Science.gov

Sample records for allen fossil plant

  1. Fossil power plant systems description

    SciTech Connect

    Not Available

    1984-01-01

    This single-volume, looseleaf text presents the functions and relationships between each major component and its auxiliaries within a system. The text also describes the relationships between systems. All major components are addressed, and system boundaries are defined for a generic fossil power plant.

  2. Cycling operation of fossil plants

    SciTech Connect

    Bhatnagar, U.S.; Weiss, M.D.; White, W.H. ); Buchanan, T.L.; Harvey, L.E.; Shewchuk, P.K.; Weinstein, R.E. )

    1991-05-01

    This report presents a methodology for examining the economic feasibility of converting fossil power plants from baseload to cycling service. It employs this approach to examine a proposed change of Pepco's Potomac River units 3, 4, and 5 from baseload operation of two-shift cycling. The project team first reviewed all components and listed potential cycling effects involved in the conversion of Potomac River units 3, 4, and 5. They developed general cycling plant screening criteria including the number of hot, warm, or cold restart per year and desired load ramp rates. In addition, they evaluated specific limitations on the boiler, turbine, and the balance of plant. They estimated the remaining life of the facility through component evaluation and boiler testing and also identified and prioritized potential component deficiencies by their impact on key operational factors: safety, heat rate, turn down, startup/shutdown time, and plant availability. They developed solutions to these problems; and, since many solutions mitigate more than one problem, they combined and reprioritized these synergistic solutions. Economic assessments were performed on all solutions. 13 figs., 20 tabs.

  3. Fossil power plant operating procedures

    SciTech Connect

    Not Available

    1984-01-01

    This three-volume text presents the theory and interaction of all components within a system. Startup, normal, emergency, and shutdown operating techniques are discussed for each component and subsystem within the sixteen systems addressed. In addition to the plant systems, pump operation, fluid piping, instrumentation and control, and piping and instrument drawings (P and IDs) are covered.

  4. Life optimization for fossil fuel power plants

    SciTech Connect

    McNaughton, W.P.; Richman, R.H. ); Parker, J.D.; McMinn, A. ); Bell, R.J. ); McCabe, P.; Leake, W.H. Jr. ); Dimmer, J.P.; Damon, J.E. ); Brusger, E.C.; Farber, M.

    1990-11-01

    During 1985 and 1986, EPRI funded several major studies of aging fossil-fuel power plants. These were aimed both at evaluation and planning on the plant level (life optimization), and condition assessment of individual components (life assessment). The experience gained during the execution of these projects, along with available international experience on the optimized use of existing power plants, was integrated in Generic Guidelines for the Life Extension of Fossil Fuel Power Plants,'' issued in November 1986 (CS-4778). These guidelines advocated the assessment of residual component life in increasingly detailed stages, the phased evaluation and refurbishment of equipment, the importance of integrated planning, and the requirement for application of data management techniques. To extend the procedures and methods presented in those generic guidelines, and to demonstrate the potential benefits of a formalized approach to the consideration of fossil fuel power plant evaluation, the Electric Power Research Institute initiated a technology transfer demonstration project, RP2596-10. This report provides a summary of the activities in that demonstration project. One of the tools that was developed during the project was a compilation of the condition assessment of 25 critical and major components. This report includes an overview of the Component Condition Assessment Guidelines, as well as other tools and analysis methods that were developed during the project. The project also served as a review of the application of the methods and procedures presented in the basic guidelines document; therefore, this report also includes an evaluation and suggested refinements of the generic guidelines.

  5. Adaptation, plant evolution, and the fossil record

    NASA Technical Reports Server (NTRS)

    Knoll, A. H.; Niklas, K. J.

    1987-01-01

    The importance of adaptation in determining patterns of evolution has become an important focus of debate in evolutionary biology. As it pertains to paleobotany, the issue is whether or not adaptive evolution mediated by natural selection is sufficient to explain the stratigraphic distributions of taxa and character states observed in the plant fossil record. One means of addressing this question is the functional evaluation of stratigraphic series of plant organs set in the context of paleoenvironmental change and temporal patterns of floral composition within environments. For certain organ systems, quantitative estimates of biophysical performance can be made on the basis of structures preserved in the fossil record. Performance estimates for plants separated in time or space can be compared directly. Implicit in different hypotheses of the forces that shape the evolutionary record (e.g. adaptation, mass extinction, rapid environmental change, chance) are predictions about stratigraphic and paleoenvironmental trends in the efficacy of functional performance. Existing data suggest that following the evolution of a significant structural innovation, adaptation for improved functional performance can be a major determinant of evolutionary changes in plants; however, there are structural and development limits to functional improvement, and once these are reached, the structure in question may no longer figure strongly in selection until and unless a new innovation evolves. The Silurian-Devonian paleobotanical record is consistent with the hypothesis that the succession of lowland floodplain dominants preserved in the fossil record of this interval was determined principally by the repeated evolution of new taxa that rose to ecological importance because of competitive advantages conferred by improved biophysical performance. This does not seem to be equally true for Carboniferous-Jurassic dominants of swamp and lowland floodplain environments. In these cases

  6. Atmospheric CO2 from fossil plant cuticles.

    PubMed

    Kerp, Hans

    2002-01-01

    Plants respond to changes in atmospheric carbon dioxide levels by regulating the number of stomata in their leaves. In his reconstruction of a continuous, 300-million-year record of atmospheric CO2, Retallack bases his curve on stomatal counts of fossil plant cuticles taken from published micrographs. However, the preservation of cuticles from Permian times is generally too fragmentary for the stomatal index to be reliably determined, the micrographs used could have biased the results, and there are important errors in the supplementary data - all of which cast doubt on the Permian part of Retallack's record.

  7. Evaluation of effects of groundwater withdrawals at the proposed Allen combined-cycle combustion turbine plant, Shelby County, Tennessee

    USGS Publications Warehouse

    Haugh, Connor J.

    2016-08-10

    The Mississippi Embayment Regional Aquifer Study groundwater-flow model was used to simulate the potential effects of future groundwater withdrawals at the proposed Allen combined-cycle combustion turbine plant in Shelby County, Tennessee. The scenario used in the simulation consisted of a 30-year average withdrawal period followed by a 30-day maximum withdrawal period. Effects of withdrawals at the Allen plant site on the Mississippi embayment aquifer system were evaluated by comparing the difference in simulated water levels in the aquifers at the end of the 30-year average withdrawal period and at the end of the scenario to a base case without the Allen combined-cycle combustion turbine plant withdrawals. Simulated potentiometric surface declines in the Memphis aquifer at the Allen plant site were about 7 feet at the end of the 30-year average withdrawal period and 11 feet at the end of the scenario. The affected area of the Memphis aquifer at the Allen plant site as delineated by the 4-foot potentiometric surface-decline contour was 2,590 acres at the end of the 30-year average withdrawal period and 11,380 acres at the end of the scenario. Simulated declines in the underlying Fort Pillow aquifer and overlying shallow aquifer were both less than 1 foot at the end of the 30-year average withdrawal period and the end of the scenario.

  8. Evaluation of effects of groundwater withdrawals at the proposed Allen combined-cycle combustion turbine plant, Shelby County, Tennessee

    USGS Publications Warehouse

    Haugh, Connor J.

    2016-01-01

    The Mississippi Embayment Regional Aquifer Study groundwater-flow model was used to simulate the potential effects of future groundwater withdrawals at the proposed Allen combined-cycle combustion turbine plant in Shelby County, Tennessee. The scenario used in the simulation consisted of a 30-year average withdrawal period followed by a 30-day maximum withdrawal period. Effects of withdrawals at the Allen plant site on the Mississippi embayment aquifer system were evaluated by comparing the difference in simulated water levels in the aquifers at the end of the 30-year average withdrawal period and at the end of the scenario to a base case without the Allen combined-cycle combustion turbine plant withdrawals. Simulated potentiometric surface declines in the Memphis aquifer at the Allen plant site were about 7 feet at the end of the 30-year average withdrawal period and 11 feet at the end of the scenario. The affected area of the Memphis aquifer at the Allen plant site as delineated by the 4-foot potentiometric surface-decline contour was 2,590 acres at the end of the 30-year average withdrawal period and 11,380 acres at the end of the scenario. Simulated declines in the underlying Fort Pillow aquifer and overlying shallow aquifer were both less than 1 foot at the end of the 30-year average withdrawal period and the end of the scenario.

  9. SO sub 2 compliance Cumberland Fossil Plant

    SciTech Connect

    Not Available

    1991-08-01

    The Clean Air Act Amendments (CAAA) of 1990 require a national reduction in SO{sub 2} emissions to control acid rain. This environmental assessment (EA) describes alternative considered (and the associated environmental consequences) for complying with SO{sub 2} reduction requirements of the amendments at Tennessee Valley Authority's (TVA) Cumberland Fossil Plant (CUF). TVA proposes to reduce SO{sub 2} emissions at CUF to 1.2 lb/10{sub 6} Btu or less as part of its compliance with the CAAA requirements. The two most viable options to achieve this reduction are a switch to western low- sulfur coal and the installation of flue gas desulfurization (FGD), also called scrubbers.

  10. Proceedings: Sixth International Conference on Fossil Plant Cycle Chemistry

    SciTech Connect

    2001-04-01

    The purity of boiler water, feedwater, and steam is central to ensuring component availability and reliability in fossil-fired plants. These conference proceedings address the state of the art in fossil plant and combined cycle/heat recovery steam generator (HRSG) cycle chemistry as well as international practices for control of corrosion and water preparation and purification.

  11. Zeolites replacing plant fossils in the Denver formation, Lakewood, Colorado.

    USGS Publications Warehouse

    Modreski, P.J.; Verbeek, E.R.; Grout, M.A.

    1984-01-01

    Well-developed crystals of heulandite and stilbite, within fossil wood, occur in sedimentary rocks in Lakewood, Jefferson County. The rocks belong to the Denver formation, a locally fossiliferous deposit of fluvial claystone, siltstone, sandstone and conglomerate, containing some volcanic mudflows (andesitic) of late Cretaceous to Palaeocene age. Altered volcanic glass released Na and Ca into the ground-water and subsequently zeolites were crystallized in the open spaces between grains and within fossil plant structures. Minor pyrite, quartz (jasper), calcite and apatite also occur as replacements of fossil wood. Similar zeolite occurrences in other areas are reviewed.-R.S.M.

  12. Bull Run Fossil Plant toxicity biomonitoring study

    SciTech Connect

    Hackney, P.A.; Moses, J.

    1986-11-01

    This report presents the results of toxicity testing of the whole waste discharge from the Bull Run Steam-Electric Plant ashpond. Water chemistry tests were conducted for heavy metals content and suspended solids. Both acute and chronic toxicity tests were conducted on Daphnia pulex, Ceriodaphnia spp., Pimephales promelas, Micropterus salmoides, Lepomis macrochirus, and Cyprinus carpio. (ACR)

  13. Impact of UBC-1988 seismic provisions on fossil plant structures

    SciTech Connect

    Singh, S.; Longlais, T.G.; Lo, A. )

    1988-01-01

    The December 1986 draft version of the 1988 edition of the Uniform Building Code (UBC) has proposed many seismic provisions based on the Applied Technology Council (ATC) 1978 report, Tentative Provisions for Development of Seismic Regulations for Buildings. The impact of the ATC provisions on residential and office buildings has been studied by others. To the authors' knowledge, their impact on fossil power plant structures has not been studied. This paper provides information on how the UBC-1988 seismic provisions will affects the bracing and connection design of a typical 600-MW fossil plant facility. Based on a comparison of the December 1986 draft version of UBC-1988 with the UBC-1985 requirements, it is estimated that the new requirements will have a major impact on plant structures with concentric bracing in seismic zones 2, 3, and 4. The paper also emphasizes the differences between power block structures and residential and office buildings and discusses the applicability of these provisions to fossil power plant structures.

  14. Productivity improvement handbook for fossil steam power plants. Final report

    SciTech Connect

    Armor, A.F.; Wolk, R.H. |

    1998-09-01

    This book is written to help electric generation staff operate their plants more profitably in a competitive environment. Since responsibility for keeping the plant running falls directly on the shoulders of plant personnel, they want to understand what can go wrong, receive information on the current condition of equipment, and fix things when equipment fails or performs poorly. The information in this book is organized so a reader can quickly and easily grasp the current state-of-the-art in maintaining fossil steam units, obtain guidance on specific plant problems, and move ahead with solutions. Many reports and guidelines have been issued on boilers, turbines, generators, heat exchangers, and other plant equipment covering failure modes, causes, fixes, and maintenance practices. Liberal use has been made of these reports to extract the salient recommendations, and the citations and bibliographies acknowledge these sources. The reader is directed to the comprehensive list of reports and papers for further details on specific issues. The scope of this book does not permit a detailed and extensive treatment of each of the hundreds of potential in-plant problems, but does permit the reader to get a first assessment of likely symptoms and modes of failure, and enough information to do something about it. It`s a working handbook for fossil plant staff who are daily faced with protecting the integrity and reliability of the electric generation business.

  15. Advanced fission and fossil plant economics-implications for fusion

    SciTech Connect

    Delene, J.G.

    1994-09-01

    In order for fusion energy to be a viable option for electric power generation, it must either directly compete with future alternatives or serve as a reasonable backup if the alternatives become unacceptable. This paper discusses projected costs for the most likely competitors with fusion power for baseload electric capacity and what these costs imply for fusion economics. The competitors examined include advanced nuclear fission and advanced fossil-fired plants. The projected costs and their basis are discussed. The estimates for these technologies are compared with cost estimates for magnetic and inertial confinement fusion plants. The conclusion of the analysis is that fusion faces formidable economic competition. Although the cost level for fusion appears greater than that for fission or fossil, the costs are not so high as to preclude fusion`s potential competitiveness.

  16. HIGH EFFICIENCY FOSSIL POWER PLANT (HEFPP) CONCEPTUALIZATION PROGRAM

    SciTech Connect

    J.L. Justice

    1999-03-25

    This study confirms the feasibility of a natural gas fueled, 20 MW M-C Power integrated pressurized molten carbonate fuel cell combined in a topping cycle with a gas turbine generator plant. The high efficiency fossil power plant (HEFPP) concept has a 70% efficiency on a LHV basis. The study confirms the HEFPP has a cost advantage on a cost of electricity basis over the gas turbine based combined cycle plants in the 20 MW size range. The study also identifies the areas of further development required for the fuel cell, gas turbine generator, cathode blower, inverter, and power module vessel. The HEFPP concept offers an environmentally friendly power plant with minuscule emission levels when compared with the combined cycle power plant.

  17. Advanced thermometrics for fossil power plant process improvement

    SciTech Connect

    Shepard, R.L.; Weiss, J.M.; Holcomb, D.E.

    1996-04-30

    Improved temperature measurements in fossil power plants can reduce heat rate and uncertainties in power production efficiencies, extend the life of plant components, reduce maintenance costs, and lessen emissions. Conventional instruments for measurement of combustion temperatures, steam temperatures, and structural component temperatures can be improved by better specification, in situ calibration, signal processing, and performance monitoring. Innovative instruments can enhance, augment, or replace conventional instruments. Several critical temperatures can be accessed using new methods that were impossible with conventional instruments. Such instruments include high temperature resistance temperature detectors (RTDs), thermometric phosphors, inductive thermometry, and ultrasonic thermometry.

  18. Justification of simulators for fossil fuel power plants. Final report

    SciTech Connect

    Beare, A.N.; Gaddy, C.D.; Lewis-Clapper, R.C.; Taylor, J.C.

    1993-10-01

    The cost-benefit analysis of simulators (CBAS) project is part of an overall effort by the Electric Power Research Institute and the fossil power industry to expand and enhance the appropriate use of simulators in the fossil industry. The CBAS project consists of three tasks: (1) quantify operator performance associated with operator-controllable plant parameters and situations, (2) compare the training effectiveness of various types of simulators, and (3) develop and demonstrate a methodology and database for quantifying the benefits of fossil training simulators. This report describes the first and third tasks of the project. For the first task in the project, eight utilities provided data for operator-controllable plant performance. This data collection effort was designed to assess the actual and potential effects of simulator training in improving operator performance and reducing error, as well as determining the dollar value of improved performance and reduced number of errors. Developing a methodology and database for assessing simulator training benefits is the second task in the project. The methodology and database will provide a basis for determining the impact of various types of simulator training on operator performance and the potential savings in plant operating costs. A worksheet developed from a portion of this task is provided in this report. The worksheet steps the user through calculations, based on plant data, to determine if purchasing a simulator is cost-beneficial. This project would benefit from additional tasks to further clarify and validate the objectives. The major emphasis would be to collect follow-up data from utilities that recently implemented simulator training and to collect data from additional utilities. Planned follow-on work includes comparing the training effectiveness of various types of simulators and continuing to transfer the technology studied in this report.

  19. Chemical signatures of fossilized resins and recent plant exudates.

    PubMed

    Lambert, Joseph B; Santiago-Blay, Jorge A; Anderson, Ken B

    2008-01-01

    Amber is one of the few gemstones based on an organic structure. Found over most of the world, it is the fossil form of sticky plant exudates called resins. Investigation of amber by modern analytical techniques provides structural information and insight into the identity of the ancient plants that produced the source resin. Mass spectrometric analysis of materials separated by gas chromatography has identified specific compounds that are the basis of a reliable classification of the different types of amber. NMR spectroscopy of bulk, solid amber provides a complementary classification. NMR spectroscopy also can be used to characterize modern resins as well as other types of plant exudates such as gums, gum resins, and kinos, which strongly resemble resins in appearance but have very different molecular constitutions.

  20. Chemical signatures of fossilized resins and recent plant exudates.

    PubMed

    Lambert, Joseph B; Santiago-Blay, Jorge A; Anderson, Ken B

    2008-01-01

    Amber is one of the few gemstones based on an organic structure. Found over most of the world, it is the fossil form of sticky plant exudates called resins. Investigation of amber by modern analytical techniques provides structural information and insight into the identity of the ancient plants that produced the source resin. Mass spectrometric analysis of materials separated by gas chromatography has identified specific compounds that are the basis of a reliable classification of the different types of amber. NMR spectroscopy of bulk, solid amber provides a complementary classification. NMR spectroscopy also can be used to characterize modern resins as well as other types of plant exudates such as gums, gum resins, and kinos, which strongly resemble resins in appearance but have very different molecular constitutions. PMID:18925589

  1. Water quality investigation of Kingston Fossil Plant dry ash stacking

    SciTech Connect

    Bohac, C.E.

    1990-04-01

    Changing to a dry ash disposal systems at Kingston Fossil Plant (KFP) raises several water quality issues. The first is that removing the fly ash from the ash pond could alter the characteristics of the ash pond discharge to the river. The second concerns proper disposal of the runoff and possibly leachate from the dry ash stack. The third is that dry ash stacking might change the potential for groundwater contamination at the KFP. This report addresses each of these issues. The effects on the ash pond and its discharge are described first. The report is intended to provide reference material to TVA staff in preparation of environmental review documents for new ash disposal areas at Kingston. Although the investigation was directed toward analysis of dry stacking, considerations for other disposal options are also discussed. This report was reviewed in draft form under the title Assessment of Kingston Fossil Plant Dry Ash Stacking on the Ash Pond and Groundwater Quality.'' 11 refs., 3 figs., 18 tabs.

  2. Proceedings: 7th International Conference on Cycle Chemistry in Fossil Plants

    SciTech Connect

    2004-02-01

    The purity of boiler water, feedwater, and steam is central to ensuring component availability and reliability in fossil-fired plants. These proceedings of EPRI's Seventh International Conference on Cycle Chemistry in Fossil Plants address the state of the art in fossil plant and combined cycle/heat recovery steam generator (HRSG) cycle chemistry as well as international practices for corrosion control and water preparation and purification.

  3. Cost and performance baseline for fossil energy plants

    SciTech Connect

    2007-05-15

    The objective of this report is to present performance and cost data for fossil energy power systems, specifically integrated gasification combined cycle (IGCC), pulverized coal (PC), and natural gas combined cycle (NGCC) plants, in a consistent technical and economic manner that accurately reflects current market conditions for plants starting operation in 2010. This is Volume 2 of the three-volume report. Twelve different power plant design configurations were analyzed. These include six IGCC cases utilizing the General Electric Energy (GEE), ConocoPhillips (CoP), and Shell gasifiers each with and without CO{sub 2} capture, and six cases representing conventional technologies: PC-subcritical, PC-supercritical, and NGCC plants both with and without CO{sub 2} capture. Cases 7 and 8 were originally included in this study and involve production of synthetic natural gas (SNG) and the repowering of an existing NGCC facility using SNG. The two SNG cases were subsequently moved to Volume 2 of this report resulting in the discontinuity of case numbers (1-6 and 9-14). Chapter 2 provides the basis for technical, environmental and cost evaluations. Chapter 3 describes the IGCC technologies modeled and presents the results for the six IGCC cases. Chapter 4 describes the PC technologies modeled and presents the results for the four PC cases. Chapter 5 described the NGCC technologies modeled and presents the results for the two NGCC cases. Chapter 6 contains the reference list. 64 refs., 253 exhibits.

  4. Hydrogen Separation Membranes for Vision 21 Fossil Fuel Plants

    SciTech Connect

    Roark, Shane E.; Mackay, Richard; Sammells, Anthony F.

    2001-11-06

    Eltron Research and team members CoorsTek, McDermott Technology, Sued Chemie, Argonne National Laboratory, and Oak Ridge National Laboratory are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying single-phase and composite membrane composition and microstructure to maximize proton and electron conductivity without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. This project was motivated by the Department of Energy (DOE) National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. The proposed technology addresses the DOE Vision 21 initiative in two ways. First, this process offers a relatively inexpensive solution for pure hydrogen separation that can be easily incorporated into Vision 21 fossil fuel plants. Second, this process could reduce the cost of hydrogen, which is a clean burning fuel under increasing demand as supporting technologies are developed for hydrogen utilization and storage. Additional motivation for this project arises from the potential of this technology for other applications. By appropriately changing the catalysts coupled with the membrane, essentially the same system can be used to facilitate alkane dehydrogenation and coupling, aromatics processing, and hydrogen sulfide decomposition.

  5. Compound hybrid geothermal-fossil power plants - Thermodynamic analyses and site-specific applications

    NASA Astrophysics Data System (ADS)

    Dipippo, R.; Kestin, J.; Avelar, E. M.; Khalifa, H. E.

    1980-02-01

    In this paper, we extend the analysis of hybrid fossil-geothermal power plants to compound systems which combine the features of the two previously analyzed hybrid plants, the geothermal preheat and the fossil superheat systems. Compound systems of the one- and two-stage type are considered. A complete summary of formulae to assess the performance of the plants is included for completeness. From the viewpoint of thermodynamics, compound hybrid plants are superior to individual all-geothermal and all-fossil plants, and have certain advantages over basic geothermal-preheat and fossil-superheat hybrid plants. The flexibility of compound hybrid systems is illustrated by showing how such plants might be used at several geothermal sites in the western United States.

  6. Specification for integrated controls and monitoring for fossil power plants

    SciTech Connect

    McKinley, J.H.; Papilla, R.P.; Shendrikar, U.D. )

    1991-06-01

    This specification was prepared by Southern California Edison Co. and used to bid the contract for a state-of-the-art integrated control and monitoring system for the El Segundo control system retrofit project. The system will be installed on Units 3 and 4 during a 12 week scheduled outage beginning in January, 1991. Since early 1989, EPRI has been cost sharing this project with SCE under research project RP2922-2. This specification is one of seven supplemental EPRI reports that will be generated from the project besides interim and final guidelines for integrated controls and monitoring for fossil power plants. The specification is a first-of-a-kind, requiring bidders to apply enhanced control logic and advanced control algorithms, and integrate various diagnostic, expert systems, performance monitoring, and other condition monitoring applications with a DCS. The proof of the quality and comprehensiveness of this specification is apparent as the project moves forward with only a few months before system delivery: There are few issues that have had to be addressed separately from the specification. The information contained in this report should be useful for any utility launching a control system upgrade project.

  7. Infrared imaging of fossil fuel power plant boiler interiors

    NASA Astrophysics Data System (ADS)

    Howard, James W.; Cranton, Brian W.; Armstrong, Karen L.; Hammaker, Robert G.

    1997-08-01

    Fossil fuel power plant boilers operate continuously for months at a time, typically shutting down only for routine maintenance or to address serious equipment failures. These shutdowns are very costly, and diagnostic tools and techniques which could be used to minimize shutdown duration and frequency are highly desirable. Due to the extremely hostile environment in these boilers, few tools exist to inspect and monitor operating boiler interiors. This paper presents the design of a passively cooled, infrared borescope used to inspect the interior of operating boilers. The borescope operates at 3.9 micrometer, where flame is partially transparent. The primary obstacles overcome in the instrument design were the harsh industrial environment surrounding the boilers and the high temperatures encountered inside the boilers. A portable yet durable lens system and enclosure was developed to work with a scanning radiometer to address these two problems by both shielding the radiometer from the environment and by extending the optical train into a snout designed to be inserted into access ports on the sides of the boiler. In this manner, interior images of the boiler can be made while keeping the radiometer safely outside the boiler. The lens views a 40 degree field of view through any 2.5' or larger opening in a foot thick boiler wall. Three of these borescopes have been built, and high resolution images of boiler interiors have been obtained.

  8. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUEL PLANTS

    SciTech Connect

    Shane E. Roark; Tony F. Sammells; Adam Calihman; Andy Girard; Pamela M. Van Calcar; Richard Mackay; Tom Barton; Sara Rolfe

    2001-01-30

    Eltron Research Inc., and team members CoorsTek, McDermott Technology, Inc., Sued Chemie, Argonne National Laboratory, and Oak Ridge National Laboratory are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying single-phase and composite membrane composition and microstructure to maximize proton and electron conductivity without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. The proposed technology addresses the DOE Vision 21 initiative in two ways. First, this process offers a relatively inexpensive solution for pure hydrogen separation that can be easily incorporated into Vision 21 fossil fuel plants. Second, this process could reduce the cost of hydrogen, which is a clean burning fuel under increasing demand as supporting technologies are developed for hydrogen utilization and storage. Additional motivation for this project arises from the potential of this technology for other applications. Membranes testing during this reporting period were greater than 1 mm thick and had the general perovskite composition AB{sub 1-x}B'{sub x}O{sub 3-{delta}}, where 0.05 {<=} x {<=} 0.3. These materials demonstrated hydrogen separation rates between 1 and 2 mL/min/cm{sup 2}, which represents roughly 20% of the target goal for

  9. [Lipids from fossil plants and their relation to modern plants. Example s of Cenomanian flora from Anjou and Bohemia].

    PubMed

    Thanh, T N; Derenne, S; Largeau, C; Pons, D; Broutin, J; Mariotti, A; Bocherens, H

    2000-01-01

    Comparative analyses of lipids from fossil plants and from their extant counterparts were undertaken in order to test the taxonomic significance of lipids in palaeobotany. The comparison between lipids from a fossil Ginkgoaceae, Eretmophyllum andegavense, and its extant counterpart, Ginkgo biloba, revealed the presence of original molecules, dimethoxyalkylcoumarins, in lipids from both plants. Such compounds confirm, on chemical grounds the relationship between these extant and fossil Ginkgoaceaes. Moreover, differences in n-alkane distribution between E. andegavense and E. obtusum which are very similar morphologically, confirm that these fossil plants do not belong to the same species. Furthermore, comparative analyses of a fossil Cheirolepidiaceae, Frenelopsis alata, and its extant counterpart, the Cupressaceae Tetraclinis articulata, revealed some similarities between these two species although they do not belong to the same family. Otherwise, comparative analyses of fungi-infected and uninfected samples of F. alata demonstrated that these micro-organisms can significantly affect the chemical composition of fossil plant lipids. In conclusion, even if chemical analyses alone are not sufficient to determine the genus or species of a given fossil plant, they can precise the taxonomy of some specimens that have been previously studied by palaeobotanists.

  10. Fossil organic carbon in wastewater and its fate in treatment plants.

    PubMed

    Law, Yingyu; Jacobsen, Geraldine E; Smith, Andrew M; Yuan, Zhiguo; Lant, Paul

    2013-09-15

    This study reports the presence of fossil organic carbon in wastewater and its fate in wastewater treatment plants. The findings pinpoint the inaccuracy of current greenhouse gas accounting guidelines which defines all organic carbon in wastewater to be of biogenic origin. Stable and radiocarbon isotopes ((13)C and (14)C) were measured throughout the process train in four municipal wastewater treatment plants equipped with secondary activated sludge treatment. Isotopic mass balance analyses indicate that 4-14% of influent total organic carbon (TOC) is of fossil origin with concentrations between 6 and 35 mg/L; 88-98% of this is removed from the wastewater. The TOC mass balance analysis suggests that 39-65% of the fossil organic carbon from the influent is incorporated into the activated sludge through adsorption or from cell assimilation while 29-50% is likely transformed to carbon dioxide (CO2) during secondary treatment. The fossil organic carbon fraction in the sludge undergoes further biodegradation during anaerobic digestion with a 12% decrease in mass. 1.4-6.3% of the influent TOC consists of both biogenic and fossil carbon is estimated to be emitted as fossil CO2 from activated sludge treatment alone. The results suggest that current greenhouse gas accounting guidelines, which assume that all CO2 emission from wastewater is biogenic may lead to underestimation of emissions.

  11. Changes in dominance patterns in upper Carboniferous plant-fossil assemblages

    NASA Astrophysics Data System (ADS)

    Pfefferkorn, Hermann W.; Thomson, Margaret C.

    1982-12-01

    Upper Carboniferous (Pennsylvanian) terrestrial clastic rocks from North America and Europe contain compression-impression plant-fossil assemblages that represent the remains of plant communities that grew on floodplains, levees, and other clastic facies of fluvial and deltaic lowlands. Quantitative analysis of 66 plant-fossil assemblages spanning the entire late Carboniferous demonstrates that before the middle of the Westphalian D Stage the majority of plant-fossil assemblages are dominated by pteridosperms and sphenopsids. Lycopods and cordaites dominate only a few assemblages counted. Ferns do not dominate any assemblages. These findings contrast sharply with the dominance of lycopods reported by others from coal swamps of the same time interval. Above the middle of the Westphalian D, however, one-third of the compression-impression assemblages counted are dominated by ferns. The change in dominance pattern in compression-impression plant-fossil assemblages occurs half a stage earlier than the previously reported change from lycopod-dominated to fern-dominated assemblages at the Westphalian-Stephanian boundary in coal swamps. A trend toward dryer climate during Westphalian D apparently influenced plants growing on better-drained alluvial soils earlier than those growing on water-logged soils of contemporaneous coal swamps. *Present address: Room 108 Math.-Geology Building, University of Minnesota, Duluth, Minnesota 55812

  12. Advanced Hydrogen Transport Membranes for Vision 21 Fossil Fuel Plants

    SciTech Connect

    Carl R. Evenson; Richard N. Kleiner; James E. Stephan; Frank E. Anderson

    2006-04-30

    Eltron Research Inc. and team members CoorsTek, Sued Chemie, Argonne National Laboratory, and NORAM are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative, which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. Currently, this project is focusing on four basic categories of dense membranes: (1) mixed conducting ceramic/ceramic composites, (2) mixed conducting ceramic/metal (cermet) composites, (3) cermets with hydrogen permeable metals, and (4) layered composites containing hydrogen permeable alloys. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. During this final quarter of the no cost extension several planar membranes of a cermet composition referred to as EC101 containing a high permeability metal and a ceramic phase were prepared and permeability testing was performed.

  13. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUELS PLANTS

    SciTech Connect

    Shane E. Roark; Anthony F. Sammells; Richard Mackay; Stewart Schesnack; Scott Morrison; Thomas A. Zirbel; Thomas F. Barton; Sara L. Rolfe; U. Balachandran; Richard N. Kleiner; James E. Stephan; Frank E. Anderson; Aaron L. Wagner; Jon P. Wagner

    2003-07-31

    Eltron Research Inc. and team members CoorsTek, Sued Chemie, and Argonne National Laboratory are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative, which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. Currently, this project is focusing on four basic categories of dense membranes: (1) mixed conducting ceramic/ceramic composites, (2) mixed conducting ceramic/metal (cermet) composites, (3) cermets with hydrogen permeable metals, and (4) layered composites containing hydrogen permeable alloys. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. This report presents hydrogen permeation data during long term tests and tests at high pressure in addition to progress with cermet, ceramic/ceramic, and thin film membranes.

  14. The Fossil Record of Plant-Insect Dynamics

    NASA Astrophysics Data System (ADS)

    Labandeira, Conrad C.; Currano, Ellen D.

    2013-05-01

    Progress toward understanding the dynamics of ancient plant-insect associations has addressed major patterns in the ecology and evolution of herbivory and pollination. This advancement involves development of more analytical ways of describing plant-insect associational patterns in time and space and an assessment of the role that the environment and internal biological processes have in their control. Current issues include the deep origins of terrestrial herbivory, the spread of herbivory across late Paleozoic landscapes, recoveries from sudden major crises, reaction to and accommodation of protracted environmental perturbations, and the nature of herbivory and pollination before the appearance of angiosperms during the mid-Mesozoic. These and other exploratory research themes provide a more complete account of a great nexus of ecological activity that has been wedged between the two most diverse organismic groups on land for the past 410 million years.

  15. Atmospheric benzenoid emissions from plants rival those from fossil fuels.

    PubMed

    Misztal, P K; Hewitt, C N; Wildt, J; Blande, J D; Eller, A S D; Fares, S; Gentner, D R; Gilman, J B; Graus, M; Greenberg, J; Guenther, A B; Hansel, A; Harley, P; Huang, M; Jardine, K; Karl, T; Kaser, L; Keutsch, F N; Kiendler-Scharr, A; Kleist, E; Lerner, B M; Li, T; Mak, J; Nölscher, A C; Schnitzhofer, R; Sinha, V; Thornton, B; Warneke, C; Wegener, F; Werner, C; Williams, J; Worton, D R; Yassaa, N; Goldstein, A H

    2015-07-13

    Despite the known biochemical production of a range of aromatic compounds by plants and the presence of benzenoids in floral scents, the emissions of only a few benzenoid compounds have been reported from the biosphere to the atmosphere. Here, using evidence from measurements at aircraft, ecosystem, tree, branch and leaf scales, with complementary isotopic labeling experiments, we show that vegetation (leaves, flowers, and phytoplankton) emits a wide variety of benzenoid compounds to the atmosphere at substantial rates. Controlled environment experiments show that plants are able to alter their metabolism to produce and release many benzenoids under stress conditions. The functions of these compounds remain unclear but may be related to chemical communication and protection against stress. We estimate the total global secondary organic aerosol potential from biogenic benzenoids to be similar to that from anthropogenic benzenoids (~10 Tg y(-1)), pointing to the importance of these natural emissions in atmospheric physics and chemistry.

  16. Atmospheric benzenoid emissions from plants rival those from fossil fuels

    PubMed Central

    Misztal, P.K.; Hewitt, C.N.; Wildt, J.; Blande, J.D.; Eller, A.S.D.; Fares, S.; Gentner, D.R.; Gilman, J.B.; Graus, M.; Greenberg, J.; Guenther, A.B.; Hansel, A.; Harley, P.; Huang, M.; Jardine, K.; Karl, T.; Kaser, L.; Keutsch, F.N.; Kiendler-Scharr, A.; Kleist, E.; Lerner, B.M.; Li, T.; Mak, J.; Nölscher, A.C.; Schnitzhofer, R.; Sinha, V.; Thornton, B.; Warneke, C.; Wegener, F.; Werner, C.; Williams, J.; Worton, D.R.; Yassaa, N.; Goldstein, A.H.

    2015-01-01

    Despite the known biochemical production of a range of aromatic compounds by plants and the presence of benzenoids in floral scents, the emissions of only a few benzenoid compounds have been reported from the biosphere to the atmosphere. Here, using evidence from measurements at aircraft, ecosystem, tree, branch and leaf scales, with complementary isotopic labeling experiments, we show that vegetation (leaves, flowers, and phytoplankton) emits a wide variety of benzenoid compounds to the atmosphere at substantial rates. Controlled environment experiments show that plants are able to alter their metabolism to produce and release many benzenoids under stress conditions. The functions of these compounds remain unclear but may be related to chemical communication and protection against stress. We estimate the total global secondary organic aerosol potential from biogenic benzenoids to be similar to that from anthropogenic benzenoids (~10 Tg y−1), pointing to the importance of these natural emissions in atmospheric physics and chemistry. PMID:26165168

  17. Atmospheric benzenoid emissions from plants rival those from fossil fuels

    NASA Astrophysics Data System (ADS)

    Misztal, P. K.; Hewitt, C. N.; Wildt, J.; Blande, J. D.; Eller, A. S. D.; Fares, S.; Gentner, D. R.; Gilman, J. B.; Graus, M.; Greenberg, J.; Guenther, A. B.; Hansel, A.; Harley, P.; Huang, M.; Jardine, K.; Karl, T.; Kaser, L.; Keutsch, F. N.; Kiendler-Scharr, A.; Kleist, E.; Lerner, B. M.; Li, T.; Mak, J.; Nölscher, A. C.; Schnitzhofer, R.; Sinha, V.; Thornton, B.; Warneke, C.; Wegener, F.; Werner, C.; Williams, J.; Worton, D. R.; Yassaa, N.; Goldstein, A. H.

    2015-07-01

    Despite the known biochemical production of a range of aromatic compounds by plants and the presence of benzenoids in floral scents, the emissions of only a few benzenoid compounds have been reported from the biosphere to the atmosphere. Here, using evidence from measurements at aircraft, ecosystem, tree, branch and leaf scales, with complementary isotopic labeling experiments, we show that vegetation (leaves, flowers, and phytoplankton) emits a wide variety of benzenoid compounds to the atmosphere at substantial rates. Controlled environment experiments show that plants are able to alter their metabolism to produce and release many benzenoids under stress conditions. The functions of these compounds remain unclear but may be related to chemical communication and protection against stress. We estimate the total global secondary organic aerosol potential from biogenic benzenoids to be similar to that from anthropogenic benzenoids (~10 Tg y-1), pointing to the importance of these natural emissions in atmospheric physics and chemistry.

  18. Atmospheric benzenoid emissions from plants rival those from fossil fuels

    DOE PAGES

    Misztal, P. K.; Hewitt, C. N.; Wildt, J.; Blande, J. D.; Eller, A. S.D.; Fares, S.; Gentner, D. R.; Gilman, J. B.; Graus, M.; Greenberg, J.; et al

    2015-07-13

    Despite the known biochemical production of a range of aromatic compounds by plants and the presence of benzenoids in floral scents, the emissions of only a few benzenoid compounds have been reported from the biosphere to the atmosphere. Here, using evidence from measurements at aircraft, ecosystem, tree, branch and leaf scales, with complementary isotopic labeling experiments, we show that vegetation (leaves, flowers, and phytoplankton) emits a wide variety of benzenoid compounds to the atmosphere at substantial rates. Controlled environment experiments show that plants are able to alter their metabolism to produce and release many benzenoids under stress conditions. The functionsmore » of these compounds remain unclear but may be related to chemical communication and protection against stress. We estimate the total global secondary organic aerosol potential from biogenic benzenoids to be similar to that from anthropogenic benzenoids (~10 Tg y-1), pointing to the importance of these natural emissions in atmospheric physics and chemistry.« less

  19. Atmospheric benzenoid emissions from plants rival those from fossil fuels

    SciTech Connect

    Misztal, P. K.; Hewitt, C. N.; Wildt, J.; Blande, J. D.; Eller, A. S.D.; Fares, S.; Gentner, D. R.; Gilman, J. B.; Graus, M.; Greenberg, J.; Guenther, A. B.; Hansel, A.; Harley, P.; Huang, M.; Jardine, K.; Karl, T.; Kaser, L.; Keutsch, F. N.; Kiendler-Scharr, A.; Kleist, E.; Lerner, B. M.; Li, T.; Mak, J.; Nölscher, A. C.; Schnitzhofer, R.; Sinha, V.; Thornton, B.; Warneke, C.; Wegener, F.; Werner, C.; Williams, J.; Worton, D. R.; Yassaa, N.; Goldstein, A. H.

    2015-07-13

    Despite the known biochemical production of a range of aromatic compounds by plants and the presence of benzenoids in floral scents, the emissions of only a few benzenoid compounds have been reported from the biosphere to the atmosphere. Here, using evidence from measurements at aircraft, ecosystem, tree, branch and leaf scales, with complementary isotopic labeling experiments, we show that vegetation (leaves, flowers, and phytoplankton) emits a wide variety of benzenoid compounds to the atmosphere at substantial rates. Controlled environment experiments show that plants are able to alter their metabolism to produce and release many benzenoids under stress conditions. The functions of these compounds remain unclear but may be related to chemical communication and protection against stress. We estimate the total global secondary organic aerosol potential from biogenic benzenoids to be similar to that from anthropogenic benzenoids (~10 Tg y-1), pointing to the importance of these natural emissions in atmospheric physics and chemistry.

  20. Atmospheric benzenoid emissions from plants rival those from fossil fuels.

    PubMed

    Misztal, P K; Hewitt, C N; Wildt, J; Blande, J D; Eller, A S D; Fares, S; Gentner, D R; Gilman, J B; Graus, M; Greenberg, J; Guenther, A B; Hansel, A; Harley, P; Huang, M; Jardine, K; Karl, T; Kaser, L; Keutsch, F N; Kiendler-Scharr, A; Kleist, E; Lerner, B M; Li, T; Mak, J; Nölscher, A C; Schnitzhofer, R; Sinha, V; Thornton, B; Warneke, C; Wegener, F; Werner, C; Williams, J; Worton, D R; Yassaa, N; Goldstein, A H

    2015-01-01

    Despite the known biochemical production of a range of aromatic compounds by plants and the presence of benzenoids in floral scents, the emissions of only a few benzenoid compounds have been reported from the biosphere to the atmosphere. Here, using evidence from measurements at aircraft, ecosystem, tree, branch and leaf scales, with complementary isotopic labeling experiments, we show that vegetation (leaves, flowers, and phytoplankton) emits a wide variety of benzenoid compounds to the atmosphere at substantial rates. Controlled environment experiments show that plants are able to alter their metabolism to produce and release many benzenoids under stress conditions. The functions of these compounds remain unclear but may be related to chemical communication and protection against stress. We estimate the total global secondary organic aerosol potential from biogenic benzenoids to be similar to that from anthropogenic benzenoids (~10 Tg y(-1)), pointing to the importance of these natural emissions in atmospheric physics and chemistry. PMID:26165168

  1. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUEL PLANTS

    SciTech Connect

    Shane E. Roark; Anthony F. Sammells; Richard Mackay; Stewart R. Schesnack; Scott R. Morrison; Thomas F. Barton; Sara L. Rolfe; U. Balachandran; Richard N. Kleiner; James E. Stephan; Frank E. Anderson; Aaron L. Wagner; Jon P. Wagner

    2003-10-30

    Eltron Research Inc. and team members CoorsTek, Sued Chemie, Argonne National Laboratory, and NORAM are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative, which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. Over the past 12 months, this project has focused on four basic categories of dense membranes: (1) mixed conducting ceramic/ceramic composites, (2) mixed conducting ceramic/metal (cermet) composites, (3) cermets with hydrogen permeable metals, and (4) layered composites containing hydrogen permeable alloys. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. The ceramic/ceramic composites demonstrate the lowest hydrogen permeation rates, with a maximum of approximately 0.1 mL/min/cm{sup 2} for 0.5-mm thick membranes at 800 to 950 C. Under equivalent conditions, cermets achieve a hydrogen permeation rate near 1 mL/min/cm{sup 2}, and the metal phase also improves structural stability and surface catalysis for hydrogen dissociation. Furthermore, if metals with high hydrogen permeability are used in cermets, permeation rates near 4 mL/min/cm{sup 2} are achievable with relatively thick membranes. Layered composite membranes have by far the highest permeation rates with a maximum flux in excess of 200 mL {center_dot} min{sup -1} {center_dot} cm{sup -2}. Moreover, these permeation rates were achieved at a total pressure differential across the membrane of 450 psi. Based on these results, effort during the next year will focus on this category of membranes. This report contains long-term hydrogen permeation data over eight

  2. Perspective on fossil power plant layup and reactivation

    SciTech Connect

    Tsou, J.L.

    1996-12-31

    In recent years, many utilities have developed excess generation capacity problems during period of low system load growth, particularly with new generation units coming on-line. System load studies may indicate that the situation is temporary and higher generation capacity will be needed in the near future. The objective of layup is to prevent component deterioration during the long shut down periods. This paper discusses equipment preservation practices in use by the electric utility industry and the advantages/disadvantages of various layup methods. Other issues related to plant layup and reactivation are also presented.

  3. INNOVATIVE FRESH WATER PRODUCTION PROCESS FOR FOSSIL FUEL PLANTS

    SciTech Connect

    James F. Klausner; Renwei Mei; Yi Li; Mohamed Darwish; Diego Acevedo; Jessica Knight

    2003-09-01

    This report describes the annual progress made in the development and analysis of a Diffusion Driven Desalination (DDD) system, which is powered by the waste heat from low pressure condensing steam in power plants. The desalination is driven by water vapor saturating dry air flowing through a diffusion tower. Liquid water is condensed out of the air/vapor mixture in a direct contact condenser. A thermodynamic analysis demonstrates that the DDD process can yield a fresh water production efficiency of 4.5% based on a feed water inlet temperature of only 50 C. An example is discussed in which the DDD process utilizes waste heat from a 100 MW steam power plant to produce 1.51 million gallons of fresh water per day. The main focus of the initial development of the desalination process has been on the diffusion tower. A detailed mathematical model for the diffusion tower has been described, and its numerical implementation has been used to characterize its performance and provide guidance for design. The analysis has been used to design a laboratory scale diffusion tower, which has been thoroughly instrumented to allow detailed measurements of heat and mass transfer coefficient, as well as fresh water production efficiency. The experimental facility has been described in detail.

  4. INNOVATIVE FRESH WATER PRODUCTION PROCESS FOR FOSSIL FUEL PLANTS

    SciTech Connect

    James F. Klausner; Renwei Mei; Yi Li; Jessica Knight

    2004-09-01

    An innovative Diffusion Driven Desalination (DDD) process was recently described where evaporation of mineralized water is driven by diffusion within a packed bed. The energy source to drive the process is derived from low pressure condensing steam within the main condenser of a steam power generating plant. Since waste heat is used to drive the process, the main cost of fresh water production is attributed to the energy cost of pumping air and water through the packed bed. This report describes the annual progress made in the development and analysis of a Diffusion Driven Desalination (DDD) system. A combined thermodynamic and dynamic analysis demonstrates that the DDD process can yield a fresh water production of 1.03 million gallon/day by utilizing waste heat from a 100 MW steam power plant based on a condensing steam pressure of only 3'' Hg. Throughout the past year, the main focus of the desalination process has been on the diffusion tower and direct contact condenser. Detailed heat and mass transfer analyses required to size and analyze these heat and mass transfer devices are described. An experimental DDD facility has been fabricated, and temperature and humidity data have been collected over a range of flow and thermal conditions. The analyses agree quite well with the current data and the information available in the literature. Direct contact condensers with and without packing have been investigated. It has been experimentally observed that the fresh water production rate is significantly enhanced when packing is added to the direct contact condensers.

  5. Neural networks for control of NO{sub x} emissions in fossil plants

    SciTech Connect

    Reifman, J.; Feldman, E.E.

    1997-04-01

    We discuss the use of two classes of artificial neural networks, multilayer feedforward networks and fully-recurrent networks, in the development of a closed-loop controller for discrete-time dynamical systems. We apply the neural system to the control of oxides of nitrogen (NO{sub x}) emissions for a simplified representation of a furnace of a coal-fired fossil plant. Plant data from one of Commonwealth Edison`s fossil power plants were used to build a recurrent neural model of NO{sub x} formation which is then used in the training of the feedforward neural controller. Preliminary simulation results demonstrate the feasibility of the approach and additional tests with increasingly realistic models should be pursued.

  6. Innovative Fresh Water Production Process for Fossil Fuel Plants

    SciTech Connect

    James F. Klausner; Renwei Mei; Yi Li; Jessica Knight; Venugopal Jogi

    2005-09-01

    This project concerns a diffusion driven desalination (DDD) process where warm water is evaporated into a low humidity air stream, and the vapor is condensed out to produce distilled water. Although the process has a low fresh water to feed water conversion efficiency, it has been demonstrated that this process can potentially produce low cost distilled water when driven by low grade waste heat. This report describes the annual progress made in the development and analysis of a Diffusion Driven Desalination (DDD) system. A dynamic analysis of heat and mass transfer demonstrates that the DDD process can yield a fresh water production of 1.03 million gallon/day by utilizing waste heat from a 100 MW steam power plant based on a condensing steam pressure of only 3 Hg. The optimum operating condition for the DDD process with a high temperature of 50 C and sink temperature of 25 C has an air mass flux of 1.5 kg/m{sup 2}-s, air to feed water mass flow ratio of 1 in the diffusion tower, and a fresh water to air mass flow ratio of 2 in the condenser. Operating at these conditions yields a fresh water production efficiency (m{sub fW}/m{sub L}) of 0.031 and electric energy consumption rate of 0.0023 kW-hr/kg{sub fW}. Throughout the past year, the main focus of the desalination process has been on the direct contact condenser. Detailed heat and mass transfer analyses required to size and analyze these heat and mass transfer devices are described. The analyses agree quite well with the current data. Recently, it has been recognized that the fresh water production efficiency can be significantly enhanced with air heating. This type of configuration is well suited for power plants utilizing air-cooled condensers. The experimental DDD facility has been modified with an air heating section, and temperature and humidity data have been collected over a range of flow and thermal conditions. It has been experimentally observed that the fresh water production rate is enhanced when air

  7. Advanced Hydrogen Transport Membranes for Vision 21 Fossil Fuel Plants

    SciTech Connect

    Carl R. Evenson; Shane E. Roark

    2006-03-31

    The objective of this project was to develop an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. A family of hydrogen separation membranes was developed including single phase mixed conducting ceramics, ceramic/ceramic composites, cermet membranes, cermet membranes containing a hydrogen permeable metal, and intermediate temperature composite layered membranes. Each membrane type had different operating parameters, advantages, and disadvantages that were documented over the course of the project. Research on these membranes progressed from ceramics to cermets to intermediate temperature composite layered membranes. During this progression performance was increased from 0.01 mL x min{sup -1} x cm{sup -2} up to 423 mL x min{sup -1} x cm{sup -2}. Eltron and team membranes not only developed each membrane type, but also membrane surface catalysis and impurity tolerance, creation of thin film membranes, alternative applications such as membrane promoted alkane dehydrogenation, demonstration of scale-up testing, and complete engineering documentation including process and mechanical considerations necessary for inclusion of Eltron membranes in a full scale integrated gasification combined cycle power plant. The results of this project directly led to a new $15 million program funded by the Department of Energy. This new project will focus exclusively on scale-up of this technology as part of the FutureGen initiative.

  8. New martensitic steels for fossil power plant: Creep resistance

    NASA Astrophysics Data System (ADS)

    Kaybyshev, R. O.; Skorobogatykh, V. N.; Shchenkova, I. A.

    2010-02-01

    In this paper, we consider the origin of high-temperature strength of heat-resistant steels belonging to martensitic class developed on the basis of the Fe—9%Cr alloy for the boiler pipes and steam pipelines of power plants at steam temperatures of up to 620°C and pressures to 300 atm. In addition, we give a brief information on the physical processes that determine the creep strength and consider the alloying philosophy of traditional heat-resistant steels. The effect of the chemical and phase composition of heat-resistant steels and their structure on creep strength is analyzed in detail. It is shown that the combination of the solid-solution alloying by elements such as W and Mo, as well as the introduction of carbides of the MX type into the matrix with the formation of a dislocation structure of tempered martensite, ensures a significant increase in creep resistance. The steels of the martensitic class withstand creep until an extensive polygonization starts in the dislocation structure of the tempered martensite(“troostomartensite”), which is suppressed by V(C,N) and Nb(C,N) dispersoids. Correspondingly, the service life of these steels is determined by the time during which the dispersed nanocarbonitrides withstand coalescence, while tungsten and molybdenum remain in the solid solution. The precipitation of the Laves phases Fe2(W,Mo) and the coalescence of carbides lead to the development of migration of low-angle boundaries, and the steel loses its ability to resist creep.

  9. Recurrent neural networks for NO{sub x} prediction in fossil plants

    SciTech Connect

    Reifman, J.; Vitela, J.E.; Feldman, E.E.; Wei, T.Y.C.

    1996-04-01

    The authors discuss the application of recurrent (dynamic) neural networks for time-dependent modeling of NO{sub x} emissions in coal-fired fossil plants. They use plant data from one of ComEd`s plants to train and test the network model. Additional tests, parametric studies, and sensitivity analyses are performed to determine if the dynamic behavior of the model matches the expected behavior of the physical system. The results are also compared with feedforward (static) neural network models trained to represent temporal information.

  10. Evaluation of innovative fossil fuel power plants with CO{sub 2} removal

    SciTech Connect

    2000-07-15

    This interim report presents initial results of an ongoing study of the potential cost of electricity produced in both conventional and innovative fossil fueled power plants that incorporate carbon dioxide (CO{sub 2}) removal for subsequent sequestration or use. The baseline cases are natural gas combined cycle (NGCC) and ultra-supercritical pulverized coal (PC) plants, with and without post combustion CO{sub 2} removal, and integrated gasification combined cycle (IGCC) plants, with and without pre-combustion CO{sub 2} removal.

  11. Environmental review for the conversion of Bellefonte Nuclear Plant to fossil fuel

    SciTech Connect

    Carter, R.; Rucker, H.; Summers, R.

    1998-07-01

    The Tennessee Valley Authority recently issued for public review a Draft Environmental Impact Statement for the conversion of the unfinished Bellefonte Nuclear Plant to fossil fuel. The DEIS was structured to support three tiers of decision making. Tier 1 is to decide between the No-Action Alternative, which is to leave Bellefonte as a partially completed nuclear plant into the indefinite future, and the Proposed Action Alternative, which is to proceed with converting Bellefonte to fossil fuel. Tier 2 is to select one of five conversion options. In the DEIS, TVA indicated no preference among the five competing fossil conversion options. The five conversion pathways would fully repower the plant consistent with fossil fuel availability, would use commercially ready systems and technologies and be designed to fully utilize the capacity of transmission lines serving Bellefonte. Conversion options addressed were pulverized coal (PC), natural gas combined cycle (NGCC), integrated gasification combined cycle (IGCC), IGCC with joint production of electricity and chemicals, and an option, which combines elements of NGCC and IGCC with coproduction. Tier 3 involves decisions about eight sub-option choices, basically types of processes, equipment, and modes of operation, which is part of two or more conversion options. An example of a sub-option choice would be the type of gasifier that would be used in conversion options involving coal or petroleum coke gasification. Other sub-option choices addressed in the DEIS were natural gas pipeline corridors; fuels, feedstocks, and by-products transportation modes; types of combustion turbines; solid fuels; types of boilers for conventional coal-fired options; chemical production mixes; and modes of onsite solid fuel conveyance. The impact of constructing and operating each proposed fossil conversion option at Bellefonte were evaluated for 18 environmental resource and economic categories.

  12. Energy-efficient air pollution controls for fossil-fueled plants: Technology assessment

    SciTech Connect

    Sayer, J.H.

    1995-06-01

    The 1990 Clean Air Act Amendments require most fossil-fuel fired power plants to reduce sulfur dioxide, nitrogen oxides, and particulate emissions. While emission-control equipment is available to help most of New York State`s 91 utility units in 31 power plants comply with the new regulations, technologies currently available consume energy, increase carbon dioxide emissions, reduce operating efficiency, and may produce large amounts of solid and/or semisolid byproducts that use additional energy for processing and disposal. This report discribes several pollution-control technologies that are more energy efficient compared to traditional technologies for controlling sulfur dioxide, nitrogen oxide, and particulates, that may have application in New York State. These technologies are either in commercial use, under development, or in the demonstration phase; This report also presents operating characteristics for these technologies and discusses solutions to dispose of pollution-control system byproducts. Estimated energy consumption for emission-control systems relative to a plant`s gross generating capacity is 3 to 5 for reducing up to 90% sulfur dioxide emissions from coal-fired plants. 0.5 to 2.5% for reducing nitrogen oxide emissions by up to 80% from all fossil-fuel fired plants; and 0.5 to 1.5 % for controlling particulate emissions from oil- and coal-fired plants. While fuel switching and/or cofiring with natural gas are options to reduce emissions, these techniques are not considered in this report; the discussion is limited to fossil-fueled steam-generating plants.

  13. Do fossil plants signal palaeoatmospheric carbon dioxide concentration in the geological past?

    PubMed Central

    McElwain, J. C.

    1998-01-01

    Fossil, subfossil, and herbarium leaves have been shown to provide a morphological signal of the atmospheric carbon dioxide environment in which they developed by means of their stomatal density and index. An inverse relationship between stomatal density/index and atmospheric carbon dioxide concentration has been documented for all the studies to date concerning fossil and subfossil material. Furthermore, this relationship has been demonstrated experimentally by growing plants under elevated and reducedcarbon dioxide concentrations. To date, the mechanism that controls the stomatal density response to atmospheric carbon dioxide concentration remains unknown. However, stomatal parameters of fossil plants have been successfully used as a proxy indicator of palaeo-carbon dioxide levels. This paper presents new estimates of palaeo-atmospheric carbon dioxide concentrations for the Middle Eocene (Lutetian), based on the stomatal ratios of fossil Lauraceae species from Bournemouth in England. Estimates of atmospheric carbon dioxide concentrations derived from stomatal data from plants of the Early Devonian, Late Carboniferous, Early Permian and Middle Jurassic ages are reviewed in the light of new data. Semi-quantitative palaeo-carbon dioxide estimates based on the stomatal ratio (a ratio of the stomatal index of a fossil plant to that of a selected nearest living equivalent) have in the past relied on the use of a Carboniferous standard. The application of a new standard based on the present-day carbon dioxide level is reported here for comparison. The resultant ranges of palaeo-carbon dioxide estimates made from standardized fossil stomatal ratio data are in good agreement with both carbon isotopic data from terrestrial and marine sources and long-term carbon cycle modelling estimates for all the time periods studied. These data indicate elevated atmospheric carbon dioxide concentrations during the Early Devonian, Middle Jurassic and Middle Eocene, and reduced

  14. Paleoclimate from fossil plants and application to the early Cenozoic Rocky Mountains

    NASA Astrophysics Data System (ADS)

    Wing, S. L.

    2011-12-01

    Wladimir Köppen called vegetation "crystallized, visible climate," and his metaphor encouraged paleobotanists to climb the chain of inference from fossil plants to paleovegetation to paleoclimate. Inferring paleovegetation from fossils has turned out to be very difficult, however, and today most paleobotanical methods for inferring paleoclimate do not try to reconstruct paleovegetation as a first step. Three major approaches are widely use to infer paleoclimate from plant fossils: 1) phylogenetic inferences rely on the climatic distributions of extant relatives of fossils, 2) morphological inferences use present-day correlations of climate with plant morphology (e.g, leaf shape, wood anatomy), and 3) chemical inferences rely on correlations between climate and the stable isotopic composition of plants or organic compounds. Each approach makes assumptions that are hard to verify. Phylogenetic inference depends on accurate identification of fossils, and also assumes that evolution and/or extinction has not shifted the climatic distributions of plant lineages through time. On average this assumption is less valid for older time periods, but probably it is not radically wrong for the early Cenozoic. Morphological approaches don't require taxonomic identification of plant fossils, but do assume that correlations between plant form and climate have been constant over time. This assumption is bolstered if the ecophysiological cause of the morphology-climate correlation is well understood, but often it isn't. Stable isotopic approaches assume that present-day correlations between isotopic composition and climate apply to the past. Commonly the chemical and physiological mechanisms responsible for the correlation are moderately well known, but often the variation among different taxonomic and functional groups of plants is poorly characterized. In spite of limitations and uncertainties on all methods for inferring paleoclimate from fossil plants, broad patterns emerge from

  15. Potentially carcinogenic species emitted to the atmosphere by fossil-fueled power plants.

    PubMed Central

    Natusch, D F

    1978-01-01

    The identities and physicochemical characteristics of potentially carcinogenic species emitted to the atmosphere by fossil-fueled power plants are presented and discussed. It is pointed out that many so-called carcinogens are preferentially concentrated on the surface of respirable fly ash particles thus enabling them to come into intimate contact with lung tissues when inhaled. Relatively little information is available about the identities of particulate polycyclic organic compounds whose emission from coal fired power plants may well be substantially greater than hitherto supposed. The importance of chemical changes, which several species may undergo following emission (but prior to inhalation) in determining their potential carcinogenic impact, is stressed. PMID:648494

  16. Evidence of land plant affinity for the Devonian fossil Protosalvinia (Foerstia)

    USGS Publications Warehouse

    Romankiw, L.A.; Hatcher, P.G.; Roen, J.B.

    1988-01-01

    The Devonian plant fossil Protosalvinia (Foerstia) has been examined by solid-state 13C nuclear magnetic resonance spectroscopy (NMR) and pyrolysis-gas chromatography-mass spectrometry (PY-GC-MS). Results of these studies reveal that the chemical structure of Protosalvinia is remarkably similar to that of coalified wood. A well-defined phenolic carbon peak in the NMR spectra and the appearance of phenol and alkylated phenols in pyrolysis products are clearly indicative of lignin-like compounds. These data represent significant new information on the chemical nature of Protosalvinia and provide the first substantial organic geochemical evidence for land plant affinity. -Authors

  17. Fossil-fueled power plants as a source of atmospheric carbon monoxide.

    PubMed

    Nicks, D K; Holloway, J S; Ryerson, T B; Dissly, R W; Parrish, D D; Frost, G J; Trainer, M; Donnelly, S G; Schauffler, S; Atlas, E L; Hübler, G; Sueper, D T; Fehsenfeld, F C

    2003-02-01

    Elevated carbon monoxide (CO) mixing ratios in excess of those derived from emissions inventories have been observed in plumes from one gas- and coal-fired power plant and three of four lignite coal-fired electric utility power plants observed in east and central Texas. Observations of elevated CO on days characterized by differing wind directions show that CO emissions from the lignite plants were relatively constant over time and cannot be ascribed to separate sources adjacent to the power plants. These three plants were found to be emitting CO at rates 22 to 34 times those tabulated in State and Federal emissions inventories. Elevated CO emissions from the gas- and coal-fired plant were highly variable on time scales of hours to days, in one case changing by a factor of 8 within an hour. Three other fossil-fueled power plants, including one lignite-fired plant observed during this study, did not emit substantial amounts of CO, suggesting that a combination of plant operating conditions and the use of lignite coal may contribute to the enhanced emissions. Observed elevated CO emissions from the three lignite plants, if representative of average operating conditions, represent an additional 30% of the annual total CO emissions from point sources for the state of Texas.

  18. H. Julian Allen

    NASA Technical Reports Server (NTRS)

    1957-01-01

    H. Julian Allen stands beside the observation window of the 8 x 7 foot test section of the NACA Ames Unitary Plan Wind Tunnel. H. Julian Allen is best known for his 'Blunt Body Theory' of aerodynamics, a design technique for alleviating the severe re-entry heating problem which was then delaying the development of ballistic missiles. His findings revolutionized the fundamental design of ballistic missle re-entry shapes. Subsequently, applied research led to applications of the 'blunt' shape to ballistic missles and spacecraft which were intended to re-enter the Earth's atmosphere. This application led to the design of ablative heat shields that protected the Mercury, Gemini and Apollo astronauts as their space capsules re- entered the Earth's atmosphere. 'Harvey' Allen as he was called by most, was not only a brilliant scientist and aeronautical engineer but was also admired for his kindness, thoughtfulness and sense of humor. Among his many other accomplishments, Harvey Allen served as Center Director of the NASA Ames Research Center from 1965 to 1969. He died of a heart attack on January 29, 1977 at the age of 66.

  19. RADIOACTIVITY IN THE ATMOSPHERIC EFFLUENTS OF POWER PLANTS THAT USE FOSSIL FUELS.

    PubMed

    EISENBUD, M; PETROW, H G

    1964-04-17

    Analysis of the fly ash produced by combustion of pulverized Appalachian coal has shown that a 1000-megawatt coal-burning power plant will discharge into the atmosphere from about 28 millicuries to nearly 1 curie per year of radium-226 and radium-228. An oil-burning plant of similar size will discharge about 0.5 millicurie of radium per year. Comparison of these data with data on the release of fission products from nuclear-powered generating stations shows that when the physical and biological properties of the various radionuclides are taken into consideration, the conventional fossil-fueled plants discharge relatively greater quantities of radioactive materials into the atmosphere than nuclearpowered plants of comparable size. PMID:14169712

  20. Solar-Augment Potential of U.S. Fossil-Fired Power Plants

    SciTech Connect

    Turchi, C.; Langle, N.; Bedilion, R.; Libby, C.

    2011-02-01

    Concentrating Solar Power (CSP) systems utilize solar thermal energy for the generation of electric power. This attribute makes it relatively easy to integrate CSP systems with fossil-fired power plants. The 'solar-augment' of fossil power plants offers a lower cost and lower risk alternative to stand-alone solar plant construction. This study ranked the potential to add solar thermal energy to coal-fired and natural gas combined cycle (NGCC) plants found throughout 16 states in the southeast and southwest United States. Each generating unit was ranked in six categories to create an overall score ranging from Excellent to Not Considered. Separate analysis was performed for parabolic trough and power tower technologies due to the difference in the steam temperatures that each can generate. The study found a potential for over 11 GWe of parabolic trough and over 21 GWe of power tower capacity. Power towers offer more capacity and higher quality integration due to the greater steam temperatures that can be achieved. The best sites were in the sunny southwest, but all states had at least one site that ranked Good for augmentation.

  1. Environmental benchmarking of the largest fossil-fueled electricity generating plants in the U.S

    NASA Astrophysics Data System (ADS)

    Sarkis, Joseph

    2004-02-01

    Environmental management, to be effective, requires performance evaluation and process improvement. This is especially the case in fossil-fueled electricity generating plants. Although eco-efficient management of these types of organizations are critical to local, national and global environmental issues, few studies have focused on performance measurement and eco-efficiency improvements in this industry. This study evaluates the eco-efficiencies of the top 100 major U.S. fossil-fueled electricity generating plants from 1998 data. Using a multi-criteria non-parametric productivity model (data envelopment analysis) efficiency scores are determined. These efficiency scores are treated by a clustering method in identifying benchmarks for improving poorly performing plants. Efficiency measures are based on three resource input measures including boiler generating capacity, total fuel heat used, and total generator capacity, and four output measures including actual energy generated, SO2, NOx, and CO2 emissions. The purpose of this paper is two-fold, to introduce the methodology"s application to eco-efficiency performance measurement and show some characteristics of the benchmarked plants and groups.

  2. Evaluation of plant biomass resources available for replacement of fossil oil

    PubMed Central

    Henry, Robert J

    2010-01-01

    The potential of plants to replace fossil oil was evaluated by considering the scale of production required, the area of land needed and the types of plants available. High yielding crops (50 tonnes/ha) that have a high conversion efficiency (75%) would require a global land footprint of around 100 million ha to replace current (2008) oil consumption. Lower yielding or less convertible plants would require a larger land footprint. Domestication of new species as dedicated energy crops may be necessary. A systematic analysis of higher plants and their current and potential uses is presented. Plant biotechnology provides tools to improve the prospects of replacing oil with plant-derived biomass by increasing the amount of biomass produced per unit area of land and improving the composition of the biomass to increase the efficiency of conversion to biofuel and biomaterials. Options for the production of high value coproducts and the expression of processing aids such as enzymes in the plant may add further value to plants as bioenergy resources. PMID:20070873

  3. Fossil plant relative abundances indicate sudden loss of Late Triassic biodiversity in East Greenland.

    PubMed

    McElwain, Jennifer C; Wagner, Peter J; Hesselbo, Stephen P

    2009-06-19

    The pace of Late Triassic (LT) biodiversity loss is uncertain, yet it could help to decipher causal mechanisms of mass extinction. We investigated relative abundance distributions (RADs) of six LT plant assemblages from the Kap Stewart Group, East Greenland, to determine the pace of collapse of LT primary productivity. RADs displayed not simply decreases in the number of taxa, but decreases in the number of common taxa. Likelihood tests rejected a hypothesis of continuously declining diversity. Instead, the RAD shift occurred over the upper two-to-four fossil plant assemblages and most likely over the last three (final 13 meters), coinciding with increased atmospheric carbon dioxide concentration and global warming. Thus, although the LT event did not induce mass extinction of plant families, it accompanied major and abrupt change in their ecology and diversity.

  4. A proposed origin for fossilized Pennsylvanian plant cuticles by pyrite oxidation (Sydney Coalfield, Nova Scotia, Canada)

    USGS Publications Warehouse

    Zodrow, E.L.; Mastalerz, Maria

    2009-01-01

    Fossilized cuticles, though rare in the roof rocks of coal seam in the younger part of the Pennsylvanian Sydney Coalfield, Nova Scotia, represent nearly all of the major plant groups. Selected for investigation, by methods of Fourier transform infrared spectroscopy (FTIR) and elemental analysis, are fossilized cuticles (FCs) and cuticles extracted from compressions by Schulze's process (CCs) of Alethopteris ambigua. These investigations are supplemented by FTIR analysis of FCs and CCs of Cordaites principalis, and a cuticle-fossilized medullosalean(?) axis. The purpose of this study is threefold: (1) to try to determine biochemical discriminators between FCs and CCs of the same species using semi-quantitative FTIR techniques; (2) to assess the effects chemical treatments have, particularly Schulze's process, on functional groups; and most importantly (3) to study the primary origin of FCs. Results are equivocal in respect to (1); (2) after Schulze's treatment aliphatic moieties tend to be reduced relative to oxygenated groups, and some aliphatic chains may be shortened; and (3) a primary chemical model is proposed. The model is based on a variety of geological observations, including stratal distribution, clay and pyrite mineralogies associated with FCs and compressions, and regional geological structure. The model presupposes compression-cuticle fossilization under anoxic conditions for late authigenic deposition of sub-micron-sized pyrite on the compressions. Rock joints subsequently provided conduits for oxygen-enriched ground-water circulation to initiate in situ pyritic oxidation that produced sulfuric acid for macerating compressions, with resultant loss of vitrinite, but with preservation of cuticles as FCs. The timing of the process remains undetermined, though it is assumed to be late to post-diagenetic. Although FCs represent a pathway of organic matter transformation (pomd) distinct from other plant-fossilization processes, global applicability of the

  5. The Allen Telescope Array

    NASA Astrophysics Data System (ADS)

    Deboer, David; Ackermann, Rob; Blitz, Leo; Bock, Douglas; Bower, Geoffrey; Davis, Michael; Dreher, John; Engargiola, Greg; Fleming, Matt; Keleta, Girmay; Harp, Gerry; Lugten, John; Tarter, Jill; Thornton, Doug; Wadefalk, Niklas; Weinreb, Sander; Welch, William J.

    2004-06-01

    The Allen Telescope Array, a joint project between the SETI Institute and the Radio Astronomy Laboratory at the University of California Berkeley, is currently under development and construction at the Hat Creek Radio Observatory in northern California. It will consist of 350 6.1-m offset Gregorian antennas in a fairly densely packed configuration, with minimum baselines of less than 10 m and a maximum baseline of about 900 m. The dual-polarization frequency range spans from about 500 MHz to 11 GHz, both polarizations of which are transported back from each antenna. The first generation processor will provide 32 synthesized beams of 104 MHz bandwidth, eight at each of four tunings, as well as outputs for a full-polarization correlator at two of the tunings at the same bandwidth. This paper provides a general description of the Allen Telescope Array.

  6. EPICS: Allen-Bradley hardware reference manual

    SciTech Connect

    Nawrocki, G.

    1993-04-05

    This manual covers the following hardware: Allen-Bradley 6008 -- SV VMEbus I/O scanner; Allen-Bradley universal I/O chassis 1771-A1B, -A2B, -A3B, and -A4B; Allen-Bradley power supply module 1771-P4S; Allen-Bradley 1771-ASB remote I/O adapter module; Allen-Bradley 1771-IFE analog input module; Allen-Bradley 1771-OFE analog output module; Allen-Bradley 1771-IG(D) TTL input module; Allen-Bradley 1771-OG(d) TTL output; Allen-Bradley 1771-IQ DC selectable input module; Allen-Bradley 1771-OW contact output module; Allen-Bradley 1771-IBD DC (10--30V) input module; Allen-Bradley 1771-OBD DC (10--60V) output module; Allen-Bradley 1771-IXE thermocouple/millivolt input module; and the Allen-Bradley 2705 RediPANEL push button module.

  7. Morphological preservation of carbonaceous plant fossils in blueschist metamorphic rocks from New Zealand.

    PubMed

    Galvez, M E; Beyssac, O; Benzerara, K; Bernard, S; Menguy, N; Cox, S C; Martinez, I; Johnston, M R; Brown, G E

    2012-03-01

    Morphological and chemical evidence of ancient life is widespread in sedimentary rocks retrieved from shallow depths in the Earth's crust. Metamorphism is highly detrimental to the preservation of biological information in rocks, thus limiting the geological record in which traces of life might be found. Deformation and increasing pressure/temperature during deep burial may alter the morphology as well as the composition and structure of both the organic and mineral constituents of fossils. However, microspore fossils have been previously observed in intensely metamorphosed rocks. It has been suggested that their small size, and/or the nature of the polymer composing their wall, and/or the mineralogy of their surrounding matrix were key parameters explaining their exceptional preservation. Here, we describe the remarkable morphological preservation of plant macrofossils in blueschist metamorphic rocks from New Zealand containing lawsonite. Leaves and stems can be easily identified at the macroscale. At the microscale, polygonal structures with walls mineralized by micas within the leaf midribs and blades may derive from the original cellular ultrastructure or, alternatively, from the shrinkage during burial of the gelified remnants of the leaves in an abiotic process. Processes and important parameters involved in the remarkable preservation of these fossils during metamorphism are discussed. Despite the excellent morphological preservation, the initial biological polymers have been completely transformed to graphitic carbonaceous matter down to the nanometer scale. This occurrence demonstrates that plant macrofossils may experience major geodynamic processes such as metamorphism and exhumation involving deep changes and homogenization of their carbon chemistry and structure but still retain their morphology with remarkable integrity even if they are not shielded by any hard-mineralized concretion.

  8. Morphological preservation of carbonaceous plant fossils in blueschist metamorphic rocks from New Zealand.

    PubMed

    Galvez, M E; Beyssac, O; Benzerara, K; Bernard, S; Menguy, N; Cox, S C; Martinez, I; Johnston, M R; Brown, G E

    2012-03-01

    Morphological and chemical evidence of ancient life is widespread in sedimentary rocks retrieved from shallow depths in the Earth's crust. Metamorphism is highly detrimental to the preservation of biological information in rocks, thus limiting the geological record in which traces of life might be found. Deformation and increasing pressure/temperature during deep burial may alter the morphology as well as the composition and structure of both the organic and mineral constituents of fossils. However, microspore fossils have been previously observed in intensely metamorphosed rocks. It has been suggested that their small size, and/or the nature of the polymer composing their wall, and/or the mineralogy of their surrounding matrix were key parameters explaining their exceptional preservation. Here, we describe the remarkable morphological preservation of plant macrofossils in blueschist metamorphic rocks from New Zealand containing lawsonite. Leaves and stems can be easily identified at the macroscale. At the microscale, polygonal structures with walls mineralized by micas within the leaf midribs and blades may derive from the original cellular ultrastructure or, alternatively, from the shrinkage during burial of the gelified remnants of the leaves in an abiotic process. Processes and important parameters involved in the remarkable preservation of these fossils during metamorphism are discussed. Despite the excellent morphological preservation, the initial biological polymers have been completely transformed to graphitic carbonaceous matter down to the nanometer scale. This occurrence demonstrates that plant macrofossils may experience major geodynamic processes such as metamorphism and exhumation involving deep changes and homogenization of their carbon chemistry and structure but still retain their morphology with remarkable integrity even if they are not shielded by any hard-mineralized concretion. PMID:22299653

  9. Green Web or megabiased clock? Plant fossils from Gondwanan Patagonia speak on evolutionary radiations.

    PubMed

    Wilf, Peter; Escapa, Ignacio H

    2015-07-01

    Evolutionary divergence-age estimates derived from molecular 'clocks' are frequently correlated with paleogeographic, paleoclimatic and extinction events. One prominent hypothesis based on molecular data states that the dominant pattern of Southern Hemisphere biogeography is post-Gondwanan clade origins and subsequent dispersal across the oceans in a metaphoric 'Green Web'. We tested this idea against well-dated Patagonian fossils of 19 plant lineages, representing organisms that actually lived on Gondwana. Most of these occurrences are substantially older than their respective, often post-Gondwanan molecular dates. The Green Web interpretation probably results from directional bias in molecular results. Gondwanan history remains fundamental to understanding Southern Hemisphere plant radiations, and we urge significantly greater caution when using molecular dating to interpret the biological impacts of geological events.

  10. Service experience, structural integrity, severe accidents, and erosion in nuclear and fossil plants. PVP-Volume 303

    SciTech Connect

    Paterson, S.R.; Bamford, W.H; Geraets, L.H.; Okazaki, M.; Cipolla, R.C.; Cowfer, C.D.; Means, K.H.

    1995-12-01

    The objective of this symposium was to disseminate information on service degradation and its prevention. Papers have been divided into the following topical sections: Service experience in nuclear plants; DOE high-level waste tank structural integrity panel--Summary reports; Severe accidents; Service experience in operating fossil power plants; and Erosion. Papers have been processed separately for inclusion on the data base.

  11. Generic guidelines for the life extension of fossil fuel power plants: Final report

    SciTech Connect

    McNaughton, W.P.; Richman, R.H.; Pillar, C.S.; Perry, L.W.

    1986-11-01

    These generic guidelines were developed under the EPRI project for fossil-fuel power plant life extension - RP2596. In addition to compiling the findings of four utility life extension projects, the guidelines incorporate worldwide experience in the residual life assessment and life extension of fossil-fuel power plant components. The guidelines are aimed at assisting those utilities without formal life extension programs to formulate initial life extension planning studies and to provide guidance in the subsequent implementation of a life extension strategy. For utilities with existing programs, the guidelines provide technical life assessment guidance and also serve as a checklist for the periodic review and updating of the programs. The guidelines review life extension on three organization levels - (1) corporate and system planning issues, (2) life assesment (plant) planning issues and (3) life extension implementation. They provide a logical, stepwise procedure for establishing or revising a life extension program. The guidelines, particularly the section on life extension implementation, are structured in a three-level approach in which increasingly costly and accurate residual life assessments are performed only as needed. A phased approach to life extension is introduced as a potentially cost- and resource-effective way of implementing life extension activities. Each step of the life extension process is illustrated with examples of the manner in which the implementation may typically occur. However, given the variety of circumstances facing each individual utility, the emphasis is on those steps that are typically performed and not upon recommending the details of a particular life extention program. 51 refs., 68 figs., 26 tabs.

  12. Comparison of manual and automated pretreatment methods for AMS radiocarbon dating of plant fossils

    USGS Publications Warehouse

    Bradley, L.-A.; Stafford, Thomas W.

    1994-01-01

    A new automated pretreatment system for the preparation of materials submitted for accelerator mass spectrometry (AMS) analysis is less time-consuming and results in a higher sample yield. The new procedure was tested using two groups of plant fossils: one group was pretreated using the traditional method, and the second, using the automated pretreatment apparatus. The time it took to complete the procedure and the amount of sample material remaining were compared. The automated pretreatment apparatus proved to be more than three times faster and, in most cases, produced a higher yield. A darker discoloration of the KOH solutions was observed indicating that the automated system is more thorough in removing humates from the specimen compared to the manual method. -Authors

  13. SO{sub 2} compliance Cumberland Fossil Plant. Final environmental assessment

    SciTech Connect

    Not Available

    1991-08-01

    The Clean Air Act Amendments (CAAA) of 1990 require a national reduction in SO{sub 2} emissions to control acid rain. This environmental assessment (EA) describes alternative considered (and the associated environmental consequences) for complying with SO{sub 2} reduction requirements of the amendments at Tennessee Valley Authority`s (TVA) Cumberland Fossil Plant (CUF). TVA proposes to reduce SO{sub 2} emissions at CUF to 1.2 lb/10{sub 6} Btu or less as part of its compliance with the CAAA requirements. The two most viable options to achieve this reduction are a switch to western low- sulfur coal and the installation of flue gas desulfurization (FGD), also called scrubbers.

  14. Device for separating CO2 from fossil-fueled power plant emissions

    DOEpatents

    Burchell, Timothy D [Oak Ridge, TN; Judkins, Roddie R [Knoxville, TN; Wilson, Kirk A [Knoxville, TN

    2002-04-23

    A gas separation device includes an inner conduit, and a concentric outer conduit. An electrically conductive filter media, preferably a carbon fiber composite molecular sieve, is provided in the annular space between the inner conduit and the outer conduit. Gas flows through the inner conduit and the annular space between the inner conduit and the outer conduit, so as to contact the filter media. The filter media preferentially adsorbs at least one constituent of the gas stream. The filter media is regenerated by causing an electric current to flow through the filter media. The inner conduit and outer conduit are preferably electrically conductive whereby the regeneration of the filter media can be electrically stimulated. The invention is particularly useful for the removal of CO.sub.2 from the exhaust gases of fossil-fueled power plants.

  15. Revisiting the origin and diversification of vascular plants through a comprehensive Bayesian analysis of the fossil record.

    PubMed

    Silvestro, Daniele; Cascales-Miñana, Borja; Bacon, Christine D; Antonelli, Alexandre

    2015-07-01

    Plants have a long evolutionary history, during which mass extinction events dramatically affected Earth's ecosystems and its biodiversity. The fossil record can shed light on the diversification dynamics of plant life and reveal how changes in the origination-extinction balance have contributed to shaping the current flora. We use a novel Bayesian approach to estimate origination and extinction rates in plants throughout their history. We focus on the effect of the 'Big Five' mass extinctions and on estimating the timing of origin of vascular plants, seed plants and angiosperms. Our analyses show that plant diversification is characterized by several shifts in origination and extinction rates, often matching the most important geological boundaries. The estimated origin of major plant clades predates the oldest macrofossils when considering the uncertainties associated with the fossil record and the preservation process. Our findings show that the commonly recognized mass extinctions have affected each plant group differently and that phases of high extinction often coincided with major floral turnovers. For instance, after the Cretaceous-Paleogene boundary we infer negligible shifts in diversification of nonflowering seed plants, but find significantly decreased extinction in spore-bearing plants and increased origination rates in angiosperms, contributing to their current ecological and evolutionary dominance.

  16. Model-based monitoring and fault diagnosis of fossil power plant process units using Group Method of Data Handling.

    PubMed

    Li, Fan; Upadhyaya, Belle R; Coffey, Lonnie A

    2009-04-01

    This paper presents an incipient fault diagnosis approach based on the Group Method of Data Handling (GMDH) technique. The GMDH algorithm provides a generic framework for characterizing the interrelationships among a set of process variables of fossil power plant sub-systems and is employed to generate estimates of important variables in a data-driven fashion. In this paper, ridge regression techniques are incorporated into the ordinary least squares (OLS) estimator to solve regression coefficients at each layer of the GMDH network. The fault diagnosis method is applied to feedwater heater leak detection with data from an operating coal-fired plant. The results demonstrate the proposed method is capable of providing an early warning to operators when a process fault or an equipment fault occurs in a fossil power plant. PMID:19084227

  17. Intramolecular ketene-allene cycloadditions.

    PubMed

    McCaleb, K L; Halcomb, R L

    2000-08-24

    [reaction: see text]This report describes intramolecular thermal [2 + 2] cycloadditions between ketenes and allenes. The formation of ketenes and the subsequent cycloadditions occurred under a variety of conditions, affording 7-methylidinebicyclo[3.2.0]heptanones and 7-methylidinebicyclo[3.1.1]heptanones in 45-78% yields. The regioselectivity of the cycloaddition varied with the substitution of the allene, and the yield of cyclized products varied with reaction conditions.

  18. A 300-million-year record of atmospheric carbon dioxide from fossil plant cuticles

    NASA Astrophysics Data System (ADS)

    Retallack, Gregory J.

    2001-05-01

    To understand better the link between atmospheric CO2 concentrations and climate over geological time, records of past CO2 are reconstructed from geochemical proxies. Although these records have provided us with a broad picture of CO2 variation throughout the Phanerozoic eon (the past 544Myr), inconsistencies and gaps remain that still need to be resolved. Here I present a continuous 300-Myr record of stomatal abundance from fossil leaves of four genera of plants that are closely related to the present-day Ginkgo tree. Using the known relationship between leaf stomatal abundance and growing season CO2 concentrations, I reconstruct past atmospheric CO2 concentrations. For the past 300Myr, only two intervals of low CO2 (<1,000p.p.m.v.) are inferred, both of which coincide with known ice ages in Neogene (1-8Myr) and early Permian (275-290Myr) times. But for most of the Mesozoic era (65-250Myr), CO2 levels were high (1,000-2,000p.p.m.v.), with transient excursions to even higher CO2 (>2,000p.p.m.v.) concentrations. These results are consistent with some reconstructions of past CO2 (refs 1, 2) and palaeotemperature records, but suggest that CO2 reconstructions based on carbon isotope proxies may be compromised by episodic outbursts of isotopically light methane. These results support the role of water vapour, methane and CO2 in greenhouse climate warming over the past 300Myr.

  19. Inputs of fossil carbon from wastewater treatment plants to U.S. Rivers and oceans

    USGS Publications Warehouse

    Griffith, D.R.; Barnes, R.T.; Raymond, P.A.

    2009-01-01

    Every day more than 500 million cubic meters of treated wastewater are discharged into rivers, estuaries, and oceans, an amount slightly less than the average flow of the Danube River. Typically, wastewaters have high organic carbon (OC) concentrations and represent a large fraction of total river flow and a higher fraction of river OC in densely populated watersheds. Here, we report the first direct measurements of radiocarbon (14C) in municipal wastewater treatment plant (WWTP) effluent. The radiocarbon ages of particulate and dissolved organic carbon (POC and DOC) in effluent are old and relatively uniform across a range of WWTPs in New York and Connecticut. Wastewater DOC has a mean radiocarbon age of 1630 ?? 500 years B.P. and a mean ??13C of -26.0 ?? 1???. Mass balance calculations indicate that 25% of wastewater DOC is fossil carbon, which is likely derived from petroleumbased household products such as detergents and pharmaceuticals. Thesefindings warrant reevaluation of the "apparent age" of riverine DOC, the total flux of petroleum carbon to U.S. oceans, and OC source assignments in waters impacted by sewage. ?? 2009 American Chemical Society.

  20. A 300-million-year record of atmospheric carbon dioxide from fossil plant cuticles.

    PubMed

    Retallack, G J

    2001-05-17

    To understand better the link between atmospheric CO2 concentrations and climate over geological time, records of past CO2 are reconstructed from geochemical proxies. Although these records have provided us with a broad picture of CO2 variation throughout the Phanerozoic eon (the past 544 Myr), inconsistencies and gaps remain that still need to be resolved. Here I present a continuous 300-Myr record of stomatal abundance from fossil leaves of four genera of plants that are closely related to the present-day Ginkgo tree. Using the known relationship between leaf stomatal abundance and growing season CO2 concentrations, I reconstruct past atmospheric CO2 concentrations. For the past 300 Myr, only two intervals of low CO2 (<1,000 p.p.m.v.) are inferred, both of which coincide with known ice ages in Neogene (1-8 Myr) and early Permian (275-290 Myr) times. But for most of the Mesozoic era (65-250 Myr), CO2 levels were high (1,000-2,000 p.p.m.v.), with transient excursions to even higher CO2 (>2,000 p.p.m.v.) concentrations. These results are consistent with some reconstructions of past CO2 (refs 1, 2) and palaeotemperature records, but suggest that CO2 reconstructions based on carbon isotope proxies may be compromised by episodic outbursts of isotopically light methane. These results support the role of water vapour, methane and CO2 in greenhouse climate warming over the past 300 Myr.

  1. Exceptionally well preserved late Quaternary plant and vertebrate fossils from a blue hole on Abaco, The Bahamas.

    PubMed

    Steadman, David W; Franz, Richard; Morgan, Gary S; Albury, Nancy A; Kakuk, Brian; Broad, Kenneth; Franz, Shelley E; Tinker, Keith; Pateman, Michael P; Lott, Terry A; Jarzen, David M; Dilcher, David L

    2007-12-11

    We report Quaternary vertebrate and plant fossils from Sawmill Sink, a "blue hole" (a water-filled sinkhole) on Great Abaco Island, The Bahamas. The fossils are well preserved because of deposition in anoxic salt water. Vertebrate fossils from peat on the talus cone are radiocarbon-dated from approximately 4,200 to 1,000 cal BP (Late Holocene). The peat produced skeletons of two extinct species (tortoise Chelonoidis undescribed sp. and Caracara Caracara creightoni) and two extant species no longer in The Bahamas (Cuban crocodile, Crocodylus rhombifer; and Cooper's or Gundlach's Hawk, Accipiter cooperii or Accipiter gundlachii). A different, inorganic bone deposit on a limestone ledge in Sawmill Sink is a Late Pleistocene owl roost that features lizards (one species), snakes (three species), birds (25 species), and bats (four species). The owl roost fauna includes Rallus undescribed sp. (extinct; the first Bahamian flightless rail) and four other locally extinct species of birds (Cooper's/Gundlach's Hawk, A. cooperii/gundlachii; flicker Colaptes sp.; Cave Swallow, Petrochelidon fulva; and Eastern Meadowlark, Sturnella magna) and mammals (Bahamian hutia, Geocapromys ingrahami; and a bat, Myotis sp.). The exquisitely preserved fossils from Sawmill Sink suggest a grassy pineland as the dominant plant community on Abaco in the Late Pleistocene, with a heavier component of coppice (tropical dry evergreen forest) in the Late Holocene. Important in its own right, this information also will help biologists and government planners to develop conservation programs in The Bahamas that consider long-term ecological and cultural processes. PMID:18077421

  2. Exceptionally well preserved late Quaternary plant and vertebrate fossils from a blue hole on Abaco, The Bahamas

    PubMed Central

    Steadman, David W.; Franz, Richard; Morgan, Gary S.; Albury, Nancy A.; Kakuk, Brian; Broad, Kenneth; Franz, Shelley E.; Tinker, Keith; Pateman, Michael P.; Lott, Terry A.; Jarzen, David M.; Dilcher, David L.

    2007-01-01

    We report Quaternary vertebrate and plant fossils from Sawmill Sink, a “blue hole” (a water-filled sinkhole) on Great Abaco Island, The Bahamas. The fossils are well preserved because of deposition in anoxic salt water. Vertebrate fossils from peat on the talus cone are radiocarbon-dated from ≈4,200 to 1,000 cal BP (Late Holocene). The peat produced skeletons of two extinct species (tortoise Chelonoidis undescribed sp. and Caracara Caracara creightoni) and two extant species no longer in The Bahamas (Cuban crocodile, Crocodylus rhombifer; and Cooper's or Gundlach's Hawk, Accipiter cooperii or Accipiter gundlachii). A different, inorganic bone deposit on a limestone ledge in Sawmill Sink is a Late Pleistocene owl roost that features lizards (one species), snakes (three species), birds (25 species), and bats (four species). The owl roost fauna includes Rallus undescribed sp. (extinct; the first Bahamian flightless rail) and four other locally extinct species of birds (Cooper's/Gundlach's Hawk, A. cooperii/gundlachii; flicker Colaptes sp.; Cave Swallow, Petrochelidon fulva; and Eastern Meadowlark, Sturnella magna) and mammals (Bahamian hutia, Geocapromys ingrahami; and a bat, Myotis sp.). The exquisitely preserved fossils from Sawmill Sink suggest a grassy pineland as the dominant plant community on Abaco in the Late Pleistocene, with a heavier component of coppice (tropical dry evergreen forest) in the Late Holocene. Important in its own right, this information also will help biologists and government planners to develop conservation programs in The Bahamas that consider long-term ecological and cultural processes. PMID:18077421

  3. Alkane distribution and carbon isotope composition in fossil leaves: An interpretation of plant physiology in the geologic past

    NASA Astrophysics Data System (ADS)

    Graham, H. V.; Freeman, K. H.

    2014-12-01

    The relative chain-length distribution and carbon-isotope composition of n-alkanes extracted from sedimentary rocks are important geochemical tools for investigating past terrestrial ecosystems. Alkanes preserved in ancient sediments are assumed to be contemporaneous, derived from the same ecosystem, and integrated from the biomass present on the landscape at the time of deposition. Further, there is an underlying assumption that ancient plants exhibited the same metabolic and physiological responses to climate conditions that are observed for modern plants. Interpretations of alkane abundances and isotopic signatures are complicated by the strong influence of phylogenetic affiliation and ecological factors, such as canopy structure. A better understanding of how ecosystem and taxa influence alkane properties, including homologue abundance patterns and leaf-lipid carbon isotope fractionation would help strengthen paleoecological interpretations based on these widely employed plant biomarkers. In this study, we analyze the alkane chain-length distribution and carbon-isotope composition of phytoleim and alkanes (d13Cleaf and d13Clipid) extracted from a selection of Cretaceous and Paleocene fossil leaves from the Guaduas and Cerrejon Formations of Colombia. These data were compared with data for the same families in a modern analogue biome. Photosynthetic and biosynthetic fractionation (∆leaf and elipid) values determined from the fossil material indicate carbon metabolism patterns were similar to modern plants. Fossil data were incorporated in a biomass-weighted mixing model to represent the expected lipid complement of sediment arising from this ecosystem and compared with alkane measurements from the rock matrix. Modeled and observed isotopic and abundance patterns match well for alkane homologs most abundant in plants (i.e., n-C27 to n-C33). The model illustrates the importance of understanding biases in litter flux and taphonomic pressures inherent in the

  4. The Allen Telescope Array

    NASA Astrophysics Data System (ADS)

    DeBoer, David R.; Welch, William J.; Dreher, John; Tarter, Jill; Blitz, Leo; Davis, Michael; Fleming, Matt; Bock, Douglas; Bower, Geoffrey; Lugten, John; Girmay-Keleta, G.; D'Addario, Larry R.; Harp, Gerry R.; Ackermann, Rob; Weinreb, Sander; Engargiola, Greg; Thornton, Doug; Wadefalk, Niklas

    2004-10-01

    The Allen Telescope Array, originally called the One Hectare Telescope (1hT) [1] will be a large array radio telescope whose novel characteristics will be a wide field of view (3.5 deg-GHz HPBW), continuous frequency coverage of 0.5 - 11 GHz, four dual-linear polarization output bands of 100 MHz each, four beams in each band, two 100 MHz spectral correlators for two of the bands, and hardware for RFI mitigation built in. Its scientific motivation is for deep SETI searches and, at the same time, a variety of other radio astronomy projects, including transient (e.g. pulsar) studies, HI mapping of the Milky Way and nearby galaxies, Zeeman studies of the galactic magnetic field in a number of transitions, mapping of long chain molecules in molecular clouds, mapping of the decrement in the cosmic background radiation toward galaxy clusters, and observation of HI absorption toward quasars at redshifts up to z=2. The array is planned for 350 6.1-meter dishes giving a physical collecting area of about 10,000 square meters. The large number of components reduces the price with economies of scale. The front end receiver is a single cryogenically cooled MIMIC Low Noise Amplifier covering the whole band. The feed is a wide-band log periodic feed of novel design, and the reflector system is an offset Gregorian for minimum sidelobes and spillover. All preliminary and critical design reviews have been completed. Three complete antennas with feeds and receivers are under test, and an array of 33 antennas is under construction at the Hat Creek Radio Observatory for the end of 2004. The present plan is to have a total of about 200 antennas completed by the summer of 2006 and the balance of the array finished before the end of the decade.

  5. Allen Telescope Array

    NASA Astrophysics Data System (ADS)

    Bower, Geoffrey

    2007-05-01

    The Allen Telescope Array (ATA) is a pioneering centimeter-wavelength radio telescope that will produce science that cannot be done with any other instrument. The ATA is the first radio telescope designed for commensal observing; it will undertake the most comprehensive and sensitive SETI surveys ever done as well as the deepest and largest area continuum and spectroscopic surveys. Science operations will commence this year with a 42-element array. The ATA will ultimately comprise 350 6-meter dishes at Hat Creek in California, and will make possible large, deep radio surveys that were not previously feasible. The telescope incorporates many new design features including hydroformed antenna surfaces, a log-periodic feed covering the entire range of frequencies from 500 MHz to 11.2 GHz, low noise, wide-band amplifiers with a flat response over the entire band. The full array has the sensitivity of the Very Large Array but with a survey capability that is greater by an order of magnitude due to the wide field of view of the 6-meter dishes. Even with 42 elements, the ATA will be one of the most powerful radio survey telescopes. Science goals include the Five GHz sky survey (FiGSS) to match the 1.4-GHz NRAO VLA Sky Survey (NVSS) and the Sloan Digital Sky Survey within the first year of operation with the 42 element array, and a deep all-sky survey of extragalactic hydrogen to investigate galaxy evolution and intergalactic gas accretion. Transient and variable source surveys, pulsar science, spectroscopy of new molecular species in the galaxy, large-scale mapping of galactic magnetic filaments, and wide-field imaging of comets and other solar system objects are among the other key science objectives of the ATA. SETI surveys will reach sufficient sensitivity to detect an Arecibo planetary radar from 1,000,000 stars to distances of 300 pc.

  6. Can hybrid solar-fossil power plants mitigate CO2 at lower cost than PV or CSP?

    PubMed

    Moore, Jared; Apt, Jay

    2013-03-19

    Fifteen of the United States and several nations require a portion of their electricity come from solar energy. We perform an engineering-economic analysis of hybridizing concentrating solar thermal power with fossil fuel in an Integrated Solar Combined Cycle (ISCC) generator. We construct a thermodynamic model of an ISCC plant in order to examine how much solar and fossil electricity is produced and how such a power plant would operate, given hourly solar resource data and hourly electricity prices. We find that the solar portion of an ISCC power plant has a lower levelized cost of electricity than stand-alone solar power plants given strong solar resource in the US southwest and market conditions that allow the capacity factor of the solar portion of the power plant to be above 21%. From a local government perspective, current federal subsidies distort the levelized cost of electricity such that photovoltaic electricity is slightly less expensive than the solar electricity produced by the ISCC. However, if the cost of variability and additional transmission lines needed for stand-alone solar power plants are taken into account, the solar portion of an ISCC power plant may be more cost-effective.

  7. Can hybrid solar-fossil power plants mitigate CO2 at lower cost than PV or CSP?

    PubMed

    Moore, Jared; Apt, Jay

    2013-03-19

    Fifteen of the United States and several nations require a portion of their electricity come from solar energy. We perform an engineering-economic analysis of hybridizing concentrating solar thermal power with fossil fuel in an Integrated Solar Combined Cycle (ISCC) generator. We construct a thermodynamic model of an ISCC plant in order to examine how much solar and fossil electricity is produced and how such a power plant would operate, given hourly solar resource data and hourly electricity prices. We find that the solar portion of an ISCC power plant has a lower levelized cost of electricity than stand-alone solar power plants given strong solar resource in the US southwest and market conditions that allow the capacity factor of the solar portion of the power plant to be above 21%. From a local government perspective, current federal subsidies distort the levelized cost of electricity such that photovoltaic electricity is slightly less expensive than the solar electricity produced by the ISCC. However, if the cost of variability and additional transmission lines needed for stand-alone solar power plants are taken into account, the solar portion of an ISCC power plant may be more cost-effective. PMID:23379665

  8. Carbon Capture and Water Emissions Treatment System (CCWESTRS) at Fossil-Fueled Electric Generating Plants

    SciTech Connect

    P. Alan Mays; Bert R. Bock; Gregory A. Brodie; L. Suzanne Fisher; J. Devereux Joslin; Donald L. Kachelman; Jimmy J. Maddox; N. S. Nicholas; Larry E. Shelton; Nick Taylor; Mark H. Wolfe; Dennis H. Yankee; John Goodrich-Mahoney

    2005-08-30

    The Tennessee Valley Authority (TVA), the Electric Power Research Institute (EPRI), and the Department of Energy-National Energy Technologies Laboratory (DOE-NETL) are evaluating and demonstrating integration of terrestrial carbon sequestration techniques at a coal-fired electric power plant through the use of Flue Gas Desulfurization (FGD) system gypsum as a soil amendment and mulch, and coal fly ash pond process water for periodic irrigation. From January to March 2002, the Project Team initiated the construction of a 40 ha Carbon Capture and Water Emissions Treatment System (CCWESTRS) near TVA's Paradise Fossil Plant on marginally reclaimed surface coal mine lands in Kentucky. The CCWESTRS is growing commercial grade trees and cover crops and is expected to sequester 1.5-2.0 MT/ha carbon per year over a 20-year period. The concept could be used to meet a portion of the timber industry's needs while simultaneously sequestering carbon in lands which would otherwise remain non-productive. The CCWESTRS includes a constructed wetland to enhance the ability to sequester carbon and to remove any nutrients and metals present in the coal fly ash process water runoff. The CCWESTRS project is a cooperative effort between TVA, EPRI, and DOE-NETL, with a total budget of $1,574,000. The proposed demonstration project began in October 2000 and has continued through December 2005. Additional funding is being sought in order to extend the project. The primary goal of the project is to determine if integrating power plant processes with carbon sequestration techniques will enhance carbon sequestration cost-effectively. This goal is consistent with DOE objectives to provide economically competitive and environmentally safe options to offset projected growth in U.S. baseline emissions of greenhouse gases after 2010, achieve the long-term goal of $10/ton of avoided net costs for carbon sequestration, and provide half of the required reductions in global greenhouse gases by 2025

  9. Estimates of health risks associated with radionuclide emissions from fossil-fueled steam-electric generating plants. Final report

    SciTech Connect

    Nelson, C.

    1995-08-01

    Under the Title III, Section 112 of the 1990 Clean Air Act Amendment, Congress directed the U.S. Environmental Protection Agency (EPA) to perform a study of the hazards to public resulting from pollutants emitted by electric utility system generating units. Radionuclides are among the groups of pollutants listed in the amendment. This report updates previously published data and estimates with more recently available information regarding the radionuclide contents of fossil fuels, associated emissions by steam-electric power plants, and potential health effects to exposed population groups.

  10. Use of Chia Plant to Monitor Urban Fossil Fuel CO2 Emission: An Example From Irvine, CA in 2010

    NASA Astrophysics Data System (ADS)

    Xu, X.; Stills, A.; Trumbore, S.; Randerson, J. T.; Yi, J.

    2011-12-01

    Δ14CO2 is a unique tracer for quantifying anthropogenic CO2 emissions. However, monitoring 14CO2 change and distribution in an urban environment is challenging because of its large spatial and temporal variations. We have tested the potential use of a chia plant (Salvia hispanica) as an alternative way to collect a time-integrated CO2 sample for radiocarbon analysis. The results show that Δ14C of the new growth of chia sprouts and chia leaves are consistent with the Δ14C of air samples collected during the growing period, indicating the new growth has no inherited C from seeds and thus records atmospheric 14CO2. Time-integrated air samples and chia leaf samples significantly reduced the noises of Δ14CO2 in an urban environment. We report here an example of monitoring 14CO2 change in Irvine, CA from Mar 2010 to Mar 2011 utilizing such a method. The results showed a clear seasonal cycle with high (close to remote air background level) Δ14C in summer and low Δ14C in winter months in this urban area. Excess (above remote air background) fossil fuel CO2 was calculated to be closed to 0 ppm in June to about 16 ppm from November 2010 to February 2011. Monthly mean Δ14CO2 was anti-correlated with monthly mean CO mixing ratio, indicating Δ14CO2 is mainly controlled by fossil fuel CO2 mixing with clean on-shore marine air. In summary, this study has shown encouraging result that chia plant can be potentially used as a convenient and inexpensive sampling method for time-integrated atmospheric 14CO2. Combined with other annual plants this provides the opportunity to map out time-integrated fossil fuel-derived CO2 in major cities at low cost. This in turn can be used to: 1) establish a baseline for fossil fuel emissions reductions in cities in the future; 2) provide invaluable information for validating emission models.

  11. Mud fossils

    USGS Publications Warehouse

    ,

    1997-01-01

    At the close of the 18th century, the haze of fantasy and mysticism that tended to obscure the true nature of the Earth was being swept away. Careful studies by scientists showed that rocks had diverse origins. Some rock layers, containing clearly identifiable fossil remains of fish and other forms of aquatic animal and plant life, originally formed in the ocean. Other layers, consisting of sand grains winnowed clean by the pounding surf, obviously formed as beach deposits that marked the shorelines of ancient seas.

  12. Partial replacement of fossil fuel in a cement plant: risk assessment for the population living in the neighborhood.

    PubMed

    Rovira, Joaquim; Mari, Montse; Nadal, Martí; Schuhmacher, Marta; Domingo, José L

    2010-10-15

    In cement plants, the substitution of traditional fossil fuels not only allows a reduction of CO(2), but it also means to check-out residual materials, such as sewage sludge or municipal solid wastes (MSW), which should otherwise be disposed somehow/somewhere. In recent months, a cement plant placed in Alcanar (Catalonia, Spain) has been conducting tests to replace fossil fuel by refuse-derived fuel (RDF) from MSW. In July 2009, an operational test was progressively initiated by reaching a maximum of partial substitution of 20% of the required energy. In order to study the influence of the new process, environmental monitoring surveys were performed before and after the RDF implementation. Metals and polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) were analyzed in soil, herbage, and air samples collected around the facility. In soils, significant decreases of PCDD/F levels, as well as in some metal concentrations were found, while no significant increases in the concentrations of these pollutants were observed. In turn, PM(10) levels remained constant, with a value of 16μgm(-3). In both surveys, the carcinogenic and non-carcinogenic risks derived from exposure to metals and PCDD/Fs for the population living in the vicinity of the facility were within the ranges considered as acceptable according to national and international standards. This means that RDF may be a successful choice in front of classical fossil fuels, being in accordance with the new EU environmental policies, which entail the reduction of CO(2) emissions and the energetic valorization of MSW. However, further long-term environmental studies are necessary to corroborate the harmlessness of RDF, in terms of human health risks.

  13. Modes of fossil preservation

    USGS Publications Warehouse

    Schopf, J.M.

    1975-01-01

    The processes of geologic preservation are important for understanding the organisms represented by fossils. Some fossil differences are due to basic differences in organization of animals and plants, but the interpretation of fossils has also tended to be influenced by modes of preservation. Four modes of preservation generally can be distinguished: (1) Cellular permineralization ("petrifaction") preserves anatomical detail, and, occasionally, even cytologic structures. (2) Coalified compression, best illustrated by structures from coal but characteristic of many plant fossils in shale, preserves anatomical details in distorted form and produces surface replicas (impressions) on enclosing matrix. (3) Authigenic preservation replicates surface form or outline (molds and casts) prior to distortion by compression and, depending on cementation and timing, may intergrade with fossils that have been subject to compression. (4) Duripartic (hard part) preservation is characteristic of fossil skeletal remains, predominantly animal. Molds, pseudomorphs, or casts may form as bulk replacements following dissolution of the original fossil material, usually by leaching. Classification of the kinds of preservation in fossils will aid in identifying the processes responsible for modifying the fossil remains of both animals and plants. ?? 1975.

  14. Responses of high-elevation herbaceous plant assemblages to low glacial CO₂ concentrations revealed by fossil marmot (Marmota) teeth.

    PubMed

    McLean, Bryan S; Ward, Joy K; Polito, Michael J; Emslie, Steven D

    2014-08-01

    Atmospheric CO2 cycles of the Quaternary likely imposed major constraints on the physiology and growth of C3 plants worldwide. However, the measured record of this remains both geographically and taxonomically sparse. We present the first reconstruction of physiological responses in a late Quaternary high-elevation herbaceous plant community from the Southern Rocky Mountains, USA. We used a novel proxy-fossilized tooth enamel of yellow-bellied marmots (Marmota flaviventris)-which we developed using detailed isotopic analysis of modern individuals. Calculated C isotopic discrimination (Δ) of alpine plants was nearly 2 ‰ lower prior to the Last Glacial Maximum than at present, a response almost identical to that of nonherbaceous taxa from lower elevations. However, initial shifts in Δ aligned most closely with the onset of the late Pleistocene bipolar temperature "seesaw" rather than CO2 increase, indicating unique limitations on glacial-age high-elevation plants may have existed due to both low temperatures and low CO2. Further development of system-specific faunal proxies can help to clarify this and other plant- and ecosystem-level responses to past environmental change.

  15. Recent Advances in the Reactions of 1,2-Allenic Ketones and α-Allenic Alcohols.

    PubMed

    Fan, Xuesen; He, Yan; Zhang, Xinying

    2016-06-01

    This Personal Account summarizes our recent efforts in searching for novel synthetic strategies for a number of organic molecules by using allene derivatives as valuable substrates. It starts with a concise description of the background of allene-related synthetic chemistry. The second part deals with the reactions of 1,2-allenic ketones, including the reactions of 1,2-allenic ketones with various nucleophiles to afford functionalized benzenes, heterocycles, and fluoroenones, and those of allenic ketones as nucleophiles under the promotion of bases to provide 1,3,4'-triones or functionalized furans. The third part of this account focuses on the reactions of α-allenic alcohols. In this section, multicomponent reactions involving α-allenic alcohols, and cascade reactions of α-allenic alcohols promoted by Brønsted acid or iodine, are presented. PMID:27230525

  16. Cyclic terpenoids of contemporary resinous plant detritus and of fossil woods, ambers and coals

    USGS Publications Warehouse

    Simoneit, B.R.T.; Grimalt, J.O.; Wang, T.-G.; Cox, R.E.; Hatcher, P.G.; Nissenbaum, A.

    1986-01-01

    Cyclic terpenoids present in the solvent extractable material of fossil woods, ambers and brown coals have been analyzed. The sample series chosen consisted of wood remains preserved in Holocene to Jurassic sediments and a set of of ambers from the Philippines (copalite), Israel, Canada and Dominican Republic. The brown coals selected were from the Fortuna Garsdorf Mine and Miocene formations on Fiji. The fossil wood extracts contained dominant diterpenoid or sesquiterpenoid skeletons, and aromatized species were present at high concentrations, with a major amount of two-ring aromatic compounds. Tricyclic diterpenoids were the predominant compounds in the ambers. Aromatized derivatives were the major components, consisting of one or two aromatic ring species with the abietane and occasionally pimarane skeletons. The saturated structures were comprised primarily of the abietane and pimarane skeletons having from three to five carbon (C1, C2, etc.) substituents. Kaurane and phyllocladane isomers were present in only minor amounts. Bicyclic sesquiterpenoids as saturated and partial or fully aromatized forms were also common in these samples, but only traces of sesterterpenoids and triterpenoid derivatives were found. The brown coal extracts were composed of major amounts of one- and two-ring aromatized terpenoids, with a greater proportion of triterpenoid derivatives than in the case of the woods and ambers. This was especially noticeable for the German coal, where the triterpenoids were predominant. Open C-ring aromatized structures were also present in this coal. Steroid compounds were not detectable, but some hopanes were found as minor components in the German brown coal. An overview of the skeletal structure classes identified in each sample, as well as the general mass spectrometric characteristics of the unknown compounds are included in the present paper. It can be concluded from these structural distributions that aromatization is the main process for the

  17. Water impacts of CO2 emission performance standards for fossil fuel-fired power plants.

    PubMed

    Talati, Shuchi; Zhai, Haibo; Morgan, M Granger

    2014-10-21

    We employ an integrated systems modeling tool to assess the water impacts of the new source performance standards recently proposed by the U.S. Environmental Protection Agency for limiting CO2 emissions from coal- and gas-fired power plants. The implementation of amine-based carbon capture and storage (CCS) for 40% CO2 capture to meet the current proposal will increase plant water use by roughly 30% in supercritical pulverized coal-fired power plants. The specific amount of added water use varies with power plant and CCS designs. More stringent emission standards than the current proposal would require CO2 emission reductions for natural gas combined-cycle (NGCC) plants via CCS, which would also increase plant water use. When examined over a range of possible future emission standards from 1100 to 300 lb CO2/MWh gross, new baseload NGCC plants consume roughly 60-70% less water than coal-fired plants. A series of adaptation approaches to secure low-carbon energy production and improve the electric power industry's water management in the face of future policy constraints are discussed both quantitatively and qualitatively. PMID:25229670

  18. Water impacts of CO2 emission performance standards for fossil fuel-fired power plants.

    PubMed

    Talati, Shuchi; Zhai, Haibo; Morgan, M Granger

    2014-10-21

    We employ an integrated systems modeling tool to assess the water impacts of the new source performance standards recently proposed by the U.S. Environmental Protection Agency for limiting CO2 emissions from coal- and gas-fired power plants. The implementation of amine-based carbon capture and storage (CCS) for 40% CO2 capture to meet the current proposal will increase plant water use by roughly 30% in supercritical pulverized coal-fired power plants. The specific amount of added water use varies with power plant and CCS designs. More stringent emission standards than the current proposal would require CO2 emission reductions for natural gas combined-cycle (NGCC) plants via CCS, which would also increase plant water use. When examined over a range of possible future emission standards from 1100 to 300 lb CO2/MWh gross, new baseload NGCC plants consume roughly 60-70% less water than coal-fired plants. A series of adaptation approaches to secure low-carbon energy production and improve the electric power industry's water management in the face of future policy constraints are discussed both quantitatively and qualitatively.

  19. Accelerating progress toward operational excellence of fossil energy plants with CO2 capture

    SciTech Connect

    Zitney, S.; Liese, E.; Mahapatra, P.; Turton, R. Bhattacharyya, D.

    2012-01-01

    To address challenges in attaining operational excellence for clean energy plants, the National Energy Technology Laboratory has launched a world-class facility for Advanced Virtual Energy Simulation Training And Research (AVESTARTM). The AVESTAR Center brings together state-of-the-art, real-time, high-fidelity dynamic simulators with operator training systems and 3D virtual immersive training systems into an integrated energy plant and control room environment. This paper will highlight the AVESTAR Center simulators, facilities, and comprehensive training, education, and research programs focused on the operation and control of an integrated gasification combined cycle power plant (IGCC) with carbon dioxide capture.

  20. Climate-vegetation modelling and fossil plant data suggest low atmospheric CO2 in the late Miocene

    NASA Astrophysics Data System (ADS)

    Forrest, M.; Eronen, J. T.; Utescher, T.; Knorr, G.; Stepanek, C.; Lohmann, G.; Hickler, T.

    2015-06-01

    There is increasing need to understand the pre-Quaternary warm climates, how climate-vegetation interactions functioned in the past, and how we can use this information for understanding the present. Here we report vegetation modelling results for the Late Miocene (11-7 Ma) to study the mechanisms of vegetation dynamics and the role of different forcing factors that influence the spatial patterns of vegetation coverage. One of the key uncertainties is the atmospheric concentration of CO2 during past climates. Estimates for the last 20 million years range from 280 to 500 ppm. We simulated Late Miocene vegetation using two plausible CO2 concentrations, 280 and 450 ppm CO2, with a dynamic global vegetation model (LPJ-GUESS) driven by climate input from a coupled AOGCM (Atmosphere-Ocean General Circulation Model). The simulated vegetation was compared to existing plant fossil data for the whole Northern Hemisphere. For the comparison we developed a novel approach that uses information of the relative dominance of different Plant Functional Types (PFTs) in the palaeobotanical data to provide a quantitative estimate of the agreement between the simulated and reconstructed vegetation. Based on this quantitative assessment we find that pre-industrial CO2 levels are largely consistent with the presence of seasonal temperate forests in Europe (suggested by fossil data) and open vegetation in North America (suggested by multiple lines of evidence). This suggests that during the Late Miocene the CO2 levels have been relatively low, or that other factors that are not included in the models maintained the seasonal temperate forests and open vegetation.

  1. Climate-vegetation modelling and fossil plant data suggest low atmospheric CO2 in the late Miocene

    NASA Astrophysics Data System (ADS)

    Forrest, M.; Eronen, J. T.; Utescher, T.; Knorr, G.; Stepanek, C.; Lohmann, G.; Hickler, T.

    2015-12-01

    There is an increasing need to understand the pre-Quaternary warm climates, how climate-vegetation interactions functioned in the past, and how we can use this information to understand the present. Here we report vegetation modelling results for the Late Miocene (11-7 Ma) to study the mechanisms of vegetation dynamics and the role of different forcing factors that influence the spatial patterns of vegetation coverage. One of the key uncertainties is the atmospheric concentration of CO2 during past climates. Estimates for the last 20 million years range from 280 to 500 ppm. We simulated Late Miocene vegetation using two plausible CO2 concentrations, 280 ppm CO2 and 450 ppm CO2, with a dynamic global vegetation model (LPJ-GUESS) driven by climate input from a coupled AOGCM (Atmosphere-Ocean General Circulation Model). The simulated vegetation was compared to existing plant fossil data for the whole Northern Hemisphere. For the comparison we developed a novel approach that uses information of the relative dominance of different plant functional types (PFTs) in the palaeobotanical data to provide a quantitative estimate of the agreement between the simulated and reconstructed vegetation. Based on this quantitative assessment we find that pre-industrial CO2 levels are largely consistent with the presence of seasonal temperate forests in Europe (suggested by fossil data) and open vegetation in North America (suggested by multiple lines of evidence). This suggests that during the Late Miocene the CO2 levels have been relatively low, or that other factors that are not included in the models maintained the seasonal temperate forests and open vegetation.

  2. Some in situ fossil plants in Late Paleozoic rocks, eastern U. S. A

    SciTech Connect

    Cross, A.T. )

    1991-01-01

    Plants entombed in growth position are generally represented by standing stumps. Rarely, leaves or fronds may also represent plants buried in place. Stemps are most often seen in surface coal mine highwalls and highway cuts. Occasionally they are also found in association with sandstone cliffs. When present in coal-bearing sequences they are most often rooted in the top of the coal and may extend upward through several successive increments of sediments representing point-bar or overbank deposits in deltaic or fluvial depositional environments. Some standing logs in sandstones represent burial by washover fans or transgressive bars. Interpretation of the life environment of the plants and the successive environments in which the sediments that engulfed the plants were deposited demonstrated their paleoenvironment.

  3. Plant hemoglobins: a molecular fossil record for the evolution of oxygen transport.

    PubMed

    Hoy, Julie A; Robinson, Howard; Trent, James T; Kakar, Smita; Smagghe, Benoit J; Hargrove, Mark S

    2007-08-01

    The evolution of oxygen transport hemoglobins occurred on at least two independent occasions. The earliest event led to myoglobin and red blood cell hemoglobin in animals. In plants, oxygen transport "leghemoglobins" evolved much more recently. In both events, pentacoordinate heme sites capable of inert oxygen transfer evolved from hexacoordinate hemoglobins that have unrelated functions. High sequence homology between hexacoordinate and pentacoordinate hemoglobins in plants has poised them for potential structural analysis leading to a molecular understanding of this important evolutionary event. However, the lack of a plant hexacoordinate hemoglobin structure in the exogenously ligand-bound form has prevented such comparison. Here we report the crystal structure of the cyanide-bound hexacoordinate hemoglobin from barley. This presents the first opportunity to examine conformational changes in plant hexacoordinate hemoglobins upon exogenous ligand binding, and reveals structural mechanisms for stabilizing the high-energy pentacoordinate heme conformation critical to the evolution of reversible oxygen binding hemoglobins.

  4. Plant Hemoglobins: A Molecular Fossil Record for the Evolutin of Oxygen Transport

    SciTech Connect

    Hoy,J.; Robinson, H.; Trent, lll, J.; Kakar, S.; Smagghe, B.; Hargrove, M.

    2007-01-01

    The evolution of oxygen transport hemoglobins occurred on at least two independent occasions. The earliest event led to myoglobin and red blood cell hemoglobin in animals. In plants, oxygen transport 'leghemoglobins' evolved much more recently. In both events, pentacoordinate heme sites capable of inert oxygen transfer evolved from hexacoordinate hemoglobins that have unrelated functions. High sequence homology between hexacoordinate and pentacoordinate hemoglobins in plants has poised them for potential structural analysis leading to a molecular understanding of this important evolutionary event. However, the lack of a plant hexacoordinate hemoglobin structure in the exogenously ligand-bound form has prevented such comparison. Here we report the crystal structure of the cyanide-bound hexacoordinate hemoglobin from barley. This presents the first opportunity to examine conformational changes in plant hexacoordinate hemoglobins upon exogenous ligand binding, and reveals structural mechanisms for stabilizing the high-energy pentacoordinate heme conformation critical to the evolution of reversible oxygen binding hemoglobins.

  5. Water resources of Allen Parish

    USGS Publications Warehouse

    Prakken, Lawrence B.; Griffith, Jason M.; Fendick, Robert B.

    2012-01-01

    In 2005, approximately 29.2 million gallons per day (Mgal/d) of water were withdrawn in Allen Parish, Louisiana, including about 26.8 Mgal/d from groundwater sources and 2.45 Mgal/d from surface-water sources. Rice irrigation accounted for 74 percent (21.7 Mgal/d) of the total water withdrawn. Other categories of use included public supply, industrial, rural domestic, livestock, general irrigation, and aquaculture. Water-use data collected at 5-year intervals from 1960 to 2005 indicate water withdrawals in the parish were greatest in 1960 (119 Mgal/d) and 1980 (98.7 Mgal/d). The substantial decrease in surface-water use between 1960 and 1965 is primarily attributable to rice-irrigation withdrawals declining from 61.2 to 6.74 Mgal/d. This fact sheet summarizes information on the water resources of Allen Parish, La. Information on groundwater and surface-water availability, quality, development, use, and trends is based on previously published reports listed in the Selected References section.

  6. Fossil plant stomata indicate decreasing atmospheric CO2 prior to the Eocene-Oligocene boundary

    NASA Astrophysics Data System (ADS)

    Steinthorsdottir, Margret; Porter, Amanda S.; Holohan, Aidan; Kunzmann, Lutz; Collinson, Margaret; McElwain, Jennifer C.

    2016-02-01

    A unique stratigraphic sequence of fossil leaves of Eotrigonobalanus furcinervis (extinct trees of the beech family, Fagaceae) from central Germany has been used to derive an atmospheric pCO2 record with multiple data points spanning the late middle to late Eocene, two sampling levels which may be earliest Oligocene, and two samples from later in the Oligocene. Using the inverse relationship between the density of stomata and pCO2, we show that pCO2 decreased continuously from the late middle to late Eocene, reaching a relatively stable low value before the end of the Eocene. Based on the subsequent records, pCO2 in parts of the Oligocene was similar to latest Eocene values. These results suggest that a decrease in pCO2 preceded the large shift in marine oxygen isotope records that characterizes the Eocene-Oligocene transition and that when a certain threshold of pCO2 change was crossed, the cumulative effects of this and other factors resulted in rapid temperature decline, ice build up on Antarctica and hence a change of climate mode.

  7. Fossil plant stomata indicate decreasing atmospheric CO2 prior to the Eocene-Oligocene boundary

    NASA Astrophysics Data System (ADS)

    Steinthorsdottir, M.; Porter, A. S.; Holohan, A.; Kunzmann, L.; Collinson, M.; McElwain, J. C.

    2015-10-01

    A unique stratigraphic sequence of fossil leaves of Eotrigonobalanus furcinervis (extinct trees of the beech family, Fagaceae) from central Germany has been used to derive an atmospheric pCO2 record with multiple data points spanning the late middle to late Eocene, two sampling levels which may be earliest Oligocene, and two samples from later in the Oligocene. Using the inverse relationship between the density of stomata and pCO2, we show that pCO2 decreased continuously from the late middle to late Eocene, reaching a relatively stable low value before the end of the Eocene. Based on the subsequent records, pCO2 in parts of the Oligocene was similar to latest Eocene values. These results show that a decrease in pCO2 preceded the large shift in marine oxygen isotope records that characterizes the Eocene-Oliogocene transition. This may be related to the "hysteresis effect" previously proposed - where a certain threshold of pCO2 change was crossed before the cumulative effects of this and other factors resulted in rapid temperature decline, ice build up on Antarctica and hence a change of climate mode.

  8. Aging management of fossil-fired plants of Electricite de France: PVP maintenance aspects

    SciTech Connect

    Thoraval, G.

    1995-12-01

    The generation mix of EDF comprises 17,000 MW of fossil-fired units, the ages of which go from 10 to 32 years. Extensive studies have been launched in 1994, inside the Company, to determine: (1) prospects of needs of the grid (domestic/exports); (2) prospects of possible competition in generation field; (3) environmental aspects and possible evolution; (4) adaptation of management of men and organizations; and (5) management of condition of equipment through maintenance policy. This paper focuses on the last item, spotted on pressure vessels and piping. The question is: How to conserve the ``patrimony`` for very long term, with lowest costs to keep it competitive in its very specific role? Several items are examined: (1) the background, the different programs of retrofitting, refurbishment and life extension; (2) conservation during outages, and mothballing procedures and experience; (3) design review, actual design life expectancy; (4) analysis of aging mechanisms through experience feedback; (5) determination of critical components, analysis of their condition, periodical updating; (6) maintenance adaptation, extensive condition-monitored maintenance approach: use of existing probes and data, development of new devices and skills; (7) policy of progressive replacement of worn-out and potentially dangerous components; examples concerning generic problems; (8) management of requirements of pressure vessels regulations; (9) adaptation of spare parts policy; and (10) research and development needed by life management.

  9. Results of studies on application of CCMHD to advanced fossil fuel power plant cycles

    SciTech Connect

    Foote, J.P.; Wu, Y.C.L.S.; Lineberry, J.T.

    1998-07-01

    A study was conducted to assess the potential for application of a Closed Cycle MHD disk generator (CCMHD) in advanced fossil fuel power generation systems. Cycle analyses were conducted for a variety of candidate power cycles, including simple cycle CCMHD (MHD); a cycle combining CCMHD and gas turbines (MHD/GT); and a triple combined cycle including CCMHD, gas turbines, and steam turbines (MHD/GT/ST). The above cycles were previously considered in cycle studies reported by Japanese researchers. Also considered was a CCMHD cycle incorporating thermochemical heat recovery through reforming of the fuel stream (MHD/REF), which is the first consideration of this approach. A gas turbine/steam turbine combined cycle (GT/ST) was also analyzed for baseline comparison. The only fuel considered in the study was CH4. Component heat and pressure losses were neglected, and the potential for NOx emission due to high combustion temperatures was not considered. Likewise, engineering limitations for cycle components, particularly the high temperature argon heater, were not considered. This approach was adopted to simplify the analysis for preliminary screening of candidate cycles. Cycle calculations were performed using in-house code. Ideal gas thermodynamic properties were calculated using the NASA SP- 273 data base, and thermodynamic properties for steam were calculated using the computerized ASME Steam Tables. High temperature equilibrium compositions for combustion gas were calculated using tabulated values of the equilibrium constants for the important reactions.

  10. Optimizing efficiency of zebra mussel monitoring at TVA power plants

    SciTech Connect

    Kerley, B.L.

    1995-06-01

    The Tennessee Valley Authority (TVA) began monitoring for zebra mussels in spring 1992 and first detected veligers entering plant intake at Shawnee, Allen and Cumberland Fossil Plans in summer 1993. Existing information indicated that densities of zebra mussel veligers at plant intakes did not always correspond to densities in critical pipe units; however, a more accurate predictive technique was unavailable. The two sites chosen for this project were Shawnee Fossil Plant on the Ohio River and Allen Fossil Plant on the Mississippi River. The project involved a coordinated series of experiments to determine how densities of zebra mussel veligers varied throughout the day, how veliger densities estimated outside the plants related to estimates at different internal locations, and how growth rate of adult zebra mussels compared using measurements taken inside and outside the plants and from the two different rivers. The data indicated no significant difference in veliger densities from samples collected at the intakes and samples collected inside the plants. There was also no significant difference in densities between samples collected inside the plants. There was also no significant difference in densities between samples taken at different times of the day. The data did indicate a significant difference in density estimates between samples collected on different days and between densities in the rivers compared to densities being drawn into the plant. The results will be used to assist plant staff in evaluating future data and in planning a more effective and cost efficient monitoring program.

  11. "Fossil" Forecasting.

    ERIC Educational Resources Information Center

    Brody, Michael J.; deOnis, Ann

    2001-01-01

    Presents a density study in which students calculate the density of limestone substrate to determine if the specimen contains any fossils. Explains how to make fossils and addresses national standards. (YDS)

  12. Paleovegetation changes recorded by n-alkyl lipids bound in macromolecules of plant fossils and kerogens from the Cretaceous sediments in Japan

    NASA Astrophysics Data System (ADS)

    Miyata, Y.; Sawada, K.; Nakamura, H.; Takashima, R.; Takahashi, M.

    2014-12-01

    Resistant macromolecules composing living plant tissues tend to be preserved through degradation and diagenesis, hence constituate major parts of sedimentary plant-derived organic matter (kerogen), and their monomer compositions vary widely among different plant taxa, organs and growth stages. Thus, analysis of such macromolecule may serve as new technique for paleobotanical evaluation distinctive from classical paleobotnical studies depends on morphological preservation of fossils. In the present study, we analyzed plant fossils and kerogens in sediments from the Cretaceous strata in Japan to examine chemotaxonomic characteristics of fossil macromolecules and to reconstruct paleovegetation change by kerogen analysis. The kerogens were separated from the powdered sediments of Cretaceous Yezo Group, Hokkaido, Japan. All kerogens have been confirmed to be mostly originated from land plant tissues by microscopic observation. Mummified angiosperm and gymnosperm fossil leaves were separated from carbonaceous sandstone of the Cretaceous Ashizawa Formation, Futaba Group. The kerogens and plant fossils were extracted with methanol and dichloromethane, and were subsequently refluxed under 110°C to remove free compounds completely. The residues are hydrolyzed by KOH/methanol under 110°C. These released compounds are analyzed by GC-MS. As main hydrolyzed products (ester-bound molecular units) from all kerogens, C10-C28 n-alkanoic acids and C10-C30 n-alkanols were detected. Recent studies on the hydrolysis products of plant tissues suggested the long chain (>C20) n-alkanols were predominantly abundant in deciduous broadleaved angiosperms. Correspondingly, the stratigraphic variation of the ratios of long chain (>C20) n-alkanols to fatty acids was concordant with the variation of angiosperm/gymnosperm ratios recorded by land plant-derived terpenoid biomarkers. In addition, we found that the long chain n-alkanols/fatty acids ratio in the angiosperm fossil leaf was

  13. Fossil Explorers

    ERIC Educational Resources Information Center

    Moran, Sean; McLaughlin, Cheryl; MacFadden, Bruce; Jacobbe, Elizabeth; Poole, Michael

    2015-01-01

    Many young learners are fascinated with fossils, particularly charismatic forms such as dinosaurs and giant sharks. Fossils provide tangible, objective evidence of life that lived millions of years ago. They also provide a timescale of evolution not typically appreciated by young learners. Fossils and the science of paleontology can, therefore,…

  14. Marquee Fossils

    ERIC Educational Resources Information Center

    Clary, Renee; Wandersee, James

    2008-01-01

    Professors of an online graduate-level paleontology class developed the concept of marquee fossils--fossils that have one or more unique characteristics that capture the attention and direct observation of students. In the classroom, Marquee fossils integrate the geology, biology, and environmental science involved in the study of fossilized…

  15. Plant and insect fossils at Norwood in south-central Minnesota: A record of late-glacial succession*1

    NASA Astrophysics Data System (ADS)

    Ashworth, Allan C.; Schwert, Donald P.; Watts, William A.; Wright, H. E.

    1981-07-01

    The Norwood site in Sibley Co., Minnesota, contains 1.6 m of silt resting on till and overlain by peat. The base of the peat has been radiocarbon dated at 12,400 ± 60 and the top at 11,200 ± 250 yr B.P. The pollen, plant macrofossils, and insect remains in the basal silt consist of boreal species inhabiting open environments, but not tundra. No modern analogue exists for the insect assemblage, which includes elements of boreal forest, tundra-forest, and western affinities. The transition from an unstable open environment to a stable coniferous forest is reflected by both plant and insect fossils and is interpreted as a successional rather than a climatic event. During this time of significant biologic change, the climate is inferred to have been relatively uniform, with temperatures similar to those presently existing in the boreal forest south of the tundra-forest transition zone. The geologic and ecologic succession at Norwood is generally similar to that presently associated with ice stagnation of the Klutlan Glacier in the Yukon Territory. Localized successional sequences similar to those at Norwood are conceived to have occurred repeatedly during the melting of the Laurentide ice, and thus the proposed model has potentially broad application to the interpretation of late-glacial sequences.

  16. Fossil-fuel power plants: Computer systems for power plant control, maintenance, and operation. October 1976-December 1989 (A Bibliography from the COMPENDEX data base). Report for October 1976-December 1989

    SciTech Connect

    Not Available

    1990-02-01

    This bibliography contains citations concerning fossil-fuel power plant computer systems. Minicomputer and microcomputer systems used for monitoring, process control, performance calculations, alarming, and administrative applications are discussed. Topics emphasize power plant control, maintenance and operation. (Contains 240 citations fully indexed and including a title list.)

  17. Crystallization and Preliminary X-ray Analysis of Allene Oxide Synthase, Cytochrome P450 CYP74A2, from Parthenium argentatum

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Oxylipins are oxygenated derivatives of fatty acids and pivotal signaling molecules in plants and animals. Allene oxide synthase (AOS) is a key cytochrome P450 CYP74 enzyme involved in the biosynthesis of plant oxylipin jasmonates to convert 13(S)-hydroperoxide to allene oxide. Guayule (Parthenium a...

  18. Cost and Quality Management: Making fossil power and plants more competitive: Phase 1. Final report

    SciTech Connect

    McQueen, R.S.

    1992-05-01

    Cost and Quality Management theory is helping to make US corporations profitable again. Summarizing Phase 1 of a three-phase study, this report defines how Cost and Quality Management (also called Total Quality Management) relates to power production plants, the barriers standing in the way, and the concepts needed to overcome them. Major barriers include resistance to change, sparse efforts to grow employee initiative and self-esteem, a lack of understanding the importance of internal customers, and traditional management practices as represented by the top-to-bottom organization chart. Breakthrough concepts include a commitment to making and sustaining quality-based changes, realizing the potential of human assets, focusing on satisfying internal as well as external customers, and treating work as a process that crosses departments. The report ends by describing five other ongoing EPRI projects designed to help utility executives change from a traditional management style to Cost and Quality Management.

  19. Cost and Quality Management: Making fossil power and plants more competitive: Phase 1

    SciTech Connect

    McQueen, R.S. . Center for Productivity and Mfg. Engineering)

    1992-05-01

    Cost and Quality Management theory is helping to make US corporations profitable again. Summarizing Phase 1 of a three-phase study, this report defines how Cost and Quality Management (also called Total Quality Management) relates to power production plants, the barriers standing in the way, and the concepts needed to overcome them. Major barriers include resistance to change, sparse efforts to grow employee initiative and self-esteem, a lack of understanding the importance of internal customers, and traditional management practices as represented by the top-to-bottom organization chart. Breakthrough concepts include a commitment to making and sustaining quality-based changes, realizing the potential of human assets, focusing on satisfying internal as well as external customers, and treating work as a process that crosses departments. The report ends by describing five other ongoing EPRI projects designed to help utility executives change from a traditional management style to Cost and Quality Management.

  20. Phosphine Catalysis of Allenes with Electrophiles

    PubMed Central

    Wang, Zhiming; Xu, Xingzhu; Kwon, Ohyun

    2014-01-01

    Nucleophilic phosphine catalysis of allenes with electrophiles is one of the most powerful and straightforward synthetic strategies for the generation of highly functionalized carbocycle or heterocycle structural motifs, which are present in a wide range of bioactive natural products and medicinally important substances. The reaction topologies can be controlled through judicious choice of the phosphine catalyst and the structural variations of starting materials. This Tutorial Review presents selected examples of nucleophilic phosphine catalysis using allenes and electrophiles. PMID:24663290

  1. Mapping Regional Patterns of Fossils Fuel CO2 in the Planetary Boundary Layer Across North America Using Radiocarbon in Annual Plants

    NASA Astrophysics Data System (ADS)

    Hsueh, D. Y.; Randerson, J. T.; Southon, J. R.; Trumbore, S. E.

    2004-12-01

    Radiocarbon levels in annual plants provide a means to map out regional and continental-scale patterns of fossil fuel emissions and biosphere-atmosphere exchange. The imprint of the local atmosphere is recorded within the leaves of these annual plants and represents a time-integral of atmospheric levels over a period of several months, complementing both flask and aircraft sampling techniques. Working with colleagues, we collected corn (Zea mays) from approximately 70 sites across North America. We designed a sampling protocol that captured regional and continental scale patterns of fossil fuel CO2 levels; we specifically avoided areas directly influenced by point sources such as major roads or cities. We then analyzed the leaves in the W.M. Keck Carbon Cycle Accelerator Mass Spectrometer at the University of California, Irvine. In areas where the corn plants were exposed to sustained and elevated levels of CO2 from fossil fuel emissions, such as the Ohio Valley, the 14C/12C ratio of the corn leaves was reduced. We found that there was a drop of approximately 15 per mil between the western U.S. (Alberta, Idaho, Colorado and New Mexico) and the Northeastern U.S. (Ohio, Maryland and Pennsylvania). This corresponds to approximately 5 ppm increase in fossil fuel CO2 levels, as air moves from west to east across the continent. These data provide a means to test our understanding of the coupling of biosphere atmosphere exchange, planetary boundary layer mixing, atmospheric transport, and fossil fuel emissions in mesoscale and global models that are used to estimate the spatial distribution of carbon sources and sinks.

  2. Novel Dual-Functional Membrane for Controlling Carbon Dioxide Emissions from Fossil Fuel Power Plants

    SciTech Connect

    C. Brinker; George Xomeritakis; C.-Y. Tsai; Ying-Bing Jiang

    2009-04-30

    CO{sub 2} captured from coal-fired power plants represents three-quarters of the total cost of an entire carbon sequestration process. Conventional amine absorption or cryogenic separation requires high capital investment and is very energy intensive. Our novel membrane process is energy efficient with great potential for economical CO{sub 2} capture. Three classes of microporous sol-gel derived silica-based membranes were developed for selective CO{sub 2} removal under simulated flue gas conditions (SFG), e.g. feed of 10% vol. CO{sub 22} in N{sub 2}, 1 atm total pressure, T = 50-60 C, RH>50%, SO2>10 ppm. A novel class of amine-functional microporous silica membranes was prepared using an amine-derivatized alkoxysilane precursor, exhibiting enhanced (>70) CO{sub 2}:N{sub 2} selectivity in the presence of H{sub 2}O vapor, but its CO{sub 2} permeance was lagging (<1 MPU). Pure siliceous membranes showed higher CO{sub 2} permeance (1.5-2 MPU) but subsequent densification occurred under prolonged SFG conditions. We incorporated NiO in the microporous network up to a loading of Ni:Si = 0.2 to retard densification and achieved CO2 permeance of 0.5 MPU and CO{sub 2}:N{sub 2} selectivity of 50 after 163 h exposure to SFG conditions. However, CO{sub 2} permeance should reach greater than 2.0 MPU in order to achieve the cost of electricity (COE) goal set by DOE. We introduced the atomic layer deposition (ALD), a molecular deposition technique that substantially reduces membrane thickness with intent to improve permeance and selectivity. The deposition technique also allows the incorporation of Ni or Ag cations by proper selection of metallorganic precursors. In addition, preliminary economic analysis provides a sensitivity study on the performance and cost of the proposed membranes for CO{sub 2} capture. Significant progress has been made toward the practical applications for CO{sub 2} capture. (1 MPU = 1.0 cm{sup 3}(STP){center_dot}cm-2{center_dot}min-1{center_dot}atm-1)

  3. Van Allen Discovery Most Important

    NASA Technical Reports Server (NTRS)

    Jastrow, R.

    1959-01-01

    The first step toward the exploration of space occurred approximately 22 months ago as a part of the International Geophysical Year. In the short interval since October, 1957, the new tools of research, the satellite and the space rocket, have produced two unexpected results of fundamental scientific importance. First, instruments placed in the Explorer satellites by James A. Van Allen have revealed the existence of layers of energetic particles in the outer atmosphere. This discovery constitutes the most significant research achievement of the IGY satellite program. The layers may provide the explanation for the aurora and other geophysical phenomena, and they will also influence the design of vehicles for manned space flight, whose occupants must be shielded against their harmful biological effects. Second, the shape of the earth has been determined very accurately with the aid of data from the first Vanguard. As a result of this investigation, we have found that our planet tends toward the shape of a pear, with its stem at the North Pole. This discovery may produce major changes in our ideas on the interior structure of the earth.

  4. Fossil Fuels.

    ERIC Educational Resources Information Center

    Crank, Ron

    This instructional unit is one of 10 developed by students on various energy-related areas that deals specifically with fossil fuels. Some topics covered are historic facts, development of fuels, history of oil production, current and future trends of the oil industry, refining fossil fuels, and environmental problems. Material in each unit may…

  5. Ediacara Fossils

    ERIC Educational Resources Information Center

    Science Teacher, 2005

    2005-01-01

    Now, a research team from Virginia Tech and Nanjing Institute of Geology and Paleontology has discovered uniquely well-preserved fossil forms from 550-million-year-old rocks of the Ediacaran Period. The research appears in the Proceedings of the National Academy of Sciences. The discovery of these unusually preserved fossils reveals unprecedented…

  6. Fossil spiders.

    PubMed

    Selden, Paul A; Penney, David

    2010-02-01

    Over the last three decades, the fossil record of spiders has increased from being previously biased towards Tertiary ambers and a few dubious earlier records, to one which reveals a much greater diversity in the Mesozoic, with many of the modern families present in that era, and with clearer evidence of the evolutionary history of the group. We here record the history of palaeoarachnology and the major breakthroughs which form the basis of studies on fossil spiders. Understanding the preservation and taphonomic history of spider fossils is crucial to interpretation of fossil spider morphology. We also review the more recent descriptions of fossil spiders and the effect these discoveries have had on the phylogenetic tree of spiders. We discuss some features of the evolutionary history of spiders and present ideas for future work.

  7. Fate of As, Se, and Hg in a Passive Integrated System for Treatment of Fossil Plant Wastewater

    SciTech Connect

    Terry Yost; Paul Pier; Gregory Brodie

    2007-12-31

    TVA is collaborating with EPRI and DOE to demonstrate a passive treatment system for removing SCR-derived ammonia and trace elements from a coal-fired power plant wastewater stream. The components of the integrated system consist of trickling filters for ammonia oxidation, reaction cells containing zero-valent iron (ZVI) for trace contaminant removal, a settling basin for storage of iron hydroxide floc, and anaerobic vertical-flow wetlands for biological denitrification. The passive integrated treatment system will treat up to 0.25 million gallons per day (gpd) of flue gas desulfurization (FGD) pond effluent, with a configuration requiring only gravity flow to obviate the need for pumps. The design of the system will enable a comparative evaluation of two parallel treatment trains, with and without the ZVI extraction trench and settling/oxidation basin components. One of the main objectives is to gain a better understanding of the chemical transformations that species of trace elements such as arsenic, selenium, and mercury undergo as they are treated in passive treatment system components with differing environmental conditions. This progress report details the design criteria for the passive integrated system for treating fossil power plant wastewater as well as performance results from the first several months of operation. Engineering work on the project has been completed, and construction took place during the summer of 2005. Monitoring of the passive treatment system was initiated in October 2005 and continued until May 18 2006. The results to date indicate that the treatment system is effective in reducing levels of nitrogen compounds and trace metals. Concentrations of both ammonia and trace metals were lower than expected in the influent FGD water, and additions to increase these concentrations will be done in the future to further test the removal efficiency of the treatment system. In May 2006, the wetland cells were drained of FGD water, refilled with

  8. Miocene fossil plants from Bukpyeong Formation of Bukpyeong Basin in Donghae City, Gangwon-do Province, Korea and their palaeoenvironmental implications

    NASA Astrophysics Data System (ADS)

    Jeong, Eun Kyoung; Kim, Hyun Joo; Uemura, Kazuhiko; Kim, Kyungsik

    2016-04-01

    The Tertiary sedimentary basins are distributed along the eastern coast of Korean Peninsula. The northernmost Bukpyeong Basin is located in Donghae City, Gangwon-do Province, Korea. The Bukpyeong Basin consists of Bukpyeong Formation and Dogyeongri Conglomerate in ascending order. The geologic age of Bukpyeong Formation has been suggested as from Early Miocene to Pliocene, In particular, Lee & Jacobs (2010) suggested the age of the Bukpyeong Formation as late Early Miocene to early Middle Miocene based on the fossils of rodent teeth. Sedimentary environment has been thought as mainly fresh water lake and/or swamp partly influenced by marine water. Lately, new outcrops of Bukpyeong Formation were exposed during the road construction and abundant fossil plants were yielded from the newly exposed outcrops. As a result of palaeobotanical studies 47 genera of 23 families have been found. This fossil plant assemblage is composed of gymnosperms and dicotyledons. Gymnosperms were Pinaceae (e.g., Pinus, Tsuga), Sciadopityaceae (e.g., Sciadopitys) and Cupressaceae with well-preserved Metasequoia cones. Dicotyledons were deciduous trees such as Betulaceae (e.g., Alnus, Carpinus) and Sapindaceae (e.g., Acer, Aesculus, Sapindus), and evergreen trees such as evergreen Fagaceae (e.g., Castanopsis, Cyclobalanopsis, Pasania) and Lauraceae (e.g., Cinnamomum, Machilus). In addition, fresh water plants such as Hemitrapa (Lytraceae) and Ceratophyllum (Ceratophyllaceae) were also found. The fossil plant assemblage of the Bukpyeong Formation supported the freshwater environment implied by previous studies. It can be suggested that the palaeoflora of Bukpyeong Formation was oak-laurel forest with broad-leaved evergreen and deciduous trees accompanying commonly by conifers of Pinaceae and Cupressaceae under warm-temperate climate.

  9. Electrophilic addition and cyclization reactions of allenes.

    PubMed

    Ma, Shengming

    2009-10-20

    Modern organic synthesis depends on the development of highly selective methods for the efficient construction of potentially useful target molecules. A primary goal in our laboratory is the discovery of new reactions that convert readily available starting materials to complex products with complete control of regio- and stereoselectivity. Allenes are one underused moiety in organic synthesis, because these groups are often thought to be highly reactive. However, many compounds containing the allene group, including natural products and pharmaceuticals, are fairly stable. The chemistry of allenes has been shown to have significant potential in organic synthesis. Electrophilic additions to allenes have often been considered to be synthetically less attractive due to the lack of efficient control of the regio- and stereoselectivity. However, this Account describes electrophilic reactions of allenes with defined regio- and stereoselectivity developed in our laboratory. Many substituted allenes are readily available from propargylic alcohols. Our work has involved an exploration of the reactions of these allenes with many different electrophiles: the E- or Z-halo- or seleno-hydroxylations of allenyl sulfoxides, sulfones, phosphine oxides, carboxylates, sulfides or selenides, butenolides, and arenes, and the halo- or selenolactonization reactions of allenoic acids and allenoates. These reactions have produced a host of new compounds such as stereodefined allylic alcohols, ethers, amides, thiiranes, and lactones. In all these reactions, water acts as a reactant and plays an important role in determining the reaction pathway and the stereoselectivity. The differing electronic properties of the two C=C bonds in these allenes determine the regioselectivity of these reactions. Through mechanistic studies of chirality transfer, isolation and reactivity of cyclic intermediates, (18)O-labeling, and substituent effects, we discovered that the E-stereoselectivity of some

  10. Plant materials and amendments for controlling wind and water erosion on a fly ash disposal area: TVA Colbert Fossil Plant, Alabama

    SciTech Connect

    Maddox, J.J.; Behel, D.; Soileau, J.M.; Kelsoe, J.

    1996-12-31

    Fly ash disposal sites adjacent to fossil fueled generating plants are subject to wind and water erosion which increases the operation and maintenance costs. Gullies and unstable areas in the disposal sites require expensive leveling and filling practices. Test evaluated both warm- and cool-season cover crops established by either sod or seed. Amendments to the ash consisted of composted poultry litter (CPL), soil, soil+CPL, fertilizer and beneficial soil microbes including mycorrhizal fungi. Turf sods (419 Bermuda, Emerald zoysia, and Raleigh St. Augustine) were compared in greenhouse and field studies. Six legumes and 12 grass species were tested in the greenhouse as seeded cover crops using similar amendments and raw poultry litter (PL). Legumes grew better with CPL and Boil amendments and grasses grew better on PL and soil amendments possibly due to differences in N requirements and N supply. Cool season crops generally grew faster than warm season species in the greenhouse tests. Amendments should be mixed with the FA to ameliorate the effects of boron and salt toxicity and to increase the water holding capacity. Bermuda sod grew faster than either St, Augustine or Emerald zoysia, but requires more water. A microbial amendment increased dry matter yields of bermuda sod 2 to 3 times after 40 to 60 days over unamended controls. Microbial amendments may be justified on an economic and sustainable basis. A field study is assessing the environmental and cultural requirements to grow a cover crop on an annual basis.

  11. Preparation of allenic sulfones and allenes from the selenosulfonation of acetylenes

    SciTech Connect

    Back, T.G.; Krishna, M.V.; Muralidharan, K.R. )

    1989-08-18

    {beta}-(phenylseleno)vinyl sulfones 2 are readily obtained from the free-radical selenosulfonation of acetylenes. Compounds 2 isomerize to allyl sulfones 4 under base-catalyzed conditions in nearly quantitative yield, with high stereoselectivity favoring the Z configuration. Allyl sulfones 4 afford generally high yields of allenic sulfones 1 when subjected to oxidation with m-chloroperbenzoic acid or tert-butyl hydroperoxide, followed by selenoxide syn-elimination. The sulfone-stabilized anion intermediates in the isomerizations of 2 to 4 can be alkylated, deuterated, or silylated in the {alpha}-position prior to oxidation, providing allenic sulfones with an additional {alpha}-substituent. In some cases, spontaneous elimination of the phenylseleno group occurred, producing the allenic sulfone without the need for an oxidation step. Desulfonylation of allyl sulfones 4f, 4c, and 25 with sodium amalgam afforded vinyl selenides that were converted to allenes in moderate to good yields by oxidation-elimination. The copper-catalyzed coupling of allyl sulfones 4 with Grignard reagents comprises an alternative route to vinyl selenide precursors of allenes. These procedures permit the synthesis of various {alpha}- and {gamma}-substituted allenic sulfones and allenes from acetylenes.

  12. Mechanisms of allene stereoinversion by imidozirconium complexes.

    PubMed

    Michael, Forrest E; Duncan, Andrew P; Sweeney, Zachary K; Bergman, Robert G

    2003-06-18

    The zirconium-mediated stereoinversion of allenes has been investigated by studying the stereochemical behavior of metallacycles derived from [2 + 2] cycloaddition of enantioenriched allenes with chiral and achiral imidozirconocene complexes. Relative rates of metallacycle racemization were measured by circular dichroism, and intermediates in the selective stereoinversion of diphenylallene with a chiral imidozirconium complex were observed by NMR spectroscopy. Metallacycles derived from dialkylallenes are proposed to racemize via reversible beta-hydride elimination. Stereoinversion of diarylallene-derived metallacycles proceeds much more slowly and is thought to proceed through an eta4-azatrimethylenemethane transition state.

  13. New insights into the Weichselian environment and climate of the East Siberian Arctic, derived from fossil insects, plants, and mammals

    NASA Astrophysics Data System (ADS)

    Sher, A. V.; Kuzmina, S. A.; Kuznetsova, T. V.; Sulerzhitsky, L. D.

    2005-03-01

    Multidisciplinary study of a key section on the Laptev Sea Coast (Bykovsky Peninsula, east Lena Delta) in 1998-2001 provides the most complete record of Middle and Late Weichselian environments in the East Siberian Arctic. The 40-m high Mamontovy Khayata cliff is a typical Ice Complex section built of icy silts with a network of large syngenetic polygonal ice wedges, and is richly fossiliferous. In combination with pollen, plant macrofossil and mammal fossils, a sequence of ca 70 insect samples provides a new interpretation of the environment and climate of the area between ca 50 and 12 ka. The large number of radiocarbon dates from the section, together with an extensive 14C database on mammal bones, allows chronological correlation of the various proxies. The Bykovsky record shows how climate change, and the Last Glacial Maximum in particular, affected terrestrial organisms such as insects and large grazing mammals. Both during the presumed "Karginsky Interstadial" (MIS 3) and the Sartanian Glacial (MIS 2), the vegetation remained a mosaic arctic grassland with relatively high diversity of grasses and herbs and dominance of xeric habitats: the tundra-steppe type. This biome was supported by a constantly very continental climate, caused by low sea level and enormous extension of shelf land. Variations within the broad pattern were caused mainly by fluctuations in summer temperature, related to global trends but overprinted by the effect of continentality. No major changes in humidity were observed nor were advances of modern-type forest or forest-tundra recorded, suggesting a major revision of the "Karginsky Interstadial" paradigm. The changing subtypes of the tundra-steppe environment were persistently favourable for mammalian grazers, which inhabited the shelf lowlands throughout the studied period. Mammal population numbers were lowered during the LGM, especially toward its end, and then flourished in a short, but impressive peak in the latest Weichselian, just

  14. Recent developments in allene-based synthetic methods.

    PubMed

    Kim, Hiyun; Williams, Lawrence J

    2008-11-01

    Presented is a review of the advances in synthetic methodology that make use of the allene functional group, with emphasis on catalytic asymmetric transformations and new mechanistic insights. The review covers the period from January 2007 to May 2008 and focuses on intra- and intermolecular cycloaddition, carbocycle cycloisomerization, heterocycle synthesis, epoxidation, addition and miscellaneous transformations. A brief discussion of allenes as transition metal ligands, the use of allenes in total synthesis and potential medicinal agents that contain the allene functionality is also presented.

  15. Fossil Horses

    NASA Astrophysics Data System (ADS)

    MacFadden, Bruce J.

    1994-06-01

    The family Equidae have an extensive fossil record spanning the past 58 million years, and the evolution of the horse has frequently been used as a classic example of long-term evolution. In recent years, however, there have been many important discoveries of fossil horses, and these, in conjunction with such new methods as cladistics, and techniques such as precise geochronology, have allowed us to achieve a much greater understanding of the evolution and biology of this important group. This book synthesizes the large body of data and research relevant to an understanding of fossil horses from several disciplines including biology, geology and paleontology. Using horses as the central theme, the author weaves together in the text such topics as modern geochronology, paleobiogeography, climate change, evolution and extinction, functional morphology, and population biology during the Cenozoic period. This book will be exciting reading for researchers and graduate students in vertebrate paleontology, evolution, and zoology.

  16. Cycads: fossil evidence of late paleozoic origin.

    PubMed

    Mamay, S H

    1969-04-18

    Plant fossils from Lower Permian strata of the southwestern United States have been interpreted as cycadalean megasporophylls. They are evidently descended from spermopterid elements of the Pennsylvanian Taeniopteris complex; thus the known fossil history of the cycads is extended from the Late Triassic into the late Paleozoic. Possible implications of the Permian fossils toward evolution of the angiosperm carpel are considered.

  17. Cycads: Fossil evidence of late paleozoic origin

    USGS Publications Warehouse

    Mamay, S.H.

    1969-01-01

    Plant fossils from Lower Permian strata of the southwestern United States have been interpreted as cycadalean megasporophylls. They are evidently descended from spermopterid elements of the Pennsylvanian Taeniopteris complex; thus the known fossil history of the cycads is extended from the Late Triassic into the late Paleozoic. Possible implications of the Permian fossils toward evolution of the angiosperm carpel are considered.

  18. Revision of the Cretaceous fossil plant-assemblage from Gardeshwar (Gujarat, India): A conifer dominated floral association from an Upper Gondwana sequence on the West Coast of India

    NASA Astrophysics Data System (ADS)

    Jana, Brajendra Nath; King, Sarah C.; Hilton, Jason

    2013-09-01

    A small but diverse fossil plant assemblage from Gardeshwar in Gujarat Province of western India is reinvestigated, based on analysis of recently collected specimens that represent previously unrecognised taxa in combination with a critical review of previously reported taxa from the site. The assemblage is dominated by conifers including Brachyphyllum Brongniart, Elatocladus Halle, Pagiophyllum Heer, the cone Conites Sternberg, and ovulate scales of an araucarian conifer. Other plant groups are rare but include notable occurrences of the pteridophytes Lycopodites Lindley and Hutton and Gleichenia Smith, and the seed fern Sphenopteris (Brongniart) Sternberg. This assemblage is important as it represents the only datable fossils available from the Gardeshwar Formation and from the information presented we conclude it belongs to the Lower Cretaceous Allocladus-Brachyphyllum-Pagiophyllum floral biozone. The Gardeshwar assemblage association is unusual as it lacks the distinctive genus Allocladus but includes other taxa more typical of the Lower Cretaceous fern-dominated Weichselia-Onychiopsis-Gleichenia floral biozone, and may represent a transitional assemblage with characters of both biozones. However, this investigation highlights the lack of detailed stratigraphic analyses on the Lower Cretaceous sedimentary sequences of the west coast of India from which it remains uncertain if these two ‘biozones' are of different ages or whether they represent stratigraphically contemporaneous but ecologically distinct environments.

  19. H. Julian Allen with Blunt Body Theory

    NASA Technical Reports Server (NTRS)

    1957-01-01

    H. Julian Allen is best known for his 'Blunt Body Theory' of aerodynamics, a design technique for alleviating the severe re-entry heating problem which was then delaying the development of ballistic missiles. His findings revolutionized the fundamental design of ballistic missle re-entry shapes. Subsequently, applied research led to applications of the 'blunt' shape to ballistic missles and spacecraft which were intended to re-enter the Earth's atmosphere. This application led to the design of ablative heat shields that protected the Mercury, Gemini and Apollo astronauts as their space capsules re- entered the Earth's atmosphere. 'Harvey' Allen as he was called by most, was not only a brilliant scientist and aeronautical engineer but was also admired for his kindness, thoughtfulness and sense of humor. Among his many other accomplishments, Harvey Allen served as Center Director of the NASA Ames Research Center from 1965 to 1969. He died of a heart attack on January 29, 1977 at the age of 66.

  20. Maximal tractable subclasses of Allen`s interval algebra: Preliminary report

    SciTech Connect

    Drakengren, T.; Jonsson, P.

    1996-12-31

    This paper continues Nebel and Burckert`s investigation of Allen`s interval algebra by presenting nine more maximal tractable subclasses of the algebra (provided that P {ne} NP), in addition to their previously reported ORD-Horn subclass. Furthermore, twelve tractable subclasses are identified, whose maximality is riot decided. Four of these can express the notion of sequentiality between intervals, which is not possible in the ORD-Horn algebra. The satisfiability algorithm, which is common for all the algebras, is shown to be linear.

  1. Fossil plants indicate that the most significant decrease in atmospheric CO2 happened prior to the Eocene-Oligocene boundary

    NASA Astrophysics Data System (ADS)

    Steinthorsdottir, Margret; Porter, Amanda; Holohan, Aidan; Kunzmann, Lutz; Collinson, Margaret; McElwain, Jennifer

    2016-04-01

    A unique stratigraphic sequence of fossil leaves of Eotrigonobalanus furcinervis (extinct trees of the beech family, Fagaceae) from central Germany was utilized to derive an atmospheric pCO2 record with multiple data points spanning the late middle to late Eocene, two sampling levels which may be earliest Oligocene, and two samples from later in the Oligocene. Using the stomatal proxy, which relies on the inverse relationship between pCO2 and leaf stomatal density, we show that a ~40% decrease in pCO2 preceded the large shift in marine oxygen isotope records that characterizes the Eocene-Oliogocene climate transition. The results endorse the theory that pCO2 drawdown was the main forcer of the Eocene-Oligocene climate change, and a 'tipping point' was reached in the latest Eocene, triggering the plunge of the Earth System into icehouse conditions.

  2. Cross-coupling/cyclization reactions of two different allenic moieties.

    PubMed

    Alcaide, Benito; Almendros, Pedro; Martínez del Campo, Teresa

    2010-05-25

    The allene moiety represents an excellent building block for allene cross-coupling cyclization reactions, affording heterocyclic skeletons in a single step. This strategy is of particular interest when two different allene derivatives are involved in a series of metal-catalyzed cross-coupling heterocyclization processes. This Concept article is focused on the Pd-catalyzed union of two different allenic moieties, with cyclization of at least one of them by intramolecular cyclometalation. These new, versatile, and highly effective transformations are complex multistep processes leading to potential privileged structures that could find wide applications in related medicinal chemistry.

  3. 5. Historic American Buildings Survey Harold Allen, Photographer 19 June ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    5. Historic American Buildings Survey Harold Allen, Photographer 19 June 1965 ICONOSTASIS AND CHANDELIER - Holy Trinity Russian & Greek Orthodox Church, 1121 North Leavitt Street, Chicago, Cook County, IL

  4. 4. Historic American Buildings Survey Harold Allen, Photographer 19 June ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    4. Historic American Buildings Survey Harold Allen, Photographer 19 June 1965 SANCTUARY FROM ENTRANCE - Holy Trinity Russian & Greek Orthodox Church, 1121 North Leavitt Street, Chicago, Cook County, IL

  5. Functional analysis of allene oxide cyclase, MpAOC, in the liverwort Marchantia polymorpha.

    PubMed

    Yamamoto, Yusuke; Ohshika, Jun; Takahashi, Tomohiro; Ishizaki, Kimitsune; Kohchi, Takayuki; Matusuura, Hideyuki; Takahashi, Kosaku

    2015-08-01

    12-Oxo-phytodienoic acid (OPDA) is an intermediate in jasmonic acid (JA) biosynthesis. OPDA exerts JA-dependent and JA-independent biological effects; therefore, it is considered a signaling molecule in flowering plants. OPDA is induced by bacterial infection and wounding and inhibits growth in the moss Physcomitrella patens. The functions of OPDA and allene oxide cyclase (AOC) in the liverwort Marchantia polymorpha were explored, which represents the most basal lineage of extant land plants. The analysis of OPDA showed that it is present in M. polymorpha and is increased by wounding. OPDA has been suggested to be involved in the response to environmental stresses. Moreover, OPDA showed growth inhibitory activity in M. polymorpha. Nonetheless JA in M. polymorpha was not found in this study. AOC synthesizes OPDA from an unstable allene oxide. A database search of the M. polymorpha genome identified only a putative gene encoding allene oxide cyclase (MpAOC). Recombinant MpAOC showed AOC activity similar to that in flowering plants. MpAOC was localized to chloroplasts, as in flowering plants. Expression of MpAOC was induced by wounding and OPDA treatment, and positive feedback regulation of OPDA was demonstrated in M. polymorpha. Overexpression of MpAOC increased the endogenous OPDA level and suppressed growth in M. polymorpha. These results indicate the role of OPDA as a signaling molecule regulating growth and the response to wounding in the liverwort M. polymorpha. PMID:25892411

  6. Evaluation of computer-aided foundation design techniques for fossil fuel power plants. Final report. [Includes list of firms involved, equipment, software, etc

    SciTech Connect

    Kulhawy, F.H.; Dill, J.C.; Trautmann, C.H.

    1984-11-01

    The use of an integrated computer-aided drafting and design system for fossil fuel power plant foundations would offer utilities considerable savings in engineering costs and design time. The technology is available, but research is needed to develop software, a common data base, and data management procedures. An integrated CADD system suitable for designing power plant foundations should include the ability to input, display, and evaluate geologic, geophysical, geotechnical, and survey field data; methods for designing piles, mats, footings, drilled shafts, and other foundation types; and the capability of evaluating various load configurations, soil-structure interactions, and other construction factors that influence design. Although no such integrated system exists, the survey of CADD techniques showed that the technology is available to computerize the whole foundation design process, from single-foundation analysis under single loads to three-dimensional analysis under earthquake loads. The practices of design firms using CADD technology in nonutility applications vary widely. Although all the firms surveyed used computer-aided drafting, only two used computer graphics in routine design procedures, and none had an integrated approach to using CADD for geotechnical engineering. All the firms had developed corporate policies related to system security, supervision, overhead allocation, training, and personnel compensation. A related EPRI project RP2514, is developing guidelines for applying CADD systems to entire generating-plant construction projects. 4 references, 6 figures, 6 tables.

  7. A new method to determine the ratio of electricity production from fossil and biogenic sources in waste-to-Energy plants.

    PubMed

    Fellner, Johann; Cencic, Oliver; Rechberger, Helmut

    2007-04-01

    New directives of the European Union require operators of waste-to-energy (WTE) plants to report the amount of electricity that is produced from renewable sources in the waste feed. Until now, the standard method to determine the portion of renewable electricity is sorting the wastes into defined fractions of fossil organic and biogenic waste components and determining the lower heating value of these fractions. Out of it the amount of electricity production from renewables is calculated. This practice is labor and cost intensive. Therefore, it is usually carried out once a year which provides only a snapshot analysis of limited significance. This paper proposes a method to calculate the portion of electricity produced from renewable materials in waste continuously by solving a set of equations. All data required are either available from literature or from operating data routinely measured in WTE plants. The advantages are statistically derived uncertainty of the result, temporal resolution of the result down to daily mean values, low implementation efforts, and virtually no operational costs. An example of the implementation of the method to a 60 000 tons per year WTE plant is given.

  8. The early evolution of land plants, from fossils to genomics: a commentary on Lang (1937) ‘On the plant-remains from the Downtonian of England and Wales'

    PubMed Central

    Edwards, Dianne; Kenrick, Paul

    2015-01-01

    During the 1920s, the botanist W. H. Lang set out to collect and investigate some very unpromising fossils of uncertain affinity, which predated the known geological record of life on land. His discoveries led to a landmark publication in 1937, ‘On the plant-remains from the Downtonian of England and Wales’, in which he revealed a diversity of small fossil organisms of great simplicity that shed light on the nature of the earliest known land plants. These and subsequent discoveries have taken on new relevance as botanists seek to understand the plant genome and the early evolution of fundamental organ systems. Also, our developing knowledge of the composition of early land-based ecosystems and the interactions among their various components is contributing to our understanding of how life on land affects key Earth Systems (e.g. carbon cycle). The emerging paradigm is one of early life on land dominated by microbes, small bryophyte-like organisms and lichens. Collectively called cryptogamic covers, these are comparable with those that dominate certain ecosystems today. This commentary was written to celebrate the 350th anniversary of the journal Philosophical Transactions of the Royal Society. PMID:25750238

  9. A research needs assessment for the capture, utilization and disposal of carbon dioxide from fossil fuel-fired power plants. Volume 1, Executive summary: Final report

    SciTech Connect

    Not Available

    1993-07-01

    This study identifies and assesses system approaches in order to prioritize research needs for the capture and non-atmospheric sequestering of a significant portion of the carbon dioxide (CO{sub 2}) emitted from fossil fuel-fired electric power plants (US power plants presently produce about 7% of the world`s CO{sub 2} emissions). The study considers capture technologies applicable either to existing plants or to those that optimistically might be demonstrated on a commercial scale over the next twenty years. Specific conclusions are as follows: (1) To implement CO{sub 2} capture and sequestration on a national scale will decrease power plant net efficiencies and significantly increase the cost of electricity. To make responsible societal decisions, accurate and consistent economic and environmental analysis of all alternatives for atmospheric CO{sub 2} mitigation are required. (2) Commercial CO{sub 2} capture technology, though expensive and energy intensive, exists today. (3) The most promising approach to more economical CO{sub 2} capture is to develop power plant systems that facilitate efficient CO{sub 2} capture. (4) While CO{sub 2} disposal in depleted oil and gas reservoirs is feasible today, the ability to dispose of large quantities Of CO{sub 2} is highly uncertain because of both technical and institutional issues. Disposal into the deep ocean or confined aquifers offers the potential for large quantity disposal, but there are technical, safety, liability, and environmental issues to resolve. Therefore, the highest priority research should focus on establishing the feasibility of large scale disposal options.

  10. 33 CFR 165.T08-0432 - Safety Zone; Waterway Closure, Morgan City-Port Allen Route from Mile Marker 0 to Port Allen Lock.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 33 Navigation and Navigable Waters 2 2011-07-01 2011-07-01 false Safety Zone; Waterway Closure, Morgan City-Port Allen Route from Mile Marker 0 to Port Allen Lock. 165.T08-0432 Section 165.T08-0432...-Port Allen Route from Mile Marker 0 to Port Allen Lock. (a) Location. Waters of the Gulf...

  11. Are the oldest 'fossils', fossils

    NASA Technical Reports Server (NTRS)

    Schopf, J. W.

    1976-01-01

    A comparative statistical study has been carried out on populations of modern algae, Precambrian algal microfossils, the 'organized elements' of the Orgueil carbonaceous meteorite, and the oldest microfossil-like objects now known (spheroidal bodies from the Fig Tree and Onverwacht Groups of the Swaziland Supergroup, South Africa). The distribution patterns exhibited by the more than 3000 m.y.-old Swaziland microstructures bear considerable resemblance to those of the abiotic 'organized elements' but differ rather markedly from those exhibited by younger, assuredly biogenic, populations. Based on these comparisons, it is concluded that the Swaziland spheroids could be, at least in part, of nonbiologic origin; these oldest known fossil-like microstructures should not be regarded as constituting firm evidence of Archean life.

  12. SETI Surveys on the Allen Telescope Array

    NASA Astrophysics Data System (ADS)

    Backus, Peter R.; Kilsdonk, T. N.; ATA Team

    2009-01-01

    The Allen Telescope Array (ATA-42) is a centimeter-wave array of 42 six-meter dishes that allows simultaneous SETI and other radio astronomy projects. In this paper we report on initial SETI observations using several observation and RFI mitigation strategies. We conducted both "targeted” observations of selected stars and "sky survey” observations of areas of the sky. Some observations were done with the SETI project directing the pointing of the array and others were "commensal,” in a direction selected by another project. In both modes, SETI observations used an independent RF tuning and two synthesized beams pointing at stars or positions in the field of view and tuned to the same frequency band. Results of the two SETI observations were compared and used to excise interference. In some observations, each beam had a null positioned at the center of the other beam. In the long term, we plan to observe one million target stars and survey large sections of the galactic plane over the frequency range from 1 GHz to 10 GHz. Much of this work may be done in parallel with other large-scale surveys. The first phase of the ATA was funded through generous grants from the Paul G. Allen Family Foundation. UC Berkeley, the SETI Institute, the National Science Foundation (Grant No. 0540599), Sun Microsystems, Xilinx, Nathan Myhrvold, Greg Papadopoulos, and other corporations and individual donors contributed additional funding.

  13. Macular pseudohaemorrhage secondary to Allen Dot artefact.

    PubMed

    Michaels, Luke; Alexander, Philip; Newsom, Richard

    2015-01-01

    A 34-year-old highly myopic (-11.00 D) woman presented to eye clinic with a 3 day history of right eye paracentral blurring. Visual acuities were 6/6 bilaterally. Clinical examination was normal. Fundus photography showed the classic appearance of a macular haemorrhage. This is a recognised complication of high myopia and would have accounted for the patient's symptoms. However, further photography showed that the haemorrhage seemed to 'jump' around the fundus and was even present in the fellow eye. The apparent haemorrhage was revealed to be an imaging artefact. The 'Allen Dot' is a 6 mm black mask incorporated into retinal cameras to reduce reflection. Rarely, in highly myopic eyes, optical artefact can result. To the best of our knowledge, we are the first in the literature to report artefacts from the Allen Dot masquerading as ophthalmic disease. This case re-iterates the importance of clinical examination, especially in high myopes, given the current trend towards virtual clinics. PMID:25564595

  14. 33 CFR 80.1440 - Port Allen, Kauai, HI.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 33 Navigation and Navigable Waters 1 2012-07-01 2012-07-01 false Port Allen, Kauai, HI. 80.1440 Section 80.1440 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY INTERNATIONAL NAVIGATION RULES COLREGS DEMARCATION LINES Pacific Islands § 80.1440 Port Allen, Kauai, HI. A line drawn...

  15. 33 CFR 80.1440 - Port Allen, Kauai, HI.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 33 Navigation and Navigable Waters 1 2013-07-01 2013-07-01 false Port Allen, Kauai, HI. 80.1440 Section 80.1440 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY INTERNATIONAL NAVIGATION RULES COLREGS DEMARCATION LINES Pacific Islands § 80.1440 Port Allen, Kauai, HI. A line drawn...

  16. 33 CFR 80.1440 - Port Allen, Kauai, HI.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 33 Navigation and Navigable Waters 1 2011-07-01 2011-07-01 false Port Allen, Kauai, HI. 80.1440 Section 80.1440 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY INTERNATIONAL NAVIGATION RULES COLREGS DEMARCATION LINES Pacific Islands § 80.1440 Port Allen, Kauai, HI. A line drawn...

  17. 33 CFR 80.1440 - Port Allen, Kauai, HI.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 33 Navigation and Navigable Waters 1 2014-07-01 2014-07-01 false Port Allen, Kauai, HI. 80.1440 Section 80.1440 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY INTERNATIONAL NAVIGATION RULES COLREGS DEMARCATION LINES Pacific Islands § 80.1440 Port Allen, Kauai, HI. A line drawn...

  18. 33 CFR 80.1440 - Port Allen, Kauai, HI.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 33 Navigation and Navigable Waters 1 2010-07-01 2010-07-01 false Port Allen, Kauai, HI. 80.1440 Section 80.1440 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY INTERNATIONAL NAVIGATION RULES COLREGS DEMARCATION LINES Pacific Islands § 80.1440 Port Allen, Kauai, HI. A line drawn...

  19. Mission Specialist (MS) Allen experiments with beverage on middeck

    NASA Technical Reports Server (NTRS)

    1982-01-01

    Mission Specialist (MS) Allen, using beverage container and drinking straw, experiments with microgravity chararcteristics of orange juice on middeck in front of the Development Flight Instrument (DFI) unit and forward lockers. Allen laughes as he watches the results of his experimentation.

  20. Bi(OTf)3-catalyzed cycloisomerization of aryl-allenes.

    PubMed

    Lemière, Gilles; Cacciuttolo, Bastien; Belhassen, Emilie; Duñach, Elisabet

    2012-06-01

    Intramolecular hydroarylation of allenes was achieved under very mild conditions using bismuth(III) triflate as the catalyst. Efficient functionalization of activated and nonactivated aromatic nuclei led to C-C bond formation through a formal Ar-H activation. A tandem bis-hydroarylation of the allene moiety was also developed giving access to various interesting polycyclic structures. PMID:22578075

  1. A Complete Fossil-Calibrated Phylogeny of Seed Plant Families as a Tool for Comparative Analyses: Testing the ‘Time for Speciation’ Hypothesis

    PubMed Central

    Harris, Liam W.; Davies, T. Jonathan

    2016-01-01

    Explaining the uneven distribution of species richness across the branches of the tree of life has been a major challenge for evolutionary biologists. Advances in phylogenetic reconstruction, allowing the generation of large, well-sampled, phylogenetic trees have provided an opportunity to contrast competing hypotheses. Here, we present a new time-calibrated phylogeny of seed plant families using Bayesian methods and 26 fossil calibrations. While there are various published phylogenetic trees for plants which have a greater density of species sampling, we are still a long way from generating a complete phylogeny for all ~300,000+ plants. Our phylogeny samples all seed plant families and is a useful tool for comparative analyses. We use this new phylogenetic hypothesis to contrast two alternative explanations for differences in species richness among higher taxa: time for speciation versus ecological limits. We calculated net diversification rate for each clade in the phylogeny and assessed the relationship between clade age and species richness. We then fit models of speciation and extinction to individual branches in the tree to identify major rate-shifts. Our data suggest that the majority of lineages are diversifying very slowly while a few lineages, distributed throughout the tree, are diversifying rapidly. Diversification is unrelated to clade age, no matter the age range of the clades being examined, contrary to both the assumption of an unbounded lineage increase through time, and the paradigm of fixed ecological limits. These findings are consistent with the idea that ecology plays a role in diversification, but rather than imposing a fixed limit, it may have variable effects on per lineage diversification rates through time. PMID:27706173

  2. A research needs assessment for the capture, utilization and disposal of carbon dioxide from fossil fuel-fired power plants. Volume 2, Topical reports: Final report

    SciTech Connect

    Not Available

    1993-07-01

    This study, identifies and assesses system approaches in order to prioritize research needs for the capture and non-atmospheric sequestering of a significant portion of the carbon dioxide (CO{sub 2}) emitted from fossil fuel-fired electric power plants (US power plants presently produce about 7% of the world`s CO{sub 2} emissions). The study considers capture technologies applicable either to existing plants or to those that optimistically might be demonstrated on a commercial scale over the next twenty years. The research needs that have high priority in establishing the technical, environmental, and economic feasibility of large-scale capture and disposal of CO{sub 2} from electric power plants are:(1) survey and assess the capacity, cost, and location of potential depleted gas and oil wells that are suitable CO{sub 2} repositories (with the cooperation of the oil and gas industry); (2) conduct research on the feasibility of ocean disposal, with objectives of determining the cost, residence time, and environmental effects for different methods of CO{sub 2} injection; (3) perform an in-depth survey of knowledge concerning the feasibility of using deep, confined aquifers for disposal and, if feasible, identify potential disposal locations (with the cooperation of the oil and gas industry); (4) evaluate, on a common basis, system and design alternatives for integration of CO{sub 2} capture systems with emerging and advanced technologies for power generation; and prepare a conceptual design, an analysis of barrier issues, and a preliminary cost estimate for pipeline networks necessary to transport a significant portion of the CO{sub 2} to potentially feasible disposal locations.

  3. Will My Fossil Float?

    ERIC Educational Resources Information Center

    Riesser, Sharon; Airey, Linda

    1993-01-01

    Explains how young students can be introduced to fossils. Suggests books to read and science activities including "Fossils to Eat" where students make fossils from peanut butter, honey, and powdered milk. (PR)

  4. Phase-transfer-catalysed asymmetric synthesis of tetrasubstituted allenes

    NASA Astrophysics Data System (ADS)

    Hashimoto, Takuya; Sakata, Kazuki; Tamakuni, Fumiko; Dutton, Mark J.; Maruoka, Keiji

    2013-03-01

    Allenes are molecules based on three carbons connected by two cumulated carbon-carbon double bonds. Given their axially chiral nature and unique reactivity, substituted allenes have a variety of applications in organic chemistry as key synthetic intermediates and directly as part of biologically active compounds. Although the demands for these motivated many endeavours to make axially chiral, substituted allenes by exercising asymmetric catalysis, the catalytic asymmetric synthesis of fully substituted ones (tetrasubstituted allenes) remained largely an unsolved issue. The fundamental obstacle to solving this conundrum is the lack of a simple synthetic transformation that provides tetrasubstituted allenes in the action of catalysis. We report herein a strategy to overcome this issue by the use of a phase-transfer-catalysed asymmetric functionalization of 1-alkylallene-1,3-dicarboxylates with N-arylsulfonyl imines and benzylic and allylic bromides.

  5. Prediction of atmospheric δ13CO2 using fossil plant tissues

    SciTech Connect

    A. Hope Jahren; Arens, Nan Crystal; Harbeson, Stephanie A.

    2008-06-30

    To summarize the content: we presented the results of laboratory experiments designed to quantify the relationship between plant tissue δ13C and δ13CO2 values under varying environmental conditions, including differential pCO2 ranging from 1 to 3 times today’s levels. As predicted, plants grown under elevated pCO2 showed increased average biomass compared to controls grown at the same temperature. Across a very large range in δ13Ca (≈ 24 ‰) and pCO2 (≈ 740 ppmv) we observed a consistent correlation between δ13Ca and δ13Cp (p<0.001). We show an average isotopic depletion of -25.4 ‰ for above-ground tissue and -23.2 ‰ for below-ground tissue of Raphanus sativus L. relative to the composition of the atmosphere under which it formed. For both above- and below-ground tissue, grown at both ~23 °C and ~29 °C, correlation was strong and significant (r2 ≥ 0.98, p<0.001); variation in pCO2 level had little or no effect on this relationship.

  6. Freeman Allen: Boston's pioneering physician anesthetist.

    PubMed

    Morris, Samuel D; Morris, Alina J; Rockoff, Mark A

    2014-11-01

    On October 16, 1846 dentist William T. G. Morton successfully demonstrated at the Massachusetts General Hospital that ether could prevent the pain of surgery. For decades afterwards, the administration of anesthesia in the United States was generally relegated to dentists, medical students, junior surgical trainees, or even nonmedical personnel. It was not until the end of the 19th century that a few pioneering physicians began devoting their careers to administering anesthesia to patients, studying ways to make it safer and more effective, and teaching others about its use. One of these individuals was Freeman Allen, who was appointed the first physician anesthetist to the medical staff at the Massachusetts General Hospital and several other major hospitals in Boston. We describe this remarkable man, his contributions to the early development of anesthesiology as a medical specialty, and the true cause of his untimely death. PMID:25329027

  7. An Estimate of the Cost of Electricity from Light Water Reactors and Fossil Plants with Carbon Capture and Sequestration

    SciTech Connect

    Simon, A J

    2009-08-21

    As envisioned in this report, LIFE technology lends itself to large, centralized, baseload (or 'always on') electrical generation. Should LIFE plants be built, they will have to compete in the electricity market with other generation technologies. We consider the economics of technologies with similar operating characteristics: significant economies of scale, limited capacity for turndown, zero dependence on intermittent resources and ability to meet environmental constraints. The five generation technologies examined here are: (1) Light Water Reactors (LWR); (2) Coal; (3) Coal with Carbon Capture and Sequestration (CCS); (4) Natural Gas; and (5) Natural Gas with Carbon Capture and Sequestration. We use MIT's cost estimation methodology (Du and Parsons, 2009) to determine the cost of electricity at which each of these technologies is viable.

  8. Mitochondrial genomes as living 'fossils'.

    PubMed

    Small, Ian

    2013-04-15

    The huge variation between mitochondrial genomes makes untangling their evolutionary histories difficult. Richardson et al. report on the remarkably unaltered 'fossil' genome of the tulip tree, giving us many clues as to how the mitochondrial genomes of flowering plants have evolved over the last 150 million years, and raising questions about how such extraordinary sequence conservation can be maintained.

  9. Fossil fuel furnace reactor

    DOEpatents

    Parkinson, William J.

    1987-01-01

    A fossil fuel furnace reactor is provided for simulating a continuous processing plant with a batch reactor. An internal reaction vessel contains a batch of shale oil, with the vessel having a relatively thin wall thickness for a heat transfer rate effective to simulate a process temperature history in the selected continuous processing plant. A heater jacket is disposed about the reactor vessel and defines a number of independent controllable temperature zones axially spaced along the reaction vessel. Each temperature zone can be energized to simulate a time-temperature history of process material through the continuous plant. A pressure vessel contains both the heater jacket and the reaction vessel at an operating pressure functionally selected to simulate the continuous processing plant. The process yield from the oil shale may be used as feedback information to software simulating operation of the continuous plant to provide operating parameters, i.e., temperature profiles, ambient atmosphere, operating pressure, material feed rates, etc., for simulation in the batch reactor.

  10. 2. Historic American Buildings Survey Harold Allen, Photographer 24 June ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    2. Historic American Buildings Survey Harold Allen, Photographer 24 June 1964 HALL AND MAIN STAIR, LOOKING NORTHWEST FROM ENTRANCE VESTIBULE - Edward E. Ayer House, 2 East Banks Street, Chicago, Cook County, IL

  11. 10. Historic American Buildings Survey Allen L. Hubbard, Photographer May ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    10. Historic American Buildings Survey Allen L. Hubbard, Photographer May 5, 1936 DINING ROOM 1ST FLOOR (west wall) - Holmes-Sayward House, West side of U.S. Route 202 (State Route 4), Alfred, York County, ME

  12. 9. Historic American Buildings Survey Allen L. Hubbard, Photographer May ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    9. Historic American Buildings Survey Allen L. Hubbard, Photographer May 5, 1936 NORTHEAST ROOM (1st floor south wall) - Holmes-Sayward House, West side of U.S. Route 202 (State Route 4), Alfred, York County, ME

  13. 8. Historic American Buildings Survey Allen L. Hubbard, Photographer May ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    8. Historic American Buildings Survey Allen L. Hubbard, Photographer May 5, 1936 NORTHEAST ROOM (west wall) - Holmes-Sayward House, West side of U.S. Route 202 (State Route 4), Alfred, York County, ME

  14. 6. Historic American Buildings Survey Harold Allen, Photographer June 1964 ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    6. Historic American Buildings Survey Harold Allen, Photographer June 1964 STAINED GLASS WINDOW, WEST WINDOW IN SOUTH WALL, FROM BALCONY - Kehilath Anshe Ma'ariv Synagogue, 3301 South Indiana Avenue, Chicago, Cook County, IL

  15. 8. Historic American Buildings Survey Harold Allen, Photographer 24 June ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    8. Historic American Buildings Survey Harold Allen, Photographer 24 June 1964 GRAND STAIRWAY, FROM SECOND FLOOR HALL, SHOWING STAINED GLASS WINDOW IN WEST WALL ABOVE LANDING - Francis J. Dewes House, 503 West Wrightwood Avenue, Chicago, Cook County, IL

  16. 3. Historic American Buildings Survey Harold Allen, Photographer 3 May ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    3. Historic American Buildings Survey Harold Allen, Photographer 3 May 1965 ENTRANCE CANOPY FROM SOUTHWEST - Holy Trinity Russian & Greek Orthodox Church, 1121 North Leavitt Street, Chicago, Cook County, IL

  17. 1. Historic American Buildings Survey Harold Allen, Photographer 31 May ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. Historic American Buildings Survey Harold Allen, Photographer 31 May 1964 WEST (NORMAL AVE.) AND SOUTHEAST (CANALPORT AVE.) ELEVATIONS - Schoenhofen Brewing Company, Powerhouse, 1770 Canalport Avenue, Chicago, Cook County, IL

  18. Synthesis and biological evaluation of 12 allenic aromatic ethers.

    PubMed

    Wang, San-Yong; Mao, Wei-Wei; She, Zhi-Gang; Li, Chun-Rong; Yang, Ding-Qiao; Lin, Yong-Cheng; Fu, Li-Wu

    2007-05-15

    Twelve allenic aromatic ethers, some of them are natural products isolated from the mangrove fungus Xylaria sp. 2508 in the South China Sea, were synthesized. Their antitumor activities against KB and KBv200 cells were determined. All these compounds demonstrated cytotoxic potential, ranging from weak to strong activity. The analysis of structure-activity relationships suggested that the introduction of allenic moiety could generate or enhance cytotoxicity of these phenol compounds.

  19. Voices: A Conversation with Allen J. Wilcox.

    PubMed

    Jukic, Anne Marie Z

    2016-09-01

    Allen James Wilcox was born on 30 September 1946 in Columbus, OH. He studied medicine at the University of Michigan, graduated in 1973, and after a rotating internship, he completed a master's degree in maternal and child health (1976) and a PhD in epidemiology (1979) at the University of North Carolina in Chapel Hill. After graduation, he went to work at the National Institute of Environmental Health Sciences (NIEHS, one of the US National Institutes of Health) in Durham, NC, where he has spent his career. He developed a research program in reproductive and perinatal epidemiology, a relatively unexplored area at the time. His studies include the early pregnancy study, which documented the extent of subclinical pregnancy loss in humans and established the fertile days of a woman's menstrual cycle. He served as the Chief of the Epidemiology Branch from 1991 to 2001, and as Editor-in-Chief of the journal EPIDEMIOLOGY from 2001 to 2014. His textbook, Fertility and Pregnancy-An Epidemiologic Perspective, was published by Oxford University Press in 2010. He was elected to the American Epidemiological Society in 1989, and served as its president in 2003. He also served as president of the Society of Pediatric and Perinatal Epidemiological Research (1996) and the president of the Society of Epidemiological Research (1998). He holds adjunct teaching appointments at the University of North Carolina, Harvard University, and the University of Bergen (Norway), which awarded him an honorary doctoral degree in 2008. PMID:27482869

  20. Spatial and temporal trends in contaminant concentrations in Hexagenia nymphs following a coal ash spill at the Tennessee Valley Authority's Kingston Fossil Plant

    DOE PAGES

    Baker, Tyler F; Jett, Robert Trent; Smith, John G.; Murphy, Cheryl A.

    2016-02-25

    A dike failure at the Tennessee Valley Authority Kingston Fossil Plant in East Tennessee, United States, in December 2008, released approximately 4.1 million m3 of coal ash into the Emory River. From 2009 through 2012, samples of mayfly nymphs (Hexagenia bilineata) were collected each spring from sites in the Emory, Clinch, and Tennessee Rivers upstream and downstream of the spill. Samples were analyzed for 17 metals. Concentrations of metals were generally highest the first 2 miles downstream of the spill, and then decreased with increasing distance from the spill. Arsenic, B, Ba, Be, Mo, Sb, Se, Sr, and V appearedmore » to have strong ash signatures, whereas Co, Cr, Cu, Ni, and Pb appeared to be associated with ash and other sources. Furthermore, the concentrations for most of these contaminants were modest and are unlikely to cause widespread negative ecological effects. Trends in Hg, Cd, and Zn suggested little (Hg) or no (Cd, Zn) association with ash. Temporal trends suggested that concentrations of ash-related contaminants began to subside after 2010, but because of the limited time period of that analysis (4 yr), further monitoring is needed to verify this trend. The present study provides important information on the magnitude of contaminant exposure to aquatic receptors from a major coal ash spill, as well as spatial and temporal trends for transport of the associated contaminants in a large open watershed. Environ Toxicol Chem 2016;35:1159 1171. Published 2015 Wiley Periodicals Inc. on behalf of SETAC. This article is a US government work and, as such, is in the public domain in the United States of America.« less

  1. Fe-Al Weld Overlay and High Velocity Oxy-Fuel Thermal Spray Coatings for Corrosion Protection of Waterwalls in Fossil Fired Plants with Low NOx Burners

    SciTech Connect

    Regina, J.R.

    2002-02-08

    Iron-aluminum-chromium coatings were investigated to determine the best candidates for coatings of boiler tubes in Low NOx fossil fueled power plants. Ten iron-aluminum-chromium weld claddings with aluminum concentrations up to 10wt% were tested in a variety of environments to evaluate their high temperature corrosion resistance. The weld overlay claddings also contained titanium additions to investigate any beneficial effects from these ternary and quaternary alloying additions. Several High-Velocity Oxy-Fuel (HVOF) thermal spray coatings with higher aluminum concentrations were investigated as well. Gaseous corrosion testing revealed that at least 10wt%Al is required for protection in the range of environments examined. Chromium additions were beneficial in all of the environments, but additions of titanium were beneficial only in sulfur rich atmospheres. Similar results were observed when weld claddings were in contact with corrosive slag while simultaneously, exposed to the corrosive environments. An aluminum concentration of 10wt% was required to prevent large amounts of corrosion to take place. Again chromium additions were beneficial with the greatest corrosion protection occurring for welds containing both 10wt%Al and 5wt%Cr. The exposed thermal spray coatings showed either significant cracking within the coating, considerable thickness loss, or corrosion products at the coating substrate interface. Therefore, the thermal spray coatings provided the substrate very little protection. Overall, it was concluded that of the coatings studied weld overlay coatings provide superior protection in these Low NOx environments; specifically, the ternary weld composition of 10wt%Al and 5wt%Cr provided the best corrosion protection in all of the environments tested.

  2. Reactivity and Chemoselectivity of Allenes in Rh(I)-Catalyzed Intermolecular (5 + 2) Cycloadditions with Vinylcyclopropanes: Allene-Mediated Rhodacycle Formation Can Poison Rh(I)-Catalyzed Cycloadditions

    PubMed Central

    2015-01-01

    Allenes are important 2π building blocks in organic synthesis and engage as 2-carbon components in many metal-catalyzed reactions. Wender and co-workers discovered that methyl substituents on the terminal allene double bond counterintuitively change the reactivities of allenes in [Rh(CO)2Cl]2-catalyzed intermolecular (5 + 2) cycloadditions with vinylcyclopropanes (VCPs). More sterically encumbered allenes afford higher cycloadduct yields, and such effects are also observed in other Rh(I)-catalyzed intermolecular cycloadditions. Through density functional theory calculations (B3LYP and M06) and experiment, we explored this enigmatic reactivity and selectivity of allenes in [Rh(CO)2Cl]2-catalyzed intermolecular (5 + 2) cycloadditions with VCPs. The apparent low reactivity of terminally unsubstituted allenes is associated with a competing allene dimerization that irreversibly sequesters rhodium. With terminally substituted allenes, steric repulsion between the terminal substituents significantly increases the barrier of allene dimerization while the barrier of the (5 + 2) cycloaddition is not affected, and thus the cycloaddition prevails. Computation has also revealed the origin of chemoselectivity in (5 + 2) cycloadditions with allene-ynes. Although simple allene and acetylene have similar reaction barriers, intermolecular (5 + 2) cycloadditions of allene-ynes occur exclusively at the terminal allene double bond. The terminal double bond is more reactive due to the enhanced d−π* backdonation. At the same time, insertion of the internal double bond of an allene-yne has a higher barrier as it would break π conjugation. Substituted alkynes are more difficult to insert compared with acetylene, because of the steric repulsion from the additional substituents. This leads to the greater reactivity of the allene double bond relative to the alkynyl group in allene-ynes. PMID:25379606

  3. Reactivity and chemoselectivity of allenes in Rh(I)-catalyzed intermolecular (5 + 2) cycloadditions with vinylcyclopropanes: allene-mediated rhodacycle formation can poison Rh(I)-catalyzed cycloadditions.

    PubMed

    Hong, Xin; Stevens, Matthew C; Liu, Peng; Wender, Paul A; Houk, K N

    2014-12-10

    Allenes are important 2π building blocks in organic synthesis and engage as 2-carbon components in many metal-catalyzed reactions. Wender and co-workers discovered that methyl substituents on the terminal allene double bond counterintuitively change the reactivities of allenes in [Rh(CO)2Cl]2-catalyzed intermolecular (5 + 2) cycloadditions with vinylcyclopropanes (VCPs). More sterically encumbered allenes afford higher cycloadduct yields, and such effects are also observed in other Rh(I)-catalyzed intermolecular cycloadditions. Through density functional theory calculations (B3LYP and M06) and experiment, we explored this enigmatic reactivity and selectivity of allenes in [Rh(CO)2Cl]2-catalyzed intermolecular (5 + 2) cycloadditions with VCPs. The apparent low reactivity of terminally unsubstituted allenes is associated with a competing allene dimerization that irreversibly sequesters rhodium. With terminally substituted allenes, steric repulsion between the terminal substituents significantly increases the barrier of allene dimerization while the barrier of the (5 + 2) cycloaddition is not affected, and thus the cycloaddition prevails. Computation has also revealed the origin of chemoselectivity in (5 + 2) cycloadditions with allene-ynes. Although simple allene and acetylene have similar reaction barriers, intermolecular (5 + 2) cycloadditions of allene-ynes occur exclusively at the terminal allene double bond. The terminal double bond is more reactive due to the enhanced d-π* backdonation. At the same time, insertion of the internal double bond of an allene-yne has a higher barrier as it would break π conjugation. Substituted alkynes are more difficult to insert compared with acetylene, because of the steric repulsion from the additional substituents. This leads to the greater reactivity of the allene double bond relative to the alkynyl group in allene-ynes.

  4. Obituary: James Alfred Van Allen, 1914-2006

    NASA Astrophysics Data System (ADS)

    Ludwig, George H.; McIlwain, Carl Edwin

    2006-12-01

    James Alfred Van Allen, world-renowned space scientist, died 9 August 2006 at the age of ninety-one. He succumbed to heart failure after a ten-week period of declining health. Van Allen served for his entire sixty-seven-year professional career as an amazingly productive researcher, space science spokesman, inspired teacher, and valued colleague. The realization by him and his associates that charged particles are trapped by the Earth's magnetic field began a whole new field of research, magnetospheric physics. Following that initial discovery, he and his associates quickly extended their observations, first to the inner planets, and then to the rest of the planets and beyond. During his tenure at Iowa, he and his group flew instruments on more than sixty successful Earth satellites and planetary spacecraft, including the first missions to the planets Venus, Mars, Jupiter, Saturn, Uranus, and Neptune. Van Allen's lifetime publication list numbers more than 275, of which many are widely-cited, seminal papers. He was the sole author of more than 125 of those papers. Beyond the research laboratory, Van Allen worked energetically throughout his career in establishing space research as a new branch of human inquiry. He was among the most sought-after as a committee member and adviser, working at the highest levels of government, including the White House and Congress, and at all levels of the national and international research establishments. Many presentations in the non-scientific arena helped to bring the exciting discoveries and challenges of space research to the attention of the general public. James Van Allen (Van to his many friends and colleagues) was born on 7 September 1914 on a small farm near Mount Pleasant, Iowa, the second of four sons of Alfred Morris Van Allen and Alma Olney Van Allen. After high school in Mount Pleasant, he entered Iowa Wesleyan College, majoring in physics and graduating summa cum laude. While there, he was introduced to geophysics

  5. Accounting for Diradical Character through DFT. The Case of Vinyl Allene Oxide Rearrangement.

    PubMed

    López, Roberto Villar; Faza, Olalla Nieto; López, Carlos Silva

    2015-11-01

    The transformation of vinyl allene oxides into cyclopentenones is key to the biosynthesis of a number of hormone-like molecules in plants. Two competitive paths are generally accepted for this transformation: a concerted SN2-like mechanism and a stepwise path with a diradical oxyallyl intermediate. Recently, a new stepwise closed-shell path has been proposed that circumvents the key oxyallyl intermediate. In this work, we conduct a thorough computational investigation, including dynamic effects, to identify the most likely mechanism for this transformation.

  6. High Power Diode Laser-Treated HP-HVOF and Twin Wire Arc-Sprayed Coatings for Fossil Fuel Power Plants

    NASA Astrophysics Data System (ADS)

    Mann, B. S.

    2013-08-01

    This article deals with high power diode laser (HPDL) surface modification of twin wire arc-sprayed (TWAS) and high pressure high velocity oxy-fuel (HP-HVOF) coatings to combat solid particle erosion occurring in fossil fuel power plants. To overcome solid particle impact wear above 673 K, Cr3C2-NiCr-, Cr3C2-CoNiCrAlY-, and WC-CrC-Ni-based HVOF coatings are used. WC-CoCr-based HVOF coatings are generally used below 673 K. Twin wire arc (TWA) spraying of Tafa 140 MXC and SHS 7170 cored wires is used for a wide range of applications for a temperature up to 1073 K. Laser surface modification of high chromium stainless steels for steam valve components and LPST blades is carried out regularly. TWA spraying using SHS 7170 cored wire, HP-HVOF coating using WC-CoCr powder, Ti6Al4V alloy, and high chromium stainless steels (X20Cr13, AISI 410, X10CrNiMoV1222, 13Cr4Ni, 17Cr4Ni) were selected in the present study. Using robotically controlled parameters, HPDL surface treatments of TWAS-coated high strength X10CrNiMoV1222 stainless steel and HP-HVOF-coated AISI 410 stainless steel samples were carried out and these were compared with HPDL-treated high chromium stainless steels and titanium alloy for high energy particle impact wear (HEPIW) resistance. The HPDL surface treatment of the coatings has improved the HEPIW resistance manifold. The improvement in HPDL-treated stainless steels and titanium alloys is marginal and it is not comparable with that of HPDL-treated coatings. These coatings were also compared with "as-sprayed" coatings for fracture toughness, microhardness, microstructure, and phase analyses. The HEPIW resistance has a strong relationship with the product of fracture toughness and microhardness of the HPDL-treated HP-HVOF and TWAS SHS 7170 coatings. This development opens up a possibility of using HPDL surface treatments in specialized areas where the problem of HEPIW is very severe. The HEPIW resistance of HPDL-treated high chromium stainless steels and

  7. Exploiting [2+2] cycloaddition chemistry: achievements with allenes.

    PubMed

    Alcaide, Benito; Almendros, Pedro; Aragoncillo, Cristina

    2010-02-01

    The allene moiety represents an excellent partner for the [2+2] cycloaddition with alkenes and alkynes, affording the cyclobutane and cyclobutene skeletons in a single step. This strategy has been widely studied under thermal, photochemical and microwave induced conditions. More recently, the use of transition metal catalysis has been introduced as an alternative relying on the activation of the allenic component. On the other hand, the intramolecular version has attracted much attention as a strategy for the synthesis of polycyclic compounds in a regio- and stereoselective fashion. This critical review focuses on the most recently developed [2+2] cycloadditions on allenes along with remarkable early works accounting for the mechanism, the regio- and diastereoselectivity of the cycloadducts formed (103 references).

  8. Fossil energy program. Progress report, July 1980

    SciTech Connect

    McNeese, L. E.

    1980-10-01

    This report - the seventy-second of a series - is a compendium of monthly progress reports for the ORNL research and development programs that are in support of the increased utilization of coal and other fossil fuel alternatives to oil and gas as sources of clean energy. The projects reported this month include those for coal conversion development, chemical research and development, materials technology, component development and process evaluation, technical support to major liquefaction projects, process and program analysis, fossil energy environmental analysis, coal preparation and waste utilization, coal preparation plant automation, atmospheric fluidized bed coal combustor for cogeneration, technical support to the TVA fluidized bed combustion demonstration plant program, fossil energy applications assessments, performance assurance system support for fossil energy projects, international assessment of atmospheric fluidized bed combustion technology, and PFBC systems analysis.

  9. Modes of Heme-Binding and Substrate Access for Cytochrome P450 CYP74A Revealed by Crystal Structures of Allene Oxide Synthase

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Cytochrome P450s exist ubiquitously in all organisms and are involved in many biological processes. Allene oxide synthase (AOS) is a P450 enzyme that plays a key role in the biosynthesis of oxylipin jasmonates which are involved in signal and defense reactions in higher plants. The crystal structure...

  10. 5. Historic American Buildings Survey Harold Allen, Photographer June 1964 ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    5. Historic American Buildings Survey Harold Allen, Photographer June 1964 TRIPLE STAINED GLASS WINDOWS AND COLUMN SUPPORTING BALCONY (EAST WINDOWS IN SOUTH WALL OF MAIN FLOOR OF AUDITORIUM) - Kehilath Anshe Ma'ariv Synagogue, 3301 South Indiana Avenue, Chicago, Cook County, IL

  11. Van Allen Probes Science Gateway: A Centralized Data Access Point

    NASA Astrophysics Data System (ADS)

    Romeo, G.; Barnes, R. J.; Ukhorskiy, A. Y.; Sotirelis, T.; Stephens, G. K.; Kessel, R.; Potter, M.

    2015-12-01

    The Van Allen Probes Science Gateway acts a centralized interface to the instrument Science Operation Centers (SOCs), provides mission planning tools, and hosts a number of science related activities such as the mission bibliography. Most importantly, the Gateway acts as the primary site for processing and delivering the Van Allen Probes Space Weather data to users. Over the past years, the web-site has been completely redesigned with the focus on easier navigation and improvements of the existing tools such as the orbit plotter, position calculator and magnetic footprint tool. In addition, a new data plotting facility has been added. Based on HTML5, which allows users to interactively plot Van Allen Probes science and space weather data. The user can tailor the tool to display exactly the plot they wish to see and then share this with other users via either a URL or by QR code. Various types of plots can be created, including, simple time series, data plotted as a function of orbital location, and time versus L-Shell, capability of visualizing data from both probes (A & B) on the same plot. In cooperation with all Van Allen Probes Instrument SOCs, the Science Gateway will soon be able to serve higher level data products (Level 3), and to visualize them via the above mentioned HTML5 interface. Users will also be able to create customized CDF files on the fly.

  12. 18. VIEW SHOWING, LEFT TO RIGHT, H. J. LAWSON, ALLEN ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    18. VIEW SHOWING, LEFT TO RIGHT, H. J. LAWSON, ALLEN MATTISON, SENATOR CARL HAYDEN, LIN B. ORME, PAUL ROCA, AND J. A. FRAPS. THE UPSTREAM FACE AND SPILLWAY GATES ARE VISIBLE IN THE BACKGROUND. October 1938 - Bartlett Dam, Verde River, Phoenix, Maricopa County, AZ

  13. James Van Allen and His Namesake NASA Mission

    NASA Astrophysics Data System (ADS)

    Baker, D. N.; Hoxie, V. C.; Jaynes, A.; Kale, A.; Kanekal, S. G.; Li, X.; Reeves, G. D.; Spence, H. E.

    2013-12-01

    In many ways, James A. Van Allen defined and "invented" modern space research. His example showed the way for government-university partners to pursue basic research that also served important national and international goals. He was a tireless advocate for space exploration and for the role of space science in the spectrum of national priorities.

  14. Regioselective intramolecular [3+2] annulation of allene-nitrones.

    PubMed

    Inagaki, Fuyuhiko; Kobayashi, Harumi; Mukai, Chisato

    2012-01-01

    The regioselective intramolecular 1,3-dipolar cycloaddition of the phenylsulfonylallene-nitrone derivatives has been developed. This reaction showed that the distal double bond of the allene exclusively reacted with the nitrone group to produce the bicyclic isoxazolidine derivatives regardless of the substitution pattern on the allenyl moiety.

  15. Thermal induced intramolecular [2 + 2] cycloaddition of allene-ACPs.

    PubMed

    Chen, Kai; Sun, Run; Xu, Qin; Wei, Yin; Shi, Min

    2013-06-28

    A facile synthetic method for preparation of bicyclo[4.2.0] nitrogen heterocycles has been developed via a thermal induced intramolecular [2 + 2] cycloaddition reaction of allene-ACPs. The DFT calculations indicate that this intramolecular cycloaddition proceeds in a concerted manner and a strained small ring is essential.

  16. The Evolving Space Weather System—Van Allen Probes Contribution

    NASA Astrophysics Data System (ADS)

    Zanetti, L. J.; Mauk, B. H.; Fox, N. J.; Barnes, R. J.; Weiss, M.; Sotirelis, T. S.; Raouafi, N.-E.; Kessel, R. L.; Becker, H. N.

    2014-10-01

    The overarching goal and purpose of the study of space weather is clear—to understand and address the issues caused by solar disturbances on humans and technological systems. Space weather has evolved in the past few decades from a collection of concerned agencies and researchers to a critical function of the National Weather Service of NOAA. The general effects have also evolved from the well-known telegraph disruptions of the mid-1800s to modern day disturbances of the electric power grid, communications and navigation, human spaceflight and spacecraft systems. The last two items in this list, and specifically the effects of penetrating radiation, were the impetus for the space weather broadcast implemented on NASA's Van Allen Probes' twin pair of satellites, launched in August of 2012 and orbiting directly through Earth's severe radiation belts. The Van Allen Probes mission, formerly the Radiation Belt Storm Probes (RBSP), was renamed soon after launch to honor the discoverer of Earth's radiation belts at the beginning of the space age, the late James Van Allen (the spacecraft themselves are still referred to as RBSP-A and RBSP-B). The Van Allen Probes are one part of NASA's Living With a Star program formulated to advance the scientific understanding of the connection between solar disturbances, the resulting heliospheric conditions, and their effects on the geospace and Earth environment.

  17. Restoring Fossil Creek

    ERIC Educational Resources Information Center

    Flaccus, Kathleen; Vlieg, Julie; Marks, Jane C.; LeRoy, Carri J.

    2004-01-01

    Fossil Creek had been dammed for the past 90 years, and plans were underway to restore the stream. The creek runs through Central Arizona and flows from the high plateaus to the desert, cutting through the same formations that form the Grand Canyon. This article discusses the Fossil Creek monitoring project. In this project, students and teachers…

  18. Propargyltrimethylsilanes as allene equivalents in transition metal-catalyzed [5 + 2] cycloadditions.

    PubMed

    Wender, Paul A; Inagaki, Fuyuhiko; Pfaffenbach, Magnus; Stevens, Matthew C

    2014-06-01

    Conventional allenes have not been effective π-reactive 2-carbon components in many intermolecular cycloadditions including metal-catalyzed [5 + 2] cycloadditions. We report herein that rhodium-catalyzed [5 + 2] cycloadditions of propargyltrimethylsilanes and vinylcyclopropanes provide, after in situ protodesilylation, a highly efficient route to formal allene cycloadducts. Propargyltrimethylsilanes function as safe, easily handled synthetic equivalents of gaseous allenes and hard-to-access monosubstituted allenes. In this one-flask procedure, they provide cycloadducts of what is formally addition to the more sterically encumbered allene double bond.

  19. Propargyltrimethylsilanes as Allene Equivalents in Transition Metal-Catalyzed [5 + 2] Cycloadditions

    PubMed Central

    2015-01-01

    Conventional allenes have not been effective π-reactive 2-carbon components in many intermolecular cycloadditions including metal-catalyzed [5 + 2] cycloadditions. We report herein that rhodium-catalyzed [5 + 2] cycloadditions of propargyltrimethylsilanes and vinylcyclopropanes provide, after in situ protodesilylation, a highly efficient route to formal allene cycloadducts. Propargyltrimethylsilanes function as safe, easily handled synthetic equivalents of gaseous allenes and hard-to-access monosubstituted allenes. In this one-flask procedure, they provide cycloadducts of what is formally addition to the more sterically encumbered allene double bond. PMID:24819093

  20. A study on the impact of nuclear power plant construction relative to decommissioning Fossil Fuel Power Plant in order to reduce carbon dioxide emissions using a modified Nordhaus Vensim DICE model

    NASA Astrophysics Data System (ADS)

    Colpetzer, Jason Lee

    The current levels of CO2 emissions and high levels accumulating in the atmosphere have climate scientists concerned. The Dynamic Integrated Climate Economy Model or "DICE" for short is a highly developed model that has been used to simulate climate change and evaluate factors addressing global warming. The model was developed by Yale's Nordhaus along with collaborators and the compilation of numerous scientific publications. The purpose of this study is to recreate DICE using Vensim and modify it to evaluate the use of nuclear power plants (NPPs) as a means to counter global temperature increases in the atmosphere and oceans and the associated cost of damages. The amount of greenhouse gas emissions from a NPP are about 6% per Megawatt as that from a Fossil Fuel Power Plant (FFPP). Based on this, a model was developed to simulate construction of NPPs with subsequent decommissioning of FFPPs with an equivalent power output. The results produced through multiple simulation runs utilizing variable NPP construction rates show that some minor benefit is achievable if all of the more than 10,000 FFPPs currently in operation in the U.S. are replaced with NPPs. The results show that a reduction in CO 2 emissions of 2.48% will occur if all of the FFPPs are decommissioned. At a minimum rate of 50 NPPs constructed per year, the largest reduction in CO2 in the atmosphere, 1.94% or 44.5 billion tons of carbon, is possible. This results in a reduction in global warming of 0.068°C or 1.31%. The results also show that this reduction in global warming will be equivalent to a reduction of 8.2% or $148 B in anticipated annual spending as a result of climate change damages. Further results indicate that using NPPs to address climate change will provide a small benefit; ultimately, it will not be enough to reduce CO2 emissions or atmospheric CO 2 to control global warming. The amount of CO2 in the atmosphere is predicted to be 1055 parts per million (ppm) even in the best case

  1. Magnetic resonance spectroscopy and imaging for the study of fossils.

    PubMed

    Giovannetti, Giulio; Guerrini, Andrea; Salvadori, Piero A

    2016-07-01

    Computed tomography (CT) has long been used for investigating palaeontological specimens, as it is a nondestructive technique which avoids the need to dissolve or ionize the fossil sample. However, magnetic resonance spectroscopy (MRS) and magnetic resonance imaging (MRI) have recently gained ground as analytical tools for examination of palaeontological samples, by nondestructively providing information about the structure and composition of fossils. While MRI techniques are able to reveal the three-dimensional geometry of the trace fossil, MRS can provide information on the chemical composition of the samples. The multidimensional nature of MR (magnetic resonance) signals has potential to provide rich three-dimensional data on the palaeontological specimens and also to help in elucidating paleopathological and paleoecological questions. In this work the verified applications and the emerging uses of MRI and MRS in paleontology are reviewed, with particular attention to fossil spores, fossil plants, ambers, fossil invertebrates, and fossil vertebrate studies.

  2. Fossil fuels -- future fuels

    SciTech Connect

    1998-03-01

    Fossil fuels -- coal, oil, and natural gas -- built America`s historic economic strength. Today, coal supplies more than 55% of the electricity, oil more than 97% of the transportation needs, and natural gas 24% of the primary energy used in the US. Even taking into account increased use of renewable fuels and vastly improved powerplant efficiencies, 90% of national energy needs will still be met by fossil fuels in 2020. If advanced technologies that boost efficiency and environmental performance can be successfully developed and deployed, the US can continue to depend upon its rich resources of fossil fuels.

  3. Obituary: James Alfred Van Allen, 1914-2006

    NASA Astrophysics Data System (ADS)

    Ludwig, George H.; McIlwain, Carl Edwin

    2006-12-01

    James Alfred Van Allen, world-renowned space scientist, died 9 August 2006 at the age of ninety-one. He succumbed to heart failure after a ten-week period of declining health. Van Allen served for his entire sixty-seven-year professional career as an amazingly productive researcher, space science spokesman, inspired teacher, and valued colleague. The realization by him and his associates that charged particles are trapped by the Earth's magnetic field began a whole new field of research, magnetospheric physics. Following that initial discovery, he and his associates quickly extended their observations, first to the inner planets, and then to the rest of the planets and beyond. During his tenure at Iowa, he and his group flew instruments on more than sixty successful Earth satellites and planetary spacecraft, including the first missions to the planets Venus, Mars, Jupiter, Saturn, Uranus, and Neptune. Van Allen's lifetime publication list numbers more than 275, of which many are widely-cited, seminal papers. He was the sole author of more than 125 of those papers. Beyond the research laboratory, Van Allen worked energetically throughout his career in establishing space research as a new branch of human inquiry. He was among the most sought-after as a committee member and adviser, working at the highest levels of government, including the White House and Congress, and at all levels of the national and international research establishments. Many presentations in the non-scientific arena helped to bring the exciting discoveries and challenges of space research to the attention of the general public. James Van Allen (Van to his many friends and colleagues) was born on 7 September 1914 on a small farm near Mount Pleasant, Iowa, the second of four sons of Alfred Morris Van Allen and Alma Olney Van Allen. After high school in Mount Pleasant, he entered Iowa Wesleyan College, majoring in physics and graduating summa cum laude. While there, he was introduced to geophysics

  4. Van Allen Probes: Resolving Fundamental Physics with Practical Consequences

    NASA Astrophysics Data System (ADS)

    Ukhorskiy, Aleksandr; Sibeck, David; Fox, Nicola; Mauk, Barry; Kessel, Ramona

    The Van Allen Probes twin spacecraft were launched on 30 August 2012 into nearly identical, 1.1 x 5.8 Re elliptical, low inclination (10°) Earth orbits with one of the two spacecraft lapping the other about every 2.5 months. The goal of the mission is to provide understanding of how populations of relativistic electrons and penetrating ions in space form or change in response to variable inputs of energy from the Sun. In this paper we overview the new understanding and discoveries of the Van Allen Probes science investigations since the operational mission began on 1 November 2012, which include formation of multiple coherently ordered structures within the outer electron belt and new persistent “zebra stripes” in the inner electron belt.

  5. Isomer-specific combustion chemistry in allene and propyne flames

    SciTech Connect

    Hansen, Nils; Miller, James A.; Westmoreland, Phillip R.; Kasper, Tina; Kohse-Hoeinghaus, Katharina; Wang, Juan; Cool, Terrill A.

    2009-11-15

    A combined experimental and modeling study is performed to clarify the isomer-specific combustion chemistry in flames fueled by the C{sub 3}H{sub 4} isomers allene and propyne. To this end, mole fraction profiles of several flame species in stoichiometric allene (propyne)/O{sub 2}/Ar flames are analyzed by means of a chemical kinetic model. The premixed flames are stabilized on a flat-flame burner under a reduced pressure of 25 Torr (=33.3 mbar). Quantitative species profiles are determined by flame-sampling molecular-beam mass spectrometry, and the isomer-specific flame compositions are unraveled by employing photoionization with tunable vacuum-ultraviolet synchrotron radiation. The temperature profiles are measured by OH laser-induced fluorescence. Experimental and modeled mole fraction profiles of selected flame species are discussed with respect to the isomer-specific combustion chemistry in both flames. The emphasis is put on main reaction pathways of fuel consumption, of allene and propyne isomerization, and of isomer-specific formation of C{sub 6} aromatic species. The present model includes the latest theoretical rate coefficients for reactions on a C{sub 3}H{sub 5} potential [J.A. Miller, J.P. Senosiain, S.J. Klippenstein, Y. Georgievskii, J. Phys. Chem. A 112 (2008) 9429-9438] and for the propargyl recombination reactions [Y. Georgievskii, S.J. Klippenstein, J.A. Miller, Phys. Chem. Chem. Phys. 9 (2007) 4259-4268]. Larger peak mole fractions of propargyl, allyl, and benzene are observed in the allene flame than in the propyne flame. In these flames virtually all of the benzene is formed by the propargyl recombination reaction. (author)

  6. Van Allen Probes Science Gateway and Space Weather Data Processing

    NASA Astrophysics Data System (ADS)

    Romeo, G.; Barnes, R. J.; Weiss, M.; Fox, N. J.; Mauk, B.; Potter, M.; Kessel, R.

    2014-12-01

    The Van Allen Probes Science Gateway acts as a centralized interface to the instrument Science Operation Centers (SOCs), provides mission planning tools, and hosts a number of science related activities such as the mission bibliography. Most importantly, the Gateway acts as the primary site for processing and delivering the VAP Space Weather data to users. Over the past year, the web-site has been completely redesigned with the focus on easier navigation and improvements of the existing tools such as the orbit plotter, position calculator and magnetic footprint tool. In addition, a new data plotting facility has been added. Based on HTML5, which allows users to interactively plot Van Allen Probes summary and space weather data. The user can tailor the tool to display exactly the plot they wish to see and then share this with other users via either a URL or by QR code. Various types of plots can be created, including simple time series, data plotted as a function of orbital location, and time versus L-Shell. We discuss the new Van Allen Probes Science Gateway and the Space Weather Data Pipeline.

  7. Fossil Simulation in the Classroom

    ERIC Educational Resources Information Center

    Hoehn, Robert G.

    1977-01-01

    Describes classroom science demonstrations and experiments that simulate the process of fossil formation. Lists materials, procedures and suggestions for successful activities. Includes ten student activities (coral fossils, leaf fossils, leaf scars, carbonization, etc.). Describes a fossil game in which students work in pairs. (CS)

  8. Fossilization of feathers

    NASA Astrophysics Data System (ADS)

    Davis, Paul G.; Briggs, Derek E. G.

    1995-09-01

    Scanning electron microscopy of feathers has revealed evidence that a bacterial glycocalyx (a network of exocellular polysaccharide fibers) played a role in promoting their fossilization in some cases. This mode of preservation has not been reported in other soft tissues. The majority of fossil feathers are preserved as carbonized traces. More rarely, bacteria on the surface are replicated by authigenic minerals (bacterial autolithification). The feathers of Archaeopteryx are preserved mainly by imprintation following early lithification of the substrate and decay of the feather. Lacustrine settings provide the most important taphonomic window for feather preservation. Preservation in terrestrial and normal-marine settings involves very different processes (in amber and in authigenically mineralized coprolites, respectively). Therefore, there may be a significant bias in the avian fossil record in favor of inland water habitats.

  9. Fossil generation restructuring in the Ukraine

    SciTech Connect

    Galambas, J.W.

    1996-12-31

    This paper describes the Ukrainian electrical system as it was in 1991, defines the need for restructuring, outlines the restructuring process, identifies a number of major obstacles that are hindering the implementation of the fossil generation, restructuring process, and points out major problems in the coal procurement system. It describes the visits to several Ukrainian power plants, defines restructuring success to date, makes suggestions for improved restructuring progress, highlights lessons learned, and enlightens the audience on the opportunities of investing in the Ukrainian power generation industry. The primary focus is on the Fossil Generator Advisor task, which was carried out under the direction of Hagler Bailly Consulting, Inc. (Hagler Bailly).

  10. Fossil fuel biomarkers in sewage sludges: environmental significance

    PubMed

    Payet; Bryselbout; Morel; Lichtfouse

    1999-10-01

    Fossil fuel biomarkers, or "molecular fossils," are specific organic substances found in coals, petroleums, and sedimentary rocks. They are formed during millions of years of sedimentary burial by geochemical alteration of biological molecules, such as cholesterol, under the effect of biodegradation, temperature, pressure, and mineral catalysis, to produce geochemically mature molecules, for example, aromatic steroids (Fig. 1). Since fossil fuel biomarkers have a very specific molecular structure betraying fossil fuel sources, such markers should be useful in assessing the fossil fuel contamination of various modern media such as soils, plants, waters, and modern sediments. Here the identification of fossil fuel biomarkers of high geothermal maturity in sewage sludges provides evidence of the contamination of sludges by petroleum products. The most likely sources of contamination are contaminated vegetal food, road dust, and soil particles carried by rain water.http://link. springer.de/link/service/journals/00114/bibs/9086010/90860484. htm

  11. Stereoselective rhodium-catalysed [2+2+2] cycloaddition of linear allene-ene/yne-allene substrates: reactivity and theoretical mechanistic studies.

    PubMed

    Haraburda, Ewelina; Torres, Óscar; Parella, Teodor; Solà, Miquel; Pla-Quintana, Anna

    2014-04-22

    Allene-ene-allene (2 and 5) and allene-yne-allene (3 and 7) N-tosyl and O-linked substrates were satisfactorily synthesised. The [2+2+2] cycloaddition reaction catalysed by the Wilkinson catalyst [RhCl(PPh3 )3 ] was evaluated. Substrates 2 and 5, which bear a double bond in the central position, gave a tricyclic structure in a reaction in which four contiguous stereogenic centres were formed as a single diastereomer. The reaction of substrates 3 and 7, which bear a triple bond in the central position, gave a tricyclic structure with a cyclohexenic ring core, again in a diastereoselective manner. All cycloadducts were formed by a regioselective reaction of the inner allene double bond and, therefore, feature an exocyclic diene motif. A Diels-Alder reaction on N-tosyl linked cycloadducts 8 and 10 allowed pentacyclic scaffolds to be diastereoselectively constructed. The reactivity of the allenes on [2+2+2] cycloaddition reactions was studied for the first time by density functional theory calculations. This mechanistic study rationalizes the order in which the unsaturations take part in the catalytic cycle, the reactivity of the two double bonds of the allene towards the [2+2+2] cycloaddition reaction, and the diastereoselectivity of the reaction.

  12. Recent synchronous radiation of a living fossil.

    PubMed

    Nagalingum, N S; Marshall, C R; Quental, T B; Rai, H S; Little, D P; Mathews, S

    2011-11-11

    Modern survivors of previously more diverse lineages are regarded as living fossils, particularly when characterized by morphological stasis. Cycads are often cited as a classic example, reaching their greatest diversity during the Jurassic-Cretaceous (199.6 to 65.5 million years ago) then dwindling to their present diversity of ~300 species as flowering plants rose to dominance. Using fossil-calibrated molecular phylogenies, we show that cycads underwent a near synchronous global rediversification beginning in the late Miocene, followed by a slowdown toward the Recent. Although the cycad lineage is ancient, our timetrees indicate that living cycad species are not much older than ~12 million years. These data reject the hypothesized role of dinosaurs in generating extant diversity and the designation of today's cycad species as living fossils. PMID:22021670

  13. Recent synchronous radiation of a living fossil.

    PubMed

    Nagalingum, N S; Marshall, C R; Quental, T B; Rai, H S; Little, D P; Mathews, S

    2011-11-11

    Modern survivors of previously more diverse lineages are regarded as living fossils, particularly when characterized by morphological stasis. Cycads are often cited as a classic example, reaching their greatest diversity during the Jurassic-Cretaceous (199.6 to 65.5 million years ago) then dwindling to their present diversity of ~300 species as flowering plants rose to dominance. Using fossil-calibrated molecular phylogenies, we show that cycads underwent a near synchronous global rediversification beginning in the late Miocene, followed by a slowdown toward the Recent. Although the cycad lineage is ancient, our timetrees indicate that living cycad species are not much older than ~12 million years. These data reject the hypothesized role of dinosaurs in generating extant diversity and the designation of today's cycad species as living fossils.

  14. Fossil-Fired Boilers

    1993-09-23

    Boiler Performance Model (BPM 3.0S) is a set of computer programs developed to analyze the performance of fossil-fired utility boilers. The programs can model a wide variety of boiler designs, and can model coal, oil, or natural gas firing. The programs are intended for use by engineers performing analyses of alternative fuels, alternative operating modes, or boiler modifications.

  15. Advanced fossil energy utilization

    SciTech Connect

    Shekhawat, D.; Berry, D.; Spivey, J.; Pennline, H.; Granite, E.

    2010-01-01

    This special issue of Fuel is a selection of papers presented at the symposium ‘Advanced Fossil Energy Utilization’ co-sponsored by the Fuels and Petrochemicals Division and Research and New Technology Committee in the 2009 American Institute of Chemical Engineers (AIChE) Spring National Meeting Tampa, FL, on April 26–30, 2009.

  16. Assessment of the US EPA's determination of the role for CO2 capture and storage in new fossil fuel-fired power plants.

    PubMed

    Clark, Victoria R; Herzog, Howard J

    2014-07-15

    On September 20, 2013, the US Environmental and Protection Agency (EPA) proposed a revised rule for "Standards of Performance for Greenhouse Gas Emissions from New Stationary Sources: Electric Utility Generating Units". These performance standards set limits on the amount of carbon dioxide (CO2) that can be emitted per megawatt-hour (MWh) of electricity generation from new coal-fired and natural gas-fired power plants built in the US. These limits were based on determinations of "best system of emission reduction (BSER) adequately demonstrated". Central in this determination was evaluating whether Carbon Dioxide Capture and Storage (CCS) qualified as BSER. The proposed rule states that CCS qualifies as BSER for coal-fired generation but not for natural gas-fired generation. In this paper, we assess the EPA's analysis that resulted in this determination. We are not trying to judge what the absolute criteria are for CCS as the BSER but only the relative differences as related to coal- vs natural gas-fired technologies. We conclude that there are not enough differences between "base load" coal-fired and natural gas-fired power plants to justify the EPA's determination that CCS is the BSER for coal-fired power plants but not for natural gas-fired power plants.

  17. Fossil-bearing deposits from the Bukpyeong Formation (Miocene) in the Bukpyeong Basin at Donghae city, Gangwon-do, South Korea: occurrences, taphonomy and paleoenvironmental implications

    NASA Astrophysics Data System (ADS)

    Kim, Hyun Joo; Jeong, Eun Kyoung; Uemura, Kazuhiko; Kim, Kyungsik; Paik, In Sung

    2016-04-01

    Abundant and diverse plant fossils such as land plants and subaqueous plants, freshwater mollusc fossils and invertebrate trace fossils are found in the Miocene Bukpyeong Formation at Donghae city, Gangwon-do, South Korea. Occurrences and taphofacies of the fossil-bearing deposits from the Bukpyeong Formation are described and their taphonomy and paleoenvironmental implications are interpreted. Based on fossil occurrences, lithofacies and sedimentary features of the fossil-bearing deposits, eight taphofacies are classified as the following: (1) Taphofacies 1: Gastropod fossils in massive silty mudstone; (2) Taphofacies 2: Bivalve fossils in massive silty mudstone; (3) Taphofacies 3: Plant fossils (leaf fossils) in massive silty mudstone; (4) Taphofacies 4: Gastropod and plant fossils in massive silty mudstone; (5) Taphofacies 5: Plant fossils in weakly fissile silty mudstone; (6) Taphofacies 6: Plant fossils (leaf fossils) in thin-bedded and graded silty mudstone to mudstone (claystone); (7) Taphofacies 7: Plant fragment fossils in thin-bedded and graded silty mudstone to mudstone (claystone); (8) Taphofacies 8: Plant debris in planar- to cross-laminated fine-grained sandstone. Taphonomy of taphofacies 1, 2, and 4 including freshwater mollusc fossils is interpreted to have been reworked or transported by turbidity currents after death and deposited in shallow lake to open lake. Taphonomy of taphofacies 3, 5, 6, and 7 including plant fossils is interpreted to have been transported by input of episodic flooding in the land and deposited by settling down in open lake. Taphofacies 8 including plant debris has been deposited in shallow lake by input of intensive episodic flooding from the land. The occurrences and taphofacies of the fossil-bearing deposits indicate that most of the fossils were transported by turbidity current induced by input of episodic flooding in the land and deposited in shallow lake to open lake. Moreover, plant fossils from the Bukpyeong

  18. Linolenate 9R-dioxygenase and allene oxide synthase activities of Lasiodiplodia theobromae.

    PubMed

    Jernerén, Fredrik; Eng, Felipe; Hamberg, Mats; Oliw, Ernst H

    2012-01-01

    Jasmonic acid (JA) is synthesized from linolenic acid (18:3n-3) by sequential action of 13-lipoxygenase, allene oxide synthase (AOS), and allene oxide cyclase. The fungus Lasiodiplodia theobromae can produce large amounts of JA and was recently reported to form the JA precursor 12-oxophytodienoic acid. The objective of our study was to characterize the fatty acid dioxygenase activities of this fungus. Two strains of L. theobromae with low JA secretion (~0.2 mg/L medium) oxygenated 18:3n-3 to 5,8-dihydroxy-9Z,12Z,15Z-octadecatrienoic acid as well as 9R-hydroperoxy-10E,12Z,15Z-octadecatrienoic acid, which was metabolized by an AOS activity into 9-hydroxy-10-oxo-12Z,15Z-octadecadienoic acid. Analogous conversions were observed with linoleic acid (18:2n-6). Studies using [11S-(2)H]18:2n-6 revealed that the putative 9R-dioxygenase catalyzed stereospecific removal of the 11R hydrogen followed by suprafacial attack of dioxygen at C-9. Mycelia from these strains of L. theobromae contained 18:2n-6 as the major polyunsaturated acid but lacked 18:3n-3. A third strain with a high secretion of JA (~200 mg/L) contained 18:3n-3 as a major fatty acid and produced 5,8-dihydroxy-9Z,12Z,15Z-octadecatrienoic acid from added 18:3n-3. This strain also lacked the JA biosynthetic enzymes present in higher plants. PMID:22048860

  19. Sustainability of Fossil Fuels

    NASA Astrophysics Data System (ADS)

    Lackner, K. S.

    2002-05-01

    For a sustainable world economy, energy is a bottleneck. Energy is at the basis of a modern, technological society, but unlike materials it cannot be recycled. Energy or more precisely "negentropy" (the opposite of entropy) is always consumed. Thus, one either accepts the use of large but finite resources or must stay within the limits imposed by dilute but self-renewing resources like sunlight. The challenge of sustainable energy is exacerbated by likely growth in world energy demand due to increased population and increased wealth. Most of the world still has to undergo the transition to a wealthy, stable society with the near zero population growth that characterizes a modern industrial society. This represents a huge unmet demand. If ten billion people were to consume energy like North Americans do today, world energy demand would be ten times higher. In addition, technological advances while often improving energy efficiency tend to raise energy demand by offering more opportunity for consumption. Energy consumption still increases at close to the 2.3% per year that would lead to a tenfold increase over the course of the next century. Meeting future energy demands while phasing out fossil fuels appears extremely difficult. Instead, the world needs sustainable or nearly sustainable fossil fuels. I propose the following definition of sustainable under which fossil fuels would well qualify: The use of a technology or resource is sustainable if the intended and unintended consequences will not force its abandonment within a reasonable planning horizon. Of course sustainable technologies must not be limited by resource depletion but this is only one of many concerns. Environmental impacts, excessive land use, and other constraints can equally limit the use of a technology and thus render it unsustainable. In the foreseeable future, fossil fuels are not limited by resource depletion. However, environmental concerns based on climate change and other environmental

  20. Hovering and forward flight energetics in Anna's and Allen's hummingbirds.

    PubMed

    Clark, Christopher James; Dudley, Robert

    2010-01-01

    Aerodynamic theory predicts that the mechanical costs of flight are lowest at intermediate flight speeds; metabolic costs of flight should trend similarly if muscle efficiency is constant. We measured metabolic rates for nine Anna's hummingbirds (Calypte anna) and two male Allen's hummingbirds (Selasphorus sasin) feeding during flight from a free-standing mask over a range of airspeeds. Ten of 11 birds exhibited higher metabolic costs during hovering than during flight at intermediate airspeeds, whereas one individual exhibited comparable costs at hovering and during forward flight up to speeds of approximately 7 m s(-1). Flight costs of all hummingbirds increased at higher airspeeds. Relative to Anna's hummingbirds, Allen's hummingbirds exhibited deeper minima in the power curve, possibly due to higher wing loadings and greater associated costs of induced drag. Although feeding at a mask in an airstream may reduce body drag and, thus, the contributions of parasite power to overall metabolic expenditure, these results suggest that hummingbird power curves are characterized by energetic minima at intermediate speeds relative to hovering costs. PMID:20455711

  1. Hovering and forward flight energetics in Anna's and Allen's hummingbirds.

    PubMed

    Clark, Christopher James; Dudley, Robert

    2010-01-01

    Aerodynamic theory predicts that the mechanical costs of flight are lowest at intermediate flight speeds; metabolic costs of flight should trend similarly if muscle efficiency is constant. We measured metabolic rates for nine Anna's hummingbirds (Calypte anna) and two male Allen's hummingbirds (Selasphorus sasin) feeding during flight from a free-standing mask over a range of airspeeds. Ten of 11 birds exhibited higher metabolic costs during hovering than during flight at intermediate airspeeds, whereas one individual exhibited comparable costs at hovering and during forward flight up to speeds of approximately 7 m s(-1). Flight costs of all hummingbirds increased at higher airspeeds. Relative to Anna's hummingbirds, Allen's hummingbirds exhibited deeper minima in the power curve, possibly due to higher wing loadings and greater associated costs of induced drag. Although feeding at a mask in an airstream may reduce body drag and, thus, the contributions of parasite power to overall metabolic expenditure, these results suggest that hummingbird power curves are characterized by energetic minima at intermediate speeds relative to hovering costs.

  2. Observations of Whistler-Mode Chorus with Van Allen Probes

    NASA Astrophysics Data System (ADS)

    Kurth, William; Hospodarsky, George; Santolik, Ondrej; Kletzing, Craig; Bounds, Scott

    2014-10-01

    The Van Allen Probes mission provides an excellent opportunity to observe whistler-mode chorus and its role in the radiation belts. The plasma wave instrument on the two probes, called Waves, includes six identical waveform receivers covering the frequency range from 10 Hz to 12 kHz. The instrument measures three orthogonal magnetic field components and three orthogonal electric field components of waves. This complement supports wave-normal and Poynting flux analyses of chorus as well as other wave modes that interact with radiation belt particles. Extensive use of burst modes provides multicomponent waveforms enabling the study of individual chorus elements, including their substructure. The early-mission publications confirm the importance of chorus to the local acceleration of electrons in the outer radiation belts. The orbital precession of the twin Van Allen Probes through a complete range of local times now allows for a new survey of the distribution of chorus emissions. Hence, we now have the tools to study chorus from the nonlinear growth in chorus element substructures through synoptic studies of the near-equatorial occurrence of chorus out to a distance of approximately 5.8 Earth radii.

  3. Neuroinformatics of the Allen Mouse Brain Connectivity Atlas.

    PubMed

    Kuan, Leonard; Li, Yang; Lau, Chris; Feng, David; Bernard, Amy; Sunkin, Susan M; Zeng, Hongkui; Dang, Chinh; Hawrylycz, Michael; Ng, Lydia

    2015-02-01

    The Allen Mouse Brain Connectivity Atlas is a mesoscale whole brain axonal projection atlas of the C57Bl/6J mouse brain. Anatomical trajectories throughout the brain were mapped into a common 3D space using a standardized platform to generate a comprehensive and quantitative database of inter-areal and cell-type-specific projections. This connectivity atlas has several desirable features, including brain-wide coverage, validated and versatile experimental techniques, a single standardized data format, a quantifiable and integrated neuroinformatics resource, and an open-access public online database (http://connectivity.brain-map.org/). Meaningful informatics data quantification and comparison is key to effective use and interpretation of connectome data. This relies on successful definition of a high fidelity atlas template and framework, mapping precision of raw data sets into the 3D reference framework, accurate signal detection and quantitative connection strength algorithms, and effective presentation in an integrated online application. Here we describe key informatics pipeline steps in the creation of the Allen Mouse Brain Connectivity Atlas and include basic application use cases.

  4. Early evolutionary colocalization of the nuclear ribosomal 5S and 45S gene families in seed plants: evidence from the living fossil gymnosperm Ginkgo biloba.

    PubMed

    Galián, J A; Rosato, M; Rosselló, J A

    2012-06-01

    In seed plants, the colocalization of the 5S loci within the intergenic spacer (IGS) of the nuclear 45S tandem units is restricted to the phylogenetically derived Asteraceae family. However, fluorescent in situ hybridization (FISH) colocalization of both multigene families has also been observed in other unrelated seed plant lineages. Previous work has identified colocalization of 45S and 5S loci in Ginkgo biloba using FISH, but these observations have not been confirmed recently by sequencing a 1.8 kb IGS. In this work, we report the presence of the 45S-5S linkage in G. biloba, suggesting that in seed plants the molecular events leading to the restructuring of the ribosomal loci are much older than estimated previously. We obtained a 6.0 kb IGS fragment showing structural features of functional sequences, and a single copy of the 5S gene was inserted in the same direction of transcription as the ribosomal RNA genes. We also obtained a 1.8 kb IGS that was a truncate variant of the 6.0 kb IGS lacking the 5S gene. Several lines of evidence strongly suggest that the 1.8 kb variants are pseudogenes that are present exclusively on the satellite chromosomes bearing the 45S-5S genes. The presence of ribosomal IGS pseudogenes best reconciles contradictory results concerning the presence or absence of the 45S-5S linkage in Ginkgo. Our finding that both ribosomal gene families have been unified to a single 45S-5S unit in Ginkgo indicates that an accurate reassessment of the organization of rDNA genes in basal seed plants is necessary.

  5. Ants and the fossil record.

    PubMed

    LaPolla, John S; Dlussky, Gennady M; Perrichot, Vincent

    2013-01-01

    The dominance of ants in the terrestrial biosphere has few equals among animals today, but this was not always the case. The oldest ants appear in the fossil record 100 million years ago, but given the scarcity of their fossils, it is presumed they were relatively minor components of Mesozoic insect life. The ant fossil record consists of two primary types of fossils, each with inherent biases: as imprints in rock and as inclusions in fossilized resins (amber). New imaging technology allows ancient ant fossils to be examined in ways never before possible. This is particularly helpful because it can be difficult to distinguish true ants from non-ants in Mesozoic fossils. Fossil discoveries continue to inform our understanding of ancient ant morphological diversity, as well as provide insights into their paleobiology.

  6. Suppression of allene oxide synthase 3 in potato increases degree of arbuscular mycorrhizal fungal colonization.

    PubMed

    Morcillo, Rafael Jorge León; Navarrete, María Isabel Tamayo; Bote, Juan Antonio Ocampo; Monguio, Salomé Prat; García-Garrido, José Manuel

    2016-01-15

    Arbuscular mycorrhizal (AM) is a mutually beneficial interaction among higher plants and soil fungi of the phylum Glomeromycota. Numerous studies have pointed that jasmonic acid plays an important role in the development of the intraradical fungus. This compound belongs to a group of biologically active compounds known as oxylipins which are derived from the oxidative metabolism of polyunsaturated fatty acids. Studies of the regulatory role played by oxylipins in AM colonization have generally focused on jasmonates, while few studies exist on the 9-LOX pathway of oxylipins during AM formation. Here, the cDNA of Allene oxide synthase 3 (AOS3), a key enzyme in the 9-LOX pathway, was used in the RNA interference (RNAi) system to transform potato plants in order to suppress its expression. Results show increases in AOS3 gene expression and 9-LOX products in roots of wild type potato mycorrhizal plants. The suppression of AOS3 gene expression increases the percentage of root with mycorrhizal colonization at early stages of AM formation. AOS3 RNA interference lead to an induction of LOXA and 13-LOX genes, a reduction in AOS3 derived 9-LOX oxylipin compounds and an increase in jasmonic acid content, suggesting compensation between 9 and 13-LOX pathways. The results in a whole support the hypothesis of a regulatory role for the 9-LOX oxylipin pathway during mycorrhization.

  7. Suppression of allene oxide synthase 3 in potato increases degree of arbuscular mycorrhizal fungal colonization.

    PubMed

    Morcillo, Rafael Jorge León; Navarrete, María Isabel Tamayo; Bote, Juan Antonio Ocampo; Monguio, Salomé Prat; García-Garrido, José Manuel

    2016-01-15

    Arbuscular mycorrhizal (AM) is a mutually beneficial interaction among higher plants and soil fungi of the phylum Glomeromycota. Numerous studies have pointed that jasmonic acid plays an important role in the development of the intraradical fungus. This compound belongs to a group of biologically active compounds known as oxylipins which are derived from the oxidative metabolism of polyunsaturated fatty acids. Studies of the regulatory role played by oxylipins in AM colonization have generally focused on jasmonates, while few studies exist on the 9-LOX pathway of oxylipins during AM formation. Here, the cDNA of Allene oxide synthase 3 (AOS3), a key enzyme in the 9-LOX pathway, was used in the RNA interference (RNAi) system to transform potato plants in order to suppress its expression. Results show increases in AOS3 gene expression and 9-LOX products in roots of wild type potato mycorrhizal plants. The suppression of AOS3 gene expression increases the percentage of root with mycorrhizal colonization at early stages of AM formation. AOS3 RNA interference lead to an induction of LOXA and 13-LOX genes, a reduction in AOS3 derived 9-LOX oxylipin compounds and an increase in jasmonic acid content, suggesting compensation between 9 and 13-LOX pathways. The results in a whole support the hypothesis of a regulatory role for the 9-LOX oxylipin pathway during mycorrhization. PMID:26629611

  8. Astronaut Andrew M. Allen, mission commander, sets up systems for a television downlink on the

    NASA Technical Reports Server (NTRS)

    1996-01-01

    STS-75 ONBOARD VIEW --- Astronaut Andrew M. Allen, mission commander, sets up systems for a television downlink on the flight deck of the Space Shuttle Columbia. Allen was joined by four other astronauts and an international payload specialist for more than 16 days of research aboard Columbia. The photograph was taken with a 70mm handheld camera.

  9. Q & A with Ed Tech Leaders: Interview with Michael W. Allen

    ERIC Educational Resources Information Center

    Shaughnessy, Michael F.

    2014-01-01

    Michael W. Allen, the Chairman and CEO of Allen Interactions, is an architect of interactive multimedia learning and is recognized for his many insights, inventions, and presentations. With over 50 years of experience in e-learning, both in academic and corporate settings, he is known for his role in creating Authorware and overseeing the work of…

  10. Highly Regioselective Radical Amination of Allenes: Direct Synthesis of Allenamides and Tetrasubstituted Alkenes.

    PubMed

    Zhang, Ge; Xiong, Tao; Wang, Zining; Xu, Guoxing; Wang, Xuedan; Zhang, Qian

    2015-10-19

    The first controllable, regioselective radical amination of allenes with N-fluoroarylsulfonimide is described to proceed under very mild reaction conditions. With this methodology, a general and straightforward route for the synthesis of both allenamides and fluorinated tetrasubstituted alkenes was realized from a wide range of terminal and internal allenes.

  11. Meeting the Challenge of Intermolecular Gold(I)-Catalyzed Cycloadditions of Alkynes and Allenes

    PubMed Central

    Muratore, Michael E; Homs, Anna; Obradors, Carla; Echavarren, Antonio M

    2014-01-01

    The development of gold(I)-catalyzed intermolecular carbo- and hetero-cycloadditions of alkynes and allenes has been more challenging than their intramolecular counterparts. Here we review, with a mechanistic perspective, the most fundamental intermolecular cycloadditions of alkynes and allenes with alkenes. PMID:25048645

  12. Ugi/Himbert Arene/Allene Diels-Alder Cycloaddition to Synthesize Strained Polycyclic Skeleton.

    PubMed

    Cheng, Guangsheng; He, Xiang; Tian, Lumin; Chen, Jiawen; Li, Chunju; Jia, Xueshun; Li, Jian

    2015-11-01

    The present work disclosed an efficient multicomponent reaction of isocyanide, allenic acid, aldehyde (ketone), and aniline. This protocol undergoes Ugi reaction followed by an intramolecular arene/allene Diels-Alder sequence, thus providing a rapid access to synthesize strained polycyclic skeletons.

  13. Petrography and microanalysis of Pennsylvanian coal-ball concretions (Herrin Coal, Illinois Basin, USA): Bearing on fossil plant preservation and coal-ball origins

    NASA Astrophysics Data System (ADS)

    Siewers, Fredrick D.; Phillips, Tom L.

    2015-11-01

    Petrographic analyses of 25 coal balls from well-studied paleobotanical profiles in the Middle Pennsylvanian Herrin Coal (Westphalian D, Illinois Basin) and five select coal balls from university collections, indicate that Herrin Coal-ball peats were permineralized by fibrous and non-fibrous carbonates. Fibrous carbonates occur in fan-like to spherulitic arrays in many intracellular (within tissue) pores, and are best developed in relatively open extracellular (between plant) pore spaces. Acid etched fibrous carbonates appear white under reflected light and possess a microcrystalline texture attributable to abundant microdolomite. Scanning electron microscopy, X-ray diffraction, and electron microprobe analysis demonstrate that individual fibers have a distinct trigonal prism morphology and are notable for their magnesium content (≈ 9-15 mol% MgCO3). Non-fibrous carbonates fill intercrystalline spaces among fibers and pores within the peat as primary precipitates and neomorphic replacements. In the immediate vicinity of plant cell walls, non-fibrous carbonates cut across fibrous carbonates as a secondary, neomorphic phase attributed to coalification of plant cell walls. Dolomite occurs as diagenetic microdolomite associated with the fibrous carbonate phase, as sparite replacements, and as void-filling cement. Maximum dolomite (50-59 wt.%) is in the top-of-seam coal-ball zone at the Sahara Mine, which is overlain by the marine Anna Shale. Coal-ball formation in the Herrin Coal began with the precipitation of fibrous high magnesium calcite. The trigonal prism morphology of the carbonate fibers suggests rapid precipitation from super-saturated, meteoric pore waters. Carbonate precipitation from marine waters is discounted on the basis of stratigraphic, paleobotanical, and stable isotopic evidence. Most non-fibrous carbonate is attributable to later diagenetic events, including void-fill replacements, recrystallization, and post-depositional fracture fills. Evidence

  14. The largest fossil rodent

    PubMed Central

    Rinderknecht, Andrés; Blanco, R. Ernesto

    2008-01-01

    The discovery of an exceptionally well-preserved skull permits the description of the new South American fossil species of the rodent, Josephoartigasia monesi sp. nov. (family: Dinomyidae; Rodentia: Hystricognathi: Caviomorpha). This species with estimated body mass of nearly 1000 kg is the largest yet recorded. The skull sheds new light on the anatomy of the extinct giant rodents of the Dinomyidae, which are known mostly from isolated teeth and incomplete mandible remains. The fossil derives from San José Formation, Uruguay, usually assigned to the Pliocene–Pleistocene (4–2 Myr ago), and the proposed palaeoenvironment where this rodent lived was characterized as an estuarine or deltaic system with forest communities. PMID:18198140

  15. Landscape planning for the future: using fossil records to independently validate potential threats, opportunities and likely future range-shifts for socio-economically valuable plant species in Europe and sub-Saharan Africa

    NASA Astrophysics Data System (ADS)

    Macias Fauria, M.; Willis, K. J.

    2011-12-01

    Bioclimatic Envelope Models (BEMs) for a set of socio-economically important tree species in Europe were independently validated using a hindcasting approach and fossil pollen records spanning the last 1000 years, including the Medieval Warm Period (MWP), the Little Ice Age (LIA) and the 20th Century warming (PRES). The aim was to determine the accuracy of combining BEMs and palaeoecological data to predict continental-scale changes in distribution, and the availability of fossil data to hindcast economically important species. Eight types of BEMs were implemented in this study, covering most state-of-the-art modelling techniques. Present and palaeoclimatic data were obtained from the Atmosphere-Ocean Global Circulation Model ECHO-G. Last millenium was divided into three climatically distinct periods: MWP (AD 900-1300), LIA (AD 1600-1850) and PRES (AD 1900-2000). Models were calibrated for each period and validated with climatic and pollen data from the remaining periods. Successfully validated models were projected onto a 1-degree European grid, allowing the reconstruction of past modelled species distributions. BEMs were successfully validated with independent data. Strong model performance suggested high potential for BEMs to be used to model future species distributions, and highlighted the importance of palaeoecological data to independently validate these models, taking into account the scales at which this data operates. Although valid, BEMs showed poorer performance with species heavily managed and/or growing in heterogeneous terrain or with discontinuous distributions. Last millennium in Europe was characterized by an increase of crop woody species and a decline of forest species, suggesting an increasing land use by humans. The same approach was then implemented to a set of sub-Saharan plant species of high importance as a source of food, wood, and other ecosystem services such as carbon storage or erosion protection. The African study covered most of the

  16. Geomagnetic Storms and EMIC waves: Van Allen Probe observations

    NASA Astrophysics Data System (ADS)

    Wang, D.; Yuan, Z.; Yu, X.; Deng, X.; Zhou, M.; Huang, S.; Li, H.

    2015-12-01

    EMIC waves are believed to play an important role in the dynamics of ring current ions and radiation belt electrons, especially during geomagnetic storms. But, in which phase of the storm do the EMIC waves occur more is still under debate. Ground and some low altitude satellite observations demonstrate that EMIC waves are observed more frequently during the recovery phase, rather than during the main phase. Halford et al. 2010 looked at the occurrences of EMIC waves during 119 storms occurring throughout the CRRES mission. They found that 49 of the 119 (41%) storms observed EMIC waves and the majority, 56.25%, of storm time EMIC waves occurring during the main phase, while 35.57% in the recovery phase. One shortcoming of the CRRES mission is that the apogee of it did not covered the dawn to noon sector during its life time. Therefore, some dayside EMIC waves caused by the compression of magnetosphere may not be included in Halford et al 2010, as they mentioned. The apogee of Van Allen Probes covered all the MLT sectors from their launch to April 2014. Utilizing the data from magnetometer instrument on board the Van Allen Probe A, Wang et al. 2015 studied the occurrence rate of H-band and He-band EMIC waves in different MLT sectors, and Yu et al 2015 reported the O-band EMIC wave observations. In this work, we analysis the occurrence of EMIC waves during storms. According to the criteria of storm in Halford et al. 2010, we find 76 storms in our interested period, 8 September 2012 to 30 April 2014, when the apogee of Van Allen Probe A covered all the MLT sectors. To identify the onset of geomagnetic storm more accurately, we corrected the Sym-H index referred to Zhao and Zong (2011), which is helpful to demonstrate the activity of ring current. 50 of the 76 storms (66%) observed 124 EMIC wave events, in which 80 (64.5%) EMIC wave events are found in the recovery phase, more than the EMIC wave events in the main phase (35, 28.2%). The remaining 9 (7.3%) EMIC wave

  17. Fossil Plants As Proxies For Climate Change In The Tropics During Greenhouse To Icehouse And Icehouse To Greenhouse Conditions During The Late Paleozoic

    NASA Astrophysics Data System (ADS)

    Pfefferkorn, H. W.; Gastaldo, R. A.; DiMichele, W. A.

    2011-12-01

    Vascular plants first experienced the effects of major glaciation during the Carboniferous (glaciation ~ 326 to 305 million years ago). The response of tropical vegetation to these climatic fluctuations, especially the transitions from greenhouse to icehouse conditions (ice age sensu lato) and back to warm times, can now be characterized based on results from large paleobotanical data sets originally collected to solve stratigraphic and paleoecologic questions. The data come from North America and central Europe, which at that time were part of a single continent situated in the tropics. At the onset of icehouse conditions innovation (species origination) occurred in ever-wet climates and environments, while floras in drier environments were still dominated by holdovers/survivors. The changes that did occur happened step-wise spread over a significant time. During the height of the ice age, glacial-interglacial cycles produced large sea-level fluctuations, and concomitant climatic changes, so that significant areas of continents in the tropics were alternately covered by shallow seas or densely vegetated terrestrial environments. In spite of the repeated destruction of wet lowland habitats during each transgression of the sea, most of the species and the basic configuration of the plant communities in the wetland biome returned again and again. This resilience demonstrates that glacial-interglacial cycles by themselves do not produce extirpations or extinctions. Actually, the Carboniferous icehouse time has the lowest values for extinctions or originations. At the transition from icehouse to greenhouse conditions evolutionary innovation was occurring on a major scale in dry environments while wet environments retained their "conservative" species make up. Thus, environmental threshold-crossing marked both the beginning and end of this cold interval, and produced extinctions and innovation, although a reversal is seen in the environments that support innovation at

  18. Fossil-energy program. Progress report for June 1981

    SciTech Connect

    Not Available

    1981-08-01

    This report - the eighty-third of series - is a compendium of monthly progress reports for the ORNL research and development programs that are in support of the increased utilization of coal and other fossil fuel alternatives as sources of clean energy. The projects reported this month include those for coal conversion development, chemical research and development, materials technology, component development and process evaluation, technical support to major liquefaction projects, process analysis and engineering evaluations, fossil energy environmental analysis, flue gas desulfurization, coal preparation waste utilization, atmospheric fluidized bed coal combustor for cogeneration, TVA FBC demonstration plant program technical support, PFBC systems analysis, fossil fuel applications assessments, performance assurance system support for fossil energy projects, international energy technology assessment, generalized equilibrium models for liquid and gaseous fuel supplies, analyses of coal production goals, and fossil energy information center.

  19. (Hetero)aromatics from dienynes, enediynes and enyne-allenes.

    PubMed

    Raviola, Carlotta; Protti, Stefano; Ravelli, Davide; Fagnoni, Maurizio

    2016-08-01

    The construction of aromatic rings has become a key objective for organic chemists. While several strategies have been developed for the functionalization of pre-formed aromatic rings, the direct construction of an aromatic core starting from polyunsaturated systems is yet a less explored field. The potential of such reactions in the formation of aromatics increased at a regular pace in the last few years. Nowadays, there are reliable and well-established procedures to prepare polyenic derivatives, such as dienynes, enediynes, enyne-allenes and hetero-analogues. This has stimulated their use in the development of innovative cycloaromatizations. Different examples have recently emerged, suggesting large potential of this strategy in the preparation of (hetero)aromatics. Accordingly, this review highlights the recent advancements in this field and describes the different conditions exploited to trigger the process, including thermal and photochemical activation, as well as the use of transition metal catalysis and the addition of electrophiles/nucleophiles or radical species.

  20. Ion spectral structures observed by the Van Allen Probes

    NASA Astrophysics Data System (ADS)

    Ferradas, C.; Zhang, J.; Spence, H. E.; Kistler, L. M.; Larsen, B.; Reeves, G. D.; Skoug, R. M.; Funsten, H. O.

    2015-12-01

    During the last decades several missions have recorded the presence of dynamic spectral features of energetic ions in the inner magnetosphere. Previous studies have reported single "nose-like" structures occurring alone and simultaneous nose-like structures (up to three). These ion structures are named after the characteristic shapes of energy bands or gaps in the energy-time spectrograms of in situ measured ion fluxes. They constitute the observational signatures of ion acceleration, transport, and loss in the global magnetosphere. The HOPE mass spectrometer onboard the Van Allen Probes measures energetic hydrogen, helium, and oxygen ions near the inner edge of the plasma sheet, where these ion structures are observed. We present a statistical study of nose-like structures, using 2-years measurements from the HOPE instrument. The results provide important details about the spatial distribution (dependence on geocentric distance), spectral features of the structures (differences among species), and geomagnetic conditions under which these structures occur.

  1. Van Allen Probe Charging During the St. Patrick's Day Event

    NASA Technical Reports Server (NTRS)

    Parker, L. Neergaard; Minow, J. I.

    2015-01-01

    The geomagnetic storms on and around March 17, 2015 marked the largest storms seen in the declining phase of the solar cycle to date. We use the Helium Oxygen Proton Electron (HOPE) mass spectrometer on board the Van Allen Probe - A and B satellites to study in detail the charging effects seen on these spacecraft during this time. Ion particle flux data provides information on the magnitude of the charging events using the ion line charging signature due to low energy ions accelerated by the spacecraft potential. Electron flux observations are used to correlate the charging environment with variations in spacecraft potential through the event. We also investigate the density and temperature of ions and electrons during the time of the charging event.

  2. The Allen telescope array: Commensal and efficient SETI

    NASA Astrophysics Data System (ADS)

    Deboer, David R.

    2006-12-01

    The Allen telescope array (ATA) currently under construction affords the possibility of a dedicated and highly efficient SETI program that may be done commensally with other radio astronomy programs. This symbiosis is important in order to maintain and sustain the long-term effort that may be required in order to achieve success as a positive or null result. The technology that is being exploited is the construction of many small elements that allow large fields-of-view at high sensitivity, the use of ultra-wideband front-ends, and the use of flexible digital “intermediate frequency (IF)” systems. The project is under construction in phases, with the first 32 antennas expected to be functional in the fall of 2004, the next 173 dishes operational early 2006, with plans for 350 antennas total within this decade.

  3. Comparative evaluation of solar, fission, fusion, and fossil energy resources. Part 4: Energy from fossil fuels

    NASA Technical Reports Server (NTRS)

    Williams, J. R.

    1974-01-01

    The conversion of fossil-fired power plants now burning oil or gas to burn coal is discussed along with the relaxation of air quality standards and the development of coal gasification processes to insure a continued supply of gas from coal. The location of oil fields, refining areas, natural gas fields, and pipelines in the U.S. is shown. The technologies of modern fossil-fired boilers and gas turbines are defined along with the new technologies of fluid-bed boilers and MHD generators.

  4. Abstracts: Eighth Annual Conference on Fossil Energy Materials. Fossil Energy Program

    SciTech Connect

    Not Available

    1994-07-01

    Abstracts are presented for about 40 papers. The Fossil Energy Advanced Research and Technology Development Materials program is an integrated materials research activity of the fossil energy coal program, whose objective is to conduct R and D for all advanced coal conversion and utilization technologies. The program is aimed at understanding materials behavior in coal system environments and the development of new materials for improving plant operations and reliability. A generic approach is used for addressing multiple coal technologies; for example, the hot-gas particulate filter development is applicable to pressurized fluidized bed combustion, integrated coal gasification combined-cycle, coal combustion, and indirectly fired combined-cycle systems.

  5. Crystallization and preliminary X-ray analysis of allene oxide synthase, cytochrome P450 CYP74A2, from Parthenium argentatum

    SciTech Connect

    Chang, Zhenzhan; Li, Lenong; Pan, Zhiqiang; Wang, Xiaoqiang

    2008-07-01

    Allene oxide synthase, an atypical cytochrome P450 from Parthenium argentatum, was crystallized and diffraction data were collected to 2.4 Å resolution. Oxylipins are oxygenated derivatives of fatty acids and pivotal signaling molecules in plants and animals. Allene oxide synthase (AOS) is a key cytochrome P450 CYP74 enzyme involved in the biosynthesis of plant oxylipin jasmonates to convert 13(S)-hydroperoxide to allene oxide. Guayule (Parthenium argentatum) AOS, CYP74A2, was expressed in Escherichia coli. Protein was purified using affinity chromatography and size exclusion chromatography, and then crystallized. Two different crystal forms were obtained from 0.2 M (NH{sub 4})H{sub 2}PO{sub 4}, 50% MPD, 0.1 M Tris, pH 8.5 at 277 K using the hanging-drop vapor-diffusion method. Preliminary X-ray analysis was carried out, and the crystals were found to belong to the tetragonal space group I422 with cell parameters a = b = 126.5, c = 163.9 Å, and the monoclinic space group C2 with cell parameters a = 336.5, b = 184.2, c = 159.0 Å, β = 118.6°. Diffraction data were collected to 2.4 Å resolution from a tetragonal form of crystal using a home X-ray source.

  6. Carbon isotopes from fossil packrat pellets and elevational movements of Utah agave plants reveal the Younger Dryas cold period in Grand Canyon, Arizona

    USGS Publications Warehouse

    Cole, K.L.; Arundel, S.T.

    2005-01-01

    Carbon isotopes in rodent fecal pellets were measured on packrat (Neotoma spp.) middens from the Grand Canyon, Arizona. The pellet samples reflect the abundance of cold-intolerant C4 and Crassulacean acid metabolism (CAM) plant species relative to the predominant C3 vegetation in the packrat diet. The temporal sequence of isotopic results suggests a temperature decline followed by a sharp increase corresponding to the B??lling/Aller??d-Younger Dryas - early Holocene sequence. This pattern was then tested using the past distribution of Utah agave (Agave utahensis). Spatial analyses of the range of this temperature-sensitive CAM species demonstrate that its upper elevational limit is controlled by winter minimum temperature. Applying this paleotemperature proxy to the past elevational limits of Utah agave suggests that minimum winter temperatures were ???8??C below modern values during the Last Glacial Maximum, 4.5-6.5 ??C below modern during the B??lling/Aller??d, and 7.5-8.7 ??C below modern during the early Younger Dryas. As the Younger Dryas terminated, temperatures warmed ???4 ??C between ca. 11.8 ka and 11.5 ka. These extreme fluctuations in winter minimum temperature have not been generally accepted for terrestrial paleoecological records from the arid southwestern United States, likely because of large statistical uncertainties of older radiocarbon results and reliance on proxies for summer temperatures, which were less affected. ?? 2005 Geological Society of America.

  7. Carbon isotopes from fossil packrat pellets and elevational movements of Utah agave plants reveal the Younger Dryas cold period in Grand Canyon, Arizona

    NASA Astrophysics Data System (ADS)

    Cole, Kenneth L.; Arundel, Samantha T.

    2005-09-01

    Carbon isotopes in rodent fecal pellets were measured on packrat (Neotoma spp.) middens from the Grand Canyon, Arizona. The pellet samples reflect the abundance of cold-intolerant C4 and Crassulacean acid metabolism (CAM) plant species relative to the predominant C3 vegetation in the packrat diet. The temporal sequence of isotopic results suggests a temperature decline followed by a sharp increase corresponding to the Bølling/ Allerød Younger Dryas early Holocene sequence. This pattern was then tested using the past distribution of Utah agave (Agave utahensis). Spatial analyses of the range of this temperature-sensitive CAM species demonstrate that its upper elevational limit is controlled by winter minimum temperature. Applying this paleotemperature proxy to the past elevational limits of Utah agave suggests that minimum winter temperatures were ˜8 °C below modern values during the Last Glacial Maximum, 4.5 6.5 °C below modern during the Bølling/Allerød, and 7.5 8.7 °C below modern during the early Younger Dryas. As the Younger Dryas terminated, temperatures warmed ˜4 °C between ca. 11.8 ka and 11.5 ka. These extreme fluctuations in winter minimum temperature have not been generally accepted for terrestrial paleoecological records from the arid southwestern United States, likely because of large statistical uncertainties of older radiocarbon results and reliance on proxies for summer temperatures, which were less affected.

  8. A wheat allene oxide cyclase gene enhances salinity tolerance via jasmonate signaling.

    PubMed

    Zhao, Yang; Dong, Wei; Zhang, Naibo; Ai, Xinghui; Wang, Mengcheng; Huang, Zhigang; Xiao, Langtao; Xia, Guangmin

    2014-02-01

    One of the two branches of the α-linolenic acid metabolism pathway is catalyzed by 12-oxo-phytodienoic acid reductase I, and the other is involved in jasmonic acid (JA) synthesis. The former is known to be active in the response to salinity tolerance in wheat (Triticum aestivum), but the participation of the latter in this response has not been established as yet. Here, the salinity-responsive bread wheat gene TaAOC1, which encodes an allene oxide cyclase involved in the α-linolenic acid metabolism pathway, was constitutively expressed in both bread wheat and Arabidopsis (Arabidopsis thaliana). In both species, transgenic lines exhibited an enhanced level of tolerance to salinity. The transgenic plants accumulated a higher content of JA and developed shorter roots. Both the shortened roots and the salinity tolerance were abolished in a background lacking a functional AtMYC2, a key component of the JA and abscisic acid signaling pathway, but were still expressed in a background deficient with respect to abscisic acid synthesis. We provide the first evidence, to our knowledge, suggesting that JA is also involved in the plant salinity response and that the α-linolenic acid metabolism pathway has a regulatory role over this response. PMID:24326670

  9. Biodesulfurization of fossil fuels.

    PubMed

    Gray, Kevin A; Mrachko, Gregory T; Squires, Charles H

    2003-06-01

    Biotechnological techniques enabling the specific removal of sulfur from fossil fuels have been developed. In the past three years there have been important advances in the elucidation of the mechanisms of biodesulfurization; some of the most significant relate to the role of a flavin reductase, DszD, in the enzymology of desulfurization, and to the use of new tools that enable enzyme enhancement via DNA manipulation to influence both the rate and the substrate range of Dsz. Also, a clearer understanding of the unique desulfinase step in the pathway has begun to emerge.

  10. Cycles in fossil diversity

    SciTech Connect

    Rohde, Robert A.; Muller, Richard A.

    2004-10-20

    It is well-known that the diversity of life appears to fluctuate during the course the Phanerozoic, the eon during which hard shells and skeletons left abundant fossils (0-542 Ma). Using Sepkoski's compendium of the first and last stratigraphic appearances of 36380 marine genera, we report a strong 62 {+-} 3 Myr cycle, which is particularly strong in the shorter-lived genera. The five great extinctions enumerated by Raup and Sepkoski may be an aspect of this cycle. Because of the high statistical significance, we also consider contributing environmental factors and possible causes.

  11. Fossil Microorganisms in Archaean

    NASA Technical Reports Server (NTRS)

    Astafleva, Marina; Hoover, Richard; Rozanov, Alexei; Vrevskiy, A.

    2006-01-01

    Ancient Archean and Proterozoic rocks are the model objects for investigation of rocks comprising astromaterials. The first of Archean fossil microorganisms from Baltic shield have been reported at the last SPIE Conference in 2005. Since this confeence biomorphic structures have been revealed in Archean rocks of Karelia. It was determined that there are 3 types of such bion structures: 1. structures found in situ, in other words microorganisms even-aged with rock matrix, that is real Archean fossils biomorphic structures, that is to say forms inhabited early formed rocks, and 3. younger than Archean-Protherozoic minerali microorganisms, that is later contamination. We made attempt to differentiate these 3 types of findings and tried to understand of burial of microorganisms. The structures belongs (from our point of view) to the first type, or real Archean, forms were under examination. Practical investigation of ancient microorganisms from Green-Stone-Belt of Northern Karelia turns to be very perspective. It shows that even in such ancient time as Archean ancient diverse world existed. Moreover probably such relatively highly organized cyanobacteria and perhaps eukaryotic formes existed in Archean world.

  12. Revealing the Link Between Solar Activity and Satellite Anomalies: Career Recollections From Joe Allen

    NASA Astrophysics Data System (ADS)

    Schultz, Colin

    2012-08-01

    Beginning his career on the heels of the 1957-1958 International Geophysical Year and the dawn of the satellite era, Joe H. Allen entered the service of the U.S. Coast and Geodetic Survey in 1963. Earning a master's of science in engineering from the University of California at Berkeley while working for the Geodetic Survey, Allen advanced within a department that evolved into the National Geophysical Data Center, a branch of NOAA. Allen earned a Department of Commerce award in 1978 and in 1981 became the chief of the Solar and Terrestrial Physics Division of the National Geophysical Data Center, a position from which he retired in 1994.

  13. ABSTRACTS: Seventh annual conference on fossil energy materials

    SciTech Connect

    Not Available

    1993-01-01

    Objective of the Advanced Research and Technology Development materials program is to conduct R and D on materials for fossil energy applications (coal processing, coal liquefaction, gasification, heat engines and recovery, combustion systems, fuel cells). Research is aimed at better understanding of materials in fossil energy environments and development of new materials for improvement of plant operations and reliability. Abstracts are given of 37 papers on ceramics/composites, intermetallics (iron aluminides, etc.), and advanced austenitics. (DLC)

  14. ABSTRACTS: Seventh annual conference on fossil energy materials

    SciTech Connect

    Not Available

    1993-06-01

    Objective of the Advanced Research and Technology Development materials program is to conduct R and D on materials for fossil energy applications (coal processing, coal liquefaction, gasification, heat engines and recovery, combustion systems, fuel cells). Research is aimed at better understanding of materials in fossil energy environments and development of new materials for improvement of plant operations and reliability. Abstracts are given of 37 papers on ceramics/composites, intermetallics (iron aluminides, etc.), and advanced austenitics. (DLC)

  15. The Crystal Structure of Arabidopsis thaliana Allene Oxide Cyclase: Insights into the Oxylipin Cyclization Reaction[W

    PubMed Central

    Hofmann, Eckhard; Zerbe, Philipp; Schaller, Florian

    2006-01-01

    We describe the crystallization and structure elucidation of Arabidopsis thaliana allene oxide cyclase 2 (AOC2), a key enzyme in the biosynthesis of jasmonates. In a coupled reaction with allene oxide synthase, AOC2 releases the first cyclic and biologically active metabolite, 12-oxo-phytodienoic acid (OPDA). AOC2 (AT3G25770) folds into an eight-stranded antiparallel β-barrel with a C-terminal partial helical extension. The protein forms a hydrophobic binding cavity with two distinct polar patches. AOC2 is trimeric in crystals, in vitro and in planta. Based on the observed folding pattern, we assigned AOC2 as a low molecular weight member of the lipocalin family with enzymatic activity in plants. We determined the binding position of the competitive inhibitor vernolic acid (a substrate analog) in the binding pocket. Based on models for bound substrate 12,13-epoxy-9,11,15-octadecatrienoic acid and product OPDA, we propose a reaction scheme that explains the influence of the C15 double bond on reactivity. Reaction is promoted by anchimeric assistance through a conserved Glu residue. The transition state with a pentadienyl carbocation and an oxyanion is stabilized by a strongly bound water molecule and favorable π–π interactions with aromatic residues in the cavity. Stereoselectivity results from steric restrictions to the necessary substrate isomerizations imposed by the protein. PMID:17085685

  16. Plant response to aqueous effluents derived from in-situ fossil-fuel processing. Part I. Eight plant species and their response to Omega 9 oil-shale retort water. [Wildrye; wheatgrass; alkali sacaton; sandreed; pointvetch

    SciTech Connect

    Skinner, Q.D.

    1981-11-01

    Growth response to water collected from an in situ oil shale retort experiment was studied. The purposes were to: (1) evaluate effect of retort water on plants; (2) document effective parameters for detecting differences in plant growth by species. A self feeding hydroponic system was utilized to subject different dilutions of oil shale retort water to plants grown in horticulture grade perlite under greenhouse conditions for 10 weeks. Parameters measured included: (1) leaf area, (2) total dry weight, (3) shoot weight, (4) root weight, (5) root/shoot ratio, and (6) shoot/leaf area ratio. Seven grass and one forb species were utilized as test plants. Results showed growth to be impaired, species to respond differently to retort water, and parameters measured to vary as to their ability to detect change in growth response.

  17. Orion GNC Mitigation Efforts for Van Allen Radiation

    NASA Technical Reports Server (NTRS)

    King, Ellis T.; Jackson, Mark

    2013-01-01

    The Orion Crew Module (CM) is NASA's next generation manned space vehicle, scheduled to return humans to lunar orbit in the coming decade. The Orion avionics and GN&C architectures have progressed through a number of project phases and are nearing completion of a major milestone. The first unmanned test mission, dubbed "Exploration Flight Test One" (EFT-1) is scheduled to launch from NASA Kennedy Space Center late next year and provides the first integrated test of all the vehicle systems, avionics and software. The EFT-1 mission will be an unmanned test flight that includes a high speed re-entry from an elliptical orbit, which will be launched on an expendable launch vehicle (ELV). The ELV will place CM and the ELV upper stage into a low Earth orbit (LEO) for one revolution. After the first LEO, the ELV upper stage will re-ignite and place the combined upper stage/CM into an elliptical orbit whose perigee results in a high energy entry to test CM response in a relatively high velocity, high heating environment. While not producing entry velocities as high as those experienced in returning from a lunar orbit, the trajectory was chosen to provide higher stresses on the thermal protection and guided entry systems, as compared against a lower energy LEO entry. However the required entry geometry with constraints on inclination and landing site result in a trajectory that lingers for many hours in the Van Allen radiation belts. This exposes the vehicle and avionics to much higher levels of high energy proton radiation than a typical LEO or lunar trajectory would encounter. As a result, Van Allen radiation poses a significant risk to the Orion avionics system, and particularly the Flight Control Module (FCM) computers that house the GN&C flight software. The measures taken by the Orion GN&C, Flight Software and Avionics teams to mitigate the risks associated with the Van Allen radiation on EFT-1 are covered in the paper. Background on the Orion avionics subsystem is

  18. Radioactivity in fossils at the Hagerman Fossil Beds National Monument.

    PubMed

    Farmer, C Neal; Kathren, Ronald L; Christensen, Craig

    2008-08-01

    Since 1996, higher than background levels of naturally occurring radioactivity have been documented in both fossil and mineral deposits at Hagerman Fossil Beds National Monument in south-central Idaho. Radioactive fossil sites occur primarily within an elevation zone of 900-1000 m above sea level and are most commonly found associated with ancient river channels filled with sand. Fossils found in clay rich deposits do not exhibit discernable levels of radioactivity. Out of 300 randomly selected fossils, approximately three-fourths exhibit detectable levels of natural radioactivity ranging from 1 to 2 orders of magnitude above ambient background levels when surveyed with a portable hand held Geiger-Muller survey instrument. Mineral deposits in geologic strata also show above ambient background levels of radioactivity. Radiochemical lab analysis has documented the presence of numerous natural radioactive isotopes. It is postulated that ancient groundwater transported radioactive elements through sand bodies containing fossils which precipitated out of solution during the fossilization process. The elevated levels of natural radioactivity in fossils may require special precautions to ensure that exposures to personnel from stored or displayed items are kept as low as reasonably achievable (ALARA).

  19. Branching Out: Rhodium-Catalyzed Allylation with Alkynes and Allenes.

    PubMed

    Koschker, Philipp; Breit, Bernhard

    2016-08-16

    We present a new and efficient strategy for the atom-economic transformation of both alkynes and allenes to allylic functionalized structures via a Rh-catalyzed isomerization/addition reaction which has been developed in our working group. Our methodology thus grants access to an important structural class valued in modern organic chemistry for both its versatility for further functionalization and the potential for asymmetric synthesis with the construction of a new stereogenic center. This new methodology, inspired by mechanistic investigations by Werner in the late 1980s and based on preliminary work by Yamamoto and Trost, offers an attractive alternative to other established methods for allylic functionalization such as allylic substitution or allylic oxidation. The main advantage of our methodology consists of the inherent atom economy in comparison to allylic oxidation or substitution, which both produce stoichiometric amounts of waste and, in case of the substitution reaction, require prefunctionalization of the starting material. Starting out with the discovery of a highly branched-selective coupling reaction of carboxylic acids with terminal alkynes using a Rh(I)/DPEphos complex as the catalyst system, over the past 5 years we were able to continuously expand upon this chemistry, introducing various (pro)nucleophiles for the selective C-O, C-S, C-N, and C-C functionalization of both alkynes and the double-bond isomeric allenes by choosing the appropriate rhodium/bidentate phosphine catalyst. Thus, valuable compounds such as branched allylic ethers, sulfones, amines, or γ,δ-unsaturated ketones were successfully synthesized in high yields and with a broad substrate scope. Beyond the branched selectivity inherent to rhodium, many of the presented methodologies display additional degrees of selectivity in regard to regio-, diastereo-, and enantioselective transformations, with one example even proceeding via a dynamic kinetic resolution. Many advances

  20. Expression of Fusion Proteins of Aspergillus terreus Reveals a Novel Allene Oxide Synthase*

    PubMed Central

    Hoffmann, Inga; Jernerén, Fredrik; Oliw, Ernst H.

    2013-01-01

    Aspergilli oxidize C18 unsaturated fatty acids by dioxygenase-cytochrome P450 fusion proteins to signal molecules involved in reproduction and host-pathogen interactions. Aspergillus terreus expresses linoleate 9R-dioxygenase (9R-DOX) and allene oxide synthase (AOS) activities in membrane fractions. The genome contains five genes (ATEG), which may code for a 9R-DOX-AOS fusion protein. The genes were cloned and expressed, but none of them oxidized 18:2n-6 to 9R-hydroperoxy-10(E),12(Z)-octadecadienoic acid (9R-HPODE). ATEG_02036 transformed 9R-HPODE to an unstable allene oxide, 9(R),10-epoxy-10,12(Z)-octadecadienoic acid. A substitution in the P450 domain (C1073S) abolished AOS activity. The N964V and N964D mutants both showed markedly reduced AOS activity, suggesting that Asn964 may facilitate homolytic cleavage of the dioxygen bond of 9R-HPODE with formation of compound II in analogy with plant AOS (CYP74) and prostacyclin synthase (CYP8A1). ATEG_03992 was identified as 5,8-linoleate diol synthase (5,8-LDS). Replacement of Asn878 in 5,8-LDS with leucine (N878L) mainly shifted ferryl oxygen insertion from C-5 toward C-6, but replacements of Gln881 markedly affected catalysis. The Q881L mutant virtually abolished the diol synthase activity. Replacement of Gln881 with Asn, Glu, Asp, or Lys residues augmented the homolytic cleavage of 8R-HPODE with formation of 10-hydroxy-8(9)-epoxy-12(Z)-octadecenoic acid (erythro/threo, 1–4:1) and/or shifted ferryl oxygen insertion from C-5 toward C-11. We conclude that homolysis and heterolysis of the dioxygen bond with formation of compound II in AOS and compound I in 5,8-LDS are influenced by Asn and Gln residues, respectively, of the I-helices. AOS of A. terreus appears to have evolved independently of CYP74 but with an analogous reaction mechanism. PMID:23479731

  1. Activity Regulation by Heteromerization of Arabidopsis Allene Oxide Cyclase Family Members

    PubMed Central

    Otto, Markus; Naumann, Christin; Brandt, Wolfgang; Wasternack, Claus; Hause, Bettina

    2016-01-01

    Jasmonates (JAs) are lipid-derived signals in plant stress responses and development. A crucial step in JA biosynthesis is catalyzed by allene oxide cyclase (AOC). Four genes encoding functional AOCs (AOC1, AOC2, AOC3 and AOC4) have been characterized for Arabidopsis thaliana in terms of organ- and tissue-specific expression, mutant phenotypes, promoter activities and initial in vivo protein interaction studies suggesting functional redundancy and diversification, including first hints at enzyme activity control by protein-protein interaction. Here, these analyses were extended by detailed analysis of recombinant proteins produced in Escherichia coli. Treatment of purified AOC2 with SDS at different temperatures, chemical cross-linking experiments and protein structure analysis by molecular modelling approaches were performed. Several salt bridges between monomers and a hydrophobic core within the AOC2 trimer were identified and functionally proven by site-directed mutagenesis. The data obtained showed that AOC2 acts as a trimer. Finally, AOC activity was determined in heteromers formed by pairwise combinations of the four AOC isoforms. The highest activities were found for heteromers containing AOC4 + AOC1 and AOC4 + AOC2, respectively. All data are in line with an enzyme activity control of all four AOCs by heteromerization, thereby supporting a putative fine-tuning in JA formation by various regulatory principles. PMID:27135223

  2. Activity Regulation by Heteromerization of Arabidopsis Allene Oxide Cyclase Family Members.

    PubMed

    Otto, Markus; Naumann, Christin; Brandt, Wolfgang; Wasternack, Claus; Hause, Bettina

    2016-01-01

    Jasmonates (JAs) are lipid-derived signals in plant stress responses and development. A crucial step in JA biosynthesis is catalyzed by allene oxide cyclase (AOC). Four genes encoding functional AOCs (AOC1, AOC2, AOC3 and AOC4) have been characterized for Arabidopsis thaliana in terms of organ- and tissue-specific expression, mutant phenotypes, promoter activities and initial in vivo protein interaction studies suggesting functional redundancy and diversification, including first hints at enzyme activity control by protein-protein interaction. Here, these analyses were extended by detailed analysis of recombinant proteins produced in Escherichia coli. Treatment of purified AOC2 with SDS at different temperatures, chemical cross-linking experiments and protein structure analysis by molecular modelling approaches were performed. Several salt bridges between monomers and a hydrophobic core within the AOC2 trimer were identified and functionally proven by site-directed mutagenesis. The data obtained showed that AOC2 acts as a trimer. Finally, AOC activity was determined in heteromers formed by pairwise combinations of the four AOC isoforms. The highest activities were found for heteromers containing AOC4 + AOC1 and AOC4 + AOC2, respectively. All data are in line with an enzyme activity control of all four AOCs by heteromerization, thereby supporting a putative fine-tuning in JA formation by various regulatory principles. PMID:27135223

  3. Iron‐catalyzed Cross‐Coupling of Propargyl Carboxylates and Grignard Reagents: Synthesis of Substituted Allenes

    PubMed Central

    Kessler, Simon N.

    2016-01-01

    Abstract Presented herein is a mild, facile, and efficient iron‐catalyzed synthesis of substituted allenes from propargyl carboxylates and Grignard reagents. Only 1–5 mol % of the inexpensive and environmentally benign [Fe(acac)3] at −20 °C was sufficient to afford a broad range of substituted allenes in excellent yields. The method tolerates a variety of functional groups. PMID:26890161

  4. Copper-catalyzed regio- and stereoselective intermolecular three-component oxyarylation of allenes.

    PubMed

    Itoh, Taisuke; Shimizu, Yohei; Kanai, Motomu

    2014-05-16

    A copper(II)-catalyzed intermolecular three-component oxyarylation of allenes using arylboronic acids as a carbon source and TEMPO as an oxygen source is described. The reaction proceeded under mild conditions with high regio- and stereoselectivity and functional group tolerance. A plausible reaction mechanism is proposed, involving carbocupration of allenes, homolysis of the intervening allylcopper(II), and a radical TEMPO trap. PMID:24766635

  5. Diastereoselective Synthesis of the Aminocyclitol Core of Jogyamycin via an Allene Aziridination Strategy

    PubMed Central

    Gerstner, Nels C.; Adams, Christopher S.; Grigg, R. David; Tretbar, Maik; Rigoli, Jared W.; Schomaker, Jennifer M.

    2016-01-01

    Oxidative allene amination provides rapid access to densely functionalized amine-containing stereotriads through highly reactive bicyclic methyleneaziridine intermediates. This strategy has been demonstrated as a viable approach for the construction of the densely functionalized aminocyclitol core of jogyamycin, a natural product with potent antiprotozoal activity. Importantly, the flexibility of oxidative allene amination will enable the syntheses of modified aminocyclitol analogues of the jogyamycin core. PMID:26741730

  6. Probable identity of Goltz syndrome and Van Allen-Myhre syndrome: evidence from phenotypic evolution.

    PubMed

    Hancock, Susan; Pryde, Peter; Fong, Christine; Brazy, Jane E; Stewart, Katharina; Favour, Amy; Pauli, Richard M

    2002-07-15

    We describe a girl who was diagnosed with split foot-split hand anomaly prenatally, in whom at birth the diagnosis of Van Allen-Myhre syndrome was made, and who at 8 months of age was recognized to have Goltz syndrome. Based on the evolution of clinical features in this infant, we suggest that our case, as well as that reported by Van Allen and Myhre, is an example of unusually severe Goltz syndrome.

  7. STS-46 Pilot Allen uses cycle ergometer on OV-104's middeck

    NASA Technical Reports Server (NTRS)

    1992-01-01

    STS-46 Pilot Andrew M. Allen exercises using the cycle ergometer on the middeck of Atlantis, Orbiter Vehicle (OV) 104. Allen, shirtless, is equipped with sensors for monitoring his biological systems during the exercise session. A communications kit assembly cable freefloats from his headset at his right and in front of the forward lockers. The open airlock hatch appears at his left and the sleep station behind him.

  8. Stereoselective nickel-catalyzed [2+2] cycloadditions of ene-allenes.

    PubMed

    Noucti, Njamkou N; Alexanian, Erik J

    2015-04-27

    A stereoselective nickel-catalyzed [2+2] cycloaddition of ene-allenes is reported. This transformation encompasses a broad range of ene-allene substrates, thus providing efficient access to fused cyclobutanes from easily accessed π-components. A simple and inexpensive first-row catalytic system comprised of [Ni(cod)2 ] and dppf was used in this process, thus constituting an attractive approach to synthetically challenging cyclobutane frameworks under mild reaction conditions.

  9. THE ALLEN TELESCOPE ARRAY SEARCH FOR ELECTROSTATIC DISCHARGES ON MARS

    SciTech Connect

    Anderson, Marin M.; Siemion, Andrew P. V.; Bower, Geoffrey C.; De Pater, Imke; Barott, William C.; Delory, Gregory T.; Werthimer, Dan

    2012-01-01

    The Allen Telescope Array was used to monitor Mars between 2010 March 9 and June 2, over a total of approximately 30 hr, for radio emission indicative of electrostatic discharge. The search was motivated by the report from Ruf et al. of the detection of non-thermal microwave radiation from Mars characterized by peaks in the power spectrum of the kurtosis, or kurtstrum, at 10 Hz, coinciding with a large dust storm event on 2006 June 8. For these observations, we developed a wideband signal processor at the Center for Astronomy Signal Processing and Electronics Research. This 1024 channel spectrometer calculates the accumulated power and power-squared, from which the spectral kurtosis is calculated post-observation. Variations in the kurtosis are indicative of non-Gaussianity in the signal, which can be used to detect variable cosmic signals as well as radio frequency interference (RFI). During the three-month period of observations, dust activity occurred on Mars in the form of small-scale dust storms; however, no signals indicating lightning discharge were detected. Frequent signals in the kurtstrum that contain spectral peaks with an approximate 10 Hz fundamental were seen at both 3.2 and 8.0 GHz, but were the result of narrowband RFI with harmonics spread over a broad frequency range.

  10. The Allen Telescope Array as Square Kilometer Array Pathfinder

    NASA Astrophysics Data System (ADS)

    Bower, Geoffrey C.

    2007-12-01

    The Allen Telescope Array (ATA) is a new radio interferometer that has begun scientific operations in 2007. Many of the technologies, techniques, and observing modes developed for the ATA are directly applicable to the Square Kilometer Array (SKA). The ATA is a pioneer of the LNSD, which refers to a large number (LN) of small diameter (SD) dishes to create the array. This concept underlies nearly all SKA designs. Other relevant technologies are the offset Gregorian ATA antenna, the ATA wideband log periodic feed, transport of broadband data over fiber optic cables, and flexible digital signal processing electronics. The small dishes of the ATA gives it extraordinary wide-field imaging and survey capability but also require new solutions for calibration and imaging. Real time imaging, rapid response to transients, and thinking telescope technology are also under development. Finally, the ATA is developing commensal observing modes, which enable multiple simultaneous science programs, such as SETI, transient surveys, and HI surveys. Opportunities exist for community members to perform scientific investigations as well as develop techniques and technology for the SKA through use of the ATA.

  11. The Benton-Van Allen faces: a lateralized tachistoscopic study.

    PubMed

    Püschel, J; Zaidel, E

    1994-03-01

    The Benton-Van Allen Facial Recognition Test (FRT) was adapted to a lateralized same-different task. The lateralized same targets were either physically identical to the central upright faces or had the same face identity but were transformed (3/4-views or shadowed faces). Faces were also modified to include or exclude external features. There was a left hemifield (right hemisphere) advantage only for the most difficult, shadowed faces. The absence of a left hemifield advantage for the matching of upright faces to identical or 3/4-view faces shows bilateral competence for face processing, both by physical and by face identity, and confirms previous observations that the FRT does not discriminate left from right hemisphere-damaged patients. Removal of external features affected performance in the right but not the left visual field, suggesting that the left hemisphere uses a less feature-dependent mechanism than the right hemisphere. This effect was only present in females, who were more lateralized than males.

  12. Wave acceleration of electrons in the Van Allen radiation belts.

    PubMed

    Horne, Richard B; Thorne, Richard M; Shprits, Yuri Y; Meredith, Nigel P; Glauert, Sarah A; Smith, Andy J; Kanekal, Shrikanth G; Baker, Daniel N; Engebretson, Mark J; Posch, Jennifer L; Spasojevic, Maria; Inan, Umran S; Pickett, Jolene S; Decreau, Pierrette M E

    2005-09-01

    The Van Allen radiation belts are two regions encircling the Earth in which energetic charged particles are trapped inside the Earth's magnetic field. Their properties vary according to solar activity and they represent a hazard to satellites and humans in space. An important challenge has been to explain how the charged particles within these belts are accelerated to very high energies of several million electron volts. Here we show, on the basis of the analysis of a rare event where the outer radiation belt was depleted and then re-formed closer to the Earth, that the long established theory of acceleration by radial diffusion is inadequate; the electrons are accelerated more effectively by electromagnetic waves at frequencies of a few kilohertz. Wave acceleration can increase the electron flux by more than three orders of magnitude over the observed timescale of one to two days, more than sufficient to explain the new radiation belt. Wave acceleration could also be important for Jupiter, Saturn and other astrophysical objects with magnetic fields.

  13. Geographical variation in bill size across bird species provides evidence for Allen's rule.

    PubMed

    Symonds, Matthew R E; Tattersall, Glenn J

    2010-08-01

    Allen's rule proposes that the appendages of endotherms are smaller, relative to body size, in colder climates, in order to reduce heat loss. Empirical support for Allen's rule is mainly derived from occasional reports of geographical clines in extremity size of individual species. Interspecific evidence is restricted to two studies of leg proportions in seabirds and shorebirds. We used phylogenetic comparative analyses of 214 bird species to examine whether bird bills, significant sites of heat exchange, conform to Allen's rule. The species comprised eight diverse taxonomic groups-toucans, African barbets, Australian parrots, estrildid finches, Canadian galliforms, penguins, gulls, and terns. Across all species, there were strongly significant relationships between bill length and both latitude and environmental temperature, with species in colder climates having significantly shorter bills. Patterns supporting Allen's rule in relation to latitudinal or altitudinal distribution held within all groups except the finches. Evidence for a direct association with temperature was found within four groups (parrots, galliforms, penguins, and gulls). Support for Allen's rule in leg elements was weaker, suggesting that bird bills may be more susceptible to thermoregulatory constraints generally. Our results provide the strongest comparative support yet published for Allen's rule and demonstrate that thermoregulation has been an important factor in shaping the evolution of bird bills. PMID:20545560

  14. Geographical variation in bill size across bird species provides evidence for Allen's rule.

    PubMed

    Symonds, Matthew R E; Tattersall, Glenn J

    2010-08-01

    Allen's rule proposes that the appendages of endotherms are smaller, relative to body size, in colder climates, in order to reduce heat loss. Empirical support for Allen's rule is mainly derived from occasional reports of geographical clines in extremity size of individual species. Interspecific evidence is restricted to two studies of leg proportions in seabirds and shorebirds. We used phylogenetic comparative analyses of 214 bird species to examine whether bird bills, significant sites of heat exchange, conform to Allen's rule. The species comprised eight diverse taxonomic groups-toucans, African barbets, Australian parrots, estrildid finches, Canadian galliforms, penguins, gulls, and terns. Across all species, there were strongly significant relationships between bill length and both latitude and environmental temperature, with species in colder climates having significantly shorter bills. Patterns supporting Allen's rule in relation to latitudinal or altitudinal distribution held within all groups except the finches. Evidence for a direct association with temperature was found within four groups (parrots, galliforms, penguins, and gulls). Support for Allen's rule in leg elements was weaker, suggesting that bird bills may be more susceptible to thermoregulatory constraints generally. Our results provide the strongest comparative support yet published for Allen's rule and demonstrate that thermoregulation has been an important factor in shaping the evolution of bird bills.

  15. Organic molecules as chemical fossils - The molecular fossil record

    NASA Technical Reports Server (NTRS)

    Eglinton, G.

    1983-01-01

    The study of biochemical clues to the early earth and the origin of life is discussed. The methods used in such investigation are described, including the extraction, fractionation, and analysis of geolipids and the analysis of kerogen. The occurrence of molecular fossils in the geological record is examined, discussing proposed precursor-product relationships and the molecular assessment of deep sea sediments, ancient sediments, and crude petroleums. Alterations in the molecular record due to diagenesis and catagenesis are considered, and the use of microbial lipids as molecular fossils is discussed. The results of searches for molecular fossils in Precambrian sediments are assessed.

  16. Fossil Leaves and Fossil Leaf n-Alkanes: Reconstructing the First Closed Canopied Rainforests

    NASA Astrophysics Data System (ADS)

    Graham, H. V.; Freeman, K. H.

    2013-12-01

    Although the age and location is disputed, the rise of the first closed-canopy forest is likely linked with the expansion of angiosperms in the late Cretacous or early Cenozoic. The carbon isotope 'canopy effect' reflects the extent of canopy closure, and is well documented in δ13C values of the leaves and leaf lipids in modern forests. To test the extent of canopy closure among the oldest documented angiosperm tropical forests, we analyzed isotopic characteristics of leaf fossils and leaf waxes from the Guaduas and Cerrejón Formations. The Guaduas Fm. (Maastrichtian) contains some of the earliest angiosperm fossils in the Neotropics, and both leaf morphology and pollen records at this site suggest an open-canopy structure. The Cerrejón Fm. (Paleocene) contains what are believed to be the first recorded fossil leaves from a closed-canopy forest. We analyzed the bulk carbon isotope content (δ13Cleaf) of 199 fossil leaves, as well as the n-alkane concentration and chain-length distribution, and δ13C of alkanes (δ13Clipid) of 73 fossil leaves and adjacent sediment samples. Fossil leaves are dominated by eudicots and include ten modern plant families (Apocynaceae, Bombaceae, Euphorbaceae, Fabaceae, Lauraceae, Malvaceae, Meliaceae, Menispermaceae, Moraceae, Sapotaceae). We interpreted extent of canopy coverage based on the range of δ13Cleaf values. The narrow range of δ13C values in leaves from the Guaduas Fm (2.7‰) is consistent with an open canopy. A significantly wider range in values (6.3‰) suggests a closed-canopy signature for site 0315 of the Cerrejón Fm,. In contrast, at Site 0318, a lacustrine deposit, leaves had a narrow range (3.3‰) in δ13C values, and this is not consistent with a closed-canopy, but is consistent with leaf assemblages from a forest edge. Leaves that accumulate in lake sediments tend to be biased toward plants living at the lake edge, which do not experience closed-canopy conditions, and do not express the isotopic

  17. Chiral nonracemic alpha-alkylidene and alpha-silylidene cyclopentenones from chiral allenes using an intramolecular allenic Pauson-Khand-type cycloaddition.

    PubMed

    Brummond, Kay M; Kerekes, Angela D; Wan, Honghe

    2002-07-26

    We have successfully effected a transfer of chirality from a chiral nonracemic allene to an alpha-alkylidene and an alpha-silylidene cyclopentenone. The molybdenum-mediated examples possessing a silyl group on the terminus of the allene show good facial selectivities, but isomerization of the (E)-silylidene cyclopentenone to the (Z)-silylidene cyclopentenone occurs upon purification of these products. Alternatively, an alkyl group on the terminus of the allene undergoes cycloaddition with moderate selectivities but gives products that undergo an isomerization of the (Z)-alkylidene cyclopentenone to the (E)-alkylidene cyclopentenone when exposed to acidic conditions. Thus, erosion of the enantiomeric excesses is observed for one of the two products as a result of this isomerization. The allenic Pauson-Khand-type cycloaddition has also been effected by first isolation the (eta(6)-arene)molybdenum tricarbonyl complex, demonstrating for the first time that this is most likely the active complex in the molybdenum-mediated reactions. Attempts to increase the facial selectivity by increasing the size of the arene moiety resulted in a marginal increase in the selectivity at the expense of the yield. Based upon these results, we have concluded that altering the approach for the preparation of nonracemic alpha-alkylidene cyclopentenones is necessary in order to obtain synthetically useful levels of stereocontrol.

  18. FOSSIL2 energy policy model documentation: FOSSIL2 documentation

    SciTech Connect

    1980-10-01

    This report discusses the structure, derivations, assumptions, and mathematical formulation of the FOSSIL2 model. Each major facet of the model - supply/demand interactions, industry financing, and production - has been designed to parallel closely the actual cause/effect relationships determining the behavior of the United States energy system. The data base for the FOSSIL2 program is large, as is appropriate for a system dynamics simulation model. When possible, all data were obtained from sources well known to experts in the energy field. Cost and resource estimates are based on DOE data whenever possible. This report presents the FOSSIL2 model at several levels. Volumes II and III of this report list the equations that comprise the FOSSIL2 model, along with variable definitions and a cross-reference list of the model variables. Volume III lists the model equations and a one line definition for equations, in a short, readable format.

  19. Fossil Energy Advanced Research and Technology Development (AR&TD) Materials Program semiannual progress report for the period ending September 30, 1991. Fossil Energy Program

    SciTech Connect

    Judkins, R.R.; Cole, N.C.

    1992-04-01

    The objective of the Fossil Energy Advanced Research and Technology Development Materials Program is to conduct research and development on materials for fossil energy applications with a focus on the longer-term and generic needs of the various fossil fuel technologies. The Program includes research aimed toward a better understanding of materials behavior in fossil energy environments and the development of new materials capable of substantial enhancement of plant operations and reliability. Research is outlined in four areas: Ceramics, New Alloys, Corrosion and Erosion Research, and Technology Development and Transfer. (VC)

  20. Fossilized bioelectric wire – the trace fossil Trichichnus

    PubMed Central

    Kędzierski, M.; Uchman, A.; Sawlowicz, Z.; Briguglio, A.

    2015-01-01

    The trace fossil Trichichnus is proposed as an indicator of fossil bioelectric bacterial activity at the oxic–anoxic interface zone of marine sediments. This fulfils the idea that such processes, commonly found in the modern realm, should be also present in the geological past. Trichichnus is an exceptional trace fossil due to its very thin diameter (mostly less than 1 mm) and common pyritic filling. It is ubiquitous in some fine-grained sediments, where it has been interpreted as a burrow formed deeper than any other trace fossils, below the redox boundary. Trichichnus, formerly referred to as deeply burrowed invertebrates, has been found as remnant of a fossilized intrasediment bacterial mat that is pyritized. As visualized in 3-D by means of X-ray computed microtomography scanner, Trichichnus forms dense filamentous fabric, which reflects that it is produced by modern large, mat-forming, sulfide-oxidizing bacteria, belonging mostly to Thioploca-related taxa, which are able to house a complex bacterial consortium. Several stages of Trichichnus formation, including filamentous, bacterial mat and its pyritization, are proposed to explain an electron exchange between oxic and suboxic/anoxic layers in the sediment. Therefore, Trichichnus can be considered a fossilized “electric wire”. PMID:26290671

  1. Rhodium-catalyzed dynamic kinetic asymmetric transformations of racemic allenes by the [3+2] annulation of aryl ketimines.

    PubMed

    Tran, Duc N; Cramer, Nicolai

    2013-09-27

    Racemization required: Rhodium(I)-catalyzed C-H activation directed by unprotected ketimines initiates selective [3+2] cycloaddition with allenes, providing access to highly substituted indenylamines. The reaction proceeds through the dynamic kinetic asymmetric transformation of racemic allenes. The catalyst controls the enantio- and diastereoselectivity, the regioselectivities of the C-H activation and allene incorporation, as well as the E/Z ratio.

  2. Dating Fossil Pollen: A Simulation.

    ERIC Educational Resources Information Center

    Sheridan, Philip

    1992-01-01

    Describes a hands-on simulation in which students determine the age of "fossil" pollen samples based on the pollen types present when examined microscopically. Provides instructions for the preparation of pollen slides. (MDH)

  3. The legacy of fossil fuels.

    PubMed

    Armaroli, Nicola; Balzani, Vincenzo

    2011-03-01

    Currently, over 80% of the energy used by mankind comes from fossil fuels. Harnessing coal, oil and gas, the energy resources contained in the store of our spaceship, Earth, has prompted a dramatic expansion in energy use and a substantial improvement in the quality of life of billions of individuals in some regions of the world. Powering our civilization with fossil fuels has been very convenient, but now we know that it entails severe consequences. We treat fossil fuels as a resource that anyone anywhere can extract and use in any fashion, and Earth's atmosphere, soil and oceans as a dump for their waste products, including more than 30 Gt/y of carbon dioxide. At present, environmental legacy rather than consistence of exploitable reserves, is the most dramatic problem posed by the relentless increase of fossil fuel global demand. Harmful effects on the environment and human health, usually not incorporated into the pricing of fossil fuels, include immediate and short-term impacts related to their discovery, extraction, transportation, distribution, and burning as well as climate change that are spread over time to future generations or over space to the entire planet. In this essay, several aspects of the fossil fuel legacy are discussed, such as alteration of the carbon cycle, carbon dioxide rise and its measurement, greenhouse effect, anthropogenic climate change, air pollution and human health, geoengineering proposals, land and water degradation, economic problems, indirect effects on the society, and the urgent need of regulatory efforts and related actions to promote a gradual transition out of the fossil fuel era. While manufacturing sustainable solar fuels appears to be a longer-time perspective, alternatives energy sources already exist that have the potential to replace fossil fuels as feedstocks for electricity production.

  4. Allen Brain Atlas: an integrated spatio-temporal portal for exploring the central nervous system.

    PubMed

    Sunkin, Susan M; Ng, Lydia; Lau, Chris; Dolbeare, Tim; Gilbert, Terri L; Thompson, Carol L; Hawrylycz, Michael; Dang, Chinh

    2013-01-01

    The Allen Brain Atlas (http://www.brain-map.org) provides a unique online public resource integrating extensive gene expression data, connectivity data and neuroanatomical information with powerful search and viewing tools for the adult and developing brain in mouse, human and non-human primate. Here, we review the resources available at the Allen Brain Atlas, describing each product and data type [such as in situ hybridization (ISH) and supporting histology, microarray, RNA sequencing, reference atlases, projection mapping and magnetic resonance imaging]. In addition, standardized and unique features in the web applications are described that enable users to search and mine the various data sets. Features include both simple and sophisticated methods for gene searches, colorimetric and fluorescent ISH image viewers, graphical displays of ISH, microarray and RNA sequencing data, Brain Explorer software for 3D navigation of anatomy and gene expression, and an interactive reference atlas viewer. In addition, cross data set searches enable users to query multiple Allen Brain Atlas data sets simultaneously. All of the Allen Brain Atlas resources can be accessed through the Allen Brain Atlas data portal.

  5. Computational Research Challenges and Opportunities for the Optimization of Fossil Energy Power Generation System

    SciTech Connect

    Zitney, S.E.

    2007-06-01

    Emerging fossil energy power generation systems must operate with unprecedented efficiency and near-zero emissions, while optimizing profitably amid cost fluctuations for raw materials, finished products, and energy. To help address these challenges, the fossil energy industry will have to rely increasingly on the use advanced computational tools for modeling and simulating complex process systems. In this paper, we present the computational research challenges and opportunities for the optimization of fossil energy power generation systems across the plant lifecycle from process synthesis and design to plant operations. We also look beyond the plant gates to discuss research challenges and opportunities for enterprise-wide optimization, including planning, scheduling, and supply chain technologies.

  6. Lipoxygenase-allene oxide synthase pathway in octocoral thermal stress response

    NASA Astrophysics Data System (ADS)

    Lõhelaid, H.; Teder, T.; Samel, N.

    2015-03-01

    Marine ecosystems are sensitive to elevated seawater temperature, with stony corals serving as model organisms for temperature-imposed declines in population viability and diversity. Several stress markers, including heat shock proteins, have been used for the detection and prediction of stress responses in stony corals. However, the stress indicators in soft corals remain elusive. In higher animals and plants, oxylipins synthesized by fatty acid di- and monooxygenases contribute to stress-induced signaling; however, the role of eicosanoid pathways in corals remains unclear. The eicosanoid gene specific to corals encodes for a natural fusion protein of allene oxide synthase and lipoxygenase ( AOS- LOX). In this work, using the easily cultivated soft coral Capnella imbricata as the stress response model, we monitored the expression of the AOS-LOX and the formation of arachidonic acid metabolites in response to an acute rise in water temperature. Gene expression profiles of two 70 kDa heat shock proteins ( Hsps: Hsp70 and Grp78) were used as a positive control for the stress response. In comparison with normal seawater temperature (23 °C), AOS- LOXa and Hsps were all up-regulated after modest (28 °C) and severe (31 °C) temperature elevation. While the up-regulation of AOS- LOXa and Grp78 was more sensitive to moderate temperature changes, Hsp70s were more responsive to severe heat shock. Concurrently, endogenous and exogenous AOS-LOXa-derived eicosanoids were up-regulated. Thus, together with the up-regulation of AOS- LOX by other abiotic and biotic stress stimuli, these data implicate AOS-LOX as part of the general stress response pathway in corals.

  7. VIEW OF IRVING FLUME FROM FOSSIL SPRINGS (LINE THROUGH CENTER ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    VIEW OF IRVING FLUME FROM FOSSIL SPRINGS (LINE THROUGH CENTER OF PHOTO) AND LOCATION OF IRVING POWER PLANT (LEFT CENTER) FROM FOREST SERVICE (FS) ROAD #708 (STRAWBERRY TO IRVING). LOOKING DOWNSTREAM (SOUTH-SOUTHWEST) - Childs-Irving Hydroelectric Project, Forest Service Road 708/502, Camp Verde, Yavapai County, AZ

  8. Space Weather data processing and Science Gateway for the Van Allen Probes

    NASA Astrophysics Data System (ADS)

    Romeo, G.; Barnes, R. J.; Weiss, M.; Fox, N. J.; Mauk, B.; Potter, M.; Kessel, R.

    2013-12-01

    A near real-time data processing pipeline for the Space Weather broadcast data from the Van Allen Probes is presented. The Van Allen Probes broadcasts a sub-set of the science data in real-time when not downlinking the principal science data. This broadcast is received by several ground stations and relayed to APL in near real time to be ingested into the space weather processing pipeline. This pipeline processes the available level zero space weather data into higher level science data products. These products are made available to the public via the Van Allen Probes Science Gateway website (http://athena.jhuapl.edu). The website acts as pivotal point though which all other instrument SOC's can be accessed. Several other data products (e.g KP/DST indices) and tools (e.g orbit calculator) are made also available to the general public.

  9. Conjugate observations of quasiperiodic emissions by the Cluster, Van Allen Probes, and THEMIS spacecraft

    NASA Astrophysics Data System (ADS)

    Němec, F.; Hospodarsky, G.; Pickett, J. S.; Santolík, O.; Kurth, W. S.; Kletzing, C.

    2016-08-01

    We present results of a detailed analysis of two electromagnetic wave events observed in the inner magnetosphere at frequencies of a few kilohertz, which exhibit a quasiperiodic (QP) time modulation of the wave intensity. The events were observed by the Cluster and Van Allen Probes spacecraft and in one event also by the THEMIS E spacecraft. The spacecraft were significantly separated in magnetic local time, demonstrating a huge azimuthal extent of the events. Geomagnetic conditions at the times of the observations were very quiet, and the events occurred inside the plasmasphere. The modulation period observed by the Van Allen Probes and THEMIS E spacecraft (duskside) was in both events about twice larger than the modulation period observed by the Cluster spacecraft (dawnside). Moreover, individual QP elements occur about 15 s earlier on THEMIS E than on Van Allen Probes, which might be related to a finite propagation speed of a modulating ULF wave.

  10. A C–H bond activation-based catalytic approach to tetrasubstituted chiral allenes

    PubMed Central

    Wu, Shangze; Huang, Xin; Wu, Wangteng; Li, Pengbin; Fu, Chunling; Ma, Shengming

    2015-01-01

    Enantioselective synthesis of fully substituted allenes has been a challenge due to the non-rigid nature of the axial chirality, which spreads over three carbon atoms. Here we show the commercially available simple Rh complex may catalyse the CMD (concerted metalation/deprotonation)-based reaction of the readily available arenes with sterically congested tertiary propargylic carbonates at ambient temperature affording fully substituted allenes. It is confirmed that the excellent designed regioselectivity for the C–C triple bond insertion is induced by the coordination of the carbonyl group in the directing carbonate group as well as the steric effect of the tertiary O-linked carbon atom. When an optically active carbonate was used, surprisingly high efficiency of chirality transfer was realized, affording fully substituted allenes in excellent enantiomeric excess (ee). PMID:26246391

  11. Spacecraft-level verification of the Van Allen Probes' RF communication system

    NASA Astrophysics Data System (ADS)

    Crowne, M. J.; Srinivasan, D.; Royster, D.; Weaver, G.; Matlin, D.; Mosavi, N.

    This paper presents the verification process, lessons learned, and selected test results of the radio frequency (RF) communication system of the Van Allen Probes, formerly known as the Radiation Belt Storm Probes (RBSP). The Van Allen Probes mission is investigating the doughnut-shaped regions of space known as the Van Allen radiation belts where the Sun interacts with charged particles trapped in Earth's magnetic field. Understanding this dynamic area that surrounds our planet is important to improving our ability to design spacecraft and missions for reliability and astronaut safety. The Van Allen Probes mission features two nearly identical spacecraft designed, built, and operated by the Johns Hopkins University Applied Physics Laboratory (JHU/APL) for the National Aeronautics and Space Administration (NASA). The RF communication system features the JHU/APL Frontier Radio. The Frontier Radio is a software-defined radio (SDR) designed for spaceborne communications, navigation, radio science, and sensor applications. This mission marks the first spaceflight usage of the Frontier Radio. RF ground support equipment (RF GSE) was developed using a ground station receiver similar to what will be used in flight and whose capabilities provided clarity into RF system performance that was previously not obtained until compatibility testing with the ground segments. The Van Allen Probes underwent EMC, acoustic, vibration, and thermal vacuum testing at the environmental test facilities at APL. During this time the RF communication system was rigorously tested to ensure optimal performance, including system-level testing down to threshold power levels. Compatibility tests were performed with the JHU/APL Satellite Communication Facility (SCF), the Universal Space Network (USN), and the Tracking and Data Relay Satellite System (TDRSS). Successful completion of this program as described in this paper validated the design of the system and demonstrated that it will be able to me

  12. A Century after Van Allen's Birth: Conclusion of Reconnaissance of Radiation Belts in the Solar System

    NASA Astrophysics Data System (ADS)

    Krimigis, S. M.

    2014-12-01

    On May 1, 1958 in the Great Hall of the US National Academy of Sciences, James A. Van Allen, having instrumented Explorer-1 and follow-on satellites with radiation detectors, announced the discovery of intense radiation at high altitudes above Earth. The press dubbed the doughnut-shaped structures "Van Allen Belts" (VAB). Soon thereafter, the search began for VAB at nearby planets. Mariner 2 flew by Venus in 1962 at a distance of 41,000 km, but no radiation was detected. The Mariner 4 mission to Mars did not observe planet-associated increase in radiation, but scaling arguments with Earth's magnetosphere yielded an upper limit to the ratio of magnetic moments of MM/ME < 0.001 (Van Allen et al, 1965). Similarly, the Mariner 5 flyby closer to Venus resulted in a ratio of magnetic moments < 0.001 (Van Allen et al, 1967), dealing a blow to the expectation that all planetary bodies must possess significant VAB. The flyby of Mercury in 1974 by Mariner 10 revealed a weak magnetic field, but the presence of durably trapped higher energy particles remained controversial until MESSENGER in 2011.The first flybys of Jupiter by Pioneers 10, 11 in 1973 and 1974, respectively, measured a plethora of energetic particles in Jupiter's magnetosphere and established the fact that their intensities were rotationally modulated. Later flybys of Jupiter and Saturn by the two Voyagers in 1979 and 1981 revealed that those magnetospheres possessed their own internal plasma source(s) and radiation belts. Subsequent discoveries of Van Allen belts at Uranus and Neptune by Voyager 2 demonstrated that VAB are the rule rather than the exception in planetary environments. We now know from the Voyagers and through Energetic Neutral Atom images from Cassini and IBEX that an immense energetic particle population surrounds the heliosphere itself. Thus, the reconnaissance of radiation belts of our solar system has been completed, some 56 years after the discovery of the Van Allen Belts at Earth.

  13. Regiodivergent Intermolecular [3+2] Cycloadditions of Vinyl Aziridines and Allenes: Stereospecific Synthesis of Chiral Pyrrolidines.

    PubMed

    Lin, Tao-Yan; Zhu, Chao-Ze; Zhang, Peichao; Wang, Yidong; Wu, Hai-Hong; Feng, Jian-Jun; Zhang, Junliang

    2016-08-26

    The first rhodium-catalyzed intermolecular [3+2] cycloaddition reaction of vinyl aziridines and allenes for the synthesis of enantioenriched functionalized pyrrolidines was realized. [3+2] cycloaddition with the proximal C=C bond of N-allenamides gave 3-methylene-pyrrolidines in high regio- and diastereoselectivity, whereas, 2-methylene-pyrrolidines were obtained as the major products by the cycloadditions of vinyl aziridines with the distal C=C bond of allenes. Use of readily available starting materials, a broad substrate scope, high selectivity, mild reaction conditions, as well as versatile functionalization of the cycloadducts make this approach very practical and attractive. PMID:27485044

  14. Experiments in no-impact control of dingoes: comment on Allen et al. 2013.

    PubMed

    Johnson, Christopher N; Crowther, Mathew S; Dickman, Chris R; Letnic, Michael I; Newsome, Thomas M; Nimmo, Dale G; Ritchie, Euan G; Wallach, Arian D

    2014-01-01

    There has been much recent debate in Australia over whether lethal control of dingoes incurs environmental costs, particularly by allowing increase of populations of mesopredators such as red foxes and feral cats. Allen et al. (2013) claim to show in their recent study that suppression of dingo activity by poison baiting does not lead to mesopredator release, because mesopredators are also suppressed by poisoning. We show that this claim is not supported by the data and analysis reported in Allen et al.'s paper. PMID:24558973

  15. Diels–Alder Reactions of Allene with Benzene and Butadiene: Concerted, Stepwise, and Ambimodal Transition States

    PubMed Central

    2015-01-01

    Multiconfigurational complete active space methods (CASSCF and CASPT2) have been used to investigate the (4 + 2) cycloadditions of allene with butadiene and with benzene. Both concerted and stepwise radical pathways were examined to determine the mechanism of the Diels–Alder reactions with an allene dienophile. Reaction with butadiene occurs via a single ambimodal transition state that can lead to either the concerted or stepwise trajectories along the potential energy surface, while reaction with benzene involves two separate transition states and favors the concerted mechanism relative to the stepwise mechanism via a diradical intermediate. PMID:25216056

  16. Diels-Alder reactions of allene with benzene and butadiene: concerted, stepwise, and ambimodal transition states.

    PubMed

    Pham, Hung V; Houk, K N

    2014-10-01

    Multiconfigurational complete active space methods (CASSCF and CASPT2) have been used to investigate the (4 + 2) cycloadditions of allene with butadiene and with benzene. Both concerted and stepwise radical pathways were examined to determine the mechanism of the Diels-Alder reactions with an allene dienophile. Reaction with butadiene occurs via a single ambimodal transition state that can lead to either the concerted or stepwise trajectories along the potential energy surface, while reaction with benzene involves two separate transition states and favors the concerted mechanism relative to the stepwise mechanism via a diradical intermediate.

  17. Differentiating mechanistic possibilities for the thermal, intramolecular [2 + 2] cycloaddition of allene-ynes.

    PubMed

    Siebert, Matthew R; Osbourn, Joshua M; Brummond, Kay M; Tantillo, Dean J

    2010-09-01

    Intramolecular [2 + 2] cycloaddition reactions of allene-ynes offer a quick and efficient route to fused bicyclic ring structures. Insights into the mechanism and regiochemical preferences of this reaction are provided herein on the basis of the results of quantum chemical calculations (B3LYP/6-31+G(d,p)) and select experiments; both indicate that the reaction likely proceeds through a stepwise diradical pathway where one radical center is stabilized through allylic delocalization. The influences of the length of the tether connecting the alkyne and allene and substituent effects are also discussed.

  18. Copper-catalyzed regiodivergent silacarboxylation of allenes with carbon dioxide and a silylborane.

    PubMed

    Tani, Yosuke; Fujihara, Tetsuaki; Terao, Jun; Tsuji, Yasushi

    2014-12-24

    A regiodivergent silacarboxylation of allenes under a CO2 atmosphere with PhMe2Si-B(pin) as a silicon source in the presence of a copper catalyst at 70 °C has been developed. The regioselectivity of the reaction is successfully reversed by the proper choice of ligand; carboxylated vinylsilanes are obtained with rac-Me-DuPhos as the ligand, whereas the use of PCy3 affords carboxylated allylsilanes. Thus, two different carboxylated silanes can be selectively and regiodivergently synthesized from a single allene substrate. PMID:25469703

  19. The early eukaryotic fossil record.

    PubMed

    Javaux, Emmanuelle J

    2007-01-01

    The Precambrian era records the evolution of the domain Eucarya. Although the taxonomy of fossils is often impossible to resolve beyond the level of domain, their morphology and chemistry indicate the evolution of major biological innovations. The late Archean record for eukaryotes is limited to trace amounts of biomarkers. Morphological evidence appears in late Paleoproterozoic and early Mesoproterozoic (1800-1300 Ma) rocks. The moderate diversity of preservable eukaryotic organisms includes cell walls without surface ornament (but with complex ultrastructure), with regularly distributed surface ornamentation, and with irregularly or regularly arranged processes. Collectively, these fossils suggest that eukaryotes with flexible membranes and cytoskeletons existed in mid-Proterozoic oceans. The late Mesoproterozoic-early Neoproterozoic (1300-750 Ma) is a time of diversification and evolution when direct evidence for important biological innovations occurs in the fossil record such as multicellularity, sex, photosynthesis, biomineralization, predation, and heterotrophy. Members of extant clades can be recognized and include bangiophyte red algae, xanthophyte algae, cladophorale green algae, euglyphid, lobose, and filose amoebae and possible fungi. In the late Neoproterozoic, besides more diversification of ornamented fossils, florideophyte red algae and brown algae diversify, and animals take the stage. The record of biological innovations documented by the fossils shows that eukaryotes had evolved most cytological and molecular complexities very early in the Proterozoic but environmental conditions delayed their diversification within clades until oxygen level and predation pressure increased significantly. PMID:17977455

  20. Travels with the Fossil Hunters

    NASA Astrophysics Data System (ADS)

    Whybrow, Peter J.

    2000-04-01

    Whether dodging bullets in West Africa, or rabid dogs in Pakistan, surviving yak-butter tea in Tibet, or eating raw fish in China, the life of a globe-trotting fossil hunter is often hazardous and always filled with surprises. Travels with the Fossil Hunters lets readers share the wonder, joys of discovery, and excitement of these intrepid scientists. Packed with more than 100 beautiful, full-color photographs, the volume takes readers on twelve expeditions to remote parts of the world in search of diverse fossil remains, from those of dinosaurs to human ancestors. Each expedition by paleontologists from London's Natural History Museum reveals the problems and challenges of working in extreme conditions, from the deserts of the Sahara and Yemen to the frozen wastes of Antarctica, from the mountains of India to the forests of Latvia. Along the way they also describe the paleontology and geology of the countries they visit and the scientific reasons for their expeditions. With a foreword from Sir David Attenborough and an introduction from Richard Fortey, this fascinating book will appeal to amateur and professional fossil hunters alike and to readers interested in accounts of exotic locales. Peter Whybrow is a research scientist at the Natural History Museum, London. His research interests include Arabian Miocene vertebrates, paleoclimates, paleogeography, and biotic diversity. He is senior editor with A. Hill of Fossil Vertebrates of Arabia (Yale University Press, New Haven, 1999).

  1. Intermolecular sequential [4 + 2]-cycloaddition-aromatization reaction of aryl-substituted allenes with DMAD affording phenanthrene and naphthalene derivatives.

    PubMed

    Jiang, Xuefeng; Kong, Wangqing; Chen, Jie; Ma, Shengming

    2008-10-01

    An efficient entry to phenanthrene and naphthalene derivatives through intermolecular sequential [4 + 2]-cycloaddition-aromatization reactions of aryl-substituted allenes with DMAD in the absence of any catalyst was discovered. In this reaction the aromatic ring and the adjacent carbon-carbon double bond of the allene unit acted as the 1,3-diene.

  2. A Critique of Mark D. Allen's "The Preservation of Verb Subcategory Knowledge in a Spoken Language Comprehension Deficit"

    ERIC Educational Resources Information Center

    Kemmerer, David

    2008-01-01

    Allen [Allen, M. (2005). "The preservation of verb subcategory knowledge in a spoken language comprehension deficit." "Brain and Language, 95", 255-264.] reports a single patient, WBN, who, during spoken language comprehension, is still able to access some of the syntactic properties of verbs despite being unable to access some of their semantic…

  3. A Galactic Fossil

    NASA Astrophysics Data System (ADS)

    2007-05-01

    How old are the oldest stars? Using ESO's VLT, astronomers recently measured the age of a star located in our Galaxy. The star, a real fossil, is found to be 13.2 billion years old, not very far from the 13.7 billion years age of the Universe. The star, HE 1523-0901, was clearly born at the dawn of time. "Surprisingly, it is very hard to pin down the age of a star", the lead author of the paper reporting the results, Anna Frebel, explains. "This requires measuring very precisely the abundance of the radioactive elements thorium or uranium, a feat only the largest telescopes such as ESO's VLT can achieve." ESO PR Photo 23a/07 ESO PR Photo 23a/07 The 'Cosmic Clock' This technique is analogous to the carbon-14 dating method that has been so successful in archaeology over time spans of up to a few tens of thousands of years. In astronomy, however, this technique must obviously be applied to vastly longer timescales. For the method to work well, the right choice of radioactive isotope is critical. Unlike other, stable elements that formed at the same time, the abundance of a radioactive (unstable) isotope decreases all the time. The faster the decay, the less there will be left of the radioactive isotope after a certain time, so the greater will be the abundance difference when compared to a stable isotope, and the more accurate is the resulting age. Yet, for the clock to remain useful, the radioactive element must not decay too fast - there must still be enough left of it to allow an accurate measurement, even after several billion years. "Actual age measurements are restricted to the very rare objects that display huge amounts of the radioactive elements thorium or uranium," says Norbert Christlieb, co-author of the report. ESO PR Photo 23b/07 ESO PR Photo 23b/07 Uranium Line in the Spectrum of an Old Star Large amounts of these elements have been found in the star HE 1523-0901, an old, relatively bright star that was discovered within the Hamburg/ESO survey [1]. The

  4. The age for the fossil-bearing Tabbowa beds in Sri Lanka

    NASA Astrophysics Data System (ADS)

    Chang, S. C.; Dassanayake, S.; Wang, J.

    2014-12-01

    Well-preserved terrestrial fossils, mainly including conifers, cycads and ferns, were discovered from the Tabbowa beds in northwestern Sri Lanka. The high diversity and abundance of plants and insects from these Jurassic sediments provide a unique window to understand floral evolution and plant-insect co-evolution in the Mesozoic. For example, unearthed fossils from the Tabbowa beds indicate that leaf feeding and dwelling insects played a significant role in the Jurassic ecosystem. For another example, feeding and chewing marks on leaves allow studying insect behavior and paleo-ecology. Additionally, the recent discoveries of Otozamites latiphyllus and Otozamites tabbowensis from these sediments provide evidence that Bennettitales, an extinct order of seed plants, widely spread in the Gondwana during the Jurassic period. Although most fossils are yet to be well studied, and only few of the fossil occurrences have been published in western journals, plant fossils from the Tabbowa beds have great potential for substantially increasing our knowledge of Jurassic terrestrial ecosystems. The fossil-bearing Tabbowa beds are mainly composed of sandstone, siltstone, and mudstone with occasional thin bands of nodular limestone. Until now, radio-isotopic age determinations for the fossil-rich Tabbowa beds are lacking. In this study, we investigate the geological and geochronological setting of this area by dating detrital zircons from the Tabbowa beds. The age data will allow testing several hypotheses regarding the plant evolution, the basin development of this region.

  5. Palaeobiology: Argentinian unhatched pterosaur fossil.

    PubMed

    Chiappe, Luis M; Codorniú, Laura; Grellet-Tinner, Gerald; Rivarola, David

    2004-12-01

    Our knowledge of the eggs and embryos of pterosaurs, the Mesozoic flying reptiles, is sparse. Until now, the recent discovery of an ornithocheirid embryo from 121-million-year-old rocks in China constituted the only reliable evidence of an unhatched pterosaur. Here we describe an embryonic fossil of a different pterosaur from the Early Cretaceous lacustrine deposits of Loma del Pterodaustro (the Lagarcito Formation, which is about 100 million years old) in central Argentina. This new fossil provides insight into the eggshell morphology, early growth and nesting environments of pterosaurs.

  6. Silencing of hydroperoxide lyase and allene oxide synthase reveals substrate and defense signaling crosstalk in Nicotiana attenuata.

    PubMed

    Halitschke, Rayko; Ziegler, Jörg; Keinänen, Markku; Baldwin, Ian T

    2004-10-01

    The fatty acid hydroperoxide (HP) substrates required for the biosynthesis of jasmonic acid (JA) and green leaf volatiles (GLVs) are supplied by separate lipoxygenases (LOX). We silenced the expression of two genes downstream of the LOX: allene oxide synthase (AOS) and HP lyase (HPL) by antisense expression of endogenous genes (NaAOS, NaHPL) in Nicotiana attenuata, in which the biosynthesis of JA is amplified by herbivore-specific elicitors. We report that these elicitors also amplify wound-induced GLV releases, but suppress the wound-induced increase of NaHPL transcripts, suggesting that substrate flux controls GLV biosynthesis. As expected, silencing of NaHPL and NaAOS reduced GLV release and JA accumulation, respectively. Surprisingly, HPL- and AOS-silenced plants had enhanced JA and GLV responses, suggesting substrate 'crosstalk' between these two oxylipin cascades. Plants with depleted GLVs (as-hpl) were less attractive than wild type (WT) or empty vector control plants in choice-tests with native lepidopteran herbivores. In feeding trials, Manduca sexta larvae developed slower on as-hpl plants. The reduced larval consumption and performance, which was not caused by increases in defense responses in as-hpl plants, could be restored to WT levels by the addition of synthetic GLVs, demonstrating that GLVs function as feeding stimulants. Gene expression profiling by cDNA microarray analysis and characterization of several induced defenses in herbivore-elicited as-hpl and as-aos plants revealed differential involvement of JA and GLVs in defense signaling. Elicitation of volatile terpenoids (an indirect defense) requires JA signaling, where as trypsin protease inhibitor elicitation (a direct defense) requires both functional JA and GLV cascades.

  7. Evaluation of conventional power systems. [emphasizing fossil fuels and nuclear energy

    NASA Technical Reports Server (NTRS)

    Smith, K. R.; Weyant, J.; Holdren, J. P.

    1975-01-01

    The technical, economic, and environmental characteristics of (thermal, nonsolar) electric power plants are reviewed. The fuel cycle, from extraction of new fuel to final waste management, is included. Emphasis is placed on the fossil fuel and nuclear technologies.

  8. Cobalt/rhodium heterobimetallic nanoparticle-catalyzed carbonylative [2+2+1] cycloaddition of allenes and bisallenes to Pauson-Khand-type reaction products.

    PubMed

    Park, Ji Hoon; Kim, Eunha; Kim, Hyeong-Mook; Choi, Soo Young; Chung, Young Keun

    2008-05-28

    The first catalytic intra- and intermolecular [2+2+1] cocyclization reactions of allenes and carbon monoxide have been developed. In the Co(2)Rh(2) heterobimetallic nanoparticle-catalyzed carbonylative [2+2+1] cycloaddition of allenes and carbon monoxide, the allenes formally serve both as an excellent alkene- and alkyne-like moiety within a Pauson-Khand-type process.

  9. Economics of scale in the production of steam with solar thermal-fossil boiler hybrid systems

    NASA Astrophysics Data System (ADS)

    Hansen, F. R.; Lindner, D. L.; Vitko, J., Jr.

    1983-03-01

    Levelized energy costs for steam plants in the size range 15 MM Btu/h to 400 MM Btu/h were estimated for steam produced by several different technologies, including stand alone oil and coal burning plants and solar central receiver fossil boiler hybrid plants. Models for the costs of plant subsystems used in these calculations are presented. Designs of the solar fossil hybrids examined were optimized for solar fraction and amount of thermal storage used by simulation of plant operation. The resulting levelized energy costs and their sensitivity to various modelling parameters are discussed.

  10. Homoallylic amines by reductive inter- and intramolecular coupling of allenes and nitriles

    PubMed Central

    Manojlovic, Marija D

    2011-01-01

    Summary The one-pot hydrozirconation of allenes and nitriles followed by an in situ transmetalation of the allylzirconocene with dimethylzinc or zinc chloride provides functionalized homoallylic amines. An intramolecular version of this process leads to 3-aminotetrahydrofurans and 3-aminotetrahydropyrans. PMID:21804878

  11. Improving the Collection of Student Accounts at Allen County Community College.

    ERIC Educational Resources Information Center

    Geffert, Barbara

    During the past several years, Allen County Community College has experienced a growing number of uncollected student accounts. In an effort to encourage timely payment of student charges, lower the number of students receiving payment deferments, increase cash flow at the beginning of each semester, and reduce the number of bad debts being…

  12. The Native Speaker, the Student, and Woody Allen: Examining Traditional Roles in the Foreign Language Classroom.

    ERIC Educational Resources Information Center

    Finger, Anke

    This paper uses a language classroom role-playing scene from a Woody Allen movie to examine the language student who has traditionally been asked to emulate and copy the native speaker and to discuss roles that teachers ask students to play. It also presents the changing paradigm of the native speaker and his or her role inside and outside the…

  13. Rotationally resolved photoelectron spectroscopic study of the Jahn-Teller effect in allene

    NASA Astrophysics Data System (ADS)

    Schulenburg, A. M.; Merkt, F.

    2009-01-01

    The pulsed-field-ionization zero-kinetic-energy photoelectron spectra of allene (C3H4) and perdeuterated allene have been recorded from the first adiabatic ionization energy up to 2200 cm-1 of internal energy in the cations at a resolution sufficient to observe the full rotational structure. The intensity distributions in the spectra are dominated by vibrational progressions in the torsional mode, which were analyzed in the realm of a two-dimensional model of the E ⊗(b1⊕b2) Jahn-Teller effect in the allene cation [C. Woywod and W. Domcke, Chem. Phys. 162, 349 (1992)]. Whereas the rotational structure of the transitions to the lowest torsional levels (00 and 41) are regular and can be qualitatively analyzed in terms of a simple orbital ionization model, the rotational structure of the spectra of the 42 and 43 levels are strongly perturbed. The photoelectron spectrum of C3H4 also reveals several weak vibrational bands in the immediate vicinity of these levels that are indicative of (ro)vibronic perturbations. A slight broadening of the transitions to the 41 levels compared to that of the vibronic ground state and the increase of the number of sharp features in the rotational structure of the spectrum of the 42 level point at the importance of large-amplitude motions not considered in previous treatments of the Jahn-Teller effect in the allene cation.

  14. Astronauts Joseph Allen rides cherry picker over stowage area/work station

    NASA Technical Reports Server (NTRS)

    1984-01-01

    Astronaut Joseph P. Allen rides a cherry picker over to a stowage area/work station to wrap up extravehicular activity (EVA) duties above Earth. The cherry picker is a union of the mobile foot restraint and the remote manipulator system (RMS), controlled from inside Discovery's cabin. The Westar VI/PAM-D satellite is pictured secured in Discovery's cargo bay.

  15. Regioselective Allene Hydrosilylation Catalyzed by NHC Complexes of Nickel and Palladium

    PubMed Central

    Miller, Zachary D.; Li, Wei; Belderrain, Tomás R.; Montgomery, John

    2013-01-01

    Regioselective methods for allene hydrosilylation have been developed, with regioselectivity being governed primarily by choice of metal. Alkenylsilanes are produced via nickel catalysis with larger N-heterocyclic carbene ligands, and allylsilanes are produced via palladium catalysis with smaller N-heterocyclic carbene ligands. These complementary methods allow either regioisomeric product to be obtained with exceptional regiocontrol. PMID:24079389

  16. Nathaniel Topliff Allen, Early Professional and 19th Century Risk Taker.

    ERIC Educational Resources Information Center

    Cadwallader, Lynn

    Nathaniel T. Allen's life (1823-1903) offers insights into 19th century professionalization of education in the United States. His independent political views set him apart as a strong-willed and dauntless supporter of equal education opportunity. Appointed by Horace Mann as principal of a model school connected with the first public normal school…

  17. An Interview with Dr. Roach van Allen (Leaders in Reading Research and Instruction).

    ERIC Educational Resources Information Center

    Searfoss, Lyndon; Jerrolds, Bob W.

    1989-01-01

    Presents an interview with Dr. Roach van Allen in which he describes how he became involved in education, who influenced him professionally, his proudest accomplishments (a theoretical model for a language experience program), what he sees as the current problems in reading education, and what he sees in the future. (RS)

  18. A Call to Action: JoBeth Allen, NCTE's 2012 Outstanding Educator in the Language Arts

    ERIC Educational Resources Information Center

    Tisdale, Carmen

    2012-01-01

    This article is a tribute to JoBeth Allen, recipient of the Elementary Section's 2012 award for Outstanding Educator in the English Language Arts. Each year, this award recognizes a distinguished educator who has made major contributions to the field of language arts in elementary education. This article was written by second-grade teacher and…

  19. All Together Now: Valerie Allen--U.S. Department of Energy

    ERIC Educational Resources Information Center

    Library Journal, 2005

    2005-01-01

    When Valerie Allen decided she did not want to be a Montessori teacher any longer, she began work on her MLIS. Immediately she learned concepts she could apply to her new job as information specialist for the Department of Energy's (DOE) Office of Scientific and Technical Information (OSTI) at Oak Ridge National Laboratory, TN. While the LIS…

  20. Precipitation of relativistic electrons of the Van Allen belts into the proton aurora

    SciTech Connect

    Jordanova, Vania K; Miyoshi, Y; Sakaguchi, K; Shiokawa, K; Evans, D S; Connors, M

    2008-01-01

    The Van Allen electron belts consist of two regions encircling the earth in which relativistic electrons are trapped in the earth's magnetic field. Populations of relativistic electrons in the Van Allen belts vary greatly with geomagnetic disturbance and they are a major source of damage to space vehicles. In order to know when and by how much these populations of relativistic electrons increase, it is important to elucidate not only the cause of acceleration of relativistic electrons but also the cause of their loss from the Van Allen belts. Here we show the first evidence that left-hand polarized electromagnetic ion cyclotron (EMIC) plasma waves can cause the loss of relativistic electrons into the atmosphere, on the basis of results of an excellent set of ground and satellite observations showing coincident precipitation of ions with energies of tens of keV and of relativistic electrons into an isolated proton aurora. The proton aurora was produced by precipitation of ions with energies of tens of keV due to EMIC waves near the plasma pause, which is a manifestation of wave-particle interactions. These observations clarify that ions with energies of tens of keV affect the evolution of relativistic electrons in the Van Allen belts via parasitic resonance with EMIC waves, an effect that was first theoretically predicted in the early 1970's.

  1. Rh(I)-Catalyzed Insertion of Allenes into C-C Bonds of Benzocyclobutenols.

    PubMed

    Zhao, Chunliang; Liu, Li-Chuan; Wang, Jing; Jiang, Chenran; Zhang, Qing-Wei; He, Wei

    2016-01-15

    Herein we report a Rh(I)-catalyzed two carbon insertion into C-C bonds of benzocyclobutenols by employing symmetrical and unsymmetrical allenes. This reaction provides rapid access to alkylidene tetralins bearing two adjacent stereogenic centers in good yields and diasteroselectivities.

  2. No Radio Flaring Detected from Cygnus X-3 at 3 GHz by Allen Telescope Array

    NASA Astrophysics Data System (ADS)

    Williams, P. K. G.; Bower, G. C.; Tomsick, J. A.; Bodaghee, A.; Corbet, R. H. D.

    2011-01-01

    Following the announcement of a 98 GHz flare from the microquasar Cygnus X-3 (ATel #3130), we observed it with the Allen Telescope Array (Welch et al., 2009 Proc. IEEE 97 1438 for 2.5 hours beginning at 2011 January 28.848 UT (MJD 55589.848), about 4.0 hours after the 98 GHz observations concluded.

  3. Complex polycyclic scaffolds by metathesis rearrangement of Himbert arene/allene cycloadducts.

    PubMed

    Lam, Jonathan K; Schmidt, Yvonne; Vanderwal, Christopher D

    2012-11-01

    The intramolecular arene/allene cycloaddition first described 30 years ago by Himbert and Henn permits rapid access to strained polycyclic compounds. Alkene metathesis processes cleanly rearrange appropriately substituted cycloadducts into complex, functional-group-rich polycyclic lactams of potential utility for natural product synthesis and medicinal chemistry.

  4. Highly selective cobalt-mediated [6 + 2] cycloaddition of cycloheptatriene and allenes.

    PubMed

    Clavier, Hervé; Le Jeune, Karel; de Riggi, Innocenzo; Tenaglia, Alphonse; Buono, Gérard

    2011-01-21

    [6 + 2] Cycloadditions between cycloheptatrienes with allenes have been investigated. Cobalt salts were found to promote this transformation efficiently. Moreover, this reaction was found to be highly selective since only one regioisomer was obtained with an excellent E/Z-selectivity.

  5. Studies on Lewis acid-mediated intramolecular cyclization reactions of allene-ene systems.

    PubMed

    Hiroi, K; Watanabe, T; Tsukui, A

    2000-03-01

    The Lewis acid-mediated reactions of allene-ene compounds, derived from 3-methylcitronellal or dimethyl malonate, were carried out using various Lewis acids such as ethylaluminum dichloride, diethylaluminum chloride, titanium chloride, zinc chloride etherate, or boron trifluoride etherate, affording unexpectedly intramolecular [2+2]cycloaddition products under some particular reaction conditions without any formation of intramolecular ene reaction products.

  6. Gold(I)-catalyzed enantioselective [4 + 2]-cycloaddition of allene-dienes.

    PubMed

    González, Ana Z; Toste, F Dean

    2010-01-01

    An enantioselective gold(I)-catalyzed intramolecular [4 + 2]-cycloaddition of allenes and dienes is reported. The reactions allow for the asymmetric synthesis of trans-hexahydroindenes and pyrrolidine products using C(3)-symmetric phosphitegold(I) and ortho-arylphosphoramiditegold(I) complexes as catalysts, respectively.

  7. Enantioselective [2 + 2 + 2] cycloaddition reaction of isocyanates and allenes catalyzed by nickel.

    PubMed

    Miura, Tomoya; Morimoto, Masao; Murakami, Masahiro

    2010-11-17

    The enantioselective intermolecular [2 + 2 + 2] cycloaddition reaction of two molecules of isocyanate and one molecule of allene is catalyzed by a nickel(0)/(S,S)-i-Pr-FOXAP complex, providing an efficient access to enantiomerically enriched dihydropyrimidine-2,4-diones.

  8. Gold-catalyzed stereocontrolled oxacyclization/[4+2]-cycloaddition cascade of ketone-allene substrates.

    PubMed

    Teng, Tse-Min; Liu, Rai-Shung

    2010-07-14

    We report the first success on the Au-catalyzed tandem oxacyclization/[4+2]-cycloaddition cascade using ketone-allene substrates to give highly substituted oxacyclics with excellent stereocontrol. In contrast to oxo-alkyne substrates, the resulting cycloadducts are isolable and efficiently produced from a reasonable scope of enol ethers.

  9. Gold(I)-catalyzed enantioselective [4 + 2]-cycloaddition of allene-dienes.

    PubMed

    González, Ana Z; Toste, F Dean

    2010-01-01

    An enantioselective gold(I)-catalyzed intramolecular [4 + 2]-cycloaddition of allenes and dienes is reported. The reactions allow for the asymmetric synthesis of trans-hexahydroindenes and pyrrolidine products using C(3)-symmetric phosphitegold(I) and ortho-arylphosphoramiditegold(I) complexes as catalysts, respectively. PMID:19961192

  10. Discovery of a linoleate 9S-dioxygenase and an allene oxide synthase in a fusion protein of Fusarium oxysporum[S

    PubMed Central

    Hoffmann, Inga; Oliw, Ernst H.

    2013-01-01

    Fusarium oxysporum is a devastating plant pathogen that oxidizes C18 fatty acids sequentially to jasmonates. The genome codes for putative dioxygenase (DOX)-cytochrome P450 (CYP) fusion proteins homologous to linoleate diol synthases (LDSs) and the allene oxide synthase (AOS) of Aspergillus terreus, e.g., FOXB_01332. Recombinant FOXB_01332 oxidized 18:2n-6 to 9S-hydroperoxy-10(E),12(Z)-octadecadienoic acid by hydrogen abstraction and antarafacial insertion of molecular oxygen and sequentially to an allene oxide, 9S(10)-epoxy-10,12(Z)-octadecadienoic acid, as judged from nonenzymatic hydrolysis products (α- and γ-ketols). The enzyme was therefore designated 9S-DOX-AOS. The 9S-DOX activity oxidized C18 and C20 fatty acids of the n-6 and n-3 series to hydroperoxides at the n-9 and n-7 positions, and the n-9 hydroperoxides could be sequentially transformed to allene oxides with only a few exceptions. The AOS activity was stereospecific for 9- and 11-hydroperoxides with S configurations. FOXB_01332 has acidic and alcoholic residues, Glu946-Val-Leu-Ser949, at positions of crucial Asn and Gln residues (Asn-Xaa-Xaa-Gln) of the AOS and LDS. Site-directed mutagenesis studies revealed that FOXB_01332 and AOS of A. terreus differ in catalytically important residues suggesting that AOS of A. terreus and F. oxysporum belong to different subfamilies. FOXB_01332 is the first linoleate 9-DOX with homology to animal heme peroxidases and the first 9-DOX-AOS fusion protein. PMID:24082064

  11. Fossils of big bang turbulence

    NASA Astrophysics Data System (ADS)

    Gibson, C. H.

    2004-12-01

    A model is proposed connecting turbulence, fossil turbulence, and the big bang origin of the universe. While details are incomplete, the model is consistent with our knowledge of these processes and is supported by observations. Turbulence arises in a hot-big-bang quantum-gravitational-dynamics scenario at Planck scales. Chaotic, eddy-like-motions produce an exothermic Planck particle cascade from 10-35 m at 1032 K to 108 larger, 104 cooler, quark-gluon scales. A Planck-Kerr instability gives high-Reynolds-number (Re 106) turbulent combustion, space-time-energy-entropy and turbulent mixing. Batchelor-Obukhov-Corrsin turbulent-temperature fluctuations are preserved as the first fossil-turbulence by inflation stretching the patterns beyond the horizon ct of causal connection faster than light speed c in time t 10-33 seconds. Fossil-big-bang-temperature-turbulence re-enters the horizon and imprints nucleosynthesis of H-He densities that seed fragmentation by gravity at 1012 s in the low Reynolds number plasma before its transition to gas at t 1013 s and T 3000 K. Multi-scaling coefficients of the cosmic-microwave-background (CMB) temperature anisotropies closely match those for high Reynolds number turbulence, Bershadskii and Sreenivasan 2002, 2003. CMB spectra support the interpretation that big-bang-turbulence-fossils triggered fragmentation of the viscous plasma at supercluster to galaxy mass scales from 1046 to 1042 kg, Gibson 1996, 2000, 2004ab.

  12. The colour of fossil feathers.

    PubMed

    Vinther, Jakob; Briggs, Derek E G; Prum, Richard O; Saranathan, Vinodkumar

    2008-10-23

    Feathers are complex integumentary appendages of birds and some other theropod dinosaurs. They are frequently coloured and function in camouflage and display. Previous investigations have concluded that fossil feathers are preserved as carbonized traces composed of feather-degrading bacteria. Here, an investigation of a colour-banded feather from the Lower Cretaceous Crato Formation of Brazil revealed that the dark bands are preserved as elongate, oblate carbonaceous bodies 1-2 microm long, whereas the light bands retain only relief traces on the rock matrix. Energy dispersive X-ray analysis showed that the dark bands preserve a substantial amount of carbon, whereas the light bands show no carbon residue. Comparison of these oblate fossil bodies with the structure of black feathers from a living bird indicates that they are the eumelanin-containing melanosomes. We conclude that most fossil feathers are preserved as melanosomes, and that the distribution of these structures in fossil feathers can preserve the colour pattern in the original feather. The discovery of preserved melanosomes opens up the possibility of interpreting the colour of extinct birds and other dinosaurs.

  13. Progress of fossil fuel science

    SciTech Connect

    Demirbas, M.F.

    2007-07-01

    Coal is the most abundant and widely distributed fossil fuel. More than 45% of the world's electricity is generated from coal, and it is the major fuel for generating electricity worldwide. The known coal reserves in the world are enough for more than 215 years of consumption, while the known oil reserves are only about 39 times of the world's consumption and the known natural gas reserves are about 63 times of the world's consumption level in 1998. In recent years, there have been effective scientific investigations on Turkish fossil fuels, which are considerable focused on coal resources. Coal is a major fossil fuel source for Turkey. Turkish coal consumption has been stable over the past decade and currently accounts for about 24% of the country's total energy consumption. Lignite coal has had the biggest share in total fossil fuel production, at 43%, in Turkey. Turkish researchers may investigate ten broad pathways of coal species upgrading, such as desulfurization and oxydesulfurization, pyrolysis and hydropyrolysis, liquefaction and hydroliquefaction, extraction and supercritical fluid extraction, gasification, oxidation, briquetting, flotation, and structure identification.

  14. Fossil energy program. Progress report for June 1980

    SciTech Connect

    McNeese, L.E.

    1980-08-01

    This report - the seventy-first of a series - is a compendium of monthly progress reports for the ORNL research and development programs that are in support of the increased utilization of coal and other fossil fuel alternatives to oil and gas as sources of clean energy. The projects reported this month include those for coal conversion development, chemical research and development, materials technology, component and process evaluation studies, technical support to major liquefaction projects, process analysis and engineering evaluation, fossil energy environmental analysis, coal preparation and waste utilization, coal preparation plant automation, atmospheric fluidized bed coal combustor for cogeneration, TVA fluidized combustion demonstration plant program technical support, coal cogeneration/district heating plant assessment, performance assurance system support, and international energy technology assessment.

  15. Fossil energy program. Progress report for May 1980

    SciTech Connect

    McNeese, L.E.

    1980-08-01

    This report - the seventieth of a series - is a compendium of monthly progress reports for the ORNL research and development programs that are in support of the increased utilization of coal and other fossil fuel alternatives to oil and gas as sources of clean energy. The projects reported this month include those for coal conversion development, chemical research and development, materials technology, component and process evaluation studies, technical support to major liquefaction projects, process analysis and engineering evaluations, fossil energy environmental analysis, coal preparation and waste utilization, coal preparation plant automation, technical support to the TVA fluidized bed combustion demonstration plant program, coal cogeneration/district heating plant assessment, atmospheric fluidized bed coal combustor for cogeneration, performance assurance system support and international energy technology assessment.

  16. Can UK fossil fuel emissions be determined by radiocarbon measurements?

    NASA Astrophysics Data System (ADS)

    Wenger, Angelina; O'Doherty, Simon; Rigby, Matthew; Manning, Alistair; Palmer, Paul

    2016-04-01

    The GAUGE project evaluates different methods to estimate UK emissions. However, estimating carbon dioxide emissions as a result of fossil fuel burning is challenging as natural fluxes in and out of the atmosphere are very large. Radiocarbon (14C) measurements offer a way to specifically measure the amount of recently added carbon dioxide from fossil fuel burning. This is possible as, due to their age, all the radiocarbon in fossil fuels has decayed. Hence the amount of recently added CO2 from fossil fuel burning can be measured as a depletion of the 14C content in air. While this method has been successfully applied by several groups on a city or a regional scale, this is the first attempt at using the technique for a national emission estimate. Geographically the UK, being an island, is a good location for such an experiment. But are 14CO2 measurements the ideal solution for estimating fossil fuel emissions as they are heralded to be? Previous studies have shown that 14CO2emissions from the nuclear industry mask the 14C depletion caused by fossil fuel burning and result in an underestimation of the fossil fuel CO2. While this might not be a problem in certain regions around the world, many countries like the UK have a substantial nuclear industry. A correction for this enhancement from the nuclear industry can be applied but are invariably difficult as 14CO2emissions from nuclear power plants have a high temporal variability. We will explain how our sampling strategy was chosen to minimize the influence form the nuclear industry and why this proved to be challenging. In addition we present the results from our ground based measurements to show why trying to estimate national emissions using radiocarbon measurements was overambitious, and how practical the technique is for the UK in general.

  17. New Results About the Earth’s Van Allen Radiation Belts

    NASA Astrophysics Data System (ADS)

    Baker, Daniel

    2015-01-01

    The first great scientific discovery of the Space Age was that the Earth is enshrouded in toroids, or 'belts', of very high-energy magnetically trapped charged particles. Early observations of the radiation environment clearly indicated that the Van Allen belts could be delineated into an inner zone dominated by high-energy protons and an outer zone dominated by high-energy electrons. Subsequent studies showed that electrons in the energy range 100 keV < E< 1 MeV often populated both the inner and outer zones with a pronounced 'slot' region relatively devoid of energetic electrons existing between them. This two-belt structure for the Van Allen moderate-energy electron component was explained as being due to strong interactions of electrons with electromagnetic waves just inside the cold plasma (plasmapause) boundary. The energy distribution, spatial extent and particle species makeup of the Van Allen belts has been subsequently explored by several space missions. However, recent observations by the NASA dual-spacecraft Van Allen Probes mission have revealed wholly unexpected properties of the radiation belts, especially at highly relativistic (E > 2 MeV) and ultra-relativistic (E > 5 MeV) kinetic energies. In this presentation we show using high spatial and temporal resolution data from the Relativistic Electron-Proton Telescope (REPT) experiment on board the Van Allen Probes that multiple belts can exist concurrently and that an exceedingly sharp inner boundary exists for ultra-relativistic electrons. Using additionally available Van Allen Probes data, we demonstrate that these remarkable features of energetic electrons are not due to a physical boundary within Earth's intrinsic magnetic field. Neither is it likely that human-generated electromagnetic transmitter wave fields might produce such effects. Rather, we conclude from these unique measurements that slow natural inward radial diffusion combined with weak, but persistent, wave-particle pitch angle

  18. Fossil Energy: Drivers and Challenges.

    NASA Astrophysics Data System (ADS)

    Friedmann, Julio

    2007-04-01

    Concerns about rapid economic growth, energy security, and global climate change have created a new landscape for fossil energy exploration, production, and utilization. Since 85% of primary energy supply comes from fossil fuels, and 85% of greenhouse gas emissions come from fossil fuel consumption, new and difficult technical and political challenges confront commercial, governmental, and public stakeholders. As such, concerns over climate change are explicitly weighed against security of international and domestic energy supplies, with economic premiums paid for either or both. Efficiency improvements, fuel conservation, and deployment of nuclear and renewable supplies will help both concerns, but are unlikely to offset growth in the coming decades. As such, new technologies and undertakings must both provide high quality fossil energy with minimal environmental impacts. The largest and most difficult of these undertakings is carbon management, wherein CO2 emissions are sequestered indefinitely at substantial incremental cost. Geological formations provide both high confidence and high capacity for CO2 storage, but present scientific and technical challenges. Oil and gas supply can be partially sustained and replaced through exploitation of unconventional fossil fuels such as tar-sands, methane hydrates, coal-to-liquids, and oil shales. These fuels provide enormous reserves that can be exploited at current costs, but generally require substantial energy to process. In most cases, the energy return on investment (EROI) is dropping, and unconventional fuels are generally more carbon intensive than conventional, presenting additional carbon management challenges. Ultimately, a large and sustained science and technology program akin to the Apollo project will be needed to address these concerns. Unfortunately, real funding in energy research has dropped dramatically (75%) in the past three decades, and novel designs in fission and fusion are not likely to provide any

  19. C-isotope composition of fossil sedges and grasses

    NASA Astrophysics Data System (ADS)

    Kurschner, Wolfram M.

    2010-05-01

    C4 plants differ from C3 plants regarding their anatomy and their C-isotope composition. Both features can be used in the geological record to determine the presence of C4 plants. Yet, the evolution of the C4 pathway in the fossil record is enigmatic as palaeobotanical and geological evidence for C4 plants is sparse. The oldest structural evidence for Kranz anatomy has been found in Late Miocene permineralized grass leaf remains. But studies on the C-isotope composition of sedimentary organic matter indicate that abundant C4 biomass was present in N-America and Asia throughout the Miocene in expanding savannahs and grasslands. The success of C4 plants appears to be related also to an increasing seasonal aridity in the tropical climate belts and the co-evolution of grazers. However, C- isotope composition of palaeosols or vertebrate teeth only allows to estimate the abundance of C4 plant biomass in the vegetation or in the diet without further taxonomical specification which plant groups would have had C4 metabolism. In this contribution the first extensive C-isotope analysis of fossil seeds of sedges and a few grasses are presented. The age of the carpological material ranges from Late Eocene to Pliocene and was collected from several central European brown coal deposits. The 52 different taxa studied include several species of Carex, Cladiocarya, Eriopherum, Eleocharis, Scirpus, Sparganium. Most of them representing herbaceous elements of a (sub)tropical vegetation growing near the edge of a lake. The C-isotope composition of the fossil seeds varies between -30 and -23 o/oo indicating C3 photosynthesis. This first systematic inventory shows that C4 plants were absent in the European (sub)tropical brown coal forming wetland vegetation during the Tertiary. These preliminary data are in agreement with phylogenetic studies which predict the origin of C4 plants outside the European realm.

  20. Paleophysiology: From Fossils to the Future.

    PubMed

    Vermeij, Geerat J

    2015-10-01

    Future environments may resemble conditions that have not existed for millions of years. To assess the adaptive options available to organisms evolving under such circumstances, it is instructive to probe paleophysiology, the ways in which ancient life coped with its physical and chemical surroundings. To do this, we need reliable proxies that are based on fundamental principles, quantitatively verified in living species, and observable in fossil remains. Insights have already come from vertebrates and plants, and others will likely emerge for marine animals if promising proxies are validated. Many questions remain about the circumstances for the evolution of environmental tolerances, metabolic rates, biomineralization, and physiological responses to interacting species, and about how living organisms will perform under exceptional conditions.

  1. Viroids: "living fossils" of primordial RNAs?

    PubMed

    Diener, Theodor O

    2016-01-01

    The discovery of the viroid in 1971, which initiated the third major expansion of the biosphere towards smaller living entities-after discovery of the "subvisual" microorganisms in 1675 and that of the "submicroscopic" viruses in 1892-has been officially endorsed by the International Committee on Virus Taxonomy as a new order called subviral agents.In 1989, I proposed that, based on their respective molecular properties, viroids are more plausible "living fossils" of the hypothetical RNA World (widely assumed to have existed prior to the evolution of DNA or proteins) than are intron-derived RNAs, which were, at that time, suggested as putative survivors. There were few citations of my proposal-and virtually none of viroids-beyond plant virology unil 1994, when Cheles-Flores critically examined the hypothesis and pointed out a serious difficulty, as well as a process by which this difficulty could be overcome. In 2013, when investigations by Koonin and Dolja revealed that of extant RNAs, viroids "strikingly" display some of the molecular properties posited for the earliest evolving, selfish RNAs (primordial RNAs), but, because extant organisms, aside from higher plants, appear not to harbor viroids, they cannot be regarded as primordial fossils, but appear to have evolved post LUCA (the Last Universal Common Ancestor). Here, I review whether some evidence nevertheless is compatible with the original postulate of the 1989 hypothesis. My analysis reveals no unequivocal evidence for an ancient origin of viroids, but suggests, alternatively, that viroids may have evolved de novo more recently, probably by novel processes similar to those suggested by each reviewer.These results are important, because they help illuminate a little understood period of abiogenesis--after the abiotic synthesis of life's chemical building blocks, which is, in principle, understood, and before the evolution of DNA and proteins in the late RNA World. PMID:27016066

  2. Fossil groups of galaxies: Are they groups? Are they fossils?

    NASA Astrophysics Data System (ADS)

    Dupke, Renato de Alencar; Miller, Eric; de Oliveira, Claudia Mendes; Sodre, Laerte; Rykoff, Eli; de Oliveira, Raimundo Lopes; Proctor, Rob

    2010-11-01

    Fossil groups present a puzzle to current theories of structure formation. Despite the low number of bright galaxies, their high velocity dispersions and high TX indicate cluster-like potential wells. Measured concentration parameters seem very high indicating early formation epochs in contradiction with the observed lack of large and well defined cooling cores. There are very few fossil groups with good quality X-ray data and their idiosyncrasies may enhance these apparent contradictions. The standard explanation for their formation suggests that bright galaxies within half the virial radii of these systems were wiped out by cannibalism forming the central galaxy. Since dry mergers, typically invoked to explain the formation of the central galaxies, are not expected to change the IGM energetics significantly, thus not preventing the formation of cooling cores, we investigate the scenario where recent gaseous (wet) mergers formed the central galaxy injecting energy and changing the chemistry of the IGM in fossil groups. We show a test for this scenario using fossil groups with enough X-ray flux in the Chandra X-ray Observatory archive by looking at individual metal abundance ratio distributions near the core. Secondary SN II powered winds would tend to erase the dominance of SN IA ejecta in the core of these systems and would help to erase previously existing cold cores. Strong SN II-powered galactic winds resulting from galaxy merging would be trapped by their deep potential wells reducing the central enhancement of SN Ia/SN II iron mass fraction ratio. The results indicate that there is a decrement in the ratio of SN Ia to SN II iron mass fraction in the central regions of the systems analyzed, varying from 99±1% in the outer regions to 85±2% within the cooling radius (Figure 1) and would inject enough energy into the IGM preventing central gas cooling. The results are consistent with a scenario of later formation epoch for fossil groups, as they are defined

  3. Palladium-catalyzed synthesis of endocyclic allenes and their application in stereoselective [2 + 2]cycloaddition with ketenes.

    PubMed

    Ogasawara, Masamichi; Okada, Atsushi; Nakajima, Kiyohiko; Takahashi, Tamotsu

    2009-01-01

    Palladium-catalyzed reactions of various 2-bromo-3-exo-methylenecycloalkenes with a stabilized nucleophile were examined. When the carbocycles were nine-membered or larger, the corresponding endocyclic allenes were isolated in excellent yields. In a reaction of the eight-membered cyclic substrate, initial formation of a cycloocta-1,2-diene derivative was detected; however, it dimerized slowly. The seven-membered carbocycle was inert to the reaction. Using a chiral Pd-catalyst, an axially chiral endocyclic allene was obtained in 65% ee. The cyclic allenes were applied to [2 + 2]cycloaddition with ketenes, and the stereoselectivity was studied.

  4. Looking at Fossils in New Ways

    ERIC Educational Resources Information Center

    Flannery, Maura C.

    2005-01-01

    Existing fossils could be studied from a different prospective with the use of new methods of analysis for gathering more information. The new techniques of studying fossils binds the new and the old techniques and information and provides another way to look at fossils.

  5. FOSSIL SPRINGS ROADLESS AREA, ARIZONA.

    USGS Publications Warehouse

    Beard, L.S.; Ellis, C.E.

    1984-01-01

    Based on field studies, the Fossil Springs Roadless Area in central Arizona is concluded to have little promise for the occurrence of mineral or energy resources. Rocks in the Supai Formation (Pennsylvanian-Permian) near the central part of the roadless area contain widespread but spotty copper mineralization and trace amounts of uranium. Analyses obtained during the study define geochemical anomalies in two portions of the area that remain unexplained. The suites of anomalous metals suggest the possibility of hydrothermal veins and the presence of ultramafic rocks; neither were found in the field. Although there is little promise for the occurrence of mineral resources in the Fossil Springs Roadless Area, studies to identify the source of the geochemical anomalies could have valuable implications for regional studies and mineral exploration in the surrounding area.

  6. Extinction and the fossil record

    NASA Technical Reports Server (NTRS)

    Sepkoski, J. J. Jr; Sepkoski JJ, ,. J. r. (Principal Investigator)

    1994-01-01

    The author examines evidence of mass extinctions in the fossil record and searches for reasons for such large extinctions. Five major mass extinctions eliminated at least 40 percent of animal genera in the oceans and from 65 to 95 percent of ocean species. Questions include the occurrence of gradual or catastrophic extinctions, causes, environment, the capacity of a perturbation to cause extinctions each time it happens, and the possibility and identification of complex events leading to a mass extinction.

  7. Microbial denitrogenation of fossil fuels.

    PubMed

    Benedik, M J; Gibbs, P R; Riddle, R R; Willson, R C

    1998-09-01

    The microbial degradation of nitrogen compounds from fossil fuels is important because of the contribution these contaminants make to the formation of nitrogen oxides (NOx) and hence to air pollution and acid rain. They also contribute to catalyst poisoning during the refining of crude oil, thus reducing process yields. We review the current status of microbial degradation of aromatic nitrogen compounds and discuss the potential of microbial processes to alleviate these problems.

  8. Molecular and Fossil Evidence on the Origin of Angiosperms

    NASA Astrophysics Data System (ADS)

    Doyle, James A.

    2012-05-01

    Molecular data on relationships within angiosperms confirm the view that their increasing morphological diversity through the Cretaceous reflected their evolutionary radiation. Despite the early appearance of aquatics and groups with simple flowers, the record is consistent with inferences from molecular trees that the first angiosperms were woody plants with pinnately veined leaves, multiparted flowers, uniovulate ascidiate carpels, and columellar monosulcate pollen. Molecular data appear to refute the hypothesis based on morphology that angiosperms and Gnetales are closest living relatives. Morphological analyses of living and fossil seed plants that assume molecular relationships identify glossopterids, Bennettitales, and Caytonia as angiosperm relatives; these results are consistent with proposed homologies between the cupule of glossopterids and Caytonia and the angiosperm bitegmic ovule. Jurassic molecular dates for the angiosperms may be reconciled with the fossil record if the first angiosperms were restricted to wet forest understory habitats and did not radiate until the Cretaceous.

  9. Expression of concern: A unifying mechanism for the rearrangement of vinyl allene oxide geometric isomers to cyclopentenones.

    PubMed

    Kelly, Richard

    2015-12-21

    Expression of concern for 'A unifying mechanism for the rearrangement of vinyl allene oxide geometric isomers to cyclopentenones' by Adán B. González-Pérez et al., Org. Biomol. Chem., 2014, 12, 7694-7701.

  10. A Versatile Room-Temperature Route to Di- and Trisubstituted Allenes Using Flow-Generated Diazo Compounds.

    PubMed

    Poh, Jian-Siang; Tran, Duc N; Battilocchio, Claudio; Hawkins, Joel M; Ley, Steven V

    2015-06-26

    A copper-catalyzed coupling reaction between flow-generated unstabilized diazo compounds and terminal alkynes provides di- and trisubstituted allenes. This extremely mild and rapid transformation is highly tolerant of several functional groups.

  11. Novel synthesis of fused isoxazolidines via a palladium catalysed allene insertion-intramoleculer 1,3-dipolar cycloaddition cascade reaction.

    PubMed

    Aftab, Tajassas; Grigg, Ronald; Ladlow, Mark; Sridharan, Visuvanathar; Thornton-Pett, Mark

    2002-08-21

    A one pot, three component palladium catalysed allenation of aryl iodides, in combination with a nitrone cycloaddition, leads to formation of fused isoxazolidines, creating two rings, two stereocentres and one tetrasubstituted carbon centre.

  12. Nickel-iminophosphine-catalyzed [4+2] cycloaddition of enones with allenes: synthesis of highly substituted dihydropyrans.

    PubMed

    Sako, Saori; Kurahashi, Takuya; Matsubara, Seijiro

    2011-06-01

    Enones were found to react with allenes intermolecularly in the presence of a catalytic amount of a nickel-iminophosphine complex to provide dihydropyrans via oxidative cyclization of an enone and Ni(0).

  13. Rh(I)-catalyzed intramolecular [3 + 2] cycloaddition reactions of 1-ene-, 1-yne- and 1-allene-vinylcyclopropanes.

    PubMed

    Jiao, Lei; Lin, Mu; Yu, Zhi-Xiang

    2010-02-21

    New Rh(I)-catalyzed intramolecular [3 + 2] cycloaddition reactions of 1-ene-, 1-yne and 1-allene-vinylcyclopropanes have been developed, affording an efficient and versatile synthesis of cyclopentane- and cyclopentene-embedded bicyclic structures.

  14. Automated determination of electron density from electric field measurements on the Van Allen Probes spacecraft

    NASA Astrophysics Data System (ADS)

    Zhelavskaya, Irina; Kurth, William; Spasojevic, Maria; Shprits, Yuri

    2016-07-01

    We present the Neural-network-based Upper-hybrid Resonance Determination (NURD) algorithm for automatic inference of the electron number density from plasma wave measurements made onboard NASA's Van Allen Probes mission. A feedforward neural network is developed to determine the upper hybrid resonance frequency, f_{uhr}, from electric field measurements, which is then used to calculate the electron number density. In previous missions, the plasma resonance bands were manually identified, and there have been few attempts to do robust, routine automated detections. We describe the design and implementation of the algorithm and perform an initial analysis of the resulting electron number density distribution obtained by applying NURD to 2.5 years of data collected with the EMFISIS instrumentation suite of the Van Allen Probes mission. Densities obtained by NURD are compared to those obtained by another recently developed automated technique and also to an existing empirical plasmasphere and trough density model.

  15. Arthroscopic Medial Meniscus Posterior Root Fixation Using a Modified Mason-Allen Stitch

    PubMed Central

    Chung, Kyu Sung; Ha, Jeong Ku; Ra, Ho Jong; Kim, Jin Goo

    2016-01-01

    A complete radial tear of the meniscus posterior root, which can effectively cause a state of total meniscectomy via loss of hoop tension, requires that the torn root be repaired. Several methods have been used to repair medial meniscus posterior root tears, most of which are based on a simple stitch technique that is known to have stitch-holding strength. We applied a modified version of the Mason-Allen stitch technique, which is recognized as a method for rotator cuff repair surgery because its locking effect overcomes the potential weakness of simple stitches. This article introduces the medial meniscus posterior root tears repair procedure based on a modified Mason-Allen stitch technique in which 2 strands (i.e., 1 simple horizontal and 1 simple vertical stitch) are used. PMID:27073778

  16. Automated Determination of Electron Density from Electric Field Measurements on the Van Allen Probes Spacecraft

    NASA Astrophysics Data System (ADS)

    Zhelavskaya, Irina; Spasojevic, Maria; Shprits, Yuri; Kurth, William

    2016-04-01

    We present the Neural-network-based Upper-hybrid Resonance Determination (NURD) algorithm for automatic inference of the electron number density from plasma wave measurement made onboard NASA's Van Allen Probes mission. A feedforward neural network is developed to determine the upper hybrid resonance frequency, fuhr, from electric field measurements, which is then used to calculate the electron number density. In previous missions, the plasma resonance bands were manually identified, and there have been few attempts to do robust, routine automated detection. We describe the design and implementation of the algorithm and perform initial analysis of the resulting electron number density distribution obtained by applying NURD to 2.5 years of data collected with the EMFISIS instrumentation suite of the Van Allen Probes mission. Densities obtained by NURD are compared to those obtained by another recently developed automated technique and also to an existing empirical plasmasphere and trough density model.

  17. Automated determination of electron density from electric field measurements on the Van Allen Probes spacecraft

    NASA Astrophysics Data System (ADS)

    Zhelavskaya, I. S.; Spasojevic, M.; Shprits, Y. Y.; Kurth, W. S.

    2016-05-01

    We present the Neural-network-based Upper hybrid Resonance Determination (NURD) algorithm for automatic inference of the electron number density from plasma wave measurements made on board NASA's Van Allen Probes mission. A feedforward neural network is developed to determine the upper hybrid resonance frequency, fuhr, from electric field measurements, which is then used to calculate the electron number density. In previous missions, the plasma resonance bands were manually identified, and there have been few attempts to do robust, routine automated detections. We describe the design and implementation of the algorithm and perform an initial analysis of the resulting electron number density distribution obtained by applying NURD to 2.5 years of data collected with the Electric and Magnetic Field Instrument Suite and Integrated Science (EMFISIS) instrumentation suite of the Van Allen Probes mission. Densities obtained by NURD are compared to those obtained by another recently developed automated technique and also to an existing empirical plasmasphere and trough density model.

  18. Van Allen Probe Spacecraft Potential Fluctuations and Electromagnetic Waves: A Parameter Space Survey

    NASA Astrophysics Data System (ADS)

    Sturner, A. P.; Ergun, R.; Malaspina, D.

    2013-12-01

    The study of chorus waves, an important mechanism for the energization and loss of particles in the radiation belts and inner magnetosphere, has been significantly aided by observations of fluctuations in a spacecraft's potential, which have been shown to be correlated with plasma density structures. However, recent analysis of Van Allen Probe data suggests that the oscillatory electromagnetic fields of chorus waves may also induce spacecraft potential fluctuations via enhanced photoelectron escape, calling into question our understanding of chorus waves. We use a fully 3D particle tracing simulation to study the equilibrium potential of a model Van Allen Probe spacecraft under various plasma conditions, varying thermal temperature, electric and magnetic field strength, plasma density, etc., to better understand the parameter space under which enhanced photoelectron escape becomes important.

  19. Electron acceleration in the heart of the Van Allen radiation belts.

    PubMed

    Reeves, G D; Spence, H E; Henderson, M G; Morley, S K; Friedel, R H W; Funsten, H O; Baker, D N; Kanekal, S G; Blake, J B; Fennell, J F; Claudepierre, S G; Thorne, R M; Turner, D L; Kletzing, C A; Kurth, W S; Larsen, B A; Niehof, J T

    2013-08-30

    The Van Allen radiation belts contain ultrarelativistic electrons trapped in Earth's magnetic field. Since their discovery in 1958, a fundamental unanswered question has been how electrons can be accelerated to such high energies. Two classes of processes have been proposed: transport and acceleration of electrons from a source population located outside the radiation belts (radial acceleration) or acceleration of lower-energy electrons to relativistic energies in situ in the heart of the radiation belts (local acceleration). We report measurements from NASA's Van Allen Radiation Belt Storm Probes that clearly distinguish between the two types of acceleration. The observed radial profiles of phase space density are characteristic of local acceleration in the heart of the radiation belts and are inconsistent with a predominantly radial acceleration process.

  20. Portrait of an instrument-maker:Wenceslaus Hollar's engraving of Elias Allen.

    PubMed

    Higton, Hester

    2004-06-01

    Among the many engravings of landscapes, buildings, portraits and other illustrations produced by the seventeenth-century artist Wenceslaus Hollar, there are a small number of images of contemporary men of science. Of particular interest is the portrait of the instrument-maker Elias Allen, both because portraits of men of his social status were extremely uncommon at this time, and also because the cluttered mass of instruments shown in the image presents a picture wholly unlike other portraits of the period. The first part of this paper explores the position of portraiture as inherently linked to nobility, and seeks to present an explanation as to why the original oil painting of Allen (made by Hendrik van der Borcht and no longer extant) might have been made. The second part looks at the image itself, and discusses possible reasons for Hollar's production of the engraving some twenty years after the original.

  1. Gold-catalyzed intramolecular [3+2] cycloadditions of 1-aryl-1-allene-6-enes.

    PubMed

    Chaudhuri, Rupsha; Liao, Hsin-Yi; Liu, Rai-Shung

    2009-09-01

    Treatment of 1-aryl-1-allen-6-enes with [PPh(3)AuCl]/AgSbF(6) (5 mol %) in CH(2)Cl(2) at 25 degrees C led to intramolecular [3+2] cycloadditions, giving cis-fused dihydrobenzo[a]fluorene products efficiently and selectively. The reactions proceeded with initial formation of trans/cis mixtures of 2-alkyl-1-isopropyl-2-phenyl-1,2-dihydronaphthalene cations B, which were convertible into the desired cis-fused cycloadducts through the combined action of a gold catalyst and a Brønsted acid. Theoretic calculation supports the participation of the trans-B cation as reaction intermediate. Although HOTf showed similar activity towards several 1-aryl-1-allen-6-enes, it lacks generality for this cycloaddition reaction.

  2. Cycloaddition reactions of allenes with N-phenylmaleimide. A two-step, diradical-intermediate process

    SciTech Connect

    Pasto, D.J.; Heid, P.F.; Warren, S.E.

    1982-06-30

    The stereoselectivities, chemoselectivities, relative reactivities, and kinetic isotope effects have been determined in the cycloaddition reactions of substituted allenes with N-phenylmaleimide. The comparison of these results with those derived from the studies of the cycloaddition of 1,1-dichloro-2,2-difluoroethene and the radical-chain addition of benzenethiol to allenes strongly indicates that the cycloadditions with N-phenylmaleimide occur via a two-step, diradical-intermediate process. The stereochemical features controlling the formation of the stereoisomeric diradical intermediates and their ring closures are discussed. In addition to the cycloaddition processes, competitive ene reactions occur to produce intermediate dienes, which react further to produce 1:2 adducts or nonreactive alkyne-containing 1:1 adducts. These ene reactions also appear to proceed via diradical intermediates.

  3. National uranium resource evaluation: McAllen and Brownsville Quadrangles, Texas

    SciTech Connect

    Charepon, A J; Stauber, A J

    1982-06-01

    The McAllen and Brownsville Quadrangles, Texas, were evaluated to a depth of 1500 m to identify geologic environments and delineate areas favorable for uranium deposits. The environments were selected according to criteria established for the National Uranium Resource Evaluation program. Surface studies included investigations of uranium occurrences described in the literature, of locations of aerial radiometric anomalies, of surface exposures, and of locations of anomalous hydrogeochemical and stream-sediment reconnaissance data and collation of information on uranium exploration. Subsurface evaluation of selected geologic units was accomplished by using electric and gamma-ray well logs to construct maps and construct maps and cross sections. In the McAllen Quadrangle, an environment favorable for Texas roll-type sandstone uranium deposits is identified in 36 areas in the Goliad, Fleming-Oakville, Catahoula-Frio, and Whitsett Formations. All other units in both quadrangles are considered unfavorable.

  4. New Optical Sensor Suite for Ultrahigh Temperature Fossil Fuel Application

    SciTech Connect

    John Coggin; Tom Flynn; Jonas Ivasauskas; Daniel Kominsky; Carrie Kozikowski; Russell May; Michael Miller; Tony Peng; Gary Pickrell; Raymond Rumpf; Kelly Stinson-Bagby; Dan Thorsen; Rena Wilson

    2007-12-31

    Accomplishments of a program to develop and demonstrate photonic sensor technology for the instrumentation of advanced powerplants and solid oxide fuel cells are described. The goal of this project is the research and development of advanced, robust photonic sensors based on improved sapphire optical waveguides, and the identification and demonstration of applications of the new sensors in advanced fossil fuel power plants, where the new technology will contribute to improvements in process control and monitoring.

  5. Spectroscopic studies of wood fossils from the Crato Formation, Cretaceous Period.

    PubMed

    da Silva, J H; Freire, P T C; Abagaro, B T O; Silva, J A F; Saraiva, G D; de Lima, F J; Barros, O A; Bantim, R A; Saraiva, A A F; Viana, B C

    2013-11-01

    In this work we study two types of wood fossils (Gymnosperms, Araucariaceae) from the Crato Formation of Araripe Basin in Brazil, from the Cretaceous Period. The samples were characterized by Raman and infrared spectroscopies, X-ray diffraction and scanning electron microscopy. The results obtained by different techniques showed that although the rocks surrounding the fossils have predominantly the same constitution - calcite - however, the formation processes of these types of wood fossils are quite different. One of the fossils, denominated as light wood, is predominantly composed of gypsum, while the other fossil, the dark wood, is rich in amorphous carbon, possibly the kerogen type. Implications relative to the environment where the plants lived millions years ago are also given. Finally, the results highlight the constitution of one of the most important paleontological sites of the Cretaceous Period in the South America.

  6. Spectroscopic studies of wood fossils from the Crato Formation, Cretaceous Period.

    PubMed

    da Silva, J H; Freire, P T C; Abagaro, B T O; Silva, J A F; Saraiva, G D; de Lima, F J; Barros, O A; Bantim, R A; Saraiva, A A F; Viana, B C

    2013-11-01

    In this work we study two types of wood fossils (Gymnosperms, Araucariaceae) from the Crato Formation of Araripe Basin in Brazil, from the Cretaceous Period. The samples were characterized by Raman and infrared spectroscopies, X-ray diffraction and scanning electron microscopy. The results obtained by different techniques showed that although the rocks surrounding the fossils have predominantly the same constitution - calcite - however, the formation processes of these types of wood fossils are quite different. One of the fossils, denominated as light wood, is predominantly composed of gypsum, while the other fossil, the dark wood, is rich in amorphous carbon, possibly the kerogen type. Implications relative to the environment where the plants lived millions years ago are also given. Finally, the results highlight the constitution of one of the most important paleontological sites of the Cretaceous Period in the South America. PMID:23856041

  7. Reactions of two-coordinate phosphines with acetylenes: Synthesis of new allenic and acetylenic phosphines

    SciTech Connect

    Angelov, C.M.; Neilson, R.H. )

    1993-02-03

    The two-coordinate phosphines (Me[sub 3]Si)[sub 2]NP[double bond]ESiMe[sub 3] (1, E = N; 2, E = CH) reacted smoothly with 2-butyne via an ene process (instead of the expected cycloaddition reaction) to give the novel allenic phosphines H[sub 2]C[double bond]C[double bond]C(CH[sub 3])P[E(H)SiMe[sub 3

  8. Cooperative, highly enantioselective phosphinothiourea catalysis of imine-allene [3 + 2] cycloadditions.

    PubMed

    Fang, Yuan-Qing; Jacobsen, Eric N

    2008-04-30

    A new family of phosphinthiourea catalysts was developed for the highly enantioselective synthesis of 2-aryl-2,5-hydropyrroles via a [3 + 2] cycloaddition of an electron-deficient allene with aryl and heteroaryl diphenylphosphinoylimines. The presence of both H2O and Et3N as additives was found to be important for achieving optimal rates. Dual activation of both nucleophile and electrophile by the bifunctional catalyst is invoked to account for the observed high reactivity and enantioselectivity.

  9. The rα structure of allene: a study of solvent effects in NMR of oriented molecules

    NASA Astrophysics Data System (ADS)

    Diehl, P.; Baraldi, C.; Kellerhals, M.; Wasser, R.

    1987-11-01

    NMR spectra of partially oriented allene in 14 different liquid crystal solvents have been analyzed. The resulting direct couplings corrected for harmonic vibrations were used to determine the rα-structures. Considerable solvent effects were detected which disappeared, if the data were corrected also for the correlated molecule deformation. A solvent independent rα-structure which agreed well with IR results, and the interaction parameters of the CH and CC bonds of allene for all the solvents were determined.

  10. Gradual Diffusion and Punctuated Phase Space Density Enhancements of Highly Relativistic Electrons: Van Allen Probes Observations

    NASA Technical Reports Server (NTRS)

    Baker, D. N.; Jaynes, A. N.; Li, X.; Henderson, M. G.; Kanekal, S. G.; Reeves, G. D.; Spence, H. E.; Claudepierre, S. G.; Fennell, J. F.; Hudson, M. K.

    2014-01-01

    The dual-spacecraft Van Allen Probes mission has provided a new window into mega electron volt (MeV) particle dynamics in the Earth's radiation belts. Observations (up to E (is) approximately 10MeV) show clearly the behavior of the outer electron radiation belt at different timescales: months-long periods of gradual inward radial diffusive transport and weak loss being punctuated by dramatic flux changes driven by strong solar wind transient events. We present analysis of multi-MeV electron flux and phase space density (PSD) changes during March 2013 in the context of the first year of Van Allen Probes operation. This March period demonstrates the classic signatures both of inward radial diffusive energization and abrupt localized acceleration deep within the outer Van Allen zone (L (is) approximately 4.0 +/- 0.5). This reveals graphically that both 'competing' mechanisms of multi-MeV electron energization are at play in the radiation belts, often acting almost concurrently or at least in rapid succession.

  11. Van Allen Probes: Successful launch campaign and early operations exploring Earth's radiation belts

    NASA Astrophysics Data System (ADS)

    Kirby, K.; Stratton, J.

    The twin Van Allen Probe observatories developed at The Johns Hopkins University Applied Physics Laboratory for NASA's Heliophysics Division completed final observatory integration and environmental test activities and were successfully launched into orbit around the Earth on August 30, 2012. As the science operations phase begins, the mission is providing exciting new information about the impact of radiation belt activity on the earth. The on-board boom mounted magnetometers and other instruments are the most sensitive sensors of their type that have ever flown in the Van Allen radiation belts. The observatories are producing near-Earth space weather information that can be used to provide warnings of potential power grid interruptions or satellite damaging storms. The Van Allen Probes are operating in a challenging high radiation environment, and at the same time they are designed to make an insubstantial electric and magnetic field contribution to their surroundings. This paper will describe the challenges associated with observatory integration and test activities and observatory on-orbit checkout and commissioning. The lessons learned can be applied to other observatories and payloads that will be exposed to similar environments.

  12. Three acoustic forms of Allen's galagos (primates; Galagonidae) in the Central African region.

    PubMed

    Ambrose, Lesley

    2003-01-01

    This study identifies populations currently classified as Allen's galago (Galago alleni) at ten locations in Gabon, Cameroon and Bioko Island. Morphological diversity was evident both within and between populations. Attention to the loud calls revealed three distinct vocal profiles which are consistent within biogeographical regions. This work is based on the Recognition Concept of Species which refers to a Specific Mate Recognition System. Galagos rely less on visual signals than diurnal primates and recognise each other principally by means of auditory and olfactory signals. Galagos possess repertoires of loud calls relating to contact and alarm which are thought to be species-specific. Other studies of nocturnal prosimians (galagos, tarsiers) have demonstrated that the unique loud call repertoires are reliable indicators of species boundaries; whereas characters such as body size and pelage coloration are highly variable, even within populations. The vocal data in this study provide evidence of at least three acoustic forms of galago within the Allen's group which are predicted to represent three distinct species: the Allen's form on Bioko Island and south-west Cameroon, the Gabon form in southern Cameroon and northern Gabon and the Makandé form in Gabon south of the Ogooué river. Some populations may be vulnerable to extinction due to limited distributions and habitat destruction.

  13. Radition belt dynamics : Recent results from van Allen Probes and future observations from CeREs

    NASA Astrophysics Data System (ADS)

    Kanekal, Shrikanth; O'Brien, Paul; Baker, Daniel N.; Ogasawara, Keiichi; Fennell, Joseph; Christian, Eric; Claudepierre, Seth; Livi, Stefano; Desai, Mihir; Li, Xinlin; Jaynes, Allison; Turner, Drew; Jones, Ashley; Schiller, Quintin

    2016-07-01

    We describe recent observations of the Earth's radiation belts made by instruments on board the Van Allen Probes mission, particularly the Relativistic Electron Proton Telescope (REPT) and the Magnetic Electron Ion spectrometer (MagEIS). These observations have significantly advanced our understanding of terrestrial radiation belt dynamics. The Van Allen Probes mission comprises two identically instrumented spacecraft which were launched 31 August, 2012 into low-inclination lapping equatorial orbits. The orbit periods are about 9 hours, with perigees and apogees of of ~600 km and 5.8 RE respectively. We discuss the new scientific findings of the Van Allen Probes mission regarding the physics of energization and loss of relativistic electrons and their implications for future low-cost missions, especially CubeSats. We describe the CeREs (a Compact Radiation belt Explorer) CubeSat mission currently being built at the Goddard Space Flight Center, and carrying on board, an innovative instrument, the Miniaturized Electron Proton Telescope (MERiT). The MERiT is a compact low-mass low-power instrument measuring electrons from a few keV to tens of MeV in multiple differential channels. MERiT is optimized to measure electron microbursts with a high time resolution of a few milliseconds. We present and discuss possible future scientific contributions from CeREs.

  14. New Insight Into the Nightside Magnetosphere Ion Plasma Regimes With the Van Allen Probes

    NASA Astrophysics Data System (ADS)

    Jahn, J.; Goldstein, J.; Reeves, G. D.; Spence, H.; Skoug, R. M.; Funsten, H. O.

    2013-12-01

    The recent successful launch of the twin Van Allen spacecraft (formerly known as RBSP) provides a new and unprecedented window into the structure and dynamics of inner magnetospheric plasma content and dynamics. The equatorially orbiting Van Allen spacecraft are returning clean, high resolution, very low background ion composition and electron plasma data throughout the radiation belt and ring current region inside geosynchronous orbit. Since both Van Allen spacecraft are positioned in near-identical chase orbits, lapping each other continuously throughout the mission, we are able to study both spatial and temporal variability in the inner magnetosphere with unprecedented resolution on a range of time and length scales. In this paper we present initial results from plasma composition measurements in the nightside of Earth's magnetosphere, focusing on plasma fractional plasma composition of H+, He+, and O+ in the plasmasphere through lower ring current energies (< 50 keV). Early results indicate a remarkable spatial and temporal variability in plasma ion composition in the inner magnetosphere. We detect frequent occurrences of multiple peak energy distributions in this energy range occurring in ring current, plasmasphere and plasma sheet. We observe distinct differences between the three ion species in these spectra. Energy spectra with 5 peaks for a single species have been observed repeatedly. We discuss possible explanations for these observations, and possible ramifications for the evolution of the outer radiation belt.

  15. The Van Allen Probes first year of discovery and understanding (Invited)

    NASA Astrophysics Data System (ADS)

    Mauk, B.; Fox, N. J.; Sibeck, D. G.; Kanekal, S. G.; Kessel, R.

    2013-12-01

    The Van Allen Probes twin spacecraft were launched on 30 August 2012 and inserted into nearly identical, 1.1 x 5.8 RE elliptical, low inclination (10°), 9-hour period Earth orbits with one of the two spacecraft lapping the other about every 2.5 months. The discoveries and understandings achieved by the Van Allen Probes science investigations since the operational mission began on 1 November 2012 are all that we had hoped. The probes are discovering new and unanticipated behaviors of the radiation belts, for example coherently ordered multiple structures, and are revealing quantitatively how and why those behaviors occur. The probes are answering definitely outstanding important questions regarding Earth's inner magnetosphere, for example, the extent to which and the processes by which local acceleration contributes to creation of the belts. With its close 2-month coordination with the BARREL mission of opportunity array of Antarctic balloons, the Probes are contributing greatly to our understanding of the causes of radiation belt loss and the relationship between high and low altitude radiation belt phenomena. In this overview presentation we assess the discoveries and findings of the Van Allen Probes mission following its first year of operation, and provide a guide to the activities and achievements anticipated over the next year.

  16. New Insight into the Inner Magnetosphere Plasma Regimes with the van Allen Probes (RBSP)

    NASA Astrophysics Data System (ADS)

    Jahn, Joerg-Micha; Denton, Richard E.; Funsten, Herbert O.; Reeves, Geoff; Spence, Harlan E.

    2013-04-01

    The recent successful launch of the twin van Allen spacecraft (formerly known as RBSP) provides a new and unprecedented window into the structure and dynamics of inner magnetospheric plasma content and dynamics. The equatorially orbiting van Allen spacecraft are returning clean high resolution, very low background ion composition and electron plasma data throughout the radiation belt and ring current region inside geosynchronous orbit. Since both van Allen spacecraft are positioned in near-identical chase orbits, lapping each other continuously throughout the mission, we are able to study both spatial and temporal variability in the inner magnetosphere with unprecedented resolution on a range of time and length scales. In this paper we are presenting initial results from plasma composition measurements in the nightside of Earth's magnetosphere, focussing on plasma fractional plasma composition of H+, He+, and O+ in the plasmasphere through lower ring current energies (< 50 keV). Early results do not only indicate a remarkable spatial and temporal variability in plasma ion composition in the inner magnetosphere, they also show frequent occurrences of multiple peak energy distributions in this energy range. Multi-peaked energy distributions with several peaks occurring in ring current, plasmasphere and (less often) plasma sheet are frequently observed, with distinct differences between the three ion species. Energy spectra with 5-6 peaks for a single species have been observed repeatedly.

  17. Enhancements and Losses of Radiation Belt Particles: Van Allen Probes Observations

    NASA Astrophysics Data System (ADS)

    Baker, D. N.

    2015-12-01

    The dual-spacecraft Van Allen Probes mission has provided a new window into megaelectron Volt (MeV) particle dynamics in the Earth's radiation belts. Observations (up to E ~10 MeV) show clearly the behavior of the outer electron radiation belt at different time scales: months-long periods of gradual inward radial diffusive transport and weak loss being punctuated by dramatic flux changes driven by strong solar wind transient events. Analysis of multi-MeV electron flux and phase space density (PSD) changes during key intervals in March 2013 and March 2015 are presented in the context of the first three years of Van Allen Probes operation. These March periods demonstrate the classic signatures both of inward radial diffusive energization as well as abrupt localized acceleration deep within the outer Van Allen zone (L ~4.0±0.5). Such results reveal graphically that both "competing" mechanisms of multi-MeV electron energization are at play in the radiation belts, often acting almost concurrently or at least in very rapid succession. They also show in remarkable ways how the coldest plasmas in the magnetosphere intimately control the most highly energetic particles.

  18. Observation of plasma depletions in outer radiation belt by Van Allen Probes

    NASA Astrophysics Data System (ADS)

    Lee, J.; Kim, K.; Lee, E.; Kim, Y.; Park, Y.; Parks, G. K.; Sibeck, D. G.

    2013-12-01

    Van Allen Probes (RBSP) observed plasma fine structures in the outer radiation belt during storm time on 14 November 2012. Five plasma depletion regions are clearly identified by VAP_A and VAP_B from 02:00UT to 04:45UT by particle instrument suite that can measure electrons and ions in a wide energy range, from 20 eV to 10 MeV. The plasma flux density dramatically decreases about 2 - 3 orders of magnitude in the depletion regions regardless of energy and particle species. Our analysis shows the plasma cavities are formed at the boundary of trapped and injected particle current. The total plasma pressures inside the depletion regions are much smaller than outside, implying unstable structures. It seems that this structures appear unusually only for storm main phase. During strong storm event, geomagnetic field is stretched and low plasma density region (lobe) moves to low latitude, this event could be analyzed by lobe region crossing of spacecraft. However, to explain temporal sequences of this event, we should assume large fluctuation of lobe boundary. Another possible analysis is plasma bubble generated in the tail region. The bubble model proposed to explain plasma transportation form tail to near Earth region in 1980s. While the bubble model reasonably explain the spatial and temporal structures observed by Van Allen probes, we cannot completely rule out the lobe region crossing model. In this presentation, we shall discuss about the characteristics of the plasma density cavities first observed by Van Allen Probes.

  19. A neural network approach for identifying particle pitch angle distributions in Van Allen Probes data

    NASA Astrophysics Data System (ADS)

    Souza, V. M.; Vieira, L. E. A.; Medeiros, C.; Da Silva, L. A.; Alves, L. R.; Koga, D.; Sibeck, D. G.; Walsh, B. M.; Kanekal, S. G.; Jauer, P. R.; Rockenbach, M.; Dal Lago, A.; Silveira, M. V. D.; Marchezi, J. P.; Mendes, O.; Gonzalez, W. D.; Baker, D. N.

    2016-04-01

    Analysis of particle pitch angle distributions (PADs) has been used as a means to comprehend a multitude of different physical mechanisms that lead to flux variations in the Van Allen belts and also to particle precipitation into the upper atmosphere. In this work we developed a neural network-based data clustering methodology that automatically identifies distinct PAD types in an unsupervised way using particle flux data. One can promptly identify and locate three well-known PAD types in both time and radial distance, namely, 90° peaked, butterfly, and flattop distributions. In order to illustrate the applicability of our methodology, we used relativistic electron flux data from the whole month of November 2014, acquired from the Relativistic Electron-Proton Telescope instrument on board the Van Allen Probes, but it is emphasized that our approach can also be used with multiplatform spacecraft data. Our PAD classification results are in reasonably good agreement with those obtained by standard statistical fitting algorithms. The proposed methodology has a potential use for Van Allen belt's monitoring.

  20. Allen Brain Atlas-Driven Visualizations: a web-based gene expression energy visualization tool.

    PubMed

    Zaldivar, Andrew; Krichmar, Jeffrey L

    2014-01-01

    The Allen Brain Atlas-Driven Visualizations (ABADV) is a publicly accessible web-based tool created to retrieve and visualize expression energy data from the Allen Brain Atlas (ABA) across multiple genes and brain structures. Though the ABA offers their own search engine and software for researchers to view their growing collection of online public data sets, including extensive gene expression and neuroanatomical data from human and mouse brain, many of their tools limit the amount of genes and brain structures researchers can view at once. To complement their work, ABADV generates multiple pie charts, bar charts and heat maps of expression energy values for any given set of genes and brain structures. Such a suite of free and easy-to-understand visualizations allows for easy comparison of gene expression across multiple brain areas. In addition, each visualization links back to the ABA so researchers may view a summary of the experimental detail. ABADV is currently supported on modern web browsers and is compatible with expression energy data from the Allen Mouse Brain Atlas in situ hybridization data. By creating this web application, researchers can immediately obtain and survey numerous amounts of expression energy data from the ABA, which they can then use to supplement their work or perform meta-analysis. In the future, we hope to enable ABADV across multiple data resources.

  1. An Impenetrable Barrier to Ultra-Relativistic Electrons in the Van Allen Radiation Belt

    NASA Astrophysics Data System (ADS)

    Baker, Daniel

    2015-04-01

    Early observations indicated that the Earth's Van Allen belts could be delineated into an inner zone dominated by high energy protons and an outer zone dominated by high energy electrons. Subsequent studies showed that moderate-energy electrons (E≲1 MeV) often populate both zones with a deep "slot" region between them. This two-belt structure was explained as being due to strong electron interactions with plasmaspheric hiss just inside the plasmapause boundary with the inner edge of the outer zone corresponding to the minimum plasmapause location. Recent Van Allen Probes observations have revealed unexpected radiation belt morphology, especially at ultra-relativistic (E > 5 MeV) kinetic energies. Here we discuss an exceedingly sharp inner boundary exists for ultra-relativistic electrons. Concurrent data reveal that this barrier for inward electron radial transport is not due to a physical boundary within Earth's intrinsic magnetic field nor is it likely that scattering by human-generated electromagnetic transmitter wave fields would inhibit inward radial diffusion. Rather, we suggest that exceptionally slow natural inward radial diffusion combined with weak, but persistent, wave-particle pitch angle scattering deep inside the Earth's plasmasphere can conspire to create an almost impenetrable barrier through which the most energetic Van Allen belt electrons cannot migrate.

  2. Determination of fossil carbon content in Swedish waste fuel by four different methods.

    PubMed

    Jones, Frida C; Blomqvist, Evalena W; Bisaillon, Mattias; Lindberg, Daniel K; Hupa, Mikko

    2013-10-01

    This study aimed to determine the content of fossil carbon in waste combusted in Sweden by using four different methods at seven geographically spread combustion plants. In total, the measurement campaign included 42 solid samples, 21 flue gas samples, 3 sorting analyses and 2 investigations using the balance method. The fossil carbon content in the solid samples and in the flue gas samples was determined using (14)C-analysis. From the analyses it was concluded that about a third of the carbon in mixed Swedish waste (municipal solid waste and industrial waste collected at Swedish industry sites) is fossil. The two other methods (the balance method and calculations from sorting analyses), based on assumptions and calculations, gave similar results in the plants in which they were used. Furthermore, the results indicate that the difference between samples containing as much as 80% industrial waste and samples consisting of solely municipal solid waste was not as large as expected. Besides investigating the fossil content of the waste, the project was also established to investigate the usability of various methods. However, it is difficult to directly compare the different methods used in this project because besides the estimation of emitted fossil carbon the methods provide other information, which is valuable to the plant owner. Therefore, the choice of method can also be controlled by factors other than direct determination of the fossil fuel emissions when considering implementation in the combustion plants.

  3. Fossil evidence for the early ant evolution

    NASA Astrophysics Data System (ADS)

    Perrichot, Vincent; Lacau, Sébastien; Néraudeau, Didier; Nel, André

    2008-02-01

    Ants are one of the most studied insects in the world; and the literature devoted to their origin and evolution, systematics, ecology, or interactions with plants, fungi and other organisms is prolific. However, no consensus yet exists on the age estimate of the first Formicidae or on the origin of their eusociality. We review the fossil and biogeographical record of all known Cretaceous ants. We discuss the possible origin of the Formicidae with emphasis on the most primitive subfamily Sphecomyrminae according to its distribution and the Early Cretaceous palaeogeography. And we review the evidence of true castes and eusociality of the early ants regarding their morphological features and their manner of preservation in amber. The mid-Cretaceous amber forest from south-western France where some of the oldest known ants lived, corresponded to a moist tropical forest close to the shore with a dominance of gymnosperm trees but where angiosperms (flowering plants) were already diversified. This palaeoenvironmental reconstruction supports an initial radiation of ants in forest ground litter coincident with the rise of angiosperms, as recently proposed as an ecological explanation for their origin and successful evolution.

  4. Fossil wood from the Miocene and Oligocene epoch: chemistry and morphology.

    PubMed

    Bardet, Michel; Pournou, Anastasia

    2015-01-01

    Fossil wood is the naturally preserved remain of the secondary xylem of plants that lived before the Holocene epoch. Typically, fossil wood is preserved as coalified or petrified and rarely as mummified tissue. The process of fossilization is very complex and it is still unknown why in the same fossil record, wood can be found in different fossilisation forms. In 2007, a fossil forest was found in the Bükkábrány open-pit coal mine in Hungary. The non-petrified forest is estimated to be 7 million years old (Miocene epoch) and its trees were found standing in an upright position. This fossil assemblage is exceptionally rare because wood has been preserved as soft waterlogged tissue. This study aimed to investigate this remarkable way of fossil wood preservation, by examining its chemistry with (13)C CPMAS NMR and its morphology with light and electron microscopy. For comparison reasons, a petrified wood trunk from the Oligocene epoch (30 Myr) found in 2001 at Porrentruy region in Switzerland and two fresh wood samples of the modern equivalents of the Miocene sample were also examined. The results obtained showed that the outstanding preservation state of the Miocene fossil is not owed to petrification or coalification. Mummification is a potential mechanism that could explain Bükkábrány trunks' condition, however this fossilisation process is not well studied and therefore this hypothesis needs to be further investigated. PMID:25294390

  5. Geoscience Outreach Activity Using Art to Understand Imprint Fossils Engaging K-5 Students

    NASA Astrophysics Data System (ADS)

    Derrick, E. R.

    2015-12-01

    In order to engage students in grades 3 through 5 in the geosciences, a hands on science activity was developed and implemented using art as a mechanism to gain knowledge of imprint fossils. The desired learning outcomes of this activity were for students to understand imprint fossils formation and how these fossils can be used to learn about past organisms. For more advanced students, an additional learning outcome was to understand how fossils provide information about depositional environments. Five graduate and undergraduate student volunteers presented imprint fossils and used a game to connect the fossils with the corresponding organisms. Students then made their own imprint fossils using modeling clay, plants, and plastic dinosaur skeletons. Of the 212 participating students, 95% (201) of students completed the hands on activity successfully and reported a knowledge gain in the formation and significance of imprint fossils. The activity was adapted to accommodate a diverse student population across grade and ability levels. Classroom teachers reported incorporating students' art into further classroom learning and requested this activity to be repeated the following year by the outreach group.

  6. [A study on Horace N. Allen's medicine and recognition of Korean body].

    PubMed

    Lee, Young Ah

    2011-12-31

    Je Jung Won was the first modern-style Government hospital built by the Korean King Ko-Jong in April 1885, and it was the medical missionary Horace Newton Allen(1858~1932) who made one of the greatest contributions to the establishment of the hospital. Allen was an American missionary. He graduated from Ohio Wesleyan University with a degree in theology in 1881, and completed one-yearcourse at Miami Medical College. In Korea and America he worked as a physician, a missionary, an American diplomatic minister to Korea and a Korean minister's secretary to America. While acting as a mediator between Korea and America, he knew and recorded the domestic and foreign situation of Korea during Gaehwagi(the civilized and enlightened age). Thus to study him is to understand Korea's Gaehwagi as well as to research American medical missionaries. During his stay in Korea(1884~1905), Allen steadily wrote diaries and letters about Korean politics, diplomacy, society, culture, and medicine. Thus his public/private record through diaries and letters(the quantity of these materials amounts to several thousands) supplements the Korean early modern era's historical record. However, until now these materials have received little scholarly attention from researchers except for a few historians of missionary work between Korea and America, or of Korean modern medicine. I intended to use these materials to suggest a new perspective on the study of Korean Gaehwagi. Allen, along with John W. Heron, who came to Seoul on June 21st 1885, treated about 10,460 Korean patients in the first year of the opening of JeJungWon. They made "the first annual report of the Korean Government Hospital". This report explained how Allen and Heron regarded and treated Korean patients. Allen's diaries, letters and other writings offer a realistic view of how the western people actually recognized the Korean people at that time. As a western doctor, Allen had an ambivalent attitude toward Korean medical concepts

  7. [A study on Horace N. Allen's medicine and recognition of Korean body].

    PubMed

    Lee, Young Ah

    2011-12-31

    Je Jung Won was the first modern-style Government hospital built by the Korean King Ko-Jong in April 1885, and it was the medical missionary Horace Newton Allen(1858~1932) who made one of the greatest contributions to the establishment of the hospital. Allen was an American missionary. He graduated from Ohio Wesleyan University with a degree in theology in 1881, and completed one-yearcourse at Miami Medical College. In Korea and America he worked as a physician, a missionary, an American diplomatic minister to Korea and a Korean minister's secretary to America. While acting as a mediator between Korea and America, he knew and recorded the domestic and foreign situation of Korea during Gaehwagi(the civilized and enlightened age). Thus to study him is to understand Korea's Gaehwagi as well as to research American medical missionaries. During his stay in Korea(1884~1905), Allen steadily wrote diaries and letters about Korean politics, diplomacy, society, culture, and medicine. Thus his public/private record through diaries and letters(the quantity of these materials amounts to several thousands) supplements the Korean early modern era's historical record. However, until now these materials have received little scholarly attention from researchers except for a few historians of missionary work between Korea and America, or of Korean modern medicine. I intended to use these materials to suggest a new perspective on the study of Korean Gaehwagi. Allen, along with John W. Heron, who came to Seoul on June 21st 1885, treated about 10,460 Korean patients in the first year of the opening of JeJungWon. They made "the first annual report of the Korean Government Hospital". This report explained how Allen and Heron regarded and treated Korean patients. Allen's diaries, letters and other writings offer a realistic view of how the western people actually recognized the Korean people at that time. As a western doctor, Allen had an ambivalent attitude toward Korean medical concepts

  8. Fossil energy program. Summary document

    SciTech Connect

    1980-05-01

    This program summary document presents a comprehensive overview of the research, development, and demonstration (RD and D) activities that will be performed in FY 1981 by the Assistant Secretary for Fossil Energy (ASFE), US Department of Energy (DOE). The ASFE technology programs for the fossil resources of coal, petroleum (including oil shale) and gas have been established with the goal of making substantive contributions to the nation's future supply and efficienty use of energy. On April 29, 1977, the Administration submitted to Congress the National Energy Plan (NEP) and accompanying legislative proposals designed to establish a coherent energy policy structure for the United States. Congress passed the National Energy Act (NEA) on October 15, 1978, which allows implementation of the vital parts of the NEP. The NEP was supplemented by additional energy policy statements culminating in the President's address on July 15, 1979, presenting a program to further reduce dependence on imported petroleum. The passage of the NEA-related energy programs represent specific steps by the Administration and Congress to reorganize, redirect, and clarify the role of the Federal Government in the formulation and execution of national energy policy and programs. The energy technology RD and D prog4rams carried out by ASFE are an important part of the Federal Government's effort to provide the combination and amounts of energy resources needed to ensure national security and continued economic growth.

  9. Evolutionary timescale of monocots determined by the fossilized birth-death model using a large number of fossil records.

    PubMed

    Eguchi, Satoshi; Tamura, Minoru N

    2016-05-01

    Although the phylogenetic relationships between monocot orders are sufficiently understood, a timescale of their evolution is needed. Several studies on molecular clock dating are available, but their results have been biased by their calibration schemes. Recently, the fossilized birth-death model, a type of Bayesian dating method, was proposed, and it does not require prior calibration and allows the use all available fossils. Using this model, we conducted divergence-time estimations of monocots to explore their evolutionary timeline without calibration bias. This is the first application of this model to seed plants. The dataset contained the matK and rbcL chloroplast genes of 118 monocot genera covering all extant orders. We employed information from 247 monocot fossils, which exceeded previous dating analyses that used a maximum of 12 monocot fossils. The crown group of monocots was dated to approximately the Late Jurassic-Early Cretaceous periods, and most extant monocot orders were estimated to diverge throughout the Early Cretaceous. Our results overlapped with the divergence time of insect lineages, such as beetles and flies, suggesting an association with pollinators in early monocot evolution. In addition, we proposed three new orders based on divergence time: Orchidales separated from Asparagales and Tofieldiales and Arales separated from Aslimatales. PMID:27061096

  10. Fossil energy biotechnology: A research needs assessment

    NASA Astrophysics Data System (ADS)

    1993-11-01

    The Office of Program Analysis of the U.S. Department of Energy commissioned this study to evaluate and prioritize research needs in fossil energy biotechnology. The objectives were to identify research initiatives in biotechnology that offer timely and strategic options for the more efficient and effective uses of the Nation's fossil resource base, particularly the early identification of new and novel applications of biotechnology for the use or conversion of domestic fossil fuels. Fossil energy biotechnology consists of a number of diverse and distinct technologies, all related by the common denominator -- biocatalysis. The expert panel organized 14 technical subjects into three interrelated biotechnology programs: (1) upgrading the fuel value of fossil fuels; (2) bioconversion of fossil feedstocks and refined products to added value chemicals; and (3) the development of environmental management strategies to minimize and mitigate the release of toxic and hazardous petrochemical wastes.

  11. Fossilization Processes in Thermal Springs

    NASA Technical Reports Server (NTRS)

    Farmer, Jack D.; Cady, Sherry; Desmarais, David J.; Chang, Sherwood (Technical Monitor)

    1995-01-01

    To create a comparative framework for the study of ancient examples, we have been carrying out parallel studies of the microbial biosedimentology, taphonomy and geochemistry of modem and sub-Recent thermal spring deposits. One goal of the research is the development of integrated litho- and taphofacies models for siliceous and travertline sinters. Thermal springs are regarded as important environments for the origin and early evolution of life on Earth, and we seek to utilize information from the fossil record to reconstruct the evolution of high temperature ecosystems. Microbial contributions to the fabric of thermal spring sinters occur when population growth rates keep pace with, or exceed rates of inorganic precipitation, allowing for the development of continuous biofilms or mats. In siliceous thermal springs, microorganisms are typically entombed while viable. Modes of preservation reflect the balance between rates of organic matter degradation, silica precipitation and secondary infilling. Subaerial sinters are initially quite porous and permeable and at temperatures higher than about 20 C, organic materials are usually degraded prior to secondary infilling of sinter frameworks. Thus, organically-preserved microfossils are rare and fossil information consists of characteristic biofabrics formed by the encrustation and underplating of microbial mat surfaces. This probably accounts for the typically low total organic carbon values observed in thermal spring deposits. In mid-temperature, (approx. 35 - 59 C) ponds and outflows, the surface morphology of tufted Phormidium mats is preserved through mat underplating by thin siliceous: crusts. Microbial taxes lead to clumping of ceils and/or preferred filament orientations that together define higher order composite fabrics in thermal spring stromatolites (e.g. network, coniform, and palisade). At lower temperatures (less than 35 C), Calothrix mats cover shallow terracette pools forming flat carpets or pustular

  12. The potential of paleozoic nonmarine trace fossils for paleoecological interpretations

    USGS Publications Warehouse

    Maples, C.G.; Archer, A.W.

    1989-01-01

    Many Late Paleozoic environments have been interpreted as marine because of the co-occurrence of supposedly exclusively marine trace fossils. Beginning in the Late Ordovician, however, nonmarine trace-fossil diversity increased throughout the Paleozoic. This diversification of nonmarine organisms and nonmarine trace fossils was especially prevalent in Devonian and later times. Diversification of freshwater organisms is indicated by the large number of freshwater fish, arthropods, annelids and molluscs that had developed by the Carboniferous. In addition to diverse freshwater assemblages, entirely terrestrial vertebrate and invertebrate ecosystems had developed by the Devonian. This rapid diversification of freshwater and terrestrial organisms is inherently linked to development and diversification of land plants and subsequent shedding of large quantities of organic detritus in nonmarine and marginal-marine areas. Nearshore marine organisms and their larvae that are able to tolerate relatively short periods of lowered salinities will follow salt-water wedges inland during times of reduced freshwater discharge. Similarly, amphidromous marine organisms will migrate periodically inland into nonmarine environments. Undoubtedly, both of these processes were active in the Paleozoic. However, both processes are restricted to stream/distributary channels, interdistributary bays, or estuaries. Therefore, the presence of diverse trace-fossil assemblages in association with floodplain deposits is interpreted to reflect true nonmarine adaptation and diversity. Conversely, diverse trace-fossil assemblages in association with stream/distributary channel deposits, interdistributary-bay deposits, or estuarine deposits may reflect migration of salt-water wedges inland, or migration of marine organisms into freshwater environments (amphidromy), or both. ?? 1989.

  13. Three-dimensional Magnetic Resonance Imaging of fossils across taxa

    NASA Astrophysics Data System (ADS)

    Mietchen, D.; Aberhan, M.; Manz, B.; Hampe, O.; Mohr, B.; Neumann, C.; Volke, F.

    2008-01-01

    The frequency of life forms in the fossil record is largely determined by the extent to which they were mineralised at the time of their death. In addition to mineral structures, many fossils nonetheless contain detectable amounts of residual water or organic molecules, the analysis of which has become an integral part of current palaeontological research. The methods available for this sort of investigations, though, typically require dissolution or ionisation of the fossil sample or parts thereof, which is an issue with rare taxa and outstanding materials like pathological or type specimens. In such cases, non-destructive techniques could provide a valuable methodological alternative. While Computed Tomography has long been used to study palaeontological specimens, a number of complementary approaches have recently gained ground. These include Magnetic Resonance Imaging (MRI) which had previously been employed to obtain three-dimensional images of pathological belemnites non-invasively on the basis of intrinsic contrast. The present study was undertaken to investigate whether 1H MRI can likewise provide anatomical information about non-pathological belemnites and specimens of other fossil taxa. To this end, three-dimensional MR image series were acquired from intact non-pathological invertebrate, vertebrate and plant fossils. At routine voxel resolutions in the range of several dozens to some hundreds of micrometers, these images reveal a host of anatomical details and thus highlight the potential of MR techniques to effectively complement existing methodological approaches for palaeontological investigations in a wide range of taxa. As for the origin of the MR signal, relaxation and diffusion measurements as well as 1H and 13C MR spectra acquired from a belemnite suggest intracrystalline water or hydroxyl groups, rather than organic residues.

  14. Three-dimensional Magnetic Resonance Imaging of fossils across taxa

    NASA Astrophysics Data System (ADS)

    Mietchen, D.; Aberhan, M.; Manz, B.; Hampe, O.; Mohr, B.; Neumann, C.; Volke, F.

    2007-08-01

    The visibility of life forms in the fossil record is largely determined by the extent to which they were mineralised at the time of their death. In addition to mineral structures, many fossils nonetheless contain detectable amounts of residual water or organic molecules, the analysis of which has become an integral part of current palaeontological research. The methods available for this sort of investigations, though, typically require dissolution or ionisation of the fossil sample or parts thereof, which is an issue with rare taxa and outstanding materials like pathological or type specimens. In such cases, non-destructive techniques could provide an interesting methodological alternative. While Computed Tomography has long been used to study palaeontological specimens, a number of complementary approaches have recently gained ground. These include Magnetic Resonance Imaging (MRI) which had previously been employed to obtain three-dimensional images of pathological belemnites non-invasively on the basis of intrinsic contrast. The present study was undertaken to investigate whether 1H MRI can likewise provide anatomical information about non-pathological belemnites and specimens of other fossil taxa. To this end, three-dimensional MR image series were acquired from intact non-pathological invertebrate, vertebrate and plant fossils. At routine voxel resolutions in the range of several dozens to some hundreds of micrometers, these images reveal a host of anatomical details and thus highlight the potential of MR techniques to effectively complement existing methodological approaches for palaeontological investigations in a wide range of taxa. As for the origin of the MR signal, relaxation and diffusion measurements as well as 1H and 13C MR spectra acquired from a belemnite suggest intracrystalline water or hydroxyl groups, rather than organic residues.

  15. Fossil diatoms and neogene paleolimnology

    USGS Publications Warehouse

    Platt, Bradbury J.

    1988-01-01

    Diatoms have played an important role in the development of Neogene continental biostratigraphy and paleolimnology since the mid-19th Century. The history of progress in Quaternary diatom biostratigraphy has developed as a result of improved coring techniques that enable sampling sediments beneath existing lakes coupled with improved chronological control (including radiometric dating and varve enumeration), improved statistical treatment of fossil diatom assemblages (from qualitative description to influx calculations of diatom numbers or volumes), and improved ecological information about analogous living diatom associations. The last factor, diatom ecology, is the most critical in many ways, but progresses slowly. Fortunately, statistical comparison of modern diatom assemblages and insightful studies of the nutrient requirements of some common freshwater species are enabling diatom paleolimnologists to make more detailed interpretations of the Quaternary record than had been possible earlier, and progress in the field of diatom biology and ecology will continue to refine paleolimnological studies. The greater age and geologic setting of Tertiary diatomaceous deposits has prompted their study in the contexts of geologic history, biochronology and evolution. The distribution of diatoms of marine affinities in continental deposits has given geologists insights about tectonism and sea-level change, and the distribution of distinctive (extinct?) diatoms has found utilization both in making stratigraphic correlations between outcrops of diatomaceous deposits and in various types of biochronological studies that involve dating deposits in different areas. A continental diatom biochronologic scheme will rely upon evolution, such as the appearance of new genera within a family, in combination with regional environmental changes that are responsible for the wide distribution of distinctive diatom species. The increased use of the scanning electron microscope for the

  16. Recent radiation belt discoveries from the Van Allen Probes mission, outstanding questions, and future opportunities

    NASA Astrophysics Data System (ADS)

    Reeves, Geoffrey; Spence, Harlan

    The twin NASA Van Allen Probes satellites (formerly called Radiation Belt Storm Probes) were launched August 30, 2012 into geosynchronous transfer type orbits. The Van Allen Probes satellites host an extensive package of fields and particle instruments that provide unprecedented resolution and insensitivity to penetrating backgrounds needed to resolve among competing physical processes. The satellites were launched with an apogee near dawn. The apogee precesses Eastward taking two years to pass through all local times. The two satellites have slightly different orbital periods allowing the satellites to lap one another. This lapping provides a variety of configurations with the satellites sometimes closely separated in space and time and sometimes measuring two parts of the inner magnetosphere simultaneously. In this paper we will present some highlights of discoveries from the Van Allen Probes mission to date. Among those are: observations of the acceleration of relativistic electrons by VLF chorus waves; some unexpected occurrence of chorus waves; resonant pitch angle scattering of relativistic electrons both in those events that lead to loss and those that don’t; observations of drift resonant interactions of relativistic and sub-relativistic electrons with global ULF waves; the critical role that the sub-relativistic seed population plays in controlling radiation belt response and how substorm injections produce those seed populations; and the remarkable advances that have been made in 3D modeling of radiation belt structure and dynamics. We will also discuss the many outstanding questions that remain (as well as new questions that have arisen) and consider the remarkable opportunities that will be available thanks to new missions anticipated in the near future.

  17. Magnetohydrodynamic modeling of three Van Allen Probes storms in 2012 and 2013

    NASA Astrophysics Data System (ADS)

    Paral, J.; Hudson, M. K.; Kress, B. T.; Wiltberger, M. J.; Wygant, J. R.; Singer, H. J.

    2015-08-01

    Coronal mass ejection (CME)-shock compression of the dayside magnetopause has been observed to cause both prompt enhancement of radiation belt electron flux due to inward radial transport of electrons conserving their first adiabatic invariant and prompt losses which at times entirely eliminate the outer zone. Recent numerical studies suggest that enhanced ultra-low frequency (ULF) wave activity is necessary to explain electron losses deeper inside the magnetosphere than magnetopause incursion following CME-shock arrival. A combination of radial transport and magnetopause shadowing can account for losses observed at radial distances into L = 4.5, well within the computed magnetopause location. We compare ULF wave power from the Electric Field and Waves (EFW) electric field instrument on the Van Allen Probes for the 8 October 2013 storm with ULF wave power simulated using the Lyon-Fedder-Mobarry (LFM) global magnetohydrodynamic (MHD) magnetospheric simulation code coupled to the Rice Convection Model (RCM). Two other storms with strong magnetopause compression, 8-9 October 2012 and 17-18 March 2013, are also examined. We show that the global MHD model captures the azimuthal magnetosonic impulse propagation speed and amplitude observed by the Van Allen Probes which is responsible for prompt acceleration at MeV energies reported for the 8 October 2013 storm. The simulation also captures the ULF wave power in the azimuthal component of the electric field, responsible for acceleration and radial transport of electrons, at frequencies comparable to the electron drift period. This electric field impulse has been shown to explain observations in related studies (Foster et al., 2015) of electron acceleration and drift phase bunching by the Energetic Particle, Composition, and Thermal Plasma Suite (ECT) instrument on the Van Allen Probes.

  18. Precambrian biota: protistan origin of trace fossils?

    PubMed

    Pawlowski, Jan; Gooday, Andrew J

    2009-01-13

    Some Precambrian trace fossils have been presented as evidence for the early origin of bilaterians; the recent finding that large amoeboid protists leave macroscopic traces at the bottom of the deep ocean questions the metazoan nature of early trace fossils, stressing the importance of single-cell organisms in Precambrian biota.

  19. Do alternative energy sources displace fossil fuels?

    NASA Astrophysics Data System (ADS)

    York, Richard

    2012-06-01

    A fundamental, generally implicit, assumption of the Intergovernmental Panel on Climate Change reports and many energy analysts is that each unit of energy supplied by non-fossil-fuel sources takes the place of a unit of energy supplied by fossil-fuel sources. However, owing to the complexity of economic systems and human behaviour, it is often the case that changes aimed at reducing one type of resource consumption, either through improvements in efficiency of use or by developing substitutes, do not lead to the intended outcome when net effects are considered. Here, I show that the average pattern across most nations of the world over the past fifty years is one where each unit of total national energy use from non-fossil-fuel sources displaced less than one-quarter of a unit of fossil-fuel energy use and, focusing specifically on electricity, each unit of electricity generated by non-fossil-fuel sources displaced less than one-tenth of a unit of fossil-fuel-generated electricity. These results challenge conventional thinking in that they indicate that suppressing the use of fossil fuel will require changes other than simply technical ones such as expanding non-fossil-fuel energy production.

  20. Forty Years Later: Updating the Fossilization Hypothesis

    ERIC Educational Resources Information Center

    Han, ZhaoHong

    2013-01-01

    A founding concept in second language acquisition (SLA) research, fossilization has been fundamental to understanding second language (L2) development. The Fossilization Hypothesis, introduced in Selinker's seminal text (1972), has thus been one of the most influential theories, guiding a significant bulk of SLA research for four decades; 2012…

  1. Species-specific proteins in fossils

    NASA Astrophysics Data System (ADS)

    Lowenstein, Jerold M.

    1980-07-01

    With a solid-phase radioimmunoassay it has been possible to detect species-specific collagen and albumin in fossils as old as 1.9 million years. This technique may provide new data on the genetic relations of fossil species to each other and to living forms.

  2. The non-uniformity of fossil preservation.

    PubMed

    Holland, Steven M

    2016-07-19

    The fossil record provides the primary source of data for calibrating the origin of clades. Although minimum ages of clades are given by the oldest preserved fossil, these underestimate the true age, which must be bracketed by probabilistic methods based on multiple fossil occurrences. Although most of these methods assume uniform preservation rates, this assumption is unsupported over geological timescales. On geologically long timescales (more than 10 Myr), the origin and cessation of sedimentary basins, and long-term variations in tectonic subsidence, eustatic sea level and sedimentation rate control the availability of depositional facies that preserve the environments in which species lived. The loss of doomed sediments, those with a low probability of preservation, imparts a secular trend to fossil preservation. As a result, the fossil record is spatially and temporally non-uniform. Models of fossil preservation should reflect this non-uniformity by using empirical estimates of fossil preservation that are spatially and temporally partitioned, or by using indirect proxies of fossil preservation. Geologically, realistic models of preservation will provide substantially more reliable estimates of the origination of clades.This article is part of the themed issue 'Dating species divergences using rocks and clocks'. PMID:27325828

  3. Precambrian biota: protistan origin of trace fossils?

    PubMed

    Pawlowski, Jan; Gooday, Andrew J

    2009-01-13

    Some Precambrian trace fossils have been presented as evidence for the early origin of bilaterians; the recent finding that large amoeboid protists leave macroscopic traces at the bottom of the deep ocean questions the metazoan nature of early trace fossils, stressing the importance of single-cell organisms in Precambrian biota. PMID:19138588

  4. The non-uniformity of fossil preservation.

    PubMed

    Holland, Steven M

    2016-07-19

    The fossil record provides the primary source of data for calibrating the origin of clades. Although minimum ages of clades are given by the oldest preserved fossil, these underestimate the true age, which must be bracketed by probabilistic methods based on multiple fossil occurrences. Although most of these methods assume uniform preservation rates, this assumption is unsupported over geological timescales. On geologically long timescales (more than 10 Myr), the origin and cessation of sedimentary basins, and long-term variations in tectonic subsidence, eustatic sea level and sedimentation rate control the availability of depositional facies that preserve the environments in which species lived. The loss of doomed sediments, those with a low probability of preservation, imparts a secular trend to fossil preservation. As a result, the fossil record is spatially and temporally non-uniform. Models of fossil preservation should reflect this non-uniformity by using empirical estimates of fossil preservation that are spatially and temporally partitioned, or by using indirect proxies of fossil preservation. Geologically, realistic models of preservation will provide substantially more reliable estimates of the origination of clades.This article is part of the themed issue 'Dating species divergences using rocks and clocks'.

  5. The Flux and Energy Spectra of the Protons in the Inner Van Allen Belt

    NASA Technical Reports Server (NTRS)

    Naugle, John E.; Kniffen, Donald A.

    1961-01-01

    A cylindrical stack of G-5 nuclear emulsions housed in the payload section of a four-stage research rocket was flown into the northern edge of the inner Van Allen belt on September 19, 1960. The experimental design permitted, for the first time, measurements of the particle fluxes and energy spectra as functions of position along the rocket trajectory. Eight points along the trajectory have been selected for analysis. Results are presented herein for three of these points, and they are discussed in the light of various theories on the trapped radiation.

  6. Science Highlights from the RBSP-ECT Particle Instrument Suite on NASA's Van Allen Probes Mission

    NASA Astrophysics Data System (ADS)

    Spence, Harlan

    2014-05-01

    The NASA Van Allen Probes mission includes an instrument suite known as the Radiation Belt Storm Probes (RBSP) - Energetic Particle, Composition, and Thermal Plasma (ECT) suite. RBSP-ECT contains a well-proven complement of particle instruments to ensure the highest quality measurements ever made in the radiation belts and the inner magnetosphere. The coordinated RBSP-ECT particle measurements, analyzed in combination with fields and waves observations and state of-the-art theory and modeling, provide new understanding on the acceleration, global distribution, and variability of radiation belt electrons and ions, key science objectives of NASA's Living With a Star program and the Van Allen Probes mission. The RBSP-ECT suite consists of three highly-coordinated instruments: the Helium Oxygen Proton Electron (HOPE) spectrometer, the Magnetic Electron Ion Spectrometer (MagEIS), and the Relativistic Electron Proton Telescope (REPT). Collectively these three instrument types cover comprehensively the full electron and ion spectra from one eV to 10's of MeV with sufficient energy resolution, pitch angle coverage and resolution, and with composition measurements in the critical energy range up to 50 keV and also from a few to 50 MeV/nucleon. All three instruments are based on measurement techniques proven in the radiation belts, then optimized to provide unambiguous separation of ions and electrons and clean energy responses even in the presence of extreme penetrating background environments. In this presentation, we summarize overall ECT science goals and then show scientific results derived from the ECT suite on the dual Van Allen Probes spacecraft to date. Mission operations began only in late October 2012, and we have now achieved significant results. Results presented here will include substantial progress toward resolving primary Van Allen Probes science targets, such as: the relative role of localized acceleration versus transport-generated particle acceleration

  7. Early Science Results From the NASA Van Allen Probes Mission RBSP-ECT Instrument Suite

    NASA Astrophysics Data System (ADS)

    Spence, Harlan; Reeves, Geoff; Rbspect Team

    2013-04-01

    The NASA Van Allen Probes mission includes an instrument suite known as the Radiation Belt Storm Probes (RBSP) - Energetic Particle, Composition, and Thermal Plasma (ECT) suite. RBSP-ECT contains a well-proven complement of particle instruments to ensure the highest quality measurements ever made in the radiation belts and the inner magnetosphere. The coordinated RBSP-ECT particle measurements, analyzed in combination with fields and waves observations and state of-the-art theory and modeling, provide new understanding on the acceleration, global distribution, and variability of radiation belt electrons and ions, key science objectives of NASA's Living With a Star program and the Van Allen Probes mission. The RBSP-ECT suite consists of three highly-coordinated instruments: the Helium Oxygen Proton Electron (HOPE) spectrometer, the Magnetic Electron Ion Spectrometer (MagEIS), and the Relativistic Electron Proton Telescope (REPT). Collectively these three instrument types cover comprehensively the full electron and ion spectra from one eV to 10's of MeV with sufficient energy resolution, pitch angle coverage and resolution, and with composition measurements in the critical energy range up to 50 keV and also from a few to 50 MeV/nucleon. All three instruments are based on measurement techniques proven in the radiation belts, then optimized to provide unambiguous separation of ions and electrons and clean energy responses even in the presence of extreme penetrating background environments. In this presentation, we summarize overall ECT science goals and then show early scientific results derived from the ECT suite on the dual Van Allen Probes spacecraft. Mission operations began only in late October 2012, but we have already achieved significant early results. Results presented here will include substantial progress toward resolving primary Van Allen Probes science targets, such as: the relative role of localized acceleration versus transport-generated particle

  8. Catalytic enantioselective protoboration of disubstituted allenes. Access to alkenylboron compounds in high enantiomeric purity.

    PubMed

    Jang, Hwanjong; Jung, Byunghyuck; Hoveyda, Amir H

    2014-09-01

    Proto-boryl additions to 1,1-disubstituted allenes in the presence of 1.0-5.0 mol % of chiral NHC-Cu complexes, B2(pin)2, and t-BuOH proceed to afford alkenyl-B(pin) products in up to 98% yield, >98:2 site selectivity, and 98:2 er. The enantiomerically enriched alkenylboron products can be converted to otherwise difficult-to-access alkenyl bromides, methyl ketones or carboxylic acids. What's more, the corresponding boronic acids may be used in highly stereoselective NHC-Cu-catalyzed allylic substitution reactions. PMID:25153792

  9. MEDICAL MANAGEMENT OF LEIOMYOMATA AND SUSPECTED ENDOMETRIOSIS IN AN ALLEN'S SWAMP MONKEY (ALLENOPITHECUS NIGROVIRIDUS).

    PubMed

    Jafarey, Yousuf S; Hanley, Christopher S; Berlinski, Ric A; Warner, Connie; Armstrong, Anthony

    2015-12-01

    A 13-yr-old female nulliparous Allen's swamp monkey (Allenopitchecus nigroviridis) presented with intermittent excessive vaginal bleeding, cyclical lethargy, and a history of irregular menstrual cycles. Abdominal ultrasonography revealed a subjectively thickened, irregular endometrium, multiple leiomyomata (uterine fibroids), and bilateral anechoic foci on the ovaries. Treatment was initiated with leuprolide acetate i.m. monthly for 6 mo. Recheck ultrasound at 3 mo showed a decrease in leiomyoma diameter and no evidence of active follicles on the ovaries. Eleven months following completion of treatment, clinical signs recurred and the animal was treated with a deslorelin implant. Since implant placement, no vaginal bleeding has been noted. PMID:26667550

  10. Effect of the orbital debris environment on the high-energy Van Allen proton belt

    NASA Technical Reports Server (NTRS)

    Konradi, Andrei

    1988-01-01

    The lifetimes of high-energy (greater than 55 MeV) protons in the Van Allen radiation belt are calculated, assuming that in time the protons will collide with and be absorbed by particulate orbiting material. The calculations are based on the NASA/DoD Civil Needs Database for orbital debris (Gaines, 1966) and moderate assumptions of future space traffic. It is found that the lifetimes of high-energy protons below 1500 km will decrease, leading to a noticeable redution in their fluxes.

  11. Regioisomeric allene dimer formation by the reaction of tetraarylbutatrienes with tetracyanoethene.

    PubMed

    Ueta, Shoko; Hida, Kazuo; Nishiuchi, Masaki; Kawamura, Yasuhiko

    2014-05-01

    The reaction of tetraarylbutatrienes (tetraaryl[3]cumulenes) with tetracyanoethene (TCNE), a strong electron-accepting molecule, at room temperature yielded novel four-membered ring compounds (head-to-tail unsymmetrically substituted diarylallene dimers) by [2 + 2] cycloaddition of the central C=C bond of the butatrienes. This reaction proceeded through a head-to-head symmetrically substituted diarylallene dimer intermediate. Unsymmetrical butatriene also formed a small amount of another head-to-tail dimer. Although the allene dimer is stable in nonpolar solvents, it converts to other bicyclic and tricyclic compounds in MeOH or CH3CN at room temperature.

  12. Atomic force microscopy of Precambrian microscopic fossils.

    PubMed

    Kempe, André; Schopf, J William; Altermann, Wladyslaw; Kudryavtsev, Anatoliy B; Heckl, Wolfgang M

    2002-07-01

    Atomic force microscopy (AFM) is a technique used routinely in material science to image substances at a submicron (including nm) scale. We apply this technique to analysis of the fine structure of organic-walled Precambrian fossils, microscopic sphaeromorph acritarchs (cysts of planktonic unicellular protists) permineralized in approximately 650-million-year-old cherts of the Chichkan Formation of southern Kazakhstan. AFM images, backed by laser-Raman spectroscopic analysis of individual specimens, demonstrate that the walls of these petrified fossils are composed of stacked arrays of approximately 200-nm-sized angular platelets of polycyclic aromatic kerogen. Together, AFM and laser-Raman spectroscopy provide means by which to elucidate the submicron-scale structure of individual microscopic fossils, investigate the geochemical maturation of ancient organic matter, and, potentially, distinguish true fossils from pseudofossils and probe the mechanisms of fossil preservation by silica permineralization.

  13. Radio properties of fossil galaxy groups

    NASA Astrophysics Data System (ADS)

    Miraghaei, H.; Khosroshahi, H. G.

    2016-09-01

    We study 1.4 GHz radio properties of a sample of fossil galaxy groups using GMRT radio observations and the FIRST survey catalog. Fossil galaxy groups, having no recent major mergers in their dominant galaxies and also group scale mergers, give us the opportunity to investigate the effect of galaxy merger on AGN activity. In this work, we compare the radio properties of a rich sample of fossil groups with a sample of normal galaxy groups and clusters and show that the brightest group galaxies in fossil groups are under luminous at 1.4 GHz, relative to the general population of the brightest group galaxies, indicating that the dynamically relaxed nature of fossil groups has influenced the AGN activity in their dominant galaxy.

  14. A 25,000-year record of climate-induced changes in lowland vegetation of eastern equatorial Africa revealed by the stable carbon-isotopic composition of fossil plant leaf waxes

    NASA Astrophysics Data System (ADS)

    Sinninghe Damsté, Jaap S.; Verschuren, Dirk; Ossebaar, Jort; Blokker, Jord; van Houten, Rianne; van der Meer, Marcel T. J.; Plessen, Birgit; Schouten, Stefan

    2011-02-01

    The debate of climate versus CO2 in controlling the long-term dynamics of tropical African vegetation has focused on events at the upper tree-line, since the relevant paleodata tend to be from mid-elevation sites (~ 2000-3000 m). Less well known is the relative importance of CO2 in regulating the dynamics of tropical lowland (< 1500 m) vegetation, particularly that of the dry open woodlands, bush- and grasslands covering much of eastern equatorial Africa. Here we examine the stable carbon isotopic composition of n-alkanes in the sediment record of Lake Challa, a lowland crater lake near Mt. Kilimanjaro, covering the last 25,000 years. The distributions of the n-alkanes, with dominance of the long-chain odd-carbon-numbered components, and their isotopic composition reveal a mixed origin. The C23 and C25n-alkanes are depleted in 13C, with δ13C values between - 30 and - 50‰. In shallow lakes these n-alkanes are thought to derive from non-emergent aquatic plants, but this is unlikely in this steep-sided crater lake as it lacks a significant littoral habitat. The C27+n-alkanes are predominantly derived from leaf wax lipids of terrestrial plants, brought into the lake predominantly by local soil run-off. Their δ13C values, in particular that of the n-C31 alkane, reveal a marked transition in local lowland vegetation from being dominated (~ 70-100%) by C4 plants during the glacial period until 16.5 cal kyr BP, to a more mixed C3/C4 composition (~ 30-60% C4) during the Holocene. The start of the late-glacial trend towards a greater proportion of C3 plants coincided with the start of increasing monsoon rainfall, ~ 1500 years after the onset of the rise in atmospheric CO2 and ~ 3500 years after the onset of post-glacial warming. The transition was interrupted during the dry Younger Dryas period (13.0-11.7 cal kyr BP), when C4 plants again became much more prevalent, almost reaching their glacial-period abundance. Notably, the principal trend in leaf-wax δ13C values

  15. Selective flotation of fossil resin from Western coal. Final report, July 1, 1990--May 25, 1992

    SciTech Connect

    Jensen, G.F.; Miller, J.D.

    1992-05-25

    The proof-of-concept test program was designed to clarify a number of concerns that have been raised by coal companies who own the valuable resin resource. First, from laboratory bench-scale flotation experiments, a froth product from cleaner flotation containing more than 80% hexane-extractable resin at higher than 80% recovery can be produced. Pilot-plant testing was initiated to demonstrate the selective flotation of fossil resin and to establish a better confidence level in the new technology. Second, pilot-plant testing was designed to evaluate the effect and impact of random variation in slurry solids concentration and feed grade on this new selective fossil resin flotation technology. The flotation performance obtained under these industrial conditions is more realistic for process evaluation. Third, more accurate operating cost data was to be obtained for economic analysis. Fourth, sufficient quantities of the fossil resin concentrate were to be produced from the test program for evaluation by potential industrial users. Fifth, and finally, optimum levels for the operating variables were to be established. Such information was required for eventual scale-up and design of a fossil resin flotation plant. The pilot-plant proof-of-concept testing of selective resinate flotation has demonstrated that: (1) technically, the new flotation technologies discovered at the University of Utah and then improved upon by Advanced Processing Technologies, Inc. provide a highly efficient means to selectively recover fossil resin from coal. The proof-of-concept continuous flotation circuit (about 0.1 tph) resulted in fossil resin recovery with the same separation efficiency as was obtained from laboratory bench-scale testing (more than 80% recovery at about 80% concentrate grade); and (2) economically, the selective flotation process has been shown to be sufficiently profitable to justify the development of a fossil resin industry based on this new flotation process.

  16. Catalyst-Dependent Stereodivergent and Regioselective Synthesis of Indole-Fused Heterocycles through Formal Cycloadditions of Indolyl-Allenes.

    PubMed

    Mei, Liang-Yong; Wei, Yin; Tang, Xiang-Ying; Shi, Min

    2015-07-01

    Stereo- and regioselective construction of poly-heterocycles, especially those with several contiguous stereocenters, is still a challenge. In this paper, catalyst-dependent stereodivergent and regioselective synthesis of indole-fused heterocycles through formal cycloadditions of indolyl-allenes has been developed. The reaction features total reversion of an all-carbon quaternary stereocenter when a gold or platinum complex was employed as the catalyst through [3 + 2] cycloaddition of allene with indole, affording different diazabenzo[a]cyclopenta[cd]azulenes as epimers, respectively. In addition, in the presence of IPrAuCl and AgNTf2, highly regioselective exo-type [2 + 2] cycloaddition was observed, in which allene served as a 2C synthon. This methodology provides a simple and straightforward approach for the construction of indole-fused tricyclic systems under mild conditions in an atom-economical way.

  17. Plant maintenance and plant life extension issue, 2007

    SciTech Connect

    Agnihotri, Newal

    2007-03-15

    The focus of the March-April issue is on plant maintenance and plant life extension. Major articles/reports in this issue include: Three proposed COLs expected in 2007, by Dale E. Klein, U.S. Nuclear Regulatory Commission; Delivering behaviors that our customers value, by Jack Allen, Westinghouse Electric Company; Facilitating high-level and fuel waste disposal technologies, by Malcolm Gray, IAEA, Austria; Plant life management and long-term operation, by Pal Kovacs, OECD-NEA, France; Measuring control rod position, by R. Taymanov, K. Sapozhnikova, I. Druzhinin, D.I. Mendeleyev, Institue for Metrology, Russia; and, 'Modernization' means higher safety, by Svetlana Genova, Kozluduy NPP plc, Bulgaria.

  18. Soot formation in pyrolysis of acetylene, allene and 1,3-butadiene

    NASA Technical Reports Server (NTRS)

    Frenklach, M.; Durgaprasad, M. B.; Matula, R. A.; Taki, S.

    1983-01-01

    The formation of soot behind reflected shock waves in argon-diluted mixtures of acetylene, allene, and 1,3-butadiene was investigated by monitoring the attenuation of a laser beam in both the visible (632.8 nm) and the infrared (3.39 microns) regions of the spectrum. The experiments utilized temperatures ranging from 1500-3100 K, reflected shock pressures of 0.3-7.0 bar, and total carbon atom concentrations of 2-20 x 10 to the 17th atoms/cu cm. A bell-shaped dependence of soot yield on temperature was observed during the pyrolysis of all three compounds, which was similar to that previously found for toluene. For acetylene, the decrese in total pressure was found to shift the soot bell to higher temperatures with a significant increase in the maximum soot yield. A computer simulation for acetylene pyrolysis suggested that the reactions between C2H3, C4H3, and C4H4 may be those which lead to the formation of aromatic structures. In addition, it was found that soot is formed much faster and in much larger quantities from allene than from 1,3-butadiene.

  19. Ion Spectral Structures Observed by the Van Allen Probes and Cluster

    NASA Astrophysics Data System (ADS)

    Ferradas, C.; Zhang, J.; Luo, H.; Kistler, L. M.; Spence, H. E.; Larsen, B.; Skoug, R. M.; Funsten, H. O.; Reeves, G. D.

    2014-12-01

    During the last decades several missions have recorded the presence of dynamic spectral features of energetic ions in the inner magnetosphere. Previous studies have revealed single "nose-like" structures occurring alone and simultaneous nose-like structures (up to three). In this study we also include signatures of new types of ion structure, namely "trunk-like" and "tusk-like" structures. All the ion structures are named after the characteristic shapes of energy bands or gaps in the energy-time spectrograms of in situ measured ion fluxes. They constitute the observational signatures of ion acceleration, transport, and loss in the global magnetosphere. Multi-spacecraft analysis of these structures is important to understand their spatial distribution and temporal evolution. Mass spectrometers onboard Cluster (in a polar orbit) and the Van Allen Probes (in an equatorial orbit) measure energetic hydrogen, helium, and oxygen ions near the inner edge of the plasma sheet, where these ion structures are observed. We present a statistical study of the ion structures, using >1-year measurements from the two missions during the Van Allen Probes era. The results provide important details about the spatial distribution (dependence on geocentric distance and magnetic local time), spectral features of the structures (e.g., characteristic energy and differences among species), and geomagnetic and solar wind conditions under which these structures occur.

  20. Marine ecological-risk assessment pilot study for Allen Harbor, Narragansett Bay, Rhode Island. Professional paper

    SciTech Connect

    Johnston, R.K.; Munns, W.R.; Mueller, C.; Nelson, W.G.; Pesch, G.G.

    1992-01-01

    An ecological risk assessment framework was applied to characterize aquatic risks associated with hazardous waste disposal at Naval Construction Battalion Center (NCBC) Davisville, Rhode Island. An initial screening phase (I) assessed exposure and related that exposure to toxicological endpoints for bivalves, amphipods, sea urchins, and biomarker assays. Results showed little evidence of major contamination in sediments or tissues except for relatively high levels of polychlorinated biphenols (PBC), butyltins compounds (TBT), and fecal coliforms observed in Allen Harbor. Effects were detected in mussel physiology, sea urchin fertilization and development, biomarker responses, and soft shell clam histology. Possible sources of contamination and toxicity from the landfill leachate, surface runoff, and recreational boating were examined using a temporaland spatial sampling scheme. Chemical and toxicological information obtained implicated all three sources as affecting Allen Harbor water quality. Laboratory bioassays of landfill exposure media, employing a variety of marine species using acute and chronic endpoints, are being used to provide data for the development of an exposure-response model for risk to the marine environment. The model will define current risk and provide an interpretive framework for long-term monitoring.

  1. Van Allen Probes RBSPICE Observations of the March 2015 Solar Storm

    NASA Astrophysics Data System (ADS)

    Manweiler, J. W.; Patterson, J. D.; Gerrard, A. J.; Gkioulidou, M.; Mitchell, D. G.; Lanzerotti, L. J.

    2015-12-01

    The Van Allen Probes Radiation Belt Storm Probes Ion Composition Experiment (RBSPICE) instrument provides the ability to measure the energetic particle composition of the Earth's ring current from 20 KeV to approximately 1 MeV. On March 17, 2015 a solar storm impacted the Earth with a maximum negative Dst of -232. The onset of the storm was directly observed by the RBSPICE B instrument. The RBSPICE A instrument observed the development of the storm prior to onset in one orbit and a few hours after onset on the subsequent orbit. These observations displayed a number of interesting features of the storm including an Oxygen beam, high beta plasma conditions, and multiple injections of protons, helium, and oxygen into the inner magnetosphere. Our presentation will report on the observations made from each RBSPICE instrument coupled with observations from other Van Allen Probes instruments (EMFISIS, ECT, and EFW) to provide a complete picture of the impact of this storm on the Earth's inner magnetosphere.

  2. Simultaneous Observation of Plasma Waves Detected by the Van Allen Probes Spacecraft During Close Spacecraft Separations

    NASA Astrophysics Data System (ADS)

    Hospodarsky, George; Santolik, Ondrej; Averkamp, Terrance; Bounds, Scott; Kurth, William; Kletzing, Craig; Wygant, John; Bonnell, John

    2014-05-01

    The twin Van Allen Probe spacecraft launched in August 2012 includes the Electric and Magnetic Field Instrument Suite and Integrated Science (EMFISIS) Wave instrument that simultaneously measures three orthogonal components of the wave magnetic field and, with the support of the Electric Fields and Waves (EFW) instrument sensors, three components of the wave electric field at two locations in Earth's magnetosphere. Measuring all six wave components simultaneously allows the wave propagation parameters, such as the wave normal angle and Poynting vector, of the plasma wave emissions to be obtained. The orbit of the spacecraft are designed such that they "lap" each other roughly every 69 days, allowing observations over a range of spacecraft separations, with the closest separations on the order of 100 km. Simultaneous measurements at a range of distances between the two spacecraft provide an opportunity to investigate the scale, size and propagation characteristics of a number of plasma wave emissions associated with the Van Allen radiation belts, including whistler mode chorus. We examine these characteristics of the emissions detected by both spacecraft during separation distance of < 1000 km. Very similar small scale chorus wave packets were detected by both spacecraft when separation distances were the smallest. The similarities and differences detected by both spacecraft and their relation to separation distances will be discussed.

  3. Collier Cobb and Allen D. Hole: Geologic mentors to early soil scientists

    NASA Astrophysics Data System (ADS)

    Brevik, Eric C.

    Many influential individuals involved in the early US soil survey program were trained as geologists rather than as agronomists or soil scientists. Several geology departments served as pipelines for students interested in a career in soil survey. This paper looks at the professional history of two early mentors of these geologists turned soil surveyors and some of the students they sent on to the US soil survey and other soil science careers. Collier Cobb sent over 10 students to the soil survey starting in 1900 when US soil survey was in its infancy, including individuals of note such as Hugh H. Bennett, George N. Coffey, Williamson E. Hearn, and Thomas D. Rice. Allen D. Hole worked on soil surveys for the state of Indiana and sent over a dozen students on to US soil survey careers between 1911 and 1937, including Mark Baldwin and James Thorp. Francis Hole and Ralph McCracken, other students of Allen Hole, also went on to have distinguished soil science careers. These mentors and students clearly show the close ties that existed between soil science and geology in the United States during the early 1900s.

  4. Collier Cobb and Allen D. Hole: Geologic Mentors to Early American Soil Scientists

    NASA Astrophysics Data System (ADS)

    Brevik, E. C.

    2012-04-01

    Many influential individuals involved in the early United States soil survey program were trained as geologists rather than as agronomists or soil scientists. Several geology departments served as pipelines for students interested in a career in soil survey. This presentation looks at the professional history of two early mentors of these geologists turned soil surveyors and some of the students they sent on to the U.S. soil survey and other soil science careers. Collier Cobb (University of North Carolina) sent over 10 students to the soil survey starting in 1900 when U.S. soil survey was in its infancy, including individuals of note such as Hugh H. Bennett, George N. Coffey, Williamson E. Hearn, and Thomas D. Rice. Allen D. Hole (Earlham College, Indiana) worked on soil surveys for the state of Indiana and sent over a dozen students on to U.S. soil survey careers between 1911 and 1937, including Mark Baldwin and James Thorp. Francis Hole and Ralph McCracken, other students of Allen Hole, also went on to have distinguished soil science careers. These mentors and students clearly show the close ties that existed between soil science and geology in the United States during the early 1900s.

  5. Impacts of intense inward and outward ULF wave radial diffusion on the Van Allen belts

    NASA Astrophysics Data System (ADS)

    Mann, Ian; Ozeke, Louis; Rae, I. Jonathan; Murphy, Kyle

    2016-07-01

    During geomagnetic storms, the power in ultra-low frequency (ULF) waves can be orders of magnitude larger than that predicted by statistics determined from an entire solar cycle. This is especially true during the main phase and early recovery phase. These periods of enhanced storm-time ULF wave power can have significant impacts on the morphology and structure of the Van Allen belts. Either fast inward or outward radial diffusion can result, depending on the profiles of the electron phase space density and the outer boundary condition at the edge of the belts. Small changes in the time sequence of powerful ULF waves, and the time sequence of any magnetopause shadowing or the recovery of plamasheet sources relative to the ULF wave occurrence, have a remarkable impact on the resulting structure of the belts. The overall impact of the enhanced ULF wave power is profound, but the response can be very different depending on the available source flux in the plasmasheet. We review these impacts by examining ultra-relativistic electron dynamics during seemingly different storms during the Van Allen Probe era, including during the Baker et al. third radiation belt, and show the observed behaviour can be largely explained by differences in the time sequence of events described above.

  6. Automatic registration of imaging mass spectrometry data to the Allen Brain Atlas transcriptome

    NASA Astrophysics Data System (ADS)

    Abdelmoula, Walid M.; Carreira, Ricardo J.; Shyti, Reinald; Balluff, Benjamin; Tolner, Else; van den Maagdenberg, Arn M. J. M.; Lelieveldt, B. P. F.; McDonnell, Liam; Dijkstra, Jouke

    2014-03-01

    Imaging Mass Spectrometry (IMS) is an emerging molecular imaging technology that provides spatially resolved information on biomolecular structures; each image pixel effectively represents a molecular mass spectrum. By combining the histological images and IMS-images, neuroanatomical structures can be distinguished based on their biomolecular features as opposed to morphological features. The combination of IMS data with spatially resolved gene expression maps of the mouse brain, as provided by the Allen Mouse Brain atlas, would enable comparative studies of spatial metabolic and gene expression patterns in life-sciences research and biomarker discovery. As such, it would be highly desirable to spatially register IMS slices to the Allen Brain Atlas (ABA). In this paper, we propose a multi-step automatic registration pipeline to register ABA histology to IMS- images. Key novelty of the method is the selection of the best reference section from the ABA, based on pre-processed histology sections. First, we extracted a hippocampus-specific geometrical feature from the given experimental histological section to initially localize it among the ABA sections. Then, feature-based linear registration is applied to the initially localized section and its two neighbors in the ABA to select the most similar reference section. A non-rigid registration yields a one-to-one mapping of the experimental IMS slice to the ABA. The pipeline was applied on 6 coronal sections from two mouse brains, showing high anatomical correspondence, demonstrating the feasibility of complementing biomolecule distributions from individual mice with the genome-wide ABA transcriptome.

  7. Prospects of Comparing Van Allen Probes Data with Recent Nonlinear Radiation Belt Theory

    NASA Astrophysics Data System (ADS)

    Summers, D.; Omura, Y.; Tang, R.

    2013-12-01

    We consider the prospects of comparing recently developed theory and simulations of nonlinear wave processes with Van Allen Probes observational data. Electron gyro-resonant interaction with whistler-mode chorus waves is considered to be a prime mechanism for generating relativistic electrons in Earth's outer radiation belt. Resonant pitch angle scattering by chorus can also cause significant electron precipitation loss from the inner magnetosphere. Whistler-mode waves can as well act to suppress radiation belt electron fluxes below a theoretical (Kennel-Petschek) limit. Nonlinear cyclotron resonance theory is required to analyze the nonlinear characteristics of whistler-mode wave generation and the interaction of chorus with radiation belt electrons. We discuss recently developed nonlinear theory that involves wave trapping of resonant electrons near the equator and the formation of an electron hole in the phase space. The resulting formation of a resonant current causes nonlinear growth of a wave with rising frequency. Nonlinear wave trapping plays a significant role in both the generation of whistler-mode chorus emissions and the acceleration of radiation belt electrons to relativistic energies. A fraction of radiation belt electrons can be energized extremely efficiently by special wave trapping mechanisms called "relativistic turning acceleration" and "ultra-relativistic acceleration". In this presentation we summarize the salient features of whistler-mode wave generation and these associated acceleration processes,and discuss how they can be compared with particle and wave data from the Van Allen Probes mission.

  8. Genetic diversity and structure in the Endangered Allen Cays Rock Iguana, Cyclura cychlura inornata

    PubMed Central

    Aplasca, Andrea C.; Iverson, John B.; Welch, Mark E.; Colosimo, Giuliano

    2016-01-01

    The Endangered Allen Cays Rock Iguana (Cyclura cychlura inornata) is endemic to the Allen Cays, a tiny cluster of islands in the Bahamas. Naturally occurring populations exist on only two cays (<4 ha each). However, populations of unknown origin were recently discovered on four additional cays. To investigate patterns of genetic variation among these populations, we analyzed nuclear and mitochondrial markers for 268 individuals. Analysis of three mitochondrial gene regions (2,328 bp) and data for eight nuclear microsatellite loci indicated low genetic diversity overall. Estimates of effective population sizes based on multilocus genotypes were also extremely low. Despite low diversity, significant population structuring and variation in genetic diversity measures were detected among cays. Genetic data confirm the source population for an experimentally translocated population while raising concerns regarding other, unauthorized, translocations. Reduced heterozygosity is consistent with a documented historical population decline due to overharvest. This study provides the first range-wide genetic analysis of this subspecies. We suggest strategies to maximize genetic diversity during ongoing recovery including additional translocations to establish assurance populations and additional protective measures for the two remaining natural populations. PMID:26989628

  9. 'Trunk-like' ion structures observed by the Van Allen Probes

    NASA Astrophysics Data System (ADS)

    Zhang, J.; Kistler, L. M.; Spence, H.; Wolf, R.; Reeves, G. D.; Skoug, R. M.; Funsten, H. O.; Larsen, B.; Niehof, J. T.; MacDonald, E.; Friedel, R. H.

    2013-12-01

    Dynamic ion spectral features in the inner magnetosphere are the observational signatures of ion acceleration, transport, and loss in the global magnetosphere. In this study, we report 'trunk-like' ion structures observed in situ by the Van Allen Probes on 2 November 2012. The trunk structures are present in heavy ions but not in H+. For the particular event, ion energies in the He+ trunks, located at L = 3.7-2.6, MLT = 8.8-10.3, and MLAT = -2.0-0.03°, vary monotonically from 3.5 to 0.04 keV. It is suggested that the trunk phenomenon is due to a combination of 1) deeper ion injections from storm activity, 2) the longer charge exchange lifetimes of heavy ions than H+, 3) the separation of a narrow layer of ions around the Alfvén layer from other convecting ions, and 4) the trajectory of the Van Allen Probes (i.e., an orbital effect). Both observation analysis and numerical modeling are utilized in the study.

  10. Relativistic Electrons in the Inner Zone and Slot - Quiet Time Observations by the Van Allen Probes

    NASA Astrophysics Data System (ADS)

    Blake, J. B.; Fennell, J. F.; Claudepierre, S. G.; Looper, M. D.; Mazur, J. E.; O'Brien, T. P.; Clemmons, J. H.; Baker, D. N.; Reeves, G. D.; Spence, H.; Funsten, H. O.

    2013-12-01

    The energy spectra of relativistic electrons in the inner zone and slot region are old questions dating from the early days of space research. There are two major reasons for this situation: the paucity of scientific missions traversing the inner zone and slot region at low inclination, and the technical difficulty of making relativistic electron measurements in the presence of the very energetic protons and intense fluxes of electrons with energies up to a few hundred keV that are found in the inner zone. The Van Allen Probes mission offers a new opportunity to address this problem. This mission to date has taken place during a time period of only modest geomagnetic activity with no unusual increases of the energetic electron population deep inside the magnetosphere such as the shock injection of 24 March 1991 or the Halloween storm of 2003. We began by examining observations made during some of the quieter times since launch, in late January and early February 2013. The data show that the inner zone electron fluxes indeed drop to very low intensities by several hundred keV. A major focus of this preliminary study has been a careful examination of sources of background and its removal in the electron spectrometers using several of the Van Allen probe instruments. Upper limits on the relativistic electron intensities as a function of L will be presented.

  11. An impenetrable barrier to ultrarelativistic electrons in the Van Allen radiation belts.

    PubMed

    Baker, D N; Jaynes, A N; Hoxie, V C; Thorne, R M; Foster, J C; Li, X; Fennell, J F; Wygant, J R; Kanekal, S G; Erickson, P J; Kurth, W; Li, W; Ma, Q; Schiller, Q; Blum, L; Malaspina, D M; Gerrard, A; Lanzerotti, L J

    2014-11-27

    Early observations indicated that the Earth's Van Allen radiation belts could be separated into an inner zone dominated by high-energy protons and an outer zone dominated by high-energy electrons. Subsequent studies showed that electrons of moderate energy (less than about one megaelectronvolt) often populate both zones, with a deep 'slot' region largely devoid of particles between them. There is a region of dense cold plasma around the Earth known as the plasmasphere, the outer boundary of which is called the plasmapause. The two-belt radiation structure was explained as arising from strong electron interactions with plasmaspheric hiss just inside the plasmapause boundary, with the inner edge of the outer radiation zone corresponding to the minimum plasmapause location. Recent observations have revealed unexpected radiation belt morphology, especially at ultrarelativistic kinetic energies (more than five megaelectronvolts). Here we analyse an extended data set that reveals an exceedingly sharp inner boundary for the ultrarelativistic electrons. Additional, concurrently measured data reveal that this barrier to inward electron radial transport does not arise because of a physical boundary within the Earth's intrinsic magnetic field, and that inward radial diffusion is unlikely to be inhibited by scattering by electromagnetic transmitter wave fields. Rather, we suggest that exceptionally slow natural inward radial diffusion combined with weak, but persistent, wave-particle pitch angle scattering deep inside the Earth's plasmasphere can combine to create an almost impenetrable barrier through which the most energetic Van Allen belt electrons cannot migrate.

  12. Mechanistic Insight into the Copper-Catalyzed Regiodivergent Silacarboxylation of Allenes with CO2.

    PubMed

    Yuan, Ruming; Hu, Rong; Fu, Gang

    2016-08-01

    DFT calculations were performed to investigate the detailed reaction mechanisms in the copper-catalyzed regiodivergent silacarboxylation of allenes. According to our calculations, the catalysis would bifurcate at the allene silylcupration step, followed by CO2 insertion, eventually leading to the carboxylated vinylsilane or allylsilane products. The gaps between the two silylcupration barriers were predicted to be -2.3, -0.4, and 2.2 kcal mol(-1) when using (rac)-Me-DuPhos, dcpe, and PCy3 (+H2 O) as the ligands, which nicely accounted for the experimental vinylsilane/allylsilane ratios of 93:7, 50:50, and 15:85, respectively. By means of transition-state-energy decomposition, we found that the energy penalty of catalyst deformation into its transition-state geometry was the key factor in determining the direction of the reaction. The switchable regioselectivity by using different P ligands could be ascribed to structural changes of the Cu-Si and Cu-P bonds during the silylcupration process. PMID:27319319

  13. An impenetrable barrier to ultrarelativistic electrons in the Van Allen radiation belts.

    PubMed

    Baker, D N; Jaynes, A N; Hoxie, V C; Thorne, R M; Foster, J C; Li, X; Fennell, J F; Wygant, J R; Kanekal, S G; Erickson, P J; Kurth, W; Li, W; Ma, Q; Schiller, Q; Blum, L; Malaspina, D M; Gerrard, A; Lanzerotti, L J

    2014-11-27

    Early observations indicated that the Earth's Van Allen radiation belts could be separated into an inner zone dominated by high-energy protons and an outer zone dominated by high-energy electrons. Subsequent studies showed that electrons of moderate energy (less than about one megaelectronvolt) often populate both zones, with a deep 'slot' region largely devoid of particles between them. There is a region of dense cold plasma around the Earth known as the plasmasphere, the outer boundary of which is called the plasmapause. The two-belt radiation structure was explained as arising from strong electron interactions with plasmaspheric hiss just inside the plasmapause boundary, with the inner edge of the outer radiation zone corresponding to the minimum plasmapause location. Recent observations have revealed unexpected radiation belt morphology, especially at ultrarelativistic kinetic energies (more than five megaelectronvolts). Here we analyse an extended data set that reveals an exceedingly sharp inner boundary for the ultrarelativistic electrons. Additional, concurrently measured data reveal that this barrier to inward electron radial transport does not arise because of a physical boundary within the Earth's intrinsic magnetic field, and that inward radial diffusion is unlikely to be inhibited by scattering by electromagnetic transmitter wave fields. Rather, we suggest that exceptionally slow natural inward radial diffusion combined with weak, but persistent, wave-particle pitch angle scattering deep inside the Earth's plasmasphere can combine to create an almost impenetrable barrier through which the most energetic Van Allen belt electrons cannot migrate. PMID:25428500

  14. The relationship of the Allen Cognitive Level Test to cognitive abilities and psychopathology.

    PubMed

    David, S K; Riley, W T

    1990-06-01

    The cognitive factors measured by the Allen Cognitive Level Test (ACL) (Allen, 1982) as well as the test's relationship to level of psychopathology were examined through a retrospective study of 71 patients from a general hospital psychiatry unit. Pearson correlations, computed for the ACL score with the Shipley Institute of Living Scale (Shipley, 1940), a general measure of intellectual functioning, were significant. A strong correlation was found between the ACL and the Symbol-Digit Modalities Test (Smith, 1982), a measure of motor speed and concentration often used as a neurological screening instrument. This suggests the potential usefulness of the ACL to screen for cognitive dysfunctions associated with organicity. Contrary to hypothesis, there was no significant correlation between the ACL and measures of psychopathology such as the Beck Depression Inventory (Beck, Ward, Mendelson, Mock, & Erbaugh, 1961) and the Minnesota Multiphasic Personality Inventory (Hathaway & McKinley, 1940). The relationship of the ACL to other recognized measures of cognitive functioning increases its usefulness as a valid measure of day-to-day limitations in the functioning of psychiatric patients. Effective communication of the implications of these cognitive levels to a multidisciplinary treatment team is enhanced by knowledge of the relationship of the ACL to measures of cognitive functioning and psychopathology used by other disciplines.

  15. Selective Preservation of Fossil Ghost Fish

    NASA Astrophysics Data System (ADS)

    Meacham, Amanda

    2016-04-01

    A unique type of fossil fish preservation has been discovered in the Angelo Member (Fossil Lake) of the Green River Formation. The Angelo Member is a predominately evaporative deposit dominated by dolomite, but contains facies of fossiliferous laminated calcimicrite. Fossil fish occurring in two beds conspicuously lack bones. Fish in the lower bed are only preserved as organic material, including skin, pigments, and eyes. Fish in the upper bed have three-dimensional etching where bones once existed but also contain skin, pigments, and eyes. The top third of the upper bed often contains calcite crystals that are pseudomorphs after trona and possibly halite. Preliminary mineralogical analysis and mapping of evaporate facies suggests that this unique preservation may be related to lake geochemical conditions, such as high pH and alkalinity. To our knowledge, this is the first time this type of preservation has been observed and studied. Fossils and sediments within these beds are being studied both vertically and laterally through the one-meter thick sequence containing the fossil fish using XRD, isotopic, SEM, thin section, and total organic carbon analysis. Nine quarries, 0.5-1 meter square, were excavated for both fossils and rock samples along with 17 additional rock sample locations across an approximately 25-kilometer square region. This investigation has the capability of reconstructing the paleoenvironment and lake chemistry of Fossil Lake during the deposition of the "ghost-fish" beds and solving the mystery of the "missing bones" and the unusual process of preservation.

  16. From the IGY to the IHY: A Changing View of the Van Allen Radiation Belts

    NASA Astrophysics Data System (ADS)

    Hudson, M. K.

    2006-12-01

    Discovery of the Van Allen radiation belts by instrumentation flown on Explorer 1 in 1958 was the first major discovery of the Space Age. A view of the belts as static inner and outer zones of energetic particles with different sources, a double-doughnut encircling the Earth, became iconic to the point that their dynamic behavior and solar connection receded from public awareness and apparent scientific import. Then the Cycle 23 maximum in solar activity arrived in 1989-1991, the first approaching the activity level of the International Geophysical Year of 1957-58, when the Van Allen belts were first discovered. Delay in launch of the NASA-Air Force Combined Radiation Release and Effects Satellite, following the Challenger accident in 1986, led to having the right instruments in the right orbit at the right time to detect prompt injection of outer belt electrons and solar energetic protons into the `slot region' between the inner and outer belts, forming new trapped populations which lasted for years in an otherwise benign location. This event in March 1991, along with the great geomagnetic storm of March 1989, and our increased dependence on space technology since the early Explorer days, led to a resurgence of interest in the Van Allen radiation belts and understanding of their connectivity to the Sun. Additional instrumentation from NASA's International Solar Terrestrial Physics Program, the Solar Anomalous and Magnetospheric Particle Explorer (SAMPEX) and IMAGE spacecraft from the Explorer program, NOAA and DOD spacecraft, and improved worldwide linkages of groundbased measurements have contributed much since 1991 to our understanding of the dynamic characteristics of the Van Allen belts. Further, the presence of continuous solar wind measurements beginning with the launch of WIND in 1994, and SOHO images of Coronal Mass Ejections and coronal hole sources of high speed solar wind flow have filled in the connection with solar activity qualitatively anticipated

  17. Allylic and Allenic Halide Synthesis via NbCl5- and NbBr5-Mediated Alkoxide Rearrangements

    PubMed Central

    Ravikumar, P. C.; Yao, Lihua; Fleming, Fraser F.

    2009-01-01

    Addition of NbCl5, or NbBr5, to a series of magnesium, lithium, or potassium allylic or propargylic alkoxides directly provides allylic or allenic halides. Halogenation formally occurs through a metalla-halo-[3,3] rearrangement although concerted, ionic, and direct displacement mechanisms appear to operate competitively. Transposition of the olefin is equally effective for allylic alkoxides prepared by nucleophilic addition, deprotonation, or reduction. Experimentally, the niobium pentahalide halogenations are rapid, afford essentially pure E-allylic or allenic halides after extraction, and are applicable to a range of aliphatic and aromatic alcohols, aldehydes, and ketones. PMID:19739606

  18. Allylic and allenic halide synthesis via NbCl(5)- and NbBr(5)-mediated alkoxide rearrangements.

    PubMed

    Ravikumar, P C; Yao, Lihua; Fleming, Fraser F

    2009-10-01

    Addition of NbCl(5) or NbBr(5) to a series of magnesium, lithium, or potassium allylic or propargylic alkoxides directly provides allylic or allenic halides. Halogenation formally occurs through a metalla-halo-[3,3] rearrangement, although concerted, ionic, and direct displacement mechanisms appear to operate competitively. Transposition of the olefin is equally effective for allylic alkoxides prepared by nucleophilic addition, deprotonation, or reduction. Experimentally, the niobium pentahalide halogenations are rapid, afford essentially pure (E)-allylic or -allenic halides after extraction, and are applicable to a range of aliphatic and aromatic alcohols, aldehydes, and ketones. PMID:19739606

  19. On the generation of large amplitude spiky solitons by ultralow frequency earthquake emission in the Van Allen radiation belt

    SciTech Connect

    Mofiz, U. A.

    2006-08-15

    The parametric coupling between earthquake emitted circularly polarized electromagnetic radiation and ponderomotively driven ion-acoustic perturbations in the Van Allen radiation belt is considered. A cubic nonlinear Schroedinger equation for the modulated radiation envelope is derived, and then solved analytically. For ultralow frequency earthquake emissions large amplitude spiky supersonic bright solitons or subsonic dark solitons are found to be generated in the Van Allen radiation belt, detection of which can be a tool for the prediction of a massive earthquake may be followed later.

  20. Use of a New Spirophosphine to Achieve Catalytic Enantioselective [4+1] Annulations of Amines with Allenes to Generate Dihydropyrroles

    PubMed Central

    Kramer, Søren; Fu, Gregory C.

    2015-01-01

    Due in part to the common occurrence of five-membered nitrogen heterocycles in bioactive molecules, the discovery of methods for the enantioselective synthesis of such structures is a useful endeavor. Building on a single example by Tong of a phosphine-catalyzed [4+1] annulation of an amine with an allene that furnished an achiral dihydropyrrole in 22% yield, we have developed, with the aid of a new chiral spirophosphine catalyst, a method with increased utility, specifically, improved yield, enhanced scope (the use of γ-substituted allenes), and good ee. The enantioenriched dihydropyrrole products can be transformed into other interesting families of compounds with very good stereoselectivity. PMID:25780940

  1. Spectroscopic studies of the fish fossils (Cladocyclus gardneri and Vinctifer comptoni) from the Ipubi Formation of the Cretaceous Period.

    PubMed

    Sousa Filho, F E; da Silva, J H; Saraiva, G D; Abagaro, B T O; Barros, O A; Saraiva, A A F; Viana, B C; Freire, P T C

    2016-03-15

    Fossils are mineralized remains or traces from animals, plants and other organisms aged to about 10(8)years. The chemical processes of fossilization are dated back from old geological periods on Earth. The understanding of these processes and the structure of the fossils are one of the goals of paleontology and geology in the sedimentary environments. Many researches have tried to unveil details about special kinds of biological samples; however, a lack of data is noticed for various other specimens. This study reports the investigations through infrared spectroscopy, X-ray fluorescence and X-ray diffraction measurements for two types of fish fossils from the Cretaceous Period. The sample of Cladocyclus gardneri and Vinctifer comptoni fossils were collected from the Ipubi Formation, being one of the less studied, among the formations that constitute the important Santana group in the Araripe Basin, Brazil. The results obtained through different techniques, showed that the C. gardneri fish fossil contains hydroxyapatite and calcite as constituents whereas its rock matrix was formed by calcite, quartz and pyrite. Regarding the V. comptoni, the measurements confirmed the presence of hydroxyapatite in the fossil and its rock matrix gypsum, pyrite, quartz and calcite. The above scientific data contributed to the understanding the fossil formation in the Ipubi Formation, an important environment of the Cretaceous Period, which is rich in well-preserved fossils from different species.

  2. Spectroscopic studies of the fish fossils (Cladocyclus gardneri and Vinctifer comptoni) from the Ipubi Formation of the Cretaceous Period

    NASA Astrophysics Data System (ADS)

    Sousa Filho, F. E.; da Silva, J. H.; Saraiva, G. D.; Abagaro, B. T. O.; Barros, O. A.; Saraiva, A. A. F.; Viana, B. C.; Freire, P. T. C.

    2016-03-01

    Fossils are mineralized remains or traces from animals, plants and other organisms aged to about 108 years. The chemical processes of fossilization are dated back from old geological periods on Earth. The understanding of these processes and the structure of the fossils are one of the goals of paleontology and geology in the sedimentary environments. Many researches have tried to unveil details about special kinds of biological samples; however, a lack of data is noticed for various other specimens. This study reports the investigations through infrared spectroscopy, X-ray fluorescence and X-ray diffraction measurements for two types of fish fossils from the Cretaceous Period. The sample of Cladocyclus gardneri and Vinctifer comptoni fossils were collected from the Ipubi Formation, being one of the less studied, among the formations that constitute the important Santana group in the Araripe Basin, Brazil. The results obtained through different techniques, showed that the C. gardneri fish fossil contains hydroxyapatite and calcite as constituents whereas its rock matrix was formed by calcite, quartz and pyrite. Regarding the V. comptoni, the measurements confirmed the presence of hydroxyapatite in the fossil and its rock matrix gypsum, pyrite, quartz and calcite. The above scientific data contributed to the understanding the fossil formation in the Ipubi Formation, an important environment of the Cretaceous Period, which is rich in well-preserved fossils from different species.

  3. Spectroscopic studies of the fish fossils (Cladocyclus gardneri and Vinctifer comptoni) from the Ipubi Formation of the Cretaceous Period.

    PubMed

    Sousa Filho, F E; da Silva, J H; Saraiva, G D; Abagaro, B T O; Barros, O A; Saraiva, A A F; Viana, B C; Freire, P T C

    2016-03-15

    Fossils are mineralized remains or traces from animals, plants and other organisms aged to about 10(8)years. The chemical processes of fossilization are dated back from old geological periods on Earth. The understanding of these processes and the structure of the fossils are one of the goals of paleontology and geology in the sedimentary environments. Many researches have tried to unveil details about special kinds of biological samples; however, a lack of data is noticed for various other specimens. This study reports the investigations through infrared spectroscopy, X-ray fluorescence and X-ray diffraction measurements for two types of fish fossils from the Cretaceous Period. The sample of Cladocyclus gardneri and Vinctifer comptoni fossils were collected from the Ipubi Formation, being one of the less studied, among the formations that constitute the important Santana group in the Araripe Basin, Brazil. The results obtained through different techniques, showed that the C. gardneri fish fossil contains hydroxyapatite and calcite as constituents whereas its rock matrix was formed by calcite, quartz and pyrite. Regarding the V. comptoni, the measurements confirmed the presence of hydroxyapatite in the fossil and its rock matrix gypsum, pyrite, quartz and calcite. The above scientific data contributed to the understanding the fossil formation in the Ipubi Formation, an important environment of the Cretaceous Period, which is rich in well-preserved fossils from different species. PMID:26745511

  4. Bayesian phylogenetic estimation of fossil ages

    PubMed Central

    Drummond, Alexei J.; Stadler, Tanja

    2016-01-01

    Recent advances have allowed for both morphological fossil evidence and molecular sequences to be integrated into a single combined inference of divergence dates under the rule of Bayesian probability. In particular, the fossilized birth–death tree prior and the Lewis-Mk model of discrete morphological evolution allow for the estimation of both divergence times and phylogenetic relationships between fossil and extant taxa. We exploit this statistical framework to investigate the internal consistency of these models by producing phylogenetic estimates of the age of each fossil in turn, within two rich and well-characterized datasets of fossil and extant species (penguins and canids). We find that the estimation accuracy of fossil ages is generally high with credible intervals seldom excluding the true age and median relative error in the two datasets of 5.7% and 13.2%, respectively. The median relative standard error (RSD) was 9.2% and 7.2%, respectively, suggesting good precision, although with some outliers. In fact, in the two datasets we analyse, the phylogenetic estimate of fossil age is on average less than 2 Myr from the mid-point age of the geological strata from which it was excavated. The high level of internal consistency found in our analyses suggests that the Bayesian statistical model employed is an adequate fit for both the geological and morphological data, and provides evidence from real data that the framework used can accurately model the evolution of discrete morphological traits coded from fossil and extant taxa. We anticipate that this approach will have diverse applications beyond divergence time dating, including dating fossils that are temporally unconstrained, testing of the ‘morphological clock', and for uncovering potential model misspecification and/or data errors when controversial phylogenetic hypotheses are obtained based on combined divergence dating analyses. This article is part of the themed issue ‘Dating species divergences

  5. Bayesian phylogenetic estimation of fossil ages.

    PubMed

    Drummond, Alexei J; Stadler, Tanja

    2016-07-19

    Recent advances have allowed for both morphological fossil evidence and molecular sequences to be integrated into a single combined inference of divergence dates under the rule of Bayesian probability. In particular, the fossilized birth-death tree prior and the Lewis-Mk model of discrete morphological evolution allow for the estimation of both divergence times and phylogenetic relationships between fossil and extant taxa. We exploit this statistical framework to investigate the internal consistency of these models by producing phylogenetic estimates of the age of each fossil in turn, within two rich and well-characterized datasets of fossil and extant species (penguins and canids). We find that the estimation accuracy of fossil ages is generally high with credible intervals seldom excluding the true age and median relative error in the two datasets of 5.7% and 13.2%, respectively. The median relative standard error (RSD) was 9.2% and 7.2%, respectively, suggesting good precision, although with some outliers. In fact, in the two datasets we analyse, the phylogenetic estimate of fossil age is on average less than 2 Myr from the mid-point age of the geological strata from which it was excavated. The high level of internal consistency found in our analyses suggests that the Bayesian statistical model employed is an adequate fit for both the geological and morphological data, and provides evidence from real data that the framework used can accurately model the evolution of discrete morphological traits coded from fossil and extant taxa. We anticipate that this approach will have diverse applications beyond divergence time dating, including dating fossils that are temporally unconstrained, testing of the 'morphological clock', and for uncovering potential model misspecification and/or data errors when controversial phylogenetic hypotheses are obtained based on combined divergence dating analyses.This article is part of the themed issue 'Dating species divergences using

  6. Bayesian phylogenetic estimation of fossil ages.

    PubMed

    Drummond, Alexei J; Stadler, Tanja

    2016-07-19

    Recent advances have allowed for both morphological fossil evidence and molecular sequences to be integrated into a single combined inference of divergence dates under the rule of Bayesian probability. In particular, the fossilized birth-death tree prior and the Lewis-Mk model of discrete morphological evolution allow for the estimation of both divergence times and phylogenetic relationships between fossil and extant taxa. We exploit this statistical framework to investigate the internal consistency of these models by producing phylogenetic estimates of the age of each fossil in turn, within two rich and well-characterized datasets of fossil and extant species (penguins and canids). We find that the estimation accuracy of fossil ages is generally high with credible intervals seldom excluding the true age and median relative error in the two datasets of 5.7% and 13.2%, respectively. The median relative standard error (RSD) was 9.2% and 7.2%, respectively, suggesting good precision, although with some outliers. In fact, in the two datasets we analyse, the phylogenetic estimate of fossil age is on average less than 2 Myr from the mid-point age of the geological strata from which it was excavated. The high level of internal consistency found in our analyses suggests that the Bayesian statistical model employed is an adequate fit for both the geological and morphological data, and provides evidence from real data that the framework used can accurately model the evolution of discrete morphological traits coded from fossil and extant taxa. We anticipate that this approach will have diverse applications beyond divergence time dating, including dating fossils that are temporally unconstrained, testing of the 'morphological clock', and for uncovering potential model misspecification and/or data errors when controversial phylogenetic hypotheses are obtained based on combined divergence dating analyses.This article is part of the themed issue 'Dating species divergences using

  7. Exploring the Relationship of Organizational Culture and Implicit Leadership Theory to Performance Differences in the Nuclear and Fossil Energy Industry

    NASA Astrophysics Data System (ADS)

    Cravey, Kristopher J.

    Notable performance differences exist between nuclear and fossil power generation plants in areas such as safety, outage duration efficiency, and capacity factor. This study explored the relationship of organizational culture and implicit leadership theory to these performance differences. A mixed methods approach consisting of quantitative instruments, namely the Organizational Culture Assessment Instrument and the GLOBE Leadership Scales, and qualitative interviews were used in this study. Subjects were operations middle managers in a U.S. energy company that serves nuclear or fossil power plants. Results from the quantitative instruments revealed no differences between nuclear and fossil groups in regards to organizational culture types and implicit leadership theories. However, the qualitative results did reveal divergence between the two groups in regards to what is valued in the organization and how that drives behaviors and decision making. These organizational phenomenological differences seem to explain why performance differences exist between nuclear and fossil plants because, ultimately, they affect how the organization functions.

  8. Single Nucleotide Polymorphisms in the Allene Oxide Synthase 2 Gene Are Associated With Field Resistance to Late Blight in Populations of Tetraploid Potato Cultivars

    PubMed Central

    Pajerowska-Mukhtar, Karolina; Stich, Benjamin; Achenbach, Ute; Ballvora, Agim; Lübeck, Jens; Strahwald, Josef; Tacke, Eckhard; Hofferbert, Hans-Reinhard; Ilarionova, Evgeniya; Bellin, Diana; Walkemeier, Birgit; Basekow, Rico; Kersten, Birgit; Gebhardt, Christiane

    2009-01-01

    The oomycete Phytophthora infestans causes late blight, the most relevant disease of potato (Solanum tuberosum) worldwide. Field resistance to late blight is a complex trait. When potatoes are cultivated under long day conditions in temperate climates, this resistance is correlated with late plant maturity, an undesirable characteristic. Identification of natural gene variation underlying late blight resistance not compromised by late maturity will facilitate the selection of resistant cultivars and give new insight in the mechanisms controlling quantitative pathogen resistance. We tested 24 candidate loci for association with field resistance to late blight and plant maturity in a population of 184 tetraploid potato individuals. The individuals were genotyped for 230 single nucleotide polymorphisms (SNPs) and 166 microsatellite alleles. For association analysis we used a mixed model, taking into account population structure, kinship, allele substitution and interaction effects of the marker alleles at a locus with four allele doses. Nine SNPs were associated with maturity corrected resistance (P < 0.001), which collectively explained 50% of the genetic variance of this trait. A major association was found at the StAOS2 locus encoding allene oxide synthase 2, a key enzyme in the biosynthesis of jasmonates, plant hormones that function in defense signaling. This finding supports StAOS2 as being one of the factors controlling natural variation of pathogen resistance. PMID:19139145

  9. Complete transfer of chirality in an intramolecular, thermal [2 + 2] cycloaddition of allene-ynes to form non-racemic spirooxindoles.

    PubMed

    Brummond, Kay M; Osbourn, Joshua M

    2011-01-01

    A thermal [2 + 2] cycloaddition reaction of allene-ynes has been used to transform chiral non-racemic allenyl oxindoles into chiral non-racemic spirooxindoles containing an alkylidene cyclobutene moiety. The enantiomeric excesses were determined by chiral lanthanide shift NMR analysis and the transfer of chiral information from the allene to the spirooxindole was found to be greater than 95%.

  10. Reply to David Kemmerer's "A Critique of Mark D. Allen's "The Preservation of Verb Subcategory Knowledge in a Spoken Language Comprehension Deficit""

    ERIC Educational Resources Information Center

    Allen, Mark D.; Owens, Tyler E.

    2008-01-01

    Allen [Allen, M. D. (2005). The preservation of verb subcategory knowledge in a spoken language comprehension deficit. "Brain and Language, "95, 255-264] presents evidence from a single patient, WBN, to motivate a theory of lexical processing and representation in which syntactic information may be encoded and retrieved independently of semantic…

  11. Spitzer Digs Up Galactic Fossil

    NASA Technical Reports Server (NTRS)

    2004-01-01

    [figure removed for brevity, see original site] Figure 1

    [figure removed for brevity, see original site] Figure 2

    This false-color image taken by NASA's Spitzer Space Telescope shows a globular cluster previously hidden in the dusty plane of our Milky Way galaxy. Globular clusters are compact bundles of old stars that date back to the birth of our galaxy, 13 or so billion years ago. Astronomers use these galactic 'fossils' as tools for studying the age and formation of the Milky Way.

    Most clusters orbit around the center of the galaxy well above its dust-enshrouded disc, or plane, while making brief, repeated passes through the plane that each last about a million years. Spitzer, with infrared eyes that can see into the dusty galactic plane, first spotted the newfound cluster during its current pass. A visible-light image (inset of Figure 1) shows only a dark patch of sky.

    The red streak behind the core of the cluster is a dust cloud, which may indicate the cluster's interaction with the Milky Way. Alternatively, this cloud may lie coincidentally along Spitzer's line of sight.

    Follow-up observations with the University of Wyoming Infrared Observatory helped set the distance of the new cluster at about 9,000 light-years from Earth - closer than most clusters - and set the mass at the equivalent of 300,000 Suns. The cluster's apparent size, as viewed from Earth, is comparable to a grain of rice held at arm's length. It is located in the constellation Aquila.

    Astronomers believe that this cluster may be one of the last in our galaxy to be uncovered.

    This image composite was taken on April 21, 2004, by Spitzer's infrared array camera. It is composed of images obtained at four wavelengths: 3.6 microns (blue), 4.5 microns (green), 5.8 microns (orange) and 8 microns (red).

    Galactic Fossil Found Behind Curtain of Dust In Figure 2, the image mosaic shows the same patch of sky in various wavelengths of light. While the

  12. A Fossil Group in Formation

    NASA Astrophysics Data System (ADS)

    Miller, Eric D.; Rappaport, Saul A.; McDonald, Michael; Bautz, Mark W.; Grant, Catherine E.; Veilleux, Sylvain

    2016-04-01

    In the current picture of hierarchical structure formation, galaxy groups play a vital role as the seeds from which large assemblies of matter form. Compact groups are also important environments in which to watch the fueling of star formation and AGN activity, as the conditions are ideal for galaxy-galaxy interactions. We have identified a galaxy system that may represent an intermediate or transition stage in group evolution. Shakhbazyan 1 (or SHK 1) is a remarkably compact collection of about ten massive, red-sequence galaxies within a region 100 kpc across. Several of these galaxies show signs of AGN activity, and new, deep optical observations with the Discovery Channel Telescope reveal an extended stellar envelope surrounding the galaxies. This envelope is much more extended than what would be expected from a superposition of normal galaxy envelopes, and it indicates a large amount of intra-group starlight, evidence that the galaxies in SHK 1 are dynamically interacting.We here present new Chandra spectral imaging observations of this unusual system that confirm the presence of an X-ray-emitting diffuse intra-group medium (IGM), with a temperature of 1.5 keV and X-ray luminosity of 1043 erg/s. Assuming hydrostatic equilibrium, the system is about 1/3 as massive as expected from the optical richness. In addition, three of the ten central galaxies exhibit signatures of X-ray AGN. The under-luminous IGM, high density of bright galaxies, and evidence for galaxy-galaxy interaction indicate that this system may be in a transition stage of galaxy merging, similar to that expected in the formation of a fossil group. Alternatively, SHK 1 may consist of multiple poor groups in the final stages of merging along our line of sight. We explore these scenarios and outline paths of future study for this enigmatic system.

  13. Fossil Finds Expand Early Hominid Anatomy.

    ERIC Educational Resources Information Center

    Bower, B.

    1991-01-01

    Hominid fossils found in late 1990 in Ethiopia are reported. A controversy surrounding these remains and those of earlier expeditions, including Lucy, over whether more than one species of hominid are represented is discussed. (CW)

  14. Microbial Fossils Detected in Desert Varnish

    NASA Astrophysics Data System (ADS)

    Flood, B. E.; Allen, C.; Longazo, T.

    2003-03-01

    Desert varnish, a mixture of clays, Mn-oxides, and Fe-oxides, is a potential terrestrial analogue to Martian hematite. A scanning electron microscopic examination of samples from Pilbara, Australia revealed evidence of microbial fossilization.

  15. Evolution: Fossil Ears and Underwater Sonar.

    PubMed

    Lambert, Olivier

    2016-08-22

    A key innovation in the history of whales was the evolution of a sonar system together with high-frequency hearing. Fossils of an archaic toothed whale's inner ear bones provide clues for a stepwise emergence of underwater echolocation ability.

  16. Development incentives for fossil fuel subsidy reform

    NASA Astrophysics Data System (ADS)

    Jakob, Michael; Chen, Claudine; Fuss, Sabine; Marxen, Annika; Edenhofer, Ottmar

    2015-08-01

    Reforming fossil fuel subsidies could free up enough funds to finance universal access to water, sanitation, and electricity in many countries, as well as helping to cut global greenhouse-gas emissions.

  17. Fossil fuels in the 21st century.

    PubMed

    Lincoln, Stephen F

    2005-12-01

    An overview of the importance of fossil fuels in supplying the energy requirements of the 21st century, their future supply, and the impact of their use on global climate is presented. Current and potential alternative energy sources are considered. It is concluded that even with substantial increases in energy derived from other sources, fossil fuels will remain a major energy source for much of the 21st century and the sequestration of CO2 will be an increasingly important requirement.

  18. Fossil facies of the Greater Caspian region

    NASA Astrophysics Data System (ADS)

    Svitoch, A. A.

    2015-05-01

    The Pliocene-Pleistocene marine sediments of the Great Caspian region host various lithological fossil facies, which reflect specific sedimentation conditions caused by different structural-geomorphologic settings, tectonic regimes, climates, and hydrologies. The facies of shelf, epicontinental basins, ingression gulfs and estuaries, intermontane and mountainous basins, and deep-sea depressions form a hierarchy of geological bodies from types to subtypes. Paragenetic associations of fossil facies, which form various series in space and along the section, are typical of marine sediments.

  19. Comparison of species-resolved energy spectra from ACE EPAM and Van Allen Probes RBSPICE

    NASA Astrophysics Data System (ADS)

    Patterson, J.; Manweiler, J. W.; Armstrong, T. P.; Lanzerotti, L. J.; Gerrard, A. J.; Gkioulidou, M.

    2013-12-01

    We present a comparison between energy spectra measured by the Advanced Composition Explorer (ACE) Electron Proton Alpha Monitor (EPAM) instrument and the Van Allen Probe Ion Composition Experiment (RBSPICE) for two significant and distinct events in early 2013. The first is an impulsive solar particle event on March 17th. While intense, this event presented no significant surprises in terms of its composition or anisotropy characteristics, thus providing a good baseline for response of the trapped radiation belts as observed by the Van Allen Probes. The second solar event occurred late May 22nd and early May 23rd. This event has a much greater concentration of medium and heavy ions than the St. Patrick's Day event, as well as having very peculiar energy spectra with evidence of two distinct populations. During the St. Patrick's Day Event, the energy spectra for helium, carbon, oxygen, neon, silicon, and iron all show the same spectral power law slope -3.1. The event shows strong anisotropy with intensities differing by a factor of four for both protons and Z>1 ions. The late May event also has strong anisotropy, and in the same directions as the St. Patrick's Day Event, but with very different composition and energy spectra. The spectra are much harder with power law spectral slopes of -0.5. Additionally, there is a significant spectral bump at 3 MeV/nuc for helium that is not present in the spectra of the heavier ions. The intensities of the heavier ions, however, show an increase that is an order of magnitude greater than the increase seen for helium. The March 17 RBSPICE observations show multiple injection events lasting for less than an hour each during the Van Allen Probes B apogees. These injections are seen in protons as well as Helium and only somewhat observed in Oxygen. Spectral slopes for the observations range from approximately -5 during quiet times to double peaked events with a spectral slope of approximately -2 at the beginning of the injection

  20. Reconciling molecular phylogenies with the fossil record.

    PubMed

    Morlon, Hélène; Parsons, Todd L; Plotkin, Joshua B

    2011-09-27

    Historical patterns of species diversity inferred from phylogenies typically contradict the direct evidence found in the fossil record. According to the fossil record, species frequently go extinct, and many clades experience periods of dramatic diversity loss. However, most analyses of molecular phylogenies fail to identify any periods of declining diversity, and they typically infer low levels of extinction. This striking inconsistency between phylogenies and fossils limits our understanding of macroevolution, and it undermines our confidence in phylogenetic inference. Here, we show that realistic extinction rates and diversity trajectories can be inferred from molecular phylogenies. To make this inference, we derive an analytic expression for the likelihood of a phylogeny that accommodates scenarios of declining diversity, time-variable rates, and incomplete sampling; we show that this likelihood expression reliably detects periods of diversity loss using simulation. We then study the cetaceans (whales, dolphins, and porpoises), a group for which standard phylogenetic inferences are strikingly inconsistent with fossil data. When the cetacean phylogeny is considered as a whole, recently radiating clades, such as the Balaneopteridae, Delphinidae, Phocoenidae, and Ziphiidae, mask the signal of extinctions. However, when isolating these groups, we infer diversity dynamics that are consistent with the fossil record. These results reconcile molecular phylogenies with fossil data, and they suggest that most extant cetaceans arose from four recent radiations, with a few additional species arising from clades that have been in decline over the last ~10 Myr. PMID:21930899

  1. Advanced Researech and Technology Development fossil energy materials program: Semiannual progress report for the period ending September 30, 1988

    SciTech Connect

    Not Available

    1989-01-01

    The objective of the ARandTD Fossil Energy Materials Program is to conduct research and development on materials for fossil energy applications with a focus on the longer-term and generic needs of the various fossil fuel technologies. The program includes research aimed toward a better understanding of materials behavior in fossil energy environments and the development of new materials capable of substantial enhancement of plant operations and reliability. The ORNL Fossil Energy Materials Program Office compiles and issues this combined semiannual progress report from camera-ready copies submitted by each of the participating subcontractor organizations. This report of activities on the program is organized in accordance with a work breakdown structure in which projects are organized according to materials research thrust areas. These areas are (1) Structural Ceramics, (2) Alloy Development and Mechanical Properties, (3) Corrosion and Erosion of Alloys, and (4) Assessments and Technology Transfer. Individual projects are processed separately for the data bases.

  2. Dialogic Considerations of Confrontation as a Counseling Activity: An Examination of Allen Ivey's Use of Confronting as a Microskill

    ERIC Educational Resources Information Center

    Strong, Tom; Zeman, Don

    2010-01-01

    The authors examine confrontation as a communication skill practiced and described by counselor educator Allen Ivey. Seeing confrontation as a dialogic activity completed interactionally, they use conversation analysis to examine 2 passages where Ivey used confrontation in his teaching tapes. Their microanalyses highlight some important and…

  3. Frontiers in Laser Cooling, Single-Molecule Biophysics, and Enrgy Science: A Talk from Leo Holberg and Allen Mills

    ScienceCinema

    Holberg, Leo; Mills, Allen [NIST

    2016-07-12

    Leo Holberg and Allen Mills present a talk at Frontiers in Laser Cooling, Single-Molecule Biophysics and Energy Science, a scientific symposium honoring Steve Chu, director of Lawrence Berkeley National Laboratory and recipient of the 1997 Nobel Prize in Physics. The symposium was held August 30, 2008 in Berkeley.

  4. Expression of concern: A unifying mechanism for the rearrangement of vinyl allene oxide geometric isomers to cyclopentenones.

    PubMed

    Kelly, Richard

    2015-12-21

    Expression of concern for 'A unifying mechanism for the rearrangement of vinyl allene oxide geometric isomers to cyclopentenones' by Adán B. González-Pérez et al., Org. Biomol. Chem., 2014, 12, 7694-7701. PMID:26575412

  5. Van Allen Probes, NOAA, and Ground Observations of an Intense Pc 1 Wave Event Extending 12 Hours in MLT

    NASA Astrophysics Data System (ADS)

    Engebretson, M. J.; Posch, J. L.; Wygant, J. R.; Kletzing, C.; Lessard, M.; Horne, R. B.; Reeves, G. D.; Gkioulidou, M.; Fennell, J.; Oksavik, K.; Raita, T.

    2014-12-01

    On February 23, 2014 a Pc 1 wave event extending 8 hours in UT and 12 hours in MLT was observed at Halley, Antarctica and Ivalo, Finland in the dawn sector, and by both Van Allen Probes spacecraft from late morning through local noon. The wave activity was stimulated by a gradual 4-hour rise and subsequent sharp increases in solar wind pressure. Intense hydrogen band, linearly polarized Pc 1 wave activity (up to 25 nT p-p) with very similar time variations also appeared for over 4 hours at both Van Allen Probes, located ~8 and ~9 hours east of Halley. Waves appeared when these spacecraft were outside the plasmapause, with densities ~5-20 cm-3. Ten passes of NOAA-POES and METOP satellites near the northern hemisphere footpoint of the Van Allen Probes (over Siberia) show the presence of 30-80 keV subauroral proton precipitation. This is the longest-duration and most intense Pc1 event we have yet observed with the Van Allen Probes. The combination of its duration, intensity, and large local time extent (from before 02 to nearly 14 hours MLT) suggests that it might have a significant effect on the ring current, and possibly even electrons in the outer radiation belt.

  6. Dehydrogenative [2 + 2 + 2] Cycloaddition of Cyano-yne-allene Substrates: Convenient Access to 2,6-Naphthyridine Scaffolds.

    PubMed

    Haraburda, Ewelina; Lledó, Agustí; Roglans, Anna; Pla-Quintana, Anna

    2015-06-19

    A rhodium-catalyzed [2 + 2 + 2] cycloaddition of cyano-yne-allene scaffolds followed by a dehydrogenative process enabling the direct synthesis of unsaturated pyridine-containing compounds that can be conveniently converted to 2,6-naphthyridine derivatives is reported.

  7. Remarkable new results for high-energy protons and electrons in the inner Van Allen belt regions

    NASA Astrophysics Data System (ADS)

    Baker, Daniel N.

    2016-04-01

    Early observations indicated that the Earth's Van Allen radiation belts could be separated into an inner zone dominated by high-energy protons and an outer zone dominated by high-energy electrons. Subsequent studies showed that electrons of moderate energy (less than about one megaelectronvolt) often populate both zones, with a deep 'slot' region largely devoid of particles between them. The two-belt radiation structure was explained as arising from strong electron interactions with plasmaspheric hiss just inside the plasmapause boundary with the inner edge of the outer radiation zone corresponding to the minimum plasmapause location.. Recent Van Allen Probes observations have revealed an unexpected radiation belt morphology, especially at ultrarelativistic kinetic energies (more than several megaelectronvolts). The data show an exceedingly sharp inner boundary for the ultrarelativistic electrons right at L=2.8. Additional, concurrently measured data reveal that this barrier to inward electron radial transport is likely due to scattering by powerful human electromagnetic transmitter (VLF) wave fields. We show that weak, but persistent, wave-particle pitch angle scattering deep inside the Earth's plasmasphere due to manmade signals can act to create an almost impenetrable barrier through which the most energetic Van Allen belt electrons cannot migrate. Inside of this distance, the Van Allen Probes data show that high energy (20 -100 MeV) protons have a double belt structure with a stable peak of flux at L~1.5 and a much more variable belt peaking at L~2.3.

  8. Choctaw Leadership in Oklahoma: The Allen Wright Family and Education in the Nineteenth and Early Twentieth Centuries

    ERIC Educational Resources Information Center

    Noley, Grayson; Smith, Joan K.; Vaughn, Courtney; Cesar, Dana

    2009-01-01

    Against the backdrop of internal colonialism, this article examines the educational and social lives of Allen Wright and his children to better understand how this Choctaw family successfully navigated the pressures of dual cultures by: (1) providing the socio-political context of the indigenous culture prior to Wright's birth; (2) chronicling and…

  9. Fossil group origins - VI. Global X-ray scaling relations of fossil galaxy clusters

    NASA Astrophysics Data System (ADS)

    Kundert, A.; Gastaldello, F.; D'Onghia, E.; Girardi, M.; Aguerri, J. A. L.; Barrena, R.; Corsini, E. M.; De Grandi, S.; Jiménez-Bailón, E.; Lozada-Muñoz, M.; Méndez-Abreu, J.; Sánchez-Janssen, R.; Wilcots, E.; Zarattini, S.

    2015-11-01

    We present the first pointed X-ray observations of 10 candidate fossil galaxy groups and clusters. With these Suzaku observations, we determine global temperatures and bolometric X-ray luminosities of the intracluster medium (ICM) out to r500 for six systems in our sample. The remaining four systems show signs of significant contamination from non-ICM sources. For the six objects with successfully determined r500 properties, we measure global temperatures in the range 2.8 ≤ TX ≤ 5.3 keV, bolometric X-ray luminosities of 0.8 × 1044 ≤ LX, bol ≤ 7.7 × 1044 erg s-1, and estimate masses, as derived from TX, of M500 ≳ 1014 M⊙. Fossil cluster scaling relations are constructed for a sample that combines our Suzaku observed fossils with fossils in the literature. Using measurements of global X-ray luminosity, temperature, optical luminosity, and velocity dispersion, scaling relations for the fossil sample are then compared with a control sample of non-fossil systems. We find the fits of our fossil cluster scaling relations are consistent with the relations for normal groups and clusters, indicating fossil clusters have global ICM X-ray properties similar to those of comparable mass non-fossil systems.

  10. Fossil group origins. IV. Characterization of the sample and observational properties of fossil systems

    NASA Astrophysics Data System (ADS)

    Zarattini, S.; Barrena, R.; Girardi, M.; Castro-Rodriguez, N.; Boschin, W.; Aguerri, J. A. L.; Méndez-Abreu, J.; Sánchez-Janssen, R.; Catalán-Torrecilla, C.; Corsini, E. M.; del Burgo, C.; D'Onghia, E.; Herrera-Ruiz, N.; Iglesias-Páramo, J.; Jimenez Bailon, E.; Lozada Muoz, M.; Napolitano, N.; Vilchez, J. M.

    2014-05-01

    Context. Virialized halos grow by the accretion of smaller ones in the cold dark matter scenario. The rate of accretion depends on the different properties of the host halo. Those halos for which this accretion rate was very fast and efficient resulted in systems dominated by a central galaxy surrounded by smaller galaxies that were at least two magnitudes fainter. These galaxy systems are called fossil systems, and they can be the fossil relics of ancient galaxy structures. Aims: We started an extensive observational program to characterize a sample of 34 fossil group candidates spanning a broad range of physical properties. Methods: Deep r-band images were obtained with the 2.5-m Isaac Newton Telescope and Nordic Optic Telescope. Optical spectroscopic observations were performed at the 3.5-m Telescopio Nazionale Galileo for ~1200 galaxies. This new dataset was completed with Sloan Digital Sky Survey Data Release 7 archival data to obtain robust cluster membership and global properties of each fossil group candidate. For each system, we recomputed the magnitude gaps between the two brightest galaxies (Δm12) and the first and fourth ranked galaxies (Δm14) within 0.5 R200. We consider fossil systems to be those with Δm12 ≥ 2 mag or Δm14 ≥ 2.5 mag within the errors. Results: We find that 15 candidates turned out to be fossil systems. Their observational properties agree with those of non-fossil systems. Both follow the same correlations, but the fossil systems are always extreme cases. In particular, they host the brightest central galaxies, and the fraction of total galaxy light enclosed in the brightest group galaxy is larger in fossil than in non-fossil systems. Finally, we confirm the existence of genuine fossil clusters. Conclusions: Combining our results with others in the literature, we favor the merging scenario in which fossil systems formed from mergers of L∗ galaxies. The large magnitude gap is a consequence of the extreme merger ratio within

  11. Wave-driven butterfly distribution of Van Allen belt relativistic electrons

    PubMed Central

    Xiao, Fuliang; Yang, Chang; Su, Zhenpeng; Zhou, Qinghua; He, Zhaoguo; He, Yihua; Baker, D. N.; Spence, H. E.; Funsten, H. O.; Blake, J. B.

    2015-01-01

    Van Allen radiation belts consist of relativistic electrons trapped by Earth's magnetic field. Trapped electrons often drift azimuthally around Earth and display a butterfly pitch angle distribution of a minimum at 90° further out than geostationary orbit. This is usually attributed to drift shell splitting resulting from day–night asymmetry in Earth's magnetic field. However, direct observation of a butterfly distribution well inside of geostationary orbit and the origin of this phenomenon have not been provided so far. Here we report high-resolution observation that a unusual butterfly pitch angle distribution of relativistic electrons occurred within 5 Earth radii during the 28 June 2013 geomagnetic storm. Simulation results show that combined acceleration by chorus and magnetosonic waves can successfully explain the electron flux evolution both in the energy and butterfly pitch angle distribution. The current provides a great support for the mechanism of wave-driven butterfly distribution of relativistic electrons. PMID:26436770

  12. Van Allen Probes observations of oxygen cyclotron harmonic waves in the inner magnetosphere

    NASA Astrophysics Data System (ADS)

    Usanova, M. E.; Malaspina, D. M.; Jaynes, A. N.; Bruder, R. J.; Mann, I. R.; Wygant, J. R.; Ergun, R. E.

    2016-09-01

    Waves with frequencies in the vicinity of the oxygen cyclotron frequency and its harmonics have been regularly observed on the Van Allen Probes satellites during geomagnetic storms. We focus on properties of these waves and present events from the main phase of two storms on 1 November 2012 and 17 March 2013 and associated dropouts of a few MeV electron fluxes. They are electromagnetic, in the frequency range ~0.5 to several Hz, and amplitude ~0.1 to a few nT in magnetic and ~0.1 to a few mV/m in electric field, with both the wave velocity and the Poynting vector directed almost parallel to the background magnetic field. These properties are very similar to those of electromagnetic ion cyclotron waves, which are believed to contribute to loss of ring current ions and radiation belt electrons and therefore can be also important for inner magnetosphere dynamics.

  13. Fractional Cahn-Hilliard, Allen-Cahn and porous medium equations

    NASA Astrophysics Data System (ADS)

    Akagi, Goro; Schimperna, Giulio; Segatti, Antonio

    2016-09-01

    We introduce a fractional variant of the Cahn-Hilliard equation settled in a bounded domain Ω ⊂RN and complemented with homogeneous Dirichlet boundary conditions of solid type (i.e., imposed in the whole of RN ∖ Ω). After setting a proper functional framework, we prove existence and uniqueness of weak solutions to the related initial-boundary value problem. Then, we investigate some significant singular limits obtained as the order of either of the fractional Laplacians appearing in the equation is let tend to 0. In particular, we can rigorously prove that the fractional Allen-Cahn, fractional porous medium, and fractional fast-diffusion equations can be obtained in the limit. Finally, in the last part of the paper, we discuss existence and qualitative properties of stationary solutions of our problem and of its singular limits.

  14. Real-time beamforming using high-speed FPGAs at the Allen Telescope Array

    NASA Astrophysics Data System (ADS)

    Barott, William C.; Milgrome, Oren; Wright, Melvyn; MacMahon, David; Kilsdonk, Tom; Backus, Peter; Dexter, Matt

    2011-02-01

    The Allen Telescope Array (ATA) at the Hat Creek Radio Observatory (HCRO) is a wide-field panchromatic radio telescope currently consisting of 42 offset-Gregorian antennas each with a 6 m aperture, with plans to expand the array to 350 antennas. Through unique back-end hardware, the ATA performs real-time wideband beamforming with independent subarray capabilities and customizable beam shaping. The beamformers enable science observations requiring the full gain of the array, time domain (nonintegrated) output, and interference excision or orthogonal beamsets. In this paper we report on the design of this beamformer, including architecture and experimental results. Furthermore, we address some practical considerations in large-N wideband beamformers implemented on field programmable gate array platforms, including device utilization, methods of calibration and control, and interchip synchronization.

  15. Five Years of SETI with the Allen Telescope Array: Lessons Learned

    NASA Astrophysics Data System (ADS)

    Harp, Gerald

    2016-01-01

    We discuss recent observations at the Allen Telescope Array (ATA) supporting a wide ranging Search for Extraterrestrial Intelligence (SETI). The ATA supports observations over the frequency range 1-10 GHz with three simultaneous phased array beams used in an anticoincidence detector for false positive rejection. Here we summarize observational results over the years 2011-2015 covering multiple campaigns of exoplanet stars, the galactic plane, infrared excess targets, etc. Approximately 2 x 108 signals were identified and classified over more than 5000 hours of observation. From these results we consider various approaches to the rapid identification of human generated interference in the process of the search for a signal with origins outside the radius of the Moon's orbit. We conclude that the multi-beam technique is superb tool for answering the very difficult question of the direction of origin of signals. Data-based simulations of future instruments with more than 3 beams are compared.

  16. Van Allen Probes Multipoint Measurements of the Spatial and Coherence Scales of EMIC Waves

    NASA Astrophysics Data System (ADS)

    Blum, L. W.; Bonnell, J. W.; Agapitov, O. V.; Bortnik, J.

    2015-12-01

    Electromagnetic ion cyclotron (EMIC) waves are able to resonate with MeV electrons and cause precipitation loss of radiation belt electrons. EMIC waves can provide a strong source of electron pitch angle diffusion, but the waves are often quite localized - thus the spatial extents of these waves can have a large effect on their overall scattering efficiency. Using measurements from the Van Allen Probes, we characterize the spatial extents of EMIC wave active regions, and how these depend on local time, radial distance, and driver. As the separation between the spacecraft along the orbital track varies in time, with one spacecraft lapping the other every ~70 days, we can determine the correlation between EMIC wave measurements at varying spacecraft separations. During individual events at close approaches (Jan 17 2013, for example - see attached figure), analysis of the detailed wave properties and coherence is performed. These studies provide important information on parameters relevant for determining resonance of EMIC waves with radiation belt electrons.

  17. Penetration of magnetosonic waves into the plasmasphere observed by the Van Allen Probes

    NASA Astrophysics Data System (ADS)

    Xiao, F.; Zhou, Q.; He, Y.; Yang, C.; Liu, S.; Baker, D. N.; Spence, H. E.; Reeves, G. D.; Funsten, H. O.; Blake, J. B.

    2015-12-01

    During the small storm on 14-15 April 2014, Van Allen Probe A measured a continuously distinct proton ring distribution and enhanced magnetosonic (MS) waves along their orbit outside the plasmapause. Inside the plasmasphere, strong MS waves were still present but the distinct proton ring distribution was falling steeply with distance. We adopt a sum of subtracted bi-Maxwellian components to model the observed proton ring distribution and simulate the wave trajectory and growth. MS waves at first propagate towards lower L-shells outside the plasmasphere, with rapidly increasing path gains related to the continuous proton ring distribution. Then they gradually cross the plasmapause into the deep plasmasphere, with almost unchanged path gains due to the falling proton ring distribution and higher ambient density. These results present the first report on how MS waves penetrate into the plasmasphere with aid of the continuous proton ring distributions during weak geomagnetic activities.

  18. Crossed molecular beam study of the reaction O([sup 3][ital P])+allene

    SciTech Connect

    Schmoltner, A.M.; Huang, S.Y.; Brudzynski, R.J.; Chu, P.M.; Lee, Y.T. )

    1993-08-01

    The reaction between ground state ([sup 3][ital P]) oxygen atoms and allene was studied under single collision conditions using the crossed molecular beams method. Product angular distributions and the translational energy distribution were determined for each channel. Two major reaction channels could be identified unambiguously: the formation of carbon monoxide and ethylene following oxygen atom attack on the central carbon atom, and the formation of allenyloxy (formyl--vinyl) radical and hydrogen atom following oxygen atom attack on the terminal carbon atom. In addition, at least one other reaction channel, which could be identified as the production of vinyl and formyl radicals, occurs. This channel involves the decomposition of acrolein which is formed by the addition of oxygen to the terminal carbon atom, followed by 1,2-hydrogen migration.

  19. Convection Electric Field Observations by THEMIS and the Van Allen Probes

    NASA Astrophysics Data System (ADS)

    Califf, S.; Li, X.; Bonnell, J. W.; Wygant, J. R.; Malaspina, D.; Hartinger, M.; Thaller, S. A.

    2013-12-01

    We present direct electric field measurements made by THEMIS and the Van Allen Probes in the inner magnetosphere, focusing on the large-scale, near-DC convection electric field. The convection electric field drives plasma Earthward from the tail into the inner magnetosphere, playing a critical role in forming the ring current. Although it is normally shielded deep inside the magnetosphere, during storm times this large-scale electric field can penetrate to low L values (L < 3), eroding the plasmasphere and also providing a mechanism for ~100 keV electron injection into the slot region and inner radiation belt. The relationship of the convection electric field with the plasmasphere is also important for understanding the dynamic outer radiation belt, as the plasmapause boundary has been strongly correlated with the dynamic variation of the outer radiation belt electrons.

  20. Wave-driven butterfly distribution of Van Allen belt relativistic electrons

    SciTech Connect

    Xiao, Fuliang; Yang, Chang; Su, Zhenpeng; Zhou, Qinghua; He, Zhaoguo; He, Yihua; Baker, D. N.; Spence, H. E.; Funsten, H. O.; Blake, J. B.

    2015-10-05

    Van Allen radiation belts consist of relativistic electrons trapped by Earth's magnetic field. Trapped electrons often drift azimuthally around Earth and display a butterfly pitch angle distribution of a minimum at 90° further out than geostationary orbit. This is usually attributed to drift shell splitting resulting from day–night asymmetry in Earth’s magnetic field. However, direct observation of a butterfly distribution well inside of geostationary orbit and the origin of this phenomenon have not been provided so far. Here we report high-resolution observation that a unusual butterfly pitch angle distribution of relativistic electrons occurred within 5 Earth radii during the 28 June 2013 geomagnetic storm. In conclusion, simulation results show that combined acceleration by chorus and magnetosonic waves can successfully explain the electron flux evolution both in the energy and butterfly pitch angle distribution. Finally, the current provides a great support for the mechanism of wave-driven butterfly distribution of relativistic electrons.

  1. Wave-driven butterfly distribution of Van Allen belt relativistic electrons.

    PubMed

    Xiao, Fuliang; Yang, Chang; Su, Zhenpeng; Zhou, Qinghua; He, Zhaoguo; He, Yihua; Baker, D N; Spence, H E; Funsten, H O; Blake, J B

    2015-01-01

    Van Allen radiation belts consist of relativistic electrons trapped by Earth's magnetic field. Trapped electrons often drift azimuthally around Earth and display a butterfly pitch angle distribution of a minimum at 90° further out than geostationary orbit. This is usually attributed to drift shell splitting resulting from day-night asymmetry in Earth's magnetic field. However, direct observation of a butterfly distribution well inside of geostationary orbit and the origin of this phenomenon have not been provided so far. Here we report high-resolution observation that a unusual butterfly pitch angle distribution of relativistic electrons occurred within 5 Earth radii during the 28 June 2013 geomagnetic storm. Simulation results show that combined acceleration by chorus and magnetosonic waves can successfully explain the electron flux evolution both in the energy and butterfly pitch angle distribution. The current provides a great support for the mechanism of wave-driven butterfly distribution of relativistic electrons.

  2. EMIC wave spatial and coherence scales as determined from multipoint Van Allen Probe measurements

    NASA Astrophysics Data System (ADS)

    Blum, L. W.; Agapitov, O.; Bonnell, J. W.; Kletzing, C.; Wygant, J.

    2016-05-01

    Electromagnetic ion cyclotron (EMIC) waves can provide a strong source of energetic electron pitch angle scattering. These waves are often quite localized, thus their spatial extent can have a large effect on their overall scattering efficiency. Using measurements from the dual Van Allen Probes, we examine four EMIC wave events observed simultaneously on the two probes at varying spacecraft separations. Correlation of both the wave amplitude and phase observed at both spacecraft is examined to estimate the active region and coherence scales of the waves. We find well-correlated wave amplitude and amplitude modulation across distances spanning hundreds to thousands of kilometers. Phase coherence persisting 30-60 s is observable during close conjunction events but is lost as spacecraft separations exceed ~1 Earth Radii.

  3. Inner zone electron radial diffusion coefficients - An update with Van Allen Probes MagEIS data

    NASA Astrophysics Data System (ADS)

    O'Brien, Paul; Fennell, Joseph; Guild, Timothy; Mazur, Joseph; Claudepierre, Seth; Clemmons, James; Turner, Drew; Blake, Bernard; Roeder, James

    2016-07-01

    Using MagEIS data from NASA's recent Van Allen Probes mission, we estimate the quiet-time radial diffusion coefficients for electrons in the inner radiation belt and slot, for energies up to ~700 keV. We provide observational evidence that energy diffusion is negligible. The main dynamic processes, then, are radial diffusion and elastic pitch angle scattering. We use a coordinate system in which these two modes of diffusion are separable. Then we integrate over pitch angle to obtain a field line content whose dynamics consist of radial diffusion and loss to the atmosphere. We estimate the loss timescale from periods of exponential decay in the time series. We then estimate the radial diffusion coefficient from the temporal and radial variation of the field line content. We show that our diffusion coefficients agree well with previously determined values. Our coefficients are consistent with diffusion by electrostatic impulses, whereas outer zone radial diffusion is thought to be dominated by electromagnetic fluctuations.

  4. "Her mouth is medicine": Beth Brant and Paula Gunn Allen's decolonizing queer erotics.

    PubMed

    Burford, Arianne

    2013-01-01

    This article asserts the need to recognize the complexity of the theoretical work of more lesbian Native American writers, focusing specifically Beth Brant (Bay of Quinte Mohawk) and Paula Gunn Allen (Laguna Pueblo). Their poetry and short stories provide a theoretically nuanced analysis of how heteronormativity is intertwined in and dependent on colonialism, and thus a methodology for Queer Theory that requires an understanding of it in relation to colonialism. They reject heteronormative Pocahontas fantasies about Native women, offering a lesbian-based tactic for decolonization through the expression of erotic desire. This article demonstrates the endless possibilities for fierce queer resistance, revolutionary change, and healing from the trauma of genocide and the accompanying colonialist heteropatriarchal disciplining of Native women's bodies.

  5. Computational and experimental investigations of the formal dyotropic rearrangements of Himbert arene/allene cycloadducts.

    PubMed

    Pham, Hung V; Karns, Alexander S; Vanderwal, Christopher D; Houk, K N

    2015-06-01

    The fascinating intramolecular arene/allene cycloaddition discovered by Himbert affords dearomatized, polycyclic intermediates with sufficient strain energy to drive rearrangement processes of the newly formed ring system. We disclose a detailed examination of a thermally induced stepwise dyotropic skeletal rearrangement of these cycloadducts, a reaction also first described by Himbert. We offer computational evidence for a two-stage mechanism for this formal dyotropic rearrangement and provide rationalizations for the significant substitution-dependent rate differences observed in experiments. These investigations led to the development of a Lewis-acid-catalyzed rearrangement of precursors that were unreactive under simple thermal instigation. The isolation of the product of an "interrupted" rearrangement under Lewis acidic conditions provides further support for the proposed stepwise mechanism. Computational results also matched experiments in terms of regiochemical preferences in unsymmetrical rearrangement precursors and explained why lactam O-, S-, and C-heterologues do not easily undergo this rearrangement.

  6. Variability of the Inner Proton Radiation Belt Observed by Van Allen Probes

    NASA Astrophysics Data System (ADS)

    Li, X.; Selesnick, R.; Baker, D. N.; Jaynes, A. N.; Kanekal, S. G.; Hudson, M. K.; Kress, B. T.

    2015-12-01

    Inner radiation belt protons with kinetic energy above 10 MeV are known to be highly stable, with a maximum intensity near L = 1.5 that varies little evenon solar-cycle time scales. However, for L = 2 and above, more rapid changes occur: (1) protons are trapped during solar particle events, (2) steady intensity changes near L = 2 may result from radial diffusion, (3) for L > 2 there are rapid losses during magnetic storms, and (4) the losses are replenished by albedo neutron decay. New measurements from Van Allen Probes describe each of the last three processes in detail (the first has not yet been observed). These data provide new constraints on theories of trapped proton dynamics and improved empirical estimates of transport coefficients for radiation belt modeling.

  7. The Unique Capabilities of the Allen Telescope Array for Pulsar Timing and Gravitational Wave Detection

    NASA Astrophysics Data System (ADS)

    McLaughlin, Maura

    2011-01-01

    Since their discovery in 1982, millisecond pulsars have served as exquisite probes of fundamental physics. I will discuss the most transformative current application of millisecond pulsars: the direct detection of gravitational waves. Timing an array of pulsars could result in the detection of a stochastic background of gravitational waves, most likely resulting from an ensemble of supermassive black hole binaries. The unique capabilities of the Allen Telescope Array (ATA) will make it a very important resource for this experiment. The multi-wavelength coverage will increase sensitivity and enable optimal removal of interstellar propagation affects and the flexibility of scheduling afforded by commensal observing will increase the number of sources times and the cadence at which we can observe each source. I will discuss how these properties complement existing facilities and how including the ATA will increase the sensitivity of the international pulsar timing array.

  8. George Herbert Mead and the Allen controversy at the University of Wisconsin.

    PubMed

    Cook, Gary A

    2007-01-01

    This essay uses previously unpublished correspondence of George Herbert Mead to tell the story of his involvement in the aftermath of a political dispute that took place at the University of Wisconsin during the years 1914-1915. It seeks thereby to clarify the historical significance of an article he published on this controversy in late 1915. Taken together with relevant information about the educational activities of William H. Allen of the New York Bureau of Municipal Research, Mead's correspondence and article throw helpful light upon his understanding of how an educational survey of a university should proceed; they also show how he went about the task of evaluating a failed attempt at such a survey.

  9. Electron dropout echoes induced by interplanetary shock: Van Allen Probes observations

    NASA Astrophysics Data System (ADS)

    Hao, Y. X.; Zong, Q.-G.; Zhou, X.-Z.; Fu, S. Y.; Rankin, R.; Yuan, C.-J.; Lui, A. T. Y.; Spence, H. E.; Blake, J. B.; Baker, D. N.; Reeves, G. D.

    2016-06-01

    On 23 November 2012, a sudden dropout of the relativistic electron flux was observed after an interplanetary shock arrival. The dropout peaks at ˜1 MeV and more than 80% of the electrons disappeared from the drift shell. Van Allen twin Probes observed a sharp electron flux dropout with clear energy dispersion signals. The repeating flux dropout and recovery signatures, or "dropout echoes", constitute a new phenomenon referred to as a "drifting electron dropout" with a limited initial spatial range. The azimuthal range of the dropout is estimated to be on the duskside, from ˜1300 to 0100 LT. We conclude that the shock-induced electron dropout is not caused by the magnetopause shadowing. The dropout and consequent echoes suggest that the radial migration of relativistic electrons is induced by the strong dusk-dawn asymmetric interplanetary shock compression on the magnetosphere.

  10. The Toda System and Clustering Interfaces in the Allen Cahn equation

    NASA Astrophysics Data System (ADS)

    Del Pino, Manuel; Kowalczyk, Michał; Wei, Juncheng

    2008-10-01

    We consider the Allen Cahn equation {\\varepsilon2Δ u + (1-u^2)u = 0} in a bounded, smooth domain Ω in {mathbb{R}^2} , under zero Neumann boundary conditions, where {\\varepsilon > 0} is a small parameter. Let Γ0 be a segment contained in Ω, connecting orthogonally the boundary. Under certain nondegeneracy and nonminimality assumptions for Γ0, satisfied for instance by the short axis in an ellipse, we construct, for any given N ≥ 1, a solution exhibiting N transition layers whose mutual distances are {O(\\varepsilon|log\\varepsilon|)} and which collapse onto Γ0 as {\\varepsilonto 0} . Asymptotic location of these interfaces is governed by a Toda-type system and yields in the limit broken lines with an angle at a common height and at main order cutting orthogonally the boundary.

  11. Cobalt-Catalyzed sp(2) -C-H Activation: Intermolecular Heterocyclization with Allenes at Room Temperature.

    PubMed

    Thrimurtulu, Neetipalli; Dey, Arnab; Maiti, Debabrata; Volla, Chandra M R

    2016-09-26

    The reactivity of allenes in transition-metal-catalyzed C-H activation chemistry is governed by the formation of either alkenyl-metal (M-alkenyl) or metal-π-allyl intermediates. Although either protonation or a β-hydride elimination is feasible with a M-alkenyl intermediate, cyclization has remained unexplored to date. Furthermore, due to the increased steric hindrance, the regioselectivity for the intramolecular cyclization of the metal-π-allyl intermediate was hampered towards the more substituted side. To address these issues, a unified approach to synthesize a diverse array of biologically and pharmaceutically relevant heterocyclic moieties by cobalt-catalyzed directed C-H functionalization was envisioned. Upon successful implementation, the present strategy led to the regioselective formation of dihydroisoquinolin-1(2H)-ones, isoquinolin-1(2H)-ones, dihydropyridones, and pyridones. PMID:27584828

  12. Wave-driven butterfly distribution of Van Allen belt relativistic electrons.

    PubMed

    Xiao, Fuliang; Yang, Chang; Su, Zhenpeng; Zhou, Qinghua; He, Zhaoguo; He, Yihua; Baker, D N; Spence, H E; Funsten, H O; Blake, J B

    2015-01-01

    Van Allen radiation belts consist of relativistic electrons trapped by Earth's magnetic field. Trapped electrons often drift azimuthally around Earth and display a butterfly pitch angle distribution of a minimum at 90° further out than geostationary orbit. This is usually attributed to drift shell splitting resulting from day-night asymmetry in Earth's magnetic field. However, direct observation of a butterfly distribution well inside of geostationary orbit and the origin of this phenomenon have not been provided so far. Here we report high-resolution observation that a unusual butterfly pitch angle distribution of relativistic electrons occurred within 5 Earth radii during the 28 June 2013 geomagnetic storm. Simulation results show that combined acceleration by chorus and magnetosonic waves can successfully explain the electron flux evolution both in the energy and butterfly pitch angle distribution. The current provides a great support for the mechanism of wave-driven butterfly distribution of relativistic electrons. PMID:26436770

  13. Pi2 Pulsations Observed by Van Allen Probes: A Case Study

    NASA Astrophysics Data System (ADS)

    Ghamry, E.; Kim, K. H.; Kwon, H. J.; Lee, D. H.; Kletzing, C.; Kurth, W. S.

    2014-12-01

    The plasmaspheric virtual resonance model has been proposed as one of the source mechanisms for low-latitude Pi2 pulsations. Few studies have used simultaneous multipoint observations in space to examine the spatial structure of Pi2 pulsations both inside and outside the plasmasphere. In this study we show multipoint observations for Pi2 pulsations using the Van Allen Probes (RBSP-A and RBSP-B). We focus on the two events that occurred between 1700 and 2000 UT on March 12, 2013, which were simultaneously observed by Van Allen Probes and Bohyun (BOH, L = 1.35) station in South Korea. By using plasma density measurements, we determined that during this time RBSP-A was located outside the plasmasphere and RBSP-B was located inside it. We found that the poloidal, radial (δBx) and compressional (δBz), magnetic field components, and the azimuthal (Ey) electric field component observed by both RBSP-A and RBSP-B have a high correlation with the H component at BOH for both events. The δBx and δBz oscillations at both RBSP-A and RBSP-B are nearly out of phase with ground Pi2. The Ey -H cross phases at RBSP-A outside the plasmapause and RBSP-B inside the plasmapause are nearly in quadrature for the first Pi2 event. These observations indicate that the Pi2 pulsations exist outside the plasmasphere with a radially standing signature which supports the plasmaspheric virtual resonance model.

  14. Formation of the oxygen torus in the inner magnetosphere: Van Allen Probes observations

    DOE PAGES

    Nose, Masahito; Oimatsu, S.; Keika, K.; Kletzing, C. A.; Kurth, W. S.; De Pascuale, S.; Smith, C. W.; MacDowall, R. J.; Reeves, Geoffrey D.; Nakano, S.; et al

    2015-02-19

    Here we study the formation process of an oxygen torus during the 12–15 November 2012 magnetic storm, using the magnetic field and plasma wave data obtained by Van Allen Probes. We estimate the local plasma mass density (ρL) and the local electron number density (neL) from the resonant frequencies of standing Alfvén waves and the upper hybrid resonance band. The average ion mass (M) can be calculated by M ~ ρL/neL under the assumption of quasi-neutrality of plasma. During the storm recovery phase, both Probe A and Probe B observe the oxygen torus at L = 3.0–4.0 and L =more » 3.7–4.5, respectively, on the morning side. The oxygen torus has M = 4.5–8 amu and extends around the plasmapause that is identified at L~3.2–3.9. We find that during the initial phase, M is 4–7 amu throughout the plasma trough and remains at ~1 amu in the plasmasphere, implying that ionospheric O+ ions are supplied into the inner magnetosphere already in the initial phase of the magnetic storm. Numerical calculation under a decrease of the convection electric field reveals that some of thermal O+ ions distributed throughout the plasma trough are trapped within the expanded plasmasphere, whereas some of them drift around the plasmapause on the dawnside. This creates the oxygen torus spreading near the plasmapause, which is consistent with the Van Allen Probes observations. We conclude that the oxygen torus identified in this study favors the formation scenario of supplying O+ in the inner magnetosphere during the initial phase and subsequent drift during the recovery phase.« less

  15. Formation of the oxygen torus in the inner magnetosphere: Van Allen Probes observations

    SciTech Connect

    Nose, Masahito; Oimatsu, S.; Keika, K.; Kletzing, C. A.; Kurth, W. S.; De Pascuale, S.; Smith, C. W.; MacDowall, R. J.; Reeves, Geoffrey D.; Nakano, S.; Spence, H. E.; Larsen, Brian Arthur

    2015-02-19

    Here we study the formation process of an oxygen torus during the 12–15 November 2012 magnetic storm, using the magnetic field and plasma wave data obtained by Van Allen Probes. We estimate the local plasma mass density (ρL) and the local electron number density (neL) from the resonant frequencies of standing Alfvén waves and the upper hybrid resonance band. The average ion mass (M) can be calculated by M ~ ρL/neL under the assumption of quasi-neutrality of plasma. During the storm recovery phase, both Probe A and Probe B observe the oxygen torus at L = 3.0–4.0 and L = 3.7–4.5, respectively, on the morning side. The oxygen torus has M = 4.5–8 amu and extends around the plasmapause that is identified at L~3.2–3.9. We find that during the initial phase, M is 4–7 amu throughout the plasma trough and remains at ~1 amu in the plasmasphere, implying that ionospheric O+ ions are supplied into the inner magnetosphere already in the initial phase of the magnetic storm. Numerical calculation under a decrease of the convection electric field reveals that some of thermal O+ ions distributed throughout the plasma trough are trapped within the expanded plasmasphere, whereas some of them drift around the plasmapause on the dawnside. This creates the oxygen torus spreading near the plasmapause, which is consistent with the Van Allen Probes observations. We conclude that the oxygen torus identified in this study favors the formation scenario of supplying O+ in the inner magnetosphere during the initial phase and subsequent drift during the recovery phase.

  16. Recent Performance Testing Results Using the 3-element Production Test Array for the Allen Telescope Array

    NASA Astrophysics Data System (ADS)

    Tarter, J. C.; Blitz, L.; ATA 25 person Team; Paul G. Allen Foundation Collaboration

    2002-12-01

    The Allen Telescope Array will consist of 350 fixed six-meter dishes at the Hat Creek Radio Observatory in northern California (land use permits pending). It is the first massively parallel array ever built. Where possible, components from consumer markets and mass-production manufacturing processes have been used to lower costs. The architecture of the array explicitly anticipates future growth as a result of "Moore's Law" improvements. There will be many novel features of this array including ultra-wideband instantaneous frequency coverage from 0.5 to 11 GHz, a very wide field of view (2.5 degrees across at 21 cm), miniaturized 80K cryogenics, full bandwidth analog data transmission from the antennas to the Myhrvold central processing facility, dynamic null-formation and tracking of satellite interferers, and continuous multi-user support for radio astronomical research and SETI explorations. Starting in July 2000, the technology development for this array has been a collaboration between the Paul G. Allen Foundation and the ATA team located at the SETI Institute and at the Radio Astronomy Laboratory at UC Berkeley. A rapid prototyping array (RPA) consisting of seven COTS antennas and room temperature L-band receivers was erected in Orinda, CA in March 2001. Thanks to strong and continuing support from Sun Microsystems, the RPA has provided an invaluable testbed for software development and evaluation of RFI mitigation schemes. An operational 3-element Production Test Array (PTA) has been implemented at Hat Creek Observatory over the last few months. The antennas, drives, monitor and control software, and frontend components are near-final versions to be manufactured for the full array. This poster provides performance data from the first few months of testing with the PTA. A final decision on commitment for construction is expected by April 1, 2003.

  17. Generation and effects of EMIC waves observed by the Van Allen Probes on 18 March 2013

    NASA Astrophysics Data System (ADS)

    Zhang, J.; Saikin, A.; Gamayunov, K. V.; Spence, H. E.; Larsen, B.; Geoffrey, R.; Smith, C. W.; Torbert, R. B.; Kurth, W. S.; Kletzing, C.

    2015-12-01

    Electromagnetic ion cyclotron (EMIC) waves play a crucial role in particle dynamics in the Earth's magnetosphere. The free energy for EMIC wave generation is usually provided by the temperature anisotropy of the energetic ring current ions. EMIC waves can in turn cause particle energization and losses through resonant wave-particle interactions. Using measurements from the Van Allen Probes, we perform a case study of EMIC waves and associated plasma conditions observed on 18 March 2013. From 0204 to 0211 UT, the Van Allen Probe-B detected He+-band EMIC wave activity in the post-midnight sector (MLT=4.6-4.9) at very low L-shells (L=2.6-2.9). The event occurred right outside the inward-pushed plasmapause in the early recovery phase of an intense geomagnetic storm - min. Dst = -132 nT at 2100 UT on 17 March 2013. During this event, the fluxes of energetic (> 1 keV), anisotropic O+ dominate both the H+ and He+ fluxes in this energy range. Meanwhile, O+ fluxes at low energies (< 0.1 keV) are low compared to H+ and He+ fluxes in the same energy range. The fluxes of <0.1 keV He+ are clearly enhanced during the wave event, indicating a signature of wave heating. To further confirm the association of the observed plasma features with the EMIC waves, we calculate the electron minimum resonant energy (Emin) and pitch angle diffusion coefficient (Dαα) of the EMIC wave packets by using nominal ion composition, derived total ion density from the frequencies of upper hybrid resonance, and measured ambient and wave magnetic field. EMIC wave growth rates are also calculated to evaluate the role of loss-cone distributed ring current ions in the EMIC wave generation.

  18. New results from the Colorado CubeSat and comparison with Van Allen Probes data

    NASA Astrophysics Data System (ADS)

    Li, X.

    2013-05-01

    The Colorado Student Space Weather Experiment (CSSWE) is a 3-unit (10cm x 10cm x 30cm) CubeSat mission funded by the NSF, launched into a highly inclined (650) low-Earth (490km x 790km) orbit on 09/13/12 as a secondary payload under NASA's Educational Launch of Nanosatellites (ELaNa) program. CSSWE contains a single science payload, the Relativistic Electron and Proton Telescope integrated little experiment (REPTile), which is a simplified and miniaturized version of the Relativistic Electron and Proton Telescope (REPT) built at the Laboratory for Atmospheric and Space Physics (LASP) of University of Colorado for NASA/Van Allen Probes mission, which consists of two identical spacecraft, launched on 08/30/12, that traverse the heart of the radiation belts in a low inclination (100) orbit. REPTile is designed to measure the directional differential flux of protons ranging from 9 to 40 MeV and electrons from 0.5 to >3.3 MeV. Three-month science mission (full success) was completed on 1/05/13. We are now into the extended mission phase, focusing on data analysis and modeling. REPTile measures a fraction of the total population that has small enough equatorial pitch angles to reach the altitude of CSSWE, thus measuring the precipitating population as well as the trapped population. These measurements are critical for understanding the loss of outer radiation belt electrons. New results from CSSWE and comparison with Van Allen Probes data will be presented. The CSSWE is also an ideal class project, involving over 65 graduate and undergraduate students and providing training for the next generation of engineers and scientists over the full life-cycle of a satellite project.

  19. New baseload power plants

    SciTech Connect

    Not Available

    1993-04-01

    This is a tabulation of the results of this magazines survey of current plans for new baseload power plants. The table lists the unit name, capacity, fuel, engineering firm, constructor, suppliers for steam generator, turbine generator and flue gas desulfurization equipment, date due on-line, and any non-utility participants. The table includes fossil-fuel plants, nuclear plants, geothermal, biomass and hydroelectric plants.

  20. Dental development in living and fossil orangutans.

    PubMed

    Smith, Tanya M

    2016-05-01

    Numerous studies have investigated molar development in extant and fossil hominoids, yet relatively little is known about orangutans, the only great ape with an extensive fossil record. This study characterizes aspects of dental development, including cuspal enamel daily secretion rate, long-period line periodicities, cusp-specific molar crown formation times and extension rates, and initiation and completion ages in living and fossil orangutan postcanine teeth. Daily secretion rate and periodicities in living orangutans are similar to previous reports, while crown formation times often exceed published values, although direct comparisons are limited. One wild Bornean individual died at 4.5 years of age with fully erupted first molars (M1s), while a captive individual and a wild Sumatran individual likely erupted their M1s around five or six years of age. These data underscore the need for additional samples of orangutans of known sex, species, and developmental environment to explore potential sources of variation in molar emergence and their relationship to life history variables. Fossil orangutans possess larger crowns than living orangutans, show similarities in periodicities, and have faster daily secretion rate, longer crown formation times, and slower extension rates. Molar crown formation times exceed reported values for other fossil apes, including Gigantopithecus blacki. When compared to African apes, both living and fossil orangutans show greater cuspal enamel thickness values and periodicities, resulting in longer crown formation times and slower extension rates. Several of these variables are similar to modern humans, representing examples of convergent evolution. Molar crown formation does not appear to be equivalent among extant great apes or consistent within living and fossil members of Pongo or Homo. PMID:27178461