Progress on multi-nuclide AMS of JAEA-AMS-TONO
NASA Astrophysics Data System (ADS)
Saito-Kokubu, Yoko; Matsubara, Akihiro; Miyake, Masayasu; Nishizawa, Akimitsu; Ohwaki, Yoshio; Nishio, Tomohiro; Sanada, Katsuki; Hanaki, Tatsumi
2015-10-01
The JAEA-AMS-TONO (Japan Atomic Energy Agency's Accelerator Mass Spectrometer established at the Tono Geoscience Center) facility has been used for the dating of geological samples. The AMS system is versatile, based on a 5 MV tandem Pelletron-type accelerator. Since its establishment in 1997, the AMS system has been used for measurement of carbon-14 (14C) mainly for 14C dating studies in neotectonics and hydrogeology, in support of JAEA's research on geosphere stability applicable to the long-term isolation of high-level radioactive waste. Results of the measurement of 14C in soils and plants has been applied to the dating of fault activity and volcanism. Development of beryllium-10 (10Be) and aluminum-26 (26Al) AMS systems are now underway to enhance the capability of the multi-nuclide AMS in studies of dating by cosmogenic nuclides. The 10Be-AMS system has already been used for routine measurements in applied studies and improvements of the measurement technique have been made. Now we plan to fine tune the system and perform test measurements to develop the 26Al-AMS system.
AMS-14C analysis of modern teeth: A comparison between two sample preparation techniques
NASA Astrophysics Data System (ADS)
Solis, C.; Solis-Meza, E.; Morales, M. E.; Rodriguez-Ceja, M.; Martínez-Carrillo, M. A.; Garcia-Calderon, D.; Huerta, A.; Chávez, E.
2017-09-01
AMS-14C analysis of modern teeth has become important for forensic studies. 14C content in human teeth reflects the 14C atmospheric concentration during its formation and allows the calculation of the actual year of birth. Through AMS, it is possible to measure the 14C concentrations in a tissue with high precision. However, there is a debate about which should be the best fraction for teeth carbon dating: collagen or enamel. This work focuses on the results obtained from enamel and collagen extracted from Mexican people in order to compare them. Collagen from dental pieces donated from people older than 60-years-old have been included to understand the turnover process and usefulness of collagen to determine the date of birth. Our results indicate that when a single dental piece is available, enamel method allows the determination of the tooth formation date. Dating collagen of the same tooth helps to discriminate if the formation date belongs to the left or the right side of the peak bomb, but also corroborates, the ages obtained through enamel analysis.
NASA Astrophysics Data System (ADS)
Li, H. C.; Yin, J.; Rao, Z.; Mii, H. S.; Shen, C. C.; Pillutla, R. K.; Li, Y. X.
2016-12-01
An 11.1-cm long stalagmite (ZZ12) collected from Zhenzhu cave (38°15'N, 113°42'E, 975m a.s.l.) located at Tiangui mountain of Hebei province, North China. The 230Th/U dates on 12 horizons exhibit large uncertainties with many reversed age sequences due to low U contents and low 230Th/232Th ratios. While the 230Th/U dating is not able to provide the chronology of this stalagmite, AMS 14C dating on 27 samples from various depths of the stalagmite yields a reliable age-depth relationship. Three AMS 14C dates from the top 5 mm appear nuclear bomb carbon indicating that this part was deposited after AD 1950. Seven samples for 210Pb dating were taken from the upper 14 mm with 2 mm intervals, showing exponential decay of excess 210Pb and supporting the AMS 14C dating results. At the base of the stalagmite, charcoal grains were included in the carbonate stalagmite. This charcoal sample has a Calibrated 14C age of 1865±20 a BP. The carbonates at adjacent depths show Calibrated 14C ages of 1900±15 and 2215±75 a BP respectively. The bomb carbon and similar ages between the charcoal and carbonates indicate that dead carbon influence on the 14C dates in some horizons may not be serious. From the 27 AMS 14C dates, we select 17 AMS 14C dates which have minimal influence of dead carbon fraction to construct the chronology. The established chronology shows that slow growth rates occurred prior to 1100 a BP and after 600 a BP. This time interval involves the Medieval Warm Period, while the fast growth rate during this interval may reflect warm and wet climatic conditions. A total of 835 samples were drilled from the stalagmite for δ18O and δ13C analyses. The current 900-year δ18O and δ13C records reveal climate and vegetation changes in the study area. Strong decadal oscillations in the δ18O record reflect variations of monsoonal rain, with relatively dry between AD 1350 and AD 1550 and after AD 1960. The δ13C record appears mainly multi-centennial variations with a 4‰ fluctuation range and an average value of -8‰ (VPDB). The δ13C values were lighter than the average during AD 1150 1480 and AD 1700 1920, whereas the δ13C values were heavier than the average during AD 1480 1700 and AD 1820 the present. The δ13C record mainly reflects the vegetation change above the cave, with lighter value indicating better vegetation coverage and vice versa.
Mirabueno, Ma. Hannah T.; Okuno, Mitsuru; Nakamura, Toshio; Newhall, Christopher G.; Kobayashi, Tetsuo
2006-01-01
This paper presents the AMS 14C dates of paleosols intercalated with tephra layers in the vicinity of Mayon Volcano, southern Luzon, Philippines. the obtained 14C dates are almost consistent with the stratigraphy of the Mayon tephra group. On the basis of calibrated 14C age of soil layer directly overlying the lowest ash layer, the oldest eruptive event must have taken place shortly before 20 cal kyr BP. This age is younger than the previous estimates for Mayon.
Assessment of 14C AMS dating of phytoliths as a new paleoenvironmental and archaeological tool
NASA Astrophysics Data System (ADS)
Corbineau, R.; Alexandre, A. E.; Santos, G. M.; Reyerson, P. E.
2011-12-01
14C AMS analysis of occluded carbon in phytoliths (phytC) is a promising dating tool for palaeoenvironmental and archaeological studies. In order to assess the accuracy of this method, different tests were recently carried out on large phytolith concentrates of phytC samples extracted from soils and harvested plants, in association with blank samples of SiO2 powder to check the absence of carbon contamination during the treatments. Despite this precaution, 14C values from recent harvested plants were inexplicably old (2 - 8 ka years BP). Nevertheless, we noticed that many chemical extraction protocols that were used did not lead to samples totally free of organic matter. In order to tackle this problem, and as a first step, the efficiency of common extraction protocols from the literature were tested. Samples were analyzed by SEM/EDX in order to assess the purity of the siliceous material following extraction. As a result of these tests, a new extraction protocol combining acid digestion, oxidation and dry ashing to acquire pure samples of phytoliths from harvested plants is proposed. In a second step, modern and well dated archaeological materials (harvested plants grown within a FACE experiment and plant residues from a 17th century French mummy) were analyzed in 14C-AMS. Results should allow either to demonstrate the reliability of 14C-AMS analysis of phytolith occluded carbon as a dating tool or trigger further investigations of possible sources of old occluded carbon in phytoliths if the 14C ages are still older than expected.
Somayajulu, B L; Bhushan, R; Sarkar, A; Burr, G S; Jull, A J
1999-09-30
Eight gravity cores from the active eastern continental margins of the Arabian Sea were dated using 210Pbxs, 137Cs and 14C. The short-term (< or = 100 years) sedimentation rates range from 0.06 to 0.66 cm/year where as the long-term (> or = 1000 years) ones using AMS 14C on planktonic foraminifera varied from 0.004 to 0.13 cm/year. For long-term chronology (< or = 50,000 years) AMS dating of well-cleaned planktonic foraminifera is most suited.
Direct dating of archaeological pottery by compound-specific 14C analysis of preserved lipids.
Stott, Andrew W; Berstan, Robert; Evershed, Richard P; Bronk-Ramsey, Christopher; Hedges, Robert E M; Humm, Martin J
2003-10-01
A methodology is described demonstrating the utility of the compound-specific 14C technique as a direct means of dating archaeological pottery. The method uses automated preparative capillary gas chromatography employing wide-bore capillary columns to isolate individual compounds from lipid extracts of archaeological potsherds in high purity (>95%) and amounts (>200 microg) sufficient for radiocarbon dating using accelerator mass spectrometry (AMS). A protocol was developed and tested on n-alkanes and n-carboxylic acids possessing a broad range of 14C ages. Analytical blanks and controls allowed background 14C measurements to be assessed and potential sources of errors to be detected, i.e., contamination with modern or dead 14C, isotopic fraction effects, etc. A "Russian doll" method was developed to transfer isolated target compounds onto tin powder/capsules prior to combustion and AMS analyses. The major advantage of the compound-specific technique is that 14C dates obtained for individual compounds can be directly linked to the commodities processed in the vessels during their use, e.g., animal fats. The compound-specific 14C dating protocol was validated on a suite of ancient pottery whose predicted ages spanned a 5000-year date range. Initial results indicate that meaningful correlations can be obtained between the predicted date of pottery and that of the preserved lipids. These findings constitute an important step forward to the direct dating of archaeological pottery.
AMS 14C and 230Th/U dating on stalagmites from North Altai Mountain, Siberia, Russia
NASA Astrophysics Data System (ADS)
Li, H. C.; Yin, J. J.; Blyakharchuk, T.; Shen, C. C.
2017-12-01
Three stalagmites, two from Lunnaya Cave (LUN-1 and LUN-2, 52º40.729'N, 88º43.854' E, 481 m a.s.l.), one from Nadezhda Cave (HOP-1, 52º38.872'N, 88º39.194'E, 550 m a.s.l.) located along Mrassy River in the northern Altai Mountains, Siberia, Russia were collected in the summer of 2016 for paleoclimate reconstruction. HOP-1 is a 21-cm long stalagmite which contains very low U content (238U = 70 ppb) and relatively high Th content (232Th = 2 9.3 ppb), resulting in unsuccessful 230Th/U dating (-262 ± 284 yr BP in the top and -19,935 ± 22,246 yr BP). Thirty one AMS 14C dates from 27 horizons of the stalagmite provide a detailed chronology, showing that the stalagmite grew from 6,350 ± 45 yr BP to 490 ± 10 Calib. yr BP. Both LUN-1 and LUN-2 are about 20-cm long. The growth feature of LUN-2 is similar to that of HOP-1 with continuous growth, clear bands of depositional cycles in white non-transparent calcite, whereas LUN-1 has light yellow transparent calcite in the center part with multiple growth hiatuses. The 230Th/U dates show that LUN-1 from 2725 ± 775 yr BP at 193 mm depth to 823 ± 28 yr BP at 12 mm depth with very fast growth rate during 900 1500 yr BP. The AMS 14C dates of LUN-1 provide similar growth pattern with very fast growth between the first hiatus at 12 mm depth and the second hiatus at 155 cm depth. Six 14C dates from this fast growth period are all around 1500 Calib. yr BP without a correct age sequence. Two 14C dates from the top 12 mm exhibit "nuclear bomb signal" (percentage of modern carbon >100%). Similar ages of AMS 14C and 230Th/U dating results in the lower part indicate that dead carbon influence in radiocarbon ages are negligible. 230Th/U dating is not successful for LUN-2. The preliminary AMS 14C dating on LUN-2 shows that the stalagmite continuously deposited from 13335 ± 150 Calib. yr BP. All three stalagmites do not have growth deposition during the Little Ice Age due to cold and dry climates. Further work on stable isotope analyses will provide us high-resolution paleoclimate changes since the deglaciation in the study area.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Jull, A.J.T.
Since 1981 we have operated an NSF Accelerator Mass Spectrometry (AMS) Facility at the University of Arizona. The AMS method allows us to use very small samples of carbon, <1 mg for radiocarbon dating in contrast to earlier counting techniques. This has opened a vast array of applications of radiocarbon dating that was difficult to do before AMS because of sample size limitations of decay counting. Some of the many applications of AMS include paleoclimatic studies, archaeological research and the age of first settlement of North America by man, dating of art works and artifacts, fall times and terrestrial residencemore » ages of meteorites, production of {sup 14}C in lunar samples by galactic and solar cosmic rays, studies of in situ {sup 14}C produced by cosmic ray spallation in rocks and ice, and studies of {sup 14}C in groundwater dissolved inorganic carbon and dissolved organic carbon. At our laboratory, we have also successfully applied AMS {sup 14}C to dating of many types of textiles, including silks and linens, art works, documents and artifacts fabricated from wood, parchment, ivory, and bone. The results for many of these samples are often important in questions of the authenticity of these works of art and artifacts. Our studies have encompassed a wide range of art works ranging from the Dead Sea Scrolls, the Shroud of Turin, and the Chinese silk trade to the works of Raphael, Rembrandt, and Picasso. Recently, we also dated the Vinland Map, a controversial document that shows the eastern coast of North America apparently using information from Viking voyages.« less
A new graphite preparation line for AMS 14C dating in the Zagreb Radiocarbon Laboratory
NASA Astrophysics Data System (ADS)
Krajcar Bronić, I.; Horvatinčić, N.; Sironić, A.; Obelić, B.; Barešić, J.; Felja, I.
2010-04-01
The new line for preparation of graphite samples for 14C dating by AMS has been constructed in the Zagreb Radiocarbon Laboratory. The performance of the rig and sample preparation procedure has been validated by preparing graphites from various reference materials of known 14C activity. The yield of the graphitization was good and the measured fraction of modern carbon ( Fm) values have not significantly deviated from the expected ones. Detailed analysis of measured Fm values indicates a slight bias to more positive values and should be carefully investigated.
NASA Astrophysics Data System (ADS)
Liou, M. S.; Li, H. C.; Huang, S. K.; Guan, B. T.
2017-12-01
Dendrochronologies built from precisely dated annual rings have shown to record the regional bomb pulse and the C-14 concentration variations caused by local events. In this study, we collected teak trees Tectona grandis near the Lake Taal, Central Philippines in 2011 for dendrochronological analysis and radiocarbon dating. The tree-ring sample contains 90 rings dated from 1922 to 2011. Currently, 28 selected subsamples have been measured by AMS 14C on bulk carbon with a few samples on holocellulose. The 14C results of the samples indicate that: 1) the results of AMS 14C dating between holocellulose and whole wood from the same ring are similar, so we select whole wood for AMS 14C dating. 2) The nuclear bomb 14C pulse was clearly recorded in the Tectona grandis growth rings. The Δ14C values rose dramatically in 1960 and reached a maximum of 692‰ in 1966. The magnitude and the peak year of the bomb curve in the Tectona grandis tree-ring record are comparable to other published tree-ring records in the tropical regions. 3) The Δ14C values suddenly dropped in 1950, 1964 and 1968, probably affected by CO2 gas releasing due to the Taal volcanic activities. Further study on the tree-ring 14C dating will allow us to evaluate the bomb pulse trends more precisely, and the volcanic activities of Pinatubo and Taal Volcanoes. The tree-ring Δ14C record not only confirms existence of the bomb curve in Taal Lake area, but also allows us compare to the Δ14C record in the lake sediment for chronological construction. A 120-cm gravity core, TLS-2, collected from Lake Taal in 2008, shows the nuclear bomb carbon curve in the TOC of the core. However, the magnitude of the nuclear bomb 14C pulse in the TOC of TLS-2 is much lower than that in the tree-ring records, due to mixing effect of different organic carbon sources, smoothing effect of 14CO2 in multiple years plant growths, local old CO2 emission from volcanic activity, degassing from the lake bottom, and industrial and city pollutions. Nevertheless, by comparing the bomb curves, the chronology of Core TLS-2 is about 60 years with a mean sedimentary rate of 2 cm/yr.
NASA Astrophysics Data System (ADS)
Kutschera, Walter; Dellinger, Franz; Liebl, Jakob; Steier, Peter
2011-03-01
This contribution conveys the power of accelerator mass spectrometry (AMS) to measure ultra-low traces of long-lived radionuclides in two highly divers fields: Astrophysics and molecular biology. Our search for nuclides of superheavy elements (SHE) in several natural materials did not confirm the claims of positive evidence for SHEs reported by the group of Amnon Marinov from Jerusalem, even though the sensitivity of our AMS measurements were several orders of magnitude higher. We also report on the investigation by the group of Kirsty Spalding from Stockholm to date human DNA with the 14C bomb peak. This allows one to determine retrospectively the birth date of cells in sections of the human body. Ongoing efforts to miniaturize carbon samples down to the level of 10 μg C for AMS measurements will allow one to venture into ever smaller subsections of the human brain.
Chronologies in wood and resin: AMS 14C dating of pre-Hispanic Caribbean Wood Sculpture
Joanna Ostapkowicz; Christopher Bronk-Ramsey; Fiona Brock; Tom Higham; Alex C. Wiedenhoeft; Erika Ribechini; Jeannette J. Lucejko; Samuel Wilson
2012-01-01
This paper establishes a chronological framework for selected pieces of Caribbean (Tafno/Lucayan) wooden sculpture, enabling previously ahistoric artefacts to fit back into the wider corpus of pre-colonial material culture. Seventy-two 14C AMS determinations from 56 artefacts held in museum collections are reported, including 32 ceremonial
Radiocarbon ages of different fractions of peat on coastal lowland of Bohai Bay: marine influence?
NASA Astrophysics Data System (ADS)
Shang, Zhiwen; Wang, Fu; Fang, Jing; Li, Jianfen; Chen, Yongsheng; Jiang, Xingyu; Tian, Lizhu; Wang, Hong
2018-05-01
Peat in boreholes is the most important 14C dating material used for constructing age framework. 20 bulk peat samples were collected from five boreholes, the 14C ages of two fractions (organic sediment fraction and peat fraction) of the bulk peat samples were investigated by AMS-dating and which fraction is better to help construct an age framework for the boreholes were compared and discussed. The results indicated that the peat fraction give a good dating results sequence in the boreholes, compared with the corresponding organic sediment fraction. And the dating results of organic sediment fraction show 161-6 702 years older than corresponding peat fraction, which was caused by marine influence. Then, we suggest an experience formula as y=0.99x-466.5 by the correlation analysis for correcting the marine influenced organic sediment ages within the conventional ages between 4 000 to 9 000 yrs BP, and more study should be carried out for the AMS 14C dating of the bulk organic sediments.
14C Analysis of protein extracts from Bacillus spores.
Cappuccio, Jenny A; Falso, Miranda J Sarachine; Kashgarian, Michaele; Buchholz, Bruce A
2014-07-01
Investigators of bioagent incidents or interdicted materials need validated, independent analytical methods that will allow them to distinguish between recently made bioagent samples versus material drawn from the archives of a historical program. Heterotrophic bacteria convert the carbon in their food sources, growth substrate or culture media, into the biomolecules they need. The F(14)C (fraction modern radiocarbon) of a variety of media, Bacillus spores, and separated proteins from Bacillus spores was measured by accelerator mass spectrometry (AMS). AMS precisely measures F(14)C values of biological materials and has been used to date the synthesis of biomaterials over the bomb pulse era (1955 to present). The F(14)C of Bacillus spores reflects the radiocarbon content of the media in which they were grown. In a survey of commercial media we found that the F(14)C value indicated that carbon sources for the media were alive within about a year of the date of manufacture and generally of terrestrial origin. Hence, bacteria and their products can be dated using their (14)C signature. Bacillus spore samples were generated onsite with defined media and carbon free purification and also obtained from archived material. Using mechanical lysis and a variety of washes with carbon free acids and bases, contaminant carbon was removed from soluble proteins to enable accurate (14)C bomb-pulse dating. Since media is contemporary, (14)C bomb-pulse dating of isolated soluble proteins can be used to distinguish between historical archives of bioagents and those produced from recent media. Copyright © 2014 Elsevier Ireland Ltd. All rights reserved.
14C Analysis of Protein Extracts from Bacillus Spores
Cappucio, Jenny A.; Sarachine Falso, Miranda J.; Kashgarian, Michaele; Buchholz, Bruce A.
2014-01-01
Investigators of bioagent incidents or interdicted materials need validated, independent analytical methods that will allow them to distinguish between recently made bioagent samples versus material drawn from the archives of a historical program. Heterotrophic bacteria convert the carbon in their food sources, growth substrate or culture media, into the biomolecules they need. The F14C (fraction modern radiocarbon) of a variety of media, Bacillus spores, and separated proteins from Bacillus spores was measured by accelerator mass spectrometry (AMS). AMS precisely measures F14C values of biological materials and has been used to date the synthesis of biomaterials over the bomb pulse era (1955 to present). The F14C of Bacillus spores reflects the radiocarbon content of the media in which they were grown. In a survey of commercial media we found that the F14C value indicated that carbon sources for the media were alive within about a year of the date of manufacture and generally of terrestrial origin. Hence, bacteria and their products can be dated using their 14C signature. Bacillus spore samples were generated onsite with defined media and carbon free purification and also obtained from archived material. Using mechanical lysis and a variety of washes with carbon free acids and bases, contaminant carbon was removed from soluble proteins to enable accurate 14C bomb-pulse dating. Since media is contemporary, 14C bomb-pulse dating of isolated soluble proteins can be used to distinguish between historical archives of bioagents and those produced from recent media. PMID:24814329
NASA Astrophysics Data System (ADS)
Heinemeier, Jan; Jungner, Högne; Lindroos, Alf; Ringbom, Åsa; von Konow, Thorborg; Rud, Niels
1997-03-01
A method for refining lime mortar samples for 14C dating has been developed. It includes mechanical and chemical separation of mortar carbonate with optical control of the purity of the samples. The method has been applied to a large series of AMS datings on lime mortar from three medieval churches on the Åland Islands, Finland. The datings show convincing internal consistency and confine the construction time of the churches to AD 1280-1380 with a most probable date just before AD 1300. We have also applied the method to the controversial Newport Tower, Rhode Island, USA. Our mortar datings confine the building to colonial time in the 17th century and thus refute claims of Viking origin of the tower. For the churches, a parallel series of datings of organic (charcoal) inclusions in the mortar show less reliable results than the mortar samples, which is ascribed to poor association with the construction time.
NASA Astrophysics Data System (ADS)
Xu, H.; Jiang, H.; Yu, S.; Yang, H.; Chen, J.
2016-12-01
Formation of dammed lakes provides exceptionally important information of continental geological processes, responding to tectonic and climatic influences. Establishing accurate geochronological frameworks within lake strata is challenging because the stratigraphy is often bereft of biostratigraphy and directly dateable material. Optically Stimulated Luminescence (OSL) and AMS 14C dating of pollen concentrates are well-established tools for dating lake sediments. Whether they are suitable for lake sediments in high-alpine settings remains uncertain. In this study, OSL and AMS 14C dating of pollen concentrate were conducted on the Diaolin section in a high-alpine setting in the eastern Tibetan Plateau. Good match of both dating results suggests that they are fit for dating lake sediments in high alpine settings. More than 300 g of sediment is required for preparation of pollen concentrates. During the pretreatment, 3% NaOH solution should be added to the sample, and then heated until just boiling ( 5 min) because NaOH treatment easily destroys pollen grains. Applying the heavy liquid flotation with specific gravity of 1.74-1.76 is useful to isolate relatively pure pollen grains. Sieving with a 20-μm and 63-μm mesh can concentrate pollen grains substantially. The OSL and AMS 14C dating yielded the basal age of the Diaolin section (650 AD). This indicates that the dammed-lake formed around 650 AD, probably caused by the earthquake occurring in the study area in 638 AD. The seismites characterized by soft-sediment deformation and phyllite layer happened at 780-980 AD, probably corresponding to the earthquake occurring on November 20, 952 AD in the study area.
Keates, Susan G; Hodgins, Gregory W L; Kuzmin, Yaroslav V; Orlova, Lyobov A
2007-07-01
Human remains from the Xarusgol Valley, Ordos Plateau, northwestern China, have been considered to date to the Late Pleistocene. In order to ascertain their true age, direct AMS (14)C dating of a femur collected in the early 1920s was conducted. The results demonstrate that the femur is very young, with one sample of 'post-bomb' age and the other sample c. 200 years old. This first direct dating of a Chinese fossil hominid underscores the need to apply the same methodology to other Chinese modern human fossils currently believed to be of Pleistocene age.
Forensic applications of 14C at CIRCE
NASA Astrophysics Data System (ADS)
Marzaioli, F.; Fiumano, V.; Capano, M.; Passariello, I.; Cesare, N. De.; Terrasi, F.
2011-12-01
The decreasing trend of the radiocarbon pulse produced during the atmospheric tests of nuclear weapons (bomb-carbon) coupled with high sensitivity accelerator mass spectrometry (AMS) measurements, drastically increased the precision of radiocarbon age determinations since the second part of the sixties, allowing the application of radiocarbon AMS to a wide range of studies previously not directly involving conventional radiocarbon dating (i.e. food authenticity, forensic, biochemistry). In the framework of authenticity evaluation of artworks, high precision radiocarbon ( 14C) AMS measurements (Δ R/ R < 0.3%) reduce the conventional uncertainty of the dating to few decades, allowing precise age estimation of materials containing carbon (C). The Centre for Isotopic Research on Cultural and Environmental heritage (CIRCE) during its activity on AMS 14C dating achieved high precision measurements opening the opportunity to these kinds of applications. This paper presents the main results obtained from radiocarbon measurements on a set of bone samples analyzed for the determination of the post-mortem interval in the framework of an unsolved case investigated by the Rome prosecutor office. The chronological characterization of the wooden support of the "Acerenza portrait" is also presented with the aim to evaluate its age and to further investigate the possibility to attribute this artwork to Leonardo da Vinci. Bomb- 14C dating on the lipid and collagen fractions of bones allows the evaluation of the year of the death of the individuals by means of ad hoc calibration data sheet with the typical few years precision and difference between collagen apparent age and the year of death appeared in agreement with the age of one individual estimated by dating of tooth collagen. Conventional radiocarbon dating on both wood and wood extracted cellulose leads to an estimation of the portrait wood board age (2σ) of 1459-1524 AD (57% relative probability), 1571-1631 AD interval (42% relative probability).and 1559-1563 AD (1% relative probability). These results attribute with the highest relative probability an age comprised within the life span of Leonardo (1452-1519) to the support.
AMS radiocarbon dating and varve chronology of Lake Soppensee: 6000 to 12000 14C years BP
NASA Astrophysics Data System (ADS)
Hajdas, Irena; Ivy, Susan D.; Beer, Jürg; Bonani, Georges; Imboden, Dieter; Lotted, André F.; Sturm, Michael; Suter, Martin
1993-12-01
For the extension of the radiocarbon calibration curve beyond 10000 14C y BP, laminated sediment from Lake Soppensee (central Switzerland) was dated. The radiocarbon time scale was obtained using accelerator mass spectrometry (AMS) dating of terrestrial macrofossils selected from the Soppensee sediment. Because of an unlaminated sediment section during the Younger Dryas (10000 11000 14C y BP), the absolute time scale, based on counting annual layers (varves), had to be corrected for missing varves. The Soppensee radiocarbon-verve chronology covers the time period from 6000 to 12000 14C y BP on the radiocarbon time scale and 7000 to 13000 calendar y BP on the absolute time scale. The good agreement with the tree ring curve in the interval from 7000 to 11450 cal y BP (cal y indicates calendar year) proves the annual character of the laminations. The ash layer of the Vasset/Killian Tephra (Massif Central, France) is dated at 8230±140 14C y BP and 9407±44 cal y BP. The boundaries of the Younger Dryas biozone are placed at 10986±69 cal y BP (Younger Dryas/Preboreal) and 1212±86 cal y BP (Alleröd/Younger Dryas) on the absolute time scale. The absolute age of the Laacher See Tephra layer, dated with the radiocarbon method at 10 800 to 11200 14C y BP, is estimated at 12350 ± 135 cal y BP. The oldest radiocarbon age of 14190±120 14C y BP was obtained on macrofossils of pioneer vegetation which were found in the lowermost part of the sediment profile. For the late Glacial, the offset between the radiocarbon (10000 12000 14C y BP) and the absolute time scale (11400 13000 cal y BP) in the Soppensee chronology is not greater than 1000 years, which differs from the trend of the U/Th-radiocarbon curve derived from corals.
Correlating the Ancient Maya and Modern European Calendars with High-Precision AMS 14C Dating
Kennett, Douglas J.; Hajdas, Irka; Culleton, Brendan J.; Belmecheri, Soumaya; Martin, Simon; Neff, Hector; Awe, Jaime; Graham, Heather V.; Freeman, Katherine H.; Newsom, Lee; Lentz, David L.; Anselmetti, Flavio S.; Robinson, Mark; Marwan, Norbert; Southon, John; Hodell, David A.; Haug, Gerald H.
2013-01-01
The reasons for the development and collapse of Maya civilization remain controversial and historical events carved on stone monuments throughout this region provide a remarkable source of data about the rise and fall of these complex polities. Use of these records depends on correlating the Maya and European calendars so that they can be compared with climate and environmental datasets. Correlation constants can vary up to 1000 years and remain controversial. We report a series of high-resolution AMS 14C dates on a wooden lintel collected from the Classic Period city of Tikal bearing Maya calendar dates. The radiocarbon dates were calibrated using a Bayesian statistical model and indicate that the dates were carved on the lintel between AD 658-696. This strongly supports the Goodman-Martínez-Thompson (GMT) correlation and the hypothesis that climate change played an important role in the development and demise of this complex civilization. PMID:23579869
A new AMS facility based on a Cockcroft-Walton type 1 MV tandetron at IFIN-HH Magurele, Romania
NASA Astrophysics Data System (ADS)
Stan-Sion, C.; Enachescu, M.; Ghita, D. G.; Calinescu, C. I.; Petre, A.; Mosu, D. V.; Klein, M.
2014-01-01
A 1 MV AMS machine was recently installed in the National Institute for Physics and Nuclear Engineering IFIN-HH, Bucharest Romania. It is the second AMS facility at IFIN-HH having the goal not only to continue but mainly to enlarge the research area of this highly sensitive analyzing method. The multi-element AMS was developed by HVEE to measure 14C, 10Be, and 26Al, and 129I. The results of an acceptance test are presented and demonstrate that this machine is capable of routine 14C age dating and of measurements of other radioisotopes in terms of accuracy and precision as well as a low background level.
Accelerator 14C dates for early upper paleolithic (basal Aurignacian) at El Castillo Cave (Spain)
Valdes, V.C.; Bischoff, J.L.
1989-01-01
Three fragments of charcoal taken from different parts of the lowermost bed containing Aurignacian artifacts at El Castillo Cave yielded AMS dates of 37??7 (?? 1??8) ka bp, 38??5 (?? 1??8) ka bp, and 40??0 (?? 2??1) ka bp (average 38??7 ?? 1??9 ka bp). These dates are almost identical to new AMS dates from l'Arbreda cave in Catalunya on the same cultural horizon (average 38??5 ?? 1??0 ka bp) and are significantly older than the earliest dates for Aurignacian industries in the Aquitaine and in other parts of Central and Western Europe. ?? 1989.
Influence of increasing combustion temperature on the AMS 14C dating of modern crop phytoliths
Yin, Jinhui; Yang, Xue; Zheng, Yonggang
2014-01-01
Several attempts have been made to directly date phytoliths, but most 14C results are not consistent with other independent chronologies. Due to the limited dataset, there is not a clear explanation for these discrepancies. Herein, we report the 14C ages of phytolith-occluded carbon (PhytOC) from contemporary rice and millet crops that were combusted at different temperatures to investigate the relationship between the combustion temperature and resulting 14C age. Our results show that the 14C age of PhytOC increases directly with combustion temperature (up to 1100°C) and results in age overestimations of hundreds of years. Considerably older ages are observed at higher temperatures, suggesting that it may be possible to distinguish between two fractions of organic carbon in phytoliths: labile and recalcitrant carbon. These findings challenge the assumption that PhytOC is homogeneous, an assumption made by those who have previously attempted to directly date phytoliths using 14C. PMID:25288281
Influence of increasing combustion temperature on the AMS 14C dating of modern crop phytoliths.
Yin, Jinhui; Yang, Xue; Zheng, Yonggang
2014-10-07
Several attempts have been made to directly date phytoliths, but most (14)C results are not consistent with other independent chronologies. Due to the limited dataset, there is not a clear explanation for these discrepancies. Herein, we report the (14)C ages of phytolith-occluded carbon (PhytOC) from contemporary rice and millet crops that were combusted at different temperatures to investigate the relationship between the combustion temperature and resulting (14)C age. Our results show that the (14)C age of PhytOC increases directly with combustion temperature (up to 1100°C) and results in age overestimations of hundreds of years. Considerably older ages are observed at higher temperatures, suggesting that it may be possible to distinguish between two fractions of organic carbon in phytoliths: labile and recalcitrant carbon. These findings challenge the assumption that PhytOC is homogeneous, an assumption made by those who have previously attempted to directly date phytoliths using (14)C.
Late quaternary regional geoarchaeology of Southeast Alaska Karst: A progress report
Dixon, E.J.; Heaton, T.H.; Fifield, T.E.; Hamilton, T.D.; Putnam, D.E.; Grady, F.
1997-01-01
Karst systems, sea caves, and rock shelters within the coastal temperate rain forest of Alaska's Alexander Archipelago preserve important records of regional archaeology, sea level history, glacial and climatic history, and vertebrate paleontology. Two 14C AMS dates on human bone discovered in a remote cave (49-PET-408) on Prince of Wales Island document the oldest reliably dated human in Alaska to ca. 9800 B.P. A series of 14C AMS dates from cave deposits span the past 40,000 years and provide the first evidence of Pleistocene faunas from the northwest coast of North America. Other discoveries include sea caves and marine beach deposits elevated above modern sea level, extensive solution caves, and mammalian remains of species previously undocumented within the region. Records of human activity, including cave art, artifacts, and habitation sites may provide new insights into the early human colonization of the Americas. ??1997 John Wiley & Sons, Inc.
Kunioka, Masao
2010-06-01
The biomass carbon ratios of biochemicals related to biomass have been reviewed. Commercial products from biomass were explained. The biomass carbon ratios of biochemical compounds were measured by accelerator mass spectrometry (AMS) based on the (14)C concentration of carbons in the compounds. This measuring method uses the mechanism that biomass carbons include a very low level of (14)C and petroleum carbons do not include (14)C similar to the carbon dating measuring method. It was confirmed that there were some biochemicals synthesized from petroleum-based carbons. This AMS method has a high accuracy with a small standard deviation and can be applied to plastic products.
High-resolution 14C dating of a 25,000-year lake-sediment record from equatorial East Africa
NASA Astrophysics Data System (ADS)
Blaauw, Maarten; van Geel, Bas; Kristen, Iris; Plessen, Birgit; Lyaruu, Anna; Engstrom, Daniel R.; van der Plicht, Johannes; Verschuren, Dirk
2011-10-01
We dated a continuous, ˜22-m long sediment sequence from Lake Challa (Mt. Kilimanjaro area, Kenya/Tanzania) to produce a solid chronological framework for multi-proxy reconstructions of climate and environmental change in equatorial East Africa over the past 25,000 years. The age model is based on a total of 168 AMS 14C dates on bulk-organic matter, combined with a 210Pb chronology for recent sediments and corrected for a variable old-carbon age offset. This offset was estimated by i) pairing bulk-organic 14C dates with either 210Pb-derived time markers or 14C dates on grass charcoal, and ii) wiggle-matching high-density series of bulk-organic 14C dates. Variation in the old-carbon age offset through time is relatively modest, ranging from ˜450 yr during glacial and late glacial time to ˜200 yr during the early and mid-Holocene, and increasing again to ˜250 yr today. The screened and corrected 14C dates were calibrated sequentially, statistically constrained by their stratigraphical order. As a result their constrained calendar-age distributions are much narrower, and the calibrated dates more precise, than if each 14C date had been calibrated on its own. The smooth-spline age-depth model has 95% age uncertainty ranges of ˜50-230 yr during the Holocene and ˜250-550 yr in the glacial section of the record. The δ 13C values of paired bulk-organic and grass-charcoal samples, and additional 14C dating on selected turbidite horizons, indicates that the old-carbon age offset in Lake Challa is caused by a variable contribution of old terrestrial organic matter eroded from soils, and controlled mainly by changes in vegetation cover within the crater basin.
New radiocarbon measurement methods in the Hertelendi Laboratory, Hungary
NASA Astrophysics Data System (ADS)
Janovics, Róbert; Major, István; Rinyu, László; Veres, Mihály; Molnár, Mihály
2013-04-01
In this paper we present two very different and novel methods for C-14 measurement from dissolved inorganic carbonate (DIC) of water samples. A new LSC sample preparation method for liquid scintillation C-14 measurements was implemented in the ATOMKI. The first method uses direct absorption into a special absorbent (Carbosorb E®) and a following liquid scintillation measurement. Typical sample size is 20-40 litre of water. The developed CO2 absorption method is fast, and simple. The C-14 activities is measured by an ultra low background LSC (TRI-CARB 3170 TR/SL, Perkin Elmer) including quenching parameter (tSIE).The corresponding limit of C-14 dating is 31200 year. Several tests were executed with old borehole CO2 gas without significant content of C-14 and also performed on samples of known C-14 activities between 29 and 7000 pMC, previously measured by GPC. The combined uncertainty of the described determination is about 2 % in the case of recent carbon. It is a very cost-effective and easy to use method based on a novel and simple static absorption process for the CO2 extracted from groundwater. The other very sensitive method is based on accelerator mass spectrometry (AMS) using gas ion source. This method does not require graphite generation and a small volume of water sample (1-20mL) is enough for the radiocarbon measurement. The procedure is very similar to pre-treatment of carbonate contained sample preparation for stable isotope measurement with gasbench technique. We applied a MICADAS type accelerator mass spectrometry (AMS) with gas ion source for C-14 analysis. The radiocarbon content of water was sat free with phosphoric acid and then the headspace gas was rinsed vials. The whole measurement needs only 20 min of each sample. The precision of measurement is better than 1% for modern samples. The preparation is vastly reduced compared to the other AMS methods and principally allows fully automated measurements of groundwater samples with an auto-sampler. The presented two new methods can be suitable for C-14 measurements and dating of hydrological, and environmental samples as well. The new AMS facility in ATOMKI (Debrecen, Hungary) using an EnvironMICADAS AMS system with gas ion source has a great potential in groundwater C-14 analyses. The research was supported by the by TÁMOP-4.2.2.A-11/1/KONV and the Hungarian NSF (OTKA MB08-A 81515)
NASA Astrophysics Data System (ADS)
Graham, Russell; Stafford, Thomas, Jr.; Semken, Holmes, Jr.
2010-05-01
Advances in AMS physics and organic geochemistry have revolutionized our ability to establish absolute chronologies on vertebrate fossils. Highly purified collagen, which provides extremely accurate 14C ages, can be extracted from single bones and teeth as small as 50 mg. Combined with measurement precisions of ±15 to 25 years for ages of < 20,000 yr, the direct AMS 14C technique enables fossil deposits to be chronologically dissected at the level of single animals. Analysis of data from a variety of sites in the United States indicates that most excavation levels (analysis units) as small as 10 cm can be time averaged by several thousand years at a minimum, even with the greatest care in excavation and processing of sediments. Time averaging of this magnitude has important implications for fine-scale paleoecological analysis of faunas, especially when compared to high-resolution climate records like those derived from speleothems, ice cores, or marine cores. To this end, we propose saturation dating of indicative taxa and plotting dates of individual specimens against high-resolution climate records rather than analysis of complete faunas or faunules. This technique provides even higher resolution of paleoenvironments than pollen spectra.
NASA Astrophysics Data System (ADS)
Hubbe, Alex; Hubbe, Mark; Karmann, Ivo; Cruz, Francisco W.; Neves, Walter A.
2013-03-01
The extinction of late Quaternary megafauna in South America has been extensively debated in past decades. The majority of the hypotheses explaining this phenomenon argue that the extinction was the result of human activities, environmental changes, or even synergism between the two. Although still limited, a good chronological framework is imperative to discuss the plausibility of the available hypotheses. Here we present six new direct AMS 14C radiocarbon dates from the state of São Paulo (Brazil) to further characterize the chronological distribution of extinct fauna in this part of South America. The new dates make evident that ground sloths, toxodonts, and saber-toothed cats lived in the region around the Pleistocene/Holocene transition, and, in agreement with previous studies, also suggest an early Holocene survival for the ground sloth Catonyx cuvieri. Taken together with local paleoclimatic and archaeological data, the new dates do not support hunting or indirect human activities as a major cause for megafauna extinction. Although more data are required, parsimony suggests that climatic changes played a major role in this extinction event.
Accelerator mass spectrometry.
Hellborg, Ragnar; Skog, Göran
2008-01-01
In this overview the technique of accelerator mass spectrometry (AMS) and its use are described. AMS is a highly sensitive method of counting atoms. It is used to detect very low concentrations of natural isotopic abundances (typically in the range between 10(-12) and 10(-16)) of both radionuclides and stable nuclides. The main advantages of AMS compared to conventional radiometric methods are the use of smaller samples (mg and even sub-mg size) and shorter measuring times (less than 1 hr). The equipment used for AMS is almost exclusively based on the electrostatic tandem accelerator, although some of the newest systems are based on a slightly different principle. Dedicated accelerators as well as older "nuclear physics machines" can be found in the 80 or so AMS laboratories in existence today. The most widely used isotope studied with AMS is 14C. Besides radiocarbon dating this isotope is used in climate studies, biomedicine applications and many other fields. More than 100,000 14C samples are measured per year. Other isotopes studied include 10Be, 26Al, 36Cl, 41Ca, 59Ni, 129I, U, and Pu. Although these measurements are important, the number of samples of these other isotopes measured each year is estimated to be less than 10% of the number of 14C samples. Copyright 2008 Wiley Periodicals, Inc.
Opportunities in low-level radiocarbon microtracing: applications and new technology
Vuong, Le Thuy; Song, Qi; Lee, Hee Joo; Roffel, Ad F; Shin, Seok-Ho; Shin, Young G; Dueker, Stephen R
2016-01-01
14C-radiolabeled (radiocarbon) drug studies are central to defining the disposition of therapeutics in clinical development. Concerns over radiation, however, have dissuaded investigators from conducting these studies as often as their utility may merit. Accelerator mass spectrometry (AMS), originally designed for carbon dating and geochronology, has changed the outlook for in-human radiolabeled testing. The high sensitivity of AMS affords human clinical testing with vastly reduced radiative (microtracing) and chemical exposures (microdosing). Early iterations of AMS were unsuitable for routine biomedical use due to the instruments’ large size and associated per sample costs. The situation is changing with advances in the core and peripheral instrumentation. We review the important milestones in applied AMS research and recent advances in the core technology platform. We also look ahead to an entirely new class of 14C detection systems that use lasers to measure carbon dioxide in small gas cells. PMID:28031933
Mass spectrometry with accelerators.
Litherland, A E; Zhao, X-L; Kieser, W E
2011-01-01
As one in a series of articles on Canadian contributions to mass spectrometry, this review begins with an outline of the history of accelerator mass spectrometry (AMS), noting roles played by researchers at three Canadian AMS laboratories. After a description of the unique features of AMS, three examples, (14)C, (10)Be, and (129)I are given to illustrate the methods. The capabilities of mass spectrometry have been extended by the addition of atomic isobar selection, molecular isobar attenuation, further ion acceleration, followed by ion detection and ion identification at essentially zero dark current or ion flux. This has been accomplished by exploiting the techniques and accelerators of atomic and nuclear physics. In 1939, the first principles of AMS were established using a cyclotron. In 1977 the selection of isobars in the ion source was established when it was shown that the (14)N(-) ion was very unstable, or extremely difficult to create, making a tandem electrostatic accelerator highly suitable for assisting the mass spectrometric measurement of the rare long-lived radioactive isotope (14)C in the environment. This observation, together with the large attenuation of the molecular isobars (13)CH(-) and (12)CH 2(-) during tandem acceleration and the observed very low background contamination from the ion source, was found to facilitate the mass spectrometry of (14)C to at least a level of (14)C/C ~ 6 × 10(-16), the equivalent of a radiocarbon age of 60,000 years. Tandem Accelerator Mass Spectrometry, or AMS, has now made possible the accurate radiocarbon dating of milligram-sized carbon samples by ion counting as well as dating and tracing with many other long-lived radioactive isotopes such as (10)Be, (26)Al, (36)Cl, and (129)I. The difficulty of obtaining large anion currents with low electron affinities and the difficulties of isobar separation, especially for the heavier mass ions, has prompted the use of molecular anions and the search for alternative methods of isobar separation. These techniques are discussed in the latter part of the review. Copyright © 2010 Wiley Periodicals, Inc.
Closed tubes preparation of graphite for high-precision AMS radiocarbon analysis
NASA Astrophysics Data System (ADS)
Hajdas, I.; Michczynska, D.; Bonani, G.; Maurer, M.; Wacker, L.
2009-04-01
Radiocarbon dating is an established tool applied in Geochronology. Technical developments of Accelerator Mass Spectrometry AMS, which allow measurements of samples containing less than 1 mg of carbon, opened opportunities for new applications. Moreover, high resolution records of the past changes require high-resolution chronologies i.e. sampling for 14C dating. In result, the field of applications is rapidly expanding and number of radiocarbon analysis is growing rapidly. Nowadays dedicated 14C AMS machines have great capacity for analysis but in order to keep up with the demand for analysis and provide the results as fast as possible a very efficient way of sample preparation is required. Sample preparation for 14C AMS analysis consists of two steps: separation of relevant carbon from the sample material (removing contamination) and preparation of graphite for AMS analysis. The last step usually involves reaction of CO2 with H2, in the presence of metal catalyst (Fe or Co) of specific mesh size heated to 550-625°C, as originally suggested by Vogel et al. (1984). Various graphitization systems have been built in order to fulfil the requirement of sample quality needed for high-precision radiocarbon data. In the early 90ties another method has been proposed (Vogel 1992) and applied by few laboratories mainly for environmental or biomedical samples. This method uses TiH2 as a source of H2 and can be easily and flexibly applied to produce graphite. Sample of CO2 is frozen in to the tube containing pre-conditioned Zn/TiH2 and Fe catalyst. Torch sealed tubes are then placed in the stepwise heated oven at 500/550°C and left to react for several hours. The greatest problem is the lack of control of the reaction completeness and considerable fractionation. However, recently reported results (Xu et al. 2007) suggest that high precision dating using graphite produced in closed tubes might be possible. We will present results of radiocarbon dating of the set of standards and secondary IAEA standards to demonstrate to what level this method can be used for high precision radiocarbon dating. References Vogel JS. 1992. Rapid Production of Graphite without Contamination for Biomedical Ams. Radiocarbon 34: 344-350. Vogel JS, Southon JR, Nelson DE, and Brown TA. 1984. Performance of Catalytically Condensed Carbon for Use in Accelerator Mass-Spectrometry. Nuclear Instruments & Methods in Physics Research Section B-Beam Interactions with Materials and Atoms 233: 289-293. Xu X, Trumbore SE, Zheng S, Southon JR, McDuffee KE, Luttgen M, and Liu JC. 2007. Modifying a sealed tube zinc reduction method for preparation of AMS graphite targets: Reducing background and attaining high precision. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms Accelerator Mass Spectrometry - Proceedings of the Tenth International Conference on Accelerator Mass Spectrometry 259: 320-329.
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Status report: Implementation of gas measurements at the MAMS 14C AMS facility in Mannheim, Germany
NASA Astrophysics Data System (ADS)
Hoffmann, Helene; Friedrich, Ronny; Kromer, Bernd; Fahrni, Simon
2017-11-01
By implementing a Gas Interface System (GIS), CO2 gas measurements for radiocarbon dating of small environmental samples (<100 μgC) have been established at the MICADAS (Mini Carbon Dating System) AMS instrument in Mannheim, Germany. The system performance has been optimized and tested with respect to stability and ion yield by repeated blank and standard measurements for sample sizes down to 3 μgC. The highest 12C- low-energy (LE) ion currents, typically reaching 8-15 μA, could be achieved for a mixing ratio of 4% CO2 in Helium, resulting in relative counting errors of 1-2% for samples larger than 10 μgC and 3-7% for sample sizes below 10 μgC. The average count rate was ca. 500 counts per microgram C for OxII standard material. The blank is on the order of 35,000-40,000 radiocarbon years, which is comparable to similar systems. The complete setup thus enables reliable dating for most environmental samples (>3 μgC).
Suitability of biogenic carbonate of Lithospermum fruits for 14C dating
NASA Astrophysics Data System (ADS)
Pustovoytov, Konstantin; Riehl, Simone
2006-05-01
Lithospermum (Boraginaceae) belongs to a small group of plant taxa that accumulate biogenic carbonate in their fruits. In this genus, carbonate incrustations form in the cells of the epidermis and sclerenchyma of the pericarp. Fossil Lithospermum fruits (nutlets) with well-preserved calcified tissues commonly occur in Quaternary sediments and cultural layers. We tested the suitability of biogenic carbonate of Lithospermum fruits for radiocarbon dating using a total of 15 AMS measurement results from four modern and 11 fossil samples. The 14C data from modern samples suggest that Lithospermum utilises only atmospheric carbon to synthesise calcite in the nutlets. In general, the ages determined through 14C dating of fossil fruitscorresponded well with the absolute-age intervals for archaeological sites over the last 5000 yr. Biogenic carbonate of Lithospermum fruits, like that of Celtis, represents a new source of chronological information for late Quaternary studies.
Increase of radiocarbon concentration in tree rings from Kujawy (SE Poland) around AD 774-775
NASA Astrophysics Data System (ADS)
Rakowski, Andrzej Z.; Krąpiec, Marek; Huels, Mathias; Pawlyta, Jacek; Dreves, Alexander; Meadows, John
2015-10-01
Evidence of a rapid increase in atmospheric radiocarbon (14C) content in AD 774-775 was presented by Miyake et al. (2012), who observed an increase of about 12‰ in the 14C content in annual tree rings from Japanese cedar. Usoskin et al. (2013) report a similar 14C spike in German oak, and attribute it to exceptional solar activity. If this phenomenon is global in character, such rapid changes in 14C concentration may affect the accuracy of calibrated dates, as the existing calibration curve is composed mainly of decadal samples. Single-year samples of dendro-chronologically dated tree rings of deciduous oak (Quercus robur) from Kujawy, a village near Krakow (SE Poland), spanning the years AD 765-796, were collected and their 14C content was measured using the AMS system in the Leibniz Laboratory. The results clearly show a rapid increase of 9.2 ± 2.1‰ in the 14C concentration in tree rings between AD 774 and AD 775, with maximum Δ14C = 4.1 ± 2.3‰ noted in AD 776.
Tips and traps in the 14C bio-AMS preparation laboratory
NASA Astrophysics Data System (ADS)
Buchholz, Bruce A.; Freeman, Stewart P. H. T.; Haack, Kurt W.; Vogel, John S.
2000-10-01
Maintaining a contamination free sample preparation lab for biological 14C AMS requires the same or more diligence as a radiocarbon dating prep lab. Isotope ratios of materials routinely range over 4-8 orders of magnitude in a single experiment, dosing solutions contain thousands of DPM and gels used to separate proteins possess 14C ratios of 1 amol 14C/mg C. Radiocarbon contamination is a legacy of earlier tracer work in most biological laboratories, even if they were never hot labs. Removable surface contamination can be found and monitored using swipes. Contamination can be found on any surface routinely touched: door knobs, light switches, drawer handles, water faucets. In general, all surfaces routinely touched need to be covered with paper, foil or plastic that can be changed frequently. Shared air supplies can also present problems by distributing hot aerosols throughout a building. Aerosols can be monitored for 14C content using graphitized coal or fullerene soot mixed with metal powder as an absorber. The monitors can be set out in work spaces for 1-2 weeks and measured by AMS with regular samples. Frequent air changes help minimize aerosol contamination in many cases. Cross-contamination of samples can be minimized by using disposable plastic or glassware in the prep lab, isolating samples from the air when possible and using positive displacement pipettors.
NASA Technical Reports Server (NTRS)
Hajdas, Irka; Bonani, Georges; Boden, Per; Peteet, Dorothy M.; Mann, Daniel H.
1999-01-01
High-resolution AMS (accelerator-mass-spectrometer) radiocarbon dating was performed on late-glacial macrofossils in lake sediments from Kodiak Island, Alaska, and on shells in marine sediments from southwest Sweden. In both records, a dramatic drop in radiocarbon ages equivalent to a rise in the atmospheric C-14 by approximately 70%. coincides with the beginning of the cold period at 11000 yr B.P. (C-14 age). Thus our results show that a close correlation between climatic records around the globe is possible by using a global signature of changes in atmospheric C-14 content.
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Optical dating of tsunami-laid sand from an Oregon coastal lake
Ollerhead, J.; Huntley, D.J.; Nelson, A.R.; Kelsey, H.M.
2001-01-01
Optical ages for five samples of tsunami-laid sand from an Oregon coastal lake were determined using an infrared optical-dating method on K-feldspar separates and, as a test of accuracy, compared to ages determined by AMS 14C dating of detrital plant fragments found in the same beds. Two optical ages were about 20% younger than calibrated 14C ages of about 3.1 and 4.3 ka. Correction of the optical ages using measured anomalous fading rates brings them into agreement with the 14C ages. The approach used holds significant promise for improving the accuracy of infrared optical-dating methods. Luminescence data for the other three samples result in optical age limits much greater than the 14C ages. These data provide a textbook demonstration of the correlation between scatter in the luminescence intensity of individual sample aliquots and their normalization values that is expected when the samples contain sand grains not adequately exposed to daylight just prior to or during deposition and burial. Thus, the data for these three samples suggest that the tsunamis eroded young and old sand deposits before dropping the sand in the lake. ?? 2001 Elsevier Science Ltd. All rights reserved.
Determination of radiocarbon reservoir age of Lake Van by mineral magnetic and geochemical analysis
NASA Astrophysics Data System (ADS)
Makaroglu, Ozlem; Namik Cagatay, M.; Pesonen, Lauri J.; Orbay, Naci
2017-04-01
Lake Van is the largest soda lake in the world, located on the east Anatolian Plateau in Turkey. Its varved sediments provide an excellent archive of high-resolution paleoclimate record for the Near East. Varve counting and radiocarbon methods are therefore important dating techniques for investigating the Lake Van sedimentary paleoclimate record. In here we present detailed magnetic and geochemical record of Lake Van. We have studied 4.56 m (core VP0801) and 4.70 m (core VP0807) long cores recovered from 80 m and 65 m water depths located in SE and SW of Lake Van, respectively. Here, we have benefited from magnetic properties with associated remanent magnetization of the sediments from Lake Van to correlate the cores which contain of tephra layers. The cores cover the last 8.4 ka and lithologically include three laminated sedimentary units. From top to the bottom, the units were dated 4.2 ka BP-present, 5.4-4.2 ka BP and older than 5.4 ka BP. We identified tephra layers previously dated by varve counting, and used the varve ages to obtain age models for the cores. We also obtained a total of eight Accelerator Mass Spectrometry (AMS) 14C dates from total organic carbon (TOC) in the two cores, close to the tephra layers. Comparison of the varve ages of the AMS 14C dated samples with their corresponding AMS 14C dates indicates large differences, suggesting significant reservoir ages that range from 2.8 to 2.5 ka for 3.0-2.4 varve ka BP and from 2.8 to 3.3 ka for 8.0-5.9 varve ka BP. The results suggest that the reservoir age of the organic matter increases with the varve age of the sediments. This increase is mainly related to the rate of supply of "dead" carbon from the old carbonate rocks in the watershed of Lake Van, which was relatively higher during 8.4-5.9 ka than during 3.0-2.4 ka BP because of the higher atmospheric precipitation and higher rate of biochemical weathering during the former period.
NASA Astrophysics Data System (ADS)
Vetter, L.; Schreiner, K. M.; Fernandez, A.; Rosenheim, B. E.; Tornqvist, T. E.
2014-12-01
Radiocarbon analyses are a key tool for quantifying the dynamics of carbon cycling and storage in both modern soils and Quaternary paleosols. Frequently, bulk 14C dates of paleosol organic carbon provide ages older than the time of soil burial, and 14C dates of geochemical fractions such as alkali and acid extracts (operationally defined as humic acids) can provide anomalously old ages when compared to coeval plant macrofossil dates. Ramped pyrolysis radiocarbon analysis of sedimentary organic material has been employed as a tool for investigating 14C age spectra in sediments with multiple organic carbon sources. Here we combine ramped pyrolysis 14C analysis and biomarker analysis (lignin-phenols and other cupric oxide products) to provide information on the source and diagenetic state of the paleosol organic carbon. We apply these techniques to immature early Holocene brackish wetland entisols from three sediment cores in southeastern Louisiana, along with overlying basal peats. Surprisingly, we find narrow 14C age spectra across all thermal aliquots from both paleosols and peats. The weighted bulk 14C ages from paleosols and overlying peats are within analytical error, and are comparable to independently analyzed 14C AMS dates from charcoal fragments and other plant macrofossils from each peat bed. Our results suggest high turnover rates of carbon in soils relative to input of exogenous carbon sources. These data raise broader questions about processes within the active soil and during pedogenesis and burial of paleosols that can effectively homogenize radiocarbon content in soils across the thermochemical spectrum. The concurrence of paleosol and peat 14C ages also suggests that, in the absence of peats with identifiable plant macrofossils, ramped pyrolysis 14C analyses of paleosols may be used to provide ages for sea-level indicators.
Argyilan, Erin P.; Forman, Steven L.; Johnston, John W.; Wilcox, Douglas A.
2005-01-01
This study evaluates the accuracy of optically stimulated luminescence to date well-preserved strandline sequences at Manistique/Thompson bay (Lake Michigan), and Tahquamenon and Grand Traverse Bays (Lake Superior) that span the past ∼4500 yr. The single aliquot regeneration (SAR) method is applied to produce absolute ages for littoral and eolian sediments. SAR ages are compared against AMS and conventional 14C ages on swale organics. Modern littoral and eolian sediments yield SAR ages 14C ages on swale organics. Significant variability in 14C ages >2000 cal yr B.P. complicates comparison to SAR ages at all sites. However, a SAR age of 4280 ± 390 yr (UIC913) on ridge77 at Tahquamenon Bay is consistent with regional regression from the high lake level of the Nipissing II phase ca. 4500 cal yr B.P. SAR ages indicate a decrease in ridge formation rate after ∼1500 yr ago, likely reflecting separation of Lake Superior from lakes Huron and Michigan. This study shows that SAR is a credible alternative to 14C methods for dating littoral and eolian landforms in Great Lakes and other coastal strandplains where 14C methods prove problematic.
A new AMS facility in Caserta/Italy
NASA Astrophysics Data System (ADS)
Terrasi, F.; Rogalla, D.; De Cesare, N.; D'Onofrio, A.; Lubritto, C.; Marzaioli, F.; Passariello, I.; Rubino, M.; Sabbarese, C.; Casa, G.; Palmieri, A.; Gialanella, L.; Imbriani, G.; Roca, V.; Romano, M.; Sundquist, M.; Loger, R.
2007-06-01
A new AMS system has been installed at Center for Isotopic Research on Cultural and Environmental Heritage (CIRCE) in Caserta/Italy. It was built by National Electrostatics Corp. Middleton, WI/USA, and arrived at CIRCE in the middle of January 2005; the installation and the acceptance tests were completed at the end of February 2005. At first, the system is intended for Radiocarbon AMS; for future Al and Be AMS only minor upgrades are needed and the magnets are designed to bend heavy isotopes like Uranium. Concerning Radiocarbon AMS, the first measurements of unknown samples, prepared in the internal preparation laboratory, already yielded results of high precision and 14C dating is in full swing.
Cooke, Colin A; Hobbs, William O; Michelutti, Neal; Wolfe, Alexander P
2010-03-15
Lake sediments are frequently used to reconstruct the rate and magnitude of human impacts on the biogeochemical cycle of mercury (Hg). The vast majority of these studies rely on excess (210)Pb inventories in short cores to temporally constrain recent trends in Hg deposition, revealing an approximately 3-fold increase in Hg deposition since preindustrial times. However, the exhaustion of unsupported (210)Pb and the onset of widespread global Hg pollution converge temporally in the late 19th century, raising the possibility that preindustrial Hg fluxes are poorly constrained. Here, we combine (210)Pb and accelerator mass spectrometry (AMS) (14)C dated lake sediment records from arctic and Andean lakes to assess the reliability of (210)Pb-derived chronologies in the estimation of preindustrial Hg fluxes. For all four studied lakes, relying on (210)Pb chronologies results in an overestimate of preindustrial Hg fluxes, because extrapolated basal (210)Pb sedimentation rates are systematically overestimated in comparison to accumulation models that include (14)C dates. In the Andes, the use of (14)C dates is critical toward assessing the full history of Hg pollution, which extends beyond the industrial era. In the Arctic, (14)C dating suggests that Hg deposition may have increased >10-fold since the Industrial Revolution, rather than the commonly quoted 3-fold increase. The incorporation of (14)C dates may therefore be necessary if accurate Hg flux histories are sought from oligotrophic lake sediments.
NASA Astrophysics Data System (ADS)
Yang, S.; Cheng, T.; Liu, W.; Fang, X.
2017-12-01
Loess deposit is widespread in the Chuanxi Plateau, the eastern Tibetan Plateau, which is a critical archive for understanding the aeolian process, the evolution of the westerly and the environment changes on the Plateau. Previous studies have shown its aeolian origin, and mainly transported by wind from the western part of the Tibetan Plateau. However, the aeolian processes of the loess and its environment implications are not well understood mainly due to lack of detailed age controls. We carry out a combined quartz optically stimulated luminescence (OSL) dating and accelerator mass spectrometry radiocarbon dating (AMS 14-C) for the loess deposits in Garzê and Jinchuan. The results indicate that the quartz OSL dating can provide reliable age controls for the loess-paleosol sequences from the Chuanxi Plateau, showing the potential of OSL to date loess in the high altitude region. The results indicate that the OSL ages are in agreement with the observed stratigraphy in the field. The constructed OSL and AMS 14-C chronology of the Garzê loess reveals that the widespread loess in Ganzi Region deposited since the Last Glacial. The dust accumulation is rapid during marine isotope stage (MIS) 3 and 2, and a relative low accumulation rate in the Holocene, which may related with the desertification processes of the inner Tibetan Plateau.
Fernandes, Ricardo; Koudelka, Tomas; Tholey, Andreas; Dreves, Alexander
2017-07-15
AMS-radiocarbon measurements of amino acids can potentially provide more reliable radiocarbon dates than bulk collagen analysis. Nonetheless, the applicability of such an approach is often limited by the low-throughput of existing isolation methods and difficulties in determining the contamination introduced during the separation process. A novel tertiary prep-HPLC amino acid isolation method was developed that relies on the combustion of eluted material without requiring any additional chemical steps. Amino acid separation was carried out using a gradient mix of pure water and phosphoric acid with an acetonitrile step in-between runs to remove hydrophobic molecules from the separation column. The amount of contaminant carbon and its 14 C content were determined from two-point measurements of collagen samples of known 14 C content. The amount of foreign carbon due to the isolation process was estimated at 4±1μg and its 14 C content was 0.43±0.01 F 14 C. Radiocarbon values corrected for carbon contamination have only a minor increase in uncertainties. For Holocene samples, this corresponds to an added uncertainty typically smaller than 10 14 Cyears. The developed method can be added to routine AMS measurements without implying significant operational changes and offers a level of measurement uncertainty that is suitable for many archaeological, ecological, environmental, and biological applications. Copyright © 2017. Published by Elsevier B.V.
Soressi, M; Jones, H L; Rink, W J; Maureille, B; Tillier, A-M
2007-04-01
The Pech-de-l'Azé I skull and mandible are included in the juvenile Neandertal remains from Europe. However, some preserved features in the cranial skeleton seem to distinguish the specimen from other Neandertal children. Unfortunately, the stratigraphic position and dating of this child has never been clear. Our recent work on unpublished archives show that the Pech-de-l'Azé I Neandertal child was discovered at the bottom of layer 6, attributed to the Mousterian of Acheulean tradition type B. These skull and mandible are the first diagnostic human remains (aside from an isolated tooth) attributed to the Mousterian of Acheulian tradition (MTA) type B. Consequently, we confirm that Neandertals were the makers of this Mousterian industry, which is characterized by unusual high frequencies of Upper Paleolithic type tools, elongated blanks and blades. We were able to date the context of the hominid remains by dating layer 6 and the layers above and beneath it using ESR, coupled ESR/(230)Th/(234)U (coupled ESR/U-series), and AMS (14)C. Coupled ESR/U-series results on 16 mammalian teeth constrain the age of the uppermost layer 7 to 41-58ka, and layer 6 to 37-51ka. The wide spread in each age estimate results mainly from uncertainties in the gamma-dose rate. These ages are concordant with AMS (14)C ages of two bones coming from the top of layer 6, which provide dates of about 41.7-43.6ka cal BP. A combination of stratigraphic arguments and dating results for layers 6 and 7 show that the Neandertal child cannot be older than 51ka or younger than 41ka. The lowermost layer 4 is shown to be older than 43ka by the principle of superposition and ESR dating in the immediately overlying layer 5. This study shows that the MTA type B had been manufactured by Neandertals before the arrival of anatomically modern humans in the local region. Additionally, by providing a firm chronological framework for the specific morphometric the features of Pech-de-l'Azé I Neandertal child, this study is a new step toward the understanding of temporal and spatial changes in the ontogenesis of Neandertals in south-western Europe during oxygen isotope stages 5-3.
NASA Astrophysics Data System (ADS)
Subt, C.; Yoon, H.; Yoo, K. C.; Lee, J. I.; Domack, E. W.; Rosenheim, B. E.
2016-02-01
Highly detrital sediments can be difficult to date when the detritus includes material similar to that from which dates are sought. For radiocarbon dating, samples with a high degree of pre-aged detrital carbon contamination necessitate measurement of a very small portion of the sample to remove that contamination from the targeted component, even when using advanced techniques such as Ramped PyrOx (RP) 14C dating. Here we present three case studies of alternative RP approaches, producing accurate and precise chronologies for highly detrital sediments near the Larsen C ice shelf, near the Drygalski Ice Tongue in Ross Sea, and in Lapeyrère Bay, Anvers Island. For sediments where the proportion of organic carbon that was modern at the time of deposition is too small for a traditional AMS analysis after RP treatment, we have developed an innovative multiple RP analyses approach to minimize the cost in precision from using smaller temperature intervals, while maximizing the benefit in accuracy. Resulting sub ice-shelf chronologies show vastly improved dates down-core, significantly younger than the equivalent 14C chronology from the bulk acid insoluble organic (AIO) carbon with increasing ages down-core. By comparison, bulk AIO 14C dates in the study areas are not only older, but are subject to age reversals and nearly constant ages that make sedimentation rates impossible to resolve. Using our new approaches, we can reduce pre-aged carbon contamination in Lapeyrère Bay, and date sediments within layers of siliceous mud and ooze in the Ross Sea, and near the Larsen C ice shelf. Improved accuracy for 14C dates of highly detrital sediments can sometimes require the incorporation of a larger blank correction to account for multiple analyses, decreasing the precision. Application of this method refines ages of hard-to-date sediments, removing limits on what to include in a regional approach to chronicle ice shelf collapse.
77 FR 7182 - Sunshine Act Meeting Notice
Federal Register 2010, 2011, 2012, 2013, 2014
2012-02-10
... INTERNATIONAL TRADE COMMISSION [USITC SE-12-004] Sunshine Act Meeting Notice AGENCY HOLDING THE MEETING: United States International Trade Commission. TIME AND DATE: February 14, 2012 at 11:00 a.m.... 4. Vote in Inv. No. 731-TA-539-C (Third Review) (Uranium from Russia). The Commission is currently...
Evidence for solar cycles in a late Holocene speleothem record from Dongge Cave, China
Duan, Fucai; Wang, Yongjin; Shen, Chuan-Chou; Wang, Yi; Cheng, Hai; Wu, Chung-Che; Hu, Hsun-Ming; Kong, Xinggong; Liu, Dianbing; Zhao, Kan
2014-01-01
The association between solar activity and Asian monsoon (AM) remains unclear. Here we evaluate the possible connection between them based on a precisely-dated, high-resolution speleothem oxygen isotope record from Dongge Cave, southwest China during the past 4.2 thousand years (ka). Without being adjusted chronologically to the solar signal, our record shows a distinct peak-to-peak correlation with cosmogenic nuclide 14C, total solar irradiance (TSI), and sunspot number (SN) at multi-decadal to centennial timescales. Further cross-wavelet analyses between our calcite δ18O and atmospheric 14C show statistically strong coherence at three typical periodicities of ~80, 200 and 340 years, suggesting important roles of solar activities in modulating AM changes at those timescales. Our result has further indicated a better correlation between our calcite δ18O record and atmospheric 14C than between our record and TSI. This better correlation may imply that the Sun–monsoon connection is dominated most likely by cosmic rays and oceanic circulation (both associated to atmospheric 14C), instead of the direct solar heating (TSI). PMID:24894978
BEAMS Lab: Novel approaches to finding a balance between throughput and sensitivity
NASA Astrophysics Data System (ADS)
Liberman, Rosa G.; Skipper, Paul L.; Prakash, Chandra; Shaffer, Christopher L.; Flarakos, Jimmy; Tannenbaum, Steven R.
2007-06-01
Development of 14C AMS has long pursued the twin goals of maximizing both sensitivity and precision in the interest, among others, of optimizing radiocarbon dating. Application of AMS to biomedical research is less constrained with respect to sensitivity requirements, but more demanding of high throughput. This work presents some technical and conceptual developments in sample processing and analytical instrumentation designed to streamline the process of extracting quantitative data from the various types of samples encountered in analytical biochemistry.
1986-02-01
AD-R168 250 INHALATION TOXICOLOGY VI EVALUATION OF THE RELATIVE i/I TOXICITY OF THERMAL D. (U) FEDERAL AVIATION ADMINISTRATION WASHINGTON DC OFFICE...FAA/AM-8613 INHALATION TOXICOLOGY : (0 Office of Aviation Medicine Vi. Evaluation of the Relative Washington, D.C. 20591 Toxicity of Thermal...Government Accession No. 3. Recipient’s Catalog No. /XO/FAA/AM-86/3 /1j, 14 4F d Y_0 4. Title and Subtitle 5. Report Date INHALATION TOXICOLOGY : VI
Vaquero, Manola; Esteban, M.; Allue, E.; Vallverdu, J.; Carbonell, E.; Bischoff, J.L.
2002-01-01
New U-Series and C14 (AMS) dates are provided for the Abric Agut (Capellades, Barcelona, Spain). This site was previously considered to be of Middle Palaeolithic age according to the characteristics of the lithic assemblage. In addition, human teeth were uncovered and attributed to neandertals. However, radiometric dating clearly indicates a Late Pleistocene-Early Holocene age. ?? 2002 Elsevier Science Ltd. All rights reserved.
Minamimoto, Ryogo; Hamabe, Yoshimi; Miyaoka, Teiji; Hara, Takamitsu; Yoshida, Keisuke; Oka, Takashi; Inoue, Tomio
2008-12-01
Phase 0 clinical studies, which are known as microdose trials, are expected to promote drug development and reduce development costs. The accelerator mass spectrometry (AMS) system is expected to play an important role in the microdosing tests, as it is a highly sensitive measurement system that can be used to determine the drug concentrations in these tests. Using the AMS system, we measured the background (14)C-concentration in human blood and evaluated the data for use as a reference in microdose studies that administer (14)C-labeled compounds in humans. Blood samples of five healthy Japanese volunteers (three men, two women, median age 40.4 +/- 9.8 years) were collected around the same time and just prior to when the subjects ate a meal (between 12:00 noon and 2:00 pm). Centrifugal separations of blood that was allowed to clot and the plasma were performed at 503 g for 2 min at 4 degrees C. Background (14)C-concentration for each of the samples was measured using the AMS system. The Institute of Accelerator Analysis, which is the first contract research organization in Japan that is capable of providing AMS analysis services for carbon dating and bioanalysis work, performed the AMS analysis. The mean (14)C-concentration in blood was 1.613 +/- 0.125 dpm/ml (men 1.668 +/- 0.114 dpm/ml, women 1.514 +/- 0.076 dpm/ml), in clots 2.373 +/- 0.087 dpm/ml (men 2.381 +/- 0.101 dpm/ml, women 2.357 +/- 0.060 dpm/ ml), and in plasma 0.648 +/- 0.049 dpm/ml (men 0.647 +/- 0.059 dpm/ml, women 0.649 +/- 0.032 dpm/ml). The coefficient variation (CV) for blood was 7.8% (men 6.9%, women 5.0%), for clots 3.7% (men 4.3%, women 2.5%), and for plasma 7.6% (men 9.1%, women 4.9%). The (14)C-concentrations of the clot and blood were higher than those of plasma. The (14)C-concentrations in the blood and plasma were slightly different between individuals when compared with the values for the clot, although the differences were quite small, with a CV value less than 7.8%. Even though the (14)C-concentration differed only slightly between individuals, (14)C-concentrations of the clot and blood were higher than those of the plasma. Therefore, the variation and difference of the background data for blood and plasma might be of use as a reference for microdosing test evaluations.
77 FR 31032 - National Eye Institute; Notice of Closed Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2012-05-24
... DEPARTMENT OF HEALTH AND HUMAN SERVICES National Institutes of Health National Eye Institute....S.C. App.), notice is hereby given of the National Advisory Eye Council. The meeting will be open to...: National Advisory Eye Council. Date: June 14, 2012. Open: 8:00 a.m. to 3:00 p.m. Agenda: Following opening...
78 FR 66354 - Warm Springs Irrigation District; Notice of Technical Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2013-11-05
... Project No. 13570 b. Date and Time of Meeting: November 14, 2013; 11:00 a.m. Pacific Time (2:00 p.m. Eastern Time). c. Place: Telephone conference call. d. FERC Contact: Kelly Wolcott, [email protected] project. f. Proposed Agenda: 1. Introduction 2. Meeting objectives 3. Plant survey discussion 4. NEPA...
75 FR 75484 - Center for Scientific Review; Notice of Closed Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2010-12-03
... and Skin Sciences. Date: December 13-14, 2010. Time: 9 a.m. to 5 p.m. Agenda: To review and evaluate...: HIV Pathogenesis, Therapy and NeuroAIDS. Date: December 15-16, 2010. Time: 8 a.m. to 5 p.m. Agenda: To...
76 FR 69745 - Center for Scientific Review; Notice of Closed Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2011-11-09
...: Cell Biology. Date: December 8-9, 2011. Time: 8 a.m. to 5:30 p.m. Agenda: To review and evaluate grant..., Program Project: Developmental Pharmacology. Date: December 14-15, 2011. Time: 8 a.m. to 5:30 p.m. Agenda...
NASA Astrophysics Data System (ADS)
Miyaoka, Teiji; Isono, Yoshimi; Setani, Kaoru; Sakai, Kumiko; Yamada, Ichimaro; Sato, Yoshiaki; Gunji, Shinobu; Matsui, Takao
2007-06-01
Institute of Accelerator Analysis Ltd. (IAA) is the first Contract Research Organization in Japan providing Accelerator Mass Spectrometry (AMS) analysis services for carbon dating and bioanalysis works. The 3 MV AMS machines are maintained by validated analysis methods using multiple control compounds. It is confirmed that these AMS systems have reliabilities and sensitivities enough for each objective. The graphitization of samples for bioanalysis is prepared by our own purification lines including the measurement of total carbon content in the sample automatically. In this paper, we present the use of AMS analysis in human mass balance and metabolism profiling studies with IAA 3 MV AMS, comparing results obtained from the same samples with liquid scintillation counting (LSC). Human samples such as plasma, urine and feces were obtained from four healthy volunteers orally administered a 14C-labeled drug Y-700, a novel xanthine oxidase inhibitor, of which radioactivity was about 3 MBq (85 μCi). For AMS measurement, these samples were diluted 100-10,000-fold with pure-water or blank samples. The results indicated that AMS method had a good correlation with LSC method (e.g. plasma: r = 0.998, urine: r = 0.997, feces: r = 0.997), and that the drug recovery in the excreta exceeded 92%. The metabolite profiles of plasma, urine and feces obtained with HPLC-AMS corresponded to radio-HPLC results measured at much higher radioactivity level. These results revealed that AMS analysis at IAA is useful to measure 14C-concentration in bioanalysis studies at very low radioactivity level.
Early procurement of scarlet macaws and the emergence of social complexity in Chaco Canyon, NM.
Watson, Adam S; Plog, Stephen; Culleton, Brendan J; Gilman, Patricia A; LeBlanc, Steven A; Whiteley, Peter M; Claramunt, Santiago; Kennett, Douglas J
2015-07-07
High-precision accelerator mass spectrometer (AMS) (14)C dates of scarlet macaw (Ara macao) skeletal remains provide the first direct evidence from Chaco Canyon in northwestern New Mexico that these Neotropical birds were procured from Mesoamerica by Pueblo people as early as ∼ A.D. 900-975. Chaco was a prominent prehistoric Pueblo center with a dense concentration of multistoried great houses constructed from the 9th through early 12th centuries. At the best known great house of Pueblo Bonito, unusual burial crypts and significant quantities of exotic and symbolically important materials, including scarlet macaws, turquoise, marine shell, and cacao, suggest societal complexity unprecedented elsewhere in the Puebloan world. Scarlet macaws are known markers of social and political status among the Pueblos. New AMS (14)C-dated scarlet macaw remains from Pueblo Bonito demonstrate that these birds were acquired persistently from Mesoamerica between A.D. 900 and 1150. Most of the macaws date before the hypothesized apogeal Chacoan period (A.D. 1040-1110) to which they are commonly attributed. The 10th century acquisition of these birds is consistent with the hypothesis that more formalized status hierarchies developed with significant connections to Mesoamerica before the post-A.D. 1040 architectural florescence in Chaco Canyon.
Early procurement of scarlet macaws and the emergence of social complexity in Chaco Canyon, NM
Watson, Adam S.; Plog, Stephen; Culleton, Brendan J.; Gilman, Patricia A.; LeBlanc, Steven A.; Whiteley, Peter M.; Claramunt, Santiago; Kennett, Douglas J.
2015-01-01
High-precision accelerator mass spectrometer (AMS) 14C dates of scarlet macaw (Ara macao) skeletal remains provide the first direct evidence from Chaco Canyon in northwestern New Mexico that these Neotropical birds were procured from Mesoamerica by Pueblo people as early as ∼A.D. 900–975. Chaco was a prominent prehistoric Pueblo center with a dense concentration of multistoried great houses constructed from the 9th through early 12th centuries. At the best known great house of Pueblo Bonito, unusual burial crypts and significant quantities of exotic and symbolically important materials, including scarlet macaws, turquoise, marine shell, and cacao, suggest societal complexity unprecedented elsewhere in the Puebloan world. Scarlet macaws are known markers of social and political status among the Pueblos. New AMS 14C-dated scarlet macaw remains from Pueblo Bonito demonstrate that these birds were acquired persistently from Mesoamerica between A.D. 900 and 1150. Most of the macaws date before the hypothesized apogeal Chacoan period (A.D. 1040–1110) to which they are commonly attributed. The 10th century acquisition of these birds is consistent with the hypothesis that more formalized status hierarchies developed with significant connections to Mesoamerica before the post-A.D. 1040 architectural florescence in Chaco Canyon. PMID:26100874
Status of the "new" AMS facility in Trondheim
NASA Astrophysics Data System (ADS)
Nadeau, Marie-Josée; Vaernes, Einar; Svarva, Helene Løvstrand; Larsen, Eiliv; Gulliksen, Steinar; Klein, Matthias; Mous, Dirk J. W.
2015-10-01
The Radiocarbon Laboratory of the Norwegian University of Science and Technology (NTNU) in Trondheim has a long history, dating back to the 1950s. Its relatively new AMS facility is based on a 1 MV Tandetron from High Voltage Engineering Europa B.V. that is equipped with a hybrid solid/gas SO-110 ion source, a low energy spectrometer supporting sequential injection, a high energy analysis system consisting of a magnet and an electrostatic deflector, allowing insertion of an absorber foil for isobar suppression, and a two dimensional gas ionisation detector (E and ΔE). The system is at present capable of measuring 10Be, 14C, and 26Al and can be easily modified to measure isotopes of higher masses. Acceptance tests results for 10Be1+, 14C2+, 26Al1+, and 26Al3+ are presented. The laboratory measures only 14C at present and the routine procedures are described. The system has demonstrated a very low background (70,000 14C years BP or 2·10-16 on Alfa Aesar 40795 graphite powder, -200 mesh, 99.9995%) for 14C when charge state 2+ is measured and the interference of Li ions in the detector is minimal. Some ion optical peculiarities of the system are also discussed.
AMS 14C analysis of teeth from archaeological sites showing anomalous esr dating results
NASA Astrophysics Data System (ADS)
Grün, Rainer; Abeyratne, Mohan; Head, John; Tuniz, Claudio; Hedges, Robert E. M.
We have carried out AMS radiocarbon analysis on two groups of samples: the first one gave reasonable ESR age estimates and the second one yielded serious age underestinations. All samples were supposedly older than 35 ka, the oldest being around 160 ka. Two pretreatment techniques were used for radiocarbon dating: acid evolution and thermal release. Heating to 600, 750 and 900°C combined with total de-gassing at these temperatures was chosen to obtain age estimates on the organic fraction, secondary carbonates and original carbonate present in the hydroxyapatite mineral phase, respectively. All radiocarbon results present serious age underestimations. The secondary carbonate fraction gives almost modern results indicating an extremely rapid exchange of this component. Owing to this very rapid carbonate exchange it is not likely that the ESR signals used for dating are associated with the secondary carbonates. One tooth from Tabun with independent age estimates of >150 ka was further investigated by the Oxford AMS laboratory, yielding an age estimate of 1930±100 BP on the residual collagen from dentine and 18,000±160 BP on the carbonate component of the enamel bioapatite. We did not, however, find an explanation of why some samples give serious ESR underestimatioils whilst many others provide reasonable results.
Coldwell, Kate E.; Cutts, Suzanne M.; Ognibene, Ted J.; Henderson, Paul T.; Phillips, Don R.
2008-01-01
Limited sensitivity of existing assays has prevented investigation of whether Adriamycin–DNA adducts are involved in the anti-tumour potential of Adriamycin. Previous detection has achieved a sensitivity of a few Adriamycin–DNA adducts/104 bp DNA, but has required the use of supra-clinical drug concentrations. This work sought to measure Adriamycin–DNA adducts at sub-micromolar doses using accelerator mass spectrometry (AMS), a technique with origins in geochemistry for radiocarbon dating. We have used conditions previously validated (by less sensitive decay counting) to extract [14C]Adriamycin–DNA adducts from cells and adapted the methodology to AMS detection. Here we show the first direct evidence of Adriamycin–DNA adducts at clinically-relevant Adriamycin concentrations. [14C]Adriamycin treatment (25 nM) resulted in 4.4 ± 1.0 adducts/107 bp (∼1300 adducts/cell) in MCF-7 breast cancer cells, representing the best sensitivity and precision reported to date for the covalent binding of Adriamycin to DNA. The exceedingly sensitive nature of AMS has enabled over three orders of magnitude increased sensitivity of Adriamycin–DNA adduct detection and revealed adduct formation within an hour of drug treatment. This method has been shown to be highly reproducible for the measurement of Adriamycin–DNA adducts in tumour cells in culture and can now be applied to the detection of these adducts in human tissues. PMID:18632763
Lowenstern, Jacob B.; Hurwitz, Shaul; McGeehin, John
2016-01-01
To explore the timing of hydrothermal activity at the Upper Geyser Basin (UGB) in Yellowstone National Park, we obtained seven new accelerator mass spectrometry (AMS) radiocarbon 14C ages of carbonaceous material trapped within siliceous sinter. Five samples came from depths of 15–152 cm within the Y-1 well, and two samples were from well Y-7 (depths of 24 cm and 122 cm). These two wells, at Black Sand and Biscuit Basins, respectively, were drilled in 1967 as part of a scientific drilling program by the U.S. Geological Survey (White et al., 1975). Even with samples as small as 15 g, we obtained sufficient carbonaceous material (a mixture of thermophilic mats, pollen, and charcoal) for the 14C analyses. Apparent time of deposition ranged from 3775 ± 25 and 2910 ± 30 14C years BP at the top of the cores to about 8000 years BP at the bottom. The dates are consistent with variable rates of sinter formation at individual sites within the UGB over the Holocene. On a basin-wide scale, though, these and other existing 14C dates hint that hydrothermal activity at the UGB may have been continuous throughout the Holocene.
2010-01-01
Catalytic graphitization for 14C-accelerator mass spectrometry (14C-AMS) produced various forms of elemental carbon. Our high-throughput Zn reduction method (C/Fe = 1:5, 500 °C, 3 h) produced the AMS target of graphite-coated iron powder (GCIP), a mix of nongraphitic carbon and Fe3C. Crystallinity of the AMS targets of GCIP (nongraphitic carbon) was increased to turbostratic carbon by raising the C/Fe ratio from 1:5 to 1:1 and the graphitization temperature from 500 to 585 °C. The AMS target of GCIP containing turbostratic carbon had a large isotopic fractionation and a low AMS ion current. The AMS target of GCIP containing turbostratic carbon also yielded less accurate/precise 14C-AMS measurements because of the lower graphitization yield and lower thermal conductivity that were caused by the higher C/Fe ratio of 1:1. On the other hand, the AMS target of GCIP containing nongraphitic carbon had higher graphitization yield and better thermal conductivity over the AMS target of GCIP containing turbostratic carbon due to optimal surface area provided by the iron powder. Finally, graphitization yield and thermal conductivity were stronger determinants (over graphite crystallinity) for accurate/precise/high-throughput biological, biomedical, and environmental14C-AMS applications such as absorption, distribution, metabolism, elimination (ADME), and physiologically based pharmacokinetics (PBPK) of nutrients, drugs, phytochemicals, and environmental chemicals. PMID:20163100
1982-09-01
Cemmotatioa of Q(C’%4JA S ACH \\)ALU- A,,jJ t b AM A&A (OASA;eIq? ,rTr LaMinated by 3"" &(~n j heked by ’i ’C _____ Date.14-CC 7- ~ I f FE e- - Am S.. I...1979 by flatbed trailer. The District rented the boat lift at the Vermilion Power Boat, Inc. marina to lift and place the dredge in the water (see... Flatbed Trailer A-3 7 Lowering Mud Cat into Water at Marina A-4 8 Dozer at Secondary Borrow Area, Lagoons Beach A-4 9 Six-Inch Diameter Pipe Stockpiled
75 FR 57965 - Center for Scientific Review; Notice of Closed Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2010-09-23
... Emphasis Panel; RFA Panel: Drug Discovery for the Nervous System. Date: October 14-15, 2010. Time: 8 a.m...: Center for Scientific Review Special Emphasis Panel; RFA Panel: Drug Discovery for the Nervous System... Review Special Emphasis Panel; Small Business: Visual Systems. Date: October 28, 2010. Time: 8 a.m. to 6...
NASA Astrophysics Data System (ADS)
Sironić, Andreja; Krajcar Bronić, Ines; Horvatinčić, Nada; Barešić, Jadranka; Obelić, Bogomil; Felja, Igor
2013-01-01
A new line for preparation of the graphite samples for 14C dating by Accelerator Mass Spectrometry (AMS) in the Zagreb Radiocarbon Laboratory has been validated by preparing graphite from various materials distributed within the Fifth International Radiocarbon Intercomparison (VIRI) study. 14C activity of prepared graphite was measured at the SUERC AMS facility. The results are statistically evaluated by means of the z-score and u-score values. The mean z-score value of 28 prepared VIRI samples is (0.06 ± 0.23) showing excellent agreement with the consensus VIRI values. Only one sample resulted in the u-score value above the limit of acceptability (defined for the confidence interval of 99%) and this was probably caused by a random contamination of the graphitization rig. After the rig had been moved to the new adapted and isolated room, all u-score values laid within the acceptable limits. Our LSC results of VIRI intercomparison samples are also presented and they are all accepted according to the u-score values.
Deglacial palaeoclimate at Puerto del Hambre, subantarctic Patagonia, Chile
NASA Astrophysics Data System (ADS)
Heusser, Calvin J.; Heusser, Linda E.; Lowell, Thomas V.; Moreira M., Andrés; Moreira M., Simón
2000-02-01
The primary objective of this study is to further substantiate multistep climatic forcing of late-glacial vegetation in southern South America. A secondary objective is to establish the age of deglaciation in Estrecho de Magallanes-Bahía Inútil. Pollen assemblages at 2-cm intervals in a core of the mire at Puerto del Hambre (53°3621S, 70°5553W) provide the basis for reconstructing the vegetation and a detailed account of palaeoclimate in subantarctic Patagonia. Chronology over the 262-cm length of core is regulated by 20 AMS radiocarbon dates between 14 455 and 10 089 14C yr BP. Of 13 pollen assemblage zones, the earliest representing the Oldest Dryas chronozone (14 455-13 000 14C yr BP) records impoverished steppe with decreasing frequencies and loss of southern beech (Nothofagus). Successive 100-yr-long episodes of grass/herbs and of heath (Empetrum/Ericaceae) before 14 000 14C yr BP infer deglacial successional communities under a climate of increased continentality prior to the establishment of grass-dominated steppe. The Bølling-Allerød (13 000-11 000 14C yr BP) is characterised by mesic grassland under moderating climate that with abrupt change to heath dominance after 12 000 14C yr BP was warmer and not as humid. At the time of the Younger Dryas (11 000-10 000 14C yr BP), grass steppe expanded with a return of colder, more humid climate. Later, with gradual warming, communities were invaded by southern beech. The Puerto del Hambre record parallels multistep, deglacial palaeoclimatic sequences reported elsewhere in the Southern Andes and at Taylor Dome in Antarctica. Deglaciation of Estrecho de Magallanes-Bahía Inútil is dated close to 14 455 14C yr BP, invalidating earlier dates of between 15 800 and 16 590 14C yr BP.
Turteltaub, K W; Felton, J S; Gledhill, B L; Vogel, J S; Southon, J R; Caffee, M W; Finkel, R C; Nelson, D E; Proctor, I D; Davis, J C
1990-01-01
Accelerator mass spectrometry (AMS) is used to determine the amount of carcinogen covalently bound to mouse liver DNA (DNA adduct) following very low-level exposure to a 14C-labeled carcinogen. AMS is a highly sensitive method for counting long-lived but rare cosmogenic isotopes. While AMS is a tool of importance in the earth sciences, it has not been applied in biomedical research. The ability of AMS to assay rare isotope concentrations (10Be, 14C, 26Al, 41Ca, and 129I) in microgram amounts suggests that extension to the biomedical sciences is a natural and potentially powerful application of the technology. In this study, the relationship between exposure to low levels of 2-amino-3,8-dimethyl[2-14C]imidazo[4,5-f]quinoxaline and formation of DNA adducts is examined to establish the dynamic range of the technique and the potential sensitivity for biological measurements, as well as to evaluate the relationship between DNA adducts and low-dose carcinogen exposure. Instrument reproducibility in this study is 2%; sensitivity is 1 adduct per 10(11) nucleotides. Formation of adducts is linearly dependent on dose down to an exposure of 500 ng per kg of body weight. With the present measurements, we demonstrate at least 1 order of magnitude improvement over the best adduct detection sensitivity reported to date and 3-5 orders of magnitude improvement over other methods used for adduct measurement. An additional improvement of 2 orders of magnitude in sensitivity is suggested by preliminary experiments to develop bacterial hosts depleted in radiocarbon. Expanded applications involving human subjects, including clinical applications, are now expected because of the great detection sensitivity and small sample size requirements of AMS. PMID:2371271
78 FR 64026 - Arts Advisory Panel Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2013-10-25
... closed. Dates: November 14, 2013 in Room 714. 9:00 a.m. to 5:00 p.m. Eastern time. Music (application...:00 p.m. Eastern time. Music (application review): This meeting will be closed. Dates: November 19, 2013. 9:00 a.m. to 3:00 p.m. Eastern time in room 714. Music (application review): This meeting will be...
NASA Astrophysics Data System (ADS)
Higginson, M. J.; Altabet, M. A.; Herbert, T. D.
2003-04-01
Despite the availability of high-quality sediment cores in key locations, little paleoclimatic information exists for the Peru margin largely because poor carbonate preservation severely restricts the use of traditional carbonate-based proxies for stratigraphy, dating, and paleo-environmental reconstruction. Many sites also include hiatuses produced by the variable influence of undercurrents on sediment accumulation. To overcome these difficulties, we have developed (in collaboration with T. Eglinton, WHOI) a laboratory facility to successfully extract and purify haptophyte-derived alkenones for compound specific 14C AMS dating (modified from OHKOUCHI et al., 2002). This avoids potential problems with dating bulk organic carbon which we assume, even in an upwelling environment as highly productive as the Peru margin, is not a priori solely of marine origin. In a recently collected, mid-Peru Margin core (ODP Leg 201 Site 1228D), comparison of our alkenone 14C dates with bulk sediment organic carbon dates and known stratigraphic markers produces a very well constrained, curvilinear age-depth relationship for at least the last 14 Kyr. A discrete ash layer at Site 1228D with an adjacent alkenone 14C age of 3890 ± 350 yr, is within error identical to the 14C age of a prominent ash layer (3800 ± 50 yr) found west of the large Peruvian El Misti volcano (16^o18'S, 71^o24'W). In summary, these results show that the Peru margin alkenones are autochthonous (i.e. not from an older, distant source) and provide sufficient dating precision to permit, for the first time, high-resolution paleoceanographic studies in this highly important marine province. Based upon this new chronology, synchronous changes in alkenone-derived SST estimates in two of our independently-dated records are the first to record at high-resolution (a) a large LGM-Holocene SST range in the Tropics (up to 7.8 ^oC during brief events in this upwelling location); and (b) sharp coolings (4 ^oC) consistent with the timing of the Younger Dryas. We presume that the enlarged SST amplitude of these sites comes from the sensitivity of the Peru margin to the dominant upwelling signal and its proximity to the Andes, from which there is evidence for a Younger Dryas response. The appearance of a Bolling-Allerod/Younger Dryas SST reversal consistent with published dates is further verification of our chronostratigraphic methods.
Si-Traceable Scale for Measurements of Radiocarbon Concentration
NASA Astrophysics Data System (ADS)
Hodges, Joseph T.; Fleisher, Adam J.; Liu, Qingnan; Long, David A.
2017-06-01
Radiocarbon (^{14}C) dating of organic materials is based on measuring the ^{14}C/^{12}C atomic fraction relative to the nascent value that existed when the material was formed by photosynthetic conversion of carbon dioxide present in the atmosphere. This field of measurement has numerous applications including source apportionment of anthropogenic and biogenic fuels and combustion emissions, carbon cycle dynamics, archaeology, and forensics. Accelerator mass spectrometry (AMS) is the most widely used method for radiocarbon detection because it can measure extremely small amounts of radiocarbon (background of nominally 1.2 parts-per-trillion) with high relative precision (0.4 %). AMS measurements of radiocarbon are typically calibrated by reference to standard oxalic-acid (C_2H_2O_4) samples of known radiocativity that are derived from plant matter. Specifically, the internationally accepted absolute dating reference for so-called "modern-equivalent" radiocarbon is 95 % of the specific radioactivity in AD 1950 of the National Bureau of Standards (NBS) oxalic acid standard reference material and normalized to δ^{13}C_{VPDB} = 19 per mil. With this definition, a "modern-equivalent" corresponds to 1.176(70) parts-per-trillion of ^{14}C relative to total carbon content. As an alternative radiocarbon scale, we propose an SI-traceable method to determine ^{14}C absolute concentration which is based on linear Beer-Lambert-law absorption measurements of selected ^{14}C^{16}O_2 ν_3-band line areas. This approach is attractive because line intensities of chosen radiocarbon dioxide transitions can be determined by ab initio calculations with relative uncertainties below 0.5 %. This assumption is justified by the excellent agreement between theoretical values of line intensities and measurements for stable isotopologues of CO_2. In the case of cavity ring-down spectroscopy (CRDS) measurements of ^{14}C^{16}O_2 peak areas, we show that absolute, SI-traceable concentrations of radiocarbon can be determined through measurements of time, frequency, pressure and temperature. Notably, this approach will not require knowledge of the radiocarbon half-life and is expected to provide a stable scale that does not require an artifact standard. M. Stuiver and H. A. Polach, Radiocarbon 19, (1977) 355 O. L. Polyansky et al., Phys. Rev. Lett. 114, (2015) 243001
77 FR 32151 - Sunshine Act Meeting; Board of Governors
Federal Register 2010, 2011, 2012, 2013, 2014
2012-05-31
... POSTAL SERVICE Sunshine Act Meeting; Board of Governors DATES AND TIMES: Thursday, June 14, 2012, at 10 a.m. PLACE: Washington, DC, at U.S. Postal Service Headquarters, 475 L'Enfant Plaza SW., in the Benjamin Franklin Room. STATUS: Closed. MATTERS TO BE CONSIDERED: Thursday, June 14, at 10:00 a.m. (Closed...
Federal Register 2010, 2011, 2012, 2013, 2014
2013-09-10
... Diseases and Nutrition. Date: October 22, 2013. Time: 8:00 a.m. to 4:00 p.m. Agenda: To review and evaluate... in Diabetic Ketoacidosis (U34) Date: October 21, 2013. Time: 9:30 a.m. to 11:30 a.m. Agenda: To... Panel; DDK-C Conflicts Date: October 22, 2013. Time: 4:00 p.m. to 6:00 p.m. Agenda: To review and...
[Maples at the sub-Alpine vegetation belt: a long history].
David, F; Barbero, M
2001-02-01
Pollen analysis was carried out on lacustrine sediment of a small hollow (15 m x 25 m) at the treeless sub-Alpine belt (202 m) of the inner Maurienne valley in the northern French Alps. A 2,500-year-long maple settlement was demonstrared. Three AMS dates of terrestrial plant macroremains support the chronology. First, Betula and Salix spread prior to 9,000 C14 BP. The first pollen grains of Acer, Abies and Pinus cembra are quoted at 8,600 C14 BP. High frequencies of Alnus glutinosa/incana (20%) and Acer (10%) show that mixed communities of Acer and Alnus persisted above the mountainous Abies forest between 7,490 and 5,850 C14 BP. After 5,850 C14 BP, the decrease in Acer stands could be attributed to fire as suggested by the strong increase in Betula and by the delayed expansion of Pinus cembra.
40 CFR 63.11514 - Am I subject to this subpart?
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 14 2011-07-01 2011-07-01 false Am I subject to this subpart? 63.11514 Section 63.11514 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS... and Finishing Source Categories Applicability and Compliance Dates § 63.11514 Am I subject to this...
Radiocarbon dating and compositional analysis of pre-Columbian human bones
NASA Astrophysics Data System (ADS)
Andrade, E.; Solís, C.; Canto, C. E.; de Lucio, O. G.; Chavez, E.; Rocha, M. F.; Villanueva, O.; Torreblanca, C. A.
2014-08-01
Analysis of ancient human bones found in "El Cóporo", an archaeological site in Guanajuato, Mexico; were performed using a multi techniques scheme: 14C radiocarbon dating, IBA (Ion Beam Analysis), SEM-EDS (Scanning Electron Microscope Energy Dispersive X-ray Spectroscopy). We measured the elemental composition of the bones, especially some with a superficial black pigmentation. Soil samples collected from the burial place were also analyzed. The 14C dating was performed with a new High Voltage Europe 1 MV Tandentron Accelerator Mass Spectrometer (AMS) recently installed in the IFUNAM (Instituto de Física, Universidad Nacional Autónoma de México). The radiocarbon dating allowed us to determine the date of death of the individual in a period between the year 890 and 975 AD, which is consistent with the late period of the Cóporo civilization. The element sample analysis of bones with the surface black pigmentation show higher levels of Fe, Mn and Ba compared when bone's black surface was mechanically removed. These three elements were found in soil samples from the skeleton burial place. These results indicate more likely that the bone black coloration is due to a postmortem alteration occurring in the burial environment.
NASA Astrophysics Data System (ADS)
Cosentino, Domenico; Öǧretmen, Nazik; Cipollari, Paola; Gliozzi, Elsa; Radeff, Giuditta; Yıldırım, Cengiz; Baykara, Oruc M.; Shen, Chuan-Chou
2016-04-01
Along the Mediterranean coastal area of southern Anatolia, markers of ancient sea-level have been reported west of Alanya and east of the Göksu delta. In both areas, bioconstructed fossil rims, consisting mainly of calcareous algae, are situated 0.5 m above the live counterpart. The fossil rim to the west of Alanya has been dated between 2690 to 1545 yrs BP, evidencing late Holocene rock uplift at the CAP southern margin. More recently, based on beachrocks along the coastal area from Incekum to the south of Adana, authors showed that the shoreline was raised around 0.5 m after 19 BC-200 AD. Based on new field observations along the coast between Aydı ncı k and Ayaş (Mersin, southern Turkey), together with AMS 14C dating and high-resolution U-Th chronology, a more complex uplift history can be suggested. Along the coast of Yeşilovacı k, we observed up to seven uplifted marine notches, from 0.5 m to 6.10 m above sea level. Some of them show relationships with a travertine crust that yielded U-Th ages of 2727 ± 1559 years and 5236 ± 2255 years. In the same area, a calcareous algae fossil trottoir related to a marine notch 5.40 m above sea level yielded an AMS 14C 2σ age of 32700 to 31645 years cal BP. Considering that the global ocean was 60 m below the present sea level at 32 ka, the Yeşilovacı k coastal area has been uplifted at 2 mm/yr. Moving to the east, in a small embayment at Eǧribük, two distinct well cemented beach deposits containing Murex brandaris, Cerithium vulgatum, and Columbella rustica have been uplifted at 0.3 m and 0.7 m above the present sea level. Although it is difficult to reconstruct the paleodepth of those beach deposits, AMS 14C 2σ ages of 5575 to 5445 years cal BP and 2130 to 1965 years cal BP show late Holocene uplift. In the Narlı kuyu area, up to seven different uplifted markers of sea level were observed between 0.8 and 7.2 m above the present sea level. In addition, near Ayaş new insights for late Holocene uplift are from the northern harbour of the ancient Roman town Elaiussa-Sebaste, which now is 4 m above sea level. More evidence for late Holocene uplift of the Elaiussa-Sebaste area come from a Roman pool located in the small peninsula to the east of the northern harbour. There, a fossil shell of Patella cf. aspera, collected 1 m above the highest living Patella, yielded an AMS 14C 2σ age of 850 to 1164 years cal AD. Considering an age of 1000 yrs AD and the level of the Mediterranean sea that was 0.2 m below the present sea level, we can estimate a tectonic uplift rate of 1.2 mm/yr for the last 1000 years. Although the CAP southern margin shows clear evidence of recent uplift, with uplift rates between 2 mm/yr to 1.2 mm/yr, to reconstruct a well-constrained uplift curve for the Holocene more AMS 14C and U-Th dates need to be collected.
78 FR 9743 - Advisory Committee for Environmental Research and Education; Notice of Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2013-02-11
... NSF's Science, Engineering and Education for Sustainability portfolio (SEES) March 14, 2013 Update on... NATIONAL SCIENCE FOUNDATION Advisory Committee for Environmental Research and Education; Notice of... and Education, 9487. Dates: March 13, 2013, 9:00 a.m.-5:00 p.m., and March 14, 2013, 9:00 a.m.-2:00 p...
NASA Astrophysics Data System (ADS)
Suzuki, K.; Yamamoto, M.; Rosenheim, B. E.; Omori, T.; Polyak, L.; Nam, S. I.
2017-12-01
The Arctic Ocean underwent dramatic climate changes in the past. Variations in sea-ice extent and ocean current system in the Arctic cause changes in surface albedo and deep water formation, which have global climatic implications. However, Arctic paleoceanographic studies are lagging behind the other oceans due largely to chronostratigraphic difficulties. One of the reasons for this is a scant presence of material suitable for 14C dating in large areas of the Arctic seafloor. To enable improved age constraints for sediments impoverished in datable material, we apply ramped pyrolysis 14C method (Ramped PyrOx 14C, Rosenheim et al., 2008) to sedimentary records from the Chukchi-Alaska margin recovering Holocene to late-glacial deposits. Samples were divided into five fraction products by gradual heating sedimentary organic carbon from ambient laboratory temperature to 1000°C. The thermographs show a trimodal pattern of organic matter decomposition over temperature, and we consider that CO2 generated at the lowest temperature range was derived from autochthonous organic carbon contemporaneous with sediment deposition, similar to studies in the Antarctic margin and elsewhere. For verification of results, some of the samples treated for ramped pyrolysis 14C were taken from intervals dated earlier by AMS 14C using bivalve mollusks. Ultimately, our results allow a new appraisal of deglacial to Holocene deposition at the Chukchi-Alaska margin with potential to be applied to other regions of the Arctic Ocean.
78 FR 28230 - Center for Scientific Review; Notice of Closed Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2013-05-14
..., Metabolism, Nutrition and Reproductive Sciences Integrated Review Group; Integrative Physiology of Obesity...; Skeletal Muscle and Exercise Physiology Study Section. Date: June 13-14, 2013. Time: 8:00 a.m. to 5:00 p.m... Group; Neurological, Aging and Musculoskeletal Epidemiology Study Section. Date: June 13-14, 2013. Time...
Martínez-Moreno, Jorge; Mora, Rafael; de la Torre, Ignacio
2010-03-01
The excavations carried out in Cova Gran de Santa Linya (Southeastern PrePyrenees, Catalunya, Spain) have unearthed a new archaeological sequence attributable to the Middle Palaeoloithic/Upper Palaeolithic (MP/UP) transition. This article presents data on the stratigraphy, archaeology, and (14)C AMS dates of three Early Upper Palaeolithic and four Late Middle Palaeolithic levels excavated in Cova Gran. All these archaeological levels fall within the 34-32 ka time span, the temporal frame in which major events of Neanderthal extinction took place. The earliest Early Upper Palaeolithic (497D) and the latest Middle Palaeolithic (S1B) levels in Cova Gran are separated by a sterile gap and permit pinpointing the time period in which the Mousterian disappeared from Northeastern Spain. Technological differences between the Early Upper Palaeolithic and Late Middle Palaeolithic industries in Cova Gran support a cultural rupture between the two periods. A series of 12 (14)C AMS dates prompts reflections on the validity of reconstructions based on radiocarbon data. Thus, results from excavations in Cova Gran lead us to discuss the scenarios relating the MP/UP transition in the Iberian Peninsula, a region considered a refuge of late Neanderthal populations. Copyright 2009 Elsevier Ltd. All rights reserved.
77 FR 66193 - Board of Governors; Sunshine Act Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2012-11-02
... POSTAL SERVICE Board of Governors; Sunshine Act Meeting DATES AND TIMES: Wednesday, November 14, 2012, at 10:00 a.m.; Thursday, November 15, at 8:30 a.m. and 10:30 a.m. PLACE: Washington, DC, at U.S. Postal Service Headquarters, 475 L'Enfant Plaza SW., in the Benjamin Franklin Room. STATUS: Wednesday...
Biokinetic and dosimetric investigations of 14C-labeled substances in man using AMS
NASA Astrophysics Data System (ADS)
Mattsson, Sören; Gunnarsson, Mikael; Svegborn, Sigrid Leide; Nosslin, Bertil; Nilsson, Lars-Erik; Thorsson, Ola; Valind, Sven; Åberg, Magnus; Östberg, Henrik; Hellborg, Ragnar; Stenström, Kristina; Erlandsson, Bengt; Faarinen, Mikko; Kiisk, Madis; Magnusson, Carl-Erik; Persson, Per; Skog, Göran
2001-07-01
Up to now, radiation dose estimates from radiopharmaceuticals, labeled with pure β-emitting radionuclides, e.g., 14C or 3H have been very uncertain. Using accelerator mass spectrometry (AMS) we have derived new and improved data for 14C-triolein and 14C-urea and are currently running a program related to the biokinetics and dosimetry of 14C-glycocholic acid and 14C-xylose. The results of our investigations have made it possible to widen the indications for the clinical use of the 14C-urea test for Helicobacter pylori infection in children. The use of ultra-low activities, which is possible with AMS (down to 1/1000 of that used for liquid scintillation counting), has opened the possibility for metabolic investigations on children as well as on other sensitive patient groups like new-borns, and pregnant or breast-feeding women. Using the full potential of AMS, new 14C-labeled drugs could be tested on humans at a much earlier stage than today, avoiding uncertain extrapolations from animal models.
NASA Astrophysics Data System (ADS)
Zhou, W.; Hou, X.; Du, Y.; Kong, X.; Cheng, P.; Zhang, L.; Fan, Y.; Zhang, L.; Niu, Z.; Dong, G.; Chen, N.; Li, M.; Zhu, Y.
2017-12-01
Long-lived radionuclides with half-lives ranging from 103 to 108 years have wide applications in geochronology and environmental tracer studies. A wide range of climatic, geologic, and environmental records preserved in diverse natural archives can be characterized by measuring their concentrations, using accelerator mass spectrometry (AMS). Relying on the operation of the Xi'an 3 MV multi-element AMS since 2006, multi-radionuclides such as 14C, 10Be, 26Al, and 129I have been widely used for the above studies. Here some representative works on the four radionuclides can be briefly summarized as (1) we have successfully obtained temporal and spatial distribution of fossil fuel CO2 in certain cities in China by analyzing Δ14C from atmospheric CO2 and one year growth plants respectively, providing direct scientific data for government's emission cutting policy; (2) we have mathematically disentangled geomagnetic field and precipitation signals in Chinese loess 10Be, and firstly confirmed that the timing of Brunhes-Matuyama (B/M) reversal in loess was synchronous with that of marine sediments; (3) we have explored the paired in situ 10Be and 26Al double dating methodology for exposure dating, which has been successfully applied in fluvial terraces investigations in Tibet and glacial evolution tracing in East Antarctica; and (4) we have evaluated the radiation risk after Fukushima nuclear accident based on the 129I observation. All the above mentioned progress has opened up the new directions in AMS applications and we hope to show more new results in the near future.
Index of FAA Office of Aviation Medicine Reports: 1961-1991
1992-01-01
82174.- DOT/FAA/AM-92/1 Index of FAA Office of Aviation Medicine Reports: Office of Aviation Medicine Washington, D.C. 20591 1961 through 1991 AD-A245...Subtitle j5. Report Date January 1992 INDEX TO FAA OFFICE OF AVIATION MEDICINE REPORTS: 6 Performing Organizoaton Code 1961 THROUGH 1991 __I B...Covered 12. Sponsoring Agency Name and Address Office of Aviation Medicine Federal Aviation Administration 800 Idependence Avenue, S.W. 14. Sponsoring
New evidence for the occurrence of Eurasian lynx (Lynx lynx) in medieval Britain
NASA Astrophysics Data System (ADS)
Hetherington, David A.; Lord, Tom C.; Jacobi, Roger M.
2006-01-01
The presence of Eurasian lynx as a former native species in Britain during the Holocene is known from bones recovered from several sites. AMS radiocarbon dating of lynx bone recovered from two sites in the Craven area of northern England gave 1842 +/- 35 14C yr BP and 1550 +/- 24 14C yr BP, together representing the youngest dates for lynx from England, and in the case of the latter, the youngest for Britain as a whole. These dates support the view that the game animal whose occurrence in the nearby Lake District is described in the early 7th century Cumbric text Pais Dinogad, and whose translation to date has been problematic, is a lynx. The occurrence of lynx in early medieval Britain shows that earlier periods of climate change, previously blamed for the species' extinction in Britain, were not responsible. Instead, anthropogenic factors such as severe deforestation, declining deer populations, and persecution, are likely to have caused the extirpation of lynx in Britain. Consequently, the lynx qualifies as a candidate for reintroduction. Large-scale reafforestation, the growth of deer populations, and more positive attitudes towards carnivores in modern society, could permit the restoration of lynx to Britain, particularly in Scotland.
A new procedure for extraction of collagen from modern and archaeological bones for 14C dating.
Maspero, F; Sala, S; Fedi, M E; Martini, M; Papagni, A
2011-10-01
Bones are potentially the best age indicators in a stratigraphic study, because they are closely related to the layer in which they are found. Collagen is the most suitable fraction and is the material normally used in radiocarbon dating. Bone contaminants can strongly alter the carbon isotopic fraction values of the samples, so chemical pretreatment for (14)C dating by accelerator mass spectrometry (AMS) is essential. The most widespread method for collagen extraction is based on the Longin procedure, which consists in HCl demineralization to dissolve the inorganic phase of the samples, followed by dissolution of collagen in a weak acid solution. In this work the possible side effects of this procedure on a modern bone are presented; the extracted collagen was analyzed by ATR-IR spectroscopy. An alternative procedure, based on use of HF instead of HCl, to minimize unwanted degradation of the organic fraction, is also given. A study by ATR-IR spectroscopic analysis of collagen collected after different demineralization times and with different acid volumes, and a study of an archaeological sample, are also presented.
Holocene Paleohydrology of the tropical andes from lake records
DOE Office of Scientific and Technical Information (OSTI.GOV)
Abbott, M. B., LLNL
Two century-scale time series in northern Bolivia constrain the ages of abrupt changes in the physical, geochemical, and biological characteristics of sediments obtained from lakes that formed during deglaciation from the late Pleistocene glacial maximum. The watersheds of Laguna Viscachani (16{degrees}12`S, 68{degrees}07`W, 3780m) and Lago Taypi Chaka Kkota (16{degrees}13`S, 68{degrees}21`W, 4300m), located on the eastern and western slopes of the Cordillera Real, respectively, contain small cirque glaciers. A high-resolution chronology of the lake sediments is provided by 23 AMS {sup 14}C dates of discrete macro-fossils. Late Pleistocene glaciers retreated rapidly, exposing the lake basins between 10,700 and 9700 {sup 14}Cmore » yr B.P. The sedimentary facies suggest that after 8900 {sup 14}C B.P. glaciers were absent from the watersheds and remained so during the middle Holocene. An increase in the precipitation-evaporation balance is indicated above unconformities dated to about 2300 {sup 14}C yr B.P. in both Lago Taypi Chaka Kkota and Laguna Viscachani. An abrupt increase in sediment accumulation rated after 1400 {sup 14}C yr B.P. signals the onset of Neoglaciation. A possible link exists between the observed millennial-scale shifts in the regional precipitation- evaporation balance and seasonal shifts in tropical insolation.« less
Calculation of the compounded uncertainty of 14C AMS measurements
NASA Astrophysics Data System (ADS)
Nadeau, Marie-Josée; Grootes, Pieter M.
2013-01-01
The correct method to calculate conventional 14C ages from the carbon isotopic ratios was summarised 35 years ago by Stuiver and Polach (1977) and is now accepted as the only method to calculate 14C ages. There is, however, no consensus regarding the treatment of AMS data, mainly of the uncertainty of the final result. The estimation and treatment of machine background, process blank, and/or in situ contamination is not uniform between laboratories, leading to differences in 14C results, mainly for older ages. As Donahue (1987) and Currie (1994), among others, mentioned, some laboratories find it important to use the scatter of several measurements as uncertainty while others prefer to use Poisson statistics. The contribution of the scatter of the standards, machine background, process blank, and in situ contamination to the uncertainty of the final 14C result is also treated in different ways. In the early years of AMS, several laboratories found it important to describe their calculation process in details. In recent years, this practise has declined. We present an overview of the calculation process for 14C AMS measurements looking at calculation practises published from the beginning of AMS until present.
76 FR 58285 - Center for Scientific Review Notice of Closed Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2011-09-20
... Integrated Review Group; Synapses, Cytoskeleton and Trafficking Study Section. Date: October 13-14, 2011... Neurodegeneration Study Section. Date: October 13-14, 2011. Time: 8:30 a.m. to 4 p.m. Agenda: To review and evaluate....306, Comparative Medicine; 93.333, Clinical Research, 93.306, 93.333, 93.337, 93.393-93.396, 93.837-93...
75 FR 55593 - Center for Scientific Review; Notice of Closed Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2010-09-13
... Behavioral Processes Integrated Review Group; Motor Function, Speech and Rehabilitation Study Section. Date... and Imaging Technologies Study Section. Date: October 7-8, 2010. Time: 8:30 a.m. to 5 p.m. Agenda: To... Review Group; Drug Discovery and Mechanisms of Antimicrobial Resistance Study Section. Date: October 14...
Evidence from Central Mexico Supporting the Younger Dryas Extraterrestrial Impact Hypothesis
2012-03-05
identified glassy spherules, CSps, high- temperature melt- rocks , shocked quartz, and a YDB black mat analogue in the Venezuelan Andes. Those authors...debate, we have examined a diverse assemblage of YDB markers at Lake Cuitzeo using a more comprehensive array of analytical techniques than in previous...accelerator mass spectroscopy (AMS) 14C dates on bulk sediment and used in a linear interpolation with the YD onset identified at approximately 2.8 m. To
75 FR 11187 - Center for Scientific Review; Notice of Closed Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2010-03-10
... for Scientific Review Special Emphasis Panel; Epidemiology of Diseases of Aging. Date: March 31, 2010... Conflicts: Cell Biology. Date: April 13-14, 2010. Time: 8 a.m. to 5 p.m. Agenda: To review and evaluate...
76 FR 35228 - Center for Scientific Review; Notice of Closed Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2011-06-16
... Review Special Emphasis Panel, Small Business: Cancer Diagnostics and Treatments (CDT). Date: July 14-15... Musculoskeletal, Oral, and Skin Systems. Date: July 15, 2011. Time: 8 a.m. to 5 p.m. Agenda: To review and...
Holocene evolution of Apalachicola Bay, Florida
Osterman, L.E.; Twichell, D.C.; Poore, R.Z.
2009-01-01
A program of geophysical mapping and vibracoring was conducted to better understand the geologic evolution of Apalachicola Bay. Analyses of the geophysical data and sediment cores along with age control provided by 34 AMS 14C dates on marine shells and wood reveal the following history. As sea level rose in the early Holocene, fluvial deposits filled the Apalachicola River paleochannel, which extended southward under the central part of the bay and seaward across the continental shelf. Sediments to either side of the paleochannel contain abundant wood fragments, with dates documenting that those areas were forested at 8,000 14C years b.p. As sea level continued to rise, spits formed of headland prodelta deposits. Between ???6,400 and ???2,500 14C years b.p., an Apalachicola prodelta prograded and receded several times across the inner shelf that underlies the western part of the bay. An eastern deltaic lobe was active for a shorter time, between ???5,800 and 5,100 14C years b.p. Estuarine benthic foraminiferal assemblages occurred in the western bay as early as 6,400 14C years b.p., and indicate that there was some physical barrier to open-ocean circulation and shelf species established by that time. It is considered that shoals formed in the region of the present barrier islands as the rising sea flooded an interstream divide. Estuarine conditions were established very early in the post-glacial flooding of the bay. ?? 2009 US Government.
NASA Astrophysics Data System (ADS)
Lien, W. Y.; Li, H. C.; Mii, H. S.
2017-12-01
Paleoclimate reconstructions help us to understand the role of the East Asian Summer Monsoon (EASM) on local precipitation and controlling factor of EASM variability, and to improve our climatic prediction. This study presents two stalagmite records from Jinlun Cave (23.553oN, 108.265oE) and Yilingyan Cave (23.041oN, 108.297oE) which are only 60 km apart in Guangxi Province, China. The 35-cm long stalagmite JL12 from Jinlun Cave and 10-cm long stalagmite YLY12 from Yilingyan Cave reveal 1500-year and 2000-year continuous growth respectively based on AMS 14C dating. Data points of the AMS 14C dates with the least dead carbon fraction (DCF) are used to build up the age model. Although dead carbons influence the 14C dating results, it is a feasible dating method for the stalagmites as 230Th/U dating on both stalagmites was not successful due to low U contents. A total of 1586 samples from JL12 and 948 samples from YLY12 have been done for stable isotopes analyses to serve as paleoclimate proxies. Comparison of the d18O records with the local rainfall records and the dry-wetness historic records shows the stalagmite d18O records as a rainfall proxy. The JL12 d18O record resembles the YLY12 d18O record in general, though some differences exist, which confirms the d18O records representing the local climate. The relatively lighter (lower) d18O values of the JL12 and YLY12 records during the Medieval Warm Period (MWP, AD900-1200) indicate stronger EASM. In the first phase of Little Ice Age (LIA), from AD1300 to AD1560, the d18O fluctuate drastically and the average during this period was lower, while the d18O was higher in the second phase of Little Ice Age (AD1560-AD1760), exhibiting a drier and stable climate in the second phase. Furthermore, the DCF varies through the stalagmite records, ascending during the LIA, descending during the MWP, which informs dry condition during the LIA and a moist climate in the MWP. Spectral analysis of the high-resolution d18O records reveal decadal variability of the local climates and the EASM influence.
The dynamics of folic acid metabolism in an adult given a small tracer dose of 14C-folic acid.
Clifford, A J; Arjomand, A; Dueker, S R; Schneider, P D; Buchholz, B A; Vogel, J S
1998-01-01
Folate is an essential nutrient that is involved in many metabolic pathways, including amino acid interconversions and nucleotide (DNA) synthesis. In genetically susceptible individuals and populations, dysfunction of folate metabolism is associated with severe illness. Despite the importance of folate, major gaps exist in our quantitative understanding of folate metabolism in humans. The gaps exist because folate metabolism is complex, a suitable animal model that mimics human folate metabolism has not been identified, and suitable experimental protocols for in vivo studies in humans are not developed. In general, previous studies of folate metabolism have used large doses of high specific activity tritium and 14C-labeled folates in clinical patients. While stable isotopes such as deuterium and 13C-labeled folate are viewed as ethical alternatives to radiolabeled folates for studying metabolism, the lack of sensitive mass spectrometry methods to quantify them has impeded advancement of the field using this approach. In this chapter, we describe a new approach that uses a major analytical breakthrough, Accelerator Mass Spectrometry (AMS). Because AMS can detect attomole concentrations of 14C, small radioactive dosages (nCi) can be safely administered to humans and traced over long periods of time. The needed dosages are sufficiently small that the total radiation exposure is only a fraction of the natural annual background radiation of Americans, and the generated laboratory waste may legally be classified non-radioactive in many cases. The availability of AMS has permitted the longest (202 d) and most detailed study to date of folate metabolism in a healthy adult human volunteer. Here we demonstrate the feasibility of our approach and illustrate its potential by determining empirical kinetic values of folate metabolism. Our data indicate that the mean sojourn time for folate is in the range of 93 to 120 d. It took > or = 350 d for the absorbed portion of small bolus dose of 14C-folic acid to be eliminated completely from the body.
New residence times of the Holocene reworked shells on the west coast of Bohai Bay, China
NASA Astrophysics Data System (ADS)
Shang, Zhiwen; Wang, Fu; Li, Jianfen; Marshall, William A.; Chen, Yongsheng; Jiang, Xingyu; Tian, Lizhu; Wang, Hong
2016-01-01
Shelly cheniers and shell-rich beds found intercalated in near-shore marine muds and sandy sediments can be used to indicate the location of ancient shorelines, and help to estimate the height of sea level. However, dating the deposition of material within cheniers and shell-rich beds is not straightforward because much of this material is transported and re-worked, creating an unknown temporal off-set, i.e., the residence time, between the death of a shell and its subsequent entombment. To quantify the residence time during the Holocene on a section of the northern Chinese coastline a total 47 shelly subsamples were taken from 17 discrete layers identified on the west coast of Bohai Bay. This material was AMS 14C dated and the calibrated ages were systematically compared. The subsamples were categorized by type as articulated and disarticulated bivalves, gastropod shells, and undifferentiated shell-hash. It was found that within most individual layers the calibrated ages of the subsamples got younger relative to the amount of apparent post-mortem re-working the material had been subject to. For examples, the 14C ages of the bivalve samples trended younger in this order: shell-hash → split shells → articulated shells. We propose that the younger subsample age determined within an individual layer will be the closest to the actual depositional age of the material dated. Using this approach at four Holocene sites we find residence times which range from 100 to 1260 cal yrs, with two average values of 600 cal yrs for the original 14C dates older than 1 ka cal BP and 100 cal yrs for the original 14C dates younger than 1 ka cal BP, respectively. Using this semi-empirical estimation of the shell residence times we have refined the existing chronology of the Holocene chenier ridges on the west coast of Bohai Bay.
78 FR 28244 - Arts Advisory Panel Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2013-05-14
.... Dates: June 12, 2013; 2:00 p.m. to 4:00 p.m. EDT. Music (application review): Room 714. This meeting... closed. Dates: June 14, 2013; 9:00 a.m. to 5:00 p.m. EDT. Music (application review): Room 714. This...
75 FR 51082 - Center for Scientific Review; Notice of Closed Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2010-08-18
...: Muscle Biology. Date: September 8, 2010. Time: 11 a.m. to 3 p.m. Agenda: To review and evaluate grant...: Technology Development for High-Throughput Structural Biology Research Review. Date: September 14-15, 2010...: Biology of Development and Aging Integrated Review Group; Development--1 Study Section. Date: September 30...
75 FR 49501 - Center for Scientific Review; Notice of Closed Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2010-08-13
...: Cell Biology. Date: September 1-2, 2010. Time: 8 a.m. to 5 p.m. Agenda: To review and evaluate grant...: Musculoskeletal Regeneration. Date: September 14, 2010. Time: 2 p.m. to 5 p.m. Agenda: To review and evaluate...
Recent advances in biomedical applications of accelerator mass spectrometry.
Hah, Sang Soo; Henderson, Paul T; Turteltaub, Kenneth W
2009-06-17
The use of radioisotopes has a long history in biomedical science, and the technique of accelerator mass spectrometry (AMS), an extremely sensitive nuclear physics technique for detection of very low-abundant, stable and long-lived isotopes, has now revolutionized high-sensitivity isotope detection in biomedical research, because it allows the direct determination of the amount of isotope in a sample rather than measuring its decay, and thus the quantitative analysis of the fate of the radiolabeled probes under the given conditions. Since AMS was first used in the early 90's for the analysis of biological samples containing enriched 14C for toxicology and cancer research, the biomedical applications of AMS to date range from in vitro to in vivo studies, including the studies of 1) toxicant and drug metabolism, 2) neuroscience, 3) pharmacokinetics, and 4) nutrition and metabolism of endogenous molecules such as vitamins. In addition, a new drug development concept that relies on the ultrasensitivity of AMS, known as human microdosing, is being used to obtain early human metabolism information of candidate drugs. These various aspects of AMS are reviewed and a perspective on future applications of AMS to biomedical research is provided.
Recent advances in biomedical applications of accelerator mass spectrometry
Hah, Sang Soo
2009-01-01
The use of radioisotopes has a long history in biomedical science, and the technique of accelerator mass spectrometry (AMS), an extremely sensitive nuclear physics technique for detection of very low-abundant, stable and long-lived isotopes, has now revolutionized high-sensitivity isotope detection in biomedical research, because it allows the direct determination of the amount of isotope in a sample rather than measuring its decay, and thus the quantitative analysis of the fate of the radiolabeled probes under the given conditions. Since AMS was first used in the early 90's for the analysis of biological samples containing enriched 14C for toxicology and cancer research, the biomedical applications of AMS to date range from in vitro to in vivo studies, including the studies of 1) toxicant and drug metabolism, 2) neuroscience, 3) pharmacokinetics, and 4) nutrition and metabolism of endogenous molecules such as vitamins. In addition, a new drug development concept that relies on the ultrasensitivity of AMS, known as human microdosing, is being used to obtain early human metabolism information of candidate drugs. These various aspects of AMS are reviewed and a perspective on future applications of AMS to biomedical research is provided. PMID:19534792
76 FR 27641 - Sunshine Act Notice
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2011-05-12
.... ACTION: Notice of Virtual Public Forum for EAC Standards Board. DATE AND TIME: Tuesday, May 31, 2011, 10 a.m. EDT through Tuesday, June 14, 2011, 10 a.m. EDT. PLACE: EAC Standards Board Virtual Public Forum at http://www.eac.gov/virtual_public_forum.aspx . Once at the main page of EAC's Web site, viewers...
78 FR 13384 - Advisory Committee for International Science and Engineering; Notice of Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2013-02-27
... NATIONAL SCIENCE FOUNDATION Advisory Committee for International Science and Engineering; Notice... Science and Engineering (25104). Date/Time: March 14, 2013 9:30 a.m.-5:00 p.m. March 15, 2013 8:30 a.m.-12... of International Science and Engineering, National Science Foundation, 4201 Wilson Blvd., Arlington...
Holocene History of the Chocó Rain Forest from Laguna Piusbi, Southern Pacific Lowlands of Colombia
NASA Astrophysics Data System (ADS)
Behling, Hermann; Hooghiemstra, Henry; Negret, Alvaro José
1998-11-01
A high-resolution pollen record from a 5-m-long sediment core from the closed-lake basin Laguna Piusbi in the southern Colombian Pacific lowlands of Chocó, dated by 11 AMS 14C dates that range from ca. 7670 to 220 14C yr B.P., represents the first Holocene record from the Chocó rain forest area. The interval between 7600 and 6100 14C yr B.P. (500-265 cm), composed of sandy clays that accumulated during the initial phase of lake formation, is almost barren of pollen. Fungal spores and the presence of herbs and disturbance taxa suggest the basin was at least temporarily inundated and the vegetation was open. The closed lake basin might have formed during an earthquake, probably about 4400 14C yr B.P. From the interval of about 6000 14C yr B.P. onwards, 200 different pollen and spore types were identified in the core, illustrating a diverse floristic composition of the local rain forest. Main taxa are Moraceae/Urticaceae, Cecropia,Melastomataceae/Combretaceae, Acalypha, Alchornea,Fabaceae, Mimosa, Piper, Protium, Sloanea, Euterpe/Geonoma, Socratea,and Wettinia.Little change took place during that time interval. Compared to the pollen records from the rain forests of the Colombian Amazon basin and adjacent savannas, the Chocó rain forest ecosystem has been very stable during the late Holocene. Paleoindians probably lived there at least since 3460 14C yr B.P. Evidence of agricultural activity, shown by cultivation of Zea maissurrounding the lake, spans the last 1710 yr. Past and present very moist climate and little human influence are important factors in maintaining the stable ecosystem and high biodiversity of the Chocó rain forest.
AMS studies of the long-term turnover of 14C-labelled fat in man
NASA Astrophysics Data System (ADS)
Gunnarsson, M.; Mattsson, S.; Stenström, K.; Leide-Svegborn, S.; Erlandsson, B.; Faarinen, M.; Hellborg, R.; Kiisk, M.; Nilsson, L.-E.; Nosslin, B.; Persson, P.; Skog, G.; Åberg, M.
2000-10-01
To estimate the biokinetics of 14C-labelled fatty acids and the associated radiation absorbed dose to man, long-term retention of 14C from oral intake of glycerol tri[1- 14C]oleate (triolein) has been studied using accelerator mass spectrometry (AMS). As a complement to earlier reported data for three individuals, we present here results for one person from measurements up to 4.6 yr after administration, now also including 14C-levels in fat, muscle and bone. In this subject, a total of 44% of the administered activity was recovered in the exhaled air. Fasting increased the exhalation of 14C. The "excess" 14CO2 due to fasting had a half-life of about 400 d. AMS measurements on fat, muscle and bone biopsies taken from the same subject 4.5 yr after ingestion indicated that a small fraction of the administered activity was still present in fat. Also, bone tissue had a higher 14C specific activity than the current environmental level. No significantly increased level was found in the muscle sample.
NASA Astrophysics Data System (ADS)
Davies, L. J.; Froese, D. G.; Appleby, P.; van Bellen, S.; Magnan, G.; Mullan-Boudreau, G.; Noernberg, T.; Shotyk, W.; Zaccone, C.
2016-12-01
Age modelling of recent peat profiles is frequently undertaken for high-resolution modern studies, but the most common techniques applied (e.g. 14C, 210Pb, cryptotephra) are rarely combined and used for testing and inter-comparison. Here, we integrate three age-dating approaches to produce a single age model to comprehensively investigate variations in the chronometers and individual site histories since 1900. OxCal's P_Sequence function is used to model dates produced using 14C (pre- and post-bomb), 210Pb (corroborated with 137Cs and 241Am) from six peat bogs in central and northern Alberta. Physical and chemical characteristics of the cores (e.g. macrofossils, humification, ash content, dry density) provide important constraints for the model by highlighting periods with significant changes in accumulation rate (e.g. fire events, permafrost development, prolonged surficial drying). Sub-cm resolution output shows there are consistent differences in how the 14C and 210Pb signals are preserved in peat profiles, with 14C commonly showing a slight bias toward older ages at the same depth relative to 210Pb data. These methods can successfully be combined in a Bayesian model and used to produce a single age model that more accurately accounts for the uncertainties inherent in each method. Understanding these differences and combining the results of these methods results in a stronger chronology at each site investigated here despite observed differences in ecological setting, accumulation rates, fire events/frequency and permafrost development.
NASA Astrophysics Data System (ADS)
Li, Z. Y.; Chen, M. T.; Shi, X.; Liu, S.; Wang, H.
2015-12-01
Zi-Ye Li a, Min-Te Chen b, Hou-Jie Wang a, Sheng-Fa Liu c, Xue-Fa Shi ca College of Marine Geosciences, Ocean University of China, Qingdao 266100, P.R. Chinab Institute of Applied Geosciences, National Taiwan Ocean University, Keelung, Taiwan 20224, ROCc First Institute of Oceanography, SOA, Qingdao 266100, P.R. China Indonesian throughflow (ITF) is one of the most important currents responsible for transporting heat and moisture from the western Pacific to the Indian Oceans. The ITF is also well-known as effectively in modulating the global climate change with the interactions among ENSO and Asian monsoons. Here we present an AMS 14C dating controlled sea surface temperature (SST) record from core SO184-10043 (07°18.57'S, 105°03.53'E), which was retrieved from 2171m water depth at a north-south depression located at the southeastern offshore area of Sumatera in the eastern Indian Ocean. Based on our high-resolution SST using Mg/Ca analyses based on planktonic foraminifera shells of Globigerinoides ruber and alkenone index, U k'37-SST, oxygen isotope stratigraphy, and AMC 14C age-controls, our records show that, during the past 32,000 years, the SSTs were decreased which imply weaker ITF during Marine Isotope Stage (MIS) 2 and 3. The weaker UTF may respond to strengthened northeast monsoon during the boreal winter. During 21 to 15ka, the southeast monsoon had been stronger and the northeast monsoon was relatively weaker. During 15 to 8ka, rapid sea level rising may allow the opening of the gateways in the Makassar Strait and Lombok Strait that may have further strengthened the ITF. During the early Holocene, the northeast and southeast monsoons seem to be both strengthened. We will discuss the implications of the hydrographic variability and their age uncertainties in this paper during the meeting.
NASA Astrophysics Data System (ADS)
Toyoguchi, Teiko; Kobayashi, Takeshi; Konno, Noboru; Shiraishi, Tadashi; Kato, Kazuhiro; Tokanai, Fuyuki
2015-10-01
Accelerator mass spectrometry (AMS) is expected to play an important role in microdose trials. In this study, we measured the 14C concentration in 14C-oxaliplatin-spiked serum, urine and supernatant of fecal homogenate samples in our Yamagata University (YU) - AMS system. The calibration curves of 14C concentration in serum, urine and supernatant of fecal homogenate were linear (the correlation coefficients were ⩾0.9893), and the precision and accuracy was within the acceptance criteria. To examine a 14C content of water in three vacuum blood collection tubes and a syringe were measured. 14C was not detected from water in these devices. The mean 14C content in urine samples of 6 healthy Japanese volunteers was 0.144 dpm/mL, and the intra-day fluctuation of 14C content in urine from a volunteer was little. The antineoplastic agents are administered to the patients in combination. Then, 14C contents of the antineoplastic agents were quantitated. 14C contents were different among 10 antineoplastic agents; 14C contents of paclitaxel injection and docetaxel hydrate injection were higher than those of the other injections. These results indicate that our quantitation method using YU-AMS system is suited for microdosing studies and that measurement of baseline and co-administered drugs might be necessary for the studies in low concentrations.
Correlation of PET and AMS analyses for early kinetics of 2-fluoro-2-deoxyglucose (FDG)
NASA Astrophysics Data System (ADS)
Minamimoto, Ryogo; Hamabe, Yoshimi; Miyaoka, Teiji; Theeraladanon, Chumpol; Oka, Takashi; Matsui, Takao; Inoue, Tomio
2010-04-01
The draft of the guidelines for microdosing in clinical trials was published in Japan in 2008 following the guidelines of the European Medicines Agency (EMEA) and the Food and Drug Administration (FDA). It recommends utilizing accelerator mass spectrometry (AMS), liquid chromatography/mass spectrometry (LC/MS/MS), and positron emission tomography (PET) for monitoring drug metabolites in preclinical studies. In this study, we clarified the correlation in measuring result between PET and AMS. The AMS measurement was undergone by using AMS system of Institute of Accelerator Analysis Ltd. (IAA, Kawasaki, Japan). First the back ground 14C level of blood in mice was measured by AMS. Second, we clarified the relationship between AMS and PET by using 2-fluoro-2-deoxyglucose (FDG). The correlation coefficient ( r) of the measurements using PET ( 18F-FDG) and AMS ( 14C-FDG) were quite high at 0.97 ( Y = 7.54 E - 05 X + 0.02, p < 0.001). The blood clearance profile of 18F-FDG was nearly identical with that of 14C-FDG. These results indicate that the AMS analysis has excellent correlation with the PET method.
76 FR 31618 - National Center on Minority Health and Health Disparities; Notice of Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2011-06-01
... Health and Health Disparities; Notice of Meeting Pursuant to section 10(d) of the Federal Advisory... Council on Minority Health and Health Disparities. The meeting will be open to the public as indicated... on Minority Health and Health Disparities. Date: June 14, 2011. Closed: 8 a.m. to 9:30 a.m. Agenda...
75 FR 53975 - National Center on Minority Health and Health Disparities; Notice of Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2010-09-02
... Health and Health Disparities; Notice of Meeting Pursuant to section 10(a) of the Federal Advisory... Council on Minority Health and Health Disparities. The meeting will be open to the public as indicated... on Minority Health and Health Disparities. Date: September 14, 2010. Closed: 8 a.m. to 9:30 a.m...
76 FR 12136 - Advisory Committee for Geosciences; Notice of Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2011-03-04
... NATIONAL SCIENCE FOUNDATION Advisory Committee for Geosciences; Notice of Meeting In accordance with the Federal Advisory Committee Act (Pub. L. 92- 463, as amended), the National Science Foundation announces the following meeting: Name: Advisory Committee for Geosciences (1755). Dates: April 13, 2011; 8:30 a.m.- 5 p.m., April 14, 2011; 8:30 a.m...
77 FR 31624 - Advisory Commission on Childhood Vaccines; Notice of Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2012-05-29
... Commission on Childhood Vaccines; Notice of Meeting In accordance with section 10(a)(2) of the Federal... Commission on Childhood Vaccines (ACCV). Date and Time: June 14, 2012, 8:30 a.m. to 11:45 a.m. EDT. Place... will include, but are not limited to: updates from the Division of Vaccine Injury Compensation (DVIC...
77 FR 6826 - Advisory Committee for Environmental Research and Education; Notice of Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2012-02-09
... Thursday, March 15, 2012 Update on NSF's Science, Engineering and Education for Sustainability portfolio... NATIONAL SCIENCE FOUNDATION Advisory Committee for Environmental Research and Education; Notice of... and Education (9487). Dates: March 14, 2012, 8:30 a.m.- 5 p.m.; March 15, 2012, 8:30 a.m.-2 p.m. Place...
78 FR 74175 - Meetings of Humanities Panel
Federal Register 2010, 2011, 2012, 2013, 2014
2013-12-10
... Library of Congress, 101 Independence Avenue SE., Washington, DC 20540- 4860. FOR FURTHER INFORMATION... Research Programs. 2. Date: January 14, 2014 Time: 8:30 a.m. to 5:00 p.m. This meeting will discuss applications for the Klug Fellowships grant program, submitted to the division of Research Programs. 3. Date...
77 FR 14043 - Government in the Sunshine Act Meeting Notice
Federal Register 2010, 2011, 2012, 2013, 2014
2012-03-08
... UNITED STATES INTERNATIONAL TRADE COMMISSION [USITC SE-12-005] Government in the Sunshine Act Meeting Notice AGENCY: Agency Holding the Meeting: United States International Trade Commission. DATES: Time and Date: March 14, 2012 at 11 a.m. Place: Room 101, 500 E Street SW., Washington, DC 20436...
1979-09-28
DAAosrt O14.NE VRO1 H__IH_1_________1_______1 1~~hN EIl 1___________ dsknind.o ~~~importance aCCA .Is %1* NU%3E OF REODE D RATA OBTAINED FROM...9~44r £LM2 ae1s ~ Am 424~~del 4e A ~-~. f3 N w ~ Ail 2~ZV41/- t-.. c4 fz d/1,C4t let e -~4Z tz 4L~ fl~4k*1 Wed 4 4-’V 4~bf6144a- 6d>zi.i Z a~ r
NASA Astrophysics Data System (ADS)
Salenbien, W.; Baker, P. A.; Fritz, S. C.; Guedron, S.
2014-12-01
Lake Titicaca is one of the most important archives of paleoclimate in tropical South America, and prior studies have elucidated patterns of climate variation at varied temporal scales over the past 0.5 Ma. Yet, slow sediment accumulation rates in the main deeper basin of the lake have precluded analysis of the lake's most recent history at high resolution. To obtain a paleoclimate record of the last few millennia at multi-decadal resolution, we obtained five short cores, ranging from 139 to 181 cm in length, from the shallower Wiñaymarka sub-basin of of Lake Titicaca, where sedimentation rates are higher than in the lake's main basin. Selected cores have been analyzed for their geochemical signature by scanning XRF, diatom stratigraphy, sedimentology, and for 14C age dating. A total of 72 samples were 14C-dated using a Gas Ion Source automated high-throughput method for carbonate samples (mainly Littoridina sp. and Taphius montanus gastropod shells) at NOSAMS (Woods Hole Oceanographic Institute) with an analytical precision higher than 2%. The method has lower analytical precision compared with traditional AMS radiocarbon dating, but the lower cost enables analysis of a larger number of samples, and the error associated with the lower precision is relatively small for younger samples (< ~8,000 years). A 172-cm-long core was divided into centimeter long sections, and 47 14C dates were obtained from 1-cm intervals, averaging one date every 3-4 cm. The other cores were radiocarbon dated with a sparser sampling density that focused on visual unconformities and shell beds. The high-resolution radiocarbon analysis reveals complex sedimentation patterns in visually continuous sections, with abundant indicators of bioturbated or reworked sediments and periods of very rapid sediment accumulation. These features are not evident in the sparser sampling strategy but have significant implications for reconstructing past lake level and paleoclimatic history.
Cvetković, B Z; Salazar, G; Kunz, D; Szidat, S; Wieland, E
2018-06-25
The combination of ion chromatography (IC) with accelerator mass spectrometry (AMS) was developed to determine the speciation of 14C-(radiocarbon) bearing organic compounds in the femto to pico molar concentration range. The development of this compound-specific radiocarbon analysis (CSRA) of carboxylic acids is reported and the application of the method on a leaching solution from neutron-irradiated steel is demonstrated. The background and the dynamic range of the AMS-based method were quantified. On using 14C-labelled standards, the measurements demonstrate the repeatability of the analytical method and the reproducible recovery of the main target carboxylic acids (i.e., acetate, formate, malonate, and oxalate). The detection limit was determined to be in the mid fmol 14C per L level while the dynamic range of the analytical method covers three orders of magnitude from the low fmol to the mid pmol 14C per L level. Cross contamination was found to be negligible during IC fractionation and was accounted for during eluate processing and 14C detection by AMS. The 14C-bearing carboxylates released from an irradiated steel nut into an alkaline leaching solution were analysed using the CSRA-based analytical method with the aim to check the applicability of the approach and develop appropriate sample preparation. The concentrations of 14C-bearing formate and acetate, the main organic corrosion products, were at a low pmol 14C per L level for convenient dimensions of the alkaline leaching experiment which demonstrates that compound-specific 14C AMS is an extremely sensitive analytical method for analysing 14C-bearing compounds. The content of total organic 14C in solution (TO14C) determined by the direct measurement of an aliquot of the leaching solution agrees well with the sum of the 14C concentrations of the individual carboxylates within the uncertainty of the data. Furthermore, the TO14C content is in good agreement with the calculated value using the corrosion rate determined from the 60Co release and the 14C inventory of the irradiated steel specimen.
López-Ráez, Juan A; Fernández, Iván; García, Juan M; Berrio, Estefanía; Bonfante, Paola; Walter, Michael H; Pozo, María J
2015-01-01
Apocarotenoids are a class of compounds that play important roles in nature. In recent years, a prominent role for these compounds in arbuscular mycorrhizal (AM) symbiosis has been shown. They are derived from carotenoids by the action of the carotenoid cleavage dioxygenase (CCD) enzyme family. In the present study, using tomato as a model, the spatio-temporal expression pattern of the CCD genes during AM symbiosis establishment and functioning was investigated. In addition, the levels of the apocarotenoids strigolactones (SLs), C13 α-ionol and C14 mycorradicin (C13/C14) derivatives were analyzed. The results suggest an increase in SLs promoted by the presence of the AM fungus at the early stages of the interaction, which correlated with an induction of the SL biosynthesis gene SlCCD7. At later stages, induction of SlCCD7 and SlCCD1 expression in arbusculated cells promoted the production of C13/C14 apocarotenoid derivatives. We show here that the biosynthesis of apocarotenoids during AM symbiosis is finely regulated throughout the entire process at the gene expression level, and that CCD7 constitutes a key player in this regulation. Once the symbiosis is established, apocarotenoid flux would be turned towards the production of C13/C14 derivatives, thus reducing SL biosynthesis and maintaining a functional symbiosis. Copyright © 2014 Elsevier Ireland Ltd. All rights reserved.
77 FR 61019 - Aquatic Nuisance Species Task Force Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2012-10-05
..., Cost Center: FF09F14000, Fund: 134] Aquatic Nuisance Species Task Force Meeting AGENCY: Fish and... Aquatic Nuisance Species (ANS) Task Force. The ANS Task Force's purpose is to develop and implement a.... DATES: The ANS Task Force will meet from 8:30 a.m. to 5:00 p.m. Wednesday November 14, and from 8:30 a.m...
76 FR 31642 - Committee on Equal Opportunities in Science and Engineering; Notice of Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2011-06-01
... NATIONAL SCIENCE FOUNDATION Committee on Equal Opportunities in Science and Engineering; Notice of... Engineering (1173). Dates/Time: June 13, 2011, 9 a.m.-4:30 p.m. June 14, 2011, 9 a.m.-2 p.m. Places: June 13... participation in science and engineering. Agenda Monday, June 13, 2011 Opening Statement by the CEOSE Chair...
76 FR 11699 - Notice of Retrospective Review of DOT Existing Regulations
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2011-03-03
... any digital presentation materials--March 10, 2011. Public Meeting--March 14, 2011--9:30 a.m.-4:30 p.m... should notify Jennifer Abdul-Wali at the address above by March 7, 2011; any digital presentation... name, title, country of citizenship, date of birth, passport number, and passport expiration date when...
Xiong, Xiaohu; Zhou, Weijian; Cheng, Peng; Wu, Shugang; Niu, Zhenchuan; Du, Hua; Lu, Xuefeng; Fu, Yunchong; Burr, George S
2017-04-01
Radiocarbon ( 14 C) has been widely used for quantification of fossil fuel CO 2 (CO 2ff ) in the atmosphere and for ecosystem source partitioning studies. The strength of the technique lies in the intrinsic differences between the 14 C signature of fossil fuels and other sources. In past studies, the 14 C content of CO 2 derived from plants has been equated with the 14 C content of the atmosphere. Carbon isotopic fractionation mechanisms vary among plants however, and experimental study on fractionation associated with dark respiration is lacking. Here we present accelerator mass spectrometry (AMS) radiocarbon results of CO 2 respired from 21 plants using a lab-incubation method and associated bulk organic matter. From the respired CO 2 we determine Δ 14 C res values, and from the bulk organic matter we determine Δ 14 C bom values. A significant difference between Δ 14 C res and Δ 14 C bom (P < 0.01) was observed for all investigated plants, ranging from -42.3‰ to 10.1‰. The results show that Δ 14 C res values are in agreement with mean atmospheric Δ 14 CO 2 for several days leading up to the sampling date, but are significantly different from corresponding bulk organic Δ 14 C values. We find that although dark respiration is unlikely to significantly influence the estimation of CO 2ff , an additional bias associated with the respiration rate during a plant's growth period should be considered when using Δ 14 C in plants to quantify atmospheric CO 2ff . Copyright © 2017 Elsevier Ltd. All rights reserved.
Applications of AMS {sup 14}C on Climate and Archaeology
DOE Office of Scientific and Technical Information (OSTI.GOV)
Gomes, P. R. S.
2007-10-26
We describe the Accelerator Mass Spectrometry (AMS) technique and two distinct applications of its use with {sup 14}C to study environmental problems in Brazil, such as forest fires and climate changes in the Amazon region and archaeological studies on the early settlements in the Southeast Brazilian coast.
NASA Astrophysics Data System (ADS)
Lougheed, Bryan; Metcalfe, Brett; Wacker, Lukas
2017-04-01
Marine sediment cores used in palaeoceanography form the basis of our current understanding of past global climate and ocean chemistry. Precision and accuracy of geochronological control in these sediment cores are crucial in unravelling the timing of rapid shifts in palaeoclimate and, ultimately, the interdependency of global climate mechanisms and their causality. Aware of the problems associated with bioturbation (the mixing of ocean sediments by benthic organisms) palaeoceanographers generally aim to retrieve sediment cores from locations with high sediment accumulation rates, thus minimising the influence of bioturbation as much as possible. However, the practice of concentrating only on areas of the ocean floor with high sedimentation accumulation rates has the potential to introduce a geographical bias into our understanding of global palaeoclimate. For example, global time averaged sediment accumulation rates for the ocean floor (excluding continental margins) indicate that vast areas of the ocean floor have sediment accumulation rates less than the recommended minimum advised sediment accumulation rates of 10 cm/ka or greater. Whilst many studies have focussed on quantifying the impact of bioturbation on our understanding of the past, few have attempted to overcome the problems associated with bioturbation. Recent pioneering developments in 14C AMS at the Laboratory of Ion Beam Physics at ETH Zürich have led to the development of the Mini Carbon Dating System (MICADAS). This compact 14C AMS system can be coupled to a carbonate handling system, thus enabling the direct AMS measurement of gaseous samples, i.e. without graphitisation, allowing for the analysis of carbonate samples of <100 μg. Likewise, while earlier isotope ratio mass spectrometry (IRMS) technology required a minimum of 100 μg of carbonate to produce a successful δ18O measurement, more recent advances in IRMS technology have made routine measurements of as little as 5 μg possible. Combining both analytical techniques enables palaeoclimate reconstructions that are independent of depth. Here, we present work on a low sedimentation core ( 2 cm/ka) core in the North Atlantic (core T86-10P, 37° 8.13' N, 29° 59.15' W) on single shells of the benthic species of foraminifera, Cibicidoides wuellerstorfi. Preliminary downcore single specimen 14C data display a large scatter in 14C ages for the various discrete 1 cm depth intervals analysed. In the case of depth intervals where three or more single specimens have been analysed, we find that the standard deviation in 14C age varies between 1210 and 9437 14C yr, with the mean variation for all such discrete depths being 3384 14C yr.
D'Amore, G; Pacciani, E; Frederic, P; Caramella Crespi, V
2007-01-01
The present study describes human skeletal remains from Riparo della Rossa, a rock shelter in the Marche region (Central Italy). The remains consist of a cranial vault and a few non-articulated postcranial bones, possibly belonging to the same adult individual. As the cranial vault showed some morphological features that are unusual for a modern human (marked prominence of the supraorbital region, very prominent nasal bones and rather high thickness of the vault), an accurate anthropological analysis and quantification of the antiquity of the bones were required. The remains were dated with two different absolute dating methods, AMS (14)C and (235)U-(231)Pa non-destructive gamma-ray spectrometry (NDGRS), which produced discordant results: the uncalibrated (14)C dating produced 5690 +/- 80 BP for the cranial vault and 6110 +/- 80 BP for the clavicle; the NDGRS dating produced 10,000 +/- 3000 BP for the cranial vault. The sex discriminant morphological characters on the skull are not unequivocal, though the masculine ones appear more evident. The aims of the present paper are: to provide a morphological and metric description of the remains; to interpret their unusual morphological features; to attempt to attribute them to male or female sex and to one of the possible prehistoric cultural groups, according to dating results (Upper Palaeolithic, Mesolithic or Neolithic). The attribution was obtained by a Bayesian procedure taking into account the reliability of the combined information of morphological/metric features and absolute dating results. The results suggest that the Riparo della Rossa remains are best attributed to a male individual of the Neolithic age.
76 FR 8788 - Sunshine Federal Register Notice
Federal Register 2010, 2011, 2012, 2013, 2014
2011-02-15
... MEETINGS: Nuclear Regulatory Commission. DATE: Weeks of February 14, 21, 28, March 7, 14, 21, 2011. PLACE..., 2011--Tentative Thursday, February 24, 2011 9 a.m. Briefing on Groundwater Task Force (Public Meeting... be Webcast live at the Web address-- http://www.nrc.gov . Week of March 7, 2011--Tentative There are...
Development of a nanofiltration method for bone collagen 14C AMS dating
NASA Astrophysics Data System (ADS)
Boudin, Mathieu; Boeckx, Pascal; Buekenhoudt, Anita; Vandenabeele, Peter; Van Strydonck, Mark
2013-01-01
Radiocarbon dating of bones is usually performed on the collagen fraction. However, this collagen can contain exogenous molecules, including humic substances (HSs) and/or other soil components that may have a different age than the bone. Incomplete removal can result in biased 14C dates. Ultrafiltration of collagen, dissolved as gelatin (molecular weight (MW) ∼100,000 Dalton), has received considerable attention to obtain more reliable dates. Ultrafiltration is an effective method of removal of low-molecular weight contaminants from bone collagen but it does not remove high-molecular weight contaminants, such as cross-linked humic collagen complexes. However, comparative dating studies have raised the question whether this cleaning step itself may introduce contamination with carbon from the filters used. In this study, a nanofiltration method was developed using a ceramic filter to avoid a possible extraneous carbon contamination introduced by the filter. This method should be applicable to various protein materials e.g. collagen, silk, wool, leather and should be able to remove low-molecular and high molecular weight HSs. In this study bone collagen was hot acid hydrolyzed to amino acids and nanofiltrated. A filter with a molecular weight cutoff (MWCO) of 450 Dalton was chosen in order to collect the amino acids in the permeate and the HSs in the retentate. Two pilot studies were set up. Two nanofiltration types were tested in pilot study 1: dead end and cross flow filtration. Humic substance (HS)-solutions with fossil carbon and modern hydrolyzed collagen contaminated with HSs were filtrated and analyzed with spectrofluorescence to determine the HS removal. Cross flow nanofiltration showed the most efficient HS removal. A second pilot study based upon these results was set up wherein only cross flow filtration was performed. 14C measurements of the permeates of hydrolyzed modern collagen contaminated with fossil HSs demonstrate a significant but incomplete removal of HSs (between 63% and 85%).
Summary of NDE of Additive Manufacturing Efforts in NASA
NASA Technical Reports Server (NTRS)
Waller, Jess; Saulsberry, Regor; Parker, Bradford; Hodges, Kenneth; Burke, Eric; Taminger, Karen
2014-01-01
(1) General Rationale for Additive Manufacturing (AM): (a) Operate under a 'design-to-constraint' paradigm, make parts too complicated to fabricate otherwise, (b) Reduce weight by 20 percent with monolithic parts, (c) Reduce waste (green manufacturing), (e) Eliminate reliance on Original Equipment Manufacturers for critical spares, and (f) Extend life of in-service parts by innovative repair methods; (2) NASA OSMA NDE of AM State-of-the-Discipline Report; (3) Overview of NASA AM Efforts at Various Centers: (a) Analytical Tools, (b) Ground-Based Fabrication (c) Space-Based Fabrication; and (d) Center Activity Summaries; (4) Overview of NASA NDE data to date on AM parts; and (5) Gap Analysis/Recommendations for NDE of AM.
78 FR 66074 - Sunshine Act Meetings: November 2013
Federal Register 2010, 2011, 2012, 2013, 2014
2013-11-04
... NATIONAL LABOR RELATIONS BOARD Sunshine Act Meetings: November 2013 TIME AND DATES: All meetings....'' See also 5 U.S.C. 552b(c)(10). CONTACT PERSON FOR MORE INFORMATION: Dated: October 31, 2013. William B. Cowen, Solicitor. [FR Doc. 2013-26408 Filed 10-31-13; 11:15 am] BILLING CODE 7545-01-P ...
75 FR 53317 - Center for Scientific Review; Notice of Closed Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2010-08-31
... Genetics Integrated Review Group, Prokaryotic Cell and Molecular Biology Study Section. Date: October 7... Committee: Genes, Genomes, and Genetics Integrated Review Group, Molecular Genetics C Study Section. Date... Translational Integrated Review Group, Cancer Genetics Study Section. Date: October 7-8, 2010. Time: 8 a.m. to 5...
NASA Astrophysics Data System (ADS)
Schillereff, Daniel; Chiverrell, Richard; Macdonald, Neil; Hooke, Janet; Welsh, Katharine; Piliposyan, Gayane; Appleby, Peter
2014-05-01
Lake sediment records are often a useful tool for investigating landscape evolution as geomorphic changes in the catchment are reflected by altered sediment properties in the material transported through the watershed and deposited at the lake bed. Recent research at Brotherswater, an upland waterbody in the Lake District, northwest England, has focused on reconstructing historical floods from their sedimentary signatures and calculating long-term sediment and carbon budgets from fourteen sediment cores extracted from across the basin. Developing accurate chronological control is essential for these tasks. One sediment core (BW11-2; 3.5 m length) from the central basin has been dated using artificial radionuclide measurements (210Pb, 137Cs, 241Am) for the uppermost sediments and radiocarbon (14C) for lower sediments. The core appears to span the past 1500 years, however a number of problems have arisen. We present our explanations for these errors, the independent chronological techniques used to generate an accurate age-depth model for this core and methods for its transferral to the other 13 cores extracted from the basin. Two distinct 137Cs markers, corresponding to the 1986 Chernobyl disaster and 1960s weapons testing, confirm the 210Pb profile for sediment deposition since ~1950, but calculations prior to this appear erroneous, possibly due to a hiatus in the sediment record. We used high-resolution geochemical profiles (measured by XRF) to cross-correlate with a second 210Pb-dated chronology from a more distal location, which returned more sensible results. Unfortunately, the longer 14C sequence exhibits two age-reversals (radiocarbon dates that are too old). We believe the uppermost two dates are erroneous, due to a shift in inflow location as a flood prevention method ~1900 A.D., dated using information from historical maps. The lower age-reversal coincides with greater supply of terrigenous material to the lake (increased Zr, K, Ti concentrations), pointing to a hillslope clearance event. A widespread concurrent hillslope gullying phase in northwest England triggering enhanced soil erosion is thus the most likely explanation, as the presence of old carbon is a known issue for lakes in the region at this time. Applying a Bayesian age-depth modelling protocol is able to account for these age-reversals with some success. However, the greatest uncertainty in the model occurs across the 1700 -1900 A.D. time window as the radiocarbon percentages offer multiple age solutions due to fluctuating atmospheric 14C concentrations from fossil fuel emissions. We address this issue by incorporating into the model geochemical markers in the sediment core related to local point-source Pb mining of known-age; the most-likely age-depth curve is subsequently much more definitively resolved. Usefully, these mining-derived chronological markers bridge the temporal gap between artificial radionuclide and conventional radiocarbon dating which is a common problem in palaeolimnology. These distinctive geochemical mining profiles (Pb, Zn, Cu) have been mapped across all cores, enabling precise core correlation and confident transferral of the age-depth model, and reveal highly spatially variable sediment accumulation rates. This has enabled more accurate sediment and carbon budgets to be calculated and some insight into palaeoflood frequency to be obtained from the Brotherswater sediment sequence.
NASA Astrophysics Data System (ADS)
Blaauw, Maarten; Heuvelink, Gerard B. M.; Mauquoy, Dmitri; van der Plicht, Johannes; van Geel, Bas
2003-06-01
14C wiggle-match dating (WMD) of peat deposits uses the non-linear relationship between 14C age and calendar age to match the shape of a sequence of closely spaced peat 14C dates with the 14C calibration curve. A numerical approach to WMD enables the quantitative assessment of various possible wiggle-match solutions and of calendar year confidence intervals for sequences of 14C dates. We assess the assumptions, advantages, and limitations of the method. Several case-studies show that WMD results in more precise chronologies than when individual 14C dates are calibrated. WMD is most successful during periods with major excursions in the 14C calibration curve (e.g., in one case WMD could narrow down confidence intervals from 230 to 36 yr).
An Application of Singularity Analysis to a Heavy Precipitation Event
1993-01-01
difference in this plot. 61 NORMAN RADAR ELEVATION: 3.094 DATE 28 MAY 87 TIM 005342 GUT Cumin a 10 Tpam c CD low am am Io CID e0UC 100 "CC C d~Cc 100...element of fluid shaped like a sphere. Assuming the fluid is friction- less, no tangential stresses or forces are applied to its surface. The pressure
Towards the measurement of the13C(d, p)14C cross section using AMS
NASA Astrophysics Data System (ADS)
Murillo-Morales, S.; Barrón-Palos, L.; Chávez, E.; Araujo-Escalona, V.
2017-07-01
A plan to study the total cross section for the13C(d, p)14C nuclear reaction has been developed for energies in the center-of-mass frame between 133 and 400 keV. The proposed experiment will use a deuterium beam (1-3 MeV of energy) from the Instituto de Física-UNAM 5.5 MV Van de Graaff accelerator and the produced14C will be afterwards measured by AMS technique in the LEMA-UNAM (HVEE 1 MV Tandetron). One of the main goals is to study the performance of the LEMA-UNAM facility in the cross section measurement in comparison with other data reported in the literature, measured by other techniques. In this work we present the current status of these studies. The relevance of the13C(d, p)14C reaction in the study of compound nucleus formation as well as in some astrophysics scenarios, and the importance of the development of the AMS technique to measure cross sections of nuclear reactions of astrophysical interest in Mixico are also discussed.
75 FR 52536 - National Center for Research Resources; Notice of Closed Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2010-08-26
... Review Group, Comparative Medicine Review Committee CMRC. Date: October 14, 2010. Time: 8 a.m. to 5 p.m... Domestic Assistance Program Nos. 93.306, Comparative Medicine; 93.333, Clinical Research; 93.371...
NASA Astrophysics Data System (ADS)
Ramirez Rozzi, Fernando V.; d'Errico, Francesco; Zarate, Marcelo
2000-08-01
The Piedra Museo site (Santa Cruz, Argentina), excavated over the past nine years has yielded a rich archaeological record, which contributes to the discussion on the first peopling of the Americas. We present here a new study of the site, based on an analysis of the stratigraphy, spatial distribution of archaeological remains, bone taphonomy, and discussion of new AMS- 14C dates. We conclude that remains of extinct species with cut-marks from the lower levels are contemporaneous of stone tools and cores from the same levels. This demonstrates that humans were present in the southern part of Patagonia around 10 300 and 11 100 years BP and suggests that hunting of large mammals was a part of their subsistence strategies.
78 FR 21197 - Notice of Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2013-04-09
.... 2013-08152 Filed 4-8-13; 8:45 am] BILLING CODE 6820-AR-P ...: Date/Time: Friday, April 19, 2013 (9:00 a.m.-3:00 p.m.). Location: 2301 Constitution Avenue NW., Washington, DC 20037. Status: Open Session--Portions may be closed pursuant to Subsection (c) of Section 552...
NASA Astrophysics Data System (ADS)
Nakamura, Toshio; Koike, Hiroko; Aizawa, Jun; Okuno, Mitsuru
2015-10-01
In this study, 14C analysis by accelerator mass spectrometry (AMS) was applied to age estimation based on temporal variations in bomb-produced-14C contents of a full elephant tusk registered at Kyushu University. The tusk measured 175 cm long and 13.8 cm in diameter at the root. Thirty tusk-fragment samples were used for 14C analysis with AMS to estimate the formation ages of different positions according to catalogued global 14C contents (F14C). The F14C value of the tip of the tusk suggested that the elephant was born around 1980, while that of the root suggested death around 1994, a lifespan of at least 14 years, rather shorter period than the average lifetime of an elephant (ca. 80 years). In addition, the F14C values of fragments collected along a cross-sectional line suggested that the outer part of the tusk formed first with inner parts being deposited gradually with growth.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Buchholz, B A; Mueller, C J; Garbak, J.
2001-08-02
Accelerator mass spectrometry (AMS) is an isotope-ratio measurement technique developed in the late 1970s for tracing long-lived radioisotopes (e.g., {sup 14}C half life = 5760 y). The technique counts individual nuclei rather than waiting for their radioactive decay, allowing measurement of more than 100 low-level {sup 14}C samples per day (Vogel et al, 1995). The LLNL AMS system is shown in Fig.1. The contemporary quantity of {sup 14}C in living things ({sup 14}C/C = 1.2 x 10{sup -12} or 110 fmol {sup 14}C/ g C) is highly elevated compared to the quantity of {sup 14}C in petroleum-derived products. This isotopicmore » elevation is sufficient to trace the fate of bio-derived fuel components in the emissions of an engine without the use of radioactive materials. If synthesis of a fuel component from biologically-derived source material is not feasible, another approach is to purchase {sup 14}C-labeled material (e.g., dibutyl maleate (DBM)) and dilute it with petroleum-derived material to yield a contemporary level of {sup 14}C. In each case, the virtual absence of {sup 14}C in petroleum based fuels gives a very low {sup 14}C background that makes this approach to tracing fuel components practical. Regulatory pressure to significantly reduce the particulate emissions from diesel engines is driving research into understanding mechanisms of soot formation. If mechanisms are understood, then combustion modeling can be used to evaluate possible changes in fuel formulation and suggest possible fuel components that can improve combustion and reduce PM emissions. The combustion paradigm assumes that large molecules break down into small components and then build up again during soot formation. AMS allows us to label specific fuel components, including oxygenates, trace the carbon atoms, and test this combustion modeling paradigm. Volatile and non-volatile organic fractions (VOF, NVOF) in the PM can be further separated. The VOF of the PM can be oxidized with catalysts in the exhaust stream to further decrease PM. The effectiveness of exhaust stream catalysts to oxidize products from tracer fuel components can be monitored through AMS measurement of carbon in PM. The objects of this report are: (1) Determine contribution of diesel fuel components and oxygenates to soot formation; (2) Separate volatile and non-volatile fractions of soot; (3) Test combustion paradigm that all carbon and oxygen in fuel is equal; and (4) Produce data to validate combustion modeling.« less
NASA Astrophysics Data System (ADS)
West, G.; O'Regan, M.; Jakobsson, M.; Nilsson, A.; Pearce, C.; Snowball, I.; Wiers, S.
2017-12-01
The lack of high-temporal resolution and well-dated palaeomagnetic records from the Arctic Ocean hinders our understanding of geomagnetic field behaviour in the region, and limits the applicability of these records in the development of accurate age models for Arctic Ocean sediments. We present a palaeomagnetic secular variation (PSV) record from a sediment core recovered from the Chukchi Sea, Arctic Ocean during the SWERUS-C3 Leg 2 Expedition. The 8.24-metre-long core was collected at 57 m water depth in the Herald Canyon (72.52° N 175.32° W), and extends to 4200 years BP based on 14 AMS 14C dates and a tephra layer associated with the 3.6 cal ka BP Aniakchak eruption. Palaeomagnetic measurements and magnetic analyses of discrete samples reveal stable characteristic remanent magnetisation directions, and a magnetic mineralogy dominated by magnetite. Centennial to millennial scale declination and inclination features, which correlate well to other Western Arctic records, can be readily identified. The relative palaeointensity record of the core matches well with spherical harmonic field model outputs of pfm9k (Nilsson et al., 2014) and CALS10k.2 (Constable et al. 2016) for the site location. Supported by a robust chronology, the presented high-resolution PSV record can potentially play a key role in constructing a well-dated master chronology for the region.
Bourgeon, Lauriane; Burke, Ariane; Higham, Thomas
2017-01-01
The timing of the first entry of humans into North America is still hotly debated within the scientific community. Excavations conducted at Bluefish Caves (Yukon Territory) from 1977 to 1987 yielded a series of radiocarbon dates that led archaeologists to propose that the initial dispersal of human groups into Eastern Beringia (Alaska and the Yukon Territory) occurred during the Last Glacial Maximum (LGM). This hypothesis proved highly controversial in the absence of other sites of similar age and concerns about the stratigraphy and anthropogenic signature of the bone assemblages that yielded the dates. The weight of the available archaeological evidence suggests that the first peopling of North America occurred ca. 14,000 cal BP (calibrated years Before Present), i.e., well after the LGM. Here, we report new AMS radiocarbon dates obtained on cut-marked bone samples identified during a comprehensive taphonomic analysis of the Bluefish Caves fauna. Our results demonstrate that humans occupied the site as early as 24,000 cal BP (19,650 ± 130 14C BP). In addition to proving that Bluefish Caves is the oldest known archaeological site in North America, the results offer archaeological support for the "Beringian standstill hypothesis", which proposes that a genetically isolated human population persisted in Beringia during the LGM and dispersed from there to North and South America during the post-LGM period.
Bourgeon, Lauriane; Burke, Ariane; Higham, Thomas
2017-01-01
The timing of the first entry of humans into North America is still hotly debated within the scientific community. Excavations conducted at Bluefish Caves (Yukon Territory) from 1977 to 1987 yielded a series of radiocarbon dates that led archaeologists to propose that the initial dispersal of human groups into Eastern Beringia (Alaska and the Yukon Territory) occurred during the Last Glacial Maximum (LGM). This hypothesis proved highly controversial in the absence of other sites of similar age and concerns about the stratigraphy and anthropogenic signature of the bone assemblages that yielded the dates. The weight of the available archaeological evidence suggests that the first peopling of North America occurred ca. 14,000 cal BP (calibrated years Before Present), i.e., well after the LGM. Here, we report new AMS radiocarbon dates obtained on cut-marked bone samples identified during a comprehensive taphonomic analysis of the Bluefish Caves fauna. Our results demonstrate that humans occupied the site as early as 24,000 cal BP (19,650 ± 130 14C BP). In addition to proving that Bluefish Caves is the oldest known archaeological site in North America, the results offer archaeological support for the “Beringian standstill hypothesis”, which proposes that a genetically isolated human population persisted in Beringia during the LGM and dispersed from there to North and South America during the post-LGM period. PMID:28060931
NASA Astrophysics Data System (ADS)
Cable, Stefanie; Christiansen, Hanne H.; Westergaard-Nielsen, Andreas; Kroon, Aart; Elberling, Bo
2018-02-01
In High Arctic northern Greenland, future responses to climatic changes are poorly understood on a landscape scale. Here, we present a study of the geomorphology and cryostratigraphy in the Zackenberg Valley in NE Greenland (74°N) containing a geomorphological map and a simplified geocryological map, combined with analyses of 13 permafrost cores and two exposures. Cores from a solifluction sheet, alluvial fans, and an emerged delta were studied with regards to cryostructures, ice and total carbon contents, grain size distribution, and pore water electrical conductivity; and the samples were AMS 14C dated. The near-surface permafrost on slopes and alluvial fans is ice rich, as opposed to the ice-poor epigenetic permafrost in the emerged delta. Ground ice and carbon distribution are closely linked to sediment transport processes, which largely depend on lithology and topography. Holocene alluvial fans on the lowermost hillslopes, covering 12% of the study area, represent paleoenvironmental archives. During the contrasting climates of the Holocene, the alluvial fans continued to aggrade - through the warmer early Holocene Optimum, the colder late Holocene, and the following climate warming - and by 0.45 mm a- 1, on average. This is caused by three factors: sedimentation, ground ice aggradation, and vegetation growth and is reflected by AMS 14C dating and continuously alternating cryostructures. Highly variable sedimentation rates in space and time at the alluvial fans have been detected. This is also reflected by alternating lenticular and microlenticular cryostructures indicating syngenetic permafrost aggradation during sedimentation with suspended and organic-matrix cryostructures indicating quasi-syngenetic permafrost aggradation in response to vegetation growth in periods with reduced or no sedimentation. Over time, this causes organic matter to become buried, indicating that alluvial fans represent effective carbon sinks that have previously been overlooked.
76 FR 32978 - National Institute on Alcohol Abuse and Alcoholism; Notice of Closed Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2011-06-07
... and Alcoholism Special Emphasis Panel; NIAAA Member Conflict Applications--Epidemiology and Behavioral Sciences. Date: June 14, 2011. Time: 11 a.m. to 1 p.m. Agenda: To review and evaluate grant applications...
76 FR 62082 - National Cancer Institute; Notice of Closed Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2011-10-06
... Sciences and Epidemiology National Cancer Institute. The meeting will be closed to the public as indicated... Epidemiology, National Cancer Institute. Date: November 14, 2011. Time: 8:30 a.m. to 4 p.m. Agenda: To review...
77 FR 25686 - Malcolm Baldrige National Quality Award Board of Overseers and Panel of Judges
Federal Register 2010, 2011, 2012, 2013, 2014
2012-05-01
..., Baldrige Enterprise Update, Judges Panel Update, Baldrige Fellows Program Discussion, and Strategic Planning. DATES: The meeting will convene on Thursday, June 14, 2012, at 8:30 a.m. Eastern time and adjourn...
An integrated data-analysis and database system for AMS 14C
NASA Astrophysics Data System (ADS)
Kjeldsen, Henrik; Olsen, Jesper; Heinemeier, Jan
2010-04-01
AMSdata is the name of a combined database and data-analysis system for AMS 14C and stable-isotope work that has been developed at Aarhus University. The system (1) contains routines for data analysis of AMS and MS data, (2) allows a flexible and accurate description of sample extraction and pretreatment, also when samples are split into several fractions, and (3) keeps track of all measured, calculated and attributed data. The structure of the database is flexible and allows an unlimited number of measurement and pretreatment procedures. The AMS 14C data analysis routine is fairly advanced and flexible, and it can be easily optimized for different kinds of measuring processes. Technically, the system is based on a Microsoft SQL server and includes stored SQL procedures for the data analysis. Microsoft Office Access is used for the (graphical) user interface, and in addition Excel, Word and Origin are exploited for input and output of data, e.g. for plotting data during data analysis.
Federal Register 2010, 2011, 2012, 2013, 2014
2013-01-15
... Nutrition. Date: February 14, 2013. Time: 8:00 a.m. to 4:00 p.m. Agenda: To review and evaluate grant... Clinical Studies on LIFE-Moms (R01). Date: February 25, 2013. Time: 1:00 p.m. to 3:00 p.m. Agenda: To... and Nutrition Research; 93.849, Kidney Diseases, Urology and Hematology Research, National Institutes...
DOE Office of Scientific and Technical Information (OSTI.GOV)
Keck, B D; Ognibene, T; Vogel, J S
2010-02-05
Accelerator mass spectrometry (AMS) is an isotope based measurement technology that utilizes carbon-14 labeled compounds in the pharmaceutical development process to measure compounds at very low concentrations, empowers microdosing as an investigational tool, and extends the utility of {sup 14}C labeled compounds to dramatically lower levels. It is a form of isotope ratio mass spectrometry that can provide either measurements of total compound equivalents or, when coupled to separation technology such as chromatography, quantitation of specific compounds. The properties of AMS as a measurement technique are investigated here, and the parameters of method validation are shown. AMS, independent of anymore » separation technique to which it may be coupled, is shown to be accurate, linear, precise, and robust. As the sensitivity and universality of AMS is constantly being explored and expanded, this work underpins many areas of pharmaceutical development including drug metabolism as well as absorption, distribution and excretion of pharmaceutical compounds as a fundamental step in drug development. The validation parameters for pharmaceutical analyses were examined for the accelerator mass spectrometry measurement of {sup 14}C/C ratio, independent of chemical separation procedures. The isotope ratio measurement was specific (owing to the {sup 14}C label), stable across samples storage conditions for at least one year, linear over 4 orders of magnitude with an analytical range from one tenth Modern to at least 2000 Modern (instrument specific). Further, accuracy was excellent between 1 and 3 percent while precision expressed as coefficient of variation is between 1 and 6% determined primarily by radiocarbon content and the time spent analyzing a sample. Sensitivity, expressed as LOD and LLOQ was 1 and 10 attomoles of carbon-14 (which can be expressed as compound equivalents) and for a typical small molecule labeled at 10% incorporated with {sup 14}C corresponds to 30 fg equivalents. AMS provides an sensitive, accurate and precise method of measuring drug compounds in biological matrices.« less
NASA Astrophysics Data System (ADS)
Agenbroad, L. D.; Johnson, J.; Morris, D.; Stafford, T. W.
2007-05-01
AMS radiocarbon dating of a pygmy mammoth (Mammuthus exilis) thoracic vertebra and associated charcoal has provided evidence for the contemporaneity of the pygmy mammoth and early human remains on Santa Rosa Island, Channel Islands National Park, California. Charcoal associated with the vertebra dated 11,010 ±70 RC yr B.P. (B-133594). That date was significantly close to the extinction date for continental mammoths to warrant a date directly on the bone. The vertebral centrum was drilled and submitted for bone collagen dating by Stafford. The resultant date was 11,030 ±50 RC yr. B P (CAMS-71697), only 20 14C years older than the charcoal date. The significance of the dates was immediately apparent, because a date from human remains from the Arlington Springs Site (CA-SRI-173), Santa Rosa Island was 10,960 ±80 RC yr B.P. (CAMS-16810) (Johnson et al., 1999) - a date nearly identical with the M. exilis measurement. The contemporaneity of the mammoth bone date and human bone date indicates that mammoths were still extant on the islands when humans arrived. These data are from only one mammoth and one human ... more research needs to be done on the mammoth and human remains on the island. Was the contemporaneity coincidence, or the prelude to extinction?
78 FR 29144 - Center for Scientific Review; Notice of Closed Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2013-05-17
... Design Study Section. Date: June 14, 2013. Time: 8:00 a.m. to 6:00 p.m. Agenda: To review and evaluate....nih.gov . (Catalogue of Federal Domestic Assistance Program Nos. 93.306, Comparative Medicine; 93.333...
76 FR 13421 - Center for Scientific Review; Notice of Closed Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2011-03-11
... . Name of Committee: Center for Scientific Review Special Emphasis Panel, PAR-10-279: Robotics Technology...-Agency Robotics SBIR, Panel 1. Date: April 14-15, 2011. Time: 8 a.m. to 5 p.m. Agenda: To review and...
76 FR 30370 - National Institute of Diabetes and Digestive and Kidney Diseases; Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2011-05-25
... Institute of Diabetes and Digestive and Kidney Diseases Special Emphasis Panel; Obesity and Pregnancy... Special Emphasis Panel; Obesity and Pregnancy. Date: July 14-15, 2011. Time: 8 a.m. to 5 p.m. Agenda: To...
75 FR 18218 - Center for Scientific Review; Notice of Closed Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2010-04-09
...: Interdisciplinary Molecular Sciences Specials. Date: April 13-14, 2010. Time: 8 a.m. to 6 p.m. Agenda: To review and... Domestic Assistance Program Nos. 93.306, Comparative Medicine; 93.333, Clinical Research, 93.306, 93.333...
Accelerator mass spectrometry analysis of aroma compound absorption in plastic packaging materials
NASA Astrophysics Data System (ADS)
Stenström, Kristina; Erlandsson, Bengt; Hellborg, Ragnar; Wiebert, Anders; Skog, Göran; Nielsen, Tim
1994-05-01
Absorption of aroma compounds in plastic packaging materials may affect the taste of the packaged food and it may also change the quality of the packaging material. A method to determine the aroma compound absorption in polymers by accelerator mass spectrometry (AMS) is being developed at the Lund Pelletron AMS facility. The high sensitivity of the AMS method makes it possible to study these phenomena under realistic conditions. As a first test low density polyethylene exposed to 14C-doped ethyl acetate is examined. After converting the polymer samples with the absorbed aroma compounds to graphite, the {14C }/{13C } ratio of the samples is measured by the AMS system and the degree of aroma compound absorption is established. The results are compared with those obtained by supercritical fluid extraction coupled to gas chromatography (SFE-GC).
Use of natural diamonds to monitor 14C AMS instrument backgrounds
NASA Astrophysics Data System (ADS)
Taylor, R. E.; Southon, John
2007-06-01
To examine one component of the instrument-based background in the University of California Keck Carbon Cycle AMS spectrometer, we have obtained measurements on a set of natural diamonds pressed into sample holders. Natural diamond samples (N = 14) from different sources within rock formations with geological ages greatly in excess of 100 Ma yielded a range of currents (∼110-250 μA 12C- where filamentous graphite typically yields ∼150 μA 12C-) and apparent 14C ages (64.9 ± 0.4 ka BP [0.00031 ± 0.00002 fm] to 80.0 ± 1.1 ka BP [0.00005 ± 0.00001 fm]). Six fragments cut from a single diamond exhibited essentially identical 14C values - 69.3 ± 0.5 ka-70.6 ± 0.5 ka BP. The oldest 14C age equivalents were measured on natural diamonds which exhibited the highest current yields.
NASA Astrophysics Data System (ADS)
Scharer, Katherine M.; Biasi, Glenn P.; Weldon, Ray J., II
2011-12-01
The Pallett Creek paleoseismic record occupies a keystone position in most attempts to develop rupture histories for the southern San Andreas fault. Previous estimates of earthquake ages at Pallett Creek were determined by decay counting radiocarbon methods. That method requires large samples which can lead to unaccounted sources of uncertainty in radiocarbon ages because of the heterogeneous composition of organic layers. In contrast, accelerator mass spectrometry (AMS) radiocarbon dates may be obtained from small samples that have known carbon sources and also allow for a more complete sampling of the section. We present 65 new AMS radiocarbon dates that span nine ground-rupturing earthquakes at Pallett Creek. Overall, the AMS dates are similar to and reveal no dramatic bias in the conventional dates. For many layers, however, individual charcoal samples were younger than the conventional dates, leading to earthquake ages that are overall slightly younger than previously reported. New earthquake ages are determined by Bayesian refinement of the layer ages based on stratigraphic ordering and sedimentological constraints. The new chronology is more regular than previously published records in large part due to new samples constraining the age of event R. The closed interval from event C to 1857 has a mean recurrence of 135 years (σ = 83.2 years) and a quasiperiodic coefficient of variation (COV) of 0.61. We show that the new dates and resultant earthquake chronology have a stronger effect on COV than the specific membership of this long series and dating precision improvements from sedimentation rates.
Accelerator mass spectrometer with ion selection in high-voltage terminal
NASA Astrophysics Data System (ADS)
Rastigeev, S. A.; Goncharov, A. D.; Klyuev, V. F.; Konstantinov, E. S.; Kutnyakova, L. A.; Parkhomchuk, V. V.; Petrozhitskii, A. V.; Frolov, A. R.
2016-12-01
The folded electrostatic tandem accelerator with ion selection in a high-voltage terminal is the basis of accelerator mass spectrometry (AMS) at the BINP. Additional features of the BINP AMS are the target based on magnesium vapors as a stripper without vacuum deterioration and a time-of-flight telescope with thin films for reliable ion identification. The acceleration complex demonstrates reliable operation in a mode of 1 MV with 50 Hz counting rate of 14C+3 radiocarbon for modern samples (14C/12C 1.2 × 10-12). The current state of the AMS has been considered and the experimental results of the radiocarbon concentration measurements in test samples have been presented.
NASA Astrophysics Data System (ADS)
Behling, Hermann; W. Arz, Helge; Pätzold, Jürgen; Wefer, Gerold
2000-06-01
Late Quaternary paleoenvironments from northeastern (NE) Brazil have been studied by pollen analysis of marine sediment. The studied core GeoB 3104-1 (3°40' S, 37°43' W, 767 m b.s.l.) from the upper continental slope off NE Brazil is 517 cm long and >42,000 14C yr BP old. Chronological control was obtained by 12 radiocarbon (AMS) dates from individuals of the foraminiferal species Globigerinoides sacculifer. Modern pollen analogs were received from 15 river, lake and forest soil surface samples from NE Brazil. Marine pollen dates indicate the predominance of semi-arid caatinga vegetation in NE Brazil during the recorded period between >42,000 and 8500 14C yr BP. The increased fluvial input of terrigenous material, with high concentrations of pollen and specially fern spores, into the marine deposits, about 40,000, 33,000 and 24,000 14C yr BP and between 15,500 and 11,800 14C yr BP, indicate short-term periods of strong rainfall on the NE Brazilian continent. The expansion of mountain, floodplain and gallery forests characterize the interval between 15,500 and 11,800 14C yr BP as the wettest recorded period in NE Brazil, which allowed floristic exchanges between Atlantic rain forest and Amazonian rain forest, and vice versa. The paleodata from core GeoB 3104-1 confirm the, in general, dry pre-Last Glacial Maximum (LGM) and LGM conditions and the change to wet Lateglacial environments in tropical South America. The annual movement of the intertropical convergence zone over NE Brazil, the strong influence of the Antarctic cold fronts and changes of the high-pressure cell over the southern Atlantic, may explain the very wet Lateglacial period in NE Brazil. The documented NE Brazilian short-term signals correlate with the documented Dansgaard-Oeschger cycles and Heinrich events from the northern Hemisphere and suggest strong teleconnections.
75 FR 21391 - Sunshine Act Meeting Notice
Federal Register 2010, 2011, 2012, 2013, 2014
2010-04-23
... TENNESSEE VALLEY AUTHORITY Sunshine Act Meeting Notice Agency Holding the Meeting: Tennessee Valley Authority. Federal Register Citation of Previous Announcement: 75 FR 19465 (April 14, 2010). Previously Announced Time and Date of Meeting: Immediately following 8:30 a.m. listening session, April 16...
Separation of lipoproteins for quantitative analysis of 14C-labeled lipid soluble compounds
USDA-ARS?s Scientific Manuscript database
Carbon-14 tracer studies using accelerator mass spectrometry (AMS) have provided novel insights into nutrient metabolism and whole body metabolite flux. In addition to a baseline separation of analytes, a critical requirement specific to the AMS analysis was a stable carbon baseline within the anal...
NASA Astrophysics Data System (ADS)
Zondervan, A.; Hauser, T. M.; Kaiser, J.; Kitchen, R. L.; Turnbull, J. C.; West, J. G.
2015-10-01
A detailed description is given of the 0.5 MV tandem accelerator mass spectrometry (AMS) system for 10Be, 14C, 26Al, installed in early 2010 at GNS Science, New Zealand. Its design follows that of previously commissioned Compact 14C-only AMS (CAMS) systems based on the Pelletron tandem accelerator. The only basic departure from that design is an extension of the rare-isotope achromat with a 45° magnet and a two-anode gas-ionisation detector, to provide additional filtering for 10Be. Realised performance of the three AMS modes is discussed in terms of acceptance-test scores, 14C Poisson and non-Poisson errors, and 10Be detection limit and sensitivity. Operational details and hardware improvements, such as 10Be beam transport and particle detector setup, are highlighted. Statistics of repeat measurements of all graphitised 14C calibration cathodes since start-up show that 91% of their total uncertainty values are less than 0.3%, indicating that the rare-isotope beamline extension has not affected precision of 14C measurement. For 10Be, the limit of detection in terms of the isotopic abundance ratio 10Be/9Be is 6 × 10-15 at at-1 and the total efficiency of counting atoms in the sample cathode is 1/8500 (0.012%).
78 FR 45252 - National Institute on Drug Abuse; Notice of Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2013-07-26
... U.S.C. App.), notice is hereby given of a meeting of the National Advisory Council on Drug Abuse... on Drug Abuse. Date: September 4, 2013. Closed: 8:30 AM to 10:30 AM. Agenda: To review and evaluate... program developments in the drug abuse field. Place: National Institutes of Health, Neuroscience Center...
AMS measurements of 14C and 129I in seawater around radioactive waste dump sites
NASA Astrophysics Data System (ADS)
Povinec, P. P.; Oregioni, B.; Jull, A. J. T.; Kieser, W. E.; Zhao, X.-L.
2000-10-01
According to a recent IAEA compilation of inventories of radioactive wastes dumped in the world ocean, a total of 85 PBq of radioactive wastes were dumped, in the Atlantic (45 PBq), the Pacific (1.4 PBq) and the Arctic (38 PBq) Oceans and their marginal seas between 1946 and 1993, mostly in the form of low-level wastes. 3H, and 14C formed an important part of the beta-activity of these dumped wastes. Because of its long half-life, 14C will be the main constituent in possible leakages from the wastes in the future. On the other hand, 14C and 129I are important radioactive tracers which have been artificially introduced into the oceans. Small amounts of 14C and 129I can be easily measured by accelerator mass spectrometry (AMS) on mg-size samples of carbon and iodine extracted from 500 ml seawater samples. The high analytical sensitivity enables one therefore to find even trace amounts of 14C and 129I which could be released from radioactive wastes, and to compare the measured levels with the global distribution of these radionuclides. The IAEAs Marine Environment Laboratory (IAEA-MEL) has been engaged in an assessment program related to radioactive waste dumping in the oceans since 1992 and has participated in several expeditions to the Atlantic, Arctic, Indian and Pacific Oceans to sample seawater, biota and sediment for radiological assessment studies. In the present paper, we report on methods of 14C and 129I measurements in seawater by AMS and present data on the NE Atlantic, the Arctic and the NW Pacific Ocean dumping sites. A small increase of 14C was observed at the NE Atlantic dumping site.
A New {sup 14}C-AMS Facility at UFF- Niteroi, Brazil
DOE Office of Scientific and Technical Information (OSTI.GOV)
Gomes, P. R. S.; Macario, K. D.; Anjos, R. M.
2010-08-04
We report a new Accelerator Mass Spectrometry facility at the Physics Institute of Fluminense Federal University in Brazil, the Nuclear Chronology Laboratory - LACRON. The sample preparation laboratory is ready to perform chemical treatment through graphitization and the acquisition of a Single Stage Accelerator Mass Spectrometry System is in progress. LACRON will be the first independent laboratory to perform the {sup 14}C-AMS technique not only in Brazil but in Latin America.
A New 14C-AMS Facility at UFF- Niteroi, Brazil
NASA Astrophysics Data System (ADS)
Gomes, P. R. S.; Macario, K. D.; Anjos, R. M.; Linares, R.; Carvalho, C.; Queiroz, E.
2010-08-01
We report a new Accelerator Mass Spectrometry facility at the Physics Institute of Fluminense Federal University in Brazil, the Nuclear Chronology Laboratory—LACRON. The sample preparation laboratory is ready to perform chemical treatment through graphitization and the acquisition of a Single Stage Accelerator Mass Spectrometry System is in progress. LACRON will be the first independent laboratory to perform the 14C-AMS technique not only in Brazil but in Latin America.
The Holocene and the Late Deglaciation: timing and development on the northern Svalbard margin
NASA Astrophysics Data System (ADS)
Slubowska, M. A.; Koc, N.; Rasmussen, T. L.
2002-12-01
Svalbard is located in the high Arctic (76§ to 81§ N and 10§ to 28§ E) at the northernmost reach of the warmer West Spitsbergen Current, which forms the continuation of the North Atlantic Current. At this position, close to the Polar Front, even small variations in the current are expected to have large effects on the regional climate. Therefore, the Svalbard area is ideal for monitoring past changes in the ocean circulation as well as the timing and the nature of the Svalbard ice sheet disintegration. We have investigated core NP94-51 SC2 (80§ 21,346 N, 16§ 17,970 E, 400m water depth and 714 cm long) retrieved from the mouth of the Hinlopen Strait in the Arctic Ocean, north of Svalbard. The main objective of this study is to document a) the deglaciation history of the area, b) the Holocene climate variability on the decadal time scales using sedimentological, physical and biological analysis. AMS-14C dating gives the age of approximately 14,000 BP for the bottom of the core. The Holocene interglacial is represented by c. 5 m. A detailed analysis of different oceanographic proxies such as: ice rafted debris, magnetic susceptibility, spectral reflectance (L*a*b scale), benthic and planktic foraminiferal fauna, diatom flora, grain size and radiocarbon dates (AMS-14C) were used to reconstruct the paleoceanographic evolution of the area. The results show that disintegration of the Hinlopen Strait ice sheet and, possibly, the northern margin of the Svalbard ice sheet began at 14,000 BP. The influx of the subsurface Atlantic waters into the area began during the Bolling interstadial at 12,600 BP, while the surface waters were still cold and of low salinity. The retreat of the sea ice cover occurred together with the opening of the surface waters at 10,800 BP. During major part of the Younger Dryas (10,800 - 10,000 BP) the Polar Front was located close to the core site. At 10,100 BP the Polar Front retreated from that area. In comparison to the deglaciation, preliminary results of grain sizes, magnetic susceptibility and reflectance from the Holocene period indicate relatively low variability in the environmental conditions.
NASA Astrophysics Data System (ADS)
Hanke, Ulrich M.; McIntyre, Cameron P.; Schmidt, Michael W. I.; Wacker, Lukas; Eglinton, Timothy I.
2016-04-01
Measurements of the natural abundance of radiocarbon (14C) concentrations in inorganic and organic carbon-containing materials can be used to investigate their date of origin. Particularly, the biogeochemical cycling of specific compounds in the environment may be investigated applying molecular marker analyses. However, the isolation of specific molecules from environmental matrices requires a complex processing procedure resulting in small sample sizes that often contain less than 30 μg C. Such small samples are sensitive to extraneous carbon (Cex) that is introduced during the purification of the compounds (Shah and Pearson, 2007). We present a thorough radiocarbon blank assessment for benzene polycarboxylic acids (BPCA), a proxy for combustion products that are formed during the oxidative degradation of condensed polyaromatic structures (Wiedemeier et al, in press). The extraneous carbon assessment includes reference material for (1) chemical extraction, (2) preparative liquid chromatography (3) wet chemical oxidation which are subsequently measured with gas ion source AMS (Accelerator Mass Spectrometer, 5-100 μg C). We always use pairs of reference materials, radiocarbon depleted (14Cfossil) and modern (14Cmodern) to determine the fraction modern (F14C) of Cex.Our results include detailed information about the quantification of Cex in radiocarbon molecular marker analysis using BPCA. Error propagation calculations indicate that ultra-microscale samples (20-30 μg) are feasible with uncertainties of less than 10 %. Calculations of the constant contamination reveal important information about the source (F14C) and mass (μg) of Cex (Wacker and Christl, 2011) for each sub procedure. An external correction of compound specific radiocarbon data is essential for robust results that allow for a high degree of confidence in the 14C results. References Shah and Pearson, 2007. Ultra-microscale (5-25μg C) analysis of individual lipids by 14C AMS: Assessment and correction for sample processing blanks. Radiocarbon 49(1), 69-82. Wacker, L. and M. Christl. 2011. Data reduction for small radiocarbon samples - error propagation using the model of constant contamination. Ion Beam Physics, ETH Zurich, Annual report 2011. Wiedemeier, D.B., S.Q. Lang, M. Gierga, S. Abiven, S.M. Bernasconi, G.L. Bernasconi-Green, I. Hajdas, U.M. Hanke, M.D. Hilf, C.P. McIntyre, M.P.W. Schneider, R.H. Smittenberg, L. Wacker, G.L.B. Wiesenberg, M.W.I. Schmidt. Characterization, quantification and compound-specific isotopic analysis of pyrogenic carbon using benzene polycarboxylic acids (BPCA). Journal of Visualized Experiments. In press.
75 FR 24880 - Sunshine Act Notice
Federal Register 2010, 2011, 2012, 2013, 2014
2010-05-06
... COMMISSION ON CIVIL RIGHTS Sunshine Act Notice AGENCY: United States Commission on Civil Rights. ACTION: Notice of meeting. Date and Time: Friday, May 14, 2010; 11 a.m. EDT. Place: 624 9th St., NW... Health Care Disparities Approval of Findings & Recommendations on Educational Effectiveness of...
78 FR 31520 - Sunshine Act Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2013-05-24
... COMMODITY FUTURES TRADING COMMISSION Sunshine Act Meeting TIME AND DATE: 10:00 a.m., Friday, June 14, 2013. PLACE: 1155 21st St. NW., Washington, DC, 9th Floor Commission Conference Room. STATUS: Closed. MATTERS TO BE CONSIDERED: Surveillance, Examinations, and Enforcement Matters. In the event that...
75 FR 21246 - Sunshine Act Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2010-04-23
... COMMODITY FUTURES TRADING COMMISSION Sunshine Act Meeting Time and Date: 11 a.m., Friday, May 14, 2010. Place: 1155 21st St., NW., Washington, DC, 9th Floor Commission Conference Room. Status: Closed. Matters to be Considered: Surveillance Matters. Contact Person for More Information: Sauntia S. Warfield...
76 FR 55648 - Sunshine Act Meeting Notice
Federal Register 2010, 2011, 2012, 2013, 2014
2011-09-08
... CONSUMER PRODUCT SAFETY COMMISSION Sunshine Act Meeting Notice TIME AND DATE: Wednesday, September 14, 2011, 10-11 a.m. PLACE: Room 420, Bethesda Towers, 4330 East West Highway, Bethesda, Maryland... INFORMATION: Todd A. Stevenson, Office of the Secretary, U.S. Consumer Product Safety Commission, 4330 East...
76 FR 59118 - Sunshine Act Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2011-09-23
... COMMODITY FUTURES TRADING COMMISSION Sunshine Act Meetings AGENCY HOLDING THE MEETING: Commodity Futures Trading Commission. TIME AND DATE: 10 a.m., Friday, October 14, 2011. PLACE: 1155 21st St., NW., Washington, DC, 9th Floor Commission Conference Room. STATUS: Closed. Matters To Be Considered Surveillance...
NASA Astrophysics Data System (ADS)
Rixhon, Gilles; May, Simon Matthias; Engel, Max; Mechernich, Silke; Schroeder-Ritzrau, Andrea; Frank, Norbert; Fohlmeister, Jens; Boulvain, Frédéric; Dunai, Tibor; Brückner, Helmut
2017-04-01
The deposition of supratidal coarse-clast deposits is difficult to date, limiting their value for inferring frequency-magnitude patterns of high-energy wave events. On Bonaire (Leeward Antilles, Caribbean), these deposits form prominent landforms, and transport by one or several Holocene tsunamis is assumed at least for the largest clasts. Although a large dataset of 14C and electron spin resonance (ESR) ages is available for major coral rubble ridges and ramparts, it is still debated whether these data reflect the timing of major events, and how these datasets are biased by the reworking of coral fragments. As an attempt to overcome the current challenges for dating the dislocation of singular boulders, three distinct dating methods are implemented and compared: (i) 14C dating of boring bivalves attached to the boulders; (ii) 230Th/U dating of post-depositional, secondary calcite flowstone and subaerial microbialites at the underside of the boulders; and (iii) surface exposure dating of overturned boulders via 36Cl concentration measurements in corals. Approaches (ii) and (iii) have never been applied to coastal boulder deposits so far. The three 14C age estimates are older than 37 ka, i.e. most probably beyond the applicability of the method, which is attributed to post-depositional diagenetic processes, shedding doubt on the usefulness of this method in the local context. The remarkably convergent 230Th/U ages, all pointing to the Late Holocene period (1.0-1.6 ka), are minimum ages for the transport event(s). The microbialite sample yields an age of 1.23±0.23 ka and both flowstone samples are in stratigraphic order: the older (onset of carbonate precipitation) and younger flowstone layers yield ages of 1.59±0.03 and 1.23±0.03 ka, respectively. Four coral samples collected from the topside of overturned boulders yielded similar 36Cl concentration measurements. However, the computed ages are affected by large uncertainties, mostly due to the high natural chlorine concentration resulting in low AMS ratios. After correction for the inherited component and chemical denudation since platform emergence (inducing additional uncertainty), the calculated 36Cl ages cluster between 2.5±1.3 and 3.0±1.3 ka for three of four boulders whilst the fourth one yields an age of 6.1±1.8 ka, probably related to a higher inheritance. These 230Th/U and 36Cl age estimates are coherent with a suggested tsunami age of <3.3 ka obtained from the investigation of allochthonous shell horizons in sediment cores of northwestern Bonaire. While 230Th/U dating of post-depositional calcite flowstone appears to be the most robust and/or accurate approach, these results illustrate the potential and current limitations of the applied methods for dating the dislocation of supralittoral boulders in carbonate-reef settings.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Muir, G.K.P., E-mail: Graham.Muir@glasgow.ac.uk; Hayward, S.; Tripney, B.G.
2015-01-15
Highlights: • Compares industry standard and {sup 14}C methods for determining bioenergy content of MSW. • Differences quantified through study at an operational energy from waste plant. • Manual sort and selective dissolution are unreliable measures of feedstock bioenergy. • {sup 14}C methods (esp. AMS) improve precision and reliability of bioenergy determination. • Implications for electricity generators and regulators for award of bio-incentives. - Abstract: {sup 14}C analysis of flue gas by accelerator mass spectrometry (AMS) and liquid scintillation counting (LSC) were used to determine the biomass fraction of mixed waste at an operational energy-from-waste (EfW) plant. Results were convertedmore » to bioenergy (% total) using mathematical algorithms and assessed against existing industry methodologies which involve manual sorting and selective dissolution (SD) of feedstock. Simultaneous determinations using flue gas showed excellent agreement: 44.8 ± 2.7% for AMS and 44.6 ± 12.3% for LSC. Comparable bioenergy results were obtained using a feedstock manual sort procedure (41.4%), whilst a procedure based on selective dissolution of representative waste material is reported as 75.5% (no errors quoted). {sup 14}C techniques present significant advantages in data acquisition, precision and reliability for both electricity generator and industry regulator.« less
Determination of 14C/ 12C of acetaldehyde in indoor air by compound specific radiocarbon analysis
NASA Astrophysics Data System (ADS)
Kato, Yoshimi; Shinohara, Naohide; Yoshinaga, Jun; Uchida, Masao; Matsuda, Ayuri; Yoneda, Minoru; Shibata, Yasuyuki
A method of compound-specific radiocarbon analysis (CSRA) for acetaldehyde in indoor air was established for the source apportionment purpose and the methodology was applied to indoor air samples. Acetaldehyde in indoor air samples was collected using the conventional 2,4-dinitrophenylhydrazine (DNPH) derivatization method. Typically 24-h air sampling at 5-10 L min -1 allowed collection of adequate amount of acetaldehyde for radiocarbon analysis by accelerator mass spectrometry (AMS). The 14C abundance of acetaldehyde in indoor air was measured by AMS after solvent extraction of derivatized acetaldehyde and sequential purification by a preparative liquid chromatography system and a preparative capillary gas chromatography system. The recovery and purity of the derivatized acetaldehyde was satisfactory for 14C analysis by AMS. 14C abundance of acetaldehyde was calculated by considering that of derivatizing agent DNPH. Our preliminary survey showed that percent modern carbon (pMC) values of acetaldehyde isolated from indoor air sampled in newly built, unoccupied housings ( n=5) in the suburb of Tokyo ranged from 49.4 to 67.0. This result indicated that contribution of anthropogenic source was greater than previously expected.
Measurements of carbon-14 with cavity ring-down spectroscopy
McCartt, A. D.; Ognibene, T.; Bench, G.; ...
2015-06-13
Accelerator Mass Spectrometry (AMS) is the most sensitive method for quantitation of 14C in biological samples. This technology has been used in a variety of low dose, human health related studies over the last 20 years when very high sensitivity was needed. AMS helped pioneer these scientific methods, but its expensive facilities and requirements for highly trained technical staff have limited their proliferation. Quantification of 14C by cavity ring-down spectroscopy (CRDS) offers an approach that eliminates many of the shortcomings of an accelerator-based system and would supplement the use of AMS in biomedical research. Our initial prototype, using a non-idealmore » wavelength laser and under suboptimal experimental conditions, has a 3.5-modern, 1-σ precision for detection of milligram-sized, carbon-14-elevated samples. Furthermore, these results demonstrate proof of principle and provided a starting point for the development of a spectrometer capable of biologically relevant sensitivities.« less
Dehnert, Christoph; Böhm, Astrid; Grigoriev, Igor; Menold, Elmar; Bärtsch, Peter
2014-09-01
Acclimatization at natural altitude effectively prevents acute mountain sickness (AMS). It is, however, unknown whether prevention of AMS is also possible by only sleeping in normobaric hypoxia. In a placebo-controlled, double-blind study 76 healthy unacclimatized male subjects, aged 18 to 50 years, slept for 14 consecutive nights at either a fractional inspired oxygen (Fio2) of 0.14 to 0.15 (average target altitude 3043 m; treatment group) or 0.209 (control group). Four days later, AMS scores and incidence of AMS were assessed during a 20-hour exposure in normobaric hypoxia at Fio2 = 0.12 (equivalent to 4500 m). Because of technical problems with the nitrogen generators, target altitude was not achieved in the tents and only 21 of 37 subjects slept at an average altitude considered sufficient for acclimatization (>2200 m; average, 2600 m). Therefore, in a subgroup analysis these subjects were compared with the 21 subjects of the control group with the lowest sleeping altitude. This analysis showed a significantly lower AMS-C score (0.38; 95% CI, 0.21 to 0.54) vs 1.10; 95% CI, 0.57 to 1.62; P = .04) and lower Lake Louise Score (3.1; 95% CI, 2.2 to 4.1 vs 5.1; 95% CI, 3.6 to 6.6; P = .07) for the treatment subgroup. The incidence of AMS defined as an AMS-C score greater than 0.70 was also significantly lower (14% vs 52%; P < .01). Sleeping 14 consecutive nights in normobaric hypoxia (equivalent to 2600 m) reduced symptoms and incidence of AMS 4 days later on exposure to 4500 m. Copyright © 2014 Wilderness Medical Society. Published by Elsevier Inc. All rights reserved.
The first radiocarbon data of bone remains of mammoth faunal forms in northwestern Russia
NASA Astrophysics Data System (ADS)
Nikonov, A. A.; van der Plicht, J.
2010-05-01
Unlike in the neighboring territories, the distribution and the period of habitation of late Pleistocene mammoth complex animals in the northwestern area of Russia had not been studied until recently. This article fills in this gap using the bone material from the Zoological Institute of the Russian Academy of Sciences and the collections of one of the authors. The samples of 14 bones and teeth of big mammals uncovered in different places of the region were dated. The data obtained by conventional 14C method and AMS method agree with each other and make it possible to determine two periods of habitation of mammoth complex animals in the region: 39 000-23 000 years ago and 13 000-9800 years ago, which confirms that ice-free landscapes existed here at these time intervals.
NASA Astrophysics Data System (ADS)
Salehpour, M.; Håkansson, K.; Possnert, G.; Wacker, L.; Synal, H.-A.
2016-03-01
A range of ion beam analysis activities are ongoing at Uppsala University, including Accelerator Mass Spectrometry (AMS). Various isotopes are used for AMS but the isotope with the widest variety of applications is radiocarbon. Up until recently, only the 5 MV Pelletron tandem accelerator had been used at our site for radiocarbon AMS, ordinarily using 12 MeV 14,13,12C3+ ions. Recently a new radiocarbon AMS system, the Green-MICADAS, developed at the ion physics group at ETH Zurich, was installed. The system has a number of outstanding features which will be described. The system operates at a terminal voltage of 175 kV and uses helium stripper gas, extracting singly charged carbon ions. The low- and high energy mass spectrometers in the system are stigmatic dipole permanent magnets (0.42 and 0.97 T) requiring no electrical power nor cooling water. The system measures both the 14C/12C and the 13C/12C ratios on-line. Performance of the system is presented for both standard mg samples as well as μg-sized samples.
77 FR 9658 - Sunshine Act Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2012-02-17
... FEDERAL MINE SAFETY AND HEALTH REVIEW COMMISSION Sunshine Act Meeting February 14, 2012. TIME AND DATE: 10 a.m., Thursday, February 23, 2012. PLACE: The Richard V. Backley Hearing Room, 9th Floor, 601 New Jersey Avenue NW., Washington, DC. STATUS: Open. MATTERS TO BE CONSIDERED: The Commission will...
78 FR 77367 - Almonds Grown in California; Continuance Referendum
Federal Register 2010, 2011, 2012, 2013, 2014
2013-12-23
... DEPARTMENT OF AGRICULTURE Agricultural Marketing Service 7 CFR Part 981 [Doc. No. AMS-FV-13-0082; FV14-981-1 CR] Almonds Grown in California; Continuance Referendum AGENCY: Agricultural Marketing... marketing order that regulates the handling of almonds grown in California. DATES: The referendum will be...
75 FR 81589 - Sunshine Act Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2010-12-28
... COMMODITY FUTURES TRADING COMMISSION Sunshine Act Meetings TIME AND DATE: 11 a.m., Friday, January 14, 2011. PLACE: 1155 21st St., NW., Washington, DC, 9th Floor Commission Conference Room. STATUS.... [FR Doc. 2010-32781 Filed 12-23-10; 4:15 pm] BILLING CODE 6351-01-P ...
75 FR 43941 - Sunshine Act Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2010-07-27
... COMMODITY FUTURES TRADING COMMISSION Sunshine Act Meetings TIME AND DATE: 11 a.m., Friday, August 14, 2010. PLACE: 1155 21st St., NW., Washington, DC, 9th Floor Commission Conference Room. STATUS.... [FR Doc. 2010-18493 Filed 7-23-10; 4:15 pm] BILLING CODE 6351-01-P ...
76 FR 55648 - Sunshine Act Meeting Notice
Federal Register 2010, 2011, 2012, 2013, 2014
2011-09-08
... CONSUMER PRODUCT SAFETY COMMISSION Sunshine Act Meeting Notice TIME AND DATE: Wednesday, September 14, 2011; 11 a.m.-12 p.m. PLACE: Hearing Room 420, Bethesda Towers, 4330 East West Highway, Bethesda.... Stevenson, Office of the Secretary, U.S. Consumer Product Safety Commission, 4330 East West Highway...
NASA Astrophysics Data System (ADS)
Jessen, Simon P.; Rasmussen, Tine L.; Nielsen, Tove; Solheim, Anders
2010-05-01
Data have been compiled from eleven sediment cores from 76° to 80°N on the western Svalbard slope. The cores are from water depths between 630 and 1880 m and show clear similarities in lithology and magnetic susceptibility. All cores penetrated into mass transported sediments from glacigenic debris flow events and turbidity flow events. The mass transport probably occurred when the ice reached the shelf edge. The deposits date between 24,080 ± 150 and 23,550 ± 185 calibrated (cal) years BP. The records also include laminated, fine grained sediments interpreted as deposits from sediment-laden meltwater plumes dated between 14,780 ± 220 and 14,300 ± 260 cal years BP. In Holocene sediments a diatom-rich fine grained layer dates 10,100 ± 150 to 9840 ± 200 cal years BP. The eleven cores have been stacked into one record with absolute age control from 35 AMS 14C dates. Together with oxygen isotope stratigraphy and contents of ice rafted detritus the stacked record provides a useful chronology tool for cores on the western Svalbard slope. Our study improves the age control of earlier well documented glacial events and shows that the maximum glacial state and the onset of the deglaciation both occurred 2500-3000 years earlier than previously reconstructed for the western Svalbard margin. The results indicate that during the last 30,000 years advance and retreat of the Svalbard-Barents Sea Ice Sheet was closely linked to the flow of Atlantic Water and Polar Water over the margin.
Carbon-14 wiggle-match dating of peat deposits: advantages and limitations
NASA Astrophysics Data System (ADS)
Blaauw, Maarten; van Geel, Bas; Mauquoy, Dmitri; van der Plicht, Johannes
2004-02-01
Carbon-14 wiggle-match dating (WMD) of peat deposits uses the non-linear relationship between 14C age and calendar age to match the shape of a series of closely spaced peat 14C dates with the 14C calibration curve. The method of WMD is discussed, and its advantages and limitations are compared with calibration of individual dates. A numerical approach to WMD is introduced that makes it possible to assess the precision of WMD chronologies. During several intervals of the Holocene, the 14C calibration curve shows less pronounced fluctuations. We assess whether wiggle-matching is also a feasible strategy for these parts of the 14C calibration curve. High-precision chronologies, such as obtainable with WMD, are needed for studies of rapid climate changes and their possible causes during the Holocene. Copyright
77 FR 24971 - National Institute of Neurological Disorders and Stroke; Notice of Closed Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2012-04-26
... Disorders and Stroke Initial Review Group; Neurological Sciences and Disorders C. Date: June 18-19, 2012..., Scientific Review Branch, Division of Extramural Research, NINDS, NIH, NSC, 6001 Executive Blvd., Suite 3204...: Neurological Sciences Training Initial Review Group; NST-2 Subcommittee. Date: June 25-26, 2012. Time: 8 a.m...
76 FR 14434 - Meetings of Humanities Panel
Federal Register 2010, 2011, 2012, 2013, 2014
2011-03-16
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75 FR 50007 - Meetings of Humanities Panel
Federal Register 2010, 2011, 2012, 2013, 2014
2010-08-16
...., Washington, DC 20506. FOR FURTHER INFORMATION CONTACT: Michael P. McDonald, Advisory Committee Management... subsections (c)(4), and (6) of section 552b of Title 5, United States Code. 1. Date: September 1, 2010. Time..., 2010 deadline. 2. Date: September 20, 2010. Time: 9 a.m. to 5 p.m. Room: 315. Program: This meeting...
Pyrolysis-combustion 14C dating of soil organic matter
Wang, Hongfang; Hackley, Keith C.; Panno, S.V.; Coleman, D.D.; Liu, J.C.-L.; Brown, J.
2003-01-01
Radiocarbon (14C) dating of total soil organic matter (SOM) often yields results inconsistent with the stratigraphic sequence. The onerous chemical extractions for SOM fractions do not always produce satisfactory 14C dates. In an effort to develop an alternative method, the pyrolysis-combustion technique was investigated to partition SOM into pyrolysis volatile (Py-V) and pyrolysis residue (Py-R) fractions. The Py-V fractions obtained from a thick glacigenic loess succession in Illinois yielded 14C dates much younger but more reasonable than the counterpart Py-R fractions for the soil residence time. Carbon isotopic composition (??13C) was heavier in the Py-V fractions, suggesting a greater abundance of carbohydrate- and protein-related constituents, and ??13C was lighter in the Py-R fractions, suggesting more lignin- and lipid-related constituents. The combination of 14C dates and ??13C values indicates that the Py-V fractions are less biodegradation resistant and the Py-R fractions are more biodegradation resistant. The pyrolysis-combustion method provides a less cumbersome approach for 14C dating of SOM fractions. With further study, this method may become a useful tool for analyzing unlithified terrestrial sediments when macrofossils are absent. ?? 2003 University of Washington. Published by Elsevier Inc. All rights reserved.
75 FR 71080 - Closed Meeting of the Department of Defense Wage Committee
Federal Register 2010, 2011, 2012, 2013, 2014
2010-11-22
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75 FR 14483 - Third Meeting: RTCA Special Committee 223: Airport Surface Wireless Communications
Federal Register 2010, 2011, 2012, 2013, 2014
2010-03-25
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76 FR 3643 - Center for Scientific Review; Notice of Closed Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2011-01-20
..., Bethesda, MD 20892. (301) 435- 1725. [email protected] . Name of Committee: Oncology 2--Translational Clinical Integrated Review Group, Clinical Oncology Study Section. Date: February 14-15, 2011. Time: 8 a.m..., Bethesda, MD 20892. 301-451-0131. [email protected] . Name of Committee: Oncology 1--Basic Translational...
76 FR 10410 - Sunshine Federal Register Notice
Federal Register 2010, 2011, 2012, 2013, 2014
2011-02-24
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75 FR 28075 - Sunshine Act Notice
Federal Register 2010, 2011, 2012, 2013, 2014
2010-05-19
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2012-09-17
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75 FR 76395 - Sunshine Act Notice
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2010-12-08
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75 FR 53349 - NASA Advisory Council; Commercial Space Committee; Meeting
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2010-08-31
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76 FR 57066 - Center for Scientific Review; Notice of Closed Meetings
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2011-09-15
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77 FR 30021 - Center for Scientific Review Notice of Closed Meetings
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2012-05-21
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75 FR 39008 - Environmental Management Site-Specific Advisory Board, Idaho National Laboratory
Federal Register 2010, 2011, 2012, 2013, 2014
2010-07-07
... Dry Storage. Waste Area Group--7 Update. In-Situ Grouting. Comment Resolution--Environmental... meeting be announced in the Federal Register. DATES: Wednesday, July 14, 2010 8 a.m.-5 p.m. Opportunities... management in the areas of environmental restoration, waste management, and related activities. Tentative...
78 FR 34036 - Sunshine Act Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2013-06-06
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78 FR 36549 - Sunshine Act; Notice of Meeting
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2013-06-18
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Forensic applications of 14C bomb-pulse dating
NASA Astrophysics Data System (ADS)
Zoppi, U.; Skopec, Z.; Skopec, J.; Jones, G.; Fink, D.; Hua, Q.; Jacobsen, G.; Tuniz, C.; Williams, A.
2004-08-01
After a brief review of the basics of 14C bomb-pulse dating, this paper presents two unique forensic applications. Particular attention is dedicated to the use of the 14C bomb-pulse to establish the time of harvest of illicit drugs such as heroin and opium. Preliminary measurements of 14C concentrations in milligram samples taken from seized drugs are presented. 14C bomb-pulse dating can determine whether drug distribution originates from stockpiles or recent manufacture, and support the action of law enforcement authorities against criminal organisations involved in drug trafficking. In addition, we describe the dating of wine vintages for a number of authenticated single label vintage red wines from the Barossa Valley - South Australia. Our results show that radiocarbon dating can be used to accurately determine wine vintages and therefore reveal the addition of unrelated materials of natural and synthetic origin.
Low-level (submicromole) environmental 14C metrology
NASA Astrophysics Data System (ADS)
Currie, L. A.; Kessler, J. D.; Marolf, J. V.; McNichol, A. P.; Stuart, D. R.; Donoghue, J. C.; Donahue, D. J.; Burr, G. S.; Biddulph, D.
2000-10-01
Accelerator mass spectrometry (AMS) measurements of environmental 14C have been employed during the past decade at the several micromole level (tens of μg carbon), but advanced research in the atmospheric and marine sciences demands still higher (μg) sensitivity, an extreme example being the determination of 14C in elemental or "black" carbon (BC) at levels of 2-10 μg per kg of Greenland snow and ice (Currie et al., 1998). A fundamental limitation for 14C AMS is Poisson counting statistics, which sets in at about 1 μg modern-C. Using the small sample (25 μg) AMS target preparation facility at NOSAMS (Pearson et al., 1998), and the microsample combustion-dilution facility at NIST, we have demonstrated an intrinsic modern-C quantification limit ( mQ) of ca. 0.9 μg, based on a 1-parameter fit to the empirical AMS variance function. (For environmental 14C, the modern carbon quantification limit is defined as that mass ( mQ) corresponding to 10% relative standard deviation (rsd) for the fraction of modern carbon, σ( fM)/ fM.) Stringent control, required for quantitative dilution factors (DL), is achieved with the NIST on-line manometric/mass spectrometry facility that compensates also for unsuspected trace impurities from vigorous chemical processing (e.g., acid digestion). Our current combustion blank is trivial (mean: 0.16 ± 0.02 μg C, n=13) but lognormally distributed (dispersion [σ]: 0.07 ± 0.01 μg). An iterative numerical expression is introduced to assess the quantitative impacts of fossil and modern carbon blank components on mQ; and a new "clean chemistry" BC processing system is described for the minimization of such blanks. For the assay of soot carbon in Greenland snow/ice, the overall processing blank has been reduced from nearly 7 μg total carbon to less than 1 μg, and is undetectable for BC.
NASA Astrophysics Data System (ADS)
Dutta, Koushik
2016-06-01
Radiocarbon, or 14C, is a radiometric dating method ideally suited for providing a chronological framework in archaeology and geosciences for timescales spanning the last 50,000 years. 14C is easily detectable in most common natural organic materials and has a half-life (5,730±40 years) relevant to these timescales. 14C produced from large-scale detonations of nuclear bombs between the 1950s and the early 1960s can be used for dating modern organic materials formed after the 1950s. Often these studies demand high-resolution chronology to resolve ages within a few decades to less than a few years. Despite developments in modern, high-precision 14C analytical methods, the applicability of 14C in high-resolution chronology is limited by short-term variations in atmospheric 14C in the past. This article reviews the roles of the principal natural drivers (e.g., solar magnetic activity and ocean circulation) and the anthropogenic perturbations (e.g., fossil fuel CO2 and 14C from nuclear and thermonuclear bombs) that are responsible for short-term 14C variations in the environment. Methods and challenges of high-resolution 14C dating are discussed.
NASA Astrophysics Data System (ADS)
Brill, Dominik; May, Simon Matthias; Mhammdi, Nadia; King, Georgina; Brückner, Helmut
2017-04-01
Fields of wave-emplaced blocks and boulders represent impressive evidence of cyclone and tsunami flooding over Holocene time scales. Unfortunately, their use for coastal hazard assessment is in many cases impeded by the absence of appropriate dating approaches, which are needed to generate robust chronologies. The commonly applied AMS-14C, U/Th or ESR dating of coral-reef rocks and marine organisms attached to the clasts depends on a - mostly hypothetical - coincidence between the organisms' death and boulder displacement, and inferred event chronologies may be biased by the marine 14C-reservoir effect and reworked organisms. Here we discuss the potential of the recently developed optically stimulated luminescence (OSL) surface exposure dating technique to directly date the relocation process of wave-emplaced boulders. By measuring the depth-dependent resetting of luminescence signals in exposed rock surfaces and comparing it to the signal-depth profiles of known-age samples, OSL surface exposure dating may be capable to model direct depositional ages for boulder transport. Thereby, it promises to overcome the limitations of existing dating techniques, and to decipher complex transport histories of clasts that underwent multiple phases of exposure and burial. The concept and some first results of OSL surface exposure dating shall be presented for coastal boulders from the Rabat coast, Morocco, where the preconditions for successful dating are promising: (i) Several coastal boulders show clear indication of overturning during wave transport in the form of downward-facing bio-eroded surfaces; (ii) the boulders are composed of different types of sandstone that contain quartz and feldspar, the required dosimeters for OSL dating; (iii) all boulders are of Holocene age and, therefore, in the dating range of OSL surface exposure dating. The main challenges for a successful application are the intensive bio-erosion and weathering of some surfaces exposed after transport, and the need for method calibration using surfaces with similar lithology and known exposure ages. However, in the best case, OSL surface exposure dating will provide quantitative information about the frequency-magnitude relationship of extreme wave events at the Rabat coast, in particular determining whether severe tsunami-induced flooding can be expected (e.g. during the 1755 Lisbon tsunami and similar events), or if boulders were only moved during flooding by exceptional winter storms.
Accuracy of post-bomb 137Cs and 14C in dating fluvial deposits
Ely, L.L.; Webb, R.H.; Enzel, Y.
1992-01-01
The accuracy and precision of 137Cs and 14C for dating post-1950 alluvial deposits were evaluated for deposits from known floods on two rivers in Arizona. The presence of 137Cs reliably indicates that deposition occurred after intensive above-ground nuclear testing was initiated around 1950. There was a positive correlation between the measured level of 137Cs activity and the clay content of the sediments, although 137Cs was detected even in sandy flood sediments with low clay content. 137Cs is a valuable dating tool in arid environments where organic materials for 14C or tree-ring dating are scarce and observational records are limited. The 14C activity measured in different types of fine organic detritus yielded dates within 1 to 8 yr of a 1980 flood deposit, and the accuracy was species-dependent. However, undifferentiated mixtures of fine organic materials from several post-bomb deposits of various ages repeatedly yielded dates between 1958 and 1962, and detrital charcoal yielded a date range of 1676-1939. In semiarid environments, the residence time of most types of organic debris precludes accurate annual resolution of post-bomb 14C dates. ?? 1992.
NASA Astrophysics Data System (ADS)
Tylmann, Wojciech; Turczyński, Marek; Kinder, Małgorzata
2009-10-01
This paper presents the dating results and basic analyses of recent sediments from Lake Piaseczno. The age of sediments was determined using the 210Pb method and constant flux: constant sedimentation (CF: CS) model. The estimated timescale was in agreement with the AMS14C date from the base of the core. The mean sediment accumulation rate during the last 100 years was calculated as 0.025 g cm-2 a-1. Based on the radiocarbon date, the rate of sediment accumulation below the 210Pb dating horizon was estimated as 0.066 g cm-2 a-1. The variability of main physical properties and sediment components along the core was analysed as well. The sediments were characterised by a very high water content (>80%). Carbonates were either not present or at a very low level (<1%). However, organic and minerogenic matter variability represents an interesting record of increasing erosion intensity in the catchment area. Analysis of archival cartographic materials demonstrated that the most likely reason for the enhanced transport of minerogenic matter to the lake was deforestation caused by human activity in the beginning of the 20th century.
Marine reservoir age variability and water mass distribution in the Iceland Sea
NASA Astrophysics Data System (ADS)
Eiríksson, Jón; Larsen, Gudrún; Knudsen, Karen Luise; Heinemeier, Jan; Símonarson, Leifur A.
2004-11-01
Lateglacial and Holocene tephra markers from Icelandic source volcanoes have been identified in five sediment cores from the North Icelandic shelf and correlated with tephra layers in reference soil sections in North Iceland and the GRIP ice core. Land-sea correlation of tephra markers, that have been radiocarbon dated with terrestrial material or dated by documentary evidence, provides a tool for monitoring reservoir age variability in the region. Age models developed for the shelf sediments north of Iceland, based on offshore tephrochronology on one hand and on calibrated AMS 14C datings of marine molluscs on the other, display major deviations during the last 4500 years. The inferred temporal variability in the reservoir age of the regional water masses exceeds by far the variability expected from the marine model calculations. The observed reservoir ages are generally considerably higher, by up to 450 years, than the standard model ocean. It is postulated that the intervals with increased and variable marine reservoir age reflect incursions of Arctic water masses derived from the East Greenland Current to the Iceland Sea and the North Icelandic shelf.
Northern peatland initiation lagged abrupt increases in deglacial atmospheric CH4.
Reyes, Alberto V; Cooke, Colin A
2011-03-22
Peatlands are a key component of the global carbon cycle. Chronologies of peatland initiation are typically based on compiled basal peat radiocarbon (14C) dates and frequency histograms of binned calibrated age ranges. However, such compilations are problematic because poor quality 14C dates are commonly included and because frequency histograms of binned age ranges introduce chronological artefacts that bias the record of peatland initiation. Using a published compilation of 274 basal 14C dates from Alaska as a case study, we show that nearly half the 14C dates are inappropriate for reconstructing peatland initiation, and that the temporal structure of peatland initiation is sensitive to sampling biases and treatment of calibrated 14C dates. We present revised chronologies of peatland initiation for Alaska and the circumpolar Arctic based on summed probability distributions of calibrated 14C dates. These revised chronologies reveal that northern peatland initiation lagged abrupt increases in atmospheric CH4 concentration at the start of the Bølling-Allerød interstadial (Termination 1A) and the end of the Younger Dryas chronozone (Termination 1B), suggesting that northern peatlands were not the primary drivers of the rapid increases in atmospheric CH4. Our results demonstrate that subtle methodological changes in the synthesis of basal 14C ages lead to substantially different interpretations of temporal trends in peatland initiation, with direct implications for the role of peatlands in the global carbon cycle.
78 FR 13882 - Notice of Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2013-03-01
... site, http://nac.samhsa.gov/ , or by contacting Crystal C. Saunders, Acting Designated Federal Official.... Date/Time/Type: April 10, 2013, 9:00 a.m.-5:30 p.m. EST: (OPEN). Place: SAMHSA Building, Sugarloaf Conference Room. Contact: Crystal C. Saunders, Acting, Designated Federal Official, SAMHSA, CMHS, National...
Radiocarbon dating of terrestrial carbonates
Pigati, Jeffrey S.; Rink, W. Jack; Thompson, Jeroen
2014-01-01
Terrestrial carbonates encompass a wide range of materials that potentially could be used for radiocarbon (14C) dating. Biogenic carbonates, including shells and tests of terrestrial and aquatic gastropods, bivalves, ostracodes, and foraminifera, are preserved in a variety of late Quaternary deposits and may be suitable for 14C dating. Primary calcareous deposits (marls, tufa, speleothems) and secondary carbonates (rhizoliths, fracture fill, soil carbonate) may also be targeted for dating when conditions are favorable. This chapter discusses issues that are commonly encountered in 14C dating of terrestrial carbonates, including isotopic disequilibrium and open-system behavior, as well as methods used to determine the reliability of ages derived from these materials. Recent methodological advancements that may improve the accuracy and precision of 14C ages of terrestrial carbonates are also highlighted.
Propagation of Sound Through the Atmosphere: Effects of Ground Cover
1978-06-19
Over Simulated Ground Cover", J. Acoust. Soc. Am. 49, 1069-1075 ( 1971 ). 8 J. . . Piercy, T. F. W. Embleton, and L. C. Sutherland, "A Review of Noise...FlPST., AM KALL C AND SUBMOUTINL NAIAE *’t.ATfl"v hISTTAD 0t "COPPIS?". C PANG4N IS Ali tUIT 01* IAANG4Kp [XCLUSVIfo UT NTt.14VENINC, Fj)ITSq C RANG
High-speed photometry of Gaia14aae: an eclipsing AM CVn that challenges formation models
NASA Astrophysics Data System (ADS)
Green, M. J.; Marsh, T. R.; Steeghs, D. T. H.; Kupfer, T.; Ashley, R. P.; Bloemen, S.; Breedt, E.; Campbell, H. C.; Chakpor, A.; Copperwheat, C. M.; Dhillon, V. S.; Hallinan, G.; Hardy, L. K.; Hermes, J. J.; Kerry, P.; Littlefair, S. P.; Milburn, J.; Parsons, S. G.; Prasert, N.; van Roestel, J.; Sahman, D. I.; Singh, N.
2018-05-01
AM CVn-type systems are ultracompact, hydrogen-deficient accreting binaries with degenerate or semidegenerate donors. The evolutionary history of these systems can be explored by constraining the properties of their donor stars. We present high-speed photometry of Gaia14aae, an AM CVn with a binary period of 49. 7 min and the first AM CVn in which the central white dwarf is fully eclipsed by the donor star. Modelling of the light curves of this system allows for the most precise measurement to date of the donor mass of an AM CVn, and relies only on geometric and well-tested physical assumptions. We find a mass ratio q = M2/M1 = 0.0287 ± 0.0020 and masses M1 = 0.87 ± 0.02 M⊙ and M2 = 0.0250 ± 0.0013 M⊙. We compare these properties to the three proposed channels for AM CVn formation. Our measured donor mass and radius do not fit with the contraction that is predicted for AM CVn donors descended from white dwarfs or helium stars at long orbital periods. The donor properties we measure fall in a region of parameter space in which systems evolved from hydrogen-dominated cataclysmic variables are expected, but such systems should show spectroscopic hydrogen, which is not seen in Gaia14aae. The evolutionary history of this system is therefore not clear. We consider a helium-burning star or an evolved cataclysmic variable to be the most likely progenitors, but both models require additional processes and/or fine-tuning to fit the data. Additionally, we calculate an updated ephemeris which corrects for an anomalous time measurement in the previously published ephemeris.
77 FR 63844 - Center for Scientific Review; Notice of Closed Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2012-10-17
... DEPARTMENT OF HEALTH AND HUMAN SERVICES National Institutes of Health Center for Scientific Review... Review, National Institutes of Health, 6701 Rockledge Drive, Room 3224, MSC 7808, Bethesda, MD 20892, 301...; Small Business: Oral, Dental and Craniofacial Sciences. Date: November 14-15, 2012. Time: 8:00 a.m. to 5...
77 FR 76569 - Sunshine Act Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2012-12-28
... Regulatory Commission [NRC-2012- 0002]. DATE: Weeks of December 24, 31, 2012, January 7, 14, 21, 28, 2013... Closed. Week of December 24, 2012 There are no meetings scheduled for the week of December 24, 2012. Week.... Week of January 7, 2013--Tentative Tuesday, January 8, 2013 9:00 a.m. Briefing on Fort Calhoun (Public...
76 FR 1653 - Sunshine Federal Register Notice
Federal Register 2010, 2011, 2012, 2013, 2014
2011-01-11
... MEETINGS: Nuclear Regulatory Commission. DATES: Weeks of January 10, 17, 24, 31, February 7, 14, 2011... January 17, 2011. Week of January 24, 2011--Tentative Monday, January 24, 2011 1 p.m. Briefing on Safety... of February 7, 2011--Tentative Tuesday, February 8, 2011 9 a.m. Briefing on Implementation of Part 26...
78 FR 64964 - Office of the Director, National Institutes of Health; Notice of Closed Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2013-10-30
... Federal Domestic Assistance Program Nos. 93.14, Intramural Research Training Award; 93.22, Clinical Research Loan Repayment Program for Individuals from Disadvantaged Backgrounds; 93.232, Loan Repayment... on Biomedical and Behavioral Research Facilities. Date: November 12-13, 2013. Time: 8:00 a.m. to 5:00...
75 FR 70273 - National Heart, Lung, and Blood Institute; Notice of Closed Meetings
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2010-11-17
... Institute Special Emphasis Panel, The Antihypertensive and Lipid-Lowering to Prevent Heart Attack Trial... Research Demonstration and Dissemination Projects. Date: December 14, 2010. Time: 8 a.m. to 2 p.m. Agenda... Assistance Program Nos. 93.233, National Center for Sleep Disorders Research; 93.837, Heart and Vascular...
78 FR 6124 - Office of the Director, National Institutes of Health; Notice of Closed Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2013-01-29
... Program Nos. 93.14, Intramural Research Training Award; 93.22, Clinical Research Loan Repayment Program... Loan Repayment Program; 93.187, Undergraduate Scholarship Program for Individuals from Disadvantaged... Programs Special Emphasis Panel; K01 Applications. Date: February 21, 2013. Time: 8:00 a.m. to 5:00 p.m...
78 FR 12767 - National Institute of Allergy and Infectious Diseases; Notice of Closed Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2013-02-25
... Allergy and Infectious Diseases; Notice of Closed Meeting Pursuant to section 10(d) of the Federal... Infectious Diseases Special Emphasis Panel; NIAID Peer Review Meeting. Date: March 14, 2013. Time: 11:00 a.m... Nos. 93.855, Allergy, Immunology, and Transplantation Research; 93.856, Microbiology and Infectious...
75 FR 33817 - National Cancer Institute; Notice of Closed Meeting
Federal Register 2010, 2011, 2012, 2013, 2014
2010-06-15
... DEPARTMENT OF HEALTH AND HUMAN SERVICES National Institutes of Health National Cancer Institute; Notice of Closed Meeting Pursuant to section 10(d) of the Federal Advisory Committee Act, as amended (5 U... for Collaborative Interaction for Minority Institution. Date: July 13-14, 2010 Time: 8 a.m. to 5 p.m...
77 FR 51579 - Meetings of Humanities Panel; Correction
Federal Register 2010, 2011, 2012, 2013, 2014
2012-08-24
... Voyatzis, Committee Management Officer, at (202) 606-8322. Correction In the Federal Register of August 14... replace with: 9. Date: September 24, 2012. Time: 8:30 a.m. to 5:00 p.m. Room: 315. This meeting will discuss applications for the Bridging Cultures at Community Colleges: Request for Proposals for a...
The timing of deglacial circulation changes in the Atlantic
NASA Astrophysics Data System (ADS)
Waelbroeck, C.; Skinner, L.; Gersonde, R.; Mackensen, A.; Michel, E.; Labeyrie, L. D.; Duplessy, J.
2009-12-01
We present new benthic isotopic data from core MD07-3076 retrieved in the Atlantic sector of the Southern Ocean (44°09’S, 14°13’W, 3770 m water depth), and place them in the context of well-dated published Atlantic benthic foraminifera isotopic records covering the last 30 ky. Dating of core MD07-3076 was achieved by a combination of 14C AMS measurements on planktonic foraminifera and correlation of sea surface temperature signals derived from both planktonic foraminifera Mg/Ca and census counts, with Antarctic ice isotopic records (Skinner et al., submitted). Comparison of benthic isotopic records from various depths in the North and South Atlantic reveals that circulation changes over the last deglaciation did not take place simultaneously in the 1000-2000 m and in the 3000-4500 m depth ranges. Circulation changes first occurred at lower depth, causing large and relatively rapid changes in benthic δ18O and δ13C at the beginning of Heinrich Stadial 1 (HS1) and the Younger Dryas. Below 3000 m depth, North Atlantic deep water hydrology changed only gradually until a large increase in deep water ventilation took place, resulting from the resumption of North Atlantic Deep Water formation at the end of HS1. In contrast, our deep South Atlantic record indicates that Circumpolar Deep Water around 3800 m depth remained quasi-isolated from northern water masses until the end of HS1. Furthermore, our record shows that core MD07-3076 site was then flushed with better ventilated waters for a few hundred years from ~14.5 to 14 calendar ky BP, before benthic δ18O and δ13C values resumed their progression towards Holocene levels. In conclusion, this set of well-dated Atlantic records demonstrates that benthic δ18O records followed different time evolutions across the last deglaciation, depending on the site latitude and water depth, so that benthic δ18O can not be used as a global correlation tool with a precision better than 3 ky.
Scarabino, Carla; Lubritto, Carmine; Proto, Antonio; Rubino, Mauro; Fiengo, Gilda; Marzaioli, Fabio; Passariello, Isabella; Busiello, Gaetano; Fortunato, Antonietta; Alfano, Davide; Sabbarese, Carlo; Rogalla, Detlef; De Cesare, Nicola; d'Onofrio, Antonio; Terrasi, Filippo
2006-06-01
Human bones recovered from the archaeological site of Pontecagnano (Salerno, Italy) have been studied to reconstruct the diet of an Etrurian population. Two different areas were investigated, named Library and Sant' Antonio, with a total of 44 tombs containing human skeletal remains, ranging in age from the 8th to the 3rd century B.C. This time span was confirmed by 14C dating obtained using Accelerator Mass Spectrometry (AMS) on one bone sample from each site. Atomic Absorption Spectrometry (AAS) was used to extract information about the concentration of Sr, Zn, Ca elements in the bone inorganic fraction, whilst stable isotope ratio measurements (IRMS) were carried out on bone collagen to obtain the delta13C and delta15N. A reliable technique has been used to extract and separate the inorganic and organic fractions of the bone remains. Both IRMS and AAS results suggest a mixed diet including C3 plant food and herbivore animals, consistent with archaeological indications.
77 FR 8877 - ICD-9-CM Coordination and Maintenance (C&M) Committee Meeting
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2012-02-15
... Coordination and Maintenance (C&M) Committee Meeting National Center for Health Statistics (NCHS... Coordination and Maintenance (C&M) Committee meeting. Time and Date: 9 a.m.-5:30 p.m., March 5, 2012. Place... entering the building. Attendees who wish to attend the ICD- 9-CM C&M meeting on March 5, 2012, must submit...
Rocky Mountain Arsenal North Boundary Expansion Containment System Construction Foundation Report
1984-03-01
APPENDIX C Am-Built Wall Data * 4 ’ FIG Timur TitleLa 2-1 Grain Size Analysis Soil A 2-3ii 2-2 Grain Size Analysis Soil 3 2-3iii 2-3 Finite Difference...letter request for investigation from the Great West- ern Sugar Company to Brigadier General C. S. Shadle, IA, dated 4 June 1954. A subsequent letter...from the Great Western Sugar Company to the Chief of Engineering and Service Division, IKA, dated 18 June 1954, related sore information concerning
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2010-03-09
... MILLENNIUM CHALLENGE CORPORATION [MCC FR 10-03] Notice of the March 24, 2010 Millennium Challenge... and Date: 10 a.m. to 12 p.m., Wednesday, March 24, 2010. Place: Department of State, 2201 C Street, NW... consideration of classified information and the meeting will be closed to the public. Dated: March 5, 2010...
NASA Astrophysics Data System (ADS)
Macario, K.; Coe, H. H.; Gomes, J.; Oliveira, F.; Gomes, P.; Carvalho, C.; Linares, R.; Alves, E.; Santos, G. M.
2012-12-01
The Brazilian Southeast was formerly occupied by Atlantic forest before the arrival of Europeans in the 16th century, when deforestation slowly started to take place. To understand the variations in the vegetation of Cabo Frio during the Quaternary, and possibly identify when they roughly took place, we make use of soil phytolith identification (as proxy), stable isotopes analyses and 14C dating of soil profiles. Nowadays, those are helpful tools to reveal the palaeoenvironmental secrets hidden below-ground. The soil profile studied, which was divided in 4 horizons ranging from 10 and 115 cm in depth, was collected in the surroundings of Cabo Frio, in the Rio de Janeiro (RJ), Southeastern coast of Brazil. Its total organic carbon (TOC) varied from 0.42 to 1.11% (for the different horizons), when its δ13C values ranged from -18.81 (topsoil) to -23.72‰ (~ 80cm deep). Phytolith D/P index varied from 0.1 to 0.21. Due to the low carbon content within soil horizons, soil organic matter (SOM) fractions were chosen for isotopic analyses. Mostly of the 14C-SOM analyses were performed in a newer 14C facility, which runs a NEC 250 kV Single Stage Accelerator Mass Spectrometry system, the Radiocarbon Laboratory of the Fluminense Federal University (LAC-UFF) located in Niteroi, RJ. In brief, before measurements could be performed, the soil samples were treated with HCl 1.0M to remove carbonates, then combusted in sealed evacuated pre-baked tubes, cryogenically clean and converted to graphite (as decribed in Xu et al. 2007). In order to verify the distribution of 14C ages of different chemical soil fractions (Pessenda et al. 2001), a refractory C fraction (humin) was extracted from the topsoil horizon, and also converted to graphite following established protocols (Santos et al. 2007a,b). Due to its very low carbon mass (<<50mgC), this graphite target was processed and measured at the Keck-CCAMS Facility at University of California, Irvine. (UCI), which runs a modified NEC AMS-system (NEC 0.5MV 1.5SDH-2 AMS system). Other SOM samples from the same profile were also 14C-AMS measured. Control and background samples, subjected to the same procedures as unknown samples, were also processed and measured by both facilities. All 14C age results were calibrated using the OxCal4 software (Bronk Ramsey 2009) coupled with the Southern Hemisphere (SHCal04) dataset (McCormac et al. 2004). Phytolith and isotope preliminary analysis indicate open vegetation with few trees, and predominantly C3 grasses for the last 10 ka yrs. The deepest horizon is the one with greater phytoliths stock and D/P index, indicating a more humid environment in the beginning of the Holocene. A detailed discussion of the results will be presented. References: Bronk Ramsey, C. (2009) Radiocarbon, 51(1): 337-360 McCormac et al. (2004) Radiocarbon 46(3):1087-1092 Pessenda et al. (2001) Radiocarbon 43 (2B): 595 - 601 Santos et al. (2007a) Nuclear Instruments and Methods in Physics Research B (259): 293-302 Santos et al. (2007b) Radiocarbon 49(2): 255-269 Xu et al. (2007) Nuclear Instruments and Methods in Physics Research B 259: 320 - 329
Recent advancements in monolithic AlGaAs/GaAs solar cells for space applications
NASA Technical Reports Server (NTRS)
Wickham, K. R.; Chung, B.-C.; Klausmeier-Brown, M.; Kuryla, M. S.; Ristow, M. Ladle; Virshup, G. F.; Werthen, J. G.
1991-01-01
High efficiency, two terminal, multijunction AlGaAs/GaAs solar cells were reproducibly made with areas of 0.5 sq cm. The multiple layers in the cells were grown by Organo Metallic Vapor Phase Epitaxy (OMVPE) on GaAs substrates in the n-p configuration. The upper AlGaAs cell has a bandgap of 1.93 eV and is connected in series to the lower GaAs cell (1.4 eV) via a metal interconnect deposited during post-growth processing. A prismatic coverglass is installed on top of the cell to reduce obscuration caused by the gridlines. The best 0.5 sq cm cell has a two terminal efficiency of 23.0 pct. at 1 sun, air mass zero (AM0) and 25 C. To date, over 300 of these cells were grown and processed for a manufacturing demonstration. Yield and efficiency data for this demonstration are presented. As a first step toward the goal of a 30 pct. efficient cell, a mechanical stack of the 0.5 sq cm cells described above, and InGaAsP (0.95 eV) solar cells was made. The best two terminal measurement to date yields an efficiency of 25.2 pct. AM0. This is the highest reported efficiency of any two terminal, 1 sun space solar cell.
Northern peatland initiation lagged abrupt increases in deglacial atmospheric CH4
Reyes, Alberto V.; Cooke, Colin A.
2011-01-01
Peatlands are a key component of the global carbon cycle. Chronologies of peatland initiation are typically based on compiled basal peat radiocarbon (14C) dates and frequency histograms of binned calibrated age ranges. However, such compilations are problematic because poor quality 14C dates are commonly included and because frequency histograms of binned age ranges introduce chronological artefacts that bias the record of peatland initiation. Using a published compilation of 274 basal 14C dates from Alaska as a case study, we show that nearly half the 14C dates are inappropriate for reconstructing peatland initiation, and that the temporal structure of peatland initiation is sensitive to sampling biases and treatment of calibrated 14C dates. We present revised chronologies of peatland initiation for Alaska and the circumpolar Arctic based on summed probability distributions of calibrated 14C dates. These revised chronologies reveal that northern peatland initiation lagged abrupt increases in atmospheric CH4 concentration at the start of the Bølling–Allerød interstadial (Termination 1A) and the end of the Younger Dryas chronozone (Termination 1B), suggesting that northern peatlands were not the primary drivers of the rapid increases in atmospheric CH4. Our results demonstrate that subtle methodological changes in the synthesis of basal 14C ages lead to substantially different interpretations of temporal trends in peatland initiation, with direct implications for the role of peatlands in the global carbon cycle. PMID:21368146
Operation of the “Small” BioAMS spectrometers at CAMS: Past and future prospects
Ognibene, T. J.; Haack, K. W.; Bench, G.; ...
2015-05-26
A summary of results from the solid samples run on our compact 1 MV AMS system over its 13.5 years of operation is presented. On average 7065 samples per year were measured with that average dropping to 3278 samples per year following the deployment of our liquid sample capability. Although the dynamic range of our spectrometer is 4.5 orders in magnitude, most of the measured graphitic samples had 14C/C concentrations between 0.1 and 1 modern. Furthermore, the measurements of our ANU sucrose standard followed a Gaussian distribution with an average of 1.5082 ± 0.0134 modern. The LLNL biomedical AMS programmore » supported many different types of experiments, however, the large majority of samples measured were derived from animal model systems. We have transitioned all of our biomedical AMS measurements to the recently installed 250 kV SSAMS instrument with good agreement compared in measured 14C/C isotopic ratios between sample splits. We then present results from replacement of argon stripping gas with helium in the SSAMS with a 22% improvement in ion transmission through the accelerator and high-energy analyzing magnet.« less
Operation of the “Small” BioAMS Spectrometers at CAMS: Past and Future Prospects
Ognibene, T.J.; Haack, K.W.; Bench, G.; Brown, T.A.; Turteltaub, K.W.
2015-01-01
A summary of results from the solid samples run on our compact 1 MV AMS system over its 13.5 years of operation is presented. On average 7065 samples per year were measured with that average dropping to 3278 samples per year following the deployment of our liquid sample capability. Although the dynamic range of our spectrometer is 4.5 orders in magnitude, most of the measured graphitic samples had 14C/C concentrations between 0.1 and 1 modern. The measurements of our ANU sucrose standard followed a Gaussian distribution with an average of 1.5082 ± 0.0134 modern. The LLNL biomedical AMS program supported many different types of experiments, however, the large majority of samples measured were derived from animal model systems. We have transitioned all of our biomedical AMS measurements to the recently installed 250 kV SSAMS instrument with good agreement compared in measured 14C/C isotopic ratios between sample splits. Finally, we present results from replacement of argon stripping gas with helium in the SSAMS with a 22% improvement in ion transmission through the accelerator and high-energy analyzing magnet. PMID:26456990
Late Holocene Environmental Changes from NY-NJ Estuaries
NASA Technical Reports Server (NTRS)
Peteet, Dorothy M.; Wong, Jennifer K.
2000-01-01
High-resolution records of environmental change in the lower Hudson estuary are quite rare. We present preliminary data from several marshes in the New York- New Jersey region in order to understand the late Holocene environmental history of this region. Our project includes salt marsh cores from Hackensack, Piermont, Staten Island, and Jamaica Bay. Our preliminary research has focused on a 11.15 m. sediment core from Piermont Marsh, New York (40 N, 74 W) in an attempt to document the Holocene environmental history of the region. Lithology, loss-on-ignition (LOI), pollen, plant macrofossils, charcoal, and foraminifera were analyzed. Core lithology consists of peat, silts, and clays that vary in color and texture. The base of the core is AMS C-14 dated to 4190 yr BP. Preliminary low-resolution analysis of the core to date includes sampling at the 1-meter interval throughout the core. LOI of the sediments ranges from 1% to 85%. Average rate of deposition is about .26 cm/yr. Major changes in pollen percentages are visible throughout the core.
78 FR 42528 - National Institute of Neurological Disorders and Stroke; Notice of Closed Meeting
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2013-07-16
... DEPARTMENT OF HEALTH AND HUMAN SERVICES National Institutes of Health National Institute of Neurological Disorders and Stroke; Notice of Closed Meeting Pursuant to section 10(d) of the Federal Advisory... Disorders and Stroke Special Emphasis Panel; EUREKA. Date: August 14, 2013. Time: 8:00 a.m. to 6:00 p.m...
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2012-03-15
... Migratory Pelagic Resources of the Gulf of Mexico and South Atlantic; Closure AGENCY: National Marine...: Temporary rule; closure. SUMMARY: NMFS closes the commercial sector of the coastal migratory pelagic fishery... king mackerel resource. DATES: This rule is effective 12:01 a.m., local time, March 14, 2012, through...
76 FR 64388 - Advisory Committee for Polar Programs; Notice of Meeting
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2011-10-18
... NATIONAL SCIENCE FOUNDATION Advisory Committee for Polar Programs; Notice of Meeting In accordance with Federal Advisory Committee Act (Pub. L. 92-463, as amended), the National Science Foundation announces the following meeting: Name: Advisory Committee for Polar Programs (1130). Date/Time: November 14, 2011, 8:30 a.m. to 5:30 p.m.; November 15...
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2011-03-18
... announces the date, time and location of the meeting, which will be open to the public. The purpose of..., from 8 a.m. to 12 Noon. A public comment period will take place on April 14, 2011, between 3:15 p.m... to attend or speak at the meeting may [[Page 15044
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2011-04-12
.... Customs and Border Protection by calling (202) 344-1060. The inquiry may also be sent to [email protected] 1060. Dated: April 1, 2011. Ira S. Reese, Executive Director, Laboratories and Scientific Services. [FR Doc. 2011-8688 Filed 4-11-11; 8:45 am] BILLING CODE 9111-14-P ...
Graphite sample preparation for AMS in a high pressure and temperature press
Rubin, M.; Mysen, B.O.; Polach, H.
1984-01-01
A high pressure-high temperature press is used to make target material for accelerator mass spectrometry. Graphite was produced from typical 14C samples including oxalic acid and carbonates. Beam strength of 12C was generally adequate, but random radioactive contamination by 14C made age measurements impractical. ?? 1984.
Graphite sample preparation for AMS in a high pressure and temperature press
Rubin, Meyer; Mysen, Bjorn O.; Polach, Henry
1984-01-01
A high pressure-temperature press is used to make target material for accelerator mass spectrometry. Graphite was produced from typical **1**4C samples including oxalic acid and carbonates. Beam strength of **1**2C was generally adequate, but random radioactive contamination by **1**4C made age measurements impractical.
Installation of hybrid ion source on the 1-MV LLNL BioAMS spectrometer
Ognibene, T. J.; Salazar, G. A.
2012-01-01
A second ion source was recently installed onto the LLNL 1-MV AMS spectrometer, which is dedicated to the quantification of 14C and 3H within biochemical samples. This source is unique among the other LLNL cesium sputter ion sources in that it can ionize both gaseous and solid samples. Also, the injection beam line has been designed to directly measure 14C/12C isotope ratios without the need for electrostatic bouncing. Preliminary tests show that this source can ionize transient CO2 gas pulses containing less than 1 ug carbon with approximately 1.5% efficiency. We demonstrate that the measured 14C/12C isotope ratio is largely unaffected by small drifts in the argon stripper gas density. We also determine that a tandem accelerating voltage of 670 kV enables the highest 14C transmission through the system. Finally, we describe a series of performance tests using solid graphite targets spanning nearly 3 orders in magnitude dynamic range and compare the results to our other ion source. PMID:23467295
Zazula, Grant D; MacPhee, Ross D E; Metcalfe, Jessica Z; Reyes, Alberto V; Brock, Fiona; Druckenmiller, Patrick S; Groves, Pamela; Harington, C Richard; Hodgins, Gregory W L; Kunz, Michael L; Longstaffe, Fred J; Mann, Daniel H; McDonald, H Gregory; Nalawade-Chavan, Shweta; Southon, John R
2014-12-30
Existing radiocarbon ((14)C) dates on American mastodon (Mammut americanum) fossils from eastern Beringia (Alaska and Yukon) have been interpreted as evidence they inhabited the Arctic and Subarctic during Pleistocene full-glacial times (∼ 18,000 (14)C years B.P.). However, this chronology is inconsistent with inferred habitat preferences of mastodons and correlative paleoecological evidence. To establish a last appearance date (LAD) for M. americanum regionally, we obtained 53 new (14)C dates on 36 fossils, including specimens with previously published dates. Using collagen ultrafiltration and single amino acid (hydroxyproline) methods, these specimens consistently date to beyond or near the ∼ 50,000 y B.P. limit of (14)C dating. Some erroneously "young" (14)C dates are due to contamination by exogenous carbon from natural sources and conservation treatments used in museums. We suggest mastodons inhabited the high latitudes only during warm intervals, particularly the Last Interglacial [Marine Isotope Stage (MIS) 5] when boreal forests existed regionally. Our (14)C dataset suggests that mastodons were extirpated from eastern Beringia during the MIS 4 glacial interval (∼ 75,000 y ago), following the ecological shift from boreal forest to steppe tundra. Mastodons thereafter became restricted to areas south of the continental ice sheets, where they suffered complete extinction ∼ 10,000 (14)C years B.P. Mastodons were already absent from eastern Beringia several tens of millennia before the first humans crossed the Bering Isthmus or the onset of climate changes during the terminal Pleistocene. Local extirpations of mastodons and other megafaunal populations in eastern Beringia were asynchrononous and independent of their final extinction south of the continental ice sheets.
Zazula, Grant D.; MacPhee, Ross D. E.; Metcalfe, Jessica Z.; Reyes, Alberto V.; Brock, Fiona; Druckenmiller, Patrick S.; Groves, Pamela; Harington, C. Richard; Hodgins, Gregory W. L.; Kunz, Michael L.; Longstaffe, Fred J.; Mann, Daniel H.; McDonald, H. Gregory; Nalawade-Chavan, Shweta; Southon, John R.
2014-01-01
Existing radiocarbon (14C) dates on American mastodon (Mammut americanum) fossils from eastern Beringia (Alaska and Yukon) have been interpreted as evidence they inhabited the Arctic and Subarctic during Pleistocene full-glacial times (∼18,000 14C years B.P.). However, this chronology is inconsistent with inferred habitat preferences of mastodons and correlative paleoecological evidence. To establish a last appearance date (LAD) for M. americanum regionally, we obtained 53 new 14C dates on 36 fossils, including specimens with previously published dates. Using collagen ultrafiltration and single amino acid (hydroxyproline) methods, these specimens consistently date to beyond or near the ∼50,000 y B.P. limit of 14C dating. Some erroneously “young” 14C dates are due to contamination by exogenous carbon from natural sources and conservation treatments used in museums. We suggest mastodons inhabited the high latitudes only during warm intervals, particularly the Last Interglacial [Marine Isotope Stage (MIS) 5] when boreal forests existed regionally. Our 14C dataset suggests that mastodons were extirpated from eastern Beringia during the MIS 4 glacial interval (∼75,000 y ago), following the ecological shift from boreal forest to steppe tundra. Mastodons thereafter became restricted to areas south of the continental ice sheets, where they suffered complete extinction ∼10,000 14C years B.P. Mastodons were already absent from eastern Beringia several tens of millennia before the first humans crossed the Bering Isthmus or the onset of climate changes during the terminal Pleistocene. Local extirpations of mastodons and other megafaunal populations in eastern Beringia were asynchrononous and independent of their final extinction south of the continental ice sheets. PMID:25453065
78 FR 62639 - National Institute on Aging; Notice of Closed Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2013-10-22
... Emphasis Panel; Alzheimer's Disease Research Centers. Date: October 30-31, 2013. Time: 8:00 a.m. to 4:00 p... U.S.C. App.), notice is hereby given of the following meetings. The meetings will be closed to the public in accordance with the provisions set forth in sections 552b(c)(4) and 552b(c)(6), Title 5 U.S.C...
76 FR 1625 - National Institute on Aging; Notice of Closed Meetings
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2011-01-11
... for Alzheimer's Disease 2011/05. Date: February 3, 2011. Time: 11 a.m. to 3 p.m. Agenda: To review and... U.S.C. App.), notice is hereby given of the following meetings. The meetings will be closed to the public in accordance with the provisions set forth in sections 552b(c)(4) and 552b(c)(6), Title 5 U.S.C...
77 FR 14026 - National Institute on Aging; Notice of Closed Meeting
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2012-03-08
..., Aging and Alzheimer's Disease. Date: March 27, 2012. Time: 8 a.m. to 5 p.m. Agenda: To review and....S.C. App.), notice is hereby given of the following meeting. The meeting will be closed to the public in accordance with the provisions set forth in sections 552b(c)(4) and 552b(c)(6), Title 5 U.S.C...
78 FR 20933 - Center for Scientific Review; Notice of Closed Meeting
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2013-04-08
....S.C. App.), notice is hereby given of the following meeting. The meeting will be closed to the public in accordance with the provisions set forth in sections 552b(c)(4) and 552b(c)(6), Title 5 U.S.C...: Viruses. Date: April 29-30, 2013. Time: 8:00 a.m. to 6:00 p.m. Agenda: To review and evaluate grant...
77 FR 40623 - Center for Scientific Review; Notice of Closed Meetings
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2012-07-10
... U.S.C. App.), notice is hereby given of the following meetings. The meetings will be closed to the public in accordance with the provisions set forth in sections 552b(c)(4) and 552b(c)(6), Title 5 U.S.C...: HIV Therapeutics. Date: August 2-3, 2012. Time: 10 a.m. to 5 p.m. Agenda: To review and evaluate grant...
DOE Office of Scientific and Technical Information (OSTI.GOV)
Peteet, D. M.; Beh, M.; Orr, C.
The conventionally accepted ages of the Last Glacial Maximum (LGM) retreat of the southeastern Laurentide Ice Sheet (LIS) are 26–21 cal. kyr (derived from bulk-sediment radiocarbon ages) and 28–23 cal. kyr (varve estimates). By utilizing accelerator mass spectrometry (AMS) 14C dating of earliest macrofossils in 13 lake/bog inorganic clays, we find that vegetation first appeared on the landscape at 16–15 cal. kyr, suggesting ice had not retreated until that time. The gap between previous age estimates and ours is significant and has large implications for our understanding of ocean-atmosphere linkages. Older ages imply extreme Arctic conditions for 9–5 cal kyr;more » a landscape with no ice, yet no deposition in lakes. Also, our new AMS chronology of LIS retreat is consistent with marine evidence of deglaciation from the N. Atlantic, showing significant freshwater input and sea level rise only after 19 cal kyr with a cold meltwater lid, perhaps delaying ice melt.« less
Peteet, D. M.; Beh, M.; Orr, C.; ...
2012-06-15
The conventionally accepted ages of the Last Glacial Maximum (LGM) retreat of the southeastern Laurentide Ice Sheet (LIS) are 26–21 cal. kyr (derived from bulk-sediment radiocarbon ages) and 28–23 cal. kyr (varve estimates). By utilizing accelerator mass spectrometry (AMS) 14C dating of earliest macrofossils in 13 lake/bog inorganic clays, we find that vegetation first appeared on the landscape at 16–15 cal. kyr, suggesting ice had not retreated until that time. The gap between previous age estimates and ours is significant and has large implications for our understanding of ocean-atmosphere linkages. Older ages imply extreme Arctic conditions for 9–5 cal kyr;more » a landscape with no ice, yet no deposition in lakes. Also, our new AMS chronology of LIS retreat is consistent with marine evidence of deglaciation from the N. Atlantic, showing significant freshwater input and sea level rise only after 19 cal kyr with a cold meltwater lid, perhaps delaying ice melt.« less
77 FR 67826 - Office of the Director, National Institutes of Health; Notice of Meeting
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2012-11-14
... Committee Act, as amended (5 U.S.C. App.), notice is hereby given of a meeting of the Recombinant DNA... Committee: Recombinant DNA Advisory Committee Date: December 4, 2012. Time: 1:50 p.m. to 5:30 p.m. Date: December 5, 2012. Time: 8:30 a.m. to 3:00 p.m. Agenda: The NIH Recombinant DNA Advisory Committee (RAC...
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2013-05-02
... from EDIC/GOKind Type I Diabetes Clinical Studies (DP3). Date: June 10, 2013. Time: 10:00 a.m. to 12:30... Panel; PAR-13-013-Research Using Biosamples from TrialNet/DPT-1 Type Diabetes Clinical Studies (DP3... Institute of Diabetes and Digestive and Kidney Diseases Special Emphasis Panel; DDK-C Conflicts. Date: June...
Nieto Penalver, Carlos G; Morin, Danièle; Cantet, Franck; Saurel, Olivier; Milon, Alain; Vorholt, Julia A
2006-01-23
Acyl-homoserine lactones (acyl-HSLs) have emerged as important regulatory molecules for many gram-negative bacteria. We have found that Methylobacterium extorquens AM1, a member of the pink-pigmented facultative methylotrophs commonly present on plant surfaces, produces several acyl-HSLs depending upon the carbon source. A novel HSL was discovered with a double unsaturated carbon chain (N-(tetradecenoyl)) (C14:2) and characterized by MS and proton NMR. This long-chain acyl-HSL is synthesized by MlaI that also directs synthesis of C14:1-HSL. The Alphaproteobacterium also produces N-hexanoyl-HSL (C6-HSL) and N-octanoyl-HSL (C8-HSL) via MsaI.
78 FR 64513 - Center For Scientific Review; Notice of Closed Meetings
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2013-10-29
... public in accordance with the provisions set forth in sections 552b(c)(4) and 552b(c)(6), Title 5 U.S.C... and Reproductive Sciences. Date: November 20, 2013. Time: 11:00 a.m. to 4:00 p.m. Agenda: To review... Review Officer, HDM IRG, Center for Scientific Review, National Institutes of Health, 6701 Rockledge...
77 FR 67015 - Center for Scientific Review; Notice of Closed Meetings
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2012-11-08
... DEPARTMENT OF HEALTH AND HUMAN SERVICES National Institutes of Health Center for Scientific Review... public in accordance with the provisions set forth in sections 552b(c)(4) and 552b(c)(6), Title 5 U.S.C...: Mitosis and Meiosis. Date: November 27-28, 2012. Time: 8:00 a.m. to 5:00 p.m. Agenda: To review and...
1986-09-01
0’ - N tT qT -0 t" C-r C-, M z a <CLW 4 0 a. o.CL- C= un z LJJIIr-= r -I CiA c= cot ’ rcli LAJI LUU CLCL LLI- IOUa a. IF LLJLm I-l - ( Cft - 4 CL...Depth Graphic Core Sample Sample Cft ) Log Interval/ID Taken* Lithologic Description 0- .. ~.G TOPSOIL; with some wood and other debris. 5-.~J SB-lA-1 ST...Date Recev 7 T ime~ L Transported By La- aml No. 0,; 0 Comments_____________________ ________ ___ Inclusive Dates of Possession
NASA Technical Reports Server (NTRS)
Parker, R. J.; Hodder, R. S.
1977-01-01
AMS 5749 steel combines the tempering, hot hardness, and hardness retention characteristics of AISI M-50 steel with the corrosion and oxidation resistance of AISI 440C stainless steel. The five-ball fatigue tester was used to evaluate the rolling-element fatigue life of AMS 5749. Double vacuum melting (vacuum induction melting plus vacuum arc remelting, VIM-VAR) produced AMS 5749 material with a rolling-element fatigue life at least 14 times that of vacuum induction melting alone. The VIM-VAR AMS 5749 steel balls gave lives from 6 to 12 times greater than VIM-VAR AISI M-50 steel balls. The highest level of retained austenite, 14.6 percent, was significantly detrimental to rolling-element fatigue life relative to the intermediate level of 11.1 percent.
An interface for the direct coupling of small liquid samples to AMS
DOE Office of Scientific and Technical Information (OSTI.GOV)
Ognibene, T. J.; Thomas, A. T.; Daley, P. F.
We describe the moving wire interface attached to the 1-MV AMS system at LLNL’s Center for Accelerator Mass Spectrometry for the analysis of nonvolatile liquid samples as either discrete drops or from the direct output of biochemical separatory instrumentation, such as high-performance liquid chromatography (HPLC). Discrete samples containing at least a few 10 s of nanograms of carbon and as little as 50 zmol 14C can be measured with a 3–5% precision in a few minutes. The dynamic range of our system spans approximately 3 orders in magnitude. Sample to sample memory is minimized by the use of fresh targetsmore » for each discrete sample or by minimizing the amount of carbon present in a peak generated by an HPLC containing a significant amount of 14C. As a result, liquid sample AMS provides a new technology to expand our biomedical AMS program by enabling the capability to measure low-level biochemicals in extremely small samples that would otherwise be inaccessible.« less
An interface for the direct coupling of small liquid samples to AMS
Ognibene, T. J.; Thomas, A. T.; Daley, P. F.; ...
2015-05-28
We describe the moving wire interface attached to the 1-MV AMS system at LLNL’s Center for Accelerator Mass Spectrometry for the analysis of nonvolatile liquid samples as either discrete drops or from the direct output of biochemical separatory instrumentation, such as high-performance liquid chromatography (HPLC). Discrete samples containing at least a few 10 s of nanograms of carbon and as little as 50 zmol 14C can be measured with a 3–5% precision in a few minutes. The dynamic range of our system spans approximately 3 orders in magnitude. Sample to sample memory is minimized by the use of fresh targetsmore » for each discrete sample or by minimizing the amount of carbon present in a peak generated by an HPLC containing a significant amount of 14C. As a result, liquid sample AMS provides a new technology to expand our biomedical AMS program by enabling the capability to measure low-level biochemicals in extremely small samples that would otherwise be inaccessible.« less
NASA Astrophysics Data System (ADS)
Sydoff, Marie; Stenström, Kristina
2010-04-01
The Department of Physics at Lund University is participating in a European Union project called EUMAPP (European Union Microdose AMS Partnership Programme), in which sample preparation and accelerator mass spectrometry (AMS) measurements of biological samples from microdosing studies have been made. This paper describes a simplified method of converting biological samples to solid graphite for 14C analysis with AMS. The method is based on online combustion of the samples, and reduction of CO 2 in septa-sealed vials. The septa-sealed vials and disposable materials are used to eliminate sample cross-contamination. Measurements of ANU and Ox I standards show deviations of 2% and 3%, respectively, relative to reference values. This level of accuracy is sufficient for biological samples from microdosing studies. Since the method has very few handling steps from sample to graphite, the risk of failure during the sample preparation process is minimized, making the method easy to use in routine preparation of samples.
Inhalation Toxicology. 11. The Effect of Elevated Temperature on Carbon Monoxide Toxicity
1990-12-01
DOT/FAA/AM-90/16 Inhalation Toxicology : XI. The Effect of Elevated Temperature on Carbon Office of Aviation Medicine Washington, D.C. 20591 M onoxide...Accession No. 3. Recipient’s Catalog No. DOT/FAA/AM-90/16 4. Title and Subtitie S. Report Date INHALATION TOXICOLOGY : XI. THE EFFECT OF ELEVATED December...Statement Combustion toxicology , carbon monoxide, This document is available to the public heat, thermal effects, time-to- through the National Technical
Disposition, profiling and identification of emixustat and its metabolites in humans.
Fitzsimmons, Michael E; Sun, Gang; Kuksa, Vladimir; Reid, Michael J
2018-06-01
1. Emixustat is a small molecule that potently inhibits retinal pigment epithelium 65 isomerohydrolase. Emixustat is in clinical development for the treatment of various retinopathies (i.e. Stargardt disease and diabetic retinopathy). 2. A human absorption, distribution, metabolism, and excretion (ADME) study was conducted with a single dose of [ 14 C]-emixustat in healthy male subjects. Total 14 C content in plasma, urine, and faeces was determined using accelerator mass spectrometry (AMS), and metabolic profiles in pooled plasma and urine were investigated by both HPLC-AMS and 2D LC-MS/MS. 3. After a single, oral 40-mg dose of [ 14 C]-emixustat, recovery of total 14 C was nearly complete within 24 h. Urine was the major route of 14 C elimination; accounting for > 90% of the administered dose. 4. Biotransformation of emixustat occurred primarily at two structural moieties; oxidation of the cyclohexyl moiety and oxidative deamination of the 3R-hydroxypropylamine, both independently and in combination to produce secondary metabolites. Metabolite profiling in pooled plasma samples identified 3 major metabolites: ACU-5124, ACU-5116 and ACU-5149, accounting for 29.0%, 11.5%, and 10.6% of total 14 C, respectively. Emixustat was metabolized in human hepatocytes with unchanged emixustat accounting for 33.7% of sample radioactivity and predominantly cyclohexanol metabolites observed.
Stepped-combustion 14C dating of bomb carbon in lake sediment
McGeehin, J.; Burr, G.S.; Hodgins, G.; Bennett, S.J.; Robbins, J.A.; Morehead, N.; Markewich, H.
2004-01-01
In this study, we applied a stepped-combustion approach to dating post-bomb lake sediment from north-central Mississippi. Samples were combusted at a low temperature (400 ??C) and then at 900 ??C. The CO2 was collected separately for both combustions and analyzed. The goal of this work was to develop a methodology to improve the accuracy of 14C dating of sediment by combusting at a lower temperature and reducing the amount of reworked carbon bound to clay minerals in the sample material. The 14C fraction modern results for the low and high temperature fractions of these sediments were compared with well-defined 137Cs determinations made on sediment taken from the same cores. Comparison of "bomb curves" for 14C and 137Cs indicate that low temperature combustion of sediment improved the accuracy of 14C dating of the sediment. However, fraction modern results for the low temperature fractions were depressed compared to atmospheric values for the same time frame, possibly the result of carbon mixing and the low sedimentation rate in the lake system.
Xu, Xiaohui Sophia; Dueker, Stephen R; Christopher, Lisa J; Lohstroh, Pete N; Keung, Chi Fung Anther; Cao, Kai Kevin; Bonacorsi, Samuel J; Cojocaru, Laura; Shen, Jim X; Humphreys, W Griffith; Stouffer, Bruce; Arnold, Mark E
2012-08-01
An absolute bioavailability study that utilized an intravenous [(14)C]microdose was conducted for saxagliptin (Onglyza(®)), a marketed drug product for the treatment of Type 2 diabetes mellitus. Concentrations of [(14)C]saxagliptin were determined by accelerator MS (AMS) after protein precipitation, chromatographic separation by UPLC and analyte fraction collection. A series of investigative experiments were conducted to maximize the release of the drug from high-affinity receptors and nonspecific adsorption, and to determine a suitable quantitation range. A technique-appropriate validation demonstrated the accuracy, precision, specificity, stability and recovery of the AMS methodology across the concentration range of 0.025 to 15.0 dpm/ml (disintegration per minute per milliliter), the equivalent of 1.91-1144 pg/ml. Based on the study sample analysis, the mean absolute bioavailability of saxagliptin was 50% in the eight subjects with a CV of 6.6%. Incurred sample reanalysis data fell well within acceptable limits. This study demonstrated that the optimized sample pretreatment and chromatographic separation procedures were critical for the successful implementation of an UPLC plus AMS method for [(14)C]saxagliptin. The use of multiple-point standards are useful, particularly during method development and validation, to evaluate and correct for concentration-dependent recovery, if observed, and to monitor and control process loss and operational variations.
NASA Astrophysics Data System (ADS)
Xiong, Jianguo; Li, Youli; Zhong, Yuezhi; Lu, Honghua; Lei, Jinghao; Xin, Weilin; Wang, Libo; Hu, Xiu; Zhang, Peizhen
2017-12-01
At the eastern Qilian Shan mountain front in the NE Tibetan Plateau, the Minle-Damaying Fault (MDF), the southernmost fault of the North Frontal Thrust (NFT) system, has previously been proposed as an inactive structure during the Holocene. Here we present a detailed record of six strath terraces of the Xie River that document the history of active deformation of the MDF. One optically stimulated luminescence dating sample constrains abandonment of the highest terrace T6 at 12.7 ± 1.4 ka. The formation ages of the lower terraces (T4-T1) are dated by AMS 14C dating. The cumulative vertical offsets of the MDF recorded by these terraces are determined as 12.2 ± 0.4 m (T6), 8.0 ± 0.4 m (T5), 6.4 ± 0.4 m (T4), 4.6 ± 0.1 m (T3), and 3.2 ± 0.2 m (T1c) by an unmanned aerial vehicle system, respectively. A long-term vertical slip rate of the MDF of 0.9 ± 0.2 mm/yr is then estimated from the above data of terrace age and vertical offset by a linear regression. Assuming that the fault dip of 35 ± 5° measured at the surface is representative for the depth-averaged fault dip, horizontal shortening rates of 0.83-1.91 mm/yr are inferred for the MDF. Our new data show that the proximal fault (the MDF) of the NFT system at the eastern Qilian Shan mountain front has remained active when the deformation propagated basinward, a different scenario from that observed at both the western and central Qilian Shan mountain front.
Expanding Spatial Coverage of Geomagnetic Field Models Using Submarine Basaltic Glass
NASA Astrophysics Data System (ADS)
Schoeller, L. M.; Bowles, J. A.; Dreyer, B.; Clague, D. A.
2009-12-01
In recent years, paleointensity of submarine basaltic glass (SBG) has been used to constrain the ages of young mid-ocean ridge flows, often in the absence of more precise age data. In the present study, samples taken from the Co-Axial segment of the Juan de Fuca Ridge allow for further testing of the paleointensity dating technique; they also provide an assessment of the feasibility of incorporating SBG data into geomagnetic field models when independent age constraints are available. The nine sampled sites include six for which 14C dating of overlying sediments provides minimum ages (950 - 6400 ybp) for the flows, and three sites from historical flows. Absolute paleointensity estimates were derived using a Thellier-type method. The paleointensities of the samples ranged from 51.8 µT to 71.1 µT (VADM 8.3 to 11.6 x 1022 Am2). We compare results from the young (historical) flows directly with the International Geomagnetic Reference Field (IGRF), and two out of three sites are consistent with IGRF. The third gives paleointensity values that are considerably higher than would be expected based on IGRF. The rest of the samples can be compared with geomagnetic field models based on archeomagnetic and paleomagnetic data. Paleointensity values from samples < 3ka are consistent with the CALS3K.3 model (Korte et al., Geochem. Geophys. Geosys., 10, Q06008, doi:10.1029/2008GC002297, 2009), given the approximate ages provided by the 14C dating of the overlying sediments. Data constraining current geomagnetic field models are spatially quite limited, with the vast majority restricted to northern hemispheric continental regions. We suggest that data from mid-ocean ridges are suitable for incorporation into such models, with the potential to greatly expand spatial coverage.
When Will It Be …?: U.S. Naval Observatory Religious Calendar Computers Expanded
NASA Astrophysics Data System (ADS)
Bartlett, Jennifer L.; Chizek Frouard, Malynda; Ziegler, Cross; Lesniak, Michael V.
2017-01-01
Reflecting increasing sensitivity to differing religious practices, the U.S. Naval Observatory (USNO) has expanded its on-line calendar resources to compute additional religious dates for specific years via an Application Programming Interface (API). This flexible method now identifies Christian, Islamic, and Jewish events in JavaScript Object Notation (JSON) that anyone can use.Selected Christian Observances (http://aa.usno.navy.mil/data/docs/easter.php) returns dates of eight events for years after 1582 C.E. (A.D. 1582): Ash Wednesday, Palm Sunday, Good Friday, Easter, Ascension, Whit Sunday, Trinity Sunday, and the first Sunday of Advent. The determination of Easter, a moveable feast, uses the method of western Christian churches.Selected Islamic Observances (http://aa.usno.navy.mil/data/docs/islamic.php) returns approximate Gregorian dates of three events for years after 1582 C.E. (A.H. 990) and Julian dates for 622-1582 C.E. (A.H. 1-990) along with the corresponding Islamic year (anno Hegirae). Ramadân, Shawwál, and the Islamic year begin at sunset on the preceding Gregorian or Julian date. For planning purposes, the determination of these dates uses a tabular calendar; in practice, observation of the appropriate waxing crescent Moon determines the actual date, which may vary.Selected Jewish Observances (http://aa.usno.navy.mil/data/docs/passover.php) returns Gregorian dates of six events for years after 1582 C.E. (A.M. 5342) and Julian dates for the years 360-1582 C.E. (A.M. 4120-5342) along with the corresponding Jewish year (anno Mundi). Passover, Shavuot, Rosh Hashanah, Yom Kippur, and Hanukkah begin at sunset on the preceding Gregorian or Julian date.On-line documentation for using the API-enabled calendar computers, including sample calls, is available (http://aa.usno.navy.mil/data/docs/api.php). The webpage also describes how to use the API with the Complete Sun and Moon Data for One Day, Phases of the Moon, Solar Eclipse Computer, Day and Night Across the Earth, Apparent Disk of a Solar System Object, Julian Date Conversion, and Sidereal Time services.Introduction to Calendars (http://aa.usno.navy.mil/faq/docs/calendars.php) provides an overview of the topic and links to additional resources.
Rakovan, Monica T.; Rech, Jason A.; Pigati, Jeffery S.; Nekola, Jeffery C.; Wiles, Gregory C.
2013-01-01
Understanding the history of stream erosion and changes in channel morphology is important for managing and restoring unstable streams. One of the significant challenges in this type of research is establishing accurate dating of late Holocene and historic alluvium. Here we evaluate the potential of using 14C dating and amino acid racemization (AAR) to date large terrestrial gastropod shells that are often preserved within alluvial sediments. Many terrestrial gastropods incorporate old carbon from limestone or other carbonate rocks into their shells and therefore are unsuitable for radiocarbon dating. Recent studies, however, have shown that some taxa avoid this ‘limestone problem’ and can yield reliable 14C ages. In this study, we measured the 14C activity of specimens for the genera Mesodon, Ventridens, and Allogona collected live and from alluvial sequences dated independently by dendrochronology, 14C dating of wood, and/or 137Cs analyses. Mesodon zaletus contained old carbon in similar concentrations (up to ~ 30%) found in previous studies of other large taxa and should be avoided for 14C dating when possible. In contrast, shells of Ventridens ligera and Allogona profunda showed minimal limestone effects and therefore may be suitable for dating late Holocene alluvium. These results highlight the importance of taxonomic identification of gastropod taxa prior to their use for 14C dating and demonstrate that shell fragments that are not identifiable should be avoided. We also measured d/l ratios (n = 17) of aspartic and glutamic acid from eight different taxa of terrestrial gastropods recovered from four late Holocene and historic stratigraphic sequences. Average d/l ratios of aspartic and glutamic acid from historic sediments < 300 years old are lower in shells from younger stratigraphic units, indicating that AAR can be used to differentiate between multiple historic stratigraphic units.
14C plateaus and global stratigraphic correlation during Termination IA
NASA Astrophysics Data System (ADS)
Sarnthein, M.; Grootes, P. M.; Kennett, J. P.; Nadeau, M.
2006-12-01
In search of a global 14C reference record for Termination IA, we analyzed three published 14C records with centennial-scale resolution, that provide independent evidence for calibrating the 14C time scale: (1) A sediment record from Cariaco Basin (ODP Site 1002) correlated to the U/Th-dated Hulu Cave record (Hughen et al., 2006), (2) a U/Th dated speleothem record from the Bahamas (Beck et al., 2001, 2006), and (3) a set of U/Th-dated coral ages (IntCal04 plus Fairbanks et al., 2005) that unfortunately lack data from 18-15 cal. ka. All these records exhibit significant changes in the slope of 14C vs. calendar ages, allowing us to define a suite of major and minor "14C plateaus" in each record, that in total occupy >70% of the 14C record between 19 and 14 cal. ka. Despite their different origin the three records are largely consistent. When dating resolution is sufficient, most plateaus show a characteristic internal structure incorporating 14C inversions, in particular near the onset of a plateau. Plateau boundary ages for the Cariaco record have a total range of uncertainty of 150-450 yr due to uncertainties with age calibration (Hughen et al., 2006), in addition to the range of dating resolution. During Termination IA, a period of dramatic climate change, these boundary ages should serve as datums for the global correlation of marine sediment records. Moreover, they are employed to deduce apparent paleoventil-ation ages and thus circulation patterns of surface and bottom water masses, as demonstrated for example from the northern Pacific and the Icelandic Sea.
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... ed. Philadelphia, PA: Elsevier Saunders; 2016:chap 106. Solomon M, Grasemann H, Keshavjee S. Pediatric lung transplantation. Pediatr Clin North Am . 2010;57(2):375-391. PMID: 20371042 www.ncbi.nlm.nih.gov/pubmed/20371042 . Review Date 4/12/2017 Updated by: Mary C. Mancini, MD, ...
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Rickert, D E; Dingley, K H; Ubick, E
2004-07-02
Administration of {sup 14}C-Moli1901 (duramycin, 2622U90), a 19 amino acid polycyclic peptide by intratracheal instillation (approximately 100 {micro}g) into the left cranial lobe of the lung of beagle dogs resulted in retention of 64% of the dose in the left cranial lobe for up to 28 days. In this study, we used accelerator mass spectrometry (AMS) to quantify Moli901 following administration of only 0.045 {micro}Ci of {sup 14}C-Moli901 per dog. Limits of quantitation of AMS were 0.03 (urine) to 0.3 (feces) ng equiv. Moli1901/g. Whole blood and plasma concentrations of {sup 14}C were <5ng/ml at all times after the dose.more » Concentrations of {sup 14}C in whole blood and plasma declined over the first day after the dose and rose thereafter, with the rise in plasma concentrations lagging behind those in whole blood. During the first 3 days after the dose, plasma accounted for the majority of {sup 14}C in whole blood, but after that time, plasma accounted for only 25-30% of the {sup 14}C in whole blood. Tissue (left and right caudal lung lobe, liver, kidney, spleen, brain) and bile concentrations were low, always less than 0.25% the concentrations found in the left cranial lung lobe. Approximately 13% of the dose was eliminated in urine and feces in 28 days, with fecal elimination accounting for about 10% of the dose. The data presented here are consistent with that obtained in other species. Moli1901 is slowly absorbed and excreted from the lung, and it does not accumulate in other tissues. Moli1901 is currently in the clinic and has proven to be safe in single dose studies in human volunteers and cystic fibrosis patients by the inhalation route. No information on the disposition of the compound in humans is available. This study in dogs demonstrates the feasibility of obtaining that information using {sup 14}C-Moli1901 and AMS.« less
75 FR 55592 - Center for Scientific Review; Notice of Closed Meetings
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Guilderson, T P; Grumet, N S; Abram, N J
Radiocarbon ({sup 14}C) in the skeletal aragonite of annually banded corals track radiocarbon concentrations in dissolved inorganic carbon (DIC) in surface seawater. As a result of nuclear weapons testing in the 1950s, oceanic uptake of excess {sup 14}C in the atmosphere has increased the contrast between surface and deep ocean {sup 14}C concentrations. We present accelerator mass spectrometric (AMS) measurements of radiocarbon isotope ({Delta}{sup 14}C) in Porites corals from the Mentawai Islands, Sumatra (0 S, 98 E) and Watamu, Kenya (3 S, 39 E) to document the temporal and spatial evolution of the {sup 14}C gradient in the tropical Indianmore » Ocean. The rise in {Delta}{sup 14}C in the Sumatra coral, in response to the maximum in nuclear weapons testing, is delayed by 2-3 years relative to the rise in coral {Delta}{sup 14}C from the coast of Kenya. Kenya coral {Delta}{sup 14}C values rise quickly because surface waters are in prolonged contact with the atmosphere. In contrast, wind-induced upwelling and rapid mixing along the coast of Sumatra entrains {sup 14}C-depleted water from the subsurface, which dilutes the effect of the uptake of bomb-laden {sup 14}C by the surface-ocean. Bimonthly AMS {Delta}{sup 14}C measurements on the Mentawai coral reveal mainly interannual variability with minor seasonal variability. The interannual signal may be a response to changes in the Walker circulation, the development of easterly wind anomalies, shoaling of the eastern thermocline, and upwelling of {sup 14}C-depleted water along the coast of Sumatra. Singular spectrum analysis of the Sumatra coral {Delta}{sup 14}C record reveals a significant 3-year periodicity. The results lend support to the concept that ocean atmosphere interactions between the Pacific and Indian Oceans operate in concert with the El Ni{tilde n}o-Southern Oscillation (ENSO).« less
NASA Astrophysics Data System (ADS)
Schindler, Matthias; Kretschmer, Wolfgang; Scharf, Andreas; Tschekalinskij, Alexander
2016-05-01
Three new methods to sample and prepare various carbonyl compounds for radiocarbon measurements were developed and tested. Two of these procedures utilized the Strecker synthetic method to form amino acids from carbonyl compounds with either sodium cyanide or trimethylsilyl cyanide. The third procedure used semicarbazide to form crystalline carbazones with the carbonyl compounds. The resulting amino acids and semicarbazones were then separated and purified using thin layer chromatography. The separated compounds were then combusted to CO2 and reduced to graphite to determine 14C content by accelerator mass spectrometry (AMS). All of these methods were also compared with the standard carbonyl compound sampling method wherein a compound is derivatized with 2,4-dinitrophenylhydrazine and then separated by high-performance liquid chromatography (HPLC).
Wang, Guangyuan; Liu, Lin; Liang, Wenxing
2018-01-01
Microbial oils are among the most attractive alternative feedstocks for biodiesel production. In this study, a newly isolated yeast strain, AM113 of Papiliotrema laurentii, was identified as a potential lipid producer, which could accumulate a large amount of intracellular lipids from hydrolysates of inulin. P. laurentii AM113 was able to produce 54.6% (w/w) of intracellular oil in its cells and 18.2 g/l of dry cell mass in a fed-batch fermentation. The yields of lipid and biomass were 0.14 and 0.25 g per gram of consumed sugar, respectively. The lipid productivity was 0.092 g of oil per hour. Compositions of the fatty acids produced were C 14:0 (0.9%), C 16:0 (10.8%), C 16:1 (9.7%), C 18:0 (6.5%), C 18:1 (60.3%), and C 18:2 (11.8%). Biodiesel obtained from the extracted lipids could be burnt well. This study not only provides a promising candidate for single cell oil production, but will also probably facilitate more efficient biodiesel production.
1987-10-10
Invted Paper) Yen, Hughes Research Laboratories. Design and fabrica- FA1 Hgh-Spmd Phenomena In GaAs Quantum Wells, A. tion of wideband and high-speed...App!. Phys., 49 1119). 5. A.M. Johnson, D.I. Auston, P.R. Smith, J.C. Dean, i.P. Harbison, and D. Kaplan ,r "Picosecond Photoconductivity in...JANUARY 16, 1987 PROSPECTOR! RUBICON ROOM 8:00 A.M.-9:30 A.M. FA1 -4 QUANTUM-WELL PHYSICS AND DEVICES C. Weisbuch, Thomson CSF, Presider .4
77 FR 38075 - Center for Scientific Review; Notice of Closed Meetings
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... Current Investment Management Contract 8. Board Meeting Calendar Review 9. FRTIB Move Update 10. Roth... FEDERAL RETIREMENT THRIFT INVESTMENT BOARD Sunshine Act Meeting TIME AND DATE: 9 a.m. (Eastern.... Investment Performance Report c. Legislative Report 3. Review of Audit Recommendations 4. Audit Reports 5...
Environmental radiation protection studies related to nuclear industries, using AMS
NASA Astrophysics Data System (ADS)
Hellborg, Ragnar; Erlandsson, Bengt; Faarinen, Mikko; Hâkansson, Helena; Hâkansson, Kjell; Kiisk, Madis; Magnusson, Carl-Erik; Persson, Per; Skog, Göran; Stenström, Kristina; Mattsson, Sören; Thornberg, Charlotte
2001-07-01
14C is produced in nuclear reactors during normal operation and part of it is continuously released into the environment. Because of the biological importance of carbon and the long physical half-life of 14C it is of interest to study these releases. The 14C activity concentrations in the air and vegetation around some Swedish as well as foreign nuclear facilities have been measured by accelerator mass spectrometry (AMS). 59Ni is produced by neutron activation in the stainless steel close to the core of a nuclear reactor. The 59Ni levels have been measured in order to be able to classify the different parts of the reactor with respect to their content of long-lived radionuclides before final storage. The technique used to measure 59Ni at a small accelerator such as the Lund facility has been developed over the past few years and material from the Swedish nuclear industry has been analyzed.
NASA Astrophysics Data System (ADS)
Rosenheim, B. E.; Firesinger, D.; Roberts, M. L.; Burton, J. R.; Khan, N.; Moyer, R. P.
2016-12-01
Radiocarbon (14C) sediment core chronologies benefit from a high density of dates, even when precision of individual dates is sacrificed. This is demonstrated by a combined approach of rapid 14C analysis of CO2 gas generated from carbonates and organic material coupled with Bayesian statistical modeling. Analysis of 14C is facilitated by the gas ion source on the Continuous Flow Accelerator Mass Spectrometry (CFAMS) system at the Woods Hole Oceanographic Institution's National Ocean Sciences Accelerator Mass Spectrometry facility. This instrument is capable of producing a 14C determination of +/- 100 14C y precision every 4-5 minutes, with limited sample handling (dissolution of carbonates and/or combustion of organic carbon in evacuated containers). Rapid analysis allows over-preparation of samples to include replicates at each depth and/or comparison of different sample types at particular depths in a sediment or peat core. Analysis priority is given to depths that have the least chronologic precision as determined by Bayesian modeling of the chronology of calibrated ages. Use of such a statistical approach to determine the order in which samples are run ensures that the chronology constantly improves so long as material is available for the analysis of chronologic weak points. Ultimately, accuracy of the chronology is determined by the material that is actually being dated, and our combined approach allows testing of different constituents of the organic carbon pool and the carbonate minerals within a core. We will present preliminary results from a deep-sea sediment core abundant in deep-sea foraminifera as well as coastal wetland peat cores to demonstrate statistical improvements in sediment- and peat-core chronologies obtained by increasing the quantity and decreasing the quality of individual dates.
Comparison of Radiocarbon Ages of Sediments, Plants, and Shells From Coastal Lakes in North Florida
NASA Astrophysics Data System (ADS)
Wang, Y.; Das, O.; Liu, J.; Xu, X.; Roy, R.; Donoghue, J. F.; Means, G. H.
2017-12-01
Coastal lakes sediments are valuable archives of paleo-hurricanes and environmental changes during the late Quaternary provided that they can be accurately dated. Here, we report new radiocarbon (14C) dates derived from various organic and inorganic substrates, including bulk sediment organic matter, plants, shells, particulate organic matter (POM) and dissolved organic matter (DOM), from three coastal lakes in Florida, and compare these ages to evaluate the "reservoir effect" on 14C dating of both organic and inorganic carbon in these lakes. Bulk sediment organic matter yielded consistently older 14C ages than contemporaneous plants and shell fragments, indicating significant radiocarbon deficiencies in sedimentary organic matter in these coastal lakes, caused by influx of old organic carbon from terrestrial sources (such as soils and ancient peat deposits) in the watershed. Several reversals are observed in the 14C ages of bulk sediment organic matter in sediment cores from these lakes, indicating that input of aged organic matter from terrestrial sources into these lakes can vary considerably over time. DOM and POM samples collected at different times also yielded variable 14C signatures, further confirming the temporal variability in the contribution of old organic carbon from terrestrial sources to the lakes. The 14C age discrepancy between bulk sediment organic matter and co-occurring plant fragments or shells varies from less than one hundred years to nearly three thousand years in sediment cores examined in this study. The results show that 14C ages obtained from bulk sediment organic matter in these coastal lakes are unreliable. Analyses of both modern and fossil shells from one of the lakes suggest that the 14C reservoir effect on inorganic carbon in the lake is small and thus freshwater shells (if preserved in the sediment cores) may serve as a good substrate for 14C dating in the absence of plant fragments. However, unidentifiable shell fragments, especially those associated with sand pockets (or sand layers), in coastal lake sediment cores are not suitable for 14C dating as they are likely of marine origin and affected by significant marine 14C reservoir effect.
Ivanova, Jasmina I; Hayes-Larson, Eleanor; Sorg, Rachael A; Birnbaum, Howard G; Berner, Todd
2014-10-01
To compare the healthcare costs of patients with overactive bladder (OAB) who switch vs persist on anti-muscarinic agents (AMs), describe resource use and costs among OAB patients who discontinue AMs, and assess factors associated with persisting vs switching or discontinuing. OAB patients initiating an AM between January 1, 2007 and March 31, 2012 were identified from a claims database of US privately insured beneficiaries (n ≈ 16 million) and required to have no AM claims in the 12 months before AM initiation (baseline period). Patients were classified as persisters, switchers, or discontinuers, and assigned a study index date based on their AM use in the 6 months following initiation. Baseline characteristics, resource use, and costs were compared between persisters and the other groups. Resource use and costs in the 1 month before and 6 months after the study index date (for switchers, the date of index AM switching; for persisters, a randomly assigned date to reflect the distribution of the time from AM initiation to switching among switchers) were also compared between persisters and switchers in unadjusted and adjusted analyses. Factors associated with persisting vs switching or discontinuing were assessed. After controlling for baseline characteristics and costs, persisters vs switchers had significantly lower all-cause and OAB-related costs in both the month before (all-cause $1222 vs $1759, OAB-related $142 vs $170) and 6 months after the study index date (all-cause $7017 vs $8806, OAB-related $642 vs $797). Factors associated with switching or discontinuing vs persisting included index AM, younger age, and history of UTI. A large proportion of OAB patients discontinue or switch AMs shortly after initiation, and switching is associated with higher costs.
Radiocarbon application in environmental science and archaeology in Croatia
NASA Astrophysics Data System (ADS)
Krajcar Bronić, I.; Obelić, B.; Horvatinčić, N.; Barešić, J.; Sironić, A.; Minichreiter, K.
2010-07-01
Radiocarbon is a cosmogenic radioisotope equally distributed throughout the troposphere and biosphere. This fact enables its most common application—radiocarbon dating. Natural equilibrium of radiocarbon has been disturbed by diverse anthropogenic activities during the last ˜150 years, enabling also the use of 14C in various environmental applications. Here we present three types of studies by using 14C that were performed in the Zagreb Radiocarbon Laboratory. 14C in atmospheric CO 2 has been monitored at several sites with various anthropogenic influences and the difference between the clean-air sites, the industrial city and the vicinity of a nuclear power plant has been established. 14C has been applied in geochronology of karst areas, especially in dating of tufa, speleothems and lake sediments, as well as in studies of geochemical carbon cycle. 14C has been used in various archaeological studies, among which the dating of the early Neolithic settlements in Croatia is presented. In these studies 14C was measured by radiometric techniques, i.e., by gas proportional counting and more recently by liquid scintillation counting (LSC). Two sample preparation techniques for LSC measurement were used: benzene synthesis for archaeological dating and other applications that require better precision, and direct absorption of CO 2 for monitoring purposes. The presented results show that various studies by using 14C can be successfully performed by the LSC technique, providing a large enough sample (>1 g of carbon).
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78 FR 76277 - National Urban and Community Forestry Advisory Council
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2013-12-17
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2012-03-09
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2011-07-26
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2010-05-07
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When Will It Be …?: U.S. Naval Observatory Calendar Computers
NASA Astrophysics Data System (ADS)
Bartlett, Jennifer L.; Chizek Frouard, Malynda; Lesniak, Michael V.
2016-06-01
Sensitivity to religious calendars is increasingly expected when planning activities. Consequently, the U.S. Naval Observatory (USNO) has redesigned its on-line calendar resources to allow the computation of select religious dates for specific years via an application programming interface (API). This flexible interface returns dates in JavaScript Object Notation (JSON) that can be incorporated into third-party websites or applications. Currently, the services compute Christian, Islamic, and Jewish events.The “Dates of Ash Wednesday and Easter” service (http://aa.usno.navy.mil/data/docs/easter.php) returns the dates of these two events for years after 1582 C.E. (1582 A.D.) The method of the western Christian churches is used to determined when Easter, a moveable feast, occurs.The “Dates of Islamic New Year and Ramadan” service (http://aa.usno.navy.mil/data/docs/islamic.php) returns the approximate Gregorian dates of these two events for years after 1582 C.E. (990 A.H.) and Julian dates are computed for the years 622-1582 C.E. (1-990 A.H.). The appropriate year in the Islamic calendar (anno Hegira) is also provided. Each event begins at 6 P.M. or sunset on the preceding day. These events are computed using a tabular calendar for planning purposes; in practice, the actual event is determined by observation of the appropriate new Moon.The “First Day of Passover” service (http://aa.usno.navy.mil/data/docs/passover.php) returns the Gregorian date corresponding to Nisan 15 for years after 1582 C.E. (5342 A.M.) and Julian dates are computed for the years 360-1582 C.E. (4120-5342 A.M.). The appropriate year in the Jewish calendar (anno Mundi) is also provided. Passover begins at 6 P.M. or sunset on the preceding day.On-line documentation for using the API-enabled calendar computers, including sample calls, is available (http://aa.usno.navy.mil/data/docs/api.php). The same web page also describes how to reach the Complete Sun and Moon Data for One Day, Phases of the Moon, Solar Eclipse Computer, Day and Night Across the Earth, and Apparent Disk of a Solar System Object services using API calls.An “Introduction to Calendars” (http://aa.usno.navy.mil/faq/docs/calendars.php) provides an overview of the topic and links to additional resources.
Baskaran, M; Bianchi, T S; Filley, T R
2017-08-01
14 C is the most widely utilized geochronometer to investigate geological, geochemical and geophysical problems over the past 5 decades. Establishment of precise sedimentation rates is crucial for the reconstruction of paleo-climate, -ecological and - environmental studies when extrapolation of sedimentation rates is utilized for time scales beyond the dating range. However, agreement between short-term and long-term sedimentation rates in anthropogenically unperturbed sediment cores has not been shown. Here we show that the AMS 14 C-based long-term mass accumulation rate (MAR) of an organic-rich (>70%) sediment core from Mud Lake, Florida to be ∼5 times lower than the short-term MAR obtained using 239,240 Pu, 137 Cs and excess 210 Pb ( 210 Pb xs ). The measured sediment inventories of 210 Pb xs , 137 Cs and 239,240 Pu are comparable to the atmospheric fallout for the sampling site, indicating very little accelerated sediment erosion over the past several decades. Presence of sharp fallout peaks of 239,240 Pu indicates very little sediment mixing. The penetration depths of 137 Cs and 239,240 Pu were found to be much deeper than expected and this is attributed to their post-depositional mobility. MAR calculated using 14 C-ages in successive layers also indicated decreasing MARs with depth, and was reflective of progressive remineralization. Using first-order kinetics, the sediment remineralization rate was found to be 4.4 × 10 -4 y -1 and propose that over the long-term, remineralization of organic-rich sediment affected the long-term MAR, but not the ratio of 14 C/ 12 C. Thus, the MAR and linear sedimentation rate obtained using 14 C (and other isotope-based methods) could be erroneous, although 14 C ages may not be affected by such remineralization. Long-term remineralization rates of organic matter has a direct bearing on the biogeochemical cycling of elements in aqueous systems and mass balance of elements needs to be taken into consideration. Copyright © 2016 Elsevier Ltd. All rights reserved.
NASA Astrophysics Data System (ADS)
Reese, D.; DeCesare, M.; Subt, C.; Bart, P. J.; Wellner, J. S.; Rosenheim, B. E.
2016-12-01
Chronicling deglaciation rates and style in Antarctic margin sediment is difficult because of low preservation/deposition of carbonate foraminiferal tests as well as incorporation of pre-aged organic carbon from carbonaceous rocks. When carbonates for radiocarbon dating are absent, acid-insoluble organic matter (AIOM) 14C dates are often used as an alternative and providing reliable chronologies in some locations. Results obtained by this method can cause difficulties such as false age reversals and ambiguity due to contamination with pre-aged carbon (Rosenheim et. al., 2008; Subt et al., 2016). Ramped PyrOx 14C dating has exploited the higher thermochemical stability of pre-aged carbon to separate carbon dating to the time of sediment deposition, and recently has produced chronologies similar to foraminifera-based chronologies (Subt et al., 2016). Samples for Ramped PyrOx 14C dating have generally been treated with acid to remove carbonates, and thus some acid soluble organic matter. In an effort to minimize the alteration of the organic matter, we apply Ramped PyrOx 14C dating to samples that have been both treated with 1N HCl and left untreated. Untreated samples display a characteristic large, sharp peak at higher temperatures than pyrolysis of organic matter that we interpret as carbonate decomposition. These carbonate decomposition peaks are characteristically sharp and occur at higher temperatures than the maximum evolution of CO2 from the organic matter in the sample. We isolated these peaks for comparison between known carbonate ages from picked foraminifera and low-temperature Ramped PyrOx splits from acid treated samples. We will discuss the treatment of the suite of 14C ages with reconciliation of two dating methods in mind. Ultimately, this approach offers promise for a single treatment of Antarctic margin sediments that provides chronologies from both carbonate and organic material.
{sup 14}C depth profiles in Apollo 15 and 17 cores and lunar rock 68815
DOE Office of Scientific and Technical Information (OSTI.GOV)
Jull, A.J.T.; Cloudt, S.; Donahue, D.J.
1998-09-01
Accelerator mass spectrometry (AMS) was used to measure the activity vs. depth profiles of {sup 14}C produced by both solar cosmic rays (SCR) and galactic cosmic rays (GCR) in Apollo 15 lunar cores 15001-6 and 15008, Apollo 17 core 76001, and lunar rock 68815. Calculated GCR production rates are in good agreement with {sup 14}C measurements at depths below {approximately}10 cm. Carbon-14 produced by solar protons was observed in the top few cm of the Apollo 15 cores and lunar rock 68815, with near-surface values as high as 66 dpm/kg in 68815. Only low levels of SCR-produced {sup 14}C weremore » observed in the Apollo 17 core 76001. New cross sections for production of {sup 14}C by proton spallation on O, Si, Al, Mg, Fe, and Ni were measured using AMS. These cross sections are essential for the analysis of the measured {sup 14}C depth profiles. The best fit to the activity-depth profiles for solar-proton-produced {sup 14}C measured in the tops of both the Apollo 15 cores and 68815 was obtained for an exponential rigidity spectral shape R{sub 0} of 110--115 MV and a 4 {pi} flux (J{sub 10}, Ep > 10 MeV) of 103--108 protons/cm{sup 2}/s. These values of R{sub 0} are higher, indicating a harder rigidity, and the solar-proton fluxes are higher than those determined from {sup 10}Be, {sup 26}Al, and {sup 53}Mn measurements.« less
Elemental analysis using ED-XRF and 14C dating of Cuman wall paintings samples
NASA Astrophysics Data System (ADS)
Brocchieri, J.; Sabbarese, C.; Marzaioli, F.; Passariello, I.; Terrasi, F.; De Maio, C.; Ferrara, L.
2018-04-01
The aim of the present research was to analyse pigments and mortars of fresco fragments located at Cuma (Naples, Italy). The ED-XRF technique and 14C dating were used to establish the nature of the pigments and the age of mortars, respectively. ED-XRF results allowed to determine the elemental composition of the pigments that identified the colours and, hence, the historical period of completion. The 14C dating, applied to mortars using a particular preparation, provided results that are in accordance with the archaeological information within the 2σ interval range.
Pharmacokinetic analysis of 14C-ursodiol in newborn infants using accelerator mass spectrometry.
Gordi, Toufigh; Baillie, Rebecca; Vuong, Le T; Abidi, Saira; Dueker, Stephen; Vasquez, Herbert; Pegis, Priscilla; Hopper, Andrew O; Power, Gordon G; Blood, Arlin B
2014-09-01
Pharmacokinetic studies in the neonatal population are often limited by the small volume of blood that can be collected. The high sensitivity of (14) C-accelerator mass spectrometry (AMS) enables pharmacokinetic studies to be conducted with greatly reduced sample volumes. We demonstrated the utility of AMS in infants by studying the plasma pharmacokinetic behavior of nanogram doses of (14) C-ursodiol administered as a non-perturbing microdose or as a microtracer with therapeutic doses of non-labeled ursodiol in infants. Five non-cholestatic infants were administered 3 consecutive oral microdoses of (14) C-ursodiol: 8 ng (1.0 nCi), 26 ng (3.3 nCi), and 80 ng (10 nCi) 48 hours apart. Three additional infants with cholestasis were administered a single 80 ng (10.0 nCi) oral dose of (14) C-ursodiol together with a therapeutic dose of 40 mg/kg of non-labeled ursodiol. A pharmacokinetic model describing ursodiol concentrations was developed using nonlinear mixed-effects modeling. The pharmacokinetics of ursodiol in this pilot study were best described by a two-compartment model with first-order elimination. This study demonstrates the feasibility and utility of microdose and microtrace methodology in pediatric research. © 2014, The American College of Clinical Pharmacology.
Methods and applications of HPLC-AMS (WBio 5)
DOE Office of Scientific and Technical Information (OSTI.GOV)
Bucholz, B A; Clifford, A J; Duecker, S R
Pharmacokinetics of physiologic doses of nutrients, pesticides, and herbicides can easily be traced in humans using a {sup 14}C-labelled compound. Basic kinetics can be monitored in blood or urine by measuring the elevation in the {sup 14}C content above the control predose tissue and converting to equivalents of the parent compound. High Performance Liquid Chromatography (HPLC) is an excellent method for the chemical separation of complex mixtures whose profiles afford estimation of biochemical pathways of metabolism. Compounds elute from the HPLC systems with characteristic retention times and can be collected in fractions that can then be graphitized for AMS measurement.more » Unknowns are identified by coelution with known standards and chemical tests that reveal functional groupings. Metabolites are quantified with the {sup 14}C signal. Thoroughly accounting for the carbon inventory in the LC solvents, ion-pairing agents, samples, and carriers adds some complexity to the analysis. In most cases the total carbon inventory is dominated by carrier. Baseline background and stability need to be carefully monitored. Limits of quantitation near 10 amol of {sup 14}C per HPLC fraction are typically achieved. Baselines are maintained by limiting injected {sup 14}C activity <0.17 Bq (4.5 pCi) on the HPLC column.« less
MA-9 [FAITH 7] SITS ON LAUNCH COMPLEX 14 AWAITING LIFTOFF
NASA Technical Reports Server (NTRS)
1963-01-01
MA-9 [FAITH 7] SITS ON LAUNCH COMPLEX 14 AWAITING LIFTOFF LOC-63C-1410.01 LOC-63C-1410.1, P-06450-A, ARCHIVE-04040 Pre-launch: Mercury-Atlas 9 stands on Pad 14 at Cape Canaveral ready for launch. Lift-off occurred at 8:04 a.m. EST, two and one half hours after Astronaut L. Gordon Cooper was inserted into the spacecraft he named FAITH 7. NASA/Mercury Complex 14, CCMTA, Test 125.
78 FR 2962 - Sunshine Act Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2013-01-15
... Announcement: Vol. 78, No. 7, Thursday, January 10, 2013, page 2257. Change in Announced Time and Date of Open Meeting: 10 a.m.-11 a.m., Wednesday January 16, 2013. Changes To Open Meeting Agenda Matters to be.... Dated: January 10, 2013. Todd A. Stevenson, Secretary. [FR Doc. 2013-00762 Filed 1-11-13; 11:15 am...
NASA Astrophysics Data System (ADS)
Shotyk, W.; Appleby, P.; Davies, L. J.; Froese, D. G.; Magnan, G.; Mullan-Boudreau, G.; Noernberg, T.; Bob, S.; van Bellen, S.; Zaccone, C.
2016-12-01
The upper layers of ombrotrophic (rain-fed) bogs are hydrologically isolated from surface waters and groundwaters and, in consequence, contaminants are supplied exclusively from the atmosphere. Peat cores from bogs have been used to reconstruct the history of heavy metal pollution since mining and metallurgy began, but the greatest changes have taken place since the start of the Industrial Revolution which was well underway by the middle of the 19th century. Dating peat, accumulated since this time has been made possible using 210Pb (t1/2 = 22.3 yr), but the validity of the age-depth relationship obtained must always be assessed using one or more chronostratigraphic markers. The post-industrial period provides an enormous range of possible time markers including various fallout radionuclides, numerous trace metals and their isotopes, and countless organic contaminants. Most of these have not yet been explored, and will be helpful only if they are immobile in the peat column; often, their fate during chemical diagenesis in anoxic, acidic bog waters is either unknown or at least poorly understood. The atmospheric bomb pulse curve of 14C for the period since AD 1950 has proved to be particularly valuable for validating 210Pb chronologies by providing accurate dates for individual plant macrofossils. Peat cores collected in northern Alberta, surrounding open pit mines and upgraders of Athabsca Bituminous Sands, were carefully dated using 210Pb and the age-depth relationship evaluated using both 241Am and 14C. The cores nearest industry (MIL, JPH4) show that atmospheric deposition of trace metals has been declining ever since industrial-scale mining and refining began in 1967. This includes all of the potentially toxic trace elements (Ag, Cd, Pb, Sb, Tl), but also the metals known for their enrichment in bitumen (V, Ni, Mo). In fact, the surface layers of these bogs today are comparable in composition to the "cleanest" peat samples ever found in the northern hemisphere. Our findings are completely opposed to recent claims about environmental pollution by metals from mining and upgrading in this region, illustrating the importance of reliable age dates and the value of robust age-depth models.
75 FR 14243 - Research, Engineering And Development Advisory Committee
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2010-03-24
... DEPARTMENT OF TRANSPORTATION Federal Aviation Administration Research, Engineering And Development....S.C. App. 2), notice is hereby given of a meeting of the FAA Research, Engineering and Development...: Research, Engineering & Development Advisory Committee. Time and Date: April 21, 2010--9 a.m. to 5 p.m...
78 FR 47049 - Research, Engineering and Development Advisory Committee
Federal Register 2010, 2011, 2012, 2013, 2014
2013-08-02
... DEPARTMENT OF TRANSPORTATION Federal Aviation Administration Research, Engineering and Development...; 5 U.S.C. App. 2), notice is hereby given of a meeting of the FAA Research, Engineering and.... Name: Research, Engineering & Development Advisory Committee. Time and Date: September 18--8:30 a.m. to...
77 FR 54648 - Research, Engineering and Development Advisory Committee
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2012-09-05
... DEPARTMENT OF TRANSPORTATION Federal Aviation Administration Research, Engineering and Development....S.C. App. 2), notice is hereby given of a meeting of the FAA Research, Engineering and Development...: Research, Engineering & Development Advisory Committee. TIME AND DATE: September 26, 2012--9 a.m. to 4 p.m...
78 FR 63128 - Dried Prunes Produced in California; Increased Assessment Rate
Federal Register 2010, 2011, 2012, 2013, 2014
2013-10-23
...; Increased Assessment Rate AGENCY: Agricultural Marketing Service, USDA. ACTION: Proposed rule. SUMMARY: This... the Regulatory Flexibility Act (RFA) (5 U.S.C. 601-612), the Agricultural Marketing Service (AMS) has... prunes. Dated: October 17, 2013. Rex A. Barnes, Associate Administrator, Agricultural Marketing Service...
A novel upgrade to Helsinki AMS: Fast switching of isotopes with electrostatic deflectors
NASA Astrophysics Data System (ADS)
Palonen, V.; Tikkanen, P.
2015-10-01
We have developed and installed electrostatic deflectors at the injection magnet entrance and exit to enable fast switching between isotopes in AMS measurements. The fast selection of the injected isotope, stable isotope current measurements, and rare isotope detection are all performed with three synchronized real-time NI-PXI computers. With the improvements, we are able to attain a precision of better than 0.2% for the 14C/13C ratio of modern samples.
Late Holocene Environmental Changes from NY-NJ Estuaries
NASA Technical Reports Server (NTRS)
Peteet, Dorothy M.
2000-01-01
High-resolution records of environmental change in the lower Hudson estuary are quite rare. We present preliminary data from several marshes in the New York- New Jersey region in order to understand the late Holocene environmental history of this region. Our project includes salt marsh cores from Hackensack, Piermont, Staten Island, and Jamaica Bay. Our preliminary research has focused on a 11.15 m sediment core from Piermont Marsh, New York (40 deg N, 74 deg W) in an attempt to document the Holocene environmental history of the region. Lithology, loss -on -ignition (LOI), pollen, plant macrofossils, charcoal, and foraminifera were analyzed. Core lithology consists of peat, silts, and clays that vary in color and texture. The base of the core is AMS C-14 dated to 4190 yr BP. Preliminary low-resolution analysis of the core to date includes sampling at the 1-meter interval throughout the core. LOI of the sediments ranges from 1% to 85%. Average rate of deposition is about .26 cm/yr. Major changes in pollen percentages are visible throughout the core.
Late Quaternary Megafaunal Extinctions in Northern Eurasia: Latest Results
NASA Astrophysics Data System (ADS)
Stuart, Anthony
2010-05-01
Anthony J. Stuart1 & Adrian M. Lister2 1 Biological and Biomedical Sciences, Durham University, South Road, Durham DH1 3LE, UK. Email: tony.s@megafauna.org.uk 2 Department of Palaeontology, The Natural History Museum, Cromwell Road, London SW7 5BD, UK. Email: a.lister@nhm.ac.uk. The global extinction of many spectacular species of megafauna (large terrestrial mammals, together with a few large reptiles and birds) within the last c. 50,000 years (Late Quaternary) has been attributed on the one hand to ‘overkill' by human hunters and on the other to environmental change. However, in spite of more than half a century of active interest and research the issue remains unresolved, largely because there are insufficient dated records of megafaunal species for most parts of the world. Northern Eurasia is an especially fruitful region in which to research megafaunal extinctions as it has a wealth of megafaunal material and crucially most extinctions occurred well within the range of radiocarbon dating. Our approach, in a series of projects over the last decade funded by the UK Natural Environment Research Council (NERC), involves amassing radiocarbon dates made directly on megafaunal material from across the entire region: a) by submitting a substantial number of samples (so far c. 500 dates) for AMS dating at Oxford (ORAU); b) obtaining AMS dates from colleagues working on aDNA projects; and c) carefully screening (‘auditing') dates from the literature. The dates (calibrated using OxCal) are plotted as time-sliced maps and as chronological/geographical charts. In our previous work we targeted a range of extinct species from Northern Eurasia: woolly mammoth, woolly rhinoceros, giant deer, cave bear (in collaboration with Martina Pacher), cave lion, and spotted hyaena (which survives today only in Sub-Saharan Africa). By this means we have established a reliable chronology for these extinctions which we are able to compare with the climatic, vegetational and archaeological records in collaboration with colleagues at Durham University, Royal Holloway, University of London and Southampton University. It is clear from the results that environmental change had a major impact, but the geographical and chronological patterns are complex and there is striking variation in extinction dynamics between species. For example cave bear and spotted hyaena show early extinction in Europe c.28 cal ka, whereas cave lion and woolly rhino disappeared in the Late Glacial c.14 cal ka, and mammoth and giant deer persisted in limited areas well into the Holocene. Our current NERC funded project (3 years from March 2009) extends the scope of our research to include several species that survive to the present day: e.g. musk ox, reindeer, horse, red deer, and moose, and is also extended geographically to Alaska, and the Yukon. Modelling of vegetational changes during the last 40,000 years (by our colleagues at Durham: Judy Allen, Yvonne Collingham, Brian Huntley, using LPJ-Guess data from Paul Valdes) is providing much better geographical coverage than the available pollen data, and also structure and productivity of the vegetation - both of considerable importance to the mammal fauna. Comparing the chronological and geographical dynamics of extant and extinct species promises to shed light on why some species were lost whereas others survived. Moreover, by using a niche-modelling approach we hope to show whether or not species became extinct due to habitat loss, or whether other factors such as human hunting might have been involved in their final disappearance.
Zuffa, G.G.; Normark, W.R.; Serra, F.; Brunner, C.A.
2000-01-01
Escanaba Trough is the southernmost segment of the Gorda Ridge and is filled by sandy turbidites locally exceeding 500 m in thickness. New results from Ocean Drilling Program (ODP) Sites 1037 and 1038 that include accelerator mass spectrometry (AMS) 14C dates and revised petrographic evaluation of the sediment provenance, combined with high-resolution seismic-reflection profiles, provide a lithostratigraphic framework for the turbidite deposits. Three fining-upward units of sandy turbidites from the upper 365 m at ODP Site 1037 can be correlated with sediment recovered at ODP Site 1038 and Deep Sea Drilling Program (DSDP) Site 35. Six AMS 14C ages in the upper 317 m of the sequence at Site 1037 indicate that average deposition rates exceeded 10 m/k.yr. between 32 and 11 ka, with nearly instantaneous deposition of one ~60-m interval of sand. Petrography of the sand beds is consistent with a Columbia River source for the entire sedimentary sequence in Escanaba Trough. High-resolution acoustic stratigraphy shows that the turbidites in the upper 60 m at Site 1037 provide a characteristic sequence of key reflectors that occurs across the floor of the entire Escanaba Trough. Recent mapping of turbidite systems in the northeast Pacific Ocean suggests that the turbidity currents reached the Escanaba Trough along an 1100-km-long pathway from the Columbia River to the west flank of the Gorda Ridge. The age of the upper fining-upward unit of sandy turbidites appears to correspond to the latest Wisconsinan outburst of glacial Lake Missoula. Many of the outbursts, or jokulhlaups, from the glacial lakes probably continued flowing as hyperpycnally generated turbidity currents on entering the sea at the mouth of the Columbia River.
NASA Astrophysics Data System (ADS)
Felton, J. S.; Turteltaub, K. W.; Vogel, J. S.; Balhorn, R.; Gledhill, B. L.; Southon, J. R.; Caffee, M. W.; Finkel, R. C.; Nelson, D. E.; Proctor, I. D.; Davis, J. C.
1990-12-01
We are utilizing accelerator mass spectrometry as a sensitive detector for tracking the disposition of radioisotopically labeled molecules in the biomedical sciences. These applications have shown the effectiveness of AMS as a tool to quantify biologically important molecules at extremely low levels. For example, AMS is being used to determine the amount of carcinogen covalently bound to animal DNA (DNA adduct) at levels relevent to human exposure. Detection sensitivities are 1 carcinogen molecule bound in 1011 to 1012 DNA bases, depending on the specific activity of the radiolabeled carcinogen. Studies have been undertaken in our laboratory utilizing heterocyclic amine food-borne carcinogens and 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD), a potent environmental carcinogen, to study the metabolism of carcinogens at low doses. In addition, AMS is being used to detect the presence of rare proteins (mutant forms of protamine) in human sperm. Approximately l per 106 sperm analyzed contain the rare form of the protamine. Protamine isolated from this small number of cells is being analyzed by AMS, following 14C labeling. Thus, AMS can be used to verify the identity of an extremely small amount of biological material. Furthermore, an additional improvement of 2 orders of magnitude in the sensitivity of biomédical tracer studies is suggested by preliminary work with bacterial hosts depleted in radiocarbon. Other problems in the life sciences where detection sensitivity or sample sizes are limitations should also benefit from AMS. Studies are underway to measure the molecular targeting of cancer chemotherapeutics in human tissue and to pursue applications for receptor biology. We are also applying other candidate isotopes, such as 3H (double labeling with 14C) and 41Ca (bone absorption) to problems in biology. The detection of 36Cl and 26Al have applications for determination of human neutron exposure and understanding neurological toxicity, respectively. The results described here with 14C-labeled molecules coupled with new isotope applications clearly show AMS technology to be an important new tool for the biomedical sciences community.
Can-AMS: The New Accelerator Mass Spectrometry Facility At The University Of Ottawa
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kieser, W. E.; Zhao, X.-L.; Clark, I. D.
2011-06-01
The Canadian Centre for Accelerator Mass Spectrometry (AMS) at the University of Ottawa will be equipped with a new, 3 MV tandem accelerator with peripheral equipment for the analysis of elements ranging from tritium to the actinides. This facility, along with a wide array of support instrumentation recently funded by the Canada Foundation for Innovation, will be located in a new science building on the downtown campus of the University of Ottawa. In addition to providing the standard AMS measurements on {sup 14}C, {sup 10}Be, {sup 26}Al, {sup 36}Cl and {sup 129}I for earth, environmental, cultural and biomedical sciences, thismore » facility will incorporate the new technologies of anion isobar separation at low energies using RFQ chemical reaction cells for {sup 36}Cl and new heavy element applications, integrated sample combustion and gas ion source for biomedical and environmental {sup 14}C analysis and the use of novel target matrices for expanding the range of applicable elements and simplifying sample preparation, all currently being developed at IsoTrace. This paper will outline the design goals for the new facility, present some details of the new AMS technologies, in particular the Isobar Separator for Anions and discuss the design of the AMS system resulting from these requirements.« less
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Radioactivities in returned lunar materials and in meteorites
NASA Technical Reports Server (NTRS)
Fireman, E. L.
1982-01-01
Carbon-14 measurements were made for meteorites with a Van der Graaf accelerator. Accelerator C-14 dating improved the precision by a factor of ten, allowed the use of smaller sample sizes, and gave speedier results than C-14 dating with counters. A methodology for determining the terrestrial ages of several antarctic meteorites is described and the results are listed.
NASA Astrophysics Data System (ADS)
Ha, Sangbeom; Khim, Boo-Keun; Colizza, Ester; Marci, Patrizia; Sagnotti, Leonardo; Caricchi, Chiara; Langone, Leonardo; Giglio, Federico; Kuhn, Gerhard
2017-04-01
High latitude marine environments including the Antarctic continental margin have sensitively responded to the climate change, and the Ross Sea is one of these examples. Subglacial marine sedimentary changes have been studied extensively in the continental shelf areas of the Ross Sea to understand the growth and retreat of glaciers in response to the glacial-interglacial changes. However, the continental slope areas of the Ross Sea have not been investigated comparatively less. Thus, in order to comprehend the glaciomarine sedimentation change on the continental slope of the Ross Sea, 3 gravity cores (GC1, GC2, GC3) and 3 box cores (BC1, BC2, BC3) were collected from 3 sites (RS14-C1, C2, C3 by decreasing water depth), respectively, across the continental slope to the eastern side of the Pennell-Iselin Bank during XXIX PNRA (Rosslope II) cruise in 2014. A variety of sedimentological (grain size, magnetic susceptibility, XRF) and geochemical (biogenic opal, total organic carbon, CaCO3, δ13C of organic matter) properties were analyzed along with AMS 14C dating of bulk sediments. All core sediments consist of mostly hemipelagic sandy clay or silty clay with scattered IRD (Ice-Rafted Debris). Sediment color of three cores changes consistently downward from brown to gray with some alternations in core GC1. Based on the basic sediment properties such as sediment color, grain size, and magnetic susceptibility, sediment lithology was decided to divide Unit A and Unit B, both of which were further divided into two subunits. Despite old carbon effect, AMS 14C dates confirm that Unit A belongs to the Holocene and Unit B covers the deglacial to last glacial period at the top of cores. Unit A is characterized by low TOC, low CaCO3, low biogenic opal content and low C/N ratios, whereas Unit B is characterized by high TOC, high CaCO3, moderate to high biogenic opal content and high C/N ratios. Consequently, Unit A represents the modern and interglacial sediments deposited mainly by the suspension settling of biogenic particles in the open marine condition. In contrast, because Unit B shows higher TOC, CaCO3 content and C/N ratios, these sediments might be supplied by the lateral melt-water plume or distal part of debris flow originated from the front of grounding ice in the subglacial continental shelf under the ice shelf and during the glacial or post-glacial period. Thus, Unit B contains mostly reworked and eroded continental shelf sediments and IRDs. In addition, because the peaks of biogenic opal and TOC contents at Site C1 are distinctly higher than Sites C2 and C3, surface water production occurred under seasonally open marine condition at the deeper Site C1. In conclusion, the influence of subglacial continental shelf sedimentation in terms of melt-water transport and/or distal stage of debris flow was limited as far as to Site C2 during the deglacial and glacial period. However, such depositional effect was insignificant, but the seasonal open marine condition was recognized, at the deeper Site C1 in the continental slope of the Ross Sea.
Lovrić, Z; Kolarić, B; Kosanović Ličina, M L; Tomljenović, M; Đaković Rode, O; Danis, K; Kaić, B; Tešić, V
2018-05-16
In 2017 Zagreb faced the largest outbreak of haemorrhagic fever with renal syndrome (HFRS) to date. We investigated to describe the extent of the outbreak and identify risk factors for infection. We compared laboratory-confirmed cases of Hantavirus infection in Zagreb residents with the onset of illness after 1 January 2017, with individually matched controls from the same household or neighbourhood. We calculated adjusted matched odds ratios (amOR) using conditional logistic regression. During 2017, 104 cases were reported: 11-81 years old (median 37) and 71% (73) male. Compared with 104 controls, cases were more likely to report visiting Mount Medvednica (amOR 60, 95% CI 6-597), visiting a forest (amOR 46, 95% CI 4.7-450) and observing rodents (amOR 20, 95% CI 2.6-159). Seventy per cent of cases (73/104) had visited Mount Medvednica prior to infection. Among participants who had visited Mount Medvednica, cases were more likely to have drunk water from a spring (amOR 22, 95% CI 1.9-265), observed rodents (amOR 17, 95% CI 2-144), picked flowers (amOR 15, 95% CI 1.2-182) or cycled (amOR 14, 95% CI 1.6-135). Our study indicated that recreational activity around Mount Medvednica was associated with HFRS. We recommend enhanced surveillance of the recreational areas during an outbreak.
NASA Astrophysics Data System (ADS)
Currie, L. A.; Kessler, J. D.
2005-10-01
The primary objective of the research reported here has been the development of a hybrid reference material (RM) to serve as a test of accuracy for elemental carbon (EC) isotopic (14C) speciation measurements. Such measurements are vital for the quantitative apportionment of fossil and biomass sources of "soot" (EC), the tracer of fire that has profound effects on health, atmospheric visibility, and climate. Previous studies of 14C-EC measurement quality, carried out with NIST SRM 1649a (Urban Dust), showed a range of results, but since the "truth" was not known for this natural matrix RM, one had to rely on isotopic-chemical consistency evidence (14C in PAH, EC) of measurement validity (Currie et al., 2002). Components of the new Hybrid RM (DiesApple), however, have known 14C and EC composition, and they are nearly orthogonal (isotopically and chemically). NIST SRM 2975 (Forklift Diesel Soot) has little or no 14C, and its major compositional component is EC; SRM 1515 (Apple Leaves) has the 14C content of biomass-C, and it has little or no EC. Thus, the Hybrid RM can serve as an absolute isotopic test for the absence of EC-mimicking pyrolysis-C (char) from SRM 1515 in the EC isolate of the Hybrid RM, as well as a test for conservation of its dominant soot fraction throughout the isolation procedure.
The secondary objective was to employ the Hybrid RM for the comparative evaluation of the thermal optical kinetic (TOK) and thermal optical transmission (TOT) methods for the isolation of EC for micro-molar carbon accelerator mass spectrometry (AMS). As part of this process, the relatively new TOK method was subjected to a critical evaluation and significant development. Key findings of our study are: (1) both methods exhibited biomass-C "leakage"; for TOT, the EC fraction isolated for AMS contained about 8% of the original biomass-C; for TOK, the refractory carbon (RC) isolated contained about 3% of the original biomass-C.; (2) the initial isothermal oxidation stage of the TOK method substantially reduced the transfer of artifact char to the RC fraction, improving isolation capabilities; (3) the Hybrid RM was not equal to the sum of its parts, with matrix interactions inducing premature loss of EC which, however, could be quantified and minimized; (4) the three-stage TOK method provided a superior capability for carbonate quantification at the sub-micromolar level, with "reagent-free" removal of carbonate-C from EC - essential for low-level EC-14C AMS.
Redefining the age of Clovis: implications for the peopling of the Americas.
Waters, Michael R; Stafford, Thomas W
2007-02-23
The Clovis complex is considered to be the oldest unequivocal evidence of humans in the Americas, dating between 11,500 and 10,900 radiocarbon years before the present (14C yr B.P.). Adjusted 14C dates and a reevaluation of the existing Clovis date record revise the Clovis time range to 11,050 to 10,800 14C yr B.P. In as few as 200 calendar years, Clovis technology originated and spread throughout North America. The revised age range for Clovis overlaps non-Clovis sites in North and South America. This and other evidence imply that humans already lived in the Americas before Clovis.
Development of the Accelerator Mass Spectrometry technology at the Comenius University in Bratislava
NASA Astrophysics Data System (ADS)
Povinec, Pavel P.; Masarik, Jozef; Ješkovský, Miroslav; Kaizer, Jakub; Šivo, Alexander; Breier, Robert; Pánik, Ján; Staníček, Jaroslav; Richtáriková, Marta; Zahoran, Miroslav; Zeman, Jakub
2015-10-01
An Accelerator Mass Spectrometry (AMS) laboratory has been established at the Centre for Nuclear and Accelerator Technologies (CENTA) at the Comenius University in Bratislava comprising of a MC-SNICS ion source, 3 MV Pelletron tandem accelerator, and an analyzer of accelerated ions. The preparation of targets for 14C and 129I AMS measurements is described in detail. The development of AMS techniques for potassium, uranium and thorium analysis in radiopure materials required for ultra-low background underground experiments is briefly mentioned.
NASA Astrophysics Data System (ADS)
Naqvi, Wajih A.; Fairbanks, Richard G.
We reconstruct here the history of the Red Sea Outflow (RSO) over the past 27,000 years from an AMS 14C-dated high-resolution δ13C record of benthic foraminifera from the inner Gulf of Aden assuming the dominance of circulation over productivity in regulating benthic δ13C. The results reveal that, following a period of suppressed RSO due to shallow sill 24,000-18,000 yr BP, the Red Sea was vigorously flushed for ˜2,000 years before a major monsoon intensification caused the cessation of deep water formation from 15,500 to 7,300 yr BP. It appears that the monsoon intensification did lag behind insolation until 15,500 yr BP. Between 15,500 and the present, however, there was no lag in conflict with the previous reports, implying a negligible dampening effect of continental albedo during this period. However, since our analysis is confined to a single depth horizon and our record is sensitive to sea level, it has some limitations as an indicator of monsoon intensity.
Porcel, Rosa; Aroca, Ricardo; Cano, Custodia; Bago, Alberto; Ruiz-Lozano, Juan Manuel
2006-10-01
In the present study, a 14-3-3 protein-encoding gene from Glomus intraradices has been identified after differential hybridization of a cDNA library constructed from the fungus growing in vitro and subjected to drought stress by addition of 25% PEG 6000. Subsequently, we have studied its expression pattern under drought stress in vitro and also when forming natural symbioses with different host plants. The results obtained suggest that Gi14-3-3 gene may be involved in the protection that the arbuscular mycorrhizal (AM) symbiosis confers to the host plant against drought stress. Our findings provide new evidences that the contribution of AM fungi to the enhanced drought tolerance of the host plant can be mediated by a group of proteins (the 14-3-3) that regulate both signaling pathways and also effector proteins involved in the final plant responses.
76 FR 30734 - Center for Scientific Review; Notice of Closed Meetings
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2011-05-26
...: Sensory, Motor, and Cognitive Neuroscience. Date: June 30-July 1, 2011. Time: 8 a.m. to 5 p.m. Agenda: To... Panel, Fellowships: Biophysical and Physiological Neuroscience. Date: June 23-24, 2011. Time: 8 a.m. to... Scientific Review Special Emphasis Panel, Fellowships: Brain Disorders and Related Neuroscience. Date: June...
76 FR 1442 - Center for Scientific Review; Notice of Closed Meetings
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2011-01-10
... Group; Macromolecular Structure and Function D Study Section. Date: February 8-9, 2011. Time: 8 a.m. to...; Biomedical Computing and Health Informatics Study Section. Date: February 8, 2011. Time: 8 a.m. to 5 p.m... Skin Sciences Integrated Review Group; Skeletal Muscle and Exercise Physiology Study Section. Date...
Georgiadou, Elisavet; Stenström, Kristina Eriksson; Uvo, Cintia Bertacchi; Nilsson, Peter; Skog, Göran; Mattsson, Sören
2013-05-01
The (14)C content of 60 human blood serum samples from residents of Malmö (Sweden) in 1978, obtained from a biobank, has been measured to estimate the accuracy of (14)C bomb-pulse dating. The difference between the date estimated using the Calibomb software and sampling date varied between -3 ± 0.4 and +0.2 ± 0.5 years. The average age deviation of all samples was -1.5 ± 0.7 years, with the delay between production and consumption of foodstuffs being probably the dominating cause. The potential influence of food habits on the (14)C date has been evaluated using stable isotope δ(13)C and δ(15)N analysis and information about the dietary habits of the investigated individuals. Although the group consisting of lacto-ovo vegetarians and vegans (pooled group) was not completely separated from the omnivores in a stable isotopic trophic level diagram, this analysis proved to add valuable information on probable dietary habits. The age deviation of the sampling date from the respective Calibomb date was found strongly correlated with the δ(13)C values, probably due to influence from marine diet components. For the omnivore individuals, there were indications of seasonal effects on δ(13)C and the age deviation. No significant correlation was found between the age deviation and the δ(15)N values of any dietary group. No influence of sex or year of birth was found on neither the (14)C nor the δ(13)C and δ(15)N values of the serum samples. The data were also divided into two groups (omnivores and pooled group), based on the level of δ(15)N in the samples. The consumption of high δ(15)N-valued fish and birds can be responsible for this clustering.
75 FR 67379 - Center for Scientific Review; Notice of Closed Meetings
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2010-11-02
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Gastrointestinal temperature trends in football linemen during physical exertion under heat stress.
Coris, Eric E; Mehra, Shabnam; Walz, Stephen M; Duncanson, Robert; Jennings, Jason; Nugent, Dylan; Zwygart, Kira; Pescasio, Michele
2009-06-01
Exertional heat stroke is the third leading cause of death in US athletes. Elevations in core temperature in the digestive tract (TGI) have correlated with core temperature and are possible indicators of those at increased risk of heat stroke. The primary objective was to compare a.m. vs. p.m. TGI variation in collegiate football linemen during intense "two-a-day" preseason practice. A secondary objective was to compare longitudinal TGI in offensive and defensive linemen. Cross-sectional observational study. Division I Intercollegiate Athletics Football Program. TGI was monitored during consecutive preseason sessions. TGI, heat illness, weight changes, environmental stress, and subjective symptoms. Mean TGI were 37.8°C and 38.3°C during a.m. and p.m. practices, respectively. The a.m. practices revealed higher TGI gain (1.8°C) compared to p.m. (1.4°C). The p.m. practices had higher maximum TGI than a.m. practices (39.1°C versus 38.8, P=0.0001). Mean time to maximum temperature (Tmax) was 1 hr and 30 min for a.m. and 1 hr and 22 min for p.m. practices. Offensive linemen trended toward higher mean TGI than defensive players (38.0°C vs. 36.7°C, P = 0.069). The rate of rise in TGI was significantly greater in a.m. practices. A decrease in rate of TGI rise was seen from the first to last a.m. practices of the week (P = 0.004). Significant TGI elevations in asymptomatic athletes are common in extreme heat during football practice. Intense a.m. practices in full gear result in higher net temperature gain and rate of temperature gain than p.m. practices. Offensive linemen trended toward higher TGI than defensive linemen. As players acclimatized, a decrease in the rate of TGI increase was appreciable, particularly in a.m. practices. Appreciating cumulative heat stress and variations in heat stress related to scheduling of practice is critical.
NASA Astrophysics Data System (ADS)
Fahrni, Simon M.; Southon, John R.; Santos, Guaciara M.; Palstra, Sanne W. L.; Meijer, Harro A. J.; Xu, Xiaomei
2017-09-01
The vast majority of radiocarbon measurement results (14C/12C isotopic ratios or sample activities) are corrected for isotopic fractionation processes (measured as 13C/12C isotopic ratios) that occur in nature, in sample preparation and measurement. In 1954 Harmon Craig suggested a value of 2.0 for the fractionation ratio b that is used to correct 14C/12C ratios for shifts in the 13C/12C ratios and this value has been applied by the radiocarbon community ever since. While theoretical considerations suggest moderate deviations of b from 2.0, some measurements have suggested larger differences (e.g. b = 2.3, measured by Saliège and Fontes in 1984). With the high precision attained in radiocarbon measurements today (±2‰), even a relatively small deviation of b from 2.0 can impact the accuracy of radiocarbon data, and it is, therefore, of interest to re-evaluate the fractionation corrections. In the present study, the fractionation ratio b was determined by independent experiments on the chemical reduction of carbon dioxide (CO2) to elemental carbon (graphitization reaction) and on the photosynthetic uptake of CO2 by C3 and C4 plants. The results yielded b = 1.882 ± 0.019 for the reduction of CO2 to solid graphite and b = 1.953 ± 0.025 for the weighted mean of measurements involving C3 and C4 photosynthesis pathways. In addition, the analysis of over 9600 full-sized OX-I and OX-II normalizing standards measured between 2002 and 2012 confirms b values lower than 2.0. The obtained values are in good agreement with quantum mechanical estimates of the equilibrium fractionation and classic kinetic fractionation as well as with results from other light three-isotope systems (oxygen, magnesium, silicon and sulfur). While the value of the fractionation ratio varies with the relative importance of kinetic and equilibrium fractionation, the values obtained in the present study cluster around b = 1.9. Our findings suggest that a significant fraction of all samples ("unknowns") would be shifted by 2‰ (16 radiocarbon years) or more due to this effect: for example, for b = 1.882, between 16.8% and 25.9% of almost 60,000 radiocarbon values measured at the Keck Carbon Cycle AMS facility between 2002 and 2012 would be affected. The implications for radiocarbon dating and its accuracy are discussed.
High Purity Americium-241 for Fuel Cycle R&D Program
DOE Office of Scientific and Technical Information (OSTI.GOV)
Dr. Paul A. Lessing
2011-07-01
Previously the U.S. Department of Energy released Am-241 for various applications such as smoke detectors and Am-Be neutron sources for oil wells. At this date there is a shortage of usable, higher purity Am-241 in metal and oxide form available in the United States. Recently, the limited source of Am-241 has been from Russia with production being contracted to existing customers. The shortage has resulted in the price per gram rising dramatically over the last few years. DOE-NE currently has need for high purity Am-241 metal and oxide to fabricate fuel pellets for reactor testing in the Fuel Cycle R&Dmore » program. All the available high purity americium has been gathered from within the DOE system of laboratories. However, this is only a fraction of the projected needs of FCRD over the next 10 years. Therefore, FCR&D has proposed extraction and purification concepts to extract Am-241 from a mixed AmO2-PuO2 feedstock stored at the Savannah River Site. The most simple extraction system is based upon high temperature reduction using lanthanum metal with concurrent evaporation and condensation to produce high purity Am metal. Metallic americium has over a four order of magnitude higher vapor pressure than plutonium. Results from small-scale reduction experiments are presented. These results confirm thermodynamic predictions that at 1000 deg C metallic lanthanum reduces both PuO2 and AmO2. Faster kinetics are expected for temperatures up to about 1500 deg C.« less
NASA Astrophysics Data System (ADS)
Uno, Kevin T.; Quade, Jay; Fisher, Daniel C.; Wittemyer, George; Douglas-Hamilton, Iain; Andanje, Samuel; Omondi, Patrick; Litoroh, Moses; Cerling, Thure E.
2013-07-01
Above-ground thermonuclear weapons testing from 1952 through 1962 nearly doubled the concentration of radiocarbon (14C) in the atmosphere. As a result, organic material formed during or after this period may be radiocarbon-dated using the abrupt rise and steady fall of the atmospheric 14C concentration known as the bomb-curve. We test the accuracy of accelerator mass spectrometry radiocarbon dating of 29 herbivore and plant tissues collected on known dates between 1905 and 2008 in East Africa. Herbivore samples include teeth, tusks, soft tissue, hair, and horn. Tissues formed after 1955 are dated to within 0.3-1.3 y of formation, depending on the tissue type, whereas tissues older than ca. 1955 have high age uncertainties (>17 y) due to the Suess effect. 14C dating of tissues has applications to stable isotope (paleo)ecology and wildlife forensics. We use data from 41 additional samples to determine growth rates of tusks, molars, and hair, which improve interpretations of serial stable isotope data for (paleo)ecological studies. 14C dating can also be used to calculate the time interval represented in periodic histological structures in dental tissues (i.e., perikymata), which in turn may be used as chronometers in fossil teeth. Bomb-curve 14C dating of confiscated animal tissues (e.g., ivory statues) can be used to determine whether trade of the item is legal, because many Convention of International Trade of Endangered Species restrictions are based on the age of the tissue, and thus can serve as a powerful forensic tool to combat illegal trade in animal parts.
Uno, Kevin T.; Quade, Jay; Fisher, Daniel C.; Wittemyer, George; Douglas-Hamilton, Iain; Andanje, Samuel; Omondi, Patrick; Litoroh, Moses; Cerling, Thure E.
2013-01-01
Above-ground thermonuclear weapons testing from 1952 through 1962 nearly doubled the concentration of radiocarbon (14C) in the atmosphere. As a result, organic material formed during or after this period may be radiocarbon-dated using the abrupt rise and steady fall of the atmospheric 14C concentration known as the bomb-curve. We test the accuracy of accelerator mass spectrometry radiocarbon dating of 29 herbivore and plant tissues collected on known dates between 1905 and 2008 in East Africa. Herbivore samples include teeth, tusks, soft tissue, hair, and horn. Tissues formed after 1955 are dated to within 0.3–1.3 y of formation, depending on the tissue type, whereas tissues older than ca. 1955 have high age uncertainties (>17 y) due to the Suess effect. 14C dating of tissues has applications to stable isotope (paleo)ecology and wildlife forensics. We use data from 41 additional samples to determine growth rates of tusks, molars, and hair, which improve interpretations of serial stable isotope data for (paleo)ecological studies. 14C dating can also be used to calculate the time interval represented in periodic histological structures in dental tissues (i.e., perikymata), which in turn may be used as chronometers in fossil teeth. Bomb-curve 14C dating of confiscated animal tissues (e.g., ivory statues) can be used to determine whether trade of the item is legal, because many Convention of International Trade of Endangered Species restrictions are based on the age of the tissue, and thus can serve as a powerful forensic tool to combat illegal trade in animal parts. PMID:23818577
Uno, Kevin T; Quade, Jay; Fisher, Daniel C; Wittemyer, George; Douglas-Hamilton, Iain; Andanje, Samuel; Omondi, Patrick; Litoroh, Moses; Cerling, Thure E
2013-07-16
Above-ground thermonuclear weapons testing from 1952 through 1962 nearly doubled the concentration of radiocarbon ((14)C) in the atmosphere. As a result, organic material formed during or after this period may be radiocarbon-dated using the abrupt rise and steady fall of the atmospheric (14)C concentration known as the bomb-curve. We test the accuracy of accelerator mass spectrometry radiocarbon dating of 29 herbivore and plant tissues collected on known dates between 1905 and 2008 in East Africa. Herbivore samples include teeth, tusks, soft tissue, hair, and horn. Tissues formed after 1955 are dated to within 0.3-1.3 y of formation, depending on the tissue type, whereas tissues older than ca. 1955 have high age uncertainties (>17 y) due to the Suess effect. (14)C dating of tissues has applications to stable isotope (paleo)ecology and wildlife forensics. We use data from 41 additional samples to determine growth rates of tusks, molars, and hair, which improve interpretations of serial stable isotope data for (paleo)ecological studies. (14)C dating can also be used to calculate the time interval represented in periodic histological structures in dental tissues (i.e., perikymata), which in turn may be used as chronometers in fossil teeth. Bomb-curve (14)C dating of confiscated animal tissues (e.g., ivory statues) can be used to determine whether trade of the item is legal, because many Convention of International Trade of Endangered Species restrictions are based on the age of the tissue, and thus can serve as a powerful forensic tool to combat illegal trade in animal parts.
Subattomole sensitivity in biological accelerator mass spectrometry.
Salehpour, Mehran; Possnert, Göran; Bryhni, Helge
2008-05-15
The Uppsala University 5 MV Pelletron tandem accelerator has been used to study (14)C-labeled biological samples utilizing accelerator mass spectrometry (AMS) technology. We have adapted a sample preparation method for small biological samples down to a few tens of micrograms of carbon, involving among others, miniaturizing of the graphitization reactor. Standard AMS requires about 1 mg of carbon with a limit of quantitation of about 10 amol. Results are presented for a range of small sample sizes with concentrations down to below 1 pM of a pharmaceutical substance in human blood. It is shown that (14)C-labeled molecular markers can be routinely measured from the femtomole range down to a few hundred zeptomole (10 (-21) mol), without the use of any additional separation methods.
Low-level biological dosimetry of heterocyclic amine carcinogens isolated from cooked food.
Turteltaub, K W; Vogel, J S; Frantz, C; Buonarati, M H; Felton, J S
1993-01-01
The bioavailability and the bioreactivity of the carcinogenic heterocyclic amine [2-14C]2-amino-1-methyl-6-phenyl-imidazo[4,5-b]pyridine (PhIP) have been investigated at a dose approximating that likely from the human diet by accelerator mass spectrometry (AMS). [2-14C]PhIP was administered to mice at a dose equivalent ot the consumption of two 100 g beef patties (41 ng/kg). The biological half-life of PhIP was 1 hr, with 90% of the dose being excreted via the urine. Peak tissue PhIP concentrations were reached within 3 hr, with the highest levels in the tissues of the gastrointestinal tract, followed by the liver, kidney, pancreas, and thymus. Since the detection limit by AMS is dependent on the natural abundance of 14C, we have achieved further increases in sensitivity by producing mice that have 20% of the natural abundance of 14C. Use of these 14C-depleted animals allows measurements to be made near the natural level of exposure for many environmental carcinogens. PhIP-DNA adduct levels have also been measured by 32P-postlabeling at doses of 1.0, 10, and 20 mg/kg. The highest adduct levels were found in the pancreas, thymus, heart, and liver and increased linearly with dose. The principal adducts are derived from guanine. Images FIGURE 4. A FIGURE 4. B PMID:8319619
76 FR 41221 - Federal Advisory Committee; Defense Health Board (DHB) Meeting
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2011-07-13
... Federal Advisory Committee Act of 1972 (5 U.S.C., Appendix as amended), the Sunshine in the Government Act of 1976 (5 U.S.C. 552b, as amended), and 41 CFR 102-3.150, and in accordance with Section 10(a)(2) of...:30 p.m. and from 1:30 to 5 p.m. DATES: The meeting will be held-- August 8, 2011 8-9 a.m...
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2013-08-16
...,402 hours. c. VA Form 10-7959c--6,728 hours. d. VA Form 10-7959d--467 hours. e. VA Form 10-7959e--1500...,000. Dated: August 13, 2013. By direction of the Secretary. Crystal Rennie, VA Clearance Officer, U.S. Department of Veterans Affairs. [FR Doc. 2013-19914 Filed 8-15-13; 8:45 am] BILLING CODE 8320-01-P ...
Intra-annual variability of the radiocarbon content of corals from the Galapagos Islands
DOE Office of Scientific and Technical Information (OSTI.GOV)
Brown, T.A.; Farwell, G.W.; Schmidt, F.H.
1993-01-01
The authors report AMS [sup 14]C measurements on sub annual samples of coral from the Galapagos Islands that span the period, 1970-1973. Both the major 1972 El Nino/Southern Oscillation event and intra-annual changes in regional upwelling of [sup 14]C-depleted waters associated with alternation of surface-ocean current patterns are evident in the record. These data show that the corals preserve a detailed record of past intra-annual variations of the [sup 14]C content of surface ocean water.
75 FR 19983 - National Heart, Lung, and Blood Institute; Notice of Closed Meetings
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2010-04-16
... Cardiovascular Conditions (GenTAC). Date: May 12, 2010. Time: 10 a.m. to 1 p.m. Agenda: To review and evaluate... Emphasis Panel, NHLBI Cardiovascular Outcomes Research Coordinating Unit. Date: May 25, 2010. Time: 8 a.m... Blood Institute Special Emphasis Panel, NHLBI Centers for Cardiovascular Outcomes Research. Date: May 25...
NASA Astrophysics Data System (ADS)
Mangerud, J.; Bondevik, S.; Gulliksen, S.; Birks, H. H.; Reimer, P.; Hufthammer, A. K.; Hoisaeter, T.
2005-12-01
In order to compare radiocarbon dates on marine and terrestrial samples, the former have to be corrected for a marine reservoir age. We have calculated present day reservoir ages in this area by dating 22 whales collected AD 1860-1901 and 23 molluscs collected AD 1857-1926. Whales feed on pelagic organisms and will provide the reservoir age for the open ocean surface water. However, they travel large distances and integrate the reservoir ages of water masses along their way. Molluscs are stationary and monitor the sea water passing their living site. For the surface water in the N-Atlantic and Norwegian Sea we recommend to use the mean obtained for the two sets, i.e. reservoir ages of 400 +/- 40 and 375 +/- 30 years relative to tree rings of Intcal04 and British oak respectively, for the parts of the Holocene where specific time-dependent reservoir ages are not determined. The reservoir ages relative to British oak best reflects regional processes and we therefore prefer those, whereas IntCal04 ages are much more precisely determined, but dominated by trees from NW-USA in this time period. The reservoir ages for Allerod-Younger Dryas (YD) are obtained by dating parallel samples of terrestrial plant fragments and marine shells from sediment cores from the outermost western coast of Norway. The marine mud contains both plant fragments blown or washed in from adjacent land and in situ marine shells. In the earliest period (13,800-14,500 cal yrs BP) the reservoir age is 300-400 years, similar to present day values. This suggests that the exchange of CO2 between the atmosphere and the surface ocean was comparable to the present. During a short interval 13,200-13,500 cal yrs BP we found higher reservoir ages of 500-600 years coinciding with lower organic carbon content in our cores, and an inter-Allerod fluctuation seen in marine records. During the early YD the reservoir ages increased gradually from 400 to 650 years, causing a 700-14C year-long plateau, centred at 11,000 14C yrs BP, for marine dates at a time of high resolution for terrestrial dates. This may reflect increased annual sea-ice cover, reducing the rate of CO2 exchange between the atmosphere and the sea surface. But better; our dates show that the marine 14C ages decreased rapidly from 10,600 to 10,100 14C yrs BP. This is the time of the well-known 10,000 14C year plateau in terrestrial dates, and the result is that one can obtain higher resolution of calibrated marine 14C dates at the YD/Holocene transition than for terrestrial 14C dates. This presentation is based on two manuscripts that will be submitted about 1. Sept 2005: Bondevik, S., Mangerud, J., Birks, H. H., Gulliksen, S., and Reimer, P.: Late-glacial reservoir ages of surface waters in the North Atlantic. Mangerud, J., Bondevik, S., Gulliksen, S., Hufthammer, A.K., Hoisaeter, T.: Marine 14C reservoir ages for whales and molluscs from the North Atlantic.
NASA Astrophysics Data System (ADS)
Dean, Joshua F.; Billett, Michael F.; Dinsmore, Kerry J.; Garnett, Mark H.; van der Velde, Ype
2017-04-01
Radiocarbon (14C) dating of dissolved organic carbon (DOC) in Arctic freshwaters has been used as a crucial tool for detecting old C mobilised from thawing permafrost, but DO14C in major Arctic rivers is usually quite young. New methods for the collection of both CO2 and CH4 from inland waters allow novel observation of dissolved 14CO2 and 14CH4 alongside DO14C, and provide a more sensitive method than aquatic OC alone - published Arctic freshwater 14C studies to date focus only on DOC, particulate OC, or ebullition CH4/CO2. The mobilisation of old C sourced from deepening permafrost soil active-layers into Arctic freshwaters has the potential to form a significant positive climate feedback. We compare 14C in DOC, dissolved CO2 and dissolved CH4 at five time points over a single growing season from streams, ponds and lakes underlain by continuous permafrost in the western Canadian Arctic. Using age distribution analysis based on atmospheric 14CO2 records, we estimated the age of aquatic C that would otherwise be labelled as "modern" due to the 14C bomb peak. We then calculated the vertical and lateral C fluxes in the study systems, and estimated the proportion derived from old permafrost C. The upper organic-rich soils are the dominant hydrologic pathway, which were completely thawed by late season, and we hypothesised that mobilisation of older, deeper organic soil C would be visible in the aquatic 14C by late in the growing season. Early in the season, median aquatic DO14C and CO2 ages were 65-131 years old (all 14C ages reported here are years before sampling date). By the end of the season, DO14C was 156-271 years old, while CO2 was 113-161 years old, demonstrating that aquatic C ages reflect the mobilisation of thawing older permafrost C. CH4 concentrations were generally low throughout and only two dates were obtained: 202 and 1,970 years old. Overall there was limited evidence of very old permafrost organic C, which comprised 0-10% of vertical and lateral aquatic fluxes. Our results demonstrate that permafrost thaw will result in the mobilisation of old C into the aquatic phase as DOC, CO2 and CH4, but also indicate potential resilience within these systems in response to climate change.
Degradation parameters of amaranth, barley and quinoa in alpacas fed grass hay.
Nilsen, B; Johnston, N P; Stevens, N; Robinson, T F
2015-10-01
This study was conducted to determine the compartment 1 (C1) characteristics of alpacas (fistulated male, 7 ± 1.5 years old, 61 ± 5 kg BW) fed grass hay (GH) supplemented with amaranth (AM), quinoa (Q) and barley (B) grains. Alpacas were provided water ad libitum while housed in metabolism crates. The GH and GH plus treatments were fed at 0700 every day. Treatment periods were for 14 days in which GH or GH plus one of the grain treatments were randomly allocated. On day 14, volatile fatty acids (VFA), pH and ammonia nitrogen (NH3 -N) were determined at 1, 3, 6, 10, 14, 18 and 24 h post-feeding. C1 degradation of each feed component was also determined with the alpacas being fed GH only and the samples incubated for 0, 2, 4, 8, 14, 24, 48 and 72 h. Dry matter (DM), neutral detergent fibre (NDF) and crude protein (CP) were determined and were divided into three categories: a = immediately soluble; b = the non-soluble but degradable; and u = non-degradable/unavailable, potential extent of degradation (PE), degradation rate (c) and effective degradation (ED). C1 passage rate was determined using acid detergent insoluble ash as a marker and was calculated to be 5.5%∙h-1. Total DM intake was highest (p < 0.05) for B and resulted in a higher (p < 0.05) CP intake. GH and AM were different in mean pH (6.81 and 6.66, respectively). B NH3 -N was greater (p < 0.05) than the other treatments. Total VFA was greatest (p < 0.05) for AM, with the greatest composition differences being a shift form acetate percentage to butyrate. DM, NDF and CP degradation was different across the treatments, where PE and ED were higher (p < 0.05) for the grain treatments. The pseudo-grains AM and Q had similar C1 degradation characteristics to B. Journal of Animal Physiology and Animal Nutrition © 2015 Blackwell Verlag GmbH.
76 FR 24499 - National Eye Institute; Notice of Closed Meeting
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2011-05-02
... DEPARTMENT OF HEALTH AND HUMAN SERVICES National Institutes of Health National Eye Institute....S.C. App.), notice is hereby given of the National Advisory Eye Council. The meeting will be open to...: National Advisory Eye Council. Date: June 16, 2011. Open: 8:30 a.m. to 12 p.m. Agenda: Following opening...
76 FR 53687 - National Eye Institute Notice of Closed Meeting
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2011-08-29
... DEPARTMENT OF HEALTH AND HUMAN SERVICES National Institutes of Health National Eye Institute....S.C. App.), notice is hereby given of the National Advisory Eye Council. The meeting will be open to...: National Advisory Eye Council. Date: October 13, 2011. Open: 8:30 a.m. to 12 p.m. Agenda: Following opening...
77 FR 2076 - National Eye Institute; Notice of Closed Meeting
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2012-01-13
... DEPARTMENT OF HEALTH AND HUMAN SERVICES National Institutes of Health National Eye Institute....S.C. App.), notice is hereby given of the National Advisory Eye Council. The meeting will be open to...: National Advisory Eye Council. Date: February 2, 2012. Open: 8 a.m. to 12 p.m. Agenda: Following opening...
77 FR 55852 - National Eye Institute; Notice of Closed Meeting
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2012-09-11
... DEPARTMENT OF HEALTH AND HUMAN SERVICES National Institutes of Health National Eye Institute....S.C. App.), notice is hereby given of the National Advisory Eye Council. The meeting will be open to...: National Advisory Eye Council. Date: October 4, 2012. Open: 8:30 a.m. to 2 p.m. Agenda: Following opening...
75 FR 76474 - National Eye Institute; Notice of Closed Meeting
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2010-12-08
... DEPARTMENT OF HEALTH AND HUMAN SERVICES National Institutes of Health National Eye Institute....S.C. App.), notice is hereby given of the National Advisory Eye Council. The meeting will be open to...: National Advisory Eye Council. Date: January 20, 2011. Open: 8:30 a.m. to 12 p.m. Agenda: Following opening...
77 FR 73037 - National Eye Institute; Notice of Closed Meeting
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2012-12-07
... DEPARTMENT OF HEALTH AND HUMAN SERVICES National Institutes of Health National Eye Institute....S.C. App.), Notice is Hereby Given of the National Advisory Eye Council. The meeting will be open to...: National Advisory Eye Council. Date: January 10, 2013. Open: 8:30 a.m. to 2:00 p.m. Agenda: Following...
78 FR 35293 - National Institute of Mental Health; Notice of Meeting
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2013-06-12
... U.S.C. App.), notice is hereby given of an Interagency Autism Coordinating Committee (IACC or... related to autism spectrum disorder (ASD) research and services activities. The meeting will be open to... Autism Coordinating Committee (IACC). Type of meeting: Open Meeting. Date: July 9, 2013. Time: 9:00 a.m...
75 FR 35801 - Meeting of the National Drinking Water Advisory Council-Notice of Public Meeting
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2010-06-23
... a.m. to noon, Eastern Daylight Savings Time. ADDRESSES: The meeting will be held at the Hotel... ensure adequate time for public involvement, individuals or organizations interested in presenting an... to give EPA as much time as possible to process your request. Dated: June 17, 2010. Cynthia C...
76 FR 23612 - National Institute of Dental & Craniofacial Research; Notice of Meeting
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2011-04-27
... DEPARTMENT OF HEALTH AND HUMAN SERVICES National Institutes of Health National Institute of Dental... amended (5 U.S.C. App.), notice is hereby given of a meeting of the National Advisory Dental and... Committee: National Advisory Dental and Craniofacial Research Council. Date: May 23, 2011. Open: 8:30 a.m...
78 FR 24761 - National Institute of Dental & Craniofacial Research; Notice of Meeting
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2013-04-26
... DEPARTMENT OF HEALTH AND HUMAN SERVICES National Institutes of Health National Institute of Dental... amended (5 U.S.C. App.), notice is hereby given of a meeting of the National Advisory Dental and... Committee: National Advisory Dental and Craniofacial Research Council. Date: May 21, 2013. Open: 8:30 a.m...
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2011-08-23
... OFFICE OF PERSONNEL MANAGEMENT 5 CFR Part 843 RIN 3206-AM29 Federal Employees' Retirement System; Present Value Conversion Factors for Spouses of Deceased Separated Employees AGENCY: Office of Personnel... Subpart C of Part 843--Present Value Conversion Factors for Earlier Commencing Date of Annuities of...
78 FR 34994 - Defense Health Board; Notice of Federal Advisory Committee Meeting
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2013-06-11
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78 FR 65318 - National Committee on Vital and Health Statistics: Meeting Full Committee
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2013-10-31
... DEPARTMENT OF HEALTH AND HUMAN SERVICES National Committee on Vital and Health Statistics: Meeting... Health Statistics (NCVHS), Full Committee Meeting. Time and Date: November 13, 2013 9:00 a.m.-2:15 p.m..., National Center for Health Statistics, 3311 Toledo Road, Auditorium B & C, Hyattsville, Maryland 20782...
76 FR 57064 - Center for Scientific Review; Notice of Closed Meetings
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2011-09-15
...: Drug Discovery for the Nervous System. Date: October 17-18, 2011. Time: 8 a.m. to 10 a.m. Agenda: To... Neuroscience Integrated Review Group, Biophysics of Neural Systems Study Section. Date: October 13, 2011. Time...
NASA Astrophysics Data System (ADS)
Janle, E.; Sojka, J.; Jackson, G. S.; Lachcik, P.; Einstien, J. A.; Santerre, C. R.
2007-06-01
Environmental pollutants pose a substantial risk to nursing infants. Many of these toxicants (i.e. PCBs, PBDEs, mercury) are passed from the maternal diet to the nursing infant in breast milk. Determining the toxicokinetics has been difficult to measure due to ethical limitations. Since extremely small amounts of 14C can be measured using Accelerator Mass Spectrometry (AMS), a goat model was used to establish a minimum oral dose of 14C-labeled PCB (2,2‧,4,4‧,5,5‧-hexachlorobiphenyl-UL-14C) that could be given to a lactating animal and traced into the milk. An oral dose of 66 nCi/kg body weight (1.84 μg PCB/kg bw) was administered. Plasma and milk samples were collected for 2 months after dosing. The concentration of 14C label reached a peak value of 1.71 ng/ml PCB equivalents in the milk on day 2 and then declined to about 135 pg/ml PCB equivalents in the milk at 3 weeks. A second goat was administered a smaller dose (22 nCi/kg bw; 616 ng PCB/kg bw). A peak concentration of 485 pg PCB equivalents/ml milk occurred at 3 days and declined to 77.6 pg PCB equivalents/ml milk by 3 weeks. Our results indicated that an even lower dosage of labeled-PCB could be used due to the extreme sensitivity of AMS measurement. Extrapolating from current data it is estimated that the dose could be reduced by a factor of 20 (31 ng PCB/kg bw; 1.1 nCi/kg bw) and still be detectable after 2 months. Thus, the potential exists for developing protocols for studying toxicokinetics in humans using radiologically- and toxicologically-benign doses of labeled environmental toxicants.
2014-12-01
itu de (d) Figure 14: 34 DRDC-RDDC-2014- frequency ti m e (a) frequency in de x (b) 0 50 100 150 200 250...frequency tim e (a) frequency in de x (b) 0 50 100 150 200 250 am pl itu de (d) 0 50 100 150 200 250 am pl itu de (c) tim e frequency (e) in de x...frequency (f) 0 50 100 150 200 250 frequency am pl itu de (h) 0 50 100 150 200 250 frequency am pl itu de (g) Figure 9: DRDC-RDDC-2014- 23 24
Jones, K.B.; Hodgins, G.W.L.; Etayo-Cadavid, M. F.; Andrus, C.F.T.; Sandweiss, D.H.
2010-01-01
Mollusk shells provide brief (<5 yr per shell) records of past marine conditions, including marine radiocarbon reservoir age (R) and upwelling. We report 21 14C ages and R calculations on small (~2 mg) samples from 2 Mesodesma donacium (surf clam) shells. These shells were excavated from a semi-subterranean house floor stratum 14C dated to 7625 ?? 35 BP at site QJ-280, Quebrada Jaguay, southern Peru. The ranges in marine 14C ages (and thus R) from the 2 shells are 530 and 170 14C yr; R from individual aragonite samples spans 130 ?? 60 to 730 ?? 170 14C yr. This intrashell 14C variability suggests that 14C dating of small (time-slice much less than 1 yr) marine samples from a variable-R (i.e. variable-upwelling) environment may introduce centuries of chronometric uncertainty. ?? 2010 by the Arizona Board of Regents on behalf of the University of Arizona.
76 FR 30371 - Center for Scientific Review; Meetings
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2011-05-25
... Panel; RFA Panel: Drug Discovery for the Nervous System. Date: June 16-17, 2011. Time: 8 a.m. to 10 a.m... Special Emphasis Panel; RFA Panel: Drug Discovery for the Nervous System. Date: June 17, 2011. Time: 10 a...
78 FR 20670 - Center for Scientific Review; Notice of Closed Meeting
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2013-04-05
...: Diabetes, Metabolism and Obesity. Date: April 11, 2013. Time: 8:00 a.m. to 9:00 a.m. Agenda: To review and..., HHS) Dated: April 1, 2013. Melanie J. Gray, Program Analyst, Office of Federal Advisory Committee...
76 FR 64359 - Center for Scientific Review; Notice of Closed Meetings
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2011-10-18
... Brain, Neurotransmission and Aging Special Emphasis Panel. Date: November 1, 2011. Time: 8 a.m. to 5 p.m...: Cell, Computational and Molecular Biology. Date: November 9, 2011. Time: 10 a.m. to 6 p.m. Agenda: To...
77 FR 23488 - Center for Scientific Review; Notice of Closed Meetings
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2012-04-19
...: Technology development for metabolomics. Date: May 16, 2012. Time: 8 a.m. to 6 p.m. Agenda: To review and... Conflict: Biological Chemistry and Macromolecular Biophysics. Date: May 17-18, 2012. Time: 11 a.m. to 10 p...
77 FR 56855 - Center For Scientific Review; Notice of Closed Meetings
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2012-09-14
... Review Group; Molecular Genetics A Study Section. Date: October 15-16, 2012. Time: 8:00 a.m. to 6:00 p.m... Genetics Study Section. Date: October 15, 2012. Time: 8:00 a.m. to 5:00 p.m. Agenda: To review and evaluate...: Oncology 1--Basic Translational Integrated Review Group; Cancer Molecular Pathobiology Study Section. Date...
77 FR 27470 - Center for Scientific Review Notice of Closed Meetings
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2012-05-10
..., Prevention and Intervention for Addictions Study Section. Date: June 7-8, 2012. Time: 8:00 a.m. to 5:00 p.m...: Bioengineering Sciences & Technologies Integrated Review Group; Nanotechnology Study Section. Date: June 7-8..., Computational Biology and Technology Study Section. Date: June 7-8, 2012. Time: 8:30 a.m. to 6:00 p.m. Agenda...
75 FR 10491 - Center for Scientific Review; Notice of Closed Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2010-03-08
...: Computational Biology, Image Processing, and Data Mining. Date: March 18, 2010. Time: 8 a.m. to 6 p.m. Agenda... Science. Date: March 24, 2010. Time: 12 p.m. to 3:30 p.m. Agenda: To review and evaluate grant...; Fellowship: Biophysical and Biochemical Sciences. Date: March 25-26, 2010. Time: 8 a.m. to 5 p.m. Agenda: To...
NASA Astrophysics Data System (ADS)
Petersen, J. O.; Deschamps, P.; Hamelin, B.; Fourré, E.; Gonçalvès, J.; Zouari, K.; Guendouz, A.; Michelot, J.-L.; Massault, M.; Dapoigny, A.; ASTER Team
2018-05-01
In a semi-arid to arid climate context, dependency on groundwater resources may lead to overexploitation and deterioration of water quality. The Continental Intercalaire (CI) aquifer is one such continental-scale aquifer (more than a million of km2), which is mainly confined, poorly recharged but intensely abstracted. To date, the management of this resource relies on hydrogeological modelling and key parameters such as recharge/discharge rate and groundwater dynamics. We use a combination of residence time indicators (14C, 36Cl, 4He) and stable isotopes of water (2H and 18O) to give greater constraint on the groundwater residence time in the CI. In previous studies, 14C measurements and steady state modelling indicate a residence time of less than 100 ka whereas in others, 36Cl measurements and transient scenarios modelling suggest a longer residence time (>500 ka). In this study, most of the 14C measurements are below the limit of detection, establishing residence times greater than 40 ka and confirming the necessity of strict sampling protocols to exclude all air and AMS measurements when low 14C concentrations are expected. In the Tunisian recharge area, detectable 14C indicate sporadic recharge episodes (3-7 ka and 29-43 ka), whereas 4He and 36Cl concentrations in central areas suggest very old (<2 Ma) groundwaters. In these central areas, chlorine concentration can reach more than 2 g/l. Since 36Cl concentrations are up to 4 time less than the initial input, we are confident there is no excessive deep 36Cl production. We characterise five distinct flowpaths reaching the Tunisian discharge area using their isotopic signatures. According to our mixing model, the average contribution from the main recharge area, the Algerian Atlas Mountains, is around 88%. This value is close to hydrogeological models. Conversely, the contribution from the Dahar Mountains is lower than in the hydrogeological modelling (2% against 10%) whereas the Tinhert shows a greater contribution (10% against 1%). Increase of abstraction from the CI can potentially activate the circulation of old brackish groundwaters and dramatically decrease the water quality in the whole system.
Analysis of 14C and 13C in teeth provides precise birth dating and clues to geographical origin
K, Alkass; BA, Buchholz; H, Druid; KL, Spalding
2011-01-01
The identification of human bodies in situations when there are no clues as to the person’s identity from circumstantial data, poses a difficult problem to investigators. The determination of age and sex of the body can be crucial in order to limit the search to individuals that are a possible match. We analyzed the proportion of bomb pulse derived carbon-14 (14C) incorporated in the enamel of teeth from individuals from different geographical locations. The ‘bomb pulse’ refers to a significant increase in 14C levels in the atmosphere caused by above ground test detonations of nuclear weapons during the cold war (1955-1963). By comparing 14C levels in enamel with 14C atmospheric levels systematically recorded over time, high precision birth dating of modern biological material is possible. Above ground nuclear bomb testing was largely restricted to a couple of locations in the northern hemisphere, producing differences in atmospheric 14C levels at various geographical regions, particularly in the early phase. Therefore, we examined the precision of 14C birth dating of enamel as a function of time of formation and geographical location. We also investigated the use of the stable isotope 13C as an indicator of geographical origin of an individual. Dental enamel was isolated from 95 teeth extracted from 84 individuals to study the precision of the 14C method along the bomb spike. For teeth formed before 1955 (N = 17), all but one tooth showed negative Δ14C values. Analysis of enamel from teeth formed during the rising part of the bomb-spike (1955-1963, N = 12) and after the peak (>1963, N = 66) resulted in an average absolute date of birth estimation error of 1.9 ±1.4 and 1.3 ± 1.0 years, respectively. Geographical location of an individual had no adverse effect on the precision of year of birth estimation using radiocarbon dating. In 46 teeth, measurement of 13C was also performed. Scandinavian teeth showed a substantially greater depression in average δ13C (−14.8) than teeth from subjects raised in Japan (−13.5), Middle East and North Africa (−12.7) and South America (−10.9). In summary, isotopic analysis of carbon in enamel from a single tooth can give a good estimate of the year of birth of an individual and also provide information about the geographical origin of the individual. This strategy can assist police and forensic authorities when attempting to solve unidentified homicide cases and may facilitate the identification work associated with mass disasters. PMID:21208756
Analysis of 14C and 13C in teeth provides precise birth dating and clues to geographical origin.
Alkass, K; Buchholz, B A; Druid, H; Spalding, K L
2011-06-15
The identification of human bodies in situations when there are no clues as to the person's identity from circumstantial data, poses a difficult problem to the investigators. The determination of age and sex of the body can be crucial in order to limit the search to individuals that are a possible match. We analyzed the proportion of bomb pulse derived carbon-14 ((14)C) incorporated in the enamel of teeth from individuals from different geographical locations. The 'bomb pulse' refers to a significant increase in (14)C levels in the atmosphere caused by above ground test detonations of nuclear weapons during the cold war (1955-1963). By comparing (14)C levels in enamel with (14)C atmospheric levels systematically recorded over time, high precision birth dating of modern biological material is possible. Above ground nuclear bomb testing was largely restricted to a couple of locations in the northern hemisphere, producing differences in atmospheric (14)C levels at various geographical regions, particularly in the early phase. Therefore, we examined the precision of (14)C birth dating of enamel as a function of time of formation and geographical location. We also investigated the use of the stable isotope (13)C as an indicator of geographical origin of an individual. Dental enamel was isolated from 95 teeth extracted from 84 individuals to study the precision of the (14)C method along the bomb spike. For teeth formed before 1955 (N=17), all but one tooth showed negative Δ(14)C values. Analysis of enamel from teeth formed during the rising part of the bomb-spike (1955-1963, N=12) and after the peak (>1963, N=66) resulted in an average absolute date of birth estimation error of 1.9±1.4 and 1.3±1.0 years, respectively. Geographical location of an individual had no adverse effect on the precision of year of birth estimation using radiocarbon dating. In 46 teeth, measurement of (13)C was also performed. Scandinavian teeth showed a substantially greater depression in average δ(13)C (-14.8) than teeth from subjects raised in Japan (-13.5), Middle East and North Africa (-12.7) and South America (-10.9). In summary, isotopic analysis of carbon in enamel from a single tooth can give a good estimate of the year of birth of an individual and also provide information about the geographical origin of the individual. This strategy can assist police and forensic authorities when attempting to solve unidentified homicide cases and may facilitate the identification work associated with mass disasters. Copyright © 2010 Elsevier Ireland Ltd. All rights reserved.
NASA Astrophysics Data System (ADS)
Dolgikh, A. V.; Matskovsky, V. V.; Voronin, K. V.; Solomina, O. N.
2017-06-01
The results of dendrochronological and radiocarbon dating by means of accelerator mass spectrometry (AMS) of six medieval icons, originating from northern European Russia and painted on wooden panels made from Scots pine, dated to the 15th to 17th centuries are presented. The panels of each icon were studied using dendrochronology. Five to six AMS dates were obtained for four icons. Although five icons were dendro-dated successfully, one failed to be reliably cross-dated with the existing master tree-ring chronologies and it was dated by radiocarbon wiggle-matching. Dendrochronological dating and wiggle-matching of radiocarbon dates allowed us to determine the narrow chronological intervals of icon creation.
Isotopic Constraints on the Sources and Associations of Organic Compounds in Marine Sediments
2006-02-01
international standard for 14C dating, Standard Reference Material 4990B " Oxalic Acid". Routine precision for 813 C and Aa4 C measurements are --0.1 and...determined by their depositional settings. Group ’a’ includes organic-rich marine sediments from Guaymas basin (GB), a hydrothermal system with active...is the per mille (%0o) deviation from the international standard for 14C dating, Standard Reference Material 4990B " Oxalic Acid". Precision for V C
NASA Astrophysics Data System (ADS)
Rick, Torben C.; Henkes, Gregory A.; Lowery, Darrin L.; Colman, Steven M.; Culleton, Brendan J.
2012-01-01
Radiocarbon dates from known age, pre-bomb eastern oyster (Crassostrea virginica) shells provide local marine reservoir corrections (∆R) for Chesapeake Bay and the Middle Atlantic coastal area of eastern North America. These data suggest subregional variability in ∆R, ranging from 148 ± 46 14C yr on the Potomac River to - 109 ± 38 14C yr at Swan Point, Maryland. The ∆R weighted mean for the Chesapeake's Western Shore (129 ± 22 14C yr) is substantially higher than the Eastern Shore (- 88 ± 23 14C yr), with outer Atlantic Coast samples falling between these values (106 ± 46 and 2 ± 46 14C yr). These differences may result from a combination of factors, including 14C-depleted freshwater that enters the bay from some if its drainages, 14C-depleted seawater that enters the bay at its mouth, and/or biological carbon recycling. We advocate using different subregional ∆R corrections when calibrating 14C dates on aquatic specimens from the Chesapeake Bay and coastal Middle Atlantic region of North America.
Carbon-14 dating of small samples by proportional counting.
Harbottle, G; Sayre, E V; Stoenner, R W
1979-11-09
Conventional carbon-14 dating by means of gas proportional counters has been extended to samples containing as little as 10 milligrams of carbon. The accuracy of the dating procedure has been checked by dating sequoia tree-ring samples of the 1st century A.D. and B.C. and an oak tree-ring sample of the 19th century A.D.
Mammoth (Mammuthus sp.) excavation on a college campus in Western Illinois, USA
Treworgy, J.D.; Saunders, J.J.; Grimley, D.A.
2007-01-01
The discovery of the remains of a mammoth, Mammuthus sp., on the Principia College campus in Elsah, Illinois, has allowed for careful excavation by students over several years. The mammoth is relatively well preserved in late Wisconsin Peoria Silt on the top of the bluffs of the Mississippi River. The mammoth was buried by loess, perhaps as a result of persistent dust storms, approximately 17 500 14C years ago. This age estimate is based on the mammoth's stratigraphic position within the Peoria Silt and is loosely supported by an AMS radiocarbon age on poorly preserved collagen from tooth dentine (???17 810??4300 14C years [CAMS #104172]). Over one hundred bones or bone pieces have been excavated to-date. The skull, containing the tusks and maxillary teeth, is complete and in close proximity to associated postcranial remains, indicating that the mammoth died where it was found. The size and characteristics of skeletal elements have allowed us to determine that this was a mature male of about 41 years of age. Taxonomic attribution-either to Mammuthus primigenius or Mammuthus jeffersonii-is pending, based on the outcome of thorough analysis once the skull with dentition has been prepared from enclosing matrix. ?? 2006 Elsevier Ltd and INQUA.
78 FR 36789 - Center for Scientific Review; Notice of Closed Meetings
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2013-06-19
...: Biochemistry & Macromolecular Biophysics. Date: July 15-17, 2013. Time: 8:00 a.m. to 12:00 p.m. Agenda: To...; Fellowships: Chemistry, Biochemistry and Biophysics. Date: July 17-18, 2013. Time: 8:30 a.m. to 5:00 p.m...
78 FR 14099 - Center for Scientific Review; Notice of Closed Meetings
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2013-03-04
... Pathobiology of Cardiovascular and Respiratory Systems. Date: March 26-27, 2013. Time: 8:00 a.m. to 5:00 p.m... Special Emphasis Panel; Member Conflict: Respiratory Diseases. Date: March 26-27, 2013. Time: 9:00 a.m. to...
Comparative AMS radiocarbon dating of pretreated versus non-pretreated tropical wood samples
NASA Astrophysics Data System (ADS)
Patrut, Adrian; von Reden, Karl F.; Lowy, Daniel A.; Mayne, Diana H.; Elder, Kathryn E.; Roberts, Mark L.; McNichol, Ann P.
2010-04-01
Several wood samples collected from Dorslandboom, a large iconic African baobab ( Adansonia digitata L.) from Namibia, were investigated by AMS radiocarbon dating subsequent to pretreatment and, alternatively, without pretreatment. The comparative statistical evaluation of results showed that there were no significant differences between fraction modern values and radiocarbon dates of the samples analyzed after pretreatment and without pretreatment, respectively. The radiocarbon date of the oldest sample was 993 ± 20 BP. Dating results also revealed that Dorslandboom is a multi-generation tree, with several stems showing different ages.
NASA Astrophysics Data System (ADS)
Rahim, K. J.; Cumming, B. F.; Hallett, D. J.; Thomson, D. J.
2007-12-01
An accurate assessment of historical local Holocene data is important in making future climate predictions. Holocene climate is often obtained through proxy measures such as diatoms or pollen using radiocarbon dating. Wiggle Match Dating (WMD) uses an iterative least squares approach to tune a core with a large amount of 14C dates to the 14C calibration curve. This poster will present a new method of tuning a time series with when only a modest number of 14C dates are available. The method presented uses the multitaper spectral estimation, and it specifically makes use of a multitaper spectral coherence tuning technique. Holocene climate reconstructions are often based on a simple depth-time fit such as a linear interpolation, splines, or low order polynomials. Many of these models make use of only a small number of 14C dates, each of which is a point estimate with a significant variance. This technique attempts to tune the 14C dates to a reference series, such as tree rings, varves, or the radiocarbon calibration curve. The amount of 14C in the atmosphere is not constant, and a significant source of variance is solar activity. A decrease in solar activity coincides with an increase in cosmogenic isotope production, and an increase in cosmogenic isotope production coincides with a decrease in temperature. The method presented uses multitaper coherence estimates and adjusts the phase of the time series to line up significant line components with that of the reference series in attempt to obtain a better depth-time fit then the original model. Given recent concerns and demonstrations of the variation in estimated dates from radiocarbon labs, methods to confirm and tune the depth-time fit can aid climate reconstructions by improving and serving to confirm the accuracy of the underlying depth-time fit. Climate reconstructions can then be made on the improved depth-time fit. This poster presents a run though of this process using Chauvin Lake in the Canadian prairies and Mt. Barr Cirque Lake located in British Columbia as examples.
NASA Astrophysics Data System (ADS)
Currie, L. A.
2003-01-01
Radiocarbon dating would not have been possible if 14C had not had the “wrong” half-life—a fact that delayed its discovery [1]. Following the discovery of this 5730 year radionuclide in laboratory experiments by Ruben and Kamen, it became clear to W. F. Libby that 14C should exist in nature, and that it could serve as a quantitative means for dating artifacts and events marking the history of civilization. The search for natural radiocarbon was a metrological challenge; the level in the living biosphere [ca. 230 Bq/kg] lay far beyond the then current state of the measurement art. This article traces the metrological history of radiocarbon, from the initial breakthrough devised by Libby, to minor (evolutionary) and major (revolutionary) advances that have brought 14C measurement from a crude, bulk [8 g carbon] dating tool, to a refined probe for dating tiny amounts of precious artifacts, and for “molecular dating” at the 10 μg to 100 μg level. The metrological advances led to opportunities and surprises, such as the non-monotonic dendrochronological calibration curve and the “bomb effect,” that spawned new multidisciplinary areas of application, ranging from cosmic ray physics to oceanography to the reconstruction of environmental history.
NASA Astrophysics Data System (ADS)
Martins, G. S.; Cordeiro, R. C.; Turcq, B.; Moreira, L. S.; Bouloubassi, I.; Sifeddine, A.
2014-12-01
Bulk, Isotope and biolomecular analysis supported by 22 14C AMS dates, allowed the reconstruction of environmental changes during the last 35 000 years BP in the Southeast Amazonian basin. A terrestrial origin has been inferred for the odd carbon-numbered long-chain (>C27) n-alkanes. The entire n-alkane δ13C range between -31.7‰ and -36.8‰, which is the isotopic range occupied by C3 vegetation. The C29:C31 ratio shows that a gramineae contribution is higher during the Pleistocene than in Holocene. The n-alkanes concentration decrease between 32 000 - 18 000, suggesting a increase in arid conditions. The ACL index confirm this interpretation showing high values due the Pleistocene linked to more hydrological stress. A shift in the abundance of n-alkane and isotopic values are observed across the late Pleistocene glacial-Holocene interglacial climate change, suggesting a climate-induced vegetational change. During the middle Holocene the n-alcanes values decreases indicating rain forest regression accompanied by increase in the ACL values confirming the dry climate conditions. Comparison with other South American records, our record indicates regression/expansion of the rain forest linked to the South American System monsoon activity since 35 kyrs.
NASA Astrophysics Data System (ADS)
Desjardins, Thierry; Turcq, Bruno; Nguetnkam, Jean-Pierre; Achoundong, Gaston; Mandeng-Yogo, Magloire; Cetin, Fethyé; Lézine, Anne-Marie
2013-07-01
In order to better understand the dynamics of the forest-savanna mosaic from central Cameroon, we analyzed 13C and 14C profiles of six oxisols: two under forests and four under savannas. The δ13C soil profiles collected in the forests indicate that these environments are stable at least since the mid-Holocene, whereas the areas currently covered by savannas were formerly occupied by more forested vegetations. The 14C dating of organic matter indicate that the late extension of the savannas in central Cameroon date from the Late Holocene, starting from 4000-3500 14C yr BP.
NASA Astrophysics Data System (ADS)
Shu, P.; Li, B.; Wang, H.; Cheng, P.; An, Z.; Zhou, W.; Zhang, D. D.
2017-12-01
Taklimakan Desert, the largest arid landform in the Eurasia, is one of the most important dust sources in the world. Growing evidences shows that millennial-scale abrupt climate changes during the last glacial period in the region. However, records on millennial-scale climate and environmental changes remain poorly understood because dating eolian, lacustrine, and fluvial sediments and establishing the reliable environmental proxies from these records are always challenging. Here, we present 32 AMS 14C dates of bulk sediments, grain size, and Rb/Sr ratio parameters from the oasis sequence and dates of bulk loess and charcoal from the upstream source regions to examine the significance of oasis sediments on millennial-scale environmental changes in the Taklimakan Desert. We found that substantial reversal of radiocarbon dates on total organic carbon (TOC) was controlled by source region organic carbon input. Loess hills, alpine meadow north of the study region provided fluvial deposits along drainage system and deflation in the river valleys further provide eolain materials. We argue that early oasis deposits experienced deflation and re-deposition less severe than the younger oasis deposits. After refining radiocarbon age-depth relationships for an age model by Bacon package, proxy records show substantial abrupt fluctuations in climate and environments during the last glacial period, among which three wet intervals, two dry periods are identified. The wetter and warmer conditions during the Holocene facilitated human to occupy the oasis.
76 FR 65206 - Agency Information Collection Activities: Small Vessel Reporting System
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2011-10-20
... States. SVRS is authorized by 8 U.S.C. 1103, 8 U.S.C. 1225, 8 CFR 235.1, 19 U.S.C. 1433, 19 U.S.C. 1498... Review: Approval of a new collection. Affected Public: Individuals. Estimated Number of Respondents: 10... Filed 10-19-11; 8:45 am] BILLING CODE 9111-14-P ...
Buchanan-Banks, J. M.; Lockwood, J.P.; Rubin, M.
1989-01-01
Twenty-eight 14C analyses are reported for carbonized roots and other plant material collected from beneath 15 prehistoric lava flows erupted from the northeast rift zone (NERZ) of Mauna Loa Volcano (ML). The new 14C dates establish ages for 13 previously undated lava flows, and correct or add to information previously reported. Limiting ages on other flows that lie either above or below the dated flows are also established. These dates help to unravel the eruptive history of ML's NERZ. -from Authors
78 FR 50066 - Center for Scientific Review; Notice of Closed Meetings
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2013-08-16
...: Child Psychopathology. Date: September 11, 2013. Time: 9:00 a.m. to 11:59 p.m. Agenda: To review and... and Alcohol. Date: September 18-19, 2013. Time: 8:00 a.m. to 8:00 p.m. Agenda: To review and evaluate...
75 FR 8977 - Center for Scientific Review; Notice of Closed Meetings
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2010-02-26
... Panel; Translational Diabetes and Obesity. Date: March 16-17, 2010. Time: 8 a.m. to 5 p.m. Agenda: To... Special Emphasis Panel; UKGD Member Conflict SEP. Date: March 25, 2010. Time: 11 a.m. to 1 p.m. Agenda: To...
75 FR 36430 - Center for Scientific Review; Notice of Closed Meetings
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2010-06-25
...: Arthritis, Connective Tissue, and Skin (ACTS). Date: July 15, 2010. Time: 8:30 a.m. to 3 p.m. Agenda: To...: Clinical Neuroimmunology and Brain Tumors. Date: July 7, 2010. Time: 11 a.m. to 1 p.m. Agenda: To review...
77 FR 19675 - Center for Scientific Review; Notice of Closed Meetings
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2012-04-02
... Perspectives. Date: April 27, 2012. Time: 8 a.m. to 5 p.m. Agenda: To review and evaluate grant applications... Biointerfaces Study Section. Date: May 3-4, 2012. Time: 8 a.m. to 4 p.m. Agenda: To review and evaluate grant...
75 FR 6044 - Center for Scientific Review; Notice of Closed Meetings
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2010-02-05
..., Member Conflicts: Lung Physiology. Date: March 9-10, 2010. Time: 9 a.m. to 6 p.m. Agenda: To review and..., Stress and Aging. Date: March 12, 2010. Time: 8 a.m. to 6 p.m. Agenda: To review and evaluate grant...
76 FR 63312 - Center for Scientific Review; Notice of Closed Meetings
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2011-10-12
...: Biological Chemistry, Biophysics, and Drug Discovery. Date: November 3-4, 2011. Time: 7:30 a.m. to 12 p.m... Network Analysis and Health. Date: November 4, 2011. Time: 8 a.m. to 6 p.m. Agenda: To review and evaluate...
77 FR 6812 - Center For Scientific Review; Notice of Closed Meetings
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2012-02-09
...: Tools for Zebrafish Research. Date: March 6-7, 2012. Time: 9 a.m. to 6 p.m. Agenda: To review and... Panel; Neurobiology of Brain Disease and Aging. Date: March 6-7, 2012. Time: 10 a.m. to 5 p.m. Agenda...
NASA Astrophysics Data System (ADS)
Gorbarenko, Sergey; Velivetskaya, Tatyana; Malakhov, Mikhail; Bosin, Aleksandr
2017-05-01
Paleoclimate data from the Okhotsk Sea (OS) over Terminations II and I (TII, TI), and the Last and Present Interglacial (LIG, PIG) periods were compiled in order to examine Northern Hemisphere climate and sea level changes. Based on records of four AMS 14C-dated OS cores over TI-PIG, it is argued that the OS productivity/climate, IRD (ice-rafted debris), and benthic foraminiferal oxygen isotope (δ18Obf) proxies provide representative and in-phase evidence of the Northern Hemisphere climate and continental ice sheet changes consistent with the LR 04 δ18Obf curve. Chronologies for two central OS cores over TII-LIG-cooling event 23 (C23) were constructed by correlating OS productivity proxies with well-dated δ18O records of Chinese speleothems because OS environment is modulated by East Asian Monsoon; and, as well as correlating measured magnetic paleointensity excursions with those in the dated PISO-1500 paleointensity stack. Results show several OS climatic and environment states, including TII coeval with Asian Weak Monsoon Interval (WMI) II since 136 ka, LIG with a sharp two-step transition (130.2-129 ka) and demise at С25 (116.5 ka), and last glaciation with coolings at C24 (111 ka) and C23. The OS productivity and IRD records demonstrate certain climate amelioration in the middle of WMI-II, and two insignificant cooling events inside the LIG marked by C27 (126 ka) and C26 (120.6 ka). OS δ18Obf records of both cores demonstrate a gradual trend of lighter values since around 131.5 ka BP, continuing from the onset of LIG (129 ka) to minimum values at 126 ka BP (C27), then nearly constant values until 121.5 ka, followed by a slight increase up to 120.6 ka (C26), and a subsequent strong increase up to 116.5 ka (C25). The magnitude of OS δ18Obf oscillations is 1.35‰, which is less than those in the N. Atlantic. It may therefore be suggested that this OS index probably tracks changes in continental ice sheet volume and sea level.
76 FR 53686 - Center For Scientific Review; Notice of Closed Meetings
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2011-08-29
... Group, Oral, Dental and Craniofacial Sciences Study Section. Date: October 4-5, 2011. Time: 8 a.m. to 5...; Notice of Closed Meetings Pursuant to section 10(d) of the Federal Advisory Committee Act, as amended (5 U.S.C. App.), notice is hereby given of the following meetings. The meetings will be closed to the...
75 FR 69092 - National Institute of General Medical Sciences; Notice of Closed Meeting
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2010-11-10
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75 FR 19245 - Drawbridge Operation Regulation; Elizabeth River, Eastern Branch, VA
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2010-04-14
....1007(b) and (c) to facilitate the resurfacing of the bridge roadway, as modified by the temporary... severe or inclement weather occurs, the alternate closure dates will be rescheduled to May 7-10, 2010 and..., Acting Commander, Fifth Coast Guard District. [FR Doc. 2010-8476 Filed 4-13-10; 8:45 am] BILLING CODE...
2012-06-01
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75 FR 36361 - Malcolm Baldrige National Quality Award Panel of Judges
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2010-06-25
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75 FR 36431 - National Heart, Lung, and Blood Institute; Notice of Meeting
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2010-06-25
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76 FR 23827 - National Heart, Lung, and Blood Institute; Notice of Meeting
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2011-04-28
... Committee: National Heart, Lung, and Blood Advisory Council. Date: June 15, 2011. Open: 8 a.m. to 12 p.m... DEPARTMENT OF HEALTH AND HUMAN SERVICES National Institutes of Health National Heart, Lung, and... amended (5 U.S.C. App.), notice is hereby given of a meeting of the National Heart, Lung, and Blood...
77 FR 22787 - HIT Policy Committee Advisory Meeting; Notice of Meeting
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2012-04-17
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1987-05-01
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Forgery at the Snite Museum of Art? Improving AMS Radiocarbon Dating at the University of Notre Dame
NASA Astrophysics Data System (ADS)
Troyer, Laura; Bagwell, Connor; Anderson, Tyler; Clark, Adam; Nelson, Austin; Skulski, Michael; Collon, Philippe
2017-09-01
The Snite Museum of Art recently obtained several donations of artifacts. Five of the pieces lack sufficient background information to prove authenticity and require further analysis to positively determine the artwork's age. One method to determine the artwork's age is radiocarbon dating via Accelerator Mass Spectrometry (AMS) performed at the University of Notre Dame's Nuclear Science Laboratory. Samples are prepared by combustion of a small amount of material and subsequent reduction to carbon into an iron powder matrix (graphitization). The graphitization procedure affects the maximum measurement rate, and a poor graphitization can be detrimental to the AMS measurement of the sample. Previous graphitization procedures resulted in a particle current too low or inconsistent to optimize AMS measurements. Thus, there was a desire to design and refine the graphitization system. The finalized process yielded physically darker samples and increased sample currents by two orders of magnitude. Additionally, the first testing of the samples was successful, yet analysis of the dates proved inconclusive. AMS measurements will be performed again to obtain better sampling statistics in the hopes of narrowing the reported date ranges. NSF and JINA-CEE.
NASA Astrophysics Data System (ADS)
Shchetnikov, A. A.; Klementiev, A. M.; Filinov, I. A.; Semeney, E. Yu.
2015-03-01
This work presents the data on new finds of fossil macrotheriofauna in the reference sections of the Upper Neopleistocene sediments in the Tunka rift valley (southwestern Baikal Region). The osteological material of a number of Late Neopleistocene mammals including extinct species rare for the Baikal region such as Crocuta spelaea, Panthera spelaea, and Spirocerus kiakhtensis (?) was directly dated with a radiocarbon (AMS) method. The obtained 14C data (18000-35000 years) allow one to rejuvenate significantly the upper limit of the common age interval of habitat of these animals in southern part of Eastern Siberia. Cave hyena and spiral-horned antelope lived in the Tunka rift valley in the Baikal region in Late Kargino time (37-24 ka), and cave lion survived the maximum in the Sartan cryochron in the region (21-20 ka). The study of collected paleontological collections provides a basis for selection of independent Kargino (MIS 3) faunal assemblages to use them for regional biostratigraphic analysis of Pleistocene deposits. Radiocarbon age dating of samples allows one to attribute confidently all paleofaunal remains available to the second half of the Late Pleistocene.
NASA Astrophysics Data System (ADS)
Peñalba, M. Cristina; Arnold, Maurice; Guiot, Joël; Duplessy, Jean-Claude; de Beaulieu, Jacques-Louis
1997-09-01
A 4.5-m-thick late-glacial pollen sequence, supported by 17 AMS 14C dates, has been investigated at the Quintanar de la Sierra marshland (Iberian cordillera, north-central Spain). Pollen zones were defined that correspond to successive phases in vegetation history during the end of the Late Würm, late-glacial interstade, and Younger Dryas periods. A transfer function approach has been adopted to derive quantitative climate estimates from the pollen assemblage data. A first expansion of Juniperusand Hippophae,about 13,500 14C yr B.P., indicates the beginning of the late-glacial interstade which is characterized by a Juniperus-Betula-Pinussuccession that suggests higher temperatures and moisture than during full-glacial time. The Younger Dryas interval is recorded by a 120-cm-thick sediment unit that is dominated by herbaceous pollen. Transfer function estimates suggest that the climate during this period was cold, with low precipitation during most of the year, although not in summer. The Holocene arboreal recolonization in the area started about 10,000 14C yr B.P., with a renewed Juniperus-Betula-Pinussuccession related to a strong increase in annual temperature and precipitation. The start of this process was synchronous with mean sea-surface temperature changes, as recorded from the nearby SU 81-18 marine core. The strong affinity with other European late-glacial pollen sequences demonstrates that the pattern of climatic changes during the last glacial-interglacial transition was similar in both northwestern and southwestern Europe.
The compact AMS facility at Guangzhou Institute of Geochemistry, Chinese Academy of Sciences
NASA Astrophysics Data System (ADS)
Zhu, Sanyuan; Ding, Ping; Wang, Ning; Shen, Chengde; Jia, Guodong; Zhang, Gan
2015-10-01
A compact 14C AMS facility manufactured by the National Electrostatics Corporation (NEC) has been installed at Guangzhou Institute of Geochemistry, Chinese Academy of Sciences (GIGCAS). The system is based on a Model 1.5SDH-1 Pelletron accelerator with a maximum terminal volt 0.6 MV. This paper reports the performance and the operation of this machine in the first several months after installation.
NASA Astrophysics Data System (ADS)
Bos, Johanna A. A.; van Geel, Bas; van der Plicht, Johannes; Bohncke, Sjoerd J. P.
2007-08-01
In order to compare environmental and inferred climatic change during the Preboreal in The Netherlands, five terrestrial records were analysed. Detailed multi-proxy analyses including microfossils (e.g., pollen, spores, algae, and fungal spores), macroremains (e.g., seeds, fruits, wood, mosses, etc.), and loss on ignition measurements were carried out with high temporal resolution. To link the five Preboreal records, accurate chronologies were produced by AMS 14C wiggle-match dating. The Dutch records show that following the Lateglacial/Holocene climate warming, birch woodlands expanded between 11,530 and 11,500 cal BP during the Friesland Phase of the Preboreal. After the Friesland Phase, two distinct climatic shifts could be inferred: (1) around 11,430-11,350 cal BP the expansion of birch forests was interrupted by a dry continental phase with open grassland vegetation, the Rammelbeek Phase. This phase was coeval with the coldest part of the Preboreal oscillation (PBO) as observed in the δ 18O record of the Greenland ice-core records and has been attributed to a large meltwater flux that resulted in a temporary decrease of the thermohaline circulation in the North Atlantic. (2) At the start of the Late Preboreal, between 11,270 and 11,210 cal BP, a sudden shift to a more humid climate occurred and birch forests expanded again. A simultaneous increase in the cosmogenic nuclides 14C and 10Be suggests that these changes in climate and vegetation were forced by a sudden decline in solar activity. Expansion of pine occurred during the later part of the Late Preboreal. At the onset of the Boreal, between 10,770 and 10,700 cal BP, dense woodlands with hazel, oak, elm and pine started to develop in The Netherlands.
78 FR 64225 - Center for Scientific Review; Notice of Closed Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2013-10-28
...: Cancer Diagnostics and Treatments (CDT). Date: November 4-5, 2013. Time: 8:00 a.m. to 5:00 p.m. Agenda... and Skin Systems. Date: November 4, 2013. Time: 8:00 a.m. to 7:00 p.m. Agenda: To review and evaluate...
75 FR 56115 - Center for Scientific Review; Notice of Closed Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2010-09-15
... Processes Integrated Review Group, Biobehavioral Regulation, Learning and Ethology Study Section. Date..., Biobehavioral Regulation, Learning and Ethology. Date: October 8, 2010. Time: 9 a.m. to 10 a.m. Agenda: To..., Cellular and Developmental Neuroscience Integrated Review Group, Biophysics of Neural Systems Study Section...
75 FR 26261 - Center for Scientific Review; Notice of Closed Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2010-05-11
... Committee: Emerging Technologies and Training Neurosciences Integrated Review Group; Molecular Neurogenetics...; Biobehavioral Regulation, Learning and Ethology. Date: June 4, 2010. Time: 9 a.m. to 10 a.m. Agenda: To review... Panel; ARRA: Biobehavioral Regulation, Learning and Ethology Competitive Revisions. Date: June 4, 2010...
76 FR 34716 - Center for Scientific Review; Notice of Closed Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2011-06-14
... and Biology SBIR/STTR. Date: July 11, 2011. Time: 8 a.m. to 5 p.m. Agenda: To review and evaluate..., NeuroAIDS and other End-Organ Diseases Study Section. Date: July 12, 2011. Time: 8 a.m. to 5 p.m. Agenda...
77 FR 75639 - Center for Scientific Review; Notice of Closed Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2012-12-21
... Systems Biology. Date: January 17-18, 2013. Time: 10:00 a.m. to 7:00 p.m. Agenda: To review and evaluate...: Member Conflicts: Cocaine, Alcohol and Reward. Date: January 23-24, 2013. Time: 8:00 a.m. to 5:00 p.m...
NASA Astrophysics Data System (ADS)
Hu, Yu; Chen, Linying; Feng, Dong; Liang, Qianyong; Xia, Zhen; Chen, Duofu
2017-05-01
Sediments at marine methane seep sites provide potential archives of past fluid flow that serve to explore seepage activities over time. Three gravity cores (D-8, D-F, and D-7) were collected from seep sites on the northern slope of the South China Sea where gas hydrates were drilled in the subsurface. Various carbon and sulfur contents, δ13C values of total inorganic carbon (δ13CTIC), δ34S values of chromium reducible sulfur (δ34SCRS), trace element contents, grain size, and AMS 14C dating of planktonic Foraminifera in the sediments were determined to explore the availability of related proxies at seeps and to trace past methane seepage activities. Evidence for the presence of methane seepage and consequently anaerobic oxidation of methane comes from the occurrence of 13C-depleted authigenic carbonate nodules (δ13C values as low as -49‰) discovered at an interval of 150-200 cm in core D-7. This finding is supported by high S/C ratios and molybdenum enrichment in the same interval. However, low contents of CRS and negative δ34SCRS values are present. It is suggested to reflect a transient methane seepage event, which continued for about 1 ka based on the 14C ages. Cores D-8 and D-F have δ13CTIC values close to zero, low S/C ratios and CRS contents, negative δ34SCRS values, and no trace element enrichment, suggesting a negligible impact of methane-seepage on the sediments. The negative δ34SCRS values of the studied seep-impacted and background sediments suggest that the application of δ34SCRS alone as a proxy to identify AOM-related process may be insufficient. Sediment carbon-sulfur-trace element systematics and 14C ages used here have the potential to be a promising tool to recognize transient methane seepages and constrain their timescales.
Optimization of a ΔE - E detector for 41Ca AMS
NASA Astrophysics Data System (ADS)
Hosoya, Seiji; Sasa, Kimikazu; Matsunaka, Tetsuya; Takahashi, Tsutomu; Matsumura, Masumi; Matsumura, Hiroshi; Sundquist, Mark; Stodola, Mark; Sueki, Keisuke
2017-09-01
A series of nuclides (14C, 26Al, and 36Cl) was measured using the 12UD Pelletron tandem accelerator before replacement by the horizontal 6 MV tandem accelerator at the University of Tsukuba Tandem Accelerator Complex (UTTAC). This paper considers the modification of the accelerator mass spectrometry (AMS) measurement parameters to suit the current 6 MV tandem accelerator setup (e.g., terminal voltage, detected ion charge state, gas pressure, and entrance window material in detector). The Particle and Heavy Ion Transport code System (PHITS) was also used to simulate AMS measurement to determine the best conditions to suppress isobaric interference. The spectra of 41Ca and 41K were then successfully separated and their nuclear spectra were identified; the system achieved a background level of 41Ca/40Ca ∼ 6 ×10-14 .
DOE Office of Scientific and Technical Information (OSTI.GOV)
Madeen, Erin P.; Ognibene, Ted J.; Corley, Richard A.
Metabolism is a key health risk factor following exposures to pro-carcinogenic polycyclic aromatic hydrocarbons (PAHs) such as dibenzo[def,p]chrysene (DBC), an IARC classified 2A probable human carcinogen. Human exposure to PAHs occurs primarily from the diet in non-smokers. However, little data is available on the metabolism and pharmacokinetics in humans of high molecular weight PAHs (≥4 aromatic rings), including DBC. We previously determined the pharmacokinetics of DBC in human volunteers orally administered a micro-dose (29 ng; 5 nCi) of [14C]-DBC by accelerator mass spectrometry (AMS) analysis of total [14C] in plasma and urine. In the current study, we utilized a novelmore » “moving wire” interface between ultra-performance liquid chromatography (UPLC) and AMS to detect and quantify parent DBC and its major metabolites. The major [14C] product identified in plasma was unmetabolized [14C]-DBC itself, (Cmax= 18.5 ± 15.9 fg/mL, Tmax= 2.1 ± 1.0 h), whereas the major metabolite was identified as [14C]-(+/-)-DBC-11,12-diol (Cmax= 2.5 ± 1.3 fg/mL, Tmax= 1.8 h). Several minor species of [14C]-DBC metabolites were also detected for which no reference standards were available. Free and conjugated metabolites were detected in urine with [14C]-(+/-)-DBC-11,12,13,14-tetraol isomers identified as the major metabolites, 56.3% of which were conjugated (Cmax= 35.8 ± 23.0 pg/pool, Tmax= 6-12 h pool). [14C]-DBC-11,12-diol, of which 97.5% was conjugated, was also identified in urine (Cmax= 29.4 ± 11.6 pg/pool, Tmax= 6-12 h pool). Parent [14C]-DBC was not detected in urine. This is the first dataset to assess metabolite profiles and associated pharmacokinetics of a carcinogenic PAH in human volunteers at an environmentally relevant dose, providing the data necessary for translation of high dose animal models to humans for translation of environmental health risk assessment.« less
78 FR 12769 - Center for Scientific Review; Notice of Closed Meetings
Federal Register 2010, 2011, 2012, 2013, 2014
2013-02-25
... Pathogenesis Study Section. Date: March 18, 2013. Time: 8:00 a.m. to 5:00 p.m. Agenda: To review and evaluate... Young Adulthood. Date: March 18, 2013. Time: 3:00 p.m. to 4:00 p.m. Agenda: To review and evaluate grant... Panel; RFA Panel: CounterACT U54 Centers of Excellence. Date: March 19, 2013. Time: 8:00 a.m. to 12:00 p...
Marine radiocarbon reservoir age simulations for the past 50,000 years
NASA Astrophysics Data System (ADS)
Butzin, M.; Köhler, P.; Lohmann, G.
2017-08-01
Radiocarbon (14C) dating calibration for the last glacial period largely relies on cross-dated marine 14C records. However, marine reservoirs are isotopically depleted with respect to the atmosphere and therefore have to be corrected by the Marine Radiocarbon Ages of surface waters (MRAs), whose temporal variabilities are largely unknown. Here we present simulations of the spatial and temporal variability in MRAs using a three-dimensional ocean circulation model covering the past 50,000 years. Our simulations are compared to reconstructions of past surface ocean Δ14C. Running the model with different climatic boundary conditions, we find that low-latitude to midlatitude MRAs have varied between 400 and 1200 14C years, with values of about 780 14C years at the Last Glacial Maximum. Reservoir ages exceeding 2000 14C years are simulated in the polar oceans. Our simulation results can be used as first-order approximation of the MRA variability in future radiocarbon calibration efforts.
NASA Astrophysics Data System (ADS)
Onken, Jill; Forman, Steven
2017-01-01
Zuni Salt Lake (ZSL) is a large maar in the Red Hill-Quemado volcanic field located in west-central New Mexico in the southwestern USA. Stratigraphic analysis of sections in and around the maar, coupled with optically stimulated luminescence (OSL) and accelerator mass spectrometry (AMS) 14C dating, indicate that ZSL volcanic activity occurred between ˜13.4 and 9.9 ka and was most likely confined to a ≤500-year interval sometime between ˜12.3 and 11.0 ka. The basal volcanic unit consists of locally widespread basaltic ash fallout interpreted to represent a violent or wind-aided strombolian eruption tentatively attributed to Cerro Pomo, a scoria cone ˜10 km south of ZSL. Subsequent eruptions emanated from vents near or within the present-day ZSL maar crater. Strombolian eruptions of multiple spatter and scoria cones produced basaltic lava and scoria lapilli fallout. Next, a phreatomagmatic eruption created the maar crater and surrounding tephra rim and apron. ZSL eruptions ended with strombolian eruptions that formed three scoria cones on the crater floor. The revised age range of ZSL is younger and more precise than the 190-24 ka 2-sigma age range derived from previous argon dating. This implies that other morphologically youthful, argon-dated volcanoes on the southern margin of the Colorado Plateau might be substantially younger than previously reported.
de Oliveira Junior, Jairo Calderari; Beirigo, Raphael Moreira; Chiapini, Mariane; do Nascimento, Alexandre Ferreira; Couto, Eduardo Guimarães; Vidal-Torrado, Pablo
2017-01-01
Vegetated mounds are an important geomorphological feature of the Pantanal, where the influence of floods dictates not only hydropedological processes, but also the distribution and ecology of the flora and fauna. This work aimed to identify factors and processes that influence the formation and spatial distribution of the mounds, which are commonly associated with termite activity. In order to characterize pedological processes, macro and micro morphological descriptions, satellite image interpretation, dating of the sandy sedimentary material using OSL and carbon dating using 14C AMS were carried out. This dating of the materials indicates that the sediments in which the soils were formed were deposited during the Pleistocene, while the carbonates are from the Holocene. The basin-like format of the laminar structures suggests that part of the more clayey material was deposited in lacustrine environments. The more humid climate in the Holocene intensified argilluviation, which at an advanced stage, led to a more pronounced textural gradient, reducing drainage and leading to ferrolysis and thickening of the E horizon. Besides pedogenic processes, more erosive flooding during the Holocene began reducing and rounding the landscape's more elevated structures (paleolevees). In the final stage, these structures were occupied by termites to shelter from flooding. Thereafter, the bio-cementation action of the termite nests has increased the resistance of the vegetated mounds to processes of erosion.
de Oliveira Junior, Jairo Calderari; Beirigo, Raphael Moreira; Chiapini, Mariane; do Nascimento, Alexandre Ferreira; Couto, Eduardo Guimarães
2017-01-01
Vegetated mounds are an important geomorphological feature of the Pantanal, where the influence of floods dictates not only hydropedological processes, but also the distribution and ecology of the flora and fauna. This work aimed to identify factors and processes that influence the formation and spatial distribution of the mounds, which are commonly associated with termite activity. In order to characterize pedological processes, macro and micro morphological descriptions, satellite image interpretation, dating of the sandy sedimentary material using OSL and carbon dating using 14C AMS were carried out. This dating of the materials indicates that the sediments in which the soils were formed were deposited during the Pleistocene, while the carbonates are from the Holocene. The basin-like format of the laminar structures suggests that part of the more clayey material was deposited in lacustrine environments. The more humid climate in the Holocene intensified argilluviation, which at an advanced stage, led to a more pronounced textural gradient, reducing drainage and leading to ferrolysis and thickening of the E horizon. Besides pedogenic processes, more erosive flooding during the Holocene began reducing and rounding the landscape’s more elevated structures (paleolevees). In the final stage, these structures were occupied by termites to shelter from flooding. Thereafter, the bio-cementation action of the termite nests has increased the resistance of the vegetated mounds to processes of erosion. PMID:28700595
NASA Astrophysics Data System (ADS)
Ott, Florian; Brauer, Achim; Słowiński, Michał; Wulf, Sabine; Putyrskaya, Victoria; Plessen, Birgit; Błaszkiewicz, Miroslaw
2015-04-01
Detailed micro-facies and geochemical analyses have been carried out for the predominantly varved Holocene sediment record of Lake Czechowskie (north-central Poland). The chronology has been established by a multiple dating approach comprising varve counting, AMS 14C dating, 137Cs activity concentration measurements and tephrochronology. The combination of independent dating techniques revealed well-constrained time scales even in phases lacking annual laminations and allows reliable high-resolution archive synchronization. Quantitative (varve thickness variations) and qualitative (sublayer structure) varve parameters as well as geochemical composition have been obtained to gain a comprehensive view of climatic and environmental evolution during the last 11500 years in northern Poland. Five major sedimentological changes have been identified, encompassing transitions from varved to non-varved sediments (and vice versa) at 10.100 and 7.300 cal a BP, respectively, changes in general varve pattern at 6.500 and 4.200 cal a BP and distinct increase of varve thickness accompanied by increased annual variability since 2.800 cal a BP. These changes reflect large-scale reorganization of the climate system throughout the Holocene with increasing influences of the North Atlantic climate system in Poland. Moreover, the observed changes suggest different thresholds and trigger mechanisms over the investigated time period. This study is a contribution to the Virtual Institute of Integrated Climate and Landscape Evolution Analyses - ICLEA - of the Helmholtz Association, grant number VH-VI-415.
78 FR 52513 - Sunshine Act Meeting; Cancellation
Federal Register 2010, 2011, 2012, 2013, 2014
2013-08-23
..., August 21, 2013, page 51713. ANNOUNCED TIME AND DATE OF MEETING: Wednesday, August 21, 2013, 10 a.m.-11 a.m. MEETING CANCELED. For a recorded message containing the latest agenda information, call (301) 504... West Highway, Bethesda, MD 20814 (301) 504- 7923. Dated: August 21, 2013. Todd A. Stevenson, Secretary...
Black soils and/or sediments at the western border of the Nördlinger Ries (South Germany)
NASA Astrophysics Data System (ADS)
Mailänder, S.; Eberle, J.; Blümel, W. D.
2009-04-01
In the framework of a geoarchaeological research project by the Institute of Geography, University of Stuttgart, in the year 2006 the construction of a kerosene pipeline trench was monitored at the western border of the impact crater "Nördlinger Ries" in South Germany (MAILÄNDER ET AL. 2008). Thereby black horizons were recognized at several places. They occured predominantly in depressions and were covered by holocene colluvial sediments, but rested on different bedrocks which include mud- and sandstones as well as lime. The most of these horizons seemed to be rich in humic material and clay. By means of various studies, which involve sedimentological, pedological, archaeobotanical and -zoological analysis as well as 14C-(AMS)-datings, the periods and circumstances of the development of these black horizons are explored. The poster presents the itemised research methods and their first results. Particularly micromorphological analysis and mollusc classifications turned out to be very valuable to reconstruct the palaeoenvironmental conditions during their formation and subsequent modifications. First datings of bulk samples and charcoal pieces refer to the Atlantic period, but the measured ages distribute to a long time space from about cal BC 5200 to cal BC 4000. The outcomes of this investigation should facilitate a comparison with similar horizons which are recovered in several Central European sediment profiles, for example in the Amöneburger Becken near Marburg in Hessen (RITTWEGER 2000). Also their composition will be contrasted with samples from archaeological findings in the surrounding and the possibility of an anthropogenic influence on their development will be checked. References MAILÄNDER, S., W. D. BLÜMEL & J. EBERLE (2008): Paläoumweltbedingungen und anthropogene Landoberflächenveränderungen im Umfeld des frühkeltischen Fürstensitzes auf dem Ipf am Westrand des Nördlinger Rieses: Erste Geländebefunde und Auswertungen 2005/2006.- In: KRAUSSE, D. L. (Ed.) (2008): Frühe Zentralisierungs- und Urbanisierungsprozesse. Zur Genese und Entwicklung frühkeltischer Fürstensitze und ihres territorialen Umlandes. Kolloquium des DFG-Schwerpunktprogramms 1171 (Blaubeuren, 9.-11. Oktober 2006).- Forschungen und Berichte zur Vor- und Frühgeschichte in Baden-Württemberg 101.- Stuttgart: 281-298. RITTWEGER, H. (2000): The "Black Floodplain Soil" in the Amöneburger Becken, Germany: a lower Holocene marker horizon and indicator of an upper Atlantic to Subboreal dry period in Central Europe?.- Catena 41: 143-164.
NASA Astrophysics Data System (ADS)
Reynard, Linda M.; Meltzer, David J.; Emslie, Steven D.; Tuross, Noreen
2015-03-01
High elevation plant and animal communities are considered extremely sensitive to environmental change. We investigated an exceptional fossil record of yellow-bellied marmot (Marmota flaviventris) specimens that was recovered from Cement Creek Cave (elev. 2860 m) and ranged in age from radiocarbon background circa 49.8 cal ka BP to ~ 1 cal ka BP. We coupled isotopic and radiocarbon measurements (δ18O, δD, δ15N, δ13C, and 14C) of bone collagen from individually-AMS dated specimens of marmots to assess ecological responses by this species to environmental change over time in a high elevation basin in the Rocky Mountains of southwestern Colorado, USA. We find little change in all four isotope ratios over time, demonstrating considerable environmental stability during periods when the marmots were present. The stable ecology and the apparent persistence of the small mammal community in the cave fauna throughout the late Quaternary are in marked contrast to the changes that occurred in the large mammal community, including local extirpation and extinction, at the end of the Pleistocene.
Lång, K.; Eriksson Stenström, K.; Rosso, A.; Bech, M.; Zackrisson, S.; Graubau, D.; Mattsson, S.
2016-01-01
The purpose of this study was to perform an initial investigation of the possibility to determine breast cancer growth rate with 14C bomb-pulse dating. Tissues from 11 breast cancers, diagnosed in 1983, were retrieved from a regional biobank. The estimated average age of the majority of the samples overlapped the year of collection (1983) within 3σ. Thus, this first study of tumour tissue has not yet demonstrated that 14C bomb-pulse dating can obtain information on the growth of breast cancer. However, with further refinement, involving extraction of cell types and components, there is a possibility that fundamental knowledge of tumour biology might still be gained by the bomb-pulse technique. Additionally, δ 13C and δ 15N analyses were performed to obtain dietary and metabolic information, and to serve as a base for improvement of the age determination. PMID:27179119
Testing Younger Dryas ET Impact (YDB) Evidence at Hall’s Cave, Texas
NASA Astrophysics Data System (ADS)
Stafford, T. W.; Lundelius, E.; Kennett, J.; Kennett, D. J.; West, A.; Wolbach, W. S.
2009-12-01
Hall’s Cave, Kerrville County Texas, 167 km WSW of Austin, provides a unique opportunity for testing the presence of a chronostratigraphic datum (YDB layer) containing rare and exotic proxies, including nanodiamonds, aciniform soot, and magnetic spherules, the origins of which remain controversial, but possibly derive from a cosmic impact ~12,900 CAL BP. The karst-collapse cave in Cretaceous limestone on the Edwards Plateau contains ≥ 3.7 m of stratified clays grading to clayey silts recording continuous deposition from 16 ka RC yr to present. The cave’s small catchment area and mode of deposition were constant, and the stratigraphy is well dated based on 162 AMS 14C dates from individual vertebrate fossils, snails, charcoal, and sediment chemical fractions. The cave sequence contains an abundant small animal vertebrate fossil record, exhibiting biostratigraphic changes, and the timing of the late Pleistocene megafaunal extinction is consistent with that elsewhere in North America. At 151 cm below datum is the extremely sharp, smooth contact separating lower, dusky red (2.5YR3/2) clays below from overlying dark reddish brown (5YR3/3) clays (forming a 20-cm-thick dark layer) and dating to 13,000 CAL BP, at or close to the age of the YDB datum elsewhere. This appears to be the most distinctive lithologic change of the deglacial sequence. Sediments at or within 10 cm of this contact contain the local extinction of 4 species of bats, the local extinction of the prairie dog (Cynomys sp.) and perhaps other burrowing mammals in response to decrease in soil thickness, and the uppermost occurrence of 6 late Pleistocene megafaunal taxa that, although rare in the cave, do not extend younger than 12.9 ka. We collected and analyzed sediments at high resolution above and below the distinct lithologic contact at 151 cm. The red clays from 151 to 153 cm and immediately preceding the lithologic contact contain an abundance of nanodiamonds (5 different allotropes), aciniform soot at 2400 ppm, magnetic spherules, and carbon spherules, all of which we interpret as evidence for a unique chronostratigraphic marker (YDB) in the Western Hemisphere. Because the age of this horizon is ~ 13,000 CAL BP, we interpret the age of the event as the beginning of the Younger Dryas cooling. Regional soil erosion began ~15,000 CAL BP and continued until 7000 CAL BP, but dating suggests that there is no discontinuity or hiatus in deposition, and thus, the exotic materials in that layer are not considered to be erosional accumulations. Future analyses include sub-centimeter sampling over the YD boundary, quantification of nanodiamonds and other event-proxies within 1000 yr of the boundary and in sediments several 1000 years older and younger, continued refinement of the AMS 14C record to determine within 50 yr the location of 12,900 CAL BP datum and high resolution analysis of small animal biostratigraphy.
A Millennial-Scale Sea Surface Temperature Record From the North Atlantic Based on Diatoms
NASA Astrophysics Data System (ADS)
Miettinen, A.; Koc, N.
2008-12-01
Sea surfaces temperatures (SSTs) are generated from a 1000-year-long sediment core from the eastern flank of Reykjanes Ridge in the subpolar North Atlantic with a time resolution of 2-10 years. 54.3 cm long box core (Rapid 21-12B) and 370 cm long gravity core (RAPID 21-3K) were recovered from deep-sea sediments (2630 m water depth) during the RRS Charles Darwin cruise 159 in 2004. The box core is dated using the 210Pb method and it is continuously subsampled and investigated at 0.5 cm intervals for the last 230 years with a two years average time resolution. The gravity core is dated 14C AMS method and it is investigated continuously at 1.0 cm intervals with a ten years average resolution for the interval representing 230-1000 cal. years BP. August SSTs are reconstructed using marine planktonic diatom species with the Weighted Averages - Partial Least Squares (WA-PLS) method. Results achieved from the box core indicate August SST warming of c. 1 °C from 1773 AD to the present. The interval 1773-1830 represents the cold period at the investigated site. It is followed by warm period between 1830 and 1885. After this the temperature frequency is more stable with short cool events around 1890 and 1930. The last 60 years represent the warm period with a slow warming trend, especially during the past 25 years. However, results do not indicate distinct SST warming since 1870s. The most high-frequency SST variability with amplitude of c. 1 °C appears after 1970 indicating several very warm years, but also coldest years since 1820s.
Intensity-Dependence Absorption and Photorefractive Effects in Barium Titanate
1988-09-01
S) barium titanate (U) George A. Brost , Ra and A. Motes, James R. Rotge’ 13& TYPE OF REPORT 13b. TIME COVERED 14. DATE OF REPORT (Yr.. Mo.. Day) 15...the copyright owner. Inthnsity-dependent absorption and photorefractive effects in barium titanate0 ELECTE 0 G. A. Brost , R. A. Motes, and 1. R. Rotge...Opt. Soc. Am. B/Vol. 5, No. 9/September 1988 Brost et al. CONDUCTION BAND the relative contributions of photoconductivities and dark conductivities
Gao, Wen-Hui; Liu, Bo; Li, Xing-Feng; Han, Jun-Hua; Jia, Ying-Min
2014-03-01
To prepare myclobutanil molecularly imprinted polymer, a method was established for the choice of the appropriate functional monomer and its dosage. UV spectra was applied to study the combination form, the effect intensity, the optimal concentration ratio and the numbers of binding sites between myclobutanil and methyl acrylic acid (MAA) or acrylamide (AM) functional monomer. The results showed that hydrogen-bonding interaction could be formed between myclobutanil and methyl acrylic acid (MAA) or acrylamide (AM) functional monomer. The pi electron of the triazole ring conjugated double bond in my clobutanil could transit to pi* conjugate antibonding orbital when it absorbed energy. The formation of hydrogen bond could make pi-->pi* absorption band transit. Maximum absorption wavelength produced red shift with the increase in the functional monomer concentration in the system. The research revealed that the optimal concentration ratios between myclobutanil and the two monomers were c(M):c(MAA) = 1:4, c(M):c(AM) = 1:2. Myclobutanil and the both the functional monomers had the bonding ability, and strong bonding force. The prepared molecularly imprinted polymer using AM as a functional monomer had better stability and specificity of recognition for myclobutanil.
Moyer, Bryan D; Murray, Justin K; Ligutti, Joseph; Andrews, Kristin; Favreau, Philippe; Jordan, John B; Lee, Josie H; Liu, Dong; Long, Jason; Sham, Kelvin; Shi, Licheng; Stöcklin, Reto; Wu, Bin; Yin, Ruoyuan; Yu, Violeta; Zou, Anruo; Biswas, Kaustav; Miranda, Les P
2018-01-01
Identification of voltage-gated sodium channel NaV1.7 inhibitors for chronic pain therapeutic development is an area of vigorous pursuit. In an effort to identify more potent leads compared to our previously reported GpTx-1 peptide series, electrophysiology screening of fractionated tarantula venom discovered the NaV1.7 inhibitory peptide JzTx-V from the Chinese earth tiger tarantula Chilobrachys jingzhao. The parent peptide displayed nominal selectivity over the skeletal muscle NaV1.4 channel. Attribute-based positional scan analoging identified a key Ile28Glu mutation that improved NaV1.4 selectivity over 100-fold, and further optimization yielded the potent and selective peptide leads AM-8145 and AM-0422. NMR analyses revealed that the Ile28Glu substitution changed peptide conformation, pointing to a structural rationale for the selectivity gains. AM-8145 and AM-0422 as well as GpTx-1 and HwTx-IV competed for ProTx-II binding in HEK293 cells expressing human NaV1.7, suggesting that these NaV1.7 inhibitory peptides interact with a similar binding site. AM-8145 potently blocked native tetrodotoxin-sensitive (TTX-S) channels in mouse dorsal root ganglia (DRG) neurons, exhibited 30- to 120-fold selectivity over other human TTX-S channels and exhibited over 1,000-fold selectivity over other human tetrodotoxin-resistant (TTX-R) channels. Leveraging NaV1.7-NaV1.5 chimeras containing various voltage-sensor and pore regions, AM-8145 mapped to the second voltage-sensor domain of NaV1.7. AM-0422, but not the inactive peptide analog AM-8374, dose-dependently blocked capsaicin-induced DRG neuron action potential firing using a multi-electrode array readout and mechanically-induced C-fiber spiking in a saphenous skin-nerve preparation. Collectively, AM-8145 and AM-0422 represent potent, new engineered NaV1.7 inhibitory peptides derived from the JzTx-V scaffold with improved NaV selectivity and biological activity in blocking action potential firing in both DRG neurons and C-fibers.
Murray, Justin K.; Ligutti, Joseph; Andrews, Kristin; Favreau, Philippe; Jordan, John B.; Lee, Josie H.; Liu, Dong; Long, Jason; Sham, Kelvin; Shi, Licheng; Stöcklin, Reto; Wu, Bin; Yin, Ruoyuan; Yu, Violeta; Zou, Anruo; Biswas, Kaustav; Miranda, Les P.
2018-01-01
Identification of voltage-gated sodium channel NaV1.7 inhibitors for chronic pain therapeutic development is an area of vigorous pursuit. In an effort to identify more potent leads compared to our previously reported GpTx-1 peptide series, electrophysiology screening of fractionated tarantula venom discovered the NaV1.7 inhibitory peptide JzTx-V from the Chinese earth tiger tarantula Chilobrachys jingzhao. The parent peptide displayed nominal selectivity over the skeletal muscle NaV1.4 channel. Attribute-based positional scan analoging identified a key Ile28Glu mutation that improved NaV1.4 selectivity over 100-fold, and further optimization yielded the potent and selective peptide leads AM-8145 and AM-0422. NMR analyses revealed that the Ile28Glu substitution changed peptide conformation, pointing to a structural rationale for the selectivity gains. AM-8145 and AM-0422 as well as GpTx-1 and HwTx-IV competed for ProTx-II binding in HEK293 cells expressing human NaV1.7, suggesting that these NaV1.7 inhibitory peptides interact with a similar binding site. AM-8145 potently blocked native tetrodotoxin-sensitive (TTX-S) channels in mouse dorsal root ganglia (DRG) neurons, exhibited 30- to 120-fold selectivity over other human TTX-S channels and exhibited over 1,000-fold selectivity over other human tetrodotoxin-resistant (TTX-R) channels. Leveraging NaV1.7-NaV1.5 chimeras containing various voltage-sensor and pore regions, AM-8145 mapped to the second voltage-sensor domain of NaV1.7. AM-0422, but not the inactive peptide analog AM-8374, dose-dependently blocked capsaicin-induced DRG neuron action potential firing using a multi-electrode array readout and mechanically-induced C-fiber spiking in a saphenous skin-nerve preparation. Collectively, AM-8145 and AM-0422 represent potent, new engineered NaV1.7 inhibitory peptides derived from the JzTx-V scaffold with improved NaV selectivity and biological activity in blocking action potential firing in both DRG neurons and C-fibers. PMID:29723257
Radiocarbon Dating, Memories, and Hopes
DOE R&D Accomplishments Database
Libby, W. F.
1972-10-01
The history of radiocarbon dating from 1939 to the present is reviewed. The basic principles of radiocarbon dating are that cosmic rays make living things radioactive with {sup 14}C to a certain level fixed by the environment and that at death the intake of food stops so no replenishment of the {sup 14}C steadily lost by the immutable decay occurs. Therefore measurement of the degree of decay gives the time lapse since death, i.e., the radiocarbon age. The equipment developed and experiments performed to measure the specific activity of specimens to be dated are described. The results obtained by world-wide experimenters are discussed. These showed that on simultaneity radiocarbon dating is apparently reliable but that absolute dates may be incorrect by as much as 600 to 700 y. The value of radiocarbon dating to archaeologists, geologists, climatologists, and historians is stressed. (LCL)
NASA Astrophysics Data System (ADS)
Baisden, W. T.; Canessa, S.
2013-01-01
In 1959, Athol Rafter began a substantial programme of systematically monitoring the flow of 14C produced by atmospheric thermonuclear tests through organic matter in New Zealand soils under stable land use. A database of ∼500 soil radiocarbon measurements spanning 50 years has now been compiled, and is used here to identify optimal approaches for soil C-cycle studies. Our results confirm the potential of 14C to determine residence times, by estimating the amount of ‘bomb 14C’ incorporated. High-resolution time series confirm this approach is appropriate, and emphasise that residence times can be calculated routinely with two or more time points as little as 10 years apart. This approach is generally robust to the key assumptions that can create large errors when single time-point 14C measurements are modelled. The three most critical assumptions relate to: (1) the distribution of turnover times, and particularly the proportion of old C (‘passive fraction’), (2) the lag time between photosynthesis and C entering the modelled pool, (3) changes in the rates of C input. When carrying out approaches using robust assumptions on time-series samples, multiple soil layers can be aggregated using a mixing equation. Where good archived samples are available, AMS measurements can develop useful understanding for calibrating models of the soil C cycle at regional to continental scales with sample numbers on the order of hundreds rather than thousands. Sample preparation laboratories and AMS facilities can play an important role in coordinating the efficient delivery of robust calculated residence times for soil carbon.
Madeen, Erin P.; Ognibene, Ted J.; Corley, Richard A.; McQuistan, Tammie J.; Baird, William M.; Bench, Graham; Turteltaub, Ken W.; Williams, David E.
2017-01-01
Metabolism is a key health risk factor for exposures to pro-carcinogenic polycyclic aromatic hydrocarbons (PAHs) such as dibenzo[def,p]chrysene (DBC), an IARC classified 2A probable human carcinogen. Human exposure to PAHs occurs primarily from the diet in non-smokers. However, little data is available on the metabolism and pharmacokinetics in humans of high molecular weight PAHs (≥4 aromatic rings), including DBC. We previously determined the pharmacokinetics of DBC in human volunteers orally administered a micro-dose (29 ng; 5 nCi) of [14C]-DBC by accelerator mass spectrometry (AMS) analysis of total [14C] in plasma and urine. In the current study, we utilized a novel “moving wire” interface between ultra-performance liquid chromatography (UPLC) and the AMS to detect and quantify parent DBC and its major metabolites. The major [14C] product identified in plasma was unmetabolized [14C]-DBC itself, (Cmax= 18.5 ± 15.9 fg/mL, Tmax= 2.1 ± 1.0 h), whereas the major metabolite was identified as [14C]-(+/−)-DBC-11,12-diol (Cmax= 2.5 ± 1.3 fg/mL, Tmax= 1.8 h). Several minor species of [14C]-DBC metabolites were also detected for which no reference standards were available. Deconjugated and conjugated metabolites were detected in urine with [14C]-(+/−)-DBC-tetraol identified as the major metabolite, 88.7% of which was detected upon enzymatic deconjugation (Cmax= 35.8 ± 23.0 pg/pool, Tmax= 6–12 h pool). [14C]-DBC-11,12-diol, of which 94.4% was conjugated and identified in urine (Cmax= 29.4 ± 11.6 pg/pool, Tmax= 6–12 h pool). Parent [14C]-DBC was not detected in the urine. This is the first dataset to assess metabolite profiles and associated pharmacokinetics of a carcinogenic PAH in human volunteers at an environmentally relevant dose, providing the data necessary for translation of high dose laboratory animal models to human translation for environmental health risk assessment. PMID:27494294
A reassessment of the presumed Neandertal remains from San Bernardino Cave, Italy.
Benazzi, Stefano; Peresani, Marco; Talamo, Sahra; Fu, Qiaomei; Mannino, Marcello A; Richards, Michael P; Hublin, Jean-Jacques
2014-01-01
In 1986-1987, three human remains were unearthed from macro-unit II of San Bernardino Cave (Berici Hills, Veneto, Italy), a deposit containing a late Mousterian lithic assemblage. The human remains (a distal phalanx, a lower right third molar and a lower right second deciduous incisor) do not show diagnostic morphological features that could be used to determine whether they were from Homo neanderthalensis or Homo sapiens. Despite being of small size, and thus more similar to recent H. sapiens, the specimens were attributed to Neandertals, primarily because they were found in Mousterian layers. We carried out a taxonomic reassessment of the lower right third molar (LRM3; San Bernardino 4) using digital morphometric analysis of the root, ancient DNA analysis, carbon and nitrogen isotope analyses, and direct accelerator mass spectrometry (AMS) radiocarbon dating of dentine collagen. Mitochondrial DNA analysis and root morphology show that the molar belongs to a modern human and not to a Neandertal. Carbon 14 ((14)C) dating of the molar attributes it to the end of the Middle Ages (1420-1480 cal AD, 2 sigma). Carbon and nitrogen isotope analyses suggest that the individual in question had a diet similar to that of Medieval Italians. These results show that the molar, as well as the other two human remains, belong to recent H. sapiens and were introduced in the Mousterian levels post-depositionally. Copyright © 2013 Elsevier Ltd. All rights reserved.
Radiocarbon dating late Quaternary loess deposits using small terrestrial gastropod shells
Pigati, Jeff S.; McGeehin, John P.; Muhs, Daniel R.; Bettis, E. Arthur
2013-01-01
Constraining the ages and mass accumulation rates of late Quaternary loess deposits is often difficult because of the paucity of organic material typically available for 14C dating and the inherent limitations of luminescence techniques. Radiocarbon dating of small terrestrial gastropod shells may provide an alternative to these methods as fossil shells are common in loess and contain ∼12% carbon by weight. Terrestrial gastropod assemblages in loess have been used extensively to reconstruct past environmental conditions but have been largely ignored for dating purposes. Here, we present the results of a multi-faceted approach to understanding the potential for using small terrestrial gastropod shells to date loess deposits in North America. First, we compare highly resolved 14C ages of well-preserved wood and gastropod shells (Succineidae) recovered from a Holocene loess section in Alaska. Radiocarbon ages derived from the shells are nearly identical to wood and plant macrofossil ages throughout the section, which suggests that the shells behaved as closed systems with respect to carbon for at least the last 10 ka (thousands of calibrated 14C years before present). Second, we apply 14C dating of gastropod shells to late Pleistocene loess deposits in the Great Plains using stratigraphy and independent chronologies for comparison. The new shell ages require less interpretation than humic acid radiocarbon ages that are commonly used in loess studies, provide additional stratigraphic coverage to previous dating efforts, and are in correct stratigraphic order more often than their luminescence counterparts. Third, we show that Succineidae shells recovered from historic loess in the Matanuska River Valley, Alaska captured the 20th century 14C bomb spike, which suggests that the shells can be used to date late Holocene and historic-aged loess. Finally, results from Nebraska and western Iowa suggest that, similar to other materials, shell ages approaching ∼40 ka should be viewed with caution as they may reflect trace amounts of contamination. In sum, our results show that small terrestrial gastropod shells, especially from the Succineidae family, provide reliable ages for late Quaternary loess deposits in North America.
Clinical Investigation Program Report.
1981-10-01
Accumulative Periodic Review C t -None ........ C -- 5" -- - s :-T Study Objective: Gastroesophageal reflux disease (GERD) refers to a clinT-aTWdF-sv i66...13 The Use of Metoclopramide to Facilitate Emergent Upper Intestinal Endoscopy. (0) 1980 G-80-14 Daytime Gastroesophageal Reflux : Characterization and...G-80-14 Status: Terminated Title: Daytime Gastroesophageal Reflux : Characterization and Specific Th erapy. Start Date: 10 Jun 80 Est Comp Date
Simulation of Extreme Arctic Cyclones in IPCC AR5 Experiments
2012-09-30
of the present-day Arctic atmosphere in CCSM4. J. Climate, 2676-2695. Overeem, I ., R . S. Anderson, C. W. Wobus, G. D. Clow, F. E. Urban, and N...intensity of extreme Arctic cyclones? APPROACH I am targeting these objectives through a retrospective analysis of the transient 20th century...simulations (spanning years 1850-2005) among the GCMs participating in the latest Coupled Model Intercomparison Project (CMIP5). I am including 14
77 FR 65581 - Labor Advisory Committee for Trade Negotiations and Trade Policy
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2012-10-29
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77 FR 59200 - National Heart, Lung, and Blood Institute; Notice of Meeting
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2012-09-26
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75 FR 56552 - National Heart, Lung, and Blood Institute; Notice of Meeting
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2010-09-16
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2013-01-08
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2012-05-29
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2013-05-20
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76 FR 7224 - Office of the Director, National Institutes of Health; Notice of Meeting
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2011-02-09
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78 FR 11897 - Office of the Director, National Institutes of Health; Notice of Meeting
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2013-02-20
... Committee Act, as amended (5 U.S.C. App.), notice is hereby given of a meeting of the Recombinant DNA... Committee: Recombinant DNA Advisory Committee. Date: March 12, 2013. Time: 8:30 a.m. to 3:30 p.m. Agenda: The NIH Recombinant DNA Advisory Committee (RAC) will review and discuss selected human gene transfer...
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2010-05-19
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2010-03-24
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78 FR 76177 - Meeting of the Judicial Conference Committee on Rules of Practice and Procedure
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2013-12-16
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78 FR 19274 - Center for Scientific Review; Notice of Closed Meetings
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2013-03-29
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2013-07-29
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2010-08-04
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2012-06-29
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2011-10-06
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Concordant 241Pu-241Am Dating of Environmental Samples: Results from Forest Fire Ash
NASA Astrophysics Data System (ADS)
Goldstein, S. J.; Oldham, W. J.; Murrell, M. T.; Katzman, D.
2010-12-01
We have measured the Pu, 237Np, 241Am, and 151Sm isotopic systematics for a set of forest fire ash samples from various locations in the western U.S. including Montana, Wyoming, Idaho, and New Mexico. The goal of this study is to develop a concordant 241Pu (t1/2 = 14.4 y)-241Am dating method for environmental collections. Environmental samples often contain mixtures of components including global fallout. There are a number of approaches for subtracting the global fallout component for such samples. One approach is to use 242Pu/239Pu as a normalizing isotope ratio in a three-isotope plot, where this ratio for the non-global fallout component can be estimated or assumed to be small. This study investigates a new, complementary method of normalization using the long-lived fission product, 151Sm (t1/2 = 90 y). We find that forest fire ash concentrates actinides and fission products with ~1E10 atoms 239Pu/g and ~1E8 atoms 151Sm/g, allowing us to measure these nuclides by mass spectrometric (MIC-TIMS) and radiometric (liquid scintillation counting) methods. The forest fire ash samples are characterized by a western U.S. regional isotopic signature representing varying mixtures of global fallout with a local component from atmospheric testing of nuclear weapons at the Nevada Test Site (NTS). Our results also show that 151Sm is well correlated with the Pu nuclides in the forest fire ash, suggesting that these nuclides have similar geochemical behavior in the environment. Results of this correlation indicate that the 151Sm/239Pu atom ratio for global fallout is ~0.164, in agreement with an independent estimate of 0.165 based on 137Cs fission yields for atmospheric weapons tests at the NTS. 241Pu-241Am dating of the non-global fallout component in the forest fire ash samples yield ages in the late 1950’s-early 1960’s, consistent with a peak in NTS weapons testing at that time. The age results for this component are in agreement using both 242Pu and 151Sm normalizations, although the errors for the 151Sm correction are currently larger due to the greater uncertainty of their measurements. Additional efforts to develop a concordant 241Pu-241Am dating method for environmental collections are underway with emphasis on soil cores.
Boudin, Mathieu; Boeckx, Pascal; Vandenabeele, Peter; Van Strydonck, Mark
2013-09-30
Radiocarbon dating and stable isotope analyses of bone collagen, wool, hair and silk contaminated with extraneous carbon (e.g. humic substances) does not yield reliable results if these materials are pre-treated using conventional methods. A cross-flow nanofiltration method was developed that can be applied to various protein materials like collagen, hair, silk, wool and leather, and should be able to remove low-molecular and high-molecular weight contaminants. To avoid extraneous carbon contamination via the filter a ceramic filter (molecular weight cut-off of 200 Da) was used. The amino acids, released by hot acid hydrolysis of the protein material, were collected in the permeate and contaminants in the retentate (>200 Da). (14)C-dating results for various contaminated archaeological samples were compared for bulk material (pre-treated with the conventional methods) and for cross-flow nanofiltrated amino acids (permeate) originating from the same samples. Contamination and quality control of (14)C dates of bulk and permeate samples were obtained by measuring C:N ratios, fluorescence spectra, and δ(13)C and δ(15)N values of the samples. Cross-flow nanofiltration decreases the C:N ratio which means that contaminants have been removed. Cross-flow nanofiltration clearly improved sample quality and (14)C results. It is a quick and non-labor-intensive technique and can easily be implemented in any (14)C and stable isotope laboratory for routine sample pre-treatment analyses. Copyright © 2013 John Wiley & Sons, Ltd.
76 FR 19104 - Center for Scientific Review; Notice of Closed Meetings
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2011-04-06
... Behavioral and Social Sciences. Date: May 16, 2011. Time: 8 a.m. to 5 p.m. Agenda: To review and evaluate... of Committee: Surgical Sciences, Biomedical Imaging and Bioengineering Integrated Review Group; Bioengineering, Technology and Surgical Sciences Study Section. Date: May 16-17, 2011. Time:8 a.m. to 5 p.m...
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2011-03-10
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76 FR 50486 - Center for Scientific Review Notice of Closed Meetings
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2011-08-15
... Review. Date: September 15-16, 2011. Time: 9 a.m. to 5 p.m. Agenda: To review and evaluate grant...; Clinical Neuroplasticity and Neurotransmitters Study Section. Date: September 19-20, 2011. Time: 8 a.m. to 5 p.m. Agenda: To review and evaluate grant applications. Place: The Westin Seattle, 1900 Fifth...
76 FR 54778 - Center For Scientific Review; Notice of Closed Meetings
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2011-09-02
..., Musculoskeletal Tissue Engineering Study Section. Date: September 29-30, 2011. Time: 8 a.m. to 5 p.m. Agenda: [email protected] . Name of Committee: Brain Disorders and Clinical Neuroscience Integrated Review Group, Clinical Neuroscience and Neurodegeneration Study Section. Date: October 5-6, 2011. Time: 8 a.m. to 5 p.m...