Sulfur isotope fractionation between fluid and andesitic melt: An experimental study

USGS Publications Warehouse

Fiege, Adrian; Holtz, François; Shimizu, Nobumichi; Mandeville, Charles W.; Behrens, Harald; Knipping, Jaayke L.

2014-01-01

Glasses produced from decompression experiments conducted by Fiege et al. (2014a) were used to investigate the fractionation of sulfur isotopes between fluid and andesitic melt upon magma degassing. Starting materials were synthetic glasses with a composition close to a Krakatau dacitic andesite. The glasses contained 4.55–7.95 wt% H2O, ∼140 to 2700 ppm sulfur (S), and 0–1000 ppm chlorine (Cl). The experiments were carried out in internally heated pressure vessels (IHPV) at 1030 °C and oxygen fugacities (fO2) ranging from QFM+0.8 log units up to QFM+4.2 log units (QFM: quartz–fayalite–magnetite buffer). The decompression experiments were conducted by releasing pressure (P) continuously from ∼400 MPa to final P of 150, 100, 70 and 30 MPa. The decompression rate (r) ranged from 0.01 to 0.17 MPa/s. The samples were annealed for 0–72 h (annealing time, tA) at the final P and quenched rapidly from 1030 °C to room temperature (T).The decompression led to the formation of a S-bearing aqueous fluid phase due to the relatively large fluid–melt partitioning coefficients of S. Secondary ion mass spectrometry (SIMS) was used to determine the isotopic composition of the glasses before and after decompression. Mass balance calculations were applied to estimate the gas–melt S isotope fractionation factor αg-m.No detectable effect of r and tA on αg-m was observed. However, SIMS data revealed a remarkable increase of αg-m from ∼0.9985 ± 0.0007 at >QFM+3 to ∼1.0042 ± 0.0042 at ∼QFM+1. Noteworthy, the isotopic fractionation at reducing conditions was about an order of magnitude larger than predicted by previous works. Based on our experimental results and on previous findings for S speciation in fluid and silicate melt a new model predicting the effect of fO2 on αg-m (or Δ34Sg–m) in andesitic systems at 1030 °C is proposed. Our experimental results as well as our modeling are of high importance for the interpretation of S isotope

Eruption cycles in a basaltic andesite system: insights from numerical modeling

NASA Astrophysics Data System (ADS)

Smekens, J. F.; Clarke, A. B.; De'Michieli Vitturi, M.

2015-12-01

Persistently active explosive volcanoes are characterized by short explosive bursts, which often occur at periodic intervals numerous times per day, spanning years to decades. Many of these systems present relatively evolved compositions (andesite to rhyolite), and their cyclic activity has been the subject of extensive work (e.g., Soufriere Hills Volcano, Montserrat). However, the same periodic behavior can also be observed at open systems of more mafic compositions, such as Semeru in Indonesia or Karymsky in Kamchatka for example. In this work, we use DOMEFLOW, a 1D transient numerical model of magma ascent, to identify the conditions that lead to and control periodic eruptions in basaltic andesite systems, where the viscosity of the liquid phase can be drastically lower. Periodic behavior occurs for a very narrow range of conditions, for which the mass balance between magma flux and open-system gas escape repeatedly generates a viscous plug, pressurizes the magma beneath the plug, and then explosively disrupts it. The characteristic timescale and magnitude of the eruptive cycles are controlled by the overall viscosity of the magmatic mixture, with higher viscosities leading to longer cycles and lower flow rates at the top of the conduit. Cyclic eruptions in basaltic andesite systems are observed for higher crystal contents, smaller conduit radii, and over a wider range of chamber pressures than the andesitic system, all of which are the direct consequence of a decrease in viscosity of the melt phase, and in turn in the intensity of the viscous forces generated by the system. Results suggest that periodicity can exist in more mafic systems with relatively lower chamber pressures than andesite and rhyolite systems, and may explain why more mafic magmas sometimes remain active for decades.

A dearth of intermediate melts at subduction zone volcanoes and the petrogenesis of arc andesites.

PubMed

Reubi, Olivier; Blundy, Jon

2009-10-29

Andesites represent a large proportion of the magmas erupted at continental arc volcanoes and are regarded as a major component in the formation of continental crust. Andesite petrogenesis is therefore fundamental in terms of both volcanic hazard and differentiation of the Earth. Andesites typically contain a significant proportion of crystals showing disequilibrium petrographic characteristics indicative of mixing or mingling between silicic and mafic magmas, which fuels a long-standing debate regarding the significance of these processes in andesite petrogenesis and ultimately questions the abundance of true liquids with andesitic composition. Central to this debate is the distinction between liquids (or melts) and magmas, mixtures of liquids with crystals, which may or may not be co-genetic. With this distinction comes the realization that bulk-rock chemical analyses of petrologically complex andesites can lead to a blurred picture of the fundamental processes behind arc magmatism. Here we present an alternative view of andesite petrogenesis, based on a review of quenched glassy melt inclusions trapped in phenocrysts, whole-rock chemistry, and high-pressure and high-temperature experiments. We argue that true liquids of intermediate composition (59 to 66 wt% SiO(2)) are far less common in the sub-volcanic reservoirs of arc volcanoes than is suggested by the abundance of erupted magma within this compositional range. Effective mingling within upper crustal magmatic reservoirs obscures a compositional bimodality of melts ascending from the lower crust, and masks the fundamental role of silicic melts (>/=66 wt% SiO(2)) beneath intermediate arc volcanoes. This alternative view resolves several puzzling aspects of arc volcanism and provides important clues to the integration of plutonic and volcanic records.

Genesis of Cenozoic intraplate high Mg# andesites in Northeast China

NASA Astrophysics Data System (ADS)

Liu, J. Q.; Chen, L. H.; Zhong, Y.; Wang, X. J.

2017-12-01

High-Mg# andesites (HMAs) are usually generated in the converged plate boundary and have genetic relationships with slab subduction. However, it still remained controversial about the origin of those HMAs erupted in the intra-plate setting. Here we present major, trace element, and Sr-Nd-Pb-Hf isotopic compositions for the Cenozoic intra-plate HMAs from Northeast China to constrain their origin and formation process. Cenozoic Xunke volcanic rocks are located in the northern Lesser Khingan Range, covering an area of about 3, 000 km2. These volcanic rocks are mainly basaltic andesite and basaltic trachyandesite, with only several classified as trachyandesite and andesites. They have high SiO2 contents (54.3-57.4 wt%) and Mg# (49.6-57.8), falling into the scope of high Mg# andesites. The Xunke HMAs are enriched in large ion lithophile elements but depleted in high field strength elements, with positive Ba, K, Sr and negative Zr-Hf, and Ti anomalies. Their trace element absolute concentrations are between those of potassic basalts and Wuchagou HMAs. The Xunke HMAs have relatively enriched Sr-Nd-Hf isotopes (87Sr/86Sr = 0.705398-0.705764, ɛNd=-8.8-3.8, ɛHf=0.5-11.7), and low radiogenic Pb isotopes (206Pb/204Pb = 16.701-17.198), towards to the EM1 end-member, which indicates that they are ultimately derived from ancient, recycled crustal components. Primitive silica-rich melts were generated from higher degrees of partial melting of recycled crustal materials (relative to potassic basalts) and then interacted with the peridotite to produce the Xunke HMAs.

Silica-enriched mantle sources of subalkaline picrite-boninite-andesite island arc magmas

NASA Astrophysics Data System (ADS)

Bénard, A.; Arculus, R. J.; Nebel, O.; Ionov, D. A.; McAlpine, S. R. B.

2017-02-01

compositions extracted from these hybrid sources are higher in normative quartz and hypersthene (i.e., they have a more silica-saturated character) in comparison with basalts derived from prior melt-depleted asthenospheric mantle beneath ridges. These primary arc melts range from silica-rich picrite to boninite and high-Mg basaltic andesite along a residual spinel harzburgite cotectic. Silica enrichment in the mantle sources of arc-related, subalkaline picrite-boninite-andesite suites coupled with the amount of water and depth of melting, are important for the formation of medium-Fe ('calc-alkaline') andesite-dacite-rhyolite suites, key lithologies forming the continental crust.

The material from Lampung as coarse aggregate to substitute andesite for concrete-making

NASA Astrophysics Data System (ADS)

Amin, M.; Supriyatna, Y. I.; Sumardi, S.

2018-01-01

Andesite stone is usually used for split stone material in the concrete making. However, its availability is decreasing. Lampung province has natural resources that can be used for coarse aggregate materials to substitute andesite stone. These natural materials include limestone, feldspar stone, basalt, granite, and slags from iron processing waste. Therefore, a research on optimizing natural materials in Lampung to substitute andesite stone for concrete making is required. This research used laboratory experiment method. The research activities included making cubical object samples of 150 x 150 x 150 mm with material composition referring to a standard of K.200 and w/c 0.61. Concrete making by using varying types of aggregates (basalt, limestone, slag) and aggregate sizes (A = 5-15 mm, B = 15-25 mm, and 25-50 mm) was followed by compressive strength test. The results showed that the obtained optimal compressive strengths for basalt were 24.47 MPa for 50-150 mm aggregate sizes, 21.2 MPa for 15-25 mm aggregate sizes, and 20.7 MPa for 25-50 mm aggregate sizes. These results of basalt compressive strength values were higher than the same result for andesite (19.69 MPa for 50-150 mm aggregate sizes), slag (22.72 MPa for 50-150 mm aggregate sizes), and limestone (19.69 Mpa for 50-150 mm aggregate sizes). These results indicated that basalt, limestone, and slag aggregates were good enough to substitute andesite as materials for concrete making. Therefore, natural resources in Lampung can be optimized as construction materials in concrete making.

Geology of Saipan, Mariana Islands; Part 2, Petrology and soils

USGS Publications Warehouse

Schmidt, R.G.; Johnson, J. H.; McCracken, R.J.

1957-01-01

The rocks that comprise the volcanic formations of Saipan are of two principal types: dacites, which are characteristically glassy, and andesites, which are comparatively crystalline. The dacites consist primarily of silicic glass, oligoclase, and silica minerals (quartz, tridymite, cristobalite, chalcedony, and opal). Minor constituents in these rocks are green hornblende, biotite, magnetite, and hematite. The andesites are composed principally of labradorite, hypersthene, augite, and subcalcrc augite. Minor but also characteristic constituents of the andesites are quartz, tridymite, cristobalite, anorthoclase, and accessory magnetite, ilmenite, rutile, and apatite. Nine varieties of dacite and andesite are recognized on the basis of chemical composition, mineralogy, and texture. These are dacite, dacite vitrophyre, dacite perlite, hornblende-bearing dacite porphyry, augite-hypersthene andesite, quartz-bearing augite-hypersthene andesite, quartz-bearing augite-hypersthene andesite porphyry, augite andesite, and hypersthene andesite.

Geochemistry, strontium isotope data, and potassium-argon ages of the andesite-rhyolite association in the Padang area, West Sumatra

USGS Publications Warehouse

Leo, G.W.; Hedge, C.E.; Marvin, R.F.

1980-01-01

Quaternary volcanoes in the Padang area on the west coast of Sumatra have produced two-pyroxene, calc-alkaline andesite and volumetrically subordinate rhyolitic and andesitic ash-flow tuffs. A sequence of andesite (pre-caldera), rhyolitic tuff and andesitic tuff, in decreasing order of age, is related to Maninjau caldera. Andesite compositions range from 55.0 to 61.2% SiO2 and from 1.13 to 2.05% K2O. Six K-Ar whole-rock age determinations on andesites show a range of 0.27 ?? 0.12 to 0.83 ?? 0.42 m.y.; a single determination on the rhyolitic ashflow tuff gave 0.28 ?? 0.12 m.y. Eight 57Sr/26Sr ratios on andesites and rhyolite tuff west of the Semangko fault zone are in the range 0.7056 - 0.7066. These ratios are higher than those elsewhere in the Sunda arc but are comparable to the Taupo volcanic zone of New Zealand and calc-alkaline volcanics of continental margins. An 87Sr/86Sr ratio of 0.7048 on G. Sirabungan east of the Semangko fault is similar to an earlier determination on nearby G. Marapi (0.7047), and agrees with 87Sr/86Sr ratios in the rest of the Sunda arc. The reason for this distribution of 87Sr/86Sr ratios is unknown. The high 87Sr/86Sr ratios are tentatively regarded to reflect a crustal source for the andesites, while moderately fractionated REE patterns with pronounced negative Eu anomalies suggest a residue enriched in plagioclase with hornblende and/or pyroxenes. Generation of associated andesite and rhyolite could have been caused by hydrous fractional melting of andesite or volcanogenic sediments under adiabatic decompression. ?? 1980.

Experimental Study on the Electrical Conductivity of Pyroxene Andesite at High Temperature and High Pressure

NASA Astrophysics Data System (ADS)

Hui, KeShi; Dai, LiDong; Li, HePing; Hu, HaiYing; Jiang, JianJun; Sun, WenQing; Zhang, Hui

2017-03-01

The electrical conductivity of pyroxene andesite was in situ measured under conditions of 1.0-2.0 GPa and 673-1073 K using a YJ-3000t multi-anvil press and Solartron-1260 Impedance/Gain-phase analyzer. Experimental results indicate that the electrical conductivities of pyroxene andesite increase with increasing temperature, and the electrical conductivities decrease with the rise of pressure, and the relationship between electrical conductivity ( σ) and temperature ( T) conforms to an Arrhenius relation within a given pressure and temperature range. When temperature rises up to 873-923 K, the electrical conductivities of pyroxene andesite abruptly increase, and the activation enthalpy increases at this range, which demonstrates that pyroxene andesite starts to dehydrate. By the virtue of the activation enthalpy (0.35-0.42 eV) and the activation volume (-6.75 ± 1.67 cm3/mole) which characterizes the electrical properties of sample after dehydration, we consider that the conduction mechanism is the small polaron conduction before and after dehydration, and that the rise of carrier concentration is the most important reason of increased electrical conductivity.

A complex magma mixing origin for rocks erupted in 1915, Lassen Peak, California

USGS Publications Warehouse

Clynne, M.A.

1999-01-01

The eruption of Lassen Peak in May 1915 produced four volcanic rock types within 3 days, and in the following order: (1) hybrid black dacite lava containing (2) undercooled andesitic inclusions, (3) compositionally banded pumice with dark andesite and light dacite bands, and (4) unbanded light dacite. All types represent stages of a complex mixing process between basaltic andesite and dacite that was interrupted by the eruption. They contain disequilibrium phenocryst assemblages characterized by the co-existence of magnesian olivine and quartz and by reacted and unreacted phenocrysts derived from the dacite. The petrography and crystal chemistry of the phenocrysts and the variation in rock compositions indicate that basaltic andesite intruded dacite magma and partially hybridized with it. Phenocrysts from the dacite magma were reacted. Cooling, cyrstallization, and vesiculation of the hybrid andesite magma converted it to a layer of mafic foam. The decreased density of the andesite magma destabilized and disrupted the foam. Blobs of foam rose into and were further cooled by the overlying dacite magma, forming the andesitic inclusions. Disaggregation of andesitic inclusions in the host dacite produced the black dacite and light dacite magmas. Formation of foam was a dynamic process. Removal of foam propagated the foam layer downward into the hybrid andesite magma. Eventually the thermal and compositional contrasts between the hybrid andesite and black dacite magmas were reduced. Then, they mixed directly, forming the dark andesite magma. About 40-50% andesitic inclusions were disaggregated into the host dacite to produce the hybrid black dacite. Thus, disaggregation of inclusions into small fragments and individual crystals can be an efficient magma-mixing process. Disaggregation of undercooled inclusions carrying reacted host-magma phenocrysts produces co-existing reacted and unreacted phenocrysts populations.

Isotopic composition of strontium in three basalt-andesite centers along the Lesser Antilles arc

USGS Publications Warehouse

Hedge, C.E.; Lewis, J.F.

1971-01-01

Si87/Sr86 ratios have been determined for lavas and py lastic rocks from three basalt-andesite centers along the Lesser Antilles arc-Mt. Misery on the island of St. Kitts, Soufriere on the island of St. Vincent, and Carriacou, an island of The Grenadines. The average Si87/Sr86 content of these rocks is 0.7038 for Mt. Misery, 0.7041 for Soufriere, and 0.7053 for Carriacou. All the Sr87/Sr86 values from each center are the same within analytical uncertainty (??0.0002). The constancy of strontium isotopic data within each center supports the hypothesis that basalts and andesites for each specific center investigated are generated from the same source - in agreement with petrographic and major- and minor-element data. Strontium isotopic compositions and elemental concentrations, particularly of strontium and nickel, indicate that this source was mantle peridotite and that the relationship between the respective basalts and andesites is probably fractional crystallization. ?? 1971 Springer-Verlag.

Investigation of Mineral Alteration in Andesite and Dacite from Three Different Volcano Hydrothermal Systems on Dominica, Lesser Antilles

NASA Astrophysics Data System (ADS)

Smith, C. I. V.; Frey, H. M.; Joseph, E. P.; Manon, M. R. F.

2017-12-01

The thermal discharges of Dominica are classified as steam-heated acidic-sulphate waters, produced by the mixing of shallow ground waters heated by sulphur bearing gases coming from magmatic sources. This study investigates the mineral alteration associated with three hydrothermal areas in Dominica that exhibit different temperature, pH, water composition and surface water abundance. Hydrothermal features (fumaroles, pools, springs) from Sulphur Springs ranged in temperature from 41 - 97 °C and pH from 1-3 in a predominantly gaseous environment, whereas the Valley of Desolation (69-98 °C and pH 1- 4) and the Cold Soufriere (18-32 °C and pH 1-4) have significant inputs of surface water. At each location, the host andesite-dacite rock was enveloped by a thin rind (up 2 cm) of precipitates, but the degree of alteration and rind thickness/composition varied with location. Cobbles from Sulphur Springs (SS) are grayish white in color with a thin outer rind (3-13 mm), and seemingly unaltered cores. Valley of Desolation (VoD) samples have a variety of patterns of alteration, with some clasts a uniform white-orange color, whereas others have variable thicknesses of an altered rind (1-20 mm), with relatively unaltered cores. Multiple hydrothermal minerals precipitated in the outer rinds display distinctive colors, suggestive of sulphides (dark gray), sulphates (orange and yellow), and iron oxides(?) (pink and purple). Cold Soufriere (CS) samples appear to be the most altered, often crumbling at touch. Others had rinds (2-10 mm) and pinkish gray cores that suggest more alteration compared to VoD and SS samples. Preliminary mineral identification of rind compositions was determined by XRD. Scans indicate the presence of silica polymorphs cristobalite and tridymite, as well as pyrite and sulphur. Elemental maps created using a SEM to identify any gradation caused by the elemental leaching and/or precipitation show that the boundaries between the weathering rind and the host

In-situ observations of bubble growth in basaltic, andesitic and rhyodacitic melts

NASA Astrophysics Data System (ADS)

Masotta, M.; Ni, H.; Keppler, H.

2013-12-01

Bubble growth strongly affects the physical properties of degassing magmas and their eruption dynamics. Natural samples and products from quench experiments provide only a snapshot of the final state of volatile exsolution, leaving the processes occurring during its early stages unconstrained. In order to fill this gap, we present in-situ high-temperature observations of bubble growth in magmas of different compositions (basalt, andesite and rhyodacite) at 1100 to 1240 °C and 1 bar, obtained using a moissanite cell apparatus. The data show that nucleation occurs at very small degrees of supersaturaturation (<20 MPa in basalt and andesite, ca. 100 MPa in rhyodacite), probably due to heterogeneous nucleation of bubbles occurring simultaneously with the nucleation of crystals. During the early stages of exsolution, melt degassing is the driving mechanism of bubble growth, with coalescence becoming increasingly important as exsolution progresses. Ostwald ripening occurs only at the end of the process and only in basaltic melt. The average bubble growth rate (GR) ranges from 3.4*10-6 to 5.2*10-7 mm/s, with basalt and andesite showing faster growth rates than rhyodacite. The bubble number density (NB) at nucleation ranges from 1.8*108 to 7.9*107 cm-3 and decreases exponentially over time. While the rhyodacite melt maintained a well-sorted bubble-size distribution (BSD) through time, the BSD's of basalt and andesite are much more inhomogeneous. Our experimental observations demonstrate that bubble growth cannot be ascribed to a single mechanism but is rather a combination of many processes, which depend on the physical properties of the melt. Depending on coalescence rate, annealing of bubbles following a single nucleation event can produce complex bubble size distributions. In natural samples, such BSD's may be misinterpreted as resulting from several separate nucleation events. Incipient crystallization upon cooling of a magma may allow bubble nucleation already at

In situ observations of bubble growth in basaltic, andesitic and rhyodacitic melts

NASA Astrophysics Data System (ADS)

Masotta, M.; Ni, H.; Keppler, H.

2014-02-01

Bubble growth strongly affects the physical properties of degassing magmas and their eruption dynamics. Natural samples and products from quench experiments provide only a snapshot of the final state of volatile exsolution, leaving the processes occurring during its early stages unconstrained. In order to fill this gap, we present in situ high-temperature observations of bubble growth in magmas of different compositions (basalt, andesite and rhyodacite) at 1,100 to 1,240 °C and 0.1 MPa (1 bar), obtained using a moissanite cell apparatus. The data show that nucleation occurs at very small degrees of supersaturaturation (<60 MPa in basalt and andesite, 200 MPa in rhyodacite), probably due to heterogeneous nucleation of bubbles occurring simultaneously with the nucleation of crystals. During the early stages of exsolution, melt degassing is the driving mechanism of bubble growth, with coalescence becoming increasingly important as exsolution progresses. Ostwald ripening occurs only at the end of the process and only in basaltic melt. The average bubble growth rate ( G R) ranges from 3.4 × 10-6 to 5.2 × 10-7 mm/s, with basalt and andesite showing faster growth rates than rhyodacite. The bubble number density ( N B) at nucleation ranges from 7.9 × 104 mm-3 to 1.8 × 105 mm-3 and decreases exponentially over time. While the rhyodacite melt maintained a well-sorted bubble size distribution (BSD) through time, the BSDs of basalt and andesite are much more inhomogeneous. Our experimental observations demonstrate that bubble growth cannot be ascribed to a single mechanism but is rather a combination of many processes, which depend on the physical properties of the melt. Depending on coalescence rate, annealing of bubbles following a single nucleation event can produce complex bubble size distributions. In natural samples, such BSDs may be misinterpreted as resulting from several separate nucleation events. Incipient crystallization upon cooling of a magma may allow

Mapping Acid Sulfate Alteration of Basaltic Andesite with Thermal Infrared Data

NASA Technical Reports Server (NTRS)

Vaughan, R. G.; Calvin, W. M.; Hook, S. J.; Taranik, J. V.

2002-01-01

Airborne thermal infrared multi- and hyperspectral data sets are used to map sulfate alteration of basaltic andesites near Reno, NV. Alteration includes quartz-alunite, jarosite and a number of clay minerals such as kaolinite and montmorillonite. Additional information is contained in the original extended abstract.

Diffusive exchange of trace elements between basaltic-andesite and dacitic melt: Insights into potential metal fractionation during magma mixing

NASA Astrophysics Data System (ADS)

Fiege, A.; Ruprecht, P.; Simon, A. C.; Holtz, F.

2017-12-01

Mafic magma recharge is a common process that triggers physical and chemical mixing in magmatic systems and drives their evolution, resulting in, e.g., hybridization and volcanic eruptions. Once magma-magma contact is initiated, rapid heat-flux commonly leads to the formation of a cooling-induced crystal mush on the mafic side of the interface. Here, on a local scale (µm to cm), at the magma-magma interface, melt-melt diffusive exchange is required to approach equilibrium. Significant chemical potential gradients drive a complex, multi-element mass flux between the two systems (Liang, 2010). This diffusive-equilibration often controls crystal dissolution rates within the boundary layers and, thus, the formation of interconnected melt or fluid networks. Such networks provide important pathways for the transport of volatiles and trace metals from the mafic recharge magma to the felsic host magma, where the latter may feed volcanic activities and ore deposits. While major element diffusion in silicate melts is mostly well understood, even in complex systems, the available data for many trace element metals are limited (Liang, 2010; Zhang et al., 2010). Differences in diffusivity in a dynamic, mixing environment can cause trace element fractionation, in particular during crystallization and volatile exsolution and separation. This may affect trace element signatures in phenocrysts and magmatic volatile phases that can form near a magma-magma boundary. As a result, the chemistry of volcanic gases and magmatic-hydrothermal ore deposits may be partially controlled by such mixing phenomena. We performed melt-melt diffusion-couple experiments at 150 MPa, 1100°C, FMQ, FMQ+1 and FMQ+3 (FMQ: fayalite-magnetite-quartz oxygen fugacity buffer). Hydrated, sulfur-bearing cylinders of dacite and basaltic andesite were equilibrated for up to 20 h. Major and trace element gradients were measured by using laser-ablation ICP-MS and electron microprobe analyses. The results we will

The 2006-2009 activity of the Ubinas volcano (Peru): Petrology of the 2006 eruptive products and insights into genesis of andesite magmas, magma recharge and plumbing system

NASA Astrophysics Data System (ADS)

Rivera, Marco; Thouret, Jean-Claude; Samaniego, Pablo; Le Pennec, Jean-Luc

2014-01-01

Following a fumarolic episode that started six months earlier, the most recent eruptive activity of the Ubinas volcano (south Peru) began on 27 March 2006, intensified between April and October 2006 and slowly declined until December 2009. The chronology of the explosive episode and the extent and composition of the erupted material are documented with an emphasis on ballistic ejecta. A petrological study of the juvenile products allows us to infer the magmatic processes related to the 2006-2009 eruptions of the andesitic Ubinas volcano. The juvenile magma erupted during the 2006 activity shows a homogeneous bulk-rock andesitic composition (56.7-57.6 wt.% SiO2), which belongs to a medium- to high-K calc-alkaline series. The mineral assemblage of the ballistic blocks and tephra consists of plagioclase > two-pyroxenes > Fe-Ti oxide and rare olivine and amphibole set in a groundmass of the same minerals with a dacitic composition (66-67 wt.% SiO2). Thermo-barometric data, based on two-pyroxene and amphibole stability, records a magma temperature of 998 ± 14 °C and a pressure of 476 ± 36 MPa. Widespread mineralogical and textural features point to a disequilibrium process in the erupted andesite magma. These features include inversely zoned "sieve textures" in plagioclase, inversely zoned clinopyroxene, and olivine crystals with reaction and thin overgrowth rims. They indicate that the pre-eruptive magmatic processes were dominated by recharge of a hotter mafic magma into a shallow reservoir, where magma mingling occurred and triggered the eruption. Prior to 2006, a probable recharge of a mafic magma produced strong convection and partial homogenization in the reservoir, as well as a pressure increase and higher magma ascent rate after four years of fumarolic activity. Mafic magmas do not prevail in the Ubinas pre-historical lavas and tephras. However, mafic andesites have been erupted during historical times (e.g. AD 1667 and 2006-2009 vulcanian eruptions). Hence

An overview of the dynamics of the Volcanic Paroxysmal Explosive Activity, and related seismicity, at andesitic and dacitic volcanoes (1960-2010)

NASA Astrophysics Data System (ADS)

Zobin, Vyacheslav M.

2018-05-01

Understanding volcanic paroxysmal explosive activity requires the knowledge of many associated processes. An overview of the dynamics of paroxysmal explosive eruptions (PEEs) at andesitic and dacitic volcanoes occurring between 1960 and 2010 is presented here. This overview is based mainly on a description of the pre-eruptive and eruptive events, as well as on the related seismic measurements. The selected eruptions are grouped according to their Volcanic Explosivity Index (VEI). A first group includes three eruptions of VEI 5-6 (Mount St. Helens, 1980; El Chichón, 1982, and Pinatubo, 1991) and a second group includes three eruptions of VEI 3 (Usu volcano, 1977; Soufriere Hills Volcano (SHV), 1996, and Volcán de Colima, 2005). The PEEs of the first group have similarity in their developments that allows to propose a 5-stage scheme of their dynamics process. Between these stages are: long (more than 120 years) period of quiescence (stage 1), preliminary volcano-tectonic (VT) earthquake swarm (stage 2), period of phreatic explosions (stage 3) and then, PEE appearance (stage 4). It was shown also that the PEEs of this group during their Plinian stage "triggered" the earthquake sequences beneath the volcanic structures with the maximum magnitude of earthquakes proportional to the volume of ejecta of PEEs (stage 5). Three discussed PEEs of the second group with lower VEI developed in more individual styles, not keeping within any general scheme. Among these, one PEE (SHV) may be considered as partly following in development to the PEEs of the first group, having stages 1, 3 and 4. The PEEs of Usu volcano and of Volcán de Colima had no preliminary long-term stages of quiescence. The PEE at Usu volcano came just at the end of the preceding short swarm of VT earthquakes. At Volcán de Colima, no preceding swarm of VT occurred. This absence of any regularity in development of lower VEI eruptions may refer, among other reasons, to different conditions of opening of the

Geochemistry and petrology of andesites from the north rift zone of Axial Seamount, Juan de Fuca Ridge

NASA Astrophysics Data System (ADS)

Smithka, I. N.; Perfit, M. R.; Clague, D. A.; Wanless, V. D.

2014-12-01

In 2013, the ROV Doc Ricketts onboard R/V Western Flyer explored ~4 km of an elongate pillow ridge up to ~300 m high along the eastern edge of the north rift zone of Axial Seamount. The steep-sided volcanic ridge is constructed of large pillow lavas up to 2-3 m in diameter and smaller elongated pillow tubes. Of the 27 samples collected during dive D526, all but one are andesites making it one of the largest confirmed high-silica exposures along a mid-ocean ridge (MOR). Based on radiocarbon ages of sediment on top of flows, the mounds are at least ~1390 years old. This minimum age is much younger than the 56 Ka age calculated based on distance from the rift axis, indicating eruption off-axis through older, colder crust and supporting the hypothesis and model calculations that extensive fractional crystallization (>85%) caused the high silica content. The andesitic lavas are primarily glassy, highly vesicular, crusty, and sparsely phyric with small (~1 mm) plagioclase crystals and olivine, clinopyroxene, and Fe-Ti oxide microphenocrysts. Microprobe analyses of glasses are similar to wax-core samples previously collected from this area but are more compositionally variable. Excluding one basalt (7.7 wt% MgO) sampled between mounds, the lavas are basaltic andesites and andesites (53-59 wt% SiO2) with <3 wt% MgO and 12.8-15.7 wt% FeO concentrations. Incompatible trace element abundances are ~4-6 times more enriched than in Axial Seamount T-MORB. Primitive mantle-normalized patterns are similar to those of high-silica lavas from other MORs (southern Juan de Fuca Ridge, 9N East Pacific Rise) with significant positive U anomalies, large negative Sr anomalies, small negative Eu anomalies, and slight positive Zr-Hf anomalies. The andesites are more enriched in light rare earth elements than basalts from Axial Seamount ((La/Yb)N 1.35-1.4 vs. 0.7-1.27) and N-MORB from the southern Juan de Fuca Ridge. The andesites also have high Cl (~0.3-0.6 wt%) and H2O (~1.60-1.71 wt

Using geochemistry as a tool for correlating proximal andesitic tephra: Case studies from Mt Rainier (USA) and Mt Ruapehu (New Zealand)

USGS Publications Warehouse

Donoghue, S.L.; Vallance, J.; Smith, I.E.M.; Stewart, R.B.

2007-01-01

Volcanic hazards assessments at andesite stratovolcanoes rely on the assessment of frequency and magnitude of past events. The identification and correlation of proximal and distal andesitic tephra, which record the explosive eruptive history, are integral to such assessments. These tephra are potentially valuable stratigraphic marker beds useful to the temporal correlation and age dating of Quaternary volcanic, volcaniclastic and epiclastic sedimentary deposits with which they are interbedded. At Mt Ruapehu (New Zealand) and Mt Rainier (USA), much of the detail of the recent volcanic record remains unresolved because of the difficulty in identifying proximal tephra. This study investigates the value of geochemical methods in discriminating andesitic tephra. Our dataset comprises petrological and geochemical analyses of tephra that span the late Quaternary eruptive record of each volcano. Our data illustrate that andesitic tephra are remarkably heterogeneous in composition. Tephra compositions fluctuate widely over short time intervals, and there are no simple or systematic temporal trends in geochemistry within either eruptive record. This complexity in tephra geochemistry limits the application of geochemical approaches to tephrostratigraphic studies, beyond a general characterisation useful to provenance assignation. Petrological and geochemical data suggest that the products of andesite systems are inherently variable and therefore intractable to discrimination by simple geochemical methods alone. Copyright ?? 2006 John Wiley & Sons, Ltd.

Integrated geophysical surveys for mapping lati-andesite intrusive bodies, Chino Valley, Arizona

USGS Publications Warehouse

El-Kaliouby, Hesham; Sternberg, Ben K.; Hoffmann, John P.; Langenheim, V.E.

2012-01-01

Three different geophysical methods (magnetic, transient electromagnetic (TEM) and gravity) were used near Chino Valley, Arizona, USA in order to map a suspected lati-andesite intrusive body (plug) previously located by interpretation of aeromagnetic data. The magnetic and TEM surveys provided the best indication of the location and depth of the plug. The north-south spatial extent of this plug was estimated to be approximately 600 meters. The depth to the top of the plug was found from the TEM survey to be approximately 350 meters near the center of the survey. The location of the plug defined by the ground magnetic data is consistent with that from the TEM data. Gravity data mostly image the basin-basement interface with a small contribution from the plug of about 0.5 mGal. Results from this investigation can be used to help define the irregular subsurface topography caused by several intrusive lati-andesite plugs that could influence groundwater flow in the area.

a Microgravity Survey to Determine the Extent of AN Andesitic Sill that Intrudes across the Rio Grande River Basin, Rio Grande Rift Valley, Sunland Park, New Mexico

NASA Astrophysics Data System (ADS)

Baker, L. A.; Shinagel, S.; Villalobos, J. I.; Avila, V.; Montana, C. J.; Kaip, G.

2012-12-01

In Sunland Park, NM, there is an andesite outcrop near the bank of the Rio Grande (called the River Andesite) which does not match the surrounding sedimentary deposition. Studies of the River Andesite by Garcia (1970) indicate the outcrop is petrologically similar to the Muleros Andesite of Mt. Cristo Rey located several km to the south. A limited GPR and magnetic survey conducted by UTEP students in 2008 suggested the River Andesite was part of a dike, although Garcia mapped smaller outcrops of andesite ~300 m west of the river that may be part of the same body. We have recently (June 2012) found large andesite boulders that may be the outcrops Garcia mapped, although it is uncertain whether these boulders are in-situ. We initially collected microgravity and magnetic data in a small region near the river outcrop in December 2011 to determine the extent of the outcrop. Our preliminary modeling of these data showed the river outcrop appeared to merge with a more extensive igneous body at depth. Ground conductivity data collected near the river outcrop in March 2012 suggested that the outcrop impacts groundwater flow and sediment deposition adjacent to the river. From May through July 2012 we have been collecting additional microgravity data on a grid with 100-200 m spacing extending ~ 500 m from both sides of the river outcrop to better determine the extent of the buried andesite body. We also plan to conduct GPR and magnetic surveys near the recently discovered andesite boulders to determine if these are truly in-situ and part of the same igneous body as the river outcrop. Our eventual goal is to determine how extensive the andesite unit is and how it may impact groundwater flow and flooding in this area of growing urbanization.

Dacite petrogenesis on mid-ocean ridges: Evidence for oceanic crustal melting and assimilation

USGS Publications Warehouse

Wanless, V.D.; Perfit, M.R.; Ridley, W.I.; Klein, E.

2010-01-01

Whereas the majority of eruptions at oceanic spreading centers produce lavas with relatively homogeneous mid-ocean ridge basalt (MORB) compositions, the formation of tholeiitic andesites and dacites at mid-ocean ridges (MORs) is a petrological enigma. Eruptions of MOR high-silica lavas are typically associated with ridge discontinuities and have produced regionally significant volumes of lava. Andesites and dacites have been observed and sampled at several locations along the global MOR system; these include propagating ridge tips at ridge-transform intersections on the Juan de Fuca Ridge and eastern Gal??pagos spreading center, and at the 9??N overlapping spreading center on the East Pacific Rise. Despite the formation of these lavas at various ridges, MOR dacites show remarkably similar major element trends and incompatible trace element enrichments, suggesting that similar processes are controlling their chemistry. Although most geochemical variability in MOR basalts is consistent with low-pressure fractional crystallization of various mantle-derived parental melts, our geochemical data for MOR dacitic glasses suggest that contamination from a seawater-altered component is important in their petrogenesis. MOR dacites are characterized by elevated U, Th, Zr, and Hf, low Nb and Ta concentrations relative to rare earth elements (REE), and Al2O3, K2O, and Cl concentrations that are higher than expected from low-pressure fractional crystallization alone. Petrological modeling of MOR dacites suggests that partial melting and assimilation are both integral to their petrogenesis. Extensive fractional crystallization of a MORB parent combined with partial melting and assimilation of amphibole-bearing altered crust produces a magma with a geochemical signature similar to a MOR dacite. This supports the hypothesis that crustal assimilation is an important process in the formation of highly evolved MOR lavas and may be significant in the generation of evolved MORB in

Volatile Evolution and Anhydrite-Bearing Dacite, Yanacocha Gold Deposit, Cajamarca, Peru: Relevance for the Sulfur Budget

NASA Astrophysics Data System (ADS)

Chambefort, I. S.; Dilles, J. H.

2006-12-01

Magmatic water, sulfur and chlorine evolved during volcanic eruptions have important climactic effects, but during passive degassing these volatiles may transport metals and produce hydrothermal ore deposits. At the Yanacocha Mine, we are examining the volatile evolution of the Miocene andesitic to dacitic volcanic rocks (ca 20 to 8 Ma). High sulfidation epithermal deposits contain >50 Moz of gold in oxides with additional deeper sulfide resources containing >5 Mt of copper. Large volumes (>10 km3) of rock are hydrothermally altered by sulfate-rich and low pH fluid to quartz, quartz-alunite, quartz-pyrophyllite, illite. Pyrite (1-5 vol.%), native sulfur, covellite, enargite and chalcopyrite constitute reduced S-species. In total, at least 500 M tonnes of sulfur were added during alteration. The San Jose ignimbrite (SJI) erupted 30 km3 magma in two cooling units at 11.50 and 11.28 Ma, and immediately predates the bulk of gold mineralization at about 10.80 Ma (Longo, 2005). This hornblende- plagioclase dacitic magma is highly oxidized with fO2 ≍ 2 NNO. Low-Al2O3 (~7 wt.%), and high- Al2O3 (~12 wt.%) amphiboles coexist in most of the samples. Plag-hbl thermobarometry on low-Al content amphibole yields ca. 1.5-2 kb and 800°C. High-Al pargasitic hornblende forms sparse crystals up to 1 cm long that often show resorption or oxide rims associated with oxyhornblende breakdown. Apatite is an inclusion but generally not plagioclase or oxide. These petrographic relations suggest that the high-Al hornblende is the liquidus phase (at 950 to 1000°C, PH2O > 3 kb) in an andesitic or basaltic magma. The high-Al amphibole in two samples contains anhydrite inclusions, one with >5 vol.% anhydrite associated with apatite having up to 1.2 wt.% SO3. Comparison of these data with experimental sulfate solubilities at NNO+2 suggests the andesitic or basaltic melt dissolved at least 1000 ppm S. One low-Al amphibole contains anhydrite, demonstrating that the cooler dacite magma was also

Viscosity measurements of crystallizing andesite from Tungurahua volcano (Ecuador).

PubMed

Chevrel, Magdalena Oryaëlle; Cimarelli, Corrado; deBiasi, Lea; Hanson, Jonathan B; Lavallée, Yan; Arzilli, Fabio; Dingwell, Donald B

2015-03-01

Viscosity has been determined during isothermal crystallization of an andesite from Tungurahua volcano (Ecuador). Viscosity was continuously recorded using the concentric cylinder method and employing a Pt-sheathed alumina spindle at 1 bar and from 1400°C to subliquidus temperatures to track rheological changes during crystallization. The disposable spindle was not extracted from the sample but rather left in the sample during quenching thus preserving an undisturbed textural configuration of the crystals. The inspection of products quenched during the crystallization process reveals evidence for heterogeneous crystal nucleation at the spindle and near the crucible wall, as well as crystal alignment in the flow field. At the end of the crystallization, defined when viscosity is constant, plagioclase is homogeneously distributed throughout the crucible (with the single exception of experiment performed at the lowest temperature). In this experiments, the crystallization kinetics appear to be strongly affected by the stirring conditions of the viscosity determinations. A TTT (Time-Temperature-Transformation) diagram illustrating the crystallization "nose" for this andesite under stirring conditions and at ambient pressure has been constructed. We further note that at a given crystal content and distribution, the high aspect ratio of the acicular plagioclase yields a shear-thinning rheology at crystal contents as low as 13 vol %, and that the relative viscosity is higher than predicted from existing viscosity models. These viscosity experiments hold the potential for delivering insights into the relative influences of the cooling path, undercooling, and deformation on crystallization kinetics and resultant crystal morphologies, as well as their impact on magmatic viscosity.

Viscosity measurements of crystallizing andesite from Tungurahua volcano (Ecuador)

PubMed Central

Cimarelli, Corrado; deBiasi, Lea; Hanson, Jonathan B.; Lavallée, Yan; Arzilli, Fabio; Dingwell, Donald B.

2015-01-01

Abstract Viscosity has been determined during isothermal crystallization of an andesite from Tungurahua volcano (Ecuador). Viscosity was continuously recorded using the concentric cylinder method and employing a Pt‐sheathed alumina spindle at 1 bar and from 1400°C to subliquidus temperatures to track rheological changes during crystallization. The disposable spindle was not extracted from the sample but rather left in the sample during quenching thus preserving an undisturbed textural configuration of the crystals. The inspection of products quenched during the crystallization process reveals evidence for heterogeneous crystal nucleation at the spindle and near the crucible wall, as well as crystal alignment in the flow field. At the end of the crystallization, defined when viscosity is constant, plagioclase is homogeneously distributed throughout the crucible (with the single exception of experiment performed at the lowest temperature). In this experiments, the crystallization kinetics appear to be strongly affected by the stirring conditions of the viscosity determinations. A TTT (Time‐Temperature‐Transformation) diagram illustrating the crystallization “nose” for this andesite under stirring conditions and at ambient pressure has been constructed. We further note that at a given crystal content and distribution, the high aspect ratio of the acicular plagioclase yields a shear‐thinning rheology at crystal contents as low as 13 vol %, and that the relative viscosity is higher than predicted from existing viscosity models. These viscosity experiments hold the potential for delivering insights into the relative influences of the cooling path, undercooling, and deformation on crystallization kinetics and resultant crystal morphologies, as well as their impact on magmatic viscosity. PMID:27656114

Magma heating by decompression-driven crystallization beneath andesite volcanoes.

PubMed

Blundy, Jon; Cashman, Kathy; Humphreys, Madeleine

2006-09-07

Explosive volcanic eruptions are driven by exsolution of H2O-rich vapour from silicic magma. Eruption dynamics involve a complex interplay between nucleation and growth of vapour bubbles and crystallization, generating highly nonlinear variation in the physical properties of magma as it ascends beneath a volcano. This makes explosive volcanism difficult to model and, ultimately, to predict. A key unknown is the temperature variation in magma rising through the sub-volcanic system, as it loses gas and crystallizes en route. Thermodynamic modelling of magma that degasses, but does not crystallize, indicates that both cooling and heating are possible. Hitherto it has not been possible to evaluate such alternatives because of the difficulty of tracking temperature variations in moving magma several kilometres below the surface. Here we extend recent work on glassy melt inclusions trapped in plagioclase crystals to develop a method for tracking pressure-temperature-crystallinity paths in magma beneath two active andesite volcanoes. We use dissolved H2O in melt inclusions to constrain the pressure of H2O at the time an inclusion became sealed, incompatible trace element concentrations to calculate the corresponding magma crystallinity and plagioclase-melt geothermometry to determine the temperature. These data are allied to ilmenite-magnetite geothermometry to show that the temperature of ascending magma increases by up to 100 degrees C, owing to the release of latent heat of crystallization. This heating can account for several common textural features of andesitic magmas, which might otherwise be erroneously attributed to pre-eruptive magma mixing.

Magmatic controls on eruption dynamics of the 1950 yr B.P. eruption of San Antonio Volcano, Tacaná Volcanic Complex, Mexico-Guatemala

NASA Astrophysics Data System (ADS)

Mora, Juan Carlos; Gardner, James Edward; Macías, José Luis; Meriggi, Lorenzo; Santo, Alba Patrizia

2013-07-01

San Antonio Volcano, in the Tacaná Volcanic Complex, erupted ~ 1950 yr. B.P., with a Pelean type eruption that produced andesitic pyroclastic surges and block-and-ash flows destroying part of the volcano summit and producing a horse-shoe shaped crater open to the SW. Between 1950 and 800 yr B.P. the eruption continued with effusive andesites followed by a dacite lava flow and a summit dome, all from a single magma batch. All products consist of phenocrysts and microphenocrysts of zoned plagioclase, amphibole, pyroxene, magnetite ± ilmenite, set in partially crystallized groundmass of glass and microlites of the same mineral phases, except for the lack of amphibole. Included in the andesitic blocks of the block-and-ash flow deposit are basaltic andesite enclaves with elongated and ellipsoidal forms and chilled margins. The enclaves have intersertal textures with brown glass between microphenocrysts of plagioclase, hornblende, pyroxene, and olivine, and minor proportions of phenocrysts of plagioclase, hornblende, and pyroxene. A compositional range obtained of blocks and enclaves resulted from mixing between andesite (866 °C ± 22) and basaltic andesite (enclaves, 932 °C ± 22), which may have triggered the explosive Pelean eruption. Vestiges of that mixing are preserved as complex compositional zones in plagioclase and clinopyroxene-rich reaction rims in amphibole in the andesite. Whole-rock chemistry, geothermometry, experimental petrology and modeling results suggest that after the mixing event the eruption tapped hybrid andesitic magma (≤ 900 °C) and ended with effusive dacitic magma (~ 825 °C), all of which were stored at ~ 200 MPa water pressure. A complex open-system evolution that involved crustal end-members best explains the generation of effusive dacite from the hybrid andesite. Amphibole in the dacite is rimmed by reaction products of plagioclase, orthopyroxene, and Fe-Ti oxides produced by decompression during ascent. Amphibole in the andesite

Magma storage and mixing conditions for the 1953-1974 eruption of Southwest Trident volcano, Katmai National Park, Alaska

USGS Publications Warehouse

Coombs, Michelle L.; Eichelberger, John C.; Rutherford, Malcom J.

2000-01-01

Between 1953 and 1974, approximately 0.5 km3 of andesite and dacite erupted from a new vent on the southwest flank of Trident volcano in Katmai National Park, Alaska, forming an edifice now known as Southwest (or New) Trident. Field, analytical, and experimental evidence shows that the eruption commenced soon after mixing of dacite and andesite magmas at shallow crustal levels. Four lava flows (58.3–65.5 wt% SiO2) are the dominant products of the eruption; these contain discrete andesitic enclaves (55.8–58.9 wt% SiO2) as well as micro- and macro-scale compositional banding. Tephra from the eruption spans the same compositional range as lava flows; however, andesite scoria (56–58.1 wt% SiO2) is more abundant relative to dacite tephra, and is the explosively erupted counterpart to andesite enclaves. Fe–Ti oxide pairs from andesite scoria show a limited temperature range, clustered around 1000 °C. Temperatures from grains found in dacite lavas possess a wider range; however, cores from large (>100 μm) magnetite and coexisting ilmenite give temperatures of ∼890 °C, taken to represent a pre-mixing temperature for the dacite. Water contents from dacite phenocryst melt inclusions and phase equilibria experiments on the andesite imply that the two magmas last resided at a water pressure of 90 MPa, and contained ∼3.5 wt% H2O, equivalent to 3 km depth if saturated. Unzoned pyroxene and sodic plagioclase in the dacite suggest that it likely underwent significant crystallization at this depth; highly resorbed anorthitic plagioclase from the andesite suggests that it originated at greater depths and underwent relatively rapid ascent until it reached 3 km, mixed with dacite, and erupted. Diffusion profiles in phenocrysts suggest that mixing preceded eruption of earliest lava by approximately one month. The lack of a compositional gap in the erupted rock suite indicates that thorough mixing of the andesite and dacite occurred quickly, via

Manupulation of microstructure, phase evolution and mechanical properties by devitrification of andesite for use as proppant

NASA Astrophysics Data System (ADS)

Koseski, Ryan P.

Small, roughly spherical ceramic particles, approximately 1mm in size are used for a number of applications including casting sands, catalysts, and cement fillers. The oil and natural gas industry utilizes such materials in tonnage quantities yearly as extraction aids. Particles intended for this application are referred to as proppants. Proppants are composed of materials that differ by density, strength and cost, and are selected on a site by site basis. Recently, competing usage and depletion of reserves of one of the most popular category of proppant materials, sintered aluminosilicates (e.g. kaolinite, bauxite) have driven the need for alternative raw materials for proppant manufacturing. Andesite, a by-product of mining operations in the south-west United States was identified as an abundant, readily available, and low cost alternative proppant material that can be fused and net-shaped into a glass which when crystallized results in microstructures which may offer substantial toughening and fracture characteristics which may serve to their advantage for use as proppants that do not decrease the permeability ("blind") the particle bed. This study addressed the devitrification behavior and its role on the mechanical properties of andesite-based glass-ceramic spheres for use as proppants. Timetemperature- transformation studies were performed to evaluate the devitrification behavior of andesite glass. Crystalline phase evolution and microstructural development were evaluated using quantitative x-ray diffraction, scanning electron microscopy, differential thermal analysis, and spectrophotometry. The andesite glass devitrification commenced with the precipitation of iron oxides (magnetite) which served as seeds for the epitaxial growth of dendritic pyroxenes. Mechanical properties, such as diametral compressive strength, fracture toughness, hardness, and fracture morphology were correlated with crystalline phase evolution. Selected heat treatments resulting in the

Pre-1991 sulfur transfer between mafic injections and dacite magma in the Mt. Pinatubo reservoir

USGS Publications Warehouse

Di, Muro A.; Pallister, J.; Villemant, B.; Newhall, C.; Semet, M.; Martinez, M.; Mariet, C.

2008-01-01

Before the 1991-1992 activity, a large andesite lava dome belonging to the penultimate Pinatubo eruptive period (Buag ??? 500??BP) formed the volcano summit. Buag porphyritic andesite contains abundant amphibole-bearing microgranular enclaves of basaltic-andesite composition. Buag enclaves have lower K2O and incompatible trace element (LREE, U, Th) contents than mafic pulses injected in the Pinatubo reservoir during the 1991-1992 eruptive cycle. This study shows that Buag andesite formed by mingling of a hot, water-poor and reduced mafic magma with cold, hydrous and oxidized dacite. Depending on their size, enclaves experienced variable re-equilibration during mixing/mingling. Re-equilibration resulted in hydration, oxidation and transfer of mobile elements (LILE, Cu) from the dacite to the mafic melts and prompted massive amphibole crystallization. In Buag enclaves, S-bearing phases (sulfides, apatite) and melt inclusions in amphibole and plagioclase record the evolution of sulfur partition among melt, crystal and fluid phases during magma cooling and oxidation. At high temperature, sulfur is partitioned between andesitic melt and sulfides (Ni-pyrrhotite). Magma cooling, oxidation and hydration resulted in exsolution of a S-Cl-H2O vapor phase at the S-solubility minimum near the sulfide-sulfate redox boundary. Primary magmatic sulfide (pyrrhotite) and xenocrystic sulfide grains (pyrite), recycled together with olivines and pyroxenes from old mafic intrusives, were replaced by Cu-rich phases (chalcopyrite, cubanite) and, partially, by Ba-Sr sulfate. Sulfides degassed and transformed into residual spongy magnetite in response to fS2 drop during final magma ascent and decompression. Our research suggests that a complete evaluation of the sulfur budget at Pinatubo must take into account the en route S assimilation from the country rocks. Moreover, this study shows that the efficiency of sulfur transfer between mafic recharges and injected magmas is controlled by the

Geochemical constraints on the origin of high-Mg andesites in the southernmost Okinawa Trough

NASA Astrophysics Data System (ADS)

Chu, C.; Chung, S.; Shinjo, R.; Gallet, S.; Wang, S.; Chen, C.

2007-12-01

The Okinawa Trough, extending from SW Kyushu to NE Taiwan, is a backarc basin of the Ryukyu arc-trench system due to subduction of the Philippine Sea plate under the Eurasian plate. The southernmost part of the Okinawa Trough (SPOT), however, does not situate in a simple backarc setting but is an embryonic rift zone in which early arc volcanism takes place. Kueishantao that consists mainly of andesitic flows dated to be ~7000 yr old is an emerged volcanic islet thus formed in SPOT. Here we report whole-rock major and trace element, and Sr-Nd-Pb-Hf isotope compositions of the Kueishantao andesites. Some of the samples have unexpectedly high magnesium, with MgO ≥ 5 wt.% and Mg# > 0.5, relative to their silica contents (SiO2 ~ 60 wt.%), so can be coined as high-Mg andesites (HMAs). These HMAs display enrichments in Cs, Rb, Ba, Th, U, LREE and Pb, and depletions in HFSE, in the incompatible element variation diagram. Their overall geochemical compositions are similar to those of the mean continental crust proposed by Rudnick and Fountain (1995). The HMAs have uniform radiogenic isotope ratios, with low ÕɛNd (-4.3 to -5.0), low ÕɛHf (-0.9 to -2.4), and high 87Sr/86Sr (~0.706) and 206Pb/204Pb (~18.75). In contrast to previous notion that calls for significant contamination of upper continental crust in the magma chamber, we propose the Kueishantao HMAs to have resulted from partial melting of the subducted sediments and altered Philippine Sea crust followed by melt-mantle interaction in the mantle wedge. This interpretation is consistent with seismic tomographic results under the SPOT region marking with a combination of collision/extension/subduction tectonic context off NE Taiwan.

Role of crystallizational differention in the origin of island-arc andesitic melts: evidence from data on melt inclusions and oxygen isotopes

NASA Astrophysics Data System (ADS)

Krasheninnikov, S. P.; Portnyagin, M.; Bindeman, I. N.; Bazanova, L. I.

2012-12-01

Several recent studies of melt inclusions in island-arc rocks revealed a strong bimodality of the melt compositions at the predominance of basic and silicic melts and the scarcity of intermediate melts with SiO2=59-66 wt% (e.g. [1]). These observations were used to interpret the origin of island-arc andesites by magma mingling, crustal assimilation and crystal accumulation rather than by fractional crystallization of basaltic magmas. In this work we addressed the question about the scarcity of andesitic melts in island-arc setting by systematic study of bulk compositions, melt inclusions and oxygen isotopes in minerals from Avachinskiy volcano in Kamchatka. We studied ~500 melt inclusions in 6 different mineral phases (Ol, Cpx, Opx, Pl, Amph, Mt), and concentrated on rapidly-quenched tephra samples from 40 Holocene eruptions of andesites and basaltic andesites. The melt inclusions span a large range of compositions from basalts to rhyolites. In comparison with host bulk tephra samples, melt inclusions tend to have more silicic compositions (up to 10 wt% of SiO2), and this disparity tend to increase with increasing SiO2 content in the host rocks. Both melt inclusion and host rock compositions form trends along the line dividing low- and middle-K island-arc series, and variations of major elements are continuous, without apparent bimodality, which is observed in data set from [1]. The MI statistical distribution is rather three-modal with maxima at ~56-58, ~66 and 74 wt% of SiO2. Much of the major element variability in MI can be explained by fractional crystallization from parental basaltic melts using numerical modeling of crystallization path. Magnetite crystallization starts at ~58 wt% of SiO2 and affects significantly on the evolutional path of melts. Abundant crystallization of magnetite lead to formation of more silica rich coexistent melts and change of crystallizing assemblage occurred at ~60 wt% of SiO2, when Opx replaced Ol, and Amph and Ap become stable

Shallow active-source imaging of an andesite dike in southern New Mexico: comparing Reftek Texan and Fairfield Z-Land recordings

NASA Astrophysics Data System (ADS)

Karplus, M. S.; Kaip, G.; Harder, S. H.; Johnson, K.

2016-12-01

In October 2015, the Advanced Exploration Seismology class at the University of Texas at El Paso together with additional volunteers acquired a 500-m active-source seismic profile across an andesite dike adjacent to the Rio Grande River near Sunland Park, New Mexico. Receivers included 100 RT-125 Reftek Texans with 4.5-Hz geophones, spaced every 5 m, and 47 Fairfield Z-Land nodes incorporating 5-Hz 3C geophones, spaced approximately every 10 m. A 8-gauge, 400 grain seismic gun source was fired every 5-10 m along most of the profile. Several locations at the ends of the profile experienced multiple gun shots, which have been stacked to increase signal-to-noise. We discuss similarities and differences in field methods and data acquired using the Texans compared to the nodes for a shallow active-source experiment. We extend the discussion to other types of active-source experiments using other recently-acquired nodal datasets. We observe changes in velocity between the andesite dike and surrounding lithologies, and create a seismic reflection image of the andesite dike.

Experimental and textural constraints on mafic enclave formation in volcanic rocks

USGS Publications Warehouse

Coombs, M.L.; Eichelberger, J.C.; Rutherford, M.J.

2002-01-01

We have used experiments and textural analysis to investigate the process of enclave formation during magma mixing at Southwest Trident volcano, Alaska. Andesite enclaves are present throughout the four dacite lava flows produced by the eruption, and resemble mafic enclaves commonly found in other volcanic rocks. Our experiments replicate the pressure-temperature-time path taken by enclave-forming andesite magma as it is engulfed in dacite during magma mixing. Pressure and temperature information for the andesite and dacite are from [Coombs et al., Contrib. Mineral. Petrol. 140 (2000) 99-118]. The andesite was annealed at 1000??C, and then cooled to 890??C at rates of 110??C h1, 10??C h1 and 2??C h1. Once cooled to 890??C, andesite was held at this lower temperature from times ranging from 1 to 40 h. The andesite that was cooled at the slower rates of 2??C h1 and 10??C h1 most resembles enclave groundmass texturally and compositionally. Based on simple thermal calculations, these rates are more consistent with cooling of the andesite groundmass below an andesite-dacite interface than with cooling of enclave-sized spheres. If enclaves do crystallize as spheres, post-crystallization disaggregation must occur. Calculations using the MELTS algorithm [Ghiorso and Sack, Contrib. Mineral. Petrol. 119 (1995) 197-212] show that for incoming andesite to become less dense than the dacite to become less dense ???34 volume % of its groundmass must crystallize to undergo~18 volume % vesiculation; these values are similar to those determined for Southwest Trident enclaves. Thus such crystallization may lead to 'flotation' of enclaves and be a viable mechanism for enclave formation and dispersal. The residual melt in the cooling experiments did not evolve to rhyolitic compositions such as seen in natural enclaves due to a lack of a decompression step in the experiments. Decompression experiments on Southwest Trident dacite suggest an average ascent rate for the eruption of ???2

Transient rheology of crystallizing andesitic magmas

NASA Astrophysics Data System (ADS)

de Biasi, L. J.; Chevrel, M. O.; Hanson, J. B.; Cimarelli, C.; Lavallée, Y.; Dingwell, D. B.

2012-04-01

The viscosity of magma strongly influences its rheological behaviour, which is a key determinant of magma transport processes and volcanic eruptions. Understanding the factors controlling the viscosity of magma is important to our assessment of hazards posed by active volcanoes. In nature, magmas span a very wide range in viscosity (10-1 to 1014 Pa s), depending on chemical composition (including volatile content), temperature, and importantly, crystal fraction, which further induces a complex strain rate dependence (i.e. non-Newtonian rheology). Here, we present results of transient viscosities of a crystallizing andesitic melt (57 wt.% SiO2) from Tungurahua volcano (Ecuador). We followed the experimental method developed by Vona et al. (2011) for the concentric cylinder apparatus, but optimized its implementation by leaving the spindle in situ before quenching the experimental products, to preserve the complete developed texture of the sample. The viscosity is investigated under super-liquidus (1400 ° C) and sub-liquidus temperatures (1162 and 1167 ° C). For each temperature increment, thermal equilibrium is achieved over a period of days while the spindle constantly stirs the magma. Simultaneous monitoring of the torque is used to calculate the apparent viscosity of the transient suspension. To get a better understanding of the nucleation and crystal growth processes that are involved at sub-liquidus conditions, further time-step experiments were carried out, where the samples were quenched at various equilibration stages. The mineralogical assemblage, as well as the crystal fraction, distribution and preferential alignment were then quantitatively analyzed. At temperatures below the liquidus, the suspension shows a progressive, but irregular increase of the relative shear viscosity. First, the viscosity slightly increases, possibly due to the crystallization of small, equant oxides and the formation of plagioclase nuclei. After some time (1.5-2.5 days

Tephra from andesitic Shiveluch volcano, Kamchatka, NW Pacific: chronology of explosive eruptions and geochemical fingerprinting of volcanic glass

NASA Astrophysics Data System (ADS)

Ponomareva, Vera; Portnyagin, Maxim; Pevzner, Maria; Blaauw, Maarten; Kyle, Philip; Derkachev, Alexander

2015-07-01

The ~16-ka-long record of explosive eruptions from Shiveluch volcano (Kamchatka, NW Pacific) is refined using geochemical fingerprinting of tephra and radiocarbon ages. Volcanic glass from 77 prominent Holocene tephras and four Late Glacial tephra packages was analyzed by electron microprobe. Eruption ages were estimated using 113 radiocarbon dates for proximal tephra sequence. These radiocarbon dates were combined with 76 dates for regional Kamchatka marker tephra layers into a single Bayesian framework taking into account the stratigraphic ordering within and between the sites. As a result, we report ~1,700 high-quality glass analyses from Late Glacial-Holocene Shiveluch eruptions of known ages. These define the magmatic evolution of the volcano and provide a reference for correlations with distal fall deposits. Shiveluch tephras represent two major types of magmas, which have been feeding the volcano during the Late Glacial-Holocene time: Baidarny basaltic andesites and Young Shiveluch andesites. Baidarny tephras erupted mostly during the Late Glacial time (~16-12.8 ka BP) but persisted into the Holocene as subordinate admixture to the prevailing Young Shiveluch andesitic tephras (~12.7 ka BP-present). Baidarny basaltic andesite tephras have trachyandesite and trachydacite (SiO2 < 71.5 wt%) glasses. The Young Shiveluch andesite tephras have rhyolitic glasses (SiO2 > 71.5 wt%). Strongly calc-alkaline medium-K characteristics of Shiveluch volcanic glasses along with moderate Cl, CaO and low P2O5 contents permit reliable discrimination of Shiveluch tephras from the majority of other large Holocene tephras of Kamchatka. The Young Shiveluch glasses exhibit wave-like variations in SiO2 contents through time that may reflect alternating periods of high and low frequency/volume of magma supply to deep magma reservoirs beneath the volcano. The compositional variability of Shiveluch glass allows geochemical fingerprinting of individual Shiveluch tephra layers which along

Contemporaneous trachyandesitic and calc-alkaline volcanism of the Huerto Andesite, San Juan Volcanic Field, Colorado, USA

USGS Publications Warehouse

Parat, F.; Dungan, M.A.; Lipman, P.W.

2005-01-01

Locally, voluminous andesitic volcanism both preceded and followed large eruptions of silicic ash-flow tuff from many calderas in the San Juan volcanic field. The most voluminous post-collapse lava suite of the central San Juan caldera cluster is the 28 Ma Huerto Andesite, a diverse assemblage erupted from at least 5-6 volcanic centres that were active around the southern margins of the La Garita caldera shortly after eruption of the Fish Canyon Tuff. These andesitic centres are inferred, in part, to represent eruptions of magma that ponded and differentiated within the crust below the La Garita caldera, thereby providing the thermal energy necessary for rejuvenation and remobilization of the Fish Canyon magma body. The multiple Huerto eruptive centres produced two magmatic series that differ in phenocryst mineralogy (hydrous vs anhydrous assemblages), whole-rock major and trace element chemistry and isotopic compositions. Hornblende-bearing lavas from three volcanic centres located close to the southeastern margin of the La Garita caldera (Eagle Mountain - Fourmile Creek, West Fork of the San Juan River, Table Mountain) define a high-K calc-alkaline series (57-65 wt % SiO2) that is oxidized, hydrous and sulphur rich. Trachyandesitic lavas from widely separated centres at Baldy Mountain-Red Lake (western margin), Sugarloaf Mountain (southern margin) and Ribbon Mesa (20 km east of the La Garita caldera) are mutually indistinguishable (55-61 wt % SiO2); they are characterized by higher and more variable concentrations of alkalis and many incompatible trace elements (e.g. Zr, Nb, heavy rare earth elements), and they contain anhydrous phenocryst assemblages (including olivine). These mildly alkaline magmas were less water rich and oxidized than the hornblende-bearing calc-alkaline suite. The same distinctions characterize the voluminous precaldera andesitic lavas of the Conejos Formation, indicating that these contrasting suites are long-term manifestations of San Juan

Formation of redox gradients during magma-magma mixing

NASA Astrophysics Data System (ADS)

Ruprecht, P.; Fiege, A.; Simon, A. C.

2015-12-01

Magma-mixing is a key process that controls mass transfer in magmatic systems. The variations in melt compositions near the magma-magma interface potentially change the Fe oxidation state [1] and, thus, affect the solubility and transport of metals. To test this hypothesis, diffusion-couple experiments were performed at 1000 °C, 150 MPa and QFM+4. Synthesized crystal-bearing cylinders of hydrous dacite and hydrous basaltic andesite were equilibrated for up to 80 h. The run products show that mafic components (Fe, Mg, etc.) were transported from the andesite into the dacite, while Si, Na and K diffused from the dacite into the andesite. A crystal dissolution sequence in the order of cpx, opx, plag, and spl/il was observed for the andesite. We combined μ-XANES spectroscopy at Fe K-edge [2] with two-oxide oxybarometry [3] to measure redox profiles within our experiments. Here, fO2 decreased towards the interface within the dacite and increased towards the interface within the andesite. This discontinuous fO2 evolution, with a sharp redox gradient of ~1.8 log fO2 units at the interface was maintained throughout the time-series despite the externally imposed fO2 of the vessel. We propose a combination of two mechanisms that create and sustain this redox gradient: 1) The dissolution of cpx and opx in the andesite mainly introduced Fe2+ into the melt, which diffused towards the dacite, lowering Fe3+/SFe near the interface. 2) Charge balance calculations in the melt during diffusive exchange suggest net positive charge excess in the andesite near the interface (i.e., oxidation) and net negative charge excess in the dacite near the interface (i.e., reduction). We suggest that this (metastable) redox layer can help to explain the contrasting Au/Cu ratios observed for arc-related porphyry-type ore deposits. [1] Moretti (2005), Ann. Geophys. 48, 583-608. [2] Cottrell et al. (2009), Chem. Geol. 268, 167-179. [3] Ghiorso and Evans (2008), Am. J. Sci. 308, 957-1039.

Fracture and compaction of andesite in a volcanic edifice.

PubMed

Heap, M J; Farquharson, J I; Baud, P; Lavallée, Y; Reuschlé, T

The failure mode of lava-dilatant or compactant-depends on the physical attributes of the lava, primarily the porosity and pore size, and the conditions under which it deforms. The failure mode for edifice host rock has attendant implications for the structural stability of the edifice and the efficiency of the sidewall outgassing of the volcanic conduit. In this contribution, we present a systematic experimental study on the failure mode of edifice-forming andesitic rocks (porosity from 7 to 25 %) from Volcán de Colima, Mexico. The experiments show that, at shallow depths (<1 km), both low- and high-porosity lavas dilate and fail by shear fracturing. However, deeper in the edifice (>1 km), while low-porosity (<10 %) lava remains dilatant, the failure of high-porosity lava is compactant and driven by cataclastic pore collapse. Although inelastic compaction is typically characterised by the absence of strain localisation, we observe compactive localisation features in our porous andesite lavas manifest as subplanar surfaces of collapsed pores. In terms of volcano stability, faulting in the upper edifice could destabilise the volcano, leading to an increased risk of flank or large-scale dome collapse, while compactant deformation deeper in the edifice may emerge as a viable mechanism driving volcano subsidence, spreading and destabilisation. The failure mode influences the evolution of rock physical properties: permeability measurements demonstrate that a throughgoing tensile fracture increases sample permeability (i.e. equivalent permeability) by about a factor of two, and that inelastic compaction to an axial strain of 4.5 % reduces sample permeability by an order of magnitude. The implication of these data is that sidewall outgassing may therefore be efficient in the shallow edifice, where rock can fracture, but may be impeded deeper in the edifice due to compaction. The explosive potential of a volcano may therefore be subject to increase over time if the

Petrogenesis of the Late Triassic diorites in the Hoh Xil area, northern Tibet: Insights into the origin of the high-Mg# andesitic signature of continental crust

NASA Astrophysics Data System (ADS)

Wang, Jun; Gou, Guo-Ning; Wang, Qiang; Zhang, Chunfu; Dan, Wei; Wyman, Derek A.; Zhang, Xiu-Zheng

2018-02-01

An integrated petrologic, geochronologic, major and trace element geochemical, and Sr-Nd-Hf isotopic study of Late Triassic ( 215 Ma) diorites from the Hoh Xil area, northern Tibet, provides new constraints on the genesis of intermediate magmas and insights into the origin of the high-Mg# andesitic signature of continental crust. These dioritic rocks are characterized by high MgO contents (3.3-5.0 wt%) and Mg# values (50-57) comparable to the estimates for the bulk continental crust at the same level of SiO2 contents (61.1-64.5 wt%). They also display continental crust-like trace element distribution patterns and uniformly enriched isotope compositions ([87Sr/86Sr]i = 0.7081 to 0.7094, ɛNd[t] = - 8.0 to - 6.9, and ɛHf[t]zircon = - 10.1 to - 5.0). Combining our results with published data from crystallization experiments, we propose that they were probably produced by fractional crystallization from a primitive andesite parent, rather than a primitive basalt parent. This parental magma may be geochemically similar to the roughly contemporaneous primitive andesites in the adjacent Malanshan area of northern Tibet. Our compilation of modern arc lavas shows that progressive fractional crystallization of primitive andesites is also required to reproduce the Mg# versus SiO2 array for natural arc magmas, in addition to differentiation of mantle-derived primitive basaltic magmas and/or mixing of basaltic with felsic magmas. Therefore, we emphasize that fractional crystallization of primitive andesitic magmas is potentially a frequent occurrence in arc crust and hence may play an important role in producing the high-Mg# signature of intermediate magmas comprising the continental crust.

Pyroclast textural variation as an indicator of eruption column steadiness in andesitic Plinian eruptions at Mt. Ruapehu

USGS Publications Warehouse

Pardo, Natalia; Cronin, Shane J.; Wright, Heather M.N.; Schipper, C. Ian; Smith, Ian; Stewart, Bob

2014-01-01

Between 27 and 11 cal. ka BP, a transition is observed in Plinian eruptions at Mt. Ruapehu, indicating evolution from non-collapsing (steady and oscillatory) eruption columns to partially collapsing columns (both wet and dry). To determine the causes of these variations over this eruptive interval, we examined lapilli fall deposits from four eruptions representing the climactic phases of each column type. All eruptions involve andesite to basaltic andesite magmas containing plagioclase, clinopyroxene, orthopyroxene and magnetite phenocrysts. Differences occur in the dominant pumice texture, the degree of bulk chemistry and textural variability, the average microcrystallinity and the composition of groundmass glass. In order to investigate the role of ascent and degassing processes on column stability, vesicle textures were quantified by gas volume pycnometry (porosity), X-ray synchrotron and computed microtomography (μ-CT) imagery from representative clasts from each eruption. These data were linked to groundmass crystallinity and glass geochemistry. Pumice textures were classified into six types (foamy, sheared, fibrous, microvesicular, microsheared and dense) according to the vesicle content, size and shape and microlite content. Bulk porosities vary from 19 to 95 % among all textural types. Melt-referenced vesicle number density ranges between 1.8 × 102 and 8.9 × 102 mm−3, except in fibrous textures, where it spans from 0.3 × 102 to 53 × 102 mm−3. Vesicle-free magnetite number density varies within an order of magnitude from 0.4 × 102 to 4.5 × 102 mm−3 in samples with dacitic groundmass glass and between 0.0 and 2.3 × 102 mm−3 in samples with rhyolitic groundmass. The data indicate that columns that collapsed to produce pyroclastic flows contained pumice with the greatest variation in bulk composition (which overlaps with but extends to slightly more silicic compositions than other eruptive products); textures

Peninsular terrane basement ages recorded by Paleozoic and Paleoproterozoic zircon in gabbro xenoliths and andesite from Redoubt volcano, Alaska

USGS Publications Warehouse

Bacon, Charles R.; Vazquez, Jorge A.; Wooden, Joseph L.

2012-01-01

Historically Sactive Redoubt volcano is an Aleutian arc basalt-to-dacite cone constructed upon the Jurassic–Early Tertiary Alaska–Aleutian Range batholith. The batholith intrudes the Peninsular tectonostratigraphic terrane, which is considered to have developed on oceanic basement and to have accreted to North America, possibly in Late Jurassic time. Xenoliths in Redoubt magmas have been thought to be modern cumulate gabbros and fragments of the batholith. However, new sensitive high-resolution ion microprobe (SHRIMP) U-Pb ages for zircon from gabbro xenoliths from a late Pleistocene pyroclastic deposit are dominated by much older, ca. 310 Ma Pennsylvanian and ca. 1865 Ma Paleoproterozoic grains. Zircon age distributions and trace-element concentrations indicate that the ca. 310 Ma zircons date gabbroic intrusive rocks, and the ca. 1865 Ma zircons also are likely from igneous rocks in or beneath Peninsular terrane basement. The trace-element data imply that four of five Cretaceous–Paleocene zircons, and Pennsylvanian low-U, low-Th zircons in one sample, grew from metamorphic or hydrothermal fluids. Textural evidence of xenocrysts and a dominant population of ca. 1865 Ma zircon in juvenile crystal-rich andesite from the same pyroclastic deposit show that this basement has been assimilated by Redoubt magma. Equilibration temperatures and oxygen fugacities indicated by Fe-Ti–oxide minerals in the gabbros and crystal-rich andesite suggest sources near the margins of the Redoubt magmatic system, most likely in the magma accumulation and storage region currently outlined by seismicity and magma petrology at ∼4–10 km below sea level. Additionally, a partially melted gabbro from the 1990 eruption contains zircon with U-Pb ages between ca. 620 Ma and ca. 1705 Ma, as well as one zircon with a U-Th disequilibrium model age of 0 ka. The zircon ages demonstrate that Pennsylvanian, and probably Paleoproterozoic, igneous rocks exist in, or possibly beneath, Peninsular

Evidence for tectonic, lithologic, and thermal controls on fracture system geometries in an andesitic high-temperature geothermal field

NASA Astrophysics Data System (ADS)

Massiot, Cécile; Nicol, Andrew; McNamara, David D.; Townend, John

2017-08-01

Analysis of fracture orientation, spacing, and thickness from acoustic borehole televiewer (BHTV) logs and cores in the andesite-hosted Rotokawa geothermal reservoir (New Zealand) highlights potential controls on the geometry of the fracture system. Cluster analysis of fracture orientations indicates four fracture sets. Probability distributions of fracture spacing and thickness measured on BHTV logs are estimated for each fracture set, using maximum likelihood estimations applied to truncated size distributions to account for sampling bias. Fracture spacing is dominantly lognormal, though two subordinate fracture sets have a power law spacing. This difference in spacing distributions may reflect the influence of the andesitic sequence stratification (lognormal) and tectonic faults (power law). Fracture thicknesses of 9-30 mm observed in BHTV logs, and 1-3 mm in cores, are interpreted to follow a power law. Fractures in thin sections (˜5 μm thick) do not fit this power law distribution, which, together with their orientation, reflect a change of controls on fracture thickness from uniform (such as thermal) controls at thin section scale to anisotropic (tectonic) at core and BHTV scales of observation. However, the ˜5% volumetric percentage of fractures within the rock at all three scales suggests a self-similar behavior in 3-D. Power law thickness distributions potentially associated with power law fluid flow rates, and increased connectivity where fracture sets intersect, may cause the large permeability variations that occur at hundred meter scales in the reservoir. The described fracture geometries can be incorporated into fracture and flow models to explore the roles of fracture connectivity, stress, and mineral precipitation/dissolution on permeability in such andesite-hosted geothermal systems.

Paleoproterozoic andesitic volcanism in the southern Amazonian craton (northern Brazil); lithofacies analysis and geodynamic setting

NASA Astrophysics Data System (ADS)

Roverato, Matteo; Juliani, Caetano; Capra, Lucia; Dias Fernandes, Carlos Marcelo

2016-04-01

Precambrian volcanism played an important role in geological evolution and formation of new crust. Most of the literature on Precambrian volcanic rocks describes settings belonging to subaqueous volcanic systems. This is likely because subaerial volcanic rocks in Proterozoic and Archean volcano-sedimentary succession are poorly preserved due to erosive/weathering processes. The late Paleoproterozoic Sobreiro Formation (SF) here described, seems to be one of the rare exceptions to the rule and deserves particular attention. SF represents the subaerial expression of an andesitic magmatism that, linked with the upper felsic Santa Rosa F., composes the Uatumã Group. Uatumã Group is an extensive magmatic event located in the Xingú region, southwestern of Pará state, Amazonian Craton (northern Brazil). The Sobreiro volcanism is thought to be related to an ocean-continent convergent margin. It is characterized by ~1880 Ma well-preserved calc-alkaline basaltic/andesitic to andesitic lava flows, pyroclastic rocks and associated reworked successions. The superb preservation of its rock-textures allowed us to describe in detail a large variety of volcaniclastic deposits. We divided them into primary and secondary, depending if they result from a direct volcanic activity (pyroclastic) or reworked processes. Our study reinforces the importance of ancient volcanic arcs and rocks contribution to the terrestrial volcaniclastic sedimentation and evolution of plate tectonics. The volcanic activity that produced pyroclastic rocks influenced the amount of detritus shed into sedimentary basins and played a major role in the control of sedimentary dispersal patterns. This study aims to provide, for the first time, an analysis of the physical volcanic processes for the subaerial SF, based in field observation, lithofacies analysis, thin section petrography and less geochemical data. The modern volcanological approach here used can serve as a model about the evolution of Precambrian

The 1994-2001 eruptive period at Rabaul, Papua New Guinea: Petrological and geochemical evidence for basalt injections into a shallow dacite magma reservoir, and significant SO2 flux

NASA Astrophysics Data System (ADS)

Patia, H.; Eggins, S. M.; Arculus, R. J.; McKee, C. O.; Johnson, R. W.; Bradney, A.

2017-10-01

The eruptions that began at Rabaul Caldera on 19 September 1994 had two focal points, the vents Tavurvur and Vulcan, located 6 km apart on opposing sides of the caldera. Vulcan eruptives define a tight cluster of dacite compositions, whereas Tavurvur eruptives span an array from equivalent dacite compositions to mafic andesites. The eruption of geochemically and mineralogically identical dacites from both vents indicates sourcing from the same magma reservoir. This, together with previously reported H2O-CO2 volatile contents of dacite melt inclusions, a caldera-wide seismic low-velocity zone, and a seismically active caldera ring fault structure are consistent with the presence at 3-6 km depth of an extensive, tabular dacitic magma body having volume of about 15-150 km3. The Tavurvur andesites form a linear compositional array and have strongly bimodal phenocryst assemblages that reflect dacite hybridisation with a mafic basalt. The moderately large volume SO2 flux documented in the Tavurvur volcanic plume (and negligible SO2 flux in the Vulcan plume) combined with high dissolved S contents of basaltic melt inclusions trapped in olivine of Tavurvur eruptives, indicate that the amount of degassed basaltic magma was 0.1 km3 and suggest that the injection of this magma was confined to the Tavurvur-side (eastern to northeastern sector) of the caldera. Circumstantial evidence suggests that the eruption was triggered and evolved in response to a series of basaltic magma injections that may have commenced in 1971 and continued up until at least the start of the 1994 eruptions. The presence of zoned plagioclase phenocrysts reflecting older basalt-dacite interaction events (i.e. anorthite cores overgrown with thick andesine rims), evaluation of limited available data for the products of previous eruptions in 1878 and 1937-1943, and the episodic occurrence of major intra-caldera seismo-deformational events indicates that the shallow magma system at Rabaul Caldera is

Contortionist bubbles in andesitic enclaves: implications for gas migration and phase segregation in crystal-rich magmas.

NASA Astrophysics Data System (ADS)

Oppenheimer, J. C.; Cashman, K. V.; Rust, A.; Dobson, K. J.; Bacon, C. R.; Dingwell, D. B.

2016-12-01

In order to constrain gas migration behaviors in crystal-rich magmas, we compare results of analogue experiments to frozen structures in andesitic enclaves. In the analogue experiments air was injected into mixtures of syrup and particles sandwiched between glass plates. We observed a significant increase in bubble deformation and coalescence when particle fractions increased beyond a critical value (the random loose packing). At high particle fractions, bubble growth re-organized (compacted) the particles adjacent to the bubble walls. This caused liquid segregation into patches within the particle suspension and into large void spaces near the outer edge of experiments. We compare these experiments to void morphologies in a 58 x 70 x 73 cm andesitic enclave from silicic-andesite lava flows of Mt Mazama, Oregon (Bacon, 1986). This enclave is zoned, with a vesicle-rich center and a glass-rich rim, suggesting gas-driven melt segregation from the center to the rim. We use both 2D (optical microscopy and SEM) and 3D (X-ray tomography) techniques to image crystal textures and bubble shapes. The center of the enclave bears scattered patches of groundmass in the main phenocryst framework. These patches are similar to those observed in experiments, and thus melt segregation in the enclave may have occurred both toward the rim and toward these patches. Bubble morphologies reveal two main types of bubbles. (1) Lobate and finger-like bubbles, similar to the deformed bubbles in experiments, are found exclusively in the groundmass patches. They are also often associated with compacted crystal structures at the bubble walls. (2) Diktytaxitic textures - angular bubbles flattened against phenocrysts - are abundant in the crystal networks. These voids are entirely connected in 3D and formed the gas-rich center of the enclave. They likely represent a gas migration regime where the expanding gas front cannot deform the crystal structure but instead invades the pore-space between

Mafic enclaves in dacitic domes and their relation with La Poruña scoria cone, Central Andes, northern Chile

NASA Astrophysics Data System (ADS)

González-Maurel, O. P.; Gallmeyer, G.; Godoy, B.; Menzies, A.; le Roux, P. J.; Harris, C.

2017-12-01

Chao Dacite, Chillahuita, Cerro Pabellón, Chanka, Chac-Inca, and Cerro La Torta (or Tocorpuri) are dacitic domes of late Pleistocene age (30 to 140 ka; Renzulli et al., 2006; Tierney et al., 2016) located in Northern Chilean Central Andean province (NCCA; 17°20'S - 27°40'S). While, La Poruña is a 180 m high basaltic-andesite scoria cone erupted ca. 100 ka (Wörner et al., 2000). This scoria cone is also located at the NCCA, 26 km to the SW of Chanka and 45 km to the NW of Chao Dacite. The dacitic domes are generally porphyritic and highly crystalline lavas (30 - 50 vol % phenocrysts, plagioclase > biotite > amphibole > quartz ≥ accessory), with hyalopilitic or intersertal groundmass. These domes contain mafic enclaves, mostly andesite in composition, with plagioclase > amphibole > biotite ≥ clinopyroxene ≥ olivine ≥ accessory phenocryst (10 - 20 vol %) in a lightly oxidized groundmass with intersertal or intergranular textures. In contrast, La Poruña rocks are mostly aphanitic (75 - 85 vol % groundmass) and highly vesicular, with plagioclase > olivine ≥ clinopyroxene ≥ orthopyroxene phenocrysts in an intersertal or hyalopilitic groundmass. Although petrographically different, the composition (57 wt % SiO2; 580 ppm Sr, 87Sr/86Sr = 0.7066) of mafic enclaves from Cerro Pabellón dome are similar to the lava flows and pyroclastic blocks of La Poruña scoria cone (55 - 59 wt % SiO2; 560 - 610 ppm Sr; 0.7062 - 0.7066 87Sr/86Sr). Based on this data and the eruption ages of these volcanic structures, we suggest that the mafic enclaves and La Poruña magmas are co-genetic. Thus, we propose that the genesis of these mafic enclaves is associated with the origin of less evolved parental magmas erupted in the NCCA, such as those from La Poruña. In this case, the mafic enclaves would represent batches of less evolved magmas that ascended from deeper sources and probably contributed in the eruption of the dacitic domes. Renzulli et al., 2006. In XI Congreso Geol

A Two-Stage Model for Origin of Al-rich Crustal Xenoliths in Miocene Andesite, Diablo Range, West-Central California

NASA Astrophysics Data System (ADS)

Metzger, E. P.; Ernst, W. G.

2003-12-01

Miocene ( ˜ 8-10.5 Ma) andesite exposed as small plugs and dikes in the Diablo Range of west-central California encloses scattered xenoliths with diverse compositions and textures. The andesite is part of the Diablo Range Volcanics (DRV), a mafic to intermediate suite that is broadly coeval with and may be erosional remnants of the more extensive Quien Sabe Field located to the south and east. The DRV suite is inferred to be part of a northwestwardly younging sequence of volcanic fields that may be related to migration of the Mendocino Triple Junction (MTJ). Two basic categories of xenoliths are present: (1) metasedimentary rocks including quartzite, biotite schist, garnet-clinopyroxene gneiss, and distinctive sillimanite-corundum rocks; and (2) gabbroic and dioritic rocks exhibiting plutonic textures. Preliminary analysis has focused on aluminous xenoliths in which blocky porphyroblasts consisting of intergrown plagioclase, corundum, and hercynite +/- sillimanite +/- alkali feldspar up to ˜ 2 cm in length are surrounded by a very fine-grained granoblastic matrix of plagioclase, orthopyroxene, and hercynite +/- biotite +/- alkali feldspar +/- minor quartz. Glass is present both within the inclusions and in the surrounding matrix. The square to elongate outlines of the plagioclase-corundum inclusions suggest that they are pseudomorphic after andalusite. The corundum-bearing xenoliths are interpreted as the products of two stages of high T-low P metamorphism. The first event involved mid-crustal metamorphism (reflecting cessation of outboard subduction/refrigeration?) to produce andalusite-bearing hornfels; other phases probably included K-feldspar, Na-plagioclase, muscovite, biotite, and quartz. The second stage of recrystallization took place when the previously metamorphosed wall rock was incorporated in andesitic magma, possibly during passage of the MTJ. In response to heating by the magma, andalusite was replaced by corundum, plagioclase +/- sillimanite

Upper Carboniferous retroarc volcanism with submarine and subaerial facies at the western Gondwana margin of Argentina

NASA Astrophysics Data System (ADS)

Koukharsky, M.; Kleiman, L.; Etcheverría, M.; Quenardelle, S.; Bercowski, F.

2009-04-01

During Late Carboniferous times a continental magmatic arc developed at the western margin of Gondwana in South America, as several marine sedimentary basins were formed at the same time in the retroarc region. North of 33°S, at Cordón Agua del Jagüel, Precordillera of Mendoza, Argentina, a volcanic sequence crops out which was emplaced in a submarine environment with some subaerial exposures, and it is intercalated in marine sediments of Agua del Jagüel Formation, which fills of one of these retroarc basins. This paper presents, for the first time, a facies analyses together with geochemical and isotopic data of this volcanic suite, suggesting its deposition in an ensialic retroarc marine basin. The volcanic succession comprises debris flows with either sedimentary or volcanic fragments, base surge, resedimented massive and laminated dacitic-andesitic hyaloclastite, pillow lava, basic hyaloclastite and dacitic-andesitic lavas and hyaloclastite facies. Its composition is bimodal, either basaltic or dacitic-andesitic. The geochemistry data indicate a subalkaline, low K calk-alkaline and metaluminous affinity. The geochemistry of the basalts points to an origin of the magmas from a depleted mantle source with some crustal contamination. Conversely, the geochemistry of the dacites-andesites shows an important participation of both crustal components and subduction related fluids. A different magmatic source for the basalts than for the dacites-andesites is also supported by Sr and Nd isotopic initial ratios and Nd model ages. The characteristics of this magmatic suite suggest its emplacement in an extensional setting probably associated with the presence of a steepened subduction zone at this latitude during Upper Carboniferous times.

Erratum: Correction to: Emplacement controls for the basaltic-andesitic radial dikes of Summer Coon volcano and implications for flank vents at stratovolcanoes

NASA Astrophysics Data System (ADS)

Harp, A. G.; Valentine, G. A.

2018-06-01

In the article "Emplacement controls for the basaltic-andesitic radial dikes of Summer Coon volcano and implications for flank vents at stratovolcanoes", the vertical axis for Fig. 8 a was incorrectly labeled (i.e., the value for dikes per km2).

Generation of high-Mg andesites in the Kueishantao volcano, the southernmost part of the Okinawa Trough

NASA Astrophysics Data System (ADS)

Chu, C.; Chung, S.; Shinjo, R.; Wang, S.; Chen, C.

2004-12-01

Kueishantao is an emerged volcanic islet located at the western end of the Southernmost Part of Okinawa Trough (SPOT). The Okinawa Trough, extending from SW Kyushu, Japan to NE Taiwan, is widely regarded as a backarc basin that is built behind the Ryukyu arc-trench system owing to subduction of the Philippine Sea plate underneath the Eurasian plate. The SPOT, however, is not a simple backarc basin but an embryonic rift zone in which early arc volcanism occurs as a result of the Ryukyu subduction (Chung et al., 2000). The Kueishantao is one of such volcanoes thus formed in the SPOT and consists mainly of andesitic lava flows dated to be ˜7000 yr old. In this study, we report whole rock major and trace element, and Sr-Nd-Pb isotope compositions of the Kueishantao andesites. The results indicate that some of the samples have unexpectedly high magnesium, with MgO ≥ 5 wt.% and Mg# > 0.5, relative to their silica contents (SiO2≈ 60 wt.%), which allow them to be coined as high-Mg andesites (HMAs). In the incompatible element variation diagram, these Kueishantao HMAs exhibit enrichments in the large ion lithophile elements and Th, U and Pb, and depletions in the high field strength elements, features typical of arc lavas from the Ryukyu subduction zone as well as convergent margins worldwide. More interestingly, their overall geochemical compositions are very similar to those of the mean continental crust proposed by Rudnick and Fountain (1995). The Kueishantao HMAs have uniform isotope compositions, with low ɛ Nd (-4.3 to -5.0), high Sr (87Sr/86Sr¡Ö≈ 0.706) and Pb (18.75, 15.68 and 39.02 of 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb, respectively) ratios. Such ¡°continental¡± isotopic signatures have led previous workers (Chen et al., 1995) to argue significant crustal contamination as a major petrogenetic process, but our evaluation shows that this simple binary mixing model fails to explain their geochemical and Pb isotope systematics. We propose, instead

Morphological features of Miocene submarine coherent lavas from the ``Green Tuff'' basins: examples from basaltic and andesitic rocks from the Shimokita Peninsula, northern Japan

NASA Astrophysics Data System (ADS)

Yamagishi, Hiromitsu

1991-04-01

Basaltic and andesitic volcanic rocks of Miocene age exposed in the Shimokita Peninsula, northern Japan, illustrate morphological features of typical submarine coherent lavas of the “Green Tuff” basins in Japan. They are pillow lobes with surface structures, such as ropey wrinkles, corrugations, spreading cracks and tensional cracks, and lava lobes composed of a lithic core and glassy border zone or rim with an in-situ breccia zone grading outward into surrounding hyaloclastite. In addition they include massive lavas with columnar joints, and jointed dykes. The submarine coherent lavas and dykes are commonly associated with hyaloclastic breccias, such as pillow fragment breccia and angular fragment breccia. The descriptions of the Miocene volcanic rocks in the Shimokita Peninsula provide good criteria for recognition of submarine coherent lavas of basalt and andesite.

Geochemistry of the 1989-1990 eruption of redoubt volcano: Part I. Whole-rock major- and trace-element chemistry

USGS Publications Warehouse

Nye, C.J.; Swanson, S.E.; Avery, V.F.; Miller, T.P.

1994-01-01

The 1989-1990 eruption of Redoubt Volcano produced medium-K calc-alkaline andesite and dacite of limited compositional range (58.2-63.4% SiO2) and entrained quenched andesitic inclusions (55% SiO2) which bear chemical similarities to the rest of the ejecta. The earliest (December 15) magmas are pumiceous, often compositionally banded, and the majority is relatively mafic ( 60 wt.%). They have Mg, Cr, Ni, Sc, and V contents higher than the andesites, but lower than Redoubt basalts and basaltic andesites. Thus, they may be crystallization products of andesites, but do not represent the cumulate residue of basalt fractionation. The xenoliths were probably derived from a shallow or intermediate crustal chamber. ?? 1994.

Eruptive history and petrology of Mount Drum volcano, Wrangell Mountains, Alaska

USGS Publications Warehouse

Richter, D.H.; Moll-Stalcup, E. J.; Miller, T.P.; Lanphere, M.A.; Dalrymple, G.B.; Smith, R.L.

1994-01-01

Mount Drum is one of the youngest volcanoes in the subduction-related Wrangell volcanic field (80x200 km) of southcentral Alaska. It lies at the northwest end of a series of large, andesite-dominated shield volcanoes that show a northwesterly progression of age from 26 Ma near the Alaska-Yukon border to about 0.2 Ma at Mount Drum. The volcano was constructed between 750 and 250 ka during at least two cycles of cone building and ring-dome emplacement and was partially destroyed by violent explosive activity probably after 250 ka. Cone lavas range from basaltic andesite to dacite in composition; ring-domes are dacite to rhyolite. The last constructional activity occured in the vicinity of Snider Peak, on the south flank of the volcano, where extensive dacite flows and a dacite dome erupted at about 250 ka. The climactic explosive eruption, that destroyed the top and a part of the south flank of the volcano, produced more than 7 km3 of proximal hot and cold avalanche deposits and distal mudflows. The Mount Drum rocks have medium-K, calc-alkaline affinities and are generally plagioclase phyric. Silica contents range from 55.8 to 74.0 wt%, with a compositional gap between 66.8 and 72.8 wt%. All the rocks are enriched in alkali elements and depleted in Ta relative to the LREE, typical of volcanic arc rocks, but have higher MgO contents at a given SiO2, than typical orogenic medium-K andesites. Strontium-isotope ratios vary from 0.70292 to 0.70353. The compositional range of Mount Drum lavas is best explained by a combination of diverse parental magmas, magma mixing, and fractionation. The small, but significant, range in 87Sr/86Sr ratios in the basaltic andesites and the wide range of incompatible-element ratios exhibited by the basaltic andesites and andesites suggests the presence of compositionally diverse parent magmas. The lavas show abundant petrographic evidence of magma mixing, such as bimodal phenocryst size, resorbed phenocrysts, reaction rims, and

Measurements of the Activity of dissolved H2O in an Andesite Melt

NASA Astrophysics Data System (ADS)

Moore, G. M.; Touran, J. P.; Pu, X.; Kelley, K. A.; Cottrell, E.; Ghiorso, M. S.

2016-12-01

The large effect of dissolved H2O on the physical and chemical nature of silicate melts, and its role in driving volcanism, is well known and underscores the importance of this volatile component. A complete understanding of the chemical behavior of dissolved H2O in silicate melts requires the quantification of its thermodynamic activity as a function of pressure, temperature, and melt composition, particularly at low H2O contents (i.e. at under-saturated conditions). Knowledge of the activity of H2O in silicate melts at H2O-undersaturated conditions will improve our understanding of hydrous phase equilibria, as well as our models of physical melt properties. Measurement of the activity of any silicate melt component, much less that of a volatile component such as H2O, is a difficult experimental task however. By using a modified double capsule design (Matjuschkin et al, 2015) to control oxygen fugacity in piston cylinder experiments, along with high precision X-ray absorption techniques (XANES) to measure iron oxidation state in silicate glasses (Cottrell et al, 2009), we are able to constrain the H2O activity in silicate melts at under-saturated conditions. Preliminary results on an andesite melt with low H2O content (3 wt%) have been shown (Moore et al, 2016) to match predicted H2O activity values calculated using the H2O equation of state of Duan and Zhang (1996) and the H2O solubility model of Ghiorso and Gualda (2015). More recent results on the same andesite melt containing approximately 5 wt% H2O however show a large negative deviation from the predicted values. Reversal experiments involving an oxidized starting material are ongoing, as well as further characterization of the samples to detect the presence of possible contaminants that would induce reduction of the melt beyond that related to the H2O activity (e.g. graphite contamination).

The glaciovolcanic evolution of an andesitic edifice, South Crater, Tongariro volcano, New Zealand

NASA Astrophysics Data System (ADS)

Cole, R. P.; White, J. D. L.; Conway, C. E.; Leonard, G. S.; Townsend, D. B.; Pure, L. R.

2018-02-01

Unusual deposits, mapped and logged in detail, around the summit area of Tongariro volcano, Tongariro Volcanic Centre, New Zealand indicate that the construction and evolution of a substantial portion of this andesitic stratovolcano was beneath a significant ice cap or summit glacier. As the edifice was built under and through the overlying ice, the style of volcanism evolved in a complex history of growth. Initially, a ≥ 100 m thick, widespread hyaloclastite deposit was emplaced within a subglacial, eruption-formed meltwater lake. This was followed by several phases of effusive and explosive eruptions, producing lava flows and primary volcaniclastic deposits emplaced along channels carved into the ice by heated meltwater. The clastic deposits contain quenched bombs and structural features that indicate waterlain transport and emplacement, and soft sediment deformation. Such accumulation of water on a steep-sided edifice without evidence for a subaerial crater lake, along with lava flow features indicating confinement, suggest that a substantial summit glacier was responsible for the production and retention of water, and the architecture of these deposits. Recent studies at nearby Ruapehu volcano have provided good evidence for glaciovolcanic interactions during the last glacial period. However, until now, little was known of the physical lava-ice interactions in the Centre during the last interglacial period and the earlier part of the last glacial period (110-64 ka). These new data support a reinterpretation for the volcanic evolution of the older Tongariro edifice and the emplacement mechanisms of primary volcaniclastic deposits. They also help to constrain local ice thicknesses and extents at the times of eruption. In addition, this study contributes to a sparse global catalogue of glaciovolcanic deposits of andesitic composition, particularly of primary volcaniclastics preserved at mid-latitude stratovolcanoes. The variety of deposit types indicates a

Mount St. Helens eruptive behavior during the past 1500 yr.

USGS Publications Warehouse

Hoblitt, R.P.; Crandell, D.R.; Mullineaux, D.R.

1980-01-01

During the past 1500 yr Mount St. Helens, Washington, has repeatedly erupted dacite domes, tephra, and pyroclastic flows as well as andesite lava flows and tephra. Two periods of activity prior to 1980, each many decades long, were both initiated by eruptions of volatile-rich dacite which were followed by andesite, then by dacite. A third eruptive period was characterized by the eruption of volatile-poor dacite that formed a dome and minor pyroclastic flows. The prolonged duration of some previous eruptive periods suggests that the current activity could continue for many years. The volatile-rich dacite that has been erupted to date probably will be followed by gas-poor magma, but it cannot yet be predicted whether a more mafic magma will be extruded during the current eruptive period.-Authors

Explosions of andesitic volcanoes in Kamchatka and danger of volcanic ash clouds to aviation

NASA Astrophysics Data System (ADS)

Gordeev, E. I.; Girina, O. A.; Neal, C. A.

2010-12-01

There are 30 active volcanoes in Kamchatka and 4 of them continuously active. The explosions of andesitic volcanoes (Bezymianny and Sheveluch) produce strong and fast ash plumes, which can rich high altitude (up to 15 km) in short time. Bezymianny and Sheveluch are the most active volcanoes of Kamchatka. A growth of the lava dome of Bezymianny into the explosive crater continues from 1956 till present. Nine strong explosive eruptions of the volcano associated with the dome-building activity occurred for last 5 years in: 2005, January 11 and November 30; 2006, May 09 and December 24; 2007, May 11 and October 14-15; 2008, August 19; 2009, December 16-17 and 2010, May 31. Since 1980, a lava dome of Sheveluch has being growing at the bottom of the explosive crater, which has formed as the result of the catastrophic eruption in 1964. Strong explosive eruptions of the volcano associated with the dome-building activity occurred in: 1993, April 22; 2001, May 19-21; 2004, May 09; 2005, February 27 and September 22; 2006, December 25-26; 2007, March 29 and December 19; 2009, April 26-28 and September 10-11. Strong explosive eruption of andesitic volcanoes is the most dangerous for aircraft because in a few hours or days in the atmosphere and the stratosphere can produce about several cubic kilometers of volcanic ash and aerosols. Volcanic ash is an extremely abrasive, as it consists of acute-angled rock fragments and volcanic glass. Due to the high specific surface of andesitic ash particles are capable of retaining an electrostatic charge and absorb droplets of water and corrosive acids. Ash plumes and the clouds, depending on the power of the eruption, the strength and wind speed, can travel thousands of kilometers from the volcano for several days, remaining hazardous to aircraft, as the melting temperature of small particles of ash below the operating temperature of jet engines. To reduce the risk of collision of aircraft with ash clouds of Kamchatkan volcanoes, was

Crystallization of oxidized, moderately hydrous arc basalt at mid- to lower-crustal pressures: implications for andesite genesis

NASA Astrophysics Data System (ADS)

Blatter, Dawnika L.; Sisson, Thomas W.; Hankins, W. Ben

2013-09-01

This study focuses on the production of convergent margin calc-alkaline andesites by crystallization-differentiation of basaltic magmas in the lower to middle crust. Previous experimental studies show that dry, reduced, subalkaline basalts differentiate to tholeiitic (high Fe/Mg) daughter liquids, but the influences of H2O and oxidation on differentiation are less well established. Accordingly, we performed crystallization experiments at controlled oxidized fO2 (Re-ReO2 ≈ ΔNi-NiO + 2) on a relatively magnesian basalt (8.7 wt% MgO) typical of mafic magmas erupted in the Cascades near Mount Rainier, Washington. The basalt was synthesized with 2 wt% H2O and run at 900, 700, and 400 MPa and 1,200 to 950 °C. A broadly clinopyroxenitic crystallization interval dominates near the liquidus at 900 and 700 MPa, consisting of augite + olivine + orthopyroxene + Cr-spinel (in decreasing abundance). With decreasing temperature, plagioclase crystallizes, Fe-Ti-oxide replaces spinel, olivine dissolves, and finally amphibole appears, producing gabbroic and then amphibole gabbroic crystallization stages. Enhanced plagioclase stability at lower pressure narrows the clinopyroxenitic interval and brings the gabbroic interval toward the liquidus. Liquids at 900 MPa track along Miyashiro's (Am J Sci 274(4):321-355, 1974) tholeiitic versus calc-alkaline boundary, whereas those at 700 and 400 MPa become calc-alkaline at silica contents ≥56 wt%. This difference is chiefly due to higher temperature appearance of magnetite (versus spinel) at lower pressures. Although the evolved liquids are similar in many respects to common calc-alkaline andesites, the 900 and 700 MPa liquids differ in having low CaO concentrations due to early and abundant crystallization of augite, with the result that those liquids become peraluminous (ASI: molar Al/(Na + K + 2Ca) > 1) at ≥61 wt% SiO2, similar to liquids reported in other studies of the high-pressure crystallization of hydrous basalts (M�

Crystallization of oxidized, moderately hydrous arc basalt at mid- to lower-crustal pressures: Implications for andesite genesis

USGS Publications Warehouse

Blatter, Dawnika L.; Sisson, Thomas W.; Hankins, W. Ben

2013-01-01

This study focuses on the production of convergent margin calc-alkaline andesites by crystallization–differentiation of basaltic magmas in the lower to middle crust. Previous experimental studies show that dry, reduced, subalkaline basalts differentiate to tholeiitic (high Fe/Mg) daughter liquids, but the influences of H2O and oxidation on differentiation are less well established. Accordingly, we performed crystallization experiments at controlled oxidized fO2 (Re–ReO2 ≈ ΔNi–NiO + 2) on a relatively magnesian basalt (8.7 wt% MgO) typical of mafic magmas erupted in the Cascades near Mount Rainier, Washington. The basalt was synthesized with 2 wt% H2O and run at 900, 700, and 400 MPa and 1,200 to 950 °C. A broadly clinopyroxenitic crystallization interval dominates near the liquidus at 900 and 700 MPa, consisting of augite + olivine + orthopyroxene + Cr-spinel (in decreasing abundance). With decreasing temperature, plagioclase crystallizes, Fe–Ti-oxide replaces spinel, olivine dissolves, and finally amphibole appears, producing gabbroic and then amphibole gabbroic crystallization stages. Enhanced plagioclase stability at lower pressure narrows the clinopyroxenitic interval and brings the gabbroic interval toward the liquidus. Liquids at 900 MPa track along Miyashiro’s (Am J Sci 274(4):321–355, 1974) tholeiitic versus calc-alkaline boundary, whereas those at 700 and 400 MPa become calc-alkaline at silica contents ≥56 wt%. This difference is chiefly due to higher temperature appearance of magnetite (versus spinel) at lower pressures. Although the evolved liquids are similar in many respects to common calc-alkaline andesites, the 900 and 700 MPa liquids differ in having low CaO concentrations due to early and abundant crystallization of augite, with the result that those liquids become peraluminous (ASI: molar Al/(Na + K + 2Ca) > 1) at ≥61 wt% SiO2, similar to liquids reported in other studies of the high-pressure crystallization of hydrous basalts

Using mineral geochemistry to decipher slab, mantle, and crustal input in the generation of high-Mg andesites and basaltic andesites from the northern Cascade Arc

USGS Publications Warehouse

Sas, May; DeBari, Susan; Clynne, Michael A.; Rusk, Brian G.

2017-01-01

To better understand the role of slab melt in the petrogenesis of North Cascades magmas, this study focuses on petrogenesis of high-Mg lavas from the two northernmost active volcanoes in Washington. High-Mg andesites (HMA) and basaltic andesites (HMBA) in the Cascade Arc have high Mg# [molar Mg/(Mg+Fe2+)] relative to their SiO2 contents, elevated Nd/Yb, and are Ni- and Cr-enriched. The rock units examined here include the Tarn Plateau HMBA (51.8–54.0 wt% SiO2, Mg# 68–70) and Glacier Creek HMA (58.3–58.7 wt% SiO2, Mg# 63–64) from the Mount Baker Volcanic Field, and the Lightning Creek HMBA (54.8–54.6 SiO2, Mg# 69–73) from Glacier Peak. This study combines major and trace element compositions of minerals and whole rocks to test several petrogenetic hypotheses and to determine which, if any, are applicable to North Cascades HMA and HMBA. In the Tarn Plateau HMBA, rare earth element (REE) equilibrium liquids calculated from clinopyroxene compositions have high Nd/Yb that positively correlates with Mg#. This correlation suggests an origin similar to that proposed for Aleutian adakites, where intermediate, high Nd/Yb slab-derived melts interact with the overlying mantle to become Mg-rich, and subsequently mix with low Nd/Yb, mantle-derived mafic magmas with lower Mg#. In the Glacier Creek HMA, elevated whole-rock MgO and SiO2 contents resulted from accumulation of xenocrystic olivine and differentiation processes, respectively, but the cause of high Nd/Yb is less clear. However, high whole-rock Sr/P (fluid mobile/fluid immobile) values indicate a mantle source that was fluxed by an enriched, hydrous slab component, likely producing the observed high Nd/Yb REE signature. The Lightning Creek HMBA is a hybridized rock unit with at least three identifiable magmatic components, but only one of which has HMA characteristics. Cr and Mg contents in Cr-spinel and olivine pairs in this HMA component suggest that its source is a strongly depleted mantle, and high

The Mount Edgecumbe tephra deposits, a marker horizon in southeastern Alaska near the Pleistocene-Holocene boundary

USGS Publications Warehouse

Riehle, J.R.; Mann, D.H.; Peteet, D.M.; Engstrom, D.R.; Brew, D.A.; Meyer, C.E.

1992-01-01

Late Pleistocene tephra deposits found from Sitka to Juneau and Lituya Bay are assigned to a source at the Mount Edgecumbe volcanic field, based on similarity of glass compositions to nearvent deposits and on thinning away from Kruzof Island. The sequence of near-vent layers is basaltic andesite and andesite at the base, rhyolite, and mixed dacite and rhyolite on top. The only breaks in the tephra sequence are two 1-mm-thick silt partings in a lake-sediment core, indicating a depositional interval from basaltic andesite to dacite of no more than about a millennium. Tephra deposits at sites >30 km from the vent are solely dacite and rhyolite and are 10,600 to 11,400 14C yr old based on interpretation of 18 radiocarbon ages, including 5 by accelerator mass spectrometry (AMS). Basaltic andesite and andesite deposits nearer the vent are as much as 12,000 yr old. Discrepancy among radiocarbon ages of upland tephra deposits provisionally correlated as the same grainfall is resolvable within ??2 ?? of analytical uncertainty. Comparison of bulk and AMS ages in one sediment core indicates a systematic bias of +600 to +1100 yr for the bulk ages; correlation of tephra deposits among upland and lacustrine sites implies an additional discrepancy of 200-400 yr between upland (relatively too young) and lacustrine ages. In any case, the Mount Edgecumbe tephra deposits are a widespread, latest Pleistocene stratigraphic marker that serves to emphasize the uncertainty in dating biogenic material from southeastern Alaska. ?? 1992.

The crustal magma storage system of Volcán Quizapu, Chile, and the effects of magma mixing on magma diversity

USGS Publications Warehouse

Bergantz, George W.; Cooper, Kari M.; Hildreth, Edward; Ruprecht, Phillipp

2012-01-01

Crystal zoning as well as temperature and pressure estimates from phenocryst phase equilibria are used to constrain the architecture of the intermediate-sized magmatic system (some tens of km3) of Volcán Quizapu, Chile, and to document the textural and compositional effects of magma mixing. In contrast to most arc magma systems, where multiple episodes of open-system behavior obscure the evidence of major magma chamber events (e.g. melt extraction, magma mixing), the Quizapu magma system shows limited petrographic complexity in two large historical eruptions (1846–1847 and 1932) that have contrasting eruptive styles. Quizapu magmas and peripheral mafic magmas exhibit a simple binary mixing relationship. At the mafic end, basaltic andesite to andesite recharge magmas complement the record from peripheral cones and show the same limited range of compositions. The silicic end-member composition is almost identical in both eruptions of Quizapu. The effusive 1846–1847 eruption records significant mixing between the mafic and silicic end-members, resulting in hybridized andesites and mingled dacites. These two compositionally simple eruptions at Volcán Quizapu present a rare opportunity to isolate particular aspects of magma evolution—formation of homogeneous dacite magma and late-stage magma mixing—from other magma chamber processes. Crystal zoning, trace element compositions, and crystal-size distributions provide evidence for spatial separation of the mafic and silicic magmas. Dacite-derived plagioclase phenocrysts (i.e. An25–40) show a narrow range in composition and limited zonation, suggesting growth from a compositionally restricted melt. Dacite-derived amphibole phenocrysts show similar restricted compositions and furthermore constrain, together with more mafic amphibole phenocrysts, the architecture of the magmatic system at Volcán Quizapu to be compositionally and thermally zoned, in which an andesitic mush is overlain by a homogeneous dacitic

Petrographic and Geochemical Investigation of Andesitic Arc Volcanism: Mount Kerinci, Sunda Arc, Indonesia

NASA Astrophysics Data System (ADS)

Tully, M.; Saunders, K.; Troll, V. R.; Jolis, E.; Muir, D. D.; Deegan, F. M.; Budd, D. A.; Astbury, R.; Bromiley, G. D.

2014-12-01

Present knowledge of the chain of dominantly andesitic volcanoes, which span the Sumatran portion of the Sunda Arc is extremely limited. Previous studies have focused on Toba and Krakatau, although over 13 further volcanic edifices are known. Several recent explosive eruptions in Sumatra such as that of Mt. Sinabung, 2014, have highlighted the potential hazard that these volcanoes pose to the local and regional communities. Mount Kerinci, is one of the most active of the volcanoes in this region, yet little is known about the petrogenesis of the magma by which it is fed. Kerinci is located approximately mid-way between Toba in the North and Krakatau in the south. Along arc variations are observed in the major, minor and trace elements of whole rock analyses. However, bulk rock approaches produce an average chemical composition for a sample, potentially masking important chemical signatures. In-situ micro-analytical analysis of individual components of samples such as melt inclusions, crystals and groundmass provides chemical signatures of individual components allowing the evolution of volcanic centres to be deciphered in considerably more detail. Examination of whole rock chemistry indicates its location may be key to unravelling the petrogenesis of the arc as significant chemical changes occur between Kerinci and Kaba, 250 km to the south. Kerinci samples are dominantly porphyritic with large crystals of plagioclase, pyroxene and Fe-Ti oxides, rare olivine crystals are observed. Plagioclase and pyroxene crystals are chemically zoned and host melt inclusions. Multiple plagioclase populations are observed. A combination of in-situ micro-analysis techniques will be used to characterise the chemical composition of melt inclusions and crystals. These data can be used along with extant geothermobarometric models to help determine the magma source, storage conditions and composition of the evolving melt. Integration of the findings from this study with existing data for

Sr isotope zoning in plagioclase from andesites at Cabo De Gata, Spain: Evidence for shallow and deep contamination

NASA Astrophysics Data System (ADS)

Waight, Tod E.; Tørnqvist, Jakob B.

2018-05-01

Plagioclase crystals in andesites from the Cabo De Gata region show generally radiogenic Sr isotope compositions and consistent core to rim increases in 87Sr/86Sr that are indicative of open system processes in the lithosphere and crustal contamination during crystallization. High-grade metamorphic rocks of the Alpujárride and Nevado-Filábride complexes represent the most likely crustal contaminants. The plagioclases are characterized by subtly zoned and resorbed calcic cores (An73-86). These cores also have radiogenic 87Sr/86Sr (0.7127-0.7129), although typically less radiogenic than plagioclase rims, groundmass plagioclase and whole rock compositions (up to 87Sr/86Sr = 0.7135). These cores are interpreted to represent early crystallization of plagioclase from hydrous melts emplaced into the lower crust. The parental melts to these andesites must therefore have already inherited their radiogenic Sr isotope compositions prior to entering the lower crust and before the onset of crystallization of plagioclase, which is inconsistent with previous models suggesting that the generally radiogenic nature of Sr in these volcanics reflects large amounts of crustal contamination. Instead, the isotope systematics are consistent with models invoked significant addition of a subducted sediment component to the mantle source. The high-An% plagioclase cores are characterized by resorption textures, which are consistent with dissolution during rapid decompression and/or devolatisation during magma migration from the lower crust into upper crustal magma chambers.

The Effect of CO2 on Partial Reactive Crystallization of MORB-Eclogite-derived Basaltic Andesite in Peridotite and Generation of Silica-Undersaturated Basalts

NASA Astrophysics Data System (ADS)

Mallik, A.; Dasgupta, R.

2012-12-01

Recycled oceanic crust (MORB-eclogite) is considered to be the dominant heterogeneity in Earth's mantle. Because MORB-eclogite is more fusible than peridotite, siliceous partial melt derived from it must react with peridotite while the latter is still in the subsolidus state. Thus, studying such reactive process is important in understanding melting dynamics of the Earth's mantle. Reaction of MORB-eclogite-derived andesitic partial melt with peridotite can produce alkalic melts by partial reactive crystallization but these melts are not as silica-undersaturated as many natural basanites, nephelinites or melititites [1]. In this study, we constrain how dissolved CO2 in a siliceous MORB-eclogite-derived partial melt affects the reaction phase equilibria involving peridotite and can produce nephelinitic melts. Here we compare experiments on CO2-free [1] and 2.6 wt.% CO2 bearing andesitic melt+lherzolite mixtures conducted at 1375 °C and 3 GPa with added melt fraction of 8-50 wt.%. In both CO2-free and CO2-bearing experiments, melt and olivine are consumed and opx and garnet are produced, with the extent of modal change for a given melt-rock ratio being greater for the CO2-bearing experiments. While the residue evolves to a garnet websterite by adding 40% of CO2-bearing melt, the residue becomes olivine-free by adding 50% of the CO2-free melt. Opx mode increases from 12 to ~55 wt.% for 0 to 40% melt addition in CO2-bearing system and 12 to ~43 wt.% for 0 to 50% melt addition in CO2-free system. Garnet mode, for a similar range of melt-rock ratio, increases from ~10 to ~15 wt.% for CO2 bearing system and to ~11 wt.% for CO2-free system. Reacted melts from 25-33% of CO2-bearing melt-added runs contain ~39 wt.% SiO2 , ~11-13 wt.% TiO2, ~9 wt.% Al2O3, ~11 wt.% FeO*, 16 wt.% MgO, 10-11 wt.% CaO, and 3 wt.% Na2O whereas experiments with a similar melt-rock ratio in a CO2-free system yield melts with 44-45 wt.% SiO2, 6-7 wt.% TiO2, 13-14 wt.% Al2O3, 10-11 wt.% FeO*, 12-13 wt

The compositionally zoned eruption of 1912 in the Valley of Ten Thousand Smokes, Katmai National Park, Alaska

USGS Publications Warehouse

Hildreth, W.

1983-01-01

On June 6-8, 1912, ??? 15 km3 of magma erupted from the Novarupta caldera at the head of the Valley of Ten Thousand Smokes (VTTS), producing ??? 20 km3 of air-fall tephra and 11-15 km3 of ash-flow tuff within ??? 60 hours. Three discrete periods of ash-fall at Kodiak correlate, respectively, with Plinian tephra layers designated A, CD, and FG by Curtis (1968) in the VTTS. The ash-flow sequence overlapped with but outlasted pumice fall A, terminating within 20 hours of the initial outbreak and prior to pumice fall C. Layers E and H consist mostly of vitric dust that settled during lulls, and Layer B is the feather edge of the ash flow. The fall units filled and obscured the caldera, but arcuate and radial fissures outline a 6-km2 depression. The Novarupta lava dome and its ejecta ring were emplaced later within the depression. At Mt. Katmai, 10 km east of the 1912 vent, a 600-m-deep caldera of similar area also collapsed at about this time, probably owing to hydraulic connection with the venting magma system; but all known ejecta are thought to have erupted at Novarupta. Mingling of three distinctive magmas during the eruption produced an abundance of banded pumice, and mechanical mixing of chilled ejecta resulted in deposits with a wide range of bulk composition. Pumice in the initial fall unit (A) is 100% rhyolite, but fall units atop the ash flow are > 98% dacite; black andesitic scoria is common only in the ash flows and in near-vent air-fall tephra. Pumice counts show the first half of the ash-flow deposit to be 91-98% rhyolite, but progressive increases of dacite and andesite eventually reduced the rhyolitic component to 20 km to the lowermost VTTS, and deposited 1-8 m of debris there. Rhyolitic ejecta contain only 1-2% phenocrysts but andesite and dacite have 30-45%. Quartz is present and augite absent only in the rhyolite, but all ejecta contain plagioclase, orthopyroxene, titanomagnetite, ilmenite, apatite, and pyrrhotite; rare olivine occurs in the

Quantitative geometric description of fracture systems in an andesite lava flow using terrestrial laser scanner data

NASA Astrophysics Data System (ADS)

Massiot, Cécile; Nicol, Andrew; Townend, John; McNamara, David D.; Garcia-Sellés, David; Conway, Chris E.; Archibald, Garth

2017-07-01

Permeability hosted in andesitic lava flows is dominantly controlled by fracture systems, with geometries that are often poorly constrained. This paper explores the fracture system geometry of an andesitic lava flow formed during its emplacement and cooling over gentle paleo-topography, on the active Ruapehu volcano, New Zealand. The fracture system comprises column-forming and platy fractures within the blocky interior of the lava flow, bounded by autobreccias partially observed at the base and top of the outcrop. We use a terrestrial laser scanner (TLS) dataset to extract column-forming fractures directly from the point-cloud shape over an outcrop area of ∼3090 m2. Fracture processing is validated using manual scanlines and high-resolution panoramic photographs. Column-forming fractures are either steeply or gently dipping with no preferred strike orientation. Geometric analysis of fractures derived from the TLS, in combination with virtual scanlines and trace maps, reveals that: (1) steeply dipping column-forming fracture lengths follow a scale-dependent exponential or log-normal distribution rather than a scale-independent power-law; (2) fracture intensities (combining density and size) vary throughout the blocky zone but have similar mean values up and along the lava flow; and (3) the areal fracture intensity is higher in the autobreccia than in the blocky zone. The inter-connected fracture network has a connected porosity of ∼0.5 % that promote fluid flow vertically and laterally within the blocky zone, and is partially connected to the autobreccias. Autobreccias may act either as lateral permeability connections or barriers in reservoirs, depending on burial and alteration history. A discrete fracture network model generated from these geometrical parameters yields a highly connected fracture network, consistent with outcrop observations.

Mineralogy and geochemistry of Eocene Helete formation , Adiyaman, Turkey

NASA Astrophysics Data System (ADS)

Choi, J.; Lee, I.; Yildirim, E.

2013-12-01

Helete formation is located at Adiyaman, Turkey which is in the Alpine-Himalayan orogeny belt. Helete formation is represented by andesitic, basaltic and gabbroic rocks cut by localized felsic intrusions and overlain by open-marine Nummulitic carbonate sediments. Electron microprobe analyses were conducted for 15 rocks samples of Helete formation. These rock samples are named as basalt, andesite, gabbro, diorite, dacite, and granite. Basalt and andesite samples are composed of clinopyroxene(augite), plagioclase(Ab98-96), carbonate, and hyaline. Gabbro samples have wide range of plagioclase composition from anorthite to albite(Ab92-16), and other minerals like clinopyroxene(augite) and amphibole(hornblende and actinolite). Diabase samples consist of epidote group minerals and sphene with plagioclase(Ab80), pyroxene and hornblende. Dacite samples are composed of dolomite and quartz. Granite samples are composed of quartz, chlorite, and plagioclase which range from albite to oligoclase in composition (Ab98-89).

Flowage differentiation in an andesitic dyke of the Motru Dyke Swarm (Southern Carpathians, Romania) inferred from AMS, CSD and geochemistry

NASA Astrophysics Data System (ADS)

Nkono, Collin; Féménias, Olivier; Diot, Hervé; Berza, Tudor; Demaiffe, Daniel

2006-06-01

Two dykes of different thickness (5.5 m for TJ31 and 23 m for TJ34) from the late Pan-African calc-alkaline Motru Dyke Swarm (S. Carpathians, Romania) have been studied by electron microprobe (mineral chemistry), crystal size distribution (CSD), anisotropy of magnetic susceptibility (AMS) and whole-rock geochemistry. All the physical and chemical variations observed across the dyke's width point to concordant results and show that the variations of both modal abundance and size of the amphibole and biotite microphenocrysts inside the dykes (deduced from the classical CSD measurements) are the result of a mechanical segregation of suspended crystals during magmatic transport. Despite a pene-contemporaneous regional tectonic, the flow-induced differentiation in the thicker dyke is characterized by the concentration of pre-existing Ti-rich pargasite-tschermakite, clinopyroxene and plagioclase crystals in the core of the dyke and of the extracted differentiated liquid near the walls. This mechanical differentiation induces a chemical differentiation with a basaltic andesite composition for the core of the dyke whereas the margins are andesitic. Thus the chilled margins appear as a slightly more evolved liquid with a Newtonian behaviour when compared to the average composition of the dyke. The localization of the liquid on both sides of the dyke has certainly facilitated the ascent of the central part of the dyke that behaved as a Binghamian mush.

Co-existing calcic amphiboles in calc-alkaline andesites: Possible evidence of a zoned magma chamber

NASA Astrophysics Data System (ADS)

Green, Nathan L.

1982-03-01

Hornblende-biotite andesites erupted from Mount Price and Clinker Peak volcanoes, southwestern British Columbia, contain two texturally and compositionally distinct calcic amphiboles: pargasitic hornblende xenocrysts and magnesio-hornblende microphenocrysts. Disequilibrium relationships exhibited by these amphiboles and associated minerals suggest that the magnesio-hornblendes precipitated under chemical and thermal conditions that were intermediate between those under which pargasitic hornblende and biotite, respectively, crystallized. Experimental studies of crystallization in double-diffusive systems (Chen and Turner, 1980; Turner, 1980; McBirney, 1980) suggest that these varied magmatic environments can be explained as a consequence of progressive crystallization within a zoned magma chamber. Although gravitational settling may have played a role, the observed mineral assemblages probably developed by convective mixing of crystals precipitated at the cooling margins with those crystallized in the interior of the compositionally stratified magma column.

Long-period seismicity at Redoubt Volcano, Alaska, 1989-1990 related to magma degassing

USGS Publications Warehouse

Morrissey, M.M.

1997-01-01

The mass of exsolved magmatic H2O is estimated and compared to the mass of superheated steam (25-50 Mtons) released through the resonating crack producing the December 13-14, 1989 swarm of long-period seismic events at Redoubt Volcano. Results indicate degassing of a H2O-CO2-SO2-saturated magma upon ascending from at least 12 km to 3-4 km beneath the crater as the source of the superheated steam. The mass of exsolved H2O (3.2-250 Mtons) is estimated from solubility diagrams of H2O-CO2-saturated silicate melts for the ascent history of the Redoubt magmas. Crystal size distribution, seismological, petrological, and geochemical data are used to constrain the ascent history of the two andesitic magmas prior to the eruption. Two stages of crystallization are inferred from crystal size distributions of plagioclase crystals in andesites erupted in December 1989. The first stage occurred 30-150 years before the eruption in both magmas and the second stage occurred at least 8 years and 15 years before the eruption in the dacitic andesite and rhyolitic andesite, respectively. The depths of crystallization are constrained from the spatial and temporal variations of volcano-tectonic earthquakes locations (Lahr et al., 1994) and from the P-wave and S-wave velocity structures (Benz et al., 1996). These data suggest that the rhyolitic andesite magma ascended to a depth of 7-8 km within at least 15 years of the eruption. Within at least 8 years of the eruption, the dacitic andesite magma migrated to a depth just below the other magma body where it resided until hours to days of the eruption. At this time, the dacitic andesite magma mixed with the rhyolitic andesite magma and established the reservoir for the eruption. Near the top of the reservoir, some of the mixed magma was displaced into fractures which extended 4-5 km toward the surface. This displaced magma created the eruption conduit and released the fluids related to the resonating crack. This scenario is consistent with

Petrographic and major elements results as indicator of the geothermal potential in Java

NASA Astrophysics Data System (ADS)

Indarto, S.; Setiawan, I.; Kausar, A.; Permana, dan H.

2018-02-01

Geothermal manifestations existed in West Java (Cilayu, Papandayan Mountain, Telagabodas, Karaha, Tampomas Mountain), Central Java (Slamet Mountain, Dieng) and East Java (Argopuro Mountain) show a difference in their mineral and geochemical compositions. The petrographic analysis of volcanic rocks from Garut (West Java) are basalt, andesite basaltic and andesite. However, based on SiO2 vs K2O value, those volcanic rocks have wide ranges of fractionated magma resulting basalt - basaltic andesite to dacitic in composition rather than those of Slamet Mountain, Dieng, and Argopuro Mountain areas which have a narrower range of fractionation magma resulting andesite basaltic and andesite in compositions. The volcanic rocks from Garut show tholeiitic affinity and calc-alkaline affinity. The geothermal potential of Java is assumed to be related to the magma fractionation level. Geothermal potential of West Java (Garut) is higher than that of Central Java (Slamet Mountain, Dieng) and East Java (Argopuro Mountain).

A chilled margin of komatiite and Mg-rich basaltic andesite in the western Bushveld Complex, South Africa

NASA Astrophysics Data System (ADS)

Maier, W. D.; Barnes, S.-J.; Karykowski, B. T.

2016-06-01

A chill sequence at the base of the Lower Zone of the western Bushveld Complex at Union Section, South Africa, contains aphanitic Mg-rich basaltic andesite and spinifex-textured komatiite. The basaltic andesite has an average composition of 15.2 % MgO, 52.8 % SiO2, 1205 ppm Cr, and 361 ppm Ni, whereas the komatiite has 18.7 % MgO, 1515 ppm Cr, and 410 ppm Ni. Both rock types have very low concentrations of immobile incompatible elements (0.14-0.72 ppm Nb, 7-31 ppm Zr, 0.34-0.69 ppm Th, 0.23-0.27 wt% TiO2), but high PGE contents (19-23 ppb Pt, 15-16 ppb Pd) and Pt/Pd ratios (Pt/Pd 1.4). Strontium and S isotopes show enriched signatures relative to most other Lower Zone rocks. The rocks could represent a ~20 % partial melt of subcontinental lithospheric mantle. This would match the PGE content of the rocks. However, this model is inconsistent with the high SiO2, Fe, and Na2O contents and, in particular, the low K2O, Zr, Hf, Nb, Ta, Th, LREE, Rb, and Ba contents of the rocks. Alternatively, the chills could represent a komatiitic magma derived from the asthenosphere that underwent assimilation of the quartzitic floor accompanied by crystallization of olivine and chromite. This model is consistent with the lithophile elements and the elevated Sr and S isotopic signatures of the rocks. However, in order to account for the high Pt and Pd contents of the magma, the mantle must have been twice as rich in PGE as the current estimate for PUM, possibly due to a component of incompletely equilibrated late veneer.

Geochemistry of the 1989-1990 eruption of redoubt volcano: Part II. Evidence from mineral and glass chemistry

USGS Publications Warehouse

Swanson, S.E.; Nye, C.J.; Miller, T.P.; Avery, V.F.

1994-01-01

Early stages (December 1989) of the 1989-1990 eruption of Redoubt Volcano produced two distinct lavas. Both lavas are high-silica andesites with a narrow range of bulk composition (58-64 wt.%) and similar mineralogies (phenocrysts of plagioclase, hornblende, augite, hypersthene and FeTi oxides in a groundmass of the same phases plus glass). The two lavas are distinguished by groundmass glass compositions, one is dacitic and the other rhyolitic. Sharp boundaries between the two glasses in compositionally banded pumices, lack of extensive coronas on hornblende phenocrysts, and seismic data suggest that a magma-mixing event immediately preceeded the eruption in December 1989. Textural disequilibrium in the phenocrysts suggests both magmas (dacitic and rhyolitic glasses) had a mixing history prior to their interaction and eruption in 1989. Sievey plagioclase and overgrowths of magnetite on ilmenite are textures that are at least consistent with magma mixing. The presence of two hornblende compositions (one a high-Al pargasitic hornblende and one a low-Al magnesiohornblende) in both the dacitic and rhyolitic groundmasses indicates a mixing event to yield these two amphibole populations prior to the magma mixing in December 1989. The pargasitic hornblende and the presence of Ca-rich overgrowths in the sievey zones of the plagioclase together indicate at least one component of this earlier mixing event was a mafic magma, either a basalt or a basaltic andesite. Eruptions in 1990 produced only andesite with a rhyolitic groundmass glass. Glass compositions in the 1990 andesite are identical to the rhyolitic glass in the 1989 andesite. Cognate xenoliths from the magma chamber (or conduit) are also found in the 1990 lavas. Magma mixing probably triggered the eruption in 1989. The eruption ended when this rather viscous (rhyolitic groundmass glass, magma capable of entraining sidewall xenoliths) magma stabalized within the conduit. ?? 1994.

Volcanic Centers of the Northern McCullough Range, Southern Nevada USA: a View of Pre- Extensional Volcanism in the Colorado River Extensional Corridor

NASA Astrophysics Data System (ADS)

Honn, D. K.; Johnsen, R.; Smith, E. I.

2007-05-01

The northern McCullough Range, just south of Las Vegas, Nevada, is being developed by the US Bureau of Land Management as the Sloan Canyon National Conservation Area to preserve its natural history. Compared to adjacent ranges, the northern McCullough Range was relatively undeformed by Miocene extension in the Colorado River Extensional Corridor. Therefore, the well preserved volcanic centers within the McCullough Range provide an excellent opportunity to study pre-extensional volcanism. There are at least seven volcanic centers in the northern McCullough Range; this study focuses on the Cactus Hill, McCullough Wash, and Eldorado Valley Volcanoes in the central McCullough Range, and the Henderson Caldera in the northern McCullough Range. The Cactus Hill volcano is a 200 m thick section of flows and agglomerates that form a broad basalt-andesite cone, nearly 2 km in diameter. This cone is cut by two (2-3 m wide) basalt dikes and at least 8 dacite domes. Each of the domes is associated with a broad debris apron. The McCullough Wash volcano is composed of at least 6 dacite domes and carapace breccias that reflect periods of dome growth and collapse. The Eldorado Valley Volcano, another series of dacite domes and flows, is the source of a 250 m thick breccia unit (Eldorado Valley breccia). The breccia is a block and ash deposit (with beds up to 1.5 m thick) containing spectacular blocks (1 cm - 3 m in diameter) and bombs (10 cm - 6 m in diameter) that are interbedded with flows from the McCullough Wash and Cactus Hill volcanoes. Interbedding of dacite breccia of the Eldorado Valley Volcano with dacitic, andesitic and basaltic dome debris from the Cactus Hill volcano reflect coeval mafic and felsic volcanism. The Henderson caldera at the northern tip of the McCullough Range is formed by a arc of domes that erupted a series of biotite dacite flows. The caldera is also filled by domes and flows of hornblende andesite, ash-flow tuff and mesobreccia deposits. The tuff of

Eruptive history of Mount Katmai, Alaska

USGS Publications Warehouse

Hildreth, Edward; Fierstein, Judith

2012-01-01

Compositionally, products of Mount Katmai represent an ordinary medium-K arc array, both tholeiitic and calcalkaline, that extends from 51.6% to 72.3% SiO2. Values of 87Sr/86Sr range from 0.70335 to 0.70372, correlating loosely with fractionation indices. The 5–6 km3 of continuously zoned andesite-dacite magma (58%–68% SiO2) that erupted at Novarupta in 1912 was withdrawn from beneath Mount Katmai and bears close compositional affinity with products of that edifice, not with pre-1912 products of the adjacent Trident cluster. Evidence is presented that the 7–8 km3 of high-silica rhyolite (77% SiO2) released in 1912 is unlikely to have been stored under Novarupta or Trident. Pre-eruptive contiguity with the andesite-dacite reservoir is suggested by (1) eruption of ∼3 km3 of rhyolite magma first, followed by mutual mingling in fluctuating proportions; (2) thermal and redox continuity of the whole zoned sequence despite the wide compositional gap; (3) Nd, Sr, O isotopic, and rare earth element (REE) affinities of the whole array; (4) compositional continuity of the nearly aphyric rhyolite with the glass (melt) phase of the phenocryst-rich dacite; and (5) phase-equilibrium experiments that indicate similar shallow pre-eruptive storage depths (3–6 km) for rhyolite, dacite, and andesite.

Multiple plagioclase crystal populations identified by crystal size distribution and in situ chemical data: Implications for timescales of magma chamber processes associated with the 1915 eruption of Lassen Peak, CA

USGS Publications Warehouse

Salisbury, M.J.; Bohrson, W.A.; Clynne, M.A.; Ramos, F.C.; Hoskin, P.

2008-01-01

Products of the 1915 Lassen Peak eruption reveal evidence for a magma recharge-magma mixing event that may have catalyzed the eruption and from which four compositional members were identified: light dacite, black dacite, andesitic inclusion, and dark andesite. Crystal size distribution, textural, and in situ chemical (major and trace element and Sr isotope) data for plagioclase from these compositional products define three crystal populations that have distinct origins: phenocrysts (long axis > 0??5 mm) that typically have core An contents between 34 and 36 mol %, microphenocrysts (long axis between 0??1 and 0??5 mm) that have core An contents of 66-69, and microlites (long axis < 0??1 mm) with variable An core contents from 64 to 52. Phenocrysts are interpreted to form in an isolated dacitic magma chamber that experienced slow cooling. Based on textural, compositional, and isotopic data for the magma represented by the dacitic component, magma recharge was not an important process until just prior to the 1915 eruption. Average residence times for phenocrysts are in the range of centuries to millennia. Microphenocrysts formed in a hybrid layer that resulted from mixing between end-member reservoir dacite and recharge magma of basaltic andesite composition. High thermal contrast between the two end-member magmas led to relatively high degrees of undercooling, which resulted in faster crystal growth rates and acicular and swallowtail crystal habits. Some plagioclase phenocrysts from the dacitic chamber were incorporated into the hybrid layer and underwent dissolution-precipitation, seen in both crystal textures and rim compositions. Average microphenocryst residence times are of the order of months. Microlites may have formed in response to decompression and/ or syn-eruptive degassing as magma ascended from the chamber through the volcanic conduit. Chemical distinctions in plagioclase microlite An contents reveal that melt of the dark andesite was more mafic than

Bimodal tholeiitic-dacitic magmatism and the Early Precambrian crust

USGS Publications Warehouse

Barker, F.; Peterman, Z.E.

1974-01-01

Interlayered plagioclase-quartz gneisses and amphibolites from 2.7 to more than 3.6 b.y. old form much of the basement underlying Precambrian greenstone belts of the world; they are especially well-developed and preserved in the Transvaal and Rhodesian cratons. We postulate that these basement rocks are largely a metamorphosed, volcanic, bimodal suite of tholeiite and high-silica low-potash dacite-compositionally similar to the 1.8-b.y.-old Twilight Gneiss - and partly intrusive equivalents injected into the lower parts of such volcanic piles. We speculate that magmatism in the Early Precambrian involved higher heat flow and more hydrous conditions than in the Phanerozoic. Specifically, we suggest that the early degassing of the Earth produced a basaltic crust and pyrolitic upper mantle that contained much amphibole, serpentine, and other hydrous minerals. Dehydration of the lower parts of a downgoing slab of such hydrous crust and upper mantle would release sufficient water to prohibit formation of andesitic liquid in the upper part of the slab. Instead, a dacitic liquid and a residuum of amphibole and other silica-poor phases would form, according to Green and Ringwood's experimental results. Higher temperatures farther down the slab would cause total melting of basalt and generation of the tholeiitic member of the suite. This type of magma generation and volcanism persisted until the early hydrous lithosphere was consumed. An implication of this hypothesis is that about half the present volume of the oceans formed before about 2.6 b.y. ago. ?? 1974.

Eruptive history of South Sister, Oregon Cascades

USGS Publications Warehouse

Fierstein, J.; Hildreth, W.; Calvert, A.T.

2011-01-01

South Sister is southernmost and highest of the Three Sisters, three geologically dissimilar stratovolcanoes that together form a spectacular 20km reach along the Cascade crest in Oregon. North Sister is a monotonously mafic edifice as old as middle Pleistocene, Middle Sister a basalt-andesite-dacite cone built between 48 and 14ka, and South Sister is a basalt-free edifice that alternated rhyolitic and intermediate modes from 50ka to 2ka (largely contemporaneous with Middle Sister). Detailed mapping, 330 chemical analyses, and 42 radioisotopic ages show that the oldest exposed South Sister lavas were initially rhyolitic ~50ka. By ~37ka, rhyolitic lava flows and domes (72-74% SiO2) began alternating with radially emplaced dacite (63-68% SiO2) and andesite (59-63% SiO2) lava flows. Construction of a broad cone of silicic andesite-dacite (61-64% SiO2) culminated ~30ka in a dominantly explosive sequence that began with crater-forming andesitic eruptions that left fragmental deposits at least 200m thick. This was followed at ~27ka by growth of a steeply dipping summit cone of agglutinate-dominated andesite (56-60.5% SiO2) and formation of a summit crater ~800m wide. This crater was soon filled and overtopped by a thick dacite lava flow and then by >150m of dacitic pyroclastic ejecta. Small-volume dacite lavas (63-67% SiO2) locally cap the pyroclastic pile. A final sheet of mafic agglutinate (54-56% SiO2) - the most mafic product of South Sister - erupted from and drapes the small (300-m-wide) present-day summit crater, ending a summit-building sequence that lasted until ~22ka. A 20kyr-long-hiatus was broken by rhyolite eruptions that produced (1) the Rock Mesa coulee, tephra, and satellite domelets (73.5% SiO2) and (2) the Devils Chain of ~20 domes and short coulees (72.3-72.8% SiO2) from N-S vent alignments on South Sister's flanks. The compositional reversal from mafic summit agglutinate to recent rhyolites epitomizes the frequently changing compositional modes of the

Eruptive history of South Sister, Oregon Cascades

NASA Astrophysics Data System (ADS)

Fierstein, Judy; Hildreth, Wes; Calvert, Andrew T.

2011-10-01

South Sister is southernmost and highest of the Three Sisters, three geologically dissimilar stratovolcanoes that together form a spectacular 20 km reach along the Cascade crest in Oregon. North Sister is a monotonously mafic edifice as old as middle Pleistocene, Middle Sister a basalt-andesite-dacite cone built between 48 and 14 ka, and South Sister is a basalt-free edifice that alternated rhyolitic and intermediate modes from 50 ka to 2 ka (largely contemporaneous with Middle Sister). Detailed mapping, 330 chemical analyses, and 42 radioisotopic ages show that the oldest exposed South Sister lavas were initially rhyolitic ~ 50 ka. By ~ 37 ka, rhyolitic lava flows and domes (72-74% SiO 2) began alternating with radially emplaced dacite (63-68% SiO 2) and andesite (59-63% SiO 2) lava flows. Construction of a broad cone of silicic andesite-dacite (61-64% SiO 2) culminated ~ 30 ka in a dominantly explosive sequence that began with crater-forming andesitic eruptions that left fragmental deposits at least 200 m thick. This was followed at ~ 27 ka by growth of a steeply dipping summit cone of agglutinate-dominated andesite (56-60.5% SiO 2) and formation of a summit crater ~ 800 m wide. This crater was soon filled and overtopped by a thick dacite lava flow and then by > 150 m of dacitic pyroclastic ejecta. Small-volume dacite lavas (63-67% SiO 2) locally cap the pyroclastic pile. A final sheet of mafic agglutinate (54-56% SiO 2) - the most mafic product of South Sister - erupted from and drapes the small (300-m-wide) present-day summit crater, ending a summit-building sequence that lasted until ~ 22 ka. A 20 kyr-long-hiatus was broken by rhyolite eruptions that produced (1) the Rock Mesa coulee, tephra, and satellite domelets (73.5% SiO 2) and (2) the Devils Chain of ~ 20 domes and short coulees (72.3-72.8% SiO 2) from N-S vent alignments on South Sister's flanks. The compositional reversal from mafic summit agglutinate to recent rhyolites epitomizes the frequently

The challenging retrieval of the displacement field from InSAR data for andesitic stratovolcanoes: Case study of Popocatepetl and Colima Volcano, Mexico

NASA Astrophysics Data System (ADS)

Pinel, V.; Hooper, A.; De la Cruz-Reyna, S.; Reyes-Davila, G.; Doin, M. P.; Bascou, P.

2011-02-01

Despite the ability of synthetic aperture radar (SAR) interferometry to measure ground motion with high-resolution, application of this remote sensing technique to monitor andesitic stratovolcanoes remains limited. Specific acquisition conditions characterizing andesitic stratovolcanoes, mainly vegetated areas with large elevation ranges, induce low signal coherence as well as strong tropospheric artefacts that result in small signal-to-noise ratio. We propose here a way to mitigate these difficulties and improve the SAR measurements. We derive ground motions for two of the most active Mexican stratovolcanoes: Popocatepetl and Colima Volcano, from the time series of SAR data acquired from December 2002 to August 2006. The SAR data are processed using a method that combines both persistent scatterers and small baseline approaches. Stratified tropospheric delays are estimated for each interferogram using inputs from the global atmospheric model NARR, up to a maximum of 10 rad/km. These delays are validated using spectrometer data, as well as the correlation between the wrapped phase and the elevation. The tropospheric effect is removed from the wrapped phase in order to improve the unwrapping process. On Popocatepetl, we observe no significant deformation. The Colima summit area exhibits a constant subsidence rate of more than 1 cm/year centered on the summit but enhanced (reaching more than 2 cm/year) around the 1998 lava flow. We model this subsidence considering both a deflating magma source at depth and the effect of the eruptive deposits load.

Mixing and mingling in Iceland: The origin of a diverse suite of Tertiary lavas

NASA Astrophysics Data System (ADS)

Jordan, B. T.

2006-12-01

A sequence of intermediate and silicic volcanic units occurs within a stratigraphic package dominated by moderately evolved tholeiitic basalts in the mountains Laxardalsfjoll and Langadalsfjall in the southern Skagi Peninsula of north-central Iceland. This sequence consists of several minor rhyolite and dacite lavas directly overlain by a voluminous (>3 km3) litholigically diverse andesite to rhyolite lava flow Above this flow is a basaltic andesite to dacite lava, or lavas (mapping not complete), and the sequence is capped by an extensive rhyolite lava. Pyroclastic deposits, including one welded tuff, occur within the sequence. The sequence was erupted at 7.8 Ma, not long before the abandonment of the Skagi-Snaefellsnes rift zone in which it was erupted. The rhyolite lavas are generally aphyric. The lower rhyolites are of variable composition (71-75% SiO2) and the upper is a high-silica rhyolite (75-76% SiO2). The lower dacite and upper basaltic andesite to dacite lava(s) are aphyric and plot on a linear mixing trend between well defined end-members, a moderately evolved basalt and a high-silica rhyolite. The most anomalous unit is the andesite-rhyolite lava. It is lithologically heterogeneous with <<1% to 20% coarse (up to 3 cm) nearly equant plagioclase phenocrysts. Lithologies commonly vary across sharp borders within the flow, with domains of different lithologies being up to 10s of m in extent. The coarse plagioclase phenocrysts are calcic, up to An87 indicating an origin in basaltic magma. The whole rock composition varies from andesite (58% SiO2) to rhyolite (70% SiO2). Silica content is inversely correlated with phenocryst abundance, but can not be explained by phenocrysts alone. A wide range of mixing and mingling textures are observed at mesoscopic and microscopic scales. Major and trace element variations are quite distinct from the other mixed unit and indicate that the end members of mixing are a plagioclase-rich basalt and a range of silicic

Cogenetic late Pleistocene rhyolite and cumulate diorites from Augustine Volcano revealed by SIMS 238U-230Th dating of zircon, and implications for silicic magma generation by extraction from mush

USGS Publications Warehouse

Coombs, Michelle L.; Vazquez, Jorge A.

2014-01-01

Augustine Volcano, a frequently active andesitic island stratocone, erupted a late Pleistocene rhyolite pumice fall that is temporally linked through zircon geochronology to cumulate dioritic blocks brought to the surface in Augustine's 2006 eruption. Zircon from the rhyolite yield a 238U-230Th age of ∼25 ka for their unpolished rims, and their interiors yield a bimodal age populations at ∼26 ka and a minority at ∼41 ka. Zircon from dioritic blocks, ripped from Augustine's shallow magmatic plumbing system and ejected during the 2006 eruption, have interiors defining a ∼26 ka age population that is indistinguishable from that for the rhyolite; unpolished rims on the dioritic zircon are dominantly younger (≤12 ka) indicating subsequent crystallization. Zircon from rhyolite and diorite overlap in U, Hf, Ti, and REE concentrations although diorites also contain a second population of high-U, high temperature grains. Andesites that brought dioritic blocks to the surface in 2006 contain zircon with young (≤9 ka) rims and a scattering of older ages, but few zircon that crystallized during the 26 ka interval. Both the Pleistocene-age rhyolite and the 2006 dioritic inclusions plot along a whole-rock compositional trend distinct from mid-Holocene–present andesites and dacites, and the diorites, rhyolite, and two early Holocene dacites define linear unmixing trends often oblique to the main andesite array and consistent with melt (rhyolite) extraction from a mush (dacites), leaving behind a cumulate amphibole-bearing residue (diorites). Rare zircon antecrysts up to ∼300 ka from all rock types indicate that a Quaternary center has been present longer than preserved surficial deposits.

Eruptive history and geochronology of the Mount Baker volcanic field, Washington

USGS Publications Warehouse

Hildreth, W.; Fierstein, J.; Lanphere, M.

2003-01-01

Mount Baker, a steaming, ice-mantled, andesitic stratovolcano, is the most conspicuous component of a multivent Quaternary volcanic field active almost continuously since 1.3 Ma. More than 70 packages of lava flows and ~110 dikes have been mapped, ???500 samples chemically analyzed, and ~80 K-Ar and 40Ar/39Ar ages determined. Principal components are (1) the ignimbrite-filled Kulshan caldera (1.15 Ma) and its precaldera and postcaldera rhyodacite lavas and dikes (1.29-0.99 Ma); (2)~60 intracaldera, hydrothermally altered, andesite-dacite dikes and pods-remnants of a substantial early-postcaldera volcanic center (1.1-0.6 Ma); (3) unaltered intracaldera andesite lavas and dikes, including those capping Ptarmigan and Lasiocarpa Ridges and Table Mountain (0.5-0.2 Ma); (4) the long-lived Chowder Ridge focus (1.29-0.1 Ma)-an andesite to rhyodacite eruptive complex now glacially reduced to ~50 dikes and remnants of ~10 lava flows; (5) Black Buttes stratocone, basaltic to dacitic, and several contemporaneous peripheral volcanoes (0.5-0.2 Ma); and (6) Mount Baker stratocone and contemporaneous peripheral volcanoes (0.1 Ma to Holocene). Glacial ice has influenced eruptions and amplified erosion throughout the lifetime of the volcanic field. Although more than half the material erupted has been eroded, liberal and conservative volume estimates for 77 increments of known age yield cumulative curves of volume erupted vs. time that indicate eruption rates in the range 0.17-0.43 km3/k.y. for major episodes and longterm background rates of 0.02-0.07 km3/k.y. Andesite and rhyodacite each make up nearly half of the 161 ?? 56 km3 of products erupted, whereas basalt and dacite represent only a few cubic kilometers, each representing 1%-3% the total. During the past 4 m.y., the principal magmatic focus has migrated stepwise 25 km southwestward, from the edge of the Chilliwack batholith to present-day Mount Baker.

Long-term changes in explosive and effusive behaviour at andesitic arc volcanoes: Chronostratigraphy of the Centre Hills Volcano, Montserrat

NASA Astrophysics Data System (ADS)

Coussens, Maya; Cassidy, Michael; Watt, Sebastian F. L.; Jutzeler, Martin; Talling, Peter J.; Barfod, Dan; Gernon, Thomas M.; Taylor, Rex; Hatter, Stuart J.; Palmer, Martin R.; Montserrat Volcano Observatory

2017-03-01

Volcanism on Montserrat (Lesser Antilles arc) has migrated southwards since the formation of the Silver Hills 2.5 Ma, and has formed three successively active volcanic centres. The Centre Hills volcano was the focus of volcanism from 1-0.4 Ma, before activity commenced at the currently active Soufrière Hills volcano. The history of activity at these two volcanoes provides an opportunity to investigate the pattern of volcano behaviour on an andesitic arc island over the lifetime of individual volcanoes. Here, we describe the pyroclastic stratigraphy of subaerial exposures around central Montserrat; identifying 11 thick (> 1 m) pumiceous units derived from sustained explosive eruptions of Centre Hills from 0.8-0.4 Ma. Over 10 other, less well- exposed pumiceous units have also been identified. The pumice-rich units are interbedded with andesite lava breccias derived from effusive, dome-forming eruptions of Centre Hills. The stratigraphy indicates that large (up to magnitude 5) explosive eruptions occurred throughout the history of Centre Hills, alongside effusive activity. This behaviour at Centre Hills contrasts with Soufrière Hills, where deposits from sustained explosive eruptions are much less common and restricted to early stages of activity at the volcano, from 175-130 ka. Subsequent eruptions at Soufriere Hills have been dominated by andesitic effusive eruptions. The bulk composition, petrography and mineral chemistry of volcanic rocks from Centre Hills and Soufrière Hills are similar throughout the history of both volcanoes, except for occasional, transient departures to different magma compositions, which mark shifts in vent location or dominant eruption style. For example, the final recorded eruption of Centre Hills, before the initiation of activity at Soufrière Hills, was more silicic than any other identified eruption on Montserrat; and the basaltic South Soufrière Hills episode marked the transition to the current stage of predominantly effusive

Origin and emplacement of the andesite of Burroughs Mountain, a zoned, large-volume lava flow at Mount Rainier, Washington, USA

USGS Publications Warehouse

Stockstill, K.R.; Vogel, T.A.; Sisson, T.W.

2002-01-01

Burroughs Mountain, situated at the northeast foot of Mount Rainier, WA, exposes a large-volume (3.4 km3) andesitic lava flow, up to 350 m thick and extending 11 km in length. Two sampling traverses from flow base to eroded top, over vertical sections of 245 and 300 m, show that the flow consists of a felsic lower unit (100 m thick) overlain sharply by a more mafic upper unit. The mafic upper unit is chemically zoned, becoming slightly more evolved upward; the lower unit is heterogeneous and unzoned. The lower unit is also more phenocryst-rich and locally contains inclusions of quenched basaltic andesite magma that are absent from the upper unit. Widespread, vuggy, gabbronorite-to-diorite inclusions may be fragments of shallow cumulates, exhumed from the Mount Rainier magmatic system. Chemically heterogeneous block-and-ash-flow deposits that conformably underlie the lava flow were the earliest products of the eruptive episode. The felsic-mafic-felsic progression in lava composition resulted from partial evacuation of a vertically-zoned magma reservoir, in which either (1) average depth of withdrawal increased, then decreased, during eruption, perhaps due to variations in effusion rate, or (2) magmatic recharge stimulated ascent of a plume that brought less evolved magma to shallow levels at an intermediate stage of the eruption. Pre-eruptive zonation resulted from combined crystallization- differentiation and intrusion(s) of less evolved magma into the partly crystallized resident magma body. The zoned lava flow at Burroughs Mountain shows that, at times, Mount Rainier's magmatic system has developed relatively large, shallow reservoirs that, despite complex recharge events, were capable of developing a felsic-upward compositional zonation similar to that inferred from large ash-flow sheets and other zoned lava flows. ?? 2002 Elsevier Science B.V. All rights reserved.

Late Cretaceous (ca. 95 Ma) magnesian andesites in the Biluoco area, southern Qiangtang subterrane, central Tibet: Petrogenetic and tectonic implications

NASA Astrophysics Data System (ADS)

He, Haiyang; Li, Yalin; Wang, Chengshan; Zhou, Aorigele; Qian, Xinyu; Zhang, Jiawei; Du, Lintao; Bi, Wenjun

2018-03-01

The tectonic evolutionary history of the Lhasa and Qiangtang collision zones remains hotly debated because of the lack of pivotal magmatic records in the southern Qiangtang subterrane, central Tibet. We present zircon U-Pb dating, whole-rock major and trace-element geochemical analyses, and Sr-Nd isotopic data for the newly discovered Biluoco volcanic rocks from the southern Qiangtang subterrane, central Tibet. Zircon U-Pb dating reveals that the Biluoco volcanic rocks were crystallized at ca. 95 Ma. The samples are characterized by low SiO2 (50.26-54.53 wt%), high Cr (109.7-125.92 ppm) and Ni (57.4-71.58 ppm), and a high Mg# value (39-56), which plot in the magnesian andesites field on the rock classification diagram. They display highly fractionated rare earth element patterns with light rare earth element enrichment ([La/Yb]N = 21.04-25.24), high Sr/Y (63.97-78.79) and no negative Eu anomalies (Eu/Eu* = 0.98-1.04). The Biluoco volcanic rocks are depleted in Nb, Ta and Ti and enriched in Ba, Th, U and Pb. Moreover, the eight samples of Biluoco volcanic rocks display constant (87Sr/86Sr)i ratios (0.70514-0.70527), a positive εNd(t) value (2.16-2.68) and younger Nd model ages (0.56-0.62 Ga). These geochemical signatures indicate that the Biluoco volcanic rocks were most likely derived from partial melting of the mantle wedge peridotite metasomatized by melts of subducted slab and sediment in the subducted slab, invoked by asthenospheric upwelling resulting from the slab break-off of the northward subduction of the Bangong-Nujiang oceanic lithosphere. Identification of ca. 95 Ma Biluoco magnesian andesites suggests they were a delayed response of slab break-off of the northward subduction of the Bangong-Nujiang oceanic lithosphere at ca. 100 Ma.

Volatile abundances and oxygen isotopes in basaltic to dacitic lavas on mid-ocean ridges: The role of assimilation at spreading centers

USGS Publications Warehouse

Wanless, V.D.; Perfit, M.R.; Ridley, W.I.; Wallace, P.J.; Grimes, Craig B.; Klein, E.M.

2011-01-01

Most geochemical variability in MOR basalts is consistent with low- to moderate-pressure fractional crystallization of various mantle-derived parental melts. However, our geochemical data from MOR high-silica glasses, including new volatile and oxygen isotope data, suggest that assimilation of altered crustal material plays a significant role in the petrogenesis of dacites and may be important in the formation of basaltic lavas at MOR in general. MOR high-silica andesites and dacites from diverse areas show remarkably similar major element trends, incompatible trace element enrichments, and isotopic signatures suggesting similar processes control their chemistry. In particular, very high Cl and elevated H2O concentrations and relatively light oxygen isotope ratios (~ 5.8‰ vs. expected values of ~ 6.8‰) in fresh dacite glasses can be explained by contamination of magmas from a component of ocean crust altered by hydrothermal fluids. Crystallization of silicate phases and Fe-oxides causes an increase in δ18O in residual magma, but assimilation of material initially altered at high temperatures results in lower δ18O values. The observed geochemical signatures can be explained by extreme fractional crystallization of a MOR basalt parent combined with partial melting and assimilation (AFC) of amphibole-bearing altered oceanic crust. The MOR dacitic lavas do not appear to be simply the extrusive equivalent of oceanic plagiogranites. The combination of partial melting and assimilation produces a distinct geochemical signature that includes higher incompatible trace element abundances and distinct trace element ratios relative to those observed in plagiogranites.

Analysis of noise pollution in an andesite quarry with the use of simulation studies and evaluation indices.

PubMed

Kosała, Krzysztof; Stępień, Bartłomiej

2016-01-01

This paper presents the verification of two partial indices proposed for the evaluation of continuous and impulse noise pollution in quarries. These indices, together with the sound power of machines index and the noise hazard index at the workstation, are components of the global index of assessment of noise hazard in the working environment of a quarry. This paper shows the results of acoustic tests carried out in an andesite quarry. Noise generated by machines and from performed blasting works was investigated. On the basis of acoustic measurements carried out in real conditions, the sound power levels of machines and the phenomenon of explosion were determined and, based on the results, three-dimensional models of acoustic noise propagation in the quarry were developed. To assess the degree of noise pollution in the area of the quarry, the continuous and impulse noise indices were used.

Early Archean sialic crust of the Siberian craton: Its composition and origin of magmatic protoliths

NASA Astrophysics Data System (ADS)

Vovna, G. M.; Mishkin, M. A.; Sakhno, V. G.; Zarubina, N. V.

2009-12-01

This study demonstrates that the base of the Archean deep-seated granulite complexes within the Siberian craton consists of a metabasite-enderbite association. The major and trace element distribution patterns revealed that the protoliths of this association are represented by calc-alkaline andesites and dacites, containing several minor sequences of komatiitic-tholeiitic volcanic rocks. The origin of the primary volcanic rocks of the metabasite-enderbite association is inferred on the basis of a model of mantle plume magmatism, which postulates that both andesitic and dacitic melts were derived from the primary basitic crust at the expense of heat generated by ascending mantle plumes. The formation of the protoliths of the Archen metabasite-enderbite association of the Siberian craton began at 3.4 Ga and continued until the late Archean.

Sorptive removal of nickel onto weathered basaltic andesite products: kinetics and isotherms.

PubMed

Shah, Bhavna A; Shah, Ajay V; Singh, Rajesh R; Patel, Nayan B

2009-07-15

The suitability of weathered basaltic andesite products (WBAP) as a potential sorbent was assessed for the removal of Ni (II) from electroplating industrial wastewater. A model study based on the batch mode of operation was carried out for Ni (II) removal from aqueous solution. The effect of various parameters such as hydronium ion concentration, shaking time, sorbent dose, initial Ni (II) concentration, and temperature on the sorption process was studied. At optimised conditions of the various parameters, the industrial wastewater loaded with Ni (II) was sorbed onto WBAP. Thermodynamic parameters for the sorption process were evaluated. Freundlich, Langmuir, Temkin, and Dubinin-Kaganer-Radushkevich isotherms were applied to the sorption pattern on the WBAP. The sorption dynamics of the process was evaluated by applying Lagergren, Bangham, and Weber & Morris equations. The sorption process follows Pseudo-second-order rate of surface diffusion which is identified as the predominating mechanism. The sorption process was found to be reversible by the recovery of sorbed Ni (II) upon extraction with 0.5 MHNO3. The sorbent before and after sorption, was characterized by Fourier transform infrared (FTIR), Powder X-Ray diffraction PXRD), and Thermogravimetric analysis (TGA) methods. The change in surface morphology and crystallanity of the mineral after sorption was analyzed by Scanning electron microscopy (SEM) and Transmission electron microscopy (TEM). Based on the previous model study, an electroplating industrial effluent was successfully treated with WBAP to minimize the pollution load caused by Ni (II).

Eruptive history of Mount Mazama and Crater Lake Caldera, Cascade Range, U.S.A.

USGS Publications Warehouse

Bacon, C.R.

1983-01-01

New investigations of the geology of Crater Lake National Park necessitate a reinterpretation of the eruptive history of Mount Mazama and of the formation of Crater Lake caldera. Mount Mazama consisted of a glaciated complex of overlapping shields and stratovolcanoes, each of which was probably active for a comparatively short interval. All the Mazama magmas apparently evolved within thermally and compositionally zoned crustal magma reservoirs, which reached their maximum volume and degree of differentiation in the climactic magma chamber ??? 7000 yr B.P. The history displayed in the caldera walls begins with construction of the andesitic Phantom Cone ??? 400,000 yr B.P. Subsequently, at least 6 major centers erupted combinations of mafic andesite, andesite, or dacite before initiation of the Wisconsin Glaciation ??? 75,000 yr B.P. Eruption of andesitic and dacitic lavas from 5 or more discrete centers, as well as an episode of dacitic pyroclastic activity, occurred until ??? 50,000 yr B.P.; by that time, intermediate lava had been erupted at several short-lived vents. Concurrently, and probably during much of the Pleistocene, basaltic to mafic andesitic monogenetic vents built cinder cones and erupted local lava flows low on the flanks of Mount Mazama. Basaltic magma from one of these vents, Forgotten Crater, intercepted the margin of the zoned intermediate to silicic magmatic system and caused eruption of commingled andesitic and dacitic lava along a radial trend sometime between ??? 22,000 and ??? 30,000 yr B.P. Dacitic deposits between 22,000 and 50,000 yr old appear to record emplacement of domes high on the south slope. A line of silicic domes that may be between 22,000 and 30,000 yr old, northeast of and radial to the caldera, and a single dome on the north wall were probably fed by the same developing magma chamber as the dacitic lavas of the Forgotten Crater complex. The dacitic Palisade flow on the northeast wall is ??? 25,000 yr old. These relatively

Late Neoproterozoic adakitic lavas in the Arabian-Nubian shield, Sinai Peninsula, Egypt

NASA Astrophysics Data System (ADS)

Abdelfadil, Khaled M.; Obeid, Mohamed A.; Azer, Mokhles K.; Asimow, Paul D.

2018-06-01

The Sahiya and Khashabi volcano-sedimentary successions are exposed near the southern tip of the Sinai Peninsula, the northernmost segment of the Arabian-Nubian Shield (ANS). These Neoproterozoic successions include a series of intermediate to acidic lavas and associated pyroclastic deposits. Field observations and geochemical data reveal two distinct eruptive phases. The lavas representing each phase are intercalated with volcaniclastic greywackes and siltstones. The first eruptive phase, well exposed at Wadi Sahiya, includes basaltic andesite, andesite and dacite with minor rhyolite. The rocks of this sequence are at most weakly deformed and slightly metamorphosed. The second eruptive phase, well exposed at Wadi Khashabi, includes only undeformed and unmetamorphosed dacite and rhyolite. The two volcano-sedimentary successions were separated and dismembered during intrusion of post-collisional calc-alkaline and alkaline granites. Geochemical compositions of the Sahiya and Khashabi volcanic rocks confirm the field data indicating discrete phases of magmatism, however all the compositions observed might plausibly be derived from a common source and be related to one another dominantly through fractional crystallization. The low and variable Mg# values (55-33) measured in the basaltic andesites and andesites preclude their equilibration with a mantle source. Rather, even the most primitive observed lavas are already the products of significant fractional crystallization, dominated by removal of amphibole and plagioclase. Continued fractionation eventually produced dacite and rhyolite marked by significant depletion in Y and HREE. The gradual appearance of negative Nb-Ta anomalies with increasing SiO2 through both suites suggests at least some component of progressive crustal contamination. The medium- to high-K calc-alkaline character of the Sahiya and Khashabi volcanics could be explained either by their formation at an active continental margin or by a two

Mesozoic high-Mg andesites from the Daohugou area, Inner Mongolia: Upper-crustal fractional crystallization of parental melt derived from metasomatized lithospheric mantle wedge

NASA Astrophysics Data System (ADS)

Meng, Fanxue; Gao, Shan; Song, Zhaojun; Niu, Yaoling; Li, Xuping

2018-03-01

Mineral chemistry, major- and trace-element data, zircon U-Pb ages, and Sr-Nd isotopic data are presented for a suite of volcanic rocks from the Daohugou area, Ningcheng City, Inner Mongolia, on the northern margin of the North China Craton. Samples from the suite are of basaltic andesite to rhyolite in composition, with the rocks containing <60 wt% SiO2 have high MgO, Cr, and Ni contents, and classify as high-Mg andesites (HMAs). Zircons from a rhyolite yielded weighted mean 206Pb/238U age of 164 ± 1 Ma, indicating that the Daohugou volcanic suite is coeval with the Tiaojishan Formation of northern Hebei and western Liaoning Province. The HMAs have similar enriched-mantle I (EMI)-type isotopic compositions to each other, with low εNd (t) values, moderate (87Sr/86Sr) i ratios, enrichment in LREEs relative to LILEs, and depletion in HFSEs (e.g., Nb, Ta, Ti), indicating formation through protracted fractional crystallization of a common parental magma. The unusually low CaO contents and CaO/FeO ratios of olivine phenocrysts in the HMAs suggest that the parental melt was subduction-related. The results of Rhyolite-MELTS modelling indicates that HMAs may form through upper-crustal fractional crystallization from arc basalts. Therefore, the Daohugou HMAs were most likely formed through fractional crystallization of a parental melt derived from metasomatized lithospheric mantle at crustal depths. The addition of "water" to the cratonic keel may have played a key role in the destruction of the North China Craton.

Mineral resources of the Sheepshead Mountains, Wildcat Canyon, and Table Mountain Wilderness Study Areas, Malheur and Harney counties, Oregon

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sherrod, D.R.; Griscom, A.; Turner, R.L.

1988-01-01

The Sheepshead Mountains, Wildcat Canyon, and Table Mountain Wilderness Study Areas encompass most of the Sheepshead Mountains in southeast Oregon. The mountains comprise several fault blocks of middle and late Miocene basalt, basaltic andesite, andesite, and dacite lava; pyroclastic and sedimentary rocks are minor. The three wilderness study areas have low resource potential for gold, silver, and oil and gas. A few small areas have low-to-high resource potential for diatomite, as indicated by the occurrence of low-grade diatomite. Some fault zones have a moderate potential for geothermal energy.

Postglacial eruptive history, geochemistry, and recent seismicity of Aniakchak volcano, Alaska Peninsula

USGS Publications Warehouse

Bacon, Charles R.; Neal, Christina A.; Miller, Thomas P.; McGimsey, Robert G.; Nye, Christopher J.

2014-01-01

Future volcanic activity of Aniakchak could include hydromagmatic explosions, possibly followed by effusion or strombolian eruption of basaltic andesite to Plinian eruption of dacite. Another voluminous eruption, such as Aniakchak II, is considered unlikely in the near future.

Geology, geochemistry, geochronology, and economic potential of Neogene volcanic rocks in the Laguna Pedernal and Salar de Aguas Calientes segments of the Archibarca lineament, northwest Argentina

NASA Astrophysics Data System (ADS)

Richards, J. P.; Jourdan, F.; Creaser, R. A.; Maldonado, G.; DuFrane, S. A.

2013-05-01

This study presents new geochemical, geochronological, isotopic, and mineralogical data, combined with new geological mapping for a 2400 km2 area of Neogene volcanic rocks in northwestern Argentina near the border with Chile, between 25°10‧S and 25°45‧S. The area covers the zone of intersection between the main axis of the Cordillera Occidental and a set of NW-SE-trending structures that form part of the transverse Archibarca lineament. This lineament has localized major ore deposits in Chile (e.g., the late Eocene La Escondida porphyry Cu deposit) and large volcanic centers such as the active Llullaillaco and Lastarría volcanoes on the border between Chile and Argentina, and the Neogene Archibarca, Antofalla, and Cerro Galán volcanoes in Argentina. Neogene volcanic rocks in the Laguna Pedernal and Salar de Aguas Calientes areas are mostly high-K calc-alkaline in composition, and range from basaltic andesites, through andesites and dacites, to rhyolites. Magmatic temperatures and oxidation states, estimated from mineral compositions, range from ~ 1000 °C and ∆FMQ ≈ 1.0-1.5 in andesites, to ~ 850 °C and ∆FMQ ≈ 1.5-2.0 in dacites and rhyolites. The oldest rocks consist of early-middle Miocene andesite-dacite plagioclase-pyroxene-phyric lava flows and ignimbrites, with 40Ar/39Ar ages ranging from 17.14 ± 0.10 Ma to 11.76 ± 0.27 Ma. Their major and trace element compositions are typical of the Andean Central Volcanic Zone, and show strong crustal contamination trends for highly incompatible elements such as Cs, Rb, Th, and U. These rocks are geochemically grouped as sub-suite 1. This widespread intermediate composition volcanism was followed in the middle-late Miocene by a period of more focused rhyodacitic flow-dome complex formation. These felsic rocks are characterized by less extreme enrichments in highly incompatible elements, and increasing depletion of heavy rare earth elements. These rocks are geochemically grouped as sub-suite 2. The

Reconstructing multiple arc-basin systems in the Altai-Junggar area (NW China): Implications for the architecture and evolution of the western Central Asian Orogenic Belt

NASA Astrophysics Data System (ADS)

Li, Di; He, Dengfa; Tang, Yong

2016-05-01

The Altai-Junggar area in northwestern China is a critical region to gain insights on the tectonic framework and geological evolution of the western Central Asian Orogenic Belt (CAOB). In this study, we report results from integrated geological, geochemical and geophysical investigations on the Wulungu Depression of the Junggar Basin to determine the basement nature of the basin and understand its amalgamation history with the Chinese Altai, within the broad tectonic evolution of the Altai-Junggar area. Based on borehole and seismic data, the Wulungu Depression is subdivided into two NW-trending tectonic units (Suosuoquan Sag and Hongyan High) by southward-vergent thrust faults. The Suosuoquan Sag consists of the Middle-Late Devonian basaltic andesite, andesite, dacite, tuff, tuffaceous sandstone and tuffite, and the overlying Early Carboniferous volcano-sedimentary sequence with lava flows and shallow marine sediments from a proximal juvenile provenance (zircon εHf(t) = 6.0-14.9), compared to the Late Carboniferous andesite and rhyolite in the Hongyan High. Zircon SIMS U-Pb ages for dacites and andesites indicate that these volcanics in the Suosuoquan Sag and Hongyan High erupted at 376.3 Ma and 313.4 Ma, respectively. The Middle-Late Devonian basaltic andesites from well LC1 are calc-alkaline and exhibit primitive magma-like MgO contents (7.9-8.6%) and Mg# values (66-68), with low initial 87Sr/86Sr (0.703269-0.704808) and positive εNd(t) values (6.6-7.6), and relatively high Zr abundance (98.2-116.0 ppm) and Zr/Y ratios (5.1-5.4), enrichment in LREEs and LILEs (e.g., Th and U) and depletion in Nb, Ta and Ti, suggesting that they were probably derived from a metasomatized depleted mantle in a retro-arc extensional setting. The well LC1 andesitic tuffs, well L8 dacites, well WL1 dacitic tuffs and well L5 andesites belong to calc-alkaline and metaluminous to peraluminous (A/CNK = 0.8-1.7) series, and display low Mg# values (35-46) and variably positive εNd(t) (4

Rapid crystallization during recycling of basaltic andesite tephra: timescales determined by reheating experiments

PubMed Central

Deardorff, Nicholas; Cashman, Katharine

2017-01-01

Microcrystalline inclusions within microlite-poor matrix are surprisingly common in low intensity eruptions around the world, yet their origin is poorly understood. Inclusions are commonly interpreted as evidence of crystallization along conduit margins. Alternatively, these clasts may be recycled from low level eruptions where they recrystallize by heating within the vent. We conducted a series of experiments heating basaltic andesite lapilli from temperatures below the glass transition (~690 °C) to above inferred eruption temperatures (>1150 °C) for durations of 2 to >60 minutes. At 690 °C < T < 800 °C, crystallization is evident after heating for ~20 minutes; at T > 800 °C, crystallization occurs in <5 minutes. At T ≥ 900 °C, all samples recrystallize extensively in 2–10 minutes, with pyroxenes, Fe-oxides, and plagioclase. Experimental crystallization textures closely resemble those observed in natural microcrystalline inclusions. Comparison of inclusion textures in lapilli from the active submarine volcano NW Rota-1, Mariana arc and subaerial volcano Stromboli suggest that characteristic signatures of clast recycling are different in the two environments. Specifically, chlorine assimilation provides key evidence of recycling in submarine samples, while bands of oxides bordering microcrystalline inclusions are unique to subaerial environments. Correct identification of recycling at basaltic vents will improve (lower) estimates of mass eruption rate and help to refine interpretations of eruption dynamics. PMID:28402339

Katmai volcanic cluster and the great eruption of 1912

USGS Publications Warehouse

Hildreth, W.; Fierstein, J.

2000-01-01

In June 1912, the world's largest twentieth century eruption broke out through flat-lying sedimentary rocks of Jurassic age near the base of Trident volcano on the Alaska Peninsula. The 60 h ash-flow and Plinian eruptive sequence excavated and subsequently backfilled with ejecta a flaring funnel-shaped vent since called Novarupta. The vent is adjacent to a cluster of late Quaternary stratocones and domes that have released about 140 km3 of magma in the past 150 k.y. Although the 1912 vent is closest to the Trident group and is also close to Mageik and Griggs volcanoes, it was the summit of Mount Katmai, 10 km east of Novarupta, that collapsed during the eruption to form a 5.5 km3 caldera. Many earthquakes, including 14 in the range M 6-7, took place during and after the eruption, releasing 250 times more seismic energy than the 1991 caldera-forming eruption of the Philippine volcano, Pinatubo. The contrast in seismic behavior may reflect the absence of older caldera faults at Mount Katmai, lack of upward (subsidence opposing) magma flow owing to lateral magma withdrawal in 1912, and the horizontally stratified structure of the thick shale-rich Mesozoic basement. The Katmai caldera compensates for only 40% of the 13 km3 of 1912 magma erupted, which included 7-8 km3 of slightly zoned high-silica rhyolite and 4.5 km3 of crystal-rich dacite that grades continuously into 1 km3 of crystal-rich andesite. We have now mapped, sampled, and studied the products of all 20 components of the Katmai volcanic cluster. Pyroxene dacite and silicic andesite predominate at all of them, and olivine andesite is also common at Griggs, Katmai, and Trident volcanoes, but basalt and rhyodacite have erupted only at Mount Katmai. Rhyolite erupted only in 1912 and is otherwise absent among Quaternary products of the cluster. Pleistocene products of Mageik and Trident and all products of Griggs are compositionally distinguishable from those of 1912 at Novarupta. Holocene products of Mount

Heterogeneity of hydrodynamic properties and groundwater circulation of a coastal andesitic volcanic aquifer controlled by tectonic induced faults and rock fracturing - Martinique island (Lesser Antilles - FWI)

NASA Astrophysics Data System (ADS)

Vittecoq, B.; Reninger, P. A.; Violette, S.; Martelet, G.; Dewandel, B.; Audru, J. C.

2015-10-01

We conducted a multidisciplinary study to analyze the structure and the hydrogeological functioning of an andesitic coastal aquifer and to highlight the importance of faults and associated rock fracturing on groundwater flow. A helicopter-borne geophysical survey with an unprecedented resolution (SkyTEM) was flown over this aquifer in 2013. TDEM resistivity, total magnetic intensity, geological and hydrogeological data from 30 boreholes and two pumping tests were correlated, including one which lasted an exceptional 15 months. We demonstrate that heterogeneous hydrodynamic properties and channelized flows result from tectonically-controlled aquifer compartmentalization along the structural directions of successive tectonic phases. Significant fracturing of the central compartment results in enhanced hydrodynamic properties of the aquifer and an inverse relationship between electrical resistivity and transmissivity. Basalts within the fractured compartment have lower resistivity and higher permeability than basalts outside the compartment. Pumping tests demonstrate that the key factor is the hydraulic conductivity contrast between compartments rather than the hydrodynamic properties of the fault structure. In addition, compartmentalization and associated transmissivity contrasts protect the aquifer from seawater intrusion. Finally, unlike basaltic volcanic islands, the age of the volcanic formations is not the key factor that determines hydrodynamic properties of andesitic islands. Basalts that are several million years old (15 Ma here) have favorable hydrodynamic properties that are generated or maintained by earthquakes/faulting that result from active subduction beneath these islands, which is superimposed on their primary permeability.

Multiplets: Their behavior and utility at dacitic and andesitic volcanic centers

USGS Publications Warehouse

Thelen, W.; Malone, S.; West, M.

2011-01-01

Multiplets, or groups of earthquakes with similar waveforms, are commonly observed at volcanoes, particularly those exhibiting unrest. Using triggered seismic data from the 1980-1986 Mount St. Helens (MSH) eruption, we have constructed a catalog of multiplet occurrence. Our analysis reveals that the occurrence of multiplets is related, at least in part, to the viscosity of the magma. We also constructed catalogs of multiplet occurrence using continuous seismic data from the 2004 eruption at MSH and 2007 eruption at Bezymianny Volcano, Russia. Prior to explosions at MSH in 2004 and Bezymianny in 2007, the multiplet proportion of total seismicity (MPTS) declined, while the average amplitudes and standard deviations of the average amplitude increased. The life spans of multiplets (time between the first and last event) were also shorter prior to explosions than during passive lava extrusion. Dome-forming eruptions that include a partially solidified plug, like MSH (1983-1986 and 2004-2008), often possess multiplets with longer life spans and MPTS values exceeding 50%. Conceptually, the relatively unstable environment prior to explosions is characterized by large and variable stress gradients brought about by rapidly changing overpressures within the conduit. We infer that such complex stress fields affect the number of concurrent families, MPTS, average amplitude, and standard deviation of the amplitude of the multiplets. We also argue that multiplet detection may be an important new monitoring tool for determining the timing of explosions and in forecasting the type of eruption.

Complexities of plinian fall deposition at vent: An example from the 1912 Novarupta eruption (Alaska)

USGS Publications Warehouse

Fierstein, J.; Houghton, Bruce F.; Wilson, C.J.N.; Hildreth, W.

1997-01-01

An extremely proximal ejecta ring, with exposures to within 100 m of vent, was deposited during later-stage plinian fall activity during the 1912 Novarupta eruption in Alaska. One bed in the ejecta ring (bed S) contains predominantly andesitic clasts which serve to delineate the striking contrast in thinning rates along dispersal axis of the ejecta ring [Pyle bt values of 70 m (bed S alone) or 190 m (whole ejecta ring)] and the coeval dacitic plinian fall deposits [Pyle bt, values of 4 km (proximal) and 37 km (medial-distal)]. The locally deposited andesitic and dacitic clasts of the ejecta ring are interpreted as products of an irregular 'collar' of low-fountaining ejecta partially sheathing the core of higher-velocity dacitic ejecta that fed the stable, convecting 23-km-high column. The presence of such an extremely proximal accumulation of ejecta appears to be a feature common to several other historic eruptions that generated widespread fall deposits. This feature in part accounts for conflicts between measured and calculated values for thickness maxima in plinian fall deposits and suggests that modifications may be required of existing models for plinian eruption columns.

Experimental constraints on the origin of high-Mg andesites: the effect of H2O and silica activity on mantle melt compositions

NASA Astrophysics Data System (ADS)

Moore, G. M.; Roggensack, K.

2009-12-01

Understanding the role volatiles (H2O, CO2) play in the origin of mantle-related melts is an important part of arc magma petrogenesis, and has implications for our understanding of many aspects of subduction zone volcanism including mass fluxes, volcanic degassing, and eruptive style. Both the occurrence of high-Mg andesites (HMA) in particular tectonic settings and their association with high H2O contents make HMA a unique window into hydrous subduction-related mantle melting processes. A significant amount of experimental work at mantle conditions has shown that increasing H2O content in the melt will not only stabilize olivine with respect to orthopyroxene, but will also increase the SiO2 content of the melt to andesitic amounts (e.g. Gaetani and Grove, 1998; Tatsumi, 1981; Tatsumi, 2006), suggesting that HMA could be a primary mantle melt if enough H2O is present. This hypothesis is supported by the rare occurrence of mantle xenoliths in Mg-rich andesites (Blatter and Carmichael, 1998; Tanaka and Aoki, 1981) that often contain hydrous mineral phases. Reliable thermodynamic modelling of such hydrous silicate melts in equilibrium with the mantle has proven difficult because of the relatively small set of experiments that allow this type of analysis. There are also experimental and analytical difficulties in dealing with hydrous high P-T samples (e.g. quench to a glass, rapid melt-solid reaction on quench, electron beam sensitivity of resulting glass, volatile content determination, etc), and statistical difficulties in determining robust model parameters because of the large degree of co-variance in the data set (e.g. T and H2O melt content). With the goal of addressing these problems, we conducted a series of “sandwich” type experiments at 1.0 GPa and 1200 deg C that saturated various hydrous melt compositions with olivine and opx. Our previous results have shown that the silica activity coefficient correlates negatively with H2O content (Moore and

Pre-eruptive rejuvenations of crystalline mush by reservoir heating: the case of trachy-dacitic lavas of Quetrupillán Volcanic Complex, Chile (39º30' lat. S)

NASA Astrophysics Data System (ADS)

Brahm, R.; Parada, M. Á.; Morgado, E. E.; Contreras, C.

2015-12-01

The Southern Volcanic Zone of the Andes is dominated by mainly basaltic to andesitic products, as is the case of the Villarrica 2015 eruption. An exception is the case of the nearby Quetrupillán Volcanic Complex (QVC). The QVC forms part of the NW-SE Villarrica-Quetrupillán-Lanín active volcanic chain and contains products of mainly trachy-dacitic composition that differs from the basaltic and basaltic-andesite composition of the neighboring stratovolcanoes. The studied Holocene QVC trachy-dacites exhibit similar geochemical, mineralogical features. They are crystal-poor (<12% phenocrysts) with phenocrysts occurring as isolated crystals or forming crystal clots within a glass-rich groundmass. Two groups of plagioclase phenocrysts were found: Group 1 plagioclases are commonly associated with pyroxene in crystal clots and with oscillatory zoning of An40-50, and Group 2 plagioclases occur as isolated crystals of variable composition (An70-85), with rims of similar composition to Group 1. Some Group 2 crystals have cores with compositions similar to the rims with resorption features. Clinopyroxenes within clots have compositions of En40-46Fs11-21Wo39-43 similar to the isolated clinopyroxenes. Orthopyroxene phenocrysts have composition of En36-68Fs15-34Wo03-04. Microphenocrysts of magnetite-ilmenite pairs (Mt14-36-Il90-94) were identified. Pyroxene phenocrysts are in disequilibrium with the whole-rock composition, suggesting that they are antecrysts. Two-pyroxene thermometry gives temperatures of 911-980ºC, while the Mt-Il equilibrium gives higher temperatures of 963-1114ºC, for the later stages of lava crystallization. The presence of a crystalline mush is suggested by the abundance of crystal clots in disequilibrium with the host rock composition whose calculated formation conditions of 0.5-1.5 kbar, 950-990ºC and 2.1-3.1 wt% of H2O, were obtained from a Rhyolite-MELTS simulation. Rejuvenation of a crystal mush by reservoir heating events is suggested due to

Attaining high-resolution eruptive histories for active arc volcanoes with argon geochronology

NASA Astrophysics Data System (ADS)

Calvert, A. T.

2012-04-01

Geochronology of active arc volcanoes commonly illuminates eruptive behavior over tens to hundreds of thousands of years, lengthy periods of repose punctuated by short eruptive episodes, and spatial and compositional changes with time. Despite the >1 Gyr half-life of 40K, argon geochronology is an exceptional tool for characterizing Pleistocene to Holocene eruptive histories and for placing constraints on models of eruptive behavior. Reliable 40Ar/39Ar ages of calc-alkaline arc rocks with rigorously derived errors small enough (± 500 to 3,000 years) to constrain eruptive histories are attainable using careful procedures. Sample selection and analytical work in concert with geologic mapping and stratigraphic studies are essential for determining reliable eruptive histories. Preparation, irradiation and spectrometric techniques have all been optimized to produce reliable, high-precision results. Examples of Cascade and Alaska/Aleutian eruptive histories illustrating duration of activity from single centers, eruptive episodicity, and spatial and compositional changes with time will be presented: (1) Mt. Shasta, the largest Cascade stratovolcano, has a 700,000-year history (Calvert and Christiansen, 2011 Fall AGU). A similar sized and composition volcano (Rainbow Mountain) on the Cascade axis was active 1200-950 ka. The eruptive center then jumped west 15 km to the south flank of the present Mt. Shasta and produced a stratovolcano from 700-450 ka likely rivaling today's Mt. Shasta. The NW portion of that edifice failed in an enormous (>30 km3) debris avalanche. Vents near today's active summit erupted 300-135 ka, then 60-15 ka. A voluminous, but short-lived eruptive sequence occurred at 11 ka, including a summit explosion producing a subplinian plume, followed by >60 km3 andesite-dacite Shastina domes and flows, then by the flank dacite Black Butte dome. Holocene domes and flows subsequently rebuilt the summit and flowed to the north and east. (2) Mt. Veniaminof on

Magmatic processes at Popocatepetl volcano, Mexico: petrology, geochemistry and Sr-Nd-Pb isotopes

NASA Astrophysics Data System (ADS)

Schaaf, P.; Stimac, J.; Siebe, C.; Mac¡as, J.

2003-12-01

Popocatepetl volcano is one of the most famous and most active stratovolcanoes of the Trans-Mexican Volcanic Belt (TMVB). It is located 60 km south-east of Mexico-City and 40 km west of the city of Puebla, both cities have more than 30 million inhabitants. In this contribution we present a study of Late Pleistocene to Recent products of Popocatépetl (Popo) volcano and surrounding scoria cones to better establish their genetic relationship and magmatic history. Popo and flanking vents are located within the central portion of the Trans Mexican Volcanic Belt, which is related to oblique subduction of young oceanic lithosphere. Current activity of Popo can be understood in the context of its past eruptions and those from surrounding scoria cones. The latest cycle of eruption began Dec. 21, 1994 with continuous to pulsating emission of phreatic ash. The last important event happened on July 19, 2003, covering Mexico-City with a thin ash-layer. Both Popo and surrounding scoria cones produced moderate-K, calc-alkaline rocks, with the two groups differing mainly in degree of differentiation, water content, and oxidation state. Some vent samples on the immediate flanks of Popo and have phenocryst assemblages and compositions transitional between typical flanking vent and stratovolcano samples. Monogenetic vents produced mainly basaltic andesites to andesites, primarily by crystal fractionation of Ol (Fo80-90)+chromite, 2PyxñOl, and 2PyxñPlagñHb assemblages, with minor assimilation of crustal debris. The andesitic to dacitic rocks of Popo are dominated by Plag-2Pyx-2OxideñHbl assemblages, with variable amounts of Ol (Fo70-90)+chromite xenocrysts. A few Popo samples contain locally abundant xenolithic debris of cognate-granitoid intrusions and their metasedimentary wallrocks. The two suites share parental Mg-rich basaltic andesite magmas, with the Popo magmas reflecting longer residence in the crust, and enhanced hydration and oxidation due to the resulting processes of

Vent processes during the 1912 eruption at Novarupta, Katmai National Park, Alaska. Progress report, [November 15, 1991--November 14, 1992

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bates, T.; Eichelberger, J.; Swanson, S.

Blocks of welded fragmental material ejected at Novarupta during the great eruption of 1912 provide evidence of the contents and development of the vent. Because they appear to represent material held at magmatic temperature for hours to days and then quenched at depth and ejected, they provide unusual information on the timing of processes of degassing, welding, and magma mixing. Two breccia types are distinguished by proportions of the three magmatic components. Type 1 breccia (Hildreth`s ``vitrophyre``) is rhyolite- and andesite-rich (``volcanic inclusions`` in the glassy matrix were found to be 1912 andesite), contains abundant lithics, and is found throughoutmore » deposits of the eruption`s second and third days. It corresponds to magmatic proportions being erupted toward the end of the first day, or Episode I. Type 2 is dacite-rich and poor in lithics, and occurs only at the surface. It corresponds to magmatic proportions erupted during Episodes II and III. A pyroclastic dike exposed in a bomb of Type 2 vent breccia is petrologically related to Novarupta lava. Water is strongly but not completely degassed from vent breccias (Type I breccia at 0.30 wt % H{sub 2}O and Type 2 breccia at 0.15 wt % H{sub 2}O even when bread crusted) and more thoroughly degassed from dome lava (rhyolite and andesite at < 0.10 wt % H{sub 2}O), but the pyroclastic dike retains significant water (averages 0.90 wt. % H{sub 2}O) and its host breccia likewise contains elevated water concentrations (0.30--0.40 wt % H{sub 2}O). The mafic component in Novarupta dome is derived from andesitic, rather than dacitic magma, and has crystallized substantially in response to mixing with its cooler host.« less

Origin of secondary sulfate minerals on active andesitic stratovolcanoes

USGS Publications Warehouse

Zimbelman, D.R.; Rye, R.O.; Breit, G.N.

2005-01-01

Sulfate minerals in altered rocks on the upper flanks and summits of active andesitic stratovolcanoes result from multiple processes. The origin of these sulfates at five active volcanoes, Citlalte??petl (Mexico), and Mount Adams, Hood, Rainier, and Shasta (Cascade Range, USA), was investigated using field observations, petrography, mineralogy, chemical modeling, and stable-isotope data. The four general groups of sulfate minerals identified are: (1) alunite group, (2) jarosite group, (3) readily soluble Fe- and Al-hydroxysulfates, and (4) simple alkaline-earth sulfates such as anhydrite, gypsum, and barite. Generalized assemblages of spatially associated secondary minerals were recognized: (1) alunite+silica??pyrite??kaolinite?? gypsum??sulfur, (2) jarosite+alunite+silica; (3) jarosite+smectite+silica??pyrite, (4) Fe- and Al-hydroxysulfates+silica, and (5) simple sulfates+silica??Al-hydroxysulfates??alunite. Isotopic data verify that all sulfate and sulfide minerals and their associated alteration assemblages result largely from the introduction of sulfur-bearing magmatic gases into meteoric water in the upper levels of the volcanoes. The sulfur and oxygen isotopic data for all minerals indicate the general mixing of aqueous sulfate derived from deep (largely disproportionation of SO2 in magmatic vapor) and shallow (oxidation of pyrite or H2S) sources. The hydrogen and oxygen isotopic data of alunite indicate the mixing of magmatic and meteoric fluids. Some alunite-group minerals, along with kaolinite, formed from sulfuric acid created by the disproportionation of SO2 in a condensing magmatic vapor. Such alunite, observed only in those volcanoes whose interiors are exposed by erosion or edifice collapse, may have ??34S values that reflect equilibrium (350??50 ??C) between aqueous sulfate and H2S. Alunite with ??34S values indicating disequilibrium between parent aqueous sulfate and H2S may form from aqueous sulfate created in higher level low

CO2 content of andesitic melts at graphite-saturated upper mantle conditions with implications for redox state of oceanic basalt source regions and remobilization of reduced carbon from subducted eclogite

NASA Astrophysics Data System (ADS)

Eguchi, James; Dasgupta, Rajdeep

2017-03-01

We have performed experiments to determine the effects of pressure, temperature and oxygen fugacity on the CO2 contents in nominally anhydrous andesitic melts at graphite saturation. The andesite composition was specifically chosen to match a low-degree partial melt composition that is generated from MORB-like eclogite in the convective, oceanic upper mantle. Experiments were performed at 1-3 GPa, 1375-1550 °C, and fO2 of FMQ -3.2 to FMQ -2.3 and the resulting experimental glasses were analyzed for CO2 and H2O contents using FTIR and SIMS. Experimental results were used to develop a thermodynamic model to predict CO2 content of nominally anhydrous andesitic melts at graphite saturation. Fitting of experimental data returned thermodynamic parameters for dissolution of CO2 as molecular CO2: ln( K 0) = -21.79 ± 0.04, Δ V 0 = 32.91 ± 0.65 cm3mol-1, Δ H 0 = 107 ± 21 kJ mol-1, and dissolution of CO2 as CO3 2-: ln (K 0 ) = -21.38 ± 0.08, Δ V 0 = 30.66 ± 1.33 cm3 mol-1, Δ H 0 = 42 ± 37 kJ mol-1, where K 0 is the equilibrium constant at some reference pressure and temperature, Δ V 0 is the volume change of reaction, and Δ H 0 is the enthalpy change of reaction. The thermodynamic model was used along with trace element partition coefficients to calculate the CO2 contents and CO2/Nb ratios resulting from the mixing of a depleted MORB and the partial melt of a graphite-saturated eclogite. Comparison with natural MORB and OIB data suggests that the CO2 contents and CO2/Nb ratios of CO2-enriched oceanic basalts cannot be produced by mixing with partial melts of graphite-saturated eclogite. Instead, they must be produced by melting of a source containing carbonate. This result places a lower bound on the oxygen fugacity for the source region of these CO2-enriched basalts, and suggests that fO2 measurements made on cratonic xenoliths may not be applicable to the convecting upper mantle. CO2-depleted basalts, on the other hand, are consistent with mixing between

Preliminary Geothermal Exploration at the Marine Corps Air Ground Combat Center, Twentynine Palms, California

DTIC Science & Technology

1987-09-01

porphyries with olivine phenocrysts. Individual flows may be about 50 feet thick around Pisgah Crater but taper out to a few feet thick at the flow’s...Pleistocene in age (Dibblee, 1966b). SUNSHINE PEAK The dominant rock of Sunshine Peak is dacite porphyry , a gray-white to light greenish- gray rock, with 40...northwest-trending andesite porphyry dikes. 14 ’-WC TP 6747 Roof pendants of biotite quartz monzonite and quartz monzonite occur in the dacite porphyry . The

Assembling an ignimbrite: Compositionally defined eruptive packages in the 1912 Valley of Ten Thousand Smokes ignimbrite, Alaska

USGS Publications Warehouse

Fierstein, J.; Wilson, C.J.N.

2005-01-01

The 1912 Valley of Ten Thousand Smokes (VTTS) ignimbrite was constructed from 9 compositionally distinct, sequentially emplaced packages, each with distinct proportions of rhyolite (R), dacite (D), and andesite (A) pumices that permit us to map package boundaries and flow paths from vent to distal extents. Changing pumice proportions and interbedding relationships link ignimbrite formation to coeval fall deposition during the first ???16 h (Episode I) of the eruption. Pumice compositional proportions in the ignimbrite were estimated by counts on ???100 lapilli at multiple levels in vertical sections wherever accessible and more widely over most of the ignimbrite surface in the VTTS. The initial, 100% rhyolite ignimbrite package (equivalent to regional fall Layer A and occupying ???3.5 h) was followed by packages with increasing proportions of andesite, then dacite, emplaced over ???12.5 h and equivalent to regional fall Layers B1-B3. Coeval fall deposits are locally intercalated with the ignimbrite and show parallel changes in R:D (rhyolite:dacite) proportions, but lack significant amounts of andesite. Andesite was thus dominantly a low-fountaining component in the eruption column and is preferentially represented in packages filling the VTTS north of the vent. The most extensive packages (3 and 4) occur in B1 and early B2 times where flow mobility and volume were optimized; earlier all-rhyolite flows (Package 1) were highly energetic but less voluminous, while later packages (5-9) were both less voluminous and emplaced at lower velocities. Package boundaries are expressed as one or more of the following: sharp color changes corresponding to compositional variations; persistent finer-grained basal parts of flow units; compaction swales filled by later packages; erosional channels cut by the flows that fill them; lobate accumulations of one package; and (mostly south of the vent) intercalated fall deposit layers. Clear flow-unit boundaries are best developed between

Effusive silicic volcanism in the Central Andes: The Chao dacite and other young lavas of the Altiplano-Puna Volcanic Complex

NASA Technical Reports Server (NTRS)

De Silva, S. L.; Self, S.; Francis, P. W.; Drake, R. E.; Ramirez, Carlos R.

1994-01-01

The largest known Quaternary silicic lava body in the world is Cerro Chao in north Chile, a 14-km-long coulee with a volume of at least 26 cu km. It is the largest of a group of several closely similar dacitic lavas erupted during a recent (less than 100,000 year old) magmatic episode in the Altiplano-Puna Volcanic Complex (APVC; 21-24 deg S) of the Centra; Andean Volcanic Zone. The eruption of Chao proceeded in three phases. Phase 1 was explosive and produced approximately 1 cu km of coarse, nonwelded dacitic pumice deposits and later block and ash flows that form an apron in front of the main lava body. Phase 2 was dominantly effusive and erupted approximately 22.5 cu km of magma in the form of a composite coulee covering approximately 53 sq km with a 400-m-high flow front and a small cone of poorly expanded pumice around the vent. The lava is homogeneous with rare flow banding and vesicular tops and selvages. Ogives (flow ridges) reaching heights of 30 m form prominent features on its surface. Phase 3 produced a 6-km-long, 3-km-wide flow that emanated from a collapsed dome. Ogives are subdued, and the lava is glassier than that produced in previous phases. All the Chao products are crystal-rich high-K dacites and rhyodacites with phenocrysts of plagioclase, quartz, hornblende, biotite, sphene, rare snidine, and oxides. Phenocryst contents reach 40-60 vol % (vesicle free) in the main phase 2 lavas but are lower in the phase 1 (20-25%) and phase 3 (approximately 40%) lavas. Ovoid andesitic inclusions with vesicular interiors and chilled margins up to 10 cm are found in the later stages of phase 2 and compose up to 5% of the phase 3 lava. There is little evidence for preeruptive zonation of the magma body in composition, temperature (approximately 840 C), fO2 (19(exp -11), or water content, so we propose that eruption of the Chao complex was driven by intrusion of fresh, hot andesitic magma into a crystallizing and largely homogeneous body of dacitic magma

Magmatic record of Late Devonian arc-continent collision in the northern Qiangtang, Tibet: Implications for the early evolution of East Paleo-Tethys Ocean

NASA Astrophysics Data System (ADS)

Dan, Wei; Wang, Qiang; Zhang, Xiu-Zheng; Zhang, Chunfu; Tang, Gong-Jian; Wang, Jun; Ou, Quan; Hao, Lu-Lu; Qi, Yue

2018-05-01

Recognizing the early-developed intra-oceanic arc is important in revealing the early evolution of East Paleo-Tethys Ocean. In this study, new SIMS zircon U-Pb dating, O-Hf isotopes, and whole-rock geochemical data are reported for the newly-discovered Late Devonian-Early Carboniferous arc in Qiangtang, central Tibet. New dating results reveal that the eastern Riwanchaka volcanic rocks were formed at 370-365 Ma and were intruded by the 360 Ma Gangma Co alkali feldspar granites. The volcanic rocks consist of basalts, andesites, dacites, and rhyodacites, whose geochemistry is similar to that typical of subduction-related volcanism. The basalts and andesites were generated by partial melting of the fluid and sediment-melt metasomatized mantle, respectively. The rhyodacites and dacites were probably derived from the fractional crystallization of andesites and from partial melting of the juvenile underplated mafic rocks, respectively. The Gangma Co alkali feldspar granites are A-type granites, and were possibly derived by partial melting of juvenile underplated mafic rocks in a post-collisional setting. The 370-365 Ma volcanic arc was characterized by basalts with oceanic arc-like Ce/Yb ratios and by rhyodacites with mantle-like or slightly higher zircon δ18O values, and it was associated with the contemporary ophiolites. Thus, we propose that it is the earliest intra-oceanic arc in the East Paleo-Tethys Ocean, and was accreted to the Northern Qiangtang Terrane during 365-360 Ma.

40Ar/39Ar geochronology and geochemical reconnaissance of the Eocene Lowland Creek volcanic field, west-central Montana

USGS Publications Warehouse

Dudas, F.O.; Ispolatov, V.O.; Harlan, S.S.; Snee, L.W.

2010-01-01

We report geochronological and geochemical data for the calc-alkalic Lowland Creek volcanic field (LCVF) in westcentral Montana. 40Ar/ 39Ar age determinations show that the LCVF was active from 52.9 to 48.6 Ma, with tuff-forming eruptions at 52.9 ?? 0.14 and 51.8 ?? 0.14 Ma. These dates span the age range of vigorous Eocene igneous activity in the Kamloops-Absaroka-Challis belt. The LCVF evolved upward from basal rhyolites (SiO 2>71 wt%) to dacites and andesites (SiO 2 > 62 wt%). Compositional change parallels a transition from early explosive volcanism to late effusive activity. Four geochemical components can be detected in the rocks. A component with 206Pb/204Pb < 16.5 and epsilon;Nd near-15 is predominant in anhydrous, two-pyroxene dacites; hydrous rhyolites, rhyodacites, and dacites with epsilon;Nd below-10 are dominated by a second component; hydrous rocks with 206Pb/ 204Pb > 18.3 and epsilon;Nd>-9 contain a third component; and an andesite with low Nd content and epsilon;Nd near-9 probably contains a fourth component. The first three components probably derive from the lower and middle crust, whereas the fourth is probably from the lithospheric mantle. ?? 2010 by The University of Chicago.

Magma storage prior to the 1912 eruption at Novarupta, Alaska

USGS Publications Warehouse

Hammer, J.E.; Rutherford, M.J.; Hildreth, W.

2002-01-01

New analytical and experimental data constrain the storage and equilibration conditions of the magmas erupted in 1912 from Novarupta in the 20th century's largest volcanic event. Phase relations at H2O+CO2 fluid saturation were determined for an andesite (58.7 wt% SiO2) and a dacite (67.7 wt%) from the compositional extremes of intermediate magmas erupted. The phase assemblages, matrix melt composition and modes of natural andesite were reproduced experimentally under H2O-saturated conditions (i.e., PH2O=PTOT) in a negatively sloping region in T-P space from 930 ??C/100 MPa to 960 ??C/75 MPa with fO2???N NO + 1. The H2O-saturated equilibration conditions of the dacite are constrained to a T-P region from 850 ??C/ 50 MPa to 880 ??C/25 MPa. If H2O-saturated, these magmas equilibrated at (and above) the level where coerupted rhyolite equilibrated (???100 MPa), suggesting that the andesite-dacite magma reservoir was displaced laterally rather than vertically from the rhyolite magma body. Natural mineral and melt compositions of intermediate magmas were also reproduced experimentally under saturation conditions with a mixed (H2O + CO2) fluid for the same range in PH2O. Thus, a storage model in which vertically stratified mafic to silicic intermediate magmas underlay H2O-saturated rhyolite is consistent with experimental findings only if the intermediates have XH2Ofl=0.7 and 0.9 for the extreme compositions, respectively. Disequilibrium features in natural pumice and scoria include pristine minerals existing outside their stability fields, and compositional zoning of titanomagnetite in contact with ilmenite. Variable rates of chemical equilibration which would eliminate these features constrain the apparent thermal excursion and re-distribution of minerals to the time scale of days.

Magmatic processes that generated the rhyolite of Glass Mountain, Medicine Lake volcano, N. California

USGS Publications Warehouse

Grove, T.L.; Donnelly-Nolan, J. M.; Housh, T.

1997-01-01

Glass Mountain consists of a 1 km3, compositionally zoned rhyolite to dacite glass flow containing magmatic inclusions and xenoliths of underlying shallow crust. Mixing of magmas produced by fractional crystallization of andesite and crustal melting generated the rhyolite of Glass Mountain. Melting experiments were carried out on basaltic andesite and andesite magmatic inclusions at 100, 150 and 200 MPa, H2O-saturated with oxygen fugacity controlled at the nickel-nickel oxide buffer to provide evidence of the role of fractional crystallization in the origin of the rhyolite of Glass Mountain. Isotopic evidence indicates that the crustal component assimilated at Glass Mountain constitutes at least 55 to 60% of the mass of erupted rhyolite. A large volume of mafic andesite (2 to 2.5 km3) periodically replenished the magma reservoir(s) beneath Glass Mountain, underwent extensive fractional crystallization and provided the heat necessary to melt the crust. The crystalline residues of fractionation as well as residual liquids expelled from the cumulate residues are preserved as magmatic inclusions and indicate that this fractionation process occurred at two distinct depths. The presence and composition of amphibole in magmatic inclusions preserve evidence for crystallization of the andesite at pressures of at least 200 MPa (6 km depth) under near H2O-saturated conditions. Mineralogical evidence preserved in olivine-plagioclase and olivine-plagioclase-high-Ca clinopyroxene-bearing magmatic inclusions indicates that crystallization under near H2O-saturated conditions also occurred at pressures of 100 MPa (3 km depth) or less. Petrologic, isotopic and geochemical evidence indicate that the andesite underwent fractional crystallization to form the differentiated melts but had no chemical interaction with the melted crustal component. Heat released by the fractionation process was responsible for heating and melting the crust.

Oligocene ash flow volcanism, northern Sierra Madre Occidental: Role of mafic and intermediate-composition magmas in rhyolite genesis

NASA Astrophysics Data System (ADS)

Wark, David A.

1991-07-01

Field, geochemical, and isotopic data from the Tomochic volcanic center in Chihuahua, Mexico, are interpreted to indicate a genetic relationship between large-volume rhyolite ash-flow tuffs and associated more mafic lithologies. These lithologies include (1) porphyritic, two-pyroxene andesite (>35 Ma) that was extruded mostly before ash-flow volcanism, and (2) crystal-poor basaltic andesite that was erupted mostly after ash-flow activity (˜30 Ma) but which was also extruded earlier (˜34 Ma) with hybrid intracaldera lavas. Major silicic units at Tomochic include the Vista (˜34 Ma) and Rio Verde (˜32 Ma) rhyolite ash-flow tuffs; also present are ash-flow tuffs (˜38, 36, and 29 Ma) erupted from other sources. A model of rhyolite genesis by closed-system crystal fractionation of andesite is consistent with geochemical and isotopic data. The least evolved Vista rhyolite was formed by fractionation of ˜65% the original mass of andesite; an additional ˜55% fractionation of plagioclase, alkali feldspar, quartz, biotite, hornblende, FeTi oxides, and sphene generated the most evolved Vista sample. Rio Verde rhyolites were generated from andesite by ˜50% mass fractionation of an assemblage dominated by plagioclase, pyroxene, and FeTi oxides. Initial Nd and Sr isotope ratios of andesite-dacite lavas (ɛNd = -2.3 to -5.2; 87Sr/86Sr = 0.7060 to 0.7089) and of rhyolites (ɛNd = +0.5 to -2.7; 87Sr/86Sr = 0.7053 to 0.7066) partly overlap and extend from values near the mantle array toward values typical of old continental crust on an ɛNd-87Sr/86Sr diagram. These isotope ratios, which do not correlate with indices of differentiation, are interpreted to indicate that parental andesite already contained a crustal component (possibly >20%) before fractionation to rhyolite. The isotopic and geochemical signatures of andesites apparently reflect the incorporation of crust by subduction-related, mafic melts represented by (but more primitive than) exposed basaltic andesites

Micro-FTIR Spectroscopy of Experimentally Shocked Basaltic Andesite (SP Flow, AZ)

NASA Astrophysics Data System (ADS)

Johnson, J. R.; Jaret, S.; Glotch, T. D.; Sims, M.

2017-12-01

As part of an ongoing systematic study of experimental shock transformations in plagioclase using micro-Raman and micro-FTIR thermal infrared hyperspectral imaging and point spectroscopy [1-7], we report new micro-FTIR results on experimentally shocked, fine-grained basaltic andesite from SP Flow (AZ). This sample has relatively high primary glass content and an average plagioclase composition of labradorite/bytownite. The powder propellant gun at the Johnson Space Center was used to conduct the original shock experiments at peak pressures from 15 to 60 GPa [6-8], from which <10 mm fragments were recovered. Polished thin sections were made from portions of these fragments, and micro-FTIR point spectra were collected from 400-4000 cm-1 (2.5-25 µm) using a spot size of 40 x 40 mm at 8 cm-1 spectral sampling. Micro-FTIR hyperspectral maps of thin sections were acquired using the same instrument equipped with a 16 pixel HgCdTe linear array detector to provide spectra between 7000 and 715 cm-1 (1.4-14.0 µm) at 25 µm/pixel and 8 cm-1 spectral sampling (see figure for color composite and band depth images from unshocked sample). Micro-FTIR results show that the unshocked sample is dominated by the glassy matrix (light green in the color composite), with contributions from plagioclase and pyroxene. Initial analyses suggest that the SP Flow samples become dominantly amorphous at relatively low shock pressures, reflective of the high primary glass content and consistent with macro-scale spectra from [7]. Results from additional shock pressures and Raman spectra will be presented at the conference. Future work will include (1) Raman and FTIR analyses of basalt from Grand Falls (AZ), which has minimal primary glass content and relatively higher calcic plagioclase than SP Flow; and (2) comparison of these basalts to results from shocked plagioclase and to similar analyses of naturally shocked samples from Ries and Lonar Craters. [1] Jaret, S. et al., 11th Internat. Geo

Chemical Analysis of Reaction Rims on Olivine Crystals in Natural Samples of Black Dacite Using Energy-Dispersive X-Ray Spectroscopy, Lassen Peak, CA.

NASA Astrophysics Data System (ADS)

Graham, N. A.

2014-12-01

Lassen Volcanic Center is the southernmost volcanic region in the Cascade volcanic arc formed by the Cascadia Subduction Zone. Lassen Peak last erupted in 1915 in an arc related event producing a black dacite material containing xenocrystic olivine grains with apparent orthopyroxene reaction rims. The reaction rims on these olivine grains are believed to have formed by reactions that ensued from a mixing/mingling event that occurred prior to eruption between the admixed mafic andesitic magma and a silicic dacite host material. Natural samples of the 1915 black dacite from Lassen Peak, CA were prepared into 15 polished thin sections and carbon coated for analysis using a FEI Quanta 250 Scanning Electron Microscope (SEM) to identify and measure mineral textures and disequilibrium reaction rims. Observed mineralogical textures related to magma mixing include biotite and amphibole grains with apparent dehydration/breakdown rims, pyroxene-rimmed quartz grains, high concentration of microlites in glass matrix, and pyroxene/amphibole reaction rims on olivine grains. Olivine dissolution is evidenced as increased iron concentration toward convolute edges of olivine grains as observed by Backscatter Electron (BSE) imagery and elemental mapping using NSS spectral imaging software. In an attempt to quantify the area of reaction rim growth on olivine grains within these samples, high-resolution BSE images of 30 different olivine grains were collected along with Energy-Dispersive X-Ray Spectroscopy (EDS) of different phases. Olivine cores and rims were extracted from BSE images using Photoshop and saved as separate image files. ImageJ software was used to calculate the area (μm2) of the core and rim of these grains. Average pyroxene reaction rim width for 30 grains was determined to be 11.68+/-1.65 μm. Rim widths of all 30 grains were averaged together to produce an overall average rim width for the Lassen Peak black dacite. By quantifying the reaction rims on olivine grains

Complete zircon and chromite digestion by sintering of granite, rhyolite, andesite and harzburgite rock reference materials for geochronological purposes

NASA Astrophysics Data System (ADS)

Bokhari, Syed Nadeem H.; Meisel, Thomas

2014-05-01

Zircon (ZrSiO4) is a common accessory mineral in nature that occurs in a wide variety of sedimentary, igneous, and metamorphic rocks. Zircon has the ability to retain substantial chemical and isotopic information that are used in range of geochemical and geo- chronological investigations. Sample digestion of such rock types is a limiting factor due to the chemical inertness of zircon (ZrSiO4) tourmaline, chromite, barite, monazite, sphene, xenotime etc. as the accuracy of results relies mainly on recovery of analytes from these minerals. Dissolution by wet acid digestions are often incomplete and high blank and total dissolved solids (TDS) contents with alkali fusions lead to an underestimation of analyte concentrations. Hence an effective analytical procedure, that successfully dissolves refractory minerals such as zircon is needed to be employed for reliable analytical results. Na2O2 digestion [1] was applied in characterisation of granite (G-3), rhyolite (MRH), andesite (MGL-AND) and harzburgite (MUH-1) powdered reference material with solution based ICP-MS analysis. In this study we undertake a systematic evaluation of decomposition time and sample:Na2O2 ratio and test portion size after minimising effect of all other constraints that makes homogeneity ambiguous. In recovering zircon and chromite 100 mg test portion was mixed with different amounts of Na2O2 i.e. 100-600 mg. Impact of decomposition time was observed by systematically increasing heating time from 30-45 minutes to 90-120 minutes at 480°C. Different test portion sizes 100-500 mg of samples were digested to control variance of inhomogeneity. An improved recovery of zirconium in zircon in granite (G-3), rhyolite MRH), andesite (MGL-AND) and chromite in harzburgite (MUH-1) was obtained by increasing heating time (2h) at 480°C and by keeping (1:6) ratio of sample:Na2O2. Through this work it has been established that due to presence of zircon and chromite, decomposition time and sample:Na2O2 ratio has

Stone Quarries and Sourcing in the Carolina Slate Belt

DTIC Science & Technology

2006-04-01

a hilltop with a localized outcrop of small boulders of andesite porphyry . A revisit revealed that the site had recently been destroyed by...rocks are dacitic and include flows, tuffs, breccias, and porphyries . Metasedimentary rocks are metamudstone and fine metasandstone. The Uwharrie...Rocks of this zone, from Shingle Trap, Hattaway, and Sugarloaf Mountains, are mainly light to dark gray metadacite porphyry or metadacitic

Subalkaline andesite from Valu Fa Ridge, a back-arc spreading center in southern Lau Basin: petrogenesis, comparative chemistry, and tectonic implications

USGS Publications Warehouse

Vallier, T.L.; Jenner, G.A.; Frey, F.A.; Gill, J.B.; Davis, A.S.; Volpe, A.M.; Hawkins, J.W.; Morris, J.D.; Cawood, Peter A.; Morton, J.L.; Scholl, D. W.; Rautenschlein, M.; White, W.M.; Williams, Ross W.; Stevenson, A.J.; White, L.D.

1991-01-01

Tholeiitic andesite was dredged from two sites on Valu Fa Ridge (VFR), a back-arc spreading center in Lau Basin. Valu Fa Ridge, at least 200 km long, is located 40-50 km west of the active Tofua Volcanic Arc (TVA) axis and lies about 150 km above the subducted oceanic plate. One or more magma chambers, traced discontinuously for about 100 km along the ridge axis, lie 3-4 km beneath the ridge. The mostly aphyric and glassy lavas had high volatile contents, as shown by the abundance and large sizes of vesicles. An extensive fractionation history is inferred from the high SiO2 contents and FeO* MgO ratios. Chemical data show that the VFR lavas have both volcanic arc and back-arc basin affinities. The volcanic arc characteristics are: (1) relatively high abundances of most alkali and alkaline earth elements; (2) low abundances of high field strength elements Nb and Ta; (3) high U/Th ratios; (4) similar radiogenic isotope ratios in VFR and TVA lavas, in particular the enrichment of 87Sr 86Sr relative to 206Pb 204Pb; (5) high 238U 230Th, 230Th 232Th, and 226Ra 230Th activity ratios; and (6) high ratios of Rb/Cs, Ba/Nb, and Ba/La. Other chemical characteristics suggest that the VFR lavas are related to MORB-type back-arc basin lavas. For example, VFR lavas have (1) lower 87Sr 86Sr ratios and higher 143Nd 144Nd ratios than most lavas from the TVA, except samples from Ata Island, and are similar to many Lau Basin lavas; (2) lower Sr/REE, Rb/Zr, and Ba/Zr ratios than in arc lavas; and (3) higher Ti, Fe, and V, and higher Ti/V ratios than arc lavas generally and TVA lavas specifically. Most characteristics of VFR lavas can be explained by mixing depleted mantle with either small amounts of sediment and fluids from the subducting slab and/or an older fragment of volcanic arc lithosphere. The eruption of subalkaline andesite with some arc affinities along a back-arc spreading ridge is not unique. Collision of the Louisville and Tonga ridges probably activated back-arc extension

Trace element geochemistry of zircons from mineralizing and non-mineralizing igneous rocks related to gold ores at Yanacocha, Peru

NASA Astrophysics Data System (ADS)

Koleszar, A. M.; Dilles, J. H.; Kent, A. J.; Wooden, J. L.

2012-12-01

Zircons record important details about the evolution of magmatic systems, are relatively insensitive to alteration, and have been used to investigate the geochemistry, temperature, and oxidation state of volcanic and plutonic system. We examine zircons that span 6-7 m.y. of calc-alkaline volcanic activity in the Yanacocha district of northern Peru, where dacitic intrusions are associated with high-sulfidation gold deposits. The 14.5-8.4 Ma Yanacocha Volcanics include cogenetic lavas and pyroclastic rocks and are underlain by the andesites and dacites of the Calipuy Group, the oldest Cenozoic rocks in the region. We present data for magmatic zircons from the Cerro Fraile dacitic pyroclastics (15.5-15.1 Ma) of the Calipuy Group, and multiple eruptive units within the younger Yanacocha Volcanics: the Atazaico Andesite (14.5-13.3 Ma), the Quilish Dacite (~14-12 Ma), the Azufre Andesite (12.1-11.6 Ma), the San Jose Ignimbrite (11.5-11.2 Ma), and the Coriwachay Dacite (11.1-8.4 Ma). Epithermal high sulfidation (alunite-bearing) gold deposits are associated with the dacite intrusions of the Coriwachay and Quilish Dacites. Zircons from the non-mineralizing rocks typically have lower Hf concentrations and record Ti-in-zircon temperatures that are ~100°C hotter than zircons from the mineralizing intrusions. Temperatures recorded by zircons from the mineralizing intrusions are remarkably similar to those of the underlying Cerro Fraile dacite pyroclastics, but the zircons discussed here generally record SHRIMP-RG 206Pb/238U ages within error of previously published Ar-Ar eruption ages (eliminating antecrystic or xenocrystic origins). These observations suggest that zircons in the mineralizing intrusions form after greater extents of crystallization (and thus record elevated Hf concentrations and lower temperatures) than do zircons in the non-mineralized deposits. Unlike zircons from mineralized units associated with the porphyry Cu(Mo) deposits in Yerington, Nevada, which

Petrogenesis of Neoarchean metavolcanic rocks in Changyukou, Northwestern Hebei: Implications for the transition stage from a compressional to an extensional regime for the North China Craton

NASA Astrophysics Data System (ADS)

Liou, Peng; Shan, Houxiang; Liu, Fu; Guo, Jinghui

2017-03-01

The 2.5 Ga metavolcanic rocks in Changyukou, Northwestern Hebei, can be classified into three groups based on major and trace elements: high-Mg basalts, tholeiitic basalts, and the calc-alkaline series (basaltic andesites-andesites and dacites-rhyolites). Both high-Mg basalts and tholeiitic basalts have negative anomalies of Nb, Zr, Ti and Heavy Rare Earth Elements (HREE) as well as enrichments of Sr, K, Pb, Ba and Light Rare Earth Elements (LREE) and show typical subduction zone affinities. The petrogenesis of high-Mg basalts can be ascribed to high-degree partial melting of an enriched mantle source in the spinel stability field that was previously enriched in Large Ion Lithophile Elements (LILE) and LREE by slab-derived hydrous fluids/melts/supercritical fluids, as well as the subsequent magma mixing processes of different sources at different source depths, with little or no influence of polybaric fractional crystallization. The flat HREE of tholeiitic basalts indicates they may also originate from the spinel stability field, but from obviously shallower depths than the source of high-Mg basalts. They may form at a later stage of the subduction process when rapid slab rollback leads to extension and seafloor spreading in the upper plate. We obtain the compositions of the Archean lower crust of the North China Craton based on the Archean Wutai-Jining section by compiling the average tonalite-trondhjemite-granodiorite (TTG) components, average mafic granulite components, and average sedimentary rock components. The modeling results show that the generation of high-Al basalts, basaltic andesites and andesites can be attributed to assimilation by high-Mg basalts (primary basalts) of relatively high-Al2O3 thickened lower crust and the subsequent crystallization of prevailing mafic mineral phases, while Al2O3-rich plagioclase crystallization is suppressed under high-pressure and nearly water-saturated conditions. Dacites and rhyolites may be the result of further

Lithologic interpretation of the De Braga No. 2 and Richard Weishaupt No. 1 geothermal wells, Stillwater project, Churchill County, Nevada

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sibbett, B.S.; Blackett, R.E.

1982-02-01

Lithologies penetrated throughout the upper 732 to 838 m (2400 to 2750 ft) within the Stillwater prospect area are terrigenous sediments of Pleistocene to Recent age. A sill of dacite to andesite composition with a thickness variable between 122 to 208 m (400 to 680 ft) is present below the terrigenous sediments. Between the base of the sill and the top of the Bunejug Formation are intercalated volcanic and sedimentary rocks. All formations overlying the Bunejug Formation are probably of Pleistocene age. The basalt and basaltic-andesite flows and ash below the depth of approximately 1128 m (3700 ft) are hereinmore » assigned to the Bunejug Formation (Morrison, 1964) of Pliocene and possibly early Pleistocene age. The Bunejug Formation is a thick sequence of basalt to andesite flows and hyaloclastite exposed in the mountains surrounding the south half of the Carson Desert. The De Braga No. 2 well bottomed in Bunejug volcanics at a depth of 2109 m (6920 ft). The Richard Weishaupt No. 1 well penetrated the entire Bunejug sequence and entered felsic volcanics and tuffaceous sediments, which possibly represent part of the Truckee Formation, at a depth of approximately 2412 m (7915 ft).« less

Miocene and early Pliocene epithermal gold-silver deposits in the northern Great Basin, western United States: Characteristics, distribution, and relationship to Magmatism

USGS Publications Warehouse

John, D.A.

2001-01-01

Numerous important Miocene and early Pliocene epithermal Au-Ag deposits are present in the northern Great Basin. Most deposits are spatially and temporally related to two magmatic assemblages: bimodal basalt-rhyolite and western andesite. These magmatic assemblages are petrogenetic suites that reflect variations in tectonic environment of magma generation. The bimodal assemblage is a K-rich tholeiitic series formed during continental rifting. Rocks in the bimodal assemblage consist mostly of basalt to andesite and rhyolite compositions that generally contain anhydrous and reduced mineral assemblages (e.g., quartz + fayalite rhyolites). Eruptive forms include mafic lava flows, dikes, cinder and/or spatter cones, shield volcanoes, silicic flows, domes, and ash-flow calderas. Fe-Ti oxide barometry indicates oxygen fugacities between the magnetite-wustite and fayalite-magnetite-quartz oxygen buffers for this magmatic assemblage. The western andesite assemblage is a high K calc-alkaline series that formed a continental-margin are related to subduction of oceanic crust beneath the western coast of North America. In the northern Great Basin, most of the western andesite assemblage was erupted in the Walker Lane belt, a zone of transtension and strike-slip faulting. The western andesite assemblage consists of stratovolcanoes, dome fields, and subvolcanic plutons, mostly of andesite and dacite composition. Biotite and hornblende phenocrysts are abundant in these rocks. Oxygen fugacities of the western andesite assemblage magmas were between the nickel-nickel oxide and hematite-magnetite buffers, about two to four orders of magnitude greater than magmas of the bimodal assemblage. Numerous low-sulfidation Au-Ag deposits in the bimodal assemblage include deposits in the Midas (Ken Snyder), Sleeper, DeLamar, Mule Canyon, Buckhorn, National, Hog Ranch, Ivanhoe, and Jarbidge districts; high-sulfidation gold and porphyry copper-gold deposits are absent. Both high- and low

‘Column on column’ structures as indicators of lava/ice interaction, Ruapehu andesite volcano, New Zealand

NASA Astrophysics Data System (ADS)

Spörli, K. B.; Rowland, J. V.

2006-10-01

Lava flows of the Mangawhero Formation (ca. 15-60 ka) on Ruapehu volcano erupted during the last glaciation. In a distal flow lobe at Tukino, on the east side of the mountain, small secondary columns (10-20 cm thick) have formed on the sides of large, rectangular, primary (0.5-3 m thick) cooling columns. Thick (10 m+) zones of such small columns form a lateral and basal outer rind of the lobe. As they do not mark glassy zones of quenching, these secondary columns are interpreted as being formed by a second cooling event at temperatures below the boundary between the low creep and elastic regimes (˜ 600 °C) by rapid influx of copious amounts of water. Temperature drops deduced from extensional strains of the two sets of columns were used to gauge the viability of such a two-stage process. Absence of reliable data on andesite contraction coefficients was overcome by using a sliding scale to assess a large range of values. The estimates indicate that two-stage chilling is feasible. After flowing across relatively ice-poor terrain, the lava flow must have interacted with a valley glacier that provided water for further chilling the already formed primary columns and formation of the outer rind small columns. Given this evidence for lava/ice interaction, it is likely that prominent, thick flows elsewhere in the Mangawhero Formation may have been constrained to their ridge-top locations by ice conditions similar to those described by Lescinsky and Sisson [Lescinsky, D.T., Sisson, T.W., 1998. Ridge-forming, ice-bounded lava flows at Mount Rainier, Washington. Geology, 26, 351-354].

The timing of compositionally-zoned magma reservoirs and mafic 'priming' weeks before the 1912 Novarupta-Katmai rhyolite eruption

USGS Publications Warehouse

Singer, Brad S.; Costa, Fidel; Herrin, Jason S.; Hildreth, Wes; Fierstein, Judith

2016-01-01

The June 6, 1912 eruption of more than 13 km3 of dense rock equivalent (DRE) magma at Novarupta vent, Alaska was the largest of the 20th century. It ejected >7 km3 of rhyolite, ~1.3 km3 of andesite and ~4.6 km3 of dacite. Early ideas about the origin of pyroclastic flows and magmatic differentiation (e.g., compositional zonation of reservoirs) were shaped by this eruption. Despite being well studied, the timing of events that led to the chemically and mineralogically zoned magma reservoir remain poorly known. Here we provide new insights using the textures and chemical compositions of plagioclase and orthopyroxene crystals and by reevaluating previous U-Th isotope data. Compositional zoning of the magma reservoir likely developed a few thousand years before the eruption by several additions of mafic magma below an extant silicic reservoir. Melt compositions calculated from Sr contents in plagioclase fill the compositional gap between 68 and 76% SiO2 in whole pumice clasts, consistent with uninterrupted crystal growth from a continuum of liquids. Thus, our findings support a general model in which large volumes of crystal-poor rhyolite are related to intermediate magmas through gradual separation of melt from crystal-rich mush. The rhyolite is incubated by, but not mixed with, episodic recharge pulses of mafic magma that interact thermochemically with the mush and intermediate magmas. Hot, Mg-, Ca-, and Al-rich mafic magma intruded into, and mixed with, deeper parts of the reservoir (andesite and dacite) multiple times. Modeling the relaxation of the Fe-Mg concentrations in orthopyroxene and Mg in plagioclase rims indicates that the final recharge event occurred just weeks prior to the eruption. Rapid addition of mass, volatiles, and heat from the recharge magma, perhaps aided by partial melting of cumulate mush below the andesite and dacite, pressurized the reservoir and likely propelled a ~10 km lateral dike that allowed the overlying rhyolite to reach the surface.

Origins of large-volume, compositionally zoned volcanic eruptions: New constraints from U-series isotopes and numerical thermal modeling for the 1912 Katmai-Novarupta eruption

USGS Publications Warehouse

Turner, Simon; Sandiford, Mike; Reagan, Mark; Hawkesworth, Chris; Hildreth, Wes

2010-01-01

We present the results of a combined U-series isotope and numerical modeling study of the 1912 Katmai-Novarupta eruption in Alaska. A stratigraphically constrained set of samples have compositions that range from basalt through basaltic andesite, andesite, dacite, and rhyolite. The major and trace element range can be modeled by 80–90% closed-system crystal fractionation over a temperature interval from 1279°C to 719°C at 100 MPa, with an implied volume of parental basalt of ∼65 km3. Numerical models suggest, for wall rock temperatures appropriate to this depth, that 90% of this volume of magma would cool and crystallize over this temperature interval within a few tens of kiloyears. However, the range in 87Sr/86Sr, (230Th/238U), and (226Ra/230Th) requires open-system processes. Assimilation of the host sediments can replicate the range of Sr isotopes. The variation of (226Ra/230Th) ratios in the basalt to andesite compositional range requires that these were generated less than several thousand years before eruption. Residence times for dacites are close to 8000 years, whereas the rhyolites appear to be 50–200 kyr old. Thus, the magmas that erupted within only 60 h had a wide range of crustal residence times. Nevertheless, they were emplaced in the same thermal regime and evolved along similar liquid lines of descent from parental magmas with similar compositions. The system was built progressively with multiple inputs providing both mass and heat, some of which led to thawing of older silicic material that provided much of the rhyolite.

Miocene volcanism in the Oaş-Gutâi Volcanic Zone, Eastern Carpathians, Romania: Relationship to geodynamic processes in the Transcarpathian Basin

NASA Astrophysics Data System (ADS)

Kovacs, Marinel; Seghedi, Ioan; Yamamoto, Masatsugu; Fülöp, Alexandrina; Pécskay, Zoltán; Jurje, Maria

2017-12-01

We present the first comprehensive study of Miocene volcanic rocks of the Oaş-Gutâi Volcanic Zone (OGVZ), Romania, which are exposed in the eastern Transcarpathian Basin (TB), within the Eastern Alpine-Western Carpathian-Northern Pannonian (ALCAPA) block. Collision between the ALCAPA block and Europe at 18-16 Ma produced the Carpathian fold-and-thrust belt. This was followed by clockwise rotation and an extensional regime forming core complexes of the separated TB fragment. Based on petrographic and geochemical data, including Srsbnd Nd isotopic compositions and Ksbnd Ar ages, we distinguish three types of volcanic activity in the OGVZ: (1) early Miocene felsic volcanism that produced caldera-related ignimbrites in the Gutâi Mountains (15.4-14.8 Ma); (2) widespread middle-late Miocene intermediate/andesitic volcanism (13.4-7.0 Ma); and (3) minor late Miocene andesitic/rhyolitic volcanism comprising the Oraşu Nou rhyolitic volcano and several andesitic-dacitic domes in the Oaş Mountains (11.3-9.5 Ma). We show that magma evolution in the OGVZ was controlled by assimilation-fractional crystallization and magma-mixing processes within an interconnected multi-level crustal magmatic reservoir. The evolution of volcanic activity within the OGVZ was controlled by the geodynamics of the Transcarpathian Basin. The early felsic and late intermediate Miocene magmas were emplaced in a post-collisional setting and were derived from a mantle source region that was modified by subduction components (dominantly sediment melts) and lower crust. The style of volcanism within the eastern TB system exhibits spatial variations, with andesitic composite volcanoes (Gutâi Mountains) observed at the margins, and isolated andesitic-rhyolitic monogenetic volcanoes (Oaş Mountains) in the center of the basin.

Les amas sulfurés du massif miocène d'El Aouana (Algérie)— I. Dynamisme de mise en place des roches volcaniques et implications métallogéniques

NASA Astrophysics Data System (ADS)

Villemaire, Cl.

Two main units have been distinguished in the Miocene El Aouana area. A tectonic event occurs between their respective deposits inducing faulting, tilting of the lower volcanic unit and caldeira structure. The lower unit comprises first continental air fall pyroclastic rocks and dacitic flows, then marine flow pyroclastic rocks, dacitic flows and epiclastic rocks. The upper volcanic unit, announced by extensive andesitic flows, is characterized by pyroclastic flow sheets. The two units are intruded by dacitic domes. These volcanic rocks belong to the calco-alcaline succession, with well-expressed acidic terms. The ore deposits are formed by lenses, stockworks and lodes. They are massive sulphides ore type. Mineralizations are strictly localized at the contact boundary between dacitic intrusive rocks and marine pyroclastic flows and epiclastic rocks. We suggest that the systematic research of dacitic domes would be successful to increase the mining reserves of this area.

Oxidized sulfur-rich mafic magma at Mount Pinatubo, Philippines

USGS Publications Warehouse

de Hoog, J.C.M.; Hattori, K.H.; Hoblitt, R.P.

2004-01-01

Basaltic fragments enclosed in andesitic dome lavas and pyroclastic flows erupted during the early stages of the 1991 eruption of Mount Pinatubo, Philippines, contain amphiboles that crystallized during the injection of mafic magma into a dacitic magma body. The amphiboles contain abundant melt inclusions, which recorded the mixing of andesitic melt in the mafic magma and rhyolitic melt in the dacitic magma. The least evolved melt inclusions have high sulfur contents (up to 1,700 ppm) mostly as SO42, which suggests an oxidized state of the magma (NNO + 1.4). The intrinsically oxidized nature of the mafic magma is confirmed by spinel-olivine oxygen barometry. The value is comparable to that of the dacitic magma (NNO + 1.6). Hence, models invoking mixing as a means of releasing sulfur from the melt are not applicable to Pinatubo. Instead, the oxidized state of the dacitic magma likely reflects that of parental mafic magma and the source region in the sub-arc mantle. Our results fit a model in which long-lived SO2 discharge from underplated mafic magma accumulated in the overlying dacitic magma and immiscible aqueous fluids. The fluids were the most likely source of sulfur that was released into the atmosphere during the cataclysmic eruption. The concurrence of highly oxidized basaltic magma and disproportionate sulfur output during the 1991 Mt. Pinatubo eruption suggests that oxidized mafic melt is an efficient medium for transferring sulfur from the mantle to shallow crustal levels and the atmosphere. As it can carry large amounts of sulfur, effectively scavenge sulfides from the source mantle and discharge SO2 during ascent, oxidized mafic magma forms arc volcanoes with high sulfur fluxes, and potentially contributes to the formation of metallic sulfide deposits. ?? Springer-Verlag 2003.

Using mineral geochemistry to decipher slab, mantle, and crustal inputs to the generation of high-Mg andesites from Mount Baker and Glacier Peak, northern Cascade arc

NASA Astrophysics Data System (ADS)

Sas, M.; DeBari, S. M.; Clynne, M. A.; Rusk, B. G.

2015-12-01

A fundamental question in geology is whether subducting plates get hot enough to generate melt that contributes to magmatic output in volcanic arcs. Because the subducting plate beneath the Cascade arc is relatively young and hot, slab melt generation is considered possible. To better understand the role of slab melt in north Cascades magmas, this study focused on petrogenesis of high-Mg andesites (HMA) and basaltic andesites (HMBA) from Mt. Baker and Glacier Peak, Washington. HMA have unusually high Mg# relative to their SiO2 contents, as well as elevated La/Yb and Dy/Yb ratios that are interpreted to result from separation of melt from a garnet-bearing residuum. Debate centers on the garnet's origin as it could be present in mineral assemblages from the subducting slab, deep mantle, thick lower crust, or basalt fractionated at high pressure. Whole rock analyses were combined with major, minor, and trace element analyses to understand the origin of these HMA. In the Tarn Plateau (Mt. Baker) flow unit (51.8-54.0 wt.% SiO2, Mg# 68-70) Mg#s correlate positively with high La/Yb in clinopyroxene equilibrium liquids, suggesting an origin similar to that of Aleutian adakites, where slab-derived melts interact with the overlying mantle to become Mg-rich and subsequently mix with mantle-derived basalts. The source for high La/Yb in the Glacier Creek (Mt. Baker) flow unit (58.3-58.7 wt.% SiO2, Mg# 63-64) is more ambiguous. High whole rock Sr/P imply origin from a mantle that was hydrated by an enriched slab component (fluid ± melt). In the Lightning Creek (Glacier Peak) flow unit (54.8-57.9 SiO2, Mg# 69-72) Cr and Mg contents in Cr-spinel and olivine pairs suggest a depleted mantle source, and high whole rock Sr/P indicate hydration-induced mantle melting. Hence Lightning Creek is interpreted have originated from a refractory mantle source that interacted with a hydrous slab component (fluid ± melt). Our results indicate that in addition to slab-derived fluids, slab

Volcanostratigraphy, petrography and petrochemistry of Late Cretaceous volcanic rocks from the Görele area (Giresun, NE Turkey)

NASA Astrophysics Data System (ADS)

Oguz, Simge; Aydin, Faruk; Baser, Rasim

2015-04-01

In this study, we have reported for lithological, petrographical and geochemical features of late Cretaceous volcanic rocks from the Çanakçı and the Karabörk areas in the south-eastern part of Görele (Giresun, NE Turkey) in order to investigate their origin and magmatic evolution. Based on the previous ages and recent volcano-stratigraphic studies, the late Cretaceous time in the study area is characterized by an intensive volcanic activity that occurred in two different periods. The first period of the late Cretaceous volcanism (Cenomanian-Santonian; 100-85 My), conformably overlain by Upper Jurassic-Lower Cretaceous massive carbonates (Berdiga Formation), is represented by bimodal units consisting of mainly mafic rock series (basaltic-andesitic lavas and hyaloclastites, dikes and sills) in the lower part (Çatak Formation), and felsic rock series (dacitic lavas and hyaloclastites, crystal- and pyrite-bearing tuffs) in the upper part (Kızılkaya Formation). The second period of the late Cretaceous volcanism (Santonian-Late Campanian; 85-75 Ma) is also represented by bimodal character and again begins with mafic rock suites (basaltic-basaltic andesitic lavas and hyaloclastites) in the lower part (Çağlayan Formation), and grades upward into felsic rock suites (biotite-bearing rhyolitic lavas, ignimbrites and hyaloclastites) through the upper part (Tirebolu Formation). These bimodal units are intercalated with volcanic conglomerates-sandstones, claystones, marl and red pelagic limestones throughout the volcanic sequence, and the felsic rock series have a special important due to hosting of volcanogenic massive sulfide deposits in the region. All volcano-sedimentary units are covered by Tonya Formation (Late Campanian-Paleocene) containing calciturbidites, biomicrites and clayey limestones. The mafic rocks in the two volcanic periods generally include basalt, basaltic andesite and minor andesite, whereas felsic volcanics of the first period mainly consists of

Controls on rind thickness on basaltic andesite clasts weathering in Guadeloupe

USGS Publications Warehouse

Sak, P.B.; Navarre-Sitchler, A. K.; Miller, C.E.; Daniel, C.C.; Gaillardet, J.; Buss, H.L.; Lebedeva, M.I.; Brantley, S.L.

2010-01-01

A clast of low porosity basaltic andesite collected from the B horizon of a soil developed on a late Quaternary volcaniclastic debris flow in the Bras David watershed on Basse-Terre Island, Guadeloupe, exhibits weathering like that observed in many weathered clasts of similar composition in other tropical locations. Specifically, elemental profiles measured across the core-rind interface document that primary minerals and glass weather to Fe oxyhydroxides, gibbsite and minor kaolinite in the rind. The earliest reaction identified in the core is oxidation of Fe in pyroxene but the earliest reaction that creates significant porosity is plagioclase dissolution. Elemental loss varies in the order Ca???Na>K???Mg>Si>Al>Fe???P??Ti, consistent with the relative reactivity of phases in the clast from plagioclase???pyroxene???glass>apatite>ilmenite. The rind surrounds a core of unaltered material that is more spherical than the original clast. The distance from the core-rind boundary to a visually prominent rind layer, L, was measured as a proxy for the rind thickness at 36 locations on a slab cut vertically through the nominal center of the clast. This distance averaged 24.4??3.1mm. Maximum and minimum values for L, 35.8 and 20.6mm, were observed where curvature of the core-rind boundary is greatest (0.12mm-1) and smallest (0.018mm-1) respectively. Extrapolating from other rinds in other locations, the rate of rind formation is estimated to vary by a factor of about 2 (from ~4 to 7??10-14ms-1) from low to high curvature. The observation of a higher rate of rind formation for a higher curvature interface is consistent with a diffusion-limited model for weathering rind formation. The diffusion-limited model predicts that, like rind thickness, values of the thickness of the reaction front (h) for a given reaction, defined as the zone over which a parent mineral such as plagioclase completely weathers to rind material, should also increase with curvature. Values of h were

Dynamic observations of vesiculation reveal the role of silicate crystals in bubble nucleation and growth in andesitic magmas

NASA Astrophysics Data System (ADS)

Pleše, P.; Higgins, M. D.; Mancini, L.; Lanzafame, G.; Brun, F.; Fife, J. L.; Casselman, J.; Baker, D. R.

2018-01-01

Bubble nucleation and growth control the explosivity of volcanic eruptions, and the kinetics of these processes are generally determined from examinations of natural samples and quenched experimental run products. These samples, however, only provide a view of the final state, from which the initial conditions of a time-evolving magmatic system are then inferred. The interpretations that follow are inexact due to the inability of determining the exact conditions of nucleation and the potential detachment of bubbles from their nucleation sites, an uncertainty that can obscure their nucleation location - either homogeneously within the melt or heterogeneously at the interface between crystals and melts. We present results of a series of dynamic, real-time 4D X-ray tomographic microscopy experiments where we observed the development of bubbles in crystal bearing silicate magmas. Experimentally synthesized andesitic glasses with 0.25-0.5 wt% H2O and seed silicate crystals were heated at 1 atm to induce bubble nucleation and track bubble growth and movement. In contrast to previous studies on natural and experimentally produced samples, we found that bubbles readily nucleated on plagioclase and clinopyroxene crystals, that their contact angle changes during growth and that they can grow to sizes many times that of the silicate on whose surface they originated. The rapid heterogeneous nucleation of bubbles at low degrees of supersaturation in the presence of silicate crystals demonstrates that silicates can affect when vesiculation ensues, influencing subsequent permeability development and effusive vs. explosive transition in volcanic eruptions.

Multivariate analysis, mass balance techniques, and statistical tests as tools in igneous petrology: application to the Sierra de las Cruces volcanic range (Mexican Volcanic Belt).

PubMed

Velasco-Tapia, Fernando

2014-01-01

Magmatic processes have usually been identified and evaluated using qualitative or semiquantitative geochemical or isotopic tools based on a restricted number of variables. However, a more complete and quantitative view could be reached applying multivariate analysis, mass balance techniques, and statistical tests. As an example, in this work a statistical and quantitative scheme is applied to analyze the geochemical features for the Sierra de las Cruces (SC) volcanic range (Mexican Volcanic Belt). In this locality, the volcanic activity (3.7 to 0.5 Ma) was dominantly dacitic, but the presence of spheroidal andesitic enclaves and/or diverse disequilibrium features in majority of lavas confirms the operation of magma mixing/mingling. New discriminant-function-based multidimensional diagrams were used to discriminate tectonic setting. Statistical tests of discordancy and significance were applied to evaluate the influence of the subducting Cocos plate, which seems to be rather negligible for the SC magmas in relation to several major and trace elements. A cluster analysis following Ward's linkage rule was carried out to classify the SC volcanic rocks geochemical groups. Finally, two mass-balance schemes were applied for the quantitative evaluation of the proportion of the end-member components (dacitic and andesitic magmas) in the comingled lavas (binary mixtures).

Multivariate Analysis, Mass Balance Techniques, and Statistical Tests as Tools in Igneous Petrology: Application to the Sierra de las Cruces Volcanic Range (Mexican Volcanic Belt)

PubMed Central

Velasco-Tapia, Fernando

2014-01-01

Magmatic processes have usually been identified and evaluated using qualitative or semiquantitative geochemical or isotopic tools based on a restricted number of variables. However, a more complete and quantitative view could be reached applying multivariate analysis, mass balance techniques, and statistical tests. As an example, in this work a statistical and quantitative scheme is applied to analyze the geochemical features for the Sierra de las Cruces (SC) volcanic range (Mexican Volcanic Belt). In this locality, the volcanic activity (3.7 to 0.5 Ma) was dominantly dacitic, but the presence of spheroidal andesitic enclaves and/or diverse disequilibrium features in majority of lavas confirms the operation of magma mixing/mingling. New discriminant-function-based multidimensional diagrams were used to discriminate tectonic setting. Statistical tests of discordancy and significance were applied to evaluate the influence of the subducting Cocos plate, which seems to be rather negligible for the SC magmas in relation to several major and trace elements. A cluster analysis following Ward's linkage rule was carried out to classify the SC volcanic rocks geochemical groups. Finally, two mass-balance schemes were applied for the quantitative evaluation of the proportion of the end-member components (dacitic and andesitic magmas) in the comingled lavas (binary mixtures). PMID:24737994

Metamorphism and plutonism around the middle and south forks of the Feather River, California

USGS Publications Warehouse

Hietanen, Anna Martta

1976-01-01

The area around the Middle and South Forks of the Feather River provides information on metamorphic and igneous processes that bear on the origin of andesitic and granitic magmas in general and on the variation of their potassium content in particular. In the north, the area joins the Pulga and Bucks Lake quadrangles studied previously. Tectonically, this area is situated in the southern part of an arcuate segment of the Nevadan orogenic belt in the northwestern Sierra Nevada. The oldest rocks are metamorphosed calcalkaline island-arc-type andesite, dacite, and sodarhyolite with interbedded tuff layers (the Franklin Canyon Formation), all probably correlative with Devonian rocks in the Klamath Mountains. Younger rocks form a sequence of volcanic, volcaniclastic, and sedimentary rocks including some limestone (The Horseshoe Bend Formation), probably Permian in age. All the volcanic and sedimentary rocks were folded and recrystallized to the greenschist facies during the Nevadan (Jurassic) orogeny and were invaded by monzotonalitic magmas shortly thereafter. A second lineation and metamorphism to the epidote-amphibolite facies developed in a narrow zone around the plutons. In light of the concept of plate tectonics, it is suggested that the early (Devonian?) island-arc-type andesite, dacite, and sodarhyolite (the Franklin Canyon Formation) were derived from the mantle above a Benioff zone by partial melting of peridotite in hydrous conditions. The water was probably derived from an oceanic plate descending to the mantle. Later (Permian?) magmas were mainly basaltic; some discontinuous layers of potassium-rich rhyolite indicate a change into anhydrous conditions and a deeper level of magma generation. The plutonic magmas that invaded the metamorphic rocks at the end of the Jurassic may contain material from the mantle, the subducted oceanic lithosphere, and the downfolded metamorphic rocks. The ratio of partial melts from these three sources may have changed with time

238U sbnd 230Th sbnd 226Ra disequilibria in young Mount St. Helens rocks: time constraint for magma formation and crystallization

NASA Astrophysics Data System (ADS)

Volpe, Alan M.; Hammond, Paul E.

1991-12-01

We use 238U-series nuclides and 230Th/ 232Th ratios measured by mass spectrometry to constrain processes and time scales of calc-alkaline magma genesis at Mount St. Helens, Washington. Olivine basalt, pyroxene andesites and dacites that erupted 10-2 ka ago show 3-14% ( 230Th) sbnd ( 238U) and 6-54% 226Ra sbnd 230Th disequilibria. Mineral phases exhibit robust ( 226Ra) sbnd ( 230Th) fractionation. Plagioclase has large 65-280% ( 226Ra) excesses, and magnetite has large 65% ( 226Ra) deficits relative to ( 230Th). Calculated partition coefficients for Ba, Th, and U in mineral-groundmass pairs, except Ba in plagioclase, are low (⩽ 0.04). Correlation between ( 226Ra/ 230Th ) activity ratios and rm/BaTh element ratios in the minerals suggests that 226Ra partitions similar to Ba during crystallization. Internal ( 230Th) sbnd ( 238U) isochrons for 1982 summit and East Dome dacites and Goat Rocks and Kalama andesites show that closed Th sbnd U system fractionation occurred 2-6 ka ago. Apparent internal isochrons for Castle Creek basalt (34 ka) and andesite (27 ka) suggest longer magma chamber residence times and mixing of old crystals and young melt. Mineral ( 226Ra) sbnd ( 230Th) disequilibrium on Ba-normalized internal isochron diagrams suggests average magma chamber residence times of 500-3000 years. In addition, radioactive ( 226Ra/ 230Th ) heterogeneity between minerals and groundmass or whole rock is evidence for open-system Ra sbnd Th behavior. This heterogeneity suggests there has been recent, post-crystallization, changes in melt chemical composition that affected 226Ra more than 230Th. Clearly, magma fractionation, residence and transport of crystal-melt before eruption of chemically diverse lavas at Mount St. Helens occurs over geologically short periods.

Small-scale disequilibrium in a magmatic inclusion and its more silicic host

NASA Technical Reports Server (NTRS)

Davidson, Jon P.; Holden, Peter; Halliday, Alex N.; De Silva, Shanaka L.

1990-01-01

An investigation of small-scale isotopic, compositional, and mineralogical variation across the interface of a basaltic-andesite inclusion and its dacitic host from Cerro-Chascon, a Holocene dome in northern Chile, is discussed. Serial sectioning across the interface of the inclusion and its host dacite, complemented by microdrill sampling and detailed microprobe work, has enabled an examination of the scale of mixing and chemical disequilibrium. The composition of the inclusion is found to be relatively homogeneous; the dacite host is heterogeneous on a small scale; the isotopic composition in the marginal zone shows the highest Sr-87/Sr-86 and lowest Nd-143/Nd-144; the large plagioclase crystals in the inclusions and host are xenocrystic. These differences are reconciled with a model of magma evolution in a crustal magma chamber.

The Laramide Mesa formation and the Ojo de Agua caldera, southeast of the Cananea copper mining district, Sonora, Mexico

USGS Publications Warehouse

Cox, Dennis P.; Miller, Robert J.; Woodbourne, Keith L.

2006-01-01

The Mesa Formation extends from Cananea, Mexico, southeast to the Sonora River and is the main host rock of Laramide porphyry copper deposits in the Cananea District and at the Alacran porphyry prospect to the east. The Mesa consists of two members-a lower andesite and an upper dacite. The lowest part of the dacite member is a crystal tuff about 100 m thick. This tuff is the outfall of a caldera centered near the village of Ojo de Agua, dated by 40Ar/39Ar at 65.8 Ma ?0.4. The Ojo de Agua Caldera is about 9 km in diameter and is filled by a light gray biotite dacite tuff with abundant flattened pumice fragments. The volume of the caldera is estimated to be 24 km3.

Eruptive history and geochronology of Mount Mazama and the Crater Lake region, Oregon

USGS Publications Warehouse

Bacon, Charles R.; Lanphere, Marvin A.

2006-01-01

Geologic mapping, K-Ar, and 40Ar/39Ar age determinations, supplemented by paleomagnetic measurements and geochemical data, are used to quantify the Quaternary volcanic history of the Crater Lake region in order to define processes and conditions that led to voluminous explosive eruptions. The Cascade arc volcano known as Mount Mazama collapsed during its climactic eruption of ∼50 km3 of mainly rhyodacitic magma ∼7700 yr ago to form Crater Lake caldera. The Mazama edifice was constructed on a Pleistocene silicic lava field, amidst monogenetic and shield volcanoes ranging from basalt to andesite similar to parental magmas for Mount Mazama. Between 420 ka and 35 ka, Mazama produced medium-K andesite and dacite in 2:1 proportion. The edifice was built in many episodes; some of the more voluminous occurred approximately coeval with volcanic pulses in the surrounding region, and some were possibly related to deglaciation following marine oxygen isotope stages (MIS) 12, 10, 8, 6, 5.2, and 2. Magmas as evolved as dacite erupted many times, commonly associated with or following voluminous andesite effusion. Establishment of the climactic magma chamber was under way when the first preclimactic rhyodacites vented ca. 27 ka. The silicic melt volume then grew incrementally at an average rate of 2.5 km3 k.y.−1 for nearly 20 k.y. The climactic eruption exhausted the rhyodacitic magma and brought up crystal-rich andesitic magma, mafic cumulate mush, and wall-rock granodiorite. Postcaldera volcanism produced 4 km3 of andesite during the first 200–500 yr after collapse, followed at ca. 4800 yr B.P. by 0.07 km3 of rhyodacite. The average eruption rate for all Mazama products was ∼0.4 km3 k.y.−1, but major edifice construction episodes had rates of ∼0.8 km3 k.y.−1. The long-term eruption rate for regional monogenetic and shield volcanoes was d∼0.07 km3 k.y.−1, but only ∼0.02 km3 k.y.−1 when the two major shields are excluded. Plutonic xenoliths and evidence for

Post-collisional magmatism in the Late Miocene Rodna-Bârgău district (East Carpathians, Romania): Geochemical constraints and petrogenetic models

NASA Astrophysics Data System (ADS)

Fedele, Lorenzo; Seghedi, Ioan; Chung, Sun-Lin; Laiena, Fabio; Lin, Te-Hsien; Morra, Vincenzo; Lustrino, Michele

2016-12-01

Post-collisional magmatism in the Late Miocene Rodna-Bârgău subvolcanic district (East Carpathians) gave rise to a wide variety of rock compositions, allowing recognition of four groups of calcalkaline rocks with distinctive petrography, mineral chemistry, whole-rock geochemistry and Sr-Nd-Hf isotope features. New U-Pb zircon datings, together with literature data, indicate that the emplacement of the four rock groups was basically contemporaneous in the 11.5-8 Ma time span. The low potassium group (LKG) includes the most abundant lithotypes of the area, ranging from basaltic andesite to dacite, characterized by K-poor tschermakitic amphibole, weak enrichment in LILE and LREE, relatively low 87Sr/86Sr, coupled with relatively high 143Nd/144Nd and 176Hf/177Hf. The high potassium group (HKG) includes amphibole-bearing microgabbro, amphibole andesite and amphibole- and biotite dacite, with K-richer magnesio-hastingsite to hastingsite amphibole, more marked enrichments in incompatible elements, higher 87Sr/86Sr and lower 143Nd/144Nd and 176Hf/177Hf. These two main rock groups seem to have originated from similar juxtaposed mantle sources, with the HKG possibly related to slightly more enriched domains (with higher H2O reflected by the higher modal amphibole) with respect to LKG (with higher plagioclase/amphibole ratios). The evolution of the two rock series involved also open-system processes, taking place mainly in the upper crust for the HKG, in the lower crust for LKG magmas. In addition, limited occurrences of generally younger strongly evolved peraluminous rhyolites and microgranites (Acid group) and sialic-dominated "leucocratic" andesites and dacites (LAD group) were also recognized to the opposite outermost areas of the district. These two latter rock groups were generated by the melting of a basic metamorphic crustal source (respectively in hydrous and anhydrous conditions), favored by the heat released by mantle melts from the adjoining central area. The

Petrology, geochemistry and U-Pb geochronology of magmatic rocks from the high-sulfidation epithermal Au-Cu Chelopech deposit, Srednogorie zone, Bulgaria

NASA Astrophysics Data System (ADS)

Chambefort, Isabelle; Moritz, Robert; von Quadt, Albrecht

2007-10-01

The Chelopech deposit is one of the largest European gold deposits and is located 60 km east of Sofia, within the northern part of the Panagyurishte mineral district. It lies within the Banat-Srednegorie metallogenic belt, which extends from Romania through Serbia to Bulgaria. The magmatic rocks define a typical calc-alkaline suite. The magmatic rocks surrounding the Chelopech deposit have been affected by propylitic, quartz-sericite, and advanced argillic alteration, but the igneous textures have been preserved. Alteration processes have resulted in leaching of Na2O, CaO, P2O5, and Sr and enrichment in K2O and Rb. Trace element variation diagrams are typical of subduction-related volcanism, with negative anomalies in high field strength elements (HFSE) and light element, lithophile elements. HFSE and rare earth elements were relatively immobile during the hydrothermal alteration related to ore formation. Based on immobile element classification diagrams, the magmatic rocks are andesitic to dacitic in compositions. Single zircon grains, from three different magmatic rocks spanning the time of the Chelopech magmatism, were dated by high-precision U-Pb geochronology. Zircons of an altered andesitic body, which has been thrust over the deposit, yield a concordant 206Pb/238U age of 92.21 ± 0.21 Ma. This age is interpreted as the crystallization age and the maximum age for magmatism at Chelopech. Zircon analyses of a dacitic dome-like body, which crops out to the north of the Chelopech deposit, give a mean 206Pb/238U age of 91.95 ± 0.28 Ma. Zircons of the andesitic hypabyssal body hosting the high-sulfidation mineralization and overprinted by hydrothermal alteration give a concordant 206Pb/238U age of 91.45 ± 0.15 Ma. This age is interpreted as the intrusion age of the andesite and as the maximum age of the Chelopech epithermal high-sulfidation deposit. 176Hf/177Hf isotope ratios of zircons from the Chelopech magmatic rocks, together with published data on the

Geochemical and Isotopic Evidences of the Magmatic Sources in the Eastern Sector of the Trans-Mexican Volcanic Belt: Xihuingo-Chichicuautla Volcanic Field

NASA Astrophysics Data System (ADS)

Valadez, S.; Martinez-serrano, R.; Juarez-Lopez, K.; Solis-Pichardo, G.; Perez-Arvizu, O.

2011-12-01

The study of magmatism in the Trans-Mexican Volcanic Belt (TMVB) has great importance due to several features such as its obliquity with respect to the Middle American Trench and its petrological and geochemical variability, which are not common in most typical volcanic arcs. Although several papers have contributed significantly to the understanding of most important magmatic processes in this province, there are still several questions such as the characterization of magmatic sources. In the present work, we provide new stratigraphic, petrographic, geochemical and Sr, Nd and Pb isotopic data as well as some K-Ar age determinations from the Xihuingo-Chichicuautla volcanic field (XCVF), located at the eastern part of the TMVB, with the aim to identify the magmatic sources that produced the main volcanic rocks. The volcanic structures in the XCVF are divided in two main groups according to the petrographic and geochemical compositions: 1) dacitic domes, andesitic lava flows and some dacitic-rhyolitic ignimbrites and 2) scoria cones, shield volcanoes and associated lava flows of basalt to basaltic-andesite composition. Distribution of most volcanic structures is probably controlled by NE-SW fault and fractures system. This fault system was studied by other authors who established that volcanic activity started ca. 13.5 Ma ago, followed by a volcanic hiatus of ca. 10 Ma, and the late volcanic activity began ca. 3 to 1 Ma. In this work we dated 2 rock samples by K-Ar method, which yielded ages of 402 and 871 Ka, which correspond to the most recent volcanic activity in this study area. The volcanic rocks of the XCVF display compositions from basalts to rhyolites but in general all rocks show trace element patterns typical of magmatic arcs. However, we can identify two main magmatic sources: a depleted magmatic source represented by dacitic-andesitic rocks which present a LILE enrichment with respect to HFSE indicating that a magmatic source was modified by fluids

Post-Hercynian subvolcanic magmatism in the Serre Massif (Central-Southern Calabria, Italy)

NASA Astrophysics Data System (ADS)

Romano, V.; Cirrincione, R.; Fiannacca, P.; Mazzoleni, P.; Tranchina, A.

2009-04-01

In the Serre Massif (Central-Southern Calabria, Italy) dykes and subvolcanic bodies intrude diffusively both Hercynian metamorphic rocks and late-Hercynian granitoids. They range in composition from basaltic andesites to dacite-rhyodacites and can be ascribed to the extensive magmatic activity that affects the entire Hercynian orogenic belt in late Paleozoic - early Mesozoic time. The geodinamic framework of the magmatic activity is still matter of debate, nevertheless most authors agree in correlating magmatism both to the late-orogenic collapse of the Hercynian belt and to the lithosphere thinning responsible for the subsequent continental rifting. In this work, we propose a petrogenetic model for acidic to basic hypabissal bodies from southern Calabria in order to define the nature of sources, discriminate magmatic processes and supply a contribution in the geodynamic reconstruction of the Late Palaeozoic in the Calabria-Peloritani Orogen. In relation to their geochemical affinity, studied dykes have been divided in two groups: a medium- to high-K calc-alkaline and a tholeiitic one. Dykes belonging to the former group, andesitic and dacitic-rhyodacitic in composition, show typical features of subduction-related magmatism, such as LILE and LREE enrichments, depletions in HFSE, peaks in Rb, Th and Ce, accentuated troughs in Ba, Nb-Ta, P and Ti (White and Dupré, 1986; McCulloch and Gamble, 1991), contrasting with the late Hercynian collisional context. On the other side, features typical of intra-plate magmatic activity, such as a moderate enrichment in Ta, Nb, Ce, P, Zr, Hf and Sm relative to MORB composition are also present in studied rocks (Shimizu & Arculus, 1975; Pearce, 1982). REE-patterns are strongly to weakly fractionated for the andesitic rocks (Lan/Ybn = 10.03-13.98) and the dacitic-rhyodacitic ones (Lan/Ybn = 6.00 to 2.82), respectively. The latter rocks exhibit a very slight negative Eu anomaly, whereas no Eu anomaly is recognizable in the andesite

The Multiphase Rheology of Andesitic Magmas from the 1.9ka Eruption of Turrialba Volcano (Costa Rica)

NASA Astrophysics Data System (ADS)

Vona, A.; Di Piazza, A.; Romano, C.; De Astis, G.; Soto, G. J.

2014-12-01

We present a study of high-temperature, uniaxial deformation experiments of natural magma from an andesitic eruption of Turrialba volcano (1.9ka Plinian eruption). The aim of this work is to investigate the multiphase rheology (liquid+vesicles+crystals) of natural samples and the effect of vesicles and crystals on the magma viscosity. The experiments were performed using a high-temperature uniaxial Geocomp LoadTrac II press at dry atmospheric conditions and controlled deformation rates. Cores of natural sample (with Φcrys=0.20-0.30 and Φves=0.41-0.58) were deformed isothermally (790-870°C) at variable strain rates (VSR, from 10-6 to 10-4 s-1) and constant strain rate (CSR, 10-5 s-1). VSR were performed at low total amount of strain (e<0.10) to parameterize the flow behavior of these complex natural materials. The stress-strain rate relationships under flow conditions showed a linear trend between the applied stress and strain rate in the temperature interval investigated. All the samples display a steep linear trend, typical of Newtonian fluids (n index ~ 1), with a very small shear thinning behavior. CSR tests were performed at different total amount of strain (e=0.15-0.25-0.35). Strain hardening was observed with increasing deformation, resulting in an increase of apparent viscosity (up to 100.5 Pa s). This increase is related to the loss of total porosity (up to ΔΦves=0.15) due to compaction of the sample as indicated by post-run analyses . The measured multiphase rheology of Turrialba magmas was compared with literature models for both crystal- and bubble-bearing suspension. We calculate a difference of ~101 Pa s in magma apparent viscosity between high and low density samples, that coupled with a lateral temperature gradient inside the conduit of the volcano, could increase up to ~103 Pa s. The large difference in viscosity could be responsible of significant rheological contrasts, possibly resulting in strain localization and brittle fragmentation of

Preliminary Findings of Petrology and Geochemistry of The Aladaǧ Volcanic System and Surrounding Areas (Kars, Turkey)

NASA Astrophysics Data System (ADS)

Duru, Olgun; Keskin, Mehmet

2017-04-01

Between the towns of Sarıkamış and Kaǧızman, NE Turkey, a medium-sized strato-volcano with satellite cones and domes on its slopes unconformably overlies the Erzurum-Kars Volcanic Plateau (EKVP) with a subhorizontal contact. It is called the Aladaǧ volcanic system (AVS). Dating results indicate that the AVS is Pliocene in age. The EKVP is known to be formed by a widespread volcanism between Middle Miocene to Pliocene. The young volcanism in E Turkey including the study area is linked to a collision between the Eurasia and Arabian continents, started almost 15 Ma ago. The EKVP lies over 2000 m above the sea level, and is deeply cut by the river Aras. On the slopes of the valley, one of the best volcano-stratigraphic transects of Eastern Anatolia, almost half a km thick, is exposed. That transect is composed of aphyric andesites-dacites, ignimbrites, tuffs, perlite and obsidian bands. Pyroclastic fall and surge-related pumice deposits are also widespread. Top of the plateau is composed of the andesitic to basaltic andesitic lavas containing plagioclase (Plg) and ortho/clino pyroxene (Opx/Cpx) phenocrysts set in glassy groundmass. In the northwest of the study area, an eroded stratovolcano, probably coeval with the plateau sequence is situated. It also consists of high-silica rhyolites and pyroclastic equivalents. The AVS is composed basically of intermediate lavas. The largest volcanic edifice of the Aladaǧ volcanic system, namely the Greater Aladaǧ stratovolcano reaches up to 3000 m height and includes a horseshoe shaped crater open to the North. Small volcanic cones and domes sit on the flanks of the Greater Aladaǧ volcano. The Aladaǧ lavas are divided into four sub-groups on the basis of their stratigraphic positions, mineral assemblages and textural properties. (1) The oldest products of the Greater Aladaǧ stratovolcano are andesitic and dasitic lavas. They directly sit on the EKVP. These are Plg and Opx/Cpx bearing lavas with porphric, vitrophyric

The onset of the volcanism in the Ciomadul Volcanic Dome Complex (Eastern Carpathians): Eruption chronology and magma type variation

NASA Astrophysics Data System (ADS)

Molnár, Kata; Harangi, Szabolcs; Lukács, Réka; Dunkl, István; Schmitt, Axel K.; Kiss, Balázs; Garamhegyi, Tamás; Seghedi, Ioan

2018-04-01

Combined zircon U-Th-Pb and (U-Th)/He dating was applied to refine the eruption chronology of the last 2 Myr for the andesitic and dacitic Pilişca volcano and Ciomadul Volcanic Dome Complex (CVDC), the youngest volcanic area of the Carpathian-Pannonian region, located in the southernmost Harghita, eastern-central Europe. The proposed eruption ages, which are supported also by the youngest zircon crystallization ages, are much younger than the previously determined K/Ar ages. By dating every known eruption center in the CVDC, repose times between eruptive events were also accurately determined. Eruption of the andesite at Murgul Mare (1865 ± 87 ka) and dacite of the Pilişca volcanic complex (1640 ± 37 ka) terminated an earlier pulse of volcanic activity within the southernmost Harghita region, west of the Olt valley. This was followed by the onset of the volcanism in the CVDC, which occurred after several 100s kyr of eruptive quiescence. At ca. 1 Ma a significant change in the composition of erupted magma occurred from medium-K calc-alkaline compositions to high-K dacitic (Baba-Laposa dome at 942 ± 65 ka) and shoshonitic magmas (Malnaş and Bixad domes; 964 ± 46 ka and 907 ± 66 ka, respectively). Noteworthy, eruptions of magmas with distinct chemical compositions occurred within a restricted area, a few km from one another. These oldest lava domes of the CVDC form a NNE-SSW striking tectonic lineament along the Olt valley. Following a brief (ca. 100 kyr) hiatus, extrusion of high-K andesitic magma continued at Dealul Mare (842 ± 53 ka). After another ca. 200 kyr period of quiescence two high-K dacitic lava domes extruded (Puturosul: 642 ± 44 ka and Balvanyos: 583 ± 30 ka). The Turnul Apor lava extrusion occurred after a ca. 200 kyr repose time (at 344 ± 33 ka), whereas formation of the Haramul Mic lava dome (154 ± 16 ka) represents the onset of the development of the prominent Ciomadul volcano. The accurate determination of eruption dates shows that the

Geochemical Composition of Volcanic Rocks from the May 2003 Eruption of Anatahan Volcano, Mariana Islands

NASA Astrophysics Data System (ADS)

Wade, J. A.; Plank, T.; Stern, R.; Hilton, D.; Fischer, T. P.; Moore, R.; Trusdell, F.; Sako, M.

2003-12-01

The first historical eruption of Anatahan volcano began on May 10, 2003, from the easternmost of the island's two craters. Samples of tephra, scoria, and bombs, collected in May by a MARGINS-supported rapid-response team, were analyzed for 34 trace elements by solution ICP-MS at Boston University and Sr-Nd-Pb isotopic composition at the University of Texas-Dallas. The new eruptive materials can be compared with an extensive suite of pre-existing volcanics (basalts through dacites) from Anatahan sampled by the USGS in 1990 and 1992, and analyzed by XRF and INAA. While most Mariana volcanoes erupt basalts and basaltic andesites, Anatahan is unusual for erupting a wide range of compositions, from basalt to dacite, and thus provides the best opportunity for addressing questions of magma evolution in this classic island arc. The newly erupted scoria and pumice are andesites and dacites that are among the most silicic materials erupted in the northern Mariana islands. The recent eruptives are highly homogeneous; 13 samples vary by only 3-5% relative standard deviation for incompatible trace elements. Isotopic compositions (0.703450 +/- 2 87Sr/86Sr and 18.806 +/- 5 206Pb/204Pb) are within the range of previously measured samples from Anatahan and other volcanic centers in the Marianas. The combined dataset for Anatahan defines virtually a single liquid line of descent. This is consistent with nearly-parallel REE patterns, and small variations in the ratios of the most incompatible trace elements (e.g., Th/Rb varies by <10% over the entire fractionation trend). Low values of Th/La and Th/Zr in Anatahan volcanics provide evidence against partial melting of crustal material as a source of the silicic magmas, as these ratios are highly senstive to apatite- and zircon- saturated crustal melts. Instead, the basalts, andesites and dacites of Anatahan appear to be related predominantly by crystal fractionation with little evidence for assimilation of crustal melts. The new data

Geological and Petrological Characteristics of Oligocene Magmatic Rocks in The Biga Peninsula, NW Turkey

NASA Astrophysics Data System (ADS)

Erenoglu, Oya

2016-04-01

Oligocene magmatic activity in the Biga Peninsula (NW-Anatolia) produced widespread volcano-plutonic complexes. The study region, where in north of the Evciler village in the middle of Biga Peninsula includes these igneous assemblages. In this study, the petrographic and geochemical characteristics of igneous rocks in the region were investigated as well as the geological locations. The magmatic rocks are classified as 6 different units using their lithostratigraphical properties. The volcanism in the region starts with basaltic andesite lava including basalt dykes in the Lower Oligocene. In the Upper Oligocene, the evolved magma by crustal contamination produced commonly dacitic and andesitic lavas. The volcanism continued with andesitic lavas which had significant alterations in the region during this period. Evciler pluton including granite and granodiorite composition with shallow intrusive, was located with the related volcanism at the same time. The volcanic products, i.e. andesitic and trachydacitic lavas, was completed in the interval between Upper Oligocene and Lower Miocene. The post-collisional Oligocene sequence is associated with calc-alkaline composition and it has middle, high-K. Trace and rare earth elements (REE) diagrams show the enrichment in both large-ion lithophile elements (LILE) and light rare earth elements (LREE) with respect to the high field strength elements (HFSE), and a significant increment in heavy rare earth element consumption (HREE). The features of major, trace and rare earth elements of plutonic and volcanic rocks and the compositional variations of Oligocene volcanic group indicate increasing amounts of partial melting, crustal contamination and/or assimilation. The Oligocene post-collisional volcanism in Biga Peninsula points out the lithospheric mantle source enriched by subduction which controlled by slab break-off and lithospheric delamination. Acknowledgement. This study was supported by Canakkale Onsekiz Mart University

Experimental determination of dissolved CO2 content in nominally anhydrous andesitic melts at graphite/diamond saturation - Remobilization of deeply subducted reduced carbon via partial melts of MORB-like eclogite

NASA Astrophysics Data System (ADS)

Eguchi, J.; Dasgupta, R.

2015-12-01

Experimental phase relations of carbonated lithologies [1] and geochemistry of deep diamonds [2] suggest that deep recycling of carbon has likely been efficient for a significant portion of Earth's history. Both carbonates and organic carbon subduct into the mantle, but with gradual decrease of fO2 with depth [3] most carbon in deep mantle rocks including eclogite could be diamond/graphite [4]. Previous studies investigated the transfer of CO2 from subducted eclogite to the ambient mantle by partial melting in the presence of carbonates, i.e., by generation of carbonate-rich melts [5]. However, the transfer of carbon from subducted eclogite to the mantle can also happen, perhaps more commonly, by extraction of silicate partial melt in the presence of reduced carbon; yet, CO2 solubility in eclogite-derived andesitic melt at graphite/diamond saturation remains unconstrained. CO2content of eclogite melts is also critical as geochemistry of many ocean island basalts suggest the presence of C and eclogite in their source regions [6]. In the present study we determine CO2 concentration in a model andesitic melt [7] at graphite/diamond saturation at conditions relevant for partial melting of eclogite in the convecting upper mantle. Piston cylinder and multi anvil experiments were conducted at 1-6 GPa and 1375-1550 °C using Pt/Gr double capsules. Oxygen fugacity was monitored with Pt-Fe sensors in the starting mix. Completed experiments at 1-3 GPa show that CO2 concentration increases with increasing P, T, and fO2 up to ~0.3 wt%. Results were used to develop empirical and thermodynamic models to predict CO2 concentration in partial melts of graphite saturated eclogite. This allowed us to quantify the extent to which CO2 can mobilize from eclogitic heterogeneities at graphite/diamond saturated conditions. With estimates of eclogite contribution to erupted basaltic lavas, the models developed here allow us to put constraints on the flux of CO2 to mantle source regions

Magma genesis in the lesser Antilles island arc

NASA Astrophysics Data System (ADS)

Hawkesworth, C. J.; Powell, M.

1980-12-01

143Nd/ 144Nd, 87Sr/ 86Sr and REE results are reported on volcanic rocks from the islands of Dominica and St. Kitts in the Lesser Antilles. Particular attention is given to the lavas and xenoliths of the Foundland (basalt-andesite) and the Plat Pays (andesite-dacite) volcanic centres on Dominica. Combined major and trace element [ 2] and isotope results suggest that the bulk of the andesites and dacites on Dominica, and by analogy in the rest of the arc, are produced by fractional crystallisation of basaltic magma. The differences in the erupted products of the two volcanoes do not appear to be related to any significant differences in the source rocks of the magmas. Along the arc 87Sr/ 86Sr ratios range from 0.7037 on St. Kitts, to 0.7041-0.7047 on Dominica, and 0.7039-0.7058 on Grenada [ 5], and these are accompanied by a parallel increase in K, Sr, Ba and the light REE's. Moreover, compared with LIL-element-enriched and -depleted rocks from MOR and intraplate environments, the basic rocks from the Lesser Antilles are preferentially enriched in alkaline elements (K, Ba, Rb, Sr) relative to less mobile elements such as the rare earths. 143Nd/ 144Nd varies from 0.51308 on St. Kitts, to 0.51286 on Dominica, and 0.51264-0.51308 on Grenada [ 5], and all these samples have relatively high 87Sr/ 86Sr ratios compared with the main trend of Nd and Sr isotopes for most mantle-derived volcanic rocks. Alkaline elements and 87Sr appear to have been introduced from the subducted ocean crust, but the results on other, less mobile elements are more ambiguous — island arc tholeiites (as on St. Kitts) do not appear to contain significant amounts of REE's, Zr, Y, etc., from the subducted oceanic crust, but such a contribution may be present in more LIL-element-enriched calc-alkaline rock types.

Recurrent eruption and subsidence at the Platoro caldera complex, southeastern San Juan volcanic field, Colorado: New tales from old tuffs

USGS Publications Warehouse

Lipman, P.W.; Dungan, M.A.; Brown, L.L.; Deino, A.

1996-01-01

Reinterpretation of a voluminous regional ash-flow sheet (Masonic Park Tuff) as two separate tuff sheets of similar phenocryst-rich dacite erupted from separate source calderas has important implications for evolution of the multicyclic Platoro caldera complex and for caldera-forming processes generally. Masonic Park Tuff in central parts of the San Juan field, including the type area, was erupted from a concealed source at 28.6 Ma, but widespread tuff previously mapped as Masonic Park Tuff in the southeastern San Juan Mountains is the product of the youngest large-volume eruption of the Platoro caldera complex at 28.4 Ma. This large unit, newly named the "Chiquito Peak Tuff," is the last-erupted tuff of the Treasure Mountain Group, which consists of at least 20 separate ash-flow sheets of dacite to low-silica rhyolite erupted from the Platoro complex during a 1 m.y. interval (29.5-28.4 Ma). Two Treasure Mountain tuff sheets have volumes in excess of 1000 km3 each, and five more have volumes of 50-150 km3. The total volume of ash-flow tuff exceeds 2500 km3, and caldera-related lavas of dominantly andesitic composition make up 250-500 km3 more. A much greater volume of intermediate-composition magma must have solidified in subcaldera magma chambers. Most preserved features of the Platoro complex - including postcollapse asymmetrical trap-door resurgent uplift of the ponded intracaldera tuff and concurrent infilling by andesitic lava flows - postdate eruption of the Chiquito Peak Tuff. The numerous large-volume pre-Chiquito Peak ash-flow tuffs document multiple eruptions accompanied by recurrent subsidence; early-formed caldera walls nearly coincide with margins of the later Chiquito Peak collapse. Repeated syneruptive collapse at the Platoro complex requires cumulative subsidence of at least 10 km. The rapid regeneration of silicic magmas requires the sustained presence of an andesitic subcaldera magma reservoir, or its rapid replenishment, during the 1 m.y. life

Mutnovsky and Gorely Volcanoes, Kamchatka as Planetary Analogue Sites

NASA Astrophysics Data System (ADS)

Evdokimova, N.; Izbekov, P. E.; Krupskaya, V.; Muratov, A.

2016-12-01

Recent advances in Mars studies suggest that volcanic rocks, which dominated Martian surface in the past, have been exposed to alteration processes in a water-bearing environment during Noachian, before 3.7 Gy. Active volcanoes on Earth are natural laboratories, where volcanic processes and their associated products can be studied directly. This is particularly important for studying of alteration of juvenile volcanic products in aqueous environment because of the transient nature of some of the alteration products, as well as the environment itself. Terrestrial analogues help us to better understand processes on Mars; they are particularly useful as a test sites for preparation to future Mars missions. In this presentation we describe planetary analogue sites at Mutnovsky and Gorely Volcanoes in Kamchatka, which might be helpful for comparative studies and preparation to future Mars missions. Mutnovsky and Gorely Volcanoes are located 75 km south of Petropavlovsk-Kamchatsky, in the southern part of the Kamchatka Peninsula, Russia. The modern volcanic landscape in the area was shaped in Holocene (recent 10,000 years) through intermittent eruption of magmas ranging in composition from basalts to dacites and rhyodacites, with basaltic andesite lavas dominating in the modern relief. Two localities could be of a particular interest: (1) Mutnovsky NW thermal field featuring processes of active hydrothermal alteration of lavas of basaltic andesite and (2) dry lake at the bottom of Gorely caldera featuring products of mechanical disintegration of basaltic andesite lavas by eolian processes with short seasonal sedimentation in aqueous environment.

Stratigraphy, distribution, and evidence for mafic triggering of the ca. 8.5 ka Driftwood Pumice eruption, Makushin Volcano, Alaska, U.S.A

NASA Astrophysics Data System (ADS)

Lerner, Allan H.; Crowley, Peter D.; Nicolaysen, Kirsten P.; Hazlett, Richard W.

2018-05-01

Makushin Volcano on Unalaska Island, Alaska, threatens the Aleutian's largest population centers (Unalaska and Dutch Harbor), yet its eruption mechanisms are poorly known. This study presents a detailed stratigraphic and geochemical investigation of Makushin's most recent highly explosive event: the ca. 8.5 ka Driftwood Pumice eruption. The Driftwood Pumice has measured thicknesses of over 2.5 m, and isopach reconstructions estimate a total deposit volume of 0.3 to 1.6 km3, indicating a VEI 4-5 eruption. Proximal deposits consist of normally-graded, tan, dacitic to andesitic pumice, capped by a thinner dark layer of lower-silica andesitic scoria mixed with abundant lithic fragments. This stratigraphy is interpreted as an initial vent-clearing eruption that strengthened into a climactic ejection of pumice and ash and concluded with vent destabilization and the eruption of somewhat more mafic, gas-poor magma. Within the pumice, geochemical trends, disequilibrium mineral populations, and mineral zonation patterns show evidence of magma mixing between a bulk silicic magma and a mafic melt. Euhedral high-Ca plagioclase (An68-91) and high-Mg olivine (Fo69-77) phenocrysts are in disequilibrium with trachydacitic glass (65-68 wt% SiO2) and more abundant sodic plagioclase (An34-55), indicating the former originally crystallized in a more mafic melt. Tephra whole rock compositions become more mafic upwards through the deposit, ranging from a basal low-silica dacite to an andesite (total range: 60.8-63.3 wt% SiO2). Collectively, these compositional variations suggest magma mixing in the Driftwood Pumice (DWP) magma reservoir, with a systematic increase in the amount of a mafic component (up to 25%) upward through the deposit. Olivine-liquid and liquid-only thermometry indicate the mafic magma intruded at temperatures 140-200 °C hotter than the silicic magma. Diffusion rates calculated for 5-7 μm thick, lower-Mg rims on the olivine phenocrysts (Fo60 rim vs Fo76 bulk) suggest

Deposits, petrology and mechanism of the 2010-2013 eruption of Kizimen volcano in Kamchatka, Russia

NASA Astrophysics Data System (ADS)

Auer, A.; Belousov, A.; Belousova, M.

2018-04-01

Kizimen volcano in Kamchatka is well known as a source of highly heterogeneous poorly mingled magmas ranging from dacites to basaltic andesites. In 2010-2013, the volcano produced its first historical magmatic eruption with the deposition of 0.27 km3 of block and ash pyroclastic flows accompanied by slow extrusion of a 200-m-thick, highly viscous (1010-1011 Pa s) block lava flow with a volume of 0.3 km3. The total volume of erupted magma comprised approximately 0.4 km3 DRE. We provide description of the eruption chronology, as well as the lithology and petrology of eruptive products. The erupted material is represented by banded dacite and high-silica andesite. The dacitic magma was formed during a long dormancy after the previous magmatic eruption several hundred years ago with mineral compositions indicating average pre-eruptive temperatures of 810 °C, fO2 of 0.9-1.6 log units above the nickel-nickel oxide (NNO) buffer and shallow crustal storage conditions at 123 MPa. The silica-rich andesite represents a hybrid magma, which shows signs of recent thermal and compositional disequilibrium. We suggest that the hybrid magma started to form in 1963 when a swarm of deep earthquakes indicated an input of mafic magma from depth into the 6-11-km-deep silicic magma chamber. It took the following 46 years until the magma filling the chamber reached an eruptible state. Poor mingling of the two melts is attributed to its unusually high viscosity that could be associated with the pre-eruptive long-term leakage of volatiles from the chamber through a regional tectonic fault. Our investigations have shown that shallow magma chambers of dormant volcanoes demonstrating strong persistent fumarolic activity can contain highly viscous, degassed magma of evolved composition. Reactivation of such magma chambers by injection of basic magma takes a long time (several decades). Thus, eruption forecasts at such volcanoes should include a possibility of long time lag between a swarm of

210Pb and 210Po Abundances in Dacites Erupted May, 2003 From Anatahan Volcano: Implications for the Time-scales of Magma Generation and Degassing

NASA Astrophysics Data System (ADS)

Reagan, M. K.; Matthew, W.; Brian, H.

2003-12-01

Six samples of dacite pumice and scoria erupted in May, 2003 and collected from a number of sites around Anathan by Tobias Fischer and David Hilton were analyzed for 210Po activities on three occasions between early June and the time of this writing. With two exceptions, all scoria and pumice samples have 210Po activities that plot on a single growth curve indicating initial (210Po)=0.15 +/-0.07 (1σ ) dpm/g and (210Pb)=1.08+/-0.20 dpm/g. More precise values for these initial activities will be presented at the meeting after further analyses are performed in November. Preliminary alpha spectrometry analyses for U and Th, and ICPMS analyses distributed by Terry Plank suggest that the average (238U) is about 0.53 dpm/g. Equilibrium (228Th)/( 232Th) ratios indicate that these samples do not have excess 228Ra. Assuming that (210Pb )< (226Ra) because of minor degassing of 210Pb (see Gauthier and Condomines, 1999, EPSL, v. 172), the degassing efficiency factor for 210Po is greater than or equal to about 0.85, which is identical to the value calculated for a basaltic andesitic lava from Arenal volcano in Costa Rica (Gill et al., 1985, GRL, v. 12). This is surprising, as the May 10 plinian eruption of Anatahan should have resulted in more closed-system degassing than a lava eruption. This and the similar 210Po values for the scoria and pumice samples suggest that the shallow-level degassing history has little impact on the efficiency of polonium degassing. The scoria and pumice samples from sample 8-1e both have significant excesses of 210Po over the calculated initial (210Pb) value for the other samples. These excesses were partially leachable, indicating that 210Po was sublimated onto these samples, and that these ejecta resided in the vent before being ejected and redeposited The high inferred (226Ra)/( 230Th) for the Anatahan dacites despite the nearly equilibrium (238U)/( 230Th) value measured for one sample contrasts with the values for these ratios in more mafic

Geologic map and geothermal assessment of the Mount Adams volcanic field, Cascade Range of southern Washington

USGS Publications Warehouse

Hildreth, Wes; Fierstein, Judy

1990-01-01

More than 60 Quaternary vents make up the basalt-to-rhyodacite Mount Adams volcanic field and have erupted scoriae and lavas with a total volume of >370 km3. The Mount Adams andesite-dacite stratocone itself is a compound edifice that includes the high cone above 2300 m (20-10 ka), remnants of at least two earlier andesite-dacite cones as old as 0.5 Ma, and 7 Holocene flank vents. Four other Holocene vents and tens of vents contemporaneous with Mount Adams are peripheral to the stratocone. All of these vents, including Mount Adams, lie within a N-S eruptive zone 55 km long and 5 km wide. The age of all known Mount Adams silicic products (>100 ka) and the heterogeneous mafic compositions of the summit cone and Holocene lavas make it unlikely that the stratocone is underlain by an upper-crustal reservoir. Rather, the stratocone at the focus is built up of fractionated hybrid magmas that rise from MASH zones (melting-assimilation-storage-homogenization). The pyroclastic core of breccia and scoria at Mount Adams has undergone acid-sulfate leaching and deposition of alunite, kaolinite, silica, gypsum, sulfur, and Fe-oxides and has been a constant source of avalanches and debris flows. Most heat supplied from depth to the fumarolically altered core is dispersed by the high precipitation rate and high permeability of the rubbly lava flows so that a hydrothermal convection pattern is not maintained. Summit-restricted fumaroles are weak and diffuse.

Monogenetic Arc Volcanism in the Central Andes: The "Hidden" Mafic Component in the Land of Andesite and Ignimbrite

NASA Astrophysics Data System (ADS)

van Alderwerelt, B. M.; Ukstins Peate, I.; Ramos, F. C.

2016-12-01

Faulting in the upper crust of the Central Andes has provided passage for small volumes of mafic magma to reach the surface, providing a window into petrogenetic processes in the region's deep crust and upper mantle. Mafic lavas are rare in the Central Andean region dominated by intermediate-composition arc volcanism and massive sheets of silicic ignimbrite, and provide key data on magmatic origin, evolution, and transport. This work characterizes fault-controlled, within-arc monogenetic eruptive centers representative of the most mafic volcanism in the Altiplano-Puna region of the Andes since (at least) the Mesozoic. Olivine-phyric basaltic andesite (54 wt% SiO2, 7.3 wt% MgO) at Cerro Overo maar and associated dome, La Albóndiga Grande, and an olivine-clinopyroxene flow (53 wt% SiO2, 6.7 wt% MgO) from Cordón de Puntas Negras have been erupted at the intersection of regional structural features and the modern volcanic arc. Bulk magma chemistry, radiogenic isotopes, and microanalyses of mineral and melt inclusion composition provide insight on the composition(s) of mafic magmas being delivered to the lowermost crust and the deep crustal processes which shape central Andean magma. Bulk major and trace elements follow regional arc differentiation trends and are clearly modified by crustal magmatic processes. In contrast, microanalyses reveal a much richer history with olivine-hosted melt inclusions recording multiple distinct magmas, including potential primary melts. Single crystal olivine 87Sr/86Sr from Cerro Overo (0.7041-0.7071) define a broader range than whole rock (0.7062-0.7065), indicating preservation of juvenile melt in olivine-hosted inclusions lost at the whole rock scale. Mineral chemistry (via EMPA) P-T calculations define a petrogenetic history for these endmember lavas. Field mapping, bulk chemistry, and microanalyses outline the generation, storage, transportation, and eventual eruption of the "hidden" mafic component of the Andean arc.

A basalt trigger for the 1991 eruptions of Pinatubo volcano?

USGS Publications Warehouse

Pallister, J.S.; Hoblitt, R.P.; Reyes, A.G.

1992-01-01

THE eruptive products of calc-alkaline volcanos often show evidence for the mixing of basaltic and acid magmas before eruption (see, for example, refs 1, 2). These observations have led to the suggestion3 that the injection of basaltic magma into the base of a magma chamber (or the catastrophic overturn of a stably stratified chamber containing basaltic magma at its base) might trigger an eruption. Here we report evidence for the mixing of basaltic and dacitic magmas shortly before the paroxysmal eruptions of Pinatubo volcano on 15 June 1991. Andesitic scoriae erupted on 12 June contain minerals and glass with disequilibrium compositions, and are considerably more mafic than the dacitic pumices erupted on 15 June. Differences in crystal abundance and glass composition among the pumices may arise from pre-heating of the dacite magma by the underlying basaltic liquid before mixing. Degassing of this basaltic magma may also have contributed to the climatologically important sulphur dioxide emissions that accompanied the Pinatubo eruptions.

A new tree-ring date for the "floating island" lava flow, Mount St. Helens, Washington

USGS Publications Warehouse

Yamaguchi, D.K.; Hoblitt, R.P.; Lawrence, D.B.

1990-01-01

Anomalously narrow and missing rings in trees 12 m from Mount St. Helens' "floating island" lava flow, and synchronous growth increases in trees farther from the flow margin, are evidence that this andesitic flow was extruded between late summer 1799 and spring 1800 a.d., within a few months after the eruption of Mount St. Helens' dacitic layer T tephra. For ease of reference, we assign here an 1800 a.d. date to this flow. The new date shows that the start of Mount St. Helens' Goat Rocks eruptive period (1800-1857 a.d.) resembled the recent (1980-1986) activity in both petrochemical trends and timing. In both cases, an initial explosive eruption of dacite was quickly succeeded by the eruption of more mafic lavas; dacite lavas then reappeared during an extended concluding phase of activity. This behavior is consistent with a recently proposed fluid-dynamic model of magma withdrawal from a compositionally zoned magma chamber. ?? 1990 Springer-Verlag.

Cenozoic volcanic geology and probable age of inception of basin-range faulting in the southeasternmost Chocolate Mountains, California

DOE Office of Scientific and Technical Information (OSTI.GOV)

Crowe, B.M.

1978-02-01

A complex sequence of Oligocene-age volcanic and volcaniclastic rocks form a major volcanic center in the Picacho area of the southeasternmost Chocolate Mountains, Imperial County, California. Basal-volcanic rocks consist of lava flows and flow breccia of trachybasalt, pyroxene rhyodacite, and pyroxene dacite (32 My old). These volcanic rocks locally overlie fanglomerate and rest unconformably on pre-Cenozoic basement rocks. South and southeast of a prominent arcuate fault zone in the central part of the area, the rhyolite ignimbrite (26 My old) forms a major ash-flow sheet. In the southwestern part of the Picacho area the rhyolite ignimbrite interfingers with and ismore » overlain by dacite flows and laharic breccia. The rhyolite ignimbrite and the dacite of Picacho Peak are overlapped by lava flows and breccia of pyroxene andesite (25 My old) that locally rest on pre-Cenozoic basement rocks. The volcanic rocks of the Picacho area form a slightly bimodal volcanic suite consisting chiefly of silicic volcanic rocks with subordinate andesite. Late Miocene augite-olivine basalt is most similar in major-element abundances to transitional alkali-olivine basalt of the Basin and Range province. Normal separation faults in the Picacho area trend northwest and north parallel to major linear mountain ranges in the region. The areal distribution of the 26-My-old rhyolite ignimbrite and the local presence of megabreccia and fanglomerate flanking probable paleohighs suggest that the ignimbrite was erupted over irregular topography controlled by northwest- and north-trending probable basin-range faults. These relations date the inception of faulting in southeasternmost California at pre-26 and probably pre-32 My ago. A transition of basaltic volcanism in the area is dated at 13 My ago. 9 figures, 2 tables.« less

The isotopic and chemical evolution of Mount St. Helens

USGS Publications Warehouse

Halliday, A.N.; Fallick, A.E.; Dickin, A.P.; Mackenzie, A.B.; Stephens, W.E.; Hildreth, W.

1983-01-01

Isotopic and major and trace element analysis of nine samples of eruptive products spanning the history of the Mt. St. Helens volcano suggest three different episodes; (1) 40,000-2500 years ago: eruptions of dacite with ??{lunate}Nd = +5, ??{lunate}Sr = -10, variable ??18O, 206Pb/204Pb ??? 18.76, Ca/Sr ??? 60, Rb/Ba ??? 0.1, La/Yb ??? 18, (2) 2500-1000 years ago: eruptions of basalt, andesite and dacite with ??{lunate}Nd = +4 to +8, ??{lunate}Sr = -7 to -22, variable ??18O (thought to represent melting of differing mantle-crust reservoirs), 206Pb/204Pb = 18.81-18.87, variable Ca/Sr, Rb/Ba, La/Yb and high Zr, (3) 1000 years ago to present day: eruptions of andesite and dacite with ??{lunate}Nd = +6, ??{lunate}Sr = -13, ??18O ???6???, variable 206Pb/204Pb, Ca/Sr ??? 77, Rb/Ba = 0.1, La/Yb ??? 11. None of the products exhibit Eu anomalies and all are LREE enriched. There is a strong correlation between 87Sr/86Sr and differentiation indices. These data are interpreted in terms of a mantle heat source melting young crust bearing zircon and garnet, but not feldspar, followed by intrusion of this crustal reservoir by mantle-derived magma which caused further crustal melting and contaminated the crustal magma system with mafic components. Since 1000 years ago all the eruptions have been from the same reservoir which has displayed a much more gradual re-equilibration of Pb isotopic compositions than other components suggesting that Pb is being transported via a fluid phase. The Nd and Sr isotopic compositions lie along the mantle array and suggest that the mantle underneath Mt. St. Helens is not as depleted as MORB sources. There is no indication of seawater involvement in the source region. ?? 1983.

Petrogenesis of Western Cascades Silicic Volcanics Near Sweet Home, Oregon

NASA Astrophysics Data System (ADS)

Cook, G. W.; White, C. M.

2002-12-01

Silicic lavas in the Menagerie Wilderness east of Sweet Home, Oregon are Oligocene to Miocene in age and range in composition from dacite (low K) to trachydacite (high K) and rhyolite (medium K). Three distinct silicic centers have been distinguished through a combination of field observation, chemistry and petrography. Phenocryst assemblages in rocks of the centers are plagioclase-hornblende-magnetite (Rooster Rock rhyolite), plagioclase-quartz-magnetite (Soda Fork rhyolite) and quartz-plagioclase-biotite-hornblende-magnetite (Moose Mt. rhyolite). The silicic volcanics in the study area are similar in terms of mineral content and overall chemical composition. Despite this, chemical evidence suggests that the three centers are petrologically unrelated. REE variations and least squares modeling of major element compositions are consistent with fractionation of plagioclase and hornblende. The rhyolites have moderate Eu anomalies and have flat MREE and HREE signatures. Least squares models and bivariate plots of major and trace elements also suggest fractionation of the aforementioned phases for both the andesite to dacite, and dacite to rhyolite steps. Comparisons with similar silicic centers show the Menagerie rocks share affinities with High Cascades rocks thought to have been derived through fractional crystallization (Crater Lake and South Sister). Plots of ratios of incompatible trace elements were utilized to determine if assimilation played some role alongside fractional crystallization in differentiation. Plots of Ba/La vs. Ba, Rb/Zr vs. Rb and Rb/Th vs. Rb show systematic positive increases in the ratios between a plausible parent magma (icelandite) and the rhyolites. These increases are not easily explained by fractional crystallization but can be modeled by assimilation of silicic crust. Overall, it seems likely that the three centers evolved independently through similar petrogenetic processes from an andesitic parent. The most plausible petrogenetic

Miocene magmatism and tectonics within the Peri-Alboran orogen (western Mediterranean)

NASA Astrophysics Data System (ADS)

El Azzouzi, M.; Bellon, H.; Coutelle, A.; Réhault, J.-P.

2014-07-01

volcanic edifice, major calc-alkaline to shoshonitic volcanoes were built between 9.0 ± 0.5 and 4.8 ± 0.5 Ma, in particular the large Gourougou volcanic complex. Near Oujda, volcanic activity of alkaline affinity leads to multiple emissions of basalts throughout Pliocene times until the beginning of Pleistocene, between 6.2 ± 0.3 and 1.5 ± 0.1 Ma. In the Alboran domain, an age of 19.7 ± 0.8 Ma is reported (this study) for the andesitic tuffites that form the emergent part of the Alboran Island. This age is comparable to that of the Algerian tuffites and cherts “silexites” and the Malaga ones in Spain. Younger activity, completely separated from the previous one, forms the low-K basaltic andesitic dikes from Alboran Island, dated between 9.1 ± 0.5 and 7.5 ± 0.3 Ma. Along the Alboran Ridge both low-K and high-K andesites to dacites were emitted in the estimated range of 10.7-8.7 Ma. Low-K and high-K andesites to dacites sampled at ODP sites 977 and 978 into the East Alboran Basin, are dated between 12.1 ± 0.2 and 9.3 ± 0.1 Ma.

Effect of fO2 on phase relationship in basaltic andesites during magmatic differentiation: Control of fO2 and sulphur speciation in piston cylinder experiments.

NASA Astrophysics Data System (ADS)

Matjuschkin, Vladimir; Tattitch, Brian; Blundy, Jonathan D.; Skora, Susanne

2014-05-01

Within the mantle wedge above subduction zones, oxidation reaction take place by interaction of reduced mantle rocks with more oxidized, hydrous fluids, which can cause a local drop of the solidus, resulting in partial melting (2,6,7). The resultant melts are more oxidized that their ocean floor counterparts, which has implications for their subsequent differentiation paths, the speciation of multivalent elements and the solubility and transport of chemical compounds in magmatic systems (1,4,5). We present a series of sulphur-doped high-pressure experiments conducted to investigate the effect of oxygen fugacity on phase relationships and the behaviour of sulphur in silicate melts. Natural aphyric andesite (FM37) erupted from Laguna del Maule volcano, Chile (3) was selected as a starting composition. Experiments were carried out at 5kbar, 950-1150° C and variable oxygen fugacity conditions. New experiments buffered at Co-CoO and Ni-NiO buffer conditions have been performed using a new "MTB capsule design" developed in order to accurately control fO2 by means of a double capsule containing metal-oxide buffers and a pyrex sleeve to minimise H2 diffusion. This new design constrains oxygen fugacity to within ±0.1-0.2logfO2 units of the target value. Before conducting these experiments, the assemblage was tested multiple times at 10kbar, 1000° C over 24-48 hours and demonstrated consistent, accurate fO2 control. Analyses of the preliminary experimental run products, from a related Chilean basaltic andesite starting composition, demonstrate a clear effect of fO2 on phase relationships and the proportion of melt generated during experiments. Under oxidized conditions, as temperature decreased from 1150° C to 1050° C, the amount of melt decreased from 100% to ~80%, due to the formation of orthopyroxene, anhydrite and plagioclase. In contrast, in reduced runs the system remains nearly liquid (~5% crystals) down to 950° C due to the change in sulphur speciation and

Mantle source beneath Turrialba volcano (Costa Rica): a geochemical investigation

NASA Astrophysics Data System (ADS)

Di Piazza, A.; Rizzo, A. L.; Barberi, F.; Carapezza, M. L.; Sortino, F.; De Astis, G.; Romano, C.

2014-12-01

In this study we analysed rocks and noble gas composition of fluid inclusions (FIs) hosted in olivine crystals contained in a suite of eruptive products of the last 10ka of activity of Turrialba volcano, Cordillera Central, Costa Rica. The suite of analyzed rocks display a calc-alkaline affinity, ranging in composition from basaltic-andesite to dacite. Trace element patterns indicate a typical behavior of subduction-related magmas and also the clear contribution of an OIB-like signature at source. A group of andesites displays also adakite-like geochemical features, as evidenced by their constant depletion in HFSE elements. Sr isotope (0.703593 - 0.703678) and Nd isotope ratios (0.512960 - 0.512968) suggest that Turrialba magmas belong to one of the less contaminated mantle source of Central America. The 3He/4He ratio of fluid inclusions from the most mafic eruptive products (basaltic-andesites) varies from 7.86 to 8.07 Ra, while that from andesite lavas varies from 7.03 to 7.18 Ra. In order to understand the mantle source feeding Turrialba volcano, we performed a geochemical investigation on fumarolic gases of summit craters. The He isotope composition of dry gases of Turrialba volcano is characterized by extremely high R/Ra values (7.08-7.96 Ra). The highest 3He/4He ratios were measured at both West and Central Craters (7.93-7.96 Ra and 7.78-7.88 Ra, respectively), and are the highest values of the entire Central America. Despite the observed variability, the 3He/4He ratio of fumarolic gases and FIs from Turrialba volcano is well in the range of arc related volcanism (~7-8 Ra; Hilton et al., 2002), and represents the signature of a mantle wedge in which the contamination by crustal fluids is small to negligible. In addition the occurrence of recent adakite-like magmatism suggests the presence of an abnormal heating of the subducting lithosphere under Turrialba volcano, allowing even old or cold oceanic crust to melt.

Geology and stratigraphy of the San Lorenzo Tezonco deep well and its correlation to surrounding ranges, Mexico Basin

NASA Astrophysics Data System (ADS)

Arce, J. L.; Layer, P. W.; Morales-Casique, E.; Benowitz, J.

2014-12-01

The San Lorenzo Tezonco deep well stratigraphy records intense episodic volcanic activity in the Mexico Basin and surroundings during the past 20 Ma. The 2008-m deep lithological column is dominated by volcanic material, either as lava flows or pyroclastic deposits (97%), and only the upper most 70 m are composed of lacustrine deposits (3%). Based on geochronology and geochemistry, the lower part of the drill core is represented by rocks correlating to the Tepoztlán Formation (876-2008 m deep) that vary in composition from basaltic-andesite to rhyolite, and ages ranging from 13 to 21.2 Ma. On the surface this formation outcrops near the towns of Malinalco and Tepoztlán, ~43 km south of the deep well. Between depths of 581 and 875 m, volcanic rocks were recovered and are interpreted as lavas from the Sierra de las Cruces that vary in composition from andesite to dacite and range in age from 0.9 Ma to 5 Ma. Additionally, we documented rocks belonging to the Xochitepec Formation, outcropping around Xochimilco, in the Mexico City, with ages ranging from 1.2 and 1.7 Ma, in contrast with the Oligocene age proposed in previous works for these rocks. These new ages plus the chemical composition data, allow us to correlate the Xochitepec rocks with Sierra de las Cruces. Upward in the drill core (510-580 m) there are andesitic rocks that correlate with the 0.25 Ma Cerro de la Estrella volcanic center. The last volcanic package found in the well is correlated to the Santa Catarina basaltic andesites (70-120 m) that are younger than 0.25 Ma, and probably Holocene. Lacustrine deposits crown the stratigraphic column of the drill core with ages probably younger than 34 ka. The San Lorenzo Tezonco well is in a graben-like structure that was filled with more than 1900 m of volcanic products, suggesting that volcanism were intense in the Miocene to the Recent, and the south drainage of the Mexico Basin was closed probably in the early Pleistocene.

The Quaternary history of effusive volcanism of the Nevado de Toluca area, Central Mexico

NASA Astrophysics Data System (ADS)

Torres-Orozco, R.; Arce, J. L.; Layer, P. W.; Benowitz, J. A.

2017-11-01

Andesite and dacite lava flows and domes, and intermediate-mafic cones from the Nevado de Toluca area were classified into five groups using field data and 40Ar/39Ar geochronology constraints. Thirty-four lava units of diverse mineralogy and whole-rock major-element geochemistry, distributed between the groups, were identified. These effusive products were produced between ∼1.5 and ∼0.05 Ma, indicating a mid-Pleistocene older-age for Nevado de Toluca volcano, coexisting with explosive products that suggest a complex history for this volcano. A ∼0.96 Ma pyroclastic deposit attests for the co-existence of effusive and explosive episodes in the mid-Pleistocene history. Nevado de Toluca initiated as a composite volcano with multiple vents until ∼1.0 Ma, when the activity began to centralize in an area close to the present-day crater. The modern main edifice reached its maximum height at ca. 50 ka after bulky, spiny domes erupted in the current summit of the crater. Distribution and geochemical behavior in major elements of lavas indicate a co-magmatic relationship between different andesite and dacite domes and flows, although unrelated to the magmatism of the monogenetic volcanism. Mafic-intermediate magma likely replenished the system at Nevado de Toluca since ca. ∼1.0 Ma and contributed to the eruption of new domes, cones, as well as effusive-explosive activity. Altogether, field and laboratory data suggest that a large volume of magma was ejected around 1 Ma in and around the Nevado de Toluca.

The May 2003 eruption of Anatahan volcano, Mariana Islands: Geochemical evolution of a silicic island-arc volcano

USGS Publications Warehouse

Wade, J.A.; Plank, T.; Stern, R.J.; Tollstrup, D.L.; Gill, J.B.; O'Leary, J. C.; Eiler, J.M.; Moore, R.B.; Woodhead, J.D.; Trusdell, F.; Fischer, T.P.; Hilton, David R.

2005-01-01

The first historical eruption of Anatahan volcano began on May 10, 2003. Samples of tephra from early in the eruption were analyzed for major and trace elements, and Sr, Nd, Pb, Hf, and O isotopic compositions. The compositions of these tephras are compared with those of prehistoric samples of basalt and andesite, also newly reported here. The May 2003 eruptives are medium-K andesites with 59-63 wt.% SiO2, and are otherwise homogeneous (varying less than 3% 2?? about the mean for 45 elements). Small, but systematic, chemical differences exist between dark (scoria) and light (pumice) fragments, which indicate fewer mafic and oxide phenocrysts in, and less degassing for, the pumice than scoria. The May 2003 magmas are nearly identical to other prehistoric eruptives from Anatahan. Nonetheless, Anatahan has erupted a wide range of compositions in the past, from basalt to dacite (49-66 wt.% SiO2). The large proportion of lavas with silicic compositions at Anatahan (> 59 wt.% SiO2) is unique within the active Mariana Islands, which otherwise erupt a narrow range of basalts and basaltic andesites. The silicic compositions raise the question of whether they formed via crystal fractionation or crustal assimilation. The lack of 87Sr/86Sr variation with silica content, the MORB-like ??18O, and the incompatible behavior of Zr rule out assimilation of old crust, altered crust, or zircon-saturated crustal melts, respectively. Instead, the constancy of isotopic and trace element ratios, and the systematic variations in REE patterns are consistent with evolution by crystal fractionation of similar parental magmas. Thus, Anatahan is a type example of an island-arc volcano that erupts comagmatic basalts to dacites, with no evidence for crustal assimilation. The parental magmas to Anatahan lie at the low 143Nd/144Nd, Ba/La, and Sm/La end of the spectrum of magmas erupted in the Marianas arc, consistent with 1-3 wt.% addition of subducted sediment to the mantle source, or roughly one

Diverse lavas from closely spaced volcanoes drawing from a common parent: Emmons Lake Volcanic Center, Eastern Aleutian Arc

USGS Publications Warehouse

Mangan, M.; Miller, T.; Waythomas, C.; Trusdell, F.; Calvert, A.; Layer, P.

2009-01-01

Emmons Lake Volcanic Center (ELVC) on the lower Alaskan Peninsula is one of the largest and most diverse volcanic centers in the Aleutian Arc. Since the Middle Pleistocene, eruption of ~ 350 km3 of basalt through rhyolite has produced a 30 km, arc front chain of nested calderas and overlapping stratovolcanoes. ELVC has experienced as many as five major caldera-forming eruptions, the most recent, at ~ 27 ka, produced ~ 50 km3 of rhyolitic ignimbrite and ash fall. These violent silicic events were interspersed with less energetic, but prodigious, outpourings of basalt through dacite. Holocene eruptions are mostly basaltic andesite to andesite and historically recorded activity includes over 40 eruptions within the last 200 yr, all from Pavlof volcano, the most active site in the Aleutian Arc. Geochemical and geophysical observations suggest that although all ELVC eruptions derive from a common clinopyroxene + spinel + plagioclase fractionating high-aluminum basalt parent in the lower crust, magma follows one of two closely spaced, but distinct paths to the surface. Under the eastern end of the chain, magma moves rapidly and cleanly through a relatively young (~ 28 ka), hydraulically connected dike plexus. Steady supply, short magma residence times, and limited interaction with crustal rocks preserve the geochemistry of deep crustal processes. Below the western part of the chain, magma moves haltingly through a long-lived (~ 500 ka) and complex intrusive column in which many generations of basaltic to andesitic melts have mingled and fractionated. Buoyant, silicic melts periodically separate from the lower parts of the column to feed voluminous eruptions of dacite and rhyolite. Mafic lavas record a complicated passage through cumulate zones and hydrous silicic residues as manifested by disequilibrium phenocryst textures, incompatible element enrichments, and decoupling of REEs and HFSEs ratios. Such features are absent in mafic lavas from the younger part of the chain

Allochthonous 2.78 Ga oceanic plateau slivers in a 2.72 Ga continental arc sequence: Vizien greenstone belt, northeastern Superior Province, Canada

NASA Astrophysics Data System (ADS)

Skulski, T.; Percival, J. A.

1996-04-01

Embedded within the vast granitoid terrane of the Minto block of northeastern Superior Province are Late Archean greenstone belts of the Goudalie domain that preserve a long-lived record of continent-ocean interaction. The Vizien greenstone belt is one such belt and it contains four fault-bounded structural panels. The 2786 Ma mafic-ultramafic sequence is an allochthonous package of pillowed basaltic andesite, komatiite and volcaniclastic rocks cut by peridotite and gabbro sills. The mafic rocks are LREE-depleted tholeiites which have primitive mantle (PRIM)-normalized abundances of Th < Nb < La, and ɛNd values of +1.5 to + 3.2 reflecting extraction from a depleted mantle source. The 2724 Ma lac Lintelle continental calc-alkaline volcanic sequence consists of massive basalt, plagioclase-porphyritic andesite, dacite, rhyolite, capped by quartz-rich sandstones/conglomerates with 2.97 Ga Nd model ages. Lac Lintelle volcanic rocks are LREE enriched, with low TiO 2 (< 1%) and Zr (< 200 ppm), PRIM-normalized enrichment in Th > La > Nb, and a range of ɛNd values from -0.1 to +1.7. The ~ 2722 Ma lac Serindac bimodal, subaerial tholeiitic volcanic sequence contains andesite (locally with tonalite xenoliths), basalt, gabbro sills, lenses of quartz-rich sedimentary rocks and a thick, upper rhyolite sequence. The lac Serindac tholeiites are LREE-enriched, have PRIM-normalized Th > La > Nb, high Zr (to 300 ppm) and Ti contents, and low ɛNd values from +0.8 in basalt to -1.4 in rhyolite. The < 2718 Ma basement-cover sequence comprises 2.94 Ga tonalitic gneiss unconformably overlain by clastic sediments and a thin upper sequence of 2700 Ma gabbro, siliceous high-Mg basalt (SHMB) and andesite. The SHMB are characterised by LREE depletion and ɛNd values of +2.6, whereas the andesite is LREE-enriched and has ɛNd values of -0.3. The 2786 Ma mafic-ultramafic sequence is interpreted as a sliver of plume-related oceanic plateau crust. The 2724 lac Lintelle sequence represents a

Magma evolution at Copahue volcano (Chile/Argentina border): insights from melt inclusions

NASA Astrophysics Data System (ADS)

Cannatelli, C.; Aracena, C.; Leisen, M.; Moncada, D.; Roulleau, E.; Vinet, N.; Petrelli, M.; Paolillo, A.; Barra, F.; Morata, D.

2016-12-01

Copahue volcano is an active stratovolcano in the Andean Southern Volcanic Zone (SVZ), straddling at the border between Central Chile and Argentina. The volcano's eruptive style during its history has changed from mainly effusive in the Pleistocene to explosive in the Holocene. The prehistoric eruptions can be divided into pre-glacial (PG), syn-glacial (SG) and post-glacial (PM) stages, with products ranging from basaltic andesites to andesites. In order to investigate the evolution of the magma source and volatiles through time, we have focused our study on the eruptive products from the SG to the 2014 eruption (SUM2014). Sampled rocks are glomero-porphyritic, with a paragenetic mineral sequence of feldspars, ortho- and clinopyroxene, and olivine in order of abundance. All samples present a variable number of vesicles, with SUM2014 samples containing the biggest amount. Feldspar composition varies from Na-rich (andesine) in SG to Ca-rich (labradorite) in SUM2014. Two pyroxene types are present in SG and PM samples (augite and enstatite), while SUM2014 presents augite, pigeonite and enstatite. Thermobarometric estimation, based on mineral chemistry, show a bimodal distribution for SG and SUM2014 (P=10-12 kbars and 5-8 kbars) and only one interval for PM (P=7-8 kbars). Melt Inclusions Assemblages (MIAs) are found in all mineral phases, mostly re-crystallized, with one or more bubbles and daughter oxide minerals. Compositions vary from trachy-andesitic to dacitic for SG, andesitic to trachydacitic for PM, and basaltic andesitic to trachydacitic for SUM2014. Major elements systematics show the existence of a bimodal distribution of pyroxene and feldspar hosted-MIA in SUM2014, which together with the co-presence of pigeonite (low-Ca pyroxene) and augite and the bimodal distribution of P, can be interpreted as evidence of mixing of two types of magmas, evolving at different depths. Trace elements systematics for MIA in SG, PM and SUM2014 show a negative anomaly for Nb

Volcanic and Tectonic Evolution of The Gulf of California Near Mulege, Baja California Sur: Results From Baja Basins NSF-REU (Research Experience for Undergraduates)

NASA Astrophysics Data System (ADS)

Hutchinson, S. J.; Allard, J.; Acuna, N.; Graettinger, A. H.; Busby, C.

2017-12-01

Cenozoic volcanic rocks have been studied along many parts of the Gulf of California margin of Baja California because they provide a record of its volcano-tectonic evolution, from subduction (24-12 Ma), to rifting (<12 Ma). The 2015-2016 Baja Basins REU studied volcanic rocks around the Boleo basin, and used geochemistry and 40Ar/39AR geochronology to recognize a ca. 10-14 Ma calcalkaline subduction assemblage, and a 6.1 Ma magnesian andesite assemblage inferred to be related to the Boleo stratiform Cu-Co-Zn sulfides. However, volcanic rocks in a 5,000 km2 region between Santa Rosalia and Mulegé remain largely undivided. The 2017 volcanology group mapped a 390 km2 area inland from Mulegé. Geologic results are described here, while geochemical data used to divide the volcanic rocks into suites are described in an accompanying abstract1. We infer the following sequence of events: (1) A half graben filled with a >820 m thick red bed sequence, sourced to the east by andesitic volcanic rocks eroded from the footwall of a west-dipping normal fault. Proximal alluvial fan bajada deposits are debris-flow dominated, with angular clasts up to 1.3 m in size. Distal braided stream deposits have sandstones and cobble conglomerates, with abundant cut and fill structures and rounded clasts. Adakite trachyandesite block-and-ash-flow tuffs are interstratified with the proximal deposits, representing pyroclastic flows generated by collapse of lava domes plumbed up the basin-bounding fault to the east. (2) The redbeds were cut by a dike swarm that fed a field of lava shield volcanoes. The dikes and lava shields include calcalkaline basaltic andesite, andesite and dacite, as well as magnesian trachyandesite and basaltic andesite. (3) A N-S, subvertical fault stepped into the basin and dropped the lava shields down to the east, while they were eroded off the uplifted footwall to the west. (4) The footwall block was beveled and overlain by plateau-forming magnesian basaltic

Mineral disequilibrium in lavas explained by convective self-mixing in open magma chambers.

PubMed

Couch, S; Sparks, R S; Carroll, M R

2001-06-28

Characteristic features of many porphyritic andesite and dacite lavas are that they are rich in crystals and display a range of disequilibrium features, including reversely zoned crystals, resorption surfaces, wide ranges of mineral compositions and minerals which are not in equilibrium with the surrounding rock matrix. These features are often interpreted as evidence of the mixing of magmas of contrasting composition, temperature and origin. Here, however, we propose that such features can also be caused by convection within a magma body with a single composition, that is heated from below and cooled from above. We describe petrological observations of andesite lava erupted at the Soufrière Hills volcano, Montserrat, which indicate a heating event and the intermingling of crystals that have very different thermal histories. We present experimental data on a representative groundmass composition of this lava, which indicate that it is difficult to explain the calcic compositions of plagioclase overgrowth rims and microphenocrysts unless parts of the magma were at temperatures much higher than the inferred average temperature. The concept of convective self-mixing allows us to explain the occurrence of compositions of minerals that apparently cannot coexist under equilibrium conditions.

Rheology of arc dacite lavas: experimental determination at low strain rates

NASA Astrophysics Data System (ADS)

Avard, Geoffroy; Whittington, Alan G.

2012-07-01

Andesitic-dacitic volcanoes exhibit a large variety of eruption styles, including explosive eruptions, endogenous and exogenous dome growth, and kilometer-long lava flows. The rheology of these lavas can be investigated through field observations of flow and dome morphology, but this approach integrates the properties of lava over a wide range of temperatures. Another approach is through laboratory experiments; however, previous studies have used higher shear stresses and strain rates than are appropriate to lava flows. We measured the apparent viscosity of several lavas from Santiaguito and Bezymianny volcanoes by uniaxial compression, between 1,109 and 1,315 K, at low shear stress (0.085 to 0.42 MPa), low strain rate (between 1.1 × 10-8 and 1.9 × 10-5 s-1), and up to 43.7 % total deformation. The results show a strong variability of the apparent viscosity between different samples, which can be ascribed to differences in initial porosity and crystallinity. Deformation occurs primarily by compaction, with some cracking and/or vesicle coalescence. Our experiments yield apparent viscosities more than 1 order of magnitude lower than predicted by models based on experiments at higher strain rates. At lava flow conditions, no evidence of a yield strength is observed, and the apparent viscosity is best approached by a strain rate- and temperature-dependent power law equation. The best fit for Santiaguito lava, for temperatures between 1,164 and 1,226 K and strain rates lower than 1.8 × 10-4 s-1, is log {η_{{app}}} = - 0.738 + 9.24 × {10^3}{/}T(K) - 0.654 \\cdot log dot{\\varepsilon } where η app is apparent viscosity and dot{\\varepsilon } is strain rate. This equation also reproduced 45 data for a sample from Bezymianny with a root mean square deviation of 0.19 log unit Pa s. Applying the rheological model to lava flow conditions at Santiaguito yields calculated apparent viscosities that are in reasonable agreement with field observations and suggests that

New perspectives on the eruption of 1912 in the valley of ten thousand smokes, Katmai National Park, Alaska

USGS Publications Warehouse

Hildreth, W.

1987-01-01

New data extend our understanding of the 1912 eruption, its backfilled vent complex at Novarupta, and magma-storage systems beneath adjacent stratovolcanoes. Initial Plinian rhyolite fallout is confined to a narrow downwind sector, and its maximum thickness may occur as far as 13 km from source. In contrast, the partly contemporaneous rhyolite-rich ash flows underwent relatively low-energy emplacement, their generation evidently being decoupled from the high column. Flow veneers 1-13 m thick on near-vent ridge crests exhibit a general rhyolite-to-andesite sequence like that of the much thicker valley-confined ignimbrite into which they merge downslope. Lithics in both the initial Plinian and the ignimbrite are predominantly fragments of the Jurassic Naknek Formation, which extends from the surface to a depth of ca. 1500 m. Absence of lithics from the underlying sedimentary section limits to 100 m thick near source and 10 m thick 3 km away, which dip back into an inner vent <0.5 km wide, nested inside the earlier vent funnel of the ignimbrite. The dacite fallout is poor in Naknek lithics but contains abundant fragments of vitrophyre, most of which was vent-filling, densely welded tuff reejected during later phases of the 3-day eruption. Adjacent to the inner vent, a 225-m-high asymmetrical accumulation of coarse near-vent ejecta is stratigraphically continuous with the regional dacite fallout. Distensional faulting of its crest may reflect spreading related to compaction and welding. Nearby andesite-dacite stratovolcanoes, i.e., Martin, Mageik, Trident, and Katmai, display at least 12 vents that define a linear volcanic front trending N65??E. The 1912 vent and adjacent dacite domes are disposed parallel to the front and ca. 4 km behind it. Mount Griggs, 10 km behind the front, is more potassic than other centers, taps isotopically more depleted source materials, and reflects a wholly independent magmatic plumbing system. Geochemical differences among the

Emplacement controls for the basaltic-andesitic radial dikes of Summer Coon volcano and implications for flank vents at stratovolcanoes

NASA Astrophysics Data System (ADS)

Harp, A. G.; Valentine, G. A.

2018-02-01

Mafic flank eruptions are common events that pose a serious hazard to the communities and infrastructure often encroaching on the slopes of stratovolcanoes. Flank vent locations are dictated by the propagation path of their feeder dikes. The dikes are commonly thought to propagate either laterally from the central conduit or vertically from a deeper source. However, these interpretations are often based on indirect measurements, such as surface deformation and seismicity at active systems, and several studies at eroded volcanoes indicate the propagation paths may be more complex. We investigated the Oligocene age Summer Coon volcano (Colorado, USA), where erosion has exposed over 700 basaltic-andesitic radial dikes, to constrain the propagation directions, geometries, and spatial distributions of mafic dikes within a stratovolcano. The mean fabric angle of aligned plagioclase crystals was measured in oriented samples from the margins of 77 dikes. Of the 41 dikes with statistically significant flow fabrics, 85% had fabric angles that were inclined—plunging both inward and outward relative to the center of the volcano. After comparing fabric angles to those reported in other studies, we infer that, while most of the dikes with outward-plunging fabrics descended toward the flanks from a source within the edifice and near its axis, dikes with inward-plunging fabrics ascended through the edifice and toward the flanks from a deeper source. A possible control for the inclination of ascending dikes was the ratio between magma overpressure and the normal stress in the host rock. While higher ratios led to high-angle propagation, lower ratios resulted in inclined emplacement. Dikes crop out in higher frequencies within a zone surrounding the volcano axis at 2500 m radial distance from the center and may be the result of ascending dikes, emplaced at similar propagation angles, intersecting the current level of exposure at common distances from the volcano axis. The process

Miocene to Recent geological evolution of the Lazufre segment in the Andean volcanic arc

NASA Astrophysics Data System (ADS)

Naranjo, J. A.; Villa, V.; Ramírez, C.; Pérez de Arce, C.

2014-12-01

The volcano-tectonic setting in which the InSAR-detected Lazufre deformation is developing is particularly relevant in the evolution of this Andean volcanic arc segment (25-26°S). Through regional mapping techniques, a comprehensive field control in addition to geochronological sampling, various volcanic units comprising stratovolcanoes, volcanic complexes, ignimbrites and caldera structures are distinguished. The Lazufre intumescence is located above the overlying block of the NE trending Middle Miocene, Pedernales-Arizaro overthrust. This area comprises an Upper Miocene (8-4 Ma) basal unit of andesitic-dacitic volcanoes and lava fields, upon which nine volcanic complexes of similar composition, including Caletones de Cori Ignimbrite and Escorial Volcano, Lastarria, Cordón del Azufre and Bayo volcanic complexes, were emplaced in several pulses between 3.5 Ma and Holocene times. Coalescing Lazufre structure, immediately to the SE, we have discovered the Miocene (9.8 Ma) Los Colorados caldera. This caldera is 30 km in diameter and sourced the homonymous dacitic ignimbrite of about 500 km3. The caldera scarp was formed in Paleozoic rocks, Miocene dacitic-rhyolitic ignimbrites and ~16 and 10 Ma volcanoes. A 6.9-6.8 Ma andesitic-dacitic volcano ridge formed by Abra Grande, Río Grande and Aguas Calientes stratovolcanoes, from NE to SW, is nested on the caldera floor. Lavas of early stages of Cordón del Azufre and Bayo complexes were shed into the NW part of the caldera. The coalescing structure formed by the Lazufre intumescence and Los Colorados caldera is conjugate at about 30° to the Pedernales-Arizaro overthrust, and has a NW-SE orientation, parallel to the Archibarca lineament. A SE to NW migration of volcanism is observed along this structure at least since the Middle Miocene. We proposed that, since Miocene, tectonic spaces with no surficial fault displacements and conjugated to the main compressive structures within the upper crust, have been created as a

Structural control on arc volcanism: The Caviahue Copahue complex, Central to Patagonian Andes transition (38°S)

NASA Astrophysics Data System (ADS)

Melnick, Daniel; Folguera, Andrés; Ramos, Victor A.

2006-11-01

This paper describes the volcanostratigraphy, structure, and tectonic implications of an arc volcanic complex in an oblique subduction setting: the Caviahue caldera Copahue volcano (CAC) of the Andean margin. The CAC is located in a first-order morphotectonic transitional zone, between the low and narrow Patagonian and the high and broad Central Andes. The evolution of the CAC started at approximately 4-3 Ma with the opening of the 20 × 15 km Caviahue pull-apart caldera; Las Mellizas volcano formed inside the caldera and collapsed at approximately 2.6 Ma; and the Copahue volcano evolved in three stages: (1) 1.2-0.7 Ma formed the approximately 1 km thick andesitic edifice, (2) 0.7-0.01 Ma erupted andesitic-dacitic subglacial pillow lavas, and (3) 0.01-0 Ma erupted basaltic-andesites and pyroclastic flows from fissures, aligned cones, and summit craters. Magma ascent has occurred along planes perpendicular to the least principal horizontal stress, whereas hydrothermal activity and hot springs also occur along parallel planes. At a regional scale, Quaternary volcanism concentrates along the NE-trending, 90 km long Callaqui-Copahue-Mandolegüe lineament, the longest of the southern volcanic zone, which is here interpreted as an inherited crustal-scale transfer zone from a Miocene rift basin. At a local scale within the CAC, effusions are controlled by local structures that formed at the intersection of regional fault systems. The Central to Patagonian Andes transition occurs at the Callaqui-Copahue-Mandolegüe lineament, which decouples active deformation from the intra-arc strike-slip Liquiñe-Ofqui fault zone to the south and the backarc Copahue-Antiñir thrust system.

Late Tertiary/Quaternary volcanics of southern Costa Rica and northern Panama

DOE Office of Scientific and Technical Information (OSTI.GOV)

Roy, A.; Byerly, G.R.

1985-01-01

The recent tectonic evolution of the Isthmus of Panama is marked by a complexity imparted by a subduction zone - magmatic arc, a transform plate boundary, and the attempted subduction of an aseismic ridge. In northern Panama andesites form the morphologically young Chiriqui stratovolcano, while in southern Costa Rica they are found interbedded with thick lahars. Two groups of andesites occur in the region. One is low in Si and K (Group I); the other high in Si and K (Group II). The Panamanian andesites belong to both the groups, while Costa Rican andesites are restricted to Group II. Groupmore » I andesites are glassy, plagioclase-phyric (An45 rims), and contain abundant augite (Wo46En46Fs8) and magnetite. Rare, resorbed olivine (Fo82) and amphibole are occasionally observed. The Group II andesites have similar mineralogy but also contain abundant pargasitic hornblende and minor orthopyroxene or pigeonite. Xenoliths are common in the Group II andesites of Chiriqui Volcano. Two types of xenoliths are recognized. Cumulate-textured, hornblende gabbro xenoliths vary from nearly pure plagioclase to nearly pure amphibole. These gabbroic xenoliths contain plagioclase (An90 cores to An53 rims), augite, and pargasitic hornblende often displaying the same reaction products as found in the andesites. These xenoliths are interpreted as cognate. These andesites are all characterized by high alkalis and alkali earths; Group II have over 1500 ppm Ba and 1000 ppm Sr. They are apparently produced by partial melting of a highly metasomatised mantle followed by high-pressure fractionation dominated by hornblende.« less

Petrological, geochemical, and stable isotope constraints on the genesis of the Miocene igneous rocks of Chetaibi and Cap de Fer (NE Algeria)

NASA Astrophysics Data System (ADS)

Laouar, R.; Boyce, A. J.; Arafa, M.; Ouabadi, A.; Fallick, A. E.

2005-06-01

Miocene igneous rocks (diorites, andesites, dacites, rhyolites and microgranites) of Chetaibi and Cap de Fer massif, NE Algeria, are high-K calc-alkaline to shoshonitic rocks. Fresh diorites have δ 34S and δ 18O values ranging between -2.5‰ and +5.9‰, +6.5‰ and +6.7‰ respectively, indicating a mantle origin. The relatively low δ 34S values (-5.4‰ to -12.2‰) and high δ 18O (+8.3‰ to +9.0‰) of altered diorites indicate the input of a crustal component to the initial magma. The microgranites' I-type signature is indicated by the geochemical data and the δ 34S and δ 18O values of -1.2‰ and -3.6‰, and +7.8‰ to +10.4‰ respectively. The andesites show a large variation of δ 34S, between -33.2‰ and +25.7‰. Massive andesites with δ 34S between +6.8‰ and +7.6‰ preserve a 34S-enriched mantle signature. The δ 34S of the lava flows between +25.7‰ and +25.8‰ are attributed to open system magma degassing, whereas the low δ 34S of two andesitic dyke samples (-13.7‰ and -33.2‰) strongly suggest a crustal sulphur input. High δ 18O (+9.2‰ to +15.7‰) of andesites indicate post-magmatic alteration (mainly silicification); the flyschs with δ 18O between of +13.3‰ and +21.7‰ are most likely the contaminant. Quartz veins within the andesites gave a δ 18O value of +23.0‰ while silica-filling vesicles yielded a value of +13.8‰. Initial Sr-isotope data are rather high for all the rocks (diorites: 0.707-0.708, andesites: 0.707-0.710, and microgranites and rhyolites: 0.717-0.719), and because geochemical and stable isotope data do not indicate a substantial amount of crustal assimilation, an extensive enrichment of the mantle source by subducted sediments is called for. A metasomatized-mantle source, characterized by high radiogenic Sr and relatively high δ 18O, has also been indicated for the genesis of similar Tertiary igneous rocks in the Western Mediterranean basin, e.g. the Volcanic Province of southeasten Spain [Benito, R

Intrusive hyaloclastite and peperitic breccias associated to sill and cryptodome emplacement on an Early Paleocene polymagmatic compound cone-dome volcanic complex from El Guanaco mine, Northern Chile

NASA Astrophysics Data System (ADS)

Páez, G. N.; Permuy Vidal, C.; Galina, M.; López, L.; Jovic, S. M.; Guido, D. M.

2018-04-01

This work explores the textural characteristics, morphology and facies architecture of well-preserved Paleocene hyaloclastic and peperitic breccias associated with subvolcanic intrusions at El Guanaco gold mine (Northern Chile). The El Guanaco mine volcanic sequence is part of a polymagmatic compound cone-dome volcanic complex grouping several dacitic domes and maar-diatremes, and subordinated subvolcanic intrusions of basaltic, andesitic and dacitic compositions. The Soledad-Peñafiel Fault System is a first order regional structure controlling the location and style of the volcanism in the region. Three different intrusive bodies (Basaltic sills, Dacitic cryptodomes and Andesitic cryptodomes) were found to intrude into a wet and poorly consolidated pyroclastic sequence representing the upper portions of a maar-diatreme. Consequently, extensive quench fragmentation and fluidization along their contacts occurred, leading to the formation of widespread breccia bodies enclosing a coherent nucleus. Differences in matrix composition allows to define two main breccias types: 1) poorly-sorted monomictic breccias (intrusive hyaloclastites) and 2) poorly-sorted tuff-matrix breccias (peperites). The observed facies architecture is interpreted as the result of the interplay of several factors, including: 1) magma viscosity, 2) the geometry of the intrusives, and 3) variations on the consolidation degree of the host rocks. Additionally, the overall geometry of each intrusive is interpreted to be controlled by the effective viscosity of the magmas along with the available magma volume at the time of the intrusions. The presence of three compositionally different subvolcanic bodies with intrusive hyaloclastite and peperite envelopes indicate, not only that all these intrusions occurred in a short period of time (probably less than 2-3 Ma), but also that the volcaniciclastic pile suffer little or none compaction nor consolidation during that time. The presence of three

Recording the transition from flare-up to steady-state arc magmatism at the Purico-Chascon volcanic complex, northern Chile

NASA Astrophysics Data System (ADS)

Burns, Dale H.; de Silva, Shanaka L.; Tepley, Frank; Schmitt, Axel K.; Loewen, Matthew W.

2015-07-01

The long-term evolution of continental magmatic arcs is episodic, where a few transient events of high magmatic flux or flare-ups punctuate the low-flux magmatism or "steady state" that makes up most of the arc history. How this duality manifests in terms of differences in crustal architecture, magma dynamics and chemistry, and the time scale over which transitions occur is poorly known. Herein we use multiscale geochemical and isotopic characteristics coupled with geothermobarometry at the Purico-Chascon Volcanic Complex (PCVC) in the Central Andes to identify a transition from flare-up to steady state arc magmatism over ∼800 kyr during which significant changes in upper crustal magmatic dynamics are recorded. The PCVC is one of the youngest volcanic centers related to a 10-1 Ma ignimbrite flare-up in the Altiplano-Puna Volcanic Complex of the Central Andes. Activity at the PCVC initiated 0.98 ± 0.03 Ma with the eruption of a large 80-100 km3 crystal-rich dacite ignimbrite. High, restricted 87Sr/86Sr isotope ratios between 0.7085 and 0.7090 in the bulk rock and plagioclase crystals from the Purico ignimbrite, combined with mineral chemistry and phase relationships indicate the dacite magma accumulated and evolved at relatively low temperatures around 800-850 °C in the upper crust at 4-8 km depth. Minor andesite pumice erupted late in the ignimbrite sequence records a second higher temperature (965 °C), higher pressure environment (17-20 km), but with similar restricted radiogenic bulk rock 87Sr/86Sr = 0.7089-0.7091 to the dacites. The compositional and isotopic characteristics of the Purico ignimbrite implicate an extensive zone of upper crustal mixing, assimilation, storage and homogenization (MASH) between ∼30 and 4 km beneath the PCVC ∼1 Ma. The final eruptions at the PCVC < 0.18 ± 0.02 Ma suggest a change in the magmatic architecture beneath the PCVC. These eruptions produced three small <6 km3 crystal-rich dacite lava domes with radiogenic bulk rock

Lithology, age and structure of early proterozoic greenstone belts, West African shield

NASA Technical Reports Server (NTRS)

Attoh, K.

1986-01-01

Lithologic and chemical data have been compiled for belts in the Proterozoic terrane. Available stratigraphic information from geologic maps of these areas indicate that a typical sequence is comprised of predominately mafic lava flows (basalt-andesite) at the base, which are overlain by felsic volcanic rocks including pyroclastic rocks and lavas. Lithostratigraphic data indicate the volcanic succession is 6-8 km thick. This is followed by 3-4 km of basaltic lava flows which are locally pillowed, the top of the unit is marked by a distinctive manganese formation (MF) consisting of Mn-Fe rich cherts up to 200 m thick. The youngest volcanic unit consists of mafic tuffs and breccia with a distinctive fragmental texture. Of about 100 chemical analyses reported calc-alkaline rocks constitute 55% and tholeiites 45%. Quartz-normative basalt constitutes 99% of the rock type in the tholeiitic suite. In the calc-alkaline suite, 9% of the analyses is basalt, 45% andesite and the rest is dacite and rhyodacite. The available data lead to the conclusion that the minimum age for the volcanic activity must be between 2200 and 2100 million years. It is significant that Archean ages have not been reported from any of the volcanic belts (1-10).

Geologic map of the central San Juan caldera cluster, southwestern Colorado

USGS Publications Warehouse

Lipman, Peter W.

2006-01-01

The San Juan Mountains are the largest erosional remnant of a composite volcanic field that covered much of the southern Rocky Mountains in middle Tertiary time. The San Juan field consists mainly of intermediate-composition lavas and breccias, erupted about 35-30 Ma from scattered central volcanoes (Conejos Formation) and overlain by voluminous ash-flow sheets erupted from caldera sources. In the central San Juan Mountains, eruption of at least 8,800 km3 of dacitic-rhyolitic magma as nine major ash flow sheets (individually 150-5,000 km3) was accompanied by recurrent caldera subsidence between 28.3 Ma and about 26.5 Ma. Voluminous andesitic-dacitic lavas and breccias erupted from central volcanoes prior to the ash-flow eruptions, and similar lava eruptions continued within and adjacent to the calderas during the period of more silicic explosive volcanism. Exposed calderas vary in size from 10 to 75 km in maximum dimension; the largest calderas are associated with the most voluminous eruptions.

Boninite and boninite-series volcanics in northern Zambales ophiolite: doubly vergent subduction initiation along Philippine Sea plate margins

NASA Astrophysics Data System (ADS)

Perez, Americus; Umino, Susumu; Yumul, Graciano P., Jr.; Ishizuka, Osamu

2018-06-01

A key component of subduction initiation rock suites is boninite, a high-magnesium andesite that is uniquely predominant in western Pacific forearc terranes and in select Tethyan ophiolites such as Oman and Troodos. We report, for the first time, the discovery of low-calcium, high-silica boninite in the middle Eocene Zambales ophiolite (Luzon Island, Philippines). Olivine-orthopyroxene microphyric high-silica boninite, olivine-clinopyroxene-phyric low-silica boninite and boninitic basalt occur as lapilli fall deposits and pillow lava flows in the upper volcanic unit of the juvenile arc section (Barlo locality, Acoje Block) of the Zambales ophiolite. This upper volcanic unit overlies a lower volcanic unit consisting of basaltic andesite, andesite to dacitic lavas and explosive eruptive material (subaqueous pahoehoe and lobate sheet flows, agglutinate and spatter deposits) forming a low-silica boninite series. The overall volcanic stratigraphy of the extrusive sequence at Barlo resembles holes U1439 and U1442 drilled by IODP Expedition 352 in the Izu-Ogasawara (Bonin) trench slope. The presence of depleted proto-arc basalts in the Coto Block (45 Ma) (Geary et al., 1989), boninite and boninite series volcanics in Barlo (Acoje Block (44 Ma)) and simultaneous and post-boninite moderate-Fe arc tholeiites in Sual and Subic areas of the Acoje Block (44-43 Ma) indicate that the observed subduction initiation stratigraphy in the Izu-Ogasawara-Mariana forearc is also present in the Zambales ophiolite. Paleolatitudes derived from tilt-corrected sites in the Acoje Block place the juvenile arc of northern Zambales ophiolite in the western margin of the Philippine Sea plate. In this scenario, the origin of Philippine Sea plate boninites (IBM and Zambales) would be in a doubly vergent subduction initiation setting.

The origin of low-K rhyolites from the mariana frontal arc

NASA Astrophysics Data System (ADS)

Meijer, A.

1983-08-01

Low-K rhyolites and overlying 2-pyroxene andesites, both of Late Eocene age, comprise the oldest volcanic units exposed on Saipan. The mineralogy and geologic setting of these rocks indicate they were erupted in a volcanic arc setting. The presence of andesite and lack of basalts of similar age suggest that the rhyolites are not part of a typical bimodal (basalt/rhyolite) suite. Major and trace element data indicate the Saipan andesites were not parental to the rhyolites. Out of various models evaluated for derivation of the rhyolites, the most reasonable involves crystal fractionation of a boninite series andesite that was very depleted in LIL elements. This andesite probably evolved from more mafic magmas which in turn were derived from the sub-arc mantle. Isotopic data suggest the mantle source for these magmas may have contained a minor seawater component.

Geochemical characterization of mid-distal Nisyros tephra on Datça peninsula (southwestern Anatolia)

NASA Astrophysics Data System (ADS)

Gençalioğlu-Kuşcu, Gonca; Uslular, Göksu

2018-04-01

We present new distal records of tephra deposits that overly the Kos ignimbrite in seven locations of Datça peninsula. Tephra in one of these locations were previously associated with Nisyros Kyra sub-unit based only on the field characteristics. We use different proxies such as field observations, petrography, mineral, glass, and whole-rock chemistry in order to characterize and correlate the previously and recently identified pumice fall deposits on Datça. The total thickness of the fall deposit reaches to 3.5 m. The size of the pumice clasts is generally within the range of lapilli, and they have vitrophyric texture consisting mainly of plagioclase (andesine to labradorite) with scarce clinopyroxene (diopside to augite), olivine (Fo48-50), amphibole (magnesio-hastingsite), and biotite crystals. Amphibole is a ubiquitous phenocryst in all Datça tephra units and used as a criterion for the correlation. Glass major element analyses by EMPA reveal two different groups with andesitic and dacitic compositions. Difference in silica content (up to ca. 4 wt%) detected in the same specimen also designates the heterogeneity in pumice glass. This heterogeneity in glass composition is also supported by the frequent occurrence of banded pumice clasts in Datça tephra. Whole-rock composition of the pumice is mainly andesitic with calc-alkaline affinity. Multi-element patterns on primitive-mantle normalized diagram display typical arc-magmatism signature (i.e. depletion in Nb, Ta, Ti, and P). In order to check and eliminate the potential alternatives, we compared the distal deposits on Datça not only with Kyra, but also with other Nisyros tephra units. Yet, Kyra is the only unit that has comparable depositional characteristics, calcic amphibole crystals, andesitic-dacitic glass and whole-rock chemistry, and distal tephra deposits on neighboring islands (Tilos and Chalki). Therefore, we associate Datça tephra deposits with some proximal Kyra subunits of intermediate

The effect of pressure and temperature on sulfur degassing from oxidized magmas: implications for magmatic-hydrothermal ore genesis and "excess sulfur" in volcanic eruptions

NASA Astrophysics Data System (ADS)

Zajacz, Z.

2017-12-01

Sulfur released during the ascent and crystallization of hydrous and oxidized arc magmas is thought to play an essential role in the genesis of magmatic-hydrothermal ore deposits, such as porphyry Cu-Mo-Au and high-sulfidation epithermal Au deposits. If emitted into the atmosphere during volcanic eruptions, it may exert a significant short-term global impact on the Earth's climate due to the generation of sulfate aerosol. Therefore, it is critically important to understand how physical-chemical variables affect the efficiency of sulfur extraction from magmas. High pressure (P) -temperature (T) experiments were conducted to systematically address the effect P-T on the equilibrium partitioning of oxidized sulfur between silicate melts and magmatic volatiles. The confining P was varied between 30 and 480 MPa, whereas the temperature ranged between 920 and 1100 oC. The oxygen fugacity (fO2) was buffered using Re-ReO2 assemblage in all experiments ensuring that sulfur was dominantly present in 4+ and 6+ oxidation state. For the pressure series experiments, a phonolite and a basaltic andesite melt composition was used, because sulfur is thought to be dissolved dominantly as alkali sulfate species in the former and as CaSO4 species in the latter. The data show that the volatile/melt partition coefficients of oxidized sulfur (DSv/m) strongly increase with decreasing pressure for both melt compositions. For example, in the case of the basaltic andesite melt, DSv/m increases from 12.7±0.5 to 71±4 as P changes from 480 to 60 MPa. For the temperature series experiments, the basaltic andesite was replaced by a dacite melt to allow for a broader range of superliquidus temperatures within the reach of the experimental apparatus. The effect of temperature on DSv/m is more moderate than that of P. For the dacite melt, DSv/m dropped by a factor of 2 as temperature decreased from 1100 to 920 oC. The DSv/m values were combined with anhydrite solubility data and implemented in a

Crystal accumulation and compositional trends in a calc-alkaline batholith: implications for correlation of plutonic and volcanic rocks

NASA Astrophysics Data System (ADS)

Barnes, C. G.; Coint, N.

2013-12-01

The Wooley Creek batholith is a tilted, calc-alkaline intrusive complex in the Klamath Mountain province, California, that can be divided into two main zones: lower (~159.2 × 0.2 Ma) and upper (~158.2 × 0.3 Ma), separated by a central transition zone. The lower zone consists of multiple intrusive units of gabbro through tonalite, with minor mafic synplutonic dikes and intrusive melagabbro and pyroxenite. Major and trace element data plot in two groups: a mafic group that encompasses pyroxenite to diorite, and a tonalitic group. For each group, Mg/Fe in augite was used to determine the approximate composition of equilibrium melt and then major element mass balance was used to calculate proportions of cumulate phases and melt. For the mafic group, no single parental magma can be identified, which is consistent with assembly via many magma batches. However, the most mafic rocks were derived from basaltic andesite magmas and represent 30 to 100% cumulate augite + opx × plagioclase × olivine. Interstitial melt in the tonalitic group was dacitic, and mass balance indicates from 30 to 80% cumulate pyroxenes + plagioclase × accessory apatite and Fe-Ti oxides. The parental magma was probably silicic andesite. The upper zone varies gradationally from structurally low quartz diorite to uppermost granite. Upper zone magmas ';leaked' to form dacitic to rhyodacitic ';roof dikes'. Previous work (Coint et al., Geosphere, in press) showed that the upper zone formed from an approximately homogeneous magma body and that compositional variation was related to upward percolation of melt. Mass balance supports this interpretation and indicates that (1) the parental magmas were andesitic, (2) structurally low rocks are 15 to 65 % cumulate hornblende + plagioclase × pyroxene, and (3) high-level granite and granodiorite are the fractionated products of this accumulation. These results show that the upper zone is a good example of fractional crystallization within a moderate

The Geology and Petrography of Yücebelen and Surrounding Area, Torul-Gümüşhane

NASA Astrophysics Data System (ADS)

Doǧacan, Özcan; Özpınar, Yahya

2013-04-01

The study area is located in the tectono-stratigraphic zone named "Eastern Pontide Zone" from the northeastern part of Turkey. Eastern Pontides were formed by the subduction of Tethys Ocean under the Eurasian plate, during the Early Cretaceous - Late Eocene. Eastern Pontide orogenic zone can be divided in two tectono-stratigraphic subgroups as the northern and southern zones. The study area is located very close to border of these two subgroups but located in northern zone. In this project, the first geological map of the study area at the scale 1:5000 was made. Subsequently, detailed geological maps at the scale 1:2000 were made for the areas rich in ores. In the study area, Upper Cretaceous volcanic rocks consisting of basalts and basaltic andesites take place at the bottom of the rock sequence. Basalts and basaltic andesites with hyaloophitic, vitrophiric and microporphyric texture comprise plagioclase +pyroxene +chlorite +calcite ±epidote ±chalcedony ±opaque minerals. They are overlain by concordant pyroclastic and dacitic-rhyodacitic rocks. Quarts + K-feldispar ±plagioclase? ±biotite ±chlorite ±calcite ±chalcedony minerals are determined as a result of microscope investigation on samples taken from these rocks. These rocks are overlain by sedimentary rocks intercalated with pyroclastic rocks. All those units mentioned above, were intruded by granitoids of supposed Upper Cretaceous-Eocene age. Granitoids that crop out in the area were classified in terms of Q-ANOR parameters as granodiorites (Adile Hamlet occurrence - investigated in detail), diorites (Tuzlak Hill occurrence- eastern-part of study area) and quartz monzodiorites (İstavroma Hill occurrence- northern part of study area). Adile Hamlet granodiorites comprise plagioclase +pyroxene +chlorite +calcite ±quarts ±epidote +opaque minerals. A sequence of quarts +orthoclase +plagioclase ±chlorite ±epidote ±calcite ±opaque minerals have been determined after investigation of the rock samples

Late Holocene Peléan-style eruption at Tacaná volcano, Mexico and Guatemala: past, present, and future hazards

USGS Publications Warehouse

Macías, J. L.; Espíndola, J. M.; Garcia-Palomo, A.; Scott, K.M.; Hughes, S.; Mora, J C.

2000-01-01

Tacaná volcano, located on the border between Mexico and Guatemala, marks the northern extent of the Central American volcanic chain. Composed of three volcanic structures, it is a volcanic complex that has had periodic explosive eruptions for at least the past 40 k.y. The most recent major eruption occurred at the San Antonio volcano, the youngest volcanic edifice forming the complex, about 1950 yr ago. The Peléan style eruption, issued from the southwest part of the dome, and swept a 30° sector with a hot block and ash flow that traveled about 14 km along the Cahoacán ravine. Deposits from this event are well exposed around the town of Mixcun and were therefore given the name of that town, the Mixcun flow deposit. The Mixcun flow deposit is, in the channel facies, a light gray, massive, thick (>10 m), matrix-supported unit with dispersed lithic clasts of gravel to boulder size, divisible in some sections into a variable number of flow units. The overbank facies is represented by a thin (2 and has a minimum estimated volume of 0.12 km3. Basaltic-andesite inclusions (54% SiO2) and various signs of disequilibrium in the mineral assemblage of the two-pyroxene andesitic products (60%–63% SiO2) suggest that magma mixing may have triggered the eruption. Following deposition of the Mixcun flow deposit andesitic to dacitic (62%–64% SiO2) lava flows were extruded and a dacitic dome (64.4% SiO2) at the San Antonio summit formed. Syn-eruptive and posteruptive lahars flooded the main drainages of the Cahoacán and Izapa-Mixcun valleys in the area of the present city of Tapachula (population 250000) and the pre-Hispanic center of Izapa. Three radiocarbon ages date this event between A.D. 25 and 72 (range ±1σ, 38 B.C.–A.D. 216), which correlates with a halt in construction at Izapa (Hato phase of ca. 50 B.C.–A.D. 100), probably due to temporary abandonment of the city caused by lahars. Another similar event would produce extensive damage to the towns (population

A Strongly Calc-alkaline Suite in the Midst of the Tholeiitic Columbia River Basalt Province: Implications for Generating the Calc-alkaline Trend Without Subduction Processes

NASA Astrophysics Data System (ADS)

Steiner, A. R.; Streck, M. J.

2012-12-01

more enriched in highly incompatible LIL while slightly more depleted in HFSE and REE, particularly HREE, relative to TH lavas. Incompatible trace elements range from the mafic to the silicic end as follows [in ppm]: Rb - CA: 11 to 43, TH: 4 to 37; Ba - CA: 550-1124, TH: 408 to 929; Th - CA: 1.2 to 4.0, TH: 1.2 to 3.5; Nb - CA: 6.0 to 16.2, TH: 9.3 to 23.1; Lu - CA: 0.3 to 0.49, TH: 0.3 to 0.63. On the other hand, great similarity among element patterns of CA and TH samples in incompatible element normalization diagrams is consistent with a common mafic component. Our preliminary interpretation is that CA magmas of the SV are generated when basaltic, CRBG-related magmas interact with the continental crust, while TH magmas escaped comparable crustal modifications. The range in compositions from basalt to CA andesite to dacite may thus be attributed to greater amounts of crustal inputs via magma mixing or AFC processes. Trace element concentrations and ratios of SV basalts are largely indistinguishable from those of CRBG lavas and have the greatest commonality with Steens and Imnaha type lavas (e.g. Zr, Ba, Sr, Th, U, Ba/Nb and Ce/Y).

Geology of the Humboldt region and the Iron King mine, Bigbug mining district, Yavapai County, Arizona

USGS Publications Warehouse

Creasey, Saville Cyrus

1951-01-01

The Humboldt region is in central Yavapai County, Arizona. The intersection of the 112? 15' meridian and the 34? 30' N parallel is in the approximate geographical center of the region, and the Iron King mine is about 2000 feet west-northwest of the intersection. Pre-Cambrian rocks form the bedrock in the Humboldt region. Late Cenozoic unconsolidated river wash and valley fill, including some interbedded basalt, locally mantle the pre-Cambrian rocks, especially in the north-central part of the region (Lonesome Valley). The pre-Cambrian rocks consist of five newly defined metavolcanic formations derived from flows and tuff s, and of six intrusive units ranging in composition from granite to gabbro or perhaps more mafic types. Relic bedding-and pillow structures are locally prominent in the metavolcanics; geopetal structures are uncommon, but where present, generally indicate that the top is toward the west, though the evidence is too meager to be conclusive. Low-grade dynamothermal metamorphism altered the metavolcanics and to a lesser extent the intrusive rocks, forming textures, structures, and mineral assemblages characteristic of low temperature and moderate stress. The Texas Gulch formation, which is the easternmost metavolcanic formation, consists of five lithologic units. Arranged in the general order of their appearance from east to west they are meta-andesite breccia, purple slate, metarhyolite tuff, meta-andesite, and green slate. The boundary between the Texas Gulch formation and the Iron King meta-andesite is apparently gradational. The Iron King meta-andesite consists of three meta-andesite tuff units, two meta-andesite flow units and one metarhyolite tuff and conglomerate unit. The assemblage chlorite-albite-epitode with or without quartz is dominant in the meta-andesites. Mafic intrusive rocks, which may be approximately contemporaneous with metamorphism, may explain the presence of actinolitic hornblende in the central part of the formation. Toward

Installation Restoration Program Records Search for Luke Air Force Base, Arizona.

DTIC Science & Technology

1982-06-01

These soils were formed in recent alluvium derived from a wide mixture of rock type, including andesite, basalt , schist, rhyolite, and granite-gneiss...were originally derived from granite, granite- gneiss, schist, andesite, basalt , and limestone. Permeability is moderate (same as Gilman series...alluvium is the crystalline rock, granite, granite-gneiss, anyolite, schist, andesite, basalt , and limestone, which eroded from the mountains, and were

Slab melting and the origin of gold in Au and Au-Cu deposits: geochemical clues from recent adakites.

NASA Astrophysics Data System (ADS)

Polve, M.; Maury, R.; Joron, J. L.

2003-04-01

Understanding the genetic processes responsible for the common occurrence of Au and Au-Cu deposits in subduction environments is a fairly "hot" question nowadays, as it is clear that most subduction-related magmatic rocks are barren. Studies of space and time relationships between magmatic intrusions, hydrothermal episodes and Au deposits have shown that, very often, Au deposits are associated with adakitic intrusions (Thieblemont et al, 1997, Sajona and Maury, 1998). Adakites are here understood as being generated by melting of the subducting oceanic crust. This study aims to check wether or not magmas derived from melted oceanic crust do contain significantly more Au than regular calc-alkaline magmas by measuring directly Au concentrations in fresh (and barren) adakites and equivalent calc-alkaline andesites. There is a lack of reliable data on Au content in unaltered adakites and andesites, because Au analyses are generally done on hydrothermalized rocks in connection with Au deposits and also because old measurements may give overestimated Au contents, due to technical limitations. Therefore we compiled recent literature data on gold contents of fresh calc-alkaline rocks, and measured Au on a selection of 40 well studied and dated adakites from different localities (Philippines, Baja California). Analyses have been performed either by INAA or by ICP-MS after Au extraction with aqua regia, following the method described by Terashima (1988). Preliminary results show that, for equivalent Si02 contents, adakites are systematically enriched in Au compared to regular dacites, even if regional trends also exist. Moreover, Au seems to behave as an incompatible element in adakitic magmas, whereas in calc-alkaline dacites it is controlled by sulfide crystallization. Our data suggest that, not excluding any other processes related to the hydrothermal phase in the deposit generation, adakites may indeed represent the source of Au, a possible explanation for the adakite

Rare earth elements geochemistry in springs from Taftan geothermal area SE Iran

NASA Astrophysics Data System (ADS)

Shakeri, Ata; Ghoreyshinia, Sayedkazem; Mehrabi, Behzad; Delavari, Morteza

2015-10-01

Concentrations of rare earth elements (REEs) were determined in springs and andesitic-dacitic rocks of Taftan geothermal field. Hydrochemical results of major ions indicate that thermal springs are Na-SO4-Cl and Ca-SO4-Cl types. Concentrations of REEs are in ranges of 10- 4 to 1.2 and 49 to 62 times of chondrite for springwater and rock samples, respectively. The thermal (STS and TTS) and the cold (APS) springs with low pH values exhibit a very high REE contents (0.64 to 3.15 mg/l). Saturation index indicates that Fe and Al phases can control dissolved REE concentration in FTS and PF cold springs. The speciation of REE complexes indicates dominant presence of LnSO4+ and free ion in the Taftan thermal springs. In APS cold spring with pH 4, fluoride complexes are dominate over the free ion and sulfate species, while in PF and FTS cold springs with pH 6.4 and 7, respectively, carbonate complexes (LnCO3+) are predominant species. Chondrite-normalized pattern for the low-pH waters show very distinctive gull-wing patterns, characteristic feature of acid-sulfate geothermal systems, and are similar to those of the host rocks. Chemical characteristics of rare earth elements in spring and volcanic rock samples indicate that REEs are originated from the andesitic-dacitic host rocks. Whole-rock-normalized REE patterns and petrographic evidences show that rare earth elements leached mainly from marginal alteration of minerals and matrix decomposition in volcanic rocks. In chondrite-normalized REE patterns, significant negative Eu anomaly in the cold springs compare to the thermal and acidic springs indicates that alteration of plagioclase is more intense in the later, corresponding to increasing in temperature and acidic state of reactant water.

Pyroclastic deposits of the Mount Edgecumbe volcanic field, southeast Alaska: eruptions of a stratified magma chamber

USGS Publications Warehouse

Riehle, J.R.; Champion, D.E.; Brew, D.A.; Lanphere, M.A.

1992-01-01

The Mount Edgecumbe volcanic field in southeastern Alaska consists of 5-6 km3 (DRE) of postglacial pyroclasts that overlie Pleistocene lavas. All eleven pyroclast vents align with the long axis of the field, implying that the pyroclast magma conduits followed a crustal fissure. Most of these vents had previously erupted lavas that are compositionally similar to the pyroclasts, so a persistent magma system (chamber) had likely evolved by the onset of the pyroclastic eruptions. The pyroclastic sequence was deposited in about a millennium and is remarkable for a wide range of upward-increasing silica contents (51-72% SiO2), which is consistent with rise of coexisting magmas at different rates governed by their viscosity. Basaltic and andesitic lava flows have erupted throughout the lifetime of the field. Rhyolite erupted late; we infer that it formed early but was hindered from rising by its high viscosity. Most of the magmas-and all siliceous ones-erupted from vents on the central fissure. Basalt has not erupted from the center of the field during at least the latter part of its lifetime. Thus the field may illustrate basalt underplating: heat and mass flux are concentrated at the center of a stratified magma chamber in which a cap of siliceous melt blocks the rise of basalt. Major-element, strontium isotope, and mineral compositions of unaltered pyroclasts are broadly similar to those of older lavas of similar SiO2 content. Slightly fewer phenocrysts, inherited grains, and trace amphibole in pyroclastic magmas may be due simply to faster rise and less undercooling and degassing before eruption relative to the lavas. Dacite occurs only in the youngest deposits; the magma formed by mixing of andesitic and rhyolitic magmas erupted shortly before by the dacitic vents. ?? 1992.

Eocene-Miocene igneous activity in Provence (SE France): 40Ar/39Ar data, geochemical-petrological constraints and geodynamic implications

NASA Astrophysics Data System (ADS)

Lustrino, Michele; Fedele, Lorenzo; Agostini, Samuele; Di Vincenzo, Gianfranco; Morra, Vincenzo

2017-09-01

Provence (SE France) was affected by two main phases of sporadic igneous activity during the Cenozoic. New 40Ar/39Ar laser step-heating data constrain the beginning of the oldest phase to late Eocene (40.82 ± 0.73 Ma), with activity present until early Miocene ( 20 Ma). The products are mainly andesites, microdiorites, dacites and basaltic andesites mostly emplaced in the Agay-Estérel area. Major- and trace-element constraints, together with Srsbnd Ndsbnd Pb isotopic ratios suggest derivation from a sub-continental lithosphere mantle source variably modified by subduction-related metasomatic processes. The compositions of these rocks overlap those of nearly coeval (emplaced 38-15 Ma) late Eocene-middle Miocene magmatism of Sardinia. The genesis of dacitic rocks cannot be accounted for by simple fractional crystallization alone, and may require interaction of evolved melts with lower crustal lithologies. The youngest phase of igneous activity comprises basaltic volcanic rocks with mildly sodic alkaline affinity emplaced in the Toulon area 10 Myr after the end of the previous subduction-related phase. These rocks show geochemical and isotopic characteristics akin to magmas emplaced in intraplate tectonic settings, indicating a sub-lithospheric HiMu + EM-II mantle source for the magmas, melting approximately in the spinel/garnet-lherzolite transition zone. New 40Ar/39Ar laser step-heating ages place the beginning of the volcanic activity in the late Miocene-Pliocene (5.57 ± 0.09 Ma). The emplacement of "anorogenic" igneous rocks a few Myr after rocks of orogenic character is a common feature in the Cenozoic districts of the Central-Western Mediterranean area. The origin of such "anorogenic" rocks can be explained with the activation of different mantle sources not directly modified by subduction-related metasomatic processes, possibly located in the sub-lithospheric mantle, and thus unrelated to the shallower lithospheric mantle source of the "orogenic" magmatism.

Volcán Popocatépetl, Mexico. Petrology, magma mixing, and immediate sources of volatiles for the 1994- Present eruption

USGS Publications Warehouse

Witter, J.B.; Kress, V.C.; Newhall, C.G.

2005-01-01

Volcán Popocatépetl has been the site of voluminous degassing accompanied by minor eruptive activity from late 1994 until the time of writing (August 2002). This contribution presents petrological investigations of magma erupted in 1997 and 1998, including major-element and volatile (S, Cl, F, and H2O) data from glass inclusions and matrix glasses. Magma erupted from Popocatépetl is a mixture of dacite (65 wt % SiO2, two-pyroxenes + plagioclase + Fe–Ti oxides + apatite, ∼3 wt % H2O, P = 1·5 kbar, fO2 = ΔNNO + 0·5 log units) and basaltic andesite (53 wt % SiO2, olivine + two-pyroxenes, ∼3 wt % H2O, P = 1–4 kbar). Magma mixed at 4–6 km depth in proportions between 45:55 and 85:15 wt % silicic:mafic magma. The pre-eruptive volatile content of the basaltic andesite is 1980 ppm S, 1060 ppm Cl, 950 ppm F, and 3·3 wt % H2O. The pre-eruptive volatile content of the dacite is 130 ± 50 ppm S, 880 ± 70 ppm Cl, 570 ± 100 ppm F, and 2·9 ± 0·2 wt % H2O. Degassing from 0·031 km3 of erupted magma accounts for only 0·7 wt % of the observed SO2 emission. Circulation of magma in the volcanic conduit in the presence of a modest bubble phase is a possible mechanism to explain the high rates of degassing and limited magma production at Popocatépetl.

Volcán Quizapu, Chilean Andes

USGS Publications Warehouse

Hildreth, Wes; Drake, Robert E.

1992-01-01

Quizapu is a flank vent of the basalt-to-rhyodacite Holocene stratocone, Cerro Azul, and lies at the focus of a complex Quaternary volcanic field on the Andean volcanic front. The Quizapu vent originated in 1846 when 5 km3 of hornblende-dacite magma erupted effusively with little accompanying tephra. Between ∼ 1907 and 1932, phreatic and strombolian activity reamed out a deep crater, from which 4 km3 of dacite magma identical to that of 1846 fed the great plinian event of 10–11 April 1932. Although a total of >9 km3 of magma was thus released in 86 years, there is no discernible subsidence. As the pre-plinian crater was lined by massive lavas, 1932 enlargement was limited and the total plinian deposit contains only ∼ 0.4 wt % lithics. Areas of 5-cm and 1-cm isopachs for compacted 1932 fallout are about half of those estimated in the 1930's, yielding a revised ejecta volume of ∼9.5 km3. A strong inflection near the 10-cm isopach (downwind ∼110 km) on a plot of log Thickness vs Area1/2 reflects slow settling of fine plinian ash — not of coignimbrite ash, as the volume of pyroclastic flows was trivial (<0.01 km3). About 17 vol.% of the fallout lies beyond the 1-cm isopach, and ∼ 82 wt% of the ejecta are finer than 1 mm. A least 18 hours of steady plinian activity produced an exceptionally uniform fall deposit. Observed column height (27–30 km) and average mass eruption rate (1.5x108 kg/s) compare well with values for height and peak intensity calculated from published eruption models. The progressive “aeolian fractionation” of downwind ash (for which Quizapu is widely cited) is complicated by the large compositional range of 1932 juvenile pumice (52–70% SiO2). The eruption began with andesitic scoria and ended with basaltic scoria, but >95% of the ejecta are dacitic pumice (67–68% SiO2); minor andesitic scoria and frothier rhyodacite pumice (70% SiO2) accompanied the dominant dacite. Phenocrysts (pl>hb∼opx>mt>ilm∼cpx) are similar in both

Quantifying weathering advance rates in basaltic andesite rinds with uranium-series isotopes: a case study from Guadeloupe

NASA Astrophysics Data System (ADS)

Ma, L.; Chabaux, F. J.; Pelt, E.; Granet, M.; Sak, P. B.; Gaillardet, J.; Brantley, S. L.

2010-12-01

Weathering of basaltic rocks plays an important role in many Earth surface processes. It is thus of great interest to quantify their weathering rates. Because of their well-documented behaviors during water-rock interaction, U-series isotopes have been shown to have utility as a potential chronometer to constrain the formation rates of weathering rinds developed on fresh basaltic rocks. In this study, U-series isotopes and trace element concentrations were analyzed in a basaltic andesite weathering rind collected from the Bras David watershed, Guadeloupe. From the clast, core and rind samples were obtained by drilling along a 63.8 mm linear profile across a low curvature segment of the core-rind boundary. Trace element concentrations reveal: significant loss of REE, Y, Rb, Sr, and Ba in the weathering rind; conservative behaviors of Ti and Th; and external addition of U into the rind during clast weathering. Measured (234U/238U) activity ratios of the rind samples are much higher than the core samples and show excess 234U. Measured (238U/232Th) and (230Th/232Th) activity ratios of the core and rind samples increase gradually from the core into the weathering rind. The observed depletion profiles for the trace elements in the clast suggest that the earliest chemical reaction that creates significant porosity is dissolution of plagioclase, consistent with the previous study [Sak et al., 2010, CG, in press]. The porosity growth within the rind allows for an influx of soil solution that carries dissolved U with (234U/238U) activity ratios >1 into the clast. The deposition of U in the rind is most likely associated with precipication of secondary minerals during clast weathering. Such a continuous U addition is responsible for the observed gradual increase of (238U/232Th) activity ratios in the rind. Subsequent production of 230Th in the rind over time from the decay of excess 234U accounts for the observed continuous increase of (230Th/232Th) activity ratios. The U

Origin of the ca. 50 Ma Linzizong shoshonitic volcanic rocks in the eastern Gangdese arc, southern Tibet

NASA Astrophysics Data System (ADS)

Liu, An-Lin; Wang, Qing; Zhu, Di-Cheng; Zhao, Zhi-Dan; Liu, Sheng-Ao; Wang, Rui; Dai, Jin-Gen; Zheng, Yuan-Chuan; Zhang, Liang-Liang

2018-04-01

The origin of the Eocene shoshonitic rocks within the upper part of the extensive Linzizong volcanic succession (i.e., the Pana Formation) in the Gangdese arc, southern Tibet remains unclear, inhibiting the detailed investigations on the crust-mantle interaction and mantle dynamics that operate the generation of the coeval magmatic flare-up in the arc. We report mineral composition, zircon U-Pb age and zircon Hf isotope, whole-rock element and Sr-Nd-Hf isotope data for the Pana Formation volcanic rocks from Pangduo, eastern Gangdese arc in southern Tibet. The Pana volcanic rocks from Pangduo include basalts, basaltic andesites, and dacites. SIMS and LA-ICPMS zircon U-Pb dating indicates that the Pangduo dacites were erupted at 50 ± 1 Ma, representing the volcanic equivalent of the coeval Gangdese Batholith that define a magmatic flare-up at 51 ± 1 Ma. The Pangduo volcanic rocks are exclusively shoshonitic, differing from typical subduction-related calc-alkaline volcanic rocks. The basalts have positive whole-rock ƐNd(t) (+1.7) and ƐHf(t) (+3.8) with high Zr abundances (121-169 ppm) and Zr/Y ratios (4.3-5.2), most likely derived from the partial melting of an enriched garnet-bearing lithospheric mantle that was metasomatized by subduction-related components with input from asthenosphere. Compared to the basalts, similar trace elemental patterns and decreased whole-rock ƐNd(t) (-3.5 to -3.3) and ƐHf(t) (-2.5 to -1.6) of the basaltic andesites can be attributed to the input of the ancient basement-derived material of the central Lhasa subterrane into the basaltic magmas. The coherent whole-rock Sr-Nd-Hf isotopic compositions ((87Sr/86Sr)i = 0.7064-0.7069, ƐNd(t) = -6.0 to -5.2, ƐHf(t) = -5.6 to -5.0) and varying zircon ƐHf(t) (-6.0 to +4.1) of the dacites can be interpreted by the partial melting of a hybrid lower crust source (juvenile and ancient lower crust) with incorporation of basement-derived components. Calculations of zircon-Ti temperature and whole

Geology of the Eymir iron mine, Edremit, Turkey

USGS Publications Warehouse

Jacobson, Herbert Samuel; Turet, Erdogan

1972-01-01

The Eymir mine near Edremit on Turkey's Aegean coast (long 27?30'E.,1at 39?36'N.) was investigated as part of the Maden Tetkik ve Arama Enstitutsu (MTA)-U. S. Geological Survey (USGS) mineral exploration and training project, for the purpose of increasing the known mineral reserves. Geologic mapping of the mine area indicates that hematite is restricted to argillized, silicified, and pyritized dacite and possibly andesite. Hematite is present as massive replacements, impregnations, disseminations, and fracture fillings. Most of the upper part of the iron deposit consists of a breccia composed mostly of silicifiled dacite fragments in a hematite matrix. The iron deposit was apparently formed in three steps: 1. Argillation, silicification, and pyritization of the andesitic lava and dacite units as a result of a regional intrusion. 2. Intrusion of the Dere Oren dacite stock, with associated faulting, fracturing, and breccia formation at the surface. 3. Deposition of hematite by oxidation of pyrite, and transfer of iron via fractures and faults by hydrothermal or meteoric fluids. The Eymir iron deposit is a blanketlike deposit on the crest of the Sivritepe-Eymir ridge. It is 1300 meters long, 80 to 450 meters wide, and has an average thickness of 18.6 meters. Drill holes in the deposit show the iron content to range from 32.0 to 57.6 percent, and to average 46.5 percent. Most of the gangue is silica, and an arsenic impurity averaging 0.39 percent is present. Most of the deposit cannot be utilized as iron ore because of low iron content, high silica content, and high arsenic content. Ore-dressing tests have shown that it is feasible to concentrate the low-grade material, producing a concentrate having increased iron content and reduced silica content. Tests have shown also that the arsenic content of the ore can be reduced substantially by sintering. Further tests and economic feasibility studies are necessary to determine whether an economic marketable iron ore can be

Paleointensity study of the historical andesitic lava flows: LTD-DHT Shaw and Thellier paleointensities from the Sakurajima 1914 and 1946 lavas in Japan

NASA Astrophysics Data System (ADS)

Yamamoto, Y.; Hoshi, H.

2005-12-01

Correct determination of absolute paleointensities is essential to investigate past geomagnetic field. There are two types of methods to obtain the paleointensities: the Thellier-type and Shaw-type methods. Many paleomagnetists have so far regarded the former method as reliable. However, there are increasing evidences that it is sometimes not robust for basaltic lavas resulting in systematic high paleointensities (e.g. Calvo et al., 2002; Yamamoto et al., 2003). Alternatively, the double heating technique of the Shaw method combined with low temperature demagnetization (LTD-DHT Shaw method; Tsunakawa et al., 1997; Yamamoto et al., 2003), a lately developed paleointensity technique in Japan, can yield reliable answers even from such basaltic samples (e.g. Yamamoto et al., 2003; Mochizuki et al., 2004; Oishi et al., 2005). In the Japanese archipelago, there are not only basaltic lavas but also andesitic lavas. They are important candidates of the absolute paleointensity determination in Japan. For a case study, we sampled oriented paleomagnetic cores from three sites of the Sakurajima 1914 (TS01 and TS02) and 1946 (SW01) lavas in Japan. Several rock magnetic experiments revealed that main magnetic carriers of the present samples are titanomagnetites with Curie temperatures of about 300-550 C, and that high temperature oxidation progresses in the order of SW01, TS01 and TS02. The LTD-DHT Shaw and Coe-Thellier experiments were conducted on 72 and 63 specimens, respectively. They gave 64 and 60 successful determinations. If the results are normalized by expected field intensities calculated from IGRF-9 (Macmillan et al., 2003) and grouped into LTD-DHT Shaw and Thellier datasets, their averages and standard deviations (1 sigma) resulted in 0.98+/-0.11 (LTD-DHT Shaw) and 1.13+/-0.13 (Thellier). Considering the standard deviations, we can say that both paleointensity methods recovered correct geomagnetic field. However, it is apparent that the LTD-DHT Shaw method has

Voluminous arc dacites as amphibole reaction-boundary liquids

NASA Astrophysics Data System (ADS)

Blatter, Dawnika L.; Sisson, Thomas W.; Hankins, W. Ben

2017-05-01

Dacites dominate the large-volume, explosive eruptions in magmatic arcs, and compositionally similar granodiorites and tonalites constitute the bulk of convergent margin batholiths. Shallow, pre-eruptive storage conditions are well known for many dacitic arc magmas through melt inclusions, Fe-Ti oxides, and experiments, but their potential origins deeper in the crust are not well determined. Accordingly, we report experimental results identifying the P-T-H2O conditions under which hydrous dacitic liquid may segregate from hornblende (hbl)-gabbroic sources either during crystallization-differentiation or partial melting. Two compositions were investigated: (1) MSH-Yn-1 dacite (SiO2: 65 wt%) from Mount St. Helens' voluminous Yn tephra and (2) MSH-Yn-1 + 10% cpx to force saturation with cpx and map a portion of the cpx + melt = hbl peritectic reaction boundary. H2O-undersaturated (3, 6, and 9 wt% H2O) piston cylinder experiments were conducted at pressures, temperatures, and fO2 appropriate for the middle to lower arc crust (400, 700, and 900 MPa, 825-1100 °C, and the Re-ReO2 buffer ≈ Ni-NiO + 2). Results for MSH-Yn-1 indicate near-liquidus equilibrium with a cpx-free hbl-gabbro residue (hbl, plg, magnetite, ± opx, and ilmeno-hematite) with 6-7 wt% dissolved H2O, 925 °C, and 700-900 MPa. Opx disappears down-temperature consistent with the reaction opx + melt = hbl. Cpx-added phase relations are similar in that once 10% cpx crystallizes, multiple saturation is attained with cpx, hbl, and plg, +/- opx, at 6-7 wt% dissolved H2O, 940 °C, and 700-900 MPa. Plg-hbl-cpx saturated liquids diverge from plg-hbl-opx saturated liquids, consistent with the MSH-Yn-1 dacite marking a liquid composition along a peritectic distributary reaction boundary where hbl appears down-temperature as opx + cpx are consumed. The abundance of saturating phases along this distributary peritectic (liquid + hbl + opx + cpx + plg + oxides) reduces the variance, so liquids are restricted to

Magma genesis of the acidic volcanism in the intra-arc rift zone of the Izu volcanic arc, Japan

NASA Astrophysics Data System (ADS)

Haraguchi, S.; Tokuyama, H.; Ishii, T.

2010-12-01

The Izu volcanic arc extends over 550 km from the Izu Peninsula, Japan, to the Nishinoshima Trough or Sofugan tectonic line. It is the northernmost segment of the Izu-Bonin-Mariana arc system, which is located at the eastern side of the Philippine Sea Plate. The recent magmatism of the Izu arc is bimodal and characterized by basalt and rhyolite (e.g. Tamura and Tatsumi 2002). In the southern Izu arc, volcanic front from the Aogashima to the Torishima islands is characterized by submarine calderas and acidic volcanisms. The intra-arc rifting, characterized by back-arc depressions, small volcanic knolls and ridges, is active in this region. Volcanic rocks were obtained in 1995 during a research cruise of the R/V MOANA WAVE (Hawaii University, cruise MW9507). Geochemical variation of volcanic rocks and magma genesis was studied by Hochstaedter et al. (2000, 2001), Machida et al (2008), etc. These studies focused magma and mantle dynamics of basaltic volcanism in the wedge mantle. Acidic volcanic rocks were also dredged during the curies MW9507. However, studies of these acidic volcanics were rare. Herein, we present petrographical and chemical analyses of these acidic rocks, and compare these results with those of other acidic rocks in the Izu arc and lab experiments, and propose a model of magma genesis in a context of acidic volcanism. Dredge sites by the cruise MW9507 are 120, and about 50 sites are in the rift zone. Recovered rocks are dominated by the bimodal assemblage of basalt-basaltic andesite and dacite-rhyolite. The most abundant phase is olivine basalt, less than 50 wt% SiO2. Andesites are minor in volume and compositional gap from 56 to 65 wt% SiO2 exists. The across-arc variation of the HFSE contents and ratios, such as Zr/Y and Nb/Zr of rhyolites exhibit depleted in the volcanic front side and enriched in reararc side. This characteristic is similar to basaltic volcanism pointed out by Hochstaedter et al (2000). The petrographical features of rhyolites

Postglacial eruptive history and geochemistry of Semisopochnoi volcano, western Aleutian Islands, Alaska

USGS Publications Warehouse

Coombs, Michelle L.; Larsen, Jessica F.; Neal, Christina A.

2018-02-14

Semisopochnoi Island, located in the Rat Islands group of the western Aleutian Islands and Aleutian volcanic arc, is a roughly circular island composed of scattered volcanic vents, the prominent caldera of Semisopochnoi volcano, and older, ancestral volcanic rocks. The oldest rocks on the island are gently radially dipping lavas that are the remnants of a shield volcano and of Ragged Top, which is an eroded stratocone southeast of the current caldera. None of these oldest rocks have been dated, but they all are likely Pleistocene in age. Anvil Peak, to the caldera’s north, has the morphology of a young stratocone and is latest Pleistocene to early Holocene in age. The oldest recognized Holocene deposits are those of the caldera-forming eruption, which produced the 7- by 6-km caldera in the center of the island, left nonwelded ignimbrite in valleys below the edifice, and left welded ignimbrite high on its flanks. The caldera-forming eruption produced rocks showing a range of intermediate whole-rock compositions throughout the eruption sequence, although a majority of clasts analyzed form a fairly tight cluster on SiO2-variation diagrams at 62.9 to 63.4 weight percent SiO2. This clustering of compositions at about 63 weight percent SiO2 includes black, dense, obsidian-like clasts, as well as tan, variably oxidized, highly inflated pumice clasts. The best estimate for the timing of the eruption is from a soil dated at 6,920±60 14C years before present underlying a thin facies of the ignimbrite deposit on the island’s north coast. Shortly after the caldera-forming eruption, two scoria cones on the northwest flank of the volcano outside the caldera, Ringworm crater and Threequarter Cone, simultaneously erupted small volumes of andesite.The oldest intracaldera lavas, on the floor of the caldera, are andesitic to dacitic, but are mostly covered by younger lavas and tephras. These intracaldera lavas include the basaltic andesites of small Windy cone, as well as the

Mafic enclaves record syn-eruptive basalt intrusion and mixing

NASA Astrophysics Data System (ADS)

Plail, Melissa; Edmonds, Marie; Woods, Andrew W.; Barclay, Jenni; Humphreys, Madeleine C. S.; Herd, Richard A.; Christopher, Thomas

2018-02-01

Mafic enclaves hosted by andesite erupted at the Soufrière Hills Volcano between 1995 and 2010 yield insights into syn-eruptive mafic underplating of an andesite magma reservoir, magma mixing and its role in sustaining eruptions that may be widely applicable in volcanic arc settings. The mafic enclaves range in composition from basalt to andesite and are generated from a hybrid thermal boundary layer at the interface between the two magmas, where the basalt quenches against the cooler andesite, and the two magmas mix. We show, using an analytical model, that the enclaves are generated when the hybrid layer, just a few tens of centimetres thick, becomes buoyant and forms plumes which rise up into the andesite. Mafic enclave geochemistry suggests that vapour-saturated basalt was underplated quasi-continuously throughout the first three eruptive phases of the eruption (the end member basalt became more Mg and V-rich over time). The andesite erupted during the final phases of the eruption contained more abundant and larger enclaves, and the enclaves were more extensively hybridised with the andesite, suggesting that at some time during the final few years of the eruption, the intrusion of mafic magma at depth ceased, allowing the hybrid layer to reach a greater thickness, generating larger mafic enclaves. The temporal trends in mafic enclave composition and abundance suggests that basalt recharge and underplating sustained the eruption by the transfer of heat and volatiles across the interface and when the recharge ceased, the eruption waned. Our study has important implications for the petrological monitoring of long-lived arc eruptions.

The eruptive chronology of the Ampato-Sabancaya volcanic complex (Southern Peru)

NASA Astrophysics Data System (ADS)

Samaniego, Pablo; Rivera, Marco; Mariño, Jersy; Guillou, Hervé; Liorzou, Céline; Zerathe, Swann; Delgado, Rosmery; Valderrama, Patricio; Scao, Vincent

2016-09-01

We have reconstructed the eruptive chronology of the Ampato-Sabancaya volcanic complex (Southern Peru) on the basis of extensive fieldwork, and a large dataset of geochronological (40K-40Ar, 14C and 3He) and geochemical (major and trace element) data. This volcanic complex is composed of two successive edifices that have experienced discontinuous volcanic activity from Middle Pleistocene to Holocene times. The Ampato compound volcano consists of a basal edifice constructed over at least two cone-building stages dated at 450-400 ka and 230-200 ka. After a period of quiescence, the Ampato Upper edifice was constructed firstly during an effusive stage (80-70 ka), and then by the formation of three successive peaks: the Northern, Southern (40-20 ka) and Central cones (20-10 ka). The Southern peak, which is the biggest, experienced large explosive phases, resulting in deposits such as the Corinta plinian fallout. During the Holocene, eruptive activity migrated to the NE and constructed the mostly effusive Sabancaya edifice. This cone comprised many andesitic and dacitic blocky lava flows and a young terminal cone, mostly composed of pyroclastic material. Most samples from the Ampato-Sabancaya define a broad high-K magmatic trend composed of andesites and dacites with a mineral assemblage of plagioclase, amphibole, biotite, ortho- and clino-pyroxene, and Fe-Ti oxides. A secondary trend also exists, corresponding to rare dacitic explosive eruptions (i.e. Corinta fallout and flow deposits). Both magmatic trends are derived by fractional crystallisation involving an amphibole-rich cumulate with variable amounts of upper crustal assimilation. A marked change in the overall eruptive rate has been identified between Ampato ( 0.1 km3/ka) and Sabancaya (0.6-1.7 km3/ka). This abrupt change demonstrates that eruptive rates have not been homogeneous throughout the volcano's history. Based on tephrochronologic studies, the Late Holocene Sabancaya activity is characterised by strong

The Fish Canyon magma body, San Juan volcanic field, Colorado: Rejuvenation and eruption of an upper-crustal batholith

USGS Publications Warehouse

Bachmann, Olivier; Dungan, M.A.; Lipman, P.W.

2002-01-01

More than 5000 km3 of nearly compositionally homogeneous crystalrich dacite (~68 wt % SiO2: ~45% Pl + Kfs + Qtz + Hbl + Bt + Spn + Mag + Ilm + Ap + Zrn + Po) erupted from the Fish Canyon magma body during three phases: (1) the pre-caldera Pagosa Peak Dacite (an unusual poorly fragmented pyroclastic deposit, ~ 200 km3); (2) the syn-collapse Fish Canyon Tuff (one of the largest known ignimbrites, ~ 5000 km3); (3) the post-collapse Nutras Creek Dacite (a volumetrically minor lava). The late evolution of the Fish Canyon magma is characterized by rejuvenation of a near-solidus upper-crustal intrusive body (mainly crystal mush) of batholithic dimensions. The necessary thermal input was supplied by a shallow intrusion of more mafic magma represented at the surface by sparse andesitic enclaves in late-erupted Fish Canyon Tuff and by the post-caldera Huerto Andesite. The solidified margins of this intrusion are represented by holocrystalline xenoliths with Fish Canyon mineralogy and mineral chemistry and widely dispersed partially remelted polymineralic aggregates, but dehydration melting was not an important mechanism in the rejuvenation of the Fish Canyon magma. Underlying mafic magma may have evolved H2O-F-S-Cl-rich fluids that fluxed melting in the overlying crystal mush. Manifestations of the late up-temperature magma evolution are: (1) resorbed quartz, as well as feldspars displaying a wide spectrum of textures indicative of both resorption and growth, including Rapakivi textures and reverse growth zoning (An27-28 to An32-33) at the margins of many plagioclase phenocrysts; (2) high Sr, Ba, and Eu contents in the high-SiO2 rhyolite matrix glass, which are inconsistent with extreme fractional crystallization of feldspar; (3) oscillatory and reverse growth zoning toward the margins of many euhedral hornblende phenocrysts (rimward increases from ~5??5-6 to 7??7-8??5 wt % Al2O3). Homogeneity in magma composition at the chamber-wide scale, contrasting with extreme textural

Deducing the magma chamber processes of middle Eocene volcanics, Sivas and Tokat regions; NE Turkey: Insights from clinopyroxene chemistry

NASA Astrophysics Data System (ADS)

Göçmengil, Gönenç; Karacık, Zekiye; Genç, Ş. Can; Prelevic, Dejan

2016-04-01

Middle Eocene Tokat and Sivas volcanic successions occur within the İzmir-Ankara-Erzincan suture zone. Different models are suggested for the development of the middle Eocene volcanism such as post-collisional, delamination and slab-breakoff models as well as the arc magmatism. In both areas, volcanic units cover all the basement units with a regional disconformity and comprise lavas spanning a compositional range from mainly basalt-basaltic andesite to a lesser amount trachyte. Here, we report mineral chemistry of different basaltic lavas through transect from northern continent (Tokat region, Pontides) to southern continent (Sivas region, Kırşehir block) to deduce the characteristics of the magma chamber processes which are active during the middle Eocene. Basaltic lavas include olivine bearing basalts (Ol-basalt: ± olivine + clinopyroxene + plagioclase); amphibole bearing basaltic andesite (Amp-basaltic andesite: amphibole + clinopyroxene + plagioclase ± biotite) and pyroxene bearing basaltic andesite (Px-basaltic andesite: clinopyroxene + plagioclase). Microlitic, glomeroporphyric and pilotaxitic texture are common. Clinopyroxene phenocrystals (macro ≥ 750 μm and micro ≤300 μm) are common in all three lava series which are investigated by transecting core to rim compositional profiles. They are generally augite and diopside; euhedral to subhedral in shape with oscillatory, normal and reverse zoning patterns. Also, all clinopyroxene phenocrystals are marked by moderately high Mg# (for Ol-basalt: 67-91; avg. 80; Amp-basaltic andesite: 76-83, avg: 80; Px -basaltic andesite 68-95, avg: 81). In Ol-basalt, clinopyroxene phenocrystals show normal zonation (high Mg# cores and low Mg# rims). In Amp-basaltic andesite, clinopyroxenes are generally homogenous in composition with minor variation of Mg# towards the rims. On the contrary, in Px-basaltic andesite, clinopyroxene macro phenocrystals show reverse zonation with the core with low Mg# and the rims with

Paleogene volcanism in Central Afghanistan: Possible far-field effect of the India-Eurasia collision

NASA Astrophysics Data System (ADS)

Motuza, Gediminas; Šliaupa, Saulius

2017-10-01

A volcanic-sedimentary succession of Paleogene age is exposed in isolated patches at the southern margin of the Tajik block in the Ghor province of Central Afghanistan. The volcanic rocks range from basalts and andesites to dacites, including adakites. They are intercalated with sedimentary rocks deposited in shallow marine environments, dated biostratigraphically as Paleocene-Eocene. This age corresponds to the age of the Asyābēd andesites located in the western Ghor province estimated by the 40Ar/39Ar method as 54 Ma. The magmatism post-dates the Cimmerian collision between the Tajik block (including the Band-e-Bayan block) and the Farah Rod block located to the south. While the investigated volcanic rocks apparently bear geochemical signatures typical to an active continental margin environment, it is presumed that the magmatism was related to rifting processes most likely initiated by far-field tectonics caused by the terminal collision of the Indian plate with Eurasia (Najman et al., 2017). This event led to the dextral movement of the Farah Rod block, particularly along Hari Rod (Herat) fault system, resulting in the development of a transtensional regime in the proximal southern margin of the Tajik block and giving rise to a rift basin where marine sediments were interbedded with pillow lavas intruded by sheeted dyke series.

Hydrogeological Modelling of Some Geothermal Waters of Ivrindi, Havran and Gönen in the Province Capital of Balikesir, Western Anatolia, Turkey

NASA Astrophysics Data System (ADS)

Özgür, Nevzat; Ugurlu, Zehra; Memis, Ümit; Aydemir, Eda

2017-12-01

In this study, hydrogeological, hydrogeochemical and isotope geochemical features of Havran, Gönen and Ivrindi within the province capital of Balıkesir, Turkey were investigated in detail. The Early Triassic Karakaya formation in the study area of Havran forms the oldest rocks consisting of spilitic basalts, diabases, gabbros, mudstones, cherts and radiolarites. There are limestone blocks in this formation with intercalations with sandstones and with feldspar contents, quartzite, conglomerates and siltstones. Oligocene to Miocene granodiorite intrusions were generated in association with intensively volcanic events in the area. Between Upper Oligocene and Early Miocene, andesitic and dacitic pyroclastic rocks cropped out due to intensively volcanism. Later, conglomerates, sandstones, claystones, marls and limestones as lacustrine sediments formed from Middle to Upper Miocene in the study area. In the study area of Gönen, the Lower Triassic Karakaya formation consists of basalts, diabases, gabbros, mudstones, cherts and radiolarites and forms the basement rocks overlain by Upper Jurassic to Lower Cretaceous sandy limestones. Upper and Middle Miocene volcanics which can be considered intensive Biga Peninsula volcanos outcrop in the area. These andesitic lava flows are of black, gray and red color with intensive fissures. Neogene lacustrine sediments consist of conglomerates, sandstones, marl, claystone and clayey limestones. Upper Miocene to Pliocene rhyolitic pyroclastics and dacitic lava flows are the volcanic rocks which are overlain by Pliocene conglomerates, sandstones and claystones. In the study area of Ivrindi, the Çaldağ limestones are the oldest formation in Permian age. Çavdartepe metamorphic rocks are of Lower Triassic in which can be observed marbles sporadically. The Kınık formation consisting of conglomerates, sandstones, siltstones and limestones are of Lower Triassic age and display a lateral Stratigraphic progress with volcanic rocks. Upper

Mineralized and unmineralized calderas in Spain; Part I, evolution of the Los Frailes Caldera

USGS Publications Warehouse

Cunningham, C.G.; Arribas, A.; Rytuba, J.J.; Arribas, A.

1990-01-01

The Cabo de Gata volcanic field of southeastern Spain contains several recently-recognized calderas. Some of the calderas are mineralized with epithermal gold, alunite, and base metal deposits, and others are barren, and yet they formed under generally similar conditions. Comparison of the magmatic, geochemical, and physical evolution of the Los Frailes, Rodalquilar, and Lomilla calderas provides insight into the processes of caldera evolution that led to precious-metal mineralization. The Los Frailes caldera formed at 14.4 Ma and is the oldest caldera. It formed in response to multiple eruptions of hornblende dacite magma. Following each eruption, the area collapsed and the caldera was invaded by the sea. Dacite domes fill the lower part of the caldera. Pyroxene andesites were erupted through the solidified core of the caldera and were probably initially responsible for magma generation. The Los Frailes caldera did not evolve to rhyolites nor was it subjected to the amount of structural development that the younger, mineralized Rodalquilar and Lomilla calderas were. ?? 1990 Springer-Verlag.

Nature and Significance of the High-Sr Aleutian Lavas

NASA Astrophysics Data System (ADS)

Yogodzinski, G. M.; Arndt, S.; Turka, J. R.; Kelemen, P. B.; Vervoort, J. D.; Portnyagin, M.; Hoernle, K.

2011-12-01

Results of the Western Aleutian Volcano Expedition and German-Russian KALMAR cruises include the discovery of seafloor volcanism at the Ingenstrem Depression and at unnamed seamounts 300 km west of Buldir, the westernmost emergent volcano in the Aleutian arc. These discoveries indicate that the surface expression of active Aleutian volcanism goes below sea level just west of Buldir, but is otherwise continuous along the full length of the arc. Many lavas dredged from western Aleutian seamounts are basalts, geochemically similar to basalts from elsewhere in Aleutians and other arcs (La/Yb 4-8, Sr/Y<30, 87Sr/86Sr=0.7031-0.7033). Western Aleutian dredge samples also include high-Sr lavas (>700 ppm Sr), which are mostly plagioclase-hornblende andesites and dacites with low Y and middle-heavy rare-earth elements, fractionated trace element patterns (Sr/Y=50-200, La/Yb=9-25) and MORB-like isotopes (87Sr/86Sr < 0.7028). The endmember Sr-rich lavas are magnesian rhyodacites (SiO2~68%, Mg# >0.65) with 1250-1700 ppm Sr, 4-7 ppm Y, low abundances of all rare-earth elements (La<7 ppm, Yb<0.4 ppm) and 87Sr/86Sr < 0.70266. The high silica and primitive (high Mg#) character of the high-Sr lavas, combined with their strongly fractionated trace element patterns and MORB-like isotopes are consistent with a source predominantly of subducted basalt and a melt residue that contained garnet. The high-Sr lavas have some characteristics of MORB fluids (low Ce/Pb and unradiogenic Pb), and their highly calc-alkaline nature implies high pre-eruptive water contents[1], but low 87Sr/86Sr indicates that their source was in MORB, not seawater-altered MORB. The high-Sr endmember is clearly present in andesites from some emergent volcanoes in the western Aleutians, and mixing arrays indicate that it may be present in all Aleutian lavas (e.g., 87Sr/86Sr vs. La/Yb or Sr/Y); however, radiogenic Pb and Sr from subducted sediment renders the high-Sr endmember isotopically invisible in most central and

Petrogenesis of volcanic rocks that host the world-class Agsbnd Pb Navidad District, North Patagonian Massif: Comparison with the Jurassic Chon Aike Volcanic Province of Patagonia, Argentina

NASA Astrophysics Data System (ADS)

Bouhier, Verónica E.; Franchini, Marta B.; Caffe, Pablo J.; Maydagán, Laura; Rapela, Carlos W.; Paolini, Marcelo

2017-05-01

We present the first study of the volcanic rocks of the Cañadón Asfalto Formation that host the Navidad world-class Ag + Pb epithermal district located in the North Patagonian Massif, Patagonia, Argentina. These volcanic and sedimentary rocks were deposited in a lacustrine environment during an extensional tectonic regime associated with the breakup of Gondwana and represent the mafic to intermediate counterparts of the mainly silicic Jurassic Chon Aike Volcanic Province. Lava flows surrounded by autobrecciated carapace were extruded in subaerial conditions, whereas hyaloclastite and peperite facies suggest contemporaneous subaqueous volcanism and sedimentation. LA-ICPMS Usbnd Pb ages of zircon crystals from the volcanic units yielded Middle Jurassic ages of 173.9 ± 1.9 Ma and 170.8 ± 3 Ma. In the Navidad district, volcanic rocks of the Cañadón Asfalto Formation show arc-like signatures including high-K basaltic-andesite to high-K dacite compositions, Rb, Ba and Th enrichment relative to the less mobile HFS elements (Nb, Ta), enrichment in light rare earth elements (LREE), Ysbnd Ti depletion, and high Zr contents. These characteristics could be explained by assimilation of crustal rocks in the Jurassic magmas, which is also supported by the presence of zircon xenocrysts with Permian and Middle-Upper Triassic ages (281.3 Ma, 246.5, 218.1, and 201.3 Ma) and quartz xenocrysts recognized in these volcanic units. Furthermore, Sr and Nd isotope compositions suggest a contribution of crustal components in these Middle Jurassic magmas. High-K basaltic andesite has initial 87Sr/86Sr ratios of 0.70416-0.70658 and ξNd(t) values of -5.3 and -4. High-K dacite and andesite have initial 87Sr/86Sr compositions of 0.70584-0.70601 and ξNd(t) values of -4,1 and -3,2. The range of Pb isotope values (206Pb/204Pb = 18.28-18.37, 207Pb/204Pb = 15.61-15.62, and 208Pb/204Pb = 38.26-38.43) of Navidad volcanic rocks and ore minerals suggest mixing Pb sources with contributions of

Voluminous arc dacites as amphibole reaction-boundary liquids

USGS Publications Warehouse

Blatter, Dawnika; Sisson, Thomas W.; Hankins, William B.

2017-01-01

Dacites dominate the large-volume, explosive eruptions in magmatic arcs, and compositionally similar granodiorites and tonalites constitute the bulk of convergent margin batholiths. Shallow, pre-eruptive storage conditions are well known for many dacitic arc magmas through melt inclusions, Fe–Ti oxides, and experiments, but their potential origins deeper in the crust are not well determined. Accordingly, we report experimental results identifying the P–T–H2O conditions under which hydrous dacitic liquid may segregate from hornblende (hbl)-gabbroic sources either during crystallization–differentiation or partial melting. Two compositions were investigated: (1) MSH–Yn−1 dacite (SiO2: 65 wt%) from Mount St. Helens’ voluminous Yn tephra and (2) MSH–Yn−1 + 10% cpx to force saturation with cpx and map a portion of the cpx + melt = hbl peritectic reaction boundary. H2O-undersaturated (3, 6, and 9 wt% H2O) piston cylinder experiments were conducted at pressures, temperatures, and fO2 appropriate for the middle to lower arc crust (400, 700, and 900 MPa, 825–1100 °C, and the Re–ReO2 buffer ≈ Ni–NiO + 2). Results for MSH–Yn−1 indicate near-liquidus equilibrium with a cpx-free hbl-gabbro residue (hbl, plg, magnetite, ± opx, and ilmeno-hematite) with 6–7 wt% dissolved H2O, 925 °C, and 700–900 MPa. Opx disappears down-temperature consistent with the reaction opx + melt = hbl. Cpx-added phase relations are similar in that once ~10% cpx crystallizes, multiple saturation is attained with cpx, hbl, and plg, +/− opx, at 6–7 wt% dissolved H2O, 940 °C, and 700–900 MPa. Plg–hbl–cpx saturated liquids diverge from plg–hbl–opx saturated liquids, consistent with the MSH–Yn−1 dacite marking a liquid composition along a peritectic distributary reaction boundary where hbl appears down-temperature as opx + cpx are consumed. The abundance of saturating phases along this distributary peritectic

Petrographic Analysis and Geochemical Source Correlation of Pigeon Peak, Sutter Buttes, CA

NASA Astrophysics Data System (ADS)

Novotny, N. M.; Hausback, B. P.

2013-12-01

The Sutter Buttes are a volcanic complex located in the center of the Great Valley north of Sacramento. They are comprised of numerous inter-intruding andesite and rhyolite lava domes of varying compositions surrounded by a shallow rampart of associated tephras. The Pigeon Peak block-and-ash flow sequence is located in the rampart and made up of a porphyritic Biotite bearing Hornblende Andesite. The andesite blocks demonstrate a high degree of propylization in hornblende crystals, highly zoned plagioclase, trace olivine, and display a red to gray color gradation. DAR is an andesite dome located less than one mile from Pigeon Peak. Of the 15 to 25 andesite lava domes within four miles from Pigeon Peak, only DAR displays trace olivine, red to grey color stratification, low biotite content, and propylitized hornblende. These characteristic similarities suggest that DAR may be the source for Pigeon Peak. My investigation used microprobe analysis of the DAR and Pigeon Peak feldspar crystals to identify the magmatic history of the magma body before emplacement. Correlation of the anorthite zoning within the feldspars from both locations support my hypothesis that DAR is the source of the Pigeon Peak block-and-ash flow.

Proterozoic Eastern Sayan ophiolites (Central Asian Orogenic Belt) record subduction initiation in vicinity of continental block

NASA Astrophysics Data System (ADS)

Belyaev, Vasilii; Gornova, Marina; Medvedev, Alexander; Dril, Sergey; Karimov, Anas

2017-04-01

volcanics and dikes are low-Ca and intermediate-Ca boninites, andesite-basalts, andesites, dacites of calc-alkaline (CA) affinity with rare evolved island-arc tholeiitic (IAT) andesite-basalts. They resemble appropriate rocks of intraoceanic island arcs, forearcs, and ophiolites. Boninites and CA-andesites are LREE-enriched (La/SmPM 1.2-3.8) at low HREE (0.5-1.6 ppm Yb) contents while evolved IAT show flat REE (La/SmPM = 1.1) and higher abundances (2.4-2.8 ppm Yb), and both have negative Nb anomalies. Nd-isotopic data expressed as epsilon Nd(1020Ma) values are -2.3 to +4.1 in cumulates, -2.8 to +0.4 in boninites and andesites, and +2.3 to +2.7 in IAT (compared to epsilon Nd(1020Ma) +7.8 in depleted mantle). The ophiolites obducted on the Gargan continental block, which contains Archean gneisses with epsilon Nd(1020) = -20 to -281. Subduction and recycling of sediments derived from these gneisses could explain enriched Nd isotopic characteristics of the studied ophiolitic rocks. The boninite-andesite-IAT association is usually found in subduction initiation settings recorded by modern forearc regions and forearc ophiolites. The difference of the Eastern Sayan ophiolites is their supposed formation close to ancient continental block which supplied recycled material into newly formed subduction zone. 1. Sklyarov et al (2016) Russ Geol Geophys 57, 127-140 2. Sobolev et al (1996) Petrology 3, 326-336.

Mount Mageik: A compound stratovolcano in Katmai National Park: A section in Geologic studies in Alaska by the U.S. Geological Survey, 1998

USGS Publications Warehouse

Hildreth, Wes; Fierstein, Judy; Lanphere, Marvin A.; Siems, David F.

2000-01-01

Mount Mageik is an ice-clad 2,165-m andesite-dacite stratovolcano in the Katmai volcanic cluster at the head of the Valley of Ten Thousand Smokes. New K-Ar ages indicate that the volcano is as old as 93±8 ka. It has a present-day volume of 20 km3 but an eruptive volume of about 30 km3, implying a longterm average volumetric eruption rate of about 0.33 km3 per 1,000 years. Mount Mageik consists of four overlapping edi- fices, each with its own central summit vent, lava-flow apron, and independent eruptive history. Three of them have small fragmental summit cones with ice-filled craters, but the fourth and highest is topped by a dacite dome. Lava flows predominate on each edifice; many flows have levees and ice-contact features, and many thicken downslope into piedmont lava lobes 50–200 m thick. Active lifetimes of two (or three) of the component edifices may have been brief, like that of their morphological and compositional analog just across Katmai Pass, the Southwest (New) Trident edifice of 1953–74. The North Summit edi- fice of Mageik may have been constructed very late in the Pleistocene and the East Summit edifice (along with nearby Mount Martin) largely or entirely in the Holocene. Substantial Holocene debris avalanches have broken loose from three sites on the south side of Mount Mageik, the youngest during the Novarupta fallout of 6 June 1912. The oldest one was especially mobile, being rich in hydrothermal clay, and is preserved for 16 km downvalley, probably having run out to the sea. Mageik's fumarolically active crater, which now contains a hot acid lake, was never a magmatic vent but was reamed by phreatic explosions through the edge of the dacite summit dome. There is no credible evidence of historical eruptions of Mount Mageik, but the historically persistent fumarolic plumes of Mageik and Martin have animated many spurious eruption reports. Lavas and ejecta of all four component edifices of Mageik are plagioclaserich, pyroxene-dacites and

The plinian eruptions of 1912 at Novarupta, Katmai National Park, Alaska

USGS Publications Warehouse

Fierstein, J.; Hildreth, W.

1992-01-01

The three-day eruption at Novarupta in 1912 consisted of three discrete episodes. Episode I began with plinian dispersal of rhyolitic fallout (Layer A) and contemporaneous emplacement of rhyolitic ignimbrites and associated proximal veneers. The plinian column was sustained throughout most of the interval of ash flow generation, in spite of progressive increases in the proportions of dacitic and andesitic ejecta at the expense of rhyolite. Accordingly, plinian Layer B, which fell in unbroken continuity with purely rhyolitic Layer A, is zoned from >99% to ???15% rhyolite and accumulated synchronously with emplacement of the correspondingly zoned ash flow sequence in Mageik Creek and the Valley of Ten Thousand Smokes (VTTS). Only the andesiterichest flow units that cap the flow sequence lack a widespread fallout equivalent, indicating that ignimbrite emplacement barely outlasted the plinian phase. On near-vent ridges, the passing ash flows left proximal ignimbrite veneers that share the compositional zonation of their valley-filling equivalents but exhibit evidence for turbulent deposition and recurrent scour. Episode II began after a break of a few hours and was dominated by plinian dispersal of dacitic Layers C and D, punctuated by minor proximal intraplinian flows and surges. After another break, dacitic Layers F and G resulted from a third plinian episode (III); intercalated with these proximally are thin intraplinian ignimbrites and several andesite-rich fall/flow layers. Both CD and FG were ejected from an inner vent <400 m wide (nested within that of Episode I), into which the rhyolitic lava dome (Novarupta) was still later extruded. Two finer-grained ash layers settled from composite regional dust clouds: Layer E, which accumulated during the D-F hiatus, includes a contribution from small contemporaneous ash flows; and Layer H settled after the main eruption was over. Both are distinct layers in and near the VTTS, but distally they merge with CD and FG

Compositional evolution of the zoned calcalkaline magma chamber of Mount Mazama, Crater Lake, Oregon

USGS Publications Warehouse

Bacon, C.R.; Druitt, T.H.

1988-01-01

The climactic eruption of Mount Mazama has long been recognized as a classic example of rapid eruption of a substantial fraction of a zoned magma body. Increased knowledge of eruptive history and new chemical analyses of ???350 wholerock and glass samples of the climactic ejecta, preclimactic rhyodacite flows and their inclusions, postcaldera lavas, and lavas of nearby monogenetic vents are used here to infer processes of chemical evolution of this late Pleistocene - Holocene magmatic system. The 6845??50 BP climactic eruption vented ???50 km3 of magma to form: (1) rhyodacite fall deposit; (2) welded rhyodacite ignimbrite; and (3) lithic breccia and zoned ignimbrite, these during collapse of Crater Lake caldera. Climactic ejecta were dominantly homogeneous rhyodacite (70.4??0.3% SiO2), followed by subordinate andesite and cumulate scoriae (48-61% SiO2). The gap in wholerock composition reflects mainly a step in crystal content because glass compositions are virtually continuous. Two types of scoriae are distinguished by different LREE, Rb, Th, and Zr, but principally by a twofold contrast in Sr content: High-Sr (HSr) and low-Sr (LSr) scoriae. HSr scoriae were erupted first. Trace element abundances indicate that HSr and LSr scoriae had different calcalkaline andesite parents; basalt was parental to some mafic cumulate scoriae. Parental magma compositions reconstructed from scoria wholerock and glass data are similar to those of inclusions in preclimactic rhyodacites and of aphyric lavas of nearby monogenetic vents. Preclimactic rhyodacite flows and their magmatic inclusions give insight into evolution of the climactic chamber. Evolved rhyodacite flows containing LSr andesite inclusions were emplaced between ???30000 and ???25000 BP. At 7015??45 BP, the Llao Rock vent produced a zoned rhyodacite pumice fall, then rhyodacite lava with HSr andesite inclusions. The Cleetwood rhyodacite flow, emplaced immediately before the climactic eruption and compositionally

Wynoochee Dam Foundation Report

DTIC Science & Technology

1988-01-01

schists and in propylitized andesite volcanic rocks. Tests on chlorite-bearing graywackes (Lumni Island and Robe Quarry, Seattle District) and... propylitized chlorite-bearing andesites (Blue River and Lookout Point Dams, Portland District) have shown these rocks to be durable materials with only minor

Calderas and caldera structures: a review

NASA Astrophysics Data System (ADS)

Cole, J. W.; Milner, D. M.; Spinks, K. D.

2005-02-01

Calderas are important features in all volcanic environments and are commonly the sites of geothermal activity and mineralisation. Yet, it is only in the last 25 years that a thorough three-dimensional study of calderas has been carried out, utilising studies of eroded calderas, geophysical analysis of their structures and analogue modelling of caldera formation. As more data has become available on calderas, their individuality has become apparent. A distinction between 'caldera', 'caldera complex', 'cauldron', and 'ring structure' is necessary, and new definitions are given in this paper. Descriptions of calderas, based on dominant composition of eruptives (basaltic, peralkaline, andesitic-dacitic, rhyolitic) can be used, and characteristics of each broad group are given. Styles of eruption may be effusive or explosive, with the former dominant in basaltic calderas, and the latter dominant in andesitic-dacitic, rhyolitic and peralkaline calderas. Four 'end-member' collapse styles occur—plate or piston, piecemeal, trapdoor, and downsag—but many calderas have multiple styles. Features of so-called 'funnel' and 'chaotic' calderas proposed in the literature can be explained by other collapse styles and the terms are considered unnecessary. Ground deformation comprises subsidence or collapse (essential characteristics of a caldera) and uplifting/doming and fracturing due to tumescence and/or resurgence (frequent, but not essential). Collapse may occur on pre-existing structures, such as regional faults or on faults created during the caldera formation, and the shape of the collapse area will be influenced by depth, size and shape of the magma chamber. The final morphology of a caldera will depend on how the caldera floor breaks up; whether collapse takes place in one event or multiple events, whether vertical movement is spasmodic or continuous throughout the eruptive sequence, and whether blocks subside uniformly or chaotically at one or more collapse centres. A

Blue Mountain and The Gas Rocks: Rear-Arc Dome Clusters on the Alaska Peninsula

USGS Publications Warehouse

Hildreth, Wes; Fierstein, Judy; Calvert, Andrew T.

2007-01-01

Behind the single-file chain of stratovolcanoes on the Alaska Peninsula, independent rear-arc vents for mafic magmas are uncommon, and for silicic magmas rarer still. We report here the characteristics, compositions, and ages of two andesite-dacite dome clusters and of several nearby basaltic units, all near Becharof Lake and 15 to 20 km behind the volcanic front. Blue Mountain consists of 13 domes (58-68 weight percent SiO2) and The Gas Rocks of three domes (62-64.5 weight percent SiO2) and a mafic cone (52 weight percent SiO2). All 16 domes are amphibole-biotite-plagioclase felsite, and nearly all are phenocryst rich and quartz bearing. Although the two dome clusters are lithologically and chemically similar and only 25 km apart, they differ strikingly in age. The main central dome of Blue Mountain yields an 40Ar/39Ar age of 632?7 ka, and two of the Gas Rocks domes ages of 25.7?1.4 and 23.3?1.2 ka. Both clusters were severely eroded by glaciation; surviving volumes of Blue Mountain domes total ~1 km3, and of the Gas Rocks domes 0.035 km3. Three basaltic vents lie close to The Gas Rocks, another lies just south of Blue Mountain, and a fifth is near the north shore of Becharof Lake. A basaltic andesite vent 6 km southeast of The Gas Rocks appears to be a flank vent of the arc-front center Mount Peulik. The basalt of Ukinrek Maars has been called transitionally alkalic, but all the other basaltic rocks are subalkaline. CO2-rich gas emissions near the eponymous Gas Rocks domes are not related to the 25-ka dacite dome cluster but, rather, to intracrustal degassing of intrusive basalt, one batch of which erupted 3 km away in 1977. The felsic and mafic vents all lie along or near the Bruin Bay Fault where it intersects a broad transverse structural zone marked by topographic, volcanologic, and geophysical discontinuities.

Upper Cretaceous to Holocene magmatism and evidence for transient Miocene shallowing of the Andean subduction zone under the northern Neuquén Basin

USGS Publications Warehouse

Kay, Suzanne M.; Burns, W. Matthew; Copeland, Peter; Mancilla, Oscar

2006-01-01

Evidence for a Miocene period of transient shallow subduction under the Neuquén Basin in the Andean backarc, and an intermittent Upper Cretaceous to Holocene frontal arc with a relatively stable magma source and arc-to-trench geometry comes from new 40Ar/39Ar, major- and trace-element, and Sr, Pb, and Nd isotopic data on magmatic rocks from a transect at ∼36°–38°S. Older frontal arc magmas include early Paleogene volcanic rocks erupted after a strong Upper Cretaceous contractional deformation and mid-Eocene lavas erupted from arc centers displaced slightly to the east. Following a gap of some 15 m.y., ca. 26–20 Ma mafic to acidic arc-like magmas erupted in the extensional Cura Mallín intra-arc basin, and alkali olivine basalts with intraplate signatures erupted across the backarc. A major change followed as ca. 20–15 Ma basaltic andesite–dacitic magmas with weak arc signatures and 11.7 Ma Cerro Negro andesites with stronger arc signatures erupted in the near to middle backarc. They were followed by ca. 7.2–4.8 Ma high-K basaltic to dacitic hornblende-bearing magmas with arc-like high field strength element depletion that erupted in the Sierra de Chachahuén, some 500 km east of the trench. The chemistry of these Miocene rocks along with the regional deformational pattern support a transient period of shallow subduction that began at ca. 20 Ma and climaxed near 5 Ma. The subsequent widespread eruption of Pliocene to Pleistocene alkaline magmas with an intraplate chemistry in the Payenia large igneous province signaled a thickening mantle wedge above a steepening subduction zone. A pattern of decreasingly arc-like Pliocene to Holocene backarc lavas in the Tromen region culminated with the eruption of a 0.175 ± 0.025 Ma mafic andesite. The northwest-trending Cortaderas lineament, which generally marks the southern limit of Neogene backarc magmatism, is considered to mark the southern boundary of the transient shallow subduction zone.

Storage conditions of the mafic and silicic magmas at Cotopaxi, Ecuador

NASA Astrophysics Data System (ADS)

Martel, Caroline; Andújar, Joan; Mothes, Patricia; Scaillet, Bruno; Pichavant, Michel; Molina, Indira

2018-04-01

The 2015 reactivation of the Cotopaxi volcano urges us to understand the complex eruptive dynamics of Cotopaxi for better management of a potential major crisis in the near future. Cotopaxi has commonly transitioned from andesitic eruptions of strombolian style (lava flows and scoria ballistics) or nuées ardentes (pyroclastic flows and ash falls) to highly explosive rhyolitic ignimbrites (pumiceous pyroclastic flows), which entail drastically different risks. To better interpret geophysical and geochemical signals, Cotopaxi magma storage conditions were determined via existing phase-equilibrium experiments that used starting materials chemically close to the Cotopaxi andesites and rhyolites. The results suggest that Cotopaxi's most mafic andesites (last erupted products) can be stored over a large range of depth from 7 km to ≥16 km below the summit (pressure from 200 to ≥400 MPa), 1000 °C, NNO +2, and contain 4.5-6.0±0.7 wt% H2O dissolved in the melt in equilibrium with 30-40% phenocrysts of plagioclase, two pyroxenes, and Fe-Ti oxides. These mafic andesites sometimes evolve towards more silicic andesites by cooling to 950 °C. Rhyolitic magmas are stored at 200-300 MPa (i.e. 7-11 km below the summit), 750 °C, NNO +2, and contain 6-8 wt% H2O dissolved in a nearly aphyric melt (<5% phenocrysts of plagioclase, biotite, and Fe-Ti oxides). Although the andesites produce the rhyolitic magmas by fractional crystallization, the Cotopaxi eruptive history suggests reactivation of either reservoirs at distinct times, likely reflecting flux or time fluctuations during deep magma recharge.

Advent of Continents: A New Hypothesis

PubMed Central

Tamura, Yoshihiko; Sato, Takeshi; Fujiwara, Toshiya; Kodaira, Shuichi; Nichols, Alexander

2016-01-01

The straightforward but unexpected relationship presented here relates crustal thickness to magma type in the Izu-Ogasawara (Bonin) and Aleutian oceanic arcs. Volcanoes along the southern segment of the Izu-Ogasawara arc and the western Aleutian arc (west of Adak) are underlain by thin crust (10–20 km). In contrast those along the northern segment of the Izu-Ogasawara arc and eastern Aleutian arc are underlain by crust ~35 km thick. Interestingly, andesite magmas dominate eruptive products from the former volcanoes and mostly basaltic lavas erupt from the latter. According to the hypothesis presented here, rising mantle diapirs stall near the base of the oceanic crust at depths controlled by the thickness of the overlying crust. Where the crust is thin, melting occurs at relatively low pressures in the mantle wedge producing andesitic magmas. Where the crust is thick, melting pressures are higher and only basaltic magmas tend to be produced. The implications of this hypothesis are: (1) the rate of continental crust accumulation, which is andesitic in composition, would have been greatest soon after subduction initiated on Earth, when most crust was thin; and (2) most andesite magmas erupted on continental crust could be recycled from “primary” andesite originally produced in oceanic arcs. PMID:27669662

Geochemical studies of abyssal lavas recovered by DSRV Alvin from Eastern Galapagos Rift, Inca Transform, and Ecuador Rift: 2. Phase chemistry and crystallization history

NASA Astrophysics Data System (ADS)

Perfit, Michael R.; Fornari, Daniel J.

1983-12-01

A diverse suite of lavas recovered by DSRV Alvin from the eastern Galapagos rift and Inca transform includes mid-ocean ridge tholeiitic basalts (MORB), iron- and titanium-enriched basalts (FeTi basalts), and abyssal andesites. Rock types transitional in character (ferrobasalts and basaltic andesites) were also recovered. The most mafic glassy basalts contain plagioclase, augite, and olivine as near-liquidus phases, whereas in more fractionated basalts, pigeonite replaces olivine and iron-titanium oxides crystallize. Plagioclase crystallizes after pyroxenes and iron-titanium oxides in andesites, possibly due to increased water contents or cooling rates. Apatite phenocrysts are present in some andesitic glasses. Ovoid sulfide globules are also common in many lavas. Compositional variations of phenocrysts in glassy lavas reflect changes in magma chemistry, temperature of crystallization, and cooling rate. The overall chemical variations parallel the chemical evolution of the lava suite and are similar to those in other fractionated tholeiitic complexes. Elemental partitioning between plagioclase-, pyroxene-, and olivine-glass pairs suggests that equilibration occurred at low pressure in a rather restricted temperature range. Various geothermometers indicate that the most primitive MORB began to crystallize between 1150° and 1200°C with fo2 < 10-7 atm. Coexisting iron-titanium oxides in more evolved lavas yield temperatures ˜1025°C to as low as 910°C withfo2 from 10-8 to 10-12 atm. PH 2 o could have been as high as 1 kbar during andesite crystallization. Compositions of the lavas from the Galapagos rift follow the experimentally determined (1 atm-QFM) liquid line of descent. Least squares calculations for the major elements indicate that the entire suite of lavas can be produced by fractional crystallization of successive residual liquids from a MORB parent magma. FeTi basalts represent 30-65 cumulative weight percent crystallization of plagioclase, augite, and

Geology of the region of Guadalajara, Mexico, and its relationships with processes of subsidence

NASA Astrophysics Data System (ADS)

Suarez-Plascencia, C.; Delgado-Argote, L. A.; Nuñez-Cornu, F. J.; Sanchez, J. J.

2008-12-01

The city of Guadalajara, Mexico, began an accelerated urban growth in early 1950. During a span of 25 years a large number of gullies were artificially filled, with the aim of incorporating new areas for urbanization, particularly in the areas north and west of the city. These gullies originally formed a complex dendritic-type system, whose evolution may be associated with faults or fracture zones whose current identification are only possible based on escarpments along the Canyon of the Rio Grande de Santiago (CRGS), north of Guadalajara. Reports of affectations documented in the 80's described subsidence in buildings and infrastructure, a process that has been continued during 2008. We present the results of work done in the CRGS, which is a tectonic erosive-depression with an average depth of 500 m and exhibits a sequence of volcanic and sedimentary deposits with rapid lateral facies changes. The stratigraphic column spans a 15 km-long section along the Matatlán-Arcediano road, and, from top to bottom contains: 1) Unconsolidated pumice and tuffs with an average thickness of 12 m; 2) basaltic lavas with average thickness of 60 m; 3) the San Gaspar ignimbrite; 4) fluvial- sedimentary deposits with a thickness of approximately 20 meters that include both sub-rounded and angular volcanic clasts, with sizes up to 0.15 m; 5) a thick sequence of ignimbrites and dacitic lavas. At a depth of 1200 m.a.s.l. in the town of Arcediano, the basal sequence is composed of dacites and andesites with interbedded pumice-rich ignimbrites with 10-20 m thickness. The Rio Grande de Santiago talweg to 1018 m.a.s.l. (apparently the base of the sequence) is formed by andesite lava. In the area of San Gaspar we identified oblique-normal left-lateral faults in lavas, with a strike 191° and a dip 89°. In the Colimilla dam, 1297 m.a.s.l., we observed normal faulting (strike 267° and dip 81°), with 20-30 m jumps with reference to a unit of tephra of 3-10 m thickness. The lavas in this

Late Ediacaran volcano-sedimentary successions of southern Sinai (Egypt): tracing the evolution from late- to post-collisional volcanism and its relation to A-type rocks

NASA Astrophysics Data System (ADS)

Azer, Mokhles; Asimow, Paul; Obeid, Mohamed; Price, Jason; Wang, Max

2017-04-01

The Late Ediacaran post-collisional volcano-sedimentary successions exposed in southern Sinai (Egypt) represent the last stage of magmatic activity associated with assembly of the northernmost segment of the Neoproterozoic Arabian-Nubian Shield. To clarify the age and tempo of post-collisional activity, three volcanic successions from southern Sinai were selected for the present study: the Sahiya, Iqna Shar'a and Meknas volcanics. They comprise a series of intermediate to silicic volcanic flows and their pyroclastic rocks. New zircon U-Pb dating by SIMS of the lava flows from the three successions yielded ages ranging between ca. 619 to 600 Ma. Combined with field evidence and the geochemical data, the obtained SIMS zircon ages enable us to recognize two phases of volcanic activity in southern Sinai at ca. 619-615 Ma and 606-600 Ma. Both age groups were found within the more northerly volcanic successions at Iqna Shar'a and Meknas and in both these sequences the younger phase uncomformably overlies the older phase. Only the older ages, ca. 615-619 Ma, were found in the Sahiya volcanics, exposed at the southern tip of Sinai. The ages of the youngest calc-alkaline volcanics in the study areas are similar to or slightly younger than the earliest phases of alkaline volcanism in southern Sinai, indicating coeval extrusion of calc-alkalic and alkalic A-type rocks. This observation corroborates similar observations documenting cogenetic calc-alkalic and alkalic plutons in the surrounding areas in southern Sinai. Geochemically, the volcanic rocks of the three successions display large silica variations and are mostly medium- to high-K calc-alkaline rocks. The first phase, from ca. 619-615 Ma, observed in all three volcanic suites, comprises basaltic andesite, andesite and dacite, whereas the second phase, from ca. 606-600 Ma and observed only in the northern volcanic suites (Iqna Shar'a and Meknas), comprises dacite, rhyodacite and rhyolite. In the Sahiya succession basal

Volcanologic and petrologic evolution of Antuco-Sierra Velluda, Southern Andes, Chile

NASA Astrophysics Data System (ADS)

Martínez, Paola; Singer, Brad S.; Roa, Hugo Moreno; Jicha, Brian R.

2018-01-01

The Andean Southern Volcanic Zone comprises > 30 active arc front volcanoes that grew over periods of hundreds of thousands of years. Quantifying the rates at which these volcanoes grow is key to appreciating geological hazards, clarifying petrologic evolution, and exploring possible relationships between volcanism, ice loading, and climate. The integration of precise geochronology and geologic mapping, together with new lava compositions and volume estimates, reveal the evolution of the Antuco-Sierra Velluda volcanic complex at 37.2°S. Thirty-one new 40Ar/39Ar age determinations illuminate a punctuated eruptive history that spans at least 430 kyr. Sierra Velluda comprises 130 km3 and began to grow prior to 426.8 ka. A lacuna in the volcanic record between 343.5 and 150.4 ka coincides with glaciations associated with marine isotope stages (MIS) 10 and 8, although shallow intrusions were emplaced at 207.0 and 190.0 ka. Antuco began to grow rapidly on the northeast flank of Sierra Velluda, erupting > 60 km3 of lava during three phases: (1) an early phase that began at 150.4 ka, (2) a post-MIS 2 phase between 16.3 and 6.2 ka, and (3) a post-sector collapse phase after 6.2 ka. Volcanism has been continuous during the last 100 kyr, with an average rate of cone growth during this period of 0.46 km3/kyr that has accelerated by about 50% during the past 6 kyr. Whereas Sierra Velluda erupted basaltic andesitic to andesitic (53.5 to 58.7 wt% SiO2) lavas, during the last expansion of glaciers between 130 and 17 ka, Early Antuco erupted a wider spectrum of lavas, ranging from basaltic andesite to dacite (52.0 to 64.5 wt% SiO2). Notably, eruptions following the last glacial termination at 17 ka produced basalts and basaltic andesites (50.9-53.7% SiO2), and following the 6.2 ka cone collapse they have been exclusively olivine basalt (50.9-53.0% SiO2) with > 5 wt% MgO. Thermodynamic and trace element modeling suggests that lavas from Sierra Velluda and Early Antuco reflect

Geochronology and eruptive history of the Katmai volcanic cluster, Alaska Peninsula

USGS Publications Warehouse

Hildreth, Wes; Lanphere, Marvin A.; Fierstein, Judy

2003-01-01

In the Katmai district of the Alaska Peninsula, K–Ar and 40Ar/39Ar ages have been determined for a dozen andesite–dacite stratocones on the arc front and for 11 rear-arc volcanoes, 10 of which are monogenetic. Tied to mapping and stratigraphic studies, our dating emphasized proximal basal lavas that rest on basement rocks, in order to estimate ages of inception of each polygenetic cone. Oldest among arc-front cones is Alagogshak Volcano (690–43 ka), succeeded in the Holocene by the active Mount Martin cone. Mount Mageik consists of four overlapping subedifices, basal lavas of which give ages of 93, 71, and 59 ka, and Holocene. The three small prehistoric cones of Trident Volcano yield ages of 143, 101–58, and 44 ka. Falling Mountain and Mount Cerberus, dacite domes near the 1912 Novarupta vent, are related compositionally to the Trident group and give ages of 70 ka and 114 ka. Mount Katmai, which underwent caldera collapse in 1912, consists of two subedifices that overlapped in space and time, and is the only arc-front center here to include basalt and rhyolite; one cone began by 90 ka, the other by 47 ka. Snowy Mountain also consists of two contiguous cones, which started around 200 and 171 ka, respectively, the younger remaining active into the Holocene. Devils Desk, the only mafic cone on the arc front, was short-lived at about 245 ka. In the rear-arc, (1) Mount Griggs produced mafic-to-silicic andesite in several episodes between 292 ka and the Holocene; (2) the Savonoski River cluster includes a Pliocene dacite dome and five small mafic cones (390–88 ka); (3) Gertrude Creek cone (49.8% SiO2) yields an age of 500 ka; and (4) the Saddlehorn Creek cluster includes five Pliocene basalt-to-andesite remnants. Eruptive volumes were reconstructed, permitting estimates of average eruption rates for edifice lifetimes. Since the mid Pleistocene, total volume erupted along the arc front here is 210±47 km3 and in the rear-arc 39±6 km3, of which Mount Griggs

Hydrous orthopyroxene-rich pyroxenite source of the Xinkailing high magnesium andesites, Western Liaoning: Implications for the subduction-modified lithospheric mantle and the destruction mechanism of the North China Craton

NASA Astrophysics Data System (ADS)

Hong, Lu-Bing; Zhang, Yin-Hui; Xu, Yi-Gang; Ren, Zhong-Yuan; Yan, Wen; Ma, Qiang; Ma, Liang; Xie, Wei

2017-06-01

Metasomatism of the lithospheric mantle by subduction-related fluids/melts is recorded in the Early Cretaceous Xinkailing high magnesium andesites (HMAs) from Western Liaoning. Olivine-hosted melt inclusions within the Xinkailing HMAs are alkaline and record a much lower SiO2 content and higher Al2O3 and CaO contents than the sub-alkaline bulk rock compositions. These observed compositional differences between bulk rocks and melt inclusions suggest that a crustally derived, high-SiO2 melt was incorporated in the Xinkailing HMAs within the pre-eruptive magma chamber. The process of this incorporation accounts for the compositional differences between upper (HMAs) and lower (high magnesium basalts) successions of the Yixian Formation. Olivine phenocrysts also record unusually high Ni and Ni/MgO contents with high Fo values. Based on the fact that bulk rocks record low Ni contents, whereas olivine crystals record a steep correlation between Fo and Ni and low CaO and CaO/FeO contents, in addition to the likely considerable depression of the olivine liquidus temperature, we argue that a hydrous (2-6% H2O) orthopyroxene-rich pyroxenite source was formed by the reaction between subducted slab-released SiO2-rich fluids and overlying mantle peridotite. We further propose that during a series of Phanerozoic successive subduction events around the Eastern NCC, a significant amount of water may have been transported to the lithospheric mantle, thus lowering its viscosity and ultimately destabilizing the cratonic lithosphere. Hydrous experiments data (circles filled by yellow color) used to parameterize the equation after screened several data significantly deviates from the line (circles without color). Data source: Gaetani and Grove (1998); Almeev et al. (2007); Médard and Grove (2008); Tenner et al. (2009); Mitchell and Grove (2015).

Temporal evolution of the Western and Central volcanism of the Aeolian Island Arc (Italy, southern Tyrhhenian Sea)

NASA Astrophysics Data System (ADS)

Leocat, E.; Gillot, P.-Y.; Peccerillo, A.

2009-04-01

�4 ka. Then the activity was followed by the construction of the Mte Terrione at 168±4 ka (Gillot 1987), which is matched by High K-Ca andesites emplaced in the Chiumento crater. Therefore, two different magmatic series took place in only 15 ka. The last eruption of Filicudi built the High K-CA dacite lava dome of Mte Montagnola. For Lipari island, the same event is observed around 120-100 ka. In fact, the emitted products evolved from CA andesitic basalts, that emplaced from 256±8 ka (Monte Chirica) to 119±7 ka (Monterosa), to High K-CA andesite after 100 ka. The rocks becam more and more differentiated to achieve High K-CA rhyolite composition during the last 40 ka. At the same time, the Monte Fossa delle Felci of Salina island shows a geochemical "excursion" around 100 ka, characterised by High K-CA dacite. The lower limit of Pollara explosive eruption, that emitted High K-CA rhyolite products, is constrain by a Monte dei Porri lava flow affected by Pollara crater and dated at 13±2 ka. Thus, all these magmatic changes correlate with morphological and volcanic variations. Finally, our first results confirm that the Aeolian arc volcanism is generated in a complex source, with important roles of both arc-type and anorogenic-type compositions. Datings on key samples show that role of different mantle sources change within a very short time span, especially in the central portion of the arc, along the TL lithosheric fault system. This work also gives new geochronological constrains on the duration of magmatic evolution and eruptive phases.

The evolution of young silicic lavas at Medicine Lake Volcano, California: Implications for the origin of compositional gaps in calc-alkaline series lavas

USGS Publications Warehouse

Grove, T.L.; Donnelly-Nolan, J. M.

1986-01-01

At Medicine Lake Volcano, California, the compositional gap between andesite (57-62 wt.% SiO2) and rhyolite (73-74 wt.% SiO2) has been generated by fractional crystallization. Assimilation of silicic crust has also occurred along with fractionation. Two varieties of inclusions found in Holocene rhyolite flows, hornblende gabbros and aphyric andesites, provide information on the crystallization path followed by lavas parental to the rhyolite. The hornblende gabbros are magmatic cumulate residues and their mineral assemblages are preserved evidence of the phases that crystallized from an andesitic precursor lava to generate the rhyolite lavas. The andesitic inclusions represent samples of a parental andesite and record the early part of the differentiation history. Olivine, plagioclase and augite crystallization begins the differentiation history, followed by the disappearance of olivine and augite through reaction with the liquid to form orthopyroxene and amphibole. Further crystallization of the assemblage plagioclase, amphibole, orthopyroxene, magnetite, and apatite from a high-SiO2 andesite leads to rhyolite. This final crystallization process occurs on a cotectic that is nearly horizontal in temperature-composition space. Since a large amount of crystallization occurs over a limited temperature interval, a compositional gap develops between rhyolite and high SiO2 andesite. Liquidus surfaces with shallow slopes in temperature-composition space are characteristic of several late-stage crystallization assemblages in the andesite to rhyolite compositional range. Experimentally produced plagioclase+ amphibole+orthopyroxene+magnetite and plagioclase+ augite+low-Ca pyroxene+magnetite cotectics have liquidus slopes that are nearly flat. At other calc-alkaline volcanic centers crystallization processes involving large compositional changes over small temperature intervals may also be important in the development of bimodal volcanism (i.e. the existence of a composition

The Cosmos greenstone succession, Agnew-Wiluna greenstone belt, Yilgarn Craton, Western Australia: Geochemistry of an enriched Neoarchaean volcanic arc succession

NASA Astrophysics Data System (ADS)

de Joux, A.; Thordarson, T.; Fitton, J. G.; Hastie, A. R.

2014-09-01

The geodynamic setting of the Neoarchaean Eastern Goldfields Superterrane (EGS) of the Yilgarn Craton is the subject of debate. Some authors propose plume models, while others advocate variants on a subduction accretion model for the origin of mineralised greenstone belt sequences. Felsic volcanism in the Kalgoorlie Terrane, the westernmost terrane of the EGS, is considered to have a tonalite-trondhjemite-granodiorite/dacite (TTG/D) geochemical affinity. The Cosmos greenstone succession, which lies in the Agnew-Wiluna greenstone belt (AWB) of the Kalgoorlie Terrane, contains several komatiite-hosted nickel sulphide deposits, the volcanic footwall to which consists of an intercalated succession of fragmental and coherent rocks ranging in composition from basaltic andesite to rhyolite. Light rare earth elements (LREEs) and large ion-lithophile elements (LILEs) are strongly enriched relative to high field strength elements (HFSEs) across all volcanic units, and the rocks display strong positive Pb and negative Nb anomalies. These geochemical characteristics resemble closely those of modern high-K calc-alkaline to shoshonite continental arc successions. Contrasting REE, LILE and HFSE concentrations, coupled with assimilation-fractional crystallisation (AFC) modelling, shows that the intercalated dacitic and andesitic volcanic rocks within the footwall succession are not co-genetic. Xenocrystic zircons within the felsic volcanic lithologies indicate that some assimilation of older continental crust contributed to the generation of the footwall volcanic sequence. The geochemical characteristics of the Cosmos volcanic succession indicate that parental melts were derived via partial melting of enriched peridotite that had been contaminated by subducted crustal material within the mantle wedge of a subduction zone. In contrast, two younger felsic porphyry intrusions, which cross-cut the volcanic succession, have a distinct TTG/D affinity. Therefore, these intrusions are

Timing the evolution of a monogenetic volcanic field: Sierra Chichinautzin, Central Mexico

NASA Astrophysics Data System (ADS)

Jaimes-Viera, M. C.; Martin Del Pozzo, A. L.; Layer, P. W.; Benowitz, J. A.; Nieto-Torres, A.

2018-05-01

The unique nature of monogenetic volcanism has always raised questions about its origin, longevity and spatial distribution. Detailed temporal and spatial boundaries resulted from a morphometric study, mapping, relative dating, twenty-four new 40Ar/39Ar dates, and chemical analyses for the Sierra Chichinautzin, Central Mexico. Based on these results the monogenetic cones were divided into four groups: (1) Peñón Monogenetic Volcanic Group (PMVG); (2) Older Chichinautzin Monogenetic Volcanic Group (Older CMVG); (3) Younger Chichinautzin Monogenetic Volcanic Group (Younger CMVG) and (4) Sierra Santa Catarina Monogenetic Volcanic Group (SSC). The PMVG cover the largest area and marks the northern and southern boundaries of this field. The oldest monogenetic volcanism (PMVG; 1294 ± 36 to 765 ± 30 ka) started in the northern part of the area and the last eruption of this group occurred in the south. These basaltic-andesite cones are widely spaced and are aligned NE-SW (N60°E). After this activity, monogenetic volcanism stopped for 527 ka. Monogenetic volcanism was reactivated with the birth of the Tezoyuca 1 Volcano, marking the beginning of the second volcanic group (Older CMVG; 238 ± 51 to 95 ± 12 ka) in the southern part of the area. These andesitic to basaltic andesite cones plot into two groups, one with high MgO and Nb, and the other with low MgO and Nb, suggesting diverse magma sources. The eruption of the Older CMVG ended with the eruption of Malacatepec volcano and then monogenetic volcanism stopped again for 60 ka. At 35 ka, monogenetic volcanism started again, this time in the eastern part of the area, close to Popocatépetl volcano, forming the Younger CMVG (<35 ± 4 ka). These cones are aligned in an E-W direction. Geochemical composition of eruptive products of measured samples varies from basalts to dacites with low and high MgO. The Younger CMVG is considered still active since the last eruptions took place <2 ka. The SSC (132 ± 70 to 2 ± 56 ka

Mineral complexities as evidence for open-system processes in intermediate magmas of the Mount Baker volcanic field, northern Cascade arc

NASA Astrophysics Data System (ADS)

Escobar-Burciaga, R. D.; DeBari, S. M.

2015-12-01

The petrogenesis of intermediate magmas in arcs is a critical contribution to crustal growth. Andesites are commonly thought of as a hybrid product, the result of two endmember magmas mixing. At the Mount Baker volcanic field (MBVF), northern Cascade arc, andesites are the predominantly erupted lavas since 1 Ma and yet their origin is poorly constrained. Previous studies have suggested that open-system processes play a dominant role. However, the studies rely heavily on bulk rock compositions and overlook complex mineral textures and compositions. To better understand the complex processes at work at MBVF, we focus on establishing mineral and crystal clot populations in three andesitic flow units (55-59% SiO2). Petrographic and geochemical analyses suggest that variable-composition crystal clot and phenocryst populations in a single flow are related. We interpret the crystal clots to represent cumulates entrained in the erupting host magma and that related phenocrysts are disaggregates of crystal clots. The existence of common, multiple phenocryst and crystal clot populations in each flow of different age and SiO2 content provides strong evidence that intermediate magmas of MBVF are more than just the end product of mixing between two magmas. Furthermore, we suggest that most phenocrysts do not represent equilibrium products of their host liquid, evident from wide compositional ranges of ferromagnesian minerals (e.g. augite core Mg# 70-87). In fact, the most primitive phenocryst populations show the least amount of disequilibrium texture but represent assemblages expected to fractionate from basaltic to basaltic-andesitic liquids rather than equilibrium assemblages from their host bulk rock "liquid" composition. As a result, we interpret the variable SiO2 signature of the three andesitic flow units to have been obtained through the incorporation of cumulates/liquids as basaltic to basaltic-andesitic magma ascends.

New insights into the origin of the bimodal volcanism in the middle Okinawa Trough: not a basalt-rhyolite differentiation process

NASA Astrophysics Data System (ADS)

Zhang, Yuxiang; Zeng, Zhigang; Chen, Shuai; Wang, Xiaoyuan; Yin, Xuebo

2018-06-01

In the middle Okinawa Trough (MOT), rhyolites have been typically considered as products of crystallization differentiation of basaltic magma as a feature of bimodal volcanism. However, the evidence is insufficient. This paper compared chemical trends of volcanic rocks from the MOT with fractional crystallization simulation models and experimental results and utilized trace element modeling combined with Rayleigh fractionation calculations to re-examine fractional crystallization processes in generating rhyolites. Both qualitative and quantitative studies indicate that andesites, rather than rhyolites, originate by fractional crystallization from basalts in the MOT. Furthermore, we established two batch-melting models for the MOT rhyolites and proposed that type 1 rhyolites are produced by remelting of andesites with amphiboles in the residue, while type 2 rhyolites are derived from remelting of andesites without residual amphiboles. It is difficult to produce melts with a SiO2 content ranging from 62% to 68% either by magmatic differentiation from basalts or by remelting of andesites, and this difficulty might help account for the compositional gap (Daly gap) for bimodal volcanism in the Okinawa Trough.

Hydrothermally-altered dacite terrains in the Methana peninsula Greece: Relevance to Mars

NASA Astrophysics Data System (ADS)

Cloutis, Edward A.; Jonatanson, Victoria; Bandfield, Joshua L.; Amador, Elena S.; Rivera-Hernández, Frances; Mann, P.; Mertzman, Stanley A.

2017-04-01

Dacitic rocks, often indicative of crustal recycling on Earth, have been identified in some regions on Mars, as have possible hydrothermally/aqueously-altered dacites. To enable more robust identification of unaltered and altered dacites on Mars and other planetary bodies, we undertook a spectroscopic-structural-compositional study of altered and unaltered dacites from a dacitic volcanic region in Methana, Greece. Dacites erupted in this region range from fresh to pervasively hydrothermally altered, resulting in friable, Si-enriched products, as well as fumarolic deposition of Si and S-rich precipitates. Spectrally, fresh dacites are unremarkable in the 0.35-2.5 μm region with low, generally flat, reflectance and few, if any, absorption bands. Dacite infrared spectra exhibit Si-O absorption features in the 8-10 μm region (which are characteristic of Si-bearing rocks, in general). With increasing alteration, reflectance over the 0.35-2.5 μm range increases, absorption bands in the 1.4 and 1.9 μm region, associated with H2O/OH, and in the 2.2-2.3 μm region, associated with SiOH, become deeper, Fe3+-associated absorption bands in the 0.43 and 0.9 μm region appear, and the Christiansen feature near 8 μm moves to shorter wavelengths. Silica-rich coatings appear to be spectrally indistinguishable from Si-rich alteration. Alteration-formed sulfates may be detectable by the presence of diagnostic absorption features in the 0.35-2.5 μm region. Spectral similarities between different poorly crystalline high-Si phases make it difficult to uniquely determine the processes that formed high-Si surfaces that have been identified on Mars. However, the samples described here show a variety of spectral features that correspond to variable amounts of alteration. We find a similar range of spectral features, likely due to similar phases, on Mars, perhaps indicating a similar range of alteration environments. Comparison of laboratory spectra to Mars observational data also

From dome to dust: shallow crystallization and fragmentation of conduit magma during the 2004-2006 dome extrusion of Mount St. Helens, Washington: Chapter 19 in A volcano rekindled: the renewed eruption of Mount St. Helens, 2004-2006

USGS Publications Warehouse

Cashman, Katharine V.; Thornber, Carl R.; Pallister, John S.; Sherrod, David R.; Scott, William E.; Stauffer, Peter H.

2008-01-01

Comparison of eruptive conditions during the 2004-6 activity at Mount St. Helens with those of other spine-forming eruptions suggests that magma ascent rates of about 10-4 m/s or less allow sufficient degassing and crystallization within the conduit to form large volcanic spines of intermediate composition (andesite to dacite). Solidification deep within the conduit, in turn, requires transport of the solid plug over long distances (hundreds of meters); resultant large strains are responsible for extensive brittle breakage and development of thick gouge zones. Moreover, similarities between gouge textures and those of ash emitted by explosions from spine margins indicate that fault gouge is the origin for the ash. As the comminution and generation of ash-sized particles was clearly a multistep process, this observation suggests that fragmentation preceded, rather than accompanied, these explosions.

Surface configuration as an explanation for lithology-related cross-polarized radar image anomalies

NASA Technical Reports Server (NTRS)

Mccauley, J. R.

1973-01-01

One problem that has persisted since the development of multipolarized radar is the cause or causes of differential depolarization which is expressed as tonal reversals between like- and cross-polarized images of certain outcrops. Rocks producing anomalously low returns on the cross-polarized image could be classed into three general types: (1) certain geologically recent lava flows (late Pleistocene and Holocene), (2) some tertiary volcanics and (3) certain massive sandstones. Differential depolarization has been produced by volcanic rocks of various compositions including rhyolite, rhyodacite, dacite, andesite, and basalt. This has led to the conclusion that differential depolarization is not directly caused by any compositional factor. However, the study of aerial photos and subsequent field observation have led to the conclusion that the weathering and other surface characteristics of the outcrops are responsible for their appearance on multipolarized imagery.

The rise and fall of periodic 'drumbeat' seismicity at Tungurahua volcano, Ecuador

NASA Astrophysics Data System (ADS)

Bell, Andrew F.; Hernandez, Stephen; Gaunt, H. Elizabeth; Mothes, Patricia; Ruiz, Mario; Sierra, Daniel; Aguaiza, Santiago

2017-10-01

Highly periodic 'drumbeat' long period (LP) earthquakes have been described from several andesitic and dacitic volcanoes, commonly accompanying incremental ascent and effusion of viscous magma. However, the processes controlling the occurrence and characteristics of drumbeat, and LP earthquakes more generally, remain contested. Here we use new quantitative tools to describe the emergence, evolution, and degradation of drumbeat LP seismicity at the andesitic Tungurahua volcano, Ecuador, in April 2015. The signals were recorded during an episode of minor explosive activity and ash emission, without lava effusion, and are the first to be reported at Tungurahua during the ongoing 17 yrs of eruption. Following four days of high levels of continuous and 'pulsed' tremor, highly-periodic LP earthquakes first appear on 10 April. Over the next four days, inter-event times and event amplitudes evolve through a series of step-wise transitions between stable behaviors, each involving a decrease in the degree of periodicity. Families of similar waveforms persist before, during, and after drumbeat activity, but the activity levels of different families change coincidentally with transitions in event rate, amplitude, and periodicity. A complex micro-seismicity 'initiation' sequence shows pulse-like and stepwise changes in inter-event times and amplitudes in the hours preceding the onset of drumbeat activity that indicate a partial de-coupling between event size and rate. The observations increase the phenomenology of drumbeat LP earthquakes, and suggest that at Tungurahua they result from gas flux and rapid depressurization controlled by shear failure of the margins of the ascending magma column.

Pre-eruptive magmatic conditions at Augustine Volcano, Alaska, 2006: Evidence from amphibole geochemistry and textures

USGS Publications Warehouse

De Angelis, Sarah; Larsen, Jessica D; Coombs, Michelle L.

2013-01-01

Variations in the geochemistry and texture of amphibole phenocrysts erupted from Augustine Volcano in 2006 provide new insights into pre- and syn-eruptive magma storage and mixing. Amphiboles are rare but present in all magma compositions (low- to high-silica andesites) from the 3 month long eruption. Unzoned magnesiohornblende in the high- and low-silica andesites exhibit limited compositional variability, relatively high SiO2 (up to 49·7 wt %), and relatively low Al2O3 (< 11·1 wt %). Intermediate-silica andesites and quenched mafic enclaves contain amphiboles that vary in composition (e.g. SiO2 40·8–48·9 wt %, Al2O3 6·52–15·2 wt %) and classification (magnesiohornblende–magnesiohastingsite–tschermakite). Compositional variation in amphibole is primarily controlled by temperature-dependent substitutions. Both high- and low-silica andesites represent remnant magmas that were stored in the shallow crust at 4–8 km depth, remaining distinct owing to a complex subsurface plumbing system. Intermediate-silica andesites and quenched mafic inclusions represent pre-eruptive hybrids of resident high- and low-silica andesite magmas and an intruding basalt. Amphiboles in explosive phase high-silica andesites are largely euhedral and unreacted, consistent with the high magma flux rates from depth during this phase (up to 13 800 m3 s–1). Phenocrysts from the other lithologies have reaction rims that range from 1 to >1000 μm in thickness. Reaction rim microlite sizes correlate with reaction rim thicknesses. Reaction rims <50 μm thick contain microlites 1–10 μm in length whereas reaction rims >80 μm thick contain microlites 10–100 μm in length. Differentiating between heating- and decompression-induced amphibole reaction rim formation is problematic because of a lack of experimental constraints. We attempt a new approach to assessing reaction rim formation, based on a kinetic theory of crystal nucleation and growth, in which the differences in reaction

Geology and radiometric dating of Quaternary monogenetic volcanism in the western Zacapu lacustrine basin (Michoacán, México): implications for archeology and future hazard evaluations

NASA Astrophysics Data System (ADS)

Reyes-Guzmán, Nanci; Siebe, Claus; Chevrel, Magdalena Oryaëlle; Guilbaud, Marie-Noëlle; Salinas, Sergio; Layer, Paul

2018-02-01

The Zacapu lacustrine basin is located in the north-central part of the Michoacán-Guanajuato volcanic field (MGVF), which constitutes the west-central segment of the Trans-Mexican Volcanic Belt. Geological mapping of a 395 km2 quadrangle encompassing the western margin of the basin, 40Ar/39Ar and 14C radiometric dating, whole-rock chemical and petrographic analyses of volcanic products provide information on the stratigraphy, erupted volumes, age, and composition of the volcanoes. Although volcanism in the MGVF initiated since at least 5 Ma ago, rocks in the western Zacapu lacustrine basin are all younger than 2.1 Ma. A total of 47 volcanoes were identified and include 19 viscous lava flows ( 40 vol.%), 17 scoria cones with associated lava flows ( 36 vol.%), seven lava shields ( 15 vol.%), three domes ( 6 vol.%), and one maar ( 2 vol.%). Erupted products are dominantly andesites with 42 km3 ( 86 vol.%) followed by 4 km3 of dacite ( 8 vol.%), 1.4 km3 of basaltic trachy-andesite ( 3 vol.%), 1 km3 of basaltic andesite ( 2 vol.%), and 0.14 km3 of rhyolite ( 0.3 vol.%). Eruptive centers are commonly aligned ENE-WSW following the direction of the regional Cuitzeo Fault System. Over time, the high frequency of eruptions and consequent accumulation of lavas and pyroclastic materials pushed the lake's shore stepwise toward the southeast. Eruptions appear to have clustered through time. One cluster occurred during the Late Pleistocene between 27,000 and 21,300 BC when four volcanoes erupted. A second cluster formed during the Late Holocene, between 1500 BC and AD 900, when four closely spaced monogenetic vents erupted forming thick viscous `a'a to blocky flows on the margin of the lacustrine flats. For still poorly understood reasons, these apparently inhospitable lava flows were attractive to human settlement and eventually became one of the most densely populated heartlands of the pre-Hispanic Tarascan civilization. With an average eruption recurrence interval of 900

Application of the FINDER system to the search for epithermal vein gold-silver deposits : Kushikino, Japan, a case study

USGS Publications Warehouse

Singer, Donald A.; Kouda, Ryoichi

1991-01-01

The FINDER system employs geometric probability, Bayesian statistics, and the normal probability density function to integrate spatial and frequency information to produce a map of probabilities of target centers. Target centers can be mineral deposits, alteration associated with mineral deposits, or any other target that can be represented by a regular shape on a two dimensional map. The size, shape, mean, and standard deviation for each variable are characterized in a control area and the results applied by means of FINDER to the study area. The Kushikino deposit consists of groups of quartz-calcite-adularia veins that produced 55 tonnes of gold and 456 tonnes of silver since 1660. Part of a 6 by 10 km area near Kushikino served as a control area. Within the control area, data plotting, contouring, and cluster analysis were used to identify the barren and mineralized populations. Sodium was found to be depleted in an elliptically shaped area 3.1 by 1.6 km, potassium was both depleted and enriched locally in an elliptically shaped area 3.0 by 1.3 km, and sulfur was enriched in an elliptically shaped area 5.8 by 1.6 km. The potassium, sodium, and sulfur content from 233 surface rock samples were each used in FINDER to produce probability maps for the 12 by 30 km study area which includes Kushikino. High probability areas for each of the individual variables are over and offset up to 4 km eastward from the main Kushikino veins. In general, high probability areas identified by FINDER are displaced from the main veins and cover not only the host andesite and the dacite-andesite that is about the same age as the Kushikino mineralization, but also younger sedimentary rocks, andesite, and tuff units east and northeast of Kushikino. The maps also display the same patterns observed near Kushikino, but with somewhat lower probabilities, about 1.5 km east of the old gold prospect, Hajima, and in a broad zone 2.5 km east-west and 1 km north-south, centered 2 km west of the

Geology of the Orcopampa 30 minute quadrangle, southern Peru with special focus on the evolution of the Chinchon and Huayta calderas

NASA Astrophysics Data System (ADS)

Swanson, Kirk Edward

The 30 minute Orcopampa quadrangle, southern Peru, was a site of several episodes of Neogene volcanism, hydrothermal activity and precious-metal mineralization. Lavas of pyroxene andesite and associated silicic tuffs of the early Miocene Santa Rosa volcanics are the remnants of stratovolcanoes overlying an irregular erosional surface developed on a transgressive Mesozoic marine succession. Major ash-flow volcanism then resulted in the 20.1 Ma Manto Tuff and the associated Chinchon caldera. Deep dissection, locally >2 km, has exposed the steep caldera margin, slide blocks and related (19.9 Ma) dikes. Flows and domes of hornblende-biotite dacite comprising the Sarpane volcanics were erupted between about 18.5--19.5 Ma over much of the northern part of the quadrangle. Early Miocene rocks were folded during the Quechua I tectonic event, and related ENE-trending normal faults host the 17.8 Ma Ag-Au veins of the Orcopampa district. Eruption of the ca. 11.6 Ma tuffs of Cerro Huayta and Cerro Hospicio resulted in formation of the Huayta caldera, nested within the northern part of the Chinchon caldera. Caldera formation was associated with, and followed by, the eruption of intermediate lavas of Cerro Sahuarque ( ca. 11.4 Ma) and the emplacement of rhyolite domes. The adularia-sericite type Au-Ag veins of Mina Shila were formed along the southern margin of the Huayta caldera several million years after collapse. The 7.3 Ma tuff of Laguna Pariguanas, erupted from vents northeast of the Huayta caldera, appears to be deformed; however, the 6.2 Ma tuff of Umachulco postdates Quechua II/III tectonism. Flows and domes of the ca. 7.2 Ma andesite of Cerro Aseruta were emplaced within the Huayta caldera, and approximately contemporaneous lavas of silicic to intermediate composition were erupted in the northern part of the quadrangle. A large area of largely barren acid-sulfate alteration (Chuchanne) formed within the Huayta caldera shortly after the eruption of the andesite of Cerro

Permian arc evolution associated with Panthalassa subduction along the eastern margin of the South China block, based on sandstone provenance and U-Pb detrital zircon ages of the Kurosegawa belt, Southwest Japan

NASA Astrophysics Data System (ADS)

Hara, Hidetoshi; Hirano, Miho; Kurihara, Toshiyuki; Takahashi, Toshiro; Ueda, Hayato

2018-01-01

We have studied the petrography, geochemistry, and detrital zircon U-Pb ages of sandstones from shallow-marine forearc sediments, accretionary complexes (ACs), and metamorphosed accretionary complexes (Meta-ACs) within the Kurosegawa belt of Southwest Japan. Those rocks formed in a forearc region of a Permian island arc associated with subduction of the Panthalassa oceanic crust along the eastern margin of the South China block (Yangtze block). The provenance of the shallow-marine sediments was dominated by basaltic to andesitic volcanic rocks and minor granitic rocks during the late Middle to Late Permian. The ACs were derived from felsic to andesitic volcanic rocks during the Late Permian. The provenance of Meta-ACs was dominated by andesitic volcanic rocks in the Middle Permian. The provenance, source rock compositions, and zircon age distribution for the forearc sediments, ACs and Meta-ACs have allowed us to reconstruct the geological history of the Permian arc system of the Kurosegawa belt. During the Middle Permian, the ACs were accreted along the eastern margin of the South China block. The Middle Permian arc was an immature oceanic island arc consisting of andesitic volcanic rocks. During the Late Permian, the ACs formed in a mature arc, producing voluminous felsic to andesitic volcanic rocks. A forearc basin developed during the late Middle to Late Permian. Subsequently, the Middle Permian ACs and part of the Late Permian AC underwent low-grade metamorphism in the Late to Early Jurassic, presenting the Meta-ACs.

Pre-eruptive storage conditions of the Holocene dacite erupted from Kizimen Volcano, Kamchatka

USGS Publications Warehouse

Browne, B.; Izbekov, P.; Eichelberger, J.; Churikova, T.

2010-01-01

This study describes an investigation of the pre-eruptive conditions (T, P and fO2) of dacite magma erupted during the KZI cycle (12,000-8400 years ago) of Kizimen Volcano, Kamchatka, the earliest, most voluminous and most explosive eruption cycle in the Kizimen record. Hydrothermal, water-saturated experiments on KZI dacite pumice coupled with titanomagnetite-ilmenite geothermometry calculations require that the KZI dacite existed at a temperature of 823 ?? 20??C and pressures of 125-150 MPa immediately prior to eruption. This estimate corresponds to a lithologic contact between Miocene volcaniclastic rocks and Pliocene-Pleistocene volcanic rocks located at a depth of 5-6 km beneath the Kizimen edifice, which may have facilitated the accumulation of atypically large volumes of gas-rich dacite during the KZI cycle.

Plagioclase zonation styles in hornblende gabbro inclusions from Little Glass Mountain, Medicine Lake volcano, California: Implications for fractionation mechanisms and the formation of composition gaps

USGS Publications Warehouse

Brophy, J.G.; Dorais, M.J.; Donnelly-Nolan, J.; Singer, B.S.

1997-01-01

The rhyolite of Little Glass Mountain (73-74% SiO2) is a single eruptive unit that contains inclusions of quenched andesite liquid (54-61% SiO2) and partially crystalline cumulate hornblende gabbro (53-55% SiO2). Based on previous studies, the quenched andesite inclusions and host rhyolite lava are related to one another through fractional crystallization and represent an example of a fractionation-generated composition gap. The hornblende gabbros represent the cumulate residue associated with the rhyolite-producing and composition gap-forming fractionation event. This study combines textural (Nomarski Differential Interference Contrast, NDIC, imaging), major element (An content) and trace element (Mg, Fe, Sr, K, Ti, Ba) data on the style of zonation of plagioclase crystals from representative andesite and gabbro inclusions, to assess the physical environment in which the fractionation event and composition gap formation took place. The andesite inclusions (54-61% SiO2) are sparsely phyric with phenocrysts of plagioclase, augite and Fe-oxide??olivine, +/-orthopyroxene, +/-hornblende set within a glassy to crystalline matrix. The gabbro cumulates (53-55% SiO2) consist of an interconnected framework of plagioclase, augite, olivine, orthopyroxene, hornblende and Fe-oxide along with highly vesicular interstitial glass (70-74% SiO2). The gabbros record a two-stage crystallization history of plagioclase + olivine + augite (Stage I) followed by plagioclase+orthopyroxene + hornblende + Fe-oxide (Stage II). Texturally, the plagioclase crystals in the andesite inclusions are characterized by complex, fine-scale oscillatory zonation and abundant dissolution surfaces. Compositionally (An content) the crystals are essentially unzoned from core-to-rim. These features indicate growth within a dynamic (convecting?), reservoir of andesite magma. In contrast, the plagioclase crystals in the gabbros are texturally smooth and featureless with strong normal zonation from An74 at the

Effusive silicic volcanism in the Paraná Magmatic Province, South Brazil: Evidence for locally-fed lava flows and domes from detailed field work

NASA Astrophysics Data System (ADS)

Polo, L. A.; Janasi, V. A.; Giordano, D.; Lima, E. F.; Cañon-Tapia, E.; Roverato, M.

2018-04-01

Lava flows and dome complexes of silicic composition were identified in the Lower Cretaceous Paraná Magmatic Province (PMP) at Rio Grande do Sul state, southern Brazil. Detailed mapping and image analysis reveals significant volumes of effusive deposits aligned according to main lineaments, likely representing the fissural systems that fed the three Palmas-type silicic units. Different structures indicative of effusive emplacement (lava domes, lobated flows, sheet flows and autobreccias) are very common in the study area, and are probably also more abundant than previously thought in whole PMP silicic magmatism. In fact, effusive deposits seem predominant in the three distinct silicic units identified in the area, since no remnants of pyroclastic components have been identified. The vitreous dacites that make up the upper flows of the basaltic andesite to dacite Barros Cassal sequence are clearly effusive, as indicated by their occurrence as thin sheet flows. The much thicker early Caxias do Sul dacites occur mostly as lava flow lobes and pancake-like, of low to moderate viscosity, and lava domes. The younger, high SiO2 Santa Maria rhyolite unit shows unequivocal examples of effusive deposits at its lower portion, as lobated flows formed by vesicle-rich obsidian. In spite of higher viscosities relative to the previous units ( 106 Pa·s), it is probable that the very low H2O contents 1 wt% of these rhyolite melts, associated with high discharge rates, resulted in an effusive nature in most to this unit.

Petrologic, tectonic, and metallogenic evolution of the Ancestral Cascades magmatic arc, Washington, Oregon, and northern California

USGS Publications Warehouse

du Bray, Edward A.; John, David A.

2011-01-01

Present-day High Cascades arc magmatism was preceded by ~40 m.y. of nearly cospatial magmatism represented by the ancestral Cascades arc in Washington, Oregon, and northernmost California (United States). Time-space-composition relations for the ancestral Cascades arc have been synthesized from a recent compilation of more than 4000 geochemical analyses and associated age data. Neither the composition nor distribution of ancestral Cascades magmatism was uniform along the length of the ancestral arc through time. Initial (>40 to 36 Ma) ancestral Cascades magmatism (mostly basalt and basaltic andesite) was focused at the north end of the arc between the present-day locations of Mount Rainier and the Columbia River. From 35 to 18 Ma, initial basaltic andesite and andesite magmatism evolved to include dacite and rhyolite; magmatic activity became more voluminous and extended along most of the arc. Between 17 and 8 Ma, magmatism was focused along the part of the arc coincident with the northern two-thirds of Oregon and returned to more mafic compositions. Subsequent ancestral Cascades magmatism was dominated by basaltic andesite to basalt prior to the post–4 Ma onset of High Cascades magmatism. Transitional tholeiitic to calc-alkaline compositions dominated early (before 40 to ca. 25 Ma) ancestral Cascades eruptive products, whereas the majority of the younger arc rocks have a calc-alkaline affinity. Tholeiitic compositions characteristic of the oldest ancestral arc magmas suggest development associated with thin, immature crust and slab window processes, whereas the younger, calc-alkaline magmas suggest interaction with thicker, more evolved crust and more conventional subduction-related magmatic processes. Presumed changes in subducted slab dip through time also correlate with fundamental magma composition variation. The predominance of mafic compositions during latest ancestral arc magmatism and throughout the history of modern High Cascades magmatism probably

Impact of Magmatism on the Geodynamic Evolution of Southern Georgia on the Example of the Lesser Caucasus Artvin-Bolnisi Block.

NASA Astrophysics Data System (ADS)

Sadradze, Nino; Adamia, Shota; Zakariadze, Guram; Beridze, Tamara; Khutsishvili, Sophio

2017-04-01

The Georgian region occupies the central part of the collisional zone between the Eurasian and Africa-Arabian continents and is actually a collage of lithospheric fragments of the Tethyan Ocean and its northern and southern continental margins. Magmatic evolution is an important event in the formation and development of the geological structure of Southern Georgia, where several reliably dated volcanogenic and volcanogenic-sedimentary formations are established. The region represents a modern analogue of continental collision zone, where subduction-related volcanic activity lasted from Paleozoic to the end of Paleogene. After the period of dormancy in the Early-Middle Miocene starting from the Late Miocene and as far as the end of the Pleistocene, primarily subaerial volcanic eruptions followed by formation of volcanic highlands and plateaus occurred in the reigon. The Upper Miocene to Holocene volcanic rocks are related to the transverse Van-Transcaucasian uplift and belong to post-collisional calc- alkaline basalt-andesite-dacite-rhyolite series. A system of island arc and intra-arc rift basins (Artvin-Bolnisi and Achara-Trialeti) have been interpreted as characteristic of the pre-collisional stage of the region development, while syn- post-collisional geodynamic events have been attributed to intracontinental stage. Outcrops of the postcollisional magmatic rocks are exposed along the boundaries of the major tectonic units of the region. The Artvin-Bolnisi unit forms the northwestern part of the Lesser Caucasus and represents an island arc domain of so called the Somkheto-Karabakh Island Arc or Baiburt-Garabagh-Kapan belt. It was formed mainly during the Jurassic-Eocene time interval on the southern margin of the Eurasian plate by nort-dipping subduction of the Neotethys Ocean and subsequent collision to the Anatolia-Iranian continental plate. The Artvin-Bolnisi unit, including the Bolnisi district, was developing as a relatively uplifted island arc-type unit

Extensional Volcanism of the Taos Plateau Volcanic Field, Northern Rio Grande Rift, USA: New Insights from Geologic Mapping, 40Ar/39Ar Geochronology, Geochemistry and Geophysical Modeling

NASA Astrophysics Data System (ADS)

Thompson, R. A.; Turner, K. J.; Cosca, M. A.; Drenth, B.; Grauch, V. J. S.

2016-12-01

The Pliocene Taos Plateau Volcanic Field (TPVF) is the largest volcanic field of the Rio Grande rift. Deposits of the TPVF are distributed across 4500 km2 in the southern part of the 11,500 km2 San Luis Valley in southern Colorado and northern New Mexico constituting a major component of the structural San Luis Basin (SLB) fill. Exposed deposit thicknesses range from a few meters near the distal termini of basaltic lava flows to 240 m in the Rio Grande gorge near Taos, NM. New geologic mapping and 100 high-resolution 40Ar/39Ar age determinations help identify a complex distribution of >50 exposed eruptive centers ranging in composition from basalt to rhyolite. Total eruptive volume, estimated from geologic map relations, geophysical modeling of basin geometry and subsurface distribution of basaltic deposits, are approximately 300 km3; comprising 66% Servilleta Basalt (tholeiite), 3% mildly alkaline trachybasalt & trachyandesite, 12% olivine andesite, 17% dacite, and <1% rhyolite. Servilleta Basalt is preserved throughout the TPVF, ranging in age from 5.3 Ma to 2.95 Ma; maximum thickness is exposed in the Rio Grande gorge in association with the largest Pliocene sub-basin in the valley, the Taos graben. Smaller volume basalt centers as young as 2.9 Ma are spatially associated with monogenetic trachybasalt and trachyandesite centers ( 4.3 Ma to 2.8 Ma) along the uplifted footwall of a western fault-bounded sub-basin, the Las Mesitas graben. The plateau surface underlain primarily by Servilleta Basalt is punctuated by large ( 15 km3 erupted volume typical) monogenetic andesitic shield volcanoes ( 5-4.4 Ma); north-south aligned and distributed along the central axis of the SLB, parallel to major intrabasin faults. Large (up to 21 km3 erupted volume) zoned dacitic lava dome complexes ( 5 Ma Guadalupe Mountain/Cerro Negro, 3.9 Ma Ute Mountain, and 3 Ma San Antonio Mountain) reach elevations of 3300 m, 770 m above the valley floor each spatially and temporally associated

Giant magmatic water reservoirs at mid-crustal depth inferred from electrical conductivity and the growth of the continental crust

NASA Astrophysics Data System (ADS)

Laumonier, Mickael; Gaillard, Fabrice; Muir, Duncan; Blundy, Jon; Unsworth, Martyn

2017-01-01

The formation of the continental crust at subduction zones involves the differentiation of hydrous mantle-derived magmas through a combination of crystallization and crustal melting. However, understanding the mechanisms by which differentiation occurs at depth is hampered by the inaccessibility of the deep crust in active continental arcs. Here we report new high-pressure electrical conductivity and petrological experiments on hydrated andesitic melt from Uturuncu volcano on the Bolivian Altiplano. By applying our results to regional magnetotelluric data, we show that giant conductive anomalies at mid-crustal levels in several arcs are characterized by relatively low amounts of intergranular andesitic partial melts with unusually high dissolved water contents (≥8 wt.% H2O). Below Uturuncu, the Altiplano-Puna Magma Body (APMB) displays an electrical conductivity that requires high water content (up to 10 wt.%) dissolved in the melt based on crystal-liquid equilibria and melt H2O solubility experiments. Such a super-hydrous andesitic melt must constitute about 10% of the APMB, the remaining 90% being a combination of magmatic cumulates and older crustal rocks. The crustal ponding level of these andesites at around 6 kbar pressure implies that on ascent through the crust hydrous magmas reach their water saturation pressure in the mid-crust, resulting in decompression-induced crystallization that increases magma viscosity and in turn leads to preferential stalling and differentiation. Similar high conductivity features are observed beneath the Cascades volcanic arc and Taupo Volcanic Zone. This suggests that large amounts of water in super-hydrous andesitic magmas could be a common feature of active continental arcs and may illustrate a key step in the structure and growth of the continental crust. One Sentence Summary: Geophysical, laboratory conductivity and petrological experiments reveal that deep electrical conductivity anomalies beneath the Central Andes

Petrological constraints on the high-Mg basalts from Capo Marargiu (Sardinia, Italy): Evidence of cryptic amphibole fractionation in polybaric environments

NASA Astrophysics Data System (ADS)

Tecchiato, Vanni; Gaeta, Mario; Mollo, Silvio; Scarlato, Piergiorgio; Bachmann, Olivier; Perinelli, Cristina

2018-01-01

This study deals with the textural and compositional characteristics of the calc-alkaline stratigraphic sequence from Capo Marargiu Volcanic District (CMVD; Sardinia island, Italy). The area is dominated by basaltic to intermediate hypabyssal (dikes and sills) and volcanic rocks (lava flows and pyroclastic deposits) emplaced during the Oligo-Miocene orogenic magmatism of Sardinia. Interestingly, a basaltic andesitic dome hosts dark-grey, crystal-rich enclaves containing up 50% of millimetre- to centimetre-sized clinopyroxene and amphibole crystals. This mineral assemblage is in equilibrium with a high-Mg basalt recognised as the parental magma of the entire stratigraphic succession at CMVD. Analogously, centimetre-sized clots of medium- and coarse-grained amphibole + plagioclase crystals are entrapped in andesitic dikes that ultimately intrude the stratigraphic sequence. Amphibole-plagioclase cosaturation occurs at equilibrium with a differentiated basaltic andesite. Major and trace element modelling indicates that the evolutionary path of magma is controlled by a two-step process driven by early olivine + clinopyroxene and late amphibole + plagioclase fractionation. In this context, enclaves represent parts of a cumulate horizon segregated at the early stage of differentiation of the precursory high-Mg basalt. This is denoted by i) resorption effects and sharp transitions between Mg-rich and Mg-poor clinopyroxenes, indicative of pervasive dissolution phenomena followed by crystal re-equilibration and overgrowth, and ii) reaction minerals found in amphibole coronas formed at the interface with more differentiated melts infiltrating within the cumulate horizon, and carrying the crystal-rich material with them upon eruption. Coherently, the mineral chemistry and phase relations of enclaves indicate crystallisation in a high-temperature, high-pressure environment under water-rich conditions. On the other hand, the upward migration and subsequent fractionation of the

Volcanic Eruption Forecasts From Accelerating Rates of Drumbeat Long-Period Earthquakes

NASA Astrophysics Data System (ADS)

Bell, Andrew F.; Naylor, Mark; Hernandez, Stephen; Main, Ian G.; Gaunt, H. Elizabeth; Mothes, Patricia; Ruiz, Mario

2018-02-01

Accelerating rates of quasiperiodic "drumbeat" long-period earthquakes (LPs) are commonly reported before eruptions at andesite and dacite volcanoes, and promise insights into the nature of fundamental preeruptive processes and improved eruption forecasts. Here we apply a new Bayesian Markov chain Monte Carlo gamma point process methodology to investigate an exceptionally well-developed sequence of drumbeat LPs preceding a recent large vulcanian explosion at Tungurahua volcano, Ecuador. For more than 24 hr, LP rates increased according to the inverse power law trend predicted by material failure theory, and with a retrospectively forecast failure time that agrees with the eruption onset within error. LPs resulted from repeated activation of a single characteristic source driven by accelerating loading, rather than a distributed failure process, showing that similar precursory trends can emerge from quite different underlying physics. Nevertheless, such sequences have clear potential for improving forecasts of eruptions at Tungurahua and analogous volcanoes.

Tephra Studies of a Violent Strombolian Cinder Cone: Parícutin, Mexico.

NASA Astrophysics Data System (ADS)

Erlund, E. J.; Pioli, L.; Delgado, H.; Cashman, K. V.; Wallace, P. J.

2006-12-01

Explosive eruptions at Parícutin volcano, Mexico, predominated throughout the first 3 years of its nine years of activity (February 1943- February 1952); effusive behaviour dominated the later years as the mass flux decreased. Explosive activity was unsteady and complex, with many blasts and explosions described in eyewitness accounts (Foshag and González, 1956). A detailed look at the tephra deposits reveals this complexity in the details of alternating ash and lapilli layers, where a single unit may consist of tens of eruptive pulses. To place the tephra sequence in the stratigraphic context provided by previous studies of dated lava flow and tephra samples (Wilcox, 1954; Luhr, 2001), we use a combination of bulk rock, matrix glass and olivine phenocryst analyses. Most obvious is the abrupt compositional shift from basaltic-andesite to andesite in 1947 (Wilcox, 1954; McBirney et al, 1987), which is also evident in the matrix glass of our tephra samples. Furthermore, measured olivine compositions of Fo86 Fo82 through the basaltic-andesite tephra sequence bracket Luhr's (2001) analyses from May 1943 to January 1945, thus confirming the completeness of the tephra record. Moreover, as both olivine and matrix glass compositions from within basal tephra layers are more primitive than previously reported analyses, we suggest that tephra deposits may provide a more complete record of the early history of mafic eruptions than the more commonly sampled lava flows. Detailed analysis of sequential tephra layers allows us to assess the relationship between eruption style and compositional change. We use two parameters to track eruption conditions: juvenile components and grain size (ash abundance). All Parícutin tephra deposits comprise three components that differ in density (vesicularity) and crystallinity: tan scoria, black scoria and lava fragments. The tan scoria is the most vesicular and least crystalline, suggesting that it represents magma that rose most quickly

Suprasubduction volcanic rocks of the Char ophiolite belt, East Kazakhstan: new geochemical and first geochronological data

NASA Astrophysics Data System (ADS)

Safonova, Inna; Simonov, Vladimir; Seltmann, Reimar; Yamamoto, Shinji; Xiao, Wenjiao

2016-04-01

The Char ophiolite belt is located in the western Central Asian Orogenic Belt, a world largest accretionary orogen, which has evolved during more than 800 Ma. The Char belt formed during Kazakhstan - Siberia collision. It has been known for hosting fragments of Late Devonian-Early Carboniferous oceanic crust, MORB, OPB and OIB, of the Paleo-Asian Ocean (Safonova et al., 2012). The Char is surrounded by two Paleozoic island-arc terranes: Zharma-Saur in the west and Rudny Altai in the east, however, until recent times, no island-arc units have been found within it. We were the first to find island-arc units as tectonic sheets occurring adjacent to those consisting of oceanic rocks. In places, island-arc andesites cut oceanic basalts. The Char volcanic and subvolcanic rocks of a probable suprasubduction origin are basalt, microgabbro, dolerite, andesite, tonalite and dacite. The mafic to andesitic volcanics possessing low TiO2 (0.85 wt.%av.) and show MgO vs. major elements crystallization trends suggesting two magma series: tholeiitic and calc-alkaline. The tholeiitic varieties are less enriched in incompatible elements then the calc-alkaline ones. Two samples are high-Mg and low-Ti andesibasalts similar to boninites. The rocks possess moderately LREE enriched rare-earth element patterns and are characterized by negative Nb anomalies present on the multi-element spectra (Nb/Lapm = 0.14-0.47; Nb/Thpm = 0.7-1.6).The distribution of rare-earth elements (La/Smn = 0.8-2.3, Gd/Ybn = 0.7-1.9) and the results of geochemical modeling in the Nb-Yb system suggest high degrees of melting of a depleted harzburgite-bearing mantle source at spinel facies depths. Fractional crystallization of clinopyroxene, plagioclase and opaque minerals also affected the final composition of the volcanic rocks. Clinopyroxene monomineral thermometry indicates crystallization of melts at 1020-1180°C. Melt inclusion composition based numerical calculations show that primary melts were derived at 1350

Permian to recent volcanism in northern sumatra, indonesia: a preliminary study of its distribution, chemistry, and peculiarities

NASA Astrophysics Data System (ADS)

Rock, N. M. S.; Syah, H. H.; Davis, A. E.; Hutchison, D.; Styles, M. T.; Lena, Rahayu

1982-06-01

Sumatra has been a ‘volcanic arc’, above an NE-dipping subduction zone, since at least the Late Permian. The principal volcanic episodes in Sumatra N of the Equator have been in the Late Permian, Late Mesozoic, Palaeogene, Miocene and Quaternary. Late Permian volcanic rocks, of limited extent, are altered porphyritic basic lavas interstratified with limestones and phyllites. Late Mesozoic volcanic rocks, widely distributed along and W of the major transcurrent. Sumatra Fault System (SFS), which axially bisects Sumatra, include ophiolite-related spilites, andesites and basalts. Possible Palaeogene volcanic rocks include an altered basalt pile with associated dyke-swarm in the extreme NW, intruded by an Early Miocene (19 my) dioritic stock; and variable pyroxene rich basic lavas and agglomerates ranging from alkali basaltic to absarokitic in the extreme SW. Miocene volcanic rocks, widely distributed (especially W of the SFS), and cropping out extensively along the W coast, include calc-alkaline to high-K calc-alkaline basalts, andesites and dacites. Quaternary volcanoes (3 active, 14 dormant or extinct) are irregularly distributed both along and across the arc; thus they lie fore-arc of the SFS near the Equator but well back-arc farther north. The largest concentration of centres, around Lake Toba, includes the >2000 km3 Pleistocene rhyolitic Toba Tuffs. Quaternary volcanics are mainly calc-alkaline andesites, dacites and rhyolites with few basalts; they seem less variable, but on the whole more acid, than the Tertiary. The Quaternary volcanism is anomalous in relation to both southern Sumatra and adjacent Java/Bali: in southern Sumatra, volcanoes are regularly spaced along and successively less active away from the SFS, but neither rule holds in northern Sumatra. Depths to the subduction zone below major calc-alkaline volcanoes in Java/Bali are 160-210 km, but little over 100 km in northern Sumatra, which also lacks the regular K2O-depth correlations seen in

Apatite sulfur systematics and crystal population in the 1991 Pinatubo magmas

NASA Astrophysics Data System (ADS)

van Hoose, A. E.; Streck, M. J.; Pallister, J. S.

2010-12-01

On June 15, 1991, Mount Pinatubo, Philippines, ejected 20 mega-tonnes of sulfur dioxide into the atmosphere, significantly impacting global climate and stratospheric ozone. Recharging basaltic magma mixed into the 50 km3 dacitic magma reservoir 6 to 11 km beneath Mount Pinatubo, and triggered the 1991 eruption. The result of the magma mixing was a hybrid andesite with quenched basalt inclusions that erupted as a dome between June 7 and June 12. On June 15, approximately 5 km3 of anhydrite bearing magma was erupted from the main phenocryst-rich dacitic reservoir. We are using this extraordinary framework of the 1991 Pinatubo eruption to investigate the systematics of sulfur uptake by apatite in order to further develop apatite as a monitor for magmatic sulfur. In the dacite and hybrid andesite, apatite occurs as individual phenocrysts (up to ~200 μm diameter) or included within anhydrite, hornblende, and plagioclase phenocrysts. In the basaltic magmatic inclusions, apatite is found as acicular microphenocrysts. Electron microprobe data collected on apatite yield low- (<0.3 SO3 wt.%), medium- (0.3-0.7 SO3 wt.%), and high-sulfur (>0.7 SO3 wt.%) apatites in all juvenile products, and show that two distinct populations of apatites exist. Apatites crystallizing from silicic melt have predominantly low- to medium-sulfur contents, but high-sulfur apatites with as much as 1.2-1.6 wt.% SO3 occur sporadically and are always found in close proximity to anhydrite. Except for a few low-sulfur apatites, apatite in the basalt is always sulfur-rich with compositions forming a continuous array between 0.9 to 2.4 wt.% SO3. The population of apatite that crystallized from silicic melt has elevated cerium, fluorine, and chlorine and lower magnesium concentrations (average dacite values in wt.%: 0.22 Ce2O3; 1.4 F; 1.1 Cl, 0.14 MgO ;) relative to the population of apatite from the basalt (average basalt values in wt.%: 0.08 Ce2O3; 0.9 F; 0.9 Cl, 0.20 MgO). These compositional

An Integrative Approach for Defining Plinian and Sub-Plinian Eruptive Scenarios at Andesitic Volcanoes: Event-Lithostratigraphy, Eruptive Parameters and Pyroclast Textural Variations of the Largest Late-Holocene Eruptions of Mt. Taranaki, New Zealand.

NASA Astrophysics Data System (ADS)

Torres-Orozco, R.; Cronin, S. J.; Damaschke, M.; Kosik, S.; Pardo, N.

2016-12-01

Three eruptive scenarios were determined based on the event-lithostratigraphic reconstruction of the largest late-Holocene eruptions of the andesitic Mt. Taranaki, New Zealand: a) sustained dome-effusion followed by sudden stepwise collapse and unroofing of gas-rich magma; b) repeated plug and burst events generated by transient open-/closed-vent conditions; and c) open-vent conditions of more mafic magmas erupting from a satellite vent. Pyroclastic density currents (PDCs) are the most frequent outcome in every scenario. They can be produced in any/every eruption phase by formation and either repetitive-partial or total gravity-driven collapse of lava domes in the summit crater (block-and-ash flows), frequently followed by sudden magma decompression and violent, highly unsteady to quasi-steady lateral expansion (blast-like PDCs); by collapse or single-pulse fall-back of unsteady eruption columns (pyroclastic flow- and surge-type currents); or during highly unsteady and explosive hydromagmatic phases (wet surges). Fall deposits are produced during the climatic phase of each eruptive scenario by the emplacement of (i) high, sustained and steady, (ii) sustained and height-oscillating, (iii) quasi-steady and pulsating, or (iv) unsteady and totally collapsing eruption columns. Volumes, column heights and mass- and volume-eruption rates indicate that these scenarios correspond to VEI 4-5 plinian and sub-plinian multi-phase and style-shifting episodes, similar or larger than the most recent 1655 AD activity, and comparable to plinian eruptions of e.g. Apoyeque, Colima, Merapi and Tarawera volcanoes. Whole-rock chemistry, textural reconstructions and density-porosity determinations suggest that the different eruptive scenarios are mainly driven by variations in the density structure of magma in the upper conduit. Assuming a simple single conduit model, the style transitions can be explained by differing proportions of alternating gas-poor/degassed and gas-rich magma.

The study of hydrothermal alteration zones in Kahang exploration area (north eastern of Isfahan, central of Iran) using microscopy studies and TM and Aster satellite data

NASA Astrophysics Data System (ADS)

Zahra Afshooni, Seyedeh; Esmaeily, Dariush

2010-05-01

Kahang ore deposit located in 73 km to the northeast of Isfahan city and 10 km to the east of Zefreh town, covering an area about 18.6 km2. This ore deposit is a part of Uromieh-Dokhtar volcanopolotonic belt. The rocks of the area included Andesite, Porphyritic Andesite, Dacite, Porphyritic, Rhyodacite, Diorite, Quartz Monzonite and Porphyry Micro Granite. In plutons, there is a trend from basic to acid features along with decreasing of age from margin to center of massive. Kahang region is an alteration and breccia zone. The occurrence of alteration zones and iron oxides were confirmed by satellite images processing. Generally, more than 90% of rocks of this region have been affected by hydrothermal fluids. Remote sensing refers to detection and measurement from a distance. For the first time, this exploration area was studied using satellite images processing (TM) and primary results showed that is suitable place for resources of Copper (Cu) and Molybdenum (Mo). Hydrothermal alteration commonly occurs in geothermal areas in association with ore deposits producing alteration assemblages typically dominated by silicates, sulfides, sulfates and carbonates. In the alteration zones studies the subject discussed is the study of existing minerals in such zones and study of chemical specifications of altering fluids. Four alteration zones Based on observations derived from the study of thin sections, XRD analysis and deep remote sensing using TM and Aster satellite images studies could be identified in this area: propylitic alteration zone with chlorite, epidot, calcite; argillic alteration zone with clay minerals; phyllic (qartz-sericite) alteration zone with quartz, sericite and pyrite and silicic alteration zone with abundant quartz.

Reverse Polarity Magnetized Melt Rocks from the Cretaceous/Tertiary Chicxulub Structure, Yucatan Peninsula, Mexico

NASA Technical Reports Server (NTRS)

Urrutia-Fucugauchi, J.; Marin, Luis; Sharpton, Virgil L.

1994-01-01

We report paleomagnetic results for core samples of the breccia and andesitic rocks recovered from the Yucatan-6 Petrolcos Mexicanos exploratory well within the Chicxulub structure (about 60 km SSW from its center), northern Yucatan, Mexico. A previous study has shown that the rocks studied contain high iridium levels and shocked breccia clasts and an Ar/Ar date of 65.2 +/- 0.4 Ma. Andesitic rocks are characterized by stable single-component magnetizations with a mean inclination of -42.6 deg +/- 2.4 deg. Breccias present a complex paleomagnetic record characterized by multivectorial magnetizations with widely different initial NRM inclinations. However, after alternating field demagnetization, well defined characteristic components with upward inclinations are defined. IRM acquisition experiments, comparison of IRM and NRM coercivity spectra and the single component magnetization of the andesitic rocks indicate the occurrence of iron-rich titanomagnetites of single or pseudo-single domain states as the dominant magnetic carriers. Mean inclinations from the andesitic rocks and most of the breccia samples give a mean inclination of about -40 deg to -45 deg, indicating a reverse polarity for the characteristic magnetization that is consistent with geomagnetic chron 29R, which spans the Cretaceous/Tertiary (K/T) boundary. The inclination is also consistent with the expected value (and corresponding paleolatitude) for the site estimated from the reference polar wander curve for North America. We suggest that the characteristic magnetizations for the andesitic and breccia rocks are the result of shock heating at the time of formation of the impact structure and that the age, polarity and pateolatitude are consistent with a time at the K/T boundary.

The Tricky Business of Identifying Rocks on Mars

NASA Astrophysics Data System (ADS)

Taylor, G. J.

2002-05-01

The Mars Global Surveyor mission carries a remote-sensing gizmo called the Thermal Emission Spectrometer (TES). TES detects heat waves flowing from the surface of the Red Planet. The TES team, led by Phil Christensen (Arizona State University), identified two large regions on Mars that have distinctive spectral properties. Using mathematical mixing calculations based on the thermal emission spectra of numerous materials, the TES team reported in papers led by Josh Bandfield and Victoria Hamilton that the two regions had mineral abundances similar to basalt (Surface Type 1) and andesite (Surface Type 2), two common volcanic rock types on Earth. Andesite has more silicon than does basalt, giving rise to a distinctive mineralogy. Scientists had mixed reactions to the possibility of andesite on Mars, greeting the news with fascination, consternation, or skepticism. One question raised is how uniquely the spectra of Surface Type 2 matches andesite. Michael Wyatt and Harry Y. McSween (University of Tennessee) have taken another look at the TES spectra by using a larger collection of aqueous alteration (weathering) products in the spectral mixing calculations. They show that weathered basalt also matches the spectral properties of Surface Type 2. Wyatt and McSween also note that Type 2 regions are generally confined to a large, low region that is the site of a purported Martian ocean that sloshed around billions of years ago. They suggest that basalts like those in Surface Type 1 were altered in the ancient Martian sea. Independent data are needed to test the andesite vs. altered-basalt hypotheses. For now, we may have to be satisfied with at least two working hypotheses and a lively debate.

Installation Restoration Program (IRP) for IRP Sites Numbers 4, 5, 7 and 14. 152 Tactical Reconnaissance Group, Nevada Air National Guard, Reno Tahoe International Airport, Reno, Nevada

DTIC Science & Technology

1996-01-01

For: HQ/ANG/CEVR Andrews AFB, Maryland Prepared By: ERM-West, Inc. 5111. N. Scottsdale Road, Suite 108 ERM Scottsdale, Arizona 85250 FINAL Document...predominantly andesite and andesite porphyry flow rock, hypabyssal intrusives, and minor siliceous welded tuff, which are commonly represented by the Kate...TERTIARY ROCKSI tuslýýj porphyry and olcomic brii I SOURCE ORNL/ETS. 1994 GEOLOGIC MAP OF THE FIGURE 3-1 RENO. NEVADA AREA 152nd TACTICAL RECONNAISSANCE

Volcanic rocks of the McDermitt Caldera, Nevada-Oregon

USGS Publications Warehouse

Greene, Robert C.

1976-01-01

The McDermitt caldera, a major Miocene eruptive center is locatedin the northernmost Great Basin directly west of McDermitt, Nev. The alkali rhyolite of Jordan Meadow was erupted from the caldera and covered an area of about 60,000 sq km; the volume of rhyolite is about 960 cubic km. Paleozoic and Mesozoic sedimentary rocks and Mesozoic granodiorite form the pre-Tertiary Basement in this area.. Overlying these is a series of volcanic rocks, probably all of Miocene age. The lowest is a dacite welded tuff, a reddish-brown rock featuring abundant phenocrysts of plagioclase, hornblende, and biotite; next is a heterogeneous unit consisting of mocks ranging from basalt to dacite. Overlying these is the basalt and andesite of Orevada View, over 700 m thick and consisting of a basal unit of cinder agglutinate overlain by basalt and andesite, much of which contains conspicuous large plagioclase phenocrysts. Near Disaster Peak and Orevada View, the basalt and andesite are overlain by additional units of silicic volcanic rocks. The lower alkali rhyolite welded tuff contains abundant phenocrysts of alkali feldspar and has a vitric phase with obvious pumice and shard texture. The rhyolite of Little Peak consists of a wide variety of banded flows or welded ruffs and breccias, mostly containing abundant alkali feldspar phenocrysts. It extends south from Disaster Peak and apparently underlies the alkali rhyolite of Jordan Meadow. The quartz latite of Sage Creek lies north of Disaster Peak and consists mostly of finely mottled quartz latite with sparse minute plagioclase phenocrysts. Volcanic rock units in the east part of the area near the Cordero mine include trachyandesite, quartz labile of McConnell Canyon, and rhyolite of McCormick Ranch. The trachyandesite is dark gray and contains less than 1 percent microphenocrysts plagioclase. It is the lowest unit exposed and may correlate with part of the basalt and andesite of Orevada View. The quartz latite of McConnell Canyon is

From source to surface: Tracking magmatic boron and chlorine input into the geothermal systems of the Taupo Volcanic Zone, New Zealand

NASA Astrophysics Data System (ADS)

Bégué, Florence; Deering, Chad D.; Gravley, Darren M.; Chambefort, Isabelle; Kennedy, Ben M.

2017-10-01

The magmatic contribution into geothermal fluids in the central Taupo Volcanic Zone (TVZ), New Zealand, has been attributed to either andesitic, 'arc-type' fluids, or rhyolitic, 'rift-type' fluids to explain the compositional diversity of discharge waters. However, this model relies on outdated assumptions related to geochemical trends associated with the magma at depth of typical arc to back-arc settings. Current tectonic models have shown that the TVZ is situated within a rifting arc and hosts magmatic systems dominated by distinct rhyolite types, that are likely to have evolved under different conditions than the subordinate andesites. Therefore, a new appraisal of the existing models is required to further understand the origin of the spatial compositional diversity observed in the geothermal fluids and its relationship to the structural setting. Here, we use volatile concentrations (i.e. H2O, Cl, B) from rhyolitic and andesitic mineral-hosted melt inclusions to evaluate the magmatic contribution to the TVZ geothermal systems. The andesite and two different types of rhyolites (R1 and R2) are each distinct in Cl/H2O and B/Cl, which will affect volatile solubility and phase separation (vapor vs. hydrosaline liquid) of the exsolved volatile phase. Ultimately, these key differences in the magmatic volatile constituents will play a significant role in governing the concentration of Cl discharged into geothermal systems. We estimate bulk fluid compositions (B and Cl) in equilibrium with the different melt types to show the potential contribution of 'parent' fluids to the geothermal systems throughout the TVZ. The results of this analysis show that the variability in fluid compositions partly reflects degassing from previously unaccounted for distinct magma source compositions. We suggest the geothermal systems that appear to have an 'arc-type' andesitic fluid contribution are actually derived from a rhyolite melt in equilibrium with a highly crystalline andesite

Depleted arc volcanism in the Alboran Sea and shoshonitic volcanism in Morocco: geochemical and isotopic constraints on Neogene tectonic processes

NASA Astrophysics Data System (ADS)

Gill, R. C. O.; Aparicio, A.; El Azzouzi, M.; Hernandez, J.; Thirlwall, M. F.; Bourgois, J.; Marriner, G. F.

2004-12-01

Samples of volcanic rocks from Alborán Island, the Alboran Sea floor and from the Gourougou volcanic centre in northern Morocco have been analyzed for major and trace elements and Sr-Nd isotopes to test current theories on the tectonic geodynamic evolution of the Alboran Sea. The Alborán Island samples are low-K tholeiitic basaltic andesites whose depleted contents of HFS elements (˜0.5×N-MORB), especially Nb (˜0.2×N-MORB), show marked geochemical parallels with volcanics from immature intra-oceanic arcs and back-arc basins. Several of the submarine samples have similar compositions, one showing low-Ca boninite affinity. 143Nd/ 144Nd ratios fall in the same range as many island-arc and back-arc basin samples, whereas 87Sr/ 86Sr ratios (on leached samples) are somewhat more radiogenic. Our data point to active subduction taking place beneath the Alboran region in Miocene times, and imply the presence of an associated back-arc spreading centre. Our sea floor suite includes a few more evolved dacite and rhyolite samples with ( 87Sr/ 86Sr) 0 up to 0.717 that probably represent varying degrees of crustal melting. The shoshonite and high-K basaltic andesite lavas from Gourougou have comparable normalized incompatible-element enrichment diagrams and Ce/Y ratios to shoshonitic volcanics from oceanic island arcs, though they have less pronounced Nb deficits. They are much less LIL- and LREE-enriched than continental arc analogues and post-collisional shoshonites from Tibet. The magmas probably originated by melting in subcontinental lithospheric mantle that had experienced negligible subduction input. Sr-Nd isotope compositions point to significant crustal contamination which appears to account for the small Nb anomalies. The unmistakable supra-subduction zone (SSZ) signature shown by our Alboran basalts and basaltic andesite samples refutes geodynamic models that attribute all Neogene volcanism in the Alboran domain to decompression melting of upwelling asthenosphere

Volcanism at Hualca Hualca Volcano, Southern Peru

NASA Astrophysics Data System (ADS)

Burkett, B.

2005-12-01

Nevado Hualca Hualca (6025m), in southern Peru, is the northernmost edifice in a north-south trending chain of 3 volcanoes that includes Ampato and the active Sabancaya stratovolcano. The oldest in the chain and considered extinct, virtually no research exists about the history of this large volcano. The summit of the volcano shows deep incision by glaciation, which from aerial photographs appears unaffected by later volcanism. Its north slope, however, possesses numerous volcanic domes, extensive lava flows with distinct levees and transverse ridges, and pyroclastic flow deposits. Deposits on the northwestern slope of Hualca Hualca include breadcrust-rich block-and-ash flows (BAF), several dacite lava flows including one with an identifiable source dome about 15km from the summit, and a sequence of small pyroclastic flow deposits with minor associated tephra. Analyses of these deposits show a restricted range of compositions (63-68 wt% SiO2). The PF sequence has an upward decrease in SiO2 and basaltic andesite (56 wt% SiO2) inclusions occur in the uppermost PFs. Principal phenocrysts include plagioclase, biotite, hornblende, clinopyroxene, orthopyroxene, Fe-Ti oxides, and sphene. Fine grained, angular to sub-rounded magmatic enclaves occur within the breadcrust-rich BAF deposits and the youngest lava flow. They are characterized by randomly oriented acicular hornblende, lack of chilled margins, and a few voids indicative of a quench texture. Plagioclase crystals with "dusty" rims or cores present in most of the deposits suggest resorption caused by magma recharge. These features imply a stratified magma chamber subject to magma recharge events and mingling to produce the quench texture enclaves. Chemical analyses indicate that the volcanic products result from magma mixing processes; the basaltic andesite inclusions may represent the mafic end-member of the mixing process. The physical characteristics of the deposits and chemical analyses were compared with data

Steady state volcanism - Evidence from eruption histories of polygenetic volcanoes

NASA Technical Reports Server (NTRS)

Wadge, G.

1982-01-01

Cumulative volcano volume curves are presented as evidence for steady-state behavior at certain volcanoes and to develop a model of steady-state volcanism. A minimum criteria of five eruptions over a year was chosen to characterize a steady-state volcano. The subsequent model features a constant head of magmatic pressure from a reservoir supplied from depth, a sawtooth curve produced by the magma arrivals or discharge from the subvolcanic reservoir, large volume eruptions with long repose periods, and conditions of nonsupply of magma. The behavior of Mts. Etna, Nyamuragira, and Kilauea are described and show continuous levels of plasma output resulting in cumulative volume increases. Further discussion is made of steady-state andesitic and dacitic volcanism, long term patterns of the steady state, and magma storage, and the lack of a sufficient number of steady-state volcanoes in the world is taken as evidence that further data is required for a comprehensive model.

Integrated inversion of airborne geophysics over a structural geological unit: A case study for delineation of a porphyry copper zone in Iran

NASA Astrophysics Data System (ADS)

Abedi, Maysam; Fournier, Dominique; Devriese, Sarah G. R.; Oldenburg, Douglas W.

2018-05-01

This work presents the application of an integrated geophysical survey of magnetometry and frequency-domain electromagetic data (FDEM) to image a geological unit located in the Kalat-e-Reshm prospect area in Iran which has good potential for ore mineralization. The aim of this study is to concentrate on a 3D arc-shaped andesite unit, where it has been concealed by a sedimentary cover. This unit consists of two segments; the top one is a porphyritic andesite having potential for ore mineralization, especially copper, whereas the lower segment corresponds to an unaltered andesite rock. Airborne electromagnetic data were used to delineate the top segment as a resistive unit embedded in a sediment column of alluvial fan, while the lower andesite unit was detected by magnetic field data. In our research, the FDEM data were first inverted by a laterally-constrained 1D program to provide three pieces of information that facilitate full 3D inversion of EM data: (1) noise levels associated with the FDEM observations, (2) an estimate of the general conductivity structure in the prospect area, and (3) the location of the sought target. Then EM data inversion was extended to 3D using a parallelized OcTree-based code to better determine the boundaries of the porphyry unit, where a transition exists from surface sediment to the upper segment. Moreover, a mixed-norm inversion approach was taken into account for magnetic data to construct a compact and sharp susceptible andesite unit at depth, beneath the top resistive and non-susceptible segment. The blind geological unit was eventually interpreted based on a combined model of conductivity and magnetic susceptibility acquired from individually inverting these geophysical surveys, which were collected simultaneously.

Magmatic context of Bou Skour copper deposit (Eastern Anti-Atlas, Morocco): Petrogrography, geochemistry and alterations

NASA Astrophysics Data System (ADS)

EL Azmi, Daoud; Aissa, M.; Ouguir, H.; Mahdoudi, M. L.; El Azmi, M.; Ouadjo, A.; Zouhair, M.

2014-09-01

The Bou Skour copper deposit is located in the western part of the Saghro massif (Eastern Anti-Atlas), about 50 km East of the city of Ouarzazate. It is subdivided into several areas that are, from North to South: “Panthère”, “Chaigne”, “Anne Marie”, “Chapeau de fer” and “Patte d'Oie”. The latter is economically the most important and is the object of this study. The “Patte d'Oie” district consists mainly of extrusive and intrusive igneous rocks. The extrusive rocks are represented by andesites spatially associated with pyroclastic terms (ignimbrites and pyroclastic breccias). This volcanic unit is intruded by a pink granite pluton and a I-type granodiorite with equigranular texture (Bou Skour granodiorite) showing to the border a microgranular facies (microgranodiorite). All these magmatic formations are intersected by rhyolitic dykes (NNE-SSW) and doleritic dykes (WNW-ESE to NW-SE). The granodiorite and andesite have undergone a polyphase hydrothermal alteration: (i) potassic alteration, (ii) phyllitic alteration, (iii) silicification, (iv) argillic alteration and (v) propylitic alteration. The analysis of geochemical data of granodiorite, granite, andesite and dolerite confirmed: (i) their petrographic natures, (ii) the medium-K calc-alkaline affiliation of andesite and granodiorite, which would have been set up into an active geotectonic environment, probably of island arc or collision, during the Pan-African orogeny, (iii) The high-K calc-alkaline character of granite indicating a post-collision development during the Pan-African orogeny and (iv) The alkaline affinity of the dolerite which is linked to an extensive post-orogenic setting (post-Pan-African). The copper mineralization of “Patte d'Oie” area is hosted, exclusively, in the andesitic and granodioritic facies. It is represented, essentially, by chalcopyrite and bornite minerals and is, probably, related to a porphyry system (disseminated and stockwork mineralization

Laboratory Studies of High Temperature Deformation and Fracture of Lava Domes

NASA Astrophysics Data System (ADS)

Smith, R.; Sammonds, P.; Tuffen, H.; Meredith, P.

2007-12-01

The high temperature fracture mechanics of magma at high temperatures exerts a fundamental control on the stability of lava domes and the timing and style of eruptions at andesitic to dacitic volcanoes. This is evidenced in the pervasive fracturing seen in both ancient and active magma conduits and lava domes; in addition to the volcanic earthquakes that occur before and during episodes of dome growth and dome collapse. Uniaxial and triaxial deformation experiments have been performed on crystal rich and crystal free magmas (andesite from Ancestral Mount Shasta, California, USA and a rhyolitic obsidian from Krafla, Iceland) at a range of temperatures (up to 900°C), confining pressures (up to 50 MPa) and strain rates (10-5s-1) to 10-3s-1) whilst recording acoustic emissions (AE). Results from these experiments provide useful inputs into models of lava dome stability, extrusion mechanisms, and source mechanisms for volcanic earthquakes. However, the large sample sizes used to ensure valid results (25mm diameter and 75mm length) made it difficult to maintain stable high temperatures under confined conditions. Also, only rudimentary AE data could be obtained, due to the distance of the transducers from the samples to keep them away from the high temperatures. Here, we present modifications to this apparatus, which include a new furnace, improved loading system, additional pore pressure and permeability measurement capability, and vastly improved acoustic monitoring. This allows (1)stable higher temperatures (up to 1000°C) to be achieved under confined conditions, (2) high temperature and moderate pressure (up to 70 MPa) hydrostatic measurements of permeability and acoustic velocities, (3) high temperature triaxial deformation under different pore fluid and pressure conditions, and (4) full waveform AE monitoring for all deformation experiments. This system can thus be used to measure the physical properties and strength of rocks under volcanic conditions and to

Volcanic Debris Flows of the Latest Paleozoic Arbasay Formation: Geomorphological Characters and Paleoenvironment Reconstruction of Northern Tian Shan, NW China

NASA Astrophysics Data System (ADS)

Yang, W.; Liu, D.; Guo, Z.

2015-12-01

Texturally well-preserved volcanic debris flows (also called lahars) are exposed in the Latest Paleozoic Arbasay Formation, Northern Tian Shan. LA-ICP-MS zircon dating of the intercalated fallout tuff sample provided an age of 314.4±3.4 Ma (MSWD=1.6), suggesting they were deposited at Latest Carboniferous. The lahars consist primarily of two lithofacies: massive, poorly lithified diamictites and stratified, moderately lithified gravelly sandstones. The diamictites can be generally divided into two subfacies, i.e., the matrix-supported and the clast-supported diamictites. Most diamictites are structureless and nongraded. They are thick in beds and contain large clasts up to 3 m in dimension. The gravelly sandstones display much finer particle size and have wedge or lenticular geometries. Large clasts are absent within them and the sorting characters are much better than the diamictites. Despite the different size grading, the matrix and the clasts of the two lithofacies appear to be homogeneous. The matrix is generally sandy mudstone. The clasts comprise rhyolites, dacites, andesites, andesitic basalts and basalts, same to the co-existing volcanic rocks, suggesting they originate from the cognate volcanics. The disorganized diamictites are supposed to deposit from a turbulent flood or pyroclastic surge. The gravelly sandstone lithofacies are interpreted as sand-rich flood flows or hyperconcentrated flood flows during the waning stage of a mass-flow event. The overall characteristics of the deposits suggest a mass-flow dominated alluvial fan environment. It's noteable that several syn- sedimentary normal faults occurred within these lahar deposits, indicating that the Southern Junggar Basin was in an extensional regime during the lahars' deposition. Structure is dominated by normal faulting, allowing the existence of relatively small, highly compartmentalized depocenters. This is also supported by geochemistry and detrital zircon studies.

LA-ICP-MS Dating and Tectonic Setting of Yeba Formation Lavas in Qulong Area east Part of the Gangdise Belt, Xizang China

NASA Astrophysics Data System (ADS)

Liu, D.

2009-12-01

In China, Xizang Gangdise tectonic belt is a large nonferrous metal and noble metal mineralized zone and in which, it is found that the mineralization correlates with Tethyan Ocean subduction, continent-continent collision and magmatism due to inter-continent extension orogeny. Qulong porphyry copper (molybdenum) deposit is the largest recently found in the Gangdise metallogenic belt and is one of the most large porphyry copper deposit in Asia. In the area of Qulong porphyry copper deposit, the adjacent strata is Yeba Formation and which can be parted into three members. The first member is built up of dacite, rhyolite, andesite, lapilli tuff, volcanic breccia and volcanic agglomerate. The second member widely occur in the area with major rocks of medium-acidic lava, debris-crystallinoclastic volcanic tuff intercalated with tuffaceous sand, tuffaceous slate and limestone. The third member is built up of andesite, liparite, crystallinoclastic tuff intercalated with sillicalite, sericite slate, tuffaceous sandstone and dirty limestone. The volcanic tuff in the second member gives a LA-ICP-MS U-Pb zircon age of 156.2±2.3 Ma, which may represent the age of the Yeba Formation. That is to say, in the study area, the Yeba Formation comes to being in age of Middle and Later Jurassic. The characteristic which comes from the research on geochronology and rockassociations suggests that the Yeba Formation volcanic rocks are built up by a long time ejection and the ejection of the Yeba Formation volcanic rocks comes from west to east in the Gangdise zone. The volcanic rocks in the Yeba Formation can be considered as the products originated from northward subduction and consumption of the Tethyan Ocean. At the same time, it is proposed that the Yeba Formation volcanic rocks have potential significances in evaluating the early Jurassic biotic crisis, climate change, regression or intrusion event and the later mineralizaion.

Geochemical characterization of a Quaternary monogenetic volcano in Erciyes Volcanic Complex: Cora Maar (Central Anatolian Volcanic Province, Turkey)

NASA Astrophysics Data System (ADS)

Gencalioglu-Kuscu, Gonca

2011-11-01

Central Anatolian Volcanic Province (CAVP) is a fine example of Neogene-Quaternary post-collisional volcanism in the Alpine-Mediterranean region. Volcanism in the Alpine-Mediterranean region comprises tholeiitic, transitional, calc-alkaline, and shoshonitic types with an "orogenic" fingerprint. Following the orogenic volcanism, subordinate, within-plate alkali basalts ( sl) showing little or no orogenic signature are generally reported in the region. CAVP is mainly characterized by widespread calc-alkaline andesitic-dacitic volcanism with orogenic trace element signature, reflecting enrichment of their source regions by subduction-related fluids. Cora Maar (CM) located within the Erciyes pull-apart basin, is an example to numerous Quaternary monogenetic volcanoes of the CAVP, generally considered to be alkaline. Major and trace element geochemical and geochronological data for the CM are presented in comparison with other CAVP monogenetic volcanoes. CM scoria is basaltic andesitic, transitional-calc-alkaline in nature, and characterized by negative Nb-Ta, Ba, P and Ti anomalies in mantle-normalized patterns. Unlike the "alkaline" basalts of the Mediterranean region, other late-stage basalts from the CAVP monogenetic volcanoes are classified as tholeiitic, transitional and mildly alkaline. They display the same negative anomalies and incompatible element ratios as CM samples. In this respect, CM is comparable to other CAVP monogenetic basalts ( sl), but different from the Meditterranean intraplate alkali basalts. Several lines of evidence suggest derivation of CM and other CAVP monogenetic basalts from shallow depths within the lithospheric mantle, that is from a garnet-free source. In a wider regional context, CAVP basalts ( sl) are comparable to Apuseni (Romania) and Big Pine (Western Great Basin, USA) volcanics, except the former have depleted Ba contents. This is a common feature for the CAVP volcanics and might be related to crustal contamination or source

Compositional dependence of lower crustal viscosity

NASA Astrophysics Data System (ADS)

Shinevar, William J.; Behn, Mark D.; Hirth, Greg

2015-10-01

We calculate the viscosity structure of the lower continental crust as a function of its bulk composition using multiphase mixing theory. We use the Gibbs free-energy minimization routine Perple_X to calculate mineral assemblages for different crustal compositions under pressure and temperature conditions appropriate for the lower continental crust. The effective aggregate viscosities are then calculated using a rheologic mixing model and flow laws for the major crust-forming minerals. We investigate the viscosity of two lower crustal compositions: (i) basaltic (53 wt % SiO2) and (ii) andesitic (64 wt % SiO2). The andesitic model predicts aggregate viscosities similar to feldspar and approximately 1 order of magnitude greater than that of wet quartz. The viscosity range calculated for the andesitic crustal composition (particularly when hydrous phases are stable) is most similar to independent estimates of lower crust viscosity in actively deforming regions based on postglacial isostatic rebound, postseismic relaxation, and paleolake shoreline deflection.

3D geophysical insights into the Ciomadu volcano

NASA Astrophysics Data System (ADS)

Besutiu, Lucian; Zlagnean, Luminita

2017-04-01

RATIONALE Located at the south easternmost end of the Neogene to Quaternary volcanic chain of East Carpathians, the Ciomadu volcano (last erupted approx 30 ka ago) seems to represent the latest volcanic manifestation within the Carpatho-Pannonian region. Based on the interpretation of some large-scale electromagnetic and seismological surveys, the hypothesis of the in depth (8 -15 km) existence of a magma reservoir raises the volcanic hazard in the region. The close neighbourhood of the Vrancea active geodynamic zone, where intermediate-depth seismicity occurs within full intra-continental environment makes the study of the Ciomadu volcano of higher interest. METHOD During the time numerous geological investigations have been conducted in the area, but except for the previously mentioned large-scale electromagnetic and seismological approaches geophysical tools have been less employed. Relatively recent, within the frame of the INSTEC project, funded through a CNCS-UEFISCDI (Romanian Science Foundation) grant, the area has been subject to an integrated gravity and geomagnetic survey accompanied by outcrops sampling and lab determinations on rock physics. Field data have been highly processed and models of their sources have been constructed through 3D inversion techniques. RESULTS Overall, the potential fields have revealed a large gravity low covering the whole volcano area associating a residual geomagnetic anomaly with local effects mainly bordering the gravity anomaly. 3D inversion of the gravity data provided an intriguing image on the mass distribution within the volcanic structure, with underground densities much bellow the figures provided by the lab determinations on rock samples collected at the surface. The geometry of the revealed gravity source clearly suggests an andesitic/dacitic intrusion acceding to the surface along a deep fault that seems to belong to the alpine overthrust system of East Carpathians. Attempts to interpret the low value densities

Using experimental petrology to constrain genesis of wet, silicic magmas in the Tonga-Kermadec island arc

NASA Astrophysics Data System (ADS)

Brens, R.; Rushmer, T. A.; Turner, S.; Adam, J.

2012-12-01

The Tongan arc system is comprised of a pair of island chains, where the western chain is the active volcanic arc. A range of rock suites, from basaltic andesites (53-56% SiO2) to dacites (64-66% SiO2), has been recovered from Late, Tofua and Fonualei in the Tonga-Kermadec primitive island arc system. For which the question arises: What is the mechanism that allows for silicic magmas to develop in a primitive island arc system? Caufield et al. (2012) suggest that fractional crystallization of a multi magma chamber process, with varying depth, is responsible for the silicic magma generation in this arc. Models such as this one have been proposed and experimentally tested in other systems (Novarupta, Alaska) to explain the origin of these silicic rocks. Our Tongan suite of rocks has had a full geochemical analysis for majors, traces and isotopes. The lavas from Tofua and Late are Fe-rich and have low concentrations of K, Rb, Ba, Zr, REE, Pb and U. However, experimental studies are needed to complement the extensive geochemical analysis done on the Tongan arc. Former geochemical work done on the igneous rocks from both of these volcanic suites from this arc suggests that the source of these rocks extend from 1.5-5.5 km in depth (Caulfield et al., 2012). Here, we present an experimental study of the phase equilibria on a natural andesitic sample (Late 1, from Ewart et al., 1975) from the island of Late. Experiments were run using the temperature constraints between 900 to 1220oC, pressure from 5 to 25 kbars and H2O addition of mostly 5wt% (but some results were obtained at 2wt% in the rocks). In the presence of 5 wt% water, phase equilibria of these experiments show the garnet stability field at >10 kb for 900 oC and increases with increasing temperature, while plagioclase enters at lower pressures when garnet exits. Experimental results currently suggests, at lower temperatures (900-950oC), a fractional crystallization relationship due to shallow level pressures of

Late Holocene hydrous mafic magmatism at the Paint Pot Crater and Callahan flows, Medicine Lake Volcano, N. California and the influence of H2O in the generation of silicic magmas

USGS Publications Warehouse

Kinzler, R.J.; Donnelly-Nolan, J. M.; Grove, T.L.

2000-01-01

This paper characterizes late Holocene basalts and basaltic andesites at Medicine Lake volcano that contain high pre-eruptive H2O contents inherited from a subduction related hydrous component in the mantle. The basaltic andesite of Paint Pot Crater and the compositionally zoned basaltic to andesitic lavas of the Callahan flow erupted approximately 1000 14C years Before Present (14C years B.P.). Petrologic, geochemical and isotopic evidence indicates that this late Holocene mafic magmatism was characterized by H2O contents of 3 to 6 wt% H2O and elevated abundances of large ion lithophile elements (LILE). These hydrous mafic inputs contrast with the preceding episodes of mafic magmatism (from 10,600 to ~3000 14C years B.P.) that was characterized by the eruption of primitive high alumina olivine tholeiite (HAOT) with low H2O (< 0.2 wt%), lower LILE abundance and different isotopic characteristics. Thus, the mantle-derived inputs into the Medicine Lake system have not always been low H2O, primitive HAOT, but have alternated between HAOT and hydrous subduction related, calc-alkaline basalt. This influx of hydrous mafic magma coincides temporally and spatially with rhyolite eruption at Glass Mountain and Little Glass Mountain. The rhyolites contain quenched magmatic inclusions similar in character to the mafic lavas at Callahan and Paint Pot Crater. The influence of H2O on fractional crystallization of hydrous mafic magma and melting of pre-existing granite crust beneath the volcano combined to produce the rhyolite. Fractionation under hydrous conditions at upper crustal pressures leads to the early crystallization of Fe-Mg silicates and the suppression of plagioclase as an early crystallizing phase. In addition, H2O lowers the saturation temperature of Fe and Mg silicates, and brings the temperature of oxide crystallization closer to the liquidus. These combined effects generate SiO2-enrichment that leads to rhyodacitic differentiated lavas. In contrast, low H2O HAOT

Mass budget partitioning during explosive eruptions: insights from the 2006 paroxysm of Tungurahua volcano, Ecuador

NASA Astrophysics Data System (ADS)

Bernard, Julien; Eychenne, Julia; Le Pennec, Jean-Luc; Narváez, Diego

2016-08-01

How and how much the mass of juvenile magma is split between vent-derived tephra, PDC deposits and lavas (i.e., mass partition) is related to eruption dynamics and style. Estimating such mass partitioning budgets may reveal important for hazard evaluation purposes. We calculated the volume of each product emplaced during the August 2006 paroxysmal eruption of Tungurahua volcano (Ecuador) and converted it into masses using high-resolution grainsize, componentry and density data. This data set is one of the first complete descriptions of mass partitioning associated with a VEI 3 andesitic event. The scoria fall deposit, near-vent agglutinate and lava flow include 28, 16 and 12 wt. % of the erupted juvenile mass, respectively. Much (44 wt. %) of the juvenile material fed Pyroclastic Density Currents (i.e., dense flows, dilute surges and co-PDC plumes), highlighting that tephra fall deposits do not depict adequately the size and fragmentation processes of moderate PDC-forming event. The main parameters controlling the mass partitioning are the type of magmatic fragmentation, conditions of magma ascent, and crater area topography. Comparisons of our data set with other PDC-forming eruptions of different style and magma composition suggest that moderate andesitic eruptions are more prone to produce PDCs, in proportions, than any other eruption type. This finding may be explained by the relatively low magmatic fragmentation efficiency of moderate andesitic eruptions. These mass partitioning data reveal important trends that may be critical for hazard assessment, notably at frequently active andesitic edifices.

Stratigraphy, petrology, and geochemistry of the Spurr Volcanic Complex, eastern Aleutian Arc, Alaska. [(Appendix for geothermal fluid chemistry)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nye, C.J.

1987-12-01

The Spurr Volcanic Complex (SVC) is a calcalkaline, medium-K, sequence of andesites erupted over the last quarter of a million years by the easternmost currently active volcanic center in the Aleutian Arc. The ancestral Mt. Spurr was built mostly of andesites of uniform composition (58 to 60% SiO/sub 2/), although andesite production was episodically interrupted by the introduction of new batches of more mafic magma. Near the end of the Pleistocene the ancestral Mt. Spurr underwent Bezyianny-type avalanche caldera formation, resulting in the production of a volcanic debris avalanche with overlying ashflows. Immediately afterward, a large dome (the present Mt.more » Spurr) was emplaced in the caldera. Both the ashflows and dome are made of acid andesite more silicic than any analyzed lavas from the ancestral Mt. Spurr (60 to 63% SiO/sub 2/), yet contain olivine and amphibole xenocrysts derived from more mafic magma. The mafic magma (53 to 57% SiO/sub 2/) erupted during and after dome emplacement, forming proto-Crater Peak and Crater Peak. Hybrid pyroclastic flows and lavas were also produced. Proto-Crater Peak underwent glacial dissection prior to the formation of Crater Peak in approximately the same location. Appendices II through VIII contain a summary of mineral compositions; Appendix I contains geochemical data. Appendix IX by R.J. Motyka and C.J. Nye describes the chemistry of geothermal fluids. 78 refs., 16 figs., 3 tabs.« less

CALIPSO Borehole Monitoring Project at Soufriere Hills Volcano, Montserrat, BWI: Overview, and Response of Magma Reservoir to Prodigious Dome Collapse

NASA Astrophysics Data System (ADS)

Voight, B.; Mattioli, G. S.; Linde, A. T.; Sacks, I. S.; Young, S. R.; Malin, P. E.; Shalev, E.; Hidayat, D.; Elsworth, D.; Widiwijayanti, C.; Miller, V.; McWhorter, N.; Schleigh, B.; Johnston, W.; Sparks, R.; Neuberg, J.; Bass, V.; Dunkley, P.; Herd, R.; Jolly, A.; Norton, G.; Syers, T.; Thompson, G.; Williams, C.; Williams, D.; Clarke, A. B.

2004-12-01

Project CALIPSO (Caribbean Andesite Lava Island Precision Seismo-geodetic Observatory) aims to investigate the magmatic system at the active Soufriere Hills Volcano (SHV), Montserrat. The collaborative project involves several institutions acting in partnership with the Montserrat Volcano Observatory (MVO), and is funded by NSF with assistance by NERC. SHV remains active after 9 years, displaying cyclic activity on several scales. Many aspects of andesite system dynamics remain poorly understood, and CALIPSO is expected to improve our understanding of SHV and andesite systems generally. Drilling was carried out Nov 02 to Mar 03. CALIPSO comprises an integrated array of four strategically located 200-m boreholes, plus several shallower holes and surface installations. The borehole instruments are designed to have long life (decades). Each site includes a very broad-band Sacks-Evertson strainmeter, three-component seismometer, tiltmeter, and surface cGPS station. At one site a hot-hole strainmeter design, involving hydraulic sensors and no downhole electronics, has been used for the first time anywhere. FreeWave telemetry is coupled with Quanterra A/D converters. These instruments are intended to probe changes in the andesitic volcanic system and underlying mafic sources with unprecedented sensitivity. Early data from the July 2003 dome collapse suggest remarkable insights about the depth, shape and nature of the volatile-saturated magmatic reservoir, gleaned from the magnitude of dilatation pulses accompanying the collapse, and their change in sign of with radial distance.

Regional Variations in Aleutian Magma Composition

NASA Astrophysics Data System (ADS)

Nye, C. J.

2008-12-01

This study is based on sample data spanning 20 years from USGS, UAF, and DGGS geologists too numerous to list here. The 2900-km long Aleutian arc contains more than 50 active and over 90 Holocene volcanoes. The arc is built on oceanic Bering-sea floor west of 166W and quasi-continental crust east of 166W. Over the past twenty years the Alaska Volcano Observatory has conducted baseline geologic mapping (or remapping) and volcanic-hazards studies of selected volcanoes - generally those targeted for geophysical monitoring. This marks the largest sustained effort to study Aleutian volcanoes in half a century; AVO scientists have logged as many as 700 person-days per field season. Geologic studies have resulted in comprehensive suites of stratigraphically constrained samples and more than 3500 new whole-rock analyses by XRF and ICP/MS from more than 30 centers, more than doubling the number of previously published analyses. Examination of the data for regional and inter-volcano variations yields a number of first-order observations. (1) The arc can be broadly divided into an eastern segment (east of 158W) of calcalkaline andesite stratocones; a central segment dominated by large, mafic, tholeiitic shield volcanoes and stratocones; and a western segment (west of 175W) of smaller volcanoes with variable morphologies and generally more andesitic compositions. (2) There are NO significant first-order compositional signals that coincide with the transition from oceanic to continental basement. (3) Individual volcanoes are often subtly distinct from neighbors, and those distinctions persist for the lifetime of the centers. (4) All centers, notably including the large basaltic centers of the central arc, are strongly affected by open-system processes significantly more complicated than mixing among sibling-fractionates of parental mafic magmas. (5) Petrogenetic pathways are long-lived; individual batches of magma are (generally) not. (6) Calcalkaline andesites have

Tectonic implications of a paleomagnetic direction obtained from a Miocene dike swarm in central Honshu, Japan

NASA Astrophysics Data System (ADS)

Hoshi, H.; Sugisaki, Y.

2017-12-01

Central Honshu of Japan is an ideal field for the study of crustal deformation related to arc-arc collision. In this study we obtained rock magnetic and paleomagnetic results from early Miocene igneous rocks in central Honshu in order to examine rotational deformation caused by the collision of the Izu-Bonin-Mariana (IBM) arc with central Honshu. In Takane of the Hida region, gabbro intrusions and older sedimentary rocks are intruded by numerous andesitic dikes that comprise a parallel dike swarm. The dikes formed under two different normal-faulting paleostress conditions, which were suggested using a method of clustering dike orientations. Cross-cutting relationships indicate that the two paleostress conditions existed during the same period. More than 240 oriented cores were taken at 38 sites in two localities for magnetic study. The andesites and gabbros generally have magnetite, and some andesites also contain pyrrhotite. The magnetite records easterly deflected remanent magnetization directions of dual polarities that pass the reversals test. Positive baked contact tests at two sites demonstrate that the easterly deflected direction is a thermoremanent magnetization acquired at the time of intrusion. The overall in situ (i.e., in geographic coordinates) mean direction for andesitic dikes is judged to be highly reliable, although there are two possible scenarios for explaining the easterly deflection: (1) clockwise rotation and (2) tilting to the northwest. We prefer the former scenario and conclude that 45° clockwise rotation occurred in Takane with respect to the North China Block of the Asian continent. This rotation must represent the clockwise rotation of entire Southwest Japan during the opening period of the Japan Sea. Very little difference is observed between the amount of the easterly deflection in Takane and those in the Tokai and Hokuriku regions, indicating no significant relative rotation. Thus, the crust beneath Takane has not suffered rotation

New Insights to the Mid Miocene Calc-alkaline Lavas of the Strawberry Volcanics, NE Oregon Surrounded by the Coeval Tholeiitic Columbia River Basalt Province

NASA Astrophysics Data System (ADS)

Steiner, A. R.; Streck, M. J.

2013-12-01

The Strawberry Volcanics (SV) of NE Oregon were distributed over 3,400 km2 during the mid-Miocene and comprise a diverse volcanic suite, which span the range of compositions from basalt to rhyolite. The predominant composition of this volcanic suite is calc-alkaline (CA) basaltic andesite and andesite, although tholeiitic (TH) lavas of basalt to andesite occur as well. The coeval flood basalts of the Columbia River province surround the SV. Here we will discuss new ages and geochemical data, and present a new geologic map and stratigraphy of the SV. The SV are emplaced on top of pre-Tertiary accreted terranes of the Blue Mountain Province, Mesozoic plutonic rocks, and older Tertiary volcanic rocks thought to be mostly Oligocene of age. Massive rhyolites (~300 m thick) are exposed mainly along the western flank and underlie the intermediate composition lavas. In the southern portion of this study area, alkali basaltic lavas, thought to be late Miocene to early Pliocene in age, erupted and overlie the SV. In addition, several regional ignimbrites reach into the area. The 9.7 Ma Devine Canyon Tuff and the 7.1 Ma Rattlesnake Tuff also overlie the SV. The 15.9-15.4 Ma Dinner Creek Tuff is mid-Miocene, and clear stratigraphic relationships are found in areas where the tuff is intercalated between thick SV lava flows. All of the basalts of the SV are TH and are dominated by phenocryst-poor (≤2%) lithologies. These basalts have an ophitic texture dominated by plagioclase, clinopyroxene and olivine (often weathered to iddingsite). Basalts and basaltic andesites have olivine Fo #'s ranging from 44 at the rims (where weathered to iddingsite) and as high as 88 at cores. Pyroxene Mg #'s range from 65 to 85. Andesites of the SV are sub-alkaline, and like the basalts, are exceedingly phenocryst-poor (≤3%) with microphenocrysts of plagioclase and lesser pyroxene and olivine, which occasionally occur as crystal clots of ~1-3 mm instead of single crystals. In addition, minimal

Asymmetric deformation structure of lava spine in Unzen Volcano, Japan

NASA Astrophysics Data System (ADS)

Miwa, T.; Okumura, S.; Matsushima, T.; Shimizu, H.

2013-12-01

Lava spine is commonly generated by effusive eruption of crystal-rich, dacitic-andesitic magmas. Especially, deformation rock on surface of lava spine has been related with processes of magma ascent, outgassing, and generation of volcanic earthquake (e.g., Cashman et al. 2008). To reveal the relationships and generation process of the spine, it is needed to understand a spatial distribution of the deformation rock. Here we show the spatial distribution of the deformation rock of lava spine in the Unzen volcano, Japan, to discuss the generation process of the spine. The lava spine in Unzen volcano is elongated in the E-W direction, showing a crest like shape with 150 long, 40 m wide and 50 m high. The lava spine is divided into following four parts: 1) Massive dacite part: Dense dacite with 30 m of maximum thickness, showing slickenside on the southern face; 2) Sheared dacite part: Flow band developed dacite with 1.0 m of maximum thickness; 3) Tuffisite part: Network of red colored vein develops in dacite with 0.5 m of maximum thickness; 4) Breccia part: Dacitic breccia with 10 m of maximum thickness. The Breccia part dominates in the northern part of the spine, and flops over Massive dacite part accross the Sheared dacite and Tuffisite parts. The slickenside on southern face of massive dacite demonstrates contact of solids. The slickenside breaks both of phenocryst and groundmass, demonstrating that the slickenside is formed after significant crystallization at the shallow conduit or on the ground surface. The lineation of the slickenside shows E-W direction with almost horizontal rake angle, which is consistent with the movement of the spine to an east before emplacement. Development of sub-vertical striation due to extrusion was observed on northern face of the spine (Hayashi, 1994). Therefore, we suggest that the spine just at extrusion consisted of Massive dacite, Sheared dacite, Tuffisite, Breccia, and Striation parts in the northern half of the spine. Such a

Dacite Melt at the Puna Geothermal Venture Wellfield, Big Island of Hawaii

NASA Astrophysics Data System (ADS)

Teplow, W. J.; Marsh, B. D.; Hulen, J.; Spielman, P.; Kaleikini, M.; Fitch, D. C.; Rickard, W.

2008-12-01

A dacite melt was encountered during routine commercial drilling operations of injection well KS-13 at the Puna Geothermal Venture wellfield, Big Island of Hawaii. The KS-13 drill hole, drilled in 2005, is located along a segment of the Kilauea Lower East Rift Zone which erupted basalt flows from rift-parallel fissures in 1955. During the drilling of KS-13 a 75-meter interval of microdiorite containing brown glass inclusions was penetrated at a depth of 2415 m. At a depth of 2488 m a melt of dacitic composition was encountered. The melt flowed up the wellbore and was repeatedly redrilled over a depth interval of ~8 m, producing several kilograms of clear, colorless vitric cuttings at the surface. The drill bit, when recovered at the surface, was missing several carbide insert teeth. Presumably the inserts were plucked cleanly from their sintered cone sockets due to differential thermal expansion under extreme heat conditions. The dacitic glass cuttings have a perlitic texture, a silica content of 67 wgt.%, are enriched in alkalis and nearly devoid of mafic minerals with the exception of rare pyroxene phenocrysts and minor euhedral to amorphous magnetite. The melt zone is overlain by an interval of strong greenschist facies metamorphism in basaltic and dioritic dike rock. The occurrence of an anhydrous dacite melt indicates a rock temperature of approximately 1050° (1922°F) and sufficient residence time of underlying basaltic magma to generate a significant volume of differentiated material. The dacite, with an inferred temperature of 1050 °C, is separated by 526 m of rock from the deepest overlying permeable zone in KS-13 at a temperature of 356 °C. The thermal gradient through this impermeable rock section is ~700°C/526 m = 1.331 °C/m. The calculated conductive heat flux from the magma upward into the deepest zone of hydrothermal circulation is given by k×(dT/dZ)=2.9 × 1.33 = 3.83 W/m2 = 3830 mW/m2 (thermal conductivity k=2.9 W m-1 °C-1 for basalt). This

Airborne filter pack measurements of S and Cl in the plume of Redoubt Volcano, Alaska February–May 2009

USGS Publications Warehouse

Pfeffer, Melissa; Doukas, Michael P.; Werner, Cynthia A.; Evans, William C.

2013-01-01

Filter pack data from six airborne campaigns at Redoubt Volcano, Alaska are reported here. These measurements provide a rare constraint on Cl output from an andesitic eruption at high emission rate (> 104 t d− 1 SO2). Four S/Cl ratios measured during a period of lava dome growth indicate a depth of last magma equilibration of 2–5 km. The S/Cl ratios in combination with COSPEC SO2 emission rate measurements indicate HCl emission rates of 1500–3600 t d− 1 during dome growth. SO2 and HCl emission rates at Redoubt Volcano correlate with each other and were low prior to the eruption, high during the eruption, and low after the eruption. S/Cl ratios measured by filter pack at andesitic volcanoes have a small range of variance, with no clear trends seen for eruptive versus passive activity. The very few S/Cl ratio measurements by filter pack at andesitic volcanoes are not as predictive of future volcanic activity as has been demonstrated for basaltic volcanoes. This may be because there are so few of these measurements. We have demonstrated it is possible to collect these samples by air between explosions during lava dome-building eruptions. We recommend more filter pack sampling be performed at andesitic volcanoes to determine the technique's utility for volcano monitoring. Filter pack data has been demonstrated to be useful for calculating the depth of magma equilibration at volcanoes including Redoubt Volcano.

Experimental study of eclogitization and melting of basic rocks at P = 4 GPa and T = 1200-1400°C

NASA Astrophysics Data System (ADS)

Gorbachev, N. S.; Shapovalov, Yu. B.; Kostyuk, A. V.

2017-06-01

Experimental study of gabbro-norite eclogitization and melting at P = 4 GPa has made it possible to reveal the effective influence of fluid and temperature on the phase relationships. The melt composition varies from andesite-dacite in "dry conditions" to phonolite and carbonate in the presence of a fluid. The Grt-containing melting curve is replaced by the Cpx-containing liquidus as the temperature changes or a fluid is added. Hence, the possible presence of "garnetitite" and "clinopyroxenite" in the upper mantle was proved experimentally. The ultimate pressure of the spinel facies at the depth of the eclogite upper mantle is controlled by the stability of Cht ≤ 4 GPa. The revealed similarity of the spectra of REE-adakite, tonalite-trondhjemite-granodiorite (TTG), and melts formed under the partial melting of eclogitized gabbro-norite does not contradict the existing ideas of the eclogite source of the TTG rocks. Wide variations in the interphase microelement distribution factors D (Grt, Cpx)/L are indicative of effective fractionation of the microelements in the course of eclogite melting and differentiation.

Late Pleistocene granodiorite beneath Crater Lake caldera, Oregon, dated by ion microprobe

USGS Publications Warehouse

Bacon, C.R.; Persing, H.M.; Wooden, J.L.; Ireland, T.R.

2000-01-01

Variably melted granodiorite blocks ejected during the Holocene caldera-forming eruption of Mount Mazama were plucked from the walls of the climactic magma chamber ~15 km depth. Ion-microprobe U-Pb dating of zircons from two unmelted granodiorite blocks with SHRIMP RG (sensitive high-resolution ion microprobe-reverse geometry) gives a nominal 238U/206Pb age of 101+78-80 ka, or 174+89-115 ka when adjusted for an initial 230Th deficit. SHRIMP RG U-Th measurements on a subset of the zircons yield a 230Th/238U isochron age of 112 ?? 24 ka, considered to be the best estimate of the time of solidification of the pluton. These results suggest that the granodiorite is related to andesite and dacite of Mount Mazama and not to magmas of the climactic eruption. The unexposed granodiorite has an area of at least 28 km2. This young, shallow pluton was emplaced in virtually the same location where a similarly large magma body accumulated and powered violent explosive eruptions ~7700 yr ago, resulting in collapse of Crater Lake caldera.

Oceanic slab melting and mantle metasomatism.

PubMed

Scaillet, B; Prouteau, G

2001-01-01

Modern plate tectonic brings down oceanic crust along subduction zones where it either dehydrates or melts. Those hydrous fluids or melts migrate into the overlying mantle wedge trigerring its melting which produces arc magmas and thus additional continental crust. Nowadays, melting seems to be restricted to cases of young (< 50 Ma) subducted plates. Slab melts are silicic and strongly sodic (trondhjemitic). They are produced at low temperatures (< 1000 degrees C) and under water excess conditions. Their interaction with mantle peridotite produces hydrous metasomatic phases such as amphibole and phlogopite that can be more or less sodium rich. Upon interaction the slab melt becomes less silicic (dacitic to andesitic), and Mg, Ni and Cr richer. Virtually all exposed slab melts display geochemical evidence of ingestion of mantle material. Modern slab melts are thus unlike Archean Trondhjemite-Tonalite-Granodiorite rocks (TTG), which suggests that both types of magmas were generated via different petrogenetic pathways which may imply an Archean tectonic model of crust production different from that of the present-day, subduction-related, one.

Effusive silicic volcanism in the Paraná Magmatic Province, South Brazil: Physico-chemical conditions of storage and eruption and considerations on the rheological behavior during emplacement

NASA Astrophysics Data System (ADS)

Polo, L. A.; Giordano, D.; Janasi, V. A.; Guimarães, L. F.

2018-04-01

Expressive occurrences of effusive deposits were identified in silicic units from the Paraná Magmatic Province outcropping in a key area in south Brazil where three units with different compositions occur (Caxias do Sul dacites, CSd, Barros Cassal andesites to dacites, BCs, and Santa Maria rhyolites, SMr). Textural and chemical characteristics of phenocrysts, microphenocrysts and microlites suggest that crystallization started in a shallow magma chamber and continued during ascent to the surface. These magmas had an unique character (e.g., very high temperatures 1000 °C and low H2O contents 1-2 wt%), and formed several types of deposits that are clearly indicative of locally fed lava flows and had physical properties consistent with this mode of eruption (e.g., viscosities as low as 104.2 Pa·s at ca. 1000 °C for the CSd). The very low estimated H2O contents are a consequence of their petrogenesis (i.e., fractionation from tholeiitic basalts plus assimilation of crustal melts from water-poor granitic sources), and was probably a key factor influencing the non-explosive nature of these deposits. The comparatively higher viscosity calculated for the Santa Maria rhyolite (> 1-2 orders of magnitude greater than CSd) would make it a better candidate to generate expressive pyroclastic deposits, but this might be offset by its remarkably low H2O contents (≤ 1 wt%) and low discharge ratios.

Temporal and spatial constraints on the evolution of a Rio Grande rift sub-basin, Guadalupe Mountain area, northern New Mexico

NASA Astrophysics Data System (ADS)

Thompson, R. A.; Turner, K. J.; Cosca, M. A.; Drenth, B.; Hudson, M. R.; Lee, J.

2013-12-01

.27-4.8 Ma), (2) lower Servilleta basalt lavas (olivine tholeiite ~5.26-4.92 Ma), (3) Hatchery volcano lavas (basaltic andesite to andesite ~4.93 Ma), (4) Red River lavas (high silica andesite ~4.93 Ma), (5) UCEM lavas (dacite ~4.85 Ma), and (6) upper Servilleta basalt lavas (olivine tholeiite ~3.84-3.45 Ma). Mapped eruptive centers are interpreted to reflect discrete pulses of volcanic activity characterized by limited compositional range and short eruption cycles. Four major, northwest-trending, dip-slip faults cut the volcanic fill. From west to east these are: (1) down-to-east Red River fault zone (post 3.84 Ma displacement), (2) down-to-east Fish Hatchery fault zone including fault splays of opposite displacement (pre- upper Servilleta displacement < 3.84 Ma and contemporaneous with eruption of Hatchery volcano lavas, ~4.93 Ma), (3) Guadalupe Mtn. fault zone, both down-to-west and down-to-east components (post ~5 Ma displacement), and (4) Tailings Pond fault zone, down-to-east (post ~5 Ma displacement). The Red River and Tailings Pond fault zones appear to have the largest cumulative displacements and may reflect eastward migration of the western sub-basin margin. This may reflect coupled partitioning of extensional strain reflected as local expressions of sub-basin development and contemporaneous volcanism.

Constraints for recently discovered ignimbrites in the Altiplano-Puna Volcanic Complex (APVC), northern Chile

NASA Astrophysics Data System (ADS)

Layana, S.; Aguilera, F.

2014-12-01

One of most voluminous ignimbrite provinces in the world (>30.000 km3) is located in the Central Andean Volcanic Zone (CAVZ), which has been continuously active since Upper Oligocene. Altiplano-Puna Volcanic Complex (APVC), located between 21 and 24ºS, is a volcano-tectonic province constituted by diverse caldera complexes and ignimbrite deposits (Upper Miocene - Lower Pleistocene) that covers an area ~50.000 km2. In this work, we present data from three new ignimbrites discovered in a portion of APVC (22°-22,4°S), with the objective to establish its origin and provenance. Were identified 3 new ignimbrites: 1) Cabana ignimbrite (>7.5 Ma), constituted by 3 pyroclastic flow and 1 pyroclastic surge units of crystal-glass rich dacitic tuffs, 80 m maximum thick, 0.18 km3 volume and 0.14 km3 DRE; 2) Inacaliri ignimbrite (7.5 Ma) constituted by two members, corresponding to glassy dacitic (basal member) and basaltic andesites (upper member) tuffs, the total thick reach up 20 m, 0.003 km3 volume and 0.002 km3 DRE; 3) Tolar ignimbrite (>1.3 Ma), constituted by a single pyroclastic flow and a basal fall glassy dacitic deposits, 50 m maximum thick, 0.04 km3 volume and 0.03 km3 DRE. Cabana ignimbrite seems to have been originated from a single caldera complex, whose cannot be recognized in the field. Inacaliri ignimbrite could be related to initial phases of building of Inacaliri and Apacheta-Aguilucho volcanic complexes, or originated to a buried caldera located below both volcanic complexes. Finally, Tolar ignimbrite corresponds to initial building stage of Toconce volcano, located 2 km at NE from these deposits.

Sr and Nd isotopic and trace element compositions of Quaternary volcanic centers of the Southern Andes

USGS Publications Warehouse

Futa, K.; Stern, C.R.

1988-01-01

Isotopic compositions of samples from six Quaternary volcanoes located in the northern and southern extremities of the Southern Volcanic Zone (SVZ, 33-46??S) of the Andes and from four centers in the Austral Volcanic Zone (AVZ, 49-54??S) range for 87Sr 86Sr from 0.70280 to 0.70591 and for 143Nd 144Nd from 0.51314 to 0.51255. The ranges are significantly greater than previously reported from the southern Andes but are different from the isotopic compositions of volcanoes in the central and northern Andes. Basalts and basaltic andesites from three centers just north of the Chile Rise-Trench triple junction have 87Sr 86Sr, 143Nd 144Nd, La Yb, Ba La, and Hf Lu that lie within the relatively restricted ranges of the basic magmas erupted from the volcanic centers as far north as 35??S in the SVZ of the Andes. The trace element and Sr and Nd isotopic characteristics of these magmas may be explained by source region contamination of subarc asthenosphere, with contaminants derived from subducted pelagic sediments and seawater-altered basalts by dehydration of subducted oceanic lithosphere. In the northern extremity of the SVZ between 33?? and 34??S, basaltic andesites and andesites have higher 87Sr 86Sr, Rb Cs, and Hf Lu, and lower 143Nd 144Nd than basalts and basaltic andesites erupted farther south in the SVZ, which suggests involvement of components derived from the continental crust. In the AVZ, the most primitive sample, high-Mg andesite from the southernmost volcanic center in the Andes (54??S) has Sr and Nd isotopic compositions and K Rb and Ba La similar to MORB. The high La Yb of this sample suggests formation by small degrees of partial melting of subducted MORB with garnet as a residue. Samples from centers farther north in the AVZ show a regionally regular northward increase in SiO2, K2O, Rb, Ba, Ba La, and 87Sr 86Sr and decrease in MgO, Sr, K Rb, Rb Cs, and 143Nd 144Nd, suggesting increasingly greater degrees of fractional crystallization and associated intra

Relationships between mineralization and silicic volcanism in the central Andes

NASA Technical Reports Server (NTRS)

Francis, P. W.; Halls, C.; Baker, M. C. W.

1983-01-01

Existing models for the genesis of porphyry copper deposits indicate that they formed in granodioritic stocks located in the infrastructure of andesitic stratovolcanoes. It is noted that sites of porphyry-type subvolcanic tin mineralization in the Eastern Cordillera of Bolivia are distinguished by the absence of such andesitic structures. The surface expression of a typical subvolcanic porphyry tin deposit is thought to be an extrusive dome of quartz latite porphyry, sometimes related to a larger caldera structure. Evidence from the El Salvador porphyry copper deposit in the Eocene magmatic belt in Chile indicates that it too may be more closely related to a silicic volcanic structure than to an andesitic stratovolcano. The dome of La Soufriere, Guadeloupe is offered as a modern analog for the surface expression of subvolcanic mineralization processes, with the phreatic eruptions there indicating the formation of hydrothermal breccia bodies in depths. It is pointed out that the occurrence of mineralized porphyries, millions of years after caldera formation, does not necessarily indicate that tin intrusions and mineralization are not genetically related to the subcaldera pluton, but may be a consequence of the long thermal histories (1-10 million years) of the lowermost parts of large plutons.

Thermal infrared spectroscopy and modeling of experimentally shocked basalts

USGS Publications Warehouse

Johnson, J. R.; Staid, M.I.; Kraft, M.D.

2007-01-01

New measurements of thermal infrared emission spectra (250-1400 cm-1; ???7-40 ??m) of experimentally shocked basalt and basaltic andesite (17-56 GPa) exhibit changes in spectral features with increasing pressure consistent with changes in the structure of plagioclase feldspars. Major spectral absorptions in unshocked rocks between 350-700 cm-1 (due to Si-O-Si octahedral bending vibrations) and between 1000-1250 cm-1 (due to Si-O antisymmetric stretch motions of the silica tetrahedra) transform at pressures >20-25 GPa to two broad spectral features centered near 950-1050 and 400-450 cm-1. Linear deconvolution models using spectral libraries composed of common mineral and glass spectra replicate the spectra of shocked basalt relatively well up to shock pressures of 20-25 GPa, above which model errors increase substantially, coincident with the onset of diaplectic glass formation in plagioclase. Inclusion of shocked feldspar spectra in the libraries improves fits for more highly shocked basalt. However, deconvolution models of the basaltic andesite select shocked feldspar end-members even for unshocked samples, likely caused by the higher primary glass content in the basaltic andesite sample.

Summary of the geology of the northern part of the Sierra Cuchillo, Socorroand Sierra Counties, southwestern New Mexico

USGS Publications Warehouse

Maldonado, Florian; Edited by Lucas, Spencer G.; McLemore, Virginia T.; Lueth, Virgil W.; Spielmann, Justin A.; Krainer, Karl

2012-01-01

The northern part of the Sierra Cuchillo is located within the northeastern part of the Mogollon-Datil volcanic field west of the Rio Grande rift in the Basin and Range Province, approximately 50 km northwest of Truth or Consequences in south-central New Mexico. The Sierra Cuchillo is a north-south, elongated horst block composed of Tertiary volcanic and intrusive rocks, sparse outcrops of Lower Permian and Upper Cretaceous rocks, and sediments of the Tertiary-Quaternary Santa Fe Group. The horst is composed mainly of a basal volcanic rock sequence of andesite-latite lava flows and mud-flow breccias with a 40Ar/39Ar isotopic age of about 38 Ma. The sequence is locally intruded by numerous dikes and plugs that range in composition from basaltic andesite through rhyolite and granite. The andesite-latite sequence is overlain by ash-flow tuffs and a complex of rhyolitic lava flows and domes. Some of these units are locally derived and some are outflow sheets derived from calderas in the San Mateo Mountains, northeast of the study area. These locally derived units and outflow sheets range in age from 28 to 24 Ma.

Stratigraphy of the unsaturated zone and the Snake River Plain aquifer at and near the Idaho National Engineering Laboratory, Idaho

DOE Office of Scientific and Technical Information (OSTI.GOV)

Anderson, S.R.; Liszewski, M.J.

1997-08-01

The unsaturated zone and the Snake River Plain aquifer at and near the Idaho National Engineering Laboratory (INEL) are made up of at least 178 basalt-flow groups, 103 sedimentary interbeds, 6 andesite-flow groups, and 4 rhyolite domes. Stratigraphic units identified in 333 wells in this 890-mile{sup 2} area include 121 basalt-flow groups, 102 sedimentary interbeds, 6 andesite-flow groups, and 1 rhyolite dome. Stratigraphic units were identified and correlated using the data from numerous outcrops and 26 continuous cores and 328 natural-gamma logs available in December 1993. Basalt flows make up about 85% of the volume of deposits underlying the area.

Volcanic stratigraphy and geochemical variations in Miocene-age rocks in western and southeastern Fort Irwin, California

NASA Astrophysics Data System (ADS)

Buesch, D.

2015-12-01

Lava flows and tuffaceous deposits ranging in composition from basalt to rhyolite, including basaltic trachyandesite to trachyte, are exposed in 800 km2 of western Fort Irwin area, California, and form the eastern edge of the Eagle Crags volcanic field (ECVF). The main ECVF has 40Ar/39Ar ages from ~18.7-12.4 Ma (mostly 18.7-18.5 Ma; Sabin et al. 1994), and on Fort Irwin, the ages are from 21.0-15.8 Ma (mostly 18.6-15.8 Ma; Schermer et al. 1996). 68 samples (56 lava flow, 4 dome-collapse breccia, 3 ignimbrite, and 5 fallout tephra) were analyzed for major, minor, and trace elements. Typically, stratigraphic sequences dip <30° (mostly <15°) except near faults, with local buttress unconfomities and no large unconfomities. Compositions are moderate-to-high-K type, and similar to Na2O+K2O from Sabin et al. (1994) but with slightly smaller ranges. The generalized stratigraphic sequence is rhyolite (R), dacite (D), or trachyte (T) that form domes, lava flows (up to 3.5 km long), dome-collapse deposits, or pyroclastic deposits, overlain by andesite (A), trachyandesite (TA), basaltic andesite (BA), basaltic trachyandesite (BT), or basalt (B) lava flows (up to 7 km long), and minor cinder cones. A general upward felsic to mafic compositional sequence occurs throughout the area, but is not continuous as B is locally in a R-D sequence and B is at the base of and interstratified with a BA-A sequence. Also, there are compositional variations at different locations along the edges of the field. In the Goldstone Mesa, Pink Canyon, and Stone Ridge areas (~70 km2), B-BA forms the youngest lava flows, but ~21 km to the north in the Garry Owen area (~25 km2), BTA forms the youngest lava flows. Compared to the Stone Ridge area with a D-A-TA-BA trend, ~6 km west in the Pioneer Plateau area is R-TA-D, ~3 km south in the Pink Canyon area is R-B-BA-A, and ~8 km east at Dacite Dome is D only (all areas have slightly different Na2O+K2O in each rock type). A non-ECVF, 5.6 Ma BA flow in SE

Lithospheric convective removal related post-collisional middle Eocene magmatism along the Izmir-Ankara-Erzincan suture zone (NE Turkey).

NASA Astrophysics Data System (ADS)

Göçmengil, Gönenç; Karacık, Zekiye; Genç, Ş. Can

2017-04-01

-57) andesite and dacites. V2 series made up of the olivine+pyroxene rich anhydrous lavas. V2a sub-group displays calc-alkaline/mildly alkaline character, moderate Mg# (33-54) and represented by basaltic andesites. Furthermore, V2b sub-group has mildly alkaline/alkaline in character and represented by more Mg# rich (40-62) basalt and trachy-basalt lavas. Final products, V3 series, cut the older units and made up of high-K - shoshonitic trachyte and trachy-andesites. The V1a sub-group, showing the alkali nature and high Mg#, is probably derived from the partial melting of a hydrous spinel lherzolitic source with minor garnet and amphibole while the V1b sub-group is a fractionated (FC) derivative of them. The V2 series are mixed products of varying amounts of magma sources similar to V1b type with a high Mg#, deep-seated magma source and their fractionated assemblages. The V3 series developed independently from the other series in shallow magma chambers, displaying the large amounts of crustal assimilation and constitutes the final product of the Middle Eocene volcanism. The data presented above shown that volcanic units; (i) are rich in potassium, (ii) have subduction-related signatures, (iii) display fluctuant alkalinity and Mg# during the course of volcanism, (iv) coevally developed on both amalgamated continental blocks after the cessation of subduction. These characteristics imply that, lithospheric convective removal related processes can be the most plausible driving mechanism of the middle Eocene magmatism.

Rear-arc vs. arc-front volcanoes in the Katmai reach of the Alaska Peninsula: A critical appraisal of across-arc compositional variation

USGS Publications Warehouse

Hildreth, W.; Fierstein, J.; Siems, D.F.; Budahn, J.R.; Ruiz, J.

2004-01-01

Physical and compositional data and K-Ar ages are reported for 14 rear-arc volcanoes that lic 11-22 km behind the narrowly linear volcanic front defined by the Mount Katmai-to-Devils Desk chain on the Alaska Peninsula. One is a 30-km3 stratocone (Mount Griggs; 51-63% SiO2) active intermittently from 292 ka to Holocene. The others are monogenetic cones, domes, lava flows, plugs, and maars, of which 12 were previously unnamed and unstudied; they include seven basalts (48-52% SiO2), four mafic andesites (53-55% SiO2), and three andesite-dacite units. Six erupted in the interval 500-88 ka, one historically in 1977, and five in the interval 3-2 Ma. No migration of the volcanic front is discernible since the late Miocene, so even the older units erupted well behind the front. Discussion explores the significance of the volcanic front and the processes that influence compositional overlaps and differences among mafic products of the rear-arc volcanoes and of the several arc-front edifices nearby. The latter have together erupted a magma volume of about 200 km3, at least four times that of all rear-arc products combined. Correlation of Sr-isotope ratios with indices of fractionation indicates crustal contributions in volcanic-front magmas (0.7033-0.7038), but lack of such trends among the rear-arc units (0.70298-0.70356) suggests weaker and less systematic crustal influence. Slab contributions and mantle partial-melt fractions both appear to decline behind the front, but neither trend is crisp and unambiguous. No intraplate mantle contribution is recognized nor is any systematic across-arc difference in intrinsic mantle-wedge source fertility discerned. Both rear-arc and arc-front basalts apparently issued from fluxing of typically fertile NMORB-source mantle beneath the Peninsular terrane, which docked here in the Mesozoic. ?? Springer-Verlag 2004.

Geologic map and structure sections of the Clear Lake Volcanics, Northern California

USGS Publications Warehouse

Hearn, B.C.; Donnelly-Nolan, J. M.; Goff, F.E.

1995-01-01

The Clear Lake Volcanics are located in the California Coast Ranges about 150 km north of San Francisco. This Quaternary volcanic field has erupted intermittently since 2.1 million years ago. This volcanic field is considered a high-threat volcanic system (Ewert and others, 2005) The adjacent Geysers geothermal field, largest power-producing geothermal field in the world, is powered by the magmatic heat source for the volcanic field. This report consists of three sheets that include the geologic map, one table, two figures, three cross sections, description of map units, charts of standard and diagrammatic correlation of map units, and references. This map supersedes U.S. Geological Survey Open-File Report 76-751. Descriptions of map units are grouped by geographic area. Summaries of the evolution, chemistry, structure, and tectonic setting of the Clear Lake Volcanics are given in Hearn and others (1981) and Donnelly-Nolan and others (1981). The geology of parts of the area underlain by the Cache Formation is based on mapping by Rymer (1981); the geology of parts of the areas underlain by the Sonoma Volcanics, Franciscan assemblage, and Great Valley sequence is based on mapping by McLaughlin (1978). Volcanic compositional map units are basalt, basaltic andesite, andesite, dacite, rhyodacite, and rhyolite, based on SiO2 content. Included in this report are maps showing the distribution of volcanic rocks through time and a chart showing erupted volumes of different lava types through time. A table gives petrographic data for each map unit by mineral type, abundance, and size. Most ages are potassium-argon (K/Ar) ages determined for whole-rock samples and mineral separates by Donnelly-Nolan and others (1981), unless otherwise noted. A few ages are carbon-14 ages or were estimated from geologic relationships. Magnetic polarities are from Mankinen and others (1978; 1981) or were determined in the field by B.C. Hearn, Jr., using a portable fluxgate magnetometer

Using noble gases and 87Sr/86Sr to constrain heat sources and fluid evolution at the Los Azufres Geothermal Field, Mexico

NASA Astrophysics Data System (ADS)

Wen, T.; Pinti, D. L.; Castro, M. C.; Lopez Hernandez, A.; Hall, C. M.; Shouakar-Stash, O.; Sandoval-Medina, F.

2017-12-01

Geothermal wells and hot springs were sampled for noble gases' volume fraction and isotopic measurements and 87Sr/86Sr in the Los Azufres Geothermal Field (LAGF), Mexico, to understand the evolution of fluid circulation following three decades of exploitation and re-injection of used brines. The LAGF, divided into the Southern Production Zone (SPZ) and the Northern Production Zone (NPZ), is hosted in a Miocene to Pliocene andesitic volcanic complex covered by Quaternary rhyolitic-dacitic units. Air contamination corrected 3He/4He ratios (Rc) normalized to the atmospheric ratio (Ra=1.384 x 10-6), show a median value of 6.58 indicating a dominant mantle helium component. Contributions of crustal helium up to 53% and 18% are observed in NPZ and SPZ, respectively. Observations based on Rc/Ra and 87Sr/86Sr ratios points to the mixing of three magmatic sources supplying mantle helium to the LAGF: (1) a pure mantle He (Rc/Ra = 8) and Sr (87Sr/86Sr = 0.7035) source; (2) a pure mantle helium (Rc/Ra = 8) with some radiogenic Sr (87Sr/86Sr = 0.7049) source possibly resulting from Quaternary rhyolitic volcanism; and (3) a fossil mantle He component (Rc/Ra = 3.8) with some radiogenic Sr (87Sr/86Sr = 0.7038), corresponding possibly to the Miocene andesite reservoir. Intrusions within the last 50 kyrs from sources (1) and (2) are likely responsible for the addition of mantle volatiles and heat to the hydrothermal system of Los Azufres. He and Ar isotopes indicate that heat flow is transported by both convection and conduction. Atmospheric noble gas elemental ratios suggest that geothermal wells located closer to the western re-injection zone are beginning to be dominated by re-injection of used brines (injectate). The area affected by boiling in LAGF has further extended to the north and west since the last noble gas sampling campaign in 2009.

Magmatic evolution of the Ilopango Caldera, El Salvador, Central America

NASA Astrophysics Data System (ADS)

Zezin, D.; Mann, C. P.; Hernández, W.; Stix, J.

2010-12-01

The Ilopango caldera (16 x 13 km) is an active, long-lived magmatic system, erupting voluminous amounts of pyroclastic material numerous times over the course of its evolution. The caldera is presently water filled and the most recent activity is a dome growth event in 1880. Established age constraints from extracaldera pyroclastic sequences, indicate caldera forming events occur ~ every 10,000 years over the last 40,000 years. The most recent pyroclastic eruption (TBJ) is constrained to A.D. 429 erupting 70 km3 DRE of pyroclastic material. We combine major element and trace element chemistry with 40Ar/39Ar age constraints of the intracaldera domes and intracaldera pyroclastic deposits to extent the caldera history. The intracaldera domes are andesitic to rhyolitic in composition (57 - 76 wt. % SiO2), some with basaltic enclaves (54 wt. % SiO2) and pyroclastic units observed inside the caldera (San Agustín Pumice Breccia) are dacitic to rhyolitic in composition (69 -75 wt. % SiO2). Formation of an intracaldera andesitic dome at 359±7.9 ka provides a minimum age of caldera formation and extends the caldera history back ~ 320 ka years. The variable composition of the intracaldera domes, the presence of mafic enclaves in the dome lavas, mafic clasts in the TB4 plinian fall, mafic banding in the TB3 and TB2, attest to the obvious involvement of a more mafic magma The highly evolved compositions of the pyroclastic units and the volume of erupted material, point towards a large evolving magma reservoir at depth. The mafic magma may replenish the subsurface reservoir and act as a catalyst for volcanic eruption. The presence of an intracaldera lake, the regularity with which the volcano erupts and the presence of a more mafic magma are the ingredients for a catastrophic disaster. The Ilopango caldera, located 10 km to the east of the capital city of San Salvador (~ 1.5 million people) poses a threat both locally and globally as demonstrated 1600 years ago as it

Total grain-size distribution of four subplinian-Plinian tephras from Hekla volcano, Iceland: Implications for sedimentation dynamics and eruption source parameters

NASA Astrophysics Data System (ADS)

Janebo, Maria H.; Houghton, Bruce F.; Thordarson, Thorvaldur; Bonadonna, Costanza; Carey, Rebecca J.

2018-05-01

The size distribution of the population of particles injected into the atmosphere during a volcanic explosive eruption, i.e., the total grain-size distribution (TGSD), can provide important insights into fragmentation efficiency and is a fundamental source parameter for models of tephra dispersal and sedimentation. Recent volcanic crisis (e.g. Eyjafjallajökull 2010, Iceland and Córdon Caulle 2011, Chile) and the ensuing economic losses, highlighted the need for a better constraint of eruption source parameters to be used in real-time forecasting of ash dispersal (e.g., mass eruption rate, plume height, particle features), with a special focus on the scarcity of published TGSD in the scientific literature. Here we present TGSD data associated with Hekla volcano, which has been very active in the last few thousands of years and is located on critical aviation routes. In particular, we have reconstructed the TGSD of the initial subplinian-Plinian phases of four historical eruptions, covering a range of magma composition (andesite to rhyolite), eruption intensity (VEI 4 to 5), and erupted volume (0.2 to 1 km3). All four eruptions have bimodal TGSDs with mass fraction of fine ash (<63 μm; m63) from 0.11 to 0.25. The two Plinian dacitic-rhyolitic Hekla deposits have higher abundances of fine ash, and hence larger m63 values, than their andesitic subplinian equivalents, probably a function of more intense and efficient primary fragmentation. Due to differences in plume height, this contrast is not seen in samples from individual sites, especially in the near field, where lapilli have a wider spatial coverage in the Plinian deposits. The distribution of pyroclast sizes in Plinian versus subplinian falls reflects competing influences of more efficient fragmentation (e.g., producing larger amounts of fine ash) versus more efficient particle transport related to higher and more vigorous plumes, displacing relatively coarse lapilli farther down the dispersal axis.

Eruption History and Geochemical Evolution of Servilleta Basalt Along the Rio Grande Gorge, Colorado and New Mexico

NASA Astrophysics Data System (ADS)

Cosca, M. A.; Thompson, R. A.; Turner, K. J.; Morgan, L. E.

2016-12-01

Subalkaline basalt to basaltic andesite lava flows formally known as Servilleta Basalt (SB) are the most voluminous rock type forming the Pliocene Taos Plateau volcanic field. Pleistocene incision by the Rio Grande into the bedrock-floored plateau has resulted in spectacular exposures of occasionally thick ( 240 m) accumulations of SB within the Rio Grande gorge. Incremental CO2 laser heating of individual rock fragments, the SB within and along the length of the Rio Grande gorge has been precisely dated by 40Ar/39Ar geochronology to between 5.3 Ma and 3.3 Ma. SB older than 4 Ma is restricted to some lava flows exposed between La Junta point, at the confluence of the Red River and Rio Grande, and the Gorge Bridge crossing northwest of Taos, NM. Vertical sampling through thick SB flow sequences within the gorge yields precise emplacement histories and also reveals small but systematic major and minor element concentration variations (including Si, Rb, Sr, Cu and Zn). 40Ar/39Ar data show that these trends developed over short (0-250 ka) timescales, and probably relate to partial assimilation of crust, possibly at multiple depths. Combined field, geochemical, and 40Ar/39Ar data consequently record short-lived changes in tholeiitic melt compositions in response to regional extension and development of the Rio Grande rift. The age, lateral extent, and thickness of exposed SB partially reflect the paleotopographic surface of the southern San Luis Basin prior to onset of Pliocene Taos Plateau volcanic field magmatism; paleotopographic highs diverted some flows while topographic lows were areas of infilling and accumulation. Heterogeneous basin paleotopography developed during contemporaneous or precursory andesitic to dacitic volcanism, extensional faulting and subsidence of sub-basins within the San Luis Basin, and deposition of prograding alluvial fans that originated in the Sangre de Cristo and Picuris Mountains. SB flowed into the southern San Luis Valley beginning 5

The `Strawberry Volcanic Field' of Northeastern Oregon: Another Piece of the CRB Puzzle?

NASA Astrophysics Data System (ADS)

Steiner, A. R.; Streck, M. J.

2010-12-01

The Mid to Late Miocene Strawberry Volcanics field (SVF) located along the southern margin of the John Day valley of NE Oregon, comprise a diverse group of volcanic rocks ranging from basalt to rhyolite. The main outcrop area of the SVF (3,400 km2) is bordered by units from the Columbia River Basalt Group (CRBG), with the main CRB units to the north, the Picture Gorge Basalt to the east and Steens Basalt to the south. The geographic position and age of the Strawberry Volcanics make a genetic relationship to CRB volcanism likely, yet little is known about this diverse volcanic field. This research aims at refining the stratigraphic and age relationships as well as the petrology and geochemistry of magmas associated with the SVF. Previous investigations (e.g. Robyn, 1977) found that the SVF was active between 20 to 10 Ma with the main pulse largely being coeval with the 15 Ma CRBG eruptions. Lavas and tuffs from the SVF are calc-alkaline with low FeO*/MgO (~ 2.56 wt. %), high Al2O3 (~ 16.4 wt. %), low TiO2 (~ 1.12 wt.%), and span the entire compositional range from basalt to rhyolite (47-78 wt. % SiO2) with andesite as the dominant lithology. Basaltic lavas from the SVF have compositional affinities to earlier Steens Basalt, and some trace element concentrations and ratios are indistinguishable from those of CRBG lavas (e.g. Zr, Ba, Sr, and Ce/Y). Andesites are calc-alkaline, but contrary to typical arc (orogenic) andesites, SVF andesites are exceedingly phenocryst poor (<3% phenocrysts with microphenocrysts of plagioclase and lesser pyroxene which occasionally occur in crystal clots instead of single crystals). In addition, some lavas (basaltic-intermediate) are phenocryst-rich (~25%), containing plagioclase, olivine, opx, and cpx. However, phenocrysts in these lavas are strongly zoned and resorbed, and in general, these lavas are volumetrically insignificant compared with the phenocrysts poor andesites. Rhyolitic lavas are also phenocryst poor (< 3%) and appear to

Airborne dust transport to the eastern Pacific Ocean off southern California: Evidence from San Clemente Island

USGS Publications Warehouse

Muhs, D.R.; Budahn, J.; Reheis, M.; Beann, J.; Skipp, G.; Fisher, E.

2007-01-01

Islands are natural dust traps, and San Clemente Island, California, is a good example. Soils on marine terraces cut into Miocene andesite on this island are clay-rich Vertisols or Alfisols with vertic properties. These soils are overlain by silt-rich mantles, 5-20 cm thick, that contrast sharply with the underlying clay-rich subsoils. The silt mantles have a mineralogy that is distinct from the island bedrock. Silt mantles are rich in quartz, which is rare in the island andesite. The clay fraction of the silt mantles is dominated by mica, also absent from local andesite, and contrasts with the subsoils, dominated by smectite. Ternary plots of immobile trace elements (Sc-Th-La and Ta-Nd-Cr) show that the island andesite has a composition intermediate between average upper continental crust and average oceanic crust. In contrast, the silt and, to a lesser extent, clay fractions of the silt mantles have compositions closer to average upper continental crust. The silt mantles have particle size distributions similar to loess and Mojave Desert dust, but are coarser than long-range-transported Asian dust. We infer from these observations that the silt mantles are derived from airborne dust from the North American mainland, probably river valleys in the coastal mountains of southern California and/or the Mojave Desert. Although average winds are from the northwest in coastal California, easterly winds occur numerous times of the year when "Santa Ana" conditions prevail, caused by a high-pressure cell centered over the Great Basin. Examination of satellite imagery shows that easterly Santa Ana winds carry abundant dust to the eastern Pacific Ocean and the California Channel Islands. Airborne dust from mainland North America may be an important component of the offshore sediment budget in the easternmost Pacific Ocean, a finding of potential biogeochemical and climatic significance.

Bulk rock composition and geochemistry of olivine-hosted melt inclusions in the Grey Porri Tuff and selected lavas of the Monte dei Porri volcano, Salina, Aeolian Islands, southern Italy

USGS Publications Warehouse

Doherty, Angela L.; Bodnar, Robert J.; De Vivo, Benedetto; Bohrson, Wendy A.; Belkin, Harvey E.; Messina, Antonia; Tracy, Robert J.

2012-01-01

The Aeolian Islands are an arcuate chain of submarine seamounts and volcanic islands, lying just north of Sicily in southern Italy. The second largest of the islands, Salina, exhibits a wide range of compositional variation in its erupted products, from basaltic lavas to rhyolitic pumice. The Monte dei Porri eruptions occurred between 60 ka and 30 ka, following a period of approximately 60,000 years of repose. The bulk rock composition of the Monte dei Porri products range from basaltic-andesite scoria to andesitic pumice in the Grey Porri Tuff (GPT), with the Monte dei Porri lavas having basaltic-andesite compositions. The typical mineral assemblage of the GPT is calcic plagioclase, clinopyroxene (augite), olivine (Fo72−84) and orthopyroxene (enstatite) ± amphibole and Ti-Fe oxides. The lava units show a similar mineral assemblage, but contain lower Fo olivines (Fo57−78). The lava units also contain numerous glomerocrysts, including an unusual variety that contains quartz, K-feldspar and mica. Melt inclusions (MI) are ubiquitous in all mineral phases from all units of the Monte dei Porri eruptions; however, only data from olivine-hosted MI in the GPT are reported here. Compositions of MI in the GPT are typically basaltic (average SiO2 of 49.8 wt %) in the pumices and basaltic-andesite (average SiO2 of 55.6 wt %) in the scoriae and show a bimodal distribution in most compositional discrimination plots. The compositions of most of the MI in the scoriae overlap with bulk rock compositions of the lavas. Petrological and geochemical evidence suggest that mixing of one or more magmas and/or crustal assimilation played a role in the evolution of the Monte dei Porri magmatic system, especially the GPT. Analyses of the more evolved mineral phases are required to better constrain the evolution of the magma.

Economic significance of revised age relations of rocks in the Cornucopia mining district, Elko County, Nevada

USGS Publications Warehouse

Coats, Robert Roy

1967-01-01

Recent geologic work in the Cornucopia mining district, a small silver-gold mining district in northwestern Elko County, Nev., has resulted in significant revision of the geological interpretation. Rocks formerly thought to be premineralization in age, but unmineralized, are now known to be postmineral extrusives, resting unconformably on the altered andesite in which the ore bodies are found. Extensions of the known productive veins may be expected at shallow depth beneath the younger volcanic rocks, and are separated from the mined part of the veins by postmineral high-angle faults that have brought the younger volcanic rocks into fault contact with the mineralized andesite. Some veins are apparently terminated against premineral faults.

Geologic Reconnaissance of the Antelope-Ashwood Area, North-Central Oregon: With Emphasis on the John Day Formation of Late Oligocene and Early Miocene Age

USGS Publications Warehouse

Peck, Dallas L.

1964-01-01

This report briefly describes the geology of an area of about 750 square miles in Jefferson, Wasco, Crook, and Wheeler Counties, Oregon. About 16,000 feet of strata that range in age from pre-Tertiary to Quaternary are exposed. These include the following units: pre-Tertiary slate, graywacke, conglomerate, and meta-andesite; Clarno Formation of Eocene age - lava flows, volcanic breccia, tuff, and tuffaceous mudstone, chiefly of andesitic composition; John Day Formation of late Oligocene and early Miocene age - pyroclastic rocks, flows, and domes, chiefly of rhyolitic composition; Columbia River Basalt of middle Miocene age - thick, columnar jointed flows of very fine grained dense dark-gray basalt; Dalles Formation of Pliocene age - bedded tuffaceous sandstone, siltstone, and conglomerate; basalt of Pliocene or Pleistocene age - lava flows of porous-textured olivine basalt; and Quaternary loess, landslide debris, and alluvium. Unconformities separate pre-Tertiary rocks and Clarno Formation, Clarno and John Day Formations, John Day Formation and Columbia River Basalt, and Columbia River Basalt and Dalles Formation. The John Day Formation, the only unit studied in detail, consists of about 4,000 feet of tuff, lapilli tuff, strongly to weakly welded rhyolite ash flows, and less abundant trachyandesite flows and rhyolite flows and domes. The formation was divided into nine mappable members in part of the area, primarily on the basis of distinctive ledge-forming welded ash-flow sheets. Most of the sheets are composed of stony rhyolite containing abundant lithophysae and sparse phenocrysts. One sheet contains 10 to 20 percent phenocrysts, mostly cryptoperthitic soda sanidine, but including less abundant quartz, myrmekitic intergrowths of quartz and sanidine, and oligoclase. The rhyolitic ash flows and lava flows were extruded from nearby vents, in contrast to some of the interbedded air-fall tuff and lapilli tuff of dacitic and andesitic composition that may have been

Silicic, high- to extremely high-grade ignimbrites and associated deposits from the Paraná Magmatic Province, southern Brazil

NASA Astrophysics Data System (ADS)

Luchetti, Ana Carolina F.; Nardy, Antonio J. R.; Madeira, José

2018-04-01

The Cretaceous trachydacites and dacites of Chapecó type (ATC) and dacites and rhyolites of Palmas type (ATP) make up 2.5% of the 800.000 km3 of volcanic pile in the Paraná Magmatic Province (PMP), emplaced at the onset of Gondwana breakup. Together they cover extensive areas in southern Brazil, overlapping volcanic sequences of tholeiitic basalts and andesites; occasional mafic units are also found within the silicic sequence. In the central region of the PMP silicic volcanism comprises porphyritic ATC-type, trachydacite high-grade ignimbrites (strongly welded) overlying aphyric ATP-type, rhyolite high- to extremely high-grade ignimbrites (strongly welded to lava-like). In the southwestern region strongly welded to lava-like high-grade ignimbrites overlie ATP lava domes, while in the southeast lava domes are found intercalated within the ignimbrite sequence. Characteristics of these ignimbrites are: widespread sheet-like deposits (tens to hundreds of km across); absence of basal breccias and basal fallout layers; ubiquitous horizontal to sub-horizontal sheet jointing; massive, structureless to horizontally banded-laminated rock bodies locally presenting flow folding; thoroughly homogeneous vitrophyres or with flow banding-lamination; phenocryst abundance presenting upward and lateral decrease; welded glass blobs in an 'eutaxitic'-like texture; negligible phenocryst breakage; vitroclastic texture locally preserved; scarcity of lithic fragments. These features, combined with high eruption temperatures (≥ 1000 °C), low water content (≤ 2%) and low viscosities (104-7 Pa s) suggest that the eruptions were characterized by low fountaining, little heat loss during collapse, and high mass fluxes producing extensive deposits.

Waste disposal mapping with electrical resistivity tomography case: Leuwigajah landfill

NASA Astrophysics Data System (ADS)

Aryanti, Erisha; Ardi, Ahmad Puji; Almunziri, Muaz; Xanggam, Zael Yahd; Eleazar, Adino; Widodo

2017-07-01

Leuwigajah landfill as administrative is located between district of Bandung and Cimahi citythat has an environmental and social problem that caused aquifer contamination due to the big amount of waste from Bandung city, Cimahi and Bandung regency. It is occupied in abandoned andesite mine site with an area of about 25 hectare. The aim of this research is to map the geology structure and to study the leachate towards aquifer layer below Leuwigajah landfill. Here, we present the study of Leuwigajah landfill subsurface using Electrical Resistivity Tomography (ERT). ERT is one of the most promising prospecting techniques mainly concerning its effective contribution to resolve several environmental problems, was applied for the geophysical modeling. ERT is a robust imaging method the theory and implementation of which are well documented in geophysical research literature. The geological setting comprises clayed weathered layer, fractured andesitic dike. Due to the above-mentioned geological singularity and in the light of the requirement for an environmentally safe construction of the landfill, an ERT survey was carried out with dipole-dipole array, 78 m of acquisition line and 6 m of electrode spacing. The model consists of 4 layers below the Leuwigajah landfill and andesitic fracture until depth of 18.7 m below the surface.

Petrological and experimental evidence for differentiation of water-rich magmas beneath St. Kitts, Lesser Antilles

NASA Astrophysics Data System (ADS)

Melekhova, Elena; Blundy, Jon; Martin, Rita; Arculus, Richard; Pichavant, Michel

2017-12-01

St. Kitts lies in the northern Lesser Antilles, a subduction-related intraoceanic volcanic arc known for its magmatic diversity and unusually abundant cognate xenoliths. We combine the geochemistry of xenoliths, melt inclusions and lavas with high pressure-temperature experiments to explore magma differentiation processes beneath St. Kitts. Lavas range from basalt to rhyolite, with predominant andesites and basaltic andesites. Xenoliths, dominated by calcic plagioclase and amphibole, typically in reaction relationship with pyroxenes and olivine, can be divided into plutonic and cumulate varieties based on mineral textures and compositions. Cumulate varieties, formed primarily by the accumulation of liquidus phases, comprise ensembles that represent instantaneous solid compositions from one or more magma batches; plutonic varieties have mineralogy and textures consistent with protracted solidification of magmatic mush. Mineral chemistry in lavas and xenoliths is subtly different. For example, plagioclase with unusually high anorthite content (An≤100) occurs in some plutonic xenoliths, whereas the most calcic plagioclase in cumulate xenoliths and lavas are An97 and An95, respectively. Fluid-saturated, equilibrium crystallisation experiments were performed on a St. Kitts basaltic andesite, with three different fluid compositions ( XH2O = 1.0, 0.66 and 0.33) at 2.4 kbar, 950-1025 °C, and fO2 = NNO - 0.6 to NNO + 1.2 log units. Experiments reproduce lava liquid lines of descent and many xenolith assemblages, but fail to match xenolith and lava phenocryst mineral compositions, notably the very An-rich plagioclase. The strong positive correlation between experimentally determined plagioclase-melt KdCa-Na and dissolved H2O in the melt, together with the occurrence of Al-rich mafic lavas, suggests that parental magmas were water-rich (> 9 wt% H2O) basaltic andesites that crystallised over a wide pressure range (1.5-6 kbar). Comparison of experimental and natural (lava

Petrology and geochemistry of the high-pressure Nilgiri Granulite Terrane, Southern India

NASA Technical Reports Server (NTRS)

Srikantappa, C.; Ashamanjari, K. G.; Raith, M.

1988-01-01

The Nilgiri granulite terrane in Southern India is predominantly composed of late Archaean medium- to coarse-grained enderbitic to charnockitic rocks. The dominant regional foliation strikes N60 to 70E with generally steep dips. Tight minor isoclinal folds have been observed in places. Granoblastic polygonal micro-structures are common and indicate thorough post-kinematic textural and chemical equilibration at conditions of the granulite facies (2.5 Ga ago). Late compressional deformation in connection with the formation of the Moyar and Bhavani shear zones to the north and south of the Nilgiri block, resulted in wide-spread development of weakly to strongly strained fabrics and was accompanied by minor rehydration. Enderbites and charnockites range from tonalitic to granodioritic in composition. A magmatogenic origin of the protoliths is inferred from their chemical characteristics which resemble those of the andesitic to dacitic members of Cordillera-type calc-alkaline igneous suites. A significant lithological feature of the Nilgiri granulite terrane are numerous extended bodies, lenses and pods of gabbroic and pyroxenitic rocks which are aligned conformable to the foliation of the enderbite-charnockite complex and which have also been deformed and metamorphosed at granulite facies conditions.

U-Th-Pb zircon dating of the 13.8-Ma dacite volcanic dome at Cerro Rico de Potosi, Bolivia

USGS Publications Warehouse

Zartman, R.E.; Cunningham, C.G.

1995-01-01

The temporal relationship between the extrusion of the Miocene dacite volcanic dome at Cerro Rico de Potasi, Bolivia, and the associated Ag-Sn mineralization has an important bearing on the heat and metal sources for this world class mineral deposit. The present study uses U-Th-Pb dating of sparse zircon contained in the dacite to demonstrate that, at most, only several hundred thousand years separate dome emplacement from main stage mineralization. -from Authors

Dacitic ash-flow sheet near Superior and Globe, Arizona

USGS Publications Warehouse

Peterson, Donald W.

1961-01-01

Remnants of a dacitic ash-flow sheet near Globe, Miama, and Superia, Arizona cover about 100 square miles; before erosion the area covered by the sheet was at least 400 square miles and perhaps as much as 1,500 square miles. Its maximum thickness is about 2,000 feet, its average thickness is about 500 feet, and its original volume was at least 40 cubic miles. It was erupted on an eroded surface with considerable relief. The main part of the deposit was thought by early workers to be a lava flow. Even after the distinctive character of welded tuffs and related rocks was discovered, the nature and origin of this deposit remained dubious because textures did not correspond to those in other welded tuff bodies. Yet a lava flow as silicic as this dacite would be viscous instead of spreading out as an extensive sheet. The purpose of this investigation has been to study the deposit, resolve the inconsistencies, and deduce its origin and history. Five stratigraphic zones are distinguished according to differences in the groundmass. From bottom to top the zones are basal tuff, vitrophyre, brown zone, gray zone, and white zone. The three upper zones are distinguished by colors on fresh surfaces, for each weathers to a similar shade of light reddish brown. Nonwelded basal tuff grades upward into the vitrophyre, which is a highly welded tuff. The brown and gray zones consist of highly welded tuff with a lithoidal groundmass. Degree of welding decreases progressively upward through the gray and the white zones, and the upper white zone is nonwelded. Textures are clearly outlined in the lower part of the brown zone, but upward they become more diffuse because of increasing devitrification. In the white zone, original textures are essentially obliterated, and the groundmass consists of spherulites and microcrystalline intergrowths. The chief groundmass minerals are cristobalite and sanidine, with lesser quartz and plagioclase. Phenocrysts comprise about 40 percent of the rock

Storage and interaction of compositionally heterogeneous magmas from the 1986 eruption of Augustine Volcano, Alaska

USGS Publications Warehouse

Roman, Diana C.; Cashman, Katharine V.; Gardner, Cynthia A.; Wallace, Paul J.; Donovan, John J.

2006-01-01

Compositional heterogeneity (56–64 wt% SiO2 whole-rock) in samples of tephra and lava from the 1986 eruption of Augustine Volcano, Alaska, raises questions about the physical nature of magma storage and interaction beneath this young and frequently active volcano. To determine conditions of magma storage and evolutionary histories of compositionally distinct magmas, we investigate physical and chemical characteristics of andesitic and dacitic magmas feeding the 1986 eruption. We calculate equilibrium temperatures and oxygen fugacities from Fe-Ti oxide compositions and find a continuous range in temperature from 877 to 947°C and high oxygen fugacities (ΔNNO=1–2) for all magmas. Melt inclusions in pyroxene phenocrysts analyzed by Fourier-transform infrared spectroscopy and electron probe microanalysis are dacitic to rhyolitic and have water contents ranging from <1 to ∼7 wt%. Matrix glass compositions are rhyolitic and remarkably similar (∼75.9–76.6 wt% SiO2) in all samples. All samples have ∼25% phenocrysts, but lower-silica samples have much higher microlite contents than higher-silica samples. Continuous ranges in temperature and whole-rock composition, as well as linear trends in Harker diagrams and disequilibrium mineral textures, indicate that the 1986 magmas are the product of mixing between dacitic magma and a hotter, more mafic magma. The dacitic endmember is probably residual magma from the previous (1976) eruption of Augustine, and we interpret the mafic endmember to have been intruded from depth. Mixing appears to have continued as magmas ascended towards the vent. We suggest that the physical structure of the magma storage system beneath Augustine contributed to the sustained compositional heterogeneity of this eruption, which is best explained by magma storage and interaction in a vertically extensive system of interconnected dikes rather than a single coherent magma chamber and/or conduit. The typically short repose period (∼10

Geologic map of the Lassen region, Cascade Range, USA

USGS Publications Warehouse

Clynne, Michael; Muffler, L.J.

1990-01-01

A preliminary geologic map at 1:50,000 of the Lassen region encompasses 1400 km2. The map displays many small, monogenetic volcanoes of basalt to andesite as well as three major late Pliocene and Quaternary volcanic centers that have erupted products ranging from basaltic andesite to rhyolite. The youngest of these volcanic centers is the Lassen volcanic center, active from 600,000 years B.P. to the present. A major caldera formed at 400,000 years B.P. and has subsequently been filled with silicic lavas. The Lassen geothermal system, which consists of a central vapor-dominated reservoir at a temperature of 235??C underlain by a reservoir of hot water, is centered at Bumpass Hell within Lassen Volcanic National Park.

Tectonic evolution of Honey Lake basin, northeastern California

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wagner, D.L.; Saucedo, G.J.; Grose, T.L.T.

New geologic mapping in northeastern California provides additional data on the age and tectonic evolution of the Honey Lake Basin. Rhylitic ash flow tuffs of latest Oligocene to early Miocene age (30 to 22 Ma) occur in the Fort Sage Mountains and in the Sierra Nevada but are not apparent in wells drilled in the Honey Lake basin. Though other interpretations can be made, the authors take this as evidence that the basin did not exist at that time. Volcanic rocks as old as 12 Ma do occur in the basin indicating initiation in mid-Miocene time probably as a grabenmore » due to block faulting. Syntectonic andesitic and basaltic volcanism occurred along faults bounding the Sierra Nevada block at 9 to 10 Ma. Lava issuing from these fractures flowed westward along Tertiary drainages indicating that the Sierran block had been uplifted and tilted westward. Andesites erupted during this time north and east of the basin are lithologically distinct from Sierran andesites. Strike-slip faulting began to dominate the tectonic setting of the region during late Pliocene and Quaternary time with the development of the Honey Lake Fault Zone. Holocene strike-slip displacement is indicated by offsets of the 12,000 year old Lake Lahontan shoreline and deposits containing a 7,000 year old ash.« less

Audio-magnetotelluric (AMT) study to investigate the genesis of Mujil hill

NASA Astrophysics Data System (ADS)

Rahmania, Suryanto, Wiwit

2017-07-01

Gunung Mujil is an isolated hill located near Pondoworejo village, Kalibawang sub-district, Kulon Progo district, and Special Province of Yogyakarta. The hill is part of the eastern Kulon Progo mountain range extended relatively in the North-South direction. The lithology of the hill consists of andesite breccia and it's similar with the Old Andesite Formation that built the Kulon Progo Mountains. There are at least two hypothesis about the genesis and the formation mechanism of this hill, (1) it was formed by debris mass from Kulon Progo Mountains, and (2) ) it was formed by an intrusion. Our study intended to determine the subsurface resistivity below the hill and to relating those results to with the scenario of the genesis of the Mujil hill. We conducted Audio-magnetotellurics (AMT) measurements along two lines survey crossing the Mujil hill consisting of 20 measurements. Since the measurements are located near the villages, most of the data has a fair to bad quality and only one station yielded an excellent data. A 1D Forward modeling was then applied to find best-fit model of the AMT data. The results shows that the Mujil hill was built by debris mass of the Old Andesite Formation from Kulon Progo mountain which is represented by a lower resistivity value under the Mujil hill.

Magmatic interactions as recorded in plagioclase phenocrysts of Chaos Crags, Lassen Volcanic Center, California

USGS Publications Warehouse

Tepley, F. J.; Davidson, J.P.; Clynne, M.A.

1999-01-01

The silicic lava domes of Chaos Crags in Lassen Volcanic National Park contain a suite of variably quenched, hybrid basaltic andesite magmatic inclusions. The inclusions represent thorough mixing between rhyodacite and basalt recharge liquids accompanied by some mechanical disaggregation of the inclusions resulting in crystals mixing into the rhyodacite host preserved by quenching on dome emplacement. 87Sr/86Sr ratios (~0.7037-0.7038) of the inclusions are distinctly lower than those of the host rhyodacite (~0.704-0.7041), which are used to fingerprint the origin of mineral components and to monitor the mixing and mingling process. Chemical, isotopic, and textural characteristics indicate that the inclusions are hybrid magmas formed from the mixing and undercooling of recharge basaltic magma with rhyodacitic magma. All the host magma phenocrysts (biotite, plagioclase, hornblende and quartz crystals) also occur in the inclusions, where they are rimmed by reaction products. Compositional and strontium isotopic data from cores of unresorbed plagioclase crystals in the host rhyodacite, partially resorbed plagioclase crystals enclosed within basaltic andesite inclusions, and partially resorbed plagioclase crystals in the rhyodacitic host are all similar. Rim 87Sr/86Sr ratios of the partially resorbed plagioclase crystals in both inclusions and host are lower and close to those of the whole-rock hybrid basaltic andesite values. This observation indicates that some crystals originally crystallized in the silicic host, were partially resorbed and subsequently overgrown in the hybrid basaltic andesite magma, and then some of these partially resorbed plagioclase crystals were recycled back into the host rhyodacite. Textural evidence, in the form of sieve zones and major dissolution boundaries of the resorbed plagioclase crystals, indicates immersion of crystals into a hotter, more calcic magma. The occurrence of partially resorbed plagioclase together with plagioclase

Late Cretaceous infant intra-oceanic arc volcanism, the Central Pontides, Turkey: Petrogenetic and tectonic implications

NASA Astrophysics Data System (ADS)

Aygül, Mesut; Okay, Aral I.; Oberhänsli, Roland; Schmidt, Alexander; Sudo, Masafumi

2015-11-01

A tectonic slice of an arc sequence consisting of low-grade metavolcanic rocks and overlying metasedimentary succession is exposed in the Central Pontides north of the İzmir-Ankara-Erzincan suture separating Laurasia from Gondwana-derived terranes. The metavolcanic rocks mainly consist of basaltic andesite/andesite and mafic cognate xenolith-bearing rhyolite with their pyroclastic equivalents, which are interbedded with recrystallized pelagic limestone and chert. The metasedimentary succession comprises recrystallized micritic limestone with rare volcanogenic metaclastic rocks and stratigraphically overlies the metavolcanic rocks. The geochemistry of the metavolcanic rocks indicates an arc setting evidenced by depletion of HFSE (Ti, P and Nb) and enrichment of fluid mobile LILE. Identical trace and rare earth elements compositions of basaltic andesites/andesites and rhyolites suggest that they are cogenetic and derived from a common parental magma. The arc sequence crops out between an Albian-Turonian subduction-accretionary complex representing the Laurasian active margin and an ophiolitic mélange. Absence of continent derived detritus in the arc sequence and its tectonic setting in a wide Cretaceous accretionary complex suggest that the Kösdağ Arc was intra-oceanic. Zircons from two metarhyolite samples give Late Cretaceous (93.8 ± 1.9 and 94.4 ± 1.9 Ma) U/Pb ages. These ages are the same as the age of the supra-subduction ophiolites in western Turkey, which implies that that the Kösdağ Arc may represent part of the incipient arc formed during the generation of the supra-subduction ophiolites. The low-grade regional metamorphism in the Kösdağ Arc is constrained to 69.9 ± 0.4 Ma by 40Ar/39Ar muscovite dating indicating that the arc sequence became part of a wide Tethyan Cretaceous accretionary complex by the latest Cretaceous. Non-collisional cessation of the arc volcanism is possibly associated with southward migration of the magmatism as in the Izu

Oligocene and Miocene arc volcanism in northeastern California: evidence for post-Eocene segmentation of the subducting Farallon plate

USGS Publications Warehouse

Colgan, J.P.; Egger, A.E.; John, D.A.; Cousens, B.; Fleck, R.J.; Henry, C.D.

2011-01-01

The Warner Range in northeastern California exposes a section of Tertiary rocks over 3 km thick, offering a unique opportunity to study the long-term history of Cascade arc volcanism in an area otherwise covered by younger volcanic rocks. The oldest locally sourced volcanic rocks in the Warner Range are Oligocene (28–24 Ma) and include a sequence of basalt and basaltic andesite lava flows overlain by hornblende and pyroxene andesite pyroclastic flows and minor lava flows. Both sequences vary in thickness (0–2 km) along strike and are inferred to be the erosional remnants of one or more large, partly overlapping composite volcanoes. No volcanic rocks were erupted in the Warner Range between ca. 24 and 16 Ma, although minor distally sourced silicic tuffs were deposited during this time. Arc volcanism resumed ca. 16 Ma with eruption of basalt and basaltic andesite lavas sourced from eruptive centers 5–10 km south of the relict Oligocene centers. Post–16 Ma arc volcanism continued until ca. 8 Ma, forming numerous eroded but well-preserved shield volcanoes to the south of the Warner Range. Oligocene to Late Miocene volcanic rocks in and around the Warner Range are calc-alkaline basalts to andesites (48%–61% SiO2) that display negative Ti, Nb, and Ta anomalies in trace element spider diagrams, consistent with an arc setting. Middle Miocene lavas in the Warner Range are distinctly different in age, composition, and eruptive style from the nearby Steens Basalt, with which they were previously correlated. Middle to Late Miocene shield volcanoes south of the Warner Range consist of homogeneous basaltic andesites (53%–57% SiO2) that are compositionally similar to Oligocene rocks in the Warner Range. They are distinctly different from younger (Late Miocene to Pliocene) high-Al, low-K olivine tholeiites, which are more mafic (46%–49% SiO2), did not build large edifices, and are thought to be related to backarc extension. The Warner Range is ∼100 km east of the

Petrology of the zoned calcalkaline magma chamber of Mount Mazama, Crater Lake, Oregon

USGS Publications Warehouse

Druitt, T.H.; Bacon, C.R.

1989-01-01

Evolution of the magma chamber at Mount Mazama involved repeated recharge by two types of andesite (high-Sr and low-Sr), crystal fractionation, crystal accumulation, assimilation, and magma mixing (Bacon and Druitt 1988). This paper addresses the modal compositions, textures, mineral chemistry and magmatic temperatures of (i) products of the 6845??50 BP climactic eruption, (ii) blocks of partially fused granitoid wallrock found in the ejecta, and (iii) preclimactic rhyodacitic lavas leaked from the chamber in late Pleistocene and early Holocene time. Immediately prior to the climactic eruption the chamber contained ??? 40 km3 of rhyodacite (10 vol% plag + opx + aug + hb + mt + ilm, ???880?? C) overlying high-Sr andesite and cumulus-crystal mush (28-51 vol% plag + hb ?? opx ?? aug + mt ?? ilm, 880?? to ???950?? C), which in turn overlay low-Sr crystal mush (50-66 vol% plag + opx + aug ?? hb ?? ol + mt + ilm, 890?? to ???950??? C). Despite the well known compositional gap in the ejecta, no thermal discontinuity existed in the chamber. Pre-eruptive water contents of pore liquids in most high-Sr and low-Sr mushes were 4-6 wt%, but on average the high-Sr mushes were slightly richer in water. Although parental magmas of the crystal mushes were andesitic, xenocrysts of bytownite and Ni-rich magnesian olivine in some scoriae record the one-time injection of basalt into the chamber. Textures in ol-bearing scoriae preserve evidence for the reactions ol + liq = opx and ol + aug + liq(+ plag?) = hb, which occurred in andesitic liquids at Mount Mazama. Strontium abundances in plagioclase phenocrysts constrain the petrogenesis of preclimactic and climactic rhyodacites. Phenocryst cores derived from high-Sr and low-Sr magmas have different Sr contents which can be resolved by microprobe. Partition coefficients for plagioclase in andesitic to rhyolitic glasses range from 2 to 7, and increase as glass %SiO2 increases. Evolved Pleistocene rhyodacites (???30-25,000 BP) and

An experimental study of permeability development as a function of crystal-free melt viscosity

NASA Astrophysics Data System (ADS)

Lindoo, A.; Larsen, J. F.; Cashman, K. V.; Dunn, A. L.; Neill, O. K.

2016-02-01

Permeability development in magmas controls gas escape and, as a consequence, modulates eruptive activity. To date, there are few experimental controls on bubble growth and permeability development, particularly in low viscosity melts. To address this knowledge gap, we have run controlled decompression experiments on crystal-free rhyolite (76 wt.% SiO2), rhyodacite (70 wt.% SiO2), K-phonolite (55 wt.% SiO2) and basaltic andesite (54 wt.% SiO2) melts. This suite of experiments allows us to examine controls on the critical porosity at which vesiculating melts become permeable. As starting materials we used both fine powders and solid slabs of pumice, obsidian and annealed starting materials with viscosities of ∼102 to ∼106 Pas. We saturated the experiments with water at 900° (rhyolite, rhyodacite, and phonolite) and 1025 °C (basaltic andesite) at 150 MPa for 2-72 hrs and decompressed samples isothermally to final pressures of 125 to 10 MPa at rates of 0.25-4.11 MPa/s. Sample porosity was calculated from reflected light images of polished charges and permeability was measured using a bench-top gas permeameter and application of the Forchheimer equation to estimate both viscous (k1) and inertial (k2) permeabilities. Degassing conditions were assessed by measuring dissolved water contents using micro-Fourier-Transform Infrared (μ-FTIR) techniques. All experiment charges are impermeable below a critical porosity (ϕc) that varies among melt compositions. For experiments decompressed at 0.25 MPa/s, we find the percolation threshold for rhyolite is 68.3 ± 2.2 vol.%; for rhyodacite is 77.3 ± 3.8 vol.%; and for K-phonolite is 75.6 ± 1.9 vol.%. Rhyolite decompressed at 3-4 MPa/s has a percolation threshold of 74 ± 1.8 vol.%. These results are similar to previous experiments on silicic melts and to high permeability thresholds inferred for silicic pumice. All basaltic andesite melts decompressed at 0.25 MPa/s, in contrast, have permeabilities below the detection

Geologic Map of Lassen Volcanic National Park and Vicinity, California

USGS Publications Warehouse

Clynne, Michael A.; Muffler, L.J. Patrick

2010-01-01

detail (1:24,000) was modified for inclusion here. Figure 2 (sheet 3) shows the mapping credit for previous work; figure 3 (sheet 3) shows locations discussed throughout the text. A CD-ROM entitled Database for the Geologic Map of Lassen Volcanic National Park and Vicinity, California accompanies the printed map (Muffler and others, 2010). The CD-ROM contains ESRI compatible geographic information system data files used to create the 1:50,000-scale geologic map, both geologic and topographic data and their associated metadata files, and printable versions of the geologic map and pamphlet as PDF formatted files. The 1:50,000-scale geologic map was compiled from 1:24,000-scale geologic maps of individual quadrangles that are also included in the CD-ROM. It also contains ancillary data that support the map including locations of rock samples selected for chemical analysis (Clynne and others, 2008) and radiometric dating, photographs of geologic features, and links to related data or web sites. Data contained in the CD-ROM are also available on this Web site. The southernmost Cascade Range consists of a regional platform of basalt and basaltic andesite, with subordinate andesite and sparse dacite. Nested within these regional rocks are 'volcanic centers', defined as large, long-lived, composite, calc-alkaline edifices erupting the full range of compositions from basalt to rhyolite, but dominated by andesite and dacite. Volcanic centers are produced by the focusing of basaltic flux from the mantle and resultant enhanced interaction of mafic magma with the crust. Collectively, volcanic centers mark the axis of the southernmost Cascade Range. The map area includes the entire Lassen Volcanic Center, parts of three older volcanic centers (Maidu, Dittmar, and Latour), and the products of regional volcanism (fig. 4, sheet 3). Terminology used for subdivision of the Lassen Volcanic Center has been modified from Clynne (1984, 1990).

Bimodal Silurian and Lower Devonian volcanic rock assemblages in the Machias-Eastport area, Maine

USGS Publications Warehouse

Gates, Olcott; Moench, R.H.

1981-01-01

Exposed in the Machias-Eastport area of southeastern Maine is the thickest (at least 8,000 m), best exposed, best dated, and most nearly complete succession of Silurian and Lower Devonian volcanic strata in the coastal volcanic belt, remnants of which crop out along the coasts of southern New Brunswick, Canada, and southeastern New England in the United States. The volcanics were erupted through the 600-700-million-year-old Avalonian sialic basement. To test the possibility that this volcanic belt was a magmatic arc above a subduction zone prior to presumed Acadian continental collision, samples representing the entire section in the Machias-Eastport area of Maine were chemically analyzed. Three strongly bimodal assemblages of volcanic rocks and associated intrusives are recognized, herein called the Silurian, older Devonian, and younger Devonian assemblages. The Silurian assemblage contains typically nonporphyritic high-alumina tholeiitic basalts, basaltic andesites, and diabase of continental characterand calc-alkalic rhyolites, silicic dacites, and one known dike of andesite. These rocks are associated with fossiliferous, predominantly marine strata of the Quoddy, Dennys, and Edmunds Formations, and the Leighton Formation of the Pembroke Group (the stratigraphic rank of both is revised herein for the Machias-Eastport area), all of Silurian age. The shallow marine Hersey Formation (stratigraphic rank also revised herein) of the Pembroke Group, of latest Silurian age (and possibly earliest Devonian, as suggested by an ostracode fauna), contains no known volcanics; and it evidently was deposited during a volcanic hiatus that immediately preceded emergence of the coastal volcanic belt and the eruption of the older Devonian assemblage. The older Devonian assemblage, in the lagoonal to subaerial Lower Devonian Eastport Formation, contains tholeiitic basalts and basaltic andesites, typically with abundant plagioclase phenocrysts and typically richer in iron and

The Massive Compound Cofre de Perote Shield Volcano: a Volcanological Oddity in the Eastern Mexican Volcanic Belt

NASA Astrophysics Data System (ADS)

Siebert, L.; Carrasco-Nunez, G.; Diaz-Castellon, R.; Rodriguez, J. L.

2007-12-01

Cofre de Perote volcano anchors the northern end of the easternmost of several volcanic chains orthogonal to the E-W trend of the Mexican Volcanic Belt (MVB). Its structure, geochemistry, and volcanic history diverge significantly from that of the large dominantly andesitic stratovolcanoes that have been the major focus of research efforts in the MVB. Andesitic-trachyandesitic to dacitic-trachydacitic effusive activity has predominated at Cofre de Perote, forming a massive low-angle compound shield volcano that dwarfs the more typical smaller shield volcanoes of the central and western MVB. The 4282-m-high volcano overlooking Xalapa, the capital city of the State of Veracruz, has a diameter of about 30 km and rises more than 3000 m above the coastal plain to the east. Repeated edifice collapse has left massive horseshoe-shaped scarps that truncate the eastern side of the edifice. Five major evolutionary stages characterize the growth of this compound volcano: 1) emplacement of a multiple-vent dome complex forming the basal structure of Cofre de Perote around 1.9-1.3 Ma; 2) construction of the basal part of the compound shield volcano from at least two main upper-edifice vents at about 400 ka; 3) effusion of the summit dome-like lavas through multiple vents at ca. 240 ka; 4) eruption of a large number of geochemically diverse, alkaline and calc-alkaline Pleistocene-to-Holocene monogenetic cones (likely related to regional volcanism) through the flanks of the Cofre de Perote edifice; 5) late-stage, large-volume edifice collapse on at least two occasions (ca. 40 ka and ca. 10 ka), producing long-runout debris avalanches that traveled to the east. An undated tephra layer from Cofre de Perote overlies deposits likely of the youngest collapse. Cofre de Perote is one of several volcanoes in the roughly N-S-trending chain that has undergone major edifice collapse. As with Citlaltepetl (Pico de Orizaba) and Las Cumbres volcanoes, Cofre de Perote was constructed at the

Time Evolution of the Basse Terre Island (Guadeloupe, French West Indies) Effusive Volcanism from New K-Ar Cassignol-Gillot Ages.

NASA Astrophysics Data System (ADS)

Samper, A.; Quidelleur, X.; Mollex, D.; Komorowski, J. C.; Boudon, G.

2004-12-01

Radiometric dating and geochemistry of effusive volcanics have been combined with geomorphological observations in order to provide a general evolution model of the volcanic island of Basse Terre, Guadeloupe (French West Indies). More than forty new Cassignol-Gillot K-Ar ages distributed within the entire island, together with the twenty ages (Blanc, 1983; Carlut et al., 2000) previously obtained with the same technique, makes the Guadeloupe Island the best place to study the evolution of volcanic processes within the Lesser Antilles Arc. Dating was performed on the carefully separated groundmass in order to avoid K loss due to weathering and excess argon carried by mafic minerals. Ages obtained are relatively younger than previously thought on Basse Terre and range from a few ka to 2.79+-0.04 Ma. When available, the paleomagnetic polarity of the dated flows agree with the GPTS and a very good coherence of ages is observed for each massif. Our results demonstrate the general north to south migration of volcanism through time. It correlates with the main volcanic stages previously identified. The 2.75 Ma Basal Complex, the 1.81+-0.03 _ 1.15+-0.02 Ma Septentrional Chain, the 1.02+-0.02 Ma _ 0.606+-0.02 Ma Axial Chain, the 442+-6 _ 207+-28 ka Mateliane _ Sans Toucher Complex and the < 200 ka Complex of La Grande Decouverte, which outlines a relative continuity in the Basse Terre magmatism. Lavas are mainly basaltic andesites and andesites although a few basalt and dacite have also been dated. All of them are characterized by low MgO values (< 6 %), tholeiitic to calc-alkaline REE chondrite-normalized patterns and are of both low K and medium K affinity. Lavas display geochemical characteristics similar to that of the central islands of the Lesser Antilles arc. Within Basse Terre, geochemical characteristics are relatively constant through time, indicating no major change of volcanic processes during the whole subaerial activity. Finally the detailed chronological

Mammoth Mountain and its mafic periphery—A late Quaternary volcanic field in eastern California

USGS Publications Warehouse

Hildreth, Wes; Fierstein, Judith; Champion, Duane E.; Calvert, Andrew T.

2014-01-01

The trachydacite complex of Mammoth Mountain and an array of contemporaneous mafic volcanoes in its periphery together form a discrete late Pleistocene magmatic system that is thermally and compositionally independent of the adjacent subalkaline Long Valley system (California, USA). The Mammoth system first erupted ca. 230 ka, last erupted ca. 8 ka, and remains restless and potentially active. Magmas of the Mammoth system extruded through Mesozoic plutonic rocks of the Sierra Nevada batholith and extensive remnants of its prebatholith wall rocks. All of the many mafic and silicic vents of the Mammoth system are west or southwest of the structural boundary of Long Valley caldera; none is inboard of the caldera’s buried ring-fault zone, and only one Mammoth-related vent is within the zone. Mammoth Mountain has sometimes been called part of the Inyo volcanic chain, an ascription we regard inappropriate and misleading. The scattered vent array of the Mammoth system, 10 × 20 km wide, is unrelated to the range-front fault zone, and its broad nonlinear footprint ignores both Long Valley caldera and the younger Mono-Inyo range-front vent alignment. Moreover, the Mammoth Mountain dome complex (63%–71% SiO2; 8.0%–10.5% alkalies) ended its period of eruptive activity (100–50 ka) long before Holocene inception of Inyo volcanism. Here we describe 25 silicic eruptive units that built Mammoth Mountain and 37 peripheral units, which include 13 basalts, 15 mafic andesites, 6 andesites, and 3 dacites. Chemical data are appended for nearly 900 samples, as are paleomagnetic data for ∼150 sites drilled. The 40Ar/39Ar dates (230–16 ka) are given for most units, and all exposed units are younger than ca. 190 ka. Nearly all are mildly alkaline, in contrast to the voluminous subalkaline rhyolites of the contiguous long-lived Long Valley magma system. Glaciated remnants of Neogene mafic and trachydacitic lavas (9.1–2.6 Ma) are scattered near Mammoth Mountain, but Quaternary

Stratigraphic, Granulometric and Geochemical Studies of a Major Plinian Eruption on Dominica, Lesser Antilles

NASA Astrophysics Data System (ADS)

Smith, A. L.; Daly, G.; Killingsworth, N.; Deuerling, K.; Schneider, S.; Fryxell, J. E.

2008-12-01

composition and show essentially no variation up stratigraphy. In contrast, the surges are more variable in composition, ranging from andesite to dacite. Modeling of these data will provide information on the dynamics of this major Plinian eruption including the effects of water/magma interaction.

Analysis of terrestrial and Martian volcanic compositions using thermal emission spectroscopy

NASA Astrophysics Data System (ADS)

Wyatt, Michael Bruce

2002-11-01

This dissertation comprises four separate parts that address the Mars Global Surveyor (MGS) Thermal Emission Spectrometer (TES) investigation objective of determining and mapping the composition and distribution of surface minerals and rocks on Mars from orbit. In Part 1, laboratory thermal infrared spectra (5 25 μm, at 2 cm-1 spectral sampling), deconvolved modal mineralogies, and derived mineral and bulk rock chemistries of basalt, basaltic andesite, andesite, and dacite were used to evaluate and revise volcanic rock classification schemes. Multiple steps of classification were required to distinguish volcanic rocks, reflecting the mineralogic diversity and continuum of compositions that exists in volcanic rock types. In Part 2, laboratory spectral data were convolved to TES 10 cm-1 sampling to ascertain whether adequate results for volcanic rock classification can be obtained with lower spectral resolution, comparable to that obtained from Mars orbit. Modeled spectra, modeled modal mineralogies, and derived bulk rock chemistries at low (10 cm-1) spectral sampling provide good matches to measured and high (2 cm-1) spectral sampling modeled values. These results demonstrate the feasibility of using similar techniques and classification schemes for the interpretation of terrestrial laboratory samples and TES-resolution data. In Part 3, new deconvolved mineral abundances from TES data and terrestrial basalts using a spectral end-member set representing minerals common in unaltered and low-temperature aqueously altered basalts were used to reclassify martian surface lithologies. The new formulations maintain the dominance of unaltered basalt in the southern highlands, but indicate the northern lowlands can be interpreted as weathered basalt. The coincidence between locations of altered basalt and a previously suggested northern ocean basin implies that lowland plains materials may be basalts altered under submarine conditions and/or weathered basaltic sediment

The diffusion of water in haploanesite

NASA Astrophysics Data System (ADS)

Ni, H.; Zhang, Y.

2008-12-01

to dacite to andesite at >1300°C, and this sequence is reversed at <600°C.

Volcanology and eruptive styles of Barren Island: an active mafic stratovolcano in the Andaman Sea, NE Indian Ocean

NASA Astrophysics Data System (ADS)

Sheth, Hetu C.; Ray, Jyotiranjan S.; Bhutani, Rajneesh; Kumar, Alok; Smitha, R. S.

2009-11-01

Barren Island (India) is a relatively little studied, little known active volcano in the Andaman Sea, and the northernmost active volcano of the great Indonesian arc. The volcano is built of prehistoric (possibly late Pleistocene) lava flows (dominantly basalt and basaltic andesite, with minor andesite) intercalated with volcaniclastic deposits (tuff breccias, and ash beds deposited by pyroclastic falls and surges), which are exposed along a roughly circular caldera wall. There are indications of a complete phreatomagmatic tephra ring around the exposed base of the volcano. A polygenetic cinder cone has existed at the centre of the caldera and produced basalt-basaltic andesite aa and blocky aa lava flows, as well as tephra, during historic eruptions (1787-1832) and three recent eruptions (1991, 1994-95, 2005-06). The recent aa flows include a toothpaste aa flow, with tilted and overturned crustal slabs carried atop an aa core, as well as locally developed tumuli-like elliptical uplifts having corrugated crusts. Based on various evidence we infer that it belongs to either the 1991 or the 1994-95 eruptions. The volcano has recently (2008) begun yet another eruption, so far only of tephra. We make significantly different interpretations of several features of the volcano than previous workers. This study of the volcanology and eruptive styles of the Barren Island volcano lays the ground for detailed geochemical-isotopic and petrogenetic work, and provides clues to what the volcano can be expected to do in the future.

Crypto-magma chambers beneath Mt. Fuji

NASA Astrophysics Data System (ADS)

Kaneko, Takayuki; Yasuda, Atsushi; Fujii, Toshitsugu; Yoshimoto, Mitsuhiro

2010-06-01

Mt. Fuji consists dominantly of basalt. A study of olivine-hosted melt-inclusions from layers of air-fall scoria, however, shows clear evidence of andesitic liquids. Whole rock compositions show a narrow range of SiO 2, but a wide range of FeO*/MgO and incompatible elements. Phenocrystic plagioclase generally shows bi-modal distributions in compositional frequency, while most olivine phenocrysts show uni-modal distribution with reverse zoning and often contain andesitic melt-inclusions. These suggest that magmas erupted from Fuji are generated through mixing between basaltic and more SiO 2-rich (often andesitic) end-members. We propose that Fuji's magmatic plumbing system consists of at least two magma chambers: a relatively deep (˜20 km) basaltic one and a relatively shallow (˜ 8-9 km) and more SiO 2-rich one. Evolved basalts with wide compositional ranges of incompatible elements are generated in the deep basaltic magma chamber by prevalent fractional crystallization of pyroxenes with olivine and calcic plagioclase at high pressure. Meanwhile basaltic magma left behind by the previous eruption in the conduit accumulates in a shallow magma chamber, and is differentiated to more SiO 2-rich composition by fractional crystallization of olivine, less-calcic plagioclase, and clinopyroxene. Shortly before a new eruption, a large amount of evolved basaltic magma containing calcic plagioclase rises from the deeper magma chamber and is mixed with the more SiO 2-rich magma in the shallow chamber, to generate the hybrid basaltic magma.

Assimilation of granite by basaltic magma at Burnt Lava flow, Medicine Lake volcano, northern California: Decoupling of heat and mass transfer

USGS Publications Warehouse

Grove, T.L.; Kinzler, R.J.; Baker, M.B.; Donnelly-Nolan, J. M.; Lesher, C.E.

1988-01-01

At Medicine Lake volcano, California, andesite of the Holocene Burnt Lava flow has been produced by fractional crystallization of parental high alumina basalt (HAB) accompanied by assimilation of granitic crustal material. Burnt Lava contains inclusions of quenched HAB liquid, a potential parent magma of the andesite, highly melted granitic crustal xenoliths, and xenocryst assemblages which provide a record of the fractional crystallization and crustal assimilation process. Samples of granitic crustal material occur as xenoliths in other Holocene and Pleistocene lavas, and these xenoliths are used to constrain geochemical models of the assimilation process. A large amount of assimilation accompanied fractional crystallization to produce the contaminated Burnt lava andesites. Models which assume that assimilation and fractionation occurred simultaneously estimate the ratio of assimilation to fractional crystallization (R) to be >1 and best fits to all geochemical data are at an R value of 1.35 at F=0.68. Petrologic evidence, however, indicates that the assimilation process did not involve continuous addition of granitic crust as fractionation occurred. Instead, heat and mass transfer were separated in space and time. During the assimilation process, HAB magma underwent large amounts of fractional crystallization which was not accompanied by significant amounts of assimilation. This fractionation process supplied heat to melt granitic crust. The models proposed to explain the contamination process involve fractionation, replenishment by parental HAB, and mixing of evolved and parental magmas with melted granitic crust. ?? 1988 Springer-Verlag.

Compositional diversity of Late Cenozoic basalts in a transect across the southern Washington Cascades: Implications for subduction zone magmatism

NASA Astrophysics Data System (ADS)

Leeman, William P.; Smith, Diane R.; Hildreth, Wes; Palacz, Zen; Rogers, Nick

1990-11-01

Major volcanoes of the Southern Washington Cascades (SWC) include the large Quaternary stratovolcanoes of Mount St. Helens (MSH) and Mount Adams (MA) and the Indian Heaven (IH) and Simcoe Mountain (SIM) volcanic fields. There are significant differences among these volcanic centers in terms of their composition and evolutionary history. The stratovolcanoes consist largely of andesitic to dacitic lavas and pyroclastics with minor basalt flows. IH consists dominantly of basaltic with minor andesite lavas, all erupted from monogenetic rift and cinder cone vents. SIM has a poorly exposed andesite to rhyolite core but mainly consists of basaltic lavas erupted from numerous widely dispersed vents; it has the morphology of a shield volcano. Distribution of mafic lavas across the SWC is related to north-northwest trending faults and fissure zones that indicate a significant component of east-west extension within the area. There is overlap in eruptive history for the areas studied, but it appears that peak activity was progressively older (MSH (<40 Ka), IH (mostly <0.5 Ma), MA (<0.5 Ma), SIM (1-4 Ma)) and more alkalic toward the east. A variety of compositionally distinct mafic magma types has been identified in the SWC, including low large ion lithophile element (LILE) tholeiitic basalts, moderate LILE calcalkalic basalts, basalts transitional between these two, LILE-enriched mildly alkalic basalts, and basaltic andesites. Compositional diversity among basaltic lavas, both within individual centers as well as across the arc, is an important characteristic of the SWC traverse. The fact that the basaltic magmas either show no correlation between isotopic and trace element components or show trends quite distinct from those of the associated evolved lavas, suggests that their compositional variability is attributable to subcrustal processes. Both the primitive nature of the erupted basalts and the fact that they are relatively common in the SWC sector also imply that such

Hydrogeology of Basins on Mars

NASA Technical Reports Server (NTRS)

Arvidson, Raymond E.

2001-01-01

This document summarizes the work accomplished under NASA Grant NAG5-3870. Emphasis was put on the development of the FIDO rover, a prototype for the twin-Mers which will be operating on the surface of Mars in 2004, specifically the primary work was the analysis of FIDO field trials. The grantees also analyzed VIKING Lander 1 XRFS and Pathfinder APXS data. Results show that the Viking site chemistry is consistent with an andesite, and the Pathfinder site is consistent with a basaltic andesite. The grantees also worked to demonstrate the capability to simulate annealing methods to apply to the inversion of remote sensing data. They performed an initial analyses of Sojourner engineering telemetry and imaging data. They performed initial analyses of Viking Lander Stereo Images, and of Hematite deposits in Terra Meridiani. They also acquired and analyzed the New Goldstone radar data.

Isotopic geochemistry of Panama rivers

USGS Publications Warehouse

Harmon, Russell S.; Worner, Gerhard; Pribil, Michael; Kern, Zoltan; Forizs, Istvan; Lyons, W. Berry; Gardner, Christopher B.; Goldsmith, Steven T.

2015-01-01

River water samples collected from 78 watersheds rivers along a 500-km transect across a Late Cretaceous-Tertiary andesitic volcanic arc terrane in west-central Panama provide a synoptic overview of riverine geochemistry, chemical denudation, and CO2 consumption in the tropics. D/H and 18O/16O relationships indicate that bedrock dissolution of andesitic arc crust in Panama is driven by water-rock interaction with meteoric precipitation as it passes through the critical zone, with no evidence of a geothermal or hydrothermal input. Sr-isotope relationships suggest a geochemical evolution for Panama riverine waters that involves mixing of bedrock pore water with water having 87Sr/86Sr ratios between 0.7037-0.7043 and relatively high Sr-contents with waters of low Sr content that enriched in radiogenic Sr that are diluted by infiltrating rainfall to variable extents.

Geologic map of the Harvard Lakes 7.5' quadrangle, Park and Chaffee Counties, Colorado

USGS Publications Warehouse

Kellogg, Karl S.; Lee, Keenan; Premo, Wayne R.; Cosca, Michael A.

2013-01-01

The Harvard Lakes 1:24,000-scale quadrangle spans the Arkansas River Valley in central Colorado, and includes the foothills of the Sawatch Range on the west and Mosquito Range on the east. The Arkansas River valley lies in the northern end of the Rio Grande rift and is structurally controlled by Oligocene and younger normal faults mostly along the west side of the valley. Five separate pediment surfaces were mapped, and distinctions were made between terraces formed by the Arkansas River and surfaces that formed from erosion and alluviation that emanated from the Sawatch Range. Three flood deposits containing boulders as long as 15 m were deposited from glacial breakouts just north of the quadrangle. Miocene and Pliocene basin-fill deposits of the Dry Union Formation are exposed beneath terrace or pediment deposits in several places. The southwestern part of the late Eocene Buffalo Peaks volcanic center, mostly andesitic breccias and flows and ash-flow tuffs, occupy the northeastern corner of the map. Dated Tertiary intrusive rocks include Late Cretaceous or early Paleocene hornblende gabbro and hornblende monzonite. Numerous rhyolite and dacite dikes of inferred early Tertiary or Late Cretaceous age also intrude the basement rocks. Basement rocks are predominantly Mesoproterozoic granites, and subordinately Paleoproterozoic biotite gneiss and granitic gneiss.

Petrography of impact glasses and melt breccias from the El'gygytgyn impact structure, Russia

NASA Astrophysics Data System (ADS)

Pittarello, Lidia; Koeberl, Christian

2013-07-01

The El'gygytgyn impact structure, 18 km in diameter and 3.6 Ma old, in Arctic Siberia, Russia, is the only impact structure on Earth mostly excavated in acidic volcanic rocks. The Late Cretaceous volcanic target includes lavas, tuffs, and ignimbrites of rhyolitic, dacitic, and andesitic composition, and local occurrence of basalt. Although the ejecta blanket around the crater is nearly completely eroded, bomb-shaped impact glasses, redeposited after the impact event, occur in lacustrine terraces within the crater. Here we present detailed petrographic descriptions of newly collected impact glass-bearing samples. The observed features contribute to constrain the formation of the melt and its cooling history within the framework of the impact process. The collected samples can be grouped into two types, characterized by specific features: (1) "pure" glasses, containing very few clasts or new crystals and which were likely formed during the early stages of cratering and (2) a second type, which represents composite samples with impact melt breccia lenses embedded in silicate glass. These mixed samples probably resulted from inclusion of unmelted impact debris during ejection and deposition. After deposition the glassy portions continued to deform, whereas the impact melt breccia inclusions that probably had already cooled down behaved as rigid bodies in the flow.

Decoding magma plumbing and geochemical evolution beneath the Lastarria volcanic complex (Northern Chile)-Evidence for multiple magma storage regions

NASA Astrophysics Data System (ADS)

Stechern, André; Just, Tobias; Holtz, François; Blume-Oeste, Magdalena; Namur, Olivier

2017-05-01

The petrology of quaternary andesites and dacites from Lastarria volcano was investigated to reconstruct the magma plumbing and storage conditions beneath the volcano. The mineral phase compositions and whole-rock major and trace element compositions were used to constrain temperature, pressure and possible mechanisms for magma differentiation. The applied thermobarometric models include two-pyroxene thermobarometry, plagioclase-melt thermometry, amphibole composition thermobarometry, and Fe-Ti oxide thermo-oxybarometry. The overall temperature estimation is in the range 840 °C to 1060 °C. Calculated oxygen fugacity ranges between NNO to NNO + 1. Results of the geo-barometric calculations reveal multiple magma storage regions, with a distinct storage level in the uppermost crust ( 6.5-8 km depth), a broad zone at mid-crustal levels ( 10-18 km depth), and a likely deeper zone at intermediate to lower crustal levels (> 20 km depth). The highest temperatures in the range 940-1040 °C are recorded in minerals stored in the mid-crustal levels ( 10-18 km depth). The whole-rock compositions clearly indicate that magma mixing is the main parameter controlling the general differentiation trends. Complex zoning patterns and textures in the plagioclase phenocrysts confirm reheating and remobilization processes due to magma replenishment.

The Ordovician magmatic arc in the northern Chile-Argentina Andes between 21° and 26° south latitude

NASA Astrophysics Data System (ADS)

Niemeyer, Hans; Götze, Jens; Sanhueza, Marcos; Portilla, Carolina

2018-01-01

A continental magmatic arc (the Famatinian magmatic arc) was developed on the western margin of Gondwana during the Early to Middle Ordovician. This has a northwestern orientation in the northern Chile-Argentina Andes between 21° and 26° south latitude with a northeastern directed subduction zone and developed on a continental crust represented by a metamorphic basement. A paleogeographical scheme for the Ordovician magmatic arc is proposed and two tectonic environments can be recognized from our own data and data from the literature: forearc and arc. The Cordón de Lila Complex can be assigned to a forearc position. Here the turbiditic flows become paralell to the northwestern elongation of the magmatic arc. The sedimentation in the frontal-arc high platform of the forearc is represented by stromatolitic limestones and a zone of phosphate production. The internal structure of the arc can be inferred from the petrographic composition of the turbidites: basaltic and andesitic lavas, dacitic and/or rhyolitic lavas and ash fall tuffs. Also the Quebrada Grande Formation was developed on the forearc. Plutonic Ordovician rocks testify the continuity of the magmatic arc. The data about the basement exposed in the present paper do not support the existence of the Arequipa-Antofalla Terrane.

Eruptive Style and Geochronology of the Initial Fases of Monogenetic Vulcanism of Southern Basis of Mexico

NASA Astrophysics Data System (ADS)

Jaimes, M. D.; Martin, A.; Layer, P. W.

2013-05-01

Monogenetic vulcanism in the central part of Mexico includes the Chichinautzin Monogenetic Volcanic Field, located at the front of the Transmexican Volcanic Belt (TMVB), 300 km from the Mesoamerican trench. At least 220 volcanoes formed during the Pleistocene and Holocene. Most are scoria cones with associated lava flows, small shield volcanoes and lava domes; and cover an área of 2400 km2 (Martin Del Pozzo, 1982; Wallace and Carmichael, 1999; Velasco-Tapia and Verma, 2001; Velasco-Tapia, 2003). Previous studies in the area (paleomagnetic, geomorphologic, vulcanologic and radiometric) indicate that volcanism is less than 0.79 Ma (Bloomfield, 1973; Mooser et al., 1974; Herrero and Pal, 1978; Martin Del Pozzo et al., 1997; Siebe et al., 2004a). Our field studies include mapping and sampling of 50 lava flows associated with scoria cones, phreatomagmatic structures (2), lava flows without cones (2) and lava domes (5). Geomorphologic analyses, whole rock chemical analyse (FRX), petrographic and geochronologic (Ar-Ar) were carried out. We identified three zones with different eruptive styles: strombolian and violent strombolian to the north and south; and phreatomagmatic style only in the north. Samples are basaltic andesites to dacites. Geochronologic data is consistent with some of the relative ages according to the geomorphologic data and corresponds to three age groups.

An overview of the 2009 eruption of Redoubt Volcano, Alaska

NASA Astrophysics Data System (ADS)

Bull, Katharine F.; Buurman, Helena

2013-06-01

In March 2009, Redoubt Volcano, Alaska erupted for the first time since 1990. Explosions ejected plumes that disrupted international and domestic airspace, sent lahars more than 35 km down the Drift River to the coast, and resulted in tephra fall on communities over 100 km away. Geodetic data suggest that magma began to ascend slowly from deep in the crust and reached mid- to shallow-crustal levels as early as May, 2008. Heat flux at the volcano during the precursory phase melted ~ 4% of the Drift glacier atop Redoubt's summit. Petrologic data indicate the deeply sourced magma, low-silica andesite, temporarily arrested at 9-11 km and/or at 4-6 km depth, where it encountered and mixed with segregated stored high-silica andesite bodies. The two magma compositions mixed to form intermediate-silica andesite, and all three magma types erupted during the earliest 2009 events. Only intermediate- and high-silica andesites were produced throughout the explosive and effusive phases of the eruption. The explosive phase began with a phreatic explosion followed by a seismic swarm, which signaled the start of lava effusion on March 22, shortly prior to the first magmatic explosion early on March 23, 2009 (UTC). More than 19 explosions (or “Events”) were produced over 13 days from a single vent immediately south of the 1989-90 lava domes. During that period multiple small pyroclastic density currents flowed primarily to the north and into glacial ravines, three major lahars flooded the Drift River Terminal over 35 km down-river on the coast, tephra fall deposited on all aspects of the edifice and on several communities north and east of the volcano, and at least two, and possibly three lava domes were emplaced. Lightning accompanied almost all the explosions. A shift in the eruptive character took place following Event 9 on March 27 in terms of infrasound signal onsets, the character of repeating earthquakes, and the nature of tephra ejecta. More than nine additional

Compositions of Low Albedo Intracrater Materials and Wind Streaks on Mars: Examination of MGS TES Data in Western Arabia Terra

NASA Technical Reports Server (NTRS)

Bandfield, J. L.; Wyatt, M. B.; Christensen, P.; McSween, H. Y., Jr.

2001-01-01

Basalt and andesite surface compositions are identified within individual low albedo intracrater features and adjacent dark wind streaks. High resolution mapping of compositional heterogeneities may help constrain origin hypotheses for these features. Additional information is contained in the original extended abstract.

History of Red Crater volcano, Tongariro Volcanic Centre (New Zealand): Abrupt shift in magmatism following recharge and contrasting evolution between neighboring volcanoes

NASA Astrophysics Data System (ADS)

Shane, Phil; Maas, Roland; Lindsay, Jan

2017-06-01

Red Crater volcano is one of several contemporaneously active vents on the Tongariro Volcanic Centre. Its history provides an opportunity to investigate the contrasting magmatic evolutionary paths of closely-spaced volcanoes. Rocks erupted at Red Crater over the last 3.4 ka display typical subduction-related trace element and isotopic signatures. Those erupted pre-1.8 ka are medium-K andesites (SiO2 59-62 wt%). They represent the most voluminous magmas and were emplaced in 5 lava flow events. An abrupt shift to the eruption of basaltic andesite (SiO2 53-54 wt%) with less radiogenic Sr-Nd-Pb isotope ratios, occurred post-1.8 ka. This period comprised 6 smaller volume, lava flow episodes and the contemporaneous development of a scoria cone. Plagioclase phenocrysts in post-1.8 ka lava flows have resorbed cores with diverse textural and compositional growth patterns, as would be expected from the disruption of a crystal mush. They are similar to phenocrysts of the pre-1.8 ka lava flows. The post-1.8 ka plagioclase is distinguished from those in the older lavas by overgrowths with elevated An ( 70-90), FeO and MgO contents, that mantle the resorbed cores ( An50-70). These rims are compositionally similar to groundmass plagioclase. This demonstrates that new mafic magma was intruded into the system, mixing with and entraining relic crystals from the older andesite system. Iron and Mg zoning patterns in the crystals are not consistent with significant re-equilibration via diffusion. Hence, the generation of eruptible magma during the last 1.8 ka required repeated mafic intrusion events. The emptying of the older andesitic magma reservoir early in the volcano's history removed buoyancy barriers to the direct eruption of more mafic magmas. This pattern of magmatism is not recorded at the contemporaneously active Ngauruhoe volcano, just 3 km to the SSW. Ngauruhoe rocks are compositionally distinct and are more heterogeneous in isotopic composition. Although mafic recharge is

Late Paleozoic tectonic evolution of the Central Asian Orogenic Belt: Constraints from multiple arc-basin systems in Altai-Junggar area, NW China

NASA Astrophysics Data System (ADS)

Li, D.

2015-12-01

In this study, we report results from integrated geological, geophysical and geochemical investigations on the Wulungu Depression of the Junggar Basin to understand the Late Paleozoic continental growth of the Junggar area and its amalgamation history with the Altai terrane, within the broad tectonic evolution of the Altai-Junggar area. Based on seismic and borehole data, the Wulungu Depression can be divided into two NW-trending tectonic units by southward thrust faults. The Suosuoquan Sag is composed of gray basaltic andesite, andesite, tuff, tuffaceous sandstone and tuffite, and the overlying Early Carboniferous volcano-sedimentary sequence with lava gushes and marine sediments from a proximal juvenile provenance, compared to the andesite in the Hongyan High. The SIMS Zircon U-Pb ages for andesites from Late Paleozoic strata indicate that these volcanics in Suosuoquan Sag and Hongyan High erupted at 376.3Ma and 313.4Ma, respectively. Most of the intermediate-mafic volcanic rocks exhibit calc-alkaline affinity, low initial 87Sr/86Sr and positive ɛNd(t) and ɛHf(t) values. Furthermore, these rocks have high Th/Yb and low Ce/Pb and La/Yb ratios as well as variable Ba/Th and Ba/La ratios. These features imply that the rocks were derived from partial melting of a mantle wedge metasomatized by subduction-related components in an island arc setting. The basin filling pattern and the distribution of island arc-type volcanics and their zircon Hf model ages with the eruptive time suggest that the Wulungu Depression represents an island arc-basin system with the development of a Carboniferous retro-arc basin. The gravity and magnetic anomaly data suggest that Altai-Junggar area incorporates three arc-basin belts from north to south: the Karamaili-Luliang-Darbut, Yemaquan-Wulungu, and Dulate-Fuhai-Saur. The recognition of the Wulungu arc-basin system demonstrates that the northern Junggar area is built by amalgamation of multiple Paleozoic linear arcs and accretionary

The influence of regional extensional tectonic stress on the eruptive behaviour of subduction-zone volcanoes

NASA Astrophysics Data System (ADS)

Tost, M.; Cronin, S. J.

2015-12-01

Regional tectonic stress is considered a trigger mechanism for explosive volcanic activity, but the related mechanisms at depth are not well understood. The unique geological setting of Ruapehu, New Zealand, allows investigation on the effect of enhanced regional extensional crustal tension on the eruptive behaviour of subduction-zone volcanoes. The composite cone is located at the southwestern terminus of the Taupo Volcanic Zone, one of the most active silicic magma systems on Earth, which extends through the central part of New Zealand's North Island. Rhyolitic caldera eruptions are limited to its central part where crustal extension is highest, whereas lower extension and additional dextral shear dominate in the southwestern and northeastern segments characterized by andesitic volcanism. South of Ruapehu, the intra-arc rift zone traverses into a compressional geological setting with updoming marine sequences dissected by reverse and normal faults. The current eruptive behaviour of Ruapehu is dominated by small-scaled vulcanian eruptions, but our studies indicate that subplinian to plinian eruptions have frequently occurred since ≥340 ka and were usually preceded by major rhyolitic caldera unrest in the Taupo Volcanic Zone. Pre-existing structures related to the NNW-SSE trending subduction-zone setting are thought to extend at depth and create preferred pathways for the silicic magma bodies, which may facilitate the development of large (>100 km3) dyke-like upper-crustal storage systems prior to major caldera activity. This may cause enhanced extensional stress throughout the entire intra-arc setting, including the Ruapehu area. During periods of caldera dormancy, the thick crust underlying the volcano and the enhanced dextral share rate likely impede ascent of larger andesitic magma bodies, and storage of andesitic melts dominantly occurs within small-scaled magma bodies at middle- to lower-crustal levels. During episodes of major caldera unrest, ascent and

Wastewater Phosphorus Removal by Two Different Types of Andesitic Volcanic Tephra

ERIC Educational Resources Information Center

Liesch, Amanda M.

2010-01-01

Phosphorus (P) is the limiting nutrient controlling productivity in most inland freshwater systems. Several materials have been proposed for use to remove excess P from wastewater treatment, including volcanic lapilli and ash (tephra). There is limited data in using tephra as a P filter. There were two objectives of this study: (1) to determine…

Biogeochemistry of hydrothermally and adjacent non-altered soils

USDA-ARS?s Scientific Manuscript database

As a field/lab project, students in the Soil Biogeochemistry class of the University of Nevada, Reno described and characterized seven pedons, developed in hydrothermally and adjacent non-hydrothermally altered andesitic parent material near Reno, NV. Hydrothermally altered soils had considerably lo...

Soil-plant-microbial relations in hydrothermally altered soils of Northern California

USDA-ARS?s Scientific Manuscript database

Soils developed on relict hydrothermally altered soils throughout the Western United States present unique opportunities to study the role of geology on above and belowground biotic activity and composition. Soil and vegetation samples were taken at three unaltered andesite and three hydrothermally ...

Specific mineral associations of hydrothermal shale (South Kamchatka)

NASA Astrophysics Data System (ADS)

Rychagov, S. N.; Sergeeva, A. V.; Chernov, M. S.

2017-11-01

The sequence of hydrothermal shale from the East Pauzhet thermal field within the Pauzhet hydrothermal system (South Kamchatka) was studied in detail. It was established that the formation of shale resulted from argillization of an andesitic lava flow under the influence of an acidic sulfate vapor condensate. The horizons with radically different compositions and physical properties compared to those of the overlying homogeneous plastic shale were distinguished at the base of the sequence. These horizons are characterized by high (up to two orders of magnitude in comparison with average values in hydrothermal shale) concentrations of F, P, Na, Mg, K, Ca, Sc, Ti, V, Cr, Cu, and Zn. We suggested a geological-geochemical model, according to which a deep metal-bearing chloride-hydrocarbonate solution infiltrated into the permeable zone formed at the root of the andesitic lava flow beneath plastic shale at a certain stage of evolution of the hydrothermal system.

Melt Inclusion Evidence for Subduction-modified Mantle Beneath the Woodlark Spreading Center, Solomon Islands

NASA Astrophysics Data System (ADS)

Chadwick, J.; Turner, A.; Collins, E.

2015-12-01

The Woodlark Spreading Center (WSC) to the east of Papua New Guinea separates the Indo-Australian plate and Solomon Sea microplate. At its eastern terminus, the WSC is being subducted at the New Britain trench, forming a triple junction near the New Georgia Group arc in the Solomon Islands. Previous studies have shown that lavas recovered from greater than 100 km from the trench on the WSC are N-MORB, but closer to the trench they have arc-like Sr-Nd-Pb isotopic ratios, enrichments in LILE, and depletions in HFSE. In the complex triple junction area of the WSC on the Simbo and Ghizo Ridges, island arc tholeiites to medium-K calc-alkaline andesites and dacites have been recovered, many with trace element and isotopic characteristics that are similar to the true arc lavas in the New Georgia Group on the other side of the trench. We suggest that subduction-modified arc mantle migrates through slab windows created by the subduction of the WSC as the plates continue to diverge after subduction. This transfer of mantle across the plate boundary leads to variable mixing between arc and N-MORB end-members, forming the hybrid to arc-like lavas recovered on the WSC. To test this hypothesis and to characterize the end-member compositions, we have analyzed melt inclusions in olivine, pyroxene, and plagioclase phenocrysts in Simbo and Ghizo Ridge lava samples. Major elements were analyzed using the electron microprobe facility at Fayetteville State University and volatiles were analyzed on the ion probe facility at Woods Hole Oceanographic Institution. The melt inclusions show a wide diversity of magmas from basalts to dacites, and mixing modeling shows that most Woodlark Spreading Center lava compositions are explained by mixing between the most extreme mafic (MORB) and felsic (arc) inclusion compositions.

Age constraints on the hydrothermal history of the Prominent Hill iron oxide copper-gold deposit, South Australia

NASA Astrophysics Data System (ADS)

Bowden, Bryan; Fraser, Geoff; Davidson, Garry J.; Meffre, Sebastien; Skirrow, Roger; Bull, Stuart; Thompson, Jay

2017-08-01

The Mesoproterozoic Prominent Hill iron-oxide copper-gold deposit lies on the fault-bound southern edge of the Mt Woods Domain, Gawler Craton, South Australia. Chalcocite-bornite-chalcopyrite ores occur in a hematitic breccia complex that has similarities to the Olympic Dam deposit, but were emplaced in a shallow water clastic-carbonate package overlying a thick andesite-dacite pile. The sequence has been overturned against the major, steep, east-west, Hangingwall Fault, beyond which lies the clastic to potentially evaporitic Blue Duck Metasediments. Immediately north of the deposit, these metasediments have been intruded by dacite porphyry and granitoid and metasomatised to form magnetite-calc-silicate skarn ± pyrite-chalcopyrite. The hematitic breccia complex is strongly sericitised and silicified, has a large sericite ± chlorite halo, and was intruded by dykes during and after sericitisation. This paper evaluates the age of sericite formation in the mineralised breccias and provides constraints on the timing of granitoid intrusion and skarn formation in the terrain adjoining the mineralisation. The breccia complex contains fragments of granitoid and porphyry that are found here to be part of the Gawler Range Volcanics/Hiltaba Suite magmatic event at 1600-1570 Ma. This indicates that some breccia formation post-dated granitoid intrusion. Monazite and apatite in Fe-P-REE-albite metasomatised granitoid, paragenetically linked with magnetite skarn formation north of the Hangingwall Fault, grew soon after granitoid intrusion, although the apatite experienced U-Pb-LREE loss during later fluid-mineral interaction; this accounts for its calculated age of 1544 ± 39 Ma. To the south of the fault, within the breccia, 40Ar-39Ar ages yield a minimum age of sericitisation (+Cu+Fe+REE) of dykes and volcanics of ˜1575 Ma, firmly placing Prominent Hill ore formation as part of the Gawler Range Volcanics/Hiltaba Suite magmatic event within the Olympic Cu-Au province of the

Prototype PBO Instrumentation of CALIPSO Project Captures World-Record Lava Dome Collapse on Montserrat Volcano

NASA Astrophysics Data System (ADS)

Mattioli, Glen S.; Young, Simon R.; Voight, Barry; Sparks, R. Steven J.; Shalev, Eylon; Selwyn, Sacks; Malin, Peter; Linde, Alan; Johnston, William; Hadayat, Dannie; Elsworth, Derek; Dunkley, Peter; Herd, Richard; Neuberg, Jurgen; Norton, Gillian; Widiwijayanti, Christina

2004-08-01

This article is an update on the status of an innovative new project designed to enhance generally our understanding of andesitic volcano eruption dynamics and, specifically, the monitoring and scientific infrastructure at the active Soufriàre Hills Volcano (SHV), Montserrat. The project has been designated as the Caribbean Andesite Lava Island Precision Seismo-geodetic Observatory, known as CALIPSO. Its purpose is to investigate the dynamics of the entire SHV magmatic system using an integrated array of specialized instruments in four strategically located ~200-m-deep boreholes in concert with several shallower holes and surface sites. The project is unique, as it represents the first, and only, such borehole volcano-monitoring array deployed at an andesitic stratovolcano. CALIPSO may be considered as a prototype for planned Plate Boundary Observatory (PBO) installations at several volcanic targets in the western United States. Scientific objectives of the EarthScope Integrated Science Plan (ES-ISP) relevant to magmatic systems are to investigate (1) melt generation in the mantle; (2) melt migration from the mantle to and through the crust to the surface; (3) melt residence times at various deep reservoirs; and (4) delineation of characteristic patterns of surface deformation and seismicity, which may prove useful in eruption forecasting. The CALIPSO project shares most of the same scientific goals and has, moreover, the benefit of a rich existing geophysical context in its deployment at SHV. Our experience during instrument design, planning, drilling and installation, systems integration, and early operation of CALIPSO, moreover, may prove valuable to EarthScope and PBO managers.

Modeling Magma Mixing: Evidence from U-series age dating and Numerical Simulations

NASA Astrophysics Data System (ADS)

Philipp, R.; Cooper, K. M.; Bergantz, G. W.

2007-12-01

Magma mixing and recharge is an ubiquitous process in the shallow crust, which can trigger eruption and cause magma hybridization. Phenocrysts in mixed magmas are recorders for magma mixing and can be studied by in- situ techniques and analyses of bulk mineral separates. To better understand if micro-textural and compositional information reflects local or reservoir-scale events, a physical model for gathering and dispersal of crystals is necessary. We present the results of a combined geochemical and fluid dynamical study of magma mixing processes at Volcan Quizapu, Chile; two large (1846/47 AD and 1932 AD) dacitic eruptions from the same vent area were triggered by andesitic recharge magma and show various degrees of magma mixing. Employing a multiphase numerical fluid dynamic model, we simulated a simple mixing process of vesiculated mafic magma intruded into a crystal-bearing silicic reservoir. This unstable condition leads to overturn and mixing. In a second step we use the velocity field obtained to calculate the flow path of 5000 crystals randomly distributed over the entire system. Those particles mimic the phenocryst response to the convective motion. There is little local relative motion between silicate liquid and crystals due to the high viscosity of the melts and the rapid overturn rate of the system. Of special interest is the crystal dispersal and gathering, which is quantified by comparing the distance at the beginning and end of the simulation for all particle pairs that are initially closer than a length scale chosen between 1 and 10 m. At the start of the simulation, both the resident and new intruding (mafic) magmas have a unique particle population. Depending on the Reynolds number (Re) and the chosen characteristic length scale of different phenocryst-pairs, we statistically describe the heterogeneity of crystal populations on the thin section scale. For large Re (approx. 25) and a short characteristic length scale of particle

Late Holocene volcanism at Medicine Lake Volcano, northern California Cascades

USGS Publications Warehouse

Donnelly-Nolan, Julie M.; Champion, Duane E.; Grove, Timothy L.

2016-05-23

Late Holocene volcanism at Medicine Lake volcano in the southern Cascades arc exhibited widespread and compositionally diverse magmatism ranging from basalt to rhyolite. Nine well-characterized eruptions have taken place at this very large rear-arc volcano since 5,200 years ago, an eruptive frequency greater than nearly all other Cascade volcanoes. The lavas are widely distributed, scattered over an area of ~300 km2 across the >2,000-km2 volcano. The eruptions are radiocarbon dated and the ages are also constrained by paleomagnetic data that provide strong evidence that the volcanic activity occurred in three distinct episodes at ~1 ka, ~3 ka, and ~5 ka. The ~1-ka final episode produced a variety of compositions including west- and north-flank mafic flows interspersed in time with fissure rhyolites erupted tangential to the volcano’s central caldera, including the youngest and most spectacular lava flow at the volcano, the ~950-yr-old compositionally zoned Glass Mountain flow. At ~3 ka, a north-flank basalt eruption was followed by an andesite eruption 27 km farther south that contains quenched basalt inclusions. The ~5-ka episode produced two caldera-focused dacitic eruptions. Quenched magmatic inclusions record evidence of intrusions that did not independently reach the surface. The inclusions are present in five andesitic, dacitic, and rhyolitic host lavas, and were erupted in each of the three episodes. Compositional and mineralogic evidence from mafic lavas and inclusions indicate that both tholeiitic (dry) and calcalkaline (wet) parental magmas were present. Petrologic evidence records the operation of complex, multi-stage processes including fractional crystallization, crustal assimilation, and magma mixing. Experimental evidence suggests that magmas were stored at 3 to 6 km depth prior to eruption, and that both wet and dry parental magmas were involved in generating the more silicic magmas. The broad distribution of eruptive events and the relative

TES Observations of Chryse and Acidalia Planitiae: Multiple Working Hypotheses for Distributions of Surface Compositions

NASA Technical Reports Server (NTRS)

Wyatt, M. B.; Bandfield, J. L.; McSween, H. Y., Jr.; Christensen, P. R.; Moersch, J.

2002-01-01

A gradation of surface units represents either (1) an influx of basaltic sediment from southern highlands, deposited on andesitic volcanics, or (2) incompletely weathered basalt marking the geographic extent of submarine alteration of basaltic crust. Additional information is contained in the original extended abstract.

Stratigraphy, geochemistry and tectonic significance of the Oligocene magmatic rocks of western Oaxaca, southern Mexico

USGS Publications Warehouse

Martiny, B.; Martinez-Serrano, R. G.; Moran-Zenteno, D. J.; MacIas-Romo, C.; Ayuso, R.A.

2000-01-01

In Western Oaxaca, Tertiary magmatic activity is represented by extensive plutons along the continental margin and volcanic sequences in the inland region. K-Ar age determinations reported previously and in the present work indicate that these rocks correspond to a relatively broad arc in this region that was active mainly during the Oligocene (~ 35 to ~ 25 Ma). In the northern sector of western Oaxaca (Huajuapan-Monte Verde-Yanhuitlan), the volcanic suite comprises principally basaltic andesite to andesitic lavas, overlying minor silicic to intermediate volcaniclastic rocks (epiclastic deposits, ash fall tuffs, ignimbrites) that were deposited in the lacustrine-fluvial environment. The southern sector of the volcanic zone includes the Tlaxiaco-Laguna de Guadalupe region and consists of intermediate to silicic pyroclastic and epiclastic deposits, with silicic ash fall tuffs and ignimbrites. In both sectors, numerous andesitic to dacitic hypabyssal intrusions (stocks and dikes) were emplaced at different levels of the sequence. The granitoids of the coastal plutonic belt are generally more differentiated than the volcanic rocks that predominate in the northern sector and vary in composition from granite to granodiorite. The studied rocks show large-ion lithophile element (LILE) enrichment (K, Rb, Ba, Th) relative to high-field-strength (HFS) elements (Nb, Ti, Zr) that is characteristic of subduction-related magmatic rocks. On chondrite-normalized rare earth element diagrams, these samples display light rare earth element enrichment (LREE) and a flat pattern for the heavy rare earth elements (HREE). In spite of the contrasting degree of differentiation between the coastal plutons and inland volcanic rocks, there is a relatively small variation in the isotopic composition of these two suites. Initial 87Sr/86Sr ratios obtained and reported previously for Tertiary plutonic rocks of western Oaxaca range from 0.7042 to 0.7054 and ??Nd values, from -3.0 to +2.4, and for

Glacial alteration of volcanic terrains: A chemical investigation of the Three Sisters, Oregon, USA.

NASA Astrophysics Data System (ADS)

Rutledge, Alicia; Horgan, Briony; Havig, Jeff

2017-04-01

Glacial silica cycling is more efficient than previously reported, and in some settings, particularly glaciated mafic volcanics, can be the dominant weathering process. Based on field work at glaciated volcanic sites, we hypothesize that this is due to a combination of high rates of silica dissolution from mafic bedrock and reprecipitation of silica in the form of opaline silica coatings and other poorly crystalline silicate alteration phases. The high rate of bedrock comminution in subglacial environments results in high rates of both chemical and physical weathering, due to the increased reactive mineral surface area formed through glacial grinding. In most bedrock types, carbonate weathering is enhanced and silica fluxes are depressed in glacial outwash compared with global average riverine catchment runoff due to low temperatures and short residence times. However, in mafic systems, higher dissolved SiO2 concentrations have been observed. The major difference between observed glacial alteration of volcanic bedrock and more typical continental terrains is the absence of significant dissolved carbonate in the former. In the absence of carbonate minerals which normally dominate dissolution processes at glacier beds, carbonation of feldspar can become the dominant weathering process, which can result in a high proportion of dissolved silica fluxes in glacial outwash waters compared to the total cation flux. Mafic volcanic rocks are particularly susceptible to silica mobility, due to the high concentration of soluble minerals (i.e. plagioclase) as compared to the high concentration of insoluble quartz found in felsic rocks. To investigate melt-driven chemical weathering of mafic volcanics, water and rock samples were collected during July 2016 from glaciated volcanic bedrock in the Three Sisters Wilderness, Oregon, U.S.A. (44°9'N, 121°46'W): Collier Glacier (basaltic andesite, andesite), Hayden Glacier (andesite, dacite), and Diller Glacier (basalt). Here we

Late Cenozoic Samtskhe-Javakheti Volcanic Highland, Georgia:The Result of Mantle Plumes Activity

NASA Astrophysics Data System (ADS)

Okrostsvaridze, Avtandil

2017-04-01

Late Cenozoic Samtskhe-Javakheti continental volcanic highland (1500-2500 m a.s.l) is located in the SW part of the Lesser Caucasus. In Georgia the highland occupies more than 4500 km2, however its large part spreads towards the South over the territories of Turkey and Armenia. One can point out three stages of magmatic activity in this volcanic highland: 1. Early Pliocene activity (5.2-2.8 Ma; zircons U-Pb age) - when a large part of the highland was built up. It is formed from volcanic lava-breccias of andesite-dacitic composition, pyroclastic rocks and andesite-basalt lava flow. The evidences of this structure are: a large volume of volcanic material (>1500 km3); big thickness (700-1100 m in average), large-scale of lava flows (length 35 km, width 2.5-3.5 km, thickness 30-80 m), big thickness of volcanic ash horizons (300 cm at some places) and big size of volcanic breccias (diameter >1 m). Based on this data we assume that a source of this structure was a supervolcano (Okrostsvaridze et al., 2016); 2. Early Pleistocene activity (2.4 -1.6 Ma; zircons U-Pb age) - when continental flood basalts of 100-300 m thickness were formed. The flow is fully crystalline, coarse-grained, which mainly consist of olivine and basic labradorite. There 143Nd/144Nd parameter varies in the range of +0.41703 - +0.52304, and 87Sr/88Sr - from 0.7034 to 0.7039; 3. Late Pleistocene activity (0.35-0.021 Ma; zircons U-Pb age) - when intraplate Abul-Samsari linear volcanic ridge of andesite composition was formed stretching to the S-N direction for 40 km with the 8-12 km width and contains more than 20 volcanic edifices. To the South of the Abul-Samsari ridge the oldest (0.35-0.30 Ma; zircons U-Pb age) volcano Didi Abuli (3305 m a.s.l.) is located. To the North ages of volcano edifices gradually increase. Farther North the youngest volcano Tavkvetili (0.021-0. 030 Ma) is located (2583 m a.s.l.). One can see from this description that the Abul-Samsari ridge has all signs characterizing

Petrology of the Rainy Lake area, Minnesota, USA-implications for petrotectonic setting of the archean southern Wabigoon subprovince of the Canadian Shield

NASA Astrophysics Data System (ADS)

Day, Warren C.

1990-08-01

The Rainy Lake area in northern Minnesota and southwestern, Ontario is a Late Archean (2.7 Ga) granite-greenstone belt within the Wabigoon subprovince of the Canadian Shield. In Minnesota the rocks include mafic and felsic volcanic rocks, volcaniclastic, chemical sedimentary rocks, and graywacke that are intrucded by coeval gabbro, tonalite, and granodiorite. New data presented here focus on the geochemistry and petrology of the Minnesota part of the Rainy Lake area. Igneous rocks in the area are bimodal. The mafic rocks are made up of three distinct suites: (1) low-TiO2 tholeiite and gabbro that have slightly evolved Mg-numbers (63 49) and relatively flat rare-earth element (REE) patterns that range from 20 8 x chondrites (Ce/YbN=0.8 1.5); (2) high-TiO2 tholeiite with evolved Mg-numbers (46 29) and high total REE abundances that range from 70 40 x chondrites (Ce/YbN=1.8 3.3), and (3) calc-alkaline basaltic andesite and geochemically similar monzodiorite and lamprophyre with primitive Mg-numbers (79 63), enriched light rare-earth elements (LREE) and depleted heavy rare-earth elements (HREE). These three suites are not related by partial melting of a similar source or by fractional crystallization of a common parental magma; they resulted from melting of heterogeneous Archean mantle. The felsic rocks are made up of two distinct suites: (1)low-Al2O3 tholeiitic rhyolite, and (2) high-Al2O3 calc-alkaline dacite and rhyolite and consanguineous tonalite. The tholeiitic felsic rocks are high in Y, Zr, Nb, and total REE that are unfractionated and have pronounced negative Eu anomalies. The calcalkaline felsic rocks are depleted in Y, Zr, and Nb, and the REE that are highly fractionated with high LREE and depleted HREE, and display moderate negative Eu anomalies. Both suites of felsic rocks were generated by partial melting of crustal material. The most reasonable modern analog for the paleotectonic setting is an immature island arc. The bimodal volcanic rocks are

Geologic map of the Gila Hot Springs 7.5' quadrangle and the Cliff Dwellings National Monument, Catron and Grant Counties, New Mexico

USGS Publications Warehouse

Ratté, James C.; Gaskill, David L.; Chappell, James R.

2014-01-01

part of the composite Copperas Creek volcano, or volcanic complex in the Copperas Peak quadrangle to the south. The altered rocks of the Alum Mountain eruptive center have been prospected by means of several short adits, or tunnels, for alum, a mixture of the iron and aluminum sulfate minerals: alunite and halotrichite. A fault on the west side of the Gila River, opposite the hot springs in the south-central part of the map area, just north of Alum Mountain, is tentatively interpreted as a segment of the wall of the Gila Cliff Dwellings caldera. The fault, which dips about 55 degrees northwest, has a footwall of the andesitic and dacitic lava flows and flow breccias of Gila Flat. The hanging wall consists of Bloodgood Canyon Tuff overlain by Bearwallow Mountain Andesite flows. However, these rocks are not faulted against the older rocks, but apparently abut and locally overlap the footwall. These are the major geologic features of the quadrangle, about three quarters of which is covered by Bearwallow Mountain Andesite lava flows and overlying volcaniclastic rocks of the Gila Conglomerate.

Petrology of the Rainy Lake area, Minnesota, USA-implications for petrotectonic setting of the archean southern Wabigoon subprovince of the Canadian Shield

USGS Publications Warehouse

Day, W.C.

1990-01-01

The Rainy Lake area in northern Minnesota and southwestern, Ontario is a Late Archean (2.7 Ga) granite-greenstone belt within the Wabigoon subprovince of the Canadian Shield. In Minnesota the rocks include mafic and felsic volcanic rocks, volcaniclastic, chemical sedimentary rocks, and graywacke that are intrucded by coeval gabbro, tonalite, and granodiorite. New data presented here focus on the geochemistry and petrology of the Minnesota part of the Rainy Lake area. Igneous rocks in the area are bimodal. The mafic rocks are made up of three distinct suites: (1) low-TiO2 tholeiite and gabbro that have slightly evolved Mg-numbers (63-49) and relatively flat rare-earth element (REE) patterns that range from 20-8 x chondrites (Ce/YbN=0.8-1.5); (2) high-TiO2 tholeiite with evolved Mg-numbers (46-29) and high total REE abundances that range from 70-40 x chondrites (Ce/YbN=1.8-3.3), and (3) calc-alkaline basaltic andesite and geochemically similar monzodiorite and lamprophyre with primitive Mg-numbers (79-63), enriched light rare-earth elements (LREE) and depleted heavy rare-earth elements (HREE). These three suites are not related by partial melting of a similar source or by fractional crystallization of a common parental magma; they resulted from melting of heterogeneous Archean mantle. The felsic rocks are made up of two distinct suites: (1)low-Al2O3 tholeiitic rhyolite, and (2) high-Al2O3 calc-alkaline dacite and rhyolite and consanguineous tonalite. The tholeiitic felsic rocks are high in Y, Zr, Nb, and total REE that are unfractionated and have pronounced negative Eu anomalies. The calcalkaline felsic rocks are depleted in Y, Zr, and Nb, and the REE that are highly fractionated with high LREE and depleted HREE, and display moderate negative Eu anomalies. Both suites of felsic rocks were generated by partial melting of crustal material. The most reasonable modern analog for the paleotectonic setting is an immature island arc. The bimodal volcanic rocks are

Leachability of uranium and other elements from freshly erupted volcanic ash

USGS Publications Warehouse

Smith, D.B.; Zielinski, R.A.; Rose, W.I.

1982-01-01

A study of leaching of freshly erupted basaltic and dacitic air-fall ash and bomb fragment samples, unaffected by rain, shows that glass dissolution is the dominant process by which uranium is initially mobilized from air-fall volcanic ash. Si, Li, and V are also preferentially mobilized by glass dissolution. Gaseous transfer followed by fixation of soluble uranium species on volcanic-ash particles is not an important process affecting uranium mobility. Gaseous transfer, however, may be important in forming water-soluble phases, adsorbed to ash surfaces, enriched in the economically and environmentally important elements Zn, Cu, Cd, Pb, B, F, and Ba. Quick removal of these adsorbed elements by the first exposure of freshly erupted ash to rain and surface water may pose short-term hazards to certain forms of aquatic and terrestrial life. Such rapid release of material may also represent the first step in transportation of economically important elements to environments favorable for precipitation into deposits of commercial interest. Ash samples collected from the active Guatemalan volcanoes Fuego and Pacaya (high-Al basalts) and Santiaguito (hornblende-hypersthene dacite); bomb fragments from Augustine volcano (andesite-dacite), Alaska, and Heimaey (basalt), Vestmann Islands, Iceland; and fragments of "rhyolitic" pumice from various historic eruptions were subjected to three successive leaches with a constant water-to-ash weight ratio of 4:1. The volcanic material was successively leached by: (1) distilled-deionized water (pH = 5.0-5.5) at room temperature for 24 h, which removes water-soluble gases and salts adsorbed on ash surfaces during eruption; (2) dilute HCl solution (pH = 3.5-4.0) at room temperature for 24 h, which continues the attack initiated by the water and also attacks acid-soluble sulfides and oxides; (3) a solution 0.05 M in both Na,CO, and NaHCO, (pH = 9.9) at 80°C for one week, which preferentially dissolves volcanic glass. The first two leaches

Recycling, Remobilization, and Eruption of Crystals from the Lassen Volcanic Center

NASA Astrophysics Data System (ADS)

Schrecengost, K.; Cooper, K. M.; Kent, A. J.; Huber, C.; Clynne, M. A.

2016-12-01

The Lassen Volcanic Center recently produced two relatively small dacitic eruptions (0.03 km3 -1.4 km3) with a complex mixing history. Preliminary data for the 1915 Lassen Peak (LP) and the 1103±13 ybp Chaos Crags (CC) eruptions indicate complex mixing between a remobilized crystal mush (hornblende, biotite, sodic plagioclase, quartz) and basalt or basaltic andesite. U-series bulk ages represent crystallization of plagioclase at an average age of either a single event or a mixture of different plagioclase populations that crystallized during distinct crystallization events separated in time. We present 238U-230Th disequilibria for the LP light dacite and black dacite along with three stages (upper pyroclastic flow deposit, Dome B, and Dome F) of the CC eruption. Initial 230Th/232Th activity ratios for the LP plagioclase are higher than the LP host liquid and modeled equilibrium zero-age plagioclase towards the CC host liquid composition. The LP plagioclase data are inconsistent with crystallization from the LP host liquid. Therefore, at least a portion of the plagioclase carried by the LP eruptive products are antecrystic originating from an older and/or isotopically distinct host liquid composition. Moreover, LP bulk plagioclase is consistent with crystallization from the CC host liquid, suggesting that both eruptions are sourced from a similar host reservoir (i.e., crystal mush). Hornblende and biotite from the LP eruption have isotopic ratios that are consistent with zero age crystallization from the LP liquid composition, suggesting that they are younger and originate from a different magma than the plagioclase, with mixing between the magmas prior to eruption. However, it is more likely that hornblende, biotite, and plagioclase with varying average crystal ages were remobilized and erupted from a common crystal mush reservoir during the LP and CC eruptions. These data are consistent with zircon 238U-230Th model ages [1] that emphasize the importance of local

Multiple shallow level sill intrusions coupled with hydromagmatic explosive eruptions marked the initial phase of Ferrar large igneous province magmatism in northern Victoria Land, Antarctica

USGS Publications Warehouse

Viereck-Goette, L.; Schöner, R.; Bomfleur, B.; Schneider, J.

2007-01-01

Field data gathered during GANOVEX IX (2005/2006) in Northern Victoria Land, Antarctica, indicate that volcaniclastic deposits of phreatomagmatic eruptions (so-called Exposure Hill Type events) are intercalated with fluvial deposits of Triassic-Jurassic age at two stratigraphic levels. Abundant scoriaceous spatter (locally welded) indicates a hawaiian/strombolian component. Breccia-filled diatremes, from which volcaniclastic deposits were sourced, are rooted in sills which intruded wet sediments. The deposits are thus subaerial expressions of initial Ferrar magmatism involving intrusion of multiple shallow-level sills. Due to magma-sediment interaction abundant clastic dikes are developed that intrude the sediments and sills. All igneous components in the volcaniclastic deposits are andesitic in composition, as are the chilled margins of the sills. They are more differentiated than the basaltic andesites of the younger effusive section of Kirkpatrick plateau lavas which in northern Victoria Land start with pillow lavas and small volume lava flows from volcanic necks.

Ar-Ar and I-Xe Ages of Caddo County and Thermal History of IAB Iron Meteorites

NASA Technical Reports Server (NTRS)

Bogard, Donald D.; Garrison, Daniel H.; Takeda, Hiroshi

2005-01-01

Inclusions in IAB iron meteorites include non-chondritic silicate and those with more primitive chondritic silicate composition. Coarse-grained gabbroic material rich in plagioclase and diopside occurs in the Caddo County IAB iron meteorite and represents a new type of chemically differentiated, extra-terrestrial, andesitic silicate. Other parts of Caddo contain mostly andesitic material. Caddo thus exhibits petrologic characteristics of parent body metamorphism of a chondrite-like parent and inhomogeneous segregation of melts. Proposed IAB formation models include parent body partial melting and fractional crystallization or incomplete differentiation due to internal heat sources, and impact/induced melting and mixing. Benedix et al. prefer a hybrid model whereby the IAB parent body largely melted, then underwent collisional breakup, partial mixing of phases, and reassembly. Most reported 129I- Xe-129 ages of IABs are greater than 4.56 Gyr and a few are greater than or = 4.567 Gyr. These oldest ages exceed the 4.567 Gyr Pb-Pb age of Ca, Al-rich inclusions in primitive meteorites,

Why large porphyry Cu deposits like high Sr/Y magmas?

PubMed Central

Chiaradia, Massimo; Ulianov, Alexey; Kouzmanov, Kalin; Beate, Bernardo

2012-01-01

Porphyry systems supply most copper and significant gold to our economy. Recent studies indicate that they are frequently associated with high Sr/Y magmatic rocks, but the meaning of this association remains elusive. Understanding the association between high Sr/Y magmatic rocks and porphyry-type deposits is essential to develop genetic models that can be used for exploration purposes. Here we present results on a Pleistocene volcano of Ecuador that highlight the behaviour of copper in magmas with variable (but generally high) Sr/Y values. We provide indirect evidence for Cu partitioning into a fluid phase exsolved at depths of ~15 km from high Sr/Y (>70) andesitic magmas before sulphide saturation. This lends support to the hypothesis that large amounts of Cu- and S-bearing fluids can be accumulated into and released from a long-lived high Sr/Y deep andesitic reservoir to a shallower magmatic-hydrothermal system with the potential of generating large porphyry-type deposits. PMID:23008750

Why large porphyry Cu deposits like high Sr/Y magmas?

PubMed

Chiaradia, Massimo; Ulianov, Alexey; Kouzmanov, Kalin; Beate, Bernardo

2012-01-01

Porphyry systems supply most copper and significant gold to our economy. Recent studies indicate that they are frequently associated with high Sr/Y magmatic rocks, but the meaning of this association remains elusive. Understanding the association between high Sr/Y magmatic rocks and porphyry-type deposits is essential to develop genetic models that can be used for exploration purposes. Here we present results on a Pleistocene volcano of Ecuador that highlight the behaviour of copper in magmas with variable (but generally high) Sr/Y values. We provide indirect evidence for Cu partitioning into a fluid phase exsolved at depths of ~15 km from high Sr/Y (>70) andesitic magmas before sulphide saturation. This lends support to the hypothesis that large amounts of Cu- and S-bearing fluids can be accumulated into and released from a long-lived high Sr/Y deep andesitic reservoir to a shallower magmatic-hydrothermal system with the potential of generating large porphyry-type deposits.

Experiments and Spectral Studies of Martian Volcanic Rocks: Implications for the Origin of Pathfinder Rocks and Soils

NASA Technical Reports Server (NTRS)

Rutherford, Malcolm J.; Mustard, Jack; Weitz, Catherine

2002-01-01

The composition and spectral properties of the Mars Pathfinder rocks and soils together with the identification of basaltic and andesitic Mars terrains based on Thermal Emission Spectrometer (TES) data raised interesting questions regarding the nature and origin of Mars surface rocks. We have investigated the following questions: (1) are the Pathfinder rocks igneous and is it possible these rocks could have formed by known igneous processes, such as equilibrium or fractional crystallization, operating within SNC magmas known to exist on Mars? If it is possible, what P (depth) and PH2O conditions are required? (2) whether TES-based interpretations of plagioclase-rich basalt and andesitic terrains in the south and north regions of Mars respectively are unique. Are the surface compositions of these regions plagioclase-rich, possibly indicating the presence of old AI-rich crust of Mars, or are the spectra being affected by something like surface weathering processes that might determine the spectral pyroxene to plagioclase ratio?

Pre-eruptive conditions of dacitic magma erupted during the 21.7 ka Plinian event at Nevado de Toluca volcano, Central Mexico

NASA Astrophysics Data System (ADS)

Arce, J. L.; Gardner, J. E.; Macías, J. L.

2013-01-01

The Nevado de Toluca volcano in Central Mexico has been active over the last ca. 42 ka, during which tens of km3 of pyroclastic material were erupted and two important Plinian-type eruptions occurred at ca. 21.7 ka (Lower Toluca Pumice: LTP) and ca. 10.5 ka (Upper Toluca Pumice: UTP). Samples from both the LTP and UTP contain plagioclase, amphibole, iron-titanium oxides, and minor anhedral biotite, set in a vesicular, rhyolitic, glassy matrix. In addition, UTP dacites contain orthopyroxene. Analysis of melt inclusions in plagioclase phenocrysts yields H2O contents of 2-3.5 wt.% for LTP and 1.3-3.6 wt.% for UTP samples. Ilmenite-ulvospinel geothermometry yields an average temperature of ~ 868 °C for the LTP magma (hotter than the UTP magma, ~ 842 °C; Arce et al., 2006), whereas amphibole-plagioclase geothermometry yields a temperature of 825-859 °C for the LTP magma. Water-saturated experiments using LTP dacite suggest that: (i) amphibole is stable above 100 MPa and below 900 °C; (ii) plagioclase crystallizes below 250-100 MPa at temperatures of 850-900 °C; and (iii) pyroxene is stable only below pressures of 200-100 MPa and temperatures of 825-900 °C. Comparison of natural and experimental data suggests that the LTP dacitic magma was stored at 150-200 MPa (5.8-7.7 km below the volcano summit). No differences in pressure found between 21.7 ka and 10.5 ka suggest that these two magmas were stored at similar depths. Orthopyroxene produced in lower temperature LTP experiments is compositionally different to those found in UTP natural samples, suggesting that they originated in two different magma batches. Whole-rock chemistry, petrographic features, and mineral compositions suggest that magma mixing was responsible for the generation of the dacitic Plinian LTP eruption.

Geothermal Potential of Adak Island, Alaska

DTIC Science & Technology

1985-10-01

alteration of the Andrew Bay Hot Springs is essentially propylitic , with the introduction of pyrite and the conversion of magnetite to pyrite. This pyritic...features: Goethite coats the walls of a 1-mm fracture in this rock. Classification: Propylitically altered andesite porphyry breccia. 71 NWC TP 6676 Date: 20

Fracture permeability in the Matalibong-25 corehole, Tiwi geothermal field, Philippines

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nielson, D.L.; Moore, J.N.; Clemente, W.C.

1996-12-31

The Tiwi geothermal field is located in southern Luzon on the northeast flank of Mt. Malinao, an andesitic volcano that was active 0.5 to 0.06 Ma. Matalibong-25 (Mat-25) was drilled through the Tiwi reservoir to investigate lithologic and fracture controls on reservoir permeability and to monitor reservoir pressure. Continuous core was collected from 2586.5 to 8000 feet (789 to 2439 meters) with greater than 95% recovery. The reservoir rocks observed in Mat-25 consist mainly of andesitic and basaltic lavas and volcaniclastic rocks above 6600 feet depth (2012 meters) and andesitic sediments below, with a transition from subaerial to subaqueous (marine)more » deposition at 5250 feet (1601 meters). The rocks in the reservoir interval are strongly altered and veined. Common secondary minerals include chlorite, illite, quartz, calcite rite, epidote, anhydrite, adularia and wairakite. An {sup 39}Ar/{sup 40}Ar age obtained on adularia from a quartz-adularia-cemented breccia at a depth of 6066 feet (2012 meters) indicates that the hydrothermal system has been active for at least 320,000 years. Fractures observed in the core were classified as either veins (sealed) or open fractures, with the latter assumed to represent fluid entries in the geothermal system. Since the core was not oriented, only fracture frequency and dip angle with respect to the core axis could be determined. The veins and open fractures are predominantly steeply dipping and have a measured density of up to 0.79 per foot in the vertical well. Below 6500 feet (1982 meters) there is a decrease in fracture intensity and in fluid inclusion temperatures.« less

Magnetic fabric and flow direction in the Ediacaran Imider dyke swarms (Eastern Anti-Atlas, Morocco), inferred from the Anisotropy of Magnetic Susceptibility (AMS)

NASA Astrophysics Data System (ADS)

Otmane, Khadija; Errami, Ezzoura; Olivier, Philippe; Berger, Julien; Triantafyllou, Antoine; Ennih, Nasser

2018-03-01

Located in the Imiter Inlier (Eastern Saghro, Anti-Atlas, Morocco), Ediacaran volcanic dykes have been studied for their petrofabric using Anisotropy of Magnetic Susceptibility (AMS) technique. Four dykes, namely TF, TD, FF and FE show andesitic compositions and are considered to belong to the same dyke swarm. They are oriented respectively N25E, N40E, N50E, and N10E and have been emplaced during a first tectonic event. The dyke FW, oriented N90E displays a composition of alkali basalt and its emplacement is attributed to a subsequent tectonic event. These rocks are propylitized under greenschist facies conditions forming a secondary paragenesis constituted by calcite, chlorite, epidote and sericite. The dykes TF, TD, FF and FE are sub-volcanic calc-alkaline, typical of post-collisional basalts/andesites, belonging to plate margin andesites. The FW dyke shows a within-plate basalt signature; alkaline affinity reflecting a different petrogenetic process. The thermomagnetic analyses show a dominantly ferromagnetic behaviour in the TF dyke core carried by single domain Ti-poor magnetite, maghemite and pyrrhotite. The dominantly paramagnetic susceptibilities in TF dyke rims and TD, FE, FF and FW dykes are controlled by ilmenite, amphibole, pyroxene and chlorite. The magnetic fabrics of the Imider dykes, determined by our AMS study, allows us to reconstitute the tectonic conditions which prevailed during the emplacement of these two generations of volcanic dykes. The first tectonic event was characterized by a roughly NE-SW compression and the second tectonic event is characterized by an E-W shortening followed by a relaxation recording the end of the Pan-African orogeny in the eastern Anti-Atlas.

The nature of magmatism at Palinpinon geothermal field, Negros Island, Philippines: implications for geothermal activity and regional tectonics

NASA Astrophysics Data System (ADS)

Rae, Andrew J.; Cooke, David R.; Phillips, David; Zaide-Delfin, Maribel

2004-01-01

The Palinpinon geothermal field, Negros Island, Philippines is a high-temperature, liquid-dominated geothermal system in an active island-arc volcanic setting. This paper presents a regional context for the Palinpinon geology, discusses the petrogenetic evolution of magmatism in the district and assesses the genetic relationships between intrusion and geothermal circulation. The oldest rock formation, the Lower Puhagan Volcanic Formation (Middle Miocene), is part of a volcanic sequence that is traceable throughout the Visayas region and is related to subduction of the Sulu Sea oceanic basin in a southeasterly direction beneath the Sulu arc. Late Miocene to Early Pliocene times mark a period of regional subsidence and marine sedimentation. A thick sequence of calcareous sediments (Okoy Formation) was deposited during this period. Magmatism in Early Pliocene to Recent times coincided with commencement of subduction at the Negros-Sulu Arc. This produced basaltic andesites and andesites belonging to the Southern Negros and Cuernos Volcanic Formations. During this time the Puhagan dikes and the Nasuji Pluton intruded Middle Miocene, Late Miocene and Early-Late Pliocene formations. Based on radiogenic ( 40Ar/ 39Ar) dating of hornblende, the Puhagan dikes are 4.1-4.2 Ma and the Nasuji Pluton 0.3-0.7 Ma. This age difference confirms these intrusions are not genetically related. The Early Pliocene age of the Puhagan dikes also confirms they are not the heat source for the current geothermal system and that a much younger intrusion is situated beyond drill depths. Igneous rock formations in southern Negros are the products of regional island-arc magmatism with medium K, calc-alkaline, basaltic to dacitic compositions. Their adakitic affinity implies that the melting of subducted oceanic basalt has influenced magmatism in this region. Considering the regional tectonic history the most likely scenarios for the generation of slab melts are: (1) during the Middle Miocene, by the

The A.D. 1835 eruption of Volcán Cosigüina, Nicaragua: A guide for assessing local volcanic hazards

USGS Publications Warehouse

Scott, William E.; Gardner, Cynthia A.; Devoli, Graziella; Alvarez, Antonio

2006-01-01

The January 1835 eruption of Volcán Cosigüina in northwestern Nicaragua was one of the largest and most explosive in Central America since Spanish colonization. We report on the results of reconnaissance stratigraphic studies and laboratory work aimed at better defining the distribution and character of deposits emplaced by the eruption as a means of developing a preliminary hazards assessment for future eruptions. On the lower flanks of the volcano, a basal tephra-fall deposit comprises either ash and fine lithic lapilli or, locally, dacitic pumice. An overlying tephra-fall deposit forms an extensive blanket of brown to gray andesitic scoria that is 35–60 cm thick at 5–10 km from the summit-caldera rim, except southwest of the volcano, where it is considerably thinner. The scoria fall produced the most voluminous deposit of the eruption and underlies pyroclastic-surge and -flow deposits that chiefly comprise gray andesitic scoria. In northern and southeastern sectors of the volcano, these flowage deposits form broad fans and valley fills that locally reach the Gulf of Fonseca. An arcuate ridge 2 km west of the caldera rim and a low ridge east of the caldera deflected pyroclastic flows northward and southeastward. Pyroclastic flows did not reach the lower west and southwest flanks, which instead received thick, fine-grained, accretionary-lapilli–rich ashfall deposits that probably derived chiefly from ash clouds elutriated from pyroclastic flows. We estimate the total bulk volume of erupted deposits to be ∼6 km3. Following the eruption, lahars inundated large portions of the lower flanks, and erosion of deposits and creation of new channels triggered rapid alluviation. Pre-1835 eruptions are poorly dated; however, scoria-fall, pyroclastic-flow, and lahar deposits record a penultimate eruption of smaller magnitude than that of 1835. It occurred a few centuries earlier—perhaps in the fifteenth century. An undated sequence of thick tephra-fall deposits on

Carboniferous volcanic rocks associated with back-arc extension in the western Chinese Tianshan, NW China: Insight from temporal-spatial character, petrogenesis and tectonic significance

NASA Astrophysics Data System (ADS)

Su, Wenbo; Cai, Keda; Sun, Min; Wan, Bo; Wang, Xiangsong; Bao, Zihe; Xiao, Wenjiao

2018-06-01

The Yili-Central Tianshan Block, as a Late Paleozoic major continental silver of the Central Asian Orogenic Belt, holds a massive volume of Carboniferous volcanic rocks, occurring as subparallel magmatic belts. However, the petrogenesis and tectonic implications of these volcanic rocks remain enigmatic. This study compiled isotopic age data for mapping their temporal-spatial character, and conducted petrogenetic study of these magmatic belts, aiming to understand their tectonic implications. Our compiled dataset reveals four magmatic belts in the Yili-Central Tianshan Block, including the Keguqinshan-Tulasu belt and the Awulale belt in the north, and the Wusun Mountain belt and the Haerk-Nalati belt in the south. In addition, our new zircon U-Pb dating results define two significant Early Carboniferous eruptive events (ca. 355-350 Ma and 325 Ma) in the Wusun Mountain belt. Volcanic rocks of the early significant eruptive event (ca. 355-350 Ma) in the Wusun Mountain comprise basalt, trachy-andesite, andesite, dacite and rhyolite, which are similar to the typical rock assemblage of a continental arc. Their positive εNd(t) values (+0.3 to +1.5) and relatively high Th/Yb and Nb/Yb ratios suggest the derivation from a mantle source with additions of slab-derived components. The gabbroic dykes and rhyolites of the late volcanic event (ca. 325 Ma) form a bimodal rock association, and they show alkaline features, with relatively low Th/Yb and Th/Nb ratios, and higher positive εNd(t) values (εNd(t) = +3.3-+5.0). It is interpreted that the gabbroic dykes and rhyolites may have been derived from mantle and juvenile crustal sources, respectively. The isotopic and trace elemental variations with time elapse of the Wusun Mountain magmatic belt show an important clue for strengthening depletion of the magma sources. Considering the distinctive temporal-spatial character of the Carboniferous volcanic rocks, two separate subduction systems in the southern and northern margins of

The Riscos Bayos Ignimbrites of the Caviahue-Copahue volcanic caldera complex, southern Andes, Argentina

NASA Astrophysics Data System (ADS)

Colvin, A.; Merrill, M.; Demoor, M.; Goss, A.; Varekamp, J. C.

2004-05-01

The Caviahue-Copahue volcanic complex (38 S, 70 W) is located on the eastern margin of the active arc in the southern Andes, Argentina. Volcán Copahue, an active stratovolcano which hosts an active hydrothermal system, sits on the southwestern rim of the elliptical Caviahue megacaldera (17 x 15 km). The caldera wall sequences are up to 0.6 km thick and consist of lavas with 51 -69 percent SiO2 and 0.2 - 5 percent MgO as well as breccias, dikes, sills, domes and minor ignimbrites. Andesitic lava flows also occur within the caldera, and are overlain by a chaotic complex of silicic lava and intracaldera pyroclastic flow deposits. The eastern wall sequence is capped by several extracaldera ignimbrites (Riscos Bayos formation) of about 50 m maximum thickness which extend 30 km east-southeast of the caldera. Young back-arc alkali basalt scoria cones occur east of the Caviahue-Copahue volcanic complex. The eruption of the Riscos Bayos formation at about 1.1 Ma (12 km cubed) may be related to the Caviahue caldera formation, though the Riscos Bayos account for only about 7 percent of the caldera volume. The Riscos Bayos consists of three lithic-bearing flow units: a grey basal flow, a tan middle flow and a bright-white, highly indurated uppermost flow. The basal unit consists of white and grey pumice fragments, black scoria clasts, black obsidian clasts (which give it the grey color), and accidental volcanic lithics set in a matrix of ash and crystals. The middle unit is composed of large mauve pumice fragments and accidental lithics set in a fine tan ash groundmass. The uppermost unit is composed of small pink and white pumice fragments set in a matrix of fine white ash. These pumices carry quartz and biotite crystals, whereas the lower two units are orthopyroxene-bearing trachy-dacites. The Caviahue-Copahue magmas all bear arc signatures, but possibly some magma mixing between the andesitic arc magmas and basaltic back-arc magmas may have occurred. The evolved top layer

Geochemistry and tectonic setting of the Paleoproterozoic metavolcanic rocks from the Chirano Gold District, Sefwi belt, Ghana

NASA Astrophysics Data System (ADS)

Senyah, Gloria A.; Dampare, Samuel B.; Asiedu, Daniel K.

2016-10-01

Major and trace elements, including rare earth elements (REEs) data are presented for metavolcanic rocks of the Paleoproterozoic Birimian Sefwi belt to determine the geochemical characteristics as well as the possible tectonic setting of emplacement of these rocks. In order to accomplish the aim of the study, the petrographical characteristics of the rocks were examined coupled with analysis of the rocks for their whole-rock major and trace elements contents by ICP-AES and ICP-MS methods respectively. The rocks have been classified as basalt/basaltic andesites and dolerites based on their textural and mineralogical compositions. It is observed that the rocks have suffered various degrees of alteration evident in the overprinting of primary minerals such as pyroxenes and plagioclase by chlorite, epidote, sericite and others. Generally, the rocks are moderately deformed and may have experienced at least greenschist metamorphism. The basalt/basaltic andesites are derivative magmas [Mg# (20-51), Cr (10-220 ppm) and Ni (5-137 ppm)], and show flat REE to fractionated REE patterns with (La/Sm)N = 1.36-3.90, (La/Yb)N = 1.17-5.32 and strong negative to non-existent Eu anomalies (Eu/Eu* = 0.51-1.03). N-MORB-normalised multi-element diagrams show that the rocks have geochemical patterns characterised by enrichment in LILE relative to HFSE and in LREE relative to HREE. The basalt/basaltic andesites exhibit characteristics of subduction zone-related magmas, such as pronounced negative Nb-Ta anomalies, slightly negative Hf and variable negative Ti anomalies. The dolerites do not vary much from the basalts and basaltic andesites. The MgO and Fe2O3 values of the dolerite range from 2.97 to 6.93 and 5.98 to 14.35 wt.% respectively, corresponding to Mg#s of 38-62. LREEs enrichment over HREEs with (La/Sm)N ranging from 0.61 to 4.61 and (Gd/Yb)N ranging from 0.99 to 2.91 is also typical of these rocks. The dolerites also exhibit quite invariable Eu anomalies (Eu/Eu* = 0.81-1.00) and

Multidisciplinary exploratory study of a geothermal resource in the active volcanic arc of Basse-Terre (Guadeloupe, Lesser Antilles)

NASA Astrophysics Data System (ADS)

Navelot, Vivien; Favier, Alexiane; Géraud, Yves; Diraison, Marc; Corsini, Michel; Verati, Chrystèle; Lardeaux, Jean-Marc; Mercier de Lépinay, Jeanne; Munschy, Marc

2017-04-01

The GEOTREF project (high enthalpy geothermal energy in fractured reservoirs), supported by the French government program, "Investissements d'avenir" develops a sustainable geothermal resource in the Vieux Habitants area, 8-km south of the currently exploited Bouillante geothermal field. The Basse Terre Island is a recent volcanic arc (< 3 Myr) belonging to the Lesser Antilles subduction zone. It is composed of arc typical calc-alkaline volcanic rocks. Outcrops of the studied area consist either of andesitic lava flows, volcanic sedimentary facies or dikes. Field studies allow to propose a structural framework and highlight three major directions N000˚ E, N050˚ E and N090˚ E, which are consistent with the regional tectonic trends of the arc. Petrographical and petrophysical studies displayed that the major part of outcropping facies in the Vieux-Habitants area are not altered. Andesitic lava flows have poor reservoir properties with porosity and permeability lower than 5 % and 10-15m2 respectively. These results are in contrast with measurements performed in volcano-sedimentary rocks, which have heterogeneous petrophysical properties ranging from 15 to 50 % for porosity and from 10-15to 10-9m2 for permeability. Such surface data would probably change and decrease when depth increases. As there is a lack of underground data under the Vieux-Habitants area (wireline, drill core), exhumated rocks outcropping in the northern part of Basse-Terre Island (Basal Complex) have been studied. Such rocks have been identified in the Basal Complex (2.5 - 3 Myr) located in the northern part of the Basse-Terre Island. Previous works have demonstrated a 1000 m/Myr erosional rate, which corresponds at least to a 2 - 3 km exhumation. The petrography study of the Basal Complex reveals sub-greenschist type mineralogical transformations (chlorite, white mica, quartz...) changing the andesitic protolith in a meta-andesite. This metamorphism forms cleavage plans thanks to a pressure

Lower Pliensbachian caldera volcanism in high-obliquity rift systems in the western North Patagonian Massif, Argentina

NASA Astrophysics Data System (ADS)

Benedini, Leonardo; Gregori, Daniel; Strazzere, Leonardo; Falco, Juan I.; Dristas, Jorge A.

2014-12-01

In the Cerro Carro Quebrado and Cerro Catri Cura area, located at the border between the Neuquén Basin and the North Patagonian Massif, the Garamilla Formation is composed of four volcanic stages: 1) andesitic lava-flows related to the beginning of the volcanic system; 2) basal massive lithic breccias that represent the caldera collapse; 3) voluminous, coarse-crystal rich massive lava-like ignimbrites related to multiple, steady eruptions that represent the principal infill of the system; and, finally 4) domes, dykes, lava flows, and lava domes of rhyolitic composition indicative of a post-collapse stage. The analysis of the regional and local structures, as well as, the architectures of the volcanic facies, indicates the existence of a highly oblique rift, with its principal extensional strain in an NNE-SSW direction (˜N10°). The analyzed rocks are mainly high-potassium dacites and rhyolites with trace and RE elements contents of an intraplate signature. The age of these rocks (189 ± 0.76 Ma) agree well with other volcanic sequences of the western North Patagonian Massif, as well as, the Neuquén Basin, indicating that Pliensbachian magmatism was widespread in both regions. The age is also coincident with phase 1 of volcanism of the eastern North Patagonia Massif (188-178 Ma) represented by ignimbrites, domes, and pyroclastic rocks of the Marifil Complex, related to intraplate magmatism.

Impact of hydrothermal alteration on time-dependent tunnel deformation in Neogene volcanic rock sequence in Japan: Petrology, Geochemistry and Geophysical investigation

NASA Astrophysics Data System (ADS)

Yamazaki, S.; Okazaki, K.; Niwa, H.; Arai, T.; Murayama, H.; Kurahashi, T.; Ito, Y.

2017-12-01

Time-dependent tunnel deformation is one of remaining geological problems for mountain tunneling. As a case study of time-dependent tunnel deformation, we investigated petrographical, mineral and chemical compositions of boring core samples and seismic exploration along a tunnel that constructed into Neogene volcanic rock sequence of andesite to dacite pyroclastic rocks and massive lavas with mafic enclaves. The tunnel has two zones of floor heaving that deformed time-dependently about 2 month after the tunnel excavation. The core samples around the deformed zones are characterized secondary mineral assemblages of smectite, cristobalite, tridymite, sulfides (pyrite and marcasite) and partially or completely reacted carbonates (calcite and siderite), which were formed by hydrothermal alteration under neutral to acidic condition below about 100 °C. The core samples also showed localized deterioration, such as crack formation and expansion, which occurred from few days to months after the drilling. The deterioration could be explained as a result of the cyclic physical and chemical weathering process with the oxidation of sulfide minerals, dissolution of carbonate mineral cementation and volumetric expantion of smectite. This weathering process is considered as a key factor for time-dependent tunnel deformation in the hydrothermally altered volcanic rocks. The zones of time-dependent deformation along a tunnel route can be predicted by the variations of whole-rock chemical compositions such as Na, Ca, Sr, Ba and S.

Recycling lower continental crust in the North China craton.

PubMed

Gao, Shan; Rudnick, Roberta L; Yuan, Hong-Ling; Liu, Xiao-Ming; Liu, Yong-Sheng; Xu, Wen-Liang; Ling, Wen-Li; Ayers, John; Wang, Xuan-Che; Wang, Qing-Hai

2004-12-16

Foundering of mafic lower continental crust into underlying convecting mantle has been proposed as one means to explain the unusually evolved chemical composition of Earth's continental crust, yet direct evidence of this process has been scarce. Here we report that Late Jurassic high-magnesium andesites, dacites and adakites (siliceous lavas with high strontium and low heavy-rare-earth element and yttrium contents) from the North China craton have chemical and petrographic features consistent with their origin as partial melts of eclogite that subsequently interacted with mantle peridotite. Similar features observed in adakites and some Archaean sodium-rich granitoids of the tonalite-trondhjemite-granodiorite series have been interpreted to result from interaction of slab melts with the mantle wedge. Unlike their arc-related counterparts, however, the Chinese magmas carry inherited Archaean zircons and have neodymium and strontium isotopic compositions overlapping those of eclogite xenoliths derived from the lower crust of the North China craton. Such features cannot be produced by crustal assimilation of slab melts, given the high Mg#, nickel and chromium contents of the lavas. We infer that the Chinese lavas derive from ancient mafic lower crust that foundered into the convecting mantle and subsequently melted and interacted with peridotite. We suggest that lower crustal foundering occurred within the North China craton during the Late Jurassic, and thus provides constraints on the timing of lithosphere removal beneath the North China craton.

Water contents, temperatures and diversity of the magmas of the catastrophic eruption of Nevado del Ruiz, Colombia, November 13, 1985

NASA Astrophysics Data System (ADS)

Melson, William G.; Allan, James F.; Jerez, Deborah Reid; Nelen, Joseph; Calvache, Marta Lucia; Williams, Stanley N.; Fournelle, John; Perfit, Mike

1990-07-01

The petrology of the highly phyric two-pyroxene andesitic to dacitic pyroclastic rocks of the November 13, 1985 eruption of Nevado del Ruiz, Colombia, reveals evidence of: (1) increasingly fractionated bulk compositions with time; (2) tapping of a small magma chamber marginally zoned in regard to H 2O contents (1 to 4%), temperature (960-1090°C), and amount of residual melt (35 to 65%); (3) partial melting and assimilation of degassed zones in the hotter less dense interior of the magma chamber; (4) probable heating, thermal disruption and mineralogic and compositional contamination of the magma body by basaltic magma "underplating"; and (5) crustal contamination of the magmas during ascent and within the magma chamber. Near-crater fall-back or "spill-over" emitted in the middle of the eruptive sequence produced a small pyroclastic flow that became welded in its central and basal portions because of ponding and thus heat conservation on the flat glaciated summit near the Arenas crater. The heterogeneity of Ruiz magmas may be related to the comparatively small volume (0.03 km 3) of the eruption, nearly ten times less than the 0.2 km 3 of the Plinian phase of Mount St. Helens, and probable steep thermal and PH 2O gradients of a small source magma chamber, estimated at 300 m long and 100 m wide for an assumed ellipsoidal shape.

Permian magmatic sequences of the Bilihe gold deposit in central Inner Mongolia, China: Petrogenesis and tectonic significance

NASA Astrophysics Data System (ADS)

Liu, Chunhua; Nie, Fengjun

2015-08-01

The Bilihe gold deposit is located in the eastern section of the Ondor Sum-Yanji Suture at the southern margin of the Xing'an-Mongolian Orogenic Belt (XMOB) and the northern margin of the North China Craton (NCC), central Inner Mongolia. The magmatic rocks in the ore district are generally high-K calc-alkaline, enriched in LREE, Zr, and Hf, and depleted in HREE, Nb, Ta, and P. The magmatic evolution sequences are norite gabbro → granodiorite porphyry → granite or norite gabbro → andesite → dacite porphyry → granodiorite, which show a trend of decreasing TiO2, FeO, MgO, CaO, and P2O5 with increasing SiO2. In the Bilihe ore district, hydrothermal processes were coeval with granitic magmatism for a period of ~ 17 Myr (272-255 Ma). The ages of the granite, granodiorite porphyry, granodiorite, and dacite porphyry are 271.5-264.1 Ma, 269.8-255.8 Ma, 268.3 Ma, and 268.6-259.4 Ma, respectively. The magmatic rocks contain magmatic, hydrothermal, and magmatic-hydrothermal zircons. The magmatic zircons have δCe > 4, La < 3 ppm, and SmN/LaN > 2.5; the hydrothermal zircons have δCe < 4, La > 3 ppm, and SmN/LaN < 2.5. The Nb/Ta and Zr/Hf ratios of granodiorite are 12.7-14.99 and 40.2-46.56, respectively. The Zr/Hf ratios successively increase in the sequence of granite (27.4-29.02) → granodiorite porphyry (29.19-32.18) → dacite porphyry (33.54-38.5) → norite gabbro (36.75-38.37), and their Nb/Ta ratios are 9.09-12.38. Zircons in granodiorite yield ε Hf (t) values of - 0.29 to - 56 (n = 13) and 2.07-7.62 (n = 5), and they give a Hf two-stage model age (tDM2) of 807-4765 Ma. The ε Hf (t) values of the zircons in granite, granodiorite porphyry, and dacite porphyry are - 0.46 to 8.03, 3.17 to 10.32, and - 0.78 to 6.58, respectively, and their Hf tDM2 ages are 787-1324 Ma, 638-1091 Ma, and 868-1343 Ma, respectively. Dehydration partial melting of subducted oceanic crust resulted in the formation of dacite porphyry; partial melting of depleted mantle resulted in

Mountain Meadows Dacite: Oligocene intrusive complex that welds together the Los Angeles Basin, northwestern Peninsular Ranges, and central Transverse Ranges, California

USGS Publications Warehouse

McCulloh, Thane H.; Beyer, Larry A.; Morin, Ronald W.

2001-01-01

Dikes and irregular intrusive bodies of distinctive Oligocene biotite dacite and serially related hornblende latite and felsite occur widely in the central and eastern San Gabriel Mountains, southern California, and are related to the Telegraph Peak granodiorite pluton. Identical dacite is locally present beneath Middle Miocene Topanga Group Glendora Volcanics at the northeastern edge of the Los Angeles Basin, where it is termed Mountain Meadows Dacite. This study mapped the western and southwestern limits of the dacite distribution to understand the provenance of derived redeposited clasts, to perceive Neogene offsets on several large strike-slip faults, to test published palinspastic reconstructions, and to better understand the tectonic boundaries that separate contrasting pre-Tertiary rock terranes where the Peninsular Ranges meet the central and western Transverse Ranges and the Los Angeles Basin. Transported and redeposited clasts of dacite-latite occur in deformed lower Miocene and lower middle Miocene sandy conglomerates (nonmarine, nearshore, and infrequent upper bathyal) close to the northern and northeastern margins of the Los Angeles Basin for a distance of nearly 60 km. Tie-lines between distinctive source suites and clast occurrences indicate that large tracts of the ancestral San Gabriel Mountains were elevated along range-bounding faults as early as 16–15 Ma. The tie-lines prohibit very large strike-slip offsets on those faults. Transport of eroded dacite began south of the range as early as 18 Ma. Published and unpublished data about rocks adjacent to the active Santa Monica-Hollywood-Raymond oblique reverse left-lateral fault indicate that cumulative left slip totals 13–14 km and total offset postdates 7 Ma. This cumulative slip, with assembly of stratigraphic and paleogeographic data, invalidates prior estimates of 60 to 90 km of left slip on these faults beginning about 17–16 Ma. A new and different palinspastic reconstruction of a region

Sulfur in Hydrous, Oxidized Basaltic Magmas: Phase Equilibria and Melt Solubilities

NASA Astrophysics Data System (ADS)

Pichavant, M.; Scaillet, B.; di Carlo, I.; Rotolo, S.; Metrich, N.

2006-05-01

Basaltic magmas from subduction zone settings are typically S-rich and may be the ultimate source of sulfur in vapor phases emitted during eruptions of more silicic systems. To understand processes of sulfur recycling in subduction zones, the behaviour of S in hydrous, oxidized, mafic arc magmas must be known. Although experimental data on S-bearing basaltic melts are available for dry conditions, and under both reduced and oxidized fO2, no study has yet examined the effect of S in hydrous mafic melts. In this work, 3 starting compositions were investigated, a basaltic andesite, a K basalt and a picritic basalt. For each composition, experimental data for S-added (1 wt % elemental sulfur) and S-free charges were obtained under similar P-T- H2O-fO2. All experiments were performed at 4 kbar and at either 950 ° C (basaltic andesite), 1100 ° C (K basalt) or 1150 ° C (picritic basalt). These were carried out in an internally heated vessel pressurized with Ar-H2 mixtures and fitted with a drop-quench device, and lasted for between 15 and 99 h. Either Au (950 ° C) or AuPd alloys (1100 and 1150 ° C) were used as containers. These latter perform satisfactorily under strongly oxidizing conditions, i.e., for fO2 above NNO+1 at 1100 and 1150 ° C. Below NNO+1, Pd- Au-S-Fe phases appear in the charges, suggesting extensive interaction between S and the capsule material. Experimental redox conditions, determined from Ni-Pd-O sensors, ranged between NNO+1.3 to +4.1 (basaltic andesite), +0.6 to +2.0 (K basalt), and +0.3 to +3.6 (picritic basalt). H2O concentrations in melt ranged from 8.2 wt % (basaltic andesite), decreasing to 2.2-3.9 wt % (K basalt) and 2.5-5.0 wt % (picritic basalt). All 3 compositions studied crystallize anhydrite and Fe-Ni-S-O sulphide as saturating S-bearing phases, anhydrite at high fO2 and sulphide at lower fO2, although melt composition also influences their stability. Anhydrite is present at a fO2 as low as NNO+1.5 in the K basalt. In the picritic

A facies model for a quaternary andesitic composite volcano: Ruapehu, New Zealand

NASA Astrophysics Data System (ADS)

Hackett, W. R.; Houghton, B. F.

1989-01-01

Ruapehu composite volcano is a dynamic volcanic-sedimentary system, characterised by high accumulation rates and by rapid lateral and vertical change in facies. Four major cone-building episodes have occurred over 250 Ka, from a variety of summit, flank and satellite vents. Eruptive styles include subplinian, strombolian, phreatomagmatic, vulcanian and dome-related explosive eruptions, and extrusion of lava flows and domes. The volcano can be divided into two parts: a composite cone of volume 110 km3, surrounded by an equally voluminous ring plain. Complementary portions of Ruapehu's history are preserved in cone-forming and ring plain environments. Cone-forming sequences are dominated by sheet- and autobrecciated-lava flows, which seldom reach the ring plain. The ring plain is built predominantly from the products of explosive volcanism, both the distal primary pyroclastic deposits and the reworked material eroded from the cone. Much of the material entering the ring plain is transported by lahars either generated directly by eruptions or triggered by the high intensity rain storms which characterise the region. Ring plain detritus is reworked rapidly by concentrated and hyperconcentrated streams in pulses of rapid aggradation immediately following eruptions and more gradually in the longer intervals between eruptions.

Magmas and reservoirs beneath the Rabaul caldera (Papua New Guinea)

NASA Astrophysics Data System (ADS)

Bouvet de Maisonneuve, C.; Costa Rodriguez, F.; Huber, C.

2013-12-01

The area of Rabaul (Papua New Guinea) consists of at least seven - possibly nine - nested-calderas that have formed over the past 200 ky. The last caldera-forming eruption occurred 1400 y BP, and produced about 10 km3 of crystal-poor, two-pyroxene dacite. Since then, five effusive and explosive eruptive episodes have occurred from volcanic centres along the caldera rim. The most recent of these was preceded by decade-long unrest (starting in 1971) until the simultaneous eruption of Vulcan and Tavurvur, two vents on opposite sides of the caldera in 1994. Most eruptive products are andesitic in composition and show clear signs of mixing/mingling between a basalt and a high-K2O dacite. The hybridization is in the form of banded pumices, quenched mafic enclaves, and hybrid bulk rock compositions. In addition, the 1400 y BP caldera-related products show the presence of a third mixing component; a low-K2O rhyodacitic melt or magma. Geochemical modeling considering major and trace elements and volatile contents shows that the high-K2O dacitic magma can be generated by fractional crystallization of the basaltic magma at shallow depths (~7 km, 200 MPa) and under relatively dry conditions (≤3 wt% H2O). The low-K2O rhyodacitic melt can either be explained by extended crystallization at low temperatures (e.g. in the presence of Sanidine) or the presence of an additional, unrelated magma. Our working model is therefore that basalts ascend to shallow crustal levels before intruding a main silicic reservoir beneath the Rabaul caldera. Storage depths and temperatures estimated from volatile contents, mineral-melt equilibria and rock densities suggest that basalts ascend from ~20 km (~600 MPa) to ~7 km (200 MPa) and cool from ~1150-1100°C before intruding a dacitic magma reservoir at ~950°C. Depending on the state of the reservoir and the volumes of basalt injected, the replenishing magma may either trigger an eruption or cool and crystallize. We use evidence from major and

High-Mg subduction-related Tertiary basalts in Sardinia, Italy

NASA Astrophysics Data System (ADS)

Morra, V.; Secchi, F. A. G.; Melluso, L.; Franciosi, L.

1997-03-01

The Oligo-Miocene volcanics (32-15 Ma), which occur in the Oligo-Miocene Sardinian Rift, were interpreted in the literature as an intracontinental volcanic arc built upon continental crust about 30 km thick. They are characterized by a close field association of dominantly andesites and acid ignimbrites, with subordinate basalts. In this paper we deal with the origin and evolution of recently discovered high-magnesia basalts aged ca. 18 Ma occurring in the Montresta area, northern Sardinia, relevant to the petrogenesis of the Cenozoic volcanics of Sardinia. The igneous rocks of the Montresta area form a tholeiitic, subduction-related suite. Major-element variation from the high-magnesia basalts (HMB) to high-alumina basalts (HAB) are consistent with crystal/liquid fractionation dominated by olivine and clinopyroxene. Proportions of plagioclase and titanomagnetite increase from HAB to andesites. Initial {87Sr }/{86Sr } ratios increase with differentiation from 0.70398 for the HMB to 0.70592 for the andesites. This suggests concomitant crustal contamination. The geochemical characteristics of the high-magnesia basalts are typical of subduction-related magmas, with negative Nb, Zr and Ti spikes in mantle-normalized diagrams. It is proposed that these high-magnesia basalts were produced by partial melting of a mantle source characterized by large-ion lithophile elements (LILE) enrichment related principally to dehydration of subducted oceanic crust. Chondrite-normalized rare earth elements (REE) patterns indicate that the lavas are somewhat enriched in light rare earth elements (LREE), with flat heavy rare earth elements (HREE) patterns. This evidence is consistent with a spinel-bearing mantle source. The sub-parallel chondrite-normalized patterns show enrichment with differentiation, with a greater increase of LREE than HREE. The occurrence of high-magnesia basalts at 18 Ma in Sardinia appears to be correlated with and favoured by pronounced extensional tectonics at

Petrogenesis of voluminous mid-Tertiary ignimbrites of the Sierra Madre Occidental, Chihuahua, Mexico

NASA Astrophysics Data System (ADS)

Cameron, Maryellen; Bagby, William C.; Cameron, Kenneth L.

1980-10-01

The mid-Tertiary ignimbrites of the Sierra Madre Occidental of western Mexico constitute the largest continuous rhyolitic province in the world. The rhyolites appear to represent part of a continental magmatic arc that was emplaced when an eastward-dipping subduction zone was located beneath western Mexico. In the Batopilas region of the northern Sierra Madre Occidental the mid-Tertiary Upper Volcanic sequence is composed predominantly of rhyolitic ignimbrites, but volumetrically minor lava flows as mafic as basaltic andesite are also present. The basaltic andesite to rhyolite series is calc-alkalic and contains ˜1% K2O at 60% SiO2. Trace element abundances of a typical ignimbrite with 73% SiO2 are Sr ˜ 225 ppm, Rb ˜130 ppm, Y ˜32 ppm, Th ˜12 ppm, Zr ˜200 ppm, and Nb ˜15 ppm. The entire series plots as coherent and continuous trends on variation diagrams involving major and trace elements, and the trends are distinct from those of geographicallyassociated rocks of other suites. We interpret these and other geochemical variations to indicate that the rocks are comagmatic. Mineral chemistry, Sr isotopic data, and REE modelling support this interpretation. Least squares calculations show that the major element variations are consistent with formation of the basaltic andesite to rhyolite series by crystal fractionation of observed phenocryst phases in approximate modal proportions. In addition, calculations modelling the behavior of Sr with the incompatible trace element Th favor a fractional crystallization origin over a crustal anatexis origin for the rock series. The fractionating minerals included plagioclase (> 50%), and lesser amounts of Fe-Ti oxides, pyroxenes, and/or hornblende. The voluminous ignimbrites represent no more than 20% of the original mass of a mantle-derived mafic parental magma.

Evolution of the East Philippine Arc: experimental constraints on magmatic phase relations and adakitic melt formation

NASA Astrophysics Data System (ADS)

Coldwell, B.; Adam, J.; Rushmer, T.; MacPherson, C. G.

2011-10-01

Piston-cylinder experiments on a Pleistocene adakite from Mindanao in the Philippines have been used to establish near-liquidus and sub-liquidus phase relationships relevant to conditions in the East Philippines subduction zone. The experimental starting material belongs to a consanguineous suite of adakitic andesites. Experiments were conducted at pressures from 0.5 to 2 GPa and temperatures from 950 to 1,150°C. With 5 wt. % of dissolved H2O in the starting mix, garnet, clinopyroxene and orthopyroxene are liquidus phases at pressures above 1.5 GPa, whereas clinopyroxene and orthopyroxene are liquidus (or near-liquidus) phases at pressures <1.5 GPa. Although amphibole is not a liquidus phase under any of the conditions examined, it is stable under sub-liquidus conditions at temperature ≤1,050°C and pressures up to 1.5 GPa. When combined with petrographic observations and bulk rock chemical data for the Mindanao adakites, these findings are consistent with polybaric fractionation that initially involved garnet (at pressures >1.5 GPa) and subsequently involved the lower pressure fractionation of amphibole, plagioclase and subordinate clinopyroxene. Thus, the distinctive Y and HREE depletions of the andesitic adakites (which distinguish them from associated non-adakitic andesites) must be established relatively early in the fractionation process. Our experiments show that this early fractionation must have occurred at pressures >1.5 GPa and, thus, deeper than the Mindanao Moho. Published thermal models of the Philippine Sea Plate preclude a direct origin by melting of the subducting ocean crust. Thus, our results favour a model whereby basaltic arc melt underwent high-pressure crystal fractionation while stalled beneath immature arc lithosphere. This produced residual magma of adakitic character which underwent further fractionation at relatively low (i.e. crustal) pressures before being erupted.

Sixty thousand years of magmatic volatile history before the caldera-forming eruption of Mount Mazama, Crater Lake, Oregon

USGS Publications Warehouse

Wright, Heather M.; Bacon, Charles R.; Vazquez, Jorge A.; Sisson, Thomas W.

2012-01-01

The well-documented eruptive history of Mount Mazama, Oregon, provides an excellent opportunity to use pre-eruptive volatile concentrations to study the growth of an explosive silicic magmatic system. Melt inclusions (MI) hosted in pyroxene and plagioclase crystals from eight dacitic–rhyodacitic eruptive deposits (71–7.7 ka) were analyzed to determine variations in volatile-element concentrations and changes in magma storage conditions leading up to and including the climactic eruption of Crater Lake caldera. Temperatures (Fe–Ti oxides) increased through the series of dacites, then decreased, and increased again through the rhyodacites (918–968 to ~950 to 845–895 °C). Oxygen fugacity began at nickel–nickel-oxide buffer (NNO) +0.8 (71 ka), dropped slightly to NNO +0.3, and then climbed to its highest value with the climactic eruption (7.7 ka) at NNO +1.1 log units. In parallel with oxidation state, maximum MI sulfur concentrations were high early in the eruptive sequence (~500 ppm), decreased (to ~200 ppm), and then increased again with the climactic eruption (~500 ppm). Maximum MI sulfur correlates with the Sr content (as a proxy for LREE, Ba, Rb, P2O5) of recharge magmas, represented by basaltic andesitic to andesitic enclaves and similar-aged lavas. These results suggest that oxidized Sr-rich recharge magmas dominated early and late in the development of the pre-climactic dacite–rhyodacite system. Dissolved H2O concentrations in MI do not, however, correlate with these changes in dominant recharge magma, instead recording vapor solubility relations in the developing shallow magma storage and conduit region. Dissolved H2O concentrations form two populations through time: the first at 3–4.6 wt% (with a few extreme values up to 6.1 wt%) and the second at ≤2.4 wt%. CO2 concentrations measured in a subset of these inclusions reach up to 240 ppm in early-erupted deposits (71 ka) and are below detection in climactic deposits (7.7 ka). Combined H2O and

Quaternary bimodal volcanism in the Niğde Volcanic Complex (Cappadocia, central Anatolia, Turkey): age, petrogenesis and geodynamic implications

NASA Astrophysics Data System (ADS)

Aydin, Faruk; Schmitt, Axel K.; Siebel, Wolfgang; Sönmez, Mustafa; Ersoy, Yalçın; Lermi, Abdurrahman; Dirik, Kadir; Duncan, Robert

2014-11-01

The late Neogene to Quaternary Cappadocian Volcanic Province (CVP) in central Anatolia is one of the most impressive volcanic fields of Turkey because of its extent and spectacular erosionally sculptured landscape. The late Neogene evolution of the CVP started with the eruption of extensive andesitic-dacitic lavas and ignimbrites with minor basaltic lavas. This stage was followed by Quaternary bimodal volcanism. Here, we present geochemical, isotopic (Sr-Nd-Pb and δ18O isotopes) and geochronological (U-Pb zircon and Ar-Ar amphibole and whole-rock ages) data for bimodal volcanic rocks of the Niğde Volcanic Complex (NVC) in the western part of the CVP to determine mantle melting dynamics and magmatic processes within the overlying continental crust during the Quaternary. Geochronological data suggest that the bimodal volcanic activity in the study area occurred between ca. 1.1 and ca. 0.2 Ma (Pleistocene) and comprises (1) mafic lavas consisting of basalts, trachybasalts, basaltic andesites and scoria lapilli fallout deposits with mainly basaltic composition, (2) felsic lavas consisting of mostly rhyolites and pumice lapilli fall-out and surge deposits with dacitic to rhyolitic composition. The most mafic sample is basalt from a monogenetic cone, which is characterized by 87Sr/86Sr = 0.7038, 143Nd/144Nd = 0.5128, 206Pb/204Pb = 18.80, 207Pb/204Pb = 15.60 and 208Pb/204Pb = 38.68, suggesting a moderately depleted signature of the mantle source. Felsic volcanic rocks define a narrow range of 143Nd/144Nd isotope ratios (0.5126-0.5128) and are homogeneous in Pb isotope composition (206Pb/204Pb = 18.84-18.87, 207Pb/204Pb = 15.64-15.67 and 208Pb/204Pb = 38.93-38.99). 87Sr/86Sr isotopic compositions of mafic (0.7038-0.7053) and felsic (0.7040-0.7052) samples are similar, reflecting a common mantle source. The felsic rocks have relatively low zircon δ18O values (5.6 ± 0.6 ‰) overlapping mantle values (5.3 ± 0.3 %), consistent with an origin by fractional crystallization

Geothermal Resource Evaluation at Naval Air Station Fallon, Nevada

DTIC Science & Technology

1987-08-01

20 4. Mainside Topographic Map Showing Warm Wells and Thermal Gradient H oles... Oligocene and early Miocene periods. These troughs were sites of intense hyohtic to andesitic volcanism and coeval faulting. The orientation and age...volcanic sequence, (2) intervolcanic sediments in the volcanic sequence. (3) a fractured reservoir within uwderlying Mio- Oligocene acid tuffs and

Paleogeographic implications of an erosional remnant of Paleogene rocks southwest of the Sur-Nacimiento Fault Zone, southern Coast Ranges, California

USGS Publications Warehouse

Vedder, J.G.; McLean, H.; Stanley, R.G.; Wiley, T.J.

1991-01-01

A small tract of heretofore-unrecognized Paleogene rocks lies about 30 km northeast of Santa Maria and 1 km southwest of the Sur-Nacimiento fault zone near upper Pine Creek. This poorly exposed assemblage of rocks is less than 50 m thick, lies unconformably on regionally distributed Upper Cretaceous submarine-fan deposits, and consists of three units: fossiliferous lower Eocene mudstone, Oligocene(?) conglomerate, and basaltic andesite that has a radiometric age of 26.6 ?? 0.5 Ma. Both the sedimentary and igneous constituents in the Paleogene sequence are unlike those of known sequences on either side of the Sur-Nacimiento fault zone. The Paleogene sedimentary rocks near upper Pine Creek presumably are remnants of formerly widespread early Eocene bathyal deposits and locally distributed Oligocene(?) fluvial deposits southwest of the fault zone. The 26.6 Ma basaltic andesite, however, may not have extended much beyond its present outcrops. An episode of Oligocene(?) displacement is required by the contrast in thicknesses, depositional patterns, and paleobathymetry of the juxtaposed rock sequences. -from Authors

LA-ICP-MS analysis of trace elements in glass spherules of the El'gygytgyn impact structure, Siberia

NASA Astrophysics Data System (ADS)

Adolph, Leonie; Deutsch, Alex

2010-05-01

The 3.58±0.04 Ma old El'gygytgyn impact structure (Central Chukotka, NE Siberia) with a diameter of 18 km (Gurov and Gurova 1979, Layer 2000) is one of only two terrestrial craters with a volcanic target; therefore, analysis of its target and impact lithologies is of basic interest for comparative planetology. Lake El'gygytgyn is a very valuable climate archive in the Arctic as it was neither covered by glaciers (Melles et al. 2007) nor has the lake ever fallen dry. Climate and impact research were the rationale for the ICDP drilling project that finished successfully in spring 2009. Impactites like melt rocks and breccias are rarely found in outcrops yet are present in the 80 m terrace of Lake El'gygytgyn (Gurov and Gurova 1979). Numerous investigations on petrography, shock metamorphism, and geochemistry of impactites from El'gygytgyn have been published so far (e.g. Gurov et al. 2007). We report the first trace element data for seven 30- to 760-μm-sized impact glass spherules that have been collected about10 km off the crater center from a terrace deposit of the Enmyvaam River outside the crater rim. The spherules are translucent with colors ranging from amber, dark brown to nearly black; they contain a few circular bubbles, schlieren, and very rarely mineral clasts and breccia fragments. Major elements were measured with the JEOL JXA 8600 MX Superprobe, 31 trace elements were analyzed with the Finnigan Element2 LA-ICP-MS with 5 Hz, 8-9 J/cm2 at with Si as internal, and NIST612 as external standard (Institut f. Mineralogie, WWU Münster). The spot size was 60 μm. All spherules show a very homogeneous major and trace element distribution yet clear differences exist between the samples in the SiO2 content (in weight percent) 53-68: four of the glasses are dacitic, two andesitic, and one basaltic-andesitic in composition. In addition, MgO (2.1-9.2), K2O (0.6-3.3), and (in ppm) Ni (317-1096), Co (25-79), Zr (100-169), Rb (18-107), and Ba (459-1092) display wide

Late Carboniferous to Early Permian magmatic pulses in the Uliastai continental margin linked to slab rollback: Implications for evolution of the Central Asian Orogenic Belt

NASA Astrophysics Data System (ADS)

Chai, Hui; Wang, Qingfei; Tao, Jixiong; Santosh, M.; Ma, Tengfei; Zhao, Rui

2018-05-01

varying from 324 to 673 Ma. The fourth magmatic pulse is represented by K-feldspar granite with zircon U-Pb ages from 283.2 ± 1.9 Ma to 280.0 ± 1.4 Ma, and typical alkalic A-type granite geochemistry. These rocks possess positive εHf (t) values in the range of 9.7 to15.2, and a restricted range of Hf model age from 327 to 684 Ma. The magmatic rocks from the four stages show comparable εHf (t) and T2DM, suggesting that the magmas were derived from the same evolving mantle-derived source. We propose a tectonic model linking the evolution of the magmatism with the closure of the Paleo Asian Ocean that involved the following stages. The andesites were formed during the initial oceanic subduction stage with magma sourced from the metasomatized lithospheric mantle. Stage 2 adakite-like rocks were derived from subduction-induced thickened crust. Subsequent slab rollback resulted in asthenospheric upwelling and melting of residual juvenile crust to generate the I- and A- type syenogranite, rhyolite and dacite suite, finally followed by the A-type K-feldspar granite.

Ultraviolet complex refractive index of Martian dust Laboratory measurements of terrestrial analogs

NASA Technical Reports Server (NTRS)

Egan, W. G.; Hilgeman, T.; Pang, K.

1975-01-01

The optical complex index of refraction of four candidate Martian surface materials has been determined between 0.185 and 0.4 microns using a modified Kubelka-Munk scattering theory. The cadidate materials were limonite, andesite, montmorillonite, and basalt. The effect of scattering has been removed from the results. Also presented are diffuse reflection and transmission data on these samples.

Volatile Abundances and Magma Geochemistry of Recent (2006) Through Ancient Eruptions (Less Than 2100 aBP) of Augustine Volcano, Alaska

NASA Astrophysics Data System (ADS)

Webster, J. D.; Mandeville, C. W.; Gerard, T.; Goldoff, B.; Coombs, M. L.

2006-12-01

Augustine Volcano, Cook Inlet, Alaska, is a subduction-related Aleutian arc volcano located approximately 275 km southwest of Anchorage. During the past 200 years, Augustine volcano has shown explosive eruptive behavior seven times, with the most recent activity occurring in January through March 2006. Its ash and pumice eruptions pose a threat to commercial air traffic, the local fishing industry, and the inhabitants of the region. Following prior investigations on volatile abundances and processes of evolution for magmas associated with the 1976 (Johnston, 1978) and 1986 (Roman et al., 2005) eruptions of Augustine, we have analyzed phenocrysts, matrix glasses, and silicate melt inclusions in andesites formed during 5 pre-historic eruptions (ranging from 2100 to 1000 years in age) as well as the 1986 and recent 2006 eruptions. Outcrops of basaltic units on Augustine are rare, and basaltic melt inclusions are as well, so most melt inclusions studied range from andesitic to rhyolitic compositions. Comparison of the volatile abundances in felsic melt inclusion glasses shows few differences in H2O, CO2, S, and Cl, respectively, between eruptive materials of the pre- historic, 1976 (Johnston, 1978), and 1986 (Roman et al., 2005; our data) events. The magmas associated with these eruptions contained 1.6 to 8.0 wt.% H2O with 0.21 to 0.84 wt.% Cl, 100 to 1800 ppm CO2, and 100 to 400 ppm S. In contrast, preliminary research on rhyodacitic to rhyolitic melt inclusions in a single 2006 andesite sample collected from a lahar deposit indicates they contain somewhat lower H2O contents and higher Cl and S abundances than felsic melt inclusions from prior eruptions, and they exhibit geochemical trends consonant with magma mixing. Relationships involving H2O, CO2, S, and Cl in prehistoric through 1986 melt inclusions are consistent with fluid-saturated magma evolution of andesitic to rhyolitic melt compositions during closed-system ascent. The various batches of magma rose through

Update of map the volcanic hazard in the Ceboruco volcano, Nayarit, Mexico

NASA Astrophysics Data System (ADS)

Suarez-Plascencia, C.; Camarena-Garcia, M. A.; Nunez-Cornu, F. J.

2012-12-01

The Ceboruco Volcano (21° 7.688 N, 104° 30.773 W) is located in the northwestern part of the Tepic-Zacoalco graben. Its volcanic activity can be divided in four eruptive cycles differentiated by their VEI and chemical variations as well. As a result of andesitic effusive activity, the "paleo-Ceboruco" edifice was constructed during the first cycle. The end of this cycle is defined by a plinian eruption (VEI between 3 and 4) which occurred some 1020 years ago and formed the external caldera. During the second cycle an andesitic dome built up in the interior of the caldera. The dome collapsed and formed the internal caldera. The third cycle is represented by andesitic lava flows which partially cover the northern and south-southwestern part of the edifice. The last cycle is represented by the andesitic lava flows of the nineteenth century located in the southwestern flank of the volcano. Actually, moderate fumarolic activity occurs in the upper part of the volcano showing temperatures ranging between 20° and 120°C. Some volcanic high frequency tremors have also been registered near the edifice. Shows the updating of the volcanic hazard maps published in 1998, where we identify with SPOT satellite imagery and Google Earth, change in the land use on the slope of volcano, the expansion of the agricultural frontier on the east sides of the Ceboruco volcano. The population inhabiting the area is 70,224 people in 2010, concentrated in 107 localities and growing at an annual rate of 0.37%, also the region that has shown an increased in the vulnerability for the development of economic activities, supported by highway, high road, railroad, and the construction of new highway to Puerto Vallarta, which is built in the southeast sector of the volcano and electrical infrastructure that connect the Cajon and Yesca Dams to Guadalajara city. The most important economic activity in the area is agriculture, with crops of sugar cane (Saccharum officinarum), corn, and jamaica

Chemical, multispectral, and textural constraints on the composition and origin of rocks at the Mars Pathfinder landing site

USGS Publications Warehouse

McSween, H.Y.; Murchie, S.L.; Crisp, J.A.; Bridges, N.T.; Anderson, R.C.; Bell, J.F.; Britt, D.T.; Brückner, J.; Dreibus, G.; Economou, T.; Ghosh, A.; Golombek, M.P.; Greenwood, J.P.; Johnson, J. R.; Moore, H.J.; Morris, R.V.; Parker, T.J.; Rieder, R.; Singer, R.; Wänke, H.

1999-01-01

Rocks at the Mars Pathfinder site are probably locally derived. Textures on rock surfaces may indicate volcanic, sedimentary, or impact-generated rocks, but aeolian abration and dust coatings prevent unambiguous interpretation. Multispectral imaging has resolved four spectral classes of rocks: gray and red, which occur on different surfaces of the same rocks; pink, which is probably soil crusts; and maroon, which occurs as large boulders, mostly in the far field. Rocks are assigned to two spectral trends based on the position of peak reflectance: the primary spectral trend contains gray, red, and pink rocks; maroon rocks constitute the secondary spectral trend. The spatial pattern of spectral variations observed is oriented along the prevailing wind direction. The primary spectral trend arises from thin ferric coatings of aeolian dust on darker rocks. The secondary spectral trend is apparently due to coating by a different mineral, probably maghemite or ferrihydrite. A chronology based on rock spectra suggests that rounded maroon boulders constitute the oldest petrologic unit (a flood deposit), succeeded by smaller cobbles possibly deposited by impact, and followed by aeolian erosion and deposition. Nearly linear chemical trends in alpha proton X-ray spectrometer rock compositions are interpreted as mixing lines between rock and adhering dust, a conclusion supported by a correlation between sulfur abundance and red/blue spectral ratio. Extrapolations of regression lines to zero sulfur give the composition of a presumed igneous rock. The chemistry and normative mineralogy of the sulfur-free rock resemble common terrestrial volcanic rocks, and its classification corresponds to andesite. Igneous rocks of this composition may occur with clastic sedimentary rocks or impact melts and breccias. However, the spectral mottling expected on conglomerates or breccias is not observed in any APXS-analyzed rocks. Interpretation of the rocks as andesites is complicated by absence

Zircon U-Pb and molybdenite Re-Os geochronology and Sr-Nd-Pb-Hf isotopic constraints on the genesis of the Xuejiping porphyry copper deposit in Zhongdian, Northwest Yunnan, China

NASA Astrophysics Data System (ADS)

Leng, Cheng-Biao; Zhang, Xing-Chun; Hu, Rui-Zhong; Wang, Shou-Xu; Zhong, Hong; Wang, Wai-Quan; Bi, Xian-Wu

2012-10-01

The Xuejiping porphyry copper deposit is located in northwestern Yunnan Province, China. Tectonically, it lies in the southern part of the Triassic Yidun island arc. The copper mineralization is mainly hosted in quartz-dioritic and quartz-monzonitic porphyries which intruded into clastic-volcanic rocks of the Late Triassic Tumugou Formation. There are several alteration zones including potassic, strong silicific and phyllic, argillic, and propylitic alteration zones from inner to outer of the mineralized porphyry bodies. The ages of ore-bearing quartz-monzonitic porphyry and its host andesite are obtained by using the zircon SIMS U-Pb dating method, with results of 218.3 ± 1.6 Ma (MSWD = 0.31, N = 15) and 218.5 ± 1.6 Ma (MSWD = 0.91, N = 16), respectively. Meanwhile, the molybdenite Re-Os dating yields a Re-Os isochronal age of 221.4 ± 2.3 Ma (MSWD = 0.54, N = 5) and a weighted mean age of 219.9 ± 0.7 Ma (MSWD = 0.88). They are quite in accordance with the zircon U-Pb ages within errors. Furthermore, all of them are contemporary with the timing of the Garzê-Litang oceanic crust subduction in the Yidun arc. Therefore, the Xuejiping deposit could be formed in a continental margin setting. There are negative ɛNd(t) values ranging from -3.8 to -2.1 and relatively high initial 87Sr/86Sr ratios from 0.7051 to 0.7059 for the Xuejiping porphyries and host andesites. The (206Pb/204Pb)t, (207Pb/204Pb)t and (208Pb/204Pb)t values of the Xuejiping porphyries and host andesites vary from 17.899 to 18.654, from 15.529 to 15.626, and from 37.864 to 38.52, respectively, indicative of high radiogenic Pb isotopic features. In situ Hf isotopic analyses on zircons by using LA-MC-ICP-MS exhibit that there are quite uniform and slightly positive ɛHf(t) values ranging from -0.2 to +3.2 (mostly between 0 and +2), corresponding to relatively young single-stage Hf model ages from 735 Ma to 871 Ma. These isotopic features suggest that the primary magmas of the Xuejiping porphyries and

Stratigraphy and Petrology of the Grande Soufriere Hills Volcano, Dominica, Lesser Antilles

NASA Astrophysics Data System (ADS)

Daly, G.; Smith, A. L.; Garcia, R.; Killingsworth, N.

2007-12-01

The Grande Soufriere Hills volcanic center is located on the south east coast of the island of Dominica in the Lesser Antilles. Although the volcano is deeply dissected, a distinct circular crater that opens to the east can be observed. Within the crater is a lava dome and unconsolidated pyroclastic deposits mantle the southeast flanks of the volcano. These pyroclastic deposits are almost entirely matrix-supported block and ash flows and surges suggesting that Pelean-style eruptions have dominated its most recent activity. Within this sequence is a relatively thin (30-50 cm) clast-supported deposit that has been interpreted as a possible blast deposit. Two age dates from these younger deposits suggest that much of this activity occurred between l0,000 and 12,000 years ago. On the southeastern coast at Pointe Mulâtre and extending approximately 4 km north and at a maximum 2 km west, is a megabreccia of large (up to 3 m) flow-banded andesite clasts set in a semi-lithified medium grained ash matrix. At Pointe Mulâtre this megabreccia is overlain by unconsolidated block and ash flow deposits. To the north of the megabreccia, exposures in the sea cliffs reveal a consolidated sequence of well-bedded alternating coarse and fine deposits suggesting deltaic foreset beds; which in turn appears to be overlain by a yellow- colored relatively coarse flow deposit with an irregular upper surface. The uppermost deposits in the sea cliffs are a sequence of unconsolidated block and ash flow deposits and interbedded fluviatile conglomerates equivalent to the younger flow deposits logged inland. Volcanic rocks from the Grande Soufriere Hills are all porphyritic andesites often containing hypabyssal inclusions. Dominant phenocrysts are plagioclase often with inclusion-rich cores and well developed zoning. Mafic phenocrysts include hornblende, augite and hypersthene. Geochemically these andesites range from 58- 63% SiO2 and show trends of decreasing values for Al2O3, FeO, MgO, CaO, Ti

Volcanic activity in the Acambay Graben: a < 25 Ka subplinian eruption from the Temascalcingo volcano and implications for volcanic hazard.

NASA Astrophysics Data System (ADS)

Pedrazzi, Dario; Aguirre Díaz, Gerardo; Sunyé Puchol, Ivan; Bartolini, Stefania; Geyer, Adelina

2016-04-01

The Trans-Mexican Volcanic Belt (TMVB) contains a large number of stratovolcanoes, some well-known, as Popocatepetl, Iztaccihuatl, Nevado de Toluca, or Colima and many others of more modest dimensions that are not well known but constitute the majority in the TMVB. Such volcanoes are, for example, Tequila, San Juan, Sangangüey, Cerro Culiacán, Cerro Grande, El Zamorano, La Joya, Palo Huerfano, Jocotitlán, Altamirano and Temascalcingo, among many others. The Temascalcingo volcano (TV) is an andesitic-dacitic stratovolcano located in the Trans-Mexican Volcanic Belt (TMVB) at the eastern part of the Acambay Graben (northwest portion of Estado de México). The TV is composed mainly by dacitic, porphyritic lavas, block and ash deposits and subordinate pumice fall deposits and ignimbrites (Roldán-Quintana et al., 2011). The volcanic structure includes a summit caldera that has a rectangular shape, 2.5×3.5 km, with the largest side oriented E-W, parallel to major normal faults affecting the edifice. The San Mateo Pumice eruption is one of the greatest paroxysmal episodes of this volcano with pumice deposits mainly exposed at the scarp of the Acambay-Tixmadeje fault and at the northern and northeastern flanks of TV. It overlies a paleosol dated at 25 Ka. A NE-trending dispersion was obtained from field data covering an area of at least 80 km2. These deposits overlie older lava flows and mud flows and are discontinuously covered and eroded by younger reworked deposits of Temascalcingo volcano. This event represents a highly explosive phase that generated a relatively thick and widespread pumice fallout deposit that may occur again in future eruptions. A similar eruption today would have a significantly impact in the region, overall due to the fact that there has been no systematic assessment of the volcanic hazard in any of the studies that have been conducted so far in the area. So, this is a pending and urgent subject that must be tackled without delay. Financed by

Discriminating assimilants and decoupling deep- vs. shallow-level crystal records at Mount Adams using 238U-230Th disequilibria and Os isotopes

USGS Publications Warehouse

Jicha, B.R.; Johnson, C.M.; Hildreth, W.; Beard, B.L.; Hart, G.L.; Shirey, S.B.; Singer, B.S.

2009-01-01

A suite of 23 basaltic to dacitic lavas erupted over the last 350??kyr from the Mount Adams volcanic field has been analyzed for U-Th isotope compositions to evaluate the roles of mantle versus crustal components during magma genesis. All of the lavas have (230Th/238U) > 1 and span a large range in (230Th/232Th) ratios, and most basalts have higher (230Th/232Th) ratios than andesites and dacites. Several of the lavas contain antecrysts (crystals of pre-existing material), yet internal U-Th mineral isochrons from six of seven lavas are indistinguishable from their eruption ages. This indicates a relatively brief period of time between crystal growth and eruption for most of the phenocrysts (olivine, clinopyroxene, plagioclase, magnetite) prior to eruption. One isochron gave a crystallization age that is ~ 20-25??ka older than its corresponding eruptive age, and is interpreted to reflect mixing of older and juvenile crystals or a protracted period of magma storage in the crust. Much of the eruptive volume since 350??ka consists of lavas that have small to moderate 230Th excesses (2-16%), which are likely inherited from melting of a garnet-bearing intraplate ("OIB-like") mantle source. Following melt generation and subsequent migration through the upper mantle, most Mt. Adams magmas interacted with young, mafic lower crust, as indicated by 187Os/188Os ratios that are substantially more radiogenic than the mantle or those expected via mixing of subducted material and the mantle wedge. Moreover, Os-Th isotope variations suggest that unusually large 230Th excesses (25-48%) and high 187Os/188Os ratios in some peripheral lavas reflect assimilation of small degree partial melts of pre-Quaternary basement that had residual garnet or Al-rich clinopyroxene. Despite the isotopic evidence for lower crustal assimilation, these processes are not generally recorded in the erupted phenocrysts, indicating that the crystal record of the deep-level 'cryptic' processes has been

Metasomatized mantle as the source of Mid-Miocene-Quaternary volcanism in NW-Iranian Azerbaijan: Geochronological and geochemical evidence

NASA Astrophysics Data System (ADS)

Lechmann, Anna; Burg, Jean-Pierre; Ulmer, Peter; Guillong, Marcel; Faridi, Mohammad

2018-04-01

Middle Miocene to Quaternary volcanic rocks cover large areas of the Azerbaijan Province in NW Iran. This study reports two separate age clusters out of 23 new LA-ICP-MS U-Pb zircon ages: (1) Middle Miocene (16.2-10.6 Ma) and (2) Latest Miocene-Late Pleistocene (5.5-0.4 Ma). Major and trace element bulk rock geochemistry and initial Sr, Nd, Pb radiogenic isotope data on the dated rocks provide new constraints on the Mid-Miocene to Quaternary volcanism in this region. The analyses are distributed over a large compositional range from low-K to high-K calc-alkaline andesites and dacites/rhyolites to more alkaline trachybasalts and dacites with shoshonitic affinities. Chondrite-normalized REE patterns are steep with significant enrichment in LREE and low abundances of HREE indicating a garnet control. Plots of primitive mantle-normalized trace elements show negative Ti and Nb-Ta anomalies indicative of an arc signature. The wide compositional range and the ubiquitous presence of an arc signature reveal that the source mantle is heterogeneous and metasomatically altered. Sr, Nd and Pb radiogenic isotope data further point towards an enriched mantle source and/or crustal contamination. Crustal contamination is best recognized by inherited zircon cores, which yield Late Neoproterozoic to Early Cambrian ages typical for the Iranian basement. The occurrence of adakite-like compositions with elevated magnesium numbers, Cr and Ni concentrations argue against a fractionation-driven process but point to a subcrustal origin. Overall, the analyzed lavas show no spatial and temporal relation to a potential subduction zone, confirming the dated volcanics to be post-collisional and not related to singular processes such as slab retreat or delamination of a continuous lower crustal sliver. We propose three hypotheses to explain the reported disparity in distribution, age and composition and favour small-scale sublithospheric convection or incorporation of crustal material into the

Volatile contents of mafic-to-intermediate magmas at San Cristóbal volcano in Nicaragua

NASA Astrophysics Data System (ADS)

Robidoux, P.; Aiuppa, A.; Rotolo, S. G.; Rizzo, A. L.; Hauri, E. H.; Frezzotti, M. L.

2017-02-01

San Cristóbal volcano in northwest Nicaragua is one of the most active basaltic-andesitic stratovolcanoes of the Central American Volcanic Arc (CAVA). Here we provide novel constraints on the volcano's magmatic plumbing system, by presenting the first direct measurements of major volatile contents in mafic-to-intermediate glass inclusions from Holocene and historic-present volcanic activity. Olivine-hosted (forsterite [Fo] < 80; Fo< 80) glass inclusions from Holocene tephra layers contain moderate amounts of H2O (0.1-3.3 wt%) and S and Cl up to 2500 μg/g, and define the mafic (basaltic) endmember component. Historic-present scoriae and tephra layers exhibit more-evolved olivines (Fo69-72) that contain distinctly lower volatile contents (0.1-2.2 wt% H2O, 760-1675 μg/g S, and 1021-1970 μg/g Cl), and represent a more-evolved basaltic-andesitic magma. All glass inclusions are relatively poor in CO2, with contents reaching 527 μg/g (as measured by nanoscale secondary ion mass spectrometry), suggesting pre- to postentrapment CO2 loss to a magmatic vapor. We use results of Raman spectroscopy obtained in a population of small (< 50 μm) inclusions with CO2-bearing shrinkage bubbles (3-12 μm) to correct for postentrapment CO2 loss to bubbles, and to estimate the original minimum CO2 content in San Cristóbal parental melts at 1889 μg/g, which is consistent with the less-CO2-degassed melt inclusions (MI) (> 1500 μg/g) found in Nicaragua at Cerro Negro, Nejapa, and Granada. Models of H2O and CO2 solubilities constrain the degassing pathway of magmas up to 425 MPa ( 16 km depth), which includes a deep CO2 degassing step (only partially preserved in the MI record), followed by coupled degassing of H2O and S plus crystal fractionation at magma volatile saturation pressures from ∼ 195 to < 10 MPa. The variation in volatile contents from San Cristóbal MI is interpreted to reflect (1) Holocene eruptive cycles characterized by the rapid emplacement of basaltic magma

The Weathering of Rocks Under Humid Tropical Conditions.

DTIC Science & Technology

kaolinitic clay, the formation of gibbsite from the kaolinite , and the leaching of silica and iron-oxides. (Modified author abstract)...rhyolitic to andesitic lavas, tuffs and granophyre, under warm humid climatic conditions. The dominant minerals in the bauxite deposits are gibbsite ... kaolinite , quartz (also chalcedony), goethite, and hematite. The occurrence of bauxite is determined primarily by the parent rocks, which are typically fine

Universal calibration of Raman spectroscopy for the analysis of volatiles in glasses of variable composition

NASA Astrophysics Data System (ADS)

Schiavi, Federica; Bolfan-Casanova, Nathalie

2017-04-01

The amount and distribution of volatiles (water, carbon dioxide …) in magmas represent key parameters for the understanding of magma processes and dynamics within volcanic plumbing systems. Micro-Raman spectroscopy is an excellent technique for accurate determination of volatile contents in magmas, as it combines several advantages. The technique is non-destructive and requires minimal sample preparation before the analysis. Its high lateral and in-depth spatial resolution is crucial for the study of small objects and samples that are chemically and texturally heterogeneous at the small scale (microns). Moreover, the high confocality allows analysis of sample regions not exposed to the surface and 3D mapping. We present a universal calibration of Raman spectroscopy for quantification of volatiles in silicate glasses. The proposed method is based on internal calibration, i.e., on the correlation between the glass water content and the ratio between the areas of the water and silicate Raman bands. Synthetic glasses with variable major element compositions (basaltic, andesitic, rhyolitic, dacitic ..) bearing different H2O (up to 7 wt%) and CO2 contents are used as standard glasses. Natural silicate glasses, mainly in the form of melt inclusions, are used to test the goodness of the proposed method. In addition to quantification of volatiles in glass, in bubble-bearing melt inclusions we perform micro-Raman spectroscopy investigation of gas-bearing bubbles for accurate determination of total volatile contents in melt inclusions.

Phase-equilibrium geobarometers for silicic rocks based on rhyolite-MELTS. Part 4: Plagioclase, orthopyroxene, clinopyroxene, glass geobarometer, and application to Mt. Ruapehu, New Zealand

NASA Astrophysics Data System (ADS)

Harmon, Lydia J.; Cowlyn, James; Gualda, Guilherme A. R.; Ghiorso, Mark S.

2018-01-01

A new phase equilibria geobarometer determines magmatic storage and crystallization conditions, including pressure, temperature, oxygen fugacity ({f_{{{o}_2}}}), and the presence of a fluid phase for glass-bearing rocks containing the assemblage plagioclase + pyroxene(s). This newly developed geobarometer can better constrain crystallization conditions of shallow (< 500 MPa; < 20 km), glass-bearing andesites to dacites. The geobarometer utilizes rhyolite-MELTS to determine crystallization conditions in natural pumice and scoria samples. The validity of the geobarometer is tested by comparing it to results from experiments. Uncertainties are assessed using Monte Carlo simulations. We apply the geobarometer to the plag + opx + cpx-bearing system of Mt. Ruapehu, in the southern Taupo Volcanic Zone, New Zealand. The samples from Mt. Ruapehu are tested from 5 to 400 MPa and from super-liquidus to 90% crystalline ( 1200 to 700 °C). Mt. Ruapehu serves as a methodological testing ground for the geobarometer, and results from our geobarometer agree with recent Mt. Ruapehu studies. Results show a distribution of crystallization pressures ranging from 50 to 150 MPa ( 2.0 to 5.9 km) for different eruptions, with modes of 110 MPa ( 4.3 km) and 130 MPa ( 5.1 km). These are consistent with field interpretations of different eruptive styles based on juvenile clast textures and previous knowledge of the magma plumbing system. Mt. Ruapehu magmas are fluid saturated, with {f_{{{o}_2}}} of ΔQFM + 1 (NNO).

Geology and geothermal potential of the tecuamburro volcano area, Guatemala

USGS Publications Warehouse

Duffield, W.A.; Heiken, G.H.; Wohletz, K.H.; Maassen, L.W.; Dengo, G.; McKee, E.H.; Castaneda, O.

1992-01-01

Tecuamburro, an andesitic stratovolcano in southeastern Guatemala, is within the chain of active volcanoes of Central America. Though Tecuamburro has no record of historic eruptions, radiocarbon ages indicate that eruption of this and three other adjacent volcanoes occurred within the past 38,300 years. The youngest eruption produced a dacite dome. Moreover, powerful steam explosions formed a 250 m wide crater about 2900 years ago near the base of this dome. The phreatic crater contains a pH-3 thermal lake. Fumaroles are common along the lake shore, and several other fumaroles are located nearby. Neutral-chloride hot springs are at lower elevations a few kilometers away. All thermal manifestations are within an area of about 400 km2 roughly centered on Tecuamburro Volcano. Thermal implications of the volume, age, and composition of the post-38.3 ka volcanic rocks suggest that magma, or recently solidified hot plutons, or both are in the crust beneath these lavas. Chemical geothermometry carried out by other workers suggests that a hydrothermal-convection system is centered over this crustal heat source. Maximum temperatures of about 300??C are calculated for samples collected in the area of youngest volcanism, whereas samples from outlying thermal manifestations yield calculated temperatures <- 165??C. An 808 m deep drill hole completed in 1990 to partly test the geothermal model developed from surface studies attained a maximum temperature of almost 240??C. Thus, the possibility of a commercial-grade hydrothermal resource in the area seems high. ?? 1992.

Quaternary silicic pyroclastic deposits of Atitlán Caldera, Guatemala

USGS Publications Warehouse

Rose, William I.; Newhall, Christopher G.; Bornhorst, Theodore J.; Self, Stephen

1987-01-01

Atitlán caldera has been the site of several silicic eruptions within the last 150,000 years, following a period of basalt/andesite volcanism. The silicic volcanism began with 5–10 km3 of rhyodacites, erupted as plinian fall and pyroclastic flows, about 126,000 yr. B.P. At 85,000 yr. B.P. 270–280 km3 of compositionally distinct rhyolite was erupted in the Los Chocoyos event which produced widely dispersed, plinian fall deposits and widespread, mobile pyroclastic flows. In the latter parts of this eruption rhyodacite and minor dacite were erupted which compositionally resembled the earliest silicic magmas of the Atitlán center. As a result of this major eruption, the modern Atitlán (III) caldera formed. Following this event, rhyodacites were again erupted in smaller (5–13 km3) volumes, partly through the lake, and mafic volcanism resumed, forming three composite volcanoes within the caldera. The bimodal mafic/silicic Atitlán volcanism is similar to that which has occurred elsewhere in the Guatemalan Highlands, but is significantly more voluminous. Mafic lavas are thought to originate in the mantle, but rise, intrude and underplate the lower crust and partly escape to the surface. Eventually, silicic melts form in the crust, possibly partly derived from underplated basaltic material, rise, crystallize and erupt. The renewed mafic volcanism could reflect either regional magmato-tectonic adjustment after the large silicic eruption or the onset of a new cycle.

Sulfur Metabolizing Microbes Dominate Microbial Communities in Andesite-Hosted Shallow-Sea Hydrothermal Systems

PubMed Central

Zhang, Yao; Zhao, Zihao; Chen, Chen-Tung Arthur; Tang, Kai; Su, Jianqiang; Jiao, Nianzhi

2012-01-01

To determine microbial community composition, community spatial structure and possible key microbial processes in the shallow-sea hydrothermal vent systems off NE Taiwan’s coast, we examined the bacterial and archaeal communities of four samples collected from the water column extending over a redoxocline gradient of a yellow and four from a white hydrothermal vent. Ribosomal tag pyrosequencing based on DNA and RNA showed statistically significant differences between the bacterial and archaeal communities of the different hydrothermal plumes. The bacterial and archaeal communities from the white hydrothermal plume were dominated by sulfur-reducing Nautilia and Thermococcus, whereas the yellow hydrothermal plume and the surface water were dominated by sulfide-oxidizing Thiomicrospira and Euryarchaeota Marine Group II, respectively. Canonical correspondence analyses indicate that methane (CH4) concentration was the only statistically significant variable that explains all community cluster patterns. However, the results of pyrosequencing showed an essential absence of methanogens and methanotrophs at the two vent fields, suggesting that CH4 was less tied to microbial processes in this shallow-sea hydrothermal system. We speculated that mixing between hydrothermal fluids and the sea or meteoric water leads to distinctly different CH4 concentrations and redox niches between the yellow and white vents, consequently influencing the distribution patterns of the free-living Bacteria and Archaea. We concluded that sulfur-reducing and sulfide-oxidizing chemolithoautotrophs accounted for most of the primary biomass synthesis and that microbial sulfur metabolism fueled microbial energy flow and element cycling in the shallow hydrothermal systems off the coast of NE Taiwan. PMID:22970260

Sulfur metabolizing microbes dominate microbial communities in Andesite-hosted shallow-sea hydrothermal systems.

PubMed

Zhang, Yao; Zhao, Zihao; Chen, Chen-Tung Arthur; Tang, Kai; Su, Jianqiang; Jiao, Nianzhi

2012-01-01

To determine microbial community composition, community spatial structure and possible key microbial processes in the shallow-sea hydrothermal vent systems off NE Taiwan's coast, we examined the bacterial and archaeal communities of four samples collected from the water column extending over a redoxocline gradient of a yellow and four from a white hydrothermal vent. Ribosomal tag pyrosequencing based on DNA and RNA showed statistically significant differences between the bacterial and archaeal communities of the different hydrothermal plumes. The bacterial and archaeal communities from the white hydrothermal plume were dominated by sulfur-reducing Nautilia and Thermococcus, whereas the yellow hydrothermal plume and the surface water were dominated by sulfide-oxidizing Thiomicrospira and Euryarchaeota Marine Group II, respectively. Canonical correspondence analyses indicate that methane (CH(4)) concentration was the only statistically significant variable that explains all community cluster patterns. However, the results of pyrosequencing showed an essential absence of methanogens and methanotrophs at the two vent fields, suggesting that CH(4) was less tied to microbial processes in this shallow-sea hydrothermal system. We speculated that mixing between hydrothermal fluids and the sea or meteoric water leads to distinctly different CH(4) concentrations and redox niches between the yellow and white vents, consequently influencing the distribution patterns of the free-living Bacteria and Archaea. We concluded that sulfur-reducing and sulfide-oxidizing chemolithoautotrophs accounted for most of the primary biomass synthesis and that microbial sulfur metabolism fueled microbial energy flow and element cycling in the shallow hydrothermal systems off the coast of NE Taiwan.

Investigation of Along-Arc Geochemical Variations in the Southern Volcanic Zone: Azufre-Planchon-Peteroa Volcanic Complex, Southern Chile

NASA Astrophysics Data System (ADS)

Holbik, S. P.; Hickey-Vargas, R.; Tormey, D.

2012-12-01

The Andean Southern Volcanic Zone (SVZ) is a vast and complex continental arc that has been studied extensively to provide an understanding of arc-magma genesis, the origin and chemical evolution of the continental crust, and geochemical compositions of volcanic products. This study focuses on volcanic rocks from the Azufre-Planchon-Peteroa (APP 35°15'S) volcanic complex, within the Transitional SVZ (34.3-37.0 °S), where crustal thickness increases from approximately 30 km in the south (Central SVZ), to 55 km in the north (Northern SVZ). Planchon is the northernmost volcano in the SVZ to erupt basaltic products, while Peteroa is the currently active cone, erupting tephra of andesitic composition, most recently in September of 2011. New data for the APP are consistent with the hypothesis of Tormey et al. (1995) that the APP experienced variable depths of crystal fractionation, and that crustal assimilation at Planchon is restricted to the lower crustal depths, as reflected by limited variability in 87Sr/86Sr isotopes. New δ18O data (26.5‰) from an outcropping dolomitic limestone country rock in the vicinity of the Azufre volcano also confirms the upper crustal source of anomalously high (7.1 and 7.3‰) oxygen isotopic values for Azufre dacites. A trend of high La/Yb (6.5-9.1) and Yb depletion with increasing La/Yb for Planchon basalts is consistent with the role of garnet as a residual or crystallizing phase at lower crustal depths, however, the La/Yb range is small when compared to published data from nearby TSVZ centers such as Nevado de Longavi (La/Yb = 5.5 to 16.7) and San Pedro Pellado (La/Yb =7.2 to 13.6). Geochemical modeling of the Planchon data shows that both hornblende and garnet must be involved in the magmatic evolution, even though erupted basalts are free of major hydrous phases, in order to account for the more limited range of La/Yb. Interestingly, baseline values of La/Yb for basalt and basaltic andesites from throughout the TSVZ, including

U-series in zircon and 40Ar/39Ar geochronology reveal the most recent stage of a supervolcanic cycle in the Altiplano-Puna Volcanic Complex, Central Andes

NASA Astrophysics Data System (ADS)

Tierney, C.; de Silva, S. L.; Schmitt, A. K.; Jicha, B.; Singer, B. S.

2010-12-01

The ignimbrite flare up that produced the Altiplano-Puna Volcanic Complex of the Central Andes is characterized by episodic supervolcanism over a ~10 Ma time-span that climaxed about 4Ma. Since peak activity, the temporal and spatial record of volcanism suggests a waning of the system with only one other supervolcanic eruption at 2.6Ma. The most recent phase of volcanism from the APVC comprises a series of late Pleistocene domes that share a general petrochemical resemblance to the ignimbrites. New U-series data on zircons and high precision 40Ar/39Ar age determinations reveal that these effusive eruptions represent a temporally coherent magmatic episode. The five largest domes (Chao, Chillahuita, Chanka, Chascon-Runtu Jarita, and Tocopuri) have a combined volume >40 km3, and are distributed over an elliptical area of over 3000km2 centered at 22°S 68°W. They are crystal rich (>50%) dacites to rhyolites. New 40Ar/39Ar age determinations on biotite for the domes range range from 108±6 to 190±50 ka. However, 40Ar/39Ar ages from sanidine for some of the domes are more precise and span from 87±4 to 97±2 ka. We therefore interpret the eruption age of all these domes to be ~90 - 100 ka. This is consistent with SIMS U-series crystallization ages from the rims of 66 zircon crystals from four of the domes that reveal a fairly continuous spread of ages from ~90 ka to >300 ka with potentially common peaks in zircon ages at 100 ka and ~200 ka. U-Pb dating on the interiors of some of these zircon crystals indicates crystallization ages of up to 1.5 Ma. The common peaks of zircon crystallization between domes suggest that magma that fed these domes shared a larger regional source. Furthermore, the large volume of this potential source and the crystal-rich nature of the lava imply that this source was likely a large body of crystal-mush. The continuous nature of the zircon rim age population indicates that the residence time of this magma body was likely >200kyr. Potential

The deep layers of a Paleozoic arc: geochemistry of the Copley-Balaklala series, northern California

NASA Astrophysics Data System (ADS)

Brouxel, Marc; Lapierre, Henriette; Michard, Annie; Albarède, Francis

1987-10-01

REE, Zr, Nb concentrations and Sr, Nd isotope compositions have been measured in Copley basalts and andesites, Balaklala rhyolites, and Mule Mountain trondhjemites (northern California) which represent the deep layers of a well preserved intra-oceanic island arc of Siluro-Devonian age. 87Sr/ 86Sr is shifted towards high values (up to 0.707) whereas Ce is preferentially removed from rhyolites. A large proportion of the analyzed samples including some acidic rocks shows a pronounced depletion in light REE. The ɛ Nd(T) values of most Copley, Balaklala, and Mule Mountain rocks fall in the range +6 to +8 which suggests that they originated from a normal MORB-type source ( ɛ Nd(T) ≈ +9 ) contaminated with either sediments or an OIB-type component. In modern island arcs, only the shallow levels are accessible: comparison with the Copley-Balaklala-Mule Mountain Series suggests that, at depth, an immature island arc is likely to comprise thick layers of LILE-depleted tholeiites and rhyolites intensely altered by pervasive circulation of seawater. Least-square solutions of trace element models suggest that rhyolites and trondhjemites represent remelting of mafic volcanics from the arc basement rather than residual melts of basalt-andesite differentiation.

Earth's early O2 cycle suppressed by primitive continents

NASA Astrophysics Data System (ADS)

Smit, Matthijs A.; Mezger, Klaus

2017-10-01

Free oxygen began to accumulate in Earth's surface environments between 3.0 and 2.4 billion years ago. Links between oxygenation and changes in the composition of continental crust during this time are suspected, but have been difficult to demonstrate. Here we constrain the average composition of the exposed continental crust since 3.7 billion years ago by compiling records of the Cr/U ratio of terrigenous sediments. The resulting record is consistent with a predominantly mafic crust prior to 3.0 billion years ago, followed by a 500- to 700-million-year transition to a crust of modern andesitic composition. Olivine and other Mg-rich minerals in the mafic Archaean crust formed serpentine minerals upon hydration, continuously releasing O2-scavenging agents such as dihydrogen, hydrogen sulfide and methane to the environment. Temporally, the decline in mafic crust capable of such process coincides with the first accumulation of O2 in the oceans, and subsequently the atmosphere. We therefore suggest that Earth's early O2 cycle was ultimately limited by the composition of the exposed upper crust, and remained underdeveloped until modern andesitic continents emerged.

Crystallisation regimes and kinetics in experimentally decompressed dacitic magma

NASA Astrophysics Data System (ADS)

Blum-Oeste, N.; Schmidt, B. C.; Webb, S. L.

2011-12-01

Kinetic processes during magma ascent may have a strong influence on the eruption style. In water bearing dacitic magmas decompression induced exsolution of water and accompanying crystallisation of plagioclase are the main processes which drive the system towards a new equilibrium state. We present new data on the evolution of residual glass composition and crystal size distributions of plagioclase from decompression experiments. Experiments have been conducted in cold seal pressure vessels at 850°C on a natural dacite composition from Taapaca volcano (N. Chile). After an initial equilibration at 2kbar decompression rates between 6.3 and 450bar/h were applied to final pressures between 50 and 1550bar where samples were rapidly quenched. Complementary equilibrium experiments were done at corresponding pressures. The glass composition evolves from the initial state towards the equilibrium at the final pressure. The completeness of this re-equilibration depends on run duration and reaction rates. We introduce the "re-equilibration index" (REI), a fraction between 0 (initial state) and 1 (final state) which allows comparison of chemical components in terms of re-equilibration at different decompression rates. REI divided by the decompression duration gives the "re-equilibration rate" (RER). The REI varies among oxides and it decreases with increasing decompression rate. The highest REIs of ~0.9 have been found for MgO, K2O and Al2O3 at 6.3bar/h whereas Na2O shows the lowest number with 0.25 at this decompression rate. Towards faster decompression all REIs tend to decrease which shows a decreasing completeness of re-equilibration. At 450bar/h the highest REIs are ~0.25. RERs increase from below ~0.005/h at 6.3bar/h up to almost 0.08/h for Al2O3 at 450bar/h. The variability of RERs of different oxides also increases with decompression rates. At 450bar/h the RERs reach from <0.005/h up to 0.08/h. Although RERs strongly increase from low to high decompression rates, this

40Ar/39Ar geochronology of hypabyssal igneous rocks in the Maranon Basin of Peru - A record of thermal history, structure, and alteration

USGS Publications Warehouse

Prueher, L.M.; Erlich, R.; Snee, L.W.

2005-01-01

Hypabyssal andesites and dacites from the Balsapuerto Dome in the Mara?on Basin of Peru record the thermal, tectonic, and alteration history of the area. The Mara?on Basin is one of 19 sub-Andean foreland basins. The hypabyssal rocks in the Balsapuerto Dome are one of four known occurrences of subvolcanic rocks along the deformation front in Peru. This dome is a potential petroleum structural trap. Petroleum seeps near the dome indicate that a source for the petroleum is present, but the extent and amount of petroleum development is unknown. The Balsapuerto hypabyssal rocks are plagioclase-, hornblende-, pyroxene-phyric andesites to dacites. Some parts of the dome are pervasively altered to a hydrothermal assemblage of quartz-sericite-pyrite. 40Ar/39Ar geochronology shows that thermal activity related to emplacement of these subvolcanic rocks took place between 12-10 Ma, subsequent to the major periods of Andean folding and faulting, previously assumed to have occurred about 9 Ma. Eleven argon mineral age-spectrum analyses were completed. Argon apparent ages on amphibole range from 12.7 to 11.6 Ma, and the age spectra are simple, which indicates that the ages are very close to emplacement ages. Potassium feldspar yields an argon age spectrum ranging in age from 12.5 to 11.4 Ma, reflecting the period during which the potassium feldspar closed to argon diffusion between the temperature range of 350?C to about 150?C; thus the potassium feldspar age spectrum reflects a cooling profile throughout this temperature range. This age range is consistent with ages of emplacement for the entire igneous complex indicating that an increased thermal state existed in the area for at least 1.0 m.y. Combined with the coexisting hornblende age, this rock cooled from ~580?C to ~150?C in ~1.2 m.y. resulting in an average cooling rate of 358?C /m.y. White mica, or sericite, formed as a later alteration phase associated with quartz- sericite- pyrite and propylitic alteration in some

Major and trace element, and Sr isotope compositions of clinopyroxene phenocrysts in mafic dykes on Jiaodong Peninsula, southeastern North China Craton: Insights into magma mixing and source metasomatism

NASA Astrophysics Data System (ADS)

Liang, Yayun; Deng, Jun; Liu, Xuefei; Wang, Qingfei; Qin, Cheng; Li, Yan; Yang, Yi; Zhou, Mian; Jiang, Jieyan

2018-03-01

Early Cretaceous mafic dyke swarms are widely developed on Jiaodong Peninsula in the southeastern part of the North China Craton (NCC), but their petrogenesis remains enigmatic. We have examined the in-situ major element, trace element and Sr isotope compositions of the clinopyroxene phenocrysts in these dykes in order to evaluate the extent of magma mixing and source metasomatism. Depending on the type of mineral zoning, the clinopyroxene phenocrysts in our samples can be classified into two groups: Group I (reverse zoning) and Group II (no zoning). Based on core compositions, the Group I phenocrysts with obvious reverse zoning can be divided into two subgroups: Groups IA and IB. The cores of Group IA clinopyroxenes have low values of Mg#, low Al2O3 contents, high Na2O contents, and high 87Sr/86Sr ratios, and they were probably derived from newly accreted lower crust that formed through the underplating of basaltic magma. In contrast, the cores of Group IB clinopyroxenes have lower Mg# values and lower contents of Al2O3, ΣREE (total rare earth elements), and incompatible elements, but they have similar 87Sr/86Sr ratios; these cores crystallised from crust-derived andesitic-dacitic magma. Group IA and IB clinopyroxene phenocryst rims (Group I rims) all have similar compositions with higher values of Mg# and higher Al2O3, Cr and Ni contents than the cores. The rims have high 87Sr/86Sr ratios, are enriched in LREEs (light rare earth elements) and LILEs (large ion lithophile elements), and are depleted in HFSEs (high field strength elements); these characteristics indicate that all the high-Mg rims were derived from a similar magma, possibly a relatively primitive magma derived from lithospheric mantle. We suggest, therefore, that the reversely-zoned clinopyroxene phenocrysts (Group I) in the Jiaodong mafic dykes provide evidence of magma mixing between a magma derived from lithospheric mantle and crust-derived andesitic-dacitic melt alongside with the newly accreted

Soil organic carbon and nitrogen pools drive soil C-CO2 emissions from selected soils in Maritime Antarctica.

PubMed

Pires, C V; Schaefer, C E R G; Hashigushi, A K; Thomazini, A; Filho, E I F; Mendonça, E S

2017-10-15

The ongoing trend of increasing air temperatures will potentially affect soil organic matter (SOM) turnover and soil C-CO 2 emissions in terrestrial ecosystems of Maritime Antarctica. The effects of SOM quality on this process remain little explored. We evaluated (i) the quantity and quality of soil organic matter and (ii) the potential of C release through CO 2 emissions in lab conditions in different soil types from Maritime Antarctica. Soil samples (0-10 and 10-20cm) were collected in Keller Peninsula and the vicinity of Arctowski station, to determine the quantity and quality of organic matter and the potential to emit CO 2 under different temperature scenarios (2, 5, 8 and 11°C) in lab. Soil organic matter mineralization is low, especially in soils with low organic C and N contents. Recalcitrant C form is predominant, especially in the passive pool, which is correlated with humic substances. Ornithogenic soils had greater C and N contents (reaching to 43.15gkg -1 and 5.22gkg -1 for total organic carbon and nitrogen, respectively). C and N were more present in the humic acid fraction. Lowest C mineralization was recorded from shallow soils on basaltic/andesites. C mineralization rates at 2°C were significant lower than at higher temperatures. Ornithogenic soils presented the lowest values of C-CO 2 mineralized by g of C. On the other hand, shallow soils on basaltic/andesites were the most sensitive sites to emit C-CO 2 by g of C. With permafrost degradation, soils on basaltic/andesites and sulfates are expected to release more C-CO 2 than ornithogenic soils. With greater clay contents, more protection was afforded to soil organic matter, with lower microbial activity and mineralization. The trend of soil temperature increases will favor C-CO 2 emissions, especially in the reduced pool of C stored and protected on permafrost, or in occasional Histosols. Copyright © 2016 Elsevier B.V. All rights reserved.

Microbiology of Low Temperature Seafloor Deposits Along a Geochemical Gradient in Lau Basin

NASA Astrophysics Data System (ADS)

sylvan, J. B.; Sia, T. Y.; Haddad, A.; Briscoe, L. J.; Girguis, P. R.; Edwards, K. J.

2011-12-01

The East Lau Spreading Center (ELSC) and Valu Fa Ridge comprise a ridge segment in the southwest Pacific Ocean where rapid transitions in the underlying mantle lenses manifest themselves by gradients in seafloor rock geochemistry. At the spreading center in the north, basaltic host rock extrudes while the influence of subduction in the south creates mainly basaltic andesite host rock. A contuous gradient between these two end members exists along the spreading center. We studied the geology and microbial diversity of three silicate rock samples and three inactive sulfide chimney samples collected along the ELSC and Valu Fa Ridge by X-ray diffraction, elemental analysis, thin section analysis and construction of bacterial 16S rRNA clone libraries. Here, we discuss the geological and biological differences between the collected rocks. We found that the bacterial community composition changed as the host rock mineralogy and chemistry changed from north to south. Also, the bacterial community composition on the silicates is distinct from those on the inactive chimneys, and the interior conduit of an inactive chimney hosts a very different community from the exterior. Basalt from the northern end of the ELSC had high proportions of Alphaproteobacteria and Bacteroidetes. These proportions decreased on the silicates collected further south. Epsilonproteobacteria were also present on the basalt, decreased further south and were absent on the basaltic andesite. Conversely, basaltic andesite rocks from the southern end had high proportions of Chloroflexi, which decreased further north and were absent on basalt. The exterior of inactive sulfide structures were dominated by lineages of sulfur oxidizing Gammaproteobacteria and Epsilonproteobacteria and were less diverse than those on the silicates. The interior of one chimney was dominated by sulfate-reducing Deltaproteobacteria and was the least diverse of all samples. These results support the Mantle to Microbe hypothesis in

A geological and geochemical reconnaissance of the Tathlith one-degree quadrangle, sheet 19/43, Kingdom of Saudi Arabia

USGS Publications Warehouse

Overstreet, William C.

1978-01-01

The Tathlith one-degree quadrangle occupies an area of 11,620 sq km in the northeastern Asir region of the Kingdom of Saudi Arabia, in the southeastern part of the Precambrian shield. In the eastern part of the quadrangle the Precambrian rocks are covered by exposures of easterly-dipping sandstone of Cambrian or Ordovician age. A well-developed and highly integrated drainage system trending northward is worn into the Precambrian rocks, but for most of the year the wadis are dry. The Precambrian rocks of the quadrangle consist of an old, non-metamorphosed to variably metamorphosed sequence of volcanic and sedimentary rocks intruded by three main successions of plutonic and hypabyssal igneous rocks. The interlayered volcanic and sedimentary rocks occupy arcuate, north-trending fold belts in which old, rather tight north-trending folds have been refolded at least once by open folds with nearly east-trending axes. Old, north-trending left-lateral faults are associated with the fold belts and are themselves intersected by younger, northwest-trending faults. Motion on both sets of faults has been reactivated several times. The interlayered volcanic and sedimentary rocks are an eugeosynclinal sequence of graywacke and andesite with sparse marble, quartzite, and rhyolite. Andesite is the dominant component of the sequence. Plutonic or hypabyssal equivalents of the andesite intrude the volcanic-sedimentary sequence. In many places these rocks are essentially non-metamorphosed, but elsewhere they are faintly to strongly metamorphosed, or even polymetamorphosed. Dynamothermal metamorphism associated with the northerly folding, and contact metamorphism are the principal kinds of metamorphism. The metamorphic grade is mostly greenschist facies or albite-epidote amphibolite facies. The largest intrusive in the area is a batholith of regional dimension, the east side of which intrudes and divides the fold belts. Granite gneiss and granodiorite gneiss are the main components of

Mineralogy of Copper-Gold Deposit, Masjid Daghi Area, Jolfa, IRAN

NASA Astrophysics Data System (ADS)

Zenoozi, Roya

2010-05-01

The Copper-Gold deposit of Masjid Daghi area is located in the Jolfa quadrangle (scale 1:100,000), East Azerbaijan Province, north-west Iran. The deposit, hosting by sub-volcanic bodies comprise of quartz monzonite composition whose intruded the Tertiary volcanic and volcanic-sedimentary rocks and turbidities. The Tertiary volcanic rocks consist of andesite, trachy andesite and quartz andesite. These mineral-bearing bodies related to Late Eocene sub-volcanic activities which intrudded the Eocene volcanic rocks. Mineralography, XRD and SEM studies showed that the variations in mineralization of the area. The main agent of mineralization is the intrusion of Late Eocene sub volcanic bodies inside the Tertiary volcanic units. The mineralography studies revealed two main groups of mineralization as oxides and sulfides. The sulfide minerals formed as veins, vein lets and stock work.The economic minerals comprise of native gold, copper sulfides. The native gold occurring in siliceous veins and almost as inclusions inside the sulfides minerals such as chalcopyrite. The copper sulfides, contain pyrite, chalcopyrite and chalco-pyrrhoyite. Pyrite is main sulfide in the area and formed as disseminations, cavity filling and colloform. The amount of pyrite, chalcopyrite and chalco-pyrrhoyite increases with depth. Supergene alteration produced digenite, covellite, bornite, and malachite. The alteration occurred as potassic, phyllic, argillic and propylitic minerals. Furthermore, selective sercitic, sericitic-chloritic and alunitic alterations are seen around the mineralized veins. The mineralography studies indicate that pyrite is main mineral phase and native gold occurred in silicious vein almost as inclusions inside the sulfide mineral. Most of economic mineral formed as veins, vein lets, disseminated, cavity filling and colloform which related to intrusions of Late Eocene quartz monzonite bodies into the Eocene volcanic rocks and turbiditse. Some types of alterations such as

An Archaean submarine volcanic debris avalanche deposit, Yilgarn Craton, western Australia, with komatiite, basalt and dacite megablocks. The product of dome collapse

NASA Astrophysics Data System (ADS)

Trofimovs, J.; Cas, R. A. F.; Davis, B. K.

2004-11-01

The Boorara Domain of the Kalgoorlie Terrane, Eastern Goldfields Superterrane, western Australia contains excellent exposure of Archaean felsic and ultramafic breccias characterised by facies associations interpreted to reflect a volcanic debris avalanche mode of deposition. Such Archaean volcanic deposits are typically difficult to identify due to poor preservation and exposure. However, primary volcanological and sedimentological features are preserved within the relatively low strain and low metamorphic grade (up to lower greenschist facies) Boorara Domain that allow accurate facies reconstruction. The breccia deposit is characterised by two clast populations. A 'block facies' comprised of metre- to decimetre-scale megablocks of dacite, basalt and komatiite is preserved within a 'mixed' matrix breccia facies of angular, coarse sand- to boulder-sized clasts. The megablocks preserve original stratigraphy and show fracturing and jigsaw-fit textures within the poorly sorted, unstratified, genetically related matrix. Overlying the volcanic debris avalanche deposit, are a series of stratified horizons. These deposits show evidence of hydraulic sorting within bedforms exhibiting normal grain-size grading and tractional scour and fill structures along their basal contacts. The stratified facies is interpreted to have been deposited by high concentration, high competency turbidity currents, triggered by slope stabilization slides in the source region. Primary contacts and volcanic textures preserved in decimetre-scale volcanic blocks allow reconstruction of the pre-collapse palaeovolcanological history of the source region. The volcanic debris avalanche deposit, together with the associated stratified sedimentary horizons, were produced by sector collapse of a submarine, dacitic volcanic dome. Contemporaneous komatiite intrusion into the dacite dome may have caused dome flank instability. However, the volcanic debris avalanche trigger is interpreted to be a post

Early Cretaceous bimodal volcanism in the Duolong Cu mining district, western Tibet: Record of slab breakoff that triggered ca. 108-113 Ma magmatism in the western Qiangtang terrane

NASA Astrophysics Data System (ADS)

Wei, Shao-gang; Tang, Ju-xing; Song, Yang; Liu, Zhi-bo; Feng, Jun; Li, Yan-bo

2017-05-01

We report new zircon U-Pb ages and Hf isotope compositions, and whole-rock major and trace element and Sr-Nd isotope data for the Meiriqiecuo Formation (MF) bimodal volcanic rocks collected from the Duolong Cu mining district (DCMD) in the western Qiangtang terrane (QT), western Tibet. These data provide important constraints on the petrogenetic evolution and geodynamic setting of Early Cretaceous magmatism in the DCMD. The MF bimodal volcanic rocks are mainly basaltic andesite and andesite, with subordinate rhyolite. Four mafic samples yielded zircon U-Pb ages of ca. 108.2-113.0 Ma, and one silicic sample has an age of 109.3 ± 2.2 Ma, indicating that the mafic and silicic eruptions were contemporaneous. The MF bimodal volcanic rocks belong to the medium-K calc-alkaline to shoshonite series. The rocks show arc-type affinities characterized by significant enrichment in light rare earth (LaN/YbN = 7.74-12.60) and large-ion lithophile elements (Rb, Cs, K, and Pb), but depletions in the high-field-strength elements (Nb, Ta, and Ti), which geochemically resemble Andean arc basalts. Therefore, the MF bimodal volcanic rocks were likely emplaced at an Andean-type active continental margin and represent an Early Cretaceous magmatic arc that was located at the western QT margin. Moreover, the mafic volcanic rocks have high initial Sr isotopic ratios (0.705269-0.705413) and negative εNd(t) values of -1.5 to -0.6 compared with the silicic volcanic rocks ((87Sr/86Sr)i = 0.704770-0.704903; εNd(t) = +1.2 to +1.3). Zircons from silicic samples have significantly higher εHf(t) values (+11.6 to +15.5) and predominantly lower Paleoproterozoic Hf crustal model ages (TDMC = 180-428 Ma) than the mafic samples, which have variable εHf(t) values of +3.4 to +13.0 and TDMC ages of 346-952 Ma. These results indicate that the mafic and silicic end-members of the MF bimodal suite were generated from mantle and crustal sources, respectively. The basaltic andesite and andesite may have been

Petrographic and geochemical characterization of the Triassic and Jurassic magmatic and volcanic rocks of southeastern Ecuador

NASA Astrophysics Data System (ADS)

Villares, Fabián; Eguez, Arturo; Yanez, Ernesto

2014-05-01

Formely, the subandean zone in the southeastern Ecuador involved large volcanic and magmatic rocks included in the Misahualli Formation and Zamora batholith, both as expression of the Jurassic cal-alcaline volcanic arc. The aim of the project carried out by the INIGEMM (Instituto Nacional de Investigación Geológico Minero Metalúrgico) was discriminate the volcanic products including a continuous set going from basalts to ryolithes and volcanoclastic rocks. Geochemical characterization was done using representative 16 whole - rock chemical analysis. The oldest rocks of the investigated area called Pachicutza Unit, include greenish to black, massive basalts and basaltic andesites, locally showing pillows structures. The texture is aphanitic to microporphyritic with slight crystal growth of plagioclase and pyroxenes. The Unit include also local pyroclastic breccias and tuffs showing variable skarnification related to the intrusion of the jurassic Zamora Batholith. Two samples of basalts show tholeiitic affinity, corresponding to an N- MORB, probably representing an early stage in opening of a regional Triassic rift reported since Colombia to Peru in the Andes. These geochemical characteristics are similar to the amphibolites of Monte Olivo Unit in the Real Cordillera. The Jurassic large volcanic assembly of the Misahualli Formation was also differenciated. Basal volcanics include green, subporphyritic andesites and volcanic breccias possibly generated at an early stage of the volcanic arc, caused by a change of extensive to compressive regime. Continental volcano sedimentary and sedimentary rock were discriminate as Nueva Esperanza and Suarez Units, respectively. The volcanosedimentary sequence include massive to laminate tuffs and tuffites of intermediate composition. The sediments of the Suarez Unit include dominant conglomerats and sandstones of fluvial domain. The regional volcanic sequence is completed by the Las Peñas Unit that includes aphanitic to

Precambrian tholeiitic-dacitic rock-suites and Cambrian ultramafic rocks in the Pennine nappe system of the Alps: Evidence from Sm-Nd isotopes and rare earth elements

USGS Publications Warehouse

Stille, P.; Tatsumoto, M.

1985-01-01

Major element, trace element and Sm-Nd isotope analyses were made of polymetamorphic hornblendefelses, plagioclase amphibolites and banded amphibolites from the Berisal complex in the Simplon area (Italy, Switzerland) to determine their age, origin and genetic relationships. In light of major and rare earth element data, the hornblendefelses are inferred to have originally been pyroxene-rich cumulates, the plagioclase amphibolites and the dark layers of the banded amphibolites to have been tholeiitic basalts and the light layers dacites. The Sm-Nd isotope data yield isochron ages of 475??81 Ma for the hornblendefelses, 1,018??59 Ma for the plagioclase amphibolites and 1,071??43 Ma for the banded amphibolites. The 1 Ga magmatic event is the oldest one ever found in the crystalline basement of the Pennine nappes. The Sm -Nd isotope data support the consanguinity of the tholeiitic dark layers and the dacitic light layers of the banded amphibolites with the tholeiitic plagioclase amphibolites and the ultramafic hornblendefelses. The initial e{open}Nd values indicate that all three rock types originated from sources depleted in light rare earth elements. We suggest that plagioclase and banded amphibolites were a Proterozoic tholeiite-dacite sequence that was strongly deformed and flattened during subsequent folding. The hornblendefelses are thought to be Cambrian intrusions of pyroxene-rich material. ?? 1985 Springer-Verlag.

3D numerical modelling of negative apparent conductivity anomalies in loop-loop electromagnetic measurements: a case study at a dacite intrusion in Sugisawa, Akita Prefecture, Japan

NASA Astrophysics Data System (ADS)

Selepeng, Ame Thato; Sakanaka, Shin'ya; Nishitani, Tadashi

2017-04-01

Under certain geological conditions, low induction number electromagnetic (LIN-EM) instruments are known to produce negative apparent conductivity (σa) responses. This is particularly the case when the shallow subsurface is characterised by highly conductive bodies, however little attention has been given to this issue in the research literature. To analyse negative σa anomalies and their causative structures, we make use of a 3D integral equation forward modelling technique based on a 3D weighting function. We present 3D numerical modelling results over a volcanic tuff body intruded by several dacite dikes, in Sugisawa, Akita Prefecture, Japan. Apparent conductivity data were acquired using a Geonics EM-34-3 system in the horizontal magnetic dipole (HMD) and vertical magnetic dipole (VMD) operating modes. Our 3D model resolved the horizontal and vertical extent of the dacite dikes and also delineated a high conductive zone between the volcanic tuff and the intrusive dacite dikes. This zone is the causative structure for negative σa responses in the VMD data, and is interpreted to be an alteration zone. Interestingly, the negative σa response was absent when the instrument alignment azimuth was changed, implying an anisotropic effect on the EM signature in the study area. The true conductivity model achieved by 3D forward modelling is shown to compare favourably with the DC resistivity data acquired in the same area.

Precambrian tholeiitic-dacitic rock-suites and Cambrian ultramafic rocks in the Pennine nappe system of the Alps: Evidence from Sm-Nd isotopes and rare earth elements

NASA Astrophysics Data System (ADS)

Stille, P.; Tatsumoto, M.

1985-04-01

Major element, trace element and Sm-Nd isotope analyses were made of polymetamorphic hornblendefelses, plagioclase amphibolites and banded amphibolites from the Berisal complex in the Simplon area (Italy, Switzerland) to determine their age, origin and genetic relationships. In light of major and rare earth element data, the hornblendefelses are inferred to have originally been pyroxene-rich cumulates, the plagioclase amphibolites and the dark layers of the banded amphibolites to have been tholeiitic basalts and the light layers dacites. The Sm-Nd isotope data yield isochron ages of 475±81 Ma for the hornblendefelses, 1,018±59 Ma for the plagioclase amphibolites and 1,071±43 Ma for the banded amphibolites. The 1 Ga magmatic event is the oldest one ever found in the crystalline basement of the Pennine nappes. The Sm -Nd isotope data support the consanguinity of the tholeiitic dark layers and the dacitic light layers of the banded amphibolites with the tholeiitic plagioclase amphibolites and the ultramafic hornblendefelses. The initial ɛ Nd values indicate that all three rock types originated from sources depleted in light rare earth elements. We suggest that plagioclase and banded amphibolites were a Proterozoic tholeiite-dacite sequence that was strongly deformed and flattened during subsequent folding. The hornblendefelses are thought to be Cambrian intrusions of pyroxene-rich material.

Geothermal Potential of Marine Corps Mountain Warfare Training Center at Pickel Meadow, California.

DTIC Science & Technology

1983-05-01

even electrical power generation, since throughout these areas warm wells, hot springs, and warm springs occur. The Pickel Meadow area is U.S. Forest...are Mesozoic granitic and Cretaceous rocks. Warm wells occur at the town of Walker (Antelope Valley), which probably indi- cates that hot water is...These sediments were deposited during tile erosional interval between Oligocene volcanism and late Miocene volcanism. Tile Mio-Pliocene andesitic rocks

Banded iron-formations of late Proterozoic age in the central eastern desert, Egypt: geology and tectonic setting.

USGS Publications Warehouse

Sims, P.K.; James, H.L.

1984-01-01

Iron-formation occurs as stratigraphic units within a layered andesite-basalt sequence. The sequence is metamorphosed to greenschist facies, intruded by syntectonic granodiorite and post-tectonic granite, and complexly deformed and grossly fragmented; the rocks are allochthonous along thrust faults. The iron deposits are chemical precipitates, accumulated during lulls in volcanism, apparently in an intraoceanic island-arc environment. The deposits are of the Algoma type of iron-formation.-G.J.N.

Optical properties of silicates in the far ultraviolet

NASA Technical Reports Server (NTRS)

Lamy, P. L.

1978-01-01

Near-normal incidence reflectance measurements in the interval 1026-1640 A were performed on four silicates already studied in the visible and infrared. A Kramers-Kronig analysis of these data is used to calculate the complex index of refraction m = n - ik. New transmission measurements improve the determination of k in the interval 2500-4500 A, except for andesite, which is more opaque than had been previously observed.

Post-middle Miocene accretion of Franciscan rocks, northwestern California.

USGS Publications Warehouse

McLaughlin, R.J.; Kling, S.A.; Poore, R.Z.; McDougall, K.; Beutner, E.C.

1982-01-01

Deformed sedimentary rocks assigned to the Franciscan assemblage in the King Range S of Cape Mendocino, N California, are dominantly deep-water argillite and sandstone occurring as thick- to thin-bedded, locally channelized marine turbidities of arkosic to andesitic volcaniclastic composition. The King Range appears to be a displaced terrane of oceanic basement overlain by Palaeogene(?) and Neogene sedimentary and igneous rocks of continental and oceanic derivation.-Authors

Geology, age, and tectonic setting of the Cretaceous Sliderock Mountain Volcano, Montana

USGS Publications Warehouse

Du Bray, E.A.; Harlan, Stephen S.

1998-01-01

The Sliderock Mountain stratovolcano, part of the Upper Cretaceous continental magmatic arc in southwestern Montana, consists of volcaniclastic strata and basaltic andesite lava flows. An intrusive complex represents the volcano's solidified magma chamber. Compositional diversity within components of the volcano appears to reflect evolution via about 50 percent fractional crystallization involving clinopyroxene and plagioclase. 40Ar/39Ar indicate that the volcano was active about 78?1 Ma.

Eruptive parameters and dynamics of the April 2015 sub-Plinian eruptions of Calbuco volcano (southern Chile)

NASA Astrophysics Data System (ADS)

Castruccio, Angelo; Clavero, Jorge; Segura, Andrea; Samaniego, Pablo; Roche, Olivier; Le Pennec, Jean-Luc; Droguett, Bárbara

2016-09-01

We conducted geological and petrological analyses of the tephra fallout and pyroclastic density current (PDC) products of the 22-23 April 2015 Calbuco eruptions. The eruptive cycle consisted of two sub-Plinian phases that generated > 15 km height columns and PDCs that travelled up to 6 km from the vent. The erupted volume is estimated at 0.38 km3 (non-DRE), with approximately 90% corresponding to tephra fall deposits and the other 10% to PDC deposits. The erupted products are basaltic-andesite, 54-55 wt.% SiO2, with minor amounts of andesite (58 wt.% SiO2). Despite the uniform composition of the products, there are at least four types of textures in juvenile clasts, with different degrees of vesicularity and types and content of crystals. We propose that the eruption triggering mechanism was either exsolution of volatiles due to crystallization, or a small intrusion into the base of the magma chamber, without significant magma mixing or with a magma compositionally similar to that of the residing magma. In either case the triggering mechanism generated convection and sufficient overpressure to promote the first eruptive phase. The start of the eruption decompressed the chamber, promoting intense vesiculation of the remaining magma and an increase in eruption rate towards the end of the eruption.

Black dimensional stones: Geology, technical properties and deposit characterization of the dolerites from Uruguay

NASA Astrophysics Data System (ADS)

Morales Demarco, M.; Oyhantçabal, P.; Stein, K.-J.; Siegesmund, S.

2012-04-01

Dimensional stones with a black color occupy a prominent place on the international market. Uruguayan dolerite dikes of andesitic and andesitic-basaltic composition are mined for commercial blocks of black dimensional stones. A total of 16 dikes of both compositions were studied and samples collected for geochemical and petrographical analysis. Color measurements were performed on different black dimensional stones in order to compare them with the Uruguayan dolerites. Samples of the two commercial varieties (Absolute Black and Moderate Black) were obtained for petrophysical analysis (e.g. density, porosity, uniaxial compressive strength, tensile strength, etc.). Detailed structural analyses were performed in several quarries. Geochemistry and petrography determines the intensity of the black color. When compared with commercial samples from China, Brazil, India and South Africa, among others, the Uruguayan dolerite Absolute Black is the darkest black dimensional stone analyzed. In addition, the petrophysical properties of the Uruguayan dolerites make them one of the highest quality black dimensional stones. Structural analyses show that five joint sets have been recognized: two sub-vertical joints, one horizontal and two diagonal. These joint sets are one of the most important factors that control the deposits, since they control the block size distribution and the amount of waste material.

Volcanic Chemostratigraphy on the Outcrop Using Field-Portable X-Ray Fluorescence: An Example from the Basaltic Flows of Hewitt's Cove, MA.

NASA Astrophysics Data System (ADS)

Wall, A. M.; Brabander, D. J.

2005-05-01

The area of Hewitt's Cove, Hingham, Massachusetts structurally represents the southern extent of the Boston Basin, and as such, provides the opportunity to identify and recognize basin-wide events. While the stratigraphy of the Boston Basin has been developed since the advent of U-Pb geochronology and formal stratigraphic facies descriptions (Socci and Smith, 2001), the stratigraphy of the Hewitt's Cove area has not been thoroughly addressed since the work of William O. Crosby in 1894 (Billings, 1976, Bailey and Bland, 2001). Hewitt's Cove consists of an andesitic basaltic flow, approximately 150 m thick, overlain by siltstone and conglomeratic sequences. Field-Portable X-Ray Fluorescence (FP-XRF) was used on fresh and weathered surfaces on the outcrop and in hand samples, and these analyses were compared with conventional laboratory XRF analyses. The in situ field-based analyses produced a reproducible chemostratigraphy that is consistent with subsequent laboratory-based analyses. These data suggest that the series of andesitic basalt flows at Hewitt's Cove are the result of compositionally different magmatic pulses. Additional analyses must be completed to determine the extent of these pulses and the extent of variation in this area before further conclusions can be made. This study particularly demonstrates the utility of using FP-XRF in igneous geologic applications.

Comparative features of volcanoes on Solar system bodies

NASA Astrophysics Data System (ADS)

Vidmachenko, A. P.

2018-05-01

The bark of many cosmic bodies is in motion because of the displacement of tectonic plates on magma. Pouring molten magma through cracks in the cortex is called a volcanic eruption. There are two main types of volcanoes: basaltic, appearing where a new material of tectonic plates is formed, and andesitic, which located in the places of destruction of these plates.The third type of volcanoes is cryovolcanoes, or ice volcanoes. This type of volcano ejects matter in the form of ice volcanic melts or steam from water, ammonia, methane. After the eruption, the cryomagma at a low temperature condenses to a solid phase. Cryovolcanoes can be formed on such objects as Pluto, Ceres, Titan, Enceladus, Europe, Triton, etc. Potential sources of energy for melting ice in the production of cryovolcanoes are tidal friction and/or radioactive decay. Semi-transparent deposits of frozen materials that can create a subsurface greenhouse effect, with the possibility of accumulating the required heat with subsequent explosive eruption, are another way to start the cryovolcano action. This type of eruption is observed on Mars and Triton. The first and second types of eruptions (basaltic and andesitic) are characteristic of terrestrial planets (Mercury, Venus, Mars) and for some satellites of the planets of the Solar system.

Tuffaceous Mud is a Volumetrically Important Volcaniclastic Facies of Reararc Submarine Volcanism

NASA Astrophysics Data System (ADS)

Gill, J. B.; Bongiolo, E.; Miyazaki, T.; Hamelin, C.; Jutzeler, M.

2016-12-01

Unexpectedly, about 2/3 of the 1806 m of rock drilled during IODP Exp 350 on the flank of an Upper Miocene andesitic seamount in the Izu reararc was tuffaceous mud and tuffaceous mudstone that accumulated at high carbonate-free sedimentation rates (60-120 m/MY). This rate is several times faster than at adjacent sites in the forearc or incoming plate. Most tuffaceous muds contain <1% <2 mm-sized fragments of glass shards and plag±cpx crystals. Most muds are dacitic in bulk composition on an anhydrous, carbonate-free basis. They are intercalated with thin ash or tuff beds. The trace element and Sr-Nd-Hf-Pb isotope geochemistry of carbonate-free tuffaceous mud and mudstone indicates that >70% and often >90% of them consist of local volcanic materials that range from basalt to rhyolite. Most exceptions were deposited during Pleistocene glacial intervals. Consequently, tuffaceous mud is an important submarine volcaniclastic facies destined to become shale or slate in the geological record while retaining geochemical information about its provenance. Even though the drill site was <10 km from the summit of a 2-km-high and at times subaerially exposed seamount, and the sedimentation rate exceeded that in the adjacent forearc, tuffaceous mud was the principal reararc volcaniclastic facies. To explain this fine grain size, we infer that much of the submarine volcanism was explosive despite water depths approaching 2 km. The resulting very fine glass quickly becomes clay or is too small to be recognized in thin section or smear slides, and can be sampled only in sediment cores.

Preliminary report on the Comet area, Jefferson County, Montana

USGS Publications Warehouse

Becraft, George Earle

1953-01-01

Several radioactivity anomalies and a few specimens of sooty pitchblende and other uranium minerals have been found on the mine dumps of formerly productive base- and precious-metal mines along the Comet-Gray Eagle shear zone in the Comet area in southwestern Montana. The shear zone is from 50 to 200 feet wide and has been traced for at least 5? miles. It trends N. 80 ? W. across the northern part of the area and cuts the quartz monzonitic rocks of the Boulder batholith and younger silicic intrusive rocks, as well as prebatholithic volcanic rocks, and is in turn cut by dacite and andesite dikes. The youngest period of mineralization is represented by chalcedonic vein zones comprising one or more discontinuous stringers and veins of cryptocrystalline silica in silicified quartz monzonite and in alaskite that has not been appreciably silicified. In some places these zones contain no distinct chalcedonic veins but are represented only by silicified quartz monzonite. These zones locally contain uranium in association with very small amounts of pyrite, galena, ruby silver, arqentite, native silver, molybdenite, chalcopyrite, arsenopyrite, and barite. At the Free Enterprise mine, uranium has been produced from a narrow chalcedonic vein that contains disseminated secondary uranium minerals and local small pods of pitchblende and also from disseminated secondary uranium ,minerals in the adjacent quartz monzonite. Undiscovered deposits of uranium ore may occur spatially associated with the base- and precious-metal deposits along the Comet-Gray Eagle shear zone and with chalcedonic vein zones similar to the Free Enterprise.

Preliminary report on the Comet area, Jefferson County, Montana

USGS Publications Warehouse

Becraft, George Earle

1952-01-01

Several radioactivity anomalies and a few specimens of sooty pitchblende and other uranium minerals have been found on the mine dumps of formerly productive base-and precious-metal mines along the Comet-Gray Eagle shear zone in the Comet area in southwestern Montana. The shear zone is from 50 to 200 feet wide and has been traced for at least 5 1/2 miles. It trends N. 80° W. across the northern part of the area and cuts the quartz monzonitic rocks of the Boulder batholith and younger silicic intrusive rocks, as well as the pre-batholitic volcanic rocks, and is in turn cut by dacite and andesite dikes. The youngest period of mineralization is represented by chalcedonic vein zones comprising one or more discontinuous stringers and veins of cryptocrystalline silica in silicified quartz monzonite and in alaskite that has not been appreciably silicified. In some places these zones contain no distinct chalcedonic veins, but are represented only by silicified quartz monzonite. These zones locally contain uranium in association with very small amounts of the following minerals: pyrite, galena, ruby silver, argentite, native silver, molybdenite, chalcopyrite, arsenopyrite, and barite. At the Free Enterprise mine, uranium has been produced from a narrow chalcedonic vein that contains disseminated secondary uranium minerals and local small pods of pitchblende and from disseminated secondary uranium minerals in the adjacent quartz monzonite. Undiscovered commercial deposits of uranium ore may occur spatially associated with the base-and precious-metal deposits along the Comet-Gray Eagle shear zone, and chalcedonic vein zones similar to the Free Enterprise.

Character, mass, distribution, and origin of tephra-fall deposits of the 1989-1990 eruption of redoubt volcano, south-central Alaska

USGS Publications Warehouse

Scott, W.E.; McGimsey, R.G.

1994-01-01

The 1989-1990 eruption of Redoubt Volcano spawned about 20 areally significant tephra-fall deposits between December 14, 1989 and April 26, 1990. Tephra plumes rose to altitudes of 7 to more than 10 km and were carried mainly northward and eastward by prevailing winds, where they substantially impacted air travel, commerce, and other activities. In comparison to notable eruptions of the recent past, the Redoubt events produced a modest amount of tephra-fall deposits - 6 ?? 107 to 5 ?? 1010 kg for individual events and a total volume (dense-rock equivalent) of about 3-5 ?? 107 m3 of andesite and dacite. Two contrasting tephra types were generated by these events. Pumiceous tephra-fall deposits of December 14 and 15 were followed on December 16 and all later events by fine-grained lithic-crystal tephra deposits, much of which fell as particle aggregates. The change in the character of the tephra-fall deposits reflects their fundamentally different modes of origin. The pumiceous deposits were produced by magmatically driven explosions. The finegrained lithic-crystal deposits were generated by two processes. Hydrovolcanic vent explosions generated tephrafall deposits of December 16 and 19. Such explosions continued as a tephra source, but apparently with diminishing importance, during events of January and February. Ash clouds of lithic pyroclastic flows generated by collapse of actively growing lava domes probably contributed to tephra-fall deposits of all events from January 2 to April 26, and were the sole source of tephra fall for at least the last 4 deposits. ?? 1994.

Subsurface structure imaging of the Sembalun-Propok area, West Nusa Tenggara, Indonesia by using the audio-frequency magnetotelluric data

NASA Astrophysics Data System (ADS)

Febriani, F.; Widarto, D. S.; Gaffar, E.; Nasution, A.; Grandis, H.

2017-07-01

We have investigated the subsurface structure of the Sembalun-Propok Area, West Nusa Tenggara, by using the audio-frequency magnetotelluric (AMT) method. This area is one of the geothermal prospect areas in eastern Indonesia. There are 38 AMT observation points, which were deployed along three profiles. We applied the phase tensor analysis on all observation points to determine both the dimensionality of and the regional strike of the study area. The results of the phase tensor analysis show that the study area can be assumed as 2-D and the regional strike of the study area is about N330°E. Then, after rotating the impedance tensor data to the regional strike, we carried out the 2-D inversion modeling to know more detail the subsurface structure of the study area. The results of the 2-D MT inversion are consistent with the geology of the study area. The near surface along all profiles is dominated by the higher resistivity layer (> 500 Ωm). It is highly associated with the surface geology of the study area which is characterized by the volcanic rock and mostly consist of andesitic to dacitic rocks of a calc-alkaline suite. Below the resistive layer at the near surface, the modelings show the layer which has the lower-moderate resistivity layer. It is possibly a cap rock layer of geothermal system of the Sembalun-Propok area. Lastly, the third layer is the very conductive layer and possibly associated with the presence of thermal fluids in the study area.

Pre-eruption deformation caused by dike intrusion beneath Kizimen volcano, Kamchatka, Russia, observed by InSAR

USGS Publications Warehouse

Ji, Lingyun; Lu, Zhong; Dzurisin, Daniel; Senyukov, Sergey

2013-01-01

Interferometric synthetic aperture radar (InSAR) images reveal a pre-eruption deformation signal at Kizimen volcano, Kamchatka, Russia, where an ongoing eruption began in mid-November, 2010. The previous eruption of this basaltic andesite-to-dacite stratovolcano occurred in 1927–1928. InSAR images from both ascending and descending orbital passes of Envisat and ALOS PALSAR satellites show as much as 6 cm of line-of-sight shortening from September 2008 to September 2010 in a broad area centered at Kizimen. About 20 cm of opening of a nearly vertical dike provides an adequate fit to the surface deformation pattern. The model dike is approximately 14 km long, 10 km high, centered 13 km beneath Kizimen, and strikes NE–SW. Time-series analysis of multi-temporal interferograms indicates that (1) intrusion started sometime between late 2008 and July 2009, (2) continued at a nearly constant rate, and (3) resulted in a volume expansion of 3.2 × 107 m3 by September 2010, i.e., about two months before the onset of the 2010 eruption. Earthquakes located above the tip of the dike accompanied the intrusion. Eventually, magma pressure in the dike exceeded the confining strength of the host rock, triggering the 2010 eruption. Our results provide insight into the intrusion process that preceded an explosive eruption at a Pacific Rim stratovolcano following nearly a century of quiescence, and therefore have implications for monitoring and hazards assessment at similar volcanoes elsewhere.

Hot and Steamy Fractures in the Philippines: The Geological Characterization and Permeability Evaluation of Fractures in the Southern Negros Geothermal Field, Philippines

NASA Astrophysics Data System (ADS)

Pastoriza, L. R.; Holdsworth, R.; McCaffrey, K. J. W.; Dempsey, E. D.; Walker, R. J.; Gluyas, J.; Reyes, J. K.

2016-12-01

Fluid flow pathway characterization is critical to geothermal exploration and exploitation. It requires a good understanding of the structural evolution, fault distribution and fluid flow properties. A dominantly fieldwork-based approach has been used to evaluate the potential fracture permeability characteristics of a typical high-temperature geothermal reservoir in the Southern Negros Geothermal Field, Philippines. This is a liquid-dominated geothermal resource hosted in the andesitic to dacitic Quaternary Cuernos de Negros Volcano in Negros Island. Fieldwork reveals two main fracture groups based on fault rock characteristics, alteration type, relative age of deformation, and associated thermal manifestation, with the younger fractures mainly related to the development of the modern geothermal system. Palaeostress analyses of cross-cutting fault and fracture arrays reveal a progressive counterclockwise rotation of stress axes from the (?)Pliocene up to the present-day, which is consistent with the regional tectonic models. A combined slip and dilation tendency analysis of the mapped faults indicates that NW-SE structures should be particularly promising drilling targets. Frequency versus length and aperture plots of fractures across six to eight orders of magnitude show power-law relationships with a change in scaling exponent in the region of 100 to 500m length-scales. Finally, evaluation of the topology of the fracture branches shows the dominance of Y-nodes that are mostly doubly connected suggesting good connectivity and permeability within the fracture networks. The results obtained in this study illustrate the value of methods that can be globally applied during exploration to better characterize fracture systems in geothermal reservoirs using multiscale datasets.

Hot and steamy fractures in the Philippines: the characterisation and permeability evaluation of fractures of the Southern Negros Geothermal Field, Negros Oriental, Philippines

NASA Astrophysics Data System (ADS)

Pastoriza, Loraine; Holdsworth, Robert; McCaffrey, Kenneth; Dempsey, Eddie; Walker, Richard; Gluyas, Jon; Reyes, Jonathan

2017-04-01

Fluid flow pathway characterisation is critical to geothermal exploration and exploitation. It requires a good understanding of the structural evolution, fault distribution and fluid flow properties. A dominantly fieldwork-based approach has been used to evaluate the potential fracture permeability characteristics of a typical high-temperature geothermal reservoir in the Southern Negros Geothermal Field, Philippines. This is a liquid-dominated geothermal resource hosted in the andesitic to dacitic Quaternary Cuernos de Negros Volcano in Negros Island. Fieldwork reveals two main fracture groups based on fault rock characteristics, alteration type, relative age of deformation, and associated thermal manifestation, with the younger fractures mainly related to the development of the modern geothermal system. Palaeostress analyses of cross-cutting fault and fracture arrays reveal a progressive counterclockwise rotation of stress axes from the (?)Pliocene up to the present-day, which is consistent with the regional tectonic models. A combined slip and dilation tendency analysis of the mapped faults indicates that NW-SE structures should be particularly promising drilling targets. Frequency versus length and aperture plots of fractures across six to eight orders of magnitude show power-law relationships with a change in scaling exponent in the region of 100 to 500m length-scales. Finally, evaluation of the topology of the fracture branches shows the dominance of Y-nodes that are mostly doubly connected suggesting good connectivity and permeability within the fracture networks. The results obtained in this study illustrate the value of methods that can be globally applied during exploration to better characterize fracture systems in geothermal reservoirs using multiscale datasets.

Mineral chemistry of magnetite from magnetite-apatite mineralization and their host rocks: examples from Kiruna, Sweden, and El Laco, Chile

NASA Astrophysics Data System (ADS)

Broughm, Shannon G.; Hanchar, John M.; Tornos, Fernando; Westhues, Anne; Attersley, Samuel

2017-12-01

Interpretation of the mineralizing environment of magnetite-apatite deposits remains controversial with theories that include a hydrothermal or magmatic origin or a combination of those two processes. To address this controversy, we have analyzed the trace element content of magnetite from precisely known geographic locations and geologic environments from the Precambrian magnetite-apatite ore and host rocks in Kiruna, Sweden, and the Pliocene-Holocene El Laco volcano in the Atacama desert of Chile. Magnetite samples from Kiruna have low trace element concentrations with little chemical variation between the ore, host, and related intrusive rocks. Magnetite from andesite at El Laco, and dacite from the nearby Láscar volcano, has high trace element concentrations typical of magmatic magnetite. El Laco ore magnetite have low trace element concentrations and displays growth zoning in incompatible elements (Si, Ca, and Ce), compatible elements (Mg, Al, and Mn), large-ion lithophile element (Sr), and high field strength element (Y, Nb, and Th). The El Laco ore magnetite are similar in composition to magnetite that has been previously interpreted to have crystallized from hydrothermal fluids; however, there is a significant difference in the internal zoning patterns. At El Laco, each zoned element is either enriched or depleted in the same layers, suggesting the magnetite crystallized from a volatile-rich, iron-oxide melt. In general, the compositions of magnetite from these two deposits plot in very wide fields that are not restricted to the proposed fields in published discriminant diagrams. This suggests that the use of these diagrams and genetic models based on them should be used with caution.

Exploration of gold occurrences in alteration zones at Dungash district, Southeastern Desert of Egypt using ASTER data and geochemical analyses

NASA Astrophysics Data System (ADS)

Salem, S. M.; El Sharkawi, M.; El-Alfy, Z.; Soliman, N. M.; Ahmed, S. E.

2016-05-01

The present study aims at exploration of new gold occurrences in the alteration zones at Dungash district. Processed ASTER images band ratios 7/6 × 4/6 and (7 + 9/8), field geology and mineralogical and geochemical data help characterize three types of alterations in three areas 1 to 3 that may be targeted for Au exploration. Area1 confined to the metavolcanics located in the SE of Dungash gold mine and revealed silicified and sericitized type alterations, composed of quartz, epidote, chlorite, biotite and opaque minerals mainly pyrite and chalcopyrite. Area2 occurs in the gabbro-diorite rocks at Abu Meraiwa area NE of Dungash gold mine, which are rich in kaolinite, illite, sericite, pyrite, arsenopyrite and chalcopyrite that record kaolinitized alteration. Area3 is hosted in carbonaceous listwaenized serpentinite thus indicating the role of listwaenitization type alteration in ore genesis. It is composed of calcite, chromite, pyrite, arsenopyrite, chalcopyrite and Ni-bearing sulphides. Au contents in area 1 range between 0.12 and 14.91 ppm, and between 6.1 and 16.3 ppm in area 2, while gold values in area 3 vary from <0.01 to 0.03 ppm. Dungash district is comprised of Pan-African assemblages of ophiolitic ultramafics thrusted over the island arc metavolcanics of dacitic- andesite composition. Gabbro-diorite rocks are intruded in the ultramafics and the acidic metavolcanics as well as diorite-quartz diorite suite intruded in the intermediate metavolcanics. Several acidic dykes, granitic dykes and quartz veins cut through the different rocks types.

40Ar/39Ar geochronology and paleomagnetism of Independence volcano, Absaroka volcanic supergroup, Beartooth mountains, Montana

USGS Publications Warehouse

Harlan, S.S.; Snee, L.W.; Geissman, J.W.

1996-01-01

Independence volcano is a major volcanic complex in the lower part of the Absaroka Volcanic Supergroup (AVS) of Montana and Wyoming. Recently reported Rb-Sr mineral dates from the complex give apparent ages of 91 and 84 Ma, whereas field relationships and the physical and compositional similarity of the rocks with other dated parts of the AVS indicate an Early to Middle Eocene age for eruption and deposition. To resolve the conflict between age assignments based on stratigraphic correlations and Rb-Sr dates, we report new paleomagnetic data and 40Ar/39Ar dates for Independence volcano. Paleomagnetic data for the stock and an and andesite plug that cuts the stock are well grouped, of reverse polarity, and yield a virtual geomagnetic pole that is essentially identical to Late Cretaceous and Tertiary reference poles. The reverse polarity indicates that the magnetization of these rocks is probably younger than the Cretaceous normal superchron, or less than about 83.5 Ma. Hornblende from a volcanic breccia near the base of the volcanic pile gives a 40Ar/39Ar age of 51.57 Ma, whereas biotites from a dacite sill and a granodiorite stock that forms the core of the volcano give dates that range from 49.96 to 48.50 Ma. These dates record the age of eruption and intrusion of these rocks and clearly show that the age of Independence volcano is Early to Middle Eocene, consistent with stratigraphic relations. We suggest that the Rb-Sr mineral dates from the Independence stock and related intrusions are unreliable.

Experimental determination of trace-element partitioning between pargasite and a synthetic hydrous andesitic melt

NASA Astrophysics Data System (ADS)

Brenan, J. M.; Shaw, H. F.; Ryerson, F. J.; Phinney, D. L.

1995-10-01

In order to more fully establish a basis for quantifying the role of amphibole in trace-element fractionation processes, we have measured pargasite/silicate melt partitioning of a variety of trace elements (Rb, Ba, Nb, Ta, Hf, Zr, Ce, Nd, Sm, Yb), including the first published values for U, Th and Pb. Experiments conducted at 1000°C and 1.5 GPa yielded large crystals free of compositional zoning. Partition coefficients were found to be constant at total concentrations ranging from ˜ 1 to > 100 ppm, indicating Henry's Law is oparative over this interval. Comparison of partition coefficients measured in this study with previous determinations yields good agreement for similar compositions at comparable pressure and temperature. The compatibility of U, Th and Pb in amphibole decreases in the order Pb > Th > U. Partial melting or fractional crystallization of amphibole-bearing assemblages will therefore result in the generation of excesses in 238U activity relative to 230Th, similar in magnitude to that produced by clinopyroxene. The compatibility of Pb in amphibole relative to U or Th indicates that melt generation in the presence of residual amphibole will result in the long-term enrichment in Pb relative to U or Th in the residue. This process is therefore incapable of producing the depletion in Pb relative to U or Th inferred from the Pb isotopic composition of MORB and OIB. Comparison of partition coefficients measured in this study with previous values for clinopyroxene allows some distinction to be made between expected trace-element fractionations produced during dry (cpx present) and wet (cpx + amphibole present) melting. Rb, Ba, Nb and Ta are dramatically less compatible in clinopyroxene than in amphibole, whereas Th, U, Hf and Zr have similar compatibilities in both phases. Interelement fractionations, such as DNb/DBa are also different for clinopyroxene and amphibole. Changes in certain ratios, such as Ba/Nb, Ba/Th, and Nb/Th within comagmatic suites may therefore offer a means to discern the loss of amphibole from the melting assemblage. Elastic strain theory is applied to the partitioning data after the approaches of Beattie and Blundy and Wood and is used to predict amphibole/melt partition coefficients at conditions of P, T and composition other than those employed in this study. Given values of DCa, DTi and DK from previous partitioning studies, this approach yields amphibole/melt trace-element partition coefficients that reproduce measured values from the literature to within 40-45%. This degree of reproducibility is considered reasonable given that model parameters are derived from partitioning relations involving iron- and potassium-free amphibole.

Sulfur diffusion in dacitic melt at various oxidation states: Implications for volcanic degassing

NASA Astrophysics Data System (ADS)

Lierenfeld, Matthias Bernhard; Zajacz, Zoltán; Bachmann, Olivier; Ulmer, Peter

2018-04-01

The diffusivity of S in a hydrous dacitic melt (4.5-6.0 wt.% H2O) has been investigated in the temperature (T) and pressure (P) range of 950 °C to 1100 °C and 200 to 250 MPa, respectively. Three series of experiments were conducted at relatively low oxygen fugacity (fO2) conditions [0.8 log units below fayalite-magnetite-quartz equilibrium (FMQ -0.8); referred to as "low fO2"] and high fO2 conditions (FMQ +2.5; referred to as "high fO2") to determine if the diffusivity of S is affected by its oxidation state and speciation. Sulfur concentration profiles were measured by electron microprobe and the diffusion coefficient (D) was calculated by fitting these profiles. Sulfur diffusion is approximately one order of magnitude faster when S is dominantly present as sulfide species (low fO2) in comparison to the sulfate dominated experiments (high fO2). The following Arrhenian equations were obtained for high and low fO2 conditions at 200 MPa: high fO2: D = 10-5.92±0.86 * exp ({-137.3±21.5 kJ/mol}/{RT}) low fO2: D = 10-5.18±1.39 * exp ({-125.7±34.4 kJ/mol}/{RT}) where D is the average diffusion coefficient in m2 s-1, R is the gas constant in 8.3144 J mol-1 K-1 and T is the temperature in K. Our results demonstrate for the first time in natural melts that S diffusion is strongly sensitive to fO2. Our S diffusivities under low fO2 conditions are only slightly slower of those found for H2O, suggesting that S can be rather efficiently purged from reduced dacitic melts during volcanic eruptions. However, for more oxidized systems (e.g. subduction zones), S diffusion will be much slower and will hinder equilibrium syn-eruptive degassing during rapid decompression. Therefore, we conclude that the "excess" measured during many explosive volcanic eruptions in arcs is dominantly derived from S-rich bubble accumulation in the eruptible portion of the magma reservoir.

MX Siting Investigation. Geotechnical Evaluation. Verification Study - Pahroc Valley, Nevada. Volume I. Synthesis.

DTIC Science & Technology

1981-06-30

Range both consist of Paleozoic limestone and dolomite overlain by Tertiary ash-flow tuffs and undiffer- entiated volcanic rocks. The central portion...andesite, detrital material, volcanic tuff, pumice). FAULT - A plane or zone of fracture along which there has been * I displacement. FAULT BLOCK...D2850-70). To conduct the test, a cylindrical specimen of soil is surrounded by a fluid in a pressure chamber and subjected to an isotropic pressure . An

A Cultural Resources Survey of the Proposed Recreational Development Areas and Wildlife Subimpoundments at the B. Everett Jordan Dam and Lake. Volume 1.

DTIC Science & Technology

1984-03-01

containing flow banding, light-gray felsite, felsic- porphyries , crystal tuffs, and rare mafic porphyries and crystal tuffs (Conley and Bain 1965:12Z). The...goods are also present in the form of glass beads, gunflints, iron axes, copper hawk bells and white clay trade pipes. HISTORICAL BACKGROUND The...points manufactured on two rock types occur most frequently: andesitic felsite in the lower valley and grey latite porphyry in the upper valley. The

The age and constitution of Cerro Campanario, a mafic stratovolcano in the Andes of central Chile

USGS Publications Warehouse

Hildreth, W.; Singer, B.; Godoy, E.; Munizaga, F.

1998-01-01

Cerro Campanario, a towering landmark on the continental divide near Paso Pehuenche, is a glacially eroded remnant of a mafic stratovolcano that is much younger than previously supposed. Consisting of fairly uniform basaltic andesite, rich in olivine and plagioclase, the 10-15 km3 edifice grew rapidly near the end of the middle Pleistocene, about 150-160 ka, as indicated by 40Ar/39Ar and unspiked K-Ar analyses of its lavas.

Eruptive history and tectonic setting of Medicine Lake Volcano, a large rear-arc volcano in the southern Cascades

USGS Publications Warehouse

Donnelly-Nolan, J. M.; Grove, T.L.; Lanphere, M.A.; Champion, D.E.; Ramsey, D.W.

2008-01-01

Medicine Lake Volcano (MLV), located in the southern Cascades ??? 55??km east-northeast of contemporaneous Mount Shasta, has been found by exploratory geothermal drilling to have a surprisingly silicic core mantled by mafic lavas. This unexpected result is very different from the long-held view derived from previous mapping of exposed geology that MLV is a dominantly basaltic shield volcano. Detailed mapping shows that < 6% of the ??? 2000??km2 of mapped MLV lavas on this southern Cascade Range shield-shaped edifice are rhyolitic and dacitic, but drill holes on the edifice penetrated more than 30% silicic lava. Argon dating yields ages in the range ??? 475 to 300??ka for early rhyolites. Dates on the stratigraphically lowest mafic lavas at MLV fall into this time frame as well, indicating that volcanism at MLV began about half a million years ago. Mafic compositions apparently did not dominate until ??? 300??ka. Rhyolite eruptions were scarce post-300??ka until late Holocene time. However, a dacite episode at ??? 200 to ??? 180??ka included the volcano's only ash-flow tuff, which was erupted from within the summit caldera. At ??? 100??ka, compositionally distinctive high-Na andesite and minor dacite built most of the present caldera rim. Eruption of these lavas was followed soon after by several large basalt flows, such that the combined area covered by eruptions between 100??ka and postglacial time amounts to nearly two-thirds of the volcano's area. Postglacial eruptive activity was strongly episodic and also covered a disproportionate amount of area. The volcano has erupted 9 times in the past 5200??years, one of the highest rates of late Holocene eruptive activity in the Cascades. Estimated volume of MLV is ??? 600??km3, giving an overall effusion rate of ??? 1.2??km3 per thousand years, although the rate for the past 100??kyr may be only half that. During much of the volcano's history, both dry HAOT (high-alumina olivine tholeiite) and hydrous calcalkaline

The geology of the northern tip of the Arabian-Nubian Shield

NASA Astrophysics Data System (ADS)

Beyth, M.; Eyal, Y.; Garfunkel, Z.

2014-11-01

Recently, a detailed (1:50,000) geological map of the Elat area, southern Israel was published. Attached to this map is a stratigraphic table of the Neoproterozoic metamorphic-magmatic complex of the study area. The Neoproterozoic basement in the Elat area encapsulates the Arabian Nubian Shield (ANS) geologic evolution. Uranium-Lead and Lead-Lead zircon ages, included in previous studies and referred to in this paper, reveal that these rocks were formed during more than 300 million years of Neoproterozoic time. The major process controlling the formation of the ANS as part of the East African Orogen is the closure of the Mozambique Ocean. The first orogenic phase in the Elat area, represented by the metamorphic rocks, includes the development of an island arc, erosion of the islands and deposition, and metamorphism. This event took place between ∼950 Ma and 780-790 Ma. Elat Schist, the oldest metamorphic rock in the area, was deformed and then intruded by quartz dioritic and granitic plutons that were later deformed and metamorphosed. The amphibolite metamorphic rock facies indicate metamorphic conditions of up to 650 °C and between 4 and 5 kbar. The peak of the metamorphic event was most probably before 750 Ma. A gradual change from compressional to extensional stress regime is evidenced by emplacement andesitic magnesium-rich dykes dated to 705 Ma that were later metamorphosed to schistose dykes at a greenschist metamorphic facies. The second orogenic phase (terrane amalgamation, main shaping of crust) was associated with the emplacement of large volumes (>50% of area) of calc-alkaline intrusions in a post-collision setting. These very last stages of metamorphism and deformation are characterized by intrusion of ∼630 Ma granitoids exhibiting some foliation. Pluton emplacement continued also after the end of deformation. Exhumation and transition to an extensional regime is recorded by the intrusion of shallow alkaline granites in ∼608 Ma which were

Geology of Mount Rainier National Park, Washington

USGS Publications Warehouse

Fiske, Richard S.; Hopson, Clifford Andrae; Waters, Aaron Clement

1963-01-01

Mount Rainier National Park includes 378 square miles of rugged terrain on the west slope of the Cascade Mountains in central Washington. Its mast imposing topographic and geologic feature is glacier-clad Mount Rainier. This volcano, composed chiefly of flows of pyroxene andesite, was built upon alt earlier mountainous surface, carved from altered volcanic and sedimentary rocks invaded by plutonic and hypabyssal igneous rocks of great complexity. The oldest rocks in the park area are those that make up the Olmnapecosh Formation of late Eocene age. This formation is more than 10,000 feet thick, and consists almost entirely of volcanic debris. It includes some lensoid accumulations of lava and coarse mudflows, heaped around volcanic centers., but these are surrounded by vastly greater volumes of volcanic clastic rocks, in which beds of unstratified coarse tuff-breccia, about 30 feet in average thickness, alternate with thin-bedded breccias, sandstones, and siltstones composed entirely of volcanic debris. The coarser tuff-breccias were probably deposited from subaqueous volcanic mudflows generated when eruption clouds were discharged directly into water, or when subaerial ash flows and mudflows entered bodies of water. The less mobile mudflows and viscous lavas built islands surrounded by this sea of thinner bedded water-laid clastics. In compostion the lava flows and coarse lava fragments of the Ohanapecosh Formation are mostly andesite, but they include less abundant dacite, basalt, and rhyolite. The Ohanapecosh Formation was folded, regionally altered to minerals characteristic of the zeolite facies of metamorphism, uplifted, and deeply eroded before the overlying Stevens Ridge Formation of Oligocene or early Miocene age was deposited upon it. The Stevens Ridge rocks, which are about 3,000 feet in maximum total thickness, consist mainly of massive ash flows. These are now devitrified and altered, but they originally consisted of rhyodacite pumice lapilli and glass

Age constraints on Jerritt Canyon and other Carlin-type gold deposits in the western United States-relationship to mid-Tertiary extension and magmatism

USGS Publications Warehouse

Hofstra, A.H.; Snee, L.W.; Rye, R.O.; Folger, H.W.; Phinisey, J.D.; Loranger, R.J.; Dahl, A.R.; Naeser, C.W.; Stein, H.J.; Lewchuk, M.

1999-01-01

Carlin-type gold deposits are difficult to date and a wide range of ages has been reported for individual deposits. Therefore, several methods were employed to constrain the age of the gold deposits in the Jerritt Canyon district. Dated igneous rocks with well-documented crosscutting relationships to ore provided the most reliable constraints. K/Ar and 40Ar/39Ar dates on igneous rocks are as follows: andesite dikes 324 Ma, sericitic alteration in andesite dikes 118 Ma, basalt dikes 40.8 Ma, quartz monzonite dikes 39.2 Ma, and calc-alkaline ignimbrites 43.1 to 40.1 Ma. Of these, only the andesite and basalt dikes are clearly altered and mineralized. The gold deposits are, therefore, younger than the 40.8 Ma basalt dikes. The sericitic alteration in the andesite dikes is unrelated to the gold deposits. A number of dating techniques did not work. K/Ar and 40Ar/39Ar dates on mica from mineralized Ordovician to Devonian sedimentary rocks gave misleading results. The youngest date of 149 Ma from the smallest <0.1-??m-size fraction shows that the temperature (120??-260??C) and duration (?) of hydrothermal activity was insufficient to reset preexisting fine-grained micas in the host rocks. The temperature and duration was also insufficient to anneal fission tracks in zircon from Ordovician quartzites as they yield Middle Proterozoic dates in both mineralized and barren samples. Apatites were too small for fission track dating. Hydrothermal sulfides have pronounced crustal osmium isotope signatures (187Os/188Os(initial) = 0.9-3.6) but did not yield a meaningful isochron due to very low Re and Os concentrations and large analytical uncertainties. Paleomagnetic dating techniques failed because the hydrothermal fluids sulfidized nearly all of the iron in the host rocks leaving no remnant magnetism. When published isotopic dates from other Carlin-type deposits in Nevada and Utah are subject to the rigorous evaluation developed for the Jerritt Canyon study, most deposits can be

Relationship between geomorphology and lithotypes of lahar deposit from Chokai volcano, Japan

NASA Astrophysics Data System (ADS)

Minami, Y.; Ohba, T.; Hayashi, S.; Kataoka, K.

2013-12-01

Chokai volcano, located in the northern Honshu arc in Japan, is an andesitic stratovolcano that collapsed partly at ca. 2500 years ago. A post collapse lahar deposit (Shirayukigawa lahar deposit) is distributed in the northern foot of the volcanic edifice. The deposit consists of 16 units of debris flow, hyperconcentrated flow and streamflow deposits. The Shirayukigawa lahar deposit has a total thickness of 30 m and overlies the 2.5-ka Kisakata debris avalanche deposit. Shirayukigawa lahar deposit forms volcanic fan and volcanic apron. The volcanic fan is subdivided into four areas on the basis of slope angles and of geomorphological features: 1) steeply sloped area, 2) moderately sloped area, 3) gently sloped area and 4) horizontal area. From sedimentary facies and structures, each unit of the Shirayukigawa lahar deposit is classified into one of four lithotypes: clast-supported debris flow deposit (Cc), matrix-supported debris flow deposit (Cm1), hyperconcentrated flow deposit (Cm2) and streamflow deposit (Sl). Each type has the following lithological characteristics. The lithotypes are well correlated with the geomorphology of the volcanic fan. The steeply-sloped and the moderately-sloped areas are dominated by Cc, Cm1, and Cm2, and The horizontal area are dominated by Sl. Debris flow deposit (Cc) is massive, very poorly sorted, partly graded, and clast-supported with polymictic clasts dominated by subrounded to rounded volcanic clasts. Matrix is sandy to muddy. Preferred clast orientation are present. Debris flow deposit (Cm1) is massive, very poorly sorted, and matrix-supported with polymictic clasts dominated by subrounded to rounded volcanic clasts. Matrix is sandy to muddy. Some layers exhibit coarse-tail normal/inverse grading. Most clasts are oriented. Hyperconcentrated flow deposit (Cm2) is massive to diffusely laminated, very poorly sorted and matrix-supported with polymictic clasts dominated by subrounded to rounded volcanic rocks. Matrix is sandy. The

Petrology and petrogenesis of the Eocene Volcanic rocks in Yildizeli area (Sivas), Central Anatolia, Turkey

NASA Astrophysics Data System (ADS)

Doğa Topbay, C.; Karacık, Zekiye; Genç, S. Can; Göçmengil, Gönenç

2015-04-01

Yıldızeli region to the south of İzmir Ankara Erzincan suture zone is situated on the large Sivas Tertiary sedimentary basin. After the northern branch of the Neotethyan Ocean was northerly consumed beneath the Sakarya Continent, a continent - continent collision occurred between the Anatolide- Tauride platform and Pontides and followed a severe intermediate magmatism during the Late Cretaceous- Tertiary period. This created an east-west trending volcanic belt along the whole Pontide range. In the previous studies different models are suggested for the Eocene volcanic succession such as post-collisional, delamination and slab-breakoff models as well as the arc model for its westernmost parts. We will present our field and geochemical data obtained from the Yıldızeli and its surroundings for its petrogenesis, and will discuss the tectonic model(s) on the basis of their geochemical/petrological aspects. Cenozoic volcanic sequences of Yıldızeli region which is the main subject of this study, overlie Pre-Mesozoic crustal meta-sedimentary group of Kırşehir Massif, Ophiolitic mélange and Cretaceous- Paleocene? flysch-like sequences. In the northern part of Yıldızeli region, north vergent thrust fault trending E-W seperates the ophiolitic mélange complex from the Upper Cretaceous-Paleocene and Tertiary formations. Volcano-sedimentary units, Eocene in age, of the Yıldızeli (Sivas-Turkey) which are intercalated with sedimentary deposits related to the collision of Anatolide-Tauride and a simultaneous volcanic activity (i.e. the Yıldızeli volcanics), exposed throughout a wide zone along E-W orientation. Yıldızeli volcanics consist of basalts, basaltic-andesites and andesitic lavas intercalated flow breccias and epiclastic, pyroclastic deposits. Basaltic andesite lavas contain Ca-rich plagioclase + clinopyroxene ± olivine with minor amounts of opaque minerals in a matrix comprised of microlites and glass; andesitic lavas are generally contain Ca

CALIPSO Borehole Instrumentation Project at Soufriere Hills Volcano, Montserrat, BWI: Overview and Prospects

NASA Astrophysics Data System (ADS)

Voight, B.; Mattioli, G. S.; Young, S. R.; Linde, A. T.; Sacks, I. S.; Malin, P.; Shalev, E.; Hidayat, D.; Elsworth, D.; Widiwijayanti, C.; Miller, V.; Sparks, R.; Neuberg, J.; Bass, V.; Dunkley, P.; Edmonds, M.; Herd, R.; Jolly, A.; Norton, G.; Thompson, G.

2003-12-01

Project CALIPSO (Caribbean Andesite Lava Island-volcano Precision Seismo-geodetic Observatory) was developed in order to investigate the magmatic system at the exceedingly active Soufriere Hills Volcano (SHV), Montserrat. The collaborative project involves a number of institutions acting in partnership with the Montserrat Volcano Observatory (MVO), and is funded by NSF with a contribution to drilling costs provided by UK NERC. SHV remains active and dynamic after 7 years and is expected to remain so for the foreseeable future. Many aspects of andesite magmatic system dynamics remain poorly understood despite significant monitoring and research efforts, and CALIPSO is expected to improve our understanding of SHV and andesite systems generally. Drilling was carried out by DOSECC, Nov 02 to Mar 03. CALIPSO uses an integrated array of four strategically located 200-m boreholes, plus a few shallower holes and surface installations. The borehole instrument package is designed to have long life (decades) at moderately high temperatures. Each site includes a single-component,very broad band, Sacks-Evertson strainmeter, a three-component seismometer (about 1 Hz to 1 kHz), a Pinnacle Technologies tiltmeter, and a surface CGPS station with choke ring antenna. At one site a new CIW hot-hole strainmeter design, involving hydraulic sensors and no downhole electronics, has been used for the first time anywhere. Data will be streamed from the remote borehole sites using FreeWave telemetry coupled with Quanterra A/D converters. The borehole observatory is being fully integrated into the surface monitoring networks of the MVO and other PSU/U Ark monitor systems, enhancing the existing CGPS and surface broadband seismic-acoustic networks. These instruments are intended to probe changes in the andesitic volcanic system and underlying mafic sources with unprecedented sensitivity. Cyclic activity at a variety of timescales has been a feature of SHV volcanism, involving seismicity

Introduction to Augustine Volcano and Overview of the 2006 Eruption

NASA Astrophysics Data System (ADS)

Nye, C. J.

2006-12-01

This overview represents the combined efforts of scores of people, including Alaska Volcano Observatory staff from the US Geological Survey, the University of Alaska Fairbanks Geophysical Institute, and the Alaska Division of Geological and Geophysical Surveys; additional members of those agencies outside of AVO; and volcanologists from elsewhere. Augustine is a young, and therefore small island volcano in the Cook Inlet region of the eastern Aleutian arc. It is among the most active volcanoes in the arc, with six major historic eruptions, and a vigorous eruptive history going back at least 2,500 years. Eruptions typically begin explosively, and finish with the extrusion of domes and sometimes short, steep lava flows. At least 14 times (most recently in 1883) the -summit has become over-steepened and failed, producing debris avalanches which reached tidewater. Magmas within each of the well-studied eruptions are crystal-rich andesite spanning up to seven weight percent silica. Mixing and mingling are ubiquitous and occur at scales from meters to microns. In general, magmagenesis at Augustine is open, messy, and transcrustal. The 2006 eruption was broadly similar to the 20th century eruptions. Unrest began midway through 2005, with steadily increasing numbers of microearthquakes and continuous inflation of the edifice. By mid-December there were obvious morphological and thermal changes at the summit, as well as phreatic explosions and more passive venting of S-rich gasses. In mid-January 2006 phreatomagmatic explosions gave way to magmatic explosions, producing pyroclastic flows dominated by low-silica andesite, as well as lahars, followed by a small summit dome. In late January the nature of seismicity, eruptive style, and type of erupted magma all changed, and block-and-ash flows of high-silica, crystal-rich andesite were emplaced as the edifice deflated. Re-inflation well below the edifice and low-level effusion continued through February. During the second week

Opal-A in Glassy Pumice, Acid Alteration, and the 1817 Phreatomagmatic Eruption at Kawah Ijen (Java), Indonesia

NASA Astrophysics Data System (ADS)

Lowenstern, Jacob B.; van Hinsberg, Vincent; Berlo, Kim; Liesegang, Moritz; Iacovino, Kayla; Bindeman, Ilya N.; Wright, Heather M.

2018-02-01

At Kawah Ijen (Indonesia), vigorous SO2 and HCl degassing sustains a hyperacid lake (pH 0) and intensely alters the subsurface, producing widespread residual silica and advanced argillic alteration products. In 1817, a VEI 2 phreatomagmatic eruption evacuated the lake, depositing a widespread layer of muddy ash fall, and sending lahars down river drainages. We discovered multiple types of opaline silica in juvenile low-silica dacite pumice and in particles within co-erupted laharic sediments. Most spectacular are opal-replaced phenocrysts of plagioclase and pyroxene adjacent to pristine matrix glass and melt inclusions. Opal-bearing pumice has been found at numerous sites, including where post-eruption infiltration of acid water is unlikely. Through detailed analyses of an initial sampling of 1817 eruption products, we find evidence for multiple origins of opaline materials in pumice and laharic sediments. Evidently, magma encountered acid-altered materials in the subsurface and triggered phreatomagmatic eruptions. Syn-eruptive incorporation of opal-alunite clasts, layered opal, and fragment-filled vesicles of opal and glass, all suggest magma-rock interactions in concert with vesiculation, followed by cooling within minutes. Our experiments at magmatic temperature confirm that the opaline materials would show noticeable degradation in time periods longer than a few tens of minutes. Some glassy laharic sedimentary grains are more andesitic than the main pumice type and may represent older volcanic materials that were altered beneath the lake bottom and were forcefully ejected during the 1817 eruption. A post-eruptive origin remains likely for most of the opal-replaced phenocrysts in pumice. Experiments at 25°C and 100°C reveal that when fresh pumice is bathed in Kawah Ijen hyperacid fluid for six weeks, plagioclase is replaced without altering either matrix glass or melt inclusions. Moreover, lack of evidence for high-temperature annealing of the opal suggests