysts of calcic to sodic plagioclase and augite in a hyalopilitic matrix of plag+cpx±amph+mag. Zircon and magnetite are common accessory minerals, whereas chlorite, epidote and calcite are typical alteration products. On the other hand, the dacitic and rhyolitic rocks commonly show a porphyritic texture with predominant feldspar, quartz and some biotite phenocrysts. The microgranular to felsophyric groundmass is mainly composed of aphanitic plagioclase, K-feldspar and quartz. Accessory minerals include zircon, apatite and magnetite. Typical alteration minerals include late-formed sericite, albite and clay minerals. Late Cretaceous mafic and felsic volcanic rocks have a largely sub-alkaline character with typical arc geochemical signatures. N-MORB-normalised multi-element patterns show that all rock samples are enriched in LILEs (e.g. Rb, Ba, Th) but depleted in Nb and Ti. The chondrite-normalized REE patterns are concave shapes with low to medium enrichment, suggesting a common mantle source for the studied bimodal rock series. All geochemical data reflecting typical characteristics of subduction-related magmas are commonly attributed to a depleted mantle source, which has been previously enriched by fluids or sediments. Acknowledgments This work was supported by the Scientific and Technological Research Council of Turkey (TUBITAK, grant 112Y365)

  6. A 2.5 G.a. reworked sialic crust: Rb-Sr ages and isotopic geochemistry of late archaean volcanic and plutonic rocks from E. Finland

    NASA Astrophysics Data System (ADS)

    Martin, Hervé; Querré, Guirec

    1984-03-01

    In east-central Finland, Archaean terrains present three main lithologic units: a) gneissic basement, emplaced from 2.86 G.a. to 2.62 G.a., b) greenstone belt (2.65 G.a.) and c) calc-alkaline magmatism (2.50 G.a. to 2.40 G.a). Twenty three rocks of the calc-alkaline suite have been chosen for geochronologic and Rb-Sr isotopic studies. These rocks are subdivided into three groups: 1) acid volcanics from Luoma, 2) augen gneiss from Arola, and 3) post kinematik pink leucogranite from Arola. The 2.50±0.10 G.a. age of the Luoma volcanics indicates that they represent the upper part of a greenstone belt composed of a single sequence of volcanic rocks. The ages, initial 87Sr/86Sr (ISr) and major element compositions of the augen gneisses of Arola and Suomussalmi indicate that these rocks are the plutonic equivalents of the Luoma acid volcanics. The Arola pink leucogranite marks the terminal phase of Archaean magmatic activity (from 2.86 G.a. to 2.41 G.a.). This was followed by at least 0.40 G.a. of quiescence. The ISr and major element compositions suggest that the genesis of the calc-alkaline magmatic rocks involved crustal materials, but all their geochemical features cannot be explained without the participation of mafic greenstone belt materials. The first crustal components had low I and low K2O/ Na2O ratios while the younger ones (calc-alkaline magmas) had medium to high ISr and high K2O/Na2O ratios. Thus the petrogenetic processes have changed with time from ensimatic to ensialic, implying major reworking of preexisting crustal materials. This evolution leads to the accretion of the continental crust from the mantle.

  7. The evolution of Neoproterozoic magmatism in Southernmost Brazil: shoshonitic, high-K tholeiitic and silica-saturated, sodic alkaline volcanism in post-collisional basins.

    PubMed

    Sommer, Carlos A; Lima, Evandro F; Nardi, Lauro V S; Liz, Joaquim D; Waichel, Breno L

    2006-09-01

    The Neoproterozoic shoshonitic and mildly alkaline bimodal volcanism of Southernmost Brazil is represented by rock assemblages associated to sedimentary successions, deposited in strike-slip basins formed at the post-collisional stages of the Brasilian/Pan-African orogenic cycle. The best-preserved volcano sedimentary associations occur in the Camaquã and Campo Alegre Basins, respectively in the Sul-riograndense and Catarinense Shields and are outside the main shear belts or overlying the unaffected basement areas. These basins are characterized by alternation of volcanic cycles and siliciclastic sedimentation developed dominantly on a continental setting under subaerial conditions. This volcanism and the coeval plutonism evolved from high-K tholeiitic and calc-alkaline to shoshonitic and ended with a silica-saturated sodic alkaline magmatism, and its evolution were developed during at least 60 Ma. The compositional variation and evolution of post-collisional magmatism in southern Brazil are interpreted as the result mainly of melting of a heterogeneous mantle source, which includes garnet-phlogopite-bearing peridotites, veined-peridotites with abundant hydrated phases, such as amphibole, apatite and phlogopite, and eventually with the addition of an asthenospheric component. The subduction-related metasomatic character of post-collisional magmatism mantle sources in southern Brazil is put in evidence by Nb-negative anomalies and isotope features typical of EM1 sources. PMID:16936944

  8. Fracture Detection in Geothermal Wells Drilled in Volcanic Rocks

    SciTech Connect

    Gonfalini, Mauro; Chelini, Walter; Cheruvier, Etienne; Suau, Jean; Klopf, Werner

    1987-01-20

    The Phlegrean Fields, close to Naples, are the site of important geothermal activity. The formations are volcanic and mostly tuffites. They are originally very tight but the geothermal alteration locally produces fractures with large increase in permeability. The lack of geological markers makes well-to-well correlation quite difficult. Thus the local detection of fractured zones in each well is very important for the evaluation of its potential. The Mofete 8 D well is a typical example. A rather complete logging program was run for fracture detection. Standard methods turned out to be disappointing. However several non-standard detectors were found to be very consistent and, later on, in excellent agreement with the analysis of cuttings. They are derived from the Dual Laterolog, the SP, the Temperature log and, most particularly, the Acoustic Waveforms from the Long Spacing Sonic. The Dual Laterolog and the Temperature Log indicate invasion by fresh and cold mud filtrate; the SP behaves as in a typical Sand-Shale sequence. Sonic Waveforms were first analyzed by a purely empirical method derived from consistent log patterns. A practical algorithm compares the total energy measured in each of the two fixed time windows located the one before, the other after the fluid arrivals. The altered zones (i.e. fractured and permeable) are clearly shown by a complete reversal of the relative energy of these two windows. A more scientific method was then applied to the Waveforms; it is based on both logging experiments and physical considerations. The energy carried by the tube wave is separated by a frequency discrimination: it correlates very well with formation alteration, thus also with the other indicators including the empirical Waveform method. It should have two advantages: – It should permit at least a semi quantitative permeability evaluation – It seems to be promising in other formations: non-volcanic geothermal wells and even hydrocarbon-bearing rocks. 10 refs

  9. 40Ar/39Ar geochronology of the Fernando de Noronha Archipelago and implications for the origin of alkaline volcanism in the NE Brazil

    NASA Astrophysics Data System (ADS)

    Perlingeiro, Gabriela; Vasconcelos, Paulo M.; Knesel, Kurt M.; Thiede, David S.; Cordani, Umberto G.

    2013-01-01

    The Fernando de Noronha archipelago, centered ~ 250 km off the northeastern coast of Brazil, is comprised of a diverse suite of alkaline volcanic rocks commonly associated with a mantle-plume origin. Although previous K-Ar determinations divide the three main volcanic formations of the archipelago (Remédios, Quixaba and São José formations) into two age groups, a few ages conflicting with the stratigraphic framework were suspected to suffer from excess argon. To evaluate the presence or absence of excess Ar and to improve the geochronological database for the archipelago, we have dated, by the laser incremental-heating 40Ar/39Ar method, the exact same hand specimens previously dated by K-Ar. The 22 samples studied here yield plateau ages for at least one of the two grains analyzed and none of the specimens contain significant excess Ar. Our results derive a chronostratigraphic sequence for the archipelago that is consistent with the earlier K-Ar determinations. The main discrepancy is related to some basanitic rocks of São José formation, interpreted as the youngest eruptive products which are in fact coeval with the oldest subareal volcanic activity at Fernando de Noronha. Our revised eruptive chronology defines a hiatus of nearly 3 Ma separating an older period of volcanism between 12.5 ± 0.1 and 9.0 ± 0.1 Ma comprising the Remédios and São José formations and a younger episode forming the Quixaba formation between 6.2 ± 0.1 and 1.3 ± 0.1 Ma. Moreover, these results confirm that much of the activity at Fernando de Noronha was contemporaneous with alkaline volcanism well onshore in northeastern Brazil, supporting the suggestion that this hotspot may be a product of small-scale, plate-driven convection in the upper mantle.

  10. Geochemistry of high-potassium rocks from the mid-Tertiary Guffey volcanic center, Thirtynine Mile volcanic field, central Colorado

    SciTech Connect

    Wobus, R.A.; Mochel, D.W. ); Mertzman, S.A.; Eide, E.A.; Rothwarf, M.T. ); Loeffler, B.M.; Johnson, D.A. ); Keating, G.N.; Sultz, K. ); Benjamin, A.E. ); Venzke, E.A. ); Filson, T. )

    1990-07-01

    The Guffey volcanic center is the largest within the 2000 km{sup 2} mid-Tertiary Thirtynine Mile volcanic field of central Colorado. This study is the first to provide extensive chemical data for these alkalic volcanic and subvolcanic rocks, which present the eroded remnants of a large stratovolcano of Oligocene age. Formation of early domes and flows of latite and trachyte within the Guffey center was followed by extrusion of a thick series of basalt, trachybasalt, and shoshonite flows and lahars. Plugs, dikes, and vents ranging from basalt to rhyolite cut the thick mafic deposits, and felsic tuffs breccias chemically identical to the small rhyolitic plutons are locally preserved. Whole-rack major and trace element analyses of 80 samples, ranging almost continuously from 47% to 78% SiO{sub 2}, indicate that the rocks of the Guffey center are among the most highly enriched in K{sub 2}O (up to 6%) and rare earth elements (typically 200-300 ppm) of any volcanic rocks in Colorado. These observations, along with the relatively high concentrations of Ba and Rb and the depletion of Cr and Ni, suggest an appreciable contribution of lower crustal material to the magmas that produced the Thirtynine Mile volcanic rocks.

  11. Geology, geochronology and tectonic setting of late Cenozoic volcanism along the southwestern Gulf of Mexico: The Eastern Alkaline Province revisited

    NASA Astrophysics Data System (ADS)

    Ferrari, Luca; Tagami, Takahiro; Eguchi, Mugihiko; Orozco-Esquivel, Ma. Teresa; Petrone, Chiara M.; Jacobo-Albarrán, Jorge; López-Martínez, Margarita

    2005-09-01

    A NNW-trending belt of alkaline mafic volcanic fields parallels the Gulf of Mexico from the U.S. border southward to Veracruz state, in eastern Mexico. Previous studies grouped this volcanism into the so-called "Eastern Alkaline Province" (EAP) and suggested that it resulted from Gulf-parallel extensional faulting migrating from north to south from Oligocene to Present. On the basis of new geologic studies, forty-nine unspiked K-Ar and two 40Ar- 39Ar ages, we propose a new geodynamic model for the volcanism along the southwestern Gulf of Mexico. We studied in detail four of the six recognized fields of mafic alkaline volcanism in Veracruz state: 1) The lavas flows of Tlanchinol area (7.3-5.7 Ma), 2) the Alamo monogenetic field and Sierra de Tantima (7.6-6.6 Ma), 3) the Poza Rica and Metlatoyuca lava flows (1.6-1.3 Ma) and 4) the Chiconquiaco-Palma Sola area (6.9-3.2 Ma). Other two mafic volcanic fields may represent the continuation of alkaline volcanism to the southeast: the Middle Miocene lavas at Anegada High, offshore port of Veracruz, and the Middle to Late Miocene volcanism at the Los Tuxtlas. The existence of major Neogene extensional faults parallel to the Gulf of Mexico (i.e., ˜N-S to NNW-SSE) proposed in previous works was not confirmed by our geological studies. Elongation of volcanic necks, vent alignment, and faults mapped by subsurface data trend dominantly NE to ENE and NW to NNW. These directions are parallel to transform and normal faults that formed during the Late Jurassic opening of the Gulf of Mexico. Ascent of mafic magmas was likely facilitated and controlled by the existence of these pre-existing basement structures. Coupled with previous studies, our data demonstrate the occurrence of three magmatic episodes in Veracruz: 1) A Middle Miocene (˜15-11 Ma) episode in southern Veracruz (Palma Sola, Anegada, and Los Tuxtlas); 2) A Late Miocene to Early Pliocene (˜7.5-3 Ma) pulse of mafic alkaline volcanism throughout the study region; and 3) A

  12. Triple junction magmatism: a geochemical study of Neogene volcanic rocks in western California

    USGS Publications Warehouse

    Johnson, C.M.; O'Neil, J.R.

    1984-01-01

    Inception of volcanism at late Oligocene to Recent centers in the eastern Coast Ranges of California (ECR suite) regularly decreases in age northward and is correlated with the northward migration of the transform-transform-trench Mendocino triple junction (MTJ). Miocene volcanism in the southern California basin (SCB suite) is spatially and temporally associated with the transform-ridge-trench Rivera triple junction (RTJ). The tholeiitic to calc-alkaline rocks in both suites were erupted through older trench melange while arc magmatism was occurring several hundred kilometers to the east. Therefore they are not related to subduction zone magmatism, but instead to interactions of the MTJ and RTJ with the continental margin. The ECR rocks, dominantly intermediate to silicic in composition, have relatively high ??18O values up to 11.3, 87Sr 86Sr ratios up to 0.7055, as well as relatively high Th contents, suggesting that crustal anatexis played a dominant role in their generation. Coupled crystal fractionation and crustal assimilation by an initially basaltic magma cannot explain the high ??18O values and 87Sr 86Sr ratios because greater than 95% of the basalt would need to crystallize. In contrast, the SCB rocks, dominantly mafic to intermediate in composition, have relatively low ??18O values down to 5.2 and 87Sr 86Sr ratios down to 0.7025 suggesting that these rocks were derived dominantly from a mantle source. Whether crustal anatexis occurs is determined largely by the type of stress a triple junction imposes upon the continental margin. Both the MTJ and RTJ are associated with high heat flow and magma fluxes from the mantle. The transform-transform-trench MTJ is associated with locally variable mild extension to compression and therefore allows pooling of basaltic magma in the crust to initiate crustal melting. The high rates of continental extension associated with the transform-ridge-trench RTJ prevents such pooling of magma. The space created by decoupling

  13. Reservoir Space Evolution of Volcanic Rocks in Deep Songliao Basin, China

    NASA Astrophysics Data System (ADS)

    Zheng, M.; Wu, X.; Zheng, M.; HU, J.; Wang, S.

    2015-12-01

    Recent years, large amount of natural gas has been discovered in volcanic rock of Lower Crataceous of Songliao basin. Volcanic reservoirs have become one of the important target reservoir types of eastern basin of China. In order to study the volcanic reservoirs, we need to know the main factors controlling the reservoir space. By careful obsercation on volcanic drilling core, casting thin sections and statistical analysis of petrophysical properties of volcanic reservoir in Songliao basin, it can be suggested that the igneous rock reservoir in Yingcheng formation of Lower Crataceous is composed of different rock types, such ad rohylite, rohylitic crystal tuff, autoclastic brecciation lava and so on. There are different reservoirs storage space in in various lithological igneous rocks, but they are mainly composed of primary stoma, secondary solution pores and fractures.The evolution of storage space can be divided into 3 stage: the pramary reservoir space,exogenic leaching process and burial diagenesis.During the evolution process, the reservoir space is effected by secondary minerals, tectonic movement and volcanic hydrothermal solution. The pore of volcanic reservoirs can be partially filled by secondary minerals, but also may be dissoluted by other chemical volcanic hydrothermal solution. Therefore, the favorable places for better-quality volcanic reservoirs are the near-crater facies of vocanic apparatus and dissolution zones on the high position of paleo-structures.

  14. Fission-track dating of volcanically derived sedimentary rocks

    SciTech Connect

    Kowallis, B.J.; Heaton, J.S.; Bringhurst, K.

    1986-01-01

    Depositional ages of sedimentary rocks can be determined using fission-track single grain ages on zircons from layers of volcanic ash or bentonite, even when the layers have been contaminated by older grains. This is done by compiling an age probability distribution or age spectrum for a sample from individual grain ages. An age spectrum is a simple and unambiguous way of testing for contamination and extracting useful age information. The youngest peak in the age spectrum approximates the time of deposition. In most contaminated samples, 30 or more grains should be counted to produce a reliable spectrum. However, useful, reproducible ages can be obtained by counting less than 10 grains in samples where most of the older, contaminating grains can be removed. The few older grains that remain after removing the obviously abraded ones may then be eliminated by examining the age spectrum. Although ages determined in this way are probably not precise enough for use in defining stratigraphic boundaries, they still provide a means of obtaining an isotopic age in sediments that cannot be dated by other radiometric methods. 18 references, 3 figures, 3 tables.

  15. Identification of kaolins and associated minerals in altered volcanic rocks by infrared spectroscopy.

    USGS Publications Warehouse

    Hunt, G.R.; Hall, R.B.

    1981-01-01

    Examples of visible and near-infrared spectra of altered volcanic rocks and their mineral constituents from Utah and Arizona are presented here to illustrate the potential of this spectral range. -from Authors

  16. Geochemistry and Ar/Ar dating of upper pleistocene volcanic rocks from Kerguelen islands (Indian Ocean)

    NASA Astrophysics Data System (ADS)

    Ethien, R.; Feraud, G.; Gerbe, M. C.; Cottin, J. Y.; O'Reilly, S. Y.; Giret, A.

    2003-04-01

    The Kerguelen islands archipelago (6500 Km^2) is the third largest oceanic island in the world, after Island and Hawaï. It is located upon the Kerguelen plateau, which is the second Large Igneous Province (LIP) after Ontong-Java. This oceanic plateau consist of an accumulation of flood basalts, related to the long-lived ˜119 Ma Kerguelen plume. The flood basalts (˜29-24 Ma; Nicolaysen et al., 2000) represent 85% of the rocks of Kerguelen. The Rallier-du-Baty (R.d.B.) peninsula, which forms the southwestern part of the Kerguelen archipelago, is mostly made of alkaline rocks constituting two well-defined ring-complexes. The northern ring-complex consists of a succession of seven discrete syenitic ring-dykes, one later caldera volcano and a more recent volcanic complex. The volcanism is bimodal with trachy-basalts and trachy-andesites, with true scarce basalts constituting the mafic lavas and trachytes and rhyolites constituting the felsic lavas. The felsic magmas were erupted as abundant pyroclastic deposits and lava flows. The mineralogy of those volcanic rocks is typical of an alcaline series, with the presence of K-feldspars (sanidines) in the most differentiated volcanic rocks. The evolution from trachyte to rhyolite seems to be controlled by crystal fractionation, with some trace element distribution and Sr isotopic ratios largely disturbed by open-system processes such as assimilation of hydrothermally altered crust and interaction with seawater. The studies of the oxygen isotopes confirm this hypothesis. Indeed, the high values of δ18O for the rhyolites (δ18O= 10.3 and 12.4) could be interpreted by an alteration by fluids at low temperatures. The Nd isotopic ratio are typical of mantellic values, with no significant variations. Whereas some units of the northern R.d.B. plutonic complex yield a narrow range of K/Ar ages on bulk rocks, from 6.2 ± 0.2 Ma to 4.9 ± 0.2 Ma (Dosso and al., 1979), the formation of a discrete caldera centered on the "Table de l

  17. Evaluation of Early Archean Volcaniclastic and Volcanic Flow Rocks as Possible Sites for Carbonaceous Fossil Microbes

    NASA Astrophysics Data System (ADS)

    Walsh, Maud M.

    2004-12-01

    Sedimentary rocks have traditionally been the focus of the search for Archean microfossils; the Earth's oldest fossil bacteria are associated with carbonaceous matter in sedimentary cherts in greenstone belts in the eastern Pilbara block of Western Australia and Barberton greenstone belt of South Africa. Reports of possible fossils in a martian meteorite composed of igneous rock and the discovery of modern bacteria associated with basalts have stimulated a new look at Archean volcanic rocks as possible sites for fossil microbes. This study examines silicified volcaniclastic rocks, near-surface altered volcanic flow rocks, and associated stromatolite- like structures from the Archean Barberton greenstone belt to evaluate their potential for the preservation of carbonaceous fossils. Detrital carbonaceous particles are widely admixed with current-deposited debris. Carbonaceous matter is also present in altered volcanic flow rocks as sparse particles in silica veins that appear to be fed by overlying carbonaceous chert layers. Neither microfossils nor mat-like material was identified in the altered volcanic rocks or adjacent stromatolite-like structures. Ancient volcanic flow and volcaniclastic rocks are not promising sites for carbonaceous fossil preservation. Astrobiology 4, 429-437.

  18. Evaluation of early Archean volcaniclastic and volcanic flow rocks as possible sites for carbonaceous fossil microbes.

    PubMed

    Walsh, Maud M

    2004-01-01

    Sedimentary rocks have traditionally been the focus of the search for Archean microfossils; the Earth's oldest fossil bacteria are associated with carbonaceous matter in sedimentary cherts in greenstone belts in the eastern Pilbara block of Western Australia and Barberton greenstone belt of South Africa. Reports of possible fossils in a martian meteorite composed of igneous rock and the discovery of modern bacteria associated with basalts have stimulated a new look at Archean volcanic rocks as possible sites for fossil microbes. This study examines silicified volcaniclastic rocks, near-surface altered volcanic flow rocks, and associated stromatolite- like structures from the Archean Barberton greenstone belt to evaluate their potential for the preservation of carbonaceous fossils. Detrital carbonaceous particles are widely admixed with current-deposited debris. Carbonaceous matter is also present in altered volcanic flow rocks as sparse particles in silica veins that appear to be fed by overlying carbonaceous chert layers. Neither microfossils nor mat-like material was identified in the altered volcanic rocks or adjacent stromatolite-like structures. Ancient volcanic flow and volcaniclastic rocks are not promising sites for carbonaceous fossil preservation. PMID:15684724

  19. Petrogenesis of Late Cenozoic volcanic rocks from the Raton-Clayton volcanic field, northeastern New Mexico and southeastern Colorado

    SciTech Connect

    Zhu, J.; Stormer, J.C.; Wright, J.E. . Dept. of Geology and Geophysics); Middlefeldt, D.D. )

    1993-04-01

    The Raton-Clayton volcanic field, located in the eastern flank of the Rio Grande rift on the Great Plains, is at the northeastern end of the Jemez lineament. A broad variety of late Cenozoic volcanic rocks ranging from rhyodacites through basalts to basanites and nephelinites, with well established ages, provides a good probe of magma sources at different depths down to the mantle. New Sr, Nd and Pb isotopic data on late Cenozoic volcanic rocks from the Raton-Clayton volcanic field yield significant variations. [sup 87]Sr/[sup 86]Sr ratios vary from 0.70397--0.70499, [var epsilon][sub Nd] values range from [minus]3.7--2.4, [sup 206]Pb/[sup 204]Pb ratios are in the range of 17.43--18.48, [sup 207]Pb/[sup 204]Pb from 15.45--15.54 and [sup 208]Pb/[sup 204]Pb from 37.27--38.05. The mafic feldspathoidal rocks, believed to be derived from the enriched mantle reservoir with little crustal contamination, show relatively homogeneous [sup 87]Sr/[sup 86]Sr (ca. 0.7041) and [var epsilon][sub Nd] (ca. 2). A positive trend of Pb isotopic ratios, however, suggests possible mantle heterogeneity in Pb isotopic composition beneath the continent. Isotopic data from basaltic lavas display well defined variation trends, bringing to light the role of crustal components in the magmatic process. A strong signature of upper crustal involvement is indicated in the formation of tholeiitic basalts with dicktytaxitic texture, while isotope data from alkali olivine basalts and Capulin trachybasalts suggest lower crust contaminations of these rocks. An apparent isotopic variation trend of the dicktytaxitic basalts is well correlated with geographic location from south to north. Significant discrepancies in isotopic compositions of more silicic rocks compared with those of similar rocks from the Taos Plateau volcanic field to the west, may indicate either large differences in lower crustal composition or different mechanisms in generating these magmas.

  20. Sr, Nd, Pb Isotope geochemistry and magma evolution of the potassic volcanic rocks, Wudalianchi, Northeast China

    USGS Publications Warehouse

    Junwen, W.; Guanghong, X.; Tatsumoto, M.; Basu, A.R.

    1989-01-01

    Wudalianchi volcanic rocks are the most typical Cenozoic potassic volcanic rocks in eastern China. Compositional comparisons between whole rocks and glasses of various occurrences indicate that the magma tends to become rich in silica and alkalis as a result of crystal differentiation in the course of evolution. They are unique in isotopic composition with more radiogenic Sr but less radiogenic Pb.87Sr /86 Sr is higher and143Nd/144Nd is lower than the undifferentiated global values. In comparison to continental potash volcanic rocks, Pb isotopes are apparently lower. These various threads of evidence indicate that the rocks were derived from a primary enriched mantle which had not been subjected to reworking and shows no sign of incorporation of crustal material. The correlation between Pb and Sr suggests the regional heterogeneity in the upper mantle in terms of chemical composition. ?? 1989 Institute of Geochemistry, Chinese Academy of Sciences.

  1. Geochronology and geochemistry of Eocene-aged volcanic rocks around the Bafra (Samsun, N Turkey) area: Constraints for the interaction of lithospheric mantle and crustal melts

    NASA Astrophysics Data System (ADS)

    Temizel, İrfan; Arslan, Mehmet; Yücel, Cem; Abdioğlu, Emel; Ruffet, Gilles

    2016-08-01

    40Ar-39Ar age, whole-rock chemical, and Sr-Nd isotope data are presented for the post-collisional, Eocene (51.3-44.1 Ma)-aged volcanic rocks from the Bafra (Samsun) area in the western part of the Eastern Pontides (N Turkey) aiming to unravel their sources and evolutionary history. The studied Eocene volcanic rocks can be divided into two groups: analcime-bearing (tephritic lava flows and dykes) and analcime-free (basaltic to trachytic lava flows and basaltic dykes). The analcime-bearing volcanic rocks have a fine-grained porphyritic texture with clinopyroxene phenocrysts, whereas analcime-free volcanic rocks show a variety of textures including hyalo-microlitic microgranular porphyritic, intersertal, trachytic, fluidal, and glomeroporphyritic. The volcanic rocks also show evidence of mineral-melt disequilibrium textures such as sieved, rounded, and corroded plagioclases, partially melted and dissolved clinopyroxenes and poikilitic texture. Petrochemically, the parental magmas of the volcanic rocks evolved from alkaline to calc-alkaline lava suites and include high-K and shoshonitic compositions. They display enrichments in light rare earth and large ion lithophile elements such as Sr, K, and Rb, as well as depletions in high field strength elements such as Nb, Ta, Zr, and Ti, resembling subduction-related magmas. The analcime-bearing and -free volcanic rocks share similar incompatible element ratios and chondrite-normalised rare rearth element patterns, indicating that they originated from similar sources. They also have relatively low to moderate initial 87Sr/86Sr (0.7042-0.7051), high positive εNd(t) values (+ 0.20 to + 3.32), and depleted mantle Nd model ages (TDM1 = 0.63-0.93 Ga, TDM2 = 0.58-0.84 Ga). The bulk-rock chemical and Sr-Nd isotope features as well as the high Rb/Y and Th/Zr, but low Nb/Zr and Nb/Y ratios, indicate that the volcanic rocks were derived from a lithospheric mantle source that had been metasomatised by slab-derived fluids. Trace element

  2. Uranium mineralization in fluorine-enriched volcanic rocks

    SciTech Connect

    Burt, D.M.; Sheridan, M.F.; Bikun, J.; Christiansen, E.; Correa, B.; Murphy, B.; Self, S.

    1980-09-01

    Several uranium and other lithophile element deposits are located within or adjacent to small middle to late Cenozoic, fluorine-rich rhyolitic dome complexes. Examples studied include Spor Mountain, Utah (Be-U-F), the Honeycomb Hills, Utah (Be-U), the Wah Wah Mountains, Utah (U-F), and the Black Range-Sierra Cuchillo, New Mexico (Sn-Be-W-F). The formation of these and similar deposits begins with the emplacement of a rhyolitic magma, enriched in lithophile metals and complexing fluorine, that rises to a shallow crustal level, where its roof zone may become further enriched in volatiles and the ore elements. During initial explosive volcanic activity, aprons of lithicrich tuffs are erupted around the vents. These early pyroclastic deposits commonly host the mineralization, due to their initial enrichment in the lithophile elements, their permeability, and the reactivity of their foreign lithic inclusions (particularly carbonate rocks). The pyroclastics are capped and preserved by thick topaz rhyolite domes and flows that can serve as a source of heat and of additional quantities of ore elements. Devitrification, vapor-phase crystallization, or fumarolic alteration may free the ore elements from the glassy matrix and place them in a form readily leached by percolating meteoric waters. Heat from the rhyolitic sheets drives such waters through the system, generally into and up the vents and out through the early tuffs. Secondary alteration zones (K-feldspar, sericite, silica, clays, fluorite, carbonate, and zeolites) and economic mineral concentrations may form in response to this low temperature (less than 200 C) circulation. After cooling, meteoric water continues to migrate through the system, modifying the distribution and concentration of the ore elements (especially uranium).

  3. Relation of Volcanism to Crustal Deformation in Klamath Falls, Oregon: Transition from Calc-alkaline Basaltic Andesite to High Alumina Olivine Tholeiite

    NASA Astrophysics Data System (ADS)

    Priest, G. R.; Hladky, F. R.; Murray, R. B.

    2009-12-01

    This paper is based on geologic mapping by Priest et al. (2008) at Klamath Falls, Oregon on the southernmost end of the Klamath Graben. Northeast-southwest extension across this area caused northeast tilting of fault blocks on the east side and southwest tilting of blocks on the west side of the Graben. Dominant strike of these Basin and Range fault blocks is N. 30-40° W. At Klamath Falls the two opposing groups of tilted blocks are separated not by a keystone graben but by a complex of bounding faults striking ~N. 65° W. The bounding faults appear to have components of right-lateral or reverse motion, cut rocks dated at ~4 Ma, and terminate to the northwest against northeast-striking faults at the southern boundary of the Graben. Normal faults within the study area cut basalt dated at 1.8 Ma on the west side of the Graben. Holocene talus is cut on the east side of the Graben immediately north of the study area. The 1993 magnitude 5.9 and 6.0 earthquakes on the west margin of the Klamath Graben are evidence that extensional deformation is continuing there. The youngest proven deformation in the map area south of the Graben boundary is offset Pleistocene alluvial fans at the base of Hogback Mountain. These fans are now preserved as discontinuous hills but once filled the local Altamont basin by up to 150 m higher than its present surface. Much of this sand and gravel has been eroded, possibly coincident with breaching of the basin at ~1 Ma by headward erosion of the Klamath River. Magmatic composition changed as crustal extension in the area progressed and the width of the Cascade volcanic arc decreased. Between ~6 and 4 Ma, calc-alkaline basaltic andesite and andesite from local volcanic centers of the volcanic arc flowed unimpeded across the area, thus the current Basin and Range topography had not developed. Angular unconformities within sequences of volcanic and volcaniclastic rocks dated at 4-2.7 Ma indicate contemporaneous tilting of fault blocks, but much

  4. Uranium-series disequilibria in Vanuatu arc volcanic rocks: constraints on pre-eruptive processes in contrasting volcanic systems

    NASA Astrophysics Data System (ADS)

    Handley, H. K.; Turner, S.; Reagan, M. K.; Girard, G.; Cronin, S. J.; Firth, C.

    2011-12-01

    Recent and present volcanism in the Vanuatu arc (South West Pacific Ocean) occurs at a variety of volcano types that exhibit a wide range of eruptive behaviour: from post-caldera lava-lake activity and lava flows at shield volcanoes (Ambrym), moderately explosive sub-plinian events and associated pyroclastic-flows and lava flows at stratovolcanoes (Lopevi), to persistent strombolian and vulcanian-style eruptions at scoria cones (Yasur). This precludes a generic model of magmatic and eruptive behaviour for the Vantuatu arc volcanoes and necessitates a detailed study of each system. Uranium-series disequilibria in volcanic rocks offer unique insights into pre-eruptive magmatic systems over process-relevant timescales e.g., 238U-230Th (380Ka), 230Th-226Ra (8Ka) and 226Ra-210Pb (100a). The short half-life of 210Pb (t1/2 = 22.6 years) and the volatile nature of the intermediate isotope, 222Rn, (intermediate between the 226Ra parent and 210Pb daughter) provide valuable information on magma transport, evolution and degassing over a timescale more pertinent to the processes leading up to volcanic eruptions. We present new Uranium-series isotope data (U-Th-Ra-210Pb) for young (< 100 years old) volcanic samples from Ambrym, Lopevi and Yasur volcanoes to investigate the timescales of magmatic evolution and degassing in the contrasting volcanic systems. 210Pb deficits ((210Pb/226Ra)0 < 1) in Ambrym and Yasur volcanic rocks suggest effective open-system magmatic degassing of 222Rn, consistent with the persistent lava-lakes/exposed magma and significant gas emissions observed at both volcanoes. Lopevi, on the other hand, largely displays excess 210Pb ((210Pb/226Ra)0 > 1) suggesting that 222Rn gas accumulation and fluxing preceding and/or during eruption (on a decadal timescale) is responsible for the more explosive-style of eruption witnessed at this volcano. Significant accumulation of recently crystallised plagioclase phenocrysts can also create 210Pb excesses in volcanic

  5. Anorthosites and alkaline rocks from the deep crust of peninsular India

    NASA Technical Reports Server (NTRS)

    Leelanandam, C.; Ratnakar, J.; Reddy, M. Narsimha

    1988-01-01

    The anorthosite and alkaline rock localities in the Precambrian Shield of Peninsular India were reviewed. There are approximately 50 localities of such rocks, generally restricted to the Eastern Ghats mobile belt. The alkaline plutons are typically confined to the margin of the Eastern Ghats. The anorthosites are all greater than 500 sq km, but many exhibit similarities to one another. It was suggested that the anorthosites are associated with cryptic sutures, and are thought to have originated as a result of ponding of basaltic magmas. An analogy was drawn between the Eastern Ghats belt and the Grenville Province of the Canadian Shield.

  6. Hydration of Volcanic Glass with Super-Critical Water and its Effect on Permeability of Volcanic Rocks

    NASA Astrophysics Data System (ADS)

    Isobe, H.

    2006-12-01

    Behavior of high-temperature, high-pressure fluid flow in volcanoes depends on permeability of rocks in fluid paths. High pressure fluids or vapors in volcanoes, which are in super-critical states, are essential factors of volcanic eruptions. Especially, phreatomagmatic eruptions are caused by excess pressures of the fluid degassed from magma body or heated water contacted with magma or high temperature rocks in volcanoes. Alteration processes of rocks and minerals with super-critical fluid can change permeability of rocks by spreading of the fluid path or obstruction with precipitated minerals. In this study, experimental reproduction on the hydration and alteration processes of rocks and minerals with super-critical fluid flow were carried out with a fluid flow apparatus. Starting materials of the experiments are powdered rhyolitic obsidian and dacite. Approximately 55g of the starting material are placed in a SUS316 sample tube. Inner diameter and length of the sample tube are 9.4mm and 572mm, respectively. Temperature gradient of the pressure vessel is controlled by triple electric furnaces. Run products are retrieved by cutting off the sample tube and observed by SEM. Permeability of run products are also measured by gas flow method. Experimental pressure is 50MPa. Flow rate of distilled water at room temperature is 0.1ml / minute pumped by a low speed high-pressure pump. Temperature of the sample is approximately 450°C for rhyolitic glass powder or 420°C for dacite powder at the first half of the sample tube, then decreased to approximately 310°C at the outlet of the sample tube. Run durations are 3 to 8 days. Obsidian grains and groundmass glass of dacite partially dissolved and changed to porous at higher than approximately 400°C. Alteration products of the volcanic glass including clay minerals, cristobalite and plagioclase occur in grain boundaries and cemented grains within a few centimeters from the outlet of the sample tube. Volcanic glass

  7. Influence of hydrothermal processes on changes of volcanic rocks (data of physical modelling)

    NASA Astrophysics Data System (ADS)

    Shanina, V. V.; Bychkov, A. Y.

    2009-04-01

    Due to active development of geothermal energy, in middle of the last century have begun papers devoted to experiments, directed on study of transformations of minerals [4] and rocks [1, 2, 5] under action of geothermal processes. But any researcher did not estimate thus change of their physical and physico-mechanical properties. The purpose of job - to study character and dynamics changes of volcanic rocks (to simulate conditions of geothermal transformations). Tasks: creation of the whole series of experiments in autoclavs at various temperatures, pressure and composition of solutions, preparation of samples, study of chemical and mineral composition, structure and properties of rocks and solutions before and after experiments. In 2006 the first similar experiments were begun [3]. Researched rocks basalts, hyaloclasites and obsidian, selected from Iceland and tuffs Payzhetka Geothermal Field, Southern Kamchatka, Russia. Were used autoclavs, consisting from titanic of an alloy ВТ-8, volume 116-119 мл, in each of which was located from 2 up to 4 samples of rocks of the investigated structure and properties. The heating was made in OVEN ТРМ-10 with accuracy + 1 °С, the constancy of temperature was supervised by thermocouples. 15 experiences (temperature 200, 300 and 450 °С; pressure 16, 86 and 1000 bars accordingly now are carried out; 4 solutions (1 alkaline and 3 acid); duration 14, 15, 30 and 60 days). All four groups of the investigated rocks appreciablly react under geothermal influence. The changes are observed in colour of samples (brighten in acid solutions), their microstructure, that for basalts is visible only in raster electronic microscope, and in education of new mineral phases, is especially active in a acid solution, the X-Ray analysis (has executed by Dr. Krupskaya V.V., apparatuses - DRON- UM1) has shown, that 94,2 % is smectite, 3,5 % - kaolinite, 1,2 % - crisrobalite, 1,1 % - diopside (?), in others pores fills chlorite, and in an

  8. Influence of hydrothermal processes on changes of volcanic rocks (data of physical modelling)

    NASA Astrophysics Data System (ADS)

    Shanina, V. V.; Bychkov, A. Y.

    2009-04-01

    Due to active development of geothermal energy, in middle of the last century have begun papers devoted to experiments, directed on study of transformations of minerals [4] and rocks [1, 2, 5] under action of geothermal processes. But any researcher did not estimate thus change of their physical and physico-mechanical properties. The purpose of job - to study character and dynamics changes of volcanic rocks (to simulate conditions of geothermal transformations). Tasks: creation of the whole series of experiments in autoclavs at various temperatures, pressure and composition of solutions, preparation of samples, study of chemical and mineral composition, structure and properties of rocks and solutions before and after experiments. In 2006 the first similar experiments were begun [3]. Researched rocks basalts, hyaloclasites and obsidian, selected from Iceland and tuffs Payzhetka Geothermal Field, Southern Kamchatka, Russia. Were used autoclavs, consisting from titanic of an alloy ВТ-8, volume 116-119 мл, in each of which was located from 2 up to 4 samples of rocks of the investigated structure and properties. The heating was made in OVEN ТРМ-10 with accuracy + 1 °С, the constancy of temperature was supervised by thermocouples. 15 experiences (temperature 200, 300 and 450 °С; pressure 16, 86 and 1000 bars accordingly now are carried out; 4 solutions (1 alkaline and 3 acid); duration 14, 15, 30 and 60 days). All four groups of the investigated rocks appreciablly react under geothermal influence. The changes are observed in colour of samples (brighten in acid solutions), their microstructure, that for basalts is visible only in raster electronic microscope, and in education of new mineral phases, is especially active in a acid solution, the X-Ray analysis (has executed by Dr. Krupskaya V.V., apparatuses - DRON- UM1) has shown, that 94,2 % is smectite, 3,5 % - kaolinite, 1,2 % - crisrobalite, 1,1 % - diopside (?), in others pores fills chlorite, and in an

  9. Precursors predicted by artificial neural networks for mass balance calculations: Quantifying hydrothermal alteration in volcanic rocks

    NASA Astrophysics Data System (ADS)

    Trépanier, Sylvain; Mathieu, Lucie; Daigneault, Réal; Faure, Stéphane

    2016-04-01

    This study proposes an artificial neural networks-based method for predicting the unaltered (precursor) chemical compositions of hydrothermally altered volcanic rock. The method aims at predicting precursor's major components contents (SiO2, FeOT, MgO, CaO, Na2O, and K2O). The prediction is based on ratios of elements generally immobile during alteration processes; i.e. Zr, TiO2, Al2O3, Y, Nb, Th, and Cr, which are provided as inputs to the neural networks. Multi-layer perceptron neural networks were trained on a large dataset of least-altered volcanic rock samples that document a wide range of volcanic rock types, tectonic settings and ages. The precursors thus predicted are then used to perform mass balance calculations. Various statistics were calculated to validate the predictions of precursors' major components, which indicate that, overall, the predictions are precise and accurate. For example, rank-based correlation coefficients were calculated to compare predicted and analysed values from a least-altered test dataset that had not been used to train the networks. Coefficients over 0.87 were obtained for all components, except for Na2O (0.77), indicating that predictions for alkali might be less performant. Also, predictions are performant for most volcanic rock compositions, except for ultra-K rocks. The proposed method provides an easy and rapid solution to the often difficult task of determining appropriate volcanic precursor compositions to rocks modified by hydrothermal alteration. It is intended for large volcanic rock databases and is most useful, for example, to mineral exploration performed in complex or poorly known volcanic settings. The method is implemented as a simple C++ console program.

  10. Observations of 231Pa/ 235U disequilibrium in volcanic rocks

    NASA Astrophysics Data System (ADS)

    Pickett, David A.; Murrell, Michael T.

    1997-04-01

    We present here the first survey of ( 231Pa/ 235U) ratios in volcanic rocks; such measurements are made possible by new mass spectrometric techniques. The data place new constraints on the timing and extent of magma source and evolutionary processes, particularly due to the sensitivity of the 231Pa- 235U pair and its intermediate time scale ( 231Pat 1/2 = 33 ky). ( 231Pa/ 235U) is found to vary widely, from 0.2 in carbonatites to 1.1-2.9 in basalts and 0.9-2.2 in arcs. Substantial Pa enrichment is nearly ubiquitous, suggestive of the relative incompatibility of Pa, qualitatively consistent with available partitioning data. The level of 231Pa- 235U disequilibrium typically far exceeds that of 230Th- 238U and is comparable to 226Ra- 230Th. The high ( 231Pa/ 235U) ratios in MORB and other basalts reflect a large degree of discrimination between two incompatible elements, posing challenges for modelling of melt generation and migration. Fundamental differences in ( 231Pa/ 235U) among different basaltic environments are likely related to contrasts in melting zone conditions (e.g., melting rate). Strong ( 231Pa/ 235U) disequilibria in continental basalts, for which ( 230Th/ 238U) disequilibria are small or absent, demonstrate that Pa-U fractionation is possible in both garnet and spinel mantle stability fields. In arcs, correlation of ( 231Pa/ 235U) and ( 230Th/ 238U) is consistent with U enrichment via slab-derived fluids, a process which is additional to the still dominant Pa enrichment. An important new constraint is provided by the observation that the near-equilibrium ( 230Th/ 238U) common to arcs and continental basalts is not typically accompanied by near-equilibrium ( 231Pa/ 235U), arguing against the influence of long magma history, crustal material, or equilibrium mantle sources in affecting decay-series ratios. Small sample sets from two silicic centers illustrate: (1) recent, rapid U enrichment in the magma chamber (El Chichón); and (2) the failure of

  11. 231Pa systematics in postglacial volcanic rocks from Iceland

    NASA Astrophysics Data System (ADS)

    Turner, Simon; Kokfelt, Thomas; Hoernle, Kaj; Lundstrom, Craig; Hauff, Folkmar

    2016-07-01

    Several recent studies have highlighted the potential of combined 238U-230Th and 235U-231Pa systematics to constrain upwelling rates and the role of recycled mafic lithologies in mantle plume-derived basalts. Accordingly, we present measurements of the 231Pa concentrations from 26 mafic volcanic rocks from Iceland, including off-axis basalts from the Snaefellsnes Peninsula, to complement previously published 238U-230Th-226Ra data. 231Pa concentrations vary from 27 to 624 fg/g and (231Pa/235U) ratios from 1.12 to 2.11 with the exception of one anomalous sample from the Southeast Rift which has a 231Pa deficit with (231Pa/235U) = 0.86. An important new result is that basalts from the Southeast Rift and the Snaefellsnes Peninsula define a trend at relatively low (231Pa/235U) for a given (230Th/238U) ratio. Many of the remaining samples fall in or around the global field for ocean island basalts but those from the Mid-Iceland Belt and the Southwest Rift/Reykjanes Peninsula extend to higher (231Pa/235U) ratios at a given (230Th/238U), similar to mid-ocean ridge basalts. In principle, these lavas could result from melting of peridotite at lower pressures. However, there is no reason to suspect that the Mid-Iceland Belt and the Southwest Rift lavas reflect shallower melting than elsewhere in Iceland. In our preferred model, these lavas reflect melting of garnet peridotite whereas those from the Southeast Rift and the Snaefellsnes Peninsula contain a significant contribution (up to 20%) of melt from garnet pyroxenite. This is consistent with incompatible trace element and radiogenic isotope evidence for recycled oceanic crust in these lavas. There is increasing agreement that the displacement of ocean island basalts to lower (231Pa/235U) ratios at a given (230Th/238U), compared to mid-ocean ridge basalts, reflects the role of recycled mafic lithologies such as garnet pyroxenite as well as higher average pressures of melting. It now seems likely that this interpretation may

  12. Geochemical constraints on the evolution of mafic and felsic rocks in the Bathani volcanic and volcano-sedimentary sequence of Chotanagpur Granite Gneiss Complex

    NASA Astrophysics Data System (ADS)

    Saikia, Ashima; Gogoi, Bibhuti; Ahmad, Mansoor; Ahmad, Talat

    2014-06-01

    The Bathani volcanic and volcano-sedimentary (BVS) sequence is a volcanic and volcano-sedimentary sequence, best exposed near Bathani village in Gaya district of Bihar. It is located in the northern fringe of the Chotanagpur Granite Gneiss Complex (CGGC). The volcano-sedimentary unit comprises of garnet-mica schist, rhyolite, tuff, banded iron formation (BIF) and chert bands with carbonate rocks as enclaves within the rhyolite and the differentiated volcanic sequence comprises of rhyolite, andesite, pillow basalt, massive basalt, tuff and mafic pyroclasts. Emplacement of diverse felsic and mafic rocks together testifies for a multi-stage and multi-source magmatism for the area. The presence of pillow basalt marks the eruption of these rocks in a subaqueous environment. Intermittent eruption of mafic and felsic magmas resulted in the formation of rhyolite, mafic pyroclasts, and tuff. Mixing and mingling of the felsic and mafic magmas resulted in the hybrid rock andesite. Granites are emplaced later, cross-cutting the volcanic sequence and are probably products of fractional crystallization of basaltic magma. The present work characterizes the geochemical characteristics of the magmatic rocks comprising of basalt, andesite, rhyolite, tuff, and granite of the area. Tholeiitic trend for basalt and calc-alkaline affinities of andesite, rhyolite and granite is consistent with their generation in an island arc, subduction related setting. The rocks of the BVS sequence probably mark the collision of the northern and southern Indian blocks during Proterozoic period. The explosive submarine volcanism may be related to culmination of the collision of the aforementioned blocks during the Neoproterozoic (1.0 Ga) as the Grenvillian metamorphism is well established in various parts of CGGC.

  13. Elemental and Sr Nd Pb isotopic geochemistry of Late Paleozoic volcanic rocks beneath the Junggar basin, NW China: Implications for the formation and evolution of the basin basement

    NASA Astrophysics Data System (ADS)

    Zheng, Jianping; Sun, Min; Zhao, Guochun; Robinson, Paul T.; Wang, Fangzheng

    2007-03-01

    The basement beneath the Junggar basin has been interpreted either as a micro-continent of Precambrian age or as a fragment of Paleozoic oceanic crust. Elemental and Sr-Nd-Pb isotopic compositions and zircon Pb-Pb ages of volcanic rocks from drill cores through the paleo-weathered crust show that the basement is composed mainly of late Paleozoic volcanic rock with minor shale and tuff. The volcanic rocks are mostly subalkaline with some minor low-K rocks in the western Kexia area. Some alkaline lavas occur in the central Luliang uplift and northeastern Wulungu depression. The lavas range in composition from basalts to rhyolites and fractional crystallization played an important role in magma evolution. Except for a few samples from Kexia, the basalts have low La/Nb (<1.4), typical for oceanic crust derived from asthenospheric melts. Zircon Pb-Pb ages indicate that the Kexia andesite, with a volcanic arc affinity, formed in the early Carboniferous (345 Ma), whereas the Luliang rhyolite and the Wucaiwan dacite, with syn-collisional to within-plate affinities, formed in the early Devonian (395 and 405 Ma, respectively). Positive ɛNd( t) values (up to +7.4) and low initial 87Sr/ 86Sr isotopic ratios of the intermediate-silicic rocks suggest that the entire Junggar terrain may be underlain by oceanic crust, an interpretation consistent with the juvenile isotopic signatures of many granitoid plutons in other parts of the Central Asia Orogenic Belt. Variation in zircon ages for the silicic rocks, different Ba, P, Ti, Nb or Th anomalies in the mafic rocks, and variable Nb/Y and La/Nb ratios across the basin, suggest that the basement is compositionally heterogeneous. The heterogeneity is believed to reflect amalgamation of different oceanic blocks representing either different evolution stages within a single terrane or possibly derivation from different terranes.

  14. Preliminary results of wildcat drilling in Absaroka volcanic rocks, Hot Springs County, Wyoming

    SciTech Connect

    Bailey, M.H.; Sundell, K.A.

    1986-08-01

    Recent drilling of three remote, high-elevation wildcat wells has proven that excellent Paleozoic reservoirs are present at shallow depths beneath Eocene volcaniclastic rocks. The Tensleep and Madison Formations are fluid filled above an elevation of 8000 ft, and all Paleozoic formations exhibit shows of oil and gas. These prolific reservoir rocks have produced billions of barrels of oil from the adjacent Bighorn and Wind river basins, and they pinch out with angular unconformity against the base of the volcanics, providing enormous potential for stratigraphic oil accumulations. Vibroseis and portable seismic data have confirmed and further delineate large anticlines of Paleozoic rocks, which were originally discovered by detailed surface geologic mapping. These structures can be projected along anticlinal trends from the western Owl Creek Mountains to beneath the volcanics as well. The overlying volcanics are generally soft, reworked sediments. However, large, hard boulders and blocks of andesite-dacite, which were previously mapped as intrusives, are present and are the result of catastrophic landslide/debris flow. The volcanics locally contain highly porous and permeable sandstones and abundant bentonite stringers. Oil and gas shows were observed throughout a 2400-ft thick interval of the Eocene Tepee Trail and Aycross Formations. Shows were recorded 9100 ft above sea level in the volcanic rocks. A minimum of 10 million bbl of oil (asphaltum) and an undetermined amount of gases and lighter oils have accumulated within the basal volcanic sequence, based on the evaluation of data from two drill sites. Significant amounts of hydrocarbons have migrated since the volcanics were deposited 50 Ma. Large Laramide anticlines were partially eroded and breached into the Paleozoic formations and resealed by overlying volcanics with subsequent development of a massive tar seal.

  15. Age and tectonic significance of volcanic rocks in the northern Los Angeles Basin, California

    USGS Publications Warehouse

    McCulloh, Thane H.; Fleck, Robert J.; Denison, Rodger E.; Beyer, Larry A.; Stanley, Richard G.

    2002-01-01

    Volcanic rocks, mostly basalts and some andesites, are interbedded with middle Miocene strata and are overlain by younger rocks throughout the greater part of the Los Angeles Basin, California. Roughly correlative flows, previously dated radiometrically (or paleontologically) at about 16.4 to 10.7 Ma, crop out in five separate regions around the basin perimeter. Los Angeles Basin volcanic rocks have special meaning because they offer clues to tectonomagmatic events associated with onset of clockwise transrotation of the western Transverse Ranges region and to the timing and locus of the initial basin opening. Whole-rock 40Ar/39Ar dating of near-tholeiitic olivine basalts of the Topanga Formation (Hoots, 1931) from three sites in the easternmost Santa Monica Mountains, combined with 87Sr/86Sr dating of fossil carbonates from interstratified marine beds at nine sites, establish a new age of 17.4 Ma for these oldest known Topanga-age volcanics of the Los Angeles Basin. We also record three new 40Ar/39Ar ages (15.3 Ma) from andesitic flows of the lower Glendora Volcanics at the northeast edge of the basin, 70 km east of the Santa Monica Mountains. A whole-rock determination of 17.2±0.5 Ma for nearby altered olivine basalt in the unfossiliferous Glendora volcanic sequence is questionable because of a complex 40Ar/39Ar age spectrum suggestive of 39Ar recoil, but it may indicate an older volcanic unit in this eastern area. We hypothesize that the 17.4-Ma volcanics in the eastern Santa Monica Mountains are an early expression of deep crustal magmatism accompanying the earliest extensional tectonism associated with rifting. The extremely thick younger volcanic pile in the western and central parts of the range may suggest that this early igneous activity in the eastern area was premonitory. Paleomagnetic declination data are needed to determine the pre-transrotational orientation of the eastern Santa Monica Mountains volcanic sequence. The new age determinations do not

  16. Marano volcanic rocks, East Azarbaijan Province, Iran, and associated Fe mineralisation

    NASA Astrophysics Data System (ADS)

    Karimzadeh Somarin, A.

    2004-10-01

    There are two main types of economic iron ore deposits in Iran: (1) magmatic segregation deposits and (2) skarns. Most of the hydrothermal iron deposits in Iran, except for the skarns, are uneconomic. One of these uneconomic hydrothermal deposits is the Marano Fe deposit, located in East Azarbaijan Province (NW Iran). This deposit is considered to have been formed by an epithermal style of mineralisation related to a volcanic-dome. There are 5 volcanic domes in the Marano area, ranging in composition from dacite to rhyolite. The volcanic rocks show geochemical evidence of fractionation of biotite, hornblende, magnetite, apatite and feldspars. The Marano volcanic domes crystallised from an I-type magma, formed in a volcanic arc setting. Fe mineralisation has occurred around one of these Marano domes (MA dome) in which the igneous rocks contain more biotite and hornblende and are less fractionated than in the other domes. The main Fe oxide, hematite, occurs as veins and disseminations in sedimentary wall rocks. Alteration of the minerals in the host rocks suggests aS2<10-9.5, aO2>10-34.2 and pH<5.5. The small size and shallow-level of emplacement of magma, together with the absence of extensive hydrothermally altered zones, shows that the hydrothermal system was not voluminous enough to form an economic iron deposit.

  17. Differentiating volcanic rock assemblages using Landsat Thematic Mapper data - Influence of petrochemistry and desert varnish

    NASA Technical Reports Server (NTRS)

    Spatz, D. M.; Taranik, J. V.; Hsu, L. C.

    1989-01-01

    An investigation has been conducted of the composition, distribution, spectral properties, and Landsat TM influences of desert varnish from three sites in southern Nevada. It is established that the TM signatures of diverse volcanic rock assemblages primarily depend on primary petrochemical characteristics. Desert varnish is found to exert a minimal influence on TM imagery at longer wavelengths, but absorbs the higher frequency radiation of TM bands 1-3, thereby leading to high TM band 5/2 values and dark contrast on 5/2 images over units with high rock-varnish albedo difference; highly evolved volcanic deposits show steep positive spectral slopes in the TM band 5-7 region.

  18. Resetting of RbSr ages of volcanic rocks by low-grade burial metamorphism

    USGS Publications Warehouse

    Asmeroma, Y.; Damon, P.; Shafiqullah, M.; Dickinson, W.R.; Zartman, R.E.

    1991-01-01

    We report a nine-point RbSr whole-rock isochron age of 70??3 Ma (MSWD 3.97) for Mid-Jurassic volcanic rocks. The same rocks have also been dated by the UThPb method on zircon, giving a crystallization age of 166 ?? 11 Ma, over twice as old as the RbSr age. The data demonstrate that whole-rock RbSr ages of volcanic rocks, even lava flows with SiO2 content as low as 57 wt.%, are susceptible to complete resetting. The rocks range in composition from rhyodacite tuffs to andesite lavas. The complete breakdown of all major minerals that contain Rb and Sr resulted in an alteration mineral assemblage consisting of phengite, albite, secondary quartz, and minor amounts of chlorite and epidote. Phengite is the K-bearing product of the breakdown of biotite and K-feldspar. Pressure during low-grade metamorphism of the volcanic rocks, estimated from phengite composition to have been in the range of 4 to 6 kbar, points to thrust-related burial as the main cause of resetting. Consequently, such reset isochrons may date large-scale events such as regional thrusting and metamorphism. The coherent resetting of the RbSr isochron suggests large-scale pervasive fluid movement during thrust-related burial metamorphism. ?? 1991.

  19. Relationship between Los Angeles attrition test and Nordic abrasion test of volcanic rocks

    NASA Astrophysics Data System (ADS)

    Krutilová, Kateřina; Prikryl, Richard

    2015-04-01

    Various volcanic rocks contribute significantly to the production of crushed stone in the Czech Republic. When used for road surfacing, results of Los Angeles attrition test (LA value below 25 or 30 depending on the mode of use) together with polished stone value are required. In the recent study, we have focused on the search for possible correlation between results obtained by Los Angeles attrition test and Nordic abrasion test, a test widely employed in Scandinavia. For the experimental study, a set of volcanic rocks from 36 active quarries was used. The rocks under study represent range of volcanic rocks from ultrabasic to acid members, formed form Neoproterozoic to Tertiary. The most favourable results of Los Angeles attrition test (i.e. the lowest LA values) were obtained for basalts (range of values 9.4-19.4) and spilites (range of values 8.4-14.9) which are in fact Neoproterozoic to Late Palaeozoic basalts affected by low grade metamorphism. Nordic abrasion test exhibited much broader range of values (6.4 to 36.9) with average value at 15.2 for basalts, resulting in weak coefficient of determination (0.19). . On contrary, narrow range of values from Nordic abrasion test of spilites (7.2-15.9), very similar to the range of LA values, is reflect in higher coefficient of determination (0.56). On contrary, the least favourable properties (LA values 12.3-29.2, Nordic abrasion 16.8-43.3) have been observed for a group of basic to intermediate rocks classified in older literature as melaphyres and diabases (ranging from basalts to trachyndesites and/or trachybasalts) of Palaeozoic age. However, in this specific group of volcanic rocks, the highest coefficient of determination (0.89) between both tests has been achieved. For volcanic rocks exhibiting acid composition (rhyolites and quartz porphyry), coefficient of determination between LA values (15.1-19.3) and Nordic abrasion test (7.3-21.9) is weak (0.42). The weakest relationship between LA values (14

  20. Middle Triassic volcanic rocks in the Northern Qiangtang (Central Tibet): Geochronology, petrogenesis, and tectonic implications

    NASA Astrophysics Data System (ADS)

    Chen, Sheng-Sheng; Shi, Ren-Deng; Yi, Guo-Ding; Zou, Hai-Bo

    2016-01-01

    Although voluminous magmatism occurred during the Triassic in the Qiangtang terrane, the petrogenesis of the volcanic rocks and the associated tectonic scenarios remain mysterious. This study focuses on new identified primitive volcanic rocks from the Yanshiping area, Northern Qiangtang subterrane. The whole-rock major-trace elemental, Sr-Nd isotopic data, and zircon U-Pb age of volcanic rocks are reported in this paper in order to understand their petrogenesis and tectonic setting. The studied volcanic rocks can be grouped into two types, i.e., Nb-enriched basalts and basaltic andesites (NEBs) in the low sequence and arc basalts in the upper sequence. Zircon U-Pb dating using LA-ICP-MS techniques yields the concordant age with a weighted mean 206Pb/238U age of ca. 242-241 Ma for the NEBs and ca. 240 Ma for the arc basalts. The distinct geochemical and isotopic characteristics of whole-rock and varying Th-U-REE components of zircon grains from the volcanic rocks suggest that the NEBs were derived from partial melting of relatively enriched mantle wedge that have been metasomatised by slab-related melts and that the arc basalts originated from partial melting of mixing of mantle wedge and depleted asthenospheric mantle in response to the slab breakoff. Our new geochemical and geochronological results, in combination with regional studies, imply that the Middle Triassic magmatism was generated in the tectonic setting of northward subduction of the Paleo-Tethys or Bangong-Nujiang Ocean. Subduction-related processes that include melting of the slab and the slab breakoff during the Permian-Middle Triassic made an important contribution to crustal growth in the Qiangtang terrane, whereas vertical crustal growth associated with collision-related setting during the Late Triassic is nonsignificant.

  1. Petrology of potassic alkaline ultramafic and carbonatitic rocks from Planalto da Serra (Mato Grosso State), Brazil

    NASA Astrophysics Data System (ADS)

    Comin-Chiaramonti, Piero; Gomes, Celso B.; De Min, Angelo; Ruberti, Excelso; Girardi, Vicente A. V.; Slejko, Francesca; Neder, Renato D.; Pinho, Francisco E. C.

    2014-12-01

    The Planalto da Serra igneous rocks form plugs, necks and dykes of carbonate-rich ultramafic lamprophyres (aillikites and glimmerites with kamafugitic affinity) and carbonatites (alvikites and beforsites). Phlogopite and/or tetraphlogopite, diopside and melanitic garnet are restricted to aillikitic rock-types, whereas pyroclore occurs only in carbonatites. Aillikites and carbonatites are altered to hydrotermalites, having chlorite and serpentine as dominant minerals. Planalto da Serra igneous rock association has kamafugitic affinity (i.e. effusive, ultrapotassic. High LREE/HREE fractionation, incompatible elements data and Sr-Nd isotopes, suggest that the K-ultramafic alkaline and carbonatite rocks originated from a variably metasomatized mantle source enriched in radiogenic Sr. Crustal contamination is negligible or absent. Age values of 600 Ma rule out the geochronological relationship between the investigated intrusions and the Mesozoic alkaline bodies from the Azimuth 125° lineament. The TDM model ages allow to conclude that Planalto da Serra magma is derived from the partial melting of a mantle source metasomatised by K-rich carbonatated melt during the Early to Late Neoproterozoic. On the basis of alkaline magmatism repetitions at 600 Ma and 90-80 Ma we question the subsistence of a stationary mantle plume for so long time.

  2. Geochemistry of intrusive rocks associated with the Latir volcanic field, New Mexico, and contrasts between evolution of plutonic and volcanic rocks

    USGS Publications Warehouse

    Johnson, C.M.; Czamanske, G.K.; Lipman, P.W.

    1989-01-01

    Plutonic rocks associated with the Latir volcanic field comprise three groups: 1) ???25 Ma high-level resurgent plutons composed of monzogranite and silicic metaluminous and peralkaline granite, 2) 23-25 Ma syenogranite, and alkali-feldspar granite intrusions emplaced along the southern caldera margin, and 3) 19-23 Ma granodiorite and granite plutons emplaced south of the caldera. Major-element compositions of both extrusive and intrusive suites in the Latir field are broadly similar; both suites include high-SiO2 rocks with low Ba and Sr, and high Rb, Nb, Th, and U contents. Moreover, both intermediateto siliciccomposition volcanic and plutonic rocks contain abundant accessory sphene and apatite, rich in rare-earth elements (REE), as well as phases in which REE's are essential components. Strong depletion in Y and REE contents, with increasing SiO2 content, in the plutonic rocks indicate a major role for accessory mineral fractionation that is not observed in volcanic rocks of equivalent composition. Considerations of the rheology of granitic magma suggest that accessory-mineral fractionation may occur primarily by filter-pressing evolved magmas from crystal-rich melts. More limited accessory-mineral crystallization and fractionation during evolution of the volcanic magmas may have resulted from markedly lower diffusivities of essential trace elements than major elements. Accessory-mineral fractionation probably becomes most significant at high crystallinities. The contrast in crystallization environments postulated for the extrusive and intrusive rocks may be common to other magmatic systems; the effects are particularly pronounced in highly evolved rocks of the Latir field. High-SiO2 peralkaline porphyry emplaced during resurgence of the Questa caldera represents non-erupted portions of the magma that produced the Amalia Tuff during caldera-forming eruption. The peralkaline porphyry continues compositional and mineralogical trends found in the tuff. Amphibole

  3. Fluorine in the rocks and sediments of volcanic areas in central Italy: total content, enrichment and leaching processes and a hypothesis on the vulnerability of the related aquifers.

    PubMed

    De Rita, Donatella; Cremisini, Carlo; Cinnirella, Alessandro; Spaziani, Fabio

    2012-09-01

    Rock, sediment and water samples from areas characterised by hydrothermal alterations in the Sabatini and Vico Volcanic Districts, near Rome and the large city of Viterbo, respectively, were collected and analysed to determine the total fluorine (F) content and to understand the F geochemical background level in the volcanic districts of central Italy. Leaching and alteration processes controlling the high concentration of F in water were also investigated. Fluorine concentrations were directly determined (potentiometrically) by an F selective electrode in water samples, while the procedure for rock samples included preliminary F dissolution through alkaline fusion. F concentrations higher than 800 mg kg(-1) were commonly found in the analysed rocks and sediments; the concentration depended on the lithology and on the distance from the alteration areas. A specific successive sampling campaign was conducted in three areas where the F content in sediments was particularly high; in the same areas, measurements of CO(2) flux were also performed to investigate the possible deep origin of F. To verify the relationships among the high F contents in rocks and sediments, the leaching processes involved and the presence of F in the aquifer, we also collected water samples in the western sector of the Sabatini Volcanic District, where hydrothermal manifestations and mineral springs are common. The data were processed using a GIS system in which the F distribution was combined with morphological and geological observations. The main results of our study are that (1) F concentrations are higher in volcanic and recently formed travertine (especially in hydrothermally altered sediments) than in sedimentary rocks and decrease with distance from hydrothermal alteration areas, (2) F is more easily leached from hydrothermally altered rocks and from travertine and (3) sediments enriched with F may indicate the presence of deep regional fractures that represent direct pathways of

  4. Geochemistry and geochronology of late Mesozoic volcanic rocks in the northern part of the Eastern Pontide Orogenic Belt (NE Turkey): Implications for the closure of the Neo-Tethys Ocean

    NASA Astrophysics Data System (ADS)

    Özdamar, Şenel

    2016-04-01

    This paper presents 40Ar/39Ar and U-Pb age data, Sr-Nd isotopes, whole-rock and mineral compositions of Upper Cretaceous volcanic rocks from the Ordu area of the Eastern Pontide Orogenic Belt (EPOB) in northeastern Turkey. The volcanic rocks exhibit a wide compositional range: basalt, basaltic-andesites, andesites and a rhyodacite suite; they are characterized by subparallel light rare earth element (LREE)-enrichment, relatively flat heavy rare earth element (HREE) patterns with Eu anomalies and moderate fractionation [average (La/Yb)N = 8.55]. The geochemical results show that the volcanic rocks have calc-alkaline affinity consistent with arc volcanic rocks erupted in an active continental margin. Initial 87Sr/86Sr values vary between 0.70569 and 0.70606, while initial 143Nd/144Nd values lie between 0.51244 and 0.51249. Crustal contamination affected the mantle-originated primary magma, as indicated by increased 87Sr/86Sr and decreased 143Nd/144Nd ratios with increasing SiO2. New precise laser ablation inductively coupled plasma mass spectrometer (LA-ICP-MS) 206Pb-238U age analyses of zircon and 40Ar/39Ar age data of plagioclase from the volcanics enable a more precise reconstruction of the EBOP. The ages provide insight into the timing of arc formation in this region, constrain the volcanic activity between 86 My (Coniacian) and 75 My (Campanian) and constrain the timing of closure of the Neo-Tethys.

  5. Influence of water saturation on rock failure - Implications for volcanic environments

    NASA Astrophysics Data System (ADS)

    Scheu, B.; Feneis, C.; Lavallee, Y.; Heap, M. J.; Dingwell, D. B.

    2011-12-01

    Water plays several important roles in the grand scheme of volcanism. As magmatic water, it influences magma generation transport and emplacement/eruption via its influence on the physicochemical properties of melts (e.g. rheology, diffusion, surface tension). As external water, it's role is manifold: (1) it is the driving force for the phreatic explosions which often are precursory to volcanic eruptions, (2) it may mix with magma and fuel phreatomagmatic eruptions, and (3) it has the ability to weaken and destabilize volcanic structures. Previous studies have shown that even small amounts of water may substantially weaken the strength of rocks. However the study of volcanic rocks is, in this respect, sparse. For this study we chose both volcanic rocks and volcanic host rocks (ranging from volcaniclastic sandstone to dacite) and compare their behaviour to that of Bentheim sandstone, an iconic rock type in rock mechanics. Two different experimental approaches are combined in this study. Firstly, we investigated the failure of rock specimens by rapid decompression using a shock-tube apparatus. Therein a rock sample is slowly pressurized with argon gas up to a maximum pressure of 50 MPa and then rapidly decompressed to atmospheric conditions. The decompression rates in this facility reach the order of 10 GPa/s and higher, allowing us to interpret these experiments as dynamic direct tensile strength tests. The experiments were carried out with varying degrees of water saturation in a temperature range from 20 to 300 °C. The degree of water saturation influences the fragmentation threshold (the minimum applied pressure required to fully fragment a sample) as well as the speed of the fragmentation process. Secondly, uniaxial compressive strength (UCS) tests and Brazilian tests were carried out to investigate, respectively, the compressive and (indirect) tensile strengths of dry and water-saturated samples. UCS tests were performed on 80 x 40mm cylinders under a strain

  6. Late Jurassic to Eocene geochemical evolution of volcanic rocks in Puerto Rico

    SciTech Connect

    Schellekens, J.H. )

    1991-03-01

    The Late Jurassic to Eocene deformed volcanic, volcaniclastic and sedimentary rocks of Puerto Rico are divided into three igneous provinces, the southwestern, central, and northeastern igneous province. Based on the stratigraphic position approximate ages could be assigned to the flow rocks in these provinces. Ba/Nb and La/Sm diagrams are presented to illustrate the origin and evolution of the flow rocks. The oldest rock in the southwestern province may include MORB. Early Cretaceous volcanic rocks in the central and northeastern province have low Ba/nb and La/Sm, that are interpreted as an early island arc stage, with none or only minor contribution of slab-derived material. The Late Cretaceous to Eocene volcanic rocks have a wide range of values for the Ba/Nb and La/Sm that are interpreted as the result of admixture of a variable amount of slab-derived material. The Maricao Basalt (Maastrichtian to Eocene) in the southeastern igneous province has the geochemical signature of magmas formed in an extensional setting.

  7. Relative Roles of Source Composition, Fractional Crystallization and Crustal Contamination in the Petrogenesis of Andean Volcanic Rocks

    NASA Astrophysics Data System (ADS)

    Thorpe, R. S.; Francis, P. W.; O'Callaghan, L.

    1984-04-01

    There are well established differences in the chemical and isotopic characteristics of the calc-alkaline basalt--andesite--decite--rhyolite association of the northern (n.v.z.), central (c.v.z.) and southern volcanic zones (s.v.z.) of the South American Andes. Volcanic rocks of the alkaline basalt--trachyte association occur within and to the east of these active volcanic zones. The chemical and isotopic characteristics of the n.v.z. basaltic andesites and andesites and the s.v.z. basalts, basaltic andesites and andesites are consistent with derivation by fractional crystallization of basaltic parent magmas formed by partial melting of the asthenospheric mantle wedge containing components from subducted oceanic lithosphere. Conversely, the alkaline lavas are derived from basaltic parent magmas formed from mantle of `within-plate' character. Recent basaltic andesites from the Cerro Galan volcanic centre to the SE of the c.v.z. are derived from mantle containing both subduction zone and within-plate components, and have experienced assimilation and fractional crystallization (a.f.c.) during uprise through the continental crust. The c.v.z. basaltic andesites are derived from mantle containing subduction-zone components, probably accompanied by a.f.c. within the continental crust. Some c.v.z. lavas and pyroclastic rocks show petrological and geochemical evidence for magma mixing. The petrogenesis of the c.v.z. lavas is therefore a complex process in which magmas derived from heterogeneous mantle experience assimilation, fractional crystallization, and magma mixing during uprise through the continental crust. Active Andean volcanoes of the calc-alkaline basalt--andesite--dacite rhyolite association occur within a northern (n.v.z.), central (c.v.z.) and southern volcanic zone (s.v.z.) (figure 9). Alkaline volcanic rocks occur within and to the east of these zones. The n.v.z. and s.v.z. lavas have chemical and isotope characteristics consistent with an origin by

  8. Geochemistry and petrology of the Early Miocene lamproites and related volcanic rocks in the Thrace Basin, NW Anatolia

    NASA Astrophysics Data System (ADS)

    Ersoy, Yalçın E.; Palmer, Martin R.; Uysal, İbrahim; Gündoğan, İbrahim

    2014-08-01

    The extensional Thrace basin (NW Anatolia) contains an association of early Miocene diopside-leucite-phlogopite (Doğanca) and diopside-phlogopite (Korucuköy) lamproites with Oligocene medium-K calc-alkaline andesites (Keşan volcanics), early Miocene shoshonitic rocks (Altınyazı trachyte) and middle Miocene Na-alkaline basalts (Beğendik basalts). The Doğanca lamproite (K2O = 5.1-5.5 wt.%; K/Na = 2.78-2.89; MgO = 11.4-11.8 wt.%) consists of olivine (Fo71-86), diopside (Al2O3 = 1.0-5.0, Na2O = 0.2-0.6), phlogopite (TiO2 = 1.1-9.4, Al2O3 = 11.1-13.9), spinel (Mg# = 22.9-32.6; Cr# = 64-83.4), leucite, apatite, zircon, Fe-Ti-oxides and magnetite in a poikilitic sanidine matrix. The potassic volcanic units (lamproites and trachytes) in the region have similarly high Sr and low Nd isotopic compositions (87Sr/86Sr(i) = 0.70835-0.70873 and 143Nd/144Nd(i) = 0.51227-0.51232). The major and trace element compositions and Sr-Nd-Pb isotopic ratios of the shoshonitic, ultrapotassic and lamproitic units closely resemble those of other Mediterranean ultrapotassic lamproites (i.e., orogenic lamproites) from Italia, Serbia, Macedonia and western Anatolia. The Beğendik basalts show intraplate geochemical signatures with an Na-alkaline composition, an absence of Nb negative anomalies on primitive mantle-normalized multi-element diagrams, as well as low Sr (~ 0.70416) and high Nd (0.51293) isotopic ratios; and include olivine (Fo72-84), diopside, spinel, Fe-Ti-oxides and magnetite. The Oligocene Keşan volcanics were emplaced in the earlier stages of extension in Thrace, and represent the typical volcanic products of post-collisional volcanism. The continental crust-like trace element abundances and isotopic compositions of the most primitive early Miocene ultrapotassic rocks (Mg# up to 74) indicate that their mantle sources were intensely contaminated by the continental material. By considering the geodynamic evolution of the region, including oceanic subduction, crustal

  9. Location, age, and rock type of volcanic rocks younger than 5 million years in Arizona and New Mexico

    SciTech Connect

    Aldrich, M.J. Jr.; Laughlin, A.W.

    1981-04-01

    As part of the assessment of the Hot Dry Rock geothermal energy potential of Arizona and New Mexico, a compilation of the locations and ages of volcanic rocks less than 5 Myr was made. The locations of those rocks less than 3 Myr are shown on a map of the region. Because the compiled information has many uses in addition to geothermal exploration, the entire compilation is presented as a tabulation. The table is organized first by state and secondly by latitude and longitude within each state. Rock type, age and error, method of dating, and original reference are also given. The K-Ar dates have not been recalculated using the most recent decay constants for /sup 40/K. A few references gave only verbal descriptions of sample location; these locations were converted to approximate latitude and longitude.

  10. Primary alkaline magmas associated with the Quaternary Alligator Lake volcanic complex, Yukon Territory, Canada

    NASA Astrophysics Data System (ADS)

    Eiché, G. E.; Francis, D. M.; Ludden, J. N.

    1987-02-01

    The Alligator Lake complex is a Quaternary alkaline volcanic center located in the southern Yukon Territory of Canada. It comprises two cinder cones which cap a shield consisting of five distinct lava units of basaltic composition. Units 2 and 3 of this shield are primitive olivine-phyric lavas (13.5 19.5 cation % Mg) which host abundant spinel lherzolite xenoliths, megacrysts, and granitoid fragments. Although the two lava types have erupted coevally from adjacent vents and are petrographically similar, they are chemically distinct. Unit 2 lavas have considerably higher abundances of LREE, LILE, and Fe, but lower HREE, Y, Ca, Si, and Al relative to unit 3 lavas. The 87Sr/86Sr and 143Nd/144Nd isotopic ratios of these two units are, however, indistinguishable. The differences between these two lava types cannot be explained in terms of low pressure olivine fractionation, and the low concentrations of Sr, Nb, P, and Ti in the granitoid xenoliths relative to the primitive lavas discounts differential crustal contamination. The abundance of spinel lherzolite xenoliths and the high Mg contents in the lavas of both units indicates that their compositional differences originated in the upper mantle. The Al and Si systematics of these lavas suggests that, compared to unit 3 magmas, the unit 2 magmas may have segregated at greater depths from a garnet lherzolite mantle. The identical isotopic composition and similar ratios of highly incompatible elements in these two lava units argues against their differences being a consequence of random metasomatism or mantle heterogeneity. The lower Y and HREE contents but higher concentrations of incompatible elements in the unit 2 lavas relative to unit 3 can be most simply explained by differential partial melting of similar garnet-bearing sources. The unit 2 magmas thus appear to have been generated by smaller degrees of melting at a greater depth than the unit 3 magmas. The contemporaneous eruption of two distinct but

  11. Clastic sedimentary rocks of the Michipicoten Volcanic-sedimentary belt, Wawa, Ontario

    NASA Technical Reports Server (NTRS)

    Ojakangas, R. W.

    1983-01-01

    The Wawa area, part of the Michipicoten greenstone belt, contains rock assemblages representative of volcanic sedimentary accumulations elsewhere on the shield. Three mafic to felsic metavolcanic sequences and cogenetic granitic rocks range in age from 2749 + or - 2Ma to 2696 + or - 2Ma. Metasedimentary rocks occur between the metavolcanic sequences. The total thickness of the supracrustal rocks may be 10,000 m. Most rocks have been metamorphosed under greenschist conditions. The belt has been studied earlier and is currently being remapped by Sage. The sedimentrologic work has been briefly summarized; two mainfacies associations of clastic sedimentary rocks are present - a Resedimented (Turbidite) Facies Association and a Nonmarine (Alluvial Fan Fluvial) Facies Association.

  12. Search for magnetic monopoles in polar volcanic rocks.

    PubMed

    Bendtz, K; Milstead, D; Hächler, H-P; Hirt, A M; Mermod, P; Michael, P; Sloan, T; Tegner, C; Thorarinsson, S B

    2013-03-22

    For a broad range of values of magnetic monopole mass and charge, the abundance of monopoles trapped inside Earth would be expected to be enhanced in the mantle beneath the geomagnetic poles. A search for magnetic monopoles was conducted using the signature of an induced persistent current following the passage of igneous rock samples through a SQUID-based magnetometer. A total of 24.6 kg of rocks from various selected sites, among which 23.4 kg are mantle-derived rocks from the Arctic and Antarctic areas, was analyzed. No monopoles were found, and a 90% confidence level upper limit of 9.8 × 10(-5)/g is set on the monopole density in the search samples. PMID:25166793

  13. Nature and origin of secondary mineral coatings on volcanic rocks of the Black Mountain, Stonewall Mountain, and Kane Springs Wash volcanic centers, southern, Nevada

    NASA Technical Reports Server (NTRS)

    Taranik, James V.; Hsu, Liang C.; Spatz, David M.; Chenevey, Michael J.

    1989-01-01

    The following subject areas are covered: (1) genetic, spectral, and LANDSAT Thematic Mapper imagery relationship between desert varnish and tertiary volcanic host rocks, southern Nevada; (2) reconnaissance geologic mapping of the Kane Springs Wash Volcanic Center, Lincoln County, Nevada, using multispectral thermal infrared imagery; (3) interregional comparisons of desert varnish; and (4) airborne scanner (GERIS) imagery of the Kane Springs Wash Volcanic Center, Lincoln County, Nevada.

  14. Bimodal Silurian and Lower Devonian volcanic rock assemblages in the Machias-Eastport area, Maine

    USGS Publications Warehouse

    Gates, Olcott; Moench, R.H.

    1981-01-01

    Exposed in the Machias-Eastport area of southeastern Maine is the thickest (at least 8,000 m), best exposed, best dated, and most nearly complete succession of Silurian and Lower Devonian volcanic strata in the coastal volcanic belt, remnants of which crop out along the coasts of southern New Brunswick, Canada, and southeastern New England in the United States. The volcanics were erupted through the 600-700-million-year-old Avalonian sialic basement. To test the possibility that this volcanic belt was a magmatic arc above a subduction zone prior to presumed Acadian continental collision, samples representing the entire section in the Machias-Eastport area of Maine were chemically analyzed. Three strongly bimodal assemblages of volcanic rocks and associated intrusives are recognized, herein called the Silurian, older Devonian, and younger Devonian assemblages. The Silurian assemblage contains typically nonporphyritic high-alumina tholeiitic basalts, basaltic andesites, and diabase of continental characterand calc-alkalic rhyolites, silicic dacites, and one known dike of andesite. These rocks are associated with fossiliferous, predominantly marine strata of the Quoddy, Dennys, and Edmunds Formations, and the Leighton Formation of the Pembroke Group (the stratigraphic rank of both is revised herein for the Machias-Eastport area), all of Silurian age. The shallow marine Hersey Formation (stratigraphic rank also revised herein) of the Pembroke Group, of latest Silurian age (and possibly earliest Devonian, as suggested by an ostracode fauna), contains no known volcanics; and it evidently was deposited during a volcanic hiatus that immediately preceded emergence of the coastal volcanic belt and the eruption of the older Devonian assemblage. The older Devonian assemblage, in the lagoonal to subaerial Lower Devonian Eastport Formation, contains tholeiitic basalts and basaltic andesites, typically with abundant plagioclase phenocrysts and typically richer in iron and

  15. Isotopic composition of strontium in volcanic rocks from oahu.

    PubMed

    Powell, J L; Delong, S E

    1966-09-01

    Analysis of several well-documented specimens from each of the three volcanic series on Oahu gives the following mean ratios of Sr(87) to Sr(86): the Waianae series, 0.7030 +/- 0.00010 (sigma); the Koolau series, 0.70385+/- 0.00009 (sigma); and the Honolulu series, 0.7029 ++/- 0.00006 ( sigma). The mean ratio of Sr(87) to Sr(86) of the Koolau series specimens is significantly higher than the means of the other two series. With one exception, significant differences in Sr(87)/ Sr(86) within a series were not found, even though some large compositional differences existed. PMID:17754246

  16. Petrology and Geochemistry of Basic Volcanic Rocks from Saveh Region, NW Iran

    NASA Astrophysics Data System (ADS)

    Ghorbani, M.

    2002-05-01

    As part of northwestern Iran volcanic belt, Saveh region, some 130 km southwest of Tehran, is dominated by Eocene volcanic rocks. Geochemical studies on the volcanic rocks from different parts of the region have produced around 256 whole rock analyses during the last 30 years. The rocks were mainly analysed for major elements at the laboratories of the Geological Survey of Iran and Grenoble University of France using wet chemistry, XRF, and mass spectrometry techniques. Geochemical variations of the Saveh basic-intermediate volcanic rocks with 45 to 60 wt.% SiO2 content (89 samples-on an anhydrous basis) bear significant petrological implications. Here, these rocks are referred to as "basic volcanic rocks". On oxides vs. silica diagrams, data points representing the basic volcanic rocks appear as two distinct series. One is richer in Al and Ca, but poorer in Si, Na, Fe, Ti, Mn, and P than the other; these two are called Al-rich and Al-poor series respectively. Containing higher than 18 wt.% Al2O3, the Al-rich series is represented by the data contributed by Caillat et al. (1978) and Khan Nazer (1980). Al-poor series that contains less than 18 wt.% Al2O3, is best represented by the data obtained by Mehdizadeh Tehrani (1991) and Moaf Pourian (1996). It is likely that the Al-poor series has undergone a major low pressure plagioclase ñ olivine fractionation, as compared to the Al-rich series which has been affected by a lesser degree of low pressure differentiation if at all. The two series, also show different spatial disrtibution. The Al-rich series corresponds with the samples collected from the western part of the Saveh region, while the Al-poor series is found in the other parts of Saveh region. It looks that the magma supply to the western part of the region has been faciliated by deep-seated plumbing system, while in other parts of the Saveh region, development of low-level magma chambers caused accumulation of magmas in the crust, where they have undergone low

  17. Is there a geochemical link between volcanic and plutonic rocks in the Organ Mountains caldera?

    NASA Astrophysics Data System (ADS)

    Memeti, V.; Davidson, J.

    2013-12-01

    Results from separate volcanic and plutonic studies have led to inconsistent conclusions regarding the origins and thus links between volcanic and plutonic systems in continental arcs and the magmatic processes and time scales responsible for their compositional variations. Some have suggested that there is a geochemical and geochronological disconnect between volcanic and plutonic rocks and hence have questioned the existence of magma mush columns beneath active volcanoes. Investigating contemporary volcanic and plutonic rocks that are spatially connected is thus critical in exploring these issues. The ca. 36 Ma Organ Mountains caldera in New Mexico, USA, represents such a system exposing contemporaneous volcanic and plutonic rocks juxtaposed at the surface due to tilting during extensional tectonics along the Rio Grande Rift. Detailed geologic and structural mapping [1] and 40Ar/39Ar ages of both volcanics and plutons [2] demonstrate the spatial and temporal connection of both rock types with active magmatism over >2.5 myr. Three caldera-forming ignimbrites erupted within 600 kyr [2] from this system with a total erupted volume of 500-1,000 km3 as well as less voluminous pre- and post-caldera trachyte and andesite lavas. The ignimbrite sequence ranges from a crystal-poor, high-SiO2 rhyolite at the base to a more crystal-rich, low-SiO2 rhyolite at the top. Compositional zoning with quartz-monzonite at the base grading to syenite and alaskite at the top is also found in the Organ Needle pluton, the main intrusion, which is interpreted to be the source for the ignimbrites [1]. Other contemporaneous and slightly younger plutons have dioritic to leucogranitic compositions. We examined both volcanic and plutonic rocks with petrography and their textural variations with color cathodoluminescence, and used whole rock element and Sr, Nd and Pb isotope geochemistry to constrain magma compositions and origins. Electron microprobe analyses on feldspars have been completed to

  18. The determination of the acoustic parameters of volcanic rocks from compressional velocity measurements

    USGS Publications Warehouse

    Carroll, R.D.

    1969-01-01

    A statistical analysis was made of the relationship of various acoustic parameters of volcanic rocks to compressional wave velocities for data obtained in a volcanic region in Nevada. Some additional samples, chiefly granitic rocks, were also included in the study to extend the range of parameters and the variety of siliceous rock types sampled. Laboratory acoustic measurements obtained on 62 dry core samples were grouped with similar measurements obtained from geophysical logging devices at several depth intervals in a hole from which 15 of the core samples had been obtained. The effects of lithostatic and hydrostatic load on changing the rock acoustic parameters measured in the hole were noticeable when compared with the laboratory measurements on the same core. The results of the analyses determined by grouping all of the data, however, indicate that dynamic Young's, shear and bulk modulus, shear velocity, shear and compressional characteristic impedance, as well as amplitude and energy reflection coefficients may be reliably estimated on the basis of the compressional wave velocities of the rocks investigated. Less precise estimates can be made of density based on the rock compressional velocity. The possible extension of these relationships to include many siliceous rocks is suggested. ?? 1969.

  19. High to ultrahigh potassic alkaline volcanic belt along the Ankara-Erzincan suture (northern Turkey): new geochemical and Ar-Ar data constraining petrogenesis with implications for the late Cretaceous subduction of the Neotethys Ocean

    NASA Astrophysics Data System (ADS)

    Genc, S. Can; Gulmez, Fatma; Tuysuz, Okan; Karacik, Zekiye; Roden, Michael F.; Zeki Billor, M.; Hames, Willis E.

    2013-04-01

    Remnants of some high- to ultrahigh-K alkaline volcanic rocks crop out as isolated small and discontinuous bodies along the Ankara-Erzincan suture belt in northern Turkey. These rocks are represented by leucite-bearing lavas (LB), basaltic andesites, trachytes, monzonite/syenites) and lamprophyres. Leucite-bearing rocks are small stocks, dikes and lava flows. Pebbles and blocks of the LB are found in the coeval volcanic debris avalanche deposits and volcanoclastic breccias. Leucite-bearing rocks are mainly phonotephrite, tephriphonolite, trachyandesite and basaltic trachyandesites (shoshonite) and have mineral assemblages of lct + cpx + ol + pl + Kfs + mag+ ap. Leucites were almost totally analcimized. Trachytes and monzonite/syenites, which are seen as small stocks and dikes, are characterized by amp + bt + pl + Kfs + spn + ap + opq paragenesis. Lamprophyres are mica-rich melanocratic dikes, and include cpx + mica (phlogopitic) + Kfs + ap + opq. Rarely leucite, olivine and plagioclase are also present. Ar-Ar data reveal that this volcanic activity occurred between 73.6±0.18 and 76.78±0.19 Ma, corresponding to latest Cretaceous. All the samples from the high- and ultrahigh-K volcanic belt are alkaline in nature. Leucite-bearing lavas are characterized by their MgO (2.70-5.81, av. 4.58 wt.%), K2O (0.79-4.81, av. 2.35 wt.%), Na2O (4.86-7.48, av. 3.58 wt.%) and K2O/Na2O (0.13-0.92, av. 0.42 wt.%). The low K2O and K2O/Na2O contents of these rocks are due to extensive analcimization of the leucites. Major oxide contents in lamprophyric rocks are 3.25-7.48 (MgO), 1.35-7.76 (K2O), 1.77-4.00 (Na2O) and 0.31-2.69 (K2O/Na2O). The silica content of these rocks are variable and range from 47.18-50.26 (wt.%) (LB) to 39.14-53.28 (lamprophyres). Based on their major element contents, these rocks are classified as plagioleucitites or ultrapotassic rocks of the active orogenic zones (Foley, 1992). Leucite-bearing rocks, lamprophyres and the trachytes (with their hypabyssal

  20. Conditions of accumulation of radioactive metals in the process of differentiation of ultrabasic alkaline-carbonatite rock associations

    NASA Astrophysics Data System (ADS)

    Kogarko, L. N.

    2014-07-01

    The distribution of radioactive elements in alkaline rocks from Polar Siberia and Ukraine shows that U and Th are markedly concentrated in carbonatite complex and nepheline syenite as final products of magma fractionation. Peralkaline nepheline syenites from Polar Siberia are characterized by very high contents of radioactive elements, which are close to the economic level. Radioactive elements are also concentrated in rocks of the carbonatite complex. For example, some soevites contain up to 294 × 10-4%U and 916 × 10-4% Th. In late dolomite carbonatites, the contents of radioactive elements are appreciably lower. The Th/U ratio in alkaline rocks of Polar Siberia is close to the chondrite value in primary high-Mg rocks and increases in late derivatives: phoscorite, calcite and dolomite carbonatites. The main amount of radioactive elements is contained in rare-metal accessory minerals: perovskite, pyrochlore, calzirtite, and apatite. Rock-forming minerals are distinguished by very low concentrations of radioactive elements. In alkaline series of the Chernigovka massif (Ukraine), U and Th also accumulate in the course of crystal fractionation, especially in phoscorites from the carbonatite complex. Mantle xenoliths and alkaline rocks from Ukraine reveal uranium specialization. Most likely, the discrepancy in fractionation of radioactive elements between Polar Siberia and Ukraine is caused by different geodynamic regimes of these provinces. The Mesozoic alkaline magmatism of Polar Siberia is a part of the Siberian superplume, whereas the Proterozoic alkaline complex in Ukraine is related to subduction of the oceanic crust.

  1. Petrogenesis and tectonic implication of the Late Triassic post-collisional volcanic rocks in Chiang Khong, NW Thailand

    NASA Astrophysics Data System (ADS)

    Qian, Xin; Wang, Yuejun; Feng, Qinglai; Zi, Jian-Wei; Zhang, Yuzhi; Chonglakmani, Chongpan

    2016-04-01

    The volcanic rocks exposed within the Chiang Khong-Lampang-Tak igneous zone in NW Thailand provide important constraints on the tectonic evolution of the eastern Paleotethys ocean. An andesite sample from the Chiang Khong area yields a zircon U-Pb age of 229 ± 4 Ma, significantly younger than the continental-arc and syn-collisional volcanic rocks (ca. 238-241 Ma). The Chiang Khong volcanic rocks are characterized by low MgO (1.71-6.72 wt.%) and high Al2O3 (15.03-17.76 wt.%). They are enriched in LILEs and LREEs and depleted in HFSEs, and have 87Sr/86Sr (i) ratios of 0.7050-0.7065, εNd (t) of - 0.32 to - 1.92, zircon εHf (t) and δ18O values of 3.5 to - 11.7 and 4.30-9.80 ‰, respectively. The geochemical data for the volcanic rocks are consistent with an origin from the enriched lithospheric mantle that had been modified by slab-derived fluid and recycled sediments. Based on available geochronological and geochemical evidences, we propose that the Late Triassic Chiang Khong volcanic rocks are equivalent to the contemporaneous volcanic rocks in the Lancangjiang igneous zone in SW China. The formation of these volcanic rocks was possibly related to the upwelling of the asthenospheric mantle during the Late Triassic, shortly after slab detachment, which induced the melting of the metasomatized mantle wedge.

  2. Geochemistry and geochronology of Hangay Dome volcanic rocks: exploring the source of high topography and volcanism in an intracontinental setting

    NASA Astrophysics Data System (ADS)

    Ancuta, L. D.; Carlson, R. W.; Idleman, B. D.; Zeitler, P. K.

    2013-12-01

    The Hangay dome in central Mongolia is an anomalous uplifted continental interior that is partially covered by diffuse Cenozoic basaltic rocks. Here we present new data on the geochemistry, stratigraphy, geomorphology and 40Ar/39Ar ages of the basaltic rocks to help elucidate the cause of the uplift and 33 Ma of volcanism in the region. 187Os/188Os ratios for the basaltic rocks range from 0.1363-0.3440. The higher values implicate crustal contamination, but the less radiogenic values limit the amount of contamination to the point where the Sr, Nd and Hf isotopic composition of the lavas are little affected, allowing them to be used as reliable tracers of the initial melt source. 87Sr/86Sr and 143Nd/144Nd ratios for the basaltic rocks from the region range from 0.7039-0.7050 and 0.5120-0.5127 respectively. These values are higher and lower, respectively, than Sr and Nd isotopic composition of the majority of spinel peridotite xenoliths contained in recent Hangay lavas, implicating a sub-lithospheric source for the magmas. The basalts have isotopic compositions approaching the EM-1 enriched mantle end member, similar to a number of other sites of young east Asian magmatism. An EM-1 type mantle source may have been generated regionally across East Asia by incorporation of pelagic sediments into the upper mantle during the protracted history of terrane accretion and subduction associated with the formation of the Central Asian orogenic system. New stratigraphically correlated 40Ar/39Ar ages for basalts from the Hangay region show that multiple episodes of laterally extensive flows occurred between 28.30×0.19 and 4.11×0.11 Ma. This first phase of volcanism was the most voluminous and long-lived. A later stage of valley-filling eruptions occurred between 3.28×0.50 Ma and 5 Ka. Flows across this range of ages occur in a number of locations within the Hangay, with no discernable age progression, indicating that the region has been the site of volcanism for over 30 Ma

  3. New high-precision 40Ar/39Ar ages on Oligocene volcanic rocks of northwestern Kenya

    NASA Astrophysics Data System (ADS)

    Brown, Francis H.; Jicha, Brian R.

    2016-02-01

    New, high-precision 40Ar/39Ar ages from volcanic rocks in northwestern Kenya are provided for some areas of exposure in this remote area. We report seven 40Ar/39Ar ages generated from single crystal total fusion experiments on alkali feldspar separated from volcanic rocks in the Mogila, Songot, and Lokwanamur Ranges and the Gatome valley. A rhyolite from the lower part of the sequence in the Mogila Range yielded ages of 32.31 ± 0.06 Ma and 32.33 ± 0.07 Ma, and a rhyolite near the top of that sequence yielded 31.67 ± 0.04 Ma. A single sample from the Songot Range yielded an age of 32.49 ± 0.07 Ma, slightly older than the rocks collected from Mogila. In both ranges the early Oligocene rhyolites are underlain by basalts, as is also the case in the Labur Range. Ages of 25.95 ± 0.03 Ma, 25.91 ± 0.04 Ma, and 27.15 ± 0.03 Ma were measured on alkali feldspar from rhyolites from the Lokwanamur Range, and the nearby Gatome valley. All of these rocks are part of an episode of widespread volcanism in northwestern Kenya in the mid-to late Oligocene that is not currently known from the Ethiopian Rift Valley.

  4. Saturated Zone Plumes in Volcanic Rock: Implications for Yucca Mountain

    SciTech Connect

    S. Kelkar; R. Roback; B. Robinson; G. Srinivasan; C. Jones; P. Reimus

    2006-02-14

    This paper presents a literature survey of the occurrences of radionuclide plumes in saturated, fractured rocks. Three sites, Idaho National laboratory, Hanford, and Oak Ridge are discussed in detail. Results of a modeling study are also presented showing that the length to width ratio of a plume starting within the repository footprint at the Yucca Mountain Project site, decreases from about 20:1 for the base case to about 4:1 for a higher value of transverse dispersivity, indicating enhanced lateral spreading of the plume. Due to the definition of regulatory requirements, this lateral spreading does not directly impact breakthrough curves at the 18 km compliance boundary, however it increases the potential that a plume will encounter reducing conditions, thus significantly retarding the transport of sorbing radionuclides.

  5. Magma-derived gas influx and water-rock interactions in the volcanic aquifer of Mt. Vesuvius, Italy

    NASA Astrophysics Data System (ADS)

    Federico, C.; Aiuppa, A.; Allard, P.; Bellomo, S.; Jean-Baptiste, P.; Parello, F.; Valenza, M.

    2002-03-01

    We report in this paper a systematic investigation of the chemical and isotopic composition of groundwaters flowing in the volcanic aquifer of Mt. Vesuvius during its current phase of dormancy, including the first data on dissolved helium isotope composition and tritium content. The relevant results on dissolved He and C presented in this paper reveal that an extensive interaction between rising magmatic volatiles and groundwaters currently takes place at Vesuvius. Vesuvius groundwaters are dilute (mean TDS ˜ 2800 mg/L) hypothermal fluids ( mean T = 17.7°C) with a prevalent alkaline-bicarbonate composition. Calcium-bicarbonate groundwaters normally occur on the surrounding Campanian Plain, likely recharged from the Apennines. δD and δ 18O data evidence an essentially meteoric origin of Vesuvius groundwaters, the contribution from either Tyrrhenian seawater or 18O-enriched thermal water appearing to be small or negligible. However, the dissolution of CO 2-rich gases at depth promotes acid alteration and isochemical leaching of the permeable volcanic rocks, which explains the generally low pH and high total carbon content of waters. Attainment of chemical equilibrium between the rock and the weathering solutions is prevented by commonly low temperature (10 to 28°C) and acid-reducing conditions. The chemical and isotope (C and He) composition of dissolved gases highlights the magmatic origin of the gas phase feeding the aquifer. We show that although the pristine magmatic composition may vary upon gas ascent because of either dilution by a soil-atmospheric component or fractionation processes during interaction with the aquifer, both 13C/ 12C and 3He/ 4He measurements indicate the contribution of a magmatic component with a δ 13C ˜ 0‰ and R/R a of ˜2.7, which is consistent with data from Vesuvius fumaroles and phenocryst melt inclusions in olivine phenocrysts. A main control of tectonics on gas ascent is revealed by data presented in this paper. For example

  6. K-Ar dating of young volcanic rocks

    SciTech Connect

    Damon, P.E.; Shafiqullah, M.

    1991-01-31

    Potassium-Argon (K-Ar) age dates were determined for forty-two young geologic samples by the Laboratory of Isotope Geochemistry, Department of Geosciences, in the period February 1, 1986 to June 30, 1989. Under the terms of Department of Energy Grant No. FG07-86ID12622, The University of Arizona was to provide state-of-the-art K-Ar age dating services, including sample preparation, analytical procedures, and computations, for forty-two young geologic samples submitted by DOE geothermal researchers. We billed only for forty samples. Age dates were determined for geologic samples from five regions with geothermal potential: the Cascade Mountains (Oregon); the Cascade Mountains (Washington); Ascension Island, South Atlantic Ocean; Cerro Prieto, Mexico; and Las Azufres, Mexico. The ages determined varied from 5.92 m.a. to 0.62 m.a. The integration of K-Ar dates with geologic data and the interpretation in terms of geologic and geothermal significance has been reported separately by the various DOE geothermal researchers. Table 1 presents a detailed listing of all samples dated, general sample location, researcher, researcher's organization, rock type, age, and probable error (1 standard deviation). Additional details regarding the geologic samples may be obtained from the respective geothermal researcher. 1 tab.

  7. Spectra of volcanic rocks glasses as analogues of Mercury surface spectra

    NASA Astrophysics Data System (ADS)

    Carli, C.; Capaccioni, F.; de Sanctis, M.; Filacchione, G.; Sgavetti, M.; di Genova, D.; Vona, A.; Visonà, D.; Ammannito, E.

    2010-12-01

    Remote-sensing studies have revealed that most of the inner planets surfaces are composed by magmatic effusive rocks as lava flows or pyroclastic deposits, that are the natural products of magma-rock dynamic systems controlled by T, P, oxygen fugacity and time. These materials generally contain a fair amount of volcanic glass, due to the magma rapid cooling once effused on the surface. The VNIR reflectance spectroscopy is one of the most relevant tools for remote-sensing studies and in the last decades gave important results identifying the presence of different Fe-Mg silicates, such as olivine and pyroxenes, on the planets surfaces. However, the mineralogical interpretation of the observed spectral features of several volcanic areas on the inner Solar System bodies is still matter of debate. In particular the presence of dark volcanic glass, which can dominate or not the rock texture, influences the spectra signatures. In fact samples with a glass-bearing groundmass have lower albedo and reduced band intensity of the spectra of samples with comparable mineral composition and intergranular texture. As a consequence, an important goal for studying the planetary crusts is to understand the spectral behavior of volcanic material, where chemical or physical parameters are different depending on geologic context and effusive processes. We present here preliminary laboratory activity to investigate VNIR reflectance spectra of several volcanic glasses. Reflectance spectra, in the wavelength range between 0.35- 2.50 μm, are measured on powders of magmatic rocks, having different composition and textures, at fine (<60 μm in diameter) and very fine (<10 μm) grain sizes. For each rock sample a corresponding “thermal shocked-sample” is produced by heating at 1300°C and P=1 atm and a glass-sample was produced by melting at 1500°C and P=1 atm, than quenching it in air. Reflectance spectra of powders of shocked and glass-samples were acquired at the same grain size, and

  8. Geochemical and isotopic (Nd-Pb-Sr-O) variations bearing on the genesis of volcanic rocks from Vesuvius, Italy

    USGS Publications Warehouse

    Ayuso, R.A.; de Vivo, B.; Rolandi, G.; Seal, R.R., II; Paone, A.

    1998-01-01

    Alkaline volcanism produced by Monte Somma-Vesuvius volcano includes explosive plinian and subplinian activity in addition to effusive lava flows. Pumice, scoria, and lava (150 samples) exhibit major- and trace-element gradients as a function of SiO2 (58.9-47.2 wt%) and MgO (0-7.8 wt%); Mg value are ???50. Internally gradational chemical groups or cycles are distinguished by age: (1) 25 000 to 14 000 yr B.P.; (2) 8000 yr B.P. to A.D. 79; and (3) A.D. 79 to 1944. A small number of lavas, dikes and scora were also analysed from the Somma formation (~ 35 000 to 25 000 yr B.P.). Within each group, contents of Na2O + K2O increas with decreasing MgO along distinct rocks. Nb/Y values are variable from 0.66 to 3.14 (at SiO2 ??? 50 wt%) generally in the range of alkaline and ultra-alkaline rocks. Variations in contents of some majro elements (e.g., P and Ti), and trace elements (e.g., Th, Nb, Ta, Zr, Hf, Pb, La, and Sc), as well as contrasting trends in ratios of various elements (e.g., Ta/Yb, Hf/U, Th/Ta, Th/Hf, Th/Yb, etc.) are also generally consistent with the group subdivisions. For example, Th/Hf increases from ??? 5 to ??? 10 with decreasing age for the Vesuvius system as a whole, yielding similar compositions in the least evolved rocks (low-silica, high-MgO, imcompatible element-poor) erupted at the end of each cycle. Internal variations within individual eruptions also systematically changed generally towards a common mafic composition at the end of each cycle, thus reflecting the dominanit volume in the magma chamber. At the start of a new eruptive cycle, the rocks are relatively enriched in incompatible elements; younger groups also contain higher abundances than other groups. N-MORB-normalized multielement diagrams exhibit selective enrichments of Sr, K, Rb, Th, and the light rare-earth elements; deep Nb and Ta negative anomalies commonly seen in rocks generated at orogenic margins are absent in the light rare-earth elements; deep Nb and Ta netgative anomalies

  9. A Holocene paleosecular variation from 14C-dated volcanic rocks in Western North America

    USGS Publications Warehouse

    Hagstrum, J.T.; Champion, D.E.

    2002-01-01

    A paleosecular variation (PSV) curve for western North America is presented on the basis of 94 virtual geomagnetic poles (VGPs) from dated volcanic rocks sampled at 446 sites. Approximately 60% of the paleomagnetic database has been previously published. A curve defined by "spherical smoothed splines" is fitted to the VGPs, ranked by the quality of the age determinations, where the data density is highest between 3690 and -30 years before present (B.P.) (A.D. 1950), between 7800 and 7050 years B.P., and between 14,060 and 12,700 years B.P. The younger segments of the curve derived from volcanic rocks are similar but less complex than other high-resolution PSV curves derived from lacustrine sediments, particularly the record at Fish Lake, Oregon. The PSV record from lava flows (PSVL), however, is perhaps more reliable in its general shape and chronology because of the higher fidelity of volcanic rocks as magnetic field recorders and because of the greater density of 14C dates. The new PSVL record provides a partial Holocene master curve for western North America and will be of particular value in dating geological and archeological materials using paleomagnetic directions.

  10. Potassium metasomatism of volcanic and sedimentary rocks in rift basins, calderas and detachment terranes

    NASA Technical Reports Server (NTRS)

    Chapin, C. E.; drographic basins.

    1985-01-01

    The chemical, mineralogical, and oxygen-isotopic changes accompanying K-metasomatism are described. The similarities with diagenetic reactions in both deep marine and alkaline, saline-lake environments are noted. The common occurrence of K-metasomatism in upper-plate rocks of detachment terranes indicates that the early stage of severe regional extension causes crustal downwarping and, in arid to semi-arid regions, development of closed hydrographic basins.

  11. Rock thermal conductivity at the cap rock and initial conditions in two-phase volcanic hydrothermal systems

    SciTech Connect

    Mario Cesar Suarez Arriaga

    1993-01-28

    Numerical experiments are performed to investigate the rock thermal conductivity influence in the formation of the thermodynamic initial conditions of two-phase systems located in volcanic rocks. These systems exhibit pressure and temperature profiles characterized by a sudden change or discontinuity in their vertical gradients. Vapor dominated, two-phase fluids are found at the upper reservoir's levels. Liquid is the dominated phase within the layers below some critical point. Numerical results presented in this paper, suggest that the vertical location of this point of discontinuity be controlled by the thermal conductivity existing between the limit of the reservoir and the caprock. Too high values could originate liquid dominated reservoirs. Small values would be at the origin of vapor dominated reservoirs. A characteristic middle value could be responsible for the formation of a counter flow mechanism originating the initial conditions observed at some locations of the Los Azufres, Mexico, geothermal field.

  12. Ulvöspinel from xenoliths of contact-altered volcanic and volcanosedimentary rocks in nepheline syenites of the Khibiny and Lovozero plutons

    NASA Astrophysics Data System (ADS)

    Ivanyuk, G. Yu.; Korchak, Yu. A.; Pakhomovsky, Ya. A.; Men'shikov, Yu. P.; Yakovenchuk, V. N.

    2012-12-01

    Ulvöspinel is a typical accessory mineral of xenoliths of volcanic and volcanosedimentary rocks in alkaline syenites of the Khibiny and Lovozero plutons. Ulvöspinel forms homogeneous Cr- and V-rich grains in slightly altered olivine basalts, basaltic tuffs, and tuffites and is enriched in Mn and Si in the course of contact-metasomatic alteration of these rocks. The strongly reduced conditions of contact metamorphism controlled by ascending flows of hydrocarbon gases and hydrogen sulfide gave rise to the subsolidus decomposition of primary ulvöspinel and Ti-high magnetite with the formation of ilmenite lamellae and then, with decreasing redox potential, of the second-generation latticed ulvöspinel lamellae.

  13. Petrogenesis and tectonic significance of the late Triassic mafic dikes and felsic volcanic rocks in the East Kunlun Orogenic Belt, Northern Tibet Plateau

    NASA Astrophysics Data System (ADS)

    Hu, Yan; Niu, Yaoling; Li, Jiyong; Ye, Lei; Kong, Juanjuan; Chen, Shuo; Zhang, Yu; Zhang, Guorui

    2016-02-01

    We present zircon U-Pb ages and geochemical data on the late Triassic mafic dikes (diabase) and felsic volcanic rocks (rhyolite and rhyolitic tuffs) in the East Kunlun Orogenic Belt (EKOB). These rocks give a small age window of 228-218 Ma. The mafic dikes represent evolved alkaline basaltic melts intruding ~ 8-9 Myrs older and volumetrically more abundant A-type granite batholith. Their rare earth element (REE) and multi-element patterns are similar to those of the present-day ocean island basalts (OIBs) except for a weak continental crustal signature (i.e., enrichment of Rb and Pb and weak depletion of Nb, Ta and Ti). Their trace element characteristics together with the high 87Sr/86Sr (0.7076-0.7104), low εNd(t) (- 2.18 to - 3.46), low εHf(t) (- 2.85 to - 4.59) and variable Pb isotopic ratios are consistent with melts derived from metasomatized subcontinental lithospheric mantle with crustal contamination. The felsic volcanic rocks are characterized by high LREE/HREE (e.g., [La/Yb]N of 5.71-17.00) with a negative Eu anomaly and strong depletion in Sr and P, resembling the model upper continental crust (UCC). Given the high 87Sr/86Sr (0.7213-0.7550) and less negative εNd(t) (- 3.83 to - 5.09) and εHf(t) (- 3.06 to - 3.83) than the UCC plus the overlapping isotopes with the mafic dikes and high Nb-Ta rhyolites, the felsic volcanic rocks are best interpreted as resulting from melting-induced mixing with 45-50% crustal materials and 50-55% mantle-derived mafic melts probably parental to the mafic dikes. Such mantle-derived melts underplated and intruded the deep crust as juvenile crustal materials. Partial melting of such juvenile crust produced felsic melts parental to the felsic volcanic rocks in the EKOB. We hypothesize that the late Triassic mafic dikes and felsic volcanic rocks are associated with post-collisional extension and related orogenic collapse. Such processes are probably significant in causing asthenospheric upwelling, decompression melting

  14. New radiometric age of volcanic rocks in the central Eritrean plateau (from Asmara to Adi Quala): Considerations on stratigraphy and correlations

    NASA Astrophysics Data System (ADS)

    Zanettin, B.; Bellieni, G.; Visentin, E. Justin

    2006-06-01

    New radiometric data have recently been acquired on basalt and rhyolite sampled at various levels of the volcanic sequence occurring in the central Eritrean plateau, confirming the stratigraphic reconstruction suggested in a previous paper [Zanettin, B., Bellieni, G., Justin Visentin, E., Haile, T., 1999. The volcanic rocks of the Eritrean plateau: stratigraphy and evolution. Acta Volcanologica 11(1), 183-193]. New considerations indicate the tholeiitic, not alkaline, nature of the Asmara basalt. Doubts about the relative age of the Aiba/Alaji and Asmara basalts have now been clarified: they are, at least partly, coeval (about 30 Ma old). The Serae rhyolite intercalated in the Adi Ugri basalt turns out to be about 24 Ma old, like the more abundant ignimbrite outcropping in the Senafe area, of which it is the westernmost extension. Its age confirms that it does not correspond to the trachyte intercalated in the Oligocene stratoid basalt of the Adwa-Axum area (where the Adi Ugri basalt probably also occurs, intercalated with the Serae trachyte and rhyolite). The upper part of the Adi Ugri basalt is 22 Ma old (an age consistent with the finding of a Deinotherium tooth). The radiometric age of these rocks also confirms already indicated correlations between Eritrean and Ethiopian volcanic formations.

  15. Paleomagnetic investigation of some volcanic rocks from the McMurdo volcanic province, Antarctica

    NASA Astrophysics Data System (ADS)

    Mankinen, Edward A.; Cox, Allan

    1988-10-01

    Paleomagnetic data for lava flows from sporadic but long-lived eruptions in the McMurdo Sound region are combined with previously published geologic and geochronologic data to determine the general eruptive sequence of the area. Lava flows in the Walcott Bay area were erupted during the Gauss Normal, Matuyama Reversed, and Brunhes Normal Polarity Chrons. The youngest flows on Black Island probably erupted near the boundary between the Gilbert and Gauss chrons. The most recent activity was concentrated on the volcanic edifices of Mounts Morning and Discovery and on Ross Island where Mount Erebus is currently active. Combining virtual geomagnetic poles calculated for 39 units sampled during this study with those of eight flows that were published previously yields a mean paleomagnetic pole at 87.3°N, 317.3°E (α95 = 6.3°). The ancient geomagnetic field dispersion about this mean pole is 23.5°, with upper and lower limits of 95% confidence equal to 27.4° and 20.5°, respectively. This value probably is a reasonable estimate of secular variation for the Antarctic continent during Pliocene and Pleistocene time.

  16. Thermo-physical rock properties of greywacke basement rock and intrusive lavas from the Taupo Volcanic Zone, New Zealand

    NASA Astrophysics Data System (ADS)

    Mielke, P.; Weinert, S.; Bignall, G.; Sass, I.

    2016-09-01

    Greywacke of the Waipapa and Torlesse (Composite) Terrane form the basement of the Taupo Volcanic Zone (TVZ), New Zealand. Together with inferred buried lavas, domes and igneous complexes they are likely to be the dominant rock type prevailing at depths > 4 km beneath the TVZ. A fundamental understanding of the rock properties of the deep formations is of utmost importance for the exploration of deep unconventional geothermal resources. An outcrop analogue study was conducted to improve the understanding of the thermo-physical rock properties of likely deep buried rock formations beneath the TVZ. A total of 145 core samples were taken at 10 locations inside and outside the TVZ and their grain and bulk density, porosity, matrix permeability, bulk thermal conductivity and specific heat capacity, and the compressional and shear wave velocities measured on oven-dry samples. Additional tests of the unconfined compressive strength were conducted for selected greywacke samples to quantify their mechanical rock strength. The obtained data indicates that the thermo-physical rock properties are mainly controlled by porosity, and minor by mineralogy, texture and grain size. Samples from Waipapa-type and Torlesse-type greywacke exhibit minor rheological differences, with Waipapa-type greywacke having lowest porosity (about 1% vs. 3%) and highest bulk thermal conductivity (2.5 W m- 1 K- 1 vs. 1.7 W m- 1 K- 1) and specific heat capacity (0.8 kJ kg- 1 K- 1 vs. 0.7 kJ kg- 1 K- 1). Matrix permeability is < 1E-16 m2 for all greywacke samples. Tested lavas exhibit heterogeneous rock properties due to their wide range of porosity (< 1% up to 32%). The thermo-physical rock properties were tested at laboratory conditions (ambient temperature and pressure), which do not reflect the in situ conditions at greater depth. With depth, thermal conductivity and acoustic wave velocity are likely to decrease caused by micro fractures resulting from thermal cracking of the rock, while specific

  17. Matrix diffusion of some alkali- and alkaline earth-metals in granitic rock

    SciTech Connect

    Johansson, H.; Byegaard, J.; Skarnemark, G.; Skaalberg, M.

    1997-12-31

    Static through-diffusion experiments were performed to study the diffusion of alkali- and alkaline earth-metals in fine-grained granite and medium-grained Aespoe-diorite. Tritiated water was used as an inert reference tracer. Radionuclides of the alkali- and alkaline earth-metals (mono- and divalent elements which are not influenced by hydrolysis in the pH-range studied) were used as tracers, i.e., {sup 22}Na{sup +}, {sup 45}Ca{sup 2+} and {sup 85}Sr{sup 2+}. The effective diffusivity and the rock capacity factor were calculated by fitting the breakthrough curve to the one-dimensional solution of the diffusion equation. Sorption coefficients, K{sub d}, that were derived from the rock capacity factor (diffusion experiments) were compared with K{sub d} determined in batch experiments using crushed material of different size fractions. The results show that the tracers were retarded in the same order as was expected from the measured batch K{sub d}. Furthermore, the largest size fraction was the most representative when comparing batch K{sub d} with K{sub d} evaluated from the diffusion experiments. The observed effective diffusivities tended to decrease with increasing cell lengths, indicating that the transport porosity decreases with increasing sample lengths used in the diffusion experiments.

  18. The nature and origin of mineral coatings on volcanic rocks of the Black Mountain, Stonewall Mountain and Kane Springs Wash volcanic centers in southern Nevada

    NASA Technical Reports Server (NTRS)

    Taranik, J. V.; Noble, D. D.; Hsu, L. C.; Hutsinpiller, A.

    1986-01-01

    Four LANDSAT thematic mapping scenes in southern Nevada were requested at two different acquisition times in order to assess the effect of vegetation on the signature of the volcanic units. The remote sensing data acquisition and analysis portion are nearly completed. The LANDSAT thematic mapping data is of good quality, and image analysis techniques are so far successful in delineating areas with distinct spectral characteristics. Spectrally distinct areas were correlated with variations in surface coating and lithologies of the volcanic rocks.

  19. Nature and origin of mineral coatings on volcanic rocks of the Black Mountain, Stonewall Mountain and Kane Springs Wash volcanic centers, southern Nevada

    NASA Technical Reports Server (NTRS)

    Taranik, J. V.; Noble, D. C.; Hsu, L. C.; Hutsinpiller, A.; Spatz, D.

    1986-01-01

    Surface coatings on volcanic rock assemblages that occur at select tertiary volcanic centers in southern Nevada were investigated using LANDSAT 5 Thematic Mapper imagery. Three project sites comprise the subject of this study: the Kane Springs Wash, Black Mountain, and Stonewall Mountain volcanic centers. LANDSAT 5 TM work scenes selected for each area are outlined along with local area geology. The nature and composition of surface coatings on the rock types within the subproject areas are determined, along with the origin of the coatings and their genetic link to host rocks, geologic interpretations are related to remote sensing units discriminated on TM imagery. Image processing was done using an ESL VAX/IDIMS image processing system, field sampling, and observation. Aerial photographs were acquired to facilitate location on the ground and to aid stratigraphic differentiation.

  20. Interpretation of volcanic gas data from tholeiitic and alkaline mafic lavas

    SciTech Connect

    Gerlach, T. M.

    1980-01-01

    Data are tabulated for approximately 150 previously reported collections of high-temperature volcanic gases from basic lavas using computational techniques recently introduced by the author. Research problems dealing with the composition of volcanic gases and their relation to lava chemistry are outlined. The need for more accurate data on the volume of gases released during eruptions is also noted. (PCS)

  1. Application Of Continuous Wavelet Transform On Aeromagnetic Data To Identify Volcanic Rocks

    NASA Astrophysics Data System (ADS)

    Yang, Y.; Li, Y.; Liu, T.

    2008-12-01

    This paper focuses on the application of continuous wavelet transform on aeromagnetic data, to locate and characterize volcanic rocks. The studied structure is sited in the north centre of the Huanghua depression in the Bohaiwan basin of east China. As channels of magmatism activities, the faults have caused multi-stage magma outpouring and intrusion, forming igneous rocks of different series of strata. As a traditional frequency decomposition method, the discrete wavelet transform is unable to localize frequency variations over time. To handle this problem, the short time Fourier transform method is widely used for the decomposition of non-stationary signals. One problem with this approach is that the fixed width `window function' results in limited resolution. Therefore, the continuous wavelet transform decomposition was used as an alternative approach to overcome this resolution problem. In the continuous wavelet transform, the signal is multiplied with a function similar to a `window function' but the width of the window is not fixed. The time window width is allowed to vary depending upon the frequency that is being considered. As for the magnetic anomalies of igneous rocks, they have different frequencies due to their depths; by analyzing the complex wavelet-based time-frequency characteristics of certain frequencies, we can identify the residual anomalies caused by volcanic rocks in different depths. The theoretical results show that local high frequency spectrum anomalies are the reflection of magnetic sources, and different scales (or different center frequencies) reflect different source depths, with larger scales for deeper sources. Therefore, by analyzing the complex wavelet-based frequency spectrum under different centre frequencies, we can analyze the distribution of magnetic field sources. Then the continuous wavelet transform was applied on the RTP aeromagnetic data of our study area. The data processing results present a detailed description of the

  2. Raman spectroscopic and scanning electron microscopic analysis of a novel biological colonisation of volcanic rocks

    NASA Astrophysics Data System (ADS)

    Jorge Villar, Susana E.; Edwards, Howell G. M.; Benning, Liane G.

    2006-09-01

    A novel type of colonisation of a basaltic rock, collected on the Arctic island of Svalbard, Norway, during the AMASE expedition in 2004, was characterised using Raman spectroscopy and Scanning Electron Microscopy (SEM). The sample contains two different types of extremophile communities, one occurring behind a radial white crystallisation and the other occurring inside a dark vacuole. Several types of minerals and microbial colonies have been identified by both Raman spectroscopy and SEM analyses. It is the first time that photosynthetic communities have been documented to colonise the inside of dark basaltic rocks. Our discovery has important implications for planetary exploration because it extends the analytical capability and our understanding of microbial rock colonisations to subaerial volcanic outcrops and has wide implications towards the search for life in extraterrestrial planets. In this work we also demonstrate that the use of different laser wavelengths for Raman spectroscopic studies and complementary microscopic analysis are critical for a comprehensive organic and inorganic compound identification.

  3. Solid Inclusions in Au-nuggets, genesis and derivation from alkaline rocks of the Guli Massif, Northern Siberia

    NASA Astrophysics Data System (ADS)

    Dvorani, Sami N.

    2016-04-01

    A total of 112 Au-nuggets, collected from alluvial placer deposits of the Ingarinda River from the Guli massif, located in northem Siberia, Russia, were investigated. The Guli massif consists of a huge dunite-clinopyroxenite complex (the largest complex in the world), an alkaline to highly alkaline rock suite (melilite, nephelinite, ijolite) enveloping the dunite and carbonatite intrusions, associated with disseminated schlieren type chromitite and Au-Ag, Pt placer deposits. The nuggets are characterized by various sizes and shapes and show chemical compositions Au, Au-Ag and AuCu, typical for a derivate of carbon-atites and/or ultramafic complexes. A great variety of oxide, silicate, REE-minerals, carbonate and sulphide inclusions have been detected in the nuggets, which are identical in mineralogy and chemical composition to mineral constituents of the alkaline to highly alkaline rock suite surrounding the Guli dunite core complex thus, considered as the source for Au-nuggets.

  4. New insights into the petrogenesis of volcanic rocks in the Shanghang Basin in the Fujian Province, China

    NASA Astrophysics Data System (ADS)

    Jiang, Si-Hong; Bagas, Leon; Liang, Qing-Ling

    2015-06-01

    The Mesozoic Shanghang Basin in southeastern China consists of Early Cretaceous mottled coarse-grained clastic and volcanic rocks, and Late Cretaceous clastic rocks. The volcanic rocks are intermediate-mafic to felsic and spatially close to the famous Zijinshan Mineral Field. In order to better understand the timing, petrogenesis and tectonic setting of these volcanic rocks and the relationship between magmatism and metallogeny in the mineral field, U-Pb zircon geochronological, geochemical and Sr-Nd-Pb-Hf isotopic studies were completed on the volcanic rocks. Fifteen LA-MC-ICP-MS U-Pb zircon analyses of the volcanic rocks yield weighted mean ages of between 105 and 99 Ma. Major and trace element geochemistry shows that these rocks are mostly high-K to shoshonitic, enriched in LREE and Th, U, and depleted in Ba, Nb, Sr, P and Ti. The volcanic rocks have 87Sr/86Sri ratios of between 0.70732 and 0.70977, 206Pb/204Pb isotope ratios of 18.57-19.77, 207Pb/204Pb isotope ratios of 15.64-15.71, 208Pb/204Pb isotope ratios of 38.87-40.62, 176Hf/177Hf ratios of 0.282589-0.282823, εNdT values of -7.5 to -4.7, and εHf(t) values of -4.2 to 4. Such characteristics, with similarities to coeval volcanic and intrusive rocks adjacent to the basin, suggest that the parent magma of the Cretaceous volcanic rocks in the basin and their contemporaneous intrusives originated from crustal melts with a juvenile component. Petrogenetically, fractional crystallization with minor wall-rock assimilation is the controlling process in deriving a wide range of more evolved rocks. With reference to the ore-forming events and isotopic features of ore-related intrusions in the Zijinshan Mineral Field, we propose that volcanism in the Shanghang Basin and coeval magmatism in the mineral field are related to the formation of the regional porphyry and epithermal Cu-Au-Mo-Ag deposits in an extension tectonic setting related to the subduction of the Paleo-Pacific Plate.

  5. Some geochemical features of Caledonian volcanism recorded in sedimentary rocks of the East Baltic area

    NASA Astrophysics Data System (ADS)

    Soesoo, Alvar; Kiipli, Tarmo; Kallaste, Toivo

    2013-04-01

    The Caledonian rocks have formed as a result of a multitude of magmatic and tectonic processes. All these major processes have generated a set of volcanic and magmatic products. While products of intrusive magmatism can still be well recognised in Caledonian mountains, some of the volcanic products can be found in a wide area of the Baltica paleocontinent. The best record of the ancient explosive volcanism can be traced in sedimentary sections adjacent to tectonically active areas. The aim of this study is to describe geochemical evolution of the volcanism near the Baltica plate using bulk geochemistry and phenocryst compositions of the Caledonian volcanic ashes stored in the Lower Palaeozoic sections of the Eastern Baltica. The bentonite samples were collected from several drill cores from Estonia, Latvia and Lithuania. Thickness of the ash beds varies mostly between 0.1 and 10 cm, rarely reaching 20-70 cm. Constructed isopach schemes indicate increase of thickness of ash beds towards the northwest and west. Original sanidine composition in ca 400 samples and biotite from 13 ash beds were analysed from grain fraction of bentonites using X-ray diffractometry. Stratigraphical distribution of volcanic ash beds in the East Baltic area can be subdivided into four major intervals separated by intervals with less frequent signs of volcanism. The above intervals show characteristic geochemical signatures. Over 175 thin altered volcanic ash beds have been recognised by authors in the East Baltic sedimentary sections from the Upper Ordovician (ca. 458 Ma) to the Upper Silurian (ca. 421 Ma). There separate ash units may correspond to distinct volcanic eruptions in Caledonides. Volcanic ashes which reached the East Baltic area fall into four time periods (time intervals distinguished by micro-paleontological methods): (1) Sandbian with main sources at the margins of the Avalonian microcontinent; (2) Katian with sources at the margin of the Baltica in Iapetus Palaeo

  6. Uranium geochemistry of selected rock units from the Marysvale Volcanic Field, Piute County, Utah

    SciTech Connect

    Hoffer, R.L.

    1982-01-01

    The Marysvale Volcanic Field is an area rich in uranium. This study was undertaken to determine if the uranium deposits might be of volcanogenic origin. This geochemical study consisted of determining the major, minor and trace element concentrations of the major volcanic units, and the relationships of the rock chemistry to uranium mineralization. The units in the Marysvale Volcanic Field, consist of ash-flow tuffs, intermediate lava flows, and associated intrusives of the Bullion Canyon volcanics and ash-flow tuffs, volcaniclastic deposits, domes and stocks of the Mount Belknap volcanics. When compared to overlaying welded tuff or rhyolitic units, the vitrophyric samples from the Mount Belknap volcanic units, are all enriched in F, Cs, and U, and that 50% of the vitrophyres are enriched in Cr, Cu, Mo, Ni, Zr, Pb, Sr, V, and Zn. Overlying untis have been devitrified and have released U as well as other trace elements into the volcanogenic system. This study has reevaluated the Marysvale Central Mining District and has proposed another theory as to the origin of the uranium deposits in that area. This hypothesis places a previously unidentified caldera around the area, and this author has named it the Marysvale caldera. Evidence for this caldera includes: arcurate faults which surround the region; alteration patterns which appear to form a circular pattern along the boundary of the proposed caldera; the presence of small monzonite intrusive bodies appear to ring the caldera; the presence of ash-flow tuffs which thicken appreciably along the northeast boundary of the caldera; and the central intrusive which may represent a resurgent phase of the proposed caldera. This seems to be a viable alternative to the magmatic hydrothermal origin for the uranium deposits presently proposed for the Central Mining District.

  7. Major element, REE, and Pb, Nd and Sr isotopic geochemistry of Cenozoic volcanic rocks of eastern China: implications for their origin from suboceanic-type mantle reservoirs

    USGS Publications Warehouse

    Basu, A.R.; Wang, Junwen; Huang, Wankang; Xie, Guanghong; Tatsumoto, M.

    1991-01-01

    Major- and rare-earth-element (REE) concentrations and UThPb, SmNd, and RbSr isotope systematics are reported for Cenozoic volcanic rocks from northeastern and eastern China. These volcanic rocks, characteristically lacking the calc-alkaline suite of orogenic belts, were emplaced in a rift system which formed in response to the subduction of the western Pacific plate beneath the eastern Asiatic continental margin. The rocks sampled range from basanite and alkali olivine basalt, through olivine tholeiite and quartz tholeiite, to potassic basalts, alkali trachytes, pantellerite, and limburgite. These rock suites represent the volcanic centers of Datong, Hanobar, Kuandian, Changbaishan and Wudalianchi in northeastern China, and Mingxi in the Fujian Province of eastern China. The major-element and REE geochemistry is characteristic of each volcanic suite broadly evolving through cogenetic magmatic processes. Some of the outstanding features of the isotopic correlation arrays are as follows: (1) NdSr shows an anticorrelation within the field of ocean island basalts, extending from the MORB end-member to an enriched, time-averaged high Rb Sr and Nd Sr end-member (EM1), (2) SrPb also shows an anticorrelation, similar to that of Hawaiian and walvis Ridge basalts, (3) NdPb shows a positive correlation, and (4) the 207Pb 204Pb vs 206Pb 204Pb plot shows linear arrays parallel to the general trend (NHRL) for MORB on both sides of the geochron, although in the 208Pb 204Pb vs 206Pb 204Pb plot the linear array is significantly displaced above the NHRL in a pattern similar to that of the oceanic island basalts that show the Dupal signatures. In all isotope correlation patterns, the data arrays define two different mantle components-a MORB-like component and an enriched mantle component. The isotopic data presented here clearly demonstrate the existence of Dupal compositions in the sources of the continental volcanic rocks of eastern China. We suggest that the subcontinental mantle

  8. Crystal chemistry of clinopyroxene from alkaline undersaturated rocks of the Monte Vulture Volcano, Italy

    NASA Astrophysics Data System (ADS)

    Bindi, Luca; Cellai, Daniela; Melluso, Leone; Conticelli, Sandro; Morra, Vincenzo; Menchetti, Silvio

    1999-02-01

    The Monte Vulture is a Late Pleistocene stratovolcano, composed of highly undersaturated alkaline potassic to ultrapotassic rocks belonging to the Roman Magmatic Province. These rocks are notably richer in Na 2O if compared to similar rocks of the Roman Province. Two distinct magmatic Series have been recognized: (1) feldspar-bearing series, ranging from basanite to phonolite, and a volumetrically subordinate (2) feldspar-free series, consisting of melilitite, melafoidite, and haüynophyre. The clinopyroxene compositions of the feldspar-bearing series ranges from diopside to ferro-salite (hedenbergite), and shows, from basanite to phonotephrite, increasing FeO tot, Al 2O 3, and TiO 2 and decreasing of MgO contents. Clinopyroxene in basanites and tephrites has generally high Fe 3+ contents, which is typical for clinopyroxene from the Roman Province. Clinopyroxene of the feldspar-free series shows a more restricted variation in MgO, and has often very high Al 2O 3, FeO tot, and TiO 2 contents. In all the crystals examined the Al 3+ content is high and is present mostly on the T site and for a minor part on the M1 site. The M1-O2 distance shows a good correlation with the R M13+ content; clinopyroxene from basanites (feldspar-bearing series) has the lowest R M13+ and that from melilitite and haüynophyre (feldspar-free series) the highest R M13+ contents. Clinopyroxene crystals from feldspar-free rocks have smaller M1 and larger T polyhedral volumes when compared to those in olivine-melilitites and melilitites (kamafugites) from Umbria, but they show similar polyhedral volumes as clinopyroxene crystals from leucite-bearing rocks. Although clinopyroxene from feldspar-free rocks has small M1 volumes due to the high R 3+ contents, M1 volumes of clinopyroxene from melilitites are larger than expected because of the higher (Fe 3+/Al 3+) M1 values. This larger M1 volume of clinopyroxene in melilitites causes a shortening of and a lengthening of the M2-O3 distance

  9. Pan-African adakitic rocks of the north Arabian-Nubian Shield: petrological and geochemical constraints on the evolution of the Dokhan volcanics in the north Eastern Desert of Egypt

    NASA Astrophysics Data System (ADS)

    Obeid, Mohamed A.; Azer, Mokhles K.

    2015-04-01

    The Precambrian basement of Egypt is part of the Red Sea Mountains and represents the north-western part of the Arabian-Nubian Shield (ANS). Five volcanic sections are exposed in the Egyptian basement complex, namely El Kharaza, Monqul, Abu Had, Mellaha and Abu Marwa. They are located in the north Eastern Desert (ED) of Egypt and were selected for petrological and geochemical studies as they represent the Dokhan volcanics. The volcanics divide into two main pulses, and each pulse was frequently accompanied by deposition of immature molasse type sediments, which represent a thick sequence of the Hammamat group in the north ED. Compositionally, the rocks form a continuum from basaltic andesite, andesite, dacite (lower succession) to rhyodacite and rhyolite (upper succession), with no apparent compositional gaps. These high-K calc-alkaline rocks have strong affinities to subduction-related rocks with enriched LILEs (Rb, Ba, K, Th, Ce) relative to high field strength elements (Nb, Zr, P, Ti) and negative Nb anomalies relative to NMORB. The lower succession displays geochemical characteristics of adakitic rocks with SiO2 >53 wt%, Al2O3 >15 wt%, MgO >2.5 wt%, Mg# >49, Sr >650 ppm, Y <17 ppm, Yb <2 ppm, Ni >25 ppm, Cr >50 ppm and Sr/Y >42.4. They also have low Nb, Rb and Zr compared to the coexisting calc-alkaline rhyodacites and rhyolites. The highly fractionated rhyolitic rocks have strong negative Eu anomalies and possess the geochemical characteristics of A-type suites. Trace element geochemical signatures indicate a magma source consistent with post-collisional suites that retain destructive plate signatures associated with subduction zones. The adakitic rocks in the northern ANS are generated through partial melting of delaminated mafic lower crust interacting with overlying mantle-derived magma. The Dokhan volcanics were likely generated by a combination of processes, including partial melting, crystal fractionation and assimilation.

  10. Th isotope and U-series studies of subduction-related volcanic rocks

    SciTech Connect

    Gill, J.B.; Williams, R.W. )

    1990-05-01

    The activities of 6-7 radionuclides measured by alpha spectrometry are reported for 35 samples of recent volcanic rocks from 24 volcanoes in 9 arcs. These include continental margins (Cascades, Alaska, Costa Rica), island arcs (the Sunda, Banda, and Sangihe arcs of Indonesia, Marianas, Japan, Aleutians, Antilles, Tonga), and a backarc basin (Lau Basin). Enrichment of {sup 238}U over {sup 230}Th is more common and greater in these subduction-related volcanics than in those from other tectonic environments. {sup 230}Th/{sup 232}Th ratios also extend to higher values, both in absolute numbers and relative to other isotope ratios. Enrichment of {sup 210}Po and {sup 226}Ra over {sup 230}Th is widespread and is more common and greater in island arcs than continental margins. The level of Po or Ra enrichment is similar to that in ocean island and ridge basalts and deceases with differentiation. The differences in Th-U systematics between subduction-related and other volcanic rocks are attributed to variations in the process of melt extraction, changes in bulk partition coefficients within the mantle wedge, or preferential addition of U from subducted lithosphere. Ra enrichments are attributed to partial melting processes which are similar to those at ocean ridges. Smaller excesses at continental margins are attributed either to slower ascent or to differences in the process of melt formation beneath continents.

  11. Geochronological and geochemical constraints on the petrogenesis of late Cretaceous volcanic rock series from the eastern Sakarya zone, NE Anatolia-Turkey

    NASA Astrophysics Data System (ADS)

    Aydin, Faruk; Oǧuz, Simge; Şen, Cüneyt; Uysal, İbrahim; Başer, Rasim

    2016-04-01

    New SHRIMP zircon U-Pb ages and whole-rock geochemical data as well as Sr-Nd-Pb and δ18O isotopes of late Cretaceous volcanic rock series from the Giresun and Artvin areas (NE Anatolia, Turkey) in the northern part of the eastern Sakarya zone (ESZ) provide important evidence for northward subduction of the Neo-Tethyan oceanic lithosphere along the southern border of the ESZ. In particular, tectonic setting and petrogenesis of these subduction-related volcanites play a critical role in determining the nature of the lower continental crust and mantle dynamics during late Mesozoic orogenic processes in this region. The late Cretaceous time in the ESZ is represented by intensive volcanic activities that occurred in two different periods, which generally consist of alternation of mafic-intermediate (basaltic to andesitic) and felsic rock series (dacitic to rhyolitic) within each period. Although there is no geochronological data for the lower mafic-intermediate rock series of the first volcanic period, U-Pb zircon dating from the first cycle of felsic rocks yielded ages ranging from 88.6±1.8 to 85.0±1.3 Ma (i.e. Coniacian-Early Santonian). The first volcanic period in the region is generally overlain by reddish biomicrite-rich sedimentary rocks of Santonian-Early Campanian. U-Pb zircon dating for the second cycle of mafic-intermediate and felsic rocks yielded ages varying from 84.9±1.7 to 80.8±1.5Ma (i.e. Early to Middle Campanian). The studied volcanic rocks have mostly transitional geochemical character changing from tholeiitic to calc-alkaline with typical arc signatures. N-MORB-normalised multi-element and chondrite-normalised rare earth element (REE) patterns show that all rocks are enriched in LILEs (e.g. Rb, Ba, Th) and LREEs (e.g. La, Ce) but depleted in Nb and Ti. In particular, the felsic samples are characterised by distinct negative Eu anomalies. The samples are characterized by a wide range of Sr-Nd-Pb isotopic compositions (initial ɛNd values from -7

  12. Catalytic properties of volcanic rocks in the synthesis of hydrocarbons from carbon monoxide and hydrogen

    SciTech Connect

    Taran, Yu.A.; Novak, F.I.; Antoshchuk, I.A.; Bashkirov, A.N.

    1981-10-01

    Results obtained from studying the catalytic properties of effusive rocks of various chemical compositions, extracted from lava flows of several Kamchatka volcanos, in the process of synthesis from carbon monoxide and hydrogen, are presented. It was evident that samples of volcanic rock display catalytic properties in the process of synthesis from CO and H/sub 2/ in which liquid and gaseous hydrocarbons and an insignificant amount of oxygen-containing compounds are formed as products of the reactions. At a synthesis temperature of 350/sup 0/C the catalytic activity of the samples is characterized by the conversion of CO at a level of 70 to 80%, and H/sub 2/ at 50 to 60%. The yield of oil, gasoline, and natural gas reached 40, 11, and 3 ml/m/sup 3/, respectively. The light synthetic products were presented based on saturated hydrocarbons of an aliphatic series with significant contents of olefins and insignificant quantities of alcohols and carbonyl compounds. The composition of gaseous products is characterized by significant unsaturation (approx. 33%) and a high content of butane-butylenic fractions (to approx. 55%). The data obtained showed that volcanic rocks were able to catalyze the synthesis of hydrocarbons from CO and H/sub 2/. The sources of the catalytic properties of the rocks shown are evidently iron compounds, and the remaining ingredients of the rocks are able to fulfill the role of structural or chemical promoters influencing the properties of the catalysts and the composition of the reaction products formed. 2 tables. (DP)

  13. Changes in Bacteria Recoverable from Subsurface Volcanic Rock Samples during Storage at 4°C

    PubMed Central

    Haldeman, Dana L.; Amy, Penny S.; White, David C.; Ringelberg, David B.

    1994-01-01

    The abundance of viable microorganisms recovered from deep subsurface volcanic rock samples increased after rock perturbation and storage for 1 week at 4°C, while the diversity and evenness of recoverable heterotrophic bacterial communities generally decreased. One sample of each morphologically distinct colony type, recovered both before and after storage of U12n rock samples, was purified and characterized by fatty acid methyl ester (MIDI) and API rapid NFT strips. As determined by MIDI cluster analysis, the composition of the recoverable microbial communities changed with storage of rock samples; some groups of organisms were recovered only before, only after, or at both sample times. In general, the isolates recovered only after storage of rock samples had a greater ability to utilize the carbohydrates included in API test strips and had faster generation times than isolates recovered only on initial plating. The nutritional versatility and faster growth rates of organisms recovered in higher proportions after sample storage provide evidence that some microbial community changes may be due to the proliferation of a few bacterial types. However, because some new genera are recovered only after storage, the possibility also exists that dormant bacterial types are resuscitated during sample perturbation and storage. PMID:16349343

  14. Synchronous late Pleistocene extensional faulting and basaltic volcanism in pluvial Fort Rock basin, central Oregon

    NASA Astrophysics Data System (ADS)

    Mackey, B. H.; Castonguay, S. R.; Wallace, P. J.; Weldon, R. J.

    2012-12-01

    Central Oregon, where northern Basin and Range extension intersects the High Lava Plains, exhibits widespread extensional faulting and Quaternary basaltic volcanism, yet the relations between the processes are complex and chronology is poorly constrained. Here we use cosmogenic 3He exposure dating of basalt to quantify the timing of normal faulting and emplacement of a related cinder cone volcanic field on the margins of pluvial Fort Rock Lake. The N15W striking North Christmas Valley fault system offsets High Lava Plains volcanics forming a ~3 km wide graben that transects the eastern Fort Rock Basin. Several young volcanic vents, including the ~740 ka Green Mountain (GM) shield volcano, and younger Four Craters lava field (4C), are aligned parallel with, and bounded by the graben. The western edge of the graben is expressed as an enigmatic monocline with up to10 m vertical throw and a prominent vertical hinge crack due to folding of the overlying GM lava flows. Younger basalt flows of the 4C field abut and flow into this crack, known as the 'Crack in the Ground' fault. Exposure dating of the 4C lava field on the eastern flank of GM indicates an emplacement age of 13 ka, which is largely consistent across multiple flows emerging from the 4 linearly aligned cinder cones. In addition, we dated the GM basalt exposed in the sub-vertical walls of the crack (the fault wall), which are cleanly separated by up to 10 m, but with uneroded (and in places identically matching) crack walls. Samples were taken >3 m below ground surface to avoid pre-faulting inheritance, and required considerable shielding corrections, but return a consistent exposure age of ~13 ka. This suggests substantial crack opening occurred at the same time the 4C lava was emplaced. A small fault offsets the 4C lava where it flows across the Crack, and dating the fault wall of this younger lava also generated an exposure age of 13 ka, indicating it must have ruptured shortly after the 4C lava cooled

  15. Nature and occurrence of cooling-induced cracking in volcanic rocks

    NASA Astrophysics Data System (ADS)

    Browning, John; Meredith, Philip G.; Gudmundssom, Agust

    2015-04-01

    Several hypotheses have been proposed regarding the role of thermo-mechanical contraction in producing cracks and joints in volcanic rocks. Nevertheless, most studies of thermally-induced cracking to date have focused on the generation of cracks formed during heating. In this latter case, the cracks are formed under an overall compressional regime. By contrast, cooling cracks are formed under an overall tensile regime. Therefore, both the nature and mechanism of crack formation during cooling are hypothesised to be different from those for crack formation during heating. Furthermore, it remains unclear whether cooling simply reactivates pre-existing cracks, induces the growth of new cracks, or both. We present results from experiments based on a new method for testing ideas on cooling-induced cracking. Cored samples of volcanic rock (basaltic to dacitic in composition) were heated at varying rates to different maximum temperatures inside a tube furnace. In the highest temperature experiments samples of both rocks were raised to the liquidus temperature appropriate to their composition, forcing melt interaction and crack annealing. We present in-situ seismic velocity and acoustic emission data, which were recorded throughout each heating and cooling cycle. It is found consistently that the rate of acoustic emission is much higher during cooling than during heating. In addition, acoustic emission events produced on cooling tend to be significantly higher in energy than those produced during heating. We therefore suggest that cracks formed during cooling are significantly larger than those formed during heating. Thin-section and crack morphology analysis of our cyclically heated samples provide further evidence of contrasting fracture morphologies. These new data are important for assessing the contribution of cooling-induced damage within volcanic structures and layers such as sills and lava flows. Our observations may also help to constrain evolving ideas regarding

  16. Late Cretaceous lithospheric extension in SE China: Constraints from volcanic rocks in Hainan Island

    NASA Astrophysics Data System (ADS)

    Zhou, Yun; Liang, Xinquan; Kröner, Alfred; Cai, Yongfeng; Shao, Tongbin; Wen, Shunv; Jiang, Ying; Fu, Jiangang; Wang, Ce; Dong, Chaoge

    2015-09-01

    Petrological, geochemical and in-situ zircon U-Pb dating and Hf-isotope analyses have been carried out on a suite of basalt-andesite-rhyolite volcanic rocks exposed in the Liuluocun area, Hainan Island, SE China. Zircon analyses show that these volcanic rocks crystallized in the Early Cretaceous (ca. 102 Ma). The basalts are characterized by low MgO contents and mg-numbers but high rare earth element, high field strength element and large ion lithophile element contents and Nb-Ta negative anomalies. They have relatively uniform Sr-Nd isotope compositions with εNd(t) values of - 4.09 to - 3.63. The andesites show enrichment of high field strength element and rare earth element with negligible Eu anomalies. They have εNd(t) values of - 2.35 to - 3.88 and εHf(t) values of - 9.73 to - 1.13. The rhyolites have high K2O and SiO2 contents. They are characterized by prominent Eu, P and Ti negative anomalies and enrichment in large ion lithophile element, and show εHf(t) values of - 7.51 to + 0.47 and εNd(t) values of - 2.49 to - 2.69. Petrogenetic analysis indicates that the Liuluocun volcanic rocks were produced by incomplete reaction of the mantle wedge peridotite with felsic melts derived from partial melting of subducted sediment. All these characteristics, combined with geological observations, suggest that their formation was related to regional lithospheric extension in the South China Craton during the Early Cretaceous, which may have been caused by subduction of the Paleo-Pacific plate beneath the continental plate of China.

  17. Cenozoic Volcanic Rocks of the Devils Postpile Quadrangle, Eastern Sierra Nevada, California

    USGS Publications Warehouse

    Huber, N. King; Rinehart, C. Dean

    1967-01-01

    Cenozoic volcanic rocks of the Devils Postpile quadrangle are of late Pliocene to Recent age and are divided into 11 map units. The suite is alkalic-calcic and ranges in composition from basalt to rhyolite. It includes a rhyolitic welded ash-flow tuff which is probably correlative with the Bishop Tuff, although the two units are geographically isolated by the Sierra Nevada drainage divide. The Devils Postpile itself is a classic example of columnar jointing in the lower part of a lava flow.

  18. Paleomagnetism of the Upper Miocene volcanic rocks from the East Carpathians (Gurghiu Mountains, Romania)

    NASA Astrophysics Data System (ADS)

    Panaiotu, Cristian George; Visan, Madalina; Necula, Cristian; Dumitru, Anca; Strachinaru, Andrei; Panaiotu, Andrei; Dimofte, Daniela; Seghedi, Ioan

    2015-04-01

    We present recent paleomagnetic results obtained from the volcanic rocks from the Gurghiu Mountains (East Carpathians, Romania). The Gurghiu Mountains are part of the 160 km long volcanic chain from the East Carpathians erupted between 10 Ma and 0.2 Ma. According to the K-Ar ages the volcanic activity took place in the Gurghiu Mountains between 9 Ma and 6 Ma. We sampled 103 sites, but after detailed AF and thermal demagnetizations only 80 sites passed the reliability criteria for the paleosecular variation studies: number of samples minimum 5, precision parameter k > 50. Rockmagnetic measurements (field dependence of magnetic susceptibility, low and high temperature variation of magnetic susceptibility, hysteresis properties, FORC diagrams) have shown that the main ferromagnetic minerals are magnetite or Ti poor magnetite. To select the data set within the paleosecular variation limits we have applied either the standard latitude cut-off at 45° or the Vandamme criterion. The data set selected using the Vandamme criterion has 65 sites and using the latitude cut-off it has 70 sites. Both data sets passed the reversal test. The paleosecular variation express as the dispersion of the virtual geomagnetic poles is within the limits expected for the latitude of 45°N. The area-mean declination is around 0° and the inclination is around 60°, which suggest a negative inclination anomaly in agreement with the global data set. The geographic distribution of the magnetic polarity is in agreement with the K-Ar ages and the magnetic polarity time scale and support the gradual migration of volcanism from north to south between 9 Ma and 6 Ma in the Gurghiu Mountains. Possible tectonics implications of the new paleomagnetic data for the evolution of volcanic chain and the Transylvanian basin will be discussed. This work was supported by a grant of the Ministry of National Education, CNCS - UEFISCDI, project number PN-II-ID-PCE-2012-4-0177.

  19. Unusual evolution of silica-under- and -oversaturated alkaline rocks in the Cenozoic Ambohimirahavavy Complex (Madagascar): Mineralogical and geochemical evidence

    NASA Astrophysics Data System (ADS)

    Estrade, Guillaume; Béziat, Didier; Salvi, Stefano; Tiepolo, Massimo; Paquette, Jean-Louis; Rakotovao, Soatsitohaina

    2014-10-01

    The almost unknown Ambohimirahavavy ring complex in the Cenozoic alkaline province of northwestern Madagascar has recently attracted considerable interest because of the discovery of important rare-metal mineralization. The complex consists of arc-shaped bodies made up of silica-under- and -oversaturated syenites and extremely evolved peralkaline granitic dykes, as well as several mafic to felsic volcanic units, including basalt, phonolite and trachyte, all of which have an alkaline affinity. Uranium-lead zircon ages of 24.2 ± 0.6 Ma and 23.5 ± 6.8 Ma have been obtained for nepheline syenites and peralkaline granitic dykes, respectively, which, together with field data and ages of neighboring complexes, support emplacement controlled by regional lithospheric structures, rather than an evolving hot spot. Whole-rock major and trace-element and Sr-Nd isotopic data for the mafic suite suggest that the parental melt of this complex was generated by low degrees of melting of a metasomatized mantle source with residual amphibole. Fractional crystallization of this alkali basaltic melt likely produced the silica-undersaturated suite. We propose that the silica-oversaturated suite evolved from the undersaturated melt after contamination of the latter by crustal material. Further evolution to peralkaline compositions in both suites is attributed mainly to plagioclase and alkali feldspar segregation. Nepheline and feldspar compositions, as well as considerations of mineral equilibria among mafic silicates and Fe-Ti oxide minerals indicate crystallization temperatures of 1000 to 700 °C and an oxygen fugacity of 0.4 to 0.8 log units below the fayalite-magnetite-quartz (FMQ) buffer at 1 kbar for the silica-undersaturated melt, and temperatures of 860 to 570 °C and an oxygen fugacity of 1.5 to 3.8 log units below FMQ for the oversaturated syenitic melt. The undersaturated melt evolved towards a more peralkaline composition. Crystallization of arfvedsonite plus aegirine

  20. Geochemistry and Geochronology of Middle Tertiary Volcanic Rocks of the Central Chiricahua Mountains, Southeast Arizona

    USGS Publications Warehouse

    du Bray, Edward A.; Pallister, John S.; Snee, Lawrence W.

    2004-01-01

    Middle Tertiary volcanic rocks of the central Chiricahua Mountains in southeast Arizona are the westernmost constituents of the Eocene-Oligocene Boot Heel volcanic field of southwestern New Mexico and southeastern Arizona. About two dozen volumetric ally and stratigraphically significant volcanic units are present in this area. These include large-volume, regionally distributed ash-flow tuffs and smaller volume, locally distributed lava flows. The most voluminous of these units is the Rhyolite Canyon Tuff, which erupted 26.9 million years ago from the Turkey Creek caldera in the central Chiricahua Mountains. The Rhyolite Canyon Tuff consists of 500-1,000 cubic kilometers of rhyolite that was erupted from a normally zoned reservoir. The tuff represents sequential eruptions, which became systematically less geochemically evolved with time, from progressively deeper levels of the source reservoir. Like the Rhyolite Canyon Tuff, other ashflow tuffs preserved in the central Chiricahua Mountains have equivalents in nearby, though isolated mountain ranges. However, correlation of these other tuffs, from range to range, has been hindered by stratigraphic discontinuity, structural complexity, and various lithologic similarities and ambiguities. New geochemical and geochronologic data presented here enable correlation of these units between their occurrences in the central Chiricahua Mountains and the remainder of the Boot Heel volcanic field. Volcanic rocks in the central Chiricahua Mountains are composed dominantly of weakly peraluminous, high-silica rhyolite welded tuff and rhyolite lavas of the high-potassium and shoshonitic series. Trace-element, and to a lesser extent, major-oxide abundances are distinct for most of the units studied. Geochemical and geochronologic data depict a time and spatial transgression from subduction to within-plate and extensional tectonic settings. Compositions of the lavas tend to be relatively homogeneous within particular units. In

  1. New Insights to the Mid Miocene Calc-alkaline Lavas of the Strawberry Volcanics, NE Oregon Surrounded by the Coeval Tholeiitic Columbia River Basalt Province

    NASA Astrophysics Data System (ADS)

    Steiner, A. R.; Streck, M. J.

    2013-12-01

    The Strawberry Volcanics (SV) of NE Oregon were distributed over 3,400 km2 during the mid-Miocene and comprise a diverse volcanic suite, which span the range of compositions from basalt to rhyolite. The predominant composition of this volcanic suite is calc-alkaline (CA) basaltic andesite and andesite, although tholeiitic (TH) lavas of basalt to andesite occur as well. The coeval flood basalts of the Columbia River province surround the SV. Here we will discuss new ages and geochemical data, and present a new geologic map and stratigraphy of the SV. The SV are emplaced on top of pre-Tertiary accreted terranes of the Blue Mountain Province, Mesozoic plutonic rocks, and older Tertiary volcanic rocks thought to be mostly Oligocene of age. Massive rhyolites (~300 m thick) are exposed mainly along the western flank and underlie the intermediate composition lavas. In the southern portion of this study area, alkali basaltic lavas, thought to be late Miocene to early Pliocene in age, erupted and overlie the SV. In addition, several regional ignimbrites reach into the area. The 9.7 Ma Devine Canyon Tuff and the 7.1 Ma Rattlesnake Tuff also overlie the SV. The 15.9-15.4 Ma Dinner Creek Tuff is mid-Miocene, and clear stratigraphic relationships are found in areas where the tuff is intercalated between thick SV lava flows. All of the basalts of the SV are TH and are dominated by phenocryst-poor (≤2%) lithologies. These basalts have an ophitic texture dominated by plagioclase, clinopyroxene and olivine (often weathered to iddingsite). Basalts and basaltic andesites have olivine Fo #'s ranging from 44 at the rims (where weathered to iddingsite) and as high as 88 at cores. Pyroxene Mg #'s range from 65 to 85. Andesites of the SV are sub-alkaline, and like the basalts, are exceedingly phenocryst-poor (≤3%) with microphenocrysts of plagioclase and lesser pyroxene and olivine, which occasionally occur as crystal clots of ~1-3 mm instead of single crystals. In addition, minimal

  2. Lead and strontium isotopes in rocks of the Absaroka volcanic field, Wyoming

    USGS Publications Warehouse

    Peterman, Z.E.; Doe, B.R.; Prostka, H.J.

    1970-01-01

    The Absaroka volcanic field is comprised of predominant andesitic volcaniclastic rocks and less abundant potassium-rich mafic lavas (shoshonites and absarokites). Strontium and lead isotopic variations preclude a simple derivation from an isotopically uniform source: Sr87/Sr86, 0.7042 to 0.7090; Pb206/Pb204, 16.31 to 17.30; Pb208/Pb204, 36.82 to 37.64. We postulate that these rocks were derived from a lower crust or upper mantle which underwent a preferential loss of uranium relative to lead approximately 2800??200 m.y. ago. Variations in lead and strontium isotopic compositions are thought to reflect small inhomogeneities in U/Pb and Rb/Sr ratios in the source. ?? 1970 Springer-Verlag.

  3. Hydrogeology and hydrogeochemistry of an alkaline volcanic area: the NE Mt. Meru slope (East African Rift - Northern Tanzania)

    NASA Astrophysics Data System (ADS)

    Ghiglieri, G.; Pittalis, D.; Cerri, G.; Oggiano, G.

    2012-02-01

    The objective of this study is to analyze the geochemical conditions associated with the presence of fluoride (F-) in the groundwater of an area of Northern Tanzania. The studied aquifers are composed of volcanic rocks such as phonolitic and nephelinitic lavas, basalts, lahars of various ages and mantling ash. Sedimentary rocks consisting of fine-grained alluvial and lacustrine deposits occur as well. Samples collected from springs, borehole and surface water, during two monitoring surveys, were analyzed for the various physico-chemical and isotopic parameters. The geochemical composition of water is typically sodium bicarbonate. High values of F- (up to 68 mg l-1) were recorded. The highest values of fluoride agreed with the highest values of pH, sodium and bicarbonate. Dissolution of major ions, exchange processes and precipitation of Ca2+ from super-saturated solutions joined with the local permeability and hydraulic gradients, control the fluoride mobilization and the contamination of the area.

  4. Hydrogeology and hydrogeochemistry of an alkaline volcanic area: the NE Mt. Meru slope (East African Rift - Northern Tanzania)

    NASA Astrophysics Data System (ADS)

    Ghiglieri, G.; Pittalis, D.; Cerri, G.; Oggiano, G.

    2011-09-01

    The objective of this study is to analyze the geochemical conditions associated with the presence of fluoride (F-) in the groundwater of an area of Northern Tanzania. The studied aquifers are composed of volcanic rocks such as phonolitic and nephelinitic lavas, basalts, lahars of various ages and mantling ash. Sedimentary rocks consisting of fine-grained alluvial and lacustrine deposits occur as well. Samples collected from springs, borehole and surface water, during two monitoring surveys, were analyzed for the various physico-chemical and isotopic parameters. The geochemical composition of water is typically sodium bicarbonate. High values of F- (up to 68 mg l-1) were recorded. The highest values of fluoride agreed with the highest values of pH, sodium and bicarbonate. Dissolution of major ions, exchange processes and precipitation of Ca2+ from super-saturated solutions joined with the local permeability and hydraulic gradients, control the fluoride mobilization and the contamination of the area.

  5. Tertiary volcanic rocks and uranium in the Thomas Range and northern Drum Mountains, Juab County, Utah

    USGS Publications Warehouse

    Lindsey, David A.

    1982-01-01

    The Thomas Range and northern Drum Mountains have a history of volcanism, faulting, and mineralization that began about 42 m.y. (million years) ago. Volcanic activity and mineralization in the area can be divided into three stages according to the time-related occurrence of rock types, trace-element associations, and chemical composition of mineral deposits. Compositions of volcanic rocks changed abruptly from rhyodacite-quartz latite (42-39 m.y. ago) to rhyolite (38-32 m.y. ago) to alkali rhyolite (21 and 6-7 m.y. ago); these stages correspond to periods of chalcophile and siderophile metal mineralization, no mineralization(?), and lithophile metal mineralization, respectively. Angular unconformities record episodes of cauldron collapse and block faulting between the stages of volcanic activity and mineralization. The youngest angular unconformity formed between 21 and 7 m.y. ago during basin-and-range faulting. Early rhyodacite-quartz latite volcanism from composite volcanoes and fissures produced flows, breccias, and ash-flow tuff of the Drum Mountains Rhyodacite and Mt. Laird Tuff. Eruption of the Mt. Laird Tuff about 39 m.y. ago from an area north of Joy townsite was accompanied by collapse of the Thomas caldera. Part of the roof of the magma chamber did not collapse, or the magma was resurgent, as is indicated by porphyry dikes and plugs in the Drum Mountains. Chalcophile and siderophile metal mineralization, resulting in deposits of copper, gold, and manganese, accompanied early volcanism. Te middle stage of volcanic activity was characterized by explosive eruption of rhyolitic ash-flow tuffs and collapse of the Dugway Valley cauldron. Eruption of the Joy Tuff 38 m.y. ago was accompanied by subsidence of this cauldron and was followed by collapse and sliding of Paleozoic rocks from the west wall of the cauldron. Landslides in The Dell were covered by the Dell Tuff, erupted 32 m.y. ago from an unknown source to the east. An ash flow of the Needles Range

  6. Magmatic origin of alkaline meta-igneous rocks from Chamberlindalen, SW Svalbard

    NASA Astrophysics Data System (ADS)

    Goluchowska, Karolina; Barker, Abigail; Manecki, Maciej; Czerny, Jerzy; Majka, Jaroslaw

    2014-05-01

    This study focuses on the late Neoproterozoic meta-igneous rocks of SW Svalbard to determine their magmatic evolution, conditions of magma storage and origin. The samples from the Chamberlindalen area form an alkaline igneous suite, from which thin dikes and intrusive bodies have been collected. The rocks in question intrude Late Neoproterozoic metasediments and are surrounded by occurrences of Neoproterozoic metabasalts in contrast to highly alkaline the Chamberlindalen intrusions. The rocks from Chamberlindalen are divided into two groups based on their geochemistry, mineralogy and field relationships. The dikes, classify as minettes, belonging to the lamprophyre group and contain mainly euhedral, elongated phlogopite and additionally clinopyroxene and feldspar. The rest of the samples are highly magnesian and are classified as alkali gabbro. The alkali gabbros contain primary magmatic minerals such as clinopyroxene, calcic amphibole and mica in different proportions. The alkali gabbros are enriched in LREE and HFSE and depleted in P, K and HREE. The minette dikes are always more enriched in HFSE and REE in comparison to the alkali gabbros. The mineral chemistry of the alkali gabbros reveals that pyroxenes are represented by diopside with Wo46-51 En35-46 Fs6-14, and calcic amphibole by kaersutite. The Mg# number for diopside is from 72 - 88, whereas for kaersutite Mg# number is 51 - 74. Thermobarometry calculations for diopside and kaersutite have been performed. In the alkali gabbros from Chamberlindalen, diopside crystallized between 0.7 - 8 kbar and 1152 - 1233°C. Results for kaersutite reveal that they crystallized between 5 - 17 kbar and 1043 - 1215°C. For diopside the main crystallization was between 10 and 38 km, whereas for kaersutite, the main crystallization was between 30 and 50 km. Clinopyroxene and minor kaersutite also show a zone of crystallization at 2 to 10 km. This reflects a main crystallization zone at 10 - 50 km throughout the continental

  7. The occurrence of a complete continental rift type of volcanic rocks suite along the Yerer-Tullu Wellel Volcano Tectonic Lineament, Central Ethiopia

    NASA Astrophysics Data System (ADS)

    Abebe Adhana, Tsegaye

    2014-11-01

    The Yerer-Tullu Wellel Volcano-tectonic Lineament (YTVL) is an E-W trending fault system or aborted rift that intercepts the Main Ethiopian Rift (MER) at Debre Zeyt (Bishoftu)/Yerer, in the eastern periphery of Addis Ababa. The structure is in correspondence with the westward extension of the southern margin of the Gulf of Aden rift. The YTVL extends for more than 500 km with a very clear northern fault margin, between Addis Ababa and Ambo known as the “Ambo Fault”. The southern margin is indicated by an E-W trending segmented lineaments at the latitude of about N 8°30‧, the Bedele-Metu being the most clear segment. In between these limits there are several evolved central volcanoes and cinder cones. The central volcanoes range in age from 12 to 7 Ma in the western most (Tullu Wellel) and gradually the upper limit get younger towards East to less than 1 Ma in the Wenchi and Debre Zeyt (Bishoftu) areas. These volcanic products cover the whole spectrum of a continental rift volcanic rocks suite: (1) in the eastern zone (Yerer-Bishoftu) the suite is silica over-saturated, ranging in composition from transitional basalt to peralkaline rhyolite, (2) moving westwards, between Wechacha and Wenchi, the rocks suite is silica saturated ranging in composition from alkali basalt to trachyte, (3) further West between Ijaji-Konchi and Nekemt the rocks suite is silica under-saturated ranging in composition from basanite to phonolite. Crossing the Dedessa lineament, the Tullu Wellel rocks appear to be silica saturated. Within a single suite fractional crystallization is the predominant evolutional process even in the silica over-saturated suite. The westwards progressive silica under-saturation and increase in alkalinity (except for the Tullu Wellel volcanic centers) is interpreted by the gradual deepening of an anomalous mantle where partial fusion took place. Therefore, as distance increases from the MER junction to the West, the amount of melt on the upper mantle was

  8. Preliminary Numerical Simulations of Nozzle Formation in the Host Rock of Supersonic Volcanic Jets

    NASA Astrophysics Data System (ADS)

    Wohletz, K. H.; Ogden, D. E.; Glatzmaier, G. A.

    2006-12-01

    Recognizing the difficulty in quantitatively predicting how a vent changes during an explosive eruption, Kieffer (Kieffer, S.W., Rev. Geophys. 27, 1989) developed the theory of fluid dynamic nozzles for volcanism, utilizing a highly developed predictive scheme used extensively in aerodynamics for design of jet and rocket nozzles. Kieffer's work shows that explosive eruptions involve flow from sub to supersonic conditions through the vent and that these conditions control the erosion of the vent to nozzle shapes and sizes that maximize mass flux. The question remains how to predict the failure and erosion of vent host rocks by a high-speed, multiphase, compressible fluid that represents an eruption column. Clearly, in order to have a quantitative model of vent dynamics one needs a robust computational method for a turbulent, compressible, multiphase fluid. Here we present preliminary simulations of fluid flowing from a high-pressure reservoir through an eroding conduit and into the atmosphere. The eruptive fluid is modeled as an ideal gas, the host rock as a simple incompressible fluid with sandstone properties. Although these simulations do not yet include the multiphase dynamics of the eruptive fluid or the solid mechanics of the host rock, the evolution of the host rock into a supersonic nozzle is clearly seen. Our simulations show shock fronts both above the conduit, where the gas has expanded into the atmosphere, and within the conduit itself, thereby influencing the dynamics of the jet decompression.

  9. A Comprehensive Study on Dielectric Properties of Volcanic Rock/PANI Composites

    NASA Astrophysics Data System (ADS)

    Kiliç, M.; Karabul, Y.; Okutan, M.; İçelli, O.

    2016-05-01

    Basalt is a very well-known volcanic rock that is dark colored and relatively rich in iron and magnesium, almost located each country in the world. These rocks have been used in the refused rock industry, to produce building tiles, construction industrial, highway engineering. Powders and fibers of basalt rocks are widely used of radiation shielding, thermal stability, heat and sound insulation. This study examined three different basalt samples (coded CM-1, KYZ-13 and KYZ-24) collected from different regions of Van province in Turkey. Polyaniline (PANI) is one of the representative conductive polymers due to its fine environmental stability, huge electrical conductivity, as well as a comparatively low cost. Also, the electrical and thermal properties of polymer composites containing PANI have been widely studied. The dielectric properties of Basalt/Polyaniline composites in different concentrations (10, 25, 50 wt.% PANI) have been investigated by dielectric spectroscopy method at the room temperature. The dielectric parameters (dielectric constants, loss and strength) were measured in the frequency range of 102 Hz-106 Hz at room temperature. The electrical mechanism change with PANI dopant. A detailed dielectrically analysis of these composites will be presented.

  10. Origin and accumulation mechanisms of petroleum in the Carboniferous volcanic rocks of the Kebai Fault zone, Western Junggar Basin, China

    NASA Astrophysics Data System (ADS)

    Chen, Zhonghong; Zha, Ming; Liu, Keyu; Zhang, Yueqian; Yang, Disheng; Tang, Yong; Wu, Kongyou; Chen, Yong

    2016-09-01

    The Kebai Fault zone of the West Junggar Basin in northwestern China is a unique region to gain insights on the formation of large-scale petroleum reservoirs in volcanic rocks of the western Central Asian Orogenic Belt. Carboniferous volcanic rocks are widespread in the Kebai Fault zone and consist of basalt, basaltic andesite, andesite, tuff, volcanic breccia, sandy conglomerate and metamorphic rocks. The volcanic oil reservoirs are characterized by multiple sources and multi-stage charge and filling history, characteristic of a complex petroleum system. Geochemical analysis of the reservoir oil, hydrocarbon inclusions and source rocks associated with these volcanic rocks was conducted to better constrain the oil source, the petroleum filling history, and the dominant mechanisms controlling the petroleum accumulation. Reservoir oil geochemistry indicates that the oil contained in the Carboniferous volcanic rocks of the Kebai Fault zone is a mixture. The oil is primarily derived from the source rock of the Permian Fengcheng Formation (P1f), and secondarily from the Permian Lower Wuerhe Formation (P2w). Compared with the P2w source rock, P1f exhibits lower values of C19 TT/C23 TT, C19+20TT/ΣTT, Ts/(Ts + Tm) and ααα-20R sterane C27/C28 ratios but higher values of TT C23/C21, HHI, gammacerane/αβ C30 hopane, hopane (20S) C34/C33, C29ββ/(ββ + αα), and C29 20S/(20S + 20R) ratios. Three major stages of oil charge occurred in the Carboniferous, in the Middle Triassic, Late Triassic to Early Jurassic, and in the Middle Jurassic to Late Jurassic periods, respectively. Most of the oil charged during the first stage was lost, while moderately and highly mature oils were generated and accumulated during the second and third stages. Oil migration and accumulation in the large-scale stratigraphic reservoir was primarily controlled by the top Carboniferous unconformity with better porosity and high oil enrichment developed near the unconformity. Secondary dissolution

  11. Geochemical and isotopic composition of volcanic rocks of the heterogeneous Miocene (~ 23-19 Ma) Tepoztlán Formation, early Transmexican Volcanic Belt, Mexico

    NASA Astrophysics Data System (ADS)

    Torres-Alvarado, Ignacio S.; Lenhardt, Nils; Arce, José Luis; Hinderer, Matthias

    2016-04-01

    We present the first geochemical data (major and trace elements, as well as Sr, Nd, and Pb isotopes) on volcanic rocks from the Tepoztlán Formation in the central Transmexican Volcanic Belt. The Tepoztlán Formation is up to 800 m thick and comprises a wide range of primary volcanic rocks (lavas, pyroclastic density current deposits, pyroclastic fall deposits), and their secondary reworked products due to mass flow (lahars) and fluvial processes. Magnetostratigraphy combined with K/Ar and Ar/Ar geochronology suggests an age of Early Miocene (23-19 Ma) for this Formation. Lava flows, pyroclastic rocks, dykes and volcanic clasts range from basaltic andesite to rhyolite, with a clear dominance of andesites and dacites. All samples are subalkaline and hy-normative. These rocks show homogeneous REE patterns with LREE enrichment and higher LILE concentrations with respect to HFSE, notably the typical negative anomaly of Nb, Ta, and Ti, suggesting a subduction-related magma genesis. Major and trace element concentrations show that either assimilation of heterogeneous continental crust or crustal recycling by subduction erosion and fractional crystallization are important processes in the evolution of the Tepoztlán Formation magmas. Isotopic compositions of the Tepoztlán Formation samples range from (87Sr/86Sr)t = 0.703693 to 0.704355 and (143Nd/144Nd)t = 0.512751 to 0.512882, falling within the mantle array. All geochemical characteristics indicate that these rocks originated from a heterogeneous mantle, modified and evolved through assimilation of country rock and fractional crystallization in the upper crust.

  12. Tectonic implications of paleomagnetic poles from Lower Tertiary Volcanic Rocks, south central Alaska

    NASA Astrophysics Data System (ADS)

    Hillhouse, John W.; Grommé, C. Sherman; Csejtey, Bela, Jr.

    1985-12-01

    We have determined the paleolatitude of lower Tertiary volcanic rocks in southern Alaska to measure possible poleward translation of the Wrangellia and the Peninsular terranes after 50 m.y. ago. Previous paleomagnetic studies have shown that in Triassic and Jurassic time these terranes were located near the equator and have moved at least 3000 km poleward relative to the North American craton. Our sample localities are in the northern Talkeetna Mountains in mildly deformed andesite and dacite flows (50.4, 51.3, 53.9, and 56.3 m.y. by K-Ar) that overlap Lower Cretaceous flysch, Lower Permian volcanic rocks of Wrangellia, and Upper Triassic pillow basalt of the Susitna terrane. Results from 26 cooling units (23 of reversed polarity and 3 of normal polarity) give a mean paleomagnetic pole at 69.5°N, 179.6°E, α95 = 12.2°. Stratigraphic sections from opposite limbs of a syncline yield directional paths that pass the fold test, satisfying a necessary condition for primary origin of the magnetization. The corresponding mean paleolatitude (76°N) of the northern Talkeetna Mountains is 8°±10° higher than the latitude predicted from the Eocene reference pole for North America. Therefore, northward drift of the Talkeetna superterrane, which is the amalgamation of the Wrangellia and Peninsular terranes during and after Middle Jurassic time, was probably complete by 50 m.y. ago. Our results are consistent with paleomagnetic poles from uppermost Cretaceous and Paleocene volcanic sequences in Denali National Park, the Lake Clark region, northern Bristol Bay region, and near McGrath. These poles generally lie south of the cratonic poles, suggesting that the region between the Kaltag, Bruin Bay, and Castle Mountain faults has rotated counterclockwise relative to North America since the early Eocene.

  13. Lichen-rock interaction in volcanic environments: evidences of soil-precursor formation

    NASA Astrophysics Data System (ADS)

    Vingiani, S.; Adamo, P.; Terribile, F.

    2012-04-01

    , according to the young age of the basaltic lava the recent lichen colonization results in a physical reorganization and chemical modification of the interface materials, which are not necessarily produced by the lichen action on the rock substrate. In volcanic environment, the ability of lichens to retain considerable amount of unconsolidated material, which becomes mixed with organic matter, produced by decomposition of the thallus, and trap atmospheric dust may contribute to the andosolization process. Accumulation of Al and Fe, found at the rock-lichen interface likely as organo-metal complexes, can be considered initial stage of Al and Fe active phases formation, distinguishing features of Andosols development. The simple chelating oxalic acid, produced by the lichens, may be involved in the formation of organo-metal complexes.

  14. The Fukuyama volcanic rocks: Submarine composite volcano in the Late Miocene to Early Pliocene Akita-Yamagata back-arc basin, northeast Honshu, Japan

    NASA Astrophysics Data System (ADS)

    Yagi, Masahiko; Ohguch, Takeshi; Akiba, Fumio; Yoshida, Takeyoshi; Tiba, Tokiko

    2009-10-01

    The Fukuyama Volcanic Rocks are composed of pyroxene andesite (FKV-1), hornblende-pyroxene andesite (FKV-2), biotite-hornblende dacite (FKV-3) and volcaniclastic debris-flow deposits and/or turbidites. FKV-1, FKV-2 and FKV-3 are medium-K calc-alkaline rocks depleted in Nd, similar to other back-arc volcanic rocks of the northeast Japan arc and constitute a dome cluster at Fukuyama. Volcaniclastic beds surround the dome cluster and thin and fine upwards. The predominant clast type in the volcaniclastic beds changes upwards from pyroxene andesite, through hornblende-pyroxene andesite, to biotite-hornblende dacite, consistent with the stratigraphic relationships of FKV-1, FKV-2 and FKV-3 lavas. All the siltstones inter-bedded with the volcaniclastic beds and overlying the whole succession contain diatom fossils indicative of the lower part of the Thalassionema schraderi zone (7.8 Ma to 8.5 Ma), compatible with the isotopic ages of FKV-1, FKV-2 and FKV-3. The Fukuyama volcano has a total eruption volume of 60-100 km 3, with a lifetime of the order of 10 5 years, as typically observed for volcanoes in the present back-arc region of northeast Honshu. FKV-1 erupted in deep water and partly disintegrated into hyaloclastite breccias due to direct contact with water. FKV-2 lava repeatedly effused over the FKV-1 lava and produced a volcanic apron of breccias that eventually grew above wave base and was eroded by wave action. The magma of FKV-3 was probably hydrous as it contains biotite and hornblende. The FKV-3 magma could have explosively erupted from a shallow-water dome or vent emergent above the wave base, followed by growth of a degassing lava dome. Repose between eruptions allowed accumulation of silt, and after the Fukuyama eruptions ceased silt entirely mantled the volcano. A small magma supply rate perhaps allowed a relatively long period of quiescence between eruptions of FKV-1, FKV-2 and FKV-3 magmas, resulting in abrasion and reworking of volcanic fragments and

  15. Geochemistry of the Yangla volcanic rocks and its relationship to Cu mineralization in the Yangla copper deposit, western Yunnan, China

    NASA Astrophysics Data System (ADS)

    Yang, Xian; Liu, Jiajun; Zhai, Degao; Han, Siyu; Wang, Huan; Yang, Longbo; Huo, Dongliang

    2012-10-01

    The Yangla copper deposit is a recently discovered, giant copper deposit with an estimated Cu reserve of about 1,200,000 tons. Development is now underway. Previous studies have reported that the Yangla copper deposit is a VMS-type deposit related to the Yangla volcanic rocks. Volcanic bulk-rock analyses shows high contents of Si (49.3%-58.7%), Na2O (Na2O = 3.3%-4.9%), MgO (MgO = 3.7%-8.6%), and CaO(CaO = 6.8%-9.0%), low TiO2 (TiO2 = 0.9%-2.1%) and K2O(K2O = 0.2%-1.4%) contents. The geochemistry of the volcanic represent forearc basalts. Four molybdenites samples from the ore bodies in the deposit yield Re-Os model ages ranging from 229.7 ± 3.3 Ma to 233 ± 3.4 Ma. The REE distribution patterns and the primitive-mantle-normalized trace element patterns of the volcanic rocks are similar to the ores, indicating the Yangla copper deposit are closely associated with the Yangla volcanic rocks. The results contribute to our understanding of the genesis of the Yangla copper deposit and will guide further exploration in the region.

  16. Xenoliths of mafic/ultramafic igneous rocks as carriers of information on lower crust beneath Złotoryja - Jawor volcanic complex (SW Poland).

    NASA Astrophysics Data System (ADS)

    Dajek, Michał; Matusiak-Malek, Magdalena; Puziewicz, Jacek; Lipa, Danuta; Ntaflos, Theodors

    2016-04-01

    The Cenozoic alkaline volcanic rocks in Lower Silesia (SW Poland) are known for their mantle peridotite xenoliths. However, the mafic and ultramafic xenoliths with cumulative textures and of composition of olivine- or hornblende clinopyroxenite, clinopyroxenite, websterite, norite and gabbro occur in some of the lavas (6 sites) of the Złotoryja-Jawor volcanic complex. The xenoliths are anhydrous, only in Wilcza Góra minor amount of amphibole occurs. The Mg# of clinopyroxene varies from 0.54 (Ostrzyca Proboszczowicka clinopyroxenite) to 0.89 (Góra Świątek clinopyroxenite). Forsterite content in olivine varies from 64% (Winna Góra gabbro) to 86% (Wilcza Góra hornblende clinopyroxenite). Anortite content in plagioclase in nortite and gabbros is 33-56%. The Mg# in amphibole is 0.43 to 0.76. Clinopyroxene trace element composition is typically LREE enriched, but in Wilcza Góra norite and Mnisza Góra clinopyroxenite it is LREE-depleted. The calculated pressures of clinopyroxene crystallization (calculated by the algorithm of Nimis and Ulmer, 1998, CMP, 1998, 122-135, assuming all Fe to be 2+) is from 0.45 to 0.96 GPa pointing to crystallization of the pyroxenitic rocks in lower crust or at crust/mantle boundary. Theoretical melts in equilibrium with clinopyroxene enriched in LREE resemble the alkaline lavas from the area and we suggest they are cognate with host magmas. We explain variations in composition of mafic xenoliths from Wilcza Góra, Winna Góra and Grodziec to be a result of magma fractionation. Xenoliths containing clinopyroxene impoverished in LREE may represent lithologies inherited from Variscan oceanic crust. Megacrysts of clinopyroxene present in some of the localities cannot result from disintegration of mafic xenoliths This study was possible thanks to project NCN UMO-2014/15/B/ST10/00095 of Polish National Centre for Science.

  17. A preliminary evaluation of volcanic rock powder for application in agriculture as soil a remineralizer.

    PubMed

    Ramos, Claudete G; Querol, Xavier; Oliveira, Marcos L S; Pires, Karen; Kautzmann, Rubens M; Oliveira, Luis F S

    2015-04-15

    Mineralogical and geochemical characteristics of volcanic rock residue, from a crushing plant in the Nova Prata Mining District, State of Rio Grande do Sul (RS), Brazil, in this work named rock powder, were investigated in view of its potential application as soil ammendment in agriculture. Abaut 52,400 m(3) of mining waste is generated annually in the city of Nova Prata without a proper disposal. The nutrients potentially available to plants were evaluated through leaching laboratory tests. Nutrient leaching tests were performed in Milli-Q water; citric acid solution 1% and 2% (AC); and oxalic acid solution 1% and 5% (AO). The bulk and leachable contents of 57 elements were determined by inductively coupled plasma mass spectrometry (ICP-MS) and inductively coupled plasma atomic emission spectroscopy (ICP-AES). Mining waste were made up by CaO, K2O, SiO2, Al2O3, Fe2O3, and P2O5. The analysis by X-ray diffraction (XRD) showed the major occurence of quartz, anorthite, cristobalite, sanidine, and augite. The water leachable concentrations of all elements studied were lower than 1.0mg/kg, indicating their low solubility. Leaching tests in acidic media yield larger leachable fractions for all elements being studied are in the leachate of the AO 1%. These date usefulness of volcanic rock powder as potential natural fertilizer in agriculture in the mining district in Nova Prata, Rio Grande do Sul, Brazil to reduce the use of chemical fertilizers. PMID:25638652

  18. Increasing Interaction of Alkaline Magmas with Lower Crustal Gabbroic Cumulates over the Evolution of Mt. Taylor Volcanic Field, New Mexico

    NASA Astrophysics Data System (ADS)

    Schmidt, M. E.; Crumpler, L. S.; Schrader, C.

    2010-12-01

    The Mount Taylor Volcanic Field at the southeastern edge of the Colorado Plateau, New Mexico erupted diverse alkaline magmas from ~3.8 to 1.5 Ma (Crumpler, 1980; Perry et al., 1990). The earliest eruptions include high silica topaz rhyolites of Grants Ridge (plagioclase, quartz, biotite) and Si-under saturated basanites and trachytes at Mt Taylor stratovolcano. Mt. Taylor was later constructed of stacks of thick, trachyandesitic to rhyolitic lava flows that were subsequently eroded into a ~4-km across amphitheatre opening toward the southeast. Early Mt. Taylor rhyolitic lavas exposed within the amphitheatre contain quartz, plagioclase, hornblende, and biotite (± sanidine) phenocrysts. Later cone-building trachydacite to trachyandesite lavas are crystal-rich with plagioclase and augite megacrysts (± hornblende, ± quartz) and record an overall trend of decreasing SiO2 with time. The last eruptions ~1.5 Ma from the stratovolcano (Perry et al. 1990) produced thick (>70 m), viscous lava flows that contain up to 50% zoned plagioclase phenocrysts. While SiO2 decreased among the silicic magmas, the degree of silica saturation increased among peripheral basaltic magmas from basanite to ne-normative hawaiite to hy-normative basalts. Evidence of increasing crustal contamination within the basalts includes zoned plagioclase megacrysts, augite and plagioclase cumulate texture xenoliths with accompanying xenocrysts. These textures within the basalts combined with abundant, complex plagioclase among the cone-building silicic magmas imply interaction and mixing with gabbroic cumulate mush in the lower crust beneath Mt. Taylor Volcano. Contemporaneous basanitic to trachytitc volcanism in the northern part of the volcanic field at Mesa Chivato (Crumpler, 1980) was more widely distributed, smaller volume, and produced mainly aphyric magmas. The lower crustal gabbroic cumulates either do not extend northward beneath Mesa Chivato, or they were not accessed by lower magma flux rate

  19. Generation of early Archaean felsic greenstone volcanic rocks through crustal melting in the Kaapvaal, craton, southern Africa

    NASA Astrophysics Data System (ADS)

    Kröner, Alfred; Elis Hoffmann, J.; Xie, Hangqiang; Wu, Fuyuan; Münker, Carsten; Hegner, Ernst; Wong, Jean; Wan, Yusheng; Liu, Dunyi

    2013-11-01

    High-potassium felsic volcanic rocks interlayered with basalt and komatiite in early Archaean greenstone sequences in the Barberton Greenstone Belt of South Africa and Swaziland, previously considered to be derived from melting of mafic precursors, are shown to be the result of melting of significantly older felsic crust. This is documented by a combination of SHRIMP zircon dating with Hf-in-zircon and whole-rock Lu-Hf and Sm-Nd isotopic data. Zircons from felsic rocks of the oldest Barberton unit, the 3.53 Ga Theespruit Formation, yielded predominantly negative ɛ-values, whereas whole-rock ɛ- and ɛ-data are slightly negative to slightly positive. Similar results were obtained for ca. 3.45 Ga felsic rocks in the Hoeggenoog and Noisy Formations higher up in the greenstone stratigraphy. These data rule out derivation of the felsic units from melting of basaltic precursors and favor a crustal source, most likely of TTG composition. The isotopic data are not compatible with an entirely oceanic origin of the Barberton greenstone sequences and favor a pre-greenstone basement beneath the volcanic rocks. Crustal melting of Eo- to Paleoarchaean lower crust probably generated the felsic volcanic rocks and is likely to have been responsible for gradual stabilization of the Kaapvaal craton.

  20. Petrogenesis of late Paleozoic volcanic rocks from the Daheshen Formation in central Jilin Province, NE China, and its tectonic implications: Constraints from geochronology, geochemistry and Sr-Nd-Hf isotopes

    NASA Astrophysics Data System (ADS)

    Yu, Qian; Ge, Wen-Chun; Yang, Hao; Zhao, Guo-Chun; Zhang, Yan-Long; Su, Li

    2014-04-01

    We present geochronological, geochemical, whole-rock Sr-Nd and zircon Hf-isotopic data for late Paleozoic volcanic rocks from the Daheshen Formation in central Jilin Province, northeastern China, and constrain the petrogenesis of the volcanic rocks and late Paleozoic tectonic evolution of the northern margin of the Northern China Craton, which is regarded as the eastern segment of the Central Asian Orogenic Belt (CAOB). Lithologically, the Daheshen Formation is composed mainly of rhyolite, rhyolitic tuff, dacite and andesite, with minor basalt. The zircons from three rhyolites, two dacites, one rhyolitic tuff and one basalt are euhedral-subhedral, display oscillatory zoning and have high Th/U ratios (0.50-2.28), implying a magmatic origin. LA-ICP-MS zircon U-Pb age data indicate that the volcanic rocks from the Daheshen Formation formed during Late Carboniferous-Early Permian time (302-299 Ma). Geochemically, late Paleozoic volcanic rocks have SiO2 = 52.13-81.77 wt.% and K2O = 0.86-6.88 wt.%, belonging to mid-K to high-K calc-alkaline series. These rocks are characterized by enrichment in large ion lithophile elements (LILEs) and light rare earth elements (LREEs), and depletion in high field strength elements (HFSEs, such as Nb, Ta, and Ti) and heavy rare earth elements (HREEs), with affinities to igneous rocks forming in an active continental margin setting. All volcanic rocks have depleted Nd isotopic compositions (ɛNd(t) = + 2.4 to + 2.5 for the basalts and + 5.8 to + 7.1 for the andesites and dacites, respectively). In situ Hf isotopic results of zircon from the rhyolites show that they have ɛHf(t) = - 1.1 to + 10.6. All these geochemical features indicate that the andesites, dacites, and rhyolites likely originated from the partial melting of Meso-Neoproterozoic accreted lower crust (Hf and Nd model ages (TDM2) of 1384-662 Ma and 1061-800 Ma, respectively). In contrast, the basalts were derived from the partial fusion of a depleted lithospheric mantle that

  1. The volcanic-subvolcanic rocks of the fernando de noronha archipelago, southern atlantic ocean: Mineral chemistry

    NASA Astrophysics Data System (ADS)

    Lopes, Rosana Peporine; Ulbrich, Mabel N. Costas; Ulbrich, Horstpeter

    2014-12-01

    Fernando de Noronha archipelago presents an older Remédios Formation with subvolcanic intrusions, belonging to two different alkaline series, the sodic (undersaturated: basanites, tephrites, essexites, tephriphonolites, phonolites), and potassic ones (mildly undersaturated to silicic, with alkali basalts, basaltic trachyandesites, trachyandesites, trachytes), and lamprophyres. The upper Quixaba Formation presents nephelinite flows and basanites. A third minor unit, São José, is constituted by basanites carrying mantle xenoliths. Magnesian olivines occur in the Remédios basanites and alkali basalts, and in nephelinites. Melilites are present as groundmass grains in melilite melanephelinites (MEM). Clinopyroxenes (cpx) are mostly salites to titaniferous salites (Remédios sodic series), grading into aegirines in the differentiated aphyric phonolites. Cpx in the lamprophyres show disequilibrium textures. In the Quixaba flows, cpx are salites, enriched in Mg (especially in MEM). Amphiboles, remarkably, are common in tephriphonolites and phonolites and in basaltic trachyandesites, sometimes with disequilibrum zoning textures, and a conspicuous phase in lamprophyres. Dark micas are present as groundmass plates in MEM, OLM and PYM (olivine and pyroxene melanephelinites), with compositional variety (enriched in Ti, Ba, Sr) depending on the composition of the parent rock; BaO can be as high as 16-19%. Feldspars crystallize as calcic plagioclases, sanidines and anorthoclases, depending on the rock types, as phenocrysts and in groundmass, both in Quixaba and Remédios rocks; they are absent in nephelinites. Nephelines are found in Remédios sodic series types and Quixaba rocks. Haüyne and noseane are rarely observed in Remédios rocks.

  2. Zeolite stability constraints on radioactive waste isolation in zeolite-bearing volcanic rocks

    SciTech Connect

    Smyth, J.R.

    1982-12-31

    Silicic tuffs of the southern Great Basin and basalts of the Columbia River Plateau are under investigation as potential host rocks for high- and intermediate-level radioactive wastes. Non-welded and partially welded tuffs may contain major amounts (> 50%) of the zeolite minerals: clinoptilolite, mordenite, and analcime. Densely welded tuffs and some basalt flows may contain clinoptilolite as fracture filling which limits permeability of these rocks. The cation exchange properties of these zeolite minerals allow them to pose a natural barrier to the migration of cationic species of various radionuclides in aqueous solutions. However, these minerals are unstable at elevated temperatures and at low water vapor pressures, and they may break down either by reversible dehydration or by irreversible mineralogical reactions. All of the breakdown reactions occurring with increased temperature involve a net volume reduction and evolution of fluids. Thus, they may provide both a pathway (shrinkage fractures) and a driving force (fluid pressure) for release of radionuclides to the biosphere. These reactions may be avoided by keeping zeolite-bearing horizons saturated with water and below about 85{sup 0}C. This may restrict allowable gross thermal loadings in radioactive waste repositories in zeolite-bearing volcanic rocks. 3 figures.

  3. Textural and Mineralogical Analysis of Volcanic Rocks by µ-XRF Mapping.

    PubMed

    Germinario, Luigi; Cossio, Roberto; Maritan, Lara; Borghi, Alessandro; Mazzoli, Claudio

    2016-06-01

    In this study, µ-XRF was applied as a novel surface technique for quick acquisition of elemental X-ray maps of rocks, image analysis of which provides quantitative information on texture and rock-forming minerals. Bench-top µ-XRF is cost-effective, fast, and non-destructive, can be applied to both large (up to a few tens of cm) and fragile samples, and yields major and trace element analysis with good sensitivity. Here, X-ray mapping was performed with a resolution of 103.5 µm and spot size of 30 µm over sample areas of about 5×4 cm of Euganean trachyte, a volcanic porphyritic rock from the Euganean Hills (NE Italy) traditionally used in cultural heritage. The relative abundance of phenocrysts and groundmass, as well as the size and shape of the various mineral phases, were obtained from image analysis of the elemental maps. The quantified petrographic features allowed identification of various extraction sites, revealing an objective method for archaeometric provenance studies exploiting µ-XRF imaging. PMID:27160144

  4. Constraints on the Jurassic time scale by /sup 40/Ar//sup 39/Ar dating of North Caucasian volcanic rocks

    SciTech Connect

    Hess, J.C.; Lippolt, H.J.; Borsuk, A.M.

    1987-07-01

    /sup 40/Ar//sup 39/Ar age measurements on biotites and high-temperature plagioclases of Jurassic basaltic to rhyolitic subvolcanic rocks from the Northern Great Caucasus (USSR) yielded plateau and total argon ages between 190 and 180 Ma. The dated rocks are intrusive sills, dikes and laccoliths in sediments of the middle to upper Pliensbachian and of the lower Toarcian (Lower Jurassic). Pebbles of the volcanic rocks exist in the basal conglomerates of the Aalenian (base of the Middle Jurassic). Thus, their stratigraphic age is restricted to the Lower Jurassic stages of middle to upper Pliensbachian and Toarcian. Because of the scarcity of tie-points in the Lower Jurassic, the isotopic ages of these volcanic rocks, in spite of their rather large stratigraphic range, may serve as new calibration points for the improvement of the Jurassic time-scale.

  5. Kaersutite-bearing xenoliths and megacrysts in volcanic rocks from the Funk Seamount in the souhtwest Indian Ocean

    NASA Technical Reports Server (NTRS)

    Reid, Arch M.; Le Roex, Anton P.

    1988-01-01

    The petrography, mineral chemistry, and whole-rock compositions of volcanic rocks dredged from the Funk Seamount, located 60 km NW of Marion Island in the southwestern Indian Ocean, are presented together with the mineral chemistry of their inclusions. On the basis of these characteristics, the possible relationships between the Funk Seamount's volcanic rocks and the megacrysts and xenoliths in these rocks are discussed. It is argued that the Funk Seamount lavas derive from a similar mantle source region as that of the Marion Island and Prince Edward Island hotspot lavas. The geochemical signature of these lavas implies derivation from a source that is enriched (e.g., in Ti, K, P, and Nb) over the depleted mantle source regions for the adjacent mid-ocean ridge basalts.

  6. Late Triassic Batang Group arc volcanic rocks in the northeastern margin of Qiangtang terrane, northern Tibet: partial melting of juvenile crust and implications for Paleo-Tethys ocean subduction

    NASA Astrophysics Data System (ADS)

    Zhao, Shao-Qing; Tan, Jun; Wei, Jun-Hao; Tian, Ning; Zhang, Dao-Han; Liang, Sheng-Nan; Chen, Jia-Jie

    2015-03-01

    The Batang Group (BTG) volcanic rocks in the Zhiduo area, with NW-trending outcrops along the northeastern margin of the Qiangtang terrane (northern Tibet), are mainly composed of volcaniclastic rocks, dacite and rhyolite. Major and trace element, Sr and Nd isotope, zircon U-Pb and Hf isotope data are presented for the BTG dacites. Laser ablation inductively coupled plasma mass spectrometry zircon U-Pb dating constrains the timing of volcanic eruption as Late Triassic (221 ± 1 Ma). Major and trace element geochemistry shows that the BTG volcanic rocks are classified as calc-alkaline series. All samples are enriched in large-ion lithophile elements and light rare earth elements with negative-slightly positive Eu anomalies (Eu/Eu* = 0.47-1.15), and depleted in high field strength elements and heavy rare earth elements. In addition, these rocks possess less radiogenic Sr [(87Sr/86Sr) i = 0.7047-0.7078], much radiogenic Nd (ɛNd( t) = -4.2 to -1.3) and Hf (ɛHf( t) = 4.0-6.6) isotopes, suggesting that they probably originated from partial melting of a crustal source containing a mantle-derived juvenile component. The inferred magma was assimilated by crustal materials during ascending and experienced significant fractional crystallization. By combining previously published and the new data, we propose that the BTG volcanic rocks were genetically related to southwestward subduction of the Ganzi-Litang ocean (a branch of Paleo-Tethys) in the northeastern margin of the Qiangtang terrane. Given the coeval arc-affinity magmatic rocks in the region, we envisage that the Ganzi-Litang ocean may extend from the Zhongdian arc through the Yidun terrane to the Zhiduo area, probably even further northwest to the Tuotuohe area.

  7. Geology and geochemistry of high-grade, volcanic rock-hosted, mercury mineralisation in the Nuevo Entredicho deposit, Almadén district, Spain

    NASA Astrophysics Data System (ADS)

    Jébrak, Michel; Higueras, Pablo L.; Marcoux, Éric; Lorenzo, Saturnino

    2002-06-01

    The Nuevo Entredicho deposit contains the richest concentration of mercury in the Almadén district, locally grading as much as 45% Hg. This ore deposit is hosted within an alkaline, conically shaped diatreme, about 150 m in diameter, which was subsequently filled with phreatomagmatic breccias. The diatreme cuts an Ordovician to Silurian clastic sedimentary rock sequence that is intercalated with basaltic sills. Structural analysis reveals a complex tectonic history with three main phases of Hercynian deformation. Mineralisation occurs as cinnabar replacements in volcanic tuffs and breccias and as recrystallised veins in tensions cracks associated with pyrophyllite and hydrothermal pyrite, which is strongly enriched in Cu, Pb and Hg. Lead isotopes in pyrite are characterised by high 207Pb/204Pb ratios (15.70-15.75), suggesting a contribution of ancient upper continental crust remobilised by Silurian-Devonian volcanism, with no mantle involvement. Sulphur isotopes of epigenetic cinnabar and pyrite range from +10.3 to +10.8‰ and from +10.6 to +11.9‰ respectively, suggesting a uniform sulphur source or a constant mixing ratio in the ore fluids. These isotopic compositions differ from those measured in the syngenetic deposits of the Almadén district; they suggest a higher temperature of ore formation of about 300 °C, and a genesis related to a distinct hydrothermal flow path at the Nuevo Entredicho deposit. Deposition of anomalously high-grade mercury ore at Nuevo Entredicho is related to a combination of (1) an abundance of black shale that provided sulphur and increasingly reducing conditions with high sulphide/sulphate ratios, (2) explosive Silurian-Devonian mafic magmatism that provided an initial source of mercury, (3) tectonic activity that lead to structurally favourable sites for ore deposition, and (4) replacement of secondary, carbonate-rich volcanic rocks.

  8. Nature and origin of mineral coatings on volcanic rocks of the Black Mountain, Stonewall Mountain, and Kane Springs Wash volcanic centers, Southern Nevada

    NASA Technical Reports Server (NTRS)

    Taranik, James V.; Hsu, Liang C.; Spatz, David

    1988-01-01

    Comparative lab spectra and Thematic Mapper imagery investigations at 3 Tertiary calderas in southern Nevada indicate that desert varnish is absorbant relative to underlying host rocks below about 0.7 to 1.3 microns, depending on mafic affinity of the sample, but less absorbant than mafic host rocks at higher wavelengths. Desert varnish occurs chiefly as thin impregnating films. Distribution of significant varnish accumulations is sparse and localized, occurring chiefly in surface recesses. These relationships result in the longer wavelength bands and high 5/2 values over felsic units with extensive desert varnish coatings. These lithologic, petrochemical, and desert varnish controlled spectral responses lead to characteristic TM band relationships which tend to correlate with conventionally mappable geologic formations. The concept of a Rock-Varnish Index (RVI) is introduced to help distinguish rocks with a potentially detectable varnish. Felsic rocks have a high RVI, and those with extensive desert varnish behave differently, spectrally, from those without extensive varnish. The spectrally distinctive volcanic formations at Stonewall Mountain provide excellent statistical class segregation on supervised classification images. A binary decision rule flow-diagram is presented to aid TM imagery analysis over volcanic terrane in semi-arid environments.

  9. Advantages of doubly polished thin sections for the study of microfossils in volcanic rock

    PubMed Central

    Ivarsson, M

    2006-01-01

    Doubly polished thin sections, originally prepared for fluid inclusion studies, present great advantages in the study of microfossils in volcanic rocks. Better visibility and light conditions, variation in thickness of the thin sections and the possibility to combine fluid inclusion studies with microfossil studies lead to a wide range of advantages over ordinary thin sections. This includes the study of morphology, internal microstructures, colonies, association with the substrate that microfossils are attached to and geological and environmental context in which the microfossil once lived. When meeting the criteria of microfossil recognition the advantages of doubly polished thin sections are substantial and can be crucial in distinguishing between biogenic microfossils and abiotically formed abiomorphs. PMID:16759373

  10. Petrochemistry of late miocene peraluminous silicic volcanic rocks from the Morococala field, Bolivia

    USGS Publications Warehouse

    Morgan, VI G.B.; London, D.; Luedke, R.G.

    1998-01-01

    Late Miocene peraluminous volcanic rocks of the Morococala field, Bolivia, define a layered stratigraphy of basal andalusite-, biotite-(?? Muscovite)-bearing rhyolite tuffs (AR), overlain by cordierite-, biotite-bearing rhyolite tuffs (CR), and capped by biotite-beanng quartz latite tuffs, lavas, and late domal flows (QL). Mineral and whole-rock compositions become more evolved from top to bottom, with differentiation reflected by decreasing Ca, Ba, Mg, Fe, and rare earth elements (REE) versus increasing F, Na/K, and aluminosity from QL to AR. Mineral, whole-rock, and glass inclusion compositions are consistent with derivation of all three rock types from a single stratified magma reservoir, but age and spatial relations between the three units make this unlikely. Genesis of the QL involved biotite-dehydration melting of an aluminous source at T > 750??C and P ??? 4-6 kbar. If not co-magmatic with QL, the other units were generated primarily by muscovite-dehydration melting at T = 730-750??C and P ??? 3??5-4??5 kbar for CR, and T ??? 750??C for AR with pre-emptive residence at low pressure (1??5-3??0 kbar). Low hematite contents (XHem ??? 0??06) of ilmenite grains in AR, CR, and early grains (as inclusions in plagioclase and sanidine cores) in QL indicate reduced conditions imposed by a graphite-bearing source. Compositional variability among texturally later oxides (ilmenite with XHem = 0??06-0??50, primary magnetite), however, apparently records progressive increases in pre-eruptive f(O2) in QL. Plagioclase-melt equilibria and electron microprobe analysis difference for quartz-hosted glass inclusions suggest pre-emptive melt H2O contents ??? 5-7 wt % for the AR, ???4-6 wt % for the CR, and ???3-5 wt % for the QL.

  11. Geochemistry of middle Tertiary volcanic rocks in the northern Aquarius Mountains, west-central Arizona

    SciTech Connect

    Simmons, A.M.; Haxel, G.B.

    1993-04-01

    The northern Aquarius Mountains volcanic field ([approximately]50km east of Kingman) covers an area of 400 km[sup 2], bounded by upper Trout Creek (S), the Truxton Valley (N), the Big Sandy Valley (W), and Cross Mountain (E). The volcanic sequence rests upon a pre-middle Eocene erosional surface. The lowest units is a 250 m-thick unit of rhyolitic pyroclastic breccias and airfall tuffs. Successively younger units are: basanite flows and cinder cones; hornblende latite flows and domes; porphyritic dacite flows, domes, and breccias; alkali basalt intrusions; and low-silica rhyolite domes and small high=silica rhyolite flows. Dacite is volumetrically dominant, and erupted primarily from vents in and around Cedar Basin (Penitentiary Mtn 7.5[prime] quad.). Other geologists have obtained K-Ar dates [approximately]24--20 Ma for the basanites and latites. The alkali basalts, latites, dacites, and rhyolites evidently constitute a genetically-related high-K to shoshonitic calcalkaline suite with chemistry typical of subduction-related magmatism: enrichment in LILE and LREE, and depletion of Nb and Ta relative to K and La and of Ti relative to Hf and Yb. Each rock type is unique and distinguishable in K/Rb and Rb/Sr. The basanites are primitive (mg=0.75--0.78), have intraplate affinities (La/Nb[<=]1), and show consistent and distinctive depletion of K relative to the other LILE. The presence of these basanites in an early Miocene volcanic sequence is unusual or unexpected, as they predate (by [approximately]10 m.y.) the regional eruption of asthenosphere-derived basalts associated with Basin-and-Range extension.

  12. Interpretation of volcanic gas data from tholeiitic and Alkaline Mafic Lavas

    NASA Astrophysics Data System (ADS)

    Gerlach, T. M.

    1982-09-01

    The analyses of approximately 100 high temperature gas samples from erupting lavas of Surtsey, Erta Ale, Ardoukoba, Kilauea, Mount Etna and Nyiragongo exhibit erratic compositions resulting from analytical errors, condensation effects, reactions with sampling devices, and contamination by atmospheric gases, meteoric water and organic material. Computational techniques have been devised to restore reported analyses to compositions representative of the erupted gases. The restored analyses show little evidence of short-term variations. The principal species are H2O, CO2, SO2, H2, CO, H2S, S2, and HCl. The O2 fugacities range from nickel-nickel oxide to a half order of magnitude below quartz-magnetite-fayalite. There is no evidence for a unique magmatic gas composition; instead, the erupted gases show regular compositional trends characterized by decreasing CO2 with progressive outgassing. The gases from more alkaline lavas (Etna, Nyiragongo) are distinctly richer in CO2, while those from less alkaline (Surtsey) or tholeiitic lavas (Erta Ale, Ardoukoba) tend to be richer in H2O. Kilauean gases range from CO2-rich to H2O-rich. The total sulfur contents of the erupted gases show an excellent positive correlation with lava O2 fugacity. All restored analyses are significantly lower in H2O and enriched in sulfur and CO2 compared to the «excess volatiles».

  13. Compilation of modal analyses of volcanic rocks from the Nevada Test Site area, Nye County, Nevada

    SciTech Connect

    Page, W.R.

    1990-10-01

    Volcanic rock samples collected from the Nevada Test Site, Nye County, Nevada, between 1960 and 1985 were analyzed by thin section to obtain petrographic mode data. In order to provide rapid accessibility to the entire database, all data from the cards were entered into a computerized database. This computer format will enable workers involved in stratigraphic studies in the Nevada Test Site area and other locations in southern Nevada to perform independent analyses of the data. The data were compiled from the mode cards into two separate computer files. The first file consists of data collected from core samples taken from drill holes in the Yucca Mountain area. The second group of samples were collected from measured sections and surface mapping traverses in the Nevada Test Site area. Each data file is composed of computer printouts of tables with mode data from thin section point counts, comments on additional data, and location data. Tremendous care was taken in transferring the data from the cards to computer, in order to preserve the original information and interpretations provided by the analyzer. In addition to the data files above, a file is included that consists of Nevada Test Site petrographic data published in other US Geological Survey and Los Alamos National Laboratory reports. These data are presented to supply the user with an essentially complete modal database of samples from the volcanic stratigraphic section in the Nevada Test Site area. 18 refs., 4 figs.

  14. Rock types of South Pole-Aitken basin and extent of basaltic volcanism

    USGS Publications Warehouse

    Pieters, C.M.; Head, J. W., III; Gaddis, L.; Jolliff, B.; Duke, M.

    2001-01-01

    The enormous pre-Nectarian South Pole-Aitken (SPA) basin represents a geophysically and compositionally unique region on the Moon. We present and analyze the mineralogical diversity across this basin and discuss the implications for basin evolution. Rock types are derived from Clementine multispectral data based on diagnostic characteristics of ferrous absorptions in fresh materials. Individual areas are characterized as noritic (dominated by low-Ca pyroxene), gabbroic/basaltic (dominated by high-Ca pyroxene), feldspathic (<3-6% FeO), and olivine-gabbro (dominated by high-Ca pyroxene and olivine). The anorthositic crust has effectively been removed from the interior of the basin. The style of volcanism within the basin extends over several 100 Myr and includes mare basalt and pyroclastic deposits. Several areas of ancient (pre-Orientale) volcanism, or cryptomaria, have also been identified. The nonmare mafic lithology that occurs across the basin is shown to be noritic in composition and is pervasive laterally and vertically. We interpret this to represent impact melt/breccia deposits derived from the lower crust. A few localized areas are identified within the basin that contain more diverse lithologies (gabbro, olivine-gabbro), some of which may represent material from the deepest part of the lower crust and perhaps uppermost mantle involved in the SPA event. Copyright 2001 by the American Geophysical Union.

  15. Suitability of alkaline leaching and etching experiments in the quantification of ASR potential of quartz-rich rocks

    NASA Astrophysics Data System (ADS)

    Kuchařová, Aneta; Šachlová, Šárka; Pertold, Zdeněk; Přikryl, Richard

    2015-04-01

    Three groups of methods are conventionally applied in the assessment of the susceptibility of aggregates used in concrete to be affected by alkali-silica reaction (ASR). The most frequently employed expansion tests (accelerated mortar bar test and concrete prism test, e.g. ASTM C1260, RILEM AAR2, RILEM AAR4.1) quantify ASR potential of aggregates according to the expansion values of mortar bars (resp. concrete prisms) measured after certain testing time period. Petrographic methods are based on the quantification of alkali-reactive phases by polarizing microscopy (e.g. RILEM AAR1). Chemical methods quantify ASR potential according to the amount of Si4+ dissolved into alkaline solution combined with the reduction of alkalinity of the solution (e.g. ASTM C289). The current study focused on the comparison of three approaches: the alkaline etching of polished rock sections and standard chemical method (following ASTM C289) with the measuring of expansion values of mortar bars (following ASTM C1260). Various types of quartz and amorphous SiO2 used for the experiments were separated from rock samples of orthoquartzite, quartz meta-greywacke, pegmatite, phyllite, chert, and flint. Polished rock sections (resp. crushed fraction 0.125/0.250) were used and subjected to leaching in 1M NaOH solution at 80°C for 14 days (resp. 24 hours). After alkaline etching in alkaline solution, the rock sections were analyzed by scanning electron microscopy combined with energy dispersive spectrometer. Representative areas were documented in back scattered electron images and quantified using fully-automatic petrographic image analysis. ASR potential of the polished rock sections was evaluated by the vol. % of area affected by alkaline etching. ASR potential of crushed aggregate was estimated by measurements of Si4+ dissolved into the solution versus the reduction of alkalinity of the solution (following ASTM C289). Classification according to the ASTM C289 indicated three of investigated

  16. Geology, geochemistry, geochronology, and economic potential of Neogene volcanic rocks in the Laguna Pedernal and Salar de Aguas Calientes segments of the Archibarca lineament, northwest Argentina

    NASA Astrophysics Data System (ADS)

    Richards, J. P.; Jourdan, F.; Creaser, R. A.; Maldonado, G.; DuFrane, S. A.

    2013-05-01

    This study presents new geochemical, geochronological, isotopic, and mineralogical data, combined with new geological mapping for a 2400 km2 area of Neogene volcanic rocks in northwestern Argentina near the border with Chile, between 25°10‧S and 25°45‧S. The area covers the zone of intersection between the main axis of the Cordillera Occidental and a set of NW-SE-trending structures that form part of the transverse Archibarca lineament. This lineament has localized major ore deposits in Chile (e.g., the late Eocene La Escondida porphyry Cu deposit) and large volcanic centers such as the active Llullaillaco and Lastarría volcanoes on the border between Chile and Argentina, and the Neogene Archibarca, Antofalla, and Cerro Galán volcanoes in Argentina. Neogene volcanic rocks in the Laguna Pedernal and Salar de Aguas Calientes areas are mostly high-K calc-alkaline in composition, and range from basaltic andesites, through andesites and dacites, to rhyolites. Magmatic temperatures and oxidation states, estimated from mineral compositions, range from ~ 1000 °C and ∆FMQ ≈ 1.0-1.5 in andesites, to ~ 850 °C and ∆FMQ ≈ 1.5-2.0 in dacites and rhyolites. The oldest rocks consist of early-middle Miocene andesite-dacite plagioclase-pyroxene-phyric lava flows and ignimbrites, with 40Ar/39Ar ages ranging from 17.14 ± 0.10 Ma to 11.76 ± 0.27 Ma. Their major and trace element compositions are typical of the Andean Central Volcanic Zone, and show strong crustal contamination trends for highly incompatible elements such as Cs, Rb, Th, and U. These rocks are geochemically grouped as sub-suite 1. This widespread intermediate composition volcanism was followed in the middle-late Miocene by a period of more focused rhyodacitic flow-dome complex formation. These felsic rocks are characterized by less extreme enrichments in highly incompatible elements, and increasing depletion of heavy rare earth elements. These rocks are geochemically grouped as sub-suite 2. The

  17. Geochronology and geochemistry of the Triassic volcanic rocks at the eastern margin of the Xing'an Massif, NE China: constraints on the spatial-temporal extent of the influence of the Mongol-Okhotsk tectonic regime

    NASA Astrophysics Data System (ADS)

    Yu, L.; Xu, W.; Wang, F.

    2015-12-01

    The Mongol-Okhotsk suture belt is located between the Siberian and the North China cratons and played an important role in the formation and tectonic evolution of the eastern part of the Eurasian continent during the Mesozoic. It was previously thought that subduction of the Mongol-Okhotsk oceanic plate beneath the Siberian Craton was north-directed throughout the entire period of subduction, but recent research has provided evidence of southward subduction beneath the Central Mongolia and Erguna massifs during the late Permian and early Mesozoic. However, the spatial and temporal extent of the influence of the Mongol-Okhotsk tectonic regime on NE China remains unclear. In this paper, we present new zircon U-Pb and geochemical data for Triassic volcanic rocks that crop out on the eastern margin of the Xing'an Massif to address the above-mentioned question. Zircon U-Pb dating indicates that the Triassic volcanism in the Xing'an Massif occurred in two stages during the Middle (~240 Ma) and Late (~224 Ma) Triassic. Triassic volcanism consists of a suite of calc-alkaline trachybasalt and andesite, and are enriched in light rare earth elements (LREE) and depleted in high field strength elements (HFSE; e.g., Nb, Ta, Zr, and Hf), indicating an affinity to arc-type volcanic rocks. The Triassic volcanic rocks formed in an active continental margin setting associated with southward subduction of the Mongol-Okhotsk oceanic plate. Combined with the spatial and temporal variations of late Mesozoic igneous rocks in NE China, we conclude that the spatial extent of the influence of the Mongol-Okhotsk tectonic regime reached at least the eastern margin of the Xing'an Massif, and the temporal influence of this tectonism spanned from the late Permian to the early Early Cretaceous. This research was financially supported by the National Natural Science Foundation of China (Grant 41330206) and Graduate Innovation Fund of Jilin University (Project 2015038).

  18. Volcanic rocks and pyroclastica as time markers in sedimentary sequences - but how to date them? Examples from the Quaternary Eifel volcanism, German

    NASA Astrophysics Data System (ADS)

    Zoeller, Ludwig; Richter, Daniel; Klinger, Philip; van den Bogaard, Paul

    2014-05-01

    Volcanic rocks, in particular tephra, can serve as most valuable time markers in sedimentary sequences such as loess-paleosol sequences, lake sediments, fluvial sediments, etc. Young (Quaternary) volcanic products are often difficult to date with K/Ar or Ar/Ar methods, due to the long half-life of 40K and/or the lack of K-rich minerals in mafic volcanic products. 14C dating is problematic in volcanic environments and limited to < ca 50 ka. Direct dating of volcanic minerals by TL is strongly hampered by so-called "anomalous fading" of volcanic feldspars or pyroxenes. We tested the orange-red (620 nm) R-TL emission of quartz extracted from crustal xenoliths of some Quaternary Eifel volcanoes which were heated during the eruption. The R-TL emission of quartz appears to be suitable because of its high saturation dose which should allow for dating >1 Ma, and because of the lack of anomalous fading as reported in literature. Comparing our first apparent TL ages with new laser Ar/Ar ages from small autogenic phlogopit crystals we found, however, unexpected age underestimations for some samples. Further test relate this observation to the so-called anomalous fading of the quartz separates. Apparently, the temperature experienced by the xenolithic quartz grains during eruption is relevant for their TL stability characteristics. By improving and adjusting R-TL measurement protocols we were so far able to reproduce some 14C and Ar/Ar ages in the range of ca 40 ka to ca 600 ka. Our continuing work will focus on establishing R-TL dating of heated xenolithic quartz as a reliable method for Upper and Middle Pleistocene volcanic events.

  19. The questa magmatic system: Petrologic, chemical and isotopic variations in cogenetic volcanic and plutonic rocks of the latir volcanic field and associated intrusives, northern New Mexico

    SciTech Connect

    Johnson, C.M.

    1986-01-01

    Field, chemical and isotopic data demonstrate that nearly all igneous rocks at Questa resulted from interactions between mantle-derived parental magmas and the crust. Strontium, neodymium and lead isotope ratios of early andesites to rhyolites (28 to 26 Ma) indicate that these magmas assimilated > 25% lower crust. Injection of basaltic magmas extensively modified the strontium and neodymium but not the lead isotope compositions of the lower crust. Eruption of comendite magmas and the peralkaline Amalia Tuff 26 Ma is correlated with inception of regional extension. Lead isotope ratios identify different sources for the metaluminous granites and the peralkaline rocks. 26 Ma metaluminous granite to granodiorite intrusions have chemical and isotopic compositions to those of the precaldera intermediate-composition rocks, and are interpreted as representing the solidified equivalents of the precaldera magmatic episode. However, both conventional and ion-microprobe isotopic data prohibit significant assimilation of crustal rocks at the level of exposure, suggesting that the plutons were emplaced a relatively crystal-rich mushes which did not have sufficient heat to assimilate country rocks. This suggest that in some cases plutonic rocks are better than volcanic rocks in representing the isotopic compositions of their source regions, because the assimilation potential of crystal-rich magmas is significantly less than that of largely liquid magmas.

  20. Active synchronous counterclockwise rotation and northwards translation of Africa toward Eurasia during the Late Cretaceous: A paleomagnetic study on the Alkaline volcanic field of Wadi Natash (ca. 100-86Ma), South Eastern Desert, Egypt

    NASA Astrophysics Data System (ADS)

    Lotfy, H.

    2009-04-01

    In order to shed light on the paleo-tectonic movement of Africa during the Late Cretaceous, the two end members of the alkaline volcanic field of Wadi Natash (ca. 100-86Ma) in the South Eastern Desert of Egypt were studied paleomagnetically. The Wadi Natash volcanic field (24.5°N-34.25°E) is made up of a succession of differentiated flows grading from alkali olivine basalt [AOB] to trachyte-phonolite [Tr/Ph]. The oldest flows of the AOB (104±7 Ma) and the youngest Tr/Ph plugs and ring dykes (86Ma) as well as the interflows sandstones [ previously know as Nubian sandstone were sampled allover the field > 400km2. The isothermal remanent magnetization [IRM] study revealed that the remanence in Wadi Natash volcanics reside mainly in magnetite with some subsidiary goethite/hematite sites. On the other hand, goethite/hematite are the sole remanence carriers in the Nubian-type interflow sandstone. After the progressive stepwise thermal demagnetization of all samples, the visual isolation and subsequent calculation of the best-fit line of the characteristic remanence [ChRM] direction of each sample, followed by the calculation of the site and rock-unit means revealed that: 1- In the tilt-corrected coordinates, the mean ChRM of the oldest AOB flows [N=12 sites

  1. Age and geochemistry of volcanic rocks from the Hikurangi and Manihiki oceanic Plateaus

    NASA Astrophysics Data System (ADS)

    Hoernle, Kaj; Hauff, Folkmar; van den Bogaard, Paul; Werner, Reinhard; Mortimer, Nick; Geldmacher, Jörg; Garbe-Schönberg, Dieter; Davy, Bryan

    2010-12-01

    Here we present the first radiometric age data and a comprehensive geochemical data set (including major and trace element and Sr-Nd-Pb-Hf isotope ratios) for samples from the Hikurangi Plateau basement and seamounts on and adjacent to the plateau obtained during the R/V Sonne 168 cruise, in addition to age and geochemical data from DSDP Site 317 on the Manihiki Plateau. The 40Ar/ 39Ar age and geochemical data show that the Hikurangi basement lavas (118-96 Ma) have surprisingly similar major and trace element and isotopic characteristics to the Ontong Java Plateau lavas (ca. 120 and 90 Ma), primarily the Kwaimbaita-type composition, whereas the Manihiki DSDP Site 317 lavas (117 Ma) have similar compositions to the Singgalo lavas on the Ontong Java Plateau. Alkalic, incompatible-element-enriched seamount lavas (99-87 Ma and 67 Ma) on the Hikurangi Plateau and adjacent to it (Kiore Seamount), however, were derived from a distinct high time-integrated U/Pb (HIMU)-type mantle source. The seamount lavas are similar in composition to similar-aged alkalic volcanism on New Zealand, indicating a second wide-spread event from a distinct source beginning ca. 20 Ma after the plateau-forming event. Tholeiitic lavas from two Osbourn seamounts on the abyssal plain adjacent to the northeast Hikurangi Plateau margin have extremely depleted incompatible element compositions, but incompatible element characteristics similar to the Hikurangi and Ontong Java Plateau lavas and enriched isotopic compositions intermediate between normal mid-ocean-ridge basalt (N-MORB) and the plateau basement. These younger (˜52 Ma) seamounts may have formed through remelting of mafic cumulate rocks associated with the plateau formation. The similarity in age and geochemistry of the Hikurangi, Ontong Java and Manihiki Plateaus suggest derivation from a common mantle source. We propose that the Greater Ontong Java Event, during which ˜1% of the Earth's surface was covered with volcanism, resulted from a

  2. Origin of andesitic rocks: Geochemical constraints from Mesozoic volcanics in the Luzong basin, South China

    NASA Astrophysics Data System (ADS)

    Chen, Long; Zhao, Zi-Fu; Zheng, Yong-Fei

    2014-03-01

    A combined study of whole-rock major-trace elements and Sr-Nd-Pb-Hf isotopes as well as zircon U-Pb ages and Hf-O isotopes was carried out for Mesozoic andesitic-basaltic volcanics from the Luzong basin in the Middle-Lower Yangtze River Belt, South China. The results provide insights into the origin of mantle sources above fossil Andes-type oceanic subduction zone and thus into the petrogenesis of andesitic rocks on fossil and modern continental margins. These volcanics are primarily composed of basaltic trachyandesite and trachyandesite, with small amounts of trachybasalt and trachyte. They exhibit variable contents of SiO2 (48.66-63.43 wt.%), MgO (0.39-4.85 wt.%), Na2O (1.22-6.07 wt.%) and K2O (2.53-10.10 wt.%), with highly variable K2O/Na2O ratios from 0.45 to 7.39. They are characterized by arc-like trace element distribution patterns, with significant enrichment of LILE, Pb and LREE but depletion of HFSE. They exhibit relatively enriched Sr-Nd-Pb-Hf isotope compositions, with initial 87Sr/86Sr ratios of 0.7050 to 0.7066, negative ɛNd(t) values of - 8.0 to - 3.1, negative ɛHf(t) values of - 11.1 to - 1.1, and elevated 207Pb/204Pb and 208Pb/204Pb ratios at given 206Pb/204Pb ratios. Zircon U-Pb dating yields consistent ages of 127 ± 2 to 137 ± 1 Ma for magma emplacement through volcanic eruption. The zircon exhibits slightly high δ18O values of 5.3 to 7.6‰ and variable ɛHf(t) values of - 13.1 to 2.6. An integrated interpretation of all these geochemical data leads to the conclusion that the Luzong andesitic-basaltic volcanics were primarily derived from partial melting of fertile and enriched, mafic-ultramafic mantle sources that are similar to those of continental arc andesites. Such mantle sources are hypothesized to form by reaction of the mantle wedge peridotite not only with hydrous felsic melts derived from partial melting of seafloor sediment but also with aqueous fluid derived from metamorphic dehydration of altered oceanic basalt during

  3. Characteristics of Fault Zones in Volcanic Rocks Near Yucca Flat, Nevada Test Site, Nevada

    USGS Publications Warehouse

    Sweetkind, Donald S.; Drake II, Ronald M.

    2007-01-01

    During 2005 and 2006, the USGS conducted geological studies of fault zones at surface outcrops at the Nevada Test Site. The objectives of these studies were to characterize fault geometry, identify the presence of fault splays, and understand the width and internal architecture of fault zones. Geologic investigations were conducted at surface exposures in upland areas adjacent to Yucca Flat, a basin in the northeastern part of the Nevada Test Site; these data serve as control points for the interpretation of the subsurface data collected at Yucca Flat by other USGS scientists. Fault zones in volcanic rocks near Yucca Flat differ in character and width as a result of differences in the degree of welding and alteration of the protolith, and amount of fault offset. Fault-related damage zones tend to scale with fault offset; damage zones associated with large-offset faults (>100 m) are many tens of meters wide, whereas damage zones associated with smaller-offset faults are generally a only a meter or two wide. Zeolitically-altered tuff develops moderate-sized damage zones whereas vitric nonwelded, bedded and airfall tuff have very minor damage zones, often consisting of the fault zone itself as a deformation band, with minor fault effect to the surrounding rock mass. These differences in fault geometry and fault zone architecture in surface analog sites can serve as a guide toward interpretation of high-resolution subsurface geophysical results from Yucca Flat.

  4. Characteristics of Fault Zones in Volcanic Rocks Near Yucca Flat, Nevada Test Site, Nevada

    SciTech Connect

    Donald Sweetkind; Ronald M. Drake II

    2007-11-27

    During 2005 and 2006, the USGS conducted geological studies of fault zones at surface outcrops at the Nevada Test Site. The objectives of these studies were to characterize fault geometry, identify the presence of fault splays, and understand the width and internal architecture of fault zones. Geologic investigations were conducted at surface exposures in upland areas adjacent to Yucca Flat, a basin in the northeastern part of the Nevada Test Site; these data serve as control points for the interpretation of the subsurface data collected at Yucca Flat by other USGS scientists. Fault zones in volcanic rocks near Yucca Flat differ in character and width as a result of differences in the degree of welding and alteration of the protolith, and amount of fault offset. Fault-related damage zones tend to scale with fault offset; damage zones associated with large-offset faults (>100 m) are many tens of meters wide, whereas damage zones associated with smaller-offset faults are generally a only a meter or two wide. Zeolitically-altered tuff develops moderate-sized damage zones whereas vitric nonwelded, bedded and airfall tuff have very minor damage zones, often consisting of the fault zone itself as a deformation band, with minor fault effect to the surrounding rock mass. These differences in fault geometry and fault zone architecture in surface analog sites can serve as a guide toward interpretation of high-resolution subsurface geophysical results from Yucca Flat.

  5. Genesis of rare-metal pegmatites and alkaline apatite-fluorite rocks of Burpala massi, Northern Baikal folded zone

    NASA Astrophysics Data System (ADS)

    Sotnikova, Irina; Vladykin, Nikolai

    2015-04-01

    Burpalinsky rare metal alkaline massif in the Northern Baikal folded zone in southern margin of Siberian Platform, is a of intrusion central type, created 287 Ma covering area of about 250 km2. It is composed of nepheline syenites and pulaskites grading to quartz syenites in the contacts. Veines and dykes are represented by shonkinites, sodalite syenite, leucocratic granophyres, alkali granites and numerous rare metal alkaline syenite pegmatites and two dykes of carbonatites. All rocks except for granites are cut by a large apatite-fluorite dyke rocks with mica and magnetite, which in turn is cut by alaskite granites dyke. The massif has been studied by A.M. Portnov, A.A. Ganzeev et al. (1992) Burpalinsky massif is highly enriched with trace elements, which are concentrated in pegmatite dykes. About 70 rare-metal minerals we found in massif. Zr-silicates: zircon, eudialyte, lovenite, Ti-lovenite, velerite, burpalite, seidozerite, Ca- seidozerite, Rosenbuschite, vlasovite, katapleite, Ca-katapleite, elpidite. Ti- minerals:- sphene, astrophyllite, ramsaite, Mn-neptunite bafertisite, chevkinite, Mn-ilmenite, pirofanite, Sr-perrerit, landauite, rutile, anatase, brookite; TR- minerals - loparite, metaloparite, britolite, rinkolite, melanocerite, bastnesite, parisite, ankilite, monazite, fluocerite, TR-apatite; Nb- minerals - pyrochlore, loparite. Other rare minerals leucophanite, hambergite, pyrochlore, betafite, torite, thorianite, tayniolite, brewsterite, cryolite and others. We have proposed a new scheme massif: shonkinites - nepheline syenites - alkaline syenite - quartz syenites - veined rocks: mariupolites, rare-metal pegmatites, apatite, fluorite rock alyaskite and alkaline granites and carbonatites (Sotnikova, 2009). Apatite-fluorite rocks are found in the central part of massif. This is a large vein body of 2 km length and a 20 m width cutting prevailing pulaskites. Previously, these rocks were regarded as hydrothermal low-temperature phase. New geological and

  6. Geochemical analyses, age dates, and flow-volume estimates for quaternary volcanic rocks, Southern Cascade Mountains, Washington

    SciTech Connect

    Hammond, P.E.; Korosec, M.A.

    1983-12-01

    Data collected over the last three years as part of a continuing study of the Quaternary volcanic rocks of the southern Cascade Mountains are presented. Whole-rock chemical analyses, selected trace element geochemistry, volume approximations, specific gravity determinations, and locations are provided for most of the 103 samples collected, and 21 radiometric age dates are included. In addition, partial information, including names and flow-volumes, are presented for 98 additional samples, collected for related studies. The study extends from the Columbia River north to the Cowlitz River and Goat Rocks Wilderness area, and from the Klickitat River west to the Puget-Willamette Trough. The volcanic rocks are all younger than 3 million years and consist primarily of tholeiitic and high-alumina basalts and basaltic-andesites erupted from numerous shield volcanoes and cinder cones. A few analyses of more silicic rocks, including hornblende and/or pyroxene andesites and dacites characteristic of the stratovolcanoes of the region, are also presented. However, systematic sampling of the stratovolcanoes in the study area, Mount Adams and Mount St. Helens, was not conducted. A map of the areal extent of Quaternary volcanic units and sample locations is included. It has been based on the 1:125,000 reconnaissance geologic map of the southern Cascade Range by Hammond (1980).

  7. Paleomagnetism and Rock Magnetic Properties from Quaternary Lavas and Tuffs of the Yellowstone Plateau Volcanic Field

    NASA Astrophysics Data System (ADS)

    Harlan, S. S.; Morgan, L. A.

    2008-12-01

    We report paleomagnetic and rock magnetic from rhyolite lava flows, ignimbrites, and basalt flows associated with the Yellowstone Caldera, within and surrounding Yellowstone National Park. These data were collected in order to understand sources of magnetic variations observed in high resolution aeromagnetic data reported by Finn and Morgan (2002), and to better understand the evolution of the Yellowstone magmatic system. Most paleomagnetic samples are from volcanic rocks of the third eruptive cycle (1.2 Ma to 0.070 Ma), including the ca. 0.640 Ma Lava Creek Tuff, postcaldera rhyolite flows, and contemporaneous marginal or post-caldera basalt flows. Magnetic intensities for samples ranged from 0.12 A/m to 5.9 A/m, with volume susceptibilities of 2.14x10-4 to 1.45x10-3 SI; Q ratios range from 0.67 to 23.8. As expected, most sites yield well-defined paleomagnetic directions of north declination and moderate positive inclination consistent with remanence acquisition during the Brunhes polarity chron. However, a few sites from older units such as the rhyolites of the Harlequin Lake (0.839 ± 0.007 Ma) and Lewis Canyon (0.853 ± 0.008 Ma) flows, and the basalts from the Junction Butte flow (at Tower Falls, 2.16 ± 0.04 Ma) and Hepburn Mesa (2.2 Ma) yield reverse polarity magnetizations (40Ar/39Ar dates from Obradovich, 1992, and Harlan, unpublished (Hepburn Mesa flow)). Rock magnetic behavior, including high coercivities during AF demagnetization, high laboratory unblocking temperatures, and susceptibility vs. temperature determinations indicate that remanence in the rhyolitic samples is carried by a combination of single or pseudo-single domain magnetite and/or hematite; in the basalt flows magnetite and high-Ti titanomagnetite carrys the remanence. Paleomagnetic results from 46 sites in 27 separate flows yields a grand mean direction with a declination of 356.9° and inclination of 61.9° (k = 35.2, α95 = 4.8°). VGPs calculated from the site-mean directions yield a

  8. The influence of porosity and vesicle size on the brittle strength of volcanic rocks and magma

    NASA Astrophysics Data System (ADS)

    Heap, Michael J.; Xu, Tao; Chen, Chong-feng

    2014-09-01

    Volcanic rocks and magma display a wide range of porosity and vesicle size, a result of their complex genesis. While the role of porosity is known to exert a fundamental control on strength in the brittle field, less is known as to the influence of vesicle size. To help resolve this issue, here, we lean on a combination of micromechanical (Sammis and Ashby's pore-emanating crack model) and stochastic (rock failure and process analysis code) modelling. The models show, for a homogenous vesicle size, that an increase in porosity (in the form of circular vesicles, from 0 to 40 %) and/or vesicle diameter (from 0.1 to 2.0 mm) results in a dramatic reduction in strength. For example, uniaxial compressive strength can be reduced by about a factor of 5 as porosity is increased from 0 to 40 %. The presence of vesicles locally amplifies the stress within the groundmass and promotes the nucleation of vesicle-emanating microcracks that grow in the direction of the applied macroscopic stress. As strain increases, these microcracks continue to grow and eventually coalesce leading to macroscopic failure. Vesicle clustering, which promotes the overlap and interaction of the tensile stress lobes at the north and south poles of neighbouring vesicles, and the increased ease of microcrack interaction, is encouraged at higher porosity and reduces sample strength. Once a microcrack nucleates at the vesicle wall, larger vesicles impart higher stress intensities at the crack tips, allowing microcracks to propagate at a lower applied macroscopic stress. Larger vesicles also permit a shorter route through the groundmass for the macroscopic shear fracture. This explains the reduction in strength at higher vesicle diameters (at a constant porosity). The modelling highlights that the reduction in strength as porosity or vesicle size increases is nonlinear; the largest reductions are observed at low porosity and small vesicle diameters. In detail, we find that vesicle diameter can play an

  9. The role of pore fluids on deforming volcanic rocks: an experimental study

    NASA Astrophysics Data System (ADS)

    Fazio, Marco; Benson, Philip; Vinciguerra, Sergio; Meredith, Philip

    2015-04-01

    Pore fluids play an important role on the process of the deformation of rocks. Not only it affects the mechanical properties and the elastic velocities of the material, but it is also responsible in the generation of a whole kind of seismicity, characterized by lower frequency and longer tail (i.e. Long Period, LP, and Hybrid events) than the Volcano-Tectonic (VT) signals, generated by simple shear. While great progress has been made in understanding VT events, LPs, Hybrid signals and the transition between these types of activity are not fully understood yet. This study, aiming in particular on the transition between VT and Hybrid events, shows the results of triaxial experiments on a volcanic rock, run both in dry and wet conditions, to better understand the role of the pore fluids on the final stage of the deformation tests, when the sample is approaching failure. This is achieved through a servo-controlled triaxial testing machine and a state-of the-art acoustic emissions (AEs) kit, composed by an array of 12 piezoelectric sensors surrounding the sample and by both a "triggered" unit, where the events are recorded only if a certain threshold is reached, and a "continuous" unit, where the data is recorded from the beginning to the end of the acquisition, fundamental when the AEs grow exponentially and the triggered unit cannot store at the same rate. The use of sensors of different dominant frequency allows us to better investigate the events occurring as the sample is approaching failure. In both conditions we observe a decrease of the dominant frequency of the seismic activity, due to two different processes: in dry conditions the coalescence of fractures, eventually leading to the major shear zone, creates relatively low-frequency VT events; the same occurs in wet conditions, but the movement of fluids, eased by the merging of the cracks, generates hybrid events. These two type of seismicity are then distinguished in terms of their source mechanism components

  10. Effect of the specimen length on ultrasonic P-wave velocity in some volcanic rocks and limestones

    NASA Astrophysics Data System (ADS)

    Karaman, Kadir; Kaya, Ayberk; Kesimal, Ayhan

    2015-12-01

    Ultrasonic P-wave velocity (UPV) is commonly used in different fields such as civil, mining, geotechnical, and rock engineering. One of the significant parameters which affect the UPV of rock materials is likely to be the length of test cores although it is not mentioned in the literature. In this study, in order to explore the influence of the specimen length on the UPV, rock samples were collected from eight different locations in Turkey. The NX-sized core specimens having different length of 50, 75, 100, 125, and 150 mm were prepared. Before the analyses, rocks were divided into two groups in terms of their geological origins such as volcanic and chemical sedimentary (limestone) rocks. The UPV tests were carried out under dry and saturated conditions for each 200 core specimens. By evaluating the test results, it was shown that the length of the specimens significantly affects the UPV values. Based on the regression analyses, a method was developed to determine the threshold specimen length of studied rocks. Fluctuations in UPVdry and UPVsat values were generally observed for cores smaller than the threshold specimen length. In this study, the threshold specimen length was determined as 79 mm for volcanic rocks and 109 mm for limestones.

  11. Neutralization/prevention of acid rock drainage using mixtures of alkaline by-products and sulfidic mine wastes.

    PubMed

    Alakangas, Lena; Andersson, Elin; Mueller, Seth

    2013-11-01

    Backfilling of open pit with sulfidic waste rock followed by inundation is a common method for reducing sulfide oxidation after mine closure. This approach can be complemented by mixing the waste rock with alkaline materials from pulp and steel mills to increase the system's neutralization potential. Leachates from 1 m3 tanks containing sulfide-rich (ca.30 wt %) waste rock formed under dry and water saturated conditions under laboratory conditions were characterized and compared to those formed from mixtures. The waste rock leachate produced an acidic leachate (pH<2) with high concentrations of As (65 mg/L), Cu (6 mg/L), and Zn (150 mg/L) after 258 days. The leachate from water-saturated waste rock had lower concentrations of As and Cu (<2 μg/L), Pb and Zn (20 μg/L and 5 mg/L), respectively, and its pH was around 6. Crushed (<6 mm) waste rock mixed with different fractions (1-5 wt %) of green liquid dregs, fly ash, mesa lime, and argon oxygen decarburization (AOD) slag was leached on a small scale for 65 day, and showed near-neutral pH values, except for mixtures of waste rock with AOD slag and fly ash (5% w/w) which were more basic (pH>9). The decrease of elemental concentration in the leachate was most pronounced for Pb and Zn, while Al and S were relatively high. Overall, the results obtained were promising and suggest that alkaline by-products could be useful additives for minimizing ARD formation. PMID:23740301

  12. Alkaline Basalts of The Quaternary Buffalo Valley Volcanic Field, NW Fish Creek Mountains, North-central Nevada, Great Basin

    NASA Astrophysics Data System (ADS)

    Cousens, B.; Henry, C. D.

    2008-12-01

    The Buffalo Valley volcanic field, 5 km southwest of Battle Mountain, consists of approximately 11 cinder cones and associated flows. Youthful volcanoes are rare in the region, and thus this field offers the opportunity to investigate mantle sources currently beneath the central Great Basin. Most of the eruptive centers are distributed along the northwestern margin of the Fish Creek Mountains, a mid-Tertiary caldera complex, along a 13-km-long northeasterly trend that is perpendicular to the regional stress field (or GPS velocity field), suggesting fault control or eruption from a now-buried fissure. The cones are geomorphologically youthful, with well-defined, commonly breached craters. At least one cone, situated slightly east of the main trend, consists of only a thin mantle of scoria and bombs overlying grey Paleozoic limestone. Previous K-Ar and Ar-Ar dating indicate that the cones are between 1.29 and 0.95 Ma in age. Two other nearby Quaternary volcanic centers lie northeast of the Fish Creek Mountains (K-Ar date of 3.3 Ma) and in the center of the Fish Creek caldera (age unknown). Rare Tertiary basalts and more common Tertiary andesites lie around the margin of the caldera. Lavas from the Buffalo Valley cones have vesicular flow tops and more massive interiors. All Quaternary centers are similar petrographically, including 1-2% olivine phenocrysts and megacrysts up to 1 cm in size, and characteristic plagioclase megacrysts that are rarely up to 4 cm long, commonly in a glassy matrix. Two cone samples are alkalic basalt and tephrite with Mg numbers of 0.55, high TiO2 (2.4%), K2O (2.0%), light REE, Nb (60 ppm), but low Cr and Ni (80 ppm), Pb (2 ppm), Ba (450 ppm) and 87Sr/86Sr (0.70375) compared to Late Pliocene/Quaternary volcanic rocks from the western Great Basin near Reno/Carson City/Fallon. The Buffalo Valley cones are similar chemically to lavas from the Pliocene-Quaternary Lunar Craters volcanic field in central Nevada, and are melts of mantle that is

  13. Age constraints on late Mesozoic lithospheric extension and origin of bimodal volcanic rocks from the Hailar basin, NE China

    NASA Astrophysics Data System (ADS)

    Li, Shuang-Qing; Hegner, Ernst; Yang, Yi-Zeng; Wu, Jia-De; Chen, Fukun

    2014-03-01

    Following the amalgamation of the late Mesoproterozoic-Carboniferous Central Asian Orogenic Belt with the Siberian and North China cratons, NE China underwent late Mesozoic lithospheric extension and widespread formation of volcano-sedimentary basins. We report U-Pb zircon ages and geochemical data for mafic and felsic volcanic rocks from the Hailar basin, located about 1000 km north of Beijing. Zircon populations of six felsic rock samples analyzed by laser ablation ICP-MS yielded similar U-Pb age spectra ranging from 158 to 125 Ma. The youngest zircon ages are interpreted as time of magma eruption and the xenocrystic zircon-age spectra as evidence for a protracted melting of lower crust due to the underplating of mantle-derived magmas during lithospheric extension. The volcanic assemblage has a bimodal composition comprising geochemically evolved trachybasalts and felsic volcanic rocks of I- and subordinate A-type compositions. The mafic volcanic rocks have negative Nb-anomalies, high Th/Nb and Ce/Pb ratios, low initial ɛNd values of + 0.4 to + 3.4, and radiogenic Pb and Sr isotopes all interpreted as evidence for the melting of passively upwelling asthenosphere and lithospheric mantle previously modified by plate subduction. The xenocrystic zircon ages and chemical/isotopic data of the felsic rocks support an origin from juvenile crustal protoliths: the data of I-type felsic rocks are consistent with the melting of underplated mafic protoliths and those of the A-type rhyolites support the melting of a crustal source with a composition similar to the I-type felsites with apatite controlling their Nb anomaly. The evidence for the persistent melting of a subduction-modified mantle in NE China is in agreement with a model of an extending coupled upper mantle-crust system due to a retreating Paleo-Pacific trench.

  14. Age and Sr isotopic composition of volcanic rocks in the Maricunga Belt, Chile: implications for magma sources

    USGS Publications Warehouse

    McKee, E.H.; Robinson, A.C.; Rybuta, J.J.; Cuitino, L.; Moscoso, R.D.

    1994-01-01

    K-Ar and 40Ar/39Ar dating of volcanic rocks from the Maricunga belt of north-central Chile indicate that igneous activity took place throughout most of Miocene time at various places in the 150 by 30 km belt. No migration patterns of volcanism appear in the Miocene rocks of the belt. Volcanic activity ceased by the end of the Miocene. All the Miocene volcanic rocks studied are calcic andesites to dacites with about 62% SiO2, 18% A12O3, 4% Fe2O3 (total), and 2% K2O. Initial 87Sr/86Sr (Sri) values fall into two groups, one of lower values around 0.7050 to the west and the other of higher values around 0.7060 to the east. It is postulated that the two Sri groups reflect two adjoining coherent lower-crustal magma sources of possibly different age and subtly different composition that form part of the western edge of the South American craton. ?? 1994.

  15. Role of crustal assimilation and basement compositions in the petrogenesis of differentiated intraplate volcanic rocks: a case study from the Siebengebirge Volcanic Field, Germany

    NASA Astrophysics Data System (ADS)

    Schneider, K. P.; Kirchenbaur, M.; Fonseca, R. O. C.; Kasper, H. U.; Münker, C.; Froitzheim, N.

    2016-06-01

    The Siebengebirge Volcanic Field (SVF) in western Germany is part of the Cenozoic Central European Volcanic Province. Amongst these volcanic fields, the relatively small SVF comprises the entire range from silica-undersaturated mafic lavas to both silica-undersaturated and silica-saturated differentiated lavas. Owing to this circumstance, the SVF represents a valuable study area representative of intraplate volcanism in Europe. Compositions of the felsic lavas can shed some new light on differentiation of intraplate magmas and on the extent and composition of potential crustal assimilation processes. In this study, we provide detailed petrographic and geochemical data for various differentiated SVF lavas, including major and trace element concentrations as well as Sr-Nd-Hf-Pb isotope compositions. Samples include tephriphonolites, latites, and trachytes with SiO2 contents ranging between 53 and 66 wt%. If compared to previously published compositions of mafic SVF lavas, relatively unradiogenic 143Nd/144Nd and 176Hf/177Hf coupled with radiogenic 87Sr/86Sr and 207Pb/204Pb lead to the interpretation that the differentiated volcanic rocks have assimilated significant amounts of lower crustal mafic granulites like the ones found as xenoliths in the nearby Eifel volcanic field. These crustal contaminants should possess unradiogenic 143Nd/144Nd and 176Hf/177Hf, radiogenic 87Sr/86Sr, and highly radiogenic 207Pb/204Pb compositions requiring the presence of ancient components in the central European lower crust that are not sampled on the surface. Using energy-constrained assimilation-fractional crystallisation (EC-AFC) model calculations, differentiation of the SVF lithologies can be modelled by approximately 39-47 % fractional crystallisation and 6-15 % crustal assimilation. Notably, the transition from silica-undersaturated to silica-saturated compositions of many felsic lavas in the SVF that is difficult to account for in closed-system models is also well explained by

  16. Geology, thermal maturation, and source rock geochemistry in a volcanic covered basin: San Juan sag, south-central Colorado

    USGS Publications Warehouse

    Gries, R.R.; Clayton, J.L.; Leonard, C.

    1997-01-01

    The San Juan sag, concealed by the vast San Juan volcanic field of south-central Colorado, has only recently benefited from oil and gas wildcat drilling and evaluations. Sound geochemical analyses and maturation modeling are essential elements for successful exploration and development. Oil has been produced in minor quantities from an Oligocene sill in the Mancos Shale within the sag, and major oil and gas production occurs from stratigraphically equivalent rocks in the San Juan basin to the south-west and in the Denver basin to the northeast. The objectives of this study were to identify potential source rocks, assess thermal maturity, and determine hydrocarbon-source bed relationships. Source rocks are present in the San Juan sag in the upper and lower Mancos Shale (including the Niobrara Member), which consists of about 666 m (2184 ft) of marine shale with from 0.5 to 3.1 wt. % organic carbon. Pyrolysis yields (S1 + S2 = 2000-6000 ppm) and solvent extraction yields (1000-4000 ppm) indicate that some intervals within the Mancos Shale are good potential source rocks for oil, containing type II organic matter, according to Rock-Eval pyrolysis assay. Oils produced from the San Juan sag and adjacent part of the San Juan basin are geochemically similar to rock extracts obtained from these potential source rock intervals. Based on reconstruction of the geologic history of the basin integrated with models of organic maturation, we conclude that most of the source rock maturation occurred in the Oligocene and Miocene. Little to no maturation took place during Laramide subsidence of the basin, when the Animas and Blanco Basin formations were deposited. The timing of maturation is unlike that of most Laramide basins in the Rocky Mountain region, where maturation occurred as a result of Paleocene and Eocene basin fill. The present geothermal gradient in the San Juan sag is slightly higher (average 3.5??C/100 m; 1.9??F/100 ft) than the regional average for southern Rocky

  17. Oxygen and strontium isotope studies of K-rich volcanic rocks from the Alban Hills, Italy

    NASA Astrophysics Data System (ADS)

    Ferrara, G.; Laurenzi, M. A.; Taylor, H. P.; Tonarini, S.; Turi, B.

    1985-09-01

    18O/ 16O and 87Sr/ 86Sr ratios and major and trace element contents were measured for 33 leucite-bearing lavas from the Alban Hills, located just south of Rome. Petrologically, this volcanic center is the least complex of all the Pleistocene to Holocene volcanoes in the Roman Comagmatic Province, and the 87Sr/ 86Sr uniformity reflects this (0.71024-0.71091). Whole-rock δ 18O = +5.6 to +9.8, but many samples were enriched in 18O by post-eruption hydration, evidenced by the good correlation between H 2O content (up to 5 wt. %) and δ 18O . Correcting for these effects, we obtain a δ 18O range of +5.6 to +7.8 for the original magmas. No other volcanic center in the Roman Province displays such uniform strontium and oxygen isotopic compositions; thus, this volcano provides special insight into the origin of the High-K Series magma end-member in Central Italy. Three groups of lavas are recognized on 87Sr/ 86Sr-1/Sr, δ 18O- 87Sr/ 86Sr , and K 2O-SiO 2 graphs; all of these groups, as well as the major caldera-forming eruption (Villa Senni Tuff), are derived from a very uniform, LIL-enriched, metasomatized source in the upper mantle. This source had δ 18O = +6.5 ± 1.0 and 87Sr/ 86Sr= 0.71030 ± 0.00010 . The δ 18O values correlate positively with 87Sr/ 86Sr , indicating minor interaction with the continental crust. Essentially all chemical and isotopic variations in the primitive (low-SiO 2, high-Ca, high-Sr) potassic lavas in Italy can be explained by mixing in the upper mantle between this Alban Hills end-member and a Low-K Series Roccamonfina-type end-member.

  18. Deciphering the Western Mediterranean mantle heterogeneities through a statistical approach of the erupted volcanic rocks.

    NASA Astrophysics Data System (ADS)

    Fernandez, M.; Melchiorre, M.; Verges, J.; Coltorti, M.; Torne, M.; Casciello, E.

    2015-12-01

    The Western Mediterranean (We-Me) is characterized by a complex geodynamic history related to subduction events that can be explained by three different models: A) N-NW dipping slab extending from the Gibraltar arc to the Balearic promontory retreating in S-SE direction; B) NW dipping slab under the Balearic promontory, retreating in SE direction towards the Gibraltar strait C) two opposite-directed subductions separated by a transform fault subparellel to the Pierre Fallot Fault Since Oligocene the geological evolution of this part of the Mediterranean is characterized by widespread volcanic activity, related to subductive (orogenic) or intraplate (anorogenic) settings. We merged two huge orogenic and anorogenic datasets containing over 14,000 chemical analyses and processed them through factor analysis, in order to reduce the large number of geochemical parameters describing each sample (major/trace elements, isotopic ratios) through a smaller number of factors. Binary diagrams obtained combining seven resulting factors allow to distinguish the anorogenic field from the orogenic one. Anorogenic rocks usually fall in a narrow range of variation, while orogenic are characterized by a greater variability and by alignment along different trends. These different trends account for large heterogeneities of the sub lithospheric mantle due to extensive recycling of geochemically different materials through time, supporting the idea that different reservoirs are responsible for the Mediterranean volcanism [1]. The spatio-temporal evolution of the We-Me lamproites allows us to speculate a two-step evolution of the mantle beneath southern Spain. This evolution has been evaluated in light of the three models. We therefore propose that a type C model accounting for the presence of two juxtaposed slabs beneath the We-Me is the most feasible model to describe the geodynamic evolution of this area. [1] Conticelli et al. (2009). Lithos 107, 68-92.

  19. /sup 230/Th - /sup 238/U disequilibrium systematics in young volcanic rocks

    SciTech Connect

    Newman, S.

    1983-01-01

    Radioactive disequilibrium between /sup 230/Th (t/sub .5/ = 75,200 years) and its parent, /sup 238/U, has two major applications to the study of young volcanic rocks: 1) geochronology and 2) geochemical tracer studies. Geochronological investigations include both the dating of young (< approx.250,000 year-old) lavas by the internal isochron method and the study of the temporal evolution of magma systems feeding volcanoes. Older, K-Ar-dated lavas from Mauna Kea, Hawaii and Marion Island (Prince Edward hot spot) exhibit constant initial (/sup 230/Th//sup 232/Th) (activity) ratios for the past 100,000-275,000 years. At Mt. Shasta, California, a general decrease in (/sup 230/Th//sup 232/Th)/sub 0/ through time, with evidence of possible mixing corroborated by other geochemical data, is observed. Geochemical tracer studies depend on the observations that Th/U and (/sup 230/Th//sup 238/U) can be changed by such processes as partial melting, mixing, or fluid transport, whereas (/sup 230/Th//sup 232/Th) can only be modified by mixing or the passage of time. The (/sup 230/Th//sup 238/U) ratio can be used to identify possible petrogenetic processes. All lavas exhibit (/sup 230/Th//sup 238/U) greater than or equal to 1 except for some from the Aleutians and Marianas. These observations suggest that subduction-related volcanism is the only type in which U may behave as a more incompatible element than Th, although it need not (Cascades). Recent vapor transport of U or retention of Th may explain the U-enrichment in island arc lavas.

  20. Uranium-series disequilibrium in volcanic rocks from the Northeast Japan Arc

    NASA Astrophysics Data System (ADS)

    Yokoyama, T.; Iwamori, H.; Ueki, K.

    2011-12-01

    Subducting slabs are considered to release fluid components as a result of mineralogical reactions during progressive metamorphic dehydration. The fluid released from the slab subsequently induces melting in the mantle wedge as it ascends, resulting in island arc volcanism [1]. To understand the characteristics of slab-derived materials, geochemical tracers such as trace elements, radiogenic isotopes (e.g., Sr, Nd, Pb), and stable isotopes (e.g., B, Li) have been commonly used [2-3]. U-series disequilibria of island arc volcanic rocks have been used to understand melt generation in the source mantle and the timescales of fluid/melt migration in subduction zones. This is possible because of the short half-lives of daughter nuclides of 238U, 235U and 232Th (e.g., 75 kyr for 230Th, and 1.6 kyr for 226Ra). We report our preliminary measurements on 238U-230Th disequilibrium in volcanic rocks from the Northeast Japan Arc. Lava samples of basalts and basaltic andesites were collected from four volcanoes (Iwate, Akita-Komagatake, Yakeyama and Kampu). The eruption ages of these rocks are estimated to be range from 0 to 30 ka. The frontal-arc lavas (Iwate and Akita-Komagatake) are characterized by 238U-230Th disequilibrium with moderate 238U enrichments (5-10%). This is due to the addition to the mantle wedge of slab-derived fluids enriched in fluid-mobile elements (U) relative to less fluid-mobile elements (Th). The extent of 238U enrichment decreases as the slab depth increases, and the rear-arc lavas (Kampu) show 230Th enrichments relative to 238U (~5%). This generally reflects gradual decrease of the amount of slab derived fluid mixed into the wedge mantle. Thus, the 230Th excesses in rear-arc lavas may be predominantly produced by the melting of garnet-bearing upwelling mantle as observed in MORB (dynamic melting). However, our data show 230Th excess with an extremely low (230Th/232Th) ratio (~0.8) that plots outside the MORB data. This strongly argues against a model

  1. In situ Laser Induced Breakdown Spectroscopy as a tool to discriminate volcanic rocks and magmatic series, Iceland

    NASA Astrophysics Data System (ADS)

    Roux, C. P. M.; Rakovský, J.; Musset, O.; Monna, F.; Buoncristiani, J.-F.; Pellenard, P.; Thomazo, C.

    2015-01-01

    This study evaluates the potentialities of a lab-made pLIBS (portable Laser-Induced Breakdown Spectroscopy) to sort volcanic rocks belonging to various magmatic series. An in-situ chemical analysis of 19 atomic lines, including Al, Ba, Ca, Cr, Cu, Fe, Mg, Mn, Na, Si, Sr and Ti, from 21 sampled rocks was performed during a field exploration in Iceland. Iceland was chosen both for the various typologies of volcanic rocks and the rugged conditions in the field in order to test the sturdiness of the pLIPS. Elemental compositions were also measured using laboratory ICP-AES measurements on the same samples. Based on these latter results, which can be used to identify three different groups of volcanic rocks, a classification model was built in order to sort pLIBS data and to categorize unknown samples. Using a reliable statistical scheme applied to LIBS compositional data, the classification capability of the pLIBS system is clearly demonstrated (90-100% success rate). Although this prototype does not provide quantitative measurements, its use should be of particular interest for future geological field investigations.

  2. The alkaline and alkaline-carbonatite magmatism from Southern Brazil

    NASA Astrophysics Data System (ADS)

    Ruberti, E.; Gomes, C. D. B.; Comin-Chiaramonti, P.

    2015-12-01

    Early to Late Cretaceous lasting to Paleocene alkaline magmatism from southern Brazil is found associated with major extensional structural features in and around the Paraná Basin and grouped into various provinces on the basis of several data. Magmatism is variable in size, mode of occurrence and composition. The alkaline rocks are dominantly potassic, a few occurrences showing sodic affinity. The more abundant silicate rocks are evolved undersaturated to saturated in silica syenites, displaying large variation in igneous forms. Less evolved types are restricted to subvolcanic environments and outcrops of effusive suites occur rarely. Cumulatic mafic and ultramafic rock types are very common, particularly in the alkali-carbonatitic complexes. Carbonatite bodies are represented by Ca-carbonatites and Mg-carbonatites and more scarcely by Fe-carbonatites. Available radiometric ages for the alkaline rocks fit on three main chronological groups: around 130 Ma, subcoveal with the Early Cretaceous flood tholeiites of the Paraná Basin, 100-110 Ma and 80-90 Ma (Late Cretaceous). The alkaline magmatism also extends into Paleocene times, as indicated by ages from some volcanic lavas. Geochemically, alkaline potassic and sodic rock types are distinguished by their negative and positive Nb-Ta anomalies, respectively. Negative spikes in Nb-Ta are also a feature common to the associated tholeiitic rocks. Sr-Nd-Pb systematics confirm the contribution of both HIMU and EMI mantle components in the formation of the alkaline rocks. Notably, Early and Late Cretaceous carbonatites have the same isotopic Sr-Nd initial ratios of the associated alkaline rocks. C-O isotopic Sr-Nd isotopic ratios indicate typical mantle signature for some carbonatites and the influence of post-magmatic processes in others. Immiscibility of liquids of phonolitic composition, derived from mafic alkaline parental magmas, has been responsible for the origin of the carbonatites. Close association of alkaline

  3. Measurement of cosmogenic /sup 36/Cl/Cl in young volcanic rocks: An application of accelerator mass spectrometry in geochronology

    SciTech Connect

    Leavy, B.D.; Phillips, F.M.; Elmore, D.; Kubik, P.W.

    1987-01-01

    We have measured /sup 36/Cl/Cl ratios in a number of young volcanic rocks in order to test the feasibility of using /sup 36/Cl buildup as a geochronometer for materials less than about 700,000 years old. All of the analyzed rocks have been dated independently using K-Ar or other radiometric dating methods and have exposure histories that are known or can be reasonably assumed. Measured /sup 36/Cl/Cl ratios in these rocks are in good agreement with the calculated in-situ /sup 36/Cl buildup curve. These analyses indicate that AMS measurement of /sup 36/Cl buildup in young rocks is a potentially powerful new method for dating materials that had previously been undatable, and as such will have broad applications in volcanology, tectonics, geophysics, and Quaternary research.

  4. Oxygen isotope geochemistry of the silicic volcanic rocks of the Etendeka-Parana province: Source constraints

    SciTech Connect

    Harris, C.; Milner, S.C.; Armstrong, R.A. ); Whittingham, A.M. )

    1990-11-01

    Oxygen isotope ratios of pyroxene phenocrysts in the silicic volcanic rocks from the Cretaceous Etendeka-Parana flood basalt province (Namibia, South America) are believed to reflect the {delta}{sup 18}O values of the original magmas. The authors recognize a high {delta}{sup 18}O value type ({delta}{sup 18}O pyroxene {approximately} +10{per thousand}) found in the south of both regions, and a low {delta}{sup 18}O value type ({delta}{sup 18}O pyroxene {approximately} +6.5{per thousand}) found in the north. Other differences between thee two rhyolite types include higher concentrations of incompatible elements and lower initial {sup 87}Sr/{sup 86}Sr ratios in the low {delta}{sup 18}O value type. The authors suggest that the regional distribution of rhyolite types reflects differences in source composition, which can best be explained if the sources are lower crustal, Late Proterozoic mobile belt material (high {delta}{sup 18}O) and Archean lower crust (low {delta}{sup 18}O).

  5. Geochemistry and petrogenesis of volcanic rocks from Daimao Seamount (South China Sea) and their tectonic implications

    NASA Astrophysics Data System (ADS)

    Yan, Quanshu; Castillo, Paterno; Shi, Xuefa; Wang, Liaoliang; Liao, Lin; Ren, Jiangbo

    2015-03-01

    The South China Sea (SCS) experienced three episodes of seafloor spreading and left three fossil spreading centers presently located at 18°N, 17°N and 15.5°N. Spreading ceased at these three locations during magnetic anomaly 10, 8, and 5c, respectively. Daimao Seamount (16.6 Ma) was formed 10 my after the cessation of the 17°N spreading center. Volcaniclastic rocks and shallow-water carbonate facies near the summit of Daimao Seamount provide key information on the seamount's geologic history. New major and trace element and Sr-Nd-Pb isotopic compositions of basaltic breccia clasts in the volcaniclastics suggest that Daimao and other SCS seamounts have typical ocean island basalt-like composition and possess a 'Dupal' isotopic signature. Our new analyses, combined with available data, indicate that the basaltic foundation of Daimao Seamount was formed through subaqueous explosive volcanic eruptions at 16.6 Ma. The seamount subsided rapidly (> 0.12 mm/y) at first, allowing the deposition of shallow-water, coral-bearing carbonates around its summit and, then, at a slower rate (< 0.12 mm/y). We propose that the parental magmas of SCS seamount lavas originated from the Hainan mantle plume. In contrast, lavas from contemporaneous seamounts in other marginal basins in the western Pacific are subduction-related.

  6. Rocks of the Thirtynine Mile volcanic field as possible sources of uranium for epigenetic deposits in central Colorado, USA.

    USGS Publications Warehouse

    Dickinson, K.A.

    1987-01-01

    The most likely volcanic source rock for uranium in epigenetic deposits of the Tallahassee Creek uranium district and nearby areas is the Wall Mountain Tuff. The widespread occurrence of the Tuff, its high apparent original uranium content, approx 11 ppm, and its apparent loss of uranium from devitrification and other alteration suggest its role in providing that element. An estimate of the original Th/U ratio is based on the present thorium and uranium contents of the basal vitrophyre of the Tuff from Castle Rock Gulch, Hecla Junction and other areas.-from Author

  7. Early to Middle Devonian granitic and volcanic rocks from the central Gulf of Maine

    NASA Astrophysics Data System (ADS)

    Barr, Sandra M.; Mortensen, James K.; Thompson, Margaret D.; Hermes, O. Don; White, Chris E.

    2011-10-01

    Cashes Ledge igneous suite in the central Gulf of Maine is represented by 10 granitic and two felsic tuff samples collected from bedrock outcrops using the submersible Alvin in 1971-1972 and archived at the Woods Hole Oceanographic Institute. Laser ablation ICP-MS analyses of zircon grains yielded crystallization ages of 414.9 ± 1.1 Ma and 399.7 ± 1.5 Ma for two alkali feldspar granite samples, 407.0 ± 1.9 Ma for a syenogranite sample, and 384.4 ± 2.3 Ma and 383.9 ± 1.6 Ma for two felsic tuff samples. The samples contain iron-rich mafic minerals, including aegirine-augite, grunerite/ferroedenite, and annite. Most of the samples are alkaline to slightly peralkaline, with high concentrations of SiO 2, Y, Zr, Nb, and REE, strong negative Eu anomalies, and positive epsilon Nd values (1.8 to 3.7). The suite resembles part of a belt of similar Silurian-Devonian rocks with ages between 426 and 370 Ma now recognized in the central part of Avalonia in southeastern New England. They formed in a long-lived, likely extensional regime linked to subduction and subsequent complex transcurrent motions among Ganderia, Avalonia, and Meguma, culminating in the closure of the Rheic Ocean.

  8. Geochronology and geochemistry of the Triassic bimodal volcanic rocks and coeval A-type granites of the Olzit area, Middle Mongolia: Implications for the tectonic evolution of Mongol-Okhotsk Ocean

    NASA Astrophysics Data System (ADS)

    Zhu, Mingshuai; Zhang, Fochin; Miao, Laicheng; Baatar, Munkhtsengel; Anaad, Chimedtseren; Yang, Shunhu; Li, Xingbo

    2016-05-01

    The Olzit volcanism in Middle Mongolia comprises a bimodal suite of basalts and peralkaline rhyolites adjacent to the Main Mongolia Lineament. The basalts are characterized by enrichment in LILE and LREE, and depletion in HFSE with typical Sr-Nd isotopic signatures (εNd(t) = -2.50 to -0.38 and (87Sr/86Sr)i = 0.7058-0.7063), indicating they were likely derived from partial melting of an enriched lithospheric mantle, modified by subducted slab-derived fluids. The rhyolites show a close affinity to A-type granites with enrichment in LILE and LREE, and depletion in Nb, Ta and Ti. They also show a significant negative Eu anomaly, and have εNd(t) values ranging from 0.50 to 1.38 and initial 87Sr/86Sr ratios ranging from 0.7022 to 0.7200, suggesting the rhyolites stem from partial melting of crustal rocks rather than fractional crystallization of the basaltic melt. The rhyolite porphyry yields a SHRIMP zircon U-Pb age of 207 ± 2 Ma (MSWD = 1.42), indicating the bimodal volcanic suite formed in the Late Triassic. The miarolitic per-alkaline granite and biotite-bearing granite, which are associated with the bimodal volcanic rocks, show typical A-type granitic geochemical affinity with εNd(t) = 0.89-0.91 and (87Sr/86Sr)i = 0.7021-0.7043, indicating they are likely generated by partial melting of crustal rocks similar to the rhyolitic end-member of bimodal suite. The miarolitic per-alkaline granite and biotite-bearing granite yielded SHRIMP zircon U-Pb ages of 209 ± 2 Ma (MSWD = 0.91) and 213 ± 3 Ma (MSWD = 1.65) respectively, which are nearly coeval with the age of the bimodal volcanic suites. In view of the new geochemical and chronological data in this study, we suggest the Olzit Late Triassic bimodal volcanic rocks together with the coeval A-type granites represent a back-arc basin extensional environment, which probably related to the roll-back of Mongol-Okhotsk oceanic plate during the southward subduction under the Central Mongolia microcontinent.

  9. Mineral chemical compositions of late Cretaceous volcanic rocks in the Giresun area, NE Turkey: Implications for the crystallization conditions

    NASA Astrophysics Data System (ADS)

    Oǧuz, Simge; Aydin, Faruk; Uysal, İbrahim; Şen, Cüneyt

    2016-04-01

    This contribution contains phenocryst assemblages and mineral chemical data of late Cretaceous volcanic (LCV) rocks from the south of Görele and Tirebolu areas (Giresun, NE Turkey) in order to investigate their crystallization conditions. The LCV rocks in the study area occur in two different periods (Coniasiyen-Early Santonian and Early-Middle Campanian), which generally consist of alternation of mafic-intermediate (basaltic to andesitic) and felsic rock series (dacitic and rhyolitic) within each period. The basaltic and andesitic rocks in both periods generally exhibit porphyritic to hyalo-microlitic porphyritic texture, and contain phenocrysts of plagioclase and pyroxene, whereas the dacitic and rhyolitic rocks of the volcanic sequence usually show a vitrophyric texture with predominant plagioclase, K-feldspar, quartz and lesser amphibole-biotite phenocrysts. Zoned plagioclase crystals of the mafic and felsic rocks in different volcanic periods are basically different in composition. The compositions of plagioclase in the first-stage mafic rocks range from An52 to An78 whereas those of plagioclase from the first-stage felsic rocks have lower An content varying from An38 to An50. Rim to core profile for the zoned plagioclase of the first-stage mafic rocks show quite abrupt and notable compositional variations whereas that of the first-stage felsic rocks show slight compositional variation, although some of the grains may display reverse zoning. On the other hand, although no zoned plagioclase phenocryst observed in the second-stage mafic rocks, the compositions of microlitic plagioclase show wide range of compositional variation (An45‑80). The compositions of zoned plagioclase in the second-stage felsic rocks are more calcic (An65‑81) than those of the first-stage felsic rocks, and their rim to core profile display considerable oscillatory zoning. The compositions of pyroxenes in the first- and second-stage mafic-intermediate rocks vary over a wide range

  10. Comparison of conventional K-Ar and 40Ar/39Ar dating of young mafic volcanic rocks

    USGS Publications Warehouse

    Lanphere, M.A.

    2000-01-01

    K-Ar and 40Ar/39Ar ages have been measured on nine mafic volcanic rocks younger than 1 myr from the Snake River Plain (Idaho), Mount Adams (Washington), and Crater Lake (Oregon). The K-Ar ages were calculated from Ar measurements made by isotope dilution and K2O measurements by flame photometry. The 40Ar/39Ar ages are incremental-heating experiments using a low-blank resistance-heated furnace. The results indicate that high-quality ages can be measured on young, mafic volcanic rocks using either the K-Ar or the 40Ar/39Ar technique. The precision of an 40Ar/39Ar plateau age generally is better than the precision of a K-Ar age because the plateau age is calculated by pooling the ages of several gas increments. The precision of a plateau age generally is better than the precision of an isotope correlation (isochron) age for the same sample. For one sample the intercept of the isochron yielded an 40Ar/36Ar value significantly different from the atmospheric value of 295.5. Recalculation of increment ages using the isochron intercept for the composition of nonradiogenic Ar in the sample resulted in much better agreement of ages for this sample. The results of this study also indicate that, given suitable material and modern equipment, precise K-Ar and 40Ar/39Ar ages can be measured on volcanic rocks as young as the latest Pleistocene, and perhaps even the Holocene.

  11. Petrology and Geochemistry of Hydrothermally Altered Volcanic Rocks in the Iheya North Hydrothermal Field, Middle Okinawa Trough

    NASA Astrophysics Data System (ADS)

    Yamasaki, T.

    2015-12-01

    The Iheya North hydrothermal field is located in the middle Okinawa Trough, a young and actively spreading back-arc basin extending behind the Ryukyu arc-trench system in the southeastern margin of the East China Sea. In this hydrothermal field, two scientific drilling expeditions (IODP Exp 331 and SIP CK14-04) were conducted using a deep-sea drilling vessel "Chikyu," and samples from a total of 27 holes were taken. Through these expeditions, Kuroko-type volcanogenic massive sulfide deposits (VMS), hydrothermally altered volcanic rocks, and pumiceous and pelagic sediments were recovered. The recovered core provided important information about the relationship between hydrothermal activity, alteration, and ore mineralization. Whole-rock major element composition and trace element (TE) patterns of pumices were very similar to those of rhyolites in the middle Okinawa Trough (RMO). However, pumices were relatively enriched in chalcophile elements Sr and Nb, which suggest incipient mineralization. Volcanic rock generally demonstrated strong silicification and was greenish pale gray in color. Regardless of severe alteration, some rock displayed major element composition broadly similar to the RMO. Alteration was evidenced by an increase in the content of SiO2 and MgO, and decrease in Al2O3, Na2O, and K2O content. The most striking geochemical feature of altered volcanic rock was the discordance between texture and the degree of modification of TEs. Some samples showed decussate texture occupied by petal-like quartz with severe silicification, but no prominent disturbance of concentration and patterns of TEs were observed. In contrast, samples with well-preserved igneous porphyritic texture showed very low TE content and modification of TE patterns. These results suggest that the modification of texture and composition of TEs, as well as silicification, do not occur by a uniform process, but several processes. This may reflect the differences in temperature and the

  12. Geology of volcanic and subvolcanic rocks of the Raton-Springer area, Colfax and Union Counties, New Mexico

    SciTech Connect

    Scott, G.R.; Wilcox, R.E.; Mehnert, H.H.

    1990-01-01

    The most prominent geomorphic features of the Raton-Springer area are the widely distributed volcanic and subvolcanic rock formations, consisting of cinder cones, domes, lava-capped mesas, a domed sill complex, and dikes. Rock compositions range from mafic to salic, and many are alkalic. Rock names used in this report are based on the classification of La Roche and others (1980). Sixteen new K-Ar age determinations and three new fission-track age determinations are given here for selected rocks in this area. Reconnaissance geologic mapping of the Springer and Raton 30 feet x 60 feet quadrangles (September 1980 to May 1982) and preparation of the resulting maps provided much field and laboratory data about the igneous rocks of this part of the Great Plains. No published geologic map or report describes adequately the distribution and character of the alkalic rocks of this area. This report presents new descriptive information on field relations, chemical analyses, and K-Ar ages of igneous rocks in the area with the hope that others will be encouraged to investigate the geology of this interesting area in greater detail.

  13. Compilation of Stratigraphic Thicknesses for Caldera-Related Tertiary Volcanic Rocks, East-Central Nevada and West-Central Utah

    USGS Publications Warehouse

    Sweetkind, D.S.; Du Bray, E.A.

    2008-01-01

    The U.S. Geological Survey (USGS), the Desert Research Institute (DRI), and a designee from the State of Utah are currently conducting a water-resources study of aquifers in White Pine County, Nevada, and adjacent areas in Nevada and Utah, in response to concerns about water availability and limited geohydrologic information relevant to ground-water flow in the region. Production of ground water in this region could impact water accumulations in three general types of aquifer materials: consolidated Paleozoic carbonate bedrock, and basin-filling Cenozoic volcanic rocks and unconsolidated Quaternary sediments. At present, the full impact of extracting ground water from any or all of these potential valley-graben reservoirs is not fully understood. A thorough understanding of intermontane basin stratigraphy, mostly concealed by the youngest unconsolidated deposits that blanket the surface in these valleys, is critical to an understanding of the regional hydrology in this area. This report presents a literature-based compilation of geologic data, especially thicknesses and lithologic characteristics, for Tertiary volcanic rocks that are presumably present in the subsurface of the intermontane valleys, which are prominent features of this area. Two methods are used to estimate volcanic-rock thickness beneath valleys: (1) published geologic maps and accompanying descriptions of map units were used to compile the aggregate thicknesses of Tertiary stratigraphic units present in each mountain range within the study areas, and then interpolated to infer volcanic-rock thickness in the intervening valley, and (2) published isopach maps for individual out-flow ash-flow tuff were converted to digital spatial data and thickness was added together to produce a regional thickness map that aggregates thickness of the individual units. The two methods yield generally similar results and are similar to volcanic-rock thickness observed in a limited number of oil and gas exploration

  14. Borosilicate alteration associated with U-Mo-Zn and Ag-Au-Zn deposits in volcanic rocks

    NASA Astrophysics Data System (ADS)

    Fuchs, Y.; Maury, R.

    1995-10-01

    Borosilicate alteration is developed in many uranium-molybdenum-zinc deposits in volcanic piles such as at Novazza (Italy), Novoveska Huta (Slovakia), Ben Lomond (Queensland, Australia), the Saar-Nahe basin (Germany), the Shengyuan district (China), and at many deposits in Russia. These uranium-molybdenum-zinc deposits share similar styles of alteration with silver-gold-zinc deposits in volcanic rocks, like those of the Humboldt Range (Nevada, USA), the Basin district (Montana, USA) and Equity Mine (British Columbia, Canada). In thick volcanic piles, fluid-rock interaction commonly develops under the influence of convective hydrothermal systems. In borosilicate-bearing systems the alteration is characterized by changes in borosilicate mineralogy and chemistry under mesothermal conditions. Zonal distribution of different compositions of tourmaline can be observed including regular increases of alkali deficiency in the X(3a) site from peripheral (chlorite-epidote-prehnite) to internal (sericite and/or pyrophyllite) alteration zones. In the central part of these systems tourmaline is absent and the alteration assemblage is characterized by an andalusitedumortierite-quartz association. Such changes in mineral assemblage are related to an increase in temperature from 250 to 350 400 °C and to decreases in pH and Eh, from the outer toward the inner parts of the hydrothermal system. The zonation of the borosilicate-bearing alteration systems is similar to that of aluminosilicate-bearing hydrothermal systems (muscovite, pyrophyllite, andalusite) developed in volcanic rocks. A kaolinite-alunitejasperoid assemblage is generally associated with the borosilicate alteration, and seems related to a late hydrothermal phase mainly located in graben structures.

  15. Geomagnetic Secular Variation Recorded in Volcanic Rocks: The End of the Geocentric Axial Dipole

    NASA Astrophysics Data System (ADS)

    Champion, D. E.; Turrin, B. D.; Robinson, J. E.

    2015-12-01

    Most paleomagnetic textbooks ascribe secular variation (SV) to the movement and waxing/waning of non-dipole magnetic features in the fluid core, perhaps joined by wobble of a geocentric axial dipole (GAD). The actuality of a GAD is profoundly limited by the existence of the static, solid inner core, and the dynamic nature of the fluid outer core. A study of >560 Brunhes Epoch Virtual Geomagnetic Poles (VGP) suggests that geomagnetic field behavior arises from the waxing/waning of three approximately "stationary" offset dipoles (OD) situated in the middle of the ring of the outer core. These OD have been loosely fixed to preferred longitudes of 40°E, 120°E, and 280°E for at least the past 17Ma. The three offset dipoles in these positions determine transitional and excursional paths, and also normal SV. An extended literature documents these longitude corridors as paths of preferred VGP movement, guided by the polarity inversion of one of the three OD. Analysis of volcanic rock and archeomagnetic SV records shows a three-fold symmetric movement of local magnetic directions, guided by the variation in strength of the three OD. Preliminary data indicates that in the recent past the dominant OD at a given time yields to the next OD in movement toward greater east longitude. The frequency of OD dominance exchange is ~400 years, with return to the original OD in ~1200 years. Archeomagnetic "jerks", not easily explained by a single dominant, inertial GAD, are more easily understood with 3 waxing/waning and exchanging OD. The particular analysis of Hawaiian SV with regard to the three OD suggests that tropical locales, far from the three spin axis-parallel OD, may still record true non-dipole influences.

  16. Ship Rock Diatreme: is it a Classical Volcano? New Evidence on Magma Ascent and Emplacement Within the Navajo Volcanic Field

    NASA Astrophysics Data System (ADS)

    Rotzien, J. R.; Mayhew, B.; Yospin, S.; Beiki, A.; Tewksbury, C.; Hardman, D.; Bank, C.; Noblett, J.; Semken, S.; Kroeger, G.

    2007-12-01

    The Navajo Volcanic Field (NVF) is an area of late-Tertiary volcanism along the New Mexico-Arizona border near the Four Corners region of the American Southwest. Among the roughly 80 exhumed diatremes that comprise the NVF, Ship Rock and The Thumb are two diatremes that present an interesting problem concerning magma ascent and emplacement within the NVF. Are the diatremes remnants of classical volcanoes with underlying magma chambers, or are the diatremes formed from buds off of upward propagating dike swarms? The 2006 Keck Consortium Geophysics Project collected non-invasive gravity and magnetic data to image the subsurface of Ship Rock and The Thumb to suggest constraints concerning the formation of these diatremes within the Navajo Volcanic Field. At Ship Rock, we collected over 120 gravity points spaced 500 m apart along 10 lines. We also collected about 65,000 magnetic points that cover an area of 1,570,000 square meters surrounding Ship Rock. The gravity data reveal gravity lows several kilometers away from Ship Rock, probably as a result of thick sedimentary units close to the surface. A steep gradient of 5 mGal/km separates the gravity lows from a strong gravity high immediately to the southwest of Ship Rock. We interpret this gravity high to be uneven basement topography or a magma chamber at depth; further studies are required to determine which of the interpretations is more likely. The Ship Rock magnetic data show the prominent west and northeast dikes extend well beyond their surface outcrops while the southern dike extends only to its visible termination. The magnetic data we collected at The Thumb along ~18 km of lines reveal a linear northeast-southwest trending magnetic anomaly about 105 to 360 nT in amplitude that crosses the diatreme. We interpret the anomaly to be a dike beneath The Thumb. Models of the total field magnetic data suggest a dike at shallow depths of about 0.1 to 4.8 m and widths of about 0.25 to 1.5 m with a steep dip to the

  17. Mapping argillic and advanced argillic alteration in volcanic rocks, quartzites, and quartz arenites in the western Richfield 1° x 2 ° quadrangle, southwestern Utah, using ASTER satellite data

    USGS Publications Warehouse

    Rockwell, Barnaby W.; Hofstra, Albert H.

    2012-01-01

    The Richfield quadrangle in southwestern Utah is known to contain a variety of porphyry Mo, skarn, polymetallic replacement and vein, alunite, and kaolin resources associated with 27-32 Ma calc-alkaline or 12-23 Ma bimodal volcano-plutonic centers in Neoproterozoic to Mesozoic carbonate and siliciclastic rocks. Four scenes of visible to shortwave-infrared image data acquired by the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) sensor were analyzed to generate maps of exposed clay, sulfate, mica, and carbonate minerals, and ASTER thermal infrared data were analyzed to identify quartz and carbonate minerals. Argillic and advanced argillic alteration minerals including alunite, pyrophyllite, dickite, and kaolinite were identified in both undocumented (U) and known (K) areas, including in the southern Paradise Mtns. (U); in calc-alkaline volcanic rocks in the Wah Wah Mtns. between Broken Ridge and the NG area (U/K); at Wah Wah Summit in a small zone adjacent to 33.1 Ma diorite and marble (U); in fractures cutting quartzites surrounding the 20-22 Ma Pine Grove Mo deposit (U); in volcanic rocks in the Shauntie Hills (U/K); in quartzites in the west-central San Francisco Mtns. (U); in volcanic rocks in the Black Mtns. (K); and in mainly 12-13 Ma rhyolitic rocks along a 20 km E-W belt that includes the Bible Spring fault zone west of Broken Ridge, with several small centers in the Escalante Desert to the south (U/K). Argillized Navajo Sandstone with kaolinite and (or) dickite ± alunite was mapped adjacent to calc-alkaline intrusions in the Star Range (U). Intense quartz-sericite alteration (K) with local kaolinite was identified in andesite adjacent to calc-alkaline intrusions in the Beaver Lake Mountains. Mo-bearing phyllic alteration was identified in 22.2 Ma rhyolite plugs at the center of the NG alunite area. Limestones, dolomites, and marbles were differentiated, and quartz and sericite were identified in most unaltered quartzites. Halos of

  18. Petrogenesis of siliceous high-Mg series rocks as exemplified by the Early Paleoproterozoic mafic volcanic rocks of the Eastern Baltic Shield: enriched mantle versus crustal contamination

    NASA Astrophysics Data System (ADS)

    Bogina, Maria; Zlobin, Valeriy; Sharkov, Evgenii; Chistyakov, Alexeii

    2015-04-01

    The Early Paleoproterozoic stage in the Earth's evolution was marked by the initiation of global rift systems, the tectonic nature of which was determined by plume geodynamics. These processes caused the voluminous emplacement of mantle melts with the formation of dike swarms, mafic-ultramafic layered intrusions, and volcanic rocks. All these rocks are usually considered as derivatives of SHMS (siliceous high-magnesian series). Within the Eastern Baltic Shield, the SHMS volcanic rocks are localized in the domains with different crustal history: in the Vodlozero block of the Karelian craton with the oldest (Middle Archean) crust, in the Central Block of the same craton with the Neoarchean crust, and in the Kola Craton with a heterogeneous crust. At the same time, these rocks are characterized by sufficiently close geochemical characteristics: high REE fractionation ((La/Yb)N = 4.9-11.7, (La/Sm)N=2.3-3.6, (Gd/Yb)N =1.66-2.74)), LILE enrichment, negative Nb anomaly, low to moderate Ti content, and sufficiently narrow variations in Nd isotope composition from -2.0 to -0.4 epsilon units. The tectonomagmatic interpretation of these rocks was ambiguous, because such characteristics may be produced by both crustal contamination of depleted mantle melts, and by generation from a mantle source metasomatized during previous subduction event. Similar REE patterns and overlapping Nd isotope compositions indicate that the studied basaltic rocks were formed from similar sources. If crustal contamination en route to the surface would play a significant role in the formation of the studied basalts, then almost equal amounts of contaminant of similar composition are required to produce the mafic rocks with similar geochemical signatures and close Nd isotopic compositions, which is hardly possible for the rocks spaced far apart in a heterogeneous crust. This conclusion is consistent with analysis of some relations between incompatible elements and their ratios. In particular, the

  19. A typical cross section based on magnetic data of lower and middle Keweenawan volcanic rocks, Ironwood area, Michigan

    USGS Publications Warehouse

    King, Elizabeth R.

    1975-01-01

    A north-trending aeromagnetic profile of a sequence of east-striking Keweenawan volcanic rocks near Ironwood, Mich., can be matched to a calculated profile over a model consisting of a series of dipping layers. (The dips were those measured by H. A. Hubbard along the north-trending valley of the Black River.) Remanent and induced magnetizations of 39 oriented cores from the Black River valley were determined by K. G. Books; felsite from Chippewa Hill and basalt from Algonquin Falls of middle Keweenawan age have normal Keweenawan magnetization and lower Keweenawan Powder Mill rocks have reverse magnetization. In the model these magetizations were assigned to 26 layers which alternated with very weakly magnetized layers. The best match of the calculated composite anomalies of remanent and induced magnetization and the aeromagnetic profile occurs if a deeper block of steeply dipping Powder Mill rocks is assumed to underlie the middle Keweenawan flows.

  20. Distribution of anomalously high K2O volcanic rocks in Arizona: metasomatism at the Picacho Peak detachment fault.

    USGS Publications Warehouse

    Brooks, W.E.

    1986-01-01

    Metasomatized Tertiary lavas with anomalously high K2O and lower Na2O content are distributed within the NW-trending extensional terrain of SW Arizona. These rocks are common near core-complex-related detachment faults at Picacho Peak and the Harcuvar Mountains and in listric-faulted terrain at the Vulture Mountains. These rocks are also enriched in Zr but depleted in MgO. Fine-grained, euhedral orthoclase (adularia) is the dominant K-mineral; other secondary introduced minerals are quartz and calcite. Spatial association of metasomatism with the detachment faults suggests that detachment provided a conduit for hydrothermal fluids that altered the initial chemistry of the Tertiary volcanics and charged the upper plate rocks with mineralizing fluids that carried Zr and Ba, along with Au, Ag and Cu during detachment 17-18 m.y. ago.-L.C.H.

  1. Trace element partitioning in rock forming minerals of co-genetic, subduction-related alkaline and tholeiitic mafic rocks in the Ural Mountains, Russia

    NASA Astrophysics Data System (ADS)

    Krause, J.; Brügmann, G. E.; Pushkarev, E. V.

    2009-04-01

    The partitioning of trace elements between rock forming minerals in igneous rocks is largely controlled by physical and chemical parameters e.g. temperature, pressure and chemical composition of the minerals and the coexisting melt. In the present study partition coefficients for REE between hornblende, orthopyroxene, feldspars, apatite and clinopyroxene in a suite of co-genetic alkaline and tholeiitic mafic rocks from the Ural Mountains (Russia) were calculated. The results give insights to the influence of the chemical composition of the parental melt on the partitioning behaviour of the REE. Nepheline-bearing, alkaline melanogabbros (tilaites) are assumed to represent the most fractionated products of the melt that formed the ultramafic cumulates in zoned mafic-ultramafic complexes in the Ural Mountains. Co-genetic with the latter is a suite of olivine gabbros, gabbronorites and hornblende gabbros formed from a tholeiitic parental melt. Negative anomalies for the HFSE along with low Nb and Ta contents and a positive Sr anomaly indicate a subduction related origin of all parental melts. The nepheline gabbros consist predominantly of coarse-grained clinopyroxene phenocrysts in a matrix of fine grained clinopyroxene, olivine, plagioclase, K-feldspar and nepheline with accessory apatite. The tholeiitic gabbros have equigranular to porphyric textures with phenocrysts of olivine, pyroxene and hornblende in a plagioclase rich matrix with olivine hornblende, pyroxene and accessory apatite. Element concentrations of adjacent matrix grains and rims of phenochrysts were measured with LA-ICPMS. The distribution of REE between hornblende and clinopyroxene in the tholeiitic rocks is similar for most of the elements (DHbl•Cpx(La-Tm) = 2.7-2.8, decreasing to 2.6 and 2.4 for Yb and Lu, respectively). These values are about two times higher than published data (e.g. Ionov et al. 1997). Partition coefficients for orthopyroxene/clinopyroxene systematically decrease from the HREE

  2. Whole rock major element chemistry of KREEP basalt clasts in lunar breccia 15205: Implications for the petrogenesis of volcanic KREEP basalts

    NASA Technical Reports Server (NTRS)

    Vetter, Scott K.; Shervais, John W.

    1993-01-01

    KREEP basalts are a major component of soils and regolith at the Apollo 15 site. Their origin is controversial: both endogenous (volcanic) and exogenous (impact melt) processes have been proposed, but it is now generally agreed that KREEP basalts are volcanic rocks derived from the nearby Apennine Bench formation. Because most pristine KREEP basalts are found only as small clasts in polymict lunar breccias, reliable chemical data are scarce. The primary aim of this study is to characterize the range in chemical composition of pristine KREEP basalt, and to use these data to decipher the petrogenesis of these unique volcanic rocks.

  3. Lower Cryogenian calc-alkaline mafic rocks of the Western Anti-Atlas (Morocco): An example of orogenic-like magmatism in an extensional setting

    NASA Astrophysics Data System (ADS)

    El Aouli, El Hassan; Gasquet, Dominique; Cheilletz, Alain

    2010-08-01

    The lower Cryogenian mafic magmatism from the Igherm, Ifni and Kerdous inliers (Moroccan Western Anti-Atlas) have calc-alkaline, tholeiitic and alkaline affinities. The calc-alkaline dolerite dykes and gabbros bodies emplaced before the conglomeratic formations of the Upper Cryogenian and after the tholeiitic mafic rocks that characterize the pre-Pan-African rifting. They are similar to rocks from orogenic setting and characterized by high LILE, Th, Ce, P, Sm contents and La/Nb ratio and a low HFSE content with negative anomalies in Nb, Zr and Ti. The geodynamic environment of the sedimentary country rocks corresponds to that of a passive margin in a distensive tectonic context. The calc-alkaline affinity of these magmas can be attributed to the influence of a Palaeoproterozoic subduction zone that contributed to the enrichment of the sub-continental mantle. During the extensional event of the Pan-African orogenesis, the mantle would have produced tholeiitic, alkaline and/or transitional magmas before melting (caused by adiabatic decompression) reached the enriched sub-continental mantle. This mantle was previously enriched during the Eburnean subduction, where it would have generated calc-alkaline magmas.

  4. Experiments and Spectral Studies of Martian Volcanic Rocks: Implications for the Origin of Pathfinder Rocks and Soils

    NASA Technical Reports Server (NTRS)

    Rutherford, Malcolm J.; Mustard, Jack; Weitz, Catherine

    2002-01-01

    The composition and spectral properties of the Mars Pathfinder rocks and soils together with the identification of basaltic and andesitic Mars terrains based on Thermal Emission Spectrometer (TES) data raised interesting questions regarding the nature and origin of Mars surface rocks. We have investigated the following questions: (1) are the Pathfinder rocks igneous and is it possible these rocks could have formed by known igneous processes, such as equilibrium or fractional crystallization, operating within SNC magmas known to exist on Mars? If it is possible, what P (depth) and PH2O conditions are required? (2) whether TES-based interpretations of plagioclase-rich basalt and andesitic terrains in the south and north regions of Mars respectively are unique. Are the surface compositions of these regions plagioclase-rich, possibly indicating the presence of old AI-rich crust of Mars, or are the spectra being affected by something like surface weathering processes that might determine the spectral pyroxene to plagioclase ratio?

  5. Halogen content in Lesser Antilles arc volcanic rocks : exploring subduction recycling

    NASA Astrophysics Data System (ADS)

    Thierry, Pauline; Villemant, Benoit; Caron, Benoit

    2016-04-01

    Halogens (F, Cl, Br and I) are strongly reactive volatile elements which can be used as tracers of igneous processes, through mantle melting, magma differentiation and degassing or crustal material recycling into mantle at subduction zones. Cl, Br and I are higly incompatible during partial melting or fractional cristallization and strongly depleted in melts by H2O degassing, which means that no Cl-Br-I fractionation is expected through magmatic differenciation [current thesis]. Thus, Cl/Br/I ratios in lavas reflect the halogen content of their mantle sources. Whereas these ratios seemed quite constant (e.g. Cl/Br =300 as seawater), recent works suggest significant variations in arc volcanism [1,2]. In this work we provide high-precision halogen measurements in volcanic rocks from the recent activity of the Lesser Antilles arc (Montserrat, Martinique, Guadeloupe, Dominique). Halogen contents of powdered samples were determined through extraction in solution by pyrohydrolysis and analysed by Ion Chromatography for F and Cl and high performance ICP-MS (Agilent 8800 Tripe Quad) for Cl, Br and I [3,4]. We show that lavas - and mantle sources - display significant vraiations in Cl/Br/I ratios along the Lesser Antilles arc. These variations are compared with Pb, Nd and Sr isotopes and fluid-mobile elements (Ba, U, Sr, Pb etc.) compositions which vary along the arc from a nothern ordinary arc compositions to a southern 'crustal-like' composition [5,6]. These characteristics are attributed to subducted sediments recycling into the mantle wedge, whose contribution vary along the arc from north to south [7,8]. The proportion of added sediments is also related to the distance to the trench as sediment melting and slab dehydration may occur depending on the slab depth [9]. Further Cl-Br-I in situ measurements by LA-ICP-MS in Lesser Antilles arc lavas melt inclusions will be performed, in order to provide better constraints on the deep halogen recycling cycle from crust to

  6. Porosity and permeability in volcanic rocks: a case study on the Serie Tobı´fera, South Patagonia, Argentina

    NASA Astrophysics Data System (ADS)

    Sruoga, P.; Rubinstein, N.; Hinterwimmer, G.

    2004-04-01

    The Middle to Late Jurassic Serie Tobı´fera belongs to the Chon-Aike Province and extends all over Patagonia and the Antarctic Peninsula. It consists largely of ignimbrites, epiclastics and rhyolitic lavas and was considered only a minor reservoir rock for oil with fracture permeability. Petrographic and petrophysical data in selected core samples from the Austral Basin were collected to determine the processes controlling the porosity and permeability of these volcanic rocks. The sequence of processes occurring during cooling and in the post-cooling stages can modify, sometimes substantially, their original petrophysic characteristics. The results show that the highest porosity and permeability occur in rocks with quench fractured glasses and in non-welded ignimbrites with gas-pipe structures, followed by autobrecciated rhyolites. Welded ignimbrites, massive glasses and fresh rhyolites have the lowest permeabilities. The new data indicate that tectonic fracturing is not as significant as was considered before and application of these concepts are relevant in the assesment of volcanic reservoir quality.

  7. A Special Issue (Part-II): Mafic-ultramafic rocks and alkaline-carbonatitic magmatism and associated hydrothermal mineralization - dedication to Lia Nikolaevna Kogarko

    NASA Astrophysics Data System (ADS)

    Kogarko, Lia N.; Gwalani, Lalchand G.; Downes, Peter J.; Randive, Kirtikumar R.

    2015-10-01

    This is the second part of a two-volumespecial issue of Open Geoscience (formerly Central European Journal of Geosciences) that aims to be instrumental in providing an update of Mafic-Ultramafic Rocks and Alkaline- Carbonatitic Magmatism and Associated Hydrothermal Mineralization. Together, these two volumes provide a detailed and comprehensive coverage of the subjects that are relevant to the research work of P.Comin-Chiaramonti (Italy) and LiaN. Kogarko (Russia) towhomPart-I and Part- II have been respectively dedicated. To a significant extent, the development of advanced sampling technologies related to alkaline and carbonatitic magmatism by Lia N. Kogarko, has allowed geoscientists to measure and sample the deep crust of the planet not only for the exploration for the mineral deposits, but also to answer basic scientific questions about the origin and evolution of alkaline rocks (kimberlites, lamproites and related rocks associated with carbonatites). The papers presented in this Part-II of the special issue cover the petrology and geochemistry of the rocks collected from the surface and penetrated by drilling. Lia Kogarko proposed a new theory for the evolution of alkaline magmatism in the geological history of the Earth - that the appearance of alkaline magmatism at the Archaean-Proterozoic boundary (~2.5 - 2.7 Ga), and its growing intensity, was related to changes in the geodynamic regime of the Earth and oxidation of the mantle due to mantle-crust interaction.

  8. Application of support vector machines and relevance vector machines in predicting uniaxial compressive strength of volcanic rocks

    NASA Astrophysics Data System (ADS)

    Ceryan, Nurcihan

    2014-12-01

    The uniaxial compressive strength (UCS) of intact rocks is an important and pertinent property for characterizing a rock mass. It is known that standard UCS tests are destructive, expensive and time-consuming task, which is particularly true for thinly bedded, highly fractured, foliated, highly porous and weak rocks. Consequently, prediction models have become an attractive alternative for engineering geologists. In the last several years, a new, alternative kernel-based technique, support vector machines (SVMs), has been popular in modeling studies. Despite superior SVM performance, this technique has certain significant, practical drawbacks. Hence, the relevance vector machines (RVMs) approach has been proposed to recast the main ideas underlying SVMs in a Bayesian context. The primary purpose of this study is to examine the applicability and capability of RVM and SVM models for predicting the UCS of volcanic rocks from NE Turkey and comparing its performance with ANN models. In these models, the porosity and P-durability index representing microstructural variables are the input parameters. The study results indicate that these methods can successfully predict the UCS for the volcanic rocks. The SVM and RVM performed better than the ANN model. When these kernel based models are considered, RVM model found successful in terms of statistical performance criterions (e.g., performance index, PI values for training and testing data are computed as 1.579 and 1.449). These values for SVM are 1.509 and 1.307. Although SVM and RVM models are powerful techniques, the RVM run time was considerably faster, and it yielded the highest accuracy.

  9. Analysis of Micro-Seismic Signals and Source Parameters of Eruptions Generated by Rapid Decompression of Volcanic Rocks

    NASA Astrophysics Data System (ADS)

    Arciniega-Ceballos, A.; Alatorre-Ibarguengoitia, M. A.; Scheu, B.; Dingwell, D. B.; Delgado Granados, H.

    2010-12-01

    Seismic evaluation of well-controlled experimental volcanic simulations offers the hope of a better understanding of source mechanisms in natural volcanic seismicity. Here, we have performed the first investigation of the dynamics of explosive volcanic eruption of magma under controlled laboratory conditions. Specifically, we analyzed the micro-seismicity generated by the rapid depressurization of volcanic rocks in a shock tube apparatus, which represents the seismic mechanism. The source parameters and the force system have been analyzed considering the relationship F=πr2 Po. Our well-constrained physical mechanism consists of the slow pressurization of the system (using Argon gas) followed by rapid depressurization of natural volcanic samples (ash, pumice and fragmented particles of pumice) contained in a steel pipe-like conduit of radius r and height ~2r. Several experiments with samples with different porosities were performed under controlled pressure conditions (ranging from 4 to 20 MPa), at room temperature. We calculated the magnitude of the vertical and downward forces and forces at the walls of the reservoir, and the kinetic energy involved during decompression and fragmentation processes from the micro-seismic signals detected at several points in the apparatus using highly dynamic piezo-film transducers. We first characterized the frequencies of the apparatus in order to distinguish in the signals between the waves produced by the natural resonance of the system due to the pressure shock and the waves generated by the rapid depressurization of the samples. In the micro-seismic records the inflation-deflation states of the pipe-like conduit and the fragmentation process after the rapid removal of the diaphragm can be recognized clearly. The decompression time is directly measured from the pressure drop curves of the system recorded by dynamic pressure transducers and correlates well with the duration of maximum amplitudes of micro-seismic waves

  10. Geochemical Characteristics of Volcanic Rocks from the Southern Okinawa Trough and its Implications for Tectono-magmatic Evolution

    NASA Astrophysics Data System (ADS)

    Shinjo, R.; Hokakubo, S.; Haraguchi, S.; Matsumoto, T.; Woodhead, J.

    2003-12-01

    The Okinawa Trough is a site of ongoing backarc rifting behind the Ryukyu arc-trench system. Recent intensive surveys, including submersible dives, at the southern Okinawa Trough (SOT) have revealed details of bathymetric, geological, and geophysical features. Here, we present the petrological and geochemical characteristics of volcanic rocks collected during these cruises, and discuss its relation to the evolutionary stage of rifting. Based on bathymetirc and magmatic features, SOT can be divided into two (i.e., eastern and western) segments with non-transform offset at ˜ 123.5° E. The eastern segment represents a well-developed rift system with E-W-trending central graben and separated NE-SW-trending volcanic front; these two features merge at ˜ 125° E. In contrast, the western segment is in the incipient rifting stage; rift axis exists close to 100 km contour of the Wadati-Benioff zone. The most notable feature is the presence of 'abnormal' volcanic chain (Cross Backarc Volcanic Trail, CBVT), which trends NE-SW and is obviously oblique to the axial trend. All rocks are subalkaline, but range from basalt to rhyolite; dacite-rhyolite are dominant in the eastern volcanic front and CBVT. Basalts from both segments are low-K tholeiites; they have high abundance of LILEs relative to HFSEs, negative Nb anomalies on MORB-normalized diagrams, and range of 143Nd/144Nd (0.5128-0.5129) and 87Sr/86Sr (0.7034-0.7048). Pb isotope systematics indicate 206Pb/204Pb=18.398-18.582, 207Pb/204Pb=15.594-15.652 and 208Pb/204Pb=38.570-38.912, clearly above the Northern Hemisphere Reference Line. These elemental and isotopic variations are compatible with derivation from Indian Ocean MORB-like mantle with strong overprint of subduction components from the slab. There is clear difference among more felsic rocks between two segments. At similar silica contents, most of felsic rocks from the western segment, including CBVT rhyolites, have higher LILE contents, 87Sr/86Sr and 208Pb/204Pb

  11. Experimental and textural constraints on mafic enclave formation in volcanic rocks

    NASA Astrophysics Data System (ADS)

    Coombs, Michelle L.; Eichelberger, John C.; Rutherford, Malcolm J.

    2003-01-01

    We have used experiments and textural analysis to investigate the process of enclave formation during magma mixing at Southwest Trident volcano, Alaska. Andesite enclaves are present throughout the four dacite lava flows produced by the eruption, and resemble mafic enclaves commonly found in other volcanic rocks. Our experiments replicate the pressure-temperature-time path taken by enclave-forming andesite magma as it is engulfed in dacite during magma mixing. Pressure and temperature information for the andesite and dacite are from [Coombs et al., Contrib. Mineral. Petrol. 140 (2000) 99-118]. The andesite was annealed at 1000°C, and then cooled to 890°C at rates of 110°C h -1, 10°C h -1, and 2°C h -1. Once cooled to 890°C, andesite was held at this lower temperature from times ranging from 1 to 40 h. The andesite that was cooled at the slower rates of 2°C h -1 and 10°C h -1 most resembles enclave groundmass texturally and compositionally. Based on simple thermal calculations, these rates are more consistent with cooling of the andesite groundmass below an andesite-dacite interface than with cooling of enclave-sized spheres. If enclaves do crystallize as spheres, post-crystallization disaggregation must occur. Calculations using the MELTS algorithm [Ghiorso and Sack, Contrib. Mineral. Petrol. 119 (1995) 197-212] show that for incoming andesite to become less dense than the dacite ˜34 volume % of its groundmass must crystallize to undergo ˜18 volume % vesiculation; these values are similar to those determined for Southwest Trident enclaves. Thus such crystallization may lead to 'flotation' of enclaves and be a viable mechanism for enclave formation and dispersal. The residual melt in the cooling experiments did not evolve to rhyolitic compositions such as seen in natural enclaves due to a lack of a decompression step in the experiments. Decompression experiments on Southwest Trident dacite suggest an average ascent rate for the eruption of ˜2-3 MPa h -1

  12. Experimental and textural constraints on mafic enclave formation in volcanic rocks

    USGS Publications Warehouse

    Coombs, M.L.; Eichelberger, J.C.; Rutherford, M.J.

    2002-01-01

    We have used experiments and textural analysis to investigate the process of enclave formation during magma mixing at Southwest Trident volcano, Alaska. Andesite enclaves are present throughout the four dacite lava flows produced by the eruption, and resemble mafic enclaves commonly found in other volcanic rocks. Our experiments replicate the pressure-temperature-time path taken by enclave-forming andesite magma as it is engulfed in dacite during magma mixing. Pressure and temperature information for the andesite and dacite are from [Coombs et al., Contrib. Mineral. Petrol. 140 (2000) 99-118]. The andesite was annealed at 1000??C, and then cooled to 890??C at rates of 110??C h1, 10??C h1 and 2??C h1. Once cooled to 890??C, andesite was held at this lower temperature from times ranging from 1 to 40 h. The andesite that was cooled at the slower rates of 2??C h1 and 10??C h1 most resembles enclave groundmass texturally and compositionally. Based on simple thermal calculations, these rates are more consistent with cooling of the andesite groundmass below an andesite-dacite interface than with cooling of enclave-sized spheres. If enclaves do crystallize as spheres, post-crystallization disaggregation must occur. Calculations using the MELTS algorithm [Ghiorso and Sack, Contrib. Mineral. Petrol. 119 (1995) 197-212] show that for incoming andesite to become less dense than the dacite to become less dense ???34 volume % of its groundmass must crystallize to undergo~18 volume % vesiculation; these values are similar to those determined for Southwest Trident enclaves. Thus such crystallization may lead to 'flotation' of enclaves and be a viable mechanism for enclave formation and dispersal. The residual melt in the cooling experiments did not evolve to rhyolitic compositions such as seen in natural enclaves due to a lack of a decompression step in the experiments. Decompression experiments on Southwest Trident dacite suggest an average ascent rate for the eruption of ???2

  13. Geology, thermal maturation, and source rock geochemistry in a volcanic covered basin: San Juan sag, south-central Colorado

    SciTech Connect

    Gries, R.R.; Clayton, J.L.; Leonard, C.

    1997-07-01

    The San Juan sag, concealed by the vast San Juan volcanic field of south-central Colorado, has only recently benefited from oil and gas wildcat drilling and evaluations. Sound geochemical analyses and maturation modeling are essential elements for successful exploration and development. Oil has been produced in minor quantities from an Oligocene sill in the Mancos Shale within the sag, and major oil and gas production occurs from stratigraphically equivalent rocks in the San Juan basin to the southwest and in the Denver basin to the northeast. The objectives of this study were to identify potential source rocks, assess thermal maturity, and determine hydrocarbon-source bed relationships. Source rocks are present in the San Juan sag in the upper and lower Mancos Shale (including the Niobrara Member), which consists of about 666 m (2184 ft) of marine shale with from 0.5 to 3.1 wt. % organic carbon. Pyrolysis yields (S{sub 1} + S{sub 2} = 2000-6000 ppm) and solvent extraction yields (1000-4000 ppm) indicate that some intervals within the Mancos Shale are good potential source rocks for oil, containing type II organic matter, according to Rock-Eval pyrolysis assay.

  14. Preparation of Al-Si Master Alloy by Electrochemical Reduction of Volcanic Rock in Cryolite Molten Salt

    NASA Astrophysics Data System (ADS)

    Liu, Aimin; Shi, Zhongning; Xu, Junli; Hu, Xianwei; Gao, Bingliang; Wang, Zhaowen

    2016-06-01

    Volcanic rock found in the Longgang Volcano Group in Jilin Province of China has properties essentially similar to Apollo lunar soils and previously prepared lunar soil simulants, such as Johnson Space Center Lunar simulant and Minnesota Lunar simulant. In this study, an electrochemical method of preparation of Al-Si master alloy was investigated in 52.7 wt.%NaF-47.3 wt.%AlF3 melt adding 5 wt.% volcanic rock at 1233 K. The cathodic electrochemical process was studied by cyclic voltammetry, and the results showed that the cathodic reduction of Si(IV) is a two-step reversible diffusion-controlled reaction. Si(IV) is reduced to Si(II) by two electron transfers at -1.05 V versus platinum quasi-reference electrode in 52.7 wt.%NaF-47.3 wt.%AlF3 molten salt adding 5 wt.% volcanic rock, while the reduction peak at -1.18 V was the co-deposition of aluminum and silicon. In addition, the cathodic product obtained by galvanostatic electrolysis for 4 h was analyzed by means of x-ray diffraction, x-ray fluorescence, scanning electron microscopy and energy dispersive spectrometry. The results showed that the phase compositions of the products are Al, Si, Al5FeSi, and Al3.21Si0.47, while the components are 90.5 wt.% aluminum, 4.4 wt.% silicon, 1.9 wt.% iron, and 0.2 wt.% titanium.

  15. Preparation of Al-Si Master Alloy by Electrochemical Reduction of Volcanic Rock in Cryolite Molten Salt

    NASA Astrophysics Data System (ADS)

    Liu, Aimin; Shi, Zhongning; Xu, Junli; Hu, Xianwei; Gao, Bingliang; Wang, Zhaowen

    2016-04-01

    Volcanic rock found in the Longgang Volcano Group in Jilin Province of China has properties essentially similar to Apollo lunar soils and previously prepared lunar soil simulants, such as Johnson Space Center Lunar simulant and Minnesota Lunar simulant. In this study, an electrochemical method of preparation of Al-Si master alloy was investigated in 52.7 wt.%NaF-47.3 wt.%AlF3 melt adding 5 wt.% volcanic rock at 1233 K. The cathodic electrochemical process was studied by cyclic voltammetry, and the results showed that the cathodic reduction of Si(IV) is a two-step reversible diffusion-controlled reaction. Si(IV) is reduced to Si(II) by two electron transfers at -1.05 V versus platinum quasi-reference electrode in 52.7 wt.%NaF-47.3 wt.%AlF3 molten salt adding 5 wt.% volcanic rock, while the reduction peak at -1.18 V was the co-deposition of aluminum and silicon. In addition, the cathodic product obtained by galvanostatic electrolysis for 4 h was analyzed by means of x-ray diffraction, x-ray fluorescence, scanning electron microscopy and energy dispersive spectrometry. The results showed that the phase compositions of the products are Al, Si, Al5FeSi, and Al3.21Si0.47, while the components are 90.5 wt.% aluminum, 4.4 wt.% silicon, 1.9 wt.% iron, and 0.2 wt.% titanium.

  16. Geologic and grade-tonnage information on Tertiary epithermal precious- and base-metal vein districts associated with volcanic rocks

    USGS Publications Warehouse

    Mosier, Dan L.; Menzie, W. David; Kleinhampl, Frank J.

    1986-01-01

    Data on grades, tonnages, and geology of selected Tertiary epithermal precious- and base-metal vein districts associated with volcanic rocks were tabulated for ease of examination and comparison of characteristics between districts. There are 215 districts listed, with a cumulative tonnage of 709 million metric tons and average grades of 4.7 g/t Au, 224 g/t Ag, 0.16 percent Cu, 0.55 percent Pb, and 0.83 percent Zn, representing about 60 percent of world districts.

  17. Identification of secondary minerals crystallized by low and high temperature alteration in the Northern Kyushu-Palau Ridge volcanic rocks

    NASA Astrophysics Data System (ADS)

    Haraguchi, S.

    2008-12-01

    Seafloor rocks were affected by hydrothermal alteration and low temperature seawater weathering display various elemental behaviors, necessitating detailed investigations to evaluate primary bulk rock compositions without the effect of elemental behaviors during alteration. Seafloor alteration entails primary minerals being changed into hydrous minerals. Bulk chemical compositions of seafloor igneous rocks are changed by high- temperature hydrothermal alteration and low-temperature seafloor weathering. In this study, I report the secondary mineral identifications by XRD analyses in the rocks from the northern Kyushu-Palau Ridge, and consider to condition of alteration processes. Volcanic rocks dredged from the Northern Kyushu Palau Ridge during cruise by Tansei-maru, ORI, University of Tokyo show petrological and geochemical characteristics of low and high temperature alterations. These rocks are classified into bulk water content, that is, low H2O- and LOI samples at the Miyazaki Seamount, high H2O- samples at the Nichinan Seamount, and high LOI samples at the Komahashi-Daini Seamount. The Nichinan Seamount samples show flesh phenocrysts, low altered groundmass minerals, and high degree alteration of groundmass glass, assumed to replace into clay minerals. These altered phenocrysts are identified by XRD to be serpentine, saponite, and talc. And these altered groundmasses are identified by XRD to be saponite with primary plagioclase and clinopyroxene. These results are assumed to replacement of glass into clay minerals under low temperature seafloor weathering. Nichinan Seamount rocks show high alkali-elements contents. The remarkable movement of bulk composition is not occur under the low temperature seafloor weathering except for K and Rb, and these enrichments reflect secondary deposition of celadonite, K-rich smectite (e.g. Nakamura, 2001). Saponite is typical identified, but celadonite is not identified in the Nichinan Seamount rocks. Therefore, the

  18. The Early Andean Magmatic Province (EAMP): 40Ar/ 39Ar dating on Mesozoic volcanic and plutonic rocks from the Coastal Cordillera, northern Chile

    NASA Astrophysics Data System (ADS)

    Oliveros, Verónica; Féraud, Gilbert; Aguirre, Luis; Fornari, Michel; Morata, Diego

    2006-10-01

    The Early Andean Magmatic Province (EAMP), consists of about 150 000 km 3 of volcanic and plutonic units in the Coastal Cordillera of northern Chile and southern Peru and represents a major magmatic Mesozoic event in the world, for which the precise age of the thick volcanic series was unknown. Thirty 40Ar/ 39Ar analyses were carried out on primary mineral phases of volcanic and plutonic rocks from northern Chile (18°30'-24°S). Reliable plateau and "mini plateau" ages were obtained on plagioclase, amphibole and biotite from volcanic and plutonic rocks, despite widespread strong alteration degree. In the Arica, Tocopilla and Antofagasta (700 km apart) regions, the ages obtained on lava flows constrain the volcanic activity between 164 and 150 Ma and no N-S migration of volcanism is observed. The uppermost lava flows of the volcanic sequence at the type locality of the La Negra Formation extruded at ca. 153-150 Ma, suggesting the end of the volcanic activity of the arc at that time. The oldest volcanic activity occurred probably at ca. 175-170 Ma in the Iquique area, although no plateau age could be obtained. The plutonic bodies of the same regions were dated between ca. 160 and 142 Ma, indicating that they were partly contemporaneous with the volcanic activity. At least one volcanic pulse around 160 Ma is evidenced over the entire investigated reach of the EAMP, according to the ages found in Arica, Tocopilla, Michilla and Mantos Blancos regions. The episodic emplacement of huge amounts of subduction related volcanism is observed throughout the whole Andean history and particularly during the Jurassic (southern Peru, northern Chile and southern Argentina). These events probably correspond to periodic extensional geodynamic episodes, as a consequence of particular subduction conditions, such as change of obliquity of the convergence, change in the subduction angle, slab roll back effect or lower convergence rate, that remain to be precisely defined.

  19. Along-arc geochemical and isotopic variations in Javanese volcanic rocks: 'crustal' versus 'source' contamination at the Sunda arc, Indonesia

    NASA Astrophysics Data System (ADS)

    Handley, H.; Blichert-Toft, J.; Turner, S.; Macpherson, C. G.

    2012-12-01

    Understanding the genesis of volcanic rocks in subduction zone settings is complicated by the multitude of differentiation processes and source components that exert control on lava geochemistry. Magma genesis and evolution at the Sunda arc is controlled and influenced by 1) along arc changes in the composition and thickness of the overriding Eurasian plate, 2) the variable age of the subducting oceanic crust and, 3) changes in the type and amount of sediment deposited on the subducting plate. Along-arc changes in geochemistry have long been recognised in the Sunda arc (Whitford, 1975), but debate still prevails over the cause of such variations and the relative importance of shallow (crustal) versus deep (subduction) contamination at the Sunda arc, Indonesia. Detailed study of individual Sunda arc volcanic centres is, therefore, a prerequisite in order to establish the relative importance and contributions of various potential source components and composition modifying differentiation processes at individual volcanoes, prior to an along arc comparative petrogenetic investigation. We present new radiogenic isotope data for Javanese volcanoes, which is combined with our recently published (Handley et al., 2007; Handley et al., 2008, Handley et al., 2010; Handley et al., 2011) geochemical and isotopic data of Javanese volcanic rocks along with data from other detailed geochemical studies to establish whether variable contributions from the subducting slab, or a change in crustal architecture of the overriding plate, best explain along-arc variations in isotope ratios and trace element characteristics. In West and Central Java Sr isotope ratios of the volcanic rocks broadly correlate with inferred lithospheric thickness implicating a shallow level control on isotopic composition. However, key trace element ratios combined with Hf isotope data indicate that the subducted slab and slab thermal regime also exert major control on the composition of the erupted Javanese

  20. Age, petrogenesis and tectonic implications of Early Devonian bimodal volcanic rocks in the South Altyn, NW China

    NASA Astrophysics Data System (ADS)

    Kang, Lei; Xiao, Pei-Xi; Gao, Xiao-Feng; Xi, Ren-Gang; Yang, Zai-Chao

    2015-11-01

    In this paper, we report zircon U-Pb dating, Hf isotopes, geochemical and Sr-Nd isotopic data, with the aim the petrogenesis and regional tectonic evolution of Early Devonian bimodal volcanic rock in the South Altyn, NW China. New LA-ICPMS zircon U-Pb isotopic data constrained them at ca. 406 Ma. The mafic samples are characterized by high Fe, Cr and Ni contents, low Ti and Mg contents, slightly enriched LREE patterns, and low (La/Yb)N, La/Nb and La/Ta ratios, and positive εNd(t) values (+3.3 to +3.4), indicating that they were likely derived from strong batch-melting of the asthenosphere in the spinel facies field. The felsic rocks show an A-type affinity, with high alkalis, Fe, Ga, Zr, Nb, Ce and Y contents, low Mg, Sr content, high Rb/Sr and Ga/Al ratios, enrichment in LILE (e.g., Rb, K, Th, U and LREE) and depletion in Ba, Sr, Nb, Ta, P and Ti, and fractionated REE patterns with very strong negative Eu anomalies. These features, along with distinct εNd(t) values (-0.5 to +2.3) and mostly positive εHf(t) (-0.29 to +5.18), indicate that the felsic rocks were mainly generated by partial melting of the crust in low pressure and high temperature conditions, and simultaneously underwent slight magma mixing of such melts with mantle magma. According to the petrogenetic schemes and geological background of the Early Devonian bimodal volcanic rocks (tholeiite and A-type dacite-rhyolite), they should have formed in a post-collisional extensional setting. Moreover, on the basis of spatial and temporal distribution, and formation mechanism, the tectonic magmatic evolution of the early Paleozoic South Altyn Tagh could be divided into three stages: - 505-472 Ma (continental collision), the magmatite formed under high-pressure conditions due to the deep subduction and initial tearing of continental slab; - 467-450 Ma (continental slab break-off), the magmatite formed at high temperature and low pressure in virtue of felsic upper crust uplifting and mantle magma

  1. Pyroxenes of the Khibiny alkaline pluton, Kola Peninsula

    NASA Astrophysics Data System (ADS)

    Yakovenchuk, V. N.; Ivanyuk, G. Yu.; Pakhomovsky, Ya. A.; Men'shikov, Yu. P.; Konopleva, N. G.; Korchak, Yu. A.

    2008-12-01

    Seven pyroxene varieties were identified in nepheline syenites and foidolites of the Khibiny pluton: enstatite, ferrosilite, diopside, hedenbergite, augite, aegirine-augite, and aegirine. Enstatite and augite are typical of alkaline and ultramafic rocks of dike series. Ferrosilite was found in country quartzitic hornfels. Diopside is a rock-forming mineral in alkaline and ultramafic rocks, alkali gabbroids, hornfels in xenoliths of volcanic and sedimentary rocks and foyaite, melteigite-urtite that assimilate them, and certain hydrothermal pegmatite veins. Hedenbergite was noted in hornfels from xenoliths of volcanic and sedimentary rocks and in a hydrothermal pegmatite vein at Mount Eveslogchorr. Aegirine-augite is the predominant pyroxene in all types of nepheline syenites, phonolites and tinguaites, foidolites, alkaline and ultramafic rocks of dike series, fenitized wall rocks surrounding the pluton, and xenoliths of Devonian volcanic and sedimentary rocks. Aegirine is an abundant primary or, more often, secondary mineral in nepheline syenites, foidolites, and hydrothermal pegmatite veins. It occurs as separate crystals, outer zones of diopside and aegirine-augite crystals, and homoaxial pseudomorphs after Na-Ca amphiboles. Microprobe analyses of 265 pyroxenes samples allowed us to distinguish ten principal trends of isomorphic replacement and corresponding typomorphic features of pyroxenes. Compositional variations in clinopyroxenes along the sampled 35-km profile from the margin of the Khibiny pluton to its center confirm the symmetric zoning of the foyaite pluton relative to semicircular faults of the Minor Arc and the Main (Central) Ring marked by Devonian volcanic and sedimentary rocks, foidolites, and related metasomatic rocks (rischorrite, albitite, and aegirinite). Changes in the composition of pyroxenes are explained mainly by the redistribution of elements between coexisting minerals of foyaites in the process of their intense differentiation under the

  2. Rock-Forming feldspars of the Khibiny alkaline pluton, Kola Peninsula, Russia

    NASA Astrophysics Data System (ADS)

    Ivanyuk, G. Yu.; Pakhomovsky, Ya. A.; Konopleva, N. G.; Kalashnikov, A. O.; Korchak, Yu. A.; Selivanova, E. A.; Yakovenchuk, V. N.

    2010-12-01

    This paper describes the structural-compositional zoning of the well-known Khibiny pluton in regard to rock-forming feldspars. The content of K-Na-feldspars increases inward and outward from the Main foidolite ring. The degree of coorientation of tabular K-Na-feldspar crystals sharply increases in the Main ring zone, and microcline-dominant foyaite turns into orthoclase-dominant foyaite. The composition of K-Na-feldspars in the center of the pluton and the Main ring zone is characterized by an enrichment in Al. This shift is compensated by a substitution of some K and Na with Ba (the Main ring zone) or by an addition of K and Na cations to the initially cation-deficient microcline (the central part of the pluton). Feldspars of volcanosedimentary rocks occurring as xenoliths in foyaite primarily corresponded to plagioclase An15-40, but high-temperature fenitization and formation of hornfels in the Main ring zone gave rise to the crystallization of anorthoclase subsequently transformed into orthoclase and albite due to cooling and further fenitization. Such a zoning is the result of filling the Main ring fault zone within the homogeneous foyaite pluton with a foidolite melt, which provided the heating and potassium metasomatism of foyaite and xenoliths of volcanosedimentary rocks therein. The process eventually led to the transformation of foyaite into rischorrite-lyavochorrite, while xenoliths were transformed into aluminum hornfels with anorthoclase, annite, andalusite, topaz, and sekaninaite.

  3. Short-Wavelength Infrared (SWIR) spectroscopy of low-grade metamorphic volcanic rocks of the Pilbara Craton

    NASA Astrophysics Data System (ADS)

    Abweny, Mohammad S.; van Ruitenbeek, Frank J. A.; de Smeth, Boudewijn; Woldai, Tsehaie; van der Meer, Freek D.; Cudahy, Thomas; Zegers, Tanja; Blom, Jan-Kees; Thuss, Barbara

    2016-05-01

    This paper shows the results of Short-Wavelength Infrared (SWIR) spectroscopy investigations of volcanic rocks sampled from low-grade metamorphic greenstone belts of the Archean Pilbara Craton in Western Australia. From the reflectance spectra a range of spectrally active minerals were identified, including chlorites, hornblende, actinolite, epidote and white micas. The rock samples were grouped into mineral assemblages based on their spectrally identified minerals and stratigraphic positions. The metamorphic amphibolite and greenschist facies could be identified from the SWIR spectroscopic data as well as three sub zones of the greenschist facies: 1) a zone containing Fe-chlorite; 2) a zone containing intermediate chlorite and epidote; and 3) a zone containing intermediate chlorite, actinolite and hornblende. Spectral parameters were calculated from the reflectance spectra to assess the metamorphic grade and zones. Plots of the depth parameters of the Fe-OH feature near 2250 nm versus the Mg-OH feature near 2390 nm differentiate the metamorphic amphibolite and greenschist facies and a transition zone between the two. The wavelength position parameter of the Mg-OH absorption feature near 2340 nm also serves to discriminate between the various metamorphic sub zones. The identification of the metamorphic grades of the volcanic sequences in greenstone belts with SWIR spectroscopy is useful for regional geological field studies, exploration for metamorphic mineral deposits hosted in the greenstone belts and the interpretation of hyperspectral remote sensing data sets covering similar types of terranes.

  4. K-Ar ages and Pb, Sr isotopic characteristics of Cenozoic volcanic rocks in Shandong Province, China

    USGS Publications Warehouse

    Daogong, C.; Zicheng, P.; Lanphere, M.A.; Zartman, R.E.

    1985-01-01

    28 samples of Cenozoic volcanic rocks collected from Shandong Province have been dated by K-Ar method. They are mainly Neogene with an age range of 4-19 m. y. The basalts from Linqu and Yishui in west Shandong Province are Miocene and those from Penglai and Qixia in east Shandong Province are Miocene and Pliocene in age. The basalts from Wudi in north Shandong Province are Middle-Early Pleistocene in age. In each area the duration of volcanic eruption was estimated at about 2-3 m. y. Pb and Sr isotopic compositions and U, Th, Pb, Rb, Sr, and major elements in most of the samples were determined. The isotopic compositions are:206Pb/204Pb-16.92-18.48,207Pb/204Pb-15.30-15.59,208Pb/204Pb-37.83-38.54, and (87Sr/86Sr)i-0.70327-0.70632. There are some positive or negative linear correlations between206Pb/204Pb and207Pb/204Pb, Pb isotopes and Pb content, Pb isotopes and Sr isotopes, and Sr isotopes and other elements. The basaltic rocks from east and west Shandong Province have somewhat differences in isotopic composition and element content. The basalts probably are products of multi-stage evolution of the mantle. They have preserved the primary features of the source, although they were influenced, to some extent, by the contamination of crustal materials. ?? 1985 Institute of Geochemistry, Chinese Academy of Sciences.

  5. Short-Wavelength Infrared (SWIR) spectroscopy of low-grade metamorphic volcanic rocks of the Pilbara Craton

    NASA Astrophysics Data System (ADS)

    Abweny, Mohammad S.; van Ruitenbeek, Frank J. A.; de Smeth, Boudewijn; Woldai, Tsehaie; van der Meer, Freek D.; Cudahy, Thomas; Zegers, Tanja; Blom, Jan-Kees; Thuss, Barbara

    2016-05-01

    This paper shows the results of Short-Wavelength Infrared (SWIR) spectroscopy investigations of volcanic rocks sampled from low-grade metamorphic greenstone belts of the Archean Pilbara Craton in Western Australia. From the reflectance spectra a range of spectrally active minerals were identified, including chlorites, hornblende, actinolite, epidote and white micas. The rock samples were grouped into mineral assemblages based on their spectrally identified minerals and stratigraphic positions. The metamorphic amphibolite and greenschist facies could be identified from the SWIR spectroscopic data as well as three sub zones of the greenschist facies: 1) a zone containing Fe-chlorite; 2) a zone containing intermediate chlorite and epidote; and 3) a zone containing intermediate chlorite, actinolite and hornblende. Spectral parameters were calculated from the reflectance spectra to assess the metamorphic grade and zones. Plots of the depth parameters of the Fe-OH feature near 2250 nm versus the Mg-OH feature near 2390 nm differentiate the metamorphic amphibolite and greenschist facies and a transition zone between the two. The wavelength position parameter of the Mg-OH absorption feature near 2340 nm also serves to discriminate between the various metamorphic sub zones. The identification of the metamorphic grades of the volcanic sequences in greenstone belts with SWIR spectroscopy is useful for regional geological field studies, exploration for metamorphic mineral deposits hosted in the greenstone belts and the interpretation of hyperspectral remote sensing data sets covering similar types of terranes.

  6. Paleomagnetism of middle Miocene volcanic rocks in the Mojave-Sonora desert region of western Arizona and southeastern California

    SciTech Connect

    Calderone, G.J. ); Butler, R.F.; Acton, G.D. )

    1990-01-10

    Paleomagnetic directions have been obtained from 190 early to middle Miocene (12-20 Ma) mafic volcanic flows in 16 mountain ranges in the Mojave-Sonora desert region of western Arizona and southeastern California. These flows generally postdate early Miocene tectonic deformation accommodated by low-angle normal faults but predate high-angle normal faulting in the region. After detailed demagnetization experiments, 179 flows yielded characteristic directions interpreted as original thermal remanent magnetizations (TRM). Because of the episodic nature of basaltic volcanism in this region, the 179 flows yielded only 65 time-distinct virtual geomagnetic poles (VGPs). The paleomagnetic pole calculated from the 65 cooling unit VGPs is located at 85.5{degree}N, 108.9{degree}E within a 4.4{degree} circle of 95% confidence. This pole is statistically indistinguishable (at 95% confidence) from reference poles calculated from rocks of similar age in stable North America and from a paleomagnetic pole calculated from rocks of similar age in Baja California. The coincidence of paleomagnetic poles from the Mojave-Sonora desert region with reference poles from the stable continental interior indicates that (1) significant vertical axis net tectonic rotations have not accompanied post-middle Miocene high-angle normal faulting in this region; (2) there has been no detectable post-middle Miocene latitudinal transport of the region; and (3) long-term nondipole components of the middle Miocene geomagnetic field probably were no larger than those of the recent (0-5 Ma) geomagnetic field. In contrast, paleomagnetic data indicate vertical axis rotations of similar age rocks in the Transverse Ranges, the Eastern Transverse Ranges, and the Mojave Block.

  7. Rock magnetism and microscopy of the Jacupiranga alkaline-carbonatitic complex, southern Brazil

    NASA Astrophysics Data System (ADS)

    Alva-Valdivia, Luis M.; Perrin, M.; Rivas-Sánchez, María L.; Goguitchaichvili, Avto; López-Loera, Héctor; Lopes, Omar Ferreira; Bonás, Thiago Bastos

    2009-01-01

    This study of the Cajati deposit provides evidence that the ore was neither purely hydrothermal, nor volcanic in origin, as previous workers have proposed. The ores were formed from magnetite-rich magmas, hydrothermally altered and intruded at an indicated crustal depth in excess of 500 m. The mineralogical and textural association between magnetite and magnesioferrite in the carbonatite, and between the titanomagnetite and magnesioferrite-Ti mineralization in the pyroxenite of hedenbergite, seems to be analog mineralizations strongly related to the ionic substitution of Fe2+ by Mg. Relatively high Q ratios (≥5) for Jacupirangite-pyroxenite may indicate a thermo remanent magnetization (TRM) by the ore during post-metamorphic cooling, however it can also be developed from chemical remanent magnetization (CRM). Vector plots for the pyroxenite samples show reasonably linear and stable magnetic components. The intensity decay curves show that only two components of magnetizations are likely present. Continuous susceptibility measurements with increasing temperature show that the main magnetic phase seems to be magnetite. Maghemite is probably produced during the cooling process. Susceptibility recorded from low temperature (liquid nitrogen (-196°C)) to room temperature produces typical curves, indicating Verwey transition of magnetite. Hysteresis parameters point out that nearly all values fall in a novel region of the Day plot, parallel to but below magnetite SD + MD mixing curves.

  8. Stratigraphy and major element geochemistry of the Lassen Volcanic Center, California

    SciTech Connect

    Clynne, M.A.

    1984-01-01

    Detailed geologic mapping of 200 km/sup 2/ in and near Lassen Volcanic National Park, California and reconnaissance of the surrounding area, combined with reinterpretation of data in the literature, allow definition of the Lassen Volcano Center and provide the stratigraphic framework necessary for interpretation of major-element chemical data. The Lassen Volcanic Center developed in three stages. Stage I and II produced Brokeoff Volcanic, an andesitic composite cone that erupted mafic andesite to dacite 0.6 to 0.35 my ago. Volcanism then shifted in character and locale. Domes and flows of dacite and rhyodacite, and flows of hybrid andesite were erupted on the northern flank of Brokeoff Volcano during the period from 0.25 my ago to the present; these rocks comprise Stage III of the Lassen Volcanic Center. Rocks of the Lassen Volcanic Center are typical of subduction-related calc-alkaline volcanic rocks emplaced on a continental margin overlying sialic crust. Porphyritic andestic and dacite with high Al/sub 2/O/sub 3/, low TiO/sub 2/, medium K/sub 2/O, and FeO/MgO 1.5-2.0 are the most abundant rock types. Major-element chemical trends of rock sequences indicate a mafic to silicic evolution for magmas of the Lassen Volcanic Center, probably owing to crystal fractionation of calc-alkaline basalt. 23 figs., 5 tabs.

  9. Field relation, geochemistry and origin of the Xinglonggou volcanic rocks in Beipiao area, Liaoning Province (China): Reappraisal on the foundering of lower continental crust of North China Craton

    NASA Astrophysics Data System (ADS)

    Wang, Yang; Cheng, Su-Hua

    2012-03-01

    Our large scale geological mapping in the Beipiao area, western Liaoning Province, the North China Craton, shows that the exposed "Xinglonggou Formation" is not a monoclinal stratum, but a suit of strongly deformed volcanic rocks intruded by some small plugs. Consequently, two rock groups are categorized for the "Xinglonggou Formation" in the Beipiao area, according to their field relation, petrography, and geochemical characteristics. The group 1 rocks are blackish and fresh, and cut across the deformed group 2 volcanic rocks. Meanwhile, the group 1 rocks exhibit characteristics of higher magnesium number (Mg# ⩾ 60), calcium content (CaO > 5 wt.%), and Sr/Y ratio (>60), but lower potassium (K2O < 2 wt.%) and Rb contents (<40 ppm). Among these rocks, most of them have higher Cs but lower Li content. Geochemically, the group 1 rocks belong to high-SiO2 adakite (HSA). On the contrary, the group 2 is composed of intermediate and acid volcanic rocks, which are brownish or greenish and strongly folded. Compared with the group 1 rocks, they have higher potassium (K2O > 2 wt.%) and Rb contents, but lower Mg# (<60) and calcium content (most samples CaO < 5 wt.%); meanwhile, they have lower Sr/Y ratios (in general <60), and lower Cs but higher Li contents. According to their near zero ɛNd(t) value and radiogenic Pb isotopic compositions, as well as the enrichment of U and Th relative to LREE, neither the group 1 or the group 2 rocks result from the partial melting of the lower crust of North China Craton. The group 1 HSAs are generated by melting of the subducted oceanic crust of the Paleo-Pacific plate; otherwise, the group 2 rocks are derivatives of the magma originated from a slab-derived melt metasomatised mantle.

  10. Alkaline fluid circulation in ultramafic rocks and formation of nucleotide constituents: a hypothesis

    PubMed Central

    Holm, Nils G; Dumont, Marion; Ivarsson, Magnus; Konn, Cécile

    2006-01-01

    Seawater is constantly circulating through oceanic basement as a low-temperature hydrothermal fluid (<150°C). In cases when ultramafic rocks are exposed to the fluids, for instance during the initial phase of subduction, ferromagnesian minerals are altered in contact with the water, leading to high pH and formation of secondary magnesium hydroxide, among other – brucite, that may scavenge borate and phosphate from seawater. The high pH may promote abiotic formation of pentoses, particularly ribose. Pentoses are stabilized by borate, since cyclic pentoses form a less reactive complex with borate. Analyses have shown that borate occupies the 2' and 3' positions of ribose, thus leaving the 5' position available for reactions like phosphorylation. The purine coding elements (adenine, in particular) of RNA may be formed in the same general hydrothermal environments of the seafloor. PMID:16867193

  11. Distribution of anomalously high K2O volcanic rocks in Arizona: Metasomatism at the Picacho Peak detachment fault

    NASA Astrophysics Data System (ADS)

    Brooks, William E.

    1986-04-01

    Metasomatized Tertiary lavas with anomalously high K2O and low Na2O content are distributed within the northwest-trending Miocene extensional terrane of southwestern Arizona. These rocks are common near core-complex related detachment faults at Picacho Peak and the Harcuvar Mountains and in listric-faulted terrane at the Vulture Mountains. In addition to systematic changes in K2O and Na2O, the rocks have been enriched in Zr and depleted in MgO. Secondary, introduced minerals include orthoclase, quartz, and calcite. Fine-grained, euhedral orthoclase (var. adularia), from 2 to 10 μm, is the dominant potassium mineral. Metasomatic changes at Picacho Peak are spatially associated with a major detachment fault. Thus, it is interpreted that detachment provided a conduit for hydrothermal fluids that altered the initial chemical composition of the Tertiary volcanics by potassium metasomatism and charged the upper-plate rocks with mineralizing fluids that carried Zr and Ba, along with Au, Ag, and Cu, during detachment 17 18 Ma.

  12. Palaeomagnetism, Potassium-argon ages and petrology of some volcanic rocks

    USGS Publications Warehouse

    Dalrymple, G.B.; Cox, A.

    1968-01-01

    Geological evidence obtained from samples of rocks from Cocos Island, Costa Rica, seems to agree with the idea that this island could have been a stepping stone for organisms migrating to the Galapagos Islands. ?? 1968 Nature Publishing Group.

  13. Alkaline igneous rocks of Magnet Cove, Arkansas: Mineralogy and geochemistry of syenites

    USGS Publications Warehouse

    Flohr, M.J.K.; Ross, M.

    1990-01-01

    Syenites from the Magnet Cove alkaline igneous complex form a diverse mineralogical and geochemical suite. Compositional zoning in primary and late-stage minerals indicates complex, multi-stage crystallization and replacement histories. Residual magmatic fluids, rich in F, Cl, CO2 and H2O, reacted with primary minerals to form complex intergrowths of minerals such as rinkite, fluorite, V-bearing magnetite, F-bearing garnet and aegirine. Abundant sodalite and natrolite formed in pegmatitic segregations within nepheline syenite where Cl- and Na-rich fluids were trapped. During autometasomatism compatible elements such as Mn, Ti, V and Zr were redistributed on a local scale and concentrated in late-stage minerals. Early crystallization of apatite and perovskite controlled the compatible behavior of P and Ti, respectively. The formation of melanite garnet also affected the behaviour of Ti, as well as Zr, Hf and the heavy rare-earth elements. Pseudoleucite syenite and garnet-nepheline syenite differentiated along separate trends, but the two groups are related to the same parental magma by early fractionation of leucite, the presumed precursor of intergrowths of K-feldspar and nepheline. The Diamond Jo nepheline syenite group defines a different differentiation trend. Sphene-nepheline syenite, alkali syenite and several miscellaneous nepheline syenites do not consistently plot with the other syenite groups or each other on element and oxide variation diagrams, indicating that they were derived from still other parental syenite magmas. Mineral assemblages indicate that relatively high f{hook};O2, at or above the fayalite-magnetite-quartz buffer, prevailed throughout the crystallization history of the syenites. ?? 1990.

  14. Petrology of ultramafic xenoliths in Cenozoic alkaline rocks of northern Madagascar (Nosy Be Archipelago)

    NASA Astrophysics Data System (ADS)

    Rocco, Ivana; Lustrino, Michele; Zanetti, Alberto; Morra, Vincenzo; Melluso, Leone

    2013-01-01

    Late Miocene basanites of Nosy Be and Nosy Sakatia islands (Nosy Be Archipelago, northern Madagascar) carry spinel-facies anhydrous ultramafic xenoliths (lherzolites, harzburgites and wehrlites). Geothermobarometric estimates indicate that these xenoliths derive from shallow mantle depths of 35-40 km, with those from Nosy Be island showing equilibration T (averages in the range of 945-985 °C) lower than the Nosy Sakatia analogues (averages ranging from 1010 to 1110 °C). One Nosy Sakatia mantle xenolith exhibits relatively fertile lherzolite composition, with trace and major element mineral chemistry consistent with a residual character after low degrees (1-2%) of mafic melt extraction. We interpret this composition as that resembling a depleted mantle (DM)-like lithospheric composition before metasomatic overprints. The other lherzolites and harzburgites display petrochemical characters consistent with variable extent of partial melting (up to 18%), associated with pronounced metasomatic overprints caused by migrating melts, as highlighted by enrichments in highly incompatible trace elements (e.g. light rare earth elements, LREE and Sr), together with the abundant occurrence of wehrlitic lithologies. The variability of petrochemical features points to different styles of metasomatism and metasomatic agents. The estimated composition of the parental melts of wehrlites matches that of host basanites. The combination of this evidence with the petrographic features, characterized by coarse-granular to porphyroclastic textures and by the presence of olivine without kink-banding, suggests that wehrlites are veins or pockets of high pressure cumulates within the mantle peridotite. The same melts also metasomatized via porous-flow percolation some lherzolites and harzburgites. Distinctly, a group of lherzolites and harzburgites was metasomatized by a different alkaline melt having markedly lower incompatible trace element contents. Late infiltration of metasomatic fluids

  15. The relationship between carbonate facies, volcanic rocks and plant remains in a late Palaeozoic lacustrine system (San Ignacio Fm, Frontal Cordillera, San Juan province, Argentina)

    NASA Astrophysics Data System (ADS)

    Busquets, P.; Méndez-Bedia, I.; Gallastegui, G.; Colombo, F.; Cardó, R.; Limarino, O.; Heredia, N.; Césari, S. N.

    2013-07-01

    The San Ignacio Fm, a late Palaeozoic foreland basin succession that crops out in the Frontal Cordillera (Argentinean Andes), contains lacustrine microbial carbonates and volcanic rocks. Modification by extensive pedogenic processes contributed to the massive aspect of the calcareous beds. Most of the volcanic deposits in the San Ignacio Fm consist of pyroclastic rocks and resedimented volcaniclastic deposits. Less frequent lava flows produced during effusive eruptions led to the generation of tabular layers of fine-grained, greenish or grey andesites, trachytes and dacites. Pyroclastic flow deposits correspond mainly to welded ignimbrites made up of former glassy pyroclasts devitrified to microcrystalline groundmass, scarce crystals of euhedral plagioclase, quartz and K-feldspar, opaque minerals, aggregates of fine-grained phyllosilicates and fiammes defining a bedding-parallel foliation generated by welding or diagenetic compaction. Widespread silicified and silica-permineralized plant remains and carbonate mud clasts are found, usually embedded within the ignimbrites. The carbonate sequences are underlain and overlain by volcanic rocks. The carbonate sequence bottoms are mostly gradational, while their tops are usually sharp. The lower part of the carbonate sequences is made up of mud which appear progressively, filling interstices in the top of the underlying volcanic rocks. They gradually become more abundant until they form the whole of the rock fabric. Carbonate on volcanic sandstones and pyroclastic deposits occur, with the nucleation of micritic carbonate and associated production of pyrite. Cyanobacteria, which formed the locus of mineral precipitation, were related with this nucleation. The growth of some of the algal mounds was halted by the progressive accumulation of volcanic ash particles, but in most cases the upper boundary is sharp and suddenly truncated by pyroclastic flows or volcanic avalanches. These pyroclastic flows partially destroyed the

  16. Nature and origin of mineral coatings on volcanic rocks of the Black Mountain, Stonewall Mountain and Kane Springs wash volcanic centers, southern Nevada

    NASA Technical Reports Server (NTRS)

    Taranik, James V.; Noble, Donald C.; Hsu, Liang C.; Spatz, David M.

    1987-01-01

    Mineral coatings, including desert varnish on volcanic rocks of the semi-arid Basin and Range province are composted of amorphous, translucent films of Fe, Mn, Si, and Al rich compounds. Coatings are chiefly thin films that impregnate intergranularly to depths of about 0.1 to 0.3 mm, rarely deeper. Sixteen coating sections and subsurface interiors were probed by SEM; 20 samples were scanned by infrated spectrometry; 10 samples were scanned for visible-near IR spectra; inductin coupling plasma analyses were collected on 34 samples; 2 desert varnish surgaces were investigated by optical density slice imagery; a few XRD analyses were conducted in addition to the 50 reported in the last period; thin section observation continued; and imagery processing focused on classification techniques. In late May, approximately 10 field days were spent at the Stonewall and Black Mountain study sited conducting more detailed mapping and observation base on imagery results and collecting spectra with the Collins Field Spectrometer. Approximately 100 spectral analyses were collected and are currently being processed.

  17. Nature and origin of mineral coatings on volcanic rocks of the Black Mountain, Stonewall Mountain, and Kane Springs, Wash volcanic centers, Southern Nevada

    NASA Technical Reports Server (NTRS)

    Taranik, James V.; Noble, Donald C.; Hsu, Liang C.; Spatz, David M.

    1987-01-01

    LANDSAT Thematic Mapper imagery was evaluated over 3 Tertiary calderas in southern Nevada. Each volcanic center derived from a highly evolved silici magmatic system represented today by well exposed diverse lithologies. Distinctive imagery contrast between some of the late ash flows and earlier units follows from the high relative reflectance in longer wavelength bands (bands 5 and 7) of the former. Enhancement techniques provide color composite images which highlight some of the units in remarkable color contrast. Inasmuch as coatings on the tuffs are incompletely developed and apparently largely dependent spectrally on rock properties independent of petrochemistry, it is felt that the distinctive imagery characteristics are more a function of primary lithologic or petrochemical properties. Any given outcrop is backdrop for a variety of cover types, of which coatings, at various stages of maturity, are one. Petrographic and X-ray diffraction analysis of the outer air-interface zone of coatings reveal they are composed chiefly of amorphous compounds, probably with varying proportions of iron and manganese. Observations support an origin for some outer (air-interface) coating constituents exogenous to the underlying host.

  18. Seismic imaging through volcanic rocks of the Snake River Plain, Idaho for the ICDP Project Hotspot

    NASA Astrophysics Data System (ADS)

    Liberty, L. M.; Schmitt, D. R.; Shervais, J. W.

    2011-12-01

    New high-resolution downhole and surface seismic reflection data tied to drill holes related to the Snake River Geothermal Drilling Project (ICDP Project Hotspot) provide insights into seismic imaging in volcanic terranes. The downhole data at the Kimberly and Kimama drill sites in southern Idaho show low seismic attenuation and large seismic velocity contrasts at volcanic flow boundaries. These lithologic and seismic boundaries tie to reflections in both borehole and surface seismic images. The Kimberly site drilled through 1,958 m of mostly rhyolite, with thin sedimentary interbeds throughout the section. Sedimentary interbeds at depth correspond with slow velocity zones that relate to reflections on surface seismic profiles. The reflection observed on 360-channel vibroseis seismic profiles that relates to a flow boundary at 300-400 m depth increases in depth with increasing elevation away from the Kimberly drill site, suggesting flow volumes may be estimated with surface seismic methods. The Kimama site drilled through 1,912 m of mostly basalt with sedimentary interbeds at depth. Downhole and surface vibroseis seismic results here also suggest seismic reflection methods are useful to image flow boundaries. Ongoing drilling at a third site in Mountain Home, Idaho will tie lithologies and measured physical properties to surface seismic data. These seismic data show key lithologic boundaries related to Quaternary basalts, lake sediments related to paleo Lake Idaho, and underlying Tertiary basalts. Ongoing analysis should help clarify the limits and capabilities of surface seismic imaging in volcanic terranes.

  19. Petrogenesis of the Late Triassic volcanic rocks in the Southern Yidun arc, SW China: Constraints from the geochronology, geochemistry, and Sr-Nd-Pb-Hf isotopes

    NASA Astrophysics Data System (ADS)

    Leng, Cheng-Biao; Huang, Qiu-Yue; Zhang, Xing-Chun; Wang, Shou-Xu; Zhong, Hong; Hu, Rui-Zhong; Bi, Xian-Wu; Zhu, Jing-Jing; Wang, Xin-Song

    2014-03-01

    Studies on zircon ages, petrology, major and trace element geochemistry, and Sr-Nd-Hf-Pb isotopic geochemistry of intermediate volcanic rocks from the Southern Yidun arc, Sanjiang-Tethyan Orogenic Belt, SW China have been undertaken in this paper. They are used to discuss the petrogenesis of these rocks and to constrain the tectonic setting and evolution of the Yidun arc. These intermediate volcanic rocks were erupted at ca. 220 Ma (U-Pb zircon ages). Trachyandesite is the dominant lithology among these volcanic rocks, and is mainly composed of hornblende and plagioclase, with minor clinopyroxene and biotite. A hornblende geobarometer suggests that the stagnation of magma in the lower crust, where plagioclase crystallization was suppressed while hornblende crystallized, giving rise to high Sr/Y ratios that are one of the distinguishing features of adakites, after the primary magma originated from the lithospheric mantle wedge. Steeply right-inclined Rare Earth Element (REE) pattern combined with high La/Yb ratios suggests adakitic affinity of these volcanic rocks, implying that slab-melt from the subducting oceanic crust is a necessary component in the primary magma. Besides, trace element geochemistry and isotopic geochemistry also indicate that partial melting of pelagic sediments in the subduction zone and noticeable contamination with the lower crust were involved in the evolution of parental magma of these volcanic rocks. Based on previous work on the Northern Yidun arc and this study, we propose that the subduction was initiated in the Northern Yidun arc and extended to the southern part and that the Northern Yidun arc is an island arc while the Southern Yidun arc represents a continental arc, probably caused by the existence of the Zhongza Massif, that was invoked to be derived from Yangtze Block, as a possible basement of the Southern Yidun arc.

  20. New data on Mesozoic Radiolaria of Serbia and Bosnia, and implications for the age and evolution of oceanic volcanic rocks in the Central and Northern Balkans

    NASA Astrophysics Data System (ADS)

    Vishnevskaya, V. S.; Djeric, N.; Zakariadze, G. S.

    2009-03-01

    The Dinaridic Ophiolite Belt (DOB) includes Middle Triassic cherty limestones, Upper Triassic radiolarian cherts associated with basaltic lavas and volcaniclastic sediments, and also Jurassic continental slope sequences. Sedimentary sequences grade upwards into Cretaceous red limestones with planktonic foraminifers of the Genus Hedbergella. Many of the Late Triassic to Late Jurassic cherts probably accumulated in an oceanic setting, and now crop out as blocks in olistostromal deposits. Jurassic radiolarite sequences of the margin of the Dinaride Ophiolite Belt are represented by Aalenian, Upper Bajocian-Lower Bathonian and Upper Bathonian-Lower Callovian, Middle Callovian-Oxfordian, Upper Callovian-Upper Oxfordian and Kimmeridgian-Tithonian-aged strata. These are overlain by Upper Tithonian-Valanginian sedimentary sequences with spongolite-radiolarites, volcaniclastic sediments and other continental slope deposits. The oldest units outcropping in the DOB are Mid-Triassic (Ladinian) red cherts and limestones. These are associated with alkaline and tholeiitic basalts in the Bistrica area, and with tholeiitic basalts in the Visoka area. In contrast, in the Vardar Zone Western Belt the oldest basalt-radiolarite formation is represented by cherts associated with tholeiitic basalt in the Ovčar Banja area. Upper Triassic red radiolarites of the Čačak area lie in direct stratigraphical contact with MORB-type pillow lavas and contain a Carnian-Norian radiolarian assemblage. The youngest radiolarian-bearing units are in the Upper Cretaceous part of the Vardar Zone Western Belt, in the Struganik area, where Coniacian-Santonian radiolarians occur in chert-clay-tuff sediments. In addition, cherty limestones from the northern slope of Kozara Mt. contain a Campanian radiolarian assemblage, together with Campanian-Maastrichtian planktonic foraminifers. Volcanic units associated with the siliceous sediments of Dinaride Ophiolite Belt and the Vardar Zone Western Belt are of MOR

  1. Origin and geodynamic relationships of the Late Miocene to Quaternary alkaline basalt volcanism in the Pannonian basin, eastern-central Europe

    NASA Astrophysics Data System (ADS)

    Harangi, Szabolcs; Jankovics, M. Éva; Sági, Tamás; Kiss, Balázs; Lukács, Réka; Soós, Ildikó

    2015-11-01

    Alkaline basaltic volcanism has been taking place in the Carpathian-Pannonian region since 11 Ma and the last eruptions occurred only at 100-500 ka. It resulted in scattered low-magma volume volcanic fields located mostly at the margins of the Pannonian basin. Many of the basalts have compositions close to those of the primitive magmas and therefore can be used to constrain the conditions of the magma generation. Low-degree (2-3 %) melting could occur in the convective asthenosphere within the garnet-spinel transition zone. Melting started at about 100 km depth and continued usually up to the base of the lithosphere. Thus, the final melting pressure could indicate the ambient lithosphere-asthenosphere boundary. The asthenospheric mantle source regions of the basalts were heterogeneous, presumably in small scale, and included either some water or pyroxenite/eclogite lithology in addition to the fertile to slightly depleted peridotite. Based on the prevailing estimated mantle potential temperature (1,300-1,400 °C) along with the number of further observations, we exclude the existence of mantle plume or plume fingers beneath this region. Instead, we propose that plate tectonic processes controlled the magma generation. The Pannonian basin acted as a thin spot after the 20-12 Ma syn-rift phase and provided suction in the sublithospheric mantle, generating asthenospheric flow from below the adjoining thick lithospheric domains. A near-vertical upwelling along the steep lithosphere-asthenosphere boundary beneath the western and northern margins of the Pannonian basin could result in decompressional melting producing low-volume melts. The youngest basalt volcanic field (Perşani) in the region is inferred to have been formed due to the dragging effect of the descending lithospheric slab beneath the Vrancea zone that could result in narrow rupture at the base of the lithosphere. Continuation of the basaltic volcanism cannot be excluded as inferred from the still fusible

  2. Pliocene-Quaternary volcanic rocks of NW Armenia: Magmatism and lithospheric dynamics within an active orogenic plateau

    NASA Astrophysics Data System (ADS)

    Neill, I.; Meliksetian, Kh.; Allen, M. B.; Navarsardyan, G.; Karapetyan, S.

    2013-11-01

    The Pliocene-Quaternary volcanic rocks of Armenia are a key component of the Arabia-Eurasia collision, representing intense magmatism within the Turkish-Iranian plateau, tens of millions of years after the onset of continental collision. Here we present whole rock elemental and NdSr isotope data from mafic, intermediate, and felsic lava flows and cinder cones in Shirak and Lori provinces, NW Armenia. Magmatism appears to be controlled locally by extension related to major strike-slip faults within the plateau. Major and trace element results show that the three series—valley-filling medium-K alkali basalt flows, ridge-forming andesite to rhyolite flows, and andesitic cinder cones—form a compositional continuum linked by a crystallisation sequence dominated by two pyroxenes, plagioclase and amphibole. There is petrographic and major and trace element evidence for magma mixing processes and potentially crustal contamination by Mesozoic-early Cenozoic arc-related rocks, which has not significantly affected the isotopic signature. Modelling of the basaltic rocks indicates that they formed by moderate degrees of partial melting (~ 3-4%) of an incompatible element enriched, subduction-modified, lithospheric mantle source. Samples have a distinctive high Zr/Hf ratio and high Zr concentrations, which are an intrinsic part of the source or the melting process, and are much more commonly found in ocean island basalts. Regional models for magmatism often argue for whole-scale delamination of the mantle lithosphere beneath Eastern Anatolia and the Lesser Caucasus, but this scenario is hard to reconcile with limited crustal signatures and the apparent lack of asthenospheric components within many studied centres.

  3. Lithologic discrimination of volcanic and sedimentary rocks by spectral examination of Landsat TM data from the Puma, Central Andes Mountains

    NASA Technical Reports Server (NTRS)

    Fielding, E. J.

    1986-01-01

    The Central Andes are widely used as a modern example of noncollisional mountain-building processes. The Puna is a high plateau in the Chilean and Argentine Central Andes extending southward from the altiplano of Bolivia and Peru. Young tectonic and volcanic features are well exposed on the surface of the arid Puna, making them prime targets for the application of high-resolution space imagery such as Shuttle Imaging Radar B and Landsat Thematic Mapper (TM). Two TM scene quadrants from this area are analyzed using interactive color image processing, examination, and automated classification algorithms. The large volumes of these high-resolution datasets require significantly different techniques than have been used previously for the interpretation of Landsat MSS data. Preliminary results include the determination of the radiance spectra of several volcanic and sedimentary rock units and the use of the spectra for automated classification. Structural interpretations have revealed several previously unknown folds in late Tertiary strata, and key zones have been targeted to be investigated in the field. The synoptic view of space imagery is already filling a critical gap between low-resolution geophysical data and traditional geologic field mapping in the reconnaissance study of poorly mapped mountain frontiers such as the Puna.

  4. Analysis of source characteristics of experimental gas burst and fragmentation explosions generated by rapid decompression of volcanic rocks

    NASA Astrophysics Data System (ADS)

    Arciniega-Ceballos, A.; Alatorre-Ibargüengoitia, M.; Scheu, B.; Dingwell, D. B.

    2015-07-01

    Gas burst and fragmentation explosions induced by rapid decompression of volcanic rocks in a high-pressure autoclave have been analyzed. We performed experiments from 4 to 20 MPa on (1) loose pyroclasts and (2) pumice from recent eruptions of Popocatépetl volcano. Our aim is to characterize the source mechanism distinguishing the physical processes that operate in the conduit which determine the dynamics of explosive volcanoes. For this aim we have analyzed experimentally the parameters that indicate the state and behavior of the conduit (i.e., decompression time, fragmentation threshold and speed, forces, and the partitioning of energy), using microseismic monitoring, the decompression time curves, and the sample rheological properties. The initial available potential energy in the system and its partitioning into different types of energies are correlated in space and time with specific stages of the explosive phenomenon. Such correlations, taken together with the energy distribution, enable the distinction of the individual physical processes involved and their causal sequence and relationships. Our observations suggest that in volcanic conduits with regular explosive activity, a source mechanism may operate whereby a causal sequence of processes results in a system that undergoes both rapid and stable transitions. Such behavior may persist over long periods of time.

  5. Gravity and aeromagnetic constraints on the extent of Cenozoic volcanic rocks within the Nefza Tabarka region, northwestern Tunisia

    NASA Astrophysics Data System (ADS)

    Jallouli, Chokri; Mickus, Kevin; Turki, Mohamed Moncef; Rihane, Chedly

    2003-03-01

    Bouguer gravity and aeromagnetic data are analyzed to determine the extent of Miocene magmatism in the Nefza and Tabarka regions of northwestern Tunisia. Construction of magnetic intensity and enhanced analytic signal (EAS) maps indicated the existence of at least two regions containing probable subsurface igneous bodies that correlate to the small scattered igneous outcrops in the Nefza and Tabarka regions. Because of the lack of lateral resolution of the EAS techniques, 3-D magnetic and 2.5-D gravity models were constructed over the anomalies at Nefza and Tabarka. The final models indicate that the maximum depths of the igneous bodies are between 2.5 and 2.7 km with maximum widths between 15 and 22 km. The final models also indicate that the bodies are tabular with a combination of laccolithic and lopolithic shapes and were probably emplaced in the shallow levels of the crust (at least 3 km). These widths greatly expand the region of known Miocene magmatism in northwestern Tunisia. Combined with geochemical and petrological data of the surface volcanic rocks, the gravity and magnetic models imply a wider range of Miocene volcanic activity in northern Tunisia, probably related to a subduction zone.

  6. Granulite facies xenoliths in Clear Lake volcanic rocks and the distribution of heat around geothermal energy sources

    SciTech Connect

    Glassley, W.E. ); Stimac, J. )

    1990-06-01

    Within the Clear Lake (CA) volcanic field, a broad range of felsic and mafic xenoliths occur at several of the volcanic centers that erupted through Franciscan Complex rocks. A small proportion of these xenoliths are composed of granulite facies mineral assemblages and appear to be of crustal origin. Most of these xenoliths contain fine-grained gneissic textures. The xenoliths preserve a complex recrystallization history in which garnet-opx-plagioclase-qtz{plus minus}kspar{plus minus}sillimanite assemblages are partially replaced either by multiple generations of plagioclase-opx-hercynite coronas around garnets or cordierite overgrowths on hercynite-spinel. In some cases, hydration of the xenoliths is recorded by the development of biotite, which often occurs as nearly concentric bands in the interior of the xenoliths. Textural and compositional evidence suggests that recrystallization records the following reaction sequence, at the indicated pressures: garnet + quartz -> opx + plag (<5.8 kb) and garnet + sillimanite -> hercynite + quartz (3.8 to 2.2 kb), followed by garnet + sillimanite + quartz -> cordierite (<5.9 kb). The geobarometric results indicate that, for all recrystallization events, reequilibration occurred at crustal depths less than {approximately}18 km. The original granulite facies assemblage appears to have formed at pressures in excess of 8 kb, but precise definition of the conditions of formation are precluded by difficulty in identifying the equilibrium high pressure garnet composition. Associated with the gneissic xenoliths are mafic xenoliths that are interpreted to represent fragments from deep crustal magma bodies. The presence of shallow to intermediate depth granulites in this region demonstrates that a significant quantity of the heat released during cooling and recrystallization of the magma bodies is used in the recrystallization of the rocks enclosing the magma chambers.

  7. Paleomagnetism of Upper Jurassic to Lower Cretaceous Volcanic and Sedimentary Rocks From the Western Tarim Basin: Implications for Inclination Shallowing and the ISEA? chron

    NASA Astrophysics Data System (ADS)

    Cogne, J.; Gilder, S.; Chen, Y.; Tan, X.; Courtillot, V.; Sun, D.; Li, Y.

    2002-12-01

    Stepwise demagnetization isolates a stable magnetic component in 13 sites of basalt flows and baked sediments dated at 113+-1.6 Ma from the Tuoyun section, western Xinjiang Province, China. Except for one flow from the base of the 300 m-thick section, the rest have exclusively reversed polarity. Five of 11 sites of Early Cretaceous red beds that underlie the basalts possess coherent directions that pass both fold and reversals tests. Six sites of Upper Jurassic red beds have a magnetic component that was likely acquired after folding in the Tertiary. The mean paleolatitude of the Lower Cretaceous red beds is 11° lower than that of the Lower Cretaceous basalts suggesting the red beds underestimate the true field inclination. We further test this result by calculating the paleolatitudes to a common point of the available Early Cretaceous to Present paleomagnetic poles from red beds and volcanic rocks from central Asian localities north of the Tibetan plateau. We find that paleolatitudes of volcanic rocks roughly equal the paleolatitudes calculated from the reference Eurasian apparent polar wander path (APWP) and that paleolatitudes of red beds are generally 10° to 20° lower than the paleolatitudes of volcanic rocks and those predicted from the reference curve. Our study suggests that central Asian red beds poorly record the Earth's field inclination, which leads to lower than expected paleolatitudes. Good agreement in paleolatitudes from volcanic rocks and the Eurasian APWP argues against proposed canted and non-dipole field models.

  8. Geochronology and geochemistry of Cretaceous Nanshanping alkaline rocks from the Zijinshan district in Fujian Province, South China: Implications for crust-mantle interaction and lithospheric extension

    NASA Astrophysics Data System (ADS)

    Li, Bin; Jiang, Shao-Yong

    2014-10-01

    In situ zircon U-Pb ages and Hf isotopic data, major and trace elements, and Sr-Nd-Pb isotopic compositions are reported for Nanshanping alkaline rocks from the Zijingshan district in southwestern Fujian Province (the Interior or Western Cathaysia Block) of South China. The Nanshanping alkaline rocks, which consist of porphyritic quartz monzonite, porphyritic syenite, and syenite, revealed a Late Cretaceous age of 100-93 Ma. All of the rocks show high SiO2, K2O + Na2O, and LREE but low CaO, Fe2O3T, MgO, and HFSE (Nb, Ta, P, and Ti) concentrations. These rocks also exhibit uniform initial 87Sr/86Sr ratios of 0.7078 to 0.7087 and εNd(t) values of -4.1 to -7.2, thus falling within the compositional field of Cretaceous basalts and mafic dikes occurring in the Cathaysia Block. Additionally, these rocks display initial Pb isotopic compositions with a 206Pb/204Pbi ratio of 18.25 to 18.45, a 207Pb/204Pbi ratio of 15.63 to 15.67, and a 208Pb/204Pbi ratio of 38.45 to 38.88. Combined with the zircon Hf isotopic compositions (εHf(t) = -11.7 to -3.2), which are different from those of the basement rocks, we suggest that Nanshanping alkaline rocks were primarily derived from a subduction-related enriched mantle source. High Rb/Sr (0.29-0.65) and Zr/Hf (37.5-49.2) but relatively low Ba/Rb (4.4-8.1) ratios suggest that the parental magmas of these rocks were most likely formed via partial melting of a phlogopite-bearing mantle source with carbonate metasomatism. The relatively high SiO2 (62.35-70.79 wt.%) and low Nb/Ta (10.0-15.3) ratios, positive correlation between SiO2 and (87Sr/86Sr)I, and negative correlation between SiO2 and εNd(t) of these rocks suggest that the crustal materials were also involved in formation of the Nanshanping alkaline rocks. Combined with geochemical and isotopic features, we infer magmatic processes similar to AFC (assimilation and fractional crystallization) involving early fractionation of clinopyroxene and olivine and subsequent fractionation of

  9. Genetic implications of minor-element and Sr-isotope geochemistry of alkaline rock complexes in the Wet Mountains area, Fremont and Custer counties, Colorado

    USGS Publications Warehouse

    Armbrustmacher, T.J.; Hedge, C.E.

    1982-01-01

    Concentrations of Rb, Sr, and REE (rare earth elements), and Sr-isotopic ratios in rocks of the Cambrian alkaline complexes in the Wet Mountains area, Colorado, show that rocks formed as end-products of a variety of magmas generated from different source materials. The complexes generally contain a bimodal suite of cumulus mafic-ultramafic rocks and younger leucocratic rocks that include nepheline syenite and hornblende-biotite syenite in the McClure Mountain Complex, nepheline syenite pegmatite in the Gem Park Complex, and quartz syenite in the complex at Democrat Creek. The nepheline syenite and hornblende-biotite syenite at McClure Mountain (535??5m.y.) are older than the syenitic rocks at Democrat Creek (511??8m.y.). REE concentrations indicate that the nepheline syenite at McClure Mountain cannot be derived from the hornblende-biotite syenite, which it intrudes, or from the associated mafic-ultramafic rocks. REE also indicate that mafic-ultramafic rocks at McClure Mountain have a source distinct from that of the mafic-ultramafic rocks at Democrat Creek. In the McClure Mountain Complex, initial87Sr/86Sr ratios for mafic-ultramafic rocks (0.7046??0.0002) are similar to those of hornblende-biotite syenite (0.7045??0.0002), suggesting a similar magmatic source, whereas ratios for carbonatites (0.7038??0.0002) are similar to those of nepheline syenite (0.7038??0.0002). At Democrat Creek, initial ratios of syenitic rocks (0.7032??0.0002) and mafic-ultramafic rocks (0.7028??0.0002) are different from those of corresponding rocks at McClure Mountain. ?? 1982 Springer-Verlag.

  10. Geochronology and correlation of Tertiary volcanic and intrusive rocks in part of the southern Toquima Range, Nye County, Nevada

    USGS Publications Warehouse

    Shawe, Daniel R.; Snee, Lawrence W.; Byers, Frank M., Jr.; du Bray, Edward A.

    2014-01-01

    Extensive volcanic and intrusive igneous activity, partly localized along regional structural zones, characterized the southern Toquima Range, Nevada, in the late Eocene, Oligocene, and Miocene. The general chronology of igneous activity has been defined previously. This major episode of Tertiary magmatism began with emplacement of a variety of intrusive rocks, followed by formation of nine major calderas and associated with voluminous extrusive and additional intrusive activity. Emplacement of volcanic eruptive and collapse megabreccias accompanied formation of some calderas. Penecontemporaneous volcanism in central Nevada resulted in deposition of distally derived outflow facies ash-flow tuff units that are interleaved in the Toquima Range with proximally derived ash-flow tuffs. Eruption of the Northumberland Tuff in the north part of the southern Toquima Range and collapse of the Northumberland caldera occurred about 32.3 million years ago. The poorly defined Corcoran Canyon caldera farther to the southeast formed following eruption of the tuff of Corcoran Canyon about 27.2 million years ago. The Big Ten Peak caldera in the south part of the southern Toquima Range Tertiary volcanic complex formed about 27 million years ago during eruption of the tuff of Big Ten Peak and associated air-fall tuffs. The inferred Ryecroft Canyon caldera formed in the south end of the Monitor Valley adjacent to the southern Toquima Range and just north of the Big Ten Peak caldera in response to eruption of the tuff of Ryecroft Canyon about 27 million years ago, and the Moores Creek caldera just south of the Northumberland caldera developed at about the same time. Eruption of the tuff of Mount Jefferson about 26.8 million years ago was accompanied by collapse of the Mount Jefferson caldera in the central part of the southern Toquima Range. An inferred caldera, mostly buried beneath alluvium of Big Smoky Valley southwest of the Mount Jefferson caldera, formed about 26.5 million years

  11. Isotopic compositions of volcanic arc rocks in the Southern Volcanic Zone (33°-43°S), Chile: along- and across-arc variations

    NASA Astrophysics Data System (ADS)

    Jacques, Guillaume; Hoernle, Kaj; Gill, Jim; Wehrmann, Heidi

    2014-05-01

    We investigate young, olivine-bearing volcanic arc (VA) rocks from the Southern Volcanic Zone (33-43°S; SVZ) in Chile, and from the backarc (BA) in Argentina for their major and trace element, and Sr-Nd-Hf-Pb-O isotope geochemistry. The compositional data are processed to identify the source components contributing to the arc magmas and to estimate their proportions, with the aim to better understand the effects of the large-scale along-arc tectonic variations onto melt generation and erupted compositions. The Transitional (T) SVZ (34.5-38°S; Jacques et al., 2013) samples overlap the BA samples in Sr and Nd isotopes, whereas the Central (C) SVZ (38-43°S; Jacques et al., submitted, Chemical Geology) samples are shifted to slightly higher Sr and/or Nd isotope ratios. All samples form a tight correlation on the Pb isotope diagrams. The VA samples plot at the radiogenic end of the positive BA array and overlap trench sediment, indicating mixing between a South Atlantic MORB-type source and a slab component derived from subducted trench sediments and altered oceanic crust. On the Nd versus Hf isotope diagram, the VA and BA form two sub parallel linear trends, neither pointing to subducting sediment. The VA may display an asthenospheric mantle array, whereas enriched Proterozoic lithospheric mantle may be involved in the BA. The CSVZ samples have higher fluid-mobile to fluid-immobile element ratios and lower more- to less-incompatible fluid-immobile element ratios than the TSVZ samples, consistent with higher hydrous melt flux and higher degrees of melting resulting in higher magma production and eruption rates in the CSVZ. Low δ18O(melt) of CSVZ lavas suggests that the source of the enhanced water flux is likely to be hydrated lower crust and serpentinized upper mantle of the incoming plate, resulting from the multiple large fracture zones in this part of the SVZ. The δ18O(melt) values of the NSVZ, TSVZ and BA, on the other hand, largely overlap the MORB mantle

  12. U-Th-Pb geochronology of meta-carbonatites and meta-alkaline rocks in the southern Canadian Cordillera: A geodynamic perspective

    NASA Astrophysics Data System (ADS)

    Millonig, Leo J.; Gerdes, Axel; Groat, Lee A.

    2012-11-01

    U-Pb and Th-Pb ages of zircons from seven meta-carbonatite and three meta-alkaline rock samples provide evidence for three distinct episodes of carbonatite and alkaline magmatism in the southern Canadian Cordillera spanning a period of ~ 460 Ma. The earliest, Neoproterozoic event occurred at ~ 800-700 Ma and coincides with the postulated initial break-up of Rodinia. The second, previously undocumented, event of carbonatitic magmatism is constrained to the Late Cambrian at ~ 500 Ma and corresponds to a period of extensional tectonics that affected the western continental margin of North America from the Canadian Cordillera to the southwestern United States. The youngest and most prevalent period of alkaline igneous activity occurred in Late Devonian to Early Carboniferous times at ~ 360-340 Ma and resulted from extensional tectonics, presumably caused by slab rollback. In addition, different episodes of amphibolite-facies metamorphism subsequently affected the igneous rocks between ~ 155 and 50 Ma. This dataset puts new constraints on the timing of carbonatite and alkaline igneous activity and the evolution of (ancestral) North America's western continental margin from Neoproterozoic to Carboniferous times.

  13. Petrological and geochemical data of volcanic rocks from the southern Afar Depression, Ethiopia.

    NASA Astrophysics Data System (ADS)

    Urbanek, Ch.; Faupl, P.; Richter, W.; Seidler, H.

    2003-04-01

    The geological and petrological investigations (FWF Project P15196) in the southern Afar Depression of Ethiopia support an international palaeoanthropological research-team (PAR) under the leadership of Horst Seidler. Mount Galila is the conspicuous centre of the research area [N 9° 44.101', E 40° 27.368'], situated about 20 km E of the NNE-SSW striking, recently active Hertale Graben, which represents a northernmost segment of the Main Ethiopian Rift (MER). Stratigraphically, the fossiliferous lacustrine and fluvial deposits, as well as the intercalated volcanic layers of the Galila area, belong to the "Upper Stratoid Series" (5-1.4 Ma) and will be named the Mount Galila Formation. They are similar to the Awash Group, from which very famous early hominid fossils have been described. In the Mount Galila Fm., 7 main volcanic horizons serve as marker beds comprising basalts, ignimbrites, tuffs and tuffaceous sands. The basalt horizons in the research area represent basaltic lava flows each consisting of one single flow unit c. 5 meters thick with maximum 5 cooling units. A first set of geochemical data from XRF spectrometry comprising main and trace element analysis shows characteristics for the volcanic marker beds as following: The basalts are clearly tholeiitic in the main elements (FeO/MgO/Alk) and show typical trace element distributions (e.g. Zr/Y-Zr; Ti/100-Yx3-Zr) as Within Plate Tholeiit Basalts. All basalt samples contain access 40Ar which can be explained by specific erruption mechanisms that leads to analytical problems for 40Ar/39Ar dating. In the TAS diagram after LeMaitre 1984 the ignimbrites vary at high alkali levels (7-9%) from trachytic to dacitic and rhyolitic composition, whereas at low alkali contents (<7%) they plot into the andesitic field. Compared to the basalts, the geochemistry of the ignimbrites is much more inhomogenous. Tuffs and tuffaceous sands are relevant as marker beds especially for the palaeoanthropological excavations in the

  14. Cenozoic volcanic rocks of North Kamchatka: In search of subduction zones

    NASA Astrophysics Data System (ADS)

    Shapiro, M. N.; Solov'ev, A. V.

    2011-05-01

    Two belts of subaerial volcanic rocks—the Eocene Kinkil belt and the Neogene belt of the Sredinny Range—extend along the Kamchatka Isthmus. It is suggested that their formation is related to subduction of the oceanic lithosphere beneath the continental margin of North Kamchatka. The oceanic lithosphere consumed in the subduction zones could have been formed as a result of active spreading in the Komandorsky Basin. In the simplest case, both spreading and subduction reflect the northwestward motion of the lithosphere of the Komandorsky Plate relative to Kamchatka, the Shirshov Ridge, and the Aleutian Basin combined into one relatively immobile plate conventionally called the North American Plate. The authors perform a simulation of conjugate spreading and subduction. The most important parameter determining the regional geodynamics—the velocity of the Komandorsky Plate moving relative to the North American Plate—is taken as 2.5, 5.0, and 7.5 cm/yr. The calculated ages of the onset and end of volcanic activity in the aforementioned belts are compared with the dates obtained with the isotopic and paleontological methods. For the Eocene Kinkil belt, where volcanism started 44 Ma ago, the model age of the onset of subduction depends on the accepted velocity of the motion of the Komandorsky Plate and varies from 54 Ma at the velocity of 2.5 cm/yr to 47.5 Ma at the velocity of 7.5 cm/yr. It can be assumed that the model of fast subduction in this age interval is most consistent with the geological data. For the Miocene-Pliocene belt of the Sredinny Range, assuming the velocity of the motion of the Komandorsky Plate at 5.0 and 7.5 cm/yr, multiple rifting at the boundary with the Shirshov Ridge should be assumed. Therefore, for the end of the Neogene, a model with low velocity (2.5-5.0 cm/yr, i.e., about 4.0 cm/yr) is preferable.

  15. Physical and hydraulic properties of volcanic rocks from Yucca Mountain, Nevada

    USGS Publications Warehouse

    Flint, L.E.

    2003-01-01

    A database of physical and hydraulic properties was developed for rocks in the unsaturated zone at Yucca Mountain, Nevada, a site under consideration as a geologic repository for high-level radioactive waste. The 5320 core samples were collected from 23 shallow (<100 m) and 10 deep (500-1000 m) vertical boreholes. Hydrogeologic units have been characterized in the unsaturated zone [Flint, 1998] that represent rocks with ranges of welding, lithophysae, and high and low temperature alteration (as a result of the depositional, cooling, and alterational history of the lithostratigraphic layers). Lithostratigraphy, the hydrogeologic unit, and the corresponding properties are described. In addition, the physical properties of bulk density, porosity, and particle density; the hydraulic properties of saturated hydraulic conductivity and moisture retention characteristics; and the field water content were measured and compiled for each core sample.

  16. Correcting for nucleogenic ^{36}Cl in cosmogenic ^{36}Cl dating of volcanic rocks from the Erciyes volcano, Central Turkey

    NASA Astrophysics Data System (ADS)

    Sarikaya, M. A.; Zreda, M.; Desilets, D.; Ciner, A.; Sen, E.

    2006-12-01

    Many radiometric methods are suitable for dating lava flows, but none is reliable for routine dating of lava flows younger than 10 ky. The cosmogenic ^{36}Cl method seems promising because it can be applied to any type of rock and laboratory and analytical work is easy and fast. But low cosmogenic ^{36}Cl inventory (after short exposure duration), combined with possible large non-cosmogenic component, makes this technique difficult to apply in a routine fashion. We applied the ^{36}Cl method to date a lava flow and the 14C technique to date the associated ash flow from the Erciyes (Argaeus) volcano, central Turkey. The average of three cosmogenic ^{36}Cl ages is 7.3 \\mp 0.5 ky and the average of two radiocarbon ages is 9.5 \\mp 0.3 ky (calibrated using Calib 5.0). The difference could be due to the overestimation of the calculated nucleogenic ^{36}Cl, which makes up almost one-third of the measured ^{36}Cl. If the nucleogenic component were set to zero, the average ^{36}Cl age would be 10.3 \\mp 0.2 ky. Thus, the ^{36}Cl age should be in the range between 7.3 ky and 10.2 ky, which includes the 14C age near the upper end of the interval. Under the assumption that the 14C age is correct and that the nucleogenic ^{36}Cl has reached a secular equilibrium with the magma, the nucleogenic ^{36}Cl needed to reconcile the ^{36}Cl and 14C ages is only about one-fifth of that previously calculated. In order to investigate this disparity of ages and possible calculating errors of nucleogenic ^{36}Cl, we are analyzing rock samples from where we can directly measure nucleogenic component of ^{36}Cl. This work is important for developing better ways to estimate the nucleogenic ^{36}Cl, which will improve the accuracy of ^{36}Cl dating of young volcanic rocks.

  17. Monitoring of the volcanic rock compositions during the 2012-2013 fissure eruption at Tolbachik volcano, Kamchatka

    NASA Astrophysics Data System (ADS)

    Volynets, Anna O.; Edwards, Benjamin R.; Melnikov, Dmitry; Yakushev, Anton; Griboedova, Irina

    2015-12-01

    Here we present the results from monitoring of the composition of rocks produced during the 2012-2013 fissure eruption at Tolbachik volcano (FTE). Major and trace element concentrations in 75 samples are reported. Products of this eruption are represented by high alumina basaltic trachyandesites with higher alkalis and titanium contents than in all previously studied rocks of the Tolbachik monogenetic volcanic field. Rocks erupted during the first three days (27-30 November) from the northern (also called Menyailov) group of vents are the most silica- and alkali-rich (SiO2 concentrations up to 55.35 wt.% and K2O up to 2.67 wt.%). From December onwards, when the eruptive activity switched from the Menyailov vents to the southern (Naboko) group of vents, silica content dropped by 2 wt.%, concentrations of MgO, FeO, TiO2 and Mg# increased, and K2O and Na2O concentrations and K2O/MgO ratio decreased. For the rest of the eruption the compositions of rocks remained constant and homogeneous; no systematic compositional differences between lava, bombs and scoria samples are evident. Trace element distributions in the rocks of the Menyailov and Naboko vent lavas are relatively uniform; Menyailov lavas have slightly higher Th, Nb, Hf, Y, and HREE concentrations than the Naboko vent lavas at more or less constant element ratios. We explain the initial change in geochemistry by tapping of a slightly cooler and fractionated (~ 3% Mt and 8% Cpx) upper part of the magma storage zone before the main storage area began to feed the eruption. Thermodynamic constraints show that apparent liquidus temperatures varied from 1142 °C to 1151 °C, and thermodynamic modeling shows that variations in compositions are consistent with a high degree of low pressure (100-300 MPa), nominally anhydrous fractionation of a parent melt compositionally similar to the 1975 Northern Breakthrough high-Mg basalt. Geochemistry, petrological observations and modeling are in agreement with the newly erupted

  18. Numerical Calculation of LP Seismic Signals Modeling the Fluid-Rock Interaction in Simulated Volcanic Conduits

    NASA Astrophysics Data System (ADS)

    Arciniega-Ceballos, Alejandra; Corona-Romero, Pedro; Sanchez-Sesma, Francisco

    2010-05-01

    We present an investigation of the fluid-solid dynamic interaction of a fluid-driven cylindrical conduit embedded within an infinite, homogeneous elastic space with physical properties similar to those encountered in volcanic environments. In our model, a pressure transient is applied at the bottom of the conduit, which perturbs the steady flow of incompressible viscous fluid, driven by a pressure gradient. The model includes radial variation of a cylindrical fluid-filled conduit driven by changes in the flow velocity of a Newtonian fluid and a pressure gradient. Both fluid and solid are dynamically coupled by the continuity of radial velocities and shear and radial stresses at the conduit wall. The conduit dynamics are governed by three ordinary non-linear differential equations of second order, which are solved numerically by applying a fifth-order Runge-Kutta scheme. Our model allows for any number of pipe segments of different sizes coupled in series, thus representing an extended source region, which closely mimics the geometry of realistic volcanic conduits. Various examples of fluid-filled pipe-systems, starting from the simplest penny-shape geometries up to conduits of hundreds of meters in length, are presented. The values assumed for the fluid density and viscosity are in the mean range of basaltic and andesitic composition. Far-field velocity synthetics radiated by the motion of the conduit and fluid flows ascending to the surface display characteristic waveforms and frequency contents that closely resemble those of long-period (LP) signals observed at active volcanoes.

  19. Synopsis of volcanic stratigraphy

    NASA Technical Reports Server (NTRS)

    Hammond, P. E.

    1974-01-01

    Volcanic stratigraphic units are mappable layered units composed of volcanic rocks that are formed on land (subaerially) or under water (subaqueously) by volcanic processes. At least ten different types of volcanic stratigraphic units are recognized. The characteristics for each are discussed briefly and some typical examples are illustrated by diagrams to show their salient features.

  20. 226Ra or 226Ra/Ba dating of Holocene volcanic rocks: application to Mt. Etna and Merapi volcanoes

    NASA Astrophysics Data System (ADS)

    Condomines, M.; Gauthier, P. J.; Tanguy, J. C.; Gertisser, R.; Thouret, J. C.; Berthommier, P.; Camus, G.

    2005-02-01

    This paper shows how 226Ra- 230Th disequilibria can be used to date Holocene volcanic rocks from some well selected volcanoes. A systematic study of these disequilibria on historical or well-dated volcanic samples is indeed first required to test the applicability of this method. Two examples are described here to illustrate its potential. In the case of Mt. Etna, the good correlation observed between ( 226Ra) 0 activities at the time of eruption and Th contents in lava flows from the last two millennia [M. Condomines, J.C. Tanguy, V. Michaud, Magma dynamics at Mt. Etna: constraints from U-Th-Ra-Pb radioactive disequilibria and Sr isotopes in historical lavas, Earth Planet. Sci. Lett. 132 (1995) 25-41] is used to infer the ages of several newly analysed lava flows. The calculated ages are in good agreement with those deduced from the archaeomagnetic curve describing the variation of the geomagnetic field direction in southern Italy [J.C. Tanguy, I. Bucur, J.F.C. Thompson, Geomagnetic secular variation in Sicily and revised ages of historic lavas from Mt. Etna, Nature 318 (1985) 453-455, J.C. Tanguy, M. Le Goff, V. Chillemi, A. Paiotti, C. Principe, S. La Delfa, G. Patane, Variation séculaire de la direction du champ géomagnétique enregistrée par les laves de l'Etna et du Vésuve pendant les deux derniers millénaires, C. R. Acad. Sci. Paris 329 (1999) 557-564, J.C. Tanguy, M. Le Goff, C. Principe, S. Arrighi, V. Chillemi, A. Paiotti, S. La Delfa, G. Patane, Archaeomagnetic dating of Mediterranean volcanics of the last 2100 years: validity and limits. Earth Planet. Sci. Lett. 211 (2003) 111-124]. We also present a whole set of new U-series data on historical, recent, and older samples from Merapi (Indonesia), and show that the ( 226Ra)/Ba ratio has probably maintained a quasi-steady state value during at least the past four millennia, and can be used to infer the ( 226Ra) 0/Ba ratio of old volcanics at the time of eruption, and thus their ages. Comparison with

  1. Implementation and compatibility of a North American Volcanic and Plutonic rock database (NAVDAT)

    NASA Astrophysics Data System (ADS)

    Walker, J. D.; Glazner, A. F.; Bowers, T. D.; Straus, A. K.; Farmer, G. L.; Carlson, R. W.; Black, R. A.; Grossman, J. N.

    2002-12-01

    NAVDAT is a database for igneous rocks in western North America that will contain geochemical and age information primarily on Cenozoic rocks. NAVDAT will allow exploration of temporal and spatial patterns in igneous activity, and to connect these patterns with local and regional tectonic development and lithospheric structure. The database will be web-accessible for downloads and queries (navdat.geo.ku.edu). Allied information, such as geologic and geophysical maps, crustal structure, etc., will also be available through a map interface. We have attempted to keep the NAVDAT schema compatible with that for PetDB and GEOROC (petdb.ldeo.columbia.edu, georoc.mpch-mainz.gwdg.de) in order to build consensus on an overall structure for of an igneous rock database. The issues to be addressed by continent-based NAVDAT, however, are somewhat different from ocean-floor based PetDB, and the schema required numerous modifications. We have extended the schema in several areas to meet the needs of the on-land database. Location and age information become critical because we are trying define changes in magma source with time tied to structural position and setting. For this reason, we have added more fields to cover such issues as how a rock is dated and where it is located. In addition, we have implemented an expanded reference section that imports all information available in AGI's Georef database. This should allow for superior query ability. One recurring issue in constructing the NAVDAT database is the inconsistency in the way geochemical data are reported. The following is a suggested publication check-list for geochemists that will enable more robust database construction: 1) all samples must have locations reported as accurately as possible, not just located on a map figure or given as a general location; 2) known sample ages must be given and the method of dating explained (e.g., directly dated, stratigraphically bracketed, or correlated in a regional sense); 3

  2. New 40Ar/39Ar isotopic dates from Miocene volcanic rocks in the Lake Mead area and southern Las Vegas Range, Nevada

    USGS Publications Warehouse

    Harlan, S.S.; Duebendorfer, E.M.; Deibert, J.E.

    1998-01-01

    New 40Ar/39Ar dates on volcanic rocks interlayered with synextensional Miocene sedimentary rocks in the western Lake Mead area and southern end of the Las Vegas Range provide tight constraints on magmatism, basin formation, and extensional deformation in the Basin and Range province of southern Nevada. Vertical axis rotations associated with movement along the Las Vegas Valley shear zone occurred after 15.67??0.10 Ma (2??), based on a 40Ar/39Ar date from a tuff in the Gass Peak formation in the southern Las Vegas Range. Basaltic magmatism in the western Lake Mead area began as early as 13.28??0.09 Ma, based on a date from a basalt flow in the Lovell Wash Member of the Horse Spring Formation. Isotopic dating of a basalt from the volcanic rocks of Callville Mesa indicates that these rocks are as old as 11.41??0.14 Ma, suggesting that volcanic activity began shortly after formation of the Boulder basin, the extensional basin in which the informally named red sandstone unit was deposited. The red sandstone unit is at least as old as 11.70??0.08 Ma and contains megabreccia deposits younger than 12.93??0.10 Ma. This results shows that formation of the Boulder basin was associated with development of topographic relief that was probably generated by movement along the Saddle Island low-angle normal fault. Stratal tilting associated with extension occurred both prior to and after 11.5 Ma.

  3. High-resolution 40Ar 39Ar chronology of Oligocene volcanic rocks, San Juan Mountains, Colorado

    USGS Publications Warehouse

    Lanphere, M.A.

    1988-01-01

    The central San Juan caldera complex consists of seven calderas from which eight major ash-flow tuffs were erupted during a period of intense volcanic activity that lasted for approximately 2 m.y. about 26-28 Ma. The analytical precision of conventional K-Ar dating in this time interval is not sufficient to unambiguously resolve this complex history. However, 40Ar 39Ar incremental-heating experiments provide data for a high-resolution chronology that is consistent with stratigraphie relations. Weighted-mean age-spectrum plateau ages of biotite and sanidine are the most precise with standard deviations ranging from 0.08 to 0.21 m.y. The pooled estimate of standard deviation for the plateau ages of 12 minerals is about 0.5 percent or about 125,000 to 135,000 years. Age measurements on coexisting minerals from one tuff and on two samples of each of two other tuffs indicate that a precision in the age of a tuff of better than 100,000 years can be achieved at 27 Ma. New data indicate that the San Luis caldera is the youngest caldera in the central complex, not the Creede caldera as previously thought. ?? 1988.

  4. Helium isotopic variations in volcanic rocks from Loihi Seamount and the Island of Hawaii

    USGS Publications Warehouse

    Kurz, M.D.; Jenkins, W.J.; Hart, S.R.; Clague, D.

    1983-01-01

    Helium isotopic ratios ranging from 20 to 32 times the atmospheric 3He 4He(RA) have been observed in a suite of 15 basaltic glasses from the Loihi Seamount. These ratios, which are up to four times higher than those of MORB glasses and more than twice those of nearby Kilauea, are strongly suggestive of a primitive source of volatiles supplying this volcanism. The Loihi glasses measured span a broad compositional range, and the 3He/4He ratios were found to be generally lower for the alkali basalts than for the tholeiites. The component with a lower 3He 4He ratio appears to be associated with olivine xenocrysts, within which fluid inclusions are probably the carrier of contaminant helium. One Loihi sample has a much lower isotopic ratio ( 30 RA) helium with some (variable) component of lithospheric contamination added during "breakthrough", while the later stages are characterized by a relaxation toward lithospheric 3He 4He ratios (??? 8 RA) due to isolation of the diapir from the mantle below (as the plate moves on), and subsequent mining of the inherited helium and contamination from the surrounding lithosphere. The abrupt contrast in 3He 4He ratios between Kilauea and Loihi, despite their close proximity, is indicative of the small lateral extent of the plume. ?? 1983.

  5. A highly unradiogenic lead isotopic signature revealed by volcanic rocks from the East Pacific Rise.

    PubMed

    Mougel, Berengere; Agranier, Arnaud; Hemond, Christophe; Gente, Pascal

    2014-01-01

    Radiogenic isotopes in oceanic basalts provide a window into the different geochemical components defining the composition of Earth's mantle. Here we report the discovery of a novel geochemical signature in volcanic glasses sampled at a sub-kilometre scale along the East Pacific Rise between 15°37'N and 15°47'N. The most striking aspect of this signature is its unradiogenic lead ((206)Pb/(204)Pb=17.49, (207)Pb/(204)Pb=15.46 and (208)Pb/(204)Pb=36.83). In conjunction with enriched Sr, Nd and Hf signatures, Pb isotopes depict mixing lines that trend away from any known mantle end-members. We suggest that this unradiogenic lead component sampled by magmatic melts corresponds to a novel upper mantle reservoir that should be considered in the Pb isotope budget of the bulk silicate Earth. Major, trace element and isotope compositions are suggestive of an ancient and lower continental origin for this unradiogenic lead component, possibly sulphide-bearing pyroxenites that were preserved even after prolonged stirring within the ambient upper mantle. PMID:25027032

  6. A Clinopyroxene-Plagioclase Geobarometer for A-type Silicic Volcanic Rocks

    NASA Astrophysics Data System (ADS)

    Wolff, J.; Iveson, A. A.; Davis, K.; Johnson, T. A.; Gahagan, S.; Ellis, B. S.

    2015-12-01

    Constraining the crustal storage depths of magmas is important in understanding volcanism. The reaction: anorthite (pl) = Ca-Tschermak's (cpx) + silica (Q or liq) has a large volume change and hence offers potential as a geobarometer, but has not been extensively exploited as such. One of the chief barriers to its wide application is consistent estimation of melt silica activity for assemblages that lack quartz. We have skirted this problem by confining attention to metaluminous silicic compositions (SiO2 > 60% by weight), for which silica activity during crystallization is presumed to be close to 1, and calibrated the barometer for the range 0 - 2 GPa using the LEPR database and additional experiments from the literature. Additional improvement is obtained by excluding hydrous phase-bearing assemblages. Despite the analytical uncertainties present in older experimental investigations, with knowledge of temperature, and clinopyroxene, plagioclase and host melt compositions, pressures for amphibole- and biotite-free dacites and rhyolites can be estimated to ±0.17 GPa (1 sigma). The limitations of the barometer render it most applicable to intraplate, A-type rhyolites. Application to one such system, the Snake River Plain rhyolites, indicate that both melt-hosted phenocrysts and clinopyroxene-plagioclase aggregate grains found in these rhyolites formed at low pressures, <0.5 GPa. This is consistent with isotopic evidence for a shallow crustal origin for Snake River Plain rhyolites.

  7. Volcanic Rocks Collected With ROV Tiburon From Rodriguez Seamount, Located at the Continental Slope of the California Borderland

    NASA Astrophysics Data System (ADS)

    Davis, A. S.; Clague, D. A.; Paduan, J. B.

    2004-12-01

    Volcanic rocks were collected from Rodriguez Seamount at the outer margin off the Continental Borderland with MBARI's ROV Tiburon in October 2003 and April 2004. Six dives recovered lava and volcaniclastic samples from the deep flanks ( ˜2120 m) to the summit at 630 m. Whole rock compositions of plagioclase-olivine-clionpyroxene bearing lava samples are predominantly alkalic basalt (<8% MgO) and hawaiite with minor mugearite (MgO=1.5%). Glass compositions of pillow rims and of volcaniclastic fragments in breccia and bedded sandstone are predominantly hawaiite, mugearite and minor evolved alkalic basalt. The lava samples include one rhyolite and one basaltic andesite with subduction-related chemistry; they are probably erratics. Other clearly identifiable erratics include granite, quartzite, amphibolite, and bored, erosion-sculpted sandstone, resembling typical beach deposits. Most of these erratics are pebble- to small cobble-size and occur in conglomerate and crossbedded sandstone that surround the summit at a break in slope that most likely marks the shoreline when Rodriguez was an island. The lava outcrops on the gently domed platform of the summit are dense, oxidized àà-like flows without glassy rinds. Sulfur content of glass, collected from the flanks of the volcano, ranges from 1300 ppm of a glass inclusion in an olivine crystal to ˜160 ppm of volcaniclastic grains, indicating extensive degassing. Petrographically and chemically these lavas are virtually identical to those erupted on Miocene seamounts offshore central California (e.g. Davidson, Guide, Pioneer, Gumdrop seamounts, Davis et al, 2002) as well as Northeast Bank on the continental shelf south of Rodriguez and seamounts farther offshore from the Continental Borderland (e.g. Little Joe, San Marcos, San Juan seamounts, Clague et al, unpublished; Davis et al., 1995). Trace element abundances and ratios (e.g. LREE, Zr/Nb, Ta/Nb) also completely overlap with those from the other sites, suggesting

  8. Laboratory and Remote Spectroscopy of Volcanic Rocks from Mauna Iki, Hawaii

    NASA Astrophysics Data System (ADS)

    Varriale, J. A.; Rogers, D.; Arnold, J. A.; Glotch, T. D.

    2012-12-01

    Previous studies have shown that remotely measured thermal infrared spectra of Hawaiian basalt flows are dominated by thin alteration coatings. The objectives of this work are to characterize the spectral properties of natural surfaces from flows of varying emplacement age as well as from flows of varying crystallinity and primary mineralogy to understand how duration of exposure and primary rock characteristics influence the alteration assemblages and their spectral properties. We have collected samples from the Mauna Iki-area lava flows that represent primary compositional variation across the flows, and that exhibit a range of alteration coatings. Samples were cataloged and prepared for spectral measurements. Mid-IR (5-50 μm) emissivity spectra and VNIR (~0.85-2.5 μm) reflectance spectra were collected. We also directly compared atmospherically corrected spectra from AVIRIS and ASTER at the sample locations to VNIR and mid-IR laboratory spectra, respectively. In most cases, a spectrally representative sample was collected, and the thin (10's of microns) alteration coatings dominate the spectral signatures of the remotely acquired data. Some sand samples were also collected. As expected, the sands are spectrally similar to fresh-cut rock surfaces in laboratory spectra, suggesting that remote measurements of sand could provide an indication of the unaltered surface mineralogy. However, remote-lab spectral comparisons showed that although widespread regions of sediment cover are apparent from the ground, the sand was not the spectrally dominant material in the regions where it was sampled and thus the primary mineralogy could not be identified remotely. Mid-IR spectra were modeled using a linear least-squares minimization routine to estimate modal abundances in fresh-cut and natural surfaces. The modeling identified key mineral groups within the composition of the altered and freshly cut surfaces; with basalt glass, olivine and plagioclase accounting for 59% of

  9. Petrogenesis of Challis Volcanic Group, east-central Idaho

    NASA Astrophysics Data System (ADS)

    Schleiffarth, W. K.; Larson, P. B.

    2013-12-01

    The Eocene Challis-Kamloops volcanic belt (CKVB) extends south and east from northern British Columbia to central Idaho and is related to the paleotectonic plate interaction between the Farallon and North American plates. Numerous volcanic fields are scattered throughout the CKVB and show a wide range of eruption styles, tectonic environments, and geochemical compositions. Several volcanic fields produced calc-alkaline rocks, while others produced moderately to strongly alkaline rocks. Some volcanic fields have a significant slab component, while others show no direct evidence of subduction-related magmatism. Proposed models for tectonic controls on the CKVB include continental volcanic arc delamination of subducted slab, rifted arc, slab window, and extensional continental tectonism. However, there is no generally accepted explanation for the petrogenesis of the CKVB. The Challis Volcanic Group (CVG) of central Idaho, located in the southern portion of the belt, is the largest of the Eocene volcanic fields (25,000 km2). The CVG is of interest because it exhibits very diverse volcanic deposits and compositions and may accurately represent the CKVB. Challis volcanism was synchronous with extension along the NE-SW-trending trans-Challis fault system and resulted in similarly oriented normal faults, dikes, calderas, and exhumation of the Pioneer core complex. The CVG covers much of central Idaho with exposures extending from the Sawtooth Mountains in the west to the Lemhi and Beaverhead ranges to the east. The CVG has high alkaline contents relative to calc-alkaline subduction-related volcanic rocks, varying isotopic signatures, and prevalent extensional features. These facts, coupled with the lack of obvious orientation of volcanic fields throughout the CKVB, explain why the petrogenesis of Eocene volcanism of the inland Pacific Northwest is controversial. Rare earth element concentrations and Sr, Nd, and Pb isotope ratios show that the CVG represents a mixture of

  10. Tectonic implications of space-time patterns of Cenozoic volcanism in the Palo Verde Mountain volcanic field, southeastern California

    SciTech Connect

    Murray, K.S.

    1981-01-01

    Variations in Cenozoic volcanism in the western United States are believed to correlate closely with changes in tectonic setting. A transition in volcanic association from calc-alkaline to fundamentally basaltic volcanism and subsequent crustal extension, appears to have coincided temporally with the initial collision of the East Pacific Rise with the continental margin trench off western North America, between 28 and 25 Ma. The volcanic stratigraphy of the Palo Verde Mountain volcanic field is broadly similar to other volcanic centers in southeastern California and can be divided into tripartite regional stratigraphy. A basal sequence of andesitic to rhyolitic lava flows, plugs, domes, and extensive pyroclastic deposits rests unconformably on pre-Cenozoic basement rocks. The basal sequence is intruded by cogenetic Cenozoic plutonic rocks and overlain by basaltic to rhyolitic lava flows, dikes, and a second widespread assemblage of pyroclastic deposits, cumulatively referred to as the silicic sequence. The youngest volcanic rocks of the field include olivine basalt flows and breccia which occur at scattered localities in the Palo Verde Mountains. The age, stratigraphy, and chemistry of the intermediate and basaltic composition volcanic rocks broadly supports previously cited volcanic-tectonic models, if modified to incorporate modern plate reconstruction theory. This modification results in a southeast migration of the transition to basaltic volcanism to southeastern California occurring significantly later in time than the previously cited ages of transition. Moreover, this southeast migration of the volcanic transition is coincident with the inception of Basin and Range faulting and the initiation of movement on the San Andreas fault south of the Transverse Ranges, corresponding to the southward migration of the Pacific-Cocos Ridge.

  11. Helium- and lead-isotope geochemistry of oceanic volcanic rocks from the East Pacific and South Atlantic. Doctoral thesis

    SciTech Connect

    Graham, D.W.

    1987-01-01

    Glassy basalts erupted at young Pacific seamounts and along the mid-ocean ridge in the South Atlantic, and volcanic rocks from the island of St. Helena were studied for He and Pb isotopes. (U+TH)/He ages of seamount alkali basalts were determined from the isotope disequilibrium of (3)He/(4)He between He trapped in vesicles and that dissolved in the glass phase. The method allows alkalic lavas to be dated in the age range of 103 to 106 years. Tholclites at the EPR seamounts have He, Pb, Sr and Nd isotope compositions indistinguishable from MORB, while associated alkali basalts show more radiogenic signatures. The low (3)He/(4)He in the vesicles of alkali basalts (1.2-2.6 RA), their low helium concentrations, and systematic variations with extent of differentiation suggest that magmatic processes influence (3)He/(4)He in these alkalic lavas. Pb-Sr-Nd isotopes at Shimada seamount (17 deg N, 117 deg W) indicate the presence of enriched mantle beneath the East Pacific which resembles that beneath Samoa. Low (3)He/(4)He (4-5 RA) appears to be an inherent characteristic of the component. Much of the South Atlantic ridge axis displays (3)He/(4)He lower than normal MORB, and is apparently contaminated by off-axis hotspots. He-Pb systematics along the ridge suggest that (3)He/(4)He at St. Helena is less than MORB, consistent with values measured by in vacuo crushing of olivine and pyroxene in St. Helena rocks (approx. 5.8 RA).

  12. 3.5 billion years of glass bioalteration: Volcanic rocks as a basis for microbial life?

    SciTech Connect

    Staudigel, H.; Furnes, H.; McLoughlin, N.; Banerjee, N.R.; Connell, L.B.; Templeton, A.

    2009-04-07

    Alteration textures in volcanic glass from the seafloor fall into two classes, one suggestive of abiotic/diffusive hydration and chemical exchange, and another likely to be caused by microbial, cavity-forming, congruent dissolution. Glass bioalteration is common in submarine lavas throughout the world's ocean, dominant in the upper 300 m of the oceanic crust, and found in all well-preserved ophiolites and greenstone belts dating back to 3.5 Ga. It may yield a significant fraction of the global biomass and geochemical fluxes and is relevant to the development of the earliest life on Earth. We present a critical review concerning these glass bioalteration textures and present new data on their microchemical environment. We explore arguments for their biogenicity and further develop the prevalent model for their formation by relating corrosion morphology to the mechanism of microbial dissolution. Biological alteration produces conspicuous micron-scale granular and tubular textures. Granular glass alteration is well explained by colonizing microbes that selectively dissolve the glass in their contact area, forming a sponge-like interconnected network of micron-sized cavities along glass surfaces. Tubular alteration meanwhile, is more likely to be caused by filamentous cell extensions in a process similar to fungal tunneling of soil feldspars and marine carbonates. While we see clear functional similarities to fungal dissolution behavior, we do not know whether fungal or prokaryotic organisms are involved. However, this functional constraint may eventually help to identify potential microbes responsible for these features, potentially including eukaryotic or prokaryotic organisms. Yet, we caution that these organisms may be difficult to identify and to study, because they are likely to be sparsely distributed, slow growing, and difficult to cultivate.

  13. 3.5 billion years of glass bioalteration: Volcanic rocks as a basis for microbial life?

    NASA Astrophysics Data System (ADS)

    Staudigel, Hubert; Furnes, Harald; McLoughlin, Nicola; Banerjee, Neil R.; Connell, Laurie B.; Templeton, Alexis

    2008-08-01

    Alteration textures in volcanic glass from the seafloor fall into two classes, one suggestive of abiotic/diffusive hydration and chemical exchange, and another likely to be caused by microbial, cavity-forming, congruent dissolution. Glass bioalteration is common in submarine lavas throughout the world's ocean, dominant in the upper 300 m of the oceanic crust, and found in all well-preserved ophiolites and greenstone belts dating back to 3.5 Ga. It may yield a significant fraction of the global biomass and geochemical fluxes and is relevant to the development of the earliest life on Earth. We present a critical review concerning these glass bioalteration textures and present new data on their microchemical environment. We explore arguments for their biogenicity and further develop the prevalent model for their formation by relating corrosion morphology to the mechanism of microbial dissolution. Biological alteration produces conspicuous micron-scale granular and tubular textures. Granular glass alteration is well explained by colonizing microbes that selectively dissolve the glass in their contact area, forming a sponge-like interconnected network of micron-sized cavities along glass surfaces. Tubular alteration meanwhile, is more likely to be caused by filamentous cell extensions in a process similar to fungal tunneling of soil feldspars and marine carbonates. While we see clear functional similarities to fungal dissolution behavior, we do not know whether fungal or prokaryotic organisms are involved. However, this functional constraint may eventually help to identify potential microbes responsible for these features, potentially including eukaryotic or prokaryotic organisms. Yet, we caution that these organisms may be difficult to identify and to study, because they are likely to be sparsely distributed, slow growing, and difficult to cultivate.

  14. Petrochemical Results for Volcanic Rocks recovered from SHINKAI 6500 diving on the Bonin Ridge (27°15'N-28°25'N): submarine extension of Ogasawara forearc volcanism

    NASA Astrophysics Data System (ADS)

    Bloomer, S. H.; Kimura, J.; Stern, R. J.; Ohara, Y.; Ishii, T.; Ishizuka, O.; Haraguchi, S.; Machida, S.; Reagan, M.; Kelley, K.; Hargrove, U.; Wortel, M.; Li, Y. B.

    2004-12-01

    Four SHINKAI 6500 submersible dives (dive #823 to #826) were performed along the Bonin Ridge escarpment west of Ogasawara (Bonin) Islands in the West Pacific during May 2004, in the hopes of finding exposures of lower crust of the IBM forearc. The Ogasawara Islands are located on the Bonin ridge, exposing 48-40 Ma boninites on Chichi-jima and depleted arc tholeiite lavas of the same age on Haha-jima. These extremely depleted lavas are believed to have been generated when subduction began beneath the Izu-Bonin-Mariana oceanic arc system. Subsequent rifting (35-30 Ma) formed the Bonin Trough and a 350 km long N-S trending eastern escarpment (Bonin Ridge), where we concentrated our dives. We observed lavas and volcaniclastic sequences by the four SHINKAI dives along the escarpment, and 16 fresh basaltic to andesitic lava samples have been recovered. The first three dives appear to have sampled volcanic constructs, of presumed Oligocene age, along the escarpment, whereas the last dive sampled exposures similar to Eocene rocks of the Bonin islands, including nummulitic limestone. The lava samples were analyzed by ICP-MS at Shimane University for 30 incompatible trace elements. All samples show arc-like chemical signatures, including elevated concentrations of LIL elements, depletions in Ta and Nb, and spikes in Pb, Sr, and Li. All samples show modest enrichments in LREE. A lava sample from the northernmost dive #824 is identical with the depleted tholeiite from Haha-jima Islands at the southernmost end of the Bonin Ridge in terms of trace element characteristics. Other lava samples from northern three dives (#823, #824, #825) have tholeiitic affinities with more elevated highly incompatible elements. This suggests derivation of the series of lavas by different degree of partial melting of a similar source mantle. Samples from southernmost dive site #826, immediately northwest of Chichi-jima Islands, are boninites with U-shaped REE patterns and relatively enriched Zr and

  15. Geochemistry of Phosphorus and Nitrogen in Volcanic Rocks Altered by Submarine Hydrothermal Activities at the Suiyo Seamount in Japan

    NASA Astrophysics Data System (ADS)

    Noda, M.; Kakegawa, T.; Naraoka, H.; Marumo, K.; Urabe, T.

    2002-12-01

    Phosphorus and nitrogen are essential major elements for all microorganisms. In order to understand the ecological conditions of subvent microorganisms and thermophilic microorganisms on ocean floor, it is necessary to understand the behavior of bio-essential elements not only in hydrothermal fluids but also in the subvent environment. Nine sites of hydrothermal discharging area were drilled in the Suiyo volcanic caldera, Izu-Ogasawara (Bonin) island-arc, western Pacific. Approximately 2 to 10 m deep drill core samples were recovered in the last two years. Chemical compositions and hydrothermal mineral assemblages in the drilled core samples were determined by XRF, ICP-MS, and XRD. Morphology of phosphorous-bearing minerals and their chemistry were examined by electron microprobe. Nitrogen isotopes were measured by the EA-IRMS system. Primary igneous-rock texture (such as euhedral plagioclase phenocryst) is found in the less altered rocks. They often associated with montmorillonite. Highly altered rocks are divided into two groups. First group is characterized by extensive (up to 90%) replacement of primary igneous mineral assemblage by chlorite, mica and sulfide. Second group is cemented with large amounts of sulfates with sulfide (mainly pyrite). It is found in a few drill core sections that hydrothermal hydrous silicate minerals change with depth from montmorillonite to chlorite and mica through mixed layer of chlorite/montmorillonite. This may suggest the more extensive and higher temperature alteration in deeper zones in a certain area. Electron microprobe analyses and bulk chemical composition indicate that the depletion of phosphorous in altered rocks (below 0.1 wt%) but enrichment of phosphorous in sulfide zones. This suggests that phosphorous was easily dissolved from igneous rocks by hydrothermal process, but readily precipitated with sulfides. The reason for co-precipitation of phosphates with sulfides is not certain, but such co-precipitation mechanism

  16. Petrogenesis of the early Cretaceous volcanic rocks in the North Huaiyang tectono-magmatic unit of the Dabie Orogen, eastern China: Implications for crust-mantle interaction

    NASA Astrophysics Data System (ADS)

    Gao, Xin-Yu; Zhao, Tai-Ping; Zhao, Jun-Hong

    2016-03-01

    New elemental and isotopic data are presented for the early Cretaceous felsic to mafic volcanic rocks in the North Huaiyang tectono-magmatic unit (NHY) of the Dabie Orogen, in order to investigate their petrogenesis and provide insights into the nature of the late Mesozoic lithosphere mantle beneath the region and its tectonic relationship with neighboring blocks. LA-ICP-MS zircon U-Pb dating reveals that volcanic rocks of the Jingangtai Formation erupted in a quite short interval about 5 Mys during the Early Cretaceous (128-123 Ma). The rocks have wide ranges of SiO2 (48-68 wt.%) and MgO (0.6-5.6 wt.%) contents. They are enriched in large-ion-lithophile-elements (LILE) (e.g. Rb, Ba) and light rare-earth-elements (LREE), and depleted in high field strength elements (e.g. Nb, Ta and Ti) with weak negative Eu anomalies (Eu/Eu∗ = 0.71-0.94). Meanwhile, the rocks show relatively high whole-rock initial 87Sr/86Sr ratios (0.7074-0.7094), strong negative εNd(t) (-19.1 to -15.8) and zircon εHf values (-20.7 to -14.1). Such typical "continental" geochemical characteristics did not result from crustal contamination during magma ascent, but from an enriched mantle source modified by materials from the subducted Yangtze Craton during the Triassic continental collision. We propose that the petrogenesis of the large-scale contemporaneous magmatism of Dabie Orogen including felsic to mafic volcanic rocks in the NHY reflects an intensive lithospheric thinning and extension during the early Cretaceous as a tectonic response to the change of plate motion of westward subducted Pacific Plate beneath the Eurasian continent.

  17. Subophitic lithologies in KREEP-rich poikilitic impact melt rocks from Cayley Plains, Apollo 16 - Remnants of a volcanic Highland crust?

    NASA Astrophysics Data System (ADS)

    Reimold, W. U.; Borchardt, R.

    1984-01-01

    Attention is given to the three KREEP-rich poikilitic impact melt rocks from the Cayley Plains stations of Apollo 16 with subophitic texture areas. The bulk chemistry of these areas and the surrounding poikilitic matrices, as well as mineral compositions, were determined by electron microprobe analysis, and all subophitic areas have been identified as impact melt rock clasts. The absence of pristine volcanic target rock fragments and the existence of KREEP-rich and anorthositic impact melt clasts in KREEP-rich impact melt rocks from Cayley Plains supports the theory that the Plains formation is part of the ejecta blanket from a large, basin-type impact crater which is underlain by anorthositic material and has been reworked by local impacts in post-Imbrian times.

  18. Database for the geologic map of upper Eocene to Holocene volcanic and related rocks in the Cascade Range, Washington

    USGS Publications Warehouse

    Barron, Andrew D.; Ramsey, David W.; Smith, James G.

    2014-01-01

    This digital database contains information used to produce the geologic map published as Sheet 1 in U.S. Geological Survey Miscellaneous Investigations Series Map I-2005. (Sheet 2 of Map I-2005 shows sources of geologic data used in the compilation and is available separately). Sheet 1 of Map I-2005 shows the distribution and relations of volcanic and related rock units in the Cascade Range of Washington at a scale of 1:500,000. This digital release is produced from stable materials originally compiled at 1:250,000 scale that were used to publish Sheet 1. The database therefore contains more detailed geologic information than is portrayed on Sheet 1. This is most noticeable in the database as expanded polygons of surficial units and the presence of additional strands of concealed faults. No stable compilation materials exist for Sheet 1 at 1:500,000 scale. The main component of this digital release is a spatial database prepared using geographic information systems (GIS) applications. This release also contains links to files to view or print the map sheet, main report text, and accompanying mapping reference sheet from Map I-2005. For more information on volcanoes in the Cascade Range in Washington, Oregon, or California, please refer to the U.S. Geological Survey Volcano Hazards Program website.

  19. Chlorine isotope composition of volcanic gases and rocks at Mount Etna (Italy) and inferences on the local mantle source

    NASA Astrophysics Data System (ADS)

    Rizzo, Andrea L.; Caracausi, Antonio; Liotta, Marcello; Paonita, Antonio; Barnes, Jaime D.; Corsaro, Rosa A.; Martelli, Mauro

    2013-06-01

    We present the first chlorine isotope compositional data for gases and lavas from Mount Etna (Italy), and to our knowledge, of active Mediterranean volcanism. We investigated lavas erupted and gases discharged during 2008-2011 from a high-temperature fumarole (HT; >300 °C) and plume gases from both North East and Central Craters. Most of the samples vary in a narrow range of chlorine isotope composition (δ37Cl values≈0±0.7‰) with gases partially overlapping with rocks. Only HT gases sampled in 2009 have been clearly affected by secondary processes (δ37Cl values>15.9‰), resulting in partial removal of chlorine and isotopic fractionation producing a 37Cl enrichment in the residual gaseous HCl. These secondary processes also affect, although to a lesser extent, plume gases from North East Crater (NEC). Although post-magmatic processes are able to modify the chlorine isotope composition, δ37Cl values are not affected by magma degassing for residual fractions ≥0.3 in the melt, or any effect is within our data variability. Finally, δ37Cl values and Cl/K ratios of magmatic chlorine constrain the Etnean source to be compatible with depleted mantle (DMM) contaminated by altered oceanic crust (AOC), in agreement with indications from more common isotopic tracers of mantle processes.

  20. Quantifying effects of humans and climate on groundwater resources through modeling of volcanic-rock aquifers of Hawaii

    NASA Astrophysics Data System (ADS)

    Rotzoll, K.; Izuka, S. K.; Nishikawa, T.; Fienen, M. N.; El-Kadi, A. I.

    2015-12-01

    The volcanic-rock aquifers of Kauai, Oahu, and Maui are heavily developed, leading to concerns related to the effects of groundwater withdrawals on saltwater intrusion and streamflow. A numerical modeling analysis using the most recently available data (e.g., information on recharge, withdrawals, hydrogeologic framework, and conceptual models of groundwater flow) will substantially advance current understanding of groundwater flow and provide insight into the effects of human activity and climate change on Hawaii's water resources. Three island-wide groundwater-flow models were constructed using MODFLOW 2005 coupled with the Seawater-Intrusion Package (SWI2), which simulates the transition between saltwater and freshwater in the aquifer as a sharp interface. This approach allowed relatively fast model run times without ignoring the freshwater-saltwater system at the regional scale. Model construction (FloPy3), automated-parameter estimation (PEST), and analysis of results were streamlined using Python scripts. Model simulations included pre-development (1870) and current (average of 2001-10) scenarios for each island. Additionally, scenarios for future withdrawals and climate change were simulated for Oahu. We present our streamlined approach and preliminary results showing estimated effects of human activity on the groundwater resource by quantifying decline in water levels, reduction in stream base flow, and rise of the freshwater-saltwater interface.

  1. The behavior of biogenic silica-rich rocks and volcanic tuffs as pozzolanic additives in cement

    NASA Astrophysics Data System (ADS)

    Fragoulis, Dimitris; Stamatakis, Michael; Anastasatou, Marianthi

    2015-04-01

    Cements currently produced, include a variety of pozzolanic materials, aiming for lower clinker addition and utilization of vast deposits of certain raw materials and/or mining wastes and byproducts. The major naturally occurring pozzolanic materials include glassy tuffs, zeolitic tuffs, diatomites and volcanic lavas rich in glassy phase, such as perlites. Therefore, based on the available raw materials in different locations, the cement composition might vary according to the accessibility of efficient pozzolanic materials. In the present investigation, the behavior of pozzolanic cements produced with representative samples of the aforementioned materials was studied, following the characterization of the implemented pozzolanas with respect to their chemical and mineralogical characteristics. Laboratory cements were produced by co-grinding 75% clinker, 5% gypsum and 20% pozzolana, for the same period of time (45 min). Regarding pozzolanic materials, four different types of pozzolanas were utilized namely, diatomite, perlite, zeolite tuff and glassy tuff. More specifically, two diatomite samples originated from Australia and Greece, with high and low reactive silica content respectively, two perlite samples originated from Turkey and from Milos Island, Greece, with different reactive silica contents, a zeolite tuff sample originated from Turkey and a glassy tuff sample originated from Milos Island, Greece. The above pozzolana samples, which were ground in the laboratory ball mill for cement production performed differently during grinding and that was reflected upon the specific surface area (cm2/gr) values. The perlites and the glassy tuff were the hardest to grind, whereas, the zeolite tuff and the Australian diatomite were the easiest ones. However, the exceedingly high specific surface area of the Australian diatomite renders cement difficult to transport and tricky to use for concrete manufacturing, due to the high water demand of the cement mixture. Regarding

  2. Zircon age range and sources of alkaline rocks from the Kurgusul intrusion, Kuznetsk Alatau: The first U-Pb (SHRIMP II) and Sm-Nd isotope data

    NASA Astrophysics Data System (ADS)

    Vrublevskii, V. V.; Gertner, I. F.; Tishin, P. A.; Bayanova, T. B.

    2014-12-01

    U-Pb isotope analysis of basic feldspathoid rocks (juvites) of the Kurgusul intrusion, NE Kuznetsk Alatau, revealed three generations of zircons of various ages (˜1.3-1.5 Ga; 484.3 ± 5.5 and 393.6 ± 9.2Ma). This suggests several stages of regional alkaline basic magmatism in the Middle Cambrian-Early Ordovician and Early-Middle Devonian and melting of the Mesoproterozoic continental crust, which form part of the basement of the Kuznetsk Alatau terrane. The trace element geochemical data indicate a continental margin setting characterized by the complex interaction of a plume-related, supra-subduction zone and crustal materials. A possible model of the magmatic evolution assumes that the ascent of a plume at the Cambrian-Ordovician boundary induced generation of the initial alkaline basaltic magmas and metasomatism and erosion of the lower lithosphere. Repeated partial melting of the lower crust after a 100 Myr period produced new magma batches of alkaline composition, which inherited zircons from the preceding episode of magma generation. The inherited juvenile magmatic source (PREMA + E-type MORB + EM) is confirmed by similarities in the Sm-Nd isotopic signatures (ɛNd( T) ≈ +4.5 to +5.7, T(Nd)DM ≈ 0.8-0.9 Ga) of derivatives of regional alkaline basic complexes of different ages.

  3. Field Measurements of Penetrator Seismic Coupling in Sediments and Volcanic Rocks

    NASA Technical Reports Server (NTRS)

    Nakamura, Y.; Latham, G. V.; Frohlich, C.; Blanchard, M. B.; Murphy, J. P.

    1979-01-01

    Field experiments were conducted to determine how well a seismometer installed using a penetrator would be coupled to the ground. A dry-lake bed and a lava bed were chosen as test sites to represent geological environments of two widely different material properties. At each site, two half-scale penetrators were fired into the ground, a three-component geophone assembly was mounted to the aft end of each penetrator, and dummy penetrators were at various distances to generate seismic signals. These signals were detected by the penetrator-mounted geophone assembly and by a reference geophone assembly buried or anchored to surface rock and 1-m from the penetrator. The recorded signals were digitized, and cross-spectral analyses were performed to compare the observed signals in terms of power spectral density ratio, coherence, and phase difference. The analyses indicate that seismometers deployed by penetrators will be as well coupled to the ground as are seismometers installed by conventional methods for the frequency range of interest in earthquake seismology.

  4. Analysis of the rock mechanics properties of volcanic tuff units from Yucca Mountain, Nevada Test Site

    SciTech Connect

    Price, R. H.

    1983-08-01

    Over two hundred fifty mechanical experiments have been run on samples of tuff from Yucca Mountain, Nevada Test Site. Cores from the Topopah Spring, Calico Hills, Bullfrog and Tram tuff units were deformed to collect data for an initial evaluation of mechanical (elastic and strength) properties of the potential horizons for emplacement of commercial nuclear wastes. The experimental conditions ranged in sample saturation from room dry to fully saturated, confining pressure from 0.1 to 20 MPa, pore pressure from 0.1 to 5 MPa, temperature from 23 to 200{sup 0}C, and strain rate from 10{sup -7} to 10{sup -2} s{sup -1}. These test data have been analyzed for variations in elastic and strength properties with changes in test conditions, and to study the effects of bulk-rock characteristics on mechanical properties. In addition to the site-specific data on Yucca Mountain tuff, mechanical test results on silicic tuff from Rainier Mesa, Nevada Test Site, are also discussed. These data both overlap and augment the Yucca Mountain tuff data, allowing more definitive conclusions to be reached, as well as providing data at some test conditions not covered by the site-specific tests.

  5. Segmentation of the Cascade Arc Based on Compositional and Sr and Nd Isotopic Variations in Primitive Volcanic Rocks

    NASA Astrophysics Data System (ADS)

    Schmidt, M. E.; Grunder, A. L.

    2006-12-01

    We define four segments in the Cascade Volcanic Arc based on 87Sr/86Sr and 143Nd/144Nd of primitive volcanic rocks: 1) The North segment extends 450 km from Mt. Meager to Glacier Peak; 2) the 350-km Columbia segment includes volcanoes from Mt. Rainier to Mt. Jefferson; 3) the 250 km Central segment comprises the portion of the arc between the Three Sisters and Crater Lake; and 4) the 350-km South segment includes Mt. Shasta to Mt. Lassen. Isotopic data were compiled for primitive bulk composition (MgO concentrations >8 wt.% MgO) as a fingerprint mantle sources. The North segment has a range in 87Sr/86Sr of 0.7030-0.7037 and is distinguished by the predominance of calcalkaline basalts (CAB) and few low K tholeiites (LKT). The North segment lies on the North Cascade craton where convergence is near orthogonal. Oblique subduction occurs beneath the Columbia, Central, and South segments. The Columbia segment (87Sr/86Sr of 0.7028-0.7037) has both LKT and CABs as well as enriched ocean island-like basalts (OIB) that are found both on the arc axis and, especially at the Simcoe Volcanic Field, behind the arc. This segment lies primarily on the accreted Tertiary oceanic plateau terrane of the Columbia Embayment. The Central segment is dominated by LKT with lesser CAB and has the most restricted Sr isotopic range (0.7034- 0.7038). Like the South segment, the Central segment mainly overlies accreted terranes stitched by Mesozoic plutons and has Basin and Range (B&R) extension behind as well as locally within the arc. Medicine Lake Volcano, on the margin of the B&R behind Mt. Shasta is also dominated by LKT and has a narrow isotopic range like the Central segment. This suggests that the LKT's are related to extension in the arc. The South segment is distinguished by the widest Sr isotopic range (0.7028-0.7042) and the presence of high Mg basaltic andesite and andesite compositions in addition to LKT and CABs. These arc segments broadly correspond to physical segments that were

  6. Petrology and age of volcanic-arc rocks from the continental margin of the Bering Sea: implications for Early Eocene relocation of plate boundaries

    USGS Publications Warehouse

    Davis, A.S.; Pickthorn, L.-B.G.; Vallier, T.L.; Marlow, M. S.

    1989-01-01

    Eocene volcanic flow and dike rocks from the Beringian margin have arc characteristics, implying a convergent history for this region during the early Tertiary. Chemical and mineralogical compositions are similar to those of modern Aleutian-arc lavas. They also resemble volcanic-arc compositions from western mainland Alaska, although greater chemical diversity and a stronger continental influence are observed in the Alaskan mainland rocks. Early Eocene ages of 54.4-50.2 Ma for the Beringian samples are well constrained by conventional K-Ar ages of nine plagioclase separates and by concordant 40Ar/39Ar incremental heating and total-fusion experiments. A concordant U-Pb zircon age of 53 Ma for the quartz-diorite dike is in good agreement with the K-Ar data. Plate motion studies of the North Pacific Ocean indicate more northerly directed subduction prior to the Tertiary and a continuous belt of arc-type volcanism extending from Siberia, along the Beringian margin, into mainland Alaska. Around 56 Ma (chron 25-24), subduction changed to a more westerly direction and subduction-related volcanism ceased for most of mainland Alaska. The increasingly oblique angle of convergence should have ended subduction along the Beringian margin as well. However, consistent ages of 54-50 Ma indicate a final pulse in arc-type magmatism during this period of plate adjustment. -from Authors

  7. Stratigraphy, regional distribution, and reconnaisance geochemistry of Oligocene and Miocene volcanic rocks in the Paradise Range and northern Pactolus Hills, Nye County, Nevada

    SciTech Connect

    Not Available

    1992-01-01

    In this paper, stratigraphy, geochronology, and geochemistry of about 40 units of Oligocene and Miocene silicic ash-flow tuff, intermediate to silicic lava, and minor sedimentary rock exposed in three stratigraphic sections are described. The distribution and sources of five regionally widespread ash-flow tuff units were delineated. The late Cenozoic volcanic and tectonic history of the Paradise Range and northern Pactolus Hills was compared to other areas in the Great Basin.

  8. Zircon age and geochemistry of the Tost bimodal volcanic rocks: Constraints on the Early Carboniferous tectonic evolution of the South Mongolia

    NASA Astrophysics Data System (ADS)

    Yang, Shunhu; Miao, Laicheng; Zhang, Fochin; Meng, Qingren; Zhu, Mingshuai; Baatar, Munkhtsengel; Anaad, Chimedtseren

    2016-04-01

    SIMS zircon U-Pb dating, geochemical and Sr-Nd isotopic data are presented for the Late Paleozoic volcanic rocks from Tost area in Mongolia, the southern portion of the Central Asian Orogenic Belt (CAOB). The Tost volcanic rocks show a bimodal feature characterized by a mafic member of basalt and a felsic component of rhyolite, which are temporally and spatially related each other, implying a genetic relationship. Zircon U-Pb isotopic data of the rhyolite constrain the Tost bimodal magmatism occurring from 355 Ma to 320 Ma. The Tost basalt is characterized by high abundances in Th, U and Pb, slightly enriched LREE patterns and low HFSE/LREE ratios. These features, together with their OIB-like isotopic signature ((87Sr/86Sr)i = 0.7039378-0.704397, εNd(t) = 3.55-5.02), suggest that they were likely derived from low-degree partial melting of a metasomatized asthenospheric mantle source with subordinate input of subduction components. The Tost rhyolite, which displays an intimate affinity to Tost basalt, with enrichment in Th, U and Pb, depleted in Nb, Ta and Ti, and gently right-tilted REE patterns, is inferred to be generated by partial melting of a juvenile lower crustal source heated by underplating mafic magmas which rise from asthenosphere during continued rifting. The Tost bimodal volcanic rocks are comparable both in age and composition with those in the East Tianshan, which together constitute an E-W-oriented belt of bimodal volcanic rocks, marking an Early Carboniferous rifting event. Considering regional geology, we propose that the rifting took place in a back-arc extensional setting, probably induced by the subduction of the Dzungaria Ocean between the East Tianshan and Junggar-Kazakhstan plate during the Early Carboniferous.

  9. Spirit Discovers New Class of Igneous Rocks

    NASA Technical Reports Server (NTRS)

    2006-01-01

    During the past two-and-a-half years of traversing the central part of Gusev Crater, NASA's Mars Exploration Rover Spirit has analyzed the brushed and ground-into surfaces of multiple rocks using the alpha particle X-ray spectrometer, which measures the abundance of major chemical elements. In the process, Spirit has documented the first example of a particular kind of volcanic region on Mars known as an alkaline igneous province. The word alkaline refers to the abundance of sodium and potassium, two major rock-forming elements from the alkali metals on the left-hand side of the periodic table.

    All of the relatively unaltered rocks -- those least changed by wind, water, freezing, or other weathering agents -- examined by Spirit have been igneous, meaning that they crystallized from molten magmas. One way geologists classify igneous rocks is by looking at the amount of potassium and sodium relative to the amount of silica, the most abundant rock-forming mineral on Earth. In the case of volcanic rocks, the amount of silica present gives scientists clues to the kind of volcanism that occurred, while the amounts of potassium and sodium provide clues about the history of the rock. Rocks with more silica tend to erupt explosively. Higher contents of potassium and sodium, as seen in alkaline rocks like those at Gusev, may indicate partial melting of magma at higher pressure, that is, deeper in the Martian mantle. The abundance of potassium and sodium determines the kinds of minerals that make up igneous rocks. If igneous rocks have enough silica, potassium and sodium always bond with the silica to form certain minerals.

    The Gusev rocks define a new chemical category not previously seen on Mars, as shown in this diagram plotting alkalis versus silica, compiled by University of Tennessee geologist Harry McSween. The abbreviations 'Na2O' and 'K2O' refer to oxides of sodium and potassium. The abbreviation 'SiO2' refers to silica. The abbreviation 'wt

  10. In-situ petrophysical properties of volcanic rocks from Detroit Seamount (ODP-Leg 197, Site 1203A)

    NASA Astrophysics Data System (ADS)

    Kock, I.; Buysch, A.; Pechnig, R.

    2002-12-01

    During Leg 197 an extensive logging program was performed on Site 1203A after drilling was completed on Detroit Seamount to a total depth of 914.6 mbsf. Logging comprised measurements with the ODP/LDEO standard logging tool strings triple combo and FMS/sonic (see: http://www.ldeo.columbia.edu/BRG/ODP/). Logging data imply a classification of the drilled lithology into five groups: three types of sedimentary rocks and two types of basaltic rocks. Non-volcanic sediments, determined down to a depth of 457 mbsf, exhibit constant and low gamma ray values (<15 gAPI). A strong increase in p-wave velocity (3.12 \\pm1.15 km/s) between 388.2-393.5 mbsf correlates with the 388-mbsf reflector in seismic profiles. A gradual increase in density from 1.3 g/ccm to 1.8 g/ccm, and a decrease in porosity from 92.7 % to 69 % with depth record expected consolidation and compaction effects. FMS pictures and standard logging tool data mark the sediment - basement boundary at 464.5 mbsf. A transition zone between 464.5-468.5 mbsf reveals high porosity/low density, high gamma-ray/low resistivity data, which is probably caused by alteration. The basement is characterised by an interlayered succession of volcanoclastic rocks and basaltic lava flows. Lava flows of type B-I are marked by a bimodal data distribution of resistivity (68.80 +/-2.41 ohmm) and porosity (21.71 +/-8.27 %) with maximum values for resistivity at 32 ohmm and 100 ohmm, and for porosity at 11 % and 19.5 %. Usually, basaltic lava exhibits low gamma-ray values as observed for rocks of the B-I flow type (18.75 +/-7.32 gAPI). Instead, lava flows of type B-II show higher gamma-ray data of 28 gAPI (\\pm5.92). This flow type occurs in the lower basement part between 761-920 mbsf and could be target of an increased alteration. It reveals higher porosity (36.56 +/-10.03 %), caused by a high vesicularity, and lower density (2.33 +/-0.18 g/ccm) values than the B-I flows (density = 2.60 \\pm0.16 g/ccm). Resistivity and porosity data

  11. Using high-resolution aeromagnetic data to recognise and map intra-sedimentary volcanic rocks and geological structures across the Cretaceous middle Benue Trough, Nigeria

    NASA Astrophysics Data System (ADS)

    Anudu, Goodluck K.; Stephenson, Randell A.; Macdonald, David I. M.

    2014-11-01

    Recently acquired high-resolution aeromagnetic data over the Cretaceous middle Benue Trough of Nigeria have been analysed employing various edge-enhancement (magnetic derivative) methods: vertical derivatives, total horizontal derivative, analytic signal, and total horizontal derivative of tilt derivative. The study was aimed at mapping intra-sedimentary volcanic rocks and their areal extents/distribution as well as delineating geological structures, their structural trends and tectonic implications. The magnetic derivative anomaly maps produced in this project greatly enhanced the high amplitude, short-wavelength (high wavenumber) anomalies associated with the surface/near-surface intra-sedimentary volcanic rocks and associated geological structures. The maps show that volcanic rocks of Late Cretaceous to Palaeocene age are much more widespread than implied by surface geological mapping, with an areal extent of greater than 12,000 km2 in the relatively shallow subsurface. The results also highlight some known and several previously unknown geological lineaments. Rose (azimuth-frequency) plots of orientations of geological structures show trends being predominantly NE-SW, NW-SE and ESE-WNW with minor ENE-WSW and N-S trends. These main groups of structural trends are associated with the Brasiliano/Pan-African orogeny (600 ± 200 Ma) and likely predate rifting of the Gondwana supercontinent. They may have been enhanced during continental break-up in Late Jurassic to Early Cretaceous.

  12. An insight to the eruption mechanism of volcanic rocks in North Tibet: Project TITAN

    NASA Astrophysics Data System (ADS)

    He, R.; Gao, R.; Li, Q.

    2013-12-01

    Since Cenozoic continent-continental collision between India and Asia [Yin and Harrison, 2000], many surface features happened within the plateau were prominent. As one of them, high-to-ultra potassic lavas of Neogene, even younger, are widely distributed in NW Tibet, as shown in Figure1. Obvious petrological and geochemical characteristics of those lavas [Turner et al., 1993; Deng et al., 1996; Hacker et al., 2000; Ding et al., 2003; Williams et al., 2004; Chung et al., 2005; Luo et al., 2006; Guo et al., 2006] were presumably associated with extensional collapse of the lithospheric mantle [Deng et al., 1998; Li et al., 2000; Ding et al., 2003; Williams et al., 2004; Chung et al., 2005; Luo et al., 2006; Guo et al., 2006], which started at about 4Ma [Yin et al., 1999] and still goes on [Lin et al., 2002]. (1) What kinetics happened within the lithosphere beneath the lava region since Late Neogene? (2) What kind of mechanism leads to the lava eruption, it is only the result of far-long effect of northward subduction of the India plate, or directly related to the south margin of the Asian lithosphere, or bilaterally affected by India and Asia plate, or other factors? (3) Why did the strong volcanic activities only wrecked the North Qiangtang terrane, Jinshajiang suture and Hoh Xil terrane, instead of going northward across Altyn Tagh Fault and East Kunlun? As is known, to reveal the scientific secret concealed in lavas within NW Tibet geophysical observations are very necessary and urgent. NW Tibet including North Qiangtang and Hoh Xil is a very tough region for human beings. The project for geophysical observatory in the region is named as TITAN. TITAN has currently made some great progress, such as 103 broadband Seismic observation stations were deployed along longitude 88.5E in recent 5 years, as shown in Figure 1. Some primary results were got, such as (1) P-velocity structure from teleseismic tomography around Shuanghu in central Qiangtang (Figure 2) showed

  13. The quality of our Nation's waters: groundwater quality in the Columbia Plateau and Snake River Plain basin-fill and basaltic-rock aquifers and the Hawaiian volcanic-rock aquifers, Washington, Idaho, and Hawaii, 1993-2005

    USGS Publications Warehouse

    Rupert, Michael G.; Hunt, Charles D., Jr.; Skinner, Kenneth D.; Frans, Lonna M.; Mahler, Barbara J.

    2015-01-01

    The Columbia Plateau, Snake River Plain, and Hawaii are large volcanic areas in the western United States and mid-Pacific ocean that contain extensive regional aquifers of a hard, gray, volcanic rock called basalt. Residents of the Columbia Plateau, the Snake River Plain, and the island of Oahu depend on groundwater as their primary source of drinking water. Although the depth to the water table can be several hundred feet, the groundwater is highly vulnerable to contamination because the permeable sediments and rocks allow contaminants to move readily down to the water table. Intense agricultural and urban activities occur above the drinking-water supply and are increasing in some areas. Contaminants, such as nitrate, pesticides, and volatile organic compounds, associated with agricultural and urban activities, have adversely affected groundwater quality.

  14. Tectonic and magmatic evolution of the northwestern Basin and Range and its transition to unextended volcanic plateaus: Black Rock Range, Nevada

    USGS Publications Warehouse

    Lerch, D.W.; Miller, E.; McWilliams, M.; Colgan, J.

    2008-01-01

    The seismically active eastern and western margins of the northern Basin and Range have been extensively studied, yet the northwestern margin of the province remains incompletely understood. The Black Rock Range of northwestern Nevada straddles the transition from the Basin and Range province to the south and east, and flat-lying volcanic plateaus to the west. This poorly understood range preserves a remarkably complete record of Cenozoic magmatism and provides an important window into the pre-Miocene history of the unextended volcanic plateaus of northeastern California and southern Oregon. Geologic mapping and 40Ar/39Ar geochronology from the northern Black Rock Range document three significant episodes of Eocene to middle Miocene volcanism. Eocene (35 Ma) basalts directly overlie Mesozoic granites and arc-related volcanic and sedimentary rocks. Locally erupted Oligocene to early Miocene (27-21 Ma) bimodal volcanic rocks comprise the bulk of the Cenozoic section and conformably overlie the Eocene basalt flows. These bimodal units include rhyolitic lavas, variably welded rhyolitic ash flows, unwelded ash-fall deposits, and thin basalt flows. In the neighboring Pine Forest Range ???20 km to the north, similar Oligocene to early Miocene units are overlain by more than 500 m of ca. 16.4 Ma Steens-equivalent basalt flows and are capped by ca. 16 Ma rhyolitic ash-flow tuffs. In the northern Black Rock Range, the ca. 16.4 Ma middle Miocene basalts are absent from the section, and a 16.2 Ma rhyolitic ash-flow tuff directly overlies the early Miocene flows. Basaltic and rhyolitic volcanic products in the northern Black Rock Range span 35-16 Ma, with many of the Oligocene volcanic units derived from local vents and dikes. Despite the map-scale complexities of locally derived lava flows, the Cenozoic section is broadly conformable and dips gently (???5??-10??) to the northwest. The region experienced no significant tilting between 35 and 16 Ma, with moderate tilting (???5

  15. Rocks.

    ERIC Educational Resources Information Center

    Lee, Alice

    This science unit is designed for limited- and non-English speaking students in a Chinese bilingual education program. The unit covers rock material, classification, characteristics of types of rocks, and rock cycles. It is written in Chinese and simple English. At the end of the unit there is a list of main terms in both English and Chinese, and…

  16. Paleomagnetism and rock magnetism of Quaternary volcanic rocks and Late Paleozoic strata, VC-1 core hole, Valles Caldera, New Mexico, with emphasis on remagnetization of Late Paleozoic strata

    NASA Astrophysics Data System (ADS)

    Geissman, John W.

    1988-06-01

    Paleomagnetic and rock magnetic data obtained from azimuthally unoriented core samples, collected at approximately 1- to 3-m intervals, of Continental Scientific Drilling Program core hole VC-1 have prompted reinterpretations of the Quaternary volcanic stratigraphy intersected by the bore and have aided in evaluating the thermal regime within late Paleozoic strata attending fluid circulation and mineral deposition during and after development of the Toledo and Valles calderas. The results from Quaternary units (Banco Bonito Obsidian: I = +35.4°, a95 = 2.8° (inclination only determinations), n = 33; Battleship Rock Tuff: D = 359.6°, I = +42.4°, a95 = 2.8°, n = 5 site means (surface sites); VC-1 Rhyolite: I = +39.2°, a95 = 12.8°, n = 7; Upper VC-1 Tuff: I = +37.2°, a95 = 10.7°, n = 13; Middle VC-1 Tuff: I = +42.1°, a95 = 2.1°, n = 39; South Mountain Rhyolite: D = 350.9°, I = +49.9°, a95 = 3.4°, n = 10 (one surface site)) are consistent with isotopic age data, indicating that the entire moat volcanic sequence intersected is less than 650 kyr. Monitoring of natural remanent magnetization (NRM) intensity, NRM directions, directions of magnetizations isolated during progressive demagnetization, median destructive forces, and rock magnetization parameters has identified systematic variations within the thick Banco Bonito Obsidian and VC-1 Tuff units. The Permian Abo Formation, Pennsylvanian to earliest Permian Madera Limestone, and Pennsylvanian Sandia Formation typically contain a moderate positive inclination magnetization component (Abo Formation: I = +52.2°, a95 = 7.4°, n = 16; Madera Limestone: I = +58.4°, a95 = 2.8°, n = 105; Sandia Formation: I = +53.9°, a95 = 4.8°, n = 21); when residing in magnetite, it is usually unblocked in the laboratory by 350°C; when carried by hematite it is unblocked by 550°C. A moderate negative inclination (e.g., Madera and Abo strata: D = 173.1°, I = -46.6°, a95 = 5.5°; n = 47 samples; assuming a north seeking

  17. Matrix diffusion coefficients in volcanic rocks at the Nevada test site: influence of matrix porosity, matrix permeability, and fracture coating minerals.

    PubMed

    Reimus, Paul W; Callahan, Timothy J; Ware, S Doug; Haga, Marc J; Counce, Dale A

    2007-08-15

    Diffusion cell experiments were conducted to measure nonsorbing solute matrix diffusion coefficients in forty-seven different volcanic rock matrix samples from eight different locations (with multiple depth intervals represented at several locations) at the Nevada Test Site. The solutes used in the experiments included bromide, iodide, pentafluorobenzoate (PFBA), and tritiated water ((3)HHO). The porosity and saturated permeability of most of the diffusion cell samples were measured to evaluate the correlation of these two variables with tracer matrix diffusion coefficients divided by the free-water diffusion coefficient (D(m)/D*). To investigate the influence of fracture coating minerals on matrix diffusion, ten of the diffusion cells represented paired samples from the same depth interval in which one sample contained a fracture surface with mineral coatings and the other sample consisted of only pure matrix. The log of (D(m)/D*) was found to be positively correlated with both the matrix porosity and the log of matrix permeability. A multiple linear regression analysis indicated that both parameters contributed significantly to the regression at the 95% confidence level. However, the log of the matrix diffusion coefficient was more highly-correlated with the log of matrix permeability than with matrix porosity, which suggests that matrix diffusion coefficients, like matrix permeabilities, have a greater dependence on the interconnectedness of matrix porosity than on the matrix porosity itself. The regression equation for the volcanic rocks was found to provide satisfactory predictions of log(D(m)/D*) for other types of rocks with similar ranges of matrix porosity and permeability as the volcanic rocks, but it did a poorer job predicting log(D(m)/D*) for rocks with lower porosities and/or permeabilities. The presence of mineral coatings on fracture walls did not appear to have a significant effect on matrix diffusion in the ten paired diffusion cell experiments

  18. Matrix diffusion coefficients in volcanic rocks at the Nevada test site: Influence of matrix porosity, matrix permeability, and fracture coating minerals

    NASA Astrophysics Data System (ADS)

    Reimus, Paul W.; Callahan, Timothy J.; Ware, S. Doug; Haga, Marc J.; Counce, Dale A.

    2007-08-01

    Diffusion cell experiments were conducted to measure nonsorbing solute matrix diffusion coefficients in forty-seven different volcanic rock matrix samples from eight different locations (with multiple depth intervals represented at several locations) at the Nevada Test Site. The solutes used in the experiments included bromide, iodide, pentafluorobenzoate (PFBA), and tritiated water ( 3HHO). The porosity and saturated permeability of most of the diffusion cell samples were measured to evaluate the correlation of these two variables with tracer matrix diffusion coefficients divided by the free-water diffusion coefficient ( Dm/ D*). To investigate the influence of fracture coating minerals on matrix diffusion, ten of the diffusion cells represented paired samples from the same depth interval in which one sample contained a fracture surface with mineral coatings and the other sample consisted of only pure matrix. The log of ( Dm/ D*) was found to be positively correlated with both the matrix porosity and the log of matrix permeability. A multiple linear regression analysis indicated that both parameters contributed significantly to the regression at the 95% confidence level. However, the log of the matrix diffusion coefficient was more highly-correlated with the log of matrix permeability than with matrix porosity, which suggests that matrix diffusion coefficients, like matrix permeabilities, have a greater dependence on the interconnectedness of matrix porosity than on the matrix porosity itself. The regression equation for the volcanic rocks was found to provide satisfactory predictions of log( Dm/ D*) for other types of rocks with similar ranges of matrix porosity and permeability as the volcanic rocks, but it did a poorer job predicting log( Dm/ D*) for rocks with lower porosities and/or permeabilities. The presence of mineral coatings on fracture walls did not appear to have a significant effect on matrix diffusion in the ten paired diffusion cell experiments.

  19. Géochimie et cadre géodynamique du volcanisme néoprotérozoïque terminal (vendien) du Haut Atlas occidental, Maroc(Geochemical features and tectonic setting of late Neoproterozoic Vendian volcanism in the western High Atlas, Morocco)

    NASA Astrophysics Data System (ADS)

    Jouhari, A.; El-Archi, A.; Aarab, M.; El-Attari, A.; Ennih, N.; Laduron, D.

    2001-05-01

    Late Neoproterozoic Vendian volcanic and volcaniclastic rocks are widely distributed in the western High Atlas. They are located north of the Tizi n'Test Fault, separating the West African Craton from a northerly adjacent craton. These volcanic rocks overlie a semipelitic formation, which represents the equivalent of the Tidilline and Anzi Formations of the Anti-Atlas. The geochemical characteristics of these volcanic rocks suggest a calc-alkaline active margine environment associated with the post Pan-African tectonics. They differ from those of the Anti-Atlas by their lower content of K 2O. The later rock type was generated by a melting process of the crust subducted beneath the northern craton. A carbonate-shale unit, which contains examples of interstratified calc-alkaline dacite, overlies the volcanic succession, demonstrating that the volcanic activity continued sporadically until Early Cambrian times.

  20. Numerical modelling of gas-water-rock interactions in volcanic-hydrothermal environment: the Ischia Island (Southern Italy) case study.

    NASA Astrophysics Data System (ADS)

    Di Napoli, R.; Federico, C.; Aiuppa, A.; D'Antonio, M.; Valenza, M.

    2012-04-01

    Hydrothermal systems hosted within active volcanic systems represent an excellent opportunity to investigate the interactions between aquifer rocks, infiltrating waters and deep-rising magmatic fluids, and thus allow deriving information on the activity state of dormant volcanoes. From a thermodynamic perspective, gas-water-rock interaction processes are normally far from equilibrium, but can be represented by an array of chemical reactions, in which irreversible mass transfer occurs from host rock minerals to leaching solutions, and then to secondary hydrothermal minerals. While initially developed to investigate interactions in near-surface groundwater environments, the reaction path modeling approach of Helgeson and co-workers can also be applied to quantitative investigation of reactions in high T-P environments. Ischia volcano, being the site of diffuse hydrothermal circulation, is an ideal place where to test the application of reaction-path modeling. Since its last eruption in 1302 AD, Ischia has shown a variety of hydrothermal features, including fumarolic emissions, diffuse soil degassing and hot waters discharges. These are the superficial manifestation of an intense hydrothermal circulation at depth. A recent work has shown the existence of several superposed aquifers; the shallowest (near to boiling) feeds the numerous surface thermal discharges, and is recharged by both superficial waters and deeper and hotter (150-260°C) hydrothermal reservoir fluids. Here, we use reaction path modelling (performed by using the code EQ3/6) to quantitatively constrain the compositional evolution of Ischia thermal fluids during their hydrothermal flow. Simulations suggest that compositions of Ischia groundwaters are buffered by interactions between reservoir rocks and recharge waters (meteoric fluids variably mixed - from 2 to 80% - with seawater) at shallow aquifer conditions. A CO2 rich gaseous phase is also involved in the interaction processes (fCO2 = 0.4-0.6 bar

  1. A First Look at Airborne Imaging Spectrometer (AIS) Data in an Area of Altered Volcanic Rocks and Carbonate Formations, Hot Creek Range, South Central Nevada

    NASA Technical Reports Server (NTRS)

    Feldman, S. C.; Taranik, J. V.; Mouat, D. A.

    1985-01-01

    Three flight lines of Airborne Imaging Spectrometer (AIS) data were collected in 128 bands between 1.2 and 2.4 microns in the Hot Creek Range, Nevada on July 25, 1984. The flight lines are underlain by hydrothermally altered and unaltered Paleozoic carbonates and Tertiary rhyolitic to latitic volcanics in the Tybo mining district. The original project objectives were to discriminate carbonate rocks from other rock types, to distinguish limestone from dolomite, and to discriminate carbonate units from each other using AIS imagery. Because of high cloud cover over the prime carbonate flight line and because of the acquisition of another flight line in altered and unaltered volcanics, the study has been extended to the discrimination of alteration products. In an area of altered and unaltered rhyolites and latites in Red Rock Canyon, altered and unaltered rock could be discriminated from each other using spectral features in the 1.16 to 2.34 micron range. The altered spectral signatures resembled montmorillonite and kaolinite. Field samples were gathered and the presence of montmorillonite was confirmed by X-ray analysis.

  2. Final closure of the Paleo-Asian Ocean along the Solonker Suture Zone: Constraints from geochronological and geochemical data of Permian volcanic and sedimentary rocks

    NASA Astrophysics Data System (ADS)

    Eizenhöfer, Paul R.; Zhao, Guochun; Zhang, Jian; Sun, Min

    2014-04-01

    There is a broad consensus that the Solonker Suture Zone marks the final closure of the Paleo-Asian Ocean, which led to the formation of the eastern segment of the Central Asian Orogenic Belt. However, when and how the final closure occurred still remains controversial. To address this issue, provenance analysis of Permian sedimentary rocks of arc basins along the Xar Moron River was carried out. Geochemical analysis revealed a close relationship between the sedimentary and volcanic rock suite in the study region suggesting short transport distances and a complex convergent arc setting. Detrital zircon U-Pb analysis identified two major age provenances: (1) the Precambrian basement of the North China Craton (~2497 Ma and ~1844 Ma) and (2) the Paleozoic Southern Accretionary Orogen along the northern margin of North China (~436 Ma and ~269 Ma). The present locations of identified age provenances indicate southward subduction beneath the northern margin of North China. A comparison of the youngest age population in the sedimentary rocks with U-Pb ages obtained for subduction-related volcanic rocks implies that the Solonker Suture Zone formed from the Late Permian to Early Triassic. The results of our study advocate a complex Permian arc system which was probably similar to present-day Southeast Asia.

  3. Volcanology, geochemistry and age of the Lausitz Volcanic Field

    NASA Astrophysics Data System (ADS)

    Büchner, J.; Tietz, O.; Viereck, L.; Suhr, P.; Abratis, M.

    2015-11-01

    The Lausitz (Lusatia) Volcanic Field is part of the Central European Volcanic Province, and its magmas represent an alkaline trend from olivine nephelinites and basanites to trachytes and phonolites, typical for intraplate settings. Neighbouring volcanic fields are the České Středohoří Mountains to the south-west and the Fore-Sudetic Basin in Lower Silesia to the east. More than 1000 volcanic structures associated with approximately 500 vents have been located within this volcanic field. Residuals of scoria cones, lava lakes, lava flows and maar-diatreme in filling occur in situ near the level of the original syn-volcanic terrain. In more deeply eroded structures, volcanic relicts outcrop as plugs or feeders. Evolved rocks occur as monogenetic domes or intrusions in diatremes, while their volcaniclastic equivalents are rare. Twenty-three localities were dated using the 40Ar/39Ar method. The ages range from 35 to 27 Ma, with a focus around 32-29 Ma, indicating Late Eocene and mainly Oligocene volcanism for the LVF. Differentiated rocks appear to be slightly younger than less differentiated. No geographical age clusters are apparent.

  4. The Quaternary volcanic rocks of the northern Afar Depression (northern Ethiopia): Perspectives on petrology, geochemistry, and tectonics

    NASA Astrophysics Data System (ADS)

    Hagos, Miruts; Koeberl, Christian; van Wyk de Vries, Benjamin

    2016-05-01

    The northern Afar Depression is one of the most volcano-tectonically active parts of the East African Rift system, a place where oceanic rifting may be beginning to form an incipient oceanic crust. In its center, over an area that is ∼80 km long and ∼50 km wide, there are seven major NNW-SSE-aligned shield volcanoes/volcanic edifices surrounded by compositionally distinct fissure-fed basalts. The Quaternary lavas in this area range from transitional to tholeiitic basalts, with significant across-axis variation both in mineralogy and chemistry. The variation in the contents of the major elements (TiO2, Al2O3, and Fe2O3), incompatible trace elements (Nd, Hf, Th, Ta), and the contents and ratios of the rare earth elements (REE) (e.g., (La/Yb)n = 5.3-8.9) indicate some variation in the petrogenetic processes responsible for the formation of these basalts. However, the variation in isotopic compositions of the mafic lavas is minimal (87Sr/86Sr = 0.7036-0.7041, 143Nd/144Nd = 0.51286-0.51289), which suggests only one source for all the Danakil Depression basalts. These basalts have isotope and incompatible trace element ratios that overlap with those of the Oligocene High-Ti2 flood basalts from the Ethiopian Plateau, interpreted as being derived from the last phase/tail of the Afar mantle plume source. Moreover, the Ce/Pb, Ba/U ratios indicate that the involvement of continental crust in the petrogenesis of the basaltic rocks is minimal; instead, both depth and degree of melting of the source reservoir underneath the northern Afar Depression played a major role for the production of incompatible element-enriched basalts (e.g., AleBagu Shield basalts) and the incompatible element-depleted tholeiitic basalts (e.g., Erta'Ale and Alu Shield basalts).

  5. Origin of the ca. 90 Ma magnesia-rich volcanic rocks in SE Nyima, central Tibet: Products of lithospheric delamination beneath the Lhasa-Qiangtang collision zone

    NASA Astrophysics Data System (ADS)

    Wang, Qing; Zhu, Di-Cheng; Zhao, Zhi-Dan; Liu, Sheng-Ao; Chung, Sun-Lin; Li, Shi-Min; Liu, Dong; Dai, Jin-Gen; Wang, Li-Quan; Mo, Xuan-Xue

    2014-06-01

    Bulk-rock major and trace element, Sr-Nd-Hf isotope, zircon U-Pb age, and zircon Hf isotopic data of the Late Cretaceous Zhuogapu volcanic rocks in the northern Lhasa subterrane provide a new insight into tectonic processes following the collision of the terrane with the Qiangtang zone. SHRIMP zircon U-Pb dating reveals that the Zhuogapu volcanic rocks crystallized at ca. 91 Ma, postdating the development of a regional angular unconformity between the Upper Cretaceous and the underlying strata in the Lhasa-Qiangtang collision zone. Compared to the Andean arc-type andesites and dacites, the Zhuogapu volcanic rocks are characterized by higher MgO of 2.78-5.86 wt.% and Mg# of 54-64 for andesites and MgO of 2.30-2.61 wt.% and Mg# of 55-58 for dacites. Eight andesite samples have whole-rock (87Sr/86Sr)i of 0.7054-0.7065, εNd(t) of - 3.2 to - 1.7, and εHf(t) of + 3.8-+ 6.4, similar to those of the three dacite samples with (87Sr/86Sr)i = 0.7056-0.7060, εNd(t) of - 2.7 to - 2.2, and εHf(t) of + 5.6-+ 7.0. Thirteen analyses from a dacite sample give positive zircon εHf(t) of + 5.6 to + 8.7. These signatures indicate that the Zhuogapu Mg-rich andesites were most likely derived from partial melting of a delaminated mafic lower crust (including the lowermost crust straddling the northern and central Lhasa subterranes) that led to the generation of the Zhuogapu primary melts with adakitic signatures and small negative εNd(t). Such melts subsequently experienced interaction of melt-asthenospheric mantle peridotite followed by the modification of highly fractionated magmas in shallow crustal magma chamber. Hornblende-controlled fractionation results in the change of geochemical composition from Mg-rich andesitic to Mg-rich dacitic magmas. Field observations, together with geochronological and geochemical data, indicate that the Zhuogapu Mg-rich volcanic rocks and coeval magmatism in the northern Lhasa subterrane may be the result of thickened lithospheric delamination

  6. Zircon U-Pb geochronology and geochemistry of low-grade metamorphosed volcanic rocks from the Dantazi Complex: Implications for the evolution of the North China Craton

    NASA Astrophysics Data System (ADS)

    Ge, Songsheng; Zhai, Mingguo; Li, Tiesheng; Peng, Peng; Santosh, M.; Shan, Houxiang; Zuo, Pengfei

    2015-11-01

    The late Neoarchean witnessed the cratonization of the North China Craton (NCC) through amalgamation of several micro-blocks to form a coherent basement. The Archean orthogneisses and supracrustal rocks in this craton have experienced various grades of metamorphism ranging up to upper amphibolite and granulite facies at ∼2500 Ma. Recently, a suite of low-grade metamorphosed (greenschist to lower amphibolite facies) volcanic rocks was discovered in the late Neoarchean Dantazi Complex in northern Hebei province. These meta-volcanic rocks consist of bimodal basalt-andesite and trachyte-dacite with a SiO2 gap between 54.4 wt.% and 60.7 wt.%. Here we report SHRIMP zircon U-Pb ages of 2490 ± 19 Ma (MSWD = 2.0) and 2502 ± 8 Ma (MSWD = 0.83) from the meta-mafic and meta-felsic volcanics, respectively, representing the timing of igneous activity. All the meta-mafic volcanic rocks display coherent trace element and REE patterns which are characterized by enriched LILE and LREE but depleted HFSE and HREE ((La/Yb)N = 6.29-15.10). Combining these trace element features with the positive zircon εHf(t) values (+1.3 to +6.6), we propose that the mafic rocks were likely derived from partial melting of a previously metasomatized lithospheric mantle. In the primitive mantle-normalized diagram, the felsic rocks display uniform patterns enriched in LILE but depleted in Nb and Ta, similar to those of lower crust. Furthermore, their strongly fractionated REE ((La/Yb)N = 15.24-61.20), lower HREE concentrations (Yb = 0.47-1.65 ppm) and positive zircon εHf(t) values (+1.6 to +5.3) suggest that they were derived from partial melting of the lower crust with garnet in the residue. This coeval occurrence of metasomatized mantle-derived mafic magmas and potassic felsic magmas from different source regions reflects an intracontinental extensional setting during the late Neoarchean to earliest Paleoproterozoic following the cratonization of the NCC. Our new data, combined with previous

  7. The anatomy of a cinder cone: preliminary paleomagnetic, rock magnetic, structural, and petrologic data from the La Cienega volcano, Cerros del Rio volcanic field, northern New Mexico

    NASA Astrophysics Data System (ADS)

    Petronis, M. S.; Foucher, M.; Lineline, J.; Van Wyk de Vries, B.

    2011-12-01

    The Cerros del Rio volcanic field is one of several middle Pliocene to Pleistocene basaltic volcanic fields of the axial Rio Grande Rift in central and northern New Mexico. It is a monogenetic volcanic field that comprises about 60 cinder-spatter cones, occupies ~ 700 km2, and ranges in age from 2.7 Ma to 1.1 Ma. Eruptive centers are typically central vent volcanoes, ranging from low-relief shields to steep-sided, breached cinder and spatter cone remnants. They represent short eruptive events that likely were derived from rapidly evolving reservoir-conduit systems. Mining activity has exposed the volcanic plumbing system of the Cienega Mine cinder cone, just west of Santa Fe, NM. Here, geologists from France and USA have been investigating the exposed roots of this eviscerated Pliocene volcano to investigate magma conduit geometry, magma flow structures, and eruption patterns. We are testing models for magma transport and volcano construction using a variety of field and laboratory tools. Common models of volcanic construction envision the magma feeder as a dike or pipe-like conduit transporting molten rock from a deep reservoir to the eruptive vent. We posit that small volcanic pluming systems are inherently more complex and actually involve numerous feeder geometries throughout the volcano lifespan. Our preliminary work suggests that the simple exteriors of some cinder cones hide a long life and complex history, both of which would change the appreciation of the related volcanic hazards in active systems. The Cienega Mine cinder cone consists of several meter- to decimeter-wide intrusions that connect to eruptive centers. These intrusions show a continuity of brittle to ductile structures from their margins to interiors. We have collected samples across each intrusion as well as along strike for anisotropy of magnetic susceptibility (AMS) and petrographic analysis in order to establish magma flow patterns. AMS results yield a remarkably consistent dataset that

  8. The Early Mesozoic volcanic arc of western North America in northeastern Mexico

    NASA Astrophysics Data System (ADS)

    Barboza-Gudiño, José Rafael; Orozco-Esquivel, María Teresa; Gómez-Anguiano, Martín; Zavala-Monsiváis, Aurora

    2008-02-01

    Volcanic successions underlying clastic and carbonate marine rocks of the Oxfordian-Kimmeridgian Zuloaga Group in northeastern Mexico have been attributed to magmatic arcs of Permo-Triassic and Early Jurassic ages. This work provides stratigraphic, petrographic geochronological, and geochemical data to characterize pre-Oxfordian volcanic rocks outcropping in seven localities in northeastern Mexico. Field observations show that the volcanic units overlie Paleozoic metamorphic rocks (Granjeno schist) or Triassic marine strata (Zacatecas Formation) and intrude Triassic redbeds or are partly interbedded with Lower Jurassic redbeds (Huizachal Group). The volcanic rocks include rhyolitic and rhyodacitic domes and dikes, basaltic to andesitic lava flows and breccias, and andesitic to rhyolitic pyroclastic rocks, including breccias, lapilli, and ashflow tuffs that range from welded to unwelded. Lower-Middle Jurassic ages (U/Pb in zircon) have been reported from only two studied localities (Huizachal Valley, Sierra de Catorce), and other reported ages (Ar/Ar and K-Ar in whole-rock or feldspar) are often reset. This work reports a new U/Pb age in zircon that confirms a Lower Jurassic (193 Ma) age for volcanic rocks exposed in the Aramberri area. The major and trace element contents of samples from the seven localities are typical of calc-alkaline, subduction-related rocks. The new geochronological and geochemical data, coupled with the lithological features and stratigraphic positions, indicate volcanic rocks are part of a continental arc, similar to that represented by the Lower-Middle Jurassic Nazas Formation of Durango and northern Zacatecas. On that basis, the studied volcanic sequences are assigned to the Early Jurassic volcanic arc of western North America.

  9. Geochemistry of the late Holocene rocks from the Tolbachik volcanic field, Kamchatka: Quantitative modelling of subduction-related open magmatic systems

    NASA Astrophysics Data System (ADS)

    Portnyagin, Maxim; Duggen, Svend; Hauff, Folkmar; Mironov, Nikita; Bindeman, Ilya; Thirlwall, Matthew; Hoernle, Kaj

    2015-12-01

    We present new major and trace element, high-precision Sr-Nd-Pb (double spike), and O-isotope data for the whole range of rocks from the Holocene Tolbachik volcanic field in the Central Kamchatka Depression (CKD). The Tolbachik rocks range from high-Mg basalts to low-Mg basaltic trachyandesites. The rocks considered in this paper represent mostly Late Holocene eruptions (using tephrochronological dating), including historic ones in 1941, 1975-1976 and 2012-2013. Major compositional features of the Tolbachik volcanic rocks include the prolonged predominance of one erupted magma type, close association of middle-K primitive and high-K evolved rocks, large variations in incompatible element abundances and ratios but narrow range in isotopic composition. We quantify the conditions of the Tolbachik magma origin and evolution and revise previously proposed models. We conclude that all Tolbachik rocks are genetically related by crystal fractionation of medium-K primary magmas with only a small range in trace element and isotope composition. The primary Tolbachik magmas contain ~ 14 wt.% of MgO and ~ 4% wt.% of H2O and originated by partial melting (~ 6%) of moderately depleted mantle peridotite with Indian-MORB-type isotopic composition at temperature of ~ 1250 °C and pressure of ~ 2 GPa. The melting of the mantle wedge was triggered by slab-derived hydrous melts formed at ~ 2.8 GPa and ~ 725 °C from a mixture of sediments and MORB- and Meiji-type altered oceanic crust. The primary magmas experienced a complex open-system evolution termed Recharge-Evacuation-Fractional Crystallization (REFC). First the original primary magmas underwent open-system crystal fractionation combined with periodic recharge of the magma chamber with more primitive magma, followed by mixing of both magma types, further fractionation and finally eruption. Evolved high-K basalts, which predominate in the Tolbachik field, and basaltic trachyandesites erupted in 2012-2013 approach steady-state REFC

  10. Fracture permeability and water-rock interaction in a shallow volcanic groundwater reservoir and the concern of its interaction with the deep geothermal reservoir of Mt. Amiata, Italy

    NASA Astrophysics Data System (ADS)

    La Felice, S.; Montanari, D.; Battaglia, S.; Bertini, G.; Gianelli, G.

    2014-09-01

    The study of core samples and in-hole data of a 545 m deep well drilled in Mt. Amiata extinct volcano allowed a better characterization of the shallow volcanic reservoir, which is exploited for domestic utilization. The new discovery is that: 1) the water table level is at a depth of 302 m b.g.l. (783 m a.s.l.), in agreement with recent magnetotelluric surveys, and in disagreement with previous hydrogeological models; 2) there is no evidence of present or past interaction with geothermal fluids, the alteration minerals being present only in fractures within the volcanic rocks and indicating fluids of low temperature and relatively low pH due to gas inlets in the volcanic reservoir; and 3) the volcanic reservoir is characterized by fracture permeability, as shown by the fracture system along the well. On the base of these new data the previous geological and hydrogeological models of Mt. Amiata should be revised. In particular, the hypothesis of a catastrophic lowering of the water table in a short time span is unlikely.

  11. Melting of the primitive martian mantle at 0.5-2.2 GPa and the origin of basalts and alkaline rocks on Mars

    NASA Astrophysics Data System (ADS)

    Collinet, Max; Médard, Etienne; Charlier, Bernard; Vander Auwera, Jacqueline; Grove, Timothy L.

    2015-10-01

    We have performed piston-cylinder experiments on a primitive martian mantle composition between 0.5 and 2.2 GPa and 1160 to 1550 °C. The composition of melts and residual minerals constrain the possible melting processes on Mars at 50 to 200 km depth under nominally anhydrous conditions. Silicate melts produced by low degrees of melting (<10 wt.%) were analyzed in layers of vitreous carbon spheres or in micro-cracks inside the graphite capsule. The total range of melt fractions investigated extends from 5 to 50 wt.%, and the liquids produced display variable SiO2 (43.7-59.0 wt.%), MgO (5.3-18.6 wt.%) and Na2O + K2O (1.0-6.5 wt.%) contents. We provide a new equation to estimate the solidus temperature of the martian mantle: T (°C) = 1033 + 168.1 P (GPa) - 14.22P2 (GPa), which places the solidus 50 °C below that of fertile terrestrial peridotites. Low- and high-degree melts are compared to martian alkaline rocks and basalts, respectively. We suggest that the parental melt of Adirondack-class basalts was produced by ∼25 wt.% melting of the primitive martian mantle at 1.5 GPa (∼135 km) and ∼1400 °C. Despite its brecciated nature, NWA 7034/7533 might be composed of material that initially crystallized from a primary melt produced by ∼10-30 wt.% melting at the same pressure. Other igneous rocks from Mars require mantle reservoirs with different CaO/Al2O3 and FeO/MgO ratios or the action of fractional crystallization. Alkaline rocks can be derived from mantle sources with alkali contents (∼0.5 wt.%) similar to the primitive mantle.

  12. Paleomagnetic and rock-magnetic study on volcanic units of the Valsequillo Basin: implications for early human occupation in central Mexico

    NASA Astrophysics Data System (ADS)

    Goguitchaichvili, Avto; Pozzo, Ana Lillian Martin-Del; Rocha-Fernandez, Jose Luis; Urrutia-Fucugauchi, Jaime; Soler-Arechalde, Ana Maria

    2009-01-01

    Alleged human and animal footprints were found within the upper bedding surfaces of the Xalnene volcanic ash layer that outcrops in the Valsequillo Basin, south of Puebla, Mexico (Gonzalez et al, 2005). The ash has been dated at 40 ka by optically stimulated luminescence analysis, thereby providing new evidence that America was colonized earlier than the Clovis culture (about 13.5 Ma). We carried out paleomagnetic and rock magnetic analysis on 18 Xalnene ash block and core samples collected at two distinct localities and 19 standard paleomagnetic cores belonging to nearby monogenetic volcanoes. Our data provide evidence that both the volcanic lava flow and Xalnene ash were emplaced during the Laschamp geomagnetic event spanning from about 45 to 39 ka.

  13. Cenozoic intra-plate magmatism in the Darfur volcanic province: mantle source, phonolite-trachyte genesis and relation to other volcanic provinces in NE Africa

    NASA Astrophysics Data System (ADS)

    Lucassen, Friedrich; Pudlo, Dieter; Franz, Gerhard; Romer, Rolf L.; Dulski, Peter

    2013-01-01

    Chemical and Sr, Nd and Pb isotopic compositions of Late Cenozoic to Quaternary small-volume phonolite, trachyte and related mafic rocks from the Darfur volcanic province/NW-Sudan have been investigated. Isotope signatures indicate variable but minor crustal contributions. Some phonolitic and trachytic rocks show the same isotopic composition as their primitive mantle-derived parents, and no crustal contributions are visible in the trace element patterns of these samples. The magmatic evolution of the evolved rocks is dominated by crystal fractionation. The Si-undersaturated strongly alkaline phonolite and the Si-saturated mildly alkaline trachyte can be modelled by fractionation of basanite and basalt, respectively. The suite of basanite-basalt-phonolite-trachyte with characteristic isotope signatures from the Darfur volcanic province fits the compositional features of other Cenozoic intra-plate magmatism scattered in North and Central Africa (e.g., Tibesti, Maghreb, Cameroon line), which evolved on a lithosphere that was reworked or formed during the Neoproterozoic.

  14. Geomagnetic imprint of the Persani volcanism

    NASA Astrophysics Data System (ADS)

    Besutiu, Lucian; Seghedi, Ioan; Zlagnean, Luminita; Atanasiu, Ligia; Popa, Razvan-Gabriel; Pomeran, Mihai; Visan, Madalina

    2016-04-01

    The Persani small volume volcanism is located in the SE corner of the Transylvanian Depression, at the north-western edge of the intra-mountainous Brasov basin. It represents the south-easternmost segment of the Neogene-Quaternary volcanic chain of the East Carpathians. The alkaline basalt monogenetic volcanic field is partly coeval with the high-K calc-alkaline magmatism south of Harghita Mountains (1-1.6 Ma). Its eruptions post-dated the calc-alkaline volcanism in the Harghita Mountains (5.3-1.6 Ma), but pre-dated the high-K calc-alkaline emissions of Ciomadul volcano (1.0-0.03 Ma). The major volcanic forms have been mapped in previous geological surveys. Still, due to the small size of the volcanoes and large extent of tephra deposits and recent sediments, the location of some vents or other volcanic structures has been incompletely revealed. To overcome this problem, the area was subject to several near-surface geophysical investigations, including paleomagnetic research. However, due to their large-scale features, the previous geophysical surveys proved to be an inappropriate approach to the volcanological issues. Therefore, during the summers of 2014 and 2015, based on the high magnetic contrast between the volcanic rocks and the hosting sedimentary formations, a detailed ground geomagnetic survey has been designed and conducted, within central Persani volcanism area, in order to outline the presence of volcanic structures hidden beneath the overlying deposits. Additionally, information on the rock magnetic properties was also targeted by sampling and analysing several outcrops in the area. Based on the acquired data, a detailed total intensity scalar geomagnetic anomaly map was constructed by using the recent IGRF12 model. The revealed pattern of the geomagnetic field proved to be fully consistent with the direction of magnetisation previously determined on rock samples. In order to enhance the signal/noise ratio, the results were further processed by

  15. Petrogenesis of coexisting SiO 2-undersaturated to SiO 2-oversaturated felsic igneous rocks: The alkaline complex of Itatiaia, southeastern Brazil

    NASA Astrophysics Data System (ADS)

    Brotzu, P.; Gomes, C. B.; Melluso, L.; Morbidelli, L.; Morra, V.; Ruberti, E.

    1997-07-01

    The Itatiaia alkaline complex is a Late Cretaceous intrusion (72 Myr) made up of felsic differentiates, with syenitic rocks dominant throughout and with presence of both nepheline- and quartz-rich varieties. Dykes with phonolitic or trachytic composition cross-cut the coarse-grained facies. The rocks are arranged concentrically, with the core of the complex being formed by SiO 2-oversaturated syenites (with a small outcrop of granites), and are radially displaced by faults related to regional tectonic lineaments. The minerals show gradual but significant changes in composition (salitic and augitic to aegirine-rich pyroxenes, hastingsite and actinolite to richterite and arfvedsonite amphiboles, sodic plagioclase to orthoclase feldspars and so on) and the whole-rock trends are broadly consistent with fractional crystallization processes dominated by alkali feldspar removal. Sr-isotopic data indicate more radiogenic ratios for the SiO 2-oversaturated rocks (0.7062-0.7067 against 0.7048-0.7054 for the SiO 2-undersaturated syenites), consistent with small amounts of crustal input. The favored hypothesis for the petrogenesis of the different syenitic groups is the prolonged differentiation starting from differently SiO 2-undersaturated mafic parental magmas (potassic alkali basalts to ankaratrites, present in the Late Cretaceous dyke swarms of the area), accompanied by variable crustal contamination prior to the final emplacement. The lack of carbonatite as a significant lithotype, the potassic affinity of the Itatiaia complex, and the relatively high Sr-isotopic ratios match the characteristics of the other complexes of the Rio de Janeiro-Sa˜o Paulo states coastline and confirm the ultimate derivation of these differentiated rocks from an enriched lithospheric mantle source.

  16. The Quaternary volcanic rocks of the northern Afar Depression (northern Ethiopia): Perspectives on petrology, geochemistry, and tectonics

    NASA Astrophysics Data System (ADS)

    Hagos, Miruts; Koeberl, Christian; van Wyk de Vries, Benjamin

    2016-05-01

    The northern Afar Depression is one of the most volcano-tectonically active parts of the East African Rift system, a place where oceanic rifting may be beginning to form an incipient oceanic crust. In its center, over an area that is ∼80 km long and ∼50 km wide, there are seven major NNW-SSE-aligned shield volcanoes/volcanic edifices surrounded by compositionally distinct fissure-fed basalts. The Quaternary lavas in this area range from transitional to tholeiitic basalts, with significant across-axis variation both in mineralogy and chemistry. The variation in the contents of the major elements (TiO2, Al2O3, and Fe2O3), incompatible trace elements (Nd, Hf, Th, Ta), and the contents and ratios of the rare earth elements (REE) (e.g., (La/Yb)n = 5.3-8.9) indicate some variation in the petrogenetic processes responsible for the formation of these basalts. However, the variation in isotopic compositions of the mafic lavas is minimal (87Sr/86Sr = 0.7036-0.7041, 143Nd/144Nd = 0.51286-0.51289), which suggests only one source for all the Danakil Depression basalts. These basalts have isotope and incompatible trace element ratios that overlap with those of the Oligocene High-Ti2 flood basalts from the Ethiopian Plateau, interpreted as being derived from the last phase/tail of the Afar mantle plume source. Moreover, the Ce/Pb, Ba/U ratios indicate that the involvement of continental crust in the petrogenesis of the basaltic rocks is minimal; instead, both depth and degree of melting of the source reservoir underneath the northern Afar Depression played a major role for the production of incompatible element-enriched basalts (e.g., AleBagu Shield basalts) and the incompatible element-depleted tholeiitic basalts (e.g., Erta'Ale and Alu Shield basalts).

  17. Tectonics and volcanism of Sierra Chichinautzin: extension at the front of the Central Trans-Mexican Volcanic belt

    NASA Astrophysics Data System (ADS)

    Márquez, Alvaro; Verma, Surendra P.; Anguita, Francisco; Oyarzun, Roberto; Brandle, José L.

    1999-11-01

    Because of its recent activity and position at the southern magmatic front of the Trans-Mexican Volcanic Belt (TMVB), the Sierra Chichinautzin volcanic field (SCN) is a key area for the understanding of this controversial volcanic province. Volcanic activity has built more than 220 monogenetic volcanoes (shields, scoria cones, thick lava flows, and hydromagmatic structures) during the last 40,000 years, for a total volume of about 470 km 3. The SCN basalts are geochemically similar to OIBs, while the intermediate and felsic volcanic rocks show a calc-alkaline trend and abundant evidence for magma mixing. The structural analysis of this volcanic field and surrounding areas has been based on field data, satellite images, and a method for detecting volcanic center alignments. The tectonic data, together with geophysical evidence, confirm active general N-S extensional conditions with a strike-slip component for the SCN area, the same structural setting that prevails in the rest of the Central TMVB. Extensional tectonics, a negative regional Bouger gravity anomaly, a low-velocity mantle, high heat flow, and shallow seismicity suggest a rift-type setting involving the upwelling of anomalous mantle beneath the Central TMVB. The combined petrological, structural and geophysical arguments support that the SCN volcanism is rift-related, and rule out processes involving the subduction of the Cocos plate, which casts further doubts on the standard subduction model for the TMVB volcanism.

  18. Petrogenetic connections between volcanic rocks and intrusive suites in the California arc - toward an integrated model for upper-crustal magma system evolution

    NASA Astrophysics Data System (ADS)

    Barth, A. P.; Riggs, N.; Walker, J. D.; Andrew, J.; Jacobson, C. E.; Miller, D. M.; Robert, J.

    2014-12-01

    Volcanic and clastic sedimentary rocks in deeply eroded, predominantly plutonic arcs provide records of arc development and the links between volcanic and plutonic processes. We are analyzing existing and new geochronologic and petrologic data from volcanic breccias, ignimbrites and intrusive suites in the Sierra Nevada and Mojave Desert sectors of the Mesozoic California arc, in an effort to construct an integrated volcano-plutonic model for silicic magmatism in arc upper crust. SIMS and TIMS U-Pb zircon ages, immobile element abundances in whole rocks, and trace element abundances in zircons allow us to interpret the magmatic heritage of ignimbrites and components of underlying granodioritic to granitic intrusive suites. Preliminary results suggest several conclusions: (1) first-order magma production was episodic, with plutonic, forearc and retro-arc detrital zircons defining three magmatic pulses of ~40-60 m.y. duration that are largely mimicked by the more limited record of zircons in ignimbrites; (2) in the Triassic and Jurassic, second-order pulses on 2-10 m.y. time scales are recorded in both the intrusive and ignimbrite records, suggesting that eruption of ignimbrites was synchronous at the shortest resolvable time scales with assembly of underlying incrementally emplaced intrusive suites; (3) ignimbrites range from dacite to rhyolite in bulk composition, and are petrographically similar to modern "monotonous intermediate" dacite or phenocryst-poor low-silica rhyolite; (4) these tuffs are as fractionated as intrusive rocks, and commonly, though not always, contain zircons with similarly complex, multi-stage growth histories. Thus ignimbrites and felsic granodiorites in this arc are complementary elements recording lengthy and episodic evolutionary histories in cool and hydrous upper-crustal arc magma systems.

  19. Dikes, sills, and stress-regime evolution during emplacement of the Jagged Rocks Complex, Hopi Buttes Volcanic Field, Navajo Nation, USA

    NASA Astrophysics Data System (ADS)

    Re, Giuseppe; White, J. D. L.; Ort, M. H.

    2015-03-01

    The dikes and related intrusions formed below small volcanoes in volcanic fields are remnants of the simplest volcanic plumbing systems. Their geometry is controlled by interaction of magma-driven cracks with country rock, and reveals regional structural and stress patterns at the time of their emplacement. The shallow stress field, however, may change during the time an intrusion complex is emplaced, in response to addition or removal of magma and country rock during associated surface eruptions. The Jagged Rocks Complex, in the Miocene Hopi Buttes Volcanic Field, Navajo Nation, Arizona, is exposed 300-350 m below the pre-eruptive surface. It comprises a group of generally NW-SE striking dikes, punctuated in places by buds, a saucer-like intrusion, larger pyroclastic massifs and a diatreme. We made measurements of 13 dikes, divided into 172 segments, with thicknesses from 8 to 122 cm (mean 43 cm) and lengths of 60 to 780 m. Several sills and inclined sheets in places are thicker than dikes, having mean thicknesses of 48 cm and 73 cm respectively. Dikes typically show straight, parallel, and en echelon patterns, while sills and inclined sheets are curved. The northwestern dikes differ from the rest in containing large mafic crystals, and are inferred to have been emplaced after the others. We find that the strike of the overall complex (dikes and other sheets, elongate massifs and aligned sub-cylindrical bodies) reflects a crystalline-basement control that is evident throughout Hopi Buttes. Over the period of the complex's emplacement, local stress patterns were not stable. We infer that excavation of deep maar craters, and perhaps the construction of a scoria cone at the surface, modified the local stress patterns to favor emplacement of sills and en echelon dikes later in the complex's evolution, in contrast to simple straight dikes as the complex first formed.

  20. Paleomagnetic secular variation study of Ar-Ar dated lavas flows from Tacambaro area (Central Mexico): Possible evidence of Intra-Jaramillo geomagnetic excursion in volcanic rocks

    NASA Astrophysics Data System (ADS)

    Peña, Rafael Maciel; Goguitchaichvili, Avto; Guilbaud, Marie-Noëlle; Martínez, Vicente Carlos Ruiz; Rathert, Manuel Calvo; Siebe, Claus; Reyes, Bertha Aguilar; Morales, Juan

    2014-04-01

    More than 350 oriented paleomagnetic cores were obtained for rock-magnetic and paleomagnetic analysis from radiometrically dated (40Ar-39Ar) magmatic rocks occurring in the southern segment (Jorullo and Tacámbaro areas) of the Michoacán-Guanajuato Volcanic Field in the Trans-Mexican Volcanic Belt. Most of the lavas (37) stem from monogenetic volcanoes dated at less than 4 Ma. Two additional sites were sampled from the plutonic basement dated at 33-30 Ma. Primary remanences carried by low-Ti titanomagnetites allowed to determining 34 reliable site-mean directions of mostly normal (27) but also reversed (7) polarities. The mean directions of these two populations are antipodal, and suggest neither major vertical-axis rotations with respect to the North America craton nor tilting in the region for the last 4 Ma (rotation and flattening of the inclination parameters being less than -5.9 ± 3.8 and 0.1 ± 3.9, respectively). The corresponding paleomagnetic pole obtained for Pliocene-Pleistocene times is PLAT = 83.4°, PLON = 2.4° (N = 32, A95 = 2.7°). Virtual geomagnetic poles also contribute to the time averaged field global database and to the paleosecular variation (PSV) investigations at low latitudes from lavas for the last 5 Ma, showing a geomagnetic dispersion value that is in agreement with available PSV models. When comparing the magnetic polarities and corresponding radiometric ages of the studied sites with the Cenozoic geomagnetic polarity time scale (GPTS), a good correlation is observable. This finding underscores the suitability of data obtained on lavas in Central Mexico for contributing to the GPTS. Furthermore, the detection of short-lived geomagnetic features seems possible, since the possible evidence of Intra-Jaramillo geomagnetic excursion could be documented for the first time in these volcanic rocks.

  1. Temporal Variation and Bifurcating Differentiation Trends from Olivine Tholeiite Among Mafic Volcanic Rocks in the Bimodal High Lava Plains, Oregon

    NASA Astrophysics Data System (ADS)

    Grunder, A.; Streck, M. J.

    2011-12-01

    The High Lava Plains are part of a large basaltic footprint that has dominated Neogene volcanism in the Pacific Northwest. Regional basalts, aka the HAOT, are distinctive for high alumina (> 16 wt%) and low K and low incompatible trace-element concentrations (K a few tenths % and Rb a few ppm). The HAOT are associated with high silica rhyolite tuffs and domes, making a strongly bimodal suite; we here focus on the diversity within the mafic compositions of the suite in the central High Lava Plains. The mafic suite ranges from about 8.5 to < 1 Ma and includes: 1) HAOT, that are compositionally and isotopically in keeping with regional trends; 2) calcalkaline basalts to basaltic andesites; and 3) a distinct set of Fe-rich basalts to trachyandesites. The latter crops out around the inferred source region of the ~300 cubic km (DRE) Rattlesnake Tuff. Primitive members of the HAOT suite last equilibrated with the depleted subcontinental asthenosphere near the Moho at about 35 km depth, based on comparison to phase equilibria and on seismic work (Eagar et al, 2010). From these primitive beginnings, the HAOT have a distinct differentiation trend from ~10 to 7.5 wt% MgO with an increase in FeO* from about 9 to12 wt% and a 10 to 20 fold enrichment in incompatible trace elements with a twofold decrease in Ni. Strong enrichments in La/Yb (1-4.5) preclude the variation being controlled mostly by variable melting, even of a garnet bearing source. An increasing tilt in rare earth element patterns with decreasing MgO is best modeled by minor assimilation of a rhyolite. At 7-8 wt% MgO, the HAOT trend bifurcates to give rise to Fe-poor (FeO* 10 to 6) basalts to basaltic andesites that have a larger amount of crustal contamination as indicated by somewhat elevated incompatible elements (La 10-30; La/Yb 4-12) coupled with crystal fractionation; These are the only basalts to have radiogenic isotope ratios slightly displaced toward crustal values. The ferrobasaltic to trachytic mafic

  2. Quaternary volcanics from the Broken Top volcano area, Oregon High Cascades: Varied low pressure processes in calc-alkaline magma chambers

    SciTech Connect

    Webster, J.R. . Div. of Science and Math)

    1992-01-01

    Broken Top (BT) is a Quaternary composite volcano in the central Oregon High Cascades. Volcanics in the vicinity of BT range from basalt to rhyodacite with a paucity of andesite. Most pre- and syn-BT lavas were generated through low pressure crystal fractionation (CF) in small, short-lived chambers. Mixing superimposed on CF generally involved magmas with minimal compositional differences. Lavas erupted from BT are dominantly phenocryst-rich bas. andesite which exhibits evidence for a mixing origin. Whole-rock and phenocryst compositions suggest mixing between basalt and andesite. The andesite can be explained by low pressure CF of the basalt. Latest BT activity consisted of bas. andesite, dacite, and rhyodacite lavas which were generated through CF. During BT activity, andesite was produced by CF during rapid sidewall crystallization and ponded at the top of the chamber. Mixing most likely took place during eruptive events, but evidence for a persistent presence of mixed (hybrid) magma in the chamber suggests incomplete evacuation of mixed magma. With time, the andesite layer became less significant due to decreasing rates of sidewall crystallization and/or frequent eruption/replenishment, more widespread crystal settling resulted in eruption of CF-generated bas. andesite and low-Si dacite. Rapid crystallization of dacitic magma followed by buoyant segregation yielded rhyodacite. These processes operating during the latest stages of the BT activity were likely similar to those operating in the short-lived chambers. Paucity of CF-generated andesite is explained by: (1) low density crust which retards andesite ascent, and (2) rapid crystallization over the dacite range. While significant amounts of andesite were produced in the longer-lived BT system, it rarely erupted unmixed.

  3. Diagenetic Iron Cycling in Ancient Alkaline Saline Lacustrine Sedimentary Rocks: A Case Study on the Jurassic Brushy Basin Member of the Morrison Formation, Colorado Plateau, USA

    NASA Astrophysics Data System (ADS)

    Potter-McIntyre, S. L.; Chan, M. A.; McPherson, B. J. O. L.

    2014-12-01

    The upper part of the Brushy Basin Member in the Four Corners region of the U.S. was deposited in an ephemeral alkaline saline lake system with copious input of volcanic ash. The variegated shale formation provides a setting for the study of early diagenetic iron cycling that records the action of alkaline saline fluid chemistries reacting with volcaniclastic sediments in the presence of microbes. A bull's-eye pattern of authigenic minerals with increasing alteration towards the basinal center similar to modern alkaline saline lakes provides evidence for an extreme paleoenvironmental interpretation. The purpose of this research is to document specific factors, such as reactive sediments, microbial influences, and grain size that affect concretion formation and iron cycling in an ancient extreme environment. Three broad diagenetic facies are interpreted by color and associated bioturbation features: red, green and intermediate. Diagenetic facies reflect meter-scale paleotopography: red facies represent shallow water to subaerial, oxidizing conditions; green facies reflect saturated conditions and reducing pore water chemistry shortly after deposition, and intermediate facies represent a combination of the previous two conditions. Evidence of biotic influence is abundant and trace fossils exhibit patterns associated with the diagenetic facies. Red diagenetic facies typically contain burrows and root traces and green diagenetic facies exhibit restricted biotic diversity typically limited to algal molds (vugs). Microbial fossils are well-preserved and are in close proximity to specific iron mineral textures suggesting biotic influence on the crystal morphology. Three categories of concretions are characterized based on mineralogy: carbonate, iron (oxyhydr)oxide and phosphate concretions. Concretion mineralogy and size vary within an outcrop and even within a stratigraphic horizon such that more than one main category is typically present in an outcrop. Variation in

  4. Anomalous Seismic Velocity Drop in Iron and Biotite Rich Amphibolite to Granulite Facies Transitional Rocks from Deccan Volcanic Covered 1993 Killari Earthquake Region, Maharashtra (India): a Case Study

    NASA Astrophysics Data System (ADS)

    Pandey, O. P.; Tripathi, Priyanka; Vedanti, Nimisha; Srinivasa Sarma, D.

    2016-03-01

    65 Ma Deccan Volcanic Province of western India forms one of the largest flood basaltic eruptions on the surface of the earth. The nature of the concealed crust below this earthquake prone region, which is marked by several low velocity zones at different depths has hardly been understood. These low velocity zones have been invariably interpreted as fluid-filled zones, genetically connected to earthquake nucleation. While carrying out detailed geological and petrophysical studies on the Late Archean basement cores, obtained from a 617 m deep KLR-1 borehole, drilled in the epicentral zone of 1993 Killari earthquake region of the southern Deccan Volcanic Province, we came across several instances where we observed remarkable drop in measured P-wave velocity in a number of high density cores. We provide detailed petrographic and geological data on 11 such anomalous samples which belong to mid-crustal amphibolite to granulite facies transitional rocks. They are associated with a mean P-wave velocity of 6.02 km/s (range 5.82-6.22 km/s) conforming to granitic upper crust, but in contrast have a high mean density of 2.91 g/cm3 (range 2.75-3.08 g/cm3), which characterise mid to lower crust. This velocity drop, which is as much as 15 % in some cores, is primarily attributed to FeOT enrichment (up to about 23 wt%) during the course of mantle-fluid driven retrogressive metasomatic reactions, caused by exhumation of deep-seated mafic rocks. Presence of Iron content (mainly magnetite), widely seen as opaques in thin sections of the rocks, seems to have resulted into sharp increase in density, as well as mean atomic weight. Our study indicates that the measured V p is inversely related to FeOT content as well as mean atomic weight of the rock.

  5. Assessing hydraulic connections across a complex sequence of volcanic rocks-Analysis of U-20 WW multiple-well aquifer test, Pahute Mesa, Nevada National Security Site, Nevada

    USGS Publications Warehouse

    Garcia, C. Amanda; Fenelon, Joseph M.; Halford, Keith J.; Reiner, Steven R.; Laczniak, Randell J.

    2011-01-01

    Groundwater beneath Pahute Mesa flows through a complexly layered sequence of volcanic rock aquifers and confining units that have been faulted into distinct structural blocks. Hydraulic property estimates of rocks and structures in this flow system are necessary to assess radionuclide migration near underground nuclear testing areas. The U.S. Geological Survey (USGS) used a 12 month (October 1, 2008-October 1, 2009) intermittent pumping schedule of well U-20 WW and continuously monitored water levels in observation wells ER-20-6 #3, UE-20bh 1, and U-20bg as a multi-well aquifer test to evaluate hydraulic connections across structural blocks, bulk hydraulic properties of volcanic rocks, and the hydraulic significance of a major fault. Measured water levels were approximated using synthetic water levels generated from an analytical model. Synthetic water levels are a summation of environmental water-level fluctuations and a Theis (1935) transform of the pumping signal from flow rate to water-level change. Drawdown was estimated by summing residual differences between measured and synthetic water levels and the Theis-transformed pumping signal from April to September 2009. Drawdown estimates were used in a three-dimensional numerical model to estimate hydraulic properties of distinct aquifers, confining units, and a major fault. A maximum water-level drawdown of nearly 0.4 foot in well UE-20bh 1, which is more than 1 mile from the pumping well, was detected across a major fault. Drawdown estimates in the observation well nearest to (ER-20-6 #3, less than 1 mile) and within the same structural block as the pumping well were less than detection (-6 per foot, respectively, and transmissivity estimates range from 1,200 to 3,600 feet squared per day. Sensitivity analyses indicate that the major fault is hydraulically similar to the permeable host rock and connects flow between structural blocks.

  6. Permeability and continuous gradient temperature monitoring of volcanic rocks: new insights from borehole and laboratory analysis at the Campi Flegrei caldera (Southern Italy).

    NASA Astrophysics Data System (ADS)

    Carlino, Stefano; Piochi, Monica; Tramelli, Anna; Troise, Claudia; Mormone, Angela; Montanaro, Cristian; Scheu, Bettina; Klaus, Mayer; Somma, Renato; De Natale, Giuseppe

    2016-04-01

    The pilot borehole recently drilled in the eastern caldera of Campi Flegrei (Southern Italy), during the Campi Flegrei Deep Drill Project (CFDDP) (in the framework of the International Continental Scientific Drilling Program) allowed (i) estimating on-field permeability and coring the crustal rocks for laboratory experiments, and (ii) determining thermal gradient measurements down to ca. 500 m of depth. We report here a first comparative in situ and laboratory tests to evaluate the rock permeability in the very high volcanic risk caldera of Campi Flegrei, in which ground deformations likely occur as the persistent disturbance effect of fluid circulation in the shallower geothermal system. A large amount of petro-physical information derives from outcropping welded tuffs, cores and geophysical logs from previous AGIP's drillings, which are located in the central and western part of the caldera. We discuss the expected scale dependency of rock permeability results in relation with well-stratigraphy and core lithology, texture and mineralogy. The new acquired data improve the database related to physical property of Campi Flegrei rocks, allowing a better constrain for the various fluid-dynamical models performed in the tentative to understand (and forecast) the caldera behavior. We also present the first data on thermal gradient continuously measured through 0 - to 475 m of depth by a fiber optic sensor installed in the CFDDP pilot hole. As regards, we show that the obtained values of permeability, compared with those inferred from eastern sector of the caldera, can explain the different distribution of temperature at depth, as well as the variable amount of vapor phase in the shallow geothermal system. The measured temperatures are consistent with the distribution of volcanism in the last 15 ka.

  7. Can a primary remanence be retrieved from partially remagnetized Eocence volcanic rocks in the Nanmulin Basin (southern Tibet) to date the India-Asia collision?

    NASA Astrophysics Data System (ADS)

    Huang, Wentao; Dupont-Nivet, Guillaume; Lippert, Peter C.; Hinsbergen, Douwe J. J.; Dekkers, Mark J.; Guo, Zhaojie; Waldrip, Ross; Li, Xiaochun; Zhang, Xiaoran; Liu, Dongdong; Kapp, Paul

    2015-01-01

    Paleomagnetic dating of the India-Asia collision hinges on determining the Paleogene latitude of the Lhasa terrane (southern Tibet). Reported latitudes range from 5°N to 30°N, however, leading to contrasting paleogeographic interpretations. Here we report new data from the Eocene Linzizong volcanic rocks in the Nanmulin Basin, which previously yielded data suggesting a low paleolatitude (~10°N). New zircon U-Pb dates indicate an age of ~52 Ma. Negative fold tests, however, demonstrate that the isolated characteristic remanent magnetizations, with notably varying inclinations, are not primary. Rock magnetic analyses, end-member modeling of isothermal remanent magnetization acquisition curves, and petrographic observations are consistent with variable degrees of posttilting remagnetization due to low-temperature alteration of primary magmatic titanomagnetite and the formation of secondary pigmentary hematite that unblock simultaneously. Previously reported paleomagnetic data from the Nanmulin Basin implying low paleolatitude should thus not be used to estimate the time and latitude of the India-Asia collision. We show that the paleomagnetic inclinations vary linearly with the contribution of secondary hematite to saturation isothermal remanent magnetization. We tentatively propose a new method to recover a primary remanence with inclination of 38.1° (35.7°, 40.5°) (95% significance) and a secondary remanence with inclination of 42.9° (41.5°,44.4°) (95% significance). The paleolatitude defined by the modeled primary remanence—21°N (19.8°N, 23.1°N)—is consistent with the regional compilation of published results from pristine volcanic rocks and sedimentary rocks of the upper Linzizong Group corrected for inclination shallowing. The start of the Tibetan Himalaya-Asia collision was situated at ~20°N and took place by ~50 Ma.

  8. Anomalous Seismic Velocity Drop in Iron and Biotite Rich Amphibolite to Granulite Facies Transitional Rocks from Deccan Volcanic Covered 1993 Killari Earthquake Region, Maharashtra (India): a Case Study

    NASA Astrophysics Data System (ADS)

    Pandey, O. P.; Tripathi, Priyanka; Vedanti, Nimisha; Srinivasa Sarma, D.

    2016-07-01

    65 Ma Deccan Volcanic Province of western India forms one of the largest flood basaltic eruptions on the surface of the earth. The nature of the concealed crust below this earthquake prone region, which is marked by several low velocity zones at different depths has hardly been understood. These low velocity zones have been invariably interpreted as fluid-filled zones, genetically connected to earthquake nucleation. While carrying out detailed geological and petrophysical studies on the Late Archean basement cores, obtained from a 617 m deep KLR-1 borehole, drilled in the epicentral zone of 1993 Killari earthquake region of the southern Deccan Volcanic Province, we came across several instances where we observed remarkable drop in measured P-wave velocity in a number of high density cores. We provide detailed petrographic and geological data on 11 such anomalous samples which belong to mid-crustal amphibolite to granulite facies transitional rocks. They are associated with a mean P-wave velocity of 6.02 km/s (range 5.82-6.22 km/s) conforming to granitic upper crust, but in contrast have a high mean density of 2.91 g/cm3 (range 2.75-3.08 g/cm3), which characterise mid to lower crust. This velocity drop, which is as much as 15 % in some cores, is primarily attributed to FeOT enrichment (up to about 23 wt%) during the course of mantle-fluid driven retrogressive metasomatic reactions, caused by exhumation of deep-seated mafic rocks. Presence of Iron content (mainly magnetite), widely seen as opaques in thin sections of the rocks, seems to have resulted into sharp increase in density, as well as mean atomic weight. Our study indicates that the measured V p is inversely related to FeOT content as well as mean atomic weight of the rock.

  9. Petrogenesis of the Early Permian volcanic rocks in the Chinese South Tianshan: Implications for crustal growth in the Central Asian Orogenic Belt

    NASA Astrophysics Data System (ADS)

    Huang, He; Zhang, Zhaochong; Santosh, M.; Zhang, Dongyang; Wang, Tao

    2015-07-01

    The Paleozoic and Early Mesozoic magmatic suites in the Central Asian Orogenic Belt (CAOB) provide important insights on the crustal growth and reworking process associated with the construction of the largest Phanerozoic orogen on the Earth. Among the tectonic blocks of the CAOB, the South Tianshan Terrane (STT) occupies the southwestern margin and is located adjacent to the Tarim Craton. Here we investigate the Early Permian Xiaotikanlike Formation in the central part of the Chinese STT in Xinjiang in Northwest China. The formation is composed of a series of terrestrial volcanic lava flows and volcanic breccia, interbedded with siltstones, sandstones and sandy conglomerates. Zircon U-Pb and Lu-Hf isotopic analysis, whole-rock major oxide, trace element and Sr-Nd isotopic data are presented for the volcanic lava flows of the Xiaotikanlike Formation exposed in the Boziguo'er, Laohutai and Wensu regions. The new zircon ages from our study, together with those reported in previous investigations on the rhyolitic lava flow from the Wensu region, suggest that the volcanic rocks of the Xiaotikanlike Formation simultaneously erupted at ca. 285 Ma. The lavas of the formation show a wide range of SiO2 (49.88 to 78.56 wt.%). The basaltic rocks show SiO2 from 49.88 to 53.78 wt.%, MgO from 3.73 to 7.01 wt.% and Mg# from 41 to 61. They possess slightly enriched Sr-Nd isotope signature [(87Sr/86Sr)t = 0.70495-0.70624 and εNd(t) = - 0.5 to + 0.6], and have trace and rare earth element patterns similar to those of oceanic island basalts (OIBs). Petrographic and whole-rock chemical characteristics indicate that the basaltic lava flows are dominantly tholeiitic, and were likely derived from a spinel-dominated peridotite asthenospheric mantle source. The felsic lavas of the Xiaotikanlike Formation show SiO2 in the range of 60.71 to 78.56 wt.% and display overall similar immobile element pattern characterized by notable troughs at Nb-Ta, P and Ti and gently sloping REEs. Zircon Lu

  10. Distribution of chemical elements in calc-alkaline igneous rocks, soils, sediments and tailings deposits in northern central Chile

    NASA Astrophysics Data System (ADS)

    Oyarzún, Jorge; Oyarzun, Roberto; Lillo, Javier; Higueras, Pablo; Maturana, Hugo; Oyarzún, Ricardo

    2016-08-01

    This study follows the paths of 32 chemical elements in the arid to semi-arid realm of the western Andes, between 27° and 33° S, a region hosting important ore deposits and mining operations. The study encompasses igneous rocks, soils, river and stream sediments, and tailings deposits. The chemical elements have been grouped according to the Goldschmidt classification, and their concentrations in each compartment are confronted with their expected contents for different rock types based on geochemical affinities and the geologic and metallogenic setting. Also, the element behavior during rock weathering and fluvial transport is here interpreted in terms of the ionic potentials and solubility products. The results highlight the similarity between the chemical composition of the andesites and that of the average Continental Crust, except for the higher V and Mn contents of the former, and their depletion in Mg, Ni, and Cr. The geochemical behavior of the elements in the different compartments (rocks, soils, sediments and tailings) is highly consistent with the mobility expected from their ionic potentials, their sulfates and carbonates solubility products, and their affinities for Fe and Mn hydroxides. From an environmental perspective, the low solubility of Cu, Zn, and Pb due to climatic, chemical, and mineralogical factors reduces the pollution risks related to their high to extremely high contents in source materials (e.g., rocks, altered zones, tailings). Besides, the complex oxyanions of arsenic get bound by colloidal particles of Fe-hydroxides and oxyhydroxides (e.g., goethite), thus becoming incorporated to the fine sediment fraction in the stream sediments.

  11. Crystal preferred orientations of minerals from mantle xenoliths in alkali basaltic rocks form the Catalan Volcanic Zone (NE Spain)

    NASA Astrophysics Data System (ADS)

    Fernández-Roig, Mercè; Galán, Gumer; Mariani, Elisabetta

    2015-04-01

    Mantle xenoliths in alkali basaltic rocks from the Catalan Volcanic Zone, associated with the Neogene-Quaternary rift system in NE Spain, are formed of anhydrous spinel lherzolites and harzburgites with minor olivine websterites. Both peridotites are considered residues of variable degrees of partial melting, later affected by metasomatism, especially the harzburgites. These and the websterites display protogranular microstructures, whereas lherzolites show continuous variation between protogranular, porphyroclastic and equigranular forms. Thermometric data of new xenoliths indicate that protogranular harzburgites, lherzolites and websterites were equilibrated at higher temperatures than porphyroclastic and equigranular lherzolites. Mineral chemistry also indicates lower equilibrium pressure for porphyroclastic and equigranular lherzolites than for the protogranular ones. Crystal preferred orientations (CPOs) of olivine and pyroxenes from these new xenoliths were determined with the EBSD-SEM technique to identify the deformation stages affecting the lithospheric mantle in this zone and to assess the relationships between the deformation fabrics, processes and microstructures. Olivine CPOs in protogranular harzburgites, lherzolites and a pyroxenite display [010]-fiber patterns characterized by a strong point concentration of the [010] axis normal to the foliation and girdle distribution of [100] and [001] axes within the foliation plane. Olivine CPO symmetry in porphyroclastic and equigranular lherzolites varies continuously from [010]-fiber to orthorhombic and [100]-fiber types. The orthorhombic patterns are characterized by scattered maxima of the three axes, which are normal between them. The rare [100]-fiber patterns display strong point concentration of [100] axis, with normal girdle distribution of the other two axes, which are aligned with each other. The patterns of pyroxene CPOs are more dispersed than those of olivine, especially for clinopyroxene, but

  12. The systematics of chlorine, fluorine, and water in Izu arc front volcanic rocks: Implications for volatile recycling in subduction zones

    NASA Astrophysics Data System (ADS)

    Straub, Susanne M.; Layne, Graham D.

    2003-11-01

    We studied the systematics of Cl, F and H 2O in Izu arc front volcanic rocks using basaltic through rhyolitic glass shards and melt inclusions (Izu glasses) from Oligocene to Quaternary distal fallout tephra. These glasses are low-K basalts to rhyolites that are equivalent to the Quaternary lavas of the Izu arc front (Izu VF). Most of the Izu glasses have Cl ˜400-4000 ppm and F ˜70-400 ppm (normal-group glasses). Rare andesitic melt inclusions (halogen-rich andesites; HRA) have very high abundances of Cl (˜6600-8600 ppm) and F (˜780-910 ppm), but their contents of incompatible large ion lithophile elements (LILE) are similar to the normal-group glasses. The preeruptive H 2O of basalt to andesite melt inclusions in plagioclase is estimated to range from ˜2 to ˜10 wt% H 2O. The Izu magmas should be undersaturated in H 2O and the halogens at their preferred levels of crystallization in the middle to lower crust (˜3 to ˜11 kbar, ˜820° to ˜1200°C). A substantial portion of the original H 2O is lost due to degassing during the final ascent to surface. By contrast, halogen loss is minor, except for loss of Cl from siliceous dacitic and rhyolitic compositions. The behavior of Cl, F and H 2O in undegassed melts resembles the fluid mobile LILE (e.g.; K, Rb, Cs, Ba, U, Pb, Li). Most of the Cl (>99%), H 2O (>95%) and F (>53%) in the Izu VF melts appear to originate from the subducting slab. At arc front depths, the slab fluid contains Cl = 0.94 ± 0.25 wt%, F = 990 ± 270 ppm and H 2O = 25 ± 7 wt%. If the subducting sediment and the altered basaltic crust were the only slab sources, then the subducted Cl appears to be almost entirely recycled at the Izu arc (˜77-129%). Conversely, H 2O (˜13-22% recycled at arc) and F (˜4-6% recycled) must be either lost during shallow subduction or retained in the slab to greater depths. If a seawater-impregnated serpentinite layer below the basaltic crust were an additional source of Cl and H 2O, the calculated percentage of

  13. Volcanic stratigraphy and geochemical variations in Miocene-age rocks in western and southeastern Fort Irwin, California

    NASA Astrophysics Data System (ADS)

    Buesch, D.

    2015-12-01

    Lava flows and tuffaceous deposits ranging in composition from basalt to rhyolite, including basaltic trachyandesite to trachyte, are exposed in 800 km2 of western Fort Irwin area, California, and form the eastern edge of the Eagle Crags volcanic field (ECVF). The main ECVF has 40Ar/39Ar ages from ~18.7-12.4 Ma (mostly 18.7-18.5 Ma; Sabin et al. 1994), and on Fort Irwin, the ages are from 21.0-15.8 Ma (mostly 18.6-15.8 Ma; Schermer et al. 1996). 68 samples (56 lava flow, 4 dome-collapse breccia, 3 ignimbrite, and 5 fallout tephra) were analyzed for major, minor, and trace elements. Typically, stratigraphic sequences dip <30° (mostly <15°) except near faults, with local buttress unconfomities and no large unconfomities. Compositions are moderate-to-high-K type, and similar to Na2O+K2O from Sabin et al. (1994) but with slightly smaller ranges. The generalized stratigraphic sequence is rhyolite (R), dacite (D), or trachyte (T) that form domes, lava flows (up to 3.5 km long), dome-collapse deposits, or pyroclastic deposits, overlain by andesite (A), trachyandesite (TA), basaltic andesite (BA), basaltic trachyandesite (BT), or basalt (B) lava flows (up to 7 km long), and minor cinder cones. A general upward felsic to mafic compositional sequence occurs throughout the area, but is not continuous as B is locally in a R-D sequence and B is at the base of and interstratified with a BA-A sequence. Also, there are compositional variations at different locations along the edges of the field. In the Goldstone Mesa, Pink Canyon, and Stone Ridge areas (~70 km2), B-BA forms the youngest lava flows, but ~21 km to the north in the Garry Owen area (~25 km2), BTA forms the youngest lava flows. Compared to the Stone Ridge area with a D-A-TA-BA trend, ~6 km west in the Pioneer Plateau area is R-TA-D, ~3 km south in the Pink Canyon area is R-B-BA-A, and ~8 km east at Dacite Dome is D only (all areas have slightly different Na2O+K2O in each rock type). A non-ECVF, 5.6 Ma BA flow in SE

  14. [Micro-area characteristics of laminated chert in the volcanic rocks of Xionger Group of Ruyang area and its geological significances].

    PubMed

    Luo, An; Li, Hong-zhong; Zhao, Ming-zhen; Yang, Zhi-jun; Liang, Jin; He, Jun-guo

    2014-12-01

    The Xionger Group was originated from the volcanic eruption and sedimentation in Precambrian, whose sedimentary strata at the top were named Majiahe Formation. In the Majiahe Formation, there were hydrothermal chert widely distributed, which were exhibited to be interlayers in the volcanic rocks. The polarized microscope, X-ray diffraction (XRD), Raman and electron back scatter diffraction (EBSD) were conducted to study the characteristics in micro area of the jasperite samples, which were from the sedimentary interlayers in the volcanic rocks of Majiahe Formation in Xionger Group. As shown in the microphotographs and EBSD images, the quartz in the chert had small grain size, low degree of crystallinity and close packed structure, which quite agreed with the characteristics of hydrothermal sedimentary chert. In the chert of Xionger Group, there were clear banded (or lamellar) structures which were contributed by the diversities of the grain size and mineral composition. The different bands (or lamellars) had alternative appearance repeatedly, and denoted the diversities and periodic changes in the substance supply during the precipitation. According to the results of the XRD analysis, the majority minerals of the chert was low temperature quartz, whose lattice parameters were a=b=0.4913 nm, c=0.5405 nm and Z=3. As denoted in the EBSD image and result of Raman analysis, several impurity minerals were formed in the chert in different stages, whose geneses and formation time were quite different. The clay minerals and pyrite were scattered in distribution, and should be contributed by the original sedimentation. On contrary, the felsic minerals and mafic silicate minerals were originated from the sedimentation of tuffaceous substance during the volcanic eruption. The minerals of volcanic genesis had relatively larger grain size, and they deposited together with the hydrothermal sediments to form the bands (or lamellars) of coarse minerals. However, the hydrothermal

  15. Petrogenesis of Mafic Volcanic Rocks from the Pribilof Islands, Alaska, by Melting of Metasomatically Enriched Depleted Lithosphere, Crystallization Differentiation, and Magma Mixing

    NASA Astrophysics Data System (ADS)

    Feeley, T. C.; Chang, J. M.; Deraps, M. R.

    2008-12-01

    The Pribilof Islands, Alaska, are located in the Bering Sea in a continental intraplate setting. In this study we examine the petrology and geochemistry of mafic volcanic rocks from St. Paul (0.54 to 0.003 Ma) and St. George (2.9 to 1.4 Ma) Islands, the two largest Pribilof Islands. Together these islands offer an opportunity to simultaneously investigate an active and extinct Bering Sea basaltic volcanic field in a setting where features such as lithospheric thickness and composition, distance from the Aleutian arc front, and other tectonic factors are virtually constant. Rocks from St. George can be divided into three groups. Group 1 contains high MgO, low SiO2 rocks that are primarily basanites. Group 2 contains high MgO, high SiO2 rocks that predominantly alkali basalts. Group 3 contains intermediate to low MgO rocks that include alkali basalts and trachybasalts with high modal plagioclase contents. Major and trace element compositions indicate that Groups 1 and 2 formed by partial melting (2-4%) of amphibole-bearing, garnet peridotite. Group 1 rocks were produced from the most hydrous parts of the mantle, as they show the strongest signature of amphibole in their source. Rocks from St. Paul inlcude alkali basalts and basanites with MgO contents from 4.2 to 14.4 wt% at relatively constant SiO2 contents (43.1 to 47.3 wt%). The most primitive St. Paul rocks are interpreted as mixtures between magmas with compositions similar to Groups 1 and 2 from St. George Island. These magmas subsequently fractionated olivine, clinopyroxene, and spinel to form more evolved, plagioclase-rich rocks. Plagioclase-rich Group 3 rocks from St. George can be modeled as mixtures between an evolved St. Paul end-member and a fractionated Group 2 end-member from St. George. Mantle potential temperatures estimated for primitive basanites and alkali basalts average 1370°C and are similar to those calculated for mid-ocean ridge basalts (MORB). Similarly, 87Sr/86Sr and 143Nd/144Nd values for

  16. Alteration mapping at Goldfield, Nevada, by cluster and discriminant analysis of Landsat digital data. [mapping of hydrothermally altered volcanic rocks

    NASA Technical Reports Server (NTRS)

    Ballew, G.

    1977-01-01

    The ability of Landsat multispectral digital data to differentiate among 62 combinations of rock and alteration types at the Goldfield mining district of Western Nevada was investigated by using statistical techniques of cluster and discriminant analysis. Multivariate discriminant analysis was not effective in classifying each of the 62 groups, with classification results essentially the same whether data of four channels alone or combined with six ratios of channels were used. Bivariate plots of group means revealed a cluster of three groups including mill tailings, basalt and all other rock and alteration types. Automatic hierarchical clustering based on the fourth dimensional Mahalanobis distance between group means of 30 groups having five or more samples was performed using Johnson's HICLUS program. The results of the cluster analysis revealed hierarchies of mill tailings vs. natural materials, basalt vs. non-basalt, highly reflectant rocks vs. other rocks and exclusively unaltered rocks vs. predominantly altered rocks. The hierarchies were used to determine the order in which sets of multiple discriminant analyses were to be performed and the resulting discriminant functions were used to produce a map of geology and alteration which has an overall accuracy of 70 percent for discriminating exclusively altered rocks from predominantly altered rocks.

  17. A multianalytical approach to investigate stone biodeterioration at a UNESCO world heritage site: the volcanic rock-hewn churches of Lalibela, Northern Ethiopia

    NASA Astrophysics Data System (ADS)

    Schiavon, Nick; De Caro, Tilde; Kiros, Alemayehu; Caldeira, Ana Teresa; Parisi, Isabella Erica; Riccucci, Cristina; Gigante, Giovanni Ettore

    2013-12-01

    A multianalytical approach combining Optical Microscopy (OM), Backscattered Variable Pressure Scanning Electron Microscopy + Energy Dispersive X-ray Spectroscopy (VP-BSEM + EDS), Powder X-ray Diffractometry (PXRD), Raman Spectroscopy, and Microbiological techniques has been applied to characterize decay products and processes occurring at the surface of two rock-hewn churches ( Bete Gyorgis and Bete Amanuel) at the UNESCO's World Heritage site of Lalibela, Northern Ethiopia. The two churches were carved into volcanic scoria deposits of basaltic composition. In their geological history, the Lalibela volcanic rocks underwent late to post-magmatic hydrothermal alteration together with partial laterization and are therefore characterized by a decay-prone highly vesicular microtexture with late stage to post-magmatic precipitation of secondary mineral phases (calcite-zeolite-smectite). The main objective of the study was to gain a better insight into the weathering products and mechanisms affecting the surface of the stone monuments and to assess the relative contribution of natural "geological" weathering processes versus biological/salt attack in stone decay at this unique heritage site. Results indicate that while the main cause of bulk rock deterioration and structural failure could be related to the stone inherited "geological" features, biological attack by micro- (bacteria) and/or macro- (lichens) organisms is currently responsible for severe stone surface physical and chemical weathering leading to significant weakening of the stone texture and to material loss at the surface of the churches walls. A prompt and careful removal of the biological patinas with the correct biocidal treatment is therefore recommended.

  18. Pliocene Volcanic Evolution of the Taos Plateau, New Mexico

    NASA Astrophysics Data System (ADS)

    Cosca, M. A.; Thompson, R. A.; Turner, K. J.; Lee, J. P.

    2012-12-01

    New geologic mapping (1:24k-1:50k scale) and high precision 40Ar/39Ar geochronology of volcanic rocks from the Taos Plateau in northern New Mexico reveals nearly 4 million years of predominantly mafic (basalt to andesite) volcanism associated with the Pliocene to Quaternary Rio Grande rift. A nearly continuous record of volcanism is recorded from ~5 to ~1 Ma with two major pulses of magmatism observed at ~4.5 Ma and ~3 Ma reflecting eruption from more than 50 mapped centers and an unresolved number of centers buried by intercalated rift volcanics and sedimentary basin fill. Volcanism, both outflow thickness and vent locations, is strongly controlled by the same north to northwest trending fault systems defining the Rio Grande rift graben. However, active loci of volcanism can be linked to sub-basins within the broader graben structure. Large composite volcanoes ranging in composition from basaltic andesite to andesite, such as Guadeloupe Mountain (~4.5-5 Ma), Ute Mountain (~3.9 Ma), and San Antonio Mountain (~3 Ma) formed over time intervals of about 300 ka during the most voluminous stages of activity. Similar time intervals are recorded in each of three Servilleta basalt flow packages (lower (~4.5 Ma), middle (~4 Ma), and upper (~3.5 Ma)) observed at the Rio Grande gorge just north of Taos that first began erupting at ~ 4.7 Ma. Distinctive reddish paleosols between each Servilleta flow package represent time intervals between eruptions of ~0.5 Ma. Late stage volcanic activity (< 3 Ma) is recorded as small volume Servilleta basalt volcanoes and numerous small basalt to basaltic andesite cinder cones and associated lavas flows. Mesita Cone, dated at ~ 1 Ma and offset by middle Pleistocene faulting, represents the youngest volcanic activity within the Taos plateau segment of the Rio Grande Rift. The Pliocene to Quaternary volcanic rocks of the Taos Plateau are locally underlain by 1) Precambrian crystalline granite basement, 2) Oligocene calc-alkaline volcanic and

  19. Geochemical, petrographic and physical characterizations and associated alterations of the volcanic rocks of the Romanesque San Nicola Church (Ottana, central Sardinia, Italy)

    NASA Astrophysics Data System (ADS)

    Columbu, Stefano; Palomba, Marcella; Sitzia, Fabio

    2015-04-01

    In this research, the volcanic rocks belonging to the Sardinia Oligo-Miocene volcanic cycle (32 - 11 Ma) and building up the structure of the San Nicola church, one of the most representative churches of the Romanesque architecture, were studied. These stones were widely used in medieval architecture for the excellent workability, but they present some disadvantages, since they are greatly affected by alteration phenomena. The main objectives of this research are i) to focus the mineral, chemical and petrographic compositions of the San Nicola stones, ii) the chemical and physical alteration processes affecting these materials, and iii) to establish the exactly provenance of the volcanic rocks. Furthermore, a comparative study between the rocks from the ancient quarries and those forming the structure of the church was performed. In the ancient quarries, where presumably a more advanced alteration occurs due to the vertical alteration gradient, different facies of the same volcanic lithology, characterized by macroscopical evidences of chemical-physical degradation degree, were sampled. Petrographic, geochemical (both major elements that the traces) and physical-mechanical features of the collected samples were determined to highlight the compositional differences (density, porosity, water-absorption kinetics, mechanical resistance) as a function of the different alteration degree. Moreover, chemical-mineralogical analysis of the sample surfaces from the church, was performed, to highlight possible presence and nature of secondary newly-formed phases (e.g., salt efflorescence). Several methodologies were applied to carry out physical-chemical and petrographic analysis: X-Ray fluorescence (XRF) and Inductively Coupled Mass Spectrometry (ICP-MS), X-Ray Diffractometry (XRD) for chemical and mineral composition; Optical and Scanning Electron Microscopy (SEM) for textures, mineral assemblages and microstructures studies; He-picnometry, water-absorption and mechanical

  20. Li sbnd δ 18O sbnd SiO 2 systematics in volcanic rocks and mafic lower crustal granulite xenoliths

    NASA Astrophysics Data System (ADS)

    Mengel, K.; Hoefs, J.

    1990-11-01

    Li sbnd δ 18O sbnd SiO 2 relationships have been examined for suites of spilitized basaltic rocks (DSDP 504B; Xigaze Ophiolite; Blanco Fracture Zone; Greater Caucasus; Rhenohercynian Fold Belt) and intra-plate evolved tholeiites (Northern Hessian Depression and Vogelsberg, W Germany; Mount Falla, Transantarctic Mountains). Relative to unaltered MORB and intra-plate primary olivine tholeiites, both the spilitic rocks and the evolved tholeiites are characterized by Li and 18O enrichment. For the spilitic rocks, Li and 18O enrichment is accompanied by a loss of SiO 2 as a result of seawater hydrothermal alteration, whereas the evolved tholeiites have gained SiO 2, Li and 18O from fractionation of mafic phases and assimilation of crustal rocks. On Li vs. SiO 2 and δ 18O vs. SiO 2 diagrams, the two rock groups plot largely in distinct fields, suggesting the possibility of so distinguishing between such lithologies in the ancient rock record. Mafic granulite xenoliths from the Northern Hessian Depression have elevated Li and 18O abundances at low SiO 2 contents. Even after correction for extraction of felsic components, their Li sbnd δ 18O sbnd SiO 2 signatures plot within the field of spilitic protoliths, suggesting that the lower crust in this region contains relics of spilitic rocks from a former oceanic crust.

  1. Sphene (Titanite) as Both Monitor and Driver of Evolution of Felsic Magma: Miocene Volcanic Plutonic and Rocks of the Colorado River Region, NV-AZ, USA

    NASA Astrophysics Data System (ADS)

    Miller, C. F.; Colombini, L. L.; Wooden, J. L.; Mazdab, F. K.; Gualda, G. A.; Claiborne, L. E.; Ayers, J. C.

    2009-05-01

    Sphene is commonly the most abundant accessory mineral in metaluminous to weakly peraluminous igneous rocks. Its relatively large crystals preserve a wide array of zoning patterns and inclusions - notably, abundant other accessories and melt inclusions - and it is a major host for REE, U, Th, and HFSE. Thus it is a valuable repository of information about the history of the magmas from which it forms. Recent development of a Zr-in- sphene thermometer (Hayden et al CMP 155:529 2008) and of sensitive and precise in situ trace element analysis by SHRIMP-RG (Mazdab et al GSA abst 39:6:406 2007) permit more powerful exploitation of this repository. We have initiated a study of sphene in Miocene intrusive and extrusive rocks of the Colorado River extensional corridor for which extensive field, geochemical, and geochronological data provide context. Sphene is present as a late interstitial phase in some gabbros and diorites and common in quartz monzonites and granites. Among extrusive rocks, it occurs as phenocrysts in rhyolite lavas and tuffs that are products of small to giant eruptions (Peach Spring Tuff, >600 km3). Glasses that host sphene in the rhyolites are highly evolved (>76 wt% SiO2). Applying the Zr-in-sphene thermometer (TZr), SHRIMP-RG analyses indicate crystallization T between 730 and 810 C in both plutonic and volcanic rocks. This range is narrower than T estimates for zircon growth (Ti thermometry) for the same suite, which extend to somewhat lower and considerably higher values; zircons also tend to record more events and, evidently, longer histories. Ranges of REE patterns are variable and to some extent sample-specific, but all reveal common characteristics: (1) extremely high concentrations, especially for middle REE (maximum Sm in interiors 10-40x103 x chondrite); (2) deep negative Eu anomalies (Eu/Eu* ca. 0.1-0.2); (3) TZr and REE dropping toward rims - especially pronounced for MREE. Estimated Kds for REE from sphene rims and rhyolite glass or

  2. Volcanic rocks and subglacial volcanism beneath the West Antarctic Ice Sheet in the West Antarctic Rift System, (WAIS) from aeromagnetic and radar ice sounding - Thiel Subglacial Volcano as possible source of the ash layer in the WAISCORE

    NASA Astrophysics Data System (ADS)

    Behrendt, J. C.

    2012-12-01

    Radar ice sounding and aeromagnetic surveys reported over the West Antarctic Ice Sheet (WAIS) have been interpreted as evidence of subglacial volcanic eruptions over a very extensive area (>500,000 km2 ) of the volcanically active West Antarctic rift system interpreted as caused by subglacial volcanic rocks. Several active volcanoes have shown evidence of eruption through the WAIS and several other active volcanoes are present beneath the WAIS reported from radar and aeromagnetic data. Five-kilometer spaced coincident aeromagnetic and radar ice sounding surveys since 1990 provide three dimensional characterization of the magnetic field and bed topography beneath the ice sheet. These 5-50-km-width, semicircular magnetic anomalies range from 100->1000 nT as observed ~1 km over the 2-3 km thick ice have been interpreted as evidence of subglacial eruptions. Comparison of a carefully selected subset of ~400 of the >1000 high-amplitude anomalies in the CWA survey having topographic expression at the glacier bed, showed >80% had less than 200-m relief. About 18 high-amplitude subglacial magnetic sources also have high topography and bed relief (>600 m) interpreted as subaerially erupted volcanic peaks when the WAIS was absent, whose competent lava flows protected their edifices from erosion. All of these would have high elevation above sea-level, were the ice removed and glacial rebound to have occurred. Nine of these subaerially erupted volcanoes are concentrated in the WAIS divide area. Behrendt et al., 1998 interpreted a circular ring of positive magnetic anomalies overlying the WAIS divide as caused by a volcanic caldera. The area is characterized by high elevation bed topography. The negative regional magnetic anomaly surrounding the caldera anomalies was interpreted as the result of a shallow Curie isotherm. High heat flow inferred from temperature logging in the WAISCORE (G. Clow 2012, personal communication; Conway, 2011) and a prominent volcanic ash layer in the

  3. Chemical, mineralogical and textural systematics of non-mare melt rocks: Implications for lunar impact and volcanic processes

    NASA Technical Reports Server (NTRS)

    Irving, A. J.

    1975-01-01

    Based on a synthesis of chemical data for over 200 samples, the nonmare rocks with fine grained melt textures can be classified into 7 major groups: anorthositic basalts, troctolitic basalts, VHA basalts, Apollo 14-type KREEP basalts, Apollo 15-type KREEP basalts, Apollo 17-type KREEP basalts, and aluminous mare basalts. Review of chemical, mineralogical, textural and experimental evidence leads to preferred hypotheses for the origins of these rocks; those hypotheses are discussed in detail.

  4. Petrogenesis of the Miocene felsic volcanism from the south of Izmir (Western Turkey) and its regional tectono-magmatic implications

    NASA Astrophysics Data System (ADS)

    Karacik, Z.; Genç, C.

    2013-12-01

    Miocene volcanism, mainly intermediate and rarely mafic and felsic in composition, was produced under the effects of the extensional tectonic regime in western Turkey. The Karaburun and Cumaovasi volcanics are the cases for understanding the magma source(s) and petrological processes, producing the extension-related mafic and felsic bimodal volcanism. The Karaburun volcanics (KV) are mainly distributed north to south direction within the Karaburun peninsula and span a wide compositional spectrum from basalt (20 Ma) to rhyolite (16 Ma), and younger trachyte and trachydacites (13 Ma). The products of the subaerial felsic volcanism (the Cumaovasi volcanics, CV; 17 Ma) which are represented by cluster of topaz bearing rhyolite domes, related pyroclastic rocks occur within the NE-SW trending Cubukludag graben. The intermediate and mafic volcanic rocks are lack in the volcanic succession of CV. The lavas of the Cumaovasi volcanics are silicic which are calc alkaline, peralumious and enriched significantly in LILE. Extremely low Sr, Ba values, Eu depletions and very low LaN/YbN ratios are typical for rhyolites. The Karaburun volcanics, with the exception of the minor alkaline basaltic and trachytic lavas, are mainly calc alkaline and metaluminous intermediate lavas. The petrological data revealed that the KV and CV were formed in extensional tectonic setting, but evolved by different petrological processes in different magma chambers. The Cumaovasi lavas have a unique chemical composition, and closely similar to the extension related topaz bearing rhyolites formed from small magma bodies. Our data reveal that extension related mafic injections caused crustal anatectic melting and produced felsic melts that rapidly ascended into the upper crust.

  5. Geochemistry of subalkaline and alkaline extrusives from the Kermanshah ophiolite, Zagros Suture Zone, Western Iran: implications for Tethyan plate tectonics

    NASA Astrophysics Data System (ADS)

    Ghazi, A. Mohamad; Hassanipak, A. A.

    1999-06-01

    The Kermanshah ophiolite is a highly dismembered ophiolite complex that is located in western Iran and belongs to the Zagros orogenic system. The igneous rocks of this complex consist of both mantle and crustal suites and include peridotites (dunite and harzburgite), cumulate gabbros, diorites, and a volcanic sequence that exhibits a wide range in composition from subalkaline basalts to alkaline basalts to trachytes. The associated sedimentary rocks include a variety of Upper Triassic to Lower Cretaceous deep- and shallow-water sedimentary rocks (e.g., dolomite, limestone, and pelagic sediments, including umber). Also present are extensive units of radiolarian chert. The geochemical data clearly identifies some of the volcanic rocks to have formed from two distinct types of basaltic melts: (i) those of the subalkaline suite, which formed from an initial melt with a light rare earth elements (LREE) enriched signature and incompatible trace element patterns that suggest an island arc affinity; and (ii) those of the alkaline suite with LREE-enriched signature and incompatible trace element patterns that are virtually identical to typical oceanic island basalt (OIB) pattern. The data also suggests that the trachytes were derived from the alkaline source, with fractionation controlled by extensive removal of plagioclase and to a lesser extent clinopyroxene. The presence of compositionally diverse volcanics together with the occurrence of a variety of Triassic-Cretaceous sedimentary rocks and radiolarian chert indicate that the studied volcanic rocks from the Kermanshah ophiolite represent off-axis volcanic units that were formed in intraplate oceanic island and island arc environments in an oceanic basin. They were located on the eastern and northern flanks of one of the spreading centers of a ridge-transform fault system that connected Troodos to Oman prior to its subduction under the Eurasian plate.

  6. Volcanic ash in bare ice south of Sør Rondane Mountains, Antarctica: geochemistry, rock magnetism and nondestructive magnetic detection with SQUID gradiometer

    NASA Astrophysics Data System (ADS)

    Oda, Hirokuni; Miyagi, Isoji; Kawai, Jun; Suganuma, Yusuke; Funaki, Minoru; Imae, Naoya; Mikouchi, Takashi; Matsuzaki, Takuya; Yamamoto, Yuhji

    2016-03-01

    Nondestructive magnetic detection of tephra layers in ice cores will be an important method to identify and correlate stratigraphic horizons of ice bearing volcanic ash particles. Volcanic ash particles were extracted from tephra-bearing ice samples collected from Nansen Ice Field south of the Sør Rondane Mountains, Antarctica. Particles are fresh glassy volcanic ash with diameters of ~50 μm, and chemical composition of the matrix glass belongs to a low-K basaltic andesite group, ranging from SiO2 60-62 wt% and K2O 0.40-0.50 wt%. Considering the grain size of ash particles and chemical composition of volcanic glass, the ash in tephra-bearing ice samples might be originated from the South Sandwich Islands located 2800 km northwest of the sampling sites. Correlations on major element concentrations with tephra layers associated with South Sandwich Islands in EPICA-Dome C, Vostok, and Dome Fuji ice cores show high similarity. Rock magnetic experiments show that the magnetic mineral is pseudo-single-domain titanomagnetite with ulvospinel content of 0.2-0.35 mixed with single-domain to superparamagnetic (titano)magnetite. Small blocks of the tephra-bering ice were measured with a SQUID gradiometer at 1-mm intervals with a spatial resolution of ~3 mm. With DC magnetic field of 25 mT, magnetic signal could be enhanced and detected for all the samples including the one with invisible amount of tephra particles. In order to simulate a thin ash layer in ice core, volcanic ash particles extracted from the tephra-bearing ice were used to fabricate a thin ash layer, which were subsequently magnetized, measured with the gradiometer. The noise level for Z axis gradiometer was about 0.6 pT. Detection limit for a half-cylinder with 29 mm radius and a thickness of 1 mm uniformly magnetized in X axis direction is ~9 × 10-5 A/m, which could be improved down to ~2 × 10-6 A/m by reducing the sensor-to-sample distance to 0.5 mm.

  7. Geological investigations of volcanic rocks at Mount Discovery, Mount Morning, and Mason Spur, McMurdo Sound

    SciTech Connect

    Wright, A.C.; Kyle, P.R.; More, J.A.; Meeker, K.

    1986-01-01

    This work includes mapping of volcanic geology, description of geologic sections, and collection of samples for geochemical analysis and potassium-argon dating. Reconnaissance mapping of Mount Discovery shows that this 2681-meter-high composite volcano comprises a core of plagioclase-phyric nepheline-benmoreite flows, lahars, and volcanoclastic fluviatile sediments, which are thought to be the unit dated at 5.44 million years. Reconnaissance mapping of Mount Morning shows that this is a young volcano principally composed of kaersutite-bearing phonolite flows erupted both from the summit crater and from small parasitic domes on the upper northern slopes of the mountain. A sample from one of these parasitic domes has been dated at 1.15 million years. Description of five geologic sections at Mason Spur has provided a more detailed understanding of the older trachytic volcanic complex, which is now dated at 11.5 to 12.8 years and is divided into seven mapped units.

  8. Planetary volcanism - A study of volcanic activity in the solar system

    NASA Technical Reports Server (NTRS)

    Cattermole, Peter

    1989-01-01

    The nature of volcanic activity, theoretical models of its role in planetary evolution, and the evidence for volcanism on the planets and planetary satellites are examined in an introductory overview for advanced undergraduate and graduate students. Chapters are devoted to volcanism as a planetary process, the generation and evolution of magmas, magma ascent and eruption, the properties and behavior of volcanic flows, volcanic landforms, the distribution of volcanic rocks in the solar system, and volcanic plains and their development. Consideration is given to lunar volcanism, shield volcanoes and paterae, volcanism on Io, volcanism on icy satellites, and the rheological analysis of volcanic flows.

  9. Specific activities of natural rocks and soils at quaternary intraplate volcanism north of Sana’a, Yemen

    PubMed Central

    Harb, Shaban; El-Kamel, Abd El-Hadi; Abbady, Abd El-Bast; Saleh, Imran Issa; El-Mageed, Abdallah Ibrahim Abd

    2012-01-01

    The level of natural radioactivity in rocks and soil of 32 samples collected from locations at North Sana′a in Yemen was measured. Concentrations of radionuclides in rocks and soils samples were determined by gamma-ray spectrometer using high purity germanium (HPGe) detector with specially designed shield. The average radioactivity concentrations of 226Ra, 232Th, 40K were determined and expressed in Bq/kg. The results showed that these radionuclides were present in concentrations of 21.79 ± 3.1, 19.5 ± 2.6 and 399.3 ± 16 Bq/kg, respectively, for rocks. For soil, the corresponding values were 48.2 ± 4.4, 41.7 ± 4.5 and 939.1 ± 36 Bq/kg, respectively. Also, the radiological hazard of the natural radionuclide content, radium equivalent activity, total dose rates, external hazard index and gamma activity concentration index of the (rocks/soils) samples in the area under consideration were calculated. The dose rates at 1 m above the ground from terrestrial sources were 38.39 and 86.89 nGy/h for rocks and surface soil, respectively, which present no significant health hazards to humans. PMID:22363113

  10. 40Ar-39Ar dating and tectonic implications of volcanic rocks recovered at IODP Hole U1342A and D on Bowers Ridge, Bering Sea

    NASA Astrophysics Data System (ADS)

    Sato, Keiko; Kawabata, Hiroshi; Scholl, David W.; Hyodo, Hironobu; Takahashi, Kozo; Suzuki, Katsuhiko; Kumagai, Hidenori

    2016-03-01

    During the Integrated Ocean Drilling Program (IODP), a total of 41.54 m of basement rock, consolidated volcaniclastic sediment, was recovered beneath a thin sediment cover. The drilled site is at the eastern end of the crestal area of Bowers Ridge, a north and westward sweeping offshoot of the Aleutian Arc into the Bering Sea. The volcanic sequence recovered from Holes U1342A and U1342D was divided into six major lithologic units. We used the single grain 40Ar-39Ar dating method performed by step-wise heated laser fusion technique to date andesites of Unit 1. Thereby two ages of Oligocene volcanism (34-32 Ma, 28-26 Ma) were distinguished each other according to our 40Ar-39Ar data. These ages refute a hypothesized Cretaceous origin in the North Pacific as an exotic arc massif or sector of the Hawaiian-Emperor chain and indicate that the Bowers Ridge is a Bering-Sea formed arc or remnant arc that ceased forming in the latest Oligocene to the earliest Miocene time.

  11. Heterogeneity of hydrodynamic properties and groundwater circulation of a coastal andesitic volcanic aquifer controlled by tectonic induced faults and rock fracturing - Martinique island (Lesser Antilles - FWI)

    NASA Astrophysics Data System (ADS)

    Vittecoq, B.; Reninger, P. A.; Violette, S.; Martelet, G.; Dewandel, B.; Audru, J. C.

    2015-10-01

    We conducted a multidisciplinary study to analyze the structure and the hydrogeological functioning of an andesitic coastal aquifer and to highlight the importance of faults and associated rock fracturing on groundwater flow. A helicopter-borne geophysical survey with an unprecedented resolution (SkyTEM) was flown over this aquifer in 2013. TDEM resistivity, total magnetic inte