Science.gov

Sample records for analysis petroleum processes

  1. Petroleum Processing Wastes.

    ERIC Educational Resources Information Center

    Baker, D. A.

    1978-01-01

    Presents a literature review of the petroleum processing wastes, covering publications of 1977. This review covers studies such as the use of activated carbon in petroleum and petrochemical waste treatment. A list of 15 references is also presented. (HM)

  2. Fractionation process for petroleum wax

    SciTech Connect

    Jones, R.L.; Mitchael, M.R.; Krenowicz, R.A.; Southard, W.M.

    1991-07-16

    This patent describes a process which comprises separating a petroleum wax into a lower boiling wax fraction of a narrow melting range and a higher boiling wax fraction of wider melting range by subjecting the petroleum wax to distillation in a wiped film evaporator.

  3. Practical Advances in Petroleum Processing

    NASA Astrophysics Data System (ADS)

    Hsu, Chang S.; Robinson, Paul R.

    "This comprehensive book by Robinson and Hsu will certainly become the standard text book for the oil refining business...[A] must read for all who are associated with oil refining." - Dr. Walter Fritsch, Senior Vice President Refining, OMV "This book covers a very advanced horizon of petroleum processing technology. For all refiners facing regional and global environmental concerns, and for those who seek a more sophisticated understanding of the refining of petroleum resources, this book has been long in coming." - Mr. Naomasa Kondo, Cosmo Oil Company, Ltd.

  4. Process and apparatus for desalting crude petroleum

    SciTech Connect

    Baumann, C.; Bourgeois, C.; Richmond, J.; Scherrer, C.; Siffert, B.; Wiegandt, H.

    1980-04-29

    A process for desalting crude petroleum comprises breaking down a stable emulsion of water and crude petroleum when formed in a desalter, by injecting a demulsifying agent, such as di-2-ethyl hexyl sulphosuccinate, into the desalter at a predetermined level, when the sample taken at this level contain a predetermined content of stable emulsion. An apparatus for carrying out this process continuously is also included.

  5. Process for producing a petroleum wax composition

    SciTech Connect

    Jones, R.L.

    1991-04-23

    This patent describes a process for producing a wax composition. It comprises: vacuum distilling a petroleum feed to prepare a 650 distillate heavy intermediate petroleum wax, having a melting point range of from about 155{degrees}F. to about 185{degrees}F., subjecting the heavy intermediate petroleum wax to furfural/duosol solvent extraction, dissolving and crystallizing the heavy intermediate petroleum wax from a methyl ethyl ketone/toluene mixed solvent, dissolving and recrystallizing the heavy intermediate petroleum wax from a methyl ethyl ketone/toluene mixed solvent, percolating the recrystallized heavy intermediate petroleum wax in the molten state through a clay bed; and blending the recrystallized heavy intermediate petroleum wax from about 50 weight percent to about 90 weight percent with from about 10 weight percent to about 30 weight percent of a polymeric compound selected from the group consisting of ethylene-vinyl acetate copolymer, ethylene-ethyl acrylate copolymer, polypropylene and mixtures there of and having a molecular weight of from about 2,000 to about 100,000 and a melt index of from about 1 to about 250{degrees} at 375{degrees}F.

  6. Process for desulfurizing petroleum feedstocks

    DOEpatents

    Gordon, John Howard; Alvare, Javier

    2014-06-10

    A process for upgrading an oil feedstock includes reacting the oil feedstock with a quantity of an alkali metal, wherein the reaction produces solid materials and liquid materials. The solid materials are separated from the liquid materials. The solid materials may be washed and heat treated by heating the materials to a temperature above 400.degree. C. The heat treating occurs in an atmosphere that has low oxygen and water content. Once heat treated, the solid materials are added to a solution comprising a polar solvent, where sulfide, hydrogen sulfide or polysulfide anions dissolve. The solution comprising polar solvent is then added to an electrolytic cell, which during operation, produces alkali metal and sulfur.

  7. Process for magnetic beneficiating petroleum cracking catalyst

    DOEpatents

    Doctor, R.D.

    1993-10-05

    A process is described for beneficiating a particulate zeolite petroleum cracking catalyst having metal values in excess of 1000 ppm nickel equivalents. The particulate catalyst is passed through a magnetic field in the range of from about 2 Tesla to about 5 Tesla generated by a superconducting quadrupole open-gradient magnetic system for a time sufficient to effect separation of said catalyst into a plurality of zones having different nickel equivalent concentrations. A first zone has nickel equivalents of about 6,000 ppm and greater, a second zone has nickel equivalents in the range of from about 2000 ppm to about 6000 ppm, and a third zone has nickel equivalents of about 2000 ppm and less. The zones of catalyst are separated and the second zone material is recycled to a fluidized bed of zeolite petroleum cracking catalyst. The low nickel equivalent zone is treated while the high nickel equivalent zone is discarded. 1 figures.

  8. Process for magnetic beneficiating petroleum cracking catalyst

    DOEpatents

    Doctor, Richard D.

    1993-01-01

    A process for beneficiating a particulate zeolite petroleum cracking catalyst having metal values in excess of 1000 ppm nickel equivalents. The particulate catalyst is passed through a magnetic field in the range of from about 2 Tesla to about 5 Tesla generated by a superconducting quadrupole open-gradient magnetic system for a time sufficient to effect separation of said catalyst into a plurality of zones having different nickel equivalent concentrations. A first zone has nickel equivalents of about 6,000 ppm and greater, a second zone has nickel equivalents in the range of from about 2000 ppm to about 6000 ppm, and a third zone has nickel equivalents of about 2000 ppm and less. The zones of catalyst are separated and the second zone material is recycled to a fluidized bed of zeolite petroleum cracking catalyst. The low nickel equivalent zone is treated while the high nickel equivalent zone is discarded.

  9. SYSTEMS CHEMICAL ANALYSIS OF PETROLEUM POLLUTANTS

    EPA Science Inventory

    The application of an established mathematical treatment useful for the characterization and identification of petroleum pollutants is described. Using discriminant analysis of relevant infrared spectrophotometric data, 99% of numerous known and unknown oil samples have been corr...

  10. Recycled fatty acid crude petroleum recovery process

    SciTech Connect

    Herter, G. L.; Herter, C.

    1984-11-06

    A method of recovering crude oil for subsequent processing. The method contemplates the step of exposing the source of crude oil such as a subterranean petroleum reservoir or a vessel or container of tar sands, kerogen or the like to aliphatic or carboxylic acid, preferably oleic acid, to produce a solvated crude oil mixture of reduced viscosity. This mixture is saponifyed by reacting it with a nucleophilic base, preferably a hydroxide of potassium or sodium, under pressure whereby to separate the solvated mixture into petroleum crude and an acid soap which migrates to an aqueous phase. The petroleum crude is separated from the aqueous soap through conventional techniques. Afterwards, a desaponification step contemplates recovery of the aliphatic or carboxylic acid for subsequent recycling in the previously mentioned exposing step. Reuse is facilitated by desaponifying aqueous soap within a high pressure containment vessel reacted with an acid suitable for donating a hydrated proton to the aqueous phase of the soap. This reconstituted acid is recycled for injection into the inputting step. Preferably carbonic acid is generated for the desaponifying step by injecting high pressure carbon dioxide within the containment vessel. By-products of the chemical reaction are separated and/or filtered as necessary to effectuate necessary purification sub-steps.

  11. Importance of technical analysis of petroleum futures

    SciTech Connect

    Henderson, J.H.

    1995-06-01

    Recent structural changes of the global economy have resulted in {open_quotes}free market{close_quotes} forces determining the prices of petroleum products. In the early years of the petroleum age, market prices were unduly influenced by forces such as Standard Oil. The Texas Railroad Commission, {open_quotes}The Seven Sisters{close_quotes} and OPEC. Petroleum product prices set on the New York Mercantile and on the International Petroleum Exchange in London reflect the current supply/demand judgement of informed participants. In dollar terms, crude oil is the worlds most important commodity. Large capital pools such as hedge and pension funds seek risk diversification through purchases of derivatives such as the Goldman Sachs Commodity Index futures contract established in 1991. Global computerized trading made possible in part by advances in telecommunication technology can result in rapid market adjustments. Computer assisted mathematical analysis of price, volume, open interest, momentum, volatility, and premiums is useful to the working energy professional when planning upstream activities such as production purchases or drilling programs.

  12. Gas Hydrate Petroleum System Analysis

    NASA Astrophysics Data System (ADS)

    Collett, T. S.

    2012-12-01

    In a gas hydrate petroleum system, the individual factors that contribute to the formation of gas hydrate accumulations, such as (1) gas hydrate pressure-temperature stability conditions, (2) gas source, (3) gas migration, and (4) the growth of the gas hydrate in suitable host sediment can identified and quantified. The study of know and inferred gas hydrate accumulations reveal the occurrence of concentrated gas hydrate is mostly controlled by the presence of fractures and/or coarser grained sediments. Field studies have concluded that hydrate grows preferentially in coarse-grained sediments because lower capillary pressures in these sediments permit the migration of gas and nucleation of hydrate. Due to the relatively distal nature of the deep marine geologic settings, the overall abundance of sand within the shallow geologic section is usually low. However, drilling projects in the offshore of Japan, Korea, and in the Gulf of Mexico has revealed the occurrence of significant hydrate-bearing sand reservoirs. The 1999/2000 Japan Nankai Trough drilling confirmed occurrence of hydrate-bearing sand-rich intervals (interpreted as turbidite fan deposits). Gas hydrate was determined to fill the pore spaces in these deposits, reaching saturations up to 80% in some layers. A multi-well drilling program titled "METI Toaki-oki to Kumano-nada" also identified sand-rich reservoirs with pore-filling hydrate. The recovered hydrate-bearing sand layers were described as very-fine- to fine-grained turbidite sand layers measuring from several centimeters up to a meter thick. However, the gross thickness of the hydrate-bearing sand layers were up to 50 m. In 2010, the Republic of Korea conducted the Second Ulleung Basin Gas Hydrate (UBGH2) Drilling Expedition. Seismic data clearly showed the development of a thick, potential basin wide, sedimentary sections characterized by mostly debris flows. The downhole LWD logs and core data from Site UBGH2-5 reveal that each debris flows is

  13. Energy Bandwidth for Petroleum Refining Processes

    SciTech Connect

    none,

    2006-10-01

    The petroleum refining energy bandwidth report analyzes the most energy-intensive unit operations used in U.S. refineries: crude oil distillation, fluid catalytic cracking, catalytic hydrotreating, catalytic reforming, and alkylation. The "bandwidth" provides a snapshot of the energy losses that can potentially be recovered through best practices and technology R&D.

  14. ARTICLES: Laser spectrochromatographic analysis of petroleum components

    NASA Astrophysics Data System (ADS)

    Korobeĭnik, G. S.; Letokhov, V. S.; Montanari, S. G.; Tumanova, L. M.

    1985-01-01

    A system combining a gas chromatograph and a laser optoacoustic spectrometer (with a CO2 laser and means for fast frequency scanning) was used to investigate model hydrocarbon mixtures, as well as some real objects in the form of benzine fractions of petroleum oil. The fast scanning regime was used to record optoacoustic spectra of hydrocarbons (in the range 9.2-10.8μ) during the travel time (1-10 sec) of the individual components of a mixture through an optoacoustic cell in the course of chromatrographic separation of these components. The spectra were used to carry out a group hydrocarbon analysis of benzine fractions of petroleum oil from various locations. The proposed method was relatively fast and was characterized by a good ability for identification of various components, compared with the usually employed method such as gas-liquid capillary chromatography.

  15. Analysis for petroleum products in marine environments

    NASA Astrophysics Data System (ADS)

    Malins, D. C.; Krahn, M. M.; Brown, D. W.; MacLeod, W. D.; Collier, T. K.

    1980-03-01

    Petroleum is composed of a complex mixture of hydrocarbons that readily undergo chemical and biological conversions on entering aquatic environments. These conversions lead to the formation of a host of oxygenated products, some of which are potentially toxic to marine life and to the consumer of fishery products. State-of-the-art analytical methods, as employed in our laboratories, utilize glass-capillary gas chromatography in conjunction with mass spectrometry to analyze environmental samples containing trace amounts of aliphatic and aromatic petroleum hydrocarbons. These procedures are applied on a routine basis to the analysis of seawater, sediments and tissues of marine organisms. Despite this analytical proficiency, a need exists for analyzing oxygenated and other polar petroleum products in environmental samples. For example, techniques such as high-performance liquid chromatography (HPLC), in conjunction with on-line fluorometric assay techniques and mass spectrometry, make possible the analysis of polar oxygenated compounds resulting from both chemical and biological conversions. These methodologies are first steps toward the development of routine assay procedures for environmental samples. Current techniques for hydrocarbon analyses and new methods for analyzing polar aromatic compounds are discussed.

  16. Environmental analysis of plastic production processes: comparing petroleum-based polypropylene and polyethylene with biologically-based poly-beta-hydroxybutyric acid using life cycle analysis.

    PubMed

    Harding, K G; Dennis, J S; von Blottnitz, H; Harrison, S T L

    2007-05-31

    Polymers based on olefins have wide commercial applicability. However, they are made from non-renewable resources and are characterised by difficulty in disposal where recycle and re-use is not feasible. Poly-beta-hydroxybutyric acid (PHB) provides one example of a polymer made from renewable resources. Before motivating its widespread use, the advantages of a renewable polymer must be weighed against the environmental aspects of its production. Previous studies relating the environmental impacts of petroleum-based and bio-plastics have centred on the impact categories of global warming and fossil fuel depletion. Cradle-to-grave studies report equivalent or reduced global warming impacts, in comparison to equivalent polyolefin processes. This stems from a perceived CO(2) neutral status of the renewable resource. Indeed, no previous work has reported the results of a life cycle assessment (LCA) giving the environmental impacts in all major categories. This study investigates a cradle-to-gate LCA of PHB production taking into account net CO(2) generation and all major impact categories. It compares the findings with similar studies of polypropylene (PP) and polyethylene (PE). It is found that, in all of the life cycle categories, PHB is superior to PP. Energy requirements are slightly lower than previously observed and significantly lower than those for polyolefin production. PE impacts are lower than PHB values in acidification and eutrophication.

  17. Environmental analysis of plastic production processes: comparing petroleum-based polypropylene and polyethylene with biologically-based poly-beta-hydroxybutyric acid using life cycle analysis.

    PubMed

    Harding, K G; Dennis, J S; von Blottnitz, H; Harrison, S T L

    2007-05-31

    Polymers based on olefins have wide commercial applicability. However, they are made from non-renewable resources and are characterised by difficulty in disposal where recycle and re-use is not feasible. Poly-beta-hydroxybutyric acid (PHB) provides one example of a polymer made from renewable resources. Before motivating its widespread use, the advantages of a renewable polymer must be weighed against the environmental aspects of its production. Previous studies relating the environmental impacts of petroleum-based and bio-plastics have centred on the impact categories of global warming and fossil fuel depletion. Cradle-to-grave studies report equivalent or reduced global warming impacts, in comparison to equivalent polyolefin processes. This stems from a perceived CO(2) neutral status of the renewable resource. Indeed, no previous work has reported the results of a life cycle assessment (LCA) giving the environmental impacts in all major categories. This study investigates a cradle-to-gate LCA of PHB production taking into account net CO(2) generation and all major impact categories. It compares the findings with similar studies of polypropylene (PP) and polyethylene (PE). It is found that, in all of the life cycle categories, PHB is superior to PP. Energy requirements are slightly lower than previously observed and significantly lower than those for polyolefin production. PE impacts are lower than PHB values in acidification and eutrophication. PMID:17400318

  18. The influence of petroleum products on the methane fermentation process.

    PubMed

    Choromański, Paweł; Karwowska, Ewa; Łebkowska, Maria

    2016-01-15

    In this study the influence of the petroleum products: diesel fuel and spent engine oil on the sewage sludge digestion process and biogas production efficiency was investigated. Microbiological, chemical and enzymatic analyses were applied in the survey. It was revealed that the influence of the petroleum derivatives on the effectiveness of the methane fermentation of sewage sludge depends on the type of the petroleum product. Diesel fuel did not limit the biogas production and the methane concentration in the biogas, while spent engine oil significantly reduced the process efficacy. The changes in physical-chemical parameters, excluding COD, did not reflect the effect of the tested substances. The negative influence of petroleum products on individual bacterial groups was observed after 7 days of the process, while after 14 days probably some adaptive mechanisms appeared. The dehydrogenase activity assessment was the most relevant parameter to evaluate the effect of petroleum products contamination. Diesel fuel was probably used as a source of carbon and energy in the process, while the toxic influence was observed in case of spent engine oil.

  19. The influence of petroleum products on the methane fermentation process.

    PubMed

    Choromański, Paweł; Karwowska, Ewa; Łebkowska, Maria

    2016-01-15

    In this study the influence of the petroleum products: diesel fuel and spent engine oil on the sewage sludge digestion process and biogas production efficiency was investigated. Microbiological, chemical and enzymatic analyses were applied in the survey. It was revealed that the influence of the petroleum derivatives on the effectiveness of the methane fermentation of sewage sludge depends on the type of the petroleum product. Diesel fuel did not limit the biogas production and the methane concentration in the biogas, while spent engine oil significantly reduced the process efficacy. The changes in physical-chemical parameters, excluding COD, did not reflect the effect of the tested substances. The negative influence of petroleum products on individual bacterial groups was observed after 7 days of the process, while after 14 days probably some adaptive mechanisms appeared. The dehydrogenase activity assessment was the most relevant parameter to evaluate the effect of petroleum products contamination. Diesel fuel was probably used as a source of carbon and energy in the process, while the toxic influence was observed in case of spent engine oil. PMID:26378365

  20. Co-processing of carbonaceous solids and petroleum oil

    DOEpatents

    Gupta, Avinash; Greene, Marvin I.

    1992-01-01

    In a process for producing distillates from coal by a first stage thermal liquefaction followed by a catalytic hydrogenation, liquefaction solvent is added at points spaced over the length of the thermal liquefaction heater. Coal may be co-processed with petroleum oil by adding pre-hydrogenated oil to the first stage or unhydrogenated oil to the second stage.

  1. Petroleum.

    ERIC Educational Resources Information Center

    McManus, T. R.; And Others

    1989-01-01

    This review of petroleum covers: crude oil; fuels, gaseous and liquid; lubricants, oils, and greases; asphalts, bitumens, tars, and pitches; hydrocarbons; physical properties; metals in oil; nonmetallic elements and heterocompounds; and analytical methods and apparatus. (MVL)

  2. Thermal acidization and recovery process for recovering viscous petroleum

    DOEpatents

    Poston, Robert S.

    1984-01-01

    A thermal acidization and recovery process for increasing production of heavy viscous petroleum crude oil and synthetic fuels from subterranean hydrocarbon formations containing clay particles creating adverse permeability effects is described. The method comprises injecting a thermal vapor stream through a well bore penetrating such formations to clean the formation face of hydrocarbonaceous materials which restrict the flow of fluids into the petroleum-bearing formation. Vaporized hydrogen chloride is then injected simultaneously to react with calcium and magnesium salts in the formation surrounding the bore hole to form water soluble chloride salts. Vaporized hydrogen fluoride is then injected simultaneously with its thermal vapor to dissolve water-sensitive clay particles thus increasing permeability. Thereafter, the thermal vapors are injected until the formation is sufficiently heated to permit increased recovery rates of the petroleum.

  3. SIMS image processing methods for petroleum cracking catalyst characterization

    SciTech Connect

    Leta, D.P.; Lamberti, W.A.; Disko, M.M.; Kugler, E.L.; Varady, W.A. )

    1990-08-01

    The technique of Imaging Secondary Ion Mass Spectrometry (SIMS) has proven to be very well suited to the characterization of fluidized petroleum cracking catalysts (FCC). The ability to view elemental distributions with 0.5 micron spatial resolution at concentrations in the ppm range mates well with the submicron phases and low concentration contaminants present in commercial multi-component FCC particles. The use of ultra-low light level imaging systems with the intrinsically sensitive SIMS technique makes real time viewing of many of the elements important in FCC catalysts possible. Aluminum, silicon and the rare earth elements serve to define the major phases present within each catalyst particle, while the transition row elements and all of the alkali and alkaline elements may be seen at trace concentrations. Of particular importance is the use of the technique to study the distributions of nickel and vanadium which are the most deleterious of the contaminant metals. Modern image processing computers and software now allow the rapid quantitative analysis of SIMS elemental images in order to more clearly reveal the locations of the catalyst phases and the quantitative distributions of the contaminant metals on those phases. Although the analysis techniques discussed in this study may be applied to any of the contaminant elements, for simplicity the authors will limit their examples to the major catalyst elements, and the nickel and vanadium contaminants.

  4. Process for stimulating petroleum production wells

    SciTech Connect

    Dor, I.

    1986-06-17

    A process is described for controlling algal growth in the wind-mixed layer of a salt water solar pond having a halocline located below the wind-mixed layer and a heat storage layer located below the halocline, wherein the halocline has a downwardly directed salt gradient and a temperature profile that follows the salinity profile, comprising rapidly changing the salinity in the wind-mixed layer for rapidly changing the osmotic pressure on algae in the wind-mixed layer which are sensitive to rapid changes in ambient salinity by an amount effective to cause such algae therein to sink into a region of increased temperature.

  5. Factorial kriging analysis applied to geological data from petroleum exploration

    SciTech Connect

    Jaquet, O.

    1989-10-01

    A regionalized variable, thickness of the reservoir layer, from a gas field is decomposed by factorial kriging analysis. Maps of the obtained components may be associated with depositional environments that are favorable for petroleum exploration.

  6. Probability theory versus simulation of petroleum potential in play analysis

    USGS Publications Warehouse

    Crovelli, R.A.

    1987-01-01

    An analytic probabilistic methodology for resource appraisal of undiscovered oil and gas resources in play analysis is presented. This play-analysis methodology is a geostochastic system for petroleum resource appraisal in explored as well as frontier areas. An objective was to replace an existing Monte Carlo simulation method in order to increase the efficiency of the appraisal process. Underlying the two methods is a single geologic model which considers both the uncertainty of the presence of the assessed hydrocarbon and its amount if present. The results of the model are resource estimates of crude oil, nonassociated gas, dissolved gas, and gas for a geologic play in terms of probability distributions. The analytic method is based upon conditional probability theory and a closed form solution of all means and standard deviations, along with the probabilities of occurrence. ?? 1987 J.C. Baltzer A.G., Scientific Publishing Company.

  7. [Analysis of fluorescence spectrum of petroleum-polluted water].

    PubMed

    Huang, Miao-Fen; Song, Qing-Jun; Xing, Xu-Feng; Jian, Wei-Jun; Liu, Yuan; Zhao, Zu-Long

    2014-09-01

    In four ratio experiments, natural waters, sampled from the mountain reservoir and the sea water around Dalian city, were mixed with the sewage from petroleum refinery and petroleum exploitation plants. The fluorescence spectra of water samples containing only chromophoric dissolved organic matters(CDOM), samples containing only petroleum, and samples containing a mixture of petroleum and CDOM were analyzed, respectively. The purpose of this analysis is to provide a basis for determining the contribution of petroleum substances and CDOM to the total absorption coefficient of the petroleum-contaminated water by using fluorescence technique. The results showed that firstly, CDOM in seawater had three main fluorescence peaks at Ex: 225-230 nm/Em: 320-330 nm, Ex: 280 nm/Em: 340 nm and Ex: 225-240 nm/Em: 430-470 nm, respectively, and these may arise from the oceanic chlorophyll. CDOM in natural reservoir water had two main fluorescence peaks at EX: 240- 260 nm/Em: 420-450 nm and Ex: 310~350 nm/Em: 420--440 nm, respectively, and these may arise from the terrestrial sources; secondly, the water samples containing only petroleum extracted with n-hexane had one to three fluorescence spectral peaksat Ex: 220-240 nm/Em: 320-340 nm, Ex: 270-290 nm/Em: 310-340 nm and Ex: 220-235 nm/Em: 280-310 nm, respectively, caused by their hydrocarbon component; finally, the water samples containing both petroleum and CDOM showed a very strong fluorescence peak at Ex: 230-250 nm/Em: 320-370 nm, caused by the combined effect of CDOM and petroleum hydrocarbons.

  8. [Analysis of fluorescence spectrum of petroleum-polluted water].

    PubMed

    Huang, Miao-Fen; Song, Qing-Jun; Xing, Xu-Feng; Jian, Wei-Jun; Liu, Yuan; Zhao, Zu-Long

    2014-09-01

    In four ratio experiments, natural waters, sampled from the mountain reservoir and the sea water around Dalian city, were mixed with the sewage from petroleum refinery and petroleum exploitation plants. The fluorescence spectra of water samples containing only chromophoric dissolved organic matters(CDOM), samples containing only petroleum, and samples containing a mixture of petroleum and CDOM were analyzed, respectively. The purpose of this analysis is to provide a basis for determining the contribution of petroleum substances and CDOM to the total absorption coefficient of the petroleum-contaminated water by using fluorescence technique. The results showed that firstly, CDOM in seawater had three main fluorescence peaks at Ex: 225-230 nm/Em: 320-330 nm, Ex: 280 nm/Em: 340 nm and Ex: 225-240 nm/Em: 430-470 nm, respectively, and these may arise from the oceanic chlorophyll. CDOM in natural reservoir water had two main fluorescence peaks at EX: 240- 260 nm/Em: 420-450 nm and Ex: 310~350 nm/Em: 420--440 nm, respectively, and these may arise from the terrestrial sources; secondly, the water samples containing only petroleum extracted with n-hexane had one to three fluorescence spectral peaksat Ex: 220-240 nm/Em: 320-340 nm, Ex: 270-290 nm/Em: 310-340 nm and Ex: 220-235 nm/Em: 280-310 nm, respectively, caused by their hydrocarbon component; finally, the water samples containing both petroleum and CDOM showed a very strong fluorescence peak at Ex: 230-250 nm/Em: 320-370 nm, caused by the combined effect of CDOM and petroleum hydrocarbons. PMID:25532346

  9. Anaerobic methanethiol degradation and methanogenic community analysis in an alkaline (pH 10) biological process for liquefied petroleum gas desulfurization.

    PubMed

    van Leerdam, Robin C; Bonilla-Salinas, Monica; de Bok, Frank A M; Bruning, H; Lens, Piet N L; Stams, Alfons J M; Janssen, Albert J H

    2008-11-01

    Anaerobic methanethiol (MT) degradation by mesophilic (30 degrees C) alkaliphilic (pH 10) communities was studied in a lab-scale Upflow Anaerobic Sludge Bed (UASB) reactor inoculated with a mixture of sediments from the Wadden Sea (The Netherlands), Soap Lake (Central Washington), and Russian soda lakes. MT degradation started after 32 days of incubation. During the first 252 days, complete degradation was achieved till a volumetric loading rate of 7.5 mmol MT/L/day, and sulfide, methane, and carbon dioxide were the main reaction products. Temporary inhibition of MT degradation occurred after MT peak loads and in the presence of dimethyl disulfide (DMDS), which is the autooxidation product of MT. From day 252 onwards, methanol was dosed to the reactor as co-substrate at a loading rate of 3-6 mmol/L/day to stimulate growth of methylotrophic methanogens. Methanol was completely degraded and also a complete MT degradation was achieved till a volumetric loading rate of 13 mmol MT/L/day (0.77 mmol MT/gVSS/day). However, from day 354 till the end of the experimental run (day 365), acetate was formed and MT was not completely degraded anymore, indicating that methanol-degrading homoacetogenic bacteria had partially outcompeted the methanogenic MT-degrading archea. The archeal community in the reactor sludge was analyzed by DGGE and sequencing of 16S rRNA genes. The methanogenic archea responsible for the degradation of MT in the reactor were related to Methanolobus oregonensis. A pure culture, named strain SODA, was obtained by serial dilutions in medium containing both trimethyl amine and dimethyl sulfide (DMS). Strain SODA degraded MT, DMS, trimethyl amine, and methanol. Flow sheet simulations revealed that for sufficient MT removal from liquefied petroleum gas, the extraction and biological degradation process should be operated above pH 9.

  10. Determination of Total Petroleum Hydrocarbons (TPH) Using Total Carbon Analysis

    SciTech Connect

    Ekechukwu, A.A.

    2002-05-10

    Several methods have been proposed to replace the Freon(TM)-extraction method to determine total petroleum hydrocarbon (TPH) content. For reasons of cost, sensitivity, precision, or simplicity, none of the replacement methods are feasible for analysis of radioactive samples at our facility. We have developed a method to measure total petroleum hydrocarbon content in aqueous sample matrixes using total organic carbon (total carbon) determination. The total carbon content (TC1) of the sample is measured using a total organic carbon analyzer. The sample is then contacted with a small volume of non-pokar solvent to extract the total petroleum hydrocarbons. The total carbon content of the resultant aqueous phase of the extracted sample (TC2) is measured. Total petroleum hydrocarbon content is calculated (TPH = TC1-TC2). The resultant data are consistent with results obtained using Freon(TM) extraction followed by infrared absorbance.

  11. APPLICATION OF SPATIAL INFORMATION TECHNOLOGY TO PETROLEUM RESOURCE ASSESSMENT ANALYSIS.

    USGS Publications Warehouse

    Miller, Betty M.; Domaratz, Michael A.

    1984-01-01

    Petroleum resource assessment procedures require the analysis of a large volume of spatial data. The US Geological Survey (USGS) has developed and applied spatial information handling procedures and digital cartographic techniques to a recent study involving the assessment of oil and gas resource potential for 74 million acres of designated and proposed wilderness lands in the western United States. The part of the study which dealt with the application of spatial information technology to petroleum resource assessment procedures is reviewed. A method was designed to expedite the gathering, integrating, managing, manipulating and plotting of spatial data from multiple data sources that are essential in modern resource assessment procedures.

  12. Hybrid vehicle assessment. Phase 1: Petroleum savings analysis

    NASA Technical Reports Server (NTRS)

    Levin, R.; Liddle, S.; Deshpande, G.; Trummel, M.; Vivian, H. C.

    1984-01-01

    The results of a comprehensive analysis of near term electric hybrid vehicles are presented, with emphasis on their potential to save significant amounts of petroleum on a national scale in the 1990s. Performance requirements and expected annual usage patterns of these vehicles are first modeled. The projected U.S. fleet composition is estimated, and conceptual hybrid vehicle designs are conceived and analyzed for petroleum use when driven in the expected annual patterns. These petroleum consumption estimates are then compared to similar estimates for projected 1990 conventional vehicles having the same performance and driven in the same patterns. Results are presented in the form of three utility functions and comparisons of sevral conceptual designs are made. The Hybrid Vehicle (HV) design and assessment techniques are discussed and a general method is explained for selecting the optimum energy management strategy for any vehicle mission battery combination. Conclusions and recommendations are presented, and development recommendations are identified.

  13. Structural integrity, NDE, risk and material performance for petroleum, process and power. PVP-Volume 336

    SciTech Connect

    Prager, M.; Bagnoli, D.L.; Warke, W.R.; Anyewuenyi, O.A.; Smith, J.P.; Chen, M.; DePadova, T.A.; Weingart, L.J.

    1996-12-01

    This volume continues a series at the 1996 Pressure Vessels and Piping Conference on the theme Service Experience in the Petroleum Industry. There is much to be gained from evaluating the performance of components after service in hostile environments. The lessons learned relate to the adequacy of design margins. Where deterioration is attributed to wet hydrogen sulfide, hydrogen attack of high temperature, the suitability of degraded materials for continuing service must be closely monitored and or life prediction tools enhanced. This volume provides numerous case histories, strategies, practical examples and theoretical approaches. For example, work on elevated temperature behavior herein discloses principles for establishing design margins and also, how off-nominal conditions in tubes and piping may shorten life. Papers in this volume are arranged under the following topics: service experience in petrochemical plants; risk-based inspection; NDE issues in the petroleum industry; high temperature service in the petroleum industry; tankage analysis and standards; and finite element analysis applications for the process industries. Most papers have been processed separately for inclusion on the data base.

  14. Treatment of petroleum refinery sourwater by advanced oxidation processes.

    PubMed

    Coelho, Alessandra; Castro, Antonio V; Dezotti, Márcia; Sant'Anna, G L

    2006-09-01

    The performance of several oxidation processes to remove organic pollutants from sourwater was investigated. Sourwater is a specific stream of petroleum refineries, which contains slowly biodegradable compounds and toxic substances that impair the industrial biological wastewater treatment system. Preliminary experiments were conducted, using the following processes: H2O2, H2O2/UV, UV, photocatalysis, ozonation, Fenton and photo-Fenton. All processes, except Fenton and photo-Fenton, did not lead to satisfactory results, reducing at most 35% of the sourwater dissolved organic carbon (DOC). Thus, further experiments were performed with these two techniques to evaluate process conditions and organic matter removal kinetics. Batch experiments revealed that the Fenton reaction is very fast and reaches, in a few minutes, an ultimate DOC removal of 13-27%, due to the formation of iron complexes. Radiation for an additional period of 60 min can increase DOC removal up to 87%. Experiments were also conducted in a continuous mode, operating one 0.4L Fenton stirred reactor and one 1.6L photo-Fenton reactor in series. DOC removals above 75% were reached, when the reaction system was operated with hydraulic retention times (HRT) higher than 85 min. An empirical mathematical model was proposed to represent the DOC removal kinetics, allowing predicting process performance quite satisfactorily.

  15. Improving petroleum contaminated land remediation decision-making through the MCA weighting process.

    PubMed

    Balasubramaniam, Anopama; Boyle, Alexander Rohan; Voulvoulis, Nikolaos

    2007-01-01

    Internationally petroleum contamination is widespread, posing serious environmental risks including surface and groundwater contamination, thus remediation is essential. The implementation of remediation options is becoming more complex with the increasing influence of stakeholders on the outcome of decision-making processes. Acceptance of remediation schemes during implementation can be increased by involving stakeholders and the public in the decision-making stage. In petroleum remediation involving multiple stakeholders, Multicriteria Analysis has been employed due to its ability to incorporate the preferences of each stakeholder through weighting. The research focused on investigating ways to improve the weighting process. The study demonstrated the utility of SWING, and determined which type of participant and how many participants to include in the decision process, through the application of ELECTRE III and Weighted Summation. It was recommended that a mixture of stakeholders, the public and experts be involved. The total number of participants will be limited by the choice of participatory and weighting methods. The careful selection of participants, as well as the choice of participatory and weighting methods, can minimize the subjectivity involved in MCA weighting, thereby lending decisions in petroleum remediation greater legitimacy.

  16. Simulation and optimization technologies for petroleum waste management and remediation process control.

    PubMed

    Qin, X S; Huang, G H; He, L

    2009-01-01

    Leakage and spill of petroleum hydrocarbons from underground storage tanks and pipelines have posed significant threats to groundwater resources across many petroleum-contaminated sites. Remediation of these sites is essential for protecting the soil and groundwater resources and reducing risks to local communities. Although many efforts have been made, effective design and management of various remediation systems are still challenging to practitioners. In recent years, the subsurface simulation model has been combined with techniques of optimization to address important problems of contaminated site management. The combined simulation-optimization system accounts for the complex behavior of the subsurface system and identifies the best management strategy under consideration of the management objectives and constraints. During the past decades, a large number of studies were conducted to simulate contaminant flow and transport in the subsurface and seek cost-effective remediation designs. This paper gives a comprehensive review on recent developments, advancements, challenges, and barriers associated with simulation and optimization techniques in supporting process control of petroleum waste management and site remediation. A number of related methodologies and applications were examined. Perspectives of effective site management were investigated, demonstrating many demanding areas for enhanced research efforts, which include issues of data availability and reliability, concerns in uncertainty, necessity of post-modeling analysis, and usefulness of development of process control techniques.

  17. Purification and detoxification of petroleum refinery wastewater by electrocoagulation process.

    PubMed

    Gousmi, N; Sahmi, A; Li, H Z; Poncin, S; Djebbar, R; Bensadok, K

    2016-09-01

    The treatment of synthetic oily wastewater having the characteristics of a typical petroleum refinery wastewater (PRW) by electrocoagulation (EC) using iron and aluminum electrodes was conducted in an electrolytic reactor equipped with fluid recirculation. During the treatment, the emulsion stability was followed by the measurement of Zeta potential and particle sizes. Effects of some operating conditions such as electrodes material, current density and electrolysis time on removal efficiencies of turbidity, and chemical oxygen demand (COD) were investigated in detail. The PRW purification by the EC process was found to be the most effective using aluminum as the anode and cathode, current density of 60 A/m(2) and 30 min of electrolysis time. Under these conditions, the process efficiencies were 83.52% and 99.94%, respectively, for COD and turbidity removals which correspond to final values of 96 mg O2/L and 0.5 NTU. A moderate energy consumption (0.341 kWh) was needed to treat 1 m(3) of PRW. Besides, the ecotoxicity test proved that toxic substances presented in the PRW, and those inhibiting the germination growth of whet, were eliminated by the EC technique.

  18. Emergency petroleum conservation: a review and analysis of selected measures

    SciTech Connect

    Boercker, F.D.; Balasubramaniam, M.; Hull, E.; Savadelis, J.; Valentini, J.J.

    1980-01-01

    ORNL was asked by the Economic Regulatory Administration to (1) collect, screen, and recommend a limited number of emergency measures that might conserve petroleum in residential and commercial buildings and in commercial transportation and (2) provide a detailed analysis of the energy savings and the economic and environmental impacts associated with restricting the hours of operation of commercial buildings. A total of 41 emergency measures were identified that might conserve petroleum, and these were reduced to a list of five that seemed most promising. Analysis of the measure to restrict hours of operation for commercial buildings shows that it might save 4 to 6% of annual commercial building energy use. The type of fuel conserved would vary widely from region to region, and appreciable negative economic impacts would result from implementing the measure.

  19. Defining Human Failure Events for Petroleum Risk Analysis

    SciTech Connect

    Ronald L. Boring; Knut Øien

    2014-06-01

    In this paper, an identification and description of barriers and human failure events (HFEs) for human reliability analysis (HRA) is performed. The barriers, called target systems, are identified from risk significant accident scenarios represented as defined situations of hazard and accident (DSHAs). This report serves as the foundation for further work to develop petroleum HFEs compatible with the SPAR-H method and intended for reuse in future HRAs.

  20. Evaluation of electrochemical processes for the removal of several target aromatic hydrocarbons from petroleum contaminated water.

    PubMed

    Alsalka, Yamen; Karabet, François; Hashem, Shahir

    2011-03-01

    Ground and surface water contamination resulting from the leakage of crude oil and refined petroleum products is a serious and growing environmental problem throughout the world. Consequently, a study of the use of electrochemical treatment in the clean-up was undertaken with the aim of reducing the water contamination by aromatic pollutants to more acceptable levels. In the experiments described, water contamination by refined petroleum products was simulated under laboratory conditions. Electrochemical treatment, using aluminium electrodes, has been optimised by full factorial design and surface response analysis in term of BTEX and PAHs removal and energy consumption. The optimal conditions of pH, current density, electrolysis time, electrolyte type, and electrolyte concentration have then been applied in the treatment of real water samples which were monitored as petroleum contaminated samples. Treatment results have shown that electrochemical methods could achieve the concentration of these pollutants to undetectable levels in particular groundwater and surface water, hence, they can be highly effective in the remediation of water contaminated by aromatic hydrocarbons, and the use of these processes is therefore recommended.

  1. An integrated bioremediation process for petroleum hydrocarbons removal and odor mitigation from contaminated marine sediment.

    PubMed

    Zhang, Zhen; Lo, Irene M C; Yan, Dickson Y S

    2015-10-15

    This study developed a novel integrated bioremediation process for the removal of petroleum hydrocarbons and the mitigation of odor induced by reduced sulfur from contaminated marine sediment. The bioremediation process consisted of two phases. In Phase I, acetate was dosed into the sediment as co-substrate to facilitate the sulfate reduction process. Meanwhile, akaganeite (β-FeOOH) was dosed in the surface layer of the sediment to prevent S(2-) release into the overlying seawater. In Phase II, NO3(-) was injected into the sediment as an electron acceptor to facilitate the denitrification process. After 20 weeks of treatment, the sequential integration of the sulfate reduction and denitrification processes led to effective biodegradation of total petroleum hydrocarbons (TPH), in which about 72% of TPH was removed. In Phase I, the release of S(2-) was effectively controlled by the addition of akaganeite. The oxidation of S(2-) by Fe(3+) and the precipitation of S(2-) by Fe(2+) were the main mechanisms for S(2-) removal. In Phase II, the injection of NO3(-) completely inhibited the sulfate reduction process. Most of residual AVS and S(0) were removed within 4 weeks after NO3(-) injection. The 16S rRNA clone library-based analysis revealed a distinct shift of bacterial community structure in the sediment over different treatment phases. The clones affiliated with Desulfobacterales and Desulfuromonadales were the most abundant in Phase I, while the clones related to Thioalkalivibrio sulfidophilus, Thiohalomonas nitratireducens and Sulfurimonas denitrificans predominated in Phase II.

  2. Downhole fluid analysis and asphaltene science for petroleum reservoir evaluation.

    PubMed

    Mullins, Oliver C; Pomerantz, Andrew E; Zuo, Julian Y; Dong, Chengli

    2014-01-01

    Petroleum reservoirs are enshrouded in mysteries associated with all manner of geologic and fluid complexities that Mother Nature can inspire. Efficient exploitation of petroleum reservoirs mandates elucidation of these complexities; downhole fluid analysis (DFA) has proven to be indispensable for understanding both fluids and reservoir architecture. Crude oil consists of dissolved gases, liquids, and dissolved solids, known as the asphaltenes. These different fluid components exhibit fluid gradients vertically and laterally, which are best revealed by DFA, with its excellent precision and accuracy. Compositional gradient analysis falls within the purview of thermodynamics. Gas-liquid equilibria can be treated with a cubic equation of state (EoS), such as the Peng-Robinson EoS, a modified van der Waals EoS. In contrast, the first EoS for asphaltene gradients, the Flory-Huggins-Zuo (FHZ) EoS, was developed only recently. The resolution of the asphaltene molecular and nanocolloidal species in crude oil, which is codified in the Yen-Mullins model of asphaltenes, enabled the development of this EoS. The combination of DFA characterization of gradients of reservoir crude oil with the cubic EoS and FHZ EoS analyses brings into view wide-ranging reservoir concerns, such as reservoir connectivity, fault-block migration, heavy oil gradients, tar mat formation, huge disequilibrium fluid gradients, and even stochastic variations of reservoir fluids. New petroleum science and DFA technology are helping to offset the increasing costs and technical difficulties of exploiting ever-more-remote petroleum reservoirs.

  3. Strategic Petroleum Reserve: Analysis of size options

    SciTech Connect

    Not Available

    1990-02-01

    This report presents the results of the deliberations of the interagency group formed to study the costs and benefits of expanding the size of the SPR. The study concentrated on severe oil supply disruptions involving sharp reductions in world oil production that were 2 to 4 times larger than the largest 1970s interruption. The disruption sizes and estimated probability of occurrence of these scenarios were supplied by the CIA. The most critical part of the CIA's analysis was the assessment of likelihood of these cases occurring. The CIA approached the likelihood problem by combining an examination of past oil supply disruptions with qualitative analysis of important oil market and regional trends. The study group then used statistical techniques and probability distributions to synthesize the historical data with CIA evaluations of as yet unobserved events. The SPR size study assumed direct purchases of SPR oil and did not assume the use of alternative financing mechanisms. Members of the working group with foreign policy and national security responsibilities provided an in-depth review of strategic considerations affecting SPR size. A number of prior studies, some classified, have addressed the strategic importance and insurance value of the SPR to the US and its allies. The results of these studies have also been incorporated in the current effort. 10 refs., 5 figs.

  4. Hybrid vehicle assessment. Phase I. Petroleum savings analysis

    SciTech Connect

    Levin, R.; Liddle, S.; Deshpande, G.; Trummel, M.; Vivian, H.

    1984-03-01

    This report presents the results of a comprehensive analysis of near-term electric-hybrid vehicles. Its purpose was to estimate their potential to save significant amounts of petroleum on a national scale in the 1990s. Performance requirements and expected annual usage patterns of these vehicles were first modeled. The projected US fleet composition was estimated, and conceptual hybrid vehicle designs were conceived and analyzed for petroleum use when driven in the expected annual patterns. These petroleum consumption estimates were then compared to similar estimates for projected 1990 conventional vehicles having the same performance and driven in the same patterns. Results are presented in the form of three utility functions and comparisons of several conceptual designs are made. The Hybrid Vehicle (HV) design and assessment techniques are discussed and a general method is explained for selecting the optimum energy management strategy for any vehicle-mission-battery combination. A discussion of lessons learned during the construction and test of the General Electric Hybrid Test Vehicle is also presented. Conclusions and recommendations are presented, and development recommendations are identified.

  5. FASP, an analytic resource appraisal program for petroleum play analysis

    USGS Publications Warehouse

    Crovelli, R.A.; Balay, R.H.

    1986-01-01

    An analytic probabilistic methodology for resource appraisal of undiscovered oil and gas resources in play analysis is presented in a FORTRAN program termed FASP. This play-analysis methodology is a geostochastic system for petroleum resource appraisal in explored as well as frontier areas. An established geologic model considers both the uncertainty of the presence of the assessed hydrocarbon and its amount if present. The program FASP produces resource estimates of crude oil, nonassociated gas, dissolved gas, and gas for a geologic play in terms of probability distributions. The analytic method is based upon conditional probability theory and many laws of expectation and variance. ?? 1986.

  6. Thickness Optimization for Petroleum Coke in Microwave Dehydrating Based on the Analysis of Dynamic Absorption Efficiency

    NASA Astrophysics Data System (ADS)

    Shang, Xiaobiao; Chen, Junruo; Peng, Jinhui; Chen, Hua; Zhang, Weifeng; Guo, Shenghui; Chen, Guo

    2015-07-01

    An analytical approach is proposed to optimize the thickness of petroleum coke for achieving maximum microwave power absorption in microwave heating based on analysis of reflection loss (RL). The microwave RL of the petroleum coke layer was studied over the moisture content range of 1%-5% at 20 °C and the petroleum coke (10% moisture content) in the temperature range of 20 to 100 °C at 2.45 GHz. The results show that RL depends sensitively on the thickness of the petroleum coke and the absorption peak shifts towards a larger thickness as the moisture content of the petroleum coke increases. There exists a matching thickness corresponding to the maximum microwave absorption, the maximum absorbing peak decreases when the thickness of petroleum coke exceeds the matching thickness. We also show that the absorption peak is found to move towards a smaller thickness region with increasing petroleum coke temperature.

  7. Fundamentals of petroleum. Third edition

    SciTech Connect

    Gerding, M.

    1986-01-01

    This book contains the following nine chapters: Petroleum Geology; Petroleum Exploration; Aspects of Leasing; Drilling Operations; Production; Transportation; Refining and Processing; Petroleum Marketing; and Economics of the Industry.

  8. National petroleum reserve - Alaska: marine transportation system analysis. Final report

    SciTech Connect

    Macpherson, M.D.

    1980-10-01

    This report presents a comprehensive parametric analysis of a number of concepts for the marine transportation of crude oil and gas from the national petroleum reserve in the Alaskan Arctic (NPR-A) to the contiguous United States. The analysis provides the transportation costs for icebreaking and ice-strengthened surface tankers and LNG carriers over a range of ship sizes and propulsion power levels and for submarine tankers for each of a number of routes from four loading ports in the Arctic to discharge ports on the East and Gulf Coasts of the United States. The report includes discussions of the technical factors related to Arctic ship construction and operation, ice technology, and the environmental and institutional factors which must be included in an evaluation of an Arctic marine transportation system.

  9. National petroleum reserve - Alaska: marine transportation system analysis. Executive summary

    SciTech Connect

    Macpherson, M.D.

    1980-10-01

    This report presents a comprehensive parametric analysis of a number of concepts for the marine transportation of crude oil and gas from the national petroleum reserve in the Alaskan Arctic (NPR-A) to the contiguous United States. The analysis provides the transportation costs for icebreaking and ice-strengthened surface tankers and LNG carriers over a range of ship sizes and propulsion power levels and for submarine tankers for each of a number of routes from four loading ports in the Arctic to discharge ports on the East and Gulf Coasts of the United States. The report includes discussions of the technical factors related to Arctic ship construction and operation, ice technology, and the environmental and institutional factors which must be included in an evaluation of an Arctic marine transportation system.

  10. The Implementation and Maintenance of a Behavioral Safety Process in a Petroleum Refinery

    ERIC Educational Resources Information Center

    Myers, Wanda V.; McSween, Terry E.; Medina, Rixio E.; Rost, Kristen; Alvero, Alicia M.

    2010-01-01

    A values-centered and team-based behavioral safety process was implemented in a petroleum oil refinery. Employee teams defined the refinery's safety values and related practices, which were used to guide the process design and implementation. The process included (a) a safety assessment; (b) the clarification of safety-related values and related…

  11. Analysis of the petroleum resources of the Norwegian Continental Shelf

    SciTech Connect

    Flertoft, I.P.; Kvadsheim, E.; Kalheim, J.E.

    1995-08-01

    The 1995 analysis of the petroleum resources of Norway is based on a play analysis. The input to the 1995 analysis is updated and refined compared with the analysis of 1993. The analysis makes a major distinction between unconfirmed play models and plays confirmed by discoveries. The unconfirmed plays have a higher risk and a greater range of uncertainty in the resource estimates compared to the confirmed plays. The effect of the unconfirmed plays on the estimates within different exploration areas is discussed. The unconfirmed play models are an important aspect of the exploration in the new exploration areas north of 62{degrees}N. The total estimate for the Norwegian Shelf is well within the estimate given in the 1993 analysis, but there are some adjustments in the relative importance of the different exploration provinces. Much emphasis is placed on incorporating historical exploration data and statistics to calibrate the play models. This includes rate of success and field size distributions of the individual play models and exploration provinces. Major confirmed plays in the North Sea have a rate of success of about 30% and show a good fit to a log normal field size distribution. Based on the log normal distribution it is possible to give prognosis for the size distribution of the undiscovered accumulation. This has made it possible to work out an economic analysis of the profitability of future exploration on the Norwegian Continental Shelf.

  12. Deconvolution of petroleum mixtures using mid-FTIR analysis and non-negative matrix factorization

    NASA Astrophysics Data System (ADS)

    Livanos, George; Zervakis, Michalis; Pasadakis, Nikos; Karelioti, Marouso; Giakos, George

    2016-11-01

    The aim of this study is to develop an efficient, robust and cost effective methodology capable of both identifying the chemical fractions in complex commercial petroleum products and numerically estimating their concentration within the mixture sample. We explore a methodology based on attenuated total reflectance fourier transform infrared (ATR-FTIR) analytical signals, combined with a modified factorization algorithm to solve this ‘mixture problem’, first in qualitative and then in quantitative mode. The proposed decomposition approach is self-adapting to data without prior knowledge and is able of accurately estimating the weight contributions of constituents in the entire chemical compound. The results of the presented work to petroleum analysis indicate that it is possible to deconvolve the mixing process and recover the content in a chemically complex petroleum mixture using the infrared signals of a limited number of samples and the principal substances forming the mixture. A focus application of the proposed methodology is the quality control of commercial gasoline by identifying and quantifying the individual fractions utilized for its formulation via a fast, robust and efficient procedure based on mathematical analysis of the acquired spectra.

  13. Rapid evolution of redox processes in a petroleum hydrocarbon-contaminated aquifer

    USGS Publications Warehouse

    Chapelle, F.H.; Bradley, P.M.; Lovley, D.R.; O'Neill, K.; Landmeyer, J.E.

    2002-01-01

    Ground water chemistry data collected over a six-year period show that the distribution of contaminants and redox processes in a shallow petroleum hydrocarbon-contaminated aquifer has changed rapidly over time. Shortly after a gasoline release occurred in 1990, high concentrations of benzene were present near the contaminant source area. In this contaminated zone, dissolved oxygen in ground water was depleted, and by 1994 Fe(III) reduction and sulfate reduction were the predominant terminal electron accepting processes. Significantly, dissolved methane was below measurable levels in 1994, indicating the absence of significant methanogenesis. By 1996, however, depletion of solid-phase Fe(III)-oxyhydroxides in aquifer sediments and depletion of dissolved sulfate in ground water resulted in the onset of methanogenesis. Between 1996 and 2000, water-chemistry data indicated that methanogenic metabolism became increasingly prevalent. Molecular analysis of 16S-rDNA extracted from sediments shows the presence of a more diverse methanogenic community inside as opposed to outside the plume core, and is consistent with water-chemistry data indicating a shift toward methanogenesis over time. This rapid evolution of redox processes reflects several factors including the large amounts of contaminants, relatively rapid ground water flow (???0.3 m/day [???1 foot/day]), and low concentrations of microbially reducible Fe(III) oxyhydroxides (???1 ??mol/g) initially present in aquifer sediments. These results illustrate that, under certain hydrologic conditions, redox conditions in petroleum hydrocarbon-contaminated aquifers can change rapidly in time and space, and that the availability of solid-phase Fe(III)-oxyhydroxides affects this rate of change.

  14. Process for removing halogenated aliphatic and aromatic compounds from petroleum products

    DOEpatents

    Googin, John M.; Napier, John M.; Travaglini, Michael A.

    1983-01-01

    A process for removing halogenated aliphatic and aromatic compounds, e.g., polychlorinated biphenyls, from petroleum products by solvent extraction. The halogenated aliphatic and aromatic compounds are extracted from a petroleum product into a polar solvent by contacting the petroleum product with the polar solvent. The polar solvent is characterized by a high solubility for the extracted halogenated aliphatic and aromatic compounds, a low solubility for the petroleum product and considerable solvent power for polyhydroxy compound. The preferred polar solvent is dimethylformamide. A miscible compound, such as, water or a polyhydroxy compound, is added to the polar extraction solvent to increase the polarity of the polar extraction solvent. The halogenated aliphatic and aromatic compounds are extracted from the highly-polarized mixture of water or polyhydroxy compound and polar extraction solvent into a low polar or nonpolar solvent by contacting the water or polyhydroxy compound-polar solvent mixture with the low polar or nonpolar solvent. The halogenated aliphatic and aromatic compounds and the low polar or nonpolar solvent are separated by physical means, e.g., vacuum evaporation. The polar and nonpolar solvents are recovered from recycling. The process can easily be designed for continuous operation. Advantages of the process include that the polar solvent and a major portion of the nonpolar solvent can be recycled, the petroleum products are reclaimable and the cost for disposing of waste containing polychlorinated biphenyls is significantly reduced.

  15. Process for removing halogenated aliphatic and aromatic compounds from petroleum products

    DOEpatents

    Googin, J.M.; Napier, J.M.; Travaglini, M.A.

    1983-09-20

    A process is described for removing halogenated aliphatic and aromatic compounds, e.g., polychlorinated biphenyls, from petroleum products by solvent extraction. The halogenated aliphatic and aromatic compounds are extracted from a petroleum product into a polar solvent by contacting the petroleum product with the polar solvent. The polar solvent is characterized by a high solubility for the extracted halogenated aliphatic and aromatic compounds, a low solubility for the petroleum product and considerable solvent power for polyhydroxy compound. The preferred polar solvent is dimethylformamide. A miscible compound, such as, water or a polyhydroxy compound, is added to the polar extraction solvent to increase the polarity of the polar extraction solvent. The halogenated aliphatic and aromatic compounds are extracted from the highly-polarized mixture of water or polyhydroxy compound and polar extraction solvent into a low polar or nonpolar solvent by contacting the water or polyhydroxy compound-polar solvent mixture with the low polar or nonpolar solvent. The halogenated aliphatic and aromatic compounds and the low polar or nonpolar solvent are separated by physical means, e.g., vacuum evaporation. The polar and nonpolar solvents are recovered from recycling. The process can easily be designed for continuous operation. Advantages of the process include that the polar solvent and a major portion of the nonpolar solvent can be recycled, the petroleum products are reclaimable and the cost for disposing of waste containing polychlorinated biphenyls is significantly reduced. 1 fig.

  16. MERCURY IN PETROLEUM AND NATURAL GAS: ESTIMATION OF EMISSIONS FROM PRODUCTION, PROCESSING, AND COMBUSTION

    EPA Science Inventory

    The report gives results of an examination of mercury (Hg) in liquid and gaseous hydrocarbons that are produced and/or processed in the U.S. The Hg associated with petroleum and natural gas production and processing enters the environment primarily via solid waste streams (drilli...

  17. Inhibition of retrogressive reactions in coal/petroleum co-processing. Final technical report

    SciTech Connect

    Schobert, H.H.; Tomic, J.

    1993-05-25

    The objective of this study was to examine the processes in coal/petroleum coprocessing systems which led to coke formation. Specifically, the interactions between the petroleum residue and coal, leading to retrogressive products, were investigated. Five coals were reacted with five model compounds in order to investigate the coal conversions in a variety of solvents and to determine the role of the solvent in promoting or inhibiting coal conversion. The selected model compounds range from paraffinic to fully aromatic and were chosen as representative of types of compounds that are found in petroleum residua. Coprocessing experiments were conducted using the five coals and three petroleum residua. The effect of temperature on coal conversions was crucial. The coal conversions at 350 and 400{degree}C seem to be governed by the nature of the coal and to a lesser extent by the petroleum residua. Negative coal conversions were observed above 400{degree}C indicating that retrogressive processes had occurred. At temperatures higher than 400{degree}C, the petroleum residua undergo physical and chemical transformations and the influence of the petroleum residua on coal conversions is significant. The structural features of the residues indicated that the residues were predominately coal-derived. An overall increase in aromaticity was observed with increasing temperature which was also accompanied by loss of oxygen functional groups. The retrogressive reactions with non-caking coals involve carbonyl and carboxyl group leading to a final solid characterized by a cross-linked structure. In the case of caking coal, these reactions are governed by loss of aromatic oxygen groups and loss of alkyl groups.

  18. The OCS leasing process. [Petroleum deposit, natural gas deposit

    SciTech Connect

    Basile, F.

    1982-01-01

    The article discusses the Outer Continental Shelf (OCS) leasing process. While at the time this summary was written the proposal for revising the leasing process was being formulated, the author comments on what the discussions about the leasing process imply.

  19. Improvement of processes for treating saline wastewater in petroleum refineries

    SciTech Connect

    Sorochenko, V.F.

    1994-11-01

    The saline waste water produced in desalting crude oil in electric desalting units is usually dumped into the sewer system of the refinery. This work was aimed at developing methods of treatment with reagents to prevent and remove salt deposits in the process of freshening saline wastes, by means of aluminium chloride waste materials that have been recovered for utilization.

  20. Computational methods for a three-dimensional model of the petroleum-discovery process

    USGS Publications Warehouse

    Schuenemeyer, J.H.; Bawiec, W.J.; Drew, L.J.

    1980-01-01

    A discovery-process model devised by Drew, Schuenemeyer, and Root can be used to predict the amount of petroleum to be discovered in a basin from some future level of exploratory effort: the predictions are based on historical drilling and discovery data. Because marginal costs of discovery and production are a function of field size, the model can be used to make estimates of future discoveries within deposit size classes. The modeling approach is a geometric one in which the area searched is a function of the size and shape of the targets being sought. A high correlation is assumed between the surface-projection area of the fields and the volume of petroleum. To predict how much oil remains to be found, the area searched must be computed, and the basin size and discovery efficiency must be estimated. The basin is assumed to be explored randomly rather than by pattern drilling. The model may be used to compute independent estimates of future oil at different depth intervals for a play involving multiple producing horizons. We have written FORTRAN computer programs that are used with Drew, Schuenemeyer, and Root's model to merge the discovery and drilling information and perform the necessary computations to estimate undiscovered petroleum. These program may be modified easily for the estimation of remaining quantities of commodities other than petroleum. ?? 1980.

  1. Co-processing of carbonaceous solids and petroleum oil

    SciTech Connect

    Gupta, A.; Greene, M.I.

    1992-06-09

    This patent describes a process for liquefying a carbonaceous solid in a thermal liquefaction heater in a first stage thermal liquefaction in the presence of a liquefaction solvent, followed by a second stage catalytic hydrogenation wherein liquefaction solvent is recovered from the second stage for use in the first stage. This patent describes improvement in introducing a liquefaction solvent to the first stage liquefaction heater.

  2. Computer processing of remote-sensing data for petroleum exploration

    SciTech Connect

    Sabins, F.F. )

    1990-05-01

    Digitally processed remote-sensing images acquired from satellites and aircraft are increasingly employed for onshore exploration. The US Landsat thematic mapper acquires regional images (170 {times} 185 km) with moderate spatial resolution (30 m) and seven spectral bands. The French SPOT system acquires local images (60 by 60 km) in two modes: infrared color images of moderate resolution (20 m) and panchromatic images of high resolution (10 m). Landsat and SPOT are passive systems that primarily record reflectance at visible and reflected infrared wavelengths which do not penetrate clouds. Radar is an active system that operates at microwave wavelengths and penetrates clouds to produce images that enhance subtle topographic and tectonic features. The following digital processes are applied to the remote-sensing data to produce images for geologic interpretation. Restoration compensates for errors, noise, and distortion introduced during the scanning, transmission, and recording of image data. Typical programs correct for dropouts, banding, noise, atmospheric effects, and geometric distortion. Enhancement modifies data to improve its interpretability. Typical programs include contrast enhancement, edge enhancement, and transformation into intensity, hue, and saturation components. Information extraction identifies specific geologic relationships for the interpreter. Principal components, ratios, and classification images provide lithologic and other geologic information. Regional studies in temperate to arid areas typically use Landsat images. Complex subareas are then examined on SPOT panchromatic images which may be digitally composited with Landsat data. Radar images are employed in cloudy regions and to enhance low-relief features. These concepts are illustrated with processed images from various exploration project.

  3. Petroleum refinery stripped sour water treatment using the activated sludge process.

    PubMed

    Merlo, Rion; Gerhardt, Matthew B; Burlingham, Fran; De Las Casas, Carla; Gill, Everett; Flippin, T Houston

    2011-11-01

    A pilot study was performed over 91 days to determine if the activated sludge process could treat a segregated stripped sour water (SSW) stream from a petroleum refinery. The study was performed in two periods. The first period was terminated after 19 days, as a result of excessive sludge bulking. The elimination of sludge bulking during the 70-day second period is attributed to operational changes, which included aerating the influent to oxidize reduced sulfur, adjusting the influent pH, and adding micronutrients to satisfy biological requirements. The pilot plant provided a chemical oxygen demand (COD) removal of up to 93%. Nitrification was achieved, with effluent ammonia values < 1 mg-N/L. These results indicate that direct treatment of SSW with the activated sludge process is possible and has direct application to full-scale petroleum refinery wastewater plant upgrades.

  4. Microarray analysis of Neosartorya fischeri using different carbon sources, petroleum asphaltenes and glucose-peptone

    PubMed Central

    Hernández-López, Edna L.; Ramírez-Puebla, Shamayim T.; Vazquez-Duhalt, Rafael

    2015-01-01

    Asphaltenes are considered as the most recalcitrant petroleum fraction and represent a big problem for the recovery, separation and processing of heavy oils and bitumens. Neosartorya fischeri is a saprophytic fungus that is able to grow using asphaltenes as the sole carbon source [1]. We performed transcription profiling using a custom designed microarray with the complete genome from N. fischeri NRRL 181 in order to identify genes related to the transformation of asphaltenes [1]. Data analysis was performed using the genArise software. Results showed that 287 genes were up-regulated and 118 were down-regulated. Here we describe experimental procedures and methods about our dataset (NCBI GEO accession number GSE68146) and describe the data analysis to identify different expression levels in N. fischeri using this recalcitrant carbon source. PMID:26484261

  5. Distribution of petroleum degrading genes and factor analysis of petroleum contaminated soil from the Dagang Oilfield, China.

    PubMed

    Liu, Qinglong; Tang, Jingchun; Bai, Zhihui; Hecker, Markus; Giesy, John P

    2015-06-18

    Genes that encode for enzymes that can degrade petroleum hydrocarbons (PHs) are critical for the ability of microorganisms to bioremediate soils contaminated with PHs. Distributions of two petroleum-degrading genes AlkB and Nah in soils collected from three zones of the Dagang Oilfield, Tianjin, China were investigated. Numbers of copies of AlkB ranged between 9.1 × 10(5) and 1.9 × 10(7) copies/g dry mass (dm) soil, and were positively correlated with total concentrations of PHs (TPH) (R(2) = 0.573, p = 0.032) and alkanes (C33 ~ C40) (R(2) = 0.914, p < 0.01). The Nah gene was distributed relatively evenly among sampling zones, ranging between 1.9 × 10(7) and 1.1 × 10(8) copies/g dm soil, and was negatively correlated with concentrations of total aromatic hydrocarbons (TAH) (R(2) = -0.567, p = 0.035) and ∑16 PAHs (R(2) = -0.599, p = 0.023). Results of a factor analysis showed that individual samples of soils were not ordinated as a function of the zones.

  6. Distribution of petroleum degrading genes and factor analysis of petroleum contaminated soil from the Dagang Oilfield, China

    NASA Astrophysics Data System (ADS)

    Liu, Qinglong; Tang, Jingchun; Bai, Zhihui; Hecker, Markus; Giesy, John P.

    2015-06-01

    Genes that encode for enzymes that can degrade petroleum hydrocarbons (PHs) are critical for the ability of microorganisms to bioremediate soils contaminated with PHs. Distributions of two petroleum-degrading genes AlkB and Nah in soils collected from three zones of the Dagang Oilfield, Tianjin, China were investigated. Numbers of copies of AlkB ranged between 9.1 × 105 and 1.9 × 107 copies/g dry mass (dm) soil, and were positively correlated with total concentrations of PHs (TPH) (R2 = 0.573, p = 0.032) and alkanes (C33 ~ C40) (R2 = 0.914, p < 0.01). The Nah gene was distributed relatively evenly among sampling zones, ranging between 1.9 × 107 and 1.1 × 108 copies/g dm soil, and was negatively correlated with concentrations of total aromatic hydrocarbons (TAH) (R2 = -0.567, p = 0.035) and ∑16 PAHs (R2 = -0.599, p = 0.023). Results of a factor analysis showed that individual samples of soils were not ordinated as a function of the zones.

  7. Distribution of petroleum degrading genes and factor analysis of petroleum contaminated soil from the Dagang Oilfield, China

    PubMed Central

    Liu, Qinglong; Tang, Jingchun; Bai, Zhihui; Hecker, Markus; Giesy, John P.

    2015-01-01

    Genes that encode for enzymes that can degrade petroleum hydrocarbons (PHs) are critical for the ability of microorganisms to bioremediate soils contaminated with PHs. Distributions of two petroleum-degrading genes AlkB and Nah in soils collected from three zones of the Dagang Oilfield, Tianjin, China were investigated. Numbers of copies of AlkB ranged between 9.1 × 105 and 1.9 × 107 copies/g dry mass (dm) soil, and were positively correlated with total concentrations of PHs (TPH) (R2 = 0.573, p = 0.032) and alkanes (C33 ~ C40) (R2 = 0.914, p < 0.01). The Nah gene was distributed relatively evenly among sampling zones, ranging between 1.9 × 107 and 1.1 × 108 copies/g dm soil, and was negatively correlated with concentrations of total aromatic hydrocarbons (TAH) (R2 = −0.567, p = 0.035) and ∑16 PAHs (R2 = −0.599, p = 0.023). Results of a factor analysis showed that individual samples of soils were not ordinated as a function of the zones. PMID:26086670

  8. North Alaska petroleum analysis: the regional map compilation

    USGS Publications Warehouse

    Saltus, Richard W.; Bird, Kenneth J.

    2003-01-01

    The U.S. Geological Survey initiated an effort to model north Alaskan petroleum systems. The geographic and geologic basis for modeling systems is provided by a set of regional digital maps that allow evaluation of the widest possible extent of each system. Accordingly, we laid out a rectangular map grid 1300 km (800 miles) east-west and 600 km (375 miles) north-south. The resulting map area extends from the Yukon Territory of Canada on the east to the Russian-U.S. Chukchi Sea on the west and from the Brooks Range on the south to the Canada basin-Chukchi borderland on the north. Within this map region, we combined disparate types of publicly available data to produce structure contour maps. Data types range from seismic-based mapping as in the National Petroleum Reserve to well penetrations in areas of little or no seismic data where extrapolation was required. With these types of data, we produced structure contour maps on three horizons: top of pre-Mississippian (basement), top of Triassic (Ellesmerian sequence), and top of Neocomian (Beaufortian sequence). These horizons, when combined with present-day topography and bathymetry, provide the bounding structural/stratigraphic surfaces of the north Alaskan petroleum province that mark major defining moments of the region's geologic history and allow regional portrayal of preserved sediment accumulations.

  9. Molecular analysis of the microbial community structures in water-flooding petroleum reservoirs with different temperatures

    NASA Astrophysics Data System (ADS)

    Wang, L.-Y.; Duan, R.-Y.; Liu, J.-F.; Yang, S.-Z.; Gu, J.-D.; Mu, B.-Z.

    2012-11-01

    Analyses of microbial communities from six water-flooding petroleum reservoirs at temperatures from 21 to 63 °C by 16S rRNA gene clone libraries indicates the presence of physiologically diverse and temperature-dependent microorganisms in these subterrestrial ecosystems. In samples originating from high-temperature petroleum reservoirs, most of the archaeal sequences belong to thermophiles affiliated with members of the genera Thermococcus, Methanothermobacter and the order Thermoplasmatales, whereas bacterial sequences predominantly belong to the phyla Firmicutes, Thermotogae and Thermodesulfobacteria. In contrast to high-temperature petroleum reservoirs, microorganisms belonging to the Proteobacteria, Methanobacteriales and Methanomicrobiales were the most encountered in samples collected from low-temperature petroleum reservoirs. Canonical correspondence analysis (CCA) revealed that temperature, mineralization, ionic type as well as volatile fatty acids showed correlation with the microbial community structures, in particular members of the Firmicutes and the genus Methanothermobacter showed positive correlation with temperature and the concentration of acetate. Overall, these data indicate the large occurrence of hydrogenotrophic methanogens in petroleum reservoirs and imply that acetate metabolism via syntrophic oxidation may represent the main methanogenic pathway in high-temperature petroleum reservoirs.

  10. Analysis and stability of mercury speciation in petroleum hydrocarbons.

    PubMed

    Bloom, N S

    2000-03-01

    Raw petroleum and natural gas often contain high concentrations of mercury, which can be damaging to the metal components of production facilities, as well as to the environment. Various Hg species have different properties in terms of mobility, reactivity and bioavailability. Thus, for cost-effective decisions regarding plant design, Hg extraction, and pollution control, speciation information must be available at the production facility. In this paper, a simple, wet chemical speciation method, which provides data on Hg(o), dissolved and particulate total Hg, Hg(II), and methyl Hg is presented. The method incorporates species-specific extraction and separation procedures, followed by cold vapor atomic fluorescence spectrometry (CVAFS). For each species, detection limits of approximately 0.1 ng/g were obtained. Storage experiments in various containers showed that organo-mercury species were stable for at least 30 days in all containers except those made of polyethylene; and Hg(o) was stable in all containers except those made of stainless steel or polyethylene. Hg(II) was rapidly lost from all containers except those made of aluminum, which rapidly converted it to Hg(o), which was stable. In general, most of the total Hg in petroleum products was particulate Hg, followed by dissolved Hg(II) and Hg(o). Sub-ng/g concentrations of methyl-Hg were observed in most samples.

  11. Regional seismic lines reprocessed using post-stack processing techniques; National Petroleum Reserve, Alaska

    USGS Publications Warehouse

    Miller, John J.; Agena, W.F.; Lee, M.W.; Zihlman, F.N.; Grow, J.A.; Taylor, D.J.; Killgore, Michele; Oliver, H.L.

    2000-01-01

    This CD-ROM contains stacked, migrated, 2-Dimensional seismic reflection data and associated support information for 22 regional seismic lines (3,470 line-miles) recorded in the National Petroleum Reserve ? Alaska (NPRA) from 1974 through 1981. Together, these lines constitute about one-quarter of the seismic data collected as part of the Federal Government?s program to evaluate the petroleum potential of the Reserve. The regional lines, which form a grid covering the entire NPRA, were created by combining various individual lines recorded in different years using different recording parameters. These data were reprocessed by the USGS using modern, post-stack processing techniques, to create a data set suitable for interpretation on interactive seismic interpretation computer workstations. Reprocessing was done in support of ongoing petroleum resource studies by the USGS Energy Program. The CD-ROM contains the following files: 1) 22 files containing the digital seismic data in standard, SEG-Y format; 2) 1 file containing navigation data for the 22 lines in standard SEG-P1 format; 3) 22 small scale graphic images of each seismic line in Adobe Acrobat? PDF format; 4) a graphic image of the location map, generated from the navigation file, with hyperlinks to the graphic images of the seismic lines; 5) an ASCII text file with cross-reference information for relating the sequential trace numbers on each regional line to the line number and shotpoint number of the original component lines; and 6) an explanation of the processing used to create the final seismic sections (this document). The SEG-Y format seismic files and SEG-P1 format navigation file contain all the information necessary for loading the data onto a seismic interpretation workstation.

  12. Evaluation Of In Situ Steam-Injection Processes For Reduction Of Petroleum Compounds Within An Abandoned Canal

    EPA Science Inventory

    A conceptual approach of a novel application of in-situ thermal processes that would either use a steam injection process or a steam/surfactant injection process was considered to remediate petroleum contaminated sediment residing in an abandoned canal. Laboratory tests were c...

  13. U.S. strategic petroleum reserve Big Hill 114 leak analysis 2012.

    SciTech Connect

    Lord, David L.; Roberts, Barry L.; Lord, Anna C. Snider; Sobolik, Steven Ronald; Park, Byoung Yoon; Rudeen, David Keith

    2013-06-01

    This report addresses recent well integrity issues related to cavern 114 at the Big Hill Strategic Petroleum Reserve site. DM Petroleum Operations, M&O contractor for the U.S. Strategic Petroleum Reserve, recognized an apparent leak in Big Hill cavern well 114A in late summer, 2012, and provided written notice to the State of Texas as required by law. DM has since isolated the leak in well A with a temporary plug, and is planning on remediating both 114 A- and B-wells with liners. In this report Sandia provides an analysis of the apparent leak that includes: (i) estimated leak volume, (ii) recommendation for operating pressure to maintain in the cavern between temporary and permanent fixes for the well integrity issues, and (iii) identification of other caverns or wells at Big Hill that should be monitored closely in light of the sequence of failures there in the last several years.

  14. Molecular Biological Analysis of Microorganisms in Petroleum Reservoirs

    NASA Astrophysics Data System (ADS)

    Ko, J.; Son, H. A.; Im, K. C.; Back, K. H.; Kim, H. T.

    2014-12-01

    Microorganisms in petroleum reservoirs were analyzed to examine the potential to apply for microbial enhanced oil recovery (MEOR). Genomic DNA (16S rDNA) were extracted from two heavy oil samples from Canadian oil sand and six light oil samples from the Salin fore-arc basin in Myanmar, and amplified using a polymerase chain reaction (PCR) method. The microbes were identified by cloning the PCR products and pyrosequencing. Actinobacteria, Firmicutes, and Proteobacteria were common in both Canadian and Myanmar samples. Staphylococcus and Streptococcus belonging to the Firmicutes phylum are abundant in oil sands, while Propionibacteria belonging to the Actinobacteria phylum and Coprothermobacter, Streptococcus, and Clostridia belonging to the Frimicutes phylum are contained in Myanmar samples. Streptococcus is known to use crude oil as nutrient, and produce organic acid, bio-gas and polysaccharide that could reduce oil viscosity, improve permeability by dissolving carbonate cement from pores throat, and reduce interfacial tension between oil and rock/water surface. Clostridia produce acids and gases by methanogenesis that could improve oil recovery.

  15. Probabilistic methodology for estimation of undiscovered petroleum resources in play analysis of the United States

    USGS Publications Warehouse

    Crovelli, R.A.

    1992-01-01

    A geostochastic system called FASPF was developed by the U.S. Geological Survey for their 1989 assessment of undiscovered petroleum resources in the United States. FASPF is a fast appraisal system for petroleum play analysis using a field-size geological model and an analytic probabilistic methodology. The geological model is a particular type of probability model whereby the volumes of oil and gas accumulations are modeled as statistical distributions in the form of probability histograms, and the risk structure is bilevel (play and accumulation) in terms of conditional probability. The probabilistic methodology is an analytic method derived from probability theory rather than Monte Carlo simulation. The resource estimates of crude oil and natural gas are calculated and expressed in terms of probability distributions. The probabilistic methodology developed by the author is explained. The analytic system resulted in a probabilistic methodology for play analysis, subplay analysis, economic analysis, and aggregation analysis. Subplay analysis included the estimation of petroleum resources on non-Federal offshore areas. Economic analysis involved the truncation of the field size with a minimum economic cutoff value. Aggregation analysis was needed to aggregate individual play and subplay estimates of oil and gas, respectively, at the provincial, regional, and national levels. ?? 1992 Oxford University Press.

  16. Process for removing halogenated aliphatic and aromatic compounds from petroleum products. [Polychlorinated biphenyls; methylene chloride; perchloroethylene; trichlorofluoroethane; trichloroethylene; chlorobenzene

    DOEpatents

    Googin, J.M.; Napier, J.M.; Travaglini, M.A.

    1982-03-31

    A process for removing halogenated aliphatic and aromatic compounds, e.g., polychlorinated biphenyls, from petroleum products by solvent extraction. The halogenated aliphatic and aromatic compounds are extracted from a petroleum product into a polar solvent by contracting the petroleum product with the polar solvent. The polar solvent is characterized by a high solubility for the extracted halogenated aliphatic and aromatic compounds, a low solubility for the petroleum product and considerable solvent power for polyhydroxy compound. The preferred polar solvent is dimethylformamide. A miscible polyhydroxy compound, such as, water, is added to the polar extraction solvent to increase the polarity of the polar extraction solvent. The halogenated aliphatic and aromatic compounds are extracted from the highly-polarized mixture of polyhydroxy compound and polar extraction solvent into a low polar or nonpolar solvent by contacting the polyhydroxy compound-polar solvent mixture with the low polar or nonpolar solvent. The halogenated aliphatic and aromatic compounds in the low polar or nonpolar solvent by physical means, e.g., vacuum evaporation. The polar and nonpolar solvents are recovered for recycling. The process can easily be designed for continuous operation. Advantages of the process include that the polar solvent and a major portion of the nonpolar solvent can be recycled, the petroleum products are reclaimable and the cost for disposing of waste containing polychlorinated biphenyls is significantly reduced. 2 tables.

  17. Compound-specific carbon and hydrogen isotope analysis of sub-parts per billion level waterborne petroleum hydrocarbons

    USGS Publications Warehouse

    Wang, Y.; Huang, Y.; Huckins, J.N.; Petty, J.D.

    2004-01-01

    Compound-specific carbon and hydrogen isotope analysis (CSCIA and CSHIA) has been increasingly used to study the source, transport, and bioremediation of organic contaminants such as petroleum hydrocarbons. In natural aquatic systems, dissolved contaminants represent the bioavailable fraction that generally is of the greatest toxicological significance. However, determining the isotopic ratios of waterborne hydrophobic contaminants in natural waters is very challenging because of their extremely low concentrations (often at sub-parts ber billion, or even lower). To acquire sufficient quantities of polycyclic aromatic hydrocarbons with 10 ng/L concentration for CSHIA, more than 1000 L of water must be extracted. Conventional liquid/liquid or solid-phase extraction is not suitable for such large volume extractions. We have developed a new approach that is capable of efficiently sampling sub-parts per billion level waterborne petroleum hydrocarbons for CSIA. We use semipermeable membrane devices (SPMDs) to accumulate hydrophobic contaminants from polluted waters and then recover the compounds in the laboratory for CSIA. In this study, we demonstrate, under a variety of experimental conditions (different concentrations, temperatures, and turbulence levels), that SPMD-associated processes do not induce C and H isotopic fractionations. The applicability of SPMD-CSIA technology to natural systems is further demonstrated by determining the ??13C and ??D values of petroleum hydrocarbons present in the Pawtuxet River, RI. Our results show that the combined SPMD-CSIA is an effective tool to investigate the source and fate of hydrophobic contaminants in the aquatic environments.

  18. Analysis of cavern shapes for the strategic petroleum reserve.

    SciTech Connect

    Ehgartner, Brian L.; Sobolik, Steven Ronald

    2006-07-01

    This report presents computational analyses to determine the structural integrity of different salt cavern shapes. Three characteristic shapes for increasing cavern volumes are evaluated and compared to the baseline shape of a cylindrical cavern. Caverns with enlarged tops, bottoms, and mid-sections are modeled. The results address pillar to diameter ratios of some existing caverns in the system and will represent the final shape of other caverns if they are repeatedly drawn down. This deliverable is performed in support of the U.S. Strategic Petroleum Reserve. Several three-dimensional models using a close-packed arrangement of 19 caverns have been built and analyzed using a simplified symmetry involving a 30-degree wedge portion of the model. This approach has been used previously for West Hackberry (Ehgartner and Sobolik, 2002) and Big Hill (Park et al., 2005) analyses. A stratigraphy based on the Big Hill site has been incorporated into the model. The caverns are modeled without wells and casing to simplify the calculations. These calculations have been made using the power law creep model. The four cavern shapes were evaluated at several different cavern radii against four design factors. These factors included the dilatant damage safety factor in salt, the cavern volume closure, axial well strain in the caprock, and surface subsidence. The relative performance of each of the cavern shapes varies for the different design factors, although it is apparent that the enlarged bottom design provides the worst overall performance. The results of the calculations are put in the context of the history of cavern analyses assuming cylindrical caverns, and how these results affect previous understanding of cavern behavior in a salt dome.

  19. Practical petroleum geology

    SciTech Connect

    Not Available

    1985-01-01

    This book presents the scope and content of the field of petroleum geology from the standpoint of the practicing petroleum geologist. Includes chapters on basic geological concepts, the sedimentation process, accumulation of hydrocarbons, exploration, economic examination, drilling of exploratory wells, recovering oil and gas (reservoir geology), and the relationship of geology to the petroleum industry as a whole.

  20. Electrical CT image reconstruction technique for powder flow in petroleum refinery process

    NASA Astrophysics Data System (ADS)

    Takei, Masahiro; Doh, Deog-Hee; Ochi, Mitsuaki

    2008-03-01

    A new reconstruction method called sampled pattern matching (SPM) was applied to the image reconstruction of an electrical capacitance computed tomography in powder flow in a vertical pipe for petroleum refinery process. This new method is able to achieve stable convergence without the use of an empirical value. Experiments were carried out using fluid catalytic cracking (FCC) catalysts as powder with two air volume flow rates and four powder volume flow rates to measure the capacitance of a pipe cross section. The SPM method is compared with conventional methods in terms of volume fraction, residual capacitance, and correlation capacitance. Overall, the SPM method proved superior to conventional methods without any empirical value because SPM achieves accurate reconstruction by using an objective function that is calculated as the inner product calculation between the experimental capacitance and the reconstructed image capacitance.

  1. Petroleum refinery secondary effluent polishing using freezing processes--toxicity and organic contaminant removal.

    PubMed

    Gao, W; Smith, D W; Habib, M

    2008-06-01

    A petroleum refinery secondary effluent was treated using two freezing techniques--spray freezing and unidirectional downward freezing (UDF). The freezing processes were effective to remove toxicity and total organic carbon (TOC)- and chemical oxygen demand (COD)-causing materials in the effluent. Agitation of the liquid during UDF significantly improved the impurity separation efficiency; 85 to 96% removal of TOC and COD was achieved without any pretreatment and freezing only 70% of the feed water. The treatment efficiency of the spray freezing was at the same level as that of UDF without mixing. The spray ice with longer storage time released more contaminants with early meltwater. The initial contaminant concentration of the feed water and the freezing temperatures (-10 degrees C and -25 degrees C) had no significant influence on the treatment efficiency. A small fluctuation in effluent TOC concentration caused a dramatic change in effluent toxicity (Microtox). The effective concentration (EC20) (Microtox) was effective in detecting effluent toxicity. PMID:18686927

  2. GC/GCMS analysis of the petroleum ether and dichloromethane extracts of Moringa oleifera roots

    PubMed Central

    Faizi, Shaheen; Sumbul, Saima; Versiani, Muhammed Ali; Saleem, Rubeena; Sana, Aisha; Siddiqui, Hira

    2014-01-01

    Objective To explore the phytochemical constituents from petroleum ether and dichloromethane extracts of Moringa oleifera (M. oleifera) roots using GC/GC-MS. Methods A total of 5.11 kg fresh and undried crushed root of M. oleifera were cut into small pieces and extracted with petroleum ether and dichloromethane (20 L each) at room temperature for 2 d. The concentrated extracts were subjected to their GC-MS analysis. Results The GC-MS analysis of the petroleum ether and dichloromethane extracts of M. oleifera roots, which showed promising biological activities, has resulted in the identification 102 compounds. These constituents belong to 15 classes of compounds including hydrocarbons, fatty acids, esters, alcohols, isothiocyanate, thiocyanate, pyrazine, aromatics, alkamides, cyanides, steroids, halocompounds, urea and N-hydroxyimine derivatives, unsaturated alkenamides, alkyne and indole. GC/GC-MS studies on petroleum ether extract of the roots revealed that it contained 39 compounds, belonging to nine classes. Cyclooctasulfur S8 has been isolated as a pure compound from the extract. The major compounds identified from petroleum ether extract were trans-13-docosene (37.9%), nonacosane (32.6%), cycloartenol (28.6%) nonadecanoic acid (13.9%) and cyclooctasulfur S8 (13.9%). Dichloromethane extract of the roots was composed of 63 compounds of which nasimizinol (58.8%) along with oleic acid (46.5%), N-benzyl-N-(7-cyanato heptanamide (38.3%), N-benzyl-N-(1-chlorononyl) amide (30.3%), bis [3-benzyl prop-2-ene]-1-one (19.5%) and N, N-dibenzyl-2-ene pent 1, 5-diamide (11.6%) were the main constituents. Conclusions This study helps to predict the formula and structure of active molecules which can be used as drugs. This result also enhances the traditional usage of M. oleifera which possesses a number of bioactive compounds. PMID:25183335

  3. Dynamic processes of indigenous microorganisms from a low-temperature petroleum reservoir during nutrient stimulation.

    PubMed

    Gao, Pei-Ke; Li, Guo-Qiang; Zhao, Ling-Xia; Dai, Xue-Cheng; Tian, Hui-Mei; Dai, Liu-Bing; Wang, Hong-Bo; Huang, Hai-Dong; Chen, Yue-Hua; Ma, Ting

    2014-02-01

    Compared to medium-high temperature petroleum reservoirs (30°C-73°C), little is known about microbial regulation by nutrients in low-temperature reservoirs. In this study, we report the performance (oil emulsification and biogas production) and community structure of indigenous microorganisms from a low-temperature (22.6°C) petroleum reservoir during nutrient stimulation. Culture-dependent approaches indicated that the number of hydrocarbon-oxidizing bacteria (HOB), nitrate-reducing bacteria (NRB) and methane-producing bacteria (MPB) increased by between 10- and 1000-fold, while sulfate-reducing bacteria (SRB) were observed at low levels during stimulation. Phylogenetic analysis of the 16S rRNA gene indicated that Pseudomonas, Ochrobactrum, Acinetobacter, Halomonas and Marinobacter, which have the capability to produce surfactants, were selectively enriched. Methanoculleus, Methanosaeta, Methanocorpusculum and Methanocalculus showed the largest increase in relative abundance among archaea. Micro-emulsion formed with an average oil droplet diameter of 14.3 μm (ranging between 4.1 μm and 84.2 μm) during stimulation. Gas chromatographic analysis of gas production (186 mL gas/200 mL medium) showed the levels of CO2 and CH4 increased 8.97% and 6.21%, respectively. Similar to medium-high temperature reservoirs, HOB, NRB, SRB and MPB were ubiquitous in the low-temperature reservoir, and oil emulsification and gas production were the main phenomena observed during stimulation. Oil emulsification required a longer duration of time to occur in the low-temperature reservoir.

  4. Petroleum supply monthly, April 1994

    SciTech Connect

    Not Available

    1994-04-01

    Data presented in the Petroleum Supply Monthly (PSM) describe the supply and disposition of petroleum products in the United States and major US geographical regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the US. The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the US.

  5. Precise measurement of liquid petroleum tank volume based on data cloud analysis

    NASA Astrophysics Data System (ADS)

    Wang, Jintao; Liu, Ziyong; Zhang, Long; Guo, Ligong; Bao, Xuesong; Tong, Lin

    2010-08-01

    Metal tanks are generally used for the measurement of liquid petroleum products for fiscal or custody transfer application. One tank volume precise measurement method based on data cloud analysis was studied, which was acquired by laser scanning principle. Method of distance measurement by laser phase shift and angular measurement by optical grating were applied to acquire coordinates of points in tank shell under the control of a servo system. Direct Iterative Method (DIM) and Section Area Method (SAM) were used to process measured data for vertical and horizontal tanks respectively. In comparison experiment, one 1000m3 vertical tank and one 30m3 horizontal tank were used as test objects. In the vertical tank experiment, the largest measured radius difference between the new laser method and strapping method (international arbitrary standard) is 2.8mm. In the horizontal tank experiment, the calibration result from laser scanning method is more close to reference than manual geometric method, and the mean deviation in full-scale range of the former and latter method are 75L and 141L respectively; with the increase of liquid level, the relative errors of laser scanning method and manual geometric method become smaller, and the mean relative errors are 0.6% and 1.5% respectively. By using the method discussed, the calibration efficiency of tank volume can be improved.

  6. Forest fire situation analysis over forest reserve land in Tomsk petroleum province

    NASA Astrophysics Data System (ADS)

    Pasko, O. A.; Baranova, A. V.

    2015-02-01

    The paper delivers the analysis of space-time characteristics of forest fire ignition and spread in the North of Tomsk oblast, i.e. petroleum production area (Kargasok, Parabel and Teguldet districts). It also presents long-term and seasonal forest fire behavior including fire ignition and spread frequency (annual and seasonal), the fire season duration and their zonality. The main driving factors of forest fire ignition both human and natural ones are revealed.

  7. Basin Analysis of Mississippi Interior Salt Basin and Petroleum System Modeling of the Jurassic Smackover Formation, Eastern Gulf Coastal Plain

    SciTech Connect

    Ernest Mancini

    2001-03-01

    Part 3 (Petroleum System Modeling of the Jurassic Smackover Formation) objectives are to provide an analysis of the Smackover petroleum system in Years 4 and 5 of the project and to transfer effectively the research results to producers through workshops and topical reports. Work Accomplished (Year 5): Task 1 - Basin Flow - Basin flow modeling has been completed and the topical report has been submitted to the U.S. DOE for review. Task 2 - Petroleum Source Rocks - Work on the characterization of Smackover petroleum source rocks has been integrated into the basin flow model. The information on the source rocks is being prepared for inclusion in the final report. Task 3 - Petroleum Reservoirs - Work on the characterization of Smackover petroleum reservoirs continues. The cores to be described have been identified and many of the cores for the eastern and western parts of the basin have been described. Task 4 - Reservoir Diagenesis - Work on reservoir diagenesis continues. Samples from the cores selected for the reservoir characterization are being used for this task. Task 5 - Underdeveloped Reservoirs - Two underdeveloped Smackover reservoirs have been identified. They are the microbial reef and shoal reservoirs. Work Planned (Year 5): Task 1 - Basin Flow - This task has been completed and the topical report has been submitted to the U.S. DOE. Task 2 - Petroleum Source Rocks - Petroleum source rock information will continue to be prepared for the final report. Task 3 - Petroleum Reservoirs - Characterization of petroleum reservoirs will continue through core studies. Task 4 - Reservoir Diagenesis - Characterization of reservoir diagenesis will continue through petrographic analysis. Task 5 - Underdeveloped Reservoirs - Study of Smackover underdeveloped reservoirs will continue with focus on the microbial reef and shoal reservoirs.

  8. [Phytoremediation of Petroleum Contaminated Soils with Iris pseudacorus L. and the Metabolic Analysis in Roots].

    PubMed

    Wang, Ya-nan; Cheng, Li-juan; Zhou, Qi-xing

    2016-04-15

    In this study, we performed a greenhouse pot-culture experiment to investigate the potential of a wild ornamental plant Iris pseudacorus L. in remediating petroleum contaminated soils from the Dagang Oilfield in Tianjin, China. The results suggested that Iris pseudacorus L. had great resistance to ≤ 40,000 mg · kg(⁻¹ of total petroleum hydrocarbons (TPHs). The removal rate of TPHs with concentrations of 10,000 mg · kg⁻¹, 20,000 mg · kg⁻¹ and 40,000 mg · kg⁻¹ in soils by Iris pseudacorus L. was 42.1%, 33.1% 31.2%, respectively, much higher than those in the corresponding controls (31.8%, 21.3% 11.9%, respectively) (P < 0.05). The root specific surface area of Iris pseudacorus L. was determined by the root scanner. The results suggested that TPHs with concentrations of 10,000 mg · kg⁻¹, 20,000 mg · kg⁻¹ and 40,000 mg · kg⁻¹ in soils increased the root specific surface area comparing with the controls. Additionally, the metabolic analysis showed that root metabolism changed to different degrees under the stress of TPHs, and the levels or species of metabolites had a significant change (P < 0.001). Furthermore, the results showed that 5 of 11 metabolites (VIP value > 1.2) with the root specific surface area from the PLS-DA model analysis, including ethanedioic acid, lactic acid, 2-butenedioic acid, phosphate and propanedioic acid, were positively correlated with the root specific surface area, but the others, gluconic acid, uridine, butanoic acid, maltose, 9,12-octadecadienoic acid, phenylalanine, were negatively correlated with it. In conclusion, using Iris pseudacorus L. to remediate petroleum contaminated soils is feasible, and the metabolic analysis in roots is useful to better understand the metabolic response of plants exposure to petroleum contaminated soils, and then reveals its remediated mechanisms.

  9. Analysis of Multi-Arm Caliper Data for the U.S. Strategic Petroleum Reserve

    SciTech Connect

    Roberts, Barry L.

    2015-03-01

    The U.S. Strategic Petroleum Reserve (SPR) has an increasing reliance on mul t i - arm caliper surveys to assess the integrity of casing for cavern access wells and to determine priorities for casing remediation. Multi - arm caliper (MAC) surveys provide a view of well casing deformation by reporting radial measurements of the inner cas ing wall as the tool is drawn through the casing. Over the last several years the SPR has collected a large number of modern MAC surveys. In total, these surveys account for over 100 million individual measurements. The surveys were collected using diff ering survey vendors and survey hardware. This has resulted in a collection of disparate data sets which confound attempts to make well - to - well or time - dependent evaluations. In addition, the vendor supplied MAC interpretations often involve variables wh ich are not well defined or which may not be applicable to casings for cavern access wells. These factors reduce the usability of these detailed data sets. In order to address this issue and provide an independent analysis of multi - arm caliper survey data, Sandia National Labs has developed processing techniques and analysis variables which allow for the comparison of MAC survey data regardless of the source of the survey data. These techniques use the raw radial arm information and newly developed analysis variables to assess the casing status and provide a means for well - to - well and time - dependent analyses. Well - to - well and t ime - dependent investigation of the MAC survey data provide s information to prioritize well remediation activities and identify wells with integrity issues. This paper presents the challenges in using disparate MAC survey data, techniques developed to address these challenges and some o f the insights gained from these new techniques.

  10. NASA Hazard Analysis Process

    NASA Technical Reports Server (NTRS)

    Deckert, George

    2010-01-01

    This viewgraph presentation reviews The NASA Hazard Analysis process. The contents include: 1) Significant Incidents and Close Calls in Human Spaceflight; 2) Subsystem Safety Engineering Through the Project Life Cycle; 3) The Risk Informed Design Process; 4) Types of NASA Hazard Analysis; 5) Preliminary Hazard Analysis (PHA); 6) Hazard Analysis Process; 7) Identify Hazardous Conditions; 8) Consider All Interfaces; 9) Work a Preliminary Hazard List; 10) NASA Generic Hazards List; and 11) Final Thoughts

  11. Prebiotic petroleum.

    PubMed

    Ali, Mekki-Berrada

    2014-12-01

    This short communication summarizes a global and continuous reflection on the origins of life. "Prebiotic Petroleum" assumes that "the class of most complex molecules of life that may have geochemical and abiotic origin is the class of fatty acids with long aliphatic chains" and proposes a physical process for the formation of liposomes. Developments following the workshop start from the idea that the liposomes also acquire ion exchange channels physically during their forming process. PMID:25743765

  12. An analysis of increasing the size of the strategic petroleum reserve to one billion barrels

    SciTech Connect

    Not Available

    1990-01-01

    The Department of Energy's Office of Energy Emergency Policy and Evaluation requested that the Energy Information Administration complete an analysis of the proposed expansion in the Strategic Petroleum Reserve (SPR) from its currently planned size of 750 million barrels to 1000 million barrels. Because the SPR contains only 580 million barrels at this point in time, the benefits and costs of increasing the SPR from 600 to 750 million barrels were also estimated. This report documents the assumptions, methodology, and results of the analysis. 17 figs., 15 tabs.

  13. Petroleum supply monthly, January 1994

    SciTech Connect

    Not Available

    1994-01-01

    Data presented describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States. The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States.

  14. Petroleum supply monthly, February 1994

    SciTech Connect

    Not Available

    1994-03-01

    The Petroleum Supply Monthly presents data describing the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the US. The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders; operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. Data are divided into two sections: Summary statistics and Detailed statistics.

  15. Optimization of ferric hydroxide coprecipitation process for selenium removal from petroleum refinery stripped four water

    SciTech Connect

    Gerhardt, M.B.; Marrs, D.R.; Roehl, R.

    1996-12-31

    Iron coprecipitation was used in bench-scale tests to remove selenium from stripped sour water generated by two petroleum refineries. Chlorine dioxide and hydrogen peroxide were found to convert selenocyanate in the stripped sour water to selenite, which can be removed by iron coprecipitation. An iodometric titration procedure was developed to determine the required oxidant dose. Iron coprecipitation reduced selenium concentrations by 40 to 99 percent in stripped sour water after chlorine dioxide pretreatment Removal was less effective with hydrogen peroxide as the oxidant: total selenium concentrations were reduced by 28 to 92 percent in stripped sour water after hydrogen peroxide pretreatment. Highest removals were obtained at the highest oxidant and iron doses. Sludges produced in coprecipitation tests were hazardous under California regulations. Ozone oxidized selenocyanate but prevented ferric hydroxide precipitation or coagulation. Air was ineffective at selenocyanate oxidation. Repeatedly contacting iron hydroxide with stripped sour water pretreated with hydrogen peroxide, in a simulation of a countercurrent adsorption process, increased the selenium adsorbed on the solids from 32 to 147 pg selenium per mg of iron, but some of the adsorbed selenite was oxidized to selenate and desorbed back into solution.

  16. Petroleum marketing annual 1994

    SciTech Connect

    1995-08-24

    The Petroleum Marketing Annual (PMA) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysis, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the fob and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Annual. For this production, all estimates have been recalculated since their earlier publication in the Petroleum Marketing Monthly (PMM). These calculations made use of additional data and corrections that were received after the PMM publication date.

  17. Petroleum supply monthly

    SciTech Connect

    1995-10-01

    The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blends, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States.

  18. Petroleum Supply Monthly

    SciTech Connect

    1996-02-01

    The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major U.S. geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics.

  19. Petroleum supply monthly, August 1993

    SciTech Connect

    Not Available

    1993-09-01

    This publication the Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report, (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. Data presented are divided into Summary Statistics and Detailed Statistics.

  20. Application of high-temperature simulated distillation to the residuum oil supercritical extraction process in petroleum refining

    PubMed

    Raia; Villalanti; Subramanian; Williams

    2000-01-01

    The gas chromatographic method of high-temperature simulated distillation (HTSD) is described, and the results are presented for the application of HTSD to the characterization of petroleum refinery feed and products from solvent deasphalting operations. Results are presented for refinery residual feed, deasphalted oil, and asphaltene fractions from the residual oil supercritical extraction process. Asphaltene removal from petroleum residuum using solvent deasphalting results in the improved quality and high recovery of deasphalted oil product for use as lube oil, fluid catalytic cracking, or hydrocracker feedstocks. The HTSD procedure presented here proves valuable for characterizing the fractions from the deasphalting process to obtain the percentage yield with boiling point data over the range from approximately 36 degrees C (97 degrees F) to 733 degrees C (1352 degrees F), which covers the boiling range of n-paraffins of carbon number C5 to C108.

  1. Biological treatment process for removing petroleum hydrocarbons from oil field produced waters

    SciTech Connect

    Tellez, G.; Khandan, N.

    1995-12-31

    The feasibility of removing petroleum hydrocarbons from oil fields produced waters using biological treatment was evaluated under laboratory and field conditions. Based on previous laboratory studies, a field-scale prototype system was designed and operated over a period of four months. Two different sources of produced waters were tested in this field study under various continuous flow rates ranging from 375 1/D to 1,800 1/D. One source of produced water was an open storage pit; the other, a closed storage tank. The TDS concentrations of these sources exceeded 50,000 mg/l; total n-alkanes exceeded 100 mg/l; total petroleum hydrocarbons exceeded 125 mg/l; and total BTEX exceeded 3 mg/l. Removals of total n-alkanes, total petroleum hydrocarbons, and BTEX remained consistently high over 99%. During these tests, the energy costs averaged $0.20/bbl at 12 bbl/D.

  2. Polyphasic microbial community analysis of petroleum hydrocarbon-contaminated soils from two northern Canadian communities.

    PubMed

    Juck; Charles; Whyte; Greer

    2000-09-01

    The cold-adapted bacterial communities in petroleum hydrocarbon-contaminated and non-impacted soils from two northern Canadian environments, Kuujjuaq, Que., and Alert, Nunavut, were analyzed using a polyphasic approach. Denaturing gradient gel electrophoresis (DGGE) separation of 16S rDNA PCR fragments from soil total community DNA revealed a high level of bacterial diversity, as estimated by the total number of bands visualized. Dendrogram analysis clustered the sample sites on the basis of geographical location. Comparison of the overall microbial molecular diversity suggested that in the Kuujjuaq sites, contamination negatively impacted diversity whereas in the Alert samples, diversity was maintained or increased as compared to uncontaminated controls. Extraction and sequencing analysis of selected 16S rDNA bands demonstrated a range of similarity of 86-100% to reference organisms, with 63.6% of the bands representing high G+C Gram-positive organisms in the order Actinomycetales and 36.4% in the class Proteobacteria. Community level physiological profiles generated using Biolog GN plates were analyzed by cluster analysis. Based on substrate oxidation rates, the samples clustered into groups similar to those of the DGGE dendrograms, i.e. separation based upon geographic origin. The coinciding results reached using culture-independent and -dependent analyses reinforces the conclusion that geographical origin of the samples, rather than petroleum contamination level, was more important in determining species diversity within these cold-adapted bacterial communities.

  3. [Phytoremediation of Petroleum Contaminated Soils with Iris pseudacorus L. and the Metabolic Analysis in Roots].

    PubMed

    Wang, Ya-nan; Cheng, Li-juan; Zhou, Qi-xing

    2016-04-15

    In this study, we performed a greenhouse pot-culture experiment to investigate the potential of a wild ornamental plant Iris pseudacorus L. in remediating petroleum contaminated soils from the Dagang Oilfield in Tianjin, China. The results suggested that Iris pseudacorus L. had great resistance to ≤ 40,000 mg · kg(⁻¹ of total petroleum hydrocarbons (TPHs). The removal rate of TPHs with concentrations of 10,000 mg · kg⁻¹, 20,000 mg · kg⁻¹ and 40,000 mg · kg⁻¹ in soils by Iris pseudacorus L. was 42.1%, 33.1% 31.2%, respectively, much higher than those in the corresponding controls (31.8%, 21.3% 11.9%, respectively) (P < 0.05). The root specific surface area of Iris pseudacorus L. was determined by the root scanner. The results suggested that TPHs with concentrations of 10,000 mg · kg⁻¹, 20,000 mg · kg⁻¹ and 40,000 mg · kg⁻¹ in soils increased the root specific surface area comparing with the controls. Additionally, the metabolic analysis showed that root metabolism changed to different degrees under the stress of TPHs, and the levels or species of metabolites had a significant change (P < 0.001). Furthermore, the results showed that 5 of 11 metabolites (VIP value > 1.2) with the root specific surface area from the PLS-DA model analysis, including ethanedioic acid, lactic acid, 2-butenedioic acid, phosphate and propanedioic acid, were positively correlated with the root specific surface area, but the others, gluconic acid, uridine, butanoic acid, maltose, 9,12-octadecadienoic acid, phenylalanine, were negatively correlated with it. In conclusion, using Iris pseudacorus L. to remediate petroleum contaminated soils is feasible, and the metabolic analysis in roots is useful to better understand the metabolic response of plants exposure to petroleum contaminated soils, and then reveals its remediated mechanisms. PMID:27548979

  4. Method for recovering petroleum

    SciTech Connect

    Coenen, H.; Kriegel, E.

    1985-08-06

    A process for recovering petroleum from deposits which have already been worked by primary extraction or are not suited for primary extraction. A gas in its supercritical state is introduced into the deposit. The supercritical gas charges itself with the petroleum while flowing through the deposit. The charged supercritical gas leaves the deposit and the petroleum is separated in a plurality of fractions from the charged supercritical gas.

  5. Bench scale studies of the soil aeration process for bioremediation of petroleum hydrocarbons

    SciTech Connect

    Hinchee, R.E.; Arthur, M.

    1991-12-31

    An alternative to traditional hydrocarbon bioremediation is to pump air through unsaturated soils to create aerobic conditions and induce biodegradation. This study examines the effects of moisture and nutrient augmentation on biodegradation of petroleum hydrocarbons in aerated soils. Findings indicate that forced aeration, coupled with additions of nutrients and moisture, stimulate hydrocarbon-degrading microorganisms and present a feasible approach to bioremediation management.

  6. Development of a three-phase reacting flow computer model for analysis of petroleum cracking

    SciTech Connect

    Chang, S.L.; Lottes, S.A.; Petrick, M.

    1995-07-01

    A general computational fluid dynamics computer code (ICRKFLO) has been developed for the simulation of the multi-phase reacting flow in a petroleum fluid catalytic cracker riser. ICRKFLO has several unique features. A new integral reaction submodel couples calculations of hydrodynamics and cracking kinetics by making the calculations more efficient in achieving stable convergence while still preserving the major physical effects of reaction processes. A new coke transport submodel handles the process of coke formation in gas phase reactions and the subsequent deposition on the surface of adjacent particles. The code was validated by comparing with experimental results of a pilot scale fluid cracker unit. The code can predict the flow characteristics of gas, liquid, and particulate solid phases, vaporization of the oil droplets, and subsequent cracking of the oil in a riser reactor, which may lead to a better understanding of the internal processes of the riser and the impact of riser geometry and operating parameters on the riser performance.

  7. An object-oriented expert system for sedimentary basin analysis with applications in petroleum geology

    SciTech Connect

    Miller, B.M. )

    1990-05-01

    Most of the world's energy resources and many of its metallic and mineral resources are derived from complex sources in sedimentary basins. A comprehensive basin analysis requires an understanding of data from many specialties, including sedimentology, stratigraphy geophysics, structural geology, and geochemistry. Such an integrated analysis is almost impossible without a computer. Research efforts in the US Geological Survey are currently being directed at exploring the feasibility of applying expert systems and knowledge acquisition techniques to the design and development of a global system of classification and geological analysis of sedimentary basins to assess their petroleum potential. The primary objective is the design of a prototype object-oriented expert system interfaced with a geographic information system (GIS) that captures both the logic used to define the geologic concepts and the reasoning under uncertainty that enables geologists to understand and reconstruct the geologic history of a sedimentary basin. NEXPERT OBJECT, a hybrid expert system that has the ability to support both a reasoning system and an object-oriented representation, is currently being used as the design tool to provide high-level, expert-oriented features to create, edit, and build knowledge bases for the basin analysis program. This system provides these capabilities through documentation of major basin analysis components such as stratigraphy, structural geology, and sedimentology. It is designed to analyze the traditional concepts of source, reservoir, and trapping mechanism; to help in the diagnosis of geological conditions favorable for the occurrence of petroleum or other energy resources; and to assist in the assessment of these resources. The design and content of the expert system program is discussed for application to basin analysis studies.

  8. Basin Analysis of the Mississippi Interior Salt Basin and Petroleum System Modeling of the Jurassic Smackover Formation, Eastern Gulf Coastal Plain

    SciTech Connect

    Ernest Mancini

    2000-12-31

    Part 3 (Petroleum System Modeling of the Jurassic Smackover Formation) objectives are to provide an analysis of the Smackover petroleum system in Years 4 and 5 of the project and to transfer effectively the research results to producers through workshops and topical reports. Work Accomplished (Year 5): Task 1 - Basin Flow - Basin flow modeling has been completed and the modeling results are being interpreted for report writing (Table 1). Task 2 - Petroleum Source Rocks - Work on the characterization of Smackover petroleum source rocks has been integrated into the basin flow model. Task 3 - Petroleum Reservoirs - Work on the characterization of Smackover petroleum reservoirs continues. The cores to be described have been identified and many of the cores for the eastern part of the basin have been described. Task 4 - Reservoir Diagenesis - Work on reservoir diagenesis has been initiated. Samples from the cores selected for the reservoir characterization are being used for this task. Work Planned (Year 5): Task 1 - Basin Flow - The report on basin flow will be completed. Task 2 - Petroleum Source Rocks - Petroleum source rock data will be reviewed in light of the basin flow model results. Task 3 - Petroleum Reservoirs - Characterization of petroleum reservoirs will continue through core studies. Task 4 - Reservoir Diagenesis - Characterization of reservoir diagenesis will continue through petrographic analysis.

  9. Double-pulse laser-induced breakdown spectroscopy analysis of scales from petroleum pipelines

    NASA Astrophysics Data System (ADS)

    Cavalcanti, G. H.; Rocha, A. A.; Damasceno, R. N.; Legnaioli, S.; Lorenzetti, G.; Pardini, L.; Palleschi, V.

    2013-09-01

    Pipeline scales from the Campos Bay Petroleum Field near Rio de Janeiro, Brazil have been analyzed by both Raman spectroscopy and by laser-induced breakdown spectroscopy (LIBS) using a double-pulse, calibration-free approach. Elements that are characteristic of petroleum (e.g. C, H, N, O, Mg, Na, Fe and V) were detected, in addition to the Ca, Al, and Si which form the matrix of the scale. The LIBS results were compared with the results of micro-Raman spectroscopy, which confirmed the nature of the incrustations inferred by the LIBS analysis. Results of this preliminary study suggest that diffusion of pipe material into the pipeline intake column plays an important role in the growth of scale. Thanks to the simplicity and relative low cost of equipment and to the fact that no special chemical pre-treatment of the samples is needed, LIBS can offer very fast acquisition of data and the possibility of in situ measurements. LIBS could thus represent an alternative or complementary method for the chemical characterization of the scales by comparison to conventional analytical techniques, such as X-ray diffraction or X-ray fluorescence.

  10. Analysis of solvent dyes in refined petroleum products by electrospray ionization mass spectrometry

    USGS Publications Warehouse

    Rostad, C.E.

    2010-01-01

    Solvent dyes are used to color refined petroleum products to enable differentiation between gasoline, diesel, and jet fuels. Analysis for these dyes in the hydrocarbon product is difficult due to their very low concentrations in such a complex matrix. Flow injection analysis/electrospray ionization/mass spectrometry in both negative and positive mode was used to optimize ionization of ten typical solvent dyes. Samples of hydrocarbon product were analyzed under similar conditions. Positive electrospray ionization produced very complex spectra, which were not suitably specific for targeting only the dyes. Negative electrospray ionization produced simple spectra because aliphatic and aromatic moieties were not ionized. This enabled screening for a target dye in samples of hydrocarbon product from a spill.

  11. Marine Oil-Degrading Microorganisms and Biodegradation Process of Petroleum Hydrocarbon in Marine Environments: A Review.

    PubMed

    Xue, Jianliang; Yu, Yang; Bai, Yu; Wang, Liping; Wu, Yanan

    2015-08-01

    Due to the toxicity of petroleum compounds, the increasing accidents of marine oil spills/leakages have had a significant impact on our environment. Recently, different remedial techniques for the treatment of marine petroleum pollution have been proposed, such as bioremediation, controlled burning, skimming, and solidifying. (Hedlund and Staley in Int J Syst Evol Microbiol 51:61-66, 2001). This review introduces an important remedial method for marine oil pollution treatment-bioremediation technique-which is considered as a reliable, efficient, cost-effective, and eco-friendly method. First, the necessity of bioremediation for marine oil pollution was discussed. Second, this paper discussed the species of oil-degrading microorganisms, degradation pathways and mechanisms, the degradation rate and reaction model, and the factors affecting the degradation. Last, several suggestions for the further research in the field of marine oil spill bioremediation were proposed.

  12. Detailed analysis of petroleum hydrocarbon attenuation in biopiles by high-performance liquid chromatography followed by comprehensive two-dimensional gas chromatography.

    PubMed

    Mao, Debin; Lookman, Richard; Van De Weghe, Hendrik; Van Look, Dirk; Vanermen, Guido; De Brucker, Nicole; Diels, Ludo

    2009-02-27

    Enhanced bioremediation of petroleum hydrocarbons in two biopiles was quantified by high-performance liquid chromatography (HPLC) followed by comprehensive two-dimensional gas chromatography (GCXGC). The attenuation of 34 defined hydrocarbon classes was calculated by HPLC-GCXGC analysis of representative biopile samples at start-up and after 18 weeks of biopile operation. In general, a-cyclic alkanes were most efficiently removed from the biopiles, followed by monoaromatic hydrocarbons. Cycloalkanes and polycyclic aromatic hydrocarbons (PAHs) were more resistant to degradation. A-cyclic biomarkers farnesane, trimethyl-C13, norpristane, pristane and phytane dropped to only about 10% of their initial concentrations. On the other hand, C29-C31 hopane concentrations remained almost unaltered after 18 weeks of biopile operation, confirming their resistance to biodegradation. They are thus reliable indicators to estimate attenuation potential of petroleum hydrocarbons in biopile processed soils.

  13. Petroleum production operations

    SciTech Connect

    Not Available

    1986-01-01

    This book is a study of petroleum production written for those with technical expertise between novice and professional. Covers petroleum reservoirs and drive mechanisms, well completion, well performance evaluation, primary cementing, perforating, squeeze cementing, packer and tubing forces, problem well analysis, workover methods, workover planning, and beam pumping.

  14. Chemical process hazards analysis

    SciTech Connect

    1996-02-01

    The Office of Worker Health and Safety (EH-5) under the Assistant Secretary for the Environment, Safety and Health of the US Department (DOE) has published two handbooks for use by DOE contractors managing facilities and processes covered by the Occupational Safety and Health Administration (OSHA) Rule for Process Safety Management of Highly Hazardous Chemicals (29 CFR 1910.119), herein referred to as the PSM Rule. The PSM Rule contains an integrated set of chemical process safety management elements designed to prevent chemical releases that can lead to catastrophic fires, explosions, or toxic exposures. The purpose of the two handbooks, ``Process Safety Management for Highly Hazardous Chemicals`` and ``Chemical Process Hazards Analysis,`` is to facilitate implementation of the provisions of the PSM Rule within the DOE. The purpose of this handbook ``Chemical Process Hazards Analysis,`` is to facilitate, within the DOE, the performance of chemical process hazards analyses (PrHAs) as required under the PSM Rule. It provides basic information for the performance of PrHAs, and should not be considered a complete resource on PrHA methods. Likewise, to determine if a facility is covered by the PSM rule, the reader should refer to the handbook, ``Process Safety Management for Highly Hazardous Chemicals`` (DOE- HDBK-1101-96). Promulgation of the PSM Rule has heightened the awareness of chemical safety management issues within the DOE. This handbook is intended for use by DOE facilities and processes covered by the PSM rule to facilitate contractor implementation of the PrHA element of the PSM Rule. However, contractors whose facilities and processes not covered by the PSM Rule may also use this handbook as a basis for conducting process hazards analyses as part of their good management practices. This handbook explains the minimum requirements for PrHAs outlined in the PSM Rule. Nowhere have requirements been added beyond what is specifically required by the rule.

  15. Petroleum products

    SciTech Connect

    Not Available

    1987-01-01

    This book is the first of three volumes devoted to petroleum products and lubricants. This volume begins with standard D 56 and contains all petroleum standards up to D 1947. It contains specifications and test methods for fuels, solvents, burner fuel oils, lubricating oils, cutting oils, lubricating greases, fluids measurement and sampling, liquified petroleum gases, light hydrocarbons, plant spray oils, sulfonates, crude petroleum, petrolatam, and wax.

  16. Automated IR determination of petroleum products in water based on sequential injection analysis.

    PubMed

    Falkova, Marina; Vakh, Christina; Shishov, Andrey; Zubakina, Ekaterina; Moskvin, Aleksey; Moskvin, Leonid; Bulatov, Andrey

    2016-02-01

    The simple and easy performed automated method for the IR determination of petroleum products (PP) in water using extraction-chromatographic cartridges has been developed. The method assumes two stages: on-site extraction of PP during a sampling by using extraction-chromatographic cartridges and subsequent determination of the extracted PP using sequential injection analysis (SIA) with IR detection. The appropriate experimental conditions for extraction of the dissolved in water PP and for automated SIA procedure were investigated. The calibration plot constructed using the developed procedure was linear in the range of 3-200 μg L(-1). The limit of detection (LOD), calculated from a blank test based on 3σ was 1 µg L(-1). The sample volume was 1L. The system throughput was found to be 12 h(-1). PMID:26653498

  17. Basin Analysis and Petroleum System Characterization and Modeling, Interior Salt Basins, Central and Eastern Gulf of Mexico

    SciTech Connect

    Ernest A. Mancini

    2006-07-31

    The principal research effort for Year 1 of Phase 2 (Concept Demonstration) of the project is Smackover petroleum system characterization and modeling. The necessary software applications are in the process of being acquired to accomplish this work. No major problems have been encountered to date, and the project is on schedule.

  18. Updated estimation of energy efficiencies of U.S. petroleum refineries.

    SciTech Connect

    Palou-Rivera, I.; Wang, M. Q.

    2010-12-08

    Evaluation of life-cycle (or well-to-wheels, WTW) energy and emission impacts of vehicle/fuel systems requires energy use (or energy efficiencies) of energy processing or conversion activities. In most such studies, petroleum fuels are included. Thus, determination of energy efficiencies of petroleum refineries becomes a necessary step for life-cycle analyses of vehicle/fuel systems. Petroleum refinery energy efficiencies can then be used to determine the total amount of process energy use for refinery operation. Furthermore, since refineries produce multiple products, allocation of energy use and emissions associated with petroleum refineries to various petroleum products is needed for WTW analysis of individual fuels such as gasoline and diesel. In particular, GREET, the life-cycle model developed at Argonne National Laboratory with DOE sponsorship, compares energy use and emissions of various transportation fuels including gasoline and diesel. Energy use in petroleum refineries is key components of well-to-pump (WTP) energy use and emissions of gasoline and diesel. In GREET, petroleum refinery overall energy efficiencies are used to determine petroleum product specific energy efficiencies. Argonne has developed petroleum refining efficiencies from LP simulations of petroleum refineries and EIA survey data of petroleum refineries up to 2006 (see Wang, 2008). This memo documents Argonne's most recent update of petroleum refining efficiencies.

  19. Myelodysplastic Syndrome and Benzene Exposure Among Petroleum Workers: An International Pooled Analysis

    PubMed Central

    2012-01-01

    Background Benzene at high concentrations is known to cause acute myeloid leukemia (AML), but its relationship with other lymphohematopoietic (LH) cancers remains uncertain, particularly at low concentrations. In this pooled analysis, we examined the risk of five LH cancers relative to lower levels of benzene exposure in petroleum workers. Methods We updated three nested case–control studies from Australia, Canada, and the United Kingdom with new incident LH cancers among petroleum distribution workers through December 31, 2006, and pooled 370 potential case subjects and 1587 matched LH cancer-free control subjects. Quantitative benzene exposure in parts per million (ppm) was blindly reconstructed using historical monitoring data, and exposure certainty was scored as high, medium, or low. Two hematopathologists assigned diagnoses and scored the certainty of diagnosis as high, medium, or low. Dose–response relationships were examined for five LH cancers, including the three most common leukemia cell-types (AML, chronic myeloid leukemia [CML], and chronic lymphoid leukemia [CLL]) and two myeloid tumors (myelodysplastic syndrome [MDS] and myeloproliferative disease [MPD]). Odds ratios (ORs) and 95% confidence intervals (CIs) were calculated using conditional logistic regression, controlling for age, sex, and time period. Results Cumulative benzene exposure showed a monotonic dose–response relationship with MDS (highest vs lowest tertile, >2.93 vs ≤0.348 ppm-years, OR = 4.33, 95% CI = 1.31 to 14.3). For peak benezene exposures (>3 ppm), the risk of MDS was increased in high and medium certainty diagnoses (peak exposure vs no peak exposure, OR = 6.32, 95% CI = 1.32 to 30.2) and in workers having the highest exposure certainty (peak exposure vs no peak exposure, OR = 5.74, 95% CI = 1.05 to 31.2). There was little evidence of dose–response relationships for AML, CLL, CML, or MPD. Conclusions Relatively low-level exposure to benzene experienced by petroleum

  20. Petroleum supply monthly, August 1994

    SciTech Connect

    Not Available

    1994-08-26

    Data presented in the Petroleum Supply Monthly (PSM) describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics.

  1. Petroleum supply monthly, July 1993

    SciTech Connect

    Not Available

    1993-07-29

    Data presented in the Petroleum Supply Monthly (PSM) describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: Petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States.

  2. Basin Analysis and Petroleum System Characterization and Modeling, Interior Salt Basins, Central and Eastern Gulf of Mexico

    SciTech Connect

    Ernest A. Mancini; Paul Aharon; Donald A. Goddard; Roger Barnaby

    2006-02-28

    The principal research effort for Year 3 of the project is basin modeling and petroleum system identification, comparative basin evaluation and resource assessment. In the first six (6) months of Year 3, the research focus is on basin modeling and petroleum system identification and the remainder of the year the emphasis is on the comparative basin evaluation and resource assessment. No major problems have been encountered to date, and the project is on schedule. The principal objectives of the project are to develop through basin analysis and modeling the concept that petroleum systems acting in a basin can be identified through basin modeling and to demonstrate that the information and analysis resulting from characterizing and modeling of these petroleum systems in the North Louisiana Salt Basin and the Mississippi Interior Salt Basin can be used in providing a more reliable and advanced approach for targeting stratigraphic traps and specific reservoir facies within a geologic system and in providing a refined assessment of undiscovered and underdeveloped reservoirs and associated oil and gas resources.

  3. Test kit/spectrometer for the analysis of petroleum substances using Friedel-Crafts colorimetry

    NASA Astrophysics Data System (ADS)

    Hanby, John D.; Hewitt, Alan D.; Lory, Ernest E.

    2001-02-01

    12 Laboratory and field results of the testing of a new, visible-range spectrometry utilizing the robust signals produced by Friedel-Crafts reaction compounds demonstrate the utility of a rapid, portable, and sensitive method of on-site analysis for petroleum substances in soil and water samples. Preliminary testing of the kits and spectrometer was performed at the U.S. Army Cold Regions Research and Engineering Laboratory (CRREL) in Hanover, NH. Specific field protocols for the sampling and handling of soils for gasoline range organics and diesel range organics were established for the field sampling, which was conducted at the U.S. Navy Facilities Engineering Service Center in Port Hueneme, CA. Co-located soil samples were collected and either split or homogenized for subsequent partitioning to provide samples for the on-site analysis by the field kit/spectrometer technology and for later analysis by off- site reference laboratories. Test kit colorimetric results are by visual and spectrometric methods, and are compared with reference laboratory results and CRREL analyses.

  4. Removal of petroleum hydrocarbons from contaminated groundwater by the combined technique of adsorption onto perlite followed by the O3/H2O2 process.

    PubMed

    Moussavi, Gholamreza; Bagheri, Amir

    2012-09-01

    Groundwater contaminated with petroleum hydrocarbons was treated using a combined system of adsorption onto powdered expanded perlite (PEP) followed by the O3/H2O2 process. The pretreatment investigations indicated a high capacity for PEP to remove petroleum hydrocarbons from the contaminated water. An experimental total petroleum hydrocarbon (TPH) adsorption capacity of 275 mg/g PEP was obtained at the natural pH of water. The experimental data fit best with the Freundlich isotherm model and pseudo-second-order adsorption model. The second phase of the experiment evaluated the performance of the O3/H2O2 process in the removal of residual TPH from pretreated water and compared the results with that of raw water. The O3/H202 process attained a maximum TPH removal rate for the pretreated water after 70 min, when 93% of the residual TPH in the effluent of the adsorption system was removed. Overall, the combination of adsorption onto PEP for 100 min and the subsequent treatment with the O3/H2O2 process for 70min eliminated over 99% of the TPH of highly petroleum-contaminated groundwater, with initial values of 162 mg/L. Therefore, we can conclude that the developed treatment system is an appropriate method of remediation for petroleum-contaminated waters.

  5. Metaproteomics and metabolomics analyses of chronically petroleum-polluted sites reveal the importance of general anaerobic processes uncoupled with degradation.

    PubMed

    Bargiela, Rafael; Herbst, Florian-Alexander; Martínez-Martínez, Mónica; Seifert, Jana; Rojo, David; Cappello, Simone; Genovese, María; Crisafi, Francesca; Denaro, Renata; Chernikova, Tatyana N; Barbas, Coral; von Bergen, Martin; Yakimov, Michail M; Ferrer, Manuel; Golyshin, Peter N

    2015-10-01

    Crude oil is one of the most important natural assets for humankind, yet it is a major environmental pollutant, notably in marine environments. One of the largest crude oil polluted areas in the word is the semi-enclosed Mediterranean Sea, in which the metabolic potential of indigenous microbial populations towards the large-scale chronic pollution is yet to be defined, particularly in anaerobic and micro-aerophilic sites. Here, we provide an insight into the microbial metabolism in sediments from three chronically polluted marine sites along the coastline of Italy: the Priolo oil terminal/refinery site (near Siracuse, Sicily), harbour of Messina (Sicily) and shipwreck of MT Haven (near Genoa). Using shotgun metaproteomics and community metabolomics approaches, the presence of 651 microbial proteins and 4776 metabolite mass features have been detected in these three environments, revealing a high metabolic heterogeneity between the investigated sites. The proteomes displayed the prevalence of anaerobic metabolisms that were not directly related with petroleum biodegradation, indicating that in the absence of oxygen, biodegradation is significantly suppressed. This suppression was also suggested by examining the metabolome patterns. The proteome analysis further highlighted the metabolic coupling between methylotrophs and sulphate reducers in oxygen-depleted petroleum-polluted sediments.

  6. Petroleum supply monthly, April 1990

    SciTech Connect

    1990-06-26

    The Petroleum Supply Monthly (PSM) is one of a family of three publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other two publications are the Weekly Petroleum Status Report (WPSR) and the Petroleum Supply Annual (PSA). Data presented in the Petroleum Supply Monthly describe (PSM) the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in Primary Supply.'' Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: (1) the Summary Statistics and (2) the Detailed Statistics.

  7. Determination of vanadium in petroleum and petroleum products using atomic spectrometric techniques.

    PubMed

    Amorim, Fábio A C; Welz, Bernhard; Costa, Antônio C S; Lepri, Fábio G; Vale, Maria Goreti R; Ferreira, Sérgio L C

    2007-04-30

    Vanadium is recognized worldwide as the most abundant metallic constituent in petroleum. It is causing undesired side effects in the refining process, and corrosion in oil-fired power plants. Consequently, it is the most widely determined metal in petroleum and its derivatives. This paper offers a critical review of analytical methods based on atomic spectrometric techniques, particularly flame atomic absorption spectrometry (FAAS), electrothermal atomic absorption spectrometry (ET AAS), inductively coupled plasma optical emission spectrometry (ICP OES), inductively coupled plasma mass spectrometry (ICP-MS). In addition an overview is provided of the sample pretreatment and preparation procedures for vanadium determination in petroleum and petroleum products. Also included are the most recent studies about speciation and fractionation analysis using atomic spectrometric techniques.

  8. Petroleum Supply Monthly, July 1990

    SciTech Connect

    Not Available

    1990-09-28

    Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 states and the District of Columbia). The reporting universe includes those petroleum sectors in Primary Supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States.

  9. Integrated hydraulic flow units analysis for carbonate and clastic conventional and unconventional petroleum reservoirs

    NASA Astrophysics Data System (ADS)

    Ivakhnenko, Aleksandr; Abirov, Rustem; Gulnur, Asan; Shopenova, Aigerim; Makarova, Maria; Telman, Meruert

    2014-05-01

    Thorough understanding of the phenomena in variation of pore properties and permeability in lithofacies of conventional carbonate and clastic petroleum reservoirs together with unconventional reservoirs before and after their hydraulic fracturing is the main concept in reservoir description. It is known that new reservoir description techniques will cut off the amount of unexplored hydrocarbon reserves. Discrepancies in pore geometry are the evidence of that there exist hydraulic flow units with similar or different characteristics. So the rock type determination processes cannot be accomplished only by one way. There is demand for several techniques in order to make away with different uncertainties by proper correlation and analysing the results. Classic determination of rock types is realized by geological observations and by the porosity versus permeability log. In this paper, the new methodology is proposed for determination of flow zones. The methodology is based on the Kozeny-Carmen equation where we can get the reservoir quality index which indicates the porosity versus permeability data. The specialty of this new technique is that it takes into account the influence of depositional and diagenetic units controlling the fluid flow besides the reservoir quality index. The proposed technique has been successfully tested in reservoirs. The paper describes the hydraulic flow units and presents graphs demonstrating the utility of this method.

  10. Maintenance Process Strategic Analysis

    NASA Astrophysics Data System (ADS)

    Jasiulewicz-Kaczmarek, M.; Stachowiak, A.

    2016-08-01

    The performance and competitiveness of manufacturing companies is dependent on the availability, reliability and productivity of their production facilities. Low productivity, downtime, and poor machine performance is often linked to inadequate plant maintenance, which in turn can lead to reduced production levels, increasing costs, lost market opportunities, and lower profits. These pressures have given firms worldwide the motivation to explore and embrace proactive maintenance strategies over the traditional reactive firefighting methods. The traditional view of maintenance has shifted into one of an overall view that encompasses Overall Equipment Efficiency, Stakeholders Management and Life Cycle assessment. From practical point of view it requires changes in approach to maintenance represented by managers and changes in actions performed within maintenance area. Managers have to understand that maintenance is not only about repairs and conservations of machines and devices, but also actions striving for more efficient resources management and care for safety and health of employees. The purpose of the work is to present strategic analysis based on SWOT analysis to identify the opportunities and strengths of maintenance process, to benefit from them as much as possible, as well as to identify weaknesses and threats, so that they could be eliminated or minimized.

  11. Signal Processing, Analysis, & Display

    1986-06-01

    SIG is a general-purpose signal processing, analysis, and display program. Its main purpose is to perform manipulations on time- and frequency-domain signals. However, it has been designed to ultimately accommodate other representations for data such as multiplexed signals and complex matrices. Two user interfaces are provided in SIG - a menu mode for the unfamiliar user and a command mode for more experienced users. In both modes errors are detected as early as possible andmore » are indicated by friendly, meaningful messages. An on-line HELP package is also included. A variety of operations can be performed on time- and frequency-domain signals including operations on the samples of a signal, operations on the entire signal, and operations on two or more signals. Signal processing operations that can be performed are digital filtering (median, Bessel, Butterworth, and Chebychev), ensemble average, resample, auto and cross spectral density, transfer function and impulse response, trend removal, convolution, Fourier transform and inverse window functions (Hamming, Kaiser-Bessel), simulation (ramp, sine, pulsetrain, random), and read/write signals. User definable signal processing algorithms are also featured. SIG has many options including multiple commands per line, command files with arguments,commenting lines, defining commands, and automatic execution for each item in a repeat sequence. Graphical operations on signals and spectra include: x-y plots of time signals; real, imaginary, magnitude, and phase plots of spectra; scaling of spectra for continuous or discrete domain; cursor zoom; families of curves; and multiple viewports.« less

  12. Contributions in petroleum geology and engineering

    SciTech Connect

    Harvey, A.H.; Koederitz, L.; Honarpour, M. )

    1989-01-01

    This book discusses petroleum reservoir components and properties. The contents include: Systems of units. Reservoir Rocks. Reservoir fluids. Relative permeability and capillarity. Reservoir volume and fluid flow. Naturally fractured reservoirs. Natural production mechanisms. Prediction of oil and gas recovery. Analysis of well performance. Gas-condensate reservoirs. Enhanced oil recovery processes.

  13. Petroleum supply monthly, October 1993

    SciTech Connect

    Not Available

    1993-10-26

    The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics.

  14. Petroleum supply monthly, May 1994

    SciTech Connect

    Not Available

    1994-05-27

    The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum supply annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics.

  15. Petroleum supply monthly, July 1994

    SciTech Connect

    Not Available

    1994-07-26

    The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics.

  16. Petroleum supply monthly, June 1994

    SciTech Connect

    Not Available

    1994-06-28

    The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics.

  17. Petroleum supply monthly, January 1996

    SciTech Connect

    1996-02-15

    The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics.

  18. Petroleum supply monthly, September 1991

    SciTech Connect

    Not Available

    1991-09-30

    The Petroleum Supply Monthly (PSM) is one of a family of three publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other two publications are the Weekly Petroleum Status Report (WPSR) and the Petroleum Supply Annual (PSA). Data presented in PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administrations for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 states and the District of Columbia). The reporting universe includes those petroleum sectors in Primary Supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections (1) the Summary Statistics and (2) the Detailed Statistics. 65 tabs.

  19. Petroleum Supply Monthly, August 1990

    SciTech Connect

    Not Available

    1990-10-30

    The Petroleum Supply Monthly (PSM) is one of a family of three publications produced by the Petroleum Supply Division within the Energy Information administration (EIA) reflecting different levels of data timeliness and completeness. The other two publications are the Weekly Petroleum Status Report (WPSR) and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) district movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in Primary Supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections (1) the Summary Statistics and (2) the Detailed Statistics.

  20. Biological monitoring of benzene exposure for process operators during ordinary activity in the upstream petroleum industry.

    PubMed

    Bråtveit, Magne; Kirkeleit, Jorunn; Hollund, Bjørg Eli; Moen, Bente E

    2007-07-01

    This study characterized the exposure of crude oil process operators to benzene and related aromatics during ordinary activity and investigated whether the operators take up benzene at this level of exposure. We performed the study on a fixed, integrated oil and gas production facility on Norway's continental shelf. The study population included 12 operators and 9 referents. We measured personal exposure to benzene, toluene, ethylbenzene and xylene during three consecutive 12-h work shifts using organic vapour passive dosimeter badges. We sampled blood and urine before departure to the production facility (pre-shift), immediately after the work shift on Day 13 of the work period (post-shift) and immediately before the following work shift (pre-next shift). We also measured the exposure to hydrocarbons during short-term tasks by active sampling using Tenax tubes. The arithmetic mean exposure over the 3 days was 0.042 ppm for benzene (range <0.001-0.69 ppm), 0.05 ppm for toluene, 0.02 ppm for ethylbenzene and 0.03 ppm for xylene. Full-shift personal exposure was significantly higher when the process operators performed flotation work during the shift versus other tasks. Work in the flotation area was associated with short-term (6-15 min) arithmetic mean exposure to benzene of 1.06 ppm (range 0.09-2.33 ppm). The concentrations of benzene in blood and urine did not differ between operators and referents at any time point. When we adjusted for current smoking in regression analysis, benzene exposure was significantly associated with the post-shift concentration of benzene in blood (P = 0.01) and urine (P = 0.03), respectively. Although these operators perform tasks with relatively high short-term exposure to benzene, the full-shift mean exposure is low during ordinary activity. Some evidence indicates benzene uptake within this range of exposure.

  1. Biostimulation of petroleum-hydrocarbon-contaminated marine sediment with co-substrate: involved metabolic process and microbial community.

    PubMed

    Zhang, Zhen; Lo, Irene M C

    2015-07-01

    This study investigated the effect of acetate and methanol as co-substrates on anaerobic biodegradation of total petroleum hydrocarbons (TPHs, C10-C40) in marine sediment. The findings evidenced that the degradation of TPH can be enhanced by adding acetate or methanol. The addition of acetate was generally more favorable than the addition of methanol for the TPH degradation. Both sulfate reduction and methanogenesis occurred in the acetate-treated sediment. However, the depletion of SO4 (2-) inhibited sulfate reduction over the incubation period. Only methanogenesis was prevalent in the methanol-treated sediment within the whole incubation period. The degradation of TPH fractions with higher carbon number ranges (C31-C40) was speculated to be more favored under sulfate-reducing condition, while TPH fractions with lower carbon number ranges (C10-C20) were preferentially degraded under methanogenic condition. The 16S rRNA clone library-based analysis revealed that the addition of different co-substrates led to distinct structures of the microbial community. Clones related to sulfate-reducing Desulfobacterales were the most abundant in the sediment dosed with acetate. Clones related to Clostridiales predominated in the sediment dosed with methanol. Acetoclastic methanogens were found to be the predominant archaeal species in the sediment dosed with acetate, while both acetoclastic methanogens and hydrogenotrophic methanogens accounted for large proportions in the sediment dosed with methanol. The results obtained in this study will contribute to more comprehensive knowledge on the role of acetate and methanol as co-substrates in biostimulation of petroleum-hydrocarbon-contaminated marine sediment. PMID:25661814

  2. Biostimulation of petroleum-hydrocarbon-contaminated marine sediment with co-substrate: involved metabolic process and microbial community.

    PubMed

    Zhang, Zhen; Lo, Irene M C

    2015-07-01

    This study investigated the effect of acetate and methanol as co-substrates on anaerobic biodegradation of total petroleum hydrocarbons (TPHs, C10-C40) in marine sediment. The findings evidenced that the degradation of TPH can be enhanced by adding acetate or methanol. The addition of acetate was generally more favorable than the addition of methanol for the TPH degradation. Both sulfate reduction and methanogenesis occurred in the acetate-treated sediment. However, the depletion of SO4 (2-) inhibited sulfate reduction over the incubation period. Only methanogenesis was prevalent in the methanol-treated sediment within the whole incubation period. The degradation of TPH fractions with higher carbon number ranges (C31-C40) was speculated to be more favored under sulfate-reducing condition, while TPH fractions with lower carbon number ranges (C10-C20) were preferentially degraded under methanogenic condition. The 16S rRNA clone library-based analysis revealed that the addition of different co-substrates led to distinct structures of the microbial community. Clones related to sulfate-reducing Desulfobacterales were the most abundant in the sediment dosed with acetate. Clones related to Clostridiales predominated in the sediment dosed with methanol. Acetoclastic methanogens were found to be the predominant archaeal species in the sediment dosed with acetate, while both acetoclastic methanogens and hydrogenotrophic methanogens accounted for large proportions in the sediment dosed with methanol. The results obtained in this study will contribute to more comprehensive knowledge on the role of acetate and methanol as co-substrates in biostimulation of petroleum-hydrocarbon-contaminated marine sediment.

  3. Experiences of a Multidisciplinary Course on Geo-Signal Processing from a DSP Perspective Offered in Electrical Engineering at King Fahd University of Petroleum and Minerals

    ERIC Educational Resources Information Center

    Mousa, W. A.

    2012-01-01

    The purpose of this paper is to share the experience gained in, and the efforts made toward, introducing and implementing a new course in the challenging and important area of geophysical signal processing at the Electrical Engineering (EE) Department, King Fahd University of Petroleum and Minerals (KFUPM), Dhahran, Saudi Arabia. The new course,…

  4. Chemical Sensing in Process Analysis.

    ERIC Educational Resources Information Center

    Hirschfeld, T.; And Others

    1984-01-01

    Discusses: (1) rationale for chemical sensors in process analysis; (2) existing types of process chemical sensors; (3) sensor limitations, considering lessons of chemometrics; (4) trends in process control sensors; and (5) future prospects. (JN)

  5. Slow Radio-Frequency Processing of Large Oil Shale Volumes to Produce Petroleum-Like Shale Oil

    SciTech Connect

    Burnham, A K

    2003-08-20

    A process is proposed to convert oil shale by radio frequency heating over a period of months to years to create a product similar to natural petroleum. Electrodes would be placed in drill holes, either vertical or horizontal, and a radio frequency chosen so that the penetration depth of the radio waves is of the order of tens to hundreds of meters. A combination of excess volume production and overburden compaction drives the oil and gas from the shale into the drill holes, where it is pumped to the surface. Electrical energy for the process could be provided initially by excess regional capacity, especially off-peak power, which would generate {approx}3 x 10{sup 5} bbl/day of synthetic crude oil, depending on shale grade. The electricity cost, using conservative efficiency assumptions, is $4.70 to $6.30/bbl, depending on grade and heating rate. At steady state, co-produced gas can generate more than half the electric power needed for the process, with the fraction depending on oil shale grade. This would increase production to 7.3 x 10{sup 5} bbl/day for 104 l/Mg shale and 1.6 x 10{sup 6} bbl/day for 146 l/Mg shale using a combination of off-peak power and power from co-produced gas.

  6. Petroleum: An energy profile, 1999

    SciTech Connect

    1999-07-01

    This report prepared by the Energy Information Administration covers the following topics: petroleum production and end-use sectors; resources and reserves; exploration and production; LPG sources and processing; motor gasoline octane enhancement; constructing pipelines; the strategic petroleum reserve; imports and exports; marketing; district descriptions and maps; and refinery processes and facilities. 33 figs., 7 tabs.

  7. Analysis of crude oil vapor pressures at the U.S. Strategic Petroleum Reserve.

    SciTech Connect

    Rudeen, David Keith; Lord, David L.

    2005-08-01

    Crude oil storage caverns at the U.S. Strategic Petroleum Reserve (SPR) are solution-mined from subsurface salt domes along the U.S. Gulf Coast. While these salt domes exhibit many attractive characteristics for large-volume, long-term storage of oil such as low cost for construction, low permeability for effective fluids containment, and secure location deep underground, they also present unique technical challenges for maintaining oil quality within delivery standards. The vapor pressures of the crude oils stored at SPR tend to increase with storage time due to the combined effects of geothermal heating and gas intrusion from the surrounding salt. This presents a problem for oil delivery offsite because high vapor-pressure oil may lead to excessive atmospheric emissions of hydrocarbon gases that present explosion hazards, health hazards, and handling problems at atmospheric pressure. Recognizing this potential hazard, the U.S. Department of Energy, owner and operator of the SPR, implemented a crude oil vapor pressure monitoring program that collects vapor pressure data for all the storage caverns. From these data, DOE evaluates the rate of change in vapor pressures of its oils in the SPR. Moreover, DOE implemented a vapor pressure mitigation program in which the oils are degassed periodically and will be cooled immediately prior to delivery in order to reduce the vapor pressure to safe handling levels. The work described in this report evaluates the entire database since its origin in 1993, and determines the current levels of vapor pressure around the SPR, as well as the rate of change for purposes of optimizing both the mitigation program and meeting safe delivery standards. Generally, the rate of vapor pressure increase appears to be lower in this analysis than reported in the past and, problematic gas intrusion seems to be limited to just a few caverns. This being said, much of the current SPR inventory exceeds vapor pressure delivery guidelines and must be

  8. Training in the Petroleum Industry: An Analysis of Its Organization and Programs.

    ERIC Educational Resources Information Center

    Taylor, William H.

    Exploratory, descriptive research was conducted to identify potential and existing shortages of skilled manpower in the petroleum industry. Data came from interviews with 60 individual companies, governments, industry groups, and professional associations. Company characteristics that were significant determinants of training were size, foreign or…

  9. The effects of Fenton process on the removal of petroleum hydrocarbons from oily sludge in Shiraz oil refinery, Iran

    PubMed Central

    2014-01-01

    Background Due to the high concentrations of total petroleum hydrocarbons (TPH) in oily sludge and their environmental hazards, the concern regarding their effects on health and the environment has increased. The main objective of this research was focused on evaluating the feasibility of using Fenton process in removing TPH in oily sludge from Shiraz oil refinery, Southern Iran. Results To determine optimum conditions, four different parameters were assessed at four different levels using Taguchi method. According to data, the optimum conditions were as follows: the reaction time of 1 hour, H2O2 to sample mass ratio of 15, H2O2 to Fe (II) molar ratio of 10 and pH of 5. The maximum TPH reduction rate was 36.47%. Because of the semi-solid nature of the sample and the hydroxyl radicals mainly generated in the aqueous solution, TPH reduction rate greatly improved by adding water. Ultimately, by adding 40 ml water per gram of the oily sludge under optimized conditions, the reduction rate of 73.07% was achieved. Conclusions The results demonstrated that this method can be used as a pre-treatment method for the oily sludge. Moreover, a complementary treatment is necessary to reach the standard limit. PMID:24422994

  10. Evaluation of concepts for controlling exhaust emissions from minimally processed petroleum and synthetic fuels

    NASA Technical Reports Server (NTRS)

    Russell, P. L.; Beal, G. W.; Sederquist, R. A.; Shultz, D.

    1981-01-01

    Rich-lean combustor concepts designed to enhance rich combustion chemistry and increase combustor flexibility for NO(x) reduction with minimally processed fuels are examined. Processes such as rich product recirculation in the rich chamber, rich-lean annihilation, and graduated air addition or staged rich combustion to release bound nitrogen in steps of reduced equivalence ratio are discussed. Variations to the baseline rapid quench section are considered, and the effect of residence time in the rich zone is investigated. The feasibility of using uncooled non-metallic materials for the rich zone combustion construction is also addressed. The preliminary results indicate that rich primary zone staged combustion provides environmentally acceptable operation with residual and/or synthetic coal-derived liquid fuels

  11. Novel Catalysts and Processing Technologies for Production of Aerospace Fuels from Non-Petroleum Raw Materials

    NASA Technical Reports Server (NTRS)

    Hepp, A. F.; Kulis, M. J.; Psarras, P. C.; Ball, D. W.; Timko, M. T.; Wong, H.-W.; Peck, J.; Chianelli, R. R.

    2014-01-01

    Transportation fuels production (including aerospace propellants) from non-traditional sources (gases, waste materials, and biomass) has been an active area of research and development for decades. Reducing terrestrial waste streams simultaneous with energy conversion, plentiful biomass, new low-cost methane sources, and/or extra-terrestrial resource harvesting and utilization present significant technological and business opportunities being realized by a new generation of visionary entrepreneurs. We examine several new approaches to catalyst fabrication and new processing technologies to enable utilization of these non-traditional raw materials. Two basic processing architectures are considered: a single-stage pyrolysis approach that seeks to basically re-cycle hydrocarbons with minimal net chemistry or a two-step paradigm that involves production of supply or synthesis gas (mainly carbon oxides and hydrogen) followed by production of fuel(s) via Sabatier or methanation reactions and/or Fischer-Tropsch synthesis. Optimizing the fraction of product stream relevant to targeted aerospace (and other transportation) fuels via modeling, catalyst fabrication and novel reactor design are described. Energy utilization is a concern for production of fuels for either terrestrial or space operations; renewable sources based on solar energy and/or energy efficient processes may be mission enabling. Another important issue is minimizing impurities in the product stream(s), especially those potentially posing risks to personnel or operations through (catalyst) poisoning or (equipment) damage. Technologies being developed to remove (and/or recycle) heteroatom impurities are briefly discussed as well as the development of chemically robust catalysts whose activity are not diminished during operation. The potential impacts on future missions by such new approaches as well as balance of system issues are addressed.

  12. Novel Catalysts and Processing Technologies for Production of Aerospace Fuels from Non-Petroleum Raw Materials

    NASA Technical Reports Server (NTRS)

    Hepp, Aloysius F.; Kulis, Michael J.; Psarras, Peter C.; Ball, David W.; Timko, Michael T.; Wong, Hsi-Wu; Peck, Jay; Chianelli, Russell R.

    2014-01-01

    Transportation fuels production (including aerospace propellants) from non-traditional sources (gases, waste materials, and biomass) has been an active area of research and development for decades. Reducing terrestrial waste streams simultaneous with energy conversion, plentiful biomass, new low-cost methane sources, and/or extra-terrestrial resource harvesting and utilization present significant technological and business opportunities being realized by a new generation of visionary entrepreneurs. We examine several new approaches to catalyst fabrication and new processing technologies to enable utilization of these nontraditional raw materials. Two basic processing architectures are considered: a single-stage pyrolysis approach that seeks to basically re-cycle hydrocarbons with minimal net chemistry or a two-step paradigm that involves production of supply or synthesis gas (mainly carbon oxides and H2) followed by production of fuel(s) via Sabatier or methanation reactions and/or Fischer-Tröpsch synthesis. Optimizing the fraction of product stream relevant to targeted aerospace (and other transportation) fuels via modeling, catalyst fabrication and novel reactor design are described. Energy utilization is a concern for production of fuels for either terrestrial or space operations; renewable sources based on solar energy and/or energy efficient processes may be mission enabling. Another important issue is minimizing impurities in the product stream(s), especially those potentially posing risks to personnel or operations through (catalyst) poisoning or (equipment) damage. Technologies being developed to remove (and/or recycle) heteroatom impurities are briefly discussed as well as the development of chemically robust catalysts whose activities are not diminished during operation. The potential impacts on future missions by such new approaches as well as balance of system issues are addressed.

  13. Prevention of iron-sulfide deposition in petroleum processing. Final CRADA report.

    SciTech Connect

    Doctor, R. D.; Panchal, C. B.; Energy Systems

    2010-03-25

    The purpose of this CRADA extension which effectively ended in 2003 was to quantify the effect of iron-sulfide formation on the fouling propensity of crude oil. The specific objectives are focused on fouling of the Crude Distillation Unit (CDU-1) at the Shell Refinery in Mobile, Alabama. The technical approach consists of analyzing the plant data, chemical analysis of crude oil to detect key precursors, performing refinery tests using the Argonne Field Fouling Unit, and verifying the effectiveness of a physical device of tube insert and enhanced tubes to change threshold conditions and thereby reducing fouling.

  14. Dynamic analysis of process reactors

    SciTech Connect

    Shadle, L.J.; Lawson, L.O.; Noel, S.D.

    1995-06-01

    The approach and methodology of conducting a dynamic analysis is presented in this poster session in order to describe how this type of analysis can be used to evaluate the operation and control of process reactors. Dynamic analysis of the PyGas{trademark} gasification process is used to illustrate the utility of this approach. PyGas{trademark} is the gasifier being developed for the Gasification Product Improvement Facility (GPIF) by Jacobs-Siffine Engineering and Riley Stoker. In the first step of the analysis, process models are used to calculate the steady-state conditions and associated sensitivities for the process. For the PyGas{trademark} gasifier, the process models are non-linear mechanistic models of the jetting fluidized-bed pyrolyzer and the fixed-bed gasifier. These process sensitivities are key input, in the form of gain parameters or transfer functions, to the dynamic engineering models.

  15. Blast resistant modular buildings for the petroleum and chemical processing industries.

    PubMed

    Harrison, Ben F

    2003-11-14

    There exists a need for blast resistant yet portable buildings to protect personnel temporarily assigned duties within explosively hazardous areas. Blast resistant portable buildings (BRPBs) are a valuable asset for protection of temporarily assigned personnel involved in activities located near potential explosion sites. Portable. Stackable and modular. Blast designed and ductile. Several companies have designed products to meet this need. Blast resistant portable buildings are the size of a typical office trailer; however, they may be installed in a variety of configurations and floor plans. The buildings are similar in design and construction to steel shipping containers but they are larger in scale, are much stronger, and are intended to be occupied within hazardous areas. Typical siting issues for modular buildings involve blast related requirements, process related requirements and conventional loading requirements. Examples of these requirements include: Sliding and overturning during blast response. Positive pressure and forced ventilation requirements. Seismic and wind loading. This paper describes blast performance, structural siting issues, and presents different applications of blast resistant modular buildings that have been installed at various facilities. PMID:14602397

  16. CO2 co-gasification of lower sulphur petroleum coke and sugar cane bagasse via TG-FTIR analysis technique.

    PubMed

    Edreis, Elbager M A; Luo, Guangqian; Li, Aijun; Chao, Chen; Hu, Hongyun; Zhang, Sen; Gui, Ben; Xiao, Li; Xu, Kai; Zhang, Pingan; Yao, Hong

    2013-05-01

    This study investigates the non-isothermal mechanism and kinetic behaviour of gasification of a lower sulphur petroleum coke, sugar cane bagasse and blends under carbon dioxide atmosphere conditions using the thermogravimetric analyser (TGA). The gas products were measured online with coupled Fourier transform infrared spectroscopy (FTIR). The achieved results explored that the sugar cane bagasse and blend gasification happened in two steps: at (<500 °C) the volatiles are released, and at (>700 °C) char gasification occurred, whereas the lower sulphur petroleum coke presented only one char gasification stage at (>800 °C). Significant interactions were observed in the whole process. Some solid-state mechanisms were studied by the Coats-Redfern method in order to observe the mechanisms responsible for the gasification of samples. The results show that the chemical first order reaction is the best responsible mechanism for whole process. The main released gases are CO2, CO, CH4, HCOOH, C6H5OH and CH3COOH.

  17. BASIN ANALYSIS AND PETROLEUM SYSTEM CHARACTERIZATION AND MODELING, INTERIOR SALT BASINS, CENTRAL AND EASTERN GULF OF MEXICO

    SciTech Connect

    Ernest A. Mancini

    2004-02-05

    The principal research effort for Year 1 of the project is data compilation and the determination of the tectonic and depositional histories of the North Louisiana Salt Basin. In the first three (3) to six (6) months of Year 1, the research focus is on data compilation and the remainder of the year the emphasis is on the tectonic and depositional histories of the basin. No major problems have been encountered to date, and the project is on schedule. The principal objectives of the project are to develop through basin analysis and modeling the concept that petroleum systems acting in a basin can be identified through basin modeling and to demonstrate that the information and analysis resulting from characterizing and modeling of these petroleum systems in the North Louisiana Salt Basin and the Mississippi Interior Salt Basin can be used in providing a more reliable and advanced approach for targeting stratigraphic traps and specific reservoir facies within a geologic system and in providing a refined assessment of undiscovered and underdeveloped reservoirs and associated oil and gas resources.

  18. Predicting petroleum phototoxicity.

    PubMed

    Wernersson, Ann-Sofie

    2003-03-01

    Phototoxicity to Daphnia magna was studied on 14 polycyclic aromatic hydrocarbons (PAHs) and 22 petroleum products (ranging from diesel to crude oil). The phototoxicity ranking of pure PAHs was about the same as found in another study on fish gill cells in vitro (Toxicology 127 (1998) 143), suggesting that the relative acute phototoxicity does not differ significantly between different species. Most petroleum products were found to be phototoxic, although the results differ somewhat between test methods (preparation of water-accommodated fractions or petroleum ether dissolved oil slurries). The degree of phototoxicity of a sample is related to both the source and the refining process of the crude oil. The best chemical predictors found were the concentrations of eight phototoxic parent PAHs. An even simpler analytical technique suggested for initial screening would be direct measurements of "total PAH," where samples having more than 3% PAH should be studied further.

  19. Studies on the origin and transformation of selenium and its chemical species along the process of petroleum refining

    NASA Astrophysics Data System (ADS)

    Stivanin de Almeida, Cibele M.; Ribeiro, Anderson S.; Saint'Pierre, Tatiana D.; Miekeley, Norbert

    2009-06-01

    Inductively coupled plasma optical emission spectrometry and mass spectrometry (ICPMS), the latter hyphenated to flow injection hydride generation, electrothermal vaporization or ion chromatography, have been applied to the chemical characterization of crude oil, aqueous process stream samples and wastewaters from a petroleum refinery, in order to get information on the behavior of selenium and its chemical species along effluent generation and treatment. Multielemental characterization of these effluents by ICPMS revealed a complex composition of most of them, with high salinity and potential spectral and non-spectral interferents present. For this reason, a critical re-assessment of the analytical techniques for the determination of total selenium and its species was performed. Methane was employed as gas in dynamic reaction cell ICPMS and cell parameters were optimized for a simulated brine matrix and for diluted aqueous solutions to match the expected process and treated wastewaters samples. The signal-to-background ratios for 78Se and 80Se were used as criteria in optimization, the first isotope resulting in better detection limits for the simulated brine matrix ( 78Se: 0.07 μg L - 1 , 80Se: 0.31 μg L - 1 ). A large variability in the concentration of selenium (from < 10 μg kg - 1 up to 960 μg kg - 1 ) was observed in 16 of the most frequently processed crude oil samples in the refinery here investigated, which may explain the pronounced concentrations changes of this element measured in aqueous process stream and wastewater samples. Highest concentrations of total selenium were analyzed in samples from the hydrotreater (up to about 1800 μg L - 1 ). The predominance of selenocyanate (SeCN -) was observed in most of the wastewaters so far investigated, but also other species were detected with retention times different from Se(IV), Se(VI) and SeCN -. Colloidal selenium (Se 0) was the only Se-species observed in samples from the atmospheric distillation

  20. Fundamentals of petroleum

    SciTech Connect

    Not Available

    1986-01-01

    This book presents basic information about the petroleum industry. Nine fully illustrated chapters cover geology, exploration, leasing, drilling, production, transportation, refining and processing, marketing, and economics of the industry, with the extensive use of high tech in every phase of the industry described. A detailed index facilitates the book's use as a reference.

  1. Analysis of Petroleum Technology Advances Through Applied Research by Independent Oil Producers

    SciTech Connect

    Brashear, Jerry P.; North, Walter B.; Thomas Charles P.; Becker, Alan B.; Faulder, David D.

    2000-01-12

    Petroleum Technology Advances Through Applied Research by Independent Oil Producers is a program of the National Oil Research Program, U.S. Department of Energy. Between 1995 and 1998, the program competitively selected and cost-shared twenty-two projects with small producers. The purpose was to involve small independent producers in testing technologies of interest to them that would advance (directly or indirectly) one or more of four national program objectives: (1) Extend the productive life of reservoirs; (2) Increase production and/or reserves; (3) Improve environmental performance; and (4) Broaden the exchange of technology information.

  2. Petroleum supply monthly, March 1994

    SciTech Connect

    Not Available

    1994-03-30

    Data presented in the Petroleum Supply Monthly (PSM) describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics. The tables and figures in the Summary Statistics section of the PSM present a time series of selected petroleum data on a US level. Most time series include preliminary estimates for one month based on the Weekly Petroleum Supply Reporting System; statistics based on the most recent data from the Monthly Petroleum Supply Reporting System (MPSRS); and statistics published in prior issues of the PSM and PSA. The Detailed Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. In most cases, the statistics are presented for several geographic areas -- the United States (50 States and the District of Columbia), five PAD Districts, and 12 Refining Districts. At the US and PAD District level, the total volume and the daily rate of activities are presented. The statistics are developed from monthly survey forms submitted by respondents to the EIA and from data provided from other sources.

  3. Petroleum supply monthly, June 1993

    SciTech Connect

    Not Available

    1993-06-28

    Data presented in the Petroleum Supply Monthly (PSM) describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics. The tables and figures ih the Summary Statistics section of the PSM present a time series of selected petroleum data on a US level. Most time series include preliminary estimates for one month based on the Weekly Petroleum Supply Reporting System; statistics based on the most recent data from the Monthly Petroleum Supply Reporting System (MPSRS); and statistics published in prior issues of the PSM and PSA. The Detailed Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. In most cases, the statistics are presented for several geographic areas - - the United States (50 States and the District of Columbia), five PAD Districts, and 12 Refining Districts. At the US and PAD District level, the total volume and the daily rate of activities are presented. The statistics are developed from monthly survey forms submitted by respondents to the EIA and from data provided firom other sources.

  4. Petroleum Processing Efficiency Improvement

    SciTech Connect

    John Schabron; Joseph Rovani; Mark Sanderson; Jenny Loveridge

    2012-09-01

    A series of volatile crude oils was characterized using the Asphaltene Determinator oncolumn precipitation and re-dissolution method developed at Western Research Institute (WRI). Gravimetric asphaltenes and polars fractions from silica gel chromatography separation of the oils were characterized also. A study to define the differences in composition of asphaltenes in refinery desalter rag layer emulsions and the corresponding feed and desalter oils was conducted. Results indicate that the most polar and pericondensed aromatic material in the asphaltenes is enriched in the emulsions. The wax types and carbon number distributions in the two heptaneeluting fractions from the Waxphaltene Determinator separation were characterized by repetitive collection of the fractions followed by high temperature gas chromatography (GC) and Fourier transform infrared spectroscopy (FTIR). High resolution Fourier transform ion cyclotron resonance mass spectrometry (FT-ICRMS) was conducted by researchers at the Florida State University National High Magnetic Field laboratory in a no-cost collaboration with the study.

  5. Petroleum system analysis of the Hunton Group in West Edmond field, Oklahoma

    USGS Publications Warehouse

    Gaswirth, Stephanie B.; Higley, Debra K.

    2013-01-01

    West Edmond field, located in central Oklahoma, is one of the largest oil accumulations in the Silurian–Devonian Hunton Group in this part of the Anadarko Basin. Production from all stratigraphic units in the field exceeds 170 million barrels of oil (MMBO) and 400 billion cubic feet of gas (BCFG), of which approximately 60 MMBO and 100 BCFG have been produced from the Hunton Group. Oil and gas are stratigraphically trapped to the east against the Nemaha uplift, to the north by a regional wedge-out of Hunton strata, and by intraformational diagenetic traps. Hunton Group reservoirs are the Bois d'Arc and Frisco Limestones, with lesser production from the Chimneyhill subgroup, Haragan Shale, and Henryhouse Formation. Hunton Group cores from three wells that were examined petrographically indicate that complex diagenetic relations influence permeability and reservoir quality. Greatest porosity and permeability are associated with secondary dissolution in packstones and grainstones, forming hydrocarbon reservoirs. The overlying Devonian–Mississippian Woodford Shale is the major petroleum source rock for the Hunton Group in the field, based on one-dimensional and four-dimensional petroleum system models that were calibrated to well temperature and Woodford Shale vitrinite reflectance data. The source rock is marginally mature to mature for oil generation in the area of the West Edmond field, and migration of Woodford oil and gas from deeper parts of the basin also contributed to hydrocarbon accumulation.

  6. Uncertainty analysis of life cycle greenhouse gas emissions from petroleum-based fuels and impacts on low carbon fuel policies.

    PubMed

    Venkatesh, Aranya; Jaramillo, Paulina; Griffin, W Michael; Matthews, H Scott

    2011-01-01

    The climate change impacts of U.S. petroleum-based fuels consumption have contributed to the development of legislation supporting the introduction of low carbon alternatives, such as biofuels. However, the potential greenhouse gas (GHG) emissions reductions estimated for these policies using life cycle assessment methods are predominantly based on deterministic approaches that do not account for any uncertainty in outcomes. This may lead to unreliable and expensive decision making. In this study, the uncertainty in life cycle GHG emissions associated with petroleum-based fuels consumed in the U.S. is determined using a process-based framework and statistical modeling methods. Probability distributions fitted to available data were used to represent uncertain parameters in the life cycle model. Where data were not readily available, a partial least-squares (PLS) regression model based on existing data was developed. This was used in conjunction with probability mixture models to select appropriate distributions for specific life cycle stages. Finally, a Monte Carlo simulation was performed to generate sample output distributions. As an example of results from using these methods, the uncertainty range in life cycle GHG emissions from gasoline was shown to be 13%-higher than the typical 10% minimum emissions reductions targets specified by low carbon fuel policies.

  7. Basin analysis and petroleum potential of Michigan Basin: deposition and subsidence history from Middle Ordovician (Trenton Formation) to Early Devonian

    SciTech Connect

    Nurmi, R.D.

    1984-12-01

    The history of the Michigan basin (Early Ordovician to Early Devonian) is that of a nonuniformly subsiding basin, with the Michigan basin, at times, nearly disappearing as either a topographic feature or a depositional center. This history is interpreted from the analysis of lithostratigraphic units, time stratigraphic features, and log formats (term by J. Forgotson). These units are defined for wells throughout the Michigan basin, and they extended eastward into the Appalachian basin. The definition and thickness mapping of these lithostratigraphic units and formats are accomplished using well cuttings, cores, and wire-line geophysical well logs. From these data, it is possible to interpret the major aspects of both the subsidence and depositional history of the basin. During deposition of both the Trenton limestones and Early Silurian carbonates and shales, the Michigan basin behaved as if it were part of the greater Appalachian basin, whereas prior to the deposition of the Trenton (Middle Ordovician) and during Middle and Late Silurian, the Michigan basin was an entity separate from, and with an apparent structural independence of, the greater Appalachian basin. The structural and topography of the Trenton prior to the deposition of the Utica Shale was mapped throughout Michigan to provide insight into the nature of petroleum entrapment in the Trenton formation. The structural entrapment of petroleum in southeast Michigan contrasts with the combination diagenetic to structural Albio-Scipio trend of south-central Michigan. Evidence is available that more of these two types of traps occur in unproducing areas of the Michigan basin.

  8. Analysis of petroleum-contaminated soils by diffuse reflectance spectroscopy and sequential ultrasonic solvent extraction-gas chromatography.

    PubMed

    Okparanma, Reuben N; Coulon, Frederic; Mouazen, Abdul M

    2014-01-01

    In this study, we demonstrate that partial least-squares regression analysis with full cross-validation of spectral reflectance data estimates the amount of polycyclic aromatic hydrocarbons in petroleum-contaminated tropical rainforest soils. We applied the approach to 137 field-moist intact soil samples collected from three oil spill sites in Ogoniland in the Niger Delta province (5.317°N, 6.467°E), Nigeria. We used sequential ultrasonic solvent extraction-gas chromatography as the reference chemical method. We took soil diffuse reflectance spectra with a mobile fibre-optic visible and near-infrared spectrophotometer (350-2500 nm). Independent validation of combined data from studied sites showed reasonable prediction precision (root-mean-square error of prediction = 1.16-1.95 mg kg(-1), ratio of prediction deviation = 1.86-3.12, and validation r(2) = 0.77-0.89). This suggests that the methodology may be useful for rapid assessment of the spatial variability of polycyclic aromatic hydrocarbons in petroleum-contaminated soils in the Niger Delta to inform risk assessment and remediation. PMID:24077341

  9. Strategic Petroleum Reserve quarterly report

    SciTech Connect

    Not Available

    1993-08-15

    This Quarterly Report highlights activities undertaken during the second quarter of calendar year 1993, including: inventory of petroleum products stored in the Reserve, under contract and in transit at the end of the calendar quarter; fill rate for the current quarter and projected fill rate for the next calendar quarter; average price of the petroleum products acquired during the calendar quarter; current and projected storage capacity and plans to accelerate the acquisition or construction of such capacity; analysis of existing or anticipated problems with the acquisition and storage of petroleum products, and future expansion of storage capacity; funds obligated by the Secretary from the SPR Petroleum Account and the Strategic Petroleum Reserve Account during the prior calendar quarter and in total; and major environmental actions completed, in progress, or anticipated.

  10. The potential for low petroleum gasoline

    SciTech Connect

    Hadder, G.R.; Webb, G.M.; Clauson, M.

    1996-06-01

    The Energy Policy Act requires the Secretary of Energy to determine the feasibility of producing sufficient replacement fuels to replace at least 30 percent of the projected consumption of motor fuels by light duty vehicles in the year 2010. The Act also requires the Secretary to determine the greenhouse gas implications of the use of replacement fuels. A replacement fuel is a non-petroleum portion of gasoline, including certain alcohols, ethers, and other components. The Oak Ridge National Laboratory Refinery Yield Model has been used to study the cost and refinery impacts for production of {open_quotes}low petroleum{close_quotes} gasolines, which contain replacement fuels. The analysis suggests that high oxygenation is the key to meeting the replacement fuel target, and a major contributor to cost increase is investment in processes to produce and etherify light olefins. High oxygenation can also increase the costs of control of vapor pressure, distillation properties, and pollutant emissions of gasolines. Year-round low petroleum gasoline with near-30 percent non-petroleum components might be produced with cost increases of 23 to 37 cents per gallon of gasoline, and with greenhouse gas emissions changes between a 3 percent increase and a 16 percent decrease. Crude oil reduction, with decreased dependence on foreign sources, is a major objective of the low petroleum gasoline program. For year-round gasoline with near-30 percent non-petroleum components, crude oil use is reduced by 10 to 12 percent, at a cost $48 to $89 per barrel. Depending upon resolution of uncertainties about extrapolation of the Environmental Protection Agency Complex Model for pollutant emissions, availability of raw materials and other issues, costs could be lower or higher.

  11. Strategic petroleum reserve. Quarterly report

    SciTech Connect

    Not Available

    1994-05-15

    The Strategic Petroleum Reserve serves as one of our most important investments in reducing the Nation`s vulnerability to oil supply disruptions. Its existence provides an effective response mechanism should a disruption occur and a formidable deterrent to the use of oil as a political instrument. The Strategic Petroleum Reserve was created pursuant to the Energy Policy and Conservation Act of December 22, 1975, (Public Law 94-163) as amended, to reduce the impact of disruptions in supplies of petroleum products and to carry out obligations of the United States under the Agreement on an International Energy Program. Section 165(a) of the Act requires the submission of Annual Reports and Section 165(b)(1) requires the submission of Quarterly Reports. This Quarterly Report highlights activities undertaken during the first quarter of calendar year 1994, including: (1) inventory of petroleum products stored in the Reserve, under contract and in transit at the end of the calendar quarter; (2) fill rate for the current quarter and projected fill rate for the next calendar quarter; (3) average price of the petroleum products acquired during the calendar quarter; (4) current and projected storage capacity; (5) analysis of existing or anticipated problems with the acquisition and storage of petroleum products, and future expansion of storage capacity; (6) funds obligated by the Secretary from the SPR Petroleum Account and the Strategic Petroleum Reserve Account during the prior calendar quarter and in total; and (7) major environmental actions completed, in progress, or anticipated.

  12. Phillips Petroleum`s Seastar Project

    SciTech Connect

    Upchurch, J.L.; Money, R.P.

    1997-02-01

    On May 1, 1995 Phillips Petroleum`s Seastar Project began production as the first cluster-type subsea development in the Gulf of Mexico. Seastar production reached approximately 60 million cubic feet of gas per day (mmscfd) in November 1995 with the completion of a second {open_quotes}sales{close_quotes} line (a pipeline that transports the petroleum to shore) at the Vermilion Block 386-B host platform. Currently, the field is producing 40 to 50 mmscfd and plans are on schedule for the addition of a third producing well during the first quarter of 1997. All of the subsea equipment was installed using a drilling vessel and onboard ROV support. The Seastar project began in 1987 when Phillips and its partners leased Garden Banks Blocks 70 and 71, located 110 miles south of Cameron Louisiana. The partnership drilled two wells in 1990 that discovered noncommercial hydrocarbon reserves. Following a reevaluation of the seismic data, Phillips assumed 100 percent ownership in the leases and drilled Garden Banks 71 No. 2, which discovered 350 feet of {open_quotes}pay{close_quotes} sand (oil resource) in March 1993. The initial phase of the project consisted of two satellite subsea trees tied back to a four-slot retrievable subsea manifold in 760 feet of water. Commingled gas production is delivered via dual subsea pipelines to a host platform processing facility in 300 feet of water 13 miles away in Vermilion Block 386-B, thence via sales lines to shore.

  13. Direct hydro-liquefaction of sawdust in petroleum ether and comprehensive bio-oil products analysis.

    PubMed

    Liu, Dong; Song, Linhua; Wu, Pingping; Liu, Yan; Li, Qingyin; Yan, Zifeng

    2014-03-01

    The effect of temperature, time, hydrogen pressure and amount of catalyst on production distribution and the bio-oil yield obtained from the direct liquefaction of sawdust in the petroleum ether (60-90°C) are investigated. The highest sawdust conversion obtained was 72.32% with a bio-oil yield of 47.69% were obtained at 370°C, 40min and 5wt.% catalyst content with the initial H2 pressure of 3.0MPa. Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) approach was utilized to analyze the non-volatile fraction. In this study, the composition of bio-oil could be analyzed in an unprecedented detail through a combination of GC-MS and FT-ICR MS techniques. PMID:24445192

  14. Analysis of well logging methods in volcanic and volcano sedimentary rocks from Pina petroleum field

    SciTech Connect

    Rodriquez, N.

    1996-09-01

    Petrophysical, petrological and geophysical methods have been applied to prospecting and well logging for several petroleum fields in Cuba. The most common reservoir in these fields are carbonate rocks. However, the Pina field, in the Central region of the island, distinguishes itself by the good quality of the oil and the volcano sedimentary and volcanic character of the reservoirs. These rocks have peculiar geophysical responses, which is why the study of these methods and the development of the interpretation methods is very important. Integrated geological and geophysical information was necessary during the drilling of wells in the Pina field in order to evaluate the hydrocarbon potential. GEONUC code permits us to use different ways to solve questions about interpretation of well logging in the volcanic sedimentary rocks. This code gives us the opportunity to analyze complex methods.

  15. Naval petroleum reserves: Preliminary analysis of future net revenues from Elk Hills production

    SciTech Connect

    Not Available

    1986-01-01

    This is an interim report on the present value of the net revenues from Elk Hills Naval Petroleum Reserve. GAO calculated alternative present values of the net revenues applying (1) low, medium, and high forecasts of future crude oil prices and (2) alternative interest rates for discounting the future net revenues to their present values. The calculations are sensitive to both the oil price forecasts and discount rates used; they are preliminary and should be used with caution. They do not take into account possible added tax revenues collected by the government if Elk Hills were sold nor varying production levels and practices, which could either increase or decrease the total amount of oil that can be extracted.

  16. A software surety analysis process

    SciTech Connect

    Trauth, S.; Tempel, P.

    1995-11-01

    As part of the High Consequence System Surety project, this work was undertaken to explore, one approach to conducting a surety theme analysis for a software-driven system. Originally, plans were to develop a theoretical approach to the analysis, and then to validate and refine this process by applying it to the software being developed for the Weight and Leak Check System (WALS), an automated nuclear weapon component handling system. As with the development of the higher level High consequence System surety Process, this work was not completed due to changes in funding levels. This document describes the software analysis process, discusses its application in a software, environment, and outlines next steps that could be taken to further develop and apply the approach to projects.

  17. Basin Analysis and Petroleum System Characterisation of Western Bredasdorp Basin, Southern Offshore of South Africa: Insights from a 3d Crust-Scale Basin Model - (Phase 1)

    NASA Astrophysics Data System (ADS)

    Sonibare, W. A.; Scheck-Wenderoth, M.; Sippel, J.; Mikeš, D.

    2012-04-01

    In recent years, construction of 3D geological models and their subsequent upscaling for reservoir simulation has become an important tool within the oil industry for managing hydrocarbon reservoirs and increasing recovery rate. Incorporating petroleum system elements (i.e. source, reservoir and trap) into these models is a relatively new concept that seems very promising to play/prospect risk assessment and reservoir characterisation alike. However, yet to be fully integrated into this multi-disciplinary modelling approach are the qualitative and quantitative impacts of crust-scale basin dynamics on the observed basin-fill architecture and geometries. The focus of this study i.e. Western Bredasdorp Basin constitutes the extreme western section of the larger Bredasdorp sub-basin, which is the westernmost depocentre of the four southern Africa offshore sub-basins (others being Pletmos, Gamtoos and Algoa). These basins, which appear to be initiated by volcanically influenced continental rifting and break-up related to passive margin evolution (during the Mid-Late Jurassic to latest Valanginian), remain previously unstudied for crust-scale basin margin evolution, and particularly in terms of relating deep crustal processes to depo-system reconstruction and petroleum system evolution. Seismic interpretation of 42 2D seismic-reflection profiles forms the basis for maps of 6 stratigraphic horizons which record the syn-rift to post-rift (i.e. early drift and late drift to present-day seafloor) successions. In addition to this established seismic markers, high quality seismic profiles have shown evidence for a pre-rift sequence (i.e. older than Late Jurassic >130 Ma). The first goal of this study is the construction of a 3D gravity-constrained, crust-scale basin model from integration of seismics, well data and cores. This basin model is constructed using GMS (in-house GFZ Geo-Modelling Software) while testing its consistency with the gravity field is performed using IGMAS

  18. Dynamic analysis of process reactors

    SciTech Connect

    Shadle, L.J.; Lawson, L.O.; Noel, S.D.

    1996-12-31

    The process design for integration of advanced gasifiers for combined-cycle facilities requires a dynamic analysis tool for predicting the gasifier performance and stability. Such a tool provides an understanding of both process reactions and the interaction of process components. To illustrate the utility of the process dynamic tool, a Gasifier Dynamic Model (GDM) was developed at the Morgantown Energy Technology Center (METC) to investigate alternative designs and operational scenarios during process design development. Empirical data and first principles were combined into steady-state process models to develop sensitivity parameters around a nominal process design condition. These gain factors were then coupled with time-dependent functions for process mass and energy inventories to develop the dynamic model (GDM). Engineering calculations performed in the GDM were used to predict process responses such as gas make, flow, pressure, and temperature. Small research facilities were constructed and operated to validate both the steady-state process and dynamic models. GDM predictions provided engineers insights into the design integrity and operational safety of the reactions, components, and control elements.

  19. Logistics Process Analysis ToolProcess Analysis Tool

    SciTech Connect

    2008-03-31

    LPAT is the resulting integrated system between ANL-developed Enhanced Logistics Intra Theater Support Tool (ELIST) sponsored by SDDC-TEA and the Fort Future Virtual Installation Tool (sponsored by CERL). The Fort Future Simulation Engine was an application written in the ANL Repast Simphony framework and used as the basis for the process Anlysis Tool (PAT) which evolved into a stand=-along tool for detailed process analysis at a location. Combined with ELIST, an inter-installation logistics component was added to enable users to define large logistical agent-based models without having to program. PAT is the evolution of an ANL-developed software system called Fort Future Virtual Installation Tool (sponsored by CERL). The Fort Future Simulation Engine was an application written in the ANL Repast Simphony framework and used as the basis for the Process Analysis Tool(PAT) which evolved into a stand-alone tool for detailed process analysis at a location (sponsored by the SDDC-TEA).

  20. Logistics Process Analysis ToolProcess Analysis Tool

    2008-03-31

    LPAT is the resulting integrated system between ANL-developed Enhanced Logistics Intra Theater Support Tool (ELIST) sponsored by SDDC-TEA and the Fort Future Virtual Installation Tool (sponsored by CERL). The Fort Future Simulation Engine was an application written in the ANL Repast Simphony framework and used as the basis for the process Anlysis Tool (PAT) which evolved into a stand=-along tool for detailed process analysis at a location. Combined with ELIST, an inter-installation logistics component wasmore » added to enable users to define large logistical agent-based models without having to program. PAT is the evolution of an ANL-developed software system called Fort Future Virtual Installation Tool (sponsored by CERL). The Fort Future Simulation Engine was an application written in the ANL Repast Simphony framework and used as the basis for the Process Analysis Tool(PAT) which evolved into a stand-alone tool for detailed process analysis at a location (sponsored by the SDDC-TEA).« less

  1. 31 CFR 576.308 - Iraqi petroleum and petroleum products.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Iraqi petroleum and petroleum products... SANCTIONS REGULATIONS General Definitions § 576.308 Iraqi petroleum and petroleum products. The term Iraqi petroleum and petroleum products means any petroleum, petroleum products, or natural gas originating in...

  2. 31 CFR 576.308 - Iraqi petroleum and petroleum products.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Iraqi petroleum and petroleum products... SANCTIONS REGULATIONS General Definitions § 576.308 Iraqi petroleum and petroleum products. The term Iraqi petroleum and petroleum products means any petroleum, petroleum products, or natural gas originating in...

  3. 31 CFR 576.308 - Iraqi petroleum and petroleum products.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Iraqi petroleum and petroleum products... SANCTIONS REGULATIONS General Definitions § 576.308 Iraqi petroleum and petroleum products. The term Iraqi petroleum and petroleum products means any petroleum, petroleum products, or natural gas originating in...

  4. 31 CFR 576.308 - Iraqi petroleum and petroleum products.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Iraqi petroleum and petroleum products... SANCTIONS REGULATIONS General Definitions § 576.308 Iraqi petroleum and petroleum products. The term Iraqi petroleum and petroleum products means any petroleum, petroleum products, or natural gas originating in...

  5. The United Nations Framework Classification for World Petroleum Resources

    USGS Publications Warehouse

    Ahlbrandt, T.S.; Blystad, P.; Young, E.D.; Slavov, S.; Heiberg, S.

    2003-01-01

    The United Nations has developed an international framework classification for solid fuels and minerals (UNFC). This is now being extended to petroleum by building on the joint classification of the Society of Petroleum Engineers (SPE), the World Petroleum Congresses (WPC) and the American Association of Petroleum Geologists (AAPG). The UNFC is a 3-dimansional classification. This: Is necessary in order to migrate accounts of resource quantities that are developed on one or two of the axes to the common basis; Provides for more precise reporting and analysis. This is particularly useful in analyses of contingent resources. The characteristics of the SPE/WPC/AAPG classification has been preserved and enhanced to facilitate improved international and national petroleum resource management, corporate business process management and financial reporting. A UN intergovernmental committee responsible for extending the UNFC to extractive energy resources (coal, petroleum and uranium) will meet in Geneva on October 30th and 31st to review experiences gained and comments received during 2003. A recommended classification will then be delivered for consideration to the United Nations through the Committee on Sustainable Energy of the Economic Commission for Europe (UN ECE).

  6. Geomechanical analysis to predict the oil leak at the wellbores in Big Hill Strategic Petroleum Reserve

    SciTech Connect

    Park, Byoung Yoon

    2014-02-01

    Oil leaks were found in wellbores of Caverns 105 and 109 at the Big Hill Strategic Petroleum Reserve site. According to the field observations, two instances of casing damage occurred at the depth of the interbed between the caprock bottom and salt top. A three dimensional finite element model, which contains wellbore element blocks and allows each cavern to be configured individually, is constructed to investigate the wellbore damage mechanism. The model also contains element blocks to represent interface between each lithology and a shear zone to examine the interbed behavior in a realistic manner. The causes of the damaged casing segments are a result of vertical and horizontal movements of the interbed between the caprock and salt dome. The salt top subsides because the volume of caverns below the salt top decrease with time due to salt creep closure, while the caprock subsides at a slower rate because the caprock is thick and stiffer. This discrepancy yields a deformation of the well. The deformed wellbore may fail at some time. An oil leak occurs when the wellbore fails. A possible oil leak date of each well is determined using the equivalent plastic strain failure criterion. A well grading system for a remediation plan is developed based on the predicted leak dates of each wellbore.

  7. Petroleum Supply Monthly, September 1990. [Contains glossary

    SciTech Connect

    Whited, D.; Jacobus, P.

    1990-11-28

    Data presented in this PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in Primary Supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. 12 figs., 46 tabs.

  8. Petroleum supply monthly, October 1991. [Contains glossary

    SciTech Connect

    Not Available

    1991-10-30

    Data presented in this report describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in Primary Supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importer, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data are divided into two sections (1) the Summary Statistics and (2) the Detailed Statistics 14 figs., 56 tabs.

  9. Petroleum supply monthly, October 1990. [Contains Glossary

    SciTech Connect

    Not Available

    1990-12-27

    Data presented in this report describes the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in Primary Supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. 12 figs., 54 tabs.

  10. Strategic petroleum reserve. Quarterly report

    SciTech Connect

    1995-08-15

    The Strategic Petroleum Reserve reduces the Nation`s vulnerability to oil supply disruptions. Its existence provides a formidable deterrent to the use of oil as a political instrument and an effective response mechanism should a disruption occur. The Strategic Petroleum Reserve was created pursuant to the Energy Policy and Conservation Act of December 22, 1975 (Public Law 94-163). Its purposes are to reduce the impact of disruptions in supplies of petroleum products and to carry out obligations of the United States under the Agreement on an International Energy Program. Section 165(a) of the Act requires the submission of Annual Reports and Section 165(b)(1) requires the submission of Quarterly Reports. This Quarterly Report highlights activities undertaken during the second quarter of calendar year 1995, including: inventory of petroleum products stored in the Reserve; current and projected storage capacity, analysis of existing or anticipated problems with the acquisition and storage of petroleum products, and future expansion of storage capacity; funds obligated by the Secretary from the SPR Petroleum Account and the Strategic Petroleum Reserve Account during the prior calendar quarter and in total; and major environmental actions completed, in progress, or anticipated.

  11. A critical review of cancer epidemiology in the petroleum industry, with a meta-analysis of a combined database of more than 350,000 workers.

    PubMed

    Wong, O; Raabe, G K

    2000-08-01

    In 1989 we published a critical review of cancer epidemiology in petroleum workers, which included as a component of the review a meta-analysis by cancer site. Subsequently we have completed three additional reviews and meta-analyses on cell-type-specific leukemias (1995), multiple myeloma (1997), and non-Hodgkin's lymphoma (2000). The objective of the present investigation was to update our 1989 review and meta-analysis of nonlymphohematopoietic cancers in cohort studies of petroleum workers. Included in the present investigation were cohort studies of petroleum workers from the United States, the United Kingdom, Canada, Australia, Finland, Sweden, and Italy. Individual studies were reviewed with regard to specific cancer sites. For each cancer of interest, risk ratios from the individual studies were presented. In some studies, subcohort analyses stratified by exposure parameters such as length of employment, job category, and hire year were also reported. These subcohort or stratified analyses were reviewed and the results of these analyses were taken into consideration in our interpretation. In addition to the qualitative review of individual studies, a meta-analysis was performed to combine data from individual cohort studies of petroleum workers. The primary purpose of the meta-analysis was to provide a summary measure of risk for each cancer site. Based on a review and meta-analyses of cohort studies of more than 350,000 petroleum workers in the United States, the United Kingdom, Canada, Australia, Finland, Sweden, and Italy, we concluded that there was no increased mortality from digestive cancers (stomach, large intestine, liver, or pancreas), lung cancer, bladder cancer, kidney cancer, or brain cancer. The summary standardized mortality ratios for these cancer sites were all below unity. Significant increases of melanoma mortality were reported in some small groups of refinery workers in the United Kingdom and upstream operation workers in Canada, but no

  12. Command Process Modeling & Risk Analysis

    NASA Technical Reports Server (NTRS)

    Meshkat, Leila

    2011-01-01

    Commanding Errors may be caused by a variety of root causes. It's important to understand the relative significance of each of these causes for making institutional investment decisions. One of these causes is the lack of standardized processes and procedures for command and control. We mitigate this problem by building periodic tables and models corresponding to key functions within it. These models include simulation analysis and probabilistic risk assessment models.

  13. Preliminary hazards analysis -- vitrification process

    SciTech Connect

    Coordes, D.; Ruggieri, M.; Russell, J.; TenBrook, W.; Yimbo, P.

    1994-06-01

    This paper presents a Preliminary Hazards Analysis (PHA) for mixed waste vitrification by joule heating. The purpose of performing a PHA is to establish an initial hazard categorization for a DOE nuclear facility and to identify those processes and structures which may have an impact on or be important to safety. The PHA is typically performed during and provides input to project conceptual design. The PHA is then followed by a Preliminary Safety Analysis Report (PSAR) performed during Title 1 and 2 design. The PSAR then leads to performance of the Final Safety Analysis Report performed during the facility`s construction and testing. It should be completed before routine operation of the facility commences. This PHA addresses the first four chapters of the safety analysis process, in accordance with the requirements of DOE Safety Guidelines in SG 830.110. The hazards associated with vitrification processes are evaluated using standard safety analysis methods which include: identification of credible potential hazardous energy sources; identification of preventative features of the facility or system; identification of mitigative features; and analyses of credible hazards. Maximal facility inventories of radioactive and hazardous materials are postulated to evaluate worst case accident consequences. These inventories were based on DOE-STD-1027-92 guidance and the surrogate waste streams defined by Mayberry, et al. Radiological assessments indicate that a facility, depending on the radioactive material inventory, may be an exempt, Category 3, or Category 2 facility. The calculated impacts would result in no significant impact to offsite personnel or the environment. Hazardous materials assessment indicates that a Mixed Waste Vitrification facility will be a Low Hazard facility having minimal impacts to offsite personnel and the environment.

  14. Analysis and occurrence of C 26-steranes in petroleum and source rocks

    NASA Astrophysics Data System (ADS)

    Moldowan, J. Michael; Lee, Cathy Y.; Watt, David S.; Jeganathan, Alwarsamy; Slougui, Nacer-Eddine; Gallegos, Emilio J.

    1991-04-01

    The C 26-steranes previously reported in oils and source rocks (MOLDOWAN et al., 1985) have been identified as 21-, 24-, and 27-norcholestanes (1A, 1B, and 1C). Various 24-norcholesterols or stanols, possible precursors for the 24-norcholestanes, occur widely at low levels in marine invertebrates and some algae, and 24-norcholestanes occur in marine petroleums of Tertiary through Paleozoic age. There are reports of 27-norcholesterols and stanols in recent sediments, but the precursor organisms have not been identified. The natural occurrence of the 21-norcholestane structure is unprecedented. Unlike 24- and 27-norcholestane, 21-norcholestane is in low concentration or absent in immature rocks and increases substantially relative to the other C 26-steranes in thermally mature rocks, oils, and condensates. This suggests an origin involving thermal degradation of a higher molecular weight steroid. The ratio of 21-norcholestane to the total C 26-steranes is shown to be an effective maturity parameter in a series of Wyoming (Phosphoria source) and California (Monterey source) oils. Molecular mechanics MM2 steric energy calculations indicate a relative stability order of 21 ≫ 27 > 24- norcholestane for the major stereoisomers. Authentic 21-, 24-, and 27-nor-5α-cholestanes and 24- and 27-nor-5β-cholestanes were synthesized and subjected to catalytic isomerization over Pd/C to yield the full suite of stereoisomers for each. In immature rocks the 5α,14α,17α(H),20R isomers predominate. Mixtures of 24- and 27-norcholestane in oils and mature rocks show a familiar elution pattern of four major peaks presumed to be 14α,17α(H),20S, 14β,17β(H),20R, 14β,17β(H),20S, and 14α,17α(H),20R in order of elution, as well as putative 20S and 20R rearranged steranes [13β,17α(H)-diasteranes]. However, the 21-norcholestanes are represented by a single peak in mature sediments under normal GC conditions, which is shown to consist of a major 14β,17α(H) peak and a minor 14α,17

  15. Instrumenting the Intelligence Analysis Process

    SciTech Connect

    Hampson, Ernest; Cowley, Paula J.

    2005-05-02

    The Advanced Research and Development Activity initiated the Novel Intelligence from Massive Data (NIMD) program to develop advanced analytic technologies and methodologies. In order to support this objective, researchers and developers need to understand what analysts do and how they do it. In the past, this knowledge generally was acquired through subjective feedback from analysts. NIMD established the innovative Glass Box Analysis (GBA) Project to instrument a live intelligence mission and unobtrusively capture and objectively study the analysis process. Instrumenting the analysis process requires tailor-made software hooks that grab data from a myriad of disparate application operations and feed into a complex relational database and hierarchical file store to collect, store, retrieve, and distribute analytic data in a manner that maximizes researchers’ understanding. A key to success is determining the correct data to collect and aggregate low-level data into meaningful analytic events. This paper will examine how the GBA team solved some of these challenges, continues to address others, and supports a growing user community in establishing their own GBA environments and/or studying the data generated by GBA analysts working in the Glass Box.

  16. Reclamation and reuse of Freon in total petroleum hydrocarbon analyses

    SciTech Connect

    Ekechukwu, A.A.; Young, J.E.

    1997-12-31

    At the Savannah River Technology Center (SRTC), we have successfully demonstrated the use of a solvent recycling system to reclaim spent Freon solvent in total petroleum hydrocarbon (TPH) analyses of radioactive samples. A wide variety of sample types including ground water, organics, laboratory waste, process control, sludge, soils, and others are received by our lab for total petroleum hydrocarbon analysis. This paper demonstrates the successful use of a commercially available carbon bed recycle system which we modified to enable the recovery of 95-98 percent of the radioactive contaminated Freon. This system has been used successfully in our lab for the past three years.

  17. Study of the petroleum schedules thermal cleaning process from asphalt, ressin and paraffin deposits using low- temperature plasma

    NASA Astrophysics Data System (ADS)

    Samigullin, A. D.; Galiakbarov, A. T.; Galiakbarov, R. T.

    2016-01-01

    Petroleum industry uses large amount of pumping and compression pipes. Carrying out the whole range of repair works requires cleaning of the pipe inner surface from deposits which appeared in it during operation [1]. The task of asphalt, resin and paraffin deposits control remains one of the most essential for the branch. The article deals with thermal method and device for asphalt, resin and paraffin deposits removal from pumping and compression pipes inner surface, describes and provides the device application scope for cleaning the pumping and compression pipes inner surface. To deal with borehole equipment and pipe systems waxing problem various deposit prevention and removal methods are used, including mechanical, thermal, chemical, combined and nonconventional methods.

  18. World petroleum systems with Jurassic source rocks

    SciTech Connect

    Klemme, H.D. )

    1993-11-08

    Fourteen petroleum systems with Upper Jurassic source rocks contain one quarter of the world's discovered oil and gas. Eleven other systems with Lower and Middle Jurassic source rocks presently have a minor but significant amount of discovered oil and gas. The purpose of this article is to review the systems geologically, describe their location in space and time on a continental scale, estimate their relative petroleum system recovery efficiencies, and outline the effect their essential elements and processes have on their petroleum plumbing.

  19. BASIN ANALYSIS AND PETROLEUM SYSTEM CHARACTERIZATION AND MODELING, INTERIOR SALT BASINS, CENTRAL AND EASTERN GULF OF MEXICO

    SciTech Connect

    Ernest A. Mancini; Donald A. Goddard

    2005-08-01

    The principal research effort for Year 3 of the project is basin modeling and petroleum system identification, comparative basin evaluation and resource assessment. In the first six (6) months of Year 3, the research focus is on basin modeling and petroleum system identification and the remainder of the year the emphasis is on the comparative basin evaluation and resource assessment. No major problems have been encountered to date, and the project is on schedule.

  20. Overview of infrared in the petroleum industry

    NASA Astrophysics Data System (ADS)

    Ohliger, Albert A.

    2003-04-01

    Infrared Thermography has been found to be a very valuable tool in the petroleum industry. It has had focus in surveying all the types of equipment in its asset base. This includes electrical distribution systems, pumping systems, piping systems, exchangers, flares, process fired heaters and many other types of equipment. The petroleum industry is divided into three basic operating areas; Upstream, Midstream and Downstream. Upstream operation covers the exploration, drilling and production of natural gas and crude oil. Midstream operation in the petroleum industry is the distribution and storage system between the Upstream to the Downstream systems. Downstream operations make the finished energy product and are the refineries and chemical plants. As in other industries, the petroleum industry has mechanical equipment, electrical equipment, pressure-containing equipment, and fixed structures. In addition to this equipment, there is some specialty equipment which includes items such as fired heaters and specialty process vessels. The industry has put in place infrared programs as a predictive maintenance tool in many of their operating areas. Using infrared to monitor the operating integrity on equipment is one of the synergies now being better developed. The opportunity is to define measurable thermal patterns that can be used to define defects and predict failures. Infrared technology is a mature reliability work process and been around for many years. The first commercial infrared camera was available in the '70's. These radiometric cameras and the support equipment have had many improvements since then. The use of the technology has also been improved with synergies incorporated from many type of industries, including the military. Infrared is a technology that has been added to the predictive & preventative maintenance toolbox of the petroleum industry reliability focus. An important part of any reliability work process is to have predictive tools to define

  1. Coal liquefaction process streams characterization and evaluation. FIMS analysis of direct coal liquefaction process streams

    SciTech Connect

    Malhotra, R.; McMillen, D.F.

    1994-03-01

    This study was designed to apply the method of field ionization mass spectrometry (FIMS) for the analysis of direct coal liquefaction process-stream samples. The FIMS method was shown to have a high potential for application to direct coal liquefaction-derived samples in a Phase 1 project in this program. In this Phase 3 project, the FIMS method was applied to a set of samples produced in HRI bench-scale liquefaction Runs CC-15 and CC-16. FIMS was used to obtain the molecular weight profile of the samples and to identify specific prominent peaks in the low end (160--420 Da) region of the molecular weight profile. In the samples examined in this study, species were identified which previously were recognized as precursors to the formation of high molecular weight structures associated with the formation of coke in petroleum vacuum gas oils.

  2. Structural analysis of vibroacoustical processes

    NASA Technical Reports Server (NTRS)

    Gromov, A. P.; Myasnikov, L. L.; Myasnikova, Y. N.; Finagin, B. A.

    1973-01-01

    The method of automatic identification of acoustical signals, by means of the segmentation was used to investigate noises and vibrations in machines and mechanisms, for cybernetic diagnostics. The structural analysis consists of presentation of a noise or vibroacoustical signal as a sequence of segments, determined by the time quantization, in which each segment is characterized by specific spectral characteristics. The structural spectrum is plotted as a histogram of the segments, also as a relation of the probability density of appearance of a segment to the segment type. It is assumed that the conditions of ergodic processes are maintained.

  3. Radar data processing and analysis

    NASA Technical Reports Server (NTRS)

    Ausherman, D.; Larson, R.; Liskow, C.

    1976-01-01

    Digitized four-channel radar images corresponding to particular areas from the Phoenix and Huntington test sites were generated in conjunction with prior experiments performed to collect X- and L-band synthetic aperture radar imagery of these two areas. The methods for generating this imagery are documented. A secondary objective was the investigation of digital processing techniques for extraction of information from the multiband radar image data. Following the digitization, the remaining resources permitted a preliminary machine analysis to be performed on portions of the radar image data. The results, although necessarily limited, are reported.

  4. Quasi-Monte Carlo based global uncertainty and sensitivity analysis in modeling free product migration and recovery from petroleum-contaminated aquifers.

    PubMed

    He, Li; Huang, Gordon; Lu, Hongwei; Wang, Shuo; Xu, Yi

    2012-06-15

    This paper presents a global uncertainty and sensitivity analysis (GUSA) framework based on global sensitivity analysis (GSA) and generalized likelihood uncertainty estimation (GLUE) methods. Quasi-Monte Carlo (QMC) is employed by GUSA to obtain realizations of uncertain parameters, which are then input to the simulation model for analysis. Compared to GLUE, GUSA can not only evaluate global sensitivity and uncertainty of modeling parameter sets, but also quantify the uncertainty in modeling prediction sets. Moreover, GUSA's another advantage lies in alleviation of computational effort, since those globally-insensitive parameters can be identified and removed from the uncertain-parameter set. GUSA is applied to a practical petroleum-contaminated site in Canada to investigate free product migration and recovery processes under aquifer remediation operations. Results from global sensitivity analysis show that (1) initial free product thickness has the most significant impact on total recovery volume but least impact on residual free product thickness and recovery rate; (2) total recovery volume and recovery rate are sensitive to residual LNAPL phase saturations and soil porosity. Results from uncertainty predictions reveal that the residual thickness would remain high and almost unchanged after about half-year of skimmer-well scheme; the rather high residual thickness (0.73-1.56 m 20 years later) indicates that natural attenuation would not be suitable for the remediation. The largest total recovery volume would be from water pumping, followed by vacuum pumping, and then skimmer. The recovery rates of the three schemes would rapidly decrease after 2 years (less than 0.05 m(3)/day), thus short-term remediation is not suggested.

  5. Digital recovery, modification, and analysis of Tetra Tech seismic horizon mapping, National Petroleum Reserve Alaska (NPRA), northern Alaska

    USGS Publications Warehouse

    Saltus, R.W.; Kulander, Christopher S.; Potter, Christopher J.

    2002-01-01

    We have digitized, modified, and analyzed seismic interpretation maps of 12 subsurface stratigraphic horizons spanning portions of the National Petroleum Reserve in Alaska (NPRA). These original maps were prepared by Tetra Tech, Inc., based on about 15,000 miles of seismic data collected from 1974 to 1981. We have also digitized interpreted faults and seismic velocities from Tetra Tech maps. The seismic surfaces were digitized as two-way travel time horizons and converted to depth using Tetra Tech seismic velocities. The depth surfaces were then modified by long-wavelength corrections based on recent USGS seismic re-interpretation along regional seismic lines. We have developed and executed an algorithm to identify and calculate statistics on the area, volume, height, and depth of closed structures based on these seismic horizons. These closure statistics are tabulated and have been used as input to oil and gas assessment calculations for the region. Directories accompanying this report contain basic digitized data, processed data, maps, tabulations of closure statistics, and software relating to this project.

  6. Aqueous solubility calculation for petroleum mixtures in soil using comprehensive two-dimensional gas chromatography analysis data.

    PubMed

    Mao, Debin; Lookman, Richard; Van De Weghe, Hendrik; Vanermen, Guido; De Brucker, Nicole; Diels, Ludo

    2009-04-01

    An assessment of aqueous solubility (leaching potential) of soil contaminations with petroleum hydrocarbons (TPH) is important in the context of the evaluation of (migration) risks and soil/groundwater remediation. Field measurements using monitoring wells often overestimate real TPH concentrations in case of presence of pure oil in the screened interval of the well. This paper presents a method to calculate TPH equilibrium concentrations in groundwater using soil analysis by high-performance liquid chromatography followed by comprehensive two-dimensional gas chromatography (HPLC-GCXGC). The oil in the soil sample is divided into 79 defined hydrocarbon fractions on two GCXGC color plots. To each of these fractions a representative water solubility is assigned. Overall equilibrium water solubility of the non-aqueous phase liquid (NAPL) present in the sample and the water phase's chemical composition (in terms of the 79 fractions defined) are then calculated using Raoult's law. The calculation method was validated using soil spiked with 13 different TPH mixtures and 1 field-contaminated soil. Measured water solubilities using a column recirculation equilibration experiment agreed well to calculated equilibrium concentrations and water phase TPH composition.

  7. Analysis of alkyl phosphates in petroleum samples by comprehensive two-dimensional gas chromatography with nitrogen phosphorus detection and post-column Deans switching.

    PubMed

    Nizio, Katie D; Harynuk, James J

    2012-08-24

    Alkyl phosphate based gellants used as viscosity builders for fracturing fluids used in the process of hydraulic fracturing have been implicated in numerous refinery-fouling incidents in North America. In response, industry developed an inductively coupled plasma optical emission spectroscopy (ICP-OES) based method for the analysis of total volatile phosphorus in distillate fractions of crude oil; however, this method is plagued by poor precision and a high limit of detection (0.5±1μg phosphorus mL(-1)). Furthermore this method cannot provide speciation information, which is critical for developing an understanding of the challenge of alkyl phosphates at a molecular level. An approach using comprehensive two-dimensional gas chromatography with nitrogen phosphorus detection (GC×GC-NPD) and post-column Deans switching is presented. This method provides qualitative and quantitative profiles of alkyl phosphates in industrial petroleum samples with increased precision and at levels comparable to or below those achievable by ICP-OES. A recovery study in a fracturing fluid sample and a profiling study of alkyl phosphates in four recovered fracturing fluid/crude oil mixtures (flowback) are also presented. PMID:22776725

  8. Basin Analysis of the Mississippi Interior Salt Basin and Petroleum System Modeling of the Jurassic Smackover Formation, Eastern Gulf Coastal Plain

    SciTech Connect

    Mancini, Ernest A.

    2003-02-06

    The project objectives are improving access to information for the Mississippi Interior Salt Basin by inventorying data files and records of the major information repositories in the region, making these inventories easily accessible in electronic format, increasing the amount of information available on domestic sedimentary basins through a comprehensive analysis of the Mississippi Interior Salt Basin, and enhancing the understanding of the petroleum systems operating in the Mississippi Interior Salt Basin.

  9. Chemical fingerprinting of petroleum biomarkers in biota samples using retention-time locking chromatography and multivariate analysis.

    PubMed

    Bartolomé, Luis; Deusto, Miren; Etxebarria, Nestor; Navarro, Patricia; Usobiaga, Aresatz; Zuloaga, Olatz

    2007-07-20

    This work was conducted to study a new separation and evaluation approach for the chemical fingerprinting of petroleum biomarkers in biota samples. The final aim of this work was to study the correlation between the observed effects in the shore habitats (mussels and limpets) and one pollution source: the oil spill of the Prestige tanker. The method combined a clean-up step of the biota extracts (mussels and limpets), the retention-time locking of the gas chromatographic set up, and the multivariate data analysis of the chromatograms. For clean-up, solid-phase extraction and gel permeation chromatography were compared, and 5g Florisil cartridges assured the lack of interfering compounds in the last extracts. In order to assure reproducible retention times and to avoid the realignment of the chromatograms, the retention-time locking feature of our gas chromatography-mass spectrometry (GC-MS) set up was used. Finally, in the case of multivariate analysis, the GC-MS chromatograms were treated, essentially by derivatization and by normalization, and all the chromatograms at m/z 191 (terpenes), m/z 217-218 (steranes and diasteranes) and m/z 231 (triaromatic steranes) were treated by means of principal component analysis. Furthermore, slightly different four oil samples from the Prestige oil spill were analyzed following the Nordtest method, and the GC-MS chromatograms were considered as the reference chemical fingerprints of the sources. In this sense, the correlation between the studied samples, including sediments and biota samples, and the source candidate was completed by means of a supervised pattern recognition method. As a result, the method proposed in this work was useful to identify the Prestige oil spill as the source of many of the analyzed samples.

  10. Petroleum-specific analytical and interpretive techniques for product identification and source allocation

    SciTech Connect

    Dahlen, D.T.; Uhler, A.D.; Sauer, T.C.; McCarthy, K.J.

    1995-12-31

    As a class, petroleum and refined petroleum products represent the single largest source of contamination to the terrestrial and aquatic environments. Petroleum products including crude oil and a wide spectrum of refined petroleum products are accidentally released by a variety of mechanisms including surface spills, tanker accidents, storage tank leaks, and pipeline ruptures. In many cases, the petroleum and other hydrocarbon products discovered in impacted environments usually cannot be readily linked to a source, because the products are often complex mixtures of various hydrocarbon-based components. The identification of hydrocarbon products in the environment is further confounded by complex physical, chemical, and biological mechanisms that alter the fresh hydrocarbons through processes known collectively as weathering. The dilution, mixing, transport, and weathering of these hydrocarbon materials in the environment renders them very different in composition and appearance from their original source materials. This paper describes the use of EPA methods of analysis that have been modified for measurement of a large suite of petrogenic organic compounds that can be used for sensitive measurement of fresh and degraded petroleum in environmental samples ranging from volatile products such as gasoline to heavy crude oils. Petroleum specific data is reduced using multivariate chemometric techniques including hierarchal cluster analysis (HCA) and principal component analysis to evaluate linkage between the samples and likely petroleum source products. Combined with high quality, petroleum specific data, these analysis techniques offer unparalleled means of identifying materials, differentiating between similar products such as gasolines, and linking contaminated samples to sources. Examples of the use of the methods to deduce sources of gasoline, jet fuel, and diesel to terrestrial spills will be presented.

  11. Petroleum supply monthly, May 1998, with data for March 1998

    SciTech Connect

    1998-05-01

    The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. 16 figs., 66 tabs.

  12. Petroleum supply monthly with data from January 1998

    SciTech Connect

    1998-03-01

    The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States.

  13. Petroleum supply monthly with data for March 1997

    SciTech Connect

    1997-05-01

    The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration reflecting different levels of data timeliness and completeness. Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major U.S. geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 states and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States.

  14. A safe, efficient and cost effective process for removing petroleum hydrocarbons from a highly heterogeneous and relatively inaccessible shoreline.

    PubMed

    Guerin, Turlough F

    2015-10-01

    A rocky, intractable and highly heterogeneous, intertidal zone, was contaminated from a diesel fuel spill that occurred during refuelling of a grader used in road construction, on an operational mine's shiploading facility. A practical, cost-effective, and safer (to personnel by avoiding drilling and earthworks), and non-invasive sampling and remediation strategy was designed and implemented since the location and nature of the impacted geology (rock fill) and sediment, precluded conventional ex-situ and any in-situ treatment where drilling would be required. Enhanced biostimulation with surfactant, available N & P (which were highly constrained), and increased aeration, increased the degradation rate from no discernable change for 2 years post-spill, to 170 mg/kg/day; the maximum degradation rate after intervention. While natural attenuation was ineffective in this application, the low-cost, biostimulation intervention proved successful, allowing the site owner to meet their regulatory obligations. Petroleum hydrocarbons (aliphatic fraction) decreased from ∼20,000 mg/kg to <200 mg/kg at the completion of 180 weeks of treatment.

  15. Petroleum supply monthly, with data from June 1996

    SciTech Connect

    1996-08-01

    The Petroleum Supply Division (PSD) of the Energy Information Administration (EIA) collects and published information on petroleum supply and disposition in the United States. The information is collected through a series of surveys that make up the Petroleum Supply Reporting System (PSRS). The PSRS data are published in the Weekly Petroleum Status Report (WPSR), Petroleum Supply Monthly (PSM), and Petroleum Supply Annual (PSA). This report presents information on crude oil production, crude oil imports and exports, refinery operations, natural gas processing, transportation, and oxygenate data.

  16. Petroleum supply monthly with data for June 1997

    SciTech Connect

    1997-08-01

    Data presented in this publication describe the supply and disposition of petroleum products in the United states and major U.S. geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the U.S. The report includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. Both summary and detailed statistics are presented. 16 figs., 56 tabs.

  17. Removal of organic compounds and trace metals from oil sands process-affected water using zero valent iron enhanced by petroleum coke.

    PubMed

    Pourrezaei, Parastoo; Alpatova, Alla; Khosravi, Kambiz; Drzewicz, Przemysław; Chen, Yuan; Chelme-Ayala, Pamela; Gamal El-Din, Mohamed

    2014-06-15

    The oil production generates large volumes of oil sands process-affected water (OSPW), referring to the water that has been in contact with oil sands or released from tailings deposits. There are concerns about the environmental impacts of the release of OSPW because of its toxicity. Zero valent iron alone (ZVI) and in combination with petroleum coke (CZVI) were investigated as environmentally friendly treatment processes for the removal of naphthenic acids (NAs), acid-extractable fraction (AEF), fluorophore organic compounds, and trace metals from OSPW. While the application of 25 g/L ZVI to OSPW resulted in 58.4% removal of NAs in the presence of oxygen, the addition of 25 g petroleum coke (PC) as an electron conductor enhanced the NAs removal up to 90.9%. The increase in ZVI concentration enhanced the removals of NAs, AEF, and fluorophore compounds from OSPW. It was suggested that the electrons generated from the oxidation of ZVI were transferred to oxygen, resulting in the production of hydroxyl radicals and oxidation of NAs. When OSPW was de-oxygenated, the NAs removal decreased to 17.5% and 65.4% during treatment with ZVI and CZVI, respectively. The removal of metals in ZVI samples was similar to that obtained during CZVI treatment. Although an increase in ZVI concentration did not enhance the removal of metals, their concentrations effectively decreased at all ZVI loadings. The Microtox(®) bioassay with Vibrio fischeri showed a decrease in the toxicity of ZVI- and CZVI-treated OSPW. The results obtained in this study showed that the application of ZVI in combination with PC is a promising technology for OSPW treatment.

  18. Removal of organic compounds and trace metals from oil sands process-affected water using zero valent iron enhanced by petroleum coke.

    PubMed

    Pourrezaei, Parastoo; Alpatova, Alla; Khosravi, Kambiz; Drzewicz, Przemysław; Chen, Yuan; Chelme-Ayala, Pamela; Gamal El-Din, Mohamed

    2014-06-15

    The oil production generates large volumes of oil sands process-affected water (OSPW), referring to the water that has been in contact with oil sands or released from tailings deposits. There are concerns about the environmental impacts of the release of OSPW because of its toxicity. Zero valent iron alone (ZVI) and in combination with petroleum coke (CZVI) were investigated as environmentally friendly treatment processes for the removal of naphthenic acids (NAs), acid-extractable fraction (AEF), fluorophore organic compounds, and trace metals from OSPW. While the application of 25 g/L ZVI to OSPW resulted in 58.4% removal of NAs in the presence of oxygen, the addition of 25 g petroleum coke (PC) as an electron conductor enhanced the NAs removal up to 90.9%. The increase in ZVI concentration enhanced the removals of NAs, AEF, and fluorophore compounds from OSPW. It was suggested that the electrons generated from the oxidation of ZVI were transferred to oxygen, resulting in the production of hydroxyl radicals and oxidation of NAs. When OSPW was de-oxygenated, the NAs removal decreased to 17.5% and 65.4% during treatment with ZVI and CZVI, respectively. The removal of metals in ZVI samples was similar to that obtained during CZVI treatment. Although an increase in ZVI concentration did not enhance the removal of metals, their concentrations effectively decreased at all ZVI loadings. The Microtox(®) bioassay with Vibrio fischeri showed a decrease in the toxicity of ZVI- and CZVI-treated OSPW. The results obtained in this study showed that the application of ZVI in combination with PC is a promising technology for OSPW treatment. PMID:24681364

  19. PRECLOSURE CRITICALITY ANALYSIS PROCESS REPORT

    SciTech Connect

    A.E. Danise

    2004-10-25

    This report describes a process for performing preclosure criticality analyses for a repository at Yucca Mountain, Nevada. These analyses will be performed from the time of receipt of fissile material until permanent closure of the repository (preclosure period). The process describes how criticality safety analyses will be performed for various configurations of waste in or out of waste packages that could occur during preclosure as a result of normal operations or event sequences. The criticality safety analysis considers those event sequences resulting in unanticipated moderation, loss of neutron absorber, geometric changes, or administrative errors in waste form placement (loading) of the waste package. The report proposes a criticality analyses process for preclosure to allow a consistent transition from preclosure to postclosure, thereby possibly reducing potential cost increases and delays in licensing of Yucca Mountain. The proposed approach provides the advantage of using a parallel regulatory framework for evaluation of preclosure and postclosure performance and is consistent with the U.S. Nuclear Regulatory Commission's approach of supporting risk-informed, performance-based regulation for fuel cycle facilities, ''Yucca Mountain Review Plan, Final Report'', and 10 CFR Part 63. The criticality-related criteria for ensuring subcriticality are also described as well as which guidance documents will be utilized. Preclosure operations and facilities have significant similarities to existing facilities and operations currently regulated by the U.S. Nuclear Regulatory Commission; therefore, the design approach for preclosure criticality safety will be dictated by existing regulatory requirements while using a risk-informed approach with burnup credit for in-package operations.

  20. Arctic lake physical processes and regimes with implications for winter water availability and management in the National Petroleum Reserve Alaska.

    PubMed

    Jones, Benjamin M; Arp, Christopher D; Hinkel, Kenneth M; Beck, Richard A; Schmutz, Joel A; Winston, Barry

    2009-06-01

    Lakes are dominant landforms in the National Petroleum Reserve Alaska (NPRA) as well as important social and ecological resources. Of recent importance is the management of these freshwater ecosystems because lakes deeper than maximum ice thickness provide an important and often sole source of liquid water for aquatic biota, villages, and industry during winter. To better understand seasonal and annual hydrodynamics in the context of lake morphometry, we analyzed lakes in two adjacent areas where winter water use is expected to increase in the near future because of industrial expansion. Landsat Thematic Mapper and Enhanced Thematic Mapper Plus imagery acquired between 1985 and 2007 were analyzed and compared with climate data to understand interannual variability. Measured changes in lake area extent varied by 0.6% and were significantly correlated to total precipitation in the preceding 12 months (p < 0.05). Using this relation, the modeled lake area extent from 1985 to 2007 showed no long-term trends. In addition, high-resolution aerial photography, bathymetric surveys, water-level monitoring, and lake-ice thickness measurements and growth models were used to better understand seasonal hydrodynamics, surface area-to-volume relations, winter water availability, and more permanent changes related to geomorphic change. Together, these results describe how lakes vary seasonally and annually in two critical areas of the NPRA and provide simple models to help better predict variation in lake-water supply. Our findings suggest that both overestimation and underestimation of actual available winter water volume may occur regularly, and this understanding may help better inform management strategies as future resource use expands in the NPRA.

  1. Arctic lake physical processes and regimes with implications for winter water availability and management in the National Petroleum Reserve Alaska.

    PubMed

    Jones, Benjamin M; Arp, Christopher D; Hinkel, Kenneth M; Beck, Richard A; Schmutz, Joel A; Winston, Barry

    2009-06-01

    Lakes are dominant landforms in the National Petroleum Reserve Alaska (NPRA) as well as important social and ecological resources. Of recent importance is the management of these freshwater ecosystems because lakes deeper than maximum ice thickness provide an important and often sole source of liquid water for aquatic biota, villages, and industry during winter. To better understand seasonal and annual hydrodynamics in the context of lake morphometry, we analyzed lakes in two adjacent areas where winter water use is expected to increase in the near future because of industrial expansion. Landsat Thematic Mapper and Enhanced Thematic Mapper Plus imagery acquired between 1985 and 2007 were analyzed and compared with climate data to understand interannual variability. Measured changes in lake area extent varied by 0.6% and were significantly correlated to total precipitation in the preceding 12 months (p < 0.05). Using this relation, the modeled lake area extent from 1985 to 2007 showed no long-term trends. In addition, high-resolution aerial photography, bathymetric surveys, water-level monitoring, and lake-ice thickness measurements and growth models were used to better understand seasonal hydrodynamics, surface area-to-volume relations, winter water availability, and more permanent changes related to geomorphic change. Together, these results describe how lakes vary seasonally and annually in two critical areas of the NPRA and provide simple models to help better predict variation in lake-water supply. Our findings suggest that both overestimation and underestimation of actual available winter water volume may occur regularly, and this understanding may help better inform management strategies as future resource use expands in the NPRA. PMID:19101761

  2. Arctic lake physical processes and regimes with implications for winter water availability and management in the national petroleum reserve alaska

    USGS Publications Warehouse

    Jones, Benjamin M.; Arp, C.D.; Hinkel, Kenneth M.; Beck, R.A.; Schmutz, J.A.; Winston, B.

    2009-01-01

    Lakes are dominant landforms in the National Petroleum Reserve Alaska (NPRA) as well as important social and ecological resources. Of recent importance is the management of these freshwater ecosystems because lakes deeper than maximum ice thickness provide an important and often sole source of liquid water for aquatic biota, villages, and industry during winter. To better understand seasonal and annual hydrodynamics in the context of lake morphometry, we analyzed lakes in two adjacent areas where winter water use is expected to increase in the near future because of industrial expansion. Landsat Thematic Mapper and Enhanced Thematic Mapper Plus imagery acquired between 1985 and 2007 were analyzed and compared with climate data to understand interannual variability. Measured changes in lake area extent varied by 0.6% and were significantly correlated to total precipitation in the preceding 12 months (p < 0.05). Using this relation, the modeled lake area extent from 1985 to 2007 showed no long-term trends. In addition, high-resolution aerial photography, bathymetric surveys, water-level monitoring, and lake-ice thickness measurements and growth models were used to better understand seasonal hydrodynamics, surface area-to-volume relations, winter water availability, and more permanent changes related to geomorphic change. Together, these results describe how lakes vary seasonally and annually in two critical areas of the NPRA and provide simple models to help better predict variation in lake-water supply. Our findings suggest that both overestimation and underestimation of actual available winter water volume may occur regularly, and this understanding may help better inform management strategies as future resource use expands in the NPRA. ?? 2008 Springer Science+Business Media, LLC.

  3. Analysis of heavy oils: Method development and application to Cerro Negro heavy petroleum

    SciTech Connect

    Carbognani, L.; Hazos, M.; Sanchez, V. ); Green, J.A.; Green, J.B.; Grigsby, R.D.; Pearson, C.D.; Reynolds, J.W.; Shay, J.Y.; Sturm, G.P. Jr.; Thomson, J.S.; Vogh, J.W.; Vrana, R.P.; Yu, S.K.T.; Diehl, B.H.; Grizzle, P.L.; Hirsch, D.E; Hornung, K.W.; Tang, S.Y.

    1989-12-01

    On March 6, 1980, the US Department of Energy (DOE) and the Ministry of Energy and Mines of Venezuela (MEMV) entered into a joint agreement which included analysis of heavy crude oils from the Venezuelan Orinoco oil belt.The purpose of this report is to present compositional data and describe new analytical methods obtained from work on the Cerro Negro Orinoco belt crude oil since 1980. Most of the chapters focus on the methods rather than the resulting data on Cerro Negro oil, and results from other oils obtained during the verification of the method are included. In addition, published work on analysis of heavy oils, tar sand bitumens, and like materials is reviewed, and the overall state of the art in analytical methodology for heavy fossil liquids is assessed. The various phases of the work included: distillation and determination of routine'' physical/chemical properties (Chapter 1); preliminary separation of >200{degree}C distillates and the residue into acid, base, neutral, saturated hydrocarbon and neutral-aromatic concentrates (Chapter 2); further separation of acid, base, and neutral concentrates into subtypes (Chapters 3-5); and determination of the distribution of metal-containing compounds in all fractions (Chapter 6).

  4. Optimization-based multicriteria decision analysis for identification of desired petroleum-contaminated groundwater remediation strategies.

    PubMed

    Lu, Hongwei; Feng, Mao; He, Li; Ren, Lixia

    2015-06-01

    The conventional multicriteria decision analysis (MCDA) methods used for pollution control generally depend on the data currently available. This could limit their real-world applications, especially where the input data (e.g., the most cost-effective remediation cost and eventual contaminant concentration) might vary by scenario. This study proposes an optimization-based MCDA (OMCDA) framework to address such a challenge. It is capable of (1) capturing various preferences of decision-makers, (2) screening and analyzing the performance of various optimized remediation strategies under changeable scenarios, and (3) compromising incongruous decision analysis results. A real-world case study is employed for demonstration, where four scenarios are considered with each one corresponding to a set of weights representative of the preference of the decision-makers. Four criteria are selected, i.e., optimal total pumping rate, remediation cost, contaminant concentration, and fitting error. Their values are determined through running optimization and optimization-based simulation procedures. Four sets of the most desired groundwater remediation strategies are identified, implying specific pumping rates under varied scenarios. Results indicate that the best action lies in groups 32 and 16 for the 5-year, groups 49 and 36 for the 10-year, groups 26 and 13 for the 15-year, and groups 47 and 13 for the 20-year remediation.

  5. BASIN ANALYSIS AND PETROLEUM SYSTEM CHARACTERIZATION AND MODELING, INTERIOR SALT BASINS, CENTRAL AND EASTERN GULF OF MEXICO

    SciTech Connect

    Ernest A. Mancini

    2004-11-05

    The principal research effort for Year 2 of the project is the determination of the burial and thermal maturation histories and basin modeling and petroleum system identification of the North Louisiana Salt Basin. In the first six (6) to nine (9) months of Year 2, the research focus is on the determination of the burial and thermal maturation histories and the remainder of the year the emphasis is on basin modeling and petroleum system identification. No major problems have been encountered to date, and the project is on schedule.

  6. Basin Analysis and Petroleum System Characterization and Modeling, Interior Salt Basins, Central and Eastern Gulf of Mexico

    SciTech Connect

    Ernest A. Mancini

    2005-03-31

    The principal research effort for Year 2 of the project is the determination of the burial and thermal maturation histories and basin modeling and petroleum system identification of the North Louisiana Salt Basin. In the first six (6) to nine (9) months of Year 2, the research focus is on the determination of the burial and thermal maturation histories and the remainder of the year the emphasis is on basin modeling and petroleum system identification. No major problems have been encountered to date, and the project is on schedule.

  7. Petroleum biodegradation in marine environments.

    PubMed

    Harayama, S; Kishira, H; Kasai, Y; Shutsubo, K

    1999-08-01

    Petroleum-based products are the major source of energy for industry and daily life. Petroleum is also the raw material for many chemical products such as plastics, paints, and cosmetics. The transport of petroleum across the world is frequent, and the amounts of petroleum stocks in developed countries are enormous. Consequently, the potential for oil spills is significant, and research on the fate of petroleum in a marine environment is important to evaluate the environmental threat of oil spills, and to develop biotechnology to cope with them. Crude oil is constituted from thousands of components which are separated into saturates, aromatics, resins and asphaltenes. Upon discharge into the sea, crude oil is subjected to weathering, the process caused by the combined effects of physical, chemical and biological modification. Saturates, especially those of smaller molecular weight, are readily biodegraded in marine environments. Aromatics with one, two or three aromatic rings are also efficiently biodegraded; however, those with four or more aromatic ring are quite resistant to biodegradation. The asphaltene and resin fractions contain higher molecular weight compounds whose chemical structures have not yet been resolved. The biodegradability of these compounds is not yet known. It is known that the concentrations of available nitrogen and phosphorus in seawater limit the growth and activities of hydrocarbon-degrading microorganisms in a marine environment. In other words, the addition of nitrogen and phosphorus fertilizers to an oil-contaminated marine environment can stimulate the biodegradation of spilled oil. This notion was confirmed in the large-scale operation for bioremediation after the oil spill from the Exxon Valdez in Alaska. Many microorganisms capable of degrading petroleum components have been isolated. However, few of them seem to be important for petroleum biodegradation in natural environments. One group of bacteria belonging to the genus

  8. Petroleum biodegradation in marine environments.

    PubMed

    Harayama, S; Kishira, H; Kasai, Y; Shutsubo, K

    1999-08-01

    Petroleum-based products are the major source of energy for industry and daily life. Petroleum is also the raw material for many chemical products such as plastics, paints, and cosmetics. The transport of petroleum across the world is frequent, and the amounts of petroleum stocks in developed countries are enormous. Consequently, the potential for oil spills is significant, and research on the fate of petroleum in a marine environment is important to evaluate the environmental threat of oil spills, and to develop biotechnology to cope with them. Crude oil is constituted from thousands of components which are separated into saturates, aromatics, resins and asphaltenes. Upon discharge into the sea, crude oil is subjected to weathering, the process caused by the combined effects of physical, chemical and biological modification. Saturates, especially those of smaller molecular weight, are readily biodegraded in marine environments. Aromatics with one, two or three aromatic rings are also efficiently biodegraded; however, those with four or more aromatic ring are quite resistant to biodegradation. The asphaltene and resin fractions contain higher molecular weight compounds whose chemical structures have not yet been resolved. The biodegradability of these compounds is not yet known. It is known that the concentrations of available nitrogen and phosphorus in seawater limit the growth and activities of hydrocarbon-degrading microorganisms in a marine environment. In other words, the addition of nitrogen and phosphorus fertilizers to an oil-contaminated marine environment can stimulate the biodegradation of spilled oil. This notion was confirmed in the large-scale operation for bioremediation after the oil spill from the Exxon Valdez in Alaska. Many microorganisms capable of degrading petroleum components have been isolated. However, few of them seem to be important for petroleum biodegradation in natural environments. One group of bacteria belonging to the genus

  9. Future petroleum energy resources of the world

    USGS Publications Warehouse

    Ahlbrandt, T.S.

    2002-01-01

    Is the world running out of oil? Where will future oil and gas supplies come from? To help answer these questions, in 2000 the U.S. Geological Survey completed a new world assessment, exclusive of the United States, of the undiscovered conventional oil and gas resources and potential additions to reserves from field growth.2 One hundred and twenty-eight provinces were assessed in a 100 man-year effort from 1995-2000. The assessed provinces included 76 priority provinces containing 95% of the world's discovered oil and gas and an additional 52 "boutique" provinces, many of which may be highly prospective. Total Petroleum Systems (TPS) were identified and described for each of these provinces along with associated Assessment Units (AU) that are the basic units for assessing undiscovered petroleum. The assessment process coupled geologic analysis with a probabilistic methodology to estimate remaining potential. Within the 128 assessed provinces were 159 TPS and 274 AU. For these provinces, the endowment of recoverable oil-which includes cumulative production, remaining reserves, reserve growth, and undiscovered resources-is estimated at about 3 trillion barrels of oil (TBO). The natural gas endowment is estimated at 2.6 trillion barrels of oil equivalent (TBOE). Oil reserves are currently 1.1 TBO; world consumption is about .028 TBO per year. Natural gas reserves are about 0.8 TBOE; world consumption is about 0.014 TBOE per year. Thus, without any additional discoveries of oil, gas or natural gas liquids, we have about 2 TBOE of proved petroleum reserves. Of the oil and gas endowment of about 5.6 TBOE, we estimate that the world has consumed about 1 TBOE, or 18%, leaving about 82% of the endowment to be utilized or found. Half of the world's undiscovered potential is offshore. Arctic basins with about 25% of undiscovered petroleum resources make up the next great frontier. An additional 279 provinces contain some oil and gas and, if considered, would increase the oil

  10. Association of petroleum and cinnabar in mercury deposits of the California Coast ranges, USA

    SciTech Connect

    Peabody, C.E.

    1990-01-01

    Many mercury deposits around the world contain small but significant amounts of petroleum in association with cinnabar. Geological and geochemical investigations of mercury deposits in the northern California Coast ranges (Mayacmas, Wilbur Springs, Knoxville, and New Almaden districts) were undertaken to document the association, determine petroleum chemical compositions, and establish the geochemical setting of such deposits in order to formulate a genetic model. Petroleum +/- cinnabar occurs in veins, vugs, between breccia fragments, between quartz or carbonate crystals, in fluid inclusions or in froth veins. The occurrence of petroleum and cinnabar along the hanging walls of permeable structures attests to the relative buoyancy of oil and Hg during the transport process. GC-MS analysis of petroleums reveals the dominance of polycyclic aromatic hydrocarbons such as phenanthrenes, chrysenes, and naphthalenes. Neutron activation analysis of 6 petroleums yields maximum trace element concentrations of 20 ppm Hg, 330 ppb Au, 2.2 ppm As, 160 ppb Ag, 39 ppm Cr, 2.3 ppb Co, and 1.5 ppm Se. Silica-carbonate rock, an alteration product of serpentinite, is commonly the ore host. Geochemical modelling indicates that this alteration can arise from interaction with a CO{sub 2}-rich, H{sub 2}O-CO{sub 2} fluid. In addition to CO{sub 2}, the only components added to the system during alteration and mineralization were petroleum, H{sub 2}S, and Hg. The presence of free CO{sub 2} in sedimentary rocks allows the concentration of mercury in the gas phase and mobilization of petroleum. When the fluid is focussed by large scale anticlinal structures, it has the potential to form a cinnabar-(petroleum) deposit as it approaches the surface.

  11. A Pareto analysis approach to assess relevant marginal CO{sub 2} footprint for petroleum products

    SciTech Connect

    Tehrani, Nejad M. Alireza

    2015-07-15

    Recently, linear programing (LP) models have been extended to track the marginal CO{sub 2} intensity of automotive fuels at the refinery gate. The obtained CO{sub 2} data are recommended for policy making because they capture the economic and environmental tensions as well as the processing effects related to oil products. However, they are proven to be extremely sensitive to small perturbations and therefore useless in practice. In this paper, we first investigate the theoretical reasons of this drawback. Then, we develop a multiple objective LP framework to assess relevant marginal CO{sub 2} footprints that preserve both defensibility and stability at a satisfactory level of acceptance. A case study illustrates this new methodology. - Highlights: • Refining LP models have limitations to provide useful marginal CO{sub 2} footprints. • A multi objective optimization framework is developed to assess relevant CO{sub 2} data. • Within a European Refinig industry, diesel is more CO{sub 2} intensive than gasoline.

  12. Petroleum Technology: From Refinery To Home, Business, and Industry.

    ERIC Educational Resources Information Center

    Shewell, John A.

    1997-01-01

    Discusses the application of petroleum technology and presents activities designed to raise students' awareness of the importance of petroleum-based products in their lives. Includes a handout designed to help students understand the refining processes in which the crude oil from the drill site is transformed into nearly 6,000 petroleum-based…

  13. Basin Analysis and Petroleum System Characterization and Modelling, Interior Salt Basins, Central and Eastern Gulf of Mexico

    SciTech Connect

    Ernest A. Mancini

    2006-09-30

    The principal research effort for Year 1 of Phase 2 (Concept Demonstration) of the project is Smackover petroleum system characterization and modeling. The necessary software applications have been acquired to accomplish this work. No major problems have been encountered to date, and the project is on schedule.

  14. Basin Analysis and Petroleum System Characterization and Modeling, Interior Salt Basins, Central and Eastern Gulf of Mexico

    SciTech Connect

    Ernest A. Mancini

    2006-12-31

    The principal research effort for Year 1 of Phase 2 (Concept Demonstration) of the project is Smackover petroleum system characterization and modeling. The necessary software applications have been acquired to accomplish this work. No major problems have been encountered to date, and the project is on schedule.

  15. Basin Analysis and Petroleum System Characterization and Modeling, Interior Salt Basins, Central and Eastern Gulf of Mexico

    SciTech Connect

    Ernest A. Mancini

    2007-06-30

    The principal research effort for Year 2 of Phase 2 (Concept Demonstration) of the project is Mesozoic (Bossier) petroleum system characterization and modeling and refined resource assessment. The necessary software applications have been acquired to accomplish this work. No major problems have been encountered to date, and the project is on schedule.

  16. Mexico's petroleum and US policy: implications for the 1980s

    SciTech Connect

    Ronfeldt, D.; Nehring, R.; Gandara, A.

    1980-06-01

    This report examines selected factor affecting Mexico's future petroleum policies, and then assesses various implications of Mexico's petroleum for US interests and policies. After a brief introduction, the report is divided into three sections. The first offers a detailed analysis of Mexico's petroleum resources and production possibilities. The second considers petroleum as a symbolic issue of profound significance for Mexican nationalism. The final section provides an assessment of these and other factors for US interests, objectives, and policy options during the 1980s.

  17. Assessment of genotoxic activity of petroleum hydrocarbon-bioremediated soil.

    PubMed

    Płaza, Grazyna; Nałecz-Jawecki, Grzegorz; Ulfig, Krzysztof; Brigmon, Robin L

    2005-11-01

    The relationship between toxicity and soil contamination must be understood to develop reliable indicators of environmental restoration for bioremediation. Two bacterial rapid bioassays, SOS chromotest and the umu test with and without metabolic activation (S-9 mixture), were used to evaluate the genotoxicity of petroleum hydrocarbon-contaminated soil following bioremediation treatment. The soil was taken from an engineered biopile at the Czechowice-Dziedzice Polish oil refinery (CZOR). The bioremediation process in the biopile lasted 4 years, and the toxicity measurements were done after this treatment. Carcinogens detected in the soil, polyaromatic hydrocarbons (PAHs), were reduced to low concentrations (2mg/kg dry wt) by the bioremediation process. Genotoxicity was not observed for soils tested with and without metabolic activation by a liver homogenate (S-9 mixture). However, the umu test was more sensitive than the SOS chromotest in the analysis of petroleum hydrocarbon-bioremediated soil. Analytical results of soil used in the bioassays confirmed that the bioremediation process reduced 81% of the petroleum hydrocarbons including PAHs. We conclude that the combined test systems employed in this study are useful tools for the genotoxic examination of remediated petroleum hydrocarbon-contaminated soil.

  18. ASSESSMENT OF GENOTOXIC ACTIVITY OF PETROLEUM HYDROCARBON-BIOREMEDIATED SOIL

    SciTech Connect

    BRIGMON, ROBIN

    2004-10-20

    The relationship between toxicity and soil contamination must be understood to develop reliable indicators of environmental restoration for bioremediation. Two bacterial rapid bioassays: SOS chromotest and umu-test with and without metabolic activation (S-9 mixture) were used to evaluate genotoxicity of petroleum hydrocarbon-contaminated soil following bioremediation treatment. The soil was taken from an engineered biopile at the Czor Polish oil refinery. The bioremediation process in the biopile lasted 4 years, and the toxicity measurements were done after this treatment. Carcinogens detected in the soil, polyaromatic hydrocarbons (PAHs), were reduced to low concentrations (2 mg/kg dry wt) by the bioremediation process. Genotoxicity was not observed for soils tested with and without metabolic activation by a liver homogenate (S-9 mixture). However, umu-test was more sensitive than SOS-chromotest in the analysis of petroleum hydrocarbon-bioremediated soil. Analytical results of soil used in the bioassays confirmed that the bioremediation process reduced 81 percent of the petroleum hydrocarbons including PAHs. We conclude that the combined test systems employed in this study are useful tools for the genotoxic examination of remediated petroleum hydrocarbon-contaminated soil.

  19. PETROLEUM BIOREFINING FOR POLLUTION PREVENTION

    SciTech Connect

    John J. Kilbane II

    2002-03-01

    The objective of this project was to isolate and characterize thermophilic bacterial cultures that can be used for the selective removal of nitrogen, sulfur, and/or metals in the biorefining of petroleum. The project was completed on schedule and no major difficulties were encountered. Significant progress was made on multiple topics relevant to the development of a petroleum biorefining process capable of operating at thermophilic temperatures. New cultures capable of selectively cleaving C-N or C-S bonds in molecules relevant to petroleum were obtained, and the genes encoding the enzymes for these unique biochemical reactions were cloned and sequenced. Genetic tools were developed that enable the use of Thermus thermophilus as a host to express any gene of interest, and information was obtained regarding the optimum conditions for the growth of T. thermophilus. The development of a practical biorefining process still requires further research and the future research needs identified in this project include the development of new enzymes and pathways for the selective cleavage of C-N or C-S bonds that have higher specific activities, increased substrate range, and are capable of functioning at thermophilic temperatures. Additionally, there is a need for process engineering research to determine the maximum yield of biomass and cloned gene products that can be obtained in fed-batch cultures using T. thermophilus, and to determine the best configuration for a process employing biocatalysts to treat petroleum.

  20. IWTU Process Sample Analysis Report

    SciTech Connect

    Nick Soelberg

    2013-04-01

    CH2M-WG Idaho (CWI) requested that Battelle Energy Alliance (BEA) analyze various samples collected during June – August 2012 at the Integrated Waste Treatment Facility (IWTU). Samples of IWTU process materials were collected from various locations in the process. None of these samples were radioactive. These samples were collected and analyzed to provide more understanding of the compositions of various materials in the process during the time of the process shutdown that occurred on June 16, 2012, while the IWTU was in the process of nonradioactive startup.

  1. (National Institute for Petroleum and Energy Research)quarterly technical report, January 1--March 31, 1992

    SciTech Connect

    Not Available

    1992-05-01

    The objectives of Development of Analytical Methodology for Analysis of Heavy Crudes'' are to identify compounds or classes of compounds with significant positive or negative effects on crude oil and/or product properties nd characteristics and to develop methods for their determination in conventional or low grade petroleum and syncrudes; specific objectives for FY92 are: (1) to determine catalytic cracking behavior of individual compound classes in petroleum, and (2) to further develop GC/MS methodology for speciation of nitrogen and sulfur compound in petroleum. The objectives of Thermochemistry and Thermophysical Properties of Organic Nitrogen and Diheteroatom-Containing Compounds'' is to provide, interpret, and correlate with molecular structure and polarity of molecules, precise and accurate values of thermodynamic properties of organic nitrogen and diheteroatom-containing compounds that occur in or are readily derivable from heavy petroleum and oil shale. The results will enable the prediction of chemical equilibria for conceptual as well as current processes.

  2. REDUCING POWER PRODUCTION COSTS BY UTILIZING PETROLEUM COKE

    SciTech Connect

    Kevin C. Galbreath; Donald L. Toman; Christopher J. Zygarlicke

    1999-09-01

    Petroleum coke, a byproduct of the petroleum-refining process, is an attractive primary or supplemental fuel for power production primarily because of a progressive and predictable increase in the production volumes of petroleum coke (1, 2). Petroleum coke is most commonly blended with coal in proportions suitable to meet sulfur emission compliance. Petroleum coke is generally less reactive than coal; therefore, the cofiring of petroleum coke with coal typically improves ignition, flame stability, and carbon loss relative to the combustion of petroleum coke alone. Although petroleum coke is a desirable fuel for producing relatively inexpensive electrical power, concerns about the effects of petroleum coke blending on combustion and pollution control processes exist in the coal-fired utility industry (3). The Energy & Environmental Research Center (EERC) completed a 2-year technical assessment of petroleum coke as a supplemental fuel. A survey questionnaire was sent to seven electric utility companies that are currently cofiring coal and petroleum coke in an effort to solicit specific suggestions on research needs and fuel selections. An example of the letter and survey questionnaire is presented in Appendix A. Interest was expressed by most utilities in evaluating the effects of petroleum coke blending on grindability, combustion reactivity, fouling, slagging, and fly ash emissions control. Unexpectedly, concern over corrosion was not expressed by the utilities contacted. Although all seven utilities responded to the question, only two utilities, Northern States Power Company (NSP) and Ameren, sent fuels to the EERC for evaluation. Both utilities sent subbituminous coals from the Power River Basin and petroleum shot coke samples. Petroleum shot coke is produced unintentionally during operational upsets in the petroleum refining process. This report evaluates the effects of petroleum shot coke blending on grindability, fuel reactivity, fouling/slagging, and

  3. Petroleum marketing monthly

    SciTech Connect

    1995-11-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data.

  4. Remedial Process Optimization and Green In-Situ Ozone Sparging for Treatment of Groundwater Impacted with Petroleum Hydrocarbons

    NASA Astrophysics Data System (ADS)

    Leu, J.

    2012-12-01

    A former natural gas processing station is impacted with TPH and BTEX in groundwater. Air sparging and soil vapor extraction (AS/AVE) remediation systems had previously been operated at the site. Currently, a groundwater extraction and treatment system is operated to remove the chemicals of concern (COC) and contain the groundwater plume from migrating offsite. A remedial process optimization (RPO) was conducted to evaluate the effectiveness of historic and current remedial activities and recommend an approach to optimize the remedial activities. The RPO concluded that both the AS/SVE system and the groundwater extraction system have reached the practical limits of COC mass removal and COC concentration reduction. The RPO recommended an in-situ chemical oxidation (ISCO) study to evaluate the best ISCO oxidant and approach. An ISCO bench test was conducted to evaluate COC removal efficiency and secondary impacts to recommend an application dosage. Ozone was selected among four oxidants based on implementability, effectiveness, safety, and media impacts. The bench test concluded that ozone demand was 8 to 12 mg ozone/mg TPH and secondary groundwater by-products of ISCO include hexavalent chromium and bromate. The pH also increased moderately during ozone sparging and the TDS increased by approximately 20% after 48 hours of ozone treatment. Prior to the ISCO pilot study, a capture zone analysis (CZA) was conducted to ensure containment of the injected oxidant within the existing groundwater extraction system. The CZA was conducted through a groundwater flow modeling using MODFLOW. The model indicated that 85%, 90%, and 95% of an injected oxidant could be captured when a well pair is injecting and extracting at 2, 5, and 10 gallons per minute, respectively. An ISCO pilot test using ozone was conducted to evaluate operation parameters for ozone delivery. The ozone sparging system consisted of an ozone generator capable of delivering 6 lbs/day ozone through two ozone

  5. Petroleum supply monthly, December 1998 with data for October 1998

    SciTech Connect

    1998-12-01

    Data presented in the Petroleum Supply Monthly (PSM) describe the supply and disposition of petroleum products in the US and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the US (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the US. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics. 82 tabs.

  6. Petroleum supply monthly: September 1996, with data for July 1996

    SciTech Connect

    1996-09-01

    Data presented in this report describe the supply and disposition of petroleum products in the US and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the US (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the US. The tables and figures in the Summary Statistics section of the PSM present a time series of selected petroleum data on a US level. The Detailed Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. 56 tabs.

  7. Petroleum supply monthly, November 1996 with data for September 1996

    SciTech Connect

    1996-11-01

    Data presented in this report describes the supply and disposition of petroleum products in the US and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products fin the US (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the US. The tables and figures in the Summary Statistics section present a time series of selected petroleum data on a US level. The Detailed Statistics tables present statistics for the most current month available as well as year-to-date. 16 figs., 66 tabs.

  8. Petroleum system modeling capabilities for use in oil and gas resource assessments

    USGS Publications Warehouse

    Higley, Debra K.; Lewan, Michael; Roberts, Laura N.R.; Henry, Mitchell E.

    2006-01-01

    Summary: Petroleum resource assessments are among the most highly visible and frequently cited scientific products of the U.S. Geological Survey. The assessments integrate diverse and extensive information on the geologic, geochemical, and petroleum production histories of provinces and regions of the United States and the World. Petroleum systems modeling incorporates these geoscience data in ways that strengthen the assessment process and results are presented visually and numerically. The purpose of this report is to outline the requirements, advantages, and limitations of one-dimensional (1-D), two-dimensional (2-D), and three-dimensional (3-D) petroleum systems modeling that can be applied to the assessment of oil and gas resources. Primary focus is on the application of the Integrated Exploration Systems (IES) PetroMod? software because of familiarity with that program as well as the emphasis by the USGS Energy Program on standardizing to one modeling application. The Western Canada Sedimentary Basin (WCSB) is used to demonstrate the use of the PetroMod? software. Petroleum systems modeling quantitatively extends the 'total petroleum systems' (TPS) concept (Magoon and Dow, 1994; Magoon and Schmoker, 2000) that is employed in USGS resource assessments. Modeling allows integration of state-of-the-art analysis techniques, and provides the means to test and refine understanding of oil and gas generation, migration, and accumulation. Results of modeling are presented visually, numerically, and statistically, which enhances interpretation of the processes that affect TPSs through time. Modeling also provides a framework for the input and processing of many kinds of data essential in resource assessment, including (1) petroleum system elements such as reservoir, seal, and source rock intervals; (2) timing of depositional, hiatus, and erosional events and their influences on petroleum systems; (3) incorporation of vertical and lateral distribution and lithologies of

  9. Lithography process window analysis with calibrated model

    NASA Astrophysics Data System (ADS)

    Zhou, Wenzhan; Yu, Jin; Lo, James; Liu, Johnson

    2004-05-01

    As critical-dimension shrink below 0.13 μm, the SPC (Statistical Process Control) based on CD (Critical Dimension) control in lithography process becomes more difficult. Increasing requirements of a shrinking process window have called on the need for more accurate decision of process window center. However in practical fabrication, we found that systematic error introduced by metrology and/or resist process can significantly impact the process window analysis result. Especially, when the simple polynomial functions are used to fit the lithographic data from focus exposure matrix (FEM), the model will fit these systematic errors rather than filter them out. This will definitely impact the process window analysis and determination of the best process condition. In this paper, we proposed to use a calibrated first principle model to do process window analysis. With this method, the systematic metrology error can be filtered out efficiently and give a more reasonable window analysis result.

  10. Recent Advances in Petroleum Microbiology

    PubMed Central

    Van Hamme, Jonathan D.; Singh, Ajay; Ward, Owen P.

    2003-01-01

    Recent advances in molecular biology have extended our understanding of the metabolic processes related to microbial transformation of petroleum hydrocarbons. The physiological responses of microorganisms to the presence of hydrocarbons, including cell surface alterations and adaptive mechanisms for uptake and efflux of these substrates, have been characterized. New molecular techniques have enhanced our ability to investigate the dynamics of microbial communities in petroleum-impacted ecosystems. By establishing conditions which maximize rates and extents of microbial growth, hydrocarbon access, and transformation, highly accelerated and bioreactor-based petroleum waste degradation processes have been implemented. Biofilters capable of removing and biodegrading volatile petroleum contaminants in air streams with short substrate-microbe contact times (<60 s) are being used effectively. Microbes are being injected into partially spent petroleum reservoirs to enhance oil recovery. However, these microbial processes have not exhibited consistent and effective performance, primarily because of our inability to control conditions in the subsurface environment. Microbes may be exploited to break stable oilfield emulsions to produce pipeline quality oil. There is interest in replacing physical oil desulfurization processes with biodesulfurization methods through promotion of selective sulfur removal without degradation of associated carbon moieties. However, since microbes require an environment containing some water, a two-phase oil-water system must be established to optimize contact between the microbes and the hydrocarbon, and such an emulsion is not easily created with viscous crude oil. This challenge may be circumvented by application of the technology to more refined gasoline and diesel substrates, where aqueous-hydrocarbon emulsions are more easily generated. Molecular approaches are being used to broaden the substrate specificity and increase the rates and

  11. Analysis of crisis intervention processes.

    PubMed

    Tschacher, Wolfgang; Jacobshagen, Nina

    2002-01-01

    The remediation processes in psychosocial crisis intervention were modeled focusing on cognitive orientation. Frequent observations and subsequent process modeling constitute a novel approach to process research and reveal process-outcome associations. A sample of 40 inpatients who were assigned to treatment in a crisis intervention unit was monitored in order to study the process of crisis intervention. The process data consisted of patients' self-ratings of the variables mood, tension, and cognitive orientation, which were assessed three times a day throughout hospitalization (M = 22.6 days). Linear time series models (vector autoregression) of the process data were computed to describe the prototypical dynamic patterns of the sample. Additionally, the outcome of crisis intervention was evaluated by pre-post questionnaires. Linear trends were found pointing to an improvement of mood, a reduction of tension, and an increase of outward cognitive orientation. Time series modeling showed that, on average, outward cognitive orientation preceded improved mood. The time series models partially predicted the treatment effect, notably the outcome domain "reduction of social anxiety," yet did not predict the domain of symptom reduction. In conclusion, crisis intervention should focus on having patients increasingly engage in outward cognitive orientation in order to stabilize mood, reduce anxiety, and activate their resources.

  12. Strategic Petroleum Reserve. Quarterly report

    SciTech Connect

    Not Available

    1993-11-15

    The Strategic Petroleum Reserve serves as one of the most important investments in reducing the Nation`s vulnerability to oil supply disruptions. This Quarterly Report highlights activities undertaken during the third quarter of calendar year 1993, including: inventory of petroleum products stored in the Reserve, under contract and in transit at the end of the calendar quarter; fill rate for the quarter and projected fill rate for the next calendar quarter; average price of the petroleum products acquired during the calendar quarter; current and projected storage capacity and plans to accelerate the acquisition or construction of such capacity; analysis of existing or anticipated problems with the acquisition and storage of petroleum products and future expansion of storage capacity; funds obligated by the Secretary from the SPR Petroleum Account and the Strategic Petroleum Reserve Account during the prior calendar quarter and in total; and major environmental actions completed, in progress, or anticipated. Samples of the oil revealed two problems that, although readily correctable, have reduced the availability of some of the oil inventory for drawdown in the near-term. These problems are: (1) a higher-than-normal gas content in some of the crude oil, apparently from years of intrusion of methane form the surrounding salt formation; and (2) elevated temperatures of some of the crude oil, due to geothermal heating, that has increased the vapor pressure of the oil. Investigations are proceeding to determine the extent to which gas intrusion and geothermal heating are impacting the availability of oil for drawdown. Preliminary designs have been developed for systems to mitigate both problems.

  13. BASIN ANALYSIS AND PETROLEUM SYSTEM CHARACTERIZATION AND MODELING, INTERIOR SALT BASINS, CENTRAL AND EASTERN GULF OF MEXICO

    SciTech Connect

    Ernest A. Mancini; Donald A. Goddard; Ronald K. Zimmerman

    2005-05-10

    The principal research effort for Year 2 of the project has been data compilation and the determination of the burial and thermal maturation histories of the North Louisiana Salt Basin and basin modeling and petroleum system identification. In the first nine (9) months of Year 2, the research focus was on the determination of the burial and thermal maturation histories, and during the remainder of the year the emphasis has basin modeling and petroleum system identification. Existing information on the North Louisiana Salt Basin has been evaluated, an electronic database has been developed, regional cross sections have been prepared, structure and isopach maps have been constructed, and burial history, thermal maturation history and hydrocarbon expulsion profiles have been prepared. Seismic data, cross sections, subsurface maps and related profiles have been used in evaluating the tectonic, depositional, burial and thermal maturation histories of the basin. Oil and gas reservoirs have been found to be associated with salt-supported anticlinal and domal features (salt pillows, turtle structures and piercement domes); with normal faulting associated with the northern basin margin and listric down-to-the-basin faults (state-line fault complex) and faulted salt features; and with combination structural and stratigraphic features (Sabine and Monroe Uplifts) and monoclinal features with lithologic variations. Petroleum reservoirs are mainly Upper Jurassic and Lower Cretaceous fluvial-deltaic sandstone facies and Lower Cretaceous and Upper Cretaceous shoreline, marine bar and shallow shelf sandstone facies. Cretaceous unconformities significantly contribute to the hydrocarbon trapping mechanism capacity in the North Louisiana Salt Basin. The chief petroleum source rock in this basin is Upper Jurassic Smackover lime mudstone beds. The generation of hydrocarbons from Smackover lime mudstone was initiated during the Early Cretaceous and continued into the Tertiary

  14. Analysis of petroleum contaminated soils by spectral modeling and pure response profile recovery of n-hexane.

    PubMed

    Chakraborty, Somsubhra; Weindorf, David C; Li, Bin; Ali, Md Nasim; Majumdar, K; Ray, D P

    2014-07-01

    This pilot study compared penalized spline regression (PSR) and random forest (RF) regression using visible and near-infrared diffuse reflectance spectroscopy (VisNIR DRS) derived spectra of 164 petroleum contaminated soils after two different spectral pretreatments [first derivative (FD) and standard normal variate (SNV) followed by detrending] for rapid quantification of soil petroleum contamination. Additionally, a new analytical approach was proposed for the recovery of the pure spectral and concentration profiles of n-hexane present in the unresolved mixture of petroleum contaminated soils using multivariate curve resolution alternating least squares (MCR-ALS). The PSR model using FD spectra (r(2) = 0.87, RMSE = 0.580 log10 mg kg(-1), and residual prediction deviation = 2.78) outperformed all other models tested. Quantitative results obtained by MCR-ALS for n-hexane in presence of interferences (r(2) = 0.65 and RMSE 0.261 log10 mg kg(-1)) were comparable to those obtained using FD (PSR) model. Furthermore, MCR ALS was able to recover pure spectra of n-hexane.

  15. Analysis of petroleum contaminated soils by spectral modeling and pure response profile recovery of n-hexane.

    PubMed

    Chakraborty, Somsubhra; Weindorf, David C; Li, Bin; Ali, Md Nasim; Majumdar, K; Ray, D P

    2014-07-01

    This pilot study compared penalized spline regression (PSR) and random forest (RF) regression using visible and near-infrared diffuse reflectance spectroscopy (VisNIR DRS) derived spectra of 164 petroleum contaminated soils after two different spectral pretreatments [first derivative (FD) and standard normal variate (SNV) followed by detrending] for rapid quantification of soil petroleum contamination. Additionally, a new analytical approach was proposed for the recovery of the pure spectral and concentration profiles of n-hexane present in the unresolved mixture of petroleum contaminated soils using multivariate curve resolution alternating least squares (MCR-ALS). The PSR model using FD spectra (r(2) = 0.87, RMSE = 0.580 log10 mg kg(-1), and residual prediction deviation = 2.78) outperformed all other models tested. Quantitative results obtained by MCR-ALS for n-hexane in presence of interferences (r(2) = 0.65 and RMSE 0.261 log10 mg kg(-1)) were comparable to those obtained using FD (PSR) model. Furthermore, MCR ALS was able to recover pure spectra of n-hexane. PMID:24686115

  16. Effect of the ultrasound-Fenton oxidation process with the addition of a chelating agent on the removal of petroleum-based contaminants from soil.

    PubMed

    Li, Ying; Li, Fangmin; Li, Fanxiu; Yuan, Fuqian; Wei, Pingfang

    2015-12-01

    The effects of ultrasonic irradiation, the chelating agent modified Fenton reaction, and a combination of ultrasound and the Fenton method in removing petroleum contaminants from a soil were studied. The results showed that the contaminant removal rate of the Fenton treatment combined with an oxalic acid chelating agent was 55.6% higher than that without a chelating agent. The average removal rate of the contaminants using the ultrasound-Fenton treatment was 59.0% higher than that without ultrasonic treatment. A combination of ultrasound and an Fe(2+)/Fe(3+)-oxalate complex-modified Fenton reagent resulted in significantly higher removal rates of n-alkanes (C(n)H(2n+2), n < 28), isoprenoid hydrocarbons, aromatic hydrocarbons, and saturated polycyclic terpenes compared with the ultrasound treatment alone or the Fenton method. The Fenton reaction and the ultrasound-Fenton treatment can unselectively remove multiple components of residual hydrocarbons and a number of benzene rings in polycyclic aromatic hydrocarbons. The chemistry of the heterocyclic compounds and the position and number of substituents can affect the degradation process.

  17. Process development for the separation and recovery of Mo and Co from chloride leach liquors of petroleum refining catalyst by solvent extraction.

    PubMed

    Banda, Raju; Sohn, Seong Ho; Lee, Man Seung

    2012-04-30

    The separation and recovery of Mo and Co from the synthetic chloride leach liquors of petroleum refining catalyst has been investigated by employing TOPO and Alamine 308 as extractants. The synthetic leach liquor contained Mo 394 mg/L, Al 1782 mg/L, Co 119 mg/L in 3 M HCl. The separation of Mo from Co and Al was achieved with 0.05 M TOPO in Escaid 110 and complete stripping of Mo was attained with combination of 0.1M NH(4)OH and 0.05 M (NH(4))(2)CO(3). After separation of molybdenum, cobalt can be selectively extracted by Alamine 308 from Mo free raffinate after adjusting the concentration of chloride ion to 5 M by adding AlCl(3). The back-extraction of cobalt was obtained easily from loaded Alamine 308 with acidified water (pH=1.0). McCabe-Thiele diagrams were constructed from the extraction and stripping experiments of each element (Mo and Co). From the batch simulation of the counter-current extraction and stripping experiments, it was confirmed that Mo and Co recovery of 99.4% and 99.1% respectively was obtained from the synthetic leach liquor of the chloride solutions. Finally a hydrometallurgical process flow sheet was developed.

  18. Petroleum supply monthly, March 1999, with data for January 1999

    SciTech Connect

    1999-03-01

    The Petroleum Supply Monthly (PSM) is one of a family of four petroleum supply publications produced by the Petroleum Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the US and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the US (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the US. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics.

  19. Process correlation analysis model for process improvement identification.

    PubMed

    Choi, Su-jin; Kim, Dae-Kyoo; Park, Sooyong

    2014-01-01

    Software process improvement aims at improving the development process of software systems. It is initiated by process assessment identifying strengths and weaknesses and based on the findings, improvement plans are developed. In general, a process reference model (e.g., CMMI) is used throughout the process of software process improvement as the base. CMMI defines a set of process areas involved in software development and what to be carried out in process areas in terms of goals and practices. Process areas and their elements (goals and practices) are often correlated due to the iterative nature of software development process. However, in the current practice, correlations of process elements are often overlooked in the development of an improvement plan, which diminishes the efficiency of the plan. This is mainly attributed to significant efforts and the lack of required expertise. In this paper, we present a process correlation analysis model that helps identify correlations of process elements from the results of process assessment. This model is defined based on CMMI and empirical data of improvement practices. We evaluate the model using industrial data.

  20. Process Correlation Analysis Model for Process Improvement Identification

    PubMed Central

    Park, Sooyong

    2014-01-01

    Software process improvement aims at improving the development process of software systems. It is initiated by process assessment identifying strengths and weaknesses and based on the findings, improvement plans are developed. In general, a process reference model (e.g., CMMI) is used throughout the process of software process improvement as the base. CMMI defines a set of process areas involved in software development and what to be carried out in process areas in terms of goals and practices. Process areas and their elements (goals and practices) are often correlated due to the iterative nature of software development process. However, in the current practice, correlations of process elements are often overlooked in the development of an improvement plan, which diminishes the efficiency of the plan. This is mainly attributed to significant efforts and the lack of required expertise. In this paper, we present a process correlation analysis model that helps identify correlations of process elements from the results of process assessment. This model is defined based on CMMI and empirical data of improvement practices. We evaluate the model using industrial data. PMID:24977170

  1. BIODEGRADATION OF PETROLEUM-WASTE BY BIOSURFACTANT-PRODUCING BACTERIA

    SciTech Connect

    Brigmon, R; Grazyna A. Plaza, G; Kamlesh Jangid, K; Krystyna Lukasik, K; Grzegorz Nalecz-Jawecki, G; Topher Berry, T

    2007-05-16

    The degradation of petroleum waste by mixed bacterial cultures which produce biosurfactants: Ralstonia pickettii SRS (BP-20), Alcaligenes piechaudii SRS (CZOR L-1B), Bacillus subtilis (1'- 1a), Bacillus sp. (T-1) and Bacillus sp. (T'-1) was investigated. The total petroleum hydrocarbons were degraded substantially (91 %) by the mixed bacterial culture in 30 days (reaching up to 29 % in the first 72 h). Similarly, the toxicity of the biodegraded petroleum waste decreased 3 times after 30 days as compared to raw petroleum waste. Thus, the mixed bacterial strains effectively clean-up the petroleum waste and they can be used in other bioremediation processes.

  2. Petroleum marketing monthly

    SciTech Connect

    1996-02-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Monthly.

  3. Petroleum marketing monthly

    SciTech Connect

    1995-08-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Monthly.

  4. Petroleum marketing monthly

    SciTech Connect

    1996-07-01

    Petroleum Marketing Monthly (PPM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o. b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Monthly.

  5. Future petroleum geologist: discussion

    SciTech Connect

    Davis, G.D.

    1987-07-01

    Robert R. Berg's (1986) article, ''The Future Petroleum Geologist,'' summarizes the findings of the 13-member AAPG Select Committee on The Future Petroleum Geologist appointed by President William L. Fisher in July 1985. While this undertaking is laudable, particularly considering present circumstance in the petroleum industry, the committee has apparently overlooked a vital aspect concerning the future knowledge requirements of the petroleum geologist. Specifically, the Select Committee makes no mention of the need for computer literacy in its list of educational training categories. Obviously, AAPG is well aware of both the interest in computers by its membership and the increasing need for training and familiarity in this discipline. The Select Committee on The Future Petroleum Geologist, while undertaking a difficult and potentially controversial task, has omitted an important aspect of the background requirements for generations of future petroleum geologists; the committee should consider an amendment to their recommendations to reflect this increasingly important field study.

  6. Petroleum potential of wilderness lands in the Western United States

    USGS Publications Warehouse

    Miller, Betty M.

    1983-01-01

    In 1982-83, the U.S. Geological Survey (USGS) conducted an investigation of the oil and gas potential of the designated and proposed Wilderness Lands in the Western United States. The scope of this study was limited to the assessment of conventional recoverable petroleum resources occurring in the designated and proposed Wilderness Lands of the Western United States that are administered under four Federal agencies: Bureau of Land Management (BLM), U.S. Forest Service (USFS), National Park Service (NPS), and Fish and Wildlife Service (FWS). The total area of the study included approximately 74 million acres of Wilderness Lands in these 11 Western States: Arizona, California, Colorado, Idaho, Montana, Nevada, New Mexico, Oregon, Utah, Washington, and Wyoming. The 74 million acres represent 31 percent of the total Federal lands within these 11 Western States. Approximately 49 percent of all the lands in these States are federally owned. The objective of this study was to assemble through various means all the available pertinent information that could be brought together within the USGS and integrate these data into a computer-based digital cartographic data system that was focused upon the single issue of reviewing the known geological and geophysical data to determine the geologic characteristics favorable or unfavorable for the occurrence of petroleum resources in these Wilderness Lands. In a joint effort in the USGS between the Geologic Division (GD) and the National Mapping Division (NMD) all of the mappable information used in this study was prepared and processed by using digital cartographic techniques. These include digitizing the location and boundaries of the Wilderness Lands; acreage calculations; the boundaries of the USGS petroleum provinces; and the geologic and tectonic boundaries within each petroleum province and State. In addition, searches were conducted on well data files which provided the locations and geologic information on over 5,000 wells

  7. Combination of surfactant enhanced soil washing and electro-Fenton process for the treatment of soils contaminated by petroleum hydrocarbons.

    PubMed

    Huguenot, David; Mousset, Emmanuel; van Hullebusch, Eric D; Oturan, Mehmet A

    2015-04-15

    In order to improve the efficiency of soil washing treatment of hydrocarbon contaminated soils, an innovative combination of this soil treatment technique with an electrochemical advanced oxidation process (i.e. electro-Fenton (EF)) has been proposed. An ex situ soil column washing experiment was performed on a genuinely diesel-contaminated soil. The washing solution was enriched with surfactant Tween 80 at different concentrations, higher than the critical micellar concentration (CMC). The impact of soil washing was evaluated on the hydrocarbons concentration in the leachates collected at the bottom of the soil columns. These eluates were then studied for their degradation potential by EF treatment. Results showed that a concentration of 5% of Tween 80 was required to enhance hydrocarbons extraction from the soil. Even with this Tween 80 concentration, the efficiency of the treatment remained very low (only 1% after 24 h of washing). Electrochemical treatments performed thereafter with EF on the collected eluates revealed that the quasi-complete mineralization (>99.5%) of the hydrocarbons was achieved within 32 h according to a linear kinetic trend. Toxicity was higher than in the initial solution and reached 95% of inhibition of Vibrio fischeri bacteria measured by Microtox method, demonstrating the presence of remaining toxic compounds even after the complete degradation. Finally, the biodegradability (BOD₅/COD ratio) reached a maximum of 20% after 20 h of EF treatment, which is not enough to implement a combined treatment with a biological treatment process.

  8. The Independent Technical Analysis Process

    SciTech Connect

    Duberstein, Corey A.; Ham, Kenneth D.; Dauble, Dennis D.; Johnson, Gary E.

    2007-04-13

    The Bonneville Power Administration (BPA) contracted with the Pacific Northwest National Laboratory (PNNL) to provide technical analytical support for system-wide fish passage information (BPA Project No. 2006-010-00). The goal of this project was to produce rigorous technical analysis products using independent analysts and anonymous peer reviewers. In the past, regional parties have interacted with a single entity, the Fish Passage Center to access the data, analyses, and coordination related to fish passage. This project provided an independent technical source for non-routine fish passage analyses while allowing routine support functions to be performed by other well-qualified entities.

  9. Estimating the capability of microalgae to physiological acclimatization and genetic adaptation to petroleum and diesel oil contamination.

    PubMed

    Romero-Lopez, Julia; Lopez-Rodas, Victoria; Costas, Eduardo

    2012-11-15

    There is increasing scientific interest in how phytoplankton reacts to petroleum contamination, since crude oil and its derivatives are generating extensive contamination of aquatic environments. However, toxic effects of short-term petroleum exposure are more widely known than the adaptation of phytoplankton to long-term petroleum exposure. An analysis of short-term and long-term effects of petroleum exposure was done using experimental populations of freshwater (Scenedesmus intermedius and Microcystis aeruginosa) and marine (Dunaliella tertiolecta) microalgae isolated from pristine sites without crude oil product contamination. These strains were exposed to increased levels of petroleum and diesel oil. Short-term exposure to petroleum or diesel oil revealed a rapid inhibition of photosynthetic performance and cell proliferation in freshwater and marine phytoplankton species. A broad degree of inter-specific variation in lethal contamination level was observed. When different strains were exposed to petroleum or diesel oil over the long-term, the cultures showed massive destruction of the sensitive cells. Nonetheless, after further incubation, some cultures were able to grow again due to cells that were resistant to the toxins. By means of a fluctuation analysis, discrimination between cells that had become resistant due to physiological acclimatization and resistant cells arising from rare spontaneous mutations was accomplished. In addition, an analysis was done as to the maximum capacity of adaptation to a gradual contamination process. An experimental ratchet protocol was used, which maintains a strong selection pressure in a temporal scale up to several months over very large experimental populations of microalgae. Microalgae are able to survive to petroleum contamination as a result of physiological acclimatization without genetic changes. However, when petroleum concentration exceeds the physiological limits, survival depends exclusively on the occurrence on

  10. Vanadium tube processing and analysis

    SciTech Connect

    Kautz, D.D.; Tanaka, G.J.

    1993-08-11

    Vanadium tubing obtained from Century Tubes, a custom tubing manufacturer, was studied to determine as-received quality and fabricability. Applications for this tubing involve crimping and sealing operations at Pantex Plant requiring very high levels of leak-tightness (leak rates less than 10{sup {minus}8} atm-cc He/sec). The as-received material had poor OD and ID surface finish and cleanliness that needed to be improved before use in component fabrication. Savannah River Technical Center (SRTC) personnel developed a cleaning procedure to make this tubing acceptable for crimping and sealing operations. After suitably cleaning the tubing, we tested several tube sealing techniques and all showed some degree of success. Pantex Plant personnel are now implementing a tube sealing process very similar to one of the techniques studied, a mechanical crimp followed by seal welding.

  11. FRACTURED PETROLEUM RESERVOIRS

    SciTech Connect

    Abbas Firoozabadi

    1999-06-11

    different from that of gas displacement processes. The work is of experimental nature and clarifies several misconceptions in the literature. Based on experimental results, it is established that the main reason for high efficiency of solution gas drive from heavy oil reservoirs is due to low gas mobility. Chapter III presents the concept of the alteration of porous media wettability from liquid-wetting to intermediate gas-wetting. The idea is novel and has not been introduced in the petroleum literature before. There are significant implications from such as proposal. The most direct application of intermediate gas wetting is wettability alteration around the wellbore. Such an alteration can significantly improve well deliverability in gas condensate reservoirs where gas well deliverability decreases below dewpoint pressure. Part I of Chapter III studies the effect of gravity, viscous forces, interfacial tension, and wettability on the critical condensate saturation and relative permeability of gas condensate systems. A simple phenomenological network model is used for this study, The theoretical results reveal that wettability significantly affects both the critical gas saturation and gas relative permeability. Gas relative permeability may increase ten times as contact angle is altered from 0{sup o} (strongly liquid wet) to 85{sup o} (intermediate gas-wetting). The results from the theoretical study motivated the experimental investigation described in Part II. In Part II we demonstrate that the wettability of porous media can be altered from liquid-wetting to gas-wetting. This part describes our attempt to find appropriate chemicals for wettability alteration of various substrates including rock matrix. Chapter IV provides a comprehensive treatment of molecular, pressure, and thermal diffusion and convection in porous media Basic theoretical analysis is presented using irreversible thermodynamics.

  12. Petroleum refinery process and apparatus for the production of alkyl aromatic hydrocarbons from fuel gas and catalytic reformate

    SciTech Connect

    Harandi, M.N.; Kushnerick, J.D.; Owen, H.

    1991-02-12

    This paper describes a process for the production of gasoline. It comprises: contacting a feed stream comprising C{sub 4}{sup {minus}} olefin hydrocarbons with a feed stream comprising C{sub 6} to C{sub 8} aromatic hydrocarbons at an aromatic to olefin weight ratio of 5:1 to 20:1 over a fluidized zeolite catalyst at a temperature of 350{degrees} to 900{degrees}F a pressure of 20 to 650 psig in a riser reactor having multiple olefin feed injection points to alkylate the C{sub 6}-C{sub 8} aromatics with the olefins to form C{sub 7} to C{sub 11} alkyl aromatic hydrocarbon gasoline products, wherein the multiple olefin feed injection points are spaced along the height of the riser reactor and the aforethe aromatic to olefin weight ratio is maintained throughout the riser reactor and withdrawing a portion of the catalyst from the riser for regeneration of the catalyst the withdrawn catalyst containing only a minor amount of deposited coke.

  13. Petroleum: An Energy Profile 1999

    EIA Publications

    1999-01-01

    Explains in layman's terms the major components and operations of the U.S. petroleum industry that include: petroleum products, resources and reserves, drilling and exploration, refining, storage and transportation, imports, exports, and petroleum marketing.

  14. Petroleum 1996: Issues and Trends

    EIA Publications

    1997-01-01

    Examines historical trends and focuses on major petroleum issues and the events they represent. It analyzes different dimensions of the petroleum industry and related markets in terms of how they relate to the volatility in petroleum markets.

  15. Petroleum supply monthly, March 1995 with data for January 1995

    SciTech Connect

    1995-03-30

    Data presented in this report for March 1995, describes the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States.

  16. Petroleum supply monthly, August 1995 with data for June 1995

    SciTech Connect

    1995-08-25

    Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics.

  17. Assessment of the impact of petroleum and petrochemical industries to the surrounding areas in Malaysia using mosses as bioindicator supported by multivariate analysis.

    PubMed

    Abdullah, Mohd Zahari Bin; Saat, Ahmad Bin; Hamzah, Zaini Bin

    2012-06-01

    Biomonitoring of multi-element atmospheric deposition using terrestrial moss is a well-established technique in Europe. Although the technique is widely known, there were very limited records of using this technique to study atmospheric air pollution in Malaysia. In this present study, the deposition of 11 trace metals surrounding the main petroleum refinery plant in Kerteh Terengganu (eastern part of peninsular Malaysia) has been evaluated using two local moss species, namely Hypnum plumaeforme and Taxithelium instratum as bioindicators. The study was also done by means of observing whether these metals are attributed to work related to oil exploration in this area. The moss samples have been collected at 30 sampling stations in the vicinity of the petrochemical industrial area covering up to 15 km to the south, north, and west in radius. The contents of heavy metal in moss samples were analyzed by energy dispersive x-ray fluorescence technique. Distribution of heavy metal content in all mosses is portrayed using Surfer software. Areas of the highest level of contaminations are highlighted. The results obtained using the principal components analysis revealed that the elements can be grouped into three different components that indirectly reflected three different sources namely anthropogenic factor, vegetation factor, and natural sources (soil dust or substrate) factor. Heavy metals deposited mostly in the distance after 9 km onward to the western part (the average direction of wind blow). V, Cr, Cu, and Hg are believed to have originated from local petrochemical-based industries operated around petroleum industrial area.

  18. Assessment of the impact of petroleum and petrochemical industries to the surrounding areas in Malaysia using mosses as bioindicator supported by multivariate analysis.

    PubMed

    Abdullah, Mohd Zahari Bin; Saat, Ahmad Bin; Hamzah, Zaini Bin

    2012-06-01

    Biomonitoring of multi-element atmospheric deposition using terrestrial moss is a well-established technique in Europe. Although the technique is widely known, there were very limited records of using this technique to study atmospheric air pollution in Malaysia. In this present study, the deposition of 11 trace metals surrounding the main petroleum refinery plant in Kerteh Terengganu (eastern part of peninsular Malaysia) has been evaluated using two local moss species, namely Hypnum plumaeforme and Taxithelium instratum as bioindicators. The study was also done by means of observing whether these metals are attributed to work related to oil exploration in this area. The moss samples have been collected at 30 sampling stations in the vicinity of the petrochemical industrial area covering up to 15 km to the south, north, and west in radius. The contents of heavy metal in moss samples were analyzed by energy dispersive x-ray fluorescence technique. Distribution of heavy metal content in all mosses is portrayed using Surfer software. Areas of the highest level of contaminations are highlighted. The results obtained using the principal components analysis revealed that the elements can be grouped into three different components that indirectly reflected three different sources namely anthropogenic factor, vegetation factor, and natural sources (soil dust or substrate) factor. Heavy metals deposited mostly in the distance after 9 km onward to the western part (the average direction of wind blow). V, Cr, Cu, and Hg are believed to have originated from local petrochemical-based industries operated around petroleum industrial area. PMID:21822578

  19. Fundamentals of Petroleum.

    ERIC Educational Resources Information Center

    Bureau of Naval Personnel, Washington, DC.

    Basic information on petroleum is presented in this book prepared for naval logistics officers. Petroleum in national defense is discussed in connection with consumption statistics, productive capacity, world's resources, and steps in logistics. Chemical and geological analyses are made in efforts to familiarize methods of refining, measuring,…

  20. An Air-Stripping Packed Bed Combined with a Biofilm-Type Biological Process for Treating BTEX and Total Petroleum Hydrocarbon Contaminated Groudwater

    NASA Astrophysics Data System (ADS)

    Hong, U.; Park, S.; Lim, J.; Lee, W.; Kwon, S.; Kim, Y.

    2009-12-01

    In this study, we examined the removal efficiency of a volatile compound (e.g. toluene) and a less volatile compound [e.g. total petroleum hydrocarbon (TPH)] using an air stripping packed bed combined with a biofilm-type biological process. We hypothesized that this system might be effective and economical to simultaneously remove both volatile and less volatile compounds. The gas-tight reactor has 5.9-inch-diameter and 48.8-inch-height. A spray nozzle was installed at the top cover to distribute the liquid evenly through reactor. The reactor was filled with polypropylene packing media for the increase of volatilization surface area and the growth of TPH degrading facultative aerobic bacteria on the surface of the packing media. In air stripping experiments, 45.6%, 71.7%, 72.0%, and 75.4% of toluene was removed at air injection rates of 0 L/min, 2.5 L/min, 4 L/min, and 6 L/min, respectively. Through the result, we confirmed that toluene removal efficiency increased by injecting higher amounts of air. TPH removal by stripping was minimal. To remove a less volatile TPH by commercial TPH degrading culture (BIO-ZYME B-52), 15-times diluted culture was circulated through the reactor for 2-3 days to build up a biofilm on the surface of packing media with 1 mg-soluble nitrogen source /L-water per 1 ppm of TPH. Experiments evaluating the degree of TPH biodegradation in this system are carrying out.

  1. World petroleum supplies

    NASA Astrophysics Data System (ADS)

    Bell, Peter M.

    A number of conclusions by political conservatives about the fate of world petroleum supplies have been emerging lately. Among the most recent of them arose from discussions, held at the 1983 spring meeting of the American Association for the Advancement of Science (AAAS), which focused on the environment and resource study entitled “The Global 2000 Report” (New Scientist, June 9, 1983). Fred Singer, representing the Heritage Foundation of Washington, D.C., criticized the report, which predicted shortages in the near future, saying that the current world-wide oil glut will continue beyond the year 2000. Alternatives to the use of petroleum are a part of the cause. Singer argued that conservation, nuclear energy, and other petroleum substitutes will continue to suppress the demand for petroleum. In addition, according to other evaluations, exploration for petroleum and natural gas has not really begun.

  2. Petroleum supply monthly, with data for September 1995

    SciTech Connect

    1995-11-01

    The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major U.S. geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States.

  3. Petroleum supply monthly - with data for May 1996

    SciTech Connect

    1996-07-01

    The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major U.S. geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. This document contains a glossary.

  4. Petroleum supply monthly, September 1995 with data for July 1995

    SciTech Connect

    1995-09-27

    The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics.

  5. Petroleum Supply Monthly, September 1998, with data for July 1998

    SciTech Connect

    1998-09-28

    The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the suppiy and disposition of petroleum products in the United States and major U.S. geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics

  6. Petroleum supply monthly, May 1995 with data for March 1995

    SciTech Connect

    1995-05-25

    The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States.Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics.

  7. Petroleum supply monthly, June 1995 with data for April 1995

    SciTech Connect

    1995-06-28

    The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics.

  8. Petroleum Supply Monthly, March 1996 (with data for January 1996)

    SciTech Connect

    1996-04-04

    The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics.

  9. Petroleum supply monthly, July 1995 with data for May 1995

    SciTech Connect

    1995-07-27

    The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics.

  10. Petroleum supply monthly with data from April 1996

    SciTech Connect

    1996-06-01

    The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major U.S. geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States.

  11. Petroleum supply monthly, with data for August 1996

    SciTech Connect

    1996-10-01

    The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major U.S. geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States.

  12. Basin Analysis and Petroleum System Characterization and Modeling, Interior Salt Basins, Central and Eastern Gulf of Mexico

    SciTech Connect

    Ernest A. Mancini; Paul Aharon; Donald A. Goddard; Roger Barnaby

    2006-05-26

    The principal research effort for Phase 1 (Concept Development) of the project has been data compilation; determination of the tectonic, depositional, burial, and thermal maturation histories of the North Louisiana Salt Basin; basin modeling (geohistory, thermal maturation, hydrocarbon expulsion); petroleum system identification; comparative basin evaluation; and resource assessment. Existing information on the North Louisiana Salt Basin has been evaluated, an electronic database has been developed, and regional cross sections have been prepared. Structure, isopach and formation lithology maps have been constructed, and burial history, thermal maturation history, and hydrocarbon expulsion profiles have been prepared. Seismic data, cross sections, subsurface maps and burial history, thermal maturation history, and hydrocarbon expulsion profiles have been used in evaluating the tectonic, depositional, burial and thermal maturation histories of the basin. Oil and gas reservoirs have been found to be associated with salt-supported anticlinal and domal features (salt pillows, turtle structures and piercement domes); with normal faulting associated with the northern basin margin and listric down-to-the-basin faults (state-line fault complex) and faulted salt features; and with combination structural and stratigraphic features (Sabine and Monroe Uplifts) and monoclinal features with lithologic variations. Petroleum reservoirs include Upper Jurassic and Cretaceous fluvial-deltaic sandstone facies; shoreline, marine bar and shallow shelf sandstone facies; and carbonate shoal, shelf and reef facies. Cretaceous unconformities significantly contribute to the hydrocarbon trapping mechanism capacity in the North Louisiana Salt Basin. The chief petroleum source rock in this basin is Upper Jurassic Smackover lime mudstone beds. The generation of hydrocarbons from Smackover lime mudstone was initiated during the Early Cretaceous and continued into the Tertiary. Hydrocarbon

  13. Comparative toxicity of crude and refined coal liquids and analogous petroleum products: II. Chemical characterization. [Products of H-Coal process

    SciTech Connect

    Griest, W.H.; Ho, C.H.; Guerin, M.R.; Witschi, H.P.; Smith, L.H.

    1986-04-01

    In Part I of this paper, the dermal tumorigenicity of crude and hydrogenated H-Coal Blends, a home heating oil and a reformed naphtha refined from the hydrotreated H-Coal Blend, and two analogous petroleum products is reported. This paper compares the tumorigenicity assay results with the chemistry of the samples.

  14. An introduction to computerized x-ray tomography for petroleum research

    SciTech Connect

    Castanier, L.M.

    1989-06-01

    This report summarizes the state of the art in the application of medical tomography (CT) to petroleum recovery problems. A brief review of the basic principles of x-ray computerized tomography is followed by a discussion of the governing equations of the method. Calculation techniques and appropriate correlations for continued testing are described and discussed. A review of existing medical software is done. Consideration of the specific software needed for petroleum engineering as well as applications of new technologies such as image processing and computer networking are described. Criteria for the choice of a machine suitable for most petroleum-related applications are given. Emphasis is placed on flexibility, reliability, accuracy and price of the scanner. Two separate sections discuss positioning of the core and design of the core holders. Examples of possible applications of CT scanning to problems of geology, core analysis, EOR as well as operational process problems are discussed. 9 refs., 8 figs., 1 tab.

  15. Artificial intelligence applied to process signal analysis

    NASA Technical Reports Server (NTRS)

    Corsberg, Dan

    1988-01-01

    Many space station processes are highly complex systems subject to sudden, major transients. In any complex process control system, a critical aspect of the human/machine interface is the analysis and display of process information. Human operators can be overwhelmed by large clusters of alarms that inhibit their ability to diagnose and respond to a disturbance. Using artificial intelligence techniques and a knowledge base approach to this problem, the power of the computer can be used to filter and analyze plant sensor data. This will provide operators with a better description of the process state. Once a process state is recognized, automatic action could be initiated and proper system response monitored.

  16. Vygotsky's Analysis of Children's Meaning Making Processes

    ERIC Educational Resources Information Center

    Mahn, Holbrook

    2012-01-01

    Vygotsky's work is extensive and covers many aspects of the development of children's meaning-making processes in social and cultural contexts. However, his main focus is on the examination of the unification of speaking and thinking processes. His investigation centers on the analysis of the entity created by this unification--an internal…

  17. Encapsulation Processing and Manufacturing Yield Analysis

    NASA Technical Reports Server (NTRS)

    Willis, P. B.

    1984-01-01

    The development of encapsulation processing and a manufacturing productivity analysis for photovoltaic cells are discussed. The goals were: (1) to understand the relationships between both formulation variables and process variables; (2) to define conditions required for optimum performance; (3) to predict manufacturing yield; and (4) to provide documentation to industry.

  18. Identification, mapping, and analysis of possible evidences of active petroleum systems in the Colorado Basin, offshore Argentina, South America

    NASA Astrophysics Data System (ADS)

    Loegering, Markus; Anka, Zahie; Rodriguez, Jorge; Marchal, Denis; di Primio, Rolando; Vallejo, Eduardo; Kohler, Guillermina; Pangaro, Francisco

    2010-05-01

    The analysis of a dense 2D seismic reflection dataset and 12 exploration wells data, allowed us to reconstruct the geological evolution of the Colorado Basin, offshore Argentina. We identified and mapped the major syn- and post-rift seismic sequences, and their boundaries such as unconformities and regional seismic markers, present on the continental shelf and slope (water depths from 50 to 1800 m) of the Colorado Basin. Seismic-to-well log correlations, as well as integration with biostratigraphic data provided a chrono-stratigraphic framework for the interpreted horizons. The construction of isochronal (twt) maps provided a 3D spatial visualisation of the stratigraphic relationship among the sequences. The maps show a change in configuration from the break-up unconformity (130 Ma) to the present-day seafloor. The break-up unconformity displays a central EW-elongated graben which prevails on the overlying sequences up to the Miocene. The EW Colorado basin turns NW-SE towards the East, going perpendicular to the present-day continental margin (oriented NE-SW). The strong obliquity of the basin orientation related to the direction corresponding to the opening of the South Atlantic (NE-SW) suggests a structural control from the pre-rift basement on the rift and post-rift sequences. Starting from the break-up unconformity, the history of basin filling is illustrated up to the flat seafloor. The basin sag phase is represented by the sequences deposited between the break-up unconformity and the Colorado discontinuity (Aptian to Campanian). The Campanian to Eocene successions are more or less parallel- layered suggesting sequence aggradation. The distribution of liquid/gas hydrocarbon-leakage features (i.e. gas chimneys, mud volcanoes, and seabed pockmarks) should allow the definition of potential migration pathways. In this sense, a systematic mapping of these paleo- and present-day features observed in the seismic profiles has been performed and their distribution was

  19. [National Institute for Petroleum and Energy Research]quarterly technical report, January 1--March 31, 1992. Volume 1, Fuels research

    SciTech Connect

    Not Available

    1992-05-01

    The objectives of ``Development of Analytical Methodology for Analysis of Heavy Crudes`` are to identify compounds or classes of compounds with significant positive or negative effects on crude oil and/or product properties nd characteristics and to develop methods for their determination in conventional or low grade petroleum and syncrudes; specific objectives for FY92 are: (1) to determine catalytic cracking behavior of individual compound classes in petroleum, and (2) to further develop GC/MS methodology for speciation of nitrogen and sulfur compound in petroleum. The objectives of ``Thermochemistry and Thermophysical Properties of Organic Nitrogen and Diheteroatom-Containing Compounds`` is to provide, interpret, and correlate with molecular structure and polarity of molecules, precise and accurate values of thermodynamic properties of organic nitrogen and diheteroatom-containing compounds that occur in or are readily derivable from heavy petroleum and oil shale. The results will enable the prediction of chemical equilibria for conceptual as well as current processes.

  20. Development, optimization, validation and application of faster gas chromatography - flame ionization detector method for the analysis of total petroleum hydrocarbons in contaminated soils.

    PubMed

    Zubair, Abdulrazaq; Pappoe, Michael; James, Lesley A; Hawboldt, Kelly

    2015-12-18

    This paper presents an important new approach to improving the timeliness of Total Petroleum Hydrocarbon (TPH) analysis in the soil by Gas Chromatography - Flame Ionization Detector (GC-FID) using the CCME Canada-Wide Standard reference method. The Canada-Wide Standard (CWS) method is used for the analysis of petroleum hydrocarbon compounds across Canada. However, inter-laboratory application of this method for the analysis of TPH in the soil has often shown considerable variability in the results. This could be due, in part, to the different gas chromatography (GC) conditions, other steps involved in the method, as well as the soil properties. In addition, there are differences in the interpretation of the GC results, which impacts the determination of the effectiveness of remediation at hydrocarbon-contaminated sites. In this work, multivariate experimental design approach was used to develop and validate the analytical method for a faster quantitative analysis of TPH in (contaminated) soil. A fractional factorial design (fFD) was used to screen six factors to identify the most significant factors impacting the analysis. These factors included: injection volume (μL), injection temperature (°C), oven program (°C/min), detector temperature (°C), carrier gas flow rate (mL/min) and solvent ratio (v/v hexane/dichloromethane). The most important factors (carrier gas flow rate and oven program) were then optimized using a central composite response surface design. Robustness testing and validation of model compares favourably with the experimental results with percentage difference of 2.78% for the analysis time. This research successfully reduced the method's standard analytical time from 20 to 8min with all the carbon fractions eluting. The method was successfully applied for fast TPH analysis of Bunker C oil contaminated soil. A reduced analytical time would offer many benefits including an improved laboratory reporting times, and overall improved clean up

  1. Development, optimization, validation and application of faster gas chromatography - flame ionization detector method for the analysis of total petroleum hydrocarbons in contaminated soils.

    PubMed

    Zubair, Abdulrazaq; Pappoe, Michael; James, Lesley A; Hawboldt, Kelly

    2015-12-18

    This paper presents an important new approach to improving the timeliness of Total Petroleum Hydrocarbon (TPH) analysis in the soil by Gas Chromatography - Flame Ionization Detector (GC-FID) using the CCME Canada-Wide Standard reference method. The Canada-Wide Standard (CWS) method is used for the analysis of petroleum hydrocarbon compounds across Canada. However, inter-laboratory application of this method for the analysis of TPH in the soil has often shown considerable variability in the results. This could be due, in part, to the different gas chromatography (GC) conditions, other steps involved in the method, as well as the soil properties. In addition, there are differences in the interpretation of the GC results, which impacts the determination of the effectiveness of remediation at hydrocarbon-contaminated sites. In this work, multivariate experimental design approach was used to develop and validate the analytical method for a faster quantitative analysis of TPH in (contaminated) soil. A fractional factorial design (fFD) was used to screen six factors to identify the most significant factors impacting the analysis. These factors included: injection volume (μL), injection temperature (°C), oven program (°C/min), detector temperature (°C), carrier gas flow rate (mL/min) and solvent ratio (v/v hexane/dichloromethane). The most important factors (carrier gas flow rate and oven program) were then optimized using a central composite response surface design. Robustness testing and validation of model compares favourably with the experimental results with percentage difference of 2.78% for the analysis time. This research successfully reduced the method's standard analytical time from 20 to 8min with all the carbon fractions eluting. The method was successfully applied for fast TPH analysis of Bunker C oil contaminated soil. A reduced analytical time would offer many benefits including an improved laboratory reporting times, and overall improved clean up

  2. Analysis of physical processes via imaging vectors

    NASA Astrophysics Data System (ADS)

    Volovodenko, V.; Efremova, N.; Efremov, V.

    2016-06-01

    Practically, all modeling processes in one way or another are random. The foremost formulated theoretical foundation embraces Markov processes, being represented in different forms. Markov processes are characterized as a random process that undergoes transitions from one state to another on a state space, whereas the probability distribution of the next state depends only on the current state and not on the sequence of events that preceded it. In the Markov processes the proposition (model) of the future by no means changes in the event of the expansion and/or strong information progression relative to preceding time. Basically, modeling physical fields involves process changing in time, i.e. non-stationay processes. In this case, the application of Laplace transformation provides unjustified description complications. Transition to other possibilities results in explicit simplification. The method of imaging vectors renders constructive mathematical models and necessary transition in the modeling process and analysis itself. The flexibility of the model itself using polynomial basis leads to the possible rapid transition of the mathematical model and further analysis acceleration. It should be noted that the mathematical description permits operator representation. Conversely, operator representation of the structures, algorithms and data processing procedures significantly improve the flexibility of the modeling process.

  3. CPAS Preflight Drop Test Analysis Process

    NASA Technical Reports Server (NTRS)

    Englert, Megan E.; Bledsoe, Kristin J.; Romero, Leah M.

    2015-01-01

    Throughout the Capsule Parachute Assembly System (CPAS) drop test program, the CPAS Analysis Team has developed a simulation and analysis process to support drop test planning and execution. This process includes multiple phases focused on developing test simulations and communicating results to all groups involved in the drop test. CPAS Engineering Development Unit (EDU) series drop test planning begins with the development of a basic operational concept for each test. Trajectory simulation tools include the Flight Analysis and Simulation Tool (FAST) for single bodies, and the Automatic Dynamic Analysis of Mechanical Systems (ADAMS) simulation for the mated vehicle. Results are communicated to the team at the Test Configuration Review (TCR) and Test Readiness Review (TRR), as well as at Analysis Integrated Product Team (IPT) meetings in earlier and intermediate phases of the pre-test planning. The ability to plan and communicate efficiently with rapidly changing objectives and tight schedule constraints is a necessity for safe and successful drop tests.

  4. [Identification of Hydrocarbon-Oxidizing Dietzia Bacteria from Petroleum Reservoirs Based on Phenotypic Properties and Analysis of the 16S rRNA and gyrB Genes].

    PubMed

    Nazina, T N; Shumkova, E S; Sokolova, D Sh; Babich, T L; Zhurina, M V; Xue, Yan-Fen; Osipov, G A; Poltaraus, A B; Tourova, T P

    2015-01-01

    The taxonomic position of hydrocarbon-oxidizing bacterial strains 263 and 32d isolated from formation water of the Daqing petroleum reservoir (PRC) was determined by polyphasic taxonomy techniques, including analysis of the 16S rRNA and the gyrB genes. The major chemotaxonomic characteristics of both strains, including the IV type cell wall, composition of cell wall fatty acids, mycolic acids, and menaquinones, agreed with those typical of Dietzia strains. The DNA G+C content of strains 263 and 32d were 67.8 and 67.6 mol%, respectively. Phylogenetic analysis of the 16S rRNA gene of strain 32d revealed 99.7% similarity to the gene of D. maris, making it possible to identify strain 32d as belonging to this species. The 16S rRNA gene sequence of strain 263 exhibited 99.7 and 99.9% similarity to those of D. natronolimnaea and D. cercidiphylli YIM65002(T), respectively. Analysis of the gyrB genes of the subterranean isolates and of a number of Dietzia type strains confirmed classiffication of strain 32d as a D. maris strain and of strain 263, as a D. natronolimnaea strain. A conclusion was made concerning higher resolving power of phylogenetic analysis of the gyrB gene compared to the 16S rRNA gene analysis in the case of determination of the species position of Dietzia isolates.

  5. Planar Inlet Design and Analysis Process (PINDAP)

    NASA Technical Reports Server (NTRS)

    Slater, John W.; Gruber, Christopher R.

    2005-01-01

    The Planar Inlet Design and Analysis Process (PINDAP) is a collection of software tools that allow the efficient aerodynamic design and analysis of planar (two-dimensional and axisymmetric) inlets. The aerodynamic analysis is performed using the Wind-US computational fluid dynamics (CFD) program. A major element in PINDAP is a Fortran 90 code named PINDAP that can establish the parametric design of the inlet and efficiently model the geometry and generate the grid for CFD analysis with design changes to those parameters. The use of PINDAP is demonstrated for subsonic, supersonic, and hypersonic inlets.

  6. Carbonate petroleum reservoirs

    SciTech Connect

    Roehl, P.O.; Choquette, P.W.

    1985-01-01

    This book presents papers on the geology of petroleum deposits. Topics considered include diagenesis, porosity, dolomite reservoirs, deposition, reservoir rock, reefs, morphology, fracture-controlled production, Cenozoic reservoirs, Mesozoic reservoirs, and Paleozoic reservoirs.

  7. Two stochastic models useful in petroleum exploration

    NASA Technical Reports Server (NTRS)

    Kaufman, G. M.; Bradley, P. G.

    1972-01-01

    A model of the petroleum exploration process that tests empirically the hypothesis that at an early stage in the exploration of a basin, the process behaves like sampling without replacement is proposed along with a model of the spatial distribution of petroleum reserviors that conforms to observed facts. In developing the model of discovery, the following topics are discussed: probabilitistic proportionality, likelihood function, and maximum likelihood estimation. In addition, the spatial model is described, which is defined as a stochastic process generating values of a sequence or random variables in a way that simulates the frequency distribution of areal extent, the geographic location, and shape of oil deposits

  8. Romania's petroleum systems

    SciTech Connect

    Stefanescu, M.O. ); Popescu, B.M. )

    1993-09-01

    In Romania, nine onshore petroleum systems and one offshore petroleum system have recently been identified. Of the onshore systems, three are related to the compressional folded basins: Teleajen-Sita (early Middle Cretaceous marine source rocks), and Puciossa-Fusaru and Alunis-Kliwa (Oligocene-early Miocene marine source rocks). In the same category, we have included the recently discovered Deleni petroleum system with source rocks of not yet identified origin but whose reservoirs certainly belong to a folded basin. In the foreland platform basins, two systems can be distinguished: Rimesti-Fauresti (Middle Jurassic marine source rocks) and Infra-Anhydrite (with presumed Middle Jurassic or middle Miocene marine source rocks). The areas corresponding to the posttectonic basins include three onshore petroleum systems and one offshore system: the Pannonian (Badenian marine and Sarmatian brackish water source rocks), the Valea Caselor-Borsa (oligocene marine source rocks) and the Transylvanian (Badenian marine shales source and Sarmatian brackish water source rocks). Offshore, there is only one petroleum system consisting of Oligocene-Miocene marine source rock and Cretaceous or Eocene reservoirs. The majority of the mentioned petroleum systems reservoirs are Paleozoic to Pliocene clastics, but in the platform areas, carbonate reservoirs are found in the Paleozoic and Mesozoic. In all the petroleum systems, despite the different ages of the source rocks, most of the hydrocarbons have been expelled relatively recently during the Late Sarmatian-Pliocene interval. This face is substantiated by examples from two petroleum systems: the Rimesti-Fauresti (duration time 173 m.y., preservation 2 m.y.) and the Alunis-Kliwa (duration time 29-30 m.y., preservation 4 m.y.). The hydrocarbons were first expelled and migrated into described systems reservoirs after Late Styrian and Moldavian overthrusting, i.e. not earlier than 12-14 m.y.

  9. Sedimentology and petroleum geology

    SciTech Connect

    Bjorlykke, K.O. )

    1989-01-01

    This book presents an introduction to sedimentology as well as petroleum geology. It integrates both subjects, which are closely related but mostly treated separately. The author covers the basic aspects of sedimentology, sedimentary geochemistry and diagenesis. Principles of stratigraphy, seismic stratigraphy and basin modelling forms the base for the part on petroleum geology. Subjects discussed include the composition of kerogen and hydrocarbons, theories of migration and trapping of hydrocarbons and properties of reservoir rocks. Introductions to well logging and production geology are given.

  10. Petroleum basin studies

    SciTech Connect

    Shannon, P.M. ); Naylor, D. )

    1989-01-01

    This book reviews the tectonic setting, basin development and history of exploration of a number of selected petroleum provinces located in a variety of settings in the Middle East, North Sea, Nigeria, the Rocky Mountains, Gabon and China. This book illustrates how ideas and models developed in one area may be applied to other regions. Regional reviews and the reassessment of petroleum provinces are presented.

  11. Size-frequency analysis of petroleum accumulations in selected United States plays: potential analogues for frontier areas

    USGS Publications Warehouse

    Attanasi, E.D.; Freeman, P.A.

    2004-01-01

    This report presents the petroleum accumulation size-frequency relationships of selected mature plays assessed in the U.S. Geological Survey?s 1995 National Assessment of Oil and Gas Resources. The plays provide assessors with potential analogue models from which to estimate the numbers of undiscovered accumulations in medium and smaller size categories. Each play selected was required to have at least 50 discovered accumulations. Discovered accumulations plus the mean number of undiscovered accumulations equals the total accumulations assessed at the play level. There were 36 plays that met the criteria for oil accumulations and 25 plays that met the criteria for gas accumulations. Other properties of the plays such as primary trap type, lithology, depth, and hydrocarbon characteristics are also provided to assist the geologist in choosing an appropriate analogue. The text explains how the analogue size-frequency relationships can be used to estimate the number of small and medium size accumulations for frontier-area plays or partially explored plays in high cost areas. Although this document has been written in support of the Alaska North Slope Assessment, the basic size?frequency relationships provided are applicable elsewhere.

  12. Oxygenation of petroleum hydrocarbons after the Deepwater Horizon disaster

    NASA Astrophysics Data System (ADS)

    Aeppli, C.; Valentine, D. L.; Arakawa, N.; Aluwihare, L. I.; Redmond, M. C.; Nelson, R. K.; Reddy, C. M.

    2012-12-01

    The release of petroleum hydrocarbons after the Deepwater Horizon incident served as a model to study petroleum oxygenation in marine systems. While such processes are well established to remove select hydrocarbons from the ocean, little attention has been given to the formed product of oil weathering: oxygenated hydrocarbons (OxHC). As they are outside the analytical windows of most commonly used method for oil spill research, OxHC have mostly been overlooked so far. However, we found that OxHC were rapidly formed during the first 100 days after the onset of the Deepwater Horizon spill, and made up 50-90% of the weathered oil mass thereafter. The OxHC fraction had an oxygen content of >10% by mass, contained carboxylic acids and alcohols, and was petroleum-derived, as confirmed by radiocarbon analysis (Aeppli et al, 2012). To investigate the oxygen incorporation processes and products, we used two strategies. First, we employed selective chemical modification of OxHC that preserved their carbon backbones while making the compounds amenable to gas chromatography for structural elucidation. This strategy allowed us to identify saturated and aromatic compounds as parent compounds of OxHC. Second, we used stable oxygen isotopes as a proxy for oxygenation, and observed O-18 enrichment with increasing degree of weathering. Overall, this study sheds light on how oil hydrocarbons are oxygenated via microbial and photochemical transformation, leading to recalcitrant products of oil weathering. Reference: Aeppli et al., (2012). Environ Sci Technol, doi:10.1021/es3015138

  13. Genetic features of petroleum systems in rift basins of eastern China

    USGS Publications Warehouse

    Qiang, J.; McCabe, P.J.

    1998-01-01

    Most oil-bearing basins in eastern China are Mesozoic-Cenozoic continental rifts which have played a habitat for oil and gas in China. Investigation of the petroleum systems may give a better understanding of the oil and gas habitats in these basins. Of the essential elements of the petroleum system, the source rock is the most important in rift basins. However, rift tectonic evolution controls all the essential elements and processes nevessary for a petroleum system. A four stage evolution model is suggested for the controls in the rift basin. A rift basin may consist of sub-basins, depressions, sub-depressions, and major, moderate, and minor uplifts. A depression or sub-depression has its own depocentre (mainly occupied by source rock) and all kinds of lacustrine sediments, and thus has all the essential elements of a petroleum system. However, only those depressions or sub-depressions which are rich in organic matter and deeply buried to generate oil and gas form petroleum systems. Immature oil, another characteristic, complicates the petroleum system in the rift basins. Three types of oil and gas habitats are described as a result of this analysis of the petroleum systems of the 26 largest oil and gas fields discovered in eastern China rift basins: uplifts between oil source centres are the most prospective areas for oil and gas accumulations, slopes connecting oil source centres and uplifts are the second, and the third type is subtle traps in the soil source centre.Most oil-bearing basins in eastern China are Mesozoic-Cenozoic continental rifts which have played a habitat for oil and gas in China. Investigation of the petroleum systems may give a better understanding of the oil and gas habitats in these basins. Of the essential elements of the petroleum system, the source rock is the most important in rift basins. However, rift tectonic evolution controls all the essential elements and processes necessary for a petroleum system. A four stage evolution model

  14. Sneak analysis applied to process systems

    NASA Astrophysics Data System (ADS)

    Whetton, Cris

    Traditional safety analyses, such as HAZOP, FMEA, FTA, and MORT, are less than effective at identifying hazards resulting from incorrect 'flow' - whether this be flow of information, actions, electric current, or even the literal flow of process fluids. Sneak Analysis (SA) has existed since the mid nineteen-seventies as a means of identifying such conditions in electric circuits; in which area, it is usually known as Sneak Circuit Analysis (SCA). This paper extends the ideas of Sneak Circuit Analysis to a general method of Sneak Analysis applied to process plant. The methods of SA attempt to capitalize on previous work in the electrical field by first producing a pseudo-electrical analog of the process and then analyzing the analog by the existing techniques of SCA, supplemented by some additional rules and clues specific to processes. The SA method is not intended to replace any existing method of safety analysis; instead, it is intended to supplement such techniques as HAZOP and FMEA by providing systematic procedures for the identification of a class of potential problems which are not well covered by any other method.

  15. Reductions in Northeast Refining Activity: Potential Implications for Petroleum Product Markets

    EIA Publications

    2011-01-01

    This report is the Energy Information Administration's (EIA) initial effort to provide information and analysis on the potential impacts on petroleum product markets from reductions in Northeast petroleum refining activity.

  16. U.S. Virgin Islands Transportation Petroleum Reduction Plan

    SciTech Connect

    Johnson, C.

    2011-09-01

    This NREL technical report determines a way for USVI to meet its petroleum reduction goal in the transportation sector. It does so first by estimating current petroleum use and key statistics and characteristics of USVI transportation. It then breaks the goal down into subordinate goals and estimates the petroleum impacts of these goals with a wedge analysis. These goals focus on reducing vehicle miles, improving fuel economy, improving traffic flow, using electric vehicles, using biodiesel and renewable diesel, and using 10% ethanol in gasoline. The final section of the report suggests specific projects to achieve the goals, and ranks the projects according to cost, petroleum reduction, time frame, and popularity.

  17. 31 CFR 542.314 - Petroleum or petroleum products of Syrian origin.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Petroleum or petroleum products of... REGULATIONS General Definitions § 542.314 Petroleum or petroleum products of Syrian origin. The term petroleum or petroleum products of Syrian origin means petroleum or petroleum products of Syrian...

  18. Sustainability Analysis for Products and Processes

    EPA Science Inventory

    Sustainability Analysis for Products and Processes Subhas K. Sikdar National Risk Management Research Laboratory United States Environmental protection Agency 26 W. M.L. King Dr. Cincinnati, OH 45237 Sikdar.subhas@epa.gov ABSTRACT Claims of both sustainable and unsu...

  19. Applied Behavior Analysis and Statistical Process Control?

    ERIC Educational Resources Information Center

    Hopkins, B. L.

    1995-01-01

    Incorporating statistical process control (SPC) methods into applied behavior analysis is discussed. It is claimed that SPC methods would likely reduce applied behavior analysts' intimate contacts with problems and would likely yield poor treatment and research decisions. Cases and data presented by Pfadt and Wheeler (1995) are cited as examples.…

  20. Petroleum engineering manpower supply

    SciTech Connect

    Dorfman, M.

    1982-09-01

    The supply of Petroleum Engineers within the U.S. has shown an exponential growth during the last decade due to increases in the price of petroleum and concommitant demand for engineers in the petroleum industry at all levels of activity. Schools currently have very large enrollments; many lack sufficient faculty and facilities to adequately handle the large loads. Recent uncertainty in long range forecasting of petroleum demand, coupled with uncertainty in the price of oil due to turmoil in the Middle East and the discovery of additional large reserves of petroleum as a result of increased drilling, has led to a decline of approximately 25% in the price of crude oil on the spot market and subsequent reductions in drilling in 1982 from a high of 4,500 rigs in the U.S. to 2528 rigs by August 31, 1982; a reduction of 44% this year. This reduction in activity will be reflected in reduced job opportunities for many new graduates in December 1982 and in 1983, and the ''pipelines'' within the schools are filled with students in expectation of good jobs in the private sector of the economy. Since Petroleum Engineering departments maintain a close tie with industry, it is essential that some balance be maintained between supply and demand, so as to try to prevent a glut of engineers descending upon the market. Steps are underway at many schools. to reduce enrollments by a variety of methods at the present time. An upturn in demand in petroleum prices may serve to mitigate the problem within the next two years, but a long-range interchange between industrial hiring forecasts and universities is essential in planning for the future.

  1. Interactive Fringe processing algorithm for interferogram analysis

    NASA Astrophysics Data System (ADS)

    Parthiban, V.; Sirohi, Rajpal S.

    A highly flexible algorithm for interferogram processing which enables the operator to interact with the computer at every stage, is presented. This algorithm developed on a PDP 11/23 microcomputer, uses Fortran callable subroutines based on Intellect 100 image processing hardware and a CUB R-G-B monitor. It also uses a single frame buffer of 512 x 512 x 8 pixels. This software employs a pseudo-colour mapping technique which helps the operator to select the optimum threshold values. Manual editing of the processed fringe pattern is also possible to enable removal of unwanted kinks and to connect any discontinuities. A fringe scanning subroutine is used to number the fringes and to store the peak coordinates in a data file for fringe analysis. The algorithm is employed for the analysis of an interferogram obtained from an inverting interferometer and the results are presented.

  2. Exergy analysis of nutrient recovery processes.

    PubMed

    Hellström, D

    2003-01-01

    In an exergy analysis, the actual consumption of resources in physical and chemical processes is calculated. Energy and chemical elements are not consumed in the processes--they are only transformed into other forms with lower quality. The principals of exergy analysis are illustrated by comparing different wastewater treatment systems for nutrient recovery. One system represents an end-of-pipe structure, whereas other systems include source separation of grey water, black water, and urine. The exergy flows analysed in this paper are those related to management and treatment of organic matter and nutrients. The study shows that the total exergy consumption is lowest for the system with source separation of urine and faeces and greatest for the conventional wastewater treatment system complemented by processes for nutrient recovery.

  3. Parallel processing in finite element structural analysis

    NASA Technical Reports Server (NTRS)

    Noor, Ahmed K.

    1987-01-01

    A brief review is made of the fundamental concepts and basic issues of parallel processing. Discussion focuses on parallel numerical algorithms, performance evaluation of machines and algorithms, and parallelism in finite element computations. A computational strategy is proposed for maximizing the degree of parallelism at different levels of the finite element analysis process including: 1) formulation level (through the use of mixed finite element models); 2) analysis level (through additive decomposition of the different arrays in the governing equations into the contributions to a symmetrized response plus correction terms); 3) numerical algorithm level (through the use of operator splitting techniques and application of iterative processes); and 4) implementation level (through the effective combination of vectorization, multitasking and microtasking, whenever available).

  4. Qualitative Analysis for Maintenance Process Assessment

    NASA Technical Reports Server (NTRS)

    Brand, Lionel; Kim, Yong-Mi; Melo, Walcelio; Seaman, Carolyn; Basili, Victor

    1996-01-01

    In order to improve software maintenance processes, we first need to be able to characterize and assess them. These tasks must be performed in depth and with objectivity since the problems are complex. One approach is to set up a measurement-based software process improvement program specifically aimed at maintenance. However, establishing a measurement program requires that one understands the problems to be addressed by the measurement program and is able to characterize the maintenance environment and processes in order to collect suitable and cost-effective data. Also, enacting such a program and getting usable data sets takes time. A short term substitute is therefore needed. We propose in this paper a characterization process aimed specifically at maintenance and based on a general qualitative analysis methodology. This process is rigorously defined in order to be repeatable and usable by people who are not acquainted with such analysis procedures. A basic feature of our approach is that actual implemented software changes are analyzed in order to understand the flaws in the maintenance process. Guidelines are provided and a case study is shown that demonstrates the usefulness of the approach.

  5. Metagenomic Approach for Understanding Microbial Population from Petroleum Muck

    PubMed Central

    Joshi, M. N.; Dhebar, S. V.; Dhebar, S. V.; Bhargava, P.; Pandit, A. S.; Patel, R. P.; Saxena, A. K.

    2014-01-01

    Petroleum products play a major role in fueling the economy of the world but the pollution they create has become a critical issue. Understanding the diversity present in pipeline muck will help with the exploration of new microbial strains with better hydrocarbon degrading capacities for bioremediation of polluted sites. This study provides an analysis of petroleum muck using next generation sequencing. PMID:24874664

  6. BIOREMEDIATION OF PETROLEUM HYDROCARBONS: A FLEXIBLE VARIABLE SPEED TECHNOLOGY

    EPA Science Inventory

    The bioremediation of petroleum hydrocarbons has evolved into a number of different processes. These processes include in-situ aquifer bioremediation, bioventing, biosparging, passive bioremediation with oxygen release compounds, and intrinsic bioremediation. Although often viewe...

  7. Petroleum fingerprinting with organic markers

    USGS Publications Warehouse

    Hostettler, Frances D.; Lorenson, T.D.; Bekins, Barbara A.

    2013-01-01

    Petroleum fingerprinting is an invaluable tool in forensic geochemistry. This article summarizes applications of fingerprinting in several oil spills and natural oil seepages that we have studied during the last 25 years. It shows how each unique chemical fingerprint can be used to correlate or differentiate oils. Fingerprints can provide information about processes in the environment that impact oils such as weathering and microbial degradation. They can be used to evaluate organic matter that contributed to oils, and classify oils with regard to the geological framework of their source, such as evaluating geological facies, age, lithology, and depositional environment.

  8. Paleogene thrust tectonics in northwestern Venezuela: Petroleum system implications

    SciTech Connect

    Quijada, E.; Oropeza, S.

    1996-08-01

    Oil exploration in northeastern Perija Mountains, northwestern Maracaibo basin, has been difficult, mainly due to the various tectonic events that have strongly deformed this area. This study is an attempt at better understanding the effect of a Paleogene thrusting event on the petroleum system development in the area. Subsidence analysis interpretation at both sides of the NNE directed Tigre fault (which separates the northern Perija Mountains from the rest of the Maracaibo basin) suggests the onset of a foreland basin during, at least, Paleocene-Early Eocene time. Continuous sedimentation occurred from Late Cretaceous to Early Eocene, as long as it kept pace with subsidence, in the west block of the fault, while the east block acted as an obstacle against the thrust-sheet movement, delaying its subsidence. Sedimentation for this time is associated with a thick unit of mainly paralic sediments west of that fault and thinner continental (fluvial) to shallow marine sediments, with an intra-Paleocene/Early Eocene unconformity, east of it. So, this tectonic event, associated with convergence from the north, caused a south-verging thrust sheet giving rise to differences in the evolution of the petroleum system on both sides of the Tigre fault, mainly regarding the existence of source rocks and their generation/migration of hydrocarbons, preservation time and critical moment. Finally, in order to evaluate the oil exploration opportunities in northeastern Perija mountains, it is advisable that any integrated interpretation of the petroleum system processes (generation-migration-accumulation) take into account this tectonic event.

  9. Analysis of rocket engine injection combustion processes

    NASA Technical Reports Server (NTRS)

    Salmon, J. W.

    1976-01-01

    A critique is given of the JANNAF sub-critical propellant injection/combustion process analysis computer models and application of the models to correlation of well documented hot fire engine data bases. These programs are the distributed energy release (DER) model for conventional liquid propellants injectors and the coaxial injection combustion model (CICM) for gaseous annulus/liquid core coaxial injectors. The critique identifies model inconsistencies while the computer analyses provide quantitative data on predictive accuracy. The program is comprised of three tasks: (1) computer program review and operations; (2) analysis and data correlations; and (3) documentation.

  10. Petroleum supply monthly, April 1998, with data for February 1998

    SciTech Connect

    1998-04-01

    The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. Data presented in the PSM describe the supply and disposition of petroleum products in the US and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the US (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the US. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics. The tables and figures in the Summary Statistics section of the PSM present a time series of selected petroleum data on a US level. Most time series include preliminary estimates for one month based on the Weekly Petroleum Supply Reporting System; statistics based on the most recent data from the Monthly Petroleum Supply Reporting System (MPSRS); and statistics published in prior issues of the PSM and PSA. The Detailed Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. In most cases, the statistics are presented for several geographic areas--the US (50 States and District of Columbia), 5 PAD Districts and 12 Refining Districts. 16 figs., 56 tabs.

  11. Petroleum supply monthly, July 1999, with data for May 1999

    SciTech Connect

    1999-07-01

    The Petroleum Supply Monthly (PSM) is one of a family of four petroleum supply publications produced by the Petroleum Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the US and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the US (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the US. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics. The Detail Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. In most cases, the statistics are presented for several geographic areas--the US (50 States and the District of Columbia), five PAD Districts, and 12 Refining Districts. At the US and PAD District level, the total volume and the daily rate of activities are presented. The statistics are developed from monthly survey forms submitted by respondents to the EIA and from data provided from other sources.

  12. Petroleum supply monthly, December 1997 with data from October 1997

    SciTech Connect

    1997-12-01

    Data presented in the Petroleum Supply Monthly (PSM) describes the supply and disposition of petroleum products in the US and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the US (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregates, the data reported by these sectors approximately represent the consumption of petroleum products in the US. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics. The tables and figures in the Summary Statistics section of the PSM present a time series of selected petroleum data on a US level. The Detailed Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. 16 figs., 66 tabs.

  13. Petroleum supply monthly, November 1998, with data for September 1998

    SciTech Connect

    1998-11-01

    Data presented in the Petroleum Supply Monthly (PSM) describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the Unites States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics. The tables and figures in the Summary Statistics section of the PSM present a time series of selected petroleum data on a US level. The Detailed Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. 72 tabs.

  14. Petroleum supply monthly, October 1998, with data for August 1998

    SciTech Connect

    1998-10-01

    Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics. The tables and figures in the Summary Statistics section of the PSM present a time series of selected petroleum data on a US level. The Detailed Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. A feature article, Accuracy of petroleum supply data, is also included. 72 tabs.

  15. Petroleum supply monthly, January 1997 with data for November 1996

    SciTech Connect

    1997-01-01

    Data presented in the Petroleum Supply Monthly describe the supply and disposition of petroleum products in the US and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the US (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the US. Data are divided into two sections: Summary Statistics and Detailed Statistics. The tables and figures in the Summary Statistics section present a time series of selected petroleum data on a US level. The Detailed Statistics tables present statistics for the most current month available as well as year-to-date. 16 figs., 66 tabs.

  16. Petroleum supply monthly, January 1999 with data for November 1998

    SciTech Connect

    1999-01-01

    Data presented in the Petroleum Supply Monthly (PSM) describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics. The tables and figures in the Summary Statistics section of the PSM present a time series of selected petroleum data on a US level. The Detailed Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. 82 tabs.

  17. Petroleum supply monthly, February 1998 with data from December 1997

    SciTech Connect

    1998-02-01

    The Petroleum Supply Monthly (PSM) describes the supply and disposition of petroleum products in the US and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the US (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the US. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics. The tables and figures in the Summary Statistics section of the PSM present a time series of selected petroleum data on a US level. The Detailed Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. 16 figs., 66 tabs.

  18. Petroleum supply monthly, May 1999, with data for March 1999

    SciTech Connect

    1999-05-01

    Data presented in the Petroleum Supply Monthly (PSM) describe the supply and disposition of petroleum products in the US and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary supplies of petroleum products in the US (50 states and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the US. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics. The tables and figures in the Summary Statistics section of the PSM present a time series of selected petroleum data on a US level. The Detailed Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. 72 tabs.

  19. Petroleum supply monthly, June 1999, with data for April 1999

    SciTech Connect

    1999-06-01

    Data presented in the Petroleum Supply Monthly (PSM) describe the supply and disposition of petroleum products in the US and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the US (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the US. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics. The tables and figures in the Summary Statistics section of the PSM present a time series of selected petroleum data on a US level. The Detailed Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. 16 figs., 66 tabs.

  20. Petroleum supply monthly, February 1999, with data for December 1998

    SciTech Connect

    1999-02-01

    Data presented in the Petroleum Supply Monthly (PSM) describes the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics. The tables and figures in the Summary Statistics section of the PSM present a time series of selected petroleum data on a US level. The Detailed Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. 16 figs., 66 tabs.

  1. Petroleum supply monthly, August 1998, with data for June 1998

    SciTech Connect

    1998-08-01

    Data presented in the Petroleum Supply Monthly (PSM) describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the US (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics. The tables and figures in the Summary Statistics section of the PSM present a time series of selected petroleum data on a US level. The Detailed Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. 16 fig., 66 tabs.

  2. Petroleum supply monthly, May 1996 with data from March 1996

    SciTech Connect

    1996-05-01

    Data presented in the Petroleum Supply Monthly (PSM) describe the supply and disposition of petroleum products in the US and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the US (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the US. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics. The tables and figures in the Summary Statistics section of the PSM present a time series of selected petroleum data on a US level. The Detailed Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. 16 figs., 66 tabs.

  3. Petroleum supply monthly: July 1998, with data for May 1998

    SciTech Connect

    1998-07-01

    Data presented in the Petroleum Supply Monthly (PSM) describes the supply and disposition of petroleum products in the US and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the US (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the US. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics. The tables and figures in the Summary Statistics section of the PSM present a time series of selected petroleum data on a US level. The Detailed Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. 16 figs., 56 tabs.

  4. Petroleum supply monthly, June 1998 with data for April 1998

    SciTech Connect

    1998-06-01

    Data presented in the Petroleum Supply Monthly (PSM) describe the supply and disposition of petroleum products in the US and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the US (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the US. The tables and figures in the Summary Statistics section of the PSM present a time series of selected petroleum data on a US level. The Detailed Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. 16 figs., 66 tabs.

  5. Petroleum supply monthly, April 1999, with data for February 1999

    SciTech Connect

    1999-04-01

    Data presented in the Petroleum Supply Monthly (PSM) describe the supply and disposition of petroleum products in the US and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the US (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the US. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics. The tables and figures in the Summary Statistics section of the PSM present a time series of selected petroleum data on a US level. The Detailed Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. 72 tabs.

  6. Petroleum supply monthly, December 1995: With data for October 1995

    SciTech Connect

    1995-12-01

    Data presented in the Petroleum Supply Monthly (PSM) describe the supply and disposition of petroleum products in the US and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the US (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the US. The tables and figures in the Summary Statistics section of the PSM present a time series of selected petroleum data on a US level. The Detailed Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. In most cases, the statistics are presented for several geographic areas--the US (50 States and the District of Columbia), five PAD Districts, and 12 Refining Districts. At the US and PAD District level, the total volume and the daily rate of activities are presented. 16 figs., 6 tabs.

  7. Petroleum supply monthly, July 1997 with data from May 1997

    SciTech Connect

    1997-07-01

    Data presented in the Petroleum Supply Monthly (PSM) describes the supply and disposition of petroleum products in the US and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the US (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the US. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics. The tables and figures in the Summary Statistics section of the PSM present a time series of selected petroleum data on a US level. The Detailed Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. 16 figs., 66 tabs.

  8. Sulphur-radical control on petroleum formation rates

    USGS Publications Warehouse

    Lewan, M.D.

    1998-01-01

    Most petroleum is formed through the partial decomposition of kerogen (an insoluble sedimentary organic material) in response to thermal stress during subsurface burial in a sedimentary basin. Knowing the mechanisms and kinetics of this process allows the determination of the extent and timing of petroleum formation, which, in turn, are critical for evaluating the potential for petroleum occurrences within a sedimentary basin. Kinetic models of petroleum generation are derived mainly from pyrolysis experiments, in which it is usually assumed that formation rates are controlled by the strength of the bonds within the precursor compounds: this agrees with the observation that petroleum formation rates increase with increasing sulphur content of thermally immature kerogen, C-S bonds being weaker than C-C bonds. However, this explanation fails to account for the overall composition of petroleum. Here I argue, on the basis of pyrolysis experiments, that it is the presence of sulphur radicals, rather than the relative weakness of C-S bonds, that controls petroleum formation rates. My findings suggest that the rate of petroleum formation depends critically on the concentration of sulphur radicals generated during the initial stages of thermal maturation. The proposed mechanism appears to provide a realistic explanation for both the overall composition of petroleum and the observed variation in formation rates.

  9. A pathway analysis of global aerosol processes

    NASA Astrophysics Data System (ADS)

    Schutgens, N. A. J.; Stier, P.

    2014-06-01

    We present a detailed budget of the changes in atmospheric aerosol mass and numbers due to various processes: emission, nucleation, coagulation, H2SO4 condensation and in-cloud production, ageing and deposition. The budget is created from monthly-averaged tracer tendencies calculated by the global aerosol model ECHAM5.5-HAM2 and allows us to investigate process contributions at various length- and time-scales. As a result, we show in unprecedented detail what processes drive the evolution of aerosol. In particular, we show that the processes that affect aerosol masses are quite different from those affecting aerosol numbers. Condensation of H2SO4 gas onto pre-existing particles is an important process, dominating the growth of small particles in the nucleation mode to the Aitken mode and the ageing of hydrophobic matter. Together with in-cloud production of H2SO4, it significantly contributes to (and often dominates) the mass burden (and hence composition) of the hydrophilic Aitken and accumulation mode particles. Particle growth itself is the leading source of number densities in the hydrophilic Aitken and accumulation modes, with their hydrophobic counterparts contributing (even locally) relatively little. As expected, the coarse mode is dominated by primary emissions and mostly decoupled from the smaller modes. Our analysis also suggests that coagulation serves mainly as a loss process for number densities and that, relative to other processes, it is a rather unimportant contributor to composition changes of aerosol. The analysis is extended with sensitivity studies where the impact of a lower model resolution or pre-industrial emissions is shown to be small. We discuss the use of the current budget for model simplification, prioritisation of model improvements, identification of potential structural model errors and model evaluation against observations.

  10. A pathway analysis of global aerosol processes

    NASA Astrophysics Data System (ADS)

    Schutgens, N. A. J.; Stier, P.

    2014-11-01

    We present a detailed budget of the changes in atmospheric aerosol mass and numbers due to various processes: emission (including instant condensation of soluble biogenic emissions), nucleation, coagulation, H2SO4 condensation and in-cloud production, aging and deposition. The budget is created from monthly averaged tracer tendencies calculated by the global aerosol model ECHAM5.5-HAM2 and allows us to investigate process contributions at various length-scales and timescales. As a result, we show in unprecedented detail what processes drive the evolution of aerosol. In particular, we show that the processes that affect aerosol masses are quite different from those that affect aerosol numbers. Condensation of H2SO4 gas onto pre-existing particles is an important process, dominating the growth of small particles in the nucleation mode to the Aitken mode and the aging of hydrophobic matter. Together with in-cloud production of H2SO4, it significantly contributes to (and often dominates) the mass burden (and hence composition) of the hydrophilic Aitken and accumulation mode particles. Particle growth itself is the leading source of number densities in the hydrophilic Aitken and accumulation modes, with their hydrophobic counterparts contributing (even locally) relatively little. As expected, the coarse mode is dominated by primary emissions and mostly decoupled from the smaller modes. Our analysis also suggests that coagulation serves mainly as a loss process for number densities and that, relative to other processes, it is a rather unimportant contributor to composition changes of aerosol. The analysis is extended with sensitivity studies where the impact of a lower model resolution or pre-industrial emissions is shown to be small. We discuss the use of the current budget for model simplification, prioritization of model improvements, identification of potential structural model errors and model evaluation against observations.

  11. Digital interactive image analysis by array processing

    NASA Technical Reports Server (NTRS)

    Sabels, B. E.; Jennings, J. D.

    1973-01-01

    An attempt is made to draw a parallel between the existing geophysical data processing service industries and the emerging earth resources data support requirements. The relationship of seismic data analysis to ERTS data analysis is natural because in either case data is digitally recorded in the same format, resulting from remotely sensed energy which has been reflected, attenuated, shifted and degraded on its path from the source to the receiver. In the seismic case the energy is acoustic, ranging in frequencies from 10 to 75 cps, for which the lithosphere appears semi-transparent. In earth survey remote sensing through the atmosphere, visible and infrared frequency bands are being used. Yet the hardware and software required to process the magnetically recorded data from the two realms of inquiry are identical and similar, respectively. The resulting data products are similar.

  12. Petroleum marketing annual, 1992

    SciTech Connect

    Not Available

    1993-07-01

    This publication contains statistical data on a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the free-on-board (f.o.b.) and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented.

  13. Petroleum Marketing Annual, 1989

    SciTech Connect

    Not Available

    1990-12-18

    This report contains statistical data on a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for us by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the free-on-board (f.o.b.) and landed cost of imported crude oil, and the refiners' acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented. 13 figs., 51 tabs.

  14. Petroleum marketing monthly, June 1994

    SciTech Connect

    Not Available

    1994-06-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oil and sales of petroleum products are presented in five sections: Summary Statistics; Crude Oil Prices; Prices of Petroleum Products; Volumes of Petroleum Products; and Prime Supplier Sales Volumes of Petroleum Products for Local Consumption. The feature article is entitled ``The Second Oxygenated Gasoline Season.`` 7 figs., 50 tabs.

  15. Big Data Analysis of Manufacturing Processes

    NASA Astrophysics Data System (ADS)

    Windmann, Stefan; Maier, Alexander; Niggemann, Oliver; Frey, Christian; Bernardi, Ansgar; Gu, Ying; Pfrommer, Holger; Steckel, Thilo; Krüger, Michael; Kraus, Robert

    2015-11-01

    The high complexity of manufacturing processes and the continuously growing amount of data lead to excessive demands on the users with respect to process monitoring, data analysis and fault detection. For these reasons, problems and faults are often detected too late, maintenance intervals are chosen too short and optimization potential for higher output and increased energy efficiency is not sufficiently used. A possibility to cope with these challenges is the development of self-learning assistance systems, which identify relevant relationships by observation of complex manufacturing processes so that failures, anomalies and need for optimization are automatically detected. The assistance system developed in the present work accomplishes data acquisition, process monitoring and anomaly detection in industrial and agricultural processes. The assistance system is evaluated in three application cases: Large distillation columns, agricultural harvesting processes and large-scale sorting plants. In this paper, the developed infrastructures for data acquisition in these application cases are described as well as the developed algorithms and initial evaluation results.

  16. Chemical Principles Revisited: Petroleum Chemistry.

    ERIC Educational Resources Information Center

    Kolb, Doris; Kolb, Kenneth E.

    1979-01-01

    Presents an historical review of the role of petroleum in world history and information on the chemistry of petroleum. It is suggested that petroleum chemistry be discussed since within the next two decades oil and gas will provide the major portion of U.S. energy. (Author/SA)

  17. Determination of octane numbers and Reid vapor pressure of commercial petroleum fuels using FT-Raman spectroscopy and partial least-squares regression analysis

    SciTech Connect

    Cooper, J.B.; Wise, K.L.; Groves, J.; Welch, W.T.

    1995-11-15

    A Fourier transform Raman spectrometer was used to collect the Raman spectra of 208 commercial petroleum fuels. The individual motor and research octane numbers (MON and RON, respectively) were determined experimentally using the industry standard ASTM knock engine method. Partial least-squares regression analysis was used to build regression models which correlate the Raman spectra of 175 of the fuels with the experimentally determined values for MON, RON, and pump octane number (the average of MON and RON) of the fuels. Each of the models was validated using leave-one-out validation. The standard errors of validation are 0.415, 0.535, and 0.410 octane units for MON, RON, and pump octane number, respectively. It is evident that the accuracy of the Raman determined values is limited by the accuracy of the training set used in creating the models. The Raman regression models were used to predict the octane numbers for the fuels which were not used to build the models. The results compare favorably with the leave-one-out validation. Also, it is demonstrated that the experimentally determined Reid vapor pressures are highly correlated with the Raman spectra of the fuel samples and can be predicted with a standard error of 0.568 psi. 11 refs., 6 figs., 2 tabs.

  18. An evaluation of the environmental implications of petroleum refinery emissions by multielemental neutron activation analysis of rumen fluid ash of buffaloes.

    PubMed

    Garg, A N; Chutke, N L; Ambulkar, M N; Dogra, R K

    1996-01-01

    In order to study environmental pollution in and around a petroleum refinery complex, a multielemental instrumental neutron activation analysis (INAA) method was used to assay concentrations of As, Ba, Br, Cl, Co, Cr, Cs, Cu, Fe, Hg, La, Mn, Mo, K, Na, P, Sc, Rb, Se, Sr, W and Zn in the rumen fluid ash samples of buffaloes from the vicinity of the refinery. Corresponding samples from a control area 300 km away from the refinery were analysed. Standard Reference Materials, Bovine liver (SRM 1577a), Oyster tissue (SRM 1566a) and Animal bone (CRM H-5) were also analysed for quality control. Samples were irradiated with thermal neutrons at 10(12)-10(13) n cm-2 s-1 and counted by high-resolution gamma spectrometry. Mean elemental concentrations of As, Ba, Br, Cr, Hg and Fe were found to be enhanced, whereas those of Na, K, Cl, Cu, Mn and P were depleted in samples from the vicinity of the refinery complex compared to controls. The environmental implications of anomalous elemental concentrations are discussed.

  19. Source identification of petroleum hydrocarbons in soil and sediments from Iguaçu River Watershed, Paraná, Brazil using the CHEMSIC method (CHEMometric analysis of Selected Ion Chromatograms).

    PubMed

    Gallotta, Fabiana D C; Christensen, Jan H

    2012-04-27

    A chemometric method based on principal component analysis (PCA) of pre-processed and combined sections of selected ion chromatograms (SICs) is used to characterise the hydrocarbon profiles in soil and sediment from Araucária, Guajuvira, General Lúcio and Balsa Nova Municipalities (Iguaçu River Watershed, Paraná, Brazil) and to indicate the main sources of hydrocarbon pollution. The study includes 38 SICs of polycyclic aromatic compounds (PACs) and four of petroleum biomarkers in two separate analyses. The most contaminated samples are inside the Presidente Getúlio Vargas Refinery area. These samples represent a petrogenic pattern and different weathering degrees. Samples from outside the refinery area are either less or not contaminated, or contain mixtures of diagenetic, pyrogenic and petrogenic inputs where different proportions predominate. The locations farthest away from industrial activity (Balsa Nova) contains the lowest levels of PAC contamination. There are no evidences to conclude positive matches between the samples from outside the refinery area and the Cusiana spilled oil.

  20. Strategic petroleum reserve data acquisition system

    SciTech Connect

    Merillat, P D; Bauer, A G

    1980-10-01

    The Strategic Petroleum Reserve Data Acquisition System is a general purpose, digital data acquisition system designed for field use in the DOE's Strategic Petroleum Reserve testing and monitoring program. The system is computer driven, under the control of an operator. The system is designed to allow the operator to perform pre-test system configuration; test monitoring and control; and post test analysis. This document is a system description and an operator users manual. Topics covered include: configuration and running on-line tests, software documentation, and maintenance programming information.

  1. Economics and regulation of petroleum futures markets

    SciTech Connect

    Not Available

    1980-08-01

    Because the futures market in petroleum products is a relatively recent phenomenon, the implications of public policies formulated for that market have not yet been fully explored. To provide the Office of Competition of the Department of Energy (DOE) with sufficient information to assess policy alternatives, Resource Planning Associates, Inc. (RPA) was asked to analyze the development of the futures market in No. 2 oil, assess the potential for futures markets in other petroleum products, and identify policy alternatives available to DOE. To perform this analysis, the criteria for a viable futures market was established first. Then, the experience to date with the 18-month-old futures market in No. 2 oil was examined, and the potential for viable futures markets in No. 6 oil, gasoline, jet fuel, and crude oil was assessed. Finally, how existing DOE regulations and prospective actions might affect petroleum futures market development was investigated.

  2. Petroleum Vapor - Field Technical

    EPA Science Inventory

    The screening approach being developed by EPA OUST to evaluate petroleum vapor intrusion (PVI) requires information that has not be routinely collected in the past at vapor intrusion sites. What is the best way to collect this data? What are the relevant data quality issues and ...

  3. Automated analysis for lifecycle assembly processes

    SciTech Connect

    Calton, T.L.; Brown, R.G.; Peters, R.R.

    1998-05-01

    Many manufacturing companies today expend more effort on upgrade and disposal projects than on clean-slate design, and this trend is expected to become more prevalent in coming years. However, commercial CAD tools are better suited to initial product design than to the product`s full life cycle. Computer-aided analysis, optimization, and visualization of life cycle assembly processes based on the product CAD data can help ensure accuracy and reduce effort expended in planning these processes for existing products, as well as provide design-for-lifecycle analysis for new designs. To be effective, computer aided assembly planning systems must allow users to express the plan selection criteria that apply to their companies and products as well as to the life cycles of their products. Designing products for easy assembly and disassembly during its entire life cycle for purposes including service, field repair, upgrade, and disposal is a process that involves many disciplines. In addition, finding the best solution often involves considering the design as a whole and by considering its intended life cycle. Different goals and constraints (compared to initial assembly) require one to re-visit the significant fundamental assumptions and methods that underlie current assembly planning techniques. Previous work in this area has been limited to either academic studies of issues in assembly planning or applied studies of life cycle assembly processes, which give no attention to automatic planning. It is believed that merging these two areas will result in a much greater ability to design for; optimize, and analyze life cycle assembly processes.

  4. A pathway analysis of global aerosol processes

    NASA Astrophysics Data System (ADS)

    Schutgens, Nick; Stier, Philip

    2014-05-01

    smaller modes. Our analysis also suggests that coagulation serves mainly as a loss process for number densities and that it is a relatively unimportant contributor to composition changes of aerosol. Our results provide an objective way of complexity analysis in a global aerosol model and will be used in future work where we will reduce this complexity in ECHAM-HAM.

  5. Cleaning up soils contaminated with petroleum hydrocarbons

    SciTech Connect

    Arniella, E.F. ); Holley, R.E. )

    1991-08-01

    This article describes one new technology used to clean up soils contaminated with petroleum hydrocarbons from underground storage tanks. Topics covered include cleanup criteria, soil remediation technologies, air stripping-soil venting system and process design and performance. This contaminated site was located in the Atlanta, Georgia metropolitan area.

  6. Eco-Efficiency Analysis of biotechnological processes.

    PubMed

    Saling, Peter

    2005-07-01

    Eco-Efficiency has been variously defined and analytically implemented by several workers. In most cases, Eco-Efficiency is taken to mean the ecological optimization of overall systems while not disregarding economic factors. Eco-Efficiency should increase the positive ecological performance of a commercial company in relation to economic value creation--or to reduce negative effects. Several companies use Eco-Efficiency Analysis for decision-making processes; and industrial examples of best practices in developing and implementing Eco-Efficiency have been reviewed. They clearly demonstrate the environmental and business benefits of Eco-Efficiency. An instrument for the early recognition and systematic detection of economic and environmental opportunities and risks for production processes in the chemical industry began use in 1997, since when different new features have been developed, leading to many examples. This powerful Eco-Efficiency Analysis allows a feasibility evaluation of existing and future business activities and is applied by BASF. In many cases, decision-makers are able to choose among alternative processes for making a product.

  7. Bone feature analysis using image processing techniques.

    PubMed

    Liu, Z Q; Austin, T; Thomas, C D; Clement, J G

    1996-01-01

    In order to establish the correlation between bone structure and age, and information about age-related bone changes, it is necessary to study microstructural features of human bone. Traditionally, in bone biology and forensic science, the analysis if bone cross-sections has been carried out manually. Such a process is known to be slow, inefficient and prone to human error. Consequently, the results obtained so far have been unreliable. In this paper we present a new approach to quantitative analysis of cross-sections of human bones using digital image processing techniques. We demonstrate that such a system is able to extract various bone features consistently and is capable of providing more reliable data and statistics for bones. Consequently, we will be able to correlate features of bone microstructure with age and possibly also with age related bone diseases such as osteoporosis. The development of knowledge-based computer vision-systems for automated bone image analysis can now be considered feasible.

  8. Preliminary Hazards Analysis Plasma Hearth Process

    SciTech Connect

    Aycock, M.; Coordes, D.; Russell, J.; TenBrook, W.; Yimbo, P.

    1993-11-01

    This Preliminary Hazards Analysis (PHA) for the Plasma Hearth Process (PHP) follows the requirements of United States Department of Energy (DOE) Order 5480.23 (DOE, 1992a), DOE Order 5480.21 (DOE, 1991d), DOE Order 5480.22 (DOE, 1992c), DOE Order 5481.1B (DOE, 1986), and the guidance provided in DOE Standards DOE-STD-1027-92 (DOE, 1992b). Consideration is given to ft proposed regulations published as 10 CFR 830 (DOE, 1993) and DOE Safety Guide SG 830.110 (DOE, 1992b). The purpose of performing a PRA is to establish an initial hazard categorization for a DOE nuclear facility and to identify those processes and structures which may have an impact on or be important to safety. The PHA is typically performed during and provides input to project conceptual design. The PRA then is followed by a Preliminary Safety Analysis Report (PSAR) performed during Title I and II design. This PSAR then leads to performance of the Final Safety Analysis Report performed during construction, testing, and acceptance and completed before routine operation. Radiological assessments indicate that a PHP facility, depending on the radioactive material inventory, may be an exempt, Category 3, or Category 2 facility. The calculated impacts would result in no significant impact to offsite personnel or the environment. Hazardous material assessments indicate that a PHP facility will be a Low Hazard facility having no significant impacts either onsite or offsite to personnel and the environment.

  9. Interactive chemistry of coal-petroleum processing: Quarterly progress report for March 15, 1987-June 15, 1987. [Effect of coal or resid on reaction

    SciTech Connect

    Curtis, C.W.; Guin, J.A.; Tarrer, A.R.

    1987-01-01

    The thermal reactions of model compounds NAPH, DMC, PN, BZT, and QN with Maya TLR (topped long resid) showed no reactions. The presence of Maya TLR blocked the intermediate hydrogenation pathway from QN to THQ compared to the reaction without Maya TLR where 13% THQ was formed. Maya TLR served as a strong inhibitor in the catalytic hydrogenations of model compounds, being more detrimental to the hydrogenation and heteroatom removal reactions than coal. The severe inhibition of Maya TLR is caused by the chemical composition of the resid. The resid contains large refractory hydrocarbon species and substantial amounts of metals. Maya TLR was most likely deactivating the NiMo/Al/sub 2/O/sub 3/ catalyst as well as possibly interacting with model species present. Catalyst deactivation due to pore-plugging by petroleum crude and residua reaction products from hydrotreating, i.e., metal sulfides and coke has been studied by Newson. In crude oils and residua, vanadium and nickel compounds are the most abundant organometallic constituents and cause major problems in hydrotreating of residuum oils. At hydroprocessing conditions, these metal compounds deposit on and deactivate the catalyst. Pore mouth plugging in the catalyst by the metal deposit has been known as the major cause in the catalyst deactivation. Tamm and co-workers studied two mechanisms of catalyst deactivation by petroleum feed metals: (1) poisoning of the active surface and (2) physical obstruction of the pore structure. Thus, two possible reasons for the severe deactivation observed in the Maya TLR are metal deposition and carbon laydown on the catalyst surface. Another reason why the Maya TLR had a stronger inhibiting effect than coal is that these reactions are at 350/sup 0/C, where the coal was only partially dissolved; therefore, all the bad actors from coal were not available in the system, while those from the resid were. 3 refs., 4 figs., 36 tabs.

  10. Preparation, characterization and photocatalytic application of TiO2/Fe-ZSM-5 nanocomposite for the treatment of petroleum refinery wastewater: Optimization of process parameters by response surface methodology.

    PubMed

    Ghasemi, Zahra; Younesi, Habibollah; Zinatizadeh, Ali Akbar

    2016-09-01

    Photocatalytic degradation of organic contaminants from petroleum refinery wastewater under UV and sunlight was investigated by immobilizing nanosized TiO2 photocatalyst into the structure of as-synthesized Fe-ZSM-5 zeolite via sol-gel method. Pure phase of TiO2/Fe-ZSM-5 photocatalyst with specific surface area of 304.6 m(2) g(-1) and loaded TiO2 of 29.28% was successfully synthesized. Effects of various operational parameters on treatment process were investigated by use of Response Surface Methodology (RSM). Maximum reduction of 80% COD was achieved at pH of 4, a photocatalyst concentration of 2.1 g l(-1), temperature of 45 °C and UV exposure time of 240 min. Gas chromatography-mass demonstrated an apparent shift in molecular weight from a higher fraction to a lower fraction even under sunlight. It is expected that the prepared photocatalyst is able to use ultraviolet and visible light energy. Results indicated that removal of COD degradation did not decrease as the reuse cycle of photocatalyst increased. Moreover, the potential to use sunlight energy and the simplicity of operation make photocatalysis an attractive prospect in terms of petroleum refinery wastewater treatment. PMID:27341159

  11. Preparation, characterization and photocatalytic application of TiO2/Fe-ZSM-5 nanocomposite for the treatment of petroleum refinery wastewater: Optimization of process parameters by response surface methodology.

    PubMed

    Ghasemi, Zahra; Younesi, Habibollah; Zinatizadeh, Ali Akbar

    2016-09-01

    Photocatalytic degradation of organic contaminants from petroleum refinery wastewater under UV and sunlight was investigated by immobilizing nanosized TiO2 photocatalyst into the structure of as-synthesized Fe-ZSM-5 zeolite via sol-gel method. Pure phase of TiO2/Fe-ZSM-5 photocatalyst with specific surface area of 304.6 m(2) g(-1) and loaded TiO2 of 29.28% was successfully synthesized. Effects of various operational parameters on treatment process were investigated by use of Response Surface Methodology (RSM). Maximum reduction of 80% COD was achieved at pH of 4, a photocatalyst concentration of 2.1 g l(-1), temperature of 45 °C and UV exposure time of 240 min. Gas chromatography-mass demonstrated an apparent shift in molecular weight from a higher fraction to a lower fraction even under sunlight. It is expected that the prepared photocatalyst is able to use ultraviolet and visible light energy. Results indicated that removal of COD degradation did not decrease as the reuse cycle of photocatalyst increased. Moreover, the potential to use sunlight energy and the simplicity of operation make photocatalysis an attractive prospect in terms of petroleum refinery wastewater treatment.

  12. POST-PROCESSING ANALYSIS FOR THC SEEPAGE

    SciTech Connect

    Y. SUN

    2004-09-29

    This report describes the selection of water compositions for the total system performance assessment (TSPA) model of results from the thermal-hydrological-chemical (THC) seepage model documented in ''Drift-Scale THC Seepage Model'' (BSC 2004 [DIRS 169856]). The selection has been conducted in accordance with ''Technical Work Plan for: Near-Field Environment and Transport: Coupled Processes (Mountain-Scale TH/THC/THM, Drift-Scale THC Seepage, and Post-Processing Analysis for THC Seepage) Report Integration'' (BSC 2004 [DIRS 171334]). This technical work plan (TWP) was prepared in accordance with AP-2.27Q, ''Planning for Science Activities''. Section 1.2.3 of the TWP describes planning information pertaining to the technical scope, content, and management of this report. The post-processing analysis for THC seepage (THC-PPA) documented in this report provides a methodology for evaluating the near-field compositions of water and gas around a typical waste emplacement drift as these relate to the chemistry of seepage, if any, into the drift. The THC-PPA inherits the conceptual basis of the THC seepage model, but is an independently developed process. The relationship between the post-processing analysis and other closely related models, together with their main functions in providing seepage chemistry information for the Total System Performance Assessment for the License Application (TSPA-LA), are illustrated in Figure 1-1. The THC-PPA provides a data selection concept and direct input to the physical and chemical environment (P&CE) report that supports the TSPA model. The purpose of the THC-PPA is further discussed in Section 1.2. The data selection methodology of the post-processing analysis (Section 6.2.1) was initially applied to results of the THC seepage model as presented in ''Drift-Scale THC Seepage Model'' (BSC 2004 [DIRS 169856]). Other outputs from the THC seepage model (DTN: LB0302DSCPTHCS.002 [DIRS 161976]) used in the P&CE (BSC 2004 [DIRS 169860

  13. Mathematical Analysis and Optimization of Infiltration Processes

    NASA Technical Reports Server (NTRS)

    Chang, H.-C.; Gottlieb, D.; Marion, M.; Sheldon, B. W.

    1997-01-01

    A variety of infiltration techniques can be used to fabricate solid materials, particularly composites. In general these processes can be described with at least one time dependent partial differential equation describing the evolution of the solid phase, coupled to one or more partial differential equations describing mass transport through a porous structure. This paper presents a detailed mathematical analysis of a relatively simple set of equations which is used to describe chemical vapor infiltration. The results demonstrate that the process is controlled by only two parameters, alpha and beta. The optimization problem associated with minimizing the infiltration time is also considered. Allowing alpha and beta to vary with time leads to significant reductions in the infiltration time, compared with the conventional case where alpha and beta are treated as constants.

  14. Applied behavior analysis and statistical process control?

    PubMed Central

    Hopkins, B L

    1995-01-01

    This paper examines Pfadt and Wheeler's (1995) suggestions that the methods of statistical process control (SPC) be incorporated into applied behavior analysis. The research strategies of SPC are examined and compared to those of applied behavior analysis. I argue that the statistical methods that are a part of SPC would likely reduce applied behavior analysts' intimate contacts with the problems with which they deal and would, therefore, likely yield poor treatment and research decisions. Examples of these kinds of results and decisions are drawn from the cases and data Pfadt and Wheeler present. This paper also describes and clarifies many common misconceptions about SPC, including W. Edwards Deming's involvement in its development, its relationship to total quality management, and its confusion with various other methods designed to detect sources of unwanted variability. PMID:7592156

  15. Polycyclic aromatic hydrocarbons and petroleum biomarkers in São Sebastião Channel, Brazil: assessment of petroleum contamination.

    PubMed

    da Silva, Denis A M; Bícego, Márcia C

    2010-06-01

    Polycyclic aromatic hydrocarbons (PAHs) and non-aromatic hydrocarbons (NAHs), including n-alkanes, isoprenoids and petroleum biomarkers (terpanes, hopanes, steranes and diasteranes), were quantified by gas chromatography with flame ionization and mass spectrometer detectors in sediment samples collected from the São Sebastião Channel (SSC), Brazil, where the largest Brazilian maritime petroleum terminal is located. The concentrations of total PAHs, total n-alkanes and petroleum biomarkers ranged from below the detection limits to 370ngg(-1), 28microgg(-1), 2200ngg(-1) (dry weight), respectively. The analysis of PAH distribution suggested combustion sources of PAHs as the main input for these compounds with smaller amount from petroleum contamination. The distribution of petroleum biomarkers undoubtedly demonstrated petroleum as a source of anthropogenic contamination throughout the region. The assessment of petrogenic sources of contamination in marine sediment is more challenging if only PAH analysis were carried out, which demonstrates that more stable hydrocarbons such as petroleum biomarkers are useful for investigating potential presence of petroleum.

  16. Strategic Petroleum Reserve quarterly report

    SciTech Connect

    1995-11-15

    The Strategic Petroleum Reserve was created pursuant to the Energy Policy and Conservation Act of December 22, 1975 (Public Law 94-163). Its purposes are to reduce the impact of disruptions in supplies of petroleum products and to carry out obligations of the United States under the Agreement on an International Energy Program. Section 165(a) of the Act requires the submission of Annual Reports and Section 165(b)(1) requires the submission of Quarterly Reports. This Quarterly Report highlights activities undertaken during the third quarter of calendar year 1995, including: inventory of petroleum products stored in the Reserve; current storage capacity and ullage available; current status of the Strategic Petroleum Reserve storage facilities, major projects and the acquisition of petroleum products; funds obligated by the Secretary from the SPR Petroleum Account and the Strategic Petroleum Reserve Account during the prior calendar quarter and in total; and major environmental actions completed, in progress, or anticipated.

  17. HYBRID SULFUR PROCESS REFERENCE DESIGN AND COST ANALYSIS

    SciTech Connect

    Gorensek, M.; Summers, W.; Boltrunis, C.; Lahoda, E.; Allen, D.; Greyvenstein, R.

    2009-05-12

    This report documents a detailed study to determine the expected efficiency and product costs for producing hydrogen via water-splitting using energy from an advanced nuclear reactor. It was determined that the overall efficiency from nuclear heat to hydrogen is high, and the cost of hydrogen is competitive under a high energy cost scenario. It would require over 40% more nuclear energy to generate an equivalent amount of hydrogen using conventional water-cooled nuclear reactors combined with water electrolysis compared to the proposed plant design described herein. There is a great deal of interest worldwide in reducing dependence on fossil fuels, while also minimizing the impact of the energy sector on global climate change. One potential opportunity to contribute to this effort is to replace the use of fossil fuels for hydrogen production by the use of water-splitting powered by nuclear energy. Hydrogen production is required for fertilizer (e.g. ammonia) production, oil refining, synfuels production, and other important industrial applications. It is typically produced by reacting natural gas, naphtha or coal with steam, which consumes significant amounts of energy and produces carbon dioxide as a byproduct. In the future, hydrogen could also be used as a transportation fuel, replacing petroleum. New processes are being developed that would permit hydrogen to be produced from water using only heat or a combination of heat and electricity produced by advanced, high temperature nuclear reactors. The U.S. Department of Energy (DOE) is developing these processes under a program known as the Nuclear Hydrogen Initiative (NHI). The Republic of South Africa (RSA) also is interested in developing advanced high temperature nuclear reactors and related chemical processes that could produce hydrogen fuel via water-splitting. This report focuses on the analysis of a nuclear hydrogen production system that combines the Pebble Bed Modular Reactor (PBMR), under development by

  18. Auxetic polyurethane foam: Manufacturing and processing analysis

    NASA Astrophysics Data System (ADS)

    Jahan, Md Deloyer

    experimental design approach to identify significant processing parameters followed by optimization of those processing parameters in fabrication of auxetic PU foam. A split-plot factorial design has been selected for screening purpose. Response Surface Methodology (RSM) has been utilized to optimize the processing parameters in fabrication of auxetic PU foam. Two different designs named Box-Behnken and I-optimal designs have been employed for this analysis. The results obtained by those designs exhibit that I-optimal design provides more accurate and realistic results than Box-Behnken design when experiments are performed in split-plot manner. Finally, a near stationary ridge system is obtained by optimization analysis. As a result a set of operating conditions are obtained that produces similar minimum Poisson's ratio in auxetic PU foam.

  19. Stability analysis of a polymer coating process

    NASA Astrophysics Data System (ADS)

    Kallel, A.; Hachem, E.; Demay, Y.; Agassant, J. F.

    2015-05-01

    A new coating process involving a short stretching distance (1 mm) and a high draw ratio (around 200) is considered. The resulting thin molten polymer film (around 10 micrometers) is set down on a solid primary film and then covered by another solid secondary film. In experimental studies, periodical fluctuation in the thickness of the coated layer may be observed. The processing conditions markedly influence the onset and the development of these defects and modeling will help our understanding of their origins. The membrane approach which has been commonly used for cast film modeling is no longer valid and two dimensional time dependent models (within the thickness) are developed in the whole domain (upstream die and stretching path). A boundary-value problem with a free surface for the Stokes equations is considered and stability of the free surface is assessed using two different numerical strategies: a tracking strategy combined with linear stability analysis involving computation of leading eigenvalues, and a Level Set capturing strategy coupled with transient stability analysis.

  20. Petroleum supply monthly: April 1996, with data from February 1996

    SciTech Connect

    1996-04-01

    Data presented in this report describe the supply and disposition of petroleum products in the US and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the US (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the US. The tables and figures in the Summary Statistics section of the report present a time series of selected petroleum data on a US level. The Detailed Statistics tables present statistics for the most current month available as well as year-to-date. In most cases, the statistics are presented for several geographic areas--the US (50 States and the District of Columbia), five PAD districts, and 12 Refining Districts. A future article gives a summer 1996 gasoline assessment. 16 figs., 66 tabs.

  1. Petroleum supply monthly, February 1995, with data for December 1994

    SciTech Connect

    1995-02-27

    Data presented in the Petroleum Supply Monthly (PSM) describe the supply and disposition of petroleum products in the US and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the US (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics. The tables and figures in the Summary Statistics section of the PSM present a time series of selected petroleum data on a US level. The detailed Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. In most cases, the statistics are presented for several geographic areas--the US (50 States and the District of Columbia), five PAD Districts, and 12 Refining Districts. 16 figs., 66 tabs.

  2. Investigating bioremediation of petroleum hydrocarbons through landfarming using apparent electrical conductivity measurements

    NASA Astrophysics Data System (ADS)

    Van De Vijver, Ellen; Van Meirvenne, Marc; Seuntjens, Piet

    2015-04-01

    Bioremediation of soil contaminated with petroleum hydrocarbons through landfarming has been widely applied commercially at large scale. Biodegradation is one of the dominant pollutant removal mechanisms involved in landfarming, but strongly depends on the environmental conditions (e.g. presence of oxygen, moisture content). Conventionally the biodegradation process is monitored by the installation of field monitoring equipment and repeated sample collection and analysis. Because the presence of petroleum hydrocarbons and their degradation products can affect the electrical properties of the soil, proximal soil sensors such as electromagnetic induction (EMI) sensors may provide an alternative to investigate the biodegradation process of these contaminants. We investigated the relation between the EMI-based apparent electrical conductivity (ECa) of a landfarm soil and the presence and degradation status of petroleum hydrocarbons. The 3 ha study area was located in an oil refinery complex contaminated with petroleum hydrocarbons, mainly composed of diesel. At the site, a landfarm was constructed in 1999. The most recent survey of the petroleum hydrocarbon concentrations was conducted between 2011 and 2013. The sampling locations were defined by a grid with a 10 m by 10 m cell size and on each location a sample was taken from four successive soil layers with a thickness of 0.5 m each. Because the survey was carried out in phases using different georeferencing methods, the final dataset suffered from uncertainty in the coordinates of the sampling locations. In September 2013 the landfarm was surveyed for ECa with a multi-receiver electromagnetic induction sensor (DUALEM-21S) using motorized conveyance. The horizontal measurement resolution was 1 m by 0.25 m. On each measurement location the sensor recorded four ECa values representative of measurement depths of 0.5 m, 1.0 m, 1.6 m and 3.2 m. After the basic processing, the ECa measurements were filtered to remove

  3. THE SOLAR TRANSFORMITY OF OIL AND PETROLEUM NATURAL GAS

    EPA Science Inventory

    This paper presents an emergy evaluation of the biogeochemical process of petroleum formation. Unlike the previous calculation, in which the transformity of crude oil was back calculated from the relative efficiency of electricity production and factors relating coal to transport...

  4. /sup 13/C NMR spectroscopy in the analysis of conjugate metabolites in the bile of fish exposed to petroleum

    SciTech Connect

    Hellou, J.; Banoub, J.H.; Payne, J.F.

    1986-01-01

    The first natural abundance /sup 13/C NMR investigation of a complex mixture of conjugate metabolites obtained from the gall bladder bile of fish exposed to hydrocarbons is presented. Cunners were exposed to water accommodated No. 2 fuel oil containing about 68% saturates and 22% aromatics. Spectral analysis indicated that the hydrocarbon derivatives were present predominantly as ..beta..-glucuronides, with the oxygen at carbon-1 of glucuronic acid preferentially attached to an aliphatic carbon. The conjugate metabolites were enriched in aromatic-type carbons when compared to the fuel oil or the aromatic fraction of oil.

  5. Sedimentology and petroleum geology

    SciTech Connect

    Bjorlykke, K.

    1989-01-01

    In this introduction to sedimentology and petroleum geology the subjects, which are closely related but mostly treated separately, are integrated. The first part covers the basic aspects of sedimentology, sedimentary geochemistry and diagenesis, including brief discussions of flow in rivers and channels, types of sediment transport, lake and river deposits, deltas (river-dominated, tide-dominated, and wave-dominated) and the water budget. Principles of stratigraphy, seismic stratigraphy and basin modeling form the basis for the last part on petroleum geology. Here subjects include the composition of kerogen and hydrocarbons, theories of migration and trapping of hydrocarbons and properties of reservoir rocks. Finally, short introductions to well logging and production geology are given.

  6. Petroleum Market Model of the National Energy Modeling System

    SciTech Connect

    1997-01-01

    The purpose of this report is to define the objectives of the Petroleum Market Model (PMM), describe its basic approach, and provide detail on how it works. This report is intended as a reference document for model analysts, users, and the public. The PMM models petroleum refining activities, the marketing of petroleum products to consumption regions. The production of natural gas liquids in gas processing plants, and domestic methanol production. The PMM projects petroleum product prices and sources of supply for meeting petroleum product demand. The sources of supply include crude oil, both domestic and imported; other inputs including alcohols and ethers; natural gas plant liquids production; petroleum product imports; and refinery processing gain. In addition, the PMM estimates domestic refinery capacity expansion and fuel consumption. Product prices are estimated at the Census division level and much of the refining activity information is at the Petroleum Administration for Defense (PAD) District level. This report is organized as follows: Chapter 2, Model Purpose; Chapter 3, Model Overview and Rationale; Chapter 4, Model Structure; Appendix A, Inventory of Input Data, Parameter Estimates, and Model Outputs; Appendix B, Detailed Mathematical Description of the Model; Appendix C, Bibliography; Appendix D, Model Abstract; Appendix E, Data Quality; Appendix F, Estimation methodologies; Appendix G, Matrix Generator documentation; Appendix H, Historical Data Processing; and Appendix I, Biofuels Supply Submodule.

  7. The Strategic Petroleum Reserve

    SciTech Connect

    Not Available

    1991-01-01

    The Strategic Petroleum Reserve program was set into motion by the 1975 Energy Policy and Conservation Act (EPCA). By 1990, 590 million barrels of oil had been placed in storage. Salt domes along the Gulf Coast offered ideal storage. Both sweet'' and sour'' crude oil have been acquired using various purchase options. Drawdown, sale, and distribution of the oil would proceed according to guidelines set by EPCA in the event of a severe energy supply disruption. (SM)

  8. Constraining the age and magnitude of uplift in the northern National Petroleum Reserve in Alaska (NPRA)-apatite fission-track analysis of samples from three wells

    USGS Publications Warehouse

    Houseknecht, David W.; Bird, Kenneth J.; O'Sullivan, Paul

    2011-01-01

    A broad, post-mid-Cretaceous uplift is defined in the northern National Petroleum Reserve in Alaska (NPRA) by regional truncation of Cretaceous strata, thermal maturity patterns, and amounts of exhumation estimated from sonic logs. Apatite fission-track (AFT) analysis of samples from three wells (South Meade No. 1, Topagoruk No. 1, and Ikpikpuk No. 1) across the eastern flank of the uplift indicates Tertiary cooling followed by Quaternary heating. Results from all three wells indicate that cooling, presumably caused by uplift and erosion, started about 75-65 Ma (latest Cretaceous-earliest Tertiary) and continued through the Tertiary Period. Data from South Meade indicate more rapid cooling after about 35-15 Ma (latest Eocene-middle Miocene) followed by a significant increase in subsurface temperature during the Quaternary, probably the result of increased heat flow. Data from Topagoruk and Ikpikpuk include subtle evidence of accelerated cooling starting in the latest Eocene-middle Miocene and possible evidence of increased temperature during the Quaternary. Subsurface temperature perturbations related to the insulating effect of permafrost may have been responsible for the Quaternary temperature increase at Topagoruk and Ikpikpuk and may have been a contributing factor at South Meade. Multiple lines of geologic evidence suggest that the magnitude of exhumation resulting from uplift and erosion is 5,000-6,500 ft at South Meade, 4,000-5,500 ft at Topagoruk, and 2,500-4,000 ft at Ikpikpuk. The results from these wells help to define the broad geometry of the uplift, which increases in magnitude from less than 1,000 ft at the Colville River delta to perhaps more than 7,000 ft along the northwestern coast of NPRA, between Point Barrow and Peard Bay. Neither the origin nor the offshore extent of the uplift, west and north of the NPRA coast, have been determined.

  9. 1993 Conference on artificial intelligence in petroleum exploration and production: Proceedings

    SciTech Connect

    Not Available

    1993-01-01

    These proceedings contain 22 papers about the use of neural networks and expert systems in the petroleum industry for the following applications: data analysis of well logs; fracture recognition; formation evaluation while drilling; cathodic protection; soil remedial action; chemical reactions; interpretation of X-ray diffraction patterns; formation damage evaluation; choosing target wells for stimulation; ranking prospects; forecasting of oil output; reservoir history matching; workover operations; and selection of injection method. Papers have been processed separately for inclusion on the data base.

  10. Norwegian petroleum guide

    SciTech Connect

    Christie, H.B.

    1984-01-01

    This is about the comprehensive guide to Norwegian oil and gas activities, very useful to anyone in the industry. Material includes political guidelines, control institutions, work possibilities and licenses, working environment law, employer and employee organizations, national insurance, taxes, communication, rescue operations and standby. Contents: Oil and the economy; Petroleum technology research; Responsibilities of different authorities; The Labour Inspection Directorate; The Health Directorate Offshore Office; The Coastal Directorate; Helicopter traffic; The Norwegian Petroleum Directorate; The Maritime Directorate; Det norske Veritas; The Norwegian Waterways and Electricity Board; The State Institute for Radiation Hygiene; The State Explosive Inspection; Work possibilities in the North Sea; Working environment legislation on the Continental Shelf; Collective bargaining agreements, labor conflicts and the right to organize; Taxation Rules; National health insurance and the petroleum activity; Occupational injuries on the Norwegian Continental Shelf; Company insurances; The private pension scheme; Other types of insuracne common among oil companies; The rescue service in Norway; Oganizations within the oil industry offshore and onshore; and Law of aliens admission to the Kindgom.

  11. Analysis of cure in composites processing

    NASA Technical Reports Server (NTRS)

    Aylward, L.; Roylance, D.; Douglas, C.

    1984-01-01

    Finite element analysis is a general numerical tool for solving the field equations of engineering practice, and this paper demonstrates its use in modeling the nonisothermal cure of pultruded composite material. A very simple grid is used in this case to model a narrow strip of material, and this grid is then solved using a time-stepping transient algorithm to simulate the passage of the strip along the pultruder die. As time proceeds, heat is conducted into the strip from the heated boundaries at the die walls, and cure proceeds at a rate dependent on the local temperature. The computer model can be used to minimize the time needed for sufficient cure, and helps avoid such processing errors as undercure or thermal degradation.

  12. Digital data processing system dynamic loading analysis

    NASA Technical Reports Server (NTRS)

    Lagas, J. J.; Peterka, J. J.; Tucker, A. E.

    1976-01-01

    Simulation and analysis of the Space Shuttle Orbiter Digital Data Processing System (DDPS) are reported. The mated flight and postseparation flight phases of the space shuttle's approach and landing test configuration were modeled utilizing the Information Management System Interpretative Model (IMSIM) in a computerized simulation modeling of the ALT hardware, software, and workload. System requirements simulated for the ALT configuration were defined. Sensitivity analyses determined areas of potential data flow problems in DDPS operation. Based on the defined system requirements and the sensitivity analyses, a test design is described for adapting, parameterizing, and executing the IMSIM. Varying load and stress conditions for the model execution are given. The analyses of the computer simulation runs were documented as results, conclusions, and recommendations for DDPS improvements.

  13. Process analysis using ion mobility spectrometry.

    PubMed

    Baumbach, J I

    2006-03-01

    Ion mobility spectrometry, originally used to detect chemical warfare agents, explosives and illegal drugs, is now frequently applied in the field of process analytics. The method combines both high sensitivity (detection limits down to the ng to pg per liter and ppb(v)/ppt(v) ranges) and relatively low technical expenditure with a high-speed data acquisition. In this paper, the working principles of IMS are summarized with respect to the advantages and disadvantages of the technique. Different ionization techniques, sample introduction methods and preseparation methods are considered. Proven applications of different types of ion mobility spectrometer (IMS) used at ISAS will be discussed in detail: monitoring of gas insulated substations, contamination in water, odoration of natural gas, human breath composition and metabolites of bacteria. The example applications discussed relate to purity (gas insulated substations), ecology (contamination of water resources), plants and person safety (odoration of natural gas), food quality control (molds and bacteria) and human health (breath analysis).

  14. Process analysis using ion mobility spectrometry.

    PubMed

    Baumbach, J I

    2006-03-01

    Ion mobility spectrometry, originally used to detect chemical warfare agents, explosives and illegal drugs, is now frequently applied in the field of process analytics. The method combines both high sensitivity (detection limits down to the ng to pg per liter and ppb(v)/ppt(v) ranges) and relatively low technical expenditure with a high-speed data acquisition. In this paper, the working principles of IMS are summarized with respect to the advantages and disadvantages of the technique. Different ionization techniques, sample introduction methods and preseparation methods are considered. Proven applications of different types of ion mobility spectrometer (IMS) used at ISAS will be discussed in detail: monitoring of gas insulated substations, contamination in water, odoration of natural gas, human breath composition and metabolites of bacteria. The example applications discussed relate to purity (gas insulated substations), ecology (contamination of water resources), plants and person safety (odoration of natural gas), food quality control (molds and bacteria) and human health (breath analysis). PMID:16132133

  15. A point process analysis of sensory encoding.

    PubMed

    Stanley, Garrett B; Webber, Roxanna M

    2003-01-01

    Nowhere is the sparse nature of neuronal coding more evident than in the sensory cortex, where neuronal response becomes increasingly tuned to specific features of the sensory environment. For such situations, where rate modulation schemes do not accurately describe the neuronal response to sensory stimuli, statistical descriptions based on point process events are particularly appropriate. Here, intensity measures derived from experimental data in the rat somatosensory cortex enable the direct analysis of statistical structure within spike trains, as well as inter-relationships between tactile stimuli and neuronal response. Intensity measures capture structure in spontaneous as well as driven activity, reflecting the interplay between excitatory and suppressive influences on neuronal firing. Second-order intensity estimates reveal strong dependencies upon patterns of tactile stimulation, which define the neuronal response characteristics to temporally structured stimuli.

  16. Isolation and characterization of a hydrocarbonoclastic bacterial enrichment from total petroleum hydrocarbon contaminated sediments: potential candidates for bioaugmentation in bio-based processes.

    PubMed

    Di Gregorio, Simona; Siracusa, Giovanna; Becarelli, Simone; Mariotti, Lorenzo; Gentini, Alessandro; Lorenzi, Roberto

    2016-06-01

    Seven hydrocarbonoclastic new bacterial isolates were isolated from dredged sediments of a river estuary in Italy. The sediments were contaminated by shipyard activities since decades, mainly ascribable to the exploitation of diesel oil as the fuel for recreational and commercial navigation of watercrafts. The bacterial isolates were able to utilize diesel oil as sole carbon source. Their metabolic capacities were evaluated by GC-MS analysis, with reference to the depletion of both the normal and branched alkanes, the nC18 fatty acid methyl ester and the unresolved complex mixture of organic compounds. They were taxonomically identified as different species of Stenotrophomonas and Pseudomonas spp. by the combination of amplified ribosomal DNA restriction analysis (ARDRA) and repetitive sequence-based PCR (REP-PCR) analysis. The metabolic activities of interest were analyzed both in relation to the single bacterial strains and to the combination of the latter as a multibacterial species system. After 6 days of incubation in mineral medium with diesel oil as sole carbon source, the Stenotrophomonas sp. M1 strain depleted 43-46 % of Cn-alkane from C28 up to C30, 70 % of the nC18 fatty acid methyl ester and the 46 % of the unresolved complex mixture of organic compounds. On the other hand, the Pseudomonas sp. NM1 strain depleted the 76 % of the nC18 fatty acid methyl ester, the 50 % of the unresolved complex mixture of organic compounds. The bacterial multispecies system was able to completely deplete Cn-alkane from C28 up to C30 and to deplete the 95 % of the unresolved complex mixture of organic compounds. The isolates, either as single strains and as a bacterial multispecies system, were proposed as candidates for bioaugmentation in bio-based processes for the decontamination of dredged sediments. PMID:26755178

  17. Decision analysis applications and the CERCLA process

    SciTech Connect

    Purucker, S.T.; Lyon, B.F. |

    1994-06-01

    Quantitative decision methods can be developed during environmental restoration projects that incorporate stakeholder input and can complement current efforts that are undertaken for data collection and alternatives evaluation during the CERCLA process. These decision-making tools can supplement current EPA guidance as well as focus on problems that arise as attempts are made to make informed decisions regarding remedial alternative selection. In examining the use of such applications, the authors discuss the use of decision analysis tools and their impact on collecting data and making environmental decisions from a risk-based perspective. They will look at the construction of objective functions for quantifying different risk-based perspective. They will look at the construction of objective functions for quantifying different risk-based decision rules that incorporate stakeholder concerns. This represents a quantitative method for implementing the Data Quality Objective (DQO) process. These objective functions can be expressed using a variety of indices to analyze problems that currently arise in the environmental field. Examples include cost, magnitude of risk, efficiency, and probability of success or failure. Based on such defined objective functions, a project can evaluate the impact of different risk and decision selection strategies on data worth and alternative selection.

  18. Thermodynamic Analysis of Nanoporous Membrane Separation Processes

    NASA Astrophysics Data System (ADS)

    Rogers, David; Rempe, Susan

    2011-03-01

    We give an analysis of desalination energy requirements in order to quantify the potential for future improvements in desalination membrane technology. Our thermodynamic analysis makes it possible to draw conclusions from the vast array of equilibrium molecular dynamics simulations present in the literature as well as create a standardized comparison for measuring and reporting experimental reverse osmosis material efficiency. Commonly employed methods for estimating minimum desalination energy costs have been revised to include operations at positive input stream recovery ratios using a thermodynamic cycle analogous to the Carnot cycle. Several gaps in the statistical mechanical theory of irreversible processes have also been identified which may in the future lead to improved communication between materials engineering models and statistical mechanical simulation. Simulation results for silica surfaces and nanochannels are also presented. Sandia National Laboratories is a multi-program laboratory operated by Sandia Corporation, a subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.

  19. Petroleum Market Model of the National Energy Modeling System. Part 1

    SciTech Connect

    1997-12-18

    The purpose of this report is to define the objectives of the Petroleum Market Model (PMM), describe its basic approach, and provide detail on how it works. This report is intended as a reference document for model analysts, users, and the public. The PMM models petroleum refining activities, the marketing of petroleum products to consumption regions, the production of natural gas liquids in gas processing plants, and domestic methanol production. The PMM projects petroleum product prices and sources of supply for meeting petroleum product demand. The sources of supply include crude oil, both domestic and imported; other inputs including alcohols and ethers; natural gas plant liquids production; petroleum product imports; and refinery processing gain. In addition, the PMM estimates domestic refinery capacity expansion and fuel consumption. Product prices are estimated at the Census division level and much of the refining activity information is at the Petroleum Administration for Defense (PAD) District level.

  20. [National Institute for Petroleum and Energy Research] monthly progress report, July 1992

    SciTech Connect

    Not Available

    1992-09-01

    Accomplishments for the month of July are described briefly under tasks for: Energy Production Research; Fuels Research; and Supplemental Government Program. Energy Production Research includes: reservoir assessment and characterization; TORIS research support; development of improved microbial flooding methods; surfactant flooding methods; development of improved alkaline flooding methods; mobility control and sweep improvement in chemical flooding; gas flood performance prediction improvement; mobility control, profile modification, and sweep improvement in gas flooding; three-phase relative permeability research; thermal processes for light oil recovery; thermal processes for heavy oil recovery; and imaging techniques applied to the study of fluids in porous media. Fuel Research includes: development of analytical methodology for analysis of heavy crudes; and thermochemistry and thermophysical properties of organic nitrogen- and diheteroatom-containing compounds. Supplement Government Program includes: microbial-enhanced waterflooding field project; feasibility study of heavy oil recovery in the midcontinent region--Oklahoma, Kansas, and Missouri; surfactant-enhanced alkaline flooding field project; development of methods for mapping distribution of clays in petroleum reservoirs; summary of geological and production characteristics of class 1. unstructured, deltaic reservoirs; third international reservoir characterization technical conference; process-engineering property measurements on heavy petroleum components; development and application of petroleum production technologies; upgrade BPO crude oil data base; simulation analysis of steam-foam projects; analysis of the US oil resource base and estimate of future recoverable oil; DOE education initiative project; and technology transfer to independent producers.

  1. (National Institute for Petroleum and Energy Research) monthly progress report, July 1992

    SciTech Connect

    Not Available

    1992-09-01

    Accomplishments for the month of July are described briefly under tasks for: Energy Production Research; Fuels Research; and Supplemental Government Program. Energy Production Research includes: reservoir assessment and characterization; TORIS research support; development of improved microbial flooding methods; surfactant flooding methods; development of improved alkaline flooding methods; mobility control and sweep improvement in chemical flooding; gas flood performance prediction improvement; mobility control, profile modification, and sweep improvement in gas flooding; three-phase relative permeability research; thermal processes for light oil recovery; thermal processes for heavy oil recovery; and imaging techniques applied to the study of fluids in porous media. Fuel Research includes: development of analytical methodology for analysis of heavy crudes; and thermochemistry and thermophysical properties of organic nitrogen- and diheteroatom-containing compounds. Supplement Government Program includes: microbial-enhanced waterflooding field project; feasibility study of heavy oil recovery in the midcontinent region--Oklahoma, Kansas, and Missouri; surfactant-enhanced alkaline flooding field project; development of methods for mapping distribution of clays in petroleum reservoirs; summary of geological and production characteristics of class 1. unstructured, deltaic reservoirs; third international reservoir characterization technical conference; process-engineering property measurements on heavy petroleum components; development and application of petroleum production technologies; upgrade BPO crude oil data base; simulation analysis of steam-foam projects; analysis of the US oil resource base and estimate of future recoverable oil; DOE education initiative project; and technology transfer to independent producers.

  2. (National Institute for Petroleum and Energy Research) monthly progress report for June 1992

    SciTech Connect

    Not Available

    1992-08-01

    Accomplishments for this period are described briefly under tasks for: Energy Production Research; Fuels Research; and Supplemental Government Program. Energy Production Research includes: reservoir assessment and characterization; TORIS research support; development of improved microbial flooding methods; surfactant flooding methods; development of improved alkaline flooding methods; mobility control and sweep improvement in chemical flooding; gas flood performance prediction improvement; mobility control, profile modification, and sweep improvement in gas flooding; three-phase relative permeability research; thermal processes for light oil recovery; thermal processes for heavy oil recovery; and imaging techniques applied to the study of fluid in porous media. Fuels research includes; development of analytical methodology for analysis of heavy crudes; and thermochemistry and thermophysical properties of organic nitrogen- and diheteroatom-containing compounds. Supplemental Government Program includes: microbial-enhanced waterflooding field project; feasibility study of heavy oil recovery in the midcontinent region--Oklahoma, Kansas, and Missouri; surfactant-enhanced alkaline flooding field project; development of methods for mapping distribution of clays in petroleum reservoirs; summary of geological and production characteristics of class 1, unstructured, deltaic reservoirs; third international reservoir characterization technical conference; process-engineering property measurements on heavy petroleum components; development and application of petroleum production technologies; upgrade BPO crude oil data base; simulation analysis of steam-foam projects; and analysis of the U. S. oil resource base and estimate of future recoverable oil.

  3. [National Institute for Petroleum and Energy Research] monthly progress report for June 1992

    SciTech Connect

    Not Available

    1992-08-01

    Accomplishments for this period are described briefly under tasks for: Energy Production Research; Fuels Research; and Supplemental Government Program. Energy Production Research includes: reservoir assessment and characterization; TORIS research support; development of improved microbial flooding methods; surfactant flooding methods; development of improved alkaline flooding methods; mobility control and sweep improvement in chemical flooding; gas flood performance prediction improvement; mobility control, profile modification, and sweep improvement in gas flooding; three-phase relative permeability research; thermal processes for light oil recovery; thermal processes for heavy oil recovery; and imaging techniques applied to the study of fluid in porous media. Fuels research includes; development of analytical methodology for analysis of heavy crudes; and thermochemistry and thermophysical properties of organic nitrogen- and diheteroatom-containing compounds. Supplemental Government Program includes: microbial-enhanced waterflooding field project; feasibility study of heavy oil recovery in the midcontinent region--Oklahoma, Kansas, and Missouri; surfactant-enhanced alkaline flooding field project; development of methods for mapping distribution of clays in petroleum reservoirs; summary of geological and production characteristics of class 1, unstructured, deltaic reservoirs; third international reservoir characterization technical conference; process-engineering property measurements on heavy petroleum components; development and application of petroleum production technologies; upgrade BPO crude oil data base; simulation analysis of steam-foam projects; and analysis of the U. S. oil resource base and estimate of future recoverable oil.

  4. A novel bioremediation strategy for petroleum hydrocarbon pollutants using salt tolerant Corynebacterium variabile HRJ4 and biochar.

    PubMed

    Zhang, Hairong; Tang, Jingchun; Wang, Lin; Liu, Juncheng; Gurav, Ranjit Gajanan; Sun, Kejing

    2016-09-01

    The present work aimed to develop a novel strategy to bioremediate the petroleum hydrocarbon contaminants in the environment. Salt tolerant bacterium was isolated from Dagang oilfield, China and identified as Corynebacterium variabile HRJ4 based on 16S rRNA gene sequence analysis. The bacterium had a high salt tolerant capability and biochar was developed as carrier for the bacterium. The bacteria with biochar were most effective in degradation of n-alkanes (C16, C18, C19, C26, C28) and polycyclic aromatic hydrocarbons (NAP, PYR) mixture. The result demonstrated that immobilization of C. variabile HRJ4 with biochar showed higher degradation of total petroleum hydrocarbons (THPs) up to 78.9% after 7-day of incubation as compared to the free leaving bacteria. The approach of this study will be helpful in clean-up of petroleum-contamination in the environments through bioremediation process using eco-friendly and cost effective materials like biochar. PMID:27593267

  5. Uptake and trans-membrane transport of petroleum hydrocarbons by microorganisms

    PubMed Central

    Hua, Fei; Wang, Hong Qi

    2014-01-01

    Petroleum-based products are a primary energy source in the industry and daily life. During the exploration, processing, transport and storage of petroleum and petroleum products, water or soil pollution occurs regularly. Biodegradation of the hydrocarbon pollutants by indigenous microorganisms is one of the primary mechanisms of removal of petroleum compounds from the environment. However, the physical contact between microorganisms and hydrophobic hydrocarbons limits the biodegradation rate. This paper presents an updated review of the petroleum hydrocarbon uptake and transport across the outer membrane of microorganisms with the help of outer membrane proteins. PMID:26740752

  6. Petroleum marketing monthly, August 1994

    SciTech Connect

    Not Available

    1994-08-15

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product Sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Monthly.

  7. Petroleum marketing monthly, September 1994

    SciTech Connect

    Not Available

    1994-09-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum product sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Monthly.

  8. Heat Recovery and Energy Conservation in Petroleum Refining.

    NASA Astrophysics Data System (ADS)

    Larsen, William Gale

    1990-01-01

    The focus of the analysis presented here is improved recovery (and use) of waste heat at existing petroleum refineries. The major energy-conservation opportunities associated with waste heat are systematically examined both physically and in terms of cost. The opportunities at the Study Refinery are systematically examined in detail. The presentation begins with an overview of the processes carried out in contemporary petroleum refineries including discussion of typical energy use. There follows a brief thermodynamic description of refinery energy flows with an emphasis on heat and on energy-efficiency analysis. The heart of the thesis is Chapters 3-5 describing heat recovery opportunities involving, respectively: extraction and use of heat from combustion gases being discharged through stacks, the exchange of heat between product streams, and uses for low-temperature waste heat. In Chapter 6, a unifying economic concept is introduced (with details in the Appendix): a "supply curve" for saved energy. This describes the potential rate of energy savings in barrels of oil-equivalent per year (in analogy with production capacity of oil or gas fields), as a function of the cost of saved energy in dollars per barrel (in analogy with the production cost of energy). The nature of the distribution is, of course, for the cost of saved energy to increase with increasing energy savings. In this chapter, estimates are presented for the energy conservation opportunities other than waste heat at the Study Refinery. All the opportunities are then summarized in a single supply curve. The extraordinary result in a cost-effective opportunity to reduce refinery energy use by some 26% at 1984 prices. This translates into roughly a 1 energy-cost reduction per 42-gallon barrel of petroleum input. Of course, investments are required; the net benefit would be about 1.5 cents per gallon of product. This would be a major benefit in relation to typical refinery earnings. The concluding

  9. Petroleum marketing monthly, December 1995

    SciTech Connect

    1995-12-05

    This publication provides information and statistical data on a variety of crude oils and refined petroleum products. It presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include domestic first purchase price, f.o.b. and landed cost of imported crude, and refiners` acquisition cost of crude. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane.

  10. National Institute for Petroleum and Energy Research 1989 annual report

    SciTech Connect

    Not Available

    1990-11-01

    Research programs on reservoir rocks petroleum, and enhanced recovery are briefly presented. Topics include: Geotechnology; reservoir assessment and characterization; TORIS Research Support; three phase relative permeability; static pore structure analysis of reservoir rocks; effects of pore structure on oil/contaminants ganglia distribution; development of improved microbial flooding methods; development of improved surfactant flooding systems; development of improved alkaline flooding methods; development of improved mobility-control methods; gas miscible displacement; development of improved immiscible gas displacement methodology; thermal processes for light oil recovery; thermal processes for heavy oil recovery; an application of natural isotopes in groundwater for solving environmental problems; processing and thermodynamics research; thermochemistry and thermophysical properties of organic nitrogen- and diheteroatom-containing compounds; in situ hydrogenation; and fuel chemistry.

  11. Petroleum supply monthly: December 1993

    SciTech Connect

    Not Available

    1993-12-01

    Data are presented which describe the supply and disposition of petroleum products in the United States and major U.S. geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States. Data are presented in two sections: Summary Statistics, presenting a time series of selected petroleum data on a U.S. level, and Detailed Statistics, presenting statistics for the most current month available as well as year to date.

  12. 15 CFR Supplement No. 1 to Part 754 - Petroleum and Petroleum Products

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 15 Commerce and Foreign Trade 2 2013-01-01 2013-01-01 false Petroleum and Petroleum Products No... SUPPLY CONTROLS Pt. 754, Supp. 1 Supplement No. 1 to Part 754—Petroleum and Petroleum Products This... petroleum (including reconstituted crude petroleum), tar sands and crude shale oil. 2710.0710...

  13. 19 CFR 151.47 - Optional entry of net quantity of petroleum or petroleum products.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 19 Customs Duties 2 2012-04-01 2012-04-01 false Optional entry of net quantity of petroleum or petroleum products. 151.47 Section 151.47 Customs Duties U.S. CUSTOMS AND BORDER PROTECTION, DEPARTMENT OF... Petroleum and Petroleum Products § 151.47 Optional entry of net quantity of petroleum or petroleum...

  14. 19 CFR 151.47 - Optional entry of net quantity of petroleum or petroleum products.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 19 Customs Duties 2 2013-04-01 2013-04-01 false Optional entry of net quantity of petroleum or petroleum products. 151.47 Section 151.47 Customs Duties U.S. CUSTOMS AND BORDER PROTECTION, DEPARTMENT OF... Petroleum and Petroleum Products § 151.47 Optional entry of net quantity of petroleum or petroleum...

  15. 31 CFR 542.412 - Transactions relating to Syrian petroleum or petroleum products from third countries...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... petroleum or petroleum products from third countries; transshipments. 542.412 Section 542.412 Money and... Syrian petroleum or petroleum products from third countries; transshipments. (a) Transactions relating to goods containing petroleum or petroleum products of Syrian origin are not prohibited by § 542.208...

  16. 19 CFR 151.47 - Optional entry of net quantity of petroleum or petroleum products.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 19 Customs Duties 2 2014-04-01 2014-04-01 false Optional entry of net quantity of petroleum or petroleum products. 151.47 Section 151.47 Customs Duties U.S. CUSTOMS AND BORDER PROTECTION, DEPARTMENT OF... Petroleum and Petroleum Products § 151.47 Optional entry of net quantity of petroleum or petroleum...

  17. 19 CFR 151.47 - Optional entry of net quantity of petroleum or petroleum products.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 19 Customs Duties 2 2011-04-01 2011-04-01 false Optional entry of net quantity of petroleum or petroleum products. 151.47 Section 151.47 Customs Duties U.S. CUSTOMS AND BORDER PROTECTION, DEPARTMENT OF... Petroleum and Petroleum Products § 151.47 Optional entry of net quantity of petroleum or petroleum...

  18. 19 CFR 151.47 - Optional entry of net quantity of petroleum or petroleum products.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 19 Customs Duties 2 2010-04-01 2010-04-01 false Optional entry of net quantity of petroleum or petroleum products. 151.47 Section 151.47 Customs Duties U.S. CUSTOMS AND BORDER PROTECTION, DEPARTMENT OF... Petroleum and Petroleum Products § 151.47 Optional entry of net quantity of petroleum or petroleum...

  19. Impact of electric cars on U.S. petroleum consumption

    NASA Astrophysics Data System (ADS)

    Collins, M. M.; Carriere, W. M.

    1980-02-01

    A computer model that forecasts electricity demand and capacity on an hourly basis for each major electric power company in the United States is used to analyze the potential impact of electric cars on national petroleum consumption in 1980, 1990, and 2000. The analysis, based on 1978 and 1979 growth projections by the industry, shows that if all cars were electrified in the year 2000, autombile petroleum use would be cut by 75 percent, saving 2.5 million barrels of crude oil a day, or 14 percent of future national petroleum consumption. Most cars could be charged overnight from otherwise idle coal and nuclear power plants.

  20. Airborne LIDAR Data Processing and Analysis Tools

    NASA Astrophysics Data System (ADS)

    Zhang, K.

    2007-12-01

    Airborne LIDAR technology allows accurate and inexpensive measurements of topography, vegetation canopy heights, and buildings over large areas. In order to provide researchers high quality data, NSF has created the National Center for Airborne Laser Mapping (NCALM) to collect, archive, and distribute the LIDAR data. However, the LIDAR systems collect voluminous irregularly-spaced, three-dimensional point measurements of ground and non-ground objects scanned by the laser beneath the aircraft. To advance the use of the technology and data, NCALM is developing public domain algorithms for ground and non-ground measurement classification and tools for data retrieval and transformation. We present the main functions of the ALDPAT (Airborne LIDAR Data Processing and Analysis Tools) developed by NCALM. While Geographic Information Systems (GIS) provide a useful platform for storing, analyzing, and visualizing most spatial data, the shear volume of raw LIDAR data makes most commercial GIS packages impractical. Instead, we have developed a suite of applications in ALDPAT which combine self developed C++ programs with the APIs of commercial remote sensing and GIS software. Tasks performed by these applications include: 1) transforming data into specified horizontal coordinate systems and vertical datums; 2) merging and sorting data into manageable sized tiles, typically 4 square kilometers in dimension; 3) filtering point data to separate measurements for the ground from those for non-ground objects; 4) interpolating the irregularly spaced elevations onto a regularly spaced grid to allow raster based analysis; and 5) converting the gridded data into standard GIS import formats. The ALDPAT 1.0 is available through http://lidar.ihrc.fiu.edu/.

  1. Meteor radar signal processing and error analysis

    NASA Astrophysics Data System (ADS)

    Kang, Chunmei

    Meteor wind radar systems are a powerful tool for study of the horizontal wind field in the mesosphere and lower thermosphere (MLT). While such systems have been operated for many years, virtually no literature has focused on radar system error analysis. The instrumental error may prevent scientists from getting correct conclusions on geophysical variability. The radar system instrumental error comes from different sources, including hardware, software, algorithms and etc. Radar signal processing plays an important role in radar system and advanced signal processing algorithms may dramatically reduce the radar system errors. In this dissertation, radar system error propagation is analyzed and several advanced signal processing algorithms are proposed to optimize the performance of radar system without increasing the instrument costs. The first part of this dissertation is the development of a time-frequency waveform detector, which is invariant to noise level and stable to a wide range of decay rates. This detector is proposed to discriminate the underdense meteor echoes from the background white Gaussian noise. The performance of this detector is examined using Monte Carlo simulations. The resulting probability of detection is shown to outperform the often used power and energy detectors for the same probability of false alarm. Secondly, estimators to determine the Doppler shift, the decay rate and direction of arrival (DOA) of meteors are proposed and evaluated. The performance of these estimators is compared with the analytically derived Cramer-Rao bound (CRB). The results show that the fast maximum likelihood (FML) estimator for determination of the Doppler shift and decay rate and the spatial spectral method for determination of the DOAs perform best among the estimators commonly used on other radar systems. For most cases, the mean square error (MSE) of the estimator meets the CRB above a 10dB SNR. Thus meteor echoes with an estimated SNR below 10dB are

  2. [Tracking analysis of three extraction processes of Arenaria Polytrichoides by Fourier transform infrared spectrocopy].

    PubMed

    Ma, Jing; Wu, Xian-Xue; Tai, Xi; Xu, Liu-Xian; Zhu, Jin-Lan; Qin, Yao; Zhou, Qun; Sun, Su-Qin

    2014-10-01

    In order to develop a process analysis method to guide extraction process of Arenaria polytrichoides (AP) based on tracking analysis by Fourier transform infrared (FTIR), IR spectra of petroleum ether extracts (PE-E), ethyl acetate extracts (EtOAc-E), n-butanol extracts (n-BuOH-E) and water extracts (H2O-E) of AP from three extraction methods were recorded. The FTIR and corresponding second derivative infrared (SDIR) spectra were analyzed comparatively from two aspects, namely, different extracts from a same extraction process and the same extracts from different methods. The spectral analysis results show that different extracts obtained from a same extraction process have distinctly different spectral absorbance character. Although the IR spectral absorption characteristics of the same extracts from different methods are rather similar in holistic, some explicit spectral differences still could be found among each other. In extraction process one (M1), main flavonoids and their glycosides of AP migrated to EtOAc-E and the rest part of them shift to n-BuOH-E according to FTIR peaks such as 1,603 and 1,123 cm(-1). However, the circumstances in method two (M2) and method three (M3) were just the reverse. Moreover, a few flavonoid glycosides got into H2O-E. The relative content of all kinds of aglycones and higher saturated alkyl are much higher in EtOAc-E of M2 than that of M1 and M3 according to the relative absorption intensive of peak at 2,850 cm(-1). Similarly, n-BuOH-E of M3 has relative rich contents of glycosides: and polysaccharides than those of M1 and M2 by peaks, such as 1,066 and 2,927 cm(-1). These results demonstrate that the migration rules of AP components are not always same in different extrac- tion process. The substance migration information during the extraction process could be recorded and disclosed in an intuitive way by FTIR tracking analysis of corresponding extracts. Consequently, FTIR tracking analysis is a fast, efficient, low-carbon and

  3. Goals Analysis Procedure Guidelines for Applying the Goals Analysis Process

    NASA Technical Reports Server (NTRS)

    Motley, Albert E., III

    2000-01-01

    One of the key elements to successful project management is the establishment of the "right set of requirements", requirements that reflect the true customer needs and are consistent with the strategic goals and objectives of the participating organizations. A viable set of requirements implies that each individual requirement is a necessary element in satisfying the stated goals and that the entire set of requirements, taken as a whole, is sufficient to satisfy the stated goals. Unfortunately, it is the author's experience that during project formulation phases' many of the Systems Engineering customers do not conduct a rigorous analysis of the goals and objectives that drive the system requirements. As a result, the Systems Engineer is often provided with requirements that are vague, incomplete, and internally inconsistent. To complicate matters, most systems development methodologies assume that the customer provides unambiguous, comprehensive and concise requirements. This paper describes the specific steps of a Goals Analysis process applied by Systems Engineers at the NASA Langley Research Center during the formulation of requirements for research projects. The objective of Goals Analysis is to identify and explore all of the influencing factors that ultimately drive the system's requirements.

  4. International petroleum statistics report

    SciTech Connect

    1995-10-01

    The International Petroleum Statistics Report is a monthly publication that provides current international oil data. This report presents data on international oil production, demand, imports, exports and stocks. The report has four sections. Section 1 contains time series data on world oil production, and on oil demand and stocks in the Organization for Economic Cooperation and Development (OECD). Section 2 presents an oil supply/demand balance for the world, in quarterly intervals for the most recent two years. Section 3 presents data on oil imports by OECD countries. Section 4 presents annual time series data on world oil production and oil stocks, demand, and trade in OECD countries.

  5. Underground petroleum tanks

    SciTech Connect

    Not Available

    1990-07-01

    This book presents the results of a survey of 46 state underground storage tank program officials. The survey covers: Whether petroleum tank insurance (mandated by the EPA) is available in each state and whether category 3 and 4 owners can obtain it; state programs that help owners meet the financial responsibility and/or technical requirements of such insurance; and lending institutions' attitudes towards providing loans to storage tank owners. A survey of the number and terms of insurance policies offered to tank owners is also presented.

  6. Applications of T-ray spectroscopy in the petroleum field

    NASA Astrophysics Data System (ADS)

    Al-Douseri, Fatemah M.

    2005-11-01

    Because of heavy usage of petroleum products, which are the main source of energy in daily life and industry, a fast, reliable, and portable analysis system is needed to complement traditional techniques. Terahertz (THz) radiation, or T-rays, is electromagnetic radiation in the 0.1 to 10 THz frequency range. One unique attribute of T-rays is their ability to sensitively measure the induced molecular dipole moments in non-polar liquids such as aromatics, which make up the majority of the contents of many petroleum products. This information can lead to several applications in petroleum analysis. The application of T-rays to petroleum product analysis has the potential to make a significant impact in the petroleum field. In this dissertation, I show the first use of T-ray time-domain spectroscopy and Fourier transform infrared (FTIR) spectroscopy techniques for petroleum product analysis. I report on the feasibility of analyzing selected petroleum products, including gasoline, diesel, lubricating oil, and selected compounds of toluene, ethylbenzene, and xylene (BTEX). With the use of a T-ray time-domain spectrometer. I demonstrate that gasolines with different octane numbers and diesel all show specific absorption coefficients and refractive indexes in the spectral range from 0.5 to 2.0 THz. Furthermore, I report the qualitative and quantitative analysis of selected BTEX components in gasoline and diesel using FTIR spectroscopy in the 50 to 650 cm-1 region. I distinguish gasolines with different octane numbers from diesel and lubricating oil according to their different spectral features. I also determine the concentration of (o, m, p) xylene isomers in gasoline according to their specific absorption bands. The experimental results in this thesis, imply that linking between the knowledge of petroleum products and the development of T-ray spectrometer with the cooperation of industry might translate the T-ray spectroscopic system into a real world application in

  7. Petroleum policy and Mexican domestic politics: left opposition, regional dissidence, and official apostasy

    SciTech Connect

    Williams, E.J.

    1980-07-01

    The economic significance of petroleum is affecting Mexico's political system and will challenge socio-economic changes as they develop. A case study of Mexico illustrates how a developing petroleum industry can lubricate the process of political change to a more-participatory democracy as increased mobilization and rising expectations trigger political reforms. The analysis traces opposition forces reacting to the state oil monopoly PEMEX's decision to build a gas pipeline to the US, the disruption of massive labor migrations to the oil fields, and the initiatives to amend the constitution to allow land appropriations. It suggests that these forces can push the political structure to either the right or the left. The analysis is compared with the situations in Iran and Venezuela, where the socio-economic picture is less encouraging than in Mexico. 69 references. (DCK)

  8. Environmental hazard and risk characterisation of petroleum substances: a guided "walking tour" of petroleum hydrocarbons.

    PubMed

    Bierkens, Johan; Geerts, Lieve

    2014-05-01

    Petroleum substances are used in large quantities, primarily as fuels. They are complex mixtures whose major constituents are hydrocarbons derived from crude oil by distillation and fractionation. Determining the complete molecular composition of petroleum and its refined products is not feasible with current analytical techniques because of the huge number of molecular components. This complex nature of petroleum products, with their varied number of constituents, all of them exhibiting different fate and effect characteristics, merits a dedicated hazard and risk assessment approach. From a regulatory perspective they pose a great challenge in a number of REACH processes, in particular in the context of dossier and substance evaluation but also for priority setting activities. In order to facilitate the performance of hazard and risk assessment for petroleum substances the European oil company association, CONCAWE, has developed the PETROTOX and PETRORISK spreadsheet models. Since the exact composition of many petroleum products is not known, an underlying assumption of the PETROTOX and PETRORISK tools is that the behaviour and fate of a total petroleum substance can be simulated based on the physical-chemical properties of representative structures mapped to hydrocarbon blocks (HBs) and on the relative share of each HB in the total mass of the product. To assess how differing chemical compositions affect the simulated chemical fate and toxicity of hydrocarbon mixtures, a series of model simulations were run using an artificial petroleum substance, containing 386 (PETROTOX) or 160 (PETRORISK) HBs belonging to different chemical classes and molecular weight ranges, but with equal mass assigned to each of them. To this artificial petroleum substance a guided series of subsequent modifications in mass allocation to a delineated number of HBs belonging to different chemical classes and carbon ranges was performed, in what we perceived as a guided "walking tour

  9. Environmental hazard and risk characterisation of petroleum substances: a guided "walking tour" of petroleum hydrocarbons.

    PubMed

    Bierkens, Johan; Geerts, Lieve

    2014-05-01

    Petroleum substances are used in large quantities, primarily as fuels. They are complex mixtures whose major constituents are hydrocarbons derived from crude oil by distillation and fractionation. Determining the complete molecular composition of petroleum and its refined products is not feasible with current analytical techniques because of the huge number of molecular components. This complex nature of petroleum products, with their varied number of constituents, all of them exhibiting different fate and effect characteristics, merits a dedicated hazard and risk assessment approach. From a regulatory perspective they pose a great challenge in a number of REACH processes, in particular in the context of dossier and substance evaluation but also for priority setting activities. In order to facilitate the performance of hazard and risk assessment for petroleum substances the European oil company association, CONCAWE, has developed the PETROTOX and PETRORISK spreadsheet models. Since the exact composition of many petroleum products is not known, an underlying assumption of the PETROTOX and PETRORISK tools is that the behaviour and fate of a total petroleum substance can be simulated based on the physical-chemical properties of representative structures mapped to hydrocarbon blocks (HBs) and on the relative share of each HB in the total mass of the product. To assess how differing chemical compositions affect the simulated chemical fate and toxicity of hydrocarbon mixtures, a series of model simulations were run using an artificial petroleum substance, containing 386 (PETROTOX) or 160 (PETRORISK) HBs belonging to different chemical classes and molecular weight ranges, but with equal mass assigned to each of them. To this artificial petroleum substance a guided series of subsequent modifications in mass allocation to a delineated number of HBs belonging to different chemical classes and carbon ranges was performed, in what we perceived as a guided "walking tour

  10. Novel applications of light hydrocarbons chemistry in petroleum exploration

    SciTech Connect

    Mango, F.D. )

    1991-03-01

    The light hydrocarbons in petroleum are products of a kerogen-specific catalytic process. The catalysts are believed to be the transition metals entrained in kerogen. The process is controlled by the metals in the active sites and the kerogenous organic structures surrounding the active sites. Different catalytic sites are suggested to yield distinct distributions of light hydrocarbons. The author recognizes three dominant (primary) distributions, with all other distributions adequately represented by some linear combination of the three primary distributions. Three catalytic sites, therefore, can be associated with the generation of light hydrocarbons. He introduces a simple and inexpensive procedure using cross plots of various product ratios to correlate oils and source rocks. It has proven to be a remarkably articulate and powerful tool for deconvoluting diverse oils into genetic groups. The light hydrocarbons are also indicators of oil-generation temperature and other physical parameters associated with oil generation. The analysis of light hydrocarbons from this perspective is new. It provides the exploration geochemist with a novel technique for gaining insight into the fundamental chemistry of petroleum generation.

  11. Potential applications of bioprocess technology in petroleum industry.

    PubMed

    Singh, Ajay; Singh, Brajesh; Ward, Owen

    2012-11-01

    Petroleum refining is traditionally based on the use of physicochemical processes such as distillation and chemical catalysis that operate under high temperatures and pressures conditions, which are energy intensive and costly. Biotechnology has become an important tool for providing new approaches in petroleum industry during oil production, refining and processing as well as managing environmentally safe pollutant remediation and disposal practices. Earlier biotechnology applications in the petroleum industry were limited to microbial enhanced oil recovery, applications of bioremediation to contaminated marine shorelines, soils and sludges. The potential role of bioprocess technology in this industry has now expanded further into the areas of biorefining and upgrading of fuels, production of fine chemicals, control of souring during production and air VOC biofiltration. In this paper we provide an overview of the major applications of bioprocesses and technology development in the petroleum industry both in upstream and downstream areas and highlight future challenges and opportunities.

  12. BTEX biodegradation by bacteria from effluents of petroleum refinery.

    PubMed

    Mazzeo, Dânia Elisa Christofoletti; Levy, Carlos Emílio; de Angelis, Dejanira de Franceschi; Marin-Morales, Maria Aparecida

    2010-09-15

    Groundwater contamination with benzene, toluene, ethylbenzene and xylene (BTEX) has been increasing, thus requiring an urgent development of methodologies that are able to remove or minimize the damages these compounds can cause to the environment. The biodegradation process using microorganisms has been regarded as an efficient technology to treat places contaminated with hydrocarbons, since they are able to biotransform and/or biodegrade target pollutants. To prove the efficiency of this process, besides chemical analysis, the use of biological assessments has been indicated. This work identified and selected BTEX-biodegrading microorganisms present in effluents from petroleum refinery, and evaluated the efficiency of microorganism biodegradation process for reducing genotoxic and mutagenic BTEX damage through two test-systems: Allium cepa and hepatoma tissue culture (HTC) cells. Five different non-biodegraded BTEX concentrations were evaluated in relation to biodegraded concentrations. The biodegradation process was performed in a BOD Trak Apparatus (HACH) for 20 days, using microorganisms pre-selected through enrichment. Although the biodegradation usually occurs by a consortium of different microorganisms, the consortium in this study was composed exclusively of five bacteria species and the bacteria Pseudomonas putida was held responsible for the BTEX biodegradation. The chemical analyses showed that BTEX was reduced in the biodegraded concentrations. The results obtained with genotoxicity assays, carried out with both A. cepa and HTC cells, showed that the biodegradation process was able to decrease the genotoxic damages of BTEX. By mutagenic tests, we observed a decrease in damage only to the A. cepa organism. Although no decrease in mutagenicity was observed for HTC cells, no increase of this effect after the biodegradation process was observed either. The application of pre-selected bacteria in biodegradation processes can represent a reliable and

  13. BTEX biodegradation by bacteria from effluents of petroleum refinery.

    PubMed

    Mazzeo, Dânia Elisa Christofoletti; Levy, Carlos Emílio; de Angelis, Dejanira de Franceschi; Marin-Morales, Maria Aparecida

    2010-09-15

    Groundwater contamination with benzene, toluene, ethylbenzene and xylene (BTEX) has been increasing, thus requiring an urgent development of methodologies that are able to remove or minimize the damages these compounds can cause to the environment. The biodegradation process using microorganisms has been regarded as an efficient technology to treat places contaminated with hydrocarbons, since they are able to biotransform and/or biodegrade target pollutants. To prove the efficiency of this process, besides chemical analysis, the use of biological assessments has been indicated. This work identified and selected BTEX-biodegrading microorganisms present in effluents from petroleum refinery, and evaluated the efficiency of microorganism biodegradation process for reducing genotoxic and mutagenic BTEX damage through two test-systems: Allium cepa and hepatoma tissue culture (HTC) cells. Five different non-biodegraded BTEX concentrations were evaluated in relation to biodegraded concentrations. The biodegradation process was performed in a BOD Trak Apparatus (HACH) for 20 days, using microorganisms pre-selected through enrichment. Although the biodegradation usually occurs by a consortium of different microorganisms, the consortium in this study was composed exclusively of five bacteria species and the bacteria Pseudomonas putida was held responsible for the BTEX biodegradation. The chemical analyses showed that BTEX was reduced in the biodegraded concentrations. The results obtained with genotoxicity assays, carried out with both A. cepa and HTC cells, showed that the biodegradation process was able to decrease the genotoxic damages of BTEX. By mutagenic tests, we observed a decrease in damage only to the A. cepa organism. Although no decrease in mutagenicity was observed for HTC cells, no increase of this effect after the biodegradation process was observed either. The application of pre-selected bacteria in biodegradation processes can represent a reliable and

  14. Invariance in the isoheptanes of petroleum

    SciTech Connect

    Mango, F.D.

    1987-07-31

    Four isoheptanes in petroleum display a remarkable invariance in a ratio of sums of concentrations. The isoheptanes are not at thermodynamic equilibrium, nor are they fixed to some constant composition. The four isomers display coherent change in relative amounts but maintain invariance in the ratio of sums. Within sets of genetically related petroleum samples, invariance reaches levels that approach the limits of their analytical precision. The invariance is inconsistent with a chemical origin that involves the thermal fragmentation of natural products or their derivatives. It suggests a reaction process at steady state, in which relative rates of product formation are constant. A mechanism is proposed in which the four isoheptanes are formed pairwise and sequentially through two intermediates in a catalytic process that operates at steady state. 13 references, 3 figures, 1 table.

  15. Indigenous Precambrian petroleum revisited

    SciTech Connect

    Murray, G.E.; Kaczor, M.J.; McArthur, R.E.

    1980-10-01

    Irrefutable evidence of fossil remains from Precambrian sediments and proved petroleum reserves in upper Proterozoic (Riphean-Vendian) strata of the Irkutsk basin, USSR, suggest that unmetamorphosed Precambrian sedimentary rocks should be a focus for hydrocarbon exploration. Since 1965, a dramatic increase in publications which document worldwide occurrences of Precambrian life forms discloses that, by the end of the Proterozoic, organic evolution had produced diversified assemblages of relatively highly developed macroorganisms and microorganisms. Some of these organisms have generated crude oil in the Nonesuch Shale of northern Michigan and kerogen in stromatolitic carbonate rocks in Africa Kerogen has been extracted from approx. 2300-m.y. old Transvaal (Africa) stromatolitic limestone containing coccoid and complex filamentous cyanophytes. Also, aromatic and aliphatic hydrocarbons have been obtained from the approx. 2800-m.y. old Bulawayan stromatolitic limestone of Rhodesia. Additional evidence indicates that commercial reserves of petroleum from Precambrian strata are possible. An oil discovery in Lower Cambrian rocks in 1962, at Markovo in the Irkutsk basin of the Siberian platform area, led to four noncommercial and eight commercial fields producing from Lower Cambrian and Upper Proterozoic strata.

  16. International petroleum statistics report

    SciTech Connect

    1997-05-01

    The International Petroleum Statistics Report is a monthly publication that provides current international oil data. This report is published for the use of Members of Congress, Federal agencies, State agencies, industry, and the general public. Publication of this report is in keeping with responsibilities given the Energy Information Administration in Public Law 95-91. The International Petroleum Statistics Report presents data on international oil production, demand, imports, and stocks. The report has four sections. Section 1 contains time series data on world oil production, and on oil demand and stocks in the Organization for Economic Cooperation and Development (OECD). This section contains annual data beginning in 1985, and monthly data for the most recent two years. Section 2 presents an oil supply/demand balance for the world. This balance is presented in quarterly intervals for the most recent two years. Section 3 presents data on oil imports by OECD countries. This section contains annual data for the most recent year, quarterly data for the most recent two quarters, and monthly data for the most recent twelve months. Section 4 presents annual time series data on world oil production and oil stocks, demand, and trade in OECD countries. World oil production and OECD demand data are for the years 1970 through 1995; OECD stocks from 1973 through 1995; and OECD trade from 1985 through 1995.

  17. Weathering of a petroleum spill in a tropical mangrove swamp

    SciTech Connect

    Fisher, S.J.; Alexander, R.; Kagi, R.I.

    1996-12-31

    In August 1987, an indeterminate amount of petroleum condensate was released from a buried pipe leading to contamination of a tropical mangrove swamp surrounding a tidal creek in North Western Australia. Since no bioremediation was attempted at this site, we have monitored the natural weathering of the condensate by detailed analysis of the petroleum hydrocarbons extracted from sediment samples collected on 11 occasions over a 3 year period.

  18. Job Prospects for Petroleum Engineers.

    ERIC Educational Resources Information Center

    Basta, Nicholas

    1988-01-01

    Describes petroleum engineering as one area in industry where job opportunities are few but where the worst of the declines has been seen. Discusses the causes of the decline. Lists several areas where petroleum engineers have found alternatives including environmental projects, water supply projects, and computer applications. (CW)

  19. Petroleum occurrences and plate tectonics

    SciTech Connect

    Olenin, V.B.; Sokolov, B.A.

    1983-01-01

    This paper analyzes the mechanisms of petroleum formation and petroleum accumulation proposed in recent years by some Russian and foreign investigators from the viewpoint of the new global or plate tectonics. On the basis of discussion and the facts, the authors conclude that the mechanisms proposed are in contradiction to reality and their use in practical application is at least premature.

  20. Petroleum industry assists hurricane relief

    SciTech Connect

    Not Available

    1992-09-14

    This paper reports that the petroleum industry is aiding victims of last month's Hurricane Andrew with cash, clothing, food, water, and other supplies. Cash contributions announced as of last week totaled more than $2.7 million for distribution in South Florida and South Louisiana. Petroleum industry employees were collecting relief items such as bottled water and diapers for distribution in those areas.

  1. Site characterization and petroleum hydrocarbon plume mapping

    SciTech Connect

    Ravishankar, K.

    1996-12-31

    This paper presents a case study of site characterization and hydrocarbon contamination plume mapping/delineation in a gas processing plant in southern Mexico. The paper describes innovative and cost-effective use of passive (non-intrusive) and active (intrusive) techniques, including the use of compound-specific analytical methods for site characterization. The techniques used, on a demonstrative basis, include geophysical, geochemical, and borehole drilling. Geochemical techniques used to delineate the horizontal extent of hydrocarbon contamination at the site include soil gas surveys. The borehole drilling technique used to assess the vertical extent of contamination and confirm geophysical and geochemical data combines conventional hollow-stem auguring with direct push-probe using Geoprobe. Compound-specific analytical methods, such as hydrocarbon fingerprinting and a modified method for gasoline range organics, demonstrate the inherent merit and need for such analyses to properly characterize a site, while revealing the limitations of noncompound-specific total petroleum hydrocarbon analysis. The results indicate that the techniques used in tandem can properly delineate the nature and extent of contamination at a site; often supplement or complement data, while reducing the risk of errors and omissions during the assessment phase; and provide data constructively to focus site-specific remediation efforts. 7 figs.

  2. Petroleum marketing monthly, March 1995

    SciTech Connect

    1995-03-10

    This report for March 1995, provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Monthly. A glossary is included.

  3. Managing Analysis Models in the Design Process

    NASA Technical Reports Server (NTRS)

    Briggs, Clark

    2006-01-01

    Design of large, complex space systems depends on significant model-based support for exploration of the design space. Integrated models predict system performance in mission-relevant terms given design descriptions and multiple physics-based numerical models. Both the design activities and the modeling activities warrant explicit process definitions and active process management to protect the project from excessive risk. Software and systems engineering processes have been formalized and similar formal process activities are under development for design engineering and integrated modeling. JPL is establishing a modeling process to define development and application of such system-level models.

  4. Articulating the Resources for Business Process Analysis and Design

    ERIC Educational Resources Information Center

    Jin, Yulong

    2012-01-01

    Effective process analysis and modeling are important phases of the business process management lifecycle. When many activities and multiple resources are involved, it is very difficult to build a correct business process specification. This dissertation provides a resource perspective of business processes. It aims at a better process analysis…

  5. Petroleum effects on neural systems in marine organisms. Progress report, 1 August 1979-14 April 1980

    SciTech Connect

    Not Available

    1980-01-01

    Progress is reported in the following areas: (1) petroleum effects on chemosensory systems in the kelp crab, Pugettia producta, and the California spiny lobster, Panulirus interruptus; (2) chemosensory bradycardia in the spiny lobster; (3) petroleum effects on epithelial potentials in the coelenterate Tubularia; (4) petroleum effects on bioluminescence in the marine dinoflagellate, Pyrocystis fusiformis; and (5) analysis of petroleum for neurological testing on crustacea. (ACR)

  6. [Petroleum substances--human health hazards. I. Classification of petroleum substances on the list of dangerous substances and assessment of existing hazards].

    PubMed

    Konieczko, Katarzyna

    2006-01-01

    Complex products derived from petroleum are widely used as fuels, greases, solvents, and intermediates in many branches of industry. Petroleum exposure-related human health hazards, observed in occupationally exposed people and in the general population, are a serious sanitary problem. Complex and variable composition of individual petroleum products makes the actual assessment of human health hazards difficult. Potential hazards, and resulting classification of individual petroleum substance groups, are discussed in the presented work. This should prove to be helpful to work safety and hygiene services as well as to supervising institutions, mainly the sanitary inspection, in a proper assessment of the hazards, and consequently in taking appropriate preventive actions. In Part I., general issues concerning the hazard assessment and legal aspects of petroleum substances classification are presented. In Part. II., individual groups of petroleum substances are discussed with respect to health hazards, resulting from both physicochemical properties and toxicity, and their classification based on this analysis is suggested. PMID:17133920

  7. Analysis of energy utilization in spinach processing

    SciTech Connect

    Chhinnan, M.S.; Singh, R.P.; Pedersen, L.D.; Carroad, P.A.; Rose, W.W.; Jacob, N.L.

    1980-03-01

    The equipment and methods used to monitor the electrical and thermal energy consumed in various unit operations in a spinach processing plant are described and the results of a processing plant energy audit are presented. It is concluded that it requires 6.5 MJ of natural gas and fuel oil and 0.072 MJ of electric power to process one kg of new spinach; the energy intensive operations in spinach processing are associated with exhaust boxes, blanchers, and retorts; uniform product flow through the canning line is essential to energy conservation; and design improvements are needed for the blancher, exhaust box, and retort. (LCL)

  8. Could petroleum biodegradation be a joint achievement of aerobic and anaerobic microrganisms in deep sea reservoirs?

    PubMed Central

    2011-01-01

    Several studies suggest that petroleum biodegradation can be achieved by either aerobic or anaerobic microorganisms, depending on oxygen input or other electron acceptors and appropriate nutrients. Evidence from in vitro experiments with samples of petroleum formation water and oils from Pampo Field indicate that petroleum biodegradation is more likely to be a joint achievement of both aerobic and anaerobic bacterial consortium, refining our previous observations of aerobic degradation. The aerobic consortium depleted, in decreasing order, hydrocarbons > hopanes > steranes > tricyclic terpanes while the anaerobic consortium depleted hydrocarbons > steranes > hopanes > tricyclic terpanes. The oxygen content of the mixed consortia was measured from time to time revealing alternating periods of microaerobicity (O2 ~0.8 mg.L-1) and of aerobicity (O2~6.0 mg.L-1). In this experiment, the petroleum biodegradation changed from time to time, alternating periods of biodegradation similar to the aerobic process and periods of biodegradation similar to the anaerobic process. The consortia showed preferences for metabolizing hydrocarbons > hopanes > steranes > tricyclic terpanes during a 90-day period, after which this trend changed and steranes were more biodegraded than hopanes. The analysis of aerobic oil degrading microbiota by the 16S rRNA gene clone library detected the presence of Bacillus, Brevibacterium, Mesorhizobium and Achromobacter, and the analysis of the anaerobic oil degrading microbiota using the same technique detected the presence of Bacillus and Acinetobacter (facultative strains). In the mixed consortia Stenotrophomonas, Brevibacterium, Bacillus, Rhizobium, Achromobacter and 5% uncultured bacteria were detected. This is certainly a new contribution to the study of reservoir biodegradation processes, combining two of the more important accepted hypotheses. PMID:22196374

  9. Could petroleum biodegradation be a joint achievement of aerobic and anaerobic microrganisms in deep sea reservoirs?

    PubMed

    da Cruz, Georgiana F; de Vasconcellos, Suzan P; Angolini, Célio Ff; Dellagnezze, Bruna M; Garcia, Isabel Ns; de Oliveira, Valéria M; Dos Santos Neto, Eugenio V; Marsaioli, Anita J

    2011-12-23

    Several studies suggest that petroleum biodegradation can be achieved by either aerobic or anaerobic microorganisms, depending on oxygen input or other electron acceptors and appropriate nutrients. Evidence from in vitro experiments with samples of petroleum formation water and oils from Pampo Field indicate that petroleum biodegradation is more likely to be a joint achievement of both aerobic and anaerobic bacterial consortium, refining our previous observations of aerobic degradation. The aerobic consortium depleted, in decreasing order, hydrocarbons > hopanes > steranes > tricyclic terpanes while the anaerobic consortium depleted hydrocarbons > steranes > hopanes > tricyclic terpanes. The oxygen content of the mixed consortia was measured from time to time revealing alternating periods of microaerobicity (O2 ~0.8 mg.L-1) and of aerobicity (O2~6.0 mg.L-1). In this experiment, the petroleum biodegradation changed from time to time, alternating periods of biodegradation similar to the aerobic process and periods of biodegradation similar to the anaerobic process. The consortia showed preferences for metabolizing hydrocarbons > hopanes > steranes > tricyclic terpanes during a 90-day period, after which this trend changed and steranes were more biodegraded than hopanes. The analysis of aerobic oil degrading microbiota by the 16S rRNA gene clone library detected the presence of Bacillus, Brevibacterium, Mesorhizobium and Achromobacter, and the analysis of the anaerobic oil degrading microbiota using the same technique detected the presence of Bacillus and Acinetobacter (facultative strains). In the mixed consortia Stenotrophomonas, Brevibacterium, Bacillus, Rhizobium, Achromobacter and 5% uncultured bacteria were detected. This is certainly a new contribution to the study of reservoir biodegradation processes, combining two of the more important accepted hypotheses.

  10. Potential displacement of petroleum imports by solar energy technologies

    NASA Astrophysics Data System (ADS)

    Deleon, P.; Jackson, B. L.; McNown, R. F.; Mahrenholz, G. J.

    1980-05-01

    The United States currently imports close to half of its petroleum requirements. The economic, social, and political costs of a foreign oil dependency are discussed. Development of alternative, domestic energy sources, such as solar energy technologies, which can displace foreign petroleum is discussed. It is estimated that by the year 2000, solar energy technologies can displace 3.6 quads of petroleum. This figure includes solar energy applications in utilities, industrial and agricultural process heat, and transportation. The estimate can be treated as a lower bound; if the United States were to achieve the proposed goal of 20 quads by 2000, the amount of displaced oil probably would be greater. Although all the displaced oil would not be imported, the reduction in imported petroleum would relieve many of the conditions that increase the present cost of foreign oil to the American consumer.

  11. Use of absorption spectroscopy for refined petroleum product discrimination

    NASA Astrophysics Data System (ADS)

    Short, Michael

    1991-07-01

    On-line discrimination between arbitrary petroleum products is necessary for optimal control of petroleum refinery and pipeline operation and process control involving petroleum distillates. There are a number of techniques by which petroleum products can be distinguished from one another. Among these, optical measurements offer fast, non-intrusive, real-time characterization. The application examined here involves optically monitoring the interface between dissimilar batches of fluids in a gasoline pipeline. After examination of near- infrared and mid-infrared absorption spectroscopy and Raman spectroscopy, Fourier transform mid-infrared (FTIR) spectroscopy was chosen as the best candidate for implementation. On- line FTIR data is presented, verifying the applicability of the technique for batch interface detection.

  12. The US petroleum refining industry in the 1980's

    SciTech Connect

    Not Available

    1990-10-11

    As part of the EIA program on petroleum, The US Petroleum Refining Industry in the 1980's, presents a historical analysis of the changes that took place in the US petroleum refining industry during the 1980's. It is intended to be of interest to analysts in the petroleum industry, state and federal government officials, Congress, and the general public. The report consists of six chapters and four appendices. Included is a detailed description of the major events and factors that affected the domestic refining industry during this period. Some of the changes that took place in the 1980's are the result of events that started in the 1970's. The impact of these events on US refinery configuration, operations, economics, and company ownership are examined. 23 figs., 11 tabs.

  13. Cutting Forces Analysis in Whirling Process

    NASA Astrophysics Data System (ADS)

    Son, Jae Hwan; Han, Chang Woo; Kim, Sun Il; Jung, Hee Chul; Lee, Young Moon

    Whirling is a cutting process in which a series of cutting edges remove material by turning over the rotating workpiece. In this process, the whirling ring with a number of cutting teeth combined with the rotation and advancement of workpiece, produces pitches of worm. Mechanics of chip formation of the process, however, has not been fully estabilished. To estimate the cutting force during the process, the kinematics and the maximum undeformed chip thickness to be removed by each cutting edge should be thoroughly analyzed. In this study, using the recently developed model of undeformed chip thickness and the DEFORM software, cutting forces of the whirling process are estimated. The effects of cutting forces on tool are analyzed using the ADAMS software. The validity of the simulations has been verified with a series of cutting experiments.

  14. Bioleaching of nickel from spent petroleum catalyst using Acidithiobacillus thiooxidans DSM- 11478.

    PubMed

    Sharma, Mohita; Bisht, Varsha; Singh, Bina; Jain, Pratiksha; Mandal, Ajoy K; Lal, Banwari; Sarma, Priyangshu M

    2015-06-01

    The present work deals with optimization of culture conditions and process parameters for bioleaching of spent petroleum catalyst collected from a petroleum refinery. The efficacy of Ni bioleaching from spent petroleum catalyst was determined using pure culture of Acidithiobacillus thiooxidans DSM- 11478. The culture conditions of pH, temperature and headspace volume to media volume ratio were optimized. EDX analysis was done to confirm the presence of Ni in the spent catalyst after roasting it to decoke its surface. The optimum temperature for A. thiooxidans DSM-11478 growth was found to be 32 degrees C. The enhanced recovery of nickel at very low pH was attributed to the higher acidic strength of sulfuric acid produced in the culture medium by the bacterium. During the bioleaching process, 89% of the Ni present in the catalyst waste could be successfully recovered in optimized conditions. This environment friendly bioleaching process proved efficient than the chemical method. Taking leads from the lab scale results, bioleaching in larger volumes (1, 5 and 10 L) was also performed to provide guidelines for taking up this technology for in situ industrial waste management.

  15. Bioleaching of nickel from spent petroleum catalyst using Acidithiobacillus thiooxidans DSM- 11478.

    PubMed

    Sharma, Mohita; Bisht, Varsha; Singh, Bina; Jain, Pratiksha; Mandal, Ajoy K; Lal, Banwari; Sarma, Priyangshu M

    2015-06-01

    The present work deals with optimization of culture conditions and process parameters for bioleaching of spent petroleum catalyst collected from a petroleum refinery. The efficacy of Ni bioleaching from spent petroleum catalyst was determined using pure culture of Acidithiobacillus thiooxidans DSM- 11478. The culture conditions of pH, temperature and headspace volume to media volume ratio were optimized. EDX analysis was done to confirm the presence of Ni in the spent catalyst after roasting it to decoke its surface. The optimum temperature for A. thiooxidans DSM-11478 growth was found to be 32 degrees C. The enhanced recovery of nickel at very low pH was attributed to the higher acidic strength of sulfuric acid produced in the culture medium by the bacterium. During the bioleaching process, 89% of the Ni present in the catalyst waste could be successfully recovered in optimized conditions. This environment friendly bioleaching process proved efficient than the chemical method. Taking leads from the lab scale results, bioleaching in larger volumes (1, 5 and 10 L) was also performed to provide guidelines for taking up this technology for in situ industrial waste management. PMID:26155679

  16. Report to the Congress: Regional petroleum reserves

    NASA Astrophysics Data System (ADS)

    1982-12-01

    Actions taken to determine the benefits and costs of establishing in-region Regional Petroleum Reserves (RPR's) and the extent to which existing analyses reflect DOE's current assessments of US and world supply/demand conditions are discussed. A discussion of sites considered, cost comparisons of RPR and Gulf Coast storage, an SPR distribution capabilities and is continuing system enhancements is given. The SPR Plan of 1977, in its thorough analysis of SPR options, developed a basic program oach which continues to be valid in today's petroleum market. Current assessments indicate that SPR system enhancements, current market strategies, and the removal of prior regulatory barriers will significantly increase the flexibility of the SPR system in providing protection to all regions and noncontiguous areas. The SPR, located in the Gulf Coast salt domes as crude oil, continues to represent the most practical, efficient, and effective means of providing flexibility, security, and low cost energy storage.

  17. Isolation and Characterization of Hydrocarbon-Degrading Yeast Strains from Petroleum Contaminated Industrial Wastewater

    PubMed Central

    Gargouri, Boutheina; Mhiri, Najla; Karray, Fatma; Aloui, Fathi; Sayadi, Sami

    2015-01-01

    Two yeast strains are enriched and isolated from industrial refinery wastewater. These strains were observed for their ability to utilize several classes of petroleum hydrocarbons substrates, such as n-alkanes and aromatic hydrocarbons as a sole carbon source. Phylogenetic analysis based on the D1/D2 variable domain and the ITS-region sequences indicated that strains HC1 and HC4 were members of the genera Candida and Trichosporon, respectively. The mechanism of hydrocarbon uptaking by yeast, Candida, and Trichosporon has been studied by means of the kinetic analysis of hydrocarbons-degrading yeasts growth and substrate assimilation. Biodegradation capacity and biomass quantity were daily measured during twelve days by gravimetric analysis and gas chromatography coupled with mass spectrometry techniques. Removal of n-alkanes indicated a strong ability of hydrocarbon biodegradation by the isolated yeast strains. These two strains grew on long-chain n-alkane, diesel oil, and crude oil but failed to grow on short-chain n-alkane and aromatic hydrocarbons. Growth measurement attributes of the isolates, using n-hexadecane, diesel oil, and crude oil as substrates, showed that strain HC1 had better degradation for hydrocarbon substrates than strain HC4. In conclusion, these yeast strains can be useful for the bioremediation process and decreasing petroleum pollution in wastewater contaminated with petroleum hydrocarbons. PMID:26339653

  18. Isolation and Characterization of Hydrocarbon-Degrading Yeast Strains from Petroleum Contaminated Industrial Wastewater.

    PubMed

    Gargouri, Boutheina; Mhiri, Najla; Karray, Fatma; Aloui, Fathi; Sayadi, Sami

    2015-01-01

    Two yeast strains are enriched and isolated from industrial refinery wastewater. These strains were observed for their ability to utilize several classes of petroleum hydrocarbons substrates, such as n-alkanes and aromatic hydrocarbons as a sole carbon source. Phylogenetic analysis based on the D1/D2 variable domain and the ITS-region sequences indicated that strains HC1 and HC4 were members of the genera Candida and Trichosporon, respectively. The mechanism of hydrocarbon uptaking by yeast, Candida, and Trichosporon has been studied by means of the kinetic analysis of hydrocarbons-degrading yeasts growth and substrate assimilation. Biodegradation capacity and biomass quantity were daily measured during twelve days by gravimetric analysis and gas chromatography coupled with mass spectrometry techniques. Removal of n-alkanes indicated a strong ability of hydrocarbon biodegradation by the isolated yeast strains. These two strains grew on long-chain n-alkane, diesel oil, and crude oil but failed to grow on short-chain n-alkane and aromatic hydrocarbons. Growth measurement attributes of the isolates, using n-hexadecane, diesel oil, and crude oil as substrates, showed that strain HC1 had better degradation for hydrocarbon substrates than strain HC4. In conclusion, these yeast strains can be useful for the bioremediation process and decreasing petroleum pollution in wastewater contaminated with petroleum hydrocarbons.

  19. ATMOS data processing and science analysis methods.

    PubMed

    Norton, R H; Rinsland, C P

    1991-02-01

    The ATMOS (atmospheric trace molecule spectroscopy) instrument, a high speed Fourier transform spectrometer operating in the middle IR (2.2-16 microm), recorded more than 1500 solar spectra at approximately 0.0105-cm(-1) resolution during its first mission onboard the shuttle Challenger in the spring of 1985. These spectra were acquired during high sun conditions for studies of the solar atmosphere and during low sun conditions for studies of the earth's upper atmosphere. This paper describes the steps by which the telemetry data were converted into spectra suitable for analysis, the analysis software and methods developed for the atmospheric and solar studies, and the ATMOS data analysis facility.

  20. Preliminary benefit analysis of biological space processing

    NASA Technical Reports Server (NTRS)

    Perrine, J.

    1976-01-01

    The value of weightlessness in bioprocessing is assessed. The ecomonic benefits are assessed for space processing urokinase and human lymphocytes for treatment of end stage renal disease and thromboembolisms.

  1. Analysis of fingerprints features of infrared spectra of various processed products of Rhizoma Coptidis and their different extracts

    NASA Astrophysics Data System (ADS)

    Xu, Beilei; Zhang, Guijun; Xu, Changhua; Sun, Suqin

    2015-09-01

    Fourier transform infrared spectroscopy (FT-IR) associated with second derivative infrared spectroscopy (SD-IR) and two-dimensional correlation infrared spectroscopy (2D-IR) are employed to analyze various processed products and different extracts of Rhizoma Coptidis. There is a shift of the peak of 1641 cm-1 of raw Rhizoma Coptidis after processed, which drifts to lower wave number. Peaks at 1508, 1387, 1363, 1332, 1274 and 1234 cm-1 barely change in most samples, except an obvious enhancement of these peaks after processed, suggesting that processed Rhizoma Coptidis may have higher content of berberine than raw material, which is corresponding to the results of correlation coefficients analysis. There are some differences in the absorption peaks in the range of 1800-1000 cm-1 in the SD-IR spectra, which have better resolution, of different processed products. 2D-IR spectra, which elevate the resolution further, can present more differences among the products in the range of 1300-800 cm-1 and 1800-1300 cm-1. Analysis of aqueous, ethanol and petroleum ether extracts of various processed products proves that there are distinctive differences of all auto-peaks in shapes and intensities in all of them. With the advantages of high resolution, high speed and convenience, FT-IR combined with 2D-IR can quickly and precisely distinguish various processed products of Rhizoma Coptidis and can be applied to predict the tendency of transformation of the complicated chemical mixture systems under heat perturbation.

  2. Petroleum fingerprinting: Effective identification of petroleum products at contaminated sites

    SciTech Connect

    Uhler, A.D.

    1997-07-01

    A critical issue in many environmental liability cases is the successful identification of the parties responsible for petroleum products that contaminate sites or properties. Identification of these parties is critical for owners of petroleum contaminated sites who are seeking to spread liability by identifying previous owners or operators of nearby properties who may be the source of, and thus be responsible for, the petroleum contamination at these sites. This issue is also critical for these potential defendants who will seek to demonstrate that the petroleum products associated with their activities could not be the source of the contamination in question. Finally, the issue is critical in situations where multiple responsible parties seek to equitably allocate among themselves shares of contamination and associated clean-up costs.

  3. Petroleum marketing monthly, March 1994

    SciTech Connect

    Not Available

    1994-03-22

    The Petroleum Marketing Monthly is designed to give information and statistical data about a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, education institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiner`s acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented.

  4. Petroleum marketing monthly, January 1994

    SciTech Connect

    Not Available

    1994-02-01

    The Petroleum Marketing Monthly (PMM) is designed to give information and statistical data about a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented.

  5. Petroleum marketing monthly, August 1993

    SciTech Connect

    Not Available

    1993-08-10

    The Petroleum Marketing Monthly (PMM) is designed to give information and statistical data about a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented.

  6. Petroleum marketing monthly, April 1994

    SciTech Connect

    Not Available

    1994-04-12

    The Petroleum Marketing Monthly (PMM) is designed to give information and statistical data about a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented.

  7. Petroleum marketing monthly, July 1993

    SciTech Connect

    Not Available

    1993-07-15

    The Petroleum Marketing Monthly (PMM) is designed to give information and statistical data about a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented.

  8. Petroleum marketing monthly, November 1993

    SciTech Connect

    Not Available

    1993-11-09

    The Petroleum Marketing Monthly (PMM) is designed to give information and statistical data about a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed costs of imported crude oil, and the refiner`s acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented.

  9. Petroleum marketing monthly, August 1990

    SciTech Connect

    Not Available

    1990-11-07

    The Petroleum Marketing Monthly (PMM) is designed to give information and statistical data about a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners' acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented. 12 figs., 49 tabs.

  10. Petroleum marketing monthly, February 1994

    SciTech Connect

    Not Available

    1994-02-25

    The Petroleum Marketing Monthly is designed to give information and statistical data about a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiner`s acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented.

  11. Identification of alkyl carbazoles and alkyl benzocarbazoles in Brazilian petroleum derivatives.

    PubMed

    Oliveira, Eniz Conceição; Vaz de Campos, Maria Cecília; Rodrigues, Maria Regina Alves; Pérez, Valéria Flores; Melecchi, Maria Inês Soares; Vale, Maria Goreti Rodrigues; Zini, Cláudia Alcaraz; Caramão, Elina Bastos

    2006-02-10

    Carbozoles are important compounds in crude oils, as they may be used as geochemical tracers, being the major type of nitrogen compounds in petroleum. At the same time, they are regarded as undesirable due to the problems they may cause in the refining process, such as catalyst poisoning, corrosion, gum or color formation in final products. As separation and identification of carbazoles are challenging goals, this work presents a chromatographic method, made of a pre-fractionation on neutral alumina followed by the separation and identification of two classes of carbazoles using FeCl(3)/Chromossorb W and gas chromatograph with mass spectrometer (GC/MS) (SIM-single ion monitoring mode) analysis. For the first time, a series of alkyl carbazoles and alkyl benzocarbazoles were identified in heavy gas oil (HGO) and atmospheric residue of distillation (ARD) obtained from Brazilian petroleum.

  12. 21 CFR 178.3710 - Petroleum wax.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 3 2012-04-01 2012-04-01 false Petroleum wax. 178.3710 Section 178.3710 Food and... and Production Aids § 178.3710 Petroleum wax. Petroleum wax may be safely used as a component of nonfood articles in contact with food, in accordance with the following conditions: (a) Petroleum wax is...

  13. 21 CFR 178.3710 - Petroleum wax.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 3 2013-04-01 2013-04-01 false Petroleum wax. 178.3710 Section 178.3710 Food and... and Production Aids § 178.3710 Petroleum wax. Petroleum wax may be safely used as a component of nonfood articles in contact with food, in accordance with the following conditions: (a) Petroleum wax is...

  14. 21 CFR 178.3710 - Petroleum wax.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 3 2011-04-01 2011-04-01 false Petroleum wax. 178.3710 Section 178.3710 Food and... and Production Aids § 178.3710 Petroleum wax. Petroleum wax may be safely used as a component of nonfood articles in contact with food, in accordance with the following conditions: (a) Petroleum wax is...

  15. 31 CFR 561.319 - Petroleum products.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Petroleum products. 561.319 Section... Definitions § 561.319 Petroleum products. The term petroleum products includes unfinished oils, liquefied petroleum gases, pentanes plus, aviation gasoline, motor gasoline, naphtha-type jet fuel, kerosene-type...

  16. 31 CFR 561.319 - Petroleum products.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Petroleum products. 561.319 Section... Definitions § 561.319 Petroleum products. The term petroleum products includes unfinished oils, liquefied petroleum gases, pentanes plus, aviation gasoline, motor gasoline, naphtha-type jet fuel, kerosene-type...

  17. 21 CFR 178.3710 - Petroleum wax.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 3 2014-04-01 2014-04-01 false Petroleum wax. 178.3710 Section 178.3710 Food and... Petroleum wax. Petroleum wax may be safely used as a component of nonfood articles in contact with food, in accordance with the following conditions: (a) Petroleum wax is a mixture of solid hydrocarbons, paraffinic...

  18. 31 CFR 561.319 - Petroleum products.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Petroleum products. 561.319 Section... Definitions § 561.319 Petroleum products. The term petroleum products includes unfinished oils, liquefied petroleum gases, pentanes plus, aviation gasoline, motor gasoline, naphtha-type jet fuel, kerosene-type...

  19. Stochastic Analysis of Reaction–Diffusion Processes

    PubMed Central

    Hu, Jifeng; Kang, Hye-Won

    2013-01-01

    Reaction and diffusion processes are used to model chemical and biological processes over a wide range of spatial and temporal scales. Several routes to the diffusion process at various levels of description in time and space are discussed and the master equation for spatially discretized systems involving reaction and diffusion is developed. We discuss an estimator for the appropriate compartment size for simulating reaction–diffusion systems and introduce a measure of fluctuations in a discretized system. We then describe a new computational algorithm for implementing a modified Gillespie method for compartmental systems in which reactions are aggregated into equivalence classes and computational cells are searched via an optimized tree structure. Finally, we discuss several examples that illustrate the issues that have to be addressed in general systems. PMID:23719732

  20. Encapsulation Processing and Manufacturing Yield Analysis

    NASA Technical Reports Server (NTRS)

    Willis, P.

    1985-01-01

    Evaluation of the ethyl vinyl acetate (EVA) encapsulation system is presented. This work is part of the materials baseline needed to demonstrate a 30 year module lifetime capability. Process and compound variables are both being studied along with various module materials. Results have shown that EVA should be stored rolled up, and enclosed in a plastic bag to retard loss of peroxide curing agents. The TBEC curing agent has superior shelf life and processing than the earlier Lupersol-101 curing agent. Analytical methods were developed to test for peroxide content, and experimental methodologies were formalized.

  1. 300 Area process trench sediment analysis report

    SciTech Connect

    Zimmerman, M.G.; Kossik, C.D.

    1987-12-01

    This report describes the results of a sampling program for the sediments underlying the Process Trenches serving the 300 Area on the Hanford reservation. These Process Trenches were the subject of a Closure Plan submitted to the Washington State Department of Ecology and to the US Environmental Protection Agency in lieu of a Part B permit application on November 8, 1985. The closure plan described a proposed sampling plan for the underlying sediments and potential remedial actions to be determined by the sample analyses results. The results and proposed remedial action plan are presented and discussed in this report. 50 refs., 6 figs., 8 tabs.

  2. Geochemistry of Dissolved Organic Matter in a Spatially Highly Resolved Groundwater Petroleum Hydrocarbon Plume Cross-Section.

    PubMed

    Dvorski, Sabine E-M; Gonsior, Michael; Hertkorn, Norbert; Uhl, Jenny; Müller, Hubert; Griebler, Christian; Schmitt-Kopplin, Philippe

    2016-06-01

    At numerous groundwater sites worldwide, natural dissolved organic matter (DOM) is quantitatively complemented with petroleum hydrocarbons. To date, research has been focused almost exclusively on the contaminants, but detailed insights of the interaction of contaminant biodegradation, dominant redox processes, and interactions with natural DOM are missing. This study linked on-site high resolution spatial sampling of groundwater with high resolution molecular characterization of DOM and its relation to groundwater geochemistry across a petroleum hydrocarbon plume cross-section. Electrospray- and atmospheric pressure photoionization (ESI, APPI) ultrahigh resolution mass spectrometry (FT-ICR-MS) revealed a strong interaction between DOM and reactive sulfur species linked to microbial sulfate reduction, i.e., the key redox process involved in contaminant biodegradation. Excitation emission matrix (EEM) fluorescence spectroscopy in combination with Parallel Factor Analysis (PARAFAC) modeling attributed DOM samples to specific contamination traits. Nuclear magnetic resonance (NMR) spectroscopy evaluated the aromatic compounds and their degradation products in samples influenced by the petroleum contamination and its biodegradation. Our orthogonal high resolution analytical approach enabled a comprehensive molecular level understanding of the DOM with respect to in situ petroleum hydrocarbon biodegradation and microbial sulfate reduction. The role of natural DOM as potential cosubstrate and detoxification reactant may improve future bioremediation strategies. PMID:27152868

  3. Geochemistry of Dissolved Organic Matter in a Spatially Highly Resolved Groundwater Petroleum Hydrocarbon Plume Cross-Section.

    PubMed

    Dvorski, Sabine E-M; Gonsior, Michael; Hertkorn, Norbert; Uhl, Jenny; Müller, Hubert; Griebler, Christian; Schmitt-Kopplin, Philippe

    2016-06-01

    At numerous groundwater sites worldwide, natural dissolved organic matter (DOM) is quantitatively complemented with petroleum hydrocarbons. To date, research has been focused almost exclusively on the contaminants, but detailed insights of the interaction of contaminant biodegradation, dominant redox processes, and interactions with natural DOM are missing. This study linked on-site high resolution spatial sampling of groundwater with high resolution molecular characterization of DOM and its relation to groundwater geochemistry across a petroleum hydrocarbon plume cross-section. Electrospray- and atmospheric pressure photoionization (ESI, APPI) ultrahigh resolution mass spectrometry (FT-ICR-MS) revealed a strong interaction between DOM and reactive sulfur species linked to microbial sulfate reduction, i.e., the key redox process involved in contaminant biodegradation. Excitation emission matrix (EEM) fluorescence spectroscopy in combination with Parallel Factor Analysis (PARAFAC) modeling attributed DOM samples to specific contamination traits. Nuclear magnetic resonance (NMR) spectroscopy evaluated the aromatic compounds and their degradation products in samples influenced by the petroleum contamination and its biodegradation. Our orthogonal high resolution analytical approach enabled a comprehensive molecular level understanding of the DOM with respect to in situ petroleum hydrocarbon biodegradation and microbial sulfate reduction. The role of natural DOM as potential cosubstrate and detoxification reactant may improve future bioremediation strategies.

  4. Simplified Processing Method for Meter Data Analysis

    SciTech Connect

    Fowler, Kimberly M.; Colotelo, Alison H. A.; Downs, Janelle L.; Ham, Kenneth D.; Henderson, Jordan W.; Montgomery, Sadie A.; Vernon, Christopher R.; Parker, Steven A.

    2015-11-01

    Simple/Quick metered data processing method that can be used for Army Metered Data Management System (MDMS) and Logistics Innovation Agency data, but may also be useful for other large data sets. Intended for large data sets when analyst has little information about the buildings.

  5. Dynamic Process Simulation for Analysis and Design.

    ERIC Educational Resources Information Center

    Nuttall, Herbert E., Jr.; Himmelblau, David M.

    A computer program for the simulation of complex continuous process in real-time in an interactive mode is described. The program is user oriented, flexible, and provides both numerical and graphic output. The program has been used in classroom teaching and computer aided design. Typical input and output are illustrated for a sample problem to…

  6. SPAN - Terminal sterilization process analysis program

    NASA Technical Reports Server (NTRS)

    1969-01-01

    Computer program, SPAN, measures the dry heat thermal sterilization process applied to a planetary capsule and calculates the time required for heat application, steady state conditions, and cooling. The program is based on the logarithmic survival of micro-organisms. Temperature profiles must be input on tape.

  7. SPAN C - Terminal sterilization process analysis program

    NASA Technical Reports Server (NTRS)

    1969-01-01

    Computer program, SPAN-C, measures the dry heat thermal sterilization process applied to a planetary capsule and calculates the time required for heat application, steady state conditions, and cooling. The program is based on the logarithmic survival of micro-organisms. Temperature profiles must be input on cards.

  8. Process Analysis of Industrial Shadow Experiences.

    ERIC Educational Resources Information Center

    Kelly, Eugene W.; Moore, Patsy R.

    1979-01-01

    Describes a career awareness program in which focused shadow experiences with General Electric employees are a key element. For two years these shadow experiences were systematically observed and analyzed to clarify actual process elements in the experiences, and to assess their effectiveness in achieving shadow experience objectives. (Author)

  9. Agriculture Products Processing. Occupational Competency Analysis Profile.

    ERIC Educational Resources Information Center

    Ohio State Univ., Columbus. Vocational Instructional Materials Lab.

    This Occupational Competency Analysis Profile (OCAP) contains a competency list verified by expert workers and developed through a modified DACUM (Developing a Curriculum) involving business, industry, labor, and community agency representatives from Ohio. This OCAP identifies the occupational, academic, and employability skills (competencies)…

  10. Biodegradation of petroleum sludge and petroleum polluted soil by a bacterial consortium: a laboratory study.

    PubMed

    Gojgic-Cvijovic, G D; Milic, J S; Solevic, T M; Beskoski, V P; Ilic, M V; Djokic, L S; Narancic, T M; Vrvic, M M

    2012-02-01

    This article presents a study of the efficiency and degradation pattern of samples of petroleum sludge and polluted sandy soil from an oil refinery. A bacterial consortium, consisting of strains from the genera Pseudomonas, Achromobacter, Bacillus and Micromonospora, was isolated from a petroleum sludge sample and characterized. The addition of nitrogen and phosphorus nutrients and a chemical surfactant to both the samples and bioaugmentation to the soil sample were applied under laboratory conditions. The extent of biodegradation was monitored by the gravimetric method and analysis of the residual oil by gas chromatography. Over a 12-week experiment, the achieved degree of TPH (total petroleum hydrocarbon) degradation amounted to 82-88% in the petroleum sludge and 86-91% in the polluted soil. Gas chromatography-mass spectrometry was utilized to determine the biodegradability and degradation rates of n-alkanes, isoprenoids, steranes, diasteranes and terpanes. Complete degradation of the n-alkanes and isoprenoids fractions occurred in both the samples. In addition, the intensities of the peaks corresponding to tricyclic terpenes and homohopanes were decreased, while significant changes were also observed in the distribution of diasteranes and steranes.

  11. Diterpenoid tetracyclic hydrocarbons of petroleum

    SciTech Connect

    Vorob'eva, N.S.; Zemskova, Z.K.; Pekh, T.I.; Petrov, A.A.

    1987-08-01

    Diterpenoid hydrocarbons are fairly widespread in various caustobioliths. However, if petroleums contain mainly acyclic diterpenoids (phytane, pristane and norpristane), cyclic diterpaenes such as fichtelite, pimarane, iosene (kaurane) and hibbane are often found in hydrocarbons isolated from coal and shale. Recent advances in the chemistry of diterpenoids isolated from caustobioliths, are described in a separate paper. Much less is known about petroleum polycyclic diterpenoid hydrocarbons, particularly those with four saturated rings. A series of tetracyclic hydrocarbons C/sub 19/H/sub 32/ (molar mass 260), found in a number of light petroleums and gas condensates from the Jura deposits of Central Kara-Kum (Turkmen S.S.R.), are examined here. These hydrocarbons are present in petroleums and condensates from the Davaly, Erden, Ortakak, Southern Beuideshik deposits, they are always identical and occur in the same ratios. The composition of the tretracyclanes isolated from the Ortakak gas condensates (well 17) will be examined in detail.

  12. The principles of radiation-chemical technology of refining the petroleum residues

    NASA Astrophysics Data System (ADS)

    Mustafaev, I.; Gulieva, N.

    1995-09-01

    The results of analysis of the scientific basises of radiationthermal refining of heavy petroleum fractions are presented. It is shown, that 71% of fuel oil are turned into gasoline fraction and diesel fuel at the absorbed radiation dose D=I kW h/ton and temperature T=430 C. The presented comparative technical-economic analysis shows, that combined radiation-thermal treatment has economic effect wich is more than 10% above than effect in catalytic process of refining fuel-oil.

  13. Processing Cost Analysis for Biomass Feedstocks

    SciTech Connect

    Badger, P.C.

    2002-11-20

    The receiving, handling, storing, and processing of woody biomass feedstocks is an overlooked component of biopower systems. The purpose of this study was twofold: (1) to identify and characterize all the receiving, handling, storing, and processing steps required to make woody biomass feedstocks suitable for use in direct combustion and gasification applications, including small modular biopower (SMB) systems, and (2) to estimate the capital and operating costs at each step. Since biopower applications can be varied, a number of conversion systems and feedstocks required evaluation. In addition to limiting this study to woody biomass feedstocks, the boundaries of this study were from the power plant gate to the feedstock entry point into the conversion device. Although some power plants are sited at a source of wood waste fuel, it was assumed for this study that all wood waste would be brought to the power plant site. This study was also confined to the following three feedstocks (1) forest residues, (2) industrial mill residues, and (3) urban wood residues. Additionally, the study was confined to grate, suspension, and fluidized bed direct combustion systems; gasification systems; and SMB conversion systems. Since scale can play an important role in types of equipment, operational requirements, and capital and operational costs, this study examined these factors for the following direct combustion and gasification system size ranges: 50, 20, 5, and 1 MWe. The scope of the study also included: Specific operational issues associated with specific feedstocks (e.g., bark and problems with bridging); Opportunities for reducing handling, storage, and processing costs; How environmental restrictions can affect handling and processing costs (e.g., noise, commingling of treated wood or non-wood materials, emissions, and runoff); and Feedstock quality issues and/or requirements (e.g., moisture, particle size, presence of non-wood materials). The study found that over the

  14. Comparison of 14C ages of hydrothermal petroleums

    USGS Publications Warehouse

    Simoneit, B.R.T.; Kvenvolden, K.A.

    1994-01-01

    In order to set limits on the time frame of formation of hydrothermal petroleum, we have obtained 14C ages on samples from three diverse regions; Gulf of California (Guaymas Basin), Northeast Pacific Ocean (Escanaba Trough and Middle Valley), and the East African Rift (Tanganyika Trough). The results date the source of carbon and therefore provide maximum ages for the formation and emplacement of the hydrothermal petroleums. The youngest petroleum occurs iin the Souther Trough of Guaymas Basin (3200-6600 yr, mean 4692 yr); in the Northern Trough the petroleum is slightly older (7400 yr). Significantly older hydrothermal petroleum occurs in Escanaba Trough (17,000 yr) and Middle Valley (29,000 yr). A continental example from the East African Rift has an age of 25,000 yr, comparable to the ages observed in the oceanic samples from the Northeast Pacific Ocean. These ages affirm that hydrothermal petroleum formation is a very rapid process and took place some time between the latest Pleistocene and the present in these active hydrothermal systems. ?? 1994.

  15. Aerobic degradation of petroleum refinery wastewater in sequential batch reactor.

    PubMed

    Thakur, Chandrakant; Srivastava, Vimal C; Mall, Indra D

    2014-01-01

    The aim of the present work was to study the effect of various parameters affecting the treatment of raw petroleum refinery wastewater (PRW) having chemical oxygen demand (COD) of 350 mg L(-1) and total organic carbon (TOC) of 70 mg L(-1) in sequential batch reactor (SBR). Effect of hydraulic retention time (HRT) was studied in instantaneous fill condition. Maximum COD and TOC removal efficiencies were found to be 80% and 84%, respectively, for fill phase of 2 h and react phase of 2 h with fraction of SBR being filled with raw PRW in each cycle being 0.4. Effect of parameters was studied in terms of settling characteristic of treated slurry. Kinetics of treatment process has been studied. FTIR and UV-visible analysis of PRW before and after treatment have been performed so as to understand the degradation mechanism.

  16. Strategic Petroleum Reserve quarterly report

    SciTech Connect

    Not Available

    1992-08-15

    The Strategic Petroleum Reserve (SPR) was created pursuant to the Energy Policy and Conservation Act (EPCA) Public Law 94-163, approved on December 22, 1975, and extended in July 1985, June 1989, March 1990, and September 1990, to reduce the impact of disroptions in petroleum supplies and to carry out obligations of the United States under the Agreement on an International Energy Program. The Strategic Petroleum Reserve Quarterly Report is submitted in accordance with section 165(b) of the Energy Policy and Conservation Act, as amended, which requires that the Secretary of Energy submit quarterly reports to Congress on activities undertaken with respect to the Strategic Petroleum Reserve. Since the Strategic Petroleum Reserve crude oil storage facilities program for the 750 minion barrels was completed in 1991, this August 15, 1992, Strategic Petroleum Reserve Quarterly Report focuses on activities related primarily to the storage facilities status, oil acquisition, budget, and cost of the Reserve during the period April 1, 1992, through June 30, 1992.

  17. Modeling and Simulation of Petroleum Coke Calcination in Pot Calciner Using Two-Fluid Model

    NASA Astrophysics Data System (ADS)

    Xiao, Jin; Huang, Jindi; Zhong, Qifan; Zhang, Hongliang; Li, Jie

    2016-02-01

    The aim of this work was to establish a mathematical model for the analysis of calcining process of petroleum coke in a 24-pot calciner via computational fluid dynamics (CFD) numerical simulation method. The model can be divided into two main parts (1) heterogeneous reacting flow of petroleum coke calcination in the pot was simulated using a two-fluid model approach where the gas and solid phase are treated as a continuous phases; and (2) the standard turbulence equations combined with the finite rate/eddy-dissipation combustion model and discrete ordinates model were solved for the turbulent gas reacting flow in the flue. The model of the calcining process was implemented in ANSYS Fluent 15.0 (commercial CFD software) and validated by industrial production data. After the validation research, the model has been applied to inspect the distribution features of the temperature field in the furnace, the concentration field of residual moisture and volatiles in the petroleum coke, and the vector velocity field of gas and solid phases. This research can provide a theoretical basis for optimizing the structure and improving the automatic control level of a pot calciner.

  18. Energy analysis of thermal, chemical, and metallurgical processes

    SciTech Connect

    Szargut, J.; Morris, D.R.; Steward, F.R.

    1988-01-01

    This book consists of the following chapters: The exergy concept and exergy losses; Calculation of exergy; Physical and chemical exergy of typical substances; Exergy analysis of typical thermal and chemical processes; Cumulative exergy consumption and cumulative degree of perfection; Reduction of external exergy losses; Exergy analysis of major thermal and chemical processes; Thermoeconomic applications of exergy; and Ecological applications of exergy.

  19. Negotiation Process Analysis: A Research and Training Tool.

    ERIC Educational Resources Information Center

    Williams, Timothy

    This paper proposes the use of interaction process analysis to study negotiation behaviors. Following a review of current literature in the field, the paper presents a theoretical framework for the analysis of both labor/management and social negotiation processes. Central to the framework described are two systems of activities that together…

  20. International petroleum statistics report

    SciTech Connect

    1996-05-01

    The International Petroleum Statistics Report presents data on international oil production, demand, imports, exports, and stocks. The report has four sections. Section 1 contains time series data on world oil production, and on oil demand and stocks in the Organization for Economic Cooperation and Development (OECD). This section contains annual data beginning in 1985, and monthly data for the most recent two years. Section 2 presents an oil supply/demand balance for the world. This balance is presented in quarterly intervals for the most recent two years. Section 3 presents data on oil imports by OECD countries. This section contains annual data for the most recent year, quarterly data for the most recent two quarters, and monthly data for the most recent twelve months. Section 4 presents annual time series data on world oil production and oil stocks, demand, and trade in OECD countries. World oil production and OECD demand data are for the years 1970 through 1995; OECD stocks from 1973 through 1995; and OECD trade from 1084 through 1994.