Neutron Diffraction of Large-Volume Samples at High Pressure Using Compact Opposed-Anvil Cells

NASA Astrophysics Data System (ADS)

Ni, Xiao-Lin; Fang, Lei-Ming; Li, Xin; Chen, Xi-Ping; Xie, Lei; He, Duan-Wei; Kou, Zi-Li

2018-04-01

Not Available Supported by the National Key Research and Development Program of China under Grant No 2016YFA0401503, the Science Challenge Project under Grant No TZ2016001, and the National Natural Science Foundation of China under Grant No 11427810.

Pressure, stress, and strain distribution in the double-stage diamond anvil cell

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lobanov, Sergey S., E-mail: slobanov@carnegiescience.edu; V.S. Sobolev Institute of Geology and Mineralogy SB RAS, Novosibirsk 630090; Prakapenka, Vitali B.

Double stage diamond anvil cells (DACs) of two designs have been assembled and tested. We used a standard symmetric DAC with flat or beveled culets as a primary stage and CVD microanvils machined by a focused ion beam as a second. We evaluated pressure, stress, and strain distributions in gold and a mixture of gold and iron as well as in secondary anvils using synchrotron x-ray diffraction with a micro-focused beam. A maximum pressure of 240 GPa was reached independent of the first stage anvil culet size. We found that the stress field generated by the second stage anvils is typicalmore » of conventional DAC experiments. The maximum pressures reached are limited by strains developing in the secondary anvil and by cupping of the first stage diamond anvil in the presented experimental designs. Also, our experiments show that pressures of several megabars may be reached without sacrificing the first stage diamond anvils.« less

Crimp sealing of tubes flush with or below a fixed surface

DOEpatents

Fischer, J.E.; Walmsley, D.; Wapman, P.D.

1996-08-20

An apparatus for crimp sealing and severing tubes flush or below a fixed surface. Tube crimping below a fixed surface requires an asymmetric die and anvil configuration. The anvil must be flat so that, after crimping, it may be removed without deforming the crimped tubes. This asymmetric die and anvil is used when a ductile metal tube and valve assembly are attached to a pressure vessel which has a fixed surface around the base of the tube at the pressure vessel. A flat anvil is placed against the tube. Die guides are placed against the tube on a side opposite the anvil. A pinch-off die is inserted into the die guides against the tube. Adequate clearance for inserting the die and anvil around the tube is needed below the fixed surface. The anvil must be flat so that, after crimping, it may be removed without deforming the crimped tubes. 8 figs.

Crimp sealing of tubes flush with or below a fixed surface

DOEpatents

Fischer, Jon E.; Walmsley, Don; Wapman, P. Derek

1996-01-01

An apparatus for crimp sealing and severing tubes flush or below a fixed surface. Tube crimping below a fixed surface requires an asymmetric die and anvil configuration. The anvil must be flat so that, after crimping, it may be removed without deforming the crimped tubes. This asymmetric die and anvil is used when a ductile metal tube and valve assembly are attached to a pressure vessel which has a fixed surface around the base of the tube at the pressure vessel. A flat anvil is placed against the tube. Die guides are placed against the tube on a side opposite the anvil. A pinch-off die is inserted into the die guides against the tube. Adequate clearance for inserting the die and anvil around the tube is needed below the fixed surface. The anvil must be flat so that, after crimping, it may be removed without deforming the crimped tubes.

21 CFR 882.4030 - Skull plate anvil.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Skull plate anvil. 882.4030 Section 882.4030 Food... DEVICES NEUROLOGICAL DEVICES Neurological Surgical Devices § 882.4030 Skull plate anvil. (a) Identification. A skull plate anvil is a device used to form alterable skull plates in the proper shape to fit...

Heating rates in tropical anvils

NASA Technical Reports Server (NTRS)

Ackerman, Thomas P.; Valero, Francisco P. J.; Pfister, Leonhard; Liou, Kuo-Nan

1988-01-01

The interaction of infrared and solar radiation with tropical cirrus anvils is addressed. Optical properties of the anvils are inferred from satellite observations and from high-altitude aircraft measurements. An infrared multiple-scattering model is used to compute heating rates in tropical anvils. Layer-average heating rates in 2 km thick anvils were found to be on the order of 20 to 30 K/day. The difference between heating rates at cloud bottom and cloud top ranges from 30 to 200 K/day, leading to convective instability in the anvil. The calculations are most sensitive to the assumed ice water content, but also are affected by the vertical distribution of ice water content and by the anvil thickness. Solar heating in anvils is shown to be less important than infrared heating but not negligible. The dynamical implications of the computed heating rates are also explored and it is concluded that the heating may have important consequences for upward mass transport in the tropics. The potential impact of tropical cirrus on the tropical energy balance and cloud forcing are discussed.

Virtual Environment Computer Simulations to Support Human Factors Engineering and Operations Analysis for the RLV Program

NASA Technical Reports Server (NTRS)

Lunsford, Myrtis Leigh

1998-01-01

The Army-NASA Virtual Innovations Laboratory (ANVIL) was recently created to provide virtual reality tools for performing Human Engineering and operations analysis for both NASA and the Army. The author's summer research project consisted of developing and refining these tools for NASA's Reusable Launch Vehicle (RLV) program. Several general simulations were developed for use by the ANVIL for the evaluation of the X34 Engine Changeout procedure. These simulations were developed with the software tool dVISE 4.0.0 produced by Division Inc. All software was run on an SGI Indigo2 High Impact. This paper describes the simulations, various problems encountered with the simulations, other summer activities, and possible work for the future. We first begin with a brief description of virtual reality systems.

Phase stability of transition metals and alloys

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hixson, R.S.; Schiferl, D.; Wills, J.M.

1997-06-01

This is the final report of a three-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). This project was focused on resolving unexplained differences in calculated and measured phase transition pressures in transition metals. Part of the approach was to do new, higher accuracy calculations of transmission pressures for group 4B and group 6B metals. Theory indicates that the transition pressures for these baseline metals should change if alloyed with a d-electron donor metal, and calculations done using the Local Density Approximation (LDA) and the Virtual Crystal Approximation (VCA) indicate that this is true. Alloymore » systems were calculated for Ti, Zr and Hf based alloys with various solute concentrations. The second part of the program was to do new Diamond Anvil Cell (DAC) measurements to experimentally verify calculational results. Alloys were prepared for these systems with grain size suitable for Diamond Anvil Cell experiments. Experiments were done on pure Ti as well as Ti-V and Ti-Ta alloys. Measuring unambiguous transition pressures for these systems proved difficult, but a new technique developed yielded good results.« less

A modified efficient purse-string stapling technique (mEST) that uses a new metal rod for intracorporeal esophagojejunostomy in laparoscopic total gastrectomy

PubMed Central

Moon, Jeong-Ho; Yamamoto, Kazuyoshi; Yanagimoto, Yoshitomo; Sugimura, Keijirou; Miyata, Hiroshi; Yano, Masahiko; Sakon, Masato

2017-01-01

Intracorporeal esophagojejunostomy after laparoscopic total gastrectomy is technically difficult because this procedure should be performed in a narrow surgical field in the upper abdomen even when completely laparoscopic approaches are used. The placement of the anvil of a circular stapling device into the esophagus and connection the instrument to the anvil are extremely difficult steps in this surgery. Therefore, we developed a simple technique for intracorporeal esophagojejunostomy using hemi-double stapling technique; we named this technique the efficient purse-string stapling technique (EST). More recently, we have developed a modified EST (mEST) that utilizes a new stainless steel anvil rod instead of a plastic rod. Relative to the plastic rod, the steel rod is reusable and shorter; thus, it was easier to perform anvil placement into the esophagus with the steel rod. Anvil preparation for mEST: a stainless steel rod is attached to the shaft of the anvil, and the needle and thread are sutured to the tip of the rod. After complete insertion of the anvil into the esophageal cavity, the needle and thread are used to penetrate the anterior esophageal wall, and the esophagus is then clamped using a linear stapler just distal to the site penetrated by the thread. The linear stapler is fired, and anvil placement in the esophagus is simultaneously accomplished. After the rod is removed from the anvil, the instrument is intracorporeally connected to the anvil and then fired to complete the gastrojejunostomy. This technique is simple and facilitates intracorporeal reconstruction procedures in laparoscopic total gastrectomy. PMID:28815221

Global Variability of Mesoscale Convective System Anvil Structure from A-Train Satellite Data

NASA Technical Reports Server (NTRS)

Yuan, Jian; Houze, Robert A.

2010-01-01

Mesoscale convective systems (MCSs) in the tropics produce extensive anvil clouds, which significantly affect the transfer of radiation. This study develops an objective method to identify MCSs and their anvils by combining data from three A-train satellite instruments: Moderate Resolution Imaging Spectroradiometer (MODIS) for cloud-top size and coldness, Advanced Microwave Scanning Radiometer for Earth Observing System (AMSR-E) for rain area size and intensity, and CloudSat for horizontal and vertical dimensions of anvils. The authors distinguish three types of MCSs: small and large separated MCSs and connected MCSs. The latter are MCSs sharing a contiguous rain area. Mapping of the objectively identified MCSs shows patterns of MCSs that are consistent with previous studies of tropical convection, with separated MCSs dominant over Africa and the Amazon regions and connected MCSs favored over the warm pool of the Indian and west Pacific Oceans. By separating the anvil from the raining regions of MCSs, this study leads to quantitative global maps of anvil coverage. These maps are consistent with the MCS analysis, and they lay the foundation for estimating the global radiative effects of anvil clouds. CloudSat radar data show that the modal thickness of MCS anvils is about 4-5 km. Anvils are mostly confined to within 1.5-2 times the equivalent radii of the primary rain areas of the MCSs. Over the warm pool, they may extend out to about 5 times the rain area radii. The warm ocean MCSs tend to have thicker non-raining and lightly raining anvils near the edges

A new type of anvil in the Acheulian of Gesher Benot Ya'aqov, Israel.

PubMed

Goren-Inbar, Naama; Sharon, Gonen; Alperson-Afil, Nira; Herzlinger, Gadi

2015-11-19

We report here on the identification and characterization of thin basalt anvils, a newly discovered component of the Acheulian lithic inventory of Gesher Benot Ya'aqov (GBY). These tools are an addition to the array of percussive tools (percussors, pitted stones and anvils) made of basalt, flint and limestone. The thin anvils were selected from particularly compact, horizontally fissured zones of basalt flows. This type of fissuring produces a natural geometry of thick and thin slabs. Hominins at GBY had multiple acquisition strategies, including the selection of thick slabs for the production of giant cores and cobbles for percussors. The selection of thin slabs was carried out according to yet another independent and targeted plan. The thinness of the anvils dictated a particular range of functions. The use of the anvils is well documented on their surfaces and edges. Two main types of damage are identified: those resulting from activities carried out on the surfaces of the anvils and those resulting from unintentional forceful blows (accidents de travaille). Percussive activities that may have been associated with the thin anvils include nut cracking and the processing of meat and bones, as well as plants. © 2015 The Author(s).

Clamp force and alignment checking device

DOEpatents

Spicer, John Patrick; Cai, Wayne W.; Chakraborty, Debejyo; Mink, Keith

2017-04-11

A check fixture measures a total clamp force applied by a welder device. The welder device includes a welding horn having a plurality of weld pads and welding anvil having a plurality of weld pads. The check fixture includes a base member operatively supporting a plurality of force sensors. The base member and the force sensors are received between the weld pads of the welding horn and the anvil pads of the welding anvil. Each force sensor is configured to measure an individual clamp force applied thereto by corresponding weld and anvil pads when the base member is received between the welding horn and the welding anvil and the welder device is in the clamped position. The individual clamp forces are used to determine whether the weld and/or anvil pads are worn or misaligned.

Users Guide for the Anvil Threat Corridor Forecast Tool V1.7.0 for AWIPS

NASA Technical Reports Server (NTRS)

Bauman, William H., III

2007-01-01

The Applied Meteorology Unit (AMU) originally developed the Anvil Threat Sector Tool for the Meteorological Interactive Data Display System (MIDDS) and delivered the capability in three phases beginning with a feasibility study in 2000 and delivering the operational final product in December 2003. This tool is currently used operationally by the 45th Weather Squadron (45 WS) Launch Weather Officers (LWO) and Spaceflight Meteorology Group (SMG) forecasters. Phase I of the task established the technical feasibility of developing an objective, observations-based tool for short-range anvil forecasting. The AMU was subsequently tasked to develop short-term anvil forecasting tools to improve predictions of the threat of triggered lightning to space launch and landing vehicles. Under the Phase II effort, the AMU developed a nowcasting anvil threat sector tool, which provided the user with a threat sector based on the most current radiosonde upper wind data from a co-located or upstream station. The Phase II Anvil Threat Sector Tool computes the average wind speed and direction in the layer between 300 and 150 mb from the latest radiosonde for a user-designated station. The following threat sector properties are consistent with the propagation and lifetime characteristics of thunderstorm anvil clouds observed over Florida and its coastal waters (Short et al. 2002): a) 20 n mi standoff circle, b) 30 degree sector width, c) Orientation given by 300 to 150 mb average wind direction, d) 1-, 2-, and 3- hour arcs in upwind direction, and e) Arc distances given by 300 to 150 mb average wind speed. Figure 1 is an example of the MIDDS Anvil Threat Sector tool overlaid on a visible satellite image at 2132 UTC 13 May 2001. Space Launch Complex 39A was selected as the center point and the Anvil Threat Sector was determined from upper-level wind data at 1500 UTC in the preconvective environment. Narrow thunderstorm anvil clouds extend from central Florida to the space launch and landing facilities at the Kennedy Space Center (KSC) and Cape Canaveral Air Force Station (CCAFS) and beyond. The anvil clouds were generated around 1930 UTC (1430 EDT) by thunderstorm activity over central Florida and transported 90 n mi east-northeastward within 2 hours, as diagnosed by the anvil forecast tool. Phase III, delivered in February 2003, built upon the results of Phase II by enhancing the Anvil Threat Sector Tool with the capability to use national model forecast winds for depiction of potential anvil lengths and orientations over the KSC/CCAFS area with lead times from 3 through 168 hours (7 days). In September 2003, AMU customers requested the capability to use data from the KSC 50 MHz Doppler Radar Wind Profiler (DRWP) in the Anvil Threat Sector Tool and this capability was delivered by the AMU in December 2003. In March 2005, the AMU was tasked to migrate the MIDDS Anvil Threat Sector Tool capabilities onto the Advanced Weather Interactive Processing System (AWIPS) as the Anvil Threat Corridor Forecast Tool.

Anvil Tool in the Advanced Weather Interactive Processing System

NASA Technical Reports Server (NTRS)

Barrett, Joe, III; Bauman, William, III; Keen, Jeremy

2007-01-01

Meteorologists from the 45th Weather Squadron (45 WS) and Spaceflight Meteorology Group (SMG) have identified anvil forecasting as one of their most challenging tasks when predicting the probability of violations of the lightning Launch Commit Criteria and Space Shuttle Flight Rules. As a result, the Applied Meteorology Unit (AMU) created a graphical overlay tool for the Meteorological Interactive Data Display Systems (MIDDS) to indicate the threat of thunderstorm anvil clouds, using either observed or model forecast winds as input. In order for the Anvil Tool to remain available to the meteorologists, the AMU was tasked to transition the tool to the Advanced Weather interactive Processing System (AWIPS). This report describes the work done by the AMU to develop the Anvil Tool for AWIPS to create a graphical overlay depicting the threat from thunderstorm anvil clouds. The AWIPS Anvil Tool is based on the previously deployed AMU MIDDS Anvil Tool. SMG and 45 WS forecasters have used the MIDDS Anvil Tool during launch and landing operations. SMG's primary weather analysis and display system is now AWIPS and the 45 WS has plans to replace MIDDS with AWIPS. The Anvil Tool creates a graphic that users can overlay on satellite or radar imagery to depict the potential location of thunderstorm anvils one, two, and three hours into the future. The locations are based on an average of the upper-level observed or forecasted winds. The graphic includes 10 and 20 nm standoff circles centered at the location of interest, in addition to one-, two-, and three-hour arcs in the upwind direction. The arcs extend outward across a 30 degree sector width based on a previous AMU study which determined thunderstorm anvils move in a direction plus or minus 15 degrees of the upper-level (300- to 150-mb) wind direction. This report briefly describes the history of the MIDDS Anvil Tool and then explains how the initial development of the AWIPS Anvil Tool was carried out. After testing was performed by SMG, 45 WS, and AMU, a number of needed improvements were identified. A bug report document was created that showed the status of each bug and desired improvement. This report lists the improvements that were made to increase the accuracy and user-friendliness of the tool. Final testing was carried out and documented and then the final version of the software and Users Guide was provided to SMG and the 45 WS. Several possible future improvements to the tool are identified that would increase the flexibility of the tool. This report contains a brief history of the development of the Anvil Tool in MIDDS, and then describes the transition and development of software to AWIPS.

Wild capuchin monkeys (Cebus libidinosus) use anvils and stone pounding tools.

PubMed

Fragaszy, Dorothy; Izar, Patrícia; Visalberghi, Elisabetta; Ottoni, Eduardo B; de Oliveira, Marino Gomes

2004-12-01

We conducted an exploratory investigation in an area where nut-cracking by wild capuchin monkeys is common knowledge among local residents. In addition to observing male and female capuchin monkeys using stones to pound open nuts on stone "anvils," we surveyed the surrounding area and found physical evidence that monkeys cracked nuts on rock outcrops, boulders, and logs (collectively termed anvils). Anvils, which were identified by numerous shallow depressions on the upper surface, the presence of palm shells and debris, and the presence of loose stones of an appropriate size to pound nuts, were present even on the tops of mesas. The stones used to crack nuts can weigh >1 kg, and are remarkably heavy for monkeys that weigh <4 kg. The abundance of shell remains and depressions in the anvil surface at numerous anvil sites indicate that nut-cracking activity is common and long-enduring. Many of the stones found on anvils (presumably used to pound nuts) are river pebbles that are not present in the local area we surveyed (except on or near the anvils); therefore, we surmise that they were transported to the anvil sites. Ecologically and behaviorally, nut-cracking by capuchins appears to have strong parallels to nut-cracking by wild chimpanzees. The presence of abundant anvil sites, limited alternative food resources, abundance of palms, and the habit of the palms in this region to produce fruit at ground level all likely contribute to the monkeys' routine exploitation of palm nuts via cracking them with stones. This discovery provides a new reference point for discussions regarding the evolution of tool use and material culture in primates. Routine tool use to exploit keystone food resources is not restricted to living great apes and ancestral hominids. Copyright 2004 Wiley-Liss, Inc.

Cirrus Simulations of CRYSTAL-FACE 23 July 2002 Case

NASA Technical Reports Server (NTRS)

Starr, David; Lin, Ruci-Fong; Demoz, Belay; Lare, Andrew

2004-01-01

A key objective of the Cirrus Regional Study of Tropical Anvils and Cirrus Layers - Florida Area Cirrus Experiment (CRYSTAL-FACE) is to understand relationships between the properties of tropical convective cloud systems and the properties and lifecycle of the extended cirrus anvils they produce. We report here on a case study of 23 July 2002 where a sequence of convective storms over central Florida produced an extensive anvil outflow. Our approach is to use a suitably-initialized cloud-system simulation with MM5 to define initial conditions and time-dependent forcing for a simulation of anvil evolution using a two-dimensional fine-resolution (100 m) cirrus cloud model that explicitly accounts for details of cirrus microphysical development (bin or spectra model) and fully interactive radiative processes. The cirrus model follows Lin. Meteorological conditions and observations for the 23 July case are described in this volume. The goals of the present study are to evaluate how well we can simulate a cirrus anvil lifecycle, to evaluate the importance of various physical processes that operate within the anvil, and to evaluate the importance of environmental conditions in regulating anvil lifecycle. CRYSTAL-FACE produced a number of excellent case studies of anvil systems that will allow environmental factors, such as static stability or wind shear in the upper troposphere, to be examined. In the present study, we strive to assess the importance of propagating gravity waves, likely produced by the deep convection itself, and radiative processes, to anvil lifecycle and characteristics.

Development of Kawai-type multianvil technology using nano-polycrystalline diamond anvils

NASA Astrophysics Data System (ADS)

Irifune, T.; Kunimoto, T.

2016-12-01

Nano-polycrystalline diamond (NPD) developed at GRC, Ehime Univ., is known to be much harder than conventional sintered polycrystalline diamond (SD), and is potentially important as material for anvils for Kawai-type (6-8 type) multianvil apparatus (KMA), as well as for diamond anvil cell. We synthesized NPD rods with about 8 mm in both diameter and length using a 6000-ton press KMA (BOTCHAN-6000), which are cut by pulsed-laser to form cubes with 6 mm edge length and tested them as anvils for KMA. In situ X-ray observations were made to evaluate the produced pressures and sample images using the "6-6-8 assembly". A combination of semi-fired pyrophyllite gaskets and alumina ceramics pressure medium optimized for the NPD anvils with a truncation (TEL) of 1.0 mm yielded pressures up to 88 GPa at a press load of only 3.4 MN, which is nearly 60% higher than the pressure (56 GPa) reached using SD anvils with the identical cell assembly at the same press load. Moreover, the high X-ray transparency of NPD has enabled us to clearly see the sample image via the anvils, allowing diffraction measurements and observations of the sample shape even if the anvil gap becomes very small under such very high pressures. The use of NPD anvils should lead to new technology for mineral physics studies under the conditions of the Earth's lowermost mantle and possibly those of the core without scarifying the advantages of KMA over DAC.

Pressure mapping for sphere and half-sphere enhanced diamond anvil cells using synchrotron x-ray diffraction and fluorescence techniques

NASA Astrophysics Data System (ADS)

Liu, H.; Liu, L. L.; Cai, Z.; Shu, J.

2015-12-01

The measurement for equation of state (EoS) of materials under pressure conditions above 200 GPa is a long-standing challenging subject. Recently, second stage anvil, which was loaded inside the diamond anvil cell (DAC), had been reported by various groups. This method could generate pressure over 300 GPa, or above 600 GPa from the EoS measurement of Re metal between the tiny anvil or 2 half-spheres. Several alternative approaches, using ruby balls, or glassy carbon, or diamond, with single sphere, 2 half-spheres, or multi spheres geometry inside DAC, were tested. The NIST X-ray powder standard, ZnO was selected as pressure marker. Focused ion beam (FIB) was used to cut the half-sphere from diamond anvil top directly to avoid the difficulty of alignment. The synchrotron x-ray diffraction with fine beam size down to 100 nm using zone plate set-up was used to map the pressure gradient at the sphere or half-sphere zone inside DAC. The pressure could be boosted at center of sphere by up to 10 - 70 GPa at about 200 GPa conditions. From broken anvils, trace element analysis using fine focusing synchrotron x-ray fluorescence method revealed the potential anvil damage from FIB cutting the diamond anvil tip, which might decrease the strength of anvils. Fine touch from FIB cutting at final stage using low ion beam current is suggested.

Anvil for Flaring PCB Guide Pins

NASA Technical Reports Server (NTRS)

Winn, E.; Turner, R.

1985-01-01

Spring-loaded anvil results in fewer fractured pins. New anvil for flaring guide pins in printed-circuit boards absorbs approximately 80 percent of press force. As result fewer pins damaged, and work output of flaring press greatly increased.

Process for Nondestructive Evaluation of the Quality of a Crimped Wire Connector

NASA Technical Reports Server (NTRS)

Yost, William T. (Inventor); Cramer, Karl E. (Inventor); Perey, Daniel F. (Inventor); Williams, Keith A. (Inventor)

2014-01-01

A process and apparatus for collecting data for nondestructive evaluation of the quality of a crimped wire connector are provided. The process involves providing a crimping tool having an anvil and opposing jaw for crimping a terminal onto a stranded wire, moving the jaw relative to the anvil to close the distance between the jaw and the anvil and thereby compress the terminal against the wire, while transmitting ultrasonic waves that are propagated through the terminal-wire combination and received at a receiving ultrasonic transducer as the jaw is moved relative to the anvil, and detecting and recording the position of the jaw relative to the anvil as a function of time and detecting and recording the amplitude of the ultrasonic wave that is received at the receiving ultrasonic transducer as a function of time as the jaw is moved relative to the anvil.

Acoustic detection of cracks in the anvil of a large-volume cubic high-pressure apparatus

NASA Astrophysics Data System (ADS)

Yan, Zhaoli; Chen, Bin; Tian, Hao; Cheng, Xiaobin; Yang, Jun

2015-12-01

A large-volume cubic high-pressure apparatus with three pairs of tungsten carbide anvils is the most popular device for synthetic diamond production. Currently, the consumption of anvils is one of the important costs for the diamond production industry. If one of the anvils is fractured during the production process, the other five anvils in the apparatus may be endangered as a result of a sudden loss of pressure. It is of critical importance to detect and replace cracked anvils before they fracture for reduction of the cost of diamond production and safety. An acoustic detection method is studied in this paper. Two new features, nested power spectrum centroid and modified power spectrum variance, are proposed and combined with linear prediction coefficients to construct a feature vector. A support vector machine model is trained for classification. A sliding time window is proposed for decision-level information fusion. The experiments and analysis show that the recognition rate of anvil cracks is 95%, while the false-alarm rate is as low as 5.8 × 10-4 during a time window; this false-alarm rate indicates that at most one false alarm occurs every 2 months at a confidence level of 90%. An instrument to monitor anvil cracking was designed based on a digital signal processor and has been running for more than eight months in a diamond production field. In this time, two anvil-crack incidents occurred and were detected by the instrument correctly. In addition, no false alarms occurred.

Acoustic detection of cracks in the anvil of a large-volume cubic high-pressure apparatus

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yan, Zhaoli, E-mail: zl-yan@mail.ioa.ac.cn; Tian, Hao; Cheng, Xiaobin

2015-12-15

A large-volume cubic high-pressure apparatus with three pairs of tungsten carbide anvils is the most popular device for synthetic diamond production. Currently, the consumption of anvils is one of the important costs for the diamond production industry. If one of the anvils is fractured during the production process, the other five anvils in the apparatus may be endangered as a result of a sudden loss of pressure. It is of critical importance to detect and replace cracked anvils before they fracture for reduction of the cost of diamond production and safety. An acoustic detection method is studied in this paper.more » Two new features, nested power spectrum centroid and modified power spectrum variance, are proposed and combined with linear prediction coefficients to construct a feature vector. A support vector machine model is trained for classification. A sliding time window is proposed for decision-level information fusion. The experiments and analysis show that the recognition rate of anvil cracks is 95%, while the false-alarm rate is as low as 5.8 × 10{sup −4} during a time window; this false-alarm rate indicates that at most one false alarm occurs every 2 months at a confidence level of 90%. An instrument to monitor anvil cracking was designed based on a digital signal processor and has been running for more than eight months in a diamond production field. In this time, two anvil-crack incidents occurred and were detected by the instrument correctly. In addition, no false alarms occurred.« less

Advances in circular stapling technique for gastric bypass: transoral placement of the anvil.

PubMed

Nguyen, Ninh T; Hinojosa, Marcelo W; Smith, Brian R; Reavis, Kevin M; Wilson, Samuel E

2008-05-01

In Roux-en-Y gastric bypass, construction of the gastrojejunostomy is commonly performed using a circular stapler. The initial description for placement of the anvil was via the transoral approach. Although the concept was ingenious, technical difficulty was encountered during passage resulting in complications such as hypopharyngeal perforation and esophageal mucosal injury. As a result, most surgeons subsequently changed their route of anvil placement to the transabdominal approach. Advances in stapler technology now allow the head of the anvil to be pre-tilted, permitting transoral introduction with greater ease and safety. This paper describes this improved method for transoral placement of the anvil during laparoscopic gastric bypass and reoperative bariatric surgery.

On the existence of tropical anvil clouds

NASA Astrophysics Data System (ADS)

Seeley, J.; Jeevanjee, N.; Langhans, W.; Romps, D.

2017-12-01

In the deep tropics, extensive anvil clouds produce a peak in cloud cover below the tropopause. The dominant paradigm for cloud cover attributes this anvil peak to a layer of enhanced mass convergence in the clear-sky upper-troposphere, which is presumed to force frequent detrainment of convective anvils. However, cloud cover also depends on the lifetime of cloudy air after it detrains, which raises the possibility that anvil clouds may be the signature of slow cloud decay rather than enhanced detrainment. Here we measure the cloud decay timescale in cloud-resolving simulations, and find that cloudy updrafts that detrain in the upper troposphere take much longer to dissipate than their shallower counterparts. We show that cloud lifetimes are long in the upper troposphere because the saturation specific humidity becomes orders of magnitude smaller than the typical condensed water loading of cloudy updrafts. This causes evaporative cloud decay to act extremely slowly, thereby prolonging cloud lifetimes in the upper troposphere. As a consequence, extensive anvil clouds still occur in a convecting atmosphere that is forced to have no preferential clear-sky convergence layer. On the other hand, when cloud lifetimes are fixed at a characteristic lower-tropospheric value, extensive anvil clouds do not form. Our results support a revised understanding of tropical anvil clouds, which attributes their existence to the microphysics of slow cloud decay rather than a peak in clear-sky convergence.

Development of Designer Diamond Anvils for High Pressure-High-Temperature Experiments in Support of the Stockpile Stewardship Program

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yogesh K. Vohra

The focus of this program at the University of Alabama at Birmingham (UAB) is to develop the next generation of designer diamond anvils that can perform simultaneous joule heating and temperature profile measurements in a diamond anvil cell. A series of tungsten-rhenium thermocouples will be fabricated onto to the anvil and encapsulated by a chemical vapor deposited diamond layer to allow for a complete temperature profile measurement across the anvil. The tip of the diamond anvil will be engineered to reduce the thermal conductivity so that the tungsten-heating coils can be deposited on top of this layer. Several different approachesmore » will be investigated to engineer the tip of the diamond anvil for reduction in thermal conductivity (a) isotopic mixture of 12C and 13C in the diamond layer, (b) doping of diamond with impurities (nitrogen and/or boron), and (c) growing diamond in a higher concentration of methane in hydrogen plasma. Under this academic alliance with Lawrence Livermore National Laboratory (LLNL), PI and his graduate students will use the lithographic and diamond polishing facility at LLNL. This proposed next generation of designer diamond anvils will allow multi-tasking capability with the ability to measure electrical, magnetic, structural and thermal data on actinide materials with unparallel sensitivity in support of the stockpile stewardship program.« less

Injection of Lightning-Produced NOx, Water Vapor, Wildfire Emissions, and Stratospheric Air to the UT/LS as Observed from DC3 Measurements

NASA Astrophysics Data System (ADS)

Huntrieser, H.; Lichtenstern, M.; Scheibe, M.; Aufmhoff, H.; Schlager, H.; Minikin, A.; Weinzierl, B.; Pollack, I. B.; Peischl, J.; Ryerson, T. B.; Weinheimer, A. J.; Honomichl, S.; Ridley, B. A.; Hair, J. W.; Schwartz, M. J.; Rappenglück, B.; Pickering, K. E.; Cummings, K.; Biggerstaff, M. I.; Heimerl, K.; Pucik, T.; Fütterer, D.; Ackermann, L.; Betten, D.; Butler, C. F.; Barth, M. C.

2015-12-01

In summer 2012 the Deep Convective Clouds and Chemistry Project (DC3) field campaign investigated a number of severe thunderstorms over the Central U.S. and their impact on the upper tropospheric (UT) - lower stratospheric (LS) composition and chemistry. In addition, during DC3 some of the largest and most destructive wildfires in New Mexico and Colorado state history were burning, influencing the air quality in the DC3 thunderstorm inflow and outflow region. Besides three instrumented aircraft platforms measuring a variety of trace species in-situ and remotely (e.g. CO, O3, SO2, NOx, VOC, CN, and black carbon), dense networks of ground-based instruments (e.g. radar and lightning) complemented the airborne measurements. Satellite measurements (e.g. GOES, MODIS, and GOME-2) and model forecasts (e.g. WRF-Chem and FLEXPART) were used to monitor the rapid development of the thunderstorms (which frequently developed huge anvils with overshooting tops) and the spread of smoke plumes in the vicinity of the storms. In-situ probing of fresh and aged (12-24 h) anvil outflows showed injection of lightning-produced NOx and wildfire emissions into the UTLS. Vertical cross sections of lidar and Doppler radar measurements supported these observations and gave detailed information on dynamical processes within and in the vicinity of the storms. Besides very strong updrafts in the storm core, surrounding downdrafts caused a direct in-mixing of O3-rich LS air masses into the boundaries of the anvil outflow. The wrapping of O3-rich LS air masses around and below the anvil outflow was also a prominent feature in several storms. The in-situ probing of the aged anvil outflow showed a pronounced influence on the UT composition and chemistry with average O3 enhancements in the range of 20-50 nmol mol-1 and evidence of new particle formation. A 10-year global climatology of H2O data from Aura-MLS confirms that the Central U.S. is a preferred region for convective injection into the LS.

Injection of Lightning-Produced NOx, Water Vapor, Wildfire Emissions, and Stratospheric Air to the UT/LS as Observed from DC3 Measurements

NASA Astrophysics Data System (ADS)

Huntrieser, H.; Lichtenstern, M.; Scheibe, M.; Aufmhoff, H.; Schlager, H.; Minikin, A.; Weinzierl, B.; Pollack, I. B.; Peischl, J.; Ryerson, T. B.; Weinheimer, A. J.; Honomichl, S.; Ridley, B. A.; Hair, J. W.; Schwartz, M. J.; Rappenglück, B.; Pickering, K. E.; Cummings, K.; Biggerstaff, M. I.; Heimerl, K.; Pucik, T.; Fütterer, D.; Ackermann, L.; Betten, D.; Butler, C. F.; Barth, M. C.

2014-12-01

In summer 2012 the Deep Convective Clouds and Chemistry Project (DC3) field campaign investigated a number of severe thunderstorms over the Central U.S. and their impact on the upper tropospheric (UT) - lower stratospheric (LS) composition and chemistry. In addition, during DC3 some of the largest and most destructive wildfires in New Mexico and Colorado state history were burning, influencing the air quality in the DC3 thunderstorm inflow and outflow region. Besides three instrumented aircraft platforms measuring a variety of trace species in-situ and remotely (e.g. CO, O3, SO2, NOx, VOC, CN, and black carbon), dense networks of ground-based instruments (e.g. radar and lightning) complemented the airborne measurements. Satellite measurements (e.g. GOES, MODIS, and GOME-2) and model forecasts (e.g. WRF-Chem and FLEXPART) were used to monitor the rapid development of the thunderstorms (which frequently developed huge anvils with overshooting tops) and the spread of smoke plumes in the vicinity of the storms. In-situ probing of fresh and aged (12-24 h) anvil outflows showed injection of lightning-produced NOx and wildfire emissions into the UTLS. Vertical cross sections of lidar and Doppler radar measurements supported these observations and gave detailed information on dynamical processes within and in the vicinity of the storms. Besides very strong updrafts in the storm core, surrounding downdrafts caused a direct in-mixing of O3-rich LS air masses into the boundaries of the anvil outflow. The wrapping of O3-rich LS air masses around and below the anvil outflow was also a prominent feature in several storms. The in-situ probing of the aged anvil outflow showed a pronounced influence on the UT composition and chemistry with average O3 enhancements in the range of 20-50 nmol mol-1 and evidence of new particle formation. A 10-year global climatology of H2O data from Aura-MLS confirms that the Central U.S. is a preferred region for convective injection into the LS.

GEWEX Cloud System Study (GCSS) Working Group on Cirrus Cloud Systems (WG2)

NASA Technical Reports Server (NTRS)

Starr, David

2002-01-01

Status, progress and plans will be given for current GCSS (GEWEX Cloud System Study) WG2 (Working Group on Cirrus Cloud Systems) projects, including: (a) the Idealized Cirrus Model Comparison Project, (b) the Cirrus Parcel Model Comparison Project (Phase 2), and (c) the developing Hurricane Nora extended outflow model case study project. Past results will be summarized and plans for the upcoming year described. Issues and strategies will be discussed. Prospects for developing improved cloud parameterizations derived from results of GCSS WG2 projects will be assessed. Plans for NASA's CRYSTAL-FACE (Cirrus Regional Study of Tropical Anvils and Layers - Florida Area Cirrus Experiment) potential opportunities for use of those data for WG2 model simulations (future projects) will be briefly described.

Demonstration of a Large-Scale Tank Assembly Via Circumferential Friction Stir Welds

NASA Technical Reports Server (NTRS)

Jones, Chip; Adams, Glynn; Colligan, Kevin; McCool, A. (Technical Monitor)

2000-01-01

Five (5) each 14-foot diameter circumferential FSWelds were conducted on the modified CWT, two (2) each pathfinder and three (3) each assembly welds Tapered circumferential welds were successfully demonstrated The use of a closeout anvil was successfully demonstrated during one of the pathfinder welds Considerable difficulty maintaining joint f it-up during the weld process Anvil deflections Hardware dimensional tolerances Inadequate clamping Variations in the heat sink characteristics of the circumferential anvil as compared to the test panel anvil

Cirrus Simulations of CRYSTAL-FACE 23 July 2002 Case

NASA Technical Reports Server (NTRS)

Starr, David; Lin, Ruei-Fong; Demoz, Belay; Lare, Andrew

2004-01-01

A key objective of the Cirrus Regional Study of Tropical Anvils and Cirrus Layers - Florida Area Cirrus Experiment (CRYSTAL-FACE) is to understand relationships between the properties of tropical convective cloud systems and the properties and lifecycle of the extended cirrus anvils they produce. We report here on a case study of 23 July 2002 where a sequence of convective storms over central Florida produced an extensive anvil outflow. Our approach is to use a suitably-initialized cloud- system simulation with MM5 (Starr et al., companion paper in this volume) to define initial conditions and time-dependent forcing for a simulation of anvil evolution using a two-dimensional fine-resolution (100 m) cirrus cloud model that explicitly accounts for details of cirrus microphysical development (bin or spectra model) and fully interactive radiative processes. The cirrus model follows Lin (1997). The microphysical components are described in Lin et al. (2004) - see Lin et a1 (this volume). Meteorological conditions and observations for the 23 July case are described in Starr et al. (this volume). The goals of the present study are to evaluate how well we can simulate a cirrus anvil lifecycle, to evaluate the importance of various physical processes that operate within the anvil, and to evaluate the importance of environmental conditions in regulating anvil lifecycle. CRYSTAL-FACE produced a number of excellent case studies of anvil systems that will allow environmental factors, such as static stability or wind shear in the upper troposphere, to be examined. In the present study, we strive to assess the importance of propagating gravity waves, likely produced by the deep convection itself, and radiative processes, to anvil lifecycle and characteristics.

21 CFR 882.4030 - Skull plate anvil.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 21 Food and Drugs 8 2011-04-01 2011-04-01 false Skull plate anvil. 882.4030 Section 882.4030 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) MEDICAL DEVICES NEUROLOGICAL DEVICES Neurological Surgical Devices § 882.4030 Skull plate anvil. (a...

Progress of research to identify rotating thunderstorms using satellite imagery

NASA Technical Reports Server (NTRS)

Anderson, Charles E.

1988-01-01

The possibility of detecting potentially tornadic thunderstorm cells from geosynchronous satelite imagery is determined. During the life of the contract, we examined eight tornado outbreak cases which had a total of 124 individual thunderstorm cells, 37 of which were tornadic.These 37 cells produced a total of 119 tornadoes. The outflow characteristics of all the cells were measured. Through the use of a 2-D flow field model, we were able to simulate the downstream developmemt of an anvil cloud plume which was emitted by the storm updraft at or near the tropopause. We used two parameters to characterize the anvil plume behavior: its speed of downstream propagation (U max) and the clockwise deviation of the centerline of the anvil plume from the storm relative ambient wind at the anvil plume outflow level (MDA). U max was the maximum U-component of the anvil wind parameter required to successfully maintain an envelope of translating particles at the tip of the expanding anvil cloud. MDA was the measured deviation angle acquired from McIDAS, between the storm relative ambient wind direction and the storm relative anvil plume outflow direction; tha latter being manipulated by controlling a tangential wind component to force the envelope of particles to maintain their position of surrounding the expanding outflow cloud.

User Guide for the Anvil Threat Cooridor Forecast Tool V2.4 for AWIPS

NASA Technical Reports Server (NTRS)

Barett, Joe H., III; Bauman, William H., III

2008-01-01

The Anvil Tool GUI allows users to select a Data Type, toggle the map refresh on/off, place labels, and choose the Profiler Type (source of the KSC 50 MHz profiler data), the Date- Time of the data, the Center of Plot, and the Station (location of the RAOB or 50 MHz profiler). If the Data Type is Models, the user selects a Fcst Hour (forecast hour) instead of Station. There are menus for User Profiles, Circle Label Options, and Frame Label Options. Labels can be placed near the center circle of the plot and/or at a specified distance and direction from the center of the circle (Center of Plot). The default selection for the map refresh is "ON". When the user creates a new Anvil Tool map with Refresh Map "ON, the plot is automatically displayed in the AWIPS frame. If another Anvil Tool map is already displayed and the user does not change the existing map number shown at the bottom of the GUI, the new Anvil Tool map will overwrite the old one. If the user turns the Refresh Map "OFF", the new Anvil Tool map is created but not automatically displayed. The user can still display the Anvil Tool map through the Maps dropdown menu* as shown in Figure 4.

Observed Enhancement of Reflectivity and Electric Field in Long-Lived Florida Anvils

NASA Technical Reports Server (NTRS)

Dye, James E.; Willett, John C.

2007-01-01

A study of two long-lived Florida anvils showed that reflectivity >20 dBZ increased in area, thickness and sometimes magnitude at mid-level well downstream of the convective cores. In these same regions electric fields maintained strengths >10 kV m1 for many tens of minutes and became quite uniform over tens of kilometers. Millimetric aggregates persisted at 9 to 10 km for extended times and distances. Aggregation of ice particles enhanced by strong electric fields might have contributed to reflectivity growth in the early anvil, but is unlikely to explain observations further out in the anvil. The enhanced reflectivity and existence of small, medium and large ice particles far out into the anvil suggest that an updraft was acting, perhaps in weak convective cells formed by instability generated from the evaporation and melting of falling ice particles. We conclude that charge separation must have occurred in these anvils, perhaps at the melting level but also at higher altitudes, in order to maintain fields >10 kV m 1 at 9 to 10 km for extended periods of time over large distances. We speculate that charge separation occurred as a result of ice-ice particle collisions (without supercooled water being present) via either a non-inductive or perhaps even an inductive mechanism, given the observed broad ice particle spectra, the strong pre-existing electric fields and the many tens of minutes available for particle interactions. The observations, particularly in the early anvil, show that the charge structure in these anvils was quite complex.

Vertical Structures of Anvil Clouds of Tropical Mesoscale Convective Systems Observed by CloudSat

NASA Technical Reports Server (NTRS)

Hence, Deanna A.; Houze, Robert A.

2011-01-01

A global study of the vertical structures of the clouds of tropical mesoscale convective systems (MCSs) has been carried out with data from the CloudSat Cloud Profiling Radar. Tropical MCSs are found to be dominated by cloud-top heights greater than 10 km. Secondary cloud layers sometimes occur in MCSs, but outside their primary raining cores. The secondary layers have tops at 6 8 and 1 3 km. High-topped clouds extend outward from raining cores of MCSs to form anvil clouds. Closest to the raining cores, the anvils tend to have broader distributions of reflectivity at all levels, with the modal values at higher reflectivity in their lower levels. Portions of anvil clouds far away from the raining core are thin and have narrow frequency distributions of reflectivity at all levels with overall weaker values. This difference likely reflects ice particle fallout and therefore cloud age. Reflectivity histograms of MCS anvil clouds vary little across the tropics, except that (i) in continental MCS anvils, broader distributions of reflectivity occur at the uppermost levels in the portions closest to active raining areas; (ii) the frequency of occurrence of stronger reflectivity in the upper part of anvils decreases faster with increasing distance in continental MCSs; and (iii) narrower-peaked ridges are prominent in reflectivity histograms of thick anvil clouds close to the raining areas of connected MCSs (superclusters). These global results are consistent with observations at ground sites and aircraft data. They present a comprehensive test dataset for models aiming to simulate process-based upper-level cloud structure around the tropics.

Vertical Structures of Anvil Clouds of Tropical Mesoscale Convective Systems Observed by CloudSat

NASA Technical Reports Server (NTRS)

Yuan, J.; Houze, R. A., Jr.; Heymsfield, A.

2011-01-01

A global study of the vertical structures of the clouds of tropical mesoscale convective systems (MCSs) has been carried out with data from the CloudSat Cloud Profiling Radar. Tropical MCSs are found to be dominated by cloud-top heights greater than 10 km. Secondary cloud layers sometimes occur in MCSs, but outside their primary raining cores. The secondary layers have tops at 6--8 and 1--3 km. High-topped clouds extend outward from raining cores of MCSs to form anvil clouds. Closest to the raining cores, the anvils tend to have broader distributions of reflectivity at all levels, with the modal values at higher reflectivity in their lower levels. Portions of anvil clouds far away from the raining core are thin and have narrow frequency distributions of reflectivity at all levels with overall weaker values. This difference likely reflects ice particle fallout and therefore cloud age. Reflectivity histograms of MCS anvil clouds vary little across the tropics, except that (i) in continental MCS anvils, broader distributions of reflectivity occur at the uppermost levels in the portions closest to active raining areas; (ii) the frequency of occurrence of stronger reflectivity in the upper part of anvils decreases faster with increasing distance in continental MCSs; and (iii) narrower-peaked ridges are prominent in reflectivity histograms of thick anvil clouds close to the raining areas of connected MCSs (superclusters). These global results are consistent with observations at ground sites and aircraft data. They present a comprehensive test dataset for models aiming to simulate process-based upper-level cloud structure around the tropics.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hunt, Simon A., E-mail: simon.hunt@ucl.ac.uk; McCormack, Richard J.; Bailey, Edward

A new multi-anvil deformation apparatus, based on the widely used 6-8 split-cylinder, geometry, has been developed which is capable of deformation experiments at pressures in excess of 18 GPa at room temperature. In 6-8 (Kawai-type) devices eight cubic anvils are used to compress the sample assembly. In our new apparatus two of the eight cubes which sit along the split-cylinder axis have been replaced by hexagonal cross section anvils. Combining these anvils hexagonal-anvils with secondary differential actuators incorporated into the load frame, for the first time, enables the 6-8 multi-anvil apparatus to be used for controlled strain-rate deformation experiments to highmore » strains. Testing of the design, both with and without synchrotron-X-rays, has demonstrated the Deformation T-Cup (DT-Cup) is capable of deforming 1–2 mm long samples to over 55% strain at high temperatures and pressures. To date the apparatus has been calibrated to, and deformed at, 18.8 GPa and deformation experiments performed in conjunction with synchrotron X-rays at confining pressures up to 10 GPa at 800 °C.« less

Automated method for determining Instron Residual Seal Force of glass vial/rubber closure systems.

PubMed

Ludwig, J D; Nolan, P D; Davis, C W

1993-01-01

Instron Residual Seal Force (IRSF) of glass vial/rubber closure systems was determined using an Instron 4501 Materials Testing System. Computer programs were written to process raw data and calculate IRSF values. Preliminary experiments indicated both the appearance of the stress-deformation curves and precision of the derived IRSF values were dependent on the internal dimensions and top surface geometry of the cap anvil. Therefore, a series of five cap anvils varying in shape and dimensions were machined to optimize performance and precision. Vials capped with West 4416/50 PURCOAT button closures or Helvoet compound 6207 lyophilization closures were tested with each cap anvil. Cap anvils with spherical top surfaces and narrow internal dimensions produced more precise results and more uniform stress-deformation curves than cap anvils with flat top surfaces and wider internal dimensions.

Actively controlled vibration welding system and method

DOEpatents

Cai, Wayne W.; Kang, Bongsu; Tan, Chin-An

2013-04-02

A vibration welding system includes a controller, welding horn, an active material element, and anvil assembly. The assembly may include an anvil body connected to a back plate and support member. The element, e.g., a piezoelectric stack or shape memory alloy, is positioned with respect to the assembly. The horn vibrates in a desirable first direction to form a weld on a work piece. The element controls any vibrations in a second direction by applying calibrated response to the anvil body in the second direction. A method for controlling undesirable vibrations in the system includes positioning the element with respect to the anvil assembly, connecting the anvil body to the support member through the back plate, vibrating the horn in a desirable first direction, and transmitting an input signal to the element to control vibration in an undesirable second direction.

Electrical structure in two thunderstorm anvil clouds

NASA Technical Reports Server (NTRS)

Marshall, Thomas C.; Rust, W. David; Winn, William P.; Gilbert, Kenneth E.

1989-01-01

Electrical structures in two thunderstorm anvil clouds (or 'anvils'), one in New Mexico, the other in Oklahoma, were investigated, using measurements of electric field by balloon-carried instruments and a one-dimensional model to calculate the time and spatial variations of electrical parameters in the clear air below the anvil. The electric field soundings through the two thunderstorm anvils showed similar charge structures; namely, negatively charged screening layers on the top and the bottom surfaces, a layer of positive charge in the interior, and one or two layers of zero charge. It is suggested that the positive charge originated in the main positive charge region normally found at high altitudes in the core of thunderclouds, and the negatively charged layers probably formed as screening layers, resulting from the discontinuity in the electrical conductivity at the cloud boundaries.

Anvil Glaciation in a Deep Cumulus Updraught over Florida Simulated with the Explicit Microphysics Model. I: Impact of Various Nucleation Processes

NASA Technical Reports Server (NTRS)

Phillips, Vaughan T. J.; Andronache, Constantin; Sherwood, Steven C.; Bansemer, Aaron; Conant, William C.; Demott, Paul J.; Flagan, Richard C.; Heymsfield, Andy; Jonsson, Haflidi; Poellot, Micheal;

Thread gauge for tapered threads

DOEpatents

Brewster, Albert L.

1994-01-11

The thread gauge permits the user to determine the pitch diameter of tapered threads at the intersection of the pitch cone and the end face of the object being measured. A pair of opposed anvils having lines of threads which match the configuration and taper of the threads on the part being measured are brought into meshing engagement with the threads on opposite sides of the part. The anvils are located linearly into their proper positions by stop fingers on the anvils that are brought into abutting engagement with the end face of the part. This places predetermined reference points of the pitch cone of the thread anvils in registration with corresponding points on the end face of the part being measured, resulting in an accurate determination of the pitch diameter at that location. The thread anvils can be arranged for measuring either internal or external threads.

Thread gauge for tapered threads

DOEpatents

Brewster, A.L.

1994-01-11

The thread gauge permits the user to determine the pitch diameter of tapered threads at the intersection of the pitch cone and the end face of the object being measured. A pair of opposed anvils having lines of threads which match the configuration and taper of the threads on the part being measured are brought into meshing engagement with the threads on opposite sides of the part. The anvils are located linearly into their proper positions by stop fingers on the anvils that are brought into abutting engagement with the end face of the part. This places predetermined reference points of the pitch cone of the thread anvils in registration with corresponding points on the end face of the part being measured, resulting in an accurate determination of the pitch diameter at that location. The thread anvils can be arranged for measuring either internal or external threads. 13 figures.

Double bevel construction of a diamond anvil

DOEpatents

Moss, W.C.

1988-10-11

A double or multiple bevel culet geometry is used on a diamond anvil in a high pressure cell apparatus to provide increased sample pressure and stability for a given force applied to the diamond tables. Double or multiple bevel culet geometries can also be used for sapphire or other hard crystal anvils. Pressures up to and above 5 Megabars can be reached. 8 figs.

Double bevel construction of a diamond anvil

DOEpatents

Moss, William C.

1988-01-01

A double or multiple bevel culet geometry is used on a diamond anvil in a high pressure cell apparatus to provide increased sample pressure and stability for a given force applied to the diamond tables. Double or multiple bevel culet geometries can also be used for sapphire or other hard crystal anvils. Pressures up to and above 5 Megabars can be reached.

Diamond anvil cells using boron-doped diamond electrodes covered with undoped diamond insulating layer

NASA Astrophysics Data System (ADS)

Matsumoto, Ryo; Yamashita, Aichi; Hara, Hiroshi; Irifune, Tetsuo; Adachi, Shintaro; Takeya, Hiroyuki; Takano, Yoshihiko

2018-05-01

Diamond anvil cells using boron-doped metallic diamond electrodes covered with undoped diamond insulating layers have been developed for electrical transport measurements under high pressure. These designed diamonds were grown on a bottom diamond anvil via a nanofabrication process combining microwave plasma-assisted chemical vapor deposition and electron beam lithography. The resistance measurements of a high-quality FeSe superconducting single crystal under high pressure were successfully demonstrated by just putting the sample and gasket on the bottom diamond anvil directly. The superconducting transition temperature of the FeSe single crystal was increased to up to 43 K by applying uniaxial-like pressure.

Thread gauge for measuring thread pitch diameters

DOEpatents

Brewster, A.L.

1985-11-19

A thread gauge which attaches to a vernier caliper to measure the thread pitch diameter of both externally threaded and internally threaded parts is disclosed. A pair of anvils are externally threaded with threads having the same pitch as those of the threaded part. Each anvil is mounted on a stem having a ball on which the anvil can rotate to properly mate with the parts to which the anvils are applied. The stems are detachably secured to the caliper blades by attachment collars having keyhole openings for receiving the stems and caliper blades. A set screw is used to secure each collar on its caliper blade. 2 figs.

Thread gauge for measuring thread pitch diameters

DOEpatents

Brewster, Albert L.

1985-01-01

A thread gauge which attaches to a vernier caliper to measure the thread pitch diameter of both externally threaded and internally threaded parts. A pair of anvils are externally threaded with threads having the same pitch as those of the threaded part. Each anvil is mounted on a stem having a ball on which the anvil can rotate to properly mate with the parts to which the anvils are applied. The stems are detachably secured to the caliper blades by attachment collars having keyhole openings for receiving the stems and caliper blades. A set screw is used to secure each collar on its caliper blade.

Analysis of in situ measurements of cirrus anvil outflow dynamics

NASA Astrophysics Data System (ADS)

Lederman, J. I.; Whiteway, J. A.

2012-12-01

The airborne campaign, EMERALD 2 (Egrett Microphysics Experiment with Radiation, Lidar, and Dynamics,) was conducted out of Darwin, Australia in 2002. Objectives included characterization of the dynamics in the cirrus anvil outflow from tropical deep convection. Two aircraft, the Egrett and King Air, were flown in tandem in the upper troposphere (7 km - 15 km) to collect in situ measurements in the anvil outflow from a storm named "Hector" that occurs on a regular basis over the Tiwi Islands north of Darwin during November and December. Turbulence probes mounted on the wings of the Egrett aircraft were used to measure the wind fluctuations across the anvil and along its length with a spatial resolution of 2 meters. The in situ measurements from the Egrett were coincident with lidar measurements of the cloud structure from the King Air aircraft flying directly below. The presentation will show results of the analysis of the measurements with an emphasis on the turbulence, gravity waves, and coherent structures that are particular to the cirrus anvil outflow environment. Emphasis is placed on the dynamics associated with the generation of mammatus formations at the base of the anvil clouds.

i-anvils : in situ measurements of pressure, temperature and conductivity in diamond anvil cells

NASA Astrophysics Data System (ADS)

Munsch, P.; Bureau, H.; Kubsky, S.; Meijer, J.; Datchi, F.; Ninet, S.; Estève, I.

2011-12-01

The precise determination of the pressure and temperature conditions during diamond anvils cells (DAC) experiments is of primary importance. Such determinations are critical more especially for the fields corresponding to "low pressures" (<4 GPa) and moderate temperature (600-1500°C). Determining the electrical properties of mantle minerals is also a condition to understand the physics of the Deep Earth. This has to be done in situ at pressures and temperatures relevant for the interior of the Earth. i-anvils allow in situ pressure (P) and temperature (T) measurements in experiments using a DAC. Boron and carbon micro-structures are implanted in the diamond anvil lattice a few micrometers below the surface, the sensors are located a few μm below the center of the diamond culet (sample chamber position). When conductive electrodes are implanted at the position of the sample chamber on the culet of the anvil, instead of P,T sensors, they allow in situ measurements of electrical properties of the loaded sample at high P,T conditions in a DAC. The principle consists of applying an electrical potential across the structures through external contacts placed on the slopes of the anvil. The resistivity of these structures is sensitive to pressure and temperature applied in the sample chamber. The electrical transport properties of the sample can be measured the same way when electrodes have been implanted on the culet. Here we will present our last progresses, more especially using the focus ion beam (FIB) technology to perform contacts and electrodes. Progresses about the i-anvils connexions with the electronic devices will also be shown. We will present the last P and T sensors calibrations. Furnaces are also introduced through Boron implantation into the anvils, allowing the possibility to reach intermediate temperatures between externally heated DAC (up to 1100°C) and laser heated DAC (from 1500°C to a few thousands). Preliminary tests and the interest of such devices will be discussed at the meeting. A new diamond anvil cell has been especially designed for this purpose. This DAC allows in situ spectroscopies and X-Ray characterisation of geological fluids in their equilibrium conditions in the crust and in the upper mantle. Preliminary results will be presented.

Community Extreme Tonnage User Service (CETUS): A 5000 Ton Open Research Facility in the United States

NASA Astrophysics Data System (ADS)

Danielson, L. R.; Righter, K.; Vander Kaaden, K. E.; Rowland, R. L., II; Draper, D. S.; McCubbin, F. M.

2017-12-01

Large sample volume 5000 ton multi-anvil presses have contributed to the exploration of deep Earth and planetary interiors, synthesis of ultra-hard and other novel materials, and serve as a sample complement to pressure and temperature regimes already attainable by diamond anvil cell experiments. However, no such facility exists in the Western Hemisphere. We are establishing an open user facility for the entire research community, with the unique capability of a 5000 ton multi-anvil and deformation press, HERA (High pressure Experimental Research Apparatus), supported by a host of extant co-located experimental and analytical laboratories and research staff. We offer wide range of complementary and/or preparatory experimental options. Any required synthesis of materials or follow up experiments can be carried out controlled atmosphere furnaces, piston cylinders, multi-anvil, or experimental impact apparatus. Additionally, our division houses two machine shops that would facilitate any modification or custom work necessary for development of CETUS, one for general fabrication and one located specifically within our experimental facilities. We also have a general sample preparation laboratory, specifically for experimental samples, that allows users to quickly and easily prepare samples for ebeam analyses and more. Our focus as contract staff is on serving the scientific needs of our users and collaborators. We are seeking community expert input on multiple aspects of this facility, such as experimental assembly design, module modifications, immediate projects, and future innovation initiatives. We've built a cooperative network of 12 (and growing) collaborating institutions, including COMPRES. CETUS is a coordinated effort leveraging HERA with our extant experimental, analytical, and planetary process modelling instrumentation and expertise in order to create a comprehensive model of the origin and evolution of our solar system and beyond. We are looking to engage the community in how the CETUS facility can best serve your needs.

Mesoanalysis of record Chicago rainstorm using radar, satellite, and rain-gage data

NASA Technical Reports Server (NTRS)

Fujita, T. T.

1977-01-01

Comparison of cloud-top topography and rainfall rates at the surface revealed that the areas of heavy rain are located where there are depressions at the anvil top. It was also found that the Z-R relationships show a large scatter when vertical and/or horizontal air currents are strong. Results of this research led to Project NIMROD proposed to begin in May 1978.

A new 6-axis apparatus to squeeze the Kawai-cell of sintered diamond cubes

NASA Astrophysics Data System (ADS)

Ito, Eiji; Katsura, Tomoo; Yamazaki, Daisuke; Yoneda, Akira; Tado, Masashi; Ochi, Takahiro; Nishibara, Eiichi; Nakamura, Akihiro

2009-05-01

In order to overcome disadvantages of the DIA type press in squeezing the Kawai-cell, such as uneven compression between the upper and lower anvils and the four surrounding anvils and frictional loss of applied load in the guide block, we have developed a new 6-axis apparatus in which the movements of the six anvils are controlled by a servo mechanism. It is possible to keep the Kawai-cell cubic within an accuracy of ±2 μm during compression and decompression. Pressure generation using sintered diamond cubic anvils with edge length of 14.0 mm and a truncation of 1.5 mm has been carried out up to ca. 60 GPa by measuring electrical resistance of GaP, Zr, and Fe 2O 3. The results are compared with our previous calibration, carried out using an almost the same sample setup for identical anvils at SPring-8, by means of in situ X-ray observation. It is demonstrated that a significant amount of the applied load is lost by friction when the Kawai-cell is squeezed in the DIA type press. The load loss increases with increasing load, or pressure, and amounts to 45% at ca. 60 GPa. Therefore the 6-axis apparatus is very advantageous to generate higher pressures in the Kawai-cell. However, individual control of the anvils sometimes induces a runaway advancement of the anvils which brings about an abrupt increase of pressure.

The relation of the yield stress of high-pressure anvils to the pressure attained at yielding and the ultimate attainable pressure

NASA Technical Reports Server (NTRS)

Panda, P. C.; Ruoff, A. L.

1979-01-01

A sensitive microprofilometer was used to determine the onset of yielding in the anvils of a supported opposed anvil device for the case of 3% cobalt-cemented tungsten carbide as the anvil material. In addition, it is shown how the commencement of yielding in boron carbide pistons, the yield strength being known, can be used to obtain the transition pressure to a conducting phase in gallium phosphide. The transition pressures of bismuth and gallium phosphide are obtained and it is found that these transitions are extremely close to the maximum attainable pressure in, respectively, a maraging steel and a 3% cobalt-cemented tungsten carbide.

Implementation of micro-ball nanodiamond anvils for high-pressure studies above 6 Mbar

PubMed Central

Dubrovinsky, Leonid; Dubrovinskaia, Natalia; Prakapenka, Vitali B; Abakumov, Artem M

2012-01-01

Since invention of the diamond anvil cell technique in the late 1950s for studying materials at extreme conditions, the maximum static pressure generated so far at room temperature was reported to be about 400 GPa. Here we show that use of micro-semi-balls made of nanodiamond as second-stage anvils in conventional diamond anvil cells drastically extends the achievable pressure range in static compression experiments to above 600 GPa. Micro-anvils (10–50 μm in diameter) of superhard nanodiamond (with a grain size below ∼50 nm) were synthesized in a large volume press using a newly developed technique. In our pilot experiments on rhenium and gold we have studied the equation of state of rhenium at pressures up to 640 GPa and demonstrated the feasibility and crucial necessity of the in situ ultra high-pressure measurements for accurate determination of material properties at extreme conditions. PMID:23093199

Reduction of Raman scattering and fluorescence from anvils in high pressure Raman scattering

NASA Astrophysics Data System (ADS)

Dierker, S. B.; Aronson, M. C.

2018-05-01

We describe a new design and use of a high pressure anvil cell that significantly reduces the Raman scattering and fluorescence from the anvils in high pressure Raman scattering experiments. The approach is particularly useful in Raman scattering studies of opaque, weakly scattering samples. The effectiveness of the technique is illustrated with measurements of two-magnon Raman scattering in La2CuO4.

Accurate temperature measurement by temperature field analysis in diamond anvil cell for thermal transport study of matter under high pressures

NASA Astrophysics Data System (ADS)

Yue, Donghui; Ji, Tingting; Qin, Tianru; Wang, Jia; Liu, Cailong; Jiao, Hui; Zhao, Lin; Han, Yonghao; Gao, Chunxiao

2018-02-01

The study on the thermal transport properties of matter under high pressure is important but is hard to fulfill in a diamond anvil cell (DAC) because the accurate measurement of the temperature gradient within the sample of DAC is very difficult. In most cases, the sample temperature can be read accurately from the thermocouples that are directly attached to the lateral edges of diamond anvils because both the sample and diamond anvils can be uniformly heated up to a given temperature. But for the thermal transport property studies in DAC, an artificial temperature distribution along the compression axis is a prerequisite. Obviously, the temperature of the top or bottom surface of the sample cannot be substituted by that of diamond anvils although diamond anvils can be considered as a good medium for heat conduction. With temperature field simulation by finite element analysis, it is found that big measurement errors can occur and are fatal to the correct analysis of thermal transport properties of materials. Thus, a method of combining both the four-thermocouple configuration and temperature field analysis is presented for the accurate temperature distribution measurement in DAC, which is based on the single-function relationship between temperature distribution and sample thermal conductivity.

Dependence of Cumulus Anvil Radiative Properties on Environmental Conditions in the Tropical West Pacific

NASA Technical Reports Server (NTRS)

Ye, B.; DelGenio, A. D.

1999-01-01

Areally extensive, optically thick anvil clouds associated with mesoscale convective clusters dominate the shortwave cloud forcing in the tropics and provide longwave forcing comparable to that of thin cirrus. Changes in the cover and optical thickness of tropical anvils as climate warms can regulate the sign of cloud feedback. As a prelude to the study of MMCR data from the ARM TWP sites, we analyze ISCCP-derived radiative characteristics of anvils observed in the tropical west Pacific during the TOGA-COARE IOP. Anvils with radius greater than 100 km were identified and tracked from inception to decay using the Machado-Rossow algorithm. Corresponding environmental conditions just prior to the start of the convectove event were diagnosed using the Lin-Johnson objective analysis product. Small clusters (100-200 km radius) are observed to have a broad range of optical thicknesses (10-50), while intermediate optical thickness clusters are observed to range in size from 100 km to almost 1000 km. Large-size clusters appear to be favored by strong pre-storm large scale upward motion throughout the troposphere, moist low-to-midlevel relative humidities, environments with slightly higher CAPE than those for smaller clusters, and strong front-to-rear flow. Optically thick anvils are favored in situations of strong low-level moisture convergence and strong upper-level shear.

Temperature compensated high-temperature/high-pressure Merrill--Bassett diamond anvil cell

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schiferl, D.

1987-07-01

A Merrill--Bassett diamond anvil cell for high-temperature/high-pressure studies up to 5 GPa at 1000 K and 13 GPa at 725 K is described. To maintain uniform, well-characterized temperatures, and to protect the diamond anvils from oxidation and graphitization, the entire cell is heated in a vacuum oven. The materials are chosen so that the pressure remains constant to within +-10% over the entire temperature range.

Optically detected magnetic resonance of nitrogen vacancies in a diamond anvil cell using designer diamond anvils

DOE Office of Scientific and Technical Information (OSTI.GOV)

Steele, L. G.; Lawson, M.; Onyszczak, M.

Optically detected magnetic resonance of nitrogen vacancy centers in diamond offers a route to both DC and AC magnetometry in diamond anvil cells under high pressures (>3 GPa). However, a serious challenge to realizing experiments has been the insertion of microwave radiation into the sample space without screening by the gasket material. We utilize designer anvils with lithographically deposited metallic microchannels on the diamond culet as a microwave antenna. We detected the spin resonance of an ensemble of microdiamonds under pressure and measured the pressure dependence of the zero field splitting parameters. Furthermore, these experiments enable the possibility for all-opticalmore » magnetic resonance experiments on nanoliter sample volumes at high pressures.« less

Optically detected magnetic resonance of nitrogen vacancies in a diamond anvil cell using designer diamond anvils

DOE PAGES

Steele, L. G.; Lawson, M.; Onyszczak, M.; ...

2017-11-28

Optically detected magnetic resonance of nitrogen vacancy centers in diamond offers a route to both DC and AC magnetometry in diamond anvil cells under high pressures (>3 GPa). However, a serious challenge to realizing experiments has been the insertion of microwave radiation into the sample space without screening by the gasket material. We utilize designer anvils with lithographically deposited metallic microchannels on the diamond culet as a microwave antenna. We detected the spin resonance of an ensemble of microdiamonds under pressure and measured the pressure dependence of the zero field splitting parameters. Furthermore, these experiments enable the possibility for all-opticalmore » magnetic resonance experiments on nanoliter sample volumes at high pressures.« less

Automated method for determining Instron Residual Seal Force of glass vial/rubber closure systems. Part II. 13 mm vials.

PubMed

Ludwig, J D; Davis, C W

1995-01-01

Instron Residual Seal Force (IRSF) of 13 mm glass vial/rubber closure systems was determined using an Instron 4501 Materials Testing System and computerized data analysis. A series of three cap anvils varying in shape and dimensions were machined to optimize cap anvil performance. Cap anvils with spherical top surfaces and narrow internal dimensions produced uniform stress-deformation curves from which precise IRSF values were derived.

New diamond cell for single-crystal x-ray diffraction

NASA Astrophysics Data System (ADS)

Boehler, Reinhard

2006-11-01

A new design for a high-precision diamond cell is described. Two kinematically mounted steel disks are elastically deflected to generate pressure. This principle provides higher precision in the diamond anvil alignment than most sliding piston-cylinder or guide-pin devices at significantly lower cost. With this new diamond cell conical diamond anvils with an x-ray aperture of 85° were successfully tested to over 50GPa using helium as a pressure medium. Anvil thickness of less than 1.4mm provides high x-ray transmission and low background, a significant improvement compared to beryllium or diamond-disk backing plates. Because the diamond anvils are supported by tungsten carbide seats, samples and pressure media can be annealed by external or laser heating to provide hydrostatic pressure conditions.

Design of a Helmet Liner for Improved Low Velocity Impact Protection

DTIC Science & Technology

2013-05-01

FIGURE 14. MONORAIL DROP TEST WITH DOT-SIZE C HEADFORM AND HEMISPHERICAL ANVIL ........................... 14  FIGURE 15. ACH PAD CONFIGURATION. LEFT...materials. In this project, the monorail drop test device, used for the helmeted headform drop test, was modified for material testing as shown in Figure...a guided free fall drop test using a monorail drop test apparatus as shown in Figure 14. All helmets tested in this study were ACH-Size Large and

Anvil Forecast Tool in the Advanced Weather Interactive Processing System, Phase II

NASA Technical Reports Server (NTRS)

Barrett, Joe H., III

2008-01-01

Meteorologists from the 45th Weather Squadron (45 WS) and Spaceflight Meteorology Group have identified anvil forecasting as one of their most challenging tasks when predicting the probability of violations of the Lightning Launch Commit Criteria and Space Light Rules. As a result, the Applied Meteorology Unit (AMU) created a graphical overlay tool for the Meteorological Interactive Data Display Systems (MIDDS) to indicate the threat of thunderstorm anvil clouds, using either observed or model forecast winds as input.

Validation Testing and Numerical Modeling of Advanced Armor Materials

DTIC Science & Technology

2012-11-01

Rigid Anvil A ground steel high-hard plate was placed in front of a massive block of steel that was anchored to the gun table. After every shot, the...photovoltaic sensors • 15.24-cm RHA steel block with a 1.27-cm thick high hard steel anvil plate The following instruments/equipment was used to perform...Range 167 was prepared using the 2.77-cm bore gas operated gun, an RHA anvil block with a high hard steel faceplate that was surface polished, and a

Using the VAHIRR Radar Algorithm to Investigate Lightning Cessation

NASA Technical Reports Server (NTRS)

Stano, Geoffrey T.; Schultz, Elise V.; Petersen, Walter A.

2012-01-01

Accurately determining the threat posed by lightning is a major area for improved operational forecasts. Most efforts have focused on the initiation of lightning within a storm, with far less effort spent investigating lightning cessation. Understanding both components, initiation and cessation, are vital to improving lightning safety. Few organizations actively forecast lightning onset or cessation. One such organization is the 45th Weather Squadron (45WS) for the Kennedy Space Center (KSC) and Cape Canaveral Air Force Station (CCAFS). The 45WS has identified that charged anvil clouds remain a major threat of continued lightning and can greatly extend the window of a potential lightning strike. Furthermore, no discernable trend of total lightning activity has been observed consistently for all storms. This highlights the need for more research to find a robust method of knowing when a storm will cease producing lightning. Previous lightning cessation work has primarily focused on forecasting the cessation of cloud-to -ground lightning only. A more recent, statistical study involved total lightning (both cloud-to-ground and intracloud). Each of these previous works has helped the 45WS take steps forward in creating improved and ultimately safer lightning cessation forecasts. Each study has either relied on radar data or recommended increased use of radar data to improve cessation forecasts. The reasoning is that radar data is able to either directly or by proxy infer more about dynamical environment leading to cloud electrification and eventually lightning cessation. The authors of this project are focusing on a two ]step approach to better incorporate radar data and total lightning to improve cessation forecasts. This project will utilize the Volume Averaged Height Integrated Radar Reflectivity (VAHIRR) algorithm originally developed during the Airborne Field Mill II (ABFM II) research project. During the project, the VAHIRR product showed a trend of increasing values with increases in the electric field magnitude above 3 kV/m. An extreme value analysis showed that VAHIRR values less than or equal to 10 dBZ-km showed that the probability of having an electric field magnitude larger than 3 kV/m was less than one in ten thousand. VAHIRR also was found to be sensitive at indicating anvil clouds that posed a threat of initiating a lightning flash. This project seeks to use VAHIRR to analyze its utility as a lightning cessation tool, particularly dealing with the threat posed by detached anvils. The results from this project will serve as a baseline effectiveness of radar ]based lightning cessation algorithms. This baseline will be used in the second, and concurrent work by the co ]author fs who are developing a lightning cessation algorithm based on dual ]polarimetric radar data. Ultimately, an accurate method for identifying lightning cessation can save money on lost manpower time as well as greatly improve lightning safety.

Convectively Generated Gravity Waves In The Tropical Stratosphere: Case Studies And Importance For The Circulation Of The Middle Atmosphere

NASA Technical Reports Server (NTRS)

Pfister, Leonhard; Chan, Kwoklong R.; Gary, Bruce; Singh, Hanwant B. (Technical Monitor)

1995-01-01

The advent of high altitude aircraft measurements in the stratosphere over tropical convective systems has made it possible to observe the mesoscale disturbances in the temperature field that these systems excite. Such measurements show that these disturbances have horizontal scales comparable to those of the underlying anvils (about 50-100 km) with peak to peak theta surface variations of about 300-400 meters. Moreover, correlative wind measurements from the tropical phase of the Stratosphere-Troposphere Exchange Project (STEP) clearly show that these disturbances are gravity waves. We present two case studies of anvil-scale gravity waves over convective systems. Using steady and time-dependent linear models of gravity wave propagation in the stratosphere, we show: (1) that the underlying convective systems are indeed the source of the observed phenomena; and (2) that their generating mechanism can be crudely represented as flow over a time-dependent mountain. We will then discuss the effects gravity waves of the observed amplitudes have on the circulation of the middle atmosphere, particularly the quasi-biennial, and semiannual oscillations.

Pressure generation to 50 GPa in Kawai-type multianvil apparatus using newly developed tungsten carbide anvils

NASA Astrophysics Data System (ADS)

Kunimoto, Takehiro; Irifune, Tetsuo; Tange, Yoshinori; Wada, Kouhei

2016-04-01

A pressure generation test for Kawai-type multianvil apparatus (KMA) has been made using second-stage anvils of a newly developed ultra-hard tungsten carbide composite. Superb performance of the new anvil with significantly less plastic deformation was confirmed as compared to those commonly used for the KMA experiments. A maximum pressure of ∼48 GPa was achieved using the new anvils with a truncation edge length (TEL) of 1.5 mm, based on in situ X-ray diffraction measurements. Further optimization of materials and sizes of the pressure medium/gasket should lead to pressures even higher than 50 GPa in KMA using this novel tungsten carbide composite, which may also be used for expansion of the pressure ranges in other types of high pressure apparatus operated in large volume press.

High-pressure resistivity technique for quasi-hydrostatic compression experiments.

PubMed

Rotundu, C R; Ćuk, T; Greene, R L; Shen, Z-X; Hemley, Russell J; Struzhkin, V V

2013-06-01

Diamond anvil cell techniques are now well established and powerful methods for measuring materials properties to very high pressure. However, high pressure resistivity measurements are challenging because the electrical contacts attached to the sample have to survive to extreme stress conditions. Until recently, experiments in a diamond anvil cell were mostly limited to non-hydrostatic or quasi-hydrostatic pressure media other than inert gases. We present here a solution to the problem by using focused ion beam ultrathin lithography for a diamond anvil cell loaded with inert gas (Ne) and show typical resistivity data. These ultrathin leads are deposited on the culet of the diamond and are attaching the sample to the anvil mechanically, therefore allowing for measurements in hydrostatic or nearly hydrostatic conditions of pressure using noble gases like Ne or He as pressure transmitting media.

Pressure induced phase transitions studies using advanced synchrotron techniques

NASA Astrophysics Data System (ADS)

Liu, Haozhe; Liu, Lisa; Zhao, Jinggeng; HIT Overseas Collaborative Base at Argonne Collaboration

2013-06-01

In this presentation, the joint effort on high pressure research through program of Harbin Institute of Technology (HIT) Overseas Collaborative Base at Argonne will be introduced. Selected research projects on pressure induced phase transitions at room temperature and high/low temperature conditions, such as A2B3 type topological insulators, iron arsenide superconductors, piezoelectric/ferroelectric materials, ABO3 type single crystals and metallic glasses, will be presented. Recent development on imaging and diffraction tomography techniques in diamond anvil cell will be reviewed as well.

Note: Novel diamond anvil cell for electrical measurements using boron-doped metallic diamond electrodes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Matsumoto, R.; Sasama, Y.; Yamaguchi, T.

2016-07-15

A novel diamond anvil cell suitable for electrical transport measurements under high pressure has been developed. A boron-doped metallic diamond film was deposited as an electrode on a nano-polycrystalline diamond anvil using a microwave plasma-assisted chemical vapor deposition technique combined with electron beam lithography. The maximum pressure that can be achieved by this assembly is above 30 GPa. We report electrical transport measurements of Pb up to 8 GPa. The boron-doped metallic diamond electrodes showed no signs of degradation after repeated compression.

Wild bearded capuchin monkeys (Sapajus libidinosus) strategically place nuts in a stable position during nut-cracking.

PubMed

Fragaszy, Dorothy M; Liu, Qing; Wright, Barth W; Allen, Angellica; Brown, Callie Welch; Visalberghi, Elisabetta

2013-01-01

Humans can use hand tools smoothly and effectively in varying circumstances; in other words, skillfully. A few other species of primates crack encased foods using hammer tools and anvils. Are they skilled? Positioning the food on the anvil so that it does not fall off when struck is a component of skilled cracking. We discovered that bearded capuchin monkeys deliberately place palm nuts in a relatively stable position on the anvil before striking them. In the first experiment, we marked the meridians of palm nuts where they stopped when rolled on a flat surface ("Stop meridian"). We videotaped monkeys as they cracked these nuts on an anvil. In playback we coded the position of the Stop meridian prior to each strike. Monkeys typically knocked the nuts on the anvil a few times before releasing them in a pit. They positioned the nuts so that the Stop meridian was within 30 degrees of vertical with respect to gravity more often than expected, and the nuts rarely moved after the monkeys released them. In the second experiment, 14 blindfolded people (7 men) asked to position marked nuts on an anvil as if to crack them reliably placed them with the Stop meridian in the same position as the monkeys did. In the third experiment, two people judged that palm nuts are most bilaterally symmetric along a meridian on, or close to, the Stop meridian. Thus the monkeys reliably placed the more symmetrical side of the nuts against the side of the pit, and the nuts reliably remained stationary when released. Monkeys apparently used information gained from knocking the nut to achieve this position. Thus, monkeys place the nuts skillfully, strategically managing the fit between the variable nuts and pits in the anvil, and skilled placement depends upon information generated by manual action.

Wild Bearded Capuchin Monkeys (Sapajus libidinosus) Strategically Place Nuts in a Stable Position during Nut-Cracking

PubMed Central

Fragaszy, Dorothy M.; Liu, Qing; Wright, Barth W.; Allen, Angellica; Brown, Callie Welch; Visalberghi, Elisabetta

2013-01-01

Humans can use hand tools smoothly and effectively in varying circumstances; in other words, skillfully. A few other species of primates crack encased foods using hammer tools and anvils. Are they skilled? Positioning the food on the anvil so that it does not fall off when struck is a component of skilled cracking. We discovered that bearded capuchin monkeys deliberately place palm nuts in a relatively stable position on the anvil before striking them. In the first experiment, we marked the meridians of palm nuts where they stopped when rolled on a flat surface (“Stop meridian”). We videotaped monkeys as they cracked these nuts on an anvil. In playback we coded the position of the Stop meridian prior to each strike. Monkeys typically knocked the nuts on the anvil a few times before releasing them in a pit. They positioned the nuts so that the Stop meridian was within 30 degrees of vertical with respect to gravity more often than expected, and the nuts rarely moved after the monkeys released them. In the second experiment, 14 blindfolded people (7 men) asked to position marked nuts on an anvil as if to crack them reliably placed them with the Stop meridian in the same position as the monkeys did. In the third experiment, two people judged that palm nuts are most bilaterally symmetric along a meridian on, or close to, the Stop meridian. Thus the monkeys reliably placed the more symmetrical side of the nuts against the side of the pit, and the nuts reliably remained stationary when released. Monkeys apparently used information gained from knocking the nut to achieve this position. Thus, monkeys place the nuts skillfully, strategically managing the fit between the variable nuts and pits in the anvil, and skilled placement depends upon information generated by manual action. PMID:23460793

31. FORGE, ANVIL, POWER FORGE HAMMER (FRONT TO BACK), AND ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

31. FORGE, ANVIL, POWER FORGE HAMMER (FRONT TO BACK), AND DOORWAY INTO MAIN SHOP-LOOKING SOUTHWEST. - W. A. Young & Sons Foundry & Machine Shop, On Water Street along Monongahela River, Rices Landing, Greene County, PA

Space treatments of insecticide for control of dengue virus vector Aedes aegypti in southern Mexico. I. Baseline penetration trials in open field and houses.

PubMed

Arrendondo-Jimenez, Juan I; Rivero, Norma E

2006-06-01

We studied the efficacy of space ultra-low volume treatments of 3 insecticides for the control of the dengue virus vector Aedes aegypti in southern Mexico. Insecticides tested were permethrin (Aqua-Reslin Super), d-phenothrin (Anvil), and cyfluthrin (Solfac), applied at rates of 10.87, 7.68, and 2 g/ha, respectively, by using London Fog, HP910-PHXL, or Micro-Gen pumps mounted on vehicles. Studies included 1) open field penetration tests and 2) house penetration tests. Open field tests indicated that Anvil and Solfac were more effective than Aqua-Reslin Super. In house tests, Anvil yielded the highest mosquito mortalities (>/=88%) of the three insecticides in the front porch, living room, bedroom, and backyard. Therefore, Anvil proved to be better than other insecticides evaluated to control Ae. aegypti in Chiapas, Mexico.

Pressure Self-focusing Effect and Novel Methods for Increasing the Maximum Pressure in Traditional and Rotational Diamond Anvil Cells.

PubMed

Feng, Biao; Levitas, Valery I

2017-04-21

The main principles of producing a region near the center of a sample, compressed in a diamond anvil cell (DAC), with a very high pressure gradient and, consequently, with high pressure are predicted theoretically. The revealed phenomenon of generating extremely high pressure gradient is called the pressure self-focusing effect. Initial analytical predictions utilized generalization of a simplified equilibrium equation. Then, the results are refined using our recent advanced model for elastoplastic material under high pressures in finite element method (FEM) simulations. The main points in producing the pressure self-focusing effect are to use beveled anvils and reach a very thin sample thickness at the center. We find that the superposition of torsion in a rotational DAC (RDAC) offers drastic enhancement of the pressure self-focusing effect and allows one to reach the same pressure under a much lower force and deformation of anvils.

On the Importance of Small Ice Crystals in Tropical Anvil Cirrus

NASA Technical Reports Server (NTRS)

Jensen, E. J.; Lawson, P.; Baker, B.; Pilson, B.; Mo, Q.; Heymsfield, A. J.; Bansemer, A.; Bui, T. P.; McGill, M.; Hlavka, D.;

Characteristics of flash initiations in a supercell cluster with tornadoes

NASA Astrophysics Data System (ADS)

Zheng, Dong; MacGorman, Donald R.

2016-01-01

Flash initiations within a supercell cluster during 10-11 May 2010 in Oklahoma were investigated based on observations from the Oklahoma Lightning Mapping Array and the Norman, Oklahoma, polarimetric radar (KOUN). The flash initiations at positions dominated by graupel, dry snow, small hail and crystals accounted for 44.3%, 44.1%, 8.0% and 3.0% of the total flashes, respectively. During the tornadic stage of the southern supercell in the cluster, flash initiations associated with graupel occupied the main body, the right flank and the forward flank of the supercell, while those associated with dry snow dominated the outskirts of the adjacent forward anvil, right anvil and rear anvil. The flash initiations associated with small hail were concentrated around the main updraft, particularly toward its front side. Highly dense flash initiations were located in the regions overlying the differential reflectivity (ZDR) arc and right anvil. The average initial height of the flashes decreased gradually from the rear to the front and from the right to the left flanks, while the height range over which initiations occurred reached a maximum at the front of the updraft. The flashes that were initiated in the adjacent forward anvils were largest on average, followed by those in the regions ahead of the updraft and near the ZDR arc. This study supports the concept of charge pockets and further deduces that the pockets in the right anvil are the most abundant and compact due to the frequent flash initiations, small-sized flashes and thin layers including flash initiations.

Development of Capabilities for New Experimental Studies on the Elasticity and Rheology of Lower Mantle Minerals

NASA Astrophysics Data System (ADS)

Triplett, R.; Weidner, D.; Whitaker, M. L.; Chen, H.; Li, L.

2017-12-01

Key mineralogical components of the mid-mantle of the Earth have historically been difficult to obtain elasticity data on because they either cannot be recovered to ambient conditions (e.g. calcium silicate perovskite) or back-transform during experimental preparation (e.g. magnesium silicate perovskite). Recently the conditions of the mid-mantle (14+ GPa, 1500+ K) and even of the lower mantle (24+ GPa, 1800+ K) have become reachable using multi-anvil apparatuses (MAA) with in-situ synchrotron x-ray capabilities, but the capabilities of these facilities have not yet fully matured. Examples include that reaching such pressures typically results in samples that are too small for ultrasonics, the few ultrasonics experiments done at these conditions have extremely limited x-ray visibility, and rheological experiments that apply differential stress have not been done at these conditions on large volume samples. The pressure reachable in a Large Volume Press (LVP) is limited by the properties of available ultra-hard (UH) materials such as tungsten carbide (WC) and x-ray transparent polycrystalline diamond (PCD) and cubic boron nitride (cBN). A key factor is the interaction of 1st stage anvils and anvils of UH materials; obtaining WC anvils of larger size is prohibitive in both capability and cost, and anvils of hardened steel are limited in the tonnage that can be applied before damage occurs. Other complications include the difference in compressibility between WC and PCD/cBN anvils and the availability of WC with simultaneous high compressive strength (pressure gain per tonnage) and high transverse rupture strength (lower chance of blowout and reusability). The DT25 press to be used at the new NSLS-II beamline XPD-D is a Kawaii-style LVP MAA which accepts 25 mm UH 2nd-stage anvils and has the capability to apply a differential load while at extreme conditions. We report on our development of techniques to do new and expanded experiments at lower mantle conditions utilizing the large anvil size and advances in UH materials, in particular ultrasonic studies and rheological experiments, with our goal being to routinely reach lower mantle pressures and temperatures with large volume samples while retaining the ability to gather x-ray diffraction data along a majority of the circumference of the Debye-Scherrer rings.

Development of a double-stage DDIA apparatus and its application to in-situ melting experiments at high pressures

NASA Astrophysics Data System (ADS)

Jing, Z.; Wang, Y.; Tange, Y.; Hilairet, N.; Yu, T.; Sakamaki, T.

2010-12-01

Melting experiments at high pressures are critical to our studies on the chemical evolution and dynamics of Earth and other terrestrial planets. A large volume press can generate a homogeneous and stable high-temperature environment, which is the key to melting experiments. However, previous in-situ melting experiments using a large volume press were often restricted to relatively low pressures. In order to expand the P-T conditions, a double-stage 6-8 configuration (6 first-stage anvils and 8 second stage-anvils) has been developed in a DDIA apparatus (DDIA-30), recently installed at the GSECARS Beamline 13-ID-D at the Advanced Photon Source. 27 mm DIA-type first-stage anvils and 14 mm second-stage anvils with the truncation edge length (TEL) of 1.5 mm are employed. A cell assembly that is suitable for synchrotron X-ray studies developed by Tange et al. (2008) has been adopted for melting experiments. High pressure and temperature conditions are generated up to 27 GPa and 2473 K by using tungsten carbide anvils, and up to 35 GPa and 1773 K by using sintered diamond anvils. Both LaCrO3 and TiB2 heater materials have been successfully applied for high-temperature generation. Although TiB2 shows a decrease of resistance at temperatures higher than 2000 K at 20 GPa, we are able to achieve 2473 K with temperature fluctuations in the range of ±30 K. Using tungsten carbide anvils and TiB2 heaters, we have determined the melting curve of gold up to 20 GPa. We constrain the melting temperature based on the disappearance of the gold peaks in energy dispersive X-ray diffraction patterns and the change of sample shape in the radiographic images. The combination of these two observations can reduce the uncertainties in melting temperatures to within 100 K. The measured melting temperatures of gold at 8, 13, and 20 GPa are consistent with the low-pressure results (up to 6 GPa) such as Mirwald and Kennedy (1979). Melting experiments with sintered diamond anvils are currently under development. This will enable us to conduct melting experiments up to 50 GPa on Fe alloys and silicates.

Electronic Structuring of Diamond Anvils - New Advances and Possibilities for HP Research

NASA Astrophysics Data System (ADS)

Burchard, M.; Zaitsev, A.; Meijer, J.; Stephan, A.; Maresch, W. V.

2001-12-01

DACs are powerful tools in high-pressure research, combining the principal advantages of transparency with the very HP attainable with this device. Nevertheless, a serious drawback for many in situ applications is the lack of a sufficiently precise method for determining the actual P in the sample volume. Hydrothermal DAC designs relying on the EOS of the P medium are susceptible to a number of potential sources of inaccuracy. One solution to this problem is the use of electronic sensors obtained by the structured HT, high-energy implantation of boron ions into the anvil culets of the DAC [1]. Recently, the sensitivity of such sensors at P in the GPa range has been successively improved from 20 [2] to 0.2 MPa [3], far surpassing that of any spectroscopic method. In addition, such P-sensing structures can also be used as temperature sensors, with a precision of 0.01 K [3]. To clarify and understand the principles on which these sensors function, we have performed conductivity and hall-effect measurements down to 4 K. The sensors show three conductivity mechanisms, depending on the T range involved. The HT (> 300K) mechanism is based on the activation of B acceptors in the diamond lattice. The two mechanisms at lower T are related to a defect conductivity. Because of these specific defect mechanisms the sensor structures are still operative at temperatures down to 4 K. A problem affecting HT DACs arises from heating via external resistance coils [4]. In such DACs the anvil seats are the weakest link and limit the force that can be applied to the anvils. Even when made of WC, the seats may deform considerably at P as low as 0.3 GPa at 1100 K. To overcome this drawback, we have implanted internal resistance heaters directly into the anvils next to the sample volume. These heaters are also composed of B-doped diamond produced by the same technique used to fabricate the P-T sensors [1,2,3]. In addition, it is possible to implant heavy ions such as silicon at RT to form graphite heaters in the anvils. The T of the seats can then be kept below 700 K, providing much better mechanical stability of the cell. No evidence of deformation was observed even on softer steel seats under a P of 0.7 GPa with the anvils heated to 1150 K. The use of steel as seat material makes it possible to adapt the seat design efficiently to the experimental set-up required. Further advantages of DACs with internally heated anvils are: 1) rapid heating at rates exceeding 500 K/s, and 2) the possibility of imposing large T differences between the anvils. Special holders have been designed to hold anvils in their seats and to provide the electrical contacts up to 1400 K. In addition, new anvil geometries are being tested to avoid the chipping at the edges ot the culets observed when hard materials are used as gaskets. Although it can be shown that HT B-implantation has no effect on the extent of this flaking problem, chipping in electronically structured anvils can lead to short-circuiting between the electronic pathways of the structures and must be minimized. Low-angle bevels next to the culet can be shown to enhance the lifetime of edges and electronic structures. (1) Burchard et al. (1999),Bull. Liasion SFMC,11, 106. (2) Burchard et al. (2000),Berichte der DMG, Beih. z. Eur. J. Mineral., 12, 28. (3) Zaitsev et al. (2001),Phys. Stat. sol. (a) 185,1,59-64. (4) Shen et al. (1992), in: HP Research: Applic. to Earth and Planetary Science(Terra Scientific Publishing Company, Tokyo, 1992), 61-68.

A dehydration mechanism for the stratosphere

NASA Technical Reports Server (NTRS)

Danielsen, E. F.

1982-01-01

Although mean circulations are generally credited with dehydration of the earth's stratosphere, convective instability in the tropics converts mean circulations to small residuals of local convective circulations. The effects of large cumulonimbus which penetrate the stratosphere and form huge anvils in the lower stratosphere are discussed with respect to hydration and dehydration of the stratosphere. Radiative heating at anvil base combined with cooling at anvil top drives a dehydration engine considered essential to explain the dry stratosphere. Seasonal and longitudinal variations in dehydration potentials are examined with maximum potential attributed to Micronesian area during winter and early spring.

High temperature detonator

DOEpatents

Johnson, James O.; Dinegar, Robert H.

1988-01-01

A detonator assembly is provided which is usable at high temperatures about 300.degree. C. A detonator body is provided with an internal volume defining an anvil surface. A first acceptor explosive is disposed on the anvil surface. A donor assembly having an ignition element, an explosive material, and a flying plate, are placed in the body effective to accelerate the flying plate to impact the first acceptor explosive on the anvil for detonating the first acceptor explosive. A second acceptor explosive is eccentrically located in detonation relationship with the first acceptor explosive to thereafter effect detonation of a main charge.

Homoepitaxial Boron Doped Diamond Anvils as Heating Elements in a Diamond Anvil Cell

NASA Astrophysics Data System (ADS)

Montgomery, Jeffrey; Samudrala, Gopi; Smith, Spencer; Tsoi, Georgiy; Vohra, Yogesh; Weir, Samuel

2013-03-01

Recent advances in designer-diamond technology have allowed for the use of electrically and thermally conducting homoepitaxially-grown layers of boron-doped diamond (grown at 1200 °C with a 2% mixture of CH4 in H, resulting in extremely high doping levels ~ 1020/cm3) to be used as heating elements in a diamond anvil cell (DAC). These diamonds allow for precise control of the temperature inside of the diamond anvil itself, particularly when coupled with a cryostat. Furthermore, the unmatched thermally conducting nature of diamond ensures that no significant lateral gradient in temperature occurs across the culet area. Since a thermocouple can easily be attached anywhere on the diamond surface, we can also measure diamond temperatures directly. With two such heaters, one can raise sample temperatures uniformly, or with any desired gradient along the pressure axis while preserving optical access. In our continuing set of benchmark experiments, we use two newly created matching heater anvils with 500 μm culets to analyze the various fluorescence emission lines of ruby microspheres, which show more complicated behavior than traditional ruby chips. We also report on the temperature dependence of the high-pressure Raman modes of paracetamol (C8H9NO2) up to 20 GPa.

High-pressure high-temperature phase diagram of gadolinium studied using a boron-doped heater anvil

NASA Astrophysics Data System (ADS)

Montgomery, J. M.; Samudrala, G. K.; Velisavljevic, N.; Vohra, Y. K.

2016-04-01

A boron-doped designer heater anvil is used in conjunction with powder x-ray diffraction to collect structural information on a sample of quasi-hydrostatically loaded gadolinium metal up to pressures above 8 GPa and 600 K. The heater anvil consists of a natural diamond anvil that has been surface modified with a homoepitaxially grown chemical-vapor-deposited layer of conducting boron-doped diamond, and is used as a DC heating element. Internally insulating both diamond anvils with sapphire support seats allows for heating and cooling of the high-pressure area on the order of a few tens of seconds. This device is then used to scan the phase diagram of the sample by oscillating the temperature while continuously increasing the externally applied pressure and collecting in situ time-resolved powder diffraction images. In the pressure-temperature range covered in this experiment, the gadolinium sample is observed in its hcp, αSm, and dhcp phases. Under this temperature cycling, the hcp → αSm transition proceeds in discontinuous steps at points along the expected phase boundary. From these measurements (representing only one hour of synchrotron x-ray collection time), a single-experiment equation of state and phase diagram of each phase of gadolinium is presented for the range of 0-10 GPa and 300-650 K.

Life Cycle of Tropical Convection and Anvil in Observations and Models

NASA Astrophysics Data System (ADS)

McFarlane, S. A.; Hagos, S. M.; Comstock, J. M.

2011-12-01

Tropical convective clouds are important elements of the hydrological cycle and produce extensive cirrus anvils that strongly affect the tropical radiative energy balance. To improve simulations of the global water and energy cycles and accurately predict both precipitation and cloud radiative feedbacks, models need to realistically simulate the lifecycle of tropical convection, including the formation and radiative properties of ice anvil clouds. By combining remote sensing datasets from precipitation and cloud radars at the Atmospheric Radiation Measurement (ARM) Darwin site with geostationary satellite data, we can develop observational understanding of the lifetime of convective systems and the links between the properties of convective systems and their associated anvil clouds. The relationships between convection and anvil in model simulations can then be compared to those seen in the observations to identify areas for improvement in the model simulations. We identify and track tropical convective systems in the Tropical Western Pacific using geostationary satellite observations. We present statistics of the tropical convective systems including size, age, and intensity and classify the lifecycle stage of each system as developing, mature, or dissipating. For systems that cross over the ARM Darwin site, information on convective intensity and anvil properties are obtained from the C-Pol precipitation radar and MMCR cloud radar, respectively, and are examined as a function of the system lifecycle. Initial results from applying the convective identification and tracking algorithm to a tropical simulation from the Weather Research and Forecasting (WRF) model run show that the model produces reasonable overall statistics of convective systems, but details of the life cycle (such as diurnal cycle, system tracks) differ from the observations. Further work will focus on the role of atmospheric temperature and moisture profiles in the model's convective life cycle.

Concept design and simulation study on a "phantom" anvil for circular stapler.

PubMed

Rulli, Francesco; Kartheuser, Alex; Amirhassankhani, Sasan; Mourad, Michel; Stefani, Mario; de Ferrá Aureli, Andrés; Sileri, Pierpaolo; Valentini, Pier Paolo

2015-04-01

Complications and challenges arising from the intraoperative double-stapling technique are seldom reported in colorectal surgery literature. Partial or full-thickness rectal injuries can occur during the introduction and the advancement of the circular stapler along the upper rectum. The aim of this study is to address some of these issues by designing and optimizing a "phantom" anvil manufactured to overcome difficulties throughout the rectal introduction and advancement of the circular stapler for the treatment of benign and malignant colon disease. The design of the "phantom" anvil has been performed using computer-aided modeling techniques, finite element investigations, and 2 essential keynotes in mind. The first one is the internal shape of the anvil, which is used for the connection to the gun. The second is the shape of the cap, which makes possible the insertion of the gun through the rectum. The "phantom" anvil has 2 functional requirements, which have been taken into account. The design has been optimized to avoid colorectal injuries, neoplastic dissemination (ie, mechanical seeding) and to reduce the fecal contamination. Numerical simulations show that a right combination of both top and bottom fillet radii of the shape of the anvil can reduce the stress for the considered anatomic configuration of >90%. Both the fillet radii at the top and the bottom of the device influence the local stress of the colon rectum. A dismountable device, which is used only for the insertion and advancement of the stapler, allows a dedicated design of its shape, keeping the remainder of the stapler unmodified. Computer-aided simulations are useful to perform numerical investigations to optimize the design of this auxiliary part for both the safety of the patient and the ease of the stapler advancement through the rectum.

Anvil Forecast Tool in the Advanced Weather Interactive Processing System (AWIPS)

NASA Technical Reports Server (NTRS)

Barrett, Joe H., III; Hood, Doris

2009-01-01

Launch Weather Officers (LWOs) from the 45th Weather Squadron (45 WS) and forecasters from the National Weather Service (NWS) Spaceflight Meteorology Group (SMG) have identified anvil forecasting as one of their most challenging tasks when predicting the probability of violating the Lightning Launch Commit Criteria (LLCC) (Krider et al. 2006; Space Shuttle Flight Rules (FR), NASA/JSC 2004)). As a result, the Applied Meteorology Unit (AMU) developed a tool that creates an anvil threat corridor graphic that can be overlaid on satellite imagery using the Meteorological Interactive Data Display System (MIDDS, Short and Wheeler, 2002). The tool helps forecasters estimate the locations of thunderstorm anvils at one, two, and three hours into the future. It has been used extensively in launch and landing operations by both the 45 WS and SMG. The Advanced Weather Interactive Processing System (AWIPS) is now used along with MIDDS for weather analysis and display at SMG. In Phase I of this task, SMG tasked the AMU to transition the tool from MIDDS to AWIPS (Barrett et aI., 2007). For Phase II, SMG requested the AMU make the Anvil Forecast Tool in AWIPS more configurable by creating the capability to read model gridded data from user-defined model files instead of hard-coded files. An NWS local AWIPS application called AGRID was used to accomplish this. In addition, SMG needed to be able to define the pressure levels for the model data, instead of hard-coding the bottom level as 300 mb and the top level as 150 mb. This paper describes the initial development of the Anvil Forecast Tool for MIDDS, followed by the migration of the tool to AWIPS in Phase I. It then gives a detailed presentation of the Phase II improvements to the AWIPS tool.

Fabrication of diamond based sensors for use in extreme environments

DOE PAGES

Samudrala, Gopi K.; Moore, Samuel L.; Vohra, Yogesh K.

2015-04-23

Electrical and magnetic sensors can be lithographically fabricated on top of diamond substrates and encapsulated in a protective layer of chemical vapor deposited single crystalline diamond. This process when carried out on single crystal diamond anvils employed in high pressure research is termed as designer diamond anvil fabrication. These designer diamond anvils allow researchers to study electrical and magnetic properties of materials under extreme conditions without any possibility of damaging the sensing elements. We describe a novel method for the fabrication of designer diamond anvils with the use of maskless lithography and chemical vapor deposition in this paper. This methodmore » can be utilized to produce diamond based sensors which can function in extreme environments of high pressures, high and low temperatures, corrosive and high radiation conditions. Here, we demonstrate applicability of these diamonds under extreme environments by performing electrical resistance measurements during superconducting transition in rare earth doped iron-based compounds under high pressures to 12 GPa and low temperatures to 10 K.« less

Thermodynamic control of anvil cloud amount

PubMed Central

Bony, Sandrine; Stevens, Bjorn; Coppin, David; Becker, Tobias; Reed, Kevin A.; Voigt, Aiko

2016-01-01

General circulation models show that as the surface temperature increases, the convective anvil clouds shrink. By analyzing radiative–convective equilibrium simulations, we show that this behavior is rooted in basic energetic and thermodynamic properties of the atmosphere: As the climate warms, the clouds rise and remain at nearly the same temperature, but find themselves in a more stable atmosphere; this enhanced stability reduces the convective outflow in the upper troposphere and decreases the anvil cloud fraction. By warming the troposphere and increasing the upper-tropospheric stability, the clustering of deep convection also reduces the convective outflow and the anvil cloud fraction. When clouds are radiatively active, this robust coupling between temperature, high clouds, and circulation exerts a positive feedback on convective aggregation and favors the maintenance of strongly aggregated atmospheric states at high temperatures. This stability iris mechanism likely contributes to the narrowing of rainy areas as the climate warms. Whether or not it influences climate sensitivity requires further investigation. PMID:27412863

Fabrication of diamond based sensors for use in extreme environments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Samudrala, Gopi K.; Moore, Samuel L.; Vohra, Yogesh K.

Electrical and magnetic sensors can be lithographically fabricated on top of diamond substrates and encapsulated in a protective layer of chemical vapor deposited single crystalline diamond. This process when carried out on single crystal diamond anvils employed in high pressure research is termed as designer diamond anvil fabrication. These designer diamond anvils allow researchers to study electrical and magnetic properties of materials under extreme conditions without any possibility of damaging the sensing elements. We describe a novel method for the fabrication of designer diamond anvils with the use of maskless lithography and chemical vapor deposition in this paper. This methodmore » can be utilized to produce diamond based sensors which can function in extreme environments of high pressures, high and low temperatures, corrosive and high radiation conditions. Here, we demonstrate applicability of these diamonds under extreme environments by performing electrical resistance measurements during superconducting transition in rare earth doped iron-based compounds under high pressures to 12 GPa and low temperatures to 10 K.« less

Thermodynamic control of anvil cloud amount

DOE PAGES

Bony, Sandrine; Stevens, Bjorn; Coppin, David; ...

2016-07-13

General circulation models show that as the surface temperature increases, the convective anvil clouds shrink. By analyzing radiative–convective equilibrium simulations, our work shows that this behavior is rooted in basic energetic and thermodynamic properties of the atmosphere: As the climate warms, the clouds rise and remain at nearly the same temperature, but find themselves in a more stable atmosphere; this enhanced stability reduces the convective outflow in the upper troposphere and decreases the anvil cloud fraction. By warming the troposphere and increasing the upper-tropospheric stability, the clustering of deep convection also reduces the convective outflow and the anvil cloud fraction.more » When clouds are radiatively active, this robust coupling between temperature, high clouds, and circulation exerts a positive feedback on convective aggregation and favors the maintenance of strongly aggregated atmospheric states at high temperatures. This stability iris mechanism likely contributes to the narrowing of rainy areas as the climate warms. Whether or not it influences climate sensitivity requires further investigation.« less

Dynamic diamond anvil cell (dDAC): A novel device for studying the dynamic-pressure properties of materials

NASA Astrophysics Data System (ADS)

Evans, William J.; Yoo, Choong-Shik; Lee, Geun Woo; Cynn, Hyunchae; Lipp, Magnus J.; Visbeck, Ken

2007-07-01

We have developed a unique device, a dynamic diamond anvil cell (dDAC), which repetitively applies a time-dependent load/pressure profile to a sample. This capability allows studies of the kinetics of phase transitions and metastable phases at compression (strain) rates of up to 500GPa/s (˜0.16s-1 for a metal). Our approach adapts electromechanical piezoelectric actuators to a conventional diamond anvil cell design, which enables precise specification and control of a time-dependent applied load/pressure. Existing DAC instrumentation and experimental techniques are easily adapted to the dDAC to measure the properties of a sample under the varying load/pressure conditions. This capability addresses the sparsely studied regime of dynamic phenomena between static research (diamond anvil cells and large volume presses) and dynamic shock-driven experiments (gas guns, explosive, and laser shock). We present an overview of a variety of experimental measurements that can be made with this device.

Electrical resistivity measurements on fragile organic single crystals in the diamond anvil cell

NASA Astrophysics Data System (ADS)

Adachi, T.; Tanaka, H.; Kobayashi, H.; Miyazaki, T.

2001-05-01

A method of sample assembly for four-probe resistivity measurements on fragile organic single crystals using a diamond anvil cell is presented. A procedure to keep insulation between the metal gasket and four leads of thin gold wires bonded to the sample crystal by gold paint is described in detail. The resistivity measurements performed on a single crystal of an organic semiconductor and that of neutral molecules up to 15 GPa and down to 4.2 K showed that this new procedure of four-probe diamond anvil resistivity measurements enables us to obtain sufficiently accurate resistivity data of organic crystals.

High-pressure high-temperature phase diagram of gadolinium studied using a boron-doped heater anvil

DOE Office of Scientific and Technical Information (OSTI.GOV)

Montgomery, J. M.; Samudrala, G. K.; Vohra, Y. K.

A boron-doped designer heater anvil is used in conjunction with powder x-ray diffraction to collect structural information on a sample of quasi-hydrostatically loaded gadolinium metal up to pressures above 8 GPa and 600 K. The heater anvil consists of a natural diamond anvil that has been surface modified with a homoepitaxially grown chemical-vapor-deposited layer of conducting boron-doped diamond, and is used as a DC heating element. Internally insulating both diamond anvils with sapphire support seats allows for heating and cooling of the high-pressure area on the order of a few tens of seconds. This device is then used to scan the phasemore » diagram of the sample by oscillating the temperature while continuously increasing the externally applied pressure and collecting in situ time-resolved powder diffraction images. In the pressure-temperature range covered in this experiment, the gadolinium sample is observed in its hcp, αSm, and dhcp phases. Under this temperature cycling, the hcp → αSm transition proceeds in discontinuous steps at points along the expected phase boundary. From these measurements (representing only one hour of synchrotron x-ray collection time), a single-experiment equation of state and phase diagram of each phase of gadolinium is presented for the range of 0–10 GPa and 300–650 K.« less

Diamond anvil cell for spectroscopic investigation of materials at high temperature, high pressure and shear

DOEpatents

Westerfield, Curtis L.; Morris, John S.; Agnew, Stephen F.

1997-01-01

Diamond anvil cell for spectroscopic investigation of materials at high temperature, high pressure and shear. A cell is described which, in combination with Fourier transform IR spectroscopy, permits the spectroscopic investigation of boundary layers under conditions of high temperature, high pressure and shear.

Volume Averaged Height Integrated Radar Reflectivity (VAHIRR) Cost-Benefit Analysis

NASA Technical Reports Server (NTRS)

Bauman, William H., III

2008-01-01

Lightning Launch Commit Criteria (LLCC) are designed to prevent space launch vehicles from flight through environments conducive to natural or triggered lightning and are used for all U.S. government and commercial launches at government and civilian ranges. They are maintained by a committee known as the NASA/USAF Lightning Advisory Panel (LAP). The previous LLCC for anvil cloud, meant to avoid triggered lightning, have been shown to be overly restrictive. Some of these rules have had such high safety margins that they prohibited flight under conditions that are now thought to be safe 90% of the time, leading to costly launch delays and scrubs. The LLCC for anvil clouds was upgraded in the summer of 2005 to incorporate results from the Airborne Field Mill (ABFM) experiment at the Eastern Range (ER). Numerous combinations of parameters were considered to develop the best correlation of operational weather observations to in-cloud electric fields capable of rocket triggered lightning in anvil clouds. The Volume Averaged Height Integrated Radar Reflectivity (VAHIRR) was the best metric found. Dr. Harry Koons of Aerospace Corporation conducted a risk analysis of the VAHIRR product. The results indicated that the LLCC based on the VAHIRR product would pose a negligible risk of flying through hazardous electric fields. Based on these findings, the Kennedy Space Center Weather Office is considering seeking funding for development of an automated VAHIRR algorithm for the new ER 45th Weather Squadron (45 WS) RadTec 431250 weather radar and Weather Surveillance Radar-1988 Doppler (WSR-88D) radars. Before developing an automated algorithm, the Applied Meteorology Unit (AMU) was tasked to determine the frequency with which VAHIRR would have allowed a launch to safely proceed during weather conditions otherwise deemed "red" by the Launch Weather Officer. To do this, the AMU manually calculated VAHIRR values based on candidate cases from past launches with known anvil cloud LLCC violations. An automated algorithm may be developed if the analyses from past launches show VAHIRR would have provided a significant cost benefit by allowing a launch to proceed. The 45 WS at the ER and 30th Weather Squadron (30 WS) at the Western Range provided the AMU with launch weather summaries from past launches that were impacted by LLCC. The 45 WS provided summaries from 14 launch attempts and the 30 WS fkom 5. The launch attempts occurred between December 2001 and June 2007. These summaries helped the AMU determine when the LLCC were "red" due to anvil cloud. The AMU collected WSR-88D radar reflectivity, cloud-to-ground lightning strikes, soundings and satellite imagery. The AMU used step-by-step instructions for calculating VAHIRR manually as provided by the 45 WS. These instructions were used for all of the candidate cases when anvil cloud caused an LLCC violation identified in the launch weather summaries. The AMU evaluated several software programs capable of visualizing radar data so that VAHIRR could be calculated and chose GR2Analyst from Gibson Ridge Software, LLC. Data availability and lack of detail from some launch weather summaries permitted analysis of six launch attempts from the ER and none from the WR. The AMU did not take into account whether or not other weather LCC violations were occurring at the same time as the anvil cloud LLCC since the goal of this task was to determine how often VAHIRR provided relief to the anvil cloud LLCC at any time during several previous launch attempts. Therefore, in the statistics presented in this report, it is possible that even though VAHIRR provided relief to the anvil cloud LLCC, other weather LCC could have been violated not permitting the launch to proceed. The results of this cost-benefit analysis indicated VAHIRR provided relief from the anvil cloud LLCC between about 15% and 18% of the time for varying 5-minute time periods based on summaries fkom six launch attempts and would have allowed launch to proceed that were otherwise "NO GO" due to the anvil cloud LLCC if the T-0 time occurred during the anvil cloud LLCC violations.

High pressure and high temperature apparatus

DOEpatents

Voronov, Oleg A.

2005-09-13

A design for high pressure/high temperature apparatus and reaction cell to achieve .about.30 GPa pressure in .about.1 cm volume and .about.100 GPa pressure in .about.1 mm volumes and 20-5000.degree. C. temperatures in a static regime. The device includes profiled anvils (28) action on a reaction cell (14, 16) containing the material (26) to be processed. The reaction cell includes a heater (18) surrounded by insulating layers and screens. Surrounding the anvils are cylindrical inserts and supporting rings (30-48) whose hardness increases towards the reaction cell. These volumes may be increased considerably if applications require it, making use of presses that have larger loading force capability, larger frames and using larger anvils.

Diamond anvil cell for spectroscopic investigation of materials at high temperature, high pressure and shear

DOEpatents

Westerfield, C.L.; Morris, J.S.; Agnew, S.F.

1997-01-14

Diamond anvil cell is described for spectroscopic investigation of materials at high temperature, high pressure and shear. A cell is described which, in combination with Fourier transform IR spectroscopy, permits the spectroscopic investigation of boundary layers under conditions of high temperature, high pressure and shear. 4 figs.

Rapid Growth of Nanocrystalline Diamond on Single Crystal Diamond for Studies on Materials under Extreme Conditions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moore, Samuel L.; Samudrala, Gopi K.; Catledge, Shane A.

Early stage nucleation morphologies of spatially localized nanocrystalline diamond (NCD) micro-anvils grown on (100)-oriented single crystal diamond (SCD) anvil surfaces were analyzed and investigated for applications in high pressure studies on materials. NCD was grown on SCD using Microwave Plasma Chemical Vapor Deposition (MPCVD) for brief time intervals ranging from 1-15 minutes. Early stage film morphologies were characterized using scanning electron microscopy (SEM) and Raman spectroscopy and were compared to films grown for several hours. Rapid nucleation and growth of NCD on SCD is demonstrated without any pre-growth seeding of the substrate surface. As grown NCD diamond micro-anvils on SCDmore » were used to generate static pressure of 0.5 Terapascal (TPa) on a tungsten sample as measured by synchrotron x-ray diffraction in a diamond anvil cell. Atomic force microscopy (AFM) analysis after decompression from ultrahigh pressures showed that the detachment of the NCD stage occurred in the bulk of the SCD and not at the interface, suggesting significant adhesive bond strength between nanocrystalline and single crystal diamond.« less

Rapid Growth of Nanocrystalline Diamond on Single Crystal Diamond for Studies on Materials under Extreme Conditions

DOE PAGES

Moore, Samuel L.; Samudrala, Gopi K.; Catledge, Shane A.; ...

2018-01-23

Early stage nucleation morphologies of spatially localized nanocrystalline diamond (NCD) micro-anvils grown on (100)-oriented single crystal diamond (SCD) anvil surfaces were analyzed and investigated for applications in high pressure studies on materials. NCD was grown on SCD using Microwave Plasma Chemical Vapor Deposition (MPCVD) for brief time intervals ranging from 1-15 minutes. Early stage film morphologies were characterized using scanning electron microscopy (SEM) and Raman spectroscopy and were compared to films grown for several hours. Rapid nucleation and growth of NCD on SCD is demonstrated without any pre-growth seeding of the substrate surface. As grown NCD diamond micro-anvils on SCDmore » were used to generate static pressure of 0.5 Terapascal (TPa) on a tungsten sample as measured by synchrotron x-ray diffraction in a diamond anvil cell. Atomic force microscopy (AFM) analysis after decompression from ultrahigh pressures showed that the detachment of the NCD stage occurred in the bulk of the SCD and not at the interface, suggesting significant adhesive bond strength between nanocrystalline and single crystal diamond.« less

Anvil Forecast Tool in the Advanced Weather Interactive Processing System

NASA Technical Reports Server (NTRS)

Barrett, Joe H., III; Hood, Doris

2009-01-01

Meteorologists from the 45th Weather Squadron (45 WS) and National Weather Service Spaceflight Meteorology Group (SMG) have identified anvil forecasting as one of their most challenging tasks when predicting the probability of violations of the Lightning Launch Commit Criteria and Space Shuttle Flight Rules. As a result, the Applied Meteorology Unit (AMU) was tasked to create a graphical overlay tool for the Meteorological Interactive Data Display System (MIDDS) that indicates the threat of thunderstorm anvil clouds, using either observed or model forecast winds as input. The tool creates a graphic depicting the potential location of thunderstorm anvils one, two, and three hours into the future. The locations are based on the average of the upper level observed or forecasted winds. The graphic includes 10 and 20 n mi standoff circles centered at the location of interest, as well as one-, two-, and three-hour arcs in the upwind direction. The arcs extend outward across a 30 sector width based on a previous AMU study that determined thunderstorm anvils move in a direction plus or minus 15 of the upper-level wind direction. The AMU was then tasked to transition the tool to the Advanced Weather Interactive Processing System (AWIPS). SMG later requested the tool be updated to provide more flexibility and quicker access to model data. This presentation describes the work performed by the AMU to transition the tool into AWIPS, as well as the subsequent improvements made to the tool.

High-pressure high-temperature phase diagram of gadolinium studied using a boron-doped heater anvil

DOE Office of Scientific and Technical Information (OSTI.GOV)

Montgomery, J. M.; Samudrala, G. K.; Velisavljevic, N.

A boron-doped designer heater anvil is used in conjunction with powder x-ray diffraction to collect structural information on a sample of quasi-hydrostatically loaded gadolinium metal up to pressures above 8 GPa and 600 K. The heater anvil consists of a natural diamond anvil that has been surface modified with a homoepitaxially-grown chemical-vapor-deposited layer of conducting boron-doped diamond, and is used as a DC heating element. Internally insulating both diamond anvils with sapphire support seats allows for heating and cooling of the high pressure area on the order of a few tens of seconds. This device is then used to scanmore » the phase diagram of the sample by oscillating the temperature while continuously increasing the externally applied pressure and collecting in situ time-resolved powder diffraction images. In the pressure-temperature range covered in the experiment the gadolinium sample is observed in its hcp, αSm, and dhcp phases. Under this temperature cycling, the hcp→αSm transition proceeds in discontinuous steps at points along the expected phase boundary. Additionally, the unit cell volumes of each phase deviate from the expected thermal expansion behavior just before each transition is observed from the diffraction data. From these measurements (representing only one hour of synchrotron x-ray collection time), a single-experiment equation of state and phase diagram of each phase of gadolinium is presented for the range of 0 - 10 GPa and 300 - 650 K.« less

Evaluation of and Suggested Improvements to the WSM6 Microphysics in WRF- ARW Using Synthetic and Observed GOES-13 Imagery

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grasso, Lewis; Lindsey, Daniel T.; Lim, Kyo-Sun

Synthetic satellite imagery can be employed to evaluate simulated cloud fields. Past studies have revealed that the Weather Research and Forecasting (WRF) WRF Single-Moment 6-class (WSM6) microphysics in WRF-ARW produces less upper level ice clouds within synthetic images compared to observations. Synthetic Geostationary Operational Environmental Satellite (GOES)-13 imagery at 10.7 μm of simulated cloud fields from the 4 km National Severe Storms Laboratory (NSSL) WRF-ARW is compared to observed GOES-13 imagery. Histograms suggest that too few points contain upper level simulated ice clouds. In particular, side-by-side examples are shown of synthetic and observed convective anvils. Such images illustrate the lackmore » of anvil cloud associated with convection produced by the NSSL WRF-ARW. A vertical profile of simulated hydrometeors suggests that too much cloud water mass may be converted into graupel mass, effectively reducing the main source of ice mass in a simulated anvil. Further, excessive accretion of ice by snow removes ice from an anvil by precipitation settling. Idealized sensitivity tests reveal that a 50% reduction of the conversion of cloud water mass to graupel and a 50% reduction of the accretion rate of ice by snow results in a significant increase in anvil ice of a simulated storm. Such results provide guidance as to which conversions could be reformulated, in a more physical manner, to increase simulated ice mass in the upper troposphere.« less

High-pressure high-temperature phase diagram of gadolinium studied using a boron-doped heater anvil

DOE PAGES

Montgomery, J. M.; Samudrala, G. K.; Velisavljevic, N.; ...

2016-04-07

A boron-doped designer heater anvil is used in conjunction with powder x-ray diffraction to collect structural information on a sample of quasi-hydrostatically loaded gadolinium metal up to pressures above 8 GPa and 600 K. The heater anvil consists of a natural diamond anvil that has been surface modified with a homoepitaxially-grown chemical-vapor-deposited layer of conducting boron-doped diamond, and is used as a DC heating element. Internally insulating both diamond anvils with sapphire support seats allows for heating and cooling of the high pressure area on the order of a few tens of seconds. This device is then used to scanmore » the phase diagram of the sample by oscillating the temperature while continuously increasing the externally applied pressure and collecting in situ time-resolved powder diffraction images. In the pressure-temperature range covered in the experiment the gadolinium sample is observed in its hcp, αSm, and dhcp phases. Under this temperature cycling, the hcp→αSm transition proceeds in discontinuous steps at points along the expected phase boundary. Additionally, the unit cell volumes of each phase deviate from the expected thermal expansion behavior just before each transition is observed from the diffraction data. From these measurements (representing only one hour of synchrotron x-ray collection time), a single-experiment equation of state and phase diagram of each phase of gadolinium is presented for the range of 0 - 10 GPa and 300 - 650 K.« less

Geophysics Under Pressure: Large-Volume Presses Versus the Diamond-Anvil Cell

NASA Astrophysics Data System (ADS)

Hazen, R. M.

2002-05-01

Prior to 1970, the legacy of Harvard physicist Percy Bridgman dominated high-pressure geophysics. Massive presses with large-volume devices, including piston-cylinder, opposed-anvil, and multi-anvil configurations, were widely used in both science and industry to achieve a range of crustal and upper mantle temperatures and pressures. George Kennedy of UCLA was a particularly influential advocate of large-volume apparatus for geophysical research prior to his death in 1980. The high-pressure scene began to change in 1959 with the invention of the diamond-anvil cell, which was designed simultaneously and independently by John Jamieson at the University of Chicago and Alvin Van Valkenburg at the National Bureau of Standards in Washington, DC. The compact, inexpensive diamond cell achieved record static pressures and had the advantage of optical access to the high-pressure environment. Nevertheless, members of the geophysical community, who favored the substantial sample volumes, geothermally relevant temperature range, and satisfying bulk of large-volume presses, initially viewed the diamond cell with indifference or even contempt. Several factors led to a gradual shift in emphasis from large-volume presses to diamond-anvil cells in geophysical research during the 1960s and 1970s. These factors include (1) their relatively low cost at time of fiscal restraint, (2) Alvin Van Valkenburg's new position as a Program Director at the National Science Foundation in 1964 (when George Kennedy's proposal for a Nation High-Pressure Laboratory was rejected), (3) the development of lasers and micro-analytical spectroscopic techniques suitable for analyzing samples in a diamond cell, and (4) the attainment of record pressures (e.g., 100 GPa in 1975 by Mao and Bell at the Geophysical Laboratory). Today, a more balanced collaborative approach has been adopted by the geophysics and mineral physics community. Many high-pressure laboratories operate a new generation of less expensive large-volume presses side-by-side with a wide variety of diamond-anvil cells.

Techniques used to identify tornado producing thunderstorms using geosynchronous satellite data

NASA Technical Reports Server (NTRS)

Schrab, Kevin J.; Anderson, Charles E.; Monahan, John F.

1992-01-01

Satellite imagery in the outbreak region in the time prior to and during tornado occurrence was examined in detail to obtain descriptive characteristics of the anvil plume. These characteristics include outflow strength (UMAX), departure of anvil centerline from the storm relative ambient wind (MDA), storm relative ambient wind (SRAW), and maximum surface vorticity (SFCVOR). It is shown that by using satellite derived parameters which characterize the flow field in the anvil region, the occurrence and intensity of tornadoes, which the parent thunderstorm produces, can be identified. Analysis of the censored regression models revealed that the five explanatory variables (UMAX, MDA, SRAW, UMAX-2, and SFCVOR) were all significant predictors in the identification of tornadic intensity of a particular thunderstorm.

When and where to practice: social influences on the development of nut-cracking in bearded capuchins (Sapajus libidinosus).

PubMed

Eshchar, Y; Izar, P; Visalberghi, E; Resende, B; Fragaszy, D

2016-05-01

The habitual use of tools by wild capuchin monkeys presents a unique opportunity to study the maintenance and transmission of traditions. Young capuchins spend several years interacting with nuts before cracking them efficiently with stone tools. Using a two-observer method, we quantified the magnitude of the social influences that sustain this long period of practice. During five collection periods (over 26 months), one observer recorded the behavior of 16 immature monkeys, and another observer concurrently recorded behavior of group members in the focal monkey's vicinity. The two-observer method provides a means to quantify distinct social influences. Data show that immatures match the behavior of the adults in time and especially in space. The rate of manipulation of nuts by the immatures quadrupled when others in the group cracked and ate nuts, and immatures were ten times more likely to handle nuts and 40 times more likely to strike a nut with a stone when they themselves were near the anvils. Moreover, immature monkeys were three times more likely to be near an anvil when others were cracking. We suggest a model for social influence on nut-cracking development, based on two related processes: (1) social facilitation from observing group members engaged in nut-cracking, and (2) opportunity for practice provided by the anvils, hammer stones and nut shells available on and around the anvils. Nut-cracking activities by others support learning by drawing immatures to the anvils, where extended practice can take place, and by providing materials for practice at these places.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Erfani, Ehsan; Mitchell, David L.

Here, ice particle mass- and projected area-dimension ( m- D and A- D) power laws are commonly used in the treatment of ice cloud microphysical and optical properties and the remote sensing of ice cloud properties. Although there has long been evidence that a single m- D or A- D power law is often not valid over all ice particle sizes, few studies have addressed this fact. This study develops self-consistent m- D and A- D expressions that are not power laws but can easily be reduced to power laws for the ice particle size (maximum dimension or D) rangemore » of interest, and they are valid over a much larger D range than power laws. This was done by combining ground measurements of individual ice particle m and D formed at temperature T < –20 °C during a cloud seeding field campaign with 2-D stereo (2D-S) and cloud particle imager (CPI) probe measurements of D and A, and estimates of m, in synoptic and anvil ice clouds at similar temperatures. The resulting m- D and A- D expressions are functions of temperature and cloud type (synoptic vs. anvil), and are in good agreement with m- D power laws developed from recent field studies considering the same temperature range (–60 °C < T < –20 °C).« less

Use of Acoustic Emission and Pattern Recognition for Crack Detection of a Large Carbide Anvil

PubMed Central

Chen, Bin; Wang, Yanan; Yan, Zhaoli

2018-01-01

Large-volume cubic high-pressure apparatus is commonly used to produce synthetic diamond. Due to the high pressure, high temperature and alternative stresses in practical production, cracks often occur in the carbide anvil, thereby resulting in significant economic losses or even casualties. Conventional methods are unsuitable for crack detection of the carbide anvil. This paper is concerned with acoustic emission-based crack detection of carbide anvils, regarded as a pattern recognition problem; this is achieved using a microphone, with methods including sound pulse detection, feature extraction, feature optimization and classifier design. Through analyzing the characteristics of background noise, the cracked sound pulses are separated accurately from the originally continuous signal. Subsequently, three different kinds of features including a zero-crossing rate, sound pressure levels, and linear prediction cepstrum coefficients are presented for characterizing the cracked sound pulses. The original high-dimensional features are adaptively optimized using principal component analysis. A hybrid framework of a support vector machine with k nearest neighbors is designed to recognize the cracked sound pulses. Finally, experiments are conducted in a practical diamond workshop to validate the feasibility and efficiency of the proposed method. PMID:29382144

Use of Acoustic Emission and Pattern Recognition for Crack Detection of a Large Carbide Anvil.

PubMed

Chen, Bin; Wang, Yanan; Yan, Zhaoli

2018-01-29

Large-volume cubic high-pressure apparatus is commonly used to produce synthetic diamond. Due to the high pressure, high temperature and alternative stresses in practical production, cracks often occur in the carbide anvil, thereby resulting in significant economic losses or even casualties. Conventional methods are unsuitable for crack detection of the carbide anvil. This paper is concerned with acoustic emission-based crack detection of carbide anvils, regarded as a pattern recognition problem; this is achieved using a microphone, with methods including sound pulse detection, feature extraction, feature optimization and classifier design. Through analyzing the characteristics of background noise, the cracked sound pulses are separated accurately from the originally continuous signal. Subsequently, three different kinds of features including a zero-crossing rate, sound pressure levels, and linear prediction cepstrum coefficients are presented for characterizing the cracked sound pulses. The original high-dimensional features are adaptively optimized using principal component analysis. A hybrid framework of a support vector machine with k nearest neighbors is designed to recognize the cracked sound pulses. Finally, experiments are conducted in a practical diamond workshop to validate the feasibility and efficiency of the proposed method.

Efficient graphite ring heater suitable for diamond-anvil cells to 1300 K

DOE Office of Scientific and Technical Information (OSTI.GOV)

Du Zhixue; Amulele, George; Lee, Kanani K. M.

In order to generate homogeneous high temperatures at high pressures, a ring-shaped graphite heater has been developed to resistively heat diamond-anvil cell (DAC) samples up to 1300 K. By putting the heater in direct contact with the diamond anvils, this graphite heater design features the following advantages: (1) efficient heating: sample can be heated to 1300 K while the DAC body temperature remains less than 800 K, eliminating the requirement of a special alloy for the DAC; (2) compact design: the sample can be analyzed with in situ measurements, e.g., x-ray, optical, and electrical probes are possible. In particular, themore » side access of the heater allows for radial x-ray diffraction (XRD) measurements in addition to traditional axial XRD.« less

Laser techniques in high-pressure geophysics

NASA Technical Reports Server (NTRS)

Hemley, R. J.; Bell, P. M.; Mao, H. K.

1987-01-01

Laser techniques in conjunction with the diamond-anvil cell can be used to study high-pressure properties of materials important to a wide range of problems in earth and planetary science. Spontaneous Raman scattering of crystalline and amorphous solids at high pressure demonstrates that dramatic changes in structure and bonding occur on compression. High-pressure Brillouin scattering is sensitive to the pressure variations of single-crystal elastic moduli and acoustic velocities. Laser heating techniques with the diamond-anvil cell can be used to study phase transitions, including melting, under deep-earth conditions. Finally, laser-induced ruby fluorescence has been essential for the development of techniques for generating the maximum pressures now possible with the diamond-anvil cell, and currently provides a calibrated in situ measure of pressure well above 100 gigapascals.

Welding fixture for joining bar-wound stator conductors

DOE Office of Scientific and Technical Information (OSTI.GOV)

De Souza, Urban J.; Rhoads, Frederick W.; Hanson, Justin

A fixture assembly for welding a plurality of stator wire end pairs may include an anvil, a movable clamp configured to translate between an unclamped state and a clamped state, a first grounding electrode, and a second grounding electrode. The movable clamp may be configured to urge the plurality of stator wire ends against the anvil when in the clamped state. The moveable clamp includes a separator feature that generally extends toward the anvil. Each of the first grounding electrode and second grounding electrodes may be configured to translate between a clamped state and an unclamped state. When in themore » clamped state, each of the first and second grounding electrodes is configured to urge a pair of the plurality of stator wire end pairs against the separator feature.« less

Rapid vertical trace gas transport by an isolated midlatitude thunderstorm

NASA Astrophysics Data System (ADS)

Hauf, Thomas; Schulte, Peter; Alheit, Reiner; Schlager, Hans

1995-11-01

During the cloud dynamics and chemistry field experiment CLEOPATRA in the summer of 1992 in southern Germany, the Deutsche Forschungsanstalt für Luft- und Raumfahrt (DLR) (German Aerospace Research Establishment) research aircraft Falcon traversed four times the anvil of a severe, isolated thunderstorm. The first two traverses were at 8 km altitude and close to the anvil cloud base, while the second two traverses were at 10 km. During the 8-km traverse, measured ozone mixing ratios dropped by 13 parts per billion by volume (ppbv) from the ambient cloud free environment to the anvil cloud, while water vapor increased by 0.3 g kg-1. At the 10-km traverses, ozone dropped by 25 ppbv, while water vapor increased by 0.18 g kg-1. Three-dimensional numerical thunderstorm simulations were performed to understand the cause of these changes. The simulations included the transport of two chemical inert tracers. Ozone was assumed to be one of them. The initial ozone profile was composed from an ozone routine sounding and the in situ Falcon measurements prior to the thunderstorm development. The second tracer is typical for a surface released pollutant with a nonzero, constant value in the boundary layer but zero above it. The redistribution of both tracers by the storm is calculated and compared with the observations. For the anvil penetration at 10 km, the calculated difference in ozone mixing ratios is 21 ppbv, while for water vapor an increase of 0.25 g kg-1 was found, in good agreement with the observations. To validate the model results, the radar reflectivity was calculated from simulated fields of cloud water, rain, graupel, hail, and snow and ice crystals and compared with observed values. With respect to maximum reflectivity values and spatial scales, again, excellent agreement was achieved. It is concluded that the rapid transport from the boundary layer directly into the anvil level is the most likely cause of the observed ozone decrease and water vapor increase. Entrainment of ozone-rich environmental air into the anvil cloud occurred but left a protected core with undiluted boundary layer air in the anvil cloud even at a distance of 120 km from the main updraft. Processes such as production of O3 by electrical discharges, chemical reactions of ozone with boundary layer-released or lightning-produced nitrogen compounds, scavenging by hydrometeors, and heterogeneous reactions at the surface of ice crystals may occur, but on the timescale of 0.5-1 hour seem to have a negligible influence on the observed ozone drop.

Acoustic transducer

DOEpatents

Drumheller, Douglas S.

2000-01-01

An active acoustic transducer tool for use down-hole applications. The tool includes a single cylindrical mandrel including a shoulder defining the boundary of a narrowed portion over which is placed a sandwich-style piezoelectric tranducer assembly. The piezoelectric transducer assembly is prestressed by being placed in a thermal interference fit between the shoulder of the mandrel and the base of an anvil which is likewise positioned over the narrower portion of the mandrel. In the preferred embodiment, assembly of the tool is accomplished using a hydraulic jack to stretch the mandrel prior to emplacement of the cylindrical sandwich-style piezoelectric transducer assembly and anvil. After those elements are positioned and secured, the stretched mandrel is allowed to return substantially to its original (pre-stretch) dimensions with the result that the piezoelectric transducer elements are compressed between the anvil and the shoulder of the mandrel.

Hydrothermal diamond anvil cell for XAFS studies of first-row transition elements in aqueous solutions up to supercritical conditions

USGS Publications Warehouse

Bassett, William A.; Anderson, Alan J.; Mayanovic, Robert A.; Chou, I.-Ming

2000-01-01

A hydrothermal diamond anvil cell (HDAC) has been modified by drilling holes with a laser to within 150 ??m of the anvil face to minimize the loss of X-rays due to absorption and scatter by diamond. This modification enables acquisition of K-edge X-ray absorption fine structure (XAFS) spectra from first-row transition metal ions in aqueous solutions at temperatures ranging from 25??C to 660??C and pressures up to 800 MPa. These pressure-temperature (P-T) conditions are more than sufficient for carrying out experimental measurements that can provide data valuable in the interpretation of fluid inclusions in minerals found in ore-forming hydrothermal systems as well as other important lithospheric processes involving water. (C) 2000 Elsevier Science B.V. All rights reserved.

CRYSTAL: The Cirrus Regional Study of Tropical Anvils and Layers

NASA Technical Reports Server (NTRS)

Delnore, Victor E.; Cox, Stephen K.; Curran, Robert J.

1999-01-01

CRYSTAL the Cirrus Regional Study of Tropical Anvils and Layers is part of the ongoing series of field experiments to study clouds and their impact on world weather and climate, and will attempt to improve the application of cloud effects in global climate models. CRYSTAL is being planned as two parts: a limited CRYSTAL field campaign in 2001 to examine towering clouds and anvil genesis over the Everglades of Florida, and the main CRYSTAL field campaign in the summer of 2003 in the Tropical Western Pacific. The latter is timed to take advantage of several cloud measurement satellites that will be operational at that time. This paper discusses some of the issues to be addressed in CRYSTAL, gives a brief description of the research plan, and describes its relationship to other important field experiments.

Limitations and possibilities of AC calorimetry in diamond anvil cells

NASA Astrophysics Data System (ADS)

Geballe, Zachary; Colins, Gilbert; Jeanloz, Raymond

2013-06-01

Dynamic laser heating or internal resistive heating could allow for the determination of calorimetric properties of samples that are held statically at high pressure. However, the highly non-adiabatic environment of high-pressure cells presents several challenges. Here, we quantify the errors in AC calorimetry measurements using laser heating or internal resistive heating inside diamond anvil cells, summarize the equipment requirements of supplying sufficient power modulated at a high enough frequency to measure specific heats and latent heats of phase transitions, and propose two new experiments in internally-heated diamond anvil cells: an absolute measurement of specific heat (with ~10% uncertainty) of non-magnetic metals using resistive heating at ~10 MHz, and a relative measurement to detect changes in either the specific heat of metals or in the effusively (the product of specific heat, density and thermal conductivity) of an insulator.

Automatic monitoring of vibration welding equipment

DOEpatents

Spicer, John Patrick; Chakraborty, Debejyo; Wincek, Michael Anthony; Wang, Hui; Abell, Jeffrey A; Bracey, Jennifer; Cai, Wayne W

2014-10-14

A vibration welding system includes vibration welding equipment having a welding horn and anvil, a host device, a check station, and a robot. The robot moves the horn and anvil via an arm to the check station. Sensors, e.g., temperature sensors, are positioned with respect to the welding equipment. Additional sensors are positioned with respect to the check station, including a pressure-sensitive array. The host device, which monitors a condition of the welding equipment, measures signals via the sensors positioned with respect to the welding equipment when the horn is actively forming a weld. The robot moves the horn and anvil to the check station, activates the check station sensors at the check station, and determines a condition of the welding equipment by processing the received signals. Acoustic, force, temperature, displacement, amplitude, and/or attitude/gyroscopic sensors may be used.

Moissanite anvil cell design for Giga-Pascal nuclear magnetic resonance.

PubMed

Meier, Thomas; Herzig, Tobias; Haase, Jürgen

2014-04-01

A new design of a non-magnetic high-pressure anvil cell for nuclear magnetic resonance (NMR) experiments at Giga-Pascal pressures is presented, which uses a micro-coil inside the pressurized region for high-sensitivity NMR. The comparably small cell has a length of 22 mm and a diameter of 18 mm, so it can be used with most NMR magnets. The performance of the cell is demonstrated with external-force vs. internal-pressure experiments, and the cell is shown to perform well at pressures up to 23.5 GPa using 800 μm 6H-SiC large cone Boehler-type anvils. (1)H, (23)Na, (27)Al, (69)Ga, and (71)Ga NMR test measurements are presented, which show a resolution of better than 4.5 ppm, and an almost maximum possible signal-to-noise ratio.

Time differentiated nuclear resonance spectroscopy coupled with pulsed laser heating in diamond anvil cells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kupenko, I., E-mail: kupenko@esrf.fr; Strohm, C.; ESRF-The European Synchrotron, CS 40220, 38043 Grenoble Cedex 9

2015-11-15

Developments in pulsed laser heating applied to nuclear resonance techniques are presented together with their applications to studies of geophysically relevant materials. Continuous laser heating in diamond anvil cells is a widely used method to generate extreme temperatures at static high pressure conditions in order to study the structure and properties of materials found in deep planetary interiors. The pulsed laser heating technique has advantages over continuous heating, including prevention of the spreading of heated sample and/or the pressure medium and, thus, a better stability of the heating process. Time differentiated data acquisition coupled with pulsed laser heating in diamondmore » anvil cells was successfully tested at the Nuclear Resonance beamline (ID18) of the European Synchrotron Radiation Facility. We show examples applying the method to investigation of an assemblage containing ε-Fe, FeO, and Fe{sub 3}C using synchrotron Mössbauer source spectroscopy, FeCO{sub 3} using nuclear inelastic scattering, and Fe{sub 2}O{sub 3} using nuclear forward scattering. These examples demonstrate the applicability of pulsed laser heating in diamond anvil cells to spectroscopic techniques with long data acquisition times, because it enables stable pulsed heating with data collection at specific time intervals that are synchronized with laser pulses.« less

New developments in high pressure x-ray spectroscopy beamline at High Pressure Collaborative Access Team

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xiao, Y. M., E-mail: yxiao@carnegiescience.edu; Chow, P.; Boman, G.

The 16 ID-D (Insertion Device - D station) beamline of the High Pressure Collaborative Access Team at the Advanced Photon Source is dedicated to high pressure research using X-ray spectroscopy techniques typically integrated with diamond anvil cells. The beamline provides X-rays of 4.5-37 keV, and current available techniques include X-ray emission spectroscopy, inelastic X-ray scattering, and nuclear resonant scattering. The recent developments include a canted undulator upgrade, 17-element analyzer array for inelastic X-ray scattering, and an emission spectrometer using a polycapillary half-lens. Recent development projects and future prospects are also discussed.

Homogenizing Surface and Satellite Observations of Cloud. Aspects of Bias in Surface Data.

DTIC Science & Technology

1987-11-10

both ( pannus ), usually below fractus of bad weather, or both ( pannus ), usu- Altostratus or Nimbostratus ally below Altostratus or Nimbostratus 8 Cumulus...Stratocumulus, Stratus of an anvil; either accompanied or not by Cu- or pannus mulonimbus without anvil or fibrous upper part, by Cumulus, Stratocumulus...Stratus or pannus CL clouds invisible owing to darkness, fog, / Stratocumulus, Stratus, Cumulus and Cu- blowing dust or sand, or other similar mulonimbus

Integrated-fin gasket for palm cubic-anvil high pressure apparatus

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cheng, J.-G.; Beijing National Laboratory for Condensed Matter Physics and Institute of Physics, Chinese Academy of Sciences, Beijing 100190; Matsubayashi, K.

2014-09-15

We described an integrated-fin gasket technique for the palm cubic-anvil apparatus specialized for the high-pressure and low-temperature measurements. By using such a gasket made from the semi-sintered MgO ceramics and the tungsten-carbide anvils of 2.5 mm square top, we successfully generate pressures over 16 GPa at both room and cryogenic temperatures down to 0.5 K. We observed a pressure self-increment for this specific configuration and further characterized the thermally induced pressure variation by monitoring the antiferromagnetic transition temperature of chromium up to 12 GPa. In addition to enlarge the pressure capacity, such a modified gasket also improves greatly the survivingmore » rate of electrical leads hanging the sample inside a Teflon capsule filled with the liquid pressure-transmitting medium. These improvements should be attributed to the reduced extrusion of gasket materials during the initial compression.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bony, Sandrine; Stevens, Bjorn; Coppin, David

General circulation models show that as the surface temperature increases, the convective anvil clouds shrink. By analyzing radiative–convective equilibrium simulations, our work shows that this behavior is rooted in basic energetic and thermodynamic properties of the atmosphere: As the climate warms, the clouds rise and remain at nearly the same temperature, but find themselves in a more stable atmosphere; this enhanced stability reduces the convective outflow in the upper troposphere and decreases the anvil cloud fraction. By warming the troposphere and increasing the upper-tropospheric stability, the clustering of deep convection also reduces the convective outflow and the anvil cloud fraction.more » When clouds are radiatively active, this robust coupling between temperature, high clouds, and circulation exerts a positive feedback on convective aggregation and favors the maintenance of strongly aggregated atmospheric states at high temperatures. This stability iris mechanism likely contributes to the narrowing of rainy areas as the climate warms. Whether or not it influences climate sensitivity requires further investigation.« less

Comparison of Finite Element Modeling and Experimental Pressure Distribution in a Diamond Anvil Cell

NASA Astrophysics Data System (ADS)

Kondrat'yev, Andreiy I.; Murphy, Michael J.; Weir, Samuel T.; Vohra, Yogesh K.

2002-10-01

Ultra high pressures can be obtained in a Diamond Anvil Cell (DAC) device by optimizing the geometrical shape of diamond anvil and by use of high strength gasket materials. Radial pressure distribution in a diamond-coated rhenium gasket was measured by the micro-collimated X-ray diffraction techniques at NSLS, Brookhaven National Laboratory up to peak pressure of 220 GPa. The process of DAC compression was described by finite element analysis using NIKE-2D software. The mechanical properties of the diamond-coated gasket material were modeled and radial pressure distribution obtained was in good agreement with the experimental data. The calculated shear stress in diamond in the axial direction was shown to depend strongly on the yield strength of the gasket material and may limit the ultimate pressure that can be obtained with the use of high strength gasket materials. Supported by the National Science Foundation (NSF) Grant No. DMR-0203779.

Robotic end gripper with a band member to engage object

DOEpatents

Pollard, Roy E.; Robinson, Samuel C.; Thompson, William F.; Couture, Scott A.; Sutton, Bill J.

1994-01-01

An end effector for use with robotic arms and like devices that utilizes a flexible band to draw an object against an anvil having a concave surface. One typical convex surface is created by a V-block, with an apex of the V being centrally located. If an object to be grasped is fragile, the contour of the concave surface closely matches the surface of the object. Typically the movement of the band is effected by a linear actuator, with the anvil remaining fixed relative to a support base. Several embodiments are described that utilize variations in drawing the band toward the anvil, with one of these embodiments described in detail in the form of a fabricated unit. One embodiment includes a cover element that can be moved over an object after the grasping thereof, with this cover potentially serving various functions. Movement of the cover can be effected with a second linear actuator.

Zeeman Effect in Ruby at High Pressures

NASA Astrophysics Data System (ADS)

Dan, Ioana

2012-02-01

We have developed a versatile fiber-coupled system for magneto-optical spectroscopy measurements at high pressure. The system is based on a miniature Cu-alloy Diamond Anvil Cell (from D'Anvils, Ltd) fitted with a custom-designed He gas-actuated membrane for in-situ pressure control, and coupled with a He transfer cryostat incorporating a superconducting magnet (from Quantum Designs). This system allows optical measurements (Raman, photoluminescence, reflectivity) within wide ranges of pressures (up to 100GPa), temperatures (4.2-300K) and magnetic fields (0-9T). We employ this system to examine the effect of pressure and non-hydrostatic stress on the Zeeman split d-d transitions of Cr^3+ in ruby (Al2O3: Cr^3+). We determine the effect of pressure and non-hydrostaticity on the trigonal crystal field in this material, and discuss the use of the Zeman-split ruby fluorescence as a possible probe for deviatoric stresses in diamond anvil cell experiments.

Automatic monitoring of the alignment and wear of vibration welding equipment

DOEpatents

Spicer, John Patrick; Cai, Wayne W.; Chakraborty, Debejyo; Mink, Keith

2017-05-23

A vibration welding system includes vibration welding equipment having a welding horn and anvil, a host machine, a check station, and a welding robot. At least one displacement sensor is positioned with respect to one of the welding equipment and the check station. The robot moves the horn and anvil via an arm to the check station, when a threshold condition is met, i.e., a predetermined amount of time has elapsed or a predetermined number of welds have been completed. The robot moves the horn and anvil to the check station, activates the at least one displacement sensor, at the check station, and determines a status condition of the welding equipment by processing the received signals. The status condition may be one of the alignment of the vibration welding equipment and the wear or degradation of the vibration welding equipment.

Moissanite anvil cell design for giga-pascal nuclear magnetic resonance

DOE Office of Scientific and Technical Information (OSTI.GOV)

Meier, Thomas; Herzig, Tobias; Haase, Jürgen

2014-04-15

A new design of a non-magnetic high-pressure anvil cell for nuclear magnetic resonance (NMR) experiments at Giga-Pascal pressures is presented, which uses a micro-coil inside the pressurized region for high-sensitivity NMR. The comparably small cell has a length of 22 mm and a diameter of 18 mm, so it can be used with most NMR magnets. The performance of the cell is demonstrated with external-force vs. internal-pressure experiments, and the cell is shown to perform well at pressures up to 23.5 GPa using 800 μm 6H-SiC large cone Boehler-type anvils. {sup 1}H, {sup 23}Na, {sup 27}Al, {sup 69}Ga, and {supmore » 71}Ga NMR test measurements are presented, which show a resolution of better than 4.5 ppm, and an almost maximum possible signal-to-noise ratio.« less

Developing and bounding ice particle mass- and area-dimension expressions for use in atmospheric models and remote sensing

DOE PAGES

Erfani, Ehsan; Mitchell, David L.

2016-04-07

Here, ice particle mass- and projected area-dimension ( m- D and A- D) power laws are commonly used in the treatment of ice cloud microphysical and optical properties and the remote sensing of ice cloud properties. Although there has long been evidence that a single m- D or A- D power law is often not valid over all ice particle sizes, few studies have addressed this fact. This study develops self-consistent m- D and A- D expressions that are not power laws but can easily be reduced to power laws for the ice particle size (maximum dimension or D) rangemore » of interest, and they are valid over a much larger D range than power laws. This was done by combining ground measurements of individual ice particle m and D formed at temperature T < –20 °C during a cloud seeding field campaign with 2-D stereo (2D-S) and cloud particle imager (CPI) probe measurements of D and A, and estimates of m, in synoptic and anvil ice clouds at similar temperatures. The resulting m- D and A- D expressions are functions of temperature and cloud type (synoptic vs. anvil), and are in good agreement with m- D power laws developed from recent field studies considering the same temperature range (–60 °C < T < –20 °C).« less

KSC00pp0888

NASA Image and Video Library

2000-06-19

This anvil-shaped cloud over the Central Florida coast is part of a NASA study measuring electric fields in this type of cloud. A specially equipped Cessna Citation aircraft is being flown into anvil clouds in the KSC area . The weather study could lead to improved lightning avoidance rules and fewer launch scrubs for the Space Shuttle and other launch vehicles on the Eastern and Western ranges.; More information about the study can be found in Release No. 56-00

KSC-00pp0888

NASA Image and Video Library

2000-06-19

This anvil-shaped cloud over the Central Florida coast is part of a NASA study measuring electric fields in this type of cloud. A specially equipped Cessna Citation aircraft is being flown into anvil clouds in the KSC area . The weather study could lead to improved lightning avoidance rules and fewer launch scrubs for the Space Shuttle and other launch vehicles on the Eastern and Western ranges.; More information about the study can be found in Release No. 56-00

Gleeble Testing of Tungsten Samples

DTIC Science & Technology

2013-02-01

as a diffusion barrier to prevent the tungsten samples from fusing to the tungsten carbide inserts at elevated temperatures. After the anvils were...anvils with removable tungsten carbide inserts. The inserts were 19.05 mm (0.75 in) in diameter and 25.4 mm (1 in) long; they were purchased from...rhenium are shown in tables 6 and 7 and figure 7. The sample tested at 1300 °C, T4, partially embedded into the tungsten carbide (WC) inserts during

Mixing Layer Formation near the Tropopause Due to Gravity Wave Critical Level Interactions in a Cloud-Resolving Model.

NASA Astrophysics Data System (ADS)

Moustaoui, Mohamed; Joseph, Binson; Teitelbaum, Hector

2004-12-01

A plausible mechanism for the formation of mixing layers in the lower stratosphere above regions of tropical convection is demonstrated numerically using high-resolution, two-dimensional (2D), anelastic, nonlinear, cloud-resolving simulations. One noteworthy point is that the mixing layer simulated in this study is free of anvil clouds and well above the cloud anvil top located in the upper troposphere. Hence, the present mechanism is complementary to the well-known process by which overshooting cloud turrets causes mixing within stratospheric anvil clouds. The paper is organized as a case study verifying the proposed mechanism using atmospheric soundings obtained during the Central Equatorial Pacific Experiment (CEPEX), when several such mixing layers, devoid of anvil clouds, had been observed. The basic dynamical ingredient of the present mechanism is (quasi stationary) gravity wave critical level interactions, occurring in association with a reversal of stratospheric westerlies to easterlies below the tropopause region. The robustness of the results is shown through simulations at different resolutions. The insensitivity of the qualitative results to the details of the subgrid scheme is also evinced through further simulations with and without subgrid mixing terms. From Lagrangian reconstruction of (passive) ozone fields, it is shown that the mixing layer is formed kinematically through advection by the resolved-scale (nonlinear) velocity field.

Techniques, applications and future prospects of diamond anvil cells for studying supercritical water systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smith, Jr., R.L.; Fang, Z.; Tohoku)

In this review, diamond anvil type cells (DACs) are reviewed as a method for studying supercritical water systems. The hydrothermal DAC provides easy and safe experimental access to high pressure (30-3000 MPa) and high temperature (400-800 C) regions and the device allows exploration of supercritical systems at high density (400-1200 kg/m{sup 3}), which is usually difficult or costly with batch or flow systems. In the first part of this review, characteristics of DACs regarding anvil type, DAC type, anvil alignment, heating, analytical methods, pressure and temperature determination, gasket, loading, physical size are discussed with emphasis on DACs that can bemore » used to generate conditions of interest for understanding supercritical water systems. In the second part of this review, applications and key findings of studies on supercritical water systems from geology, chemical, biomass, energy, environmental, polymer, and materials related fields are discussed. Some of the key findings determined with DAC are related to the dissolution or existence of phases at conditions of high temperature and high pressure, however, DAC has been used in many quantitative studies to determine fundamental properties such as speeds of sound, phase behavior, solubilities, partition coefficients and viscosities. Future prospects for DAC as a method for exploring supercritical water systems include combination of DAC with transmission electron microscopy (TEM) for studying nanostructures, use of high-speed streak cameras to study high-speed reactions, combustions, and energetic materials, use of time-dependent loads to study kinetics, precipitation and crystallization phenomena, the use of DAC with synchrotron radiation to follow reaction and material processes in situ, and the many modifications that can be made to DAC anvils and rapid heating methods such as lasers and masers used in conjunction with in situ techniques. The DAC is a highly versatile instrument and should find widespread use in studying supercritical water systems.« less

Experimental Investigation of Magnetic Superconducting and other Phase Transitions in Novel f-Electron Materials at Ultra-high Pressures using Designer Diamond Anvils

DOE Office of Scientific and Technical Information (OSTI.GOV)

Maple, M. Brian; Jeffries, Jason R.; Ho, Pei-Chun

Pressure is often used as a controlled parameter for the investigation of condensed matter systems. In particular, pressure experiments can provide valuable information into the nature of superconductivity, magnetism, and the coexistence of these two phenomena. Some f-electron, heavy-fermion materials display interesting and novel behavior at moderately low pressures achievable with conventional experimental techniques; however, a growing number of condensed matter systems require ultrahigh pressure techniques, techniques that generate significantly higher pressures than conventional methods, to sufficiently explore their important properties. To that end, we have been funded to develop an ultrahigh pressure diamond anvil cell facility at the Universitymore » of California, San Diego (UCSD) in order to investigate superconductivity, magnetism, non-Fermi liquid behavior, and other phenomena. Our goals for the first year of this grant were as follows: (a) set up and test a suitable refrigerator; (b) set up a laser and spectrometer fluorescence system to determine the pressure within the diamond anvil cell; (c) perform initial resistivity measurements at moderate pressures from room temperature to liquid helium temperatures ({approx}1K); (d) investigate f-electron materials within our current pressure capabilities to find candidate materials for high-pressure studies. During the past year, we have ordered almost all the components required to set up a diamond anvil cell facility at UCSD, we have received and implemented many of the components that have been ordered, we have performed low pressure research on several materials, and we have engaged in a collaborative effort with Sam Weir at Lawrence Livermore National Lab (LLNL) to investigate Au4V under ultrahigh pressure in a designer diamond anvil cell (dDAC). This report serves to highlight the progress we have made towards developing an ultrahigh pressure research facility at UCSD, the research performed in the past year, as well as future directions we plan to pursue.« less

A Safe and Reproducible Anastomotic Technique for Minimally Invasive Ivor Lewis Esophagectomy: The Circular Stapled Anastomosis with the Transoral Anvil

PubMed Central

Campos, Guilherme M; Jablons, David; Brown, Lisa M; Ramirez, René M; Rabl, Charlotte; Theodore, Pierre

2010-01-01

Objectives In expert hands, the intra-thoracic esophago-gastric anastamosis usually provides a low rate of strictures and leaks. However, anastomoses can be technically challenging and time consuming when minimally invasive techniques are used. We present our preliminary results of a standardized 25mm/4.8mm circular stapled anastomosis using a trans-orally placed anvil. Materials and Methods We evaluated a prospective cohort of 37 consecutive patients offered minimally invasive Ivor Lewis Esophagectomy at a tertiary referral center. The esophagogastric anastomosis was created using a 25mm anvil (Orvil, Autosuture, Norwalk, CT) passed trans-orally, in a tilted position, and connected to a 90cm long PVC delivery tube through an opening in the esophageal stump. The anastomosis was completed by joining the anvil to a circular stapler (EEA XL 25mm with 4.8mm Staples, Autosuture, Norwalk, CT) inserted into the gastric conduit. Primary outcomes were leak and stricture rates. Results Thirty-seven patients (mean age 65 yrs) with distal esophageal adenocarcinoma (n=29), squamous cell cancer (n=5), or high-grade dysplasia in Barrett's Esophagus (n=3) underwent an Ivor Lewis Esophagectomy between October 2007 and August 2009. The abdominal portion of the operation was completed laparoscopically in 30 patients (81.1%). The thoracic portion was done using a muscle sparing mini-thoracotomy in 23 patients (62.2%) and thoracoscopic techniques in 14 patients (37.8%). There were no intra-operative technical failures of the anastomosis or deaths. Five patients had strictures (13.5%) and all were successfully treated with endoscopic dilations. One patient had an anastomotic leak (2.7%) that was successfully treated by re-operation and endoscopic stenting of the anastomosis. Discussion The circular stapled anastomosis with the transoral anvil allows for an efficient, safe and reproducible anastomosis. This straightforward technique is particularly suited to the completely minimally invasive Ivor Lewis Esophagectomy. PMID:20153660

An improved hydrothermal diamond anvil cell

NASA Astrophysics Data System (ADS)

Li, Jiankang; Bassett, W. A.; Chou, I.-Ming; Ding, Xin; Li, Shenghu; Wang, Xinyan

2016-05-01

A new type of HDAC-V hydrothermal diamond anvil cell (HDAC-VT) has been designed to meet the demands of X-ray research including X-Ray Fluorescence, X-ray Absorption Spectroscopy, and small angle X-ray scattering. The earlier version of HDAC-V that offered a large rectangular solid angle used two posts and two driver screws on both sides of a rectangular body. The new version HDAC-VT in a triangular shape has two alternative guide systems, either three posts inserted into bushings suitable for small anvil faces or linear ball bearings suitable for large anvil faces. The HDAC-VT having three driver screws offers the advantage of greater control and stability even though it sacrifices some of the size of solid angle. The greater control allows better sealing of samples, while greater stability results in longer survival for anvils and ceramic parts. This improved design retains several beneficial features of the original HDAC-V as well. These include the small collar that surrounds the heater and sample chamber forming an Ar + H2 gas chamber to protect diamonds and their heating parts from being oxidized. Three linear ball bearings, when used, fit to the three posts prevent seizing that can result from deterioration of lubricant at high temperatures. Positioning the posts and bearings outside of the gas chamber as in HDAC-V also prevents seizing and possible deformation due to overheating. In order to control the heating rate precisely with computer software, we use Linkam T95 and have replaced the Linkam 1400XY heating stage with the HDAC-VT allowing the HDAC to be heated to 950 °C at a rate from 0.01 °C/min to 50 °C/min. We have used the HDAC-VT and Linkam T95 to observe in situ nucleation and growth of zabuyelite in aqueous fluid and to homogenize melt inclusions in quartz from three porphyry deposits in Shanxi, China.

11. BUILDING NO. 620B. INTERIOR VIEW LOOKING NORTH, SHOWING PENDULUM ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

11. BUILDING NO. 620-B. INTERIOR VIEW LOOKING NORTH, SHOWING PENDULUM AND FRAME IN FOREGROUND, SHIELD FOR OPERATORS IN BACKGROUND. FRICTION TEST IS OBSERVED FROM BEHIND BLAST SHIELD BY A SERIES OF MIRRORS. ANVIL IN CENTER OF PENDULUM FRAME HOLDS EXPLOSIVE WHOSE SENSITIVITY TO FRICTION IS TO BE TESTED. PANS ON EITHER SIDE CATCH ANY UNBURNT EXPLOSIVE SLUNG FROM ANVIL DURING TEST TO PREVENT EXPLOSIVE HAZARD. - Picatinny Arsenal, 600 Area, Test Areas District, State Route 15 near I-80, Dover, Morris County, NJ

Analysis of satellite data for sensor improvement (detection of severe storms from space)

NASA Technical Reports Server (NTRS)

Fujita, T. T.

1984-01-01

Stereo photography of clouds over southeast Asia was obtained using NOAA-7 and the Japanese GMS. Due to the breakdown of GMS2, GMS1, which had been retired, is being used as the replacement satellite. The launch of GMS should permit the US-Japan stereo experiment to be reactivated. The Lear jet experiment based at Grand Island, Nebraska was successful and provided data on the Redwood Falls clouds & Grand Island thunderstorm; an anvil-top cirrus deck; a circular thunderstorm; and jumping cirrus. The IR temperature field of the thunderstorm which induced the Andrews AFB microburst was analyzed with 1 C accuracy. The microburst and severe thunderstorm project is being planned.

Passive microwave structure of severe tornadic storms on 16 November 1987

NASA Technical Reports Server (NTRS)

Heymsfield, Gerald M.; Fulton, Richard

1994-01-01

Passive microwave observations using the Special Sensor Microwave/Imager (SSM/I) are presented for severe tornadic storms in the lower midwestern United States on 16 November 1987. These measurements are compared with Geostationary Operational Environmental Satellite infrared (IR) measurements for the same case. The IR observations had a classic 'V' cold feature commonly associated with severe Midwest thunderstorms. The minimum microwave brightness temperatures at 86 GHz, which primarily respond to ice scattering by larger ice particles, were located in the convective region and the warm interior of the anvil top, between the arms of the IR V feature. The interior warm region was the only portion of the entire anvil region that had high 86-GHz polarization difference temperatures. Microphysical implications of these multispectral observations are discussed. The observations suggest that there are large variations of ice microphysical characteristics spatially and vertically in the anvil region. These observations are discussed in the context of previous dynamical and microphysical hypotheses on the IR V feature.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kim, Jungho

Hard x-ray resonant inelastic x-ray scattering (RIXS) is a promising x-ray spectroscopic tool for measuring low-energy excitation spectra at high pressure which have been stymied heretofore by the technical difficulties inherent in measuring a sample held at high pressure in a diamond anvil cell. The currently available facilities of high resolution (< 200 meV) RIXS has been used to probe low-energy excitation spectra from the diamond anvil cell, by virtue of advanced photon detection instrumentations of high-brilliance synchrotron x-ray radiation sources. Compared to a structural elastic scattering and x-ray emission, RIXS is a photon hungry technique and high-resolution RIXS undermore » high pressure is at its infancy stage. In this review, the fundamentals of RIXS including instrumentation of high-resolution RIXS are presented and then experimental details of diamond anvil cell, sample preparation and measurement geometry are discussed. Experimental data of 3d and 5d transition metal oxides are presented. Finally, future improvements in high-resolution RIXS instrumentation for the high pressure experiment is discussed.« less

An estimate of the NO(x) production rate in electrified clouds based on NO observations from the GTE/CITE 1 fall 1983 field operation

NASA Technical Reports Server (NTRS)

Chameides, W. L.; Davis, D. D.; Bradshaw, J.; Rodgers, M.; Sandholm, S.

1987-01-01

During the NASA GTE/CITE 1 fall 1983 airborne field operation the NASA Convair 990 penetrated the anvils of two active cumulonimbus clouds. While NO levels outside the anvils averaged about 20 parts per trillion per volume (pptv), the average NO inside the anvils was about 440 pptv. Extrapolation of this observation along with data on the amount of air typically advected out of cumulonimbus clouds and the total number of thunderclouds occurring over the globe at any moment, implies a rate of nitrogen fixation in electrified clouds of about 7 x 10 to the 6th trillion/yr. Although the data base used to make this estimate is quite limited, the approach differs from that used in previous studies of the global production of nitrogen oxides by lightning, and thus represents an independent assessment of the role of electrified clouds in the atmospheric nitrogen oxide budget.

Effective Ice Particle Densities for Cold Anvil Cirrus

NASA Technical Reports Server (NTRS)

Heymsfield, Andrew J.; Schmitt, Carl G.; Bansemer, Aaron; Baumgardner, Darrel; Weinstock, Elliot M.; Smith, Jessica

2002-01-01

This study derives effective ice particle densities from data collected from the NASA WB-57F aircraft near the tops of anvils during the Cirrus Regional Study of Tropical Anvils and Cirrus Layers (CRYSTAL) Florida Area Cirrus Experiment (FACE) in southern Florida in July 2002. The effective density, defined as the ice particle mass divided by the volume of an equivalent diameter liquid sphere, is obtained for particle populations and single sizes containing mixed particle habits using measurements of condensed water content and particle size distributions. The mean effective densities for populations decrease with increasing slopes of the gamma size distributions fitted to the size distributions. The population-mean densities range from near 0.91 g/cu m to 0.15 g/cu m. Effective densities for single sizes obey a power-law with an exponent of about -0.55, somewhat less steep than found from earlier studies. Our interpretations apply to samples where particle sizes are generally below 200-300 microns in maximum dimension because of probe limitations.

Validation Study of Unnotched Charpy and Taylor-Anvil Impact Experiments using Kayenta

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kamojjala, Krishna; Lacy, Jeffrey; Chu, Henry S.

2015-03-01

Validation of a single computational model with multiple available strain-to-failure fracture theories is presented through experimental tests and numerical simulations of the standardized unnotched Charpy and Taylor-anvil impact tests, both run using the same material model (Kayenta). Unnotched Charpy tests are performed on rolled homogeneous armor steel. The fracture patterns using Kayenta’s various failure options that include aleatory uncertainty and scale effects are compared against the experiments. Other quantities of interest include the average value of the absorbed energy and bend angle of the specimen. Taylor-anvil impact tests are performed on Ti6Al4V titanium alloy. The impact speeds of the specimenmore » are 321 m/s and 393 m/s. The goal of the numerical work is to reproduce the damage patterns observed in the laboratory. For the numerical study, the Johnson-Cook failure model is used as the ductile fracture criterion, and aleatory uncertainty is applied to rate-dependence parameters to explore its effect on the fracture patterns.« less

The Hydrothermal Diamond Anvil Cell (HDAC) for raman spectroscopic studies of geologic fluids at high pressures and temperatures

USGS Publications Warehouse

Schmidt, Christian; Chou, I-Ming; Dubessy, Jean; Caumon, Marie-Camille; Pérez, Fernando Rull

2012-01-01

In this chapter, we describe the hydrothermal diamond-anvil cell (HDAC), which is specifically designed for experiments on systems with aqueous fluids to temperatures up to ⬚~1000ºC and pressures up to a few GPa to tens of GPa. This cell permits optical observation of the sample and the in situ determination of properties by ‘photon-in photon-out’ techniques such as Raman spectroscopy. Several methods for pressure measurement are discussed in detail including the Raman spectroscopic pressure sensors a-quartz, berlinite, zircon, cubic boron nitride (c-BN), and 13C-diamond, the fluorescence sensors ruby (α-Al2O3:Cr3+), Sm:YAG (Y3Al5O12:Sm3+) and SrB4O7:Sm2+, and measurements of phase-transition temperatures. Furthermore, we give an overview of published Raman spectroscopic studies of geological fluids to high pressures and temperatures, in which diamond anvil cells were applied.

Chapter 7: The hydrothermal diamond anvil cell (HDAC) for Raman spectroscopic studies of geological fluids at high pressures and temperatures

USGS Publications Warehouse

Schmidt, Christian; Chou, I-Ming; Dubessy, J.; Caumon, M.-C.; Rull, F.

2012-01-01

In this chapter, we describe the hydrothermal diamond-anvil cell (HDAC), which is specifically designed for experiments on systems with aqueous fluids to temperatures up to ~1000ºC and pressures up to a few GPa to tens of GPa. This cell permits optical observation of the sample and the in situ determination of properties by ‘photon-in photon-out’ techniques such as Raman spectroscopy. Several methods for pressure measurement are discussed in detail including the Raman spectroscopic pressure sensors a-quartz, berlinite, zircon, cubic boron nitride (c-BN), and 13C-diamond, the fluorescence sensors ruby (α-Al2O3:Cr3+), Sm:YAG (Y3Al5O12:Sm3+) and SrB4O7:Sm2+, and measurements of phase-transition temperatures. Furthermore, we give an overview of published Raman spectroscopic studies of geological fluids to high pressures and temperatures, in which diamond anvil cells were applied.

Robotic end gripper with a band member to engage object

DOEpatents

Pollard, R.E.; Robinson, S.C.; Thompson, W.F.; Couture, S.A.; Sutton, B.J.

1994-05-10

An end effector for use with robotic arms and like devices is described that utilizes a flexible band to draw an object against an anvil having a concave surface. One typical convex surface is created by a V-block, with an apex of the V being centrally located. If an object to be grasped is fragile, the contour of the concave surface closely matches the surface of the object. Typically the movement of the band is effected by a linear actuator, with the anvil remaining fixed relative to a support base. Several embodiments are described that utilize variations in drawing the band toward the anvil, with one of these embodiments described in detail in the form of a fabricated unit. One embodiment includes a cover element that can be moved over an object after the grasping thereof, with this cover potentially serving various functions. Movement of the cover can be effected with a second linear actuator. 8 figures.

Spray-loading: A cryogenic deposition method for diamond anvil cell

NASA Astrophysics Data System (ADS)

Scelta, Demetrio; Ceppatelli, Matteo; Ballerini, Riccardo; Hajeb, Ahmed; Peruzzini, Maurizio; Bini, Roberto

2018-05-01

An efficient loading technique has been developed for flammable, toxic, or explosive gases which can be condensed at liquid nitrogen temperature and ambient pressure in membrane diamond anvil cells (DACs). This cryogenic technique consists in a deposition of small quantities of the desired gas directly into the sample chamber. The deposition is performed using a capillary that reaches the space between the diamond anvils. The DAC is kept under inert gas overpressure during the whole process, in order to avoid contamination from atmospheric O2, CO2, and H2O. This technique provides significant advantages over standard cryo-loading and gas-loading when the condensation of dangerous samples at liquid nitrogen temperature raises safety concerns because it allows dealing with minimum quantities of condensed gases. The whole procedure is particularly fast and efficient. The "spray-loading" has been successfully used in our laboratory to load several samples including acetylene, ammonia, ethylene, and carbon dioxide/water or red phosphorus/NH3 mixtures.

Friction Stir Welding of Line-Pipe Steels

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sanderson, Samuel; Mahoney, Murray; Feng, Zhili

Friction stir welding (FSW) offers both economic and technical advantages over conventional fusion welding practices for welding line-pipe. For offshore line-pipe construction, the economic savings has been shown to be considerable, approaching a calculated 25%. Offshore pipe is relatively small diameter but heavy wall compared to onshore pipe. One concern is the ability to achieve consistent full weld penetration in an on-site offshore FSW operation, e.g., on a lay-barge. In addition, depending on the size and morphology of the unwelded zone, lack of penetration at the weld root can be difficult if not impossible to detect by conventional NDE methods.more » Thus, an approach to assure consistent full penetration via process control is required for offshore line-pipe construction using FSW. For offshore construction, an internal structural mandrel can be used offering the opportunity to use a sacrificial anvil FSW approach. With this approach, a small volume of sacrificial material can be inserted into the structural anvil. The FSW tool penetrates into the sacrificial anvil, beyond the inner diameter of the pipe wall, thus assuring full penetration. The sacrificial material is subsequently removed from the pipe inner wall. In the work presented herein, FSW studies were completed on both 6 mm and 12 mm wall thickness line-pipe. Lastly, post-FSW evaluations including radiography, root-bend tests, and metallography demonstrated the merits of the sacrificial anvil approach to achieve consistent full penetration.« less

A new diamond anvil cell for hydrothermal studies to 2.5 GPa and from -190 to 1200 °C

USGS Publications Warehouse

Bassett, William A.; Shen, A.H.; Bucknum, M.; Chou, I.-Ming

1993-01-01

A new style of diamond anvil cell(DAC) has been designed and built for conducting research in fluids at pressures to 2.5 GPa and temperatures from −190 to 1200 °C. The new DAC has been used for optical microscope observations and synchrotron x‐ray diffraction studies. Fringes produced by interference of laser light reflected from top and bottom anvil faces and from top and bottom sample faces provide a very sensitive means of monitoring the volume of sample chamber and for observing volume and refractive index changes in samples that have resulted from transitions and reactions. X‐ray diffraction patterns of samples under hydrothermal conditions have been made by the energy dispersive method using synchrotron radiation. The new DAC has individual heaters and individual thermocouples for the upper and lower anvils that can be controlled and can maintain temperatures with an accuracy of ±0.5 °C. Low temperatures are achieved by introducing liquid nitrogen directly into the DAC. The equation of state of H2O and the α‐β quartz transition are used to determine pressure with an accuracy of ±1% in the aqueous samples. The new DAC has been used to redetermine five isochores of H2O as well as the dehydration curves of brucite, Mg(OH)2, and muscovite, KAl2(Si3Al)O10(OH)2.

Designer Diamonds: Applications in Iron-based Superconductors and Lanthanides

NASA Astrophysics Data System (ADS)

Vohra, Yogesh

2013-06-01

This talk will focus on the recent progress in the fabrication of designer diamond anvils as well as scientific applications of these diamonds in static high pressure research. The two critical parameters that have emerged in the microwave plasma chemical vapor deposition of designer diamond anvils are (1) the precise [100] alignment of the starting diamond substrate and (2) balancing the competing roles of parts per million levels of nitrogen and oxygen in the diamond growth plasma. The control of these parameters results in the fabrication of high quality designer diamonds with culet size in excess of 300 microns in diameter. The three different applications of designer diamond anvils will be discussed (1) simultaneous electrical resistance and crystal structure measurements using a synchrotron source on Iron-based superconductors with data on both electron and hole doped BaFe2As2 materials and other novel superconducting materials (2) high-pressure high-temperature melting studies on metals using eight-probe Ohmic heating designer diamonds and (3) high pressure low temperature studies on magnetic behavior of 4f-lanthanide metals using four-probe electrical resistance measurements and complementary neutron diffraction studies on a spallation neutron source. Future opportunities in boron-doped conducting designer diamond anvils as well as fabrication of two-stage designer diamonds for ultra high pressure experiments will also be presented. This work was supported by the Department of Energy (DOE) - National Nuclear Security Administration (NNSA) under Grant No. DE-FG52-10NA29660.

Analysis of TRMM Microphysical Measurements: Tropical Rainfall Measuring Mission (TRMM)

NASA Technical Reports Server (NTRS)

2004-01-01

SPEC Incorporated participated in three of the four TRMM field campaigns (TEFLUN-A, TEFLUN-B and KWAJEX), installing and operating a cloud particle imager (CPI) and a high volume precipitation spectrometer (HVPS) on the SPEC Learjet in TEFLUN-A, the University of North Dakota Citation in TEFLUN-B and KWAJEX, and a CPI on the NASA DC-8 in KWAJEX. This report presents and discusses new software tools and algorithms that were developed to analyze microphysical data collected during these field campaigns, as well as scientific interpretations of the data themselves. Software algorithms were developed to improve the analysis of microphysical measurements collected by the TRMM aircraft during the field campaigns. Particular attention was paid to developing and/or improving algorithms used to compute particle size distributions and ice water content. Software was also developed in support of production of the TRMM Common Microphysical Product (CMP) data files. CMP data files for TEFLUN-A field campaign were produced and submitted to the DAAC. Typical microphysical properties of convective and stratiform regions from TEFLUN-A and KWAJEX clouds were produced. In general, it was found that in the upper cloud region near -20 to -25 C, stratiform clouds contain very high (greater than 1 per cubic centimeter) concentrations of small ice particles, which are suspected to be a residual from homogeneous freezing and sedimentation of small drops in a convective updraft. In the upper cloud region near -20 to -25 C, convective clouds contain aggregates, which are not found lower in the cloud. Stratiform clouds contain aggregates at all levels, with the majority in the lowest levels. Convective cloud regions contain much higher LWC and drop concentrations than stratiform regions at all levels, and higher LWC in the middle and upper regions. Stratiform clouds contain higher IWC than convective clouds only at the lowest level. Irregular shaped ice particles are found in very high concentrations throughout both convective and stratiform cloud regions. A striking difference in particle shape in cirrus formed in situ, cirrus formed from maritime anvils and cirrus formed from continental anvils. Over 50% of the mass of in situ cirrus ice particles is composed of bullet rosettes, while bullet rosettes are virtually non-existent in maritime and tropical anvils. Tropical anvils are composed of mostly singular, plates, capped columns, and blocky irregular shapes, while continental anvils have a much higher percentage of aggregates, some of which are chains of small spheroidal particles that appear to result from homogeneous freezing of drops. A correlation between high electric fields in continental anvils and the formation of aggregates is hypothesized.

A safe and reproducible anastomotic technique for minimally invasive Ivor Lewis oesophagectomy: the circular-stapled anastomosis with the trans-oral anvil.

PubMed

Campos, Guilherme M; Jablons, David; Brown, Lisa M; Ramirez, René M; Rabl, Charlotte; Theodore, Pierre

2010-06-01

In expert hands, the intrathoracic oesophago-gastric anastamosis usually provides a low rate of strictures and leaks. However, anastomoses can be technically challenging and time consuming when minimally invasive techniques are used. We present our preliminary results of a standardised 25 mm/4.8mm circular-stapled anastomosis using a trans-orally placed anvil. We evaluated a prospective cohort of 37 consecutive patients offered minimally invasive Ivor Lewis oesophagectomy at a tertiary referral centre. The oesophago-gastric anastomosis was created using a 25-mm anvil (Orvil, Autosuture, Norwalk, CT, USA) passed trans-orally, in a tilted position, and connected to a 90-cm long polyvinyl chloride delivery tube through an opening in the oesophageal stump. The anastomosis was completed by joining the anvil to a circular stapler (end-to-end anastomosis stapler (EEA XL) 25 mm with 4.8-mm staples, Autosuture, Norwalk, CT, USA) inserted into the gastric conduit. Primary outcomes were leak and stricture rates. Thirty-seven patients (mean age 65 years) with distal oesophageal adenocarcinoma (n=29), squamous cell cancer (n=5) or high-grade dysplasia in Barrett's oesophagus (n=3) underwent an Ivor Lewis oesophagectomy between October 2007 and August 2009. The abdominal portion was operated laparoscopically in 30 patients (81.1%). The thoracic portion was done using a muscle-sparing mini-thoracotomy in 23 patients (62.2%) and thoracoscopic techniques in 14 patients (37.8%). There were no intra-operative technical failures of the anastomosis or deaths. Five patients had strictures (13.5%) and all were successfully treated with endoscopic dilations. One patient had an anastomotic leak (2.7%) that was successfully treated by re-operation and endoscopic stenting of the anastomosis. The circular-stapled anastomosis with the trans-oral anvil allows for an efficient, safe and reproducible anastomosis. This straightforward technique is particularly suited to the completely minimally invasive Ivor Lewis oesophagectomy. Copyright 2010 European Association for Cardio-Thoracic Surgery. Published by Elsevier B.V. All rights reserved.

Acoustic travel time gauges for in-situ determination of pressure and temperature in multi-anvil apparatus

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Xuebing; Chen, Ting; Qi, Xintong

In this study, we developed a new method for in-situ pressure determination in multi-anvil, high-pressure apparatus using an acoustic travel time approach within the framework of acoustoelasticity. The ultrasonic travel times of polycrystalline Al{sub 2}O{sub 3} were calibrated against NaCl pressure scale up to 15 GPa and 900 °C in a Kawai-type double-stage multi-anvil apparatus in conjunction with synchrotron X-radiation, thereby providing a convenient and reliable gauge for pressure determination at ambient and high temperatures. The pressures derived from this new travel time method are in excellent agreement with those from the fixed-point methods. Application of this new pressure gauge in anmore » offline experiment revealed a remarkable agreement of the densities of coesite with those from the previous single crystal compression studies under hydrostatic conditions, thus providing strong validation for the current travel time pressure scale. The travel time approach not only can be used for continuous in-situ pressure determination at room temperature, high temperatures, during compression and decompression, but also bears a unique capability that none of the previous scales can deliver, i.e., simultaneous pressure and temperature determination with a high accuracy (±0.16 GPa in pressure and ±17 °C in temperature). Therefore, the new in-situ Al{sub 2}O{sub 3} pressure gauge is expected to enable new and expanded opportunities for offline laboratory studies of solid and liquid materials under high pressure and high temperature in multi-anvil apparatus.« less

Refinement of pressure calibration for multi-anvil press experiments

NASA Astrophysics Data System (ADS)

Ono, S.

2016-12-01

Accurate characterization of the pressure and temperature environment in high-pressure apparatuses is of essential importance when we apply laboratory data to the study of the Earth's interior. Recently, the synchrotron X-ray source can be used for the high-pressure experiments, and the in situ pressure calibration has been a common technique. However, this technique cannot be used in the laboratory-based experiments. Even now, the conventional pressure calibration is of great interest to understand the Earth's interior. Several high-pressure phase transitions used as the pressure calibrants in the laboratory-based multi-anvil experiments have been investigated. Precise determinations of phase boundaries of CaGeO3 [1], Fe2SiO4 [2], SiO2, and Zr [3] were performed by the multi-anvil press or the diamond anvil cell apparatuses combined with the synchrotron X-ray diffraction technique. The transition pressures in CaGeO3 (garnet-perovskite), Fe2SiO4 (alfa-gamma), and SiO2 (coesite-stishovite) were in general agreement with those reported by previous studies. However, significant discrepancies for the slopes, dP/dT, of these transitions between our and previous studies were confirmed. In the case of Zr study [3], our experimental results elucidate the inconsistency in the transition pressure between omega and beta phase in Zr observed in previous studies. [1] Ono et al. (2011) Phys. Chem. Minerals, 38, 735-740.[2] Ono et al. (2013) Phys. Chem. Minerals, 40, 811-816.[3] Ono & Kikegawa (2015) J. Solid State Chem., 225, 110-113.

Gas loading apparatus for the Paris-Edinburgh press

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bocian, A.; Kamenev, K. V.; Bull, C. L.

2010-09-15

We describe the design and operation of an apparatus for loading gases into the sample volume of the Paris-Edinburgh press at room temperature and high pressure. The system can be used for studies of samples loaded as pure or mixed gases as well as for loading gases as pressure-transmitting media in neutron-scattering experiments. The apparatus consists of a high-pressure vessel and an anvil holder with a clamp mechanism. The vessel, designed to operate at gas pressures of up to 150 MPa, is used for applying the load onto the anvils located inside the clamp. This initial load is sufficient formore » sealing the pressurized gas inside the sample containing gasket. The clamp containing the anvils and the sample is then transferred into the Paris-Edinburgh press by which further load can be applied to the sample. The clamp has apertures for scattered neutron beams and remains in the press for the duration of the experiment. The performance of the gas loading system is illustrated with the results of neutron-diffraction experiments on compressed nitrogen.« less

An Intelligent Monitoring Network for Detection of Cracks in Anvils of High-Press Apparatus.

PubMed

Tian, Hao; Yan, Zhaoli; Yang, Jun

2018-04-09

Due to the endurance of alternating high pressure and temperature, the carbide anvils of the high-press apparatus, which are widely used in the synthetic diamond industry, are prone to crack. In this paper, an acoustic method is used to monitor the crack events, and the intelligent monitoring network is proposed to classify the sound samples. The pulse sound signals produced by such cracking are first extracted based on a short-time energy threshold. Then, the signals are processed with the proposed intelligent monitoring network to identify the operation condition of the anvil of the high-pressure apparatus. The monitoring network is an improved convolutional neural network that solves the problems that may occur in practice. The length of pulse sound excited by the crack growth is variable, so a spatial pyramid pooling layer is adopted to solve the variable-length input problem. An adaptive weighted algorithm for loss function is proposed in this method to handle the class imbalance problem. The good performance regarding the accuracy and balance of the proposed intelligent monitoring network is validated through the experiments finally.

Experimental technique for measuring the isentrope of hydrogen to several megabars

NASA Astrophysics Data System (ADS)

Barker, L. M.; Truncano, T. G.; Wise, J. I.; Asay, J. R.

The experimental measurement of the Equations of State (EOS) of hydrogen has been of interest for some time because of the theoretical expectation of a transition to the metallic state in the multi-megabar pressure regime. Previous experiments have reported results which are consistent with a metallic transition, but experimental uncertainties have precluded positive identification of the metallic phase. In this paper we describe a new experimental approach to the measurement of the high-pressure EOS of hydrogen. A cryogenic hydrogen specimen, either liquid or solid, is located in the muzzle of a gun barrel between a tungsten anvil and another tungsten disk called a shim. Helium gas in the gun barrel cushions the impact and allows nearly isentropic compression of the hydrogen. The time-resolved pressure in the specimen is calculated from a laser interferometer (VISAR) measurement of the acceleration history of the anvil's free surface, and volume measurements at specific times are made by combining VISAR data, which define the position of the anvil, with flash X-ray photographs which define the shim position.

Minerals of the earth's deep interior

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schiferl, D.; Zhao, Y.; Shankland, T.J.

1998-11-01

This is the final report of a three-year, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). The project addresses the major geophysical issue of the nature of the seismic velocity and density discontinuity at 670 km depth (the boundary between upper and lower mantle with temperature about 1,900 K and pressure about 23 GPa). A phase change at this depth would represent a relatively small barrier to mantle convection through the discontinuity, but compositional change would inhibit thermal convection throughout the mantle. To address this problem the authors measured equation of state parameters in mantlemore » minerals as functions of high P-T using single crystal x-ray diffraction with a unique, new diamond-anvil cell (DAC) at simultaneous high temperature and pressure. Single-crystal diffraction improves absolute accuracy in lattice constants over those from powder diffraction by a factor of 5 to 10. The authors have measured equations of state of orthoenstatite MgSiO{sub 3} and hexagonal boron nitride hBN.« less

Preparation of W-Ta thin-film thermocouple on diamond anvil cell for in-situ temperature measurement under high pressure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang Jie; Fundamental Department, Aviation University, Changchun 130022; Li Ming

2011-04-15

In this paper, a W-Ta thin-film thermocouple has been integrated on a diamond anvil cell by thin-film deposition and photolithography methods. The thermocouple was calibrated and its thermal electromotive force was studied under high pressure. The results indicate that the thermal electromotive force of the thermocouple exhibits a linear relationship with temperature and is not associated with pressure. The resistivity measurement of ZnS powders under high pressure at different temperatures shows that the phase transition pressure decreases as the temperature increases.

Preparation of W-Ta thin-film thermocouple on diamond anvil cell for in-situ temperature measurement under high pressure.

PubMed

Yang, Jie; Li, Ming; Zhang, Honglin; Gao, Chunxiao

2011-04-01

In this paper, a W-Ta thin-film thermocouple has been integrated on a diamond anvil cell by thin-film deposition and photolithography methods. The thermocouple was calibrated and its thermal electromotive force was studied under high pressure. The results indicate that the thermal electromotive force of the thermocouple exhibits a linear relationship with temperature and is not associated with pressure. The resistivity measurement of ZnS powders under high pressure at different temperatures shows that the phase transition pressure decreases as the temperature increases. © 2011 American Institute of Physics

Parameterizations of the Vertical Variability of Tropical Cirrus Cloud Microphysical and Optical Properties

NASA Technical Reports Server (NTRS)

Twohy, Cynthia; Heymsfield, Andrew; Gerber, Hermann

2005-01-01

Our multi-investigator effort was targeted at the following areas of interest to CRYSTAL-FACE: (1) the water budgets of anvils, (2) parameterizations of the particle size distributions and related microphysical and optical properties (3) characterizations of the primary ice particle habits, (4) the relationship of the optical properties to the microphysics and particle habits, and (5) investigation of the ice-nuclei types and mechanisms in anvil cirrus. Dr. Twohy's effort focused on (l), (2), and (5), with the measurement and analysis of ice water content and cirrus residual nuclei using the counterflow virtual impactor (CVI).

Susceptibility measurements at high pressures using a microcoil system in an anvil cell

NASA Astrophysics Data System (ADS)

Alireza, Patricia Lebre; Julian, Stephen R.

2003-11-01

We present here a microcoil setup for susceptibility measurements in anvil cells. In contrast to previous designs, we have placed the secondary coil inside the high pressure volume. This dramatically boosts the signal and eliminates the need for complex background subtraction. For samples of lead, tin, and the metal-insulator oxide calcium ruthenate (Ca2RuO4), our procedure has produced very clear signals for both superconducting transitions and ferromagnetic ordering with a weak magnetic moment (0.2μB/Ru), up to 75 kbar, with a signal-to-noise ratio of ˜80.

Dimensions and aspect ratios of natural ice crystals

DOE PAGES

Um, J.; McFarquhar, G. M.; Hong, Y. P.; ...

2015-04-15

During the 2006 Tropical Warm Pool International Cloud Experiment (TWP-ICE) in the tropics, the 2008 Indirect and Semi-Direct Aerosol Campaign (ISDAC) in the Arctic, and the 2010 Small PARTicles In CirrUS (SPARTICUS) campaign at mid-latitudes, high-resolution images of ice crystals were recorded by a Cloud Particle Imager at temperatures ( T) between -87 and 0 °C. The projected maximum dimension ( D'), length ( L'), and width ( W') of pristine columns, plates, and component bullets of bullet rosettes were measured using newly developed software, the Ice Crystal Ruler. The number of bullets in each bullet rosette was also measured.more » Column crystals were further distinguished as either horizontally oriented columns or columns with other orientations to eliminate any orientation effect on the measured dimensions. The dimensions and aspect ratios (AR, the dimension of the major axis divided by the dimension of the minor axis) of crystals were determined as functions of temperature, geophysical location, and type of cirrus. Dimensions of crystals generally increased with temperature. Columns and bullets had larger dimensions (i.e., W') of the minor axis (i.e., a axis) for a given dimension (i.e., D' or L') of the major axis (i.e., c axis), and thus smaller AR, as T increased, whereas this trend did not occur for plate crystals. The average number of branches in bullet rosettes was 5.50 ± 1.35 during three campaigns and 6.32 ± 1.34 (5.46 ± 1.34; 4.95 ± 1.01) during TWP-ICE (SPARTICUS; ISDAC). The AR of bullets increased with the number of branches in bullet rosettes. Most dimensions of crystals and ARs of columnar crystals measured during SPARTICUS were larger than those measured during TWP-ICE and ISDAC at −67 < T < -35 °C and at −40 < T < −15 °C, respectively. The relative occurrence of varying pristine habits depended strongly on cirrus type (i.e., anvil or non-anvil clouds), with plates especially occurring more frequently in anvils. Finally, the L– W relationships of columns derived using current data exhibited a strong dependence on temperature; similar relationships determined in previous studies were within the range of the current data.« less

Dimensions and aspect ratios of natural ice crystals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Um, J.; McFarquhar, G. M.; Hong, Y. P.

During the 2006 Tropical Warm Pool International Cloud Experiment (TWP-ICE) in the tropics, the 2008 Indirect and Semi-Direct Aerosol Campaign (ISDAC) in the Arctic, and the 2010 Small PARTicles In CirrUS (SPARTICUS) campaign at mid-latitudes, high-resolution images of ice crystals were recorded by a Cloud Particle Imager at temperatures ( T) between -87 and 0 °C. The projected maximum dimension ( D'), length ( L'), and width ( W') of pristine columns, plates, and component bullets of bullet rosettes were measured using newly developed software, the Ice Crystal Ruler. The number of bullets in each bullet rosette was also measured.more » Column crystals were further distinguished as either horizontally oriented columns or columns with other orientations to eliminate any orientation effect on the measured dimensions. The dimensions and aspect ratios (AR, the dimension of the major axis divided by the dimension of the minor axis) of crystals were determined as functions of temperature, geophysical location, and type of cirrus. Dimensions of crystals generally increased with temperature. Columns and bullets had larger dimensions (i.e., W') of the minor axis (i.e., a axis) for a given dimension (i.e., D' or L') of the major axis (i.e., c axis), and thus smaller AR, as T increased, whereas this trend did not occur for plate crystals. The average number of branches in bullet rosettes was 5.50 ± 1.35 during three campaigns and 6.32 ± 1.34 (5.46 ± 1.34; 4.95 ± 1.01) during TWP-ICE (SPARTICUS; ISDAC). The AR of bullets increased with the number of branches in bullet rosettes. Most dimensions of crystals and ARs of columnar crystals measured during SPARTICUS were larger than those measured during TWP-ICE and ISDAC at −67 < T < -35 °C and at −40 < T < −15 °C, respectively. The relative occurrence of varying pristine habits depended strongly on cirrus type (i.e., anvil or non-anvil clouds), with plates especially occurring more frequently in anvils. Finally, the L– W relationships of columns derived using current data exhibited a strong dependence on temperature; similar relationships determined in previous studies were within the range of the current data.« less

The impact performance of headguards for combat sports.

PubMed

McIntosh, Andrew S; Patton, Declan A

2015-09-01

To assess the impact energy attenuation performance of a range of headguards for combat sports. Seven headguards worn during combat sport training or competition, including two Association Internationale de Boxe Amateur (AIBA)-approved boxing models, were tested using drop tests. An International Organization for Standardization (ISO) rigid headform was used with a 5.6 kg drop assembly mass. Tests were conducted against a flat rigid anvil both with and without a boxing glove section. The centre forehead and lateral headguard areas were tested. Peak headform acceleration was measured. Tests from a selection of drop heights and repeated tests on the same headguard were conducted. Headguard performance varied by test condition. For the 0.4 m rigid anvil tests, the best model headguard was the thickest producing an average peak headform acceleration over 5 tests of 48 g compared with 456 g for the worst model. The mean peak acceleration for the 0.4, 0.5 and 0.6 frontal and lateral rigid anvil impact tests was between 32% and 40% lower for the Top Ten boxing model compared with the Adidas boxing model. The headguard performance deterioration observed with repeat impact against the flat anvil was reduced for impacts against the glove section. The overall reduction in acceleration for the combination of glove and headguard in comparison to the headguard condition was in the range of 72-93% for 0.6 and 0.8 m drop tests. The impact tests show the benefits of performance testing in identifying differences between headguard models. Published by the BMJ Publishing Group Limited. For permission to use (where not already granted under a licence) please go to http://group.bmj.com/group/rights-licensing/permissions.

Aerosol-Induced Changes of Convective Cloud Anvils Produce Strong Climate Warming

NASA Technical Reports Server (NTRS)

Koren, I.; Remer, L. A.; Altaratz, O.; Martins, J. V.; Davidi, A.

2010-01-01

The effect of aerosol on clouds poses one of the largest uncertainties in estimating the anthropogenic contribution to climate change. Small human-induced perturbations to cloud characteristics via aerosol pathways can create a change in the top-of-atmosphere radiative forcing of hundreds of Wm(exp-2) . Here we focus on links between aerosol and deep convective clouds of the Atlantic and Pacific Intertropical Convergence Zones, noting that the aerosol environment in each region is entirely different. The tops of these vertically developed clouds consisting of mostly ice can reach high levels of the atmosphere, overshooting the lower stratosphere and reaching altitudes greater than 16 km. We show a link between aerosol, clouds and the free atmosphere wind profile that can change the magnitude and sign of the overall climate radiative forcing. We find that increased aerosol loading is associated with taller cloud towers and anvils. The taller clouds reach levels of enhanced wind speeds that act to spread and thin the anvi1 clouds, increasing areal coverage and decreasing cloud optical depth. The radiative effect of this transition is to create a positive radiative forcing (warming) at top-of-atmosphere. Furthermore we introduce the cloud optical depth (r), cloud height (Z) forcing space and show that underestimation of radiative forcing is likely to occur in cases of non homogenous clouds. Specifically, the mean radiative forcing of towers and anvils in the same scene can be several times greater than simply calculating the forcing from the mean cloud optical depth in the scene. Limitations of the method are discussed, alternative sources of aerosol loading are tested and meteorological variance is restricted, but the trend of taller clouds; increased and thinner anvils associated with increased aerosol loading remains robust through all the different tests and perturbations.

CRYSTAL-FACE Analysis and Simulations of the July 23rd Extended Anvil Case

NASA Technical Reports Server (NTRS)

Starr, David

2003-01-01

A key focus of CRYSTAL-FACE (Cirrus Regional Study of Tropical Anvils and cirrus Layers - Florida Area Cirrus Experiment) was the generation and subsequent evolution of cirrus outflow from deep convective cloud systems. Present theoretical background and motivations will be discussed. An integrated look at the observations of an extended cirrus anvil cloud system observed on 23 July 2002 will be presented, including lidar and millimeter radar observation; from NASA s ER-2 and in-situ observations from NASA s WB-57 and University of North Dakota Citation. The observations will be compared to results of simulations using 1-D and 2-D high-resolution (100 meter) cloud resolving models. The CRMs explicitly account for cirrus microphysical development by resolving the evolving ice crystal size distribution (bin model) in time and space. Both homogeneous and heterogeneous nucleation are allowed in the model. The CRM simulations are driven using the output of regional simulations using MM5 that produces deep convection similar to what was observed. The MM5 model employs a 2 km inner grid (32 layers) over a 360 km domain, nested within a 6-km grid over a 600-km domain. Initial and boundary conditions for the 36-hour MM5 simulation are taken from NCEP Eta model analysis at 32 km resolution. Key issues to be explored are the settling of the observed anvil versus the model simulations, and comparisons of dynamical properties, such as vertical motions, occurring in the observations and models. The former provides an integrated measure of the validity of the model microphysics (fallspeed) while the latter is the key factor in forcing continued ice generation.

Improvement of Representation of the Cloud-Aerosol Interaction in Large-Scale Models

DOE Office of Scientific and Technical Information (OSTI.GOV)

Khain, Alexander; Phillips, Vaughan; Pinsky, Mark

The main achievements reached under the DOE award DE-SC0006788 are described. It is shown that the plan of the Project is completed. Unique results concerning cloud-aerosol interaction are obtained. It is shown that aerosols affect intensity of hurricanes. The effects of small aerosols on formation of ice in anvils of deep convective clouds are discovered, for the first time the mechanisms of drizzle formation are found and described quantitatively. Mechanisms of formation of warm rain are clarified and the dominating role of adiabatic processes and turbulence are stressed. Important results concerning the effects of sea spray on intensity of cloudsmore » and tropical cyclones are obtained. A novel methods of calculation of hail formation has been developed and implemented.« less

Thunderstorms over the Pacific Ocean as seen from STS-64

NASA Technical Reports Server (NTRS)

1994-01-01

Multiple thunderstorm cells leading to Earth's atmosphere were photographed on 70mm by the astronauts of STS-64, orbiting aboard the Space Shuttle Discovery 130 nautical miles away. These thunderstorms are located about 16 degrees southeast of Hawaii in the Pacific Ocean. Every stage of a developing thunderstorm is documented in this photo: from the building cauliflower tops to the mature anvil phase. The anvil or the tops of the clouds being blown off are at about 50,000 feet. The light line in the blue atmosphere is either clouds in the distance or an atmospheric layer which is defined but different particle sizes.

Peculiar Features of Microstructure Formation and Microhardness Variations During Torsional Straining of Tantalum Specimens in Bridgman Anvils

NASA Astrophysics Data System (ADS)

Ditenberg, I. A.; Tymentsev, A. N.; Korznikov, A. V.

2015-04-01

Using the method of transmission electron microscopy, peculiar features of evolution of microstructure and variations in microhardness of Та are investigated under torsional loading in the Bridgman anvil as a function of plastic deformation at room temperature. A quantitative examination of grain and defect's structure of the material under study and the values of local internal stresses is performed in different loading stages. The mechanisms of formation of submicrocrystalline and nanostructured states are analyzed and so is the microstructure variation as a function of the defect-structure characteristics, strain level, and spacing from the axis of torsion.

Synthesis of Binary Transition Metal Nitrides, Carbides and Borides from the Elements in the Laser-Heated Diamond Anvil Cell and Their Structure-Property Relations

PubMed Central

Friedrich, Alexandra; Winkler, Björn; Juarez-Arellano, Erick A.; Bayarjargal, Lkhamsuren

2011-01-01

Transition metal nitrides, carbides and borides have a high potential for industrial applications as they not only have a high melting point but are generally harder and less compressible than the pure metals. Here we summarize recent advances in the synthesis of binary transition metal nitrides, carbides and borides focusing on the reaction of the elements at extreme conditions generated within the laser-heated diamond anvil cell. The current knowledge of their structures and high-pressure properties like high-(p,T) stability, compressibility and hardness is described as obtained from experiments. PMID:28824101

United States Army, Seventh Army Field Order No. 1 (ANVIL)

DTIC Science & Technology

1944-07-29

4471- FHANCE, 1/100,000, GSGS 4249. ’ FR..fu."JCE, road maps, 1/200,000, GSGS 4238. FR.~~CE, 1/250,000, GSGS 2738. Target Area Beach panoramas . All...8217These plants are link.... ed to the thermal plants in the nor-th by a high tension. grid system of 150 and 220 kv, . b. The hydro-electric piants in...Saint-Lary Soulcm Trame zaygues ~ Sms~M’·- BIGOT ANVIL BAY OF BI~ ~: Thermal II II .§PANISH BORDE1t Type: Hydro 11 11 11 II II 11 "" "II "II tI "" II

Electric Field Magnitude and Radar Reflectivity as a Function of Distance from Cloud Edge

NASA Technical Reports Server (NTRS)

Ward, Jennifer G.; Merceret, Francis J.

2004-01-01

The results of analyses of data collected during a field investigation of thunderstorm anvil and debris clouds are reported. Statistics of the magnitude of the electric field are determined as a function of distance from cloud edge. Statistics of radar reflectivity near cloud edge are also determined. Both analyses use in-situ airborne field mill and cloud physics data coupled with ground-based radar measurements obtained in east-central Florida during the summer convective season. Electric fields outside of anvil and debris clouds averaged less than 3 kV/m. The average radar reflectivity at the cloud edge ranged between 0 and 5 dBZ.

90-kilobar diamond-anvil high-pressure cell for use on an automatic diffractometer.

PubMed

Schiferl, D; Jamieson, J C; Lenko, J E

1978-03-01

A gasketed diamond-anvil high-pressure cell is described which can be used on a four-circle automatic diffractometer to collect x-ray intensity data from single-crystal samples subjected to truly hydrostatic pressures of over 90 kilobars. The force generating system exerts only forces normal to the diamond faces to obtain maximum reliability. A unique design allows exceptionally large open areas for maximum x-ray access and is particularly well suited for highly absorbing materials, as the x rays are not transmitted through the sample. Studies on ruby show that high-pressure crystal structure determinations may be done rapidly, reliably, and routinely with this system.

Liquid mercury sound velocity measurements under high pressure and high temperature by picosecond acoustics in a diamond anvils cell

NASA Astrophysics Data System (ADS)

Decremps, F.; Belliard, L.; Couzinet, B.; Vincent, S.; Munsch, P.; Le Marchand, G.; Perrin, B.

2009-07-01

Recent improvements to measure ultrasonic sound velocities of liquids under extreme conditions are described. Principle and feasibility of picosecond acoustics in liquids embedded in a diamond anvils cell are given. To illustrate the capability of these advances in the sound velocity measurement technique, original high pressure and high temperature results on the sound velocity of liquid mercury up to 5 GPa and 575 K are given. This high pressure technique will certainly be useful in several fundamental and applied problems in physics and many other fields such as geophysics, nonlinear acoustics, underwater sound, petrology or physical acoustics.

Revealing sub-μm and μm-scale textures in H2O ice at megabar pressures by time-domain Brillouin scattering

PubMed Central

Nikitin, Sergey M.; Chigarev, Nikolay; Tournat, Vincent; Bulou, Alain; Gasteau, Damien; Castagnede, Bernard; Zerr, Andreas; Gusev, Vitalyi E.

2015-01-01

The time-domain Brillouin scattering technique, also known as picosecond ultrasonic interferometry, allows monitoring of the propagation of coherent acoustic pulses, having lengths ranging from nanometres to fractions of a micrometre, in samples with dimension of less than a micrometre to tens of micrometres. In this study, we applied this technique to depth-profiling of a polycrystalline aggregate of ice compressed in a diamond anvil cell to megabar pressures. The method allowed examination of the characteristic dimensions of ice texturing in the direction normal to the diamond anvil surfaces with sub-micrometre spatial resolution via time-resolved measurements of the propagation velocity of the acoustic pulses travelling in the compressed sample. The achieved imaging of ice in depth and in one of the lateral directions indicates the feasibility of three-dimensional imaging and quantitative characterisation of the acoustical, optical and acousto-optical properties of transparent polycrystalline aggregates in a diamond anvil cell with tens of nanometres in-depth resolution and a lateral spatial resolution controlled by pump laser pulses focusing, which could approach hundreds of nanometres. PMID:25790808

Hydrothermal Diamond Anvil Cell (HDAC): From Visual Observation to X-ray Absorption Spectroscopy

NASA Astrophysics Data System (ADS)

Bassett, W. A.; Mibe, K.

2006-05-01

A fluid sample contained in a Re gasket between two diamond anvils can be subjected to pressures up to 2.5 GPa and temperatures up to 1200°C in a resistively heated hydrothermal diamond anvil cell (HDAC). Thermocouples are used to measure temperature. The constant-volume sample chamber permits isochoric measurements that can be used to determine pressure from the equation of state of H2O and to map phases and properties in P-T space. A movie of reactions between K-feldspar and water up to 2.5 GPa and 880°C illustrates the use of visual observations for mapping coexisting solution, melt, and solid phases. X-ray absorption spectroscopy of ZnBr2 in solution up to 500°C and 500 MPa shows hydrogen bond breaking in the hydration shells of the ZnBr42- and Br- ions with increasing temperature. In other studies the stability field of ikaite (CaCO3·6H2O) has been mapped by visual observation and Raman spectroscopy; the phases of montmorillonite have been mapped by X-ray diffraction; and the leaching of Pb from zircon has been measured by X-ray microprobe.

An Overview of the Lightning - Atmospheric Chemistry Aspects of the Deep Convective Clouds and Chemistry (DC3) Experiment

NASA Technical Reports Server (NTRS)

Pickering, K. E.; Barth, M. C.; Koshak, W.; Bucsela, E. J.; Allen, D. J.; Weinheimer, A.; Ryerson, T.; Huntrieser, H.; Bruning, E.; MacGorman, D.;

Feasibility and safety of modified inverted T-shaped method using linear stapler with movable cartridge fork for esophagojejunostomy following laparoscopic total gastrectomy.

PubMed

Ohuchida, Kenoki; Nagai, Eishi; Moriyama, Taiki; Shindo, Koji; Manabe, Tatsuya; Ohtsuka, Takao; Shimizu, Shuji; Nakamura, Masafumi

2017-01-01

We previously reported the use of an inverted T-shaped method to obtain a suitable view for hand sewing to close the common entry hole when the linear stapler was fired for esophagojejunostomy after laparoscopic total gastrectomy (LTG). This conventional method involved insertion of the fixed cartridge fork to the Roux limb and the fine movable anvil fork to the esophagus to avoid perforation of the jejunum. However, insertion of the movable anvil fork to the esophagus during this procedure often requires us to strongly push down the main body of the stapler with the fixed cartridge fork to bring the direction of the anvil fork in line with the direction of the long axis of the esophagus while controlling the opening of the movable anvil fork. We therefore modified this complicated inverted T-shaped method using a linear stapler with a movable cartridge fork. This modified method involved insertion of the movable cartridge fork into the Roux limb followed by natural, easy insertion of the fixed anvil fork into the esophagus without controlling the opening of the movable cartridge fork. We performed LTG in a total of 155 consecutive patients with gastric cancer from November 2007 to December 2015 in Kyushu University Hospital. After LTG, we performed the conventional inverted T-shaped method using a linear stapler with a fixed cartridge fork in 61 patients from November 2007 to July 2011 (fixed cartridge group). From August 2011, we used a linear stapler with a movable cartridge fork and performed the modified inverted T-shaped method in 94 patients (movable cartridge group). We herein compare the short-term outcomes in 94 cases of LTG using the modified method (movable cartridge fork) with those in 61 cases using the conventional method (fixed cartridge fork). We found no significant differences in the perioperative or postoperative events between the movable and fixed cartridge groups. One case of anastomotic leakage occurred in the fixed cartridge group, but no anastomotic leakage occurred in the movable cartridge group. Although there were no remarkable differences in the short-term outcomes between the movable and fixed cartridge groups, we believe that the modified inverted T-shaped method is technically more feasible and reliable than the conventional method and will contribute to the improved safety of LTG.

Feasibility and safety of modified inverted T-shaped method using linear stapler with movable cartridge fork for esophagojejunostomy following laparoscopic total gastrectomy

PubMed Central

Ohuchida, Kenoki; Moriyama, Taiki; Shindo, Koji; Manabe, Tatsuya; Ohtsuka, Takao; Shimizu, Shuji; Nakamura, Masafumi

2017-01-01

Background We previously reported the use of an inverted T-shaped method to obtain a suitable view for hand sewing to close the common entry hole when the linear stapler was fired for esophagojejunostomy after laparoscopic total gastrectomy (LTG). This conventional method involved insertion of the fixed cartridge fork to the Roux limb and the fine movable anvil fork to the esophagus to avoid perforation of the jejunum. However, insertion of the movable anvil fork to the esophagus during this procedure often requires us to strongly push down the main body of the stapler with the fixed cartridge fork to bring the direction of the anvil fork in line with the direction of the long axis of the esophagus while controlling the opening of the movable anvil fork. We therefore modified this complicated inverted T-shaped method using a linear stapler with a movable cartridge fork. This modified method involved insertion of the movable cartridge fork into the Roux limb followed by natural, easy insertion of the fixed anvil fork into the esophagus without controlling the opening of the movable cartridge fork. Methods We performed LTG in a total of 155 consecutive patients with gastric cancer from November 2007 to December 2015 in Kyushu University Hospital. After LTG, we performed the conventional inverted T-shaped method using a linear stapler with a fixed cartridge fork in 61 patients from November 2007 to July 2011 (fixed cartridge group). From August 2011, we used a linear stapler with a movable cartridge fork and performed the modified inverted T-shaped method in 94 patients (movable cartridge group). We herein compare the short-term outcomes in 94 cases of LTG using the modified method (movable cartridge fork) with those in 61 cases using the conventional method (fixed cartridge fork). Results We found no significant differences in the perioperative or postoperative events between the movable and fixed cartridge groups. One case of anastomotic leakage occurred in the fixed cartridge group, but no anastomotic leakage occurred in the movable cartridge group. Conclusions Although there were no remarkable differences in the short-term outcomes between the movable and fixed cartridge groups, we believe that the modified inverted T-shaped method is technically more feasible and reliable than the conventional method and will contribute to the improved safety of LTG. PMID:28616606

Reconstruction of the esophagojejunostomy by double stapling method using EEA™ OrVil™ in laparoscopic total gastrectomy and proximal gastrectomy

PubMed Central

2011-01-01

Here we report the method of anastomosis based on double stapling technique (hereinafter, DST) using a trans-oral anvil delivery system (EEATM OrVilTM) for reconstructing the esophagus and lifted jejunum following laparoscopic total gastrectomy or proximal gastric resection. As a basic technique, laparoscopic total gastrectomy employed Roux-en-Y reconstruction, laparoscopic proximal gastrectomy employed double tract reconstruction, and end-to-side anastomosis was used for the cut-off stump of the esophagus and lifted jejunum. We used EEATM OrVilTM as a device that permitted mechanical purse-string suture similarly to conventional EEA, and endo-Surgitie. After the gastric lymph node dissection, the esophagus was cut off using an automated stapler. EEATM OrVilTM was orally and slowly inserted from the valve tip, and a small hole was created at the tip of the obliquely cut-off stump with scissors to let the valve tip pass through. Yarn was cut to disconnect the anvil from a tube and the anvil head was retained in the esophagus. The end-Surgitie was inserted at the right subcostal margin, and after the looped-shaped thread was wrapped around the esophageal stump opening, assisting Maryland forceps inserted at the left subcostal and left abdomen were used to grasp the left and right esophageal stump. The surgeon inserted anvil grasping forceps into the right abdomen, and after grasping the esophagus with the forceps, tightened the end Surgitie, thereby completing the purse-string suture on the esophageal stump. The main unit of the automated stapler was inserted from the cut-off stump of the lifted jejunum, and a trocar was made to pass through. To prevent dropout of the small intestines from the automated stapler, the automated stapler and the lifted jejunum were fastened with silk thread, the abdomen was again inflated, and the lifted jejunum was led into the abdominal cavity. When it was confirmed that the automated stapler and center rod were made completely linear, the anvil and the main unit were connected with each other and firing was carried out. Then, DST-based anastomosis was completed with no dog-ear. The method may facilitate safe laparoscopic anastomosis between the esophagus and reconstructed intestine. This is also considered to serve as a useful anastomosis technique for upper levels of the esophagus in laparotomy. PMID:21599911

Orion Parachute Riser Cutter Development

NASA Technical Reports Server (NTRS)

Oguz, Sirri; Salazar, Frank

2011-01-01

This paper presents the tests and analytical approach used on the development of a steel riser cutter for the CEV Parachute Assembly System (CPAS) used on the Orion crew module. Figure 1 shows the riser cutter and the steel riser bundle which consists of six individual cables. Due to the highly compressed schedule, initial unavailability of the riser material and the Orion Forward Bay mechanical constraints, JSC primarily relied on a combination of internal ballistics analysis and LS-DYNA simulation for this project. Various one dimensional internal ballistics codes that use standard equation of state and conservation of energy have commonly used in the development of CAD devices for initial first order estimates and as an enhancement to the test program. While these codes are very accurate for propellant performance prediction, they usually lack a fully defined kinematic model for dynamic predictions. A simple piston device can easily and accurately be modeled using an equation of motion. However, the accuracy of analytical models is greatly reduced on more complicated devices with complex external loads, nonlinear trajectories or unique unlocking features. A 3D finite element model of CAD device with all critical features included can vastly improve the analytical ballistic predictions when it is used as a supplement to the ballistic code. During this project, LS-DYNA structural 3D model was used to predict the riser resisting load that was needed for the ballistic code. A Lagrangian model with eroding elements shown in Figure 2 was used for the blade, steel riser and the anvil. The riser material failure strain was fine tuned by matching the dent depth on the anvil with the actual test data. LS-DYNA model was also utilized to optimize the blade tip design for the most efficient cut. In parallel, the propellant type and the amount were determined by using CADPROG internal ballistics code. Initial test results showed a good match with LS-DYNA and CADPROG simulations. Final paper will present a detailed roadmap from initial ballistic modeling and LS-DYNA simulation to the performance testing. Blade shape optimization study will also be presented.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smith, Jesse S.; Sinogeikin, Stanislav V.; Lin, Chuanlong

Complementary advances in high pressure research apparatus and techniques make it possible to carry out time-resolved high pressure research using what would customarily be considered static high pressure apparatus. This work specifically explores time-resolved high pressure x-ray diffraction with rapid compression and/or decompression of a sample in a diamond anvil cell. Key aspects of the synchrotron beamline and ancillary equipment are presented, including source considerations, rapid (de)compression apparatus, high frequency imaging detectors, and software suitable for processing large volumes of data. A number of examples are presented, including fast equation of state measurements, compression rate dependent synthesis of metastable statesmore » in silicon and germanium, and ultrahigh compression rates using a piezoelectric driven diamond anvil cell.« less

Remote measurements of the structure of midwest thunderstorm tops and anvils from high altitude aircraft

NASA Technical Reports Server (NTRS)

Heymsfield, Gerald M.; Fulton, Richard

1990-01-01

Results are presented from observations by a visible and IR scanning radiometer, a scanning passive microwave radiometer, and a nadir-viewing cloud lidar system (CLS), carried out from ER-2 overflights for two midwest severe weather events both of which presented following phenomena: (1) a group of severe thunderstorms which later transformed into a linear mesoscale convective system, and (2) a severe thunderstorm which produced large hail. Most of the aircraft in situ and remote measurements pointed to a deep subsidence region and gravity waves downstream of the overshooting cloud tops. The observations do not support a radiative explanation for the warm areas in the anvil.

High pressure cosmochemistry applied to major planetary interiors: Experimental studies

NASA Technical Reports Server (NTRS)

Nicol, M. F.; Johnson, M.; Koumvakalis, A. S.

1984-01-01

Progress is reported on a project to determine the properties and boundaries of high pressure phases of the H2-He-H2O-NH3-CH4 system that are needed to constrain theoretical models of the interiors of the major planets. This project is one of the first attempts to measure phase equilibria in binary fluid-solid systems in diamond anvil cells. Vibrational spectroscopy, direct visual observations, and X-ray diffraction crystallography of materials confined in externally heated cells are the primary experimental probes. Adiabats of these materials are also measured in order to constrain models of heat flow in these bodies and to detect phase transitions by thermal anomalies. Initial efforts involve the NH3-H2O binary. This system is especially relevant to models for surface reconstruction of the icy satellites of Jupiter and Saturn. Thermal analysis experiments were completed for the P-X space, p4GPa:0 or = 0.50, near room temperature. The cryostat, sample handling equipment, and optics needed to extend the optical P-T-X work below room temperature was completed.

Sound velocity measurements of CaSiO3 perovskite under lower mantle pressures

NASA Astrophysics Data System (ADS)

Kudo, Y.; Hirose, K.

2010-12-01

The chemical composition of the lower mantle and the distribution of subducted crustal materials in the lower mantle can be constrained by the comparison of seismological observations with laboratory measurements of sound velocities of expected constituent minerals in lower mantle conditions. To date, sound velocities of two major constituent minerals of the lower mantle, namely magnesium silicate perovskite and ferropericlase have been well studied although the data are mostly limited to low temperature (300 K). On the other hand, another major mineral, CaSiO3-perovskite appears in both peridtite (~7 wt.%) and subducted basaltic crusts (~23 wt.%) at the lower mantle pressure-temperature conditions. In spite of its abundance in those rocks, little is known about acoustic velocity, mostly because it cannot be quenched to the ambient pressure. Synthesis and measurement should be made under pressure, which has been a challenging project for the current experimental techniques. We have conducted sound velocity measurements of polycrystalline CaSiO3 perovskite by a combination of a diamond anvil cell (DAC) and Brillouin scattering spectroscopy. High-pressure was generated by the DAC with a pair of 300-micron culet diamond anvils. Calcium silicate perovskite was synthesized from gel by laser annealing in the DAC with the CO2 laser. A tetragonal perovskite structure was confirmed by the X-ray diffraction at the station BL10XU, SPring-8. Brillouin scattering measurements were made at 300 K under pressures corresponding to the middle lower mantle conditions. Results demonstrate that the S-wave velocity is significantly lower than previous theoretical results. We will discuss the possible source for this discrepancy and resulting implications for the lower mantle materials.

High quality x-ray absorption spectroscopy measurements with long energy range at high pressure using diamond anvil cell.

PubMed

Hong, Xinguo; Newville, Matthew; Prakapenka, Vitali B; Rivers, Mark L; Sutton, Stephen R

2009-07-01

We describe an approach for acquiring high quality x-ray absorption fine structure (XAFS) spectroscopy spectra with wide energy range at high pressure using diamond anvil cell (DAC). Overcoming the serious interference of diamond Bragg peaks is essential for combining XAFS and DAC techniques in high pressure research, yet an effective method to obtain accurate XAFS spectrum free from DAC induced glitches has been lacking. It was found that these glitches, whose energy positions are very sensitive to the relative orientation between DAC and incident x-ray beam, can be effectively eliminated using an iterative algorithm based on repeated measurements over a small angular range of DAC orientation, e.g., within +/-3 degrees relative to the x-ray beam direction. Demonstration XAFS spectra are reported for rutile-type GeO2 recorded by traditional ambient pressure and high pressure DAC methods, showing similar quality at 440 eV above the absorption edge. Accurate XAFS spectra of GeO2 glass were obtained at high pressure up to 53 GPa, providing important insight into the structural polymorphism of GeO2 glass at high pressure. This method is expected be applicable for in situ XAFS measurements using a diamond anvil cell up to ultrahigh pressures.

High quality x-ray absorption spectroscopy measurements with long energy range at high pressure using diamond anvil cell

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hong, X.; Newville, M.; Prakapenka, V.B.

We describe an approach for acquiring high quality x-ray absorption fine structure (XAFS) spectroscopy spectra with wide energy range at high pressure using diamond anvil cell (DAC). Overcoming the serious interference of diamond Bragg peaks is essential for combining XAFS and DAC techniques in high pressure research, yet an effective method to obtain accurate XAFS spectrum free from DAC induced glitches has been lacking. It was found that these glitches, whose energy positions are very sensitive to the relative orientation between DAC and incident x-ray beam, can be effectively eliminated using an iterative algorithm based on repeated measurements over amore » small angular range of DAC orientation, e.g., within {+-}3{sup o} relative to the x-ray beam direction. Demonstration XAFS spectra are reported for rutile-type GeO{sub 2} recorded by traditional ambient pressure and high pressure DAC methods, showing similar quality at 440 eV above the absorption edge. Accurate XAFS spectra of GeO{sub 2} glass were obtained at high pressure up to 53 GPa, providing important insight into the structural polymorphism of GeO{sub 2} glass at high pressure. This method is expected be applicable for in situ XAFS measurements using a diamond anvil cell up to ultrahigh pressures.« less

Instrumented Taylor anvil-on-rod impact tests for validating applicability of standard strength models to transient deformation states

NASA Astrophysics Data System (ADS)

Eakins, D. E.; Thadhani, N. N.

2006-10-01

Instrumented Taylor anvil-on-rod impact tests have been conducted on oxygen-free electronic copper to validate the accuracy of current strength models for predicting transient states during dynamic deformation events. The experiments coupled the use of high-speed digital photography to record the transient deformation states and laser interferometry to monitor the sample back (free surface) velocity as a measure of the elastic/plastic wave propagation through the sample length. Numerical continuum dynamics simulations of the impact and plastic wave propagation employing the Johnson-Cook [Proceedings of the Seventh International Symposium on Ballistics, 1983, The Netherlands (Am. Def. Prep. Assoc. (ADPA)), pp. 541-547], Zerilli-Armstrong [J. Appl. Phys. C1, 1816 (1987)], and Steinberg-Guinan [J. Appl. Phys. 51, 1498 (1980)] constitutive equations were used to generate transient deformation profiles and the free surface velocity traces. While these simulations showed good correlation with the measured free surface velocity traces and the final deformed sample shape, varying degrees of deviations were observed between the photographed and calculated specimen profiles at intermediate deformation states. The results illustrate the usefulness of the instrumented Taylor anvil-on-rod impact technique for validating constitutive equations that can describe the path-dependent deformation response and can therefore predict the transient and final deformation states.

Amorphous boron gasket in diamond anvil cell research

NASA Astrophysics Data System (ADS)

Lin, Jung-Fu; Shu, Jinfu; Mao, Ho-kwang; Hemley, Russell J.; Shen, Guoyin

2003-11-01

Recent advances in high-pressure diamond anvil cell experiments include high-energy synchrotron x-ray techniques as well as new cell designs and gasketing procedures. The success of high-pressure experiments usually depends on a well-prepared sample, in which the gasket plays an important role. Various gasket materials such as diamond, beryllium, rhenium, and stainless steel have been used. Here we introduce amorphous boron as another gasket material in high-pressure diamond anvil cell experiments. We have applied the boron gasket for laser-heating x-ray diffraction, radial x-ray diffraction, nuclear resonant inelastic x-ray scattering, and inelastic x-ray scattering. The high shear strength of the amorphous boron maximizes the thickness of the sample chamber and increases the pressure homogeneity, improving the quality of high-pressure data. Use of amorphous boron avoids unwanted x-ray diffraction peaks and reduces the absorption of incident and x rays exiting the gasket material. The high quality of the diffraction patterns makes it possible to refine the cell parameters with powder x-ray diffraction data under high pressure and high temperature. The reactivity of boron prevents its use at high temperatures, however. When heated, boron may also react with the specimen to produce unwanted phases. The relatively porous boron starting material at ambient conditions also poses some challenges for sample preparation.

Comparison of single-stapling and hemi-double-stapling methods for intracorporeal esophagojejunostomy using a circular stapler after totally laparoscopic total gastrectomy.

PubMed

Amisaki, Masataka; Kihara, Kyoichi; Endo, Kanenori; Suzuki, Kazunori; Nakamura, Seiichi; Sawata, Takashi; Shimizu, Tetsu

2016-07-01

Laparoscopic total gastrectomy is not widely performed because of the difficulty of esophagojejunal reconstruction. This study analyzed complication rates of two different methods for reconstruction by a circular stapler after totally laparoscopic total gastrectomy (TLTG). Between 2010 and 2014, clinical data of 19 patients who underwent TLTG for gastric adenocarcinoma were collected retrospectively. There were two methods to fix the anvil of a circular stapler into the distal esophagus: In the single-stapling technique (SST) group, Endo-PSI(II) was used for purse-suturing on the distal esophagus for reconstruction, and in the hemi-double-stapling technique (hemi-DST) group, the esophagus was cut by linear stapler with the entry hole of the anvil shaft opened after inserting the anvil tail. In both groups, surgical procedures were the same, except for the reconstruction. All TLTGs were performed securely without mortality. Intracorporeal laparoscopic esophagojejunal anastomosis was performed successfully for all the patients. In the hemi-DST group, four patients experienced anastomotic stenosis, three of whom required endoscopic balloon dilation. In contrast, no stenosis was seen in the SST group (p = 0.033). Anastomosis with SST is preferred to that with hemi-DST to minimize postoperative complications.

Focusing polycapillary to reduce parasitic scattering for inelastic x-ray measurements at high pressure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chow, P., E-mail: pchow@carnegiescience.edu; Xiao, Y. M.; Rod, E.

2015-07-15

The double-differential scattering cross-section for the inelastic scattering of x-ray photons from electrons is typically orders of magnitude smaller than that of elastic scattering. With samples 10-100 μm size in a diamond anvil cell at high pressure, the inelastic x-ray scattering signals from samples are obscured by scattering from the cell gasket and diamonds. One major experimental challenge is to measure a clean inelastic signal from the sample in a diamond anvil cell. Among the many strategies for doing this, we have used a focusing polycapillary as a post-sample optic, which allows essentially only scattered photons within its input fieldmore » of view to be refocused and transmitted to the backscattering energy analyzer of the spectrometer. We describe the modified inelastic x-ray spectrometer and its alignment. With a focused incident beam which matches the sample size and the field of view of polycapillary, at relatively large scattering angles, the polycapillary effectively reduces parasitic scattering from the diamond anvil cell gasket and diamonds. Raw data collected from the helium exciton measured by x-ray inelastic scattering at high pressure using the polycapillary method are compared with those using conventional post-sample slit collimation.« less

Containment of fluid samples in the hydrothermal diamond-anvil cell without the use of metal gaskets: Performance and advantages for in situ analysis

NASA Astrophysics Data System (ADS)

Chou, I.-Ming; Bassett, William A.; Anderson, Alan J.; Mayanovic, Robert A.; Shang, Linbo

2008-11-01

Metal gaskets (Re, Ir, Inconel, or stainless steel) normally used to contain fluid samples in the hydrothermal diamond-anvil cell (HDAC) are sometimes undesirable due to possible contamination and to gasket deformation at high pressures and temperatures resulting in nonisochoric behavior. Furthermore, in x-ray spectroscopic experiments, metal gaskets may attenuate the incident x-ray beam and emitted fluorescence x-rays, and the interaction of scattered radiation with the gasket may produce fluorescence that interferes with the x-ray spectrum of the sample. New arrangements and procedures were tested for the operation of the HDAC without using the metal gaskets. Distilled, de-ionized water was loaded into the sample chamber, a laser-milled recess 300 μm in diameter and ˜50 μm deep centered in the 1.0 mm face of the lower diamond anvil, and sealed by pressing the top diamond anvil face directly against the lower one without a metal gasket in between. A maximum sample pressure of 202 MPa at 617 °C was maintained for a duration of 10 min without evidence of leakage. A small change in fluid density was observed in one experiment where the sample was held at 266 MPa at 708 °C for 10 min. The gasketless HDAC was also employed in x-ray absorption spectroscopy experiments, where, in addition to the sample chamber in the lower diamond, two grooves were milled at a 90° angle to each other around the sample chamber to minimize the attenuation of incident and fluorescent x rays. With a minimum distance between the sample chamber and the grooves of 80 μm, a pressure of 76 MPa at 500 °C was maintained for 2 h with no change in the original fluid density.

Containment of fluid samples in the hydrothermal diamond-anvil cell without the use of metal gaskets: Performance and advantages for in situ analysis

USGS Publications Warehouse

Chou, I.-Ming; Bassett, William A.; Anderson, Alan J.; Mayanovic, Robert A.; Shang, L.

2008-01-01

Metal gaskets (Re, Ir, Inconel, or stainless steel) normally used to contain fluid samples in the hydrothermal diamond-anvil cell (HDAC) are sometimes undesirable due to possible contamination and to gasket deformation at high pressures and temperatures resulting in nonisochoric behavior. Furthermore, in x-ray spectroscopic experiments, metal gaskets may attenuate the incident x-ray beam and emitted fluorescence x-rays, and the interaction of scattered radiation with the gasket may produce fluorescence that interferes with the x-ray spectrum of the sample. New arrangements and procedures were tested for the operation of the HDAC without using the metal gaskets. Distilled, de-ionized water was loaded into the sample chamber, a laser-milled recess 300 ??m in diameter and ???50 ??m deep centered in the 1.0 mm face of the lower diamond anvil, and sealed by pressing the top diamond anvil face directly against the lower one without a metal gasket in between. A maximum sample pressure of 202 MPa at 617 ??C was maintained for a duration of 10 min without evidence of leakage. A small change in fluid density was observed in one experiment where the sample was held at 266 MPa at 708 ??C for 10 min. The gasketless HDAC was also employed in x-ray absorption spectroscopy experiments, where, in addition to the sample chamber in the lower diamond, two grooves were milled at a 90?? angle to each other around the sample chamber to minimize the attenuation of incident and fluorescent x rays. With a minimum distance between the sample chamber and the grooves of 80 ??m, a pressure of 76 MPa at 500 ??C was maintained for 2 h with no change in the original fluid density. ?? 2008 American Institute of Physics.

Containment of fluid samples in the hydrothermal diamond-anvil cell without the use of metal gaskets: performance and advantages for in situ analysis.

PubMed

Chou, I-Ming; Bassett, William A; Anderson, Alan J; Mayanovic, Robert A; Shang, Linbo

2008-11-01

Metal gaskets (Re, Ir, Inconel, or stainless steel) normally used to contain fluid samples in the hydrothermal diamond-anvil cell (HDAC) are sometimes undesirable due to possible contamination and to gasket deformation at high pressures and temperatures resulting in nonisochoric behavior. Furthermore, in x-ray spectroscopic experiments, metal gaskets may attenuate the incident x-ray beam and emitted fluorescence x-rays, and the interaction of scattered radiation with the gasket may produce fluorescence that interferes with the x-ray spectrum of the sample. New arrangements and procedures were tested for the operation of the HDAC without using the metal gaskets. Distilled, de-ionized water was loaded into the sample chamber, a laser-milled recess 300 microm in diameter and approximately 50 microm deep centered in the 1.0 mm face of the lower diamond anvil, and sealed by pressing the top diamond anvil face directly against the lower one without a metal gasket in between. A maximum sample pressure of 202 MPa at 617 degrees C was maintained for a duration of 10 min without evidence of leakage. A small change in fluid density was observed in one experiment where the sample was held at 266 MPa at 708 degrees C for 10 min. The gasketless HDAC was also employed in x-ray absorption spectroscopy experiments, where, in addition to the sample chamber in the lower diamond, two grooves were milled at a 90 degrees angle to each other around the sample chamber to minimize the attenuation of incident and fluorescent x rays. With a minimum distance between the sample chamber and the grooves of 80 microm, a pressure of 76 MPa at 500 degrees C was maintained for 2 h with no change in the original fluid density.

Extreme mechanical properties of materials under extreme pressure and temperature conditions (Invited)

NASA Astrophysics Data System (ADS)

Kavner, A.; Armentrout, M. M.; Xie, M.; Weinberger, M.; Kaner, R. B.; Tolbert, S. H.

2010-12-01

A strong synergy ties together the high-pressure subfields of mineral physics, solid-state physics, and materials engineering. The catalog of studies measuring the mechanical properties of materials subjected to large differential stresses in the diamond anvil cell demonstrates a significant pressure-enhancement of strength across many classes of materials, including elemental solids, salts, oxides, silicates, and borides and nitrides. High pressure techniques—both radial diffraction and laser heating in the diamond anvil cell—can be used to characterize the behavior of ultrahard materials under extreme conditions, and help test hypotheses about how composition, structure, and bonding work together to govern the mechanical properties of materials. The principles that are elucidated by these studies can then be used to help design engineering materials to encourage desired properties. Understanding Earth and planetary interiors requires measuring equations of state of relevant materials, including oxides, silicates, and metals under extreme conditions. If these minerals in the diamond anvil cell have any ability to support a differential stress, the assumption of quasi-hydrostaticity no longer applies, with a resulting non-salubrious effect on attempts to measure equation of state. We illustrate these applications with the results of variety of studies from our laboratory and others’ that have used high-pressure radial diffraction techniques and also laser heating in the diamond anvil cell to characterize the mechanical properties of a variety of ultrahard materials, especially osmium metal, osmium diboride, rhenium diboride, and tungsten tetraboride. We compare ambient condition strength studies such as hardness testing with high-pressure studies, especially radial diffraction under differential stress. In addition, we outline criteria for evaluating mechanical properties of materials at combination high pressures and temperatures. Finally, we synthesize our understanding of mechanical properties and composite behavior to suggest new approaches to designing high-pressure experiments to target specific measurements of a wide variety of mechanical properties.

The Anvils as Pressure Calibrants in the Hydrothermal Diamond Anvil Cell

NASA Astrophysics Data System (ADS)

Davis, M. K.; Panero, W. R.; Stixrude, L. P.

2003-12-01

Throughout the crust and the upper part of the mantle, water is an important agent of heat and mass transport in processes ranging from metasomatism to magma generation in arc environments. One of the important properties of water in this regime: its ability to dissolve significant amounts of solids, presents a substantial challenge to the experimental study of water-rich systems. Many commonly used pressure standards, such as quartz and ruby, dissolve in water under the conditions accessible to the hydrothermal diamond anvil cell (up to 1200 K and 5 GPa). For this reason, it is important to develop alternative pressure calibrants. Two methods have been developed by other groups for pressure calibration in the HDAC in the presence of water. One method relies on the equation of state of the ambient fluid and the observation that the sample chamber remains approximately isochoric on heating. Disadvantages of this method include our imperfect knowledge of the equation of state of water over the relevant pressure-temperature interval, possible changes in fluid composition, and sample chamber assembly relaxation at temperatures above 800 K. The second method is based on the Raman signal from diamond chips loaded with the sample. Synthetic 13C diamond is used to avoid overlap with the much stronger signal from the anvils. Diamond is an ideal pressure sensor since it is chemically inert and unaffected by water. Therefore, we use the tips of the diamond anvils as "internal" sensors. The primary disadvantage of this method is that the stress distribution inside the anvils is non-hydrostatic and inhomogeneous, although the normal stress across the diamond-sample interface must be continuous. Using confocal micro-Raman spectroscopy we are able to characterize both the inhomogeneity and the non-hydrostaticity of the diamond stress field by combining axial and radial transects with peak shapes. We find that on room temperature loading there is substantial inhomogeneity in the diamond stress field: variations of up to 2.3 cm-1 or about 0.8 GPa over a pressure range of 0 to 3.5 GPa. However, heating substantially reduces inhomogeneity in the vicinity of the diamond-sample interface allowing the derivation of a useful pressure calibration. Preliminary results show that the primary Raman line of diamond shifts with respect to temperature according to the equation 1332.15 - 0.0016x - 3.5e-5x2 + 7.1e-11x3 where x is temperature. The same Raman line of diamond shifts with pressure according to the equation 1332.15 + 3.4*P where the pressure, P, is in GPa. We find that the effects of temperature and pressure are independent of one another so that an independent measurement of temperature (with thermocouples) together with the measured Raman shift determines the pressure with an accuracy of 0.27 GPa at 800K and 2 GPa. We compare our calibration to the quartz and ruby calibration scales over the range where they are stable. We also compare our calibration to previous experiments using independent pressure calibrants.

Characteristics of anvil-top associated with the Poplar Bluff tornado of 7 May 1973

NASA Technical Reports Server (NTRS)

Pearl, E. W.

1973-01-01

Investigation of potential tornado-producing thunderstorms was performed during part of the 1972 and 1973 tornado seasons. On May 7, 1973 twenty-one tornadoes were confirmed over southern Missouri, northern Arkansas, and southwestern Illinois. The region was surveyed by high altitude photography performed on a Learjet over the region of reported tornadoes. Two storms were chosen from aircraft observation with the guidance of ground and radar reports, and a series of photographs were taken of a tornado producing cloud. An analysis of the activity before and during the tornado is made, and most noteworthy were changes detected in the growth and collapse of overshooting domes above the anvil. Suggestions are included for a comprehensive study.

Thunderstorms over the Pacific Ocean as seen from STS-64

NASA Image and Video Library

1994-09-18

STS064-83-099 (9-20 Sept. 1994) --- Multiple thunderstorm cells leading to Earth's atmosphere were photographed on 70mm by the astronauts, orbiting aboard the space shuttle Discovery 130 nautical miles away. These thunderstorms are located about 16 degrees southeast of Hawaii in the Pacific Ocean. Every stage of a developing thunderstorm is documented in this photo; from the building cauliflower tops to the mature anvil phase. The anvil or the tops of the clouds being blown off are at about 50,000 feet. The light line in the blue atmosphere is either clouds in the distance or an atmospheric layer which is defined but different particle sizes. Photo credit: NASA or National Aeronautics and Space Administration

Material transport in laser-heated diamond anvil cell melting experiments

NASA Technical Reports Server (NTRS)

Campbell, Andrew J.; Heinz, Dion L.; Davis, Andrew M.

1992-01-01

A previously undocumented effect in the laser-heated diamond anvil cell, namely, the transport of molten species through the sample chamber, over distances large compared to the laser beam diameter, is presented. This effect is exploited to determine the melting behavior of high-pressure silicate assemblages of olivine composition. At pressures where beta-spinel is the phase melted, relative strengths of partitioning can be estimated for the incompatible elements studied. Iron was found to partition into the melt from beta-spinel less strongly than calcium, and slightly more strongly than manganese. At higher pressures, where a silicate perovskite/magnesiowuestite assemblage is melted, it is determined that silicate perovskite is the liquidus phase, with iron-rich magnesiowuestite accumulating at the end of the laser-melted stripe.

BX90: A new diamond anvil cell design for X-ray diffraction and optical measurements

NASA Astrophysics Data System (ADS)

Kantor, I.; Prakapenka, V.; Kantor, A.; Dera, P.; Kurnosov, A.; Sinogeikin, S.; Dubrovinskaia, N.; Dubrovinsky, L.

2012-12-01

We present a new design of a universal diamond anvil cell, suitable for different kinds of experimental studies under high pressures. Main features of the cell are an ultimate 90-degrees symmetrical axial opening and high stability, making the presented cell design suitable for a whole range of techniques from optical absorption to single-crystal X-ray diffraction studies, also in combination with external resistive or double-side laser heating. Three examples of the cell applications are provided: a Brillouin scattering of neon, single-crystal X-ray diffraction of α-Cr2O3, and resistivity measurements on the (Mg0.60Fe0.40)(Si0.63Al0.37)O3 silicate perovskite.

High Pressure Superconductivity in Iron Based Layered Compounds Studied using Designer Diamonds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vohra, Yogesh, K.

High pressure superconductivity in Iron based superconductor FeSe0.5Te0.5 has been studied up to 15 GPa and 10 K using an eight probe designer diamond anvil in a diamond anvil cell device. Four probe electrical resistance measurements show onset of superconductivity (Tc) at 14 K at ambient pressure with Tc increasing with increasing pressure to 19 K at a pressure of 3.6 GPa. At higher pressures beyond 3.6 GPa, Tc decreases and extrapolation suggests non superconducting behavior above 10 GPa. This loss of superconductivity coincides with the pressure induced amorphization of Fe(SeTe)4 tetrahedra reported at 11 GPa in x-ray diffraction studiesmore » at ambient temperature.« less

High-pressure spectroscopic measurement on diffusion with a diamond-anvil cell

NASA Astrophysics Data System (ADS)

Aoki, K.; Katoh, Eriko; Yamawaki, H.; Fujihisa, H.; Sakashita, M.

2003-04-01

We report a diamond-anvil-cell (DAC) technique developed for spectroscopic measurement on the diffusion process in molecular solids at high pressure. The diffusion processes of atoms, molecules, or their ionic species are investigated for a bilayer specimen by measuring the variation of infrared vibrational spectra with time. The experimental procedures for the protonic and molecular diffusion measurements on ice at 400 K and 10.2 GPa are presented as an example study. The in situ spectroscopic technique with a DAC significantly extends the pressure range accessible for diffusion measurement. The diffusion process at a rate of 10-16-10-14 m2/s can currently be observed at temperatures of 300-600 K and pressures up to several tens of gigaPascals.

[Recent advances of anastomosis techniques of esophagojejunostomy after laparoscopic totally gastrectomy in gastric tumor].

PubMed

Li, Xi; Ke, Chongwei

2015-05-01

The esophageal jejunum anastomosis of the digestive tract reconstruction techniques in laparoscopic total gastrectomy includes two categories: circular stapler anastomosis techniques and linear stapler anastomosis techniques. Circular stapler anastomosis techniques include manual anastomosis method, purse string instrument method, Hiki improved special anvil anastomosis technique, the transorally inserted anvil(OrVil(TM)) and reverse puncture device technique. Linear stapler anastomosis techniques include side to side anastomosis technique and Overlap side to side anastomosis technique. Esophageal jejunum anastomosis technique has a wide selection of different technologies with different strengths and the corresponding limitations. This article will introduce research progress of laparoscopic total gastrectomy esophagus jejunum anastomosis from both sides of the development of anastomosis technology and the selection of anastomosis technology.

Diamond-anvil cell for radial x-ray diffraction.

PubMed

Chesnut, G N; Schiferl, D; Streetman, B D; Anderson, W W

2006-06-28

We have designed a new diamond-anvil cell capable of radial x-ray diffraction to pressures of a few hundred GPa. The diffraction geometry allows access to multiple angles of Ψ, which is the angle between each reciprocal lattice vector g(hkl) and the compression axis of the cell. At the 'magic angle', Ψ≈54.7°, the effects of deviatoric stresses on the interplanar spacings, d(hkl), are significantly reduced. Because the systematic errors, which are different for each d(hkl), are significantly reduced, the crystal structures and the derived equations of state can be determined reliably. At other values of Ψ, the effects of deviatoric stresses on the diffraction pattern could eventually be used to determine elastic constants.

Polarized pressure dependence of the anisotropic dielectric functions of highly oriented poly(p-phenylene vinylene)

NASA Astrophysics Data System (ADS)

Morandi, V.; Galli, M.; Marabelli, F.; Comoretto, D.

2010-04-01

In this work, we combined an experimental technique and a detailed data analysis to investigate the influence of an applied pressure on the anisotropic dielectric functions of highly oriented poly(p-phenylene vinylene) (PPV). The dielectric constants were derived from polarized reflectance spectra recorded through a diamond anvil cell up to 50 kbar. The presence of the diamond anvils strongly affects measured spectra requiring the development in an optical model able to take all spurious effects into account. A parametric procedure was then applied to derive the complex dielectric constants for both polarizations as a function of pressure. A detailed analysis of their pressure dependence allows addressing the role of intermolecular interactions and electron-phonon coupling in highly oriented PPV.

Spear-anvil point-contact spectroscopy in pulsed magnetic fields

NASA Astrophysics Data System (ADS)

Arnold, F.; Yager, B.; Kampert, E.; Putzke, C.; Nyéki, J.; Saunders, J.

2013-11-01

We describe a new design and experimental technique for point-contact spectroscopy in non-destructive pulsed magnetic fields up to 70 {T}. Point-contact spectroscopy uses a quasi-dc four-point measurement of the current and voltage across a spear-anvil point-contact. The contact resistance could be adjusted over three orders of magnitude by a built-in fine pitch threaded screw. The first measurements using this set-up were performed on both single-crystalline and exfoliated graphite samples in a 150 {ms}, pulse length 70 {T} coil at 4.2 {K} and reproduced the well known point-contact spectrum of graphite and showed evidence for a developing high field excitation above 35 T, the onset field of the charge-density wave instability in graphite.

Synchrotron x-ray spectroscopy of EuHN O3 aqueous solutions at high temperatures and pressures and Nb-bearing silicate melt phases coexisting with hydrothermal fluids using a modified hydrothermal diamond anvil cell and rail assembly

USGS Publications Warehouse

Mayanovic, Robert A.; Anderson, Alan J.; Bassett, William A.; Chou, I.-Ming

2007-01-01

A modified hydrothermal diamond anvil cell (HDAC) rail assembly has been constructed for making synchrotron x-ray absorption spectroscopy, x-ray fluorescence, and x-ray mapping measurements on fluids or solid phases in contact with hydrothermal fluids up to ???900??C and 700 MPa. The diamond anvils of the HDAC are modified by laser milling grooves or holes, for the reduction of attenuation of incident and fluorescent x rays and sample cavities. The modified HDAC rail assembly has flexibility in design for measurement of light elements at low concentrations or heavy elements at trace levels in the sample and the capability to probe minute individual phases of a multiphase fluid-based system using focused x-ray microbeam. The supporting rail allows for uniform translation of the HDAC, rotation and tilt stages, and a focusing mirror, which is used to illuminate the sample for visual observation using a microscope, relative to the direction of the incident x-ray beam. A structure study of Eu(III) aqua ion behavior in high-temperature aqueous solutions and a study of Nb partitioning and coordination in a silicate melt in contact with a hydrothermal fluid are described as applications utilizing the modified HDAC rail assembly. ?? 2007 American Institute of Physics.

Hydrothermal studies in a new diamond anvil cell up to 10 GPa and from -190°C to 1200°C

USGS Publications Warehouse

Bassett, William A.; Shen, A.H.; Bucknum, M.; Chou, I.-Ming

1993-01-01

The new hydrothermal diamond anvil cell (HDAC) has been designed for optical microscopy and X-ray diffraction at pressures up to 10 GPa and temperatures between −190°C and 1200°C. Laser light reffected from the top and bottom anvil faces and the top and bottom solid sample faces produce interference fringes that provide a very sensitive means of monitoring the volume of sample chamber and for observing volume and refractive index changes in solid samples due to transitions and reactions. Synchrotron radiation has been used to make X-ray diffraction patterns of samples under hydrothermal conditions. Individual heaters and individual thermocouples provide temperature control with an accuracy of ±0.5°C. Liquid nitrogen directly introduced into the HDAC has been used to reduce the sample temperature to −190°C. The α-β phase boundary of quartz has been used to calculate the transition pressures from measured transition temperatures. With this method we have redetermined 5 isochores of H2O up to 850°C and 1.2 GPa at which the solution rate of the quartz became so rapid that the quartz dissolved completely before the α-β transition could be observed. When silica solutions were cooled, opal spherules and rods formed.

On the Composition and Temperature of the Terrestrial Planetary Core

NASA Astrophysics Data System (ADS)

Fei, Yingwei

2013-06-01

The existence of liquid cores of terrestrial planets such as the Earth, Mar, and Mercury has been supported by various observation. The liquid state of the core provides a unique opportunity for us to estimate the temperature of the core if we know the melting temperature of the core materials at core pressure. Dynamic compression by shock wave, laser-heating in diamond-anvil cell, and resistance-heating in the multi-anvil device can melt core materials over a wide pressure range. There have been significant advances in both dynamic and static experimental techniques and characterization tool. In this tal, I will review some of the recent advances and results relevant to the composition and thermal state of the terrestrial core. I will also present new development to analyze the quenched samples recovered from laser-heating diamond-anvil cell experiments using combination of focused ion beam milling, high-resolution SEM imaging, and quantitative chemical analysi. With precision milling of the laser-heating spo, the melting point and element partitioning between solid and liquid can be precisely determined. It is also possible to re-construct 3D image of the laser-heating spot at multi-megabar pressures to better constrain melting point and understanding melting process. The new techniques allow us to extend precise measurements of melting relations to core pressures, providing better constraint on the temperature of the cor. The research is supported by NASA and NSF grants.

Use of a miniature diamond-anvil cell in high-pressure single-crystal neutron Laue diffraction

PubMed Central

Binns, Jack; Kamenev, Konstantin V.; McIntyre, Garry J.; Moggach, Stephen A.; Parsons, Simon

2016-01-01

The first high-pressure neutron diffraction study in a miniature diamond-anvil cell of a single crystal of size typical for X-ray diffraction is reported. This is made possible by modern Laue diffraction using a large solid-angle image-plate detector. An unexpected finding is that even reflections whose diffracted beams pass through the cell body are reliably observed, albeit with some attenuation. The cell body does limit the range of usable incident angles, but the crystallographic completeness for a high-symmetry unit cell is only slightly less than for a data collection without the cell. Data collections for two sizes of hexamine single crystals, with and without the pressure cell, and at 300 and 150 K, show that sample size and temperature are the most important factors that influence data quality. Despite the smaller crystal size and dominant parasitic scattering from the diamond-anvil cell, the data collected allow a full anisotropic refinement of hexamine with bond lengths and angles that agree with literature data within experimental error. This technique is shown to be suitable for low-symmetry crystals, and in these cases the transmission of diffracted beams through the cell body results in much higher completeness values than are possible with X-rays. The way is now open for joint X-ray and neutron studies on the same sample under identical conditions. PMID:27158503

High-Pressure High-Temperature Phase Diagram of the Organic Crystal Paracetamol

NASA Astrophysics Data System (ADS)

Smith, Spencer; Montgomery, Jeffrey; Vohra, Yogesh

High-pressure high-temperature (HPHT) Raman spectroscopy studies have been performed on the organic crystal paracetamol in a diamond anvil cell utilizing boron-doped diamond as heating anvil. The HPHT data obtained from boron-doped diamond heater is cross-checked with data obtained using a standard block heater diamond anvil cell. Isobaric measurements were conducted at pressures up to 8.5 GPa and temperature up to 520 K in a number of different experiments. Solid state phase transitions from monoclinic Form I --> orthorhombic Form II were observed at various pressures and temperatures as well as transitions from Form II --> unknown Form IV. The melting temperature for paracetamol was observed to increase with increasing pressures to 8.5 GPa. Our previous angle dispersive x-ray diffraction studies at the Advanced Photon Source has confirmed the existence of two unknown crystal structures Form IV and Form V of paracetamol at high pressure and ambient temperature. The phase transformation from Form II to Form IV occurs at ~8.5 GPa and from Form IV to Form V occurs at ~11 GPa at ambient temperature. Our new data is combined with the previous ambient temperature high-pressure Raman and X- ray diffraction data to create the first HPHT phase diagram of paracetamol. Doe-NNSA Carnegie DOE Alliance Center (CDAC) under Grant Number DE-NA0002006.

High-pressure high-temperature phase diagram of organic crystal paracetamol

DOE PAGES

Smith, Spencer J.; Montgomery, Jeffrey M.; Vohra, Yogesh K.

2016-01-06

High-pressure high-temperature (HPHT) Raman spectroscopy studies have been performed on the organic crystal paracetamol in a diamond anvil cell utilizing boron-doped heating diamond anvil. Isobaric measurements were conducted at pressures up to 8.5 GPa and temperature up to 520 K in five different experiments. Solid state phase transitions from monoclinic Form I → orthorhombic Form II were observed at various pressures and temperatures as well as transitions from Form II → unknown Form IV. The melting temperature for paracetamol was observed to increase with increasing pressures to 8.5 GPa. As a result, this new data is combined with previous ambientmore » temperature high-pressure Raman and X- ray diffraction data to create the first HPHT phase diagram of paracetamol.« less

Passively damped vibration welding system and method

DOEpatents

Tan, Chin-An; Kang, Bongsu; Cai, Wayne W.; Wu, Tao

2013-04-02

A vibration welding system includes a controller, welding horn, an anvil, and a passive damping mechanism (PDM). The controller generates an input signal having a calibrated frequency. The horn vibrates in a desirable first direction at the calibrated frequency in response to the input signal to form a weld in a work piece. The PDM is positioned with respect to the system, and substantially damps or attenuates vibration in an undesirable second direction. A method includes connecting the PDM having calibrated properties and a natural frequency to an anvil of an ultrasonic welding system. Then, an input signal is generated using a weld controller. The method includes vibrating a welding horn in a desirable direction in response to the input signal, and passively damping vibration in an undesirable direction using the PDM.

Image analysis of speckle patterns as a probe of melting transitions in laser-heated diamond anvil cell experiments.

PubMed

Salem, Ran; Matityahu, Shlomi; Melchior, Aviva; Nikolaevsky, Mark; Noked, Ori; Sterer, Eran

2015-09-01

The precision of melting curve measurements using laser-heated diamond anvil cell (LHDAC) is largely limited by the correct and reliable determination of the onset of melting. We present a novel image analysis of speckle interference patterns in the LHDAC as a way to define quantitative measures which enable an objective determination of the melting transition. Combined with our low-temperature customized IR pyrometer, designed for measurements down to 500 K, our setup allows studying the melting curve of materials with low melting temperatures, with relatively high precision. As an application, the melting curve of Te was measured up to 35 GPa. The results are found to be in good agreement with previous data obtained at pressures up to 10 GPa.

3D modeling of unconstrained HPT process: role of strain gradient on high deformed microstructure formation

NASA Astrophysics Data System (ADS)

Ben Kaabar, A.; Aoufi, A.; Descartes, S.; Desrayaud, C.

2017-05-01

During tribological contact’s life, different deformation paths lead to the formation of high deformed microstructure, in the near-surface layers of the bodies. The mechanical conditions (high pressure, shear) occurring under contact, are reproduced through unconstrained High Pressure Torsion configuration. A 3D finite element model of this HPT test is developed to study the local deformation history leading to high deformed microstructure with nominal pressure and friction coefficient. For the present numerical study the friction coefficient at the interface sample/anvils is kept constant at 0.3; the material used is high purity iron. The strain distribution in the sample bulk, as well as the main components of the strain gradients according to the spatial coordinates are investigated, with rotation angle of the anvil.

High-pressure high-temperature phase diagram of organic crystal paracetamol

NASA Astrophysics Data System (ADS)

Smith, Spencer J.; Montgomery, Jeffrey M.; Vohra, Yogesh K.

2016-01-01

High-pressure high-temperature (HPHT) Raman spectroscopy studies have been performed on the organic crystal paracetamol in a diamond anvil cell utilizing boron-doped heating diamond anvil. Isobaric measurements were conducted at pressures up to 8.5 GPa and temperature up to 520 K in five different experiments. Solid state phase transitions from monoclinic Form I  →  orthorhombic Form II were observed at various pressures and temperatures as well as transitions from Form II  →  unknown Form IV. The melting temperature for paracetamol was observed to increase with increasing pressures to 8.5 GPa. This new data is combined with previous ambient temperature high-pressure Raman and x-ray diffraction data to create the first HPHT phase diagram of paracetamol.

Sub-Kelvin magnetic and electrical measurements in a diamond anvil cell with in situ tunability

NASA Astrophysics Data System (ADS)

Palmer, A.; Silevitch, D. M.; Feng, Yejun; Wang, Yishu; Jaramillo, R.; Banerjee, A.; Ren, Y.; Rosenbaum, T. F.

2015-09-01

We discuss techniques for performing continuous measurements across a wide range of pressure-field-temperature phase space, combining the milli-Kelvin temperatures of a helium dilution refrigerator with the giga-Pascal pressures of a diamond anvil cell and the Tesla magnetic fields of a superconducting magnet. With a view towards minimizing remnant magnetic fields and background magnetic susceptibility, we characterize high-strength superalloy materials for the pressure cell assembly, which allows high fidelity measurements of low-field phenomena such as superconductivity below 100 mK at pressures above 10 GPa. In situ tunability and measurement of the pressure permit experiments over a wide range of pressure, while at the same time making possible precise steps across abrupt phase transitions such as those from insulator to metal.

X-radiography, XRD and Ultrasonic Data Transfer Function Technique - Simultaneous Measurements Under Simulated Mantle Conditions in a Multi-Anvil Device

NASA Astrophysics Data System (ADS)

Mueller, H. J.; Schilling, F. R.; Lathe, C.

2004-05-01

The interpretation of seismic data from the Earth's deep interior requires measurements of the physical properties of Earth materials under experimental simulated mantle conditions. Elastic wave velocity measurement is an important tool for the determination of the elastic properties. Ultrasonic interferometry allows the highly precise travel time measurement at a sample enclosed in a high-pressure multi-anvil device. But the calculation of wave velocities requires the exact sample length under in situ conditions. There are two options - scanning the interfaces of the sample by XRD (Mueller et al., 2003) and X-radiography (Li et al., 2001). The multi-anvil apparatus MAX80 is equipped for both methods. Only the X-radiography is fast enough for transient measurements. Contrary to XRD measurements, imaging the sample by X-rays requires a beam diameter larger than the sample length. Therefore the fixed primary slits of Max80 were exchanged by 4-blade high precision slits of Advanced Design Consulting, Inc. A Ce-YAG-crystal converts the X-ray image to an optical one, redirected by a mirror and captured by a CCD-camera. To derive the sample length, the different brightness of sample, buffer rod and reflector at the electronic image is evaluated. Classical ultrasonic interferometry is very time consuming, because the ultrasonic waves of the frequency range under study are generated and detected one after another with a given step rate. A 60 MHz frequency sweep with 100 kHz steps lasts for more than 30 minutes. This is a serious limitation for all transient measurements, but also limits the data collection at elevated temperatures to prevent the pressure transmitting boron epoxy cubes and the anvils from overheating. The ultrasonic transfer function technique (UTF), first described by Li et al. (2002), generates all the frequencies simultaneously. Related to the results and experiences of Li the UTF-technique was developed independently at GFZ. This version allows to consider the characteristics of the specific transducer-glue-anvil combination (Mueller et al., 2003). To collect the data for the following calculation of Vp and Vs requires just few seconds. The excitation function, applied to the transducer by an arbitrary waveform generator, is the result of the summation of all sinusoidal waves inside the frequency range. The response of the system - transducer - anvil - buffer rod - sample - reflector - for each of the frequencies can be reproduced by convoluting the resulting transfer function with these monochromatic waves step by step. Some recent results on the non-quenchable high-P - low-P clinoenstatite transition and to the quartz-coesite transition will be given to discuss the different interferometric techniques, including the XRD-data and X-radiography results, necessary to detect the phase transitions under in situ conditions and to measure the sample deformation. Li, B.; Vaughan, M.T.; Kung, J.; Weidner, D.J., NSLS Activity Report 2001, 2-103-106, (2001). Li, B.; Chen, K.; Kung, J.; Liebermann, R.C.; Weidner, D.J., J. Phys.: Condens. Matter 14, 11337-11342, (2002). Mueller, H.J.; Schilling, F.R.; Lauterjung, J.; Lathe, C., Eur. J. Mineral., 15, 865-873, (2003). Mueller, H.J.; Wunder, B.; Lathe, C.; Schilling, F.R.; Eur. J. Mineral., submitted, (2004).

A modified technique for esophagojejunostomy or esophagogastrostomy after laparoscopic gastrectomy.

PubMed

Chong-Wei, Ke; Dan-Lei, Chen; Dan, Ding

2013-06-01

Reconstruction of the digestive tract involving esophageal anastomosis after laparoscopic gastrectomy is a surgically difficult procedure. In this study, a newly developed transoral pretilted circular anvil, a "the oral to the abdomen" method, was proven to be effective. A total of 34 consecutive patients underwent esophageal anastomosis using the OrVil in our hospital from July 2009 to February 2011. The esophagus was transected and a small hole was then made in the esophageal stump through which the nasogastric tube of the OrVil was passed to insert the anvil into the abdominal cavity. After fixation with a stapler and a glove at the jejunal loop or the remnant stomach, the abdominal cavity was entered through the minilaparotomy. Pneumoperitoneum and airtightness were reestablished after the glove edge was turned over to seal off the protector. Eventually, intracorporeal esophagojejunostomy or esophagogastrostomy was accomplished under the guidance of laparoscopy. There were 34 patients in the study: 1 with Zollinger-Ellison syndrome, 7 with stromal tumors in cardia, 23 with adenocarcinoma in the stomach, and 3 with cardia adenocarcinoma involving the lower esophagus. The surgical margins for all tumor patients were negative for tumor cells. The mean operative time was 175.0 minutes (90 to 240 min) and the mean intraoperative blood loss was 195.6 mL (50 to 800 mL). The 34 patients underwent successful laparoscopic surgeries with no open conversions. For 32 patients, there were no technological complications in the transoral insertion of the anvil to the esophageal stump. There were no anastomotic leaks after the surgery. The use of the OrVil device, a "the oral to the abdomen" method, changes the direction of the anvil insertion and significantly decreases both difficulty and duration of the laparoscopic surgery. More importantly, if the mass is at a higher position, this approach can achieve a higher surgical margin compared with the hand-sewn purse-string suture technique, thus avoiding the need to undergo a thoracotomy (Supplemental Digital Content 1, http://links.lww.com/SLE/A83).

Novel diamond cells for neutron diffraction using multi-carat CVD anvils.

PubMed

Boehler, R; Molaison, J J; Haberl, B

2017-08-01

Traditionally, neutron diffraction at high pressure has been severely limited in pressure because low neutron flux required large sample volumes and therefore large volume presses. At the high-flux Spallation Neutron Source at the Oak Ridge National Laboratory, we have developed new, large-volume diamond anvil cells for neutron diffraction. The main features of these cells are multi-carat, single crystal chemical vapor deposition diamonds, very large diffraction apertures, and gas membranes to accommodate pressure stability, especially upon cooling. A new cell has been tested for diffraction up to 40 GPa with an unprecedented sample volume of ∼0.15 mm 3 . High quality spectra were obtained in 1 h for crystalline Ni and in ∼8 h for disordered glassy carbon. These new techniques will open the way for routine megabar neutron diffraction experiments.

Final Report. IUT No. B560420 with UC Berkeley. Organic Chemistry at High Pressures &Temperatures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Montgomery, W; Crowhurst, J C; Zaug, J M

We have successfully completed the research outlined in our proposal: Organic Chemistry at High Pressures and Temperatures. We have experimentally determined a phase diagram which documents the phases and reaction regimes of cyanuric acid , H{sub 3}C{sub 3}N{sub 3}O{sub 3} (1,3,5-triazine-2,4,6-trione), from 300 - 750 K and 0 - 8.1 GPa. We utilized a comparatively new technique to study thin samples of cyanuric acid in the diamond anvil cell in order to collect ambient temperature, high pressure FTIR and Raman data as well as the high-pressure, high-temperature data used in the phase diagram. These experiments made use of the CMLSmore » High-pressure lab's diamond anvil facilities as well as the FTIR and Raman systems.« less

Virtual Environment User Interfaces to Support RLV and Space Station Simulations in the ANVIL Virtual Reality Lab

NASA Technical Reports Server (NTRS)

Dumas, Joseph D., II

1998-01-01

Several virtual reality I/O peripherals were successfully configured and integrated as part of the author's 1997 Summer Faculty Fellowship work. These devices, which were not supported by the developers of VR software packages, use new software drivers and configuration files developed by the author to allow them to be used with simulations developed using those software packages. The successful integration of these devices has added significant capability to the ANVIL lab at MSFC. In addition, the author was able to complete the integration of a networked virtual reality simulation of the Space Shuttle Remote Manipulator System docking Space Station modules which was begun as part of his 1996 Fellowship. The successful integration of this simulation demonstrates the feasibility of using VR technology for ground-based training as well as on-orbit operations.

Development of Designer Diamond Technology for High Pressure High Temperature Experiments in Support of Stockpile Stewardship Program

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vohra, Yogesh, K.

The role of nitrogen in the fabrication of designer diamond was systematically investigated by adding controlled amount of nitrogen in hydrogen/methane/oxygen plasma. This has led to a successful recipe for reproducible fabrication of designer diamond anvils for high-pressure high-temperature research in support of stockpile stewardship program. In the three-year support period, several designer diamonds fabricated with this new growth chemistry were utilized in high-pressure experiments at UAB and Lawrence Livermore National Laboratory. The designer diamond anvils were utilized in high-pressure studies on heavy rare earth metals, high pressure melting studies on metals, and electrical resistance measurements on iron-based layered superconductorsmore » under high pressures. The growth chemistry developed under NNSA support can be adapted for commercial production of designer diamonds.« less

Vibration welding system with thin film sensor

DOEpatents

Cai, Wayne W; Abell, Jeffrey A; Li, Xiaochun; Choi, Hongseok; Zhao, Jingzhou

2014-03-18

A vibration welding system includes an anvil, a welding horn, a thin film sensor, and a process controller. The anvil and horn include working surfaces that contact a work piece during the welding process. The sensor measures a control value at the working surface. The measured control value is transmitted to the controller, which controls the system in part using the measured control value. The thin film sensor may include a plurality of thermopiles and thermocouples which collectively measure temperature and heat flux at the working surface. A method includes providing a welder device with a slot adjacent to a working surface of the welder device, inserting the thin film sensor into the slot, and using the sensor to measure a control value at the working surface. A process controller then controls the vibration welding system in part using the measured control value.

Sub-Kelvin magnetic and electrical measurements in a diamond anvil cell with in-situ tunability

DOE PAGES

Palmer, Alexander; Silevitch, Daniel; Feng, Yejun; ...

2015-09-04

We discuss techniques for performing continuous measurements across a wide range of pressure-field-temperature phase space, combining the milli-Kelvin temperatures of a helium dilution refrigerator with that of the giga-Pascal pressures of a diamond anvil cell and the Tesla magnetic fields of a superconducting magnet. With a view towards minimizing remnant magnetic fields and background magnetic susceptibility, we then characterize high-strength superalloy materials for the pressure cell assembly, which allows high fidelity measurements of low-field phenomena such as superconductivity below 100 mK at pressures above 10 GPa. In situ tunability and measurement of the pressure permit experiments over a wide rangemore » of pressure, while at the same time making possible precise steps across abrupt phase transitions such as that from insulator to metal.« less

Met The Press: What It's LIke to Talk to Reporters about Physics

NASA Astrophysics Data System (ADS)

Thompson, Rebecca

2013-03-01

Someone from the Huffington Post just called you because they are doing a story about science and you are a physicist. The problem is that they need you to take time away from your grapheme experiments to talk about the physics of exploding anvils. It's been a long time since you've shot an anvil in the air so you think you might not be right for this. But, as long as you understand general physics and can explain things well, you can be a real asset. This talk will recount first-hand experiences talking to a range of news outlets from the PBS New Hour to Real Simple Magazine about everything from quick-freezing water to pumpkin boats. It will include helpful information about preparing for an interview, learning new physics fast, timelines and follow-up.

New developments in laser-heated diamond anvil cell with in situ synchrotron x-ray diffraction at High Pressure Collaborative Access Team

DOE Office of Scientific and Technical Information (OSTI.GOV)

Meng, Yue; Hrubiak, Rostislav; Rod, Eric

An overview of the in situ laser heating system at the High Pressure Collaborative Access Team, with emphasis on newly developed capabilities, is presented. Since its establishment at the beamline 16-ID-B a decade ago, laser-heated diamond anvil cell coupled with in situ synchrotron x-ray diffraction has been widely used for studying the structural properties of materials under simultaneous high pressure and high temperature conditions. Recent developments in both continuous-wave and modulated heating techniques have been focusing on resolving technical issues of the most challenging research areas. Furthermore, the new capabilities have demonstrated clear benefits and provide new opportunities in researchmore » areas including high-pressure melting, pressure-temperature-volume equations of state, chemical reaction, and time resolved studies.« less

New developments in laser-heated diamond anvil cell with in situ synchrotron x-ray diffraction at High Pressure Collaborative Access Team

DOE PAGES

Meng, Yue; Hrubiak, Rostislav; Rod, Eric; ...

2015-07-17

An overview of the in situ laser heating system at the High Pressure Collaborative Access Team, with emphasis on newly developed capabilities, is presented. Since its establishment at the beamline 16-ID-B a decade ago, laser-heated diamond anvil cell coupled with in situ synchrotron x-ray diffraction has been widely used for studying the structural properties of materials under simultaneous high pressure and high temperature conditions. Recent developments in both continuous-wave and modulated heating techniques have been focusing on resolving technical issues of the most challenging research areas. Furthermore, the new capabilities have demonstrated clear benefits and provide new opportunities in researchmore » areas including high-pressure melting, pressure-temperature-volume equations of state, chemical reaction, and time resolved studies.« less

New developments in laser-heated diamond anvil cell with in situ synchrotron x-ray diffraction at High Pressure Collaborative Access Team

DOE Office of Scientific and Technical Information (OSTI.GOV)

Meng, Yue; Hrubiak, Rostislav; Rod, Eric

An overview of the in situ laser heating system at the High Pressure Collaborative Access Team, with emphasis on newly developed capabilities, is presented. Since its establishment at the beamline 16-ID-B a decade ago, laser-heated diamond anvil cell coupled with in situ synchrotron x-ray diffraction has been widely used for studying the structural properties of materials under simultaneous high pressure and high temperature conditions. Recent developments in both continuous-wave and modulated heating techniques have been focusing on resolving technical issues of the most challenging research areas. The new capabilities have demonstrated clear benefits and provide new opportunities in research areasmore » including high-pressure melting, pressure-temperature-volume equations of state, chemical reaction, and time resolved studies.« less

Sub-Kelvin magnetic and electrical measurements in a diamond anvil cell with in situ tunability

DOE Office of Scientific and Technical Information (OSTI.GOV)

Palmer, A; Silevitch, D M; Feng, Yejun

2015-09-01

We discuss techniques for performing continuous measurements across a wide range of pressure–field–temperature phase space, combining the milli-Kelvin temperatures of a helium dilution refrigerator with the giga-Pascal pressures of a diamond anvil cell and the Tesla magnetic fields of a superconducting magnet. With a view towards minimizing remnant magnetic fields and background magnetic susceptibility, we characterize high-strength superalloy materials for the pressure cell assembly, which allows high fidelity measurements of low-field phenomena such as superconductivity below 100 mK at pressures above 10 GPa. In situ tunability and measurement of the pressure permit experiments over a wide range of pressure, whilemore » at the same time making possible precise steps across abrupt phase transitions such as those from insulator to metal.« less

Equation of state of rhenium and application for ultra high pressure calibration

DOE Office of Scientific and Technical Information (OSTI.GOV)

Anzellini, Simone; Dewaele, Agnès; Occelli, Florent

2014-01-28

The isothermal equation of state of rhenium has been measured by powder X-ray diffraction experiments up to 144 GPa at room temperature in a diamond anvil cell. A helium pressure transmitting medium was used to minimize the non-hydrostatic stress on the sample. The fit of pressure-volume data yields a bulk modulus K{sub 0} = 352.6 GPa and a pressure derivative of the bulk modulus K′{sub 0}=4.56. This equation of state differs significantly from a recent determination [Dubrovinsky et al., Nat. Commun. 3, 1163 (2012)], giving here a lower pressure at a given volume. The possibility of using rhenium gasket X-ray diffraction signal, with themore » present equation of state, to evaluate multi-Mbar pressures in the chamber of diamond anvil cells is discussed.« less

Diamond dissolution and the production of methane and other carbon-bearing species in hydrothermal diamond-anvil cells

USGS Publications Warehouse

Chou, I-Ming; Anderson, Alan J.

2009-01-01

Raman analysis of the vapor phase formed after heating pure water to near critical (355–374 °C) temperatures in a hydrothermal diamond-anvil cell (HDAC) reveals the synthesis of abiogenic methane. This unexpected result demonstrates the chemical reactivity of diamond at relatively low temperatures. The rate of methane production from the reaction between water and diamond increases with increasing temperature and is enhanced by the presence of a metal gasket (Re, Ir, or Inconel) which is compressed between the diamond anvils to seal the aqueous sample. The minimum detection limit for methane using Raman spectroscopy was determined to be ca. 0.047 MPa, indicating that more than 1.4 nanograms (or 8.6 × 10−11 mol) of methane were produced in the HDAC at 355 °C and 30 MPa over a period of ten minutes. At temperatures of 650 °C and greater, hydrogen and carbon dioxide were detected in addition to methane. The production of abiogenic methane, observed in all HDAC experiments where a gasket was used, necessitates a reexamination of the assumed chemical systems and intensive parameters reported in previous hydrothermal investigations employing diamonds. The results also demonstrate the need to minimize or eliminate the production of methane and other carbonic species in experiments by containing the sample within a HDAC without using a metal gasket.

Stress-controlled thermoelectric module for energy harvesting and its application for the significant enhancement of the power factor of Bi2Te3-based thermoelectrics

NASA Astrophysics Data System (ADS)

Korobeinikov, Igor V.; Morozova, Natalia V.; Lukyanova, Lidia N.; Usov, Oleg A.; Kulbachinskii, Vladimir A.; Shchennikov, Vladimir V.; Ovsyannikov, Sergey V.

2018-01-01

We propose a model of a thermoelectric module in which the performance parameters can be controlled by applied tuneable stress. This model includes a miniature high-pressure anvil-type cell and a specially designed thermoelectric module that is compressed between two opposite anvils. High thermally conductive high-pressure anvils that can be made, for instance, of sintered technical diamonds with enhanced thermal conductivity, would enable efficient heat absorption or rejection from a thermoelectric module. Using a high-pressure cell as a prototype of a stress-controlled thermoelectric converter, we investigated the effect of applied high pressure on the power factors of several single-crystalline thermoelectrics, including binary p-type Bi2Te3, and multi-component (Bi,Sb)2Te3 and Bi2(Te,Se,S)3 solid solutions. We found that a moderate applied pressure of a few GPa significantly enhances the power factors of some of these thermoelectrics. Thus, they might be more efficiently utilized in stress-controlled thermoelectric modules. In the example of one of these thermoelectrics crystallizing in the same rhombohedral structure, we examined the crystal lattice stability under moderate high pressures. We uncovered an abnormal compression of the rhombohedral lattice of (Bi0.25,Sb0.75)2Te3 along the c-axis in a hexagonal unit cell, and detected two phase transitions to the C2/m and C2/c monoclinic structures above 9.5 and 18 GPa, respectively.

The Crab pulsar and its pulsar-wind nebula in the optical and infrared

NASA Astrophysics Data System (ADS)

Tziamtzis, A.; Lundqvist, P.; Djupvik, A. A.

2009-12-01

Aims. We investigate the emission mechanism and evolution of pulsars that are associated with supernova remnants. Methods: We used imaging techniques in both the optical and near infrared, using images with very good seeing (≤0.primeprime6) to study the immediate surroundings of the Crab pulsar. In the case of the infrared, we took two data sets with a time window of 75 days to check for variability in the inner part of the Crab nebula. We also measure the spectral indices of all these wisps, the nearby knot, and the interwisp medium, using our optical and infrared data. We then compared the observational results with the existing theoretical models. Results: We report variability in the three nearby wisps located to the northwest of the pulsar and also in a nearby anvil wisp in terms of their structure, position, and emissivity within the time window of 75 days. All the wisps display red spectra with similar spectral indices (α_ν = -0.58 ± 0.08, α_ν = -0.63 ± 0.07, α_ν = -0.53 ± 0.08) for the northwest triplet. The anvil wisp (anvil wisp 1) has a spectral index of α_ν = -0.62 ± 0.10. Similarly, the interwisp medium regions also show red spectra similar to those of the wisps, with the spectral index being α_ν = -0.61 ± 0.08, α_ν = -0.50 ± 0.10, while the third interwisp region has a flatter spectrum with spectral α_ν = -0.49 ± 0.10. The inner knot has a spectral index of α_ν = -0.63 ± 0.02. Also, based on archival HST data and our IR data, we find that the inner knot remains stationary for a time period of 13.5 years. The projected average velocity relative to the pulsar for this period is ≲8 ~km s-1. Conclusions: By comparing the spectral indices of the structures in the inner Crab with the current theoretical models, we find that the Del Zanna et al. model for the synchrotron emission fits our observations, although the spectral index is at the flatter end of their modelled spectra. Based on observations made with the Nordic Optical Telescope, operated on the island of La Palma jointly by Denmark, Finland, Iceland, Norway, and Sweden, in the Spanish Observatorio del Roque de los Muchachos of the Instituto de Astrofisica de Canarias. Part of the data presented here have been taken using ALFOSC, which is owned by the Instituto de Astrofisica de Andalucia (IAA) and operated at the Nordic Optical Telescope under an agreement between IAA and the NBIfAFG of the Astronomical Observatory of Copenhagen.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bhadram, Venkata S.; Liu, Hanyu; Xu, Enshi

We report the discovery of a long-sought-after phase of titanium nitride with stoichiometry Ti3N4 using diamond anvil cell experiments combined with in situ high-resolution x-ray diffraction and Raman spectroscopy techniques, supported by ab initio calculations.

Silicate garnet studies at high pressures: A view into the Earth's mantle

NASA Astrophysics Data System (ADS)

Conrad, Pamela Gales

Silicate garnets are an abundant component in the Earth's upper mantle and transition zone. Therefore, an understanding of garnet behavior under the pressure and temperature conditions of the mantle is critical to the development of models for mantle mineralogy and dynamics. Work from three projects is presented in this report. Each investigation explores an aspect of silicate garnet behavior under high pressures. Moreover, each investigation was made possible by state-of-the-art methods that have previously been unavailable. Brillouin scattering was used to determine the elastic constants and aggregate elastic moduli of three end-member garnets at high pressures in a diamond anvil cell. These are the first high-pressure measurements of the elastic constants of end-member silicate garnets by direct measurement of acoustic velocities. The results indicate that the pressure dependence of silicate garnet elastic constants varies with composition. Therefore, extrapolation from measurements on mixed composition garnets is not possible. A new method of laser heating minerals in a diamond anvil cell has made possible the determination of the high-pressure and high-temperature stability of almandine garnet. This garnet does not transform to a silicate perovskite phase as does pyrope garnet, but it decomposes to its constituent oxides: FeO, Alsb2Osb3, and SiOsb2. These results disprove an earlier prediction that ferrous iron may expand the stability field of garnet to the lower mantle. The present results demonstrate that this is not the case. The third topic is a presentation of the results of a new technique for studying inclusions in mantle xenoliths with synchrotron X-ray microdiffraction. The results demonstrate the importance of obtaining structural as well as chemical information on inclusions within diamonds and other high-pressure minerals. An unusual phase with garnet composition is investigated and several other phases are identified from a suite of natural diamonds that are thought to have a lower mantle origin.

Elevated O3 in Fresh and Aged Lightning-NOx Plumes Interacting with Biomass Burning Plumes over the Central U.S. during DC3 (Invited)

NASA Astrophysics Data System (ADS)

Huntrieser, H.; Lichtenstern, M.; Scheibe, M.; Aufmhoff, H.; Schlager, H.; Pucik, T.; Minikin, A.; Weinzierl, B.; Heimerl, K.; Fütterer, D.; Rappenglück, B.; Ackermann, L.; Pickering, K. E.; Cummings, K.; Barth, M. C.

2013-12-01

During the Deep Convective Clouds and Chemistry Experiment (DC3) in summer 2012 a variety of different thunderstorm systems were investigated over the Central U.S. by the DLR research aircraft Falcon together with the NCAR GV and NASA DC-8 aircraft. In addition, the complete DC3 field phase was characterized by a number of extended wildfires burning in the surroundings of the thunderstorms. Here we mainly focus on trace gas in situ measurements, such as NOx, CO, O3, CH4, SO2, NMHC, and a variety of aerosol measurements carried out by the Falcon in the fresh (~0-6 h) and aged (~12-24 h) anvil outflow at ~10-12 km altitude. It is well-known that thunderstorms modify the trace gas composition in the upper troposphere (UT) and may affect O3 mixing ratios, an important greenhouse gas in the UT. However, a complete picture of the different processes affecting the UT-O3 composition in vicinity of thunderstorms and its large-scale effects is still missing. From the DC3 data set we present an example of small-scale effects on the O3 composition in the anvil outflow, such as immediate O3 production by an aircraft-induced flash. But we also show how the efficient convective transport that extended over the whole updraft region may transport O3-poorer air masses from the, in general, rather unpolluted inflow region (with regard to anthropogenic emissions) over the Central U.S. directly to the UT. However, in a few cases enhanced O3 mixing ratios were observed in the anvil outflow attributed to different chemical and dynamical processes. In the two most powerful convective systems, an intense MCS over Missouri/Arkansas and a supercell over Texas, extended biomass burning (BB) plumes from New Mexico interacted with the thunderstorms. Ozone production was obvious in the BB plumes transported mainly in the lower troposphere at ~2-5 km altitude (ΔO3/ΔCO=0.1). However, if these air masses affected by BB emissions (containing high amounts of O3 precursors such as CH4 and NMHC) were ingested into the surrounding thunderstorms (with high HOx and NOx) and transported to the UT region, the ΔO3/ΔCO slope increased dramatically to values up to ~0.6-2.5. In addition to enhanced O3 production rates in thunderstorm outflows interacting with BB plumes, the pronounced downward mixing of O3-rich air mass from the stratosphere down to 8 km was observed in an aged anvil outflow from a squall line active over Colorado which was advected to Kansas the day after. Overall, from the local DC3 Falcon measurements the effect of downward mixing of O3-rich stratospheric air masses seems to cause the largest increase in O3 mixing ratios in the aged anvil outflow.

Structural and magnetic phase transitions in gadolinium under high pressures and low temperatures

DOE PAGES

Samudrala, Gopi K.; Tsoi, Georgiy M.; Weir, Samuel T.; ...

2014-11-07

High pressure structural transition studies have been carried out on rare earth metal gadolinium in a diamond anvil cell at room temperature to 169 GPa. Gadolinium has been compressed to 38% of its initial volume at this pressure. With increasing pressure, a crystal structure sequence of hcp → Smtype→ dhcp → fcc → dfcc → monoclinic has been observed in our studies on gadolinium. The measured equation of state of gadolinium is presented to 169 GPa at ambient temperature. Magnetic ordering temperature of gadolinium has been studied using designer diamond anvils to a pressure of 25 GP and a temperaturemore » of 10 K. The magnetic ordering temperature has been determined from the four-point electrical resistivity measurements carried out on gadolinium. Furthermore, our experiments show that the magnetic transition temperature decreases with increasing pressure to 19 GPa and then increases when gadolinium is subjected to higher pressures.« less

Mechanochemical induced structural changes in sucrose using the rotational diamond anvil cell

NASA Astrophysics Data System (ADS)

Ciezak-Jenkins, Jennifer A.; Jenkins, Timothy A.

2018-02-01

The response of sucrose to high-pressure and shear conditions has been studied in a rotational diamond anvil cell. Previous experiments conducted by Bridgman and Teller showed divergent behavior in regard to the existence of a rheological explosion under mechanochemical stimuli. Raman spectroscopy confirmed the existence of the isostructural Phase I to Phase II transition near 5 GPa. When subjected to high-pressure and shear, Raman spectra of Phase I showed evidence that while the sucrose molecule underwent significant molecular deformation, there was no evidence of a complete chemical reaction. In contrast, Phase II showed a near-total loss of the in-situ Raman signal in response to shear, suggesting the onset of amorphization or decomposition. The divergent behaviors of Phase I and Phase II are examined in light of the differences in the hydrogen bonding and plasticity of the material.

Thermal equation of state of Molybdenum determined from in situ synchrotron X-ray diffraction with laser-heated diamond anvil cells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Huang, Xiaoli; Li, Fangfei; Zhou, Qiang

Here we report that the equation of state (EOS) of Mo is obtained by an integrated technique of laser-heated DAC and synchrotron X-ray diffraction. The cold compression and thermal expansion of Mo have been measured up to 80 GPa at 300 K, and 92 GPa at 3470 K, respectively. The P-V-T data have been treated with both thermodynamic and Mie–Gruneisen-Debye methods for the thermal EOS inversion. The results are self-consistent and in agreement with the static multi-anvil compression data of Litasov et al. (J. Appl. Phys. 113, 093507 (2013)) and the theoretical data of Zeng et al. (J. Phys. Chem.more » B 114, 298 (2010)). Furthermore, these high pressure and high temperature (HPHT) data with high precision firstly complement and close the gap between the resistive heating and the shock compression experiment.« less

Thermal equation of state of Molybdenum determined from in situ synchrotron X-ray diffraction with laser-heated diamond anvil cells

DOE PAGES

Huang, Xiaoli; Li, Fangfei; Zhou, Qiang; ...

2016-02-17

Here we report that the equation of state (EOS) of Mo is obtained by an integrated technique of laser-heated DAC and synchrotron X-ray diffraction. The cold compression and thermal expansion of Mo have been measured up to 80 GPa at 300 K, and 92 GPa at 3470 K, respectively. The P-V-T data have been treated with both thermodynamic and Mie–Gruneisen-Debye methods for the thermal EOS inversion. The results are self-consistent and in agreement with the static multi-anvil compression data of Litasov et al. (J. Appl. Phys. 113, 093507 (2013)) and the theoretical data of Zeng et al. (J. Phys. Chem.more » B 114, 298 (2010)). Furthermore, these high pressure and high temperature (HPHT) data with high precision firstly complement and close the gap between the resistive heating and the shock compression experiment.« less

A convenient dynamic loading device for studying kinetics of phase transitions and metastable phases using symmetric diamond anvil cells

NASA Astrophysics Data System (ADS)

Cheng, Hu; Zhang, Junran; Li, Yanchun; Li, Gong; Li, Xiaodong; Liu, Jing

2018-01-01

We have designed and implemented a novel DLD for controlling pressure and compression/decompression rate. Combined with the use of the symmetric diamond anvil cells (DACs), the DLD adopts three piezo-electric (PE) actuators and three static load screws to remotely control pressure in accurate and consistent manner at room temperature. This device allows us to create different loading mechanisms and frames for a variety of existing and commonly used diamond cells rather than designing specialized or dedicated diamond cells with various drives. The sample pressure compression/decompression rate that we have achieved is up to 58.6/43.3 TPa/s, respectively. The minimum of load time is less than 1 ms. The DLD is a powerful tool for exploring the effects of rapid (de)compression on the structure of materials and the properties of materials.

Diamond-anvil cell observations of a new methane hydrate phase in the 100-MPa pressure range

USGS Publications Warehouse

Chou, I.-Ming; Sharma, A.; Burruss, R.C.; Hemley, R.J.; Goncharov, A.F.; Stern, L.A.; Kirby, S.H.

2001-01-01

A new high-pressure phase of methane hydrate has been identified based on its high optical relief, distinct pressure-temperature phase relations, and Raman spectra. In-situ optical observations were made in a hydrothermal diamond-anvil cell at temperatures between -40?? and 60 ??C and at pressures up to 900 MPa. Two new invariant points were located at -8.7 ??C and 99 MPa for the assemblage consisting of the new phase, structure I methane hydrate, ice Ih, and water, and at 35.3 ??C and 137 MPa for the new phase-structure I methane hydrate-water-methane vapor. Existence of the new phase is critical for understanding the phase relations among the hydrates at low to moderate pressures, and may also have important implications for understanding the hydrogen bonding in H2O and the behavior of water in the planetary bodies, such as Europa, of the outer solar system.

CePt2In7: Shubnikov-de Haas measurements on micro-structured samples under high pressures

NASA Astrophysics Data System (ADS)

Kanter, J.; Moll, P.; Friedemann, S.; Alireza, P.; Sutherland, M.; Goh, S.; Ronning, F.; Bauer, E. D.; Batlogg, B.

2014-03-01

CePt2In7 belongs to the CemMnIn3 m + 2 n heavy fermion family, but compared to the Ce MIn5 members of this group, exhibits a more two dimensional electronic structure. At zero pressure the ground state is antiferromagnetically ordered. Under pressure the antiferromagnetic order is suppressed and a superconducting phase is induced, with a maximum Tc above a quantum critical point around 31 kbar. To investigate the changes in the Fermi Surface and effective electron masses around the quantum critical point, Shubnikov-de Haas measurements were conducted under high pressures in an anvil cell. The samples were micro-structured and contacted using a Focused Ion Beam (FIB). The Focused Ion Beam enables sample contacting and structuring down to a sub-micrometer scale, making the measurement of several samples with complex shapes and multiple contacts on a single anvil feasible.

Structural and magnetic phase transitions in gadolinium under high pressures and low temperatures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Samudrala, Gopi K.; Tsoi, Georgiy M.; Weir, Samuel T.

High pressure structural transition studies have been carried out on rare earth metal gadolinium in a diamond anvil cell at room temperature to 169 GPa. Gadolinium has been compressed to 38% of its initial volume at this pressure. With increasing pressure, a crystal structure sequence of hcp → Smtype→ dhcp → fcc → dfcc → monoclinic has been observed in our studies on gadolinium. The measured equation of state of gadolinium is presented to 169 GPa at ambient temperature. Magnetic ordering temperature of gadolinium has been studied using designer diamond anvils to a pressure of 25 GP and a temperaturemore » of 10 K. The magnetic ordering temperature has been determined from the four-point electrical resistivity measurements carried out on gadolinium. Furthermore, our experiments show that the magnetic transition temperature decreases with increasing pressure to 19 GPa and then increases when gadolinium is subjected to higher pressures.« less

Phase relations of Fe Ni alloys at high pressure and temperature

NASA Astrophysics Data System (ADS)

Mao, Wendy L.; Campbell, Andrew J.; Heinz, Dion L.; Shen, Guoyin

2006-04-01

Using a diamond anvil cell and double-sided laser-heating coupled with synchrotron X-ray diffraction, we determined phase relations for three compositions of Fe-rich FeNi alloys in situ at high pressure and high temperature. We studied Fe with 5, 15, and 20 wt.% Ni to 55, 62, and 72 GPa, respectively, at temperatures up to ˜3000 K. Ni stabilizes the face-centered cubic phase to lower temperatures and higher pressure, and this effect increases with increasing pressure. Extrapolation of our experimental results for Fe with 15 wt.% Ni suggests that the stable phase at inner core conditions is hexagonal close packed, although if the temperature at the inner core boundary is higher than ˜6400 K, a two phase outer region may also exist. Comparison to previous laser-heated diamond anvil cell studies demonstrates the importance of kinetics even at high temperatures.

Melting temperatures of H2O up to 72 GPa measured in a diamond anvil cell using CO2 laser heating technique.

PubMed

Kimura, T; Kuwayama, Y; Yagi, T

2014-02-21

The melting curve of H2O from 49 to 72 GPa was determined by using a laser-heated diamond anvil cell. Double-sided CO2 laser heating technique was employed in order to heat the sample directly. Discontinuous changes of the heating efficiency attributed to the H2O melting were observed between 49 and 72 GPa. The obtained melting temperatures at 49 and 72 GPa are 1200 and 1410 K, respectively. We found that the slope of the melting curve significantly decreases with increasing pressure, only 5 K/GPa at 72 GPa while 44 K/GPa at 49 GPa. Our results suggest that the melting curve does not intersect with the isentropes of Uranus and Neptune, and hence, H2O should remain in the liquid state even at the pressure and temperature conditions found deep within Uranus and Neptune.

Strength and texture of Pt compressed to 63 GPa

NASA Astrophysics Data System (ADS)

Dorfman, Susannah M.; Shieh, Sean R.; Duffy, Thomas S.

2015-02-01

Angle- and energy-dispersive X-ray diffraction experiments in a radial geometry were performed in the diamond anvil cell on polycrystalline platinum samples at pressures up to 63 GPa. Observed yield strength and texture depend on grain size. For samples with 70-300-nm particle size, the yield strength is 5-6 GPa at ˜60 GPa. Coarse-grained (˜2-μm particles) Pt has a much lower yield strength of 1-1.5 GPa at ˜60 GPa. Face-centered cubic metals Pt and Au have lower strength to shear modulus ratio than body-centered cubic or hexagonal close-packed metals. While a 300-nm particle sample exhibits the <110> texture expected of face-centered-cubic metals under compression, smaller and larger particles show a weak mixed <110> and <100> texture under compression. Differences in texture development may also occur due to deviations from uniaxial stress under compression in the diamond anvil cell.

Novel diamond cells for neutron diffraction using multi-carat CVD anvils

DOE PAGES

Boehler, R.; Molaison, J. J.; Haberl, B.

2017-08-17

Traditionally, neutron diffraction at high pressure has been severely limited in pressure because low neutron flux required large sample volumes and therefore large volume presses. At the high-flux Spallation Neutron Source at the Oak Ridge National Laboratory, we have developed in this paper new, large-volume diamond anvil cells for neutron diffraction. The main features of these cells are multi-carat, single crystal chemical vapor deposition diamonds, very large diffraction apertures, and gas membranes to accommodate pressure stability, especially upon cooling. A new cell has been tested for diffraction up to 40 GPa with an unprecedented sample volume of ~0.15 mm 3.more » High quality spectra were obtained in 1 h for crystalline Ni and in ~8 h for disordered glassy carbon. Finally, these new techniques will open the way for routine megabar neutron diffraction experiments.« less

Structural and magnetic phase transitions in gadolinium under high pressures and low temperatures

NASA Astrophysics Data System (ADS)

Samudrala, Gopi K.; Tsoi, Georgiy M.; Weir, Samuel T.; Vohra, Yogesh K.

2014-10-01

High pressure structural transition studies have been carried out on rare earth metal gadolinium in a diamond anvil cell at room temperature to 169 GPa. Gadolinium has been compressed to 38% of its initial volume at this pressure. With increasing pressure, a crystal structure sequence of hcp → Sm-type → dhcp → fcc → dfcc → monoclinic has been observed in our studies on gadolinium. The measured equation of state of gadolinium is presented to 169 GPa at ambient temperature. Magnetic ordering temperature of gadolinium has been studied using designer diamond anvils to a pressure of 25 GPa and a temperature of 10 K. The magnetic ordering temperature has been determined from the four-point electrical resistivity measurements carried out on gadolinium. Our experiments show that the magnetic transition temperature decreases with increasing pressure to 19 GPa and then increases when gadolinium is subjected to higher pressures.

Evaluation of Forces on the Welding Probe of the Automated Retractable Pin-Tool (RPT)

NASA Technical Reports Server (NTRS)

Ding, R. J.

2001-01-01

The NASA invention entitled 'The Hydraulic Controlled Auto-Adjustable Pin Tool for Friction Stir Welding' (US Patent 5,893,507), better known as the Retractable Pin-Tool (RPT), has been instrumented with a load-detecting device allowing the forces placed on the welding probe to be measured. As the welding probe is plunged into the material, the forces placed on the probe can now be characterized. Of particular interest are those forces experienced as the welding probe comes within close proximity to the back-up anvil. For a given material, it is believed that unique forces are generated relative to the distance between the welding probe and the anvil. The forces have been measured and characterized for several materials, and correlations have been made between these forces and the pin's position relative to the backside of the weld material.

Saharan dust, convective lofting, aerosol enhancement zones, and potential impacts on ice nucleation in the tropical upper troposphere

NASA Astrophysics Data System (ADS)

Twohy, C. H.; Anderson, B. E.; Ferrare, R. A.; Sauter, K. E.; L'Ecuyer, T. S.; van den Heever, S. C.; Heymsfield, A. J.; Ismail, S.; Diskin, G. S.

2017-08-01

Dry aerosol size distributions and scattering coefficients were measured on 10 flights in 32 clear-air regions adjacent to tropical storm anvils over the eastern Atlantic Ocean. Aerosol properties in these regions were compared with those from background air in the upper troposphere at least 40 km from clouds. Median values for aerosol scattering coefficient and particle number concentration >0.3 μm diameter were higher at the anvil edges than in background air, showing that convective clouds loft particles from the lower troposphere to the upper troposphere. These differences are statistically significant. The aerosol enhancement zones extended 10-15 km horizontally and 0.25 km vertically below anvil cloud edges but were not due to hygroscopic growth since particles were measured under dry conditions. Number concentrations of particles >0.3 μm diameter were enhanced more for the cases where Saharan dust layers were identified below the clouds with airborne lidar. Median number concentrations in this size range increased from 100 l-1 in background air to 400 l-1 adjacent to cloud edges with dust below, with larger enhancements for stronger storm systems. Integration with satellite cloud frequency data indicates that this transfer of large particles from low to high altitudes by convection has little impact on dust concentrations within the Saharan Air Layer itself. However, it can lead to substantial enhancement in large dust particles and, therefore, heterogeneous ice nuclei in the upper troposphere over the Atlantic. This may induce a cloud/aerosol feedback effect that could impact cloud properties in the region and downwind.

CO Signatures in Subtropical Convective Clouds and Anvils During CRYSTAL-FACE: An Analysis of Convective Transport and Entertainment Using Observations and a Cloud-Resolving Model

NASA Technical Reports Server (NTRS)

Lopez, Jimena P.; Fridlind, Ann M.; Jost, Hans-Jurg; Loewenstein, Max; Ackerman, Andrew S.; Campos, Teresa L.; Weinstock, Elliot M.; Sayres, David S.; Smith, Jessica B.; Pittman, Jasna V.;

CO Signatures in Subtropical Convective Clouds and Anvils during CRYSTAL-FACE: An Analysis of Convective Transport and Entrainment using Observations and a Cloud-Resolving Model

NASA Technical Reports Server (NTRS)

Lopez, Jimena P.; Fridlind, Ann M.; Jost, Hans-Juerg; Loewenstein, Max; Ackerman, Andrew S.; Campos, Teresa L.; Weinstock, Elliot M.; Sayres, David S.; Smith, Jessica B.; Pittman, Jasna V.

2006-01-01

Convective systems are an important mechanism in the transport of boundary layer air into the upper troposphere. The Cirrus Regional Study of Tropical Anvils and Cirrus Layers-Florida Area Cirrus Experiment (CRYSTAL-FACE) campaign, in July 2002, was developed as a comprehensive atmospheric mission to improve knowledge of subtropical cirrus systems and their roles in regional and global climate. In situ measurements of carbon monoxide (CO), water vapor (H2Ov), and total water (H2Ot) aboard NASA's WB-57F aircraft and CO aboard the U.S. Navy's Twin Otter aircraft were obtained to study the role of convective transport. Three flights sampled convective outflow on 11, 16 and 29 July found varying degrees of CO enhancement relative to the free troposphere. A cloud-resolving model used the in situ observations and meteorological fields to study these three systems. Several methods of filtering the observations were devised here using ice water content, relative humidity with respect to ice, and particle number concentration as a means to statistically sample the model results to represent the flight tracks. A weighted histogram based on ice water content observations was then used to sample the simulations for the three flights. In addition, because the observations occurred in the convective outflow cirrus and not in the storm cores, the model was used to estimate the maximum CO within the convective systems. In general, anvil-level air parcels contained an estimated 20-40% boundary layer air in the analyzed storms.

Finite element modeling of melting and fluid flow in the laser-heated diamond-anvil cell

NASA Astrophysics Data System (ADS)

Gomez-Perez, N.; Rodriguez, J. F.; McWilliams, R. S.

2017-04-01

The laser-heated diamond anvil cell is widely used in the laboratory study of materials behavior at high-pressure and high-temperature, including melting curves and liquid properties at extreme conditions. Laser heating in the diamond cell has long been associated with fluid-like motion in samples, which is routinely used to determine melting points and is often described as convective in appearance. However, the flow behavior of this system is poorly understood. A quantitative treatment of melting and flow in the laser-heated diamond anvil cell is developed here to physically relate experimental motion to properties of interest, including melting points and viscosity. Numerical finite-element models are used to characterize the temperature distribution, melting, buoyancy, and resulting natural convection in samples. We find that continuous fluid motion in experiments can be explained most readily by natural convection. Fluid velocities, peaking near values of microns per second for plausible viscosities, are sufficiently fast to be detected experimentally, lending support to the use of convective motion as a criterion for melting. Convection depends on the physical properties of the melt and the sample geometry and is too sluggish to detect for viscosities significantly above that of water at ambient conditions, implying an upper bound on the melt viscosity of about 1 mPa s when convective motion is detected. A simple analytical relationship between melt viscosity and velocity suggests that direct viscosity measurements can be made from flow speeds, given the basic thermodynamic and geometric parameters of samples are known.

Multiple Experimental Efforts to Understand the Structure and Dynamics of Earth's Core

NASA Astrophysics Data System (ADS)

Fei, Y.; Han, L.; Bennett, N.; Hou, M.; Kuwayama, Y.; Huang, H.

2014-12-01

It requires integration of data from different types of high-pressure experiments to understand the structure and dynamics of Earth's core. In particular, measurements of physical properties and element partitioning in systems relevant to the core provide complementary data to narrow down the range of possible core compositions. We have performed both static and dynamic compression experiments and combined results from these with literature data to establish a reliable thermal equation of state of iron. This allows us to precisely determine the density deficit in the solid inner core. The combination of density and sound velocity measurements for both solid and liquid iron and its alloys provide tight constraints on the density deficit in the liquid outer core and the amount of sulphur required to match the geophysical observations. We then conducted element-partitioning experiments between solid and liquid iron in both multi-anvil apparatus and the laser-heated diamond-anvil cell to determine the sulphur, silicon, and oxygen partitioning between the liquid outer core and solid inner core. We present newly developed high-pressure experimental and nano-scale analytical techniques that allow us to simulate the conditions of the inner core boundary (ICB) and analyze the chemical compositions of coexisting phases in the recovered samples. We have established protocols to obtain high-quality partitioning data in the laser-heating diamond-anvil cell combined with FIB/SEM crossbeam technology. The partitioning data obtained up to at least 200 GPa provide additional criteria to explain the observed density and velocity jumps at the ICB.

Metal-Silicate Partitioning of Various Siderophile Elements at High Pressure and High Temperatures: a Diamond Anvil Cell Study

NASA Astrophysics Data System (ADS)

Badro, J.; Blanchard, I.; Siebert, J.

2015-12-01

Core formation is the major chemical fractionation that occurred on Earth. This event is widely believed to have happened at pressures of at least 40 GPa and temperatures exceeding 3000 K. It has left a significant imprint on the chemistry of the mantle by removing most of the siderophile (iron-loving) elements from it. Abundances of most siderophile elements in the bulk silicate Earth are significantly different than those predicted from experiments at low P-T. Among them, vanadium, chromium, cobalt and gallium are four siderophile elements which abundances in the mantle have been marked by core formation processes. Thus, understand their respective abundance in the mantle can help bringing constraints on the conditions of Earth's differentiation. We performed high-pressure high-temperature experiments using laser heating diamond anvil cell to investigate the metal-silicate partitioning of those four elements. Homogeneous glasses doped in vanadium, chromium, cobalt and gallium were synthesized using a levitation furnace and load inside the diamond anvil cell along with metallic powder. Samples were recovered using a Focused Ion Beam and chemically analyzed using an electron microprobe. We investigate the effect of pressure, temperature and metal composition on the metal-silicate partitioning of V, Cr, Co and Ga. Three previous studies focused on V, Cr and Co partitioning at those conditions of pressure and temperature, but none explore gallium partitioning at the relevant extreme conditions of core formation. We will present the first measurements of gallium metal-silicate partitioning performed at the appropriate conditions of pressure and temperature of Earth's differentiation.

Measuring the structure factor of simple fluids under extreme conditions

NASA Astrophysics Data System (ADS)

Weck, Gunnar

2013-06-01

The structure and dynamics of fluids, although a long standing matter of investigations, is still far from being well established. In particular, with the existence of a first order liquid-liquid phase transition (LLT) discovered in liquid phosphorus at 0.9 GPa and 1300 K it is now recognized that the fluid state could present complex structural changes. At present, very few examples of LLTs have been clearly evidenced, which may mean that a larger range of densities must be probed. First order transitions between a molecular and a polymeric liquid have been recently predicted by first principles calculations in liquid nitrogen at 88 GPa and 2000 K and in liquid CO2 at 45 GPa and 1850 K. The only device capable of reaching these extreme conditions is the diamond anvil cell (DAC), in which, the sample is sandwiched between two diamond anvils of thickness 100 times larger. Consequently, the diffracted signal from the sample is very weak compared to the Compton signal of the anvils, and becomes hardly measurable for pressures above ~20 GPa. A similar problem has been faced by the high pressure community using large volume press so as to drastically reduce the x-ray background from the sample environment. In the angle-dispersive diffraction configuration, it was proposed to use a multichannel collimator (MCC). This solution has been implemented to fit the constraints of the Paris-Edimburg (PE) large volume press and it is now routinely used on beamline ID27 of the European Synchrotron Radiation Facility. In this contribution, we present our adaptation of the MCC device accessible at ID27 for the DAC experiment. Because of the small sample volume a careful alignment procedure between the MCC slits and the DAC had to be implemented. The data analysis procedure initially developed by Eggert et al. has also been completed in order to take into account the complex contribution of the MCC slits. A large reduction of the Compton diffusion from the diamond anvils is obtained enabling quantitative structure factor measurement, even for the weakest x-ray scatterer liquid. Experimental results on fluid hydrogen will be presented to test the limits of this new setup. In collaboration with Gaston Garbarino, ESRF, France; Frederic Datchi, Sandra Ninet, Université Pierre et Marie Curie-Paris VI, France; Dylan Spaulding, Paul Loubeyre, CEA, DAM, DIF, France; and Mohamed Mezouar, ESRF, France.

Shear Deformation of Fe Polycrystals in the Rotational Diamond Anvil Cell

NASA Astrophysics Data System (ADS)

Merkel, S.; Lincot, A.; Nisr, C.; Hanfland, M.; Zerr, A.

2014-12-01

For many years, experiments are being developed for performing deformation experiments under lower mantle conditions. They include methods such as the Deformation-DIA (Wang et al, 2003) or radial x-ray diffraction in the diamond anvil cell (Merkel et al, 2002). However, the strain applied to the sample is typically limited to about 40%. This can be an issue for studying effects of large deformation or, for the case of diamond anvil cells, applying actual plastic strain at megabar pressures. The issue can be solved using apparatus such as the Rotational-Drickamer (RDA) (e.g. Yamazaki and Karato, 2001). However, the RDA offers limited diffraction access to the sample and operating pressures do not reach those of the lower mantle.In this abstract, we investigate the potential applications of the rotational diamond anvil cell (Rot-DAC) for such studies. 300 K experiments in the Rot-DAC have been performed up to pressures exceeding 50 GPa (e.g. Serebryanaya et al, 1995) with studies focusing on the effect of shear on solid-solid phase transformation pressures. The authors did not investigate the possibility of using the Rot-DAC for studying rheological properties.Here, a sample of polycrystalline Fe is submitted to shear deformation in the Rot-DAC at pressures up to 20 GPa. Synchrotron X-ray diffraction and Rietveld refinements are then used to study the texture and stress state at multiple locations in the sample. The study shows that the Rot-DAC is efficient at producing deformation textures in a polycrystalline aggregate but that care should be taken in ensuring that the sample is actually undergoing plastic deformation and not solid rotation. Stresses, on the other hand, are difficult to extract from the x-ray diffraction data because of lack of understanding of stress distributions in the deforming aggregate.S. Merkel, H. R. Wenk, J. Shu, G. Shen, P. Gillet, H. K. Mao and R. J. Hemley, J. Geophys. Res., 107, 2271 (2002)N. Serebryanaya, V. Blank and V. Ivdenko, Phys. Lett. A, 197, 63-66 (1995)Y. Wang, W. B. Duhram, I. C. Getting and D. J. Weidner, Rev. Sci. Instrum., 74, 3002-3011 (2003)D. Yamazaki and S.-I. Karato, Rev. Sci. Instrum., 72, 4207-4211 (2001)

A con-focal setup for micro-XRF experiments using diamond anvil cells

NASA Astrophysics Data System (ADS)

Wilke, Max; Rickers, Karen; Vincze, Laszlo; Schmidt, Christian; Borchert, Manuela; Pascarelli, Sakura

2010-05-01

In this contribution we introduce an experimental setup to perform con-focal micro X-ray fluorescence measurements in situ in samples at high temperatures and pressures in diamond anvil cells (DAC) (e.g. Schmidt et al. 2007). The con-focal arrangement is used to suppress the background in X-ray fluorescence (XRF) spectra that stems from elastic and inelastic scattering of the diamond anvils. The setup is based on a focusing optic in the incident beam that reaches a spot of 5-10 μm and a focusing poly-capillary in front of an energy-dispersive solid-state detector. The detector poly-capillary is designed to work at a very long working distance of 50 mm in order to collect the radiation from the center of the DAC at 90° to the incident beam. The probing volume is defined by the two foci and has a size of ca. 300 μm at 8 keV and 150 μm at 19 keV as measured by scans through thin metal foils. Comparison of XRF spectra acquired with a usual detector collimator and spectra recorded with the detector capillary shows a strong suppression of XRF signal generated outside the probed volume, i.e. XRF from the gasket material and signal from elastic and Compton scattering by the diamond anvils. The ratio of the Zr K-alpha fluorescence peak to the peak of the Compton scattering changes from 0.5 (collimator) to 1.26 (detector capillary) for a ca. 1000 ppm Zr standard solution and an incident beam energy of 20 keV. For a standard solution containing ca. 1000 ppm Hf, the ratio of the L-alpha to the Compton signal increases to 6 using the detector capillary and an incident beam energy of 9.7 keV. Thus, the con-focal setup substantially improves the fluorescence to background ratio. This will result in higher sensitivities for dilute elements in the sample chamber of the DAC. Furthermore, the possibilities of interference of the sample's signal with signal from the sample environment are greatly reduced. In a broader sense, the setup can also be applied to other confined samples that require long working distances. Schmidt et al. (2007) Lithos 95, 87-102

Novel Techniques for High Pressure Falling Sphere Viscosimetry under Simulated Earth's Mantle Conditions

NASA Astrophysics Data System (ADS)

Mueller, H. J.; Beckmann, F.; Dobson, D. P.; Hunt, S. A.; Secco, R.; Lauterjung, J.; Lathe, C.

2014-12-01

Viscosity data of melts measured under in situ high pressure conditions are crucial for the understanding of Earth's lower mantle and the interior of terrestrial and extrasolar Super-Earth planets. We report recent technical advances and techniques enabling falling sphere viscosity measurements in single- and double-stage DIA-type multi-anvil apparatus. For the experiments we used presses with a maximum load of 250 tons and 1750 tons. We anticipate that our system will enable viscosity measurements up to the maximum pressure for non-diamond anvils, i.e. pressures up to some 30 GPa. For the development of the new set ups the deformation of the cell assemblies were analyzed by X-ray absorption tomography at beamline W II at DESY/HASYLAB after the high pressure runs. These analysis gave considerable insights into strategies for improving the cell assembly with the result that the optimized assemblies could be used at much higher pressures without blow-outs. We think this approach is much faster and more beneficial than the classical way of trial and error. Additionally to prevent high pressure blow outs the task was to make the whole melting chamber accessible for the high pressure X-radiography system up to the maximum pressures. This way the accuracy and reliability of the measurements can be improved. For this goal we used X-ray transparent cBN-anvils at the single-stage DIA large volume press. Because this material is recently not available for the cube size of 32 mm this aproach did not work for the double-stage DIA. As a very useful and economical alternative we used slotted carbide anvils filled with fired pyrophyllite bars. To improve the frame quality of the platinum spheres taken by the CCD-camera the energy of the monochromatic X-rays had to be increased to 100 keV. The resulting ascent of scattered radiation required a new design of the X-radiography unit. Our results are demonstrated with viscosity measurements following Stokes law by evaluation of X-radiography sequences taken by a CCD-camera at pressures of 5 GPa as well as 10 GPa and temperatures of 1890 K. As the first result we could increase the maximum pressure range of published viscosity measurements with dacite melts by almost factor 1.5 (see Tinker et al., 2004).

Wind-fuel cell hybrid project in rural Alaska

DOE Office of Scientific and Technical Information (OSTI.GOV)

David Lockard

2000-02-18

This is a summary of the work performed on the Wind-Fuel Cell Hybrid Project: (1) On October 5th, Tim Howell of the Golden Field Office and Tom Anderson of Battelle Labs arrived in Anchorage. They met with David Lockard, Project Manager, and Percy Frisby, Director of the Alaska Rural Energy Programs Group. (2) On October 6th, Tim, Tom and David flew to Nome to inspect the proposed wind turbine site and meet with John Handeland, Director of the Nome Joint Utility System. They visited the proposed site as well as several private, residential-sized wind turbines operating in the Nome area.more » (3)Tim and Tom flew to Unalaska on October 7th to meet with Mike Golat, City of Unalaska Public Utility Director, and to inspect the proposed wind turbine sites at Pyramid Creek and Pyramid Valley. (4)Tim sent a scoping letter on December 17th to a variety of local, state and federal agencies requesting comments on the proposed wind turbine project. (5) David discussed this project with Marc Schwartz and Gerry Nix at NREL. Marc provided David with a list of wind prospectors and meteorologists. (6) Tom raised the question of FAA permits for structures over 200 feet tall. Gerry provided information on NREL's experience with FAA permitting on other projects. David summarized the potential turbine choices and heights in a spreadsheet and initiated contact with the Alaska region FAA office regarding the permitting process. (7) David responded to a list of design questions from Tom regarding the project foundations, power output, and size for use in developing the environmental assessment. (8) David tried to get wind data for the Nome Anvil Mountain White Alice site from the Corps of Engineers and the Air Force, but was not able to find any. (9) David solicited quotes from vendors of wind monitoring equipment and provided cost information to Doug Hooker, federal grant manager in preparation for ordering the equipment.« less

Tunable Quantum Dot Solids: Impact of Interparticle Interactions on Bulk Properties

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sinclair, Michael B.; Fan, Hongyou; Brener, Igal

2015-09-01

QD-solids comprising self-assembled semiconductor nanocrystals such as CdSe are currently under investigation for use in a wide array of applications including light emitting diodes, solar cells, field effect transistors, photodetectors, and biosensors. The goal of this LDRD project was develop a fundamental understanding of the relationship between nanoparticle interactions and the different regimes of charge and energy transport in semiconductor quantum dot (QD) solids. Interparticle spacing was tuned through the application of hydrostatic pressure in a diamond anvil cell, and the impact on interparticle interactions was probed using x-ray scattering and a variety of static and transient optical spectroscopies. Duringmore » the course of this LDRD, we discovered a new, previously unknown, route to synthesize semiconductor quantum wires using high pressure sintering of self-assembled quantum dot crystals. We believe that this new, pressure driven synthesis approach holds great potential as a new tool for nanomaterials synthesis and engineering.« less

Anvil Mountain Site, Silverton CO: Technical Memorandum - Energy Efficiency for Affordable Housing at a Brownfield Redevelopment

EPA Pesticide Factsheets

This document illustrates how the U.S. Environmental Protection Agency (EPA) Brownfields Program empowers states, communities, and other stakeholders to work together to prevent, assess, safely clean up, and sustainably reuse brownfields.

Improved Point Analysis Model (IPAM) (Users Guide)

DTIC Science & Technology

1991-02-01

Descriptions 7 Stratus fractus of bad weather* or Cumulus fractus of bad weather, or both ( pannus ), usually below Altostratus or Nimbostratus. 8...Cumulonimbus without anvil or fibrous upper part, Cumulus, Stratocumulus, Stratus or pannus . / Stratocumulus, Stratus, Cumulus and Cumulonimbus invisible owing

High Pressure Single Crystal Diffraction at PX 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Dongzhou; Dera, Przemyslaw K.; Eng, Peter J.

2017-01-01

In this report, we describe detailed procedures for carrying out single crystal X-ray diffraction experiments with a diamond anvil cell at the GSECARS 13-BM-C beamline at the Advanced Photon Source. ATREX and RSV programs are used to analyze the data.

A New Technique for In Situ X-ray Microtomography Under High Pressure

NASA Astrophysics Data System (ADS)

Uchida, T.; Wang, Y.; Westferro, F.; Gebhardt, J.; Rivers, M. L.; Sutton, S. R.

2004-12-01

We have developed a new technique for in situ synchrotron microtomography to study texture evolution in multi-phase specimens under high pressure and temperature. Two critical issues in performing tomography experiments under pressure are (1) the limited X-ray access to the sample because of the highly absorbing materials, such as tungsten carbide and tool steel, typically used in the pressure vessel and (2) a high pressure compatible rotation mechanism to collect projections of the sample continuously from 0 to 180° . We addressed these issues by (1) employing an opposed-anvil high pressure cell, known as the Drickamer cell, with an X-ray transparent containment ring, to allow panoramic X-ray access, and (2) rotating the Dricakmer cell by Harmonic DriveTM gear reducers, with thrust bearings supporting the hydraulic load. The design of the rotation mechanism benefited from the rotational deformation apparatus developed by Yamazaki and Karato (Rev. Sci. Instrum., 72, 4207, 2001). We report results obtained from a test run performed under pressure with monochromatic synchrotron radiation. A sapphire sphere (1.0 mm dia.) was embedded in a powdered mixture of Fe and 9 wt.% S alloy. The diameter of the sample chamber was 2 mm. Under pressure, the entire Drickamer cell was rotated to collect radiographs of the sample at various angles from 0 to 179.5° in 0.5° step size. Computational reconstruction of these projections provided three dimensional (3D) distribution of linear attenuation coefficient of the sample with a spatial resolution of 6 microns. The shape change in the sapphire sphere during compression was clearly observed. Using the program Blob3d, reconstructed 3D images of the sphere were separated from the surrounding Fe-S alloy. Volumes of the sphere were then accurately determined from the extracted images, by carefully defining the image intensity threshold. The errors in the volume measurement are about 0.3 to 0.7%, mostly due to shadowing by anvil deformation. The results, although performed using a solid sample, demonstrate the potential of measuring melt volume. Previous density measurements using X-ray radiography with only one dimensional data assumed that the shape of the sample remained unchanged throughout the experiment. In our new technique, this assumption is no longer required and density of melts can be inferred directly from the sample volume even when the molten sample is distorted. Other applications of this apparatus will be also discussed.

High-pressure studies with x-rays using diamond anvil cells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shen, Guoyin; Mao, Ho Kwang

2016-11-22

Pressure profoundly alters all states of matter. The symbiotic development of ultrahigh-pressure diamond anvil cells, to compress samples to sustainable multi-megabar pressures; and synchrotron x-ray techniques, to probe materials' properties in situ, has enabled the exploration of rich high-pressure (HP) science. In this article, we first introduce the essential concept of diamond anvil cell technology, together with recent developments and its integration with other extreme environments. We then provide an overview of the latest developments in HP synchrotron techniques, their applications, and current problems, followed by a discussion of HP scientific studies using x-rays in the key multidisciplinary fields. Thesemore » HP studies include: HP x-ray emission spectroscopy, which provides information on the filled electronic states of HP samples; HP x-ray Raman spectroscopy, which probes the HP chemical bonding changes of light elements; HP electronic inelastic x-ray scattering spectroscopy, which accesses high energy electronic phenomena, including electronic band structure, Fermi surface, excitons, plasmons, and their dispersions; HP resonant inelastic x-ray scattering spectroscopy, which probes shallow core excitations, multiplet structures, and spin-resolved electronic structure; HP nuclear resonant x-ray spectroscopy, which provides phonon densities of state and time-resolved Mössbauer information; HP x-ray imaging, which provides information on hierarchical structures, dynamic processes, and internal strains; HP x-ray diffraction, which determines the fundamental structures and densities of single-crystal, polycrystalline, nanocrystalline, and non-crystalline materials; and HP radial x-ray diffraction, which yields deviatoric, elastic and rheological information. Integrating these tools with hydrostatic or uniaxial pressure media, laser and resistive heating, and cryogenic cooling, has enabled investigations of the structural, vibrational, electronic, and magnetic properties of materials over a wide range of pressure-temperature conditions.« less

Parameterization of the Vertical Variability of Tropical Cirrus Cloud Microphysical and Optical Properties

NASA Technical Reports Server (NTRS)

Gerber, Hermann E.

2004-01-01

Cloud Integrating Nephelometers (CIN) were flown on the U. North Dakota Citation aircraft and the NASA WB-57 aircraft for the purpose of measuring in-situ the optical extinction coefficient and the asymmetry parameter (g) at a wavelength of 635 nm of primarily ice particles encountered during the NASA CRYSTAL-FACE study of large cumulus clouds (Cu) and their anvils found in the southern Florida region. The probes performance was largely successful and produced archived data for vertical profiles of extinction, asymmetry parameter, and effective radius (Re), the latter being obtained by combining CIN and CVI (total water; Oregon State U.) measurements. Composites of the CIN and CVI data describing the average microphysical and optical behavior of the Cu and their anvils showed the following: The extinction increases with height as a result of the size of the particles also decreasing with height as shown by the Re measurements; near the top of anvils the size of the primary ice particles is about 10-um radius; and the value of g does not vary significantly with height and has a mean value of about 0.73 consistent with the idea that ambient ice crystals are primarily of complex shape and reflect solar radiation more efficiently than particles of pristine crystal shape. Other observations include: The g measurements were found to be an indicator of the phase of the cloud permitting identification of the clouds with water droplets, rain, and ice; visual ranges as small as several tens of meters were occasionally found in "extinction cores" that coincided with strong updraft cores; and comparison of the cloud probes on the Citation showed significant disagreement.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gamboa, E. J.; Fletcher, L. B.; Lee, H. J.

The extraordinary mechanical and optical properties of diamond are the basis of numerous technical applications and make diamond anvil cells a premier device to explore the high-pressure behavior of materials. However, at applied pressures above a few hundred GPa, optical probing through the anvils becomes difficult because of the pressure-induced changes of the transmission and the excitation of a strong optical emission. Such features have been interpreted as the onset of a closure of the optical gap in diamond, and can significantly impair spectroscopy of the material inside the cell. In contrast, a comparable widening has been predicted for purelymore » hydrostatic compressions, forming a basis for the presumed pressure stiffening of diamond and resilience to the eventual phase change to BC8. We here present the first experimental evidence of this effect at geo-planetary pressures, exceeding the highest ever reported hydrostatic compression of diamond by more than 200 GPa and any other measurement of the band gap by more than 350 GPa. We here apply laser driven-ablation to create a dynamic, high pressure state in a thin, synthetic diamond foil together with frequency-resolved x-ray scattering as a probe. The frequency shift of the inelastically scattered x-rays encodes the optical properties and, thus, the behavior of the band gap in the sample. Using the ultra-bright x-ray beam from the Linac Coherent Light Source (LCLS), we observe an increasing direct band gap in diamond up to a pressure of 370 GPa. This finding points to the enormous strains in the anvils and the impurities in natural Type Ia diamonds as the source of the observed closure of the optical window. Our results demonstrate that diamond remains an insulating solid to pressures approaching its limit strength.« less

Acoustic emissions imaging and synchrotron X-ray diffraction analysis of calcite at high pressure and temperature

NASA Astrophysics Data System (ADS)

Gasc, J.; Brantut, N.; Schubnel, A.; Brunet, F.; Mueller, H.

2008-12-01

We have monitored from in-situ X-ray diffraction coupled to Acoustic Emission (AE) imaging, the behavior of a fine grained synthetic calcite aggregate, at 0.66 GPa and for temperatures ranging from ambient to 1200° C. The powder sample was placed in a boron-epoxy assembly with an 8 mm edge-length and loaded in the MAX80 cubic multi-anvil press installed on the German synchrotron (HASYLAB-DESY, Hamburg). AE were recorded using five piezoceramic transducers (5 MHz eigen frequency) glued on each of the five WC anvils (4 side anvils and upper one). Full waveforms were acquired using an eight channel digital oscilloscope and located using the software Insite (ASC Ltd). Beyond 600° C, calcite grains started growing as evidenced by huge changes in the relative intensity of the diffraction lines. This is correlated to a sudden burst of AE which all located within the sample volume. These AE may indicate that stress relaxation, going on as intra-crystalline plasticity mechanisms were activated, released enough acoustic energy to be recorded and located. Although the diffraction data showed that grain growth continued beyond 800° C, the acoustic activity progressively decreased to below the sensitivity of our recording device (i.e. the triggering level). However, at temperature higher than 1000° C, a large number of AE were recorded again ( 2000 events). AE location revealed that the AE front progressed inwards the sample. The complete loss of diffraction signal and the post-mortem recovery of small amounts of CaO suggest that the second AE burst may be related to calcite melting/decarbonation. Perspectives include thorough microstructural analysis of the samples using electron microscopies (SEM and TEM) as well as a statistical and mechanical analysis of the acoustic data.

Cryo-Compression System in a 3000 Ton Multi-Anvil Press

NASA Astrophysics Data System (ADS)

Secco, R. A.; Yong, W.

2016-12-01

Most large volume high pressure devices are capable of high temperature experiments that are typically achieved by using localized resistive heating of a metal foil, graphite or ceramic sleeve inside a thermally insulated sample volume in a high pressure cell. Low temperatures at high pressures are needed for physical property studies of materials that comprise planetary bodies in the outer solar system. However, low temperatures are more difficult to achieve mainly because the massive steel components of the press, which are in good thermal contact with each other under high load, act as large heat reservoirs and pathways that encumber the removal of heat from the pressure cell. We describe a new custom-designed system under development for a 3000 ton multi-anvil press to reach temperatures below 295K at high pressures. The system was designed to remove heat selectively and conductively from the sample volume through six of the eight WC cubes in direct contact with the octahedral pressure cell. Cooling fins made of Cu are sandwiched between, and in thermal contact with, neighboring anvil faces and are each connected to a dedicated Cu heat exchanger chamber through which liquid nitrogen flows. The chamber internal geometry consists of either square pillars that double the internal surface area of the rectangular parallelepiped enclosed volume or continuous walls separated by valleys. Gas from each chamber is vented to the lab through an exhaust pipe. High pressure results will be presented of several temperature monitoring points in the center of the pressure cell and on the surfaces of the WC cubes and steel wedges which recorded the time-dependent cooling progress. Temperature stability tests will also be presented.

Thermal equation of state of CaFe 2O 4-type MgAl 2O 4

NASA Astrophysics Data System (ADS)

Sueda, Yuichiro; Irifune, Tetsuo; Sanehira, Takeshi; Yagi, Takehiko; Nishiyama, Norimasa; Kikegawa, Takumi; Funakoshi, Ken-ichi

2009-05-01

In situ X-ray diffraction measurements of CaFe 2O 4-type MgAl 2O 4 have been conducted at pressures up to 42 GPa and temperatures to 2400 K using Kawai-type multianvil apparatus with sintered diamond anvils. Additional measurements have also been conducted at pressures to 12 GPa using diamond anvil cell with helium as a pressure medium at room temperature, and at temperatures to 836 K at the ambient pressure using a high-temperature X-ray diffractometer. The analysis of room-temperature data yielded V0 = 240.1(2) Å 3, K0 = 205(6) GPa, and K0=4.1(3). A fit of the present data to high-temperature Birch-Murnaghan equation of state (EOS) yielded (∂ K0/∂ T) P = -0.030(2) GPa/K and α0 = a0 + b0T with values of a0 = 1.96(13) × 10 -5 K -1 and b0 = 1.64(24) × 10 -8 K -2. The present data set was also fitted to Mie-Grüneisen-Debye (MGD) EOS and we obtained γ0 = 1.73(7), q = 2.03(37), and θ0 = 1546(104) K. Density changes of MORB have been estimated using the newly obtained thermoelastic parameters, assuming that the Al-rich phase in this composition possesses the CaFe 2O 4-type structure under the lower mantle P, T conditions. The calculated densities along geotherms for the normal mantle and subducting cold slabs are both significantly higher than those of typical seismological models, confirming the conclusion of some recent results on MORB by laser-heated diamond anvil cell experiments.

High-pressure studies with x-rays using diamond anvil cells

NASA Astrophysics Data System (ADS)

Shen, Guoyin; Mao, Ho Kwang

2017-01-01

Pressure profoundly alters all states of matter. The symbiotic development of ultrahigh-pressure diamond anvil cells, to compress samples to sustainable multi-megabar pressures; and synchrotron x-ray techniques, to probe materials’ properties in situ, has enabled the exploration of rich high-pressure (HP) science. In this article, we first introduce the essential concept of diamond anvil cell technology, together with recent developments and its integration with other extreme environments. We then provide an overview of the latest developments in HP synchrotron techniques, their applications, and current problems, followed by a discussion of HP scientific studies using x-rays in the key multidisciplinary fields. These HP studies include: HP x-ray emission spectroscopy, which provides information on the filled electronic states of HP samples; HP x-ray Raman spectroscopy, which probes the HP chemical bonding changes of light elements; HP electronic inelastic x-ray scattering spectroscopy, which accesses high energy electronic phenomena, including electronic band structure, Fermi surface, excitons, plasmons, and their dispersions; HP resonant inelastic x-ray scattering spectroscopy, which probes shallow core excitations, multiplet structures, and spin-resolved electronic structure; HP nuclear resonant x-ray spectroscopy, which provides phonon densities of state and time-resolved Mössbauer information; HP x-ray imaging, which provides information on hierarchical structures, dynamic processes, and internal strains; HP x-ray diffraction, which determines the fundamental structures and densities of single-crystal, polycrystalline, nanocrystalline, and non-crystalline materials; and HP radial x-ray diffraction, which yields deviatoric, elastic and rheological information. Integrating these tools with hydrostatic or uniaxial pressure media, laser and resistive heating, and cryogenic cooling, has enabled investigations of the structural, vibrational, electronic, and magnetic properties of materials over a wide range of pressure-temperature conditions.

Improving Satellite Quantitative Precipitation Estimation Using GOES-Retrieved Cloud Optical Depth

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stenz, Ronald; Dong, Xiquan; Xi, Baike

To address significant gaps in ground-based radar coverage and rain gauge networks in the U.S., geostationary satellite quantitative precipitation estimates (QPEs) such as the Self-Calibrating Multivariate Precipitation Retrievals (SCaMPR) can be used to fill in both the spatial and temporal gaps of ground-based measurements. Additionally, with the launch of GOES-R, the temporal resolution of satellite QPEs may be comparable to that of Weather Service Radar-1988 Doppler (WSR-88D) volume scans as GOES images will be available every five minutes. However, while satellite QPEs have strengths in spatial coverage and temporal resolution, they face limitations particularly during convective events. Deep Convective Systemsmore » (DCSs) have large cloud shields with similar brightness temperatures (BTs) over nearly the entire system, but widely varying precipitation rates beneath these clouds. Geostationary satellite QPEs relying on the indirect relationship between BTs and precipitation rates often suffer from large errors because anvil regions (little/no precipitation) cannot be distinguished from rain-cores (heavy precipitation) using only BTs. However, a combination of BTs and optical depth (τ) has been found to reduce overestimates of precipitation in anvil regions (Stenz et al. 2014). A new rain mask algorithm incorporating both τ and BTs has been developed, and its application to the existing SCaMPR algorithm was evaluated. The performance of the modified SCaMPR was evaluated using traditional skill scores and a more detailed analysis of performance in individual DCS components by utilizing the Feng et al. (2012) classification algorithm. SCaMPR estimates with the new rain mask applied benefited from significantly reduced overestimates of precipitation in anvil regions and overall improvements in skill scores.« less

Density Measurement for MORB Melts by X-ray Absorption Method

NASA Astrophysics Data System (ADS)

Sakamaki, T.; Urakawa, S.; Suzuki, A.; Ohtani, E.; Katayama, Y.

2006-12-01

Density of silicate melts at high pressure is one of the most important properties to understand magma migration in the planetary interior and the differentiation of the terrestrial planets. The density measurements of silicate melts have been carried out by several methods (shock compression experiments and sink-float method in static experiments, etc.). However, since these methods have difficulties in acquisition of data at a desired pressure and temperature, the density of the silicate melt have been measured under only a few conditions. Recently a new density measurement was developed by the X-ray absorption method. Advantage of this method is to measure density of liquids at a desired pressure and temperature. In the present study we measured the density of MORB melt by X-ray absorption method. Experiments were carried out at the BL22XU beamline at SPring-8. A DIA-type cubic anvil apparatus was used for generation of high pressure and temperature. We used tungsten carbide anvils with the top anvil sizes of 6 mm and 4 mm. The energy of monochromateized X-ray beam was 23 keV. The intensities of incident and transmitted X-ray were measured by ion chambers. The density of the melt was calculated on the basis of Beer-Lambert law. The starting material was a glass with the MORB composition. Experiments were made from 1 atm to 5 GPa, from 300 to 2000 K. We compared the density of MORB melt with the compression curve of the melt in previous works. The density measured by this study is lower than that expected from the compression curve determined at higher pressures by the sink-float method. Structural change of the MORB melt with increasing pressure might be attributed to this discrepancy.

The laser micro-machining system for diamond anvil cell experiments and general precision machining applications at the High Pressure Collaborative Access Team

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hrubiak, Rostislav; Sinogeikin, Stanislav; Rod, Eric

We have designed and constructed a new system for micro-machining parts and sample assemblies used for diamond anvil cells and general user operations at the High Pressure Collaborative Access Team, sector 16 of the Advanced Photon Source. The new micro-machining system uses a pulsed laser of 400 ps pulse duration, ablating various materials without thermal melting, thus leaving a clean edge. With optics designed for a tight focus, the system can machine holes any size larger than 3 μm in diameter. Unlike a standard electrical discharge machining drill, the new laser system allows micro-machining of non-conductive materials such as: amorphousmore » boron and silicon carbide gaskets, diamond, oxides, and other materials including organic materials such as polyimide films (i.e., Kapton). An important feature of the new system is the use of gas-tight or gas-flow environmental chambers which allow the laser micro-machining to be done in a controlled (e.g., inert gas) atmosphere to prevent oxidation and other chemical reactions in air sensitive materials. The gas-tight workpiece enclosure is also useful for machining materials with known health risks (e.g., beryllium). Specialized control software with a graphical interface enables micro-machining of custom 2D and 3D shapes. The laser-machining system was designed in a Class 1 laser enclosure, i.e., it includes laser safety interlocks and computer controls and allows for routine operation. Though initially designed mainly for machining of the diamond anvil cell gaskets, the laser-machining system has since found many other micro-machining applications, several of which are presented here.« less

Community Extreme Tonnage User Service (CETUS): A 5000 Ton Open Research Facility in the United States

NASA Technical Reports Server (NTRS)

Danielson, L.; Righter, K.; McCubbin, F.

2016-01-01

Large sample volume 5000 ton multi-anvil presses have contributed to the exploration of deep Earth and planetary interiors, synthesis of ultra-hard and other novel materials, and serve as a sample complement to pressure and temperature regimes already attainable by diamond anvil cell experiments. However, no such facility exists on the North American continent. We propose the establishment of an open user facility for COMPRES members and the entire research community, with the unique capability of a 5000 ton (or more) press, supported by a host of extant co-located experimental and analytical laboratories and research staff. We offer wide range of complementary and/or preparatory experimental options. Any required synthesis of materials or follow up experiments can be carried out controlled atmosphere furnaces, piston cylinders, multi-anvil, or experimental impact apparatus. Additionally, our division houses two machine shops that would facilitate any modification or custom work necessary for development of CETUS, one for general fabrication and one located specifically within our experimental facilities. We also have a general sample preparation laboratory, specifically for experimental samples, that allows users to quickly and easily prepare samples for ebeam analyses and more. A service we can offer to COMPRES community members in general, and CETUS visiting users specifically, is a multitude of analytical instrumentation literally steps away from the experimental laboratories. This year we will be pursuing site funding of our laboratories through NASA's Planetary Science Directorate, which should result in substantial cost savings to all visiting users, and supports our mission of interagency cooperation for the enhancement of science for all (see companion PSAMS abstract). The PI is in a unique position as an employee of Jacobs Technology to draw funding from multiple sources, including those from industry and commerce. We submitted a Planetary Major Equipment proposal to the NASA Emerging Worlds solicitation for the full cost of a press, with competitive bids submitted from Sumitomo, Rockland Research, and Voggenreiter. Additional funding is currently being sought from industry sources through the Strategic Partnerships Office at NASA JSC, External Pursuits Program Office on the JETS contract, and Jacobs corporate in the United States. Internal funding is available for JETS contract personnel to travel to large press locations worldwide to study set-up and operations. We also anticipate a fortuitous cost savings in installation of the large press because plans are already underway for major renovations to the entire experimental petrology suite within the next 2 years in order to accommodate our growing user base. Our focus as contract staff is on serving the scientific needs of our users and collaborators. We are seeking community expert input on multiple aspects of this proposed facility, such as the press type and design, access management, immediate projects, and future innovation initiatives.

Semiconducting cubic titanium nitride in the Th 3 P 4 structure

DOE PAGES

Bhadram, Venkata S.; Liu, Hanyu; Xu, Enshi; ...

2018-01-22

We report the discovery of a long-sought-after phase of titanium nitride with stoichiometry Ti3N4 using diamond anvil cell experiments combined with in situ high-resolution x-ray diffraction and Raman spectroscopy techniques, supported by ab initio calculations.

Impact initiation of reactive aluminized fluorinated acrylic nanocomposites

DOE PAGES

White, Bradley W.; Crouse, Christopher A.; Spowart, Jonathan E.; ...

2016-04-18

The initiation of aluminized fluorinated acrylic (AlFA) nanocomposites during modified Taylor impact tests was investigated. Samples were impacted against a steel or sapphire anvil at a nominal velocity of 150 m/s. A framing camera was used to capture head-on and side-profile impact images for the sapphire window and steel plate rigid anvils, respectively. Correlations were drawn between both experimental setups to determine the initiation locations and reaction times. Reactions were found to initiate at an intermediate radius on the impact face of the pellet at a time near full compaction. From simulations, the highest strains and temperatures were found atmore » radii similar to those observed in experiments at the time of ignition. Off-normal impacts produced higher localized straining and temperatures on one-half of the pellet. As a result, the copper projectile, used for delivery, was revealed to aid in a shear assisted reaction by helping to drive the pellet material outward as the projectile deformed radially.« less

On the Magnitude of the Electric Field Near Thunderstorm-Associated Clouds

NASA Technical Reports Server (NTRS)

Merceret, Francis J.; Ward, Jennifer G.; Mach, Douglas M.; Bateman, Monte G.; Dye, James E.

2007-01-01

Electric field measurements made in and near clouds during two airborne field mill programs are presented. Aircraft equipped with multiple electric field mills and cloud physics sensors were flown near active convection and into thunderstorm anvil and debris clouds. The magnitude of the electric field was measured as a function of position with respect to the cloud edge in order to provide an observational basis for modifications to the lightning launch commit criteria (LLCC) used by the U.S. space program. These LLCC are used to reduce the risk that an ascending launch vehicle will trigger a lightning strike that could cause the loss of the mission or vehicle. The results suggest that even with fields of tens of kV/m inside electrically active convective clouds, the fields external to these clouds decay to less than 3 kV/m within fifteen kilometers of cloud edge. Fields exceeding 3 kV/m were not found external to anvil and debris clouds.

Homogeneous Aerosol Freezing in the Tops of High-Altitude Tropical Cumulonimbus Clouds

NASA Technical Reports Server (NTRS)

Jensen, E. J.; Ackerman, A. S.

2006-01-01

Numerical simulations of deep, intense continental tropical convection indicate that when the cloud tops extend more than a few kilometers above the liquid water homogeneous freezing level, ice nucleation due to freezing of entrained aqueous sulfate aerosols generates large concentrations of small crystals (diameters less than approx. equal to 20 micrometers). The small crystals produced by aerosol freezing have the largest impact on cloud-top ice concentration for convective clouds with strong updrafts but relatively low aerosol concentrations. An implication of this result is that cloud-top ice concentrations in high anvil cirrus can be controlled primarily by updraft speeds in the tops of convective plumes and to a lesser extent by aerosol concentrations in the uppermost troposphere. While larger crystals precipitate out and sublimate in subsaturated air below, the population of small crystals can persist in the saturated uppermost troposphere for many hours, thereby prolonging the lifetime of remnants from anvil cirrus in the tropical tropopause layer.

Structural, optical and high pressure electrical resistivity studies of pure NiO and Cu-doped NiO nanoparticles

NASA Astrophysics Data System (ADS)

Marselin, M. Abila; Jaya, N. Victor

2016-04-01

In this paper, pure NiO and Cu-doped NiO nanoparticles are prepared by co-precipitation method. The electrical resistivity measurements by applying high pressure on pure NiO and Cu-doped NiO nanoparticles were reported. The Bridgman anvil set up is used to measure high pressures up to 8 GPa. These measurements show that there is no phase transformation in the samples till the high pressure is reached. The samples show a rapid decrease in electrical resistivity up to 5 GPa and it remains constant beyond 5 GPa. The electrical resistivity and the transport activation energy of the samples under high pressure up to 8 GPa have been studied in the temperature range of 273-433 K using diamond anvil cell. The temperature versus electrical resistivity studies reveal that the samples behave like a semiconductor. The activation energies of the charge carriers depend on the size of the samples.

Modified Cooling System for Low Temperature Experiments in a 3000 Ton Multi-Anvil Press

NASA Astrophysics Data System (ADS)

Secco, R.; Yong, W.

2017-12-01

A new modified cooling system for a 3000-ton multi-anvil press has been developed to reach temperatures below room temperature at high pressures. The new system is much simpler in design, easier to make and use, and has the same cooling capability as the previous design (Secco and Yong, RSI, 2016). The key component of the new system is a steel ring surrounding the module wedges that contains liquid nitrogen (LN2) which flows freely through an entrance port to flood the interior of the pressure module. Upper and lower O-rings on the ring seal in the liquid while permitting modest compression and an thermally insulating layer of foam is attached to the outside of the ring. The same temperature of 220 K reached with two different cooling systems suggests that thermal equilibrium is reached between the removal of heat by LN2 and the influx of heat through the massive steel components of this press.

Thermal conductance of metal–diamond interfaces at high pressure

DOE PAGES

Hohensee, Gregory T.; Wilson, R. B.; Cahill, David G.

2015-03-06

The thermal conductance of interfaces between metals and diamond, which has a comparatively high Debye temperature, is often greater than can be accounted for by two phonon-processes. The high pressures achievable in a diamond anvil cell can significantly extend the metal phonon density of states to higher frequencies, and can also suppress extrinsic effects by greatly stiffening interface bonding. Here we report time-domain thermoreflectance measurements of metal-diamond interface thermal conductance up to 50 GPa in the DAC for Pb, Au 0.95Pd 0.05, Pt, and Al films deposited on Type 1A natural [100] and Type 2A synthetic [110] diamond anvils. Inmore » all cases, the thermal conductances increase weakly or saturate to similar values at high pressure. Lastly, our results suggest that anharmonic conductance at metal-diamond interfaces is controlled by partial transmission processes, where a diamond phonon that inelastically scatters at the interface absorbs or emits a metal phonon.« less

Experimental Study of Grit Particle Enhancement in Non-Shock Ignition

NASA Astrophysics Data System (ADS)

Browning, Richard V.; Peterson, Paul D.; Roemer, Edward L.; Oldenborg, Michael R.; Thompson, Darla G.; Deluca, Racci

2006-07-01

The drop weight impact test is the most commonly used configuration for evaluating sensitivity of explosives to non-shock ignition. Although developed 60 years ago and widely used both as a material compression test and as a test bed for understanding the ignition process itself, little is known about the flow mechanisms or involvement of grit particles as sensitizing agents. In this paper, we present the results of a series of experiments designed to study the flow mechanisms and events leading up to ignition. The experimental configuration used involves two pellet sizes, 3 and 5 mm in diameter, tested with three conditions: (1) smooth steel anvils, (2) standard flint sandpaper, and (3) shed grit particles loaded between the steel anvils and the pellet faces. Diagnostics include optical micrographs, and scanning electron micrographs. Un-reacted samples show a variety of morphologies, including what appear to be quenched reaction sites, even at very low drop heights. Quasi-static crushing experiments were also done to quantify load-time histories.

Experimental Study of Grit Particle Enhancement in Non-Shock Ignition of PBX 9501

NASA Astrophysics Data System (ADS)

Peterson, Paul

2005-07-01

The drop weight impact test is the most commonly used configuration for evaluating sensitivity of explosives to non-shock ignition. Although developed 60 years ago and widely used both as a material compression test and as a test bed for understanding the ignition process itself, little is known about the flow mechanisms or involvement of grit particles as sensitizing agents. In this paper we present the results of a series of experiments designed to study the flow mechanisms and events leading up to ignition. The experimental configuration used involves two pellet sizes, 3 and 5 mm in diameter, tested in three conditions, (1) with smooth steel anvils, (2) with standard flint sandpaper, and (3) with shed grit particles loaded between the steel anvils and the pellet faces. Diagnostics include optical micrographs, and scanning electron micrographs. Un-reacted samples show a variety of morphologies, including what appear to be quenched reaction sites, even at very low drop heights. Quasi-static crushing experiments were also done to quantify load-time histories.

Dynamic behavior of reactive aluminum nanoparticle-fluorinated acrylic (AlFA) polymer composites

NASA Astrophysics Data System (ADS)

Crouse, Christopher A.; White, Brad; Spowart, Jonathan E.

2011-06-01

The dynamic behavior of aluminum nanoparticle-fluorinated acrylic (AlFA) composite materials has been explored under high strain rates. Cylindrical pellets of the AlFA composite materials were mounted onto copper sabots and impacted against a rigid anvil at velocities between 100 and 400 m/s utilizing a Taylor gas gun apparatus to achieve strain rates on the order of 104 /s. A framing camera was used to record the compaction and reaction events that occurred upon contact of the pellet with the anvil. Under both open air and vacuum environments the AlFA composites demonstrated high reactivity suggesting that the particles are primarily reacting with the fluorinated matrix. We hypothesize, based upon the compaction history of these materials, that reaction is initiated when the oxide shells on the aluminum nanoparticles are broken due an interparticle contact deformation process. We have investigated this hypothesis through altering the particle loading in the AlFA composites as well as impact velocities. This data and the corresponding trends will be presented in detail.

Anvil cell gasket design for high pressure nuclear magnetic resonance experiments beyond 30 GPa

DOE Office of Scientific and Technical Information (OSTI.GOV)

Meier, Thomas; Haase, Jürgen

2015-12-15

Nuclear magnetic resonance (NMR) experiments are reported at up to 30.5 GPa of pressure using radiofrequency (RF) micro-coils with anvil cell designs. These are the highest pressures ever reported with NMR, and are made possible through an improved gasket design based on nano-crystalline powders embedded in epoxy resin. Cubic boron-nitride (c-BN), corundum (α-Al{sub 2}O{sub 3}), or diamond based composites have been tested, also in NMR experiments. These composite gaskets lose about 1/2 of their initial height up to 30.5 GPa, allowing for larger sample quantities and preventing damages to the RF micro-coils compared to precipitation hardened CuBe gaskets. It ismore » shown that NMR shift and resolution are less affected by the composite gaskets as compared to the more magnetic CuBe. The sensitivity can be as high as at normal pressure. The new, inexpensive, and simple to engineer gaskets are thus superior for NMR experiments at high pressures.« less

An investigation of the detection of tornadic thunderstorms by observing storm top features using geosynchronous satellite imagery

NASA Technical Reports Server (NTRS)

Anderson, Charles E.

1991-01-01

The number of tornado outbreak cases studied in detail was increased from the original 8. Detailed ground and aerial studies were carried out of two outbreak cases of considerable importance. It was demonstrated that multiple regression was able to predict the tornadic potential of a given thunderstorm cell by its cirrus anvil plume characteristics. It was also shown that the plume outflow intensity and the deviation of the plume alignment from storm relative winds at anvil altitude could account for the variance in tornadic potential for a given cell ranging from 0.37 to 0.82 for linear to values near 0.9 for quadratic regression. Several predictors were used in various discriminant analysis models and in censored regression models to obtain forecasts of whether a cell is tornadic and how strong tornadic it could be potentially. The experiments were performed with the synoptic scale vertical shear in the horizontal wind and with synoptic scale surface vorticity in the proximity of the cell.

Explosive Compations of Intermetallic-Forming Powder Mixtures for Fabricating Structural Energetic Materials

NASA Astrophysics Data System (ADS)

Du, S. W.; Aydelotte, B.; Fondse, D.; Wei, C.-T.; Jiang, F.; Herbold, E.; Vecchio, K.; Meyers, M. A.; Thadhani, N. N.

2009-12-01

A double-tube implosion geometry is used to explosively shock consolidate intermetallic-forming Ni-Al, Ta-Al, Nb-Al, Mo-Al and W-Al powder mixtures for fabricating bulk structural energetic materials, with mechanical strength and ability to undergo impact-initiated exothermic reactions. The compacts are characterized based on uniformity of micro structure and degree of densification. Mechanical properties of the compacts are characterized over the strain-rate range of 10-3 to 104 s-1. The impact reactivity is determined using rod-on-anvil experiments, in which disk-shaped compacts mounted on a copper projectile, are impacted against a steel anvil in using a 7.62 mm gas gun. The impact reactivity of the various explosively-consolidated reactive powder mixture compacts is correlated with overall kinetic energy and impact stress to determine their influence on threshold for reaction initiation. The characteristics of the various compacts, their mechanical properties and impact-initiated chemical reactivity will be described in this paper.

Monthly Covariability of Amazonian Convective Cloud Properties and Radiative Diurnal Cycle

NASA Technical Reports Server (NTRS)

Dodson, J. Brant; Taylor, Patrick C.

2016-01-01

The diurnal cycle of convective clouds greatly influences the top-of-atmosphere radiative energy balance in convectively active regions of Earth, through both direct presence and the production of anvil and stratiform clouds. CloudSat and CERES data are used to further examine these connections by determining the sensitivity of monthly anomalies in the radiative diurnal cycle to monthly anomalies in multiple cloud variables. During months with positive anomalies in convective frequency, the longwave diurnal cycle is shifted and skewed earlier in the day by the increased longwave cloud forcing during the afternoon from mature deep convective cores and associated anvils. This is consistent with previous studies using reanalysis data to characterize anomalous convective instability. Contrary to this, months with positive anomalies in convective cloud top height (commonly associated with more intense convection) shifts the longwave diurnal cycle later in the day. The contrary results are likely an effect of the inverse relationships between cloud top height and frequency. The albedo diurnal cycle yields inconsistent results when using different cloud variables.

Bridge-indentation precracking of glass bars

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lue, J.L.; Scattergood, R.O.

1993-07-01

Bridge indentation precracking was first reported by Sadahiro et al., and has been used by a number of subsequent investigators. The procedure involves placing a half-penny starter crack, formed by Vickers indentation, at the center of the bottom surface of a rectangular bar specimen. The bar is loaded between pusher and anvil platens. The bridge span S produces tensile bending stress on the bottom surface of the bar, which contains the starter crack. With increasing load, the crack grows stably outward and inward, and at a certain load the crack will propagate unstably (pop-in) to a straight, through-section crack ofmore » length c. The method is very convenient for producing sharp, through-section precracks in ceramic bars without the need for saw cutting or fatigue cycling. However, the effects of bridge geometry and friction on the precracking results will be presented here which point to an important influence of the friction between the specimen and anvil platens.« less

Ionic Liquids as Quasihydrostatic Pressure Media for Diamond Anvil Cell Experiments

NASA Astrophysics Data System (ADS)

Mayorga, Sierra; Moldowan, Kaela; Dan, Ioana; Forster, Paul; Iota, Valentin

2012-02-01

Ionic liquids (ILs) are salts in which the ions are poorly coordinated to the point where the eutectic mixture remains liquid at room temperature. In general, ILs exhibit high chemical and thermal stability, have extended liquid regions in the pressure-temperature domain, and can be easily obtained. Commercial ionic liquids are relatively inexpensive and custom ionic solutions can be easily synthesized by mixing common reactants. These properties make ionic liquids attractive candidates for high-pressure media in Diamond Anvil Cell (DAC) experiments. In this presentation we explore the use of ionic liquids as DAS quasihydrostatic pressure media for pressures up to 50 GPa. As a measure of hydrostaticity we monitor the splitting and peak-widths of the R1 andR 2 fluorescence lines from small ruby chips (Al2O3 :Cr^3+) imbedded in the pressure medium. We present results on a series of commercially available ionic fluids against standard pressure media: methanol-ethanol mixtures, silicone oil, sodium chloride (NaCl) and noble gases (Ar, Ne, He).

Impact initiation of reactive aluminized fluorinated acrylic nanocomposites

DOE Office of Scientific and Technical Information (OSTI.GOV)

White, Bradley W.; Crouse, Christopher A.; Spowart, Jonathan E.

The initiation of aluminized fluorinated acrylic (AlFA) nanocomposites during modified Taylor impact tests was investigated. Samples were impacted against a steel or sapphire anvil at a nominal velocity of 150 m/s. A framing camera was used to capture head-on and side-profile impact images for the sapphire window and steel plate rigid anvils, respectively. Correlations were drawn between both experimental setups to determine the initiation locations and reaction times. Reactions were found to initiate at an intermediate radius on the impact face of the pellet at a time near full compaction. From simulations, the highest strains and temperatures were found atmore » radii similar to those observed in experiments at the time of ignition. Off-normal impacts produced higher localized straining and temperatures on one-half of the pellet. As a result, the copper projectile, used for delivery, was revealed to aid in a shear assisted reaction by helping to drive the pellet material outward as the projectile deformed radially.« less

The high - low-p clinoenstatite transition: in situ xrd and ultrasonic study

NASA Astrophysics Data System (ADS)

Müller, H. J.; Wunder, B.; Lathe, C.; Schilling, F. R.

2003-04-01

Using single-crystal X-ray diffraction analyses in a diamond anvil cell Angel et al. (1992) published the transformation of MgSiO_3 from LCEn to a C2/c-polymorph (HCEn) at around 5.5 - 8.0 GPa and room-T (RT)conditions. This LCEn - HCEn-transition is not quenchable. However, the knowledge of the exact phase boundary positions for the MgSiO_3-transitions is essential as pyroxene is an important component of the Earth's mantle and will significantly influence elastic properties (e.g. v_p, v_s) of the mantle. We determined the HCEn - LCEn-transition by in-situ XRD experiments under high P, T using the multi-anvil appar atus MAX80 at the synchrotron facility HASYLAB, Hamburg. Our preliminary results only represent the minimum P-conditions of the HCEn - LCEn phase boundary, which is approximated by equation P (GPa) = 0.0021T (/C) + 6.06. Nevertheless, our results are in good agreement to data published by Angel & Hugh-Jones (1994). The invariant point defined by the intersection of the HCEn - LCEn equilibrium determined within this study and the OEn - LCEn reaction after Angel &Hugh-Jones (1994) lies at about 7.9 GPa and 875/C. This is in contrast to earlier experimental results of Kanzaki (1991) and Ulmer &Stalder (2001). The samples for the ultrasonic interferometry experiments were prepared by hot-isostatic pressing also using the MAX80. Adjacent XRD ruled out any phase transition during the hip-process. For the ultrasonic measurements one of the six anvils of MAX80 were exchanged by an anvil equipped with lithium niobate p- and s-wave transducers of 33.3 MHz natural frequency (Mueller et al., 2002). Corresponding to the XRD experiments HCEn was formed by increasing the pressure at RT. The velocities of elastic compressional and shear waves were measured under in situ conditions using the classical digital sweep technique. After the phase transition to LCEn as a result of rising the temperature at given pressure the measurements were repeated. The newly developed ultra sonic data transfer function (UDTF) technique, first described by Li (pers. comm.), enabling much faster measurements than the classical method, was used to measure both the elastic wave velocities of LCEn in dependence on pressure at 700/C. To compare the results v_p and v_s were measured at 6.7 GPa and 7.5 GPa using both interferometric techniques. The results demonstrate the correspondence in the limits of less than 1 %.

High pressure generation using scaled-up Kawai-cell

NASA Astrophysics Data System (ADS)

Shatskiy, A.; Katsura, T.; Litasov, K. D.; Shcherbakova, A. V.; Borzdov, Y. M.; Yamazaki, D.; Yoneda, A.; Ohtani, E.; Ito, E.

2011-11-01

A scaled-up version of a 6-8 Kawai-type multianvil apparatus equipped with 47-mm WC anvils has been developed at the Institute for the Study of the Earth's Interior for operation over pressure ranging up to 19 and 24 GPa using the conventional system with larger compressional volumes between 1.2 and 0.4 cm 3, respectively. This system is used under uniaxial compression along cube diagonal of the Kawai-cell up to the press load of 19 MN. Experiments are performed using octahedral pressure media (PM) made of MgO- and ZrO 2-based semi-sintered ceramics and unfired pyrophyllite gaskets. In this study we used "Toshiba-F" grade WC anvils allowing pressure generation up to 24 GPa. We perform pressure calibrations at room and high temperatures, with octahedron/anvil truncation edge-length ratios ( a0/ b, mm) of 12.2/6, 14/6, 14/7, 16/7, 18/7, 18/9, and 18/10. Different configurations show that an increase in edge-length ratio of a0/b permits the achievement of higher pressure, which agrees with the results of Frost at al. (Frost, D.J., Poe, B.T., Tronnes, R.G., Liebske, C., Duba, A., Rubie, D.C., 2004. A new large-volume multianvil system. Phys. Earth Planet. Inter. 143, 507). However, it also shifts the pressure maximum to higher press loads, in some cases exceeding the capacity of a press. Our and Frost et al. (2004) data reveal that the 14/6, 18/8, and 18/10 assemblies are the most suitable in generating pressures of up to 19-24 GPa at 19 MN press load limits. The assemblies with a low a0/ b ratio have a lower upper pressure limit; however, they exhibit a systematically higher efficiency in pressure generation at low press loads. Consequently, assemblages with high and low a0/ b ratios should be used in high and low pressure experiments, respectively. For example, the 18/12 assembly is suitable for 5-11 GPa pressure range (Stoyanov, E., Haussermann, U., Leinenweber, K., 2010. Large-volume multianvil cells designed for chemical synthesis at high pressures. High Pressure Res., 30, 175), whereas the 14/6, 18/8 ( Frost et al., 2004), and 18/10 assemblies are suitable for 22-24, 19-23, and 11-19 GPa pressure ranges, respectively. The maximum pressure generation achieved in the present study is 24 GPa, using the 14/6 assembly. This appears to be the maximum pressure level attainable by using WC anvils.

Applied Meteorology Unit (AMU) Quarterly Report First Quarter FY-04

NASA Technical Reports Server (NTRS)

Bauman, William; Wheeler, Mark; Labert, Winifred; Jonathan Case; Short, David

2004-01-01

This report summarizes the Applied Meteorology Unit (AMU) activities for the First Quarter of Fiscal Year 2004 (October - December 2003). Tasks reviewed are: (1) Objective Lightning Probability Forecast, (2) Mesonet Temperature and Wind Climatology, (3) Severe Weather Forecast Decision Aid and (4) Anvil Transparency Relationship to Radar Reflectivity

Florida Thunderstorms: A Faucet of Reactive Nitrogen to the Upper Troposphere

NASA Technical Reports Server (NTRS)

Ridley, B.; Ott, L.; Emmons, L.; Montzka, D.; Weinheimer, A.; Knapp, D.; Grahek, F.; Li, L.; Heymsfield, G.; McGill, M.

2004-01-01

During the NASA Cirrus Regional Study of Tropical Anvils and Cirrus Layers-Florida Area Cirrus Experiment (CRYSTAL-FACE) enhanced mixing ratios of nitric oxide were measured in the anvils of thunderstorms and in clear air downwind of storm systems on flights of a Wl3-57F high-altitude aircraft. Mixing ratios greater than l0 - 20 times background were readily observed over distances of 25-120 km due to lightning activity. In many of the Florida storms deposition of NO occurred up to near the tropopause but major deposition usually occurred 1 - 2 km below the tropopause, or mostly within the visible anvil volume formed prior to storm decay. Observations from two storms of very different anvil size and electrical activity allowed estimates of the total mass of NO, vented to the middle and upper troposphere. Using the cloud-to ground (CG) flash accumulations from the National Lightning Detection Network, climatological intra-cloud (IC) to CG ratios, and assuming that CG and IC flashes were of equivalent efficiency for NO production, the ranges of production per flash for a moderate-sized and a large storm were (0.51 - 1.0) x l0(exp 26) and (2.3 - 3.1) x 10(exp 26) molecules NO/flash, respectively. Using the recently determined average global flash rate of 44 8, a gross extrapolation of these two storms to represent possible global annual production rates yield 1.6 - 3.2 and 7.3 - 9.9 Tg(N)/yr, respectively. If the more usual assumption is made that IC efficiency is l/l0th that of CG activity, the ranges of production for the moderate-sized and large storm were (1.3 - 2.7) x l0(exp 26) and (6.0 - 8.1) x l0(exp 26) molecules NO/CG flash, respectively. The estimates from the large storm may be high because there is indirect evidence that the IC/CG ratio was larger than would be derived from climatology. These two storms and others studied did not have flash rates that scaled as approx. H(sup 5) where H is the cloud top altitude. The observed CG flash accumulations and NO(x) mass production estimate for the month of July over the Florida area were compared with a representative 3D global Chemistry-Transport Model (CTMJ that uses the Price et al. lightning parameterization. For two land grid points representing the Florida peninsula the model compared well with the observations: CG flash rates were low by only a factor of approx. 2. When the model grid points included the coastal regions of Florida the flash accumulations were lower than observed by a factor of 3.4 - 4.6. It is recommended that models using the Price et al. parameterization allow any global coastal grid point to maintain the land rather than the marine flash rate parameterization. The convection in this CTM underestimated the actual cloud top heights over Florida by 1 - 2 km and thus the total lightning flash rates and the altitude range of reactive nitrogen deposition. Broad scale (20 - 120 km) median mixing ratios of NO within anvils over Florida were significantly larger than in storms previously investigated over Colorado and New Mexico.

Standard-free Pressure Measurement by Ultrasonic Interferometry in a Multi-Anvil Device

NASA Astrophysics Data System (ADS)

Mueller, H. J.; Lathe, C.; Schilling, F. R.; Lauterjung, J.

2002-12-01

A key question to all high pressure research arises from the reliability of pressure standards. There is some indication and discussion of an uncertainty of 10-20% for higher pressures in all standards. Simultaneous and independent investigation of the dynamical (ultrasonic interferometry of elastic wave velocities) and static (XRD-measurement of the pressure-induced volume decline) compressibility on a sample reveal the possibility of a standard-free pressure calibration (see Getting, 1998) and, consequently an absolute pressure measurement. Ultrasonic interferometry is used to measure velocities of elastic compressional and shear waves in the multi-anvil high pressure device MAX80 at HASYLAB Hamburg enabling simultaneous XRD and ultrasonic experiments. Two of the six anvils were equipped with overtone polished lithium niobate transducers of 33.3 MHz natural frequency, for generation and detection of ultrasonic waves with a frequency sweep between 5 and 55 MHz. Different buffer - reflector combinations were tested to optimize the critical interference between both sample echoes. NaCl powder of 99.5 % purity (analytical grade by Merck) was used as starting material for manufacturing the samples used as pressure calibrant after Decker (1971). The medium grain size was 50 μm. The powder was pressed to a crude sample cylinder of 10 mm diameter and a length of 20 mm using a load of 6 tons resulting in an effective pressure of 0.25 to 0.3 GPa. The millimeter sized samples (diameter 2.4 mm and 1.6 mm length for 6 mm anvil truncation and diameter 3.1 mm and 1.1 mm length for 3.5 mm anvil truncation) for the high pressure experiments were shaped with a high-precision (+/- 0.5 μm) cylindrical grinding machine and polished at the front faces. From the ultrasonic wave velocity data we calculated the compressibility of NaCl. This requires in situ density data. Therefore the sample deformation during the high pressure experiments was analyzed in detail and the results were compared with models published by different authors. The experimental results measured with different set-ups under different pressure conditions were compared with EoS-data derived from static compression experiments up to 5 GPa (Bridgman, 1940) and up to 30 GPa (Holland and Ahrens, 1998; Birch, 1986) using experimental data from Boehler and Kennedy (1980) and Fritz et al. (1971). At 1.2 GPa and 5.3 GPa the results of static compression data exactly correspond to our velocity-based data, polynomial-fitted up to the power of 7. In the range between 2 and 4 GPa our dynamical data have 1.5 - 3 % higher values. Furthermore the pressure revealed according to Decker (1971) is in accordance to our standard-free pressure calibration within the uncertainty of the experiment. Birch, F., J., Geophys. Res., 91, 4,949-4,954, (1986).\\Boehler, R., Kennedy, G.C., J. Phys. Chem. Solids, 41, 517-523, (1980). Bridgman, P.W., Physical Review, 57, 237-239, (1940).\\Decker, D.L., J. Appl. Physics, 42, 3,239-3,244, (1971).\\Fritz, J.N., Marsh, S.P., Carter, W.J., McQueen, R.G., NBS Spec. Publ., E.C. Lloyd ed., 326, 201-208, (1971). Getting, I.C., Eos, 79, F830, (1998).\\Holland, K.G., Ahrens, T.H., Geophys. Mon. 101, Manghnani, M.H. and Yagi, T. eds., 335-355, (1998).

The Origins of Air Parcels Uplifted in a Two Dimensional Gravity Wave in the Tropical Upper Troposphere During the NASA Stratosphere Troposphere Exchange Project (STEP)

NASA Technical Reports Server (NTRS)

Selkirk, Henry B.; Pfister, Leonhard; Chan, K. Roland; Kritz, Mark; Kelly, Ken

1989-01-01

During January and February 1987, as part of the Stratosphere-Troposphere Exchange Project, the NASA ER-2 made 11 flights from Darwin, Australia to investigate dehydration mechanisms in the vicinity of the tropical tropopause. After the monsoon onset in the second week of January, steady easterly flow of 15-25 ms (exp -1) was established in the upper troposphere and lower stratosphere over northern Australia and adjacent seas. Penetrating into this regime were elements of the monsoon convection such as overshooting convective turrets and extensive anvils including cyclone cloud shields. In cases of the latter, the resulting flow obstructions tended to produce mesoscale gravity waves. In several instances the ER- 2 meteorological and trace constituent measurements provide a detailed description of the structure of these gravity waves. Among these was STEP Flight 6, 22-23 January. It is of particular interest to STEP because of the close proximity of ice-laden and dehydrated air on the same isentropic surfaces. Convective events inject large amounts of ice into the upper troposphere and lower stratosphere which may not be completely removed by local precipitation processes. In the present instance, a gravity wave for removed from the source region appears to induce relativity rapid upward motion in the ice-laden air and subsequent dessication. Potential mechanisms for such a localized removal process are under investigation.

Chemistry through cocrystals: pressure-induced polymerization of C 2H 2·C 6H 6 to an extended crystalline hydrocarbon

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ward, Matthew D.; Huang, Haw-Tyng; Zhu, Li

The 1:1 acetylene–benzene cocrystal, C 2H 2·C 6H 6, was synthesized under pressure in a diamond anvil cell (DAC) and its evolution under pressure was studied with single-crystal X-ray diffraction and Raman spectroscopy.

Chemistry through cocrystals: pressure-induced polymerization of C 2H 2·C 6H 6 to an extended crystalline hydrocarbon

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ward, Matthew D.; Huang, Haw-Tyng; Zhu, Li

The 1 : 1 acetylene–benzene cocrystal, C 2H 2·C 6H 6, was synthesized under pressure in a diamond anvil cell (DAC) and its evolution under pressure was studied with single-crystal X-ray diffraction and Raman spectroscopy.

14 CFR Appendix G to Part 417 - Natural and Triggered Lightning Flight Commit Criteria

Code of Federal Regulations, 2013 CFR

2013-01-01

... all clouds in the specified volume, computed as follows: (i) The cloud base to be averaged is the..., height-integrated radar reflectivity (VAHIRR) of clouds, are used with the lightning flight commit... the purpose of this appendix: Anvil cloud means a stratiform or fibrous cloud formed by the upper...

14 CFR Appendix G to Part 417 - Natural and Triggered Lightning Flight Commit Criteria

Code of Federal Regulations, 2012 CFR

2012-01-01

... all clouds in the specified volume, computed as follows: (i) The cloud base to be averaged is the..., height-integrated radar reflectivity (VAHIRR) of clouds, are used with the lightning flight commit... the purpose of this appendix: Anvil cloud means a stratiform or fibrous cloud formed by the upper...

14 CFR Appendix G to Part 417 - Natural and Triggered Lightning Flight Commit Criteria

Code of Federal Regulations, 2014 CFR

2014-01-01

... all clouds in the specified volume, computed as follows: (i) The cloud base to be averaged is the..., height-integrated radar reflectivity (VAHIRR) of clouds, are used with the lightning flight commit... the purpose of this appendix: Anvil cloud means a stratiform or fibrous cloud formed by the upper...

77 FR 58582 - Notice of Determinations Regarding Eligibility To Apply for Worker Adjustment Assistance

Federal Register 2010, 2011, 2012, 2013, 2014

2012-09-21

... thereof under section 421(b)(1); or (C) An affirmative final determination of material injury or threat..... 81,888 Anvil Knitwear, Inc Hamer, SC August 6, 2011. 81,894 WS Packaging Group, Inc., Franklin, PA... investigations were issued because the petitioning groups of workers are covered by active certifications...

Nationality Politics in the Soviet Union: At Last, a Subject of Serious Scholarship in the US

DTIC Science & Technology

1991-01-01

Arens, Olavi, Book review: Rei , August, The Drama of the Baltic Peoples (Stockholm: Kirjastus Vaba Eesti, 1970), 384pp, Bulletin of Baltic Studies, Vol...1940-1980 (Berkeley: University of California Press, 1983) EE. Nodel, Emanuel, Estonia: Nation on the Anvil (New York: Bookman Astor , Inc, 1963) FF

Pressurizing Field-Effect Transistors of Few-Layer MoS 2 in a Diamond Anvil Cell

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, Yabin; Ke, Feng; Ci, Penghong

Hydrostatic pressure applied using diamond anvil cells (DAC) has been widely explored to modulate physical properties of materials by tuning their lattice degree of freedom. Independently, electrical field is able to tune the electronic degree of freedom of functional materials via, for example, the field-effect transistor (FET) configuration. Combining these two orthogonal approaches would allow discovery of new physical properties and phases going beyond the known phase space. Such experiments are, however, technically challenging and have not been demonstrated. In this paper, we report a feasible strategy to prepare and measure FETs in a DAC by lithographically patterning the nanodevicesmore » onto the diamond culet. Multiple-terminal FETs were fabricated in the DAC using few-layer MoS 2 and BN as the channel semiconductor and dielectric layer, respectively. It is found that the mobility, conductance, carrier concentration, and contact conductance of MoS 2 can all be significantly enhanced with pressure. Finally, we expect that the approach could enable unprecedented ways to explore new phases and properties of materials under coupled mechano-electrostatic modulation.« less

The Influence of Wavelength-Dependent Absorption and Temperature Gradients on Temperature Determination in Laser-Heated Diamond-Anvil Cells

NASA Astrophysics Data System (ADS)

Deng, J.; Lee, K. K. M.; Du, Z.; Benedetti, L. R.

2016-12-01

In situ temperature measurements in the laser-heated diamond-anvil cell (LHDAC) are among the most fundamental experiments undertaken in high-pressure science. Despite its importance, few efforts have been made to examine the alteration of thermal radiation spectra of hot samples by wavelength-dependent absorption of the sample itself together with temperature gradients within samples while laser heating and their influence on temperature measurement. For example, iron-bearing minerals show strong wavelength dependent absorption in the wavelength range used to determine temperature, which, together with temperature gradients can account for largely aliased apparent temperatures (e.g., 1200 K deviation for a 4000 K melting temperature) in some experiments obtained by fitting of detected thermal radiation intensities. As such, conclusions of melting temperatures, phase diagrams and partitioning behavior, may be grossly incorrect for these materials. In general, wavelength-dependent absorption and temperature gradients of samples are two key factors to consider in order to rigorously constrain temperatures, which have been largely ignored in previous LHDAC studies. A reevaluation of temperatures measured in recent high-profile papers will be reviewed.

Creating Interactive Graphical Overlays in the Advanced Weather Interactive Processing System (AWIPS) Using Shapefiles and DGM Files

NASA Technical Reports Server (NTRS)

Barrett, Joe H., III; Lafosse, Richard; Hood, Doris; Hoeth, Brian

2007-01-01

Graphical overlays can be created in real-time in the Advanced Weather Interactive Processing System (AWIPS) using shapefiles or DARE Graphics Metafile (DGM) files. This presentation describes how to create graphical overlays on-the-fly for AWIPS, by using two examples of AWIPS applications that were created by the Applied Meteorology Unit (AMU). The first example is the Anvil Threat Corridor Forecast Tool, which produces a shapefile that depicts a graphical threat corridor of the forecast movement of thunderstorm anvil clouds, based on the observed or forecast upper-level winds. This tool is used by the Spaceflight Meteorology Group (SMG) and 45th Weather Squadron (45 WS) to analyze the threat of natural or space vehicle-triggered lightning over a location. The second example is a launch and landing trajectory tool that produces a DGM file that plots the ground track of space vehicles during launch or landing. The trajectory tool can be used by SMG and the 45 WS forecasters to analyze weather radar imagery along a launch or landing trajectory. Advantages of both file types will be listed.

Nuts, nut cracking, and pitted stones at Gesher Benot Ya‘aqov, Israel

PubMed Central

Goren-Inbar, Naama; Sharon, Gonen; Melamed, Yoel; Kislev, Mordechai

2002-01-01

The Acheulian site of Gesher Benot Ya‘aqov (Israel) has revealed a unique association of edible nuts with pitted hammers and anvils. Located in the Dead Sea rift, on the boundary between the Arabian and African plates, the site dates to the Early-Middle Pleistocene, oxygen isotope stage 19. In a series of strata, seven species of nuts, most of which can be cracked open only by a hard hammer, were uncovered. Five of the species are extant terrestrial nuts, and two are aquatic nuts now extinct in the Levant. In addition, the site yielded an assemblage of pitted hammers and anvils similar in pit morphology to those used by chimpanzees and contemporary hunter–gatherers. This is the first time, to our knowledge, that a site has offered both paleobotanical and lithic evidence of plant foods eaten by early hominins and technologies used for processing these foods. The evidence also sheds light on the structure of the community: ethnographic analogies suggest that mixedgender groups may have been active on the shores of paleoLake Hula. PMID:11854536

The stability and Raman spectra of ikaite, CaCO3·6H2O, at high pressure and temperature

USGS Publications Warehouse

Shahar, Anat; Bassett, William A.; Mao, Ho-kwang; Chou, I-Ming; Mao, Wendy

2005-01-01

Raman analyses of single crystals of ikaite, CaCO3·6H2O, synthesized in a diamond-anvil cell at ambient temperature yield spectra from 0.14 to 4.08 GPa; the most intense peaks are at 228 and 1081 cm−1 corresponding to Eg(external) and A1g (internal) modes of vibrations in CO2− 3 ions, respectively. These are in good agreement with Raman spectra previously published for ikaite in powder form at ambient temperature and pressure. Visual observations of a sample consisting initially of a mixture of calcite + water in a hydrothermal diamond-anvil cell yielded a P-T phase diagram up to 2 GPa and 120 °C; the boundary for the reaction ikaite ↔ aragonite + water has a positive slope and is curved convexly toward the aragonite + water field similar to typical melt curves. This curvature can be explained in terms of the Clapeyron equation for a boundary between a solid phase and a more compressible liquid phase or largely liquid phase assemblage.

An estimation of the condensation rates in three severe storm systems from satellite observations of the convective mass flux

NASA Technical Reports Server (NTRS)

Mack, R. A.; Wylie, D. P.

1982-01-01

A technique was developed for estimating the condensation rates of convective storms using satellite measurements of cirrus anvil expansion rates and radiosonde measurements of environmental water vapor. Three cases of severe convection in Oklahoma were studied and a diagnostic model was developed for integrating radiosonde data with satellite data. Two methods were used to measure the anvil expansion rates - the expansion of isotherm contours on infrared images, and the divergent motions of small brightness anomalies tracked on the visible images. The differences between the two methods were large as the storms developed, but these differences became small in the latter stage of all three storms. A comparison between the three storms indicated that the available moisture in the lowest levels greatly affected the rain rates of the storms. This was evident from both the measured rain rates of the storms and the condensation rates estimated by the model. The possibility of using this diagnostic model for estimating the intensities of convective storms also is discussed.

Origin of temperature plateaus in laser-heated diamond anvil cell experiments

NASA Astrophysics Data System (ADS)

Geballe, Zachary M.; Jeanloz, Raymond

2012-06-01

Many high-pressure high-temperature studies using laser-heated diamond cells have documented plateaus in the increase of temperature with increasing laser power or with time. By modeling heat transfer in typical laser-heated diamond anvil cell experiments, we demonstrate that latent heat due to melting or other phase transformation is unlikely to be the source of observed plateaus in any previously published studies, regardless of whether pulsed or continuous lasers were used. Rather, large increases (˜10-fold) in thermal conductivity can explain some of the plateaus, and modest increases in reflectivity (tens of percent) can explain any or all of them. Modeling also shows that the sub-microsecond timescale of heating employed in recent pulsed heating experiments is fast enough compared to heat transport into and through typical insulations, but too slow compared to heat transport into metallic laser absorbers themselves to allow the detection of a large plateau due to latent heat of fusion. Four new designs are suggested for future experiments that could use the simple observation of a latent heat-induced plateau to provide reliable high-pressure melting data.

How to measure heat capacity of metals at 10s to 100s of GPa

NASA Astrophysics Data System (ADS)

Geballe, Z. M.; Townley, A.; Jeanloz, R.

2014-12-01

Adapting methods of calorimetry to the diamond-anvil cell can provide important new information for understanding planetary interiors. Here we show that heat capacity of metals can be measured to the 10-100 GPa range by using AC electrical heating inside diamond anvil cells. Frequencies of f ≈ 1-100 MHz must be used to contain the heat within the sample of interest, as evidenced by numerical and physical models of heat flow: f > DinsCins2/(Csamdsam)2, where Dins is the thermal diffusivity of the insulation, Cins and Csam are specific heat capacities of insulation and metal sample, and dsam is sample thickness. Heat must be deposited uniformly (e.g. skin depth > sample thickness) for the most accurate and unambiguous measurements, thereby allowing measurement of the energetics of pre-melting, melting and partial melting of metals, including iron and its alloys. In principle, high-pressure calorimetry can be used to independently determine melting at high pressures, and also to quantify latent heats of fusion, thereby revealing the density of liquid metals at Earth core conditions.

Zero-Kelvin Compression Isotherms of the Elements 1 ≤ Z ≤ 92 to 100 GPa

DOE Office of Scientific and Technical Information (OSTI.GOV)

Young, David A.; Cynn, Hyunchae; Söderlind, Per

2016-12-01

Most of the chemical elements have now been compressed close to or above 100 GPa (1 Mbar) pressure in diamond-anvil cells and the pressure–volume room-temperature isotherms have been measured. We collect these data and use simple lattice-dynamics models to reduce the isotherms to 0 K. We have extended the published work by making new diamond-anvil-cell measurements on Cr and Rh, and by conducting density-functional calculations on the elements Po, At, Rn, Fr, Ra, and Ac. The 0 K data are tabulated for all elements 1 ≤ Z ≤ 92 and 0 ≤ P ≤ 100 GPa. These data are usefulmore » for generating wide-range equation of state models and for studying the stability of chemical compounds at high pressure (“Megabar chemistry”). The tables presented here are intended to be reference thermodynamic tables for use in high-pressure research. Further experimental and theoretical work will be needed to extend the tables to higher pressure and to improve accuracy.« less

Common Problems with Pyrometry at Shock Physics Experiments and How to Avoid Them

NASA Astrophysics Data System (ADS)

Seifter, Achim; Obst, Andrew; Holtkamp, David

2007-06-01

Temperature is not only one of the most prominent parameters in shock physics experiments but also very hard to determine experimentally. Only a few techniques are available because of difficulties due to the short timescale and often very low temperatures. Pyrometry is the most portable of these techniques but has to deal with some problems which give rise to uncertainties. Only if the experiment is designed very carefully some of these difficulties like background radiation from high explosive burn products, muzzle flash or laser light can be avoided. Other problems like spatial temperature non-uniformities or thermal radiation from a transparent anvil are inherent to the experiment and cannot be avoided. By choosing the proper spectral range covered by the pyrometer and fitting the obtained spectral radiance traces with appropriate models meaningful results can be obtained. In this paper we will describe the most important points to be taken into account when designing the experiment, present considerations for choosing the wavelength range of the pyrometer and show data where spatial non uniformities or radiation from hot anvils occurred and temperature data could still be obtained.

Earth Observation

NASA Image and Video Library

2014-08-05

ISS040-E-088891 (5 Aug. 2014) --- Thunderheads near Borneo, Indonesia are featured in this image photographed by an Expedition 40 crew member on the International Space Station. Late afternoon sun casts long shadows from high thunderhead anvils over southern Borneo. Crews aboard the space station have recently concentrated on panoramic views of clouds?taken with lenses similar to the focal length of the human eye. These images reveal the kinds of views crews see -- huge areas of the planet, with a strong three-dimensional sense of what it is like to fly 350 kilometers above Earth. Winds usually blow in different directions at different altitudes. High-altitude winds are clearly sweeping the tops off the many tallest thunderclouds, generating long anvils of diffuse cirrus plumes that trail south. At low levels, ?streets? of white dots -- fair-weather cumulus clouds -- are aligned with west-moving winds (lower left). Small smoke plumes from forest fires onshore are also aligned west. Storm formation near the horizon -- more than 1,000 kilometers away (center) -- is assisted by air currents rising over the central mountains of Borneo.

A 130,000-year-old archaeological site in southern California, USA.

PubMed

Holen, Steven R; Deméré, Thomas A; Fisher, Daniel C; Fullagar, Richard; Paces, James B; Jefferson, George T; Beeton, Jared M; Cerutti, Richard A; Rountrey, Adam N; Vescera, Lawrence; Holen, Kathleen A

2017-04-26

The earliest dispersal of humans into North America is a contentious subject, and proposed early sites are required to meet the following criteria for acceptance: (1) archaeological evidence is found in a clearly defined and undisturbed geologic context; (2) age is determined by reliable radiometric dating; (3) multiple lines of evidence from interdisciplinary studies provide consistent results; and (4) unquestionable artefacts are found in primary context. Here we describe the Cerutti Mastodon (CM) site, an archaeological site from the early late Pleistocene epoch, where in situ hammerstones and stone anvils occur in spatio-temporal association with fragmentary remains of a single mastodon (Mammut americanum). The CM site contains spiral-fractured bone and molar fragments, indicating that breakage occured while fresh. Several of these fragments also preserve evidence of percussion. The occurrence and distribution of bone, molar and stone refits suggest that breakage occurred at the site of burial. Five large cobbles (hammerstones and anvils) in the CM bone bed display use-wear and impact marks, and are hydraulically anomalous relative to the low-energy context of the enclosing sandy silt stratum. 230 Th/U radiometric analysis of multiple bone specimens using diffusion-adsorption-decay dating models indicates a burial date of 130.7 ± 9.4 thousand years ago. These findings confirm the presence of an unidentified species of Homo at the CM site during the last interglacial period (MIS 5e; early late Pleistocene), indicating that humans with manual dexterity and the experiential knowledge to use hammerstones and anvils processed mastodon limb bones for marrow extraction and/or raw material for tool production. Systematic proboscidean bone reduction, evident at the CM site, fits within a broader pattern of Palaeolithic bone percussion technology in Africa, Eurasia and North America. The CM site is, to our knowledge, the oldest in situ, well-documented archaeological site in North America and, as such, substantially revises the timing of arrival of Homo into the Americas.

Airborne In Situ and Ground-based Polarimetric Radar Measurements of Tropical Convection in Support of CRYSTAL-FACE

NASA Technical Reports Server (NTRS)

Poellot, Michael R.; Kucera, Paul A.

2004-01-01

This report describes the work performed by the University of North Dakota (UND) under NASA Grant NAG5-11509, titled Airborne In Situ and Ground-based Polarimetric Radar Measurements of Tropical Convection in Support of CRYSTAL-FACE. This work focused on the collection of data by two key platforms: the UND Citation II research aircraft and the NASA NPOL radar system. The CRYSTAL-FACE (C-F) mission addresses several key issues from the NASA Earth System Enterprise, including the variability of water in the atmosphere, the forcing provided by tropical cirrus and the response of the Earth system to this forcing. In situ measurements and radar observations of tropical convection, cirrus clouds and their environment are core elements of C-F. One of the primary issues that C-F is addressing is the relationship of tropical cirrus anvils to precipitating deep convection. The in situ measurements from C-F are being used to validate remote sensing of Earth-Atmosphere properties, increase our knowledge of upper tropospheric water vapor and its distribution, and increase our knowledge of tropical cirrus cloud morphology and composition. Radar measurements, especially polarimetric diversity observations available fiom the NASA NPOL radar, are providing essential information about the initiation, modulation, and dissipation of convective cores and the generation of associated anvils in tropical convection. Specifically, NPOL radar measurements contain information about convective intensity and its vertical structure for comparison with thermodynamic and kinematic environmental measurements observed from soundings. Because of the polarimetric diversity of MOL, statistics on bulk microphysical properties can be retrieved and compared to the other characteristics of convection and associated cirrus anvils. In summary, the central objectives of this proposal were to deploy the UND Citation research aircraft as an in situ sensing platform for this mission and to provide collaborative analyses of the recorded data and to deploy the NPOL radar to observe the characteristics of cirrus and parent convection.

Combined resistive and laser heating technique for in situ radial X-ray diffraction in the diamond anvil cell at high pressure and temperature

DOE Office of Scientific and Technical Information (OSTI.GOV)

Miyagi, Lowell; Department of Earth Sciences, Montana State University, Bozeman, Montana 59717; Kanitpanyacharoen, Waruntorn

2013-02-15

To extend the range of high-temperature, high-pressure studies within the diamond anvil cell, a Liermann-type diamond anvil cell with radial diffraction geometry (rDAC) was redesigned and developed for synchrotron X-ray diffraction experiments at beamline 12.2.2 of the Advanced Light Source. The rDAC, equipped with graphite heating arrays, allows simultaneous resistive and laser heating while the material is subjected to high pressure. The goals are both to extend the temperature range of external (resistive) heating and to produce environments with lower temperature gradients in a simultaneously resistive- and laser-heated rDAC. Three different geomaterials were used as pilot samples to calibrate andmore » optimize conditions for combined resistive and laser heating. For example, in Run1, FeO was loaded in a boron-mica gasket and compressed to 11 GPa then gradually resistively heated to 1007 K (1073 K at the diamond side). The laser heating was further applied to FeO to raise temperature to 2273 K. In Run2, Fe-Ni alloy was compressed to 18 GPa and resistively heated to 1785 K (1973 K at the diamond side). The combined resistive and laser heating was successfully performed again on (Mg{sub 0.9}Fe{sub 0.1})O in Run3. In this instance, the sample was loaded in a boron-kapton gasket, compressed to 29 GPa, resistive-heated up to 1007 K (1073 K at the diamond side), and further simultaneously laser-heated to achieve a temperature in excess of 2273 K at the sample position. Diffraction patterns obtained from the experiments were deconvoluted using the Rietveld method and quantified for lattice preferred orientation of each material under extreme conditions and during phase transformation.« less

Measurements of mineral thermal conductivity at high pressures and temperatures with the laser-heated diamond anvil cell

NASA Astrophysics Data System (ADS)

McGuire, C. P.; Rainey, E.; Kavner, A.

2016-12-01

The high-pressure, high-temperature thermal conductivities of lower mantle oxides and silicates play an important role in governing the heat flow across the core-mantle boundary, and the thermal conductivity of core materials determines, at first order, the power required to run the geodynamo. Uncertainties in the pressure-dependence and compositional-dependence of thermal conductivities has complicated our understanding of the heat flow in the deep earth and has implications for the geodynamo mechanism (Buffett, 2012). The goal of this study is to measure how thermal conductivity varies with pressure and composition using a technique that combines temperature measurements as a function of power input in the laser-heated diamond anvil cell (LHDAC) with a model of three-dimensional heat flow (Rainey & Kavner, 2014). In one set of experiments, we measured temperature versus laser-power for iron, iron silicide, and stainless steel (Fe:Cr:Ni = 70:19:11 wt%), using a variety of insulating layers. In another set of experiments, we measured temperature vs. laser power for a series of Fe-bearing periclase (Mg1-x,FexO) samples, with compositions ranging from x = .24 to x = .78. These experiments were conducted up to pressures of 25 GPa and temperatures of 2800 K. A numerical model for heat conduction in the LHDAC is used to forward model the temperature versus laser power curves at successive pressures, solving for the change in thermal conductivity of the material required to best reproduce the measurements. The heat flow model is implemented using a finite element full-approximation storage (FAS) multi-grid solver, which allows for efficient computation with flexible inputs for geometry and material properties in the diamond anvil cell (Rainey et al., 2013). We use the results of our experiments and model to extract pressure and compositional dependencies of thermal conductivity for the materials described herein. The results are used to help constrain models of the thermal properties of core and mantle materials.

Coupled Fracture and Flow in Shale in Hydraulic Fracturing

NASA Astrophysics Data System (ADS)

Carey, J. W.; Mori, H.; Viswanathan, H.

2014-12-01

Production of hydrocarbon from shale requires creation and maintenance of fracture permeability in an otherwise impermeable shale matrix. In this study, we use a combination of triaxial coreflood experiments and x-ray tomography characterization to investigate the fracture-permeability behavior of Utica shale at in situ reservoir conditions (25-50 oC and 35-120 bars). Initially impermeable shale core was placed between flat anvils (compression) or between split anvils (pure shear) and loaded until failure in the triaxial device. Permeability was monitored continuously during this process. Significant deformation (>1%) was required to generate a transmissive fracture system. Permeability generally peaked at the point of a distinct failure event and then dropped by a factor of 2-6 when the system returned to hydrostatic failure. Permeability was very small in compression experiments (< 1 mD), possibly because of limited fracture connectivity through the anvils. In pure share experiments, shale with bedding planes perpendicular to shear loading developed complex fracture networks with narrow apertures and peak permeability of 30 mD. Shale with bedding planes parallel to shear loading developed simple fractures with large apertures and a peak permeability as high as 1 D. Fracture systems held at static conditions for periods of several hours showed little change in effective permeability at hydrostatic conditions as high as 140 bars. However, permeability of fractured systems was a function of hydrostatic pressure, declining in a pseudo-linear, exponential fashion as pressure increased. We also observed that permeability decreased with increasing fluid flow rate indicating that flow did not follow Darcy's Law, possibly due to non-laminar flow conditions, and conformed to Forscheimer's law. The coupled deformation and flow behavior of Utica shale, particularly the large deformation required to initiate flow, indicates the probable importance of activation of existing fractures in hydraulic fracturing and that these fractures can have adequate permeability for the production of hydrocarbon.

Microseismic Monitoring of the Olivine → Spinel Transition in Fayalite Under Non-Hydrostatic Stress

NASA Astrophysics Data System (ADS)

Officer, T.; Secco, R. A.

2016-12-01

In subduction zones, deep earthquakes are thought to be associated with faulting that arises from phase transformations. In order to test the viability of this mechanism experimentally, it is necessary to make microseismic measurements while the mineral under investigation is subjected to the pressure and temperature (P,T) environment at depth. A system has been developed capable of making in situ acoustic emission (AE) measurements on samples under P,T conditions representative of the upper mantle and transition zone. Experiments are performed in a 3000-ton multi-anvil press using an 18/11 octahedral cell with 6 piezoelectric transducers mounted on the rear side of the anvils. AE signals are collected at a sampling rate of 40 MHz using a triggered system and a data buffer for continuous recording so full waveforms of AE events are captured. The use of multiple transducers distributed in a microseismic array allows for events to be located within the sample through automatic arrival time picking and least squares inversion techniques. The multi-anvil apparatus constitutes an inherently noisy environment both acoustically and electrically, therefore methods of noise reduction were developed and will be discussed. This technique has been used to measure acoustic signals generated from the fracturing of quartz beads during high pressure deformation and to investigate the possibility that the phase transformation from olivine to spinel, known to occur in subduction zones, is associated with deep-focus earthquakes (300 - 690 km depth). The analog material fayalite (Fe2SiO4), the iron end member of olivine, has been examined. Information about its synthesis and sintering will be discussed as well as results of AE experiments on samples experiencing deviatoric stress under high pressure (P = 4-9 GPa) and high temperature (T = 773-1273 K) conditions in the spinel stability field.

The Applied Meteorology Unit: Nineteen Years Successfully Transitioning Research into Operations for America's Space Program

NASA Technical Reports Server (NTRS)

Madura, John T.; Bauman, William H.; Merceret, Francis J.; Roeder, William P.; Brody, Frank C.; Hagemeyer, Bartlett C.

2010-01-01

The Applied Meteorology Unit (AMU) provides technology transition and technique development to improve operational weather support to the Space Shuttle and the entire American space program. The AMU is funded and managed by NASA and operated by a contractor that provides five meteorologists with a diverse mix of advanced degrees, operational experience, and associated skills including data processing, statistics, and the development of graphical user interfaces. The AMU's primary customers are the U.S. Air Force 45th Weather Squadron at Patrick Air Force Base, the National Weather Service Spaceflight Meteorology Group at NASA Johnson Space Center, and the National Weather Service Melbourne FL Forecast Office. The AMU has transitioned research into operations for nineteen years and worked on a wide range of topics, including new forecasting techniques for lightning probability, synoptic peak winds,.convective winds, and summer severe weather; satellite tools to predict anvil cloud trajectories and evaluate camera line of sight for Space Shuttle launch; optimized radar scan strategies; evaluated and implemented local numerical models; evaluated weather sensors; and many more. The AMU has completed 113 projects with 5 more scheduled to be completed by the end of 2010. During this rich history, the AMU and its customers have learned many lessons on how to effectively transition research into operations. Some of these lessons learned include collocating with the operational customer and periodically visiting geographically separated customers, operator submitted projects, consensus tasking process, use of operator primary advocates for each project, customer AMU liaisons with experience in both operations and research, flexibility in adapting the project plan based on lessons learned during the project, and incorporating training and other transition assistance into the project plans. Operator involvement has been critical to the AMU's remarkable success and many awards from NASA, the National Weather Association, and two citations from the Navy's Center of Excellence for Best Manufacturing Practices. This paper will present the AMU's proven methods and explain how they may be applied by other organizations to effectively transition research into operations.

Electrical Anomalies Observed During DC3

NASA Technical Reports Server (NTRS)

Lang, Timothy J.; Rutledge, Steven A.; Dolan, Brenda; Krehbiel, Paul; Rison, William; Lindsey, Daniel T.; Lyons, Walt

2013-01-01

The primary scientific goals of DC3 involved improving our understanding of the chemical impacts of thunderstorms and their anvils. However, the Colorado domain provided opportunities to study other interesting phenomena, including the potential impacts of smoke ingestion on convection and thunderstorms, electrification processes in smoke plumes and pyrocumulonimbus clouds, and the production of sprites by unconventional thunderstorm.

Holding fixture for a hot stamping press

NASA Technical Reports Server (NTRS)

Harris, R. P. (Inventor)

1983-01-01

A hand held guide for manually positioning a work piece between the anvil rib and tool of a hot die stamping press is described. A groove completed by interchangeable cover plates attached at one end of the guide conforms to a cross sectional dimension common to similar workpieces and, with a force fit, retentively holds each of the workpieces.

Search for New Highly Energetic Phases under Compression and Shear

DTIC Science & Technology

2015-05-01

bar barn British thermal unit (thermochemical) calorie (thermochemical) cal (thermochemical/cm ) curie degree (angle) degree Fahrenheit...corresponding finite element algorithms and subroutines are developed. (c) Problems on compression and shear of a sample in rotational diamond anvil...element algorithms and subroutines are developed. Model problems on martensitic microstructure evolution are solved. (f) Experimental approaches to study

16 CFR § 1203.17 - Impact attenuation test.

Code of Federal Regulations, 2013 CFR

2013-01-01

... 135 kg (298 lb), the upper surface of which shall consist of a steel plate at least 12 mm (0.47 in... mm (1/4 in.) thick aluminum plate. The geometric center of the MEP pad shall be aligned with the... anvil sites and orientation shall be chosen by the test personnel to provide the most severe test for...

Sand Fly Surveillance and Control on Camp Ramadi, Iraq, as Part of a Leishmaniasis Control Program

DTIC Science & Technology

2013-12-01

Environmental Science, Research Triangle Park, NC, U.S.A.) and Anvil® 10+10 ULV (Clarke Mosquito Control Products, Roselle , IL, U.S.A). Scourge® was...contract personnel using a Clarke Pro-Mist ULV machine (Clarke Mosquito Control Products, Roselle , IL): April (n=2), May (n=6), June (n=6), July

Thin Clouds

Atmospheric Science Data Center

2013-04-18

... and six research aircraft at the US Naval Air Station near Key West, Florida for the Cirrus Regional Study of Tropical Anvils Layers-Florida Area Cirrus Experiment (CRYSTAL-FACE) field campaign. The campaign had many goals, one of which was making ... the MAS instrument on the ER-2. Data from the MAS shortwave infrared channel that detects cirrus is shown in blue. An animation of the ...

Civic Learning through Agricultural Improvement: Bringing the Loom and the Anvil into Proximity with the Plow. Studies in the History of Education

ERIC Educational Resources Information Center

Lauzon, Glenn P.

2010-01-01

How do people use education to respond to change? How do people learn what is expected of "good citizens" in their communities? These questions have long concerned educational historians, civic educators, and social scientists. In recent years, they have captured national attention through high-profile education reform proposals and…

Acousto-optic Imaging System for In-situ Measurement of the High Temperature Distribution in Micron-size Specimens

NASA Astrophysics Data System (ADS)

Machikhin, Alexander S.; Zinin, Pavel V.; Shurygin, Alexander V.

We developed a unique acousto-optic imaging system for in-situ measurement of high temperature distribution on micron-size specimens. The system was designed to measure temperature distribution inside minerals and functional material phases subjected to high pressure and high temperatures in a diamond anvil cell (DAC) heated by a high powered laser.

A new approach to kinetics study of the anhydrite crystallization at 373 K using a diamond anvil cell with Raman spectroscopy

NASA Astrophysics Data System (ADS)

Liu, C. J.; Zheng, H. F.

2013-04-01

A new approach to the kinetics study of anhydrite (CaSO4) crystallization has been performed in situ using a hydrothermal diamond anvil cell with Raman spectroscopy in the pressure range 896-1322 MPa and a constant temperature of 373 K. Transformed volume fraction X(t) was determined from Raman peak intensity of the sulfate ion in aqueous solution. The transformation-time plots display a sigmoidal shape with time, which indicates that the reaction rate is different at each stage of anhydrite crystallization. At 373 K, the rate constant k increases from 1.14 × 10-4 s-1 to 1.86 × 10-3 s-1, demonstrating a positive effect of pressure on the overall rate at isothermal condition. We first achieved the molar volume change (ΔVm) equal to -1.82 × 10-5 m3/mol in the course of anhydrite crystallization through Avrami kinetic theory, showing a process of reduction in volume at high pressure and high temperature. According to the exponent n derived from our experiments, a grain-boundary nucleation and diffusion-controlled growth kinetically dominates the crystallization of anhydrite.

Nanocrystalline hexagonal diamond formed from glassy carbon

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shiell, Thomas. B.; McCulloch, Dougal G.; Bradby, Jodie E.

Carbon exhibits a large number of allotropes and its phase behaviour is still subject to signifcant uncertainty and intensive research. The hexagonal form of diamond, also known as lonsdaleite, was discovered in the Canyon Diablo meteorite where its formation was attributed to the extreme conditions experienced during the impact. However, it has recently been claimed that lonsdaleite does not exist as a well-defned material but is instead defective cubic diamond formed under high pressure and high temperature conditions. Here we report the synthesis of almost pure lonsdaleite in a diamond anvil cell at 100GPa and 400 C. The nanocrystalline materialmore » was recovered at ambient and analysed using difraction and high resolution electron microscopy. We propose that the transformation is the result of intense radial plastic fow under compression in the diamond anvil cell, which lowers the energy barrier by locking in favourable stackings of graphene sheets. This strain induced transformation of the graphitic planes of the precursor to hexagonal diamond is supported by frst principles calculations of transformation pathways and explains why the new phase is found in an annular region. Furthermore, our findings establish that high purity lonsdaleite is readily formed under strain and hence does not require meteoritic impacts.« less

Six-axis multi-anvil press for high-pressure, high-temperature neutron diffraction experiments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sano-Furukawa, A., E-mail: sano.asami@jaea.go.jp; Hattori, T.; J-PARC Center, Japan Atomic Energy Agency, Ibaraki 319-1195

2014-11-15

We developed a six-axis multi-anvil press, ATSUHIME, for high-pressure and high-temperature in situ time-of-flight neutron powder diffraction experiments. The press has six orthogonally oriented hydraulic rams that operate individually to compress a cubic sample assembly. Experiments indicate that the press can generate pressures up to 9.3 GPa and temperatures up to 2000 K using a 6-6-type cell assembly, with available sample volume of about 50 mm{sup 3}. Using a 6-8-type cell assembly, the available conditions expand to 16 GPa and 1273 K. Because the six-axis press has no guide blocks, there is sufficient space around the sample to use themore » aperture for diffraction and place an incident slit, radial collimators, and a neutron imaging camera close to the sample. Combination of the six-axis press and the collimation devices realized high-quality diffraction pattern with no contamination from the heater or the sample container surrounding the sample. This press constitutes a new tool for using neutron diffraction to study the structures of crystals and liquids under high pressures and temperatures.« less

In situ defect annealing of swift heavy ion irradiated CeO 2 and ThO 2 using synchrotron X-ray diffraction and a hydrothermal diamond anvil cell

DOE PAGES

Palomares, Raul I.; Tracy, Cameron L.; Zhang, Fuxiang; ...

2015-04-16

Hydrothermal diamond anvil cells (HDACs) provide facile means for coupling synchrotron Xray techniques with pressure up to 10 GPa and temperature up to 1300 K. This manuscript reports on an application of the HDAC as an ambient-pressure sample environment for performing in situ defect annealing and thermal expansion studies of swift heavy ion irradiated CeO 2 and ThO 2 using synchrotron X-ray diffraction. The advantages of the in situ HDAC technique over conventional annealing methods include: rapid temperature ramping and quench times, high-resolution measurement capability, simultaneous annealing of multiple samples, and prolonged temperature- and apparatus stability at high temperatures. Isochronalmore » annealing between 300 K and 1100 K revealed 2-stage and 1-stage defect recovery processes for irradiated CeO 2 and ThO 2, respectively; indicating that the morphology of the defects produced by swift heavy ion irradiation of these two materials differs significantly. These results suggest that electronic configuration plays a major role in both the radiation-induced defect production and high temperature defect recovery mechanisms of CeO 2 and ThO 2.« less

Multipurpose high-pressure high-temperature diamond-anvil cell with a novel high-precision guiding system and a dual-mode pressurization device

NASA Astrophysics Data System (ADS)

Pippinger, Thomas; Miletich, Ronald; Burchard, Michael

2011-09-01

A novel diamond-anvil cell (DAC) design has been constructed and tested for in situ applications at high-pressure (HP) operations and has proved to be suitable even for HP sample environments at non-ambient temperature conditions. The innovative high-precision guiding mechanism, comparable to a dog clutch, consists of perpendicular planar sliding-plane elements and is integrated directly into the base body of the cylindrically shaped DAC. The combination of two force-generating devices, i.e., mechanical screws and an inflatable gas membrane, allows the user to choose independently between, and to apply individually, two different forcing mechanisms for pressure generation. Both mechanisms are basically independent of each other, but can also be operated simultaneously. The modularity of the DAC design allows for an easy exchange of functional core-element groups optimized not only for various analytical in situ methods but also for HP operation with or without high-temperature (HT) application. For HP-HT experiments a liquid cooling circuit inside the specific inner modular groups has been implemented to obtain a controlled and limited heat distribution within the outer DAC body.

Measurements of sound velocity in iron-nickel alloys by femtosecond laser pulses in a diamond anvil cell

NASA Astrophysics Data System (ADS)

Wakamatsu, Tatsuya; Ohta, Kenji; Yagi, Takashi; Hirose, Kei; Ohishi, Yasuo

2018-01-01

By comparing the seismic wave velocity profile in the Earth with laboratory data of the sound velocity of iron alloys, we can infer the chemical composition of materials in the Earth's core. The sound velocity of pure iron (Fe) has been sufficiently measured using various techniques, while experimental study on the sound velocity of iron-nickel (Fe-Ni) alloys is limited. Here, we measured longitudinal wave velocities of hexagonal-close-packed (hcp) structured Fe up to 29 GPa, Fe-5 wt% Ni, and Fe-15 wt% Ni up to 64 GPa via a combination of the femtosecond pulse laser pump-probe technique and a diamond anvil cell at room temperature condition. We found that the effect of Ni on the sound velocity of an Fe-based alloy is weaker than that determined by previous experimental study. In addition, we obtained the parameters of Birch's law to be V P = 1146(57)ρ - 3638(567) for Fe-5 wt% Ni and V P = 1141(45)ρ- 3808(446) for Fe-15 wt% Ni, respectively, where V P is longitudinal wave velocity (m/s) and ρ is density (g/cm3).

High pressure effects on the iron iron oxide and nickel nickel oxide oxygen fugacity buffers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Campbell, Andrew J; Danielson, Lisa; Righter, Kevin

The chemical potential of oxygen in natural and experimental samples is commonly reported relative to a specific oxygen fugacity (fO{sub 2}) buffer. These buffers are precisely known at 1 bar, but under high pressures corresponding to the conditions of the deep Earth, oxygen fugacity buffers are poorly calibrated. Reference (1 bar) fO{sub 2} buffers can be integrated to high pressure conditions by integrating the difference in volume between the solid phases, provided that their equations of state are known. In this work, the equations of state and volume difference between the metal-oxide pairs Fe-FeO and Ni-NiO were measured using synchrotronmore » X-ray diffraction in a multi-anvil press and laser heated diamond anvil cells. The results were used to construct high pressure fO{sub 2} buffer curves for these systems. The difference between the Fe-FeO and Ni-NiO buffers is observed to decrease significantly, by several log units, over 80 GPa. The results can be used to improve interpretation of high pressure experiments, specifically Fe-Ni exchange between metallic and oxide phases.« less

Upper tropospheric cloud systems determined from IR Sounders and their influence on the atmosphere

NASA Astrophysics Data System (ADS)

Stubenrauch, Claudia; Protopapadaki, Sofia; Feofilov, Artem; Velasco, Carola Barrientos

2017-02-01

Covering about 30% of the Earth, upper tropospheric clouds play a key role in the climate system by modulating the Earth's energy budget and heat transport. Infrared Sounders reliably identify cirrus down to an IR optical depth of 0.1. Recently LMD has built global cloud climate data records from AIRS and IASI observations, covering the periods from 2003-2015 and 2008-2015, respectively. Upper tropospheric clouds often form mesoscale systems. Their organization and properties are being studied by (1) distinguishing cloud regimes within 2° × 2° regions and (2) applying a spatial composite technique on adjacent cloud pressures, which estimates the horizontal extent of the mesoscale cloud systems. Convective core, cirrus anvil and thin cirrus of these systems are then distinguished by their emissivity. Compared to other studies of tropical mesoscale convective systems our data include also the thinner anvil parts, which make out about 30% of the area of tropical mesoscale convective systems. Once the horizontal and vertical structure of these upper tropospheric cloud systems is known, we can estimate their radiative effects in terms of top of atmosphere and surface radiative fluxes and by computing their heating rates.

XAFS measurements on zinc chloride aqueous solutions from ambient to supercritical conditions using the diamond anvil cell

USGS Publications Warehouse

Mayanovic, Robert A.; Anderson, Alan J.; Bassett, William A.; Chou, I.-Ming

1999-01-01

The structure and bonding properties of metal complexes in subcritical and supercritical fluids are still largely unknown. Conventional high pressure and temperature cell designs impose considerable limitations on the pressure, temperature, and concentration of metal salts required for measurements on solutions under supercritical conditions. In this study, we demonstrate the first application of the diamond anvil cell, specially designed for x-ray absorption studies of first-row transition metal ions in supercritical fluids. Zn K-edge XAFS spectra were measured from aqueous solutions of 1-2m ZnCl2 and up to 6m NaCl, at temperatures ranging from 25-660 ??C and pressures up to 800 MPa. Our results indicate that the ZnCl42- complex is predominant in the 1m ZnCl2/6m NaCl solution, while ZnCl2(H2O)2 is similarly predominant in the 2m ZnCl2 solution, at all temperatures and pressures. The Zn-Cl bond length of both types of chlorozinc(II) complexes was found to decrease at a rate of about 0.01 A??/100 ??C.

Dynamic XRD, Shock and Static Compression of CaF2

NASA Astrophysics Data System (ADS)

Kalita, Patricia; Specht, Paul; Root, Seth; Sinclair, Nicholas; Schuman, Adam; White, Melanie; Cornelius, Andrew; Smith, Jesse; Sinogeikin, Stanislav

2017-06-01

The high-pressure behavior of CaF2 is probed with x-ray diffraction (XRD) combined with both dynamic compression, using a two-stage light gas gun, and static compression, using diamond anvil cells. We use XRD to follow the unfolding of a shock-driven, fluorite to cotunnite phase transition, on the timescale of nanoseconds. The dynamic behavior of CaF2 under shock loading is contrasted with that under static compression. This work leverages experimental capabilities at the Advanced Photon Source: dynamic XRD and shock experiments at the Dynamic Compression Sector, as well as XRD and static compression in diamond anvil cell at the High-Pressure Collaborative Access Team. These experiments and cross-platform comparisons, open the door to an unprecedented understanding of equations of state and phase transitions at the microstructural level and at different time scales and will ultimately improve our capability to simulate the behavior of materials at extreme conditions. Sandia National Laboratories is a multi-mission laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.

First GIS Analysis of Modern Stone Tools Used by Wild Chimpanzees (Pan troglodytes verus) in Bossou, Guinea, West Africa

PubMed Central

Arroyo, Adrian; Matsuzawa, Tetsuro; de la Torre, Ignacio

2015-01-01

Stone tool use by wild chimpanzees of West Africa offers a unique opportunity to explore the evolutionary roots of technology during human evolution. However, detailed analyses of chimpanzee stone artifacts are still lacking, thus precluding a comparison with the earliest archaeological record. This paper presents the first systematic study of stone tools used by wild chimpanzees to crack open nuts in Bossou (Guinea-Conakry), and applies pioneering analytical techniques to such artifacts. Automatic morphometric GIS classification enabled to create maps of use wear over the stone tools (anvils, hammers, and hammers/ anvils), which were blind tested with GIS spatial analysis of damage patterns identified visually. Our analysis shows that chimpanzee stone tool use wear can be systematized and specific damage patterns discerned, allowing to discriminate between active and passive pounders in lithic assemblages. In summary, our results demonstrate the heuristic potential of combined suites of GIS techniques for the analysis of battered artifacts, and have enabled creating a referential framework of analysis in which wild chimpanzee battered tools can for the first time be directly compared to the early archaeological record. PMID:25793642

Raman study of opal at high pressure

NASA Astrophysics Data System (ADS)

Farfan, G.; Wang, S.; Mao, W. L.

2011-12-01

More commonly known for their beauty and lore as gemstones, opals are also intriguing geological materials which may have potential for materials science applications. Opal lacks a definite crystalline structure, and is composed of an amorphous packing of hydrated silica (SiO2) spheroids, which provides us with a unique nano-scaled mineraloid with properties unlike those of other amorphous materials like glass. Opals from different localities were studied at high pressure using a diamond anvil cell to apply pressure and Raman spectroscopy to look at changes in bonding as pressure was increased. We first tested different samples from Virgin Valley, NV, Spencer, ID, Juniper Ridge, OR, and Australia, which contain varying amounts of water at ambient conditions, using Raman spectroscopy to determine if they were opal-CT (semicrystalline cristobalite-trydimite volcanic origin) or opal-A (amorphous sedimentary origin). We then used x-ray diffraction and Raman spectroscopy in a diamond anvil cell to see how their bonding and structure changed under compression and to determine what effect water content had on their high pressure behavior. Comparison of our results on opal to other high pressure studies of amorphous materials like glass has implications from a geological and materials science standpoint.

Zero-Kelvin compression isotherms of the elements 1 ≤ Z ≤ 92 to 100 GPa [Zero-Kelvin compression isotherms of the elements 1 ≤ Z ≤ 90 to 100 GPa (1 megabar)

DOE PAGES

Young, David A.; Cynn, Hyunchae; Soderlind, Per; ...

2016-10-24

Most of the chemical elements have now been compressed close to or above 100 GPa (1 Mbar) pressure in diamond-anvil cells and the pressure–volume room-temperature isotherms have been measured. We collect these data and use simple lattice-dynamics models to reduce the isotherms to 0 K. We have extended the published work by making new diamond-anvil-cell measurements on Cr and Rh, and by conducting density-functional calculations on the elements Po, At, Rn, Fr, Ra, and Ac. The 0 K data are tabulated for all elements 1 ≤ Z ≤ 92 and 0 ≤ P ≤ 100 GPa. These data are usefulmore » for generating wide-range equation of state models and for studying the stability of chemical compounds at high pressure (“Megabar chemistry”). As a result, the tables presented here are intended to be reference thermodynamic tables for use in high-pressure research. Further experimental and theoretical work will be needed to extend the tables to higher pressure and to improve accuracy.« less

Demonstration of a Large-Scale Tank Assembly via Circumferential Friction Stir Welds

NASA Technical Reports Server (NTRS)

Jones, Clyde S.; Adams, Glynn; Colligan, Kevin

2000-01-01

A collaborative effort between NASA/Marshall Space Flight Center and the Michoud Unit of Lockheed Martin Space Systems Company was undertaken to demonstrate assembly of a large-scale aluminum tank using circumferential friction stir welds. The hardware used to complete this demonstration was fabricated as a study of near-net- shape technologies. The tooling used to complete this demonstration was originally designed for assembly of a tank using fusion weld processes. This presentation describes the modifications and additions that were made to the existing fusion welding tools required to accommodate circumferential friction stir welding, as well as the process used to assemble the tank. The tooling modifications include design, fabrication and installation of several components. The most significant components include a friction stir weld unit with adjustable pin length capabilities, a continuous internal anvil for 'open' circumferential welds, a continuous closeout anvil, clamping systems, an external reaction system and the control system required to conduct the friction stir welds and integrate the operation of the tool. The demonstration was intended as a development task. The experience gained during each circumferential weld was applied to improve subsequent welds. Both constant and tapered thickness 14-foot diameter circumferential welds were successfully demonstrated.

Study of the phase transformations and equation of state of magnesium by synchrotron x-ray diffraction

NASA Astrophysics Data System (ADS)

Errandonea, Daniel; Meng, Yue; Häusermann, Daniel; Uchida, Takeyuki

2003-03-01

We studied the phase behaviour and the P - V - T equation of state of Mg by in situ energy-dispersive x-ray diffraction in a multi-anvil apparatus in the pressure-temperature range up to 18.6 GPa and 1527 K. At high temperatures, an hcp to dhcp transition was found above 9.6 GPa, which differs from the hcp to bcc transformation predicted by theoretical calculations. At room temperature, the hcp phase remains stable within the pressure range of this study with an axial ratio, c/a, close to the ideal. The melting of Mg was determined at 2.2, 10 and 12 GPa; the detected melting temperatures are in good agreement with previous diamond anvil cell results. The P - V - T equation of state determined based on the data of this study gives B0 = (36.8 ± 3) GPa, B0 ' = 4.3 ± 0.4, alpha0 = 25 × 10-6 K-1, partialalpha/partialT = (2.3 ± 0.2) × 10-7 K-2 and partialB0,T /partialT = (-2.08 ± 0.09) × 10-2 GPa K-1.

Measurements of sound velocity in iron-nickel alloys by femtosecond laser pulses in a diamond anvil cell

NASA Astrophysics Data System (ADS)

Wakamatsu, Tatsuya; Ohta, Kenji; Yagi, Takashi; Hirose, Kei; Ohishi, Yasuo

2018-06-01

By comparing the seismic wave velocity profile in the Earth with laboratory data of the sound velocity of iron alloys, we can infer the chemical composition of materials in the Earth's core. The sound velocity of pure iron (Fe) has been sufficiently measured using various techniques, while experimental study on the sound velocity of iron-nickel (Fe-Ni) alloys is limited. Here, we measured longitudinal wave velocities of hexagonal-close-packed (hcp) structured Fe up to 29 GPa, Fe-5 wt% Ni, and Fe-15 wt% Ni up to 64 GPa via a combination of the femtosecond pulse laser pump-probe technique and a diamond anvil cell at room temperature condition. We found that the effect of Ni on the sound velocity of an Fe-based alloy is weaker than that determined by previous experimental study. In addition, we obtained the parameters of Birch's law to be V P = 1146(57) ρ - 3638(567) for Fe-5 wt% Ni and V P = 1141(45) ρ- 3808(446) for Fe-15 wt% Ni, respectively, where V P is longitudinal wave velocity (m/s) and ρ is density (g/cm3).

Nanocrystalline hexagonal diamond formed from glassy carbon

DOE PAGES

Shiell, Thomas. B.; McCulloch, Dougal G.; Bradby, Jodie E.; ...

2016-11-29

Carbon exhibits a large number of allotropes and its phase behaviour is still subject to signifcant uncertainty and intensive research. The hexagonal form of diamond, also known as lonsdaleite, was discovered in the Canyon Diablo meteorite where its formation was attributed to the extreme conditions experienced during the impact. However, it has recently been claimed that lonsdaleite does not exist as a well-defned material but is instead defective cubic diamond formed under high pressure and high temperature conditions. Here we report the synthesis of almost pure lonsdaleite in a diamond anvil cell at 100GPa and 400 C. The nanocrystalline materialmore » was recovered at ambient and analysed using difraction and high resolution electron microscopy. We propose that the transformation is the result of intense radial plastic fow under compression in the diamond anvil cell, which lowers the energy barrier by locking in favourable stackings of graphene sheets. This strain induced transformation of the graphitic planes of the precursor to hexagonal diamond is supported by frst principles calculations of transformation pathways and explains why the new phase is found in an annular region. Furthermore, our findings establish that high purity lonsdaleite is readily formed under strain and hence does not require meteoritic impacts.« less

The Fe-Ni-(S) System at 23 GPa: The Possibility of Strong Chemical Fractionation Between Phases in the Cores of the Earth, Mars and Mercury

NASA Astrophysics Data System (ADS)

Stewart, A. J.; Schmidt, M. W.

2004-12-01

The presence of nickel in the Earths core is widely accepted based on cosmochemical and seismological arguments. However, experimental studies into core compositions rarely include nickel, thus adding a degree of simplicity to otherwise complex experiments. Diamond-anvil cell studies have discovered that Fe-Ni alloys appear to separate into two phases upon heating above 10 GPa: from a single hexagonally close-packed (hcp) phase to the presence of both hcp and face centered cubic (fcc) phases (Lin et al., 2002). Unfortunately, due to the small size of diamond-anvil cell samples, meaningful quantitative analysis is commonly impossible. We have conducted multi-anvil experiments at 23 GPa into the Fe-Ni system and have confirmed the presence of two phases in the sub-solidus system. The starting material for these experiments contains 6 wt% nickel, approximating the amount expected to be found in the Earths core (McDonough, 2003). In experiments to 1500° C (the highest temperature thus far examined), electron microprobe analyses show dramatic phase fractionation with charges separating into an iron-rich phase containing less than 1 wt% Ni and a nickel-rich phase containing as much as 98 wt% Ni. We have observed the effect over a range of more than 500° ºC; further experiments are underway to determine whether these phases both persist toward the melting point of the alloy. Multi-anvil experiments at 23 GPa have also been conducted to examine the effect of nickel on the Fe-S system. Sulphur is an element favoured by many researchers as the light element component in the core of the Earth as well as that of Mars. Previous research has suggested that the addition of nickel to the Fe-S system results in the lowering of eutectic temperatures by about 75° C (Pike et al., 1999). The starting material for these experiments is the same as that used for the pure Fe-Ni experiments discussed above, with the addition of sulphur. Our results indicate a pseudo-binary, (Fe, Ni)-S, eutectic point lying slightly below 1200° C, roughly consistent with the results of Pike et al. (1999). The measured eutectic liquid composition contains 4.4 wt% Ni and 15.8 wt% S. This liquid composition fits closely to the ideal composition of a (Fe, Ni)3S compound (16.0 wt% S with 4.4 wt% Ni in the alloy), suggesting the possible importance of this structure in Fe-Ni-S melts. At subsolidus temperatures in the Fe-Ni-S system, our results become very interesting with each charge showing at least 3 coexisting phases. Based on these results, solid cores of Mercury and Mars containing iron, nickel and sulphur will hold at least 3 phases. Extrapolating our results to the inner core of the Earth would suggest that multiple phases occur in our planet as well.

Mineral Physics Research on Earth's Core and UTeach Outreach Activities at UT Austin

NASA Astrophysics Data System (ADS)

Lin, J.; Wheat, A. J.

2011-12-01

Comprehension of the alloying effects of major candidate light elements on the phase diagram and elasticity of iron addresses pressing issues on the composition, thermal structures, and seismic features of the Earth's core. Integrating this mineral physics research with the educational objectives of the CAREER award was facilitated by collaboration with the University of Texas at Austin's premier teaching program, UTeach. The UTeach summer outreach program hosts three one-week summer camps every year exposing K-12th graders to university level academia, emphasizing math and science initiatives and research. Each week of the camp either focuses on math, chemistry, or geology. Many of the students were underrepresented minorities and some required simultaneous translation; this is an effect of the demographics of the region, and caused some language barrier challenges. The students' opportunity to see first-hand what it is like to be on a university campus, as well as being in a research environment, such as the mineral physics lab, helps them to visualize themselves in academia in the future. A collection of displayable materials with information about deep-Earth research were made available to participating students and teachers to disseminate accurate scientific knowledge and enthusiasm. These items included a diamond anvil cell and diagrams of the diamond crystal structure, the layers of the Earth, and the phases of carbon to show that one element can have very different physical properties purely based on differences in structure. The students learned how advanced X-ray and optical laser spectroscopies are used to study properties of planetary materials in the diamond anvil cell. Stress was greatly placed on the basic mathematical relationship between force, area, and pressure, the fundamental principle involved with diamond anvil cell research. Undergraduate researchers from the lab participated in the presentations and hands-on experiments, and answered any questions the young students had about college life and studies. Outreach benefits include effective and organized collaborations with the UTeach program, which prepares undergraduates at UT-Austin to teach secondary science courses, as well as positive connections made with Austin-area science teachers, providing them with alternative knowledge and experience to share with their students in the classroom. The CAREER award offers an excellent venue to connect the PI's research and educational activities, and has made constructive impacts on the PI's career development and on his continuation in this frontier research. The students who visited the lab wrote thank you cards, some expressing great interest in being scientists, geophysicists, and chemical engineers, as well as drawings of diamond anvil cells and the pressure/area relationship, showing excellent comprehension of the subject matter. Program improvements may lie in also outreaching to teachers to create stronger relationships in an effort to enrich curricula and keep students aware of research and degree options as the time to enter college nears.

Gravity waves generated by a tropical cyclone during the STEP tropical field program - A case study

NASA Technical Reports Server (NTRS)

Pfister, L.; Chan, K. R.; Bui, T. P.; Bowen, S.; Legg, M.; Gary, B.; Kelly, K.; Proffitt, M.; Starr, W.

1993-01-01

Overflights of a tropical cyclone during the Australian winter monsoon field experiment of the Stratosphere-Troposphere Exchange Project (STEP) show the presence of two mesoscale phenomena: a vertically propagating gravity wave with a horizontal wavelength of about 110 km and a feature with a horizontal scale comparable to that of the cyclone's entire cloud shield. The larger feature is fairly steady, though its physical interpretation is ambiguous. The 110-km gravity wave is transient, having maximum amplitude early in the flight and decreasing in amplitude thereafter. Its scale is comparable to that of 100-to 150-km-diameter cells of low satellite brightness temperatures within the overall cyclone cloud shield; these cells have lifetimes of 4.5 to 6 hrs. These cells correspond to regions of enhanced convection, higher cloud altitude, and upwardly displaced potential temperature surfaces. The temporal and spatial distribution of meteorological variables associated with the 110-km gravity wave can be simulated by a slowly moving transient forcing at the anvil top having an amplitude of 400-600 m, a lifetime of 4.5-6 hrs, and a size comparable to the cells of low brightness temperature.

Applied Meteorology Unit (AMU)

NASA Technical Reports Server (NTRS)

Bauman, William; Lambert, Winifred; Wheeler, Mark; Barrett, Joe; Watson, Leela

2007-01-01

This report summarizes the Applied Meteorology Unit (AMU) activities for the second quarter of Fiscal Year 2007 (January - March 2007). Tasks reported on are: Obiective Lightning Probability Tool, Peak Wind Tool for General Forecasting, Situational Lightning Climatologies for Central Florida, Anvil Threat Corridor Forecast Tool in AWIPS, Volume Averaqed Heiqht lnteq rated Radar Reflectivity (VAHIRR), Tower Data Skew-t Tool, and Weather Research and Forecastini (WRF) Model Sensitivity Study

High-pressure Irreversible Amorphization of La1/3NbO3

DOE Office of Scientific and Technical Information (OSTI.GOV)

I Halevy; A Hen; A Broide

2011-12-31

The crystallographic structure of La{sub 1/3}NbO{sub 3} perovskite was studied at high pressures using a diamond-anvil cell and synchrotron radiation. High-pressure energy dispersive (EDS) x-ray diffraction and high-pressure angle dispersive (ADS) x-ray diffraction revealed an irreversible amorphization at {approx}10 GPa. A large change in the bulk modulus accompanied the high-pressure amorphization.

CloudSat Takes a 3D Slice of Hurricane Matthew

NASA Image and Video Library

2016-10-07

NASA's CloudSat flew east of Hurricane Matthew's center on Oct. 6 at 11:30 a.m. PDT (2:30 p.m. EDT), intersecting parts of Matthew's outer rain bands and revealing Matthew's anvil clouds (thick cirrus cloud cover), with cumulus and cumulonimbus clouds beneath (lower image). Reds/pinks are larger water/ice droplets. http://photojournal.jpl.nasa.gov/catalog/PIA21095

Laser shock compression experiments on precompressed water in ``SG-II'' laser facility

NASA Astrophysics Data System (ADS)

Shu, Hua; Huang, Xiuguang; Ye, Junjian; Fu, Sizu

2017-06-01

Laser shock compression experiments on precompressed samples offer the possibility to obtain new hugoniot data over a significantly broader range of density-temperature phase than was previously achievable. This technique was developed in ``SG-II'' laser facility. Hugoniot data were obtained for water in 300 GPa pressure range by laser-driven shock compression of samples statically precompressed in diamond-anvil cells.

Amorphous and liquid samples structure and density measurements at high pressure - high temperature using diffraction and imaging techniques

NASA Astrophysics Data System (ADS)

Guignot, N.; King, A.; Clark, A. N.; Perrillat, J. P.; Boulard, E.; Morard, G.; Deslandes, J. P.; Itié, J. P.; Ritter, X.; Sanchez-Valle, C.

2016-12-01

Determination of the density and structure of liquids such as iron alloys, silicates and carbonates is a key to understand deep Earth structure and dynamics. X-ray diffraction provided by large synchrotron facilities gives excellent results as long as the signal scattered from the sample can be isolated from its environment. Different techniques already exist; we present here the implementation and the first results given by the combined angle- and energy-dispersive structural analysis and refinement (CAESAR) technique introduced by Wang et al. in 2004, that has never been used in this context. It has several advantages in the study of liquids: 1/ the standard energy-dispersive technique (EDX), fast and compatible with large multi-anvil presses frames, is used for fast analysis free of signal pollution from the sample environment 2/ some limitations of the EDX technique (homogeneity of the sample, low resolution) are irrelevant in the case of liquid signals, others (wrong intensities, escape peaks artifacts, background subtraction) are solved by the CAESAR technique 3/ high Q data (up to 15 A-1 and more) can be obtained in a few hours (usually less than 2). We present here the facilities available on the PSICHE beamline (SOLEIL synchrotron, France) and a few results obtained using a Paris-Edinburgh (PE) press and a 1200 tons load capacity multi-anvil press with a (100) DIA compression module. X-ray microtomography, used in conjunction with a PE press featuring rotating anvils (RotoPEc, Philippe et al., 2013) is also very effective, by simply measuring the 3D volume of glass or liquid spheres at HPHT, thus providing density. This can be done in conjunction with the CAESAR technique and we illustrate this point. Finally, absorption profiles can be obtained via imaging techniques, providing another independent way to measure the density of these materials. References Y. Wang et al., A new technique for angle-dispersive powder diffraction using an energy-dispersive setup and synchrotron radiation (2004), J. Appl. Cryst. (2004). 37, 947-956 J. Philippe, Y. Le Godec, F. Bergame et M. Morand, Patent INPI 11 62335 (2013)

A 130,000-year-old archaeological site in southern California, USA

USGS Publications Warehouse

Holen, Steven R.; Deméré, Thomas A.; Fisher, Daniel C.; Fullagar, Richard; Paces, James B.; Jefferson, George T.; Beeton, Jared M.; Cerutti, Richard A.; Rountrey, Adam N.; Vescera, Lawrence; Holen, Kathleen A.

2017-01-01

The earliest dispersal of humans into North America is a contentious subject, and proposed early sites are required to meet the following criteria for acceptance: (1) archaeological evidence is found in a clearly defined and undisturbed geologic context; (2) age is determined by reliable radiometric dating; (3) multiple lines of evidence from interdisciplinary studies provide consistent results; and (4) unquestionable artefacts are found in primary context1,2. Here we describe the Cerutti Mastodon (CM) site, an archaeological site from the early late Pleistocene epoch, where in situ hammerstones and stone anvils occur in spatio-temporal association with fragmentary remains of a single mastodon (Mammut americanum). The CM site contains spiral-fractured bone and molar fragments, indicating that breakage occured while fresh. Several of these fragments also preserve evidence of percussion. The occurrence and distribution of bone, molar and stone refits suggest that breakage occurred at the site of burial. Five large cobbles (hammerstones and anvils) in the CM bone bed display use-wear and impact marks, and are hydraulically anomalous relative to the low-energy context of the enclosing sandy silt stratum. 230Th/U radiometric analysis of multiple bone specimens using diffusion–adsorption–decay dating models indicates a burial date of 130.7 ± 9.4 thousand years ago. These findings confirm the presence of an unidentified species of Homo at the CM site during the last interglacial period (MIS 5e; early late Pleistocene), indicating that humans with manual dexterity and the experiential knowledge to use hammerstones and anvils processed mastodon limb bones for marrow extraction and/or raw material for tool production. Systematic proboscidean bone reduction, evident at the CM site, fits within a broader pattern of Palaeolithic bone percussion technology in Africa3,4,5,6, Eurasia7,8,9 and North America10,11,12. The CM site is, to our knowledge, the oldest in situ, well-documented archaeological site in North America and, as such, substantially revises the timing of arrival of Homo into the Americas.

Phase transitions in the system CaCO3 at high P and T determined by in situ vibrational spectroscopy in diamond anvil cells and first-principles simulations

NASA Astrophysics Data System (ADS)

Koch-Müller, Monika; Jahn, Sandro; Birkholz, Natalie; Ritter, Eglof; Schade, Ulrich

2016-09-01

The stability of the high-pressure CaCO3 calcite (cc)-related polymorphs was studied in experiments that were performed in conventional diamond anvil cells (DAC) at room temperature as a function of pressure up to 30 GPa as well as in internally heated diamond anvil cells (DAC-HT) at pressures and temperatures up to 20 GPa and 800 K. To probe structural changes, we used Raman and FTIR spectroscopy. For the latter, we applied conventional and synchrotron mid-infrared as well as synchrotron far-infrared radiation. Within the cc-III stability field (2.2-15 GPa at room temperature, e.g., Catalli and Williams in Phys Chem Miner 32(5-6):412-417, 2005), we observed in the Raman spectra consistently three different spectral patterns: Two patterns at pressures below and above 3.3 GPa were already described in Pippinger et al. (Phys Chem Miner 42(1):29-43, 2015) and assigned to the phase transition of cc-IIIb to cc-III at 3.3 GPa. In addition, we observed a clear change between 5 and 6 GPa that is independent of the starting material and the pressure path and time path of the experiments. This apparent change in the spectral pattern is only visible in the low-frequency range of the Raman spectra—not in the infrared spectra. Complementary electronic structure calculations confirm the existence of three distinct stability regions of cc-III-type phases at pressures up to about 15 GPa. By combining experimental and simulation data, we interpret the transition at 5-6 GPa as a re-appearance of the cc-IIIb phase. In all types of experiments, we confirmed the transition from cc-IIIb to cc-VI at about 15 GPa at room temperature. We found that temperature stabilizes cc-VI to lower pressure. The reaction cc-IIIb to cc-VI has a negative slope of -7.0 × 10-3 GPa K-1. Finally, we discuss the possibility of the dense cc-VI phase being more stable than aragonite at certain pressure and temperature conditions relevant to the Earth's mantle.

Melting of KCl and pressure calibration from in situ ionic conductivity measurements in a multi-anvil apparatus

NASA Astrophysics Data System (ADS)

Li, J.; Dong, J.; Zhu, F.

2017-12-01

Melting plays an unparalleled role in planetary differentiation processes including the formation of metallic cores, basaltic crusts, and atmospheres. Knowledge of the melting behavior of Earth materials provides critical constraints for establishing the Earth's thermal structure, interpreting regional seismic anomalies, and understanding the nature of chemical heterogeneity. Measuring the melting points of compressed materials, however, have remained challenging mainly because melts are often mobile and reactive, and temperature and pressure gradients across millimeter or micron-sized samples introduce large uncertainties in melting detection. Here the melting curve of KCl was determined through in situ ionic conductivity measurements, using the multi-anvil apparatus at the University of Michigan. The method improves upon the symmetric configuration that was used recently for studying the melting behaviors of NaCl, Na2CO3, and CaCO3 (Li and Li 2015 American Mineralogist, Li et al. 2017 Earth and Planetary Science Letters). In the new configuration, the thermocouple and electrodes are placed together with the sample at the center of a cylindrical heater where the temperature is the highest along the axis, in order to minimize uncertainties in temperature measurements and increase the stability of the sample and electrodes. With 1% reproducibility in melting point determination at pressures up to 20 GPa, this method allows us to determine the sample pressure to oil load relationship at high temperatures during multiple heating and cooling cycles, on the basis of the well-known melting curves of ionic compounds. This approach enables more reliable pressure measurements than relying on a small number of fixed-point phase transitions. The new data on KCl bridge the gap between the piston-cylinder results up to 4 GPa (Pistorius 1965 J. of Physics and Chemistry of Solids) and several diamond-anvil cell data points above 20 GPa (Boehler et al. 1996 Physical Review). We will examine the effect of solid-state phase transition on the melting curves of halides and test the validity of various melting theories.

Flash Location, Size, and Rates Relative to the Evolving Kinematics and Microphysics of the 29 May 2012 DC3 Supercell Storm

NASA Astrophysics Data System (ADS)

MacGorman, D. R.; DiGangi, E.; Ziegler, C.; Biggerstaff, M. I.; Betten, D.; Bruning, E. C.

2014-12-01

A supercell thunderstorm was observed on 29 May 2012 during the Deep Convective Clouds and Chemistry (DC3) experiment. This storm was part of a cluster of severe storms and produced 5" hail, an EF-1 tornado, and copious lightning over the course of a few hours. During a period in which flash rates were increasing rapidly, observations were obtained from mobile polarimetric radars and a balloon-borne electric field meter (EFM) and particle imager, while aircraft sampled the chemistry of the inflow and anvil. In addition, the storm was within the domain of the 3-dimensional Oklahoma Lightning Mapping Array (LMA) and the S-band KTLX WSR-88D radar. The focus of this paper is the evolution of flash rates, the location of flash initiations, and the distribution of flash size and flash extent density as they relate to the evolving kinematics and microphysics of the storm for the approximately 30-minute period in which triple-Doppler coverage was available. Besides analyzing reflectivity structure and three-dimensional winds for the entire period, we examine mixing ratios of cloud water, cloud ice, rain, and graupel/hail that have been retrieved by a Lagrangian analysis for three select times, one each at the beginning, middle, and end of the period. Flashes in an around the updraft of this storm were typically small. Flash size tended to increase, and flash rates tended to decrease as distance from the updraft increased. Although flash initiations were most frequent near the updraft, some flashes were initiated near the edge of 30 dBZ cores and propagated into the anvil. Later, some flashes were initiated in the anvil itself, in vertical cells that formed and became electrified tens of kilometers downshear of the main body of the storm. Considerable lightning structure was inferred to be in regions dominated by cloud ice in the upper part of the storm. The continual small discharges in the overshooting top of the storm tended to be near or within 15 dBZ contours, although occasional discharges appeared to extend above the storm.

Quasicrystals at extreme conditions: The role of pressure in stabilizing icosahedral Al 63Cu 24Fe 13 at high temperature

DOE PAGES

Stagno, Vincenzo; Bindi, Luca; Park, Changyong; ...

2015-11-20

Icosahedrite, the first natural quasicrystal with composition Al 63Cu 24Fe 13, was discovered in several grains of the Khatyrka meteorite, a unique CV3 carbonaceous chondrite. The presence in the meteorite fragments of icosahedrite strictly associated with high-pressure phases like ahrensite and stishovite indicates a formation conditions at high pressures and temperatures, likely during an impact-induced shock occurred in contact with the reducing solar nebula gas. In contrast, previous experimental studies on the stability of synthetic icosahedral AlCuFe, which were limited to ambient pressure, indicated incongruent melting at ~1123 K, while high-pressure experiments carried out at room temperature showed structural stabilitymore » up to about 35 GPa. These data are insufficient to experimentally constrain the formation and stability of icosahedrite under extreme conditions. Here we present the results of in situ high pressure experiments using diamond anvil cells of the compressional behavior of synthetic icosahedrite up to ~50 GPa at room temperature. Simultaneous high P-T experiments have been also carried out using both laser-heated diamond anvil cells combined with in situ synchrotron X-ray diffraction (at ~42 GPa) and multi-anvil apparatus (at 21 GPa) to investigate the structural evolution of icosahedral Al 63Cu 24Fe 13 and crystallization of possible coexisting phases. The results demonstrate that the quasiperiodic symmetry of icosahedrite is retained over the entire experimental pressure range explored. In addition, we show that pressure acts to stabilize the icosahedral symmetry at temperatures much higher than previously reported. Based on our experimental study, direct crystallization of Al-Cu-Fe quasicrystals from an unusual Al-Cu-rich melt would be possible but limited to a narrow temperature range beyond which crystalline phases would form, like those observed in the Khatyrka meteorite. Here, an alternative mechanism would consist in late formation of the quasicrystal after crystallization and solid-solid reaction of Al-rich phases. In both cases, linking our results with observations in nature, quasicrystals are expected to preserve their structure even after hypervelocity impacts that involve simultaneous high pressures and temperatures, thus proving their cosmic stability.« less

In situ experimental study of subduction zone fluids using diamond anvil cells

NASA Astrophysics Data System (ADS)

Bureau, H.; Foy, E.; Somogyi, A.; Munsch, P.; Simon, G.; Kubsky, S.

2008-12-01

Experiments carried out in diamond anvil cells combined with in situ synchrotron light source measurements represent the only one issue to observe and study fluid equilibria in real time, at the pressure and temperature conditions of the subduction zones. We will present new results recently obtained at the DIFFABS beam line (SOLEIL Synchrotron) aiming at studying equilibria between silica-rich hydrous melts and aqueous fluids in the presence of U, Th, Pb, Ba and Br. We used synchrotron X-Ray fluorescence analysis performed in situ in Bassett-modified hydrothermal diamond anvil cells in order to monitor the chemical transfers of the studied elements between the phases in equilibrium at different pressures (up to 1.6 GPa) and temperatures (up to 900°C). We have calculated the partition coefficients for each studied element (i): Difluid/melt = Cifluid/Cimelt. Results show that U and Th exhibit more affinities for the silica-rich hydrous fluids in the presence or absence of Br, considered here such as an analogue for Cl, (i.e. 0.4 < DUfluid/melt < 0.7 depending on P,T conditions). Br partitioning shows that whereas this halogen element has very strong affinity to the aqueous fluid during magma degassing (DBrfluid/melt >> 10 after decompression) this coefficient decreases with pressure suggesting that Br would not be immediately washed out from the subducted plate during dehydration but may be recycled deeper in the mantle. These new data combined with previous ones obtained for Pb, Ba (Bureau et al., 2007, HPR vol 27, p. 235) and Rb, Sr, Zr (Bureau et al., 2004, Eos Trans. AGU, 85(47), V11C-05), allow us to propose a general outline of the fluid phase transfers through the subduction factory: (1) at shallow level: their nature and composition, the impact of the presence of halogens and the fertilizing role of such fluids in the mantle wedge, where the generation of arc magmas takes place (2) deeper in the mantle: where hydrous silica-rich supercritical fluids may also favour a deep recycling of a fraction of volatiles and trace elements present in the subducted oceanic crust.

Ultrapressure materials science

NASA Technical Reports Server (NTRS)

Ruoff, A. L.

1984-01-01

Three active areas of research at ultra pressure are pursued, i.e., diffraction studies with the Cornell High Energy Synchrotron Source (CHESS), band gap and absorption edge effects, indentor-anvil experiments and theory and research to attain higher pressures. The range over which X-ray diffraction data and absorption edge data are obtained is extended to 700 kbars. Using the indentor technique pressures of 2.1 Mbars are obtained. Research results and methods are discussed.

Joint Publication 3-31. Command and Control for Joint Land Operations

DTIC Science & Technology

2010-06-29

task force] FALCON .” Admiral James Ellis, Commander, Joint Task Force NOBLE ANVIL during Operation ALLIED FORCE in letter correspondence to RAND...beneficial effect on the gr ound cam paign.” D uring t he ca mpaign, “ Army and M arine artillery were used interchangeably.” SOURCE: Lieutenant...consolidates, prioritizes, and forwards ultra -high frequency tactical satellite requirements to the JFC for channel allocation. k. Establishes, supervises

Electronic energy gap of molecular hydrogen from electrical conductivity measurements at high shock pressures

NASA Technical Reports Server (NTRS)

Nellis, W. J.; Mitchell, A. C.; Mccandless, P. C.; Erskine, D. J.; Weir, S. T.

1992-01-01

Electrical conductivities were measured for liquid D2 and H2 shock compressed to pressures of 10-20 GPa (100-200 kbar), molar volumes near 8 cu cm/mol, and calculated temperatures of 2900-4600 K. The semiconducting energy gap derived from the conductivities is 12 eV, in good agreement with recent quasi-particle calculations and with oscillator frequencies measured in diamond-anvil cells.

Melting curve of materials: theory versus experiments

NASA Astrophysics Data System (ADS)

Alfè, D.; Vocadlo, L.; Price, G. D.; Gillan, M. J.

2004-04-01

A number of melting curves of various materials have recently been measured experimentally and calculated theoretically, but the agreement between different groups is not always good. We discuss here some of the problems which may arise in both experiments and theory. We also report the melting curves of Fe and Al calculated recently using quantum mechanics techniques, based on density functional theory with generalized gradient approximations. For Al our results are in very good agreement with both low pressure diamond-anvil-cell experiments (Boehler and Ross 1997 Earth Planet. Sci. Lett. 153 223, Hänström and Lazor 2000 J. Alloys Compounds 305 209) and high pressure shock wave experiments (Shaner et al 1984 High Pressure in Science and Technology ed Homan et al (Amsterdam: North-Holland) p 137). For Fe our results agree with the shock wave experiments of Brown and McQueen (1986 J. Geophys. Res. 91 7485) and Nguyen and Holmes (2000 AIP Shock Compression of Condensed Matter 505 81) and the recent diamond-anvil-cell experiments of Shen et al (1998 Geophys. Res. Lett. 25 373). Our results are at variance with the recent calculations of Laio et al (2000 Science 287 1027) and, to a lesser extent, with the calculations of Belonoshko et al (2000 Phys. Rev. Lett. 84 3638). The reasons for these disagreements are discussed.

Photothermal effects during nanodiamond synthesis from a carbon aerogel in a laser-heated diamond anvil cell

DOE Office of Scientific and Technical Information (OSTI.GOV)

Crane, Matthew J.; Smith, Bennett E.; Meisenheimer, Peter B.

Nanodiamonds have emerged as promising materials for quantum computing, biolabeling, and sensing due to their ability to host color centers with remarkable photostability and long spin-coherence times at room temperature. Recently, a bottom-up, high-pressure, high-temperature (HPHT) approach was demonstrated for growing nanodiamonds with color centers from amorphous carbon precursors in a laser-heated diamond anvil cell (LH-DAC) that was supported by a near-hydrostatic noble gas pressure medium. However, a detailed understanding of the photothermal heating and its effect on diamond growth, including the phase conversion conditions and the temperature-dependence of color center formation, has not been reported. In this work, wemore » measure blackbody radiation during LH-DAC synthesis of nanodiamond from carbon aerogel to examine these temperature-dependent effects. Blackbody temperature measurements suggest that nanodiamond growth can occur at 16.3 GPa and 1800 K. We use Mie theory and analytical heat transport to develop a predictive photothermal heating model. This model demonstrates that melting the noble gas pressure medium during laser heating decreases the local thermal conductivity to drive a high spatial resolution of phase conversion to diamond. In conclusion, we observe a temperature-dependent formation of nitrogen vacancy centers and interpret this phenomenon in the context of HPHT carbon vacancy diffusion.« less

Fe, Co, Ni: Electrical Resistivity Along their Melting Boundaries

NASA Astrophysics Data System (ADS)

Silber, R. E.; Ezenwa, I.; Secco, R.; Yong, W.

2017-12-01

Electrical resistivity of Fe, Co, and Ni was measured at pressures up to 11 GPa and temperatures into their liquid states in multi-anvil and cubic-anvil presses. Two thermocouples placed at opposite ends of the wire sample served as T probes as well as 4-wire resistance electrodes in a switched circuit. A polarity switch was also used to remove any bias associated with current flow and voltage measurement using thermocouple legs. Post experimental examination of recovered and sectioned samples was done using electron microprobe analyses to check for diffusion in our samples. The observed large jumps in resistivity at the high P melting T of each metal is consistent with its known P,T phase diagram and with post-run compositional analyses. The electrical resistivity behavior in these late transition metals as a function of increasing P and T shows expected trends consistent with 1atm data. Within the error of measurement, the resistivity values at the melting T at high P of Co and Ni appear to mimic their 1 atm value suggesting constant resistivity along the melting boundary. For liquid Fe, resistivity decreases along the melting boundary up to the triple point at 5.2 GPa, and then is nearly constant at higher pressures. The results are compared to prediction by Stacey and Loper (PEPI, 2007).

Diamond-anvil high-pressure cell with improved X-ray collimation system

DOEpatents

Schiferl, David; Olinger, Barton W.; Livingston, Robert W.

1986-01-01

An adjustable X-ray collimation system for a diamond-anvil high-pressure cell of the type including a cooperable piston and cylinder and a pair of opposing diamonds located between the head of the piston and the head of the cylinder. The X-ray collimation system includes a tubular insert which contains an X-ray collimator. The insert is engageable in the bore of the piston. The collimator is mounted within the insert by means of an elastomeric O-ring at the end closest the opposed diamonds, and by means of a set of adjustable set screws at the opposite end. By adjustment of the set screws the collimator can be pivoted about the O-ring and brought into alignment with the opposed diamonds and the sample contained therein. In the preferred embodiment there is further provided a set of plugs which are insertable in the bore of the collimator. The plugs have bores of different diameters. By successively inserting plugs of progressively smaller bore diameters and adjusting the alignment of the collimator with each plug, the collimator can be quickly brought into accurate alignment with the diamonds. The collimation system allows alignment of the collimator either before or after the cell has been loaded and pressurized.

A perforated diamond anvil cell for high-energy x-ray diffraction of liquids and amorphous solids at high pressure.

PubMed

Soignard, Emmanuel; Benmore, Chris J; Yarger, Jeffery L

2010-03-01

Diamond anvil cells (DACs) are widely used for the study of materials at high pressure. The typical diamonds used are between 1 and 3 mm thick, while the sample contained within the opposing diamonds is often just a few microns in thickness. Hence, any absorbance or scattering from diamond can cause a significant background or interference when probing a sample in a DAC. By perforating the diamond to within 50-100 microm of the sample, the amount of diamond and the resulting background or interference can be dramatically reduced. The DAC presented in this article is designed to study amorphous materials at high pressure using high-energy x-ray scattering (>60 keV) using laser-perforated diamonds. A small diameter perforation maintains structural integrity and has allowed us to reach pressures >50 GPa, while dramatically decreasing the intensity of the x-ray diffraction background (primarily Compton scattering) when compared to studies using solid diamonds. This cell design allows us for the first time measurement of x-ray scattering from light (low Z) amorphous materials. Here, we present data for two examples using the described DAC with one and two perforated diamond geometries for the high-pressure structural studies of SiO(2) glass and B(2)O(3) glass.

Clouds in GEOS-5

NASA Technical Reports Server (NTRS)

Bacmeister, Julio; Rienecker, Michele; Suarez, Max; Norris, Peter

2007-01-01

The GEOS-5 atmospheric model is being developed as a weather-and-climate capable model. It must perform well in assimilation mode as well as in weather and climate simulations and forecasts and in coupled chemistry-climate simulations. In developing GEOS-5, attention has focused on the representation of moist processes. The moist physics package uses a single phase prognostic condensate and a prognostic cloud fraction. Two separate cloud types are distinguished by their source: "anvil" cloud originates in detraining convection, and large-scale cloud originates in a PDF-based condensation calculation. Ice and liquid phases for each cloud type are considered. Once created, condensate and fraction from the anvil and statistical cloud types experience the same loss processes: evaporation of condensate and fraction, auto-conversion of liquid or mixed phase condensate, sedimentation of frozen condensate, and accretion of condensate by falling precipitation. The convective parameterization scheme is the Relaxed Arakawa-Schubert, or RAS, scheme. Satellite data are used to evaluate the performance of the moist physics packages and help in their tuning. In addition, analysis of and comparisons to cloud-resolving models such as the Goddard Cumulus Ensemble model are used to help improve the PDFs used in the moist physics. The presentation will show some of our evaluations including precipitation diagnostics.

Tornado occurrences related to overshooting cloud-top heights as determined from ATS pictures

NASA Technical Reports Server (NTRS)

Fujita, T. T.

1972-01-01

A sequence of ATS 3 pictures including the development history of large anvil clouds near Salina, Kansas was enlarged by NASA into 8X negatives which were used to obtain the best quality prints by mixing scan lines in 8 steps to minimize checker-board patterns. These images resulted in the best possible resolution, permitting use to compute the heights of overshooting tops above environmental anvil levels based on cloud shadow relationships along with the techniques of lunar topographic mapping. Of 39 heights computed, 6 were within 15 miles of reported positions of 3 tornadoes. It was found that the tornado proximity tops were mostly less than 5000 ft, with one exception of 7000 ft, suggesting that tornadoes are most likely to occur when overshooting height decreases. In order to simulate surface vortices induced by cloud-scale rotation and updraft fields, a laboratory model was constructed. The model experiment has shown that the rotation or updraft field induces a surface vortex but their combination does prevent the formation of the surface vortex. This research leads to a conclusion that the determination of the cloud-top topography and its time variation is of extreme importance in predicting severe local storms for a period of 0 to 6 hours.

Very high pressure combustion; Reaction propagation rates of nitromethane within a diamond anvil cell

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rice, S.F.; Foltz, M.F.

1991-11-01

This paper reports on the combustion-front propagation rate of nitromethane that has been examined to pressures of 40 GPa. A new and general technique involving pulsed laser ignition of an energetic material within a diamond anvil cell and a method for monitoring the rapid decomposition of nitromethane and other explosives to more stable chemical products is described in detail. Nitromethane is shown to exhibit a flame propagation rate that increases smoothly to 100 m/s at 30 GPa as a function of pressure. Above 30 GPa, the final solid-state combustion products change dramatically and the flame propagation rate begins to decrease.more » The combustion-front propagation rate is analyzed in terms of an existing condensed-phase model that predicts a relationship between the front propagation rate, U, and the pressure derivative of the chemical kinetic activation energy, dE{sub a}/dP, such that a plot of logU{sup 2} vs. P should be linear. The activation energy is analyzed to yield an effective volume of activation, {Delta}V, of {minus}3.4 ml/mol. The chemical kinetic parameters determined from the combustion-front propagation rate analysis of solid high-pressure nitromethane is compared with results from other thermal decomposition studies of this prototypic molecular explosive.« less

Diamond-anvil high-pressure cell with improved x-ray collimation system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schiferl, D.; Olinger, B.W.; Livingston, R.W.

1986-07-22

This patent describes a diamond-anvil high-pressure cell having a tubular piston and a cylinder in which the piston is slidable to effect compression of a pair of opposed diamonds located between the piston and the cylinder. The piston includes a central bore opening on one end, an adjustable X-ray collimation system comprising a tubular insert engageable in the bore of the piston, the insert including a central bore and having first and second ends, with the first end of the insert being closest to the opposed diamonds and the second end of the insert extending out of the open endmore » of the piston, a collimator insertable in the bore of the tubular insert. The collimator has a central bore and having first and second ends corresponding respectively with the first and second ends of the insert, elastomeric pivot means mounted in the bore of the insert at the first end of the insert for flexibly retaining the first end of the collimator while allowing the collimator to pivot within the pivot means, and adjustable locking means located at the second end of the insert for adjusting and securing the second end of the collimator so as to be in alignment with the opposed diamonds.« less

Diamond-anvil high-pressure cell with improved x-ray collimation system

DOEpatents

Schiferl, D.; Olinger, B.W.; Livingston, R.W.

1984-03-30

An adjustable x-ray collimation system for a diamond-anvil high-pressure cell of the type including a cooperable piston and cylinder and a pair of opposing diamonds located between the head of the piston and the head of the cylinder. The x-ray collimation system includes a tubular insert which contains an x-ray collimator. The insert is engageable in the bore of the piston. The collimator is mounted within the insert by means of an elastomeric o-ring at the end closest the opposed diamonds, and by means of a set of adjustable set screws at the opposite end. By adjustment of the set screws the collimator can be pivoted about the o-ring and brought into alignment with the opposed diamonds and the sample contained therein. In the preferred embodiment there is further provided a set of plugs which are insertable in the bore of the collimator. The plugs have bores of different diameters. By successively inserting plugs of progressively smaller bore diameters and adjusting the alignment of the collimator with each plug, the collimator can be quickly brought into accurate alignment with the diamonds. The collimation system allows alignment of the collimator either before or after the cell has been loaded and pressurized.

Photothermal effects during nanodiamond synthesis from a carbon aerogel in a laser-heated diamond anvil cell

DOE PAGES

Crane, Matthew J.; Smith, Bennett E.; Meisenheimer, Peter B.; ...

2018-05-17

Nanodiamonds have emerged as promising materials for quantum computing, biolabeling, and sensing due to their ability to host color centers with remarkable photostability and long spin-coherence times at room temperature. Recently, a bottom-up, high-pressure, high-temperature (HPHT) approach was demonstrated for growing nanodiamonds with color centers from amorphous carbon precursors in a laser-heated diamond anvil cell (LH-DAC) that was supported by a near-hydrostatic noble gas pressure medium. However, a detailed understanding of the photothermal heating and its effect on diamond growth, including the phase conversion conditions and the temperature-dependence of color center formation, has not been reported. In this work, wemore » measure blackbody radiation during LH-DAC synthesis of nanodiamond from carbon aerogel to examine these temperature-dependent effects. Blackbody temperature measurements suggest that nanodiamond growth can occur at 16.3 GPa and 1800 K. We use Mie theory and analytical heat transport to develop a predictive photothermal heating model. This model demonstrates that melting the noble gas pressure medium during laser heating decreases the local thermal conductivity to drive a high spatial resolution of phase conversion to diamond. In conclusion, we observe a temperature-dependent formation of nitrogen vacancy centers and interpret this phenomenon in the context of HPHT carbon vacancy diffusion.« less

High-pressure synthesis of predicted oxynitride perovskite: Yttrium Silicon Oxynitride (YSiO2N)

NASA Astrophysics Data System (ADS)

Ahart, Muhtar; Somayazulu, M.; Vadapoo, Rajasekarakumar; Cohen, R. E.

We synthesized the previously predicted polar oxynitride perovskite in a diamond anvil cell with laser heating. YSiO2N was predicted to have the polar P4mm structure with an effective spontaneous polarization of 130 μC/cm2. A mixture of Yttrium nitride (YN) and amorphous Silicon dioxide (SiO2) were loaded into a diamond anvil cell and laser heated at or above 1200 C at 12 GPa. The run products were investigated by x-ray diffraction, Raman spectroscopy, and second harmonic generation, for their phase and structural properties. The x-ray diffraction pattern (a = 3.235 Å, c = 4.485 Å) shows the phase formation of YSiO2N and matches with the diffraction pattern derived from the first-principle predicted lattice parameters. However, minor unknown peaks are on the diffraction pattern indicating of the co-existence of other unknown phases. Further study of Raman spectroscopy observes the theoretically predicted modes, and second harmonic generation shows strong non-linear optical signal, which confirms the polar properties of YSiO2N. This work is supported by ONR Grants N00014-12-1-1038 and N00014-14-1-0561, by the ERC Advanced Grant ToMCaT.

System for Controlling the Stirring Pin of a Friction Stir Welding Apparatus

NASA Technical Reports Server (NTRS)

Ding, R. Jeffrey (Inventor); Romine, Peter L. (Inventor); Oelgoetz, Peter A. (Inventor)

2002-01-01

A control is provided for a friction stir welding apparatus comprising a pin tool which includes a shoulder and a rotating pin extending outwardly from the shoulder of the pin tool and which, in use, is plunged into a workpiece formed contacting workpiece members to stir weld the members together. The control system controls the penetration of the pin tool into the workpiece members which are mounted on a support anvil. The control system includes a pin length controller for controlling pin length relative to the shoulder and for producing a corresponding pin length signal. A pin force sensor senses the force being exerted on the pin during welding and produces a corresponding actual pin force signal. A probe controller controls a probe extending outwardly from the pin, senses a parameter related to the distance between the probe and the supporting anvil and produces a corresponding probe signal. A workpiece standoff sensor senses the standoff distance between the workpiece and the standoff sensor and produces a corresponding standoff signal. A control unit receives the various signals, together with a weld schedule, and, based on these signals and the weld schedule, controls the pin length controller so as to control pin penetration into the workpiece.

A compact membrane-driven diamond anvil cell and cryostat system for nuclear resonant scattering at high pressure and low temperature

DOE PAGES

Zhao, J. Y.; Bi, W.; Sinogeikin, S.; ...

2017-12-13

In order to study the vibrational and thermal dynamic properties of materials using the nuclear resonant inelastic X-ray scattering (NRIXS) and the hyperfine interactions and magnetic properties using the synchrotron Mössbauer spectroscopy (SMS) at simultaneously high pressure (multi-Mbar) and low temperature (T< 10 K), a new miniature panoramic diamond anvil cell (mini-pDAC) as well as a special gas membrane driven mechanism have been developed and implemented at 3ID, Advanced Photon Source. The gas membrane system allows in situ pressure tuning of the mini- pDAC at low temperature. The mini-pDAC fits into a specially designed compact liquid helium flow cryostat systemmore » to achieve low temperature, where liquid helium flows through the holder of the mini-pDAC to cool the sample more efficiently. The sample temperature as low as 9 K has been achieved. Through the membrane, the sample pressure as high as 1.4 Mbar has been generated from this mini-pDAC. The instrument has been routinely used at 3ID for NRIXS and SMS studies. In this paper, technical details of the mini-pDAC, membrane engaging mechanism and the cryostat system are described, and some experimental results are discussed.« less

A compact membrane-driven diamond anvil cell and cryostat system for nuclear resonant scattering at high pressure and low temperature

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhao, J. Y.; Bi, W.; Sinogeikin, S.

In order to study the vibrational and thermal dynamic properties of materials using the nuclear resonant inelastic X-ray scattering (NRIXS) and the hyperfine interactions and magnetic properties using the synchrotron Mössbauer spectroscopy (SMS) at simultaneously high pressure (multi-Mbar) and low temperature (T< 10 K), a new miniature panoramic diamond anvil cell (mini-pDAC) as well as a special gas membrane driven mechanism have been developed and implemented at 3ID, Advanced Photon Source. The gas membrane system allows in situ pressure tuning of the mini- pDAC at low temperature. The mini-pDAC fits into a specially designed compact liquid helium flow cryostat systemmore » to achieve low temperature, where liquid helium flows through the holder of the mini-pDAC to cool the sample more efficiently. The sample temperature as low as 9 K has been achieved. Through the membrane, the sample pressure as high as 1.4 Mbar has been generated from this mini-pDAC. The instrument has been routinely used at 3ID for NRIXS and SMS studies. In this paper, technical details of the mini-pDAC, membrane engaging mechanism and the cryostat system are described, and some experimental results are discussed.« less

Thermal reduction of MoO3 in sub- and supercritical water: Insights on redox conditions in Hydrothermal Diamond Anvil Cell (HDAC) experiments

NASA Astrophysics Data System (ADS)

Solferino, G.; Anderson, A. J.

2011-12-01

The Hydrothermal Diamond Anvil Cell (HDAC) is a key tool used in the study of volatile bearing melts and solute-rich fluids at the pressure and temperatures existent in the crust and shallow upper mantle (100-1500 MPa). Oxygen fugacity is among the key parameters that must be constrained in phase equilibrium and speciation studies of melt and aqueous fluid systems. It is however difficult to assess fO2 during HDAC experiments due to decomposition of water, interaction of fluid with gasket materials and the diamond themselves. In this study the temperature at which molybdenum trioxide was thermally reduced to molybdenum dioxide in the presence of deoxygenated water was measured in order to constrain the oxygen fugacity in the HDAC experiment. The sample was contained within either a rhenium gasket between two diamond anvils or within a laser-milled recess in the culet face of one of the diamond anvils (i.e. no gasket). Experiments consisted of loading a MoO3 crystal and deoxygenated water into the sample chamber and then holding the system at a temperature for the desired amount of time. MoO3 dissolved in large part or completely after 30-60 minutes at high temperature. In most experiments tugarinovite (MoO2) precipitated directly from solution once the temperature of thermal reduction was attained. MicroRaman spectroscopy was used to characterize run products. The temperature at which tugarinovite appeared varied depending on the experimental setup, and was 315 ± 2.0 °C in experiments where a gasket was used and 344 ± 2.5 °C in the experiments without a gasket. This implies that the presences of a Re gasket resulted in more reducing conditions of log(fO2) = -20.6 ± 0.5, compared to log(fO2) = -19.5 ± 0.2 for the series without gasket. Moreover, in some of the experiments performed below the transition temperature to tugarinovite, and when MoO3 crystals were not dissolved completely, an additional Raman peak at 854 cm-1 was observed that is not present in pure orthorhombic molybdite (α-MoO3). This feature, which is attributed to the presence of metastable monoclinic MoO3, is absent or poorly developed in runs where no gasket was used but was very intense in experiments where a gasket was used. According to previous studies, monoclinic MoO3 is formed in reducing conditions. The results indicate that for very simple systems, where water is the only or the dominating fluid medium, a Re gasket has a significant reducing effect on the fO2 at relatively low temperatures (200-400 °C). Furthermore, the fO2 conditions appear to be imposed (mainly) by the fluid and not by the noble metal gasket. Despite the reducing effect of the rhenium metal on the fluid, fO2 values for the Re-ReO2 buffer are much smaller than those extrapolated for our runs (i.e. log (fO2) = -27 to -29).

Modeling of Cloud/Radiation Processes for Tropical Anvils

DTIC Science & Technology

1992-11-30

absorption assumption. The band 800-980 cm-l is located in the atmospheric window, where the greenhouse effect of clouds is most pronounced. It can be...9a) is always positive, corresponding to the heating of the earth-atmosphere system due to the greenhouse effect of clouds, while the solar cloud...observed midlatitude cirrus cases, the IR greenhouse effect outweighs the solar albedo effect. The degree of the greenhouse effect involving cirrus

Pressure–Temperature Phase Diagram Reveals Spin–Lattice Interactions in Co[N(CN) 2 ] 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Musfeldt, J. L.; O’Neal, K. R.; Brinzari, T. V.

2017-04-07

Diamond anvil cell techniques, synchrotron-based infrared and Raman spectroscopies, and lattice dynamics calculations are combined with prior magnetic property work to reveal the pressure–temperature phase diagram of Co[N(CN)2]2. The second-order structural boundaries converge on key areas of activity involving the spin state exposing how the pressure-induced local lattice distortions trigger the ferromagnetic → antiferromagnetic transition in this quantum material.

Testing Machine for Biaxial Loading

NASA Technical Reports Server (NTRS)

Demonet, R. J.; Reeves, R. D.

1985-01-01

Standard tensile-testing machine applies bending and tension simultaneously. Biaxial-loading test machine created by adding two test fixtures to commercial tensile-testing machine. Bending moment applied by substrate-deformation fixture comprising yoke and anvil block. Pneumatic tension-load fixture pulls up on bracket attached to top surface of specimen. Tension and deflection measured with transducers. Modified test apparatus originally developed to load-test Space Shuttle surface-insulation tiles and particuarly important for composite structures.

Sunrise, Earth Limb, SW Pacific Ocean

NASA Technical Reports Server (NTRS)

1992-01-01

The colors of this sunrise/sunset scene provide insights into the relative density of the Earth's atmosphere (15.5S, 158.5E). This scene captures the silhouette of several thunderstorms with their cirrus anvil tops spreading out against the tropopause - the top of the lowest layer of atmosphere, the troposphere which is also the most dense and refracts light at the red end of the spectrum while the blues refract in the stratosphere, the highest layer.

Experimental and Computational Studies of Molecular and Lattice Symmetries of Energetic Materials at High Pressure

DTIC Science & Technology

2002-01-01

Prescribed by ANSI Std Z39-18 Research and Technology Department Dynamics and Diagnostics Division, Static High- Pressure Group Overall Research...Department Dynamics and Diagnostics Division, Static High- Pressure Group Impact of this Basic Research • This research generates phase and density...Static High- Pressure Group Experimental Methodology Use Diamond Anvil Cells (DAC) with coil Heaters (HDAC) to achieve • High pressures (P) to 10 GPa

X-Ray Diffraction Study of Elemental Erbium to 65 GPa

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pravica, M.G.; Lipinska-Kalita, K.; Quine, Z.

2006-02-02

We have investigated phase transitions in elemental erbium in a diamond anvil cell up to 65 GPa using x-ray powder diffraction methods. We present preliminary evidence of a series of phase transitions that appear to follow the expected hcp {yields} Sm-type {yields} dhcp {yields} distorted fcc sequence. In particular, we believe that we have evidence for the predicted dhcp {yields} distorted fcc transition between 43 GPa and 65 GPa.

Measuring refractive index and volume of liquid under high pressure with optical coherence tomography and light microscopy.

PubMed

Wang, Donglin; Yang, Kun; Zhou, Yin

2016-03-20

Measuring the refractive index and volume of liquid under high pressure simultaneously is a big challenge. This paper proposed an alternative solution by combing optical coherence tomography with microscopy. An experiment for a feasibility study was carried out on polydimethylsiloxane liquid in a diamond anvil cell. The refractive index of the sample increased dramatically with pressure loaded, and the curve of pressure volume was also obtained.

Antiaccess / Area-Denial: Old Concepts, New Frontiers

DTIC Science & Technology

2015-05-21

Vulcan’s Anvil: The American Civil War and the Foundation of the Operational Art (Fort Leavenworth, KS: U.S. Army Command and General Staff College, 2004...all elements of operational design and operational art , as well as all possible methods to exploit the operational environment considered to some...considerations in future military campaigns. Case Studies The Maginot Line Romantically dubbed the “Shield of France,” the Maginot Line included eighty-seven

Structure of Al-Fe alloys prepared by different methods after severe plastic deformation under pressure

NASA Astrophysics Data System (ADS)

Dobromyslov, A. V.; Taluts, N. I.

2017-06-01

Al-Fe alloys prepared by casting, rapid quenching from the melt, and mechanical alloying from elemental powders have been studied using X-ray diffraction analysis, optical metallography, transmission electron microscopy, and microhardness measurements in the initial state and after severe plastic deformation by high-pressure torsion using Bridgman anvils. The relationship between the phase composition, microstructure, and the microhardness of the investigated alloys has been established.

The Hammer and the Anvil: The Need for A Comprehensive Southwest Border Security Strategy

DTIC Science & Technology

2010-06-02

ublic figures voiced concern about the “war on drugs,” the right level and kind of immigration, problems along the southwest border, migration , crises...thesis, Naval Postgraduate School, 2006), 1. 27 K. Larry Stores, Mexico-U.S. Dialogue on Migration and Border Issues 2001-2005, (Washington, DC...13 Seven organized crime families operate the drug trade in and from Mexico. The Sinaloa Federation is a cocaine smuggling organization headed by

X-ray diffraction study of elemental erbium to 70 GPa

NASA Astrophysics Data System (ADS)

Pravica, Michael G.; Romano, Edward; Quine, Zachary

2005-12-01

We have investigated phase transitions in elemental erbium in a diamond anvil cell (DAC) up to 70GPa using angular-dispersive x-ray powder diffraction methods. We present evidence of a series of phase transitions that appear to follow the anticipated hcp→Sm-type→doublehcp(dhcp)→distorted fcc sequence. In particular, we present evidence for the predicted dhcp→distorted fcc transition above 63GPa . Equation of state data are also presented up to 70GPa .

Aerosol nucleation and growth in the TTL, due to tropical convection, during the ACTIVE campaign

NASA Astrophysics Data System (ADS)

Waddicor, D.; Vaughan, G.; Choularton, T.

2009-04-01

The Aerosol and Chemical Transport In tropical convection (ACTIVE) campaign took place between October 2005 and February 2006. This investigation involved the sampling of deep convective storms that occur in the Tropics; the campaign was based in Darwin, Northern Territory, Australia - the latter half of the campaign coincided with the monsoon season. A range of scientific equipment was used to sample the inflow and outflow air from these storms; of particular importance were the NERC Dornier (low-level) and ARA Egrett (high-level outflow) aircraft. The Dornier held a range of aerosol, particle and chemical detectors for the purpose of analysing the planetary boundary layer (PBL), in the vicinity of tropical convection. The Egrett contained detection instrumentation for a range of sizes of aerosol and cloud particles (2 Condensation Particle Counters (CPC), CAPS, CIP, CPI) in the storm outflow. This allowed a quantifiable measurement to be made of the effect of deep tropical convection on the aerosol population in the Tropical Tropopause Layer (TTL). The ACTIVE campaign found that there were large numbers of aerosol particles in the 10 - 100 nm (up to 25,000 /cm3 STP) and 100 - 1000 nm (up to 600 /cm3) size ranges. These values, in many instances, surpassed those found in the PBL. The higher levels of aerosol found in the TTL compared to the PBL could indicate that aerosol nucleation was occurring in the TTL as a direct result of convective activity. Furthermore, the Egrett aircraft found distinct boundaries between the high levels of aerosol, which were found in cloud free regions, and very low numbers of aerosol, which were found in the cloudy regions (storm anvil). The air masses were determined, from back trajectories, to have been through convective uplift and were formerly part of the anvil cloud. The cloudy regions would have contained high levels of entrapped precursor gases. Reduced nucleation and cloud particle scavenging of aerosol and gases would give a much reduced aerosol number concentration in cloud. The high aerosol (cloud free) areas would appear after the cloud began to evaporate through the process of aerosol nucleation. The evaporating cloud particles and reduced cloud surface area would allow aerosol nucleation to occur - typically involving sulphuric acid and water, released from ice crystals. The time scales for the particle production have also been investigated using satellite and wind projections/ECMWF back trajectories.

Hydrothermal diamond-anvil cell: Application to studies of geologic fluids

USGS Publications Warehouse

Chou, I.-Ming

2003-01-01

The hydrothermal diamond-anvil cell (HDAC) was designed to simulate the geologic conditions of crustal processes in the presence of water or other fluids. The HDAC has been used to apply external pressure to both synthetic and natural fluid inclusions in quartz to minimize problems caused by stretching or decrepitation of inclusions during microthermometric analysis. When the HDAC is loaded with a fluid sample, it can be considered as a large synthetic fluid inclusion and therefore, can be used to study the PVTX properties as well as phase relations of the sample fluid. Because the HDAC has a wide measurement pressure-temperature range and also allows in-situ optical observations, it has been used to study critical phenomena of various chemical systems, such as the geologically important hydrous silicate melts. It is possible, when the HDAC is combined with synchrotron X-ray sources, to obtain basic information on speciation and structure of metal including rare-earth elements (REE) complexes in hydrothermal solutions as revealed by X-ray absorption fine structure (XAFS) spectra. Recent modifications of the HDAC minimize the loss of intensity of X-rays due to scattering and absorption by the diamonds. These modifications are especially important for studying elements with absorption edges below 10 keV and therefore particularly valuable for our understanding of transport and deposition of first-row transition elements and REE in hydrothermal environments.

Cloud feedback mechanisms and their representation in global climate models

DOE PAGES

Ceppi, Paulo; Brient, Florent; Zelinka, Mark D.; ...

2017-05-11

Cloud feedback—the change in top-of-atmosphere radiative flux resulting from the cloud response to warming—constitutes by far the largest source of uncertainty in the climate response to CO 2 forcing simulated by global climate models (GCMs). In this paper, we review the main mechanisms for cloud feedbacks, and discuss their representation in climate models and the sources of intermodel spread. Global-mean cloud feedback in GCMs results from three main effects: (1) rising free-tropospheric clouds (a positive longwave effect); (2) decreasing tropical low cloud amount (a positive shortwave [SW] effect); (3) increasing high-latitude low cloud optical depth (a negative SW effect). Thesemore » cloud responses simulated by GCMs are qualitatively supported by theory, high-resolution modeling, and observations. Rising high clouds are consistent with the fixed anvil temperature (FAT) hypothesis, whereby enhanced upper-tropospheric radiative cooling causes anvil cloud tops to remain at a nearly fixed temperature as the atmosphere warms. Tropical low cloud amount decreases are driven by a delicate balance between the effects of vertical turbulent fluxes, radiative cooling, large-scale subsidence, and lower-tropospheric stability on the boundary-layer moisture budget. High-latitude low cloud optical depth increases are dominated by phase changes in mixed-phase clouds. Finally, the causes of intermodel spread in cloud feedback are discussed, focusing particularly on the role of unresolved parameterized processes such as cloud microphysics, turbulence, and convection.« less

Cloud feedback mechanisms and their representation in global climate models

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ceppi, Paulo; Brient, Florent; Zelinka, Mark D.

Cloud feedback—the change in top-of-atmosphere radiative flux resulting from the cloud response to warming—constitutes by far the largest source of uncertainty in the climate response to CO 2 forcing simulated by global climate models (GCMs). In this paper, we review the main mechanisms for cloud feedbacks, and discuss their representation in climate models and the sources of intermodel spread. Global-mean cloud feedback in GCMs results from three main effects: (1) rising free-tropospheric clouds (a positive longwave effect); (2) decreasing tropical low cloud amount (a positive shortwave [SW] effect); (3) increasing high-latitude low cloud optical depth (a negative SW effect). Thesemore » cloud responses simulated by GCMs are qualitatively supported by theory, high-resolution modeling, and observations. Rising high clouds are consistent with the fixed anvil temperature (FAT) hypothesis, whereby enhanced upper-tropospheric radiative cooling causes anvil cloud tops to remain at a nearly fixed temperature as the atmosphere warms. Tropical low cloud amount decreases are driven by a delicate balance between the effects of vertical turbulent fluxes, radiative cooling, large-scale subsidence, and lower-tropospheric stability on the boundary-layer moisture budget. High-latitude low cloud optical depth increases are dominated by phase changes in mixed-phase clouds. Finally, the causes of intermodel spread in cloud feedback are discussed, focusing particularly on the role of unresolved parameterized processes such as cloud microphysics, turbulence, and convection.« less

Earth, soil and environmental science research facility at sector 13 of the Advanced Photon Source. II. Scientific program and experimental instrumentation (abstract)

NASA Astrophysics Data System (ADS)

Sutton, S.; Eng., P. J.; Jaski, Y. R.; Lazaraz, N.; Pluth, J.; Murray, P.; Rarback, H.; Rivers, M.

1996-09-01

The GSECARS (APS sector 13) scientific program will provide fundamental new information on the deep structure and composition of the Earth and other planets, the formation of economic mineral deposits, the cycles and fate of toxic metals in the environment, and the mechanisms of nutrient uptake and disease in plants. In the four experimental stations (2 per beamline), scientists will have access to three main x-ray techniques: diffraction (microcrystal, powder, diamond anvil cell, and large volume press), fluorescence microprobe, and spectroscopy (conventional, microbeam, liquid and solid surfaces). The high pressure facilities will be capable of x-ray crystallography at P≳360 GPa and T˜6000 K with the diamond anvil cell and P˜25 GPa and T˜2500 °C with the large volume press. Diffractometers will allow study of 1 micrometer crystals and micro-powders. The microprobe (1 micrometer focused beam) will be capable of chemical analyses in the sub-ppm range using wavelength and energy dispersive detectors. Spectroscopy instrumentation will be available for XANES and EXAFS with microbeams as well as high sensitivity conventional XAS and studies of liquid and solid interfaces. Visiting scientists will be able to setup, calibrate, and test experiments in off-line laboratories with equipment such as micromanipulators, optical microscopes, clean bench, glove boxes, high powered optical and Raman spectrometers.

Evidence for Tropopause Layer Moistening by Convection During CRYSTAL-FACE

NASA Technical Reports Server (NTRS)

Ackerman, A.; Fridlind, A.; Jensen, E.; Miloshevich, L.; Heymsfield, G.; McGill, M.

2003-01-01

Measurements and analysis of the impact of deep convection on tropopause layer moisture are easily confounded by difficulties making precise observations with sufficient spatial coverage before and after convective events and difficulties distinguishing between changes due to local convection versus large-scale advection. The interactions between cloud microphysics and dynamics in the convective transport of moisture into the tropopause layer also result in a sufficiently complex and poorly characterized system to allow for considerable freedom in theoretical models of stratosphere-troposphere exchange. In this work we perform detailed large-eddy simulations with an explicit cloud microphysics model to study the impact of deep convection on tropopause layer moisture profiles observed over southern Florida during CRYSTALFACE. For four days during the campaign (July 11, 16, 28, and 29) we initialize a 100-km square domain with temperature and moisture profiles measured prior to convection at the PARSL ground site, and initiate convection with a warm bubble that produces an anvil at peak elevations in agreement with lidar and radar observations on that day. Comparing the moisture field after the anvils decay with the initial state, we find that convection predominantly moistens the tropopause layer (as defined by minimum temperature and minimum potential temperature lapse rate), although some drying is also predicted in localized layers. We will also present results of sensitivity tests designed to separate the roles of cloud microphysics and dynamics.

Improved Tensile Adhesion Specimens for High Strength Epoxy Systems in Aerospace Applications

NASA Technical Reports Server (NTRS)

Haddock, M. Reed; McLennan, Michael L.

2000-01-01

An improved tensile adhesion button has been designed and tested that results in higher measured tensile adhesion strength while providing increased capability for testing high strength epoxy adhesive systems. The best attributes of two well-established tensile button designs were combined and refined into an optimized tensile button. The most significant design change to the tensile button was to improve alignment of the bonded tensile button specimens during tensile testing by changing the interface between the tensile button and the tensile test machine. The established or old button design uses a test fixture that pulls from a grooved annulus or anvil head while the new button design pulls from a threaded hole in the centerline of the button. Finite element (FE) analysis showed that asymmetric loading of the established anvil head tensile button significantly increases the stress concentration in the adhesive, causing failure at lower tensile test loads. The new tensile button was designed to eliminate asymmetric loading and eliminate misalignment sensitivity. Enhanced alignment resulted in improved tensile adhesion strength measurement up to 13.8 MPa (2000psi) over the established button design. Another design change increased the capability of the button by increasing the threaded hole diameter allowing it to test high strength epoxy systems up to 85 MPa(less than 12,000 psi). The improved tensile button can be used in button- to-button or button-to-panel configurations.

Climate Variability during the TRMM Era: Relationships between TRMM Precipitation and Upper-Tropospheric Hydrometeors

NASA Technical Reports Server (NTRS)

Robertson, Franklin

2008-01-01

Tropical rainfall as seen by the TRMM radar has multiple scales of organization, one prominent example of which is mesoscale deep convection that supports the production of strong, widespread anvil systems important to the planet's water and energy balance. TRMM PR precipitation retrievals (i.e. the 2A25 algorithm) are reliable down to rates below 1.0 mm/h which captures the majority of near-surface rainfall. However, much of the precipitating hydrometeor mass above the freezing level in these anvil systems may be associated with particles where TRMM PR s/n is low. In out analysis we are examining the question of 'What portions of the total hydrometeor spectrum can we see individually with TRMM, CloudSat, high frequency passive microwave (e.g. AMSU-B, MHS) and MODIS'. This will allow us to pursue fundamental issues of precipitation, efficiency, maintenance of upper-troposheric humidity, and cloud forcing variability in the tropical climate system. We do this by generating frequency distributions of ice water content (IWC), integrated IWC (IWP), and precipitation as appropriate for these sensors and relate these to TRMM near-surface rainfall. Joint frequency distributions are developed from more limited coincidence between TRMM and these sensors. We interpret these results in terms of a climate regime descriptor and as an index of precipitation efficiency for tropical rain systems.

Relationships Between TRMM Precipitation and Upper-Tropospheric Hydrometeors as Seen From AMSU-B/MHS and A-Train Sensors

NASA Technical Reports Server (NTRS)

Robertson, Franklin; Pittman, Jasna; Atkinson, Robert

2008-01-01

Tropical rainfall as seen by the TRMM radar has multiple scales of organization, one prominent example of which is mesoscale deep convection that supports the production of strong, widespread anvil systems important to the planet's water and energy balance. TRMM PR precipitation retrievals (i.e. the 2A25 algorithm) are reliable down to rates below 1.0 mm/h which captures the majority of near-surface rainfall. However, much of the precipitating hydrometeor mass above the freezing level in these anvil systems may be associated with particles where TRMM PR s/n is low. In our analysis we are examining the question of "What portions of the total hydrometeor spectrum can we see individually with TRMM, CloudSat, high frequency passive microwave (e.g. AMSU-B, MHS) and MODIS". This will allow us to pursue fundamental issues of precipitation efficiency, maintenance of upper-tropospheric humidity, and cloud forcing variability in the tropical climate system. We do this by generating frequency distributions of ice water content (IWC), integrated IWC (IWP), and precipitation as appropriate for these sensors and relate these to TRMM near-surface rainfall. Joint frequency distributions are developed from more limited coincidence between TRMM and these sensors. We interpret these results in terms of a climate regime descriptor and as an index of precipitation efficiency for tropical rain systems.

A quenchable superhard carbon phase synthesized by cold compression of carbon nanotubes.

PubMed

Wang, Zhongwu; Zhao, Yusheng; Tait, Kimberly; Liao, Xiaozhou; Schiferl, David; Zha, Changsheng; Downs, Robert T; Qian, Jiang; Zhu, Yuntian; Shen, Tongde

2004-09-21

A quenchable superhard high-pressure carbon phase was synthesized by cold compression of carbon nanotubes. Carbon nanotubes were placed in a diamond anvil cell, and x-ray diffraction measurements were conducted to pressures of approximately 100 GPa. A hexagonal carbon phase was formed at approximately 75 GPa and preserved at room conditions. X-ray and transmission electron microscopy electron diffraction, as well as Raman spectroscopy at ambient conditions, explicitly indicate that this phase is a sp(3)-rich hexagonal carbon polymorph, rather than hexagonal diamond. The cell parameters were refined to a(0) = 2.496(4) A, c(0) = 4.123(8) A, and V(0) = 22.24(7) A (3). There is a significant ratio of defects in this nonhomogeneous sample that contains regions with different stacking faults. In addition to the possibly existing amorphous carbon, an average density was estimated to be 3.6 +/- 0.2 g/cm(3), which is at least compatible to that of diamond (3.52 g/cm(3)). The bulk modulus was determined to be 447 GPa at fixed K' identical with 4, slightly greater than the reported value for diamond of approximately 440-442 GPa. An indented mark, along with radial cracks on the diamond anvils, demonstrates that this hexagonal carbon is a superhard material, at least comparable in hardness to cubic diamond.

A quenchable superhard carbon phase synthesized by cold compression of carbon nanotubes

PubMed Central

Wang, Zhongwu; Zhao, Yusheng; Tait, Kimberly; Liao, Xiaozhou; Schiferl, David; Zha, Changsheng; Downs, Robert T.; Qian, Jiang; Zhu, Yuntian; Shen, Tongde

2004-01-01

A quenchable superhard high-pressure carbon phase was synthesized by cold compression of carbon nanotubes. Carbon nanotubes were placed in a diamond anvil cell, and x-ray diffraction measurements were conducted to pressures of ≈100 GPa. A hexagonal carbon phase was formed at ≈75 GPa and preserved at room conditions. X-ray and transmission electron microscopy electron diffraction, as well as Raman spectroscopy at ambient conditions, explicitly indicate that this phase is a sp3-rich hexagonal carbon polymorph, rather than hexagonal diamond. The cell parameters were refined to a0 = 2.496(4) Å, c0 = 4.123(8) Å, and V0 = 22.24(7) Å 3. There is a significant ratio of defects in this nonhomogeneous sample that contains regions with different stacking faults. In addition to the possibly existing amorphous carbon, an average density was estimated to be 3.6 ± 0.2 g/cm3, which is at least compatible to that of diamond (3.52 g/cm3). The bulk modulus was determined to be 447 GPa at fixed K′≡4, slightly greater than the reported value for diamond of ≈440–442 GPa. An indented mark, along with radial cracks on the diamond anvils, demonstrates that this hexagonal carbon is a superhard material, at least comparable in hardness to cubic diamond. PMID:15361581

Density Determination of Metallic Melts from Diffuse X-Ray Scattering

NASA Astrophysics Data System (ADS)

Brauser, N.; Davis, A.; Greenberg, E.; Prakapenka, V. B.; Campbell, A.

2017-12-01

Liquids comprise several important structural components of the deep Earth, for example, the present outer core and a hypothesized magma ocean early in Earth history. However, the physical properties of the constituent materials of these structures at high pressures and temperatures are less well constrained than their crystalline counterparts. Determination of the physical properties of these liquids can inform geophysical models of the composition and structure of the Earth, but methods for studying the physical properties of liquids at high pressure and temperatures are underdeveloped. One proposed method for direct determination of density of a melt requires analysis of the diffuse scattered X-ray signal of the liquid. Among the challenges to applying this technique to high-pressure melts within a laser heated diamond anvil cell are the low signal-to-noise ratio and overlapping diffraction peaks from the crystalline components of the sample assembly interfering with the diffuse scattering from the liquid. Recent advances in instrumentation at synchrotron X-ray sources have made this method more accessible for determination of density of melted material. In this work we present the technique and report the densities of three high-pressure melts of the FCC metals iron, nickel, and gold derived from diffuse scattered X-ray spectra collected from in situ laser-heated diamond anvil cell synchrotron experiments. The results are compared to densities derived from shock wave experiments.

Determining the Best Method for Estimating the Observed Level of Maximum Detrainment Based on Radar Reflectivity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Carletta, Nicholas D.; Mullendore, Gretchen L.; Starzec, Mariusz

Convective mass transport is the transport of mass from near the surface up to the upper troposphere and lower stratosphere (UTLS) by a deep convective updraft. This transport can alter the chemical makeup and water vapor balance of the UTLS, which affects cloud formation and the radiative properties of the atmosphere. It is therefore important to understand the exact altitudes at which mass is detrained from convection. The purpose of this study was to improve upon previously published methodologies for estimating the level of maximum detrainment (LMD) within convection using data from a single ground-based radar. Four methods were usedmore » to identify the LMD and validated against dual-Doppler derived vertical mass divergence fields for six cases with a variety of storm types. The best method for locating the LMD was determined to be the method that used a reflectivity texture technique to determine convective cores and a multi-layer echo identification to determine anvil locations. Although an improvement over previously published methods, the new methodology still produced unreliable results in certain regimes. The methodology worked best when applied to mature updrafts, as the anvil needs time to grow to a detectable size. Thus, radar reflectivity is found to be valuable in estimating the LMD, but storm maturity must also be considered for best results.« less

Structural Mineral Physics at Extreme Conditions

NASA Astrophysics Data System (ADS)

Chariton, S.; Dubrovinsky, L. S.; Dubrovinskaia, N.

2017-12-01

Laser heating techniques in diamond anvil cells (DACs) cover a wide pressure-temperature range - above 300 GPa and up to 5000 K. Recent advantages in on-line laser heating techniques resulted in a significant improvement of reliability of in situ X-ray powder diffraction studies in laser-heated DACs, which have become routine at a number of synchrotron facilities including specialized beam-lines at the 3rd generation synchrotrons. However, until recently, existing DAC laser-heating systems could not be used for structural X-ray diffraction studies aimed at structural refinements, i.e. measuring of the diffraction intensities, and not only at determining of lattice parameters. The reason is that in existing DAC laser-heating facilities the laser beam enters the cell at a fixed angle, and a partial rotation of the DAC, as required in monochromatic structural X-ray diffraction experiments, results in a loss of the target crystal and may be even dangerous if the powerful laser light starts to scatter in arbitrary directions by the diamond anvils. In order to overcome this problem we have develop a portable laser heating system and implement it at different diffraction beam lines. We demonstrate the application of this system for simultaneous high-pressure and high-temperature powder and single crystal diffraction studies using examples of studies of chemical and phase relations in the Fe-O system, transition metals carbonates, and silicate perovskites.

Local structure of solid Rb at megabar pressures

DOE Office of Scientific and Technical Information (OSTI.GOV)

De Panfilis, S.; Gorelli, F.; Santoro, M.

2015-06-07

We have investigated the local and electronic structure of solid rubidium by means of x-ray absorption spectroscopy up to 101.0 GPa, thus doubling the maximum investigated experimental pressure. This study confirms the predicted stability of phase VI and was completed by the combination of two pivotal instrumental solutions. On one side, we made use of nanocrystalline diamond anvils, which, contrary to the more commonly used single crystal diamond anvils, do not generate sharp Bragg peaks (glitches) at specific energies that spoil the weak fine structure oscillations in the x-ray absorption cross section. Second, we exploited the performance of a state-of-the-artmore » x-ray focussing device yielding a beam spot size of 5 × 5 μm{sup 2}, spatially stable over the entire energy scan. An advanced data analysis protocol was implemented to extract the pressure dependence of the structural parameters in phase VI of solid Rb from 51.2 GPa up to the highest pressure. A continuous reduction of the nearest neighbour distances was observed, reaching about 6% over the probed pressure range. We also discuss a phenomenological model based on the Einstein approximation to describe the pressure behaviour of the mean-square relative displacement. Within this simplified scheme, we estimate the Grüneisen parameter for this high pressure Rb phase to be in the 1.3–1.5 interval.« less

Guided earth boring tool

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mc Donald, W.J.; Pittard, G.T.; Maurer, W.C.

A controllable tool for drilling holes in the earth is described comprising a hollow elongated rigid supporting drill pipe having a forward end for entering the earth, means supporting the drill pipe for earth boring or piercing movement, including means for moving the drill pipe longitudinally for penetrating the earth, the drill pipe moving means being constructed to permit addition and removal of supporting drill pipe during earth penetrating operation, a boring mole supported on the forward end of the hollow low drill pipe comprising a cylindrical housing supported on and open to the forward end of the drill pipe,more » a first means on the front end for applying a boring force to the soil comprising an anvil having a striking surface inside the housing and a boring surface outside the housing, a second means comprising a reciprocally movable hammer positioned in the housing to apply a percussive force to the anvil striking surface for transmitting a percussive force to the boring force applying means, and means permitting introduction of air pressure supplied through the hollow pipe into the housing for operating the hammer and for discharging spent air from the housing to the hole being bored, and the tool being operable to penetrate the earth upon longitudinal movement of the drill rod by the longitudinal rod moving means and operation of the mole by reciprocal movement of the hammer.« less

Non-linear optical techniques and optical properties of condensed molecular systems

NASA Astrophysics Data System (ADS)

Citroni, Margherita

2013-06-01

Structure, dynamics, and optical properties of molecular systems can be largely modified by the applied pressure, with remarkable consequences on their chemical stability. Several examples of selective reactions yielding technologically attractive products can be cited, which are particularly efficient when photochemical effects are exploited in conjunction with the structural conditions attained at high density. Non-linear optical techniques are a basic tool to unveil key aspects of the chemical reactivity and dynamic properties of molecules. Their application to high-pressure samples is experimentally challenging, mainly because of the small sample dimensions and of the non-linear effects generated in the anvil materials. In this talk I will present results on the electronic spectra of several aromatic crystals obtained through two-photon induced fluorescence and two-photon excitation profiles measured as a function of pressure (typically up to about 25 GPa), and discuss the relationship between the pressure-induced modifications of the electronic structure and the chemical reactivity at high pressure. I will also present the first successful pump-probe infrared measurement performed as a function of pressure on a condensed molecular system. The system under examination is liquid water, in a sapphire anvil cell, up to 1 GPa along isotherms at 298 and 363 K. These measurements give a new enlightening insight into the dynamical properties of low- and high-density water allowing a definition of the two structures.

AC calorimetry of H2O at pressures up to 9 GPa in diamond anvil cells

NASA Astrophysics Data System (ADS)

Geballe, Zachary M.; Struzhkin, Viktor V.

2017-06-01

If successfully developed, calorimetry at tens of GPa of pressure could help characterize phase transitions in materials such as high-pressure minerals, metals, and molecular solids. Here, we extend alternating-current calorimetry to 9 GPa and 300 K in a diamond anvil cell and use it to study phase transitions in H2O. In particular, water is loaded into the sample chambers of diamond-cells, along with thin metal heaters (1 μm-thick platinum or 20 nm-thick gold on a glass substrate) that drive high-frequency temperature oscillations (20 Hz to 600 kHz; 1 to 10 K). The heaters also act as thermometers via the third-harmonic technique, yielding calorimetric data on (1) heat conduction to the diamonds and (2) heat transport into substrate and sample. Using this method during temperature cycles from 300 to 200 K, we document melting, freezing, and proton ordering and disordering transitions of H2O at 0 to 9 GPa, and characterize changes in thermal conductivity and heat capacity across these transitions. The technique and analysis pave the way for calorimetry experiments on any non-metal at pressures up to ˜100 GPa, provided a thin layer (several μm-thick) of thermal insulation supports a metallic thin-film (tens of nm thick) Joule-heater attached to low contact resistance leads inside the sample chamber of a diamond-cell.

Formation of a metastable hollandite phase from amorphous plagioclase: A possible origin of lingunite in shocked chondritic meteorites

NASA Astrophysics Data System (ADS)

Kubo, Tomoaki; Kono, Mari; Imamura, Masahiro; Kato, Takumi; Uehara, Seiichiro; Kondo, Tadashi; Higo, Yuji; Tange, Yoshinori; Kikegawa, Takumi

2017-11-01

We conducted high-pressure experiments in plagioclase with different anorthite contents at 18-27 GPa and 25-1750 °C using both a laser-heated diamond anvil cell and a Kawai-type multi-anvil apparatus to clarify the formation conditions of the hollandite phase in shocked chondritic and Martian meteorites. Lingunite (NaAlSi3O8-rich hollandite) was found first to crystallize from amorphous oligoclase as a metastable phase before decomposing into the final stable state. This process might account for the origin of lingunite found along with maskelynite in shocked chondritic meteorites. Metastable lingunite appeared at ∼20-24 GPa and ∼1100-1300 °C in laboratory tests lasting tens of minutes; however, it might also form at the higher temperatures and shorter time periods of shock events. In contrast, the hollandite phase was not observed during any stage of crystallization when using albite or labradorite as starting materials. The formation process of (Ca,Na)-hollandite in the labradorite composition found in Martian shergottites remains unresolved. The orthoclase contents of the hollandite phase both in shocked meteorites (2.4-8.2 mol%) and our oligoclase sample (3.9 mol%) are relatively high compared to the albite and labradorite samples (0.6 and 1.9 mol%, respectively). This might critically affect the crystallization kinetics of hollandite phase.

Experimental studies of transplutonium metals and compounds under pressure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peterson, J.R.; Haire, R.G.; Benedict, U.

1986-01-01

The structural behavior of the first four transplutonium metals and two Bk-Cf alloys as a function of pressure has been studied in diamond anvil cells via x-ray diffraction. The sequence of structures exhibited as pressure is increased is dhcp ..-->.. ccp ..-->.. orthorhombic. In addition a distorted ccp phase is observed in Am, Bk/sub 0.40/Cf/sub 0.60/, and Cf between the ccp and orthorhombic phases. Diamond anvil cells have also been used to contain AmI/sub 3/, CfBr/sub 3/, and CfCl/sub 3/ under pressure for investigation by absorption spectrophotometry. Both AmI/sub 3/ and CfBr/sub 3/ exhibit pressure-induced, irreversible phase transformations to themore » PuBr/sub 3/-type orthorhombic structure, a more dense form of these compounds. Thus the driving force for these transformations is more efficient crystal packing. Both hexagonal (to 22 GPa) and orthorhombic (to 35 GPa) CfCl/sub 3/ exhibit only reversible spectral changes with pressure. This probably reflects their nearly identical RTP unit cell volumes. In both cases the spectra obtained are consistent with a continuous alteration of the RTP structure with pressure; physical compression seems to make a given f-f transition easier. Additional data are being sought to elucidate more completely the behavior of CfCl/sub 3/ under pressure. 23 refs., 4 figs.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bass, Jay D.

This project is aimed at experimental characterization of the sound velocities, equations of state (EOS), and derived physical and chemical properties of aqueous solutions and carbon dioxide at extreme pressure and temperature conditions relevant to processes occurring in the interior of the Earth. Chemical transport, phase changes (including melting), fluid-solid reactions, and formation of magmatic liquids at convergent plat boundaries are a key motivation for this project. Research in this area has long been limited by the extreme experimental challenges and lack of data under the appropriate pressure-temperature (P-T) conditions. The vast majority of studies of aqueous geochemistry relevant tomore » terrestrial problems of fluid-rock interactions have been conducted at 0.3 GPa or less, and the widely used Helgeson-Kirkham-Flowers equation of state for aqueous species is applicable only at ~ < 0.5 GPa. These limits are unfortunate because fluid flow and reactions plays a central role in many deeper environments. Recent efforts including our own, have resulted in new experimental techniques that now make it possible to investigate properties of homogeneous and heterogeneous equilibria involving aqueous species and minerals over a much broader range of pressure and temperature appropriate for deep crustal and upper mantle processes involving water-rich fluids. We carried out 1) Brillouin scattering measurements of the equations of state and molar volume of water and carbon dioxide to over 10 GPa and 870K using precise resistance heating of samples under pressure in the diamond anvil cell, and 2) the phase diagrams of the water and CO2, and 3) Exploring new experimental approaches, including CO2 laser heating of samples in a diamond cell, to measurements of sound velocities, EOS, and phase relations by Brillouin scattering to far greater pressures and temperatures.« less

Combined Determination of Elastic Properties and Structure of Coesite under Simulated Mantle Conditions

NASA Astrophysics Data System (ADS)

Mueller, H. J.; Schilling, F. R.; Lauterjung, J.; Lathe, C.

2001-12-01

The high pressure SiO2-polymorph coesite seems to be an important mineral in the subduction process including crustal material (Chopin, 1984; Schreyer, 1995). The quartz to coesite transition is thus of fundamental importance to understand the processes within a subducting crust. Furthermore, the nature of the quartz to coesite transition is discussed controversially, because high pressure XRD-studies suggest an intermediate phase during the transformation process (Zinn et al., 1997). For the combined determination of elastic properties and structure a cubic multi-anvil high pressure apparatus (MAX80) was used. For the maximum sample volume of 20 mm3 the pressure limit is about 7GPa. The pressure is measured by use of NaCl as an internal pressure marker with calibrated PVT-data. The maximum temperature of about 2,000K is generated by an internal graphite heater and controlled by a thermocouple. The synchrotron beam (100x100 microns) is guided by a collimator through the sample between the anvils. For energy-dispersive X-ray diffraction, a Ge-solid state detector analyses the diffracted white beam at a fixed angle. The compressional and shear wave velocities were determined simultaneously by ultrasonic interferometry inside MAX80. Two of the six anvils are equipped with overtone polished lithium niobate transducers at their rear side, outside the volume under pressure, for generation and detection of ultrasonic waves between 10 and 60 MHz. Different buffer - reflector combinations and transducer arrangements were used to optimize the critical interference between both sample echoes. Therefore MAX80 is equipped for asymmetrical and symmetrical interferometric set-ups, i.e. compressional and shear waves are generated from the same or from two anvils, opposite to each other. We used for our transient measurements 3 natural fine-grained quartzites from Turkey and Germany. As a first step the pressure was increased gradually up to 4GPa at ambient temperature. At each pressure Vp and Vs was measured by ultrasonic interferometry. After reaching a given pressure, temperature was increased. At 4.5GPa and 800\\deg C the phase transition to coesite took place in less than 2 minutes. The fast kinetic of transformation was observed by synchrotron radiation. The compressional wave velocity increased by 30% and the shear wave velocity by 10% during the phase transition. The kinetic of the transition was varied by choosing different pressure and temperature conditions. The transformation with lower kinetic was studied in detail by XRD and ultrasonic interferometry. At 4.2 GPa the transformation could not be observed even above 950\\deg C. At 4.5 GPa and 750\\deg C the transition stopped at about 50% transformation, but transforms complete while increasing temperature to 800\\deg C. After the phase transition monitored by X-ray scattering the sample was quenched and Vp and Vs of coesite was measured at ambient temperatures up to the maximum pressure. Small differences in grain size, shape and in minor graphite contents did not change systematically the PT-conditions and kinetics. In addition to the kinetic and change of elastic properties the pressure and temperature derivatives of elastic properties of coesite will be presented.\\Chopin, C., Contr. Min. Petrol., 86 (1984), 107-118\\Schreyer, W., J. Geophys. Res., 100 (1995), 8,353-8,366\\Zinn P., Lauterjung J., Wirth R. & Hinze E. Zeitschrift für Kristallographie, 212 (1997), 691-698.

Operation ANVIL/DRAGOON: The Invasion of Southern France, Offensive, Deliberate Assault, Amphibious, 15 August-1 September 1944

DTIC Science & Technology

1984-05-01

QUADRANT —where it was agreed a diversionary attack -for OVERLORD would take place in southern France. The operation, as proposed by the Americans...diversionary attack in southern France was codified by the American and British leadership at QUADRANT , the issue was again heavily debated by the "Big...the outcome at the war. Ore can ssv that the outcome ot the war in Europa was decided when operation OVERLORD was approved ior execution. The battle

Modeling of Cloud/Radiation Processes for Large-Scale Clouds and Tropical Anvils

DTIC Science & Technology

1994-05-31

Bergeron- Findeisen process. The saturation vapor pressure over ice is less than 2.4. Radiative transfer parameterization that over water. As a result, ice...nucleation to generate ice dN ) ’- if T>- -20 0C crystals, depositional growth to simulate the T•’= 0j At (3.7) Bergeron- Findeisen process, sublimation...and (0 if T< - 200C. melting of ice crystals, and gravitational settling to deplete the ice crystals. The Bergeron- Findeisen Here, N, +,,, and N, are

Achieving high-density states through shock-wave loading of precompressed samples

PubMed Central

Jeanloz, Raymond; Celliers, Peter M.; Collins, Gilbert W.; Eggert, Jon H.; Lee, Kanani K. M.; McWilliams, R. Stewart; Brygoo, Stéphanie; Loubeyre, Paul

2007-01-01

Materials can be experimentally characterized to terapascal pressures by sending a laser-induced shock wave through a sample that is precompressed inside a diamond-anvil cell. This combination of static and dynamic compression methods has been experimentally demonstrated and ultimately provides access to the 10- to 100-TPa (0.1–1 Gbar) pressure range that is relevant to planetary science, testing first-principles theories of condensed matter, and experimentally studying a new regime of chemical bonding. PMID:17494771

[Simulated used of the "grasping tie" as in esophago-jejunostomy after total gastrectomy].

PubMed

Picardi, Nicola

2003-01-01

Simulated test of effectiveness of the original tool grasping tie--technically already illustrated in a former paper listed in bibliography--for fixing a spongy rubber tube simulating an oesophagus on a circular stapler head axis, by tightening over it a nylon ribbon slip-knot (the tie). After connecting the head to the stapler anvil through an other spongy rubber tube simulating a jejunal loop, and the firing of the stapler, it is demonstrated the correct circular anastomosis achievable.

USSR Report, Military Affairs, No. 1794

DTIC Science & Technology

1983-09-14

by the rifle were developed by the Dinamit Nobel firm. The cartridge consists of a bullet, powder charge, anvil, and primer. The powder charge is...made from powder with higher ignition temper- ature (100 degrees centigrade higher than gun cotton powder ). It is made in the form of a 21 mm high...seat A-10B trainers. Deployment of the wing at Eielson, which is located near the gar - risons of the main forces of the U. S. Army contingent in Alaska

Raman spectroscopic study of DL valine under pressure up to 20 GPa

NASA Astrophysics Data System (ADS)

Rêgo, F. S. C.; Lima, J. A.; Freire, P. T. C.; Melo, F. E. A.; Mendes Filho, J.; Polian, A.

2016-04-01

DL-valine crystal was studied by Raman spectroscopy under hydrostatic pressure using a diamond anvil cell from ambient pressure up to 19.4 GPa in the spectral range from 40 to 3300 cm-1. Modifications in the spectra furnished evidence of the occurrence of two structural phase transitions undergone by this racemic amino acid crystal. The classification of the vibrational modes, the behavior of their wavenumber as a function of the pressure and the reversibility of the phase transitions are discussed.

Static high-pressure structural studies on Dy to 119 GPa

NASA Astrophysics Data System (ADS)

Patterson, Reed; Saw, Cheng K.; Akella, Jagannadham

2004-05-01

Structural phase transitions in the rare-earth metal dysprosium have been studied in a diamond anvil cell to 119 GPa by x-ray diffraction. Four transformations following the sequence hcp→Sm-type→dhcp→hR24 (hexagonal)→bcm (monoclinic) are observed at 6, 15, 43, and 73 GPa, respectively. The hexagonal to monoclinic transformation is accompanied by a 6% reduction in volume, which is attributed to delocalization of the 4f electrons, similar to that seen in Ce, Pr, and Gd.

X-ray diffraction study of elemental erbium to 70 GPa

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pravica, Michael G.; Romano, Edward; Quine, Zachary

2005-12-01

We have investigated phase transitions in elemental erbium in a diamond anvil cell (DAC) up to 70 GPa using angular-dispersive x-ray powder diffraction methods. We present evidence of a series of phase transitions that appear to follow the anticipated hcp{yields}Sm-type{yields}double hcp (dhcp){yields}distorted fcc sequence. In particular, we present evidence for the predicted dhcp{yields}distorted fcc transition above 63 GPa. Equation of state data are also presented up to 70 GPa.

Translations on Near East and North Africa, Number 1635, Background to May 1977 Israeli Geneal Electrions

DTIC Science & Technology

1977-04-04

the spirit of the social humanism of the 20th Century. The liberalism of the Democratic Movement for Change is according to the clas- sic model of...prime minister to have superior power, like a ministering angel, in any case, to be without any human weakness. Among other things, these general...them from a precious human reservoir, had afforded them a space in which to function, had provided them with an anvil for their hammer--now

Pressure-induced phase transition in GaN nanocrystals

NASA Astrophysics Data System (ADS)

Cui, Q.; Pan, Y.; Zhang, W.; Wang, X.; Zhang, J.; Cui, T.; Xie, Y.; Liu, J.; Zou, G.

2002-11-01

High-pressure in situ energy-dispersive x-ray diffraction experiments on GaN nanocrystals with 50 nm diameter have been carried out using a synchrotron x-ray source and a diamond-anvil cell up to about 79 GPa at room temperature. A pressure-induced first-order structural phase transition from the wurtzite-type structure to the rock-salt-type structure starts at about 48.8 GPa. The rock-salt-type phase persists to the highest pressure in our experimental range.

Thermo-Mechanical Processing in Friction Stir Welds

NASA Technical Reports Server (NTRS)

Schneider, Judy

2003-01-01

Friction stir welding is a solid-phase joining, or welding process that was invented in 1991 at The Welding Institute (TWI). The process is potentially capable of joining a wide variety of aluminum alloys that are traditionally difficult to fusion weld. The friction stir welding (FSW) process produces welds by moving a non-consumable rotating pin tool along a seam between work pieces that are firmly clamped to an anvil. At the start of the process, the rotating pin is plunged into the material to a pre-determined load. The required heat is produced by a combination of frictional and deformation heating. The shape of the tool shoulder and supporting anvil promotes a high hydrostatic pressure along the joint line as the tool shears and literally stirs the metal together. To produce a defect free weld, process variables (RPM, transverse speed, and downward force) and tool pin design must be chosen carefully. An accurate model of the material flow during the process is necessary to guide process variable selection. At MSFC a plastic slip line model of the process has been synthesized based on macroscopic images of the resulting weld material. Although this model appears to have captured the main features of the process, material specific interactions are not understood. The objective of the present research was to develop a basic understanding of the evolution of the microstructure to be able to relate it to the deformation process variables of strain, strain rate, and temperature.

Partitioning experiments in the laser-heated diamond anvil cell: volatile content in the Earth's core.

PubMed

Jephcoat, Andrew P; Bouhifd, M Ali; Porcelli, Don

2008-11-28

The present state of the Earth evolved from energetic events that were determined early in the history of the Solar System. A key process in reconciling this state and the observable mantle composition with models of the original formation relies on understanding the planetary processing that has taken place over the past 4.5Ga. Planetary size plays a key role and ultimately determines the pressure and temperature conditions at which the materials of the early solar nebular segregated. We summarize recent developments with the laser-heated diamond anvil cell that have made possible extension of the conventional pressure limit for partitioning experiments as well as the study of volatile trace elements. In particular, we discuss liquid-liquid, metal-silicate (M-Sil) partitioning results for several elements in a synthetic chondritic mixture, spanning a wide range of atomic number-helium to iodine. We examine the role of the core as a possible host of both siderophile and trace elements and the implications that early segregation processes at deep magma ocean conditions have for current mantle signatures, both compositional and isotopic. The results provide some of the first experimental evidence that the core is the obvious replacement for the long-sought, deep mantle reservoir. If so, they also indicate the need to understand the detailed nature and scale of core-mantle exchange processes, from atomic to macroscopic, throughout the age of the Earth to the present day.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Virts, Katrina S.; Houze, Robert A.

Seasonal and intraseasonal differences in mesoscale convective systems (MCSs) over South Asia are examined using A-Train satellites, a ground-based lightning network, and reanalysis fields. Pre-monsoon (April-May) MCSs occur primarily over Bangladesh and the eastern Bay of Bengal. During the monsoon (June-September), small MCSs occur over the Meghalaya Plateau and northeast Himalayan notch, while large and connected MCSs are most widespread over the Bay of Bengal. Monsoon MCSs produce less lightning and exhibit more extensive stratiform and anvil reflectivity structures in CloudSat observations than do pre-monsoon MCSs. During the monsoon season, Bay of Bengal and Meghalaya Plateau MCSs vary with themore » 30-60 day northward-propagating intraseasonal oscillation, while northeast Himalayan notch MCSs are associated with weak large-scale anomalies but locally enhanced CAPE. During intraseasonal active periods, a zone of enhanced large and connected MCSs, precipitation, and lightning extends from the northeastern Arabian Sea southeast over India and the Bay of Bengal, flanked by suppressed anomalies. Spatial variability is observed within this enhancement zone: lightning is most enhanced where MCSs are less enhanced, and vice versa. Reanalysis composites indicate that Bay of Bengal MCSs are associated with monsoon depressions, which are frequent during active monsoon periods, while Meghalaya Plateau MCSs are most frequent at the end of break periods, as anomalous southwesterly winds strengthen moist advection toward the terrain. Over both regions, MCSs exhibit more extensive stratiform and anvil regions and less lightning when the large-scale environment is moister, and vice versa.« less

Electron Density Distribution Changes of Magnesiowüstite With Pressure

NASA Astrophysics Data System (ADS)

Diamond, M. R.; Popov, D.; Shen, G.; Jeanloz, R.

2017-12-01

Magnesiowüstite is one of the dominant minerals in the earth's lower mantle; its density and elasticity, substantially altered by its spin crossover, have direct consequence to interpreting deep-earth geophysical data. High-resolution single-crystal x-ray diffraction data can portray the 3-dimensional distribution of electron density through the Fourier transform of measured form factors. Here we present experimentally measured changes in electron density distribution of single-crystal (Mg.85,Fe.15)O as it goes through its iron(II) high-spin to low-spin electronic transition between about 40 and 60 GPa [Lin and Tsuchiya, 2008], in a diamond-anvil cell. As (Mg,Fe)O undergoes a pressure induced spin crossover (from high spin at low pressure to low spin at high pressure) due to overlap of its eg orbitals, the t2g orbitals become more pronounced to due a higher population of electrons, while the eg orbitals diminish. The spin splitting energy becomes increasingly unfavorable compared to the spin orbital pairing energy. By looking at the population of electrons at different directions in real space, we directly observe these changes in orbital occupation leading up to and during the spin crossover. Since high-Mg magnesiowüstite has a high symmetry structure at these pressure conditions, detecting relative changes in electron density distribution (comparing subsequent pressure steps) is feasible by collecting high resolution data offered by high-energy X rays and wide opening-angle diamond-anvil cells.

High-pressure X-ray diffraction and Raman spectroscopy of CaFe2O4-type β-CaCr2O4

NASA Astrophysics Data System (ADS)

Zhai, Shuangmeng; Yin, Yuan; Shieh, Sean R.; Shan, Shuangming; Xue, Weihong; Wang, Ching-Pao; Yang, Ke; Higo, Yuji

2016-04-01

In situ high-pressure synchrotron X-ray diffraction and Raman spectroscopic studies of orthorhombic CaFe2O4-type β-CaCr2O4 chromite were carried out up to 16.2 and 32.0 GPa at room temperature using multi-anvil apparatus and diamond anvil cell, respectively. No phase transition was observed in this study. Fitting a third-order Birch-Murnaghan equation of state to the P-V data yields a zero-pressure volume of V 0 = 286.8(1) Å3, an isothermal bulk modulus of K 0 = 183(5) GPa and the first pressure derivative of isothermal bulk modulus K 0' = 4.1(8). Analyses of axial compressibilities show anisotropic elasticity for β-CaCr2O4 since the a-axis is more compressible than the b- and c-axis. Based on the obtained and previous results, the compressibility of several CaFe2O4-type phases was compared. The high-pressure Raman spectra of β-CaCr2O4 were analyzed to determine the pressure dependences and mode Grüneisen parameters of Raman-active bands. The thermal Grüneisen parameter of β-CaCr2O4 is determined to be 0.93(2), which is smaller than those of CaFe2O4-type CaAl2O4 and MgAl2O4.

Role of interfacial bonding in the design and realization of Magnetically Applied Pressure Shear (MAPS) experiments

NASA Astrophysics Data System (ADS)

Ding, Jow; Alexander, C. Scott

2017-06-01

MAPS (Magnetically Applied Pressure Shear) is a new technique that can be used to explore the material behavior under dynamic compression-shear loadings at strain rates and pressures that are much higher than those that can be achieved by gas-gun driven pressure shear experiments. A significant challenge for MAPS is the transmission of large shear stress through material interfaces. In this study, numerical simulations were used to gain insights on the behavior of the interface between molybdenum, which is the driver, and zirconia, the anvil, in MAPS experiments. Molybdenum was stressed into the plastic regime and zirconia stayed elastic but appeared to have incurred some spall damage at the later stage of the experiments. By including damage for the anvil and interfacial sliding in the simulations, both the longitudinal and transverse velocity data were able to be reasonably simulated. The results indicate that the interfacial slip appears to usually occur at the beginning stage of the shear loading when the pressure is relatively low. After the pressure reaches a certain level, the shear stress could be fully transmitted. Some other possible experiment designs to minimize the role of interface in MAPS are discussed. Sandia National Labs is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corp., for the U.S. Dept. of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.

Super-deep diamond genesis at Redox conditions of slab-mantle boundary

NASA Astrophysics Data System (ADS)

Gao, J.; Chen, B.; Wu, X.

2017-12-01

Diamond genesis is an intriguing issue for diamond resources and the deep carbon cycle of the Earth's interiors. Super-deep diamonds, representing only 6% of the global diamond population, often host inclusions with phase assemblages requiring a sublithospheric origin (>300 km). Being the windows for probing the deep Earth, super-deep diamonds with their distinctive micro-inclusions not only record a history of oceanic lithosphere subduction and upward transport at a depth of >250 km to even 1000 km, but indicate their genesis pertinent to mantle-carbonate melts in a Fe0-bufferred reduced condition. Our pilot experiments have evidenced the formation of diamonds from MgCO3-Fe0 system in a diamond anvil cell device at 25 GPa and 1800 K. Detailed experimental investigations of redox mechanism of MgCO3-Fe0 and CaCO3-Fe0 coupling have been conducted using multi-anvil apparatus. The conditions are set along the oceanic lithosphere subduction paths in the pressure-temperature range of 10-24 GPa and 1200-2000 K, covering the formation region of most super-deep diamonds. The clear reaction zones strongly support the redox reaction between carbonatitic slab and Fe0-bearing metals under mantle conditions. Our study has experimentally documented the possibility of super-deep diamond genesis at redox conditions of carbonateitic slab and Fe0-bearings. The kinetics of diamond formation as a function of pressure-temperature conditions are also discussed.

An in situ approach to study trace element partitioning in the laser heated diamond anvil cell

DOE Office of Scientific and Technical Information (OSTI.GOV)

Petitgirard, S.; Mezouar, M.; Borchert, M.

2012-01-15

Data on partitioning behavior of elements between different phases at in situ conditions are crucial for the understanding of element mobility especially for geochemical studies. Here, we present results of in situ partitioning of trace elements (Zr, Pd, and Ru) between silicate and iron melts, up to 50 GPa and 4200 K, using a modified laser heated diamond anvil cell (DAC). This new experimental set up allows simultaneous collection of x-ray fluorescence (XRF) and x-ray diffraction (XRD) data as a function of time using the high pressure beamline ID27 (ESRF, France). The technique enables the simultaneous detection of sample meltingmore » based to the appearance of diffuse scattering in the XRD pattern, characteristic of the structure factor of liquids, and measurements of elemental partitioning of the sample using XRF, before, during and after laser heating in the DAC. We were able to detect elements concentrations as low as a few ppm level (2-5 ppm) on standard solutions. In situ measurements are complimented by mapping of the chemical partitions of the trace elements after laser heating on the quenched samples to constrain the partitioning data. Our first results indicate a strong partitioning of Pd and Ru into the metallic phase, while Zr remains clearly incompatible with iron. This novel approach extends the pressure and temperature range of partitioning experiments derived from quenched samples from the large volume presses and could bring new insight to the early history of Earth.« less

The response of a simulated mesoscale convective system to increased aerosol pollution: Part I: Precipitation intensity, distribution, and efficiency

NASA Astrophysics Data System (ADS)

Clavner, Michal; Cotton, William R.; van den Heever, Susan C.; Saleeby, Stephen M.; Pierce, Jeffery R.

2018-01-01

Mesoscale Convective Systems (MCSs) are important contributors to rainfall in the High Plains of the United States and elsewhere in the world. It is therefore of interest to understand how different aerosols serving as cloud condensation nuclei (CCN) may impact the total amount, rates and spatial distribution of precipitation produced by MCSs. In this study, different aerosol concentrations and their effects on precipitation produced by an MCS are examined by simulating the 8 May 2009 "Super-Derecho" MCS using the Regional Atmospheric Modeling System (RAMS), a cloud-resolving model (CRM) with sophisticated aerosol and microphysical parameterizations. Three simulations were conducted that differed only in the initial concentration, spatial distribution, and chemical composition of aerosols. Aerosol fields were derived from the output of GEOS-Chem, a 3D chemical transport numerical model. Results from the RAMS simulations show that the total domain precipitation was not significantly affected by variations in aerosol concentrations, however, the pollution aerosols altered the precipitation characteristics. The more polluted simulations exhibited higher precipitation rates, higher bulk precipitation efficiency, a larger area with heavier precipitation, and a smaller area with lighter precipitation. These differences arose as a result of aerosols enhancing precipitation in the convective region of the MCS while suppressing precipitation from the MCS's stratiform-anvil. In the convective region, several processes likely contributed to an increase of precipitation. First, owing to the very humid environment of this storm, the enhanced amount of cloud water available to be collected overwhelmed the reduction in precipitation efficiency associated with the aerosol-induced production of smaller droplets which led to a net increase in the conversion of cloud droplets to precipitation. Second, higher aerosol concentrations led to invigoration of convective updrafts which enhanced precipitation in accordance to the convective invigoration hypothesis. The reduction in stratiform precipitation in the more polluted simulations was found to be attributed to the presence of greater aerosol number concentrations that reduced both collision-coalescence and riming. Analysis of back trajeocty flow showed that the air feeding the stratiform-anvil originated within the free troposphere, by mesoscale ascent. Therefore, increased aerosol pollution at higher elevations impacted the stratiform precipitation formation within the simulated MCS. As a consequence, the more polluted simulations produced the smallest precipitation from the MCS stratiform-anvil region. In Part II the impact of aerosols on the severe winds produced by this storm is examined.

Dehydration of δ-AlOOH in the lower mantle

NASA Astrophysics Data System (ADS)

Piet, H.; Shim, S. H.; Tappan, J.; Leinenweber, K. D.; Greenberg, E.; Prakapenka, V. B.

2017-12-01

Hydrous phase δ-AlOOH is an important candidate for water transport and storage in the Earth's deep mantle [1]. Knowing the conditions, under which it is stable and dehydrated, is therefore important for understanding the water transportation to the deep mantle or even to the core. A few experimental studies [1, 2] have shown that δ-AlOOH may be stable in cold descending slabs while it is dehydrated into a mixture of corundum and water under normal mantle conditions, up to 25 GPa. A subsequent study [3] reported the stability of δ-AlOOH in cold descending slabs to the core-mantle boundary conditions (2300 K at 135 GPa). However, the dehydration of δ-AlOOH has not bee directly observed in the experiments conducted at pressures above 25 GPa. We have synthesized δ-AlOOH from diaspore and Al(OH)3 in multi-anvil press at ASU. The sample was mixed with Au for coupling with near IR laser beams and loaded in diamond-anvil cells. We performed the laser-heated diamond anvil cell experiments at the 13IDD beamline of the Advanced Photon Source and ASU. At APS, we measured X-ray diffraction patterns at in situ high pressure and temperature. We observed the appearance of the corundum diffraction lines at 1700-2000 K and 55-90 GPa, indicating the dehydration of δ-AlOOH to Al2O3+ H2O. We found that the transition occurs over a broad range of temperature (500 K). We also observed that the dehydration of δ-AlOOH was accompanied by sudden change in laser coupling, most likely due to the release of fluids. The property change also helps us to determine the dehydration at ASU without in situ XRD. Our new experimental results indicate that δ-AlOOH would be stable in most subducting slabs in the deep mantle. However, because the dehydration occurs very close to the temperatures expected for the lower mantle, its stability is uncertain in the normal mantle. [1] Ohtani et al. 2001, Stability field of new hydrous phase, delta-AlOOH, Geophysical Research Letters 28, 3991-3993. [2] Sano et al. 2004, In situ XRD of dehydration of AlSiO3OH and d-AlOOH, JPCS 65, 1547-1554. [3] Sano et al. 2008, Aluminous hydrous mineral d-AlOOH as a carrier of hydrogen into the core-mantle boundary, Geophysical Research Letters 35, L03303.

The effect of ice nuclei on a deep convective cloud in South China

NASA Astrophysics Data System (ADS)

Deng, Xin; Xue, Huiwen; Meng, Zhiyong

2018-07-01

This study uses the Weather Research and Forecasting Model to simulate a deep convective cloud under a relatively polluted condition in South China. Ice nuclei (IN) aerosols near the surface are effectively transported upwards to above the 0 °C level by the strong updrafts in the convective cloud. Four cases with initial surface IN aerosol concentrations of 1, 10, 100, and 1000 L-1 are simulated. All simulations can well reproduce the major characteristics of the deep convective cloud in terms of the evolution, spatial distribution, and its track. IN aerosols have little effect on these macrophysical characteristics but can significantly affect ice formation. When IN concentration is increased, all heterogeneous nucleation modes are significantly enhanced, whereas the homogeneous freezing of cloud droplets is unchanged or weakened depending on the IN concentration and the development stages of the deep convective cloud. The homogeneous freezing of haze particles is generally not affected by increased IN but is slightly weakened in the extremely high IN case. As IN concentration is increased by 10 and 100 times, the enhanced heterogeneous nucleation is still not strong enough to compete with homogeneous freezing. Ice formation is hence still dominated by the homogenous freezing of cloud droplets and haze particles in the layer of 9-14 km, where most of the ice crystals are produced. The microphysical properties are generally unaffected in all the stages of cloud evolution. As IN concentration is increased by 1000 times and heterogeneous nucleation is further enhanced, the homogeneous freezing of cloud droplets and haze particles dominates only in the mature and dissipating stages, leading to unaffected ice number mixing ratio in the anvil region (approximately above 9 km) for these two stages. However, in the developing stage, when the supply of cloud droplets is limited, the homogeneous freezing of cloud droplets is weakened or even suppressed due to the very strong competition for liquid water with heterogeneous nucleation, leading to significantly lower ice number mixing ratio in the anvil regions. In addition, the microphysical properties in the convective core regions below the cloud anvil (approximately below 9 km) are also affected in the case of 1000 L-1. The enhanced heterogeneous nucleation produces more ice crystals below 9 km, leading to a stronger conversion from ice crystals to snow particles, and hence higher number and mass mixing ratios of snow. The IN effect on the spatial distributions and temporal evolutions of the surface precipitation and updraft velocity is generally insignificant.

Stability and melting of Fe3C at high pressure and temperature: Implication for the carbon in the Earth's core

NASA Astrophysics Data System (ADS)

Takahashi, S.; Ohtani, E.; Sakai, T.; Hirao, N.; Ohishi, Y.

2012-12-01

The Earth's core is regarded as an Fe-Ni alloy but its density is lower than that of pure Fe at the core conditions. Therefore, the Earth's core is supposed to contain light elements and carbon is one of the candidates of the light elements to explain the density deficit of the Earth's core. Nakajima et al. (2009) reported the melting temperature of Fe3C up to around 30 GPa based on textual observations, the chemical analysis of the quenched run products and in situ X-ray diffraction experiments using a Kawai-type multi anvil apparatus. Lord et al. (2009) reported melting temperatures of Fe3C up to 70 GPa, which was determined by the temperature plateau during increasing laser power using a laser-heated diamond anvil cell. They also suggested Fe+Fe7C3 is a stable subsolidus phase. There are obvious discrepancies between the melting curve and the stable subsolidus phase reported by Nakajima et al. (2009) and those reported by Lord et al. (2009). In this study, the melting temperatures of Fe3C and a subsolidus phase relation were determined based on in situ X-ray diffraction experiments. This study aims to reveal the stability field of Fe3C and the melting temperature of Fe3C and to discuss the behaviors of carbon in the Earth's core. We have performed experiments using a laser-heated diamond anvil cell combined with in situ X-ray diffraction experiment at BL10XU beamline, SPring-8 synchrotron facility. An NaCl powder and a rhenium or tungsten foil were used for the insulator and gasket, respectively. Melting of the sample was determined by disappearance of the X-ray diffraction peaks. We determined the melting relation of Fe3C up to 145 GPa by in situ X-ray diffraction experiments. Present results are close to Nakajima et al. (2009) up to 30 GPa but become close to that reported by Lord et al. (2009) at higher pressure conditions. The solidus temperature extrapolated to the ICB pressure, 330 GPa, is 5400 K. We also confirmed that Fe3C is stable as a subsolidus phase at least up to 237 GPa and 4100 K. This strongly suggests that Fe3C is a potential candidate of the Earth's inner core although we need further studies at the inner core conditions.

Phase Relations of Iron and Iron-Nickel Alloys up to 3 Mbars

NASA Astrophysics Data System (ADS)

Kuwayama, Y.; Hirose, K.; Sata, N.; Ohishi, Y.

2007-12-01

Iron is believed to be the major component of the Earth's core because it is the most abundant element that satisfies the observed seismic densities. Based on cosmochemical models and the studies of iron meteorites, it is generally accepted that the Earth's core also contains substantial amounts of nickel. Therefore, the high pressure behaviour of iron-nickel alloys is crucially important for interpreting and constraining geophysical and geochemical models of the Earth's core. The phase relation of iron at relatively low pressure has been well established. α-Fe with bcc structure at ambient condition transforms to γ-Fe at high temperature and to ɛ-Fe with hcp structure at above ~ 10 GPa. In contrast, the phase relation and the crystal structure at high pressure and temperature are still highly controversial. The phase relations of iron-nickel alloys were also studied in an externally-heated diamond-anvil cell (Huang et al. 1988, 1992) and in a laser-heated diamond-anvil cell (Lin et al. 2002, Mao et al. 2005, Dubrovinsky et al. 2007), but these experiments were limited to the pressure of 225 GPa. Applications of the previous results to the Earth's inner core conditions required significant extrapolations. In this study, we have investigated the phase relations of iron and a number of iron-nickel alloys in a wide range of pressures (>300 GPa), temperatures (>2000 K) and compositions (0-80 wt% Ni) using a laser-heated diamond-anvil cell with synchrotron x-ray diffraction. For iron, in-situ x-ray diffraction studies showed a wide range of stability of ɛ-Fe with an hcp structure up to 300 GPa and 2000 K and up to 343 GPa at room temperature. No evidence for the existence of phases other than ɛ-Fe, such as β-Fe with a dhcp structure (suggested by Dubrovinsky et al. 2000) or orthorhombic structure (suggested by Andrault et al. 1997), was observed. For iron-nickel alloys, high pressure and temperature experiments were conducted on Fe-18.4 wt% Ni, Fe-24.9 wt% Ni, Fe-35.7 wt% Ni, Fe-50.0 wt% Ni and Fe-80.0 wt% Ni up to 300 GPa. The experimental results indicate that the iron-nickel alloys strongly favour an fcc structure under multimegabar pressures. Our results can directly apply to the Earth's inner core pressures and the phase relations of iron- nickel alloys may interpret seismically observed anisotropy and discontinuity in the Earth's inner core.

The Airborne Cloud-Aerosol Transport System. Part I; Overview and Description of the Instrument and Retrival Algorithms

NASA Technical Reports Server (NTRS)

Yorks, John E.; Mcgill, Matthew J.; Scott, V. Stanley; Kupchock, Andrew; Wake, Shane; Hlavka, Dennis; Hart, William; Selmer, Patrick

2014-01-01

The Airborne Cloud-Aerosol Transport System (ACATS) is a multi-channel Doppler lidar system recently developed at NASA Goddard Space Flight Center (GSFC). A unique aspect of the multi-channel Doppler lidar concept such as ACATS is that it is also, by its very nature, a high spectral resolution lidar (HSRL). Both the particulate and molecular scattered signal can be directly and unambiguously measured, allowing for direct retrievals of particulate extinction. ACATS is therefore capable of simultaneously resolving the backscatterextinction properties and motion of a particle from a high altitude aircraft. ACATS has flown on the NASA ER-2 during test flights over California in June 2012 and science flights during the Wallops Airborne Vegetation Experiment (WAVE) in September 2012. This paper provides an overview of the ACATS method and instrument design, describes the ACATS retrieval algorithms for cloud and aerosol properties, and demonstrates the data products that will be derived from the ACATS data using initial results from the WAVE project. The HSRL retrieval algorithms developed for ACATS have direct application to future spaceborne missions such as the Cloud-Aerosol Transport System (CATS) to be installed on the International Space Station (ISS). Furthermore, the direct extinction and particle wind velocity retrieved from the ACATS data can be used for science applications such 27 as dust or smoke transport and convective outflow in anvil cirrus clouds.

High-pressure pair distribution function (PDF) measurement using high-energy focused x-ray beam

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hong, Xinguo, E-mail: xhong@bnl.gov; Weidner, Donald J.; Ehm, Lars

In this paper, we report recent development of the high-pressure pair distribution function (HP-PDF) measurement technique using a focused high-energy X-ray beam coupled with a diamond anvil cell (DAC). The focusing optics consist of a sagittally bent Laue monochromator and Kirkpatrick-Baez (K–B) mirrors. This combination provides a clean high-energy X-ray beam suitable for HP-PDF research. Demonstration of the HP-PDF technique for nanocrystalline platinum under quasi-hydrostatic condition above 30 GPa is presented.

Applied Meteorology Unit (AMU) Quarterly Report Third Quarter FY-08

NASA Technical Reports Server (NTRS)

Bauman, William; Crawford, Winifred; Barrett, Joe; Watson, Leela; Dreher, Joseph

2008-01-01

This report summarizes the Applied Meteorology Unit (AMU) activities for the third quarter of Fiscal Year 2008 (April - June 2008). Tasks reported on are: Peak Wind Tool for User Launch Commit Criteria (LCC), Anvil Forecast Tool in AWIPS Phase II, Completion of the Edward Air Force Base (EAFB) Statistical Guidance Wind Tool, Volume Averaged Height Integ rated Radar Reflectivity (VAHIRR), Impact of Local Sensors, Radar Scan Strategies for the PAFB WSR-74C Replacement, VAHIRR Cost Benefit Analysis, and WRF Wind Sensitivity Study at Edwards Air Force Base

High pressure melting curve of platinum up to 35 GPa

NASA Astrophysics Data System (ADS)

Patel, Nishant N.; Sunder, Meenakshi

2018-04-01

Melting curve of Platinum (Pt) has been measured up to 35 GPa using our laboratory based laser heated diamond anvil cell (LHDAC) facility. Laser speckle method has been employed to detect onset of melting. High pressure melting curve of Pt obtained in the present study has been compared with previously reported experimental and theoretical results. The melting curve measured agrees well within experimental error with the results of Kavner et al. The experimental data fitted with simon equation gives (∂Tm/∂P) ˜25 K/GPa at P˜1 MPa.

Process for making diamonds

NASA Technical Reports Server (NTRS)

Rasquin, J. R.; Estes, M. F. (Inventor)

1973-01-01

A description is given of a device and process for making industrial diamonds. The device is composed of an exponential horn tapering from a large end to a small end, with a copper plate against the large end. A magnetic hammer abuts the copper plate. The copper plate and magnetic hammer function together to create a shock wave at the large end of the horn. As the wave propagates to the small end, the extreme pressure and temperature caused by the wave transforms the graphite, present in an anvil pocket at the small end, into diamonds.

Experimental Evidence of Negative Linear Compressibility in the MIL-53 Metal-organic Framework Family

DOE Office of Scientific and Technical Information (OSTI.GOV)

Serra-Crespo, Pablo; Dikhtiarenko, Alla; Stavitski, Eli

Here we report a series of powder X-ray diffraction experiments performed on the soft porous crystals MIL-53(Al) and NH 2-MIL-53(Al) in a diamond anvil cell under different pressurization media. Systematic refinements of the obtained powder patterns demonstrate that these materials expand along a specific direction while undergoing total volume reduction under an increasing hydrostatic pressure. Our results confirm for the first time the negative linear compressibility behaviour of this family of materials, recently predicted from quantum chemical calculations.

Experimental evidence of negative linear compressibility in the MIL-53 metal–organic framework family

DOE Office of Scientific and Technical Information (OSTI.GOV)

Serra-Crespo, Pablo; Dikhtiarenko, Alla; Stavitski, Eli

Here we report a series of powder X-ray diffraction experiments performed on the soft porous crystals MIL-53(Al) and NH 2-MIL-53(Al) in a diamond anvil cell under different pressurization media. Systematic refinements of the obtained powder patterns demonstrate that these materials expand along a specific direction while undergoing total volume reduction under an increasing hydrostatic pressure. The results confirm for the first time the negative linear compressibility behaviour of this family of materials, recently predicted from quantum chemical calculations.

Experimental Evidence of Negative Linear Compressibility in the MIL-53 Metal-Organic Framework Family

DOE Office of Scientific and Technical Information (OSTI.GOV)

Serra-Crespo, Pablo; Dikhtiarenko, Alla; Stavitski, Eli

Here, we report a series of powder X-ray diffraction experiments performed on the soft porous crystals MIL-53(Al) and NH 2-MIL-53(Al) in a diamond anvil cell under different pressurization media. Systematic refinements of the obtained powder patterns demonstrate that these materials expand along a specific direction while undergoing total volume reduction under an increasing hydrostatic pressure. Our results confirm for the first time the negative linear compressibility behaviour of this family of materials, recently predicted from quantum chemical calculations.

Experimental evidence of negative linear compressibility in the MIL-53 metal–organic framework family

DOE PAGES

Serra-Crespo, Pablo; Dikhtiarenko, Alla; Stavitski, Eli; ...

2014-03-24

Here we report a series of powder X-ray diffraction experiments performed on the soft porous crystals MIL-53(Al) and NH 2-MIL-53(Al) in a diamond anvil cell under different pressurization media. Systematic refinements of the obtained powder patterns demonstrate that these materials expand along a specific direction while undergoing total volume reduction under an increasing hydrostatic pressure. The results confirm for the first time the negative linear compressibility behaviour of this family of materials, recently predicted from quantum chemical calculations.

Phase boundary of hot dense fluid hydrogen

PubMed Central

Ohta, Kenji; Ichimaru, Kota; Einaga, Mari; Kawaguchi, Sho; Shimizu, Katsuya; Matsuoka, Takahiro; Hirao, Naohisa; Ohishi, Yasuo

2015-01-01

We investigated the phase transformation of hot dense fluid hydrogen using static high-pressure laser-heating experiments in a laser-heated diamond anvil cell. The results show anomalies in the heating efficiency that are likely to be attributed to the phase transition from a diatomic to monoatomic fluid hydrogen (plasma phase transition) in the pressure range between 82 and 106 GPa. This study imposes tighter constraints on the location of the hydrogen plasma phase transition boundary and suggests higher critical point than that predicted by the theoretical calculations. PMID:26548442

X-ray diffraction on radioactive materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schiferl, D.; Roof, R.B.

1978-01-01

X-ray diffraction studies on radioactive materials are discussed with the aim of providing a guide to new researchers in the field. Considerable emphasis is placed on the safe handling and loading of not-too-exotic samples. Special considerations such as the problems of film blackening by the gamma rays and changes induced by the self-irradiation of the sample are covered. Some modifications of common diffraction techniques are presented. Finally, diffraction studies on radioactive samples under extreme conditions are discussed, with primary emphasis on high-pressure studies involving diamond-anvil cells.

Effect of pressure on infrared spectra of ice 7

NASA Technical Reports Server (NTRS)

Holzapfel, W. B.; Seiler, B.; Nicol, M.

1983-01-01

The effect of pressure on the infrared spectra of H2O and D2O ice VII was studied at room temperature and pressures between 2 and 15 GPa with a Fourier transform infrared spectrometer and a diamond anvil high pressure cell. Two librational modes, one bending mode, and various overtone bands are well resolved. The stretching modes, nu sub 1 and nu sub 3 are poorly resolved due to overlap with diamond window absorption. Differences between the spectra of H2O and D2O are discussed.

Pressure-enhanced ortho-para conversion in solid hydrogen up to 58 GPa.

PubMed

Eggert, J H; Karmon, E; Hemley, R J; Mao, A; Goncharov, A F

1999-10-26

We measured the ortho-para conversion rate in solid hydrogen by using Raman scattering in a diamond-anvil cell, extending previous measurements by a factor of 60 in pressure. We confirm previous experiments that suggested a decrease in the conversion rate above about 0.5 GPa. We observe a distinct minimum at 3 GPa followed by a drastic increase in the conversion rate to our maximum pressure of 58 GPa. This pressure enhancement of conversion is not predicted by previous theoretical treatments and must be due to a new conversion pathway.

Raman spectra of solid benzene under high pressure

NASA Technical Reports Server (NTRS)

Thiery, M.-M.; Kobashi, K.; Spain, I. L.

1985-01-01

Raman spectra of solid benzene have been measured at room temperature up to about 140 kbar, using the diamond anvil cell. Effort has been focused upon the lattice vibration spectra at pressures above that of phase II. It is found that a change in slopes occurs in the frequency-pressure curves at about 40 kbar. Furthermore, a new band appears above 90 kbar. These features probably correspond respectively to the II-III phase transition, which has been reported previously, and a III-IV phase transition, reported here for the first time.

Backbone N xH compounds at high pressures

DOE PAGES

Goncharov, Alexander F.; Holtgrewe, Nicholas; Qian, Guangrui; ...

2015-06-05

Optical and synchrotron x-ray diffraction diamond anvil cell experiments have been combined with first principles theoretical structure predictions to investigate mixtures of N 2 and H 2 up to 55 GPa. Our experiments show the formation of structurally complex van der Waals compounds above 10 GPa. However, we found that these N xH (0.52, H 2, and NH 3 above approximately 40 GPa. Lastly, our results suggest new pathways for synthesis of environmentally benign high energy-density materials. These materials could also exist as alternative planetary ices.

A high-pressure van der Waals compound in solid nitrogen-helium mixtures

NASA Technical Reports Server (NTRS)

Vos, W. L.; Finger, L. W.; Hemley, R. J.; Hu, J. Z.; Mao, H. K.; Schouten, J. A.

1992-01-01

A detailed diamond anvil-cell study using synchrotron X-ray diffraction, Raman scattering, and optical microscopy has been conducted for the He-N system, with a view to the weakly-bound van der Waals molecule interactions that can be formed in the gas phase. High pressure is found to stabilize the formation of a stoichiometric, solid van der Waals compound of He(N2)11 composition which may exemplify a novel class of compounds found at high pressures in the interiors of the outer planets and their satellites.

Static High Pressure Structural studies on Dy to 119 GPa

DOE Office of Scientific and Technical Information (OSTI.GOV)

Patterson, J R; Saw, C K; Akella, J

2003-11-12

Structural phase transitions in the rare-earth metal Dysprosium have been studied in a Diamond Anvil Cell (DAC) to 119 GPa by x-ray diffraction. Four transformations following the sequence hcp {yields} Sm-type {yields} dhcp {yields} hR24 (hexagonal) {yields} bcm (monoclinic) are observed at 6, 15, 43, and 73 GPa respectively. The hexagonal to monoclinic transformation is accompanied by a 6% reduction in volume, which is attributed to delocalization of the 4f electrons, similar to that seen in Ce, Pr, and Gd.

X-ray diffraction study of elemental thulium to 86 GPa

NASA Astrophysics Data System (ADS)

Pravica, Michael; Romano, Edward; Quine, Zachary; Pravica, Walter

2006-03-01

We have studied the structures and equation of state of elemental thulium up to 86 GPa in a diamond anvil cell using angular-dispersive x-ray powder diffraction methods at the Advanced Photon Source. This is part of a study of phase transitions in the lanthanide-series metals using cyclohexane as a quasi-hydrostatic medium. We present evidence of a series of phase transitions that appear to follow the anticipated hcp ->Sm-type -> dhcp -> distorted fcc sequence of transitions and show the equation of state derived from the x-ray fit data.

Equation of state and phase transformations study of Nd at ultra-high pressures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Akella, J.; Smith, G.S.; Weir, S.

1991-10-01

Neodymium was investigated to 96.0 GPa pressure in a diamond-anvil ell at room temperature. The observed structural sequence as a function of pressure is dhcp-fcc- six layered'' structure. In the diffraction pattern hexagonal doublets; notably 102, 006 and 100, 108; appear as single reflection when the c/a ratio is 4.899. However, when cc/a approaches 4.7, the splitting is clear. So far in this study, no monoclinic phase or tetragonal phase were observed. 1 fig., 18 refs.

Developing Dual Polarization Applications For 45th Weather Squadron's (45 WS) New Weather Radar: A Cooperative Project With The National Space Science and Technology Center (NSSTC)

NASA Technical Reports Server (NTRS)

Roeder, W.P.; Peterson, W.A.; Carey, L.D.; Deierling, W.; McNamara, T.M.

2009-01-01

A new weather radar is being acquired for use in support of America s space program at Cape Canaveral Air Force Station, NASA Kennedy Space Center, and Patrick AFB on the east coast of central Florida. This new radar includes dual polarization capability, which has not been available to 45 WS previously. The 45 WS has teamed with NSSTC with funding from NASA Marshall Spaceflight Flight Center to improve their use of this new dual polarization capability when it is implemented operationally. The project goals include developing a temperature profile adaptive scan strategy, developing training materials, and developing forecast techniques and tools using dual polarization products. The temperature profile adaptive scan strategy will provide the scan angles that provide the optimal compromise between volume scan rate, vertical resolution, phenomena detection, data quality, and reduced cone-of-silence for the 45 WS mission. The mission requirements include outstanding detection of low level boundaries for thunderstorm prediction, excellent vertical resolution in the atmosphere electrification layer between 0 C and -20 C for lightning forecasting and Lightning Launch Commit Criteria evaluation, good detection of anvil clouds for Lightning Launch Commit Criteria evaluation, reduced cone-of-silence, fast volume scans, and many samples per pulse for good data quality. The training materials will emphasize the appropriate applications most important to the 45 WS mission. These include forecasting the onset and cessation of lightning, forecasting convective winds, and hopefully the inference of electrical fields in clouds. The training materials will focus on annotated radar imagery based on products available to the 45 WS. Other examples will include time sequenced radar products without annotation to simulate radar operations. This will reinforce the forecast concepts and also allow testing of the forecasters. The new dual polarization techniques and tools will focus on the appropriate applications for the 45 WS mission. These include forecasting the onset of lightning, the cessation of lightning, convective winds, and hopefully the inference of electrical fields in clouds. This presentation will report on the results achieved so far in the project.

New developments in the Paris-Edinburgh cell program at HPCAT

NASA Astrophysics Data System (ADS)

Park, C.; Kenney-Benson, C.; Kono, Y.; Shen, G.; Yu, T.; Sakamaki, T.; Jing, Z.; Wang, Y.; Abd El Qader, M.; Baker, J.; Kumar, R.; Velisavljevic, N.

2011-12-01

The Paris-Edinburgh cell at HPCAT 16BM-B station is capable of maintaining sample pressure and temperature up to 7GPa and 2,300K for long durations more than 24 hrs for various types of materials in the molten state. Materials including rock forming minerals, metal alloys, semiconductors, and energetic organic compounds have been studied for their liquid structures and phase transition behaviors under these conditions. The sample volume ranges from 0.03 mm3 to 1.2 mm3 by adjusting the cylindrical sample diameter depending on x-ray attenuation, while the sample height available for x-ray scattering is limited to 0.4 mm due to the gap between the two co-axial WC anvils. The sample cell assembly has been optimized for x-ray transparency, chemical inertness, and thermal insulation using boron-epoxy composite gasket, hexagonal boron nitride or graphite crucible, and low density magnesia supporting the cylindrical graphite heater. For consistent measurements of liquid/amorphous and crystalline structures during melting and phase transitions, the energy-dispersive x-ray diffraction (EDXD) with multiple 2θ angles is applied, fully exploiting the bending magnet white beam spectrum provided by the Advanced Photon Source up to 120 keV energy. Fine collimation slits are applied for the diffracted beam to control the depth resolution at various diffraction angles and to minimize background scattering from the pressure media. A real-time radiography imaging system is also statically installed at the beamline for sample alignment and 2D projection volumetry applications. This combined setup is established as the routine PEC application at the station. Recently, a few new capabilities have been added: Ultrasonic velocity measurement for liquid samples having a disc shape (0.2-0.4 mm in thickness) has been successfully commissioned with the help of the radiography imaging system, which calibrates the acoustic travel distances through the sample cell assembly within 5 μm uncertainty. The white beam radiography also has been utilized in an in-situ thermoelectric property measurement for high-pressure solid phase. Electrical resistivity, thermoelectric coefficient (Seebeck coefficient), and thermal conductivity of solid phases can be simultaneously measured with a four-probe approach using inserted thermocouple wires. These new applications were made through substantial modifications of the sample assembly components as well as adding in-situ probing electrodes in- and outside of the PE anvils. These series of new instrumental developments at HPCAT opened new opportunities for in-situ studies of structure and property correlations for melts. New developments to extend the pressure and temperature capabilities while retaining the outstanding stability of the sample in molten state are ongoing.

Effect of a viscoelastic target on the impact response of a flat-nosed projectile

NASA Astrophysics Data System (ADS)

Liu, Hu; Yang, Jialing; Liu, Hua

2018-02-01

Taylor impact is a widely used strategy in which a flat-nosed projectile is fired onto a rigid anvil directly to determine the dynamic strength of rod specimens. Nowadays, the rigid anvil is often replaced by an output target bar to ensure the accuracy of measurement via recording strain signals in the output bar. For testing the dynamic strength of low-density materials, a low-impedance target bar, which exhibits viscoelastic characteristics is often employed. In this paper, an extended Taylor model is proposed to improve the idealization of treating the target bar as perfectly rigid material in the classic Taylor model, and the viscoelastic effect of the target bar is incorporated. The viscoelastic target bar is depicted by two elastic springs and one dashpot. Based on the plastic shock wave theory in the flat-nosed projectile associated with the viscoelastic wave analysis in the target bar, the viscoelastic effect of the target bar on the impact response of the flat-nosed projectile is investigated. The finite element simulation is also carried out to verify the theoretical model, and good agreement is found. The present theoretical model is also called the Taylor-cylinder Hopkinson impact, which provides a more accurate way to identify the dynamic material parameters. The dynamic responses of the present model are further compared with previous elastic and rigid target bar models. It is found that the viscoelastic effect of the target bar should be taken into consideration in the Taylor-cylinder Hopkinson impact test for low-impedance materials.

High-pressure behavior of amorphous selenium from ultrasonic measurements and Raman spectroscopy

NASA Astrophysics Data System (ADS)

He, Z.; Wang, Z. G.; Zhu, H. Y.; Liu, X. R.; Peng, J. P.; Hong, S. M.

2014-07-01

The high-pressure behavior of melt-quenched amorphous selenium (a-Se) has been investigated via ultrasonic measurements and Raman scattering at room temperature. The ultrasonic measurements were conducted on a-Se in a multi-anvil apparatus with two different sample assemblies at pressures of up to 4.5 and 4.8 GPa. We discovered that similar kinks occur in the slopes of the pressure dependence characteristics of the travel time and the sound velocity in both shear and longitudinal waves in the 2.0-2.5 GPa range. These kinks are independent of the sample assemblies, indicating an intrinsic transformation of the a-Se. Additionally, we deduced the pressure-volume relationship of a-Se from the sound velocity characteristics using the Birch-Murnaghan equation of state, and the results agreed well with those of previous reports. In situ high-pressure Raman scattering measurements of a-Se were conducted in a diamond anvil cell with an 830 nm excitation line up to a pressure of 4.3 GPa. We found that the characteristic band of a-Se at ˜250 cm-1 experienced a smooth shift to a lower frequency with pressure, but a sharp slope change in the band intensity versus pressure occurred near 2.5 GPa. The results of X-ray diffraction and differential scanning calorimetry measurements indicate that the samples remain in their amorphous states after decompression. Thus, we proposed that the abnormal compression behavior of a-Se in the 2.0-2.5 GPa range can be attributed to pressure-induced local atomic reconfiguration, implying an amorphous-amorphous transition of the elementary selenium.

The Tropical Convective Spectrum. Part 1; Archetypal Vertical Structures

NASA Technical Reports Server (NTRS)

Boccippio, Dennis J.; Petersen, Walter A.; Cecil, Daniel J.

2005-01-01

A taxonomy of tropical convective and stratiform vertical structures is constructed through cluster analysis of 3 yr of Tropical Rainfall Measuring Mission (TRMM) "warm-season" (surface temperature greater than 10 C) precipitation radar (PR) vertical profiles, their surface rainfall, and associated radar-based classifiers (convective/ stratiform and brightband existence). Twenty-five archetypal profile types are identified, including nine convective types, eight stratiform types, two mixed types, and six anvil/fragment types (nonprecipitating anvils and sheared deep convective profiles). These profile types are then hierarchically clustered into 10 similar families, which can be further combined, providing an objective and physical reduction of the highly multivariate PR data space that retains vertical structure information. The taxonomy allows for description of any storm or local convective spectrum by the profile types or families. The analysis provides a quasi-independent corroboration of the TRMM 2A23 convective/ stratiform classification. The global frequency of occurrence and contribution to rainfall for the profile types are presented, demonstrating primary rainfall contribution by midlevel glaciated convection (27%) and similar depth decaying/stratiform stages (28%-31%). Profiles of these types exhibit similar 37- and 85-GHz passive microwave brightness temperatures but differ greatly in their frequency of occurrence and mean rain rates, underscoring the importance to passive microwave rain retrieval of convective/stratiform discrimination by other means, such as polarization or texture techniques, or incorporation of lightning observations. Close correspondence is found between deep convective profile frequency and annualized lightning production, and pixel-level lightning occurrence likelihood directly tracks the estimated mean ice water path within profile types.

Comment on 'Modeling of Convective-Stratiform Precipitation Processes: Sensitivity to Partitioning Methods' by Matthias Steiner

NASA Technical Reports Server (NTRS)

Lang, Steve; Tao, W.-K.; Simpson, J.; Ferrier, B.

2003-01-01

Despite the obvious notion that the presence of hail or graupel is a good indication of convection, the model results show this does not provide an objective benchmark partly due to the unrealistic presence of small amounts of hail or graupel throughout the anvil in the model but mainly because of the significant amounts of hail or graupel, especially in the tropical TOGA COARE simulation, in the transition zone. Without use of a "transition" category, it is open to debate as how this region should best be defined, as stratiform or as convective. So, the presence of significant hail or graupel contents in this zone significantly degrades its use an objective benchmark for convection. The separation algorithm comparison was done in the context of a cloud-resolving model. These models are widely used and serve a variety of purposes especially with regard to retrieving information that cannot be directly measured by providing synthetic data sets that are consistent and complete. Separation algorithms are regularly applied in these models. However, as with any modeling system, these types 'of models are constantly being improved to overcome any known deficiencies and make them more accurate representations of observed systems. The presence of hail and graupel in the anvil and the bias towards heavy rainfall rates are two such examples of areas that need improvement. Since, both of these can effect the perceived performance of the separation algorithms, the Lang et al. (2003) study did not want to overstate the relative performance of any specific algorithms.

Novel Totally Laparoscopic Endolumenal Rectal Resection With Transanal Natural Orifice Specimen Extraction (NOSE) Without Rectal Stump Opening: A Modification of Our Recently Published Clean Surgical Technique in a Porcine Model.

PubMed

Kvasha, Anton; Hadary, Amram; Biswas, Seema; Szvalb, Sergio; Willenz, Udi; Waksman, Igor

2015-06-01

Our group has recently described a novel technique for clean endolumenal bowel resection, in which abdominal and transanal approaches were used. In the current study, 2 modifications of this procedure were tested for feasibility in a porcine model. A laparoscopic approach to the peritoneal cavity was employed in rectal mobilization; this was followed by a transanal rectorectal intussusception and pull-through (IPT). IPT was established in a stepwise fashion. First, the proximal margin of resection was attached to the shaft of the anvil of an end-to-end circular stapler with a ligature around the rectum. Second, this complex was pulled transanally to produce IPT. Once IPT was established, a second ligature was placed around the rectum approximating the proximal and distal resection margins. This was followed by a purse string suture through 2 bowel walls, encircling the shaft of the anvil just proximal to the ligatures. The specimen was resected and extracted by making a full-thickness incision through the 2 bowel walls distal to the previously placed purse string suture and ligatures. The anastomosis was achieved by applying the stapler. The technique was found to be feasible. Peritoneal samples, collected after transanal specimen extraction, did not demonstrate bacterial growth. Although, this is a novel and evolving procedure, its minimally invasive nature, as well as aseptic bowel manipulation during endolumenal rectal resection, has the potential to limit the complications associated with abdominal wall incision and surgical site infection. © The Author(s) 2014.

Metal/Silicate Partitioning at High Pressures and Temperatures

NASA Technical Reports Server (NTRS)

Shofner, G.; Campbell, A.; Danielson, L.; Righter, K.; Rahman, Z.

2010-01-01

The behavior of siderophile elements during metal-silicate segregation, and their resulting distributions provide insight into core formation processes. Determination of partition coefficients allows the calculation of element distributions that can be compared to established values of element abundances in the silicate (mantle) and metallic (core) portions of the Earth. Moderately siderophile elements, including W, are particularly useful in constraining core formation conditions because they are sensitive to variations in T, P, oxygen fugacity (fO2), and silicate composition. To constrain the effect of pressure on W metal/silicate partitioning, we performed experiments at high pressures and temperatures using a multi anvil press (MAP) at NASA Johnson Space Center and laser-heated diamond anvil cells (LHDAC) at the University of Maryland. Starting materials consisted of natural peridotite mixed with Fe and W metals. Pressure conditions in the MAP experiments ranged from 10 to 16 GPa at 2400 K. Pressures in the LHDAC experiments ranged from 26 to 58 GPa, and peak temperatures ranged up to 5000 K. LHDAC experimental run products were sectioned by focused ion beam (FIB) at NASA JSC. Run products were analyzed by electron microprobe using wavelength dispersive spectroscopy. Liquid metal/liquid silicate partition coefficients for W were calculated from element abundances determined by microprobe analyses, and corrected to a common fO2 condition of IW-2 assuming +4 valence for W. Within analytical uncertainties, W partitioning shows a flat trend with increasing pressure from 10 to 16 GPa. At higher pressures, W becomes more siderophile, with an increase in partition coefficient of approximately 0.5 log units.

The Solidus of Mar

NASA Astrophysics Data System (ADS)

Duncan, M. S.; Schmerr, N. C.; Fei, Y.

2017-12-01

Knowledge of the melting behavior of a planetary interior is critical to determine the thermal history of a planet. In particular, the location of the mantle solidus with depth is a key parameter for constraining temperatures of magma ocean crystallization, understanding volcanic and magmatic processes, and inferring mantle rheology. The properties of the martian mantle are experimentally accessible through a combination of piston cylinder and multi-anvil apparatuses. Here we constrain the solidus of martian mantle from the surface to the potential core-mantle boundary by combining previous low pressure experiments with new, high pressure multi-anvil experiments. Experiments were conducted on a simplified anhydrous Dreibus and Wänke composition [Bertka and Fei, JGR, 1997] from 10 to 25 GPa and 1775 to 2300 °C placed in rhenium capsules. The mineralogy and melt phases in each experiment were identified and quantified with an electron microprobe. Experiments spanned 100 to 200 °C at each pressure (10, 16, 20, 23, 25 GPa) and allowed us to constrain the location of the solidus within 50 °C. By combining our data with solidus experiments at lower pressures completed previously with the Dreibus and Wänke composition, we parameterized the solidus of the entire martian mantle. When considering the high pressure experiments, the Fe-rich solidus of the martian mantle is 100 °C lower than the peridotite mantle solidus for the Earth [Hirschmann et al., PEPI, 2009]. These new results provide an experimental determination of the melting temperature of martian mantle that is an essential constraint for modeling the thermal evolution and volcanism on Mars.

High-pressure high-temperature stability of hcp-Ir xOs 1-x (x = 0.50 and 0.55) alloys

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yusenko, Kirill V.; Bykova, Elena; Bykov, Maxim

2016-12-23

Hcp-Ir 0.55Os 0.45 and hcp-Ir 0.50Os 0.50 alloys were synthesised by thermal decomposition of single-source precursors in hydrogen atmosphere. Both alloys correspond to a miscibility gap in the Ir–Os binary phase diagram and therefore are metastable at ambient conditions. An in situ powder X-ray diffraction has been used for a monitoring a formation of hcp-Ir0.55Os0.45 alloy from (NH 4) 2[Ir 0.55Os 0.45Cl 6] precursor. A crystalline intermediate compound and nanodimentional metallic particles with a large concentration of defects has been found as key intermediates in the thermal decomposition process in hydrogen flow. High-temperature stability of titled hcp-structured alloys has beenmore » investigated upon compression up to 11 GPa using a multi-anvil press and up to 80 GPa using laser-heated diamond-anvil cells to obtain a phase separation into fcc + hcp mixture. Compressibility curves at room temperature as well as thermal expansion at ambient pressure and under compression up to 80 GPa were collected to obtain thermal expansion coefficients and bulk moduli. hcp-Ir 0.55Os 0.45 alloy shows bulk moduli B0 = 395 GPa. Thermal expansion coefficients were estimated as α = 1.6·10 -5 K -1 at ambient pressure and α = 0.3·10 -5 K -1 at 80 GPa. Obtained high-pressure high-temperature data allowed us to construct the first model for pressure-dependent Ir–Os phase diagram.« less

Observational evidence for the convective transport of dust over the Central United States

NASA Astrophysics Data System (ADS)

Corr, C. A.; Ziemba, L. D.; Scheuer, E.; Anderson, B. E.; Beyersdorf, A. J.; Chen, G.; Crosbie, E.; Moore, R. H.; Shook, M.; Thornhill, K. L.; Winstead, E.; Lawson, R. P.; Barth, M. C.; Schroeder, J. R.; Blake, D. R.; Dibb, J. E.

2016-02-01

Bulk aerosol composition and aerosol size distributions measured aboard the DC-8 aircraft during the Deep Convective Clouds and Chemistry Experiment mission in May/June 2012 were used to investigate the transport of mineral dust through nine storms encountered over Colorado and Oklahoma. Measurements made at low altitudes (<5 km mean sea level (MSL)) in the storm inflow region were compared to those made in cirrus anvils (altitude > 9 km MSL). Storm mean outflow Ca2+ mass concentrations and total coarse (1 µm < diameter < 5 µm) aerosol volume (Vc) were comparable to mean inflow values as demonstrated by average outflow/inflow ratios greater than 0.5. A positive relationship between Ca2+, Vc, ice water content, and large (diameter > 50 µm) ice particle number concentrations was not evident; thus, the influence of ice shatter on these measurements was assumed small. Mean inflow aerosol number concentrations calculated over a diameter range (0.5 µm < diameter < 5.0 µm) relevant for proxy ice nuclei (NPIN) were ~15-300 times higher than ice particle concentrations for all storms. Ratios of predicted interstitial NPIN (calculated as the difference between inflow NPIN and ice particle concentrations) and inflow NPIN were consistent with those calculated for Ca2+ and Vc and indicated that on average less than 10% of the ingested NPIN were activated as ice nuclei during anvil formation. Deep convection may therefore represent an efficient transport mechanism for dust to the upper troposphere where these particles can function as ice nuclei cirrus forming in situ.

Phase transformation of GaAs at high pressures and temperatures

NASA Astrophysics Data System (ADS)

Ono, Shigeaki; Kikegawa, Takumi

2018-02-01

The high-pressure behavior of gallium arsenide, GaAs, has been investigated using an in-situ X-ray powder diffraction technique in a diamond anvil cell combined with a resistance heating method, at pressures and temperatures up to 25 GPa and 1000 K respectively. The pressure-induced phase transition from a zincblende to an orthorhombic (Cmcm) structure was observed. This transition occurred at 17.3 GPa and at room temperature, where a negative temperature dependence for this transition was confirmed. The transition boundary was determined to be P (GPa) = 18.0 - 0.0025 × T (K).

Thermal Stability of Microstructure and Microhardness of Heterophase BCC-Alloys After Torsional Deformation on Bridgman Anvils

NASA Astrophysics Data System (ADS)

Ditenberg, I. A.; Tyumentsev, A. N.

2018-03-01

The results of investigations of thermal stability of microstructure and microhardness of alloys of the V-4Ti-4Cr and Mo-47Re systems, subjected to torsional deformation by high quasi-hydrostatic pressure at room temperature, are reported. It is shown that submicrocrystalline and nanocrystalline states, and the respective high values of microhardness, persist up to the upper bound ( 0.4 Tmelt) of the temperature interval of their recovery and polygonization in a single-phase state. The main factors ensuring thermal stability of highlydefective states in heterophase alloys are discussed.

Molecular Solid EOS based on Quasi-Harmonic Oscillator approximation for phonons

DOE Office of Scientific and Technical Information (OSTI.GOV)

Menikoff, Ralph

2014-09-02

A complete equation of state (EOS) for a molecular solid is derived utilizing a Helmholtz free energy. Assuming that the solid is nonconducting, phonon excitations dominate the specific heat. Phonons are approximated as independent quasi-harmonic oscillators with vibrational frequencies depending on the specific volume. The model is suitable for calibrating an EOS based on isothermal compression data and infrared/Raman spectroscopy data from high pressure measurements utilizing a diamond anvil cell. In contrast to a Mie-Gruneisen EOS developed for an atomic solid, the specific heat and Gruneisen coefficient depend on both density and temperature.

High pressure induced crossover between metal and insulator conductivity type in low dimensionality electron systems

NASA Astrophysics Data System (ADS)

Dizhur, E.; Voronovskii, A.; Kostyleva, I.; Kotel'nikov, I.; Zaitsev-Zotov, S.

2011-12-01

We report the results of our recent experimental studies concerned with electron systems of lower dimensionality the conductivity of which may be toggled between metallic and insulating regime appliing high pressure. The objects under present study include: a) tunneling through Shottky barrier into two-dimension (2D) electron system formed in the δ-doped layer in GaAs under hydrostatic pressure up to 3 GPa in a cylinder-piston cell; b) quasi-one-dimension (1D) `insulator' crystals NbS3 which obtain metallic conductivity type at pressures above 5.5 GPa in `toroid' anvils.