Why is the Great Red Spot Red? The Exogenic, Photolytic Origin of the UV/Blue-Absorbing Chromophores of Jupiter’s Great Red Spot as Determined by Spectral Analysis of Cassini/VIMS Observations using New Laboratory Optical Coefficients

NASA Astrophysics Data System (ADS)

Baines, Kevin H.; Carlson, Robert W.; Momary, Thomas W.

2014-11-01

For centuries, a major question for Jupiter has been: Why is the Great Red Spot red? In particular, two major theories have been proposed: (1) that the coloring is due to photolytic processes in the upper cloud layer, or (2) it is due to the upwellimg of red materials processed relatively deep within the troposphere. Utilizing indices of refraction for red choromophores generated by the photolysis of ammonia and acetylene in the laboratory, we present results of a spectral analysis of the core of Jupiter’s Great Red Spot (GRS) as observed by the visual channel of the Cassini/Visual Infrared Mapping Spectrometer (VIMS). Consistent with the physical origin of such laboratory-generated chromophores in Jupiter - i.e., by solar-driven UV photolysis within the upper levels of the GRS structure near ~ 0.3 bar - our spectral modeling yields satisfactory results for such Mie scattering chromophores only when they are confined to the upper ~ 100 mbar of the GRS. Beneath this reddish upper cloud layer, our models indicate that the remainder of the GRS cloud - assumed to extend down to at least the ammonia condensation level near 0.6 bar - must be relatively spectrally bright throughout the UV-red spectrum; that is, they must be predominantly a whitish or grey color at depth. Thus, our 0.35-1.0 micron spectral models of the GRS are inconsistent with an endogenic origin of the reddish coloring originating in the depths of Jupiter, but are consistent with a photolytic origin due to the photolysis of ammonia and acetylene in the upper troposphere.

Probing Storm Activity on Jupiter

NASA Technical Reports Server (NTRS)

2007-01-01

Scientists assume Jupiter's clouds are composed primarily of ammonia, but only about 1% of the cloud area displays the characteristic spectral fingerprint of ammonia. This composite of infrared images taken by the New Horizons Linear Etalon Infrared Spectral Imager (LEISA) captures several eruptions of this relatively rare breed of ammonia cloud and follows the evolution of the clouds over two Jovian days. (One day on Jupiter is approximately 10 hours, which is how long it takes Jupiter to make one complete rotation about its axis.)

The New Horizons spacecraft was still closing in on the giant planet when it made these observations: Jupiter was 3.4 million kilometers (2.1 million miles) from the New Horizons spacecraft for the LEISA image taken at 19:35 Universal Time on February 26, 2007, and the distance decreased to 2.5 million kilometers (1.6 million miles) for the last image shown. LEISA's spatial resolution scale varied from approximately 210 kilometers (130 miles) for the first image to 160 kilometers (100 miles) for the last one.

New Horizons scientists originally targeted the region slightly northwest (up and to the left) of the Great Red Spot to search for these special ammonia clouds because that's where they were most easily seen during infrared spectral observations made by the Galileo spacecraft. But unlike the churning, turbulent cloud structures seen near the Great Red Spot during the Galileo era, this region has been quieting down during the past several months and was unusually tranquil when New Horizons passed by. Nevertheless, LEISA managed to find other regions of fresh, upwelling ammonia clouds, and the temporal evolution of one such region is displayed in this figure. In the first image, a fresh ammonia cloud (the blue region) sprouts from between white clouds and a dark elongated region. This blue cloud subsequently stretches along the white-dark border in the next two images.

These fresh ammonia clouds trace the strong upwelling of gases from the largely hidden depths of Jupiter to higher altitudes. Presumably, water is also being dragged up from below, and the subsequent condensation of that water, which is far more abundant than ammonia in Jupiter's atmosphere, into cloud droplets energizes the lower troposphere.

LEISA produces images at infrared wavelengths, which is heat radiation that cannot be sensed by the human eye. These 'false color' images were produced by putting images of Jupiter at wavelengths of 1.99 micrometers, 1.94 micrometers and 2.04 micrometers into the red, green and blue channels, respectively, of the image display. Ammonia has an absorption feature at 1.99 microns, and when the colors are combined in this way the fresh ammonia clouds take on a bluish hue.

Ammonia Observations of NGC 6334 I(N)

NASA Technical Reports Server (NTRS)

Kuiper, T. B. H.; Peters, W. L., III; Foster, J. R.; Gardner, F. F.; Whiteoak, J. B.

1995-01-01

Coincident with the far-infrared source NGC 6334 I(N) and water maser source E is a massive dense cloud which has the most intense ammonia (1, 1) emission of any known interstellar cloud. We have mapped the (3, 3) emission and find the cloud is extended 0.8 pc in the direction parallel to the Galactic plane, and 0.5 pc perpendicular to it. It has a velocity gradient of 1 km/s.pc perpendicular to the Galactic plane. The gas kinetic temperature is about 30 K and the density is greater than 10(exp 6)/cc. The mass of the cloud is about 3000 solar mass, 3 times greater than previously estimated. The para-ammonia column density is 6 - 8 x 10(exp 15)/sq cm. An ammonia abundance of 0.5 - 1.5 x 10(exp -8) is inferred, where the larger number assumes an early time ortho/para ratio. This suggests either a cloud age of less than approximately 10(exp 6) yr, or substantial depletion of ammonia.

Fading of Jupiter's South Equatorial Belt

NASA Technical Reports Server (NTRS)

Sola, Michael A.; Orton, Glenn; Baines, Kevin; Yanamandra-Fisher, Padma

2011-01-01

One of Jupiter's most dominant features, the South Equatorial Belt, has historically gone through a "fading" cycle. The usual dark, brownish clouds turn white, and after a period of time, the region returns to its normal color. Understanding this phenomenon, the latest occurring in 2010, will increase our knowledge of planetary atmospheres. Using the near infrared camera, NSFCAM2, at NASA's Infrared Telescope Facility in Hawaii, images were taken of Jupiter accompanied by data describing the circumstances of each observation. These images are then processed and reduced through an IDL program. By scanning the central meridian of the planet, graphs were produced plotting the average values across the central meridian, which are used to find variations in the region of interest. Calculations using Albert4, a FORTRAN program that calculates the upwelling reflected sunlight from a designated cloud model, can be used to determine the effects of a model atmosphere due to various absorption, scattering, and emission processes. Spectra that were produced show ammonia bands in the South Equatorial Belt. So far, we can deduce from this information that an upwelling of ammonia particles caused a cloud layer to cover up the region. Further investigations using Albert4 and other models will help us to constrain better the chemical make up of the cloud and its location in the atmosphere.

Colors of Alien Worlds from Direct Imaging Exoplanet Missions

NASA Astrophysics Data System (ADS)

Hu, Renyu

2016-01-01

Future direct-imaging exoplanet missions such as WFIRST will measure the reflectivity of exoplanets at visible wavelengths. Most of the exoplanets to be observed will be located further away from their parent stars than is Earth from the Sun. These "cold" exoplanets have atmospheric environments conducive for the formation of water and/or ammonia clouds, like Jupiter in the Solar System. I find the mixing ratio of methane and the pressure level of the uppermost cloud deck on these planets can be uniquely determined from their reflection spectra, with moderate spectral resolution, if the cloud deck is between 0.6 and 1.5 bars. The existence of this unique solution is useful for exoplanet direct imaging missions for several reasons. First, the weak bands and strong bands of methane enable the measurement of the methane mixing ratio and the cloud pressure, although an overlying haze layer can bias the estimate of the latter. Second, the cloud pressure, once derived, yields an important constraint on the internal heat flux from the planet, and thus indicating its thermal evolution. Third, water worlds having H2O-dominated atmospheres are likely to have water clouds located higher than the 10-3 bar pressure level, and muted spectral absorption features. These planets would occupy a confined phase space in the color-color diagrams, likely distinguishable from H2-rich giant exoplanets by broadband observations. Therefore, direct-imaging exoplanet missions may offer the capability to broadly distinguish H2-rich giant exoplanets versus H2O-rich super-Earth exoplanets, and to detect ammonia and/or water clouds and methane gas in their atmospheres.

Jupiter cloud composition, stratification, convection, and wave motion: a view from new horizons.

PubMed

Reuter, D C; Simon-Miller, A A; Lunsford, A; Baines, K H; Cheng, A F; Jennings, D E; Olkin, C B; Spencer, J R; Stern, S A; Weaver, H A; Young, L A

2007-10-12

Several observations of Jupiter's atmosphere made by instruments on the New Horizons spacecraft have implications for the stability and dynamics of Jupiter's weather layer. Mesoscale waves, first seen by Voyager, have been observed at a spatial resolution of 11 to 45 kilometers. These waves have a 300-kilometer wavelength and phase velocities greater than the local zonal flow by 100 meters per second, much higher than predicted by models. Additionally, infrared spectral measurements over five successive Jupiter rotations at spatial resolutions of 200 to 140 kilometers have shown the development of transient ammonia ice clouds (lifetimes of 40 hours or less) in regions of strong atmospheric upwelling. Both of these phenomena serve as probes of atmospheric dynamics below the visible cloud tops.

Accurate Spectral Fits of Jupiter's Great Red Spot: VIMS Visual Spectra Modelled with Chromophores Created by Photolyzed Ammonia Reacting with Acetyleneχ±

NASA Astrophysics Data System (ADS)

Baines, Kevin; Sromovsky, Lawrence A.; Fry, Patrick M.; Carlson, Robert W.; Momary, Thomas W.

2016-10-01

We report results incorporating the red-tinted photochemically-generated aerosols of Carlson et al (2016, Icarus 274, 106-115) in spectral models of Jupiter's Great Red Spot (GRS). Spectral models of the 0.35-1.0-micron spectrum show good agreement with Cassini/VIMS near-center-meridian and near-limb GRS spectra for model morphologies incorporating an optically-thin layer of Carlson (2016) aerosols at high altitudes, either at the top of the tropospheric GRS cloud, or in a distinct stratospheric haze layer. Specifically, a two-layer "crème brûlée" structure of the Mie-scattering Carlson et al (2016) chromophore attached to the top of a conservatively scattering (hereafter, "white") optically-thick cloud fits the spectra well. Currently, best agreement (reduced χ2 of 0.89 for the central-meridian spectrum) is found for a 0.195-0.217-bar, 0.19 ± 0.02 opacity layer of chromophores with mean particle radius of 0.14 ± 0.01 micron. As well, a structure with a detached stratospheric chromophore layer ~0.25 bar above a white tropospheric GRS cloud provides a good spectral match (reduced χ2 of 1.16). Alternatively, a cloud morphology with the chromophore coating white particles in a single optically- and physically-thick cloud (the "coated-shell model", initially explored by Carlson et al 2016) was found to give significantly inferior fits (best reduced χ2 of 2.9). Overall, we find that models accurately fit the GRS spectrum if (1) most of the optical depth of the chromophore is in a layer near the top of the main cloud or in a distinct separated layer above it, but is not uniformly distributed within the main cloud, (2) the chromophore consists of relatively small, 0.1-0.2-micron-radius particles, and (3) the chromophore layer optical depth is small, ~ 0.1-0.2. Thus, our analysis supports the exogenic origin of the red chromophore consistent with the Carlson et al (2016) photolytic production mechanism rather than an endogenic origin, such as upwelling of material from the depths of Jupiter.

Ammonia Clouds on Jupiter

NASA Image and Video Library

2007-10-09

In this movie, put together from false-color images taken by the New Horizons Ralph instrument as the spacecraft flew past Jupiter in early 2007, show ammonia clouds appearing as bright blue areas as they form and disperse.

Colors of Alien Worlds from Direct Imaging Exoplanet Missions

NASA Astrophysics Data System (ADS)

Hu, Renyu

2015-08-01

Future direct-imaging exoplanet missions such as WFIRST/AFTA, Exo-C, and Exo-S will measure the reflectivity of exoplanets at visible wavelengths. Most of the exoplanets to be observed will be located further away from their parent stars than is Earth from the Sun. These “cold” exoplanets have atmospheric environments conducive for the formation of water and/or ammonia clouds, like Jupiter in the Solar System. I find the mixing ratio of methane and the pressure level of the uppermost cloud deck on these planets can be uniquely determined from their reflection spectra, with moderate spectral resolution, if the cloud deck is between 0.6 and 1.5 bars. The existence of this unique solution is useful for exoplanet direct imaging missions for several reasons. First, the weak bands and strong bands of methane enable the measurement of the methane mixing ratio and the cloud pressure, although an overlying haze layer can bias the estimate of the latter. Second, the cloud pressure, once derived, yields an important constraint on the internal heat flux from the planet, and thus indicating its thermal evolution. Third, water worlds having H2O-dominated atmospheres are likely to have water clouds located higher than the 10-3 bar pressure level, and muted spectral absorption features. These planets would occupy a confined phase space in the color-color diagrams, likely distinguishable from H2-rich giant exoplanets by broadband observations. Therefore, direct-imaging exoplanet missions may offer the capability to broadly distinguish H2-rich giant exoplanets versus H2O-rich super-Earth exoplanets, and to detect ammonia and/or water clouds and methane gas in their atmospheres.

Precipitating Condensation Clouds in Substellar Atmospheres

NASA Technical Reports Server (NTRS)

Ackerman, Andrew S.; Marley, Mark S.; Gore, Warren J. (Technical Monitor)

2000-01-01

We present a method to calculate vertical profiles of particle size distributions in condensation clouds of giant planets and brown dwarfs. The method assumes a balance between turbulent diffusion and precipitation in horizontally uniform cloud decks. Calculations for the Jovian ammonia cloud are compared with previous methods. An adjustable parameter describing the efficiency of precipitation allows the new model to span the range of predictions from previous models. Calculations for the Jovian ammonia cloud are found to be consistent with observational constraints. Example calculations are provided for water, silicate, and iron clouds on brown dwarfs and on a cool extrasolar giant planet.

NIMS Views of a Jovian 'Hot Spot'

NASA Technical Reports Server (NTRS)

1997-01-01

These four Galileo/NIMS near-infrared images of a small portion of the equatorial region of Jupiter show a dark clearing of clouds in the meteorologically-active troposphere of Jupiter. This region constitutes a 'hot spot', a nearly-clear area devoid of thick ammonia clouds which allows Jupiter's indigenous heat radiation to shine through at 5 microns (not shown). These features are thought to be areas of downwelling, dry (low ammonia and water humidity) air. The second image from the top, taken at a wavelength sensitive to methane absorption, has muted contrast, showing that a high-level optically-thin haze layer overlies the entire region. All other images, taken over a large range of methane-insensitive wavelengths from 0.76 to 2.74 microns, reveal such 5 micron bright hotspots as actually being dark in reflected sunlight, confirming clearings in the bright reflective surrounding cloud layer and perhaps indicating absorption by clouds and/or gases at relatively deep levels in the atmosphere.

These images were acquired December 17, 1996 from a distance of 1.43 million kilometers above the cloudtops. The large dark clearing near the middle of the image is approximately 7000 km wide in the east-west direction and 4000 km tall in the north-south direction, about twice the size of the continental U. S. Images shown are at 0.76, 1.61, 1.99, and 2.74 microns, proceeding from top to bottom.

The Jet Propulsion Laboratory, Pasadena, CA manages the mission for NASA's Office of Space Science, Washington, DC.

The Jet Propulsion Laboratory, Pasadena, CA manages the mission for NASA's Office of Space Science, Washington, DC.

This image and other images and data received from Galileo are posted on the World Wide Web, on the Galileo mission home page at URL http://galileo.jpl.nasa.gov.

ATCA survey of ammonia in the galactic center: The temperatures of dense gas clumps between Sgr A* and Sgr B2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ott, Jürgen; Weiß, Axel; Henkel, Christian

We present a large-scale, interferometric survey of ammonia (1, 1) and (2, 2) toward the Galactic center observed with the Australia Telescope Compact Array. The survey covers Δℓ ∼ 1° (∼150 pc at an assumed distance of 8.5 kpc) and Δb ∼ 0.°2 (∼30 pc) which spans the region between the supermassive black hole Sgr A* and the massive star forming region Sgr B2. The resolution is ∼20'' (∼0.8 pc) and emission at scales ≳ 2' (≳ 3.2 pc) is filtered out due to missing interferometric short spacings. Consequently, the data represent the denser, compact clouds and disregards the large-scale,more » diffuse gas. Many of the clumps align with the 100 pc dust ring and mostly anti-correlate with 1.2 cm continuum emission. We present a kinetic temperature map of the dense gas. The temperature distribution peaks at ∼38 K with a width at half maximum between 18 K and 61 K (measurements sensitive within T {sub kin} ∼ 10-80 K). Larger clumps are on average warmer than smaller clumps which suggests internal heating sources. Our observations indicate that the circumnuclear disk ∼1.5 pc around Sgr A* is supplied with gas from the 20 km s{sup –1} molecular cloud. This gas is substantially cooler than gas ∼3-15 pc away from Sgr A*. We find a strong temperature gradient across Sgr B2. Ammonia column densities correlate well with SCUBA 850 μm fluxes, but the relation is shifted from the origin, which may indicate a requirement for a minimum amount of dust to form and shield ammonia. Around the Arches and Quintuplet clusters we find shell morphologies with UV-influenced gas in their centers, followed by ammonia and radio continuum layers.« less

The Green Bank Ammonia Survey: Observations of Hierarchical Dense Gas Structures in Cepheus-L1251

NASA Astrophysics Data System (ADS)

Keown, Jared; Di Francesco, James; Kirk, Helen; Friesen, Rachel K.; Pineda, Jaime E.; Rosolowsky, Erik; Ginsburg, Adam; Offner, Stella S. R.; Caselli, Paola; Alves, Felipe; Chacón-Tanarro, Ana; Punanova, Anna; Redaelli, Elena; Seo, Young Min; Matzner, Christopher D.; Chun-Yuan Chen, Michael; Goodman, Alyssa A.; Chen, How-Huan; Shirley, Yancy; Singh, Ayushi; Arce, Hector G.; Martin, Peter; Myers, Philip C.

2017-11-01

We use Green Bank Ammonia Survey observations of NH3 (1, 1) and (2, 2) emission with 32″ FWHM resolution from a ˜10 pc2 portion of the Cepheus-L1251 molecular cloud to identify hierarchical dense gas structures. Our dendrogram analysis of the NH3 data results in 22 top-level structures, which reside within 13 lower-level parent structures. The structures are compact (0.01 {pc}≲ {R}{eff}≲ 0.1 {pc}) and are spatially correlated with the highest H2 column density portions of the cloud. We also compare the ammonia data to a catalog of dense cores identified by higher-resolution (18.″2 FWHM) Herschel Space Observatory observations of dust continuum emission from Cepheus-L1251. Maps of kinetic gas temperature, velocity dispersion, and NH3 column density, derived from detailed modeling of the NH3 data, are used to investigate the stability and chemistry of the ammonia-identified and Herschel-identified structures. We show that the dust and dense gas in the structures have similar temperatures, with median T dust and T K measurements of 11.7 ± 1.1 K and 10.3 ± 2.0 K, respectively. Based on a virial analysis, we find that the ammonia-identified structures are gravitationally dominated, yet may be in or near a state of virial equilibrium. Meanwhile, the majority of the Herschel-identified dense cores appear to be not bound by their own gravity and instead confined by external pressure. CCS (20 - 10) and HC5N (9-8) emission from the region reveal broader line widths and centroid velocity offsets when compared to the NH3 (1, 1) emission in some cases, likely due to these carbon-based molecules tracing the turbulent outer layers of the dense cores.

Saturn's depths in a new light: Novel views of meteorology, circulation and dynamics by Cassini/VIMS

NASA Astrophysics Data System (ADS)

Baines, Kevin; Momary, Thomas; Roos-Serote, Maarten; Showman, Adam; Atreya, Sushil K.; Brown, Robert H.; Buratti, Bonnie; Clark, Roger; Nicholson, Phillip

The depths of Saturn below the ubiquitous covering of ammonia hazes have been revealed in detail by the Visual Infrared Mapping Spectrometer (VIMS) onboard the Cassini orbiter. Using Saturn's own indigenous glow produced by warm air at depth to back-light deep clouds, a diverse array of cloud features have been discovered near the 3-bar level, some 75 km underneath the ammonia clouds. Likely comprised of ammonia hydrosulfide, perhaps with a complement of water, the menagerie of deep cloud structures - including dozens of surprisingly narrow axisymmetric "zones", "smoke rings", a long-lived "string of pearls" spanning 1/4 of the planet, large plume-like and cyclonic features, and a deep-seated hexagonal feature circumscribing the north pole - reveal Saturn at depth to be a dynamic, meteorologically active planet much more like frenetic Jupiter than the classically serene face Saturn shows in sunlight. Additional information on Saturn's dynamically active nature is provided by daytime imagery of discrete clouds observed at the southpole - revealing two compositional types of clouds, suggesting a variety of upwelling phenomena - and the latitudinal variability of the trace disequilibrium gases arsine and phosphine observed in VIMS spectra.

A detailed investigation of proposed gas-phase syntheses of ammonia in dense interstellar clouds

NASA Technical Reports Server (NTRS)

Herbst, Eric; Defrees, D. J.; Mclean, A. D.

1987-01-01

The initial reactions of the Herbst and Klemperer (1973) and the Dalgarno (1974) schemes (I and II, respectively) for the gas-phase synthesis of ammonia in dense interstellar clouds were investigated. The rate of the slightly endothermic reaction between N(+) and H2 to yield NH(+) and H (scheme I) under interstellar conditions was reinvestigated under thermal and nonthermal conditions based on laboratory data. It was found that the relative importance of this reaction in synthesizing ammonia is determined by how the laboratory data at low temperature are interpreted. On the other hand, the exothermic reaction between N and H3(+) to form NH2(+) + H (scheme II) was calculated to possess significant activation energy and, therefore, to have a negligible rate coefficient under interstellar conditions. Consequently, this reaction cannot take place appreciably in interstellar clouds.

Under Jupiter's Cloud Tops

NASA Image and Video Library

2017-05-25

NASA's Juno spacecraft carries an instrument called the Microwave Radiometer, which examines Jupiter's atmosphere beneath the planet's cloud tops. This image shows the instrument's view of the outer part of Jupiter's atmosphere. Before Juno began using this instrument, scientists expected the atmosphere to be uniform at depths greater than 60 miles (100 kilometers). But with the Microwave Radiometer, scientists have discovered that the atmosphere has variations down to at least 220 miles (350 kilometers), as deep as the instrument can see. In the cut-out image to the right, orange signifies high ammonia abundance and blue signifies low ammonia abundance. Jupiter appears to have a band around its equator high in ammonia abundance, with a column shown in orange. This is contrary to scientists' expectations that ammonia would be uniformly mixed. https://photojournal.jpl.nasa.gov/catalog/PIA21642

Labeled drawing of Jupiter showing its core and composition

NASA Technical Reports Server (NTRS)

1989-01-01

Labeled drawing of Jupiter identifies fluid molecular hydrogen, transition zone, fluid metallic hydrogen, and possible core and the composition of its atmosphere - cloud tops - aerosols, ammonia crystals, ammonium hydrosulfide clouds, ice crystal clouds, and water droplets.

Scavenging of ammonia by raindrops in Saturn's great storm clouds

NASA Astrophysics Data System (ADS)

Delitsky, M. L.; Baines, Kevin

2016-10-01

Observations of the great Saturn storms of 2010-2011 by Cassini instruments showed a very large depletion in atmospheric ammonia. While dynamics will play a role, the very high solubility of ammonia in water may be another important contributor to ammonia depletion in storms. Ammonia exists in Earth's atmosphere and rainstorms dissolve ammonia to a great degree, leaving almost no NH3 in the atmosphere. Studies by Elperin et al (2011, 2013) show that scavenging of ammonia is greatest as a rainstorm starts and lessens as raindrops fall, tapering off to almost zero by the time the rain reaches the ground (Elperin et al 2009). Ammonia is reaching saturation as it dissolves in the aqueous solution. As concentration increases, NH3 is then converted to aqueous species (NH3)x.(H2O)y (Max and Chapados 2013).Ammonia has the highest solubility in water compared to all other gases in the Saturn atmosphere. The Henry's Law constant for NH3 in water is 60 M/atm at 25 C. For H2S, it is 0.001 M/atm. In Saturn storms, it is "raining UP": As water-laden storm clouds convectively rise, ammonia gas will be scavenged and go into solution to a great degree, whilst all the other gases remain mostly in the gas phase. Aqueous ammonia acts as an antifreeze: if ammonia is dissolved in water cloud droplets to the limit of its solubility, as water droplets rise, they can stay liquid (and continue to scavenge NH3) to well below their normal freezing point of 0 Celsius (273 K). The freezing point for a 30 wt % water-ammonia solution is ~189 K. The pressure level where T = 189 K is at 2.8 bars. The normal freezing point of water occurs at the 9 bar pressure level in Saturn's atmosphere. 2.8 bars occurs at the -51 km altitude (below the 1 bar level). 9 bars is at the -130 km level: a difference of 79 km. A water droplet containing 30 wt% NH3 can move upwards from 9 bars to 2.8 bars (79 km) and still remain liquid, only freezing above that altitude. Calculations by the E-AIM model show that ammonia becomes the dominant species as the water droplets rise and cool. Ammonia will be effectively depleted as it is scavenged into water droplets in Saturn's storms.

Characterization of BN rich layer on ammonia treated Nextel{trademark}312 fibers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Khasgiwale, N.R.; Butler, E.P.; Tsakalakos, L.

A BN rich layer grown on Nextel{trademark}312 fibers by appropriate ammonia treatments was evaluated using various complimentary techniques including X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Scanning Electron Microscopy (SEM), and Transmission Electron Microscopy (TEM)/Parallel Electron Energy Loss Spectroscopy (PEELS in TEM). Three different ammonia treatments were studied. Ammonia treatment resulted in crystallization of the Nextel{trademark}312 fiber. The BN rich surface layer formed due to ammonia treatment was clearly detected in XPS and PEELS both before and after oxidation. The layer thickness was estimated to be between 5--10 nm. The layer was stable after oxidation treatment at 600 C formore » 100 hours. High resolution TEM observations of the fiber surface revealed a variable BN rich layer thickness. Patches of turbostratic BN were observed under certain conditions, however mostly the layer appeared to be amorphous.« less

3-Dimensional simulations of storm dynamics on Saturn

NASA Astrophysics Data System (ADS)

Hueso, R.; Sanchez-Lavega, A.

2000-10-01

The formation and evolution of convective clouds in the atmosphere of Saturn is investigated using an anelastic three-dimensional time-dependent model with parameterized microphysics. The model is designed to study the development of moist convection on any of the four giant planets and has been previously used to investigate the formation of water convective storms in the jovian atmosphere. The role of water and ammonia in moist convection is investigated with varying deep concentrations. Results imply that most of the convective activity observed at Saturn may occur at the ammonia cloud deck while the formation of water moist convection may happen only when very strong constraints on the lower troposphere are met. Ammonia storms can ascend to the 300 mb level with vertical velocities around 30 ms-1. The seasonal effect on the thermal profile at the upper troposphere may have important effects on the development of ammonia storms. In the cases where water storms can develop they span many scale heights with peak vertical velocities around 160 ms-1 and cloud particles can be transported up to the 150 mb level. These predicted characteristics are similar to the Great White Spots observed in Saturn which, therefore, could be originated at the water cloud base level. This work has been supported by Gobierno Vasco PI 1997-34. R. Hueso acknowledges a PhD fellowship from Gobierno Vasco.

Migration of nitrate, nitrite, and ammonia through the municipal solid waste incinerator bottom ash layer in the simulated landfill.

PubMed

Yao, Jun; Chen, Luxi; Zhu, Huayue; Shen, Dongsheng; Qiu, Zhanhong

2017-04-01

Simulated landfill was operated for 508 days to investigate the effect of municipal solid waste incinerator (MSWI) bottom ash layer on the migration of nitrate, nitrite, and ammonia when it was used as the intermediate layer in the landfill. The result suggested that the MSWI bottom ash layer could capture the nitrate, nitrite, and ammonia from the leachate. The adsorption of the nitrate, nitrite, and ammonia on the MSWI bottom ash layer was saturated at the days 396, 34, and 97, respectively. Afterwards, the nitrogen species were desorbed from the MSWI bottom ash layer. Finally, the adsorption and desorption could reach the equilibrium. The amounts of adsorbed nitrate and nitrite on the MSWI bottom ash layer were 1685.09 and 7.48 mg, respectively, and the amount of the adsorbed and transformed ammonia was 13,773.19 mg, which was much higher than the desorbed. The water leaching test and synthetic precipitation leaching procedure (SPLP) results showed that the leachable nitrate, nitrite, and ammonia in the MSWI bottom ash were greatly increased after the landfill operation, suggesting that the adsorbed nitrogen could be finally leached out. Besides, the results also showed that MSWI bottom ash layer could affect the release of nitrate and ammonia at the initial stage of the landfill. However, it had little effect on the release of nitrite.

Fresh clouds: A parameterized updraft method for calculating cloud densities in one-dimensional models

NASA Astrophysics Data System (ADS)

Wong, Michael H.; Atreya, Sushil K.; Kuhn, William R.; Romani, Paul N.; Mihalka, Kristen M.

2015-01-01

Models of cloud condensation under thermodynamic equilibrium in planetary atmospheres are useful for several reasons. These equilibrium cloud condensation models (ECCMs) calculate the wet adiabatic lapse rate, determine saturation-limited mixing ratios of condensing species, calculate the stabilizing effect of latent heat release and molecular weight stratification, and locate cloud base levels. Many ECCMs trace their heritage to Lewis (Lewis, J.S. [1969]. Icarus 10, 365-378) and Weidenschilling and Lewis (Weidenschilling, S.J., Lewis, J.S. [1973]. Icarus 20, 465-476). Calculation of atmospheric structure and gas mixing ratios are correct in these models. We resolve errors affecting the cloud density calculation in these models by first calculating a cloud density rate: the change in cloud density with updraft length scale. The updraft length scale parameterizes the strength of the cloud-forming updraft, and converts the cloud density rate from the ECCM into cloud density. The method is validated by comparison with terrestrial cloud data. Our parameterized updraft method gives a first-order prediction of cloud densities in a “fresh” cloud, where condensation is the dominant microphysical process. Older evolved clouds may be better approximated by another 1-D method, the diffusive-precipitative Ackerman and Marley (Ackerman, A.S., Marley, M.S. [2001]. Astrophys. J. 556, 872-884) model, which represents a steady-state equilibrium between precipitation and condensation of vapor delivered by turbulent diffusion. We re-evaluate observed cloud densities in the Galileo Probe entry site (Ragent, B. et al. [1998]. J. Geophys. Res. 103, 22891-22910), and show that the upper and lower observed clouds at ∼0.5 and ∼3 bars are consistent with weak (cirrus-like) updrafts under conditions of saturated ammonia and water vapor, respectively. The densest observed cloud, near 1.3 bar, requires unexpectedly strong updraft conditions, or higher cloud density rates. The cloud density rate in this layer may be augmented by a composition with non-NH4SH components (possibly including adsorbed NH3).

A Cloud Microphysics Model for the Gas Giant Planets

NASA Astrophysics Data System (ADS)

Palotai, Csaba J.; Le Beau, Raymond P.; Shankar, Ramanakumar; Flom, Abigail; Lashley, Jacob; McCabe, Tyler

2016-10-01

Recent studies have significantly increased the quality and the number of observed meteorological features on the jovian planets, revealing banded cloud structures and discrete features. Our current understanding of the formation and decay of those clouds also defines the conceptual modes about the underlying atmospheric dynamics. The full interpretation of the new observational data set and the related theories requires modeling these features in a general circulation model (GCM). Here, we present details of our bulk cloud microphysics model that was designed to simulate clouds in the Explicit Planetary Hybrid-Isentropic Coordinate (EPIC) GCM for the jovian planets. The cloud module includes hydrological cycles for each condensable species that consist of interactive vapor, cloud and precipitation phases and it also accounts for latent heating and cooling throughout the transfer processes (Palotai and Dowling, 2008. Icarus, 194, 303-326). Previously, the self-organizing clouds in our simulations successfully reproduced the vertical and horizontal ammonia cloud structure in the vicinity of Jupiter's Great Red Spot and Oval BA (Palotai et al. 2014, Icarus, 232, 141-156). In our recent work, we extended this model to include water clouds on Jupiter and Saturn, ammonia clouds on Saturn, and methane clouds on Uranus and Neptune. Details of our cloud parameterization scheme, our initial results and their comparison with observations will be shown. The latest version of EPIC model is available as open source software from NASA's PDS Atmospheres Node.

Infrared laboratory studies of synthetic planetary atmospheres

NASA Technical Reports Server (NTRS)

Williams, D.

1977-01-01

Topics covered include: the broadening of individual lines in the CO fundamental by various gases; total band absorptance as a function of absorber thickness and total effect pressure at various temperatures for bands of CO and N2O; nitric acid vapor content in the region of the ozone layer; optical properties of solid NH3; HSO4 concentration in Venus clouds; Burch's law of multiplicative transmittance for mixing absorbing gases when their lines are broadened by helium and hydrogen; ling strength and self-broadening parameters in the v3 fundamental of CO2 and N2O; optical constants of liquid ammonia, liquid methane, saturated hydrocarbons, ammonium hydride and ammonium salts.

Water-Ammonia Ionic Ocean on Uranus and Neptune-Clue from Tropospheric Hydrogen Sulfide Clouds

NASA Astrophysics Data System (ADS)

Atreya, S. K.; Egeler, P. A.; Wong, A.

2005-12-01

Interior models of the ice-giants, Uranus and Neptune, predict a water-ammonia ionic ocean at tens of kilobar pressure [1,2]. If correct, its implication for planetary formation models is profound. In this presentation we demonstrate that the existence of an ionic ocean will manifest itself in the planets' tropospheric cloud structure, particularly in the form of a hydrogen sulfide, i.e. H2S-ice, cloud. In fact, an H2S cloud was introduced ad hoc in the 3-5 bar region to explain microwave absorption [3] and the methane [4] observations, but its presence cannot be proved in the absence of entry probes. Our equilibrium cloud condensation model (ECCM) shows that an H2S-ice cloud does not form when conventional enrichment factors (20-30× solar at Uranus, and 30-50× solar at Neptune) are employed for all heavy elements (mass >4) [5]. However, a deep ``cloud'' composed of a weak solution of ammonia and water forms, and its base is at 370 and 500 bars, respectively, for 30× solar and 50× solar enrichment factors. If an ionic ``ocean'' exists much deeper, water vapor, as well as ammonia dissolved in it, would be severely depleted at levels above this ocean. The consequences of such water vapor and ammonia depletions are that (1) clouds of water and ammonia, if present, are much less prominent; (2) only small amount of H2S vapor is removed by NH3, to form an NH4SH cloud; so that (3) a cloud of H2S-ice can now form; and (4) an H2O ``ocean'' in the 1-kilobar region [6] does not form. This scenario has important implications for the design of entry probe missions, as measurements to only 10-20 bars, rather than kilobar levels, will need to be made. The heavy elements, Ar, Kr, Xe, Ne, C, and S, as well as He, D/H, GeH4, AsH3, PH3, and CO can all be accessed at pressures less than 20 bars. These measurements are critical for constraining the formation models [5,7,8]. Measurement of water in the well-mixed region of Uranus and Neptune is technologically highly challenging, even if there were no ionic ocean. And, neither H2O nor NH3 can be accessed if there is a deep ionic ocean. On the other hand, if all other heavy elements and above species and isotopes were measured, O and N are not critical for the formation models of Uranus and Neptune [5]. References: [1] Podolak, et al., 1991, in Uranus (J. Bergstralh, et al., eds.), Univ. of Arizona Press. pp 48-49.1991; [2] Ree, FH, Physica, 1986, 139-140B, 73-78; [3] de Pater, et al., 1991, Icarus, 91, 220; [4] Baines, K, Hammel, H, 1994, Icarus, 109, 20 ; [5] Atreya, SK, and Wong, AS, pp121-126, in ``Outer Planets", T. Encrenaz, et al., eds, Springer, 2005; [6] Wiktorowicz, SJ, Ingersoll, AP, 2004 DPS 36.0501; [7] Owen, T, Encrenaz, T, 2003, 106, 121; [8] Atreya, S.K., et al., 2003, Planet Space Sci., 47. 1243.

Ortho-to-para abundance ratios of NH2 in 26 comets: implications for the real meaning of OPRs

NASA Astrophysics Data System (ADS)

Shinnaka, Yoshiharu; Kawakita, Hideyo; Jehin, Emmanuël; Decock, Alice; Hutsemékers, Damien; Manfroid, Jean

2016-11-01

Abundance ratios of nuclear-spin isomers for cometary molecules having identical protons, such as water and ammonia, have been measured and discussed from the viewpoint that they are primordial characters in comet. In the case of ammonia, its ortho-to-para abundance ratio (OPR) is usually estimated from OPRs of NH2 because of difficulty in measuring OPR of ammonia directly. We report our survey for OPRs of NH2 in 26 comets. A weighted mean of ammonia OPRs for the comets is 1.12 ± 0.01 and no significant difference is found between the Oort Cloud comets and the Jupiter-family comets. These values correspond to ˜30 K as nuclear-spin temperatures. The OPRs of ammonia in comets probably reflect the physicochemical conditions in coma, rather than the conditions for the molecular formation or condensation in the pre-solar molecular cloud/the solar nebula, based on comparison of OPRs (and nuclear-spin temperatures) of ammonia with those of water, 14N/15N ratios in ammonia, and D/H ratios in water. The OPRs could be reset to a nuclear-spin weights ratio in solid phase and modified by interactions with protonated ions like H3O+, water clusters (H2O)n, ice grains, and paramagnetic impurities (such as O2 molecules and grains) in the inner coma gas. Relationship between the OPRs of ammonia and water is a clue to understanding the real meaning of the OPRs.

A Condensation-coalescence Cloud Model for Exoplanetary Atmospheres: Formulation and Test Applications to Terrestrial and Jovian Clouds

NASA Astrophysics Data System (ADS)

Ohno, Kazumasa; Okuzumi, Satoshi

2017-02-01

A number of transiting exoplanets have featureless transmission spectra that might suggest the presence of clouds at high altitudes. A realistic cloud model is necessary to understand the atmospheric conditions under which such high-altitude clouds can form. In this study, we present a new cloud model that takes into account the microphysics of both condensation and coalescence. Our model provides the vertical profiles of the size and density of cloud and rain particles in an updraft for a given set of physical parameters, including the updraft velocity and the number density of cloud condensation nuclei (CCNs). We test our model by comparing with observations of trade-wind cumuli on Earth and ammonia ice clouds in Jupiter. For trade-wind cumuli, the model including both condensation and coalescence gives predictions that are consistent with observations, while the model including only condensation overestimates the mass density of cloud droplets by up to an order of magnitude. For Jovian ammonia clouds, the condensation-coalescence model simultaneously reproduces the effective particle radius, cloud optical thickness, and cloud geometric thickness inferred from Voyager observations if the updraft velocity and CCN number density are taken to be consistent with the results of moist convection simulations and Galileo probe measurements, respectively. These results suggest that the coalescence of condensate particles is important not only in terrestrial water clouds but also in Jovian ice clouds. Our model will be useful to understand how the dynamics, compositions, and nucleation processes in exoplanetary atmospheres affect the vertical extent and optical thickness of exoplanetary clouds via cloud microphysics.

AN INFRARED VIEW OF SATURN

NASA Technical Reports Server (NTRS)

2002-01-01

In honor of NASA Hubble Space Telescope's eighth anniversary, we have GIFt wrapped Saturn in vivid colors. Actually, this image is courtesy of the new Near Infrared Camera and Multi-Object Spectrometer (NICMOS), which has taken its first peek at Saturn. The false-color image - taken Jan. 4, 1998 - shows the planet's reflected infrared light. This view provides detailed information on the clouds and hazes in Saturn's atmosphere. The blue colors indicate a clear atmosphere down to a main cloud layer. Different shadings of blue indicate variations in the cloud particles, in size or chemical composition. The cloud particles are believed to be ammonia ice crystals. Most of the northern hemisphere that is visible above the rings is relatively clear. The dark region around the south pole at the bottom indicates a big hole in the main cloud layer. The green and yellow colors indicate a haze above the main cloud layer. The haze is thin where the colors are green but thick where they are yellow. Most of the southern hemisphere (the lower part of Saturn) is quite hazy. These layers are aligned with latitude lines, due to Saturn's east-west winds. The red and orange colors indicate clouds reaching up high into the atmosphere. Red clouds are even higher than orange clouds. The densest regions of two storms near Saturn's equator appear white. On Earth, the storms with the highest clouds are also found in tropical latitudes. The smaller storm on the left is about as large as the Earth, and larger storms have been recorded on Saturn in 1990 and 1994. The rings, made up of chunks of ice, are as white as images of ice taken in visible light. However, in the infrared, water absorption causes various colorations. The most obvious is the brown color of the innermost ring. The rings cast their shadow onto Saturn. The bright line seen within this shadow is sunlight shining through the Cassini Division, the separation between the two bright rings. It is best observed on the left side, just above the rings. This view is possible due to a rare geometry during the observation. The next time this is observable from Earth will be in 2006. An accurate investigation of the ring's shadow also shows sunlight shining through the Encke Gap, a thin division very close to the outer edge of the ring system. Two of Saturn's satellites were recorded, Dione on the lower left and Tethys on the upper right. Tethys is just ending its transit across the disk of Saturn. They appear in different colors, yellow and green, indicating different conditions on their icy surfaces. Wavelengths: A color image consists of three exposures (or three film layers). For visible true-color images, the wavelengths of these three exposures are 0.4, 0.5, and 0.6 micrometers for blue, green, and red light, respectively. This Saturn image was taken at longer infrared wavelengths of 1.0, 1.8, and 2.1 micrometers, displayed as blue, green, and red. Reflected sunlight is seen at all these wavelengths, since Saturn's own heat glows only at wavelengths above 4 micrometers. Image credit: Erich Karkoschka (University of Arizona), and NASA

The evolution of grain mantles and silicate dust growth at high redshift

NASA Astrophysics Data System (ADS)

Ceccarelli, Cecilia; Viti, Serena; Balucani, Nadia; Taquet, Vianney

2018-05-01

In dense molecular clouds, interstellar grains are covered by mantles of iced molecules. The formation of the grain mantles has two important consequences: it removes species from the gas phase and promotes the synthesis of new molecules on the grain surfaces. The composition of the mantle is a strong function of the environment that the cloud belongs to. Therefore, clouds in high-zeta galaxies, where conditions - like temperature, metallicity, and cosmic ray flux - are different from those in the Milky Way, will have different grain mantles. In the last years, several authors have suggested that silicate grains might grow by accretion of silicon-bearing species on smaller seeds. This would occur simultaneously with the formation of the iced mantles and be greatly affected by its composition as a function of time. In this work, we present a numerical study of the grain mantle formation in high-zeta galaxies, and we quantitatively address the possibility of silicate growth. We find that the mantle thickness decreases with increasing redshift, from about 120 to 20 layers for z varying from 0 to 8. Furthermore, the mantle composition is also a strong function of the cloud redshift, with the relative importance of CO, CO2, ammonia, methane, and methanol highly varying with z. Finally, being Si-bearing species always a very minor component of the mantle, the formation of silicates in molecular clouds is practically impossible.

A Condensation–coalescence Cloud Model for Exoplanetary Atmospheres: Formulation and Test Applications to Terrestrial and Jovian Clouds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ohno, Kazumasa; Okuzumi, Satoshi

A number of transiting exoplanets have featureless transmission spectra that might suggest the presence of clouds at high altitudes. A realistic cloud model is necessary to understand the atmospheric conditions under which such high-altitude clouds can form. In this study, we present a new cloud model that takes into account the microphysics of both condensation and coalescence. Our model provides the vertical profiles of the size and density of cloud and rain particles in an updraft for a given set of physical parameters, including the updraft velocity and the number density of cloud condensation nuclei (CCNs). We test our modelmore » by comparing with observations of trade-wind cumuli on Earth and ammonia ice clouds in Jupiter. For trade-wind cumuli, the model including both condensation and coalescence gives predictions that are consistent with observations, while the model including only condensation overestimates the mass density of cloud droplets by up to an order of magnitude. For Jovian ammonia clouds, the condensation–coalescence model simultaneously reproduces the effective particle radius, cloud optical thickness, and cloud geometric thickness inferred from Voyager observations if the updraft velocity and CCN number density are taken to be consistent with the results of moist convection simulations and Galileo probe measurements, respectively. These results suggest that the coalescence of condensate particles is important not only in terrestrial water clouds but also in Jovian ice clouds. Our model will be useful to understand how the dynamics, compositions, and nucleation processes in exoplanetary atmospheres affect the vertical extent and optical thickness of exoplanetary clouds via cloud microphysics.« less

New Particle Formation in an Urban Atmosphere: The Role of Various Ingredients Investigated in the CLOUD Chamber

NASA Astrophysics Data System (ADS)

Baltensperger, U.; Xiao, M.; Hoyle, C.; Dada, L.; Garmash, O.; Stolzenburg, D.; Molteni, U.; Lehtipalo, K.; El-Haddad, I.; Dommen, J.

2017-12-01

Atmospheric aerosols play an important role on climate via aerosol-radiation interaction and aerosol-cloud interaction. The latter is strongly influenced by new particle formation (NPF). The physical and chemical mechanisms behind the NPF process are still under investigation. Great advancements were made in resolving chemical and physical mechanisms of NPF with a series of experiments conducted at the CLOUD (Cosmics Leaving Outdoor Droplets) chamber facility at CERN (Geneva, Switzerland), including binary nucleation of sulfuric acid - water, ternary nucleation of sulfuric acid - water with ammonia or dimethylamine as well as oxidation products (highly oxygenated molecules, HOMs) from biogenic precursors with and without the presence of sulfuric acid. Here, we investigate possible NPF mechanisms in urban atmospheres, where large populations are exposed to high aerosol concentrations; these mechanisms are still missing and are urgently needed. Urban atmospheres are highly polluted with high concentrations of SO2, ammonia, NOx and volatile organic vapors from anthropogenic activity as well as with high particle concentrations, which provide a high condensation sink for condensable gases. Aromatic hydrocarbons from industrial activities, traffic and residential combustion are present at high concentrations and contribute significantly to photochemical smog in the urban environment.The experiments were conducted at the CLOUD chamber facility during the CLOUD11 campaign in fall 2016. Three aromatic hydrocarbons were selected: toluene, 1,2,4-trimethylbenzene (1,2,4-TMB) and naphthalene (NPT). Experiments were also conducted with mixtures of the three aromatic hydrocarbons to better represent the urban atmosphere. All the experiments were conducted in the presence of sulfuric acid concentrations with or without the addition of ammonia and NOx. New particle formation rates and early growth rates derived for each precursor and their mixture, together with sulfuric acid and with or without the addition of ammonia and NOx will be reported.

Novel time-temperature and 'consume-within' indicator based on gas-diffusion.

PubMed

Mills, A; Hawthorne, D; Graham, A; Lawrie, K

2016-11-29

The novel time-temperature indicator label comprises an ammonia sensitive indicator layer film pressed onto a second film, comprising an ammonia-generating, adhesive layer. When separated the blue-coloured indicator film reverts back to its original (ammonia free) yellow form at a controllable, temperature dependant rate. The labels are easily made and stored.

Photo-EMF sensitivity of porous silicon thin layer-crystalline silicon heterojunction to ammonia adsorption.

PubMed

Vashpanov, Yuriy; Jung, Jae Il; Kwack, Kae Dal

2011-01-01

A new method of using photo-electromotive force in detecting gas and controlling sensitivity is proposed. Photo-electromotive force on the heterojunction between porous silicon thin layer and crystalline silicon wafer depends on the concentration of ammonia in the measurement chamber. A porous silicon thin layer was formed by electrochemical etching on p-type silicon wafer. A gas and light transparent electrical contact was manufactured to this porous layer. Photo-EMF sensitivity corresponding to ammonia concentration in the range from 10 ppm to 1,000 ppm can be maximized by controlling the intensity of illumination light.

Contribution of Arctic seabird-colony ammonia to atmospheric particles and cloud-albedo radiative effect

NASA Astrophysics Data System (ADS)

Croft, B.; Wentworth, G. R.; Martin, R. V.; Leaitch, W. R.; Murphy, J. G.; Murphy, B. N.; Kodros, J. K.; Abbatt, J. P. D.; Pierce, J. R.

2016-11-01

The Arctic region is vulnerable to climate change and able to affect global climate. The summertime Arctic atmosphere is pristine and strongly influenced by natural regional emissions, which have poorly understood climate impacts related to atmospheric particles and clouds. Here we show that ammonia from seabird-colony guano is a key factor contributing to bursts of newly formed particles, which are observed every summer in the near-surface atmosphere at Alert, Nunavut, Canada. Our chemical-transport model simulations indicate that the pan-Arctic seabird-influenced particles can grow by sulfuric acid and organic vapour condensation to diameters sufficiently large to promote pan-Arctic cloud-droplet formation in the clean Arctic summertime. We calculate that the resultant cooling tendencies could be large (about -0.5 W m-2 pan-Arctic-mean cooling), exceeding -1 W m-2 near the largest seabird colonies due to the effects of seabird-influenced particles on cloud albedo. These coupled ecological-chemical processes may be susceptible to Arctic warming and industrialization.

Contribution of Arctic seabird-colony ammonia to atmospheric particles and cloud-albedo radiative effect.

PubMed

Croft, B; Wentworth, G R; Martin, R V; Leaitch, W R; Murphy, J G; Murphy, B N; Kodros, J K; Abbatt, J P D; Pierce, J R

2016-11-15

The Arctic region is vulnerable to climate change and able to affect global climate. The summertime Arctic atmosphere is pristine and strongly influenced by natural regional emissions, which have poorly understood climate impacts related to atmospheric particles and clouds. Here we show that ammonia from seabird-colony guano is a key factor contributing to bursts of newly formed particles, which are observed every summer in the near-surface atmosphere at Alert, Nunavut, Canada. Our chemical-transport model simulations indicate that the pan-Arctic seabird-influenced particles can grow by sulfuric acid and organic vapour condensation to diameters sufficiently large to promote pan-Arctic cloud-droplet formation in the clean Arctic summertime. We calculate that the resultant cooling tendencies could be large (about -0.5 W m -2 pan-Arctic-mean cooling), exceeding -1 W m -2 near the largest seabird colonies due to the effects of seabird-influenced particles on cloud albedo. These coupled ecological-chemical processes may be susceptible to Arctic warming and industrialization.

Modeling marine boundary-layer clouds with a two-layer model: A one-dimensional simulation

NASA Technical Reports Server (NTRS)

Wang, Shouping

1993-01-01

A two-layer model of the marine boundary layer is described. The model is used to simulate both stratocumulus and shallow cumulus clouds in downstream simulations. Over cold sea surfaces, the model predicts a relatively uniform structure in the boundary layer with 90%-100% cloud fraction. Over warm sea surfaces, the model predicts a relatively strong decoupled and conditionally unstable structure with a cloud fraction between 30% and 60%. A strong large-scale divergence considerably limits the height of the boundary layer and decreases relative humidity in the upper part of the cloud layer; thus, a low cloud fraction results. The efffects of drizzle on the boundary-layer structure and cloud fraction are also studied with downstream simulations. It is found that drizzle dries and stabilizes the cloud layer and tends to decouple the cloud from the subcloud layer. Consequently, solid stratocumulus clouds may break up and the cloud fraction may decrease because of drizzle.

An Infrared View of Saturn

NASA Technical Reports Server (NTRS)

1998-01-01

In honor of NASA Hubble Space Telescope's eighth anniversary, we have gift wrapped Saturn in vivid colors. Actually, this image is courtesy of the new Near Infrared Camera and Multi-Object Spectrometer (NICMOS), which has taken its first peek at Saturn. The false-color image - taken Jan. 4, 1998 - shows the planet's reflected infrared light. This view provides detailed information on the clouds and hazes in Saturn's atmosphere.

The blue colors indicate a clear atmosphere down to a main cloud layer. Different shadings of blue indicate variations in the cloud particles, in size or chemical composition. The cloud particles are believed to be ammonia ice crystals. Most of the northern hemisphere that is visible above the rings is relatively clear. The dark region around the south pole at the bottom indicates a big hole in the main cloud layer.

The green and yellow colors indicate a haze above the main cloud layer. The haze is thin where the colors are green but thick where they are yellow. Most of the southern hemisphere (the lower part of Saturn) is quite hazy. These layers are aligned with latitude lines, due to Saturn's east-west winds.

The red and orange colors indicate clouds reaching up high into the atmosphere. Red clouds are even higher than orange clouds. The densest regions of two storms near Saturn's equator appear white. On Earth, the storms with the highest clouds are also found in tropical latitudes. The smaller storm on the left is about as large as the Earth, and larger storms have been recorded on Saturn in 1990 and 1994.

The rings, made up of chunks of ice, are as white as images of ice taken in visible light. However, in the infrared, water absorption causes various colorations. The most obvious is the brown color of the innermost ring. The rings cast their shadow onto Saturn. The bright line seen within this shadow is sunlight shining through the Cassini Division, the separation between the two bright rings. It is best observed on the left side, just above the rings. This view is possible due to a rare geometry during the observation. The next time this observable from Earth will be in 2006. An accurate investigation of the ring's shadow also shows sunlight shining through the Encke Gap, a thin division very close to the outer edge of the ring system.

Two of Saturn's satellites were recorded, Dione on the lower left and Tethys on the upper right. Tethys is just ending its transit across the disk of Saturn. They appear in different colors, yellow and green, indicating different conditions on their icy surfaces.

Wavelengths: A color image consists of three exposures (or three film layers). For visible true-color images, the wavelengths of these three exposures are 0.4, 0.5, and 0.6 micrometers for blue, green, and red light, respectively. This Saturn image was taken at longer infrared wavelengths of 1.0, 1.8, and 2.1 micrometers, displayed as blue, green, and red. Reflected sunlight is seen at all these wavelengths, since Saturn's own heat glows only at wavelengths above 4 micrometers.

The Wide Field/Planetary Camera 2 was developed by the Jet Propulsion Laboratory and managed by the Goddard Spaced Flight Center for NASA's Office of Space Science.

This image and other images and data received from the Hubble Space Telescope are posted on the World Wide Web on the Space Telescope Science Institute home page at URL http://oposite.stsci.edu/pubinfo/

Studies of star formation in isolated small dark clouds - II. A southern ammonia survey

NASA Astrophysics Data System (ADS)

Bourke, T. L.; Hyland, A. R.; Robinson, G.; James, S. D.; Wright, C. M.

1995-10-01

A study of the set of small, southern molecular clouds (globules) compiled by Bourke, Hyland & Robinson has been undertaken, through radio observations of ammonia using the Parkes 64-m telescope. The aim of the study is to determine the physical characteristics of the globules, their role in the formation of low-mass stars, and the physical mechanism that triggers the star formation process, or stabilizes the globules against collapse. With this general aim in mind, the (1,1) and (2,2) inversion transitions of ammonia have been surveyed in order to determine the densities, temperatures and masses of the globules. Half of the globules have been detected in ammonia, but only 6 per cent of the detections are `strong' (T*_a>=0.35K). Comparing the globule properties with those of Benson & Myers for cores within complexes, we find that the globules are less opaque and less dense, and are less active sites of star formation. Other properties are comparable. The Vela cometary globules are detected more readily in ammonia than the more isolated globules, and are more active star formation sites. These results suggest that the dense core's environment, in particular the presence of either a large external mass or a significant stellar wind, plays an important role in initiating the star formation process.

Nitrification and the ammonia-oxidizing communities in the central Baltic Sea water column

NASA Astrophysics Data System (ADS)

Jäntti, Helena; Ward, Bess B.; Dippner, Joachim W.; Hietanen, Susanna

2018-03-01

The redoxclines that form between the oxic and anoxic water layers in the central Baltic Sea are sites of intensive nitrogen cycling. To gain better understanding of nitrification, we measured the biogeochemical properties along with potential nitrification rates and analyzed the assemblages of ammonia-oxidizing bacteria and archaea using functional gene microarrays. To estimate nitrification in the entire water column, we constructed a regression model for the nitrification rates and applied it to the conditions prevailing in the area in 2008-2012. The highest ammonia oxidation rates were found in a thin layer at the top of the redoxcline and the rates quickly decreased below detection limit when oxygen was exhausted. This is probably because extensive suboxic layers, which are known to harbor pelagic nitrification, are formed only for short periods after inflows in the Baltic Sea. The nitrification rates were some of the highest measured in the water columns, but the thickness of the layer where conditions were favorable for nitrification, was very small and it remained fairly stable between years. However, the depth of the nitrification layer varied substantially between years, particularly in the eastern Gotland Basin (EGB) due to turbulence in the water column. The ammonia oxidizer communities clustered differently between the eastern and western Gotland Basin (WGB) and the composition of ammonia-oxidizing assemblages correlated with the environmental variables. The ammonia oxidizer community composition was more even in the EGB, which may be related to physical instability of the redoxcline that does not allow predominance of a single archetype, whereas in the WGB, where the position of the redoxcline is more constant, the ammonia-oxidizing community was less even. Overall the ammonia-oxidizing communities in the Baltic Sea redoxclines were very evenly distributed compared to other marine environments where microarrays have been applied previously.

Cloud layer thicknesses from a combination of surface and upper-air observations

NASA Technical Reports Server (NTRS)

Poore, Kirk D.; Wang, Junhong; Rossow, William B.

1995-01-01

Cloud layer thicknesses are derived from base and top altitudes by combining 14 years (1975-1988) of surface and upper-air observations at 63 sites in the Northern Hemisphere. Rawinsonde observations are employed to determine the locations of cloud-layer top and base by testing for dewpoint temperature depressions below some threshold value. Surface observations serve as quality checks on the rawinsonde-determined cloud properties and provide cloud amount and cloud-type information. The dataset provides layer-cloud amount, cloud type, high, middle, or low height classes, cloud-top heights, base heights and layer thicknesses, covering a range of latitudes from 0 deg to 80 deg N. All data comes from land sites: 34 are located in continental interiors, 14 are near coasts, and 15 are on islands. The uncertainties in the derived cloud properties are discussed. For clouds classified by low-, mid-, and high-top altitudes, there are strong latitudinal and seasonal variations in the layer thickness only for high clouds. High-cloud layer thickness increases with latitude and exhibits different seasonal variations in different latitude zones: in summer, high-cloud layer thickness is a maximum in the Tropics but a minimum at high latitudes. For clouds classified into three types by base altitude or into six standard morphological types, latitudinal and seasonal variations in layer thickness are very small. The thickness of the clear surface layer decreases with latitude and reaches a summer minimum in the Tropics and summer maximum at higher latitudes over land, but does not vary much over the ocean. Tropical clouds occur in three base-altitude groups and the layer thickness of each group increases linearly with top altitude. Extratropical clouds exhibit two groups, one with layer thickness proportional to their cloud-top altitude and one with small (less than or equal to 1000 m) layer thickness independent of cloud-top altitude.

Odour and ammonia emissions from intensive poultry units in Ireland.

PubMed

Hayes, E T; Curran, T P; Dodd, V A

2006-05-01

Odour and ammonia emissions were measured from three broiler, two layer and two turkey houses in Ireland. The broiler units gave a large range of odour and ammonia emission rates depending on the age of the birds and the season. A considerable variation between the odour and ammonia emission rates was evident for the two layer units which may have been due to the different manure handling systems utilised in the houses. There was relatively little difference in the odour and ammonia emissions from the two turkey houses. As a precautionary principle, odour emission rates utilised in atmospheric dispersion models should use the maximum values for broilers and turkeys (1.22 and 10.5 ou(E) s(-1) bird(-1) respectively) and the mean value for the layers depending on the manure handling system used (0.47 or 1.35 ou(E) s(-1) bird(-1)).

Chromophores from photolyzed ammonia reacting with acetylene: Application to Jupiter's Great Red Spot

NASA Astrophysics Data System (ADS)

Carlson, R. W.; Baines, K. H.; Anderson, M. S.; Filacchione, G.; Simon, A. A.

2016-08-01

The high altitude of Jupiter's Great Red Spot (GRS) may enhance the upward flux of gaseous ammonia (NH3) into the high troposphere, where NH3 molecules can be photodissociated and initiate a chain of chemical reactions with downwelling acetylene molecules (C2H2). These reactions, experimentally studied earlier by (Ferris and Ishikawa [1987] Nature 326, 777-778) and (Ferris and Ishikawa [1988] J. Amer. Chem. Soc. 110, 4306-4312), produce chromophores that absorb in the visible and ultraviolet regions. In this work we photolyzed mixtures of NH3 and C2H2 using ultraviolet radiation with a wavelength of 214 nm and measured the spectral transmission of the deposited films in the visible region (400-740 nm). From these transmission data we estimated the imaginary indices of refraction. Assuming that ammonia grains at the top of the GRS clouds are coated with this material, we performed layered sphere and radiative transfer calculations to predict GRS reflection spectra. Comparison of those results with observed and previously unreported Cassini visible spectra and with true-color images of the GRS show that the unknown GRS chromophore is spectrally consistent with the coupled NH3-C2H2 photochemical products produced in our laboratory experiments. Using high-resolution mass spectrometry and infrared spectroscopy we infer that the chromophore-containing residue is composed of aliphatic azine, azo, and diazo compounds.

Chromophores from photolyzed ammonia reacting with acetylene: Application to Jupiters Great Red Spot

NASA Technical Reports Server (NTRS)

Carlson, Robert W.; Baines, Kevin H.; Anderson, M. S.; Filacchione, G.; Simon, A. A.

2016-01-01

The high altitude of Jupiter's Great Red Spot (GRS) may enhance the upward flux of gaseous ammonia (NH3 ) into the high troposphere, where NH3 molecules can be photodissociated and initiate a chain of chemical reactions with downwelling acetylene molecules (C2H2 ). These reactions, experimentally studied earlier by (Ferris and Ishikawa [1987] Nature 326, 777-778) and (Ferris and Ishikawa [1988] J. Amer. Chem. Soc. 110, 4306-4312), produce chromophores that absorb in the visible and ultraviolet regions. In this work we photolyzed mixtures of NH3 and C2H2 using ultraviolet radiation with a wavelength of 214 nm and measured the spectral transmission of the deposited films in the visible region (400-740 nm). From these transmission data we estimated the imaginary indices of refraction. Assuming that ammonia grains at the top of the GRS clouds are coated with this material, we performed layered sphere and radiative transfer calculations to predict GRS reflection spectra. Comparison of those results with observed and previously unreported Cassini visible spectra and with true-color images of the GRS show that the unknown GRS chromophore is spectrally consistent with the coupled NH3-C2H2 photochemical products produced in our laboratory experiments. Using high-resolution mass spectrometry and infrared spectroscopy we infer that the chromophore-containing residue is composed of aliphatic azine, azo, and diazo compounds.

Backscatter laser depolarization studies of simulated stratospheric aerosols - Crystallized sulfuric acid droplets

NASA Technical Reports Server (NTRS)

Sassen, Kenneth; Zhao, Hongjie; Yu, Bing-Kun

1989-01-01

The optical depolarizing properties of simulated stratospheric aerosols were studied in laboratory laser (0.633 micrometer) backscattering experiments for application to polarization lidar observations. Clouds composed of sulfuric acid solution droplets, some treated with ammonia gas, were observed during evaporation. The results indicate that the formation of minute ammonium sulfate particles from the evaporation of acid droplets produces linear depolarization ratios of beta equivalent to 0.02, but beta equivalent to 0.10 to 0.15 are generated from aged acid cloud aerosols and acid droplet crystalization effects following the introduction of ammonia gas into the chamber. It is concluded that partially crystallized sulfuric acid droplets are a likely candidate for explaining the lidar beta equivalent to 0.10 values that have been observed in the lower stratosphere in the absence of the relatively strong backscattering from homogeneous sulfuric acid droplet (beta equivalent to 0) or ice crystal (beta equivalent to 0.5) clouds.

Backscatter laser depolarization studies of simulated stratospheric aerosols: Crystallized sulfuric acid droplets

NASA Technical Reports Server (NTRS)

Sassen, Kenneth; Zhao, Hongjie; Yu, Bing-Kun

1988-01-01

The optical depolarizing properties of simulated stratospheric aerosols were studied in laboratory laser (0.633 micrometer) backscattering experiments for application to polarization lidar observations. Clouds composed of sulfuric acid solution droplets, some treated with ammonia gas, were observed during evaporation. The results indicate that the formation of minute ammonium sulfate particles from the evaporation of acid droplets produces linear depolarization ratios of beta equivalent to 0.02, but beta equivalent to 0.10 to 0.15 are generated from aged acid cloud aerosols and acid droplet crystallization effects following the introduction of ammonia gas into the chamber. It is concluded that partially crystallized sulfuric acid droplets are a likely candidate for explaining the lidar beta equivalent to 0.10 values that have been observed in the lower stratosphere in the absence of the relatively strong backscattering from homogeneous sulfuric acid droplet (beta equivalent to 0) or ice crystal (beta equivalent to 0.5) clouds.

Jovian cloud structure from 5-mu M images

NASA Astrophysics Data System (ADS)

Ortiz, J. L.; Moreno, F.; Molina, A.; Roos-Serote, M.; Orton, G. S.

1999-09-01

Most radiative transfer studies place the cloud clearings responsible for the 5-mu m bright areas at pressure levels greater than 1.5 bar whereas the low-albedo clouds are placed at lower pressure levels, in the so-called ammonia cloud. If this picture is correct, and assuming that the strong vertical shear of the zonal wind detected by the Galileo Entry Probe exists at all latitudes in Jupiter, the bright areas at 5 mu m should drift faster than the dark clouds, which is not observed. At the Galileo Probe Entry latitude this can be explained by a wave, but this is not a likely explanation for all regions where the anticorrelation between 5-mu m brightness and red-nIR reflectivity is observed. Therefore, either the vertical zonal wind shears are not global or cloud clearings and dark clouds are located at the same pressure level. We have developed a multiple scattering radiative transfer code to model the limb-darkening at several jovian features derived from IRTF 4.8-mu m images, in order to retrieve information on the cloud levels. The limb darkening coefficients range from 1.4 at hot spots to 0.58 at the Equatorial Region. We also find that reflected light is dominant over thermal emission in the Equatorial Region, as already pointed out by other investigators. Preliminary results from our code tend to favor the idea that the ammonia cloud is a very high-albedo cloud with little influence on the contrast seen in the red and nIR and that a deeper cloud at P >1.5 bar can be responsible for the cloud clearings and for the low-albedo features simultaneously. This research was supported by the Comision Interministerial de Ciencia y Tecnologia under contract ESP96-0623.

NIMS Spectral Maps of Jupiter Great Red Spot

NASA Image and Video Library

1998-03-26

The Near-Infrared Mapping Spectrometer (NIMS) instrument looks at Jupiter's Great Red Spot, in these views from June 26, 1996. NIMS studies infrared wavelengths of light that our eye cannot see. These maps are at four different infrared wavelengths, each one picked to reveal something different about the atmosphere. The top image is a false color map of a wavelength that is at the red edge of our ability to see. It shows the shapes of features that we would see with our eyes. The second map is of ammonia ice, red showing where the most ice is, blue where none exists. The differences between this and the first image are due to the amount and size of ammonia ice crystals. The third map down is from a wavelength that shows cloud heights, with the highest clouds in red, and the lowest in blue. The bottom map uses a wavelength that shows the hot Jupiter shining through the clouds. Red represents the thinnest clouds, and blue is thickest where it is more difficult to see below. Comparing the bottom two images, note that the highest clouds are in the center of the Great Red Spot, while there are relatively few clouds around the edges. http://photojournal.jpl.nasa.gov/catalog/PIA00501

The Green Bank Ammonia Survey: Dense Cores under Pressure in Orion A

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kirk, Helen; Di Francesco, James; Friesen, Rachel K.

We use data on gas temperature and velocity dispersion from the Green Bank Ammonia Survey and core masses and sizes from the James Clerk Maxwell Telescope Gould Belt Survey to estimate the virial states of dense cores within the Orion A molecular cloud. Surprisingly, we find that almost none of the dense cores are sufficiently massive to be bound when considering only the balance between self-gravity and the thermal and non-thermal motions present in the dense gas. Including the additional pressure binding imposed by the weight of the ambient molecular cloud material and additional smaller pressure terms, however, suggests thatmore » most of the dense cores are pressure-confined.« less

The Green Bank Ammonia Survey: Dense Cores under Pressure in Orion A

NASA Astrophysics Data System (ADS)

Kirk, Helen; Friesen, Rachel K.; Pineda, Jaime E.; Rosolowsky, Erik; Offner, Stella S. R.; Matzner, Christopher D.; Myers, Philip C.; Di Francesco, James; Caselli, Paola; Alves, Felipe O.; Chacón-Tanarro, Ana; Chen, How-Huan; Chun-Yuan Chen, Michael; Keown, Jared; Punanova, Anna; Seo, Young Min; Shirley, Yancy; Ginsburg, Adam; Hall, Christine; Singh, Ayushi; Arce, Héctor G.; Goodman, Alyssa A.; Martin, Peter; Redaelli, Elena

2017-09-01

We use data on gas temperature and velocity dispersion from the Green Bank Ammonia Survey and core masses and sizes from the James Clerk Maxwell Telescope Gould Belt Survey to estimate the virial states of dense cores within the Orion A molecular cloud. Surprisingly, we find that almost none of the dense cores are sufficiently massive to be bound when considering only the balance between self-gravity and the thermal and non-thermal motions present in the dense gas. Including the additional pressure binding imposed by the weight of the ambient molecular cloud material and additional smaller pressure terms, however, suggests that most of the dense cores are pressure-confined.

ISO ammonia line absorption reveals a layer of hot gas veiling Sgr B2

NASA Astrophysics Data System (ADS)

Ceccarelli, C.; Baluteau, J.-P.; Walmsley, M.; Swinyard, B. M.; Caux, E.; Sidher, S. D.; Cox, P.; Gry, C.; Kessler, M.; Prusti, T.

2002-02-01

We report the first results of the unbiased spectral high resolution survey obtained towards Sgr B2 with the Long Wavelength Spectrometer on board ISO. The survey detected more than one hundreds lines from several molecules. Ammonia is the molecule with the largest number (21) of detected lines in the survey. We detected NH3 transitions from levels with energies from 45 to 500 cm-1. The detected transitions are from both para and ortho ammonia and metastable and non-metastable levels. All the ammonia lines are in absortion against the FIR continuum of Sgr B2. With such a large number of detected lines in such a large range of energy levels, we could very efficiently constrain the main parameters of the absorbing gas layer. The gas is at (700 +/- 100) K and has a density lower than 104 cm-3. The total NH3 column density in the layer is (3+/- 1) x 1016 cm-2, equally shared between ortho and para ammonia. Given the derived relatively high gas temperature and ammonia column density, our observations support the hypothesis previously proposed of a layer of shocked gas between us and Sgr B2. We also discuss previous observations of far infrared line absorption from other molecules, like H2O and HF, in the light of this hot absorbing layer. If the absorption is done by the hot absorbing layer rather than by the warm envelope surrounding Sgr B2, as was previously supposed in order to interpret the mentioned observations, the derived H2O and HF abundances are one order of magitude larger than previously estimated. Yet, the present H2O and HF observations do not allow one to disentangle the absorption from the hot layer against the warm envelope. Our conclusions are hence that care should be applied when interpreting the absorption observations in Sgr B2, as the hot layer clearly seen in the ammonia transitions may substantially contribute to the absorption. ISO is an ESA project with instruments funded by ESA Member States (especially the PI countries: France, Germany, The Netherlands and the United Kingdom) and with the participation of ISAS and NASA.

Contribution of Arctic seabird-colony ammonia to atmospheric particles and cloud-albedo radiative effect

PubMed Central

Croft, B.; Wentworth, G. R.; Martin, R. V.; Leaitch, W. R.; Murphy, J. G.; Murphy, B. N.; Kodros, J. K.; Abbatt, J. P. D.; Pierce, J. R.

2016-01-01

The Arctic region is vulnerable to climate change and able to affect global climate. The summertime Arctic atmosphere is pristine and strongly influenced by natural regional emissions, which have poorly understood climate impacts related to atmospheric particles and clouds. Here we show that ammonia from seabird-colony guano is a key factor contributing to bursts of newly formed particles, which are observed every summer in the near-surface atmosphere at Alert, Nunavut, Canada. Our chemical-transport model simulations indicate that the pan-Arctic seabird-influenced particles can grow by sulfuric acid and organic vapour condensation to diameters sufficiently large to promote pan-Arctic cloud-droplet formation in the clean Arctic summertime. We calculate that the resultant cooling tendencies could be large (about −0.5 W m−2 pan-Arctic-mean cooling), exceeding −1 W m−2 near the largest seabird colonies due to the effects of seabird-influenced particles on cloud albedo. These coupled ecological–chemical processes may be susceptible to Arctic warming and industrialization. PMID:27845764

Saturns Thermal Emission at 2.2-cm Wavelength as Imaged by the Cassini RADAR Radiometer

NASA Technical Reports Server (NTRS)

Janssen, M. A.; Ingersoll, A. P.; Allison, M. D.; Gulkis, S.; Laraia, A. L.; Baines, K. H.; Edgington, S. G.; Anderson, Y. Z.; Kelleher, K.; Oyafuso, F. A.

2013-01-01

We present well-calibrated, high-resolution maps of Saturn's thermal emission at 2.2-cm wavelength obtained by the Cassini RADAR radiometer through the Prime and Equinox Cassini missions, a period covering approximately 6 years. The absolute brightness temperature calibration of 2% achieved is more than twice better than for all previous microwave observations reported for Saturn, and the spatial resolution and sensitivity achieved each represent nearly an order of magnitude improvement. The brightness temperature of Saturn in the microwave region depends on the distribution of ammonia, which our radiative transfer modeling shows is the only significant source of absorption in Saturn's atmosphere at 2.2-cm wavelength. At this wavelength the thermal emission comes from just below and within the ammonia cloud-forming region, and yields information about atmospheric circulations and ammonia cloud-forming processes. The maps are presented as residuals compared to a fully saturated model atmosphere in hydrostatic equilibrium. Bright regions in these maps are readily interpreted as due to depletion of ammonia vapor in, and, for very bright regions, below the ammonia saturation region. Features seen include the following: a narrow equatorial band near full saturation surrounded by bands out to about 10deg planetographic latitude that demonstrate highly variable ammonia depletion in longitude; narrow bands of depletion at -35deg latitude; occasional large oval features with depleted ammonia around -45deg latitude; and the 2010-2011 storm, with extensive saturated and depleted areas as it stretched halfway around the planet in the northern hemisphere. Comparison of the maps over time indicates a high degree of stability outside a few latitudes that contain active regions.

Jupiter in blue, ultraviolet and near infrared

NASA Technical Reports Server (NTRS)

2000-01-01

These three images of Jupiter, taken through the narrow angle camera of NASA's Cassini spacecraft from a distance of 77.6 million kilometers (48.2 million miles) on October 8, reveal more than is apparent to the naked eye through a telescope.

The image on the left was taken through the blue filter. The one in the middle was taken in the ultraviolet. The one on the right was taken in the near infrared.

The blue-light filter is within the part of the electromagnetic spectrum detectable by the human eye. The appearance of Jupiter in this image is, consequently, very familiar. The Great Red Spot (below and to the right of center) and the planet's well-known banded cloud lanes are obvious. The brighter bands of clouds are called zones and are probably composed of ammonia ice particles. The darker bands are called belts and are made dark by particles of unknown composition intermixed with the ammonia ice.

Jupiter's appearance changes dramatically in the ultraviolet and near infrared images. These images are near negatives of each other and illustrate the way in which observations in different wavelength regions can reveal different physical regimes on the planet.

All gases scatter sunlight efficiently at short wavelengths; this is why the sky appears blue on Earth. The effect is even more pronounced in the ultraviolet. The gases in Jupiter's atmosphere, above the clouds, are no different. They scatter strongly in the ultraviolet, making the deep banded cloud layers invisible in the middle image. Only the very high altitude haze appears dark against the bright background. The contrast is reversed in the near infrared, where methane gas, abundant on Jupiter but not on Earth, is strongly absorbing and therefore appears dark. Again the deep clouds are invisible, but now the high altitude haze appears relatively bright against the dark background. High altitude haze is seen over the poles and the equator.

The Great Red Spot, prominent in all images, is obviously a feature whose influence extends high in the atmosphere. As the Cassini cameras continue to return images of Jupiter, it will be possible to construct a three-dimensional picture of how clouds form and evolve by watching the changing appearance of Jupiter in different spectral regions.

JPL manages the Cassini mission for NASA's Office of Space Science, Washington, D.C. JPl is a division of the California Institute of Technology in Pasadena.

Global atmospheric particle formation from CERN CLOUD measurements

NASA Astrophysics Data System (ADS)

Dunne, Eimear M.; Gordon, Hamish; Carslaw, Kenneth S.

2017-04-01

New particle formation (or nucleation) is acknowledged as a significant source of climate-relevant aerosol throughout the atmosphere. However, performing atmospherically relevant nucleation experiments in a laboratory setting is extremely challenging. As a result, until now, the parameterisations used to represent new particle formation in global aerosol models were largely based on in-situ observations or theoretical nucleation models, and usually only represented the binary H2SO4-H2O system. Several different chemicals can affect particle formation rates, even at extremely low trace concentrations, which are technically challenging to measure directly. Nucleation rates also respond to environmental changes in e.g. temperature in a highly non-linear fashion. The CERN CLOUD experiment was designed to provide the most controlled and accurate nucleation rate measurements to date, over the full range of free tropospheric temperatures and down to sulphuric acid concentrations of the order of 105 cm-3. We will present a parameterisation of inorganic nucleation rates for use in global models, based on these measurements, which includes four separate nucleation pathways: binary neutral, binary ion-induced, ternary neutral, and ternary ion-induced. Both inorganic and organic nucleation parameterisations derived from CLOUD measurements have been implemented in the GLOMAP global aerosol model. The parameterisations depend on temperature and on concentrations of sulphuric acid, ammonia, organic vapours, and ions. One of CLOUD's main original goals was to determine the sensitivity of atmospheric aerosol to changes in the nucleation rate over a solar cycle. We will show that, in a present-day atmosphere, the changes in climate-relevant aerosol (in the form of cloud-level cloud condensation nuclei) over a solar cycle are on average about 0.1%, with local changes of less than 1%. In contrast, anthropogenic changes in ammonia since pre-industrial times were estimated to have a much greater influence, resulting in a radiative forcing of between -0.62 and -0.66 W m-2. Including ternary inorganic pathways in GLOMAP improved the model's agreement with free tropospheric observations, especially aircraft measurements. The further inclusion of an organic parameterisation, which increased nucleation in the summertime boundary layer, brought our results more in line with observations made at surface stations. We therefore believe that, while the addition of other nucleation pathways (such as amine-induced nucleation) will doubtless improve agreement with local in-situ measurements, this model set-up provides a good representation of the global atmosphere as a whole. By presenting this novel parameterisation at EGU, we hope to encourage its uptake among the aerosol modelling community.

Evaluation of multi-layer cloud detection based on MODIS CO2-slicing algorithm with CALIPSO-CloudSat measurements.

NASA Astrophysics Data System (ADS)

Viudez-Mora, A.; Kato, S.; Smith, W. L., Jr.; Chang, F. L.

2016-12-01

Knowledge of the vertical cloud distribution is important for a variety of climate and weather applications. The cloud overlapping variations greatly influence the atmospheric heating/cooling rates, with implications for the surface-troposphere radiative balance, global circulation and precipitation. Additionally, an accurate knowledge of the multi-layer cloud distribution in real-time can be used in applications such safety condition for aviation through storms and adverse weather conditions. In this study, we evaluate a multi-layered cloud algorithm (Chang et al. 2005) based on MODIS measurements aboard Aqua satellite (MCF). This algorithm uses the CO2-slicing technique combined with cloud properties determined from VIS, IR and NIR channels to locate high thin clouds over low-level clouds, and retrieve the τ of each layer. We use CALIPSO (Winker et. al, 2010) and CloudSat (Stephens et. al, 2002) (CLCS) derived cloud vertical profiles included in the C3M data product (Kato et al. 2010) to evaluate MCF derived multi-layer cloud properties. We focus on 2 layer overlapping and 1-layer clouds identified by the active sensors and investigate how well these systems are identified by the MODIS multi-layer technique. The results show that for these multi-layered clouds identified by CLCS, the MCF correctly identifies about 83% of the cases as multi-layer. However, it is found that the upper CTH is underestimated by about 2.6±0.4 km, because the CO2-slicing technique is not as sensitive to the cloud physical top as the CLCS. The lower CTH agree better with differences found to be about 1.2±0.5 km. Another outstanding issue for the MCF approach is the large number of multi-layer false alarms that occur in single-layer conditions. References: Chang, F.-L., and Z. Li, 2005: A new method for detection of cirrus overlapping water clouds and determination of their optical properties. J. Atmos. Sci., 62. Kato, S., et al. (2010), Relationships among cloud occurrence frequency, overlap, and effective thickness derived from CALIPSO and CloudSat merged cloud vertical profiles, J. Geophys. Res., 115. Stephens, G. L., et al. (2002), The CloudSat mission and A-Train, Bull. Am. Meteorol. Soc., 83. Winker, D. M., et al., 2010: The CALIPSO Mission: A global 3D view of aerosols and clouds. Bull. Amer. Meteor. Soc., 91.

RACORO Extended-Term Aircraft Observations of Boundary-Layer Clouds

NASA Technical Reports Server (NTRS)

Vogelmann, Andrew M.; McFarquhar, Greg M.; Ogren, John A.; Turner, David D.; Comstock, Jennifer M.; Feingold, Graham; Long, Charles N.; Jonsson, Haflidi H.; Bucholtz, Anthony; Collins, Don R.;

Storm clouds on Saturn: Lightning-induced chemistry and associated materials consistent with Cassini/VIMS spectra

USGS Publications Warehouse

Baines, K.H.; Delitsky, M.L.; Momary, T.W.; Brown, R.H.; Buratti, B.J.; Clark, R.N.; Nicholson, P.D.

2009-01-01

Thunderstorm activity on Saturn is associated with optically detectable clouds that are atypically dark throughout the near-infrared. As observed by Cassini/VIMS, these clouds are ~20% less reflective than typical neighboring clouds throughout the spectral range from 0.8 ??m to at least 4.1 ??m. We propose that active thunderstorms originating in the 10-20 bar water-condensation region vertically transport dark materials at depth to the ~1 bar level where they can be observed. These materials in part may be produced by chemical processes associated with lightning, likely within the water clouds near the ~10 bar freezing level of water, as detected by the electrostatic discharge of lightning flashes observed by Cassini/RPWS (e.g., Fischer et al. 2008, Space Sci. Rev., 137, 271-285). We review lightning-induced pyrolytic chemistry involving a variety of Saturnian constituents, including hydrogen, methane, ammonia, hydrogen sulfide, phosphine, and water. We find that the lack of absorption in the 1-2 ??m spectral region by lightning-generated sulfuric and phosphorous condensates renders these constituents as minor players in determining the color of the dark storm clouds. Relatively small particulates of elemental carbon, formed by lightning-induced dissociation of methane and subsequently upwelled from depth - perhaps embedded within and on the surface of spectrally bright condensates such as ammonium hydrosulfide or ammonia - may be a dominant optical material within the dark thunderstorm-related clouds of Saturn. ?? 2009 Elsevier Ltd. All rights reserved.

Jovian Lightning and Moonlit Clouds

NASA Technical Reports Server (NTRS)

1997-01-01

Jovian lightning and moonlit clouds. These two images, taken 75 minutes apart, show lightning storms on the night side of Jupiter along with clouds dimly lit by moonlight from Io, Jupiter's closest moon. The images were taken in visible light and are displayed in shades of red. The images used an exposure time of about one minute, and were taken when the spacecraft was on the opposite side of Jupiter from the Earth and Sun. Bright storms are present at two latitudes in the left image, and at three latitudes in the right image. Each storm was made visible by multiple lightning strikes during the exposure. Other Galileo images were deliberately scanned from east to west in order to separate individual flashes. The images show that Jovian and terrestrial lightning storms have similar flash rates, but that Jovian lightning strikes are a few orders of magnitude brighter in visible light.

The moonlight from Io allows the lightning storms to be correlated with visible cloud features. The latitude bands where the storms are seen seem to coincide with the 'disturbed regions' in daylight images, where short-lived chaotic motions push clouds to high altitudes, much like thunderstorms on Earth. The storms in these images are roughly one to two thousand kilometers across, while individual flashes appear hundreds of kilometer across. The lightning probably originates from the deep water cloud layer and illuminates a large region of the visible ammonia cloud layer from 100 kilometers below it.

There are several small light and dark patches that are artifacts of data compression. North is at the top of the picture. The images span approximately 50 degrees in latitude and longitude. The lower edges of the images are aligned with the equator. The images were taken on October 5th and 6th, 1997 at a range of 6.6 million kilometers by the Solid State Imaging (SSI) system on NASA's Galileo spacecraft.

The Jet Propulsion Laboratory, Pasadena, CA manages the Galileo mission for NASA's Office of Space Science, Washington, DC. JPL is an operating division of California Institute of Technology (Caltech).

This image and other images and data received from Galileo are posted on the World Wide Web, on the Galileo mission home page at URL http://galileo.jpl.nasa.gov.

Stormy Day at Jupiter

NASA Image and Video Library

2017-05-25

Small bright clouds dot Jupiter's entire south tropical zone in this image acquired by JunoCam on NASA's Juno spacecraft on May 19, 2017, at an altitude of 7,990 miles (12,858 kilometers). Although the bright clouds appear tiny in this vast Jovian cloudscape, they actually are cloud towers roughly 30 miles (50 kilometers) wide and 30 miles (50 kilometers) high that cast shadows on the clouds below. On Jupiter, clouds this high are almost certainly composed of water and/or ammonia ice, and they may be sources of lightning. This is the first time so many cloud towers have been visible, possibly because the late-afternoon lighting is particularly good at this geometry. https://photojournal.jpl.nasa.gov/catalog/PIA21647

Photo-EMF Sensitivity of Porous Silicon Thin Layer–Crystalline Silicon Heterojunction to Ammonia Adsorption

PubMed Central

Vashpanov, Yuriy; Jung, Jae Il; Kwack, Kae Dal

2011-01-01

A new method of using photo-electromotive force in detecting gas and controlling sensitivity is proposed. Photo-electromotive force on the heterojunction between porous silicon thin layer and crystalline silicon wafer depends on the concentration of ammonia in the measurement chamber. A porous silicon thin layer was formed by electrochemical etching on p-type silicon wafer. A gas and light transparent electrical contact was manufactured to this porous layer. Photo-EMF sensitivity corresponding to ammonia concentration in the range from 10 ppm to 1,000 ppm can be maximized by controlling the intensity of illumination light. PMID:22319353

On the Surface Formation of NH3 and HNCO in Dark Molecular Clouds - Searching for Wöhler Synthesis in the Interstellar Medium

NASA Astrophysics Data System (ADS)

Fedoseev, Gleb; Lamberts, Thanja; Linnartz, Harold; Ioppolo, Sergio; Zhao, Dongfeng

Despite its potential to reveal the link between the formation of simple species and more complex molecules (e.g., amino acids), the nitrogen chemistry of the interstellar medium (ISM) is still poorly understood. Ammonia (NH _{3}) is one of the few nitrogen-bearing species that have been observed in interstellar ices toward young stellar objects (YSOs) and quiescent molecular clouds. The aim of the present work is to experimentally investigate surface formation routes of NH _{3} and HNCO through non-energetic surface reactions in interstellar ice analogues under fully controlled laboratory conditions and at astrochemically relevant cryogenic temperatures. This study focuses on the formation of NH _{3} and HNCO in CO-rich (non-polar) interstellar ices that simulate the CO freeze-out stage in interstellar dark cloud regions, well before thermal and energetic processing start to become predominant. Our work confirms the surface formation of ammonia through the sequential addition of three hydrogen/deuterium atoms to a single nitrogen atom at low temperature. The H/D fractionation of the formed ammonia is also shown. Furthermore, we show the surface formation of solid HNCO through the interaction of CO molecules with NH radicals - one of the intermediates in the formation of solid NH _{3}. Finally, we discuss the implications of HNCO in astrobiology, as a possible starting point for the formation of more complex prebiotic species.

Validation of the Two-Layer Model for Correcting Clear Sky Reflectance Near Clouds

NASA Technical Reports Server (NTRS)

Wen, Guoyong; Marshak, Alexander; Evans, K. Frank; Vamal, Tamas

2014-01-01

A two-layer model was developed in our earlier studies to estimate the clear sky reflectance enhancement near clouds. This simple model accounts for the radiative interaction between boundary layer clouds and molecular layer above, the major contribution to the reflectance enhancement near clouds for short wavelengths. We use LES/SHDOM simulated 3D radiation fields to valid the two-layer model for reflectance enhancement at 0.47 micrometer. We find: (a) The simple model captures the viewing angle dependence of the reflectance enhancement near cloud, suggesting the physics of this model is correct; and (b) The magnitude of the 2-layer modeled enhancement agree reasonably well with the "truth" with some expected underestimation. We further extend our model to include cloud-surface interaction using the Poisson model for broken clouds. We found that including cloud-surface interaction improves the correction, though it can introduced some over corrections for large cloud albedo, large cloud optical depth, large cloud fraction, large cloud aspect ratio. This over correction can be reduced by excluding scenes (10 km x 10km) with large cloud fraction for which the Poisson model is not designed for. Further research is underway to account for the contribution of cloud-aerosol radiative interaction to the enhancement.

A 19-Month Climatology of Marine Aerosol-Cloud-Radiation Properties Derived From DOE ARM AMF Deployment at the Azores: Part I: Cloud Fraction and Single-Layered MBL Cloud Properties

NASA Technical Reports Server (NTRS)

Dong, Xiquan; Xi, Baike; Kennedy, Aaron; Minnis, Patrick; Wood, Robert

2013-01-01

A 19-month record of total, and single-layered low (0-3 km), middle (3-6 km), and high (> 6 km) cloud fractions (CFs), and the single-layered marine boundary layer (MBL) cloud macrophysical and microphysical properties has been generated from ground-based measurements taken at the ARM Azores site between June 2009 and December 2010. It documents the most comprehensive and longest dataset on marine cloud fraction and MBL cloud properties to date. The annual means of total CF, and single-layered low, middle, and high CFs derived from ARM radar-lidar observations are 0.702, 0.271, 0.01 and 0.106, respectively. More total and single-layered high CFs occurred during winter, while single-layered low CFs were greatest during summer. The diurnal cycles for both total and low CFs are stronger during summer than during winter. The CFs are bimodally distributed in the vertical with a lower peak at approx. 1 km and higher one between 8 and 11 km during all seasons, except summer, when only the low peak occurs. The persistent high pressure and dry conditions produce more single-layered MBL clouds and fewer total clouds during summer, while the low pressure and moist air masses during winter generate more total and multilayered-clouds, and deep frontal clouds associated with midlatitude cyclones.

The Effects of an Absorbing Smoke Layer on MODIS Marine Boundary Layer Cloud Optical Property Retrievals and Radiative Forcing

NASA Technical Reports Server (NTRS)

Meyer, Kerry; Platnick, Steven

2012-01-01

Clouds, aerosols, and their interactions are widely considered to be key uncertainty components in our current understanding of the Earth's atmosphere and radiation budget. The work presented here is focused on the quasi-permanent marine boundary layer . (MBL) clouds off the southern Atlantic coast of Africa and the effects on MODIS cloud optical property retrievals (MOD06) of an overlying absorbing smoke layer. During much of August and September, a persistent smoke layer resides over this region, produced from extensive biomass burning throughout the southern African savanna. The resulting absorption, which increases with decreasing wavelength, potentially introduces biases into the MODIS cloud optical property retrievals of the underlying MBL clouds. This effect is more pronounced in the cloud optical thickness retrievals, which over ocean are derived from the wavelength channel centered near 0.86 micron (effective particle size retrievals are derived from the longer-wavelength near-IR channels at 1.6, 2.1, and 3.7 microns). Here, the spatial distributions of the scalar statistics of both the cloud and aerosol layers are first determined from the CALIOP 5 km layer products. Next, the MOD06 look-up tables (LUTs) are adjusted by inserting an absorbing smoke layer of varying optical thickness over the cloud. Retrievals are subsequently performed for a subset of MODIS pixels collocated with the CALIOP ground track, using smoke optical thickness from the CALIOP 5km aerosol layer product to select the appropriate LUT. The resulting differences in cloud optical property retrievals due to the inclusion of the smoke layer in the LUTs will be examined. In addition, the direct radiative forcing of this smoke layer will be investigated from the perspective of the cloud optical property retrieval differences.

Determination of Ice Water Path in Ice-over-Water Cloud Systems Using Combined MODIS and AMSR-E Measurements

NASA Technical Reports Server (NTRS)

Huang, Jianping; Minnis, Patrick; Lin, Bing; Yi, Yuhong; Fan, T.-F.; Sun-Mack, Sunny; Ayers, J. K.

2006-01-01

To provide more accurate ice cloud properties for evaluating climate models, the updated version of multi-layered cloud retrieval system (MCRS) is used to retrieve ice water path (IWP) in ice-over-water cloud systems over global ocean using combined instrument data from the Aqua satellite. The liquid water path (LWP) of lower layer water clouds is estimated from the Advanced Microwave Scanning Radiometer for EOS (AMSR-E) measurements. With the lower layer LWP known, the properties of the upper-level ice clouds are then derived from Moderate Resolution Imaging Spectroradiometer measurements by matching simulated radiances from a two-cloud layer radiative transfer model. Comparisons with single-layer cirrus systems and surface-based radar retrievals show that the MCRS can significantly improve the accuracy and reduce the over-estimation of optical depth and ice water path retrievals for ice over-water cloud systems. During the period from December 2004 through February 2005, the mean daytime ice cloud optical depth and IWP for overlapped ice-over-water clouds over ocean from Aqua are 7.6 and 146.4 gm(sup -2), respectively, significantly less than the initial single layer retrievals of 17.3 and 322.3 gm(sup -2). The mean IWP for actual single-layer clouds was 128.2 gm(sup -2).

KSC-01PP1471

NASA Image and Video Library

2001-08-10

KENNEDY SPACE CENTER, Fla. -- Clouds of smoke and steam roll across the ground as Space Shuttle Discovery hurtles into the blue sky against a backdrop of cumulus clouds. Liftoff from Launch Pad 39A occurred at 5:10:14 p.m. EDT. Besides the Shuttle crew of four, Discovery carries the Expedition Three crew who will replace Expedition Two on the Space Station. The mission payload includes the third flight of the Italian-built Multi-Purpose Logistics Module Leonardo, delivering additional scientific racks, equipment and supplies for the Space Station, and the Early Ammonia Servicer (EAS) tank. The EAS, which will be attached to the Station during two spacewalks, contains spare ammonia for the Station’s cooling system. The three-member Expedition Two crew will be returning to Earth aboard Discovery after a five-month stay on the Station

Planar waveguide sensor of ammonia

NASA Astrophysics Data System (ADS)

Rogoziński, Roman; Tyszkiewicz, Cuma; Karasiński, Paweł; Izydorczyk, Weronika

2015-12-01

The paper presents the concept of forming ammonia sensor based on a planar waveguide structure. It is an amplitude sensor produced on the basis of the multimode waveguide. The technological base for this kind of structure is the ion exchange method and the sol-gel method. The planar multimode waveguide of channel type is produced in glass substrate (soda-lime glass of Menzel-Glaser company) by the selective Ag+↔Na+ ion exchange. On the surface of the glass substrate a porous (~40%) silica layer is produced by the sol-gel method. This layer is sensitized to the presence of ammonia in the surrounding atmosphere by impregnation with Bromocresol Purple (BCP) dye. Therefore it constitutes a sensor layer. Spectrophotometric tests carried out showed about 50% reduction of cross-transmission changes of such sensor layer for a wave λ=593 nm caused by the presence of 25% ammonia water vapor in its ambience. The radiation source used in this type of sensor structure is a light emitting diode LED. The gradient channel waveguide is designed for frontal connection (optical glue) with a standard multimode telecommunications waveguide 62.5/125μm.

Assessment of physical server reliability in multi cloud computing system

NASA Astrophysics Data System (ADS)

Kalyani, B. J. D.; Rao, Kolasani Ramchand H.

2018-04-01

Business organizations nowadays functioning with more than one cloud provider. By spreading cloud deployment across multiple service providers, it creates space for competitive prices that minimize the burden on enterprises spending budget. To assess the software reliability of multi cloud application layered software reliability assessment paradigm is considered with three levels of abstractions application layer, virtualization layer, and server layer. The reliability of each layer is assessed separately and is combined to get the reliability of multi-cloud computing application. In this paper, we focused on how to assess the reliability of server layer with required algorithms and explore the steps in the assessment of server reliability.

Clouds and Hazes in Saturn's Troposphere and Stratosphere

NASA Astrophysics Data System (ADS)

Merlet, Cecile; Irwin, P.; Fletcher, L.

2012-10-01

We present new results from the analysis of Saturn's near-infrared spectra measured with the Visual and Infrared Mapping Spectrometer (VIMS) instrument on the Cassini orbiter. VIMS near-infrared data are particularly relevant for the study of clouds and hazes in the troposphere and stratosphere of Saturn. Thermal emission in the 4.5-5.1 wavelength range is absorbed and scattered mainly by tropospheric clouds and radiatively active gases. The vertical structure as well as the optical and physical properties of tropospheric aerosols are obtained from Saturn's thermal emission spectra by using the retrieval algorithm Nemesis. The distribution of tropospheric phosphine and ammonia in gas phase will also be presented here. We managed to break the degeneracies inherent to the retrieval problem by analysing Saturn's thermal emission simultaneously at various viewing geometries. By using this method, we found that VIMS spectra at 4.5-5.1 microns are also sensitive to the hazes formed above the cloud layers. Saturn's reflected sunlight spectra at 0.8-3.5 microns measured with VIMS were also analysed in order to constrain the haze properties in the upper troposphere and lower stratosphere of the planet. Results from both the 0.8-3.5 and 4.5-5.1 wavelength ranges were combined to determine the cloud and haze model most consistent with VIMS spectroscopy over a wide range of viewing geometries and lighting conditions. An increase of temperature below the tropopause, often referred to as the temperature knee, was retrieved from Cassini/CIRS spectra. Seasonal variations of the knee and haze structure are compared, and as a result the assumption of local heating by the hazes to explain this feature will be discussed.

Boundary-layer cumulus over heterogeneous landscapes: A subgrid GCM parameterization. Final report, December 1991--November 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stull, R.B.; Tripoli, G.

1996-01-08

The authors developed single-column parameterizations for subgrid boundary-layer cumulus clouds. These give cloud onset time, cloud coverage, and ensemble distributions of cloud-base altitudes, cloud-top altitudes, cloud thickness, and the characteristics of cloudy and clear updrafts. They tested and refined the parameterizations against archived data from Spring and Summer 1994 and 1995 intensive operation periods (IOPs) at the Southern Great Plains (SGP) ARM CART site near Lamont, Oklahoma. The authors also found that: cloud-base altitudes are not uniform over a heterogeneous surface; tops of some cumulus clouds can be below the base-altitudes of other cumulus clouds; there is an overlap regionmore » near cloud base where clear and cloudy updrafts exist simultaneously; and the lognormal distribution of cloud sizes scales to the JFD of surface layer air and to the shape of the temperature profile above the boundary layer.« less

Detection of Multi-Layer and Vertically-Extended Clouds Using A-Train Sensors

NASA Technical Reports Server (NTRS)

Joiner, J.; Vasilkov, A. P.; Bhartia, P. K.; Wind, G.; Platnick, S.; Menzel, W. P.

2010-01-01

The detection of mUltiple cloud layers using satellite observations is important for retrieval algorithms as well as climate applications. In this paper, we describe a relatively simple algorithm to detect multiple cloud layers and distinguish them from vertically-extended clouds. The algorithm can be applied to coincident passive sensors that derive both cloud-top pressure from the thermal infrared observations and an estimate of solar photon pathlength from UV, visible, or near-IR measurements. Here, we use data from the A-train afternoon constellation of satellites: cloud-top pressure, cloud optical thickness, the multi-layer flag from the Aqua MODerate-resolution Imaging Spectroradiometer (MODIS) and the optical centroid cloud pressure from the Aura Ozone Monitoring Instrument (OMI). For the first time, we use data from the CloudSat radar to evaluate the results of a multi-layer cloud detection scheme. The cloud classification algorithms applied with different passive sensor configurations compare well with each other as well as with data from CloudSat. We compute monthly mean fractions of pixels containing multi-layer and vertically-extended clouds for January and July 2007 at the OMI spatial resolution (l2kmx24km at nadir) and at the 5kmx5km MODIS resolution used for infrared cloud retrievals. There are seasonal variations in the spatial distribution of the different cloud types. The fraction of cloudy pixels containing distinct multi-layer cloud is a strong function of the pixel size. Globally averaged, these fractions are approximately 20% and 10% for OMI and MODIS, respectively. These fractions may be significantly higher or lower depending upon location. There is a much smaller resolution dependence for fractions of pixels containing vertically-extended clouds (approx.20% for OMI and slightly less for MODIS globally), suggesting larger spatial scales for these clouds. We also find higher fractions of vertically-extended clouds over land as compared with ocean, particularly in the tropics and summer hemisphere.

Determination of ice water path in ice-over-water cloud systems using combined MODIS and AMSR-E measurements

NASA Astrophysics Data System (ADS)

Huang, Jianping; Minnis, Patrick; Lin, Bing; Yi, Yuhong; Fan, T.-F.; Sun-Mack, Sunny; Ayers, J. K.

2006-11-01

To provide more accurate ice cloud microphysical properties, the multi-layered cloud retrieval system (MCRS) is used to retrieve ice water path (IWP) in ice-over-water cloud systems globally over oceans using combined instrument data from Aqua. The liquid water path (LWP) of lower-layer water clouds is estimated from the Advanced Microwave Scanning Radiometer for EOS (AMSR-E) measurements. The properties of the upper-level ice clouds are then derived from Moderate Resolution Imaging Spectroradiometer (MODIS) measurements by matching simulated radiances from a two-cloud-layer radiative transfer model. The results show that the MCRS can significantly improve the accuracy and reduce the over-estimation of optical depth and IWP retrievals for ice-over-water cloud systems. The mean daytime ice cloud optical depth and IWP for overlapped ice-over-water clouds over oceans from Aqua are 7.6 and 146.4 gm-2, respectively, down from the initial single-layer retrievals of 17.3 and 322.3 gm-2. The mean IWP for actual single-layer clouds is 128.2 gm-2.

Cloud and boundary layer interactions over the Arctic sea-ice in late summer

NASA Astrophysics Data System (ADS)

Shupe, M. D.; Persson, P. O. G.; Brooks, I. M.; Tjernström, M.; Sedlar, J.; Mauritsen, T.; Sjogren, S.; Leck, C.

2013-05-01

Observations from the Arctic Summer Cloud Ocean Study (ASCOS), in the central Arctic sea-ice pack in late summer 2008, provide a detailed view of cloud-atmosphere-surface interactions and vertical mixing processes over the sea-ice environment. Measurements from a suite of ground-based remote sensors, near surface meteorological and aerosol instruments, and profiles from radiosondes and a helicopter are combined to characterize a week-long period dominated by low-level, mixed-phase, stratocumulus clouds. Detailed case studies and statistical analyses are used to develop a conceptual model for the cloud and atmosphere structure and their interactions in this environment. Clouds were persistent during the period of study, having qualities that suggest they were sustained through a combination of advective influences and in-cloud processes, with little contribution from the surface. Radiative cooling near cloud top produced buoyancy-driven, turbulent eddies that contributed to cloud formation and created a cloud-driven mixed layer. The depth of this mixed layer was related to the amount of turbulence and condensed cloud water. Coupling of this cloud-driven mixed layer to the surface boundary layer was primarily determined by proximity. For 75% of the period of study, the primary stratocumulus cloud-driven mixed layer was decoupled from the surface and typically at a warmer potential temperature. Since the near-surface temperature was constrained by the ocean-ice mixture, warm temperatures aloft suggest that these air masses had not significantly interacted with the sea-ice surface. Instead, back trajectory analyses suggest that these warm airmasses advected into the central Arctic Basin from lower latitudes. Moisture and aerosol particles likely accompanied these airmasses, providing necessary support for cloud formation. On the occasions when cloud-surface coupling did occur, back trajectories indicated that these air masses advected at low levels, while mixing processes kept the mixed layer in equilibrium with the near-surface environment. Rather than contributing buoyancy forcing for the mixed-layer dynamics, the surface instead simply appeared to respond to the mixed-layer processes aloft. Clouds in these cases often contained slightly higher condensed water amounts, potentially due to additional moisture sources from below.

Cloud and boundary layer interactions over the Arctic sea ice in late summer

NASA Astrophysics Data System (ADS)

Shupe, M. D.; Persson, P. O. G.; Brooks, I. M.; Tjernström, M.; Sedlar, J.; Mauritsen, T.; Sjogren, S.; Leck, C.

2013-09-01

Observations from the Arctic Summer Cloud Ocean Study (ASCOS), in the central Arctic sea-ice pack in late summer 2008, provide a detailed view of cloud-atmosphere-surface interactions and vertical mixing processes over the sea-ice environment. Measurements from a suite of ground-based remote sensors, near-surface meteorological and aerosol instruments, and profiles from radiosondes and a helicopter are combined to characterize a week-long period dominated by low-level, mixed-phase, stratocumulus clouds. Detailed case studies and statistical analyses are used to develop a conceptual model for the cloud and atmosphere structure and their interactions in this environment. Clouds were persistent during the period of study, having qualities that suggest they were sustained through a combination of advective influences and in-cloud processes, with little contribution from the surface. Radiative cooling near cloud top produced buoyancy-driven, turbulent eddies that contributed to cloud formation and created a cloud-driven mixed layer. The depth of this mixed layer was related to the amount of turbulence and condensed cloud water. Coupling of this cloud-driven mixed layer to the surface boundary layer was primarily determined by proximity. For 75% of the period of study, the primary stratocumulus cloud-driven mixed layer was decoupled from the surface and typically at a warmer potential temperature. Since the near-surface temperature was constrained by the ocean-ice mixture, warm temperatures aloft suggest that these air masses had not significantly interacted with the sea-ice surface. Instead, back-trajectory analyses suggest that these warm air masses advected into the central Arctic Basin from lower latitudes. Moisture and aerosol particles likely accompanied these air masses, providing necessary support for cloud formation. On the occasions when cloud-surface coupling did occur, back trajectories indicated that these air masses advected at low levels, while mixing processes kept the mixed layer in equilibrium with the near-surface environment. Rather than contributing buoyancy forcing for the mixed-layer dynamics, the surface instead simply appeared to respond to the mixed-layer processes aloft. Clouds in these cases often contained slightly higher condensed water amounts, potentially due to additional moisture sources from below.

Differential distribution patterns of ammonia-oxidizing archaea and bacteria in acidic soils of Nanling National Nature Reserve forests in subtropical China.

PubMed

Gan, Xian-Hua; Zhang, Fang-Qiu; Gu, Ji-Dong; Guo, Yue-Dong; Li, Zhao-Qing; Zhang, Wei-Qiang; Xu, Xiu-Yu; Zhou, Yi; Wen, Xiao-Ying; Xie, Guo-Guang; Wang, Yong-Feng

2016-02-01

In addition to ammonia-oxidizing bacteria (AOB) the more recently discovered ammonia-oxidizing archaea (AOA) can also oxidize ammonia, but little is known about AOA community structure and abundance in subtropical forest soils. In this study, both AOA and AOB were investigated with molecular techniques in eight types of forests at surface soils (0-2 cm) and deep layers (18-20 cm) in Nanling National Nature Reserve in subtropical China. The results showed that the forest soils, all acidic (pH 4.24-5.10), harbored a wide range of AOA phylotypes, including the genera Nitrosotalea, Nitrososphaera, and another 6 clusters, one of which was reported for the first time. For AOB, only members of Nitrosospira were retrieved. Moreover, the abundance of the ammonia monooxygenase gene (amoA) from AOA dominated over AOB in most soil samples (13/16). Soil depth, rather than forest type, was an important factor shaping the community structure of AOA and AOB. The distribution patterns of AOA and AOB in soil layers were reversed: AOA diversity and abundances in the deep layers were higher than those in the surface layers; on the contrary, AOB diversity and abundances in the deep layers were lower than those in the surface layers. Interestingly, the diversity of AOA was positively correlated with pH, but negatively correlated with organic carbon, total nitrogen and total phosphorus, and the abundance of AOA was negatively correlated with available phosphorus. Our results demonstrated that AOA and AOB were differentially distributed in acidic soils in subtropical forests and affected differently by soil characteristics.

An experimental investigation of the angular scattering and backscattering behaviors of the simulated clouds of the outer planets

NASA Technical Reports Server (NTRS)

Sassen, K.

1984-01-01

A cryogenic, 50 liter volume Planetary Cloud Simulation Chamber has been constructed to permit the laboratory study of the cloud compositions which are likely to be found in the atmospheres of the outer planets. On the basis of available data, clouds composed of water ice, carbon dioxide, and liquid and solid ammonia and methane, both pure and in various mixtures, have been generated. Cloud microphysical observations have been permitted through the use of a cloud particle slide injector and photomicrography. Viewports in the lower chamber have enabled the collection of cloud backscattering data using 633 and 838 nm laser light, including linear depolarization ratios and complete Stokes parameterization. The considerable technological difficulties associated with the collection of angular scattering patterns within the chamber, however, could not be completely overcome.

Cloud condensation nuclei near marine cumulus

NASA Technical Reports Server (NTRS)

Hudson, James G.

1993-01-01

Extensive airborne measurements of cloud condensation nucleus (CCN) spectra and condensation nuclei below, in, between, and above the cumulus clouds near Hawaii point to important aerosol-cloud interactions. Consistent particle concentrations of 200/cu cm were found above the marine boundary layer and within the noncloudy marine boundary layer. Lower and more variable CCN concentrations within the cloudy boundary layer, especially very close to the clouds, appear to be a result of cloud scavenging processes. Gravitational coagulation of cloud droplets may be the principal cause of this difference in the vertical distribution of CCN. The results suggest a reservoir of CCN in the free troposphere which can act as a source for the marine boundary layer.

Cloud retrievals from satellite data using optimal estimation: evaluation and application to ATSR

NASA Astrophysics Data System (ADS)

Poulsen, C. A.; Siddans, R.; Thomas, G. E.; Sayer, A. M.; Grainger, R. G.; Campmany, E.; Dean, S. M.; Arnold, C.; Watts, P. D.

2012-08-01

Clouds play an important role in balancing the Earth's radiation budget. Hence, it is vital that cloud climatologies are produced that quantify cloud macro and micro physical parameters and the associated uncertainty. In this paper, we present an algorithm ORAC (Oxford-RAL retrieval of Aerosol and Cloud) which is based on fitting a physically consistent cloud model to satellite observations simultaneously from the visible to the mid-infrared, thereby ensuring that the resulting cloud properties provide both a good representation of the short-wave and long-wave radiative effects of the observed cloud. The advantages of the optimal estimation method are that it enables rigorous error propagation and the inclusion of all measurements and any a priori information and associated errors in a rigorous mathematical framework. The algorithm provides a measure of the consistency between retrieval representation of cloud and satellite radiances. The cloud parameters retrieved are the cloud top pressure, cloud optical depth, cloud effective radius, cloud fraction and cloud phase. The algorithm can be applied to most visible/infrared satellite instruments. In this paper, we demonstrate the applicability to the Along-Track Scanning Radiometers ATSR-2 and AATSR. Examples of applying the algorithm to ATSR-2 flight data are presented and the sensitivity of the retrievals assessed, in particular the algorithm is evaluated for a number of simulated single-layer and multi-layer conditions. The algorithm was found to perform well for single-layer cloud except when the cloud was very thin; i.e., less than 1 optical depths. For the multi-layer cloud, the algorithm was robust except when the upper ice cloud layer is less than five optical depths. In these cases the retrieved cloud top pressure and cloud effective radius become a weighted average of the 2 layers. The sum of optical depth of multi-layer cloud is retrieved well until the cloud becomes thick, greater than 50 optical depths, where the cloud begins to saturate. The cost proved a good indicator of multi-layer scenarios. Both the retrieval cost and the error need to be considered together in order to evaluate the quality of the retrieval. This algorithm in the configuration described here has been applied to both ATSR-2 and AATSR visible and infrared measurements in the context of the GRAPE (Global Retrieval and cloud Product Evaluation) project to produce a 14 yr consistent record for climate research.

Cirrus Cloud Retrieval Using Infrared Sounding Data: Multilevel Cloud Errors.

NASA Astrophysics Data System (ADS)

Baum, Bryan A.; Wielicki, Bruce A.

1994-01-01

In this study we perform an error analysis for cloud-top pressure retrieval using the High-Resolution Infrared Radiometric Sounder (HIRS/2) 15-µm CO2 channels for the two-layer case of transmissive cirrus overlying an overcast, opaque stratiform cloud. This analysis includes standard deviation and bias error due to instrument noise and the presence of two cloud layers, the lower of which is opaque. Instantaneous cloud pressure retrieval errors are determined for a range of cloud amounts (0.1 1.0) and cloud-top pressures (850250 mb). Large cloud-top pressure retrieval errors are found to occur when a lower opaque layer is present underneath an upper transmissive cloud layer in the satellite field of view (FOV). Errors tend to increase with decreasing upper-cloud elective cloud amount and with decreasing cloud height (increasing pressure). Errors in retrieved upper-cloud pressure result in corresponding errors in derived effective cloud amount. For the case in which a HIRS FOV has two distinct cloud layers, the difference between the retrieved and actual cloud-top pressure is positive in all casts, meaning that the retrieved upper-cloud height is lower than the actual upper-cloud height. In addition, errors in retrieved cloud pressure are found to depend upon the lapse rate between the low-level cloud top and the surface. We examined which sounder channel combinations would minimize the total errors in derived cirrus cloud height caused by instrument noise and by the presence of a lower-level cloud. We find that while the sounding channels that peak between 700 and 1000 mb minimize random errors, the sounding channels that peak at 300—500 mb minimize bias errors. For a cloud climatology, the bias errors are most critical.

Roles of drizzle in a one-dimensional third-order turbulence closure model of the nocturnal stratus-topped marine boundary layer

NASA Technical Reports Server (NTRS)

Wang, Shouping; Wang, Qing

1994-01-01

This study focuses on the effects of drizzle in a one-dimensional third-order turbulence closure model of the nocturnal stratus-topped marine boundary layer. When the simulated drizzle rate is relatively small (maximum approximately equal to 0.6 mm/day), steady-state solutions are obtained. The boundary layer stabilizes essentially because drizzle causes evaporative cooling of the subcloud layer. This stabilization considerably reduces the buoyancy flux and turbulence kinetic energy below the stratus cloud. Thus, drizzle tends to decouple the cloud from the subcloud layer in the model, as suggested by many observational studies. In addition, the evaporation of drizzle in the subcloud layer creates small scattered clouds, which are likely to represent cumulus clouds, below the solid stratus cloud in the model. The sensitivity experiments show that these scattered clouds help maintain a coupled boundary layer. When the drizzle rate is relatively large (maximum approximately equal to 0.9 mm/day), the response of the model becomes transient with bursts in turbulent fluxes. This phenomenon is related to the formation of the scattered cloud layer below the solid stratus cloud. It appears that the model is inadequate to represent the heat and moisture transport by strong updrafts covering a small fractional area in cumulus convection.

Cloud Detection Using Measured and Modeled State Parameters

NASA Technical Reports Server (NTRS)

Yi, Y.; Minnis, P.; Huang, J.; Ayers, J. K.; Doelling, D. R.; Khaiyer, M. M.; Nordeen, M. L.

2004-01-01

In this study, hourly RUC analyses were used to examine the differences between RH and temperature values from RUC reanalysis data and from radiosonde atmospheric profiles obtained at the ARM SCF. The results show that the temperature observations from the SONDE and RUC are highly correlated. The RHs are also well-correlated, but the SONDE values generally exceed those from RUC. Inside cloud layers, the RH from RUC is 2-14% lower than the RH from SONDE for all RUC layers. Although the layer mean RH within clouds is much greater than the layer mean RH outside cloud or in the clear-sky, RH thresholds chosen as a function of temperature can more accurately diagnose cloud occurrence for either dataset. For overcast clouds, it was found that the 50% probability RH threshold for diagnosing a cloud, within a given upper tropospheric layer is roughly 90% for the Vaisala RS80-15LH radisonde and 80% for RUC data. While for the partial cloud (cloud amount is less than 90%), the RH thresholds of SONDE are close to RUC for a given probability in upper tropospheric layers. The probabilities of detecting clouds at a given RH and temperature should be useful for a variety of application such as the development of new cloud parameterizations or for estimating the vertical profile of cloudiness underneath a given cloud observed from the satellite to construct a 3-D cloud data set for computing atmospheric radiative heating profiles or determining potential aircraft icing conditions.

Height Distribution Between Cloud and Aerosol Layers from the GLAS Spaceborne Lidar in the Indian Ocean Region

NASA Technical Reports Server (NTRS)

Hart, William D.; Spinhirne, James D.; Palm, Steven P.; Hlavka, Dennis L.

2005-01-01

The Geoscience Laser Altimeter System (GLAS), a nadir pointing lidar on the Ice Cloud and land Elevation Satellite (ICESat) launched in 2003, now provides important new global measurements of the relationship between the height distribution of cloud and aerosol layers. GLAS data have the capability to detect, locate, and distinguish between cloud and aerosol layers in the atmosphere up to 40 km altitude. The data product algorithm tests the product of the maximum attenuated backscatter coefficient b'(r) and the vertical gradient of b'(r) within a layer against a predetermined threshold. An initial case result for the critical Indian Ocean region is presented. From the results the relative height distribution between collocated aerosol and cloud shows extensive regions where cloud formation is well within dense aerosol scattering layers at the surface. Citation: Hart, W. D., J. D. Spinhime, S. P. Palm, and D. L. Hlavka (2005), Height distribution between cloud and aerosol layers from the GLAS spaceborne lidar in the Indian Ocean region,

NIMS Spectral Maps of Jupiter's Great Red Spot

NASA Technical Reports Server (NTRS)

1996-01-01

The Near-Infrared Mapping Spectrometer (NIMS) instrument looks at Jupiter's Great Red Spot, in these views from June 26, 1996. NIMS studies infrared wavelengths of light that our eye cannot see. These maps are at four different infrared wavelengths, each one picked to reveal something different about the atmosphere.

The top image is a false color map of a wavelength that is at the red edge of our ability to see. It shows the shapes of features that we would see with our eyes.

The second map is of ammonia ice, red showing where the most ice is, blue where none exists. The differences between this and the first image are due to the amount and size of ammonia ice crystals.

The third map down is from a wavelength that shows cloud heights, with the highest clouds in red, and the lowest in blue.

The bottom map uses a wavelength that shows the hot Jupiter shining through the clouds. Red represents the thinnest clouds, and blue is thickest where it is more difficult to see below. Comparing the bottom two images, note that the highest clouds are in the center of the Great Red Spot, while there are relatively few clouds around the edges.

The Jet Propulsion Laboratory, Pasadena, CA manages the mission for NASA's Office of Space Science, Washington, DC.

This image and other images and data received from Galileo are posted on the World Wide Web, on the Galileo mission home page at URL http://galileo.jpl.nasa.gov.

NIMS Observes the Structure and Composition of Jupiter Clouds

NASA Image and Video Library

1998-03-26

With the NIMS instrument high quality observations are being obtained from all parts of Jupiter. The images in the upper panel are taken at a wavelength of 4.8 microns. At this wavelength thermal radiation from about 100 km deep below the visible cloud deck is escaping, allowing us to study the deep atmospheric region. The overlying cloud deck absorbs a part of the radiation, but there are places where it is thin and more radiation can escape. These are called hot spot regions. Many hotspots regions occur in a zone between the equator and 15 degrees north latitude, the North Equatorial Belt (NEB), but thermal radiation is seen from much of the planet. The uniqueness of NIMS is that it is capable of observing the same spatial region at a maximum of 408 different wavelengths between 0.7 and 5.2 micron simultaneously. Every picture element (pixel) contains a spectrum of up to 408 wavelengths. The gases that compose the atmosphere leave there traces in the spectra. In this particular case, 48 wavelengths were available between 4.6 and 5.2 micron, and we see spectral signatures of water, ammonia, and phosphine. Also, the total amount of radiation is determined by the amount of overlying cloud, characterized by the cloud opacity. By means of model calculations, we can determine the amount of water and the cloud opacity for each individual spectrum. The amount ammonia and phosphine is more difficult to obtain because its influence on the spectra is weaker. The results of these calculations are shown in the form of maps in the next two panels. With NIMS, we can now have a detailed look at the spatial distribution of the water and ammonia amounts and the cloud opacity in the atmosphere. Not all the pixels from the observations have good spectra, so for some data points no reliable determination of the water and cloud opacity could be made. We find that the atmosphere is extremely dry in, and close to, the hot spot, with relative humidities between 0.02 % and 10 %, with the dryest places being inside the hot spot. This corroborates the in-situ Galileo Entry Probe measurements. The Probe entered the atmosphere, on December 5 1995, in a hot spot region. Whereas the Probe obtained only a very localized snapshot, with NIMS we can do observations of larger areas and over longer periods. The spatial distribution of water is more complex than expected. More detailed investigations will be necessary to fully understand these results. http://photojournal.jpl.nasa.gov/catalog/PIA01224

Global Single and Multiple Cloud Classification with a Fuzzy Logic Expert System

NASA Technical Reports Server (NTRS)

Welch, Ronald M.; Tovinkere, Vasanth; Titlow, James; Baum, Bryan A.

1996-01-01

An unresolved problem in remote sensing concerns the analysis of satellite imagery containing both single and multiple cloud layers. While cloud parameterizations are very important both in global climate models and in studies of the Earth's radiation budget, most cloud retrieval schemes, such as the bispectral method used by the International Satellite Cloud Climatology Project (ISCCP), have no way of determining whether overlapping cloud layers exist in any group of satellite pixels. Coakley (1983) used a spatial coherence method to determine whether a region contained more than one cloud layer. Baum et al. (1995) developed a scheme for detection and analysis of daytime multiple cloud layers using merged AVHRR (Advanced Very High Resolution Radiometer) and HIRS (High-resolution Infrared Radiometer Sounder) data collected during the First ISCCP Regional Experiment (FIRE) Cirrus 2 field campaign. Baum et al. (1995) explored the use of a cloud classification technique based on AVHRR data. This study examines the feasibility of applying the cloud classifier to global satellite imagery.

Continuing Studies of Planetary Atmospheres Associated with Experiments on the Galileo Jupiter Probe and Infrared Observations of Venus

NASA Technical Reports Server (NTRS)

Ragent, Boris

1998-01-01

The results of the nephelometer experiment conducted aboard the Probe of the Galileo mission to Jupiter are presented. The tenuous clouds and sparse particulate matter in the relatively particle-free 5-micron "hot spot" region of the Probe's descent were documented from about 0.46 bars to about 12 bars. Three regions of apparent coherent structure were noted, in addition to many indications of extremely small particle concentrations along the descent path. From the first valid measurement at about 0.46 bars down to about 0.55 bars a feeble decaying lower portion of a cloud, corresponding with the predicted ammonia particle cloud, was encountered. A denser, but still very modest, particle structure was present in the pressure regime extending from about 0.76 to a distinctive base at 1.34 bars, and is compatible with the expected ammonium hydrosulfide cloud. No massive water cloud was encountered, although below the second structure, a small, vertically thin layer at about 1.65 bars may be detached from the cloud above, but may also be water condensation, compatible with reported measurements of water abundance from other Galileo Mission experiments. A third small signal region, extending from about 1.9 to 4.5 bars, exhibited quite weak but still distinctive structure, and, although the identification of the light scatterers in this region is uncertain, may also be a water cloud perhaps associated with lateral atmospheric motion and/or reduced to a small mass density by atmospheric subsidence or other explanations. Rough descriptions of the particle size distributions and cloud properties in these regions have been derived, although they may be imprecise because of the small signals and experimental difficulties. These descriptions document the small number densities of particles, the moderate particle sizes, generally in the slightly submicron to few micron range, and the resulting small optical depths, mass densities due to particles, column particle number loading and column mass loading in the atmosphere encountered by the Galileo Probe during its descent.

Continuing Studies of Planetary Atmospheres Associated With Experiments on the Galileo Jupiter Probe and Infrared Observations of Venus

NASA Technical Reports Server (NTRS)

Goodman,Jindra; Ragent, Boris

1998-01-01

The results of the nephelometer experiment conducted aboard the Probe of the Galileo mission to Jupiter are presented. The tenuous clouds and sparse particulate matter in the relatively particle-free 5-micron "hot spot" region of the Probe's descent were documented from about 0.46 bars to about 12 bars. Three regions of apparent coherent structure were noted, in addition to many indications of extremely small particle concentrations along the descent path. From the first valid measurement at about 0.46 bars down to about 0.55 bars a feeble decaying lower portion of a cloud, corresponding with the predicted ammonia particle cloud, was encountered. A denser, but still very modest, particle structure was present in the pressure regime extending from about 0.76 to a distinctive base at 1.34 bars, and is compatible with the expected ammonium hydrosulfide cloud. No massive water cloud was encountered, although below the second structure, a small, vertically thin layer at about 1.65 bars may be detached from the cloud above, but may also be water condensation, compatible with reported measurements of water abundance from other Galileo Mission experiments. A third small signal region, extending from about 1.9 to 4.5 bars, exhibited quite weak but still distinctive structure, and, although the identification of the light scatterers in this region is uncertain, may also be a water cloud perhaps associated with lateral atmospheric motion and/or reduced to a small mass density by atmospheric subsidence or other explanations. Rough descriptions of the particle size distributions and cloud properties in these regions have been derived, although they may be imprecise because of the small signals and experimental difficulties. These descriptions document the small number densities of particles, the moderate particle sizes, generally in the slightly submicron to few micron range, and the resulting small optical depths, mass densities due to particles, column particle number loading and column mass loading in the atmosphere encountered by the Galileo Probe during its descent.

Multi-Layer Arctic Mixed-Phase Clouds Simulated by a Cloud-Resolving Model: Comparison with ARM Observations and Sensitivity Experiments

NASA Technical Reports Server (NTRS)

Luo, Yali; Xu, Kuan-Man; Morrison, Hugh; McFarquhar, Greg M.; Wang, Zhien; Zhang, Gong

2007-01-01

A cloud-resolving model (CRM) is used to simulate the multiple-layer mixed-phase stratiform (MPS) clouds that occurred during a three-and-a-half day subperiod of the Department of Energy-Atmospheric Radiation Measurement Program s Mixed-Phase Arctic Cloud Experiment (M-PACE). The CRM is implemented with an advanced two-moment microphysics scheme, a state-of-the-art radiative transfer scheme, and a complicated third-order turbulence closure. Concurrent meteorological, aerosol, and ice nucleus measurements are used to initialize the CRM. The CRM is prescribed by time-varying large-scale advective tendencies of temperature and moisture and surface turbulent fluxes of sensible and latent heat. The CRM reproduces the occurrences of the single- and double-layer MPS clouds as revealed by the M-PACE observations. However, the simulated first cloud layer is lower and the second cloud layer thicker compared to observations. The magnitude of the simulated liquid water path agrees with that observed, but its temporal variation is more pronounced than that observed. As in an earlier study of single-layer cloud, the CRM also captures the major characteristics in the vertical distributions and temporal variations of liquid water content (LWC), total ice water content (IWC), droplet number concentration and ice crystal number concentration (nis) as suggested by the aircraft observations. However, the simulated mean values differ significantly from the observed. The magnitude of nis is especially underestimated by one order of magnitude. Sensitivity experiments suggest that the lower cloud layer is closely related to the surface fluxes of sensible and latent heat; the upper cloud layer is probably initialized by the large-scale advective cooling/moistening and maintained through the strong longwave (LW) radiative cooling near the cloud top which enhances the dynamical circulation; artificially turning off all ice-phase microphysical processes results in an increase in LWP by a factor of 3 due to interactions between the excessive LW radiative cooling and extra cloud water; heating caused by phase change of hydrometeors could affect the LWC and cloud top height by partially canceling out the LW radiative cooling. It is further shown that the resolved dynamical circulation appears to contribute more greatly to the evolution of the MPS cloud layers than the parameterized subgrid-scale circulation.

Temperature structure and kinematics of the IRDC G035.39-00.33

NASA Astrophysics Data System (ADS)

Sokolov, Vlas; Wang, Ke; Pineda, Jaime E.; Caselli, Paola; Henshaw, Jonathan D.; Tan, Jonathan C.; Fontani, Francesco; Jiménez-Serra, Izaskun; Lim, Wanggi

2017-10-01

Aims: Infrared dark clouds represent the earliest stages of high-mass star formation. Detailed observations of their physical conditions on all physical scales are required to improve our understanding of their role in fueling star formation. Methods: We investigate the large-scale structure of the IRDC G035.39-00.33, probing the dense gas with the classical ammonia thermometer. This allows us to put reliable constraints on the temperature of the extended, pc-scale dense gas reservoir and to probe the magnitude of its non-thermal motions. Available far-infrared observations can be used in tandem with the observed ammonia emission to estimate the total gas mass contained in G035.39-00.33. Results: We identify a main velocity component as a prominent filament, manifested as an ammonia emission intensity ridge spanning more than 6 pc, consistent with the previous studies on the Northern part of the cloud. A number of additional line-of-sight components are found, and a large-scale linear velocity gradient of 0.2km s-1 pc-1 is found along the ridge of the IRDC. In contrast to the dust temperature map, an ammonia-derived kinetic temperature map, presented for the entirety of the cloud, reveals local temperature enhancements towards the massive protostellar cores. We show that without properly accounting for the line of sight contamination, the dust temperature is 2-3 K larger than the gas temperature measured with NH3. Conclusions: While both the large-scale kinematics and temperature structure are consistent with that of starless dark filaments, the kinetic gas temperature profile on smaller scales is suggestive of tracing the heating mechanism coincident with the locations of massive protostellar cores. The reduced spectral cubes (FITS format) are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/606/A133

Initial studies of middle and upper tropospheric stratiform clouds

NASA Technical Reports Server (NTRS)

Cox, S. K.

1982-01-01

The spatial and temporal occurrence of cloud layers, the development of a physical-numerical model to simulate the life cycles of tropospheric cloud layers, and the design of an observational program to study the properties of these layers are described.

Boundary Layer Thermodynamics and Cloud Microphysics for a Mixed Stratocumulus and Cumulus Cloud Field Observed during ACE-ENA

NASA Astrophysics Data System (ADS)

Jensen, M. P.; Miller, M. A.; Wang, J.

2017-12-01

The first Intensive Observation Period of the DOE Aerosol and Cloud Experiments in the Eastern North Atlantic (ACE-ENA) took place from 21 June through 20 July 2017 involving the deployment of the ARM Gulfstream-159 (G-1) aircraft with a suite of in situ cloud and aerosol instrumentation in the vicinity of the ARM Climate Research Facility Eastern North Atlantic (ENA) site on Graciosa Island, Azores. Here we present preliminary analysis of the thermodynamic characteristics of the marine boundary layer and the variability of cloud properties for a mixed cloud field including both stratiform cloud layers and deeper cumulus elements. Analysis combines in situ atmospheric state observations from the G-1 with radiosonde profiles and surface meteorology from the ENA site in order to characterize the thermodynamic structure of the marine boundary layer including the coupling state and stability. Cloud/drizzle droplet size distributions measured in situ are combined with remote sensing observations from a scanning cloud radar, and vertically pointing cloud radar and lidar provide quantification of the macrophysical and microphysical properties of the mixed cloud field.

The Green Bank Ammonia Survey of the Gould Belt

NASA Astrophysics Data System (ADS)

Friesen, Rachel; Pineda, Jaime; GAS Team

2018-01-01

The past several years have seen a tremendous advancement in our ability to characterize the structure of nearby molecular clouds traced by large-scale continuum surveys. Critical, comparable data on the dense gas kinematics and temperatures are needed to understand the history and future fate of star-forming material. Filling this gap is the Green Bank Ammonia Survey (GAS), an ambitious legacy survey for the Green Bank Telescope to observe key molecular tracers of dense gas within all Gould Belt clouds visible from the northern hemisphere. I will present the latest science from GAS, whose goals are to 1) evaluate the stability of dense gas structures as a function of scale, 2) track the dissipation of turbulence and evolution of angular momentum in filaments and cores, and 3) quantitatively test predictions of models of core and filament formation via mass flows and accretion.

Global atmospheric particle formation from CERN CLOUD measurements.

PubMed

Dunne, Eimear M; Gordon, Hamish; Kürten, Andreas; Almeida, João; Duplissy, Jonathan; Williamson, Christina; Ortega, Ismael K; Pringle, Kirsty J; Adamov, Alexey; Baltensperger, Urs; Barmet, Peter; Benduhn, Francois; Bianchi, Federico; Breitenlechner, Martin; Clarke, Antony; Curtius, Joachim; Dommen, Josef; Donahue, Neil M; Ehrhart, Sebastian; Flagan, Richard C; Franchin, Alessandro; Guida, Roberto; Hakala, Jani; Hansel, Armin; Heinritzi, Martin; Jokinen, Tuija; Kangasluoma, Juha; Kirkby, Jasper; Kulmala, Markku; Kupc, Agnieszka; Lawler, Michael J; Lehtipalo, Katrianne; Makhmutov, Vladimir; Mann, Graham; Mathot, Serge; Merikanto, Joonas; Miettinen, Pasi; Nenes, Athanasios; Onnela, Antti; Rap, Alexandru; Reddington, Carly L S; Riccobono, Francesco; Richards, Nigel A D; Rissanen, Matti P; Rondo, Linda; Sarnela, Nina; Schobesberger, Siegfried; Sengupta, Kamalika; Simon, Mario; Sipilä, Mikko; Smith, James N; Stozkhov, Yuri; Tomé, Antonio; Tröstl, Jasmin; Wagner, Paul E; Wimmer, Daniela; Winkler, Paul M; Worsnop, Douglas R; Carslaw, Kenneth S

2016-12-02

Fundamental questions remain about the origin of newly formed atmospheric aerosol particles because data from laboratory measurements have been insufficient to build global models. In contrast, gas-phase chemistry models have been based on laboratory kinetics measurements for decades. We built a global model of aerosol formation by using extensive laboratory measurements of rates of nucleation involving sulfuric acid, ammonia, ions, and organic compounds conducted in the CERN CLOUD (Cosmics Leaving Outdoor Droplets) chamber. The simulations and a comparison with atmospheric observations show that nearly all nucleation throughout the present-day atmosphere involves ammonia or biogenic organic compounds, in addition to sulfuric acid. A considerable fraction of nucleation involves ions, but the relatively weak dependence on ion concentrations indicates that for the processes studied, variations in cosmic ray intensity do not appreciably affect climate through nucleation in the present-day atmosphere. Copyright © 2016, American Association for the Advancement of Science.

Test study on the performance of shielding configuration with stuffed layer under hypervelocity impact

NASA Astrophysics Data System (ADS)

Ke, Fa-wei; Huang, Jie; Wen, Xue-zhong; Ma, Zhao-xia; Liu, Sen

2016-10-01

In order to study the cracking and intercepting mechanism of stuffed layer configuration on the debris cloud and to develop stuffed layer configuration with better performance, the hypervelocity impact tests on shielding configurations with stuffed layer were carried out. Firstly, the hypervelocity impact tests on the shielding configuration with stuffed layer of 3 layer ceramic fibre and 3 layer aramid fibre were finished, the study results showed that the debris cloud generated by the aluminum sphere impacting bumper at the velocity of about 6.2 km/s would be racked and intercepted by the stuffed layer configuration efficiently when the ceramic fibre layers and aramid fibre layers were jointed together, however, the shielding performance would be declined when the ceramic fibre layers and aramid fibre layers were divided by some distance. The mechanism of stuffed layer racking and intercepting the debris cloud was analyzed according to the above test results. Secondly, based on the mechanism of the stuffed layer cracking and intercepint debirs cloud the hypervelocity impact tests on the following three stuffed layer structures with the equivalent areal density to the 1 mm-thick aluminum plate were also carried out to compare their performance of cracking and intercepting debris cloud. The mechanisms of stuffed layer racking and intercepting the debris cloud were validated by the test result. Thirdly, the influence of the stuffed layer position on the shielding performance was studied by the test, too. The test results would provide reference for the design of better performance shielding configuration with stuffed layer.

Relation of Cloud Occurrence Frequency, Overlap, and Effective Thickness Derived from CALIPSO and CloudSat Merged Cloud Vertical Profiles

NASA Technical Reports Server (NTRS)

Kato, Seiji; Sun-Mack, Sunny; Miller, Walter F.; Rose, Fred G.; Chen, Yan; Minnis, Patrick; Wielicki, Bruce A.

2009-01-01

A cloud frequency of occurrence matrix is generated using merged cloud vertical profile derived from Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) and Cloud Profiling Radar (CPR). The matrix contains vertical profiles of cloud occurrence frequency as a function of the uppermost cloud top. It is shown that the cloud fraction and uppermost cloud top vertical pro les can be related by a set of equations when the correlation distance of cloud occurrence, which is interpreted as an effective cloud thickness, is introduced. The underlying assumption in establishing the above relation is that cloud overlap approaches the random overlap with increasing distance separating cloud layers and that the probability of deviating from the random overlap decreases exponentially with distance. One month of CALIPSO and CloudSat data support these assumptions. However, the correlation distance sometimes becomes large, which might be an indication of precipitation. The cloud correlation distance is equivalent to the de-correlation distance introduced by Hogan and Illingworth [2000] when cloud fractions of both layers in a two-cloud layer system are the same.

Unexpectedly acidic nanoparticles formed in dimethylamine-ammonia-sulfuric-acid nucleation experiments at CLOUD

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lawler, Michael J.; Winkler, Paul M.; Kim, Jaeseok

New particle formation driven by acid–base chemistry was initiated in the CLOUD chamber at CERN by introducing atmospherically relevant levels of gas-phase sulfuric acid and dimethylamine (DMA). Ammonia was also present in the chamber as a gas-phase contaminant from earlier experiments. The composition of particles with volume median diameters (VMDs) as small as 10 nm was measured by the Thermal Desorption Chemical Ionization Mass Spectrometer (TDCIMS). Particulate ammonium-to-dimethylaminium ratios were higher than the gas-phase ammonia-to-DMA ratios, suggesting preferential uptake of ammonia over DMA for the collected 10–30 nm VMD particles. This behavior is not consistent with present nanoparticle physicochemical models,more » which predict a higher dimethylaminium fraction when NH 3 and DMA are present at similar gas-phase concentrations. Despite the presence in the gas phase of at least 100 times higher base concentrations than sulfuric acid, the recently formed particles always had measured base : acid ratios lower than 1 : 1. The lowest base fractions were found in particles below 15 nm VMD, with a strong size-dependent composition gradient. The reasons for the very acidic composition remain uncertain, but a plausible explanation is that the particles did not reach thermodynamic equilibrium with respect to the bases due to rapid heterogeneous conversion of SO 2 to sulfate. Furthermore, these results indicate that sulfuric acid does not require stabilization by ammonium or dimethylaminium as acid–base pairs in particles as small as 10 nm.« less

Unexpectedly acidic nanoparticles formed in dimethylamine-ammonia-sulfuric-acid nucleation experiments at CLOUD

DOE PAGES

Lawler, Michael J.; Winkler, Paul M.; Kim, Jaeseok; ...

2016-11-03

New particle formation driven by acid–base chemistry was initiated in the CLOUD chamber at CERN by introducing atmospherically relevant levels of gas-phase sulfuric acid and dimethylamine (DMA). Ammonia was also present in the chamber as a gas-phase contaminant from earlier experiments. The composition of particles with volume median diameters (VMDs) as small as 10 nm was measured by the Thermal Desorption Chemical Ionization Mass Spectrometer (TDCIMS). Particulate ammonium-to-dimethylaminium ratios were higher than the gas-phase ammonia-to-DMA ratios, suggesting preferential uptake of ammonia over DMA for the collected 10–30 nm VMD particles. This behavior is not consistent with present nanoparticle physicochemical models,more » which predict a higher dimethylaminium fraction when NH 3 and DMA are present at similar gas-phase concentrations. Despite the presence in the gas phase of at least 100 times higher base concentrations than sulfuric acid, the recently formed particles always had measured base : acid ratios lower than 1 : 1. The lowest base fractions were found in particles below 15 nm VMD, with a strong size-dependent composition gradient. The reasons for the very acidic composition remain uncertain, but a plausible explanation is that the particles did not reach thermodynamic equilibrium with respect to the bases due to rapid heterogeneous conversion of SO 2 to sulfate. Furthermore, these results indicate that sulfuric acid does not require stabilization by ammonium or dimethylaminium as acid–base pairs in particles as small as 10 nm.« less

Trade cumulus clouds embedded in a deep regional haze: Results from Indian Ocean CARDEX experiment

NASA Astrophysics Data System (ADS)

Wilcox, E. M.; Thomas, R. M.; Praveen, P. S.; Pistone, K.; Bender, F.; Feng, Y.; Ramanathan, V.

2013-12-01

During the winter monsoon, trade cumulus clouds over the North Indian Ocean are embedded within a deep regional haze described as an atmospheric brown cloud. While the trade-cu clouds are largely confined to the marine boundary layer, the sooty brown cloud extends from the boundary layer to as high as 3 km; well above the tops of the cumulus. The boundary layer pollution is persistent and limits drizzle in the cumulus over a period of greater than a month at the Maldives Climate Observatory located at Hanimaadhoo Island. The elevated haze from 1 to 3 km altitude is episodic and strongly modulated by synoptic variability in the 700 hPa flow. The elevated plume enhances heating above the marine boundary layer through daytime absorption of sunlight by the haze particles. The interplay between the microphysical modification of clouds by boundary layer pollution and the episodic elevated heating by the atmospheric brown cloud are explored in in-situ observations from UAVs and surface remote sensing during the CARDEX field campaign of winter 2012 and supported by multi-year analysis of satellite remote sensing observations. These observations document the variability in pollution at the surface and above the marine boundary layer and the effects of pollution on the microphysics of the trade-cu clouds, the depth of the marine boundary layer, the liquid water path of trade-cu clouds, and the profile of turbulent moisture flux through the boundary layer. The consequences of these effects for the radiative forcing of regional climate will be discussed.

[Effects of nitrogen application level on soil nitrate accumulation and ammonia volatilization in high-yielding wheat field].

PubMed

Wang, Dong; Yu, Zhenwen; Yu, Wenming; Shi, Yu; Zhou, Zhongxin

2006-09-01

The study showed that during the period from sowing to pre-wintering, the soil nitrate in high-yielding wheat field moved down to deeper layers, and accumulated in the layers below 140 cm. An application rate of 96-168 kg N x hm(-2) increased the nitrate content in 0-60 cm soil layer and the wheat grain yield and its protein content, and decreased the proportion of apparent N loss to applied N and the ammonia volatilization loss from basal nitrogen. Applying 240 kg N x hm(-2) promoted the downward movement of soil nitrate and its accumulation in deeper layers, increased the proportion of apparent N loss to applied N and the ammonia volatilization loss from basal nitrogen, had no significant effect on the protein content of wheat grain, but decreased the grain yield. The appropriate application rate of nitrogen on high-yielding wheat field was 132-204 kg N x hm(-2).

Cloud-Resolving Model Simulations of Aerosol-Cloud Interactions Triggered by Strong Aerosol Emissions in the Arctic

NASA Astrophysics Data System (ADS)

Wang, H.; Kravitz, B.; Rasch, P. J.; Morrison, H.; Solomon, A.

2014-12-01

Previous process-oriented modeling studies have highlighted the dependence of effectiveness of cloud brightening by aerosols on cloud regimes in warm marine boundary layer. Cloud microphysical processes in clouds that contain ice, and hence the mechanisms that drive aerosol-cloud interactions, are more complicated than in warm clouds. Interactions between ice particles and liquid drops add additional levels of complexity to aerosol effects. A cloud-resolving model is used to study aerosol-cloud interactions in the Arctic triggered by strong aerosol emissions, through either geoengineering injection or concentrated sources such as shipping and fires. An updated cloud microphysical scheme with prognostic aerosol and cloud particle numbers is employed. Model simulations are performed in pure super-cooled liquid and mixed-phase clouds, separately, with or without an injection of aerosols into either a clean or a more polluted Arctic boundary layer. Vertical mixing and cloud scavenging of particles injected from the surface is still quite efficient in the less turbulent cold environment. Overall, the injection of aerosols into the Arctic boundary layer can delay the collapse of the boundary layer and increase low-cloud albedo. The pure liquid clouds are more susceptible to the increase in aerosol number concentration than the mixed-phase clouds. Rain production processes are more effectively suppressed by aerosol injection, whereas ice precipitation (snow) is affected less; thus the effectiveness of brightening mixed-phase clouds is lower than for liquid-only clouds. Aerosol injection into a clean boundary layer results in a greater cloud albedo increase than injection into a polluted one, consistent with current knowledge about aerosol-cloud interactions. Unlike previous studies investigating warm clouds, the impact of dynamical feedback due to precipitation changes is small. According to these results, which are dependent upon the representation of ice nucleation processes in the employed microphysical scheme, Arctic geoengineering/shipping could have substantial local radiative effects, but is unlikely to be effective as the sole means of counterbalancing warming due to climate change.

Simulations of arctic mixed-phase clouds in forecasts with CAM3 and AM2 for M-PACE

DOE PAGES

Xie, Shaocheng; Boyle, James; Klein, Stephen A.; ...

2008-02-27

[1] Simulations of mixed-phase clouds in forecasts with the NCAR Atmosphere Model version 3 (CAM3) and the GFDL Atmospheric Model version 2 (AM2) for the Mixed-Phase Arctic Cloud Experiment (M-PACE) are performed using analysis data from numerical weather prediction centers. CAM3 significantly underestimates the observed boundary layer mixed-phase cloud fraction and cannot realistically simulate the variations of liquid water fraction with temperature and cloud height due to its oversimplified cloud microphysical scheme. In contrast, AM2 reasonably reproduces the observed boundary layer cloud fraction while its clouds contain much less cloud condensate than CAM3 and the observations. The simulation of themore » boundary layer mixed-phase clouds and their microphysical properties is considerably improved in CAM3 when a new physically based cloud microphysical scheme is used (CAM3LIU). The new scheme also leads to an improved simulation of the surface and top of the atmosphere longwave radiative fluxes. Sensitivity tests show that these results are not sensitive to the analysis data used for model initialization. Increasing model horizontal resolution helps capture the subgrid-scale features in Arctic frontal clouds but does not help improve the simulation of the single-layer boundary layer clouds. AM2 simulated cloud fraction and LWP are sensitive to the change in cloud ice number concentrations used in the Wegener-Bergeron-Findeisen process while CAM3LIU only shows moderate sensitivity in its cloud fields to this change. Furthermore, this paper shows that the Wegener-Bergeron-Findeisen process is important for these models to correctly simulate the observed features of mixed-phase clouds.« less

Simulations of Arctic mixed-phase clouds in forecasts with CAM3 and AM2 for M-PACE

NASA Astrophysics Data System (ADS)

Xie, Shaocheng; Boyle, James; Klein, Stephen A.; Liu, Xiaohong; Ghan, Steven

2008-02-01

Simulations of mixed-phase clouds in forecasts with the NCAR Atmosphere Model version 3 (CAM3) and the GFDL Atmospheric Model version 2 (AM2) for the Mixed-Phase Arctic Cloud Experiment (M-PACE) are performed using analysis data from numerical weather prediction centers. CAM3 significantly underestimates the observed boundary layer mixed-phase cloud fraction and cannot realistically simulate the variations of liquid water fraction with temperature and cloud height due to its oversimplified cloud microphysical scheme. In contrast, AM2 reasonably reproduces the observed boundary layer cloud fraction while its clouds contain much less cloud condensate than CAM3 and the observations. The simulation of the boundary layer mixed-phase clouds and their microphysical properties is considerably improved in CAM3 when a new physically based cloud microphysical scheme is used (CAM3LIU). The new scheme also leads to an improved simulation of the surface and top of the atmosphere longwave radiative fluxes. Sensitivity tests show that these results are not sensitive to the analysis data used for model initialization. Increasing model horizontal resolution helps capture the subgrid-scale features in Arctic frontal clouds but does not help improve the simulation of the single-layer boundary layer clouds. AM2 simulated cloud fraction and LWP are sensitive to the change in cloud ice number concentrations used in the Wegener-Bergeron-Findeisen process while CAM3LIU only shows moderate sensitivity in its cloud fields to this change. This paper shows that the Wegener-Bergeron-Findeisen process is important for these models to correctly simulate the observed features of mixed-phase clouds.

Remote Sensing of Cloud Top Heights Using the Research Scanning Polarimeter

NASA Technical Reports Server (NTRS)

Sinclair, Kenneth; van Diedenhoven, Bastiaan; Cairns, Brian; Yorks, John; Wasilewski, Andrzej

2015-01-01

Clouds cover roughly two thirds of the globe and act as an important regulator of Earth's radiation budget. Of these, multilayered clouds occur about half of the time and are predominantly two-layered. Changes in cloud top height (CTH) have been predicted by models to have a globally averaged positive feedback, however observational changes in CTH have shown uncertain results. Additional CTH observations are necessary to better and quantify the effect. Improved CTH observations will also allow for improved sub-grid parameterizations in large-scale models and accurate CTH information is important when studying variations in freezing point and cloud microphysics. NASA's airborne Research Scanning Polarimeter (RSP) is able to measure cloud top height using a novel multi-angular contrast approach. RSP scans along the aircraft track and obtains measurements at 152 viewing angles at any aircraft location. The approach presented here aggregates measurements from multiple scans to a single location at cloud altitude using a correlation function designed to identify the location-distinct features in each scan. During NASAs SEAC4RS air campaign, the RSP was mounted on the ER-2 aircraft along with the Cloud Physics Lidar (CPL), which made simultaneous measurements of CTH. The RSPs unique method of determining CTH is presented. The capabilities of using single and combinations of channels within the approach are investigated. A detailed comparison of RSP retrieved CTHs with those of CPL reveal the accuracy of the approach. Results indicate a strong ability for the RSP to accurately identify cloud heights. Interestingly, the analysis reveals an ability for the approach to identify multiple cloud layers in a single scene and estimate the CTH of each layer. Capabilities and limitations of identifying single and multiple cloud layers heights are explored. Special focus is given to sources of error in the method including optically thin clouds, physically thick clouds, multi-layered clouds as well as cloud phase. When determining multi-layered CTHs, limits on the upper clouds opacity are assessed.

A General Cross-Layer Cloud Scheduling Framework for Multiple IoT Computer Tasks.

PubMed

Wu, Guanlin; Bao, Weidong; Zhu, Xiaomin; Zhang, Xiongtao

2018-05-23

The diversity of IoT services and applications brings enormous challenges to improving the performance of multiple computer tasks' scheduling in cross-layer cloud computing systems. Unfortunately, the commonly-employed frameworks fail to adapt to the new patterns on the cross-layer cloud. To solve this issue, we design a new computer task scheduling framework for multiple IoT services in cross-layer cloud computing systems. Specifically, we first analyze the features of the cross-layer cloud and computer tasks. Then, we design the scheduling framework based on the analysis and present detailed models to illustrate the procedures of using the framework. With the proposed framework, the IoT services deployed in cross-layer cloud computing systems can dynamically select suitable algorithms and use resources more effectively to finish computer tasks with different objectives. Finally, the algorithms are given based on the framework, and extensive experiments are also given to validate its effectiveness, as well as its superiority.

SATURN, IN NATURAL COLORS

NASA Technical Reports Server (NTRS)

2002-01-01

NASA's Hubble Space Telescope has provided images of Saturn in many colors, from black-and-white, to orange, to blue, green, and red. But in this picture, image processing specialists have worked to provide a crisp, extremely accurate view of Saturn, which highlights the planet's pastel colors. Bands of subtle color - yellows, browns, grays - distinguish differences in the clouds over Saturn, the second largest planet in the solar system. Saturn's high-altitude clouds are made of colorless ammonia ice. Above these clouds is a layer of haze or smog, produced when ultraviolet light from the sun shines on methane gas. The smog contributes to the planet's subtle color variations. One of Saturn's moons, Enceladus, is seen casting a shadow on the giant planet as it passes just above the ring system. The flattened disk swirling around Saturn is the planet's most recognizable feature, and this image displays it in sharp detail. This is the planet's ring system, consisting mostly of chunks of water ice. Although it appears as if the disk is composed of only a few rings, it actually consists of tens of thousands of thin 'ringlets.' This picture also shows the two classic divisions in the ring system. The narrow Encke Gap is nearest to the disk's outer edge; the Cassini division, is the wide gap near the center. Scientists study Saturn and its ring system to gain insight into the birth of our solar system. Credit: Hubble Heritage Team (AURA/STScI/NASA)

Examining the Impact of Overlying Aerosols on the Retrieval of Cloud Optical Properties from Passive Remote Sensing

NASA Technical Reports Server (NTRS)

Coddington, O. M.; Pilewskie, P.; Redemann, J.; Platnick, S.; Russell, P. B.; Schmidt, K. S.; Gore, W. J.; Livingston, J.; Wind, G.; Vukicevic, T.

2010-01-01

Haywood et al. (2004) show that an aerosol layer above a cloud can cause a bias in the retrieved cloud optical thickness and effective radius. Monitoring for this potential bias is difficult because space ]based passive remote sensing cannot unambiguously detect or characterize aerosol above cloud. We show that cloud retrievals from aircraft measurements above cloud and below an overlying aerosol layer are a means to test this bias. The data were collected during the Intercontinental Chemical Transport Experiment (INTEX-A) study based out of Portsmouth, New Hampshire, United States, above extensive, marine stratus cloud banks affected by industrial outflow. Solar Spectral Flux Radiometer (SSFR) irradiance measurements taken along a lower level flight leg above cloud and below aerosol were unaffected by the overlying aerosol. Along upper level flight legs, the irradiance reflected from cloud top was transmitted through an aerosol layer. We compare SSFR cloud retrievals from below ]aerosol legs to satellite retrievals from the Moderate Resolution Imaging Spectroradiometer (MODIS) in order to detect an aerosol ]induced bias. In regions of small variation in cloud properties, we find that SSFR and MODIS-retrieved cloud optical thickness compares within the uncertainty range for each instrument while SSFR effective radius tend to be smaller than MODIS values (by 1-2 microns) and at the low end of MODIS uncertainty estimates. In regions of large variation in cloud properties, differences in SSFR and MODIS ]retrieved cloud optical thickness and effective radius can reach values of 10 and 10 microns, respectively. We include aerosols in forward modeling to test the sensitivity of SSFR cloud retrievals to overlying aerosol layers. We find an overlying absorbing aerosol layer biases SSFR cloud retrievals to smaller effective radii and optical thickness while nonabsorbing aerosols had no impact.

The evolution of nocturnal boundary-layer clouds in southern West Africa - a case study from DACCIWA

NASA Astrophysics Data System (ADS)

Adler, Bianca; Kalthoff, Norbert; Babić, Karmen; Lohou, Fabienne; Dione, Cheikh; Lothon, Marie; Pedruzo-Bagazgoitia, Xabier

2017-04-01

During the monsoon season, the atmospheric boundary layer in southern West Africa is characterised by various kinds of low-level clouds which experience a distinct diurnal cycle. During the night, extensive low-level stratiform clouds frequently form with a cloud base often less than few hundred metres above ground. After sunrise the cloud base slowly starts rising and eventually a transition to convective clouds occurs. While the existence of the clouds is documented in satellite images and synoptic observations, little is known about the mechanisms controlling their evolution. To provide observational evidence, a field campaign was conducted in southern West Africa in June and July 2016 within the framework of the Dynamics-aerosol-chemistry-cloud interactions in West Africa (DACCIWA) project. Comprehensive ground-based in situ and remote sensing measurements were performed at three different supersites in Ghana, Benin and Nigeria. In this contribution, we present the diurnal cycle of boundary-layer clouds for a typical day using data from a supersite at Savè in Benin. Due to the synergy of various instruments, we are able to obtain detailed information on the evolution of the clouds as well as on the boundary-layer structure with high temporal and vertical resolution. By combining ceilometer, cloud radar and microwave radiometer data we determined the cloud base, -depth and -density. The clouds form in the same layer as a nocturnal low-level jet (NLLJ), which we probe by sodar and UHF profiler. There is evidence for a strong link between the height and strength of the NLLJ and the density of the nocturnal clouds.

Highly Sensitive Ammonia Gas Sensor Based on Single-Crystal Poly(3-hexylthiophene) (P3HT) Organic Field Effect Transistor.

PubMed

Mun, Seohyun; Park, Yoonkyung; Lee, Yong-Eun Koo; Sung, Myung Mo

2017-11-28

A highly sensitive organic field-effect transistor (OFET)-based sensor for ammonia in the range of 0.01 to 25 ppm was developed. The sensor was fabricated by employing an array of single-crystal poly(3-hexylthiophene) (P3HT) nanowires as the organic semiconductor (OSC) layer of an OFET with a top-contact geometry. The electrical characteristics (field-effect mobility, on/off current ratio) of the single-crystal P3HT nanowire OFET were about 2 orders of magnitude larger than those of the P3HT thin film OFET with the same geometry. The P3HT nanowire OFET showed excellent sensitivity to ammonia, about 3 times higher than that of the P3HT thin film OFET at 25 ppm ammonia. The ammonia response of the OFET was reversible and was not affected by changes in relative humidity from 45 to 100%. The high ammonia sensitivity of the P3HT nanowire OFET is believed to result from the single crystal nature and high surface/volume ratio of the P3HT nanowire used in the OSC layer.

A Case Study of Ship Track Formation in a Polluted Marine Boundary Layer.

NASA Astrophysics Data System (ADS)

Noone, Kevin J.; Johnson, Doug W.; Taylor, Jonathan P.; Ferek, Ronald J.; Garrett, Tim; Hobbs, Peter V.; Durkee, Philip A.; Nielsen, Kurt; Öström, Elisabeth; O'Dowd, Colin; Smith, Michael H.; Russell, Lynn M.; Flagan, Richard C.; Seinfeld, John H.; de Bock, Lieve; van Grieken, René E.; Hudson, James G.; Brooks, Ian;  Gasparovic, Richard F.;  Pockalny, Robert A.

2000-08-01

A case study of the effects of ship emissions on the microphysical, radiative, and chemical properties of polluted marine boundary layer clouds is presented. Two ship tracks are discussed in detail. In situ measurements of cloud drop size distributions, liquid water content, and cloud radiative properties, as well as aerosol size distributions (outside-cloud, interstitial, and cloud droplet residual particles) and aerosol chemistry, are presented. These are related to remotely sensed measurements of cloud radiative properties.The authors examine the processes behind ship track formation in a polluted marine boundary layer as an example of the effects of anthropogenic particulate pollution on the albedo of marine stratiform clouds.

Role of vacancy sites and UV-ozone treatment on few layered MoS2 nanoflakes for toxic gas detection

NASA Astrophysics Data System (ADS)

Burman, Debasree; Ghosh, Ruma; Santra, Sumita; Ray, Samit Kumar; Guha, Prasanta Kumar

2017-10-01

Various issues like global warming and environmental pollutions have led to the research of toxic gas detection worldwide. In this work, we have tried to develop a molybdenum disulfide (MoS2) based gas sensor to detect toxic gases like ammonia and NO. MoS2, an inorganic analog of graphene, has attracted lots of attention for many different applications recently. This paper reports the use of liquid exfoliated MoS2 nanoflakes as the sensing layer in a handheld, resistive toxic gas sensor. The nanoflakes were exfoliated from MoS2 bulk powder using a sonication based exfoliation technique at room temperature. The successful exfoliation of the nanoflakes was characterized using different techniques e.g., optical microscopy, atomic force microscopy, field emission scanning electron microscopy, high resolution transmission electron microscopy, x-ray diffraction, Raman spectroscopy, x-ray photoelectron spectroscopy and ultraviolet-visible spectrophotometry. The characterization results showed that few-layered nanoflakes have successfully been exfoliated. The MoS2 nanoflakes showed reasonable sensing towards ammonia and NO. In order to explore the effect of particle size on ammonia sensing, the MoS2 flakes were also exfoliated using different sonication times. We also observed that various factors like presence of vacancy sites, ambient oxygen, humidity, different contact electrodes have significant effect on the sensing characteristics. In fact, the response of the sensing layer against 400 ppm of ammonia increased from 54.1% to ˜80% when it was UV-ozone treated. This work holds promises to developing cost-effective, reliable and highly sensitive MoS2 based ammonia sensors.

Seasonally Transported Aerosol Layers Over Southeast Atlantic are Closer to Underlying Clouds than Previously Reported

NASA Technical Reports Server (NTRS)

Rajapakshe, Chamara; Zhang, Zhibo; Yorks, John E.; Yu, Hongbin; Tan, Qian; Meyer, Kerry; Platnick, Steven; Winker, David M.

2017-01-01

From June to October, low-level clouds in the southeast (SE) Atlantic often underlie seasonal aerosol layers transported from African continent. Previously, the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) 532 nm lidar observations have been used to estimate the relative vertical location of the above-cloud aerosols (ACA) to the underlying clouds. Here we show new observations from NASA's Cloud-Aerosol Transport System (CATS) lidar. Two seasons of CATS 1064 nm observations reveal that the bottom of the ACA layer is much lower than previously estimated based on CALIPSO 532 nm observations. For about 60% of CATS nighttime ACA scenes, the aerosol layer base is within 360 m distance to the top of the underlying cloud. Our results are important for future studies of the microphysical indirect and semidirect effects of ACA in the SE Atlantic region.

Manufacture of a Polyaniline Nanofiber Ammonia Sensor Integrated with a Readout Circuit Using the CMOS-MEMS Technique

PubMed Central

Liu, Mao-Chen; Dai, Ching-Liang; Chan, Chih-Hua; Wu, Chyan-Chyi

2009-01-01

This study presents the fabrication of a polyaniline nanofiber ammonia sensor integrated with a readout circuit on a chip using the commercial 0.35 μm complementary metal oxide semiconductor (CMOS) process and a post-process. The micro ammonia sensor consists of a sensing resistor and an ammonia sensing film. Polyaniline prepared by a chemical polymerization method was adopted as the ammonia sensing film. The fabrication of the ammonia sensor needs a post-process to etch the sacrificial layers and to expose the sensing resistor, and then the ammonia sensing film is coated on the sensing resistor. The ammonia sensor, which is of resistive type, changes its resistance when the sensing film adsorbs or desorbs ammonia gas. A readout circuit is employed to convert the resistance of the ammonia sensor into the voltage output. Experimental results show that the sensitivity of the ammonia sensor is about 0.88 mV/ppm at room temperature. PMID:22399944

Manufacture of a Polyaniline Nanofiber Ammonia Sensor Integrated with a Readout Circuit Using the CMOS-MEMS Technique.

PubMed

Liu, Mao-Chen; Dai, Ching-Liang; Chan, Chih-Hua; Wu, Chyan-Chyi

2009-01-01

This study presents the fabrication of a polyaniline nanofiber ammonia sensor integrated with a readout circuit on a chip using the commercial 0.35 μm complementary metal oxide semiconductor (CMOS) process and a post-process. The micro ammonia sensor consists of a sensing resistor and an ammonia sensing film. Polyaniline prepared by a chemical polymerization method was adopted as the ammonia sensing film. The fabrication of the ammonia sensor needs a post-process to etch the sacrificial layers and to expose the sensing resistor, and then the ammonia sensing film is coated on the sensing resistor. The ammonia sensor, which is of resistive type, changes its resistance when the sensing film adsorbs or desorbs ammonia gas. A readout circuit is employed to convert the resistance of the ammonia sensor into the voltage output. Experimental results show that the sensitivity of the ammonia sensor is about 0.88 mV/ppm at room temperature.

Large Eddy Simulations of Continental Boundary Layer Clouds Observed during the RACORO Field Campaign

NASA Astrophysics Data System (ADS)

Endo, S.; Fridlind, A. M.; Lin, W.; Vogelmann, A. M.; Toto, T.; Liu, Y.

2013-12-01

Three cases of boundary layer clouds are analyzed in the FAst-physics System TEstbed and Research (FASTER) project, based on continental boundary-layer-cloud observations during the RACORO Campaign [Routine Atmospheric Radiation Measurement (ARM) Aerial Facility (AAF) Clouds with Low Optical Water Depths (CLOWD) Optical Radiative Observations] at the ARM Climate Research Facility's Southern Great Plains (SGP) site. The three 60-hour case study periods are selected to capture the temporal evolution of cumulus, stratiform, and drizzling boundary-layer cloud systems under a range of conditions, intentionally including those that are relatively more mixed or transitional in nature versus being of a purely canonical type. Multi-modal and temporally varying aerosol number size distribution profiles are derived from aircraft observations. Large eddy simulations (LESs) are performed for the three case study periods using the GISS Distributed Hydrodynamic Aerosol and Radiative Modeling Application (DHARMA) model and the WRF-FASTER model, which is the Weather Research and Forecasting (WRF) model implemented with forcing ingestion and other functions to constitute a flexible LES. The two LES models commonly capture the significant transitions of cloud-topped boundary layers in the three periods: diurnal evolution of cumulus layers repeating over multiple days, nighttime evolution/daytime diminution of thick stratus, and daytime breakup of stratus and stratocumulus clouds. Simulated transitions of thermodynamic structures of the cloud-topped boundary layers are examined by balloon-borne soundings and ground-based remote sensors. Aircraft observations are then used to statistically evaluate the predicted cloud droplet number size distributions under varying aerosol and cloud conditions. An ensemble approach is used to refine the model configuration for the combined use of observations with parallel LES and single-column model simulations. See Lin et al. poster for single-column model investigation.

[CII] observations of H2 molecular layers in transition clouds

NASA Astrophysics Data System (ADS)

Velusamy, T.; Langer, W. D.; Pineda, J. L.; Goldsmith, P. F.; Li, D.; Yorke, H. W.

2010-10-01

We present the first results on the diffuse transition clouds observed in [CII] line emission at 158 μm (1.9 THz) towards Galactic longitudes near 340° (5 LOSs) & 20° (11 LOSs) as part of the HIFI tests and GOT C+ survey. Out of the total 146 [CII] velocity components detected by profile fitting we identify 53 as diffuse molecular clouds with associated 12CO emission but without 13CO emission and characterized by AV < 5 mag. We estimate the fraction of the [CII] emission in the diffuse HI layer in each cloud and then determine the [CII] emitted from the molecular layers in the cloud. We show that the excess [CII] intensities detected in a few clouds is indicative of a thick H2 layer around the CO core. The wide range of clouds in our sample with thin to thick H2 layers suggests that these are at various evolutionary states characterized by the formation of H2 and CO layers from HI and C+, respectively. In about 30% of the clouds the H2 column densities (“dark gas”) traced by the [CII] is 50% or more than that traced by 12CO emission. On the average ~25% of the total H2 in these clouds is in an H2 layer which is not traced by CO. We use the HI, [CII], and 12CO intensities in each cloud along with simple chemical models to obtain constraints on the FUV fields and cosmic ray ionization rates. Herschel is an ESA space observatory with science instruments provided by European-led Principal Investigator consortia and with important participation from NASA.

H-1 NMR study of ternary ammonia-alkali metal-graphite intercalation compounds

NASA Technical Reports Server (NTRS)

Tsang, T.; Fronko, R. M.; Resing, H. A.; Qian, X. W.; Solin, S. A.

1987-01-01

For the first-stage ternary ammonia-alkali metal-graphite intercalation compounds M(NH3)(x)C24(x of about 4, M = K, Rb, Cs), three sets of triplet H-1 NMR spectral lines have been observed at various temperatures and orientations due to the H-1 - H-1 and N-14 - H-1 dipolar interactions. The structures of these compounds have been inferred as mobile (liquid-like) intercalant layers of planar M(NH3)4 ions in between the carbon layers. For the intercalated ammonia molecules, the potential barrier is about 0.2 eV and the molecular geometry is very close to the free NH3 in gas phase.

Modification of the Atmospheric Boundary Layer by a Small Island: Observations from Nauru

DOE Office of Scientific and Technical Information (OSTI.GOV)

Matthews, Stuart; Hacker, Jorg M.; Cole, Jason N.

2007-03-01

Nauru, a small island in the tropical pacific, generates plumes of clouds that may grow to several hundred km length. This study uses observations to examine the mesoscale disturbance of the marine atmospheric boundary layer by the island that produces these cloud streets. Observations of the surface layer were made from two ships in the vicinity of Nauru and from instruments on the island. The structure of the atmospheric boundary layer over the island was investigated using aircraft flights. Cloud production over Nauru was examined using remote sensing instruments. During the day the island surface layer was warmer than themore » marine surface layer and wind speed was lower than over the ocean. Surface heating forced the growth of a thermal internal boundary layer, above which a street of cumulus clouds formed. The production of clouds resulted in reduced downwelling shortwave irradiance at the island surface. A plume of warm-dry air was observed over the island which extended 15 – 20 km downwind.« less

Insights into aerosols, chemistry, and clouds from NETCARE: Observations from the Canadian Arctic in summer 2014

NASA Astrophysics Data System (ADS)

Abbatt, J.

2015-12-01

The Canadian Network on Aerosols and Climate: Addressing Key Uncertainties in Remote Canadian Regions (or NETCARE) was established in 2013 to study the interactions between aerosols, chemistry, clouds and climate. The network brings together Canadian academic and government researchers, along with key international collaborators. Attention is being given to observations and modeling of Arctic aerosol, with the goal to understand underlying processes and so improve predictions of aerosol climate forcing. Motivation to understand the summer Arctic atmosphere comes from the retreat of summer sea ice and associated increase in marine influence. To address these goals, a suite of measurements was conducted from two platforms in summer 2014 in the Canadian Arctic, i.e. an aircraft-based campaign on the Alfred Wegener Institute POLAR 6 and an ocean-based campaign from the CGCS Amundsen icebreaker. NETCARE-POLAR was based out of Resolute Bay, Nunavut during an initial period of little transport and cloud-free conditions and a later period characterized by more transport with potentially biomass burning influence. Measurements included particle and cloud droplet numbers and size distributions, aerosol composition, cloud nuclei, and levels of gaseous tracers. Ultrafine particle events were more frequently observed in the marine boundary layer than above, with particle growth observed in some cases to cloud condensation nucleus sizes. The influence of biological processes on atmospheric constituents was also assessed from the ship during NETCARE-AMUNDSEN, as indicated by high measured levels of gaseous ammonia, DMS and oxygenated VOCs, as well as isolated particle formation and growth episodes. The cruise took place in Baffin Bay and through the Canadian archipelago. Interpretation of the observations from both campaigns is enhanced through the use of chemical transport and particle dispersion models. This talk will provide an overview of NETCARE Arctic observational and related modeling activities, focusing on 2014 Arctic activities and highlighting upcoming presentations within the session and the work of individual research teams. An attempt will be made to synthesize the observations and model results, drawing connections of aerosol sources through to cloud formation and deposition processes.

A Fast Infrared Radiative Transfer Model for Overlapping Clouds

NASA Technical Reports Server (NTRS)

Niu, Jianguo; Yang, Ping; Huang, Huang-Lung; Davies, James E.; Li, Jun; Baum, Bryan A.; Hu, Yong X.

2006-01-01

A fast infrared radiative transfer model (FIRTM2) appropriate for application to both single-layered and overlapping cloud situations is developed for simulating the outgoing infrared spectral radiance at the top of the atmosphere (TOA). In FIRTM2 a pre-computed library of cloud reflectance and transmittance values is employed to account for one or two cloud layers, whereas the background atmospheric optical thickness due to gaseous absorption can be computed from a clear-sky radiative transfer model. FIRTM2 is applicable to three atmospheric conditions: 1) clear-sky, 2) single-layered ice or water cloud, and 3) two simultaneous cloud layers in a column (e.g., ice cloud overlying water cloud). Moreover, FIRTM2 outputs the derivatives (i.e., Jacobians) of the TOA brightness temperature with respect to cloud optical thickness and effective particle size. Sensitivity analyses have been carried out to assess the performance of FIRTM2 for two spectral regions, namely the longwave (LW) band (587.3 - 1179.5/cm) and the short-to-medium wave (SMW) band (1180.1 - 2228.9/cm). The assessment is carried out in terms of brightness temperature differences (BTD) between FIRTM2 and the well-known discrete ordinates radiative transfer model (DISORT), henceforth referred to as BTD (F-D). The BTD (F-D) values for single-layered clouds are generally less than 0.8 K. For the case of two cloud layers (specifically ice cloud over water cloud), the BTD(F-D) values are also generally less than 0.8 K except for the SMW band for the case of a very high altitude (>15 km) cloud comprised of small ice particles. Note that for clear-sky atmospheres, FIRTM2 reduces to the clear-sky radiative transfer model that is incorporated into FIRTM2, and the errors in this case are essentially those of the clear-sky radiative transfer model.

Multi-sensor quantification of aerosol-induced variability in warm clouds over eastern China

NASA Astrophysics Data System (ADS)

Wang, Fu; Guo, Jianping; Zhang, Jiahua; Huang, Jingfeng; Min, Min; Chen, Tianmeng; Liu, Huan; Deng, Minjun; Li, Xiaowen

2015-07-01

Aerosol-cloud (AC) interactions remain uncharacterized due to difficulties in obtaining accurate aerosol and cloud observations. In this study, we quantified the aerosol indirect effects (AIE) on warm clouds over Eastern China based on near-simultaneous retrievals from MODIS/AQUA, CALIOP/CALIPSO, and CPR/CLOUDSAT between June 2006 and December 2010. The seasonality of aerosols from ground-based PM10 (aerosol particles with diameter of 10 μm or less) significantly differed from that estimated using MODIS aerosol optical depth (AOD). This result was supported by the lower level frequency profile of aerosol occurrence from CALIOP, indicative of the significant role of CALIOP in the AC interaction. To focus on warm clouds, cloud layers with base (top) altitudes above 7 (10) km were excluded. The combination of CALIOP and CPR was applied to determine the exact position of warm clouds relative to aerosols out of the following six scenarios in terms of AC mixing states: 1) aerosol only (AO); 2) cloud only (CO); 3) single aerosol layer-single cloud layer (SASC); 4) single aerosol layer-double cloud layers (SADC); 5) double aerosol layers - single cloud layer (DASC); and 6) others. The cases with vertical distance between aerosol and cloud layer less (more) than 100 m (700 m) were marked mixed (separated), and the rest as uncertain. Results showed that only 8.95% (7.53%) belonged to the mixed (separated and uncertain) state among all of the collocated AC overlapping cases, including SASC, SADC, and DASC. Under mixed conditions, the cloud droplet effective radius (CDR) decreased with increasing AOD at moderate aerosol loading (AOD<0.4), and then became saturated at an AOD of around 0.5, followed by an increase in CDR with increasing AOD, known as boomerang shape. Under separated conditions, no apparent changes in CDR with AOD were observed. We categorized the AC dataset into summer- and winter-season subsets to determine how the boomerang shape varied with season. The response of CDR to AOD in summer exhibited similar but much more deepened boomerang shape, as compared with the all year round case. In contrast, CDR in winter did not follow the boomerang shape for its continued decreasing with increasing AOD, even after the saturation zone (AOD around 0.5) of a cloud droplet.

Vertical Structure of Ice Cloud Layers From CloudSat and CALIPSO Measurements and Comparison to NICAM Simulations

NASA Technical Reports Server (NTRS)

Ham, Seung-Hee; Sohn, Byung-Ju; Kato, Seiji; Satoh, Masaki

2013-01-01

The shape of the vertical profile of ice cloud layers is examined using 4 months of CloudSat and Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) global measurements taken on January, April, July, and October 2007. Ice clouds are selected using temperature profiles when the cloud base is located above the 253K temperature level. The obtained ice water content (IWC), effective radius, or extinction coefficient profiles are normalized by their layer mean values and are expressed in the normalized vertical coordinate, which is defined as 0 and 1 at the cloud base and top heights, respectively. Both CloudSat and CALIPSO observations show that the maximum in the IWC and extinction profiles shifts toward the cloud bottom, as the cloud depth increases. In addition, clouds with a base reaching the surface in a high-latitude region show that the maximum peak of the IWC and extinction profiles occurs near the surface, which is presumably due to snow precipitation. CloudSat measurements show that the seasonal difference in normalized cloud vertical profiles is not significant, whereas the normalized cloud vertical profile significantly varies depending on the cloud type and the presence of precipitation. It is further examined if the 7 day Nonhydrostatic Icosahedral Atmospheric Model (NICAM) simulation results from 25 December 2006 to 1 January 2007 generate similar cloud profile shapes. NICAM IWC profiles also show maximum peaks near the cloud bottom for thick cloud layers and maximum peaks at the cloud bottom for low-level clouds near the surface. It is inferred that oversized snow particles in the NICAM cloud scheme produce a more vertically inhomogeneous IWC profile than observations due to quick sedimentation.

An experimental study of the role of particle diffusive convection on the residence time of volcanic ash clouds

NASA Astrophysics Data System (ADS)

Deal, E.; Carazzo, G.; Jellinek, M.

2013-12-01

The longevity of volcanic ash clouds generated by explosive volcanic plumes is difficult to predict. Diffusive convective instabilities leading to the production of internal layering are known to affect the stability and longevity of these clouds, but the detailed mechanisms controlling particle dynamics and sedimentation are poorly understood. We present results from a series of analog experiments reproducing diffusive convection in a 2D (Hele-Shaw) geometry, which allow us to constrain conditions for layer formation, sedimentation regime and cloud residence time as a function of only the source conditions. We inject a turbulent particle-laden jet sideways into a tank containing a basal layer of salt water and an upper layer of fresh water, which ultimately spreads as a gravity current. After the injection is stopped, particles in suspension settle through the cloud to form particle boundary layers (PBL) at the cloud base. We vary the initial particle concentration of the plume and the injection velocity over a wide range of conditions to identify and characterize distinct regimes of sedimentation. Our experiments show that convective instabilities driven as a result of differing diffusivities of salt and particles lead to periodic layering over a wide range of conditions expected in nature. The flux of particles from layered clouds and the thicknesses of the layers are understood using classical theory for double diffusive convection adjusted for the hydrodynamic diffusion of particles. Although diffusive convection increases sedimentation rates for the smallest particles (<30 μm) its overall effect is to extend the cloud residence time to several hours by maintaining larger particles in suspension within the layers, which is several orders of magnitude longer than expected when considering individual settling rates.

A modeling study of marine boundary layer clouds

NASA Technical Reports Server (NTRS)

Wang, Shouping; Fitzjarrald, Daniel E.

1993-01-01

Marine boundary layer (MBL) clouds are important components of the earth's climate system. These clouds drastically reduce the amount of solar radiation absorbed by the earth, but have little effect on the emitted infrared radiation on top of the atmosphere. In addition, these clouds are intimately involved in regulating boundary layer turbulent fluxes. For these reasons, it is important that general circulation models used for climate studies must realistically simulate the global distribution of the MBL. While the importance of these cloud systems is well recognized, many physical processes involved in these clouds are poorly understood and their representation in large-scale models remains an unresolved problem. The present research aims at the development and improvement of the parameterization of these cloud systems and an understanding of physical processes involved. This goal is addressed in two ways. One is to use regional modeling approach to validate and evaluate two-layer marine boundary layer models using satellite and ground-truth observations; the other is to combine this simple model with a high-order turbulence closure model to study the transition processes from stratocumulus to shallow cumulus clouds. Progress made in this effort is presented.

Evaluating stratiform cloud base charge remotely

NASA Astrophysics Data System (ADS)

Harrison, R. Giles; Nicoll, Keri A.; Aplin, Karen L.

2017-06-01

Stratiform clouds acquire charge at their upper and lower horizontal boundaries due to vertical current flow in the global electric circuit. Cloud charge is expected to influence microphysical processes, but understanding is restricted by the infrequent in situ measurements available. For stratiform cloud bases below 1 km in altitude, the cloud base charge modifies the surface electric field beneath, allowing a new method of remote determination. Combining continuous cloud height data during 2015-2016 from a laser ceilometer with electric field mill data, cloud base charge is derived using a horizontal charged disk model. The median daily cloud base charge density found was -0.86 nC m-2 from 43 days' data. This is consistent with a uniformly charged region 40 m thick at the cloud base, now confirming that negative cloud base charge is a common feature of terrestrial layer clouds. This technique can also be applied to planetary atmospheres and volcanic plumes.